u-series dated speleothem: Topics by Science.gov

Sample records for u-series dated speleothem

The Sima de los Huesos hominids date to beyond U/Th equilibrium (>350 kyr) and perhaps to 400-500 kyr: New radiometric dates

USGS Publications Warehouse

Bischoff, J.L.; Shamp, D.D.; Aramburu, Arantza; Arsuaga, J.L.; Carbonell, E.; Bermudez de Castro, Jose Maria

2003-01-01

The Sima de los Huesos site of the Atapuerca complex near Burgos, Spain contains the skeletal remains of at least 28 individuals in a mud breccia underlying an accumulation of the Middle Pleistocene cave bear (U. deningeri). Earlier dating estimates of 200 to 320 kyr were based on U-series and ESR methods applied to bones, made inaccurate by unquantifiable uranium cycling. We report here on a new discovery within the Sima de los Huesos of human bones stratigraphically underlying an in situ speleothem. U-series analyses of the speleothem shows the lower part to be at isotopic U/Th equilibrium, translating to a firm lower limit of 350 kyr for the SH hominids. Finite dates on the upper part suggest a speleothem growth rate of c. 1 cm/32 kyr. This rate, along with paleontological constraints, place the likely age of the hominids in the interval of 400 to 600 kyr. ?? 2002 Elsevier Science Ltd. All rights reserved.
New U-series dates at the Caune de l'Arago, France

USGS Publications Warehouse

Falgueres, Christophe; Yokoyama, Y.; Shen, G.; Bischoff, J.L.; Ku, T.-L.; de Lumley, Henry

2004-01-01

In the beginning of the 1980s, the Caune de l'Arago was the focus of an interdisciplinary effort to establish the chronology of the Homo heidelbergensis (Preneandertals) fossils using a variety of techniques on bones and on speleothems. The result was a very large spread of dates particularly on bone samples. Amid the large spread of results, some radiometric data on speleothems showed a convergence in agreement with inferences from faunal studies. We present new U-series results on the stalagmitic formation located at the bottom of Unit IV (at the base of the Upper Stratigraphic Complex). Samples and splits were collaboratively analyzed in the four different laboratories with excellent interlaboratory agreement. Results show the complex sequence of this stalagmitic formation. The most ancient part is systematically at internal isotopic equilibrium (>350 ka) suggesting growth during or before isotopic stage 9, representing a minimum age for the human remains found in Unit III of the Middle Stratigraphical Complex which is stratigraphically under the basis of the studied stalagmitic formation. Overlaying parts of the speleothem date to the beginning of marine isotope stages 7 and 5. ?? 2003 Elsevier Science Ltd. All rights reserved.
New U-series dates at the Caune de l'Arago, France

USGS Publications Warehouse

Falgueres, Christophe; Yokoyama, Y.; Shen, G.; Bischoff, J.L.; Ku, T.-L.; de Lumley, Henry

2004-01-01

In the beginning of the 1980s, the Caune de l'Arago was the focus of an interdisciplinary effort to establish the chronology of the Homo heidelbergensis (Preneandertals) fossils using a variety of techniques on bones and on speleothems. The result was a very large spread of dates particularly on bone samples. Amid the large spread of results, some radiometric data on speleothems showed a convergence in agreement with inferences from faunal studies. We present new U-series results on the stalagmitic formation located at the bottom of Unit IV (at the base of the Upper Stratigraphic Complex). Samples and splits were collaboratively analyzed in the four different laboratories with excellent interlaboratory agreement. Results show the complex sequence of this stalagmitic formation. The most ancient part is systematically at internal isotopic equilibrium (>350 ka) suggesting growth during or before isotopic stage 9, representing a minimum age for the human remains found in Unit III of the Middle Stratigraphical Complex which is stratigraphically under the basis of the studied stalagmitic formation. Overlaying parts of the speleothem date to the beginning of marine isotope stages 7 and 5. ?? 2003 Elsevier Ltd. All rights reserved.
Geochemistry of speleothem records from southern Illinois: Development of (234U)/(238U) as a proxy for paleoprecipitation

USGS Publications Warehouse

Zhou, Juanzuo; Lundstrom, C.C.; Fouke, B.; Panno, S.; Hackley, K.; Curry, B.

2005-01-01

Natural waters universally show fractionation of uranium series (U-series) parent-daughter pairs, with the disequilibrium between 234U and 238U (234U)/(238U) commonly used as a tracer of groundwater flow. Because speleothems provide a temporal record of geochemical variations in groundwater precipitating calcite, (234U)/(238U) variations in speleothems provide a unique method of investigating water-rock interaction processes over millennium time scales. We present high precision Thermal Ionization Mass Spectrometric (TIMS) U-series analyses of speleothems and drip waters from Fogelpole Cave in southern Illinois. Data from all speleothems from the cave show an inverse correlation between (234U)/(238U) and U concentration, following the pattern observed in groundwaters globally. Within a 65-cm-long stalagmite, concordant 234U-238 U-230Th and 235U-231Pa ages for 5 samples indicate accurate chronology from 78.5 ka to 30 ka. Notably, (234U)/(238U)o which differs from most speleothems by having (234U)/(238U)o <1, positively correlates with speleothem growth rate. We generalize this to the observation that speleothems globally show (234U)/ (238U)o deviating farther from secular equilibrium at lower growth rates and approaching secular equilibrium at higher grow rates. Based on the Fogelpole observations, we suggest that groundwater (234U)/(238U) is controlled by the U oxidation state, the U concentration of the water and the fluid velocity. A transport model whereby U-series nuclides react and exchange with mineral surfaces can reproduce the observed trend between growth rate and (234U)/(238U)o. Based on this result, we suggest that (234U)/(238U)o in speleothems may record changes in hydrologic flux with time and thus could provide a useful proxy for long term records of paleoprecipitation. ?? 2005 Elsevier B.V. All rights reserved.
Geology and preliminary dating of the hominid-bearing sedimentary fill of the Sima de los Huesos Chamber, Cueva Mayor of the Sierra de Atapuerca, Burgos, Spain.

PubMed

Bischoff, J L; Fitzpatrick, J A; León, L; Arsuagà, J L; Falgueres, C; Bahain, J J; Bullen, T

1997-01-01

Sediments of the Sima de los Huesos vary greatly over distances of a few meters. This is typical of interior cave facies, and caused by cycles of cut and fill. Mud breccias containing human bones, grading upwards to mud containing bear bones, fill an irregular surface cut into basal marks and sands. The lack of Bedding and the chaotic abundance of fragile speleothem clasts in the fossiliferous muds suggests that the deposit was originally a subterranean pond facies, and that after emplacement of the human remains, underwent vigorous post-depositional rotation and collapse and brecciation, caused by underlying bedrock dissolution and undermining. The fossiliferous deposits are capped by flowstone and guano-bearing muds which lack large-mammal fossils. U-series and radiocarbon dating indicates the capping flowstones formed from about 68 ka to about 25 ka. U-series analyses of speleothem clasts among the human fossils indicate that all are at, or close to, isotopic equilibrium (> 350 ka). The distribution of U-series dates for 25 bear bones (154 +/- 66 ka) and for 16 human bones (148 +/- 34 ka) is similar and rather broad. Because the human bones seem to be stratigraphically older than chose of the bears, the results would indicate that most of the bones have been accumulating uranium irregularly with time. Electron spin resonance (ESR) analyses of six selected bear bones indicates dates of 189 +/- 28 ka, for which each is cordant with their corresponding U-series date (181 +/- 41 ka). Combined ESR and U-series dates for these samples yielded 200 +/- 4 ka. Such agreement is highly suggestive that uranium uptake in these bones was close to the early-uptake (EU) model, and the dates are essentially correct. Another three selected samples yielded combined ESR U-series dates of 320 +/- 4 ka with a modeled intermediate-mode of uranium uptake. The dating results, therefore, seem to provide a firm minimum age of about 200 ka for the human entry: and suggestive evidence of entry before 320 ka.
Geology and preliminary dating of the hominid-bearing sedimentary fill of the Sima de los Huesos Chamber, Cueva Mayor of the Sierra de Atapuerca, Burgos, Spain

USGS Publications Warehouse

Bischoff, J.L.; Fitzpatrick, J.A.; Leon, L.; Arsuaga, J.L.; Falgueres, Christophe; Bahain, J.-J.; Bullen, T.

1997-01-01

Sediments of the Sima de los Huesos vary greatly over distances of a few meters. This is typical of interior cave facies, and caused by cycles of cut and fill. Mud breccias containing human bones, grading upwards to mud containing bear bones, fill an irregular surface cut into basal marls and sands. The lack of bedding and the chaotic abundance of fragile speleothem clasts in the fossiliferous muds suggests that the deposit was originally a subterranean pond facies, and that after emplacement of the human remains, underwent vigorous post-depositional rotation and collapse and brecciation, caused by underlying bedrock dissolution and undermining. The fossiliferous deposits are capped by flowstone and guano-bearing muds which lack large-mammal fossils. U-series and radiocarbon dating indicates the capping flowstones formed from about 68 ka to about 25 ka. U-series analyses of speleothem clasts among the human fossils indicate that all are at, or close to, isotopic equilibrium (>350 ka). The distribution of U-series dates for 25 bear bones (154??66ka) and for 16 human bones (148??34 ka) is similar and rather broad. Because the human bones seem to be stratigraphically older than those of the bears, the results would indicate that most of the bones have been accumulating uranium irregularly with time. Electron spin resonance (ESR) analyses of six selected bear bones indicates dates of 189??28 ka, for which each is concordant with their corresponding U-series date (181??41 ka). Combined ESR and U-series dates for these samples yielded 200??4 ka. Such agreement is highly suggestive that uranium uptake in these bones was close to the early-uptake (EU) model, and the dates are essentially correct. Another three selected samples yielded combined ESR-U-series dates of 320??4 ka with a modeled intermediate-mode of uranium uptake. The dating results, therefore, seem to provide a firm minimum age of about 200 ka for the human entry; and suggestive evidence of entry before 320 ka. ?? 1997 Academic Press Limited.
Sharpening the U-Th Chronometer: Progress and Outlook

NASA Astrophysics Data System (ADS)

McLean, N. M.; Condon, D. J.; Henderson, G. M.; Richards, D. A.; Noble, S.; Mason, A.

2013-12-01

Uranium is incorporated into a variety of natural materials when they form, including carbonates like speleothems and corals. The two most abundant naturally occurring uranium isotopes, 238U and 235U, decay to 206Pb and 207Pb over long timescales with half-lives of 4.5 and 0.7 billion years respectively, but transition through several intermediate daughter isotopes with shorter half-lives first. Fractionation between these daughter isotopes, including 234U, 230Th, and 231Pa, and their parent isotopes, followed by their time-dependent return to secular equilibrium over the course of up to ~800 kyr, forms the basis for U-series geochronology, and allows speleothems and corals to be precisely dated. These carbonates often additionally incorporate chemical and isotopic signatures (e.g., trace elements, δ18O and δ13C) from the environment in which they form, and thus are some of the best dated paleoclimate archives, offering clues about past and future conditions for life on Earth. Over the past decade, the analytical precision of U-series isotope measurements has improved dramatically, largely due to the steadily increasing sensitivity of multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). Analytical uncertainties in U-Th dates now approach or are better than 0.1% (2σ), for instance ×100 years for a speleothem or coral that is 130 kyr old (Cheng et al., 2013). However, the accuracy of U-series dates also depends on the accuracy of tracer calibrations, reference solutions and data reduction protocols, which has not kept pace in many laboratories. This means that dates measured in different labs, while impressively precise, may not be directly comparable. To address issues of inter-laboratory bias and improve the accuracy and inter-comparability of U-Th dates, we have instigated work in three related directions. First, we report on the mixing of three synthetic U-Th age solutions, created by combining high-purity mono-isotopic solutions to mimic the isotopic composition of commonly analyzed materials. These age solutions will form the basis for an inter-laboratory comparison and serve as international reference materials for assessing long-term reproducibility. Second is the creation of several U-Th gravimetric solutions, which can be used to calibrate the mixed 229Th-236U×233U tracers used in the community without having to rely on materials assumed to be in secular equilibrium. Tracers calibrated against these solutions, and therefore U-Th dates measured with these tracers, will be fully metrologically traceable. Finally, we report progress on and important considerations in developing data reduction and uncertainty propagation protocols for calculating U-Th dates and constructing and interpreting U-Th age models. Reference: Cheng et al. (2013) EPSL 371-372, 82-91
Thermal ionization mass spectrometry U-series dating of a hominid site near Nanjing, China

NASA Astrophysics Data System (ADS)

Zhao, Jian-Xin; Hu, Kai; Collerson, Kenneth D.; Xu, Han-Kui

2001-01-01

Mass spectrometric U-series dating of speleothems from Tangshan Cave, combined with ecological and paleoclimatic evidence, indicates that Nanjing Man, a typical Homo erectus morphologically correlated with Peking Man at Zhoukoudian, should be at least 580 k.y. old, or more likely lived during the glacial oxygen isotope stage 16 (˜620 ka). Such an age estimate, which is ˜270 ka older than previous electron spin resonance and alpha-counting U-series dates, has significant implications for the evolution of Asian H. erectus. Dentine and enamel samples from the coexisting fossil layer yield significantly younger apparent ages, that of the enamel sample being only less than one-fourth of the minimum age of Nanjing Man. This suggests that U uptake history is far more complex than existing models can handle. As a result, great care must be taken in the interpretation of electron spin resonance and U-series dates of fossil teeth.
A Uranium-Lead Chronology of Speleothem Deposition in the Canadian Arctic

NASA Astrophysics Data System (ADS)

Gambino, C.; Shakun, J. D.; McGee, D.; Ramezani, J.; Khadivi, S.; Wong, C. I.

2017-12-01

The Artic is one of the fastest warming regions on the planet. Currently much of the Arctic is covered by permafrost, which contains approximately 1,700 gigatons of organic carbon. Permafrost thaw could release a substantial amount of this carbon as greenhouse gases into the atmosphere through microbial decomposition, potentially dramatically amplifying anthropogenic warming. However, the risk of permafrost thaw is uncertain, with models exhibiting a wide range of possibilities. Assessing the stability of permafrost during past interglacial periods enables evaluation of the sensitivity of permafrost to warming. Cave mineral deposits (speleothems) in areas currently covered with permafrost can act as a proxy for past permafrost thaw, as liquid water is one criteria of speleothem growth and thus implies thawed ground conditions. Previous uranium-thorium (U-Th) dating of speleothems (n=67) from a wide range of latitudes and permafrost zones across the southern Canadian Rockies, Northwest Territories, and the northern Yukon suggest deposition during Marine Isotope Stage (MIS) 11 and 13. The majority of U-Th dates of these speleothems, however, exceed the U-Th dating limit of 600 ka. In this study, we apply uranium-lead (U-Pb) geochronology to several of these speleothems to extend the records of speleothem growth further back in time. Initial results include a U-Pb age of 428 ± 14 ka that replicates a previous U-Th age of 416.8 ± 7.9 ka, and U-Pb ages on two other speleothems of 870 ± 100 ka and 1502 ± 30 ka. The results of currently in progress U-Pb analyses and a comparison of results with paleo-temperature and ice volume reconstructions will also be presented.
High-resolution U-series dates from the Sima de los Huesos hominids yields 600 +∞-66: implications for the evolution of the early Neanderthal lineage

USGS Publications Warehouse

Bischoff, James L.; Williams, Ross W.; Rosenbauer, Robert J.; Aramburu, Arantza; Arsuaga, Juan Luis; Garcia, Nuria; Cuenca-Bescos, Gloria

2007-01-01

The Sima de los Huesos site of the Atapuerca complex near Burgos, Spain contains the skeletal remains of at least 28 individuals in a mud-breccia underlying an accumulation of the Middle Pleistocene cave bear (Ursus deningeri). We report here on new high-precision dates on the recently discovered speleothem SRA-3 overlaying human bones within the Sima de los Huesos. Earlier analyses of this speleothem by TIMS (thermal-ionization mass-spectrometry) showed the lower part to be indistinguishable from internal isotopic equilibrium at the precision of the TIMS instrumentation used, yielding minimum age of 350 kyr (kyr = 103 yr before present). Reanalysis of six samples of SRA-3 by inductively-coupled plasma-multicollector mass-spectrometry (ICP-MS) produced high-precision analytical results allowing calculation of finite dates. The new dates cluster around 600 kyr. A conservative conclusion takes the lower error limit ages as the minimum age of the speleothem, or 530 kyr. This places the SH hominids at the very beginnings of the Neandertal evolutionary lineage.
Direct Measurement of Initial 230TH/ 232TH Ratios in Central Texas Speleothems for More Accurate Age Determination

NASA Astrophysics Data System (ADS)

Wortham, B. E.; Banner, J. L.; James, E.; Loewy, S. L.

2013-12-01

Speleothems, calcite deposits in caves, preserve a record of climate in their growth rate, isotope ratios and trace element concentrations. These variables must be tied to precise ages to produce pre-instrumental records of climate. The 238U-234U- 230Th disequilibrium method of dating can yield precise ages if the amount of 230Th from the decay of radiogenic 238U can be constrained. 230Th in a speleothem calcite growth layer has two potential sources - 1) decay of radioactive 238U since the time of growth of the calcite layer; and 2) initial detrital 230Th, incorporated along with detrital 232Th, into the calcite layer at the time it grew. Although the calcite lattice does not typically incorporate Th, samples can contain impurities with relatively high Th contents. Initial 230Th/232Th is commonly estimated by assuming a source with bulk-Earth U/Th values in a state of secular equilibrium in the 238U-decay chain. The uncertainty in this 230Th/232Th estimate is also assumed, typically at +/-100%. Both assumptions contribute to uncertainty in ages determined for young speleothems. If the amount of initial detrital 230Th can be better quantified for samples or sites, then U-series ages will have smaller uncertainties and more precisely define the time series of climate proxies. This study determined the initial 230Th/232Th of modern calcite to provide more precise dates for central Texas speleothems. Calcite was grown on glass-plate substrates placed under active drips in central Texas caves. The 230Th/232Th of this modern calcite was determined using thermal ionization mass spectrometry. Results show that: 1) initial 230Th/232Th ratios can be accurately determined in these young samples and 2) measuring 230Th/232Th reduces the uncertainties in previously-determined ages on stalagmites from under the same drips. For example, measured initial 230Th/232Th in calcite collected on substrates from different locations in the cave at Westcave Preserve are 15.3 × 0.67 ppm, 14.6 × 0.83 ppm, 5.8 × 0.56 ppm, and 5.9 × 0.60 ppm, which are higher and more precise than the value commonly assumed for initial 230Th/232Th, 4.4 × 4.4 ppm. Soil sampled above Westcave, a potential source of detrital Th incorporated into speleothems, also has a high calculated 230Th/232Th. We calculate soil 230Th/232Th from measured U and Th concentrations of soil leachates (using DI water and ammonium acetate). Calculated 230Th/232Th for Westcave soils range from 0.39 to 28.4 ppm, which encompasses the range of initial 230Th/232Th values found in the modern calcite. Soil leachates from Natural Bridge Caverns and Inner Space Cavern were analyzed by the same method, yielding calculated 230Th/232Th ranging from 1.5 to 12.6 ppm (Natural Bridge), and from 1.43 to 272 ppm (Inner Space). Soil and calcite data indicate that the commonly assumed initial 230Th/232Th is not always applicable and that initial 230Th/232Th can be estimated more accurately by measuring Th isotope ratios in modern calcite and soils to determine speleothem U-series ages.
Carbonate speleothems from western Mediterranean gypsum karst: palaeoclimate implications

NASA Astrophysics Data System (ADS)

Columbu, Andrea; Drysdale, Russell; Woodhead, Jon; Chiarini, Veronica; De Waele, Jo; Hellstrom, John; Forti, Paolo; Sanna, Laura

2016-04-01

Gypsum caves are uncommon environments for carbonate speleothems (cave deposits). Contrary to limestone caves, the only source of non-atmospheric carbon is from biogenic CO2 produced by the overlying soils. Enhanced CO2 content in soils is in turn related with climate, where warm temperatures and high humidity favour plant activity .().....(Fairchild and Baker, 2012). Although poorly decorated, the exploration of northern Italian and Spanish gypsum karst systems reveals the existence of several generations of carbonate speleothems, which have been dated with the U-Th series method .()......(Hellstrom, 2003; Scholz and Hoffmann, 2008). Their ages coincide with current and previous two interglacials (MIS 1, 5e and 7e and Greenland interstadials (GIS) 19, 20, 21 and 24. Considering that these periods are amongst the most pronounced warm-wet pulsations over the last 250,000 ...(Martrat et al., 2007; NGRIP, 2004), and that CO2 has a fundamental role in this karst process, this study explores the climate-driven hydrogeological conditions necessary to trigger carbonate deposition in gypsum voids. The further correlation with sapropel events 5, 4, 3 and 1, considered symptomatic of enhanced rainfall across the whole Mediterranean basin .(.)(Emeis et al., 1991), highlights the importance of flow-rate in the fracture network and infiltration of meteoric water into the caves. The combination of high CO2 and a phreatic status of the fracture network is thus indispensable for the formation of carbonate speleothems in gypsum karst. This condition appears to be triggered by periods of orbital precession minimum, when the monsoonal activity peaked in the Atlantic area. Stable oxygen isotope signatures suggest that the speleothems did not grow during any interglacial-glacial or main interstadial-stadial transitions, confirming that variations from optimum climate conditions may hamper the formation of this category of speleothems. New speleological exploration and sampling campaign may extend this model in space (extra-Mediterranean regions) and time (500,000 BP - the limit of U-Th dating), enhancing knowledge on the latitudinal impact and timing of such climate variability. References .Emeis, K.-C., Camerlenghi, A., McKenzie, J. A., Rio, D., and Sprovieri, R., 1991, The occurrence and significance of Pleistocene and Upper Pliocene sapropels in the Tyrrhenian Sea: Marine geology, v. 100, no. 1, p. 155-182. Fairchild, I. J., and Baker, A., 2012, Speleothem science: from process to past environments: John Wiley & Sons, Chichester. Hellstrom, J., 2003, Rapid and accurate U/Th dating using parallel ion-counting multi-collector ICP-MS.: Journal of Analytical Atomic Spectrometry, v. 18. Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F., 2007, Four climate cycles of recurring deep and surface water destabilizations on the Iberian margin: Science, v. 317, no. 5837, p. 502-507. NGRIP, N. G. I. C. P. M., 2004, High-resolution record of Northern Hemisphere climate extending into the last interglacial period: Nature, v. 431, no. 7005, p. 147-151. Scholz, D., and Hoffmann, D., 2008, 230Th/U-dating of fossil corals and speleothems: Quat. Sci. J, v. 57, p. 52.
Timing of the onset of MIS 11 revealed by speleothem in southern Europe

NASA Astrophysics Data System (ADS)

Hu, Hsun-Ming; Shen, Chuan-Chou; Michel, Véronique; Kano, Akihiro

2017-04-01

The interglacial period, known as Marine Isotope Stage 11 (MIS 11, 428-397 thousand years ago), is often considered as a potential analogue for future climate projection because of the similar patterns of insolation variability. However, studies on mechanisms of the onset of MIS 11 (called Termination V, T-V) in response to insolation increase is still hampered by a lack of good dating materials in paleoclimate archives, despite a stack of East Asian monsoon records with precise U-Th dates has been proposed. Previous studies suggested the δ18O value registered in speleothems in Mediterranean realm can be a good bridge connecting the U-Th-based age model of speleothem to marine cores from Mediterranean sea, which opens a new possibility to detect ocean-atmosphere/internal-external forcing interaction beyond 14C dating limitation. Here we present a new speleothem δ18O record from northern Italy covering 500-300 thousand years ago. The results show a similar pattern with δ18O records of marine cores around Mediterranean. The age model of the speleothem hence provides an opportunity for tuning the marine cores, which could improve our understanding of relationship between global atmosphere and ocean circulations.
The earliest settlers of Mesoamerica date back to the late Pleistocene.

PubMed

Stinnesbeck, Wolfgang; Becker, Julia; Hering, Fabio; Frey, Eberhard; González, Arturo González; Fohlmeister, Jens; Stinnesbeck, Sarah; Frank, Norbert; Terrazas Mata, Alejandro; Benavente, Martha Elena; Avilés Olguín, Jerónimo; Aceves Núñez, Eugenio; Zell, Patrick; Deininger, Michael

2017-01-01

Preceramic human skeletal remains preserved in submerged caves near Tulum in the Mexican state of Quintana Roo, Mexico, reveal conflicting results regarding 14C dating. Here we use U-series techniques for dating a stalagmite overgrowing the pelvis of a human skeleton discovered in the submerged Chan Hol cave. The oldest closed system U/Th age comes from around 21 mm above the pelvis defining the terminus ante quem for the pelvis to 11311±370 y BP. However, the skeleton might be considerable older, probably as old as 13 ky BP as indicated by the speleothem stable isotope data. The Chan Hol individual confirms a late Pleistocene settling of Mesoamerica and represents one of the oldest human osteological remains in America.
The earliest settlers of Mesoamerica date back to the late Pleistocene

PubMed Central

Becker, Julia; Hering, Fabio; Frey, Eberhard; González, Arturo González; Fohlmeister, Jens; Stinnesbeck, Sarah; Frank, Norbert; Terrazas Mata, Alejandro; Benavente, Martha Elena; Avilés Olguín, Jerónimo; Aceves Núñez, Eugenio; Zell, Patrick; Deininger, Michael

2017-01-01

Preceramic human skeletal remains preserved in submerged caves near Tulum in the Mexican state of Quintana Roo, Mexico, reveal conflicting results regarding 14C dating. Here we use U-series techniques for dating a stalagmite overgrowing the pelvis of a human skeleton discovered in the submerged Chan Hol cave. The oldest closed system U/Th age comes from around 21 mm above the pelvis defining the terminus ante quem for the pelvis to 11311±370 y BP. However, the skeleton might be considerable older, probably as old as 13 ky BP as indicated by the speleothem stable isotope data. The Chan Hol individual confirms a late Pleistocene settling of Mesoamerica and represents one of the oldest human osteological remains in America. PMID:28854194
Speleothem evidence for the greening of the Sahara and its implications for the early human dispersal out of sub-Saharan Africa

NASA Astrophysics Data System (ADS)

El-Shenawy, Mohammed I.; Kim, Sang-Tae; Schwarcz, Henry P.; Asmerom, Yemane; Polyak, Victor J.

2018-05-01

Although there is a consensus that there were wet periods (greening events) in the Sahara in the past, the spatial extent and the timing of these greening events are still in dispute, yet critical to our understanding of the early human dispersal out of Africa. Our U-series dates of speleothems from the Northeastern Sahara (Wadi Sannur cave, Egypt) reveal that the periods of speleothem growth were brief and restricted to the interglacial Marine Isotope Stages MIS 5.5, MIS 7.3, and the early MIS 9 with a remarkable absence of the Holocene deposition of speleothems. These growth periods of Wadi Sannur cave speleothems correspond to periods of high rainfall and spread of vegetation (green Sahara). Distinct low δ18O values of speleothems indicate a distal moisture source that we interpret to be the Atlantic Ocean. These two lines of evidence from the Wadi Sannur speleothems thus suggest that maximal northward shifts in the West African monsoon system occurred during the growth periods of the speleothems, leading to greening of the Sahara, facilitating human migration into Eurasia. The periods of speleothem growth at Wadi Sannur cave are contemporaneous with important archeological events: (1) the earliest occurrence of the Middle Stone Age assemblages and Homo sapiens in North Africa (Jebel Irhoud), suggesting wide spread of greening conditions over the East-West transect of the Sahara, (2) the sharp technological break between the Acheulo-Yabrudian and the Mousterian industries, and (3) the arrival of Homo sapiens in Levant, indicating a key role of the Sahara route in early human dispersal out of Africa.
Statistical U-Th dating results of speleothem from south Europe and the orbital-scale implication

NASA Astrophysics Data System (ADS)

Hu, H. M.

2016-12-01

Reconstructing of hydroclimate in the Mediterranean on an orbital time scale helps improve our understanding of interaction between orbital forcing and north hemisphere climate. We collected 180 speleothem subsamples from Observatoire Cave (Monaco), Prince Cave (south France), Chateaueuf Cave (South France), Arago Cave (South France), and Basura Cave (North Italy) during 2013 to 2015 C.E. Uranium-thorium dating were conducted in the High-Precision Mass Spectrometry and Environment Change Laboratory (HISPEC), National Taiwan University. The results show that most of the speleothem formed during interglacial periods, particularly in marine isotope stage (MIS) 1, 5, and 11. However, only a few speleothem were dated between 180 to 250 thousand years ago (ka). The interval is approximately equivalent to MIS 7, which is a period with contrasting orbital parameters compared to MIS1, 5, and 11. Our statistical dating result implies that the orbital-scale humid/dry condition in southern Europe could be dominantly controlled by orbital forcing.
ESR and 230Th/234U dating of speleothems from Aladağlar Mountain Range (AMR) in Turkey

NASA Astrophysics Data System (ADS)

Ulusoy, Ülkü; Anbar, Gül; Bayarı, Serdar; Uysal, Tonguç

2014-03-01

Electron spin resonance (ESR) and 230Th/234U ages of speleothem samples collected from karstic caves located around 3000 m elevation in the Aladağlar Mountain Range (AMR), south-central Turkey, were determined in order to provide new insight and information regarding late Pleistocene climate. ESR ages were validated with the 230Th/234U ages of test samples. The ESR ages of 21 different layers of six speleothem samples were found to range mostly between about 59 and 4 ka, which cover the Marine Oxygen Isotope Stages (MIS) MIS 3 to MIS 1. Among all, only six layers appear to have deposited during MIS 8 and 5. Most of the samples dated were deposited during the late glacial stage (MIS 2). It appears that a cooler climate with a perennial and steady recharge was more conducive to speleothem development rather than a warmer climate with seasonal recharge in the AMR during the late Quaternary. This argument supports previous findings that suggest a two -fold increase in last glacial maximum mean precipitation in Turkey with respect to the present value.
A Detailed 31,000-Year Record of Climate and Vegetation Change, from the Isotope Geochemistry of Two New Zealand Speleothems

NASA Astrophysics Data System (ADS)

Hellstrom, John; McCulloch, Malcolm; Stone, John

1998-09-01

Uranium-series dating and stable isotope analyses of two speleothems from northwest Nelson, New Zealand, record changes in regional climate and local forest extent over the past 31,000 years. Oxygen isotope variation in these speleothems primarily represents changes in the meteoric waters falling above the caves, possibly responding to latitudinal changes in the position of the Subtropical Front in the Tasman Sea. Seven positive excursions can be identified in the oxygen isotope record, which coincide with periods of glacier advance, known to be sensitive to northward movement of the Subtropical Front. Four glacier advances occurred during oxygen isotope stage 2, with the most extreme glacial conditions centered on 19,000 cal yr B.P. 2An excursion in the oxygen isotope record from 13,800 to 11,700 cal yr B.P. provides support for a previously identified New Zealand glacier advance at the time of the Younger Dryas Stade, but suggests it began slightly before the Younger Dryas as recorded in Greenland ice cores. Carbon isotope variations in the speleothems record changes in forest productivity, closely matching existing paleovegetation records. On the basis of vegetation changes, stage 2 glacial climate conditions terminated abruptly in central New Zealand, from 15,700 to 14,200 cal yr B.P. Evidence of continuous speleothem growth at one site suggests that depression of the local treeline was limited to 600-700 m below its present altitude, throughout the last 31,000 years. All ages reported or cited in this paper are in calendar years before present, expressed as "cal yr B.P." With the exception of the U-series dates of Williams (1996), all ages cited for events in New Zealand were reported by the sources cited as radiocarbon ages. In this paper, these radiocarbon ages have been corrected to calendar years before present using the 1993 calibration data set of Stuiver and Reimer (1993), or, for ages of greater than 19,000 14C yr B.P., by the addition of 4000 yr, on the basis of data in Bard et al.(1993).
Age of Zhoukoudian Homo erectus determined with (26)Al/(10)Be burial dating.

PubMed

Shen, Guanjun; Gao, Xing; Gao, Bin; Granger, Darryl E

2009-03-12

The age of Zhoukoudian Homo erectus, commonly known as 'Peking Man', has long been pursued, but has remained problematic owing to the lack of suitable dating methods. Here we report cosmogenic (26)Al/(10)Be burial dating of quartz sediments and artefacts from the lower strata of Locality 1 in the southwestern suburb of Beijing, China, where early representatives of Zhoukoudian Homo erectus were discovered. This study marks the first radioisotopic dating of any early hominin site in China beyond the range of mass spectrometric U-series dating. The weighted mean of six meaningful age measurements, 0.77 +/- 0.08 million years (Myr, mean +/- s.e.m.), provides the best age estimate for lower cultural layers 7-10. Together with previously reported U-series dating of speleothem calcite and palaeomagnetic stratigraphy, as well as sedimentological considerations, these layers may be further correlated to S6-S7 in Chinese loess stratigraphy or marine isotope stages (MIS) 17-19, in the range of approximately 0.68 to 0.78 Myr ago. These ages are substantially older than previously supposed and may imply early hominin's presence at the site in northern China through a relatively mild glacial period corresponding to MIS 18.

New Comprehensive System to Construct Speleothem Fabrics Time Series

NASA Astrophysics Data System (ADS)

Frisia, S.; Borsato, A.

2014-12-01

Speleothem fabrics record processes that influence the way geochemical proxy data are encoded in speleothems, yet, there has been little advance in the use of fabrics as a complement to palaeo-proxy datasets since the fabric classification proposed by us in 2010. The systematic use of fabrics documentation in speleothem science has been limited by the absence of a comprehensive, numerical system that would allow constructing fabric time series comparable with the widely used geochemical time series. Documentation of speleothem fabrics is fundamental for a robust interpretation of speleothem time series where stable isotopes and trace elements are used as proxy, because fabrics highlight depositional as well as post-depositional processes whose understanding complements reconstructions based on geochemistry. Here we propose a logic system allowing transformation of microscope observations into numbers tied to acronyms that specify each fabric type and subtype. The rationale for ascribing progressive numbers to fabrics is based on the most up-to-date growth models. In this conceptual framework, the progression reflects hydrological conditions, bio-mediation and diagenesis. The lowest numbers are given to calcite fabrics formed at relatively constant drip rates: the columnar types (compact and open). Higher numbers are ascribed to columnar fabrics characterized by presence of impurities that cause elongation or lattice distortion (Elongated, Fascicular Optic and Radiaxial calcites). The sequence progresses with the dendritic fabrics, followed by micrite (M), which has been observed in association with microbial films. Microsparite (Ms) and mosaic calcite (Mc) have the highest numbers, being considered as diagenetic. Acronyms and subfixes are intended to become universally acknowledged. Thus, fabrics can be plotted vs. age to yield time series, where numbers are replaced by the acronyms. This will result in a visual representation of climate- or environmental-related parameters underpinning speleothem crystal growth. The Fabric log thus becomes a useful tool providing robustness to the geochemical data or test the overall utility of the speleothem record.
Ion microprobe δ18O analyses to calibrate slow growth rate speleothem records with regional δ18O records of precipitation

NASA Astrophysics Data System (ADS)

Domínguez-Villar, David; Lojen, Sonja; Krklec, Kristina; Kozdon, Reinhard; Edwards, R. Lawrence; Cheng, Hai

2018-01-01

Paleoclimate reconstructions based on speleothems require a robust interpretation of their proxies. Detailed transfer functions of external signals to the speleothem can be obtained using models supported by monitoring data. However, the transferred signal may not be stationary due to complexity of karst processes. Therefore, robust interpretations require the calibration of speleothem records with instrumental time series lasting no less than a decade. We present the calibration of a speleothem δ18O record from Postojna Cave (Slovenia) with the regional record of δ18O composition of precipitation during the last decades. Using local meteorological data and a regional δ18O record of precipitation, we developed a model that reproduces the cave drip water δ18O signal measured during a two-year period. The model suggests that the average water mixing and transit time in the studied aquifer is 11 months. Additionally, we used an ion microprobe to study the δ18O record of the top 500 μm of a speleothem from the studied cave gallery. According to U-Th dates and 14C analyses, the uppermost section of the speleothem was formed during the last decades. The δ18O record of the top 500 μm of the speleothem has a significant correlation (r2 = 0.64; p-value <0.001) with the modelled δ18O record of cave drip water. Therefore, we confirm that the top 500 μm of the speleothem grew between the years 1984 and 2003 and that the speleothem accurately recorded the variability of the δ18O values of regional precipitation filtered by the aquifer. We show that the recorded speleothem δ18O signal is not seasonally biased and that the hydrological dynamics described during monitoring period were stationary during recent decades. This research demonstrates that speleothems with growth rates <50 μm/yr can also be used for calibration studies. Additionally, we show that the fit of measured and modelled proxy data can be used to achieve annually resolved chronologies in speleothems that were not actively growing at the time of collection and/or that do not record annual laminae.
Application of U/Th and 40Ar/39Ar Dating to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic Site in Ardèche, France

PubMed Central

Michel, Véronique; Shen, Guanjun; Shen, Chuan-Chou; Wu, Chung-Che; Vérati, Chrystèle; Gallet, Sylvain; Moncel, Marie-Hélène; Combier, Jean; Khatib, Samir; Manetti, Michel

2013-01-01

Refined radio-isotopic dating techniques have been applied to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic site in France. Evidence of Levallois core technology appeared in level 4b in the middle of the sequence, became predominant in the upper horizons, and was best represented in uppermost level 1, making the site one of the oldest examples of Levallois technology. In our dating study, fourteen speleothem samples from levels 7, 6 and 5b, were U/Th-dated. Four pure calcite samples from the speleothem PL1 (levels 5b, 6) yield ages between 265 ± 4 (PL1-3) and 312 ± 15 (PL1-6) thousand years ago (ka). Three samples from the top of a second stalagmite, PL2, yield dates ranging from 288 ± 10 ka (PL2-1) to 298 ± 17 ka (PL2-3). Three samples from the base of PL2 (level 7) yield much younger U/Th dates between 267 and 283 ka. These dates show that the speleothems PL1 and PL2 are contemporaneous and formed during marine isotope stage (MIS) 9 and MIS 8. Volcanic minerals in level 2, the upper sequence, were dated by the 40Ar/39Ar method, giving a weighted mean of 302.9 ± 2.5 ka (2σ) and an inverse isochron age of 302.9 ± 5.9 ka (2σ). Both 40Ar/39Ar dating of volcanic sanidines and U/Th dating of relatively pure and dense cave calcites are known to be well established. The first parallel application of the two geochronometers to Orgnac 3 yields generally consistent results, which point to the reliability of the two methods. The difference between their age results is discussed. PMID:24349273
Application of U/Th and 40Ar/39Ar dating to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic site in Ardèche, France.

PubMed

Michel, Véronique; Shen, Guanjun; Shen, Chuan-Chou; Wu, Chung-Che; Vérati, Chrystèle; Gallet, Sylvain; Moncel, Marie-Hélène; Combier, Jean; Khatib, Samir; Manetti, Michel

2013-01-01

Refined radio-isotopic dating techniques have been applied to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic site in France. Evidence of Levallois core technology appeared in level 4b in the middle of the sequence, became predominant in the upper horizons, and was best represented in uppermost level 1, making the site one of the oldest examples of Levallois technology. In our dating study, fourteen speleothem samples from levels 7, 6 and 5b, were U/Th-dated. Four pure calcite samples from the speleothem PL1 (levels 5b, 6) yield ages between 265 ± 4 (PL1-3) and 312 ± 15 (PL1-6) thousand years ago (ka). Three samples from the top of a second stalagmite, PL2, yield dates ranging from 288 ± 10 ka (PL2-1) to 298 ± 17 ka (PL2-3). Three samples from the base of PL2 (level 7) yield much younger U/Th dates between 267 and 283 ka. These dates show that the speleothems PL1 and PL2 are contemporaneous and formed during marine isotope stage (MIS) 9 and MIS 8. Volcanic minerals in level 2, the upper sequence, were dated by the (40)Ar/(39)Ar method, giving a weighted mean of 302.9 ± 2.5 ka (2σ) and an inverse isochron age of 302.9 ± 5.9 ka (2σ). Both (40)Ar/(39)Ar dating of volcanic sanidines and U/Th dating of relatively pure and dense cave calcites are known to be well established. The first parallel application of the two geochronometers to Orgnac 3 yields generally consistent results, which point to the reliability of the two methods. The difference between their age results is discussed.
600 yr High-Resolution Climate Reconstruction of the Atlantic Multidecadal Oscillation deduced from a Puerto Rican Speleothem

NASA Astrophysics Data System (ADS)

Vieten, Rolf; Winter, Amos; Scholz, Denis; Black, David; Spoetl, Christoph; Winterhalder, Sophie; Koltai, Gabriella; Schroeder-Ritzrau, Andrea; Terzer, Stefan; Zanchettin, Davide; Mangini, Augusto

2016-04-01

A multi-proxy speleothem study tracks the regional hydrological variability in Puerto Rico and highlights its close relation to the Atlantic Multidecadal Oscillation (AMO) describing low-frequency sea-surface temperature (SST) variability in the North Atlantic ocean. Our proxy record extends instrumental observations 600 years into the past, and reveals the range of natural hydrologic variability for the region. A detailed interpretation and understanding of the speleothem climate record is achieved by the combination of multi-proxy measurements, thin section petrography, XRD analysis and cave monitoring results. The speleothem was collected in Cueva Larga, a one mile-long cave system that has been monitored since 2012. MC-ICPMS 230Th/U-dating reveals that the speleothem grew constantly over the last 600 years. Trace element ratios (Sr/Ca and Mg/Ca) as well as stable isotope ratios (δ18O and δ13C) elucidate significant changes in atmospheric precipitation at the site. Monthly cave monitoring results demonstrate that the epikarst system responds to multi-annual changes in seepage water recharge. The drip water isotope and trace element composition lack short term or seasonal variability. This hydrological system creates favorable conditions to deduce decadal climate variability from Cueva Larga's climate record. The speleothem time series mimics the most recent AMO reconstruction over the last 200 years (Svendsen et al., 2014) with a time lag of 10-20 years. The lag seems to results from slow atmospheric signal transmission through the epikarst but the effect of dating uncertainties cannot be ruled out. Warm SSTs in the North Atlantic are related to drier conditions in Puerto Rico. During times of decreased rainfall a relative increase in prior calcite precipitation seems to be the main process causing increased Mg/Ca trace element ratios. High trace element ratios correlate to higher δ13C values. The increase in both proxies indicates a shift towards time periods of decreased rainfall. Before 1800 there were two intervals of increased Mg/Ca and δ13C values (dryer conditions) lasting several decades in our speleothem record centered around 1680 CE and 1470 CE. The elevated ratios indicate that drier conditions than present may have occurred in the region during periods of warm Atlantic surface waters.
600 yr High-Resolution Climate Reconstruction of the Atlantic Multidecadal Variability deduced from a Puerto Rican Speleothem

NASA Astrophysics Data System (ADS)

Winter, A.; Vieten, R.

2015-12-01

A multi-proxy speleothem study tracks the regional hydrological variability in Puerto Rico and highlights its close relation to the Atlantic Multidecadal Oscillation. Our proxy record extends instrumental observations 600 years into the past, and reveals the range of natural hydrologic variability for the region. A detailed interpretation and understanding of the speleothem climate record is achieved by the combination of multi-proxy measurements, thin section petrography, XRD analysis and cave monitoring results. The speleothem was collected in Cueva Larga, a one mile-long cave system that has been monitored since 2012. MC-ICPMS 230Th/U-dating reveals that the speleothem grew constantly over the last 600 years. Trace element ratios (Sr/Ca and Mg/Ca) as well as stable isotope ratios (δ18O and δ13C) elucidate significant changes in atmospheric precipitation at the site. Monthly cave monitoring results demonstrate that the epikarst system responds to multi-annual changes in seepage water recharge. The drip water isotope and trace element composition lack short term or seasonal variability. This hydrological system creates favorable conditions to deduce decadal climate variability from Cueva Larga's climate record. The speleothem time series mimics the most-recently published AMO reconstruction over the last 200 years with a time lag of 10-20 years. The time lag seems to results from slow atmospheric signal transmission through the epikarst but the effect of dating uncertainties cannot be ruled out. Warm SSTs in the North Atlantic are related to drier conditions in Puerto Rico. During times of decreased rainfall a relative increase in prior calcite precipitation seems to be the main process causing increased Mg/Ca trace element ratios. High trace element ratios correlate to higher δ13C values. The increase in both proxies indicates a shift towards time periods of decreased rainfall. Over the past 600 years there are two intervals of increased Mg/Ca and δ13C values lasting several decades in our speleothem record. They are centered around 1680 CE and 1470 CE. The elevated ratios indicate that drier conditions than present occurred in the region during periods of warm Atlantic surface waters. This may be a precursor of conditions now and to come.
Little Ice Age versus Present Day: Comparison of Temperature, Precipitation and Seasonality in Speleothem Records from the Han-sur-Lesse Cave, Belgium.

NASA Astrophysics Data System (ADS)

Vansteenberge, S.; Van Opdenbosch, J.; Van Rampelbergh, M.; Verheyden, S.; Keppens, E.; Cheng, H.; Edwards, R. L.; Claeys, P. F.

2015-12-01

The Proserpine stalagmite is a 2 m large, tabular-shaped speleothem located in the Han-sur-Lesse cave in Belgium. The speleothem formed over the last 1000 years and is still growing. High-accuracy U/Th datings have indicated exceptionally high growth-rates of up to 2 mm per year. This, together with a well expressed annual layering, makes the Proserpine stalagmite an ideal candidate for high-resolution paleoclimate reconstructions of the last millennium. Previous work, including over 10 years of cave monitoring, has already learned us how short-term, i.e. decadal to seasonal, climate variations are incorporated within speleothem calcite from the Han-sur-Lesse cave system. It has been shown that δ18O and δ13C stable isotopes and trace element proxies of recently formed calcite reflect seasonal variations in temperature and precipitation of the near-cave environment (Verheyden et al, 2008; Van Rampelbergh et al., 2014). Now, this knowledge was used to infer local climate parameters further back in time to the period of +/- 1620-1630 CE, corresponding to one of the cold peaks within the Little Ice Age. Speleothem calcite was sampled at sub-annual resolution, with approximately 11 samples per year, for stable isotope analysis. LA-ICP-MS and µXRF analyses resulted in time series of trace elements. Preliminary results indicate a well expressed seasonal signal in δ13C and trace element composition but a multi-annual to decadal trend in δ18O. This combined proxy study eventually enables comparison of the expression of seasonality and longer term climate variations between a Little Ice Age cold peak and Present Day. References: Verheyden, S. et al., 2008, Monitoring climatological, hydrological and geochemical parameters in the Père Noël cave (Belgium): implication for the interpretation of speleothem isotopic and geochemical time-series. International Journal of Speleology, 37(3), 221-234. Van Rampelbergh, M. et al., 2014, Seasonal variations recorded in cave monitoring results and a 10-year monthly resolved speleothem δ13C and δ18O record from the Han-sur-Lesse cave, Belgium. Climate of the Past, 10, 1-15, 2014.
Geochemistry of speleothems affected by aragonite to calcite recrystallization - Potential inheritance from the precursor mineral

NASA Astrophysics Data System (ADS)

Domínguez-Villar, David; Krklec, Kristina; Pelicon, Primož; Fairchild, Ian J.; Cheng, Hai; Edwards, Lawrence R.

2017-03-01

Formerly aragonite speleothems recrystallized to calcite result from solutions subsaturated in aragonite and supersaturated in calcite that infiltrate into the speleothem through the interconnected porosity. In most cases, the crystal replacement takes place through a thin solution film. This diagenetic process can occur under open or semi-closed geochemical conditions. Thus, secondary calcite crystals record the composition of the fluid at the time of diagenesis affected by calcite partition coefficients and fractionation factors (open system) or partly inherit the composition of the primary aragonite (semi-closed system). So, whether or not recrystallized aragonite speleothems can record reliable geochemical signals from the time of speleothem primary deposition still is an open debate. We studied a stalagmite from Eagle Cave (Spain) predominantly composed of secondary calcite that replaced aragonite, although a core of primary aragonite extending 45 mm along the growth direction was preserved at the base of the sample. We obtained Mg and Sr compositional maps, paired U-Th dating and δ18O and δ13C profiles across the diagenetic front. Additionally, two parallel isotope records were obtained along the speleothem growth direction in the aragonite and calcite sectors. Our results support that recrystallization of this speleothem took place in open system conditions for δ18O, δ13C, Mg and Sr, but in semi-closed system conditions for U and Th. The recrystallization of this sample took place during one or several events, likely after the Younger Dryas as a result of climate change influencing drip water composition. Based on compositional zoned patterns, we suggest that the advance of diagenetic fronts in this speleothem had an average rate of 50 ± 45 μm/yr. Such recrystallization rate can transform any aragonite speleothem into calcite within a few centuries. We suggest that the volume of water interacting with the speleothem at the time of recrystallization is of critical importance for inheritance of different elements. The volume of solution is controlled by (1) the discharge of water passing through the sample and (2) the lapse time between aragonite dissolution and calcite precipitation. Hydrology and hydrochemistry of the interacting solution, together with the mineralogy and texture of the speleothem are the essential controls for the diagenesis of the speleothem. Recrystallization of aragonite speleothems does not follow stratigraphical levels of the sample but occurs along sites with preferential flow paths in any sector of the speleothem. In these cases the relationship between age and distance from base is not preserved. However, alternation of periods of recrystallization with periods of aragonite precipitation causing speleothem accretion can result in recrystallized speleothems with coherent distance from the base-age relationship. Thus, early diagenesis of speleothems affected by seasonal or inter-annual oscillation of drip waters supersaturated and subsaturated in aragonite may provide best-scenario conditions for dating and preservation of paleoenvironmental records along recrystallized speleothems. However, even in this scenario, the variable discharge and the diagenetic rate control the geochemical inheritance from the primary aragonite crystals.
Speleothem chronology with sub-annual resolution in a near-entrance cave setting using oxygen isotope and trace element records

NASA Astrophysics Data System (ADS)

Carlson, P. E.; Miller, N. R.; Banner, J.; Breecker, D.

2016-12-01

Speleothems that grow in well-ventilated zones of caves are typically avoided when selecting specimens for paleoclimate reconstruction, due to concerns about evaporation and kinetic isotope effects. Near-entrance cave environments are characterized by near-ambient CO2 concentrations year-round and are influenced by surface temperature fluctuations. At Westcave Preserve (Westcave), a shallow, well-ventilated cave in central Texas, we have found seasonal temperature differences recorded in both the oxygen isotope and trace element compositions of speleothem calcite. The seasonal nature of these records has been confirmed by monitoring the chemical composition of drip water and substrate calcite since 2009 (Feng et al., 2014; Casteel and Banner, 2015). We present an ultrahigh-resolution (weekly to monthly) record of δ18O, Mg, Sr, and Ba in Westcave stalagmite WC-3, as well as monthly measurements of drip water geochemistry. We find drip water δ18O and [Mg] are essentially invariant, while seasonal variations in stalagmite calcite δ18O and Mg compositions are in good agreement with predicted temperature-dependent fractionation between water and calcite. Both drip water and speleothem calcite Sr and Ba vary seasonally, which we hypothesize is due to seasonal changes in moisture conditions in the epikarst. We use each of these annual geochemical cycles as independent chronological controls in order to develop a single age model for the stalagmite. These independent chronological counts are consistent with each other, and with 14C bomb-peak and U-series evidence. We argue that the potential for this kind of multi-proxy, seasonally-resolved dating in near-entrance stalagmites makes them especially valuable paleoclimate archives that should not be ignored in speleothem studies.
Cova del Rinoceront (Castelldefels, Barcelona): a terrestrial record for the Last Interglacial period (MIS 5) in the Mediterranean coast of the Iberian Peninsula

NASA Astrophysics Data System (ADS)

Daura, J.; Sanz, M.; Julià, R.; García-Fernández, D.; Fornós, J. J.; Vaquero, M.; Allué, E.; López-García, J. M.; Blain, H. A.; Ortiz, J. E.; Torres, T.; Albert, R. M.; Rodríguez-Cintas, À.; Sánchez-Marco, A.; Cerdeño, E.; Skinner, A. R.; Asmeron, Y.; Polyak, V. J.; Garcés, M.; Arnold, L. J.; Demuro, M.; Pike, A. W. G.; Euba, I.; Rodríguez, R. F.; Yagüe, A. S.; Villaescusa, L.; Gómez, S.; Rubio, A.; Pedro, M.; Fullola, J. M.; Zilhão, J.

2015-04-01

The Cova del Rinoceront, a site in NE Iberia, contains a thick sedimentary fill preserving a faunal archive from the penultimate glacial and the the last interglacial periods. Layers I to III have been dated to between 74 and 147 ka, coinciding with MIS 5a to 5e, a period poorly represented in the Mediterranean terrestrial record. The results from Cova del Rinoceront are of broader interest for the reconstruction of ecological dynamics during warm stages and the understanding of the evolution and geographical variation of several taxa. The palaeoecological evidence suggests a landscape dominated by mixed wooded vegetation with mild climatic conditions, slightly more humid than today. Several vertebrate taxa, including Haploidoceros mediterraneus, Stephanorhinus hundsheimensis and Glis glis, are documented for the first time in the early Upper Pleistocene of Europe, showing that these species persisted across the region for longer than previously thought. In addition, the recovery of a small lithic assemblage indicates human presence in the surroundings of the site. The 11 m-thick stratigraphic section also provides an ideal setting in which to compare several geochronological methods. U-Th dating of the flowstones that cap the deposit, of speleothems formed along the cave walls, and of speleothems buried by the deposit at different elevations provides minimum and maximum ages of 74 and 175 ka, respectively, for the accumulation. The ages obtained by luminescence, electron spin resonance (ESR), amino acid racemisation (AAR), palaeomagnetism and U-series dating of bone are in good agreement with each other and are stratigraphically consistent. This well-dated faunal succession presents a unique opportunity to assess changes in the Pleistocene fauna of the Mediterranean coast over an interval of more than 100 ka.
Luminescent microbanding in speleothems: High-resolution chronology and paleoclimate

NASA Astrophysics Data System (ADS)

Shopov, Y. Y.; Ford, D. C.; Schwarcz, H. P.

1994-05-01

When illuminated by ultraviolet light, many calcite speleothems (stalagmites, stalactites, flowstones) display luminescence caused by the presence of organic (humic) substances occluded in the calcite. The amplitude of luminescence varies in a banded pattern parallel to growth layering. Through 14C and thermal ionization mass spectrometry uranium-series dating, we show that cyclical oscillations in the luminescence have periodicities ranging from a few days to ≥105 yr. A well-defined annual cycle is present in many vadose-zone speleothems and can be used to define the chronology of short-term events. This cycle is probably a response to hydrological events in the recharge to the cave. Longer term oscillations are inferred to be controlled by climate, through its effect on organic activity in the overlying soil.
An 80 kyr-long continuous speleothem record from Dim Cave, SW Turkey with paleoclimatic implications for the Eastern Mediterranean

PubMed Central

Ünal-İmer, Ezgi; Shulmeister, James; Zhao, Jian-Xin; Tonguç Uysal, I.; Feng, Yue-Xing; Duc Nguyen, Ai; Yüce, Galip

2015-01-01

Speleothem-based stable isotope records are valuable in sub-humid and semi-arid settings where many other terrestrial climate proxies are fragmentary. The Eastern Mediterranean is one such region. Here we present an 80-kyr-long precisely-dated (by U-series) and high-resolution oxygen (δ18O) and carbon (δ13C) records from Dim Cave (~36°N) in SW Turkey. The glacial-interglacial δ18O variations in the Dim Cave speleothem are best explained in terms of changes in the trajectories of winter westerly air masses. These are along a northerly (European) track (isotopically less depleted) during the early last glaciation but are gradually depressed southward closer to the modern westerly track along the North African coast (more depleted) after c.50 kyr and remain in the southern track through the Last Glacial Maximum. The southward displacement of the westerly track reflects growth of the Fennoscandian ice sheet and its impact on westerly wind fields. Changes in δ13C are interpreted as reflecting soil organic matter composition and/or thickness. δ13C values are significantly more negative in interglacials reflecting active carbonic acid production in the soil and less negative in glacial times reflecting carbonate rock values. Several Heinrich events are recorded in the Dim record indicating intensification of westerly flow across this part of the EM. PMID:26337921
The paleomagnetism of clastic and precipitate deposits in limestone and dolomite caves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Latham, A.G.; Ford, D.C.

1991-03-01

Clastic sediments and calcite precipitates (stalagmites, flowstones, etc.) are abundant in modern limestone caves and normally are the dominant infillings in buried (paleokarst) caves. Clastic sediment fillings are chiefly of fluviatile or local breakdown origin, but lacustrine, colluvial, eolian, and glacial deposits are known. Paleomagnetism has been studied in the fluviatile and lacustrine types: (1) reversal stratigraphy aids dating of geomorphic and paleoclimatic events in the late Pliocene/Pleistocene; (2) fine magnetostratigraphy has yielded estimates of the westward drift. Calcite precipitates (speleothems) may display natural remanent magnetism of either depositional (DRM) or chemical (CRM) origin. NRMs of modern speleothems are primary,more » not diagenetic; CRMs are invariably associated with the degradation of surface organic matter. (1) Coarse reversal stratigraphy dates geomorphic, etc., events and erosion rates. (2) Fine stratigraphy combined with {sup 230}Th:{sup 234}U dating gives high precision estimates of secular variation, westward drift, and rate of change of geomagnetic anomalies in upper Pleistocene and Holocene deposits. Magnetostratigraphy of paleokarst speleothem fillings associated with hydrocarbons in Ordovician limestones suggest a Permian age for the karstification. Potential applications of magnetostratigraphy to paleokarst deposits of many different scales are considerable.« less
Tales from the South (and West) Pacific in the Common Era: A Climate Proxy Perspective (Invited)

NASA Astrophysics Data System (ADS)

Quinn, T. M.; Taylor, F. W.; Partin, J. W.; Maupin, C. R.; Hereid, K. A.; Gorman, M. K.

2010-12-01

The southwest Pacific is a major source of tropical climate variability through heat and moisture exchanges associated with the Western Pacific Warm Pool (WPWP) and the South Pacific Convergence Zone (SPCZ). These variations are especially significant at the annual, interannual (El Niño-Southern Oscillation, ENSO), and multi-decadal timescales. Gridded SST data products are available in the pre-satellite era in this region for the past ~130 years, although data density is a significant issue for the older half of these records. Time series of salinity (SSS) and rainfall from this region are exceedingly rare. Thus, climate proxy records must be used to reconstruct SST, SSS, and rainfall variations in the Common Era (CE) in the tropical Pacific. The analytical laboratory for paleoclimate studies at UT has focused its research efforts into producing climate proxy time series from southwest tropical Pacific using modern and fossil corals, and speleothems. Our most recent results are summarized in this presentation, although much of this work is still in progress. Coral climate records have been generated from Sabine Bank, Vanuatu (16°S, 166°E) and Misima Island, Papua New Guinea (10.6°S, 152.8°E). The Vanuatu coral record of monthly resolved Sr/Ca variations extends back to the late 18th century. All strong ENSO warm phase events of the 20th century observed in the instrumental record are also observed in the coral record. We note that several ENSO warm phase events in the 19th century portion of the coral record are comparable in size to that recorded in response to the 1982/1983 and 1997/1998 events. The Misima coral record of monthly resolved δ18O and Sr/Ca variations spans the interval ~1414-1645 CE — the heart of the Little Ice Age. Amplitude modulation of interannual variability is observed in this LIA record, much like what is observed during the relatively quiescent period of 1920-1950 in the 20th century instrumental and proxy records of ENSO. However, the amplitude of individual ENSO warm phase events in the LIA record is reduced, relative to that of the 1941/1942 ENSO warm phase events observed in a near modern coral record from Misima. Speleothem climate records have been generated from Espirito Santo, Vanuatu (15.5°S, 167°E) and Guadalcanal, Solomon Islands (~9°S, 160°E). The Vanuatu record of δ18O variations is from a fast-growing speleothem (~1-3 mm/year), which yields a record of rainfall variability spanning ~1670-2005 CE, as dated by U-Th disequilibrium techniques. Interannual changes in speleothem δ18O appear to capture ENSO events and subsequent reorganizations of the SPCZ. The Vanuatu speleothem δ18O record also exhibits concentrations of variance on the decadal scale. The Guadalcanal record of δ18O variations is also from a fast-growing speleothem (~1-4 mm/year), which yields a record of rainfall variability spanning ~1650-2010 CE, as dated by U-Th disequilibrium techniques. The δ18O records from both of these stalagmites provide evidence for changes in convection in the equatorial WPWP region of the SPCZ: the rising limb of the Pacific Walker Circulation.
Connecting the U-Th and U-Pb Chronometers: New Algorithms and Applications

NASA Astrophysics Data System (ADS)

McLean, N. M.; Smith, C. J. M.; Roberts, N. M. W.; Richards, D. A.

2016-12-01

The U-Th and U-Pb geochronometers are important clocks for separate intervals of the geologic timescale. U-Th dates exploit disequilibrium in the 238U intermediate daughter isotopes 234U and 230Th, and are often used to date corals and speleothems that are zero age through 800 ka. The U-Pb system relies on secular equilibrium decay of 238U to 206Pb and 235U to 207Pb over longer timescales, and can be used to date samples from <1 Ma to 4.5 Ga. Disequilibrium plays a role in young U-Pb dates, but only as a nuisance correction. Both chronometers can produce dates with uncertainties <0.1% near the center of their applicable age ranges, but become less precise at their intersection, when the 238U decay chain approaches secular equilibrium and there has been little time for ingrowth of radiogenic Pb. However, if measurements or assumptions about both chronometers can be made, then they can be combined into a single, more informed date. Coupling the datasets can improve their precision and accuracy and help interrogate the assumptions that underpin each. Working with this data is difficult for two reasons. The Bateman equations are long and cumbersome for U decay chains that include 238U, 234U, 230Th, 226Ra, 206Pb and 235U, 231Pa, and 207Pb. Also, Pb measurements often comprise varying amounts of radiogenic Pb from locally heterogeneous U concentrations mixed with varying amounts of common Pb. At present there is no established, flexible computational framework to combine information from measurements and/or assumptions of these parameters, and no way to visualize and interpret the results. We present new algorithms to quickly and accurately solve the system of differential equations defined by both of the uranium decay chains and the linear regression through the U-Pb isochron. The results are illustrated on a new concordia diagram, where the concordia curve is determined by measured and/or assumed U-series disequilibrium and can have unfamiliar topologies. We demonstrate this approach using data collected by solution and laser ablation ICPMS on carbonates with measurable 230Th and 234U disequilibrium, measurable disequilibrium for only 234U, and when only assumptions can be made about initial U-series disequilibrium. Potential applications include refining chronologies at ca. 1 Ma, an important period in Earth history.
Cosmogenic 36Cl in karst waters: Quantifying contributions from atmospheric and bedrock sources

NASA Astrophysics Data System (ADS)

Johnston, V. E.; McDermott, F.

2009-12-01

Improved reconstructions of cosmogenic isotope production through time are crucial to understand past solar variability. As a preliminary step to derive atmospheric 36Cl/Cl solar proxy time-series from speleothems, we quantify 36Cl sources in cave dripwaters. Atmospheric 36Cl fallout rates are a potential proxy for solar output; however extraneous 36Cl derived from in-situ production in cave host-rocks could complicate the solar signal. Results from numerical modeling and preliminary geochemical data presented here show that the atmospheric 36Cl source dominates in many, but not all cave dripwaters. At favorable low elevation, mid-latitude sites, 36Cl based speleothem solar irradiance reconstructions could extend back to 500 ka, with a possible centennial scale temporal resolution. This would represent a marginal improvement in resolution compared with existing polar ice core records, with the added advantages of a wider geographic range, independent U-series constrained chronology, and the potential for contemporaneous climate signals within the same speleothem material.
Speleothem stable isotope records for east-central Europe: resampling sedimentary proxy records to obtain evenly spaced time series with spectral guidance

NASA Astrophysics Data System (ADS)

Gábor Hatvani, István; Kern, Zoltán; Leél-Őssy, Szabolcs; Demény, Attila

2018-01-01

Uneven spacing is a common feature of sedimentary paleoclimate records, in many cases causing difficulties in the application of classical statistical and time series methods. Although special statistical tools do exist to assess unevenly spaced data directly, the transformation of such data into a temporally equidistant time series which may then be examined using commonly employed statistical tools remains, however, an unachieved goal. The present paper, therefore, introduces an approach to obtain evenly spaced time series (using cubic spline fitting) from unevenly spaced speleothem records with the application of a spectral guidance to avoid the spectral bias caused by interpolation and retain the original spectral characteristics of the data. The methodology was applied to stable carbon and oxygen isotope records derived from two stalagmites from the Baradla Cave (NE Hungary) dating back to the late 18th century. To show the benefit of the equally spaced records to climate studies, their coherence with climate parameters is explored using wavelet transform coherence and discussed. The obtained equally spaced time series are available at https://doi.org/10.1594/PANGAEA.875917.
A 3000-year annual-resolution record of the North Atlantic Oscillation

NASA Astrophysics Data System (ADS)

Kelly, B. F.; Mariethoz, G.; Hellstrom, J.; Baker, A.

2013-12-01

The North Atlantic Oscillation provides an index of North Atlantic climate variability. The 947-yr long annual resolution record of the North Atlantic Oscillation (NAO) of Trouet et al. (2009, Science, 324, 78-81), the NAO Morocco-Scotland index, combined tree ring and stalagmite data, the latter a single stalagmite growth rate archive from NW Scotland. Trouet et al (2009) noted the unusual persistence of the positive phase of the NAO during the Medieval Climate Anomaly (MCA; 1050-1400AD). In order to better assess the uniqueness of the persistently positive NAO in the MCA, we extend the speleothem portion of the proxy NAO record with a composite of five stalagmites from the same cave system. We present the first-ever composite speleothem growth rate record. Using a combination of lamina counting, U-Th dating, and correlation between growth rate series, we build a continuous, annual-resolution, annually laminated, stalagmite growth rates series for the last 3000 years. We use geostatistical and stochastic approaches appropriate to stalagmite growth rate time series to characterise uncertainty in the stalagmite series and to screen them for periods of relative climate sensitivity vs. periods where there is hydrologically introduced, non-climatic variability. We produce the longest annual-resolution annual lamina record of the NAO for the last 3000 years. The screened stalagmite series is compared to instrumental and proxy records of the NAO. Spectral and wavelet analysis demonstrates that the series contains significant decadal to centennial scale periodicity throughout the record. We demonstrate that the persistently positive NAO during the MCA (1080-1460 CE) is remarkable within the last 3000 years. Two other phases of persistent, positive NAO, occur at 290-550 CE and 660-530 BCE, in agreement with the lower resolution, 5,200-yr Greenland lake sediment NAO proxy (Olsen et al, 2012, Nature Geoscience, 5, 808-812).
Major earthquakes recorded by Speleothems in Midwestern U.S. caves

USGS Publications Warehouse

Panno, S.V.; Lundstrom, C.C.; Hackley, Keith C.; Curry, B. Brandon; Fouke, B.W.; Zhang, Z.

2009-01-01

Historic earthquakes generated by the New Madrid seismic zone represent some of the largest recorded in the United States, yet prehistoric events are recognized only through deformation in late-Wisconsin to Holocene-age, near surface sediments (liquefaction, monoclinal folding, and changes in river meanders). In this article, we show that speleothems in caves of southwestern Illinois and southeastern Missouri may constitute a previously unrecognized recorder of large earthquakes in the U.S. midcontinent region. The timing of the initiation and regrowth of stalagmites in southwestern Illinois and southeastern Missouri caves is consistent with the historic and prehistoric record of several known seismic events in the U.S. midcontinent region. We conclude that dating the initiation of original stalagmite growth and later postearthquake rejuvenation constitutes a new paleoseismic method that has the potential for being applied to any region around the world in the vicinity of major seismic zones where caves exist. Use of this technique could expand the geographical distribution of paleoseimic data, document prehistoric earthquakes, and help improve interpretations of paleoearthquakes.
Reconstructing Past Climate Using Speleothems from Cueva de las Perlas, Northern Spain.

NASA Astrophysics Data System (ADS)

Deeprose, Laura; Wynn, Peter; Barker, Philip; Leng, Melanie; Noble, Stephen; Sahy, Diana

2017-04-01

Abrupt and severe oscillations in climate, termed Heinrich events, are documented in North Atlantic Ocean sediments between 85,000 - 30,000 years ago [1]. This time period also encapsulates the Neanderthal demise, a key transition in human evolution which is proposed to be driven at least in part by changing climate. The Iberian Peninsula represents the last known refuge of the Neanderthals. However, due to a scarcity of palaeoclimate archives from Iberia during this time period, the expression of these cooling events in the terrestrial realm remains poorly understood. As the extinction of the Neanderthal population seems to broadly coincide with the timing of Heinrich event 4, it is therefore critical to understand the terrestrial expression of these changes in ocean circulation. Speleothems from Cueva de las Perlas, northern Spain are being used to reconstruct past climatic and environmental change spanning this period of Neanderthal demise. U-Th dating has identified three suitable speleothems, allowing a precise chronology to be established. Through contemporary monitoring, the oxygen isotope composition of speleothem carbonate has been interpreted to carry a primary environmental signal of rainfall amount. The oxygen isotope values indicate a drying climate across the period of the Neanderthal population demise. Additionally, the carbon isotope record, interpreted to represent shifts in vegetation dynamics, indicates an overall drying during the studied time period. A high degree of climatic instability is superimposed on the overall drying trend, suggesting the prevailing climatic conditions could have been adding environmental pressure to an already marginalised hominin population. Further U-Th dating and high-resolution stable isotope analysis aims to constrain the magnitude and timing of these events. [1] Bond, G., Broecker, W., Johnsen, S.J., McManus, J., Labeyrie, L., Jouzel, J., Bonani, G., 1993. Correlations between North Atlantic sediments and Greenland ice. Nature 365, 143-147.

The speleothem record from Sicily, an important palaeoclimate testimony in the heart of the Mediterranean: overview of current research

NASA Astrophysics Data System (ADS)

Deininger, Michael; Vattano, Marco; McDermott, Frank; Frisia, Silvia; Borsato, Andrea; Frank, Norbert; Spötl, Christoph; Scholz, Denis; Di Maggio, Cipriano; Madonia, Giuliana

2017-04-01

Sicily is located in the heart of the Mediterranean and takes a strategic position between the western and eastern Mediterranean as well as between northern Africa and continental Europe. It is a place of a diverse and great cultural heritage that goes back many thousands of years; it had been colonised by Phoenicians, Carthaginians, Greeks and Romans in Ancient times and served as a trading post and granary - the latter particularly for the Romans. Climate change scenarios studies suggest that Mediterranean ecosystems could change into deserts as a consequence of shifting temperature and precipitation patterns unparalleled in the Holocene period (Guiot and Cramer, 2016). It is, therefore, essential to shed light on past precipitation changes to gain knowledge on the timing, dynamics and causes of these changes by making use of natural environmental archives (such as speleothems). This information is not only important for palaeoclimate data-model comparisons but can also give archaeologists a wealth of information when studying cultural transformations. Speleothems are valuable natural archives of past climatic and environmental conditions on the continents. Major strengths include their suitability for accurate U-series age determinations and their preservation of multiple quasi-independent climate proxies - that can be linked to precipitation changes. Hence, speleothems proxy time series from the Mediterranean can be regarded as an important testimony of past environmental and climate changes (including precipitation) that allow to provide answers to the aforementioned questions. Here we present first result of ongoing speleothem research on Sicily, with focuses on Pietrazzi cave (Grotta dei Pietrazzi) located west of Palermo. It developed in limestone (limestone consisting of bioclastic packstone/wackestones, fore reef coral rudstones (calcirudite) and calcarenites.) of the Calcare di Piano Battaglia Formation. Pietrazzi cave is more than 600 m in length and has a depth of roughly 90m. We will show preliminary analysis of three stalagmites (PZ-1, PZ-2, PZ-3) including U-Th age models and stable oxygen and carbon isotope data of PZ-1. Guiot, J., and Cramer, W.: Climate change: The 2015 Paris Agreement thresholds and Mediterranean basin ecosystems, Science, 354, 465, 2016.
Holocene Hydrologic Variability of the Eastern Caribbean Derived from Speleothems of the Recent Two Millennia: a Progress Report

NASA Astrophysics Data System (ADS)

Sperberg, F.; Miller, T.; Winter, A.; Scholz, D.; Estrella, J.

2013-12-01

To improve models of future climate variability, knowledge of past temperature and precipitation is essential, especially in the Neotropics where proxies have been historically limited to sediment cores. Speleothems offer high resolution dating using uranium-series techniques, and in combination with stable carbon and oxygen isotopes can function as effective archives of terrestrial changes in precipitation, vegetation and mean annual temperature. Speleothem archives are relatively well documented throughout Europe and Asia as well as Central and South America to the extent that replication is possible among archives at nearby locations. This study aims to reconstruct hydrologic variability over the recent two millennia using two stalagmites each from Venezuela and Puerto Rico. The Venezuelan stalagmites were collected from Cueva Camillo within a Cariaco Basin terrestrial catchment. Preliminary analysis of Venezuelan stalagmite VECA1a stable oxygen isotopes over the last 600 years shows increasing precipitation from ~300 - 588 yBP and comparison with Cariaco Basin titanium concentrations and planktonic foraminifera oxygen isotopes show a weak correlation. Spectral analysis reveals solar influence from ~ 330 - 400 yBP and also appears to be influenced by the Atlantic Multidecadal Oscillation (AMO) from ~ 350 - 400 yBP and from ~550 - 588 yBP where the record terminates at a hiatus. Further examination of the geographic climate applicability of this locale's data will be tested through comparison with these terrestrial proxies, by analyzing annual, centennial, and millennial-scale variation of 18O in speleothems. The Puerto Rican stalagmites will be compared via dating and stable isotope analysis with Venezuelan stalagmites, as well as the local instrumental record. Cave monitoring of parameters at Cueva Dos Ojos (Puerto Rico) include temperature, relative humidity, spot pCO2 measurements, drip rate and drip water chemistry. Monitoring initiated in March of 2013 has already detected seasonality, and is expected to provide insight to the isotopic signature of speleothems collected there.
Changes in seasonal climate patterns from 34-4 ka in a Soreq Cave (Israel) speleothem: Sub-annual resolution by ion microprobe and CLFM

NASA Astrophysics Data System (ADS)

Orland, I. J.; Bar-Matthews, M.; Kita, N.; Ayalon, A.; Valley, J. W.

2009-12-01

Speleothems provide an important proxy-record of paleoclimate. Isotopic data from calcite-dominated cave formations have been used to identify changes in annual rainfall, monsoon strength, telecommunication of Northern Hemisphere climate aberrations, changes in vegetation cover, and other region-specific paleoclimate time-series over annual to millennial timescales. As more research is devoted to understanding abrupt climate change events, there is a need to develop high-temporal-resolution records from continental regions. However, in most isotopic studies, seasonality information is lost due to technical limitations. This study focuses on a speleothem from the semi-arid Eastern Mediterranean region (Soreq Cave, Israel) where prior research shows that conventional drill-sampling methods permit a temporal resolution of ~10-50 years in speleothem paleoclimate records. The WiscSIMS lab has developed analytical protocols for ion microprobe analysis that yield a precision of ~0.3‰ (2 s.d.) in δ18O from 10 μm-diameter spots, which permit multiple analyses/year in many speleothems. Orland et al. (2009, Quat. Res.) establish the methodology for the current study by identifying seasonal variability using a combination of confocal laser fluorescent microscopy (CLFM) and ion microprobe analysis in a younger (~2-1 ka) Soreq speleothem that has a consistent bright-grading-to-dark fluorescence pattern within each annual band. Further, Orland et al. define a quantitative measure of seasonality, Δ18O, that measures the difference in δ18O between bright and dark fluorescent portions of individual annual growth bands [Δ18O = δ18Odark - δ18Obright]. Smaller values of Δ18O are interpreted to be caused by dry years. The current study employs the aforementioned methods to examine seasonality trends in a sample that covers a much longer time period. We report δ18O from >1000 spots across a radial traverse of Soreq Cave sample 2N matched to imaging of annual growth bands by CLFM. This record, which extends from 34-4 ka, based on 27 new U-Th dates from the Geological Survey of Israel, preserves a time-series of δ18O across multiple significant climate changes including the last glacial termination, the onset/termination of the YD, and multiple abrupt regional events. As in the younger sample from Soreq, CLFM of the Holocene portion of sample 2N reveals concentric, annual growth bands in bright-grading-to-dark fluorescent couplets. In the pre-Holocene portion of 2N, however, the pattern of fluorescence banding is consistently reversed (i.e. dark-grading-to-bright). Furthermore, the magnitude of Δ18O changes through time. The prominent change in the CLFM and Δ18O record for sample 2N suggests a shift in seasonality in the Eastern Mediterranean before the termination of the YD; variation in seasonal rainfall and/or surface vegetation may have contributed to the observed change.
Identifying regional moisture source during the last deglaciation through analysis of central Texas speleothems

NASA Astrophysics Data System (ADS)

James, C.; Charlton, T.; Banner, J.; Koleszar, A. M.; James, E. W.; Breecker, D.; Miller, N. R.; Edwards, R. L.

2016-12-01

Precipitation in the drought-prone Southwest US is principally sourced from the Gulf of Mexico (GoM) and/or Pacific Ocean, each with distinctive δ18O compositions. Temporal changes in moisture source in this region have been reconstructed from speleothem proxies for the last deglaciation ( 19 - 11 ka). In this study we focus on how moisture sources in Texas speleothem records varied in response to abrupt deglacial warming/cooling events, namely the Bølling-Allerod (BA) interstadial (14.7-14.1 ka) and the Younger Dryas stadial (12.9-11.5 ka). A recent speleothem oxygen isotope record (CWN-4) in a stalagmite from Cave Without A Name near Boerne, Texas, suggests that both the magnitude and timing of changes in δ18O values during the deglaciation closely match δ18O values from a seawater proxy record based on GoM foraminifera (Feng et al., 2014; Flower et al., 2004). A distinct negative δ18O excursion of -3‰ is observed in both records at the onset of the BA, with a subsequent 3‰ increase occurring at the end of the BA. Based on these similarities, regional moisture was hypothesized to be predominantly sourced from the GoM. In order to test the hypothesis that the CWN-4 record captures a regional climate signal, as opposed to recording local variations in in-cave processes, we analyze multiple central Texas speleothem δ18O records. We present oxygen isotope records of a flowstone (IC-2) from a cave 130 km WSW of CWN and a stalagmite (McN-1) from a cave 140 km NE of CWN, with both records spanning the onset of the deglaciation through the Holocene. The IC-2 δ18O record is consistent with that of CWN-4, however, the age model relies on several dates with high uncertainties related to elevated concentrations of detritus containing common Th. The McN-1 record is anticipated to have a more robust age model as it appears to contain less detrital material based on low 232Th concentrations (< 0.009 ppb) in the growth layers that have been selected for U-series analysis. Preliminary δ18O values for the pre-BA period of McN-1 cover a similar range of δ18O values (-4.5 to -2.5‰) compared with the pre-BA portions of the CWN-4 and IC-2 records. These results are consistent with the regional climate hypothesis, which will be tested further by building a complete, high-resolution oxygen isotope time series for McN-1.
A geochronological approach for cave evolution in the Cantabrian Coast (Pindal Cave, NW Spain)

USGS Publications Warehouse

Jimenez-Sanchez, M.; Bischoff, J.L.; Stoll, H.; Aranburu, A.

2006-01-01

Some of the oldest speleothems in the North Cantabrian Coast (Spain) are reported for the first time in this work. Pindal Cave is developed at 24 m above sea level, in a karstic massif reaching its highest surface in a marine terrace (rasa) located at 50-64 m above the present sea level. Several phases of evolution were previously recognized into the cave, including block collapse of the roof, episodic flooding and detrital sedimentation, and chemical precipitation of at least four speleothem generations over both alluvial and collapse deposits. Three of these speleothem generations have been dated by U/Th. The first generation yielded ages from 124,2 ?? 1, 5 ka BP to 73,1 ?? 0,9 ka BP, giving a minimum age for the main detritic sediments in the cave. The second one is not dated. The third generation gives an age of 3,71 ?? 0,4 ka BP (mathematically corrected to 2.7 ?? 0.5 ka BP), while for the youngest generation, with actively growing stalagmites in the cave, basal ages of 200 years BP are estimated by counting annual laminae. The data suggest a tentative maximum elevation rate close to 0, 2 mm/yr for the Cantabrian Margin in this area, although further chronological studies will be needed to check this hypothesis. ?? 2006 Gebru??der Borntraeger.
Speleothem records of changes in the South American Summer Monsoon during MIS stages 5 and 6

NASA Astrophysics Data System (ADS)

Burns, S. J.; Kanner, L.; Cheng, H.; Edwards, R.

2011-12-01

Little information exists about the behavior of the South American Summer Monsoon prior to the Last Glacial Period. Speleothems from the Peruvian Altiplano are one possible archive of SASM intensity because oxygen isotopes of rainfall on the Altiplano are primarily controlled by the intensity of rainfall in upstream moisture source region, the Amazon Basin. Here, we present results from a two speleothems collected from Gruta de Huagapo, a cave in the central Peruvian Altiplano (12°S, 76°W, ~3800m elevation). The samples grew from approximately 115-125 ky BP and from 136-168 ky BP, spanning time periods equivalent to much of MIS stage 5e and the transition into MIS 5d and MIS 6. Chronologies were determined by U-Th dating techniques and the dates are in stratigraphic with analytical errors < 0.4%. 100 preliminary δ18O values were micromilled from each sample along the growth axis. Oxygen isotopic values of the younger sample, stalagmite P10-H1, range from -12.5% to -16.5%. The overall trend in isotopic values generally parallels summer insolation, with more depleted values associated with greater insolation. The most enriched values, between -12.5% and -13.5% occur from 121-125 ky BP, with an abrupt transition to more depleted values at 121 ky BP. The values plateau at about -15% until 117 ky BP, then abruptly decrease again to around -16 % for the rest of the record. The enriched values during the middle and latter parts of MIS 5e suggest a weakened monsoon during that time and coincide with observed low lake levels at Lake Titicaca (Fritz et al, 2007). At present we have isotopic data from only the youngest 10 ky of the older sample. The values are generally more depleted, with most between -16% and -17%, suggesting an intensified SASM during MIS 6 as compared to 5e. A rapid increase in δ18O occurs at ~136 ky BP. Overall the trends in the data parallel major changes in δD from EPICA, but appear to lead the Antarctic time series by ~2 ky.
A High-Resolution Speleothem Record From Florida of Atmospheric Teleconnections Since 1,500 Years Ago

NASA Astrophysics Data System (ADS)

Polk, J. S.; van Beynen, P.; Asmerom, Y.

2008-12-01

Understanding atmospheric teleconnections between tropical, subtropical, and higher-latitude regions of the North Atlantic Ocean is necessary to better evaluate the anthropogenic contribution to climate change. Here, we present a precisely dated, high- resolution speleothem record of stable isotopes and trace elements from Florida spanning the last 1,500 years. By using a multi-proxy approach, the different climatic influences were deconvolved, including the NAO, ENSO, PDO, and ITCZ, which all can affect our region. Further comparison using time-series analysis between our data and other high-resolution records covering this same period reveal differing influences of these teleconnections on geographic regions. Our record shows both the influence of changing rainfall above the cave and the influence of sea surface temperatures on atmospheric convection caused by atmospheric-oceanic variability over time.
Caves in caves: Post depositional holes in stalagmites

NASA Astrophysics Data System (ADS)

Shtober Zisu, Nurit; Schwarcz, Henry P.; Chow, Tom; Konyer, Norman B.; Noseworthy, Michael D.

2010-05-01

Previous studies of speleothems for the purposes of isotopic analysis and U-series dating have resulted in preparation of stalagmites by sectioning longitudinally along the growth axis. We frequently observe holes in such sections, both along the growth axis, and laterally to it, ranging in size up to several mm in diameter. Our initial supposition was that these holes are produced during the growth of the stalagmite under constant dripping conditions, but it was found that two kinds of holes exist within the stalagmites. "Axial holes" were formed syngenetically as is shown by the depression of growth layers into the holes and the persistence of the axial hole over many cm of the growth history. Some cut the active growth surface of the stalagmite. "Off-axis holes" are seen in many stalagmites (as well as stalactites); they cut discordantly through growth layers, and never terminate at a growth surface. They range in size from a few mm to several cm in maximum dimension, and may not be coaxially oriented. They are lined with micron-sized, randomly oriented calcite crystals and under which lies an organic-rich coating. We used CT (Computed Tomography) and MRI (Magnetic Resonance Imaging) scanning in order to locate holes, and to search for water trapped in these macro-inclusions. These methods, allow us to visualize the holes without destruction of the stalagmite, the holes and the surrounding calcite. To our best knowledge, the present paper is the first to combine CT and MRI methods in the study of fluid inclusions in rocks, or in visualizing the distribution of holes in speleothems. CT scans reveal abundant off-axis holes in some speleothems, while most display at least a few holes. MRI scans shows that, in uncut speleothems, these holes never contain water (although Genty et al. [2002] found water-filled holes in some stalagmites). Off-axis holes may be a result of bioerosion, possibly bacterial, followed by partial refilling of the hole with calcite which is prevented from growing epitaxially on the host calcite.
Environmental control of U concentration and 234U/238U in speleothems at subannual resolution

NASA Astrophysics Data System (ADS)

Hu, C.; Henderson, G. M.

2003-12-01

Trace element and isotope variability in speleothems encodes a range of information about the past environment, although its interpretation is often problematic. U concentration and isotopes have frequently been analysed in speleothems in order to provide chronology, but their use as environmental proxies in their own right has not been comprehensively investigated. In this study, we have investigated the environmental controls of U in a stalagmite from the Central Yangtze Valley in China. This stalagmite grew rapidly throughout the Holocone and contains visible annual layers about 300microns thick. Analysis of a portion of the stalagmite corresponding to the 1970s by electron probe, LA-ICP-MS, and by physical subsampling indicate clear annual cycles in Sr/Ca, Mg/Ca, and Ba/Ca. The reasonably open cave structure and the correlation of Sr/Ca with Mg/Ca suggest that temperature exerts considerable control over these trace element variations. U/Ca also varies seasonally by up to 42 % and shows a clear anti-correlation with Mg/Ca (correlation coefficient -0.64). Based on the inverse relationship between U/Ca and temperature exhibited in other carbonates (e.g. corals) the speleothem U/Ca is suggested to be controlled primarily by temperature and may provide a paleo cave thermometer with less rainfall influence than Mg/Ca. Ongoing monitoring of the cave temperature and humidity will assess the robustness of this conclusion and the sensitivity of speleothem U/Ca to temperature. (234U/238U) in this stalagmite range from 1.733 to 1.872 during the Holocene. The U concentration is high enough (typically 0.48 ppm) and growth rate fast enough, that (234U/238U) can also be measured at a subannual resolution. The expected alpha-recoil control of excess 234U supply suggests that these measurements may provide a measure of the transit time of recharge waters to the stalagmite during the seasonal cycle. Such a proxy would enable deconvolution of temperature and recharge-rate control in trace element records from speleothems.
U-Th dating of carbonate crusts reveals Neandertal origin of Iberian cave art.

PubMed

Hoffmann, D L; Standish, C D; García-Diez, M; Pettitt, P B; Milton, J A; Zilhão, J; Alcolea-González, J J; Cantalejo-Duarte, P; Collado, H; de Balbín, R; Lorblanchet, M; Ramos-Muñoz, J; Weniger, G-Ch; Pike, A W G

2018-02-23

The extent and nature of symbolic behavior among Neandertals are obscure. Although evidence for Neandertal body ornamentation has been proposed, all cave painting has been attributed to modern humans. Here we present dating results for three sites in Spain that show that cave art emerged in Iberia substantially earlier than previously thought. Uranium-thorium (U-Th) dates on carbonate crusts overlying paintings provide minimum ages for a red linear motif in La Pasiega (Cantabria), a hand stencil in Maltravieso (Extremadura), and red-painted speleothems in Ardales (Andalucía). Collectively, these results show that cave art in Iberia is older than 64.8 thousand years (ka). This cave art is the earliest dated so far and predates, by at least 20 ka, the arrival of modern humans in Europe, which implies Neandertal authorship. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.
New Luminescence Ages for the Galería Complex Archaeological Site: Resolving Chronological Uncertainties on the Acheulean Record of the Sierra de Atapuerca, Northern Spain

PubMed Central

Demuro, Martina; Arnold, Lee J.; Parés, Josep M.; Pérez-González, Alfredo; Ortega, Ana I.; Arsuaga, Juan L.; Bermúdez de Castro, José M.; Carbonell, Eudald

2014-01-01

The archaeological karstic infill site of Galería Complex, located within the Atapuerca system (Spain), has produced a large faunal and archaeological record (Homo sp. aff. heidelbergensis fossils and Mode II lithic artefacts) belonging to the Middle Pleistocene. Extended-range luminescence dating techniques, namely post-infrared infrared stimulated luminescence (pIR-IR) dating of K-feldspars and thermally transferred optically stimulated luminescence (TT-OSL) dating of individual quartz grains, were applied to fossil-bearing sediments at Galería. The luminescence dating results are in good agreement with published chronologies derived using alternative radiometric dating methods (i.e., ESR and U-series dating of bracketing speleothems and combined ESR/U-series dating of herbivore teeth), as well as biochronology and palaeoenvironmental reconstructions inferred from proxy records (e.g., pollen data). For the majority of samples dated, however, the new luminescence ages are significantly (∼50%) younger than previously published polymineral thermoluminescence (TL) chronologies, suggesting that the latter may have overestimated the true burial age of the Galería deposits. The luminescence ages obtained indicate that the top of the basal sterile sands (GIb) at Galería have an age of up to ∼370 thousand years (ka), while the lowermost sub-unit containing Mode II Acheulean lithics (base of unit GIIa) was deposited during MIS 9 (mean age = 313±14 ka; n = 4). The overlying units GIIb-GIV, which contain the richest archaeopalaeontological remains, were deposited during late MIS 8 or early MIS 7 (∼240 ka). Galería Complex may be correlative with other Middle Pleistocene sites from Atapuerca, such as Gran Dolina level TD10 and unit TE19 from Sima del Elefante, but the lowermost archaeological horizons are ∼100 ka younger than the hominin-bearing clay breccias at the Sima de los Huesos site. Our results suggest that both pIR-IR and single-grain TT-OSL dating are suitable for resolving Middle Pleistocene chronologies for the Sierra de Atapuerca karstic infill sequences. PMID:25338076
New luminescence ages for the Galería Complex archaeological site: resolving chronological uncertainties on the acheulean record of the Sierra de Atapuerca, northern Spain.

PubMed

Demuro, Martina; Arnold, Lee J; Parés, Josep M; Pérez-González, Alfredo; Ortega, Ana I; Arsuaga, Juan L; Bermúdez de Castro, José M; Carbonell, Eudald

2014-01-01

The archaeological karstic infill site of Galería Complex, located within the Atapuerca system (Spain), has produced a large faunal and archaeological record (Homo sp. aff. heidelbergensis fossils and Mode II lithic artefacts) belonging to the Middle Pleistocene. Extended-range luminescence dating techniques, namely post-infrared infrared stimulated luminescence (pIR-IR) dating of K-feldspars and thermally transferred optically stimulated luminescence (TT-OSL) dating of individual quartz grains, were applied to fossil-bearing sediments at Galería. The luminescence dating results are in good agreement with published chronologies derived using alternative radiometric dating methods (i.e., ESR and U-series dating of bracketing speleothems and combined ESR/U-series dating of herbivore teeth), as well as biochronology and palaeoenvironmental reconstructions inferred from proxy records (e.g., pollen data). For the majority of samples dated, however, the new luminescence ages are significantly (∼50%) younger than previously published polymineral thermoluminescence (TL) chronologies, suggesting that the latter may have overestimated the true burial age of the Galería deposits. The luminescence ages obtained indicate that the top of the basal sterile sands (GIb) at Galería have an age of up to ∼370 thousand years (ka), while the lowermost sub-unit containing Mode II Acheulean lithics (base of unit GIIa) was deposited during MIS 9 (mean age = 313±14 ka; n = 4). The overlying units GIIb-GIV, which contain the richest archaeopalaeontological remains, were deposited during late MIS 8 or early MIS 7 (∼240 ka). Galería Complex may be correlative with other Middle Pleistocene sites from Atapuerca, such as Gran Dolina level TD10 and unit TE19 from Sima del Elefante, but the lowermost archaeological horizons are ∼100 ka younger than the hominin-bearing clay breccias at the Sima de los Huesos site. Our results suggest that both pIR-IR and single-grain TT-OSL dating are suitable for resolving Middle Pleistocene chronologies for the Sierra de Atapuerca karstic infill sequences.
Calibrating multiple isotopic proxies in a modern aragonite speleothem from northeast India

NASA Astrophysics Data System (ADS)

Ronay, E.; Oster, J. L.; Sharp, W. D.; Marks, N.; Erhardt, A.; Breitenbach, S. F. M.

2017-12-01

Uranium, strontium, and calcium isotope ratios in calcite speleothems are used as proxies for water-soil-rock interactions and prior calcite precipitation, and thus provide information about effective rainfall amount variations, primarily in semi-arid or highly seasonal regions. However, less is known about how these proxies function in humid regions and in aragonite speleothems. In this study, we use meteorological data to calibrate (234U/238U)i and 87Sr/86Sr in a modern aragonite speleothem from northeast India, the rainiest place on Earth, to determine how these proxies reflect effective monsoon rainfall amount. MAW-0201 is an annually laminated aragonite stalagmite that grew from 1960-2013 in Mawmluh Cave, Meghalaya, India. Rainfall here is extremely seasonal due to the Indian Summer Monsoon (ISM), which brings several meters of rain to the region each summer, but with inter-annual variability in total rainfall. The δ18O in Mawmluh dripwater and speleothems reflects moisture source and transport, rather than rainfall amount. Variations in Mg, U, and Ba concentrations in MAW-0201 show seasonal and multi-annual variability. U and Mg are closely correlated, but multi-year periods show significant anti-correlation. The Mg and U distribution coefficients in calcite and aragonite indicate correlated periods are times of prior calcite precipitation (PCP) and anti-correlated periods are times of prior aragonite precipitation (PAP) in the epikarst. We use δ44/40Ca to test this hypothesis, as Ca isotopes fractionate differently during calcite and aragonite precipitation and speleothem δ44/40Ca will record unique PAP and PCP fingerprints. We propose such shifts from PCP to PAP reflect hydrologic variability and/or flow path changes, which provide a useful tool for understanding epikarst hydrology but may also be a complicating factor in speleothem-based paleoclimate interpretations. Preliminary (234U/238U)i (always <1) and 87Sr/86Sr spanning 1991-2009 each show significant variability outside of analytical error. (234U/238U)i displays a decadal trend, gradually increasing until 2000 and decreasing to the end of the record. Several years in the 87Sr/86Sr record have anomalously high values, which may reflect increased sea spray input and provide unique information on the wind component of the ISM.
Uranium/Thorium Dating and Growth Laminae Counting of Stalagmites Reveal a Record of Major Earthquakes in the Midwestern US

NASA Astrophysics Data System (ADS)

Zhang, Z.; Lundstrom, C.; Panno, S.; Hackley, K. C.; Fouke, B. W.; Curry, B.

2009-12-01

The recurrence interval of large New Madrid Seismic Zone (NMSZ) earthquakes is uncertain because of the limited number and likely incomplete nature of the record of dated seismic events. Data on paleoseismicity in this area is necessary for refining estimates of a recurrence interval for these earthquakes and for characterizing the geophysical nature of the NMSZ. Studies of the paleoseismic history of the NMSZ have previously used liquefaction features and flood plain deposits along the Mississippi River to estimate recurrence interval with considerable uncertainties. More precise estimates of the number and ages of paleoseismic events would enhance the ability of federal, state, and local agencies to make critical preparedness decisions. Initiation of new speleothems (cave deposits) has been shown in several localities to record large earthquake events. Our ongoing work in caves of southwestern Illinois, Missouri, Indiana and Arkansas has used both U/Th age dating techniques and growth laminae counting of actively growing stalagmites to determine the age of initiation of stalagmites in caves across the Midwestern U.S. These age initiations cluster around two known events, the great NMSZ earthquakes of 1811-1812 and the Missouri earthquake of 1917, suggesting that cave deposits in this region constitute a unique record of paleo-seismic history of the NMSZ. Furthermore, the U-Th disequilibria growth laminae ages of young, white stalagmites and of older stalagmites on which they grew, plus published Holocene stalagmite ages of initiation and regrowth from Missouri caves, are all coincident with suspected NMSZ earthquakes based on liquefaction and other paleoseimic techniques. We hypothesize that these speleothems were initiated by earthquake-induced opening/closing of fracture-controlled flowpaths in the ceilings of cave passages.
Speleothem evidence for MIS 5c and 5a sea level above modern level at Bermuda

NASA Astrophysics Data System (ADS)

Wainer, Karine A. I.; Rowe, Mark P.; Thomas, Alexander L.; Mason, Andrew J.; Williams, Bruce; Tamisiea, Mark E.; Williams, Felicity H.; Düsterhus, André; Henderson, Gideon M.

2017-01-01

The history of sea level in regions impacted by glacio-isostasy provides constraints on past ice-sheet distribution and on the characteristics of deformation of the planet in response to loading. The Western North Atlantic-Caribbean region, and Bermuda in particular, is strongly affected by the glacial forebulge that forms as a result of the Laurentide ice-sheet present during glacial periods. The timing of growth of speleothems, at elevations close to sea level can provide records of minimum relative sea level (RSL). In this study we used U-Th dating to precisely date growth periods of speleothems from Bermuda which were found close to modern-day sea level. Results suggest that RSL at this location was above modern during MIS5e, MIS5c and MIS5a. These data support controversial previous indications that Bermudian RSL was significantly higher than RSL at other locations during MIS 5c and MIS 5a. We confirm that it is possible to explain a wide range of MIS5c-a relative sea levels observed across the Western North Atlantic-Caribbean in glacial isostatic adjustment models, but only with a limited range of mantle deformation constants. This study demonstrates the particular power of Bermuda as a gauge for response of the forebulge to glacial loading, and demonstrates the potential for highstands at this location to be significantly higher than in other regions, helping to explain the high sea levels observed for Bermuda from earlier highstands.
Environmental influences on speleothem growth in southwestern Oregon during the last 380, 000 years

USGS Publications Warehouse

Ersek, Vasile; Hostetler, Steven W.; Cheng, Hai; Clark, Peter U.; Anslow, Faron S.; Mix, Alan C.; Edwards, R. Lawrence

2009-01-01

The growth of carbonate formations in caves (speleothems) is sensitive to changes in environmental conditions at the surface (temperature, precipitation and vegetation) and can provide useful paleoclimatic and paleoenvironmental information. We use 73 230Th dates from speleothems collected from a cave in southwestern Oregon (USA) to constrain speleothem growth for the past 380 000 years. Most speleothem growth occurred during interglacial periods, whereas little growth occurred during glacial intervals. To evaluate potential environmental controls on speleothem growth we use two new modeling approaches: i) a one-dimensional thermal advection–diffusion model to estimate cave temperatures during the last glacial cycle, and ii) a regional climate model simulation for the Last Glacial Maximum (21 000 years before present) that assesses a range of potential controls on speleothem growth under peak glacial conditions. The two models are mutually consistent in indicating that permafrost formation did not influence speleothem growth during glacial periods. Instead, the regional climate model simulation combined with proxy data suggest that the influence of the Laurentide and Cordilleran ice sheets on atmospheric circulation induced substantial changes in water balance in the Pacific Northwest and affected speleothem growth at our location. The overall drier conditions during glacial intervals and associated periods of frozen topsoil at times of maximum surface runoff likely induced drastic changes in cave recharge and limited speleothem growth. This mechanism could have affected speleothem growth in other mid-latitude caves without requiring the presence of permafrost.
The impact of MIS-3 climate events at the transition from Neanderthals to modern humans in Europe

NASA Astrophysics Data System (ADS)

Staubwasser, M.; Dragusin, V.; Assonov, S.; Ersek, V.; Hoffmann, D.; Veres, D.; Onac, B. P.

2017-12-01

We report on last glacial stable C and O isotope records from two U-Th dated speleothems from Romania. The southerly record (Ascunsa Cave, South Carpathians) from the Danube region matches the pacing and relative change in amplitude of the Greenland ice temperature record at 30-50 ka BP as well as the abundance of coastal winter sea ice in the Black Sea. The northerly record (Tausoare Cave, East Carpathians) in parts shares the pacing of events with the Greenland or the southern Romanian record, but best matches northern Black Sea summer season temperature change. Heinrich events do not stand out in either record, but the temperature amplitudes of Greenland stadials and Black Sea records are generally reproduced. Based on similarity with the Black Sea we interpret the combined two speleothem records in terms of seasonal temperature change in central Eastern Europe. A climatic influence on the transition from Neanderthals to modern humans has long been suspected. However, the diachronous and spatially complex archaeologic succession across the Middle-Upper Paleolithic (MUPL) in Europe ( 38 - 48 ka) is difficult to reconcile with the millennial-scale pacing of northern hemisphere paleoclimate. Two extreme cold events at 44.0-43.3 recorded and 40.7-39.8 ka in the speleothems bracket the dates of the first known appearance of modern humans - the Aurignacian complex - and the disappearance of Neanderthals from most of Europe. These cold events are coeval with Greenland Stadials GS-12 and GS-10. The speleothem records generally match the paleosol/loess succession from central Europe across the MUPL. The combined record suggests that permafrost advance may have made central Europe uninhabitable at least during winter. The combined paleoclimate and archaeologic records suggest that depopulation-repopulation cycles may have occurred during and after each cold event. Repopulation of central Europe geographically favored the modern human Aurignacians from SE Europe.
Quaternary climate change on the northern margins of Saharo-Arabian Desert with possible impact on human evolution, evidence from Negev Desert speleothems, Israel

NASA Astrophysics Data System (ADS)

Vaks, A.; Bar-Matthews, M.; Ayalon, A.; Matthews, A.; Halicz, L.; Frumkin, A.

2006-12-01

The Saharo-Arabian Desert belt is the largest and driest desert in the world and its margins are vulnerable to climatic change. The paleoclimate of the northern margins of Saharo-Arabian Desert is not yet fully understood, and it is the subject of our study. The Negev Desert, southern Israel, located in the northern part of the Saharo-Arabian Desert is ideal for paleoclimate research, because of its very steep north-south precipitation gradient and numerous caves rich with carbonate cave deposits (speleothems). Speleothems grow only when precipitation is high enough to enable meteoric water to reach the caves. No present day speleothem deposition occurs in the Negev Desert. The aims of the study were: timing of the humid periods by U-Th dating of the speleothem deposition periods; origin of the rainfall by speleothem δ18O and fluid inclusions δ2H; correlations between local and global climate changes and between the climate changes to out of Africa dispersals of Early Modern Humans (EMH). Speleothems were collected from 7 caves located on the north-south transect of the Negev Desert, between 300 mm to 30 mm isohyets. Whereas in the Mediterranean climate zone (>350 mm) of central and northern Israel the speleothem deposition was continuous, in the Negev Desert periods of speleothem deposition alternated with multiple hiatuses. In the mildly arid transition zone of northern Negev (300 to 150 mm) speleothem deposition occurred most of the time during the last 210 ka, with hiatuses at 150-144 ka, ~140 ka, 117-96 ka, 93-85 ka, 25- 23 ka, and 14-0 ka. In present-day arid and hyper-arid zone of central and southern Negev (150 to 30 mm) no speleothem deposition occurred most of the last 350 ka, with humid intervals at 350-290 ka, 220-190 ka, 137- 110 ka, and ~85 ka. The origin of the precipitation in the Negev Desert during these intervals was from Eastern Mediterranean Sea, i. e. mid-latitude cyclones (as present day). The latter conclusion is based on three evidences: thinning laminae width of dateable speleothems from few tens of cm in northern Negev to less than 2 cm in the south; similarity of oxygen isotopic trends between desert speleothems and speleothems from Mediterranean climate; and δ18O - δ2H relationships of speleothem fluid inclusions that follow usually the Mediterranean Meteoric Water Line. The intensification of the mid-latitude cyclones that caused increased rainfall in northern Saharo-Arabian desert at 350-290 ka, 220-190 ka, 137-110 ka, and ~85 ka correlate to the peaks of monsoon activity in southern and central parts of the desert belt. We assume that during these events the Saharo-Arabian Desert significantly reduced its size, opening climatic windows for hominids and African animals to get out of the African continent. One of the evidences supporting this hypothesis is first appearance of the EMH out of the Africa at ~130 ka in Israeli caves Skhul and Qafzeh, during the peak of the humid period of 137-110 ka. The expanding aridity after 110 ka blocked the way back to Africa and may have driven the EMH further east and north.
Formation of amorphous calcium carbonate in caves and its implications for speleothem research.

PubMed

Demény, Attila; Németh, Péter; Czuppon, György; Leél-Őssy, Szabolcs; Szabó, Máté; Judik, Katalin; Németh, Tibor; Stieber, József

2016-12-22

Speleothem deposits are among the most valuable continental formations in paleoclimate research, as they can be dated using absolute dating methods, and they also provide valuable climate proxies. However, alteration processes such as post-depositional mineralogical transformations can significantly influence the paleoclimatic application of their geochemical data. An innovative sampling and measurement protocol combined with scanning and transmission electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy is presented, demonstrating that carbonate precipitating from drip water in caves at ~10 °C contains amorphous calcium carbonate (ACC) that later transforms to nanocrystalline calcite. Stable oxygen isotope fractionations among calcite, ACC and water were also determined, proving that ACC is 18 O-depleted (by >2.4 ± 0.8‰) relative to calcite. This, in turn, has serious consequences for speleothem-based fluid inclusion research as closed system transformation of ACC to calcite may induce a negative oxygen isotope shift in fluid inclusion water, resulting in deterioration of the original compositions. ACC formation increases the speleothems' sensitivity to alteration as its interaction with external solutions may result in the partial loss of original proxy signals. Mineralogical analysis of freshly precipitating carbonate at the studied speleothem site is suggested in order to determine the potential influence of ACC formation.
The last glacial inception in continental northwestern Europe: characterization and timing of the Late Eemian Aridity Pulse (LEAP) recorded in multiple Belgian speleothems.

