230Th-U dating of surficial deposits using the ion microprobe (SHRIMP-RG): A microstratigraphic perspective

USGS Publications Warehouse

Maher, K.; Wooden, J.L.; Paces, J.B.; Miller, D.M.

2007-01-01

We used the sensitive high-resolution ion microprobe reverse-geometry (SHRIMP-RG) to date pedogenic opal using the 230Th-U system. Due to the high-spatial resolution of an ion microprobe (typically 30 ??m), regions of pure opal within a sample can be targeted and detrital material can be avoided. In addition, because the technique is non-destructive, the sample can be preserved for other types of analyses including electron microprobe or other stable isotope or trace element ion microprobe measurements. The technique is limited to material with U concentrations greater than ???50 ppm. However, the high spatial resolution, small sample requirements, and the ability to avoid detrital material make this technique a suitable technique for dating many Pleistocene deposits formed in semi-arid environments. To determine the versatility of the method, samples from several different deposits were analyzed, including silica-rich pebble coatings from pedogenic carbonate horizons, a siliceous sinter deposit, and opaline silica deposited as a spring mound. U concentrations for 30-??m-diameter spots ranged from 50 to 1000 ppm in these types of materials. The 230Th/232Th activity ratios also ranged from ???100 to 106, eliminating the need for detrital Th corrections that reduce the precision of traditional U-Th ages for many milligram- and larger-sized samples. In pedogenic material, layers of high-U opal (ca. 500 ppm) are commonly juxtaposed next to layers of calcite with much lower U concentrations (1-2 ppm). If these types of samples are not analyzed using a technique with the appropriate spatial resolution, the ages may be strongly biased towards the age of the opal. Comparison with standard TIMS (Thermal Ionization Mass Spectrometry) measurements from separate microdrilled samples suggests that although the analytical precision of the ion microprobe (SHRIMP-RG) measurements is less than TIMS, the high spatial resolution results in better accuracy in the age determination for finely layered or complex deposits. The ion microprobe approach also may be useful for pre-screening samples to determine the age and degree of post-depositional alteration, analyzing finely layered samples or samples with complex growth histories, and obtaining simultaneous measurements of trace elements.

The paleomagnetism of clastic and precipitate deposits in limestone and dolomite caves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Latham, A.G.; Ford, D.C.

1991-03-01

Clastic sediments and calcite precipitates (stalagmites, flowstones, etc.) are abundant in modern limestone caves and normally are the dominant infillings in buried (paleokarst) caves. Clastic sediment fillings are chiefly of fluviatile or local breakdown origin, but lacustrine, colluvial, eolian, and glacial deposits are known. Paleomagnetism has been studied in the fluviatile and lacustrine types: (1) reversal stratigraphy aids dating of geomorphic and paleoclimatic events in the late Pliocene/Pleistocene; (2) fine magnetostratigraphy has yielded estimates of the westward drift. Calcite precipitates (speleothems) may display natural remanent magnetism of either depositional (DRM) or chemical (CRM) origin. NRMs of modern speleothems are primary,more » not diagenetic; CRMs are invariably associated with the degradation of surface organic matter. (1) Coarse reversal stratigraphy dates geomorphic, etc., events and erosion rates. (2) Fine stratigraphy combined with {sup 230}Th:{sup 234}U dating gives high precision estimates of secular variation, westward drift, and rate of change of geomagnetic anomalies in upper Pleistocene and Holocene deposits. Magnetostratigraphy of paleokarst speleothem fillings associated with hydrocarbons in Ordovician limestones suggest a Permian age for the karstification. Potential applications of magnetostratigraphy to paleokarst deposits of many different scales are considerable.« less

Thermal history of the unsaturated zone at Yucca Mountain, Nevada, USA

USGS Publications Warehouse

Whelan, J.F.; Neymark, L.A.; Moscati, R.J.; Marshall, B.D.; Roedder, E.

2008-01-01

Secondary calcite, silica and minor amounts of fluorite deposited in fractures and cavities record the chemistry, temperatures, and timing of past fluid movement in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a high-level radioactive waste repository. The distribution and geochemistry of these deposits are consistent with low-temperature precipitation from meteoric waters that infiltrated at the surface and percolated down through the unsaturated zone. However, the discovery of fluid inclusions in calcite with homogenization temperatures (Th) up to ???80 ??C was construed by some scientists as strong evidence for hydrothermal deposition. This paper reports the results of investigations to test the hypothesis of hydrothermal deposition and to determine the temperature and timing of secondary mineral deposition. Mineral precipitation temperatures in the unsaturated zone are estimated from calcite- and fluorite-hosted fluid inclusions and calcite ??18O values, and depositional timing is constrained by the 207Pb/235U ages of chalcedony or opal in the deposits. Fluid inclusion Th from 50 samples of calcite and four samples of fluorite range from ???35 to ???90 ??C. Calcite ??18O values range from ???0 to ???22??? (SMOW) but most fall between 12 and 20???. The highest Th and the lowest ??18O values are found in the older calcite. Calcite Th and ??18O values indicate that most calcite precipitated from water with ??18O values between -13 and -7???, similar to modern meteoric waters. Twenty-two 207Pb/235U ages of chalcedony or opal that generally postdate elevated depositional temperatures range from ???9.5 to 1.9 Ma. New and published 207Pb/235U and 230Th/Uages coupled with the Th values and estimates of temperature from calcite ??18O values indicate that maximum unsaturated zone temperatures probably predate ???10 Ma and that the unsaturated zone had cooled to near-present-day temperatures (24-26 ??C at a depth of 250 m) by 2-4 Ma. The evidence of elevated temperatures persisting in ash flow tuffs adjacent to parent calderas for as much as ???8 Ma is a new finding, but consistent with thermal modeling. Simulations using the HEAT code demonstrate that prolonged cooling of the unsaturated zone is consistent with magmatic heat inputs and deep-seated (sub-water table) hydrothermal activity generated by the large magma body ???8 km to the north that produced the 15-11 Ma ash flows and ash falls that make up Yucca Mountain. The evidence discussed in this and preceding papers strongly supports unsaturated zone deposition of the secondary minerals from descending meteoric waters. Although depositional temperatures reflect conductive (and possibly vapor-phase convective) heating of the unsaturated zone related to regional magmatic sources until perhaps 6 Ma, depositional conditions similar to the present-day unsaturated zone have prevailed for at least the past 2-4 Ma.

Geochemistry of speleothems affected by aragonite to calcite recrystallization - Potential inheritance from the precursor mineral

NASA Astrophysics Data System (ADS)

Domínguez-Villar, David; Krklec, Kristina; Pelicon, Primož; Fairchild, Ian J.; Cheng, Hai; Edwards, Lawrence R.

2017-03-01

Formerly aragonite speleothems recrystallized to calcite result from solutions subsaturated in aragonite and supersaturated in calcite that infiltrate into the speleothem through the interconnected porosity. In most cases, the crystal replacement takes place through a thin solution film. This diagenetic process can occur under open or semi-closed geochemical conditions. Thus, secondary calcite crystals record the composition of the fluid at the time of diagenesis affected by calcite partition coefficients and fractionation factors (open system) or partly inherit the composition of the primary aragonite (semi-closed system). So, whether or not recrystallized aragonite speleothems can record reliable geochemical signals from the time of speleothem primary deposition still is an open debate. We studied a stalagmite from Eagle Cave (Spain) predominantly composed of secondary calcite that replaced aragonite, although a core of primary aragonite extending 45 mm along the growth direction was preserved at the base of the sample. We obtained Mg and Sr compositional maps, paired U-Th dating and δ18O and δ13C profiles across the diagenetic front. Additionally, two parallel isotope records were obtained along the speleothem growth direction in the aragonite and calcite sectors. Our results support that recrystallization of this speleothem took place in open system conditions for δ18O, δ13C, Mg and Sr, but in semi-closed system conditions for U and Th. The recrystallization of this sample took place during one or several events, likely after the Younger Dryas as a result of climate change influencing drip water composition. Based on compositional zoned patterns, we suggest that the advance of diagenetic fronts in this speleothem had an average rate of 50 ± 45 μm/yr. Such recrystallization rate can transform any aragonite speleothem into calcite within a few centuries. We suggest that the volume of water interacting with the speleothem at the time of recrystallization is of critical importance for inheritance of different elements. The volume of solution is controlled by (1) the discharge of water passing through the sample and (2) the lapse time between aragonite dissolution and calcite precipitation. Hydrology and hydrochemistry of the interacting solution, together with the mineralogy and texture of the speleothem are the essential controls for the diagenesis of the speleothem. Recrystallization of aragonite speleothems does not follow stratigraphical levels of the sample but occurs along sites with preferential flow paths in any sector of the speleothem. In these cases the relationship between age and distance from base is not preserved. However, alternation of periods of recrystallization with periods of aragonite precipitation causing speleothem accretion can result in recrystallized speleothems with coherent distance from the base-age relationship. Thus, early diagenesis of speleothems affected by seasonal or inter-annual oscillation of drip waters supersaturated and subsaturated in aragonite may provide best-scenario conditions for dating and preservation of paleoenvironmental records along recrystallized speleothems. However, even in this scenario, the variable discharge and the diagenetic rate control the geochemical inheritance from the primary aragonite crystals.

Defects in Calcite.

DTIC Science & Technology

1991-05-13

AD-A245 645 A TRIDENT SCHOLAR PROJECT REPORT NO. 181 "DEFECTS IN CALCITE " DTTC %N FEB 5-1912 UNITED STATES NAVAL ACADEMY ANNAPOLIS, MARYLAND 92-02841...report; no. 181 (1991) "DEFECTS IN CALCITE " A Trident Scholar Project Report by Midshipman Anthony J. Kotarski, Class of 1991 U. S. Naval Academy Annapolis...REPORT TYPE AND DATES COVERED 13 May 1991 Final 1990/91 . TITLE AND SUBTITLE s. FUNDING NUMBERS DEFECTS IN CALCITE 6. AUTHOR(S) Anthony J. Kotarski 7

Controls on the long term earthquake behavior of an intraplate fault revealed by U-Th and stable isotope analyses of syntectonic calcite veins

NASA Astrophysics Data System (ADS)

Williams, Randolph; Goodwin, Laurel; Sharp, Warren; Mozley, Peter

2017-04-01

U-Th dates on calcite precipitated in coseismic extension fractures in the Loma Blanca normal fault zone, Rio Grande rift, NM, USA, constrain earthquake recurrence intervals from 150-565 ka. This is the longest direct record of seismicity documented for a fault in any tectonic environment. Combined U-Th and stable isotope analyses of these calcite veins define 13 distinct earthquake events. These data show that for more than 400 ka the Loma Blanca fault produced earthquakes with a mean recurrence interval of 40 ± 7 ka. The coefficient of variation for these events is 0.40, indicating strongly periodic seismicity consistent with a time-dependent model of earthquake recurrence. Stochastic statistical analyses further validate the inference that earthquake behavior on the Loma Blanca was time-dependent. The time-dependent nature of these earthquakes suggests that the seismic cycle was fundamentally controlled by a stress renewal process. However, this periodic cycle was punctuated by an episode of clustered seismicity at 430 ka. Recurrence intervals within the earthquake cluster were as low as 5-11 ka. Breccia veins formed during this episode exhibit carbon isotope signatures consistent with having formed through pronounced degassing of a CO2 charged brine during post-failure, fault-localized fluid migration. The 40 ka periodicity of the long-term earthquake record of the Loma Blanca fault is similar in magnitude to recurrence intervals documented through paleoseismic studies of other normal faults in the Rio Grande rift and Basin and Range Province. We propose that it represents a background rate of failure in intraplate extension. The short-term, clustered seismicity that occurred on the fault records an interruption of the stress renewal process, likely by elevated fluid pressure in deeper structural levels of the fault, consistent with fault-valve behavior. The relationship between recurrence interval and inferred fluid degassing suggests that pore fluid pressure along the fault may have been driven by variations in CO2 content, thereby fundamentally affecting earthquake frequency. Thus, the Loma Blanca fault provides a record of "naturally induced" seismicity, with lessons for better understanding anthropogenic induced seismicity.

206Pb-230Th-234U-238U and 207Pb-235U geochronology of Quaternary opal, Yucca Mountain, Nevada

USGS Publications Warehouse

Neymark, Leonid A.; Amelin, Yuri V.; Paces, James B.

2000-01-01

U–Th–Pb isotopic systems have been studied in submillimeter-thick outermost layers of Quaternary opal occurring in calcite–silica fracture and cavity coatings within Tertiary tuffs at Yucca Mountain, Nevada, USA. These coatings preserve a record of paleohydrologic conditions at this site, which is being evaluated as a potential high-level nuclear waste repository. The opal precipitated from groundwater is variably enriched in 234U (measured 234U/238U activity ratio 1.124–6.179) and has high U (30–313 ppm), low Th (0.008–3.7 ppm), and low common Pb concentrations (measured 206Pb/204Pb up to 11,370). It has been demonstrated that the laboratory acid treatment used in this study to clean sample surfaces and to remove adherent calcite, did not disturb U–Th–Pb isotopic systems in opal. The opal ages calculated from 206Pb∗/238U and 207Pb∗/235U ratios display strong reverse discordance because of excess radiogenic 206Pb∗ derived from the elevated initial 234U. The data are best interpreted using projections of a new four-dimensional concordia diagram defined by 206Pb∗/238U, 207Pb∗/235U, 234U/238Uactivity, and 230Th/238Uactivity. Ages and initial 234U/238U activity ratios have been calculated using different projections of this diagram and tested for concordance. The data are discordant, that is observed 207Pb∗/235U ages of 170 ± 32 (2σ) to 1772 ± 40 ka are systematically older than 230Th/U ages of 34.1 ± 0.6 to 452 ± 32 ka. The age discordance is not a result of migration of uranium and its decay products under the open system conditions, but a consequence of noninstantaneous growth of opal. Combined U–Pb and 230Th/U ages support the model of slow mineral deposition at the rates of millimeters per million years resulting in layering on a scale too fine for mechanical sampling. In this case, U–Pb ages provide more accurate estimates of the average age for mixed multiage samples than 230Th/U ages, because ages based on shorter-lived isotopes are nonlinearly biased by younger mineral additions. Use of the combined U–Th–Pb technique to date Yucca Mountain Quaternary opals significantly extends the age range beyond that of the 230Th/U dating method and shows that selected fracture pathways in the unsaturated zone felsic tuffs of Yucca Mountain have been active throughout the Quaternary.

Age of the North Anatolian Fault Segments in the Yalova with U/Th Dating Method by Travertine Data

NASA Astrophysics Data System (ADS)

Selim, Haluk; Ömer Taş, K.

2016-04-01

Travertine occurrences developed along the segments of the North Anatolian Fault (NAF) in the south of Yalova. Travertines outcrop approximately 1 km2 area. These are middle-thick bedded approximately 20-40 m and back-tilted southward or horizontally. Lithology of travertines deposited such as physolite, stalactites-stalagmites, cave pearls, sharp pebble carbonate nodules, spherical-roller-intricate shapes or laminated banded travertine. Geochemical analyses were performed on the six samples of the travertines. X-ray analysis indicates that all samples are entirely composed of low-Mg calcite. Banded travertines with some tubular structures formed by precipitation from rising hot water are best developed near the toes of the large, hanging-wall-derived alluvial fans, whereas phreatic cement preferentially exists in footwall-derived, alluvial-fan conglomerates. The unit developed clarity which is controlled by normal fault as the structural and morphological, relationship with active tectonics. The travertines are a range-front type. U/Th series age dating results indicate that the travertine deposition extends back to 155 ka and yields ages of 60.000 (± 3, 091) to 153.149 (±13,466) from the range-front type travertines.

CHRONOLOGICAL CONSTRAINTS ON FLUID CIRCULATION IN MESOZOIC FORMATIONS OF THE EASTERN PART OF THE PARIS BASIN INFERRED FROM U-Pb DATING OF SECONDARY INFILLING CARBONATES

NASA Astrophysics Data System (ADS)

Pisapia, C.; Deschamps, P.; Hamelin, B.; Buschaert, S.

2009-12-01

The French agency for nuclear waste management (ANDRA) developed an Underground Research Laboratory in the Mesozoic formations of Eastern part of the Paris Basin (France) to assess the feasibility of a high-level radioactive wastes repository in sedimentary formations. The target host formation is a low-porosity detrital argillite (Callovo-Oxfordian) embedded between two shelf limestones formations (of Bajocian-Bathonian and Oxfordian-Kimmeridgian ages). These formations are affected by fracture networks, likely inherited mainly from the Eocene-Oligocene extension tectonics, also responsible of the Rhine graben formation in the same region. The limestones have very low permeability, the primary and secondary porosity being infilled by secondary carbonated minerals. The inter-particle porosity is filled with euhedral calcite spar cements. Similarly, macro-cavities and connected micro-fractures are almost sealed by euhedral calcite. Geochemical evidences (δ18O) suggest that the secondary carbonates likely derived from a common parent fluid (Buschaert et al., 2004, Appl. Geochem. (19) 1201-1215p). This late carbonated precipitation phase is responsible for the intense cementation of the limestone formations and bears witness of a major phase of fluids circulation that marked the late diagenetic evolution of the system. Knowledge of the chronology of the different precipitation phases of secondary minerals is thus of critical importance in order to determine the past hydrological conditions of the geological site. The aim of this study is to provide chronological constraints on the secondary carbonate mineral precipitation using U/Th and U/Pb methods. Analyses are performed on millimeter to centimeter scale secondary calcites collected within fractures outcropping in the regional fault zone of Gondrecourt and in cores from the ANDRA exploration-drilling program. Preliminary U-Th analyses obtained on secondary carbonates from surface fractures infillings yield secular equilibrium composition, indicating that the precipitation phase was older than 650 ky. U-Pb measurements were performed on a VG sector Thermal Ionization Mass Spectrometer (TIMS) using a 205Pb-236U-233U-229Th spike. Pb contents are generally very low, between 3 and 20 ppb, while U contents are more variable, leading to μ = 238U/204Pb up to ~600. Sub-samples with high μ show radiogenic 206Pb/204Pb ratio, but at this stage isochrons generally show high scatter. These U-Pb data however are consistent with an Eocene-Oligocene period for the late carbonates precipitation phase. We will discuss the different processes that may be responsible for these errorchrons (i.e. heterogeneities in the initial isotopic composition; multi-stage growth) as well as the chronological constraints that can be drawn from these data.

Aragonite-calcite precipitation in vertical fractures of the "Erzberg" siderite deposit (Austria): Hydrogeochemical and neotectonic implications

NASA Astrophysics Data System (ADS)

Boch, Ronny; Wang, Xianfeng; Kluge, Tobias; Kurz, Walter; Leis, Albrecht; Lin, Ke; Pluch, Hannes; Mittermayr, Florian; Dietzel, Martin

2017-04-01

The ore deposit "Erzberg" represents the worldwide largest FeCO3 occurrence and is amongst Austria's most prominent geological places due to its historic, economic and scientific value. The iron-ore (siderite/ankerite) bearing Devonian carbonates of the open pit mine locally host sequential aragonite-calcite precipitates infilling vertical fractures. These typically laminated carbonates are referred to as erzbergite in mineral collections. To study their formation conditions we recovered samples on-site, i.e. from the rare veins being cm to dm in horizontal and tenths of meters in vertical extension. Additionally, samples from our university collection and private collectors were investigated. Some of the fractures filled with aragonite/calcite further exhibit cataclastic sediments, damage zones and slickenside striations. Modern water samples were collected from fractures currently accessible to conduct hydrochemical analyses and modeling. Selected precipitates were analyzed applying microscopic techniques, XRD, electron microprobe elemental mapping, stable and clumped isotopes, and 238U-234U-230Th radiometric dating. Erzbergite veins show either uni- or bidirectional growth, i.e. on one or both fracture/fault planes toward complete infilling depending on vadose water flow. The laminated precipitates are dominated by aragonite relative to pristine as well as partially diagenetic (Mg)-calcite. Intercalated and recurrent brownish Fe-rich layers consisting of goethite, quartz, muscovite are probably of detrital origin. Stable C and O isotopes of the precipitates reveal pronounced spatiotemporal variations in which low δ18O values (-10.4 to -5.1 ‰ VPDB) reflect a meteoric origin and low temperatures of the erzbergite depositing solutions. Carbonate clumped isotope measurements verify formation temperatures ≤25 °C. High δ13C values (-0.7 to +6.8 ‰ VPDB) of the precipitates indicate an origin from dissolution of local ankerite and limestone, without a significant proportion from soil CO2. Prominently high δ13C in DIC (≤+3.8 ‰) were also measured in modern fracture waters next to elevated sulfate (up to 226 mg/l) and high total dissolved solid contents (up to 1273 mg/l). These results suggest intense water-rock interaction based on sulfide oxidation and sulfuric acid evolution providing an efficient mechanism for host rock dissolution, mobilization and typically rapid aragonite-calcite mineralization. Sulfide accessories are widespread at Erzberg and the brownish Fe-rich layers within erzbergite could be explained by corrosion of Fe-sulfides and/or Fe-carbonates. The aragonite-calcite lamination is interpreted as an event lamination (not annual), i.e. variable aqueous Mg2+/Ca2+ ratios and CaCO3 supersaturation states triggering the polymorphism. U-Th analyses yielded surprisingly young ages for erzbergite dated so far, i.e. late Pleistocene and mostly younger than the last glacial maximum. A 4 cm thick sample composed of aragonite exclusively and filling a tenths of meters extending fracture formed 10.4 ±0.2 (sample base, initiation) to 1.03 ±0.04 kyr BP (top, fracture filled). Another 25 cm laminated aragonite-calcite precipitate covers 14.2 ±0.2 to 5.0 ±0.2 kyr. Thus, the precipitates support geologically young and rather short time intervals of infilling and we consider it unlikely that the fractures are much older. An intimate connection with neotectonic activity entailing new vadose water flow routes and fresh reaction surfaces in fractures would be in accordance with our hydrogeochemical and field observations.

Climate and human impacts on vegetation changes in central Guizhou, China: Carbon and oxygen isotopic records in a stalagmite from Yelang Cave

NASA Astrophysics Data System (ADS)

Lee, T.; Liu, Z.; Li, H.; Shen, C.

2009-12-01

High-resolution δ18O and δ13C records of a 13.5-cm long stalagmite from Yelang Cave, 60 km west of Guiyang in the southwestern China, have been established by 750 measurements. With low U (10~40 ppb) and Th (0.01~0.367 ppb), four ICP-MS 230Th/U dates indicate that the upper 5.5 cm part is younger than 1000 years, with clear calcite deposition. Below 6 cm depth where the age suddenly changed from late Holocene to late Pleistocene, the stalagmite shows the deposition alternating between white-pure calcite layers and dark-dirty carbonate layers. The dating samples below 6 cm depth have low U contents (26~41 ppb) but high Th concentrations (10~22 ppb) showing 230Th/U dates ranging from 11 ka to 25 ka with large uncertainties. Based on current chronologies, the δ18O and δ13C records exhibit different features in the late Holocene and late Pleistocene. During the past 1000 yrs (0~5.5 cm), the δ18O ranges from -12.0‰ to -9.0‰ (PDB), containing many 10-100 yrs variations with Δδ18O >1‰. The δ13C during this period varies between -7.4‰ and -1.9‰, showing no correlation with the δ18O. Prior to 10.7 ka (below 6 cm), the δ18O and δ13C strongly co-varied, indicating climatic control on the surface vegetation with wet climates (lighter δ18O) resulting in better vegetation (lighter δ13C). The δ13C during the past 1000 yrs had three long-term increasing trends and a sharp decreasing trend, reflecting human impacts on the surface vegetation. The δ13C increased from about -6‰ at ca. AD 1370 to -3.2‰ around AD 1580, illustrating the first deforestation caused by human activity due to large immigration in Ming Dynasty to the region. The δ13C fluctuated between -4.5‰ and -3.0‰ from AD 1580 to AD 1740, then increased to -2.0‰ around AD 1770 with an opposite δ18O trend. This second deforestation event might be caused a strong immigration in early Qing Dynasty due to mining demand. Karst desertification occurred in the area reflected by heavy δ13C values of -3‰ ~ -2‰ ca. AD 1770 ~ 1900. From AD 1900 to 1910, the δ13C sharply decreased from -2‰ to -7.4‰, perhaps due to planting crops above the cave. After then, the increased δ13C trend reflects the influence of modern human activity.

Age and significance of the Quaternary cemented deposits of the Duje Valley (Picos de Europa, Northern Spain)

NASA Astrophysics Data System (ADS)

Villa, Elisa; Stoll, Heather; Farias, Pedro; Adrados, Luna; Edwards, R. Lawrence; Cheng, Hai

2013-01-01

Cemented calcareous breccias appear in the Picos de Europa (Cantabrian Mountains, Spain) resting on glacially abraded surfaces and covered by moraines. U/Th dating of the calcite coating the clasts was successful in two samples, the oldest one indicating that the breccias accumulated during or prior to Marine Isotope Stage (MIS) 11, and the youngest indicating later cementation during MIS 8. The former introduces a limit for the age of the glaciation preceding the breccias, which cannot correspond to an event younger than MIS 12. This is the oldest absolute age so far obtained for intercalated glacial/interglacial deposits of the Iberian Peninsula.

Palaeoclimate determination from cave calcite deposits

NASA Astrophysics Data System (ADS)

Gascoyne, M.

Calcite deposits formed in limestone caves have been found to be an excellent repository of palaeoclimatic data for terrestrial environments. The very presence of a relict deposit indicates non-glacial conditions at the time of formation, and both 14C and uranium-series methods can be used to date the deposit and, hence, the age of these climatic conditions. Variations in 13C and 18O content of the calcite, in 2H and 18O content of fluid inclusions, in trace element concentrations and, more recently, in pollen assemblages trapped in the calcite, are all potentially available as synchronous palaeoclimatic indicators. Previous work has tended to concentrate mainly on abundance of deposits as a palaeoclimatic indicator for the last 300,000 years. This literature is briefly reviewed here, together with the theory and methods of analysis of the U-series and stable isotopic techniques. The combined use of U-series ages and 13C and 18O variations in cave calcites illustrates the potential for palaeoclimate determination. Previously unpublished results of stable isotopic variations in dated calcites from caves in northern England indicate the level of detail of stable isotopic variations and time resolution that can be obtained, and the complexity of interpretation that may arise. Tentative palaeoclimatic signals for the periods 90-125 ka and 170-300 ka are presented. More comprehensive studies are needed in future work, especially in view of the difficulty in obtaining suitable deposits and the ethics of cave deposits conservation.

Hematite (U-Th)/He thermochronometry constrains intraplate strike-slip faulting on the Kuh-e-Faghan Fault, central Iran

NASA Astrophysics Data System (ADS)

Calzolari, Gabriele; Rossetti, Federico; Ault, Alexis K.; Lucci, Federico; Olivetti, Valerio; Nozaem, Reza

2018-03-01

The Kuh-e-Faghan strike-slip fault system (KFF), located to the northern edge of the Lut Block in central Iran, developed through a Neogene-Quaternary pulsed history of eastward fault propagation and fault-related exhumation. This system is a consequence of the residual stresses transmitted from the Arabia-Eurasia convergent plate boundary. Here we integrate structural and textural analysis with new and previously published apatite fission-track (AFT) and apatite (U-Th)/He (apatite He) results, chlorite thermomentry, and hematite (U-Th)/He data from hematite-coated brittle fault surfaces to constrain the timing of tectonic activity and refine patterns of late Miocene-Pliocene burial and exhumation associated with the propagation of the KFF. Twenty-nine hematite (U-Th)/He (hematite He) dates from three striated hematite coated slip surfaces from the KFF fault core and damage zone yield individual dates from 12-2 Ma. Petrographic analysis and chlorite thermometry of a polyphase, fossil fluid system in the KFF fault core document that fluid circulation and mineralization transitioned from a closed system characterized by pressure solution and calcite growth to an open system characterized by hot hydrothermal (T = 239 ± 10 °C) fluids and hematite formation. Hematite microtextures and grain size analysis reveal primary and secondary syntectonic hematite fabrics, no evidence of hematite comminution and similar hematite He closure temperatures ( 60-85 °C) in each sample. Integration of these results with thermal history modeling of AFT and apatite He data shows that KFF activity in the late Miocene is characterized by an early stage of fault nucleation, fluid circulation, hematite mineralization, and eastward propagation not associated with vertical movement that lasted from 12 to 7 Ma. Hematite He, AFT, and apatite He data track a second phase of fault system activity involving fault-related exhumation initiating at 7 Ma and continuing until present time. Our new data constrain the onset of the recognized Late Miocene-Pliocene tectonic reorganization in north-central Iran.

Advances in Laser Microprobe (U-Th)/He Geochronology

NASA Astrophysics Data System (ADS)

van Soest, M. C.; Monteleone, B. D.; Boyce, J. W.; Hodges, K. V.

2008-12-01

The development of the laser microprobe (U-Th)/He dating method has the potential to overcome many of the limitations that affect conventional (U-Th)/He geochronology. Conventional single- or multi-crystal (U- Th)/He geochronology requires the use of pristine, inclusion-free, euhedral crystals. Furthermore, the ages that are obtained require corrections for the effects of zoning and alpha ejection based on an ensemble of assumptions before interpretation of their geological relevance is possible. With the utilization of microbeam techniques many of the limitations of conventional (U-Th)/He geochronology can either be eliminated by careful spot selection or accounted for by detailed depth profiling analyses of He, U and Th on the same crystal. Combined He, Th, and U depth profiling on the same crystal potentially even offers the ability to extract thermal histories from the analyzed grains. Boyce et al. (2006) first demonstrated the laser microprobe (U-Th)/He dating technique by successfully dating monazite crystals using UV laser ablation to liberate He and determined U and Th concentrations using a Cameca SX-Ultrachron microprobe. At Arizona State University, further development of the microprobe (U-Th)/He dating technique continues using an ArF Excimer laser connected to a GVI Helix Split Flight Tube noble gas mass spectrometer for He analysis and SIMS techniques for U and Th. The Durango apatite age standard has been successfully dated at 30.7 +/- 1.7 Ma (2SD). Work on dating zircons by laser ablation is currently underway, with initial results from Sri Lanka zircon at 437 +/- 14 Ma (2SD) confirmed by conventional (U-Th)/He analysis and in agreement with the published (U-Th)/He age of 443 +/- 9 Ma (2SD) for zircons from this region in Sri Lanka (Nasdala et al., 2004). The results presented here demonstrate the laser microprobe (U-Th)/He method as a powerful tool that allows application of (U- Th)/He dating to areas of research such as detrital apatite and zircon dating, where conventional (U-Th)/He geochronology has limited applicability. Boyce et al. (2006) GCA 70 (3031-3039), Nasdala et al. (2004) Am. Min. 89 (219-231)

U-Pb Dating of Calcite to Constrain Basinal Brine Flux Events: An Example from the Upper Midwest USA

NASA Astrophysics Data System (ADS)

Rasbury, T.; Luczaj, J.

2017-12-01

Calcite forms in a variety of settings and can be the product of surface to deep basinal fluids. As such, this mineral can uniquely record details of the fluids responsible for its formation. The forms of calcium carbonates and their stratigraphic relationships from the thin section to the regional scale give important insights on pulses of fluids. A fundamental question is the age of such fluid pulses. While calcite excludes uranium (U) from its crystal structure, some is incorporated and depending on the U/Pb ratio, this provides an opportunity for radiometric dating. Calcite crystals of various sizes and crystal habits are found in Paleozoic carbonate rocks throughout the region from the western Michigan basin to the upper Mississippi valley. These are typically associated with Mississippi Valley-type (MVT) mineralization, including galena, sphalerite, and iron sulfides, but typically post-date the main MVT event. We have analyzed a variety of these calcites and find multiple generations of calcite, separated by tens of millions of years. The initial Pb isotope ratios are similar to the isotope ratios of nearby galena, strongly suggesting a genetic relationship. Our oldest ages are 200 Ma, and we find ages ranging into the Cenozoic. Based on the Paleozoic-hosted galena Pb-isotope isoscapes from the region, the fluids may have been sourced from both the Michigan and Illinois basins. An important and unanswered question is what would cause significant fluid movement out of the basins substantially after Appalachian orogenesis. Noble gas data from brines in the Michigan Basin have a mantle component and have been suggested to be responsible for recognized elevated temperatures across the basin (Ma et al., 2009). Multiple thermal events during the Paleozoic and Mesozoic eras may have an internal heat source related to reactivation of faults of the Keweenawan Rift system below the Michigan Basin. Perhaps a mantle heat source from below episodically fluxes into the basins and displaces brines with important ore metals out of the basin. More work on the calcites will help to establish the geographic extent of the various fluid pulses in the region, which will lead to an improved understanding of the sources and paths of these fluids.

Calcite veining and feeding conduits in a hydrothermal system: Insights from a natural section across the Pleistocene Gölemezli travertine depositional system (western Anatolia, Turkey)

NASA Astrophysics Data System (ADS)

Capezzuoli, Enrico; Ruggieri, Giovanni; Rimondi, Valentina; Brogi, Andrea; Liotta, Domenico; Alçiçek, Mehmet Cihat; Alçiçek, Hülya; Bülbül, Ali; Gandin, Anna; Meccheri, Marco; Shen, Chuan-Chou; Baykara, Mehmet Oruç

2018-02-01

Linking the architecture of structural conduits with the hydrothermal fluids migrating from the reservoir up to the surface is a key-factor in geothermal research. A contribution to this achievement derives from the study of spring-related travertine deposits, but although travertine depositional systems occur widely, their feeding conduits are only rarely exposed. The integrated study carried out in the geothermal Gölemezli area, nearby the well-known Pamukkale area (Denizli Basin, western Anatolia, Turkey), focused on onyx-like calcite veins (banded travertine) and bedded travertine well exposed in a natural cross-section allowing the reconstruction of the shallower part of a geothermal system. The onyx-like veins represent the thickest vein network (> 150 m) so far known. New field mapping and structural/kinematic analyses allowed to document a partially dismantled travertine complex (bedded travertine) formed by proximal fissure ridges and distal terraced/pools depositional systems. The banded calcite veins, WNW-trending and up to 12 m thick, developed within a > 200 m thick damaged rock volume produced by parallel fault zones. Th/U dating indicates a long lasting (middle-late Pleistocene) fluids circulation in a palaeo-geothermal system that, due to its location and chemical characteristics, can be considered the analogue of the nearby, still active, Pamukkale system. The isotopic characteristics of the calcite veins together with data from fluid inclusions analyses, allow the reconstruction of some properties (i.e. temperature, salinity and isotopic composition) and processes (i.e. temperature variation and intensity of degassing) that characterized the parent fluids and the relation between degassing intensity and specific microfabric of calcite crystals (elongated/microsparite-micrite bands), controlled by changes/fluctuations of the physico-chemical fluid characteristics.

Geochemical gradients within modern and fossil shells of Concholepas concholepas from northern Chile: an insight into U-Th systematics and diagenetic/authigenic isotopic imprints in mollusk shells

NASA Astrophysics Data System (ADS)

Labonne, Maylis; Hillaire-Marcel, Claude

2000-05-01

Seriate geochemical measurements through shells of one modern, one Holocene, and two Sangamonian Concholepas concholepas, from marine terraces of Northern Chile, were performed to document diagenetic vs. authigenic geochemical signatures, and to better interpret U-series ages on such material. Subsamples were recovered by drilling from the outer calcitic layer to the inner aragonitic layer of each of the studied shells. Unfortunately, this sampling procedure induces artifacts, notably the convertion of up to ˜20% of calcite into aragonite, and of up to ˜6% of aragonite into calcite, as well as in the epimerization of a few percent of isoleucine into D-alloisoleucine/ L-isoleucine. Negligible sampling artifacts were noticed for stable isotope and total amino acid contents. Diagenetic effects on the geochemical properties of the shells are particularly pronounced in the inner aragonitic layer and more discrete in the outer calcitic layer. The time-dependent decay of the organic matrix of the shell is illustrated by a one order of magnitude lower total amino acid content in the Sangamonian specimens by comparison with the modern shell. Conversely, the Sangamonian shells U contents increase by a similar factor and 13C- 18O enrichments as high as 2 to 3‰ seem also to occur through the same time interval possibly due to partial replacement of aragonite by gypsum. The decay of the organic matrix of the aragonitic layer of the shell is thought to play a major role with respect to U-uptake processes and stable isotope shifts. Nevertheless, asymptotic 230Th-ages (˜100 ka) in the inner U-rich layers of the Sangamonian shells, and 234U/ 238U ratios compatible with a marine origin for U, suggest U-uptake within a short diagenetic interval, when marine waters were still bathing the embedding sediment. Thus, U-series ages on fossil mollusks from such a hyper-arid environment should not differ much from the age of the corresponding marine unit deposition. However, the diagenetic enrichments in stable isotopes raise concerns about their use for paleoenvironmental reconstructions under such climate conditions.

Sea-level history and tectonic uplift during the last-interglacial period (LIG): Inferred from the Bab al-Mandab coral reef terraces, southern Red Sea

NASA Astrophysics Data System (ADS)

Al-Mikhlafi, Ahmed Saif; Edwards, Lawrence R.; Cheng, Hai

2018-02-01

Results of U-series dating of late Pleistocene raised coral reef terraces from the Bab al-Mandab area, define two distinct groups: (1) well-preserved aragonitic fossil corals recorded from the Al-Hajaja terrace (Tr3) yield ages for last-interglacial period (LIG); and (2) calcitic fossil corals recovered from Perim Island terrace (Tr1) show varying degrees of U-series open system behavior and yield coral assemblage ages of LIG and older ages. Fossil corals from Tr1 are recrystallized corals, have anomalously high initial δ234U ranged from (152 ± 2‰ to 287 ± 7‰), corresponding to ages of ∼120 ka and ∼406 ka, respectively. Applying age reliability criteria on the current data suggest majority of the ages cannot be considered reliable and all are suspected for open system behavior associated with U loss/addition that significantly affects the 230Th/U ages. The diagenesis shown by these corals occurred probably due to extensive interaction of fossil corals with freshwater during the wet periods prevailed in southern Arabia coeval with the African monsoon, which led to U loss. Post-depositional U loss suggest (230Th/238U) increase, which shift the U-Th ages to unexpectedly higher levels as it is shown here. Measured elevation at the Al-Hajaja terrace (Tr3) is ∼4 ± 2 m above present sea level (apsl) consistent with eustatic sea level changes and indicates that the Bab al-Mandab area is stable at least since the LIG period. The Perim Island terrace (Tr1) is at elevation of 7 ± 2 m apsl; its reef yields diageneticaly-altered corals of multiple ages and cannot be used for sea level reconstructions.

Coupling of Uranium and Thorium Series Isotope Systematics for Age Determination of Late Pleistocene Zircons using LA-ICP-MS

NASA Astrophysics Data System (ADS)

Sakata, S.; Hirakawa, S.; Iwano, H.; Danhara, T.; Hirata, T.

2014-12-01

Zircon U-Th-Pb dating method is one of the most important tools for estimating the duration of magmatism by means of coupling of uranium, actinium and thorium decay series. Using U-Pb dating method, its reliability is principally guaranteed by the concordance between 238U-206Pb and 235U-207Pb ages. In case of dating Quaternary zircons, however, the initial disequilibrium effect on 230Th and 231Pa should be considered. On the other hands, 232Th-208Pb dating method can be a simple but powerful approach for investigating the age of crystallization because of negligible influence from initial disequilibrium effect. We have developed a new correction model for accurate U-Pb dating of the young zircon samples by taking into consideration of initial disequilibrium and a U-Pb vs Th-Pb concordia diagram for reliable age calibration was successfully established. Hence, the U-Th-Pb dating method can be applied to various zircons ranging from Hadean (4,600 Ma) to Quaternary (~50 ka) ages, and this suggests that further detailed information concerning the thermal history of the geological sequences can be made by the coupling of U-Th-Pb, fission track and Ar-Ar ages. In this presentation, we will show an example of U-Th-Pb dating for zircon samples from Sambe Volcano (3 to 100 ka), southwest Japan and the present dating technique using LA-ICP-MS.

Empirical constraints on the effects of radiation damage on helium diffusion in zircon

NASA Astrophysics Data System (ADS)

Anderson, Alyssa J.; Hodges, Kip V.; van Soest, Matthijs C.

2017-12-01

In this study, we empirically evaluate the impact of radiation damage on zircon (U-Th)/He closure temperatures for a suite of zircon crystals from the slowly cooled McClure Mountain syenite of south-central Colorado, USA. We present new zircon, titanite, and apatite conventional (U-Th)/He dates, zircon laser ablation (U-Th)/He and U-Pb dates, and zircon Raman spectra for crystals from the syenite. Titanite and apatite (U-Th)/He dates range from 447 to 523 Ma and 88.0 to 138.9 Ma, respectively, and display no clear correlation between (U-Th)/He date and effective uranium concentration. Conventional zircon (U-Th)/He dates range from 230.3 to 474 Ma, while laser ablation zircon (U-Th)/He dates show even greater dispersion, ranging from 5.31 to 520 Ma. Dates from both zircon (U-Th)/He datasets decrease with increasing alpha dose, indicating that most of the dispersion can be attributed to radiation damage. Alpha dose values for the dated zircon crystals range from effectively zero to 2.15 × 1019 α /g, spanning the complete damage spectrum. We use an independently constrained thermal model to empirically assign a closure temperature to each dated zircon grain. If we assume that this thermal model is robust, the zircon radiation damage accumulation and annealing model of Guenthner et al. (2013) does not accurately predict closure temperatures for many of the analyzed zircon crystals. Raman maps of the zircons dated by laser ablation document complex radiation damage zoning, sometimes revealing crystalline zones in grains with alpha dose values suggestive of amorphous material. Such zoning likely resulted in heterogeneous intra-crystalline helium diffusion and may help explain some of the discrepancies between our empirical findings and the Guenthner et al. (2013) model predictions. Because U-Th zoning is a common feature in zircon, radiation damage zoning is likely to be a concern for most ancient, slowly cooled zircon (U-Th)/He datasets. Whenever possible, multiple mineral-isotopic systems should be employed to add additional, independent constraints to a sample's thermal history.