NASA Astrophysics Data System (ADS)

Vansteenberge, Stef; Verheyden, Sophie; Quinif, Yves; Genty, Dominique; Blamart, Dominique; Deprez, Maxim; Van Stappen, Jeroen; Cnudde, Veerle; Cheng, Hai; Edwards, R. Lawrence; Claeys, Philippe

2017-04-01

Interglacial-glacial transitions represent important turnovers in the climate system. In contrast with glacial terminations, they are described as a more gradual cooling. So far, the last interglacial has yielded a wealth of knowledge regarding climate dynamics during past warm periods. On top of the assumed gradual temperature drop starting at 119 ka, evidence for the presence of a drastic drying/cooling event in northern Europe has been observed. In lake records from Germany, a distinct shift in pollen assembly at 117.5 ka is interpreted as the consequence of a short dry event lasting 470 years, defined as the Late Eemian Aridity Pulse (LEAP, Sirocko et al., 2005). In a Belgian stalagmite from Han-sur-Lesse Cave, the LEAP is characterized by a 5‰ increase in δ13C occurring in just 200 years. The δ13C enrichment is dated at 117.5 ka and associated with a vegetation change above the cave, induced by a drying and/or cooling event (Vansteenberge et al., 2016). Also, within North Atlantic sediment cores, an increase in ice rafted debris was linked to the occurrence of a colder period at 117 ka (Irvali et al., 2016). Its coevality with the LEAP indicates a likely more regional extent than previously thought. Up to now, no independent chronology exists and little is known about the continental climatic expression of the LEAP. This study aims at 1) constructing an improved and independent chronology for the LEAP event, 2) characterizing this event in terms of its climatic expression and 3) placing the LEAP within the context of an interglacial-glacial transition. For this, two additional speleothems (Han-8, RSM-17) from two different Belgian caves (Han-sur-Lesse, Remouchamps) are added to the existing Han-9 dataset. Exceptionally high growth rates (0.5 mm yr-1) and a presumed annual layering of the RSM-17 sample enable an annual to decadal resolution to investigate the LEAP. U-Th age models covering the glacial inception are constructed with 25 dates on the three speleothems. All samples are investigated through a multiproxy approach consisting of growth rate, stable isotopes (δ13C and δ18O) and trace elements (Mg, Sr, Ba, Zn, Pb, U). Furthermore, µCT scans with a resolution down to 10µm characterize pronounced changes in speleothem morphology. First results show the presence of similar δ13C excursions in the two newly analyzed speleothems. The plenitude of U-Th dates now confirms the timing of the LEAP at 117.5 ka, as determined from Han-9 but significantly reduce the age error to 0.4 ka. Also, the various proxies demonstrate that pre-LEAP climate conditions were not reestablished after the event, indicating that, at least in Belgium, the LEAP may have had a more severe impact than previously thought. This study shows that events such as the LEAP are an important feature within the gradual cooling occurring during glacial inceptions, and they contribute to a better understanding of the dynamics of an interglacial-glacial transition. References: Irvali, N., et al., 2016, Quaternary Science Reviews, 150, 184-199. Sirocko, F., et al., 2005, Nature, 436, 833-836. Vansteenberge, S., et al., 2016, Climate of the Past., 12, 1445-1458.

Composite δ13C and petrographic 195-355 ka record from Frasassi cave (central Italy) stalagmites: investigating drivers of speleothem calcite carbon isotope signals.

NASA Astrophysics Data System (ADS)

Vanghi, V.; Borsato, A.; Frisia, S.; Drysdale, R.; Hellstrom, J. C.; Bajo, P.; Montanari, A.

2016-12-01

Carbon isotope ratio of speleothem calcite is known to be a proxy for climate-dependent soil CO2 production. One of the paradigms is that, ideally, C stable isotope incorporation occurred in equilibrium. Yet, the process of degassing in the cave commonly results in δ13C values more positive than theoretically expected for speleothems formed in temperate-humid settings. Fabrics then provide the benchmark to unravel local, regional and global significance of speleothem δ13C. The δ13C time-series from two precisely U-Th dated Frasassi stalagmites covering the interval from 195 ka to 355 ka (Marine Isotope Stages 7 - 10) were interpreted on the basis of the sequence of fabrics. Columnar fabrics indicated deposition under constant kinetic fractionation, whereby δ13C shifts through time reflected a combination of atmospheric CO2 concentration changes and soil efficiency variability, controlled by regional mean annual temperature. Given that the δ13C values are constantly more-positive-than-expected because of the effect of degassing, shifts to more positive δ13C values above a baseline of -7 permil during glacials are here interpreted as driven by low soil efficiency and higher contribution of atmospheric CO2 (Breecker et al. 2012, Borsato et al. 2015). The comparison of high resolution δ13C curves with atmospheric pCO2 and benthic δ18O records further suggests that hemispheric temperature changes driven by insolation modulated the δ13C shifts above or below the baseline. Thus, a -3‰ shift from glacial to interglacial at terminations IV and III is here ascribed to changes in atmospheric pCO2 (Schubert and Jahren 2012). More open fabrics mark warmer conditions and increased soil productivity and are associated with more negative δ13C. In conclusion, only by coupling petrography and geochemical properties the global and local drivers of δ13C anomalies in stalagmites from this deep cave could be distinguished. Borsato et al. (2015), Earth Surface Processes and Landforms 40 (9), 1158-1170. Breecker et al. (2012), Geochimica et Cosmochimica Acta 96 (1), 230-246. Schubert and Jahren (2012), Geochimica et Cosmochimica Acta 96, 29-43.
New constraints on MIS 7 and 5 relative sea-level at Bermuda: a speleothem approach

NASA Astrophysics Data System (ADS)

Wainer, Karine; Henderson, Gideon; Mason, Andrew; Thomas, Alexander; Williams, Bruce; Rowe, Mark; van Hengstum, Peter; Chandler, Robert

2014-05-01

It is now widely accepted that a sea-level rise is associated with global warming [1]. However, its rate, and the height it might reach by the end of the century remain poorly constrained. This study aims to provide better information and precision on the rates and magnitudes of past sea-level change, for periods when sea-level is close to its modern value, using speleothems from Bermudian caves. Speleothems interrupt their growth when they are submerged by sea-water, so U-Th dating periods of growth in coastal sites allows the reconstruction of past sea-level variation versus absolute time [e.g. 2,3,4]. We will present new MC-ICP-MS U-Th ages, trace elements and isotopic data from a set of speleothems (stalagmites, stalactites, flowstones) collected from -14 to +12 m versus modern sea level from several caves in this northern Atlantic archipelago. Relative sea-level (RSL) at Bermuda is of particular interest because it is at a distance from northern hemisphere ice sheets where the isostatic response to ice-unloading is uncertain. RSL reconstruction therefore provides both an indicates of possible rates of sea level change, and a test for glacial-isostatic-adjustment (GIA) models. We will present new relative sea level data for late MIS7, and the different highstands of MIS5. The RSL at Bermuda for these episodes appears to be higher than present. For MIS5a, this is significantly distinct from what is expected from the eustatic sea level. These results will be considered in the context of previous assessments of eustatic change, and of GIA models. [1] Intergovernmental Panel on Climate Change (2007) Contribution of Working Group I to the Fourth Assessment Report, Cambridge Univ. Press. [2] Harmon et al. (1981) Nature 289, 357-360. [3] Richards et al. (1994) Nature 367, 481-483. [4] Bard (2002) EPSL 196, 135-146.
Subtropical Climate Variability since the Last Glacial Maximum from Speleothem Precipitation Reconstructions in Florida

NASA Astrophysics Data System (ADS)

Polk, J.; van Beynen, P.; DeLong, K. L.; Asmerom, Y.; Polyak, V. J.

2017-12-01

Teleconnections between the tropical-subtropical regions of the Americas since the Last Glacial Maximum (LGM), particularly the Mid- to Late-Holocene, and high-resolution proxy records refining climate variability over this period continue to receive increasing attention. Here, we present a high-resolution, precisely dated speleothem record spanning multiple periods of time since the LGM ( 30 ka) for the Florida peninsula. The data indicate that the amount effect plays a significant role in determining the isotopic signal of the speleothem calcite. Collectively, the records indicate distinct differences in climate in the region between the LGM, Mid-Holocene, and Late Holocene, including a progressive shift in ocean composition and precipitation isotopic values through the period, suggesting Florida's sensitivity to regional and global climatic shifts. Comparisons between speleothem δ18O values and Gulf of Mexico marine records reveal a strong connection between the Gulf region and the terrestrial subtropical climate in the Late Holocene, while the North Atlantic's influence is clear in the earlier portions of the record. Warmer sea surface temperatures correspond to enhanced evaporation, leading to more intense atmospheric convection in Florida, and thereby modulating the isotopic composition of rainfall above the cave. These regional signals in climate extend from the subtropics to the tropics, with a clear covariance between the speleothem signal and other proxy records from around the region, as well as global agreement during the LGM period with other records. These latter connections appear to be driven by changes in the mean position of the Intertropical Convergence Zone and time series analysis of the δ18O values reveals significant multidecadal periodicities in the record, which are evidenced by agreement with the AMV and other multidecadal influences (NAO and PDO) likely having varying influence throughout the period of record. The climate variability recorded in our record suggests complex responses to major and abrupt shifts during these periods, likely due to Florida's subtropical location and the influence of multiple climate forcing mechanisms in the region.
Mid-late Holocene palaeoclimate of northern Jordan from speleothem geochemistry

NASA Astrophysics Data System (ADS)

Robinson, S. A.; Black, S.; Lovell, J.; Atkinson, T. C.

2009-04-01

The southern Levant region (encompassing the modern countries of Israel and Jordan) is a climatically sensitive area due to the proximity of the Negev and Arabian Deserts to the south and east. Although there is a general pattern of decreasing rainfall to the south and east of the region, local topographic features, most notably the Dead Sea Rift Valley, have a significant effect on detailed rainfall patterns. Our understanding of the Holocene climate of the southern Levant is principally known from records obtained to the west of the Dead Sea Rift, on the borders of the Negev Desert and from the lakes within the rift valley itself. Palaeoclimate records from the more interior regions, such as Jordan, are fewer in number and, generally at lower stratigraphic resolution. A recent archaeological survey has revealed the existence of limestone caves in northern Jordan, many of which were previously unknown to academics working in the region. These caves contain a variety of architectures, including stalagmites, stalactites, flowstones and soda straws. We present geochemical data (oxygen and carbon-isotopes, and uranium-series dates) from a small speleothem that provides the first detailed mid-late Holocene climate record for the area east. The new data are similar in value and contain similar magnitude shifts to previously published data from Israel (Soreq and Nahal Qanah Caves) and Lebanon (Jeita Cave). Through comparison with these other speleothem records we suggest that the oxygen-isotopic composition of the Jordanian speleothem is consistent with rainfall from Mediterranean-sourced weather systems that evolved to lighter isotopic compositions through rainout of 18O as they moved into the interior of the southern Levant. The Ras Muneef GNIP monitoring station provides a limited record of precipitation rates and isotopic compositions of rainwater. Combining this data with the speleothem data, suggests that Holocene temperatures in northern Jordan were broadly similar to present day mean annual temperatures and that the fluctuations in δ18O are likely the result of changes in the amount of precipitation.
Evaluating interannual variability in speleothem records of North American monsoon rainfall

NASA Astrophysics Data System (ADS)

Truebe, S. A.; Cole, J. E.; Ault, T. R.; Kimbrough, A.; Henderson, G. M.; Barmett, H.; Hlohowskyj, S.

2013-12-01

Speleothems can produce long, high resolution, absolutely-dated records of past climate. They are especially useful for past climate reconstruction in areas such as the southwestern United States, where traditional sources of past climate information (corals, lake or ocean sediments, ice cores) are absent. Here we present two records of Holocene rainfall variability from two Arizona caves less than 40km apart: Cave of the Bells (COB) and Fort Huachuca Cave (FHC), spanning 7000 and 4000 years respectively. Both records show a trend towards more negative oxygen isotope values into the modern era. Extensive monthly monitoring suggests that speleothem oxygen isotope composition is an average of the oxygen isotope composition of the summer North American monsoon (NAM) and winter frontal storms, with a bias towards winter likely due to lack of infiltration of intense monsoon rainfall. This bias is stronger in COB than in FHC. Winter rainfall has had an increasing influence at both sites from the mid-Holocene until the present; in other words, the NAM has been weakening over the past few thousand years, in step with changes in other monsoon systems and Northern Hemisphere insolation. Although the records are similar in overall trend, short-term variability is inconsistent. When providing information to water managers about future rainfall availability in the Southwest, having only millennial-scale information does not help much! To investigate the differences between the two records, we use a combination of approaches, including assessing age model uncertainty and modern climate heterogeneity, and monitoring cave-specific processes that may be overprinting the climate signal. We assess age model uncertainty using a statistical age-modeling program, which allows us to develop many physically plausible time series for the same age-depth data. With this age modeling tool, we critically assess whether particular isotope excursions correspond between speleothems and if they are temporally related to global climate events. However, even correlation and coherence analyses across the suites of time series for each speleothem do not elicit a common high-frequency climate story. We further investigate the discrepancy between cave records by assessing modern climate heterogeneity using historical observations. Climate in the arid Southwest is spatially heterogeneous, especially during the summer monsoon, contributing to the mismatch between these two climate records. Finally, after a decade of monitoring at COB, we recognize that storage and mixing in the epikarst above the cave affect what parts (if any) of the seasonal signal are recorded in a speleothem. In addition to new insights about North American monsoon behavior during the Holocene, the important lesson from these speleothem records is that in caves, because of underlying (overlying?) climate heterogeneity, replication of a common climate signal using oxygen isotopes may be an unattainable goal. The COB and FHC records may record very local climate at their respective locations, overprinted by water storage and mixing in the epikarst. Very local-scale reconstructions of past rainfall variability from speleothems can still be useful and important, if interpreted for what they are.
Mapping tropical hydroclimate changes with speleothem δ18O records

NASA Astrophysics Data System (ADS)

Wang, X.; Liu, G.; Yuan, S.; Chiang, H. W.

2017-12-01

Speleothem δ18O records have been extensively used to study tropical hydroclimate change. However, less attention has been paid to the spatial distribution of speleothem δ18O values. Despite some caveats, we advocate an approach to reconstruct spatial and temporal transects ("maps") of speleothem δ18O, thus time series of precipitation δ18O distribution in a region. We present here two examples in using speleothem δ18O records to establish a spatial and temporal pattern of tropical hydroclimate changes. In the first case, we compare the speleothem δ18O records from caves located separately in the eastern and western Amazon lowlands. The decrease in speleothem δ18O values from the east to the west indicates an overall continental rainout effect of water isotopes when surface moisture is transported across the lowlands. A much large δ18O gradient however exists during the last glacial maximum than in the Holocene, suggesting that the Amazon was probably widely dry during the glacial, with much less recycling of water and reduced plant transpiration. And in the second case, we compare speleothem δ18O records obtained from caves along a SW-NE transect from coastal Myanmar to southwestern China. These records similarly show a larger gradient in speleothem δ18O along the transport path of Indian monsoon moisture during the glacial period than in the Holocene. Caution therefore is needed when interpreting the speleothem δ18O records from the monsoon downwind region.
Ocean-Ice Sheet Interactions in the Norwegian Sea and Teleconnections to Low Latitude Hydrology and Atmospheric Circulation

NASA Astrophysics Data System (ADS)

Brendryen, J.; Hannisdal, B.; Haaga, K. A.; Haflidason, H.; Castro, D. D.; Grasmo, K. J.; Sejrup, H. P.; Edwards, R. L.; Cheng, H.; Kelly, M. J.; Lu, Y.

2016-12-01

Abrupt millennial scale climatic events known as Dansgaard-Oeschger events are a defining feature of the Quaternary climate system dynamics in the North Atlantic and beyond. We present a high-resolution multi-proxy record of ocean-ice sheet interactions in the Norwegian Sea spanning the interval between 50 and 150 ka BP. A comparison with low latitude records indicates a very close connection between the high northern latitude ocean-ice sheet interactions and large scale changes in low latitude atmospheric circulation and hydrology even on sub-millennial scales. The records are placed on a common precise radiometric chronology based on correlations to U/Th dated speleothem records from China and the Alps. This enables a comparison of the records to orbital and other climatically important parameters such as U/Th dated sea-level data from corals and speleothems. We explore the drive-response relationships in these coupled systems with the information transfer (IT) and the convergent cross mapping (CCM) analytical techniques. These methods employ conceptually different approaches to detect the relative strength and directionality of potentially chaotic and nonlinearly coupled systems. IT is a non-parametric measure of information transfer between data records based on transfer entropy, while CCM relies on delay reconstructions using Takens' theorem. This approach enables us to address how the climate system processes interact and how this interaction is affected by external forcing from for example greenhouse gases and orbital variability.
Speleothem records of western Mediterranean. Hydrological variability along the Last Interglacial Period and marine linkages

NASA Astrophysics Data System (ADS)

Torner, Judit; Cacho, Isabel; Moreno, Ana; Stoll, Heather; Belmonte, Anchel; Sierro, Francisco J.; Frigola, Jaime; Martrat, Belen; Fornós, Joan; Arnau Fernández, Pedro; Hellstrom, John; Cheng, Hai; Edwards, R. Lawrence

2016-04-01

This study aims to identify and characterize regional hydrological variability in the western Mediterranean region in base to different geochemical parameters (δ18O, δ13C, and Mg/Ca ratios). Speleothems have been recovered from several caves located in southern central Pyrenees one and the others form the Balearic Islands. Their chronologies have been constructed in base on U/Th absolute dating and indicate that the speleothem sequences cover the end of the last interglacial and the glacial inception. One of the most remarkable features of the records is the intense and abrupt shift toward more arid conditions that marks the end of the last interglacial (MIS 5e). Furthermore, our speleothem records also show relatively humid but highly variable hydrological conditions during the interstadial periods from MIS 5c to 5a. These speleothem records have been compared with new generated western Mediterranean marine records from the Balearic Sea (MD99-2343) and Alboran Sea (OPD-977). Marine records include (1) proxies of sea surface temperature and changes in evaporation-precipitation rates based on pair analysis of δ18O and the Mg/Ca ratios in planktonic foraminifera Globigerina bulloides; (2) proxies of deep-water currents associated with the Western Mediterranean Deep Water (WMDW) based on grain size analyses. The results reveal that arid conditions on land were coeval with cold sea surface sub-stages (MIS 5b and 5d), and also with increases in the intensity of the WMDW-related currents. By contrast, humid and hydrological unstable atmosphere conditions were synchronous with sea surface warm sub-stages, and lower WMDW-related currents intensities (MIS 5a, c and e). Consequently, our results highly evidence a strong atmospheric-oceanic coupling, involving parallel changes in both surface but also deep western Mediterranean Sea conditions during the last interglacial period and the glacial inception.
Stalagmite geochemistry and the timing of the last interglacial-glacial transition in Central Europe (NE Hungary)

NASA Astrophysics Data System (ADS)

Siklosy, Z.; Demeny, A.; Pilet, S.; Leel-Ossy, Sz.; Lin, K.; Shen, C.-C.

2009-04-01

Speleothems can provide accurate chronologies for reconstructions of climate change by combination of U/Th dating and climate-related geochemical compositions. Geochemical studies of speleothems from Central Europe are mostly based on stable C and O isotope analyses, thus, complex geochemical studies combining isotope and trace element measurements are needed for more reliable climate models for this transitional area between oceanic and continental regions. We present stable H-C-O isotope and trace element records obtained on speleothems covering the Last Interglacial (MIS 5e) and the transition to MIS 5d. A stalagmite from Baradla Cave grew from 127.5 to 110 ka. Accelerated growth rates have been detected by U/Th age data in the 127 to 126 ka and 119 to 117 ka parts. Trace element compositions and 230Th/232Th ratios suggest changes in the hydrological regime, whereby early calcite precipitates formed in fissures during the dry and cold glacial period were dissolved by the starting flux of infiltrating meteoric water (producing elevated dissolved ion concentration but low detrital Th component), then the increasing amount of dripwater during the interglacial period resulted in trace element dilution. Temperature and precipitation amount variations are also reflected by the stable isotope compositions. Oxygen isotope composition shows a continuous increase from 127.5 ka until about 118 ka most probably related to temperature rise, whereas C isotope values are shifted in negative direction suggesting increasing humidity in accordance with trace element contents. The presumably warmest period at ca. 118 ka is associated with rather arid climate as indicated by peak d18O values coinciding with the highest dD values of fluid inclusion water. This is followed by a pronounced negative shift in both O and H isotope values, similarly to recent Alpine studies (Meyer et al., 2008), most probably related to cooling. Hydrogen isotope compositions of fluid inclusion water evaluated together with calculated oxygen isotope compositions of water indicate warming and increasing significance of summer precipitation at the latest period of the last interglacial, then increasing importance of winter precipitation and/or changes in oceanic source composition during the cooling phase. The good agreement with other (Alpine and marine) records indicate a synchronous climate change. However, after a negative shift in the wet/warm phase (increasing soil activity), C isotope values start to increase already at about 119 ky BP, warning to the use of the two isotope systems as event correlation tools. In conclusion, our combined isotope and trace element study indicate a complex pattern of temperature and humidity variations during and right after the Last Interglacial. Acknowledgements — This study was financially supported by the Hungarian Scientific Research Fund (OTKA T 049713). Measurements of U-Th isotopic compositions and and 230Th dates were supported by the National Science Council grants (94-2116-M002-012, 97-2752-M002-004-PAE & -005-PAE to C.C.S.). [Meyer, M.; Spötl, C.; Mangini, A. (2008): The demise of the Last Interglacial recorded in isotopically dated speleothems from the Alps. Quaternary Science Reviews, 27, 476-496.
Changing amounts and sources of moisture in the U.S. southwest since the Last Glacial Maximum in response to global climate change

USGS Publications Warehouse

Feng, Weimin; Hardt, Benjamin F.; Banner, Jay L.; Meyer, Kevin J.; James, Eric W.; Musgrove, MaryLynn; Edwards, R. Lawrence; Cheng, Hai; Min, Angela

2014-01-01

The U.S. southwest has a limited water supply and is predicted to become drier in the 21st century. An improved understanding of factors controlling moisture sources and availability is aided by reconstruction of past responses to global climate change. New stable isotope and growth-rate records for a central Texas speleothem indicate a strong influence of Gulf of Mexico (GoM) moisture and increased precipitation from 15.5 to 13.5 ka, which includes the majority of the Bølling–Allerød warming (BA: 14.7–12.9 ka). Coeval speleothem records from 900 and 1200 km to the west allow reconstruction of regional moisture sources and atmospheric circulation. The combined isotope and growth-rate time series indicates 1) increased GoM moisture input during the majority of the BA, producing greater precipitation in Texas and New Mexico; and 2) a retreat of GoM moisture during Younger Dryas cooling (12.9–11.5 ka), reducing precipitation. These results portray how late-Pleistocene atmospheric circulation and moisture distribution in this region responded to global changes, providing information to improve models of future climate.
Belgian speleothems from the Last Interglacial: insights in the onset of glacial conditions in north western Europe.

NASA Astrophysics Data System (ADS)

Vansteenberge, Stef; Verheyden, Sophie; Cheng, Hai; Edwards, Lawrence R.; Keppens, Eddy; Claeys, Philippe

2015-04-01

Currently, a dataset combining at least four speleothems from two different cave systems in southern Belgium (Han-sur-Lesse and Remouchamps) is being constructed to improve the understanding of the termination of the Eemian and the millennial to decadal variability of the Early Glacial times in north western Europe. Here, one of those speleothems is presented. The Han-stm-9 (or 'Triptyque') speleothem is a broken, 68 cm long and candle-shaped stalagmite from the Han-sur-Lesse cave system. The stalagmite was collected in summer 2013 within the southern part of the cave network and was dated between ~126 and ~99ka. Most likely, climate optimum conditions during the 130-125ka interval are linked to the growth of this and other speleothems from Belgian caves. This particular speleothem gained interest because of the partial conformity with the continental interglacial period in northern western Europe (130 - 118ka) and its dense calcite composition with visible layering, excluding post-depositional deformation. Furthermore, the stalagmite displays a complex growth history, with large variations in growth rates (ranging from and periods of ceased speleothem formation. Two hiatuses, with a distinct macroscopic expression, occur. The first one starts at 118.4ka and lasts until 113.0ka. A second hiatus is situated between ~108ka and 103.7ka. A trend in growth rate, consisting of slow growth gradually increasing towards very fast speleothem formation before both hiatuses, is observed. These intervals with very high growth rates, for instance around 118ka, enable high-resolution climate reconstructions via stable isotopes (δ18O and δ13C) and trace elements (Mg, Sr, Ba and P), down to centennial and decadal scale. The timing of the first hiatus corresponds with Greenland Stadial 26 and with the generally accepted termination of the Eemian in northern Europe at 119-118ka. Also, preliminary stable isotope studies have indicated a large detoriation of δ13C occurring right before the second hiatus, while δ18O increases only gradually. This could indicate drastic vegetation changes in the area occurring around the timing of GS25. Furthermore, both δ18O and δ13C time series clearly display millennial to centennial scaled variability during the onset of the Last Glacial. These proxies thus indicate a rather complex glacial-interglacial transition, which is in line with other archives from different locations in Belgium and Europe. Eventually, integrating these findings into a more regional dataset can lead to an improved knowledge of continent-scaled tendencies, such as previously suggested N-S gradients in the onset of Interglacial and Glacial conditions.
Damaged Speleothems of the Ms 8.0 Wenchuan Earthquake, China, and the Implications for Seismology

NASA Astrophysics Data System (ADS)

Xueqin, Zhao; Fudong, Wang

2017-04-01

Broken or deformed speleothems can be used for paleoseismic research since they can be dated with radiometric techniques. But it rarely happens that speleologists are in caves just at the time of strong earthquake shocks, and there are only a few published cases of observations from caves visited immediately after an earthquake. So that it is really plausible that earthquakes break speleothem. Therefore, it needs more evidence of recent strong seismic to prove the way of speleoseismology. In order to provide more on-site data for speleoseismology, four underground cavities in the Longmenshan Fault Zone where a devastating Ms 8.0 earthquake has occurred at 2:28 pm, May 12, 2008, have been selected for speleoseismic analysis. We document damaged carbonate cave deposits by Wenchuan earthquake, including collapsed and broken stalactites, in-situ severed stalagmites and stalactites, collapsed bedrock ceilings, and strictures; and discuss the implications of damaged speleothems as possible earthquake recorder. The results show that massive damaged speleothem, as an effective method for paleoseismic, can compatible with strong earthquake.
Carbon cycle dynamics and solar activity embedded in a high-resolution 14C speleothem record from Belize, Central America

NASA Astrophysics Data System (ADS)

Lechleitner, Franziska A.; Breitenbach, Sebastian F. M.; McIntyre, Cameron; Asmerom, Yemane; Prufer, Keith M.; Polyak, Victor; Culleton, Brendan J.; Kennett, Douglas J.; Eglinton, Timothy I.; Baldini, James U. L.

2015-04-01

Speleothem 14C has recently emerged as a potentially powerful proxy for climate reconstruction. Several studies have highlighted the link between karst hydrology and speleothem 14C content, and a number of possible causes for this relationship have been proposed, such as dripwater flow dynamics in the karst and changes in soil organic matter (SOM) turnover time (e.g. Griffiths et al., 2012). Here we present a high resolution 14C record for a stalagmite (YOK-I) from Yok Balum cave in southern Belize, Central America. YOK-I grew continuously over the last 2000 years, and has been dated very precisely with the U-Th method (40 dates, mean uncertainty < 10 years). The excellent chronological control for this stalagmite allows us to calculate 14C activity (a14C) at the time of speleothem deposition (a14Cinit), as well as the dead carbon fraction (DCF), predominantly a measure of the reservoir effect introduced by limestone dissolution in the karst (Genty et al., 2001). Both records show striking similarities to atmospheric a14C (IntCal13) and reconstructions of solar activity and 14C production rate. We infer close coupling between cave environment and atmosphere, with minimal signal dampening, an observation supported by monitoring data (Ridley et al., in press). DCF fluctuates between approximately 10% and 16% over the entire record, with distinctly lower DCF values and higher a14Cinit during a period of reduced rainfall between ca. 700-1100 AD (linked to the Classic Maya Collapse). This behavior is consistent with observations made elsewhere, and suggests that DCF responds to karst hydrological variability, specifically open-closed system transitions. YOK-I a14Cinit typically lags atmospheric values by 10-100 cal years. A shorter lag appears to be linked to periods of drought, suggesting a response of SOM dynamics above the cave to rainfall reduction. Specifically, drought is inferred to lead to reduced bioproductivity and soil carbon turnover, lowering contributions of old recalcitrant carbon to the soil water, and resulting in closer coupling between atmosphere and cave environment. The resolution of the record (0.3-0.7 mm/sample) permits identification of the dominant drivers of stalagmite 14C during different intervals. For example, hydrologic control on 14C appears dominant during the 11th century drought, while in the 16th to 18th century a clear solar influence exists. Solar activity is reflected in YOK-I as lower a14Cinit, reflecting the atmospheric a14C. We apply simple hydrological models to investigate the different factors influencing 14C in YOK-I. We estimate the importance of mean SOM age to signal dampening, and quantify the strength of the solar influence and the global carbon cycle on the record. References: Genty, D., Baker, A., Massault, M., Proctor, C., Gilmour, M., Pons-Branchu, E., Hamelin, B. (2001) Dead carbon in stalagmites: carbonate bedrock paleodissolution vs. ageing of soil organic matter. Implications for 13C variations in speleothems, GCA, 65 Griffiths, M.L., Fohlmeister, J., Drysdale, R.N., Hua, Q., Johnson, K.R., Hellstrom, J.C., Gagan, M.K., Zhao, J.-x. (2012) Hydrological control of the dead carbon fraction in a Holocene tropical speleothem, Quat. Geochron. 14 Ridley, H.E., Baldini, J.U.L., Prufer, K.M., Walczak, I.W., Breitenbach, S.F.M. (in press) High resolution monitoring of a tropical cave system reveals dynamic ventilation and hydrologic resilience to seismic activity, Journal of Cave and Karst Studies
Subglacial Calcites from Northern Victoria Land: archive of Antarctic volcanism in the Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Frisia, Silvia; Weirich, Laura; Hellstrom, John; Borsato, Andrea; Golledge, Nicholas R.; Anesio, Alexandre M.; Bajo, Petra; Drysdale, Russell N.; Augustinus, Paul C.; Barbante, Carlo; Cooper, Alan

2017-04-01

Subglacial carbonates bear similarities to stalagmites in their fabrics and the potential to obtain precise chronologies using U-series methods. Their chemical properties also reflect those of their parent waters, which, in contrast to stalagmites, are those of subglacial meltwaters. In analogy to speleothems, stable Carbon isotope ratios and trace elements such as Uranium, Iron and Manganese provide the opportunity to investigate ancient extreme environments without the need to drill through thousands of metres of ice. Sedimentological, geochemical and microbial evidence preserved in LGM subglacial calcites from Northern Victoria Land, close to the East Antarctic Ice Sheet margin, allow us to infer that subglacial volcanism was active in the Trans Antarctic Mountain region and induced basal ice melting. We hypothesize that a meltwater reservoir was drained and injected into interconnected basal pore systems where microbial processes enhanced bedrock weathering and, thus, released micronutrients. Volcanic influence is supported by the presence of fluorine (F) and sulphur in sediment-laden calcite layers containing termophilic species. Notably, calcite δ13C points to dissolved inorganic carbon evolved from subglacial metabolic processes. Once transported to the sea, soluble iron likely contributed to fertilizing the Southern Ocean and CO2 drawdown. This is the first well-dated evidence for LGM volcanism in Antarctica, which complements the record of volcanic eruptions retrieved from Talos Dome ice core, and supports the hypothesis of large-scale volcanism as an important driver of climate change. We conclude that subglacial carbonates are equivalent to speleothems in their palaeoclimate potential and may become a most useful source of information of ecosystems and processes at peak glacials in high altitude/high latitude settings.
First 226Ra- 210Pb dating of a young speleothem

NASA Astrophysics Data System (ADS)

Condomines, M.; Rihs, S.

2006-10-01

Whereas the method based on the decrease of excess 210Pb has already been used to date young (< 120 yr) speleothems (e.g. [M. Baskaran, T. M. Iliffe, Age determination of recent cave deposits using excess 210Pb — A new technique, Geophys. Res. Lett. 20 (1993) 603-606.]), this paper presents the first dating of a speleothem through the 226Ra- 210Pb method. Dating of a young hydrothermal stalagmite from the Mt Cornadore cave (St Nectaire, French Massif Central) was made possible by the high 226Ra and negligible 210Pb contents of such carbonates, formed by precipitation from CO 2-rich thermal waters. ( 210Pb/ 226Ra) ratios regularly increase with depth along the axis of the 33 cm long stalagmite. The age-depth relationship can be interpreted by two main phases of growth, with high but variable axial growth rates of 5.3 mm/yr from 1909 to 1967, and 2.6 mm/yr from 1967 to 1989 (alternatively, the oldest phase can be subdivided in three episodes with growth rates varying from 2 to 7 mm/yr). Thin-section examination reveals the presence of numerous laminae, indicating infra-annual variations. We suggest that this fine layered structure might reflect short-term fluctuations in drip waters, possibly induced by near-surface mixing between thermal and ground waters, and ultimately linked to the pluviometry. A detailed examination of this laminated structure combined with 226Ra- 210Pb dating could thus provide a high-resolution record of local paleohydrological fluctuations.
A multi-archive coherent chronology: from Greenland to the Mediterranean sea

NASA Astrophysics Data System (ADS)

Bazin, Lucie; Landais, Amaelle; Lemieux-Dudon, Bénédicte; Siani, Giuseppe; Michel, Elisabeth; Combourieu-Nebout, Nathalie; Blamart, Dominique; Genty, Dominique

2015-04-01

Understanding the climate mechanisms requires a precise knowledge of the sequence of events during major climate changes. In order to provide precise relationships between changes in orbital and/or greenhouse gases concentration forcing, sea level changes and high vs low latitudes temperatures, a common chronological framework for different paleoclimatic archives is required. Coherent chronologies for ice cores have been recently produced using a bayesian dating tool, DATICE (Lemieux-Dudon et al., 2010, Bazin et al., 2013, Veres et al., 2013). Such tool has been recently developed to include marine cores and speleothems in addition to ice cores. This new development should enable one to test the coherency of different chronologies using absolute and stratigraphic links as well as to provide relationship between climatic changes recorded in different archives. We present here a first application of multi-archive coherent dating including paleoclimatic archives from (1) Greenland (NGRIP ice core), (2) Mediterranean sea (marine core MD90-917, 41° N17° E, 1010 m) and (3) speleothems from the South of France and North Tunisia (Chauvet, Villars and La Mine speleothems, Genty et al., 2006). Thanks to the good absolute chronological constraints from annual layer counting in NGRIP, 14C and tephra layers in MD90-917 and U-Th dating in speleothems, we can provide a precise chronological framework for the last 50 ka (ie. thousand years before present). Then, we present different tests on how to combine the records from the different archives and give the most plausible scenario for the sequence of events at different latitudes over the last deglaciation. Bazin, L., Landais, A. ; Lemieu¬-Dudon, B. ; Kele, H. T. M. ; Veres, D. ; Parrenin, F. ; Martinerie, P. ; Ritz, C. ; Capron, E. ; Lipenkov, V. ; Loutre, M.-F. ; Raynaud, D. ; Vinther, B. ; Svensson, A. ; Rasmussen, S. ; Severi, M. ; Blunier, T. ; Leuenberger, M. ; Fischer, H. ; Masson-¬-Delmotte, V. ; Chappellaz, J. & Wolff, E., An optimized multi-proxy, multi-site Antarctic ice and gas orbital chronology (AICC2012): 120-800 ka,Clim. Past 9, 1715-1731, 2013. Genty, D., Blamart, D., Ghaleb B., Plagnes, V., Causse, Ch., Bakalowicz, M., Zouari, K., Chkir, N., Hellstrom, J., Wainer, K., Bourges, F., Timing and dynamics of the last deglaciation from European and North African δ13C stalagmite profiles - comparison with Chinese ans South Hemisphere stalagmites, Quat. Sci. Rev. 25, 2118-2142, 2006. Lemieux-Dudon, B. ; Blayo, E. ; Petit, J.-R. ; Waelbroeck, C. ;Svensson, A. ; Ritz, C. ; Barnola, J.-M. ; Narcisi, B.M. ; Parrenin, F., Consitent dating for Antarctic and Greenland ice cores, Quat. Sci. Rev. 29(1-2), 2010. Veres, D. ; Bazin, L. ; Landais, A. ; Lemieux-Dudon, B. ; Parrenin, F. ; Martinerie, P. ; Toyé Mahamadou Kele, H. ; Capron, E. ; Chappellaz, J. ; Rasmussen, S. ; Severi, M. ; Svensson, A. ; Vinther, B. & Wolff, E., The Antarctic ice core chronology (AICC2012): an optimized multi-parameter and multi-site dating approach for the last 120 thousand years, Clim. Past, 9, 1733-1748, 2013.
Age and speleogenesis of epigenic gypsum caves in the northern Apennines (Italy)

NASA Astrophysics Data System (ADS)

Columbu, Andrea; Chiarini, Veronica; De Waele, Jo; Drysdale, Russell; Forti, Paolo; Hellstrom, John; Woodhead, Jon

2016-04-01

Triassic and Messinian gypsum beds host the majority of the caves in the eastern flank of the northern Apennines. To date, more than six hundreds voids have been mapped, including the longest known epigenic gypsum cave system in the world (Spipola-Acquafredda, ~11 km of tunnels) (De Waele et al., 2013). Superimposed caves are typically sub-horizontal (Klimchouk, 2000) and connected through vertical shafts, reflecting the palaeo base-level variations. When preserved, river terraces at the surface lie at the same palaeo altitude of the base level and horizontal cave passages. Notwithstanding the well-known geology of the area known (Vai and Martini, 2001), the age of these caves has been greatly underestimated in the past. Considering the rapid dissolution of the gypsum and uplifting of the area, the start of speleogenesis activity was considered to have occurred during the last glacial age. The age of karst voids can be only indirectly estimated by the dating of the infilling sediments. U-Th dating on carbonate speleothems provides high-precision and accurate ages (Hellstrom, 2003; Scholz and Hoffmann, 2008). We thus applied this methodology to 20 speleothems coming from 14 different caves belonging to the Monte Tondo, Spipola Acquafredda, Castelnuovo, Stella-Rio Basino and Brisighella systems. The results show that: i) caves were forming since at least ~300 ka; ii) the peak of speleogenesis was reached during relatively cold climate stages, when rivers formed terraces at the surface and aggradation caused paragenesis in the stable cave levels (Columbu et al., 2015). Besides the significant contribution to the understanding of the Apennines evaporite karst evolution, this study (and its further advancement) may also refine knowledge of the local vs regional uplifting rates and base-level variations since the late Pleistocene (Wegmann and Pazzaglia, 2009). References Columbu, A., De Waele, J., Forti, P., Montagna, P., Picotti, V., Pons-Branchu, E., Hellstrom, J., Bajo, P., and Drysdale, R., 2015, Gypsum caves as indicators of climate-driven river incision and aggradation in a rapidly uplifting region: Geology. De Waele, J., Fabbri, F., Forti, P., Lucci, P., and Marabini, S., 2013, Evoluzione speleogenetica del sistema carsico del re Tiberio (Vena del gesso Romagnola): I gessi e la cava di Monte Tondo. Memorie dell'istituto Italiano di speleologia. Hellstrom, J., 2003, Rapid and accurate U/Th dating using parallel ion-counting multi-collector ICP-MS.: Journal of Analytical Atomic Spectrometry, v. 18. Klimchouk, A. B., 2000, Speleogenesis in noncarbonate lithologies: In: Klimchouk, A.B., Ford, D.C., Palmer, A.N., Dreybrodt, W. (Eds.) Speleogenesis, evolution of karst aquifers, p. 430-442. Scholz, D., and Hoffmann, D., 2008, 230Th/U-dating of fossil corals and speleothems: Quat. Sci. J, v. 57, p. 52. Vai, G. B., and Martini, I. P., 2001, Anatomy of an orogen: The Apennines and adjacent Mediterranean:: Dordrecht, Netherlands, Kluwer Academic Publishers,, p. 631. Wegmann, K. W., and Pazzaglia, F. J., 2009, Late Quaternary fluvial terraces of the Romagna and Marche Apennines, Italy: climatic, lithologic, and tectonic controls on terrace genesis in an active orogen: Quaternary Science Reviews, v. 28, no. 1, p. 137-165.
Evaluating the reliability of Late Quaternary landform ages: Integrating 10Be cosmogenic surface exposure dating with U-series dating of pedogenic carbonate on alluvial and fluvial deposits, Sonoran desert, California

NASA Astrophysics Data System (ADS)

Blisniuk, K.; Sharp, W. D.

2015-12-01

To assess the reliability of Quaternary age determinations of alluvial and fluvial deposits across the Sonoran Desert (Coachella Valley and Anza Borrego) in southern California, we applied both 10Be exposure age dating of surface clasts and U-series dating of pedogenic carbonate from subsurface clast-coatings to the same deposits. We consider agreement between dates from the two techniques to indicate reliable age estimates because each technique is subject to distinct assumptions and therefore their systematic uncertainties are largely independent. 10Be exposure dates should yield maximum ages when no correction is made for inheritance and post-depositional erosion is negligible. U-series dating, in contrast, provides minimum dates because pedogenic carbonate forms after deposition. Our results show that: (1) For deposits ca. 70 ka or younger, 10Be and U-series dates were generally concordant. We note, however, that in most cases U-series soil dates exceed 10Be exposure dates that are corrected for inheritance when using 10Be in modern alluvium. This suggests that 10Be concentrations of modern alluvium may exceed the 10Be acquired by late Pleistocene deposits during fluvial transport and hillslope residence (i.e., Pleistocene inherited 10Be). (2) For deposits older than ~70 ka, U-series dates are significantly younger than the 10Be dates. This implies that U-series dates in this region may significantly underestimate the depositional age of older alluvium, probably because of delayed onset of deposition, slow accumulation, or poor preservation of secondary carbonate in response to climatic controls. Thus, whenever possible, multiple dating methods should be applied to obtain reliable ages for late Quaternary deposits.
Climate reconstruction from Barrow Island, Western Australia

NASA Astrophysics Data System (ADS)

Placzek, C.; Coningham, K.; Turner, L.; Veth, P.; Ditchfield, K.; Wurster, C. M.; Kendrick, P.

2016-12-01

Barrow Island ( 20.7°S) is ideally situated to register the first coastal occupations in Australia as well as peoples' responses to major changes in sea level, climate and eventual isolation from critical resources on the mainland. Its location in the arid region between monsoonal and extratropical rainfall belts also imply that Barrow Island may have experienced dramatic changes in precipitation over the period of human occupation. Boodie cave has been the focus of Barrow Island Archeological Project and records a rich record of human occupation. Also present at Boodie cave are significant quantities of water-lain cave carbonates (flowstones, stalactites, and stalagmites). Active (modern) deposition of such carbonates is limited to very small encrustations and consists primarily of stalactites that are less than 5 cm in diameter. This situation indicates that deposition of significant carbonates is indicative of wetter conditions at Barrow Island and dating of these carbonates using the U/Th method provides a record of wet intervals at Barrow Island over the last 120 thousand years. In addition to ages from flowstones, three complete speleothems were collected Ledge Cave for climatic reconstruction using stable isotopes. Ledge cave is large subterranean with high relative humidity (>98%) and abundant, but largely inactive speleothems. The wettest interval in our cave carbonate record predates stratigraphic units with cultural material, but indicates that wet intervals on Barrow Island were broadly coincidental with lake expansions on the Australian mainland. In particular, a very wet interval between 120 and 90 ka is recorded in two of the Ledge Cave speleothems. The Barrow Island speleothem record suggests that displacement of the Intertropical Convergence Zone (ITCZ) and the strength of the Indo-Australian monsoon may have been the most important influence on water balance at Barrow Island. Continued development of these climate archives will offer insights into climate that is directly applicable to the unique human occupation record also preserved at this site.
High-Resolution Speleothem Records of the Indian Ocean Monsoon Variability of the Last 6 ka and 0,5 ka From Soqotra Island, Yemen

NASA Astrophysics Data System (ADS)

de Geest, P.; Verheyden, S.; Cheng, H.; Edwards, L. R.; Keppens, E.

2004-12-01

Soqotra is an arid tropical island in the Indian Ocean, situated between the Horn of Africa and the Arabian Peninsula. The inter-tropical convergence zone (ITCZ) passes there twice each year, resulting in a bi-annual rainy season. High-resolution \\delta18O and \\delta13C ratios of speleothems from two different caves are used to reconstruct changes in the Monsoon intensity and/or variability. Based on 10 TIMS 234U/230Th dating, two active speleothems from Hoq (S-STM1) and Kazekas Caves (S-STM5) have formed over a period of 6 ka BP and 0,5 ka BP, respectively. To obtain a detailed climate reconstruction more than 1000 \\delta13C and \\delta18O measurements were carried out, providing a time resolution between 2,5 and 10 years. In S-STM1 \\delta18O -values range between -4,5\\permil and -1,5\\permil and \\delta13C -values between -10,5\\permil and -5,5\\permil; while for S-STM5 these values range respectively between -4\\permil and -2\\permil and -7\\permil and -3\\permil (vs VPDB). Based on the comparison between \\delta18O excursions and historical meteorological data, the amount of precipitation is reflected in the \\delta18O signal. Different mechanisms for the \\delta13C are considered, such as a diminution of the C4-type vegetation during droughts, resulting in more positive \\delta13C -value or kinetic effects during the calcification process itself. Throughout the time series, co-variation occur between \\delta13C and \\delta18O -values (R2= 0,69) exhibiting long term (millennial) and short term (decadal) variations. In both stalagmites, layers of white porous calcite (WPC) (0,1-0,5mm) and dark dense calcite (DDC) (0,01-0,1mm) alternate, most probably due to seasonal variations. The WPC has more positive \\delta13C and \\delta18O -values, while the DDC shows more negative values, clearly demonstrated by high-resolution micro sampling up to a monthly to bi-weekly resolution. A positive correlation between the greyscale variations in the calcite fabric, the presumably annual growth banding and the inverse stable isotope ratios records support this hypothesis. During dry periods, less precipitation enters the cave-system, resulting in a whitish porous calcite deposition, thinner annual banding and more negative stable isotope ratios and vice versa. To better understand the climatic significance of these records, adapted Environmental Data Acquisition Systems (EDAS) are installed in and near Hoq Cave to obtain information on the actual transfer functions between climate and the proxy data in our speleothems.

Impacts of climate change on Middle Eastern societies over the last 2700 years: new results from the Gejkar speleothem, Iraq

NASA Astrophysics Data System (ADS)

Flohr, Pascal; Fleitmann, Dominik; Bosomworth, Matt; Cheng, Hai; Sadekov, Aleksey; Matthews, Roger; Matthews, Wendy; Black, Stuart; Edwards, Lawrence

2016-04-01

Climatic and environmental changes are often cited as a major factor for past social, economic, and political changes. This is especially relevant in the semi-arid to arid Middle East, where, however, only few precisely dated, high-resolution climate records are available. Here we present new results from an up to annually resolved stalagmite from Gejkar Cave in the Kurdish Regional Government of Iraq region. Based on Uranium-series dating and annual layer counts, the record dates back ~2700 years, and its annual layer thickness and carbon and oxygen isotope profile appear indicative of precipitation and effective moisture. We also assess if observed decadal to multi-decadal shifts in precipitation are synchronous with socio-economic changes as observed in the archaeological and historical record in the wider Middle East over the last 2000 years, such as the largely prosperous Roman and Byzantine periods, the Seljuq invasion, and the decline of the Ottoman Empire.
A colluvium - travertine sedimentary succession from the Tibetan Plateau: dating and climatic significance

NASA Astrophysics Data System (ADS)

Meyer, Michael; Wang, Zhijun; Schlütz, Frank; Hoffmann, Dirk; May, Jan-Hendrik; Aldenderfer, Mark

2014-05-01

Morphodynamics and sedimentation on the Tibetan Plateau are strongly controlled by cold-arid climate conditions and distinct freeze-thaw cycles. In such a periglacial environment mass-wasting processes are dominant on mountain slopes, causing thick successions of talus and colluvium to accumulate. While periglacial slope dynamics are ubiquitous on the plateau today, they were probably much more intense during the various cold stages of the Late Pleistocene. However, the exact nature as well as the timing and duration of such temperature controlled slope dynamics on the Tibetan plateau are not well constrained. Travertines are secondary carbonates precipitated from hydrothermal springs. On the Tibetan Plateau these types of spring deposits form along neotectonic faults, where super-saturated ground water can penetrate onto the surface, facilitating degassing and carbonate precipitation. Spring carbonate formation further requires non-permanently frozen ground and reasonable humid conditions in order to recharge the ground water aquifer. Travertines hold potential for palaeoenvironmental reconstruction, because they are dateable via U-series techniques and their geochemical, biological and petrographic signature can be used to extract high resolution palaeoenvironmental information. Due to a dense network of neotectonic faults on the Tibetan plateau, travertines are relatively common. Nevertheless, the potential of these hydrothermal spring deposits as an archive for palaeoenvironmental change on the plateau has yet to be explored. Here we present the first results obtained for an unusual, non-continuous sediment sequence encountered in southern Tibet at an altitude of 4200 m asl. near Chusang village, i.e. a ca. 200 m thick succession of periglacial colluvium alternating with travertine deposits. Preliminary data indicate that travertine deposition at the Chusang hydrothermal spring occurred periodically throughout the Late Pleistocene and extensive travertine precipitation was also responsible for preserving old colluvial sediment. We combine U-series disequilibrium dating with optically stimulated luminescence dating and radiocarbon dating to constrain the depositional history of this unique sediment sequence. Sedimentological logging and geomorphological mapping is used to understand past depositional processes and environmental constraints. Comparison to published high resolution climate records that are continuous in nature (e.g. speleothem records from adjacent catchments and regions) will allow us to link this clastic-chemical sediment sequence into the broader palaeoclimatic framework of High Asia.
Could the collapse of a massive speleothem be the record of a large paleoearthquake?

NASA Astrophysics Data System (ADS)

Valentini, Alessandro; Pace, Bruno; Vasta, Marcello; Ferranti, Luigi; Colella, Abner; Vassallo, Maurizio

2016-04-01

Earthquake forecast and seismic hazard models are generally based on historical and instrumental seismicity. However, in regions characterized by moderate strain rates and by strong earthquakes with recurrence longer than the time span covered by historical catalogues, different approaches are desirable to provide an independent test of seismologically-based models. We used non-conventional methods, such as the so-called "Fragile Geological Features", and in particular cave speleothems, for assessing and improving existing paleoseismological databases and seismic hazard models. In this work we present a detailed study of a massive speleothem found collapsed in the Cola Cave (Abruzzo region, Central Apennines, Italy) that could be considered the record of a large paleoearthquake. Radiometric dating and geotechnical measurements are carried out to characterize the collapse time and the mechanical properties of speleothem. We performed theoretical and numerical modelling in order to estimate the values of the horizontal ground acceleration required to failure the speleothems. In particular we used a finite element method (FEM), with the SAP200 software, starting from the detailed geometry of the speleothem and its mechanical properties. We used several individual seismogenic source geometries and four different ground motion prediction equations to calculate the possible response spectra. We carried out also a seismic noise survey to understand and quantify any ground motion amplification phenomenon. The results suggest two faults located in the Fucino area as the most probable causative sources of the cave speleothem collapses, recorded ~4-5 ka ago, with a Mw=6.8 ± 0.2. Our approach contributes to assess the existence of past earthquakes integrating the classical paleoseismological trenches techniques, and to attribute the retrieved event to geometrically-defined individual seismogenic sources, which represents a key contribution to improve fault-based seismic hazard models.
CO 2 release variations during the last 2000 years at the Colli Albani volcano (Roma, Italy) from speleothems studies

NASA Astrophysics Data System (ADS)

Tuccimei, P.; Giordano, G.; Tedeschi, M.

2006-03-01

The Colli Albani is the quiescent volcano that dominates the southwestern skyline of Roma (Italy). The last eruption occurred during the Holocene, from the eccentric Albano maar, along its western slope. The volcano is presently affected by cyclic seismic swarms, ground uplift and diffuse CO 2 degassing. The degassing has caused several deadly incidents during the last years and constitutes a major civil protection concern, as the volcano slopes are densely inhabited. Nevertheless, the volcano does not have a permanent monitoring network, and the background level and anomalous CO 2 levels, the relationship between the gas release and the seismic and ground deformation activity at the Colli Albani are still to be defined. The aim of this work is to define the historical record of CO 2 release. Evidences of deep CO 2 periodic release during the last 2000 years in the area of Colli Albani volcano (Roma, Italy) are offered from speleothems studies. A Roman-age stone mine, now used for mushroom cultivation, is decorated with actively growing speleothems, characterised by depositional hiatuses. Different levels of four stalactites, separated by depositional unconformities, and several samples from a single depositional cycle belonging to a stalagmite have been dated by U/Th method and analysed for their O and C isotopic composition. Eight cycles of deposition have been identified from 90-110 A.D. to 1350-1370 A.D., some of which are recognised across different speleothems. The age gap dividing different growth layers is in the order of one to few hundred years giving a temporal span for periodic interruption of speleothems deposition. O and C isotopic analyses performed on the samples collected from a single cycle (the oldest) have shown that the composition of the mother solutions was initially mainly meteoric and that a progressive increase in the input of a deep component rich in CO 2 (up to a proportion of 20-30%) occurred just before the interruption of the speleothem deposition. This could be due to a progressive increase of the acidity of the water solutions that caused the undersaturation of fluids. If we extrapolate this mechanism to the other cycles of deposition, being characterised by analogue isotopic compositions, we can hypothesise periods of deposition interrupted by episodes of CO 2 release which in the Colli Albani volcano are often recorded in coincidence with earthquakes. Therefore we have correlated the hiatuses with some of the largest historical earthquakes interesting to the city of Rome.
Interpretation of orbital scale variability in mid-latitude speleothem δ18O: Significance of growth rate controlled kinetic fractionation effects

NASA Astrophysics Data System (ADS)

Stoll, Heather; Mendez-Vicente, Ana; Gonzalez-Lemos, Saul; Moreno, Ana; Cacho, Isabel; Cheng, Hai; Edwards, R. Lawrence

2015-11-01

Oxygen isotopes have been the most widely used climate indicator in stalagmites, applied to reconstruct past changes in rainfall δ18O and cave temperature. However, the δ18O signal in speleothems may also be influenced by variable kinetic fractionation effects, here conceived broadly as fractionation effects not arising from temperature variation. The regional reproducibility of speleothem δ18O signals has been proposed as a way to distinguish the δ18O variations arising directly from changes rainfall δ18O and cave temperature, from variations due to kinetic effects which may nonetheless be influenced by climate. Here, we compare isotopic records from 5 coeval stalagmites from two proximal caves in NW Spain covering the interval 140 to 70 ka, which experienced the same primary variations in temperature and rainfall δ18O, but exhibit a large range in growth rates and temporal trends in growth rate. Stalagmites growing at faster rates near 50 μm/yr have oxygen isotopic ratios over 1‰ more negative than coeval stalagmites with very slow (5 μm/yr) growth rates. Because growth rate variations also occur over time within any given stalagmite, the measured oxygen isotopic time series for a given stalagmite includes both climatic and kinetic components. Removal of the kinetic component of variation in each stalagmite, based on the dependence of the kinetic component on growth rate, is effective at distilling a common temporal evolution of among the oxygen isotopic records of the multiple stalagmites. However, this approach is limited by the quality of the age model. For time periods characterized by very slow growth and long durations between dates, the presence of crypto-hiatus may result in average growth rates which underestimate the instantaneous speleothem deposition rates and which therefore underestimate the magnitude of kinetic effects. The stacked growth rate-corrected speleothem δ18O is influenced by orbital scale variation in the cave temperature and the δ18O of the ocean moisture source, but also by temporally variable fractionation in the hydrological cycle. The most salient trend is increased hydrological fractionation during the GI-22 period, when warmer sea surface temperatures in the subtropical Atlantic moisture source region may have favored greater precipitation amounts.
Millennial-scale variations in western Sierra Nevada precipitation during the last glacial cycle MIS 4/3 transition

NASA Astrophysics Data System (ADS)

Oster, Jessica L.; Montañez, Isabel P.; Mertz-Kraus, Regina; Sharp, Warren D.; Stock, Greg M.; Spero, Howard J.; Tinsley, John; Zachos, James C.

2014-07-01

Dansgaard-Oeschger (D-O) cycles had far-reaching effects on Northern Hemisphere and tropical climate systems during the last glacial period, yet the climatic response to D-O cycles in western North America is controversial, especially prior to 55 ka. We document changes in precipitation along the western slope of the central Sierra Nevada during early Marine Oxygen Isotope Stages (MIS) 3 and 4 (55-67 ka) from a U-series dated speleothem record from McLean's Cave. The timing of our multi-proxy geochemical dataset is coeval with D-O interstadials (15-18) and stadials, including Heinrich Event 6. The McLean's Cave stalagmite indicates warmer and drier conditions during Greenland interstadials (GISs 15-18), signified by elevated δ18O, δ13C, reflectance, and trace element concentrations, and less radiogenic 87Sr/86Sr. Our record extends evidence of a strong linkage between high-latitude warming and reduced precipitation in western North America to early MIS 3 and MIS 4. This record shows that the linkage persists in diverse global climate states, and documents the nature of the climatic response in central California to Heinrich Event 6.
Speleothems as proxy for the carbon isotope composition of atmospheric CO2

NASA Astrophysics Data System (ADS)

Baskaran, M.; Krishnamurthy, R. V.

1993-12-01

We have measured the stable isotope ratios of carbon in a suite of recent cave deposits (less than 200 years) from the San Saba County, Texas, USA. The methodology for dating these deposits using excess Pb-210 was recently established (Baskaran and Iliffe, 1993). The carbon isotope ratios of these samples, spanning the time period approximately 1800-1990 AD, reflect the carbon isotope ratio of atmospheric CO2 for the same period. The pathways by which the delta C-13 of atmospheric CO2 is imprinted on these speleothems can be explained using a model developed by Cerling (1984). The results suggest that the carbon isotope ratios of speleothems can be used to develop long-term, high-resolution chronologies of the delta C-13 of atmospheric CO2 and, by implication, the concentration of the atmospheric CO2.
Dansgaard-Oeschger events and their reflection in speleothems (Hans Oeschger Medal Lecture)

NASA Astrophysics Data System (ADS)

Bar-Matthews, Miryam

2013-04-01

Speleothems in karstic cave environments form by passage of meteoric water through the overlying soils, where the water dissolves CO2 to form carbonic acid, which in turn dissolves the host-rock carbonate. Degassing of the carbonate supersaturated meteoric water leads to the formation of calcite speleothems, which therefore can be considered as the end product in the much larger sea-atmosphere-land cycle. Their stable isotopic and geochemical composition reflect the environmental conditions above the cave, which in turn depend on larger scale parameters such as isotopic composition of the rainfall source, atmospheric storm patterns, ocean-land heat transfer. In this talk I specifically address the potential of using speleothems to look at short term climatic events: the Dansgaard-Oeschger (D-O) events; rapid climate changes first observed in Greenland ice cores by Hans Oeschger with Willi Dansgaard and suggested to occur during the last glacial period. Many researches now show that D-O events are globally synchronous and can be identified in the marine and terrestrial climate records. Given, the ability to accurately date speleothems and to perform high-resolution studies of stable isotopes, trace elements and various other proxies (e.g., fluid inclusions, 'clumped isotopes' thermometry), it has become clear that speleothems enable us to better date the exact timing of D-O events and to understand the climatic response on land in different parts of the world to their occurrence, i.e., to address specific questions on the marine-atmosphere interaction, sea surface temperature, rainfall generation and their influence on human habitation and dispersal. Since the stable isotopic signal in speleothems primarily is a function of temperature and isotopic composition of rainfall, short time climatic events can be registered in fast growing speleothems. Indeed recent studies clearly demonstrate that D-O events are registered in speleothems, for example, vegetation changes in Western Europe show good correlation with D-O events1; changes in the monsoon intensity during glacials are recorded in Chinese speleothems2; the response of the Indian Ocean hydrological cycle to temperature changes in Greenland ice cores are recorded in speleothems from Oman3. D-O events are also registered in the mid-latitude, Eastern Mediterranean (EM) speleothems and marine cores4,5,6. Of special interest are the responses to D-O 15 and 14. The multiple proxy speleothems record from the southern extension of the high altitude Alpine karst in Mount Hermon7, shows that from ~56 ka to 51 ka several major pulses of wet and warm episodes occurred. This is expressed by vegetation development, and significant snow melting that drained a large amount of water to the Dead Sea Rift Valley. Speleothems from the Middle-East and Arabia demonstrate that during these D-O wet pulses, the African monsoon and westerly storm/rainfall systems intensified, resulting in the 'greening' of the Sahara. A major question that is currently under investigation using speleothems is the recent Modern Human migration out of Africa at 60-50 ka into the Levant and Europe: is this migration is related to D-O 15 and 14? So called "D-O events" are also found in mid-Holocene speleothems from Soreq Cave, central Israel8. High-resolution (~3 to 20 years) speleothems records reveal a ~1500 years cyclicity pattern similar to Bond cycles. Superimposed on these cycles are rapid climate changes (RCC) resembling the structure of D-O events, The characteristic "dogtooth" shaped isotopic changes indicate rather fast (~50-100 years) trends of increase in rainfall (up to ~30%) and vegetation development, followed by gradual aridification over a longer period of ~100-500 years. This climate oscillation is also expressed in the archeological cultural record. It is not clear yet what cause these RCC, and it is possible that of all potential climate forcing mechanisms, the most probable was solar variability, but this needs to be further investigated. 1Genty et al., 2003 Nature, 833-837; 2Wamg et al., Nature, 2008, 1090-1093; 3Burns et al., 2003, Science, 301, 1365-1367; 4Almogi-Labin et al., 2009 Quat. Sci. Rev 28, 2882-2896; 5Bar-Matthews et al., 1998 EPSL 166, 85-95; 6Bar-Matthews et al., 2003 GCA, 67, 3181-3199;7Ayalon et al., 2013 Quat.Sci. Rev., 59, 43-56. 8Bar-Matthews and Ayalon, 2011 The Holocene 21, 163-171;
Climatic and environmental controls on speleothem oxygen-isotope values

NASA Astrophysics Data System (ADS)

Lachniet, Matthew S.

2009-03-01

Variations in speleothem oxygen-isotope values ( δ18O) result from a complicated interplay of environmental controls and processes in the ocean, atmosphere, soil zone, epikarst, and cave system. As such, the controls on speleothem δ18O values are extremely complex. An understanding of the processes that control equilibrium and kinetic fractionation of oxygen isotopes in water and carbonate species is essential for the proper interpretation of speleothem δ18O as paleoclimate and paleoenvironmental proxies, and is best complemented by study of site-specific cave processes such as infiltration, flow routing, drip seasonality and saturation state, and cave microclimate, among others. This review is a process-based summary of the multiple controls on δ18O in the atmosphere, soil, epikarst, and speleothem calcite, illustrated with case studies. Primary controls of δ18O in the atmosphere include temperature and relative humidity through their role in the multiple isotope "effects". Variability and modifications of water δ18O values in the soil and epikarst zones are dominated by evaporation, mixing, and infiltration of source waters. The isotopically effective recharge into a cave system consists of those waters that participate in precipitation of CaCO 3, resulting in calcite deposition rates which may be biased to time periods with optimal dripwater saturation state. Recent modeling, experimental, and observational data yield insight into the significance of kinetic fractionation between dissolved carbonate phases and solid CaCO 3, and have implications for the 'Hendy' test. To assist interpretation of speleothem δ18O time series, quantitative and semi-quantitative δ18O-climate calibrations are discussed with an emphasis on some of the difficulties inherent in using modern spatial and temporal isotope gradients to interpret speleothems as paleoclimate proxy records. Finally, several case studies of globally significant speleothem paleoclimate records are discussed that show the utility of δ18O to reconstruct past climate changes in regions that have been typically poorly represented in paleoclimate records, such as tropical and subtropical terrestrial locations. The new approach to speleothem paleoclimatology emphasizes climate teleconnections between regions and attribution of forcing mechanisms. Such investigations allow paleoclimatologists to infer regional to global-scale climate dynamics.
A high-resolution Holocene speleothem record from NE Romania: the nexus of Arctic and North Atlantic atmospheric circulations

NASA Astrophysics Data System (ADS)

Constantin, S.; Pourmand, A.; Moldovan, O.; Sharifi, A.; Mehterian, S.; Swart, P. K.

2017-12-01

The Romanian Carpathians act as a geomorphological barrier between different atmospheric circulation systems over Central and Eastern Europe; the NW of Romania lies under the remote influence of the North Atlantic oscillation, while the NE is influenced by the Arctic climate. In NW Romania, previous stable isotope studies of speleothems have not yielded a clear account of abrupt climate oscillations during the Holocene. Here we present results from a stalagmite collected from the Tauşoare Cave, located in NE Carpathians. The chronology of stalagmite T141 is based on 15 high-precision Th/U dates ranging between 32 and 1.1 ka with a continuous growth between 13.3 and 1.1 ka. The portion of the record within the Holocene was analyzed for δ18O and δ13C at a resolution ranging between 15 to 200 years/sample. The resulting δ18O record captures the Younger Dryas (YD) event centered at 12.9 ka, with δ18O values about 4 ‰ more depleted than those corresponding to the Holocene Climatic Optimum. The 8.2 ka event appears to be also captured in the record, although less prominent. The T141 isotope record is significantly different when compared to coeval records measured in speleothems from NW Carpathians, which do not exhibit marked changes during the YD or 8.2 ka events. This is likely due to the contrasting effect of temperature and atmospheric transport on δ18O signal in NW Romania. Within a distance of 200 km to the east, on the eastern flank of the Carpathian range, the δ18O signal of the Arctic circulation appears to be more prominent and clearly exhibits a positive relationship with temperature changes.
Abrupt Climate Change in the Southern Great Plains during the Last Glacial Interval

NASA Astrophysics Data System (ADS)

Housson, A. L.; Maupin, C. R.; Roark, B.; Shen, C. C.; Baykara, O.; White, K.; Kampen-Lewis, S. V.; McChesney, C. L.

2016-12-01

Understanding how the climate of the North American Great Plains may change in the future is of tremendous socioeconomic importance, yet the regional response to previous abrupt global climate events, such as the Dansgaard-Oeschger (DO) cycles of the last glacial interval, are poorly known. Here we present two absolutely dated (U/Th), partially replicated oxygen isotope (δ18O) records from calcite speleothems in central Texas (30° N, 98° W) that grew during marine isotope stage 3 (MIS 3) (31 to 49 ky BP). The study site experiences boreal spring and fall maxima in precipitation with rainfall moisture sourced almost exclusively from the Gulf of Mexico. The two samples exhibit reproducible δ18O means and variability during overlapping growth intervals. Weak correlations between paired oxygen and carbon isotopic values coupled with reproducible δ18O strongly suggest that dripwater δ18O and calcite formation temperatures are the primary drivers of speleothem δ18O variations through time. We interpret more depleted (enriched) δ18O values to reconstruct warmer and wetter (cooler and drier) conditions based on observations of modern rainfall stable isotope variations at the study site. We find that warmer and wetter conditions in the Southern Plains are contemporaneous with MIS 3 DO interstadials, while cooler and more arid conditions prevail during stadials and Heinrich Events 4 and 5. Our results show a response opposite that of hydrologic reconstructions from the American Southwest, where wetter conditions occur with stadial conditions. Future work includes exploration of paleoclimate model results to examine potential mechanisms responsible for this opposite phasing. Our speleothem data indicate that further intensification of rainy seasons in the Southern Plains should not be ruled out as a response to anthropogenic global warming.
Final Technical Report for "High-resolution temporal variations in groundwater chemistry: Tracing the links between climate, hydrology, and element mobility in the vadose zone"

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jay L. Banner

2002-04-23

In spite of a developing emphasis on geochemical methods in studies of modern hydrologic systems, there have been few attempts to examine temporal fluctuations in groundwater chemistry and element mobility in the near-surface environment. Relatively little is known regarding how groundwaters evolve over 10 to 10,000 year scales, yet this knowledge provides a critical framework for understanding the links between climate and hydrology, the evolution of soils, and element migration in the vadose environment. Recent analytical advances allow U-series measurements to be applied to developing high-resolution chronologies of Pleistocene and Holocene carbonates. The potential of these new tools is examinedmore » through an analysis of two well-defined, active karst systems in (1) Barbados and (2) Texas. (1) The research effort on Barbados has developed methods of estimating recharge and inferring the spatial and seasonal distribution of recharge to the Pleistocene limestone aquifer on Barbados. A new method has been developed to estimate recharge based on oxygen isotope variations in rainwater and groundwater. Inter-annual recharge variations indicate that recharge is dependent on the distribution of rainfall throughout the year rather than total annual rainfall. Consequently, a year when rainfall occurs primarily during the peak wet season months (August through November) may have more recharge than a year when rainfall is more evenly distributed through the year. These results lay important groundwork for analysis of rainfall/recharge variations over different time scales based on isotopic records presently being constructed using Barbados speleothems from the same aquifer. (2) The chronology of speleothems (cave calcite deposits) from three caves across 130 kilometers in central Texas provides a 71,000-year record of temporal changes in hydrology and climate. Fifty-three ages were determined by mass spectrometric 238U - 230Th and 235U - 231Pa analyses. The accuracy of the ages and the closed-system behavior of the speleothems are indicated by inter-laboratory comparisons, concordancy of 230Th and 231Pa ages, and the result that all ages are in correct stratigraphic order. Over the last 71,000 years, the stalagmites have similar growth histories with alternating periods of relatively rapid and slow growth. The growth rates vary over more than two orders-of-magnitude, with three periods of rapid growth from 71-60 ka, 39-33 ka, and 24-12 ka. These growth rate shifts correspond in part with global glacial-interglacial climatic shifts. The potential effects of temporal variations in precession of Earth?s orbit on regional effective moisture may provide a mechanism for increased effective moisture coincident with the observed intervals of increased speleothem growth. The stalagmites all exhibit a large drop in growth rate between 15 and 12 ka, and very slow growth up to the present, consistent with drier climate during the Holocene. These results illustrate that speleothem growth rates can reflect the regional response of a hydrologic system to regional and global climate variability.« less
The Asian Monsoon Moisture Transportation Revealed by Two Cave Sites in Myanmar

NASA Astrophysics Data System (ADS)

Liu, G.; Wang, X.; Chiang, H. W.; Maung Maung, P.; Jiang, X.; Aung, L. T.; Tun, S. T.

2014-12-01

Here we present two well-resolved, calcite δ18O records on Myanmar speleothems. The samples were collected from a coastal site in southeastern Myanmar and a plateau site in central Myanmar, respectively. Chronologically determined by high-precision U/Th dating techniques, both records span a large portion of the past 40,000 years. The two records show similar millennial-scale oscillations during the last glacial period, which are also in-phase with the speleothem records from Chinese cave sites located in the downstream of Indian Monsoon trajectories. The δ18O values between the two profiles are virtually the same, ~ -7.5‰, during late Holocene, in concert with the numbers in modern rainfall at the two sites. However, in glacial time, the δ18O value of the central Myanmar record shifts from -6.5‰ to -8‰, approximately 2‰ lower than that in the coastal dataset, which varies from -4.5‰ to -6‰. We interpret the similarly low δ18O values during Holocene in both records as a result of strong monsoonal rainfall and water recycling particularly through forest transpiration. However in glacial time, with a possibly drier and less forested land, water recycling is weaker. Therefore, rainfall δ18O and subsequently speleothem δ18O appear a stronger geographical gradient, possibly dominated by the continental rainout effect. Our interpretation can be supported by the speleothem δ13C records from the two sites. Calcite δ13C from the coastal site varies slightly from ~-7‰ in the last glacial to ~-9‰ in Holocene. Whereas it shares a similar value to the coastal record during Holocene, the δ13C profile from the plateau site shows a much higher value, up to -0.7‰, during the glacial time. This suggests that the mountainous region in central Myanmar was likely dominated by C4 plants (e.g., grass) during the glacial time, while the same region is covered by forests today. Such change on vegetation type and coverage may influence the δ18O of recycling moisture transported further inland.
Volcanic forcing of the North Atlantic Oscillation over the last 2,000 years

NASA Astrophysics Data System (ADS)

Breitenbach, Sebastian F. M.; Ridley, Harriet E.; Lechleitner, Franziska A.; Asmerom, Yemane; Rehfeld, Kira; Prufer, Keith M.; Kennett, Douglas J.; Aquino, Valorie V.; Polyak, Victor; Goswami, Bedartha; Marwan, Norbert; Haug, Gerald H.; Baldini, James U. L.

2015-04-01

The North Atlantic Oscillation (NAO) is a principal mode of atmospheric circulation in the North Atlantic realm (Hurrell et al. 2003) and influences rainfall distribution over Europe, North Africa and North America. Although observational data inform us on multi-annual variability of the NAO, long and detailed paleoclimate datasets are required to understand the mechanisms and full range of its variability and the spatial extent of its influence. Chronologies of available proxy-based NAO reconstructions are often interdependent and cover only the last ~1,100 years, while longer records are characterized by low sampling resolution and chronological constraints. This complicates the reconstruction of regional responses to NAO changes. We present data from a 2,000 year long sub-annual carbon isotope record from speleothem YOK-I from Yok Balum Cave, Belize, Central America. YOK-I has been extensively dated using U-series (Kennett et al. 2012). Monitoring shows that stalagmite δ13C in Yok Balum cave is governed by infiltration changes associated with tropical wet season rainfall. Higher (lower) δ13C values reflect drier (wetter) conditions related to Intertropical Convergence Zone position and trade winds intensity. Comparison with NAO reconstructions (Proctor et al. 2000, Trouet et al. 2009, Wassenburg et al. 2013) reveals that YOK-I δ13C sensitively records NAO-related rainfall dynamics over Belize. The Median Absolute Deviation (MAD) of δ13C extends NAO reconstructions to the last 2,000 years and indicates that high latitude volcanic aerosols force negative NAO phases. We infer that volcanic aerosols modify inter-hemispheric temperature contrasts at multi-annual scale, resulting in meridional relocation of the ITCZ and the Bermuda-Azores High, altering NAO and tropical rainfall patterns. Decade-long dry periods in the 11th and the late 18th century relate to major high northern latitude eruptions and exemplify the climatic response to volcanic forcing by reorganization of atmospheric circulation over the North Atlantic. References Hurrell et al. (2003) An Overview of the North Atlantic Oscillation. Geophys. Monogr. 134 Kennett & Breitenbach et al. (2012) Development and Disintegration of Maya Political Systems in Response to Climate Change. Science 338, 788-791 Proctor et al. (2000) A thousand year speleothem proxy record of North Atlantic climate from Scotland. Clim. Dyn. 16, 815-820 Trouet et al. (2009) Persistent Positive North Atlantic Oscillation Mode Dominated the Medieval Climate Anomaly. Science 324, 78-80 Wassenburg et al. (2013) Moroccan speleothem and tree ring records suggest a variable positive state of the North Atlantic Oscillation during the Medieval Warm Period. Earth Planet. Sci. Lett. 375, 291-302
Millennial-Scale ITCZ Variability in the Tropical Atlantic and Dynamics of Amazonian Rain Forest

NASA Astrophysics Data System (ADS)

Wang, X.; Auler, A. S.; Edwards, R. L.; Cheng, H.; Shen, C.; Smart, P. L.; Richards, D. A.

2003-12-01

Precipitation in the Amazon Basin is largely related to the intertropical convergence zone (ITCZ) in the tropical Atlantic which undergoes a regular seasonal migration. We chose a site south of the present day rainforest in semiarid northeastern Brazil, in order to study the timing of pluvial periods when the southern extend of the ITCZ would have been much further south than today. Shifts in the ITCZ position may have influenced the dynamics of rain forest and species diversity. We collected speleothems from northern Bahia state, located southeast of Amazonia. Age determinations with U-series dating methods show that samples grew rapidly during relatively short intervals (several hundreds of years) of glacial periods in the last 210 kyr. In addition, paleopluvial phases delineated by speleothem growth intervals show millennial-scale variations. Pluvial phases coincide with the timing of weak East Asian summer monsoon intensities (Wang et al., 2001, Science 294: 2345-2348), which have been correlated to the timing of stadials in Greenland ice core records and Heinrich events (Bond and Lotti, 1995, Science 267: 1005-1010). Furthermore, these intervals correspond to the periods of light color reflectance of Cariaco Basin sediments from ODP Hole 1002C (Peterson et al., 2000, Science, 290: 1947-1951), which was suggested to be caused by a southward shift of the northernmost position of the ITCZ and decreased rainfall in this region. Abrupt precipitation changes in northeastern Brazil may be due to the southward displacement of the southernmost position of the ITCZ associated with atmosphere-ocean circulation changes caused by (1) an increase in northern high latitude-tropical temperature gradient (Chiang et al., 2003, Paleoceanography, in press), and/or (2) the bipolar seesaw mechanism (Broecker et al., 1998, Paleoceanography 13: 119-121) during these Heinrich events. Pluvial phases are also coincident with higher insolation at 10° S during austral autumn. This association implies that insolation may contribute to the southward shift of the ITCZ and enhanced precipitation in northeastern Brazil. The mean latitudinal migration of the ITCZ in the tropical Atlantic may force Amazon rain forest dynamics. Fossils and geomorphologic evidence found nearby indicate much wetter climates and possible tropical rainforest expansion to this locality in the past (Auler and Smart, 2001, Quaternary Research 55: 159-167). Furthermore, low δ 13C (around -11‰ ) values in speleothems suggest an extensive C3 forest coverage, different from current drought-resistant caatinga vegetation. During time of high rainfall, northeastern Brazil may act as a migration corridor between two species-rich communities, the Amazon Rain Forest and the Atlantic Rain Forest.
14C plateaus and global stratigraphic correlation during Termination IA

NASA Astrophysics Data System (ADS)

Sarnthein, M.; Grootes, P. M.; Kennett, J. P.; Nadeau, M.

2006-12-01

In search of a global 14C reference record for Termination IA, we analyzed three published 14C records with centennial-scale resolution, that provide independent evidence for calibrating the 14C time scale: (1) A sediment record from Cariaco Basin (ODP Site 1002) correlated to the U/Th-dated Hulu Cave record (Hughen et al., 2006), (2) a U/Th dated speleothem record from the Bahamas (Beck et al., 2001, 2006), and (3) a set of U/Th-dated coral ages (IntCal04 plus Fairbanks et al., 2005) that unfortunately lack data from 18-15 cal. ka. All these records exhibit significant changes in the slope of 14C vs. calendar ages, allowing us to define a suite of major and minor "14C plateaus" in each record, that in total occupy >70% of the 14C record between 19 and 14 cal. ka. Despite their different origin the three records are largely consistent. When dating resolution is sufficient, most plateaus show a characteristic internal structure incorporating 14C inversions, in particular near the onset of a plateau. Plateau boundary ages for the Cariaco record have a total range of uncertainty of 150-450 yr due to uncertainties with age calibration (Hughen et al., 2006), in addition to the range of dating resolution. During Termination IA, a period of dramatic climate change, these boundary ages should serve as datums for the global correlation of marine sediment records. Moreover, they are employed to deduce apparent paleoventil-ation ages and thus circulation patterns of surface and bottom water masses, as demonstrated for example from the northern Pacific and the Icelandic Sea.
Speleothem dating using Sulfur to Calcium ratio

NASA Astrophysics Data System (ADS)

Sabri, Raghid

2017-04-01

A speleothem sample from underground water tunnel in Nablus, Palestine, showed contamination from wastewater. The young sample has low concentration of Uranium and could not be dated with uranium thorium dating method. An alternative method was used to determine the age of the sample: lamina counting coupled with Sulfur to calcium ratio peaks counting. Sulfur and Calcium concentrations were measured using SEM-EDS to have a better resolution than the CNS analyzer. Assuming seasonal growth of laminations, it was possible to determine the primarily ages. The sinter was still growing during sampling in 2011. The counting reveals 271 laminae, for seasonal growth it means 135 years. In the 1959, it was observed that there is an unexpected peak of Sulfur to calcium ratio and this peak was repeated seasonally. The sulfur peak increased as a result of diesel use in the heating system during the winter season. For the youngest 117 laminae, 59 S/Ca peaks are observed. Each two lamination layers correspond to one peak. So, it was possible to determine the age of the sample using Sulfur to Calcium ratio.
Early-Mid Holocene climatic variations in Tasmania, Australia: multi-proxy records in a stalagmite from Lynds Cave

NASA Astrophysics Data System (ADS)

Xia, Qikai; Zhao, Jian-xin; Collerson, K. D.

2001-12-01

Mass spectrometric uranium-series dating and C-O isotopic analysis of a stalagmite from Lynds Cave, northern Tasmania, Australia provide a high-resolution record of regional climate change between 5100 and 9200 yr before present (BP). Combined δ18O, δ13C, growth rate, initial 234U/238U and physical property (color, transparency and porosity) records allow recognition of seven climatic stages: Stage I (>9080 yr BP) - a relatively dry period at the beginning of stalagmite growth evidenced by elevated 234U/238U; Stage II (9080-8600 yr BP) - a period of unstable climate characterized by high-frequency variability in temperature and bio-productivity; Stage III (8600-8000 yr BP) - a period of stable and moderate precipitation and stable and high bio-productivity, with a continuously rising temperature; Stage IV (8000-7400 yr BP) - the warmest period with high evaporation and low effective precipitation (rainfall less evaporation); Stage V (7400-7000 yr BP) - the wettest period with highest stalagmite growth and enhanced but unstable bio-productivity; Stage VI (7000-6600 yr BP) - a period with a significantly reduced precipitation and bio-productivity without noticeable change in temperature; Stage VII (6600-5100 yr BP) - a period of lowest temperature and precipitation marking a significant climatic deterioration. Overall, the records suggest that the warmest climate occurred between 8000 and 7400 yr BP, followed by a wettest period between 7400 and 7000 yr BP. These are broadly correlated with the so-called 'Mid Holocene optimum' previously proposed using pollen and lake level records. However, the timing and resolution of the speleothem record from Lynds Cave are significantly higher than in both the pollen and lake level records. This allows us to correlate the abrupt change in physical property, δ18O, δ13C, growth rate, and initial 234U/238U of the stalagmite at ˜8000 yr BP with a global climatic event at Early-Mid Holocene transition.
Correcting for initial Th in speleothems to obtain the age of calcite nucleation after a growth hiatus

NASA Astrophysics Data System (ADS)

Richards, D. A.; Nita, D. C.; Moseley, G. E.; Hoffmann, D. L.; Standish, C. D.; Smart, P. L.; Edwards, R.

2013-12-01

In addition to the many U-Th dated speleothem records (δ18O δ13C, trace elements) of past environmental change based on continuous phases of calcite growth, discontinuous records also provide important constraints for a wide range of past states of the Earth system, including sea levels, permafrost extent, regional aridity and local cave flooding. Chronological information about human activity or faunal evolution can also be obtained where calcite can be seen to overlie cave art or mammalian bones, for example. Among the important considerations when determining the U-Th age of calcite that nucleates on an exposed surface are (1) initial 230Th/232Th, which can be elevated and variable in some settings, and (2) growth rate and sub-sample density, where extrapolation is required. By way of example, we present sea level data based on U-Th ages of vadose speleothems (i.e. formed above the water table and distinct from 'phreatic' examples) from caves of the circum-Caribbean , where calcite growth was interrupted by rising sea levels and then reinitiated after regression. These estimates demand large corrections and derived sea level constraints are compared with alternative data from coral reef terraces, phreatic overgrowths on speleothems or indirect, proxy evidence from oxygen isotopes to constrain rates of ice volume growth. Flowstones from the Bahamas provide useful sea level constraints because they present the longest and most continuous records in such settings (a function of preservation potential in addition to hydrological routing) and also earliest growth post-emergence after sea level fall. We revisit estimates for sea level regression at the end of MIS 5 at ~ 80 ka (Richards et al, 1994; Lundberg and Ford, 1994) and make corrections for non-Bulk Earth initial Th contamination (230Th/232Th activity ratio > 10), based on isochron analysis of alternative stalagmites from the same settings and recent high resolution analysis. We also present new U-Th ages for contiguous layers sub-sampled from the first 2-3 mm of flowstone growth after the MIS 5 hiatus, using a sub-sample milling strategy that matches spatial resolution with maximum achievable precision (ThermoFinnigan Neptune MC-ICPMS methodology; 20-30 mg calcite, U = ~ 300 ng.g-1, 2σ age uncertainty is × 600 a at ~80 ka). Isochron methods are used to estimate the range of initial 230Th/232Th ratio and are compared with elevated values obtained from stalagmites from the same cave (Beck et al, 2001; Hoffmann et al, 2010). A similar strategy is presented for a stalagmite with much faster axial growth data, and the data are combined with additional sea level information from the same region to estimate the rate and uncertainty of sea level regression at the MIS stage 5/4 boundary. Elevated initial 230Th/232Th values have also been observed in a stalagmite from 6 m below present sea level in a cenote from the Yucatan, Mexico, where 5 phases of calcite between 10 and 5.5 ka are separated by serpulid worm tubes formed during periods of submergence. The transition between each phase provides constraints on age and elevation of relative sea level, but the former is hampered by the uncertainty of the high initial 230Th/232Th correction. We consider the possible sources of elevated Th ratios: hydrogenous, colloidal and carbonate or other detrital components.
A 10,000 yr record of high-resolution Paleosecular Variation from a flowstone of Rio Martino Cave, Northwestern Alps, Italy

NASA Astrophysics Data System (ADS)

Zanella, Elena; Tema, Evdokia; Lanci, Luca; Regattieri, Eleonora; Isola, Ilaria; Hellstrom, John C.; Costa, Emanuele; Zanchetta, Giovanni; Drysdale, Russell N.; Magrì, Federico

2018-03-01

Speleothems are potentially excellent archives of the Earth's magnetic field, capable of recording its past variations. Their characteristics, such as the continuity of the record, the possibility to be easily dated, the almost instantaneous remanence acquisition and the high time-resolution make them potentially unique high-quality Paleosecular Variation (PSV) recorders. Nevertheless, speleothems are commonly characterized by low magnetic intensities, which often limits their resolution. Here we present a paleomagnetic study performed on two cores from a flowstone from the Rio Martino Cave (Western Alps, Italy). U/Th dating indicates that the flowstone's deposition covers almost the entire Holocene, spanning the period ca. 0.5-9.0 ka, while an estimation of its mean growth rate is around 1 mm per 15 years. The flowstone is composed of columnar calcite, characterized by a highly magnetic detrital content from meta-ophiolites in the cave's catchment. This favorable geological context results in an intense magnetic signal that permits the preparation and measurement of thin (∼3 mm depth equivalent) samples, each representing around 45 yr. The Characteristic Remanent Magnetization (ChRM), isolated after systematic stepwise Alternating Field demagnetization, is well defined, with Maximum Angular Deviation (MAD) generally lower than 10°. Paleomagnetic directional data allow the reconstruction of the PSV path during the Holocene for the area. Comparison of the new data with archeomagnetic data from Italian archeological and volcanic records and using the predictions of the SHA.DIF.14k and pfm9k.1a global geomagnetic field models shows that the Rio Martino flowstone represents an excellent recorder of the Earth's magnetic field during the last 9,000 years. Our high resolution paleomagnetic record, anchored by a high-quality chronology, provides promising data both for the detection of short term geomagnetic field variations and for complementing existing regional PSV curves for the prehistoric period, for which well-dated data are still scarce.

Coastal cliffs, rock-slope failures and Late Quaternary transgressions of the Black Sea along southern Crimea

NASA Astrophysics Data System (ADS)

Pánek, Tomáš; Lenart, Jan; Hradecký, Jan; Hercman, Helena; Braucher, Règis; Šilhán, Karel; Škarpich, Václav

2018-02-01

Rock-slope failures represent a significant hazard along global coastlines, but their chronology remains poorly documented. Here, we focus on the geomorphology and chronology of giant rockslides affecting the Crimean Mountains along the Black Sea coast. Geomorphic evidence suggests that high (>100 m) limestone cliffs flanking the southern slopes of the Crimean Mountains are scarps of rockslides nested within larger deep-seated gravitational slope deformations (DSGSDs). Such pervasive slope failures originated due to lateral spreading of intensively faulted Late Jurassic carbonate blocks moving atop weak/plastic Late Triassic flysch and tuff layers. By introducing a dating strategy relying on the combination of the uranium-thorium dating (U-Th) of exposed calcareous speleothems covering the landslide scarps with the 36Cl exposure dating of rock walls, we are able to approximate the time interval between the origin of incipient crevices and the final collapse of limestone blocks that exposed the cliff faces. For the three representative large-scale rockslides between the towns of Foros and Yalta, the initiation of the DSGSDs as evidenced by the widening of crevices and the onset of speleothem accumulation was >300 ka BP, but the recent cliff morphology along the coast is the result of Late Pleistocene/Holocene failures spanning ∼20-0.5 ka BP. The exposures of rockslide scarps occurred mostly at ∼20-15, ∼8, ∼5-4 and ∼2-0.5 ka, which substantially coincide with the last major Black Sea transgressions and/or more humid Holocene intervals. Our study suggests that before ultimate fast and/or catastrophic slope failures, the relaxation of rock massifs correlative with karstification, cracks opening, and incipient sliding lasted on the order of 104-105 years. Rapid Late Glacial/Holocene transgressions of the Black Sea likely represented the last impulse for the collapse of limestone blocks and the origin of giant rockslides, simultaneously affecting the majority of the SW coast of the Crimean Peninsula.
ESR dating of tooth enamel: comparison with {230Th }/{234U } speleothem dates at La Chaise-de-Vouthon (Charente), France

NASA Astrophysics Data System (ADS)

Blackwell, Bonnie; Porat, N.; Schwarcz, H. P.; Debénath, A.

One way to assess a new dating method's reliability is by comparing its results with those from well established, independent techniques. A controlled test of the electron spin resonance (ESR) dating method as it is currently being applied to teeth was attempted for the time range 100-250 ka, beyond that of 14C, at the archaeological site of La Chaise-de-Vouthon (Charente, France). Although absent in modern enamel, a single ESR signal with g = 2.0018 in fossil tooth enamel hydroxyapatite increases in amplitude with increasing irradiation doses. ESR ages are derived from the ratio of the AD, the radiation dose needed to produce the observed ESR signal, relative to the natural, environmental dose rate (ED) experienced by the tooth after deposition. Since the age depends on the uranium (U) uptake history assumed, three ages are calculated assuming: (1) early U uptake (EU); (2) continuous (linear) uptake (LU); (3) recent uptake (RU). Generally, the LU age agrees best with known ages determined by other methods, although the RU model is better for some teeth. ESR dating assumes that the fossil has not suffered recrystallization or significant diagenetic alteration. In the preliminary test, three teeth were dated. In Bourgeois-Delaunay, a bovid molar associated with Palaeolithic artefacts was collected from layers dated at 101 ± 12 to 114 ± 7 ka by {230Th }/{234U } dating of the over- and underlying stalagmitic floors. From Suard, two Equus teeth were collected from beneath a stalagmitic floor dating 112 ± 12 ka. ESR dating teeth significantly underestimated the true age for the teeth: the mean ESR ages range from 37 to 94 ka with standard errors of 2-6 ka, and good replicability. Although more teeth at La Chaise need to be tested to ascertain that the underestimation does not result from random variation commonly seen among teeth within one unit, the consistent underestimation suggests a fault in one of the assumptions underlying the dating method. The most obvious source of error lies in the difficulty in modelling the external γ dose. Only U leaching, not incorrectly modelled U uptake, would cause the underestimation. Diagenetic alteration may also cause anomalous fading, thermal instability, variation in k, or ESR signal suppression. More study into the effects of diagenesis alteration on enamel ESR signals is needed, as is a reevaluation of the mean signal life and α efficiency for several more enamel samples.
Tropical Indo-Pacific hydroclimate response to North Atlantic forcing during the last deglaciation as recorded by a speleothem from Sumatra, Indonesia

NASA Astrophysics Data System (ADS)

Wurtzel, Jennifer B.; Abram, Nerilie J.; Lewis, Sophie C.; Bajo, Petra; Hellstrom, John C.; Troitzsch, Ulrike; Heslop, David

2018-06-01

Abrupt changes in Atlantic Meridional Overturning Circulation are known to have affected the strength of the Indian and Asian Monsoons during glacial and deglacial climate states. However, there is still much uncertainty around the hydroclimate response of the Indo-Pacific Warm Pool (IPWP) region to abrupt climate changes in the North Atlantic. Many studies suggest a mean southward shift in the intertropical convergence zone (ITCZ) in the IPWP region during phases of reduced Atlantic meridional overturning, however, existing proxies have seasonal biases and conflicting responses, making it difficult to determine the true extent of North Atlantic forcing in this climatically important region. Here we present a precisely-dated, high-resolution record of eastern Indian Ocean hydroclimate variability spanning the last 16 ky (thousand years) from δ18O measurements in an aragonite-calcite speleothem from central Sumatra. This represents the western-most speleothem record from the IPWP region. Precipitation arrives year-round at this site, with the majority sourced from the local tropical eastern Indian Ocean and two additional long-range seasonal sources associated with the boreal and austral summer monsoons. The Sumatran speleothem demonstrates a clear deglacial structure that includes 18O enrichment during the Younger Dryas and 18O depletion during the Bølling-Allerød, similar to the pattern seen in speleothems of the Asian and Indian monsoon realms. The speleothem δ18O changes at this site are best explained by changes in rainfall amount and changes in the contributions from different moisture pathways. Reduced rainfall in Sumatra during the Younger Dryas is most likely driven by reductions in moisture transport along the northern or southern monsoon transport pathways to Sumatra. Considered with other regional proxies, the record from Sumatra suggests the response of the IPWP to North Atlantic freshwater forcing is not solely driven by southward shifts of the ITCZ, but also a reduction in moisture transport along both monsoon pathways.
230Th/U dating of a late Pleistocene alluvial fan along the southern San Andreas fault

USGS Publications Warehouse

Fletcher, Kathryn E.K.; Sharp, Warren D.; Kendrick, Katherine J.; Behr, Whitney M.; Hudnut, Kenneth W.; Hanks, Thomas C.

2010-01-01

U-series dating of pedogenic carbonate-clast coatings provides a reliable, precise minimum age of 45.1 ± 0.6 ka (2σ) for the T2 geomorphic surface of the Biskra Palms alluvial fan, Coachella Valley, California. Concordant ages for multiple subsamples from individual carbonate coatings provide evidence that the 238U-234U-230Th system has remained closed since carbonate formation. The U-series minimum age is used to assess previously published 10Be exposure ages of cobbles and boulders. All but one cobble age and some boulder 10Be ages are younger than the U-series minimum age, indicating that surface cobbles and some boulders were partially shielded after deposition of the fan and have been subsequently exhumed by erosion of fine-grained matrix to expose them on the present fan surface. A comparison of U-series and 10Be ages indicates that the interval between final alluvial deposition on the T2 fan surface and accumulation of dateable carbonate is not well resolved at Biskra Palms; however, the “time lag” inherent to dating via U-series on pedogenic carbonate can be no larger than ∼10 k.y., the uncertainty of the 10Be-derived age of the T2 fan surface. Dating of the T2 fan surface via U-series on pedogenic carbonate (minimum age, 45.1 ± 0.6 ka) and 10Be on boulder-top samples using forward modeling (preferred age, 50 ± 5 ka) provides broadly consistent constraints on the age of the fan surface and helps to elucidate its postdepositional development.
230Th/U dating of a late pleistocene alluvial fan along the southern san andreas fault

USGS Publications Warehouse

Fletcher, K.E.K.; Sharp, W.D.; Kendrick, K.J.; Behr, W.M.; Hudnut, K.W.; Hanks, T.C.

2010-01-01

U-series dating of pedogenic carbonate-clast coatings provides a reliable, precise minimum age of 45.1 ?? 0.6 ka (2??) for the T2 geomorphic surface of the Biskra Palms alluvial fan, Coachella Valley, California. Concordant ages for multiple subsamples from individual carbonate coatings provide evidence that the 238U-234U-230Th system has remained closed since carbonate formation. The U-series minimum age is used to assess previously published 10Be exposure ages of cobbles and boulders. All but one cobble age and some boulder 10Be ages are younger than the U-series minimum age, indicating that surface cobbles and some boulders were partially shielded after deposition of the fan and have been subsequently exhumed by erosion of fine-grained matrix to expose them on the present fan surface. A comparison of U-series and 10Be ages indicates that the interval between final alluvial deposition on the T2 fan surface and accumulation of dateable carbonate is not well resolved at Biskra Palms; however, the "time lag" inherent to dating via U-series on pedogenic carbonate can be no larger than ~10 k.y., the uncertainty of the 10Be-derived age of the T2 fan surface. Dating of the T2 fan surface via U-series on pedogenic carbonate (minimum age, 45.1 ?? 0.6 ka) and 10Be on boulder-top samples using forward modeling (preferred age, 50 ?? 5 ka) provides broadly consistent constraints on the age of the fan surface and helps to elucidate its postdepositional development. ?? 2010 Geological Society of America.
Decoupled evolution of temperature and precipitation in western Germany during the Last Interglacial reconstructed from a precisely dated speleothem

NASA Astrophysics Data System (ADS)

Scholz, Denis; Hoffmann, Dirk; Spötl, Christoph; Hopcroft, Peter; Mangini, Augusto; Richter, Detlef K.

2010-05-01

We present high-resolution stable oxygen and carbon isotope (δ18O and δ13C) as well as trace element profiles for stalagmite HBSH-1 from Hüttenbläserschachthöhle, western Germany. The chronology was established by MC-ICPMS 230Th/U-dating, and the high U-content of the stalagmite allowed determination of very precise 230Th/U-ages although using very small sample sizes. The beginning and end of individual growth phases of the stalagmite could, thus, be determined very accurately. Stalagmite HBSH-1 grew during the penultimate interglacial (MIS 7), the Last Interglacial (MIS 5) and the Holocene. The major part of the sample (40 cm) grew between 130 and 80 ka providing a climate record with decadal to centennial resolution for this period. The record shows three growth interruptions during MIS 5 coinciding with Greenland Stadials 25, 24 and 22, as recorded in the NGRIP ice core (North Greenland Ice Core Project members, 2004). The end of the MIS 5 growth phase coincides with GS 21. This shows that stalagmite growth in this area is a very sensitive proxy for northern hemisphere cooling. Correlation of the absolutely dated stalagmite record with Greenland ice cores may provide a tool to improve the chronology of the Greenland Stadials. The δ18O profile of stalagmite HBSH-1 shows a distinct similarity during MIS 5 with the NGRIP ice core and a sea surface temperature record from the Iberian Margin (Martrat et al., 2007). This suggests that stalagmite δ18O mainly reflects past temperature variability. Stalagmite HBSH-1 consists of aragonite rather than calcite, which is probably a result of pronounced prior calcite precipitation in the epikarst above the cave (Fairchild and Treble, 2009). In this case, the δ13C signal rather reflects changes in past precipitation than temperature. The δ13C record of HBSH-1 shows three pronounced negative peaks during MIS 5, in agreement with the three MIS 5 warm phases, MIS 5e, 5c and 5a. During the Last Interglacial, however, the evolution of δ18O and δ13C, and thus temperature and precipitation, is opposite. Whereas the δ18O signal suggests the warmest temperatures around 125 ka followed by a gradual decrease, the δ13C signal indicates wetter conditions towards the end of the Last Interglacial. The decoupling of temperature and precipitation during this time period is also seen in a series of snapshot simulations performed using a fast coupled ocean-atmosphere general circulation model. This behaviour can be explained by the influence of varying solar insolation patterns (in response to changing orbital configuration) on atmospheric dynamics and the resulting influence on storm activity in the region. References Fairchild, I. J. and Treble, P. C., 2009. Trace elements in speleothems as recorders of environmental change. Quaternary Science Reviews 28, 449-468. Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F., 2007. Four climate cycles of recurring deep and surface water destabilizations on the Iberian Margin. Science 317, 502-507. North Greenland Ice Core Project members, 2004. High-resolution record of Northern Hemisphere climate extending into the last interglacial period. Nature 431, 147-151.
ESR and mass-spectrometric uranium-series dating studies of a mammoth tooth from stanton harcourt, Oxfordshire, England

NASA Astrophysics Data System (ADS)

Zhou, L. P.; McDermott, F.; Rhodes, E. J.; Marseglia, E. A.; Mellars, P. A.

The age of the Channel Deposits at Stanton Harcourt, Oxfordshire, England, has been a topic of debate with important implications for British Pleistocene stratigraphy. Recent excavations led by K. Scott reveal ample evidence for ancient environmental conditions characteristic of an interglacial. However, the question remains on the assignment of its age. At present it is thought to represent an interglacial corresponding to either marine OI Stage 7 or 5e. In an attempt to constrain the chronology of the site, and to assess the techniques' reliability, we have made electron spin resonance (ESR) measurements on enamel and mass-spectrometric U-series measurements on both enamel and dentine from a mammoth tooth buried in the Channel Deposits at Stanton Harcourt. Four dentine samples gave U-series dates between 65.4±0.4 and 146.5±1.0 ka and two enamel samples between these dentine layers were dated to 53.3±0.2 and 61.1±0.6 ka. The corresponding ESR age estimates for the enamel samples are 59±6 and 62±4 ka (early U-uptake, EU) and 95±11 and 98±7 ka (linear U-uptake, LU). The recent U-uptake (RU) dates are 245±38 and 238±31 ka, but in light of the U-series data we would not expect these to represent realistic age estimates. Similar ESR results were obtained from two other adjacent enamel samples. The effect of the large size of the mammoth tooth on the external gamma dose, and the internal gamma contribution from the high U content of the dentine, are considered. While the recent uptake ESR dates appear to coincide with OI Stage 7, all the early and linear uptake ESR and mass-spectrometric U-series dates are younger than the expected age estimation based on recent geological interpretation and amino acid racemisation measurements (>200 ka) and optical dating studies (200-450 ka). Possible causes of the unexpected dating results are discussed. We conclude that our mass-spectrometric U-series and EU and LU ESR measurements represent minimum age estimates for the tooth analysed. Our results seem to suggest that the tooth and hence the Channel Deposits are at least 147 ka in age. i.e. predating the last interglacial.
Pleistocene cave art from Sulawesi, Indonesia.

PubMed

Aubert, M; Brumm, A; Ramli, M; Sutikna, T; Saptomo, E W; Hakim, B; Morwood, M J; van den Bergh, G D; Kinsley, L; Dosseto, A

2014-10-09

Archaeologists have long been puzzled by the appearance in Europe ∼40-35 thousand years (kyr) ago of a rich corpus of sophisticated artworks, including parietal art (that is, paintings, drawings and engravings on immobile rock surfaces) and portable art (for example, carved figurines), and the absence or scarcity of equivalent, well-dated evidence elsewhere, especially along early human migration routes in South Asia and the Far East, including Wallacea and Australia, where modern humans (Homo sapiens) were established by 50 kyr ago. Here, using uranium-series dating of coralloid speleothems directly associated with 12 human hand stencils and two figurative animal depictions from seven cave sites in the Maros karsts of Sulawesi, we show that rock art traditions on this Indonesian island are at least compatible in age with the oldest European art. The earliest dated image from Maros, with a minimum age of 39.9 kyr, is now the oldest known hand stencil in the world. In addition, a painting of a babirusa ('pig-deer') made at least 35.4 kyr ago is among the earliest dated figurative depictions worldwide, if not the earliest one. Among the implications, it can now be demonstrated that humans were producing rock art by ∼40 kyr ago at opposite ends of the Pleistocene Eurasian world.
Holocene climate variability in Texas, USA: An integration of existing paleoclimate data and modeling with a new, high-resolution speleothem record

NASA Astrophysics Data System (ADS)

Wong, Corinne I.; Banner, Jay L.; Musgrove, MaryLynn

2015-11-01

Delineating the climate processes governing precipitation variability in drought-prone Texas is critical for predicting and mitigating climate change effects, and requires the reconstruction of past climate beyond the instrumental record. We synthesize existing paleoclimate proxy data and climate simulations to provide an overview of climate variability in Texas during the Holocene. Conditions became progressively warmer and drier transitioning from the early to mid Holocene, culminating between 7 and 3 ka (thousand years ago), and were more variable during the late Holocene. The timing and relative magnitude of Holocene climate variability, however, is poorly constrained owing to considerable variability among the different records. To help address this, we present a new speleothem (NBJ) reconstruction from a central Texas cave that comprises the highest resolution proxy record to date, spanning the mid to late Holocene. NBJ trace-element concentrations indicate variable moisture conditions with no clear temporal trend. There is a decoupling between NBJ growth rate, trace-element concentrations, and δ18O values, which indicate that (i) the often direct relation between speleothem growth rate and moisture availability is likely complicated by changes in the overlying ecosystem that affect subsurface CO2 production, and (ii) speleothem δ18O variations likely reflect changes in moisture source (i.e., proportion of Pacific-vs. Gulf of Mexico-derived moisture) that appear not to be linked to moisture amount.
Measuring U-series Disequilibrium in Weathering Rinds to Study the Influence of Environmental Factors to Weathering Rates in Tropical Basse-Terre Island (French Guadeloupe)

NASA Astrophysics Data System (ADS)

Guo, J.; Ma, L.; Sak, P. B.; Gaillardet, J.; Chabaux, F. J.; Brantley, S. L.

2015-12-01

Chemical weathering is a critical process to global CO2 consumption, river/ocean chemistry, and nutrient import to biosphere. Weathering rinds experience minimal physical erosion and provide a well-constrained system to study the chemical weathering process. Here, we applied U-series disequilibrium dating method to study weathering advance rates on the wet side of Basse-Terre Island, French Guadeloupe, aiming to understand the role of the precipitation in controlling weathering rates and elucidate the behavior and immobilization mechanisms of U-series isotopes during rind formation. Six weathering clasts from 5 watersheds with mean annual precipitation varying from 2000 to 3000 mm/yr were measured for U-series isotope ratios and major element compositions on linear core-to-rind transects. One sample experienced complete core-to-rind transformation, while the rest clasts contain both rinds and unweathered cores. Our results show that the unweathered cores are under U-series secular equilibrium, while all the rind materials show significant U-series disequilibrium. For most rinds, linear core-to-rind increases of (230Th/232Th) activity ratios suggest a simple continuous U addition history. However, (234U/238U) and (238U/232Th) trends in several clasts show evidences of remobilization of Uranium besides the U addition, complicating the use of U-series dating method. The similarity between U/Th ratios and major elements trends like Fe, Al, P in some transects and the ongoing leaching experiments suggest that redox and organic colloids could control the mobilization of U-series isotopes in the rinds. Rind formation ages and weathering advance rate (0.07-0.29mm/kyr) were calculated for those rinds with a simple U-addition history. Our preliminary results show that local precipitation gradient significantly influenced the weathering advance rate, revealing the potential of estimating weathering advance rates at a large spatial scale using the U-series dating method.
Orbital- and Millennial-Scale Changes in the Australasian Monsoon over the Last 470,000 Years

NASA Astrophysics Data System (ADS)

Gagan, M. K.; Ayliffe, L.; Drysdale, R.; Zhao, J.; Griffiths, M. L.; Hellstrom, J.; Dunbar, G.; Hantoro, W.; Edwards, R.; Cheng, H.; Suwargadi, B.

2011-12-01

Speleothem 18O/16O records from China have revealed changes in East Asian monsoon rainfall over the last ~390,000 years (e.g. Wang et al. 2008, Cheng et al. 2010), yet little is known about orbital- and millennial-scale climate change in the 'southern half' of the Australasian monsoon domain. To fill this gap, we aim to build speleothem 18O/16O records for the seasonal monsoon rainfall belt of south-central Indonesia. Between 2006 and 2009, we sampled speleothems in Flores and southwest Sulawesi (latitudes 5-9 S) with U-series ages extending to ~90,000 yBP and ~470,000 yBP, respectively. Development of the 18O/16O records for Sulawesi is in progress, but the basal ages of the speleothems (onset of stalagmite growth) are intriguing because they cluster around glacial terminations, when the East Asian monsoon is known to have been weak (Cheng et al. 2010). There is clear antiphasing of the Flores and China speleothem 18O/16O records on precession time-scales over the last ~90,000 years. A distinct maximum in monsoon rainfall in Flores occurred ~21,000 yBP, suggesting the ITCZ moved south during the Last Glacial Maximum in response to the southern hemisphere summer insolation maximum. This important finding indicates that ITCZ positioning in tropical Australasia, through its influence on large-scale oceanic-atmospheric circulation, could have played a key role in the rapid rise of atmospheric CO2 and global warming that ultimately led to the demise of the ice age, as summarised by Denton et al. (2010) and others. The new Flores speleothem 18O/16O records also show that climate change in the North Atlantic region and Australasian monsoon rainfall are inextricably linked on millennial timescales (Griffiths et al. 2009, Lewis et al. 2011). For example, rapid warming in the North Atlantic region during Dansgaard-Oeschger Event 21 (~86,000 yBP) was linked to a synchronous northward shift of the Australasian ITCZ, marking the final demise of MIS 5b. In contrast, cooling in the North Atlantic during Heinrich Events 3 (~30,000 yBP) and 1 (~16,000 yBP) and the YD (12,800-11,500 yBP) correlates with southward shifts in the Australasian ITCZ. However, the 8,200 yBP cold snap in the North Atlantic produced drying and cooling around Flores. The key difference here is that sea level was relatively high, and cooler sea-surface temperatures in the Indonesian maritime continent at that time (based on nearby coral records) may have suppressed a southward migration of the ITCZ. Cheng, H. et al. (2010), Science, 326, 248-. Denton, G.H. et al. (2010), Science, 328, 1652-. Griffiths, M.L. et al. (2009), Nature Geoscience, 2, 636-. Lewis, S.C. et al. (2011), Earth Planet. Sci. Lett., 303, 133-. Wang, Y. et al. (2008), Nature, 451, 1090-.
Alchemy in the underworld - recent progress and future potential of organic geochemistry applied to speleothems.

NASA Astrophysics Data System (ADS)

Blyth, Alison

2016-04-01

Speleothems are well used archives for chemical records of terrestrial environmental change, and the integration of records from a range of isotopic, inorganic, and organic geochemical techniques offers significant power in reconstructing both changes in past climates and identifying the resultant response in the overlying terrestrial ecosystems. The use of organic geochemistry in this field offers the opportunity to recover new records of vegetation change (via biomarkers and compound specific isotopes), temperature change (via analysis of glycerol dialkyl glycerol tetraethers, a compound group derived from microbes and varying in structure in response to temperature and pH), and changes in soil microbial behaviour (via combined carbon isotope analysis). However, to date the use of organic geochemical techniques has been relatively limited, due to issues relating to sample size, concerns about contamination, and unanswered questions about the origins of the preserved organic matter and rates of transport. Here I will briefly review recent progress in the field, and present a framework for the future research needed to establish organic geochemical analysis in speleothems as a robust palaeo-proxy approach.
Pollen from accurately dated speleothems supports alpine glacier low-stands during the early Holocene

NASA Astrophysics Data System (ADS)

Festi, Daniela; Hoffmann, Dirk L.; Luetscher, Marc

2016-07-01

Deciphering pollen assemblages from alpine speleothems holds potential to provide unique information about past vegetation in rapidly changing environments. Here, we reconstruct subsurface aerosol transport at Milchbach cave (Switzerland, 1840 m asl) based on the pollen content of two Holocene stalagmites. We demonstrate that pollen is chiefly associated with bacterially mediated calcite fabrics, typical of a well-ventilated cave system. In contrast, pollen is absent from columnar calcite fabrics confirming that hydrological transport is not a significant process for the incorporation of pollen into speleothems at Milchbach cave. Our results support significant changes in the subsurface ventilation regime, which can be associated with the waxing and waning of Upper Grindelwald glacier. Pollen assemblages obtained from six carbonate sub-samples attest the presence of a mixed deciduous forest in the Grindelwald valley during the early and middle Holocene, in agreement with coeval regional pollen records. This study demonstrates that even small amounts of calcite (0.3-2.8 cm3) are capable of delivering pollen spectra representative of the original vegetation if sufficiently elevated deposition fluxes are provided.
Multi-Proxy Evidence for Decoupled Monsoon Intensity and Southeast Asian Precipitation on Orbital and Millennial Timescales

NASA Astrophysics Data System (ADS)

Johnson, K. R.; Griffiths, M. L.; Borsato, A.; Frisia, S.; Bhattacharya, T.; Tierney, J. E.; LeGrande, A. N.; Henderson, G. M.

2017-12-01

Despite significant advances in our understanding of Asian monsoon variability on orbital to millennial timescales, we still know very little about the range and mechanisms of variability in the Southeast Asian monsoon region. To address this need, we have developed a decadally-resolved and replicated speleothem δ18O and δ13C record from Tham Doun Mai Cave in Northern Laos. The record spans the period from 37.7 kyr BP to the present and the age model is constrained by 35 U-Th dates. The orbital and millennial scale δ18O variability is remarkably similar to other Asian speleothem records, with the lowest values observed during the early Holocene summer insolation maxima and clear δ18O increases observed during Heinrich Stadials (HS) 1-3, the Younger Dryas, and the 8.2 kyr event. The strong similarity with Chinese speleothem δ18O records suggests that variations in upstream rainout over the Indian Ocean, Bay of Bengal, and Indian Monsoon region are the dominant control on orbital and millennial scale precipitation δ18O variability across Southeast and East Asia. In contrast to δ18O, TM speleothem δ13C is reflective of local hydroclimate. The δ13C record shows large positive excursions during HS 1-3, suggesting dry conditions during these events. Positive δ13C values during the early Holocene indicate dry conditions in SE Asia were synchronous with increased upstream rainout. This interpretation is further supported by crystal fabric and greyscale analyses, which reflect internal porosity changes likely related to infiltration variability. Compact columnar, translucent calcite is associated with decreased infiltration, and typifies HS events and the early Holocene. The positive δ13C excursions during these periods may then be enhanced by the prolonged degassing associated with slower drip rates. Time-slice simulations conducted with the isotope-enabled GISS Model E further support a dry early Holocene in this region. Model analyses suggest dry conditions in SE Asia during insolation maxima may arise from decreased low-level moisture convergence over the Indo-China Peninsula as precipitation over India and East Asia increases, effectively drawing away moisture from our study site. Nevertheless, the impacts of upstream rainout lead to regionally coherent δ18O decreases across the broad Asian monsoon region.
Reconstruction of Pleistocene Paleo-Hydrology and Climate Variations in Western Asia as Recorded in Speleothems from West-Central Iran

NASA Astrophysics Data System (ADS)

Mehterian, S.; Pourmand, A.; Sharifi, A.; Lahijani, H. A. K.; Naderi, M.; Swart, P. K.

2014-12-01

Extending from the eastern Mediterranean Sea to the northwest Indian Ocean and modern Iran, West Asia represents one of the most climatically dynamic regions in the northern hemisphere. The regional climate of West Asia is governed by interactions between the mid-latitude Westerlies, the Siberian Anticyclone and the Indian Ocean Summer Monsoon. In recent years, sparse records of Pleistocene climate variability have emerged from cave deposits (speleothems) in East Asia, the Arabian Peninsula and eastern Mediterranean. However, there remains a large gap in our understanding of abrupt and long-term climate variability in this region. We present for the first time δ18O data from speleothem and water samples that were collected from two cave systems in west-central Iran at similar latitudes, 60km apart: Qaleh Kord Cave (QKC, 35°47'50"N, 48°51'25"E) and Kataleh Khor Cave (KKC, 35°50'09"N, 48°09'41"E). U-Th geochronometry in two stalagmites from QKC yielded ages that range from 73,000 to 118,000 years B.P. Likewise, two stalagmites dated from KKC yielded ages 214,000-260,000 years B.P. and 300,000-500,000 years B.P. The analysis of additional speleothems from these caves should help to establish a continuous half million year multi-proxy record of δ18O variations, trace metal composition (Mg/Ca, Sr/Ca), and radiogenic Sr isotopes in these cave systems. High-resolution δ18O analyses of QKC stalagmites show patterns of variation that can be attributed to Marine Isotope Stage (MIS) 5a and 5b. Since both these caves sit at relatively high elevations (QKC: 2,160 masl, KKC: 1,695 masl) far from major seas (1,100km from Mediterranean Sea, 1,500km from North Indian Ocean), this record potentially reflects the synoptic interactions between the Westerlies and the Siberian Anticyclone during this time interval, as opposed to direct variations caused by sea level fluctuations. Measurements of drip water composition and modern environmental parameters (temperature, relative humidity and pCO2) inside the caves paired with δ18O analyses of fluid inclusions in the stalagmites will place additional constraints on multi-proxy reconstruction of paleo-records from these cave systems.
Mid-Holocene drying of the U.S. Great Basin recorded in Nevada speleothems

NASA Astrophysics Data System (ADS)

Steponaitis, Elena; Andrews, Alexandra; McGee, David; Quade, Jay; Hsieh, Yu-Te; Broecker, Wallace S.; Shuman, Bryan N.; Burns, Stephen J.; Cheng, Hai

2015-11-01

Lake level records point to dramatic changes in Great Basin water balance over the last 25 ka, but the timing and pace of Holocene drying in the region remains poorly documented. Here we present stable isotope and trace metal data from two Lehman Caves, NV speleothems that provide a well-dated record of latest Pleistocene to mid-Holocene hydroclimate in the U.S. Great Basin. Together the stalagmites span the interval between 16.4 ka and 3.8 ka, with a hiatus from 15.0 ka to 12.7 ka. Mg/Ca and δ13C covary throughout the records, consistent with control by the extent of degassing and prior calcite precipitation (PCP); measurements of modern cave and soil waters support PCP as the primary control on drip-water trace-element composition. We therefore interpret Mg/Ca and δ13C as reflecting infiltration rates, with higher values corresponding to drier periods. Both Mg/Ca and δ13C indicate a wet period at the beginning of the record (12.7-8.2 ka) followed by pronounced drying after 8.2 ka. This mid-Holocene drying is consistent with records from around the western United States, including a new compilation of Great Basin lake-level records. The strong temporal correspondence with the collapse of the Laurentide ice sheet over Hudson Bay suggests that this drying may have been triggered by northward movement of the winter storm track as a result of ice sheet retreat. However, we cannot rule out an alternative hypothesis that wet early Holocene conditions are related to equatorial Pacific sea-surface temperature. Regardless, our results suggest that Great Basin water balance in the early Holocene was driven by factors other than orbital changes.
Reconstruction of Late Quaternary Climate in Central Europe - A Comparison of Stable Isotope and Trace Element Variations in Speleothems From Different Cave Systems in Germany.

NASA Astrophysics Data System (ADS)

Nordhoff, P.; Wiegand, B.; Simon, K.; Rosendahl, W.; Hansen, B. T.; Kempe, S.

2003-12-01

Speleothems (stalagmites, stalactites, flowstones) are important archives for Late Quaternary continental climatic and paleo-environmental reconstruction. Speleothems form when calcium carbonate precipitates from solutions seeping into caves hosted e.g. in limestone or dolomite complexes. Information of past climate variability and changes in local environmental conditions can be obtained from signatures of the stable isotopes of oxygen and carbon as well as trace element pattern recorded in speleothems. Reconstruction of paleo-temperature and past environmental conditions from stable isotopes, however, require isotopic equilibrium between the drip water and the precipitating calcium carbonate. Results from Dietzel et al. (1992) and Johnson and Ingram (2001) indicate that the formation of modern travertine and speleothem calcite occurs under isotopic equilibrium. Factors that influence the stable oxygen and carbon isotope composition during speleothem precipitation include e.g. the moisture source and precipitation, photosynthetic pathways, the bedrock proportion, and the drip rate. This often leads to a situation with several variables. However, a specific interpretation is possible when dealing with environments where only one of the factors is dominant, or specific settings are assumed to be invariant, or further proxies like trace element variations help to define the frame conditions during speleothem formation. Concentrations of trace elements (e.g. Sr, Mg) which are co-precipitated with calcite are related to changes in the composition of the solution and strongly depend on the dissolution/precipitation dynamics along drip water flow paths. In a multiproxy approach they are a valuable tool for the interpretation of the recorded stable isotope variations. We present first results from different cave systems located in the Swabian Alps and the Harz Mountains (Germany). Our study includes a high-resolution multiproxy approach, using U/Th-TIMS data, stable oxygen/carbon isotope data, and geochemical compositions of speleothems, covering ages from the Late Pleistocene to the Early Holocene. The results are compared to geochemical data from host rocks, soil zones, cave sediments, drip water compositions, and recent calcium carbonate precipitates. Understanding the response of a cave system to the actual climatic, hydrologic and environmental regimen is a main requirement for the interpretation of "paleo-information" conserved in speleothems in order to lead to a coherent picture of past continental climate dynamics. References: Dietzel M., Usdowski E., and Hoefs J., (1992): Applied Geochemistry 7: 177-184. Johnson, K.R. and Ingram, B.L. (2001): Abstract volume, 4th Internat. Symp. On Applied Isotope Geochemistry, Pacific Groove, USA: 70-72.
Steady incision of Grand Canyon at the million year timeframe: a case for mantle-driven differential uplift

USGS Publications Warehouse

Crow, Ryan S.; Karl Karlstrom,; Laura Crossey,; Richard Young,; Michael Ort,; Yemane Asmerom,; Victor Polyak,; Andrew Darling,

2014-01-01

The Grand Canyon region provides an excellent laboratory to examine the interplay between river incision, magmatism, and the geomorphic and tectonic processes that shape landscapes. Here we apply U-series, Ar–Ar, and cosmogenic burial dating of river terraces to examine spatial variations in incision rates along the 445 km length of the Colorado River through Grand Canyon. We also analyze strath terrace sequences that extend to heights of several hundred meters above the river, and integrate these with speleothem constrained maximum incision rates in several reaches to examine any temporal incision variations at the million-year time frame. This new high-resolution geochronology shows temporally steady long-term incision in any given reach of Grand Canyon but significant variations along its length from 160 m/Ma in the east to 101 m/Ma in the west. Spatial and temporal patterns of incision, and the long timescale of steady incision rule out models where geomorphic controls such as climate oscillations, bedrock strength, sediment load effects, or isostatic response to differential denudation are the first order drivers of canyon incision. The incision pattern is best explained by a model of Neogene and ongoing epeirogenic uplift due to an eastward propagating zone of increased upper mantle buoyancy that we infer from propagation of Neogene basaltic volcanism and a strong lateral gradient in modern upper mantle seismic structure.
Coherency of European speleothem δ18O records linked to North Atlantic ocean circulation

NASA Astrophysics Data System (ADS)

Deininger, Michael; McDermott, Frank

2016-04-01

Speleothem δ18O records can provide valuable information about past continental environmental and climatic conditions. In recent decades a European speleothem network has been assembled that allows us to reconstruct past climate variability in both space and time. In particular climate variability during the Holocene was investigated by these studies. The Holocene is thus an ideal period to apply sophisticated statistical methods to derive spatio-temporal pattern of common climate variability in the European speleothem record. Here we evaluate a compilation of 10 speleothem δ18O records covering the last 4.5 ka for their shared variability. The selected speleothem δ18O records must satisfy certain quality criteria to be included: (i) a robust age model; (ii) a temporal intra-sampling resolution of smaller than 30 years; and (iii) the record should be published. A Monte Carlo based Principal Component Analysis (MC-PCA) that accounts for uncertainties in individual speleothem age models and for the different and varying temporal resolutions of each speleothem δ18O record was used for this purpose. Our MC-PCA approach allows not only the identification of temporally coherent changes in δ18O records, but it also facilitates their depiction and evaluation spatially. The compiled speleothem δ18O records span almost the entire European continent (with the exception of the circum-Mediterranean region) ranging from the western Margin of the European continent (stalagmite CC-3, Ireland) to Northern Turkey (SO-1) and from Northern Italy (CC-26) to Norway (FM-3). For the MC-PCA analysis, the 4.5 ka period was sub-divided into eight 1 ka long time windows that overlap the subsequent time window by 500 years to allow a comparison of the temporal evolution of the common signal. In this study we only interpreted the 1st principal component (PC) that depict the spatio-temporal pattern with the highest explained variability of all speleothem δ18O records. Our MC-PCA results demonstrate that a common signal (expressed by the 1st PCs) is shared by the investigated speleothem δ18O records for each individual time window and that the 1st PCs agree in the overlapping periods. This allowed us to construct a common speleothem record (CSR) for the last 4.5 ka. The CSR shows a strong millennial cyclicity in the investigated period. We demonstrate that the large-scale changes in the European CSR, reflected by its millennial cyclicity, are in phase with the well-known Bond cycles during the last 4.5 ka that reflect changes of drift ice in the North Atlantic (Bond et al., 2001). Evidence for this link was also shown by Mangini et al. (2007) using a stalagmite from the Central Alps. Furthermore, the CSR shows a very good agreement with a recent, independently dated reconstruction for the strength of the sub-polar gyre (Thornalley et al., 2009) and we argue that these changes during the last 4.5 ka are likely caused by the variability of the atmospheric circulation affecting the interplay between the subpolar gyre and the subtropical gyre in the North Atlantic, as well as European speleothem δ18O records. BOND, G., KROMER, B., BEER, J., MUSCHELER, R., EVANS, M. N., SHOWERS, W., HOFFMANN, S., LOTTI-BOND, R., HAJDAS, I. & BONANI, G. 2001. Persistent solar influence on North Atlantic climate during the Holocene. Science, 294, 2130-6. MANGINI, A., VERDES, P., SPÖTL, C., SCHOLZ, D., VOLLWEILER, N. & KROMER, B. 2007. Persistent influence of the North Atlantic hydrography on central European winter temperature during the last 9000 years. Geophysical Research Letters, 34. THORNALLEY, D. J. R., ELDERFIELD, H. & MCCAVE, I. N. 2009. Holocene oscillations in temperature and salinity of the surface subpolar North Atlantic. Nature, 457, 711-714.
Trace-element partition coefficients in the calcite-water system and their paleoclimatic significance in cave studies

NASA Astrophysics Data System (ADS)

Gascoyne, Melvyn

1983-02-01

Speleothems (stalactites, stalagmites) formed in limestone caves have been found to contain much information on the timing and intensity of past climates, from analysis of their U, Th, 13C and 18O contents. Because the incorporation of certain trace elements (e.g., Mg, Mn and Zn) in calcite is known to be temperature-dependent, it may be possible to use variations in trace-metal content of fossil speleothems as an alternative paleotem-perature indicator. Using specially developed ion-exchange sampling techniques, analysis of trace-metal content of seepage water and associated fresh calcite deposits in caves in Vancouver Island and Jamaica shows that Mg is distributed between phases in a consistent manner within the temperature regimes of the caves (7° and 23°C, respectively). Average values of the distribution coefficient for Mg are respectively 0.017 and 0.045 at these temperatures. These results indicate that the Mg content of calcite varies directly with temperature and in a sufficiently pronounced manner that a 1°C rise in depositional temperature of a speleothem containing 500 ppm Mg, at ˜10°C, would be seen as an increase of ˜35ppm Mg — a readily determinable shift. Other factors affecting Mg content of a speleothem are considered.

Uranium series dating of Allan Hills ice

NASA Technical Reports Server (NTRS)

Fireman, E. L.

1986-01-01

Uranium-238 decay series nuclides dissolved in Antarctic ice samples were measured in areas of both high and low concentrations of volcanic glass shards. Ice from the Allan Hills site (high shard content) had high Ra-226, Th-230 and U-234 activities but similarly low U-238 activities in comparison with Antarctic ice samples without shards. The Ra-226, Th-230 and U-234 excesses were found to be proportional to the shard content, while the U-238 decay series results were consistent with the assumption that alpha decay products recoiled into the ice from the shards. Through this method of uranium series dating, it was learned that the Allen Hills Cul de Sac ice is approximately 325,000 years old.
Geological constraints on cave development in the plateau-gorge karst of South China (Wulong, Chongqing)

NASA Astrophysics Data System (ADS)

Szczygieł, Jacek; Golicz, Mateusz; Hercman, Helena; Lynch, Erin

2018-03-01

The Houping Tiankeng cluster is a part of the South China Karst UNESCO World Natural Heritage Site. Within the distinctive Wulong plateau-gorge karst, > 200 km of cave passages have been documented to date. This paper focuses on detailed tectonic and morphological research on the Luo Shui Kong cave, enriched with U-series dating of speleothems and complemented by morphometric analysis of the San Wang Dong and Er Wang Dong caves. All of these caves exhibit three regional levels of cave development: 1) 1040-1020 m a.s.l.; 2) 900-840 m a.s.l.; and 3) 740-660 m a.s.l. The Houping Tiankeng area is a carbonate rock sequence several hundred meters thick, overlain by the less soluble Lower Ordovician strata, limiting recharge points to faults exposing underlying easily soluble formations. This leads to the domination of concentrated, high-volume inflow and thus results in caves of large volume in the plateau-gorge karst. Shafts connecting the surface with cave passages located underneath formed along faults, changing the hydrogeological pattern through karst water capture and remodeling of existing conduits, albeit mainly by increasing their overall dimensions rather than by deepening them. The most favorable structures for cave-level development are two sets of joints conjugated with gently inclined bedding. Since these joints are characterized by a small vertical extent, downward development is limited. Hence, most of the passages are wide but not deep canyons and typical of a water-table cave pattern. Places where the fault plane is eroded from the surface and where, at the same time, an underneath cave chamber ceiling expands upwards are particularly predisposed to the formation of a tiankeng.
A Holocene Record of Monsoon Intensity From Speleothems in Flores, Indonesia

NASA Astrophysics Data System (ADS)

Griffiths, M. L.; Drysdale, R.; Gagan, M.; Ayliffe, L.; Zhao, J.; St. Pierre, E.; Hantoro, W.; Suwargadi, B.

2007-12-01

The Australasian monsoon is among the largest monsoon systems on Earth. The affected region experiences a marked seasonal cycle in winds and precipitation, similar to its Northern Hemisphere counterparts (e.g., Asian monsoons). The Australasian monsoon is the life blood of the millions of people of the Indonesian archipelago. Since the climate is the dominating factor controlling food production, it is of great significance and urgency that we gain a firmer grasp on the parameters that control variations in monsoon intensity. Precise uranium series dating of two actively growing speleothems measuring ~1.25 (LR06-B1) and ~1.61 (LR06-B3) meters in length from Liang Luar cave (Flores, eastern Indonesia), reveal basal ages of ~12,846±103 and 23,605±171 years respectively. In previous studies, stable isotope ratios (δ18O and δ13C) and trace element concentrations in speleothems have revealed past environmental change (e.g., Burns et al., 2001; Wang et al., 2001; Fleitmann et al., 2004; Drysdale et al., 2004).In monsoon-affected regions, the δ18O signal recorded in stalagmites seems to be dominated by the amount of precipitation (so-called `amount effect'), whereby more negative (positive) δ18O values indicate enhanced (diminished) precipitation. Preliminary results from LR06-B1 indicate that δ18O values show a general increase in monsoon intensity from the beginning of the record to ~2000 years BP: this more or less follows insolation changes over the Australian continent.Comparison of our record with D4 from Dongge Cave reveals an anticorrelation during the Holocene, further supporting the hypothesis that tropical monsoon intensity is largely controlled by changes in insolation in both the Northern and Southern Hemisphere. Examination of our δ13C record demonstrates a high-frequency signal superimposed on low- frequency variability which correlates with the reconstructed sunspot cycle: higher (lower) sunspot numbers, and hence increased solar activity, correspond with higher (lower) δ13C values. An exception to this correlation is the abrupt shift towards higher δ13C values at approximately 1500 years BP, which does not correspond with the sunspot trend. This result may be indicative of a major volcanic eruption or the clearing of vegetation by modern humans; metal tools were introduced into the area just prior to this change. Given the lack of accurately dated palaeoclimate time series from the Australasian region, there is an urgent need for high-resolution records covering periods of known environmental change. Results from our study will contribute to a better understanding of tropical palaeoclimates and help scientists gain a clearer understanding of the mechanisms driving the changes in the Australasian monsoon system during the Holocene. Lastly, following the recent discovery of the `Hobbit' in a cave just a short distance from Liang Luar, there is scope for studying climatic conditions for the region around the time of the Hobbit's demise.
UDATE1: A computer program for the calculation of uranium-series isotopic ages

USGS Publications Warehouse

Rosenbauer, R.J.

1991-01-01

UDATE1 is a FORTRAN-77 program with an interface for an Apple Macintosh computer that calculates isotope activities from measured count rates to date geologic materials by uranium-series disequilibria. Dates on pure samples can be determined directly by the accumulation of 230Th from 234U and of 231Pa from 235U. Dates for samples contaminated by clays containing abundant natural thorium can be corrected by the program using various mixing models. Input to the program and file management are made simple and user friendly by a series of Macintosh modal dialog boxes. ?? 1991.
Holocene climate variability in Texas, USA: An integration of existing paleoclimate data and modeling with a new, high-resolution speleothem record

USGS Publications Warehouse

Wong, Corinne I.; Banner, Jay L.; Musgrove, MaryLynn

2015-01-01

Delineating the climate processes governing precipitation variability in drought-prone Texas is critical for predicting and mitigating climate change effects, and requires the reconstruction of past climate beyond the instrumental record. We synthesize existing paleoclimate proxy data and climate simulations to provide an overview of climate variability in Texas during the Holocene. Conditions became progressively warmer and drier transitioning from the early to mid Holocene, culminating between 7 and 3 ka (thousand years ago), and were more variable during the late Holocene. The timing and relative magnitude of Holocene climate variability, however, is poorly constrained owing to considerable variability among the different records. To help address this, we present a new speleothem (NBJ) reconstruction from a central Texas cave that comprises the highest resolution proxy record to date, spanning the mid to late Holocene. NBJ trace-element concentrations indicate variable moisture conditions with no clear temporal trend. There is a decoupling between NBJ growth rate, trace-element concentrations, and δ18O values, which indicate that (i) the often direct relation between speleothem growth rate and moisture availability is likely complicated by changes in the overlying ecosystem that affect subsurface CO2 production, and (ii) speleothem δ18O variations likely reflect changes in moisture source (i.e., proportion of Pacific-vs. Gulf of Mexico-derived moisture) that appear not to be linked to moisture amount.
Persistent drying in the tropics linked to natural forcing.

PubMed

Winter, Amos; Zanchettin, Davide; Miller, Thomas; Kushnir, Yochanan; Black, David; Lohmann, Gerrit; Burnett, Allison; Haug, Gerald H; Estrella-Martínez, Juan; Breitenbach, Sebastian F M; Beaufort, Luc; Rubino, Angelo; Cheng, Hai

2015-07-14

Approximately half of the world's population lives in the tropics, and future changes in the hydrological cycle will impact not just the freshwater supplies but also energy production in areas dependent upon hydroelectric power. It is vital that we understand the mechanisms/processes that affect tropical precipitation and the eventual surface hydrological response to better assess projected future regional precipitation trends and variability. Paleo-climate proxies are well suited for this purpose as they provide long time series that pre-date and complement the present, often short instrumental observations. Here we present paleo-precipitation data from a speleothem located in Mesoamerica that reveal large multi-decadal declines in regional precipitation, whose onset coincides with clusters of large volcanic eruptions during the nineteenth and twentieth centuries. This reconstruction provides new independent evidence of long-lasting volcanic effects on climate and elucidates key aspects of the causal chain of physical processes determining the tropical climate response to global radiative forcing.
A Chinese cave links climate change, social impacts, and human adaptation over the last 500 years.

PubMed

Tan, Liangcheng; Cai, Yanjun; An, Zhisheng; Cheng, Hai; Shen, Chuan-Chou; Breitenbach, Sebastian F M; Gao, Yongli; Edwards, R Lawrence; Zhang, Haiwei; Du, Yajuan

2015-08-13

The collapse of some pre-historical and historical cultures, including Chinese dynasties were presumably linked to widespread droughts, on the basis of synchronicities of societal crises and proxy-based climate events. Here, we present a comparison of ancient inscriptions in Dayu Cave from Qinling Mountains, central China, which described accurate times and detailed impacts of seven drought events during the period of 1520-1920 CE, with high-resolution speleothem records from the same cave. The comparable results provide unique and robust tests on relationships among speleothem δ(18)O changes, drought events, and societal unrest. With direct historical evidences, our results suggest that droughts and even modest events interrupting otherwise wet intervals can cause serious social crises. Modeling results of speleothem δ(18)O series suggest that future precipitation in central China may be below the average of the past 500 years. As Qinling Mountain is the main recharge area of two large water transfer projects and habitats of many endangered species, it is imperative to explore an adaptive strategy for the decline in precipitation and/or drought events.
A Chinese cave links climate change, social impacts, and human adaptation over the last 500 years

PubMed Central

Tan, Liangcheng; Cai, Yanjun; An, Zhisheng; Cheng, Hai; Shen, Chuan-Chou; Breitenbach, Sebastian F. M.; Gao, Yongli; Edwards, R. Lawrence; Zhang, Haiwei; Du, Yajuan

2015-01-01

The collapse of some pre-historical and historical cultures, including Chinese dynasties were presumably linked to widespread droughts, on the basis of synchronicities of societal crises and proxy-based climate events. Here, we present a comparison of ancient inscriptions in Dayu Cave from Qinling Mountains, central China, which described accurate times and detailed impacts of seven drought events during the period of 1520–1920 CE, with high-resolution speleothem records from the same cave. The comparable results provide unique and robust tests on relationships among speleothem δ18O changes, drought events, and societal unrest. With direct historical evidences, our results suggest that droughts and even modest events interrupting otherwise wet intervals can cause serious social crises. Modeling results of speleothem δ18O series suggest that future precipitation in central China may be below the average of the past 500 years. As Qinling Mountain is the main recharge area of two large water transfer projects and habitats of many endangered species, it is imperative to explore an adaptive strategy for the decline in precipitation and/or drought events. PMID:26270656
Orbital- and Millennial-Scale Changes in the Australasian Monsoon Through the Late Pleistocene

NASA Astrophysics Data System (ADS)

Gagan, M. K.; Ayliffe, L. K.; Scroxton, N. G.; Krause, C. E.; Kimbrough, A. K.; Hantoro, W. S.; Drysdale, R.; Hellstrom, J.; Cheng, H.; Edwards, R.; Zhao, J.; Griffiths, M. L.

2012-12-01

Speleothem 18O/16O records from China and Borneo have revealed changes in Asian monsoon rainfall over the last ~570,000 years (e.g. Wang et al. 2008, Cheng et al. 2010, Meckler et al. 2012), yet little is known about orbital- and millennial-scale climate change in the 'southern half' of the Australasian monsoon domain. To fill this gap, we aim to build speleothem 18O/16O records for the seasonal monsoon rainfall belt of south-central Indonesia. Between 2006 and 2011, we sampled speleothems in Flores and southwest Sulawesi (latitudes 5-9oS) with U-series ages extending to 92,000 yBP and ~470,000 yBP, respectively. Development of the 18O/16O records for Sulawesi is in progress, but the basal ages of the speleothems (onset of stalagmite growth) are intriguing because they cluster around glacial terminations, when the East Asian monsoon is known to have been weak (Cheng et al. 2010). There is clear antiphasing of the Flores and China speleothem 18O/16O records on precession time-scales over the last ~90,000 years. A distinct maximum in monsoon rainfall in Flores occurred ~21,000 yBP, suggesting the ITCZ moved south during the Last Glacial Maximum in response to the southern hemisphere summer insolation maximum. This finding indicates that ITCZ positioning in tropical Australasia, through its influence on large-scale oceanic-atmospheric circulation, could have played a key role in the rapid rise of atmospheric CO2 and global warming that ultimately led to the demise of the last ice age, as summarised by Denton et al. (2010) and others. The new Flores speleothem 18O/16O records also show that climate change in the North Atlantic region and Australasian monsoon rainfall are inextricably linked on millennial timescales (Griffiths et al. 2009, Lewis et al. 2011). For example, rapid warming in the North Atlantic region during Dansgaard-Oeschger Event 21 (~86,000 yBP) was linked to a synchronous northward shift of the Australasian ITCZ, marking the final demise of MIS 5b. In contrast, cooling in the North Atlantic during Heinrich Events 3 (~30,000 yBP) and 1 (~16,000 yBP) and the YD (12,800-11,500 yBP) correlates with southward shifts in the Australasian ITCZ. However, the 8,200 yBP cold snap in the North Atlantic produced drying and cooling around Flores. The key difference here is that sea level was relatively high, and cooler sea-surface temperatures in the Indonesian maritime continent at that time (based on nearby coral records) may have suppressed a southward migration of the ITCZ. Cheng, H. et al. (2010), Science, 326, 248-. Denton, G.H. et al. (2010), Science, 328, 1652-. Griffiths, M.L. et al. (2009), Nature Geoscience, 2, 636-. Lewis, S.C. et al. (2011), Earth Planet. Sci. Lett., 303, 133-. Meckler et al. (2012), Science, 336, 1301-. Wang, Y. et al. (2008), Nature, 451, 1090-.
Widespread Permafrost Thaw During Marine Isotope Stage 11 from Arctic Speleothems

NASA Astrophysics Data System (ADS)

Shakun, J. D.; Biller, N.; McGee, D.; Hardt, B. F.; Wong, C. I.; Ford, D.; Lauriol, B.

2017-12-01

Permafrost is widespread in the Arctic and contains twice as much carbon as the atmosphere in the form of frozen organic matter. This carbon may be vulnerable to release to the atmosphere as CH4 and CO2 under a warming climate, making permafrost thaw a potentially significant amplifying feedback. However, the short instrumental record is insufficient to gauge permafrost sensitivity to climate change, and there is considerable spread among permafrost model projections of the future. One way to address this problem is to assess the stability of permafrost during previous interglacial periods, which provide natural experiments to examine the Arctic's sensitivity to warming. Cave mineral deposits (speleothems) in areas of the Arctic that are currently permafrost are relicts of past periods of thaw that enabled meteoric waters to seep into caves and deposit calcite (e.g., Vaks et al., 2013). We employed uranium-thorium dating to constrain the chronology and extent of permafrost thaw in the North American Arctic during the past 600,000 years. We sampled caves from a range of permafrost zones (continuous, discontinuous, and isolated permafrost) and latitudes (67°N to 49°N), in the Yukon, Alaska, Northwest Territories, and along the British Columbia-Alberta border. Of the samples dated to this point (n=67), finite ages tend to cluster near Marine Isotope Stage (MIS) 11 (n=14), with additional samples dated to MIS 13 within uncertainty (n=15). This dataset, coupled with a similar permafrost-speleothem study in Siberia (Vaks et al., 2013), is thus suggestive of an episode of widespread thaw during the MIS 11 interglacial about 400,000 years ago, when several other records also point to strong Arctic warmth. Interestingly, however, ice core records show no anomalous spike in CH4 or CO2 concentrations at this time, perhaps suggesting that the Arctic carbon pool was smaller then or that permafrost carbon release was gradual enough to be buffered by other reservoirs.
The Blake geomagnetic excursion recorded in a radiometrically dated speleothem

NASA Astrophysics Data System (ADS)

Osete, María-Luisa; Martín-Chivelet, Javier; Rossi, Carlos; Edwards, R. Lawrence; Egli, Ramon; Muñoz-García, M. Belén; Wang, Xianfeng; Pavón-Carrasco, F. Javier; Heller, Friedrich

2012-11-01

One of the most important developments in geomagnetism has been the recognition of polarity excursions of the Earth's magnetic field. Accurate timing of the excursions is a key point for understanding the geodynamo process and for magnetostratigraphic correlation. One of the best-known excursions is the Blake geomagnetic episode, which occurred during marine isotope stage MIS 5, but its morphology and age remain controversial. Here we show, for the first time, the Blake excursion recorded in a stalagmite which was dated using the uranium-series disequilibrium techniques. The characteristic remanent magnetisation is carried by fine-grained magnetite. The event is documented by two reversed intervals (B1 and B2). The age of the event is estimated to be between 116.5±0.7 kyr BP and 112.0±1.9 kyr BP, slightly younger (∼3-4 kyr) than recent estimations from sedimentary records dated by astronomical tuning. Low values of relative palaeointensity during the Blake episode are estimated, but a relative maximum in the palaeofield intensity coeval with the complete reversal during the B2 interval was observed. Duration of the Blake geomagnetic excursion is 4.5 kyr, two times lower than single excursions and slightly higher than the estimated diffusion time for the inner core (∼3 kyr).
Coupling of Uranium and Thorium Series Isotope Systematics for Age Determination of Late Pleistocene Zircons using LA-ICP-MS

NASA Astrophysics Data System (ADS)

Sakata, S.; Hirakawa, S.; Iwano, H.; Danhara, T.; Hirata, T.

2014-12-01

Zircon U-Th-Pb dating method is one of the most important tools for estimating the duration of magmatism by means of coupling of uranium, actinium and thorium decay series. Using U-Pb dating method, its reliability is principally guaranteed by the concordance between 238U-206Pb and 235U-207Pb ages. In case of dating Quaternary zircons, however, the initial disequilibrium effect on 230Th and 231Pa should be considered. On the other hands, 232Th-208Pb dating method can be a simple but powerful approach for investigating the age of crystallization because of negligible influence from initial disequilibrium effect. We have developed a new correction model for accurate U-Pb dating of the young zircon samples by taking into consideration of initial disequilibrium and a U-Pb vs Th-Pb concordia diagram for reliable age calibration was successfully established. Hence, the U-Th-Pb dating method can be applied to various zircons ranging from Hadean (4,600 Ma) to Quaternary (~50 ka) ages, and this suggests that further detailed information concerning the thermal history of the geological sequences can be made by the coupling of U-Th-Pb, fission track and Ar-Ar ages. In this presentation, we will show an example of U-Th-Pb dating for zircon samples from Sambe Volcano (3 to 100 ka), southwest Japan and the present dating technique using LA-ICP-MS.
Confirmation of a late middle Pleistocene age for the Omo Kibish 1 cranium by direct uranium-series dating.

PubMed

Aubert, Maxime; Pike, Alistair W G; Stringer, Chris; Bartsiokas, Antonis; Kinsley, Les; Eggins, Stephen; Day, Michael; Grün, Rainer

2012-11-01

While it is generally accepted that modern humans evolved in Africa, the specific physical evidence for that origin remains disputed. The modern-looking Omo 1 skeleton, discovered in the Kibish region of Ethiopia in 1967, was controversially dated at ~130 ka (thousands of years ago) by U-series dating on associated Mollusca, and it was not until 2005 that Ar-Ar dating on associated feldspar crystals in pumice clasts provided evidence for an even older age of ~195 ka. However, questions continue to be raised about the age and stratigraphic position of this crucial fossil specimen. Here we present direct U-series determinations on the Omo 1 cranium. In spite of significant methodological complications, which are discussed in detail, the results indicate that the human remains do not belong to a later intrusive burial and are the earliest representative of anatomically modern humans. Given the more archaic morphology shown by the apparently contemporaneous Omo 2 calvaria, we suggest that direct U-series dating is applied to this fossil as well, to confirm its age in relation to Omo 1. Copyright © 2012 Elsevier Ltd. All rights reserved.
A Two-year Record of Daily Rainfall Isotopes from Fiji: Implications for Reconstructing Precipitation from Speleothem δ18O

NASA Astrophysics Data System (ADS)

Brett, M.; Mattey, D.; Stephens, M.

2015-12-01

Oxygen isotopes in speleothem provide opportunities to construct precisely dated records of palaeoclimate variability, underpinned by an understanding of both the regional climate and local controls on isotopes in rainfall and groundwater. For tropical islands, a potential means to reconstruct past rainfall variability is to exploit the generally high correlation between rainfall amount and δ18O: the 'amount effect'. The GNIP program provides δ18O data at monthly resolution for several tropical Pacific islands but there are few data for precipitation isotopes at daily resolution, for investigating the amount effect over different timescales in a tropical maritime setting. Timescales are important since meteoric water feeding a speleothem has undergone storage and mixing in the aquifer system and understanding how the isotope amount effect is preserved in aquifer recharge has fundamental implications on the interpretation of speleothem δ18O in terms of palaeo-precipitation. The islands of Fiji host speleothem caves. Seasonal precipitation is related to the movement of the South Pacific Convergence Zone, and interannual variations in rainfall are coupled to ENSO behaviour. Individual rainfall events are stratiform or convective, with proximal moisture sources. We have daily resolution isotope data for rainfall collected at the University of the South Pacific in Suva, covering every rain event in 2012 and 2013. δ18O varies between -18‰ and +3‰ with the annual weighted averages at -7.6‰ and -6.8‰ respectively, while total recorded rainfall amount is similar in both years. We shall present analysis of our data compared with GNIP, meteorological data and back trajectory analyses to demonstrate the nature of the relationship between rainfall amount and isotopic signatures over this short timescale. Comparison with GNIP data for 2012-13 will shed light on the origin of the amount effect at monthly and seasonal timescales in convective, maritime, tropical climates.
Millennial-scale Asian summer monsoon variations in South China since the last deglaciation

NASA Astrophysics Data System (ADS)

Wang, Xisheng; Chu, Guoqiang; Sheng, Mei; Zhang, Shuqin; Li, Jinhua; Chen, Yun; Tang, Ling; Su, Youliang; Pei, Junling; Yang, Zhenyu

2016-10-01

Characterizing spatiotemporal variability of the Asian summer monsoon (ASM) is critical for full understanding of its behavior, dynamics, and future impacts. The present knowledge about ASM variations since the last glaciation in South China largely relies on several precisely-dated speleothem stable oxygen isotope (δ18 O) records. Although these speleothem δ18 O signals provide useful evidence for regional past environmental changes, their validity for denoting ASM intensity remains a great controversy. The Huguangyan Maar Lake (HML) provides one of the most complete archives of environmental and climatic changes in the tropical-subtropical South and East Asia since the last glaciation. Here we document a continuous centennial- to millennial-scale ASM record over the past 16 ky BP from the high-sedimentation-rate HML sediments. In contrast with the low-amplitude variations of Chinese speleothem-derived δ18 O signals and the Chinese loess-based monsoon precipitation proxy indexes, our multi-proxy records reveal a pattern of high-amplitude regional climatic fluctuations, including fine-scale oscillations during the Bølling-Allerød warming, the 8.2 ka cooling event, and an abrupt climate shift from 6.5-5.9 ka. The existence of Bond-like cold/dry events indicates a distinct influence of the North Atlantic circulation on low-latitude monsoon changes. The broad comparability between the HML paleo-proxies, Chinese speleothem δ18 O records, and the northern hemisphere summer insolation throughout the Holocene, suggests that solar insolation exerts a profound influence on ASM changes. These findings reinforce a model of combined insolation and glacial forcing of the ASM.
Natural radionuclide mobility and its influence on U-Th-Pb dating of secondary minerals from the unsaturated zone at Yucca Mountain, Nevada

USGS Publications Warehouse

Neymark, L.A.; Amelin, Y.V.

2008-01-01

Extreme U and Pb isotope variations produced by disequilibrium in decay chains of 238U and 232Th are found in calcite, opal/chalcedony, and Mn-oxides occurring as secondary mineral coatings in the unsaturated zone at Yucca Mountain, Nevada. These very slowly growing minerals (mm my-1) contain excess 206Pb and 208Pb formed from excesses of intermediate daughter isotopes and cannot be used as reliable 206Pb/238U geochronometers. The presence of excess intermediate daughter isotopes does not appreciably affect 207Pb/235U ages of U-enriched opal/chalcedony, which are interpreted as mineral formation ages. Opal and calcite from outer (younger) portions of coatings have 230Th/U ages from 94.6 ?? 3.7 to 361.3 ?? 9.8 ka and initial 234U/238U activity ratios (AR) from 4.351 ?? 0.070 to 7.02 ?? 0.12, which indicate 234U enrichment from percolating water. Present-day 234U/238U AR is ???1 in opal/chalcedony from older portions of the coatings. The 207Pb/235U ages of opal/chalcedony samples range from 0.1329 ?? 0.0080 to 9.10 ?? 0.21 Ma, increase with microstratigraphic depth, and define slow long-term average growth rates of about 1.2-2.0 mm my-1, in good agreement with previous results. Measured 234U/238U AR in Mn-oxides, which pre-date the oldest calcite and opal/chalcedony, range from 0.939 ?? 0.006 to 2.091 ?? 0.006 and are >1 in most samples. The range of 87Sr/86Sr ratios (0.71156-0.71280) in Mn-oxides overlaps that in the late calcite. These data indicate that Mn-oxides exchange U and Sr with percolating water and cannot be used as a reliable dating tool. In the U-poor calcite samples, measured 206Pb/207Pb ratios have a wide range, do not correlate with Ba concentration as would be expected if excess Ra was present, and reach a value of about 1400, the highest ever reported for natural Pb. Calcite intergrown with opal contains excesses of both 206Pb and 207Pb derived from Rn diffusion and from direct ??-recoil from U-rich opal. Calcite from coatings devoid of opal/chalcedony contains 206Pb and 208Pb excesses, but no appreciable 207Pb excesses. Observed Pb isotope anomalies in calcite are explained by Rn-produced excess Pb. The Rn emanation may strongly affect 206Pb-238U ages of slow-growing U-poor calcite, but should be negligible for dating fast-growing U-enriched speleothem calcite.
Advancements in the use of speleothems as climate archives

NASA Astrophysics Data System (ADS)

Wong, Corinne I.; Breecker, Daniel O.

2015-11-01

Speleothems have become a cornerstone of the approach to better understanding Earth's climatic teleconnections due to their precise absolute chronologies, their continuous or semicontinuous deposition and their global terrestrial distribution. We review the last decade of speleothem-related research, building off a similar review by McDermott (2004), in three themes - i) investigation of global teleconnections using speleothem-based climate reconstructions, ii) refinement of climate interpretations from speleothem proxies through cave monitoring, and iii) novel, technical methods of speleothem-based climate reconstructions. Speleothem records have enabled critical insight into the response of global hydroclimate to large climate changes. This includes the relevant forcings and sequence of climatic responses involved in glacial terminations and recognition of a global monsoon response to climate changes on orbital and millennial time scales. We review advancements in understanding of the processes that control speleothem δ13C values and introduce the idea of a direct atmospheric pCO2 influence. We discuss progress in understanding kinetic isotope fractionation, which, with further advances, may help quantify paleoclimate changes despite non-equilibrium formation of speleothems. This feeds into the potential of proxy system modeling to consider climatic, hydrological and biogeochemical processes with the objective of quantitatively interpreting speleothem proxies. Finally, we provide an overview of emerging speleothem proxies and novel approaches using existing proxies. Most recently, technical advancements made in the measurement of fluid inclusions are now yielding reliable determinations of paleotemperatures.
Younger Dryas to Early Holocene paleoclimate in Cantabria (N Spain): Constraints from speleothem Mg, annual fluorescence banding and stable isotope records

NASA Astrophysics Data System (ADS)

Rossi, Carlos; Bajo, Petra; Lozano, Rafael P.; Hellstrom, John

2018-07-01

The Younger Dryas (YD) stadial represents the most abrupt climate change of the Earth's recent history. Thus, understanding its causes and different local responses is relevant for Quaternary paleoclimatology. We present a speleothem high-resolution proxy record of the Lateglacial to Early Holocene paleoclimate of the Cantabrian Cordillera (N Spain), a strategic location to evaluate the influence of North Atlantic events such as the YD on South-Western Europe. Fluorescence lamination, growth-rate, stable-isotope, and [Mg] records from stalagmite SIR-1 were dated using an age-depth model constrained by U-Th dates and annual-lamina counting. The YD is recorded as a prominent positive δ13C excursion whose chronology (12.95 ± 0.14 to 11.62 ± 0.16 ka) and shape closely agree with the GS-1 stadial as defined in Greenland ice, supporting the event synchronicity in both areas. A colder and drier YD climate limited soil productivity and dripwater availability, leading to higher δ13C and [Mg], reduced growth rate, and virtually absent fluorescence lamination. The early YD record (until ∼12.5 ka) reflects increasing aridity, whereas the late YD (from ∼12.2 ka on) shows the opposite trend. At the YD boundaries, temperature changes influenced the [Mg] record by modifying the Mg partition into calcite. However, this effect was superseded by major changes in dripwater Mg/Ca linked to rainfall variations. During the Early Holocene, the Arnero Sierra was forested and had a relatively warm and humid seasonal climate, indicated in SIR-1 by higher growth rates, lower δ13C and [Mg], and well-developed fluorescent lamination. Similar to other high-resolution stalagmitic records of the Cordillera, from ∼8.5 to 8.0 ka SIR-1 reflects a temporary trend of increasing aridity.
Climatic variability during the penultimate interglacial (MIS 7) and glacial (MIS 6) periods recorded in a speleothem from Kanaan cave, Lebanon (Central Levant)

NASA Astrophysics Data System (ADS)

Nehme, Carole; Verheyden, Sophie; Breitenbach, Sebastian F. M.; Gillikin, David P.; Verheyden, Anouk; Cheng, Hai; Edwards, Laurence; Hellstrom, John; Noble, Stephen R.; Farrant, Andrew R.; Sahy, Diana; Goovaerts, Thomas; Salem, Ghada; Claeys, Philippe

2017-04-01

Little is known about terrestrial climate dynamics of the Levant during the penultimate interglacial-glacial period. A well-dated stalagmite ( 194 to 154 ka) from Kanaan cave, located near the Mediterranean in Lebanon, is examined for its petrography, growth history, and stable isotope geochemistry to answer the climate instability pattern of the glacial MIS 6 and possible wet phases. A highly resolved continental climate record from the northern Levant has been recovered from this precisely U-Th-dated speleothem, spanning the late penultimate interglacial (equivalent of the MIS 7) to the mid-penultimate glacial period ( MIS 6). The stalagmite grew slowly and discontinuously with an unstable isotopic pattern from 194 and at least up to 178 ka. Subsequently, the stalagmite ceased growing from 169.5 to 163.1 ka (interpolated ages) with a hiatus of ca. 6.24 ka according to the model age. However, low δ 18O and δ 13C values indicate generally cold, but overall more humid climate compared to the last glacial (MIS 3). Higher growth rates during the mid-penultimate glacial period ( 163-154 ka) are most probably linked to increased water recharge in the vadose zone. A short More distinct layering in the upper section compared to the basal part of the stalagmite suggests stronger seasonality from 163 ka to 154 ka. Negative oxygen and carbon isotope excursions were found at ˜155.5 ka, ˜156 ka, between ˜159.6 and ˜160.1 ka and at ˜162.6 ka. The inferred Kanaan cave humid intervals during the mid-penultimate period follow variations of pollen records in the Eastern and Western Mediterranean basins and correlate well with the synthetic Greenland records and East Asian Summer Monsoon Interstadials, indicating short warm/wet periods similar to the D-O events during MIS 4-3 in the Eastern Mediterranean region.
U-Pb SHRIMP dating of uraniferous opals

USGS Publications Warehouse

Nemchin, A.A.; Neymark, L.A.; Simons, S.L.

2006-01-01

U-Pb and U-series analyses of four U-rich opal samples using sensitive high-resolution ion microprobe (SHRIMP) demonstrate the potential of this technique for the dating of opals with ages ranging from several tens of thousand years to millions of years. The major advantages of the technique, compared to the conventional thermal ionisation mass spectrometry (TIMS), are the high spatial resolution (???20 ??m), the ability to analyse in situ all isotopes required to determine both U-Pb and U-series ages, and a relatively short analysis time which allows obtaining a growth rate of opal as a result of a single SHRIMP session. There are two major limitations to this method, determined by both current level of development of ion probes and understanding of ion sputtering processes. First, sufficient secondary ion beam intensities can only be obtained for opal samples with U concentrations in excess of ???20 ??g/g. However, this restriction still permits dating of a large variety of opals. Second, U-Pb ratios in all analyses drifted with time and were only weakly correlated with changes in other ratios (such as U/UO). This drift, which is difficult to correct for, remains the main factor currently limiting the precision and accuracy of the U-Pb SHRIMP opal ages. Nevertheless, an assumption of similar behaviour of standard and unknown opals under similar analytical conditions allowed successful determination of ages with precisions of ???10% for the samples investigated in this study. SHRIMP-based U-series and U-Pb ages are consistent with TIMS dating results of the same materials and known geological timeframes. ?? 2005 Elsevier B.V. All rights reserved.

Dating of the Basal Aurignacian Sandwich at Abric Romanı́ (Catalunya, Spain) by Radiocarbon and Uranium-Series

USGS Publications Warehouse

Bischoff, James L.; Ludwig, Kenneth R.; Garcia, Jose Francisco; Carbonell, E.; Vaquero, Manola; Stafford, Thomas W.; Jull, A.J.T.

1994-01-01

Abric Romani{dotless}??, a rock shelter located near Barcelona, Spain, contains a charcoal-bearing basal Aurignacian occupation level sandwiched between beds of moss-generated carbonate. The Aurignacian culture is the oldest artefact industry in Europe with which anatomically modern human remains have been associated. Radiocarbon analysis of charcoal fragments by accelerator mass spectrometry (AMS) dates the basal Aurignacian to about 37 ?? 2 ka bp. U-series analyses by alpha spectrometry (AS) and mass spectrometry (MS) date the enclosing carbonate to 43 ?? 1 ka bp. These results confirm the great antiquity of the Aurignacian in northern Spain and support the similar AMS dates from El Castillo and l'Arbreda caves. They also show that radiocarbon dates are significantly younger than U-series at 40 ka bp, as predicted by theory. ?? 1994 Academic Press. All rights reserved.
A 74 or 75 ka Age for the Toba Super-eruption? Resolving the Debate.

NASA Astrophysics Data System (ADS)

Storey, M.; Roberts, R. G.; Haslam, M.

2015-12-01

The Toba super-eruption in Sumatra, ~74,000 years ago, was the largest terrestrial volcanic event of the Quaternary. Some have proposed that the eruption produced widespread perturbations of climate and ecosystems. Evaluation of the environmental impact of the eruption and linkage to rapid climate oscillations recorded in ice core, sediment and speleothem records requires an accurate and precise age for the event, with uncertainties at the centurial level. Two recent studies, however, have proposed quite different 40Ar/39Ar ages for this volcanic event of 73.88 ± 0.32 ka (Storey et al., 2012) and 75.0 ± 0.9 ka (Mark et al, 2014), with both uncertainties expressed at 1σ, leading to radically different interpretations of its global impact. 40Ar/39Ar is a relative dating method, in which the unknown is run against a mineral standard of known age. Storey et al (2012) obtained their age estimate using a new-generation, multi-collector noble gas mass spectrometer (NU Instruments Noblesse) equipped with ion-counters, while Mark et al. (2014) used an earlier generation of lower resolution, single-collector mass spectrometer (MAP 215-50). Both studies used the same mineral standard (Alder Creek sanidine, ACs), except that Mark et al. (2014) used an older value, which accounts for the discrepancy in ages between the two studies. The value used by Mark et al. for ACs is geologically implausible, because it results in older 40Ar/39Ar dates than the youngest co-existing zircon U/Pb CATIMS ages (e.g., Rivera et al., 2013, 2014). Use of the same value for ACs as used by Storey et al. (2012) results in an identical, but less precise, astronomically calibrated age of 73.9 ± 0.9 ka for the Mark et al. data. Here, we review combined U/Pb and 40Ar/39Ar age data (both published and unpublished) for a number of Quaternary and older volcanic ash deposits, and U/Th ages for late Quaternary speleothems. These data strongly support the age assigned to ACs by Storey et al. (2012) and Rivera et al. (2013) and, hence, an astronomically calibrated age of 73.9 ka age for the Toba super-eruption. This confirms the original high-precision 40Ar/39Ar age determination of Storey et al. (2012) Storey et al., 2012, PNAS, 109, 18684-18688; Rivera et al., 2013, Chem. Geol., 345, 87-98; Rivera et al., 2014, Geol. 42 643-646; Mark et al, 2014, Quat. Geochron. 21, 90-103
The Flores speleothem carbon isotope record: vegetation, volcanism and the demise of Homo floresiensis

NASA Astrophysics Data System (ADS)

Scroxton, N.; Gagan, M. K.; Ayliffe, L. K.; Hantoro, W. S.; Hellstrom, J. C.; Cheng, H.; Edwards, R. L.; Zhao, J. X.; Suwargadi, B. W.; Scott-Gagan, H.; Cowley, J. A.; Rifai, H.

2015-12-01

The last surviving non-human member of the Homo genus: Homo floresiensis, disappeared from the stratigraphic record in Liang Bua cave, Flores, Indonesia, between 17 and 10 kyr BP (Roberts et al. 2009, J. Hum. Evol.). The cause of the disappearance (e.g. climate change, volcanic catastrophe or human competition) has not been established. Here, we present a new 92,000-year long speleothem δ13C record for Liang Luar cave, 800m South of Liang Bua. Our record acts as a proxy for local environmental and vegetation health throughout H. floresiensis' occupation of the area. The Liang Luar speleothem δ13C record is primarily a record of vegetation productivity and soil respiration rates, highlighting local ecological responses to changing regional and global climate forcings such as temperature, atmospheric pCO2 and precipitation amount. Changes in speleothem δ13C can largely be considered an environmental response to climate change. Events that caused significant harm to the local environment and H. floresiensis are likely to be outside the natural range of variability: being quick enough or extreme enough that adaptation to new conditions is not possible. We identify disturbances to the vegetation system using two indicators in the speleothem record. 1) Abrupt positive δ13C excursions which indicate periods of reduced vegetative activity. 2) A loss of correlation between the δ13C and δ18O records, indicating that precipitation is no longer a dominant control on vegetation productivity. The largest (8‰) and longest (7 kyr) abrupt positive excursion, the 68 kyr event, sees positive speleothem δ13C values, due to increased bedrock contribution and/or C4 vegetation at this time. Crucially a H. floresiensis occupation interval dates to this period. The largest abrupt deterioration in vegetation (positive δ13C excursion) between 17 and 10 kyr BP is a 1 in 5kyr occurrence - An event of a magnitude that was likely encountered and survived by H. floresiensis multiple times during the last 90kyr. The mechanism/s that led to the disappearance of H. floresiensis must have been highly selective, and did not have a major impact on the local environment. This seemingly rules out volcanism and climate change as potential agents, leaving us with an intriguing puzzle as to what caused the recent extinction of Homo floresiensis.
75 FR 14660 - Proposed Collection: Comment Request

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-26

... required by the Paperwork Reduction Act of 1995, Public Law 104-13 (44 U.S.C. 3506(c)(2)(A). Currently the... transaction request for U.S. Treasury Securities State and Local Government Series Early Redemption. DATES...: U.S. Treasury Securities State and Local Government Series Early Redemption Request. OMB Number...
Practical experience using speleothem data in multi-proxy climate reconstructions

NASA Astrophysics Data System (ADS)

Graham, N.

2009-04-01

Speleothem records have clear potential to extend and sharpen our understanding of past climate change. Many speleothem records feature both high sample resolution and precision age models, characteristics generally available only in tree-ring records, among terrestrial climate proxies. Speleothem records also avoid some processes that add uncertainty to the interpretation of biological proxy records. At the same time, model results suggest that even if speleothems did provide long and perfect records of meteoric water isotope concentrations, it would not be always be obvious how to interpret the isotopic fluctuations unambiguously in terms of precipitation or temperature variability. Other uncertainties can arise from local hydrologic and speleothem growth processes, as well as sampling and calibration uncertainties. Similar comments apply to other sorts of speleothem-derived records, e.g., verve thickness. These issues of interpretation are especially important in cases where data availability makes calibration to local climate data problematic and when past climate conditions limit the relevance of such calibrations. The presentation will focus broadly on the use of speleothem records together with other sorts of proxy records either to get a general idea of climatic change during some period, or for more formal climate field reconstruction. Examples from few such efforts will be given. Results from simulations with models incorporating stable water isotopes will be discussed, with consideration of what the results imply about the climatic interpretation of speleothem isotope records. The views will be those a climate scientist trying to make better use of speleothem data, a perspective which will highlight 1) where climate researchers would benefit from better understanding of isotope and speleothem processes, and 2) what steps that speleothem researchers could take to tighten the physical interpretation of their records. Convergence on these points will allow us to take better take advantage of the precision and spatial distribution of speleothem records offer for the understanding of past climate.
Inter-annual precipitation variabiity inferred from late Holocene speleothem records from Fiji: implications for SPCZ localisation and ENSO behaviour

NASA Astrophysics Data System (ADS)

Mattey, D.; Stephens, M.; Hoffmann, D.; Brett, M.

2015-12-01

The modern tropical Fiji climate is characterised by seasonal rainfall controlled by the position of the South Pacific Convergence Zone (SPCZ). Interannual rainfall is strongly modulated on decadal timescales by ENSO with higher rainfall associated with La Nina events. Voli Voli cave near Sigatoga (Viti Levu) is a stream passage that has been monitored since 2009. A U-Th dated laminated speleothem spans a 1500 year interval across the transition from the Medieval Warm Period into the Little Ice Age marked by a fabric change from finely laminated calcite with thin clay layers, to white well-laminated calcite. The older record is characterised by rising δ13C values followed by a rapid decrease in δ13C around 1200 AD. Evidence from cave monitoring shows that cave air CO2 levels are strongly seasonal as a result of greater ventilation by winter trade winds and high resolution δ13C record shows regularly spaced peaks correlated with paired laminae and cycles in P and S which provide annual markers driven by rainfall and seasonal ventilation. δ18O values remain relatively unchanged throughout the record but micromilling at sub-annual resolution reveals systematic cycles in δ18O that span groups of paired laminae with an inferred periodicity of 3-7 years i.e. a similar frequency to modern ENSO. The presence of these sub-decadal cycles in δ18O may be a result of a combination of factors. The amplitude of 2-3‰ would be equivalent to an amount-effect related change in annual precipitation of around 50% but an additional smoothing process, perhaps a result of aquifer storage, is required to attenuate interannual variance in precipitation. The Voli Voli record provides evidence of an underlying climatic change to more frequent La Niña conditions from 1200 AD and may be associated with increased conflict, shifts in settlements and changes in subsistence strategies on the island. Coeval speleothem isotope records from tropical Pacific Islands provide a provide a powerful means of locating the mean position and intensity of the SPCZ and changes in regional coupling of ocean-atmospheric circulation patterns.
Middle Palaeolithic refugium, or archaeological misconception? A new U-Series and radiocarbon chronology of Abric Agut (Capellades, Spain)

USGS Publications Warehouse

Vaquero, Manola; Esteban, M.; Allue, E.; Vallverdu, J.; Carbonell, E.; Bischoff, J.L.

2002-01-01

New U-Series and C14 (AMS) dates are provided for the Abric Agut (Capellades, Barcelona, Spain). This site was previously considered to be of Middle Palaeolithic age according to the characteristics of the lithic assemblage. In addition, human teeth were uncovered and attributed to neandertals. However, radiometric dating clearly indicates a Late Pleistocene-Early Holocene age. ?? 2002 Elsevier Science Ltd. All rights reserved.
Investigation into MIS 11 in the U.S. Great Basin Using Trace Elements and Stable Isotopes from two Lehman Caves Stalagmites

NASA Astrophysics Data System (ADS)

Neary, A.; McGee, D.; Tal, I.; Shakun, J. D.

2015-12-01

Marine Isotope Stage 11 (MIS 11) represents a long interglacial period of high temperatures and muted orbital variability that occurred around 424-374 kya, and is referred to as a 'super-interglacial'. MIS 11 is marked by especially pronounced high latitude warming in the Northern Hemisphere from 410-400 ka and thus presents a natural experiment for investigating the response of Great Basin precipitation to high latitude temperatures.MIS 11 is recorded by stalagmites LC3 and BT1 from Lehman Caves in Great Basin National Park, Nevada. LC3 represents 378-413 ka, while BT1 has a bottom age of 410 ka. Ongoing U-Th dating will refine chronologies from these samples. We will present stable isotope (δ13C and δ18O) and trace element (Mg/Ca and Sr/Ca) data from these stalagmites to study changes in precipitation recorded in them. Previous studies have shown a relationship between Mg/Ca, Sr/Ca, δ13C and prior calcite precipitation, and thus infiltration rates, in the cave system (Cross et al., 2015; Steponaitis et al., 2015). Meanwhile, δ18O has been shown to reflect larger scale atmospheric circulation.We will compare the records to previously published trace element and stable isotope data from more recent interglacials (Lachniet et al., 2014; Cross et al., 2015; Steponaitis et al., 2015) to test whether extensive high-latitude warming during MIS 11 was marked by anomalous precipitation patterns in the Great Basin. As they are coeval, we will also test the reproducibility between the stalagmites.References cited:Cross M., et al. (2015) Great Basin hydrology, paleoclimate, and connections with the North Atlantic: A speleothem stable isotope and trace element record from Lehman Caves, NV. Quaternary Science Reviews, in press.Steponaitis E., et al. (2015) Mid-Holocene drying the U.S. Great Basin recorded in Nevada speleothems. Quaternary Science Reviews, in press.Lachniet M. S., et al. (2014) Orbital control of western North America atmospheric circulation and climate over two glacial cycles. Nature Communications 5, 1-8.
Correlations of cave levels, stream terraces and planation surfaces along the River Mur—Timing of landscape evolution along the eastern margin of the Alps

PubMed Central

Wagner, Thomas; Fritz, Harald; Stüwe, Kurt; Nestroy, Othmar; Rodnight, Helena; Hellstrom, John; Benischke, Ralf

2011-01-01

The transition zone of the Eastern Alps to the Pannonian Basin provides one of the best sources of information on landscape evolution of the Eastern Alpine mountain range. The region was non-glaciated during the entire Pleistocene. Thus, direct influence of glacial carving as a landscape forming process can be excluded and relics of landforms are preserved that date back to at least the Late Neogene. In this study, we provide a correlation between various planation surfaces across the orogen-basin transition. In particular, we use stream terraces, planation surfaces and cave levels that cover a vertical spread of some 700 m. Our correlation is used to show that both sides of the transition zone uplifted together starting at least about 5 Ma ago. For our correlation we use recently published terrestrial cosmogenic nuclide (TCN) burial ages from cave sediments, new optically stimulated luminescence (OSL) ages of a stream terrace and U–Th ages from speleothems. Minimum age constraints of cave levels from burial ages of cave sediments covering the last ~ 4 Ma are used to place age constraints on surface features by parallelizing cave levels with planation surfaces. The OSL results for the top section of the type locality of the Helfbrunn terrace suggest an Early Würm development (80.5 ± 3.7 to 68.7 ± 4.0 ka). The terrace origin as a penultimate gravel deposit (in classical Alpine terminology Riss) is therefore questioned. U-series speleothem ages from caves nearby indicate formation during Marine Isotope Stages (MIS) 5c and 5a which are both interstadial warm periods. As OSL ages from the terrace also show a time of deposition during MIS 5a ending at the MIS 5/4 transition, this supports the idea of temperate climatic conditions at the time of deposition. In general, tectonic activity is interpreted to be the main driving force for the formation and evolution of these landforms, whilst climate change is suggested to be of minor importance. Obvious hiatuses in Miocene to Pleistocene sediments are related to ongoing erosion and re-excavation of an uplifting and rejuvenating landscape. PMID:22053124
Why was there increased moisture in the eastern Caribbean when Europe was cold? Evidence from Speleothems

NASA Astrophysics Data System (ADS)

Winter, Amos; Vieten, Rolf-martin; Miller, Thomas; Mangini, Augusto; Scholz, Denis; Kushnir, Yochanan; Black, David

2014-05-01

We present evidence for the last 10,000 years from speleothems collected from the eastern Caribbean showing that this region was anomalously moist at the same time that Europe and the north Atlantic were unusually cold. The most noticeable period for this association was during the 8.2ka event when Greenland ice cores (GISP2) show that northern Europe and the north Atlantic were cooler by 3 - 6 deg C. The trigger for the 8.2ka event is thought to be pulsed melt water discharges from a multi-event drainage of proglacial lakes associated with the decaying Laurentide Ice Sheet margin. The melt water apparently slowed the thermohaline circulation decreasing warmth to northern Europe. At the same time moisture transfer to the northern latitudes may have slowed resulting in the observed lower latitude precipitation patterns. The eastern Caribbean seems to be especially sensitive to the changes in the strength of the Atlantic meridional overturning circulation (AMOC). Higher precipitation values may also have increased lowland flooding along the coastal areas of north eastern South America, already affected by early Holocene sea-level change, and are linked to social territory reshuffling which stimulated the earliest migrations into the Caribbean Archipelago shortly afterwards. Our age models based on precise MC ICPMS 230ThU dating indicate that the eastern Caribbean stalagmites all grew at about the same rate of 15 cm through the 8.2ka event, much faster than during any other growth period, except today when they are also growing at an accelerated rate.
An early modern human presence in Sumatra 73,000-63,000 years ago.

PubMed

Westaway, K E; Louys, J; Awe, R Due; Morwood, M J; Price, G J; Zhao, J-X; Aubert, M; Joannes-Boyau, R; Smith, T M; Skinner, M M; Compton, T; Bailey, R M; van den Bergh, G D; de Vos, J; Pike, A W G; Stringer, C; Saptomo, E W; Rizal, Y; Zaim, J; Santoso, W D; Trihascaryo, A; Kinsley, L; Sulistyanto, B

2017-08-17

Genetic evidence for anatomically modern humans (AMH) out of Africa before 75 thousand years ago (ka) and in island southeast Asia (ISEA) before 60 ka (93-61 ka) predates accepted archaeological records of occupation in the region. Claims that AMH arrived in ISEA before 60 ka (ref. 4) have been supported only by equivocal or non-skeletal evidence. AMH evidence from this period is rare and lacks robust chronologies owing to a lack of direct dating applications, poor preservation and/or excavation strategies and questionable taxonomic identifications. Lida Ajer is a Sumatran Pleistocene cave with a rich rainforest fauna associated with fossil human teeth. The importance of the site is unclear owing to unsupported taxonomic identification of these fossils and uncertainties regarding the age of the deposit, therefore it is rarely considered in models of human dispersal. Here we reinvestigate Lida Ajer to identify the teeth confidently and establish a robust chronology using an integrated dating approach. Using enamel-dentine junction morphology, enamel thickness and comparative morphology, we show that the teeth are unequivocally AMH. Luminescence and uranium-series techniques applied to bone-bearing sediments and speleothems, and coupled uranium-series and electron spin resonance dating of mammalian teeth, place modern humans in Sumatra between 73 and 63 ka. This age is consistent with biostratigraphic estimations, palaeoclimate and sea-level reconstructions, and genetic evidence for a pre-60 ka arrival of AMH into ISEA. Lida Ajer represents, to our knowledge, the earliest evidence of rainforest occupation by AMH, and underscores the importance of reassessing the timing and environmental context of the dispersal of modern humans out of Africa.
An early modern human presence in Sumatra 73,000-63,000 years ago

NASA Astrophysics Data System (ADS)

Westaway, K. E.; Louys, J.; Awe, R. Due; Morwood, M. J.; Price, G. J.; Zhao, J.-X.; Aubert, M.; Joannes-Boyau, R.; Smith, T. M.; Skinner, M. M.; Compton, T.; Bailey, R. M.; van den Bergh, G. D.; de Vos, J.; Pike, A. W. G.; Stringer, C.; Saptomo, E. W.; Rizal, Y.; Zaim, J.; Santoso, W. D.; Trihascaryo, A.; Kinsley, L.; Sulistyanto, B.

2017-08-01

Genetic evidence for anatomically modern humans (AMH) out of Africa before 75 thousand years ago (ka) and in island southeast Asia (ISEA) before 60 ka (93-61 ka) predates accepted archaeological records of occupation in the region. Claims that AMH arrived in ISEA before 60 ka (ref. 4) have been supported only by equivocal or non-skeletal evidence. AMH evidence from this period is rare and lacks robust chronologies owing to a lack of direct dating applications, poor preservation and/or excavation strategies and questionable taxonomic identifications. Lida Ajer is a Sumatran Pleistocene cave with a rich rainforest fauna associated with fossil human teeth. The importance of the site is unclear owing to unsupported taxonomic identification of these fossils and uncertainties regarding the age of the deposit, therefore it is rarely considered in models of human dispersal. Here we reinvestigate Lida Ajer to identify the teeth confidently and establish a robust chronology using an integrated dating approach. Using enamel-dentine junction morphology, enamel thickness and comparative morphology, we show that the teeth are unequivocally AMH. Luminescence and uranium-series techniques applied to bone-bearing sediments and speleothems, and coupled uranium-series and electron spin resonance dating of mammalian teeth, place modern humans in Sumatra between 73 and 63 ka. This age is consistent with biostratigraphic estimations, palaeoclimate and sea-level reconstructions, and genetic evidence for a pre-60 ka arrival of AMH into ISEA. Lida Ajer represents, to our knowledge, the earliest evidence of rainforest occupation by AMH, and underscores the importance of reassessing the timing and environmental context of the dispersal of modern humans out of Africa.
Uranium-Series Dating of the East Franklin Mountain's Fault Carbonates in El Paso, Texas

NASA Astrophysics Data System (ADS)

Garcia, V. H.; Ma, L.; Pavlis, T. L.; Hurtado, J. M., Jr.

2017-12-01

Direct dating of fault activity is a fundamentally important part of many paleoseismic studies and has potential implications on the quantity, magnitude, recurrence intervals, and timing of earthquake occurrences in the past and future. Faults in the Rio Grande Rift (RGR) in southern New Mexico and West Texas have often been overlooked in seismic hazard assessments due to inferred low tectonic rates and long recurrence intervals. However, there is geologic evidence from surface ruptures that at least 22 large earthquakes (M > 6.25) have occurred in the RGR within the last 10,000 kyrs. The binational conurbation of the El Paso-Juarez region (home to 2.3 million people) lies in the southern extent of the RGR and is traversed by many Quaternary faults, which pose a potentially catastrophic hazard for the region. One fault in particular, the East Franklin Mountains fault (EFMF), is made up of many smaller fault segments that cross through heavily populated areas of the El Paso-Juarez region. Direct dating of past movement on a central segment of the EFMF is a fundamental and important piece of the puzzle in understanding when and how often seismic activity occurred in the fault. In this study, we applied Uranium-series (U-series) dating of fault carbonates collected from a trench that was dug on the central segment of the EFMF. Fault related calcite precipitants and pedogenic carbonates from a nearby soil profile were collected to (1) constraint the timing of past fault activity and (2) understand the relationship and timing of pedogenic carbonate formation away from the EFMF. U-series dating reveals that pedogenic carbonates collected from colluvial wedges along the fault are approximately half the optically stimulated luminescence age of the deposits, suggesting the U-Series dates record a relatively continuous accumulation of carbonates post-deposition. U-Series dates from within the EFMF, however, provided potentially the best estimates for the age of the most recent seismic event with ages of 10 - 12 kyrs, suggesting this method has potential broader applications in paleoseismic studies.
Radiocarbon dating of terrestrial carbonates

USGS Publications Warehouse

Pigati, Jeffrey S.; Rink, W. Jack; Thompson, Jeroen

2014-01-01

Terrestrial carbonates encompass a wide range of materials that potentially could be used for radiocarbon (14C) dating. Biogenic carbonates, including shells and tests of terrestrial and aquatic gastropods, bivalves, ostracodes, and foraminifera, are preserved in a variety of late Quaternary deposits and may be suitable for 14C dating. Primary calcareous deposits (marls, tufa, speleothems) and secondary carbonates (rhizoliths, fracture fill, soil carbonate) may also be targeted for dating when conditions are favorable. This chapter discusses issues that are commonly encountered in 14C dating of terrestrial carbonates, including isotopic disequilibrium and open-system behavior, as well as methods used to determine the reliability of ages derived from these materials. Recent methodological advancements that may improve the accuracy and precision of 14C ages of terrestrial carbonates are also highlighted.
31 CFR 315.35 - Payment (redemption).

Code of Federal Regulations, 2014 CFR

2014-07-01

... and Savings Notes. A Series E bond will be paid at any time after two months from issue date at the... time after six (6) months from issue date. In any case where Series H bonds are surrendered to a..., SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment § 315.35...
Seasonal variations in modern speleothem calcite growth in Central Texas, U.S.A

USGS Publications Warehouse

Banner, J.L.; Guilfoyle, A.; James, E.W.; Stern, L.A.; Musgrove, M.

2007-01-01

Variations in growth rates of speleothem calcite have been hypothesized to reflect changes in a range of paleoenvironmental variables, including atmospheric temperature and precipitation, drip-water composition, and the rate of soil CO2 delivery to the subsurface. To test these hypotheses, we quantified growth rates of modern speleothem calcite on artificial substrates and monitored concurrent environmental conditions in three caves across the Edwards Plateau in central Texas. Within each of two caves, different drip sites exhibit similar annual cycles in calcite growth rates, even though there are large differences between the mean growth rates at the sites. The growth-rate cycles inversely correlate to seasonal changes in regional air temperature outside the caves, with near-zero growth rates during the warmest summer months, and peak growth rates in fall through spring. Drip sites from caves 130 km apart exhibit similar temporal patterns in calcite growth rate, indicating a controlling mechanism on at least this distance. The seasonal variations in calcite growth rate can be accounted for by a primary control by regional temperature effects on ventilation of cave-air CO2 concentrations and/or drip-water CO2 contents. In contrast, site-to-site differences in the magnitude of calcite growth rates within an individual cave appear to be controlled principally by differences in drip rate. A secondary control by drip rate on the growth rate temporal variations is suggested by interannual variations. No calcite growth was observed in the third cave, which has relatively high values of and small seasonal changes in cave-air CO2. These results indicate that growth-rate variations in ancient speleothems may serve as a paleoenvironmental proxy with seasonal resolution. By applying this approach of monitoring the modern system, speleothem growth rate and geochemical proxies for paleoenviromnental change may be evaluated and calibrated. Copyright ?? 2007, SEPM (Society for Sedimentary Geology).
Wet periods in northeastern Brazil over the past 210 kyr linked to distant climate anomalies.

PubMed

Wang, Xianfeng; Auler, Augusto S; Edwards, R Lawrence; Cheng, Hai; Cristalli, Patricia S; Smart, Peter L; Richards, David A; Shen, Chuan-Chou

2004-12-09

The tropics are the main source of the atmosphere's sensible and latent heat, and water vapour, and are therefore important for reconstructions of past climate. But long, accurately dated records of southern tropical palaeoclimate, which would allow the establishment of climatic connections to distant regions, have not been available. Here we present a 210,000-year (210-kyr) record of wet periods in tropical northeastern Brazil--a region that is currently semi-arid. The record is obtained from speleothems and travertine deposits that are accurately dated using the U/Th method. We find wet periods that are synchronous with periods of weak East Asian summer monsoons, cold periods in Greenland, Heinrich events in the North Atlantic and periods of decreased river runoff to the Cariaco basin. We infer that the wet periods may be explained with a southward displacement of the Intertropical Convergence Zone. This widespread synchroneity of climate anomalies suggests a relatively rapid global reorganization of the ocean-atmosphere system. We conclude that the wet periods probably affected rainforest distribution, as plant fossils show that forest expansion occurred during these intermittent wet intervals, and opened a forest corridor between the Amazonian and Atlantic rainforests.
The Last Interglacial Climate Variability in Northern China

NASA Astrophysics Data System (ADS)

Li, X.; Lu, Y.; Sinha, A.; Ma, Z.; Tan, M.; Edwards, R.; Cheng, H.

2013-12-01

Speleothem oxygen isotope (δ18O) records can reconstruct high-resolution and absolutely dated climate history, in particular, the variability of monsoon precipitation that is associated with the changes in atmospheric circulation and, in turn, the δ18O of precipitation. In the East Asian monsoon domain, although speleothem records have been established in southeastern China over the last decade, including several records covering the last interglacial period (MIS 5e), similar records are virtually absent in northern China. This hampers our understanding of the mechanism of the East Asian monsoon changes, because the northern China δ18O record is, as recently shown by modeling work, more sensitive to changes in summer monsoon precipitation than that from southeastern China. Here we provide a high-resolution and absolutely dated speleothem δ18O record between ~129 and 119 ka BP from Kulishu cave, Beijing, northern China. It shows an abrupt onset of MIS 5e at 129.4×0.7 ka BP, similar within dating uncertainty to the Dongge, Hulu, and Sanbao records from southeastern China. However, the end of MIS 5e is rather gradual in comparison to the southern China counterparts. While overall MIS5e monsoon climate appears to be rather stable on orbital timescales, broadly following northern hemisphere summer insolation, millennial/centennial-scale events punctuate the Kulishu record. Spectral analysis reveals a significant quasi-1500 year periodicity, comparable to the Bond cycle, first observed in the North Atlantic during the Holocene, and more recently in interglacial East Asian monsoon cave records. As such, events with a ~1500 year pacing appear to be a persistent characteristic of the East Asian monsoon for good portions of the past two glacial-interglacial periods. Changes in solar output would be one possibility for the trigger; changes in ocean circulation with a ~1500-year time constant would be another. Comparison with Hulu(MSX, Cheng et al., 2006)-Dongge(D3, D4, Kelly et al., 2006)-Sanbao(SB23, SB25, Wang et al., 2008) complex.
Application of the 226Ra– 230Th– 234U and 227Ac– 231Pa– 235U radiochronometers to uranium certified reference materials

DOE PAGES

Rolison, John M.; Treinen, Kerri C.; McHugh, Kelly C.; ...

2017-11-06

Uranium certified reference materials (CRM) issued by New Brunswick Laboratory were subjected to dating using four independent uranium-series radiochronometers. In all cases, there was acceptable agreement between the model ages calculated using the 231Pa– 235U, 230Th– 234U, 227Ac– 235U or 226Ra– 234U radiochronometers and either the certified 230Th– 234U model date (CRM 125-A and CRM U630), or the known purification date (CRM U050 and CRM U100). Finally, the agreement between the four independent radiochronometers establishes these uranium certified reference materials as ideal informal standards for validating dating techniques utilized in nuclear forensic investigations in the absence of standards with certifiedmore » model ages for multiple radiochronometers.« less
Application of the 226Ra– 230Th– 234U and 227Ac– 231Pa– 235U radiochronometers to uranium certified reference materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rolison, John M.; Treinen, Kerri C.; McHugh, Kelly C.

Uranium certified reference materials (CRM) issued by New Brunswick Laboratory were subjected to dating using four independent uranium-series radiochronometers. In all cases, there was acceptable agreement between the model ages calculated using the 231Pa– 235U, 230Th– 234U, 227Ac– 235U or 226Ra– 234U radiochronometers and either the certified 230Th– 234U model date (CRM 125-A and CRM U630), or the known purification date (CRM U050 and CRM U100). Finally, the agreement between the four independent radiochronometers establishes these uranium certified reference materials as ideal informal standards for validating dating techniques utilized in nuclear forensic investigations in the absence of standards with certifiedmore » model ages for multiple radiochronometers.« less

Anatomy of biologically mediated opal speleothems in the World's largest sandstone cave: Cueva Charles Brewer, Chimantá Plateau, Venezuela

NASA Astrophysics Data System (ADS)

Aubrecht, R.; Brewer-Carías, Ch.; Šmída, B.; Audy, M.; Kováčik, Ľ.

2008-01-01

Siliceous speleothems can be formed in sandstone caves. Recently, opal "biospeleothems" have been found in the World's largest cave in Precambrian sandstones on the Chimantá Tepui in Venezuela. The speleothems, although reminiscent of normal stalactites and stalagmites from limestone caves, are in fact large microbialites. More than a dozen forms were distinguished, but they share a common structure and origin. They consist of two main types: 1. fine-laminated columnar stromatolite formed by silicified filamentous microbes (either heterotrophic filamentous bacteria or cyanobacteria) and 2. a porous peloidal stromatolite formed by Nostoc-type cyanobacteria. The first type usually forms the central part and the second type, the outer part, of speleothems. Fungal hyphae, metazoan and plant remains also subordinately contribute to speleothem construction. The speleothems occur out of the reach of flowing water; the main source of silica is the condensed cave moisture which is the main dissolution-reprecipitation agent. Speleothems which originated by encrustation of spider threads are unique.
Meteoric phreatic speleothems and the development of cave stratigraphy: An example from Tounj Cave, Dinarides, Croatia

NASA Astrophysics Data System (ADS)

Babić, Ljubomir; Lacković, Damir; HorvatinČIĆ, Nada

Speleothems occurring in some caves of the carbonate Dinarides line all channel surfaces, and have been deposited from meteoric waters under phreatic conditions. Such phreatic speleothemic deposition modifies common experience (l) that meteoric phreatic conditions cause dissolutional widening of cave voids, and (2) that speleothems imply vadose conditions. The phreatic speleothems described here postdate an early polygenetic evolution of the cave voids, and predate the last, vadose stage. They were likely produced during the late/postglacial warming period, when dissolved carbonate was amply supplied, and when there was much water available for saturation of underground voids. Phreatic speleothems may be used as a tool for time correlation of internal deposits, both within one cave and within a karst region. They indicate an important stage in the history of the ground-water regime of an area. In general, phreatic speleothems help in better understanding of the development of subterranean voids and related karst/palaeokarst.
Correcting speleothem oxygen isotopic variations for growth-rate controlled kinetic fractionation effects

NASA Astrophysics Data System (ADS)

Stoll, Heather; Moreno, Ana; Cacho, Isabel; Mendez Vicence, Ana; Gonzalez Lemos, Saul; Pirla Casasayas, Gemma; Cheng, Hai; Wang, Xianfeng; Edwards, R. Lawrence

2015-04-01

The oxygen isotopic signature may be the most widely used climate indicator in stalagmites, but recent experimental and theoretical studies indicate the potential for kinetic fractionation effects which may be significant, especially in situations where the primary signal from rainfall isotopic composition and cave temperature is limited to a few permil. Here we use a natural set of stalagmites to illustrate the magnitude of such effects and the potential for deconvolving kinetic signals from the primary temperature and rainfall signals. We compare isotopic records from 6 coeval stalagmites covering the interval 140 to 70 ka, from two proximal caves in NW Spain which experienced the same primary variations in temperature and rainfall d18O, but exhibit a large range in growth rates and temporal trends in growth rate. Stalagmites growing at faster rates near 50 microns/year have oxygen isotopic ratios more than 1 permil more negative than coeval stalagmites with very slow (5 micron/year) growth rates. Because growth rate variations also occur over time within any given stalagmite, the measured oxygen isotopic time series for a given stalagmite includes both climatic and kinetic components. Removal of the kinetic component of variation in each stalagmite, based on the dependence of the kinetic component on growth rate, is effective at distilling a common temporal evolution among the oxygen isotopic records of the multiple stalagmites. However, this approach is limited by the quality of the age model. For time periods characterized by very slow growth and long durations between dates, the presence of crypto-hiatus may result in average growth rates which underestimate the instantaneous speleothem deposition rates and which therefore underestimate the magnitude of kinetic effects. We compare the composite corrected oxygen isotopic record with other records of the timing of glacial inception in the North Atlantic realm.
Uranium-Series Ages of Marine Terrace Corals from the Pacific Coast of North America and Implications for Last-Interglacial Sea Level History

USGS Publications Warehouse

Muhs, D.R.; Kennedy, G.L.; Rockwell, T.K.

1994-01-01

Few of the marine terraces along the Pacific coast of North America have been dated using uranium-series techniques. Ten terrace sequences from southern Oregon to southern Baja California Sur have yielded fossil corals in quantities suitable for U-series dating by alpha spectrometry. U-series-dated terraces representing the ???80,000 yr sea-level high stand are identified in five areas (Bandon, Oregon; Point Arena, San Nicolas Island, and Point Loma, California; and Punta Banda, Baja California); terraces representing the ???125,000 yr sea-level high stand are identified in eight areas (Cayucos, San Luis Obispo Bay, San Nicolas Island, San Clemente Island, and Point Loma, California; Punta Bands and Isla Guadalupe, Baja California; and Cabo Pulmo, Baja California Sur). On San Nicolas Island, Point Loma, and Punta Bands, both the ???80,000 and the ???125,000 yr terraces are dated. Terraces that may represent the ???105,000 sea-level high stand are rarely preserved and none has yielded corals for U-series dating. Similarity of coral ages from midlatitude, erosional marine terraces with coral ages from emergent, constructional reefs on tropical coastlines suggests a common forcing mechanism, namely glacioeustatically controlled fluctuations in sea level superimposed on steady tectonic uplift. The low marine terrace dated at ???125,000 yr on Isla Guadalupe, Baja California, presumed to be tectonically stable, supports evidence from other localities for a +6-m sea level at that time. Data from the Pacific Coast and a compilation of data from other coasts indicate that sea levels at ???80,000 and ???105,000 yr may have been closer to present sea level (within a few meters) than previous studies have suggested.
Magnetically Derived Flood Recurrence Rate Estimates from Stalagmites in Southeastern Minnesota

NASA Astrophysics Data System (ADS)

Feinberg, J. M.; Lascu, I.; Andrade Lima, E.; Weiss, B. P.

2012-12-01

The magnetism of speleothems remains an untapped resource of paleoclimatic, hydrogeologic, and geomagnetic information. Similar to other deposits containing magnetic minerals, speleothems chronicle the evolution of local environmental parameters via the concentration, composition and grain size of their magnetic mineral assemblages. Here we report a novel use of scanning SQUID microscopy to calculate flood recurrence rates from an annually laminated ~500 year old stalagmite from Spring Valley Caverns (SVC) in southeastern Minnesota. Mineral and organic detritus adheres to the surface of a speleothem as flood waters recede from a cavern, and are subsequently encapsulated by calcite as drip water conditions are reestablished. Such detritus typically consists of allochthonous grains of quartz, clay, and titanomagnetite with an average grain size of ~10 μm. Larger flood layers occur on polished surfaces as dark bands that delineate stalagmite growth horizons. We use scanning SQUID microscopy (with a nominal sensitivity of 10-16 Am2) to map the presence of these flood layers by measuring the vertical component of the stray magnetic field resulting from a 1 T isothermal remanent magnetization (IRM) imparted perpendicular to a polished surface. A magnetization model of the IRM field was then obtained by inverting the field data measured 210 μm above the sample using an algorithm in the Fourier domain. By integrating the magnetic data parallel to the stalagmite growth axis we produce a time series of IRM peaks, each of which corresponds to a flooding event. We calculate an average flood recurrence rate of 5 per century for the last 500 years. This rate increases to >10 floods per century in the last century, thereby capturing the combined effects of both climate change and agricultural land-use on karst hydrogeology. These results agree with recurrence rate estimates derived from historical records, tree ring studies, and geochemical analyses of speleothems. The presence of flood layers within speleothems may compromise their use as recorders of the geomagnetic field. Empirical examination of stalagmites both with and without flood layers shows that samples containing flood layers generally have NRM and SIRM intensities greater than 10-3 Am-1 and 10-1 Am-1, respectively; an order of magnitude higher than those without. These values provide a convenient, low-tech mechanism for identifying stalagmite samples that are likely to contain flood layers. Thus, the NRMs of stalagmites containing flood layers will be strongly biased towards the field orientation present at the time of flooding, and may not necessarily represent a time averaged field direction for the corresponding duration of speleothem growth. For this reason, we recommend that workers exercise caution when using speleothems for geomagnetic studies that may contain flood layers.
Thermal Properties of the ESR Centres in Speleothem Samples

NASA Astrophysics Data System (ADS)

Ulusoy, Ü.; Anbar, Gül

2007-04-01

The paramagnetic centres used for ESR (Electron Spin Resonance) dating method should be thermally stable which is the main factor limiting the range of this method. In this work, thermal stabilities of the ESR centres in the cave deposites from the Aladaǧlar Massive and Alanya in Turkey has been investigated. The life times of the dating signal were calculated as about 4.0 and 3.7 years for G06 and G08 samples at the 10 °C depositing temperature. The activation energies of the centres are obtained the same, 0.7eV for both samples.
Comparison of a spatio-temporal speleothem-based reconstruction of late Holocene climate variability to the timing of cultural developments

NASA Astrophysics Data System (ADS)

Deininger, Michael; Lippold, Jörg; Abele, Florian; McDermott, Frank

2016-04-01

Speleothems are considered as a valuable continental climate archive. Their δ18O records provide information onto past changes of the atmospheric circulation accompanied by changes in surface air temperature and precipitation. During the last decades European speleothem studies have assembled a European speleothem network (including numerous speleothem δ18O records) that allow now not only to picture past climate variability in time but also in space. In particular the climate variability of the last 4.5 ka was investigated by these studies. This allows the comparison of the speleothem-based reconstructed palaeoclimate with the timings of the rise and fall of ancient civilisations in this period - including the Dark Ages. Here we evaluate a compilation of 10 speleothem δ18O records covering the last 4.5 ka using a Monte Carlo based Principal Component Analysis (MC-PCA) that accounts for uncertainties in individual speleothem age models and for the different and varying temporal resolutions of each speleothem δ18O record. Our MC-PCA approach allows not only the identification of temporally coherent changes in δ18O records, i.e. the common signal in all investigated speleothem δ18O records, but it also facilitates their depiction and evaluation spatially. The speleothem δ18O records are spanning almost the entire European continent ranging from the western Margin of the European continent to Northern Turkey and from Northern Italy to Norway. For the MC-PCA analysis the 4.5 ka are divided into eight 1ka long time windows that overlap the subsequent time window by 500 years to allow a comparison of the spatio-temporal evolution of the common signal. For every single time window we derive a common mode of climate variability of all speleothem δ18O records as well as its spatial extent. This allows us to compare the rise and fall of ancient civilisations, like the Hittite and the Roman Empire, with our reconstructed spatio-temporal record.
Mid-latitude interhemispheric hydrologic seesaw over the past 550,000 years.

PubMed

Jo, Kyoung-nam; Woo, Kyung Sik; Yi, Sangheon; Yang, Dong Yoon; Lim, Hyoun Soo; Wang, Yongjin; Cheng, Hai; Edwards, R Lawrence

2014-04-17

An interhemispheric hydrologic seesaw--in which latitudinal migrations of the Intertropical Convergence Zone (ITCZ) produce simultaneous wetting (increased precipitation) in one hemisphere and drying in the other--has been discovered in some tropical and subtropical regions. For instance, Chinese and Brazilian subtropical speleothem (cave formations such as stalactites and stalagmites) records show opposite trends in time series of oxygen isotopes (a proxy for precipitation variability) at millennial to orbital timescales, suggesting that hydrologic cycles were antiphased in the northerly versus southerly subtropics. This tropical to subtropical hydrologic phenomenon is likely to be an initial and important climatic response to orbital forcing. The impacts of such an interhemispheric hydrologic seesaw on higher-latitude regions and the global climate system, however, are unknown. Here we show that the antiphasing seen in the tropical records is also present in both hemispheres of the mid-latitude western Pacific Ocean. Our results are based on a new 550,000-year record of the growth frequency of speleothems from the Korean peninsula, which we compare to Southern Hemisphere equivalents. The Korean data are discontinuous and derived from 24 separate speleothems, but still allow the identification of periods of peak speleothem growth and, thus, precipitation. The clear hemispheric antiphasing indicates that the sphere of influence of the interhemispheric hydrologic seesaw over the past 550,000 years extended at least to the mid-latitudes, such as northeast Asia, and that orbital-timescale ITCZ shifts can have serious effects on temperate climate systems. Furthermore, our result implies that insolation-driven ITCZ dynamics may provoke water vapour and vegetation feedbacks in northern mid-latitude regions and could have regulated global climate conditions throughout the late Quaternary ice age cycles.
Mid-latitude interhemispheric hydrologic seesaw over the past 550,000 years

NASA Astrophysics Data System (ADS)

Jo, Kyoung-Nam; Woo, Kyung Sik; Yi, Sangheon; Yang, Dong Yoon; Lim, Hyoun Soo; Wang, Yongjin; Cheng, Hai; Edwards, R. Lawrence

2014-04-01

An interhemispheric hydrologic seesaw--in which latitudinal migrations of the Intertropical Convergence Zone (ITCZ) produce simultaneous wetting (increased precipitation) in one hemisphere and drying in the other--has been discovered in some tropical and subtropical regions. For instance, Chinese and Brazilian subtropical speleothem (cave formations such as stalactites and stalagmites) records show opposite trends in time series of oxygen isotopes (a proxy for precipitation variability) at millennial to orbital timescales, suggesting that hydrologic cycles were antiphased in the northerly versus southerly subtropics. This tropical to subtropical hydrologic phenomenon is likely to be an initial and important climatic response to orbital forcing. The impacts of such an interhemispheric hydrologic seesaw on higher-latitude regions and the global climate system, however, are unknown. Here we show that the antiphasing seen in the tropical records is also present in both hemispheres of the mid-latitude western Pacific Ocean. Our results are based on a new 550,000-year record of the growth frequency of speleothems from the Korean peninsula, which we compare to Southern Hemisphere equivalents. The Korean data are discontinuous and derived from 24 separate speleothems, but still allow the identification of periods of peak speleothem growth and, thus, precipitation. The clear hemispheric antiphasing indicates that the sphere of influence of the interhemispheric hydrologic seesaw over the past 550,000 years extended at least to the mid-latitudes, such as northeast Asia, and that orbital-timescale ITCZ shifts can have serious effects on temperate climate systems. Furthermore, our result implies that insolation-driven ITCZ dynamics may provoke water vapour and vegetation feedbacks in northern mid-latitude regions and could have regulated global climate conditions throughout the late Quaternary ice age cycles.
U-series dating of the Late Pleistocene mammalian fauna from Wood Quarry (Steetley), Nottinghamshire, UK

NASA Astrophysics Data System (ADS)

Pike, A. W. G.; Eggins, S.; Grün, R.; Hedges, R. E. M.; Jacobi, R. M.

2005-01-01

We present the U-series dating of bones from Wood Quarry (Steetley Quarry Cave) using the diffusion-adsorption model to account for uranium uptake. The results give a weighted mean date of 66.8 ± 3.0 kyr, placing this assemblage within or just before Marine Oxygen Isotope Stage 4. The fauna is thought to correlate with the Banwell Bone Cave mammal assemblage-zone of the Early Devensian in Britain. Our results support the idea that this assemblage-zone immediately precedes the assemblage represented nearby at Pin Hole in Creswell Crags which is contemporary with the Mid-Devensian and correlates with MIS 3. Our dates, and dates for the Banwell Bone Cave mammal assemblage-zone from Stump Cross Cavern and evidence from other sites may indicate a longevity for this fauna.
The role of skeletal micro-architecture in diagenesis and dating of Acropora palmata

NASA Astrophysics Data System (ADS)

Tomiak, P. J.; Andersen, M. B.; Hendy, E. J.; Potter, E. K.; Johnson, K. G.; Penkman, K. E. H.

2016-06-01

Past variations in global sea-level reflect continental ice volume, a crucial factor for understanding the Earth's climate system. The Caribbean coral Acropora palmata typically forms dense stands in very shallow water and therefore fossil samples mark past sea-level. Uranium-series methods are commonly used to establish a chronology for fossil coral reefs, but are compromised by post mortem diagenetic changes to coral skeleton. Current screening approaches are unable to identify all altered samples, whilst models that attempt to correct for 'open-system' behaviour are not applicable across all diagenetic scenarios. In order to better understand how U-series geochemistry varies spatially with respect to diagenetic textures, we examine these aspects in relation to skeletal micro-structure and intra-crystalline amino acids, comparing an unaltered modern coral with a fossil A. palmata colony containing zones of diagenetic alteration (secondary overgrowth of aragonite, calcite cement and dissolution features). We demonstrate that the process of skeletogenesis in A. palmata causes heterogeneity in porosity, which can account for the observed spatial distribution of diagenetic features; this in turn explains the spatially-systematic trends in U-series geochemistry and consequently, U-series age. We propose a scenario that emphasises the importance of through-flow of meteoric waters, invoking both U-loss and absorption of mobilised U and Th daughter isotopes. We recommend selective sampling of low porosity A. palmata skeleton to obtain the most reliable U-series ages. We demonstrate that intra-crystalline amino acid racemisation (AAR) can be applied as a relative dating tool in Pleistocene A. palmata samples that have suffered heavy dissolution and are therefore unsuitable for U-series analyses. Based on relatively high intra-crystalline concentrations and appropriate racemisation rates, glutamic acid and valine are most suited to dating mid-late Pleistocene A. palmata. Significantly, the best-preserved material in the fossil specimen yields a U-series age of 165 ± 8 ka, recording a paleo sea-level of -35 ± 7 msl during the MIS 6.5 interstadial on Barbados.
Homogenization of long instrumental temperature and precipitation series over the Spanish Northern Coast

NASA Astrophysics Data System (ADS)

Sigro, J.; Brunet, M.; Aguilar, E.; Stoll, H.; Jimenez, M.

2009-04-01

The Spanish-funded research project Rapid Climate Changes in the Iberian Peninsula (IP) Based on Proxy Calibration, Long Term Instrumental Series and High Resolution Analyses of Terrestrial and Marine Records (CALIBRE: ref. CGL2006-13327-C04/CLI) has as main objective to analyse climate dynamics during periods of rapid climate change by means of developing high-resolution paleoclimate proxy records from marine and terrestrial (lakes and caves) deposits over the IP and calibrating them with long-term and high-quality instrumental climate time series. Under CALIBRE, the coordinated project Developing and Enhancing a Climate Instrumental Dataset for Calibrating Climate Proxy Data and Analysing Low-Frequency Climate Variability over the Iberian Peninsula (CLICAL: CGL2006-13327-C04-03/CLI) is devoted to the development of homogenised climate records and sub-regional time series which can be confidently used in the calibration of the lacustrine, marine and speleothem time series generated under CALIBRE. Here we present the procedures followed in order to homogenise a dataset of maximum and minimum temperature and precipitation data on a monthly basis over the Spanish northern coast. The dataset is composed of thirty (twenty) precipitation (temperature) long monthly records. The data are quality controlled following the procedures recommended by Aguilar et al. (2003) and tested for homogeneity and adjusted by following the approach adopted by Brunet et al. (2008). Sub-regional time series of precipitation, maximum and minimum temperatures for the period 1853-2007 have been generated by averaging monthly anomalies and then adding back the base-period mean, according to the method of Jones and Hulme (1996). Also, a method to adjust the variance bias present in regional time series associated over time with varying sample size has been applied (Osborn et al., 1997). The results of this homogenisation exercise and the development of the associated sub-regional time series will be widely discussed. Initial comparisons with rapidly growing speleothems in two different caves indicate that speleothem trace element ratios like Ba/Ca are recording the decrease in littoral precipitation in the last several decades. References Aguilar, E., Auer, I., Brunet, M., Peterson, T. C. and Weringa, J. 2003. Guidelines on Climate Metadata and Homogenization, World Meteorological Organization (WMO)-TD no. 1186 / World Climate Data and Monitoring Program (WCDMP) no. 53, Geneva: 51 pp. Brunet M, Saladié O, Jones P, Sigró J, Aguilar E, Moberg A, Lister D, Walther A, Almarza C. 2008. A case-study/guidance on the development of long-term daily adjusted temperature datasets, WMO-TD-1425/WCDMP-66, Geneva: 43 pp. Jones, P D, and Hulme M, 1996, Calculating regional climatic time series for temperature and precipitation: Methods and illustrations, Int. J. Climatol., 16, 361- 377. Osborn, T. J., Briffa K. R., and Jones P. D., 1997, Adjusting variance for sample-size in tree-ring chronologies and other regional mean time series, Dendrochronologia, 15, 89- 99.
The last Deglaciation in the Mediterranean region: a multi-archives synthesis

NASA Astrophysics Data System (ADS)

Bazin, Lucie; Siani, Giuseppe; Landais, Amaelle; Bassinot, Frank; Genty, Dominique; Govin, Aline; Michel, Elisabeth; Nomade, Sebastien; Waelbroeck, Claire

2016-04-01

Multiple proxies record past climatic changes in different climate archives. These proxies are influenced by different component of the climate system and bring complementary information on past climate variability. The major limitation when combining proxies from different archives comes from the coherency of their chronologies. Indeed, each climate archives possess their own dating methods, not necessarily coherent with each other's. Consequently, when we want to assess the latitudinal changes and mechanisms behind a climate event, we often have to rely on assumptions of synchronisation between the different archives, such as synchronous temperature changes during warming events (Austin and Hibbert 2010). Recently, a dating method originally developed to produce coherent chronologies for ice cores (Datice,Lemieux-Dudon et al., 2010) has been adapted in order to integrate different climate archives (ice cores, sediment cores and speleothems (Lemieux-Dudon et al., 2015, Bazin et al., in prep)). In this presentation we present the validation of this multi-archives dating tool with a first application covering the last Deglaciation in the Mediterranean region. For this experiment, we consider the records from Monticchio, the MD90-917, Tenaghi Philippon and Lake Orhid sediment cores as well as continuous speleothems from Sofular, Soreq and La Mine caves. Using the Datice dating tool, and with the identification of common tephra layers between the cores considered, we are able to produce a multi-archives coherent chronology for this region, independently of any climatic assumption. Using this common chronological framework, we show that the usual climatic synchronisation assumptions are not valid over this region for the last glacial-interglacial transition. Finally, we compare our coherent Mediterranean chronology with Greenland ice core records in order to discuss the sequence of events of the last Deglaciation between these two regions.
A test of uranium-series dating of fossil tooth enamel: results from Tournal Cave, France

USGS Publications Warehouse

Bischoff, J.L.; Rosenbauer, R.J.; Tavoso, A.; de Lumley, Henry

1988-01-01

A series of well preserved mammal bones and horse teeth was analyzed from archaeological levels of Tournal Cave (Magdalenian, Aurignacian, and Mousterain) to test the hypothesis that well-crystallized enamel behaves more as a closed system than does whole bone. The isotopic composition of bones and tooth enamels from this deposit meet criteria for confidence, and gave no reasons to suspect contamination or open-system behavior. Two samples for which 231Pa could be analyzed showed internal concordance with the respective 230Th ages. In spite of the favourable isotopic criteria, however, comparison of the U-series ages of the bones and the tooth enamel with stratigraphic position and 14C control indicated the dates were not meaningful. In general, both bones and tooth enamels gave ages too young, although some were clearly too old. Neither group showed any systematic increase of age with stratigraphic depth. Tooth enamel, therefore, shows no advantage over bone for U-series dating for this site. In Tournal cave both bones and enamel are apparently open to U, which is probably cycling as a consequences of post-depositional groundwater movement. ?? 1988.
Direct dating of human fossils.