Formation of the world's largest REE deposit through protracted fluxing of carbonatite by subduction-derived fluids

PubMed Central

Ling, Ming-Xing; Liu, Yu-Long; Williams, Ian S.; Teng, Fang-Zhen; Yang, Xiao-Yong; Ding, Xing; Wei, Gang-Jian; Xie, Lu-Hua; Deng, Wen-Feng; Sun, Wei-Dong

2013-01-01

Rare Earth Elements (REE) are essential to modern society but the origins of many large REE deposits remain unclear. The U-Th-Pb ages, chemical compositions and C, O and Mg isotopic compositions of Bayan Obo, the world's largest REE deposit, indicate a protracted mineralisation history with unusual chemical and isotopic features. Coexisting calcite and dolomite are in O isotope disequilibrium; some calcitic carbonatite samples show highly varied δ26Mg which increases with increasing Si and Mg; and ankerite crystals show decreases in Fe and REE from rim to centre, with highly varied REE patterns. These and many other observations are consistent with an unusual mineralisation process not previously considered; protracted fluxing of calcitic carbonatite by subduction-released high-Si fluids during the closure of the Palaeo-Asian Ocean. The fluids leached Fe and Mg from the mantle wedge and scavenged REE, Nb and Th from carbonatite, forming the deposit through metasomatism of overlying sedimentary carbonate.

DEMONSTRATING SLOW GROWTH RATES IN OPAL FROM Y.M.,NV, USING MICRODIGESTION AND ION-PROBE URANIUM-SERIES DATING

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. PACES; L. NEYMARK; H. PERSING

Thinly laminated (<0.01 mm) opal sheets and globules associated with calcite in fractures and cavities in the unsaturated zone at Yucca Mountain, Nevada, have U concentrations of 50 to 300 ppm. Previous uranium-series thermal ionization mass spectrometry (TIMS) analyses of 0.2- to 1-mm-thick subsamples resulted in a model of slow mineral growth at rates of 0.5 to 5 mm/m.y. To test this growth model using finer sampling resolution, in situ microdigestions were performed by applying a drop of hydrofluoric acid directly to opal surfaces within a small area encircled by jeweler's wax. After several minutes, the liquid was removed, spikedmore » with a tracer solution, and analyzed by TIMS for both U and Th using a single rhenium filament with colloidal graphite. Solutions contained about 0.5 nanograms of U, equivalent to opal weights of 1 to 10 micrograms and dissolved-layer thicknesses less than 0.003 mm. Microdigested opal surfaces have Th-230/U ages of 5 to 10 thousand years (ka) in contrast to much older ages of 150 to 250 ka obtained previously from whole-globule digestions. Additional tests of the growth model were made on cross sections of identical opal globules using the sensitive high-resolution ion microprobe (SHRIMP) with a 0.04-mm-diameter O-minus primary beam. Counting rates for Tho-246 and U-234 varied between 5 and 70 counts per second with Th-230/Th-232 activity ratios typically much greater than a million. The Th-230/U ages in the outer 0.3 mm of the globules ranged from about 30 ka at the outer edge to 400 ka at depth. Ages correlate with microstratigraphic depths and indicate average growth rates between 0.5 and 0.7 mm/m.y. Current U-series data do not resolve differential growth rates related to climate changes during this time period. However, both microdigestion and SHRIMP results confirm the previous TIMS-based model of slow, uniform rates of mineral growth in a hydrologically stable environment.« less

Distribution of naturally occurring radionuclides (U, Th) in Timahdit black shale (Morocco).

PubMed

Galindo, C; Mougin, L; Fakhi, S; Nourreddine, A; Lamghari, A; Hannache, H

2007-01-01

Attention has been focused recently on the use of Moroccan black oil shale as the raw material for production of a new type of adsorbent and its application to U and Th removal from contaminated wastewaters. The purpose of the present work is to provide a better understanding of the composition and structure of this shale and to determine its natural content in uranium and thorium. A black shale collected from Timahdit (Morocco) was analyzed by powder X-ray diffraction and SEM techniques. It was found that calcite, dolomite, quartz and clays constitute the main composition of the inorganic matrix. Pyrite crystals are also present. A selective leaching procedure, followed by radiochemical purification and alpha-counting, was performed to assess the distribution of naturally occurring radionuclides. Leaching results indicate that 238U, 235U, 234U, 232Th, 230Th and 228Th have multiple modes of occurrence in the shale. U is interpreted to have been concentrated under anaerobic conditions. An integrated isotopic approach showed the preferential mobilization of uranium carried by humic acids to carbonate and apatite phases. Th is partitioned between silicate minerals and pyrite.

From Texas to the Northwest Territories: Low temperature history of the North American craton using a radiation damage model for apatite He diffusion

NASA Astrophysics Data System (ADS)

Flowers, R. M.; Ault, A. K.; Wolin, E.; Kelley, S.; Bowring, S. A.

2009-12-01

The radiation damage accumulation and annealing model (RDAAM) for apatite He diffusion helps resolve previously enigmatic characteristics of apatite (U-Th)/He data in cratonic regions. First, nonlinear positive date-eU correlations are predicted for many T-t paths, thus explaining excessive scatter in some (U-Th)/He datasets. Second, under common circumstances, the RDAAM predicts (U-Th)/He dates that are older than corresponding apatite fission-track (AFT) dates, helping reconcile previous data in which (U-Th)/He dates were older than expected using Durango He diffusion kinetics. We present five apatite (U-Th)/He datasets, three with co-existing AFT data, from the North American craton that can quantitatively be explained by the RDAAM. These datasets include three from the Canadian shield (Trans-Hudson Orogen, Lake Athabasca region, Slave Craton) and two from the U.S. midcontinent (Kansas, Texas panhandle). All samples are Precambrian (4.0-1.6 Ga) basement, except for Triassic-Jurassic sandstones analyzed in the Texas study. We use the results of these studies to evaluate broad thermal history patterns across the North American craton. Although each dataset yields a distinct thermal history, all can be accounted for by varying the magnitudes of two well-documented episodes of burial and unroofing in Paleozoic-Mesozoic and Cretaceous-Tertiary times. The oldest consistent (U-Th)/He and AFT dates of these studies are early Paleozoic and are preserved in the Trans-Hudson Orogen. Together with a strong (U-Th)/He date-eU correlation and dates as young as Jurassic in the Lake Athabasca region, as well as widespread Permo-Triassic dates from the Slave craton, the three Canadian shield datasets are most simply explained by increased magnitudes of burial toward the northwest in Paleozoic-Mesozoic time, with less significant burial in the Cretaceous. In contrast, (U-Th)/He data from Kansas yield a date-eU correlation and a cluster of Cretaceous dates, (U-Th)/He dates from the Texas panhandle are Cretaceous-Tertiary, and AFT dates from both areas are Permo-Triassic. Thus, the U.S. midcontinent datasets preserve a significant Cretaceous-Tertiary signal, requiring more substantial burial and unroofing during this time than the Canadian results. These younger dates in Texas and Kansas are likely related to flat slab evolution beneath the western U.S. in Cretaceous-Tertiary time, while the absence of this strong signal in the Canadian shield data is consistent with the lack of a flat slab beneath that region. The NW-SE trend in Paleozoic-Mesozoic thermal histories in the Canadian shield may be related to earlier spatial variability in plate margin subduction processes. The ability of the RDAAM to account for otherwise inexplicable aspects of the data presented here suggests that we can now reliably couple (U-Th)/He and AFT techniques to decipher low temperature cratonic histories in unprecedented detail, permitting insight into how cratons respond to external tectonic forces in the billions of years following their stabilization.

Corrosion Protection by Calcite-Type Coatings

DTIC Science & Technology

1989-10-01

CORROSION PROTECTION BY CALCITE -TYPE COATINGS OCTOBER, 1989 Prepared by: OCEAN CITY RESEARCH CORPORATION Tennessee Avenue & Beach Thorofare Ocean...REPORT DATE OCT 1989 2. REPORT TYPE N/A 3. DATES COVERED - 4. TITLE AND SUBTITLE Corrosion Protection by Calcite -Type Coatings 5a. CONTRACT... calcite -type coatings to segregated seawater ballast tanks. If perfected, a calcite coating approach could substantially reduce the cost of corrosion

Matrix effects for elemental fractionation within ICPMS: applications for U-Th-Pb geochronology

NASA Astrophysics Data System (ADS)

Chen, W.

2016-12-01

Recent development in instruments provides significant technical supports for daily, quick, money saving geochemical analyses. Laser ablation ICPMS stands out due to these reasons, especially for the U-Th-Pb isotopic dating. Matrix-matched external standardization is by far the most common approach used in U-Th-Pb dating via LA-ICPMS. However, matrix-effects between standard and sample for in-situ dating have shown to be both significant and insignificant. It remains mysterious whether a well matrix-matched standard is needed for U-Th-Pb dating by LA-ICPMS. This study provides an experimental framework for the understanding of matrix effects induced elemental fractionation for U-Th-Pb associated with ICPMS. A preliminary study on the influence of varied U, Th and Pb amounts on their fractionations has been carried out. Experimental data show that different U, Th and Pb contents result in varied 238U/206Pb and 232Th/208Pb ratios. The fractionations of U/Pb and Th/Pb increase with the increasing contents (1 ppb to 100 ppb) with a strong positive anomaly at 10 ppb. Matrixes representing minerals frequently used in dating have been investigated for the influences on U/Pb and Th/Pb fractionations, which suggest a complicated effect. Little fractionations observed between mineral pairs (e.g., monazite and apatite; zircon and perovskite; rutile and perovskite; xenotime and baddeleyite), whereas large fractionations identified for other minerals (e.g., zircon and baddeleyite; monazite and sphene; rutile and baddeleyite). Single element matrix (i.e., Si, P, Ca, Zr, Ti) has been studied to identify their effects on the fractionations. U/Pb ratio increases with the increasing Si and P contents, whereas it decreases for Zr, Ca and Ti. Th/Pb ratio increases with increasing Si contents, decreases for P and Zr, and increases first then decreases for Ca and Ti. Above all, different matrix and U, Th and Pb amounts show distinct U/Pb and Th/Pb fractionations within ICPMS. The minerals with matrix indicating similar fractionations in ICPMS can be used as suitable reference standards for each other with proper laser ablation settings via LA-ICPMS. Moreover, matched U, Th and Pb contents should be considered when using a matrix-matched standard in laser ablation analysis.

Reply to Comment on "Zircon U-Th-Pb dating using LA-ICP-MS: Simultaneous U-Pb and U-Th dating on the 0.1 Ma Toya Tephra, Japan"

NASA Astrophysics Data System (ADS)

Ito, Hisatoshi

2015-04-01

Guillong et al. (2015) mentioned that corrections for abundance sensitivity for 232Th and molecular zirconium sesquioxide ions (Zr2O3+) are critical for reliable determination of 230Th abundances in zircon for LA-ICP-MS analyses. There is no denying that more rigorous treatments are necessary to obtain more reliable ages than those in Ito (2014). However, as shown in Fig. 2 in Guillong et al. (2015), the uncorrected (230Th)/(238U) for reference zircons except for Mud Tank are only 5-20% higher than unity. Since U abundance of Toya Tephra zircons that have U-Pb ages < 1 Ma is in-between that of FCT and Plesovice, the overestimation of 230Th by both abundance sensitivity and molecular interferences is expected to be 5-20% for the Toya Tephra. Moreover Ito (2014) obtained U-Th ages of the Toya Tephra by comparison with Fish Canyon Tuff (FCT) data. Because both the FCT and the Toya Tephra have similar trends of overestimation of 230Th, the effect of overestimation of 230Th to cause overestimation of U-Th age should be cancelled out or negligible. Therefore the pivotal conclusion in Ito (2014) that simultaneous U-Pb and U-Th dating using LA-ICP-MS is possible and useful for Quaternary zircons holds true.

Sharpening the U-Th Chronometer: Progress and Outlook

NASA Astrophysics Data System (ADS)

McLean, N. M.; Condon, D. J.; Henderson, G. M.; Richards, D. A.; Noble, S.; Mason, A.

2013-12-01

Uranium is incorporated into a variety of natural materials when they form, including carbonates like speleothems and corals. The two most abundant naturally occurring uranium isotopes, 238U and 235U, decay to 206Pb and 207Pb over long timescales with half-lives of 4.5 and 0.7 billion years respectively, but transition through several intermediate daughter isotopes with shorter half-lives first. Fractionation between these daughter isotopes, including 234U, 230Th, and 231Pa, and their parent isotopes, followed by their time-dependent return to secular equilibrium over the course of up to ~800 kyr, forms the basis for U-series geochronology, and allows speleothems and corals to be precisely dated. These carbonates often additionally incorporate chemical and isotopic signatures (e.g., trace elements, δ18O and δ13C) from the environment in which they form, and thus are some of the best dated paleoclimate archives, offering clues about past and future conditions for life on Earth. Over the past decade, the analytical precision of U-series isotope measurements has improved dramatically, largely due to the steadily increasing sensitivity of multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). Analytical uncertainties in U-Th dates now approach or are better than 0.1% (2σ), for instance ×100 years for a speleothem or coral that is 130 kyr old (Cheng et al., 2013). However, the accuracy of U-series dates also depends on the accuracy of tracer calibrations, reference solutions and data reduction protocols, which has not kept pace in many laboratories. This means that dates measured in different labs, while impressively precise, may not be directly comparable. To address issues of inter-laboratory bias and improve the accuracy and inter-comparability of U-Th dates, we have instigated work in three related directions. First, we report on the mixing of three synthetic U-Th age solutions, created by combining high-purity mono-isotopic solutions to mimic the isotopic composition of commonly analyzed materials. These age solutions will form the basis for an inter-laboratory comparison and serve as international reference materials for assessing long-term reproducibility. Second is the creation of several U-Th gravimetric solutions, which can be used to calibrate the mixed 229Th-236U×233U tracers used in the community without having to rely on materials assumed to be in secular equilibrium. Tracers calibrated against these solutions, and therefore U-Th dates measured with these tracers, will be fully metrologically traceable. Finally, we report progress on and important considerations in developing data reduction and uncertainty propagation protocols for calculating U-Th dates and constructing and interpreting U-Th age models. Reference: Cheng et al. (2013) EPSL 371-372, 82-91

Time-Series Radiocarbon Measurements Indicate Carbon Turnover Across Soil Fractions is Correlated With Productivity in a Long-Term Agricultural Experiment

NASA Astrophysics Data System (ADS)

Sanderman, J.; Baisden, W. T.; Creamer, C.; Farrell, M.; Fallon, S.

2016-12-01

Carbonatites and alkaline intrusions are important sources of REEs. Environmental risks related to these deposit types have been assessed through literature review and evaluation of the geochemical properties of representative samples of mill tailings and their leachates. The main ore mineral in carbonatite deposits is bastnasite [(Ce,La)(CO3)F], which is found with dolomite and calcite ( 65 %), barite (20 - 25 %), plus a number of minor accessory minerals including sulfides such as galena and pyrite. Generally, alkaline intrusion-related REE deposits either occur in layered complexes or with dikes and veins cutting alkaline intrusions. Such intrusions have a more diverse group of REE ore minerals that include fluorcarbonates, oxides, silicates, and phosphates. Ore also can include minor calcite and iron (Fe), lead (Pb), and zinc (Zn) sulfides. The acid-generating potential of both deposit types is low because of a predominance of carbonate minerals in the carbonatite deposits, the presence of feldspars and minor calcite in alkaline intrusion-related deposits, and to only minor to trace occurrence of potentially acid-generating sulfide minerals. Both deposit types, however, are produced by igneous and hydrothermal processes that enrich high-field strength, incompatible elements, which typically are excluded from common rock-forming minerals. Elements such as yttrium (Y), niobium Nb), zirconium (Zr), hafnium (Hf), tungsten (W), titanium (Ti), tantalum (Ta), scandium (Sc), thorium (Th), and uranium (U) can be characteristic of these deposits and may be of environmental concern. Most of these elements, including the REEs, but with the exception of U, have low solubilities in water at the near-neutral pH values expected around these deposits. Mill tailings from carbonatite deposits can exceed residential soil and sediment criteria for Pb, and leachates from mill tailings can exceed drinking water guidelines for Pb. The greatest environmental challenges, however, are linked to the presence of Th and U, although mineral hosts for these elements are moderately unreactive in the environment. Both deposit types can have mill tailings that exceed residential soil criteria for U. Uranium can be recovered as a byproduct to mitigate its environmental effects, but Th remains a waste product that requires management.

Environmental Characteristics of Carbonatite and Alkaline Intrusion-related Rare Earth Element (REE) Deposits

NASA Astrophysics Data System (ADS)

Seal, R. R., II; Piatak, N. M.

2017-12-01

Carbonatites and alkaline intrusions are important sources of REEs. Environmental risks related to these deposit types have been assessed through literature review and evaluation of the geochemical properties of representative samples of mill tailings and their leachates. The main ore mineral in carbonatite deposits is bastnasite [(Ce,La)(CO3)F], which is found with dolomite and calcite ( 65 %), barite (20 - 25 %), plus a number of minor accessory minerals including sulfides such as galena and pyrite. Generally, alkaline intrusion-related REE deposits either occur in layered complexes or with dikes and veins cutting alkaline intrusions. Such intrusions have a more diverse group of REE ore minerals that include fluorcarbonates, oxides, silicates, and phosphates. Ore also can include minor calcite and iron (Fe), lead (Pb), and zinc (Zn) sulfides. The acid-generating potential of both deposit types is low because of a predominance of carbonate minerals in the carbonatite deposits, the presence of feldspars and minor calcite in alkaline intrusion-related deposits, and to only minor to trace occurrence of potentially acid-generating sulfide minerals. Both deposit types, however, are produced by igneous and hydrothermal processes that enrich high-field strength, incompatible elements, which typically are excluded from common rock-forming minerals. Elements such as yttrium (Y), niobium Nb), zirconium (Zr), hafnium (Hf), tungsten (W), titanium (Ti), tantalum (Ta), scandium (Sc), thorium (Th), and uranium (U) can be characteristic of these deposits and may be of environmental concern. Most of these elements, including the REEs, but with the exception of U, have low solubilities in water at the near-neutral pH values expected around these deposits. Mill tailings from carbonatite deposits can exceed residential soil and sediment criteria for Pb, and leachates from mill tailings can exceed drinking water guidelines for Pb. The greatest environmental challenges, however, are linked to the presence of Th and U, although mineral hosts for these elements are moderately unreactive in the environment. Both deposit types can have mill tailings that exceed residential soil criteria for U. Uranium can be recovered as a byproduct to mitigate its environmental effects, but Th remains a waste product that requires management.

238U-230Th dating of chevkinite in high-silica rhyolites from La Primavera and Yellowstone calderas

USGS Publications Warehouse

Vazquez, Jorge A.; Velasco, Noel O.; Schmitt, Axel K.; Bleick, Heather A.; Stelten, Mark E.

2014-01-01

Application of 238U-230Th disequilibrium dating of accessory minerals with contrasting stabilities and compositions can provide a unique perspective on magmatic evolution by placing the thermochemical evolution of magma within the framework of absolute time. Chevkinite, a Th-rich accessory mineral that occurs in peralkaline and metaluminous rhyolites, may be particularly useful as a chronometer of crystallization and differentiation because its composition may reflect the chemical changes of its host melt. Ion microprobe 128U-230Th dating of single chevkinite microphenocrysts from pre- and post-caldera La Primavera, Mexico, rhyolites yields model crystallization ages that are within 10's of k.y. of their corresponding K-Ar ages of ca. 125 ka to 85 ka, while chevkinite microphenocrysts from a post-caldera Yellowstone, USA, rhyolite yield a range of ages from ca. 110 ka to 250 ka, which is indistinguishable from the age distribution of coexisting zircon. Internal chevkinite-zircon isochrons from La Primavera yield Pleistocene ages with ~5% precision due to the nearly two order difference in Th/U between both minerals. Coupling chevkinite 238U-230Th ages and compositional analyses reveals a secular trend of Th/U and rare earth elements recorded in Yellowstone rhyolite, likely reflecting progressive compositional evolution of host magma. The relatively short timescale between chevkinite-zircon crystallization and eruption suggests that crystal-poor rhyolites at La Primavera were erupted shortly after differentiation and/or reheating. These results indicate that 238U-230Th dating of chevkinite via ion microprobe analysis may be used to date crystallization and chemical evolution of silicic magmas.

Calcite precipitation on glass substrates and active stalagmites in Katerloch Cave (Austria): Constraints from environmental monitoring

NASA Astrophysics Data System (ADS)

Sakoparnig, Marlene; Boch, Ronny; Wang, Xianfeng; Lin, Ke; Spötl, Christoph; Leis, Albrecht; Gollowitsch, Anna; Dietzel, Martin

2016-04-01

Located near Graz at the SE-rim of the Alps Katerloch is well-known for its impressive dripstone decoration, e.g. several metres tall and relatively fast growing (0.2-0.7 mm/yr on average) candle-stick-type stalagmites. In the course of an ongoing multi-annual and partially high-resolution cave monitoring program we study modern (active) sites of carbonate deposition focusing on the site-specific growth dynamics and connection of modern regional and cave environmental conditions with petrographic, chemical and stable isotopic information captured in the speleothems. Fresh calcite precipitates on artificial (glass) substrates underneath active drip sites were collected continuously from 2006 to 2014 (eight years!). The samples (up to 7 mm thick) represent cave sections of different temperature and drip sites of partially different characteristics (e.g. drip rate). We also recovered short drill cores (up to 3 cm length, 1 cm diameter) from the top of active stalagmites probably representing the last decades to centuries of calcite crystallization. Moreover, an actively growing stalagmite (K10) comprising both modern and past calcite deposition was collected. 238U-234U-230Th dating using MC-ICP-MS of K10 (71 cm long) revealed several distinct growth intervals (separated by growth interruptions) starting at 129.1 ±1.2 kyr BP (Last Interglacial) up to now, mostly reflecting warm and humid climate intervals. High-resolution (100 μm) isotope profiles micromilled from the multi-annual modern calcite precipitates on artificial substrates revealed low δ13C values of -12.8 to -8.3 ‰ (VPDB) and relatively high δ18O of -6.9 to -4.9 ‰Ṫhe δ18O curves from all collection sites (different growth rate) record a pronounced decrease during their most recent growth period most likely corresponding to a significant decrease towards lower oxygen isotope values observed in drip waters collected in the year 2014 compared with samples from 2005 to 2007. Drip water δ2H /δ18O values plot between the Western Mediterranean Meteoric Water Line and Global MWL indicating a significant contribution of Mediterranean moisture to regional precipitation. The prominent shifts could also be explained by changes in seasonality of precipitation and water infiltration. Geochemical and petrographic results from the modern stalagmite calcite are therefore compared to new and published (Boch et al., 2011) hydrochemical and cave air data, as well as regional meteorological data. The modern datasets are further compared to data from Katerloch stalagmites of older time intervals. BOCH, R., SPÖTL, C., FRISIA, S. (2011): Sedimentology, 58, 508-531

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

NASA Astrophysics Data System (ADS)

Ludwig, K. R.; Paces, J. B.

2002-02-01

A 230Th-234U-238U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the 232Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for 230Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the 230Th/U ages were preserved in all cases; (2) back-calculated initial 234U/238U fall in a restricted range (typically 1.67±0.19), so that 234U/238U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt 230Th/U ages. We conclude that 230Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of 238U/232Th, or isochrons.

Connecting the U-Th and U-Pb Chronometers: New Algorithms and Applications

NASA Astrophysics Data System (ADS)

McLean, N. M.; Smith, C. J. M.; Roberts, N. M. W.; Richards, D. A.

2016-12-01

The U-Th and U-Pb geochronometers are important clocks for separate intervals of the geologic timescale. U-Th dates exploit disequilibrium in the 238U intermediate daughter isotopes 234U and 230Th, and are often used to date corals and speleothems that are zero age through 800 ka. The U-Pb system relies on secular equilibrium decay of 238U to 206Pb and 235U to 207Pb over longer timescales, and can be used to date samples from <1 Ma to 4.5 Ga. Disequilibrium plays a role in young U-Pb dates, but only as a nuisance correction. Both chronometers can produce dates with uncertainties <0.1% near the center of their applicable age ranges, but become less precise at their intersection, when the 238U decay chain approaches secular equilibrium and there has been little time for ingrowth of radiogenic Pb. However, if measurements or assumptions about both chronometers can be made, then they can be combined into a single, more informed date. Coupling the datasets can improve their precision and accuracy and help interrogate the assumptions that underpin each. Working with this data is difficult for two reasons. The Bateman equations are long and cumbersome for U decay chains that include 238U, 234U, 230Th, 226Ra, 206Pb and 235U, 231Pa, and 207Pb. Also, Pb measurements often comprise varying amounts of radiogenic Pb from locally heterogeneous U concentrations mixed with varying amounts of common Pb. At present there is no established, flexible computational framework to combine information from measurements and/or assumptions of these parameters, and no way to visualize and interpret the results. We present new algorithms to quickly and accurately solve the system of differential equations defined by both of the uranium decay chains and the linear regression through the U-Pb isochron. The results are illustrated on a new concordia diagram, where the concordia curve is determined by measured and/or assumed U-series disequilibrium and can have unfamiliar topologies. We demonstrate this approach using data collected by solution and laser ablation ICPMS on carbonates with measurable 230Th and 234U disequilibrium, measurable disequilibrium for only 234U, and when only assumptions can be made about initial U-series disequilibrium. Potential applications include refining chronologies at ca. 1 Ma, an important period in Earth history.

Prospects for Practical Laser Ablation U/Pb and (U-Th)/He Double-Dating (LADD) of Detrital Apatite

NASA Astrophysics Data System (ADS)

Horne, A.; Hodges, K. V.; Van Soest, M. C.

2017-12-01

A laser ablation micro-analytical technique for (U-Th)/He dating has been shown to be an effective approach to the thermochronologic study of detrital zircons (Tripathy-Lang et al., J. Geophys. Res., 2013), while Evans et al. (J. Anal. At. Spectrom., 2015) and Horne et al. (Geochim. Cosmochim. Acta, 2016) demonstrated how the technique could be modified to enable laser ablation U/Pb and (U-Th)/He double-dating (LADD) of detrital zircon and titanite. These successes beg the question of whether or not LADD is viable for another commonly encountered detrital mineral: apatite. Exploratory LADD studies in Arizona State University's Group 18 Laboratories - using Durango fluorapatite, apatite from the Fish Canyon tuff, and detrital apatite from modern fluvial sediments in the eastern Sierra Nevada of California - illustrate that the method is indeed viable for detrital apatite. However, the method may not be appropriate for all detrital samples. For example, many apatite grains encountered in detrital samples from young orogenic settings have low concentrations of U and Th and small crystal sizes. This can lead to imprecise laser ablation (U-Th)/He dates, especially for very young grains potentially obscuring or inhibiting relevant interpretations of the data set.

Improved spatial resolution for U-series dating of opal at Yucca Mountain, Nevada, USA, using ion-microprobe and microdigestion methods

USGS Publications Warehouse

Paces, J.B.; Neymark, L.A.; Wooden, J.L.; Persing, H.M.

2004-01-01

Two novel methods of in situ isotope analysis, ion microprobe and microdigestion, were used for 230Th/U and 234U/238U dating of finely laminated opal hemispheres formed in unsaturated felsic tuff at Yucca Mountain, Nevada, proposed site for a high-level radioactive waste repository. Both methods allow analysis of layers as many as several orders of magnitude thinner than standard methods using total hemisphere digestion that were reported previously. Average growth rates calculated from data at this improved spatial resolution verified that opal grew at extremely slow rates over the last million years. Growth rates of 0.58 and 0.69 mm/m.y. were obtained for the outer 305 and 740 ??m of two opal hemispheres analyzed by ion microprobe, and 0.68 mm/m.y. for the outer 22 ??m of one of these same hemispheres analyzed by sequential microdigestion. These Pleistocene growth rates are 2 to 10 times slower than those calculated for older secondary calcite and silica mineral coatings deposited over the last 5 to 10 m.y. dated by the U-Pb method and may reflect differences between Miocene and Pleistocene seepage flux. The microdigestion data also imply that opal growth rates may have varied over the last 40 k.y. These data are the first indication that growth rates and associated seepage in the proposed repository horizon may correlate with changes in late Pleistocene climate, involving faster growth during wetter, cooler climates (glacial maximum), slower growth during transition climates, and no growth during the most arid climate (modern). Data collected at this refined spatial scale may lead to a better understanding of the hydrologic variability expected within the thick unsaturated zone at Yucca Mountain over the time scale of interest for radioactive waste isolation. ?? 2004 Elsevier Ltd.

Combined Th/U, Pa/U and Ra/Th dating of fossil reef corals

NASA Astrophysics Data System (ADS)

Obert, J. C.; Scholz, D.; Lippold, J.; Felis, T.; Jochum, K. P.; Andreae, M. O.

2016-12-01

Fossil reef corals are often subject to post-depositional open-system behaviour, which is a major problem for accurate absolute dating. The commonly used 230Th/U-system can be disturbed by diagenetic alteration resulting in wrong apparent 230Th/U-ages. Since fossil reef corals are important palaeoenvironmental archives, precise absolute dating is essential for sea-level reconstruction and high-resolution climate reconstruction. We have developed a method for combined preparation and analysis of fossil reef corals by the 230Th/U-, 231Pa/U- and 226Ra/230Th-methods. Inconsistencies between ages determined by the different methods provide a means to identify diagenetically altered corals. In addition, the comparison of the 230Th/U and 231Pa/U data on concordia diagrams reveals further information about the alteration processes. (226Ra/230Th) and (226Ra/U) ratios in particular provide information about the more recent past (last 10 to approx. 50 ka) of the coral's diagenetic history. We compare these data with quantitative modelling of various diagenetic scenarios in order to identify the potential open-system processes. Here we present new data on the combined application of the three isotope systems to fossil Last Interglacial corals from the Gulf of Aqaba, northern Red Sea. Previous studies have shown that these corals were subject to substantial open-system behaviour, documented by very high initial (234U/238U) activity ratios. The process that was proposed to explain the activity ratios of these corals is U gain with subsequent U loss after a specific amount of time. The amount of U loss is assumed to be proportional to the amount of U previously gained. The application of our new method aims to test whether this diagenetic scenario can be verified.

(U-Th-Sm)/He thermochronological age distribution in a slowly cooled plutonic complex (Ploumanac'h intrusion, France): insights into helium diffusion processes.

NASA Astrophysics Data System (ADS)

Recanati, A. C.; Gautheron, C.; Barbarand, J.; Tassan-Got, L.; Missenard, Y.; Pinna-Jamme, R.

2015-12-01

(U-Th-Sm)/He thermochronology is widely used to determine the thermal histories of mountain ranges and sedimentary basins. Apatite crystals retain helium at low temperatures, thus giving an insight into upper crustal evolution (e.g. exhumation, subsidence, erosion). Advanced models predict He production and diffusion rates in apatite crystals, thereby allowing determination of helium dates by integration over time/temperature paths (e.g. Gautheron et al., 2009). However, scattered dates and discordance between predicted and measured dates suggest that other parameters than time or temperature may also influence helium contents in apatite. The present study determines the variables that affect He diffusion in apatite over long timescales. We report the (U-Th-Sm)/He date distribution within a slowly cooled intrusion, along with AFT data, as well as extensive petrological and chemical characterization. The Ploumanac'h site (Brittany, France) was chosen because it includes small-scale spatial variations in petrology and chemistry (6-9106 tracks/cm2). GAUTHERON C., TASSAN-GOT L., BARBARAND J., PAGEL M., 2009. Effect of alpha-damage annealing on apatite (U-Th)/He thermochronology. Chem. Geol. 266, 166-179.

Integrated Laser Ablation U/Pb and (U-Th)/He Dating of Detrital Accessory Minerals from the Naryani River, Central Nepal

NASA Astrophysics Data System (ADS)

Horne, A.; Hodges, K. V.; Van Soest, M. C.

2015-12-01

The newly developed 'laser ablation double dating' (LADD) technique, an integrated laser microprobe U/Pb and (U-Th)/He dating method, could be an exceptionally valuable tool in detrital thermochronology for identifying sedimentary provenance and evaluating the exhumation history of a source region. A recent proof-of-concept study has used LADD to successfully date both zircon and titanite crystals from the well-characterized Fish Canyon tuff, but we also believe that another accessory mineral, rutile, could be amenable to dating via the LADD technique. To continue the development of the method, we present an application of LADD to detrital zircon, titanite, and rutile from a sample collected on the lower Naryani River of central Nepal. Preliminary analyses of the sample have yielded zircon U/Pb dates ranging from 31.4 to 2405 Ma; zircon (U-Th)/He from 1.8 to 15.4 Ma; titanite U/Pb between 18 and 110 Ma; titanite (U-Th)/He between 1 and 16 Ma; rutile U/Pb from 6 to 45 Ma; and rutile (U-Th)/He from 2 to 25 Ma. In addition to the initial data, we can use Ti-in-zircon, Zr-in-titanite, and Zr-in-rutile thermometers to determine the range of possible long-term cooling rates from grains with U/Pb ages younger than collision. Thus far our results from zircon analyses imply a cooling rate of approximately 15°C/Myr; titanite analyses imply between 10 and 67°C/Myr; and rutile between 9 and 267°C/Myr. This spread in potential cooling rates, especially in the order of magnitude differences of cooling rates calculated from the rutile grains, suggests that the hinterland source regions of the Naryani river experienced dramatically different exhumation histories during Himalayan orogenisis. Ongoing analyses will expand the dataset such that we can more adequately characterize the range of possibilities represented in the sample.

The role of skeletal micro-architecture in diagenesis and dating of Acropora palmata

NASA Astrophysics Data System (ADS)

Tomiak, P. J.; Andersen, M. B.; Hendy, E. J.; Potter, E. K.; Johnson, K. G.; Penkman, K. E. H.

2016-06-01

Past variations in global sea-level reflect continental ice volume, a crucial factor for understanding the Earth's climate system. The Caribbean coral Acropora palmata typically forms dense stands in very shallow water and therefore fossil samples mark past sea-level. Uranium-series methods are commonly used to establish a chronology for fossil coral reefs, but are compromised by post mortem diagenetic changes to coral skeleton. Current screening approaches are unable to identify all altered samples, whilst models that attempt to correct for 'open-system' behaviour are not applicable across all diagenetic scenarios. In order to better understand how U-series geochemistry varies spatially with respect to diagenetic textures, we examine these aspects in relation to skeletal micro-structure and intra-crystalline amino acids, comparing an unaltered modern coral with a fossil A. palmata colony containing zones of diagenetic alteration (secondary overgrowth of aragonite, calcite cement and dissolution features). We demonstrate that the process of skeletogenesis in A. palmata causes heterogeneity in porosity, which can account for the observed spatial distribution of diagenetic features; this in turn explains the spatially-systematic trends in U-series geochemistry and consequently, U-series age. We propose a scenario that emphasises the importance of through-flow of meteoric waters, invoking both U-loss and absorption of mobilised U and Th daughter isotopes. We recommend selective sampling of low porosity A. palmata skeleton to obtain the most reliable U-series ages. We demonstrate that intra-crystalline amino acid racemisation (AAR) can be applied as a relative dating tool in Pleistocene A. palmata samples that have suffered heavy dissolution and are therefore unsuitable for U-series analyses. Based on relatively high intra-crystalline concentrations and appropriate racemisation rates, glutamic acid and valine are most suited to dating mid-late Pleistocene A. palmata. Significantly, the best-preserved material in the fossil specimen yields a U-series age of 165 ± 8 ka, recording a paleo sea-level of -35 ± 7 msl during the MIS 6.5 interstadial on Barbados.

Relatively Recent Volcanism on Oahu, Hawaii: New U-series and Paleomagnetic Age Constraints on the Hanauma Bay Eruption

NASA Astrophysics Data System (ADS)

Rubin, K. H.; Jurado-Chichay, Z.; Urrutia-Fucugauchi, J.

2002-12-01

The Koko Rift Zone (KRZ), eastern Oahu, is generally regarded as among the youngest volcanic features on the island. Previous workers have suggested that the 9 or 10 vents of this rift erupted near-simultaneously. However, K-Ar data in the literature (32-39 ka vs 320 ka) provide only general guidance on the youthfulness of these eruptions. We present new age constraints on KRZ volcanism using deposits of the phreatomagmatic eruption that produced Hanauma Bay (a popular snorkeling spot) and spatially associated lava flows. Numerous continuous basaltic ash units within the walls of Hanauma crater contain lithic fragments of well-preserved coral reef, beach rock, and marine mollusks, indicating that the eruption occurred in a near shore environment. 238U-234U-230Th dating of coral clasts in the deposit demonstrates that the eruption breached reef of MIS stage 7 age (200 +/- 30 ka), thereby ruling out the K-Ar age of 320 ka. U-series nuclides in "normal" MIS 7 coral lithics are indistinguishable from those in the island encircling Waianae Reef of the same age. However, U-series components in some originally aragonitic coral clasts were offset during the eruption when the rims recrystallized to calcite. 87Sr/86Sr, 234U/238U and Sr and U concentration indicate chemical mixing with host basaltic ash during this event, from which potential ages of the eruption can be constructed using isochron methods. More modeling of the data remains to be done but our preliminary estimate places the eruption at less than 100 ka. This result is consistent with new data on paleointensity and paleomagnetic secular variation within the lava flows exposed in or around the crater. This U-series dating approach should prove useful for eruptions in other locales where carbonate bioclast lithics are present in the deposits.

U-Pb ages of secondary silica at Yucca Mountain, Nevada: Implications for the paleohydrology of the unsaturated zone

USGS Publications Warehouse

Neymark, L.A.; Amelin, Y.; Paces, J.B.; Peterman, Z.E.

2002-01-01

Uranium, Th and Pb isotopes were analyzed in layers of opal and chalcedony from individual mm- to cm-thick calcite and silica coatings at Yucca Mountain, Nevada, USA, a site that is being evaluated for a potential high-level nuclear waste repository. These calcite and silica coatings on fractures and in lithophysal cavities in Miocene-age tuffs in the unsaturated zone (UZ) precipitated from descending water and record a long history of percolation through the UZ. Opal and chalcedony have high concentrations of U (10 to 780 ppm) and low concentrations of common Pb as indicated by large values of 206Pb/204Pb (up to 53,806), thus making them suitable for U-Pb age determinations. Interpretations of U-Pb isotope systems in opal samples at Yucca Mountain are complicated by the incorporation of excess 234U at the time of mineral formation, resulting in reverse discordance of U-Pb ages. However, the 207PB/235U ages are much less affected by deviation from initial secular equilibrium and provide reliable ages of most silica deposits between 0.6 and 9.8 Ma. For chalcedony subsamples showing normal age discordance, these ages may represent minimum times of deposition. Typically, 207Pb/235U ages are consistent with the microstratigraphy in the mineral coating samples, such that the youngest ages are for subsamples from outer layers, intermediate ages are from inner layers, and oldest ages are from innermost layers. 234U and 230Th in most silica layers deeper in the coatings are in secular equilibrium with 238U, which is consistent with their old age and closed system behavior during the past -0.5 Ma. The ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from lithophysal cavities in the welded part of the Topopah Spring Tuff yield slow long-term average growth rates of 1 to 5 mm/Ma. These data imply that the deeper parts of the UZ at Yucca Mountain maintained long-term hydrologic stability over the past 10 Ma. despite significant climate variations. U-Pb ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from fractures in the shallower part of the UZ (welded part of the overlying Tiva Canyon Tuff) indicate larger long-term average growth rates up to 23 mm/Ma and an absence of recently deposited materials (ages of outermost layers are 3-5 Ma.). These differences between the characteristics of the coatings for samples from the shallower and deeper parts of the UZ may indicate that the nonwelded tuffs (PTn), located between the welded parts of the Tiva Canyon and Topopah Spring Tuffs, play an important role in moderating UZ flow.

Apatite (U-Th)/He thermochronometry using a radiation damage accumulation and annealing model

NASA Astrophysics Data System (ADS)

Flowers, Rebecca M.; Ketcham, Richard A.; Shuster, David L.; Farley, Kenneth A.

2009-04-01

Helium diffusion from apatite is a sensitive function of the volume fraction of radiation damage to the crystal, a quantity that varies over the lifetime of the apatite. Using recently published laboratory data we develop and investigate a new kinetic model, the radiation damage accumulation and annealing model (RDAAM), that adopts the effective fission-track density as a proxy for accumulated radiation damage. This proxy incorporates creation of crystal damage proportional to α-production from U and Th decay, and the elimination of that damage governed by the kinetics of fission-track annealing. The RDAAM is a version of the helium trapping model (HeTM; Shuster D. L., Flowers R. M. and Farley K. A. (2006) The influence of natural radiation damage on helium diffusion kinetics in apatite. Earth Planet. Sci. Lett.249, 148-161), calibrated by helium diffusion data in natural and partially annealed apatites. The chief limitation of the HeTM, now addressed by RDAAM, is its use of He concentration as the radiation damage proxy for circumstances in which radiation damage and He are not accumulated and lost proportionately from the crystal. By incorporating the RDAAM into the HeFTy computer program, we explore its implications for apatite (U-Th)/He thermochronometry. We show how (U-Th)/He dates predicted from the model are sensitive to both effective U concentration (eU) and details of the temperature history. The RDAAM predicts an effective He closure temperature of 62 °C for a 28 ppm eU apatite of 60 μm radius that experienced a 10 °C/Ma monotonic cooling rate; this is 8 °C lower than the 70 °C effective closure temperature predicted using commonly assumed Durango diffusion kinetics. Use of the RDAAM is most important for accurate interpretation of (U-Th)/He data for apatite suites that experienced moderate to slow monotonic cooling (1-0.1 °C/Ma), prolonged residence in the helium partial retention zone, or a duration at temperatures appropriate for radiation damage accumulation followed by reheating and partial helium loss. Under common circumstances the RDAAM predicts (U-Th)/He dates that are older, sometimes much older, than corresponding fission-track dates. Nonlinear positive correlations between apatite (U-Th)/He date and eU in apatites subjected to the same temperature history are a diagnostic signature of the RDAAM for many but not all thermal histories. Observed date-eU correlations in four different localities can be explained with the RDAAM using geologically reasonable thermal histories consistent with independent fission-track datasets. The existence of date-eU correlations not only supports a radiation damage based kinetic model, but can significantly limit the range of acceptable time-temperature paths that account for the data. In contrast, these datasets are inexplicable using the Durango diffusion model. The RDAAM helps reconcile enigmatic data in which apatite (U-Th)/He dates are older than expected using the Durango model when compared with thermal histories based on apatite fission-track data or other geological constraints. It also has the potential to explain at least some cases in which (U-Th)/He dates are actually older than the corresponding fission-track dates.

Role of light and heavy minerals on natural radioactivity level of high background radiation area, Kerala, India.