PubMed

Grün, Rainer

2006-01-01

The methods that can be used for the direct dating of human remains comprise of radiocarbon, U-series, electron spin resonance (ESR), and amino acid racemization (AAR). This review gives an introduction to these methods in the context of dating human bones and teeth. Recent advances in ultrafiltration techniques have expanded the dating range of radiocarbon. It now seems feasible to reliably date bones up to 55,000 years. New developments in laser ablation mass spectrometry permit the in situ analysis of U-series isotopes, thus providing a rapid and virtually non-destructive dating method back to about 300,000 years. This is of particular importance when used in conjunction with non-destructive ESR analysis. New approaches in AAR analysis may lead to a renaissance of this method. The potential and present limitations of these direct dating techniques are discussed for sites relevant to the reconstruction of modern human evolution, including Florisbad, Border Cave, Tabun, Skhul, Qafzeh, Vindija, Banyoles, and Lake Mungo. (c) 2006 Wiley-Liss, Inc.
Speleothem Mg-isotope time-series data from different climate belts

NASA Astrophysics Data System (ADS)

Riechelmann, S.; Buhl, D.; Richter, D. K.; Schröder-Ritzrau, A.; Riechelmann, D. F. C.; Niedermayr, A.; Vonhof, H. B.; Wassenburg, J.; Immenhauser, A.

2012-04-01

Speleothem Mg-isotope time-series data from different climate belts Sylvia Riechelmann (1), Dieter Buhl(1), Detlev K. Richter (1), Andrea Schröder-Ritzrau (2), Dana F.C. Riechelmann (3), Andrea Niedermayr (1), Hubert B. Vonhof (4) , Jasper Wassenburg (1), Adrian Immenhauser (1) (1) Ruhr-University Bochum, Institute for Geology, Mineralogy and Geophysics, Universitätsstraße 150, D-44801 Bochum, Germany (2) Heidelberg Academy of Sciences, Im Neuenheimer Feld 229, D-69120 Heidelberg, Germany (3) Johannes Gutenberg-University Mainz, Institute of Geography, Johann-Joachim-Becher-Weg 21, D-55128 Mainz, Germany (4) Faculty of Earth and Life Sciences, Vrije Universiteit Amsterdam, De Boelelaan 1085, 1081 HV, Amsterdam, The Netherlands The Magnesium isotope proxy in Earth surface research is still underexplored. Recently, field and laboratory experiments have shed light on the complex suite of processes affecting Mg isotope fractionation in continental weathering systems. Magnesium-isotope fractionation in speleothems depends on a series of factors including biogenic activity and composition of soils, mineralogy of hostrock, changes in silicate versus carbonate weathering ratios, water residence time in the soil and hostrock and disequilibrium factors such as the precipitation rate of calcite in speleothems. Furthermore, the silicate (here mainly Mg-bearing clays) versus carbonate weathering ratio depends on air temperature and rainfall amount, also influencing the soil biogenic activity. It must be emphasized that carbonate weathering is generally dominant, but under increasingly warm and more arid climate conditions, silicate weathering rates increase and release 26Mg-enriched isotopes to the soil water. Furthermore, as shown in laboratory experiments, increasing calcite precipitation rates lead to elevated delta26Mg ratios and vice versa. Here, data from six stalagmite time-series Mg-isotope records (Thermo Fisher Scientific Neptune MC-ICP-MS) are shown. Stalagmites from caves in Morocco, Germany and Peru are presented. The lowest mean Mg-isotope compositions are found in two Pleistocene Moroccan stalagmites (delta26Mg: -4.26 ± 0.07‰ and -4.17 ± 0.15‰). The cyclical shifts in both stalagmites are best explained by periods of increasing and decreasing aridity. In contrast, Holocene Peruvian stalagmites (0 to 14 ka) show a high mean delta26Mg-value of -3.96 ± 0.04‰ and a very low level of variability in time. This is probably due to the equatorial climate lacking significant variations in temperature and/or rainfall amount. Changes in precipitation rate show effects in stalagmites from western Germany and Peru resulting in a small variability exceeding the error of the delta26Mg-values. Stalagmites from Western Germany (BU 4 mean delta26Mg: -4.20 ± 0.10‰; AH-1 mean delta26Mg: -4.01 ± 0.07‰) are, in terms of the factors that control isotope fractionation, complex. This is because factors such as precipitation rate, changes in silicate versus carbonate weathering ratios, air temperature and rainfall amount interfere in a highly complicated manner.
Human Remains from the Pleistocene-Holocene Transition of Southwest China Suggest a Complex Evolutionary History for East Asians

PubMed Central

Curnoe, Darren; Xueping, Ji; Herries, Andy I. R.; Kanning, Bai; Taçon, Paul S. C.; Zhende, Bao; Fink, David; Yunsheng, Zhu; Hellstrom, John; Yun, Luo; Cassis, Gerasimos; Bing, Su; Wroe, Stephen; Shi, Hong; Parr, William C. H.; Shengmin, Huang; Rogers, Natalie

2012-01-01

Background Later Pleistocene human evolution in East Asia remains poorly understood owing to a scarcity of well described, reliably classified and accurately dated fossils. Southwest China has been identified from genetic research as a hotspot of human diversity, containing ancient mtDNA and Y-DNA lineages, and has yielded a number of human remains thought to derive from Pleistocene deposits. We have prepared, reconstructed, described and dated a new partial skull from a consolidated sediment block collected in 1979 from the site of Longlin Cave (Guangxi Province). We also undertook new excavations at Maludong (Yunnan Province) to clarify the stratigraphy and dating of a large sample of mostly undescribed human remains from the site. Methodology/Principal Findings We undertook a detailed comparison of cranial, including a virtual endocast for the Maludong calotte, mandibular and dental remains from these two localities. Both samples probably derive from the same population, exhibiting an unusual mixture of modern human traits, characters probably plesiomorphic for later Homo, and some unusual features. We dated charcoal with AMS radiocarbon dating and speleothem with the Uranium-series technique and the results show both samples to be from the Pleistocene-Holocene transition: ∼14.3-11.5 ka. Conclusions/Significance Our analysis suggests two plausible explanations for the morphology sampled at Longlin Cave and Maludong. First, it may represent a late-surviving archaic population, perhaps paralleling the situation seen in North Africa as indicated by remains from Dar-es-Soltane and Temara, and maybe also in southern China at Zhirendong. Alternatively, East Asia may have been colonised during multiple waves during the Pleistocene, with the Longlin-Maludong morphology possibly reflecting deep population substructure in Africa prior to modern humans dispersing into Eurasia. PMID:22431968
Human remains from the Pleistocene-Holocene transition of southwest China suggest a complex evolutionary history for East Asians.

PubMed

Curnoe, Darren; Xueping, Ji; Herries, Andy I R; Kanning, Bai; Taçon, Paul S C; Zhende, Bao; Fink, David; Yunsheng, Zhu; Hellstrom, John; Yun, Luo; Cassis, Gerasimos; Bing, Su; Wroe, Stephen; Shi, Hong; Parr, William C H; Shengmin, Huang; Rogers, Natalie

2012-01-01

Later Pleistocene human evolution in East Asia remains poorly understood owing to a scarcity of well described, reliably classified and accurately dated fossils. Southwest China has been identified from genetic research as a hotspot of human diversity, containing ancient mtDNA and Y-DNA lineages, and has yielded a number of human remains thought to derive from Pleistocene deposits. We have prepared, reconstructed, described and dated a new partial skull from a consolidated sediment block collected in 1979 from the site of Longlin Cave (Guangxi Province). We also undertook new excavations at Maludong (Yunnan Province) to clarify the stratigraphy and dating of a large sample of mostly undescribed human remains from the site. We undertook a detailed comparison of cranial, including a virtual endocast for the Maludong calotte, mandibular and dental remains from these two localities. Both samples probably derive from the same population, exhibiting an unusual mixture of modern human traits, characters probably plesiomorphic for later Homo, and some unusual features. We dated charcoal with AMS radiocarbon dating and speleothem with the Uranium-series technique and the results show both samples to be from the Pleistocene-Holocene transition: ∼14.3-11.5 ka. Our analysis suggests two plausible explanations for the morphology sampled at Longlin Cave and Maludong. First, it may represent a late-surviving archaic population, perhaps paralleling the situation seen in North Africa as indicated by remains from Dar-es-Soltane and Temara, and maybe also in southern China at Zhirendong. Alternatively, East Asia may have been colonised during multiple waves during the Pleistocene, with the Longlin-Maludong morphology possibly reflecting deep population substructure in Africa prior to modern humans dispersing into Eurasia.
A chronology for late prehistoric Madagascar.

PubMed

Burney, David A; Burney, Lida Pigott; Godfrey, Laurie R; Jungers, William L; Goodman, Steven M; Wright, Henry T; Jull, A J Timothy

2004-01-01

A database has been assembled with 278 age determinations for Madagascar. Materials 14C dated include pretreated sediments and plant macrofossils from cores and excavations throughout the island, and bones, teeth, or eggshells of most of the extinct megafaunal taxa, including the giant lemurs, hippopotami, and ratites. Additional measurements come from uranium-series dates on speleothems and thermoluminescence dating of pottery. Changes documented include late Pleistocene climatic events and, in the late Holocene, the apparently human-caused transformation of the environment. Multiple lines of evidence point to the earliest human presence at ca. 2300 14C yr BP (350 cal yr BC). A decline in megafauna, inferred from a drastic decrease in spores of the coprophilous fungus Sporormiella spp. in sediments at 1720+/-40 14C yr BP (230-410 cal yr AD), is followed by large increases in charcoal particles in sediment cores, beginning in the SW part of the island, and spreading to other coasts and the interior over the next millennium. The record of human occupation is initially sparse, but shows large human populations throughout the island by the beginning of the Second Millennium AD. Dating of the "subfossil" megafauna, including pygmy hippos, elephant birds, giant tortoises, and large lemurs, demonstrates that most if not all the extinct taxa were still present on the island when humans arrived. Many taxa overlapped chronologically with humans for a millennium or more. The extinct lemurs Hadropithecus stenognathus, Pachylemur insignis, Mesopropithecus pithecoides, and Daubentonia robusta, and the elephant birds Aepyornis spp. and Mullerornis spp., were still present near the end of the First Millennium AD. Palaeopropithecus ingens, Megaladapis edwardsi, and Archaeolemur sp. (cf. edwardsi) may have survived until the middle of the Second Millennium A.D. One specimen of Hippopotamus of unknown provenance dates to the period of European colonization.
Speleothems in the desert: Glimpses of the Pleistocene history of the Death Valley Regional Groundwater Flow System, Nevada and California

NASA Astrophysics Data System (ADS)

Spötl, Christoph; Dublyansky, Yuri; Moseley, Gina; Wendt, Kathleen; Edwards, Larry; Scholger, Robert; Woodhead, Jon

2016-04-01

Death Valley in eastern California holds North Americás record for the deepest, hottest and driest place. Despite these unfavourable boundary conditions speleothems are present in this hyperarid depression and the surrounding deserts and provide unique insights into long-term regional climate change and landscape evolution of this tectonically and geomorphologically highly active region. Most of the speleothems are inactive and exposed due to tectonic uplift and erosion. They differ from common speleothems, because the majority formed under phreatic conditions as part of a regional groundwater flow system that is still active today. Data from three sites will be discussed illustrating the spectrum of speleothem deposits and their modes of formation. At Devils Hole, the thermal aquifer and the associated subaqueous and water-table speleothems can be directly accessed and provide a record reaching back about 1 million years. At Travertine Point, close to modern discharge points of this large groundwater flow system, phreatic speleothems form near-vertical veins up to about 2 m wide showing evidence of high flow rates along these fractures, which are connected to fossil spring tufa deposits. Finally, outcrops along Titus Canyon expose several generations of speleothems documenting the progressive lowering of the regional groundwater table. The youngest calcite generation records the transition towards vadose conditions 500-400 ka ago.

Speleothem records decadal to multidecadal hydroclimate variations in southwestern Morocco during the last millennium

NASA Astrophysics Data System (ADS)

Ait Brahim, Yassine; Cheng, Hai; Sifeddine, Abdelfettah; Wassenburg, Jasper A.; Cruz, Francisco W.; Khodri, Myriam; Sha, Lijuan; Pérez-Zanón, Núria; Beraaouz, El Hassane; Apaéstegui, James; Guyot, Jean-Loup; Jochum, Klaus Peter; Bouchaou, Lhoussaine

2017-10-01

This study presents the first well-dated high resolution stable isotope (δ18 O and δ13 C) and trace element (Mg and Sr) speleothem records from southwestern Morocco covering the last 1000 yrs. Our records reveal substantial decadal to multidecadal swings between dry and humid periods, consistent with regional paleorecords with prevailing dry conditions during the Medieval Climate Anomaly (MCA), wetter conditions during the second part of the Little Ice Age (LIA), and a trend towards dry conditions during the current warm period. These coherent regional climate signals suggest common climate controls. Statistical analyses indicate that the climate of southwestern Morocco remained under the combined influence of both the North Atlantic Oscillation (NAO) and the Atlantic Multidecadal Oscillation (AMO) over the last millennium. Interestingly, the generally warmer MCA and colder LIA at longer multidecadal timescales probably influenced the regional climate in North Africa through the influence on Sahara Low which weakened and strengthened the mean moisture inflow from the Atlantic Ocean during the MCA and LIA respectively.
Widespread Lake Highstands in the Southernmost Andean Altiplano during Heinrich Event 1: Implications for the South American Summer Monsoon

NASA Astrophysics Data System (ADS)

Chen, C. Y.; McGee, D.; Quade, J.

2014-12-01

Speleothem-based oxygen isotope records provide strong evidence of anti-phased behavior of the northern and southern hemisphere summer monsoons during Heinrich events, but we lack rigorous constraints on the amount of wetting or drying occurring in monsoon regions. Studies centered on shoreline deposits of closed-basin lakes are well suited for establishing such quantitative controls on water balance changes by providing unequivocal evidence of lake volume variations. Here we present new dating constraints on the highstands of several high-altitude (3800-4350 m) paleolakes in the southern Andean Altiplano, an outlying arid region of the Atacama Desert stretching across the Chilean-Bolivian-Argentinian border east of the Andes (20-25°S). These lakes once occupied the closed basins where only phreatic playas, dry salars, and shallow ponds exist today. Initial U-Th dating of massive shoreline tufas reveals that these deposits are dateable to within ±150 to 300 yrs due to high U concentrations and low initial Th content (as indicated by high 230Th/232Th). Our U-Th and 14C dates show that lake highstands predominantly occur between 18.5 and 14.5 kyrs BP, coinciding with Heinrich Event 1 (HE1) and the expansion of other nearby lakes, such as Lake Titicaca. Because of their (1) location at the modern-day southwestern edge of the summer monsoon, (2) intact shoreline preservation, and (3) precise age control, these lakes may uniquely enable us to reconstruct the evolution of water balance (P-E) changes associated with HE1. Hydrologic modeling constrained by temperature estimates provided by local glacial records is used to provide bounds for past precipitation changes. We also examine North Atlantic cooling as the mechanism for these changes by comparing a compilation of S. American lake level records with various hosing experiments and transient climate simulations at HE1. Our results lend us confidence in expanding our U-Th work to other shoreline tufas in the surrounding region to produce a more detailed, spatiotemporal record of water balance changes in S. America.
Past climate variability between 97 and 7 ka reconstructed from a multi proxy speleothem record from Western Cuba

NASA Astrophysics Data System (ADS)

Winterhalder, Sophie; Scholz, Denis; Mangini, Augusto; Spötl, Christoph; Jochum, Klaus Peter; Pajón, Jesús M.

2016-04-01

The tropical hydrological cycle plays a key role in regulating global climate, mainly through the export of heat and moisture to higher latitudes, and is highly sensitive to climate change, for instance due to changes in the position of the Intertropical Convergence Zone (ITCZ). Previous work on Caribbean stalagmites suggests a strong connection of precipitation variability to North Atlantic (NA) sea surface temperatures on multidecadal to millenial timescales (Fensterer et al., 2012; Fensterer et al., 2013; Winter et al., 2011). Cold phases in the NA potentially lead to a southward shift of the ITCZ and thus drier conditions in Cuba. On orbital timescales, Cuban stalagmites suggest a relation of speleothem δ18O values with the δ18O value of Caribbean surface waters (Fensterer et al., 2013). Here we present an expansion of the Cuban speleothem record covering the whole last glacial period from the end of MIS5c (97 ka BP) until 7 ka with hiatuses between 93-80 ka, 37-35 ka and 13-10 ka. Stalagmite Cuba medio (CM) has been precisely dated with 60 230Th/U-ages, mainly performed by the MC-ICPMS technique. The δ18O and δ13C records are completed by a continuous, high resolution LA-ICPMS trace element profile. These data allow for the first time to establish a multi-proxy climate reconstruction for the North Western Caribbean at decadal to centennial resolution for this period. The long-term variability of the δ18O values probably reflects rainfall amount in Cuba. The response to some Dansgaard/Oeschger and Heinrich stadials confirms the previously observed correlation between Caribbean and NA climate variability. However, this connection is not clearly imprinted throughout the record. Furthermore, trace elements, such as Mg, do not proof without ambiguity drier conditions in Cuba during NA cold events, such as the Heinrich stadials. This suggests that climate variability in Cuba was more complex during the last 100ka, and that the NA was not the only driving factor. Due to the competing influence of the NA, the Gulf of Mexico and the Pacific Ocean, the proposed severe changes in the tropical hydrological cycle during that time (such as variations of the ITCZ, insolation and the thermohaline circulation (THC)) have potentially lead to significant changes in sources and trajectories of precipitation in Western Cuba. Our record, thus, provides an important contribution towards understanding and differentiating these parameters on Caribbean climate during glacial climate changes. References: Fensterer, C., Scholz, D., Hoffmann, D., Spötl, C., Pajón, J.M., Mangini, A., 2012. Cuban stalagmite suggests relationship between Caribbean precipitation and the Atlantic Multidecadal Oscillation during the past 1.3 ka. The Holocene, 0959683612449759. Fensterer, C., Scholz, D., Hoffmann, D.L., Spötl, C., Schröder-Ritzrau, A., Horn, C., Pajón, J.M., Mangini, A., 2013. Millennial-scale climate variability during the last 12.5 ka recorded in a Caribbean speleothem. Earth and Planetary Science Letters 361, 143-151. Winter, A., Miller, T., Kushnir, Y., Sinha, A., Timmermann, A., Jury, M.R., Gallup, C., Cheng, H., Edwards, R.L., 2011. Evidence for 800years of North Atlantic multi-decadal variability from a Puerto Rican speleothem. Earth and Planetary Science Letters 308, 23-28.
Calibrating the Cryogenian

NASA Astrophysics Data System (ADS)

MacDonald, F. A.; Schmitz, M. D.; Crowley, J. L.; Haam, E.; Huybers, P.; Cohen, P. A.; Johnston, D. T.

2009-12-01

The IGCP 512 sub-commission on the Neoproterozoic is currently discussing criteria for the definition of the Cryogenian period. Herein we provide new U/Pb ID-TIMS ages and carbon and oxygen isotope data from Fifteenmile and Mt. Harper Groups in the Yukon Territory that inform the basis for the placement of the basal Cryogenian “golden spike”. Our U/Pb ages are from volcanic tuffs interbedded within glaciogenic, fossiliferous, and carbonate strata. With the current lack of Neoproterozoic index fossils and the paucity of radiogenic age constraints, chemo-stratigraphic correlations are particularly important for tuning the Neoproterozoic timescale. In an effort to move beyond conventional 'wiggle matching', chemostratigraphic correlations are determined using a new statistical method1, which indicates that the resulting chemo-stratigraphic correlations are statistically significant. These results permit us to refine and integrate Neoproterozoic climate, microfossil, and geochemical proxy records both regionally and globally. The newly calibrated microfossil record points to a eukaryotic radiation roughly coincident with the Bitter Springs isotopic stage and a barren interval between the Sturtian and Marinoan glaciations. 1 Haam, E. & Huybers, P., 2009, A test for the presence of covariance between time-uncertain series of data with applications to the Dongge Cave speleothem and atmospheric radiocarbon records, Paleoceanography, in press.
Temperature reconstruction from dripwater hydrochemistry, speleothem fabric and speleothem δ13C: towards an integrated approach in temperate climate caves

NASA Astrophysics Data System (ADS)

Borsato, Andrea; Frisia, Silvia; Johnston, Vanessa; Spötl, Christoph

2017-04-01

Accurate reconstruction of past climate records from speleothem minerals requires a thorough understanding of both environmental and hydrologic conditions underpinning their formation. These conditions likely influenced how speleothems incorporate chemical signals that are used as climate proxies. Thus, a thorough investigation of environmental and hydrologic parameters is a pre-requisite to gain robust palaeoclimate reconstructions from stalagmites. Here, we present a systematic study of soil, dripwater and speleothems in temperate climate caves at different altitudes, which allowed the assessment of how mean annual air temperature in the infiltration area (MATinf) influences vegetation cover, soil pCO2 and, eventually, pCO2 of karst water and cave air. Our study demonstrates that for caves developed in pure carbonate rocks, the soil and aquifer pCO2 are directly related to the MATinf (Borsato et al., 2015). It is well known that soil and aquifer pCO2 control carbonate dissolution and the carbonate-carbonic acid system. By establishing a relationship between dripwater pCO2 and MATinf, we show that dripwater Ca content and calcite saturation state SIcc) are correlated with MATinf when unaffected by Prior Calcite Precipitation. In particular, dripwater saturation (SIcc = 0) is reached at a MATinf of 4.4°C in our study area. This MATinf delineates a ''speleothem limit", above which speleothems composed of sparitic calcite should not form (Borsato et al., 2016). In fact, sparitic calcite speleothems do not form, today, in caves with a MATinf < 4.4°C. This relationship offers the opportunity to estimate past MATinf from fossil sparitic calcite speleothems found in high-altitude caves by comparing the required SIcc for their formation to the present-day dripwater SIcc. Furthermore, soil and aquifer pCO2 control dripwater DIC δ13C as well as calcite δ13C in speleothems that were not significantly influenced by kinetic fractionation. A linear correlation between calcite δ13C and MATinf was obtained for modern sparitic speleothems that formed at isotopic equilibrium (Johnston et al., 2013). The combination of these two approaches (present-day dripwater SIcc and calcite δ13C in sparitic speleothems) can be used to reconstruct the past MATinf for high-altitude caves. References: Borsato et al., (2015). Earth Surf. Proc. Land. 40, 1158-1170. Borsato et al., (2016). Geochim. Cosmochim. Ac. 177, 275-297. Johnston et al., (2013). Clim. Past 9, 99-118.
Th-230 - U-238 series disequilibrium of the Olkaria rhyolites Gregory Rift Valley, Kenya: Residence times

NASA Technical Reports Server (NTRS)

Black, S.; Macdonald, R.; Kelly, M.

1993-01-01

U-series disequilibrium analyses have been conducted on samples from Olkaria rhyolite centers with ages being available for all but one center using both internal and whole rock isochrons. 67 percent of the rhyolites analyzed show U-Th disequilibrium, ranging from 27 percent excess thorium to 36 percent excess uranium. Internal and whole rock isochrons give crystallization/formation ages between 65 ka and 9 ka, in every case these are substantially older than the eruptive dates. The residence times of the rhyolites (U-Th age minus the eruption date) have decreased almost linearly with time, from 45 ka to 7 Ka suggesting a possible increase of activity within the system related to increased basaltic input. The long residence times are mirrored by large Rn-222 fluxes from the centers which cannot be explained by larger U contents.
Climatic and hydrological control on trace element variations in a speleothem from the Chauvet Cave, France

NASA Astrophysics Data System (ADS)

Bourdin, C.; Genty, D.; Douville, E.

2009-04-01

An ICPMS quantitative analysis of Ca, Mg, Ba, Sr, U, Mn, Y and 14 Rare Earth Elements (REE) has been performed on a speleothem from the Chauvet cave (south-east of France). The Chau-stm-6 stalagmite that grew from 33 ky to 11.5 ky before present had been previously dated by U-Th series method and the published d13C and d18O profile is used as a paleoclimatic benchmark. Chau-stm-6 recorded that major element Ca ratios (Mg, Ba, Sr), U and REY (REE + Y) responded to early deglaciation (15 ky). Their concentrations show relative variations of 40% to 75%. Ba and Sr profiles are significantly correlated (r = 0.85) and show a two-step increase during early deglaciation. Mg and U are weakly correlated and display a decreasing trend from 15 ky to 11.5 ky. REY concentrations decrease during early deglaciation (15 ky to 14.5 ky). The clear onset of Younger Dryas as recorded by both d13C and d18O profiles is not well marked by any of these trace elements though the averaged Sr concentration is slightly lower in the more recent part of the profile. Sr and Ba increase is best explained by the tenfold rise of the growth rate rather than changes in water residence time in the karst which would also increase Mg. The incongruent dissolution of dolomite upstream is invalidated by the absence of reported dolomite in the Chauvet karst system. No correlation was found between REY and Mn (an element strongly bound with colloidal and particular phases in water), suggesting that REY were mainly dissolved (and likely to be complexed) in groundwater. Due to the poorly developed soil above the cave, REY are thought to come mainly from the dissolution of the limestone bedrock. Bedrock samples display a rather flat pattern, only slightly depleted in LREE (light REE) and with a weak cerium (Ce) anomaly (0.6 to 1). In comparison Chau-stm-6 patterns show a marked depletion in LREE and a more pronounced Ce anomaly (0.3 to 0.75). This shale-normalized pattern is construed as coming from REY fractionation during mobilization or transport of the elements in seepage water rather than from the mixing of several REY sources. Preferential removal of LREE may come from their stronger affinity with particles and from a weaker carbonate complexation. The different climatic and environmental conditions don't seem to have affected REY fractionation - LREE/HREE (light REE on heavy REE) remained quite constant, although the ratio peaks or fall sharply at the climatic transitions. This could be the result of brief periods of intense leaching of colloids or particles. A weak anticorrelation was found between the Y/REE ratio and Ce anomaly. Moreover glacial conditions correspond to a high Y/REE-low Ce pattern whereas milder climate correspond to the opposite situation. The probable higher concentration of particles during the warmer period could explain both the better transport of REE relative to Y that has a slower particle-reactivity and larger scavenging of all REE that smoothes Ce anomaly. pH and Eh could also control the selective removal of Ce. Again no significant difference between Bolling-Allerod and Younger Dryas samples could be observed on REY patterns. This study is one of the first steps towards the use of REY as paleohydrologic and paleoclimatic proxies in continental environments.
Taphonomic problems in reconstructing sea-level history from the late Quaternary marine terraces of Barbados

USGS Publications Warehouse

Muhs, Daniel; Simmons, Kathleen R.

2017-01-01

Although uranium series (U-series) ages of growth-position fossil corals are important to Quaternary sea-level history, coral clast reworking from storms can yield ages on a terrace dating to more than one high-sea stand, confounding interpretations of sea-level history. On northern Barbados, U-series ages corals from a thick storm deposit are not always younger with successively higher stratigraphic positions, but all date to the last interglacial period (~127 ka to ~112 ka), Marine Isotope Substage (MIS) 5.5. The storm deposit ages are consistent with the ages of growth-position corals found at the base of the section and at landward localities on this terrace. Thus, in this case, analysis of only a few corals would not have led to an error in interpreting sea-level history. In contrast, a notch cut into older Pleistocene limestone below the MIS 5.5 terrace contains corals that date to both MIS 5.5 (~125 ka) and MIS 5.3 (~108 ka). We infer that the notch formed during MIS 5.3 and the MIS 5.5 corals are reworked. Similar multiple ages of corals on terraces have been reported elsewhere on Barbados. Thus, care must be taken in interpreting U-series ages of corals that are reported without consideration of taphonomy.
Stable oxygen and carbon isotope characteristics in speleothems from Southern Africa - how good are they?

NASA Astrophysics Data System (ADS)

Holmgren, K.

2009-04-01

Much remains to be understood about the interaction between the African climate system, its surrounding ocean-atmosphere climate variability and the global climate system. A better understanding of the regional climate evolution is crucial for understanding global climate dynamics and issues surrounding environmental change throughout Africa and a prerequisite for increasing climate forecasting capabilities for the region. As part of developing this understanding, a longer term perspective that reaches beyond the information available from instrumental records is required. Speleothems are frequently abundant in southern Africa. Quite a few records are now available, reporting significant changes in climate and environmental conditions over longer and shorter time scales. Conclusions are mainly based on the stable isotopic composition of the speleothems. The interpretation of the stable isotope data is, however, not always straight-forward, since many processes contribute to the observed signal in the speleothem and these processes may influence the signal differently at different spatial and temporal scales. For example was the Makapansgat speleothem oxygen isotope record, originally interpreted as being generally determined by shifts in atmospheric circulation pattern (Lee-Thorp et al. 2001, Holmgren et al. 2003), recently challenged and re-interpreted by Partin et al. (2008) to reflect annual rainfall amounts. Historically, less attention has been paid to the stable carbon isotope composition in speleothems. Today, an increasing number of studies demonstrate the potential of stable carbon variations as providing additional information on climate and environment. Measured variations can be a function of the amount of C3 versus C4 vegetation, vegetation cover and soil biological activity, bedrock proportion, rainfall amount and the drip rate. Clearly the multitudes of plausible processes behind the isotopic composition of speleothems in southern Africa (as well as elsewhere) are a challenge to firm conclusions. However, the need for more globally well dispersed terrestrial palaeoclimatic records; the strong advantages of speleothems to provide precise ages and the empirical experience of successful solutions in previous speleothem research, encourage us to continue research on speleothems from southern Africa. If the understanding of the forcing mechanisms behind measured variables in speleothems can be increased, then there is a great potential for retrieving good climate records from the sub-continent, since the availability of caves containing speleothems is fairly frequent. Available speleothem research from southern Africa will be summarised and potentials and constraints will be discussed. References: Holmgren, K., Lee-Thorp, J.A., Cooper, G.J., Lundblad, K., Partridge, T.C., Scott, L., Sithaldeen, R., Talma, A.S. and Tyson, P.D. 2003: Persistent Millennial-Scale Climatic Variability over the Past 25 thousand Years in Southern Africa. Quaternary Science Reviews, 22, 2311-2326. Lee-Thorp, J.A., Holmgren, K., S.E. Lauritzen, Linge, H., Moberg, A., Partridge, T.C., Stevenson, C. and Tyson P., 2001: Rapid climate shifts in the southern African interior throughout the mid to late Holocene. Geophysical Research Letters 28, 4507-4510. Partin, J.W., Cobb, K.M. and Banner, J.L. 2008: Climate variability recorded in tropical and sub-tropical speleothems. PAGES news, 16, 3, p. 9-10.
Microbial Diversity and Mineralogical-Mechanical Properties of Calcitic Cave Speleothems in Natural and in Vitro Biomineralization Conditions

PubMed Central

Dhami, Navdeep K.; Mukherjee, Abhijit; Watkin, Elizabeth L. J.

2018-01-01

Natural mineral formations are a window into important processes leading to carbon storage and mineralized carbonate structures formed through abiotic and biotic processes. In the current study, we made an attempt to undertake a comprehensive approach to characterize the mineralogical, mechanical, and microbial properties of different kinds of speleothems from karstic caves; with an aim to understand the bio-geo-chemical processes in speleothem structures and their impact on nanomechanical properties. We also investigated the biomineralization abilities of speleothem surface associated microbial communities in vitro. Mineralogical profiling using techniques such as X-ray powder Diffraction (XRD) and Tescan Integrated Mineral Analyzer (TIMA) demonstrated that calcite was the dominant mineral in the majority of speleothems with Energy Dispersive X-ray Analysis (EDS) indicating a few variations in the elemental components. Differing proportions of polymorphs of calcium carbonate such as aragonite and vaterite were also recorded. Significant variations in trace metal content were recorded through Inductively Coupled Plasma Mass Spectrometer (ICP-MS). Scanning Electron Microscopy (SEM) analysis revealed differences in morphological features of the crystals which varied from triangular prismatic shapes to etched spiky forms. Microbial imprints and associations were seen in a few sections. Analysis of the associated microbial diversity showed significant differences between various speleothems at Phylum level; although Proteobacteria and Actinobacteria were found to be the predominant groups. Genus level microbial associations showed a relationship with the geochemistry, mineralogical composition, and metal content of the speleothems. The assessment of nanomechanical properties measured by Nanoindentation revealed that the speleothems with a dominance of calcite were stronger than the speleothems with mixed calcium carbonate polymorphs and silica content. The in vitro metabolic activity of the microbial communities associated with the surfaces of the speleothems resulted in calcium carbonate crystal precipitation. Firmicutes and Proteobacteria dominated these populations, in contrast to the populations seen in natural systems. The precipitation of calcium carbonate crystals in vitro indicated that microbial metabolic activity may also play an important role in the synthesis and dissociation of biominerals in the natural environment. Our study provides novel evidence of the close relationship between mineralogy, microbial ecology, geochemistry, and nanomechanical properties of natural formations. PMID:29472898
Developing a Toolkit for Model Evaluation Using Speleothem Isotope Data

NASA Astrophysics Data System (ADS)

Comas-Bru, L.; Deininger, M.; Harrison, S.

2017-12-01

Speleothems can provide high-resolution records of changes in both climate and atmospheric composition. These records have the potential to be used to document regional changes in mean climate and climate variability on annual to centennial timescales. They can also be used to refine our understanding of regional changes in climate forcings, such as dust and volcanic aerosols, through time. Many climate models now explicitly include isotopic tracers, and thus the isotopic records from speleothems can be used for model evaluation. Previous attempts to compile speleothem data have not provided a globally-comprehensive synthesis, nor have they provided assessments of measurement, chronological or interpretation uncertainties. SISAL (Speleothem Isotopes Synthesis and Analysis) is a new community-based working groupsponsored by Past Global Changes (PAGES) to synthesise the 500+speleothem isotopic records available globallyand develop a public-accessdatabase, that can be used both to explore past climate changes and in model evaluation. This presentation will showcase preliminary syntheses for the Last Glacial Maximum (21 ka), the mid-Holocene (6 ka) and the Last Millennium (850-1850 CE).
U-series dating of impure carbonates: An isochron technique using total-sample dissolution

USGS Publications Warehouse

Bischoff, J.L.; Fitzpatrick, J.A.

1991-01-01

U-series dating is a well-established technique for age determination of Late Quaternary carbonates. Materials of sufficient purity for nominal dating, however, are not as common as materials with mechanically inseparable aluminosilicate detritus. Detritus contaminates the sample with extraneous Th. We propose that correction for contamination is best accomplished with the isochron technique using total sample dissolution (TSD). Experiments were conducted on artificial mixtures of natural detritus and carbonate and on an impure carbonate of known age. Results show that significant and unpredictable transfer of radionuclides occur from the detritus to the leachate in commonly used selective leaching procedures. The effects of correcting via leachate-residue pairs and isochron plots were assessed. Isochrons using TSD gave best results, followed by isochron plots of leachates only. ?? 1991.
Speleothems in a wave-cut notch, Cayman Brac, British West Indies: The integrated product of subaerial precipitation, dissolution, and microbes

NASA Astrophysics Data System (ADS)

Jones, Brian

2010-12-01

A wave-cut notch that is deeply incised into the vertical cliff faces of Cayman Brac is adorned with stalactites, stalagmites, and columns. The prefix "notch" is applied to each type of speleothem in order to distinguish them from cave speleothems. These speleothemic deposits must have formed since the highstand, ~ 125,000 years ago, which was responsible for the development of the notch. The laminated notch speleothems are formed largely of aragonite (small and large crystals) and calcite (columnar, fiber, and grain-coating mats) along with minor amounts of dolomite, a Mg-Si precipitate (kerolite?), gypsum, and halite. Laminae, typically < 2 mm thick, are commonly bounded by dissolution discontinuities that truncate the older laminae and their formative aragonite and calcite crystals. The patchy tan, grey, to green surface coloration of the notch speleothems reflects the random distribution of the subaerial biofilms, which are formed of a diverse array of filamentous and non-filamentous microbes. The notch speleothems are the integrated product of precipitation and dissolution that was, in some places, microbially mediated. Interpretations based on their mineralogy and internal structures indicate that the composition of the formative waters must have temporally fluctuated with periods of precipitation being interrupted by periods of dissolution. The microbes that formed the subaerial biofilms may have influenced some of these processes. The aragonite, calcite, and kerolite (?) probably formed as evaporation and loss of Ca through precipitation progressively increased the Mg:Ca and the Si/(Ca + Mg) ratios. The dolomite, gypsum, and halite probably formed during early diagenesis during the evaporation of seawater that percolated into the interiors of the notch speleothems.
Dating of Submarine Landslides and Their Tsunami Deposits Using Hawaii as an Example

NASA Astrophysics Data System (ADS)

McMurtry, G. M.; Herrero-Bervera, E.

2003-12-01

There have been several approaches to dating the initiation of submarine landslides and the tsunamis they inevitably produce. In Hawaii, the timing of flank failures of major volcanoes has been estimated by radiometric and paleomagnetic dating of the youngest shield-building flows and dikes, the apex ages of the volcanoes, which can also be constrained by the oldest flows of post-collapse volcanism. More precise age estimates can be obtained by direct dating of the landslide. These approaches include paleomagnetic and U-series stratigraphic dating of the overlying pelagic sediment cover upon and in front of the landslide, the latter method producing minimum ages of last landslide turbidite emplacement, e.g., the ca. 120 ka Alika phase 2 event. Elevated, detached landslide blocks make the best targets for such dating because it is assumed that smaller post-emplacement turbidites will not reach their summits. Catastrophic events such as the 1.0 Ma Wailau giant landslide have, however, been dated by turbidite deposition upon large, elevated blocks of the nearby 1.8 Ma Nuuanu giant landslide. Other direct methods for older events include use of thickness of ferromanganese crusts collected from steep, exposed rock scarps and cosmogenic Be-10 or U-series radiometric determination of the few mm/Ma rate of accumulation. In subtropical areas such as Hawaii, coral clast-bearing, elevated marine deposits on the southeastern islands have been identified as deposits from giant tsunamis. Among the key evidence are the great age and paleo-elevations of the coral clasts found in situ. Since modern coral clasts are relatively young, a few thousand years old or less, older analogs swept from the presently submerged reefs offshore can reliably date tsunamigenic depositional events within the late Quaternary using U-series methods. The age of the tsunami will date within these limits (and the analytical precisions) to the youngest in situ coral clast that was entrained by the waves. U-series dates approximately coeval with the Alika 2 giant landslide suggest a youngest 100 ka tsunami emplacement age from 100-137 ka corals collected on Lanai and Hawaii; likewise, older deposits on Molokai and Lanai suggest a 200 ka tsunami emplacement age from corals that range 200-258 ka in age, but interpretative care must be taken as open-system behavior upon weathering may produce apparently younger dates. Other promising methods for dating these deposits include cosmogenic Cl-36 exposure ages of cements and Cl-36 and He-3 exposure ages of the entrained volcanic rocks. Younger events can be dated by the above methods using C-14 or unsupported Pb-210.
Paleoclimate in continental northwestern Europe during the Eemian and early Weichselian (125-97 ka): insights from a Belgian speleothem

NASA Astrophysics Data System (ADS)

Vansteenberge, Stef; Verheyden, Sophie; Cheng, Hai; Edwards, R. Lawrence; Keppens, Eddy; Claeys, Philippe

2016-07-01

The last interglacial serves as an excellent time interval for studying climate dynamics during past warm periods. Speleothems have been successfully used for reconstructing the paleoclimate of last interglacial continental Europe. However, all previously investigated speleothems are restricted to southern Europe or the Alps, leaving large parts of northwestern Europe undocumented. To better understand regional climate changes over the past, a larger spatial coverage of European last interglacial continental records is essential, and speleothems, because of their ability to obtain excellent chronologies, can provide a major contribution. Here, we present new, high-resolution data from a stalagmite (Han-9) obtained from the Han-sur-Lesse Cave in Belgium. Han-9 formed between 125.3 and ˜ 97 ka, with interruptions of growth occurring at 117.3-112.9 and 106.6-103.6 ka. The speleothem was investigated for its growth, morphology and stable isotope (δ13C and δ18O) composition. The speleothem started growing relatively late within the last interglacial, at 125.3 ka, as other European continental archives suggest that Eemian optimum conditions were already present during that time. It appears that the initiation of Han-9 growth is caused by an increase in moisture availability, linked to wetter conditions around 125.3 ka. The δ13C and δ18O proxies indicate a period of relatively stable conditions after 125.3 ka; however, at 120 ka the speleothem δ18O registered the first signs of regionally changing climate conditions, being a modification of ocean source δ18O linked to an increase in ice volume towards the Marine Isotope Stage (MIS) 5e-5d transition. At 117.5 ka, drastic vegetation changes are recorded by Han-9 δ13C immediately followed by a cessation of speleothem growth at 117.3 ka, suggesting a transition to significantly dryer conditions. The Han-9 record covering the early Weichselian displays larger amplitudes in both isotope proxies and changes in stalagmite morphology, evidencing increased variability compared to the Eemian. Stadials that appear to be analogous to those in Greenland are recognized in Han-9, and the chronology is consistent with other European (speleothem) records. Greenland Stadial 25 is reflected as a cold/dry period within Han-9 stable isotope proxies, and the second interruption in speleothem growth occurs simultaneously with Greenland Stadial 24.
Directly dated MIS 3 lake-level record from Lake Manix, Mojave Desert, California, USA

USGS Publications Warehouse

Reheis, Marith; Miller, David M.; McGeehin, John P.; Redwine, Joanna R.; Oviatt, Charles G.; Bright, Jordon E.

2015-01-01

An outcrop-based lake-level curve, constrained by ~ 70 calibrated 14C ages on Anodonta shells, indicates at least 8 highstands between 45 and 25 cal ka BP within 10 m of the 543-m upper threshold of Lake Manix in the Mojave Desert of southern California. Correlations of Manix highstands with ice, marine, and speleothem records suggest that at least the youngest three highstands coincide with Dansgaard–Oeschger (D–O) stadials and Heinrich events 3 and 4. The lake-level record is consistent with results from speleothem studies in the Southwest that indicate cool wet conditions during D–O stadials. Notably, highstands between 43 and 25 ka apparently occurred at times of generally low levels of pluvial lakes farther north as interpreted from core-based proxies. Mojave lakes may have been supported by tropical moisture sources during oxygen-isotope stage 3, perhaps controlled by southerly deflection of Pacific storm tracks due to weakening of the sea-surface temperature gradient in response to North Atlantic climate perturbations.
Interrogating trees for isotopic archives of atmospheric sulphur deposition and comparison to speleothem records.

PubMed

Wynn, P M; Loader, N J; Fairchild, I J

2014-04-01

Palaeorecords which depict changes in sulphur dynamics form an invaluable resource for recording atmospheric pollution. Tree rings constitute an archive that are ubiquitously available and can be absolutely dated, providing the potential to explore local- to regional-scale trends in sulphur availability. Rapid isotopic analysis by a novel "on-line" method using elemental analyser isotope ratio mass spectrometry (EA-IRMS) is developed, achieving sample precision of <0.4‰ using sample sizes of 40 mg wood powder. Tree cores from NE Italy show trends in pollution, evidenced through increasing concentrations of sulphur towards the youngest growth, and inverse trends in sulphur isotopes differentiating modern growth with light sulphur isotopes (+0.7‰) from pre-industrial growth (+7.5‰) influenced by bedrock composition. Comparison with speleothem records from the same location demonstrate replication, albeit offset in isotopic value due to groundwater storage. Using EA-IRMS, tree ring archives form a valuable resource for understanding local- to regional-scale sulphur pollution dynamics. Copyright © 2013 Elsevier Ltd. All rights reserved.
Evidence for solar cycles in a late Holocene speleothem record from Dongge Cave, China

PubMed Central

Duan, Fucai; Wang, Yongjin; Shen, Chuan-Chou; Wang, Yi; Cheng, Hai; Wu, Chung-Che; Hu, Hsun-Ming; Kong, Xinggong; Liu, Dianbing; Zhao, Kan

2014-01-01

The association between solar activity and Asian monsoon (AM) remains unclear. Here we evaluate the possible connection between them based on a precisely-dated, high-resolution speleothem oxygen isotope record from Dongge Cave, southwest China during the past 4.2 thousand years (ka). Without being adjusted chronologically to the solar signal, our record shows a distinct peak-to-peak correlation with cosmogenic nuclide 14C, total solar irradiance (TSI), and sunspot number (SN) at multi-decadal to centennial timescales. Further cross-wavelet analyses between our calcite δ18O and atmospheric 14C show statistically strong coherence at three typical periodicities of ~80, 200 and 340 years, suggesting important roles of solar activities in modulating AM changes at those timescales. Our result has further indicated a better correlation between our calcite δ18O record and atmospheric 14C than between our record and TSI. This better correlation may imply that the Sun–monsoon connection is dominated most likely by cosmic rays and oceanic circulation (both associated to atmospheric 14C), instead of the direct solar heating (TSI). PMID:24894978
Palaeomagnetic analysis of the Sterkfontein palaeocave deposits: implications for the age of the hominin fossils and stone tool industries.

PubMed

Herries, Andy I R; Shaw, John

2011-05-01

Palaeomagnetic analysis was conducted on speleothems from Members 1-5 at Sterkfontein Cave, South Africa. Palaeomagnetic analysis of siltstone and speleothem from the bulk of Member 4 indicate a reversed magnetic polarity that dates the deposits and its Australopithecus africanus fossils to between 2.58 and ~2.16 Ma. Further confirmation of this age comes in the form of two short normal polarity events correlated to the Rèunion (~2.16 Ma) and Huckleberry Ridge (~2.05 Ma) events in speleothem capping the bulk of Member 4 and coeval with deposition of the final phase of Member 4, including A. africanus fossil Sts 5. At ~2.16-2.05 Ma, Sts 5 is the youngest representative of A. africanus yet discovered. Palaeomagnetic analysis of the Silberberg Grotto deposits identifies a single short geomagnetic field event in flowstone overlying the StW 573 Australopithecus fossil, which is suggested to represent the Rèunion event at ~2.16 Ma. This further supports the uranium lead age estimates of 2.3-2.2 Ma for the StW 573 fossil. Based on a reversed polarity for the deposits below the skeleton it cannot be older than 2.58 Ma. If StW 573 is considered to be a second species of Australopithecus then this indicates that two species of Australopithecus are present at Sterkfontein between 2.6 and 2.0 Ma. All of the Member 5 deposits date to less than 1.8 Ma based on a comparison of palaeomagnetic, faunal, and electron spin resonance age estimates. The StW 53 fossil bearing infill (M5A) is intermediate in age between Member 4 and the rest of Member 5 (B-C) at around 1.78-1.49 Ma. The rest of Member 5 (B-C) containing Oldowan and Acheulian stone tools and Homo and Paranthropus fossils was deposited gradually between 1.40 and 1.07 Ma, much younger than previously suggested. Copyright © 2010 Elsevier Ltd. All rights reserved.
Did Heinrich Events Impact Climate in the Southwest Pacific? - Evidence From New Zealand Speleothems

NASA Astrophysics Data System (ADS)

Whittaker, T. E.; Hendy, C. H.; Hellstrom, J.

2008-12-01

Speleothems, layered calcium-carbonate cave deposits such as stalagmites, stalactites and flowstones, have been shown to offer much potential as paleoclimate archives. We present a new, high-resolution, independently-dated, paleoclimate record from a stalagmite which formed in Hollywood Cave (42.0°S, 171.5°E) on South Island, New Zealand. Over 700 stable oxygen and carbon isotope measurement pairs are supported by a chronology from 18 sequential 230Th dates. The stalagmite grew between 73 and 11 kyr B.P. Growth rates varied from ~1-54 mm/kyr and data resolution yields one sample per 10- 320 years. Weak covariance between δ13C and δ18O in the speleothem calcite suggests that recorded climate signals are primarily driven by mean annual precipitation amount and source. Both stable isotope proxies indicate relatively cold and dry conditions prevailed for much of the period 73-11 kyr B.P. However, abrupt-onset, millennial-scale shifts to wet and cool climate interrupt the dry conditions at 67.7-61, 56-55, 50.5-47.5, 40-39, 30.5-29, 25.5-24.3, 16.1-15, and 12.2-11.8 kyr B.P. Significantly, these eight abrupt climate changes occur synchronously with widely accepted ages for Heinrich events H6-H0 (including H5a). Many of these abrupt events can also be matched to known periods of glacier advance in the Southern Alps, New Zealand, which, arguably, were driven by increased mean annual precipitation and reduced potential for summer melting. In addition, preliminary stable isotope data (> 550 δ13C and δ18O pairs) from two North Island, New Zealand (~38°S), stalagmites will be shown that also displays abrupt shifts from relatively dry to wet climate during the period 60-6 kyr B.P. In combination, these results argue stongly for coeval climate changes in antipodean locations, and therefore provide compelling evidence for globally synchronous climate variability during the last glacial period.

Sea-cave temperature measurements and amino acid geochronology of British Late Pleistocene Sea stands

USGS Publications Warehouse

Hollin, John T.; Smith, Franklin L.; Renouf, John T.; Jenkins, D. Graham

1993-01-01

‘Calibrating’ amino acid ratios with uranium-series dates requires an accurate knowledge of current mean annual temperatures (CMATs) over the region studied. To measure these, test-tube sized ‘diffusion sensors’ were emplaced for 1 year (in 1984, 1985 and 1986), both outside and inside Minchin Hole sea-cave in South Wales and Belle Hougue sea-cave in Jersey, both of which have yielded Oxygen Isotope Substage 5e uranium-series ages on speleothems. Our outside temperatures agreed with meteorological ones. Our inside temperatures were over 1°C lower. To allow for this, a mean of ‘empirical’, ‘linear’ and ‘parabolic’ epimerisation calculations suggests that ratios from molluscs inside the caves should be multiplied by over 1.1 for comparison with outside ratios. This raises Bowen et al.'s ‘Pennard’ stage ratios from inside Minchin (and Bacon) Hole up towards the ‘Unnamed’ stage ratios outside, and suggests that the Unnamed sites are also from Oxygen Isotope Substage 5e, as proposed by Proctor and Smart. The same conclusion is reached more strongly by comparisons with the ratios and temperatures inside Belle Hougue to the south, and at Eemian (assumed 5e) sites in The Netherlands, Germany and Denmark to the east. The Pennard ratios from outside sites may provide further evidence for global sea stands close to the present level later in Oxygen Isotope Stage 5.
Numerical dating of a Late Quaternary spit-shoreline complex at the northern end of Silver Lake playa, Mojave Desert, California: A comparison of the applicability of radiocarbon, luminescence, terrestrial cosmogenic nuclide, electron spin resonance, U-series and amino acid racemization methods

USGS Publications Warehouse

Owen, L.A.; Bright, Jordon; Finkel, R.C.; Jaiswal, M.K.; Kaufman, D.S.; Mahan, S.; Radtke, U.; Schneider, J.S.; Sharp, W.; Singhvi, A.K.; Warren, C.N.

2007-01-01

A Late Quaternary spit-shoreline complex on the northern shore of Pleistocene Lake Mojave of southeastern California, USA was studied with the goal of comparing accelerator mass spectrometry (AMS) radiocarbon, luminescence, electron spin resonance (ESR), terrestrial cosmogenic radionuclide (TCN) surface exposure, amino acid racemization (AAR) and U-series dating methods. The pattern of ages obtained by the different methods illustrates the complexity of processes acting in the lakeshore environment and highlights the utility of a multi-method approach. TCN surface exposure ages (mostly ???20-30 ka) record the initial erosion of shoreline benches, whereas radiocarbon ages on shells (determined in this and previous studies) within the spit, supported by AAR data, record its construction at fluctuating lake levels from ???16 to 10 ka. Luminescence ages on spit sediment (???6-7 ka) and ESR ages on spit shells (???4 ka) are anomalously young relative to radiocarbon ages of shells within the same deposits. The significance of the surprisingly young luminescence ages is not clear. The younger ESR ages could be a consequence of post-mortem enrichment of U in the shells. High concentrations of detrital thorium in tufa coating spit gravels inhibited the use of single-sample U-series dating. Detailed comparisons such as this provide one of the few means of assessing the accuracy of Quaternary dating techniques. More such comparisons are needed. ?? 2007 Elsevier Ltd and INQUA.
The variability of the North Atlantic Oscillation throughout the Holocene

NASA Astrophysics Data System (ADS)

Wassenburg, Jasper; Dietrich, Stephan; Fietzke, Jan; Fohlmeister, Jens; Wei, Wei; Jochum, Klaus Peter; Scholz, Denis; Richter, Detlev; Sabaoui, Abdellah; Lohmann, Gerrit; Andreae, Meinrat; Immenhauser, Adrian

2013-04-01

The North Atlantic Oscillation (NAO) has a major impact on Northern Hemisphere winter climate. Trouet et al. (2009) reconstructed the NAO for the last millennium based on a Moroccan tree ring PDSI (Palmer Drought Severity Index) reconstruction and a Scottish speleothem record. More recently, Olsen et al. (2012) extended the NAO record back to 5.2 ka BP based on a lake record from West Greenland. It is, however, well known that the NAO exhibits non-stationary behavior and the use of a single location for a NAO reconstruction may not capture the complete variability. In addition, the imprint of the NAO on European rainfall patterns in the Early and Mid Holocene on (multi-) centennial timescales is still largely unknown. This is related to difficulties in establishing robust correlations between different proxy records and the fact that proxies may not only reflect winter conditions (i.e., the season when the NAO has the largest influence). Here we present a precisely dated, high resolution speleothem δ18O record from NW Morocco covering the complete Early and Mid Holocene. Carbon and oxygen isotopes were measured at a resolution of 15 years. A multi-proxy approach provides solid evidence that speleothem δ18O values reflect changes in past rainfall intensity. The Moroccan record shows a significant correlation with a speleothem rainfall record from western Germany, which covers the entire Holocene (Fohlmeister et al., 2012). The combination with the extended speleothem record from Scotland, speleothem records from north Italy and the NAO reconstruction from West Greenland (Olsen et al., 2012) allows us to study the variability of the NAO during the entire Holocene. The relation between West German and Northwest Moroccan rainfall has not been stationary, which is evident from the changing signs of correlation. The Early Holocene is characterized by a positive correlation, which changes between 9 and 8 ka BP into a negative correlation. Simulations with the state-of-the-art earth system model COSMOS for the Early and Mid Holocene (Wei and Lohmann, 2012) indicate that this change in the NAO teleconnection is related to large-scale circulation changes due to the ice sheet configuration and deglaciation. References: Fohlmeister, J., Schroder-Ritzrau, A., Scholz, D., Riechelmann, D.F.C., Mudelsee, M., Wackerbarth, A., Gerdes, A., Riechelmann, S., Immenhauser, A., Richter, D.K., Mangini, A., 2012. Bunker Cave stalagmites: an archive for central European Holocene climate variability. Climate of the Past 8, 1751-1764. Olsen, J., Anderson, J.N., Knudsen, M.F., 2012. Variability of the North Atlantic Oscillation over the past 5,200 years. Nature Geoscience DOI:10.1038/NGEO1589, Trouet, V., Esper, J., Graham, N.E., Baker, A., Scourse, J.D., Frank, D.C., 2009. Persistent Positive North Atlantic Oscillation Mode Dominated the Medieval Climate Anomaly. Science 324, 78-80. Wei, W., Lohmann, G., 2012. Simulated Atlantic Multidecadal Oscillation during the Holocene. Journal of Climate 6989-7002.
Was the Eemian warmer than the Holocene? Indications from high- and low-altitude speleothems in the Italian Alps

NASA Astrophysics Data System (ADS)

Johnston, V. E.; Borsato, A.; Frisia, S.; Spoetl, C.; Edwards, R.; Cheng, H.; Hellstrom, J.; Eggins, S. M.

2012-12-01

The Eemian was the most recent period, prior to the Holocene, where conditions were similar to the present. This permits its use for comparison with recent times but without anthropogenic influence. However, the natural similarity between these two periods must be questioned, and therefore, the suitability of using Eemian climate as a reference for modern times. Present-day speleothem growth in the high altitude Cesere Battisti (CB) cave (1880 m a.s.l.) is scarce and limited to only a few, thin calcite crusts and moonmilk deposits, despite ample time for soil development to occur. By contrast, during the Eemian, flowstone deposits and large stalagmites filled parts of the cave. Dating indicates that these deposits commenced growth shortly after deglaciation, with the growth phase corresponding well with the step to negative δ18O values seen at Soreq Cave (Bar-Matthews et al., 2003, Geochim. Cosmochim. Acta, 67, 3181-3199). δ13C values of Eemian speleothems are more negative than present-day precipitates indicating that either the Eemian soil was better developed or there was less in-cave fractionation, both in agreement with favorable speleothem growth conditions and corresponding with greater mass of calcite during the Eemian. The situation is similar at the lower altitude (370 m a.s.l.) Bigonda Cave (BG) that presently hosts stalagmites and stalactites in parts of the cave, but during the Eemian thick flowstones covered large sections of cave passage. High resolution stable isotope and trace element data on two corresponding flowstones from BG cave indicate that flowstone growth commenced rapidly, even during the deglacial phase, with a negative meltwater spike in δ18O and Sr concentrations initially decreasing from the progressive weathering of glacial till in the infiltration area. It is therefore possible that the Eemian climate in the Italian Alps was warmer and more humid than the Holocene, promoting stronger weathering and faster soil development. Alternatively, the glaciation prior to the Eemian interglacial may have been less harsh than the Last Glacial Maximum, thus maintaining some soil in cracks and depressions and allowing the rapid regeneration of biogeochemical cycles. Our five speleothem records from CB and BG caves, spanning the end of Termination II, the Eemian and the demise of the last interglacial, give a precise indication of the timing, European and local climate and the intensity of the Eemian compared to the present-day.
Holocene precipitation changes in the deep tropics recorded by Speleothems (Invited)

NASA Astrophysics Data System (ADS)

Wang, X.; Auler, A. S.; Edwards, R.; Kong, X.; Cheng, H.; Cruz, F. W.; Wang, Y.; Broecker, W. S.

2010-12-01

We have obtained a high-resolution oxygen isotope (δ18O) record of cave calcite from Paraiso Cave, eastern Amazon, which covers most of the Holocene. Its chronology was determined by U-Th ages from three column-shaped stalagmites. Their δ18O profiles replicate among their contemporaneous growth periods. Therefore, the samples were likely precipitated under equilibrium conditions and their oxygen isotopic variations are primarily caused by climate change. We find that the δ18O decreases steadily from ~11.0 to 5.0 thousand years ago, with a growth gap between ~8.4 to 6.3 thousand years ago, and then gradually increases until the present. The large amplitude of the δ18O change (up to 4 per mil) suggests that the variation in δ18O value is dominated by meteoric precipitation change at this equatorial site. In order to investigate the interactions between the Intertropical Convergence Zone (ITCZ), monsoons and El Niño-Southern Oscillation (ENSO) activity during the Holocene, we compare the Paraiso record to speleothem records from other locations in the deep tropics, namely, cave sites from Flores, Borneo and Peru. We find that all these speleothem records are consistent, with a progressive δ18O decrease (rainfall increase) during the early Holocene, probably in response to the southward retreat of the ITCZ from its northernmost location in the early Holocene. This is evident from the strong anti-correlation between the speleothem monsoonal records from China and southern Brazil. However, our record is distinct from the others during the last 4 thousand years, when it switches to a continuous δ18O increase (rainfall decrease) trend, while the others flatten out. We propose that, during the late Holocene, the strengthened South American Summer Monsoon may override the ENSO influence and cause the discrepancy in precipitation between eastern Amazon and other deep tropical cave sites.
Historical droughts in northern Vietnam captured by variability in speleothem δ18O

NASA Astrophysics Data System (ADS)

Hardt, B. F.; McGee, D.; Burns, S. J.; Hieu, N.; Hieu, D. T.

2015-12-01

Speleothem records overlapping with the historical period offer valuable comparisons of documentary evidence with speleothem proxy data. These records provide opportunities to 'ground-truth' the paleo-record, fill in gaps in the historical record, and more confidently extent the paleo-record into deeper time. Here we present isotopic results from a stalagmite collected in northern Vietnam spanning 1200 to 1950 CE, a period with a rich historical record in Vietnam. This sample adds significantly to the relatively sparse paleoclimate record from Southeast Asia. The record includes several multi-decadal positive excursions of ≥1 per mille in calcite δ18O. A preliminary age model, based on six U/Th ages, suggests possible correspondence to noted droughts from the historical record, including the Angkor Droughts, the Ming Dynasty Drought, the Strange Parallels Drought, and the Victorian Holocaust Drought. As modeling studies indicate a strong correlation between rainfall δ18O and both the intensity of summer monsoon winds and summer rainfall over northern Vietnam (e.g., Liu et al., 2014), these excursions are consistent with a decrease in regional precipitation. The Vietnam record shows an overall negative trend during the Little Ice Age. The study site is located well south of the westerly wind belt, ruling out a shift between monsoonal and mid-latitude circulation systems as a likely explanation for the northern Vietnam record. We explore the correspondence between our record and other proxy data from Southeast Asia and suggest possible implications of the differences between Vietnamese and Chinese speleothem records during the Little Ice Age. References cited: Liu Z., Wen X., Brady E. C., Otto-Bliesner B., Yu G., Lu H., Cheng H., Wang Y., Zheng W., Ding Y., Edwards R. L., Cheng J., Liu W. and Yang H. (2014) Chinese cave records and the East Asia Summer Monsoon. Quaternary Science Reviews 83, 115-128.
Seawater 234U/238U recorded by modern and fossil corals

NASA Astrophysics Data System (ADS)

Chutcharavan, Peter M.; Dutton, Andrea; Ellwood, Michael J.

2018-03-01

U-series dating of corals is a crucial tool for generating absolute chronologies of Late Quaternary sea-level change and calibrating the radiocarbon timescale. Unfortunately, coralline aragonite is susceptible to post-depositional alteration of its primary geochemistry. One screening technique used to identify unaltered corals relies on the back-calculation of initial 234U/238U activity (δ234Ui) at the time of coral growth and implicitly assumes that seawater δ234U has remained constant during the Late Quaternary. Here, we test this assumption using the most comprehensive compilation to date of coral U-series measurements. Unlike previous compilations, this study normalizes U-series measurements to the same decay constants and corrects for offsets in interlaboratory calibrations, thus reducing systematic biases between reported δ234U values. Using this approach, we reassess (a) the value of modern seawater δ234U, and (b) the evolution of seawater δ234U over the last deglaciation. Modern coral δ234U values (145.0 ± 1.5‰) agree with previous measurements of seawater and modern corals only once the data have been normalized. Additionally, fossil corals in the surface ocean display δ234Ui values that are ∼5-7‰ lower during the last glacial maximum regardless of site, taxon, or diagenetic setting. We conclude that physical weathering of U-bearing minerals exposed during ice sheet retreat drives the increase in δ234U observed in the oceans, a mechanism that is consistent with the interpretation of the seawater Pb-isotope signal over the same timescale.
Paleo-watertable definition using cave ferromanganese stromatolites and associated cave-wall notches (Sierra de Arnero, Spain)

NASA Astrophysics Data System (ADS)

Rossi, Carlos; Villalaín, Juan J.; Lozano, Rafael P.; Hellstrom, John

2016-05-01

The steeply-dipping-dolostone-hosted caves of the Sierra de Arnero (N Spain) contain low-gradient relict canyons with up to ten mapped levels of ferromanganese stromatolites and associated wall notches over a vertical range of 85 m, the highest occurring 460 m above base level. Despite a plausible speleogenetic contribution by pyrite oxidation, and the irregular cave-wall mesomorphologies suggestive of hypogenic speleogenesis, the Arnero relict caves are dominantly epigenic, as indicated by the conduit pattern and the abundant allogenic sediments. Allogenic input declined over time due to a piracy-related decrease in the drainage area of allogenic streams, explaining the large size of the relict Arnero caves relative to the limited present-day outcrop area of the karstified carbonates. Allogenic-sediment input also explains the observed change from watertable canyons to phreatic conduits in the paleo-downstream direction. Stromatolites and notches arguably formed in cave-stream passages at the watertable. The best-defined paleo-watertables show an overall slope of 1.7°, consistent with the present-day relief of the watertable, with higher-slope segments caused by barriers related to sulfide mineralization. The formation of watertable stromatolites favored wall notching by the combined effect of enhanced acidity by Mn-Fe oxidation and shielding of cave floors against erosion. Abrasive bedload further contributed to notch formation by promoting lateral mechanical erosion and protecting passage floors. The irregular wallrock erosional forms of Arnero caves are related partly to paragenesis and partly to the porous nature of the host dolostones, which favored irregular dissolution near passage walls, generating friable halos. Subsequent mechanical erosion contributed to generate spongework patterns. The dolostone porosity also contributes to explain the paradox that virtually all Arnero caves are developed in dolostone despite being less soluble than adjacent limestone. U-series dating of carbonate speleothems and paleomagnetic data from ferromanganese stromatolites and clastic sediments indicate that the paleo-watertables recorded 320 m above the present-day watertable formed during the Matuyama Chron but prior to 1.5 Ma, implying long-term base-level-lowering rates from 125 to 213 m/Ma. To our knowledge, this is the first attempt of paleomagnetic dating of cave ferromanganese stromatolites. These deposits are excellent geomagnetic recorders and offer a direct way to delineate and date paleo-watertables, especially in caves developed in dolostone.
31 CFR 315.43 - Effective date of request for payment.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING U.S. SAVINGS BONDS, SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment...
A Robust Analysis Method For Δ13c Signal Of Bulk Organic Matter In Speleothems

NASA Astrophysics Data System (ADS)

Bian, F.; Blyth, A. J.; Smith, C.; Baker, A.

2017-12-01

Speleothems preserve organic matter that is derived from both the surface soil and cave environments. This organic matter can be used to understand paleoclimate and paleoenvironments. However, a stable and quick micro-analysis method to measure the δ13C signals from speleothem organic matter separate from the total δ13C remains absent. And speleothem organic geochemistry is still relatively unexplored compared to inorganic geochemistry. In this research, for the organic matter analysis, bulk homogeneous power samples were obtained from one large stalagmite. These were dissolved by phosphoric acid to produce the aqueous solution. Then, the processed solution was degassed through a rotational vacuum concentrator. A liquid chromatograph was coupled to IRMS to control the oxidization and the measurement of analytes. This method is demonstrated to be robust for the analysis of speleothem d13C organic matter analysis under different preparation and instrumental settings, with the low standard deviation ( 0.2‰), and low sample consumption (<25 mg). Considering the complexity of cave environments, this method will be useful in further investigations the δ13C of entrapped organic matter and environmental controls in other climatic and ecological contexts, including the determination of whether vegetation or soil microbial activity is the dominant control on speleothem d13C of organic matter.
Magnetic fingerprint of southern Portuguese speleothems and implications for paleomagnetism and environmental magnetism

NASA Astrophysics Data System (ADS)

Font, Eric; Veiga-Pires, Cristina; Pozo, Manuel; Carvallo, Claire; de Siqueira Neto, António Carlos; Camps, Pierre; Fabre, Sébastien; Mirão, José

2014-11-01

Environmental magnetism of speleothems is still in its early stage of development. Here we report on our investigation of the environmental and paleomagnetic information that has been recorded in speleothems, and what are the factors that control its preservation and reliability. To address these issues, we used a multidisciplinary approach, including rock magnetism, petrography, scanning electron microscopy, stable carbon and oxygen isotope compositions, and major and trace element concentrations. We applied this to a set of samples from different stages of speleothem evolution: present-day dripwater (glass plates), a weathered stalactite, a fresh stalagmite, cave sediments, and terra rossa soils. These samples come from the Penico and Excentricas caves, located in two distinct aquifers of the Algarve region, South Portugal. Our results show that the main magnetic carriers of the speleothems under study are primary (detrital) and consist of maghemite (and magnetite?). Similarities in coercivity and temperature dependence of the studied set of samples suggest that iron oxides are inherited from the terra rossa soils that cap the cave and were transported to the speleothems by dripwater. Hence, they represent a regional environmental signature. Interestingly, a stable and probably detrital remanent magnetization could be isolated in the fresh stalagmite, whereas the weathered stalactite yielded chaotic magnetic directions and very low remanent intensities. We propose that these low intensities can be the result from (i) different remanence acquisition mechanisms between stalagmite and stalactite and/or (ii) iron dissolution by fungal activity. We also suggest that magnetic properties and color and the content in detrital elements in the fresh speleothem inform about environmental processes acting on the interface of rock (soil)-atmosphere, while oxygen isotope composition and alkaline-earth element concentrations inform about calcite-water interaction processes. These results provide a better understanding of how environmental information is recorded in speleothems and what the factors are that control the reliability of the paleomagnetic and paleo-environmental signal.
Glacial to Interglacial Climate and Sea Level Changes Recorded in Submerged Speleothems, Argentarola, Italy

NASA Astrophysics Data System (ADS)

Folz-Donahue, K.; Dutton, A.; Antonioli, F.; Richards, D. A.; Nita, D. C.; Lambeck, K.

2014-12-01

Direct records of Quaternary sea level change can provide insight on the timing and nature of ice sheet retreat during glacial terminations. Such records are generally rare, particularly prior to the last deglaciation, due in part to the difficulty of recovering material from sites that have been submerged by subsequent sea-level rise. A suite of stalagmites recovered from a submerged cave on Argentarola Island in the Tyrrhenian Sea contains hiatuses that were formed when the cave became submerged by seawater. These hiatuses are remarkable due to the presence of calcite tubes secreted by serpulid worms, providing direct evidence of marine inundation. As sea level drops during the following glacial inception, the cave is drained and dense spelean calcite encases the serpulid worm tubes, forming alternating layers of spelean and serpulid calcite. U-Th dates of spelean calcite directly above and below these serpulid layers has previously been used to constrain timing and amplitude of sea level highstands in the Mediterranean. Stable isotope records from the same cave have also been used to indicate increased precipitation across the Mediterranean during Sapropel 6 (175 ka). Here we present U-Th dates and stable isotope records for three Argentarola stalagmites. These specimens were recovered from -22, -18, and -14 m relative to present sea level (rpsl), and complement previously published data for Argentarola stalagmites at -21, -18.5, and -18 m rpsl. The timing and elevation of spelean calcite directly above and below serpulid tube layers provide rare insight on rates of sea-level change between -14 and -22 m during glacial terminations and inceptions prior to the last termination. Stable isotope records from the same stalagmites are used to investigate changes in western Mediterranean climate and potential relationships to Mediterranean sapropel events.
31 CFR 315.35 - Payment (redemption).

Code of Federal Regulations, 2013 CFR

2013-07-01

... and Savings Notes. A Series E bond will be paid at any time after two months from issue date at the... interest is $6.90 per $500. (e) Series H. A Series H bond will be redeemed at face value at any time after..., SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment § 315.35...
31 CFR 315.35 - Payment (redemption).

Code of Federal Regulations, 2010 CFR

2010-07-01

... and Savings Notes. A Series E bond will be paid at any time after two months from issue date at the... interest is $6.90 per $500. (e) Series H. A Series H bond will be redeemed at face value at any time after..., SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment § 315.35...
31 CFR 315.35 - Payment (redemption).

Code of Federal Regulations, 2012 CFR

2012-07-01

... and Savings Notes. A Series E bond will be paid at any time after two months from issue date at the... interest is $6.90 per $500. (e) Series H. A Series H bond will be redeemed at face value at any time after..., SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment § 315.35...
31 CFR 315.35 - Payment (redemption).

Code of Federal Regulations, 2011 CFR

2011-07-01

... and Savings Notes. A Series E bond will be paid at any time after two months from issue date at the... interest is $6.90 per $500. (e) Series H. A Series H bond will be redeemed at face value at any time after..., SERIES A, B, C, D, E, F, G, H, J, AND K, AND U.S. SAVINGS NOTES General Provisions for Payment § 315.35...
Age determination of recent cave deposits using excess Pb-210 - A new technique

NASA Astrophysics Data System (ADS)

Baskaran, M.; Iliffe, Thomas M.

1993-04-01

We show that speleothems contain high concentrations of excess Pb-210 and that this Pb-210 excess can be successfully employed to obtain growth rates of speleothems deposited during the last 100 years. Of two specimens analyzed, a tubular 'soda straw' stalactite yielded a longitudinal growth rate of 1.1 mm/yr, while a normal icicle-shaped stalactite had a lateral growth rate of 0.028 mm/yr. The mass growth rates of these two speleothems (149 and 78 mg/yr respectively) are comparable within a factor of two. Studies of fine-scale variations in the isotopic composition of recent speleothems will help to corroborate the validity of palaeoclimate records obtained using longer lived isotopes and extending back into Pleistocene.
Palaeohydrology of a 3D-maze cave (Hermannshöhle, Lower Austria)

NASA Astrophysics Data System (ADS)

Schober, Andrea; Plan, Lukas

2013-04-01

The 4.4 km-long Hermannshöhle (located in Kirchberg/Wechsel, Lower Austria) is one of the largest caves in the Lower Austroalpine Unit. It is developed in an isolated block of carbonate marble, taking up only 140 x 160 m of ground area and 73 m of elevation difference. The cave is unusual in two respects: (a) its dense network of corridors is arranged in a three-dimensional maze and (b) the most outstanding macro- and micromorphologic features were caused by paragenesis. Speleothems are abundant throughout the cave comprising flowstones, dripstones, helictites, popcorn, calcite rafts, a shield, and moonmilk. Even though most passages are canyon-shaped, the cave shows exclusively phreatic features. Sediment fills are abundant as well, mostly covering the floor of passages to an unknown depth, containing mainly allochthonous material, i.e. schists and gneisses. Besides some vadose dripwater the cave is dry today. A conspicuous feature is the lack of a single water path and instead a maze with multiple flow paths formed. Another interesting feature is that one part of the cave developed below the nearby Ramsbach brook but is still dry. There are small ponors reported from the Ramsbach brook (which were observed during river regulation) indicating an actively draining karst system, which is not yet explored. The aim of this study was to enlighten the palaeohydrology of this cave using morphological and sedimentological observations as well as U/Th dating of speleothems. First results show that the palaeo-environment and the hydrologic setting of the Hermannshöhle were drastically different from today. Undersaturated water sourced from nearby non-karstic gneisses and schists gave rise to well-developed contact karst features. Surprisingly the palaeo flow direction deduced from indicators like scallops and sediment structures was opposite to the flow direction of the present nearby brooks (Rams- and Feistrizbach). Following pulses of clastic sediment input a distinct system of paragenetic canyons developed creating the unique maze character of the cave.
Influence of the Solar Luminosity on the Glaciations, sea Level Changes and Resulting Earthquakes.

NASA Astrophysics Data System (ADS)

Shopov, Y. Y.; Stoykova, D. A.; Tsankov, L. T.; Sanabria, M. E.; Georgieva, D. I.; Ford, D. C.; Georgiev, L. N.

2002-12-01

Glaciations were attributed to variations of the Earth's orbit (Milankovitch cycles). But the best ever dated paleoclimatic record (from Devils Hole, Nevada) demonstrated that the end of the last glacial period (termination II) happened 10 000 years before the one suggested by the orbital variations, i.e. the result appeared before the reason. This fact suggests that there is something wrong in the theory. Calcite speleothems luminescence of organics depends exponentially upon soil temperatures that are determined primarily by the solar radiation. So the microzonality of luminescence of speleothems may be used as an indirect Solar Insolation (radiation) proxy index. We obtained luminescence solar insolation proxy records in speleothems (from Jewel Cave, South Dakota, US and Duhlata cave, Bulgaria). These records exhibit very rapid increasing of the solar insolation at 139 kyrs BP responsible for the termination II (the end of the last glaciation) and demonstrate that solar luminosity variations contribute to Earth's heating almost as much as the orbital variations of the Earth's orbit (Milankovitch cycles). The most powerful cycle of the solar luminosity (11500 yrs) is responsible for almost 1/2 of the variations in solar insolation experimental records. Changes in the speed of Earth's rotation during glacial- interglacial transitions produce fracturing of the Earth's crust and major earthquakes along the fractures. The intensity of this process is as higher as faster is the change of the sea level and as higher is its amplitude. Glaciations and deglaciations drive changes of the sea level. Much higher dimensions of this process should be caused by eruptive increasing of solar luminosity, which may be caused only by collision of large asteroids with the Sun. We demonstrate that such collision may cause "Bible Deluge" type of event.
Earliest hominin occupation of Sulawesi, Indonesia

NASA Astrophysics Data System (ADS)

van den Bergh, Gerrit D.; Li, Bo; Brumm, Adam; Grün, Rainer; Yurnaldi, Dida; Moore, Mark W.; Kurniawan, Iwan; Setiawan, Ruly; Aziz, Fachroel; Roberts, Richard G.; Suyono; Storey, Michael; Setiabudi, Erick; Morwood, Michael J.

2016-01-01

Sulawesi is the largest and oldest island within Wallacea, a vast zone of oceanic islands separating continental Asia from the Pleistocene landmass of Australia and Papua (Sahul). By one million years ago an unknown hominin lineage had colonized Flores immediately to the south, and by about 50 thousand years ago, modern humans (Homo sapiens) had crossed to Sahul. On the basis of position, oceanic currents and biogeographical context, Sulawesi probably played a pivotal part in these dispersals. Uranium-series dating of speleothem deposits associated with rock art in the limestone karst region of Maros in southwest Sulawesi has revealed that humans were living on the island at least 40 thousand years ago (ref. 5). Here we report new excavations at Talepu in the Walanae Basin northeast of Maros, where in situ stone artefacts associated with fossil remains of megafauna (Bubalus sp., Stegodon and Celebochoerus) have been recovered from stratified deposits that accumulated from before 200 thousand years ago until about 100 thousand years ago. Our findings suggest that Sulawesi, like Flores, was host to a long-established population of archaic hominins, the ancestral origins and taxonomic status of which remain elusive.

Indian Summer Monsoon dynamics during Termination II and MIS 5e

NASA Astrophysics Data System (ADS)

Magiera, Matthias; Erhardt, Andrea M.; Hartland, Adam; Kwiecien, Ola; Cheng, Hai; Immenhauser, Adrian; Turchyn, Alexandra; Breitenbach, Sebastian F. M.

2017-04-01

The interpretation of speleothem oxygen isotope ratios (δ18O) as proxy for Indian Summer Monsoon (ISM) dynamics is ambiguous, due to multiple influencing factors. Here we combine δ18O and calcium isotope δ44Ca analyses with elemental data to delineate regional shifts in moisture source, local rainfall amount, and changes in ISM intensity and length during Termination II and MIS 5e. Oxygen isotope ratios reflect a mixed signal of moisture source dynamics and rainfall amount; δ44Ca and Mg/Ca ratios are interpreted as proxies for local effective moisture and prior calcite precipitation (PCP) in the epikarst. The age of stalagmite MAW-3 from Mawmluh Cave, NE India, is constraint by six U-series dates. 108 samples, obtained at 0.4 mm resolution from the 70 mm long speleothem sample, have been analysed for δ18O, δ44Ca and Mg/Ca. Oxygen isotope ratios were measured on a ThermoFisher Scientific MAT 253 at Ruhr-University Bochum. Elemental ratios were measured on a quadrupole ICP-MS at Waikato University. Calcium isotope ratios were analyzed on a ThermoFisher Scientific Triton at University of Cambridge. MAW-3 grew from 136 kyrs BP to 96 kyrs BP, covering Termination II and MIS 5e. Oxygen isotope values are high (ca. +0.91 ‰) during Termination II, reach a minimum during MIS 5e (-3.5 ‰), and rise again to -0.2 ‰ at the end of MIS 5e. Calcium isotope ratios range from -0.32 ‰ to -0.70 ‰ and show a positive correlation (R2= 0.7) with δ18O. High δ18O values during Termination II reflect reduced atmospheric circulation and/or a proximal moisture source (Bay of Bengal), implying lowered ISM intensity. A positive correlation of δ18O with δ44Ca suggests concurrent changes of moisture source location and local rainfall amount, with a proximal moisture source and reduced effective rainfall during periods of weak ISM. Elevated Mg/Ca ratios at such intervals corroborate PCP occurrence, which reflects dry conditions. The beginning of MIS 5e (ca. 132 kyrs BP) is marked by a rapid change to lower δ18O and δ44Ca, suggesting increased local infiltration with increasing ISM rainfall, and a concurrent change to a more distal moisture source. The MAW-3 multi-proxy record compares well with reconstructions from China and northern India, the latter being more depleted, due to Rayleigh fractionation. We suggest that multi-proxy analyses of δ18O, δ44Ca and Mg/Ca greatly help to delineate regional circulation pattern and local effective moisture dynamics in monsoonal settings.
New on-line method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)

NASA Astrophysics Data System (ADS)

Affolter, S.; Fleitmann, D.; Leuenberger, M.

2014-01-01

A new online method to analyse water isotopes of speleothem fluid inclusions using a wavelength scanned cavity ring down spectroscopy (WS-CRDS) instrument is presented. This novel technique allows us to simultaneously measure hydrogen and oxygen isotopes for a released aliquot of water. To do so, we designed a new simple line that allows the on-line water extraction and isotope analysis of speleothem samples. The specificity of the method lies in the fact that fluid inclusions release is made on a standard water background, which mainly improves the δD reliability. To saturate the line, a peristaltic pump continuously injects standard water into the line that is permanently heated to 140 °C and flushed with dry nitrogen gas. This permits instantaneous and complete vaporisation of the standard water resulting in an artificial water background with well-known δD and δ18O values. The speleothem sample is placed into a copper tube, attached to the line and after system stabilisation is crushed using a simple hydraulic device to liberate speleothem fluid inclusions water. The released water is carried by the nitrogen/standard water gas stream directly to a Picarro L1102-i for isotope determination. To test the accuracy and reproducibility of the line and to measure standard water during speleothem measurements a syringe injection unit was added to the line. Peak evaluation is done similarly as in gas chromatography to obtain δD and δ18O isotopic composition of measured water aliquots. Precision is better than 1.5‰ for δD and 0.4‰ for δ18O for water measurement for an extended range (-210 to 0‰ for δD and -27 to 0‰ for δ18O) primarily dependent on the amount of water released from speleothem fluid inclusions and secondarily on the isotopic composition of the sample. The results show that WS-CRDS technology is suitable for speleothem fluid inclusion measurements and gives results that are comparable to Isotope Ratio Mass Spectrometry (IRMS) technique.
New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)

NASA Astrophysics Data System (ADS)

Affolter, S.; Fleitmann, D.; Leuenberger, M.

2014-07-01

A new online method to analyse water isotopes of speleothem fluid inclusions using a wavelength scanned cavity ring down spectroscopy (WS-CRDS) instrument is presented. This novel technique allows us simultaneously to measure hydrogen and oxygen isotopes for a released aliquot of water. To do so, we designed a new simple line that allows the online water extraction and isotope analysis of speleothem samples. The specificity of the method lies in the fact that fluid inclusions release is made on a standard water background, which mainly improves the δ D robustness. To saturate the line, a peristaltic pump continuously injects standard water into the line that is permanently heated to 140 °C and flushed with dry nitrogen gas. This permits instantaneous and complete vaporisation of the standard water, resulting in an artificial water background with well-known δ D and δ18O values. The speleothem sample is placed in a copper tube, attached to the line, and after system stabilisation it is crushed using a simple hydraulic device to liberate speleothem fluid inclusions water. The released water is carried by the nitrogen/standard water gas stream directly to a Picarro L1102-i for isotope determination. To test the accuracy and reproducibility of the line and to measure standard water during speleothem measurements, a syringe injection unit was added to the line. Peak evaluation is done similarly as in gas chromatography to obtain &delta D; and δ18O isotopic compositions of measured water aliquots. Precision is better than 1.5 ‰ for δ D and 0.4 ‰ for δ18O for water measurements for an extended range (-210 to 0 ‰ for δ D and -27 to 0 ‰ for δ18O) primarily dependent on the amount of water released from speleothem fluid inclusions and secondarily on the isotopic composition of the sample. The results show that WS-CRDS technology is suitable for speleothem fluid inclusion measurements and gives results that are comparable to the isotope ratio mass spectrometry (IRMS) technique.
Application of LA-MC-ICP-MS for analysis of Sr isotope ratios in speleothems

NASA Astrophysics Data System (ADS)

Weber, Michael; Scholz, Denis; Wassenburg, Jasper A.; Jochum, Klaus Peter; Breitenbach, Sebastian

2017-04-01

Speleothems are well established climate archives. In order to reconstruct past climate variability, several geochemical proxies, such as δ13C and δ18O as well as trace elements are available. Since several factors influence each individual proxy, robust interpretation is often hampered. This calls for multi-proxy approaches involving additional isotope systems that can help to delineate the role of different sources of water within the epikarst and changes in soil composition. Sr isotope ratios (87Sr/86Sr) have been shown to provide useful information about water residence time and water mixing in the host rock. Furthermore, Sr isotopes are not fractionated during calcite precipitation, implying that the 87Sr/86Sr ratio of the speleothem provides a direct record of the drip water. While most speleothem studies applying Sr isotopes used the TIMS methodology, LA-MC-ICP-MS has been utilized for several other archives, such as otoliths and teeth. This method provides the advantage of faster data acquisition, higher spatial resolution, larger sample throughput and the absence of chemical treatment prior to analysis. Here we present the first LA-MC-ICP-MS Sr isotope data for speleothems. The analytical uncertainty of our LA-MC-ICP-MS Sr data is in a similar range as for other carbonate materials. The results of different ablation techniques (i.e. line scan and spots) are reproducible within error, implying that the application of this technique on speleothems is possible. In addition, several comparative measurements of different carbonate reference materials (i.e. MACS-3, JCt-1, JCp-1), such as tests with standard bracketing and comparison of the 87Sr/86Sr ratios with nanosecond laser ablation system and a state-of-the-art femtosecond laser ablation system, show the robustness of the method. We applied the method to samples from Morocco (Grotte de Piste) and India (Mawmluh Cave). Our results show only very small changes in the 87Sr/86Sr ratios of both speleothems. However, one speleothem from Mawmluh Cave shows a slight increase of 87Sr/86Sr within the error, which is reproducible with line scans and spots.
A Guatemalan Speleothem Record Of Climate Of The Past Millennium

NASA Astrophysics Data System (ADS)

Miller, T.; Winter, A.; Burnett, A.; Haug, G. H.; Kelly, M. J.; Edwards, R.

2012-12-01

A 32-cm active stalagmite collected in 2007 in eastern Guatemala near the Belize border began growing in ~1000 AD, and provides a near continuous record of the past 1000 years. The cave was at 350 m asl, and 23C. 15 U/Th MC ICPMS dates were used to establish the growth model, and almost 1000 δ18O stable isotope samples have been analyzed at sub-annual resolution. The GUXI-1 speleothem grew at a rate of 0.35mm/y from ~1000 to ~1450, when it tilted 25 mm/ 11 degrees from its original axis, possibly related to seismic events of the Motagua River plate margin to the south. Growth continued on the angled upside as a transparent calcite, but with restricted deposition rates from ~1460 to 1650: this reduction was likely due to the time to re-create a more suitable site for deposition, but also to environmental conditions on the surface. After 1660 to the present, GUXI-1 grew steadily along a new axis, much faster at 0.58mm/yr than its pre-tilt rate. The δ18 oxygen isotopes of the deposited calcite are construed as a rainfall proxy, influenced by the amount effect of the tropics. The values range from -4 ‰ to -2.75‰, showing four major regimes over the millennium, and indicating several periods of drought [less-negative δ18O]. Prior to tilting, the Guatemala stalagmite displayed a trend of increasing precipitation following its inception, until it was tilted. Average δ18O was -3.4‰. The record during the ~1450-1660 tilt suggests a period of aridity, but from 1700-1800 precipitation was increasing again as δ18O reached its most negative mean values of ~ -3.6‰, and growth rate was also at its highest. A very abrupt drop in δ18O [0.2 ‰] occurred in 1816 (the year of a major nearby earthquake and a year after the Tambora mega-eruption), and continued as a long-term drying trend to the present, though with a sharp central peak and 2 troughs. This drying trend was also accompanied by a 1/3 decrease in growth rate. A new δ18O mean of -3.1‰ is higher than that during the tilt interval. Other nearby climate records include stalagmites from Belize. The closest (Macal Chasm) speleothem record 30 km to the north reported a coarse δ18O resolution of 50 years, and suggest a long arid period ending about 1150 AD, and another centered about 1500 [mean δ18O -4‰]. The luminescence record [organic acid concentration indicating greater rainfall] of this speleothem supports the presence of the first long arid period, but not that of about 1500; a long modern drying began about 1800. A second stalagmite [Yok Balum] a similar distance to the south also recorded its "most pronounced dry period" between 1000-1100 AD, with elevated rainfall in about half of the subsequent millennium. The final years from 1840 to the present have been drier. A wider Caribbean comparison is possible with speleothem from the northern Yucatan and one as far east as Puerto Rico. Like that of GUXI-1, the period from 1100-1550 appears relatively wetter than preceding centuries, declining to a minimum about 1600, recovering by 1750, then dropping rapidly after 1800. Each of the three also experienced a brief wet interval about 1900. In summary, Central America and the Caribbean appeared to be recovering from dry conditions in the first centuries of the past millennium, encountered a deep rainfall decline in the middle followed by wetter conditions until ~1800, and since then have been experiencing increasing dryness.
Hydro-climate variability and teleconnection patterns during the last millennium in NW Africa, inferred from speleothem records

NASA Astrophysics Data System (ADS)

Ait Brahim, Y.; Cheng, H.; Sifeddine, A.; Wassenburg, J. A.; Khodri, M.; Cruz, F. W., Sr.

2017-12-01

In this study, we present new paleoclimate records from two well dated Moroccan speleothems. Our stalagmites were sampled from Ifoulki cave in the Western High Atlas Mountains in SW Morocco and Chaara cave in the Eastern Middle Atlas Mountains in NE Morocco. The new paleo-records cover the last 1000 years with a high resolution and reveal substantial swings of dry and humid periods with decadal to multidecadal frequencies. The Medieval Climate Anomaly (MCA) is characterized by generally dry conditions, while wetter conditions are recorded during the Little Ice Age (LIA) and a trend towards dry conditions during the 20th century. These observations are consistent with regional climate signals, providing new insights on common climate controls and teleconnection patterns in NW Africa. We emphasize that the hydro-climate conditions in Morocco remained under the influence of the Atlantic Multidecadal Oscillation (AMO) and the North Atlantic Oscillation (NAO). At longer timescales, we hypothesize that the generally warmer MCA and colder LIA influenced the regional climate in NW Africa through interactions with local mechanisms, such as the Sahara Low, which weakened and strengthened the mean moisture inflow from the Atlantic Ocean during the MCA and LIA respectively.
Testing the Limits to Accurate Comminution Dates: A Progress Report

NASA Astrophysics Data System (ADS)

Piccione, G.; Blackburn, T.; Edwards, G. H.

2017-12-01

The ability to resolve the timing of fine particle production holds potential for contributing to several Earth Science sub-disciplines including glaciology, eolian and fluvial geomorphology, soil production, and fault dynamics. A relatively new geochronologic tool, U-series comminution dating, has shown potential to directly date the timing of particle comminution. This system's sensitivity to particle size arises from a physical disequilibrium in the 238U decay chain generated by the ejected loss of intermediate daughter products (e.g. 234U). It is the goal of this ongoing study to develop and test analytical procedures to improve the accuracy of comminution dating. In the geologic settings explored by previous studies, comminution dates integrate both the time of particle transport and time since deposition. To better test the accuracy of comminution dates, our study focuses on settings where silt has experienced little to no transport time, specifically, glacial moraines in the Eastern Sierras and Rock Avalanches in the San Gabriel Mountains, both locations with existing independent geochronologic constraints. Previous studies demonstrate the dependency of U-series comminution date on grain size and shape. Here we show that mineralogy of samples also plays a role, possibly controlled by the uranium content and crystal bond strength. To separate samples by size and mineralogy, we use dry sonic-sieving, density and magnetic separation. Non-detrital materials deposited on the rim of comminuted grains have an isotopic composition that is unrelated to the isotopic evolution since comminution and therefore must be removed through a multi-step leaching procedure. Leaching is complicated by the fact that areas within the comminuted crystal that have experienced physical fractionation are contained within damaged zones and are prone to being leached themselves, which removes areas of interest from the crystal. We present progress made on a sample processing method developed to alleviate complications that affect comminution age measurements. Initial 234U/238U measurements for untreated silt from an 800ka Sierran glacial till are up to 6% above secular equilibrium, while samples processed with this method have measured ratios as low as 3% below secular equilibrium.
Hydroclimate of the Last Glacial Maximum and deglaciation in southern Australia's arid margin interpreted from speleothem records (23-15 ka)

NASA Astrophysics Data System (ADS)

Treble, Pauline C.; Baker, Andy; Ayliffe, Linda K.; Cohen, Timothy J.; Hellstrom, John C.; Gagan, Michael K.; Frisia, Silvia; Drysdale, Russell N.; Griffiths, Alan D.; Borsato, Andrea

2017-06-01

Terrestrial data spanning the Last Glacial Maximum (LGM) and deglaciation from the southern Australian region are sparse and limited to discontinuous sedimentological and geomorphological records with relatively large chronological uncertainties. This dearth of records has hindered a critical assessment of the role of the Southern Hemisphere mid-latitude westerly winds on the region's climate during this time period. In this study, two precisely dated speleothem records for Mairs Cave, Flinders Ranges, are presented, providing for the first time a detailed terrestrial hydroclimatic record for the southern Australian drylands during 23-15 ka. Recharge to Mairs Cave is interpreted from the speleothem record by the activation of growth, physical flood layering, and δ18O and δ13C minima. Periods of lowered recharge are indicated by 18O and 13C enrichment, primarily affecting δ18O, argued to be driven by evaporation of shallow soil/epikarst water in this water-limited environment. A hydrological driver is supported by calcite fabric changes. These include the presence of laminae, visible organic colloids, and occasional dissolution features, related to recharge, as well as the presence of sediment bands representing cave floor flooding. A shift to slower-growing, more compact calcite and an absence of lamination is interpreted to represent reduced recharge. The Mairs Cave record indicates that the Flinders Ranges were relatively wet during the LGM and early deglaciation, particularly over the interval 18.9-15.8 ka. This wetter phase ended abruptly with a shift to drier conditions at 15.8 ka. These findings are in agreement with the geomorphic archives for this region, as well as the timing of events in records from the broader Australasian region. The recharge phases identified in the Mairs Cave record are correlated with, but antiphase to, the position of the westerly winds interpreted from marine core MD03-2611, located 550 km south of Mairs Cave in the Murray Canyons region. The implication is that the mid-latitude westerlies are located further south during the period of enhanced recharge in the Mairs Cave record (18.9-16 ka) and conversely are located further north when greater aridity is interpreted in the speleothem record. A further comparison with speleothem records from the northern Australasian region reveals that the availability of tropical moisture is the most likely explanation driving enhanced recharge, with further amplification of recharge occurring during the early half of Heinrich Stadial 1 (HS1), possibly influenced by a more southerly displaced Intertropical Convergence Zone (ITCZ). A rapid transition to aridity at 15.8 ka is consistent with a retraction of this tropical moisture source.
U-series dating and classification of the Apidima 2 hominin from Mani Peninsula, Southern Greece.

PubMed

Bartsiokas, Antonis; Arsuaga, Juan Luis; Aubert, Maxime; Grün, Rainer

2017-08-01

Laser ablation U-series dating results on a human cranial bone fragment from Apidima, on the western cost of the Mani Peninsula, Southern Greece, indicate a minimum age of 160,000 years. The dated cranial fragment belongs to Apidima 2, which preserves the facial skeleton and a large part of the braincase, lacking the occipital bone. The morphology of the preserved regions of the cranium, and especially that of the facial skeleton, indicates that the fossil belongs to the Neanderthal clade. The dating of the fossil at a minimum age of 160,000 years shows that most of the Neanderthal traits were already present in the MIS 6 and perhaps earlier. This makes Apidima 2 the earliest known fossil with a clear Neanderthal facial morphology. Together with the nearby younger Neanderthal specimens from Lakonis and Kalamakia, the Apidima crania are of crucial importance for the evolution of Neanderthals in the area during the Middle to Late Pleistocene. It can be expected that systematic direct dating of the other human fossils from this area will elucidate our understanding of Neanderthal evolution and demise. Copyright © 2017 Elsevier Ltd. All rights reserved.
A record of more than 500,000 years of large-volume travertine formation in the southwestern United States and links between paleohydrology, paleoclimate, and landscape evolution

NASA Astrophysics Data System (ADS)

Priewisch, A.; Crossey, L. J.; Embid, E.; Karlstrom, K. E.; Polyak, V.; Asmerom, Y.; Ricketts, J. W.

2011-12-01

CO2 springs and associated travertine deposits offer a unique tool to better understand Cenozoic paleohydrology and paleoclimate in the context of geomorphic and neotectonic evolution of the southwestern United States. Travertine accumulations represent places of persistent and significant mantle CO2 degassing in high discharge spring systems that are found along faults and above magmatic systems. They complement speleothem records from the same regions in that they can provide better links to the surface geomorphic and neotectonic systems. New Mexico and Arizona host several exceptionally well-preserved, large-volume travertine deposits that extend from 10 - 60 km2, with thicknesses ranging from 15 to more than 60 m. Precise U-series and stable isotope analyses are underway for large travertine platforms at Mesa del Oro, NM (~27 km2), Riley North and South Mesa, NM (~60 km2), Mesa Aparejo/Belen Quarries, NM (~13 km2), and Springerville, AZ (~30 km2). New ages for the travertine deposits at Mesa del Oro are 56 ka, 253 ka, 361 ka, and more than 500 ka. The travertine deposits at Riley North and South Mesa are older than 500 ka and 207/287 ka, respectively. At Mesa Aparejo, travertine ages are 312 ka and more than 500 ka. U/Th dates from Springerville, AZ show that major travertine accumulations occurred over several time intervals: 36-100 ka, 200-280 ka and 300-350 ka. Stable isotope analyses overlap substantially, exhibiting high δ13C values, +2.0% to +8.3%, and δ18O values that range from -13.5% to -4%. High δ13C values are interpreted to be caused by rapid CO2 degassing while the range of δ18O values is interpreted to represent changing water temperatures and mixing trends of groundwater. U-series data show that travertine deposition at all of these localities overlapped temporally and that major aggradation and high volume deposition was not steady, but occurred episodically at 36-100, 200-280, and 300-380 ka. Times of high accumulation rates are interpreted as times of high groundwater flow and hence as a proxy for regional paleohydrology/paleoclimate controls while the locations of the travertine occurrences (along faults of the Jemez lineament and Rio Grande rift) reflect more local CO2-discharge (tectonic) controls. These travertine occurrences are important indicators of the extent of past natural CO2 leakage that can inform carbon sequestration models both in areas of modern CO2 gas fields (Springerville) and at sites of potential paleo-gas fields. The travertine platforms now occupy positions high in the landscape (inverted topography) and also provide data on the scales and timing of regional landscape denudation.
78 FR 17349 - Section 538 Guaranteed Rural Rental Housing Program 2013 Industry Forums-Open Teleconference and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-21

... Section 538 Guaranteed Rural Rental Housing Program 2013 Industry Forums--Open Teleconference and/or Web... series of teleconference and/or web conference meetings regarding the U.S. Department of Agriculture... teleconference and/or web conference meetings. DATES: The dates and times for the teleconference and/or web...
Uranium series, volcanic rocks

USGS Publications Warehouse

Vazquez, Jorge A.

2014-01-01

Application of U-series dating to volcanic rocks provides unique and valuable information about the absolute timing of crystallization and differentiation of magmas prior to eruption. The 238U–230Th and 230Th-226Ra methods are the most commonly employed for dating the crystallization of mafic to silicic magmas that erupt at volcanoes. Dates derived from the U–Th and Ra–Th methods reflect crystallization because diffusion of these elements at magmatic temperatures is sluggish (Cherniak 2010) and diffusive re-equilibration is insignificant over the timescales (less than or equal to 10^5 years) typically associated with pre-eruptive storage of nearly all magma compositions (Cooper and Reid 2008). Other dating methods based on elements that diffuse rapidly at magmatic temperatures, such as the 40Ar/39Ar and (U–Th)/He methods, yield dates for the cooling of magma at the time of eruption. Disequilibrium of some short-lived daughters of the uranium series such as 210Po may be fractionated by saturation of a volatile phase and can be employed to date magmatic gas loss that is synchronous with volcanic eruption (e.g., Rubin et al. 1994).
A simple-rapid method to separate uranium, thorium, and protactinium for U-series age-dating of materials

PubMed Central

Knight, Andrew W.; Eitrheim, Eric S.; Nelson, Andrew W.; Nelson, Steven; Schultz, Michael K.

2017-01-01

Uranium-series dating techniques require the isolation of radionuclides in high yields and in fractions free of impurities. Within this context, we describe a novel-rapid method for the separation and purification of U, Th, and Pa. The method takes advantage of differences in the chemistry of U, Th, and Pa, utilizing a commercially-available extraction chromatographic resin (TEVA) and standard reagents. The elution behavior of U, Th, and Pa were optimized using liquid scintillation counting techniques and fractional purity was evaluated by alpha-spectrometry. The overall method was further assessed by isotope dilution alpha-spectrometry for the preliminary age determination of an ancient carbonate sample obtained from the Lake Bonneville site in western Utah (United States). Preliminary evaluations of the method produced elemental purity of greater than 99.99% and radiochemical recoveries exceeding 90% for U and Th and 85% for Pa. Excellent purity and yields (76% for U, 96% for Th and 55% for Pa) were also obtained for the analysis of the carbonate samples and the preliminary Pa and Th ages of about 39,000 years before present are consistent with 14C-derived age of the material. PMID:24681438
Assessing Covariation of Holocene Monsoon Intensity and Local Moisture Conditions in Eastern and Southwestern Amazon Basin Using Speleothem δ18O and 87Sr/86Sr Values

NASA Astrophysics Data System (ADS)

Ward, B. M.; Wong, C. I.; Novello, V. F.; Silva, L.; McGee, D.; Cheng, H.; Wang, X.; Edwards, R. L.; Cruz, F. W., Sr.; Santos, R. V.

2017-12-01

δ18O records from South America offer insight into past variability of the South American Monsoon System (SAMS). Potential, however, for understanding local moisture conditions is limited as precipitation δ18O is strongly influenced by regional climate dynamics. Here we create Holocene speleothem 87Sr/86Sr records at 200-yr resolution using TIMS methods in the Center for Isotope Geochemistry at Boston College to complement existing Holocene δ18O speleothem records and investigate local moisture conditions above caves located in the eastern Amazon Basin (PAR - 4°S, 55°W) and southwestern Brazil (JAR - 21°S, 56°W). Speleothem 87Sr/86Sr variability is interpreted to reflect differences in the extent of water-rock interaction due to differences in infiltration rates under wet and dry conditions. Drier conditions promote longer residence time, enhanced water-rock interaction, and greater evolution of dripwater 87Sr/86Sr values from an initial isotopic signature acquired from the soil to the signature of the cave host rock. PAR speleothem 87Sr/86Sr values range from 0.71024 to 0.71067 and are bracketed by soil (0.71710 to 0.70956) and bedrock (0.70852 to 0.70899) values. JAR speleothem 87Sr/86Sr values range from 0.71216 to 0.71539 and are greater than bedrock values (0.70825 to 0.71219), although some speleothem values exceed the single analysis conducted of the soil isotopic composition (0.71473). JAR speleothem 87Sr/86Sr values increase from the early to mid Holocene, consistent with increase in local moisture availability associated with intensification of the SAMS suggested by decreasing δ18O values in many records from the region. Speleothem 87Sr/86Sr values at JAR decrease from the mid to late Holocene, consistent with an increase in δ18O values at PAR that suggest a decline in monsoon intensity. 87Sr/86Sr variability at JAR, however, is positively correlated with the δ18O record. Preliminary 87Sr/86Sr results from PAR are only broadly consistent with the JAR 87Sr/86Sr record and exhibit variability that is not obviously consistent with other records in the region. On-going research investigates the conceptual model of Sr-isotopes as a local moisture proxy and the nature of coupling between local and regional Holocene hydroclimate at these sites and additional sites in central and southeast Brazil.
Three centuries of heavy metal pollution in Paris (France) recorded by urban speleothems.

PubMed

Pons-Branchu, Edwige; Ayrault, Sophie; Roy-Barman, Matthieu; Bordier, Louise; Borst, Wolfgang; Branchu, Philippe; Douville, Eric; Dumont, Emmanuel

2015-06-15

The first record of urban speleothems used to reconstruct the history of heavy metal pollution of shallow groundwaters is presented. Two speleothems grew during the last 300 years in an underground aqueduct in the north-eastern part of Paris. They display high Pb, Mn V, Cu, Cd and Al concentrations since 1900 due to the urbanization of the site which triggered anthropogenic contamination of the water feeding the speleothems. Surprisingly, these heavy metal concentrations are also high in the oldest part. This early pollution could come from the use of Parisian waste as fertilizers in the orchards and vineyards cultivated above the aqueduct before urbanization. Lead isotopes were measured in these carbonates as well as in lead artifacts from the 17th-18th centuries ((206)Pb/(207)Pb=1.180+/-0.003). The mean (206)Pb/(207)Pb ratio, for one of the speleothems is 1.181+/-0.003 unvarying with time. These lead signatures are close to those of coal and old lead from northern European mines, lower than the natural background signature. It confirms that the high metal concentrations found come from anthropogenic pollution. Conversely, the lead isotopic composition of the second speleothem presents two temporal trends: for the oldest levels, the mean value (1.183+/-0.003) is similar to the first speleothem. For the youngest part, a lower value (1.172+/-0.005) is recorded, evidencing the contribution of a new lead source at the beginning of the industrial revolution. Pb isotopes were also measured in recent samples from a nearby superficial site. The first sample is a recent (AD 1975+/-15 years) deposit ((206)Pb/(207)Pb=1.148+/-0.003), and the second, a thin subactual layer ((206)Pb/(207)Pb=1.181+/-0.002). These data are compatible with the adding of anthropogenic sources (leaded gasoline and industrial lead from Rio Tinto ore). Copyright © 2015 Elsevier B.V. All rights reserved.
Relatively Recent Volcanism on Oahu, Hawaii: New U-series and Paleomagnetic Age Constraints on the Hanauma Bay Eruption

NASA Astrophysics Data System (ADS)

Rubin, K. H.; Jurado-Chichay, Z.; Urrutia-Fucugauchi, J.

2002-12-01

The Koko Rift Zone (KRZ), eastern Oahu, is generally regarded as among the youngest volcanic features on the island. Previous workers have suggested that the 9 or 10 vents of this rift erupted near-simultaneously. However, K-Ar data in the literature (32-39 ka vs 320 ka) provide only general guidance on the youthfulness of these eruptions. We present new age constraints on KRZ volcanism using deposits of the phreatomagmatic eruption that produced Hanauma Bay (a popular snorkeling spot) and spatially associated lava flows. Numerous continuous basaltic ash units within the walls of Hanauma crater contain lithic fragments of well-preserved coral reef, beach rock, and marine mollusks, indicating that the eruption occurred in a near shore environment. 238U-234U-230Th dating of coral clasts in the deposit demonstrates that the eruption breached reef of MIS stage 7 age (200 +/- 30 ka), thereby ruling out the K-Ar age of 320 ka. U-series nuclides in "normal" MIS 7 coral lithics are indistinguishable from those in the island encircling Waianae Reef of the same age. However, U-series components in some originally aragonitic coral clasts were offset during the eruption when the rims recrystallized to calcite. 87Sr/86Sr, 234U/238U and Sr and U concentration indicate chemical mixing with host basaltic ash during this event, from which potential ages of the eruption can be constructed using isochron methods. More modeling of the data remains to be done but our preliminary estimate places the eruption at less than 100 ka. This result is consistent with new data on paleointensity and paleomagnetic secular variation within the lava flows exposed in or around the crater. This U-series dating approach should prove useful for eruptions in other locales where carbonate bioclast lithics are present in the deposits.
Dating the Laschamp Excursion: Why Speleothems are Valuable Tools for Constraining the Timing and Duration of Short-Lived Geomagnetic Events

NASA Astrophysics Data System (ADS)

Lascu, I.; Feinberg, J. M.; Dorale, J. A.; Cheng, H.; Edwards, R. L.

2015-12-01

Short-lived geomagnetic events are reflections of geodynamo behavior at small length scales. A rigorous documentation of the anatomy, timing, duration, and frequency of centennial-to-millennial scale geomagnetic events can be invaluable for theoretical and numerical geodynamo models, and for the understanding the finer dynamics of the Earth's core. A critical ingredient for characterizing such geomagnetic instabilities are tightly constrained age models that enable high-resolution magnetostratigraphies. Here we focus on a North American speleothem geomagnetic record of the Laschamp excursion, which was the first geomagnetic excursion recognized and described in the paleomagnetic record, and remains the most studied event of its kind. The geological significance of the Laschamp lies chiefly in the fact that it constitutes a global time-synchronous geochronological marker. The Laschamp excursion occurred around the time of the demise of Homo neanderthalensis, in conjunction with high-amplitude, rapid climatic oscillations leading into the Last Glacial Maximum, and precedes a major supervolcano eruption in the Mediterranean. Thus, the precise determination of the timing and duration of the Laschamp would help in elucidating major scientific questions situated at the intersection of geology, paleoclimatology, and anthropology. Here we present a geomagnetic record from a stalagmite collected in Crevice Cave, Missouri, which we have dated using a combination of high-precision 230Th ages and annual layer counting using confocal microscopy. We have found a maximum duration for the Laschamp that spans the interval 42,250-39,700 years BP, and an age of 41,100 ± 350 years BP for the height of the excursion. During this period relative paleointensity decreased by an order of magnitude and the virtual geomagnetic pole was located at southerly latitudes. Our chronology provides the first robust bracketing for the Laschamp excursion, and improves on previous age determinations based on 40Ar/39Ar dating of lava flows, and orbitally-tuned sedimentary and ice-core records.
Evaporative cooling of speleothem drip water

PubMed Central

Cuthbert, M. O.; Rau, G. C.; Andersen, M. S.; Roshan, H.; Rutlidge, H.; Marjo, C. E.; Markowska, M.; Jex, C. N.; Graham, P. W.; Mariethoz, G.; Acworth, R. I.; Baker, A.

2014-01-01

This study describes the first use of concurrent high-precision temperature and drip rate monitoring to explore what controls the temperature of speleothem forming drip water. Two contrasting sites, one with fast transient and one with slow constant dripping, in a temperate semi-arid location (Wellington, NSW, Australia), exhibit drip water temperatures which deviate significantly from the cave air temperature. We confirm the hypothesis that evaporative cooling is the dominant, but so far unattributed, control causing significant disequilibrium between drip water and host rock/air temperatures. The amount of cooling is dependent on the drip rate, relative humidity and ventilation. Our results have implications for the interpretation of temperature-sensitive, speleothem climate proxies such as δ18O, cave microecology and the use of heat as a tracer in karst. Understanding the processes controlling the temperature of speleothem-forming cave drip waters is vital for assessing the reliability of such deposits as archives of climate change. PMID:24895139
Evidence of a prolonged drought ca. 4200 yr BP correlated with prehistoric settlement abandonment from the Gueldaman GLD1 Cave, N-Algeria

NASA Astrophysics Data System (ADS)

Ruan, J.; Kherbouche, F.; Genty, D.; Blamart, D.; Cheng, H.; Dewilde, F.; Hachi, S.; Edwards, L. R.; Régnier, E.; Michelot, J.-L.

2015-07-01

Middle Holocene cultures have been widely studied round the E-Mediterranean basin in the last 30 years and past cultural activities have been commonly linked with regional climate changes. However, in many cases such linkage is equivocal, in part due to existing climatic evidence that has been derived from areas outside the distribution of ancient settlements, leading to uncertainty from complex spatial heterogeneity in both climate and demography. A few high-resolution well-dated paleoclimate records were recently established using speleothems in the Central and E-Mediterranean basin, however, the scarcity of such records in the western part of the Mediterranean prevents us from correlating past climate evolutions across the basin and deciphering climate-culture relation at fine time scales. Here we report the first decadal-resolved Mid-Holocene climate proxy records from the W-Mediterranean basin based on the stable carbon and oxygen isotopes analyses of two U/Th dated stalagmites from the Gueldaman GLD1 Cave in N-Algeria. Comparison of our records with those from Italy and Israel reveals synchronous (multi) centennial dry phases centered at ca. 5600, ca. 5200 and ca. 4200 yr BP across the Mediterranean basin. New calibrated radiocarbon dating constrains reasonably well the age of rich anthropogenic deposits (e.g., faunal remains, pottery, charcoal) excavated inside the cave, which allows the comparison between in situ evidence of human occupation and of climate change. This approach shows that the timing of a prolonged drought at ca. 4400-3800 yr BP blankets the onset of cave abandonment shortly after ca. 4403 cal yr BP, supporting the hypothesis that a climate anomaly may have played a role in this cultural disruption.
Evidence of a prolonged drought ca. 4200 yr BP correlated with prehistoric settlement abandonment from the Gueldaman GLD1 Cave, Northern Algeria

NASA Astrophysics Data System (ADS)

Ruan, J.; Kherbouche, F.; Genty, D.; Blamart, D.; Cheng, H.; Dewilde, F.; Hachi, S.; Edwards, R. L.; Régnier, E.; Michelot, J.-L.

2016-01-01

Middle Holocene cultures have been widely studied around the Eastern-Mediterranean basin in the last 30 years and past cultural activities have been commonly linked with regional climate changes. However, in many cases such linkage is equivocal, in part due to existing climatic evidence that has been derived from areas outside the distribution of ancient settlements, leading to uncertainty from complex spatial heterogeneity in both climate and demography. A few high-resolution well-dated paleoclimate records were recently established using speleothems in the Central and Eastern-Mediterranean basin, however, the scarcity of such records in the western part of the Mediterranean prevents us from correlating past climate evolutions across the basin and deciphering climate-culture relation at fine timescales. Here we report the first decadal-resolved Mid-Holocene climate proxy records from the Western-Mediterranean basin based on the stable carbon and oxygen isotopes analyses of two U/Th dated stalagmites from the Gueldaman GLD1 Cave in Northern Algeria. Comparison of our records with those from Italy and Israel reveals synchronous (multi) centennial dry phases centered at ca. 5600, ca. 5200 and ca. 4200 yr BP across the Mediterranean basin. New calibrated radiocarbon dating constrains reasonably well the age of rich anthropogenic deposits (e.g., faunal remains, pottery, charcoal) excavated inside the cave, which allows the comparison between in situ evidence of human occupation and of climate change. This approach shows that the timing of a prolonged drought at ca. 4400-3800 yr BP blankets the onset of cave abandonment shortly after ca. 4403 cal yr BP, supporting the hypothesis that a climate anomaly may have played a role in this cultural disruption.

The impact of fire on the geochemistry of speleothem-forming drip water in a sub-alpine cave.

PubMed

Coleborn, Katie; Baker, Andy; Treble, Pauline C; Andersen, Martin S; Baker, Andrew; Tadros, Carol V; Tozer, Mark; Fairchild, Ian J; Spate, Andy; Meehan, Sophia

2018-06-12

Fire dramatically modifies the surface environment by combusting vegetation and changing soil properties. Despite this well-documented impact on the surface environment, there has been limited research into the impact of fire events on karst, caves and speleothems. Here we report the first experiment designed to investigate the short-term impacts of a prescribed fire on speleothem-forming cave drip water geochemistry. Before and after the fire, water was collected on a bi-monthly basis from 18 drip sites in South Glory Cave, New South Wales, Australia. Two months post-fire, there was an increase in B, Si, Na, Fe and Pb concentrations at all drip sites. We conclude that this response is most likely due to the transport of soluble ash-derived elements from the surface to the cave drip water below. A significant deviation in stable water isotopic composition from the local meteoric water line was also observed at six of the sites. We hypothesise that this was due to partial evaporation of soil water resulting in isotopic enrichment of drip waters. Our results demonstrate that even low-severity prescribed fires can have an impact on speleothem-forming cave drip water geochemistry. These findings are significant because firstly, fires need to be considered when interpreting past climate from speleothem δ 18 O isotope and trace element records, particularly in fire prone regions such as Australia, North America, south west Europe, Russia and China. Secondly, it supports research that demonstrates speleothems could be potential proxy records for past fires. Copyright © 2017 Elsevier B.V. All rights reserved.
The chronology of hand stencils in European Palaeolithic rock art: implications of new U-series results from El Castillo Cave (Cantabria, Spain).

PubMed

García-Diez, Marcos; Garrido, Daniel; Hoffmann, Dirk; Pettitt, Paul; Pike, Alistair; Zilhão, Joao

2015-07-20

The hand stencils of European Paleolithic art tend to be considered of pre-Magdalenian age and scholars have generally assigned them to the Gravettian period. At El Castillo Cave, application of U-series dating to calcite accretions has established a minimum age of 37,290 years for underlying red hand stencils, implying execution in the earlier part of the Aurignacian if not beforehand. Together with the series of red disks, one of which has a minimum age of 40,800 years, these motifs lie at the base of the El Castillo parietal stratigraphy. The similarity in technique and colour support the notion that both kinds of artistic manifestations are synchronic and define an initial, non-figurative phase of European cave art. However, available data indicate that hand stencils continued to be painted subsequently. Currently, the youngest, reliably dated examples fall in the Late Gravettian, approximately 27,000 years ago.
31 CFR 315.27 - Application for relief-nonreceipt of bond.

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2010-07-01

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Code of Federal Regulations, 2010 CFR

2010-07-01

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Water Isotope Proxy-Proxy and Proxy-Model Convergence for Late Pleistocene East Asian Monsoon Rainfall Reconstructions

NASA Astrophysics Data System (ADS)

Clemens, S. C.; Holbourn, A.; Kubota, Y.; Lee, K. E.; Liu, Z.; Chen, G.

2017-12-01

Confidence in reconstruction of East Asian paleomonsoon rainfall using precipitation isotope proxies is a matter of considerable debate, largely due to the lack of correlation between precipitation amount and isotopic composition in the present climate. We present four new, very highly resolved records spanning the past 300,000 years ( 200 year sample spacing) from IODP Site U1429 in the East China Sea. We demonstrate that all the orbital- and millennial-scale variance in the onshore Yangtze River Valley speleothem δ18O record1 is also embedded in the offshore Site U1429 seawater δ18O record (derived from the planktonic foraminifer Globigerinoides ruber and sea surface temperature reconstructions). Signal replication in these two independent terrestrial and marine archives, both controlled by the same monsoon system, uniquely identifies δ18O of precipitation as the primary driver of the precession-band variance in both records. This proxy-proxy convergence also eliminates a wide array of other drivers that have been called upon as potential contaminants to the precipitation δ18O signal recorded by these proxies. We compare East Asian precipitation isotope proxy records to precipitation amount from a CCSM3 transient climate model simulation of the past 300,000 years using realistic insolation, ice volume, greenhouse gasses, and sea level boundary conditions. This model-proxy comparison suggests that both Yangtze River Valley precipitation isotope proxies (seawater and speleothem δ18O) track changes in summer-monsoon rainfall amount at orbital time scales, as do precipitation isotope records from the Pearl River Valley2 (leaf wax δ2H) and Borneo3 (speleothem δ18O). Notably, these proxy records all have significantly different spectral structure indicating strongly regional rainfall patterns that are also consistent with model results. Transient, isotope-enabled model simulations will be necessary to more thoroughly evaluate these promising results, and to evaluate potentially distinct regional mechanisms linking rainfall amount to precipitation isotopes at orbital and millennial time scales in other monsoon regions. 1 Cheng et al., 10.1038/nature18591 2 Thomas et al., 10.1130/G36289.1 3 Carolin et al., 10.1016/j.epsl.2016.01.028
On the Quality of ENSDF {gamma}-Ray Intensity Data for {gamma}-Ray Spectrometric Determination of Th and U and Their Decay Series Disequilibria, in the Assessment of the Radiation Dose Rate in Luminescence Dating of Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Corte, Frans de; Vandenberghe, Dimitri; Wispelaere, Antoine de

In luminescence dating of sediments, one of the most interesting tools for the determination of the annual radiation dose is Ge {gamma}-ray spectrometry. Indeed, it yields information on both the content of the radioelements K, Th, and U, and on the occurrence - in geological times - of disequilibria in the Th and U decay series. In the present work, two methodological variants of the {gamma}-spectrometric analysis were tested, which largely depend on the quality of the nuclear decay data involved: (1) a parametric calibration of the sediment measurements, and (2) the correction for the heavy spectral interference of themore » 226Ra 186.2 keV peak by 235U at 185.7 keV. The performance of these methods was examined via the analysis of three Certified Reference Materials, with the introduction of {gamma}-ray intensity data originating from ENSDF. Relevant conclusions were drawn as to the accuracy of the data and their uncertainties quoted.« less
13C 18O clumping in speleothems: Observations from natural caves and precipitation experiments

NASA Astrophysics Data System (ADS)

Daëron, M.; Guo, W.; Eiler, J.; Genty, D.; Blamart, D.; Boch, R.; Drysdale, R.; Maire, R.; Wainer, K.; Zanchetta, G.

2011-06-01

The oxygen isotope composition of speleothems is an important proxy of continental paleoenvironments, because of its sensitivity to variations in cave temperature and drip water δ 18O. Interpreting speleothem δ 18O records in terms of absolute paleotemperatures and δ 18O values of paleo-precipitation requires quantitative separation of the effects of these two parameters, and correcting for possible kinetic isotope fractionation associated with precipitation of calcite out of thermodynamic equilibrium. Carbonate clumped-isotope thermometry, based on measurements of Δ47 (a geochemical variable reflecting the statistical overabundance of 13C 18O bonds in CO 2 evolved from phosphoric acid digestion of carbonate minerals), potentially provides a method for absolute speleothem paleotemperature reconstructions independent of drip water composition. Application of this new technique to karst records is currently limited by the scarcity of published clumped-isotope studies of modern speleothems. The only modern stalagmite reported so far in the literature yielded a lower Δ47 value than expected for equilibrium precipitation, possibly due to kinetic isotope fractionation. Here we report Δ47 values measured in natural speleothems from various cave settings, in carbonate produced by cave precipitation experiments, and in synthetic stalagmite analogs precipitated in controlled laboratory conditions designed to mimic natural cave processes. All samples yield lower Δ47 and heavier δ 18O values than predicted by experimental calibrations of thermodynamic equilibrium in inorganic calcite. The amplitudes of these isotopic disequilibria vary between samples, but there is clear correlation between the amount of Δ47 disequilibrium and that of δ 18O. Even pool carbonates believed to offer excellent conditions for equilibrium precipitation of calcite display out-of-equilibrium δ 18O and Δ47 values, probably inherited from prior degassing within the cave system. In addition to these modern observations, clumped-isotope analyses of a flowstone from Villars cave (France) offer evidence that the amount of disequilibrium affecting Δ47 in a single speleothem can experience large variations at time scales of 10 kyr. Application of clumped-isotope thermometry to speleothem records calls for an improved physical understanding of DIC fractionation processes in karst waters, and for the resolution of important issues regarding equilibrium calibration of Δ47 in inorganic carbonates.
Impact of uranium mining activity on cave deposit (stalagmite) and pine trees (S-Hungary)

NASA Astrophysics Data System (ADS)

Siklosy, Z.; Kern, Z.; Demeny, A.; Pilet, S.; Leel-Ossy, Sz.; Lin, K.; Shen, C.-C.; Szeles, E.

2009-04-01

Speleothems are well known paleoclimate archives but their potential for monitoring environmental pollution has not been fully explored. This study deals with an actively growing stalagmite whose trace-element concentration suggests anthropogenic contamination, rather then natural forcing. Paralell, as a potential independent chemo-enviromental archive, living pine (Pinus sylvestis) trees were also involved into investigation. U production in S-Hungary started in 1957 and was expanded closer to the cave site in 1965, covering a mining plot area of ca. 65 km2. The deep-level ore production ended in 1997 and remediation of the mine site has since been completed. Our objective was to determine the possible effect of the four-decade-long uranium (U) ore mining activity on the environment, as recorded by a cave deposit and the pine trees. The Trio Cave is located in the Mecsek Mts (S-Hungary), ca. 1.5-3 km east from the nearest air-shaft and entrance of the uranium mine. A stalagmite located about 150 m away from the cave entrance was drilled and the core investigated for stable isotope and trace element compositions. Pine trees were sampled by increment borer. Continuous flow mass spectrometry was applied on carbonate samples and laser ablation ICP-MS was applied for trace element analysis of both stalagmite (Siklosy et al., 2009) and pine samples. The youngest 1 cm of the drill core was selected for this study that may represent the last cca. 100 years (based on MC-ICP-MS age dating of older parts of the core) that covers the uranium mining period. The pre-mining period is characterized by systematic co-variations of trace elements (U, P, Si, Al, Ba, Mg, etc.) that can be related to soil activity and precipitation amount. The youngest 1.3 mm, however, records a sudden change in U content uncorrelated with any other variables. Starting from a background value of 0.2-0.3 ppm, the concentration gradually increases to about 2 ppm (within about 1 mm), remains constant for about 0.5 mm, then declines to about 1.5 ppm at the surface. The increase in U concentration coincided with a significant decrease in d234U initial values (Siklosy et al., 2008) suggesting contribution from a U source different from the natural weathering input. This is also supported by a change in the P/U ratio and much weaker correlation of the U concentrations with P in the U-enriched section of the stalagmite ("mining-period"). According to the average growth rate of the stalagmite, this period represents the last 30-50 years. Dendrochemical data covered the 1914-2004 period. The trace element time series derived from tree rings are characterized by plateaux-like maxima during the late-1960s and the 1985-95 period. This elevated events closely coupled to opening of two different uranium mine pits. Two prominent peaks emerged in the U-record coinciding the 1968 and 1991 tree rings. Dendrochemical data show abrupt increase in trace elemets (most pronounced in metals) from the tree ring dated to 1966 while the sudden decrease positioned to 1998 tree-ring. The perfect agreement between the dendrochronological dates of major changes in the chemistry of the wood and the onset-offset dates of mining history gives high probability that the mining activity is the main agent responsible for this environmental change. The possible source of U is therefore the 40-year-old Mecsek uranium mine, which produced ca. 500 tons of U concentrate per year and has reworked millions of tons of solid material (Bánik et al., 2002). Acknowledgements — This study was financially supported by the Hungarian Scientific Research Fund (OTKA T 049713 and K 67583). Measurements of U-Th isotopic compositions and and 230Th dates were supported by the National Science Council grants (94-2116-M002-012, 97-2752-M002-004-PAE & -005-PAE to C.C.S.). Bánik, J., Csicsák, J. and Berta, Zs. 2002: Experience on application of continuous drain trench during the remediation of tailings ponds in Hungary. In: Broder J. M., et al. (Eds), Uranium Mining and Hydrogeology III, 913-921. Siklósy, Z., Demény, A.,Pilet, S., Leél-Ossy, Lin, K. and Shen, C-C. 2008: Monitoring environmental pollution using a stalagmite from Hungary. PAGES News 16/3. 27-28. Siklósy, Z., Demény, A., Vennemann, T.W., Pilet, S., Kramers, J., Leél-Ossy, Sz., Bondár, M., Shen, C-C. and Hegner, E. 2009: Bronze Age volcanic event recorded in stalagmites by combined isotope and trace element studies, Rapid Communications in Mass Spectrometry, Accepted for publ.
Chemical characterization of lipids in speleothems and cave drip water by organic trace analysis (HPLC-ESI-IT/MS) and its potential for the investigation of palaeoenvironmental changes

NASA Astrophysics Data System (ADS)

Bosle, J.; Scholz, D.; Hoffmann, T.

2012-04-01

Cave drip water, speleothems and the proxies preserved within them have significant potential to record palaeoenvironmental changes in the regional vegetation [1]. The use of stalagmites provides valuable information because they form a chemically closed system which does not change much after lithification, they grow continuously and are amenable to precise Th/U-dating [2]. The most common proxies measured in speleothems are inorganic proxies, in particular oxygen isotopes, but more recently the importance of organic matter analyses in this field is examined. This study focuses on the research of lipid biomarkers. The lipids contained in stalagmites originate from the overlying soil and different plants, bacteria and fungi. Therefore different compositions of lipids may provide records of environmental changes [3]. In the following the development of a new method for the extraction of saturated free fatty acids from cave drip water and their measurement by RP-HPLC-ESI-IT/MS (reversed phase high performance liquid chromatography coupled to electrospray ion trap mass spectrometry) is presented. Four different fatty acids (myristic acid, palmitic acid, stearic acid and arachidic acid) with chain lengths from C14 to C20 were applied as analytical standards. A mixture of these was used to optimize the separation by HPLC. The analytes were measured in MRM mode (multiple reactions monitoring) and negative polarity (m/z: 227, 255, 283, 311) therefore a time consuming derivatisation of the fatty acids was not necessary. By using a certain gradient program an adequate separation of the standards was accomplished. Likewise the realization of calibration curves of the different fatty acids showed that quantitative analyses are possible as well. To simulate the extraction of the analytes from cave drip water a spiking experiment with the analytical standards was performed. Three water samples were spiked with the same amount of the fatty acids to test the reproducibility of the extraction. The extraction was carried out using a SPE (solid phase extraction) procedure in which the elution of the analytes was assured by using a rather apolar solvent like dichloromethane. Measurements of water blanks which were treated the same way as the spikes showed high amounts of palmitic acid and stearic acid which were reduced by heating the glass ware to 400 °C before usage. To achieve an improvement of the reproducibility of the spiking experiment different amounts and compositions of organic solvents were added to the water samples to function as a modifier. These parameters are optimized to obtain a sufficient reproducibility of the extraction procedure in order to extract the actual cave drip water samples.
High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardèche, France) using laser ablation ICP-MS

NASA Astrophysics Data System (ADS)

Grün, Rainer; Aubert, Maxime; Joannes-Boyau, Renaud; Moncel, Marie-Hélène

2008-11-01

We have mapped U ( 238U) and Th ( 232Th) elemental concentrations as well as U-series isotope distributions in a Neanderthal tooth from the Middle Palaeolithic site of Payre using laser ablation ICP-MS. The U-concentrations in an enamel section varied between 1 and 1500 ppb. The U-concentration maps show that U-migration through the external enamel surface is minute, the bulk of the uranium having migrated internally via the dentine into the enamel. The uranium migration and uptake is critically dependent on the mineralogical structure of the enamel. Increased U-concentrations are observed along lineaments, some of which are associated with cracks, and others may be related to intra-prismatic zones or structural weaknesses reaching from the dentine into the enamel. The uranium concentrations in the dentine vary between about 25,000 and 45,000 ppb. Our systematic mapping of U-concentration and U-series isotopes provides insight into the time domain of U-accumulation. Most of the uranium was accumulated in an early stage of burial, with some much later overprints. None of the uranium concentration and U-series profiles across the root of the tooth complied with a single stage diffusion-adsorption (D-A) model that is used for quality control in U-series dating of bones and teeth. Nevertheless, in the domains that yielded the oldest apparent U-series age estimates, U-leaching could be excluded. This means that the oldest apparent U-series ages of around 200 ka represent a minimum age for this Neanderthal specimen. This is in good agreement with independent age assessments (200-230 ka) for the archaeological layer, in which it was found. The Th elemental concentrations in the dental tissues were generally low (between about 1 and 20 ppb), and show little relationship with the nature of the tissue.
High-resolution isotope records of early Holocene rapid climate change from two coeval stalagmites of Katerloch Cave, Austria

NASA Astrophysics Data System (ADS)

Boch, Ronny; Spötl, Christoph; Kramers, Jan

2009-11-01

Two coeval stalagmites from Katerloch Cave show pronounced intervals of low δ18O values around 8.2, 9.1, and 10.0 kyr (all ages are reported before the year 2000 AD) and represent an inorganic U-Th dated climate archive from the southeast of the European Alps, a region where only very few well-dated climate records exist. The O isotope curves, providing near-annual resolution, allow a direct comparison to the Greenland ice core records, as temperature was the primary factor controlling the O isotopic composition of Katerloch speleothems. The 8.2 kyr climate anomaly lasted about one century, from 8196 to 8100 yr, with a maximum amplitude of 1.1‰ at 8175 yr. The event is characterized by a rapid onset and a more gradual demise and U-Th data as well as annual lamina counting support a rapid climate change towards cooler conditions within 10-20 yr. There is no strong evidence that the 8.2 kyr anomaly was superimposed on a pronounced longer-term cooling episode, nor do the new data support two separate cooling events within the 8.2 kyr event as reported by other studies. Our record also shows a distinct climate anomaly around 9.1 kyr, which lasted 70-110 yr and showed a maximum amplitude of 1.0‰, i.e. it had a similar duration and amplitude as the (central) 8.2 kyr event. Compared to the 8.2 kyr event, the 9.1 kyr anomaly shows a more symmetrical structure, but onset and demise still occurred within a few decades only. The different progression of the 8.2 (asymmetrical) and 9.1 kyr anomaly (symmetrical) suggests a fundamental difference in the trigger and/or the response of the climate system. Moreover, both stalagmites show evidence of a climate anomaly around 10.0 kyr, which was of comparable magnitude to the two subsequent events. Using a well constrained modern calibration between air temperature and δ18O of precipitation for the study area and cave monitoring data (confirming speleothem deposition in Katerloch reflecting cave air temperature), a maximum cooling by ca 3 °C can be inferred at 8.2 and 9.1 kyr, which is similar to other estimates, e.g., from Lake Ammersee north of the Alps. The O isotopic composition of meteoric precipitation, however, is a complex tracer of the hydrological cycle and these temperature estimates do not take into account additional effects such as changes in the source area or synoptic shifts. Apart from that, the relative thickness of the seasonally controlled lamina types in the Katerloch stalagmites remains rather constant across the intervals comprising the isotopic anomalies, i.e. the stalagmite petrography argues against major shifts in seasonality during the early Holocene climate excursions.
Temperature and altitudinal influence on karst dripwater chemistry: Implications for regional-scale palaeoclimate reconstructions from speleothems

NASA Astrophysics Data System (ADS)

Borsato, Andrea; Johnston, Vanessa E.; Frisia, Silvia; Miorandi, Renza; Corradini, Flavio

2016-03-01

The reconstruction of robust past climate records from speleothems requires a prior understanding of the environmental and hydrological conditions that lead to speleothem formation and the chemical signals encoded within them. On regional-scales, there has been little quantification of the dependency of cave dripwater geochemistry on meteorology (net infiltration, temperature), environmental and geographical factors (elevation, latitude, soil activity, vegetation cover, atmospheric aerosol composition) and geological properties of the aquifer (lithology, porosity and thickness). In the present study, we analysed over 200 karst waters collected in 11 caves of the Trentino region (NE Italy). The caves span sub-humid Mediterranean to cold-humid temperate climates and infiltration elevations (Zinf) ranging from 355 to 2400 m a.s.l., corresponding to infiltration mean annual temperatures (MATinf) between 12 and 0 °C. Since all the caves developed in pure carbonate rocks, soil pCO2 is found to be the main factor controlling the carbonate dissolution. For this reason, the parameters controlling the carbonate-carbonic acid system and calcite saturation state (SICC) are directly correlated with the MATinf, which influences the vegetation zones and eventually the production of CO2 in the soil. SICC linearly depends on MATinf (SICC = 0.09 MATinf - 0.4) and SICC = 0 is reached at Zinf = 1.66 km a.s.l., corresponding to a MATinf = 4.4 °C. This point identifies the ;speleothem limit; defined here as the elevation (or corresponding MATinf) above which no sparitic speleothem precipitation usually occurs. We demonstrate that due to temperature-forced changes in the soil and vegetation and subsequently SICC, the speleothem limit shifts to higher altitudes during maximum interglacial conditions. Speleothems from high altitude caves (1.5-2.5 km a.s.l.) thus can identify optimum interglacial periods. By contrast, speleothems formed at lower altitudes are better suited as archives of hydrological proxies. At altitudes below 1.2 km a.s.l., prior calcite precipitation (PCP) modifies percolating waters, particularly during periods of reduced infiltration. We introduce the use of the SiO2/Ca and SO4/Ca ratios in cave waters to complement Mg/Ca and Sr/Ca ratios as markers of PCP. SO4 and SiO2 are derived from atmospheric deposition and siliciclastic minerals in the soil zone, rather than carbonate host rocks (as in the case of Mg and Sr). By combing shifts to higher Mg/Ca, SiO2/Ca and SO4/Ca ratios along their characteristics PCP lines, we improve the robustness of the interpretation that this resulted from increasing PCP, rather than incongruent calcite dissolution (ICD). Our method permits the quantification of PCP between 0% and 40% for low elevation cave waters. This novel approach has important implications for speleothem-based paleoclimate studies where the distinction between PCP and ICD can be ambiguous and, in combination with Mg/Ca and Sr/Ca ratios, permits the quantification of net infiltration and/or rainfall amount from speleothem records.
Comparison of the timings between abrupt climate changes in Greenland, Antarctica, China and Japan based on robust correlation using Lake Suigetsu as a template.

NASA Astrophysics Data System (ADS)

Nakagawa, T.

2014-12-01

High-resolution pollen-derived climate records from Lake Suigetsu varved sediment core were compared with climate archives from other regions and revealed a particular spatio-temporal structure of the monsoon climate change during so-called D-O events. Leads and lags of the climate change between different regions hold the key to understand the climate system. However, robust assessment of the relative timing of the climate change is often very challenging because correlation of the climatic archives from different regions often has inevitable uncertainties. Greenland and Cariaco basin, for example, provide two of the most frequently sited palaeoclimatic proxy data representative of the high- and low-latitudinal Atlantic regions. However, robust correlation of the records from those regions is difficult because of the uncertainties in layer countings, lack of the radiocarbon age control from ice cores, marine reservoir age of the Cariaco sediments, and the absence of the tephra layers shared by both cites. Similarly, Speleothem and ice core records are not robustly correlated to each other, either for the dead carbon fraction in the speleothems and lack of reliable correlation markers. The generally accepted hypothesis of synchronous climate change between China and the Greenland is, therefore, essentially hypothetical. Lake Suigetsu provides solution to this problem. The lake Suigetsu chronology is supposed to be coherent to the speleothems' U-Th age scale. Suigetsu's semi-continuous radiocarbon dataset, which constitutes major component of the IntCal13 radiocarbon calibration model, also provides opportunity to correlate lake Suigetsu and the Greenland and Antarctic ice cores using cosmogenic isotopes as the correlation key. Results of the correlation and timing comparison, which cast new lights to the mechanism of the monsoon change, will be presented.
A simple-rapid method to separate uranium, thorium, and protactinium for U-series age-dating of materials.

PubMed

Knight, Andrew W; Eitrheim, Eric S; Nelson, Andrew W; Nelson, Steven; Schultz, Michael K

2014-08-01

Uranium-series dating techniques require the isolation of radionuclides in high yields and in fractions free of impurities. Within this context, we describe a novel-rapid method for the separation and purification of U, Th, and Pa. The method takes advantage of differences in the chemistry of U, Th, and Pa, utilizing a commercially-available extraction chromatographic resin (TEVA) and standard reagents. The elution behavior of U, Th, and Pa were optimized using liquid scintillation counting techniques and fractional purity was evaluated by alpha-spectrometry. The overall method was further assessed by isotope dilution alpha-spectrometry for the preliminary age determination of an ancient carbonate sample obtained from the Lake Bonneville site in western Utah (United States). Preliminary evaluations of the method produced elemental purity of greater than 99.99% and radiochemical recoveries exceeding 90% for U and Th and 85% for Pa. Excellent purity and yields (76% for U, 96% for Th and 55% for Pa) were also obtained for the analysis of the carbonate samples and the preliminary Pa and Th ages of about 39,000 years before present are consistent with (14)C-derived age of the material. Copyright © 2014 Elsevier Ltd. All rights reserved.
U-series ages of solitary corals from the California coast by mass spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stein, M.; Wasserburg, G.J.; Chen, J.H.

1991-12-01

The purpose of this study is to evaluate the feasibility of dating fossil solitary corals from Pleistocene marine strandlines outside tropical latitudes using the recently developed high sensitivity, high-precision U-series technique based on thermal-ionization mass-spectrometry (TIMS). The TIMS technique is much more efficient than conventional {alpha} spectrometry and, as a result, multiple samples of an individual coral skeleton, or different specimens from the same bed can be analyzed. Detached and well-rounded fossil specimens of the solitary coral Balanophyllia elegans were collected from relict littoral deposits on emergent marine terraces along the California coast at Cayucos terrace, Shell Beach terrace, Nestormore » terrace, San Diego, Bird Rock terrace, San Diego. Attached living specimens were collected from the intertidal zone on the modern terrace at Moss Beach. The calculated initial {sup 234}U activities in the fossil specimens of Balanophyllia elegans are higher than the {sup 234}U activity in modern seawater or in the modern specimen. The higher initial activities could possibly reflect the influx of {sup 234}U-enriched continental water into Pleistocene coastal waters, or it could reflect the influx of {sup 234}U-enriched continental water into Pleistocene coastal waters, or it could reflect minor diagenetic alteration, a persistent and fundamental problem in dating all corals.« less
The U.S. Commercial Motor Vehicle Safety Act of 1986. Workforce & Workplace Literacy Series.

ERIC Educational Resources Information Center

BCL Brief, 1991

1991-01-01

This brief presents summary information about the U.S. Commercial Motor Vehicle Safety Act of 1986, which mandated the Commercial Driver's License Test (CDL); the compliance status of states and drivers to date; and a recently authorized government grants program that will help fund CDL adult education programs. It also provides…

Holocene moisture changes in western China, Central Asia, inferred from stalagmites

NASA Astrophysics Data System (ADS)

Cai, Yanjun; Chiang, John C. H.; Breitenbach, Sebastian F. M.; Tan, Liangcheng; Cheng, Hai; Edwards, R. Lawrence; An, Zhisheng

2017-02-01

Central Asia lies at the convergence between the Mediterranean and Asian monsoon climates, and there is a complex interaction between the westerlies with the monsoon to form the climate of that region and its variability. The region is highly vulnerable to changes in rainfall, highlighting the need to understand the underlying controls. We present a stalagmite-based δ18O record from Kesang Cave in western China, using MC-ICP-MS U-series dating and stable isotope analysis. Stalagmite calcite δ18O largely documents changes in the δ18O of precipitation. δ18O in stalagmites was low during the early and middle Holocene (10.0-3.0 ka BP), and shifted to higher values between 3.0 and 2.0 ka BP. After 2.0 ka BP, δ18O fluctuates with distinct centennial-scale variations. Drawing from results of state-of-the-art atmospheric general circulation model simulations for the preindustrial period and 9 ka BP, we propose that changes in moisture source regions and the wetter climate both contributed to the isotopic depletion of precipitation during the early and middle Holocene. Multiple records from surrounding regions indicate a generally wetter climate during the early and mid- Holocene, supporting our interpretation on the speleothem δ18O. Changes in precipitation seasonality do not appear to be a viable explanation for the observed changes, nor increased penetration of monsoonal moisture to the study site. We speculate that the climatic regime shifted around 3.0-2.0 ka BP towards a drier climate, resulting in temperature having dominant control on precipitation δ18O. The demise of three settlements around 500AD at the margin of Tarim Basin coincided with a period of decreased precipitation and increased temperature that likely affected local water resources, underscoring the potential impact of climate on human habitation in this region.
Multi-proxy evidence of millennial climate variability from multiple Bahamian speleothems

NASA Astrophysics Data System (ADS)

Arienzo, Monica M.; Swart, Peter K.; Broad, Kenneth; Clement, Amy C.; Pourmand, Ali; Kakuk, Brian

2017-04-01

Northern Hemisphere tropical paleoclimate records support significant changes associated with Dansgaard Oeschger (D/O) events and Heinrich stadials 1 to 6 during the last 64,000 years. However, few absolutely dated terrestrial records from the western Atlantic span the last six Heinrich stadials. Here we present geochemical results from three new stalagmites collected from a cave in the Bahamas which encompass Heinrich stadials 1 to 6. We build on a previous study of the δ13C and δ18O values of the calcite and δ18O value of fluid inclusions from a single stalagmite from the same cave spanning the last three Heinrich stadials. Absolute geochronometry using U-Th equilibrium series demonstrates that the stalagmites formed between 63.8 and 13.8 kyr BP. The δ13C and δ18O values of the calcite show higher values associated with Heinrich stadials 1-6, and lower values during the D/O interstadial events. The Sr/Ca ratios of the calcite are shown to be relatively invariant, while in two of the samples the Mg/Ca ratios track the δ13C values. Increases in the δ18O values across Heinrich stadials 1-6 are interpreted as being driven by lower temperatures. The two deeper occurring stalagmites demonstrate increased Mg/Ca ratios and δ13C values during Heinrich stadials 1 and 2 which are interpreted as a signal of reduced flow rates in the epikarst and increased water/rock interactions as a result of increased aridity which potentially occurred across all six Heinrich stadials. The observed reductions in mean annual temperature and amount of precipitation across Heinrich stadials are proposed to be driven by a reduction in sea surface temperatures in the North Atlantic and an expanded Bermuda High. During D/O interstadials, the Bahamas cave records likely indicate warmer and/or wetter climate; however the isotopic shifts are not as significant as the isotopic excursions associated with Heinrich stadials.
Southern Arizona hydroclimate over the last 3000 years: a comparison of speleothem elemental data and climate model simulations

NASA Astrophysics Data System (ADS)

King, J.; Harrington, M. D.; Cole, J. E.; Drysdale, R.; Woodhead, J. D.; Fasullo, J.; Stevenson, S.; Otto-Bliesner, B. L.; Overpeck, J. T.; Edwards, R. L.; Henderson, G. M.

2017-12-01

Understanding long-term hydroclimate is particularly important in semiarid regions where prolonged droughts may be exacerbated by a warming climate. In many regions, speleothem trace elements correlate with regional wet and dry climate signals. In the drought-prone Southwestern US (SW), wet and dry episodes are strongly influenced by seasonal changes in atmospheric circulation and teleconnections to remote forcing. Here, we address the need for seasonal moisture reconstructions using paleoclimate and climate model approaches. First, we present a high-resolution (sub-annual) record of speleothem trace elements spanning the last 3000 years from Fort Huachuca Cave, AZ, to investigate the variability of regional seasonal precipitation and sustained regional droughts. In a principal component (PC) analysis of the speleothem, trace elements associated with wet (Sr, Ba) and dry (P, Y, Zn) episodes load strongly and inversely, and the associated PC signals correlate with local gridded precipitation data over the last 50 years (R > 0.6, p < 0.1). These results suggest that the elemental signals provide a seasonal moisture record for Southern Arizona. We use the record to examine the frequency and timing of extreme droughts in the region and compare the speleothem record's frequency domain characteristics with other regional moisture records and with climate model output. The speleothem record demonstrates strong low-frequency variability with pronounced multi-decadal dry periods, a feature notably lacking in drought metrics from simulations of the last millennium. We also examine the seasonal SW precipitation response to modes of climate variability and external forcings, including volcanic eruptions, in both the speleothem record and the Community Earth System Model's Last Millennium Ensemble (CESM-LME). Notably, ENSO and volcanic forcing have a discernable effect on SW seasonal precipitation in model simulations, particularly when the two processes combine to shift the position of the ITCZ. This integrated analysis of paleodata with climate model results will help us identify and explain discrepancies between these information sources and improve stakeholders' ability to anticipate and prepare for future drought.
Bomb 14C time history recorded in two modern stalagmites — importance for soil organic matter dynamics and bomb 14C distribution over continents

NASA Astrophysics Data System (ADS)

Genty, D.; Vokal, B.; Obelic, B.; Massault, M.

1998-08-01

Carbon 14 activity measurements made by Accelerator Mass Spectrometry on two modern stalagmites from the Han-sur-Lesse cave (Belgium) and from the Postojna Cave (Slovenia) permit the construction of 14C activity ( a14C) time series over the last 50 years. A high precision chronology is given by annual laminae in the first stalagmite and by a specific mark (explosion in the Postojna Cave in 1944) in the second one. In both stalagmites, 14C activity increase due to nuclear tests in the atmosphere is remarkable. However, instead of a sharp peak like the one observed in the atmosphere around 1963-1964, the 14C activities of the stalagmite CaCO 3 show an abrupt increase, with an offset of 1-10 years, followed by a high activity plateau for the Han-sur-Lesse sample and a slight decrease for the Postojna sample. For both stalagmites, the variation of the a14C amplitude between pre- and post-bomb period is much lower than the atmospheric record, which demonstrates the damping effect of the soil carbon reservoir. We have modeled the CaCO 3 activities using fractionation processes between atmosphere CO 2, soil CO 2 and organic matter (OM), dissolved inorganic carbon and stalagmite CaCO 3. In both cases studied, the model and former soil studies suggest that CO 2 from soil organic matter (SOM) decomposition, which has a slow turnover (i.e. >1 y), is of major importance in winter, when the development of speleothem is the most important. Combined with the fact that 80-90% of the stalagmite carbon comes from soil CO 2, this produces a damping effect on the speleothem a14C. Consequently, the `geochemical time resolution', at least for speleothem carbon, is much lower than the structural resolution given by annual laminae alternations and is mainly controlled by soil carbon dynamics: a14C and δ 13C are smoothed over several years. Differences between the 14C time series of the Han-sur-Lesse and Postojna stalagmites are likely to be due to the double amount of precipitation in Postojna, which produces a faster soil OM turnover and thus a `system' which is more sensitive to atmospheric changes.
Speleothems as Examples of Chemical Equilibrium Processes.

ERIC Educational Resources Information Center

Wilson, James R.

1984-01-01

The chemical formation of speleothems such as stalactites and stalagmites is poorly understood by introductory geology instructors and misrepresented in most textbooks. Although evaporation may be a controlling factor in some caves, it is necessary to consider chemical precipitation as more important in controlling the diagenesis of calcium…
Millennial Scale Rapid Climate Change Events of the last 60kya as Observed in Multiple Stalagmites from The Bahamas

NASA Astrophysics Data System (ADS)

Mehterian, S.; Arienzo, M. M.; Pourmand, A.; Broad, K.; Kakuk, B.; Swart, P. K.

2016-12-01

Nine stalagmites collected from various depths of a submerged cave system on the island of Abaco, Bahamas comprise a continuous record of oxygen isotopic variation between 7.3 to 63kyr. The depths from which the speleothems were collected range from 12m to 37m. The youngest age of the speleothems reflect the inundation of the cave system by rising sea level. Millennial scale rapid climate change events can be seen in the δ18O record of the Bahamian stalagmites as Heinrich Stadials H0 to H6 and Dansgaard Oeschger Events. This collection of stalagmites represents different depths in a cave in Abaco, and their collective geochemical record reflects the global climatic effects as experienced locally in the subtropical islands of the Bahamas. Separately, various stalagmites that grew during the same time periods reflect similar patterns in the δ18O values of their calcite mineralogy despite having been located at vastly different depth elevations relative to each other. In general, the average δ18O value for the stalagmites collected from this cave is -2.5‰ VPDB with a maximum and minimum δ18O value between 0.5 ‰ and -5.5‰ VPDB respectively during Heinrich stadials and D/O events. In addition to δ18O values measured in these stalagmites, ratios of Sr/Ca, Mg/Ca, and Ba/Ca are also compared with one another. This study attempts to elucidate differences, if any, that locations in a cave relative to sea level would have on recording the true climate signals of a region. Finally, results from this study are compared with stalagmites collected from Eleuthera, another Bahamian island with speleothems younger than those from Abaco in order to create a mostly continuous record of rapid climate change events dating back from present day to 63,000 years.
Application of Scanning Electron Microscopy/Energy-Dispersive X-Ray Spectroscopy for Characterization of Detrital Minerals in Karst Cave Speleothems.

PubMed

Zupančič, Nina; Miler, Miloš; Šebela, Stanka; Jarc, Simona

2016-02-01

Micro-scale observations in karst caves help to identify different processes that shaped local morphology. Scanning electron microscopy/energy-dispersive X-ray spectroscopy inspection of speleothems from two karst caves in Slovenia, Predjama and Črna Jama, confirmed the presence of sub-angular to sub-rounded detrital fragments of clay minerals, feldspars, quartz, Fe-oxides/hydroxides, rutile and Nb-rutile, xenotime, kassite, allanite, fluorapatite, epidote, ilmenite, monazite, sphene, and zircon, between 2 and 50 μm across. These occur in porous layers separating calcite laminae in the clayey coating on the layer below the surface of the speleothems, and are also incorporated within actual crystals. It is likely that they are derived from the weathered rocks of the Eocene flysch. Probably they were first transported into the caves by floodwaters forming cave sediments. Later, depending upon the climate conditions, they were moved by air currents or by water to the surface of active speleothems. They might also be redeposited from overlying soils enriched with wind-transported minerals from the flysch, or from higher passages filled with weathered flysch sediment, by drip water percolating through the fissured limestone. As some of the identified minerals are carriers of rare earth elements, Ti and Zr, their presence could affect any palaeoclimatic interpretations that are based upon the geochemical composition of the speleothems.
Exploring the U-Pb systematics of titanite from the Archean Stillwater Complex

NASA Astrophysics Data System (ADS)

Friedman, R. M.; Wall, C. J.; Scoates, J. S.; Weis, D. A.; Meurer, W. P.

2011-12-01

The Stillwater Complex is a large mafic-ultramafic layered intrusion in the Beartooth Mountains of Montana (USA) and host to the world-class J-M Reef platinum group element deposit. The size and geologic/economic importance of this igneous complex make it an important target for high-precision U-Pb dating. As a part of a comprehensive U-Pb study of the Stillwater Complex, we present ID-TIMS U-Pb titanite data, including new single grain results produced using the EARTHTIME ET535 spike, for very low-volume, relatively felsic granophyric and pegmatitic rocks associated with Stillwater layered rocks. Four samples studied include a pegmatitic ksp-qtz core to a gabbroic pegmatoid in the Lower Banded Series (N1), an alaskite (quartz diorite) and an amphibole-rich reaction zone between the alaskite and anorthosite (AN1) in the Middle Banded Series, and an amphibole-bearing granophyre from the Upper Banded Series (GN3). CA-TIMS U-Pb dating of zircon from these samples yielded concordant results only for the pegmatitic rock (weighted 207Pb/206Pb: 2709.65 ± 0.80 Ma, n = 5), which agrees with new zircon ages from Stillwater layered rocks. Results for high-U (up to 1438 ppm) metamict zircon that occurs in the other three rocks were highly discordant and did not yield precise ages. Titanite U-Pb results for the pegmatite are about -1% to +1% discordant with two groupings of 207Pb/206Pb dates: one with a weighted average of 2708.1 ± 2.0 Ma (n = 2), which overlaps in age with zircon from the same sample and the crystallization age of the Stillwater Complex, and a second, younger grouping of 2701.1 ± 1.3 Ma (n = 5). Younger dates record an early Pb-loss event, possibly related to intrusion of cross-cutting quartz monzonites. The alaskite data also shows two groupings of 207Pb/206Pb dates, although more subtle: a weighted average of 2709.3 ± 1.8 Ma (n = 3) and a single result of 2706.5 ± 1.7 Ma. Titanite from the other two samples has undergone significant Pb-loss. Results for four analyses from the reaction zone sample are 1.74-54.3% discordant and lie in a quasi-linear array with intercepts at ca. 2700 Ma and 325 Ma. Data for the granophyre in the Upper Banded Series also have a wide range of discordance (1.5-3.4%, 21.4% and 61.3%). Titanites from these samples appear to have undergone a two stage Pb-loss history: an early, relatively minor event as suggested for the pegmatite, and a subsequent episode, which for some grains resulted in significant discordance. Concordant U-Pb titanite data from two of the Stillwater Complex granophyres confirms nearly synchronous crystallization with that of the layered rocks in the intrusion. For the pegmatite, the ages and overlap of zircon and titanite suggest a direct relationship between the granophyres and the layered rock and relatively rapid cooling of the complex through titanite closure temperature. Titanite from the alaskite yields useful age information, whereas coexisting zircon are highly discordant and not age diagnostic.
Biomineralization and biosignatures of coralloid-type speleothems from lava tubes of Galapagos Islands: evidences on the fossil record of prokaryotes

NASA Astrophysics Data System (ADS)

Miller, Ana Z.; Garcia-Sanchez, Angela M.; Pereira, Manuel F. C.; Gazquez, Fernando; Calaforra, José M.; Forti, Paolo; Toulkeridis, Theofilos; Martínez-Frías, Jesús; Saiz-Jimenez, Cesareo

2016-04-01

Lava tubes have traditionally been considered of little interest from a mineralogical point of view. Recently, this type of volcanic caves has received particular attention because lava tubes have been described on Mars. Speleothems, or secondary mineral deposits in lava tubes are mainly composed of siliceous minerals. Coralloid-type speleothems are found either on basaltic cave walls or on the surface of other speleothems. Several authors attribute a microbially mediated origin to their formation. This type of speleothems was recorded within Royal Palm Cave of Santa Cruz Island in Galapagos Archipelago (Ecuador), a lava tube 600 m long, 5 to 15 m height and 2 to 10 m width. The Galapagos Islands are an archipelago of 19 volcanic islands located some 1500 km west of Ecuador, in the Pacific Ocean. These islands host one of the most biodiverse settings on Earth, studied by Charles Darwin. Beige and greyish small coralloids were collected in Royal Palm Cave and analysed by field emission scanning electron microscopy with energy dispersive X-ray spectroscopy (FESEM-EDS), X-ray micro-computed tomography (micro-CT) and mineralogical analyses for morphological, 3D microstructural and compositional characterization, as well as for assessing microbe-mineral interactions and biogenicity. In addition, 16S rRNA gene analyses were performed to identify microbial communities associated with the coralloid-type speleothems. The coralloids showed internal compositional zonation along the growth direction of the speleothems, according to micro-CT data. Internal layering was clearly discernable by the differences in opacity of the distinct mineralogical phases to X-rays, being dominated by alteration products of siliceous composition, whereas more opaque phases, usually Ca-rich minerals, were dominant in the outermost part of the speleothems. X-ray diffraction and infrared spectroscopy reinforced that the first stage of deposition is mainly composed of opal A and clay minerals, whereas the final stage mainly consists of low crystalline calcite. FESEM-EDS analysis revealed mineralized bacterial filaments rich in Si on the coralloid samples, as well as minerals precipitation associated with extracellular polymeric substances (EPS), which serve as nuclei for preferential precipitation on the extracellular sheaths. This suggests that biological activity played a major role in the development of these speleothems. In addition, imprints of filamentous cells and microboring readily preserved on siliceous minerals were observed on the coralloid speleothems. These features are recognized as biosignatures valuable for astrobiology and may represent modern analogs of the fossil record of prokaryotes. DNA-based analyses showed that bacteria belonging to Actinobacteria (31%) Gemmatimonadetes (25%) and Proteobacteria (24%) phyla dominated in this cave ecosystem, followed by Acidobacteria, Firmicutes and Nitrospirae. Most of the identified phylotypes were affiliated to chemoautotrophs, including thermophilic bacteria such as Ferrithrix thermotolerans, and other mineral utilizing microorganisms like Aciditerrimonas ferrireducens, Desulfuromonas sp. and Desulfovibrio sp., indicating that Galapagos lava tubes host highly specialized subsurface biosphere dominated by microorganisms able to interact with minerals and promote biomineralization. Acknowledgments: This work has been supported by the project PC-65-14 from the Ministry of Environment of Ecuador. AZM acknowledges the support from the Marie Curie Fellowship of the 7th EC Framework Programme (PIEF-GA-2012-328689-DECAVE). The authors acknowledge the Spanish Ministry of Economy and Competitiveness (project CGL2013-41674-P) and FEDER funds for financial support.
A high-resolution speleothem record of western equatorial Pacific rainfall: Implications for Holocene ENSO evolution

NASA Astrophysics Data System (ADS)

Chen, Sang; Hoffmann, Sharon S.; Lund, David C.; Cobb, Kim M.; Emile-Geay, Julien; Adkins, Jess F.

2016-05-01

The El Niño-Southern Oscillation (ENSO) is the primary driver of interannual climate variability in the tropics and subtropics. Despite substantial progress in understanding ocean-atmosphere feedbacks that drive ENSO today, relatively little is known about its behavior on centennial and longer timescales. Paleoclimate records from lakes, corals, molluscs and deep-sea sediments generally suggest that ENSO variability was weaker during the mid-Holocene (4-6 kyr BP) than the late Holocene (0-4 kyr BP). However, discrepancies amongst the records preclude a clear timeline of Holocene ENSO evolution and therefore the attribution of ENSO variability to specific climate forcing mechanisms. Here we present δ18 O results from a U-Th dated speleothem in Malaysian Borneo sampled at sub-annual resolution. The δ18 O of Borneo rainfall is a robust proxy of regional convective intensity and precipitation amount, both of which are directly influenced by ENSO activity. Our estimates of stalagmite δ18 O variance at ENSO periods (2-7 yr) show a significant reduction in interannual variability during the mid-Holocene (3240-3380 and 5160-5230 yr BP) relative to both the late Holocene (2390-2590 yr BP) and early Holocene (6590-6730 yr BP). The Borneo results are therefore inconsistent with lacustrine records of ENSO from the eastern equatorial Pacific that show little or no ENSO variance during the early Holocene. Instead, our results support coral, mollusc and foraminiferal records from the central and eastern equatorial Pacific that show a mid-Holocene minimum in ENSO variance. Reduced mid-Holocene interannual δ18 O variability in Borneo coincides with an overall minimum in mean δ18 O from 3.5 to 5.5 kyr BP. Persistent warm pool convection would tend to enhance the Walker circulation during the mid-Holocene, which likely contributed to reduced ENSO variance during this period. This finding implies that both convective intensity and interannual variability in Borneo are driven by coupled air-sea dynamics that are sensitive to precessional insolation forcing. Isolating the exact mechanisms that drive long-term ENSO evolution will require additional high-resolution paleoclimatic reconstructions and further investigation of Holocene tropical climate evolution using coupled climate models.
Potential effects of alpha-recoil on uranium-series dating of calcrete

USGS Publications Warehouse

Neymark, L.A.

2011-01-01

Evaluation of paleosol ages in the vicinity of Yucca Mountain, Nevada, at the time the site of a proposed high-level nuclear waste repository, is important for fault-displacement hazard assessment. Uranium-series isotope data were obtained for surface and subsurface calcrete samples from trenches and boreholes in Midway Valley, Nevada, adjacent to Yucca Mountain. 230Th/U ages of 33 surface samples range from 1.3 to 423 thousand years (ka) and the back-calculated 234U/238U initial activity ratios (AR) are relatively constant with a mean value of 1.54 ± 0.15 (1σ), which is consistent with the closed-system behavior. Subsurface calcrete samples are too old to be dated by the 230Th/U method. U-Pb data for post-pedogenic botryoidal opal from a subsurface calcrete sample show that these subsurface calcrete samples are older than ~ 1.65 million years (Ma), old enough to have attained secular equilibrium had their U-Th systems remained closed. However, subsurface calcrete samples show U-series disequilibrium indicating open-system behavior of 238U daughter isotopes, in contrast with the surface calcrete, where open-system behavior is not evident. Data for 21 subsurface calcrete samples yielded calculable 234U/238U model ages ranging from 130 to 1875 ka (assuming an initial AR of 1.54 ± 0.15, the mean value calculated for the surface calcrete samples). A simple model describing continuous α-recoil loss predicts that the 234U/238U and 230Th/238U ARs reach steady-state values ~ 2 Ma after calcrete formation. Potential effects of open-system behavior on 230Th/U ages and initial 234U/238U ARs for younger surface calcrete were estimated using data for old subsurface calcrete samples with the 234U loss and assuming that the total time of water-rock interaction is the only difference between these soils. The difference between the conventional closed-system and open-system ages may exceed errors of the calculated conventional ages for samples older than ~ 250 ka, but is negligible for younger soils.
Space orbits of collaboration. [international cooperation and the U.S.S.R. space program

NASA Technical Reports Server (NTRS)

Petrov, B.

1978-01-01

The U.S.S.R. cooperative space efforts with other Socialist countries dating back to 1957 are reviewed. The Interkosmos program, which is divided into three series of satellites (solar, ionospheric and magnetospheric), is discussed as well as the Prognoz, Kosmos, Soyuz, and Molniya spacecraft. Collaboration with France, India, Sweden, and the United States is mentioned.
Stalagmite carbon isotopes and dead carbon proportion (DCP) in a near-closed-system situation: An interplay between sulphuric and carbonic acid dissolution

NASA Astrophysics Data System (ADS)

Bajo, Petra; Borsato, Andrea; Drysdale, Russell; Hua, Quan; Frisia, Silvia; Zanchetta, Giovanni; Hellstrom, John; Woodhead, Jon

2017-08-01

In this study, the 'dead carbon proportion' (DCP) calculated from combined U-Th and radiocarbon analyses was used to explore the carbon isotope systematics in Corchia Cave (Italy) speleothems, using the example of stalagmite CC26 which grew during the last ∼12 ka. The DCP values in CC26 are among the highest ever recorded in a stalagmite, spanning the range 44.8-68.8%. A combination of almost closed-system conditions and sulphuric acid dissolution (SAD) are proposed as major drivers in producing such a high DCP with minor contribution from old organic matter from the deep vadose zone. The long-term decrease in both DCP and δ13C most likely reflects post-glacial soil recovery above the cave, with a progressive increase of soil CO2 contribution to the total dissolved inorganic carbon (DIC). Pronounced millennial-scale shifts in DCP and relatively small coeval but antipathetic changes in δ13C are modulated by the effects of hydrological variability on open and closed-system dissolution, SAD and prior calcite precipitation. Hence, the DCP in Corchia Cave speleothems represents an additional proxy for rainfall amount.
Major Mesoamerican droughts of the past millennium

NASA Astrophysics Data System (ADS)

Stahle, D. W.; Diaz, J. Villanueva; Burnette, D. J.; Paredes, J. Cerano; Heim, R. R., Jr.; Fye, F. K.; Acuna Soto, R.; Therrell, M. D.; Cleaveland, M. K.; Stahle, D. K.

2011-03-01

Ancient Montezuma baldcypress (Taxodium mucronatum) trees found in Barranca de Amealco, Queretaro, have been used to develop a 1,238-year tree-ring chronology that is correlated with precipitation, temperature, drought indices, and crop yields in central Mexico. This chronology has been used to reconstruct the spring-early summer soil moisture balance over the heartland of the Mesoamerican cultural province, and is the first exactly dated, annually resolved paleoclimatic record for Mesoamerica spanning the Late Classic, Post Classic, Colonial, and modern eras. The reconstruction indicates that the Terminal Classic drought extended into central Mexico, supporting other sedimentary and speleothem evidence for this early 10th century drought in Mesoamerica. The reconstruction also documents severe and sustained drought during the decline of the Toltec state (1149-1167) and during the Spanish conquest of the Aztec state (1514-1539), providing a new precisely dated climate framework for Mesoamerican cultural change.
Abrupt climate changes during Termination III in Southern Europe

PubMed Central

Pérez-Mejías, Carlos; Moreno, Ana; Sancho, Carlos; Bartolomé, Miguel; Stoll, Heather; Cacho, Isabel; Cheng, Hai; Edwards, R. Lawrence

2017-01-01

The Late Quaternary glacial–interglacial transitions represent the highest amplitude climate changes over the last million years. Unraveling the sequence of events and feedbacks at Termination III (T-III), including potential abrupt climate reversals similar to those of the last Termination, has been particularly challenging due to the scarcity of well-dated records worldwide. Here, we present speleothem data from southern Europe covering the interval from 262.7 to 217.9 kyBP, including the transition from marine isotope stage (MIS) 8 to MIS 7e. High-resolution δ13C, δ18O, and Mg/Ca profiles reveal major millennial-scale changes in aridity manifested in changing water availability and vegetation productivity. uranium–thorium dates provide a solid chronology for two millennial-scale events (S8.1 and S8.2) which, compared with the last two terminations, has some common features with Heinrich 1 and Heinrich 2 in Termination I (T-I). PMID:28874530
Abrupt climate changes during Termination III in Southern Europe.

PubMed

Pérez-Mejías, Carlos; Moreno, Ana; Sancho, Carlos; Bartolomé, Miguel; Stoll, Heather; Cacho, Isabel; Cheng, Hai; Edwards, R Lawrence

2017-09-19

The Late Quaternary glacial-interglacial transitions represent the highest amplitude climate changes over the last million years. Unraveling the sequence of events and feedbacks at Termination III (T-III), including potential abrupt climate reversals similar to those of the last Termination, has been particularly challenging due to the scarcity of well-dated records worldwide. Here, we present speleothem data from southern Europe covering the interval from 262.7 to 217.9 kyBP, including the transition from marine isotope stage (MIS) 8 to MIS 7e. High-resolution δ 13 C, δ 18 O, and Mg/Ca profiles reveal major millennial-scale changes in aridity manifested in changing water availability and vegetation productivity. uranium-thorium dates provide a solid chronology for two millennial-scale events (S8.1 and S8.2) which, compared with the last two terminations, has some common features with Heinrich 1 and Heinrich 2 in Termination I (T-I).
Abrupt climate changes during Termination III in Southern Europe

NASA Astrophysics Data System (ADS)

Pérez-Mejías, Carlos; Moreno, Ana; Sancho, Carlos; Bartolomé, Miguel; Stoll, Heather; Cacho, Isabel; Cheng, Hai; Edwards, R. Lawrence

2017-09-01

The Late Quaternary glacial-interglacial transitions represent the highest amplitude climate changes over the last million years. Unraveling the sequence of events and feedbacks at Termination III (T-III), including potential abrupt climate reversals similar to those of the last Termination, has been particularly challenging due to the scarcity of well-dated records worldwide. Here, we present speleothem data from southern Europe covering the interval from 262.7 to 217.9 kyBP, including the transition from marine isotope stage (MIS) 8 to MIS 7e. High-resolution δ13C, δ18O, and Mg/Ca profiles reveal major millennial-scale changes in aridity manifested in changing water availability and vegetation productivity. uranium-thorium dates provide a solid chronology for two millennial-scale events (S8.1 and S8.2) which, compared with the last two terminations, has some common features with Heinrich 1 and Heinrich 2 in Termination I (T-I).
U-Pb zircon geochronology of the Paleoproterozoic Tagragra de Tata inlier and its Neoproterozoic cover, western Anti-Atlas, Morocco

USGS Publications Warehouse

Walsh, G.J.; Aleinikoff, J.N.; Benziane, F.; Yazidi, A.; Armstrong, T.R.

2002-01-01

New U-Pb zircon data obtained by sensitive high resolution ion microprobe (SHRIMP) from the Tagragra de Tata inlier in the western Anti-Atlas, Morocco establish Paleoproterozoic ages for the basement schists, granites, and metadolerites, and a Neoproterozoic age for an ignimbrite of the Ouarzazate Series in the cover sequence. The age of interbedded felsic metatuff in the metasedimentary and metavolcanic sequence of the basement schists is 2072 ?? 8 Ma. This date represents: (1) the first reliable age from the metasedimentary and metavolcanic sequence; (2) the oldest reliable age for the basement of the Anti-Atlas; (3) the first date on the timing of deposition of the sediments on the northern edge of the Paleoproterozoic West African craton; (4) a lower age limit on deformation during the Eburnean orogeny; and (5) the first date obtained from the non-granitic Paleoproterozoic basement of Morocco. Ages of 2046 ?? 7 Ma (Targant granite) and 2041 ?? 6 Ma (Oudad granite) support earlier interpretations of a Paleoproterozoic Eburnean igneous event in the Anti-Atlas. The granites post-date the Eburnean D1 deformation event in the Paleoproterozoic schist sequence, and place a ???2046 Ma limit on short-lived Eburnean deformation in the area. Cross-cutting metadolerite is 2040 ?? 6 Ma; this is the first date from a metadolerite in the western Anti-Atlas. All of the dolerites in the area post-date emplacement of the two granites and the new age constrains the onset of late- or post-Eburnean extension. Ignimbrite of the Ouarzazate Series, immediately above the Paleoproterozoic basement is 565 ?? 7 Ma. This Neoproterozoic age agrees with ages of similar volcanic rocks elsewhere from the Ouarzazate Series. The date also agrees with the ages of associated hypabyssal intrusions, and marks the second and final stage of Pan-African orogenic activity in the western Anti-Atlas. ?? 2002 Elsevier Science B.V. All rights reserved.
Actinobacteria Isolated from an Underground Lake and Moonmilk Speleothem from the Biggest Conglomeratic Karstic Cave in Siberia as Sources of Novel Biologically Active Compounds

PubMed Central

Tokovenko, Bogdan T.; Protasov, Eugeniy S.; Gamaiunov, Stanislav V.; Rebets, Yuriy V.; Luzhetskyy, Andriy N.; Timofeyev, Maxim A.

2016-01-01

Actinobacteria isolated from unstudied ecosystems are one of the most interesting and promising sources of novel biologically active compounds. Cave ecosystems are unusual and rarely studied. Here, we report the isolation and characterization of ten new actinobacteria strains isolated from an ancient underground lake and moonmilk speleothem from the biggest conglomeratic karstic cave in Siberia with a focus on the biological activity of the obtained strains and the metabolite dereplication of one active strain. Streptomyces genera isolates from moonmilk speleothem demonstrated antibacterial and antifungal activities. Some of the strains were able to inhibit the growth of pathogenic Candida albicans. PMID:26901168
75 FR 3983 - Airworthiness Directives; Airbus Model A318 Series Airplanes

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-26

..., German, or EASA airworthiness certificate or the date of issuance of the original French, German, or EASA..., under the provisions of the Paperwork Reduction Act (44 U.S.C. 3501 et seq.), the Office of Management...

A MIS 9/MIS 8 speleothem record of hydrological variability from Macedonia (F.Y.R.O.M.)

NASA Astrophysics Data System (ADS)

Regattieri, Eleonora; Zanchetta, Giovanni; Isola, Ilaria; Bajo, Petra; Perchiazzi, Natale; Drysdale, Russell N.; Boschi, Chiara; Hellstrom, John C.; Francke, Alexander; Wagner, Bernd

2018-03-01

The period corresponding to Marine Isotope Stages 9 (MIS 9) offers the opportunity to study orbital and sub-orbital scale climate variability under boundary conditions different from those of better studied intervals such as the Holocene and the Last Interglacial. Yet, it is poorly represented in independently-dated continental archives around the Mediterranean Region. Here, we present a speleothem stable isotope record (δ18O and δ13C) from the Former Yugoslavian Republic of Macedonia (F.Y.R.O.M., southern Balkans), which consists of two periods of growth broadly covering the ca. 332 to 292 ka and the ca. 264 to 248 ka intervals (MIS 9e-b and late MIS 8). We interpret the speleothem δ18O as mostly related to regional hydrology, with variations that can be interpreted as due to changes in rainfall amount, with higher/lower values associated to drier/wetter condition. This interpretation is corroborated by a change in mineralogical composition between aragonite and calcite at ca. 328 ka, which marks increasing precipitation at the onset of MIS 9 and occurs within a trend of decreasing δ18O values. Also the comparison with the multiproxy climate record available from the nearby Lake Ohrid seems to support the proposed interpretation. The MIS 9e interglacial appears to be characterized by wettest conditions between ca. 326 and 321 ka, i.e. lasting ca. 5 kyr. Decreasing precipitation and enhanced millennial scale variability matches the glacial inception (MIS9 d to b), with drier events at ca. 319 ka (ca. 2 kyr long) and 310 ka (ca. 1 kyr long), and a major rainfall reduction between 306 and 298 ka. The latter is followed by a prominent wetter period between 298 and 295 ka, for which carbon data values suggest high infiltration rate. Rainfall decreases again after 295 ka, and remain low until the growth interruption at ca. 292 ka. Resumption of the growth and progressive soil development, expressed by the carbon isotope record, occurred during the late part of MIS 8. Despite the rather high temporal uncertainty (average 6 ka), the speleothem hydrological record complements the environmental information provided by the Lake Ohrid record and also fits well to the framework of regional and extra-regional variability, showing similarities with pollen records from southern and western Europe, both at orbital and at sub-orbital time scale.
Did the demise of Green Sahara play a role in the mid-to-late Holocene megadrought and `missing millennia' in southeast Asian societies?

NASA Astrophysics Data System (ADS)

Griffiths, M. L.; Johnson, K. R.; Pausata, F. S. R.; White, J.; Yang, H.; Henderson, G. M.; Conrad, C.

2017-12-01

The mid-to-late Holocene in eastern Africa and Eurasia was characterized by one of, if not the, largest climate anomalies of the past 10,000 years (i.e. the `4.2 ka event'), yet the cause of this event remains enigmatic. The nature and geographical extent of the event has been a topic of great interest because of its potential connections with societal upheavals in western Asia and northeastern Africa. However, while paleoclimate data from India and southern China show evidence for a large-scale megadrought during this period, there have hitherto been no high-resolution and well-dated records from mainland southeast Asia (MSEA) to document the regional footprint of this event. This is somewhat surprising given that this period also coincides with what has been termed the `missing millennia' in MSEA, which refers to the major gap in archeological evidence that may have some link with the broader Asian monsoon failure during this time. To help shed light on the potential connection between climate change and the missing millennia, we have compiled four new speleothem oxygen (δ18O) and carbon (δ13C) isotope records from Tham Doun Mai cave in northern Laos. The δ18O profiles show a general increasing trend through much of the Holocene which is interpreted to reflect an overall weakening of the Southeast Asian monsoon. This general trend is punctuated by a marked positive δ18O shift at 4-5 ka, signifying an overall reduction in monsoon strength that persisted until 3.5 ka. Interestingly, the onset of this anomaly coincides with the cessation in speleothem growth of three speleothems, and a 4 per mil increase in δ13C for the speleothem that continued to grow. We interpret this large and abrupt increase in δ13C to reflect enhanced CO2 degassing due to a much slower drip-rate (supported by a slower growth rate), and the hiatuses to reflect large groundwater deficits to those drip sites. The onset of this abrupt megadrought in northern Laos is consistent with abrupt cooling in the Indo-Pacific Warm Pool, and matches the timing of west African monsoon (WAM) failure. Using fully coupled ocean-atmosphere model simulations, we show that reduced vegetation and increased dust emissions (such as during the Green Sahara demise) cool the Indian Ocean and shift eastward the Walker circulation, causing a weakening of the Indian Summer Monsoon.
Methodology to assess water presence on speleothems during periods of low precipitation, with implications for recharge sources - Kartchner Caverns, Arizona

USGS Publications Warehouse

Blasch, Kyle W.

2011-01-01

Beginning in January 2005, recharge processes and the presence of water on speleothems were monitored in Kartchner Caverns during a 44-month period when annual rainfall rates were 6 to 18 percent below the long-term mean. Electrical-resistance sensors designed to detect the presence of water were used to identify ephemeral streamflow in the channels overlying the cave as well as the movement of water within the cave system. Direct infiltration of precipitation through overhead rocks provided consistent inflow to the cave, but precipitation rates and subsequent infiltration rates were reduced during the comparatively dry years. Ephemeral stream-channel recharge through autogenic and allogenic processes, the predominant recharge mechanism during wetter periods, was limited to two low-volume events. From visual observations, it appeared that recharge from channel infiltration was equal to or less than recharge from overhead infiltration. Electrical-resistance sensors were able to detect thin films of water on speleothems, including stalactites, ribbons, and stalagmites. These films of water were directly attributed to overhead infiltration of precipitation. Periods of low precipitation resulted in decreased speleothem wetness.
Air abrasion experiments in U-Pb dating of zircon

USGS Publications Warehouse

Goldich, S.S.; Fischer, L.B.

1986-01-01

Air abrasion of zircon grains can remove metamict material that has lost radiogenic Pb and zircon overgrowths that were added during younger events and thereby improve the precision of the age measurements and permit closer estimates of the original age. Age discordance that resulted from a single disturbance of the U-Pb isotopic decay systems, as had been demonstrated by T.E. Krogh, can be considerably reduced, and, under favorable conditions, the ages brought into concordancy. Two or more events complicate the U-Pb systematics, but a series of abrasion experiments can be helpful in deciphering the geologic history and in arriving at a useful interpretation of the probable times of origin and disturbances. In east-central Minnesota, U.S.A., Penokean tonalite gneiss is dated at 1869 ?? 5 Ma, and sheared granite gneiss is shown to have been a high-level granite intrusion at 1982 ?? 5 Ma in the McGrath Gneiss precursor. Tonalite gneiss and a mafic granodiorite in the Rainy Lake area, Ontario, Canada, are dated at 2736 ?? 16 and 2682 ?? 4 Ma, respectively. The tonalitic phase of the Morton Gneiss, southwestern Minnesota, is dated at 3662 ?? 42 Ma. ?? 1986.
The Pech-de-l'Azé I Neandertal child: ESR, uranium-series, and AMS 14C dating of its MTA type B context.

PubMed

Soressi, M; Jones, H L; Rink, W J; Maureille, B; Tillier, A-M

2007-04-01

The Pech-de-l'Azé I skull and mandible are included in the juvenile Neandertal remains from Europe. However, some preserved features in the cranial skeleton seem to distinguish the specimen from other Neandertal children. Unfortunately, the stratigraphic position and dating of this child has never been clear. Our recent work on unpublished archives show that the Pech-de-l'Azé I Neandertal child was discovered at the bottom of layer 6, attributed to the Mousterian of Acheulean tradition type B. These skull and mandible are the first diagnostic human remains (aside from an isolated tooth) attributed to the Mousterian of Acheulian tradition (MTA) type B. Consequently, we confirm that Neandertals were the makers of this Mousterian industry, which is characterized by unusual high frequencies of Upper Paleolithic type tools, elongated blanks and blades. We were able to date the context of the hominid remains by dating layer 6 and the layers above and beneath it using ESR, coupled ESR/(230)Th/(234)U (coupled ESR/U-series), and AMS (14)C. Coupled ESR/U-series results on 16 mammalian teeth constrain the age of the uppermost layer 7 to 41-58ka, and layer 6 to 37-51ka. The wide spread in each age estimate results mainly from uncertainties in the gamma-dose rate. These ages are concordant with AMS (14)C ages of two bones coming from the top of layer 6, which provide dates of about 41.7-43.6ka cal BP. A combination of stratigraphic arguments and dating results for layers 6 and 7 show that the Neandertal child cannot be older than 51ka or younger than 41ka. The lowermost layer 4 is shown to be older than 43ka by the principle of superposition and ESR dating in the immediately overlying layer 5. This study shows that the MTA type B had been manufactured by Neandertals before the arrival of anatomically modern humans in the local region. Additionally, by providing a firm chronological framework for the specific morphometric the features of Pech-de-l'Azé I Neandertal child, this study is a new step toward the understanding of temporal and spatial changes in the ontogenesis of Neandertals in south-western Europe during oxygen isotope stages 5-3.
The Glacial-Interglacial Monsoon Recorded by Speleothems from Sulawesi, Indonesia

NASA Astrophysics Data System (ADS)

Kimbrough, A. K.; Gagan, M. K.; Dunbar, G. B.; Krause, C.; Hantoro, W. S.; Cheng, H.; Edwards, R. L.; Shen, C. C.; Sun, H.; Cai, B.; Hellstrom, J. C.; Rifai, H.

2015-12-01

The Indo-Pacific Warm Pool is a primary source of heat and moisture to the global atmosphere and a key player in tropical and global climate variability. There is mounting evidence that atmospheric convection and oceanic processes in the tropics can modulate global climate on orbital and sub-orbital timescales. Glacial-interglacial cycles represent the largest natural climate changes over the last 800 kyr with each cycle terminated by rapid global warming and sea level rise. Our understanding of the role and response of tropical atmospheric convection during these periods of dramatic warming is limited. We present the first speleothem paleomonsoon record for southwest Sulawesi (5ºS, 119ºE), spanning two glacial-interglacial cycles, including glacial termination IV (~340 kyr BP) and both phases of termination III (~248 and ~220 kyr BP). This unique record is constructed from multiple stalagmites from two separate caves and is based on a multi-proxy approach (δ18O, δ13C, Mg/Ca, Sr/Ca) that provides insight into the mechanisms controlling Australian-Indonesian summer monsoon variability. Speleothem δ18O and trace element data indicate a rapid increase in rainfall at glacial terminations and wet interglacials. Terminations IV, III, and I are each characterized by an abrupt 3‰ decrease in δ18O. Variability in δ18O leading-in to glacial terminations is also similar, and corresponds to October insolation. Prior to deglaciation, there is a distinct shift to higher δ18O that is synchronized with weak monsoon intervals in Chinese speleothem records. The remarkably consistent pattern among terminations implies that the response of tropical convection to changing background climates is well regulated. Furthermore, we find that speleothem δ13C leads δ18O by ~5 kyr during glacial terminations. The early decrease in speleothem δ13C may reflect the response of tropical vegetation to rising atmospheric CO2 and temperature, rather than regional changes in rainfall.
Interpreting δ18O and δ13C of two co-eval calcite and aragonite speleothems supported by cave monitoring from Grotte de Piste, Morocco

NASA Astrophysics Data System (ADS)

Wassenburg, Jasper A.; Spoetl, Christoph; Cheng, Hai; Jochum, Klaus Peter; Niedermayr, Andrea; Richter, Detlev K.; Immenhauser, Adrian; Scholz, Denis

2016-04-01

Interpreting speleothem δ18O and δ13C records can be challenging. Although these proxies can be affected by various processes taking place within the cave environment, δ18O values commonly reflect local and regional atmospheric and hydrological processes, whereas δ13C values are rather controlled by local processes only, such as type of vegetation (C3 versus C4), soil CO2 production, cave air circulation, and drip rate. In order to relate speleothem stable isotope data to the exterior climate, monitoring of the local meteoric rainfall and drip water isotope composition, and temperature is necessary. In the case of δ18O values, it is important to assess whether the speleothem reflects the δ18O value of meteoric precipitation or whether there are significant isotope effects due to evapo-transpiration and/or other processes occurring within the karst environment. In addition, net infiltration is commonly restricted to a particular season, and speleothem growth may be seasonal. Hence speleothem δ18O values may be biased to a specific season. Here we present the results of two years (2011-2012) of monitoring of the δ18O values of spring water, meteoric rainfall and cave drip water in Grotte de Piste, NW Middle Atlas, Morocco. Watch glass experiments were performed at the monitored drip sites that correspond to an actively growing calcite stalagmite (GP7) and an actively growing aragonite stalagmite (GP5). This enabled us to assess the link between the δ18O values of the rainfall, the drip water, the associated CaCO3 precipitates and the stalagmite δ18O values of both polymorphs. In addition, δ18O and δ13C values of both stalagmites were analyzed at 5-year or higher resolution for the last 600 years. As expected, a systematic isotopic offset between the calcite and the aragonite stalagmite can be observed. This is approximately 0.86 ‰ for δ18O and 0.88 ‰ for δ13C. However, both stalagmites show similar trends in their δ18O and δ13C records, even though speleothem growth rates differ considerably. This replication test increases the confidence that these stalagmites recorded an environment signal.
Using the Geoscience Concept Inventory to Understand how Students Learn about Geologic Time

NASA Astrophysics Data System (ADS)

Teed, R. E.

2009-12-01

108 pre-service teachers completed a standardized multiple-choice test at the beginning and at the end of a ten-week introductory survey course on geology. Four of the fifteen questions dealt explicitly with geologic time. Correct student answers that the age of the Earth is known from uranium-series dating increased significantly, but only from ~0% to about 20%. However, answers that included U-series dating with other (irrelevant) sources of evidence increased from ~10% to ~70%. On the pre-test, students avoided the U-series dating in favor of incorrect, but probably more familiar, dating techniques or combinations of dating techniques. They seem to have gained familiarity with, if not an understanding of U-series dating in the class. There was no real change in students’ conceptions of what the newly-formed Earth would have looked like. Most (70% on pre-test, 65% on post-test) chose an image that looked like the modern Earth with a single continent (which they may have believed to be Pangea). Interestingly, 78% of those who chose that image on the pre-test chose it on the post-test, so they were not guessing. This is a powerful misconception and remained intact in most cases despite the work the students did in the geology class. On the other hand, most students appeared to be guessing when they answered how long Pangea took to break up. There were no significant changes in the totals for any response, but about half students changed their answers between the pre- and post-test with no significant pattern in the changes. Responses to a choice of timelines which all included the formation of the Earth, the appearances of life, dinosaurs, and humans, and the disappearance of dinosaurs, were more complex. There was an increase in the number of students who chose the correct timeline (from 20% to 42%), and a decrease in the number who chose a timeline in which all life appears at once (from 14% to 10%). In this case some misconceptions (based on incorrect answers on the pre-test) were more likely than others to grow into a correct understanding. For example, students who chose “C”, an incorrect timeline with events in the correct order but incorrectly scaled, on the pretest, were more likely to choose correctly on the post-test than students who gave other incorrect answers on the pre-test.
South America Monsoon variability on millennial to multi-centennial time scale during the Holocene in central eastern Brazil

NASA Astrophysics Data System (ADS)

Strikis, N. M.; Cruz, F. W.; Cheng, H.; Karmann, I.; Vuille, M.; Edwards, R.; Wang, X.; Paula, M. S.; Novello, V. F.; Auler, A.

2011-12-01

A paleoprecipitation reconstruction based on high resolution and well-dated speleothem oxygen isotope records shows that the monsoon precipitation over central eastern Brazil underwent to strong variations on millennial to multi-centennial time-scales during the Holocene. This new record indicates that abrupt events of increase in monsoon precipitation are correlated to Bond events 6, 5 and 4 and also with 8.2 ky event during the early and mid-Holocene, with a mean amplitude of 1.5 % (PDB). The pacing and structure of such events are general consistent with variations in solar activity suggested by atmospheric Δ14 C records. In the late-Holocene, abrupt events of increase in monsoon precipitation peaking at 3.2, 2.7 and 2.3 ky B.P. are approximately synchronous with periods of low solar minima. In this regard, the most prominent event occurred during the late Holocene occurred at ~2.7 ky B.P. In addition, these positive anomalies of the precipitation recorded in central eastern Brazil are also in good agreement with variations in Titicaca lake level. The good correspondence between the speleothem and marine records imply that the variations in the north Atlantic sea surface temperature is the main forcing for abrupt millennial to multi-centennial precipitations variation within the region under influence of South American Monsoon.
Exploring Holocene climate fluctuations registered in Bosnian stalagmites adopting a multiproxy approach

NASA Astrophysics Data System (ADS)

Chiarini, Veronica; Couchoud, Isabelle; Drysdale, Russell; Bajo, Petra; Milanolo, Simone; Hellstrom, John; De Waele, Jo

2016-04-01

The central Mediterranean area, a crucial region for present day and future climate change, has been characterised by contrasting patterns between northern and southern climate influences over the Holocene (e.g. Magny et al., 2012; Peyron et al., 2013). Several records from the Italian Peninsula identify this phenomenon: relatively dry conditions experienced during the first half of the Holocene are followed by an increase in moisture in the northern regions, while in the southern portion of the Peninsula the opposite trend occurs. On the Balkan side of the Adriatic Sea, this contrasting pattern is less well documented. The available studies focused on lake sediments show a more gradual and less warm early Holocene and more stable conditions during the early-mid Holocene compared to Italy (Bordon et al., 2009; Vogel et al., 2010). Several speleothems have been collected from Banja Stijena and Govještica Caves (Bosnia and Herzegovina). Preliminary U-Th dating allowed to choose the five most promising samples for further study. Stable oxygen and carbon isotopes have been analysed along the stalagmite growth axes and trace elements of one sample have been investigated. Air-mass back-trajectory analyses of present day precipitation in the area have been performed in association with GNIP rainfall isotope data analyses, with the aim of understanding the parameters driving rainfall stable oxygen isotope composition variations. Considering the impossibility of having a detailed monitoring of cave conditions due to the practical difficulties of identifying the original location of the samples collected, petrographic observations have been coupled with δ13C and δ18O in order to improve the understanding of the environmental processes recorded by these samples, as suggested in Frisia (2015) and Borsato et al. (2015). Here we will present the results of these multiproxy analyses, exploring the potential of these samples in recording regional climate fluctuations and discussing their implications for a better understanding of Holocene climate dynamics in the Balkans. References Bordon A. et al. (2009). Pollen-inferred Late-Glacial and Holocene climate in southern Balkans (Lake Maliq). Quat. Int. 200, 19-30. Borsato A. et al. (2015). Carbon dioxide concentration in temperate climate caves and parent soils over an altitudinal gradient and its influence on speleothem growth and fabrics. Earth Surf. Process. Landforms 40(9), 1158-1170. Frisia S. (2015). Microstratigrahic logging of calcite fabrics in speleothems as tool for palaeoclimate studies. Int. J. Spel. 44(1), 1-16. Magny M. et al. (2012). Contrasting patterns of precipitation seasonality during the Holocene in the south- and north-central Mediterranean. J. Quat. Sci. 27, 290-296. Peyron O. et al. (2013). Contrasting patters of climatic changes during the Holocene across the Italian Peninsula reconstructed from pollen data. Clim. Past 9, 1233-1252. Vogel H. et al. (2010). A paleoclimate record with tephrochronological age control for the last glacial-interglacial cycle from Lake Ohrid, Albania and Macedonia. J. Paleolimnol. 44, 295-310.
Discussion of “Deglacial paleoclimate in the southwestern United States: an abrupt 18.6 cold event and evidence for a North Atlantic forcing of Termination I” by M.S. Lachniet, Y. Asmerom and V. Polyak

USGS Publications Warehouse

Winograd, Isaac J.

2012-01-01

Utilizing a stable isotopic time series obtained from a speleothem (PC-1), which grew between 20.1 and 15.6 ka, Lachniet, Asmeron and Polyak (2011; hereafter LAP) present evidence for a significant cold event in the southern Great Basin at 18.6 ka, a finding that we accept. Supplementing this short record with a literature review, they go on to claim, as their central thesis, that the paleoclimate of the southwestern US was driven by “the transmission of atmospheric anomalies to the southwest…that coincided with deglacial climate changes in Greenland and the North Atlantic region”, not by a “dominant Pacific Ocean SST control” as suggested by SST time series off California and by the Devils Hole δ18O time series from the southern Great Basin. We do not find their central thesis supportable.
Palaeoclimate significance of speleothems in crystalline rocks: a test case from the Late Glacial and early Holocene (Vinschgau, northern Italy)

NASA Astrophysics Data System (ADS)

Koltai, Gabriella; Cheng, Hai; Spötl, Christoph

2018-03-01

Partly coeval flowstones formed in fractured gneiss and schist were studied to test the palaeoclimate significance of this new type of speleothem archive on a decadal-to-millennial timescale. The samples encompass a few hundred to a few thousand years of the Late Glacial and the early Holocene. The speleothem fabric is primarily comprised of columnar fascicular optic calcite and acicular aragonite, both indicative of elevated Mg / Ca ratios in the groundwater. Stable isotopes suggest that aragonite is more prone to disequilibrium isotope fractionation driven by evaporation and prior calcite/aragonite precipitation than calcite. Changes in mineralogy are therefore attributed to these two internal fracture processes rather than to palaeoclimate. Flowstones formed in the same fracture show similar δ18O changes on centennial scales, which broadly correspond to regional lacustrine δ18O records, suggesting that such speleothems may provide an opportunity to investigate past climate conditions in non-karstic areas. The shortness of overlapping periods in flowstone growth and the complexity of in-aquifer processes, however, render the establishment of a robust stacked δ18O record challenging.
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Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-02

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Assessing modern climatic controls on southern Sierra Nevada precipitation and speleothem δ18O

NASA Astrophysics Data System (ADS)

McCabe-Glynn, S. E.; Johnson, K. R.; Berkelhammer, M. B.

2012-12-01

Precipitation in the southwestern United States (SW US) is highly seasonal and exhibits inter-annual to inter-decadal variability. A 1154-year δ18O time series obtained from a southwestern Sierra Nevada Mountain stalagmite from Crystal Cave, CRC-3, (36.58°N; 118.56°W; 1540 m) reveals substantial decadal to multi-decadal variability closely linked to the Pacific Decadal Oscillation (PDO), and more specifically, to sea surface temperatures (SSTs) in the Kuroshio Extension region, which impact the atmospheric trajectory and isotopic composition of moisture reaching the study site. The instrumental portion of the CRC-3 δ18O time series suggests that more negative precipitation δ18O values are delivered from higher latitudes during positive phases of the PDO and/or when SSTs in the Kuroshio Extension region are anomalously cool, such as during La Niña events. In order to improve our understanding of the controls on speleothem δ18O in this region, we have conducted a detailed modern study of the climate, hydrology, and stable isotopic composition of meteoric waters (precipitation and drip water) at the cave. Here we present Crystal Cave drip logger results from 2010 to 2012, the isotopic composition of North American Deposition Program precipitation samples collected from 2001 to 2012 from several locations near our site including Ash Mountain (ASM), Sequoia National Park-Giant Forest (Ca75), and Yosemite National Park (Ca99), and isotopic composition of cave drip water and glass plate calcite. We also compare the δ18O values in the precipitation to satellite imagery, NCAR/NCEP data, and NOAA Hysplit Model backward trajectories between the sites. Results indicate that this site is particularly sensitive to "Pineapple Express" type storms, a persistent flow of atmospheric moisture and heavy rainfall extending from near the Hawaiian Islands to the coast of North America, which average about twice as much precipitation as other storms in the Sierra Nevada during winter. Crystal Cave drip logger results indicate a low drip rate variability in the cave between July 2010 and July 2011, averaging between ~25 drips/hour but we observe a significant increase during three "Pineapple Express" type storms (PE) during the 2010-2011 winter. Analysis of the δ18O of precipitation samples collected during these storms events exhibit significantly more negative values which could complicate the interpretation of speleothem δ18O if the relative contribution of PE moisture varies on interannual to multi-decadal timescales.
Datation U_Pb : âge de mise en place du magmatisme bimodal des Jebilet centrales (chaîne Varisque, Maroc). Implications géodynamiquesU_Pb dating: emplacement age of the bimodal magmatism of central Jebilet (Variscan Belt, Morocco). Geodynamic implications

NASA Astrophysics Data System (ADS)

Essaifi, Abderrahim; Potrel, Alain; Capdevila, Ramon; Lagarde, Jean-Louis

2003-01-01

The bimodal magmatism of central Jebilet is dated to 330.5 +0.68-0.83 Ma by UPb dating on zircons. This age, similar to that of the syntectonic Jebilet cordierite-bearing granitoids, corresponds to the age of the local major tectonometamorphic event. The syntectonic plutonism of the Jebilet massif, composed of tholeiitic, alkaline, and peraluminous calc-alkaline series, is variegated. Magmas emplacement was favoured by the local extension induced by the motion along the western boundary of the Carboniferous basins of the Moroccan Meseta. The Jebilet massif exemplifies the activation of various magmas sources during an episode of continental convergence and crustal wrenching.
Late Holocene climate and environmental change from Asiul cave speleothems: interpretations in light of modern cave monitoring.

NASA Astrophysics Data System (ADS)

Smith, Andrew; Wynn, Peter; Barker, Philip; Leng, Melanie; Noble, Steve; Tych, Wlodek

2017-04-01

Northern Iberia offers an excellent location to study fluctuations in North Atlantic Ocean (NA) conditions and the impact that changes in the NA have on atmospheric systems, which dominate Europe's climate. Two speleothems from Cueva de Asiul (Matienzo, N. Spain) have been used to reconstruct rainfall variability in N. Spain throughout the Holocene (Smith et al., 2016a). The carbonate δ18O records from these speleothems are interpreted in the light of a rigorous modern cave monitoring program undertaken at Cueva de Asiul (Smith et al., 2016b). Drip water δ18O reflects a modern rainfall amount effect whilst δ13C appears influenced by Prior Calcite Precipitation (PCP) in the short term and changes in vegetation at long timescales. The speleothem δ18O shows that long duration ( 1500 year) cycles in wetting and drying are prevalent in N. Spain during the Holocene and that dry climate phases are related to the timing of cold events (Bond et al., 2001) in the NA. Here we look in more detail at one of these speleothems, assessing both δ18O and δ13C during the last two thousand years. We show that Cueva de Asiul speleothems not only preserve long duration climate cycles in δ18O, but that they also appear influenced by shorter duration changes in the North Atlantic Oscillation (NAO), in-sync with other NAO archives (Olsen et al., 2012). However, the Cueva de Asiul record does not appear to preserve a predominately positive NAO signal during the Medieval Climate Anomaly (MCA) as is common within many European archives (Trouet et al., 2009), possibly due to the sites' close proximity to the NA and localised oceanic weather systems (Moreno et al., 2012). Alongside climatic changes, the speleothem δ13C shows a clear transition toward higher isotope values around 360 years BP (BP=1950), signalling a major environmental change in the region possibly due to anthropogenic removal of vast swathes of natural forest to support ship building and industry related to the Spanish Armada. Bond et al., (2001), Science 294, 2130-2136. Moreno et al., (2012), Quat. Sci. Rev. 43, 16-32. Olsen et al., (2012), Nat. Geosci. 5, 1-14. Smith et al., (2016a), Sci. Reports.6:24745. Smith et al., (2016b) Int. J. Speleol. 45, 1-9. Trouet et al., (2009), Science 324, 78-80.
1,500 Year Periodicity in Central Texas Moisture Source Variability Reconstructed from Speleothems

NASA Astrophysics Data System (ADS)

Wong, C. I.; James, E. W.; Silver, M. M.; Banner, J. L.; Musgrove, M.

2014-12-01

Delineating the climate processes governing precipitation variability in drought-prone Texas is critical for predicting and mitigating climate change effects, and requires the reconstruction of past climate beyond the instrumental record. Presently, there are few high-resolution Holocene climate records for this region, which limits the assessment of precipitation variability during a relatively stable climatic interval that comprises the closest analogue to the modern climate state. To address this, we present speleothem growth rate and δ18O records from two central Texas caves that span the mid to late Holocene, and assess hypotheses about the climate processes that can account for similarity in the timing and periodicity of variability with other regional and global records. A key finding is the independent variation of speleothem growth rate and δ18O values, suggesting the decoupling of moisture amount and source. This decoupling likely occurs because i) the often direct relation between speleothem growth rate and moisture availability is complicated by changes in the overlying ecosystem that affect subsurface CO2 production, and ii) speleothem δ18O variations reflect changes in moisture source (i.e., proportion of Pacific- vs. Gulf of Mexico-derived moisture) that appear not to be linked to moisture amount. Furthermore, we document a 1,500-year periodicity in δ18O values that is consistent with variability in the percent of hematite-stained grains in North Atlantic sediments, North Pacific SSTs, and El Nino events preserved in an Ecuadorian lake. Previous modeling experiments and analysis of observational data delineate the coupled atmospheric-ocean processes that can account for the coincidence of such variability in climate archives across the northern hemisphere. Reduction of the thermohaline circulation results in North Atlantic cooling, which translates to cooler North Pacific SSTs. The resulting reduction of the meridional SST gradient in the Pacific weakens the air-sea coupling that modulates ENSO activity, resulting in faster growth of interannual anomalies and larger mature El Niño relative to La Niña events. The asymmetrically enhanced ENSO variability can account for a greater portion of Pacific-derived moisture reflected by speleothem δ18O values.
Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

NASA Astrophysics Data System (ADS)

Ludwig, K. R.; Paces, J. B.

2002-02-01

A 230Th-234U-238U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the 232Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for 230Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the 230Th/U ages were preserved in all cases; (2) back-calculated initial 234U/238U fall in a restricted range (typically 1.67±0.19), so that 234U/238U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt 230Th/U ages. We conclude that 230Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of 238U/232Th, or isochrons.
Transformation-cost time-series method for analyzing irregularly sampled data

NASA Astrophysics Data System (ADS)

Ozken, Ibrahim; Eroglu, Deniz; Stemler, Thomas; Marwan, Norbert; Bagci, G. Baris; Kurths, Jürgen

2015-06-01

Irregular sampling of data sets is one of the challenges often encountered in time-series analysis, since traditional methods cannot be applied and the frequently used interpolation approach can corrupt the data and bias the subsequence analysis. Here we present the TrAnsformation-Cost Time-Series (TACTS) method, which allows us to analyze irregularly sampled data sets without degenerating the quality of the data set. Instead of using interpolation we consider time-series segments and determine how close they are to each other by determining the cost needed to transform one segment into the following one. Using a limited set of operations—with associated costs—to transform the time series segments, we determine a new time series, that is our transformation-cost time series. This cost time series is regularly sampled and can be analyzed using standard methods. While our main interest is the analysis of paleoclimate data, we develop our method using numerical examples like the logistic map and the Rössler oscillator. The numerical data allows us to test the stability of our method against noise and for different irregular samplings. In addition we provide guidance on how to choose the associated costs based on the time series at hand. The usefulness of the TACTS method is demonstrated using speleothem data from the Secret Cave in Borneo that is a good proxy for paleoclimatic variability in the monsoon activity around the maritime continent.
Transformation-cost time-series method for analyzing irregularly sampled data.

PubMed

Ozken, Ibrahim; Eroglu, Deniz; Stemler, Thomas; Marwan, Norbert; Bagci, G Baris; Kurths, Jürgen

2015-06-01

Irregular sampling of data sets is one of the challenges often encountered in time-series analysis, since traditional methods cannot be applied and the frequently used interpolation approach can corrupt the data and bias the subsequence analysis. Here we present the TrAnsformation-Cost Time-Series (TACTS) method, which allows us to analyze irregularly sampled data sets without degenerating the quality of the data set. Instead of using interpolation we consider time-series segments and determine how close they are to each other by determining the cost needed to transform one segment into the following one. Using a limited set of operations-with associated costs-to transform the time series segments, we determine a new time series, that is our transformation-cost time series. This cost time series is regularly sampled and can be analyzed using standard methods. While our main interest is the analysis of paleoclimate data, we develop our method using numerical examples like the logistic map and the Rössler oscillator. The numerical data allows us to test the stability of our method against noise and for different irregular samplings. In addition we provide guidance on how to choose the associated costs based on the time series at hand. The usefulness of the TACTS method is demonstrated using speleothem data from the Secret Cave in Borneo that is a good proxy for paleoclimatic variability in the monsoon activity around the maritime continent.

An optimized multi-proxy, multi-site Antarctic ice and gas orbital chronology (AICC2012): 120-800 ka

NASA Astrophysics Data System (ADS)

Bazin, L.; Landais, A.; Lemieux-Dudon, B.; Toyé Mahamadou Kele, H.; Veres, D.; Parrenin, F.; Martinerie, P.; Ritz, C.; Capron, E.; Lipenkov, V.; Loutre, M.-F.; Raynaud, D.; Vinther, B.; Svensson, A.; Rasmussen, S. O.; Severi, M.; Blunier, T.; Leuenberger, M.; Fischer, H.; Masson-Delmotte, V.; Chappellaz, J.; Wolff, E.

2013-08-01

An accurate and coherent chronological framework is essential for the interpretation of climatic and environmental records obtained from deep polar ice cores. Until now, one common ice core age scale had been developed based on an inverse dating method (Datice), combining glaciological modelling with absolute and stratigraphic markers between 4 ice cores covering the last 50 ka (thousands of years before present) (Lemieux-Dudon et al., 2010). In this paper, together with the companion paper of Veres et al. (2013), we present an extension of this work back to 800 ka for the NGRIP, TALDICE, EDML, Vostok and EDC ice cores using an improved version of the Datice tool. The AICC2012 (Antarctic Ice Core Chronology 2012) chronology includes numerous new gas and ice stratigraphic links as well as improved evaluation of background and associated variance scenarios. This paper concentrates on the long timescales between 120-800 ka. In this framework, new measurements of δ18Oatm over Marine Isotope Stage (MIS) 11-12 on EDC and a complete δ18Oatm record of the TALDICE ice cores permit us to derive additional orbital gas age constraints. The coherency of the different orbitally deduced ages (from δ18Oatm, δO2/N2 and air content) has been verified before implementation in AICC2012. The new chronology is now independent of other archives and shows only small differences, most of the time within the original uncertainty range calculated by Datice, when compared with the previous ice core reference age scale EDC3, the Dome F chronology, or using a comparison between speleothems and methane. For instance, the largest deviation between AICC2012 and EDC3 (5.4 ka) is obtained around MIS 12. Despite significant modifications of the chronological constraints around MIS 5, now independent of speleothem records in AICC2012, the date of Termination II is very close to the EDC3 one.
Analytical pyrolysis and stable isotope analyses reveal past environmental changes in coralloid speleothems from Easter Island (Chile).

PubMed

Miller, Ana Z; De la Rosa, José M; Jiménez-Morillo, Nicasio T; Pereira, Manuel F C; González-Pérez, José A; Calaforra, José M; Saiz-Jimenez, Cesareo

2016-08-26

This study comprises an innovative approach based on the combination of chromatography (analytical pyrolysis and pyrolysis compound-specific isotope analysis (Py-CSIA)), light stable isotopes, microscopy and mineralogy analyses to characterize the internal layering of coralloid speleothems from the Ana Heva lava tube in Easter Island (Chile). This multidisciplinary proxy showed that the speleothems consist of banded siliceous materials of low crystallinity with different mineralogical compositions and a significant contribution of organic carbon. Opal-A constitutes the outermost grey layer of the coralloids, whereas calcite and amorphous Mg hydrate silicate are the major components of the inner whitish and honey-brown layers, respectively. The differences found in the mineralogical, elemental, molecular and isotopic composition of these distinct coloured layers are related to environmental changes during speleothem development. Stable isotopes and analytical pyrolysis suggested alterations in the water regime, pointing to wetter conditions during the formation of the Ca-rich layer and a possible increase in the amount of water dripping into the cave. The trend observed for δ(15)N values suggested an increase in the average temperature over time, which is consistent with the so-called climate warming during the Holocene. The pyrolysis compound-specific isotope analysis of each speleothem layer showed a similar trend with the bulk δ(13)C values pointing to the appropriateness of direct Py-CSIA in paleoenvironmental studies. The δ(13)C values for n-alkanes reinforced the occurrence of a drastic environmental change, indicating that the outermost Opal layer was developed under drier and more arid environmental conditions. Copyright © 2016 Elsevier B.V. All rights reserved.
Making a living while starving in the dark: metagenomic insights into the energy dynamics of a carbonate cave.