PubMed

Ramasamy, V; Sundarrajan, M; Suresh, G; Paramasivam, K; Meenakshisundaram, V

2014-02-01

Natural radionuclides ((238)U, (232)Th and (40)K) concentrations and eight different radiological parameters have been analyzed for the beach sediments of Kerala with an aim of evaluating the radiation hazards. Activity concentrations ((238)U and (232)Th) and all the radiological parameters in most of the sites have higher values than recommended values. The Kerala beach sediments pose significant radiological threat to the people living in the area and tourists going to the beaches for recreation or to the sailors and fishermen involved in their activities in the study area. In order to know the light mineral characterization of the present sediments, mineralogical analysis has been carried out using Fourier transform infrared (FTIR) spectroscopic technique. The eight different minerals are identified and they are characterized. Among the various observed minerals, the minerals such as quartz, microcline feldspar, kaolinite and calcite are major minerals. The relative distribution of major minerals is determined by calculating extinction co-efficient and the values show that the amount of quartz is higher than calcite and much higher than microcline feldspar. Crystallinity index is calculated to know the crystalline nature of quartz present in the sediments. Heavy mineral separation analysis has been carried out to know the total heavy mineral (THM) percentage. This analysis revealed the presence of nine heavy minerals. The minerals such as monazite, zircon, magnetite and illmenite are predominant. Due to the rapid and extreme changes occur in highly dynamic environments of sandy beaches, quantities of major light and heavy minerals are widely varied from site to site. Granulometric analysis shows that the sand is major content. Multivariate statistical (Pearson correlation, cluster and factor) analysis has been carried out to know the effect of mineralogy on radionuclide concentrations. The present study concluded that heavy minerals induce the (238)U and (232)Th concentrations. Whereas, light mineral (calcite) controls the (40)K concentration. In addition to the heavy minerals, clay content also induces the important radioactive variables. © 2013 Published by Elsevier Ltd.

The 230Th correction is the 1st priority for accurate dates of young zircons: U/Th partitioning experiments and measurements

NASA Astrophysics Data System (ADS)

Krawczynski, M.; McLean, N.

2017-12-01

One of the most accurate and useful ways of determining the age of rocks that formed more than about 500,000 years ago is uranium-lead (U-Pb) geochronology. Earth scientists use U-Pb geochronology to put together the geologic history of entire regions and of specific events, like the mass extinction of all non-avian dinosaurs about 66 million years ago or the catastrophic eruptions of supervolcanoes like the one currently centered at Yellowstone. The mineral zircon is often utilized because it is abundant, durable, and readily incorporates uranium into its crystal structure. But it excludes thorium, whose isotope 230Th is part of the naturally occurring isotopic decay chain from 238U to 206Pb. Calculating a date from the relative abundances of 206Pb and 238U therefore requires a correction for the missing 230Th. Existing experimental and observational constraints on the way U and Th behave when zircon crystallizes from a melt are not known precisely enough, and thus currently the uncertainty in dates introduced by they `Th correction' is one of the largest sources of systematic error in determining dates. Here we present preliminary results on our study of actinide partitioning between zircon and melt. Experiments have been conducted to grow zircon from melts doped with U and Th that mimic natural magmas at a range of temperatures, and compositions. Synthetic zircons are separated from their coexisting glass and using high precision and high-spatial-resolution techniques, the abundance and distribution of U and Th in each phase is determined. These preliminary experiments are the beginning of a study that will result in precise determination of the zircon/melt uranium and thorium partition coefficients under a wide variety of naturally occurring conditions. This data will be fit to a multidimensional surface using maximum likelihood regression techniques, so that the ratio of partition coefficients can be calculated for any set of known parameters. The results of this study will reduce the largest source of uncertainty in dating young zircons and improve the accuracy of U-Pb dates, improving our ability to tell time during geologic processes. The attainment of more accurate timing of the geologic timescale is important to geologists of all disciplines, from paleontology to planetary cosmochemistry to geobiology.

Fluid inclusions and preliminary studies of hydrothermal alteration in core hole PLTG-1, Platanares geothermal area, Honduras

USGS Publications Warehouse

Bargar, K.E.

1991-01-01

The Platanares geothermal area in western Honduras consists of more than 100 hot springs that issue from numerous hot-spring groups along the banks or within the streambed of the Quebrada de Agua Caliente (brook of hot water). Evaluation of this geothermal area included drilling a 650-m deep PLTG-1 drill hole which penetrated a surface mantling of stream terrace deposits, about 550 m of Tertiary andesitic lava flows, and Cretaceous to lower Tertiary sedimentary rocks in the lower 90 m of the drill core. Fractures and cavities in the drill core are partly to completely filled by hydrothermal minerals that include quartz, kaolinite, mixed-layer illite-smectite, barite, fluorite, chlorite, calcite, laumontite, biotite, hematite, marcasite, pyrite, arsenopyrite, stibnite, and sphalerite; the most common open-space fillings are calcite and quartz. Biotite from 138.9-m depth, dated at 37.41 Ma by replicate 40Ar/39 Ar analyses using a continuous laser system, is the earliest hydrothermal mineral deposited in the PLTG-1 drill core. This mid-Tertiary age indicates that at least some of the hydrothermal alteration encountered in the PLTG-1 drill core occured in the distant past and is unrelated to the present geothermal system. Furthermore, homogenization temperatures (Th) and melting-point temperatures (Tm) for fluid inclusions in two of the later-formed hydrothermal minerals, calcite and barite, suggest that the temperatures and concentration of dissolved solids of the fluids present at the time these fluid inclusions formed were very different from the present temperatures and fluid chemistry measured in the drill hole. Liquid-rich secondary fluid inclusions in barite and caicite from drill hole PLTG-1 have Th values that range from about 20??C less than the present measured temperature curve at 590.1-m depth to as much as 90??C higher than the temperature curve at 46.75-m depth. Many of the barite Th measurements (ranging between 114?? and 265??C) plot above the reference surface boiling-point curve for pure water assuming hydrostatic conditions; however, the absence of evidence for boiling in the fluid inclusions indicates that at the time the minerals formed, the ground surface must have been at least 80 m higher than at present and underwent stream erosion to the current elevation. Near-surface mixed-layer illite-smectite is closely associated with barite and appears to have formed at about the same temperature range (about 120?? to 200??C) as the fluid-inclusion Th values for barite. Fluid-inclusion Th values for calcite range between about 136?? and 213??C. Several of the calcite Th values are significantly lower than the present measured temperature curve. The melting-point temperatures (Tm) of fluid-inclusion ice yield calculated salinities, ranging from near zero to as much as 5.4 wt. % NaCl equivalent, which suggest that much of the barite and calcite precipitated from fluids of significantly greater salinity than the present low salinity Platanares hot-spring water or water produced from the drill hole. ?? 1991.

New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA

USGS Publications Warehouse

Coble, Matthew A.; Burgess, Seth; Klemetti, Erik W.

2017-01-01

Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to accurate dating of Quaternary tephra, and highlight the challenges and opportunities of this technique.

New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA

NASA Astrophysics Data System (ADS)

Coble, Matthew A.; Burgess, Seth D.; Klemetti, Erik W.

2017-09-01

Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to accurate dating of Quaternary tephra, and highlight the challenges and opportunities of this technique.

Late Pleistocene eruptive history of the Mono Craters rhyolites, eastern California, from U-Th dating of explosive and effusive products

NASA Astrophysics Data System (ADS)

Marcaida, M.; Vazquez, J. A.; Calvert, A. T.; Miller, J. S.

2016-12-01

During late Pleistocene-Holocene time, repeated explosive and effusive eruptions of high-silica rhyolite magma south of Mono Lake, California, have produced a chain of massive domes known as the Mono Craters and a time-series of tephra deposits preserved in sediments of the Wilson Creek formation of ancestral Mono Lake. The record of late Holocene volcanism at Mono Craters is relatively well constrained by tephrostratigraphy and 14C dating, and the timing of late Pleistocene eruptions is similarly well constrained by tephrochronology and magnetostratigraphy of the Wilson Creek formation. However, the chronology of eruptions for the Mono Craters chain, comprising at least 28 individual domes, has thus far been based on age estimates from hydration rind dating of obsidian that is highly dependent on local calibration. We constrain the timing of late Pleistocene dome emplacement by linking independently dated Wilson Creek tephras to their dome equivalents in the Mono Craters using combined titanomagnetite geochemistry and U-Th geochronology. Ion microprobe 238U-230Th dating of unpolished allanite and zircon rims gives isochron dates of ca. 42 ka, ca. 38 ka, ca. 26 ka, and ca. 20 ka for domes 19, 24, 31 (newly recognized), and 11 of the Mono Craters, respectively. These domes are biotite-bearing rhyolites with titanomagnetites that are compositionally identical to those from several Wilson Creek tephras. Specifically, we correlate Ash 15, Ash 7, and Ash 3 of the Wilson Creek formation to domes 19, 31, and 11 of the Mono Craters, respectively, based on matching titanomagnetite compositions and indistinguishable U-Th ages. 40Ar/39Ar dating of single sanidines from domes 19 and 31 yield mean dates that are 10 k.y. older than their corresponding U-Th dates, likely due to excess argon from melt inclusions and/or incompletely re-equilibrated antecrysts. Based on our new U-Th isochron date of ca. 34 ka for allanite-zircon from Ash 8 pumice and the ca. 26-27 ka age of Ash 7 and its extrusive equivalent dome 31, we infer that the stratigraphic position of the ca. 32 ka Auckland/Mono Lake geomagnetic excursion, if recorded in beds of the Wilson Creek formation, is between Ashes 7 and 8. Accordingly, the prominent geomagnetic excursion bisected by Ash 15 lower in the section is the ca. 41 ka global Laschamp event.

Finnish wallpaper pigments in the 18th-19th century: Presence of KFe3(CrO4)2(OH)6 and odd pigment mixtures

NASA Astrophysics Data System (ADS)

Castro, Kepa; Knuutinen, Ulla; Vallejuelo, Silvia Fdez-Ortiz de; Irazola, Mireia; Madariaga, Juan Manuel

2013-04-01

Several Finish wallpapers from the 18th and 19th century were analysed by using Raman spectroscopy assisted with EDXRF instrumentation, in an attempt of determine the pigments used in their manufacture process as well as of trying to date some of the samples through pigment composition. All pigments present in samples were determined and surprisingly the unusual and strange iron (III) chromate yellow pigment was found. Besides, unusual mixtures were found to obtain fashionable colours, especially in blue and green areas, where more than one blue pigments were mixed with green and yellow pigments. Blue verditer, ultramarine blue, Prussian blue, chrome yellow, calcite, lead white, red and yellow iron oxide, gypsum and carbon black were identified. The presence of the risky and poisonous emerald green must be highlighted. The results were compared with those found in other wallpapers from Spain and France.

Stalagmite geochemistry and the timing of the last interglacial-glacial transition in Central Europe (NE Hungary)

NASA Astrophysics Data System (ADS)

Siklosy, Z.; Demeny, A.; Pilet, S.; Leel-Ossy, Sz.; Lin, K.; Shen, C.-C.

2009-04-01

Speleothems can provide accurate chronologies for reconstructions of climate change by combination of U/Th dating and climate-related geochemical compositions. Geochemical studies of speleothems from Central Europe are mostly based on stable C and O isotope analyses, thus, complex geochemical studies combining isotope and trace element measurements are needed for more reliable climate models for this transitional area between oceanic and continental regions. We present stable H-C-O isotope and trace element records obtained on speleothems covering the Last Interglacial (MIS 5e) and the transition to MIS 5d. A stalagmite from Baradla Cave grew from 127.5 to 110 ka. Accelerated growth rates have been detected by U/Th age data in the 127 to 126 ka and 119 to 117 ka parts. Trace element compositions and 230Th/232Th ratios suggest changes in the hydrological regime, whereby early calcite precipitates formed in fissures during the dry and cold glacial period were dissolved by the starting flux of infiltrating meteoric water (producing elevated dissolved ion concentration but low detrital Th component), then the increasing amount of dripwater during the interglacial period resulted in trace element dilution. Temperature and precipitation amount variations are also reflected by the stable isotope compositions. Oxygen isotope composition shows a continuous increase from 127.5 ka until about 118 ka most probably related to temperature rise, whereas C isotope values are shifted in negative direction suggesting increasing humidity in accordance with trace element contents. The presumably warmest period at ca. 118 ka is associated with rather arid climate as indicated by peak d18O values coinciding with the highest dD values of fluid inclusion water. This is followed by a pronounced negative shift in both O and H isotope values, similarly to recent Alpine studies (Meyer et al., 2008), most probably related to cooling. Hydrogen isotope compositions of fluid inclusion water evaluated together with calculated oxygen isotope compositions of water indicate warming and increasing significance of summer precipitation at the latest period of the last interglacial, then increasing importance of winter precipitation and/or changes in oceanic source composition during the cooling phase. The good agreement with other (Alpine and marine) records indicate a synchronous climate change. However, after a negative shift in the wet/warm phase (increasing soil activity), C isotope values start to increase already at about 119 ky BP, warning to the use of the two isotope systems as event correlation tools. In conclusion, our combined isotope and trace element study indicate a complex pattern of temperature and humidity variations during and right after the Last Interglacial. Acknowledgements — This study was financially supported by the Hungarian Scientific Research Fund (OTKA T 049713). Measurements of U-Th isotopic compositions and and 230Th dates were supported by the National Science Council grants (94-2116-M002-012, 97-2752-M002-004-PAE & -005-PAE to C.C.S.). [Meyer, M.; Spötl, C.; Mangini, A. (2008): The demise of the Last Interglacial recorded in isotopically dated speleothems from the Alps. Quaternary Science Reviews, 27, 476-496.

230Th/U dating of Last Interglacial brain corals from Bonaire (southern Caribbean) using bulk and theca wall material

NASA Astrophysics Data System (ADS)

Obert, J. Christina; Scholz, Denis; Felis, Thomas; Brocas, William M.; Jochum, Klaus P.; Andreae, Meinrat O.

2016-04-01

We compared the suitability of two skeletal materials of the Atlantic brain coral Diploria strigosa for 230Th/U-dating: the commonly used bulk material comprising all skeletal elements and the denser theca wall material. Eight fossil corals of presumably Last Interglacial age from Bonaire, southern Caribbean Sea, were investigated, and several sub-samples were dated from each coral. For four corals, both the ages and the activity ratios of the bulk material and theca wall agree within uncertainty. Three corals show significantly older ages for their bulk material than for their theca wall material as well as substantially elevated 232Th content and (230Th/238U) ratios. The bulk material samples of another coral show younger ages and lower (230Th/238U) ratios than the corresponding theca wall samples. This coral also contains a considerable amount of 232Th. The application of the available open-system models developed to account for post-depositional diagenetic effects in corals shows that none of the models can successfully be applied to the Bonaire corals. The most likely explanation for this observation is that the assumptions of the models are not fulfilled by our data set. Comparison of the theca wall and bulk material data enables us to obtain information about the open-system processes that affected the corals. The corals showing apparently older ages for their bulk material were probably affected by contamination with a secondary (detrital) phase. The most likely source of the detrital material is carbonate sand. The higher (230Th/232Th) ratio of this material implies that detrital contamination would have a much stronger impact on the ages than a contaminant with a bulk Earth (230Th/232Th) ratio and that the threshold for the commonly applied 232Th reliability criterion would be much lower than the generally used value of 1 ng g-1. The coral showing apparently younger ages for its bulk material was probably influenced by more than one diagenetic process. A potential scenario is a combination of detrital contamination and U addition by secondary pore infillings. Our results show that the dense theca wall material of D. strigosa is generally less affected by post-depositional open-system behaviour and better suited for 230Th/U-dating than the bulk material. This is also obvious from the fact that all ages of theca wall material reflect a Last Interglacial origin (∼125 ka), whereas the bulk material samples are either substantially older or younger. However, for some corals, the 230Th/U-ages and activity ratios of the bulk material and the theca wall samples are similar. This shows that strictly reliable 230Th/U-ages can also be obtained from bulk material samples of exceptionally well-preserved corals. However, the bulk material samples more frequently show elevated activity ratios and ages than the corresponding theca wall samples. Our findings should be generally applicable to brain corals (Mussidae) that are found in tropical oceans worldwide and may enable reliable 230Th/U-dating of fossil corals with similar skeletal architecture, even if their bulk skeleton is altered by diagenesis. The 230Th/U-ages we consider reliable (120-130 ka), along with a recently published age of 118 ka, provide the first comprehensive dating of the elevated lower reef terrace at Bonaire (118-130 ka), which is in agreement in timing and duration with other Last Interglacial records.

Evaluating the utility of detrital thermochronometric studies: detrital laser ablation (U-Th)/He dating and conventional bedrock zircon (U-Th)/He analyses from the eastern Sierra Nevada, California

NASA Astrophysics Data System (ADS)

Horne, A.; Hodges, K. V.; Van Soest, M. C.

2016-12-01

Recent applications of the newly developed `laser ablation double dating' (LADD) technique, an integrated laser microprobe U/Pb and (U-Th)/He dating method, have showcased the potential utility of LADD for detrital thermochronologic studies. However, detrital thermochronologic techniques rely on confidence that detrital data adequately represent the full range of bedrock cooling ages within a catchment. To test this primary assumption, we compare (U-Th)/He zircon ages from age-elevation transects to LADD (U-Th)/He zircon ages from modern fluvial detritus collected at the range front in the eastern Sierra Nevada, California. Terminated by a normal fault escarpment, the small, steep catchments along the eastern side of the Sierra Nevada batholith are apropos locations for comparing the ability of detrital data to deduce the exhumation history of a source terrain with standard age-elevation transects. Additionally, the exhumation of the Sierra Nevada batholith is also intriguing, as past evaluations of the post-emplacement exhumation history of the range have yielded discrepant results. Thus far, analyses from the southern extent of the eastern Sierra Nevada show narrow ranges of cooling ages consistent with simple, relatively rapid exhumation. Ongoing analyses will expand the dataset such that we can fully compare bedrock and detrital age ranges as well as characterize the exhumation history of the range with a thermochronometer that has not been used to date the batholith.

Dating Kimberlite Eruption and Erosion Phases Using Perovskite, Zircon, and Apatite (U-Th)/He Geochronology to Link Cratonic Lithosphere Evolution and Surface Processes

NASA Astrophysics Data System (ADS)

Stanley, J. R.; Flowers, R. M.

2015-12-01

In many cases it is difficult to evaluate the synchronicity and thus potential connections between disparate geologic events, such as the links between processes in the mantle lithosphere and at the surface. Developing new geochronologic tools and strategies for integrating existing chronologic data with other information is essential for addressing these problems. Here we use (U-Th)/He dating of multiple kimberlitic minerals to date kimberlite eruption and cratonic erosion phases. This approach permits us to more directly assess the link between unroofing and thermomodification of the lithosphere by tying our results to information obtained from mantle-derived clasts in the same pipes. Kimberlites are rich sources of information about the composition of the cratonic lithosphere and its evolution over time. Their xenoliths and xenocrysts can preserve a snapshot of the entire lithosphere and its sedimentary cover at the time of eruption. Accurate geochronology of these eruptions is crucial for interpreting spatiotemporal trends, but kimberlites can be difficult to date using standard techniques. Here we show that the mid-temperature thermochonometers of the zircon and perovskite (U-Th)/He (ZHe, PHe) systems can be viable tools for dating kimberlite eruption. When combined with the low temperature sensitivity of (U-Th)/He in apatite (AHe), the (U-Th)/He system can be used to date both the emplacement and the erosional cooling history of kimberlites. The southern African shield is an ideal location to test the utility of this approach because the region was repeatedly intruded by kimberlites in the Cretaceous, with two major pulses at ~200-110 Ma and ~100-80 Ma. These kimberlites contain a well-studied suite of mantle xenoliths and xenocrysts that document lithospheric heating and metasomatism over this interval. Our ZHe and PHe dates overlap with published eruption ages and add new ages for undated pipes. Our AHe dates constrain the spatial patterns of Cretaceous erosion across the craton, with a phase of erosion that overlaps with when the lithosphere was thermochemically modified, especially in the more heavily altered off-craton regions. These results highlight the value of the (U-Th)/He system for dating a range of geologic events and evaluating elusive links between surface and deeper-earth processes.

Discerning the timing and cause of historical mortality events in modern Porites from the Great Barrier Reef

NASA Astrophysics Data System (ADS)

Clark, Tara R.; Zhao, Jian-xin; Roff, George; Feng, Yue-xing; Done, Terence J.; Nothdurft, Luke D.; Pandolfi, John M.

2014-08-01

The life history strategies of massive Porites corals make them a valuable resource not only as key providers of reef structure, but also as recorders of past environmental change. Yet recent documented evidence of an unprecedented increase in the frequency of mortality in Porites warrants investigation into the history of mortality and associated drivers. To achieve this, both an accurate chronology and an understanding of the life history strategies of Porites are necessary. Sixty-two individual Uranium-Thorium (U-Th) dates from 50 dead massive Porites colonies from the central inshore region of the Great Barrier Reef (GBR) revealed the timing of mortality to have occurred predominantly over two main periods from 1989.2 ± 4.1 to 2001.4 ± 4.1, and from 2006.4 ± 1.8 to 2008.4 ± 2.2 A.D., with a small number of colonies dating earlier. Overall, the peak ages of mortality are significantly correlated with maximum sea-surface temperature anomalies. Despite potential sampling bias, the frequency of mortality increased dramatically post-1980. These observations are similar to the results reported for the Southern South China Sea. High resolution measurements of Sr/Ca and Mg/Ca obtained from a well preserved sample that died in 1994.6 ± 2.3 revealed that the time of death occurred at the peak of sea surface temperatures (SST) during the austral summer. In contrast, Sr/Ca and Mg/Ca analysis in two colonies dated to 2006.9 ± 3.0 and 2008.3 ± 2.0, suggest that both died after the austral winter. An increase in Sr/Ca ratios and the presence of low Mg-calcite cements (as determined by SEM and elemental ratio analysis) in one of the colonies was attributed to stressful conditions that may have persisted for some time prior to mortality. For both colonies, however, the timing of mortality coincides with the 4th and 6th largest flood events reported for the Burdekin River in the past 60 years, implying that factors associated with terrestrial runoff may have been responsible for mortality. Our results show that a combination of U-Th and elemental ratio geochemistry can potentially be used to precisely and accurately determine the timing and season of mortality in modern massive Porites corals. For reefs where long-term monitoring data are absent, the ability to reconstruct historical events in coral communities may prove useful to reef managers by providing some baseline knowledge on disturbance history and associated drivers.

Site-specific incorporation of uranyl carbonate species at the calcite surface

NASA Astrophysics Data System (ADS)

Reeder, Richard J.; Elzinga, Evert J.; Tait, C. Drew; Rector, K. D.; Donohoe, Robert J.; Morris, David E.

2004-12-01

Spatially resolved luminescence spectra from U(VI) co-precipitated at the (101¯4) growth surface of synthetic calcite single crystals confirm heterogeneous incorporation corresponding to the distribution of structurally non-equivalent steps composing the vicinal surfaces of spiral growth hillocks. Spectral structure from U(VI) luminescence at the "-" vicinal regions and featureless, weak luminescence at the "+" vicinal regions are consistent with previously reported observations of enrichment at the former sites during calcite growth. Luminescence spectra differ between the non-equivalent regions of the crystal, with the spectral features from the "-" vicinal region corresponding to those observed in bulk calcite samples. Subtle spectral shifts are observed from U(VI) co-precipitated with microcrystalline calcite synthesized by a different method, and all of the U(VI)-calcite sample spectra differ significantly from that of U(VI) co-precipitated with aragonite. The step-selective incorporation of U(VI) can be explained by a proposed model in which the allowed orientation for adsorption of the dominant calcium uranyl triscarbonate species is controlled by the atomic arrangement at step edges. Differences in the tilt angles of carbonate groups between non-equivalent growth steps favor adsorption of the calcium uranyl triscarbonate species at "-" steps, as observed in experiments.

Using zircon (U-Th)/He damage-diffusivity patterns to quantify detachment-related basement exhumation in the Mecca Hills, CA

NASA Astrophysics Data System (ADS)

Moser, A. C.; Ault, A. K.; Evans, J. P.; Reiners, P. W.; Stearns, M.; Guenthner, W.

2017-12-01

Exposures of gneiss and Orocopia Schist (OS) in the Mecca Hills, California, adjacent to the southernmost San Andreas Fault system, preserve the exhumation history of Oligocene detachment faulting. We investigate the duration, magnitude, and mechanisms of exhumation of these units at regional and local scales using in situ U-Pb zircon dating (n = 248), (U-Th)/He (He) thermochronometry (n = 39), and He date-effective U (eU) patterns. Zircons with variable preserved visual metamictization were targeted for He analyses to purposefully build a dataset with a range in eU concentration and zircon He closure temperatures, as well as induce a He date-eU correlation. Analyzed zircon crystals range from clear and transparent to purple-brown and translucent in each sample. Zircon cathodoluminescence images reveal oscillatory and sector chemical zoning. Each sample contains a population of largely Proterozoic U-Pb dates implying some grains accumulated radiation damage since 1.9-1.1 Ga. Zircon (U-Th)/He dates from seven samples of OS and gneiss yield a mean date of 24 ± 3.5 Ma (n = 32) and uniform dates over an 90-2950 ppm eU range. One gneiss sample yields a mean date of 65 ± 5.6 Ma (n = 7) over a limited eU spread ( 500-950 ppm). Mean zircon He dates from these two units overlap, but dates are broadly younger in northeastern exposures dominated by OS. Preliminary thermal history simulations integrating zircon U-Pb data, He date-eU patterns, and independent geologic constraints require at least 200 °C of cooling through the zircon He partial retention zone 30-21 Ma and show that the pre-70 Ma thermal history does not affect the predicted date-eU correlation. This shared rapid cooling history documented in the OS and gneiss imply these units were juxtaposed prior to 30 Ma and exhumed as a coherent structural block within the footwall of the Orocopia Mountains Detachment Fault in the Mecca Hills. Spatio-temporal variation in mean zircon He dates may delineate time-transgressive cooling of these units as they exhumed. Zircon textures and overall invariant He dates regardless of eU imply that visual metamictization persists in zircons at temperatures >200 °C and indicates these grains experienced a thermal history characterized by temperatures that preserved visual damage but fully induced He loss in the crystals prior to exhumation.

Comment on "Zircon U-Th-Pb dating using LA-ICP-MS: Simultaneous U-Pb and U-Th dating on 0.1 Ma Toya Tephra, Japan" by Hisatoshi Ito

NASA Astrophysics Data System (ADS)

Guillong, M.; Schmitt, A. K.; Bachmann, O.

2015-04-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) of eight zircon reference materials and synthetic zircon-hafnon end-members indicate that corrections for abundance sensitivity and molecular zirconium sesquioxide ions (Zr2O3+) are critical for reliable determination of 230Th abundances in zircon. Other polyatomic interferences in the mass range 223-233 amu are insignificant. When corrected for abundance sensitivity and interferences, activity ratios of (230Th)/(238U) for the zircon reference materials we used average 1.001 ± 0.010 (1σ error; mean square of weighted deviates MSWD = 1.45; n = 8). This includes the 91500 and Plešovice zircons, which were deemed unsuitable for calibration of (230Th)/(238U) by Ito (2014). Uranium series zircon ages generated by LA-ICP-MS without mitigating (e.g., by high mass resolution) or correcting for abundance sensitivity and molecular interferences on 230Th such as those presented by Ito (2014) are potentially unreliable.

Multi-proxy evidence of millennial climate variability from multiple Bahamian speleothems

NASA Astrophysics Data System (ADS)

Arienzo, Monica M.; Swart, Peter K.; Broad, Kenneth; Clement, Amy C.; Pourmand, Ali; Kakuk, Brian

2017-04-01

Northern Hemisphere tropical paleoclimate records support significant changes associated with Dansgaard Oeschger (D/O) events and Heinrich stadials 1 to 6 during the last 64,000 years. However, few absolutely dated terrestrial records from the western Atlantic span the last six Heinrich stadials. Here we present geochemical results from three new stalagmites collected from a cave in the Bahamas which encompass Heinrich stadials 1 to 6. We build on a previous study of the δ13C and δ18O values of the calcite and δ18O value of fluid inclusions from a single stalagmite from the same cave spanning the last three Heinrich stadials. Absolute geochronometry using U-Th equilibrium series demonstrates that the stalagmites formed between 63.8 and 13.8 kyr BP. The δ13C and δ18O values of the calcite show higher values associated with Heinrich stadials 1-6, and lower values during the D/O interstadial events. The Sr/Ca ratios of the calcite are shown to be relatively invariant, while in two of the samples the Mg/Ca ratios track the δ13C values. Increases in the δ18O values across Heinrich stadials 1-6 are interpreted as being driven by lower temperatures. The two deeper occurring stalagmites demonstrate increased Mg/Ca ratios and δ13C values during Heinrich stadials 1 and 2 which are interpreted as a signal of reduced flow rates in the epikarst and increased water/rock interactions as a result of increased aridity which potentially occurred across all six Heinrich stadials. The observed reductions in mean annual temperature and amount of precipitation across Heinrich stadials are proposed to be driven by a reduction in sea surface temperatures in the North Atlantic and an expanded Bermuda High. During D/O interstadials, the Bahamas cave records likely indicate warmer and/or wetter climate; however the isotopic shifts are not as significant as the isotopic excursions associated with Heinrich stadials.

Influence of calcite and dissolved calcium on uranium(VI) sorption to a hanford subsurface sediment.

PubMed

Dong, Wenming; Ball, William P; Liu, Chongxuan; Wang, Zheming; Stone, Alan T; Bai, Jing; Zachara, John M

2005-10-15

The influence of calcite and dissolved calcium on U(VI) adsorption was investigated using a calcite-containing sandy silt/clay sediment from the U. S. Department of Energy Hanford site. U(VI) adsorption to sediment, treated sediment, and sediment size fractions was studied in solutions that both had and had not been preequilibrated with calcite, at initial [U(VI)] = 10(-7)-10(-5) mol/L and final pH = 6.0-10.0. Kinetic and reversibility studies (pH 8.4) showed rapid sorption (30 min), with reasonable reversibility in the 3-day reaction time. Sorption from solutions equilibrated with calcite showed maximum U(VI) adsorption at pH 8.4 +/- 0.1. In contrast, calcium-free systems showed the greatest adsorption at pH 6.0-7.2. At pH > 8.4, U(VI) adsorption was identical from calcium-free and calcium-containing solutions. For calcite-presaturated systems, both speciation calculations and laser-induced fluorescence spectroscopic analyses indicated that aqueous U(VI) was increasingly dominated by Ca2UO2(CO3)3(0)(aq) at pH < 8.4 and thatformation of Ca2UO2(CO3)3(0)(aq) is what suppresses U(VI) adsorption. Above pH 8.4, aqueous U(VI) speciation was dominated by UO2(CO3)3(4-) in all solutions. Finally, results also showed that U(VI) adsorption was additive in regard to size fraction but not in regard to mineral mass: Carbonate minerals may have blocked U(VI) access to surfaces of higher sorption affinity.

Trace-element partition coefficients in the calcite-water system and their paleoclimatic significance in cave studies

NASA Astrophysics Data System (ADS)

Gascoyne, Melvyn

1983-02-01

Speleothems (stalactites, stalagmites) formed in limestone caves have been found to contain much information on the timing and intensity of past climates, from analysis of their U, Th, 13C and 18O contents. Because the incorporation of certain trace elements (e.g., Mg, Mn and Zn) in calcite is known to be temperature-dependent, it may be possible to use variations in trace-metal content of fossil speleothems as an alternative paleotem-perature indicator. Using specially developed ion-exchange sampling techniques, analysis of trace-metal content of seepage water and associated fresh calcite deposits in caves in Vancouver Island and Jamaica shows that Mg is distributed between phases in a consistent manner within the temperature regimes of the caves (7° and 23°C, respectively). Average values of the distribution coefficient for Mg are respectively 0.017 and 0.045 at these temperatures. These results indicate that the Mg content of calcite varies directly with temperature and in a sufficiently pronounced manner that a 1°C rise in depositional temperature of a speleothem containing 500 ppm Mg, at ˜10°C, would be seen as an increase of ˜35ppm Mg — a readily determinable shift. Other factors affecting Mg content of a speleothem are considered.

U-Pb Dating of Calcite by LA-ICPMS

NASA Astrophysics Data System (ADS)

Hacker, B. R.; Kylander-Clark, A. R.; Holder, R. M.; Nuriel, P.

2016-12-01

An emerging frontier area in geochronology is U-Pb dating of carbonate minerals by laser-ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The spate of papers over the last few years applying LA-ICPMS to carbonate dating stems from the capability of LA-ICPMS to deal with the variable, and often low, U/Pb ratios of carbonate. LA-ICPMS is an excellent tool for efficiently screening out samples with low U/Pb ratios and provides the ability to measure many spots with different U/Pb ratios and obtain dates free of assumptions about the composition of common Pb. Because this technique is in its infancy, important questions remain. What percentage of carbonate samples have high enough U/Pbc ratios that they can be dated? What percentage of samples yield isochronous datasets? What are the limits on precision and accuracy of carbonate U/Pb dates? What is the best analytical method in the absence of isotopically homogeneous reference materials? Through the generosity of our colleagues we have acquired 8 reference materials ranging in age from 3 to 250 Ma. We have analyzed 125 unknowns from a variety of locations using a 193 nm ns laser with an 80-100 μm spot and a Nu Plasma HR-ES. We measure 207Pb/206Pb using NIST 614 glass and then calculate a 206Pb/238U correction factor based on the measured vs. known ages of the reference materials. Sixty of these samples ( 50%) have high enough U/Pb ratios that they can be dated. There is great heterogeneity among the sample suites: some have no datable samples, whereas one suite of 68 samples yielded 53 datable rocks. Of the samples with high U/Pbc ratios, a majority yielded isochronous U-Pb data, indicating that the U-Pb system closed at a given time and was not subsequently disturbed.

Detrital zircon and apatite (U-Th)/He geochronology of intercalated baked sediments: A new approach to dating young basalt flows

NASA Astrophysics Data System (ADS)

Cooper, Frances J.; van Soest, Matthijs C.; Hodges, Kip V.

2011-07-01

Simple numerical models suggest that many basaltic lava flows should sufficiently heat the sediments beneath them to reset (U-Th)/He systematics in detrital zircon and apatite. This result suggests a useful way to date such flows when more conventional geochronological approaches are either impractical or yield specious results. We present here a test of this method on sediments interstratified with basalt flows of the Taos Plateau Volcanic Field of New Mexico. Nineteen zircons and apatites from two samples of baked sand collected from the uppermost 2 cm of a fluvial channel beneath a flow of the Upper Member of the Servilleta Basalt yielded an apparent age of 3.487 ± 0.047 Ma (2 SE confidence level), within the range of all published 40Ar/39Ar dates for other flows in the Upper Member (2.81-3.72 Ma) and statistically indistinguishable from the 40Ar/39Ar dates for basal flows of the Upper Member with which the studied flow is broadly correlative (3.61 ± 0.13 Ma). Given the high yield of 4He from U and Th decay, this technique may be especially useful for dating Pleistocene basalt flows. Detailed studies of the variation of (U-Th)/He detrital mineral dates in sedimentary substrates, combined with thermal modeling, may be a valuable tool for physical volcanologists who wish to explore the temporal and spatial evolution of individual flows and lava fields.

A simple-rapid method to separate uranium, thorium, and protactinium for U-series age-dating of materials

PubMed Central

Knight, Andrew W.; Eitrheim, Eric S.; Nelson, Andrew W.; Nelson, Steven; Schultz, Michael K.

2017-01-01

Uranium-series dating techniques require the isolation of radionuclides in high yields and in fractions free of impurities. Within this context, we describe a novel-rapid method for the separation and purification of U, Th, and Pa. The method takes advantage of differences in the chemistry of U, Th, and Pa, utilizing a commercially-available extraction chromatographic resin (TEVA) and standard reagents. The elution behavior of U, Th, and Pa were optimized using liquid scintillation counting techniques and fractional purity was evaluated by alpha-spectrometry. The overall method was further assessed by isotope dilution alpha-spectrometry for the preliminary age determination of an ancient carbonate sample obtained from the Lake Bonneville site in western Utah (United States). Preliminary evaluations of the method produced elemental purity of greater than 99.99% and radiochemical recoveries exceeding 90% for U and Th and 85% for Pa. Excellent purity and yields (76% for U, 96% for Th and 55% for Pa) were also obtained for the analysis of the carbonate samples and the preliminary Pa and Th ages of about 39,000 years before present are consistent with 14C-derived age of the material. PMID:24681438

Dating kimberlite emplacement with zircon and perovskite (U-Th)/He geochronology

NASA Astrophysics Data System (ADS)

Stanley, Jessica; Flowers, Rebecca

2017-04-01

Kimberlites provide rich information about the composition and evolution of cratonic lithosphere. They can entrain xenoliths and xenocrysts from the entire lithospheric column as they transit rapidly to the surface, providing information on the state of the deep lithosphere as well as any sedimentary units covering the craton at the time of eruption. Accurate geochronology of these eruptions is key for interpreting this information and discerning spatiotemporal trends in lithospheric evolution, but kimberlites can sometimes be difficult to date with available methods. Here we explore whether (U-Th)/He dating of zircon and perovskite can serve as reliable techniques for determining kimberlite emplacement ages by dating a suite of sixteen southern African kimberlites by zircon and/or perovskite (U-Th)/He (ZHe, PHe). Most samples with abundant zircon yielded ZHe dates reproducible to ≤15% dispersion that are in good agreement with published eruption ages, though there were several samples that were more scattered. Since the majority of dated zircon were xenocrystic, zircon with reproducible dates were fully reset during eruption or resided at temperatures above the ZHe closure temperature ( 180 °C) prior to entrainment in the kimberlite magma. We attribute scattered ZHe dates to shallowly sourced zircon that underwent incomplete damage annealing and/or partial He loss during the eruptive process. All seven kimberlites dated with PHe yielded dates reproducible to ≤15% dispersion and reasonable results. As perovskite has not previously been used as a (U-Th)/He chronometer, we conducted two preliminary perovskite 4He diffusion experiments to obtain initial estimates of its temperature sensitivity. These experiments suggest a PHe closure temperature of >300 °C. Perovskite in kimberlites is unlikely to be xenocrystic and its relatively high temperature sensitivity suggests that PHe dates will typically record emplacement rather than post-emplacement processes. ZHe and PHe geochronology can effectively date kimberlite emplacement and provide useful complements to existing techniques.

77 FR 56208 - Filing Dates for the Kentucky Special Election in the 4th Congressional District

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-12

... FEDERAL ELECTION COMMISSION [Notice 2012-06] Filing Dates for the Kentucky Special Election in the 4th Congressional District AGENCY: Federal Election Commission. ACTION: Notice of filing dates for special election. SUMMARY: Kentucky has scheduled a general election on November 6, 2012, to fill the U.S...

Laser Ablation in situ (U-Th-Sm)/He and U-Pb Double-Dating of Apatite and Zircon: Techniques and Applications

NASA Astrophysics Data System (ADS)

McInnes, B.; Danišík, M.; Evans, N.; McDonald, B.; Becker, T.; Vermeesch, P.

2015-12-01

We present a new laser-based technique for rapid, quantitative and automated in situ microanalysis of U, Th, Sm, Pb and He for applications in geochronology, thermochronometry and geochemistry (Evans et al., 2015). This novel capability permits a detailed interrogation of the time-temperature history of rocks containing apatite, zircon and other accessory phases by providing both (U-Th-Sm)/He and U-Pb ages (+trace element analysis) on single crystals. In situ laser microanalysis offers several advantages over conventional bulk crystal methods in terms of safety, cost, productivity and spatial resolution. We developed and integrated a suite of analytical instruments including a 193 nm ArF excimer laser system (RESOlution M-50A-LR), a quadrupole ICP-MS (Agilent 7700s), an Alphachron helium mass spectrometry system and swappable flow-through and ultra-high vacuum analytical chambers. The analytical protocols include the following steps: mounting/polishing in PFA Teflon using methods similar to those adopted for fission track etching; laser He extraction and analysis using a 2 s ablation at 5 Hz and 2-3 J/cm2fluence; He pit volume measurement using atomic force microscopy, and U-Th-Sm-Pb (plus optional trace element) analysis using traditional laser ablation methods. The major analytical challenges for apatite include the low U, Th and He contents relative to zircon and the elevated common Pb content. On the other hand, apatite typically has less extreme and less complex zoning of parent isotopes (primarily U and Th). A freeware application has been developed for determining (U-Th-Sm)/He ages from the raw analytical data and Iolite software was used for U-Pb age and trace element determination. In situ double-dating has successfully replicated conventional U-Pb and (U-Th)/He age variations in xenocrystic zircon from the diamondiferous Ellendale lamproite pipe, Western Australia and increased zircon analytical throughput by a factor of 50 over conventional methods.Reference: Evans NJ, McInnes BIA, McDonald B, Becker T, Vermeesch P, Danisik M, Shelley M, Marillo-Sialer E and Patterson D. An in situ technique for (U-Th-Sm)/He and U-Pb double dating. J Analytical Atomic Spectrometry, 30, 1636 - 1645.

Uranium in foraminiferal calcite as a recorder of seawater uranium concentrations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, A.D.; Emerson, S.; Nelson, B.K.

The authors present results of an investigation of uranium/calcium ratios in cleaned foraminiferal calcite as a recorder of seawater uranium concentrations. For accurate reconstruction of past seawater uranium content, shell calcite must incorporate uranium in proportion to seawater concentration and must preserve its original uranium composition over time. Laboratory culture experiments with live benthic (Amphistegina lobifera) and live planktonic (Globigerinell calida) foraminifera show that the U/Ca ratio of cleaned calcite tests is proportional to the concentration of uranium in solution. After correcting results for the presence of initial calcite, the apparent distribution coefficient D = (U/Ca[sub calcite])/(U/Ca)[sub solution] = 10.6more » [+-] 0.3 (x10[sup [minus]3]) for A. lobifera and D = 7.9 [+-] 0.1 (x10[sup [minus]3]) for G. calida. U/Ca ratios in planktonic foraminifera from core tops collected above 3900 m in the equatorial Atlantic and above 2100 m in the Pacific Ocean show no significant difference among the species analyzed. D estimated form core top samples ranges from 7.6 [+-] 0.4 (x10[sup [minus]3]) for O. universa to 8.4 [+-] 0.5 (x10[sup [minus]3]) for G. ruber. In benthic species C. wuellerstorfi, D = 7.0 [+-] 0.8 (x10[sup [minus]3]). U/Ca and Mg/Ca in G. tumida and G. sacculifer from core tops taken near and below the regional lysocline decrease with water depth. Smaller decreases in U/Ca and Mg/Ca with depth were observed in C. wuellerstorfi. In the planktonic species, the authors believe that U/CA and Mg/Ca are lower in the more dissolution-resistant fraction of calcite, leading to lower U/Ca in more highly dissolved samples.« less

Prospects for dating monazite via single-collector HR-ICP-MS

NASA Astrophysics Data System (ADS)

Kohn, M. J.; Vervoort, J. D.

2006-12-01

ICP-MS analysis permits rapid and precise dating of minerals with high U and Th contents. Here we describe a new method for in situ determination of 206Pb/238U, 207Pb/^{235}U, ^{208}Pb/232Th, and 207Pb/206Pb ages in monazite via laser ablation (New Wave Research UP-213 laser system), single-collector, magnetic sector ICP-MS (ThermoFinnigan Element2), using spot sizes of 8-30 μm, a repetition rate of 5 Hz, and a fluence of 10 J/cm2. Based on analysis of 9 monazite samples of known ages ranging from 280 to 1800 Ma, analytical precision (single sample) is ±2-3% (2σ), and reproducibility (single sample) is ±2-4% (2σ), yielding age precisions of ±3- 5% (2σ) for single points, or ±1-2% (2 s.e.) for pooled multiple analyses (n > 4). Issues of accuracy are paramount. 207Pb/206Pb ages are consistently the most accurate and agree to ±2% with accepted TIMS ages. In contrast, 206Pb/238U, 207Pb/^{235}U, and ^{208}Pb/232Th ages can differ by as much as ±5% (2σ), a problem that has also been observed for SIMS Th-Pb dating. The sources of the interelement standardization disparities among monazites remain enigmatic, but do not result from molecular interferences on Pb, U, or Th peaks. Unresolvable mass interference between 204Pb and trace contaminant 204Hg in commercial Ar gas precludes precise common Pb corrections. Instead common Pb corrections are made assuming concordancy between 207Pb/^{235}U and either 206Pb/238U or ^{208}Pb/232Th ages. The new method offers rapid analysis (~1 minute), minimal sample preparation (polished thin section), and high sensitivity. Comparatively large errors on the 206Pb/238U, 207Pb/^{235}U, and ^{208}Pb/232Th ages will likely restrict analysis of younger monazite grains (<250 Ma) to applications where 5% accuracy is sufficient. Older grains (c. 500 Ma and older) can be dated more precisely and accurately using 207Pb/206Pb. One application to young materials involves dating a large vein monazite from the Llallagua tin district of Bolivia, which resolves a ~2 Myr history of mineralization at 20-22 Ma. These data support mineralization age estimates of 21 Ma (K-Ar on wallrock minerals) rather than 44 Ma (Sm-Nd on apatite).

Fluid-inclusion technique for determining maximum temperature in calcite and its comparison to the vitrinite reflectance geothermometer

USGS Publications Warehouse

Barker, C.E.; Goldstein, R.H.

1990-01-01

The hypothesis that aqueous fluid inclusions in calcite can be used to establish maximum temperature (Tpeak) is tested. Fluid inclusion Th, mean random vitrinite reflectance (Rm), and present-day Tpeak from 46 diverse geologic systems that have been at Tpeak from 104 to 106 yr have been compiled. Present Tpeak ranged from 65 to 345??C, Th modes and means ranged from 59 to 350??C, and Rm data ranged from 0.4% to 4.6%, spanning the temperature and thermal maturity range associated with burial diagenesis, hydrothermal alteration, and low-grade metamorphism. Plots of Th and Tpeak data for systems thought to be currently at maximum temperature demonstrate close agreement between Th and present Tpeak in sedimentary basins. The relation suggests that Th of aqueous fluid inclusions in calcite may be a useful measure of maximum temperature. This study also compared Th to mean random vitrinite reflectance (Rm). Th correlates well with Rm and results in a curve similar to Rm vs. Tpeak calibrations determined by other workers. Strong correlation between Tpeak and Rm in these systems suggests that maximum temperature is the major control on thermal maturation. -after Authors

Constraining the Uplift History of the Jabal Akhdar and Saih Hatat Culminations, Al Hajar Mountains, Oman, with Fission Track and (U-Th)/He Ages

NASA Astrophysics Data System (ADS)

Hansman, R. J.; Ring, U.; Thomson, S. N.; Den Brok, B.; Stübner, K.

2016-12-01

We constrain the timing of the enigmatic uplift history of the Al Hajar Mountains in Oman by apatite (U-Th)/He and fission-track (AHe and AFT), as well as zircon (U-Th)/He (ZHe) ages. Our data show differential cooling between the two major culminations of the mountain range, which are separated by the Semail gap, a major NNE-oriented depression in the Al Hajar Mountains. In the up to 3 km high Jabal Akhdar Culmination west of the Semail Gap AHe sample mean ages range between 35.5 ± 4.3 Ma and 23.9 ± 8.8 Ma (1σ errors), AFT ages range 51 ± 4 to 32 ± 2 Ma (1σ errors), and ZHe sample mean ages range 50.6 ± 16.7 to 46.1 ± 7.1 Ma (1σ errors). Whereas, in the Saih Hatat Culmination to the east AHe ages range from 23.6 ± 1.7 Ma to 15.7 ± 4.1 Ma, AFT ages range 73 ± 10 to 57 ± 4 Ma, and ZHe ages range 70.6 ± 10.8 Ma through to 58.8 ± 1.8 Ma. These data demonstrate that the uplift initiated at 45 Ma and had ceased by 15 Ma, climaxing between 40 to 35 Ma. In addition, U-Pb dating of calcite tectonics also supports N-S shortening at 40 to 35 Ma. We propose that the Semail gap is a west-dipping thrust, which uplifted the Jabal Akhdar Culmination in the hanging-wall but hardly affected the Saih Hatat Culmination in the footwall. During mountain uplift, the Al Hajar Mountains were located at least 600 km outboard of the current Eurasia-Arabia subduction/collision zone on the continental margin of the downgoing Arabian Plate. We therefore conclude that the uplift of the Al Hajar Mountains preceded the Zagros collisional event by at least 15 Myr and were not causally related to the Zagros collision and Makran subduction.

The first case study of 230Th/U and 14C dating of mid-valdai organic deposits

NASA Astrophysics Data System (ADS)

Maksimov, F. E.; Kuznetsov, V. Yu.; Zaretskaya, N. E.; Subetto, D. A.; Shebotinov, V. V.; Zherebtsov, I. E.; Levchenko, S. B.; Kuznetsov, D. D.; Larsen, E.; Lysö, A.; Jensen, M.

2011-05-01

From the viewpoint of precision and reliability of radioisotopic dating, deposits whose quantitative age can be determined through several methods of geochronometry are of special interest. The mutually conforming finite 14C and 230Th/U dates of buried Neopleistocene organic deposits, taken from the Tolokonka section by the North Dvina River (100 km downstream from the city of Kotlas), have been obtained for the first time in Russia. The stratigraphical reference of these results to those obtained via the optically induced luminescence for upper and lower bedding layers has been established. The presented geochronometric data have allowed us to consider the age of oxbow lake organic deposits completely reliable and refer the time of their formation to the Tyrbei warming within the MIS-3. The applicability of the new version of the 230Th/U method for dating of interglacial and interstadial deposits, for the purpose of solving the Middle and Late Neopleistocene chronostratigraphy issues, is confirmed.

Thermal and exhumation history of the central Tianshan (NW China): Constraints by U-Pb geochronology and Ar-Ar and (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Yin, J.; Chen, W.; Hodges, K. V.; Xiao, W.; Van Soest, M. C.; Cai, K.; Zhang, B.; Mercer, C. M.; Yuan, C.

2015-12-01

Geochronology and thermochronology using multiple mineral-isotopic chronometers reveals the thermo-tectonic history of the central Tianshan (NW China) from emplacement to exhumation. Granites from the central Tianshan, which are associated with the southward subduction of the northern Tianshan Ocean, have been dated at 362-354 Ma using the LA-ICP-MS Zircon U-Pb method. A younger diorite sample (282 ± 1 Ma, Zircon U-Pb method by LA-ICP-MS) from northern Tianshan formed during the final closure of the Northern Tianshan Ocean when the Junggar Block collided with the Yili-Central Tianshan Block. 40Ar/39Ar step-wise heating plateau dates (biotite Ar/Ar: 312-293 Ma; Plagioclase Ar/Ar: 270-229 Ma) from the Central Tianshan show rapid post-magmatic cooling during the Late Carboniferous-Early Permian followed by a more modest rate of cooling from the middle Permian to the middle Jurassic. The northern Tianshan diorite (biotite Ar/Ar: 240 ± 1 Ma) also reveals a middle Jurassic cooling. Apatite (U-Th )/He dates from the central Tianshan samples range from ca. 130 Ma to ca. 116 Ma. The Apatite (U-Th )/He date for the northern Tianshan sample is ca. 27 Ma. Previous studies also reported Apatite (U-Th)/He ages of ca. 44 Ma-11 Ma in the Baluntai area of the southern Central Tianshan[1]. Two episodes of cooling are distinguished by thermal history modelling: (1) Mesozoic cooling occurred as the result of the exhumation and tectonic reactivation of the central Tianshan; and (2) The Tianshan orogenic belt has been rapidly exhumed since the Middle Cenozoic. References [1] Lü, H.H., Chang, Y., Wang, W., Zhou, Z.Y., 2013. Rapid exhumation of the Tianshan Mountains since the early Miocene: Evidence from combined apatite fission track and (U-Th)/He thermochronology. Science China: Earth Sciences, 43(12): 1964-1974 (in Chinese).

Enhanced provenance interpretation using combined U-Pb and (U-Th)/He double dating of detrital zircon grains from lower Miocene strata, proximal Gulf of Mexico Basin, North America

NASA Astrophysics Data System (ADS)

Xu, Jie; Stockli, Daniel F.; Snedden, John W.

2017-10-01

Detrital zircon U-Pb analysis is an effective approach for investigating sediment provenance by relating crystallization age to potential crystalline source terranes. Studies of large passive margin basins, such as the Gulf of Mexico Basin, that have received sediment from multiple terranes with non-unique crystallization ages or sedimentary strata, benefit from additional constraints to better elucidate provenance interpretation. In this study, U-Pb and (U-Th)/He double dating analyses on single zircons from the lower Miocene sandstones in the northern Gulf of Mexico Basin reveal a detailed history of sediment source evolution. U-Pb age data indicate that most zircon originated from five major crystalline provinces, including the Western Cordillera Arc (<250 Ma), the Appalachian-Ouachita orogen (500-260 Ma), the Grenville (1300-950 Ma) orogen, the Mid-Continent Granite-Rhyolite (1500-1300 Ma), and the Yavapai-Mazatzal (1800-1600 Ma) terranes as well as sparse Pan-African (700-500 Ma) and Canadian Shield (>1800 Ma) terranes. Zircon (U-Th)/He ages record tectonic cooling and exhumation in the U.S. since the Mesoproterozoic related to the Grenville to Laramide Orogenies. The combined crystallization and cooling information from single zircon double dating can differentiate volcanic and plutonic zircons. Importantly, the U-Pb-He double dating approach allows for the differentiation between multiple possible crystallization-age sources on the basis of their subsequent tectonic evolution. In particular, for Grenville zircons that are present in all of lower Miocene samples, four distinct zircon U-Pb-He age combinations are recognizable that can be traced back to four different possible sources. The integrated U-Pb and (U-Th)/He data eliminate some ambiguities and improves the provenance interpretation for the lower Miocene strata in the northern Gulf of Mexico Basin and illustrate the applicability of this approach for other large-scale basins to reconstruct sediment provenance and dispersal patterns.

A simple-rapid method to separate uranium, thorium, and protactinium for U-series age-dating of materials.

PubMed

Knight, Andrew W; Eitrheim, Eric S; Nelson, Andrew W; Nelson, Steven; Schultz, Michael K

2014-08-01

Uranium-series dating techniques require the isolation of radionuclides in high yields and in fractions free of impurities. Within this context, we describe a novel-rapid method for the separation and purification of U, Th, and Pa. The method takes advantage of differences in the chemistry of U, Th, and Pa, utilizing a commercially-available extraction chromatographic resin (TEVA) and standard reagents. The elution behavior of U, Th, and Pa were optimized using liquid scintillation counting techniques and fractional purity was evaluated by alpha-spectrometry. The overall method was further assessed by isotope dilution alpha-spectrometry for the preliminary age determination of an ancient carbonate sample obtained from the Lake Bonneville site in western Utah (United States). Preliminary evaluations of the method produced elemental purity of greater than 99.99% and radiochemical recoveries exceeding 90% for U and Th and 85% for Pa. Excellent purity and yields (76% for U, 96% for Th and 55% for Pa) were also obtained for the analysis of the carbonate samples and the preliminary Pa and Th ages of about 39,000 years before present are consistent with (14)C-derived age of the material. Copyright © 2014 Elsevier Ltd. All rights reserved.

The Sima de los Huesos hominids date to beyond U/Th equilibrium (>350 kyr) and perhaps to 400-500 kyr: New radiometric dates

USGS Publications Warehouse

Bischoff, J.L.; Shamp, D.D.; Aramburu, Arantza; Arsuaga, J.L.; Carbonell, E.; Bermudez de Castro, Jose Maria

2003-01-01

The Sima de los Huesos site of the Atapuerca complex near Burgos, Spain contains the skeletal remains of at least 28 individuals in a mud breccia underlying an accumulation of the Middle Pleistocene cave bear (U. deningeri). Earlier dating estimates of 200 to 320 kyr were based on U-series and ESR methods applied to bones, made inaccurate by unquantifiable uranium cycling. We report here on a new discovery within the Sima de los Huesos of human bones stratigraphically underlying an in situ speleothem. U-series analyses of the speleothem shows the lower part to be at isotopic U/Th equilibrium, translating to a firm lower limit of 350 kyr for the SH hominids. Finite dates on the upper part suggest a speleothem growth rate of c. 1 cm/32 kyr. This rate, along with paleontological constraints, place the likely age of the hominids in the interval of 400 to 600 kyr. ?? 2002 Elsevier Science Ltd. All rights reserved.

Age of Zhoukoudian Homo erectus determined with (26)Al/(10)Be burial dating.

PubMed

Shen, Guanjun; Gao, Xing; Gao, Bin; Granger, Darryl E

2009-03-12

The age of Zhoukoudian Homo erectus, commonly known as 'Peking Man', has long been pursued, but has remained problematic owing to the lack of suitable dating methods. Here we report cosmogenic (26)Al/(10)Be burial dating of quartz sediments and artefacts from the lower strata of Locality 1 in the southwestern suburb of Beijing, China, where early representatives of Zhoukoudian Homo erectus were discovered. This study marks the first radioisotopic dating of any early hominin site in China beyond the range of mass spectrometric U-series dating. The weighted mean of six meaningful age measurements, 0.77 +/- 0.08 million years (Myr, mean +/- s.e.m.), provides the best age estimate for lower cultural layers 7-10. Together with previously reported U-series dating of speleothem calcite and palaeomagnetic stratigraphy, as well as sedimentological considerations, these layers may be further correlated to S6-S7 in Chinese loess stratigraphy or marine isotope stages (MIS) 17-19, in the range of approximately 0.68 to 0.78 Myr ago. These ages are substantially older than previously supposed and may imply early hominin's presence at the site in northern China through a relatively mild glacial period corresponding to MIS 18.

Assessment of Alternative [U] and [Th] Zircon Standards for SIMS

NASA Astrophysics Data System (ADS)

Monteleone, B. D.; van Soest, M. C.; Hodges, K.; Moore, G. M.; Boyce, J. W.; Hervig, R. L.

2009-12-01

The quality of in situ (U-Th)/He zircon dates is dependent upon the accuracy and precision of spatially distributed [U] and [Th] measurements on often complexly zoned zircon crystals. Natural zircon standards for SIMS traditionally have been used to obtain precise U-Pb ages rather than precise U and Th concentration. [U] and [Th] distributions within even the most homogeneous U-Pb age standards are not sufficient to make good microbeam standards (i.e., yield good precision: 2σ < 5%) for (U-Th)/He dates. In the absence of sufficiently homogeneous natural zircon crystals, we evaluate the use of the NIST 610 glass standard and a synthetic polycrystalline solid “zircon synrock” made by powdering and pressing natural zircon crystals at 2 GPa and 1100°C within a 13 mm piston cylinder for 24 hours. SIMS energy spectra and multiple spot analyses help assess the matrix-dependence of secondary ion emission and [U] and [Th] homogeneity of these materials. Although spot analyses on NIST 610 glass yielded spatially consistent ratios of 238U/30Si and 232Th/30Si (2σ = 2%, n = 14), comparison of energy spectra collected on glass and zircon reveal significant differences in U, UO, Th, and ThO ion intensities over the range of initial kinetic energies commonly used for trace element analyses. Computing [U] and [Th] in zircon using NIST glass yields concentrations that vary by more than 10% for [U] and [Th], depending on the initial kinetic energy and ion mass (elemental, oxide, or sum of elemental and oxide) used for the analysis. The observed effect of chemistry on secondary ion energy spectra suggests that NIST glass cannot be used as a standard for trace [U] and [Th] in zircon without a correction factor (presently unknown). Energy spectra of the zircon synrock are similar to those of natural zircon, suggesting matrix compatibility and therefore potential for accurate standardization. Spot analyses on the zircon powder pellets, however, show that adequate homogeneity of [U] and [Th] (2σ = 37% and 33% for 238U/30Si and 232Th/30Si, respectively, n = 8) has yet to be achieved. Modeling shows that homogenization of [U] and [Th] within these pellets requires preparation of powders with <2 micron sized particles, which has yet to be achieved in sample preparation. Thus, the zircon synrock pellet remains a viable potential [U], [Th] standard, although the preparation of a sufficiently fine grained, homogeneous pellet is a work in progress.

In situ detrital zircon (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Tripathy, A.; Monteleone, B. D.; van Soest, M. C.; Hodges, K.; Hourigan, J. K.

2010-12-01

Detrital studies of both sand and rock are relevant to many problems, ranging from the climate and tectonics feedback debate to the long-term record of orogenic evolution. When applying the conventional (U-Th)/He technique to such studies, two important issues arise. Often, only euhedral grains are permissible for analysis in order to make simple geometric corrections for α-recoil. In detrital samples, this is problematic because euhedral grains can be scarce due to mechanical abrasion during transport, and potentially introduce bias in favour of more proximally sourced grains. Second, inherent to detrital studies is the need to date many grains (>100) per sample to ensure a representative sampling of the sediment source region, thus making robust conventional detrital studies both expensive and time-consuming. UV laser microprobes can improve this by permitting careful targeting of the grain interior away from the α-ejection zone, rendering the α-recoil correction unnecessary, thus eliminating bias toward euhedral grains. In the Noble Gas, Geochemistry, and Geochronology Laboratory at ASU, apatite and zircon have been successfully dated using in situ methods. For this study, the conventional and in situ techniques are compared by dating zircons from a modern river sand that drains a small catchment in the Mesozoic-Cenozoic Ladakh Batholith in NW India. This sample has a simple provenance, which allows us to demonstrate the robustness of the in situ method. Moreover, different microbeam techniques will be explored to establish the most efficient approach to obtain accurate and precise U-Th concentrations using synrock, which is our powdered, homogenized, and reconstituted zircon-rock standard. Without this, such in situ U-Th data would be difficult to obtain. 117 zircons were dated using the conventional (U-Th)/He method, revealing dates ranging from 9.70±0.35 to 106.6±3.5 Ma (2σ) with the major mode at 26 Ma. For comparison, 44 grains were dated using the in situ method, utilizing SIMS to determine the U-Th concentrations. The major mode is the same as the conventional dataset, with only single outliers missing from the in situ dataset. The in situ method is described as follows: Zircons are polished and imaged using cathodoluminesence to guide laser spot placement. Then, each grain is ablated with a 193nm ArF Excimer laser using 20-35µm beam sizes and depths of 10-17µm. After purification, 4He is analyzed on a ThermoScientific Helix Split Flight Tube mass spectrometer. U-Th concentrations are measured on the polished mount using a Cameca IMS 6f by placing a 60µm diameter beam directly over the He laser pit to cover the surface area contributing to the measured He. In theory, using LA-ICP-MS to obtain U-Th concentrations could be a faster, cheaper, but possibly less precise, technique. However, using laser ablation would allow pit sizes that average the U-Th concentration over the volume of material available that contributes to the measured He, thus accounting for intracrystalline α-recoil effects. Preliminary data on slabs of Sri Lankan zircon suggest this could be a viable method, but will require further exploration and refinement.

Th-230 - U-238 series disequilibrium of the Olkaria rhyolites Gregory Rift Valley, Kenya: Residence times

NASA Technical Reports Server (NTRS)

Black, S.; Macdonald, R.; Kelly, M.

1993-01-01

U-series disequilibrium analyses have been conducted on samples from Olkaria rhyolite centers with ages being available for all but one center using both internal and whole rock isochrons. 67 percent of the rhyolites analyzed show U-Th disequilibrium, ranging from 27 percent excess thorium to 36 percent excess uranium. Internal and whole rock isochrons give crystallization/formation ages between 65 ka and 9 ka, in every case these are substantially older than the eruptive dates. The residence times of the rhyolites (U-Th age minus the eruption date) have decreased almost linearly with time, from 45 ka to 7 Ka suggesting a possible increase of activity within the system related to increased basaltic input. The long residence times are mirrored by large Rn-222 fluxes from the centers which cannot be explained by larger U contents.

Consequences of slow growth for 230Th/U dating of Quaternary opals, Yucca Mountain, NV, USA

USGS Publications Warehouse

Neymark, L.A.; Paces, J.B.

2000-01-01

Thermal ionization mass-spectrometry 234U/238U and 230Th/238U data are reported for uranium-rich opals coating fractures and cavities within the silicic tuffs forming Yucca Mountain, NV, the potential site of a high-level radioactive waste repository. High uranium concentrations (up to 207 ppm) and extremely high 230Th/232Th activity ratios (up to about 106) make microsamples of these opals suitable for precise 230Th/U dating. Conventional 230Th/U ages range from 40 to greater than 600 ka, and initial 234U/238U activity ratios between 1.03 and 8.2. Isotopic evidence indicates that the opals have not experienced uranium mobility; however, wide variations in apparent ages and initial 234U/238U ratios for separate subsamples of the same outermost mineral surfaces, positive correlation between ages and sample weights, and negative correlation between 230Th/U ages and calculated initial 234U/238U are inconsistent with the assumption that all minerals in a given subsample was deposited instantaneously. The data are more consistent with a conceptual model of continuous deposition where secondary mineral growth has occurred at a constant, slow rate up to the present. This model assumes that individual subsamples represent mixtures of older and younger material, and that calculations using the resulting isotope ratios reflect an average age. Ages calculated using the continuous-deposition model for opals imply average mineral growth rates of less than 5 mm/m.y. The model of continuous deposition also predicts discordance between ages obtained using different radiometric methods for the same subsample. Differences in half-lives will result in younger apparent ages for the shorter-lived isotope due to the greater influence of younger materials continuously added to mineral surfaces. Discordant 14C, 230Th/U and U-Pb ages obtained from outermost mineral surfaces at Yucca Mountain support this model. (C) 2000 Elsevier Science B.V. All rights reserved.

Lifetime of an ocean island volcano feeder zone: constraints from U-Pb dating on coexisting zircon and baddeleyite, and 40/39Ar age determinations, Fuerteventura, Canary Islands

USGS Publications Warehouse

Allibon, James; Ovtcharova, Maria; Bussy, Francois; Cosca, Michael; Schaltegger, Urs; Bussien, Denise; Lewin, Eric

2011-01-01

High-precision isotope dilution - thermal ionization mass spectrometry (ID-TIMS) U-Pb zircon and baddeleyite ages from the PX1 vertically layered mafic intrusion Fuerteventura, Canary Islands, indicate initiation of magma crystallization at 22.10 ± 0.07 Ma. The magmatic activity lasted a minimum of 0.52 Ma. 40Ar/39Ar amphibole dating yielded ages from 21.9 ± 0.6 to 21.8 ± 0.3, identical within errors to the U-Pb ages, despite the expected 1% theoretical bias between 40Ar/39Ar and U-Pb dates. This overlap could result from (i) rapid cooling of the intrusion (i.e., less than the 0.3 to 0.6 Ma 40Ar/39Ar age uncertainties) from closure temperatures (Tc) of zircon (699-988 °C) to amphibole (500-600 °C); (ii) lead loss affecting the youngest zircons; or (iii) excess argon shifting the plateau ages towards older values. The combination of the 40Ar/39Ar and U/Pb datasets implies that the maximum amount of time PX1 intrusion took to cool below amphibole Tc is 0.8 Ma, suggesting PX1 lifetime of 520,000 to 800,000 Ma. Age disparities among coexisting baddeleyite and zircon (22.10 ± 0.07/0.08/0.15 Ma and 21.58 ± 0.15/0.16/0.31 Ma) in a gabbro sample from the pluton margin suggest complex genetic relationships between phases. Baddeleyite is found preserved in plagioclase cores and crystallized early from low silica activity magma. Zircon crystallized later in a higher silica activity environment and is found in secondary scapolite and is found close to calcite veins, in secondary scapolite that recrystallised from plagioclase. close to calcite veins. Oxygen isotope δ18O values of altered plagioclase are high (+7.7), indicating interaction with fluids derived from host-rock carbonatites. The coexistence of baddeleyite and zircon is ascribed to interaction of the PX1 gabbro with CO2-rich carbonatite-derived fluids released during contact metamorphism.

Can Single Crystal (U-Th)/He Zircon Ages from Nördlinger Ries Suevite be Linked to Impact-Related Shock Effects?

NASA Astrophysics Data System (ADS)

van Soest, M. C.; Cooper, F. J.; Wartho, J.; Hodges, K.; Buchner, E.; Schmieder, M.; Koeberl, C.

2010-12-01

Dating of impact-related material is difficult especially when pristine impact melt is unavailable. In the absence of such melts, most geochronometers in shocked basement or melt-poor impact rocks yield only partially reset or non-reset ages. In such cases, application of the low closure temperature apatite and zircon (U-Th)/He geochronometers can be successful, since impact-related physical and thermal shock should reset the He systematics in both minerals in most materials affected by the impact. For a proof of concept study on the well-studied Ries impact structure, we (U-Th)/He dated apatites (14.08 ± 0.26 Ma 2σ, n = 5) and zircons (14.26 ± 0.31 Ma 2σ, n = 10) from two Aumühle quarry suevite samples and one Polsingen quarry impact melt rock, which was dated at 14.37 ± 0.30 Ma (2σ) using Ar-Ar stepwise heating of recrystallized K-feldspar melt (Buchner et al., 2010). The (U-Th)/He ages agree well with the 14.37 Ma age, but are slightly younger than the suggested age of 14.59 ± 0.20 Ma (2σ - based on recent, post 1995, Ar-Ar data, Buchner et al., 2010) for the impact structure. However, among the 27 zircons dated, 6 were partially reset (>16Ma), and 11 zircons yielded younger dates (<13.5 Ma).The younger dates are problematic for successful (U-Th)/He dating of impact structures of unknown age, as they would be identified incorrectly as the age of the impact event. The cause for these younger dates may be: a) partial He loss due to a post-impact thermal event, which at Ries is unlikely as there is no geological evidence for such an event; b) compromised He retention due to metamictization by progressive radiation damage; or c) compromised He retention due to impact shock-related effects. The latter two causes can produce similar visual effects on zircon and the He loss mechanism is also similar, i.e. changes in the zircon crystal structure on a micro scale. However, the effects of these processes on zircon have been documented extensively by non-destructive analytical methods such as Raman spectroscopy, single crystal XRD, and SEM. These techniques have provided a means to distinguish shock from radiation damage effects, based on the presence of the high pressure zircon polymorph reidite, at shock levels >20 GPa (Wittmann et al., 2006). In order to establish if these effects can be identified in individual zircons before undertaking (U-Th)/He dating, and thus if these analytical methods can be used to pre-select suitable zircons for dating, 30 Ries zircons have been picked, based on euhedral shape and size, from two suevite samples for non-destructive geochemical and crystal structure studies prior to (U-Th)/He dating. Initial results from Raman spectroscopy indicate reidite is present in >80% of the grains, providing clear evidence for shock, while other grains show extensive amorphization likely due to extreme shock or radiation damage. References: Buchner et al. (2010) MAPS 45, 5: 662-674; Wittman et al. (2006) MAPS 41, 3: 433-454.

Decoupled evolution of temperature and precipitation in western Germany during the Last Interglacial reconstructed from a precisely dated speleothem

NASA Astrophysics Data System (ADS)

Scholz, Denis; Hoffmann, Dirk; Spötl, Christoph; Hopcroft, Peter; Mangini, Augusto; Richter, Detlef K.

2010-05-01

We present high-resolution stable oxygen and carbon isotope (δ18O and δ13C) as well as trace element profiles for stalagmite HBSH-1 from Hüttenbläserschachthöhle, western Germany. The chronology was established by MC-ICPMS 230Th/U-dating, and the high U-content of the stalagmite allowed determination of very precise 230Th/U-ages although using very small sample sizes. The beginning and end of individual growth phases of the stalagmite could, thus, be determined very accurately. Stalagmite HBSH-1 grew during the penultimate interglacial (MIS 7), the Last Interglacial (MIS 5) and the Holocene. The major part of the sample (40 cm) grew between 130 and 80 ka providing a climate record with decadal to centennial resolution for this period. The record shows three growth interruptions during MIS 5 coinciding with Greenland Stadials 25, 24 and 22, as recorded in the NGRIP ice core (North Greenland Ice Core Project members, 2004). The end of the MIS 5 growth phase coincides with GS 21. This shows that stalagmite growth in this area is a very sensitive proxy for northern hemisphere cooling. Correlation of the absolutely dated stalagmite record with Greenland ice cores may provide a tool to improve the chronology of the Greenland Stadials. The δ18O profile of stalagmite HBSH-1 shows a distinct similarity during MIS 5 with the NGRIP ice core and a sea surface temperature record from the Iberian Margin (Martrat et al., 2007). This suggests that stalagmite δ18O mainly reflects past temperature variability. Stalagmite HBSH-1 consists of aragonite rather than calcite, which is probably a result of pronounced prior calcite precipitation in the epikarst above the cave (Fairchild and Treble, 2009). In this case, the δ13C signal rather reflects changes in past precipitation than temperature. The δ13C record of HBSH-1 shows three pronounced negative peaks during MIS 5, in agreement with the three MIS 5 warm phases, MIS 5e, 5c and 5a. During the Last Interglacial, however, the evolution of δ18O and δ13C, and thus temperature and precipitation, is opposite. Whereas the δ18O signal suggests the warmest temperatures around 125 ka followed by a gradual decrease, the δ13C signal indicates wetter conditions towards the end of the Last Interglacial. The decoupling of temperature and precipitation during this time period is also seen in a series of snapshot simulations performed using a fast coupled ocean-atmosphere general circulation model. This behaviour can be explained by the influence of varying solar insolation patterns (in response to changing orbital configuration) on atmospheric dynamics and the resulting influence on storm activity in the region. References Fairchild, I. J. and Treble, P. C., 2009. Trace elements in speleothems as recorders of environmental change. Quaternary Science Reviews 28, 449-468. Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F., 2007. Four climate cycles of recurring deep and surface water destabilizations on the Iberian Margin. Science 317, 502-507. North Greenland Ice Core Project members, 2004. High-resolution record of Northern Hemisphere climate extending into the last interglacial period. Nature 431, 147-151.

36Chlorine exposure dating of a terminal moraine in the Galicica Mountains, Macedonia

NASA Astrophysics Data System (ADS)

Gromig, R.; Mechernich, S.; Ribolini, A.; Dunai, T. J.; Wagner, B.

2015-12-01

The glaciation history of the Balkan Peninsula is subject of research since the late 19th century. To date, only a few moraines on the Balkan Peninsula are dated, mainly using 10Be exposure dating applied on quartz bearing rocks. Since large parts of the Balkan Peninsula mountains are composed of carbonatic rocks, absolute age dating is restricted to 36Cl exposure dating, which, to date, was not conducted in this region yet. So far, an absolute chronological control in limestone-dominated areas is limited to U-series minimum ages of calcitic cements. In order to obtain more information about the timing of the glaciation history on the Balkan Peninsula, we investigated a terminal moraine in a NNE-facing cirque in the Galicica Mountains (40°56´N, 20°49´E) in the Former Yugoslav Republic of Macedonia. The cirque comprises a series of nested moraine ridges at the base of the cirque wall, with the largest one being sampled. Samples from five limestone boulders in crest position (≈ 2050 m a.s.l.) were taken and pre-treated for AMS measurement at the University of Cologne. Three preliminary ages point to a moraine formation in the course of a late Pleistocene glaciation, either Last Glacial Maximum or Younger Dryas. The data were discussed concerning corrections for topographic shielding, snow cover, inheritance, and erosion. However, five AMS re-measurements are currently in progress in order to refine the correlation of the moraine formation to a specific glacial period. The resulting ages will be compared to sediments of the adjacent Lakes Ohrid and Prespa, which represent valuable climatic and environmental archives. Several studies on these sediments were carried out in order to reconstruct relative changes in temperature and moisture availability. Moreover, the inferred moraine formation ages will be compared to glaciation reconstructions of other mountainous regions on the Balkan Peninsula to improve the knowledge on past climatic conditions.

U-Th-Pb zircon dating of the 13.8-Ma dacite volcanic dome at Cerro Rico de Potosi, Bolivia

USGS Publications Warehouse

Zartman, R.E.; Cunningham, C.G.

1995-01-01

The temporal relationship between the extrusion of the Miocene dacite volcanic dome at Cerro Rico de Potasi, Bolivia, and the associated Ag-Sn mineralization has an important bearing on the heat and metal sources for this world class mineral deposit. The present study uses U-Th-Pb dating of sparse zircon contained in the dacite to demonstrate that, at most, only several hundred thousand years separate dome emplacement from main stage mineralization. -from Authors

Radiation damage-He diffusivity models applied to deep-time thermochronology: Zircon and titanite (U-Th)/He datasets from cratonic settings

NASA Astrophysics Data System (ADS)

Guenthner, W.; DeLucia, M. S.; Marshak, S.; Reiners, P. W.; Drake, H.; Thomson, S.; Ault, A. K.; Tillberg, M.

2017-12-01

Advances in understanding the effects of radiation damage on He diffusion in uranium-bearing accessory minerals have shown the utility of damage-diffusivity models for interpreting datasets from geologic settings with long-term, low-temperature thermal histories. Craton interiors preserve a billion-year record of long-term, long-wavelength vertical motions of the lithosphere. Prior thermochronologic work in these settings has focused on radiation damage models used in conjunction with apatite (U-Th)/He dates to constrain Phanerozoic thermal histories. Owing to the more complex damage-diffusivity relationship in zircon, the zircon (U-Th)/He system yields both higher and, in some cases, lower temperature sensitivities than the apatite system, and this greater range in turn allows researchers to access deeper time (i.e., Proterozoic) segments of craton time-temperature histories. Here, we show two examples of this approach by focusing on zircon (U-Th)/He datasets from 1.8 Ga granitoids of the Fennoscandian Shield in southeastern Sweden, and 1.4 Ga granites and rhyolites of the Ozark Plateau in southeastern Missouri. In the Ozark dataset, the zircon (U-Th)/He data, combined with a damage-diffusivity model, predict negative correlations between date and effective uranium (eU) concentration (a measurement proportional to radiation damage) from thermal histories that include an episode of Proterozoic cooling (interpreted as exhumation) following reheating (interpreted as burial) to temperature of 260°C at 850-680 Ma. In the Fennoscandian Shield, a similar damage model-based approach yields time-temperature constraints with burial to 217°C between 944 Ma and 851 Ma, followed by exhumation from 850 to 500 Ma, and burial to 154°C between 366 Ma and 224 Ma. Our Fennoscandian Shield samples also include titanite (U-Th)/He dates that span a wide range (945-160 Ma) and are negatively correlated with eU concentration, analogous to our zircon He dataset. These results support the initial findings of Baughman et al. (2017, Tectonics), and suggest that further research into the radiation damage effect on He diffusion in titanite could yield a comprehensive damage-diffusivity model for the titanite (U-Th)/He thermochronometer.

Sequential Determination of U and Th Decay Series in Santana Cave, Southwest Brazil

NASA Astrophysics Data System (ADS)

Silva, P. S. C.; Damatto, S. R.; Mazzilli, B. P.

2008-08-01

Parque Estadual Turístico do Alto Ribeira (PETAR) is located in the South-western part of São Paulo State, in the Ribeira Valley. In this national state park a large number of caves are found, which are among the most visited of the country. These caves, located in a karstic zone, are characterized by the presence of carbonaceous rocks frequently fractured and collapsed. Although, carbonates (dolomites and calcitic rocks) usually have low U content, this element can be found in the structure of the surrounding rocks. This paper aims to determine 238U, 234U, 226Ra and 210Pb concentration in samples of rock, soil, river water and sediment, in Santana cave. The radionuclide 238U was determined by alpha spectrometry using a surface barrier detector. 226Ra and 210Pb were determined by measuring the gross alpha and beta activity on a gas flow proportional counter.

In-Situ Apatite Laser Ablation U-Th-Sm/He Dating, Methods and Challenges

NASA Astrophysics Data System (ADS)

Pickering, J. E.; Matthews, W.; Guest, B.; Hamilton, B.; Sykes, C.

2015-12-01

In-situ, laser ablation U-Th-Sm/He dating is an emerging technique in thermochronology that has been proven as a means to date zircon and monzonite1-5. In-situ U-Th-Sm/He thermochronology eliminates many of the problems and inconveniences associated with traditional, whole grain methods, including; reducing bias in grain selection based on size, shape and clarity; allowing for the use of broken grains and grains with inclusions; avoiding bad neighbour effects; and eliminating safety hazards associated with dissolution. In-situ apatite laser ablation is challenging due to low concentrations of U and Th and thus a low abundance of radiogenic He. For apatite laser ablation to be effective the ultra-high-vacuum (UHV) line must have very low and consistent background levels of He. To reduce He background, samples are mounted in a UHV stable medium. Our mounting process uses a MicroHePP (Microscope Mounted Heated Platen Press) to press samples into FEP (fluorinated ethylene propylene) bonded to an aluminum backing plate. Samples are ablated using a Resonetics 193 nm excimer laser and liberated He is measured using a quadrupole mass spectrometer on the ASI Alphachron noble gas line; collectively this system is known as the Resochron. The ablated sites are imaged using a Zygo Zescope optical profilometer and ablated pit volume measured using PitVol, a custom MatLab algorithm developed to enable precise and unbiased measurement of the ablated pit geometry. We use the well-characterized Durango apatite to demonstrate the accuracy and precision of the method. He liberated from forty-two pits, having volumes between 1700 and 9000 um3, were measured using the Resochron. The ablated sites were imaged using a Zygo Zescope optical profilometer and ablated pit volume measured using PitVol. U, Th and Sm concentrations were measured by laser ablation and the U-Th-Sm/He age calculated by standard age equation. An age of 33.8±0.31 Ma was determined and compares well with conventional U-Th/He methods, whole grain degassing and dissolution, that produced an age of 32.73±0.47 Ma for chips of the same Durango crystal. Further dating of other well characterized apatite crystals will be used to test the robustness of the method.

8. PHOTOGRAPHIC COPY OF AERIAL PHOTOGRAPH, DATED CA. 19201925, FORT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. PHOTOGRAPHIC COPY OF AERIAL PHOTOGRAPH, DATED CA. 1920-1925, FORT BLISS, ARROW POINTS TO 7TH CAVALRY CANTONMENT, COPY ON FILE IN THE ENVIRONMENTAL MANAGEMENT OFFICE, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

11. PHOTOGRAPHIC COPY OF ORIGINAL PHOTOGRAPH, DATED APRIL 29, 1926, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. PHOTOGRAPHIC COPY OF ORIGINAL PHOTOGRAPH, DATED APRIL 29, 1926, 7TH CAVALRY CANTONMENT MESS HALL, NATIONAL ARCHIVES PHOTOGRAPH, RECORD GROUP 92, GEOGRAPHIC FILE, 1922-1935, No. 600-1, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

Measuring U-series Disequilibrium in Weathering Rinds to Study the Influence of Environmental Factors to Weathering Rates in Tropical Basse-Terre Island (French Guadeloupe)

NASA Astrophysics Data System (ADS)

Guo, J.; Ma, L.; Sak, P. B.; Gaillardet, J.; Chabaux, F. J.; Brantley, S. L.

2015-12-01

Chemical weathering is a critical process to global CO2 consumption, river/ocean chemistry, and nutrient import to biosphere. Weathering rinds experience minimal physical erosion and provide a well-constrained system to study the chemical weathering process. Here, we applied U-series disequilibrium dating method to study weathering advance rates on the wet side of Basse-Terre Island, French Guadeloupe, aiming to understand the role of the precipitation in controlling weathering rates and elucidate the behavior and immobilization mechanisms of U-series isotopes during rind formation. Six weathering clasts from 5 watersheds with mean annual precipitation varying from 2000 to 3000 mm/yr were measured for U-series isotope ratios and major element compositions on linear core-to-rind transects. One sample experienced complete core-to-rind transformation, while the rest clasts contain both rinds and unweathered cores. Our results show that the unweathered cores are under U-series secular equilibrium, while all the rind materials show significant U-series disequilibrium. For most rinds, linear core-to-rind increases of (230Th/232Th) activity ratios suggest a simple continuous U addition history. However, (234U/238U) and (238U/232Th) trends in several clasts show evidences of remobilization of Uranium besides the U addition, complicating the use of U-series dating method. The similarity between U/Th ratios and major elements trends like Fe, Al, P in some transects and the ongoing leaching experiments suggest that redox and organic colloids could control the mobilization of U-series isotopes in the rinds. Rind formation ages and weathering advance rate (0.07-0.29mm/kyr) were calculated for those rinds with a simple U-addition history. Our preliminary results show that local precipitation gradient significantly influenced the weathering advance rate, revealing the potential of estimating weathering advance rates at a large spatial scale using the U-series dating method.