PubMed

Ortiz, Marianyoly; Legatzki, Antje; Neilson, Julia W; Fryslie, Brandon; Nelson, William M; Wing, Rod A; Soderlund, Carol A; Pryor, Barry M; Maier, Raina M

2014-02-01

Carbonate caves represent subterranean ecosystems that are largely devoid of phototrophic primary production. In semiarid and arid regions, allochthonous organic carbon inputs entering caves with vadose-zone drip water are minimal, creating highly oligotrophic conditions; however, past research indicates that carbonate speleothem surfaces in these caves support diverse, predominantly heterotrophic prokaryotic communities. The current study applied a metagenomic approach to elucidate the community structure and potential energy dynamics of microbial communities, colonizing speleothem surfaces in Kartchner Caverns, a carbonate cave in semiarid, southeastern Arizona, USA. Manual inspection of a speleothem metagenome revealed a community genetically adapted to low-nutrient conditions with indications that a nitrogen-based primary production strategy is probable, including contributions from both Archaea and Bacteria. Genes for all six known CO2-fixation pathways were detected in the metagenome and RuBisCo genes representative of the Calvin-Benson-Bassham cycle were over-represented in Kartchner speleothem metagenomes relative to bulk soil, rhizosphere soil and deep-ocean communities. Intriguingly, quantitative PCR found Archaea to be significantly more abundant in the cave communities than in soils above the cave. MEtaGenome ANalyzer (MEGAN) analysis of speleothem metagenome sequence reads found Thaumarchaeota to be the third most abundant phylum in the community, and identified taxonomic associations to this phylum for indicator genes representative of multiple CO2-fixation pathways. The results revealed that this oligotrophic subterranean environment supports a unique chemoautotrophic microbial community with potentially novel nutrient cycling strategies. These strategies may provide key insights into other ecosystems dominated by oligotrophy, including aphotic subsurface soils or aquifers and photic systems such as arid deserts.
Comparison of speleothem δ 18O records from eastern China with solar insolation, ice core and marine records: Similarities and discrepancies on different time scales

NASA Astrophysics Data System (ADS)

Wan, Naijung; Chung, Weiling; Li, Hong-Chun; Lin, Huilin; Ku, Teh-Lung; Shen, Chuan-Chou; Yuan, Daoxian; Zhang, Meiliang; Lin, Yushi

2011-04-01

Four 230Th-dated δ 18O records in three stalagmites: one from Dragon Spring (stalagmite L12) and two from Golden Lion Caves (stalagmites JSD-01 and JSD-02) located in Libo County, southeast Guizhou, China, are presented. These records cover age ranges of 0.75-2 ka (late Holocene), 9-9.6 ka (early Holocene), 87.9-88.2 ka and 93.8-95.2 ka (late Pleistocene). They fit well with the published Dongge Cave record from the same area, where the climate has been much influenced by the East Asian Monsoon. The agreement reinforces the role of stalagmite δ 18O as a proxy for regional precipitation or monsoon strength. On millennial or longer time scales, the δ 18O record of Dongge Cave resembles those of Sanbao Cave in Hubei and Hulu Cave in Jiangsu of China. The matching of these records with the northern hemisphere solar-insolation variations points to the importance of insolation in affecting the East Asian Summer Monsoon strength on 10 3-10 4-yr scales. While the monsoon variations as depicted by these Chinese speleothem δ 18O records show a strong coupling to insolation's precession component (23-kyr period), other climate records of global significance extracted from oceanic and terrestrial deposits (e.g., deep-sea sediments, polar ice cores, cave deposits from non-monsoonal regions) do not. Although the latter records were thought to be also influenced by the large changes in global ice volume, they show variations modulated chiefly by insolation due to earth's eccentricity change (100-kyr period). It is hypothesized that precession variations control the distribution of solar insolation between the northern and southern hemispheres, the ITCZ position and the modulation of low-latitude summer monsoon variability. Increasing rainfall and/or summer/winter precipitation ratio brought about by strong summer monsoons leads to δ 18O depletion in stalagmites grown in monsoonal regions. One should use caution to compare speleothem δ 18O records with other paleoclimate records reflecting Pleistocene ice ages on 10 4-10 5-yr timescales.
A speleothem record of South Pacific Convergence Zone dynamics during MIS 3 - Evidence for non-stationary coupling between the southern tropical Pacific and Greenland?

NASA Astrophysics Data System (ADS)

Sinclair, D. J.; Sherrell, R. M.; Rowe, H. D.; Wright, J. D.; Mortlock, R. A.; Hellstrom, J. C.; Cheng, H.; Min, A.; Edwards, R. L.

2014-12-01

The South Pacific Convergence Zone (SPCZ) is the largest component of the Intertropical Convergence Zone (ITCZ), and its impact on global climate rivals that of the deep convection at the heart of the Western Pacific Warm Pool. Rapid glacial climate fluctuations, such as Dansgaard-Oeschger (D-O) Events, would have triggered a reorganization of tropical systems such as the SPCZ, manifesting as significantly altered rainfall across the tropical south Pacific. However, a critical lack of high-resolution glacial records from this region means the dynamics of the SPCZ are largely unknown. We present a decade-resolution, absolute-dated speleothem rainfall record from the Island of Niue in the southern Tropical Pacific spanning 25-45 ka. Sr, Mg, δ18O and δ13C variations show that Niue experienced large, rapid fluctuations in rainfall lasting up to 1200 years. Between 40 and 45 ka, these show a remarkable concordance with the timing, duration and shape of D-O events 9-11. Rapid warming in Greenland was accompanied by a sudden increase in rainfall in Niue, implying that the SPCZ was strongly coupled with climate in the high Northern latitudes. These changes are not consistent with a wholesale northward shift in the SPCZ, which would have resulted in drying in Niue, and instead imply that the SPCZ underwent a more complex reorganization, perhaps rotating around its western edge in a manner analogous to modern-day extreme ENSO events. The speleothem record between 25-40 ka also shows large changes in rainfall, with D-O events identifiable. However, these changes are less well matched to Greenland, and include events not captured by the ice cores. It is clear that the SPCZ response to global climate change is complex: while it can closely couple with high-northern latitude climate for periods, this coupling may not be stationary with time. We speculate that this might result from changing precession, influencing which teleconnections dominate climate changes in the south tropical Pacific.
Regional influence of decadal to multidecadal Atlantic Oscillations during the last two millennia in Morocco, inferred from two high resolution δ18O speleothem records

NASA Astrophysics Data System (ADS)

Ait Brahim, Yassine; Sifeddine, Abdelfettah; Khodri, Myriam; Bouchaou, Lhoussaine; Cruz, Francisco W.; Pérez-Zanón, Núria; Wassenburg, Jasper A.; Cheng, Hai

2017-04-01

Climate projections predict substantial increase of extreme heats and drought occurrences during the coming decades in Morocco. It is however not clear what can be attributed to natural climate variability and to anthropogenic forcing, as hydroclimate variations observed in areas such as Morocco are highly influenced by the Atlantic climate modes. Since observational data sets are too short to resolve properly natural modes of variability acting on decadal to multidecadal timescales, high resolution paleoclimate reconstructions are the only alternative to reconstruct climate variability in the remote past. Herein, we present two high resolution and well dated speleothems oxygen isotope (δ18O) records sampled from Chaara and Ifoulki caves (located in Northeastern and Southwestern Morocco respectively) to investigate hydroclimate variations during the last 2000 years. Our results are supported by a monitoring network of δ18O in precipitation from 17 stations in Morocco. The new paleoclimate records are discussed in the light of existing continental and marine paleoclimate proxies in Morocco to identify significant correlations at various lead times with the main reconstructed oceanic and atmospheric variability modes and possible climate teleconnections that have potentially influenced the climate during the last two millennia in Morocco. The results reveal substantial decadal to multidecadal swings between dry and humid periods, consistent with regional paleorecords. Evidence of dry conditions exist during the Medieval Climate Anomaly (MCA) period and the Climate Warm Period (CWP) and humid conditions during the Little Ice Age (LIA) period. Statistical analyses suggest that the climate of southwestern Morocco remained under the combined influence of both the Atlantic Multidecadal Oscillation (AMO) and the North Atlantic Oscillation (NAO) over the last two millennia. Interestingly, the generally warmer MCA and colder LIA at longer multidecadal timescales probably influenced the regional climate in North Africa through the influence on Sahara Low which weakened and strengthened the mean moisture inflow from the Atlantic Ocean during the MCA and LIA respectively. Keywords: Speleothems, δ18O, Morocco, Hydroclimate, AMO, NAO.
U-series dating of Paleolithic art in 11 caves in Spain.

PubMed

Pike, A W G; Hoffmann, D L; García-Diez, M; Pettitt, P B; Alcolea, J; De Balbín, R; González-Sainz, C; de las Heras, C; Lasheras, J A; Montes, R; Zilhão, J

2012-06-15

Paleolithic cave art is an exceptional archive of early human symbolic behavior, but because obtaining reliable dates has been difficult, its chronology is still poorly understood after more than a century of study. We present uranium-series disequilibrium dates of calcite deposits overlying or underlying art found in 11 caves, including the United Nations Educational, Scientific, and Cultural Organization (UNESCO) World Heritage sites of Altamira, El Castillo, and Tito Bustillo, Spain. The results demonstrate that the tradition of decorating caves extends back at least to the Early Aurignacian period, with minimum ages of 40.8 thousand years for a red disk, 37.3 thousand years for a hand stencil, and 35.6 thousand years for a claviform-like symbol. These minimum ages reveal either that cave art was a part of the cultural repertoire of the first anatomically modern humans in Europe or that perhaps Neandertals also engaged in painting caves.
Similar speleothem δ18O signals indicating diverging climate variations in inland central Asia and monsoonal south Asia during the Holocene

NASA Astrophysics Data System (ADS)

Jin, Liya; Zhang, Xiaojian

2017-04-01

High-resolution and precisely dated speleothem oxygen isotope (δ18O) records from Asia have provided key evidence for past monsoonal changes. It is found that δ18O records of stalagmites from Kesang Cave (42°52'N, 81°45'E, Xinjiang, China) in inland central Asia were very similar to those from Qunf Cave (17°10'N, 54°18'E, southern Oman) in South Asia, shifting from light to heavy throughout the Holocene, which was regarded as a signal that strong Asian summer monsoon (ASM) may have intruded into the Kesang Cave site and/or adjacent areas in inland central Asia to produce heavy rainfall during the high insolation times (e.g. the early Holocene). However, this is in contrast to conclusions based on other Holocene proxy records and modeling simulations, showing a persistent wetting trend in arid central Asia during the Holocene with a dryer condition in the early Holocene and the wettest condition in the late Holocene. With an analysis of model-proxy data comparison, we revealed a possible physical mechanism responsible for the Holocene evolution of moisture/precipitation in Asian summer monsoon (ASM)-dominated regions and that in the inland central Asia. It is revealed that a recurrent circumglobal teleconnection (CGT) pattern in the summertime mid-latitude circulation of the Northern Hemisphere was closely related to the ASM and the climate of inland central Asia, acting as a bridge linking the ASM to insolation, high-latitude forcing (North Atlantic sea surface temperature (SST)), and low-latitude forcing (tropical Ocean SST). Also, the CGT influence speleothem δ18O values in South Asia via its effect on the amount of precipitation. In addition, the moisture source from the Indian Ocean is associated with relatively high δ18O values compared with that from the North Atlantic Ocean, leading to increased precipitation δ18O values. Hence, the CGT has probably been the key factor responsible for the in-phase relationship in speleothem δ18O values (Kesang Cave and Qunf Cave), but out-of-phase relationship in moisture/precipitation evolutions between inland central Asia and the ASM region during the Holocene. In addition, since boreal winter (December-January-February, DJF) precipitation in northwestern China (a part of the core zone in inland central Asia) during the Holocene has been revealed to contribute a great deal to moisture evolution in inland central Asia, and the changes in the seasonal cycle of incoming solar radiation driven by Earth's orbital changes have probably played an important role in the out-of-phase relationship in the moisture evolution between the inland central Asia and ASM regions during the Holocene.
Weathering processes and dating of soil profiles from São Paulo State, Brazil, by U-isotopes disequilibria.

PubMed

Bonotto, Daniel Marcos; Jiménez-Rueda, Jairo Roberto; Fagundes, Isabella Cruz; Filho, Carlos Roberto Alves Fonseca

2017-01-01

This study reports the use of the U-series radionuclides 238 U and 234 U for dating two soil profiles. The soil horizons developed over sandstones from Tatuí and Pirambóia formations at the Paraná sedimentary basin, São Paulo State, Brazil. Chemical data in conjunction with the 234 U/ 238 U activity ratios (AR's) of the soil horizons allowed investigating the U-isotopes mobility in the shallow oxidizing environment. Kaolinization and laterization processes are taking place in the profiles sampled, as they are especially common in regions characterized by a wet and dry tropical climate and a water table that is close to the surface. These processes are implied by inverse significant correlations between silica and iron in both soil profiles. Iron oxides were also very important to retain uranium in the two sites investigated, helping on the understanding of the weathering processes acting there. 238 U and its progeny 234 U permitted evaluating the processes of physical and chemical alteration, allowing the suggestion of a possible timescale corresponding to the Middle Pleistocene for the development of the more superficial soil horizons. Copyright Â© 2016 Elsevier Ltd. All rights reserved.
The origin of black carbon on speleothems in tourist caves in South Korea: Chemical characterization and source discrimination by radiocarbon measurement

NASA Astrophysics Data System (ADS)

Chang, Sae Jung; Jeong, Gi Young; Kim, Soo Jin

Since the Gosu, Ondal, and Sungryu karst caves in South Korea became open to the public several decades ago, the surface of their speleothems has been turning black due to pollutants. The black pollutant is concentrated at the surface of speleothems, and the surface black layer is 0.1 to several millimeters thick. Elemental measurements of three bulk, acid-dissolved and oxidized fractions of the surface black layer show that the black pigment is a black carbon. The black carbon correlates positively with sulfates, nitrates, manganese, and lead, which are typical tracers of industrial and urban emissions. The 14C-measurement of the black carbon, using accelerator mass spectrometry, shows that the black carbon was derived from both fossil-fuel combustion and biomass burning in roughly equal amounts, evidenced by fC value ranging from 0.340 to 0.592 (<±0.004, 1 σ). Therefore, protection of speleothems from black coloration requires control of anthropogenic black carbons carried by visitors. Suitable measures might include closure of caves, air cleaning of visitors and regulation of visitor numbers. The application of radiocarbon measurement of black carbon suggests that the fC is a valuable proxy for tracing the blackening phenomenon of natural and cultural heritage sites such as caves.
Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Méndez-García, C.; Renteria-Villalobos, M.; García-Tenorio, R.; Montero-Cabrera, M. E.

2014-07-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232Th-series, 238U-series, 40K and 137Cs activity concentrations (AC, Bq kg-1) were determined by gamma spectrometry with a high purity Ge detector. 238U and 234U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210Pb activities. Results were verified by 137Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento - Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234U/overflow="scroll">238U and 238U/overflow="scroll">226Ra in sediments have values between 0.9-1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232Th/overflow="scroll">238U, 228Ra/overflow="scroll">226Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.
Evidence for the timing and duration of the last interglacial period from high-precision uranium-series ages of corals on tectonically stable coastlines

USGS Publications Warehouse

Muhs, D.R.

2002-01-01

The last interglacial period has a timing and duration that can be estimated from U-series dating of emergent, coral-bearing deposits on tectonically stable coastlines. High-precision dating from Bermuda, the Bahamas, Hawaii, and Australia suggests that the last interglacial period had a sea level at least as high as present from ???128,000 to 116,000 yr B.P. Sea level reached a near-present level more quickly after the close of the penultimate glacial period than at the close of the last glacial period and the duration of high sea level is longer than that implied by the deep-sea record. ?? 2002 University of Washington.
Early diagenesis of travertine deposits from the Tibetan Plateau - implications for 230Th/234U dating and palaeoenvironmental reconstruction

NASA Astrophysics Data System (ADS)

Wang, Zhijun; Meyer, Michael; Hoffmann, Dirk; Spötl, Christoph; Aldenderfer, Mark; Sanders, Diethard

2014-05-01

Travertine is calcium carbonate precipitated from hydrothermal springs. These terrestrial carbonate deposits can be used as high-resolution archives for reconstructing palaeoclimatic and palaeoenvironmental change and are also suitable for uranium-series disequilibrium (230Th/234U) dating. In many instances such spring deposits are associated with archaeological remains (e.g. stone artifacts and other traces of prehistoric human activity) and are therefore of interest for palaeoclimatologists and archaeologists alike. However, travertines are often affected by early diagenesis that can impact on the closed-system U-series behavior and on their geochemical signature. Hence, careful evaluation of the travertine microfabrics is required before these types of hot spring deposits can be accurately dated and used for paleoenviromental reconstruction. The Tibetan plateau hosts numerous hydrothermal spring deposits that occur along neotectonic faults. In this study, samples were collected from two archaeological travertine sites, i.e. Chusang and Tirthapuri, located in southern and western Tibet, respectively. Microscopic analysis of thin sections reveals a wide variety of crystal fabrics, including micrite, microspar and sparite, the latter can be composed of columnar or mosaic crystals, respectively. Areas where dendritic crystals are preserved are identified in our micrographs as well. Many of the Chusang and Tirthapuri travertine samples are porous. Drusy sparite is rimming most of the pore walls and a complex succession of secondary calcite phases precipitated in these pore spaces as well. The different generations of pore cement comprise micrite and sparite that can be laminated or fibrous in character and show sometimes evidence of an aragonite precursor. Detrital material like quartz, feldspar and other grains as well as humic and fulvic acids have been washed into the travertine pores too. Based on our microscopic analysis a complex growth history can be reconstructed for these Tibetan travertine samples with evidence for early diagenetic alteration. In particular the dendritic calcite is known to form under hydrothermal conditions and can thus be regarded as a primary hydrothermal fabric. However, this fabric is preserved as a relict in some samples only, suggestive of widespread early diagenesis. In other samples primary - biologically mediated - calcite precipitation can be inferred from microfabrics; however, recrystallization to mosaic sparite took place soon after deposition for most of them, too. Here we combine detailed petrographic investigations with XRD, microprobe as well as stable isotope analysis and a systematic 230Th/234U dating approach. We show that certain fabrics act as closed system with respect to radiogenic isotopes and are thus suitable for U-series dating. For the majority of fabrics encountered in our Tibetan samples, however, early diagenesis can be inferred and these fabrics also suffer from open-system behavior, hence, require and 'isochron' dating approach. Guidelines are established for identifying early diagenesis in these Tibetan travertine samples and implications for palaeoenvironmental reconstruction are discussed.
Quantification of Magnetic Components in Sediments with Applications in Paleoenvironmental Studies

NASA Astrophysics Data System (ADS)

Lascu, Ioan

The present dissertation is a collection of papers investigating the magnetic properties of sediments. The main aim of the work presented here is to study the magnetic characteristics of sedimentary deposits by using a methodology that efficiently quantifies the contributions of various ferrimagnetic components in sediments, and to exemplify how this model can be used to make inferences about past climatic and environmental variability. Magnetic minerals in sediments have long been used as indicators of variability in the factors controlling sediment deposition, and sediment-magnetic properties can be interpreted in terms of the processes controlling the fluxes of various magnetic components. Ferrimagnetic minerals, such as magnetite, are strong magnetically, and tend to dominate the signal from bulk measurements. Two sedimentary ferrimagnetic components that play a major role in shaping the magnetic record with time: a detrital component and a biogenic component. The detrital component of magnetic assemblages probably accounts for the greater proportion of the magnetic signal in many records, and therefore has been the focus of most environmental magnetism studies. The processes that control detrital records are mostly tied to local hydrology, climate, and vegetation cover. However, there is strong evidence that many magnetic assemblages are dominated by autochthonous magnetic particles, which in most cases are produced as a result of direct biologic control. Knowing the contribution of each of these components to the total mass of ferrimagnetic material becomes important when making inferences about past climatic or environmental conditions. The theoretical mixing model devised here using the characteristics of detrital and biogenic end members was tested on lake sediments from Minnesota. The analysis incorporates both spatial and temporal effects on magnetic record. We have investigated the history of sediment flux to Deming Lake, Minnesota, for the past 1000 years. Our results reveal several episodes of reduced precipitation, during which less sediment is mobilized from the catchment by overland flow and runoff. The most prominent episode occurred at the end of the Little Ice Age, indicating that this time period was not only cold but might have been drier than previously thought. The spatial control on sediment-magnetic properties was established via a survey of the magnetic properties of surface sediments from several Minnesota lakes. The magnetic properties are controlled by the competing fluxes of detrital and biogenic particles, according to location in the basin, while the position of the oxic-anoxic interface controls whether biogenic magnetite is formed in the sediment or in the water column, with implications in the preservation of intact versus collapsed bacterial chains. The thesis concludes with an incursion into the magnetic properties of chemical sediments from caves, or speleothems. The magnetic recordings preserved in calcite speleothems hold enormous potential for paleomagnetic and paleoenvironmental reconstructions. Speleothems lock in magnetization instantly, are not affected by post-depositional effects, and can be dated with high precision. The natural remanence in speleothems is carried mainly by magnetite, and the main remanence acquisition mechanism is depositional, through physical alignment of detrital magnetic grains parallel to the Earth's magnetic field. Future speleothem magnetism studies should benefit from increasingly sensitive magnetometers, operating at high spatial resolution, that are able to resolve short-term geomagnetic variability, and characterize events such as geomagnetic excursions at an unprecedented scale.
A >400 kyrs archive of sedimentation in Scladina cave (Belgium)

NASA Astrophysics Data System (ADS)

Vonhof, Hubert; Bonjean, Dominique; Pirson, Stéphane; van der Lubbe, Jeroen; Hellstrom, John; Scholz, Denis; Verheyden, Sophie

2017-04-01

Scladina Cave, near the Meuse River in Belgium, is well-known for its well preserved Neanderthal fossils and stone tools. Cave research started in the 1970's, when archeological findings near the entrance of the cave initiated a long-running excavation programme in the -at that time- almost completely sediment-infilled cave. Over the past decades, a wealth of mammal fossils, stone tools, and a mandible of a Neanderthal child were found, and the complex sedimentary context of the cave strata was reconstructed in high detail. Crucial to understanding the cave stratigraphy is the construction of an absolutely dated age model. Until recently, this age model was based on a number of OSL ages, pollen stratigraphy and a few U-series ages on flowstone and stalagmite calcite. These U-series ages, however, had much lower precision than can be obtained by modern MC-ICP-MS techniques. In this study, we present new and more precise U-series ages for the major flow stone levels in Scladina Cave (upper stratigraphical sequence), and two flowstone levels from Sous-Saint-Paul Cave (lower stratigraphical sequence). The oldest flow stone layer dates back to > 400 ka, and the youngest represents the Holocene. The age model shows that flow stone formation typically occurred during warm climate conditions. These findings help to improve the existing age model for Scladina Cave significantly, and place better constraints on the age of individual fossils, and fossil assemblages in the cave.
High-resolution speleothem record of precipitation from the Yucatan Peninsula spanning the Maya Preclassic Period

NASA Astrophysics Data System (ADS)

Medina-Elizalde, Martín; Burns, Stephen J.; Polanco-Martínez, Josué M.; Beach, Timothy; Lases-Hernández, Fernanda; Shen, Chuan-Chou; Wang, Hao-Cheng

2016-03-01

We produced a new high-resolution absolute U-Th dated stalagmite oxygen isotope record (δ18O) from Río Secreto, Playa del Carmen, Yucatan Peninsula (YP). This new 1434-year stalagmite record (named Itzamna after the Maya god of creation) spans the time interval between BCE 1037 and CE 397 with an average resolution of 8 ± 2 years. It provides a novel view of climate evolution over the Preclassic and early Classic periods in Maya history. To understand the controls of regional precipitation δ18O on seasonal time scales, we characterized the amount effect between precipitation amount (P) and precipitation δ18O (δP). We found that precipitation δ18O in the Yucatan Peninsula is controlled by the amount effect on seasonal scales (δP/ΔP = - 0.0137 ± 0.0031‰ per mm, r = 0.9), as suspected but never before demonstrated. Cave drip δ18O is consistent with the annual amount-weighted δ18O composition of precipitation. Multiple lines of evidence suggest that stalagmite δ18O reflects isotopic equilibrium conditions and thus stalagmite δ18O changes are interpreted to reflect precipitation amount. We determined quantitative precipitation changes from the stalagmite δ18O record following previous methods (Medina-Elizalde and Rohling, 2012). The stalagmite precipitation record suggests twelve periods of anomalous precipitation reductions ranging between about 30 and 70% below mean conditions at the time and with durations from 6 years to 31 years. Between BCE 520 and 166, the speleothem precipitation record suggests that the YP experienced an interval of high precipitation labeled the Late Preclassic Humid Period (LPHP) with precipitation maxima of up to + 86 ± 20%. Preclassic Maya cultural expansion in El Mirador Basin, located in northern Guatemala, took place while the peninsula transitioned from the LPHP to an interval with below average precipitation. We find that the Preclassic abandonment of major centers in the Mirador Basin and others around the Maya Lowlands was synchronous with two unprecedented multi-decadal events of severe precipitation reduction with magnitudes of - 55 ± 13% and - 49 ± 12 and centered at CE 186 and 234, respectively. We also find evidence that centennial scale precipitation variability in the YP during the Preclassic Period may have been associated with shifts in rainfall fluxes from Atlantic tropical cyclones.
Late Pleistocene eruptive history of the Mono Craters rhyolites, eastern California, from U-Th dating of explosive and effusive products

NASA Astrophysics Data System (ADS)

Marcaida, M.; Vazquez, J. A.; Calvert, A. T.; Miller, J. S.

2016-12-01

During late Pleistocene-Holocene time, repeated explosive and effusive eruptions of high-silica rhyolite magma south of Mono Lake, California, have produced a chain of massive domes known as the Mono Craters and a time-series of tephra deposits preserved in sediments of the Wilson Creek formation of ancestral Mono Lake. The record of late Holocene volcanism at Mono Craters is relatively well constrained by tephrostratigraphy and 14C dating, and the timing of late Pleistocene eruptions is similarly well constrained by tephrochronology and magnetostratigraphy of the Wilson Creek formation. However, the chronology of eruptions for the Mono Craters chain, comprising at least 28 individual domes, has thus far been based on age estimates from hydration rind dating of obsidian that is highly dependent on local calibration. We constrain the timing of late Pleistocene dome emplacement by linking independently dated Wilson Creek tephras to their dome equivalents in the Mono Craters using combined titanomagnetite geochemistry and U-Th geochronology. Ion microprobe 238U-230Th dating of unpolished allanite and zircon rims gives isochron dates of ca. 42 ka, ca. 38 ka, ca. 26 ka, and ca. 20 ka for domes 19, 24, 31 (newly recognized), and 11 of the Mono Craters, respectively. These domes are biotite-bearing rhyolites with titanomagnetites that are compositionally identical to those from several Wilson Creek tephras. Specifically, we correlate Ash 15, Ash 7, and Ash 3 of the Wilson Creek formation to domes 19, 31, and 11 of the Mono Craters, respectively, based on matching titanomagnetite compositions and indistinguishable U-Th ages. 40Ar/39Ar dating of single sanidines from domes 19 and 31 yield mean dates that are 10 k.y. older than their corresponding U-Th dates, likely due to excess argon from melt inclusions and/or incompletely re-equilibrated antecrysts. Based on our new U-Th isochron date of ca. 34 ka for allanite-zircon from Ash 8 pumice and the ca. 26-27 ka age of Ash 7 and its extrusive equivalent dome 31, we infer that the stratigraphic position of the ca. 32 ka Auckland/Mono Lake geomagnetic excursion, if recorded in beds of the Wilson Creek formation, is between Ashes 7 and 8. Accordingly, the prominent geomagnetic excursion bisected by Ash 15 lower in the section is the ca. 41 ka global Laschamp event.
AMS Radiocarbon Dating Individual Taxa and Individual Specimens: Implications for Small Mammal Paleoecology.

NASA Astrophysics Data System (ADS)

Graham, Russell; Stafford, Thomas, Jr.; Semken, Holmes, Jr.

2010-05-01

Advances in AMS physics and organic geochemistry have revolutionized our ability to establish absolute chronologies on vertebrate fossils. Highly purified collagen, which provides extremely accurate 14C ages, can be extracted from single bones and teeth as small as 50 mg. Combined with measurement precisions of ±15 to 25 years for ages of < 20,000 yr, the direct AMS 14C technique enables fossil deposits to be chronologically dissected at the level of single animals. Analysis of data from a variety of sites in the United States indicates that most excavation levels (analysis units) as small as 10 cm can be time averaged by several thousand years at a minimum, even with the greatest care in excavation and processing of sediments. Time averaging of this magnitude has important implications for fine-scale paleoecological analysis of faunas, especially when compared to high-resolution climate records like those derived from speleothems, ice cores, or marine cores. To this end, we propose saturation dating of indicative taxa and plotting dates of individual specimens against high-resolution climate records rather than analysis of complete faunas or faunules. This technique provides even higher resolution of paleoenvironments than pollen spectra.
The impact of Last Glacial climate variability in west-European loess revealed by radiocarbon dating of fossil earthworm granules.

PubMed

Moine, Olivier; Antoine, Pierre; Hatté, Christine; Landais, Amaëlle; Mathieu, Jérôme; Prud'homme, Charlotte; Rousseau, Denis-Didier

2017-06-13

The characterization of Last Glacial millennial-timescale warming phases, known as interstadials or Dansgaard-Oeschger events, requires precise chronologies for the study of paleoclimate records. On the European continent, such chronologies are only available for several Last Glacial pollen and rare speleothem archives principally located in the Mediterranean domain. Farther north, in continental lowlands, numerous high-resolution records of loess and paleosols sequences show a consistent environmental response to stadial-interstadial cycles. However, the limited precision and accuracy of luminescence dating methods commonly used in loess deposits preclude exact correlations of paleosol horizons with Greenland interstadials. To overcome this problem, a radiocarbon dating protocol has been developed to date earthworm calcite granules from the reference loess sequence of Nussloch (Germany). Its application yields a consistent radiocarbon chronology of all soil horizons formed between 47 and 20 ka and unambiguously shows the correlation of every Greenland interstadial identified in isotope records with specific soil horizons. Furthermore, eight additional minor soil horizons dated between 27.5 and 21 ka only correlate with minor decreases in Greenland dust records. This dating strategy reveals the high sensitivity of loess paleoenvironments to Northern Hemisphere climate changes. A connection between loess sedimentation rate, Fennoscandian ice sheet dynamics, and sea level changes is proposed. The chronological improvements enabled by the radiocarbon "earthworm clock" thus strongly enhance our understanding of loess records to a better perception of the impact of Last Glacial climate changes on European paleoenvironments.
The impact of Last Glacial climate variability in west-European loess revealed by radiocarbon dating of fossil earthworm granules

PubMed Central

Moine, Olivier; Antoine, Pierre; Hatté, Christine; Landais, Amaëlle; Mathieu, Jérôme; Prud’homme, Charlotte

2017-01-01

The characterization of Last Glacial millennial-timescale warming phases, known as interstadials or Dansgaard–Oeschger events, requires precise chronologies for the study of paleoclimate records. On the European continent, such chronologies are only available for several Last Glacial pollen and rare speleothem archives principally located in the Mediterranean domain. Farther north, in continental lowlands, numerous high-resolution records of loess and paleosols sequences show a consistent environmental response to stadial–interstadial cycles. However, the limited precision and accuracy of luminescence dating methods commonly used in loess deposits preclude exact correlations of paleosol horizons with Greenland interstadials. To overcome this problem, a radiocarbon dating protocol has been developed to date earthworm calcite granules from the reference loess sequence of Nussloch (Germany). Its application yields a consistent radiocarbon chronology of all soil horizons formed between 47 and 20 ka and unambiguously shows the correlation of every Greenland interstadial identified in isotope records with specific soil horizons. Furthermore, eight additional minor soil horizons dated between 27.5 and 21 ka only correlate with minor decreases in Greenland dust records. This dating strategy reveals the high sensitivity of loess paleoenvironments to Northern Hemisphere climate changes. A connection between loess sedimentation rate, Fennoscandian ice sheet dynamics, and sea level changes is proposed. The chronological improvements enabled by the radiocarbon “earthworm clock” thus strongly enhance our understanding of loess records to a better perception of the impact of Last Glacial climate changes on European paleoenvironments. PMID:28559353

Carbon dioxide budgets in cave air and carbon in speleothems; insights from a shallow cave in Ireland

NASA Astrophysics Data System (ADS)

McDermott, Frank; Phillips, Dominika

2017-04-01

The conventional view that hydrological inputs (e.g. drip-water degassing) comprise the dominant source of cave air CO2 has been challenged by recent studies that emphasise the importance of direct advection of gaseous CO2from above and beneath cave voids (e.g. 'soil air' and 'ground air'). A better understanding of CO2 gas budgets in caves is important, not only for the correct interpretation of δ13C values and 14C activity data in speleothems, but also for an understanding of the wider role of karst in the global carbon cycle as a source or sink of atmospheric CO2. This study presents new results from a combined air-temperature and CO2 monitoring programme at a small multi-chamber cave in SE Ireland (Ballynamintra cave, Co. Waterford), building on an earlier study at this cave (Baldini et al., 2006). Episodic, low-amplitude but temporally coherent diurnal-scale cave air temperature fluctuations detected almost simultaneously by a series of temperature loggers within the cave were used to detect air mass advection. The sequence and pattern of temperature fluctuations at different locations within the cave enabled the identification of discrete air-inflow and air-outflow events. These diurnal-scale events occur episodically throughout the year in the winter/ spring and summer/autumn temperature ventilation regimes of the cave. Importantly, changes in cave air pCO2 values recorded by an infra-red logger located in the inner chamber a few metres from the back of the cave occur contemporaneously with the air-mass displacement events, and are consistent with direct advection of CO2-rich soil air via fractures in the subjacent cave roof and walls. In the winter regime, episodic diurnal-scale air outflow events draw CO2-rich air over the logger, resulting in short-lived pulses of air, typically containing c. 0.7% CO2 (by volume), several times the ambient cave air CO2 values at this site. Similar events occur during the summer/autumn thermal regime, but these reach higher CO2values (1-1.2%), similar to those measured previously in the overlying soil. Overall, the data confirm an important role for soil and/or ground air sources at this cave and indicate that the episodic CO2 inputs are not controlled by drip-water inputs,. Some recent studies have additionally argued that advected 'ground-air' is not only an important constituent of cave air, but also an important source of carbon in speleothems. This claim is critically evaluated here using 14C activity measurements from actively growing zero-age soda-straw stalactites from the small inner chamber of the cave where the CO2 monitoring was carried out. Surprisingly, soda-straws collected from within a few metres of each other in this inner chamber exhibit quite different 14C activities (93-101 pMC), and are not identical as might be expected if complete carbon isotope exchange had occurred between the dissolved inorganic carbon and the cave atmosphere. The reasons for this will be discussed, drawing on the results of published kinetic models for degassing and isotope exchange. Overall, it is concluded that while the CO2 budget of the air in Ballynamintra cave is dominated by directly advected soil air, water transported dissolved inorganic carbon (DIC) likely remains an important carbon source for its speleothems. Baldini, J.U.L., Baldini, L.M., McDermott, F. and Clipson, N. (2006) Carbon dioxide sources, sinks, and spatial variability in shallow temperate zone caves: evidence from Ballynamintra Cave, Ireland. Journal of Cave and Karst Studies, 68, 4-11.
Chronology of the cave interior sediments at Gran Dolina archaeological site, Atapuerca (Spain)

NASA Astrophysics Data System (ADS)

Parés, J. M.; Álvarez, C.; Sier, M.; Moreno, D.; Duval, M.; Woodhead, J. D.; Ortega, A. I.; Campaña, I.; Rosell, J.; Bermúdez de Castro, J. M.; Carbonell, E.

2018-04-01

The so-called "Gran Dolina site" (Atapuerca mountain range, N Spain) is a karstic cavity filled by sediments during the Pleistocene, some of which contain a rich ensemble of archaeological and paleontological records. These sediments have contributed significantly to our understanding of early human dispersal in Europe but, in contrast, older, interior facies deposits have received much less of attention. The stratigraphy of Gran Dolina reveals an abrupt sedimentary change of interior to entrance facies from bottom to top, reflecting a significant paleoenvironmental change that promoted the accumulation of sediments transported from the vicinity of the cave by water or "en masse". Since the major magnetic polarity reversal known as the Matuyama-Brunhes boundary (0.78 Ma) was detected within the TD7 unit in the middle of the stratigraphic section, we carried out a new combined paleomagnetic, radiometric (U-Pb), and electron spin resonance (ESR) dating study of the lower part of the sequence in order to constrain the chronology of the interior facies at Gran Dolina. U-Pb analysis of speleothems did not produce age information as the samples proved to be extremely unradiogenic. The magnetic stratigraphy of the cave interior sediments reveals a dominant reverse magnetic polarity, coherent with a Matuyama age, and interrupted by a normal polarity magnetozone interpreted as the Jaramillo Subchron (1.0-1.1 Ma). ESR ages on quartz grains from the upper part of the interior facies sediments are coherent with such an interpretation. We conclude that the fluvial deposits (interior facies) that constitute the cave floor began accumulating before 1.2 Ma. The development of large cave entrances at Gran Dolina occurred shortly after the Jaramillo Subchron but before ca 900 ka ago.
The magnesium isotope record of cave carbonate archives

NASA Astrophysics Data System (ADS)

Riechelmann, S.; Buhl, D.; Schröder-Ritzrau, A.; Riechelmann, D. F. C.; Richter, D. K.; Vonhof, H. B.; Wassenburg, J. A.; Geske, A.; Spötl, C.; Immenhauser, A.

2012-05-01

Here we explore the potential of time-series magnesium (δ26Mg) isotope data as continental climate proxies in speleothem calcite archives. For this purpose, a total of six Pleistocene and Holocene stalagmites from caves in Germany, Morocco and Peru and two flowstones from a cave in Austria were investigated. These caves represent the semi-arid to arid (Morocco), the warm-temperate (Germany), the equatorial-humid (Peru) and the cold-humid (Austria) climate zones. Changes in the calcite magnesium isotope signature with time are placed against carbon and oxygen isotope records from these speleothems. Similar to other proxies, the non-trivial interaction of a number of environmental, equilibrium and non-equilibrium processes governs the δ26Mg fractionation in continental settings. These include the different sources of magnesium isotopes such as rain water or snow as well as soil and hostrock, soil zone biogenic activity, shifts in silicate versus carbonate weathering ratios and residence time of water in the soil and karst zone. Pleistocene stalagmites from Morocco show the lowest mean δ26Mg values (GDA: -4.26 ± 0.07 ‰ and HK3: -4.17 ± 0.15 ‰) and the data are well explained in terms of changes in aridity over time. The Pleistocene to Holocene stalagmites from Peru show the highest mean value (NC-A and NC-B δ26Mg: -3.96 ± 0.04 ‰) but only minor variations in Mg-isotope composition, which is in concert with the rather stable equatorial climate at this site. Holocene stalagmites from Germany (AH-1 mean δ26Mg: -4.01 ± 0.07 ‰; BU 4 mean δ26Mg: -4.20 ± 0.10 ‰) record changes in outside air temperature as driving factor rather than rainfall amount. The alpine Pleistocene flowstones from Austria (SPA 52: -3.00 ± 0.73 ‰; SPA 59: -3.70 ± 0.43 ‰) are affected by glacial versus interglacial climate change with outside air temperature affecting soil zone activity and weathering balance. Several data points in the Austrian and two data points in the German speleothems are shifted to higher values due to sampling in detrital layers (Mg-bearing clay minerals) of the speleothems. The data and their interpretation shown here highlight the potential but also the limitations of the magnesium isotope proxy applied in continental climate research. An obvious potential lies in its sensitivity for even subtle changes in soil-zone parameters, a hitherto rather poorly understood but extremely important component in cave archive research. Limitations are most obvious in the low resolution and high sample amount needed for analysis. Future research should focus on experimental and conceptual aspects including quantitative and well calibrated leaching and precipitation experiments.
The magnesium isotope record of cave carbonate archives

NASA Astrophysics Data System (ADS)

Riechelmann, S.; Buhl, D.; Schröder-Ritzrau, A.; Riechelmann, D. F. C.; Richter, D. K.; Vonhof, H. B.; Wassenburg, J. A.; Geske, A.; Spötl, C.; Immenhauser, A.

2012-11-01

Here we explore the potential of magnesium (δ26Mg) isotope time-series data as continental climate proxies in speleothem calcite archives. For this purpose, a total of six Pleistocene and Holocene stalagmites from caves in Germany, Morocco and Peru and two flowstones from a cave in Austria were investigated. These caves represent the semi-arid to arid (Morocco), the warm-temperate (Germany), the equatorial-humid (Peru) and the cold-humid (Austria) climate zones. Changes in the calcite magnesium isotope signature with time are compared against carbon and oxygen isotope records from these speleothems. Similar to other proxies, the non-trivial interaction of a number of environmental, equilibrium and disequilibrium processes governs the δ26Mg fractionation in continental settings. These include the different sources of magnesium isotopes such as rainwater or snow as well as soil and host rock, soil zone biogenic activity, shifts in silicate versus carbonate weathering ratios and residence time of water in the soil and karst zone. Pleistocene stalagmites from Morocco show the lowest mean δ26Mg values (GDA: -4.26 ± 0.07‰ and HK3: -4.17 ± 0.15‰), and the data are well explained in terms of changes in aridity over time. The Pleistocene to Holocene stalagmites from Peru show the highest mean value of all stalagmites (NC-A and NC-B δ26Mg: -3.96 ± 0.04‰) but only minor variations in Mg-isotope composition, which is consistent with the rather stable equatorial climate at this site. Holocene stalagmites from Germany (AH-1 mean δ26Mg: -4.01 ± 0.07‰; BU 4 mean δ26Mg: -4.20 ± 0.10‰) suggest changes in outside air temperature was the principal driver rather than rainfall amount. The alpine Pleistocene flowstones from Austria (SPA 52: -3.00 ± 0.73‰; SPA 59: -3.70 ± 0.43‰) are affected by glacial versus interglacial climate change with outside air temperature affecting soil zone activity and weathering balance. Several δ26Mg values of the Austrian and two δ26Mg values of the German speleothems are shifted to higher values due to sampling in detrital layers (Mg-bearing clay minerals) of the speleothems. The data and their interpretation shown here highlight the potential but also the limitations of the magnesium isotope proxy applied in continental climate research. An obvious potential lies in its sensitivity for even subtle changes in soil-zone parameters, a hitherto rather poorly understood but extremely important component in cave archive research. Limitations are most obvious in the low resolution and high sample amount needed for analysis. Future research should focus on experimental and conceptual aspects including quantitative and well-calibrated leaching and precipitation experiments.
Constraining Holocene hydrological changes in the Carpathian-Balkan region using speleothem δ18O and pollen-based temperature reconstructions

NASA Astrophysics Data System (ADS)

Drăguşin, V.; Staubwasser, M.; Hoffmann, D. L.; Ersek, V.; Onac, B. P.; Veres, D.

2014-07-01

Here we present a speleothem isotope record (POM2) from Ascunsă Cave (Romania) that provides new data on past climate changes in the Carpathian-Balkan region from 8.2 ka until the present. This paper describes an approach to constrain the effect of temperature changes on calcite δ18O values in stalagmite POM2 over the course of the middle Holocene (6-4 ka), and across the 8.2 and 3.2 ka rapid climate change events. Independent pollen temperature reconstructions are used to this purpose. The approach combines the temperature-dependent isotope fractionation of rain water during condensation and fractionation resulting from calcite precipitation at the given cave temperature. The only prior assumptions are that pollen-derived average annual temperature reflects average cave temperature, and that pollen-derived coldest and warmest month temperatures reflect the range of condensation temperatures of rain above the cave site. This approach constrains a range of values between which speleothem δ18O changes should be found if controlled only by surface temperature variations at the cave site. Deviations of the change in δ18Ocspel values from the calculated temperature-constrained range of change are interpreted towards large-scale variability of climate-hydrology. Following this approach, we show that an additional ∼0.6‰ enrichment of δ18Oc in the POM2 stalagmite was caused by changing hydrological patterns in SW Romania across the middle Holocene, most likely comprising local evaporation from the soil and an increase in Mediterranean moisture δ18O. Further, by extending the calculations to other speleothem records from around the entire Mediterranean basin, it appears that all eastern Mediterranean speleothems recorded a similar isotopic enrichment due to changing hydrology, whereas all changes recorded in speleothems from the western Mediterranean are fully explained by temperature variation alone. This highlights a different hydrological evolution between the two sides of the Mediterranean. Our results also demonstrate that during the 8.2 ka event, POM2 stable isotope data essentially fit the temperature-constrained isotopic variability. In the case of the 3.2 ka event, an additional climate-related hydrological factor is more evident. This implies a different rainfall pattern in the Southern Carpathian region during this event at the end of the Bronze Age.
High resolution geochemical proxy record of the last 600yr in a speleothem from the northwest Iberian Peninsula

NASA Astrophysics Data System (ADS)

Iglesias González, Miguel; Pisonero, Jorge; Cheng, Hai; Edwards, R. Lawrence; Stoll, Heather

2017-04-01

In meteorology and climatology, the instrumental period is the period where we have measured directly by instrumentation, different meteorological data along the surface which allow us to determinate the evolution of the climate during the last 150 years over the world. At the beginning, the density of this data were very low, so we have to wait until the last 75-100 years to have a good network in most of the parts of the surface. This time period is very small if we want to analyze the relationship between geochemical and instrumental variability in any speleothem. So a very high resolution data is needed to determinate the connection between both of them in the instrumental period, to try to determinate de evolution of climate in the last 600 years. Here we present a high resolution speleothem record from a cave located in the middle of the Cantabrian Mountains without any anthropologic influence and with no CO2 seasonal variability. This 600yr stalagmite, dated with U/Th method with a growth rate from 100 to 200 micrometers/yr calculated with Bchron model, provide us accurate information of the climate conditions near the cave. Trace elements are analyzed at 8 micrometers intervals by Laser Ablation ICP-MS which resolves even monthly resolution during the last 600 years with special attention with Sr, Mg, Al and Si. This data, without seasonal variability and with the presence of a river inside the cave, give us very valuable information about the extreme flood events inside the cave during the whole period, which is related with the precipitations and the snow fusion events outside the cave. We identify more extremely flood events during the Little Ice Age than in the last 100yr. As well, we have trace elements data with spatial resolution of 0.2mm analyzed with ICP-AES which allow us to compare the geochemical variability with both technics. We also analyze stable isotope d13C and d18O with a spatial resolution of 0.2mm, so we are able to identify variations and all possible correlations between them, trace elements and instrumental records from the different weather stations located near the cave. We use instrumental data, and the statistical correlation between our proxy and them, to calibrate and analyze the variability along the 600yr which provide us a lot of information about the climate variability. In spite of the significate global warming during the last 25 years, we have less variability during this period than along the transition between the Medieval Warm Period and the Little Ice Age. We also analyze this variability along the 600 years with wavelet analysis, with special attention in the instrumental period. With this mathematical method, we can identify several cycles both in trace elements and stable isotopes at special scales compatible with the decadal and multidecadal variability with a value similar to very important climate index like AMO.
High-resolution records of soil humification and paleoclimate change from variations in speleothem luminescence excitation and emission wavelengths

NASA Astrophysics Data System (ADS)

Baker, Andy; Genty, Dominique; Smart, Peter L.

1998-10-01

Recent advances in the precision and accuracy of the optical techniques required to measure luminescence permit the nondestructive analysis of solid geologic samples such as speleothems (secondary carbonate deposits in caves). In this paper we show that measurement of speleothem luminescence demonstrates a strong relationship between the excitation and emission wavelengths and both the extent of soil humification and mean annual rainfall. Raw peat with blanket bog vegetation has the highest humification and highest luminescence excitation and emission matrix wavelengths, because of the higher proportion of high-molecular-weight organic acids in these soils. Brown ranker and rendzina soils with dry grassland and woodland cover have the lowest wavelengths. Detailed analysis of one site where an annually laminated stalagmite has been deposited over the past 70 yr during a period with instrumental climate records and no vegetation change suggests that more subtle variations in luminescence emission wavelength correlate best with mean annual rainfall, although there is a lag of ˜10 yr. These results are used to interpret soil humification and climate change from a 130 ka speleothem at an upland site in Yorkshire, England. These data provide a new continuous terrestrial record of climate and environmental change for northwestern Europe and suggest the presence of significant variations in wetness and vegetation within interglacial and interstadial periods.
Microbial community biofabrics in a geothermal mine adit.

PubMed

Spear, John R; Barton, Hazel A; Robertson, Charles E; Francis, Christopher A; Pace, Norman R

2007-10-01

Speleothems such as stalactites and stalagmites are usually considered to be mineralogical in composition and origin; however, microorganisms have been implicated in the development of some speleothems. We have identified and characterized the biological and mineralogical composition of mat-like biofabrics in two novel kinds of speleothems from a 50 degrees C geothermal mine adit near Glenwood Springs, CO. One type of structure consists of 2- to 3-cm-long, 3- to 4-mm-wide, leather-like, hollow, soda straw stalactites. Light and electron microscopy indicated that the stalactites are composed of a mineralized biofabric with several cell morphotypes in a laminated form, with gypsum and sulfur as the dominant mineral components. A small-subunit rRNA gene phylogenetic community analysis along the stalactite length yielded a diverse gradient of organisms, with a relatively simple suite of main constituents: Thermus spp., crenarchaeotes, Chloroflexi, and Gammaproteobacteria. PCR analysis also detected putative crenarchaeal ammonia monooxygenase subunit A (amoA) genes in this community, the majority related to sequences from other geothermal systems. The second type of speleothem, dumpling-like rafts floating on a 50 degrees C pool on the floor of the adit, showed a mat-like fabric of evidently living organisms on the outside of the dumpling, with a multimineral, amorphous, gypsum-based internal composition. These two novel types of biofabrics are examples of the complex roles that microbes can play in mineralization, weathering, and deposition processes in karst environments.
Comment on "Zircon U-Th-Pb dating using LA-ICP-MS: Simultaneous U-Pb and U-Th dating on 0.1 Ma Toya Tephra, Japan" by Hisatoshi Ito

NASA Astrophysics Data System (ADS)

Guillong, M.; Schmitt, A. K.; Bachmann, O.

2015-04-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) of eight zircon reference materials and synthetic zircon-hafnon end-members indicate that corrections for abundance sensitivity and molecular zirconium sesquioxide ions (Zr2O3+) are critical for reliable determination of 230Th abundances in zircon. Other polyatomic interferences in the mass range 223-233 amu are insignificant. When corrected for abundance sensitivity and interferences, activity ratios of (230Th)/(238U) for the zircon reference materials we used average 1.001 ± 0.010 (1σ error; mean square of weighted deviates MSWD = 1.45; n = 8). This includes the 91500 and Plešovice zircons, which were deemed unsuitable for calibration of (230Th)/(238U) by Ito (2014). Uranium series zircon ages generated by LA-ICP-MS without mitigating (e.g., by high mass resolution) or correcting for abundance sensitivity and molecular interferences on 230Th such as those presented by Ito (2014) are potentially unreliable.
Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Méndez-García, C.; Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx; Renteria-Villalobos, M.

2008-01-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. ²³²Th-series, ²³⁸U-series, ⁴⁰K and ¹³⁷Cs activity concentrations (AC, Bq kg⁻¹) were determined by gamma spectrometry with a high purity Ge detector. ²³⁸U and ²³⁴U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating ofmore » core sediments was performed applying CRS method to ²¹⁰Pb activities. Results were verified by ¹³⁷Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High ²³⁸U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) ²³⁴U/²³⁸U and ²³⁸U/²²⁶Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. ²³²Th/²³⁸U, ²²⁸Ra/²²⁶Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.« less
Evaluating intra- and inter- sample variability in Electron Spin Resonance dating of fossil teeth: an example from Cuesta de la Bajada site (Spain).

NASA Astrophysics Data System (ADS)

Duval, Mathieu; Grün, Rainer; Shao, Qingfeng; Martin, Loïc; Arnold, Lee J.

2017-04-01

Over the last decades, technological improvements have progressively enabled to significantly decrease the amount of material required for dating analyses. In particular, the combined use of laser ablation (LA) with ICP-MS opened new possibilities for high resolution in situ U-series analyses of fossil teeth. With this technique it is now possible to directly visualise the spatial distribution of U and Th isotopes in dental tissues. Moreover, the combination of LA-ICP-MS with Electron Spin Resonance (ESR) enables an increased sampling resolution, and offers the possibility to produce several ages for different areas within a given fossil tooth. To test the potential of this new approach, several fossil teeth were collected from the Middle Palaeolithic site of Cuesta de la Bajada (Teruel, Spain). Each tooth was divided into several subsamples, providing thus several combined US-ESR age results per tooth. For each subsample, ESR, high-resolution laser ablation and solution ICP-MS U-series analyses were systematically performed. Relative beta dose rate contributions from the different tissues and the sediment were also adjusted using DosiVox software and compared with those derived from the standard approach. The results of this work give some interesting insight into the intra- and inter- sample variability that may exist at a given site. The consistency of the final US-ESR age estimates obtained on teeth are also evaluated by comparison with the (semi)-independent results derived from ESR and Luminescence dating of optically bleached quartz grains collected from the same excavation area.
Numerical Modelling of Speleothem and Dripwater Chemistry: Interpreting Coupled Trace Element and Isotope Proxies for Climate Reconstructions

NASA Astrophysics Data System (ADS)

Owen, R.; Day, C. C.; Henderson, G. M.

2016-12-01

Speleothem palaeoclimate records are widely used but are often difficult to interpret due to the geochemical complexity of the soil-karst-cave system. Commonly analysed proxies (e.g. δ18O, δ13C and Mg/Ca) may be affected by multiple processes along the water flow path from atmospheric moisture source through to the cave drip site. Controls on speleothem chemistry include rainfall and aerosol chemistry, bedrock chemistry, temperature, soil pCO2, the degree of open-system dissolution and prior calcite precipitation. Disentangling the effects of these controls is necessary to fully interpret speleothem palaeoclimate records. To quantify the effects of these processes, we have developed an isotope-enabled numerical model based on the geochemical modelling software PHREEQC. The model calculates dripwater chemistry and isotopes through equilibrium bedrock dissolution and subsequent iterative CO2 degassing and calcite precipitation. This approach allows forward modelling of dripwater and speleothem proxies, both chemical (e.g. Ca concentration, pH, Mg/Ca and Sr/Ca ratios) and isotopic (e.g. δ18O, δ13C, δ44Ca and radiocarbon content), in a unified framework. Potential applications of this model are varied and the model may be readily expanded to include new isotope systems or processes. Here we focus on calculated proxy co-variation due to changes in model parameters. Examples include: - The increase in Ca concentration, decrease in δ13C and increase in radiocarbon content as bedrock dissolution becomes more open-system. - Covariation between δ13C, δ44Ca and trace metal proxies (e.g. Mg/Ca) predicted by changing prior calcite precipitation. - The effect of temperature change on all proxies through the soil-karst-cave system. Separating the impact of soil and karst processes on geochemical proxies allows more quantitative reconstruction of the past environment, and greater understanding in modern cave monitoring studies.
Assessing response of local moisture conditions in central Brazil to variability in regional monsoon intensity using speleothem 87Sr/86Sr values

NASA Astrophysics Data System (ADS)

Wortham, Barbara E.; Wong, Corinne I.; Silva, Lucas C. R.; McGee, David; Montañez, Isabel P.; Troy Rasbury, E.; Cooper, Kari M.; Sharp, Warren D.; Glessner, Justin J. G.; Santos, Roberto V.

2017-04-01

Delineating the controls on hydroclimate throughout Brazil is essential to assessing potential impact of global climate change on water resources and biogeography. An increasing number of monsoon reconstructions from δ18O records provide insight into variations in regional monsoon intensity over the last millennium. The strength, however, of δ18O as a proxy of regional climate limits its ability to reflect local conditions, highlighting the need for comparable reconstructions of local moisture conditions. Here, speleothem 87Sr/86Sr values are developed as a paleo-moisture proxy in central Brazil to complement existing δ18O-based reconstructions of regional monsoon intensity. Speleothem 87Sr/86Sr values are resolved using laser ablation and conventional solution mass spectrometry at high resolution relative to existing (non-δ18O-based) paleo-moisture reconstructions to allow comparisons of centennial variability in paleo-monsoon intensity and paleo-moisture conditions. Variations in speleothem 87Sr/86Sr values from Tamboril Cave are interpreted to reflect varying extents of water interaction with the carbonate host rock, with more interaction resulting in greater evolution of water isotope values from those initially acquired from the soil to those of the carbonate bedrock. Increasing speleothem 87Sr/86Sr values over the last millennium suggest progressively less interaction with the carbonate host rock likely resulting from higher infiltration rates, expected under wetter conditions. Increasingly wetter conditions over the last millennium are consistent with an overall trend of increasing monsoon intensity (decreasing δ18O values) preserved in many existing δ18O records from the region. Such a trend, however, is absent in δ18O records from our site (central Brazil) and Cristal Cave (southeast Brazil), suggesting the existence of divergent (relevant to δ18Oprecip) shifts in the climate patterns within and outside the core monsoon region.
How scaling fluctuation analyses can transform our view of the climate

NASA Astrophysics Data System (ADS)

Lovejoy, Shaun; Schertzer, Daniel

2013-04-01

There exist a bewildering diversity of proxy climate data including tree rings, ice cores, lake varves, boreholes, ice cores, pollen, foraminifera, corals and speleothems. Their quantitative use raises numerous questions of interpretation and calibration. Even in classical cases - such as the isotope signal in ice cores - the usual assumption of linear dependence on ambient temperature is only a first approximation. In other cases - such as speleothems - the isotope signals arise from multiple causes (which are not always understood) and this hinders their widespread use. We argue that traditional interpretations and calibrations - based on essentially deterministic comparisons between instrumental data, model outputs and proxies (albeit with the help of uncertainty analyses) - have been both overly ambitious while simultaneously underexploiting the data. The former since comparisons typically involve series at different temporal resolutions and from different geographical locations - one does not expect agreement in a deterministic sense, while with respect to climate models, one only expects statistical correspondences. The proxies are underexploited since comparisons are done at unique temporal and / or spatial resolutions whereas the fluctuations they describe provide information over wide ranges of scale. A convenient method of overcoming these difficulties is the use of fluctuation analysis systematically applied over the full range of available scales to determine the scaling proeprties. The new transformative element presented here, is to define fluctuations ΔT in a series T(t) at scale Δt not by differences (ΔT(Δt) = T(t+Δt) - T(t)) but rather by the difference in the means over the first and second halves of the lag Δt . This seemingly minor change - technically from "poor man's" to "Haar" wavelets - turns out to make a huge difference since for example, it is adequate for analysing temperatures from seconds to hundreds of millions of years yet remaining simple to interpret [Lovejoy and Schertzer, 2012]. It has lead for example to the discovery of the new "macroweather" regime between weather (Δt <≈ 10days) and climate (Δt ≈> 30 yrs) in which fluctuations decrease rather than increase with scale [Lovejoy, 2013]. We illustrate the transformative power of combining such fluctuation analysis with scaling by giving numerous examples from instrumental data, multiproxies, ice core proxies, corals, speleothems and GCM outputs [Lovejoy and Schertzer, 2013]. References: Lovejoy, S. (2013), What is climate?, EOS, 94, (1), 1 January, p1-2. Lovejoy, S., and D. Schertzer (2012), Haar wavelets, fluctuations and structure functions: convenient choices for geophysics, Nonlinear Proc. Geophys. , 19, 1-14 doi: 10.5194/npg-19-1-2012. Lovejoy, S., and D. Schertzer (2013), The Weather and Climate: Emergent Laws and Multifractal Cascades, 480 pp., Cambridge University Press, Cambridge.
Atmospheric dust contribution to budget of U-series nuclides in weathering profiles. The Mount Cameroon volcano

NASA Astrophysics Data System (ADS)

Pelt, E.; Chabaux, F. J.; Innocent, C.; Ghaleb, B.

2009-12-01

Analysis of U-series nuclides in weathering profiles is developed today for constraining time scale of soil and weathering profile formation (e.g., Chabaux et al., 2008). These studies require the understanding of U-series nuclides sources and fractionation in weathering systems. For most of these studies the impact of aeolian inputs on U-series nuclides in soils is usually neglected. Here, we propose to discuss such an assumption, i.e., to evaluate the impact of dust deposition on U-series nuclides in soils, by working on present and paleo-soils collected on the Mount Cameroon volcano. Recent Sr, Nd, Pb isotopic analyses performed on these samples have indeed documented significant inputs of Saharan dusts in these soils (Dia et al., 2006). We have therefore analyzed 238U-234U-230Th nuclides in the same samples. Comparison of U-Th isotopic data with Sr-Nd-Pb isotopic data indicates a significant impact of the dust input on the U and Th budget of the soils, around 10% for both U and Th. Using Sr-Nd-Pb isotopic data of Saharan dusts given by Dia et al. (2006) we estimate U-Th concentrations and U-Th isotope ratios of dusts compatible with U-Th data obtained on Saharan dusts collected in Barbados (Rydell H.S. and Prospero J.M., 1972). However, the variations of U/Th ratios along the weathering profiles cannot be explained by a simple mixing scenario between material from basalt and from the defined atmospheric dust pool. A secondary uranium migration associated with chemical weathering has affected the weathering profiles. Mass balance calculation suggests that U in soils from Mount Cameroon is affected at the same order of magnitude by both chemical migration and dust accretion. Nevertheless, the Mount Cameroon is a limit case were large dust inputs from continental crust of Sahara contaminate basaltic terrain from Mount Cameroon volcano. Therefore, this study suggests that in other contexts were dust inputs are lower, or the bedrocks more concentrated in U and Th, the dust contribution will not significantly influence U-series dating. Chabaux F., Bourdon B., Riotte J. (2008). U-series Geochemistry in weathering profiles, river waters and lakes. Radioactivity in the Environment, 13, 49-104. Dia A., Chauvel C., Bulourde M. and Gérard M. (2006). Eolian contribution to soils on Mount Cameroon: Isotopic and trace element records. Chem. Geol. 226, 232-252. Rydell H.S. and Prospero J.M. (1972). Uranium and thorium concentrations in wind-borne Saharan dust over the western equatorial north atlantic ocean. EPSL 14, 397-402.
PIXE study of Cuban quaternary paleoclimate geological samples and speleothems.

PubMed

Montero, M E; Aspiazu, J; Pajón, J; Miranda, S; Moreno, E

2000-02-01

PIXE elemental analysis of sediments, speleothems, and other geological formations related to the karst of the Sierra de San Carlos is presented. The similarity of the elemental composition of the sediments studied, as well as the alluvial regime which created them, indicate their common origin at each location. The Sr/Ca concentration ratio of a stalactite indicates that the average atmospheric temperature 12,000 and 18,000 years B.P. was colder than that of 6000 years B.P.
Measurements of natural uranium concentration and isotopic composition with permil-level precision by inductively coupled plasma-quadrupole mass spectrometry

NASA Astrophysics Data System (ADS)

Shen, Chuan-Chou; Lin, Huei-Ting; Chu, Mei-Fei; Yu, Ein-Fen; Wang, Xianfeng; Dorale, Jeffrey A.

2006-09-01

A new analytical technique using inductively coupled plasma-quadrupole mass spectrometry (ICP-QMS) has been developed that produces permil-level precision in the measurement of uranium concentration ([U]) and isotopic composition (δ234U) in natural materials. A 233U-236U double spike method was used to correct for mass fractionation during analysis. To correct for ratio drifting, samples were bracketed by uranium standard measurements. A sensitivity of 6-7 × 108 cps/ppm was generated with a sample solution uptake rate of 30 μL/min. With a measurement time of 15-20 min, standards of 30-ng uranium produced a within-run precision better than 3‰ (±2 R.S.D.) for δ234U and better than 2‰ for [U]. Replicate measurements made on standards show that a between-run reproducibility of 3.5‰ for δ234U and 2‰ for [U] can be achieved. ICP-QMS data of δ234U and [U] in seawater, coral, and speleothem materials are consistent with the data measured by other ICP-MS and TIMS techniques. Advantages of the ICP-QMS method include low cost, easy maintenance, simple instrumental operation, and few sample preparation steps. Sample size requirements are small, such as 10-14 mg of coral material. The results demonstrate that this technique can be applied to natural samples with various matrices.
Seventh Annual V. M. Goldschmidt Conference

NASA Technical Reports Server (NTRS)

1997-01-01

Topics considered include: Subduction of the Aseismic Cocos Ridge Displaced Magma Sources Beneath the Cordillera de Talamanca, Costa Rica; Topography of Transition Zone Discontinuities: A Measure of 'Olivine' Content and Evidence for Deep Cratonic Roots; Uranium Enrichment in Lithospheric Mantle: Case Studies from French Massif Central; Rare-Earth-Element Anomalies in the Decollement Zone of the nankai Accretionary Prism, Japan: Evidence of Fluid Flow?; Rare Earth Elements in Japanese Mudrocks: The Influence of Provenance; The Evolution of Seawater Strontium Isotopes in the Last Hundred Million Years: Reinterpretation and Consequences for Erosion and Climate Models; From Pat to Tats: The Lead Isotope Legacy in the Studies of the Continental Crust-Upper Mantle System; Geochronology of the Jack Hills Detrital Zircons by Precise Uranium-Lead Isotope-Dilution Analysis of Crystal Fragments; Iridium in the Oceans; The Helium-Heat-Lead Paradox; Control of Distribution Patterns of Heavy Metals in Ganga Plain Around Kanpur Region, India, by Fluvial Geomorphic Domains; Geochemical and Isotopic Features of Ferrar Magmatic Provience (Victoria Land, Antarctica); Rare Earth Elements in Marine Fine-Grained Sediments from the Northwestern Portuguese Shelf (Atlantic); Aspects of Arc Fluxes; General Kinetic Model for Dolomite Precipitation Rate with Application to the Secular History of Seawater Composition; High-Precision Uranium-series Chronology from Speleothems; Trace-Element Modeling of Aqueous Fluid-Peridotite Interaction in the Mantle Wedge of Subduction Zones; Rainfall Variations in Southeastern Australia over the Last 500,000 Years from Speleothem Deposition; The Role of Water in High-Pressure Fluids; The Kinetic Conditions of Metamorphic Minearogenesis: Evidence from Minerals and Assemblages.
A 500-year seasonally resolved δ18O and δ13C, layer thickness and calcite aspect record from a speleothem deposited in the Han-sur-Lesse cave, Belgium

NASA Astrophysics Data System (ADS)

Van Rampelbergh, M.; Verheyden, S.; Allan, M.; Quinif, Y.; Cheng, H.; Edwards, L. R.; Keppens, E.; Claeys, P.

2015-06-01

Speleothem δ18O and δ13C signals enable climate reconstructions at high resolution. However, scarce decadal and seasonally resolved speleothem records are often difficult to interpret in terms of climate due to the multitude of factors that affect the proxy signals. In this paper, a fast-growing (up to 2 mm yr-1) seasonally laminated speleothem from the Han-sur-Lesse cave (Belgium) is analyzed for its δ18O and δ13C values, layer thickness and changes in calcite aspect. The studied record covers the period between AD 2001 and 1479 as indicated by layer counting and confirmed by 20 U / Th ages. The Proserpine proxies are seasonally biased and document drier (and colder) winters on multidecadal scales. Higher δ13C signals reflect increased prior calcite precipitation (PCP) and lower soil activity during drier (and colder) winters. Thinner layers and darker calcite relate to slower growth and exist during drier (and colder) winter periods. Exceptionally dry (and cold) winter periods occur from 1565 to 1610, at 1730, from 1770 to 1800, from 1810 to 1860, and from 1880 to 1895 and correspond to exceptionally cold periods in historical and instrumental records as well as European winter temperature reconstructions. More relative climate variations, during which the four measured proxies vary independently and display lower amplitude variations, occur between 1479 and 1565, between 1610 and 1730, and between 1730 and 1770. The winters during the first and last periods are interpreted as relatively wetter (and warmer) and correspond to warmer periods in historical data and in winter temperature reconstructions in Europe. The winters in the period between 1610 and 1730 are interpreted as relatively drier (and cooler) and correspond to generally colder conditions in Europe. Interpretation of the seasonal variations in δ18O and δ13C signals differs from that on a decadal and multidecadal scale. Seasonal δ18O variations reflect cave air temperature variations and suggest a 2.5 °C seasonality in cave air temperature during the two relatively wetter (and warmer) winter periods (1479-1565 and 1730-1770), which corresponds to the cave air temperature seasonality observed today. Between 1610 and 1730, the δ18O values suggest a 1.5 °C seasonality in cave air temperature, indicating colder summer temperatures during this drier (and cooler) interval. The δ13C seasonality is driven by PCP and suggests generally lower PCP seasonal effects between 1479 and 1810 compared to today. A short interval of increased PCP seasonality occurs between 1600 and 1660, and reflects increased PCP in summer due to decreased winter recharge.
Estimated Marine Residence Times for Drowned Barbadian Paleoreefs

NASA Astrophysics Data System (ADS)

Mey, J. L.

2008-12-01

Fossil corals are used to estimate past sea level and also to calibrate 14C ages with the aid of U-Th and U-Pa dating methods. These coral fossils have often been subaerially exposed and thus are affected by diagenesis during their initial interaction with fresh water. In an effort to understand when such disequilibria in fossil coral reefs occurred, we have quantified our 'dissolution-cum-adsorption' model (Mey, 2008) for the uranium series disequilibria using a geometrical construction, based on the evolution of the activities in a 230Th/238U versus 234U/238U diagram for closed versus open systems. The traditional age equations for the uranium-series with excess daughters have been used to construct a relationship between (i) the angles of the equal age lines in the 230Th/238U versus 234U/238U activity diagrams, and (ii) the quantified angles of the regressed lines of several uranium series disequilibria trends from Barbados. Our results indicate that the severity of the Barbados uranium series disequilibria is not only explained by 234U and 230Th addition, but may also reflect a loss of 238U through dissolution of coral skeletal structure. The net effect is 238U removal, whereas 234U and 230Th remain; thus, the disequilibria for the extant coral increase the excess daughters' ratio. Our results further indicate that the activity of 234U is reduced (compared to 230Th), as would be expected in regard to the lower mobility of trapped 230Th. It is proposed that the major dissolution that caused the uranium series disequilibria occurred during one relatively short-lived event when the paleoreefs experienced the very first freshwater exposure. During this event, the diagenetic potential was at its maximum for redistribution of the uranium series; this then caused the 234U and the 230Th to behave in a systematic way, resulting in linear trends. The linear trends in the open system uranium series were set early, as shown in the 230Th/238U versus 234U/238U activity diagrams. The timing of the first exposure of the freshwater in the reefs is calculated based on the results of our new model. From the relationship between, (i) dissolution, (ii) in-grown 230Th, and (iii) excess 234U, we derived that the 60,000 old Marine Isotope stage 3 (MIS 3) reef was exposed to freshwater 36-38,000 years after growth in the marine environment. We have calculated these 'marine residence times' for the MIS 3 5a, 5c, 5e, 6.0, 7a and 7c reefs; our results correspond with the duration of the sea level high stand in each of the stages. References: Mey, J. L., (2008) The Uranium Series Diagenesis and the Morphology of Drowned Barbadian Paleoreefs, PhD dissertation, 325pp: Graduate Center, City University of New York, New York.

77 FR 213 - United States Savings Bonds, Series EE and I

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-04

... (APA). Because this rule relates to United States securities, which are contracts between Treasury and the owner of the security, this rule falls within the contract exception to the APA, 5 U.S.C. 553(a)(2). As a result, the notice, public comment, and delayed effective date provisions of the APA are...
The timber resources of West Virginia

Treesearch

Roland H. Ferguson

1964-01-01

To provide up-to-date information about the forest resources of the Nation, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of the various states. This is a report on the latest forest resurvey of West Virginia, made by the Northeastern Forest Experiment Station. It supersedes a report published in 1952, which...
North wall, central part, showing partial partition wall at left. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

North wall, central part, showing partial partition wall at left. This area is labeled Pioneering Research on drawing copy NV-35-B-5 (submitted with HABS No. NV-35-B) (series 2 of 4) - Bureau of Mines Metallurgical Research Laboratory, Original Building, Date Street north of U.S. Highway 93, Boulder City, Clark County, NV
Constraints on the Miocene landscape evolution of the Eastern Alps from the Kalkspitze region, Niedere Tauern (Austria)

NASA Astrophysics Data System (ADS)

Dertnig, Florian; Stüwe, Kurt; Woodhead, Jon; Stuart, Finlay M.; Spötl, Christoph

2017-12-01

In order to unravel aspects of the Miocene landscape evolution of the eastern European Alps, we present geomorphic and isotopic data from the western Niedere Tauern region (Austria). The region is critical for such interpretations, because it is one of the few regions along the topographic axis of the Eastern Alps where the highest peaks (up to 2500 m a.s.l.) are dominated by limestone. As such, the region contains a record of Miocene landscape-forming events that survived the Pleistocene glaciations, not preserved elsewhere in the central Eastern Alps. This record includes karst caves, karstified planation surfaces and crystalline fluvial pebbles (Augenstein Formation) preserved on planation surfaces and in karst caves. Caves in the region occur in three distinct levels that correlate with well-known cave levels in the Northern Calcareous Alps, although they are somewhat higher in the Niedere Tauern. In part, these cave elevations also correlate with three planation surfaces and knickpoints of major streams draining the region, testifying their pre-glacial origin. We report details of a karst cave (Durchgangshöhle) from the highest cave level located at 2340 m a.s.l. In this cave, allochthonous fluvial gravels are present, overgrown by speleothems. One speleothem yielded an early middle Pleistocene U-Pb age (682 ± 17 ka). We regard this as a minimum age for the erosion of the fluvial cave deposits during Marine Isotope Stages 17 or 16. Carbon and oxygen isotope data of these speleothems imply a climate that is consistent with this interpretation. Cosmogenic 21Ne data of fluvial quartz clasts collected from the surface on plateaus of the Northern Calcareous Alps suggest minimum exposure durations of 115 and 262 ka. They probably reflect successive exposure since removal of the sediment cover of the Oligocene Augenstein Formation during the Pleistocene. While our geochronological data fail to record aspects of the earlier Miocene uplift history, they are consistent with the overall geomorphic history inferred from the geomorphic markers. This suggests that the Niedere Tauern share a common uplift history with the Northern Calcareous Aps and implies a moderate south-north topographic gradient that has been maintained since the Miocene.
A 500 year seasonally resolved δ18O and δ13C, layer thickness and calcite fabric record from a speleothem deposited in equilibrium of the Han-sur-Lesse cave, Belgium

NASA Astrophysics Data System (ADS)

Van Rampelbergh, M.; Verheyden, S.; Allan, M.; Quinif, Y.; Cheng, H.; Edwards, L.; Keppens, E.; Claeys, P.

2014-10-01

Speleothem δ18O and δ13C signals have already proven to enable climate reconstructions at high resolution. However, seasonally resolved speleothem records are still scarce and often difficult to interpret in terms of climate due to the multitude of factors that can affect the proxy signals. In this paper, a fast growing (up to 2 mm yr-1) seasonally laminated speleothem from the Han-sur-Lesse cave (Belgium) is analyzed for its δ18O and δ13C values, layer thickness and changes in calcite fabric. The studied part of the speleothem covers the most recent 500 years as indicated by layer counting and confirmed by 20 U/Th-ages. Epikarst recharge occurs mainly in winter and lesser during spring and fall. a good correlation can be established between lower winter temperatures and lower winter precipitation (DJF) based on the measured data by the Belgian meteorological institute since 1833 indicating that a dry winter is also a cold winter. Colder and dryer winters cause lower winter recharge and generally drier conditions in the cave. Lower winter recharge decreases the amount of isotopically light (δ18O) winter precipitation added to the epikarst in comparison to the heavier spring and fall waters, which leads to a net increase in δ18O value of the water in the epikarst. Increased δ18O values in the Proserpine are consequently interpreted to reflect colder and dryer winters. Higher δ13C signals are interpreted to reflect increased prior calcite precipitation (PCP) due to colder and dryer winters, when recharge is lower. Thinner layers and darker calcite relate to slower growth and occur when drip rates are low and when the drip water calcium ion concentration is low due to increased PCP, both caused by lower recharge during periods with colder and dryer winters. Exceptionally cold and dry winters cause the drip discharge to decrease under a certain threshold value inducing anomalies in the measured proxy records. Such anomalies occur from 1565 to 1610, from 1770 to 1800, from 1810 to 1860 and from 1880 to 1895 and correspond with exceptionally cold periods in proxy-based, historical and instrumental records and may relate to different factors such as negative winter NAO phases, lower solar irradiance and/or volcanic eruptions. When the discharge threshold is not reached, lower amplitude variations are observed such as between 1479 and 1565 and between 1730 and 1770 with two periods of relatively warmer and wetter winters. Between 1610 and 1730 a period of relatively cooler and dryer winters occurs and may relate to a decrease in solar irradiance during the Maunder Minimum (1640-1714). Seasonal δ18O variations indicate a 2.5 °C seasonality in cave air temperature during the two periods with warmer and wetter winters (1479-1565 and 1730-1770), and correspond to the cave air temperature seasonality observed today. a smaller 1.5 °C seasonality in cave air temperature occurs during the interval with colder and wetter winters between 1610 and 1730 and suggests colder summers. The δ13C seasonal changes suggest that the seasonality in discharge was lower than the one observed today with a short interval of increased seasonality between 1600 and 1660 reflecting stronger summer PCP-effects due to decreased winter recharge.
Radiocarbon application in environmental science and archaeology in Croatia

NASA Astrophysics Data System (ADS)

Krajcar Bronić, I.; Obelić, B.; Horvatinčić, N.; Barešić, J.; Sironić, A.; Minichreiter, K.

2010-07-01

Radiocarbon is a cosmogenic radioisotope equally distributed throughout the troposphere and biosphere. This fact enables its most common application—radiocarbon dating. Natural equilibrium of radiocarbon has been disturbed by diverse anthropogenic activities during the last ˜150 years, enabling also the use of 14C in various environmental applications. Here we present three types of studies by using 14C that were performed in the Zagreb Radiocarbon Laboratory. 14C in atmospheric CO 2 has been monitored at several sites with various anthropogenic influences and the difference between the clean-air sites, the industrial city and the vicinity of a nuclear power plant has been established. 14C has been applied in geochronology of karst areas, especially in dating of tufa, speleothems and lake sediments, as well as in studies of geochemical carbon cycle. 14C has been used in various archaeological studies, among which the dating of the early Neolithic settlements in Croatia is presented. In these studies 14C was measured by radiometric techniques, i.e., by gas proportional counting and more recently by liquid scintillation counting (LSC). Two sample preparation techniques for LSC measurement were used: benzene synthesis for archaeological dating and other applications that require better precision, and direct absorption of CO 2 for monitoring purposes. The presented results show that various studies by using 14C can be successfully performed by the LSC technique, providing a large enough sample (>1 g of carbon).
Microbial Community Biofabrics in a Geothermal Mine Adit▿ †

PubMed Central

Spear, John R.; Barton, Hazel A.; Robertson, Charles E.; Francis, Christopher A.; Pace, Norman R.

2007-01-01

Speleothems such as stalactites and stalagmites are usually considered to be mineralogical in composition and origin; however, microorganisms have been implicated in the development of some speleothems. We have identified and characterized the biological and mineralogical composition of mat-like biofabrics in two novel kinds of speleothems from a 50°C geothermal mine adit near Glenwood Springs, CO. One type of structure consists of 2- to 3-cm-long, 3- to 4-mm-wide, leather-like, hollow, soda straw stalactites. Light and electron microscopy indicated that the stalactites are composed of a mineralized biofabric with several cell morphotypes in a laminated form, with gypsum and sulfur as the dominant mineral components. A small-subunit rRNA gene phylogenetic community analysis along the stalactite length yielded a diverse gradient of organisms, with a relatively simple suite of main constituents: Thermus spp., crenarchaeotes, Chloroflexi, and Gammaproteobacteria. PCR analysis also detected putative crenarchaeal ammonia monooxygenase subunit A (amoA) genes in this community, the majority related to sequences from other geothermal systems. The second type of speleothem, dumpling-like rafts floating on a 50°C pool on the floor of the adit, showed a mat-like fabric of evidently living organisms on the outside of the dumpling, with a multimineral, amorphous, gypsum-based internal composition. These two novel types of biofabrics are examples of the complex roles that microbes can play in mineralization, weathering, and deposition processes in karst environments. PMID:17693567
The Soil Series in Soil Classifications of the United States

NASA Astrophysics Data System (ADS)

Indorante, Samuel; Beaudette, Dylan; Brevik, Eric C.

2014-05-01

Organized national soil survey began in the United States in 1899, with soil types as the units being mapped. The soil series concept was introduced into the U.S. soil survey in 1903 as a way to relate soils being mapped in one area to the soils of other areas. The original concept of a soil series was all soil types formed in the same parent materials that were of the same geologic age. However, within about 15 years soil series became the primary units being mapped in U.S. soil survey. Soil types became subdivisions of soil series, with the subdivisions based on changes in texture. As the soil series became the primary mapping unit the concept of what a soil series was also changed. Instead of being based on parent materials and geologic age, the soil series of the 1920s was based on the morphology and composition of the soil profile. Another major change in the concept of soil series occurred when U.S. Soil Taxonomy was released in 1975. Under Soil Taxonomy, the soil series subdivisions were based on the uses the soils might be put to, particularly their agricultural uses (Simonson, 1997). While the concept of the soil series has changed over the years, the term soil series has been the longest-lived term in U.S. soil classification. It has appeared in every official classification system used by the U.S. soil survey (Brevik and Hartemink, 2013). The first classification system was put together by Milton Whitney in 1909 and had soil series at its second lowest level, with soil type at the lowest level. The second classification system used by the U.S. soil survey was developed by C.F. Marbut, H.H. Bennett, J.E. Lapham, and M.H. Lapham in 1913. It had soil series at the second highest level, with soil classes and soil types at more detailed levels. This was followed by another system in 1938 developed by M. Baldwin, C.E. Kellogg, and J. Thorp. In this system soil series were again at the second lowest level with soil types at the lowest level. The soil type concept was dropped and replaced by the soil phase in the 1950s in a modification of the 1938 Baldwin et al. classification (Simonson, 1997). When Soil Taxonomy was released in 1975, soil series became the most detailed (lowest) level of the classification system, and the only term maintained throughout all U.S. classifications to date. While the number of recognized soil series have increased steadily throughout the history of U.S. soil survey, there was a rapid increase in the recognition of new soil series following the introduction of Soil Taxonomy (Brevik and Hartemink, 2013). References Brevik, E.C., and A.E. Hartemink. 2013. Soil maps of the United States of America. Soil Science Society of America Journal 77:1117-1132. doi:10.2136/sssaj2012.0390. Simonson, R.W. 1997. Evolution of soil series and type concepts in the United States. Advances in Geoecology 29:79-108.
U-series constraints on the Holocene human presence in the Cuatro Cienegas basin, Mexico

NASA Astrophysics Data System (ADS)

Noble, S. R.; Felstead, N.; Gonzalez, S.; Leng, M. J.; Metcalfe, S. E.; Patchett, P. J.

2010-12-01

U-series tufa ages dating a human trackway have been obtained, part of a larger Late Pleistocene - Recent palaeoclimate and human occupation study of the Cuatro Cienegas basin, NE Mexico. Our analytical approach, including tracer calibration, couples aspects of what we consider best practice in the U-series community with our U-Pb experiences which includes the EarthTime U-Pb tracer calibration exercise. The recently discovered trackway is near a small hydrothermal pool within the basin [1], an ecologically highly significant oasis in the Chihuahuan desert. The oasis comprises >200 freshwater hydrothermal pools and a river system, and the related ecosystem hosts >70 endemic species[2]. Pools are fed by waters that circulate a deep karstic system and that originate in the surrounding upper Jurassic-lower Cretaceous Sierra Madre Oriental mountains (>3000m) [3]. The area hosted nomadic hunter-gatherers during the Holocene, and possibly as early as Late Pleistocene (~12 ka BP). Despite the basin's ecological significance, only three palaeoenvironmental studies have been published to date, and limited geochronological constraints are available. A pollen study of drill core through peats and tufas proximal to the pools suggested a long period of climatic stability and biogeographic isolation[4], a notion supported by the large number of endemic species, but other palynological and plant macrofossil data suggest that large climatic changes occurred post Late Pleistocene [5]. The 10 m long in situ trackway is preserved in tufa and five samples from the uppermost surfaces were analysed to date the footprints. The tufas comprise clean carbonate with no petrographic evidence of replacement and little contaminant detrital material (on some exposed upper surfaces). Powdered tufa was processed following [6-8], and analysed by TIMS (Triton, U) and MC-ICP-MS (Th, Nu HR), although our future analyses will primarily be obtained on a Neptune. Samples were spiked with a 229Th/236U tracer calibrated against gravimetric solutions prepared from Ames high-purity Th metal crystal and CRM 112a U metal ingot rather than natural materials of assumed secular equilibrium. ICP-MS mass bias and Faraday-SEM gain was monitored using CRM 112a and an in-house 229Th-230Th-232Th solution. Most samples have relatively high U contents (~2 ppm U), moderate [230Th/232Th] = 29-44, and initial [234U/238U] ~ 1.92. We obtain an age of 7.24 ± 0.13 ka BP for this trackway based on an average of two samples of the uppermost tufa surface. Depth profiling of one sample shows consistently increasing age downwards (~370 a/cm). [1] Gonzalez, A.H.G. et al., 2006, Ichnos 16, 12-24;[2] Souza, V. et al., 2006, PNAS 103, 6565-6570; [3] Johannesson, K.H. et al., 2004, J.S.Am.Earth Sci. 17, 171-180; [4] Meyer, E. 1973, Ecology 54, 982-995; [5] Minckley, T.A. & Jackson, S. 2008. J. Biogeography 35, 188-190; [6] Edwards, R.L. et al., 1987, EPSL 81, 175-192; [8] Cheng, H. et al., 2000, Chem. Geol. 169, 17-33; [8] Potter, E.K. et al., 2005, EPSL 247, 10-17.
The timber resources of New Jersey

Treesearch

Roland H. Ferguson; Carl E. Mayer

1974-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U.S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. The first forest survey of New Jersey was made in 1955 by the Northeastern...
The timber resources of southern New England

Treesearch

Neal P. Kingsley

1974-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U.S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the nation. A resurvey of the forest resources of the three southern New England...
Timber resources of Ohio

Treesearch

Neal P. Kingsley; Carl E. Mayer

1970-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. A resurvey of the timber resources of Ohio was made in 1966 and 1967 by...
The timber resources of Maine

Treesearch

Roland H. Ferguson; Neal P. Kingsley

1972-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. The first forest survey of Maine was made in 1954-58 by the Northeastern...
The timber resources of New York

Treesearch

Roland H. Ferguson; Carl E. Mayer

1970-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U.S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. The first forest survey of New York was made in 1948-50 by the...
The timber resources of Delaware

Treesearch

Roland H. Ferguson; Carl E. Mayer

1974-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U.S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. The first forest survey of Delaware was made in 1956 by the Northeastern...
Novel Combinatorial Immunotherapy for Melanoma

DTIC Science & Technology

2015-10-01

table discussions regarding career development. 5. The department of Microbiology & Molecular Genetics hosts once a month seminar series regarding...ORGANIZATION: Medical college of Wisconsin Hanover, NH 03755 REPORT DATE: Oct 2015 TYPE OF REPORT: Annual PREPARED FOR: U.S. Army Medical ...NAME(S) AND ADDRESS(ES) Medical College of Wisconsin Inc, 8701 Watertown Plank Rd. n 8. PERFORMING ORGANIZATION REPORT NUMBER Milwaukee, WI 53226
The timber resources of Maryland

Treesearch

Roland H. Ferguson

1967-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of the states to provide up-to-date information about the forest resources of the Nation. A resurvey of the timber resources in Maryland was made in 1962-63 by the...
The timber resources of Pennsylvania

Treesearch

Roland H. Ferguson

1968-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. A resurvey of the timber resources in Pennsylvania was made in 1963-65 by...
The timber resources of Vermont

Treesearch

Neal P. Kingsley; Joseph E. Barnard

1968-01-01

Under the authority of the McSweeney-McNary Forest Research Act of May 22, 1928, and subsequent amendments, the Forest Service, U. S. Department of Agriculture, conducts a series of continuing forest surveys of all states to provide up-to-date information about the forest resources of the Nation. A resurvey of the timber resources in Vermont was made in 1965 and 1966...
Evidence for a fundamental and pervasive shift away from nature-based recreation

PubMed Central

Pergams, Oliver R. W.; Zaradic, Patricia A.

2008-01-01

After 50 years of steady increase, per capita visits to U.S. National Parks have declined since 1987. To evaluate whether we are seeing a fundamental shift away from people's interest in nature, we tested for similar longitudinal declines in 16 time series representing four classes of nature participation variables: (i) visitation to various types of public lands in the U.S. and National Parks in Japan and Spain, (ii) number of various types of U.S. game licenses issued, (iii) indicators of time spent camping, and (iv) indicators of time spent backpacking or hiking. The four variables with the greatest per capita participation were visits to Japanese National Parks, U.S. State Parks, U.S. National Parks, and U.S. National Forests, with an average individual participating 0.74–2.75 times per year. All four time series are in downtrends, with linear regressions showing ongoing losses of −1.0% to −3.1% per year. The longest and most complete time series tested suggest that typical declines in per capita nature recreation began between 1981 and 1991, are proceeding at rates of −1.0% to −1.3% per year, and total to date −18% to −25%. Spearman correlation analyses were performed on untransformed time series and on transformed percentage year-to-year changes. Results showed very highly significant correlations between many of the highest per capita participation variables in both untransformed and in difference models, further corroborating the general downtrend in nature recreation. In conclusion, all major lines of evidence point to an ongoing and fundamental shift away from nature-based recreation. PMID:18250312

8.2 ky event associated with high precipitation in the eastern Caribbean

NASA Astrophysics Data System (ADS)

Winter, A.; Vieten, R.; Miller, T.; Mangini, A.; Scholz, D.

2013-12-01

We present data from speleothems collected in Venezuela and Puerto Rico showing that the eastern Caribbean was anomalously moist during the 8.2ka event. Evidence from high-resolution analyses of Greenland ice core (GISP2) shows that at the same time northern Europe and the north Atlantic were cooler by 3 - 6° C. The trigger for the 8.2ka event is thought to be pulsed meltwater discharges from a multi-event drainage of proglacial lakes associated with the decaying Laurentide Ice Sheet margin. The meltwater apparently slowed the thermohaline circulation decreasing warmth to northern Europe. At the same time moisture transfer to the northern latitudes may have slowed resulting in the observed lower latitude precipitation patterns. The eastern Caribbean seems to be especially sensitive to the changes in the strength of the Atlantic meridional overturning circulation (AMOC). Higher precipitation values may also have increased lowland flooding along the coastal areas of north eastern South America, already affected by early Holocene sea-level change, and are linked to social territory reshuffling which stimulated the earliest migrations into the Caribbean Archipelago shortly afterwards. Our age models based on precise MC-ICPMS 230Th/U-dating indicate that the eastern Caribbean stalagmites all grew at about the same rate of 15 cm through the 8.2 ka event, much faster than during any other growth period, except today when they are also growing at an accelerated rate.
Combined ESR/U-series chronology of Acheulian hominid-bearing layers at Trinchera Galería site, Atapuerca, Spain.

PubMed

Falguères, Christophe; Bahain, Jean-Jacques; Bischoff, James L; Pérez-González, Alfredo; Ortega, Ana Isabel; Ollé, Andreu; Quiles, Anita; Ghaleb, Bassam; Moreno, Davinia; Dolo, Jean-Michel; Shao, Qingfeng; Vallverdú, Josep; Carbonell, Eudald; Bermúdez de Castro, Jose María; Arsuaga, Juan Luis

2013-08-01

The Sierra de Atapuerca, northern Spain, is known from many prehistoric and palaeontological sites documenting human prehistory in Europe. Three major sites, Gran Dolina, Galería and Sima del Elefante, range in age from the oldest hominin of Western Europe dated to 1.1 to 1.3 Ma (millions of years ago) at Sima del Elefante to c.a. 0.2 Ma on the top of the Galería archaeological sequence. Recently, a chronology based on luminescence methods (Thermoluminescence [TL] and Infrared Stimulated Luminescence [IRSL]) applied to cave sediments was published for the Gran Dolina and Galería sites. The authors proposed for Galería an age of 450 ka (thousands of years ago) for the units lower GIII and GII, suggesting that the human occupation there is younger than the hominid remains of Sima de los Huesos (>530 ka) around 1 km away. In this paper, we present new results obtained by combined Electron Spin Resonance/Uranium-series (ESR/U-series) dating on 20 herbivorous teeth from different levels at the Galería site. They are in agreement with the TL results for the upper part of the stratigraphic sequence (GIV and GIIIb), in the range of between 200 and 250 ka. But for the GIIIa to GIIb levels, the TL ages become abruptly older by 200 ka while ESR ages remain relatively constant. Finally, the TL and ESR data agree in the lowest part of the section (GIIa); both fall in the range of around 350-450 ka. Our results suggest a different interpretation for the GII, GIII and GIV units of Galería and the upper part of Gran Dolina (TD10 and TD11) than obtained by TL. The ESR/U-series results are supported by a Bayesian analysis, which allows a better integration between stratigraphic information and radiometric data. Copyright © 2013 Elsevier Ltd. All rights reserved.
Combined ESR/U-series chronology of Acheulian hominid-bearing layers at Trinchera Galería site, Atapuerca, Spain

USGS Publications Warehouse

Falguères, Christophe; Bahain, Jean-Jacques; Bischoff, James L.; Pérez-González, Alfredo; Ortega, Ana Isabel; Ollé, Andreu; Quilles, Anita; Ghaleb, Bassam; Moreno, Davinia; Dolo, Jean-Michel; Shao, Qingfeng; Vallverdú, Josep; Carbonell, Eudald; María Bermúdez de Castro, Jose; Arsuaga, Juan Luis

2013-01-01

The Sierra de Atapuerca, northern Spain, is known from many prehistoric and palaeontological sites documenting human prehistory in Europe. Three major sites, Gran Dolina, Galería and Sima del Elefante, range in age from the oldest hominin of Western Europe dated to 1.1 to 1.3 Ma (millions of years ago) at Sima del Elefante to c.a. 0.2 Ma on the top of the Galería archaeological sequence. Recently, a chronology based on luminescence methods (Thermoluminescence [TL] and Infrared Stimulated Luminescence [IRSL]) applied to cave sediments was published for the Gran Dolina and Galería sites. The authors proposed for Galería an age of 450 ka (thousands of years ago) for the units lower GIII and GII, suggesting that the human occupation there is younger than the hominid remains of Sima de los Huesos (>530 ka) around 1 km away. In this paper, we present new results obtained by combined Electron Spin Resonance/Uranium-series (ESR/U-series) dating on 20 herbivorous teeth from different levels at the Galería site. They are in agreement with the TL results for the upper part of the stratigraphic sequence (GIV and GIIIb), in the range of between 200 and 250 ka. But for the GIIIa to GIIb levels, the TL ages become abruptly older by 200 ka while ESR ages remain relatively constant. Finally, the TL and ESR data agree in the lowest part of the section (GIIa); both fall in the range of around 350–450 ka. Our results suggest a different interpretation for the GII, GIII and GIV units of Galería and the upper part of Gran Dolina (TD10 and TD11) than obtained by TL. The ESR/U-series results are supported by a Bayesian analysis, which allows a better integration between stratigraphic information and radiometric data.
Organic trace analysis of lignin phenols in speleothems using UHPLC-ESI-HRMS and their use as vegetation proxy

NASA Astrophysics Data System (ADS)

Hitzemann, Inken; Hoffmann, Thorsten

2016-04-01

To understand the climate of the past, it is necessary to get information not only about temperature and precipitation, but also about the vegetation. In contrast to the vegetation proxies used in speleothems so far, like δ13C, the analysis of lignin can provide information not only about the quantity, but also about the type of the regional vegetation. Lignin is widely used as vegetation proxy in sediment samples and natural waters,[1] but there are no methods to analyse lignin in speleothems yet. Lignin is one of the main constituents of wood and woody plants. It is a biopolymer that consists mainly of three monomers, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol. The proportion of these three monomers varies with the type of vegetation, for example gymnosperms, angiosperms or herbaceous plants.[2] To analyse the composition of lignin particles in speleothems, it is necessary to extract the speleothem samples, to digest the lignin polymer in order to split it into its monomers, also called lignin phenols, and then to enrich and quantify these lignin phenols. In the method we are presenting here, stalagmite samples are acid digested and the acidic solution is extracted by solid phase extraction. The resulting organic fraction is submitted to an alkaline cupric oxide oxidation using a microwave digestion system.[3] The oxidation products are enriched by solid phase extraction and analysed by ultra high performance liquid chromatography coupled to electrospray high resolution mass spectrometry. We present the limits of detection and quantification, reproducibility and recovery rates as well as first proof-of-principle results from stalagmite samples from the Herbstlabyrinth-Adventshöhle in Germany. References: [1] S. M. Tareq, H. Kitagawa, K. Ohta, Holocene Lake Records: Patterns, Impacts, Causes And Societal Response Selected Papers from the 3rd LIMPACS Conference, Chandigarh, India 2011, 229, 47-56. [2] C. N. Jex, G. H. Pate, A. J. Blyth, R. G. Spencer, P. J. Hernes, S. J. Khan, A. Baker, Quaternary Science Reviews 2014, 87, 46-59. [3] M. A. Goñi, S. Montgomery, Analytical chemistry 2000, 72, 3116-3121.
Speleothem records of acid sulphate deposition and organic carbon mobilisation

NASA Astrophysics Data System (ADS)

Wynn, Peter; Fairchild, Ian; Bourdin, Clement; Baldini, James; Muller, Wolfgang; Hartland, Adam; Bartlett, Rebecca

2017-04-01

Dramatic increases in measured surface water DOC in recent decades have been variously attributed to either temperature rise, or destabilisation of long-term soil carbon pools following sulphur peak emissions status. However, whilst both drivers of DOC dynamics are plausible, they remain difficult to test due to the restricted nature of the available records of riverine DOC flux (1978 to present), and the limited availability of SO2 emissions inventory data at the regional scale. Speleothems offer long term records of both sulphur and carbon. New techniques to extract sulphur concentrations and isotopes from speleothem calcite have enabled archives of pollution history and environmental acidification to be reconstructed. Due to the large dynamic range in sulphur isotopic values from end member sources (marine aerosol +21 ‰ to continental biogenic emissions -30 ‰) and limited environmental fractionation under oxidising conditions, sulphur isotopes form an ideal tracer of industrial pollution and environmental acidification in the palaeo-record. We couple this acidification history to the carbon record, using organic matter fluorescence and trace metals. Trace metal ratios and abundance can be used to infer the type and size of organic ligand and are therefore sensitive to changes in temperature as a driver of organic carbon processing and biodegradation. This allows fluorescent properties and ratios of trace metals in speleothem carbonate to be used to represent both the flux of organic carbon into the cave as well as the degradation pathway. Here we present some of the first results of this work, exploring sulphur acidification as a mechanistic control on carbon solubility and export throughout the twentieth century.
Earliest humans in Europe: The age of TD6 Gran Dolina, Atapuerca, Spain

USGS Publications Warehouse

Falgueres, Christophe; Bahain, J.-J.; Yokoyama, Y.; Arsuaga, J.L.; Bermudez de Castro, Jose Maria; Carbonell, E.; Bischoff, J.L.; Dolo, J.-M.

1999-01-01

Hominid remains found in 1994 from the stratified Gran Dolina karst-filling at the Atapuerca site in NE Spain were dated to somewhat greater than 780 ka based on palaeomagnetic measurements, making these the oldest known hominids in Europe (sensu stricto). We report new ESR and U-series results on teeth from four levels of the Gran Dolina deposit which confirm the palaeomagnetic evidence, and indicate that TD6 (from which the human remains have been recovered) dates to the end of the Early Pleistocene. The results for the other levels are consistent with estimates based mainly on microfaunal evidence, and suggest that TD8, TD10 and TD11 date to the Middle Pleistocene. (C) 1999 Academic Press.
A multi-proxy reconstruction of Holocene climate change from Blessberg Cave, Germany

NASA Astrophysics Data System (ADS)

Breitenbach, Sebastian F. M.; Plessen, Birgit; Wenz, Sarah; Leonhardt, Jens; Tjallingii, Rik; Scholz, Denis; Jochum, Klaus Peter; Marwan, Norbert

2016-04-01

Although Holocene climate dynamics were relatively stable compared to glacial conditions, climatic changes had significant impact on ecosystems and human society on various timescales (Mayewski et al. 2004, Donges et al. 2015, Tan et al. 2015). Precious few high-resolution records on Holocene temperature and precipitation conditions in Central Europe are available (e.g., von Grafenstein et al. 1999, Fohlmeister et al. 2012). Here we present a speleothem-based reconstruction of past climate dynamics from Blessberg Cave, Thuringia, central Germany. Three calcitic stalagmites were recovered when the cave was discovered during tunneling operations in 2008. Samples BB-1, -2 and -3 were precisely dated by the 230Th/U-method, with errors between 10 and 160 years (2σ). The combined record covers large parts of the Holocene (10 - 0.4 ka BP). δ13C and δ18O were analysed at 100 μm resolution. To gain additional insights in infiltration conditions, Sr/Ca and S/Ca were measured on BB-1 and BB-3 using an Röntgenanalytik Eagle XXL μXRF scanner. Differences to other central European records (e.g., von Grafenstein et al. 1999, Fohlmeister et al. 2012) suggest complex interaction between multiple factors influencing speleothem δ18O in Blessberg Cave. Furthermore, no clear influence of the North Atlantic Oscillation on our proxies is found. However, a link across the N Atlantic realm is indicated by a centennial-scale correlation between Blessberg δ18O values and minerogenic input into lake SS1220 in Greenland over the last 5 ka (Olsen et al. 2012). In addition, recurrence analysis indicates an imprint of Atlantic Bond events on Blessberg δ18O values (Marwan et al. 2014), corroborating the suggested link with high northern latitudes. Larger runoff into the Greenland lake seems to be associated with lower δ18O, higher δ13C and S/Ca ratios, as well as lower Sr/Ca ratios in Blessberg Cave speleothems. This might be linked to lower local temperature and/or changes in precipitation seasonality. Opposing millennial scale trends with lowering S/Ca ratios and δ13C values but increasing Sr/Ca ratios calls for more than one controlling factor. Most likely, δ13C decreased through the Holocene due to afforestation, which in turn might have increased sulphate retention in the thickening soil cover (Frisia et al. 2005) and limited sulphur flux into the cave. Alternatively, marine sulfur flux could have diminished with winter wind intensities. However, additional data is required to clarify this hypothesis. A positive Sr/Ca trend through the Holocene might result from increasing prior calcite precipitation induced by a negative moisture balance in summer. References Breitenbach et al. (2012) Climate of the Past 8, 1765-1779 Donges et al. (2015) Climate of the Past 11, 709-741 Fohlmeister et al. (2012) Climate of the Past 8, 1751-1764 Frisia et al. (2005) EPSL 235, 729-740 Marwan et al. (2014) Geophysical Research Abstracts 16, EGU2014-8893 Mayewski et al. (2004) Quaternary Research 62, 243-255 Olsen et al. (2012) Nature Geoscience 5, 808-812 Tan et al. (2015) Scientific Reports 5:12284 von Grafenstein et al. (1999) Science 284, 1654-1657
The role of biophysical indicators in the reconstruction of long-term late-spring - summer temperatures for the region of Western Hungary and Eastern Austria

NASA Astrophysics Data System (ADS)

Kiss, Andrea; Wilson, Rob; Holawe, Franz; Strömmer, Elisabeth; Bariska, István.

2010-05-01

We present an almost 500-year May-July temperature reconstruction based on 24 biophysical series. 19 are vine-related series from Kőszeg, Szombathely and Sopron in Western Hungary (11 series, from 1580s onwards), Vienna, Klosterneuburg, Perchtoldsdorf (7 series; at present from 1520s onwards) in Eastern Austria and Bratislava in Western Slovakia (1 series, from 1770s onwards). At present, the first, largest group is the vine related indicators, where dates of blossoming (1 series), beginning of grape ripening (3 series), dates of full ripening (2 series), beginning of grapevine harvest (8 series), starting dates of pressing out the juice (1 series: at present 1520s onwards), starting dates of tax-collection (after the pressed juice: 1 series) and wine quality indices (3 series: from 1580s onwards) are also included. The second main group of 4 indicators applied in the analysis are grain-harvest related indicators from Western Hungary, such as dates for estimation of harvesting-shares which are strongly dependant on the beginning of grain harvesting (at present 2 series: from 1640s onwards) and dates of grain tax collection (2 series: from 1560s onwards). A third group, still in development, is mainly related to more natural vegetation, and is strongly dependent on the full ripening of oak acorns: the starting dates of woodland pasture (at present 1 series: from 1770s onwards). The above-mentioned historical series correlate well, over the 18th-19th century period, with Vienna May-July measured temperature (Böhm, et. al. 2009). The complicated nature of these historical data is described (e.g. with respect to the normality of the data distribution), and we present methods to transform and composite the data into a homogenous, homoscedastic time-series that can be used for proxy based calibration. Finally, a preliminary May-July temperature reconstruction is derived using modified dendrochronological methods. (see Leijonhufvud et al. 2009) The Kőszeg, Szombathely, Sopron and Bratislava series and all presented analyses were developed within the framework of the EU project 'Millenium'. The Austrian series are partly based on published series (Pribram 1938, Lauscher 1985, Strömmer 2003) although in some cases modified and extended for this study, as well as newly developed data. The present work is a continuation of the 'Analysis of late spring-summer temperatures for Western Hungary based on vine, grain tithes and harvest records', presented at the annual congress of EGU in 2009 (Kiss and Wilson 2009). References Böhm, R., Jones, P.D., Hiebl, J., Frank, D., Brunetti, M., Maugeri and M. 2009: The early instrumental warm-bias: a solution for long central European temperature series 1760-2007. Climatic Change, doi: 10.1007/s10584-009-9649-4. Kiss, A. and Wilson, R. 2009: Analysis of late spring-summer temperatures for Western Hungary based on vine, grain tithes and harvest records. Geophysical Research Abstracts Vol 11, EGU2009-10945-1. Lauscher, F. 1985: Beiträge zur Wetterchronik seit dem Mittelalter. In: Sitzungsberichte, Abtheilung II, Mathematische, Physikalische und Technische Wissenschaften, Band 194, Heft 1-3. pp. 93-131. Leijonhufvud, L., Wilson, R., Möberg, A., Söderberg, J., Retső, D. and Söderlind, U. 2009: Five centuries of Stockholm winter/spring temperatures reconstructed from documentary evidence and instrumental observations. Climatic Change, doi: 10.1007/s10584-009-9650-y. Pribram, A. F. 1938: Materialien zur Geschichte der Preise und Löhne in Österreich. Band. I. Carl Ueberreuters Verlag, Wien. pp. 364-370. Strömmer, E. 2003: Klima-Geschichte. Methoden der Rekonstruction und historische Perspektive. Ostösterreich 1700 bis 1830. Forschungen und Beiträge zur Wiener Stadtgescichte 39. Franz Deuticke, Wien. pp. 59-71.
A Bat's-Eye View of Holocene Climate Change in the Southwest: Resolving Ambiguities in Cave Isotopic Records

NASA Astrophysics Data System (ADS)

Cole, J. E.; Truebe, S. A.; Harrington, M. D.; Woodhead, J. D.; Overpeck, J. T.; Hlohowskyj, S.; Henderson, G. M.