Fires. A Joint Publication for U.S. Artillery Professionals. May-June 2011

DTIC Science & Technology

2011-05-01

DATE MAY 2011 2. REPORT TYPE 3. DATES COVERED 00-05-2011 to 00-06-2011 4. TITLE AND SUBTITLE Fires. A Joint Publication for U.S. Artillery...celebration in front of the original School of Fire, which dates back to 1911. (Photo by Keith Pannell, U.S. Army) 3 sill-www.army.mil/firesbulletin... date ) in the photograph - for example: “SGT Joe B. Smith, C/2-20 Fires, 4th Fires Brigade, fires the M777A2 howitzer during unit qualification

Abrupt Climate Change in the Southern Great Plains during the Last Glacial Interval

NASA Astrophysics Data System (ADS)

Housson, A. L.; Maupin, C. R.; Roark, B.; Shen, C. C.; Baykara, O.; White, K.; Kampen-Lewis, S. V.; McChesney, C. L.

2016-12-01

Understanding how the climate of the North American Great Plains may change in the future is of tremendous socioeconomic importance, yet the regional response to previous abrupt global climate events, such as the Dansgaard-Oeschger (DO) cycles of the last glacial interval, are poorly known. Here we present two absolutely dated (U/Th), partially replicated oxygen isotope (δ18O) records from calcite speleothems in central Texas (30° N, 98° W) that grew during marine isotope stage 3 (MIS 3) (31 to 49 ky BP). The study site experiences boreal spring and fall maxima in precipitation with rainfall moisture sourced almost exclusively from the Gulf of Mexico. The two samples exhibit reproducible δ18O means and variability during overlapping growth intervals. Weak correlations between paired oxygen and carbon isotopic values coupled with reproducible δ18O strongly suggest that dripwater δ18O and calcite formation temperatures are the primary drivers of speleothem δ18O variations through time. We interpret more depleted (enriched) δ18O values to reconstruct warmer and wetter (cooler and drier) conditions based on observations of modern rainfall stable isotope variations at the study site. We find that warmer and wetter conditions in the Southern Plains are contemporaneous with MIS 3 DO interstadials, while cooler and more arid conditions prevail during stadials and Heinrich Events 4 and 5. Our results show a response opposite that of hydrologic reconstructions from the American Southwest, where wetter conditions occur with stadial conditions. Future work includes exploration of paleoclimate model results to examine potential mechanisms responsible for this opposite phasing. Our speleothem data indicate that further intensification of rainy seasons in the Southern Plains should not be ruled out as a response to anthropogenic global warming.

Ice cores and calcite precipitates from alpine ice caves as useful proxies in paleoclimate reconstructions

NASA Astrophysics Data System (ADS)

Colucci, Renato R.; Barbante, Carlo; Bertò, Michele; Dreossi, Giuliano; Festi, Daniela; Forte, Emanuele; Gabrieli, Jacopo; Guglielmin, Mauro; Lenaz, Davide; Luetscher, Marc; Maggi, Valter; Princivalle, Francesco; Schwikowski, Margit; Stenni, Barbara; Žebre, Manja

2017-04-01

In the last years a growing set of research campaigns have been undertaken in the European southeastern Alps. The aim of such interest is mainly due to the peculiar climatic conditions of this area, allowing the existence of periglacial and glacial evidence at the lowest altitude in the Alps. The reason for such "anomaly" is likely ascribable to very high mean annual precipitation and local topoclimatic amplifications. In the frame of this research, in the fall 2013 a 7.8 m long ice-core has been extracted from a permanent cave ice deposit located in the area of Mt. Canin (2,587 masl) in the Julian Alps. The ice-core has been cut and analysed in terms of: a) oxygen and hydrogen isotope composition; b); black carbon and dust concentrations; c) water conductivity; d) mineralogical analyses via X-ray powder diffraction. In the fall 2016, in the same area, a set of 1.0 m long horizontal ice cores have been extracted in another ice cave deposit, intercepting a preserved layer of coarse cryogenic cave carbonates (CCCcoarse). Such original finding represents the first alpine evidence of in situ CCCcoarse and the first occurrence from the southern side of the Alps. A unique opportunity to better understand the processes associated with the formation of CCCcoarse and the well-preserved status of samples allow planning, besides U/Th datings, several different analyses which may be associated with the precipitation of CCC. Subglacial calcite crusts, widespread in the area, represents a further proxy able to help understanding the evolution of climate during the holocene in this alpine sector. In the light of accelerated climate change we discuss here the potential of this still untapped and fragile cryospheric archives for paleoclimatic reconstructions in high elevated areas of the Alps.

Th-U-total Pb Geochronology of Authigenic Monazite Near the top of the Sturtian-Marinoan Interglacial, Adelaide Rift Complex, South Australia

NASA Astrophysics Data System (ADS)

Mahan, K. H.; Wernicke, B. P.; Jercinovic, M. J.

2007-12-01

The Adelaide Rift Complex in South Australia contains the type sections for Sturtian and Marinoan glacial deposits. The litho- and chemostratigraphy of these deposits play a central role in evaluating global Neoproterozoic ice age hypotheses ("snowball Earth") and Rodinia supercontinent reconstructions, but precise ages on igneous units do not yet exist. We report preliminary results of in situ Th-U-total Pb electron microprobe dating of monazite in sandstones within the Holowilena Ironstone ("older" Sturtian glacial at Enorama Creek) and at the top of the Enorama Shale (youngest pre-Marinoan, interglacial clastics at Elatina Creek). Several distinct populations are recognized. First, rounded cores with high Th, U, and Y + HREE abundances are interpreted as igneous or metamorphic detrital grains and yield ca. 1590 Ma, ca. 1280-1300 Ma, and ca. 1040 Ma dates related to well-known orogenic events in surrounding cratonic regions. A second group also occurs as "cores" but contains significantly lower U and Y + HREE, characteristics that may be indicative of an authigenic origin. Some rounded domains may represent "recycled" authigenic grains and yield dates of ca. 880 Ma and ca. 760 Ma. However, a subset observed in the Enorama sample occurs as very small (~2 x 10 microns), euhedral lathes that are unlikely to have survived a detrital history and yield a date of 680 +/-23 Ma. The youngest population forms very low Th and U, inclusion-rich overgrowths with ca. 500 Ma dates (Delamerian Orogeny) that probably grew hydrothermally. The recognition of "recycled" authigenic monazite further emphasizes the detail in textural and petrological documentation that is required for accurate geochronological interpretations. The date of 680 +/-23 Ma (1) provides an estimate for the age of the base of the Trezona carbon isotopic anomaly just beneath the Marinoan glacial deposits, (2) provides an absolute minimum age constraint on the underlying Sturtian glacial deposits, and (3) is confirming of proposed correlations between type Marinoan deposits and precisely dated glacial deposits in Namibia and China.

75 FR 17742 - Filing Dates for the Georgia Special Election in the 9th Congressional District

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-07

... 9th Congressional District AGENCY: Federal Election Commission. ACTION: Notice of filing dates for special election. SUMMARY: Georgia has scheduled a special general election on May 11, 2010, to fill the U... participate in the Georgia Special General and Special Runoff Elections shall file a 12-day Pre-General Report...

6. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED MAY 15, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED MAY 15, 1919, 7TH CAVALRY CANTONMENT POST EXCHANGE, WAR DEPARTMENT, CONSTRUCTION DIVISION, PLAN No. 357, COPY ON FILE IN THE ENVIRONMENTAL MANAGEMENT OFFICE, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

5. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED JUNE 14, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED JUNE 14, 1919, 7TH CAVALRY CANTONMENT MESS BUILDING, WAR DEPARTMENT, CONSTRUCTION DIVISION, PLAN No. 316A, COPY ON FILE IN THE ENVIRONMENTAL MANAGEMENT OFFICE, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

Paleoclimate and Paleoecology of Central Utah during the Past ≈200,000 Years from Soil Carbonate Pendants

NASA Astrophysics Data System (ADS)

Huth, T.; Cerling, T. E.; Fernandez, D. P.; Mackey, G. N., III; Bowling, D. R.; Marchetti, D. W.; Passey, B. H.

2016-12-01

Understanding the magnitude and duration of past climate events is essential to make accurate predictions about how global climate will vary over the next century. Quantitative paleoclimate records from arid regions are difficult to obtain, often present complex growth histories, and have poor chronologic dating relative to marine sediment archives. Pendants, which are several centimeter thick coatings of soil carbonate formed on the bottoms of boulders, represent a novel source for soil and climate records in arid areas. We developed two high resolution stable isotope paleorecords (C and O) from pendants collected in Utah at Torrey and the University of Utah Rio Mesa research station ≈200 km east of Torrey. The pendants are dense, finely laminated, and formed at >20 cm depth. They were dated by the cosmogenic 3He, U/Th, and radiocarbon methodologies. The pendants have nearly identical C isotope records with a roughly sinusoidal shape. The most negative values (-4‰ VPDB) occur during what we tentatively identify through radiocarbon dates as the Younger Dryas. Plants using the C4 photosynthetic pathway dominate through both records, as demonstrated by δ13C values of -4 to -1‰ (≈70-100% C4 plants). The consistency between these two records meets theoretical expectations that the sites, which sit at similar latitudes, should show similar changes in paleoecology and paleoclimate through time. The oxygen isotope record at Rio Mesa is dynamic and does not match the Torrey record. It ranges from -7 to -13‰ (VPDB) and shows a consistent increase towards the present. At 11 cal yr BP there is a 1.5‰ spike in the record. These patterns are in strong contrast to the Torrey record, which stays between -8 and -9‰ for the entirety of the record. The Torrey record can be reasonably explained through isotopic effects caused by factors like ocean temperature, glaciation extent, and temperature of calcite formation. However, these factors are inadequate to explain the long-term 6‰ and short-term 1.5‰ shifts observed in the Rio Mesa record. The C isotope records indicate both sites experienced similar paleoclimate, which argues against, for example, differences in rainfall amount or intensity. Instead, these data may point to a regional, long-term change in water source or seasonality of calcite or progressive soil erosion.

Uranium series dating of Allan Hills ice

NASA Technical Reports Server (NTRS)

Fireman, E. L.

1986-01-01

Uranium-238 decay series nuclides dissolved in Antarctic ice samples were measured in areas of both high and low concentrations of volcanic glass shards. Ice from the Allan Hills site (high shard content) had high Ra-226, Th-230 and U-234 activities but similarly low U-238 activities in comparison with Antarctic ice samples without shards. The Ra-226, Th-230 and U-234 excesses were found to be proportional to the shard content, while the U-238 decay series results were consistent with the assumption that alpha decay products recoiled into the ice from the shards. Through this method of uranium series dating, it was learned that the Allen Hills Cul de Sac ice is approximately 325,000 years old.

A Uranium-Lead Chronology of Speleothem Deposition in the Canadian Arctic

NASA Astrophysics Data System (ADS)

Gambino, C.; Shakun, J. D.; McGee, D.; Ramezani, J.; Khadivi, S.; Wong, C. I.

2017-12-01

The Artic is one of the fastest warming regions on the planet. Currently much of the Arctic is covered by permafrost, which contains approximately 1,700 gigatons of organic carbon. Permafrost thaw could release a substantial amount of this carbon as greenhouse gases into the atmosphere through microbial decomposition, potentially dramatically amplifying anthropogenic warming. However, the risk of permafrost thaw is uncertain, with models exhibiting a wide range of possibilities. Assessing the stability of permafrost during past interglacial periods enables evaluation of the sensitivity of permafrost to warming. Cave mineral deposits (speleothems) in areas currently covered with permafrost can act as a proxy for past permafrost thaw, as liquid water is one criteria of speleothem growth and thus implies thawed ground conditions. Previous uranium-thorium (U-Th) dating of speleothems (n=67) from a wide range of latitudes and permafrost zones across the southern Canadian Rockies, Northwest Territories, and the northern Yukon suggest deposition during Marine Isotope Stage (MIS) 11 and 13. The majority of U-Th dates of these speleothems, however, exceed the U-Th dating limit of 600 ka. In this study, we apply uranium-lead (U-Pb) geochronology to several of these speleothems to extend the records of speleothem growth further back in time. Initial results include a U-Pb age of 428 ± 14 ka that replicates a previous U-Th age of 416.8 ± 7.9 ka, and U-Pb ages on two other speleothems of 870 ± 100 ka and 1502 ± 30 ka. The results of currently in progress U-Pb analyses and a comparison of results with paleo-temperature and ice volume reconstructions will also be presented.

LA-ICP-MS and SIMS U-Pb and U-Th zircon geochronological data of Late Pleistocene lava domes of the Ciomadul Volcanic Dome Complex (Eastern Carpathians).

PubMed

Lukács, Réka; Guillong, Marcel; Schmitt, Axel K; Molnár, Kata; Bachmann, Olivier; Harangi, Szabolcs

2018-06-01

This article provides laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and secondary ionization mass spectrometry (SIMS) U-Pb and U-Th zircon dates for crystals separated from Late Pleistocene dacitic lava dome rocks of the Ciomadul Volcanic Dome Complex (Eastern Carpathians, Romania). The analyses were performed on unpolished zircon prism faces (termed rim analyses) and on crystal interiors exposed through mechanical grinding an polishing (interior analyses). 206 Pb/ 238 U ages are corrected for Th-disequilibrium based on published and calculated distribution coefficients for U and Th using average whole-rock and individually analyzed zircon compositions. The data presented in this article were used for the Th-disequilibrium correction of (U-Th)/He zircon geochronology data in the research article entitled "The onset of the volcanism in the Ciomadul Volcanic Dome Complex (Eastern Carpathians): eruption chronology and magma type variation" (Molnár et al., 2018) [1].

Measurements of rare isotopes of U and Th by MC-ICP-MS using a 1013 ohm resistor

NASA Astrophysics Data System (ADS)

Pythoud, M.; Edwards, R. L.; Cheng, H.; Lu, Y.; Zhang, P.; Nissen, J.; Berry, A. E.

2016-12-01

We have tested a 1013 ohm resistor on a Thermo-Scientific Neptune Plus, a multi-collector inductively-coupled plasma mass spectrometer (MC-ICP-MS), for the measurement of rare isotopes of uranium (U) and thorium (Th). In nature, the isotopic disequilibrium among U-series nuclides provides the potential to date materials and time processes over the last 700,000 years. Using gravimetric standards and a Minnesota stalagmite, we demonstrate the reproducibility of δ234U and 230Th dates with uncertainties at the 1-‰ to sub-‰ level (2σ), with relatively small samples. Compared to traditional secondary electron multiplier (SEM) techniques, measurement times decrease from > 1 hour to < 5 min for U and from tens of min to < 2 min for Th, with comparable or better precision. The characteristics of the new amplifier design and typical instrumental conditions allow for 234U and 230Th sample loads as small as 1-2 pg, a reduction in sample size close to an order of magnitude over cup measurements with 1011 ohm resistors. The main sources of error include the amplifier noise, uncertainty in the characterization of the tailing effect, and in some cases, counting statistics. Importantly, our overall characterization suggests that this new method forms the basis for future and further improvements on instrumental precision.

Provenance of the lower Miocene of the Gulf of Mexico from detrital zircon double dating

NASA Astrophysics Data System (ADS)

xu, J.

2013-12-01

The lower Miocene interval of the Gulf of Mexico (GOM) has recently gained increasing attention from oil and gas industry due to its hydrocarbon potential below the salt canopy. However, it has been less well studied than both the underlying Oligocene and overlying middle Miocene strata. The lower Miocene worldwide is a transitional period of tectonic, climatic, and oceanographic change. In particular, it is a period of major tectonic reorganization in the western interior of North America (Rocky Mountains), involving a shift from the Oligocene thermal phase, with abundant volcanic activity recorded in the thick Frio/Vicksburg succession of the GOM, to the Miocene Basin-Range extensional phase. Climatic conditions also changed from a relatively arid Oligocene to wetter Miocene, resulting in increased sediment yields from exhumed tectonic structures. Previous provenance studies used proportions of quartz, feldspar and lithic fragments and consideration of likely river courses through known paleogeomorphological elements. Only limited detrital zircon (DZ) U-Pb studies on Paleocene strata have been undertaken and there has been no previous U-Pb and (U-Th)/He double dating in the GOM. In this study we apply the latest analytical approaches, such as DZ U-Pb dating to gain robust source terranes ages and more fully elucidate the complex sediment provenance and dispersal history of GOM. We also employ DZ (U-Th)/He (ZHe) dating, combined with DZ U-Pb, to not only define sedimentary provenance but also the exhumation histories of detrital source regions. Samples of lower Miocene outcrop exposures in Texas and Louisiana have been collected to discriminate the varied tectonic and drainage system changes across the basin in lateral. In addition, samples from the Eocene, Oligocene and middle Miocene have been obtained to reveal vertical shift of source terranes contributions. Our initial age data show detrital zircons of lower Miocene sediments come from a wide range of source terranes including a large populations from the western interior of North America (Rocky Mountains), Grenville, Mid-Continent, and Yavapai-Mazatzal provinces, with smaller populations from the Appalachian-Ouachita, Wyoming or Superior regions. Based on U-Pb dating results, we will carry out (U-Th)/He dating on selected zircons to reveal the detailed exhumation histories of the sediment source regions. Using the dual criteria of DZ crystallization age (U-Pb) and cooling age (U-Th/He) to constrain provenance will enable us to generate rigorous reconstructions of the lower Miocene depositional systems from source terrane to deep-water sink for this key transitional period in geologic history.

In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary

USGS Publications Warehouse

Neymark, Leonid; Holm-Denoma, Christopher S.; Moscati, Richard J.

2018-01-01

Cassiterite (SnO2), a main ore mineral in tin deposits, is suitable for U–Pb isotopic dating because of its relatively high U/Pb ratios and typically low common Pb. We report a LA-ICPMS analytical procedure for U–Pb dating of this mineral with no need for an independently dated matrix-matched cassiterite standard. LA-ICPMS U-Th-Pb data were acquired while using NIST 612 glass as a primary non-matrix-matched standard. Raw data are reduced using a combination of Iolite™ and other off-line data reduction methods. Cassiterite is extremely difficult to digest, so traditional approaches in LA-ICPMS U-Pb geochronology that utilize well-characterized matrix-matched reference materials (e.g., age values determined by ID-TIMS) cannot be easily implemented. We propose a new approach for in situ LA-ICPMS dating of cassiterite, which benefits from the unique chemistry of cassiterite with extremely low Th concentrations (Th/U ratio of 10−4 or lower) in some cassiterite samples. Accordingly, it is assumed that 208Pb measured in cassiterite is mostly of non-radiogenic origin—it was initially incorporated in cassiterite during mineral formation, and can be used as a proxy for common Pb. Using 208Pb as a common Pb proxy instead of 204Pb is preferred as 204Pb is much less abundant and is also compromised by 204Hg interference during the LA-ICPMS analyses.Our procedure relies on 208Pb/206Pb vs 207Pb/206Pb (Pb-Pb) and Tera-Wasserburg 207Pb/206Pb vs 238U/206Pb (U-Pb) isochron dates that are calculated for a ~1.54 Ga low-Th cassiterite reference material with varying amounts of common Pb that we assume remained a closed U-Pb system. The difference between the NIST 612 glass normalized biased U-Pb date and the Pb-Pb age of the reference material is used to calculate a correction factor (F) for instrumental U-Pb fractionation. The correction factor (F) is then applied to measured U/Pb ratios and Tera-Wasserburg isochron dates are obtained for the unknown cassiterite analyzed in the same analytical session. This allows for U-Pb dating of cassiterite of any age with no need for an independently dated matrix-matched reference material, nor assumptions about the isotopic composition of common Pb.Results for cassiterite from tin deposits in Bolivia, Brazil, China, Russia, Saudi Arabia, South Africa, Spain, and the United Kingdom, with ages ranging from ~20 Ma to ~2060 Ma, demonstrate the applicability of this approach across a broad range of geologic time. These ages are in good agreement with published geochronology of the host rocks associated with the tin deposits and with previously published U-Pb ages of some cassiterites from the same deposits. Thus, our in situ LA-ICPMS methodology verifies the use of cassiterite as a reliable U-Pb mineral-geochronometer with the advantages of fast and relatively low cost in situ analyses with moderate spatial resolution.

CO2 outburst events in relation to seismicity: Constraints from microscale geochronology, geochemistry of late Quaternary vein carbonates, SW Turkey

NASA Astrophysics Data System (ADS)

Ünal-İmer, Ezgi; Uysal, I. Tonguç; Zhao, Jian-Xin; Işık, Veysel; Shulmeister, James; İmer, Ali; Feng, Yue-Xing

2016-08-01

Vein and breccia carbonates precipitated in a highly fractured/faulted carbonate bedrock in SW Turkey were investigated through high-resolution U-series geochronology, microstructural and geochemical studies including C-O-Sr isotope and rare-earth element and yttrium (REY) analyses. Petrographical observations and geochronological data are interpreted as evidence that the calcite veins formed through a crack-seal mechanism, mostly accompanied/initiated by intensive hydraulic fracturing of the host limestone in response to high-pressure fluids, which is manifested by multi-stage breccia deposits. Microscale U-series dates (272.6-20.5 kyr) and geochemical compositions of the vein/breccia samples provide information on the timing and mechanism of the vein formation and identify the source of CO2-bearing fluids responsible for the carbonate precipitation. δ18OVPDB and δ13CVPDB values of the calcite veins range between -5.9 and -1.7‰, and -10.6 and -4.6‰, respectively. The isotopic compositions of the veins show highly fluctuating values as calcite grew successively perpendicular to vein walls, which, in combination with microstructural and geochronological constraints, are interpreted to reflect episodic CO2 degassing events associated with seismic and aseismic deformation. Oxygen and Sr isotope compositions (δ18OVPDB: -5.9 to -1.7‰; 87Sr/86Sr: 0.7082 to 0.7085) together with REY concentrations indicate deep infiltration of meteoric waters with various degrees of interactions mostly with the host limestone and siliciclastic parts of the basement rocks. Oxygen and carbon isotope compositions suggest CO2 degassing through intensive limestone dissolution. While majority of the veins display similar Post-Archaean Australian Shale (PAAS)-normalised REY variations, some of the veins show positive EuPAAS anomalies, which could be indicative of contributions from a deeply derived, heated, and reduced fluid component, giving rise to multiple fluid sources for the calcite veins. Vein calcite formed in fault-induced fractures offers insights into structural features, genetic characterisation of the parental fluids, and late Quaternary degassing of subsurface CO2 accumulations.

Late accretion to the Moon recorded in zircon (U-Th)/He thermochronometry

NASA Astrophysics Data System (ADS)

Kelly, Nigel M.; Flowers, Rebecca M.; Metcalf, James R.; Mojzsis, Stephen J.

2018-01-01

We conducted zircon (U-Th)/He (ZHe) analysis of lunar impact-melt breccia 14311 with the aim of leveraging radiation damage accumulated in zircon over extended intervals to detect low-temperature or short-lived impact events that have previously eluded traditional isotopic dating techniques. Our ZHe data record a coherent date vs. effective Uranium concentration (eU) trend characterized by >3500 Ma dates from low (≤75 ppm) eU zircon grains, and ca. 110 Ma dates for high (≥100 ppm) eU grains. A progression between these date populations is apparent for intermediate (75-100 ppm) eU grains. Thermal history modeling constrains permissible temperatures and cooling rates during and following impacts. Modeling shows that the data are most simply explained by impact events at ca. 3950 Ma and ca. 110 Ma, and limits allowable temperatures of heating events between 3950-110 Ma. Modeling of solar cycling thermal effects at the lunar surface precludes this as the explanation for the ca. 110 Ma ZHe dates. We propose a sample history characterized by zircon resetting during the ca. 3950 Ma Imbrium impact event, with subsequent heating during an impact at ca. 110 Ma that ejected the sample to the vicinity of its collection site. Our data show that zircon has the potential to retain 4He over immense timescales (≥3950 Myrs), thus providing a valuable new thermochronometer for probing the impact histories of lunar samples, and martian or asteroidal meteorites.

U-Th dating of carbonate crusts reveals Neandertal origin of Iberian cave art.

PubMed

Hoffmann, D L; Standish, C D; García-Diez, M; Pettitt, P B; Milton, J A; Zilhão, J; Alcolea-González, J J; Cantalejo-Duarte, P; Collado, H; de Balbín, R; Lorblanchet, M; Ramos-Muñoz, J; Weniger, G-Ch; Pike, A W G

2018-02-23

The extent and nature of symbolic behavior among Neandertals are obscure. Although evidence for Neandertal body ornamentation has been proposed, all cave painting has been attributed to modern humans. Here we present dating results for three sites in Spain that show that cave art emerged in Iberia substantially earlier than previously thought. Uranium-thorium (U-Th) dates on carbonate crusts overlying paintings provide minimum ages for a red linear motif in La Pasiega (Cantabria), a hand stencil in Maltravieso (Extremadura), and red-painted speleothems in Ardales (Andalucía). Collectively, these results show that cave art in Iberia is older than 64.8 thousand years (ka). This cave art is the earliest dated so far and predates, by at least 20 ka, the arrival of modern humans in Europe, which implies Neandertal authorship. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

Speleothem chronology with sub-annual resolution in a near-entrance cave setting using oxygen isotope and trace element records

NASA Astrophysics Data System (ADS)

Carlson, P. E.; Miller, N. R.; Banner, J.; Breecker, D.

2016-12-01

Speleothems that grow in well-ventilated zones of caves are typically avoided when selecting specimens for paleoclimate reconstruction, due to concerns about evaporation and kinetic isotope effects. Near-entrance cave environments are characterized by near-ambient CO2 concentrations year-round and are influenced by surface temperature fluctuations. At Westcave Preserve (Westcave), a shallow, well-ventilated cave in central Texas, we have found seasonal temperature differences recorded in both the oxygen isotope and trace element compositions of speleothem calcite. The seasonal nature of these records has been confirmed by monitoring the chemical composition of drip water and substrate calcite since 2009 (Feng et al., 2014; Casteel and Banner, 2015). We present an ultrahigh-resolution (weekly to monthly) record of δ18O, Mg, Sr, and Ba in Westcave stalagmite WC-3, as well as monthly measurements of drip water geochemistry. We find drip water δ18O and [Mg] are essentially invariant, while seasonal variations in stalagmite calcite δ18O and Mg compositions are in good agreement with predicted temperature-dependent fractionation between water and calcite. Both drip water and speleothem calcite Sr and Ba vary seasonally, which we hypothesize is due to seasonal changes in moisture conditions in the epikarst. We use each of these annual geochemical cycles as independent chronological controls in order to develop a single age model for the stalagmite. These independent chronological counts are consistent with each other, and with 14C bomb-peak and U-series evidence. We argue that the potential for this kind of multi-proxy, seasonally-resolved dating in near-entrance stalagmites makes them especially valuable paleoclimate archives that should not be ignored in speleothem studies.

Uranium series, volcanic rocks

USGS Publications Warehouse

Vazquez, Jorge A.

2014-01-01

Application of U-series dating to volcanic rocks provides unique and valuable information about the absolute timing of crystallization and differentiation of magmas prior to eruption. The 238U–230Th and 230Th-226Ra methods are the most commonly employed for dating the crystallization of mafic to silicic magmas that erupt at volcanoes. Dates derived from the U–Th and Ra–Th methods reflect crystallization because diffusion of these elements at magmatic temperatures is sluggish (Cherniak 2010) and diffusive re-equilibration is insignificant over the timescales (less than or equal to 10^5 years) typically associated with pre-eruptive storage of nearly all magma compositions (Cooper and Reid 2008). Other dating methods based on elements that diffuse rapidly at magmatic temperatures, such as the 40Ar/39Ar and (U–Th)/He methods, yield dates for the cooling of magma at the time of eruption. Disequilibrium of some short-lived daughters of the uranium series such as 210Po may be fractionated by saturation of a volatile phase and can be employed to date magmatic gas loss that is synchronous with volcanic eruption (e.g., Rubin et al. 1994).

Palaeoredox indicators from the organic-rich Messinian early post-evaporitic deposits of the Apennines (Central Italy)

NASA Astrophysics Data System (ADS)

Sampalmieri, G.; Iadanza, A.; Cipollari, P.; Cosentino, D.; Lo Mastro, S.

2009-04-01

Bottom redox conditions in marine and lacustrine ancient basins are often inferred by the occurrence of peculiar sedimentological structures and microfaunal assemblages. The co-occurrence, in such environments, of authigenic uranium, framboidal pyrite, barite and Fe-Mn nodules and encrustations, provides a good constraint for palaeo reconstructions. Authigenic uranium is a common constituent of hydrocarbon source rocks: it forms at the sediment-water interface under oxygen-deficient conditions and accumulates together with organic matter (OM). Its precipitation is triggered by the reduction of the soluble U6+ion in seawater to insoluble U4+. With respect to black shales, uranium content has even been used to estimate the TOC. Also authigenic pyrite forms under anoxic conditions and replaces organic matter: 1) the increase in pyrite content and in organic matter are directly correlated; 2) the size distribution of framboidal pyrite (consistent with sulphate-reducing bacterial activity) is considered a measure of redox conditions within the sediment. Barite is an authigenic mineral related to Corg content, since its organic precipitation is triggered by sulphate-reduction processes occurring in decaying OM-bearing microenvironments. Finally, also Fe-Mn oxyhydroxide are typical indicators of redox conditions. About 6 My ago the Mediterranean Sea underwent a giant event of concentration referred to as Messinian Salinity Crisis, which can be roughly subdivided into an evaporitic and a post evaporitic phase. The post evaporitic phase (p-ev; 5.61-5.33 Ma) developed in a context of humid conditions and can be further distinguished into two steps: p-ev1 (early post evaporitic phase) and p-ev2 (late post evaporitic phase). Previous works focused on pev2, which is interpreted to represent the establishment of brackish water conditions (Lago-Mare biofacies). In other respects, the palaeoenvironment of p-ev1 deposits, mostly represented by resedimented evaporitic deposits or barren laminated sediments, hasn't been thoroughly clarified yet. The aim of the present study, dealing with messinian p-ev1 deposits from Marche and Maiella successions, is to provide more details in the definition of the environment developed during the early post-evaporitic phase. Since the lamination and the absence of benthic fauna suggest the occurrence of anoxic conditions, the following indirect proxies for the detection of organic matter have been investigated: 1) sedimentary fabric and microfacies; 2) framboidal pyrite size distribution; 3) natural radioactivity (authigenic uranium values, Th/U ratios). Natural radioactivity has been achieved through gamma spectrometry, with field and laboratory specific techniques. In the Maccarone section (Marche region), p-ev1 deposits are constituted by: barren greyish shales; laminated black shales interbedded with calcitic and ankeritic horizons; thin intercalations of sandstones. Organic-matter and framboidal pyrite commonly occur. Size analysis of framboids populations yielded a mean diameter of 4÷8 m, typical of disaerobic facies. Microfacies analysis yielded also the presence of crystals aggregates of barite, up to 50 m in size, and of isolated detrital (silicilastic) crystals. Without considering γ-ray values of the volcaniclastic layer (52-65 Cps) occurring within the p-ev1 interval, black shales horizons revealed the maximum natural radioactivity (NRD of about 50 Cps) recorded inthe studied section. Lower γ-activity characterizes the calcitic layers (i.e. "Colombacci") and the ankerites. Field NRD spectra acquired on different lithologies, showed variable contributions of 238U, 232Th and 40K. Both the blue-greyish shales and the black shales are characterized by total NRD related to the three main radioelements: 40K is associated to abundant 238U content (Thppm/Uppm 1). The 238U content is primarily referable to processes of organic matter enrichment (authigenic uranium) and secondarily to the input of detrital grains. In contrast, 40K and 232Th are entirely ascribed to the clastic fraction. P-ev1 deposits from Maiella section consist of thinly-laminated grey-brownish pelites, enclosing carbonatic lenses and interrupted horizons. The pelitic fraction contains Fe-Mn-Ni encrustated micronodules. The carbonate portion is made up of locally brecciated calcitic limestones, associated with calcitic concretions and discontinuous laminae. Traces of organic matter and bitumen have been observed in thin section. Framboidal pyrite occurs both as single element and as aggregate, reaching dimensions up to about 10 m. Barite and celestite occur as well. NRD measurements yielded high values of radioactivity both in carbonates (20-63 Cps) and in terrigenous sediments (21-70 Cps). Limestones NRD-spectra showed a 238U-dominant (5 ppm in content) radioactivity. 238U is totally referable to an authigenic origin, since the γ-activity of limestones is devoid of contributions from 40K and 232Th (proxies for the detritic fraction). In the latest Messinian frame, authigenic uranium, barite, ankerite, Fe-Mn oxyhydroxide and framboidal pyrite indicate strongly palaeoredox conditions (from disaerobic to fully anoxic). In particular, with respect to NRD data, this peculiar environment is confirmed by the Th/U ratio, mostly

Castiglione (Oletta, Corsica): relationships between phenomena of calcification and tectonic fossiliferous fracture dating

NASA Astrophysics Data System (ADS)

Pereira, Elisabeth; Rouzaud, François; Salotti, Michelle; Dubois, Jean-Noël; Ferrandini, Jean; Ottaviani-Spella, Marie-Madeleine; Quinif, Yves

Six cavities have been discovered in the Oletta massif. The massif, today constitued of Schistes lustrés with several metres of calcareous layers above them, has undergone intense fracturing. The networks of cavities are organised along north-south and subequatorial directions, and form a narrow bayonnet-network. All the elements in the galleries appear to be karstic: stalagmites, stalactites and calcitic deposits along the walls; but no trace of dissolution or excavation was found. Thus, the origin of the galleries is only tectonic, while the calcitic deposits result from the dissolution of the old, thick calcareous layers above, which are no longer present. The thickness and the volume of the calcitic deposits, which is variable depending on the galleries, indicates the chronology of the different tectonic periods which have fractured the massif. Five tectonic and successsive events have been detected. Calcitic datings confirm the timing of successional fracturing, indicating also the variable age of the fossiliferous Middle Pleistocene deposits found in these cavities.

Sequential Determination of U and Th Decay Series in Santana Cave, Southwest Brazil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Silva, P. S. C.; Damatto, S. R.; Mazzilli, B. P.

2008-08-07

Parque Estadual Turistico do Alto Ribeira (PETAR) is located in the South-western part of Sao Paulo State, in the Ribeira Valley. In this national state park a large number of caves are found, which are among the most visited of the country. These caves, located in a karstic zone, are characterized by the presence of carbonaceous rocks frequently fractured and collapsed. Although, carbonates (dolomites and calcitic rocks) usually have low U content, this element can be found in the structure of the surrounding rocks. This paper aims to determine {sup 238}U, {sup 234}U, {sup 226}Ra and {sup 210}Pb concentration inmore » samples of rock, soil, river water and sediment, in Santana cave. The radionuclide {sup 238}U was determined by alpha spectrometry using a surface barrier detector. {sup 226}Ra and {sup 210}Pb were determined by measuring the gross alpha and beta activity on a gas flow proportional counter.« less

Rapid evolution of ritual architecture in central Polynesia indicated by precise 230Th/U coral dating.

PubMed

Sharp, Warren D; Kahn, Jennifer G; Polito, Christina M; Kirch, Patrick V

2010-07-27

In Polynesia, the complex Society Islands chiefdoms constructed elaborate temples (marae), some of which reached monumental proportions and were associated with human sacrifice in the 'Oro cult. We investigated the development of temples on Mo'orea Island by 230Th/U dating of corals used as architectural elements (facing veneers, cut-and-dressed blocks, and offerings). The three largest coastal marae (associated with the highest-ranked chiefly lineages) and 19 marae in the inland 'Opunohu Valley containing coral architectural elements were dated. Fifteen corals from the coastal temples meet geochemical criteria for accurate 230Th/U dating, yield reproducible ages for each marae, and have a mean uncertainty of 9 y (2sigma). Of 41 corals from wetter inland sites, 12 show some diagenesis and may yield unreliable ages; however, the majority (32) of inland dates are considered accurate. We also obtained six 14C dates on charcoal from four marae. The dates indicate that temple architecture on Mo'orea Island developed rapidly over a period of approximately 140 y (ca. AD 1620-1760), with the largest coastal temples constructed immediately before initial European contact (AD 1767). The result of a seriation of architectural features corresponds closely with this chronology. Acropora coral veneers were superceded by cut-and-dressed Porites coral blocks on altar platforms, followed by development of multitier stepped altar platforms and use of pecked basalt stones associated with the late 'Oro cult. This example demonstrates that elaboration of ritual architecture in complex societies may be surprisingly rapid.

Rapid evolution of ritual architecture in central Polynesia indicated by precise 230Th/U coral dating

PubMed Central

Sharp, Warren D.; Kahn, Jennifer G.; Polito, Christina M.; Kirch, Patrick V.

2010-01-01

In Polynesia, the complex Society Islands chiefdoms constructed elaborate temples (marae), some of which reached monumental proportions and were associated with human sacrifice in the ‘Oro cult. We investigated the development of temples on Mo‘orea Island by 230Th/U dating of corals used as architectural elements (facing veneers, cut-and-dressed blocks, and offerings). The three largest coastal marae (associated with the highest-ranked chiefly lineages) and 19 marae in the inland ‘Opunohu Valley containing coral architectural elements were dated. Fifteen corals from the coastal temples meet geochemical criteria for accurate 230Th/U dating, yield reproducible ages for each marae, and have a mean uncertainty of 9 y (2σ). Of 41 corals from wetter inland sites, 12 show some diagenesis and may yield unreliable ages; however, the majority (32) of inland dates are considered accurate. We also obtained six 14C dates on charcoal from four marae. The dates indicate that temple architecture on Mo‘orea Island developed rapidly over a period of approximately 140 y (ca. AD 1620–1760), with the largest coastal temples constructed immediately before initial European contact (AD 1767). The result of a seriation of architectural features corresponds closely with this chronology. Acropora coral veneers were superceded by cut-and-dressed Porites coral blocks on altar platforms, followed by development of multitier stepped altar platforms and use of pecked basalt stones associated with the late ‘Oro cult. This example demonstrates that elaboration of ritual architecture in complex societies may be surprisingly rapid. PMID:20616079

The nature of annual lamination in flowstones from non-karstic fractures, Vinschgau (northern Italy)

NASA Astrophysics Data System (ADS)

Koltai, Gabriella; Spötl, Christoph; Cheng, Hai

2016-04-01

The Vinschgau is an inneralpine valley in the Southern Alps. The region is built up by metamorphic rocks characterised by a high degree of tectonic deformation. Although karst is not known in the Vinschgau, calcite and calcite-aragonite flowstones are deposited from supersaturated groundwater along the South-facing mountain slope as a result of strong evaporation (Spötl et al. 2002). Flowstone precipitation is strongly connected to fracture openings created by deep-seated gravitational slope deformations. The carbonate-depositing springs are part of an extended groundwater system controlled by the geometry of the deep-seated gravitational slope deformation. Although the mean residence time of the groundwater is up to several decades (Spötl et al. 2002), a few flowstones show macroscopically visible laminae whose annual origin is confirmed by U-Th dating. These laminae are composed of a darker and a lighter sublamina forming couplets whose thickness ranges from 0.2 to 2 mm. In thin section, the darker sublaminae show a higher abundance of opaque particles, whereas the light ones are inclusion-poor. Strong epifluorescence confirms the organic origin of these dark inclusions. The crystal fabric, dominated by the fascicular-optic type, shows no change across lamina boundaries. Laminated calcite shows δ18O oscillations with an amplitude of up to 1.4 permil. These oscillations are also present in unlaminated calcite, albeit at much smaller amplitude. δ13C lacks such a regular pattern in laminated samples, and only shows small variations which do not correlate with δ18O in a consistent way. Changes in δ13C show smaller amplitudes than δ18O. The extent of correlation between petrographic laminae and the stable isotopes varies both in time and space. During the late Younger Dryas darker sublaminae mostly coincide with δ18O lows, whereas in the Mid-Holocene they usually correlate with isotope highs. These data reflect the high degree of heterogeneity of such fracture zones in deep-seated gravitational slope deformations. The annual signal is still preserved by the δ18O values, but the development of laminae varies both in space and time. Spötl, C., Unterwurzacher, M., Mangini, A., Longstaffe, F.J., 2002: Carbonate speleothems in the dry, inneralpine Vinschgau Valley, northernmost Italy: Witnesses of changes in climate and hydrology since the Last Glacial Maximum. Journal of Sedimentary Research, 72, 793-808.

U-series dating of Paleolithic art in 11 caves in Spain.

PubMed

Pike, A W G; Hoffmann, D L; García-Diez, M; Pettitt, P B; Alcolea, J; De Balbín, R; González-Sainz, C; de las Heras, C; Lasheras, J A; Montes, R; Zilhão, J

2012-06-15

Paleolithic cave art is an exceptional archive of early human symbolic behavior, but because obtaining reliable dates has been difficult, its chronology is still poorly understood after more than a century of study. We present uranium-series disequilibrium dates of calcite deposits overlying or underlying art found in 11 caves, including the United Nations Educational, Scientific, and Cultural Organization (UNESCO) World Heritage sites of Altamira, El Castillo, and Tito Bustillo, Spain. The results demonstrate that the tradition of decorating caves extends back at least to the Early Aurignacian period, with minimum ages of 40.8 thousand years for a red disk, 37.3 thousand years for a hand stencil, and 35.6 thousand years for a claviform-like symbol. These minimum ages reveal either that cave art was a part of the cultural repertoire of the first anatomically modern humans in Europe or that perhaps Neandertals also engaged in painting caves.

Uranium-234 anomalies in corals older than 150,000 years

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bard, E.; Fairbanks, R.G.; Zindler, A.

1991-08-01

The authors present new precise U-Th ages of well-preserved coral specimens collected from the island of Barbados, West Indies, and the atoll of Mururoa, French Polynesia. Their new data confirm the ages attributed to oxygen isotope stage 7 in the framework of the Milankovitch theory. By using thermal ionization mass spectrometry (TIMS), it is also possible to quantify precisely the [sup 234]U/[sup 238]U ratios in corals. Samples older than 150 kyr B.P. are shown to be characterized by significant excesses of [sup 234]U relative to the uranium isotopic composition expected if the corals grew in present-day sea water. Assuming thatmore » the [sup 230]Th-ingrowth ages are accurate, these anomalies translate into high initial [sup 234]U/[sup 238]U ratios: about 1.2 at 200 kyr and up to 1.5 at about 450 kyr B.P. They propose that the anomalies result from both diagenetic addition and replacement of U and possibly from global changes in the [sup 234]U/[sup 238]U composition of the sea water through time. The [sup 234]U anomalies cast doubt on the accuracy of the classical [sup 230]Th-ingrowth dating method in old corals, and in particular for the use of measured [sup 234]U/[sup 238]U ratios alone to date corals older than 150 kyr.« less

Rb-Sr and Sm-Nd Isotopic Studies of Martian Depleted Shergottes SaU 094/005

NASA Technical Reports Server (NTRS)

Shih, C.-Y.; Nyquist, L. E.; Reese, Y.

2007-01-01

Sayh al Uhaymir (SaU) 094 and SaU 005 are olivine-phyric shergottites from the Oman desert and are considered as pairs. [e.g., 1]. They are very similar to the Libyan desert shergottite Dar al Gani (DaG) 476 in petrology, chemistry and ejection age [2-6]. This group of shergottites, also recognized as depleted shergottites [e.g. 7] has been strongly shocked and contains very low abundances of light rare earth elements (REE). In addition, terrestrial contaminants are commonly present in meteorites found in desert environments. Age-dating these samples is very challenging, but lower calcite contents in the SaU meteorites suggest that they have been subjected to less severe desert weathering than their DaG counterparts [3-4]. In this report, we present Rb-Sr and Sm-Nd isotopic results for SaU 094 and SaU 005, discuss the correlation of their ages with those of other similar shergottites, and discuss their petrogenesis.

The chronology of hand stencils in European Palaeolithic rock art: implications of new U-series results from El Castillo Cave (Cantabria, Spain).

PubMed

García-Diez, Marcos; Garrido, Daniel; Hoffmann, Dirk; Pettitt, Paul; Pike, Alistair; Zilhão, Joao

2015-07-20

The hand stencils of European Paleolithic art tend to be considered of pre-Magdalenian age and scholars have generally assigned them to the Gravettian period. At El Castillo Cave, application of U-series dating to calcite accretions has established a minimum age of 37,290 years for underlying red hand stencils, implying execution in the earlier part of the Aurignacian if not beforehand. Together with the series of red disks, one of which has a minimum age of 40,800 years, these motifs lie at the base of the El Castillo parietal stratigraphy. The similarity in technique and colour support the notion that both kinds of artistic manifestations are synchronic and define an initial, non-figurative phase of European cave art. However, available data indicate that hand stencils continued to be painted subsequently. Currently, the youngest, reliably dated examples fall in the Late Gravettian, approximately 27,000 years ago.

Helium diffusion experiments on synthetic apatite crystals and single-grain fragments: can we retrieve the He diffusion profiles?

NASA Astrophysics Data System (ADS)

Kasanzu, C.; Beucher, R.; Brown, R. W.; Persano, C.; Stuart, F.

2011-12-01

Apatite (U-Th)/he thermochronometry is one of the most widely used methods of quantifying thermal histories of rocks within the vicinity of the surface. Theoretical and practical development carried out during the last decade, among which was the release of affordable LASERs, have led to standard practice of analyzing single grain rather than multigrain aliquots. The standard theoretical basis for interpreting these ages assumes that the technique is used on full grains. However, the natural weak cleavage of apatite leads to fragmentation of these individual prismatic crystals during the rock crushing and mineral separation process. Apatites are most often broken along a weak cleavage perpendicular to the c-axis. It is therefore common practice to analyze fragments of whole grains, not complete crystals. It is also well known that dating often leads to single ages being more dispersed than expected whatever the efforts to avoid perturbations on the He system. Using a theoretical numerical model and considering both axial and radial diffusion, we demonstrate thata largepart (most?) of the dispersion is due to analyses of single apatite fragments. This effect is larger for older grains which have exprienced a slow cooling history and have well rounded diffusive profiles. Ages are a strongfunction of the fragment size (length specifically), we show that ages from apatite fragments with 1 prismatic termination (1T) can be used to retrieve the helium diffusion profile, provided a sufficient number of single fragment analyses are carried out. The shape of the helium diffusion profile provides a strong constraint on the style of the thermal history and so we propose to use single crystal fragment analyses to extract a mean diffusion profile, and deduce the thermal history of the sample. In order to test these ideas, we performed a set of experiments with natural samples and semi-synthetic grains of apatite. Synthetic grains are obtained by drilling cores of various length/width ratios within standard Durango crystals while natural grains are separated from a deep borehole in south-Africa (BK1) and from the Australian craton. Several experiences are presented: 1) (U-Th)/He dating of about 100 1T single-fragment aliquots of different shape ratio from the BK1 borehole; 2) (U-Th)/He dating of 20 2T single-fragment aliquot from an Australian sample previously dated following standard procedure. 3) (U-Th)/He dating of synthetic fragmentsfrom synthetic grains previously degassed by a known percentageusing a thermo-regulated furnace. The results of the experiments lead to important new insight into the natural dispersion of (U-Th)/He single-grain ages. They show that far from being problematic, highly dispersed data may indeed contain first-order information on the thermal history of rocks. We discuss all the details of the standard (U-Th)/He approach such as the effects of temporally variable diffusivity (e.g. radiation damage models), zonation of U and Th and arbitrary grain size variations.

Spatial variability of initial 230Th/ 232Th in modern Porites from the inshore region of the Great Barrier Reef

NASA Astrophysics Data System (ADS)

Clark, Tara R.; Zhao, Jian-xin; Feng, Yue-xing; Done, Terry J.; Jupiter, Stacy; Lough, Janice; Pandolfi, John M.

2012-02-01

The main limiting factor in obtaining precise and accurate uranium-series (U-series) ages of corals that lived during the last few hundred years is the ability to constrain and correct for initial thorium-230 ( 230Th 0), which is proportionally much higher in younger samples. This is becoming particularly important in palaeoecological research where accurate chronologies, based on the 230Th chronometer, are required to pinpoint changes in coral community structure and the timing of mortality events in recent time (e.g. since European settlement of northern Australia in the 1850s). In this study, thermal ionisation mass spectrometry (TIMS) U-series dating of 43 samples of known ages collected from living Porites spp. from the far northern, central and southern inshore regions of the Great Barrier Reef (GBR) was performed to spatially constrain initial 230Th/ 232Th ( 230Th/ 232Th 0) variability. In these living Porites corals, the majority of 230Th/ 232Th 0 values fell within error of the conservative bulk Earth 230Th/ 232Th atomic value of 4.3 ± 4.3 × 10 -6 (2 σ) generally assumed for 230Th 0 corrections where the primary source is terrestrially derived. However, the results of this study demonstrate that the accuracy of 230Th ages can be further improved by using locally determined 230Th/ 232Th 0 values for correction, supporting the conclusion made by Shen et al. (2008) for the Western Pacific. Despite samples being taken from regions adjacent to contrasting levels of land modification, no significant differences were found in 230Th/ 232Th 0 between regions exposed to varying levels of sediment during river runoff events. Overall, 39 of the total 43 230Th/ 232Th 0 atomic values measured in samples from inshore reefs across the entire region show a normal distribution ranging from 3.5 ± 1.1 to 8.1 ± 1.1 × 10 -6, with a weighted mean of 5.76 ± 0.34 × 10 -6 (2 σ, MSWD = 8.1). Considering the scatter of the data, the weighted mean value with a more conservative assigned error of 25% (i.e. 5.8 ± 1.4 × 10 -6) that encompasses the full variation of the 39 230Th/ 232Th 0 measurements is recommended as a more appropriate value for initial 230Th corrections for U-series dating of most Porites samples from inshore regions of the GBR. This will result in significant improvement in both the precision and accuracy of the corrected 230Th ages related to those based on the assumed bulk Earth 230Th/ 232Th 0 value of 4.3 ± 4.3 × 10 -6. However, several anomalously high 230Th/ 232Th 0 values reaching up to 28.0 ± 1.6 × 10 -6 occasionally found in some coral annual bands coinciding with El Niño years imply high 230Th/ 232Th 0 sources and highlight the complexities of understanding 230Th/ 232Th 0 variability. For U-series dating of young coral samples from such sites where anomalous 230Th/ 232Th 0 values occur, we suggest replicate dating of multiple growth bands with known age difference to verify age accuracy.

Age of the moon: An isotopic study of uranium-thorium-lead systematics of lunar samples

USGS Publications Warehouse

Tatsumoto, M.; Rosholt, J.N.

1970-01-01

Concentrations of U, Th, and Pb in Apollo 11 samples studied are low (U. 0.16 to 0.87; Th, 0.53 to 3.4; Pb, 0.29 to 1.7, in ppm) but the extremely radiogenic lead in samples allows radiometric dating. The fine dust and the breccia have a concordant age of 4.66 billion years on the basis of 207Pb/206Pb, 206Pb/238U, 207Pb/235U, and 208Pb/232Th ratios. This age is comparable with the age of meteorites and with the age generally accepted for the earth. Six crystalline and vesicular samples are distinctly younger than the dust and breccia. The 238U/235U ratio is the same as that in earth rocks, and 234U is in radioactive equilibrium with parent 238U.

U, Th, Pb and REE abundances and Pb 207/Pb 206 ages of individual minerals in returned lunar material by ion microprobe mass analysis.

NASA Technical Reports Server (NTRS)

Andersen, C. A.; Hinthorne, J. R.

1972-01-01

Results of ion microprobe analyses of Apollo 11, 12 and 14 material, showing that U, Th, Pb and REE are concentrated in accessory minerals such as apatite, whitlockite, zircon, baddeleyite, zirkelite, and tranquillityite. Th/U ratios are found to vary by over a factor of 40 in these minerals. K, Ba, Rb and Sr have been localized in a K rich, U and Th poor glass phase that is commonly associated with the U and Th bearing accessory minerals. Li is observed to be fairly evenly distributed between the various accessory phases. The phosphates have been found to have REE abundance patterns (normalized to the chondrite abundances) that are fairly flat, while the Zr bearing minerals have patterns that rise steeply, by factors of ten or more, from La to Gd. All the accessory minerals have large negative Eu anomalies. Radiometric age dates (Pb 207/Pb 206) of the individual U and Th bearing minerals compare favorably with the Pb 207/Pb 206 age of the bulk rocks.

Zircon U-Pb dating of eclogite from the Qiangtang terrane, north-central Tibet: a case of metamorphic zircon with magmatic geochemical features

NASA Astrophysics Data System (ADS)

Zhai, Qing-guo; Jahn, Bor-ming; Li, Xian-hua; Zhang, Ru-yuan; Li, Qiu-li; Yang, Ya-nan; Wang, Jun; Liu, Tong; Hu, Pei-yuan; Tang, Suo-han

2017-06-01

Zircon is probably the most important mineral used in the dating formation of high-pressure (HP) and ultrahigh-pressure (UHP) metamorphic rocks. The origin of zircon, i.e., magmatic or metamorphic, is commonly assessed by its external morphology, internal structure, mineral inclusions, Th/U ratios and trace element composition. In this study, we present an unusual case of metamorphic zircon from the Qiangtang eclogite, north-central Tibet. The zircon grains contain numerous eclogite-facies mineral inclusions, including omphacite, phengite, garnet and rutile; hence, they are clearly of metamorphic origin. However, they display features similar to common magmatic zircon, including euhedral crystal habit, high Th/U ratios and enriched heavy rare earth elements pattern. We suggest that these zircon grains formed from a different reservoir from that for garnet where no trace elements was present and trace element equilibrium between zircon and garnet was achieved. U-Pb dating of zircon gave an age of 232-237 Ma for the eclogite, and that of rutile yielded a slightly younger age of ca. 217 Ma. These ages are consistent with the reported Lu-Hf mineral isochron and phengite Ar-Ar ages. The zircon U-Pb and mineral Lu-Hf isochron ages are interpreted as the time of the peak eclogite-facies metamorphism, whereas the rutile U-Pb and phengite Ar-Ar ages represent the time of exhumation to the middle crust. Thus, the distinction between metamorphic and magmatic zircons cannot be made using only Th/U ratios and heavy REE compositions for HP-UHP metamorphic rocks of oceanic derivation.

Estimation of past seepage volumes from calcite distribution in the Topopah Spring Tuff, Yucca Mountain, Nevada

USGS Publications Warehouse

Marshall, B.D.; Neymark, L.A.; Peterman, Z.E.

2003-01-01

Low-temperature calcite and opal record the past seepage of water into open fractures and lithophysal cavities in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level radioactive waste repository. Systematic measurements of calcite and opal coatings in the Exploratory Studies Facility (ESF) tunnel at the proposed repository horizon are used to estimate the volume of calcite at each site of calcite and/or opal deposition. By estimating the volume of water required to precipitate the measured volumes of calcite in the unsaturated zone, seepage rates of 0.005 to 5 liters/year (l/year) are calculated at the median and 95th percentile of the measured volumes, respectively. These seepage rates are at the low end of the range of seepage rates from recent performance assessment (PA) calculations, confirming the conservative nature of the performance assessment. However, the distribution of the calcite and opal coatings indicate that a much larger fraction of the potential waste packages would be contacted by this seepage than is calculated in the performance assessment.

Helium Diffusion in Natural Xenotime

NASA Astrophysics Data System (ADS)

Anderson, A. J.; Hodges, K. V.; Van Soest, M. C.; Hanchar, J. M.

2017-12-01

Xenotime (nominally YPO4) occurs as an accessory mineral in felsic igneous rocks, pegmatites, and gneisses, often incorporating weight percent levels of U, Th, and REEs. Although commonly used for precise U-Pb geochronology, xenotime is seldom used for (U-Th)/He thermochronometry despite the fact that its high radionuclide content allows for the rapid accumulation of radiogenic He that could potentially allow for the precise dating of very young cooling events in active geologic settings. Xenotime's likely high concentrations of radiogenic 4He also make it a promising candidate for laser microprobe (U-Th)/He dating. Unfortunately, limited data are currently available for He diffusion in xenotime, and previous experimental studies of natural and synthetic xenotime have led to discrepant results (1). Published estimates of the (U-Th)/He closure temperature for xenotime based on these experiments range from 60˚C to 300˚C. In this contribution, we report new results for incremental step heating `bulk' 4He diffusion experiments on a fragment of a natural xenotime crystal from the Torghar district of the Khyber Agency in the Federally Administered Tribal Areas of Pakistan. Laser ablation 238U/206Pb dating of this crystal yields a crystallization age of 28.82 ± 0.13 Ma. The results of our He diffusion experiments- which display excellent linearity on an Arrhenius plot assuming a spherical geometry - indicate kinetic parameters of E 133 kJ/mol and ln(D0/a2) 10.9 s-1. Our results imply a preliminary (U-Th)/He closure temperature of 80˚C for xenotime crystals with a diffusion dimension of 220 μm. This closure temperature is much lower than that previously estimated for natural xenotime (1), and it is possible, perhaps likely, that He diffusion in natural xenotime crystals display a strong compositional dependency (1). Nevertheless, our experimental data suggest that near-end member (YPO4) xenotime has an intrinsic helium diffusivity consistent with a closure temperature comparable to that of the apatite (U-Th)/He thermochronometer. As a consequence, xenotime He chronometry may serve as a higher-precision alternative to apatite He chronometry for revealing low temperature cooling histories of rocks in which it crystallized. References: 1) Farley, 2007, Geochimica et Cosmochimica Acta, v. 71.

Late Pleistocene granodiorite beneath Crater Lake caldera, Oregon, dated by ion microprobe

USGS Publications Warehouse

Bacon, C.R.; Persing, H.M.; Wooden, J.L.; Ireland, T.R.

2000-01-01

Variably melted granodiorite blocks ejected during the Holocene caldera-forming eruption of Mount Mazama were plucked from the walls of the climactic magma chamber ~15 km depth. Ion-microprobe U-Pb dating of zircons from two unmelted granodiorite blocks with SHRIMP RG (sensitive high-resolution ion microprobe-reverse geometry) gives a nominal 238U/206Pb age of 101+78-80 ka, or 174+89-115 ka when adjusted for an initial 230Th deficit. SHRIMP RG U-Th measurements on a subset of the zircons yield a 230Th/238U isochron age of 112 ?? 24 ka, considered to be the best estimate of the time of solidification of the pluton. These results suggest that the granodiorite is related to andesite and dacite of Mount Mazama and not to magmas of the climactic eruption. The unexposed granodiorite has an area of at least 28 km2. This young, shallow pluton was emplaced in virtually the same location where a similarly large magma body accumulated and powered violent explosive eruptions ~7700 yr ago, resulting in collapse of Crater Lake caldera.

On the Quality of ENSDF {gamma}-Ray Intensity Data for {gamma}-Ray Spectrometric Determination of Th and U and Their Decay Series Disequilibria, in the Assessment of the Radiation Dose Rate in Luminescence Dating of Sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Corte, Frans de; Vandenberghe, Dimitri; Wispelaere, Antoine de

In luminescence dating of sediments, one of the most interesting tools for the determination of the annual radiation dose is Ge {gamma}-ray spectrometry. Indeed, it yields information on both the content of the radioelements K, Th, and U, and on the occurrence - in geological times - of disequilibria in the Th and U decay series. In the present work, two methodological variants of the {gamma}-spectrometric analysis were tested, which largely depend on the quality of the nuclear decay data involved: (1) a parametric calibration of the sediment measurements, and (2) the correction for the heavy spectral interference of themore » 226Ra 186.2 keV peak by 235U at 185.7 keV. The performance of these methods was examined via the analysis of three Certified Reference Materials, with the introduction of {gamma}-ray intensity data originating from ENSDF. Relevant conclusions were drawn as to the accuracy of the data and their uncertainties quoted.« less

230Th/U dating of a late Pleistocene alluvial fan along the southern San Andreas fault

USGS Publications Warehouse

Fletcher, Kathryn E.K.; Sharp, Warren D.; Kendrick, Katherine J.; Behr, Whitney M.; Hudnut, Kenneth W.; Hanks, Thomas C.

2010-01-01

U-series dating of pedogenic carbonate-clast coatings provides a reliable, precise minimum age of 45.1 ± 0.6 ka (2σ) for the T2 geomorphic surface of the Biskra Palms alluvial fan, Coachella Valley, California. Concordant ages for multiple subsamples from individual carbonate coatings provide evidence that the 238U-234U-230Th system has remained closed since carbonate formation. The U-series minimum age is used to assess previously published 10Be exposure ages of cobbles and boulders. All but one cobble age and some boulder 10Be ages are younger than the U-series minimum age, indicating that surface cobbles and some boulders were partially shielded after deposition of the fan and have been subsequently exhumed by erosion of fine-grained matrix to expose them on the present fan surface. A comparison of U-series and 10Be ages indicates that the interval between final alluvial deposition on the T2 fan surface and accumulation of dateable carbonate is not well resolved at Biskra Palms; however, the “time lag” inherent to dating via U-series on pedogenic carbonate can be no larger than ∼10 k.y., the uncertainty of the 10Be-derived age of the T2 fan surface. Dating of the T2 fan surface via U-series on pedogenic carbonate (minimum age, 45.1 ± 0.6 ka) and 10Be on boulder-top samples using forward modeling (preferred age, 50 ± 5 ka) provides broadly consistent constraints on the age of the fan surface and helps to elucidate its postdepositional development.

230Th/U dating of a late pleistocene alluvial fan along the southern san andreas fault

USGS Publications Warehouse

Fletcher, K.E.K.; Sharp, W.D.; Kendrick, K.J.; Behr, W.M.; Hudnut, K.W.; Hanks, T.C.

2010-01-01

U-series dating of pedogenic carbonate-clast coatings provides a reliable, precise minimum age of 45.1 ?? 0.6 ka (2??) for the T2 geomorphic surface of the Biskra Palms alluvial fan, Coachella Valley, California. Concordant ages for multiple subsamples from individual carbonate coatings provide evidence that the 238U-234U-230Th system has remained closed since carbonate formation. The U-series minimum age is used to assess previously published 10Be exposure ages of cobbles and boulders. All but one cobble age and some boulder 10Be ages are younger than the U-series minimum age, indicating that surface cobbles and some boulders were partially shielded after deposition of the fan and have been subsequently exhumed by erosion of fine-grained matrix to expose them on the present fan surface. A comparison of U-series and 10Be ages indicates that the interval between final alluvial deposition on the T2 fan surface and accumulation of dateable carbonate is not well resolved at Biskra Palms; however, the "time lag" inherent to dating via U-series on pedogenic carbonate can be no larger than ~10 k.y., the uncertainty of the 10Be-derived age of the T2 fan surface. Dating of the T2 fan surface via U-series on pedogenic carbonate (minimum age, 45.1 ?? 0.6 ka) and 10Be on boulder-top samples using forward modeling (preferred age, 50 ?? 5 ka) provides broadly consistent constraints on the age of the fan surface and helps to elucidate its postdepositional development. ?? 2010 Geological Society of America.

Potential effects of alpha-recoil on uranium-series dating of calcrete

USGS Publications Warehouse

Neymark, L.A.

2011-01-01

Evaluation of paleosol ages in the vicinity of Yucca Mountain, Nevada, at the time the site of a proposed high-level nuclear waste repository, is important for fault-displacement hazard assessment. Uranium-series isotope data were obtained for surface and subsurface calcrete samples from trenches and boreholes in Midway Valley, Nevada, adjacent to Yucca Mountain. 230Th/U ages of 33 surface samples range from 1.3 to 423 thousand years (ka) and the back-calculated 234U/238U initial activity ratios (AR) are relatively constant with a mean value of 1.54 ± 0.15 (1σ), which is consistent with the closed-system behavior. Subsurface calcrete samples are too old to be dated by the 230Th/U method. U-Pb data for post-pedogenic botryoidal opal from a subsurface calcrete sample show that these subsurface calcrete samples are older than ~ 1.65 million years (Ma), old enough to have attained secular equilibrium had their U-Th systems remained closed. However, subsurface calcrete samples show U-series disequilibrium indicating open-system behavior of 238U daughter isotopes, in contrast with the surface calcrete, where open-system behavior is not evident. Data for 21 subsurface calcrete samples yielded calculable 234U/238U model ages ranging from 130 to 1875 ka (assuming an initial AR of 1.54 ± 0.15, the mean value calculated for the surface calcrete samples). A simple model describing continuous α-recoil loss predicts that the 234U/238U and 230Th/238U ARs reach steady-state values ~ 2 Ma after calcrete formation. Potential effects of open-system behavior on 230Th/U ages and initial 234U/238U ARs for younger surface calcrete were estimated using data for old subsurface calcrete samples with the 234U loss and assuming that the total time of water-rock interaction is the only difference between these soils. The difference between the conventional closed-system and open-system ages may exceed errors of the calculated conventional ages for samples older than ~ 250 ka, but is negligible for younger soils.

Postorogenic carbonatites at Eden Lake, Trans-Hudson Orogen (northern Manitoba, Canada): Geological setting, mineralogy and geochemistry

NASA Astrophysics Data System (ADS)

Chakhmouradian, A. R.; Mumin, A. H.; Demény, A.; Elliott, B.

2008-07-01

The Eden Lake pluton in the Trans-Hudson Orogen is the first known occurrence of carbonatites in Manitoba. The pluton is largely made up of modally and geochemically diverse syenitic rocks derived from postorogenic magma(s) of shoshonitic affinity. Their diversity can be accounted for by a combination of crystal fractionation and fluid release in the final evolutionary stage (crystallization of quartz alkali-feldspar syenite). At Eden Lake, carbonatites, represented predominantly by coarse-grained massive to foliated sövite, occur as branching veins and lenticular bodies up to 4 m in thickness showing crosscutting relations with respect to all of the syenitic units. The host rocks are intensely fenitized at the contact, and there is also abundant mineralogical and textural evidence for assimilation of silicate material by carbonatitic magma through wallrock reaction and xenolith fragmentation and digestion. The bulk of the carbonatites are composed of (in order of crystallization): Sr-REE-rich fluorapatite, aegirine-augite, and coarse calcite crystals surrounded by fine-grained calcite (on average, ˜ 90 vol.% of the rock). Noteworthy accessory constituents are celestine, bastnäsite-(Ce) (both as primary inclusions in calcite), Nb-Zr-rich titanite, low-Hf zircon, allanite-(Ce) and andradite. The calcite is chemically uniform (Sr-rich, Mg-Mn-Fe-poor and low in 13C), but shows clear evidence of ductile deformation and syndeformational cataclasis. Geochemically, the carbonatites are enriched in Sr, Ba, light rare-earth elements, Th and U, but depleted in high-field-strength elements (particularly, Ti, Nb and Ta). The stable-isotope composition of coarse- and fine-grained calcite from the carbonatites and interstitial calcite from syenites is remarkably uniform: ca. - 8.16 ± 0.27‰ δ13C (PDB) and + 8.04 ± 0.19‰ δ18O (SMOW). The available textural and geochemical evidence indicates that the Eden Lake carbonatites are not consanguineous with the associated syenites and may have been derived from a Nb-Ti-retentive and 13C-depleted source such as the subducted crustal material underlying the Eden Lake deformation corridor.

Integrated multi-site U-Th chronology of the last glacial Lake Lisan

NASA Astrophysics Data System (ADS)

Torfstein, Adi; Goldstein, Steven L.; Kagan, Elisa J.; Stein, Mordechai

2013-03-01

We present a new integrated multi-site chronology for Lake Lisan, which occupied the Dead Sea basin and Jordan Valley during the last glacial period (70-14 kka, Marine Isotope Stages 4, 3, 2). The Dead Sea basin lacustrine deposits are unique among closed basin sediments in that they formed in a deep, hypersaline water body that precipitated primary aragonite which is amenable to radiometric dating by U-series, providing a solid basis for studies of the relationship of Middle East climate to other changes in the high latitudes or the tropics. The application of U-Th dating for lacustrine carbonates requires corrections for detrital U and Th and hydrogenous ("initial") 230Th. Here we followed an iterative approach, in which we evaluate the composition of the detrital contamination independently for every set of coeval samples to determine the corrected ages. These were further filtered and combined with lithological-limnological considerations, which were used to construct age-height models for all studied stratigraphic sections. Finally, the ages of stratigraphic tie-points were used to integrate the individual age-height models into a unified chronology. The resulting chronological framework indicates that the ages of several primary gypsum units associated with catastrophic lake level drops correspond with the timing of Heinrich events in the North Atlantic. Thus, a final iterative step involves refining the ages of "Lisan-gypsum events" based on the ages of Heinrich events 6, 5, 5a, 4, and 1. This approach yields an unprecedented basin-wide, unified, event-anchored chronology for the Lisan Formation, with typical age uncertainties ca. 1000-2000 years (95% confidence limit) across the entire last glacial, well below those typically related to individual U-Th and radiocarbon dating of "dirty" carbonates from similar time intervals. The results can be further extrapolated to new sites and serve as a geochronometric reference for the reconstruction of the limnological history of Lake Lisan.

U-Pb dating of large zircons in low-temperature jadeitite from the Osayama serpentinite melange, southwest Japan: insights into the timing of serpentinization

USGS Publications Warehouse

Tsujimori, T.; Liou, J.G.; Wooden, J.; Miyamoto, T.

2005-01-01

Crystals of zircon up to 3 mm in length occur in jadeitite veins in the Osayama serpentinite mélange, Southwest Japan. The zircon porphyroblasts show pronounced zoning, and are characterized by both low Th/U ratios (0.2-0.8) and low Th and U abundances (Th = 1-81 ppm; U = 6-149 ppm). They contain inclusions of high-pressure minerals, including jadeite and rutile; such an occurrence indicates that the zircon crystallized during subduction-zone metamorphism. Phase equilibria and the existing fluid-inclusion data constrain P-T conditions to P > 1.2 GPa at T > 350°C for formation of the jadeitite. Most U/Pb ages obtained by SHRIMP-RG are concordant, with a weighted mean 206Pb/238U age of 472 ± 8.5 Ma (MSWD = 2.7, n = 25). Because zircon porphyroblasts contain inclusions of high-pressure minerals, the SHRIMP U-Pb age represents the timing of jadeitite formation, i.e., the timing of interaction between alkaline fluid and ultramafic rocks in a subduction zone. Although this dating does not provide a direct time constraint for serpentinization, U-Pb ages of zircon in jadeitite associated with serpentinite result in new insights into the timing of fluid-rock interaction of ultramafic rocks at a subduction zone and the minimum age for serpentinization.

Analysis of 19th century ceramic fragments excavated from Pirenópolis (Goiás, Brazil) using FT-IR, Raman, XRF and SEM

NASA Astrophysics Data System (ADS)

Freitas, Renato P.; Coelho, Filipe A.; Felix, Valter S.; Pereira, Marcelo O.; de Souza, Marcos André Torres; Anjos, Marcelino J.

2018-03-01

This study used Raman, FT-IR and XRF spectroscopy and SEM to analyze ceramic fragments dating from the 19th century, excavated from an old farm in the municipality of Pirenópolis, Goiás, Brazil. The results show that the samples were produced in an open oven at a firing temperature below 500 °C, using raw materials including kaolinite, hematite, magnetite, quartz, microcline, albite, anhydrite, calcite, illite, orthoclase and MnO2. Although the analyses showed similarities in the manufacturing process and the presence of many minerals was common in all samples, multivariate statistical methods (PCA) allowed a more detailed assessment of similarities and differences in the mineral composition of the samples. The results of the PCA showed that the samples excavated in one of the slave quarters (senzalas) group with those excavated at the farmhouse, where the landowner lived, which indicates a paternalistic attitude towards captives, including the sharing of ceramic materials of everyday use.

Dating native gold by noble gas analyses

NASA Technical Reports Server (NTRS)

Niedermann, S.; Eugster, O.; Hofmann, B.; Thalmann, CH.; Reimold, W. U.

1993-01-01

Our recent work on He, Ne, and Ar in Alpine gold samples has demonstrated that gold is extremely retentive for He and could thus, in principle, be used for U/Th-He-4 dating. For vein-type gold from Brusson, Northern Italy, we derived a U/Th-He-4 age of 36 Ma, in agreement with the K-Ar formation age of associated muscovites and biotites. However, in placer gold from the Napf area, Central Switzerland, we observed large excesses of both He-4 and radiogenic Ar-40 (Ar-40 sub rad, defined as Ar-40-295.5-Ar-.36). The gas release systematics indicate two distinct noble gas components, one of which is released below about 800 C and the other one at the melting point of gold (1064 C). We now present results of He and Xe measurements in a 1 g placer gold sample from the river Kruempelgraben, as well as He and Ar data for Brusson vein-type gold and for gold from the Lily Gold Mine, South Africa. We calculate reasonable U/Th-He-4 as well as U-Xe ages based on those gases which are released at approximately 800 C. Probably the low-temperature components represent in-situ-produced radiogenic He and fission Xe, whereas the gases evolving when gold melts have been trapped during gold formation. Therefore, only the low-temperature components are relevant for dating purposes.

3. PHOTOGRAPHIC COPY OF MASTER PLAN, DETAIL SITE PLAN, 7TH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. PHOTOGRAPHIC COPY OF MASTER PLAN, DETAIL SITE PLAN, 7TH CAVALRY BUILDINGS, DATED SEPTEMBER 10, 1951, SEE ARROW, DRAWING # BM-036, COPY ON FILE IN THE ENVIRONMENTAL MANAGEMENT OFFICE, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

Upper crustal emplacement and deformation of granitoids inside the Uppermost Unit of the Cretan nappe stack: constraints from U-Pb zircon dating, microfabrics and paleostress analyses

NASA Astrophysics Data System (ADS)

Kneuker, Tilo; Dörr, Wolfgang; Petschick, Rainer; Zulauf, Gernold

2015-03-01

The present study is dealing with the emplacement and deformation of diorite and quartz diorite exposed along new road cuts between Agios Nikolaos and Sitia (Uppermost Unit, eastern Crete). Mingling of both melt types is indicated by enclaves of diorite inside quartz diorite and vice versa. The diorite and quartz diorite intruded into coarse-grained white marble, which is in lateral contact to, but also forms the roof of, the intrusive body. Evidence for contact metamorphism is indicated by increasing grain size of calcite in the marble with decreasing distance from the diorite. U-Pb (TIMS) dating of zircons, separated from quartz diorite, yielded a concordant age at 74.0 ± 0.25 Ma, which is interpreted as emplacement age. As this age is close to published K-Ar cooling ages of hornblende and biotite, the melt should have intruded and cooled down rapidly at upper structural levels, which is not common for granitoids of the Uppermost Unit of Crete. Upper crustal melt emplacement is also documented by stoped blocks and by the lack of any ductile (viscous) deformation. The diorite and quartz diorite, however, are affected by strong post-Oligocene brittle faulting. Paleostress analysis, based on these faults, revealed a change in stress field from N-S and NNW-SSE shortening by thrusting (convergence between African and European plates) to NNE-SSW and NE-SW shortening accommodated by strike-slip (SW-ward extrusion of the Anatolian microplate). Calcite-twin density indicates high differential stress (260 ± 20 MPa) related to these phases of crustal shortening.

Laser-Ablation (U-Th)/He Geochronology

NASA Astrophysics Data System (ADS)

Hodges, K.; Boyce, J.

2003-12-01

Over the past decade, ultraviolet laser microprobes have revolutionized the field of 40Ar/39Ar geochronology. They provide unprecedented information about Ar isotopic zoning in natural crystals, permit high-resolution characterization of Ar diffusion profiles produced during laboratory experiments, and enable targeted dating of multiple generations of minerals in thin section. We have modified the analytical protocols used for 40Ar/39Ar laser microanalysis for use in (U-Th)/He geochronologic studies. Part of the success of the 40Ar/39Ar laser microprobe stems from fact that measurements of Ar isotopic ratios alone are sufficient for the calculation of a date. In contrast, the (U-Th)/He method requires separate analysis of U+Th and 4He. Our method employs two separate laser microprobes for this process. A target mineral grain is placed in an ultrahigh vacuum chamber fitted with a window of appropriate composition to transmit ultraviolet radiation. A focused ArF (193 nm) excimer laser is used to ablate tapered cylindrical pits on the surface of the target. The liberated material is scrubbed with a series of getters in a fashion similar to that used for 40Ar/39Ar geochronology, and the 4He abundance is determined using a quadrupole mass spectrometer with well-calibrated sensitivity. A key requirement for calculation of the 4He abundance in the target is a precise knowledge of the volume of the ablation pit. This is the principal reason why we employ the ArF excimer for 4He analysis rather than a less-expensive frequency-multiplied Nd-YAG laser; the excimer creates tapered cylindrical pits with extremely reproducible and easily characterized geometry. After 4He analysis, U and Th are measured on the same sample surface using the more familiar technique of laser-ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Our early experiments have been done using a frequency-quintupled Nd-YAG microprobe (213nm), While the need to analyze U+Th and He in separate ablation experiments results in considerably worse spatial resolution than that typically possible for 40Ar/39Ar laser microprobe dating, it is possible to site the LA-ICPMS ablation pit within a few microns of the pit used for He extraction, or to simply re-occupy and enlarge the original ablation pit. The potential effective spatial resolution of the technique is thus on the order of a few tens to roughly 100 microns. As a proof-of-concept exercise, we have applied this technique to fluorapatite from Cerro de Mercado, Durango, Mexico, which has a generally accepted (U-Th)/He age of 32.1 +/- 3.4 Ma (2 sigma) based on single-crystal fusion analyses reported by House et al. (2000, EPSL). Using the approach described above, we made 48 separate age measurements on a 12 mm polished section cut through a single crystal of Durango fluorapatite perpendicular to its c axis. The measured dates yield a mean of 34.9 +/- 5.1 Ma (2 sigma), with a total dispersion of dates comparable to that reported by House et al. Much of the apparent age variation observed in both studies is due to documented U+Th heterogeneities in single crystals of the Durango fluorapatite. Nevertheless, the consistency of the laser ablation and conventional results for this material is striking. Compared to conventional laser and furnace methods of (U-Th)/He geochronology, the laser microprobe approach offers substantially improved spatial resolution, and the ability to avoid (or at least minimize) alpha-ejection corrections. In addition, the method affords improved sample throughput, such that age estimates for homogeneous materials can be made with considerably higher precision based on a larger number of analyses.

Little Ice Age versus Present Day: Comparison of Temperature, Precipitation and Seasonality in Speleothem Records from the Han-sur-Lesse Cave, Belgium.

NASA Astrophysics Data System (ADS)

Vansteenberge, S.; Van Opdenbosch, J.; Van Rampelbergh, M.; Verheyden, S.; Keppens, E.; Cheng, H.; Edwards, R. L.; Claeys, P. F.

2015-12-01

The Proserpine stalagmite is a 2 m large, tabular-shaped speleothem located in the Han-sur-Lesse cave in Belgium. The speleothem formed over the last 1000 years and is still growing. High-accuracy U/Th datings have indicated exceptionally high growth-rates of up to 2 mm per year. This, together with a well expressed annual layering, makes the Proserpine stalagmite an ideal candidate for high-resolution paleoclimate reconstructions of the last millennium. Previous work, including over 10 years of cave monitoring, has already learned us how short-term, i.e. decadal to seasonal, climate variations are incorporated within speleothem calcite from the Han-sur-Lesse cave system. It has been shown that δ18O and δ13C stable isotopes and trace element proxies of recently formed calcite reflect seasonal variations in temperature and precipitation of the near-cave environment (Verheyden et al, 2008; Van Rampelbergh et al., 2014). Now, this knowledge was used to infer local climate parameters further back in time to the period of +/- 1620-1630 CE, corresponding to one of the cold peaks within the Little Ice Age. Speleothem calcite was sampled at sub-annual resolution, with approximately 11 samples per year, for stable isotope analysis. LA-ICP-MS and µXRF analyses resulted in time series of trace elements. Preliminary results indicate a well expressed seasonal signal in δ13C and trace element composition but a multi-annual to decadal trend in δ18O. This combined proxy study eventually enables comparison of the expression of seasonality and longer term climate variations between a Little Ice Age cold peak and Present Day. References: Verheyden, S. et al., 2008, Monitoring climatological, hydrological and geochemical parameters in the Père Noël cave (Belgium): implication for the interpretation of speleothem isotopic and geochemical time-series. International Journal of Speleology, 37(3), 221-234. Van Rampelbergh, M. et al., 2014, Seasonal variations recorded in cave monitoring results and a 10-year monthly resolved speleothem δ13C and δ18O record from the Han-sur-Lesse cave, Belgium. Climate of the Past, 10, 1-15, 2014.

Ages and stable-isotope compositions of secondary calcite and opal in drill cores from Tertiary volcanic rocks of the Yucca Mountain area, Nevada

USGS Publications Warehouse

Szabo, B. J.; Kyser, T.K.

1990-01-01

Stable-isotope compositions of fracture- and cavity-filling calcite from the unsaturated zone of three drill cores at Yucca Mountain Tertiary volcanic complex indicate that the water from which the minerals precipitated was probably meteoric in origin. A decrease in 18O in the calcite with depth is interpreted as being due to the increase in temperature in drill holes corresponding to an estimated average geothermal gradient of 34?? per kilometer. A few of the calcite samples and all of the opal samples yielded uranium-series ages older than 400 000 yr, although most of the calcite samples yielded ages between 26 000 and 310 000 yr. The stable-isotope and uranium-series dates from precipitated calcite and opal of this reconnaissance study suggest a complex history of fluid movement through the volcanic pile, and episodes of fracture filling predominantly from meteoric water during at least the past 400 000 yr. -Authors

A 2000-yr High-resolution Stalagmite Record From Zhenzhu Cave in Hebei, North China: Interpretations of AMS 14C, 230Th/U, 210Pb Dating, and δ18O, δ13C Results

NASA Astrophysics Data System (ADS)

Li, H. C.; Yin, J.; Rao, Z.; Mii, H. S.; Shen, C. C.; Pillutla, R. K.; Li, Y. X.

2016-12-01

An 11.1-cm long stalagmite (ZZ12) collected from Zhenzhu cave (38°15'N, 113°42'E, 975m a.s.l.) located at Tiangui mountain of Hebei province, North China. The 230Th/U dates on 12 horizons exhibit large uncertainties with many reversed age sequences due to low U contents and low 230Th/232Th ratios. While the 230Th/U dating is not able to provide the chronology of this stalagmite, AMS 14C dating on 27 samples from various depths of the stalagmite yields a reliable age-depth relationship. Three AMS 14C dates from the top 5 mm appear nuclear bomb carbon indicating that this part was deposited after AD 1950. Seven samples for 210Pb dating were taken from the upper 14 mm with 2 mm intervals, showing exponential decay of excess 210Pb and supporting the AMS 14C dating results. At the base of the stalagmite, charcoal grains were included in the carbonate stalagmite. This charcoal sample has a Calibrated 14C age of 1865±20 a BP. The carbonates at adjacent depths show Calibrated 14C ages of 1900±15 and 2215±75 a BP respectively. The bomb carbon and similar ages between the charcoal and carbonates indicate that dead carbon influence on the 14C dates in some horizons may not be serious. From the 27 AMS 14C dates, we select 17 AMS 14C dates which have minimal influence of dead carbon fraction to construct the chronology. The established chronology shows that slow growth rates occurred prior to 1100 a BP and after 600 a BP. This time interval involves the Medieval Warm Period, while the fast growth rate during this interval may reflect warm and wet climatic conditions. A total of 835 samples were drilled from the stalagmite for δ18O and δ13C analyses. The current 900-year δ18O and δ13C records reveal climate and vegetation changes in the study area. Strong decadal oscillations in the δ18O record reflect variations of monsoonal rain, with relatively dry between AD 1350 and AD 1550 and after AD 1960. The δ13C record appears mainly multi-centennial variations with a 4‰ fluctuation range and an average value of -8‰ (VPDB). The δ13C values were lighter than the average during AD 1150 1480 and AD 1700 1920, whereas the δ13C values were heavier than the average during AD 1480 1700 and AD 1820 the present. The δ13C record mainly reflects the vegetation change above the cave, with lighter value indicating better vegetation coverage and vice versa.

Inverted Apatite (U-Th)/He and Fission-track Dates from the Rae craton, Baffin Island, Canada and Implications for Apatite Radiation Damage-He Diffusivity Models

NASA Astrophysics Data System (ADS)

Ault, A. K.; Reiners, P. W.; Thomson, S. N.; Miller, G. H.