2015-12-01

In dry environments, speleothems provide an outstanding archive of information on past climate change, particularly since lakes are typically absent or intermittent. Speleothem stable isotopes are widely used for climate reconstruction, but the isotope-climate relationship is complex in arid-region precipitation, and within-cave processes further complicate climate interpretations. Our isotope results from 3 southeastern Arizona caves, spanning the past 3.5-12 kyr, collectively indicate a weakening monsoon from 7kyr to present. These records exhibit substantial multidecadal-multicentury variability that is sometimes shared, and sometimes independent among caves. Strategies to overcome ambiguities in isotope records include long-term monitoring of cave dripwaters, multi-site comparisons, and multiproxy measurements. Monthly dripwater measurements from two caves spanning several years highlight substantial seasonal biases that create distinct differences in the climate sensitivity of individual cave records. These biases can lead to lack of correlation between records, but also creates opportunities for seasonally specific moisture reconstructions. New preliminary analyses suggest that elemental data can help to unravel the multivariate signal contained in speleothem oxygen isotope records.
Dry or wet in East Asia during North Atlantic cooling? New perspectives from multiproxy climate records and coupled model simulations

NASA Astrophysics Data System (ADS)

Zhang, H.; Griffiths, M. L.; Wu, S.; Kong, W.; Chiang, J. C. H.; Atwood, A. R.; Cheng, H.; Huang, J.; Xie, S.

2017-12-01

Chinese speleothem δ18Oc records have revealed that the Asian summer monsoon underwent pronounced millennial-scale variability during the last deglaciation, yet there is still debate as to what the δ18Oc signals represent. Traditionally, these δ18Oc records were interpreted as a proxy for regional rainfall variability via the East Asian Summer Monsoon (EASM), however, recent isotope-enabled model simulations have suggested that precipitation δ18O over central China is more a reflection of rainfall in the upstream region of the Indian monsoon. Therefore, despite the increased number of speleothem records emerging from the EASM region, we still lack a robust understanding of how local monsoon rainfall variability fluctuated in central China during the last deglaciation. To address this, here we present two new multiproxy speleothem records from Haozhu Cave (HZ), central China, during the deglaciation. HZ δ18Oc time series largely parallel those from other distal cave sites in China and India, suggesting that the oxygen isotopes are indeed dominated by upstream rainout. To inspect the local hydrology, we also examined Sr-Mg-Ba/Ca ratios and d13C. Interestingly, results show that during Heinrich Stadial 1 and the Younger Dryas, the d13C and trace elements decrease significantly, which we interpret to reflect higher cave recharge. Thus, despite a weakened Indian monsoon during these cooling events (inferred from the δ18Oc), our results suggest that central China was in fact wetter. To test this hypothesis, we examined past rainfall variability in China using CESM1.0.5 imposed with 1Sv of North Atlantic (NA) fresh water forcing. Similar to the proxies, results from these simulations demonstrate that south-central China was wetter following NA cooling, whilst northern China was drier. This `dipole' pattern can best be explained by a seasonally-lagged onset of the mei-yu stage of monsoon evolution. A later onset of mei-yu to midsummer during NA cooling would have resulted in a shorter midsummer stage, leaving south-central China wet at the expense of dry conditions to the north. Our proxy and model results thus support a recent hypothesis, that paleoclimate changes over East Asia reflect the timing and duration of its intraseasonal stages, modulated by the position of the westerlies relative to the Tibetan Plateau.
Investigation of the Biogenic Origin of Cave Pool Precipitates in the Guadalupe Mountains, NM Using Extracted Phospholipids and Other Biomarkers

NASA Astrophysics Data System (ADS)

Kooser, A. S.; Crossey, L.; Northup, D.; Spilde, M.; Melim, L.

2008-12-01

Biomarker analysis is an important tool for understanding biogenic carbonates. Past and present bacterial communities utilize chemical species present in the cave environments for metabolic processes and may directly or indirectly contribute to carbonate production. Paleo-communities of bacteria are preserved in speleothems (cave formations) called pool fingers. These speleothems range from 1-4 cm in diameter, 5- 50cm in length and contain alternating layers of micritic calcite and dog tooth spar. The outer portion of the finger can have a moonmilk coating. Pool fingers contain fossilized microbes that can be seen using scanning electron microscopy on etch samples. The lithified communities also leave behind fingerprints in the form of biomarkers. The biomarkers are extracted from pool fingers using a series of solvent washes; the products of each wash are analyzed using gas chromatography followed by gas chromatography/mass spectroscopy. Six samples including pool spar (abiotic speleothem) were examined using this technique. The moonmilk portion of the large pool finger from Cottonwood Cave contained several short-chained fatty acids (C16-C22), which are of microbial origin. In the polar fraction unknown hopanes were detected. The presence of a hopanes with short-chained fatty acids confirms the presence of bacterial biomarkers in the moonmilk portion of the pool finger. The pool spar sample (assumed to be abiotic) produced a different mass spectral pattern for the acid fraction and polar fraction. The acid fraction contains short-chain fatty acids (C16-22), but there are no hopanes present in the other fractions. The polar fraction for the polar spar is dominated by plant biomarkers producing the 'rainbow' spectra of C22 and higher chains. The pool finger, which is thought to be partially biogenic, contains both fossilized bacteria and bacteria biomarkers while the pool spar contains general biomarkers and plant biomarkers. The plant biomarkers found in the pool spar may have originated in the roots of the desert plants over the cave system. The presence of microbial biomarkers in the micritic layer of the pool finger and their absence in the pool spar provide support for the biogenicity of the micritic layers of cave pool fingers.
Tufa deposits sheltered by Inland notches as indicators of Quaternary denudation rates

NASA Astrophysics Data System (ADS)

Shtober-Zisu, Nurit; Vaks, Anton; Amasha, Hani; Frumkin, Amos

2017-04-01

Denudation is the long-term sum of processes that cause the wearing away of the Earth's surface by weathering and erosion. As denudation of carbonate terrains involves mainly karstic dissolution, Israel is a natural laboratory for the study of denudation rates because of its carbonate terrain and steep precipitation gradient, ranging from >1000 mm in the north to less than 100 mm in the south. Several studies on denudation rates in Israel provide contradictory evidences. Ryb et al [1] found that denudation rates in the Mediterranean climate zone are 21±7 mm per ky, whereas Bar et al [2] showed much lower rates on the long-term scale (Oligocene-present). In this study we determined minimal ages of formation of Inland notches [3] using U-Th dating of tufa deposits developed under the notches' visors or covering notches' cavity beds. The ages of tufa were used to determine the relative slope denudation rates on Mt. Carmel (Israel) that receives annual precipitation rates of 700 mm. Inland notches are elongated concave-shape indentations that develop on the carbonate rocky cliffs of mountainous zones. These unique features formed as a result of the interaction between specific lithological and weathering factors, emphasizing the importance of climate upon denudation. Inland notches form because the most porous cavity bed retreats at a faster rate compared to the slower subaerial dissolution of the visor bed, until a critical point is reached where the visor collapses. Notches are most common in semi-arid and in Mediterranean climates, mainly in areas with annual rainfall of between 400 mm and 850 mm. Occasionally, tufa stalactites and stalagmites grow within the cavity of the notch. The Carmel tufa deposits that grew under the notches visors and on the cavity back-wall were dated by U-Th at the Geological Survey of Israel using ion exchange column chemistry and MC-ICP-MS techniques modified after Vaks et al [4]. In each notch the oldest tufa layer was dated giving the minimum age of the surface formation. Six layers from four tufa samples were dated giving ages spanning from 13,636 ± 834 ky to 37,562 ± 2,397 ky, implying that the minimal age of these notches is last glacial period, or last deglaciation. 1. Ryb, U., et al., Controls on denudation rates in tectonically stable Mediterranean carbonate terrain. Bulletin of the Geological Society of America, 2014. 126(3-4): 553-568. 2. Bar, O., et al., The uplift history of the Arabian Plateau as inferred from geomorphologic analysis of its northwestern edge. Tectonophysics, 2016. 671: 9-23. 3. Shtober-Zisu, N., et al., Inland notches: Implications for subaerial formation of karstic landforms—An example from the carbonate slopes of Mt. Carmel, Israel. Geomorphology, 2015. 229: 85-99. 4. Vaks, A., et al., Paleoclimate and location of the border between Mediterranean climate region and the Saharo-Arabian Desert as revealed by speleothems from the northern Negev Desert, Israel Earth and Planetary Science Letters, 2006. 249(3-4): 384-399.
Geochronology and Regional Correlation of Continental Permo-Triassic Sediments in West Texas

NASA Astrophysics Data System (ADS)

Mitchell, W.; Renne, P. R.; Mundil, R.; Chang, S.; Geissman, J. W.; Tabor, N. J.; Mack, G.

2011-12-01

Although many aspects of marine sections spanning the Permian-Triassic boundary (PTB) have been studied in great detail across a broad paleogeographic area, less is known about the timing, pace, and extent of environmental changes and extinctions across this boundary in continental environments, particularly along the Panthalassa margin. Extensive outcrops in the Ochoan Series of west Texas provide an opportunity to investigate the terrestrial record spanning the PTB. The presence of several silicic tuffs in these sections allows for precise radioisotopic dating using both U-Pb and 40Ar/39Ar techniques. Dated strata then serve as a calibration basis for paleomagnetic and lithostratigraphic studies and facilitate stratigraphic correlation across the few to hundreds of kilometers separating study sites. Depending on the possible correlations, as many as seven tuffs have been identified in this region, the ages of which are within about a million years of the chronometrically-defined PTB at the Meishan section in China at ca. 252 Ma. Data obtained thus far indicate that the PTB occurs within the Quartermaster/Dewey Lake Formation. With the aims of determining the number and ages of distinct tuffs found and facilitating a well-correlated regional stratigraphy among the studied sections, we present preliminary radioisotopic age determinations of, and correlations among, these tuffs using the zircon U-Pb system, 40Ar/39Ar dating where possible, as well as mineral chemistry. Our results include the first dated tuff in the Ochoan Series that lies within the Alibates Formation which underlies the Dewey Lake Fm. Other samples in progress from the various tuffs in the region, in combination with results from magneto- and chemostratigraphy, will significantly expand the areal coverage of these strata and lead towards a greatly improved chronostratigraphic framework.
Water wells on St. Thomas, U.S. Virgin Islands

USGS Publications Warehouse

Steiger, J.I.; Kessler, Richard

1993-01-01

This report is a compilation of well-inventory data collected from December 1989 to December 1990 on St. Thomas, U.S. Virgin Islands from 367 wells. The report includes well locations on 1982, 7.5 minute series, USGS topographic maps, which are published to scale, and tables of selected well data. The report includes the following well information; well name, U.S. Geological Survey Ground Water Site Identification number, use of water, year well constructed, reported depth of well, measured depth of well, casing diameter, type of well finish and finish interval, land surface altitude of well, depth to water below land surface, date water level measured, and well yield. (USGS)
Influence of glacial meltwater on global seawater δ234U

NASA Astrophysics Data System (ADS)

Arendt, Carli A.; Aciego, Sarah M.; Sims, Kenneth W. W.; Das, Sarah B.; Sheik, Cody; Stevenson, Emily I.

2018-03-01

We present the first published uranium-series measurements from modern Greenland Ice Sheet (GrIS) runoff and proximal seawater, and investigate the influence of glacial melt on global seawater δ234U over glacial-interglacial (g-ig) timescales. Climate reconstructions based on closed-system uranium-thorium (U/Th) dating of fossil corals assume U chemistry of seawater has remained stable over time despite notable fluctuations in major elemental compositions, concentrations, and isotopic compositions of global seawater on g-ig timescales. Deglacial processes increase weathering, significantly increasing U-series concentrations and changing the δ234U of glacial meltwater. Analyses of glacial discharge from GrIS outlet glaciers indicate that meltwater runoff has elevated U concentrations and differing 222Rn concentrations and δ234U compositions, likely due to variations in subglacial residence time. Locations with high δ234U have the potential to increase proximal seawater δ234U. To better understand the impact of bulk glacial melt on global seawater δ234U over time, we use a simple box model to scale these processes to periods of extreme deglaciation. We account for U fluxes from the GrIS, Antarctica, and large Northern Hemisphere Continental Ice Sheets, and assess sensitivity by varying melt volumes, duration and U flux input rates based on modern subglacial water U concentrations and compositions. All scenarios support the hypothesis that global seawater δ234U has varied by more than 1‰ through time as a function of predictable perturbations in continental U fluxes during g-ig periods.
Climate variability during the Holocene inferred from northeastern Iberian speleothems

NASA Astrophysics Data System (ADS)

Moreno, A.; Bartolomé, M.; Sancho, C.; Belmonte, Á.; Stoll, H.; Cacho, I.; Edwards, R. L.; Hellstrom, J.

2012-04-01

Although the general climate trends during the Holocene in the Iberian Peninsula have been well described after the study of marine and lacustrine records, many questions regarding the timing of some of the events together with the characterization of the higher-frequency climate variability are still poorly understood. New speleothem records from several caves in northeastern Iberia provide data to explore Holocene climate changes. The selected caves are located in a latitudinal transect from the Pyrenees to the Iberian Range and placed at different altitude. Two of them, 5 de Agosto and Pot au Feu, belong to the same karstic complex in Cotiella massif (Central Pyrenees, 1600 m asl). Seso Cave, also in the Central Pyrenees but at 781 m of altitude, and Molinos cave, a cavity very rich in speleothems located at 1040 m in the Iberian Range, complete the transect. Although in all the caves precipitation coming from Atlantic fronts dominates over the year, a significant Mediterranean influence, specially in summer months, is identified after rainfall monitoring. Speleothem formation during the Holocene occurred at a very low pace in 5 de Agosto cave (80yrs/mm) and increased dramatically at low-altitude caves and during particular periods proved to be wetter (eg. Early Holocene in Molinos cave, less than 10yr/mm). In Seso and Pot au Feu caves, up to seven studied speleothems only grew during short climatic events such as the Iron Cold Period (3000-2500 cal yr BP) or the Little Ice Age (1300-1850 yr AD) that, although cold, were particularly humid periods in northeastern Spain. First stable isotope results highlight the importance of comparing speleothems with similar growing rates and from the same cave to extract climate information and discard other influences. From the integration of four stalagmites from Molinos cave covering since the Holocene onset to 2000 cal yrs BP, the Early Holocene (11.7-8.5 ka BP) with d13C values between -11 and - 9‰ appears as the wetter interval. The highest isotopic values are reached during Middle Holocene (8.5-5.5 ka BP) while there is a tendency towards more negative values during Late Holocene (last 5000 yrs). The range of d18O values is low (about 2‰) but still lighter values during Early Holocene and heavier afterwards are well marked. Shorter events characterized by more negative d13C values are observed at 4 ka, 6 ka, 7.5 ka, 8.2, 8.7, 9.2, 10.3 ka and interpreted as cold but probably wetter periods with denser vegetation cover and soil development over the cave. However, changes in the source of precipitation (Atlantic vs Mediterranean) or the influence of fresh-water outbursts in North Atlantic can not be neglected.
Palaeoclimate determination from cave calcite deposits

NASA Astrophysics Data System (ADS)

Gascoyne, M.

Calcite deposits formed in limestone caves have been found to be an excellent repository of palaeoclimatic data for terrestrial environments. The very presence of a relict deposit indicates non-glacial conditions at the time of formation, and both 14C and uranium-series methods can be used to date the deposit and, hence, the age of these climatic conditions. Variations in 13C and 18O content of the calcite, in 2H and 18O content of fluid inclusions, in trace element concentrations and, more recently, in pollen assemblages trapped in the calcite, are all potentially available as synchronous palaeoclimatic indicators. Previous work has tended to concentrate mainly on abundance of deposits as a palaeoclimatic indicator for the last 300,000 years. This literature is briefly reviewed here, together with the theory and methods of analysis of the U-series and stable isotopic techniques. The combined use of U-series ages and 13C and 18O variations in cave calcites illustrates the potential for palaeoclimate determination. Previously unpublished results of stable isotopic variations in dated calcites from caves in northern England indicate the level of detail of stable isotopic variations and time resolution that can be obtained, and the complexity of interpretation that may arise. Tentative palaeoclimatic signals for the periods 90-125 ka and 170-300 ka are presented. More comprehensive studies are needed in future work, especially in view of the difficulty in obtaining suitable deposits and the ethics of cave deposits conservation.
Stalagmites from Spannagel cave (Austria) and holocene climate

NASA Astrophysics Data System (ADS)

Vollweiler, N.; Mangini, A.; Spötl, C.; Scholz, D.; Mühlinghaus, C.

2009-04-01

The Spannagel cave is located around 2,500 m asl at the end of the Tux Valley in Tyrol (Austria) close to the Hintertux glacier. While the area above the cave is ice free at present, it was covered by ice during past glacials as well as during colder periods of Interglacials. Presently, the temperature inside the cave is between 1.8° and 2.0° C. We used the d18O time-series of three stalagmites which grew in small distance from each other. This speleothem record is not influenced by effects of kinetic isotope fractionation due to the low temperatures in the cave. The stalagmites were precisely dated with the U/Th-method. The combined record (COMNISPA, Vollweiler et al. 2006) shows substantial variability within the last 9 kyr with features like the Holocene Climatic Optimum between 7.5 and 6.5 kyr, the Mediaeval Warm Period between 1.2 and 0.7 kyr and the Roman Warm Period between 2.25 and 1.7 kyr. In contrast, periods of lower temperatures are visible between 7.9 and 7.5, 5.9 and 5.1, 3.5 and 3 kyr, and during the LIA between 600 and 150 yr. The period between 5.9 and 5.1 kyr has equivalence in many records from various regions in both hemispheres corresponding to global cooling. It also includes the time of the Alpine Iceman at 5.3 kyr. The timing of the climatic variations revealed by COMNISPA agrees approximately with that shown by other Alpine archives. Joerin et al. (2006) dated wood and peat samples which were released by melting Swiss Alpine glaciers located between Engadin and Valais. Both the d18O maxima and minima recorded in COMNISPA clearly have counterparts in the glacier recession record. Comparisons of COMNISPA with other archives have shown that our stalagmite curve does not only record local climate but also the history of European climate. The extremely high correlation to the Hematite Stained Grain record of Bond et al. (2001) suggests that COMNISPA is a good archive for climate in the North Atlantic region (Mangini et al. 2007). In addition we found that COMNISPA is also an archive for human activities such as rise and fall of cultures and settlement. For example archaeologists know from their excavations that their are several epochs of Troy culture. The reasons for the downfalls are still under consideration. We think that the absence of precipitation as shown in COMNISPA could be an important cause for the fall of the Troyan empire especially of the famous Homerian epoch Troy VI.
Ages of subsurface stratigraphic intervals in the Quaternary of Enewetak Atoll, Marshall Islands

USGS Publications Warehouse

Szabo, B. J.; Tracey, J.I.; Goter, E.R.

1985-01-01

Drill cores of Enewetak Atoll, Marshall Islands, reveal six stratigraphic intervals, numbered in downward sequence, which represent vertical coral growth during Quaternary interglaciations. Radiocarbon dates indicate that the Holocene sea transgressed the emergent reef platform by about 8000 yr B.P. The reef grew rapidly upward (about 5 to 10 mm/yr) until about 6500 yr B.P. Afterward vertical growth slowed to about 0.5 mm/yr, then lateral development became dominant during the last several thousand years. The second interval is dated at 131,000 ?? 3000 yr B.P. by uranium series. This unit correlates with oxygen-isotope substage 5e and with terrace VIIa of Huon Peninsula, New Guinea, and of Main Reef-2 terrace at Atauro Island. The third interval is not dated because corals were recrystallized and it is tentatively correlated with either oxygen-isotope stages 7 or 9. The age of the fourth interval is estimated at 454,000 ?? 100,000 yr B.P. from measured 234U 238U activity ratios. This unit is correlated with either oxygen-isotope stage 9, 11, or 13. ?? 1985.
Dating lacustrine episodes in the eastern Sahara by the epimerization of isoleucine in ostrich eggshells

USGS Publications Warehouse

Miller, G.H.; Wendorf, F.; Ernst, R.; Schild, R.; Close, A.E.; Friedman, I.; Schwarcz, H.P.

1991-01-01

The eggshell of the African ostrich, Struthio camelus, closely approximates a closed system for the retention of indigenous proteinaceous residues. Epimerization of the protein amino acid isoleucine follows linear first-order kinetics in laboratory simulations nearly to racemic equilibrium, and the variation in D/L ratio within a single fragment, or between fragments of the same age, is significantly less than in other carbonate systems. These observations suggest that the extent of isoleucine epimerization (aIle/Ile ratio) in ostrich eggshell offers the potential for high-resolution geochronology of Quaternary deposits. From the simulation experiments, and dated early Holocene samples for which we have in situ mean annual sediment temperature measurements, Arrhenius parameters have been calculated; the activation energy is 30.33 kcal mol-1, similar to that of other carbonate systems. We have measured the aIle/Ile ratio in ostrich eggshell associated with lacustrine episodes at Bir Tarfawi and Bir Sahara East, two depressions in what is currently the hyperarid eastern Sahara. The ratios can be used directly to indicate qualitatively the time represented by each series of lake sediment, and to correlate disjunct lacustrine deposits within and between the basins. Uranium-series disequilibrium dating of algal mats contained within some of the lake beds indicate that a major wet interval occurred about 130 ka ago. Using the U-series date for calibration, the amino acid ratios are used to date the most recent lacustrine interval to about 100 ka B.P., and two older intervals, one about 200 ?? 25 ka B.P., and an older interval that occurred prior to 250 ka ago. ?? 1991.

Astrobiology Training in Lava Tubes (ATiLT): Characterizing coralloid speleothems in basaltic lava tubes as a Mars analogue

NASA Astrophysics Data System (ADS)

Ni, J.; Leveille, R. J.; Douglas, P.

2017-12-01

Coralloid speleothems or cave corals are small mineralised nodes that can take a variety of forms, and which develop through groundwater seepage and water-rock interaction in caves. They are found commonly on Earth in a plethora of caves, including lava tubes. Since lava tubes have been identified on the surface of Mars from remotely sensed images, there has been interest in studying Earth's lava tube systems as an analogue for understanding Martian lava environments. If cave minerals were found on Mars, they could indicate past or present water-rock interaction in the Martian subsurface. Martian lava tubes could also provide insights into habitable subsurface environments as well as conditions favourable for the synthesis and preservation of biosignatures. One of the aims of the Astrobiology Training in Lava Tubes (ATiLT) project is to analyze biosignatures and paleoenvironmental indicators in secondary cave minerals, which will be looked at in-situ and compared to collected field samples. In this study, secondary mineralization in lava cave systems from Lava Beds National Monument, CA is examined. In the field, coralloid speleothems have been observed growing on all surfaces of the caves, including cave ceilings, floors, walls and overhangs. They are also observed growing adjacent to biofilms, which sometimes fill in the cracks of the coralloid nodes. Preliminary results show the presence of opal, calcite, quartz and other minor minerals in the speleothems. This study seeks to understand the formation mechanism and source of these secondary minerals, as well as determine their possible relation to the biofilms. This will be done through the analysis of the water chemistry, isotope geochemistry and microscale mineralogy.
Insights into changes in precipitation patterns in Brazil from oxygen isotope ratios on speleothems

NASA Astrophysics Data System (ADS)

Cruz, F.; Mathias, V.; Stephen, B. J.; Wang, X.; Cheng, H.; Werner, M.; Edwards, R. L.; Karmann, I.; Auler, A. S.

2008-12-01

Variations in tropical precipitation on millennial and orbital time scales can reflect a Hadley-cell-related anti- phasing between the Northern and Southern hemispheres due to the influence of insolation on the global summer monsoons. A new δ18O speleothem record from northeastern Brazil shows that insolation- driven changes in monsoon intensity are capable of producing a similar, zonally oriented anti-phasing within the same hemisphere. Comparison of our speleothem record with other precipitation-sensitive proxies from the central Andes and southeastern Brazil shows that precipitation in Northeastern Brazil has been out of phase with insolation and rainfall in the rest of tropical South America south of the equator since the Last Glacial Maximum. Northeastern Brazil experienced humid conditions when summer insolation was reduced and arid conditions when insolation was high. While previous interpretations of past climate change in NE South America have commonly invoked meridional displacements in ITCZ location as the main mechanism for changes in precipitation on millennial time scales, our results suggest that remote monsoon forcing is responsible for much of the observed precipitation changes on orbital time scales during the Holocene. These results demonstrate that orbitally driven out-of-phase relationships in precipitation are not limited to interhemispheric anti-phasing as demonstrated previously, but may well occur within the same hemisphere. Speleothem records also indicate contrasting climatic conditions around the Last Glacial Maximum in Brazil, characterized by marked dry and wet climates in the Nordeste and in southeastern Brazil, respectively. It is likely, however, that these regional differences primarily reflect more distant extratropical teleconnections from the Atlantic Ocean and high northern latitude changes during glacial conditions.
Quantifying weathering advance rates in basaltic andesite rinds with uranium-series isotopes: a case study from Guadeloupe

NASA Astrophysics Data System (ADS)

Ma, L.; Chabaux, F. J.; Pelt, E.; Granet, M.; Sak, P. B.; Gaillardet, J.; Brantley, S. L.

2010-12-01

Weathering of basaltic rocks plays an important role in many Earth surface processes. It is thus of great interest to quantify their weathering rates. Because of their well-documented behaviors during water-rock interaction, U-series isotopes have been shown to have utility as a potential chronometer to constrain the formation rates of weathering rinds developed on fresh basaltic rocks. In this study, U-series isotopes and trace element concentrations were analyzed in a basaltic andesite weathering rind collected from the Bras David watershed, Guadeloupe. From the clast, core and rind samples were obtained by drilling along a 63.8 mm linear profile across a low curvature segment of the core-rind boundary. Trace element concentrations reveal: significant loss of REE, Y, Rb, Sr, and Ba in the weathering rind; conservative behaviors of Ti and Th; and external addition of U into the rind during clast weathering. Measured (234U/238U) activity ratios of the rind samples are much higher than the core samples and show excess 234U. Measured (238U/232Th) and (230Th/232Th) activity ratios of the core and rind samples increase gradually from the core into the weathering rind. The observed depletion profiles for the trace elements in the clast suggest that the earliest chemical reaction that creates significant porosity is dissolution of plagioclase, consistent with the previous study [Sak et al., 2010, CG, in press]. The porosity growth within the rind allows for an influx of soil solution that carries dissolved U with (234U/238U) activity ratios >1 into the clast. The deposition of U in the rind is most likely associated with precipication of secondary minerals during clast weathering. Such a continuous U addition is responsible for the observed gradual increase of (238U/232Th) activity ratios in the rind. Subsequent production of 230Th in the rind over time from the decay of excess 234U accounts for the observed continuous increase of (230Th/232Th) activity ratios. The U-series activity ratios in the clast were modeled with a weathering advance rate of ~0.3 mm kyr-1. This represents the rind advance rate at the low curvature segment of the core-rind boundary under tropical climate. This rate is consistent with the previously estimated formation rates of basaltic rinds under similar tropic conditions in Costa Rica [Sak et al., 2004, GCA 68, 1453; Pelt et al., 2008, EPSL 276, 98]. This rate is about one order of magnitude greater than those in temperate regions, documenting the important control of temperature on basalt weathering. This work illustrates that the weathering advance rates of rinds can be successfully estimated by U-series isotopes, demonstrating their great potential as dating tools for Earth surface processes. Furthermore, U-series chronometry provides a suitable method for independently testing the hypothesis that rind advance rates around an individual clast increase with increasing interfacial curvature.
Spatial variability of initial 230Th/ 232Th in modern Porites from the inshore region of the Great Barrier Reef

NASA Astrophysics Data System (ADS)

Clark, Tara R.; Zhao, Jian-xin; Feng, Yue-xing; Done, Terry J.; Jupiter, Stacy; Lough, Janice; Pandolfi, John M.

2012-02-01

The main limiting factor in obtaining precise and accurate uranium-series (U-series) ages of corals that lived during the last few hundred years is the ability to constrain and correct for initial thorium-230 ( 230Th 0), which is proportionally much higher in younger samples. This is becoming particularly important in palaeoecological research where accurate chronologies, based on the 230Th chronometer, are required to pinpoint changes in coral community structure and the timing of mortality events in recent time (e.g. since European settlement of northern Australia in the 1850s). In this study, thermal ionisation mass spectrometry (TIMS) U-series dating of 43 samples of known ages collected from living Porites spp. from the far northern, central and southern inshore regions of the Great Barrier Reef (GBR) was performed to spatially constrain initial 230Th/ 232Th ( 230Th/ 232Th 0) variability. In these living Porites corals, the majority of 230Th/ 232Th 0 values fell within error of the conservative bulk Earth 230Th/ 232Th atomic value of 4.3 ± 4.3 × 10 -6 (2 σ) generally assumed for 230Th 0 corrections where the primary source is terrestrially derived. However, the results of this study demonstrate that the accuracy of 230Th ages can be further improved by using locally determined 230Th/ 232Th 0 values for correction, supporting the conclusion made by Shen et al. (2008) for the Western Pacific. Despite samples being taken from regions adjacent to contrasting levels of land modification, no significant differences were found in 230Th/ 232Th 0 between regions exposed to varying levels of sediment during river runoff events. Overall, 39 of the total 43 230Th/ 232Th 0 atomic values measured in samples from inshore reefs across the entire region show a normal distribution ranging from 3.5 ± 1.1 to 8.1 ± 1.1 × 10 -6, with a weighted mean of 5.76 ± 0.34 × 10 -6 (2 σ, MSWD = 8.1). Considering the scatter of the data, the weighted mean value with a more conservative assigned error of 25% (i.e. 5.8 ± 1.4 × 10 -6) that encompasses the full variation of the 39 230Th/ 232Th 0 measurements is recommended as a more appropriate value for initial 230Th corrections for U-series dating of most Porites samples from inshore regions of the GBR. This will result in significant improvement in both the precision and accuracy of the corrected 230Th ages related to those based on the assumed bulk Earth 230Th/ 232Th 0 value of 4.3 ± 4.3 × 10 -6. However, several anomalously high 230Th/ 232Th 0 values reaching up to 28.0 ± 1.6 × 10 -6 occasionally found in some coral annual bands coinciding with El Niño years imply high 230Th/ 232Th 0 sources and highlight the complexities of understanding 230Th/ 232Th 0 variability. For U-series dating of young coral samples from such sites where anomalous 230Th/ 232Th 0 values occur, we suggest replicate dating of multiple growth bands with known age difference to verify age accuracy.
College Enrollment and Work Activity of 2005 High School Graduates. Bureau of Labor Statistics News. USDL 06-514

ERIC Educational Resources Information Center

Bureau of Labor Statistics, 2006

2006-01-01

In October 2005, 68.6 percent of high school graduates from the class of 2005 were enrolled in colleges or universities, according to data released on March 24, 2006 by the U.S. Department of Labor's Bureau of Labor Statistics. The college enrollment rate for recent high school graduates was a historical high for the series dating back to 1959.…
Extreme drying event in the Dead Sea basin during MIS5 from the ICDP Dead Sea Deep Drill Core

NASA Astrophysics Data System (ADS)

Goldstein, S. L.; Stein, M.; Ben-Avraham, Z.; Agnon, A.; Ariztegui, D.; Brauer, A.; Haug, G. H.; Ito, E.; Kitagawa, H.; Torfstein, A.; Yasuda, Y.; The Icdp-Dsddp Scientific Party

2011-12-01

The ICDP funded Dead Sea Deep Drilling Project (DSDDP) recovered the longest and most complete paleo-environmental record in the Middle East, drilling holes of ~450 and ~350 meters in length in deep (~300 m below the lake level) and shallow sites (~3 mbll) respectively. The Dead Sea expands during the glacials and contracts during interglacials, and the sediments comprise a geological archive of the evolving environmental conditions (e.g. rains, floods, dust-storms, droughts). Dead Sea sediments include inorganic aragonite, allowing for dating by U-series (e.g. Haase-Schramm et al. GCA 2004). The deep site cores were opened and described in June 2011. The cores are composed mainly of alternating intervals of marl (aragonite, gypsum and detritus) during glacials, and salts and marls during interglacials. From this stratigraphy we estimate that the deep site core spans ~200 kyr (to the boundary of MIS 6 and 7). A dramatic discovery is a ~40 cm thick interval of partly rounded pebbles at ~235 m below the lake floor. This is the only clean pebbly unit in the entire core. It appears to be a beach layer, near the deepest part of the Dead Sea, lying above ~35 meters of mainly salt. If it is a beach layer, it implies an almost complete dry-down of the paleo-Dead Sea. The pebble layer lies within the last interglacial interval. Our initial attempt to more precisely estimate the age of the possible dry down shows an intriguing correlation between the salt-mud stratigraphy of the Dead Sea core and the oxygen isotope record of Soreq Cave, whereby excursions to light oxygen in the speleothems correspond to periods of salt deposition. Through this comparison, we estimate that the possible dry down occurred during MIS 5e. The occurrence of ~35 meters of mainly salt along with the pebble layer demonstrates a severe dry interval during MIS 5. This observation has implications for the Middle East today, where the Dead Sea level is dropping as all the countries in the area use the runoff. GCM models indicate a more arid future in the region. The core shows that the runoff nearly stopped during a past warm period without human intervention.
Direct U-series analysis of the Lezetxiki humerus reveals a Middle Pleistocene age for human remains in the Basque Country (northern Iberia).

PubMed

de-la-Rúa, Concepción; Altuna, Jesús; Hervella, Monserrat; Kinsley, Leslie; Grün, Rainer

2016-04-01

In 1964, a human humerus was found in a sedimentary deposit in Lezetxiki Cave (Basque Country, northern Iberia). The first studies on the stratigraphy, associated mammal faunal remains and lithic implements placed the deposits containing the humerus into the Riss glacial stage. Direct chronometric evidence has so far been missing, and the previous chronostratigraphic framework and faunal dating gave inconsistent results. Here we report laser ablation U-series analyses on the humerus yielding a minimum age of 164 ± 9 ka, corresponding to MIS 6. This is the only direct dating analysis of the Lezetxiki humerus and confirms a Middle Pleistocene age for this hominin fossil. Morphometric analyses suggest that the Lezetxiki humerus has close affinities to other Middle Pleistocene archaic hominins, such as those from La Sima de los Huesos at Atapuerca. This emphasizes the significance of the Lezetxiki fossil within the populations that predate the Neanderthals in south-western Europe. It is thus an important key fossil for the understanding of human evolution in Europe during the Middle Pleistocene, a time period when a great morphological diversity is observed but whose phylogenetic meaning is not yet fully understood. Copyright © 2016 Elsevier Ltd. All rights reserved.
31 CFR 351.64 - What is the issue date of a book-entry Series EE savings bond?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What is the issue date of a book-entry... OF UNITED STATES SAVINGS BONDS, SERIES EE Book-Entry Series EE Savings Bonds § 351.64 What is the issue date of a book-entry Series EE savings bond? The issue date of a book-entry Series EE savings bond...
31 CFR 351.64 - What is the issue date of a book-entry Series EE savings bond?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false What is the issue date of a book... OFFERING OF UNITED STATES SAVINGS BONDS, SERIES EE Book-Entry Series EE Savings Bonds § 351.64 What is the issue date of a book-entry Series EE savings bond? The issue date of a book-entry Series EE savings bond...
Human papillomavirus vaccination coverage using two-dose or three-dose schedule criteria.

PubMed

Lin, Xia; Rodgers, Loren; Zhu, Liping; Stokley, Shannon; Meites, Elissa; Markowitz, Lauri E

2017-10-13

In October 2016, the Advisory Committee on Immunization Practices (ACIP) updated the human papillomavirus (HPV) vaccination recommendation to include a 2-dose schedule for U.S. adolescents initiating the vaccine series before their 15th birthday. We analyzed records for >4million persons aged 9-17years receiving any HPV vaccine by the end of each quarter during January 1, 2014-September 30, 2016 from six Immunization Information Systems Sentinel Sites, and reclassified HPV vaccination up-to-date coverage according to the updated recommendations. Compared with HPV vaccination up-to-date coverage by the 3-dose schedule only, including criteria for either a 2-dose or 3-dose schedule increased up-to-date coverage in 11-12, 13-14, and 15-17 year-olds by 4.5-8.5 percentage points. The difference between 3-dose up-to-date coverage and 2- or 3-dose up-to-date coverage was greatest in late 2016. These data provide baseline HPV vaccination coverage using current ACIP recommendations. Published by Elsevier Ltd.
The response of East Asian monsoon to the precessional cycle

NASA Astrophysics Data System (ADS)

Lee, J. E.

2017-12-01

The oxygen isotopic composition of cave speleothems exhibits a large amplitude change following the insolation, particularly the precessional cycle. Whether speleothem d18O reflects local precipitation amount, however, has been questioned by alternative hypotheses: (1) d18O reflects upstream Indian monsoon precipitation, which influences the isotopic composition of the input vapor to East Asia, and (2) the isotopic composition of pre-monsoon and monsoon exhibits a large difference, and the seasonality of precipitation may have shifted in response to insolation. Motivated the fact that the magnitude of Asian monsoon d18O was not reproduced by most climate models, here I show new results, using the fully coupled GFDL model, that precipitation increases when the northern hemisphere receives more summer insolation, similar to the original claim. I argue that previous models do not produce enough rainfall during the monsoon season, possibly because the westerly jet is located too north in relation to the Tibetan Plateau during the monsoon season. I conclude that Asian monsoon intensity probably increases with increasing insolation there, given a large change in speleothem d18O. My next step will be testing this hypothesis after incorporating isotopes into the GFDL model.
Mushroom speleothems: Stromatolites that formed in the absence of phototrophs

NASA Astrophysics Data System (ADS)

Bontognali, Tomaso; D'Angeli, Ilenia; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano; Gonzales, Esteban; DeWaele, Jo

2016-04-01

Unusual speleothems resembling giant mushrooms occur in Santa Catalina Cave, Cuba. Although these mineral buildups are considered a natural heritage, their composition and formation mechanism remain poorly understood. Here we characterize their morphology and mineralogy and present a model for their genesis. We propose that the mushrooms, which are mainly comprised of calcite and aragonite, formed during four different phases within an evolving cave environment. The stipe of the mushroom is an assemblage of three well-known speleothems: a stalagmite surrounded by calcite rafts that were subsequently encrusted by cave clouds (mammilaries). More peculiar is the cap of the mushroom, which is morphologically similar to cerebroid stromatolites and thrombolites of microbial origin occurring in marine environments. Scanning electron microscopy investigations of this last unit revealed the presence of fossilized extracellular polymeric substances (EPS) - the constituents of biofilms and microbial mats. These organic microstructures are mineralized with Ca-carbonate, suggesting that the mushroom cap formed through a microbially-influenced mineralization process. The existence of cerebroid Ca-carbonate buildups forming in dark caves (i.e., in the absence of phototrophs) has interesting implications for the study of fossil microbialites preserved in ancient rocks, which are today considered as one of the earliest evidence for life on Earth.
Phosphatic precipitates associated with actinomycetes in speleothems from Grand Cayman, British West Indies

NASA Astrophysics Data System (ADS)

Jones, Brian

2009-07-01

Calcitic speleothems from a cave located on the north central coast of Grand Cayman commonly include corrosion surfaces that developed when calcite precipitation ceased and corrosion mediated by condensates became the operative process. Dissolution features associated with these surfaces, including etched crystal surfaces, microcavities, and solution-widened boundaries between crystals, are commonly occupied by microbes and microbial mats that have been replaced by calcium phosphate and/or coated with calcium phosphate. No mineralized microbes were found in the calcite crystals that form the speleothems. The morphology of the mineralized hyphae (eight morphotypes) and spores (nine morphotypes) are indicative of actinomycetes, a group of microbes that are ideally adapted to life in oligotrophic cave environs. Superb preservation of the delicate hyphae, aerial hyphae, and delicate ornamentation on the hyphae and spores indicate that the microbes underwent rapid mineralized while close to their original life positions. Although these actinomycetes were extremely susceptible to replacement by calcium phosphate, there is no evidence that they directly or indirectly controlled precipitation. Nevertheless, the association between the P-rich precipitates and microbes shows that the use of phosphorus as a proxy for seasonal climate changes in paleoclimate analyses must be treated with caution.
Speleothems from Mawsmai and Krem Phyllut caves, Meghalaya, India: some evidences on biogenic activities

NASA Astrophysics Data System (ADS)

Baskar, Sushmitha; Baskar, R.; Lee, Natuschka; Theophilus, P. K.

2009-05-01

The Mawsmai cave and Krem Phyllut caves, East Khasi hills, Meghalaya, India has so far not yet attracted the attention of geomicrobiologists. Observations and hypotheses on the possible influence of identified microorganisms for speleothem formations in Meghalaya are reported for the first time. XRD studies identified calcite in speleothems and gypsum in cave wall deposits as the dominant minerals. SEM-EDAX showed interesting microfabric features showing strong resemblance with fossilised bacteria, calcified filaments, needle calcite and numerous nano scale calcite crystals, highly weathered and disintegrated crystals of calcite, that point towards a significant microbial influence in its genesis. Thin section petrography showed laminated stromatolitic features. The microorganisms identified by conventional isolation and further evaluation of isolates by molecular techniques include Bacillus cereus, Bacillus mycoides, Bacillus licheniformis, Micrococcus luteus, and Actinomycetes. Microscopic observations also showed unidentifiable cocci and four unidentifiable strains of CaSO4 (gypsum) precipitating bacteria. Experimental studies confirmed that these bacteria are able to precipitate calcium minerals (calcite, gypsum, minor amounts of dolomite) in the laboratory. These results allow us to postulate that species like these may contribute to active biogenic influence in the cave formations at Meghalaya.
Sulphate partitioning into calcite: Experimental verification of pH control and application to seasonality in speleothems

NASA Astrophysics Data System (ADS)

Wynn, Peter M.; Fairchild, Ian J.; Borsato, Andrea; Spötl, Christoph; Hartland, Adam; Baker, Andy; Frisia, Silvia; Baldini, James U. L.

2018-04-01

Carbonate-associated sulphate (CAS) is a useful carrier of palaeoenvironmental information throughout the geologic record, particularly through its stable isotope composition. However, a paucity of experimental data restricts quantitative understanding of sulphate incorporation into carbonates, and consequently CAS concentrations and their diagenetic modifications are rarely interpreted. However, in the case of calcite speleothems, the remarkably high-resolution CAS records which are obtainable via modern microanalytical techniques represent a potentially invaluable source of palaeoenvironmental information. Here, we describe the results of controlled experiments of sulphate co-precipitation with calcite in freshwater solutions where pH, saturation state, and sulphate concentration were varied independently of each other. Solution pH is confirmed as the principal control on sulphate incorporation into calcite. The relative efficiency of incorporation was calculated as a partition coefficient DSO4 = (mSO4/mCO3)solid/(mSO4/mCO3)solution. High crystal growth rates (driven by either pH or saturation state) encouraged higher values of DSO4 because of an increasing concentration of defect sites on crystal surfaces. At low growth rates, DSO4 was reduced due to an inferred competition between sulphate and bicarbonate at the calcite surface. These experimental results are applied to understand the incorporation of sulphate into speleothem calcite. The experimentally determined pH-dependence suggests that strong seasonal variations in cave air PCO2 could account for annual cycles in sulphate concentration observed in stalagmites. Our new experimentally determined values of DSO4 were compared with DSO4 values calculated from speleothem-drip water monitoring from two caves within the Austrian and Italian Alps. At Obir cave, Austria, DSO4 (×105) varies between 11.1 (winter) and 9.0 (summer) and the corresponding figures for Ernesto cave, Italy, are 15.4 (winter) and 14.9 (summer). These values approximate predicted DSO4 values based on our chamber experiments containing both low (2 ppm) and high (20 ppm) sulphate concentrations. Our experimental values of DSO4 obtained at crystal growth rates typical of stalagmites, closely match those observed in other cave sites from around the world. This validates the universality of the controls behind DSO4 and will enhance the use of speleothem CAS as a palaeoenvironmental proxy.
Measurements of rare isotopes of U and Th by MC-ICP-MS using a 1013 ohm resistor

NASA Astrophysics Data System (ADS)

Pythoud, M.; Edwards, R. L.; Cheng, H.; Lu, Y.; Zhang, P.; Nissen, J.; Berry, A. E.

2016-12-01

We have tested a 1013 ohm resistor on a Thermo-Scientific Neptune Plus, a multi-collector inductively-coupled plasma mass spectrometer (MC-ICP-MS), for the measurement of rare isotopes of uranium (U) and thorium (Th). In nature, the isotopic disequilibrium among U-series nuclides provides the potential to date materials and time processes over the last 700,000 years. Using gravimetric standards and a Minnesota stalagmite, we demonstrate the reproducibility of δ234U and 230Th dates with uncertainties at the 1-‰ to sub-‰ level (2σ), with relatively small samples. Compared to traditional secondary electron multiplier (SEM) techniques, measurement times decrease from > 1 hour to < 5 min for U and from tens of min to < 2 min for Th, with comparable or better precision. The characteristics of the new amplifier design and typical instrumental conditions allow for 234U and 230Th sample loads as small as 1-2 pg, a reduction in sample size close to an order of magnitude over cup measurements with 1011 ohm resistors. The main sources of error include the amplifier noise, uncertainty in the characterization of the tailing effect, and in some cases, counting statistics. Importantly, our overall characterization suggests that this new method forms the basis for future and further improvements on instrumental precision.
Paleoclimate reconstruction in the Levant region from the petrography and the geochemistry of a MIS 5 stalagmite from the Kanaan Cave, Lebanon

NASA Astrophysics Data System (ADS)

Nehme, C.; Verheyden, S.; Noble, S. R.; Farrant, A. R.; Delannoy, J. J.; Claeys, P.

2015-07-01

Lying at the transition between the temperate Mediterranean domain and subtropical deserts, the Levant is a key area to study the palaeoclimatic response over glacial-interglacial cycles. This paper presents a precisely dated last interglacial (MIS 5) stalagmite (129-84 ka) from the Kanaan Cave, Lebanon. Variations in growth rate and isotopic records indicate a warm humid phase at the onst of the last interglacial at ~129 ka that lasted until ~125 ka. A gradual shift in speleothem isotopic composition (125-122 ka) is driven mainly by the δ18O source effect of the Eastern Mediterranean surface waters during Sapropel S5. The onset of glacial inception began after ~122 ka, interrupted by a short wet pulse during Sapropel S4. Low growth rates and enriched oxygen and carbon values until ~84 ka indicate a transition to drier conditions during Northern Hemisphere glaciation.
Reconstruction of MIS 5 climate in the central Levant using a stalagmite from Kanaan Cave, Lebanon

NASA Astrophysics Data System (ADS)

Nehme, C.; Verheyden, S.; Noble, S. R.; Farrant, A. R.; Sahy, D.; Hellstrom, J.; Delannoy, J. J.; Claeys, P.

2015-12-01

Lying at the transition between the temperate Mediterranean domain and subtropical deserts, the Levant is a key area to study the palaeoclimatic response over glacial-interglacial cycles. This paper presents a precisely dated last interglacial (MIS 5) stalagmite (129-84 ka) from the Kanaan Cave, Lebanon. Variations in growth rate and isotopic records indicate a warm humid phase at the onset of the last interglacial at ~ 129 ka that lasted until ~ 125 ka. A gradual shift in speleothem isotopic composition (125-122 ka) is driven mainly by the δ18O source effect of the eastern Mediterranean surface waters during sapropel 5 (S5). The onset of glacial inception began after ~ 122 ka, interrupted by a short wet pulse during the sapropel 4 (S4) event. Low growth rates and enriched oxygen and carbon values until ~ 84 ka indicate a transition to drier conditions during Northern Hemisphere glaciation.
Climate change patterns in Amazonia and biodiversity.

PubMed

Cheng, Hai; Sinha, Ashish; Cruz, Francisco W; Wang, Xianfeng; Edwards, R Lawrence; d'Horta, Fernando M; Ribas, Camila C; Vuille, Mathias; Stott, Lowell D; Auler, Augusto S

2013-01-01

Precise characterization of hydroclimate variability in Amazonia on various timescales is critical to understanding the link between climate change and biodiversity. Here we present absolute-dated speleothem oxygen isotope records that characterize hydroclimate variation in western and eastern Amazonia over the past 250 and 20 ka, respectively. Although our records demonstrate the coherent millennial-scale precipitation variability across tropical-subtropical South America, the orbital-scale precipitation variability between western and eastern Amazonia exhibits a quasi-dipole pattern. During the last glacial period, our records imply a modest increase in precipitation amount in western Amazonia but a significant drying in eastern Amazonia, suggesting that higher biodiversity in western Amazonia, contrary to 'Refugia Hypothesis', is maintained under relatively stable climatic conditions. In contrast, the glacial-interglacial climatic perturbations might have been instances of loss rather than gain in biodiversity in eastern Amazonia, where forests may have been more susceptible to fragmentation in response to larger swings in hydroclimate.
31 CFR 359.49 - What is the issue date of a book-entry Series I savings bond?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What is the issue date of a book-entry... OF UNITED STATES SAVINGS BONDS, SERIES I Book-Entry Series I Savings Bonds § 359.49 What is the issue date of a book-entry Series I savings bond? The issue date of a book-entry Series I savings bond is the...

Timing and warmth of the Last Interglacial period: New U-series evidence from Hawaii and Bermuda and a new fossil compilation for North America

USGS Publications Warehouse

Muhs, D.R.; Simmons, K.R.; Steinke, B.

2002-01-01

The timing and duration of the Last Interglacial period have been controversial, with some studies suggesting a relatively short duration that is orbitally forced and others suggesting a long duration that is at most only partly related to orbital forcing. New, high-precison thermal ionization mass spectrometric (TIMS) U-series ages of Last Interglacial corals from Hawaii and Bermuda test these competing hypotheses. Waimanalo Formation corals from slowly uplifting Oahu, Hawaii range in age from ???134 to ???113 ka, with most ages between ???125 and ???115 ka. Combined with published U-series ages from nearby Lanai, the data suggest a long Last Interglacial period that may have occurred from ???136 to at least 115 ka. The results indicate that orbital forcing may not have been the only control on ice sheet growth and decay, because sea level would have been high at times of relatively low Northern Hemisphere summer insolation. On tectonically stable Bermuda, deposits from the ???200 ka (penultimate interglacial period), ???120 ka (peak Last Interglacial period) and ???80 ka (late Last Interglacial period) high sea stands have been newly dated. Fossil corals on Bermuda are derived from patch reefs that likely were "catch-up" responses to sea level rise. It is expected that U-series ages of Last-Interglacial corals on Bermuda should overlap with, but not be as old as the range of corals on Oahu. Last-Interglacial corals on Bermuda give a range of ???125-113 ka, which supports this hypothesis. A large number of emergent marine deposits on Hawaii, Bermuda and along coastal North America have now been dated to the Last Interglacial period. Both Oahu and Bermuda have marine invertebrate faunas with a number of extralimital southern species of mollusks, suggesting warmer-than-present waters during the Last Interglacial period. Warmer waters are also suggested for Last-Interglacial localities around most of North America, from Florida to Canada and Greenland and Baja California to Alaska. These observations are consistent with similar warm-water faunas of Last-Interglacial age reported from Japan, the Mediterranean basin and Western Australia. It is likely that significant changes in ocean currents took place during the Last Interglacial period, with a movement of relatively warm waters to higher latitudes than is the case today. ?? 2002 Elsevier Science Ltd. All rights reserved.
High resolution pCO2 monitoring reveals ventilation of Bunker Cave (NW Germany) and its impact on speleothem growth

NASA Astrophysics Data System (ADS)

Riechelmann, Sylvia; Breitenbach, Sebastian F. M.; Schröder-Ritzrau, Andrea; Immenhauser, Adrian

2017-04-01

Understanding the environmental processes that influence geochemical proxies archived in speleothems depends critically on detailed cave monitoring. Cave air pCO2 is one of the most important factors controlling speleothem growth. The pCO2 concentration of cave air depends on (i) the productivity of its source(s), (ii) CO2-transport dynamics through the epikarst and (iii) cave ventilation processes. We monitored the pCO2 concentration ca. 100 m from the lower entrance of the Bunker-Emst-Cave system (NW Germany) with a CORA CO2-logger at a two-hourly resolution between April 2012 and February 2014. Near-atmospheric minimum pCO2 concentrations of 408 ppm are observed in winter, while higher values up to 811 ppm are recorded in summer. Higher summer concentrations are due to increased plant and soil microbial activity, resulting in elevated CO2 in the soil, which is transferred to the cave with infiltrating water. Generally, the front passages of Bunker Cave are well ventilated. Besides the seasonal pattern, pCO2 concentrations vary at diurnal scale. Correlations of pCO2 with the temperature difference between surface and cave air are positive during summer and negative in winter, with no clear pattern for spring and autumn months. Thus, Bunker Cave ventilation is driven by temperature and density differences between cave and surface air, with two entrances at different elevations allowing dynamic ventilation. During summer, relatively cooler cave air flows from the upper to the lower entrance, while in winter this pattern is reversed due to ascending warm cave air. The situation is further complicated by preferential south/southwestern winds that point directly on the cave entrances. Thus, cave ventilation is frequently disturbed, especially during periods of higher wind speed. Modern ventilation systematics only developed when the two cave entrances were artificially opened (1863 and 1926). Before that, ventilation was restricted and cave pCO2 concentrations were presumably higher under natural conditions. Thus, the present-day ventilation system of Bunker Cave is not a direct analogue for natural ventilation conditions. pCO2 concentrations are relatively low compared to other caves, and because the difference between summer and winter pCO2 is relatively low (max. 400 ppm), a significant effect on seasonal speleothem growth rate is unlikely. In case of Bunker Cave, it is rather a combination of the availability of water, and thus of calcium and carbonate ions and pCO2 concentrations that allow higher carbonate precipitation during winter than summer. Holocene speleothems from Bunker Cave display relatively slow growth rates. We suggest that - with absence of major entrances to the cave system during the Holocene - ventilation was minimal and pCO2 concentrations significantly higher, making winterly water supply the governing factor regulating speleothem growth. Thus, stalagmites from Bunker Cave are likely to record a climatic signal biased towards the winter season.
Speleothem carbon isotopes in the tropics: a proxy for vegetation and what they reveal about the demise of Homo floresiensis

NASA Astrophysics Data System (ADS)

Scroxton, N.; Gagan, M. K.; Ayliffe, L. K.; Hellstrom, J.; Cheng, H.; Edwards, R.; Zhao, J.; Hantoro, W. S.; Rifai, H.; Scott-Gagan, H.; Cowley, J. A.; Suwargadi, B. W.

2013-12-01

Most long-term speleothem climate records focus on δ18O (Cruz Jr. et al. 2005, Wang et al. 2005, Meckler et al. 2012, Carolin et al. 2013). In tropical regions, where temperature variability is relatively small, speleothem δ18O serves as a proxy for precipitation amount. On orbital timescales, changes in moisture source, sea level and global ice volume also influence speleothem δ18O. As both δ18O and δ13C are measured simultaneously, a wealth of potential paleoclimatic information from the δ13C records for numerous sites awaits publication. However, δ13C is less well understood as an environmental proxy, and a simple control and explanation may not be forthcoming. We present a new 92,000-year long speleothem δ13C record for Liang Luar cave in Flores, Indonesia. Here, δ13C acts as a proxy for soil CO2 production above the cave, which is strongly linked to vegetative changes. Since vegetation and soil CO2 production are closely linked to a climatic control, changes in speleothem δ13C can be considered an environmental response to climate change. The Liang Luar δ13C record mainly tracks the δ18O, indicating close affiliation between vegetation and climate. Peak vegetation cover and soil activity (lower δ13C) occur in the early Holocene. The Last Glacial Maximum does not have notably higher δ13C than Isotope Stages 3 and 5a. δ13C variability in the glacial is much higher than that in the Holocene. Differences between the δ13C and δ18O records indicate periods of vegetative change without a climatic cause. The largest increase in δ13C (8‰) during the last 90kyr occurred at 68kyr BP. This anomalous δ13C excursion represents a major loss of vegetation around Liang Luar. The last surviving non-human member of the Homo genus: Homo floresiensis, disappeared from the stratigraphic record in nearby Liang Bua cave between 17 and 10kyr BP (Roberts et al. 2009). The cause of the disappearance, (e.g. climate change, volcanic catastrophe or human competition, has not been established. In contrast to the environmental upheaval around 68kyr BP, the period between 17 and 10kyr BP is remarkably stable. With little change in vegetation at this time, we can rule out volcanism or climate change as a likely cause of the extinction. We are left with an intriguing puzzle as to what caused the recent extinction of Homo floresiensis. Cruz Jr. et al. 2005, Nature, v. 434, p. 63 Wang et al. 2005, Science, v. 308, p. 854 Meckler et al. 2012, Science, v. 336, p. 1301 Carolin et al. 2013, Science, v. 340, p. 1564 Roberts et al. 2009, J. Hum. Evol., v. 57, p. 484
New frontiers in coral geochronology: advancing the state of the art

NASA Astrophysics Data System (ADS)

Thompson, William G.

2010-05-01

New developments in mass spectrometry and a better understanding of open-system processes are ushering in a new era of precision and accuracy in coral geochronology. An effort is underway to develop a uniform set of reference materials and reporting standards to assure age comparability between laboratories and eliminate inter-laboratory and age interpretation biases. PALSEA is a PAGES/IMAGES working group that aims to extract information about ice sheet response to temperature change by examining the history of sea during past interglacials. As reef-building corals are one of the primary archives of past sea levels, the U-series coral dating community is well represented in this group. During workshop discussions, it became clear that further progress on the sea level problem requires engaging the coral dating community in a cooperative standardization effort. Improvements in analytical precision continue to extend the potential precision and range of the U-Th chronometer. As a result, assuring comparability of ages reported by different labs becomes a crucial issue. Ideally, all measurements should be traceable to the same set of reference standards. Unfortunately, internationally recognized standards are not currently available. A widely used U/Th uraninite standard, HU-1, is no longer be suitable, as different aliquots have different isotope ratios and the assumption of radioactive equilibrium no longer appears valid when measured at current levels of precision. The time is ripe for the development of new reference standards. A strategy for their production and distribution has been initiated in collaboration with the NERC Isotope Geosciences Laboratory, UK, and drawing on the experiences of the EARTHTIME initiative (http://www.earth-time.org). Quaternary sea level data is presently scattered across the scientific literature with widely varying reporting formats, screening and correction criteria, and decay constants. Stratigraphic information is often incomplete, and elevations are not tied to consistent benchmarks. It would be highly desirable to compile existing data in a uniform format that can be made available to the wider community, and to adopt a uniform set of standards for future data reporting. While best practices for sample screening and/or age correction are still keenly debated, reported ages depend heavily on assumptions about the 234U/238U history of seawater over the last 800 thousand years. A standard history of ocean 234U/238U for quality and correction criteria, with associated error estimates, would make ages reported by different labs more directly comparable. Data reduction and archiving software has been developed as part of the EARTHTIME project, and discussions are underway to adapt this software for the U-Th chronometer. Standardized reporting through data reduction and databasing software has great potential to make U-series dating of coral sea-level indicators more useful and accessible to the wider paleoclimate community.
Quantification of shoreline change along Hatteras Island, North Carolina: Oregon Inlet to Cape Hatteras, 1978-2002, and associated vector shoreline data

USGS Publications Warehouse

Hapke, Cheryl J.; Henderson, Rachel E.

2015-01-01

Shoreline change spanning twenty-four years was assessed along the coastline of Cape Hatteras National Seashore, at Hatteras Island, North Carolina. The shorelines used in the analysis were generated from georeferenced historical aerial imagery and are used to develop shoreline change rates for Hatteras Island, from Oregon Inlet to Cape Hatteras. A total of 14 dates of aerial photographs ranging from 1978 through 2002 were obtained from the U.S. Army Corp of Engineers Field Research Facility in Duck, North Carolina, and scanned to generate digital imagery. The digital imagery was georeferenced and high water line shorelines (interpreted from the wet/dry line) were digitized from each date to produce a time series of shorelines for the study area. Rates of shoreline change were calculated for three periods: the full span of the time series, 1978 through 2002, and two approximately decadal subsets, 1978–89 and 1989–2002.
An annually resolved precisely-dated speleothem record from the Guatemala/Belize border

NASA Astrophysics Data System (ADS)

Burnett, A.; Winter, A.; Miller, T.; Haug, G. H.; Edwards, R.; Cheng, H.

2009-12-01

A precisely dated, high resolution record from Guatemala covering the last millennium, located at ~17°N, sheds light on the Central American climatic response to the Medieval Climate Anomaly (MCA) and the Little Ice Age (LIA). Our record began growing at ~1025 AD and is marked by the highest δ18O values in the entire record at this time, indicative of arid conditions and low precipitation. This coincides with the end of the Terminal Classic Drought period (TCD) in Central America, which has previously been dated at ~1100 AD at 20°N (Hodell et al., 2005) and 1000 AD at 10°N (Haug et al., 2003). Our new date for the end of the TCD, based on a U/Th age model of 13 U/Th dates with errors ranging from 3 to 87 years, provides a more precise estimate of the return to more humid conditions in the region. The Medieval Climate Anomaly (MCA), a period of time from ~1000 to ~1200 AD during which there were higher temperatures throughout Europe (Lamb, 1965), is marked by moderate δ18O values of -3.3. In 1400 AD our record hits a local δ18O minimum of -3.7, indicative of high precipitation at this time, and then steadily climbs until 1430, at which time the record abruptly stops. The record doesn’t resume until 1682 AD, though the growth axis of the stalagmite changed during the hiatus. The change in growth axis is likely due to an earthquake in this interval. Although many earthquakes have struck this region throughout history, a particularly devastating quake struck in 1541 that was so large the capital was entirely destroyed. Reports of this quake were printed throughout Central America and were some of the first secular writings in the New World Spanish kingdom (pg. 27, Nauman, 1999). The hiatus in our record, from 1430 to 1682, corresponds to the broader period of time known as the Little Ice Age, dated from ~1550 to ~1850 (Lamb, 1985, p. 150; Bradley et al., 2003). In the Yucatan Peninsula, arid conditions began in ~1450 (Hodell et al., 2005); the Cariaco Basin records dry conditions from ~1400 to 1750 AD (Haug et al., 2001), though the nature of that record makes it difficult to assign a start and end point to the drought period, and in the nearby Caribbean SSTs were 2°-3° colder (Winter et al., 2000). Our record agrees with these earlier assessments; although the most intense portion of this drought lasted from 1430 to 1682, elevated δ18O indicates that drought-like conditions endured from ~1400 to ~1700. Zhang and Delworth (2005) modeled the effect of a weakened Atlantic thermohaline circulation and found that this signal is transmitted to the Pacific via Central America; strong cooling in the tropical Atlantic off the Central American coast, such as occurred during the LIA, causes strongly reduced precipitation throughout Central America. Further modeling has suggested that northern hemisphere cooling would lead to a southward displacement of the ITCZ (Zhang and Delworth, 2005; Broccoli et al., 2006). This helps to explain the regional evidence for drought during the LIA in Central America.
Congressional Submission RDT&E Descriptive Summaries, FY 1994

DTIC Science & Technology

1993-04-01

U) Extremely High Frequency (EHF) lower cost, communication technologies ( ASTEC ) will be developed to support the ASD/C 3 1 MILSATCOM modernization...restructured and formalized into the ASTEC , CAMEO and IMPACT Programs. F. (U) PROGRAM DOCUMENTATION: * (U) U.S. Air Force/DARPA MOA dated 1988 * (U) U.S...Army/DARPA MOA dated 1990 * (U) SDIO/DARPA MOA dated 1990 * (U) DARPA/U.S. Air Force TAOS MOA dated 1992 * (U) DARPA/Joint Services ASTEC MOA (in
The age of Homo naledi and associated sediments in the Rising Star Cave, South Africa

PubMed Central

Dirks, Paul HGM; Roberts, Eric M; Hilbert-Wolf, Hannah; Kramers, Jan D; Hawks, John; Dosseto, Anthony; Duval, Mathieu; Elliott, Marina; Evans, Mary; Grün, Rainer; Hellstrom, John; Herries, Andy IR; Joannes-Boyau, Renaud; Makhubela, Tebogo V; Placzek, Christa J; Robbins, Jessie; Spandler, Carl; Wiersma, Jelle; Woodhead, Jon; Berger, Lee R

2017-01-01

New ages for flowstone, sediments and fossil bones from the Dinaledi Chamber are presented. We combined optically stimulated luminescence dating of sediments with U-Th and palaeomagnetic analyses of flowstones to establish that all sediments containing Homo naledi fossils can be allocated to a single stratigraphic entity (sub-unit 3b), interpreted to be deposited between 236 ka and 414 ka. This result has been confirmed independently by dating three H. naledi teeth with combined U-series and electron spin resonance (US-ESR) dating. Two dating scenarios for the fossils were tested by varying the assumed levels of 222Rn loss in the encasing sediments: a maximum age scenario provides an average age for the two least altered fossil teeth of 253 +82/–70 ka, whilst a minimum age scenario yields an average age of 200 +70/–61 ka. We consider the maximum age scenario to more closely reflect conditions in the cave, and therefore, the true age of the fossils. By combining the US-ESR maximum age estimate obtained from the teeth, with the U-Th age for the oldest flowstone overlying Homo naledi fossils, we have constrained the depositional age of Homo naledi to a period between 236 ka and 335 ka. These age results demonstrate that a morphologically primitive hominin, Homo naledi, survived into the later parts of the Pleistocene in Africa, and indicate a much younger age for the Homo naledi fossils than have previously been hypothesized based on their morphology. DOI: http://dx.doi.org/10.7554/eLife.24231.001 PMID:28483040
Hydrodynamic-Driven Stability Analysis of Morphological Patterns on Stalactites and Implications for Cave Paleoflow Reconstructions

NASA Astrophysics Data System (ADS)

Camporeale, Carlo; Ridolfi, Luca

2012-06-01

A novel hydrodynamic-driven stability analysis is presented for surface patterns on speleothems, i.e., secondary sedimentary cave deposits, by coupling fluid dynamics to the geochemistry of calcite precipitation or dissolution. Falling film theory provides the solution for the flow-field and depth perturbations, the latter being crucial to triggering patterns known as crenulations. In a wide range of Reynolds numbers, the model provides the dominant wavelengths and pattern celerities, in fair agreement with field data. The analysis of the phase velocity of ridges on speleothems has a potential as a proxy of past film flow rates, thus suggesting a new support for paleoclimate analyses.
Influences of the Agulhas Current on South African terrestrial climate as inferred from speleothem stable isotope records

NASA Astrophysics Data System (ADS)

Braun, K.; Bar-Matthews, M.; Ayalon, A.; Marean, C.; Herries, A. I. R.; Zahn, R.; Matthews, A.

2012-04-01

South African (SA) climate is strongly influenced by the circulation systems surrounding the subcontinent. The warm tropical Agulhas Current provides large amounts of moisture, transported onshore by south-easterly trade winds during summer. As the trade wind shifts north during winter, the south-western tip of SA is especially affected by temperate westerlies. High amounts of rainfall from the Benguela region off the west coast then only affect the very south-west of the country. This seasonal pattern creates a highly variable terrestrial climate, characterized by strong E-W gradients in the seasonal distribution and amount of rainfall. As summer and winter rain is derived from sources with different properties (density, salinity, temperature), the rainfall also displays seasonal isotopic compositional variations, as for example the present mean δ18O of rainfall in Mossel Bay located in the transition region varies from ~0.13‰ in January to -6.05‰ in July. Vegetation type (C3 vs C4) also follows the rainfall regime with C4 vegetation dominating in the summer rainfall region. As part of the GATEWAYS project, speleothems are used as an excellent, high resolution, precisely dated archive of terrestrial paleoenvironmental conditions[1]. This study focuses on a speleothem record from Crevice Cave on the South African south coast (near Mossel Bay), covering the interval between ~111 and ~53 ka[1,2]. At present, the area is influenced by both summer and winter rainfall, and has mostly C3 type vegetation. Variations in the past show more positive δ18O and δ13C values in the interval corresponding to the glacial MIS 4 and indicate increased summer rainfall and C4 vegetation. This contradicts the common assumption that MIS 4 was characterized by a northward shift of the climatic belts over SA and an increase of winter rainfall and C3 vegetation in the cave area[3]. Comparison of the record to marine sediment cores from the Agulhas Retroflection area[4] and the Cape Basin[5,6] as well as an ice-core record from Antarctica[7] reveal that the speleothem δ18O and δ13C are more closely related to the sea surface temperature shifts in the Agulhas region and Antarctica (with lower δ18O and δ13C values corresponding to higher temperatures) than to the influence of global ice-volume related changes in the isotopic composition of the ocean. A contemporary record from a cave site situated ~92 km inland from Mossel Bay (E-Flux Cave, Klein Karoo) shows a very different signal, corresponding to overall changes in Obliquity[8]. The influence of the Agulhas Current is thus apparent on the coast, but reduced inland. [1] Bar-Matthews, M. et al. 2010. Quaternary Science Reviews 29 p2131. [2] Braun, K. et al. 2011. Conference Abstract, Climate Change - The Karst Record 6. Birmingham England p27. [3] Chase, B. M. & Meadows, M. E., 2007. Earth-Science Reviews 84 p103. [4] Cortese, G. et al. 2004. Earth and Planetary Science Letters 222 p767. [5] Martínez-Méndez, G. et al. (2010). Paleoceanography 25(PA4227): doi:10.1029/2009PA001879. [6] Peeters, F. J. C. et al. 2004. Nature 430 p661. [7] Petit, J. R. et al. 1999. Nature 399 p429. [8] Berger, A. L. 1978. Quaternary Research 9 p139.
Investigating the Usefulness of Cosmogenic in situ 14C for the Dating of Alluvial Fan Surfaces

NASA Astrophysics Data System (ADS)

Goehring, B. M.; Blisniuk, K.; Moon, S.

2017-12-01

Accurate and unambiguous constraints on the age of alluvial fan surfaces remain one of the ultimate achievements for the application of cosmogenic nuclides exposure dating. Information on the age of a fan is not only useful for understanding the rate of sediment transfer from adjacent hillslopes, but also the displacement of an alluvial fan surface and their incised channels represent one of the clearest markers of long-term (102 - 104 years) slip along faults in many regions. Common nuclides such as 10Be, 26Al, and 36Cl, which are often applied to dating alluvial fans, are hampered by inheritance due to their long half-life as nuclides accumulate during exhumation and transport. Here, we present results from a systematic study investigating the usefulness of the cosmogenic nuclide carbon-14 (14C) from the Ash Wash Fan of the Anza Borrego Desert, California, which is well-dated with both 10Be of amalgamated boulder surfaces and U-series ages from pedogenic carbonates. We sampled individual boulders from multiple fan channel bars, rather than an amalgamation of many boulders from a single fan channel bar. Our new14C results yield a median ± half-interquartile age of 4.7 ± 0.8 ka (n = 4, 1 outlier removed). These results are in excellent agreement with the existing U-series and new p-IR-IRSL chronology (5.2 ± 0.3 ka and 5.5 ± 0.8 ka, respectively), but slightly younger than the previously published 10Be amalgamation date of 7.0 ± 1.0 ka. In contrast, 10Be exposure dates of the same boulder in our study yield a median ± half-interquartile age of 10.9 ± 2.6 ka, which we interpret to be the result of insufficient burial time during transport and/or erosion of the boulder to remove accumulated 10Be. Our results suggest that 14C may be a viable chronometer of alluvial fan surfaces less than ca. 25 ka. Finally, inspired by approaches in the burial dating community, we will also explore the possibility of a paired nuclide isochron approach. Measured 14C and 10Be concentrations display a strong correlation (r2 = 0.9), suggesting there may be gains to be made using a paired nuclide approach; we will explore this relationship further in the presentation.
Sediment data collected in 2010 from Cat Island, Mississippi

USGS Publications Warehouse

Buster, Noreen A.; Kelso, Kyle W.; Miselis, Jennifer L.; Kindinger, Jack G.

2014-01-01

Scientists from the U.S. Geological Survey, St. Petersburg Coastal and Marine Science Center, in collaboration with the U.S. Army Corps of Engineers, conducted geophysical and sedimentological surveys in 2010 around Cat Island, Mississippi, which is the westernmost island in the Mississippi-Alabama barrier island chain. The objective of the study was to understand the geologic evolution of Cat Island relative to other barrier islands in the northern Gulf of Mexico by identifying relationships between the geologic history, present day morphology, and sediment distribution. This data series serves as an archive of terrestrial and marine sediment vibracores collected August 4-6 and October 20-22, 2010, respectively. Geographic information system data products include marine and terrestrial core locations and 2007 shoreline data. Additional files include marine and terrestrial core description logs, core photos, results of sediment grain-size analyses, optically stimulated luminescence dating and carbon-14 dating locations and results, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata.
U-series dating of Lake Nyos maar basalts, Cameroon (West Africa): Implications for potential hazards on the Lake Nyos dam

NASA Astrophysics Data System (ADS)

Aka, Festus T.; Yokoyama, Tetsuya; Kusakabe, Minoru; Nakamura, Eizo; Tanyileke, Gregory; Ateba, Bekoa; Ngako, Vincent; Nnange, Joseph; Hell, Joseph

2008-09-01

From previously published 14C and K-Ar data, the age of formation of Lake Nyos maar in Cameroon is still in dispute. Lake Nyos exploded in 1986, releasing CO 2 that killed 1750 people and over 3000 cattle. Here we report results of the first measurements of major elements, trace elements and U-series disequilibria in ten basanites/trachy-basalts and two olivine tholeiites from Lake Nyos. It is the first time tholeiites are described in Lake Nyos. But for the tholeiites which are in 238U- 230Th equilibrium, all the other samples possess 238U- 230Th disequilibrium with 15 to 28% enrichment of 230Th over 238U. The ( 226Ra/ 230Th) activity ratios of these samples indicate small (2 to 4%) but significant 226Ra excesses. U-Th systematics and evidence from oxygen isotopes of the basalts and Lake Nyos granitic quartz separates show that the U-series disequilibria in these samples are source-based and not due to crustal contamination or post-eruptive alteration. Enrichment of 230Th is strong prima facie evidence that Lake Nyos is younger than 350 ka. The 230Th- 226Ra age of Nyos samples calculated with the ( 226Ra/ 230Th) ratio for zero-age Mt. Cameroon samples is 3.7 ± 0.5 ka, although this is a lower limit as the actual age is estimated to be older than 5 ka, based on the measured mean 230Th/ 238U activity ratio. The general stability of the Lake Nyos pyroclastic dam is a cause for concern, but judging from its 230Th- 226Ra formation age, we do not think that in the absence of a big rock fall or landslide into the lake, a big earthquake or volcanic eruption close to the lake, collapse of the dam from erosion alone is as imminent and alarming as has been suggested.
Climatic evolution of Marine Isotope Stage 5 and particularly the Eemian reconstructed from precisely dated speleothems from western Germany

NASA Astrophysics Data System (ADS)

Scholz, Denis; Hoffmann, Dirk L.; Spötl, Christoph; Hopcroft, Peter; Jochum, Klaus Peter; Richter, Detlev K.

2015-04-01

We present high-resolution δ18O, δ13C and trace element profiles for three stalagmites from western Germany, which grew during Marine Isotope Stage (MIS) 5. All stalagmites were precisely dated by MC-ICPMS 230Th/U-dating. Stalagmite HBSH-1 from Hüttenbläserschachthöhle grew between 130 and 80 ka and provides a climate record with decadal to centennial resolution. The other two stalagmites grew faster than HBSH 1, but their growth phases are shorter. Stalagmite HBSH 5 grew between 129 and 122 ka, whereas stalagmite BR 5 grew between 126 and 122 ka. The record of HBSH 1 shows four growth interruptions coinciding with Greenland Stadials (GS) 21, 22, 24, 25, and 26. This shows that stalagmite growth is a very sensitive proxy for cool and dry conditions in the northern hemisphere and enables us to precisely determine the timing and duration of the GS. We interpret stalagmite δ18O values as a proxy for supra-regional temperature changes in the North Atlantic realm, which is paticularly evident from their close resemblance with the δ18O values of the NGRIP and NEEM ice core records. Stalagmite δ13C values primarily reflect changes in hydrological balance and (local) vegetation and are, thus, a proxy for terrestrial climate change in central European. The δ13C record shows three pronounced negative peaks during MIS 5, and their timing is in agreement with MIS 5e, 5c and 5a. This suggests generally warm and humid climate in central Europe during these phases. The evolution of the δ18O and δ13C values during the Eemian is not parallel. The δ18O values progressively increase from 130 ka, peak at 125 ka and subsequently show a gradual decrease. The δ13C values, in contrast, start to decrease at 123 ka, show a negative peak at 120 ka and an aprupt increase at 114 ka. This suggests that the Eemian sensu strictu lasted from 124 to 114 ka, in agreement with a marine record from the Norwegian Sea and indicates and a strong influence on central European climate from high northern latitudes. We also compare our records with other MIS 5 climate records and climate modelling simulations performed with the general circulation model FAMOUS.
Understanding the d18O Response to Precession in the South Asian Monsoon Region

NASA Astrophysics Data System (ADS)

Tabor, C. R.; Otto-Bliesner, B. L.; Brady, E. C.; Nusbaumer, J. M.; Zhu, J.; Erb, M. P.

2017-12-01

Speleothem records from the South Asian Monsoon (SAM) region display d18O variability at orbital frequencies. The dominant mode of variability in many of these records reflects cycles of precession. There are several potential explanations for why speleothem records from the SAM region show a strong precession signal, including the amount effect, temperature differences, and circulation changes. Here, we use a version of the Community Earth System Model with water isotope tracking capability to explore the mechanisms responsible for precession driven d18O variability in the SAM region. By using a fully coupled model with idealized orbits and regional isotope tracking techniques, we are able to tease apart the various contributions to the precession driven d18O signal found in the SAM speleothem records. Our preliminary results suggest that neither the amount effect nor temperature differences cause the majority of SAM d18O response to changes in precession. Instead, changes in the relative moisture contributions from different source regions drive much of the d18O variability. During Northern Hemisphere summer at aphelion, much of the SAM precipitation sources from the nearby ocean. The nearby location of these sources limits the amount of rainout that occurs before reaching the SAM region, which results in a relatively enriched precipitation d18O signal. Conversely, during Northern Hemisphere summer at perihelion, a greater portion of the SAM precipitation sources from far away regions such as the Southern Hemisphere and Northern Africa. Water vapor from these sources is more depleted by the time it reaches the SAM region, leading to precipitation relatively depleted in d18O as well. Further, we find that the modeled d18O signals of soil water better match the d18O signals in the SAM speleothems, suggesting that local evaporation also plays an important role.
ENSO-cave drip water hydrochemical relationship: a 7-year dataset from south-eastern Australia

NASA Astrophysics Data System (ADS)

Tadros, Carol V.; Treble, Pauline C.; Baker, Andy; Fairchild, Ian; Hankin, Stuart; Roach, Regina; Markowska, Monika; McDonald, Janece

2016-11-01

Speleothems (cave deposits), used for palaeoenvironmental reconstructions, are deposited from cave drip water. Differentiating climate and karst processes within a drip-water signal is fundamental for the correct identification of palaeoenvironmental proxies and ultimately their interpretation within speleothem records. We investigate the potential use of trace element and stable oxygen-isotope (δ18O) variations in cave drip water as palaeorainfall proxies in an Australian alpine karst site. This paper presents the first extensive hydrochemical and δ18O dataset from Harrie Wood Cave, in the Snowy Mountains, south-eastern (SE) Australia. Using a 7-year long rainfall δ18O and drip-water Ca, Cl, Mg / Ca, Sr / Ca and δ18O datasets from three drip sites, we determined that the processes of mixing, dilution, flow path change, carbonate mineral dissolution and prior calcite precipitation (PCP) accounted for the observed variations in the drip-water geochemical composition. We identify that the three monitored drip sites are fed by fracture flow from a well-mixed epikarst storage reservoir, supplied by variable concentrations of dissolved ions from soil and bedrock dissolution. We constrained the influence of multiple processes and controls on drip-water composition in a region dominated by El Niño-Southern Oscillation (ENSO). During the El Niño and dry periods, enhanced PCP, a flow path change and dissolution due to increased soil CO2 production occurred in response to warmer than average temperatures in contrast to the La Niña phase, where dilution dominated and reduced PCP were observed. We present a conceptual model, illustrating the key processes impacting the drip-water chemistry. We identified a robust relationship between ENSO and drip-water trace element concentrations and propose that variations in speleothem Mg / Ca and Sr / Ca ratios may be interpreted to reflect palaeorainfall conditions. These findings inform palaeorainfall reconstruction from speleothems regionally and provide a basis for palaeoclimate studies globally, in regions where there is intermittent recharge variability.
Radiometric dating of the type-site for Homo heidelbergensis at Mauer, Germany.

PubMed

Wagner, Günther A; Krbetschek, Matthias; Degering, Detlev; Bahain, Jean-Jacques; Shao, Qingfeng; Falguères, Christophe; Voinchet, Pierre; Dolo, Jean-Michel; Garcia, Tristan; Rightmire, G Philip

2010-11-16

The Mauer mandible, holotype of Homo heidelbergensis, was found in 1907 in fluvial sands deposited by the Neckar River 10 km southeast of Heidelberg, Germany. The fossil is an important key to understanding early human occupation of Europe north of the Alps. Given the associated mammal fauna and the geological context, the find layer has been placed in the early Middle Pleistocene, but confirmatory chronometric evidence has hitherto been missing. Here we show that two independent techniques, the combined electron spin resonance/U-series method used with mammal teeth and infrared radiofluorescence applied to sand grains, date the type-site of Homo heidelbergensis at Mauer to 609 ± 40 ka. This result demonstrates that the mandible is the oldest hominin fossil reported to date from central and northern Europe and raises questions concerning the phyletic relationship of Homo heidelbergensis to more ancient populations documented from southern Europe and in Africa. We address the paleoanthropological significance of the Mauer jaw in light of this dating evidence.
Radiometric dating of the type-site for Homo heidelbergensis at Mauer, Germany

PubMed Central

Wagner, Günther A.; Krbetschek, Matthias; Degering, Detlev; Bahain, Jean-Jacques; Shao, Qingfeng; Falguères, Christophe; Voinchet, Pierre; Dolo, Jean-Michel; Garcia, Tristan; Rightmire, G. Philip

2010-01-01

The Mauer mandible, holotype of Homo heidelbergensis, was found in 1907 in fluvial sands deposited by the Neckar River 10 km southeast of Heidelberg, Germany. The fossil is an important key to understanding early human occupation of Europe north of the Alps. Given the associated mammal fauna and the geological context, the find layer has been placed in the early Middle Pleistocene, but confirmatory chronometric evidence has hitherto been missing. Here we show that two independent techniques, the combined electron spin resonance/U-series method used with mammal teeth and infrared radiofluorescence applied to sand grains, date the type-site of Homo heidelbergensis at Mauer to 609 ± 40 ka. This result demonstrates that the mandible is the oldest hominin fossil reported to date from central and northern Europe and raises questions concerning the phyletic relationship of Homo heidelbergensis to more ancient populations documented from southern Europe and in Africa. We address the paleoanthropological significance of the Mauer jaw in light of this dating evidence. PMID:21041630
Reconstructing last 2000 years of temperature variation from Pyrenean caves (N Spain)

NASA Astrophysics Data System (ADS)

Moreno, Ana; Bartolomé, Miguel; Pérez, Carlos; Sancho, Carlos; Cacho, Isabel; Stoll, Heather; Delgado-Huertas, Antonio; Edwards, R. Lawrence; Cheng, Hai

2016-04-01

The Central Pyrenees, and particularly the protected area known as Ordesa and Monte Perdido National Park, is a high-altitude karstic region rich in cavities with active drips and present precipitation of carbonates. Although not generally very abundant, there are speleothems growths in several of those cavities. We present here (1) a three-year seasonal monitoring survey to isolate the environmental parameters influencing isotopic composition of farmed carbonate and (2) the last 2000 years isotopic record resulting from compiling seven stalagmites from three different caves. In temperate regions such as the NE Iberian Peninsula is difficult to discern the influences on δ18O variation in speleothems since temperature, amount of precipitation or even source effect are usually acting simultaneously. Main results after three years monitoring period indicate a strong dependence on air temperature through its influence on rainfall δ18O, although a small amount effect is not discarded. The good overlapping during the observational period of δ18O from actively growing modern stalagmites and air temperature in the area supports this dependence and provides a reliable proxy for the temperature evolution along last millennia. The stalagmites belong to three different caves (Seso, Gloces and B-1 caves) but still present a very coherent isotopic signal allowing us to discard local effects (diagenetic imprint, non-equilibrium fractionation) and to produce a stacked record with decadal resolution. Interpreting this signal as regional temperature variation divides the temporal sequence in five main periods, in consonance with historical stages. Thus, a continuous decrease in temperature characterized the end of the Roman period (0-500 AD). Lower temperatures are dominant during "Dark Ages" (500-1000 AD) that increase during the Medieval Climate Anomaly (MCA, 1000-1400 AD). Following this warm period, the cold signal during the Little Ice Age is very well replicated in several speleothems, even for short events lasting less than a decade. The warming that identifies the Industrial Era (from 1850 AD to present day) is also well document. This reconstruction is in striking similarity with other high-resolution records in Europe and, particularly, with global temperature reconstructions for last 2000 years. In addition, the fact that the δ18O signal presented here is so well replicated in speleothems from different caves gives strong support to our interpretation and opens the door to further research on Pyrenean speleothems as exceptional archives of thermal oscillations.
Lessons learned from oxygen isotopes in modern precipitation applied to interpretation of speleothem records of paleoclimate from eastern Asia

NASA Astrophysics Data System (ADS)

Dayem, Katherine E.; Molnar, Peter; Battisti, David S.; Roe, Gerard H.

2010-06-01

Variability in oxygen isotope ratios collected from speleothems in Chinese caves is often interpreted as a proxy for variability of precipitation, summer precipitation, seasonality of precipitation, and/or the proportion of 18O to 16O of annual total rainfall that is related to a strengthening or weakening of the East Asian monsoon and, in some cases, to the Indian monsoon. We use modern reanalysis and station data to test whether precipitation and temperature variability over China can be related to changes in climate in these distant locales. We find that annual and rainy season precipitation totals in each of central China, south China, and east India have correlation length scales of ∼ 500 km, shorter than the distance between many speleothem records that share similar long-term time variations in δ18O values. Thus the short distances of correlation do not support, though by themselves cannot refute, the idea that apparently synchronous variations in δ18O values at widely spaced (> 500 km) caves in China are due to variations in annual precipitation amounts. We also evaluate connections between climate variables and δ18O values using available instrumental measurements of δ18O values in precipitation. These data, from stations in the Global Network of Isotopes in Precipitation (GNIP), show that monthly δ18O values generally do not correlate well with either local precipitation amount or local temperature, and the degree to which monthly δ18O values do correlate with them varies from station to station. For the few locations that do show significant correlations between δ18O values and precipitation amount, we estimate the differences in precipitation amount that would be required to account for peak-to-peak differences in δ18O values in the speleothems from Hulu and Dongge caves, assuming that δ18O scales with the monthly amount of precipitation or with seasonal differences in precipitation. Insofar as the present-day relationship between δ18O values and monthly precipitation amounts can be applied to past conditions, differences of at least 50% in mean annual precipitation would be required to explain the δ18O variations on orbital time scales, which are implausibly large and inconsistent with published GCM results. Similarly, plausible amplitudes of seasonal cycles in amounts or in seasonal variations in δ18O values can account for less than half of the 4-5‰ difference between glacial and interglacial δ18O values from speleothems in China. If seasonal cycles in precipitation account for the amplitudes of δ18O values on paleoclimate timescales, they might do so by extending or contracting the durations of seasons (a frequency modulation of the annual cycle), but not by simply varying the amplitudes of the monthly rainfall amounts or monthly average δ18O values (amplitude modulation). Allowing that several processes can affect seasonal variability in isotopic content, we explore the possibility that one or more of the following processes contribute to variations in δ18O values in Chinese cave speleothems: different source regions of the precipitation, which bring different values of δ18O in vapor; different pathways between the moisture source and the paleorecord site along which exchange of 18O between vapor, surface water, and condensate might differ; a different mix of processes involving condensation and evaporation within the atmosphere; or different types of precipitation. Each may account for part of the range of δ18O values revealed by speleothems, and each might contribute to seasonal differences between past and present that do not scale with monthly or even seasonal precipitation amounts.

Holocene geologic slip rate for the Banning strand of the southern San Andreas Fault, southern California

USGS Publications Warehouse

Gold, Peter O.; Behr, Whitney M.; Rood, Dylan; Sharp, Warren D.; Rockwell, Thomas; Kendrick, Katherine J.; Salin, Aaron

2015-01-01

Northwest directed slip from the southern San Andreas Fault is transferred to the Mission Creek, Banning, and Garnet Hill fault strands in the northwestern Coachella Valley. How slip is partitioned between these three faults is critical to southern California seismic hazard estimates but is poorly understood. In this paper, we report the first slip rate measured for the Banning fault strand. We constrain the depositional age of an alluvial fan offset 25 ± 5 m from its source by the Banning strand to between 5.1 ± 0.4 ka (95% confidence interval (CI)) and 6.4 + 3.7/−2.1 ka (95% CI) using U-series dating of pedogenic carbonate clast coatings and 10Be cosmogenic nuclide exposure dating of surface clasts. We calculate a Holocene geologic slip rate for the Banning strand of 3.9 + 2.3/−1.6 mm/yr (median, 95% CI) to 4.9 + 1.0/−0.9 mm/yr (median, 95% CI). This rate represents only 25–35% of the total slip accommodated by this section of the southern San Andreas Fault, suggesting a model in which slip is less concentrated on the Banning strand than previously thought. In rejecting the possibility that the Banning strand is the dominant structure, our results highlight an even greater need for slip rate and paleoseismic measurements along faults in the northwestern Coachella Valley in order to test the validity of current earthquake hazard models. In addition, our comparison of ages measured with U-series and 10Be exposure dating demonstrates the importance of using multiple geochronometers when estimating the depositional age of alluvial landforms.
Changes in monsoon-driven upwelling in the South China Sea over glacial Terminations I and II: a multi-proxy record

NASA Astrophysics Data System (ADS)

Sadatzki, Henrik; Sarnthein, Michael; Andersen, Nils

2016-06-01

Upwelling intensity in the South China Sea has changed over glacial-interglacial cycles in response to orbital-scale changes in the East Asian Monsoon. Here, we evaluate new multi-proxy records of two sediment cores from the north-eastern South China Sea to uncover millennial-scale changes in winter monsoon-driven upwelling over glacial Terminations I and II. On the basis of U/Th-based speleothem chronology, we compare these changes with sediment records of summer monsoon-driven upwelling east of South Vietnam. Ocean upwelling is traced by reduced (UK'37-based) temperature and increased nutrient and productivity estimates of sea surface waters (δ13C on planktic foraminifera, accumulation rates of alkenones, chlorins, and total organic carbon). Accordingly, strong winter upwelling occurred north-west of Luzon (Philippines) during late Marine Isotope Stage 6.2, Heinrich (HS) and Greenland stadials (GS) HS-11, GS-26, GS-25, HS-1, and the Younger Dryas. During these stadials, summer upwelling decreased off South Vietnam and sea surface salinity reached a maximum suggesting a drop in monsoon rains, concurrent with speleothem records of aridity in China. In harmony with a stadial-to-interstadial see-saw pattern, winter upwelling off Luzon in turn was weak during interstadials, in particular those of glacial Terminations I and II, when summer upwelling culminated east of South Vietnam. Most likely, this upwelling terminated widespread deep-water stratification, coeval with the deglacial rise in atmospheric CO2. Yet, a synchronous maximum in precipitation fostered estuarine overturning circulation in the South China Sea, in particular as long as the Borneo Strait was closed when sea level dropped below -40 m.
Precise U/Pb zircons dates of bentonites in Upper Ordovician and Lower Silurian reference sections in North America and Britain.

NASA Astrophysics Data System (ADS)

Suarez, S. E.; Brookfield, M. E.; Catlos, E. J.; Stockli, D. F.; Batchelor, R. A.

2016-12-01

The end of the Ordovician marks one of the greatest of the Earth's mass extinctions. One hypothesis explains this mass extinction as the result of a short-lived, major glaciation preceded by episodes of increased volcanism brought on by the Taconic orogeny. K-bentonites, weathered volcanic ash, provide evidence for increased volcanism. However, there is a lack of modern precise U-Pb dating of these ashes and some confusion in the biostratigraphy. The aim of this study is to obtain more precise U-Pb zircon ages from biostratigraphically constrained bentonites which will lead to better correlation of the Upper Ordovician and Lower Silurian relative time scales, as well as time the pulses of eruption. Zircon grains were extracted from the samples by heavy mineral separation and U-Pb dated using the Laser Ablation-Inductively Coupled Plasma-Mass Spectrometer at the University of Texas-Austin. We report here 3 precise U-Pb zircon ages from the Trenton Group, Ontario, Canada, and Dob's Linn, Scotland. The youngest age from the top of the Kirkfield Formation in Ontario is 448.0 +/- 18 Ma, which fits with existing late Ordovician stratigraphic ages. At Dob's Linn, Scotland, the site of the Ordovician/Silurian Global Boundary Stratigraphic Section and Point (GSSP), the youngest age for DL7, a bentonite 5 meters below the GSSP is 402.0 +/- 12.0 Ma, and for DL24L, a bentonite 8 meters above the GSSP is 358.2 +/- 7.9 Ma. These are Devonian ages in current timescales - the current age for the GSSP is 443.8 +/- 1.8 Ma, based on an U/Pb dates from a bentonite 1.6 meters above the GSSP at Dob's Linn. We are confident that our techniques rule out contamination and the most likely explanation is that the small zircons we analyzed either suffered Pb loss, or grew overgrowths during low grade hydrothermal metamorphism of the sediments during the intrusion of the Southern Upland Devonian granites during the Caledonian orogeny. These Devonian ages suggest that the 443.8 +/- 1.8 Ma age may also be suspect. The Dob's Linn site is therefore unsuitable for calibrating the biostratigraphic horizons. Work in progress will provide more U-Pb dating of bentonites from around the Ordovician-Silurian boundary in Canada, United States, Britain and Scandinavia with the aim of calibrating the local series and stages in order to help in International correlations.
The 1990 conterminous U. S. AVHRR data set

USGS Publications Warehouse

Eidenshink, Jeffery C.

1992-01-01

The U.S. Geological Survey, using NOAA-ll Advanced Very High Resolution Radiometer (AVHRR) 1-km data, has produced a time series of 19 biweekly maximum normalized difference vegetation index (NDV!) composites of the conterminous United States for the 1990 growing season. Each biweekly composite included data from approximately 20 calibrated and georegistered daily overpasses. The output is a data set which includes all five calibrated AVHRR channels, NOV! values, three satellite/solar viewing angles, and date of observation pointer for each biweekly composite. The data set is intended for assessing seasonal variations in vegetation condition and provides a foundation for studying long-term changes in vegetation resulting from human interactions or global climate alterations.
U-Th Burial Dates on Ostrich Eggshell

NASA Astrophysics Data System (ADS)

Sharp, W. D.; Fylstra, N. D.; Tryon, C. A.; Faith, J. T.; Peppe, D. J.

2015-12-01

Obtaining precise and accurate dates at archaeological sites beyond the range of radiocarbon dating is challenging but essential for understanding human origins. Eggshells of ratites (large flightless birds including ostrich, emu and others) are common in many archaeological sequences in Africa, Australia and elsewhere. Ancient eggshells are geochemically suitable for the U-Th technique (1), which has about ten times the range of radiocarbon dating (>500 rather than 50 ka), making eggshells attractive dating targets. Moreover, C and N isotopic studies of eggshell provide insights into paleovegetation and paleoprecipitation central to assessing past human-environment interactions (2,3). But until now, U-Th dates on ratite eggshell have not accounted for the secondary origin of essentially all of their U. We report a novel approach to U-Th dating of eggshell that explicitly accounts for secondary U uptake that begins with burial. Using ostrich eggshell (OES) from Pleistocene-Holocene east African sites, we have measured U and 232Th concentration profiles across OES by laser ablation ICP-MS. U commonly peaks at 10s to 100s of ppb and varies 10-fold or more across the ~2 mm thickness of OES, with gradients modulated by the layered structure of the eggshell. Common Th is high near the shell surfaces, but low in the middle "pallisade" layer of OES, making it optimal for U-Th dating. We determine U-Th ages along the U concentration gradient by solution ICP-MS analyses of two or more fractions of the pallisade layer. We then estimate OES burial dates using a simple model for diffusive uptake of uranium. Comparing such "U-Th burial dates" with radiocarbon dates for OES calcite from the same shells, we find good agreement in 7 out of 9 cases, consistent with rapid burial and confirming the accuracy of the approach. The remaining 2 eggshells have anomalous patterns of apparent ages that reveal they are unsuitable for U-Th dating, thereby providing reliability criteria innate to the U-Th data. The oldest OES we have analyzed yields a U-Th burial date of ~140 ka, indicating that U-Th burial dating of OES may be applicable throughout the Late Pleistocene. 1. Magee, J.W. et al. (2009) Quatern. Geochron. 4, 84-89. 2. Johnson, B.J. et al. (1998) Geochim. Cosmochim. Acta 62, 2451-2461. 3. Miller, G.H. et al. (2005) Science 309, 287-290.
Uranium uptake history, open-system behaviour and uranium-series ages of fossil Tridacna gigas from Huon Peninsula, Papua New Guinea

NASA Astrophysics Data System (ADS)

Ayling, Bridget F.; Eggins, Stephen; McCulloch, Malcolm T.; Chappell, John; Grün, Rainer; Mortimer, Graham

2017-09-01

Molluscs incorporate negligible uranium into their skeleton while they are living, with any uranium uptake occurring post-mortem. As such, closed-system U-series dating of molluscs is unlikely to provide reliable age constraints for marine deposits. Even the application of open-system U-series modelling is challenging, because uranium uptake and loss histories can affect time-integrated uranium distributions and are difficult to constrain. We investigate the chemical and isotopic distribution of uranium in fossil Tridacna gigas (giant clams) from Marine Isotope Stage (MIS) 5e (128-116 ka) and MIS 11 (424-374 ka) reefs at Huon Peninsula in Papua New Guinea. The large size of the clams enables detailed chemical and isotopic mapping of uranium using LA-ICPMS and LA-MC-ICPMS techniques. Within each fossil Tridacna specimen, marked differences in uranium concentrations are observed across the three Tridacna growth zones (outer, inner, hinge), with the outer and hinge zones being relatively enriched. In MIS 5e and MIS 11 Tridacna, the outer and hinge zones contain approximately 1 ppm and 5 ppm uranium respectively. In addition to uptake of uranium, loss of uranium appears prevalent, especially in the MIS 11 specimens. The effect of uranium loss is to elevate measured [230Th/238U] values with little effect on [234U/238U] values. Closed-system age estimates are on average 50% too young for the MIS 5e Tridacna, and 25% too young for the MIS 11 Tridacna. A complex, multi-stage uptake and loss history is interpreted for the fossil Tridacna and we demonstrate that they cannot provide independent, reliable geochronological controls on the timing of past reef growth at Huon Peninsula.
Metric and geometric morphometric analysis of new hominin fossils from Maba (Guangdong, China).

PubMed

Xiao, Dongfang; Bae, Christopher J; Shen, Guanjun; Delson, Eric; Jin, Jennie J H; Webb, Nicole M; Qiu, Licheng

2014-09-01

We present an analysis of a set of previously unreported hominin fossils from Maba (Guangdong, China), a cave site that is best known for the presence of a partial hominin cranium currently assigned as mid-Pleistocene Homo and that has been traditionally dated to around the Middle-Late Pleistocene transition. A more recent set of Uranium series dates indicate that the Maba travertine may date to >237 ka (thousands of years ago), as opposed to the original U-series date, which placed Maba at 135-129 ka. The fossils under study include five upper first and second molars and a partial left mandible with a socketed m3, all recovered from different parts of the site than the cranium or the dated sediments. The results of our metric and 2D geometric morphometric ('GM') study suggest that the upper first molars are likely from modern humans, suggesting a more recent origin. The upper second molars align more closely with modern humans, though the minimum spanning tree from the 2D GM analysis also connects Maba to Homo neanderthalensis. The patterning in the M2s is not as clear as with the M1s. The m3 and partial mandible are morphometrically intermediate between Holocene modern humans and older Homo sapiens. However, a minimum spanning tree indicates that both the partial mandible and m3 align most closely with Holocene modern humans, and they also may be substantially younger than the cranium. Because questions exist regarding the context and the relationship of the dated travertine with the hominin fossils, we suggest caution is warranted in interpreting the Maba specimens. Copyright © 2014 Elsevier Ltd. All rights reserved.
San Bernardino Cave (Italy) and the Appearance of Levallois Technology in Europe: Results of a Radiometric and Technological Reassessment

PubMed Central

Picin, Andrea; Peresani, Marco; Falguères, Christophe; Gruppioni, Giulia; Bahain, Jean-Jacques

2013-01-01

The introduction of Levallois technology in Europe marked the transition from the Lower to the early Middle Paleolithic. This new method of flake production was accompanied by significant behavioral changes in hominin populations. The emergence of this technological advance is considered homogeneous in the European archaeological record at the Marine isotopic stage (MIS) 9/MIS 8 boundary. In this paper we report a series of combined electron spin resonance/U-series dates on mammal bones and teeth recovered from the lower units of San Bernardino Cave (Italy) and the technological analyses of the lithic assemblages. The San Bernardino Cave has yielded the earliest evidence of Levallois production on the Italian Peninsula recovered to date. In addition to our results and the review of the archaeological record, we describe the chronological and geographical differences between European territories and diversities in terms of technological developments. The belated emergence of Levallois technology in Italy compared to western Europe corresponds to the late Italian Neanderthal speciation event. The new radiometric dates and the technological analyses of San Bernardino Cave raise the issue of the different roles of glacial refugia in the peopling and the spread of innovative flaking strategies in Europe during the late Middle Pleistocene. PMID:24146836
Historical Orthoimagery of the Lake Tahoe Basin

USGS Publications Warehouse

Soulard, Christopher E.; Raumann, Christian G.

2008-01-01

The U.S. Geological Survey (USGS) Western Geographic Science Center has developed a series of historical digital orthoimagery (HDO) datasets covering part or all of the Lake Tahoe Basin. Three datasets are available: (A) 1940 HDOs for the southern Lake Tahoe Basin, (B) 1969 HDOs for the entire Lake Tahoe Basin, and (C) 1987 HDOs for the southern Lake Tahoe Basin. The HDOs (for 1940, 1969, and 1987) were compiled photogrammically from aerial photography with varying scales, camera characteristics, image quality, and capture dates. The resulting datasets have a 1-meter horizontal resolution. Precision-corrected Ikonos multispectral satellite imagery was used as a substitute for HDOs/DOQs for the 2002 imagery date, but these data are not available for download in this series due to licensing restrictions. The projection of the HDO data is set to UTM Zone 10, NAD 1983. The data for each of the three available dates are clipped into files that spatially approximate the 3.75-minute USGS quarter quadrangles (roughly 3,000 to 4,000 hectares), and have roughly 100 pixels (or 100 meters) of overlap to facilitate combining the files into larger regions without data gaps. The files are named after 3.75-minute USGS quarter quadrangles that cover the same general spatial extent. These files are available in the ERDAS Imagine (.img) format.
San Bernardino Cave (Italy) and the appearance of Levallois technology in Europe: results of a radiometric and technological reassessment.

PubMed

Picin, Andrea; Peresani, Marco; Falguères, Christophe; Gruppioni, Giulia; Bahain, Jean-Jacques

2013-01-01

The introduction of Levallois technology in Europe marked the transition from the Lower to the early Middle Paleolithic. This new method of flake production was accompanied by significant behavioral changes in hominin populations. The emergence of this technological advance is considered homogeneous in the European archaeological record at the Marine isotopic stage (MIS) 9/MIS 8 boundary. In this paper we report a series of combined electron spin resonance/U-series dates on mammal bones and teeth recovered from the lower units of San Bernardino Cave (Italy) and the technological analyses of the lithic assemblages. The San Bernardino Cave has yielded the earliest evidence of Levallois production on the Italian Peninsula recovered to date. In addition to our results and the review of the archaeological record, we describe the chronological and geographical differences between European territories and diversities in terms of technological developments. The belated emergence of Levallois technology in Italy compared to western Europe corresponds to the late Italian Neanderthal speciation event. The new radiometric dates and the technological analyses of San Bernardino Cave raise the issue of the different roles of glacial refugia in the peopling and the spread of innovative flaking strategies in Europe during the late Middle Pleistocene.
Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms

NASA Astrophysics Data System (ADS)

Baresel, Bjoern; Bucher, Hugo; Bagherpour, Borhan; Brosse, Morgane; Guodun, Kuang; Schaltegger, Urs

2017-04-01

High-precision U-Pb dating of single-zircon crystals by chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) is applied to volcanic beds that are intercalated in sedimentary sequences across the Permian-Triassic boundary (PTB). By assuming that the zircon crystallization age closely approximate that of the volcanic eruption and subsequent deposition, U-Pb zircon geochronology is the preferred approach for dating abiotic and biotic events, such as the formational PTB and the Permian-Triassic boundary mass extinction (PTBME). We will present new U-Pb zircon dates for a series of volcanic ash beds in shallow-marine Permian-Triassic sections in the Nanpanjiang Basin, South China. These high-resolution U-Pb dates indicate a duration of 90 ± 38 kyr for the Permian sedimentary hiatus and a duration of 13 ± 57 kyr for the overlying Triassic microbial limestone in the shallow water settings of the Nanpanjiang pull apart Basin. The age and duration of the hiatus coincides with the formational PTB and the extinction interval in the Meishan Global Stratotype Section and Point, thus strongly supporting a glacio-eustatic regression, which best explains the genesis of the worldwide hiatus straddling the PTB in shallow water records. In adjacent deep marine troughs, rates of sediment accumulation display a six-fold decrease across the PTB compatible with a dryer and cooler climate during the Griesbachian as indicated by terrestrial plants. Our model of the PTBME hinges on the synchronicity of the hiatus with the onset of the Siberian Traps volcanism. This early eruptive phase likely released sulfur-rich volatiles into the stratosphere, thus simultaneously eliciting a short-lived ice age responsible for the global regression and a brief but intense acidification. Abrupt cooling, shrunk habitats on shelves and acidification may all have synergistically triggered the PTBME. Subsequently, the build-up of volcanic CO2 induced this transient cool climate whose early phase saw the deposition of the microbial limestone.
Stratigraphic constraints on the timing and emplacement of the Alika 2 giant Hawaiian submarine landslide

USGS Publications Warehouse

McMurtry, Gary M.; Herrero-Bervera, Emilio; Cremer, Maximilian D.; Smith, John R.; Resig, Johanna; Sherman, Clark; Torresan, Michael E.