2015-12-01

Coupled apatite (U-Th)/He and fission-track (AFT) thermochronology data from the same sample can be used to decipher complex low temperature thermal histories and evaluate compatibility between these two methods. Existing apatite He damage-diffusivity models parameterize radiation damage annealing as fission-track annealing and yield inverted apatite He and AFT dates for samples with prolonged residence in the He partial retention zone. Apatite chemistry also impacts radiation damage and fission-track annealing, temperature sensitivity, and dates in both systems. We present inverted apatite He and AFT dates from the Rae craton, Baffin Island, Canada, that cannot be explained by apatite chemistry or existing damage-diffusivity and fission track models. Apatite He dates from 34 individual analyses from 6 samples range from 237 ± 44 Ma to 511 ± 25 Ma and collectively define a positive date-eU relationship. AFT dates from these same samples are 238 ± 15 Ma to 350 ± 20 Ma. These dates and associated track length data are inversely correlated and define the left segment of a boomerang diagram. Three of the six samples with 20-90 ppm eU apatite grains yield apatite He and AFT dates inverted by 300 million years. These samples have average apatite Cl chemistry of ≤0.02 wt.%, with no correlation between Cl content and Dpar. Thermal history simulations using geologic constraints, an apatite He radiation damage accumulation and annealing model, apatite He dates with the range of eU values, and AFT date and track length data, do not yield any viable time-temperature paths. Apatite He and AFT data modeled separately predict thermal histories with Paleozoic-Mesozoic peaks reheating temperatures differing by ≥15 °C. By modifying the parameter controlling damage annealing (Rmr0) from the canonical 0.83 to 0.5-0.6, forward models reproduce the apatite He date-eU correlation and AFT dates with a common thermal history. Results imply apatite radiation damage anneals at higher temperatures than fission-track damage and the impact on coupled apatite He and AFT dates is magnified for protracted cooling histories. Further experimental and field-based tests are important for refining radiation damage and fission-track annealing parameters for accurate interpretation of apatite He- and AFT-derived thermal histories.

Investigation of the Cross-Section Stratifications of Icons Using Micro-Raman and Micro-Fourier Transform Infrared (FT-IR) Spectroscopy.

PubMed

Lazidou, Dimitra; Lampakis, Dimitrios; Karapanagiotis, Ioannis; Panayiotou, Costas

2018-01-01

The cross-section stratifications of samples, which were removed from six icons, are studied using optical microscopy, micro-Raman spectroscopy, and micro-Fourier transform infrared (FT-IR) spectroscopy. The icons, dated from the 14th to 19th centuries, are prominent examples of Byzantine painting art and are attributed to different artistic workshops of ​​northern Greece. The following materials are identified in the cross-sections of the icon samples using micro-Raman spectroscopy: anhydrite; calcite; carbon black; chrome yellow; cinnabar; gypsum; lead white; minium; orpiment; Prussian blue; red ochre; yellow ochre; and a paint of organic origin which can be either indigo ( Indigofera tinctoria L. and others) or woad ( Isatis tinctoria L.). The same samples are investigated using micro-FT-IR which leads to the following identifications: calcite; calcium oxalates; chrome yellow; gypsum; kaolinite; lead carboxylates; lead sulfate (or quartz); lead white; oil; protein; Prussian blue; saponified oil; shellac; silica; and tree resin. The study of the cross-sections of the icon samples reveals the combinations of the aforementioned inorganic and organic materials. Although the icons span over a long period of six centuries, the same stratification comprising gypsum ground layer, paint layers prepared by modified "egg tempera" techniques (proteinaceous materials mixed with oil and resins), and varnish layer is revealed in the investigated samples. Moreover, the presence of three layers of varnishes, one at the top and other two as intermediate layers, in the cross-section analysis of a sample from Virgin and Child provide evidence of later interventions.

Spectral pathways for exploration of secondary uranium: An investigation in the desertic tracts of Rajasthan and Gujarat, India

NASA Astrophysics Data System (ADS)

Bharti, Rishikesh; Kalimuthu, R.; Ramakrishnan, D.

2015-10-01

This study aims at identifying potential zones of secondary uranium enrichment using hyperspectral remote sensing, γ-ray spectrometry, fluorimetry and geochemical techniques in the western Rajasthan and northern Gujarat, India. The investigated area has suitable source rocks, conducive past-, and present-climate that can facilitate such enrichment. This enrichment process involves extensive weathering of uranium bearing source rocks, leaching of uranyl compounds in groundwater, and their precipitation in chemical deltas along with duricrusts like calcretes and gypcretes. Spatial distribution of groundwater calcretes (that are rich in Mg-calcite) and gypcretes (that are rich in gypsum) along palaeochannels and chemical deltas were mapped using hyperspectral remote sensing data based on spectral absorptions in 1.70 μm, 2.16 μm, 2.21 μm, 2.33 μm, 2.44 μm wavelength regions. Subsequently based on field radiometric survey, zones of U anomalies were identified and samples of duricrusts and groundwater were collected for geochemical analyses. Anomalous concentration of U (2345.7 Bq/kg) and Th (142.3 Bq/kg) are observed in both duricrusts and groundwater (U-1791 μg/l, Th-34 μg/l) within the palaeo-delta and river confluence. The estimated carnotite Solubility Index also indicates the secondary enrichment of U and the likelihood of occurrence of an unconventional deposit.

U-series constraints on the Holocene human presence in the Cuatro Cienegas basin, Mexico

NASA Astrophysics Data System (ADS)

Noble, S. R.; Felstead, N.; Gonzalez, S.; Leng, M. J.; Metcalfe, S. E.; Patchett, P. J.

2010-12-01

U-series tufa ages dating a human trackway have been obtained, part of a larger Late Pleistocene - Recent palaeoclimate and human occupation study of the Cuatro Cienegas basin, NE Mexico. Our analytical approach, including tracer calibration, couples aspects of what we consider best practice in the U-series community with our U-Pb experiences which includes the EarthTime U-Pb tracer calibration exercise. The recently discovered trackway is near a small hydrothermal pool within the basin [1], an ecologically highly significant oasis in the Chihuahuan desert. The oasis comprises >200 freshwater hydrothermal pools and a river system, and the related ecosystem hosts >70 endemic species[2]. Pools are fed by waters that circulate a deep karstic system and that originate in the surrounding upper Jurassic-lower Cretaceous Sierra Madre Oriental mountains (>3000m) [3]. The area hosted nomadic hunter-gatherers during the Holocene, and possibly as early as Late Pleistocene (~12 ka BP). Despite the basin's ecological significance, only three palaeoenvironmental studies have been published to date, and limited geochronological constraints are available. A pollen study of drill core through peats and tufas proximal to the pools suggested a long period of climatic stability and biogeographic isolation[4], a notion supported by the large number of endemic species, but other palynological and plant macrofossil data suggest that large climatic changes occurred post Late Pleistocene [5]. The 10 m long in situ trackway is preserved in tufa and five samples from the uppermost surfaces were analysed to date the footprints. The tufas comprise clean carbonate with no petrographic evidence of replacement and little contaminant detrital material (on some exposed upper surfaces). Powdered tufa was processed following [6-8], and analysed by TIMS (Triton, U) and MC-ICP-MS (Th, Nu HR), although our future analyses will primarily be obtained on a Neptune. Samples were spiked with a 229Th/236U tracer calibrated against gravimetric solutions prepared from Ames high-purity Th metal crystal and CRM 112a U metal ingot rather than natural materials of assumed secular equilibrium. ICP-MS mass bias and Faraday-SEM gain was monitored using CRM 112a and an in-house 229Th-230Th-232Th solution. Most samples have relatively high U contents (~2 ppm U), moderate [230Th/232Th] = 29-44, and initial [234U/238U] ~ 1.92. We obtain an age of 7.24 ± 0.13 ka BP for this trackway based on an average of two samples of the uppermost tufa surface. Depth profiling of one sample shows consistently increasing age downwards (~370 a/cm). [1] Gonzalez, A.H.G. et al., 2006, Ichnos 16, 12-24;[2] Souza, V. et al., 2006, PNAS 103, 6565-6570; [3] Johannesson, K.H. et al., 2004, J.S.Am.Earth Sci. 17, 171-180; [4] Meyer, E. 1973, Ecology 54, 982-995; [5] Minckley, T.A. & Jackson, S. 2008. J. Biogeography 35, 188-190; [6] Edwards, R.L. et al., 1987, EPSL 81, 175-192; [8] Cheng, H. et al., 2000, Chem. Geol. 169, 17-33; [8] Potter, E.K. et al., 2005, EPSL 247, 10-17.

Unraveling the Alteration History of Serpentinites and Associated Ultramafic Rocks from the Kampos HPLT Subduction Complex, Syros, Greece

NASA Astrophysics Data System (ADS)

Cooperdock, E. H. G.; Stockli, D. F.

2016-12-01

Serpentinization, hydration of peridotite, has a profound effect on fundamental tectonic and petrologic processes such as deformation of the lithosphere, bulk rheology, fluid-mobile element cycling and deep earth carbon cycling. Though numerous studies have investigated the petrology, structure and geochemistry of serpentinites, the absolute chronology of serpentinization remains elusive due to a lack of accessory minerals that can be dated using established geochronological techniques. Magnetite forms as a common secondary mineral in serpentinites from the fluid-induced breakdown reaction of primary peridotite minerals. Magnetite (U-Th)/He chronometry provides the potential to directly date the cooling of exhumed ultramafic bodies and the low-temperature fluid alteration of serpentinites. We present the first application of magnetite (U-Th)/He chronometry to date stages of alteration in ultramafic rocks from the Kampos mélange belt, a high-pressure low-temperature (HP-LT) subduction complex that experienced exhumation in the Miocene on the island of Syros, Greece. Two generations of magnetite are distinguishable by grain size, magnetite trace element geochemistry and (U-Th)/He age. Large magnetite grains (mm) from a chlorite schist and a serpentinite schist have distinct geochemical signatures indicative of formation during blackwall-related fluid alteration and record Mid-Miocene exhumation-related cooling ages, similar to zircon (U-Th)/He ages from northern Syros. Smaller grains (µm) from the serpentinite schist lack blackwall-related fluid signatures and record post-exhumation mineral formation associated with widespread high-angle Pliocene normal faulting. These results reveal evidence for multiple episodes of fluid-rock alteration, which has implications for the cooling history and local geochemical exchanges of this HP-LT terrane. Given the fundamental impact of serpentinizaton on a vast array of tectonic, petrological, and geochemical processes, the ability to differentiate and date these alteration events can be used to address significant questions related to serpentinization in exhumed subduction complexes, continental margins, or obducted ophiolites.

Incorporation of Mg, Sr, Ba, U, and B in High-Mg Calcite Benthic Foraminifers Cultured Under Controlled pCO2

NASA Astrophysics Data System (ADS)

Not, C.; Thibodeau, B.; Yokoyama, Y.

2018-01-01

Measurement of elemental ratios (E/Ca) has been performed in two symbiont-bearing species of high-Mg calcite benthic foraminifers (hyaline, Baculogypsina sphaerulata and porcelaneous, Amphisorus hemprichii), cultured under five pCO2 levels, representing preindustrial, modern, and three predicted future values. E/Ca ratios were analyzed by Laser Ablation coupled with Inductively Coupled Plasma Mass Spectrometer (LA-ICP-MS). We measured several E/Ca, such as Mg/Ca, Sr/Ca, Ba/Ca, U/Ca, and B/Ca simultaneously. We observed that high-Mg calcite benthic foraminifers possess higher E/Ca than low-Mg calcite foraminifers, irrespective of their calcification mode (hyaline or porcelaneous). In both modes of calcification, Mg, Sr, Ba, U, and B incorporation could be controlled by Rayleigh fractionation. However, more data are needed to validate and quantify the relative importance of this process and closely investigate the presence/absence of other mechanism. Therefore, it highlights the need for a multielemental approach when looking at trace element incorporation. Finally, no significant relationship was observed between the different ratios and the pCO2 of the water, suggesting that none of the Mg/Ca, Sr/Ca, Ba/Ca, U/Ca, and B/Ca is sensitive to bottom water pCO2 or pH for these species.

Comment on “Reconciliation of the Devils Hole climate record with orbital forcing”

USGS Publications Warehouse

Winograd, Isaac J.

2016-01-01

Moseley et al. (Reports, 8 January 2016, p. 165) postulate an increase in dissolved thorium isotope 230Th with depth below the water table as the explanation for the differing ages of Termination II. Flow of geothermal water through the Devils Hole caverns precludes this explanation. Deposition of younger secondary calcite into the initial porosity of the calcite comprising their cores is a plausible alternate explanation.

Comment on “Reconciliation of the Devils Hole climate record with orbital forcing”

NASA Astrophysics Data System (ADS)

Winograd, Isaac J.

2016-10-01

Moseley et al. (Reports, 8 January 2016, p. 165) postulate an increase in dissolved thorium isotope 230Th with depth below the water table as the explanation for the differing ages of Termination II. Flow of geothermal water through the Devils Hole caverns precludes this explanation. Deposition of younger secondary calcite into the initial porosity of the calcite comprising their cores is a plausible alternate explanation.

High-Resolution Speleothem Records of the Indian Ocean Monsoon Variability of the Last 6 ka and 0,5 ka From Soqotra Island, Yemen

NASA Astrophysics Data System (ADS)

de Geest, P.; Verheyden, S.; Cheng, H.; Edwards, L. R.; Keppens, E.

2004-12-01

Soqotra is an arid tropical island in the Indian Ocean, situated between the Horn of Africa and the Arabian Peninsula. The inter-tropical convergence zone (ITCZ) passes there twice each year, resulting in a bi-annual rainy season. High-resolution \\delta18O and \\delta13C ratios of speleothems from two different caves are used to reconstruct changes in the Monsoon intensity and/or variability. Based on 10 TIMS 234U/230Th dating, two active speleothems from Hoq (S-STM1) and Kazekas Caves (S-STM5) have formed over a period of 6 ka BP and 0,5 ka BP, respectively. To obtain a detailed climate reconstruction more than 1000 \\delta13C and \\delta18O measurements were carried out, providing a time resolution between 2,5 and 10 years. In S-STM1 \\delta18O -values range between -4,5\\permil and -1,5\\permil and \\delta13C -values between -10,5\\permil and -5,5\\permil; while for S-STM5 these values range respectively between -4\\permil and -2\\permil and -7\\permil and -3\\permil (vs VPDB). Based on the comparison between \\delta18O excursions and historical meteorological data, the amount of precipitation is reflected in the \\delta18O signal. Different mechanisms for the \\delta13C are considered, such as a diminution of the C4-type vegetation during droughts, resulting in more positive \\delta13C -value or kinetic effects during the calcification process itself. Throughout the time series, co-variation occur between \\delta13C and \\delta18O -values (R2= 0,69) exhibiting long term (millennial) and short term (decadal) variations. In both stalagmites, layers of white porous calcite (WPC) (0,1-0,5mm) and dark dense calcite (DDC) (0,01-0,1mm) alternate, most probably due to seasonal variations. The WPC has more positive \\delta13C and \\delta18O -values, while the DDC shows more negative values, clearly demonstrated by high-resolution micro sampling up to a monthly to bi-weekly resolution. A positive correlation between the greyscale variations in the calcite fabric, the presumably annual growth banding and the inverse stable isotope ratios records support this hypothesis. During dry periods, less precipitation enters the cave-system, resulting in a whitish porous calcite deposition, thinner annual banding and more negative stable isotope ratios and vice versa. To better understand the climatic significance of these records, adapted Environmental Data Acquisition Systems (EDAS) are installed in and near Hoq Cave to obtain information on the actual transfer functions between climate and the proxy data in our speleothems.

78 FR 56217 - Steel Threaded Rod from India: Postponement of Preliminary Determination of Countervailing Duty...

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Subglacial Calcites from Northern Victoria Land: archive of Antarctic volcanism in the Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Frisia, Silvia; Weirich, Laura; Hellstrom, John; Borsato, Andrea; Golledge, Nicholas R.; Anesio, Alexandre M.; Bajo, Petra; Drysdale, Russell N.; Augustinus, Paul C.; Barbante, Carlo; Cooper, Alan

2017-04-01

Subglacial carbonates bear similarities to stalagmites in their fabrics and the potential to obtain precise chronologies using U-series methods. Their chemical properties also reflect those of their parent waters, which, in contrast to stalagmites, are those of subglacial meltwaters. In analogy to speleothems, stable Carbon isotope ratios and trace elements such as Uranium, Iron and Manganese provide the opportunity to investigate ancient extreme environments without the need to drill through thousands of metres of ice. Sedimentological, geochemical and microbial evidence preserved in LGM subglacial calcites from Northern Victoria Land, close to the East Antarctic Ice Sheet margin, allow us to infer that subglacial volcanism was active in the Trans Antarctic Mountain region and induced basal ice melting. We hypothesize that a meltwater reservoir was drained and injected into interconnected basal pore systems where microbial processes enhanced bedrock weathering and, thus, released micronutrients. Volcanic influence is supported by the presence of fluorine (F) and sulphur in sediment-laden calcite layers containing termophilic species. Notably, calcite δ13C points to dissolved inorganic carbon evolved from subglacial metabolic processes. Once transported to the sea, soluble iron likely contributed to fertilizing the Southern Ocean and CO2 drawdown. This is the first well-dated evidence for LGM volcanism in Antarctica, which complements the record of volcanic eruptions retrieved from Talos Dome ice core, and supports the hypothesis of large-scale volcanism as an important driver of climate change. We conclude that subglacial carbonates are equivalent to speleothems in their palaeoclimate potential and may become a most useful source of information of ecosystems and processes at peak glacials in high altitude/high latitude settings.

Newly Described Tephra Provide Middle Pleistocene Age Constraints to Stegodon Fossils in West (Indonesian) Timor

NASA Astrophysics Data System (ADS)

Jensen, B. J. L.; Dufrane, A.; Mark, D.; Zaim, Y.; Rizal, Y.; Aswan, A.; Hascaryo, A.; Ciochon, R.; Gunnell, G.; Larick, R.; Zonnveld, J. P.

2017-12-01

As the Asian proboscidian Stegodon dispersed across Island Southeast Asia during the Pleistocene, multiple forms developed. On Timor, a southerly island east of Wallace's Line, the Ainaro gravels have yielded a highly dwarfed S. timorensis and a larger S. `trigonocephalus.' During a half-century of exploration, the age of the fossil bearing gravels remains in question, with only one age determination of >130 ka derived from six 230Th- 238U dates on a tusk fragment found in the Raebia area (Louys et al. 2016). Here we present radiometric ages for two tephra deposits bracketing Ainaro gravels at Raebia, a S. timorensis fossil locality 8 km northeast of Atambua city. The Raebia ravine exposes 2-10 meters of coarse-grained gravels incised into silt and clay deposits, bracketed by two indurated and largely devitrified tephras. Some intact glass was present to geochemically characterize each unit, which are both high-silica rhyolites. Biotite and zircons for 40Ar/39Ar and laser ablation U-Pb dating were extracted from the upper unit (Raebia Tuff 1; RT1), and zircons from the lower unit (Raebia Tuff 2; RT2). RT1 had zircons with two distinct age populations, but the youngest yield a 230Th deficiency corrected 206Pb/238U age of 665 ± 19 ka, (2s, n = 23, MSWD = 0.81), consistent with the 40Ar/39Ar age 614.9 ± 16.4 ka (2s, full external precision). Preliminary zircon dates on RT2 are more problematic, providing a large range that suggests inheritance by xenoliths and/or locally-sourced detrital zircons. However, a single zircon yielded 230Th deficiency corrected 206Pb/238U age of 708 ± 66 ka (2s, n=17, MSWD = 0.41), which is stratigraphically consistent. These are the first reliable age constraints on a higher elevation Ainaro gravel terrace and fossils they contain. The only other direct ages on the gravels are 230Th- 238U dates on lower terraces interbedded with coral, ranging from 130 ka to Holocene in age (Roosmawati and Harris 2009). These two newly described and dated tephra are likely regionally distributed and may represent important stratigraphic horizons for this portion of Southern Wallacea. They also provide useful data for calculating uplift rates for the region from the middle Pleistocene.

Results from the (U-Th)/He dating systems in Japan Atomic Energy Agency

NASA Astrophysics Data System (ADS)

Yamada, K.; Hanamuro, T.; Tagami, T.; Yamada, R.; Umeda, K.

2007-12-01

Japan Atomic Energy Agency (JAEA) has jointly set up the lab of the (U-Th)/He dating in cooperation with Kyoto University and National Research Institute for Earth Science and Disaster Prevention. We use the MM5400 rare gas mass spectrometer and the SPQ9000 ICP quadrupole mass spectrometer, belonging to JAEA, and built a new vacuum heater using infrared laser to extract helium. HF decomposes zircon after the alkali-fusion method using XRF bead sampler and LiBO3 in the preparation of ICP solution. Helium is quantified using sensitivity method. Uranium and thorium are using standard addition method. Quantifications of uranium-238 and thorium-232 are only need for parent isotopes to date samples because they are expected that the state of secular equilibrium becomes established and samarium does not compose the samples. At the present stage, we calibrate our systems by dating some standards, such as zircon from the Fish Canyon Tuff and apatite from the Durango, those are the international age standard, and apatite and zircon from the Tanzawa Tonalite Complex, that was dated in Yamada's PhD thesis, as a working standard. We report the results and detailed views of the dating systems.

76 FR 60805 - Quarterly Update to Annual Listing of Foreign Government Subsidies on Articles of Cheese Subject...

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2011-09-30

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77 FR 60105 - Honey From Argentina: Notice of Initiation of Antidumping and Countervailing Duty Changed...

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2012-10-02

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U-series ages of solitary corals from the California coast by mass spectrometry

USGS Publications Warehouse

Stein, Martin; Wasserburg, G.J.; Lajoie, K.R.; Chen, J.-H.

1991-01-01

The purpose of this study is to evaluate the feasibility of dating fossil solitary corals from Pleistocene marine strandlines outside tropical latitudes using the recently developed high sensitivity, high-precision U-series technique based on thermal-ionization mass-spectrometry (TIMS). The TIMS technique is much more efficient than conventional a spectrometry and, as a result, multiple samples of an individual coral skeleton, or different specimens from the same bed can be analyzed. Detached and well-rounded fossil specimens of the solitary coral Balanophyllia elegans were collected from relict littoral deposits on emergent marine terraces along the California coast at Cayucos terrace (elevation 8 m, previously dated at 124 and 117 Ky by ?? counting), Shell Beach terrace (elevation about 25 m, previously undated), Nestor terrace, San Diego (elevation 23 m, previously dated at 131 to 109 Ky ), Bird Rock terrace, San Diego ( elevation 8 m, previously dated at 81 Ky ). Attached living specimens were collected from the intertidal zone on the modern terrace at Moss Beach. Concentrations of 232Th in both living and fossil specimens are much higher than in reef-building corals (12 to 624 pmol/g vs. 0.1 to 1.6 pmol/g, respectively). However, because 230Th/232Th in Balanophyllia elegans are very low (2.22 ?? 10-3 to 4.33 ?? 10-4), the high 232Th concentrations have negligible effect on the 230Th-234U dates. The high 232Th concentration in the living specimen (33.1 pmol/g) indicates that a significant amount of 232Th is incorporated in the aragonitic skeleton during growth, or attached to clay-sized silicates trapped in the skeletal material. The calculated initial 234U activities in the fossil specimens of Balanophyllia elegans are higher than the 234U activity in modern seawater or in the modern specimen. The higher initial activities could possibly reflect the influx of 234U-enriched continental water into Pleistocene coastal waters, or it could reflect minor diagenetic alteration, a persistent and fundamental problem in dating all corals. Samples from a compound specimen from the Cayucos terrace were subjected to different preparation procedures. Samples prepared by a standard acid washing procedure yielded 230Th-234U ages of 125, 123, and 122 Ky, whereas samples prepared by an abbreviated procedure without acid washing yield significantly lower ages of 113 and 112 Ky. Two other specimens from the same bed yielded 230Th-234U ages of 118 and 115 Ky. Also, two specimens from a stratigraphically higher bed yielded ages of 120 and 117 Ky, and three specimens from a lower bed yield ages of 115, 113, and 101 Ky. Nine of the twelve ages of the treated samples from the Cayucos terrace range from 125 to 113 Ky. However, the ages do not follow the stratigraphie order. Two possible interpretations are ( 1 ) the age of the terrace deposit is 125 Ky and all younger ages reflect variable diagenetic alteration or (2) the age of the terrace is 125 to 113 Ky and the ages reflect sediment reworking over a period of 12 Ky. Three specimens from a single bed on the Shell Beach terrace yield ages of 126, 122, and 121 Ky, similar to the older ages from Cayucos. The ages of solitary corals from the Cayucos and Shell Beach terraces are similar to ages of reef-building corals from terraces at numerous tropical localities. These are correlated with the last interglacial sea-level highstand, which probably stood 2 to 10 m above present sea level. The youngest ages and present elevations of the Cayucos and Shell Beach terraces yield tectonic uplift rates of 0.01 and 0.15 m/Ky, respectively, assuming the original elevation of each terrace was 7 m. Four specimens from the basal gravel on the Nestor terrace yielded ages of 145, 143, 137, and 133 Ky. The three oldest ages, however, are older than that associated with the last interglacial. The possible explanations for these older ages are ( 1 ) diagenic alteration or ( 2 ) the Nestor terrace deposits reflect in s

Non-Reductive Strategies for U Sequestration: Natural Analogues and Practical Application

NASA Astrophysics Data System (ADS)

Maher, K.; Bethke, C. M.; Massey, M. S.

2011-12-01

A number of strategies have been proposed for the in situ remediation of U contaminated zones, including bioreduction, permeable reactive barriers, and incorporation into secondary phases such as phosphates. An alternative approach is to sequester U within amorphous Si phases such as opaline silica. We have investigated the isotopic and major element composition and structure of naturally occurring U-rich opaline silica in semi-arid soil environments across the western United States. These phases constitute a large natural reservoir of sequestered U. By combining these observations with geochemical considerations, we propose a remedial strategy for sequestering U in amorphous silica. The U-rich opal occurs as laminations, veins, and coatings on clasts in soils developed on a range of parent materials. U-rich opal deposits are also found as speleothems in caves, as silica-rich spring deposits, and as cavity fillings and hydrothermal veins in volcanic tuffs. Measurements of U, Th and Pb isotopes reveal the age of the opaline silica, demonstrating the long-term stability of U sequestration in open chemical environments. The isotopic data also suggest that opaline silica will retain the majority of the initial U over millions of years. U in naturally occurring opal generally ranges between 200 to 1000 ppm. In contrast, co-existing calcite contains less than 100 ppb U. From pore water chemistry, the distribution coefficient for U incorporation into opaline silica is approximately 20, whereas the coefficient for calcite is typically between 0.2 and 1. X-ray absorption spectroscopy investigations confirm that hexavalent U is incorporated in amorphous silica as the UO22+ ion. Coexisting Fe-oxides provide a further sink for sequestering UO22+ from the pore water. However, preliminary calculations suggest that incorporation of U into amorphous silica may be a dominant mechanism for isolating UO22+from groundwater over long time scales. Nature's mechanism for sequestering UO22+ from the environment might be profitably incorporated into groundwater remediation strategies. We consider a remedial strategy in which Na2SiO3 is amended into the subsurface. The silicate flood reacts with the surface acidity in the sediments to lower pH and precipitate amorphous silica. Hexavalent uranium is partitioned strongly into the silica, as well as complexed with the sediment surfaces.

A high-resolution geochronological and geochemical study on Aegean carbonate deposits, SW Turkey

NASA Astrophysics Data System (ADS)

Ünal-İmer, Ezgi; Uysal, I. Tonguç; Işık, Veysel; Zhao, Jian-Xin; Shulmeister, James

2014-05-01

Vein and breccia carbonates precipitated in highly fractured/faulted carbonate bedrock were investigated using high-resolution U-series geochronology, as well as through microstructural and geochemical studies including Sr-O-C isotope and REE element analyses. The study area (Kumlubük and Amos vein systems), located south of the town of Marmaris in SW Turkey, is a part of an active large-scale extensional system. Field studies show that the calcite veins generally occur sub-vertically and strike mostly NW and EW, in agreement with the regional N-S extensional stress regime. Microscopic observations indicate that the calcite veins formed through crack-seal mechanism, typically accompanied/initiated by intensive hydraulic fracturing of wall-rock evidenced by the presence of widespread breccia deposits. Vein textures are dominated by elongated, fibrous, and blocky calcites. Successive fracturing and layering of calcite with sharp contacts are traceable along the fluid inclusion bands occurring parallel to the wall rock boundary. In particular, inclusion trails aligned perpendicular to the wall-rock and calcite crystal elongation give information about the vein dilation (crack opening) vector and growth direction. High-resolution U-series dating (11-272 ka BP) and geochemical compositions of the vein and breccia samples were used to investigate the long-term behaviour as well as the general identity of the CO2-bearing fluids within deformed crust. The seismic nature of calcite veining is further assessed by stable isotopic ratio (δ18O and δ13C) plots against vein depths (distance from the wall-rock). The average δ18OPDBvalue for Kumlubük veins is -3.79o, while Amos has an average value of -4.05o. Similarly, average carbon isotope ratio (-8.30o) of the Kumlubük veins is slightly higher than that is observed for the Amos veins (-9.66o). Isotopic compositions are interpreted to reflect cyclic (or episodic) CO2 variations. This suggests the presence of several fluid sources and mechanisms (e.g. luid-rock interaction) indicating the significance of pressure and temperature controls on the evolution of the CO2-bearing fluid system. Sr-isotope ratios (87Sr/86Sr: 0.7082-0.7085) in combination with REE compositions are used to trace fluid sources. REE data of the veins from both regions show typical seawater signatures with distinct negative Ce and positive Y anomalies, which corresponds well with the REE composition of the host limestone. While majority of the samples show similar PAAS-normalised REE variations, some of the veins further display positive Eu anomalies, which could be indicative of contribution from a deeply derived, hot, and reduced fluid component.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aciego, S.M.; Jourdan, F.; DePaolo, D.J.

Late Quaternary, post-shield lavas from the Mauna Kea and Kohala volcanoes on the Big Island of Hawaii have been dated using the {sup 40}Ar/{sup 39}Ar and U-Th/He methods. The objective of the study is to compare the recently demonstrated U-Th/He age method, which uses basaltic olivine phenocrysts, with {sup 40}Ar/{sup 39}Ar ages measured on groundmass from the same samples. As a corollary, the age data also increase the precision of the chronology of volcanism on the Big Island. For the U-Th/He ages, U, Th and He concentrations and isotopes were measured to account for U-series disequilibrium and initial He. Singlemore » analyses U-Th/He ages for Hamakua lavas from Mauna Kea are 87 {+-} 40 ka to 119 {+-} 23 ka (2{sigma} uncertainties), which are in general equal to or younger than {sup 40}Ar/{sup 39}Ar ages. Basalt from the Polulu sequence on Kohala gives a U-Th/He age of 354 {+-} 54 ka and a {sup 40}Ar/{sup 39}Ar age of 450 {+-} 40 ka. All of the U-Th/He ages, and all but one spurious {sup 40}Ar/{sup 39}Ar ages conform to the previously proposed stratigraphy and published {sup 14}C and K-Ar ages. The ages also compare favorably to U-Th whole rock-olivine ages calculated from {sup 238}U - {sup 230}Th disequilibria. The U-Th/He and {sup 40}Ar/{sup 39}Ar results agree best where there is a relatively large amount of radiogenic {sup 40}Ar (>10%), and where the {sup 40}Ar/{sup 36}Ar intercept calculated from the Ar isochron diagram is close to the atmospheric value. In two cases, it is not clear why U-Th/He and {sup 40}Ar/{sup 39}Ar ages do not agree within uncertainty. U-Th/He and {sup 40}Ar/{sup 39}Ar results diverge the most on a low-K transitional tholeiitic basalt with abundant olivine. For the most alkalic basalts with negligible olivine phenocrysts, U-Th/He ages were unattainable while {sup 40}Ar/{sup 39}Ar results provide good precision even on ages as low as 19 {+-} 4 ka. Hence, the strengths and weaknesses of the U-Th/He and {sup 40}Ar/{sup 39}Ar methods are complimentary for basalts with ages of order 100-500 ka.« less

14C plateaus and global stratigraphic correlation during Termination IA

NASA Astrophysics Data System (ADS)

Sarnthein, M.; Grootes, P. M.; Kennett, J. P.; Nadeau, M.

2006-12-01

In search of a global 14C reference record for Termination IA, we analyzed three published 14C records with centennial-scale resolution, that provide independent evidence for calibrating the 14C time scale: (1) A sediment record from Cariaco Basin (ODP Site 1002) correlated to the U/Th-dated Hulu Cave record (Hughen et al., 2006), (2) a U/Th dated speleothem record from the Bahamas (Beck et al., 2001, 2006), and (3) a set of U/Th-dated coral ages (IntCal04 plus Fairbanks et al., 2005) that unfortunately lack data from 18-15 cal. ka. All these records exhibit significant changes in the slope of 14C vs. calendar ages, allowing us to define a suite of major and minor "14C plateaus" in each record, that in total occupy >70% of the 14C record between 19 and 14 cal. ka. Despite their different origin the three records are largely consistent. When dating resolution is sufficient, most plateaus show a characteristic internal structure incorporating 14C inversions, in particular near the onset of a plateau. Plateau boundary ages for the Cariaco record have a total range of uncertainty of 150-450 yr due to uncertainties with age calibration (Hughen et al., 2006), in addition to the range of dating resolution. During Termination IA, a period of dramatic climate change, these boundary ages should serve as datums for the global correlation of marine sediment records. Moreover, they are employed to deduce apparent paleoventil-ation ages and thus circulation patterns of surface and bottom water masses, as demonstrated for example from the northern Pacific and the Icelandic Sea.

UDATE1: A computer program for the calculation of uranium-series isotopic ages

USGS Publications Warehouse

Rosenbauer, R.J.

1991-01-01

UDATE1 is a FORTRAN-77 program with an interface for an Apple Macintosh computer that calculates isotope activities from measured count rates to date geologic materials by uranium-series disequilibria. Dates on pure samples can be determined directly by the accumulation of 230Th from 234U and of 231Pa from 235U. Dates for samples contaminated by clays containing abundant natural thorium can be corrected by the program using various mixing models. Input to the program and file management are made simple and user friendly by a series of Macintosh modal dialog boxes. ?? 1991.

U-Th isotopic systematics and ages of carbonate chimneys at the Lost City Hydrothermal Field

NASA Astrophysics Data System (ADS)

Ludwig, K. A.; Shen, C.; Kelley, D. S.; Cheng, H.; Edwards, R.

2009-12-01

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th isotopic systematics of hydrothermal fluids and the 230Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples with <15 mmol/kg Mg, 232Th concentration is 0.11 to 0.13 pg/g and surrounding seawater concentration average is 0.133 ± 0.016 pg/g. The 230Th/232Th atomic ratios of the vent fluids range from 1 ± 10 to 26 ± 4 ×10-6 and are less than those of seawater. Chimney U is seawater-derived and 238U concentrations range from 1-10 μg/g and the mean chimney corrected initial δ234U is 146.9 ± 0.5, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate thorium concentrations range broadly from 0.035-125 ng/g and 230Th/232Th atomic ratios vary from near seawater values of 43 ± 8 × 10-6 up to 530 ± 25 × 10-3. Chimney ages range from 18 ± 6 yrs to 122 ± 12 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.

U-Th systematics and 230Th ages of carbonate chimneys at the Lost City Hydrothermal Field

NASA Astrophysics Data System (ADS)

Ludwig, Kristin A.; Shen, Chuan-Chou; Kelley, Deborah S.; Cheng, Hai; Edwards, R. Lawrence

2011-04-01

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the 230Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The 230Th/ 232Th atomic ratios of the vent fluids range from 1 (±10) × 10 -6 to 11 (±5) × 10 -6, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic 230Th to the LCHF carbonate chimney deposits. Chimney 238U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ 234U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate 232Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and 230Th/ 232Th atomic ratios vary from near seawater values of 43 (±8) × 10 -6 up to 530 (±25) × 10 -3. Chimney ages, corrected for initial 230Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.

Widespread Lake Highstands in the Southernmost Andean Altiplano during Heinrich Event 1: Implications for the South American Summer Monsoon

NASA Astrophysics Data System (ADS)

Chen, C. Y.; McGee, D.; Quade, J.

2014-12-01

Speleothem-based oxygen isotope records provide strong evidence of anti-phased behavior of the northern and southern hemisphere summer monsoons during Heinrich events, but we lack rigorous constraints on the amount of wetting or drying occurring in monsoon regions. Studies centered on shoreline deposits of closed-basin lakes are well suited for establishing such quantitative controls on water balance changes by providing unequivocal evidence of lake volume variations. Here we present new dating constraints on the highstands of several high-altitude (3800-4350 m) paleolakes in the southern Andean Altiplano, an outlying arid region of the Atacama Desert stretching across the Chilean-Bolivian-Argentinian border east of the Andes (20-25°S). These lakes once occupied the closed basins where only phreatic playas, dry salars, and shallow ponds exist today. Initial U-Th dating of massive shoreline tufas reveals that these deposits are dateable to within ±150 to 300 yrs due to high U concentrations and low initial Th content (as indicated by high 230Th/232Th). Our U-Th and 14C dates show that lake highstands predominantly occur between 18.5 and 14.5 kyrs BP, coinciding with Heinrich Event 1 (HE1) and the expansion of other nearby lakes, such as Lake Titicaca. Because of their (1) location at the modern-day southwestern edge of the summer monsoon, (2) intact shoreline preservation, and (3) precise age control, these lakes may uniquely enable us to reconstruct the evolution of water balance (P-E) changes associated with HE1. Hydrologic modeling constrained by temperature estimates provided by local glacial records is used to provide bounds for past precipitation changes. We also examine North Atlantic cooling as the mechanism for these changes by comparing a compilation of S. American lake level records with various hosing experiments and transient climate simulations at HE1. Our results lend us confidence in expanding our U-Th work to other shoreline tufas in the surrounding region to produce a more detailed, spatiotemporal record of water balance changes in S. America.

Trace element geochemistry and surface water chemistry of the Bon Air coal, Franklin County, Cumberland Plateau, southeast Tennessee

USGS Publications Warehouse

Shaver, S.A.; Hower, J.C.; Eble, C.F.; McLamb, E.D.; Kuers, K.

2006-01-01

Mean contents of trace elements and ash in channel, bench-column, and dump samples of the abandoned Bon Air coal (Lower Pennsylvanian) in Franklin County, Tennessee are similar to Appalachian COALQUAL mean values, but are slightly lower for As, Fe, Hg, Mn, Na, Th, and U, and slightly higher for ash, Be, Cd, Co, Cr, REEs, Sr, and V, at the 95% confidence level. Compared to channel samples, dump sample means are slightly lower in chalcophile elements (As, Cu, Fe, Ni, Pb, S, Sb, and V) and slightly higher in clay or heavy-mineral elements (Al, K, Mn, REEs, Th, Ti, U, and Y), but at the 95% confidence level, only As and Fe are different. Consistent abundances of clay or heavy-mineral elements in low-Br, high-S, high-ash benches that are relatively enriched in quartz and mire-to-levee species like Paralycopodites suggest trace elements are largely fluvial in origin. Factor analysis loadings and correlation coefficients between elements suggest that clays host most Al, Cr, K, Ti, and Th, significant Mn and V, and some Sc, U, Ba, and Ni. Heavy accessory minerals likely house most REEs and Y, lesser Sc, U, and Th, and minor Cr, Ni, and Ti. Pyrite appears to host As, some V and Ni, and perhaps some Cu, but Cu probably exists largely as chalcopyrite. Data suggest that organic debris houses most Be and some Ni and U, and that Pb and Sb occur as Pb-Sb sulfosalt(s) within organic matrix. Most Hg, and some Mn and Y, appear to be hosted by calcite, suggesting potential Hg remobilization from original pyrite, and Hg sorption by calcite, which may be important processes in abandoned coals. Most Co, Zn, Mo, and Cd, significant V and Ni, and some Mn probably occur in non-pyritic sulfides; Ba, Sr, and P are largely in crandallite-group phosphates. Selenium does not show organic or "clausthalite" affinities, but Se occurrence is otherwise unclear. Barium, Mn, Ni, Sc, U, and V, with strongly divided statistical affinities, likely occur subequally in multiple modes. For study area surface waters, highest levels of most trace elements occur in mine-adit or mine-dump drainage. Effluent flow rates strongly affect both acidity and trace element levels. Adit drainages where flow is only a trickle have the most acidic waters (pH 3.78-4.80) and highest trace element levels (up to two orders of magnitude higher than in non-mine site waters). Nonetheless, nearly all surface waters have low absolute concentrations of trace elements of environmental concern, and all waters sampled meet U.S. EPA primary drinking water standards and aquatic life criteria for all elements analyzed. Secondary drinking water standards are also met for all parameters except Al, pH, Fe, and Mn, but even in extreme cases (mine waters with pH as low as 3.78 and up to 1243 ppb Al, 6280 ppb Fe, and 721 ppb Mn, and non-mine dam-outflow waters with up to 18,400 ppb Fe and 1540 ppb Mn) downslope attenuation is apparently rapid, as down-drainage plateau-base streams show background levels for all these parameters. ?? 2005 Elsevier B.V. All rights reserved.

Uranium-Series Dating of the East Franklin Mountain's Fault Carbonates in El Paso, Texas

NASA Astrophysics Data System (ADS)

Garcia, V. H.; Ma, L.; Pavlis, T. L.; Hurtado, J. M., Jr.

2017-12-01

Direct dating of fault activity is a fundamentally important part of many paleoseismic studies and has potential implications on the quantity, magnitude, recurrence intervals, and timing of earthquake occurrences in the past and future. Faults in the Rio Grande Rift (RGR) in southern New Mexico and West Texas have often been overlooked in seismic hazard assessments due to inferred low tectonic rates and long recurrence intervals. However, there is geologic evidence from surface ruptures that at least 22 large earthquakes (M > 6.25) have occurred in the RGR within the last 10,000 kyrs. The binational conurbation of the El Paso-Juarez region (home to 2.3 million people) lies in the southern extent of the RGR and is traversed by many Quaternary faults, which pose a potentially catastrophic hazard for the region. One fault in particular, the East Franklin Mountains fault (EFMF), is made up of many smaller fault segments that cross through heavily populated areas of the El Paso-Juarez region. Direct dating of past movement on a central segment of the EFMF is a fundamental and important piece of the puzzle in understanding when and how often seismic activity occurred in the fault. In this study, we applied Uranium-series (U-series) dating of fault carbonates collected from a trench that was dug on the central segment of the EFMF. Fault related calcite precipitants and pedogenic carbonates from a nearby soil profile were collected to (1) constraint the timing of past fault activity and (2) understand the relationship and timing of pedogenic carbonate formation away from the EFMF. U-series dating reveals that pedogenic carbonates collected from colluvial wedges along the fault are approximately half the optically stimulated luminescence age of the deposits, suggesting the U-Series dates record a relatively continuous accumulation of carbonates post-deposition. U-Series dates from within the EFMF, however, provided potentially the best estimates for the age of the most recent seismic event with ages of 10 - 12 kyrs, suggesting this method has potential broader applications in paleoseismic studies.