1999-01-01

Previous work has found evidence for giant tsunami waves that impacted the coasts of Lanai, Molokai and other southern Hawaiian Islands, tentatively dated at 100 + and 200 + ka by U-series methods on uplifted coral clasts. Seafloor imaging and related work off Hawaii Island has suggested the Alika phase 2 debris avalanche as the source of the ~ 100 ka "giant wave deposits", although its precise age has been elusive. More recently, a basaltic sand bed in ODP site 842 (~ 300 km west of Hawaii) estimated at 100 ?? 20 ka has been suggested to correlate with this or another large Hawaiian landslide. Our approach to the timing and linkage of giant submarine landslides and paleo-tsunami deposits is a detailed stratigraphic survey of pelagic deposits proximal to the landslide feature, beginning with a suite of seven piston, gravity and box cores collected in the vicinity of the Alika 2 slide. We used U-series dating techniques, including excess 230Th and 210Pb profiling, high-resolution paleomagnetic stratigraphy, including continuous, U-channel analysis, δ18O stratigraphy, visual and X-ray sediment lithology, and the petrology and geochemistry of the included turbidites and ash layers. Minimum ages for the Alika phase 2a slide from detailed investigation of two of the cores are 112 ± 15 ka and 125 ± 24 ka (2σ) based on excess 230Th dating. A less precise age for the Alika phase 1 and/or South Kona slide is 242 ± 80 ka (2σ), consistent with previous geological estimates. Oxygen isotope analyses of entrained planktonic foraminifera better constrain the Alika phase 2a maximum age at 127 ± 5 ka, which corresponds to the beginning of the stage 5e interglacial period. It is proposed that triggering of these giant landslides may be related to climate change when wetter periods increase the possibility of groundwater intrusion and consequent phreatomagmatic eruptions of shallow magma chambers. Our study indicates the contemporaneity of the Alika giant submarine landslides and distal deposits from enormous turbidity currents as well as coral clasts reported to be tsunami deposits on Lanai and Molokai through direct dating and compositional analysis of the landslide deposits.
Stratigraphic constraints on the timing and emplacement of the Alika 2 giant Hawaiian submarine landslide

NASA Astrophysics Data System (ADS)

McMurtry, Gary M.; Herrero-Bervera, Emilio; Cremer, Maximilian D.; Smith, John R.; Resig, Johanna; Sherman, Clark; Torresan, Michael E.

1999-12-01

Previous work has found evidence for giant tsunami waves that impacted the coasts of Lanai, Molokai and other southern Hawaiian Islands, tentatively dated at 100+ and 200+ ka by U-series methods on uplifted coral clasts. Seafloor imaging and related work off Hawaii Island has suggested the Alika phase 2 debris avalanche as the source of the ˜100 ka "giant wave deposits", although its precise age has been elusive. More recently, a basaltic sand bed in ODP site 842 (˜300 km west of Hawaii) estimated at 100±20 ka has been suggested to correlate with this or another large Hawaiian landslide. Our approach to the timing and linkage of giant submarine landslides and paleo-tsunami deposits is a detailed stratigraphic survey of pelagic deposits proximal to the landslide feature, beginning with a suite of seven piston, gravity and box cores collected in the vicinity of the Alika 2 slide. We used U-series dating techniques, including excess 230Th and 210Pb profiling, high-resolution paleomagnetic stratigraphy, including continuous, U-channel analysis, δ 18O stratigraphy, visual and X-ray sediment lithology, and the petrology and geochemistry of the included turbidites and ash layers. Minimum ages for the Alika phase 2a slide from detailed investigation of two of the cores are 112±15 ka and 125±24 ka (2 σ) based on excess 230Th dating. A less precise age for the Alika phase 1 and/or South Kona slide is 242±80 ka (2 σ), consistent with previous geological estimates. Oxygen isotope analyses of entrained planktonic foraminifera better constrain the Alika phase 2a maximum age at 127±5 ka, which corresponds to the beginning of the stage 5e interglacial period. It is proposed that triggering of these giant landslides may be related to climate change when wetter periods increase the possibility of groundwater intrusion and consequent phreatomagmatic eruptions of shallow magma chambers. Our study indicates the contemporaneity of the Alika giant submarine landslides and distal deposits from enormous turbidity currents as well as coral clasts reported to be tsunami deposits on Lanai and Molokai through direct dating and compositional analysis of the landslide deposits.
Sea-level history and tectonic uplift during the last-interglacial period (LIG): Inferred from the Bab al-Mandab coral reef terraces, southern Red Sea

NASA Astrophysics Data System (ADS)

Al-Mikhlafi, Ahmed Saif; Edwards, Lawrence R.; Cheng, Hai

2018-02-01

Results of U-series dating of late Pleistocene raised coral reef terraces from the Bab al-Mandab area, define two distinct groups: (1) well-preserved aragonitic fossil corals recorded from the Al-Hajaja terrace (Tr3) yield ages for last-interglacial period (LIG); and (2) calcitic fossil corals recovered from Perim Island terrace (Tr1) show varying degrees of U-series open system behavior and yield coral assemblage ages of LIG and older ages. Fossil corals from Tr1 are recrystallized corals, have anomalously high initial δ234U ranged from (152 ± 2‰ to 287 ± 7‰), corresponding to ages of ∼120 ka and ∼406 ka, respectively. Applying age reliability criteria on the current data suggest majority of the ages cannot be considered reliable and all are suspected for open system behavior associated with U loss/addition that significantly affects the 230Th/U ages. The diagenesis shown by these corals occurred probably due to extensive interaction of fossil corals with freshwater during the wet periods prevailed in southern Arabia coeval with the African monsoon, which led to U loss. Post-depositional U loss suggest (230Th/238U) increase, which shift the U-Th ages to unexpectedly higher levels as it is shown here. Measured elevation at the Al-Hajaja terrace (Tr3) is ∼4 ± 2 m above present sea level (apsl) consistent with eustatic sea level changes and indicates that the Bab al-Mandab area is stable at least since the LIG period. The Perim Island terrace (Tr1) is at elevation of 7 ± 2 m apsl; its reef yields diageneticaly-altered corals of multiple ages and cannot be used for sea level reconstructions.
Urbanization impact on sulfur content of groundwater revealed by the study of urban speleothem-like deposits: Case study in Paris, France.

PubMed

Pons-Branchu, E; Roy-Barman, M; Jean-Soro, L; Guillerme, A; Branchu, P; Fernandez, M; Dumont, E; Douville, E; Michelot, J L; Phillips, A M

2017-02-01

Speleothem-like deposits that develop underground in urban areas are an archive of the environmental impact of anthropic activities that has been little studied so far. In this paper, the sulfate content in shallow groundwater from northern Paris (France) is compared with the sulfur content in two 300-year-old urban carbonate deposits that grew in a historical underground aqueduct. The present-day waters of the aqueduct have very high sulfur and calcium contents, suggesting pollution from gypsum dissolution. However, geological gypsum levels are located below the water table. Sulfur content was measured by micro-X-ray fluorescence in these very S-rich carbonate deposits (0.5 to 1% of S). A twofold S increase during the second half of the 1800s was found in both samples. These dates correspond to two major periods of urbanization above the site. We discus three possible S sources: anthropic sources (industries, fertilizers…), volcanic eruptions and input within the water through gypsum brought for urbanization above the studied site (backfill with quarry waste) since the middle of the 19th century. For the younger second half of the studied section, S input from gypsum brought during urbanization was confirmed by the study of isotopic sulfur composition (δ 34 S=+15.2‰ at the top). For the oldest part, several sulfur peaks could be related to early industrial activity in Paris, that caused high local air pollution, as reported in historical archives but also to historical gypsum extraction. This study provides information on the origin and timing of the very high SO 4 2- levels measured nowadays within the shallow groundwater, thus demonstrating the interest in using carbonate deposits in urban areas as a proxy for the history of urbanization or human activities and their impact on water bodies. Copyright © 2016 Elsevier B.V. All rights reserved.
Holocene soil pH changes and East Asian summer monsoon evolution derived from loess brGDGTs in the northeastern Tibetan Plateau

NASA Astrophysics Data System (ADS)

Duan, Y.; Sun, Q.; Zhao, H.

2017-12-01

GDGTs-based proxies have been used successfully to reconstruct paleo-temperature from loess-paleosol sequences during the past few years. However, the pH variations of loess sediments derived from GDGTs covering the geological history remain poorly constrained. Here we present two pH records spanning the last 12 ka (1ka=1000years) based on the modified cyclization ratio index (CBT') of the branched GDGTs using regional CBT'-pH empirical relationship from two well-dated loess-paleosol sections (YWY14 and SHD09) in the northeastern Tibetan Plateau. The results indicate that a slightly alkaline condition occurred during 12 8.5 ka with pH values ranging from 6.98 to 7.24, then CBT'-derived pH decreased from 8.5 to 6.5 ka with values from 7.19 to 6.49 and gradually increased thereafter. The reconstructed pH values from topmost samples can be well compared with instrumental pH values of the surrounding surface soil. The lowest intervals of CBT'-derived pH values during the mid-Holocene in our records are consistent with the results of highest tree pollen percentage from the adjacent lake sediments and regional weakest aeolian activities, which reveals that the moisture maximum during that period, but conflicted with previous results of the wettest early-Holocene inferred from speleothem or ostracod shell oxygen isotope (δ18O) values. Taking together, we conclude that Holocene humidity evolution (wettest middle Holocene) in response to the East Asian summer monsoon (EASM) changes exerts important control on pH variations of loess deposits in northeastern Tibetan Plateau. CBT'-derived pH variations can be potentially used as an indicator of EASM evolution reconstructions. In addition, we argue that speleothem or ostracod shell δ18O records are essentially a signal of the isotopic composition of precipitations rather than EASM intensity.
Early Holocene humidity patterns in the Iberian Peninsula reconstructed from lake, pollen and speleothem records

NASA Astrophysics Data System (ADS)

Morellón, Mario; Aranbarri, Josu; Moreno, Ana; González-Sampériz, Penélope; Valero-Garcés, Blas L.

2018-02-01

Comparison of selected, well-dated, lacustrine, speleothem and terrestrial pollen records spanning the Holocene onset and the Early Holocene (ca. 11.7-8 cal kyrs BP) in the Iberian Peninsula shows large hydrological fluctuations and landscape changes with a complex regional pattern in timing and intensity. Marine pollen records from Alboran, the Mediterranean and off shore Atlantic sites show a step-wise increase in moisture and forest during this transition. However, available continental records point to two main patterns of spatial and temporal hydrological variability: i) Atlantic-influenced sites located at the northwestern areas (Enol, Sanabria, Lucenza, PRD-4), characterized by a gradual increase in humidity from the end of the Younger Dryas to the Mid Holocene, similarly to most North Atlantic records; and ii) continental and Mediterranean-influenced sites (Laguna Grande, Villarquemado, Fuentillejo, Padul, Estanya, Banyoles, Salines), with prolonged arid conditions of variable temporal extension after the Younger Dryas, followed by an abrupt increase in moisture at 10-9 cal kyrs BP. Different local climate conditions influenced by topography or the variable sensitivity (gradual versus threshold values) of the proxies analyzed in each case are evaluated. Vegetation composition (conifers versus mesothermophilous taxa) and resilience would explain a subdued response of vegetation in central continental areas while in Mediterranean sites, insufficient summer moisture availability could not maintain high lake levels and promote mesophyte forest, in contrast to Atlantic-influenced areas. Comparison with available climate models, Greenland ice cores, North Atlantic marine sequences and continental records from Central and Northern Europe and the whole Mediterranean region underlines the distinctive character of the hydrological changes occurred in inner Iberia throughout the Early Holocene. The persistent arid conditions might be explained by the intensification of the summer drought due to the high seasonality contrast at these latitudes caused by the orbital-induced summer insolation maximum. New records, particularly from western and southernmost Iberia, and palaeoclimate models with higher spatial resolution would help to constrain these hypotheses.
Low-resolution Australasian palaeoclimate records of the last 2000 years

NASA Astrophysics Data System (ADS)

Dixon, Bronwyn C.; Tyler, Jonathan J.; Lorrey, Andrew M.; Goodwin, Ian D.; Gergis, Joëlle; Drysdale, Russell N.

2017-10-01

Non-annually resolved palaeoclimate records in the Australasian region were compiled to facilitate investigations of decadal to centennial climate variability over the past 2000 years. A total of 675 lake and wetland, geomorphic, marine, and speleothem records were identified. The majority of records are located near population centres in southeast Australia, in New Zealand, and across the maritime continent, and there are few records from the arid regions of central and western Australia. Each record was assessed against a set of a priori criteria based on temporal resolution, record length, dating methods, and confidence in the proxy-climate relationship over the Common Era. A subset of 22 records met the criteria and were endorsed for subsequent analyses. Chronological uncertainty was the primary reason why records did not meet the selection criteria. New chronologies based on Bayesian techniques were constructed for the high-quality subset to ensure a consistent approach to age modelling and quantification of age uncertainties. The primary reasons for differences between published and reconstructed age-depth models were the consideration of the non-singular distribution of ages in calibrated 14C dates and the use of estimated autocorrelation between sampled depths as a constraint for changes in accumulation rate. Existing proxies and reconstruction techniques that successfully capture climate variability in the region show potential to address spatial gaps and expand the range of climate variables covering the last 2000 years in the Australasian region. Future palaeoclimate research and records in Australasia could be greatly improved through three main actions: (i) greater data availability through the public archiving of published records; (ii) thorough characterisation of proxy-climate relationships through site monitoring and climate sensitivity tests; and (iii) improvement of chronologies through core-top dating, inclusion of tephra layers where possible, and increased date density during the Common Era.
On the use of δ18Oatm for ice core dating

NASA Astrophysics Data System (ADS)

Extier, Thomas; Landais, Amaelle; Bréant, Camille; Prié, Frédéric; Bazin, Lucie; Dreyfus, Gabrielle; Roche, Didier M.; Leuenberger, Markus

2018-04-01

Deep ice core chronologies have been improved over the past years through the addition of new age constraints. However, dating methods are still associated with large uncertainties for ice cores from the East Antarctic plateau where layer counting is not possible. Indeed, an uncertainty up to 6 ka is associated with AICC2012 chronology of EPICA Dome C (EDC) ice core, which mostly arises from uncertainty on the delay between changes recorded in δ18Oatm and in June 21st insolation variations at 65°N used for ice core orbital dating. Consequently, we need to enhance the knowledge of this delay to improve ice core chronologies. We present new high-resolution EDC δ18Oatm record (153-374 ka) and δO2/N2 measurements (163-332 ka) performed on well-stored ice to provide continuous records of δ18Oatm and δO2/N2 between 100 and 800 ka. The comparison of δ18Oatm with the δ18Ocalcite from East Asian speleothems shows that both signals present similar orbital and millennial variabilities, which may represent shifts in the InterTropical Convergence Zone position, themselves associated with Heinrich events. We thus propose to use the δ18Ocalcite as target for δ18Oatm orbital dating. Such a tuning method improves the ice core chronology of the last glacial inception compared to AICC2012 by reconciling NGRIP and mid-latitude climatic records. It is especially marked during Dansgaard-Oeschger 25 where the proposed chronology is 2.2 ka older than AICC2012. This δ18Oatm - δ18Ocalcite alignment method applied between 100 and 640 ka improves the EDC ice core chronology, especially over MIS 11, and leads to lower ice age uncertainties compared to AICC2012.
The Holocene Indian Summer Monsoon Variability Recorded in a Stalagmite From NE India.

NASA Astrophysics Data System (ADS)

Breitenbach, S.; Plessen, B.; Oberhänsli, H.; Marwan, N.; Lund, D.; Adkins, J.; Günther, D.; Fricker, M.; Haug, G.

2007-12-01

South Asian economies depend on the timely onset of the Indian Summer Monsoon (ISM), but understanding of the ISM variability is incomplete, due to lack of information on past ISM. Our stalagmite is the first well-dated climate record from the heart of the ISM region spanning the past 11,000 years. The speleothem was collected from Krem Umsynrang Cave, located 825 m above sea level in NE India. This region is influenced by the ISM, with more than 75% of annual rainfall falling during the monsoon season. The chronology of the stalagmite is based on 36 U/Th multi-collector ICP MS dates. Our data reveal profound changes in ISM rainfall and moisture balance. A strong increase of the ISM between 11.4 and 9.3 kyr BP is followed by a gradual decline over the course of the Holocene. This may be best explained by a strong coupling between ISM and the Intertropical Convergence Zone (ITCZ), with a stronger ISM during a more northerly position of the ITCZ. This long-term trend is punctuated by centennial to multi- to sub-decadal events of a weaker ISM. The most pronounced events occurred at 10.7, 8.5-8.1, 7.4, 4.4-4.0, 3.5, 1.4, 0.3 kyr BP. The δ13C record is interpreted to reflect centennial to decadal changes in the drip rate of the stalagmite. δ13C fractionation during periods of higher drip rates (i.e. times of longer residence time of percolating water) correspond with periods of a weaker ISM as inferred from our δ18O record. Our record shows in great detail periods of weaker ISM. They provide new insights on the sensitivity of terrestrial climate archives on the Indian subcontinent. Drought events recorded in our stalagmite correspond well with intervals of severe aridity known from other regions of the Asian monsoon. Moreover, our 11,000 year climate record shows that NE India experienced its driest conditions during the last three millennia.

Holocene ENSO-related cyclic storms recorded by magnetic minerals in speleothems of central China.

PubMed

Zhu, Zongmin; Feinberg, Joshua M; Xie, Shucheng; Bourne, Mark D; Huang, Chunju; Hu, Chaoyong; Cheng, Hai

2017-01-31

Extreme hydrologic events such as storms and floods have the potential to severely impact modern human society. However, the frequency of storms and their underlying mechanisms are limited by a paucity of suitable proxies, especially in inland areas. Here we present a record of speleothem magnetic minerals to reconstruct paleoprecipitation, including storms, in the eastern Asian monsoon area over the last 8.6 ky. The geophysical parameter IRM soft-flux represents the flux of soil-derived magnetic minerals preserved in stalagmite HS4, which we correlate with rainfall amount and intensity. IRM soft-flux exhibits relatively higher values before 6.7 ky and after 3.4 ky and lower values in the intervening period, consistent with regional hydrological changes observed in independent records. Abrupt enhancements in the flux of pedogenic magnetite in the stalagmite agree well with the timing of known regional paleofloods and with equatorial El Niño-Southern Oscillation (ENSO) patterns, documenting the occurrence of ENSO-related storms in the Holocene. Spectral power analyses reveal that the storms occur on a significant 500-y cycle, coincident with periodic solar activity and ENSO variance, showing that reinforced (subdued) storms in central China correspond to reduced (increased) solar activity and amplified (damped) ENSO. Thus, the magnetic minerals in speleothem HS4 preserve a record of the cyclic storms controlled by the coupled atmosphere-oceanic circulation driven by solar activity.
Mass balance approaches to understanding evolution of dripwater chemistry

NASA Astrophysics Data System (ADS)

Fairchild, I. J.; Baker, A.; Andersen, M. S.; Treble, P. C.

2015-12-01

Forward and inverse modelling of dripwater chemistry is a fast-developing area in speleothem science. Such approaches can incorporate theoretical, parameterized or observed relationships between forcing factors and water composition, but at the heart is mass balance: a fundamental principle that provides important constraints. Mass balance has been used in speleothem studies to trace the evolution of dissolved inorganic carbon and carbon isotopes from soil to cave, and to characterize the existence and quantification of prior calcite precipitation (PCP) based on ratios of Mg and Sr to Ca. PCP effects can dominate slow drips, whereas fast drips are more likely to show a residual variability linked to soil-biomass processes. A possible configuration of a more complete mass balance model is illustrated in the figure. Even in humid temperate climates, evapotranspiration can be 50% of total atmospheric precipitation leading to substantially raised salt contents and there can be significant exchange with biomass. In more arid settings, at least seasonal soil storage of salts is likely. Golgotha Cave in SW Australia is in a Mediterranean climate with a strong summer soil moisture deficit. The land surface is forested leading to large ion fluxes related to vegetation. There are also periodic disturbances related to fire. Mass balance approaches have been applied to an 8-year monitoring record. Inter-annual trends of elements coprecipitated in speleothems from fast drips are predicted to be dominated by biomass effects.
Climate variations of Central Asia on orbital to millennial timescales.

PubMed

Cheng, Hai; Spötl, Christoph; Breitenbach, Sebastian F M; Sinha, Ashish; Wassenburg, Jasper A; Jochum, Klaus Peter; Scholz, Denis; Li, Xianglei; Yi, Liang; Peng, Youbing; Lv, Yanbin; Zhang, Pingzhong; Votintseva, Antonina; Loginov, Vadim; Ning, Youfeng; Kathayat, Gayatri; Edwards, R Lawrence

2016-11-11

The extent to which climate variability in Central Asia is causally linked to large-scale changes in the Asian monsoon on varying timescales remains a longstanding question. Here we present precisely dated high-resolution speleothem oxygen-carbon isotope and trace element records of Central Asia's hydroclimate variability from Tonnel'naya cave, Uzbekistan, and Kesang cave, western China. On orbital timescales, the supra-regional climate variance, inferred from our oxygen isotope records, exhibits a precessional rhythm, punctuated by millennial-scale abrupt climate events, suggesting a close coupling with the Asian monsoon. However, the local hydroclimatic variability at both cave sites, inferred from carbon isotope and trace element records, shows climate variations that are distinctly different from their supra-regional modes. Particularly, hydroclimatic changes in both Tonnel'naya and Kesang areas during the Holocene lag behind the supra-regional climate variability by several thousand years. These observations may reconcile the apparent out-of-phase hydroclimatic variability, inferred from the Holocene lake proxy records, between Westerly Central Asia and Monsoon Asia.
Climate variations of Central Asia on orbital to millennial timescales

PubMed Central

Cheng, Hai; Spötl, Christoph; Breitenbach, Sebastian F. M.; Sinha, Ashish; Wassenburg, Jasper A.; Jochum, Klaus Peter; Scholz, Denis; Li, Xianglei; Yi, Liang; Peng, Youbing; Lv, Yanbin; Zhang, Pingzhong; Votintseva, Antonina; Loginov, Vadim; Ning, Youfeng; Kathayat, Gayatri; Edwards, R. Lawrence

2016-01-01

The extent to which climate variability in Central Asia is causally linked to large-scale changes in the Asian monsoon on varying timescales remains a longstanding question. Here we present precisely dated high-resolution speleothem oxygen-carbon isotope and trace element records of Central Asia’s hydroclimate variability from Tonnel’naya cave, Uzbekistan, and Kesang cave, western China. On orbital timescales, the supra-regional climate variance, inferred from our oxygen isotope records, exhibits a precessional rhythm, punctuated by millennial-scale abrupt climate events, suggesting a close coupling with the Asian monsoon. However, the local hydroclimatic variability at both cave sites, inferred from carbon isotope and trace element records, shows climate variations that are distinctly different from their supra-regional modes. Particularly, hydroclimatic changes in both Tonnel’naya and Kesang areas during the Holocene lag behind the supra-regional climate variability by several thousand years. These observations may reconcile the apparent out-of-phase hydroclimatic variability, inferred from the Holocene lake proxy records, between Westerly Central Asia and Monsoon Asia. PMID:27833133
Using zircon (U-Th)/He damage-diffusivity patterns to quantify detachment-related basement exhumation in the Mecca Hills, CA

NASA Astrophysics Data System (ADS)

Moser, A. C.; Ault, A. K.; Evans, J. P.; Reiners, P. W.; Stearns, M.; Guenthner, W.

2017-12-01

Exposures of gneiss and Orocopia Schist (OS) in the Mecca Hills, California, adjacent to the southernmost San Andreas Fault system, preserve the exhumation history of Oligocene detachment faulting. We investigate the duration, magnitude, and mechanisms of exhumation of these units at regional and local scales using in situ U-Pb zircon dating (n = 248), (U-Th)/He (He) thermochronometry (n = 39), and He date-effective U (eU) patterns. Zircons with variable preserved visual metamictization were targeted for He analyses to purposefully build a dataset with a range in eU concentration and zircon He closure temperatures, as well as induce a He date-eU correlation. Analyzed zircon crystals range from clear and transparent to purple-brown and translucent in each sample. Zircon cathodoluminescence images reveal oscillatory and sector chemical zoning. Each sample contains a population of largely Proterozoic U-Pb dates implying some grains accumulated radiation damage since 1.9-1.1 Ga. Zircon (U-Th)/He dates from seven samples of OS and gneiss yield a mean date of 24 ± 3.5 Ma (n = 32) and uniform dates over an 90-2950 ppm eU range. One gneiss sample yields a mean date of 65 ± 5.6 Ma (n = 7) over a limited eU spread ( 500-950 ppm). Mean zircon He dates from these two units overlap, but dates are broadly younger in northeastern exposures dominated by OS. Preliminary thermal history simulations integrating zircon U-Pb data, He date-eU patterns, and independent geologic constraints require at least 200 °C of cooling through the zircon He partial retention zone 30-21 Ma and show that the pre-70 Ma thermal history does not affect the predicted date-eU correlation. This shared rapid cooling history documented in the OS and gneiss imply these units were juxtaposed prior to 30 Ma and exhumed as a coherent structural block within the footwall of the Orocopia Mountains Detachment Fault in the Mecca Hills. Spatio-temporal variation in mean zircon He dates may delineate time-transgressive cooling of these units as they exhumed. Zircon textures and overall invariant He dates regardless of eU imply that visual metamictization persists in zircons at temperatures >200 °C and indicates these grains experienced a thermal history characterized by temperatures that preserved visual damage but fully induced He loss in the crystals prior to exhumation.
Environmental flow allocation and statistics calculator

USGS Publications Warehouse

Konrad, Christopher P.

2011-01-01

The Environmental Flow Allocation and Statistics Calculator (EFASC) is a computer program that calculates hydrologic statistics based on a time series of daily streamflow values. EFASC will calculate statistics for daily streamflow in an input file or will generate synthetic daily flow series from an input file based on rules for allocating and protecting streamflow and then calculate statistics for the synthetic time series. The program reads dates and daily streamflow values from input files. The program writes statistics out to a series of worksheets and text files. Multiple sites can be processed in series as one run. EFASC is written in MicrosoftRegistered Visual BasicCopyright for Applications and implemented as a macro in MicrosoftOffice Excel 2007Registered. EFASC is intended as a research tool for users familiar with computer programming. The code for EFASC is provided so that it can be modified for specific applications. All users should review how output statistics are calculated and recognize that the algorithms may not comply with conventions used to calculate streamflow statistics published by the U.S. Geological Survey.
Crustal subsidence rate off Hawaii determined from sup 234 U/ sup 238 U ages of drowned coral reefs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ludwig, K.R.; Szabo, B.J.; Simmons, K.R.

1991-02-01

A series of submerged coral reefs off northwestern Hawaii was formed during (largely glacial) intervals when the rate of local sea-level rise was less than the maximum upward growth rate of the reefs. Mass-spectrometric {sup 234}U/{sup 238}U ages for samples from six such reefs range from 17 to 475 ka and indicate that this part of the Hawaiian Ridge has been subsiding at a roughly uniform rate of 2.6 mm/yr for the past 475 ka. The {sup 234}U/{sup 238}U ages are in general agreement with model ages of reef drowning (based on estimates of paleo-sea-level stands derived from oxygen-isotope ratiosmore » of deep-sea sediments), but there are disagreements in detail. The high attainable precision ({plus minus}10 ka or better on samples younger than {approximately}800 ka), large applicable age range, relative robustness against open-system behavior, and ease of analysis for this technique hold great promise for future applications of dating of 50-1,000 ka coral.« less
Carbon dioxide concentration in caves and soils in an alpine setting: implications for speleothem fabrics and their palaeoclimate significance

NASA Astrophysics Data System (ADS)

Borsato, Andrea; Frisia, Silvia; Miorandi, Renza

2015-04-01

Carbon dioxide concentration in soils controls carbonate dissolution, soil CO2 efflux to the atmosphere, and CO2 transfer to the subsurface that lead, ultimately, to speleothem precipitation. Systematic studies on CO2 concentration variability in soil and caves at regional scale are, however, few. Here, the systematic investigation of CO2 concentration in caves and soils in a temperate, Alpine region along a 2,100 m altitudinal range transect, which corresponds to a mean annual temperature (MAT) range of 12°C is presented. Soil pCO2 is controlled by the elevation and MAT and exhibits strong seasonality, which follows surface air temperature with a delay of about a month. The aquifer pCO2, by contrast, is fairly constant throughout the year, and it is primarily influenced by summer soil pCO2. Cave CO2 concentration is a balance between the CO2 influx and CO2 efflux, where the efflux is controlled by the cave ventilation, which is responsible for low pCO2 values recorded in most of the caves with respect to soil levels. Carbon dioxide in the innermost part of the studied caves exhibits a clear seasonal pattern. Thermal convection is the most common mechanism causing higher ventilation and low cave air pCO2 levels during the winter season: this promotes CO2 degassing and higher supersaturation in the drip water and, eventually, higher speleothem growth rates during winter. The combined influence of three parameters - dripwater pCO2, dripwater Ca content, and cave air pCO2 - all related to the infiltration elevation and MAT directly controls calcite supersaturation in dripwater. Four different altitudinal belts are then defined, which reflect temperature-dependent saturation state of dripwaters. These belts broadly correspond to vegetation zones: the lower montane (100 to 800 m asl), the upper montane (800 to 1600 m asl), the subalpine (1600 to 2200 m asl) and the Alpine (above 2200 m asl). Each altitudinal belt is characterised by different calcite fabrics, which can shift upward/downward in elevation as a response to temperature increase/decrease through time. In the lower and upper montane zones the columnar types (compact, open, fascicular optic) are the most common fabrics, with the microcrystalline type most typical of the upper montane zone. The dendritic fabric becomes predominant in the higher upper montane and lower subalpine zones. The higher subalpine to lower alpine zones the only speleothem actually forming is moonmilk. Eventually, the occurrence of "altitudinal" fabrics within the vertical growth axis of a stalagmite is indicative of changes in the MAT through time Therefore, fabric changes in fossil speleothems in temperate climate settings can be potentially used to reconstruct regional MAT changes in the past.
77 FR 46024 - Purified Carboxymethylcellulose From the Netherlands: Preliminary Results of Antidumping Duty...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-02

... the invoice date as the date of sale for the home market and one of the U.S. market channels of distribution (i.e., U.S. market Channel 2) because the date of invoice reflects the date on which the material terms of sale were finalized. For Akzo Nobel's other U.S. market channel of distribution (i.e., U.S...
36Chlorine exposure dating of a terminal moraine in the Galicica Mountains, Macedonia

NASA Astrophysics Data System (ADS)

Gromig, R.; Mechernich, S.; Ribolini, A.; Dunai, T. J.; Wagner, B.

2015-12-01

The glaciation history of the Balkan Peninsula is subject of research since the late 19th century. To date, only a few moraines on the Balkan Peninsula are dated, mainly using 10Be exposure dating applied on quartz bearing rocks. Since large parts of the Balkan Peninsula mountains are composed of carbonatic rocks, absolute age dating is restricted to 36Cl exposure dating, which, to date, was not conducted in this region yet. So far, an absolute chronological control in limestone-dominated areas is limited to U-series minimum ages of calcitic cements. In order to obtain more information about the timing of the glaciation history on the Balkan Peninsula, we investigated a terminal moraine in a NNE-facing cirque in the Galicica Mountains (40°56´N, 20°49´E) in the Former Yugoslav Republic of Macedonia. The cirque comprises a series of nested moraine ridges at the base of the cirque wall, with the largest one being sampled. Samples from five limestone boulders in crest position (≈ 2050 m a.s.l.) were taken and pre-treated for AMS measurement at the University of Cologne. Three preliminary ages point to a moraine formation in the course of a late Pleistocene glaciation, either Last Glacial Maximum or Younger Dryas. The data were discussed concerning corrections for topographic shielding, snow cover, inheritance, and erosion. However, five AMS re-measurements are currently in progress in order to refine the correlation of the moraine formation to a specific glacial period. The resulting ages will be compared to sediments of the adjacent Lakes Ohrid and Prespa, which represent valuable climatic and environmental archives. Several studies on these sediments were carried out in order to reconstruct relative changes in temperature and moisture availability. Moreover, the inferred moraine formation ages will be compared to glaciation reconstructions of other mountainous regions on the Balkan Peninsula to improve the knowledge on past climatic conditions.
Sources and transport of microbial tetraether membrane lipids in Karst Systems

NASA Astrophysics Data System (ADS)

Jex, C.; Blyth, A. J.; McDonald, J.; Woltering, M.; Khan, S.; Baker, A.

2014-12-01

Speleothems preserve organic biomarkers, proxies for surface climate. Microbial-derived lipids, specifically glycerol dialkyl glycerol tetraetheral (GDGT) lipids have been identified in cave deposits and shown to correlate well with surface air temperature using the archaea-derived isoprenoid '(i)GDGT' index of TEX86 and the bacteria derived branched '(b)GDGT' index of MBT/CBT of modern speleothems [1]. Two competing sources for GDGTs in karst systems have been suggested: 1) A soil derived microbial signal dominated by bGDGTs; and 2) An in situ signal dominated by iGDGTs, representative of archaea existing within the cave or overlying bedrock [2]. These findings are yet to be thoroughly tested by characterising the seasonal nature of GDGTs in caves to establish the source and transport pathways within these complex fractured rock systems. Here, we address this and present the results of a yearlong monitoring campaign of GDGTs within two contrasting cave sites from the Yarrangobilly Caves in Kosciuszko national park, SE Australia. The caves are located at a high altitude, semi-arid site. Harriewood cave is dominated by discrete infiltration events throughout the year. Above the cave there are thin soils consisting of loose shallow scree, steep slopes and sparse shrub vegetation. The surface above Jillabenan is characterised by thick red clays of moderate to no slope and Eucalypt dominated forest. As such, these caves provide ideal test sites to characterise the variability in GDGT signals that may be a result of non-temperature related factors, including varying inputs (groundwater vs. in situ growth) or site-specific hydrological conditions. We present data obtained from within the cave: drip waters and in situ collection of GDGTs formed on filter papers left inside the cave throughout the year, and externally sourced signals from soils and their leachates. We also identify key differences in soil pH and cave air temperatures that are best predicted by using cave specific GDGT calibrations of [1]. [1] Blyth et al. 2013. Calibrating the glycerol dialkyl glycerol tetraether temperature signal in speleothems. Geochim Cosmochim Ac. 109, 312-328. [2] Blyth et al. 2014. Contrasting distributions of glycerol dialkyl glycerol tetraethers (GDGTs) in speleothems and associated soils, Org Geochem, 69, 1-10.
Magnesium-isotope fractionation during low-Mg calcite precipitation in a limestone cave - Field study and experiments

NASA Astrophysics Data System (ADS)

Immenhauser, A.; Buhl, D.; Richter, D.; Niedermayr, A.; Riechelmann, D.; Dietzel, M.; Schulte, U.

2010-08-01

The chemical and isotopic composition of speleothem calcite and particularly that of stalagmites and flowstones is increasingly exploited as an archive of past environmental change in continental settings. Despite intensive research, including modelling and novel approaches, speleothem data remain difficult to interpret. A possible way foreword is to apply a multi-proxy approach including non-conventional isotope systems. For the first time, we here present a complete analytical dataset of magnesium isotopes (δ 26Mg) from a monitored cave in NW Germany (Bunker Cave). The data set includes δ 26Mg values of loess-derived soil above the cave (-1.0 ± 0.5‰), soil water (-1.2 ± 0.5‰), the carbonate hostrock (-3.8 ± 0.5‰), dripwater in the cave (-1.8 ± 0.2‰), speleothem low-Mg calcite (stalactites, stalagmites; -4.3 ± 0.6‰), cave loam (-0.6 ± 0.1‰) and runoff water (-1.8 ± 0.1‰) in the cave, respectively. Magnesium-isotope fractionation processes during weathering and interaction between soil cover, hostrock and solute-bearing soil water are non-trivial and depend on a number of variables including solution residence times, dissolution rates, adsorption effects and potential neo-formation of solids in the regolith and the carbonate aquifer. Apparent Mg-isotope fractionation between dripwater and speleothem low-Mg calcite is about 1000ln αMg-cc-Mg(aq) = -2.4‰. A similar Mg-isotope fractionation (1000ln αMg-cc-Mg(aq) ≈ -2.1‰) is obtained by abiogenic precipitation experiments carried out at aqueous Mg/Ca ratios and temperatures close to cave conditions. Accordingly, 26Mg discrimination during low-Mg calcite formation in caves is highly related to inorganic fractionation effects, which may comprise dehydration of Mg 2+ prior to incorporation into calcite, surface entrapment of light isotopes and reaction kinetics. Relevance of kinetics is supported by a significant negative correlation of Mg-isotope fractionation with the precipitation rate for inorganic precipitation experiments.
A 250,000-year climatic record from great basin vein calcite: Implications for Milankovitch theory

USGS Publications Warehouse

Winograd, I.J.; Szabo, B. J.; Coplen, T.B.; Riggs, A.C.

1988-01-01

A continuous record of oxygen-18 (??18O) variations in the continental hydrosphere during the middle-to-late Pleistocene has been obtained from a uranium-series dated calcitic vein in the southern Great Basin. The vein was deposited from ground water that moved through Devils Hole - an open fault zone at Ash Meadows, Nevada - between 50 and 310 ka (thousand years ago). The configuration of the ??18O versus time curve closely resembles the marine and Antarctic ice core (Vostok) ??18O curves; however, the U-Th dates indicate that the last interglacial stage (marine oxygen isotope stage 5) began before 147 ?? 3 ka, at least 17,000 years earlier than indicated by the marine ??18O record and 7,000 years earlier than indicated by the less well dated Antarctic ??18O record. This discrepancy and other differences in the timing of key climatic events suggest that the indirectly dated marine ??18O chronology may need revision and that orbital forcing may not be the principal cause of the Pleistocene ice ages.
Improved spatial resolution for U-series dating of opal at Yucca Mountain, Nevada, USA, using ion-microprobe and microdigestion methods

USGS Publications Warehouse

Paces, J.B.; Neymark, L.A.; Wooden, J.L.; Persing, H.M.

2004-01-01

Two novel methods of in situ isotope analysis, ion microprobe and microdigestion, were used for 230Th/U and 234U/238U dating of finely laminated opal hemispheres formed in unsaturated felsic tuff at Yucca Mountain, Nevada, proposed site for a high-level radioactive waste repository. Both methods allow analysis of layers as many as several orders of magnitude thinner than standard methods using total hemisphere digestion that were reported previously. Average growth rates calculated from data at this improved spatial resolution verified that opal grew at extremely slow rates over the last million years. Growth rates of 0.58 and 0.69 mm/m.y. were obtained for the outer 305 and 740 ??m of two opal hemispheres analyzed by ion microprobe, and 0.68 mm/m.y. for the outer 22 ??m of one of these same hemispheres analyzed by sequential microdigestion. These Pleistocene growth rates are 2 to 10 times slower than those calculated for older secondary calcite and silica mineral coatings deposited over the last 5 to 10 m.y. dated by the U-Pb method and may reflect differences between Miocene and Pleistocene seepage flux. The microdigestion data also imply that opal growth rates may have varied over the last 40 k.y. These data are the first indication that growth rates and associated seepage in the proposed repository horizon may correlate with changes in late Pleistocene climate, involving faster growth during wetter, cooler climates (glacial maximum), slower growth during transition climates, and no growth during the most arid climate (modern). Data collected at this refined spatial scale may lead to a better understanding of the hydrologic variability expected within the thick unsaturated zone at Yucca Mountain over the time scale of interest for radioactive waste isolation. ?? 2004 Elsevier Ltd.
Integrated multi-site U-Th chronology of the last glacial Lake Lisan

NASA Astrophysics Data System (ADS)

Torfstein, Adi; Goldstein, Steven L.; Kagan, Elisa J.; Stein, Mordechai

2013-03-01

We present a new integrated multi-site chronology for Lake Lisan, which occupied the Dead Sea basin and Jordan Valley during the last glacial period (70-14 kka, Marine Isotope Stages 4, 3, 2). The Dead Sea basin lacustrine deposits are unique among closed basin sediments in that they formed in a deep, hypersaline water body that precipitated primary aragonite which is amenable to radiometric dating by U-series, providing a solid basis for studies of the relationship of Middle East climate to other changes in the high latitudes or the tropics. The application of U-Th dating for lacustrine carbonates requires corrections for detrital U and Th and hydrogenous ("initial") 230Th. Here we followed an iterative approach, in which we evaluate the composition of the detrital contamination independently for every set of coeval samples to determine the corrected ages. These were further filtered and combined with lithological-limnological considerations, which were used to construct age-height models for all studied stratigraphic sections. Finally, the ages of stratigraphic tie-points were used to integrate the individual age-height models into a unified chronology. The resulting chronological framework indicates that the ages of several primary gypsum units associated with catastrophic lake level drops correspond with the timing of Heinrich events in the North Atlantic. Thus, a final iterative step involves refining the ages of "Lisan-gypsum events" based on the ages of Heinrich events 6, 5, 5a, 4, and 1. This approach yields an unprecedented basin-wide, unified, event-anchored chronology for the Lisan Formation, with typical age uncertainties ca. 1000-2000 years (95% confidence limit) across the entire last glacial, well below those typically related to individual U-Th and radiocarbon dating of "dirty" carbonates from similar time intervals. The results can be further extrapolated to new sites and serve as a geochronometric reference for the reconstruction of the limnological history of Lake Lisan.
230Th/U ages Supporting Hanford Site-Wide Probabilistic Seismic Hazard Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paces, James B.

This product represents a USGS Administrative Report that discusses samples and methods used to conduct uranium-series isotope analyses and resulting ages and initial 234U/238U activity ratios of pedogenic cements developed in several different surfaces in the Hanford area middle to late Pleistocene. Samples were collected and dated to provide calibration of soil development in surface deposits that are being used in the Hanford Site-Wide probabilistic seismic hazard analysis conducted by AMEC. The report includes description of sample locations and physical characteristics, sample preparation, chemical processing and mass spectrometry, analytical results, and calculated ages for individual sites. Ages of innermost rindsmore » on a number of samples from five sites in eastern Washington are consistent with a range of minimum depositional ages from 17 ka for cataclysmic flood deposits to greater than 500 ka for alluvium at several sites.« less
230Th/U ages Supporting Hanford Site‐Wide Probabilistic Seismic Hazard Analysis

USGS Publications Warehouse

Paces, James B.

2014-01-01

This product represents a USGS Administrative Report that discusses samples and methods used to conduct uranium-series isotope analyses and resulting ages and initial 234U/238U activity ratios of pedogenic cements developed in several different surfaces in the Hanford area middle to late Pleistocene. Samples were collected and dated to provide calibration of soil development in surface deposits that are being used in the Hanford Site-Wide probabilistic seismic hazard analysis conducted by AMEC. The report includes description of sample locations and physical characteristics, sample preparation, chemical processing and mass spectrometry, analytical results, and calculated ages for individual sites. Ages of innermost rinds on a number of samples from five sites in eastern Washington are consistent with a range of minimum depositional ages from 17 ka for cataclysmic flood deposits to greater than 500 ka for alluvium at several sites.
76 FR 59455 - Curian Series Trust and Curian Capital, LLC; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-26

...] Curian Series Trust and Curian Capital, LLC; Notice of Application AGENCY: Securities and Exchange... Series Trust (``Trust'') and Curian Capital, LLC (the ``Adviser''). DATES: Filing Dates: The application.... Applicants, Curian Series Trust, 7601 Technology Way, Denver, CO 80237. FOR FURTHER INFORMATION CONTACT: Jaea...
Compilation of seismic-refraction crustal data in the Soviet Union

USGS Publications Warehouse

Rodriguez, Robert; Durbin, William P.; Healy, J.H.; Warren, David H.

1964-01-01

The U.S. Geological Survey is preparing a series of terrain atlases of the Sino-Soviet bloc of nations for use in a possible nuclear-test detection program. Part of this project is concerned with the compilation and evaluation of crustal-structure data. To date, a compilation has been made of data from Russian publications that discuss seismic refraction and gravity studies of crustal structure. Although this compilation deals mainly with explosion seismic-refraction measurements, some results from earthquake studies are also included. None of the data have been evaluated.
Plutonium age dating reloaded

NASA Astrophysics Data System (ADS)

Sturm, Monika; Richter, Stephan; Aregbe, Yetunde; Wellum, Roger; Mayer, Klaus; Prohaska, Thomas

2014-05-01

Although the age determination of plutonium is and has been a pillar of nuclear forensic investigations for many years, additional research in the field of plutonium age dating is still needed and leads to new insights as the present work shows: Plutonium is commonly dated with the help of the 241Pu/241Am chronometer using gamma spectrometry; in fewer cases the 240Pu/236U chronometer has been used. The age dating results of the 239Pu/235U chronometer and the 238Pu/234U chronometer are scarcely applied in addition to the 240Pu/236U chronometer, although their results can be obtained simultaneously from the same mass spectrometric experiments as the age dating result of latter. The reliability of the result can be tested when the results of different chronometers are compared. The 242Pu/238U chronometer is normally not evaluated at all due to its sensitivity to contamination with natural uranium. This apparent 'weakness' that renders the age dating results of the 242Pu/238U chronometer almost useless for nuclear forensic investigations, however turns out to be an advantage looked at from another perspective: the 242Pu/238U chronometer can be utilized as an indicator for uranium contamination of plutonium samples and even help to identify the nature of this contamination. To illustrate this the age dating results of all four Pu/U clocks mentioned above are discussed for one plutonium sample (NBS 946) that shows no signs of uranium contamination and for three additional plutonium samples. In case the 242Pu/238U chronometer results in an older 'age' than the other Pu/U chronometers, contamination with either a small amount of enriched or with natural or depleted uranium is for example possible. If the age dating result of the 239Pu/235U chronometer is also influenced the nature of the contamination can be identified; enriched uranium is in this latter case a likely cause for the missmatch of the age dating results of the Pu/U chronometers.

Ancient and modern sites of natural CO2 leakage: Geochemistry and geochronology of Quaternary and modern travertine deposits on the Colorado Plateau, USA, and implications for CO2 sequestration

NASA Astrophysics Data System (ADS)

Priewisch, A.; Crossey, L. J.; Karlstrom, K. E.; McPherson, B. J.; Mozley, P.

2013-12-01

Travertine-precipitating springs and travertine deposits of the Colorado Plateau serve as natural analogues for evaluating potential leakage associated with geologic sequestration of carbon dioxide (CO2). Extensive Quaternary and modern travertine deposits occur along the Jemez lineament and Rio Grande rift in New Mexico and Arizona, and in the Paradox Basin in Utah, along the Little Grand Wash Fault and the Salt Wash Graben. These groundwater discharge deposits are interpreted to be sites of persistent and significant CO2 degassing along faults and above magmatic systems. Analysis of the geochemical and isotopic composition of U-series dated travertine deposits and modern travertine-precipitating waters allows evaluation of the flow paths of CO2-charged waters. Initial results from New Mexico and Arizona travertine deposits show characteristic rare earth element (REE) signatures for individual travertine deposits and yet generally overlap in concentrations of other trace elements such as Al, As, B, Ba, K, and Si. We report stable oxygen and carbon isotopes of the travertines in New Mexico, Arizona, and Utah. Different travertine deposits have different carbon-oxygen isotope variation patterns suggesting that these stable isotopes are tracers that have the ability to identify distinctive groundwater sources within and between spring groups based on the travertine record. Stable isotope analyses of travertine deposits in New Mexico and Arizona overlap substantially between deposits and cluster around -10‰ to -6‰ for δ18O and around 3.5‰ to 6.5‰ for δ13C. Travertine deposits in Utah show a distinctly different range of stable isotope values: δ18O values cluster around -14‰ to -10.5‰ and δ13C around 4.5‰ to 6.5‰. U-series dating of travertine deposits shows episodic travertine formation in New Mexico and Arizona over the last 700,000 years, and travertine accumulation over the last 400,000 years in Utah. We use U-series dating and volumetric analysis of the travertine deposits to estimate the minimum CO2 flux that was necessary to form the deposits and compare it to modern flux measurements in order to assess the extent of former and modern CO2 leakage. In addition, the thickness of dated travertine sections provides information about the longevity of travertine mound or spring systems that may be controlled by, e. g., sealing of faults, alternating wet/ dry paleohydrologic conditions, and/or rates of magmatic CO2 supply to springs. Understanding travertine deposition is important for the assessment of the long-term performance of a potential CO2 sequestration site because travertine deposits give insight into the complexities of CO2 pathways and leakage rates over timescales necessary for CO2 sequestration.
DEMONSTRATING SLOW GROWTH RATES IN OPAL FROM Y.M.,NV, USING MICRODIGESTION AND ION-PROBE URANIUM-SERIES DATING

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. PACES; L. NEYMARK; H. PERSING

Thinly laminated (<0.01 mm) opal sheets and globules associated with calcite in fractures and cavities in the unsaturated zone at Yucca Mountain, Nevada, have U concentrations of 50 to 300 ppm. Previous uranium-series thermal ionization mass spectrometry (TIMS) analyses of 0.2- to 1-mm-thick subsamples resulted in a model of slow mineral growth at rates of 0.5 to 5 mm/m.y. To test this growth model using finer sampling resolution, in situ microdigestions were performed by applying a drop of hydrofluoric acid directly to opal surfaces within a small area encircled by jeweler's wax. After several minutes, the liquid was removed, spikedmore » with a tracer solution, and analyzed by TIMS for both U and Th using a single rhenium filament with colloidal graphite. Solutions contained about 0.5 nanograms of U, equivalent to opal weights of 1 to 10 micrograms and dissolved-layer thicknesses less than 0.003 mm. Microdigested opal surfaces have Th-230/U ages of 5 to 10 thousand years (ka) in contrast to much older ages of 150 to 250 ka obtained previously from whole-globule digestions. Additional tests of the growth model were made on cross sections of identical opal globules using the sensitive high-resolution ion microprobe (SHRIMP) with a 0.04-mm-diameter O-minus primary beam. Counting rates for Tho-246 and U-234 varied between 5 and 70 counts per second with Th-230/Th-232 activity ratios typically much greater than a million. The Th-230/U ages in the outer 0.3 mm of the globules ranged from about 30 ka at the outer edge to 400 ka at depth. Ages correlate with microstratigraphic depths and indicate average growth rates between 0.5 and 0.7 mm/m.y. Current U-series data do not resolve differential growth rates related to climate changes during this time period. However, both microdigestion and SHRIMP results confirm the previous TIMS-based model of slow, uniform rates of mineral growth in a hydrologically stable environment.« less
31 CFR 351.35 - What do I need to know about interest rates, penalties, and redemption values for Series EE bonds...

Code of Federal Regulations, 2011 CFR

2011-07-01

... rates, penalties, and redemption values for Series EE bonds with issue dates of May 1, 2005, or... SAVINGS BONDS, SERIES EE Maturities, Redemption Values, and Investment Yields of Series EE Savings Bonds Series Ee Savings Bonds with Issue Dates of May 1, 2005, Or Thereafter § 351.35 What do I need to know...
31 CFR 351.35 - What do I need to know about interest rates, penalties, and redemption values for Series EE bonds...

Code of Federal Regulations, 2012 CFR

2012-07-01

... rates, penalties, and redemption values for Series EE bonds with issue dates of May 1, 2005, or... SAVINGS BONDS, SERIES EE Maturities, Redemption Values, and Investment Yields of Series EE Savings Bonds Series Ee Savings Bonds with Issue Dates of May 1, 2005, Or Thereafter § 351.35 What do I need to know...
31 CFR 351.35 - What do I need to know about interest rates, penalties, and redemption values for Series EE bonds...

Code of Federal Regulations, 2010 CFR

2010-07-01

... rates, penalties, and redemption values for Series EE bonds with issue dates of May 1, 2005, or... SAVINGS BONDS, SERIES EE Maturities, Redemption Values, and Investment Yields of Series EE Savings Bonds Series Ee Savings Bonds with Issue Dates of May 1, 2005, Or Thereafter § 351.35 What do I need to know...
31 CFR 351.35 - What do I need to know about interest rates, penalties, and redemption values for Series EE bonds...

Code of Federal Regulations, 2014 CFR

2014-07-01

... rates, penalties, and redemption values for Series EE bonds with issue dates of May 1, 2005, or... SAVINGS BONDS, SERIES EE Maturities, Redemption Values, and Investment Yields of Series EE Savings Bonds Series Ee Savings Bonds with Issue Dates of May 1, 2005, Or Thereafter § 351.35 What do I need to know...
31 CFR 351.35 - What do I need to know about interest rates, penalties, and redemption values for Series EE bonds...

Code of Federal Regulations, 2013 CFR

2013-07-01

... rates, penalties, and redemption values for Series EE bonds with issue dates of May 1, 2005, or... SAVINGS BONDS, SERIES EE Maturities, Redemption Values, and Investment Yields of Series EE Savings Bonds Series Ee Savings Bonds with Issue Dates of May 1, 2005, Or Thereafter § 351.35 What do I need to know...
U-series ages of solitary corals from the California coast by mass spectrometry

USGS Publications Warehouse

Stein, Martin; Wasserburg, G.J.; Lajoie, K.R.; Chen, J.-H.

1991-01-01

The purpose of this study is to evaluate the feasibility of dating fossil solitary corals from Pleistocene marine strandlines outside tropical latitudes using the recently developed high sensitivity, high-precision U-series technique based on thermal-ionization mass-spectrometry (TIMS). The TIMS technique is much more efficient than conventional a spectrometry and, as a result, multiple samples of an individual coral skeleton, or different specimens from the same bed can be analyzed. Detached and well-rounded fossil specimens of the solitary coral Balanophyllia elegans were collected from relict littoral deposits on emergent marine terraces along the California coast at Cayucos terrace (elevation 8 m, previously dated at 124 and 117 Ky by ?? counting), Shell Beach terrace (elevation about 25 m, previously undated), Nestor terrace, San Diego (elevation 23 m, previously dated at 131 to 109 Ky ), Bird Rock terrace, San Diego ( elevation 8 m, previously dated at 81 Ky ). Attached living specimens were collected from the intertidal zone on the modern terrace at Moss Beach. Concentrations of 232Th in both living and fossil specimens are much higher than in reef-building corals (12 to 624 pmol/g vs. 0.1 to 1.6 pmol/g, respectively). However, because 230Th/232Th in Balanophyllia elegans are very low (2.22 ?? 10-3 to 4.33 ?? 10-4), the high 232Th concentrations have negligible effect on the 230Th-234U dates. The high 232Th concentration in the living specimen (33.1 pmol/g) indicates that a significant amount of 232Th is incorporated in the aragonitic skeleton during growth, or attached to clay-sized silicates trapped in the skeletal material. The calculated initial 234U activities in the fossil specimens of Balanophyllia elegans are higher than the 234U activity in modern seawater or in the modern specimen. The higher initial activities could possibly reflect the influx of 234U-enriched continental water into Pleistocene coastal waters, or it could reflect minor diagenetic alteration, a persistent and fundamental problem in dating all corals. Samples from a compound specimen from the Cayucos terrace were subjected to different preparation procedures. Samples prepared by a standard acid washing procedure yielded 230Th-234U ages of 125, 123, and 122 Ky, whereas samples prepared by an abbreviated procedure without acid washing yield significantly lower ages of 113 and 112 Ky. Two other specimens from the same bed yielded 230Th-234U ages of 118 and 115 Ky. Also, two specimens from a stratigraphically higher bed yielded ages of 120 and 117 Ky, and three specimens from a lower bed yield ages of 115, 113, and 101 Ky. Nine of the twelve ages of the treated samples from the Cayucos terrace range from 125 to 113 Ky. However, the ages do not follow the stratigraphie order. Two possible interpretations are ( 1 ) the age of the terrace deposit is 125 Ky and all younger ages reflect variable diagenetic alteration or (2) the age of the terrace is 125 to 113 Ky and the ages reflect sediment reworking over a period of 12 Ky. Three specimens from a single bed on the Shell Beach terrace yield ages of 126, 122, and 121 Ky, similar to the older ages from Cayucos. The ages of solitary corals from the Cayucos and Shell Beach terraces are similar to ages of reef-building corals from terraces at numerous tropical localities. These are correlated with the last interglacial sea-level highstand, which probably stood 2 to 10 m above present sea level. The youngest ages and present elevations of the Cayucos and Shell Beach terraces yield tectonic uplift rates of 0.01 and 0.15 m/Ky, respectively, assuming the original elevation of each terrace was 7 m. Four specimens from the basal gravel on the Nestor terrace yielded ages of 145, 143, 137, and 133 Ky. The three oldest ages, however, are older than that associated with the last interglacial. The possible explanations for these older ages are ( 1 ) diagenic alteration or ( 2 ) the Nestor terrace deposits reflect in s
Differentiated Responses of Apple Tree Floral Phenology to Global Warming in Contrasting Climatic Regions.

PubMed

Legave, Jean-Michel; Guédon, Yann; Malagi, Gustavo; El Yaacoubi, Adnane; Bonhomme, Marc

2015-01-01

The responses of flowering phenology to temperature increases in temperate fruit trees have rarely been investigated in contrasting climatic regions. This is an appropriate framework for highlighting varying responses to diverse warming contexts, which would potentially combine chill accumulation (CA) declines and heat accumulation (HA) increases. To examine this issue, a data set was constituted in apple tree from flowering dates collected for two phenological stages of three cultivars in seven climate-contrasting temperate regions of Western Europe and in three mild regions, one in Northern Morocco and two in Southern Brazil. Multiple change-point models were applied to flowering date series, as well as to corresponding series of mean temperature during two successive periods, respectively determining for the fulfillment of chill and heat requirements. A new overview in space and time of flowering date changes was provided in apple tree highlighting not only flowering date advances as in previous studies but also stationary flowering date series. At global scale, differentiated flowering time patterns result from varying interactions between contrasting thermal determinisms of flowering dates and contrasting warming contexts. This may explain flowering date advances in most of European regions and in Morocco vs. stationary flowering date series in the Brazilian regions. A notable exception in Europe was found in the French Mediterranean region where the flowering date series was stationary. While the flowering duration series were stationary whatever the region, the flowering durations were far longer in mild regions compared to temperate regions. Our findings suggest a new warming vulnerability in temperate Mediterranean regions, which could shift toward responding more to chill decline and consequently experience late and extended flowering under future warming scenarios.
Publication dates of the North American Fauna series

USGS Publications Warehouse

Banks, Richard C.

1971-01-01

The correct date of publication of numbers in the well-known North American Fauna series, begun in 1889, was printed on the cover of each issue through No. 48. After that time dates of publication that appear on the covers are either incomplete or incorrect. For taxonomic purposes, for developing a chronological survey of a subject, or for other reasons, the exact date of publication of numbers in this important series is useful. We think it important to call attention to the correct dates of publication for numbers beyond 48. Those dealing with birds are listed below by number, followed by the author's name for ease of reference, the date printed on the cover of the issue, and the correct date of publication in parentheses. Numbers not listed do not relate to birds (see J. Mammal., 51: 845, 1970).
New U/Th ages for Pleistocene megafauna deposits of southeastern Queensland, Australia

NASA Astrophysics Data System (ADS)

Price, Gilbert J.; Zhao, Jian-xin; Feng, Yue-xing; Hocknull, Scott A.

2009-02-01

Arguments over the extinction of Pleistocene megafauna have become particularly polarised in recent years. Causes for the extinctions are widely debated with climate change, human hunting and/or habitat modification, or a combination of those factors, being the dominant hypotheses. However, a lack of a spatially constrained chronology for many megafauna renders most hypotheses difficult to test. Here, we present several new U/Th dates for a series of previously undated, megafauna-bearing localities from southeastern Queensland, Australia. The sites were previously used to argue for or against various megafauna extinction hypotheses, and are the type localities for two now-extinct Pleistocene marsupials (including the giant koala, Phascolarctos stirtoni). The new dating allows the deposits to be placed in a spatially- and temporally constrained context relevant to the understanding of Australian megafaunal extinctions. The results indicate that The Joint (Texas Caves) megafaunal assemblage is middle Pleistocene or older (>292 ky); the Cement Mills (Gore) megafaunal assemblage is late Pleistocene or older (>53 ky); and the Russenden Cave Bone Chamber (Texas Caves) megafaunal assemblage is late Pleistocene (˜55 ky). Importantly, the new results broadly show that the sites date prior to the hypothesised megafaunal extinction 'window' (i.e., ˜30-50 ky), and therefore, cannot be used to argue exclusively for or against human/climate change extinction models, without first exploring their palaeoecological significance on wider temporal and spatial scales.
Stable isotope compositions of speleothems from the last interglacial - Spatial patterns of climate fluctuations in Europe

NASA Astrophysics Data System (ADS)

Demény, Attila; Kern, Zoltán; Czuppon, György; Németh, Alexandra; Leél-Őssy, Szabolcs; Siklósy, Zoltán; Lin, Ke; Hu, Hsun-Ming; Shen, Chuan-Chou; Vennemann, Torsten W.; Haszpra, László

2017-04-01

Studies on the last interglacial (LIG) can provide information on how our environment behaved in a period of slightly higher global temperatures at about 125 ± 4 ka, even if it is not the best analogue for the Holocene. The available LIG climate proxy records are usually better preserved and can be studied at a higher resolution than those of the preceding interglacials, allowing detailed comparisons. This paper presents complex stable hydrogen, carbon and oxygen isotope records obtained for carbonate (δ13C and δ18Ocarb) and fluid inclusion hosted water (δD and δ18Ow) of a stalagmite from the Baradla Cave system in Central Europe that covers most of the LIG, as proven by U-Th dates. Comparing its C and O isotope data with records reported for other speleothem (cave-hosted carbonate) deposits from Europe revealed the complex behavior of these climate proxies, with a concerted relative increase in 18O of carbonates from 128 to 120 ka and synchronized shifts in the opposite direction after 119 ka. The hydrogen isotope analyses of inclusion-hosted water extracted from the BAR-II stalagmite also correspond to the regional climate proxy records, with meaningful deviations from global temperature trends. Beside following the general paleotemperature pattern from the climate optimum (high δD values up to -64‰ around 120 ka) to the subsequent cooling starting at about 119 ka (low δD values down to -90‰ at about 109 ka), a period between 126.5 and 123 ka with low δD values (down to -81‰) is detected in the BAR-II stalagmite. Although the isotope shifts are muted in the C-O isotope data of carbonate due to competitive fractionation processes, the δ13C data show a positive relationship with the δD pattern, indicating humidity - and possibly temperature - variations. The periods with low δD values fit well to temperature and humidity changes inferred from proxy records from western Europe to the eastern Mediterranean. Spatial distributions of these variables show, that at about 125 ± 2 ka the Mediterranean region was characterized by warm, humid conditions and enhanced seasonality with elevated winter precipitation. The combined interpretation of stable isotope data revealed that the Alpine and Mediterranean regions behaved differently during Greenland Stadial 26 (GS26, ∼119 to 116.2 ka). While the Alpine records fluctuated in close agreement with the Central Greenland ice core δ18O data, the BAR-II stalagmite show a positive δ18Ocarb anomaly. The Baradla data indicate enhanced aridity and seasonality for a part of GS26, with the relative dominance of summer precipitation and Mediterranean moisture contribution. Following the GS26 event, the effect of long-term global cooling becomes dominant in the Baradla isotope records and leads to glacial inception at about 109 ka.
NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0015, VL0016, VL0017, VL0018, VL0019, and VL0020

NASA Technical Reports Server (NTRS)

Papthakos, L. C.; Briehl, D.

1981-01-01

This is the twelfth of a series of reports which describes the data currently available from GASP, including flight routes and dates, instrumentation, data processing procedures, and data tape specifications. In-situ measurements of atmospheric ozone, cabin ozone, carbon monoxide, water vapor, particles, clouds, condensation nuclei, filter samples and related meteorological and flight information obtained during 1732 flights of aircraft N533PA, N4711U, N655PA, and VH-EBE from January 5, 1978 through October 9, 1978 are reported. These data are now available from the National Climatic Center, Asheville, NC, 22801. In addition to the GASP data, tropopause pressures obtained from time ans space interpolation of National Meteorological Center archived data for the dates of the flights are included.
Uranium series ages of corals from the upper Pleistocene Mulege terrace, Baja California Sur, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ashby, J.R.; Ku, T.L.; Minch, J.A.

1987-02-01

Specimens of Porites californica contained in the sediments of upper Pleistocene, +12-m marine terrace deposits developed on the east coast of the Baja California (Mexico) peninsula at Mulege have yielded /sup 239/Th//sup 234/U dates of 124 +/- 5 and 144 +/- 7 ka (+/- 1 sigma). These dates can be assigned to the well-documented late Pleistocene oxygen-isotope stage 5e high sea stand. Differences between the eustatic and present elevations of this terrace indicate average uplift rates since terrace formation of approximately 4 to 5 cm/1000 yr, indicating a relative stability and lack of major vertical deformation since the late Pleistocene.more » This terrace in the Mulege area can now be correlated with other marine terraces throughout the Baja California peninsula and southern California.« less
Beginning of grain harvest in the tri-border region Basel as a proxy for mean April - May temperatures; creation of a long Swiss series c. 1455 AD - 1950 AD

NASA Astrophysics Data System (ADS)

Wetter, Oliver; Pfister, Christian

2010-05-01

Beginning of grain harvest in the tri-border region Basel as a proxy for mean April-July temperatures; creation of a long Swiss series c. 1454 AD - 1950 AD O. Wetter and C. Pfister Section of Economic, Social and Environmental History, Institute of History, University of Bern, Bern, Switzerland (oliver.wetter@hist.unibe.ch) Before agricultural harvesting machines replaced manual labour the date of the grain harvest was largely dependent on mean temperatures from spring to early summer. It thus constitutes a very valuable source of information to reconstruct these temperatures. The later the harvest began, the cooler spring and early summer must have been and vice versa. For this reconstruction a new data series of grain harvests in the tri-border region Basel (representative for north-west Switzerland, the Alsace (France) and south-west Germany) was used as a temperature proxy. The harvesting dates have been extracted from the account books of the hospital of Basel which cover the period from c.1454 AD to 1705 AD. This series could be completed with several series of grain tithe dates originating from the Swiss Midland, covering the period between 1557 and 1825 and several grain harvest dates series covering the time between 1825 and 1950. Thus a series of almost 500 years could be compiled. Since the method of harvesting remained unchanged until the 1950's when manual labour was replaced by machines, the harvest dates of the modern series, lying within the temperature measurement series, could be used for calibrating the medieval dates.
Advances in Laser Microprobe (U-Th)/He Geochronology

NASA Astrophysics Data System (ADS)

van Soest, M. C.; Monteleone, B. D.; Boyce, J. W.; Hodges, K. V.

2008-12-01

The development of the laser microprobe (U-Th)/He dating method has the potential to overcome many of the limitations that affect conventional (U-Th)/He geochronology. Conventional single- or multi-crystal (U- Th)/He geochronology requires the use of pristine, inclusion-free, euhedral crystals. Furthermore, the ages that are obtained require corrections for the effects of zoning and alpha ejection based on an ensemble of assumptions before interpretation of their geological relevance is possible. With the utilization of microbeam techniques many of the limitations of conventional (U-Th)/He geochronology can either be eliminated by careful spot selection or accounted for by detailed depth profiling analyses of He, U and Th on the same crystal. Combined He, Th, and U depth profiling on the same crystal potentially even offers the ability to extract thermal histories from the analyzed grains. Boyce et al. (2006) first demonstrated the laser microprobe (U-Th)/He dating technique by successfully dating monazite crystals using UV laser ablation to liberate He and determined U and Th concentrations using a Cameca SX-Ultrachron microprobe. At Arizona State University, further development of the microprobe (U-Th)/He dating technique continues using an ArF Excimer laser connected to a GVI Helix Split Flight Tube noble gas mass spectrometer for He analysis and SIMS techniques for U and Th. The Durango apatite age standard has been successfully dated at 30.7 +/- 1.7 Ma (2SD). Work on dating zircons by laser ablation is currently underway, with initial results from Sri Lanka zircon at 437 +/- 14 Ma (2SD) confirmed by conventional (U-Th)/He analysis and in agreement with the published (U-Th)/He age of 443 +/- 9 Ma (2SD) for zircons from this region in Sri Lanka (Nasdala et al., 2004). The results presented here demonstrate the laser microprobe (U-Th)/He method as a powerful tool that allows application of (U- Th)/He dating to areas of research such as detrital apatite and zircon dating, where conventional (U-Th)/He geochronology has limited applicability. Boyce et al. (2006) GCA 70 (3031-3039), Nasdala et al. (2004) Am. Min. 89 (219-231)
A cross comparison of spatiotemporally enhanced springtime phenological measurements from satellites and ground in a northern U.S. mixed forest

USGS Publications Warehouse

Liang, Liang; Schwartz, Mark D.; Zhuosen Wang,; Gao, Feng; Schaaf, Crystal B.; Bin Tan,; Morisette, Jeffrey T.; Zhang, Xiaoyang

2014-01-01

Cross comparison of satellite-derived land surface phenology (LSP) and ground measurements is useful to ensure the relevance of detected seasonal vegetation change to the underlying biophysical processes. While standard 16-day and 250-m Moderate Resolution Imaging Spectroradiometer (MODIS) vegetation index (VI)-based springtime LSP has been evaluated in previous studies, it remains unclear whether LSP with enhanced temporal and spatial resolutions can capture additional details of ground phenology. In this paper, we compared LSP derived from 500-m daily MODIS and 30-m MODIS-Landsat fused VI data with landscape phenology (LP) in a northern U.S. mixed forest. LP was previously developed from intensively observed deciduous and coniferous tree phenology using an upscaling approach. Results showed that daily MODIS-based LSP consistently estimated greenup onset dates at the study area (625 m × 625 m) level with 4.48 days of mean absolute error (MAE), slightly better than that of using 16-day standard VI (4.63 days MAE). For the observed study areas, the time series with increased number of observations confirmed that post-bud burst deciduous tree phenology contributes the most to vegetation reflectance change. Moreover, fused VI time series demonstrated closer correspondences with LP at the community level (0.1-20 ha) than using MODIS alone at the study area level (390 ha). The fused LSP captured greenup onset dates for respective forest communities of varied sizes and compositions with four days of the overall MAE. This study supports further use of spatiotemporally enhanced LSP for more precise phenological monitoring.
Absolute dating and palaeoenvironmental evolution in Palaeolithic Mani, SW Peloponnesus

NASA Astrophysics Data System (ADS)

Christodoulakis, John; Bassiakos, Yannis; Athanassas, Constantin

2013-04-01

Data derived from palaeoenvironmental indicators are considered the most reliable in back casting former environmental contexts and also, where possible, in forecasting future trends in the environment. The peninsula of Mani, southern Peloponnesus, southwestern Greece, is a challenging area for studying past environmental changes of the Upper Quaternary, because of its nodal position between three continents, its long and multifarious coastal zone, as well as its active local tectonic regime. A great deal of sea level oscillations and palaeoclimatic and palaeoanthropological evidence have been well-documented in the terrestrial and coastal sedimentery deposits of the peninsula, particularly for the later part of the Quaternary (Kelletat und Gassert, 1975, Imperatori, 1966). That evidence mostly comes from paleoenvironmental indicators such as raised marine notches and marine terraces, as well as from other,indicators, and is frequently associated with sites of paleoanthropological significance An important parameter of those sedimentary deposits is their chronology. To date, the chronological framework of those processes is only loosely constrained. A first effort to produce chronological data for this area was made about twenty years ago by applying electron spin resonance (ESR) dating to speleothems from the local subsurface caverns system and other karst formations. Here, by engaging luminescence dating, we aimed to further control former ESR chronology as well as to extend numeric dating on sedimentary formations previously non-datable through ESR alone (i.e. fluvial/deltaic sediments occurring in the area as well as anthropogenic composite deposits usually including burnt bones and fragments of stone tools). Specifically, optically stimulated luminescence (OSL) dating, combined with the single-aliquot regenerative dose (SAR) protocol, produced a number of ages that are in fair agreement with the previous ESR chronology. Current data allowed us to comprehend the chronological framework of human-palaeoenvironment interactions over the later part of the Pleistocene with higher resolution than that attained formerly by ESR, A report about the progress of this effort is here presented. This study is funded by the NARNIA/FP7 Marie Curie Initial Training Network project.
Hunting for eruption ages in accessory minerals

NASA Astrophysics Data System (ADS)

Vazquez, J. A.

2012-12-01

A primary goal in geochronology is to provide precise and accurate ages for tephras that serve as chronostratigraphic markers for constraining the timing and rates of volcanism, sedimentation, climate change, and catastrophic events in Earth history. Zircon remains the most versatile accessory mineral for dating silicic tephras due to its common preservation in distal pyroclastic deposits, as well as the robustness of its U-Pb and U-series systems even after host materials have been hydrothermally altered or weathered. Countless studies document that zircon may be complexly zoned in age due to inheritance, contamination, recycling of antecrysts, protracted crystallization in long-lived magma reservoirs, or any combination of these. Other accessory minerals such as allanite or chevkinite can retain similar records of protracted crystallization. If the goal is to date the durations of magmatic crystallization, differentiation, and/or magma residence, then these protracted chronologies within and between accessory minerals are a blessing. However, if the goal is to date the timing of eruption with high precision, i.e., absolute ages with millennial-scale uncertainties, then this age zoning is a curse. Observations from ion microprobe 238U-230Th dating of Pleistocene zircon and allanite provide insight into the record of near-eruption crystallization in accessory minerals and serve as a guide for high-precision whole-crystal dating. Although imprecise relative to conventional techniques, ion probe analysis allows high-spatial resolution 238U-230Th dating that can document multi-millennial age distributions at the crystal scale. Analysis of unpolished rims and continuous depth profiling of zircon from small and large volume eruptions (e.g., Coso, Mono Craters, Yellowstone) reveals that the final several micrometers of crystallization often yield ages that are indistinguishable from associated eruption ages from the 40Ar/39Ar or (U-Th)/He methods. Using this approach, we have derived relatively precise (± ~ 5%, 2σ) U-Th isochron ages from the unpolished rims of pumice-derived allanite and zircon from late Pleistocene Wilson Creek Formation tephras in eastern California, whose ages are controversial and have been difficult to resolve via 40Ar/39Ar and radiocarbon dating. Allanite and zircon rims from Ashes 7-19 in the lower portion of Wilson Creek sediments yield stratigraphically consistent ages of ca. 27 ka to ca. 62 ka, with a minority of crystals identifiable as xenocrysts from early Mono Craters rhyolites. Model ages for the interiors of allanite crystals are mostly < 10 k.y. older than their rims. Tephra deposited during the geomagnetic excursion debated to be either the Mono Lake or Laschamp event yields a rim isochron age of ca. 41 ka. This age is indistinguishable from an independent age of 41 ka derived at the latter excursion's type locality in France (Singer et al., 2009) as well as from age-models for deep-sea sediments. The results are in excellent agreement with a previously determined chronology derived from magnetostratigraphy (Zimmerman et al., 2006). Refs: Singer et al., 2009, EPSL 286: 80-88; Zimmerman et al., 2006, EPSL 252: 94-106
Empirical constraints on the effects of radiation damage on helium diffusion in zircon

NASA Astrophysics Data System (ADS)

Anderson, Alyssa J.; Hodges, Kip V.; van Soest, Matthijs C.

2017-12-01

In this study, we empirically evaluate the impact of radiation damage on zircon (U-Th)/He closure temperatures for a suite of zircon crystals from the slowly cooled McClure Mountain syenite of south-central Colorado, USA. We present new zircon, titanite, and apatite conventional (U-Th)/He dates, zircon laser ablation (U-Th)/He and U-Pb dates, and zircon Raman spectra for crystals from the syenite. Titanite and apatite (U-Th)/He dates range from 447 to 523 Ma and 88.0 to 138.9 Ma, respectively, and display no clear correlation between (U-Th)/He date and effective uranium concentration. Conventional zircon (U-Th)/He dates range from 230.3 to 474 Ma, while laser ablation zircon (U-Th)/He dates show even greater dispersion, ranging from 5.31 to 520 Ma. Dates from both zircon (U-Th)/He datasets decrease with increasing alpha dose, indicating that most of the dispersion can be attributed to radiation damage. Alpha dose values for the dated zircon crystals range from effectively zero to 2.15 × 1019 α /g, spanning the complete damage spectrum. We use an independently constrained thermal model to empirically assign a closure temperature to each dated zircon grain. If we assume that this thermal model is robust, the zircon radiation damage accumulation and annealing model of Guenthner et al. (2013) does not accurately predict closure temperatures for many of the analyzed zircon crystals. Raman maps of the zircons dated by laser ablation document complex radiation damage zoning, sometimes revealing crystalline zones in grains with alpha dose values suggestive of amorphous material. Such zoning likely resulted in heterogeneous intra-crystalline helium diffusion and may help explain some of the discrepancies between our empirical findings and the Guenthner et al. (2013) model predictions. Because U-Th zoning is a common feature in zircon, radiation damage zoning is likely to be a concern for most ancient, slowly cooled zircon (U-Th)/He datasets. Whenever possible, multiple mineral-isotopic systems should be employed to add additional, independent constraints to a sample's thermal history.

Effect of soil-rock system on speleothems weathering in Bailong Cave, Yunnan Province, China*

PubMed Central

Wang, Jing; Song, Lin-hua

2005-01-01

Bailong Cave with its well-developed Middle Triassic calcareous dolomite’s system was opened as a show cave for visitors in 1988. The speleothem scenery has been strongly weathered as white powder on the outer layers. Study of the cave winds, permeability of soil-rock system and the chemical compositions of the dripping water indicated: (1) The cave dimension structure distinctively affects the cave winds, which were stronger at narrow places. (2) Based on the different soil grain size distribution, clay was the highest in composition in the soil. The response sense of dripping water to the rainwater percolation was slow. The density of joints and other openings in dolomite make the dolomite as mesh seepage body forming piles of thin and high columns and stalactites. (3) Study of 9 dripping water samples by HYDROWIN computer program showed that the major mineral in the water was dolomite. PMID:15682505
Indian monsoon variability on millennial-orbital timescales.

PubMed

Kathayat, Gayatri; Cheng, Hai; Sinha, Ashish; Spötl, Christoph; Edwards, R Lawrence; Zhang, Haiwei; Li, Xianglei; Yi, Liang; Ning, Youfeng; Cai, Yanjun; Lui, Weiguo Lui; Breitenbach, Sebastian F M

2016-04-13

The Indian summer monsoon (ISM) monsoon is critical to billions of people living in the region. Yet, significant debates remain on primary ISM drivers on millennial-orbital timescales. Here, we use speleothem oxygen isotope (δ(18)O) data from Bittoo cave, Northern India to reconstruct ISM variability over the past 280,000 years. We find strong coherence between North Indian and Chinese speleothem δ(18)O records from the East Asian monsoon domain, suggesting that both Asian monsoon subsystems exhibit a coupled response to changes in Northern Hemisphere summer insolation (NHSI) without significant temporal lags, supporting the view that the tropical-subtropical monsoon variability is driven directly by precession-induced changes in NHSI. Comparisons of the North Indian record with both Antarctic ice core and sea-surface temperature records from the southern Indian Ocean over the last glacial period do not suggest a dominant role of Southern Hemisphere climate processes in regulating the ISM variability on millennial-orbital timescales.
Effect of soil-rock system on speleothems weathering in Bailong Cave, Yunnan Province, China.

PubMed

Wang, Jing; Song, Lin-Hua

2005-03-01

Bailong Cave with its well-developed Middle Triassic calcareous dolomite's system was opened as a show cave for visitors in 1988. The speleothem scenery has been strongly weathered as white powder on the outer layers. Study of the cave winds, permeability of soil-rock system and the chemical compositions of the dripping water indicated: (1) The cave dimension structure distinctively affects the cave winds, which were stronger at narrow places. (2) Based on the different soil grain size distribution, clay was the highest in composition in the soil. The response sense of dripping water to the rainwater percolation was slow. The density of joints and other openings in dolomite make the dolomite as mesh seepage body forming piles of thin and high columns and stalactites. (3) Study of 9 dripping water samples by HYDROWIN computer program showed that the major mineral in the water was dolomite.
Two Millennia of South Atlantic Convergence Zone Variability Reconstructed From Isotopic Proxies

NASA Astrophysics Data System (ADS)

Novello, V. F.; Cruz, F. W.; Moquet, J. S.; Vuille, M.; de Paula, M. S.; Nunes, D.; Edwards, R. L.; Cheng, H.; Karmann, I.; Utida, G.; Stríkis, N. M.; Campos, J. L. P. S.

2018-05-01

Most reconstructions of the South American Monsoon System (SAMS) over the last two millennia are based on δ18O records from locations at high-elevation sites in the Andes, which are not influenced by the South Atlantic Convergence Zone (SACZ). Yet the SACZ is a key driver of SAMS variability over much of Brazil. Here we use two new δ18O records from speleothems sampled in the central and southwestern portions of the SACZ core to show that the SAMS was not varying in phase over the entire tropical continent during the last two millennia. In fact, speleothem records located to the northeast of the SACZ record precipitation variations that are antiphased with similar records on the opposite side of the SACZ, in particular during the Little Ice Age period, while records close to the core of the SACZ axis show no significant departure from the mean state during this period.
77 FR 61650 - The Entire United States and U.S. Territories

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-10

... SMALL BUSINESS ADMINISTRATION [Disaster Declaration 13332 Disaster ZZ-00008] The Entire United States and U.S. Territories AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is... . DATES: Effective Date: 10/01/2012. MREIDL Loan Application Deadline Date: 1 year after the essential...
LA-ICP-MS-derived U-concentrations and microstructural domains within biogenic aragonite of Arctica islandica shell.

PubMed

Helama, Samuli; Heikkilä, Pasi; Rinne, Katja; Nielsen, Jan Kresten; Nielsen, Jesper Kresten

2015-05-01

Understanding of the uranium uptake processes (both in vivo and post-mortem) into the skeletal structures of marine calcifiers is a subject of multi-disciplinary interest. U-concentration changes within the molluscan shell may serve as a paleoceanographic proxy of the pH history. A proxy of this type is needed to track the effects of fossil fuel emissions to ocean acidification. Moreover, attaining reliable U-series dates using shell materials would be a geochronological breakthrough. Picturing the high-resolution changes of U-concentrations in shell profiles is now possible by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Here, we analyzed in situ U-concentration variations in sub-fossilized shells of ocean quahog (Arctica islandica), a commonly studied bivalve species in Quaternary geoscience, using LA-ICP-MS. Microstructural details of the shell profiles were achieved by the scanning electron microscopy (SEM). Comparison of the shell aragonite microstructure with the changes in U-concentration revealed that uranium of possibly secondary origin is concentrated into the porous granular layers of the shell. Our results reinforce the hypothesis that U-concentration variations can be linked with microstructural differences within the shell. A combination of LA-ICP-MS and SEM analyses is recommended as an interesting approach for understanding the U-concentration variations in similar materials.
U/Th dating by SHRIMP RG ion-microprobe mass spectrometry using single ion-exchange beads

NASA Astrophysics Data System (ADS)

Bischoff, James L.; Wooden, Joe; Murphy, Fred; Williams, Ross W.

2005-04-01

We present a new analytical method for U-series isotopes using the SHRIMP RG (Sensitive High mass Resolution Ion MicroProbe) mass spectrometer that utilizes the preconcentration of the U-series isotopes from a sample onto a single ion-exchange bead. Ion-microprobe mass spectrometry is capable of producing Th ionization efficiencies in excess of 2%. Analytical precision is typically better than alpha spectroscopy, but not as good as thermal ionization mass spectroscopy (TIMS) and inductively coupled plasma multicollector mass spectrometry (ICP-MS). Like TIMS and ICP-MS the method allows analysis of small samples sizes, but also adds the advantage of rapidity of analysis. A major advantage of ion-microprobe analysis is that U and Th isotopes are analyzed in the same bead, simplifying the process of chemical separation. Analytical time on the instrument is ˜60 min per sample, and a single instrument-loading can accommodate 15-20 samples to be analyzed in a 24-h day. An additional advantage is that the method allows multiple reanalyses of the same bead and that samples can be archived for reanalysis at a later time. Because the ion beam excavates a pit only a few μm deep, the mount can later be repolished and reanalyzed numerous times. The method described of preconcentrating a low concentration sample onto a small conductive substrate to allow ion-microprobe mass spectrometry is potentially applicable to many other systems.
U/Th dating by SHRIMP RG ion-microprobe mass spectrometry using single ion-exchange beads

USGS Publications Warehouse

Bischoff, J.L.; Wooden, J.; Murphy, F.; Williams, Ross W.

2005-01-01

We present a new analytical method for U-series isotopes using the SHRIMP RG (Sensitive High mass Resolution Ion MicroProbe) mass spectrometer that utilizes the preconcentration of the U-series isotopes from a sample onto a single ion-exchange bead. Ion-microprobe mass spectrometry is capable of producing Th ionization efficiencies in excess of 2%. Analytical precision is typically better than alpha spectroscopy, but not as good as thermal ionization mass spectroscopy (TIMS) and inductively coupled plasma multicollector mass spectrometry (ICP-MS). Like TIMS and ICP-MS the method allows analysis of small samples sizes, but also adds the advantage of rapidity of analysis. A major advantage of ion-microprobe analysis is that U and Th isotopes are analyzed in the same bead, simplifying the process of chemical separation. Analytical time on the instrument is ???60 min per sample, and a single instrument-loading can accommodate 15-20 samples to be analyzed in a 24-h day. An additional advantage is that the method allows multiple reanalyses of the same bead and that samples can be archived for reanalysis at a later time. Because the ion beam excavates a pit only a few ??m deep, the mount can later be repolished and reanalyzed numerous times. The method described of preconcentrating a low concentration sample onto a small conductive substrate to allow ion-microprobe mass spectrometry is potentially applicable to many other systems. Copyright ?? 2005 Elsevier Ltd.
From Texas to the Northwest Territories: Low temperature history of the North American craton using a radiation damage model for apatite He diffusion

NASA Astrophysics Data System (ADS)

Flowers, R. M.; Ault, A. K.; Wolin, E.; Kelley, S.; Bowring, S. A.

2009-12-01

The radiation damage accumulation and annealing model (RDAAM) for apatite He diffusion helps resolve previously enigmatic characteristics of apatite (U-Th)/He data in cratonic regions. First, nonlinear positive date-eU correlations are predicted for many T-t paths, thus explaining excessive scatter in some (U-Th)/He datasets. Second, under common circumstances, the RDAAM predicts (U-Th)/He dates that are older than corresponding apatite fission-track (AFT) dates, helping reconcile previous data in which (U-Th)/He dates were older than expected using Durango He diffusion kinetics. We present five apatite (U-Th)/He datasets, three with co-existing AFT data, from the North American craton that can quantitatively be explained by the RDAAM. These datasets include three from the Canadian shield (Trans-Hudson Orogen, Lake Athabasca region, Slave Craton) and two from the U.S. midcontinent (Kansas, Texas panhandle). All samples are Precambrian (4.0-1.6 Ga) basement, except for Triassic-Jurassic sandstones analyzed in the Texas study. We use the results of these studies to evaluate broad thermal history patterns across the North American craton. Although each dataset yields a distinct thermal history, all can be accounted for by varying the magnitudes of two well-documented episodes of burial and unroofing in Paleozoic-Mesozoic and Cretaceous-Tertiary times. The oldest consistent (U-Th)/He and AFT dates of these studies are early Paleozoic and are preserved in the Trans-Hudson Orogen. Together with a strong (U-Th)/He date-eU correlation and dates as young as Jurassic in the Lake Athabasca region, as well as widespread Permo-Triassic dates from the Slave craton, the three Canadian shield datasets are most simply explained by increased magnitudes of burial toward the northwest in Paleozoic-Mesozoic time, with less significant burial in the Cretaceous. In contrast, (U-Th)/He data from Kansas yield a date-eU correlation and a cluster of Cretaceous dates, (U-Th)/He dates from the Texas panhandle are Cretaceous-Tertiary, and AFT dates from both areas are Permo-Triassic. Thus, the U.S. midcontinent datasets preserve a significant Cretaceous-Tertiary signal, requiring more substantial burial and unroofing during this time than the Canadian results. These younger dates in Texas and Kansas are likely related to flat slab evolution beneath the western U.S. in Cretaceous-Tertiary time, while the absence of this strong signal in the Canadian shield data is consistent with the lack of a flat slab beneath that region. The NW-SE trend in Paleozoic-Mesozoic thermal histories in the Canadian shield may be related to earlier spatial variability in plate margin subduction processes. The ability of the RDAAM to account for otherwise inexplicable aspects of the data presented here suggests that we can now reliably couple (U-Th)/He and AFT techniques to decipher low temperature cratonic histories in unprecedented detail, permitting insight into how cratons respond to external tectonic forces in the billions of years following their stabilization.
Age of the North Anatolian Fault Segments in the Yalova with U/Th Dating Method by Travertine Data

NASA Astrophysics Data System (ADS)

Selim, Haluk; Ömer Taş, K.

2016-04-01

Travertine occurrences developed along the segments of the North Anatolian Fault (NAF) in the south of Yalova. Travertines outcrop approximately 1 km2 area. These are middle-thick bedded approximately 20-40 m and back-tilted southward or horizontally. Lithology of travertines deposited such as physolite, stalactites-stalagmites, cave pearls, sharp pebble carbonate nodules, spherical-roller-intricate shapes or laminated banded travertine. Geochemical analyses were performed on the six samples of the travertines. X-ray analysis indicates that all samples are entirely composed of low-Mg calcite. Banded travertines with some tubular structures formed by precipitation from rising hot water are best developed near the toes of the large, hanging-wall-derived alluvial fans, whereas phreatic cement preferentially exists in footwall-derived, alluvial-fan conglomerates. The unit developed clarity which is controlled by normal fault as the structural and morphological, relationship with active tectonics. The travertines are a range-front type. U/Th series age dating results indicate that the travertine deposition extends back to 155 ka and yields ages of 60.000 (± 3, 091) to 153.149 (±13,466) from the range-front type travertines.
Multiple dating approach (14C, U/Th and 36Cl) of tsunami-transported reef-top megaclasts on Bonaire (Leeward Antilles) - potential and current limitations

NASA Astrophysics Data System (ADS)

Rixhon, Gilles; May, Simon Matthias; Engel, Max; Mechernich, Silke; Keulertz, Rebecca; Schroeder-Ritzrau, Andrea; Fohlmeister, Jens; Frank, Norbert; Dunai, Tibor; Brueckner, Helmut

2016-04-01

Coastal hazard assessment depends on reliable information on the magnitude and frequency of past high-energy wave events (EWE: tsunamis, storms). For this purpose onshore sedimentary records represent promising geo-archives for the mid- and late-Holocene EWE history. In comparison to fine-grained sediments which have been extensively studied in the recent past, supralittoral megaclasts are less investigated, essentially due to the difficulties related to the dating of corresponding depositional events, and thus their limited value for inferring the timing of major events. On Bonaire (Leeward Antilles, Caribbean), supratidal coarse-clast deposits form prominent landforms all around the island. Fields of large boulders (up to 150 t) are among the best-studied reef-top megaclasts worldwide. Transport by Holocene tsunamis is assumed at least for the largest boulders (Engel and May, 2012). Although a large dataset of 14C and electron spin resonance (ESR) ages is available for major coral rubble ridges and ramparts, showing some age clusters during the Late Holocene, it is still debated whether these data reflect the timing of major depositional/transport event(s), and how these data sets are biased by reworking of coral fragments. In addition, different processes may be responsible for the deposition of the coral rubble ridges and ramparts (storm) and the solitary megaclasts (tsunami). As an attempt to overcome the current challenges for dating the dislocation of the megaclasts, three distinct dating methods were implemented: (i) 14C dating of boring bivalves (Lithophaga) attached to the boulders; (ii) uranium-series (U/Th) dating of post-depositional, secondary calcitic flowstone at the underside of the boulders; and (iii) surface exposure dating of overturned boulders via 36Cl concentration measurements in corals. The three 14C datings yield age estimates >37 ka, i.e. most probably beyond the applicability of the method, which sheds doubt on the usefulness of this method in the current context. It seems that the bivalves had incorporated the old CaCO3 from the MIS 5.5 mother rock. A U/Th age of the calcitic flowstone points to the Late Holocene period (1.3 ka); it represents a minimum age for boulder transport. Further U/Th dating is in progress. Four coral samples collected from three overturned boulders yielded similar 36Cl concentration measurements, also pointing to a late Holocene dislocation of the clasts. However, it remains unclear whether this concentration cluster mostly results from nuclide accumulation at the "blank" side, subsequent to their overturning during the depositional event, or already from pre-exposure at depth in the MIS 5.5 coral reef platform prior to the EWE. Further analysis is in progress to disentangle the problematic role of inheritance. These preliminary results show the potential and the current limitations of the applied methods for dating the dislocation of supralittoral megaclasts. Reference: Engel, M., May, S.M.: Bonaire's boulder fields revisited: evidence for Holocene tsunami impact on the Leeward Antilles. Quat. Sci. Rev., 54, 126-141, 2012.
Multidecadal climate variability in Brazil's Nordeste during the last 3000 years based on speleothem isotope records

NASA Astrophysics Data System (ADS)

Novello, Valdir F.; Cruz, Francisco W.; Karmann, Ivo; Burns, Stephen J.; Stríkis, Nicolás M.; Vuille, Mathias; Cheng, Hai; Lawrence Edwards, R.; Santos, Roberto V.; Frigo, Everton; Barreto, Eline A. S.

2012-12-01

We present the first high resolution, approximately ∼4 years sample spacing, precipitation record from northeastern Brazil (hereafter referred to as ‘Nordeste’) covering the last ∼3000 yrs from 230Th-dated stalagmites oxygen isotope records. Our record shows abrupt fluctuations in rainfall tied to variations in the intensity of the South American summer monsoon (SASM), including the periods corresponding to the Little Ice Age (LIA), the Medieval Climate Anomaly (MCA) and an event around 2800 yr B.P. Unlike other monsoon records in southern tropical South America, dry conditions prevailed during the LIA in the Nordeste. Our record suggests that the region is currently undergoing drought conditions that are unprecedented over the past 3 millennia, rivaled only by the LIA period. Using spectral, wavelet and cross-wavelet analyses we show that changes in SASM activity in the region are mainly associated with variations of the Atlantic Multidecadal Oscillation (AMO) and to a lesser degree caused by fluctuations in tropical Pacific SST. Our record also shows a distinct periodicity around 210 years, which has been linked to solar variability.
The Asian monsoon over the past 640,000 years and ice age terminations.

PubMed

Cheng, Hai; Edwards, R Lawrence; Sinha, Ashish; Spötl, Christoph; Yi, Liang; Chen, Shitao; Kelly, Megan; Kathayat, Gayatri; Wang, Xianfeng; Li, Xianglei; Kong, Xinggong; Wang, Yongjin; Ning, Youfeng; Zhang, Haiwei

2016-06-30

Oxygen isotope records from Chinese caves characterize changes in both the Asian monsoon and global climate. Here, using our new speleothem data, we extend the Chinese record to cover the full uranium/thorium dating range, that is, the past 640,000 years. The record's length and temporal precision allow us to test the idea that insolation changes caused by the Earth's precession drove the terminations of each of the last seven ice ages as well as the millennia-long intervals of reduced monsoon rainfall associated with each of the terminations. On the basis of our record's timing, the terminations are separated by four or five precession cycles, supporting the idea that the '100,000-year' ice age cycle is an average of discrete numbers of precession cycles. Furthermore, the suborbital component of monsoon rainfall variability exhibits power in both the precession and obliquity bands, and is nearly in anti-phase with summer boreal insolation. These observations indicate that insolation, in part, sets the pace of the occurrence of millennial-scale events, including those associated with terminations and 'unfinished terminations'.
(De)coupled zircon metamictization, radiation damage, and He diffusivity

NASA Astrophysics Data System (ADS)

Ault, A. K.; Guenthner, W.; Reiners, P. W.; Moser, A. C.; Miller, G. H.; Refsnider, K. A.

2017-12-01

We develop and apply a new protocol for targeting crystals for the zircon (U-Th)/He (He) thermochronometry to maximize effective U (eU) and corresponding closure temperature variability to develop zircon He date-eU correlations observed in some datasets. Our approach exploits visual proxies for radiation damage accumulation (metamictization) during zircon selection. We show that by purposefully targeting a spectrum of zircon textures from pristine to metamict grains, it is possible to generate broad eU variation in suites of zircon from a single sample and zircon He date-eU-metamictization trends that can be exploited to resolve increasingly complex thermal histories. We present plane light photographs, eU concentration, and zircon He results from 59 individual zircons from nine crystalline rock samples. Six of the nine samples come from exposed Proterozoic granitoids on SE Baffin Island, Canada; Boulder Creek, CO; Sandia Mountains, NM; and Mecca Hills, CA. We report data from three Archean Baffin samples to compare with the Proterozoic Baffin sample date-eU-metamictization trend. In each Proterozoic sample, target zircons display a spectrum of metamictization from pristine, transparent crystals to purple-brown, translucent grains. Progressive loss of transparency and increase in discoloration consistently corresponds to an increase in eU in all samples. Individual zircon eU varies from 89-1885 ppm and, within each sample, the total eU spread is 538 ppm to 1374 ppm. For any given eU value, the Archean zircon appear comparatively more metamict than the Proterozoic Baffin grains and samples collectively define a 1681 ppm range in eU, with more restrictive intrasample eU spreads (199-1120 ppm). Proterozoic samples from Baffin, Sandia, and Front Range yield negative zircon He date-eU correlations with intrasample date ranges of 90-783 Ma. Increasing eU and younger dates correspond with increasing metamictization. In contrast, all three Proterozoic Mecca Hills samples yield uniform 25 Ma zircon He dates over 1800 ppm eU. We apply simple thermal history models that account for the coevolution of zircon radiation damage and He-diffusivity to demonstrate that visible zircon metamictization and He diffusivity can be either coupled or decoupled depending on a sample's thermal history.
An evaluation of uranium-series dating of fossil echinoids from southern California Pleistocene marine terraces

USGS Publications Warehouse

Muhs, D.R.; Kennedy, G.L.

1985-01-01

Fossil sea urchins (Strongylocentrotus) from Pleistocene marine terraces on the southern California Channel Islands have been dated by the uranium-series method in order to test the suitability of echinoids for dating marine terraces. Results indicate that urchin plates and spines do not behave as closed systems with respect to both uranium and thorium. Calculated ages based on these data do not agree with uranium-series ages (120,000 and 127,000 yrs) obtained previously from corals from the same localities. Thus, fossil sea urchins (Strongylocentrotus) are not considered suitable for uraniumseries dating of Pleistocene marine terrace deposits. ?? 1985.
60,000 Year Climate and Vegetation History of Southeast Alaska

NASA Astrophysics Data System (ADS)

Wilcox, Paul S.

Sedimentological and palynological analyses of lacustrine cores from Baker Island, located in Southeast Alaska's Alexander Archipelago, indicate that glaciers persisted on the island until 14,500 cal yr. BP. However, the appearance of tree pollen, including Pinus cf. contorta ssp. contorta (shore pine) and Tsuga mertensiana (mountain hemlock) immediately following deglaciation suggests that a forest refugium may have been present on ice-free portions of neighboring islands or the adjacent continental shelf. Sedimentological and palynological analyses indicate a variable climate during the Younger Dryas interval between 13,000 and 11,500 cal yr. BP, with a cold and dry onset followed by ameliorating conditions during the latter half of the interval. An eight cm-thick black tephra dated to 13,500 +/- 250 cal yr. BP is geochemically distinct from the Mt. Edgecumbe tephra and thus derived from a different volcano. Based on overall thickness, multiple normally graded beds, and grain size, I infer that the black tephra was emplaced by a large strombolian-style paroxysm. Because the dominant wind direction along this coast is from the west, the Addington Volcanic Field on the continental shelf, which would have been subaerially exposed during the eruption, is a potential source. The similarity in timing between this eruption and the Mt. Edgecumbe eruption suggests a shared trigger, possibly a response to unloading as the Cordilleran Ice Sheet retreated. To complement the Baker Island lacustrine record, a speleothem paleoclimate record based on delta13C and delta18O values spanning the interval from 60,000 yr. BP to 11,150 yr. BP was recovered from El Capitan Cave on neighboring Prince of Wales Island. More negative delta13 C values are attributed to predominance of angiosperms in the vegetation above the cave at 22,000 yr. BP and between 53,000 and 46,000 yr. BP while more positive delta13C values in speleothem EC-16-5-F indicate the presence of gymnosperms. These data suggest limited or no ice cover above El Capitan Cave for the duration of the record, possibly indicating that this region was a nunatak during glacial periods.
Speleology and magnetobiostratigraphic chronology of the GD 2 locality of the Gondolin hominin-bearing paleocave deposits, North West Province, South Africa.

PubMed

Herries, Andy I R; Adams, Justin W; Kuykendall, Kevin L; Shaw, John

2006-12-01

Speleological, paleomagnetic, mineral magnetic, and biochronological analyses have been undertaken at the Gondolin hominin-bearing paleocave, North West Province, South Africa. Two fossiliferous but stratigraphically separate sequences, GD2 and GD1/3, which were once part of a large cavern system, have been identified. Although some comparative paleomagnetic samples were taken from the GD 1, 3, and 4 localities that are currently under investigation, the research presented here focuses on the fossil-rich, in situ deposits at locality GD 2, excavated by E.S. Vrba in 1979. The GD 2 deposits are dominated by normal-polarity calcified clastic deposits that are sandwiched between clastic-free flowstone speleothems. The lower flowstone has a sharp contact with the red siltstone deposits and is of reversed polarity. The capping flowstone shows a change from normal to reversed polarity, thereby preserving a polarity reversal. While the paleomagnetic work indicates that the GD 2 fossil material was deposited during a normal-polarity period, the shortness of the sequence made matching of the magnetostratigraphy to the geomagnetic polarity time scale (GPTS) impossible without the aid of biochronology. While lacking multiple time-sensitive taxa, the recovery of specimens attributable to Stage III Metridiochoerus andrewsi is consistent with a deposition date between 1.9 and 1.5 Ma. A comparison of the magnetostratigraphy with the GPTS therefore suggests that the fauna-bearing siltstone of GD 2 date to the Olduvai normal-polarity event, which occurred between 1.95 and 1.78 Ma, and that the reversal from normal to reversed polarity identified in the capping flowstone dates to 1.78 Ma. The main faunal layers therefore date to slightly older than 1.78 Ma. Deposits from the GD 1 locality are dominated by reversed directions of magnetization, which show that this deposit is not of the same age as the faunal layers from the GD 2 locality.
78 FR 77175 - Catalyst Capital Advisors LLC and Mutual Fund Series Trust; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2013-12-20

... Capital Advisors LLC and Mutual Fund Series Trust; Notice of Application December 16, 2013. ACTION: Notice... shareholder approval. APPLICANTS: Catalyst Capital Advisors LLC (``CCA'' or the ``Adviser'') and Mutual Fund Series Trust (formerly Catalyst Funds) (the ``Trust''). DATES: Filing Dates: The application was filed on...
Comparison of transfer entropy methods for financial time series

NASA Astrophysics Data System (ADS)

He, Jiayi; Shang, Pengjian

2017-09-01

There is a certain relationship between the global financial markets, which creates an interactive network of global finance. Transfer entropy, a measurement for information transfer, offered a good way to analyse the relationship. In this paper, we analysed the relationship between 9 stock indices from the U.S., Europe and China (from 1995 to 2015) by using transfer entropy (TE), effective transfer entropy (ETE), Rényi transfer entropy (RTE) and effective Rényi transfer entropy (ERTE). We compared the four methods in the sense of the effectiveness for identification of the relationship between stock markets. In this paper, two kinds of information flows are given. One reveals that the U.S. took the leading position when in terms of lagged-current cases, but when it comes to the same date, China is the most influential. And ERTE could provide superior results.
Assessing the origin of unusual organic formations in lava caves from Canary Islands (Spain)

NASA Astrophysics Data System (ADS)

Miller, Ana Z.; de la Rosa, Jose M.; Garcia-Sanchez, Angela M.; Pereira, Manuel F. C.; Jurado, Valme; Fernández, Octavio; Knicker, Heike; Saiz-Jimenez, Cesareo

2016-04-01

Lava tubes, like other caves, contain a variety of speleothems formed in the initial stage of a lava tube formation or due to leaching and subsequent precipitation of secondary minerals. Primary and secondary mineral formations in lava caves are mainly composed of silicate minerals, although secondary minerals common in limestone caves have been also reported in this type of caves. In addition, unusual colored deposits have been found on the walls and ceilings of lava tubes, some of them of unknown origin and composition. A brown to black-colored mud-like deposits was observed in "Llano de los Caños" Cave, La Palma Island, Canary Islands, Spain. These black deposits coat the wall and ceiling of the lava tube where sub-horizontal fractures occur. FESEM-EDS, X-ray micro-computed tomography and mineralogical analyses were conducted for morphological, 3D microstructural and compositional characterization of these unusual speleothem samples. These techniques revealed that they are mainly composed of amorphous materials, suggesting an organic carbon composition. Hence, analytical pyrolysis (Py-GC/MS), solid-state 13C Nuclear Magnetic Resonance (NMR) and stable isotope analysis were applied to assess the nature and origin of the black deposits. The combination of these analytical tools permits the identification of specific biomarkers (di- and triterpenoids) for tracing the potential sources of the organic compounds in the speleothems. For comparison purposes, samples from the topsoil and overlaying vegetation were also analyzed. Chromatograms resulting from the Py-GC/MS showed an abundance of polysaccharides, lipids and terpenoids typically derived from the vegetation of the area (Erica arborea). In addition, levoglucosan, polycyclic aromatic hydrocarbons and N-containing heterocyclic compounds were detected. They probably derived from the leaching of charred vegetation resulting from a wildfire occurred in the area in 2012. The lack of the typical pattern of odd-over-even in the series of n-alkanes observed for the topsoil and black deposits has been recognized as an indication of fire. The 13C NMR spectrum of the black deposits showed a mixture of alkyl and O-alkyl compounds, carboxylic compounds and polysaccharides. Stable isotope analysis of δ 13C performed on the cave black deposits, topsoil and vegetation confirmed that the source of the organic fraction of the sample is a combination of partially charred vegetation (mainly Erica) and organic compounds from the andic soil over the cave. Therefore, these black deposits are the result of an input of plant organic matter and charred vegetation into the cave from rock fractures, which may constitute an important source of energy for cave organisms. Acknowledgments: AZM and JMR acknowledge the support from the Marie Curie Fellowships within the 7th European Community Framework Programme (Grants PIEF-GA-2012-328689-DECAVE and PCIG12-GA-2012-333784-Biocharisma respectively). The authors acknowledge the Spanish Ministry of Economy and Competitiveness (project CGL2013-41674-P) and FEDER funds for financial support.

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