Calibrating multiple isotopic proxies in a modern aragonite speleothem from northeast India

NASA Astrophysics Data System (ADS)

Ronay, E.; Oster, J. L.; Sharp, W. D.; Marks, N.; Erhardt, A.; Breitenbach, S. F. M.

2017-12-01

Uranium, strontium, and calcium isotope ratios in calcite speleothems are used as proxies for water-soil-rock interactions and prior calcite precipitation, and thus provide information about effective rainfall amount variations, primarily in semi-arid or highly seasonal regions. However, less is known about how these proxies function in humid regions and in aragonite speleothems. In this study, we use meteorological data to calibrate (234U/238U)i and 87Sr/86Sr in a modern aragonite speleothem from northeast India, the rainiest place on Earth, to determine how these proxies reflect effective monsoon rainfall amount. MAW-0201 is an annually laminated aragonite stalagmite that grew from 1960-2013 in Mawmluh Cave, Meghalaya, India. Rainfall here is extremely seasonal due to the Indian Summer Monsoon (ISM), which brings several meters of rain to the region each summer, but with inter-annual variability in total rainfall. The δ18O in Mawmluh dripwater and speleothems reflects moisture source and transport, rather than rainfall amount. Variations in Mg, U, and Ba concentrations in MAW-0201 show seasonal and multi-annual variability. U and Mg are closely correlated, but multi-year periods show significant anti-correlation. The Mg and U distribution coefficients in calcite and aragonite indicate correlated periods are times of prior calcite precipitation (PCP) and anti-correlated periods are times of prior aragonite precipitation (PAP) in the epikarst. We use δ44/40Ca to test this hypothesis, as Ca isotopes fractionate differently during calcite and aragonite precipitation and speleothem δ44/40Ca will record unique PAP and PCP fingerprints. We propose such shifts from PCP to PAP reflect hydrologic variability and/or flow path changes, which provide a useful tool for understanding epikarst hydrology but may also be a complicating factor in speleothem-based paleoclimate interpretations. Preliminary (234U/238U)i (always <1) and 87Sr/86Sr spanning 1991-2009 each show significant variability outside of analytical error. (234U/238U)i displays a decadal trend, gradually increasing until 2000 and decreasing to the end of the record. Several years in the 87Sr/86Sr record have anomalously high values, which may reflect increased sea spray input and provide unique information on the wind component of the ISM.

Mineral types of hydrothermal alteration zones in the Dukat ore field and their relationships to leucogranite and epithermal gold-silver ore, northeastern Russia

NASA Astrophysics Data System (ADS)

Filimonova, L. G.; Trubkin, N. V.; Chugaev, A. V.

2014-05-01

The paper considers the localization of potassic and propylitic hydrothermal alteration zones in the domal volcanic-plutonic structure controlling the position of the Dukat ore field with the eponymous unique epithermal Au-Ag deposit. Comprehensive mineralogical and geochemical data on rocks and minerals in hydrothermal alteration zones and associated intrusions have shown that quartz-jarosite-sericite, quartz-pyrite-sericite, and quartz-adularia-chlorite alterations were formed with the participation of fluid flows related to a fingerlike projection of a high-K leucogranite porphyry intrusion with large phenocrysts. These hydrothermal alterations developed in the rifted graben under conditions of divergent plate boundaries, whereas quartz-clinozoisite-calcite, epidote-chlorite, and garnet-calcite-chlorite alterations were linked to K-Na leucogranite intrusive bodies and developed under conditions of convergent plate boundaries reactivated as a result of formation of the marginal Okhotsk-Chukotka volcanic belt. Phase separation and coagulation of specific portions of ascending fluids resulted in the formation and stabilization of small-sized particles of native silver and other ore components, which enabled involvement in flows of secondary geothermal solutions and ore-forming fluids. The Sr, Nd, and Pb isotopic compositions of rocks and minerals from the hydrothermal alteration zones, associated intrusions, and economic orebodies at the Dukat deposit indicate that their components have been derived from the juvenile continental crust, which was altered in pre-Cretaceous periods of endogenic activity. The components of gangue minerals of potassic and propylitic hydrothertmal alterations and associated intrusions have been taken from deep sources differing in 87Sr/86Sr and 143Nd/144Nd at similar U/Pb and Th/Pb ratios. Chalcophile lead in products of hydrothermal activity and melanocratic inclusions in leucogranite has been taken from regions with elevated U/Pb and Th/Pb ratios.

Late Permian volcanic dykes in the crystalline basement of the Považský Inovec Mts. (Western Carpathians): U-Th-Pb zircon SHRIMP and monazite chemical dating

NASA Astrophysics Data System (ADS)

Pelech, Ondrej; Vozárová, Anna; Uher, Pavel; Petrík, Igor; Plašienka, Dušan; Šarinová, Katarína; Rodionov, Nikolay

2017-08-01

This paper presents geochronological data for the volcanic dykes located in the northern Považský Inovec Mts. The dykes are up to 5 m thick and tens to hundreds of metres long. They comprise variously inclined and oriented lenses, composed of strongly altered grey-green alkali basalts. Their age was variously interpreted and discussed in the past. Dykes were emplaced into the Tatricum metamorphic rocks, mostly consisting of mica schists and gneisses of the Variscan (early Carboniferous) age. Two different methods, zircon SHRIMP and monazite chemical dating, were applied to determine the age of these dykes. U-Pb SHRIMP dating of magmatic zircons yielded the concordia age of 260.2 ± 1.4 Ma. The Th-U-Pb monazite dating of the same dyke gave the CHIME age of 259 ± 3Ma. Both ages confirm the magmatic crystallization at the boundary of the latest Middle Permian to the Late Permian. Dyke emplacement was coeval with development of the Late Paleozoic sedimentary basin known in the northern Považský Inovec Mts. and could be correlated with other pre-Mesozoic Tethyan regions especially in the Southern Alps.

(U/Th)-He dating of Fe- and Mn-oxide minerals from the Buckskin-Rawhide detachment fault: a new method to determine timing of faulting and fluid flow

NASA Astrophysics Data System (ADS)

Evenson, N. S.; Reiners, P. W.; Spencer, J. E.

2012-12-01

The Buckskin-Rawhide-Harcuvar detachment fault is one of the largest and youngest extensional detachment faults on Earth. It is also associated with abundant deposits of specular hematite with less common Pb, Zn, Ag, Au, and Mn mineralization. Mineralization is thought to be the result of movement of basin brines along the active detachment and subsidiary normal faults, with circulation driven by the heat of the uplifted footwall rocks of the Harcuvar metamorphic core complex. (U/Th)-He dating of specular hematite from the Buckskin-Rawhide detachment system, and Mn oxide minerals from syn-extensional clastic sedimentary rocks directly above the detachment fault, yield ages primarily between 16-10 Ma. These ages are consistent with low-temperature apatite (U/Th)-He and fission track cooling ages from the Rawhide Mountains and other ranges along the detachment. This suggests that Fe and Mn mineralization occurred during a period of rapid footwall exhumation that was underway by ~16 Ma. Aliquots from four hematite samples from the eastern Rawhide Mountains yielded weighted mean ages of 12.1 ± 0.24 Ma, 12.8 ± 0.15 Ma, 13.1 ± 0.17 Ma, and 13.8 ± 0.20 Ma (all uncertainties as 2-sigma standard error). These ages are similar to apatite (U/Th)-He and fission track ages of nearby samples, and display a SW to NE-younging trend when projected parallel to the extension direction, consistent with findings from previous low-T thermochronology studies. Three hematite samples from the western Rawhide and Buckskin Mountains yield more dispersed ages than samples in the eastern part of the core complex. Published apatite fission-track and (U/Th)-He dates from the Rawhide and Buckskin Mountains fall between 16-10 Ma. These ages are interpreted to represent the timing of final tectonic exhumation and fault-driven fluid circulation along the detachment. Average ages for one hematite sample fall in this age range, but one other is younger (9.5 Ma) and another is substantially older (35 Ma). The older age age may indicate the presence of excess He in fluid inclusions. The younger age could indicate that hydrothermal circulation outlasted exhumation by several million years, or other unknown complications to the system. (U/Th)-He analysis of two samples of manganese oxides from the Artillery Mountains yielded weighted mean ages of 13.8 ± 0.20 and 8.12 ± 0.13 Ma. Both ages are consistent with the age of host strata, and suggest that these dates record near-surface mineralization that occurred shortly after the syn-extension host sandstone and conglomerate were deposited. Our results suggest that hematite and manganese oxide (U/Th)-He systems can provide information about the timing of faulting and related fluid flow/mineralization events. With further development in this and other localities, these systems have the potential to provide valuable insights that until now have been difficult or impossible to obtain by other methods.

Constraining Circulation Changes Through the Last Deglaciation with Deep-sea Coral Radiocarbon and Sedimentary Pa231/Th230

DTIC Science & Technology

2012-02-01

et al. (2002), U-Th dating of marine isotope stage 7 in Bahamas slope sediments, Earth and Planetary Science Letters, 196(3-4), Pii S0012- 821x(01...and radioisotope studies, Earth Planet. Sci. Lett., 32(2), 420–429, doi:10.1016/ 0012-821X(76)90082-0. Krishnaswami, S., M. M. Sarin, and B. L. K...degree of Doctor of Philosophy ABSTRACT Radioactive isotopes can be used in paleoceanography both for dating samples and as tracers of ocean

1. PHOTOGRAPHIC COPY OF MAP OF FORT BLISS DATED JUNE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. PHOTOGRAPHIC COPY OF MAP OF FORT BLISS DATED JUNE 15, 1934, REVISED TO JUNE 1, 1940, DRAWING No. FB-DWG-434, ORIGINAL ON FILE IN DIRECTORATE OF FACILITIES ENGINEERING, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

4. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED MAY 13, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED MAY 13, 1919, DETACHMENT BARRACK WITHOUT MESS, WAR DEPARTMENT, CONSTRUCTION DIVISION, PLAN # 353, COPY ON FILE IN THE ENVIRONMENTAL MANAGEMENT OFFICE, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

75 FR 75698 - Sunshine Act Notice

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-06

... DEPARTMENT OF JUSTICE Parole Commission Sunshine Act Notice Public Announcement; Pursuant to the Government in the Sunshine Act (Pub. L. 94-409) [5 U.S.C. Section 552b] DATE AND TIME: 12 a.m., Tuesday, December 7, 2010. PLACE: U.S. Parole Commission, 5550 Friendship Boulevard, 4th Floor Chevy Chase, Maryland...

A 10,000 yr record of high-resolution Paleosecular Variation from a flowstone of Rio Martino Cave, Northwestern Alps, Italy

NASA Astrophysics Data System (ADS)

Zanella, Elena; Tema, Evdokia; Lanci, Luca; Regattieri, Eleonora; Isola, Ilaria; Hellstrom, John C.; Costa, Emanuele; Zanchetta, Giovanni; Drysdale, Russell N.; Magrì, Federico

2018-03-01

Speleothems are potentially excellent archives of the Earth's magnetic field, capable of recording its past variations. Their characteristics, such as the continuity of the record, the possibility to be easily dated, the almost instantaneous remanence acquisition and the high time-resolution make them potentially unique high-quality Paleosecular Variation (PSV) recorders. Nevertheless, speleothems are commonly characterized by low magnetic intensities, which often limits their resolution. Here we present a paleomagnetic study performed on two cores from a flowstone from the Rio Martino Cave (Western Alps, Italy). U/Th dating indicates that the flowstone's deposition covers almost the entire Holocene, spanning the period ca. 0.5-9.0 ka, while an estimation of its mean growth rate is around 1 mm per 15 years. The flowstone is composed of columnar calcite, characterized by a highly magnetic detrital content from meta-ophiolites in the cave's catchment. This favorable geological context results in an intense magnetic signal that permits the preparation and measurement of thin (∼3 mm depth equivalent) samples, each representing around 45 yr. The Characteristic Remanent Magnetization (ChRM), isolated after systematic stepwise Alternating Field demagnetization, is well defined, with Maximum Angular Deviation (MAD) generally lower than 10°. Paleomagnetic directional data allow the reconstruction of the PSV path during the Holocene for the area. Comparison of the new data with archeomagnetic data from Italian archeological and volcanic records and using the predictions of the SHA.DIF.14k and pfm9k.1a global geomagnetic field models shows that the Rio Martino flowstone represents an excellent recorder of the Earth's magnetic field during the last 9,000 years. Our high resolution paleomagnetic record, anchored by a high-quality chronology, provides promising data both for the detection of short term geomagnetic field variations and for complementing existing regional PSV curves for the prehistoric period, for which well-dated data are still scarce.

Formation of amorphous calcium carbonate in caves and its implications for speleothem research.

PubMed

Demény, Attila; Németh, Péter; Czuppon, György; Leél-Őssy, Szabolcs; Szabó, Máté; Judik, Katalin; Németh, Tibor; Stieber, József

2016-12-22

Speleothem deposits are among the most valuable continental formations in paleoclimate research, as they can be dated using absolute dating methods, and they also provide valuable climate proxies. However, alteration processes such as post-depositional mineralogical transformations can significantly influence the paleoclimatic application of their geochemical data. An innovative sampling and measurement protocol combined with scanning and transmission electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy is presented, demonstrating that carbonate precipitating from drip water in caves at ~10 °C contains amorphous calcium carbonate (ACC) that later transforms to nanocrystalline calcite. Stable oxygen isotope fractionations among calcite, ACC and water were also determined, proving that ACC is 18 O-depleted (by >2.4 ± 0.8‰) relative to calcite. This, in turn, has serious consequences for speleothem-based fluid inclusion research as closed system transformation of ACC to calcite may induce a negative oxygen isotope shift in fluid inclusion water, resulting in deterioration of the original compositions. ACC formation increases the speleothems' sensitivity to alteration as its interaction with external solutions may result in the partial loss of original proxy signals. Mineralogical analysis of freshly precipitating carbonate at the studied speleothem site is suggested in order to determine the potential influence of ACC formation.

Examining the ground layer of St. Anthony from Padua 19th century oil painting by Raman spectroscopy, scanning electron microscopy and X-ray diffraction

NASA Astrophysics Data System (ADS)

Vančo, Ľubomír; Kadlečíková, Magdaléna; Breza, Juraj; Čaplovič, Ľubomír; Gregor, Miloš

2013-01-01

In this paper we studied the material composition of the ground layer of a neoclassical painting. We used Raman spectroscopy (RS) as a prime method. Thereafter scanning electron microscopy combined with energy dispersive spectroscopy (SEM-EDS) and X-ray powder diffraction (XRD) were employed as complementary techniques. The painting inspected was of the side altar in King St. Stephen's Church in Galanta (Slovakia), signed and dated by Jos. Chr. Mayer 1870. Analysis was carried out on both covered and uncovered ground layers. Four principal compounds (barite, lead white, calcite, dolomite) and two minor compounds (sphalerite, quartz) were identified. This ground composition is consistent with the 19th century painting technique used in Central Europe consisting of white pigments and white fillers. Transformation of lead white occurred under laser irradiation. Subdominant Raman peaks of the components were measured. The observed results elucidate useful partnership of RS and SEM-EDS measurements supported by X-ray powder diffraction as well as possibilities and limitations of non-destructive analysis of covered lower layers by RS.

NanoSIMS U-Pb dating of hydrothermally altered monazite: Constraints on the Timing of LaoZaiWan Carlin-type gold deposit in the golden triangle region, SW China

NASA Astrophysics Data System (ADS)

PI, Q.

2017-12-01

Abstract: Direct dating of Carlin-type Au deposits was restricted due to the absence of a geochronometer. Back-scattered electron (BSE) imaging and X-ray element mapping of monazite in gold-rich ore samples from the LaoZaiWan Au deposit in SW China, reveal the presence of distinct, high-Th cores surrounded by low-Th, inclusion-rich rims. The monazite grain is considered to be the product of fluid-aided coupled dissolution-reprecipitation during Au mineralization via prograde metamorphic reactions. We present results of in situ NonSIMS U-Pb dating applied to the rims of monazite . NonSIMS U-Pb age of hydrothermal monazite gave ages of 228 ± 9 Ma(2σ) and 230 ± 16 Ma(2σ) for LaoZaiWan Au deposit. These ages are interpreted as Au mineralization ages, which consistent with the Re-Os age of arsenopyite for JinYa Au deposit, the U-Pb age of rutile for and 40Ar-39Ar age of sericite for Zhesang Au deposit. We postulate that the formation of the Carlin-type Au deposits in the Golden Triangle region was triggered by the Indosinian Orogen, related to collision of the Indochina Block with South China Block.

Equilibrium and Disequilibrium of 230Th-238U in Zircon from the Minoan Eruption, Santorini, Aegean Sea, Greece

NASA Astrophysics Data System (ADS)

Schmitt, A. K.; Stockli, D. F.; Song, E. J.; Storm, S.

2016-12-01

The Minoan eruption (ca. 1600 BCE; 40-80 km3 dense rock equivalent) occurred after a ca. 18 ka period of dormancy followed by rapid reinvigoration through arrival of new magma from deep reservoirs colliding with evolved magmas in shallow storage. Although zoned phenocrysts indicate brief timescales ranging between years to decades for final pre-eruptive magma recharge and mixing, it remains unclear how magma accumulation vs. crystallization were balanced in the subvolcanic reservoir during the preceding inter-eruptive cycle. To directly probe magma presence over the repose interval prior to the Minoan eruption and further back in time, we reconnoitered the potential of U-Th zircon geochronology to date the crystallization of individual zircon crystals from pumice from the Minoan eruption. Zircon crystals were extracted from composite pumice samples (several kg each) from basal fall out deposits using gravity and magnetic separation. Etching in cold HF removed adherent glass and revealed the shape of crystals, which were pressed into indium metal to expose unpolished rims to the ion beam of a CAMECA IMS 1270 secondary ionization mass spectrometer. Adherent glass was ubiquitous, indicating that crystals were in contact with melt at the time of eruption. Six of 18 crystals were in 230Th/238U secular equilibrium, two crystals yielded ages of ca. 160 ka, and the remaining rims dated between eruption age and ca. 20 ka. Low Th/U of some secular equilibrium zircon suggests recycling of metamorphic basement zircon, which is also indicated by the presence of rutile in heavy mineral separates. U-Th dates also reveal recycling of zircon from Pleistocene intrusions that likely represent left-over magma from antecedent eruption cycles. We tentatively interpret the dominant zircon population with near-eruption to ca. 20 ka ages to indicate continuous melt presence underneath Santorini during the last repose interval. Distinguishing a hiatus in zircon crystallization between 20 ka and 160 ka from continuous presence of a crystal mush capable of crystallizing zircon throughout the late Pleistocene requires further analyses. A corollary of mixed zircon populations of heterogeneous provenance in Minoan pumice is that the age significance of U-series data for major phases analyzed in bulk is suspect.

ESR and 230Th/234U dating of speleothems from Aladağlar Mountain Range (AMR) in Turkey

NASA Astrophysics Data System (ADS)

Ulusoy, Ülkü; Anbar, Gül; Bayarı, Serdar; Uysal, Tonguç

2014-03-01

Electron spin resonance (ESR) and 230Th/234U ages of speleothem samples collected from karstic caves located around 3000 m elevation in the Aladağlar Mountain Range (AMR), south-central Turkey, were determined in order to provide new insight and information regarding late Pleistocene climate. ESR ages were validated with the 230Th/234U ages of test samples. The ESR ages of 21 different layers of six speleothem samples were found to range mostly between about 59 and 4 ka, which cover the Marine Oxygen Isotope Stages (MIS) MIS 3 to MIS 1. Among all, only six layers appear to have deposited during MIS 8 and 5. Most of the samples dated were deposited during the late glacial stage (MIS 2). It appears that a cooler climate with a perennial and steady recharge was more conducive to speleothem development rather than a warmer climate with seasonal recharge in the AMR during the late Quaternary. This argument supports previous findings that suggest a two -fold increase in last glacial maximum mean precipitation in Turkey with respect to the present value.

Correlating rates of magmatic arc unroofing and sedimentation using detrital zircon U/Pb and (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Fosdick, J. C.

2017-12-01

Double and triple dating of minerals using multiple geo-thermochronometers has revolutionized efforts to evaluate complex thermotectonic histories of orogens, isolate unique sedimentary sources, and quantify basin burial reheating. A persisting challenge is to distinguish volcanic sources from rapidly exhumed sources, with the simplistic premise that coincident cooling dates among high- to low-temperature thermochronometers are diagnostic of volcanic sources. Coupled zircon U/Pb and (U-Th)/He geo-thermochronometry from the Miocene Bermejo foreland basin in the southern Central Andes reveals a high temporal resolution of unroofing signatures of the Choiyoi Group, a Permian-Triassic silicic volcanic and plutonic complex, and the Pennsylvanian-Permian Colangüil batholith. Both units are important sediment sources within the High Andes for the Cenozoic east-flowing sediment routing systems. Results show fluvial sourcing of Colangüil detrital zircons with progressively greater partial loss of He (<8% to 12-23% fractional loss from 9.5 Ma to 6 Ma), as indicated by upsection younging of zircon He dates for a given U/Pb age cluster. These findings suggest erosion of increasingly deeper levels of the Colangüil arc during late Miocene development of the High Andes. This progression of higher He loss and thus younger He dates during sedimentation for a given U/Pb age cluster is analogous to the magmatic arc unroofing trend revealed by undissected to dissected arc provenance fields in sandstone petrography. Multi-method thermochronometry of detrital minerals may reveal an added level of information regarding rates of cooling, unroofing, and thermal evolution of magmatic systems as preserved in the detrital record.

Uranium Isotopes in Calcium Carbonate: A Possible Proxy for Paleo-pH and Carbonate Ion Concentration?

NASA Astrophysics Data System (ADS)

Chen, X.; Romaniello, S. J.; Herrmann, A. D.; Wasylenki, L. E.; Anbar, A. D.

2015-12-01

Natural variations of 238U/235U in marine carbonates are being explored as a paleoredox proxy. However, in order for this proxy to be robust, it is important to understand how pH and alkalinity affect the fractionation of 238U/235U during coprecipitation with calcite and aragonite. Recent work suggests that the U/Ca ratio of foraminiferal calcite may vary with seawater [CO32-] concentration due to changes in U speciation[1]. Here we explore analogous isotopic consequences in inorganic laboratory co-precipitation experiments. Uranium coprecipitation experiments with calcite and aragonite were performed at pH 8.5 ± 0.1 and 7.5 ± 0.1 using a constant addition method [2]. Dissolved U in the remaining solution was periodically collected throughout the experiments. Samples were purified with UTEVA resin and 238U/235U was determined using a 233U-236U double-spike and MC-ICP-MS, attaining a precision of ± 0.10 ‰ [3]. Small but resolvable U isotope fractionation was observed in aragonite experiments at pH ~8.5, preferentially enriching heavier U isotopes in the solid phase. 238U/235U of the dissolved U in these experiments can be fit by Rayleigh fractionation curves with fractionation factors of 1.00002 - 1.00009. In contrast, no resolvable U isotope fractionation was detected in an aragonite experiment at pH ~7.5 or in calcite experiments at either pH. Equilibrium isotope fractionation among dissolved U species is the most likely mechanism driving these isotope effects. Our quantitative model of this process assumes that charged U species are preferentially incorporated into CaCO3 relative to the neutral U species Ca2UO2(CO3)3(aq), which we hypothesize to have a lighter equilibrium U isotope composition than the charged U species. According to this model, the magnitude of U isotope fractionation should scale with the fraction of the neutral U species in the solution, in agreement with our experimental results. These findings suggest that U isotope variations in abiotic CaCO3 reflect changes in aqueous U(VI) speciation, which are in turn a function of carbonate ion chemistry and pH. Hence, the door is opened to the development of a possible 238U/235U proxy for the carbonate ion system. [1] DeCarlo et al., (2015), GCA, 162,151-165. [2] Reeder et a., (2001), GCA, 65, 3491-3503. [3] Weyer et al., (2008) GCA 72, 345-359.

Post-extension shortening strains preserved in calcites of the Keweenawan rift

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donnelly, K.; Craddock, J.; McGovern, M.

1993-02-01

The Keweenawan rift is part of failed triple junction system that underlies Lake Superior and the Michigan Basin. The rift experienced extensional stresses dating about 1.1 Ga, which were followed by compressional stresses from about 1,060 Ma to < 350 Ma. Associated with the rift are two thrust faults: the Douglas (dipping southeast) and the Keweenawan-Lake Owen (dipping northwest). To determine the direction of rifting, calcite twins were used to calculate strain ellipsoids (Groshong method) which are indicative of the intensity and direction of the stress applied to a rocks in a region at a given time. Rock samples whichmore » contain significant calcite within the zone of rifting were collected, slabbed, and made into thin sections. Calcite appears as amygdule, vein, and cement filings, as well as limestones. Analyses show that different calcite types show different stain orientations. Two principle directions of sub-horizontal shortening are present: one parallel to rift, and one normal to the rift, indicating that rifting motion varied out the time in which different calcite types were deposited. Shortening parallel to the rift is seen predominantly on the western margin while shortening normal to the rift is seen predominantly on the eastern margin.« less

Science and Art in the National Parks

ERIC Educational Resources Information Center

Clary, Renee

2016-01-01

This year marks the U.S. National Park Service's 100th anniversary. Although the nation's first national park--Yellowstone--dates to 1872, the government organization protecting and administering the national parks was founded just a hundred years ago, in 1916. Many U.S. national parks were established to preserve their unique geology or biology.…

Last interglacial sea levels and regional tectonics from fossil coral reefs at the Gulf of Aqaba

NASA Astrophysics Data System (ADS)

Bar, N.; Agnon, A.; Yehudai, M.; Lazar, B.; Shaked, Y.; Stein, M.

2017-12-01

Elevated fossil reef terraces along the northeast coast of the Gulf of Aqaba (GOA) illuminate the history of tectonic uplift and sea-level changes during the last interglacial period. The terraces comprise fringing reefs, some with clear reef structure that includes a reef flat and a shallow back lagoon accurately marking sea-levels. U-Th ages of precipitation of aragonitic corals and recrystallization of aragonite to calcite corals from three terraces are used to constrain the local sea-level pattern. Terrace R3 was probably formed during an earlier stage of MIS5e at 130-132 ka and recrystallized to calcite at 124±8 ka. Terrace R2, comprising a wide and developed reef flat, formed during a stable sea level of MIS5e at 129-121 ka and recrystallized to calcite at 104±6 ka. Terrace R1 formed during a short still-stand at 117 ka. All terraces formed when sea level was a few meters above the modern GOA level. The recrystallization age of Terrace R2 implies that at around 104±6 ka (MIS5c) sea level was close to its MIS5e elevation. The tectonic setting is superimposed by local faulting that caused small vertical displacements within the terraces. The elevation and ages of the reef flats indicate a slow average uplift, 0.12±0.05 m/kyr, similar to rates inferred for other reef terraces along GOA and the Red Sea. This implies an overall long-term slow tectonic uplift of the Arabian lithosphere during the late Quaternary.

U-series dating of Lake Nyos maar basalts, Cameroon (West Africa): Implications for potential hazards on the Lake Nyos dam

NASA Astrophysics Data System (ADS)

Aka, Festus T.; Yokoyama, Tetsuya; Kusakabe, Minoru; Nakamura, Eizo; Tanyileke, Gregory; Ateba, Bekoa; Ngako, Vincent; Nnange, Joseph; Hell, Joseph

2008-09-01

From previously published 14C and K-Ar data, the age of formation of Lake Nyos maar in Cameroon is still in dispute. Lake Nyos exploded in 1986, releasing CO 2 that killed 1750 people and over 3000 cattle. Here we report results of the first measurements of major elements, trace elements and U-series disequilibria in ten basanites/trachy-basalts and two olivine tholeiites from Lake Nyos. It is the first time tholeiites are described in Lake Nyos. But for the tholeiites which are in 238U- 230Th equilibrium, all the other samples possess 238U- 230Th disequilibrium with 15 to 28% enrichment of 230Th over 238U. The ( 226Ra/ 230Th) activity ratios of these samples indicate small (2 to 4%) but significant 226Ra excesses. U-Th systematics and evidence from oxygen isotopes of the basalts and Lake Nyos granitic quartz separates show that the U-series disequilibria in these samples are source-based and not due to crustal contamination or post-eruptive alteration. Enrichment of 230Th is strong prima facie evidence that Lake Nyos is younger than 350 ka. The 230Th- 226Ra age of Nyos samples calculated with the ( 226Ra/ 230Th) ratio for zero-age Mt. Cameroon samples is 3.7 ± 0.5 ka, although this is a lower limit as the actual age is estimated to be older than 5 ka, based on the measured mean 230Th/ 238U activity ratio. The general stability of the Lake Nyos pyroclastic dam is a cause for concern, but judging from its 230Th- 226Ra formation age, we do not think that in the absence of a big rock fall or landslide into the lake, a big earthquake or volcanic eruption close to the lake, collapse of the dam from erosion alone is as imminent and alarming as has been suggested.

Large Variations of Atmospheric 14C Associated With Dansgaard-Oeschger Cycles 10- 13

NASA Astrophysics Data System (ADS)

Weyhenmeyer, C. E.; Burns, S. J.; Fleitmann, D.; Mangini, A.; Matter, A.; Guilderson, T.; Reimer, P. J.

2006-12-01

A 1.7 m long stalagmite from Moomi Cave, Socotra Island in the Indian Ocean provides a continuous, high- resolution record of climate change between 53 and 41 kyr BP. In the northern high-latitude regions, this time period is characterized by several rapid climate change events, corresponding to Dansgaard-Oeschger (D/O) cycles 10-13. It has been suggested that these D/O cycles may be global events but high-resolution data from the low-latitude regions are scarce. As a result, the driving and feedback mechanisms of these rapid changes remain poorly understood. The presented stalagmite data of U/Th, stable isotopes (del 18O, del 13C) and radiocarbon (14C) provide unique information regarding the nature and timing of rapid climate changes in the tropics. A depth-age model for the Moomi Cave stalagmite was developed from 25 high-precision U/Th measurements, providing a solid chronology for this record. Oxygen isotope measurements of the stalagmite calcite reveal several large variations that are believed to reflect changes in the amount of precipitation, rather than temperature. A comparison to the Greenland Ice Core records shows a remarkable similarity to D/O cycles 10- 13 with warmer periods in the high-latitude regions being associated with increased precipitation in the tropics and vice versa. The stalagmite radiocarbon (14C) values from over 100 individual measurements reveal an almost identical cyclic pattern, tracing all four D/O cycles. Assuming no changes in the carbonate chemistry of the precipitating fluid, the radiocarbon values of the stalagmite calcite directly reflect changes in global atmospheric 14C concentrations. There are three possible explanations for these cyclic variations of 14C values: 1) changes in the carbonate chemistry of the drip water resulting in changes of the dead carbon fraction (DCF); 2) changes in the solar activity and/or Earth's magnetic field resulting in direct variations of atmospheric 14C concentrations; and 3) changes in the global ocean circulation resulting in varying amounts of 'dead' (14C-free) carbon being released into the atmosphere. We exclude the first scenario based on the fact that calcite del 13C values show very little variation throughout this record, thus excluding any significant changes in the carbonate chemistry and DCF. Based on model calculations and 10Be data from ice core records, we propose changes in the global ocean circulation as the primary mechanism for rapid changes in the atmospheric 14C reservoir.

Compositional and quantitative microtextural characterization of historic paintings by micro-X-ray diffraction and Raman microscopy.

PubMed

Romero-Pastor, Julia; Duran, Adrian; Rodríguez-Navarro, Alejandro Basilio; Van Grieken, René; Cardell, Carolina

2011-11-15

This work shows the benefits of characterizing historic paintings via compositional and microtextural data from micro-X-ray diffraction (μ-XRD) combined with molecular information acquired with Raman microscopy (RM) along depth profiles in paint stratigraphies. The novel approach was applied to identify inorganic and organic components from paintings placed at the 14th century Islamic University-Madrasah Yusufiyya-in Granada (Spain), the only Islamic University still standing from the time of Al-Andalus (Islamic Spain). The use of μ-XRD to obtain quantitative microtextural information of crystalline phases provided by two-dimensional diffraction patterns to recognize pigments nature and manufacture, and decay processes in complex paint cross sections, has not been reported yet. A simple Nasrid (14th century) palette made of gypsum, vermilion, and azurite mixed with glue was identified in polychromed stuccos. Here also a Christian intervention was found via the use of smalt, barite, hematite, Brunswick green and gold; oil was the binding media employed. On mural paintings and wood ceilings, more complex palettes dated to the 19th century were found, made of gypsum, anhydrite, barite, dolomite, calcite, lead white, hematite, minium, synthetic ultramarine blue, and black carbon. The identified binders were glue, egg yolk, and oil.

ESR dating of tooth enamel: comparison with {230Th }/{234U } speleothem dates at La Chaise-de-Vouthon (Charente), France

NASA Astrophysics Data System (ADS)

Blackwell, Bonnie; Porat, N.; Schwarcz, H. P.; Debénath, A.

One way to assess a new dating method's reliability is by comparing its results with those from well established, independent techniques. A controlled test of the electron spin resonance (ESR) dating method as it is currently being applied to teeth was attempted for the time range 100-250 ka, beyond that of 14C, at the archaeological site of La Chaise-de-Vouthon (Charente, France). Although absent in modern enamel, a single ESR signal with g = 2.0018 in fossil tooth enamel hydroxyapatite increases in amplitude with increasing irradiation doses. ESR ages are derived from the ratio of the AD, the radiation dose needed to produce the observed ESR signal, relative to the natural, environmental dose rate (ED) experienced by the tooth after deposition. Since the age depends on the uranium (U) uptake history assumed, three ages are calculated assuming: (1) early U uptake (EU); (2) continuous (linear) uptake (LU); (3) recent uptake (RU). Generally, the LU age agrees best with known ages determined by other methods, although the RU model is better for some teeth. ESR dating assumes that the fossil has not suffered recrystallization or significant diagenetic alteration. In the preliminary test, three teeth were dated. In Bourgeois-Delaunay, a bovid molar associated with Palaeolithic artefacts was collected from layers dated at 101 ± 12 to 114 ± 7 ka by {230Th }/{234U } dating of the over- and underlying stalagmitic floors. From Suard, two Equus teeth were collected from beneath a stalagmitic floor dating 112 ± 12 ka. ESR dating teeth significantly underestimated the true age for the teeth: the mean ESR ages range from 37 to 94 ka with standard errors of 2-6 ka, and good replicability. Although more teeth at La Chaise need to be tested to ascertain that the underestimation does not result from random variation commonly seen among teeth within one unit, the consistent underestimation suggests a fault in one of the assumptions underlying the dating method. The most obvious source of error lies in the difficulty in modelling the external γ dose. Only U leaching, not incorrectly modelled U uptake, would cause the underestimation. Diagenetic alteration may also cause anomalous fading, thermal instability, variation in k, or ESR signal suppression. More study into the effects of diagenesis alteration on enamel ESR signals is needed, as is a reevaluation of the mean signal life and α efficiency for several more enamel samples.

Provenance implications of Th U Pb electron microprobe ages from detrital monazite in the Carboniferous Upper Silesia Coal Basin, Poland

NASA Astrophysics Data System (ADS)

Kusiak, Monika Agnieszka; Kędzior, Artur; Paszkowski, Mariusz; Suzuki, Kazuhiro; González-Álvarez, Ignacio; Wajsprych, Bolesław; Doktor, Marek

2006-05-01

This paper reports the results of CHIME (chemical Th-U-Pb isochron method) dating of detrital monazites from Carboniferous sandstones in the Upper Silesia Coal Basin (USCB). A total of 4739 spots on 863 monazite grains were analyzed from samples of sandstone derived from six stratigraphic units in the sedimentary sequence. Age distributions were identified in detrital monazites from the USCB sequence and correlated with specific dated domains in potential source areas. Most monazites in all samples yielded ca. 300-320 Ma (Variscan) ages; however, eo-Variscan, Caledonian and Cadomian ages were also obtained. The predominant ages are comparable to reported ages of certain tectonostratigraphic domains in the polyorogenic Bohemian Massif (BM), which suggests that various crystalline lithologies in the BM were the dominant sources of USCB sediments.

Developing 226Ra and 227Ac age-dating techniques for nuclear forensics to gain insight from concordant and non-concordant radiochronometers

DOE PAGES

Kayzar, Theresa M.; Williams, Ross W.

2015-09-26

The model age or ‘date of purification’ of a nuclear material is an important nuclear forensic signature. In this study, chemical separation and MC-ICP-MS measurement techniques were developed for 226 Ra and 227Ac: grand-daughter nuclides in the 238U and 235U decay chains respectively. The 230Th- 234U, 226Ra- 238U, 231Pa- 235U, and 227Ac- 235U radiochronometers were used to calculate model ages for CRM-U100 standard reference material and two highly-enriched pieces of uranium metal from the International Technical Working Group Round Robin 3 Exercise. In conclusion, the results demonstrate the accuracy of the 226Ra- 238U and 227Ac- 235U chronometers and provide informationmore » about nuclide migration during uranium processing.« less

Developing 226Ra and 227Ac age-dating techniques for nuclear forensics to gain insight from concordant and non-concordant radiochronometers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kayzar, Theresa M.; Williams, Ross W.

The model age or ‘date of purification’ of a nuclear material is an important nuclear forensic signature. In this study, chemical separation and MC-ICP-MS measurement techniques were developed for 226 Ra and 227Ac: grand-daughter nuclides in the 238U and 235U decay chains respectively. The 230Th- 234U, 226Ra- 238U, 231Pa- 235U, and 227Ac- 235U radiochronometers were used to calculate model ages for CRM-U100 standard reference material and two highly-enriched pieces of uranium metal from the International Technical Working Group Round Robin 3 Exercise. In conclusion, the results demonstrate the accuracy of the 226Ra- 238U and 227Ac- 235U chronometers and provide informationmore » about nuclide migration during uranium processing.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eppich, Gary R.; Williams, Ross W.; Gaffney, Amy M.

Here, age dating of nuclear material can provide insight into source and suspected use in nuclear forensic investigations. We report here a method for the determination of the date of most recent chemical purification for uranium materials using the 235U- 231Pa chronometer. Protactinium is separated from uranium and neptunium matrices using anion exchange resin, followed by sorption of Pa to an SiO 2 medium. The concentration of 231Pa is measured by isotope dilution mass spectrometry using 233Pa spikes prepared from an aliquot of 237Np and calibrated in-house using the rock standard Table Mountain Latite and the uranium isotopic standard U100.more » Combined uncertainties of age dates using this method are 1.5 to 3.5 %, an improvement over alpha spectrometry measurement methods. Model ages of five uranium standard reference materials are presented; all standards have concordant 235U- 231Pa and 234U- 230Th model ages.« less

Community-based Approaches to Improving Accuracy, Precision, and Reproducibility in U-Pb and U-Th Geochronology

NASA Astrophysics Data System (ADS)

McLean, N. M.; Condon, D. J.; Bowring, S. A.; Schoene, B.; Dutton, A.; Rubin, K. H.

2015-12-01

The last two decades have seen a grassroots effort by the international geochronology community to "calibrate Earth history through teamwork and cooperation," both as part of the EARTHTIME initiative and though several daughter projects with similar goals. Its mission originally challenged laboratories "to produce temporal constraints with uncertainties approaching 0.1% of the radioisotopic ages," but EARTHTIME has since exceeded its charge in many ways. Both the U-Pb and Ar-Ar chronometers first considered for high-precision timescale calibration now regularly produce dates at the sub-per mil level thanks to instrumentation, laboratory, and software advances. At the same time new isotope systems, including U-Th dating of carbonates, have developed comparable precision. But the larger, inter-related scientific challenges envisioned at EARTHTIME's inception remain - for instance, precisely calibrating the global geologic timescale, estimating rates of change around major climatic perturbations, and understanding evolutionary rates through time - and increasingly require that data from multiple geochronometers be combined. To solve these problems, the next two decades of uranium-daughter geochronology will require further advances in accuracy, precision, and reproducibility. The U-Th system has much in common with U-Pb, in that both parent and daughter isotopes are solids that can easily be weighed and dissolved in acid, and have well-characterized reference materials certified for isotopic composition and/or purity. For U-Pb, improving lab-to-lab reproducibility has entailed dissolving precisely weighed U and Pb metals of known purity and isotopic composition together to make gravimetric solutions, then using these to calibrate widely distributed tracers composed of artificial U and Pb isotopes. To mimic laboratory measurements, naturally occurring U and Pb isotopes were also mixed in proportions to mimic samples of three different ages, to be run as internal standards and as measures of inter-laboratory reproducibility. The U-Th community is undertaking many of the same protocols, and has recently created publicly available gravimetric solutions, and large volumes of three age solutions for widespread distribution and inter-laboratory comparison.

Comparative analysis of dose rates in bricks determined by neutron activation analysis, alpha counting and X-ray fluorescence analysis for the thermoluminescence fine grain dating method

NASA Astrophysics Data System (ADS)

Bártová, H.; Kučera, J.; Musílek, L.; Trojek, T.

2014-11-01

In order to evaluate the age from the equivalent dose and to obtain an optimized and efficient procedure for thermoluminescence (TL) dating, it is necessary to obtain the values of both the internal and the external dose rates from dated samples and from their environment. The measurements described and compared in this paper refer to bricks from historic buildings and a fine-grain dating method. The external doses are therefore negligible, if the samples are taken from a sufficient depth in the wall. However, both the alpha dose rate and the beta and gamma dose rates must be taken into account in the internal dose. The internal dose rate to fine-grain samples is caused by the concentrations of natural radionuclides 238U, 235U, 232Th and members of their decay chains, and by 40K concentrations. Various methods can be used for determining trace concentrations of these natural radionuclides and their contributions to the dose rate. The dose rate fraction from 238U and 232Th can be calculated, e.g., from the alpha count rate, or from the concentrations of 238U and 232Th, measured by neutron activation analysis (NAA). The dose rate fraction from 40K can be calculated from the concentration of potassium measured, e.g., by X-ray fluorescence analysis (XRF) or by NAA. Alpha counting and XRF are relatively simple and are accessible for an ordinary laboratory. NAA can be considered as a more accurate method, but it is more demanding regarding time and costs, since it needs a nuclear reactor as a neutron source. A comparison of these methods allows us to decide whether the time- and cost-saving simpler techniques introduce uncertainty that is still acceptable.

Radioactive dating of the elements

NASA Technical Reports Server (NTRS)

Cowan, John J.; Thielemann, Friedrich-Karl; Truran, James W.

1991-01-01

The extent to which an accurate determination of the age of the Galaxy, and thus a lower bound on the age of the universe, can be obtained from radioactive dating is discussed. Emphasis is given to the use of the long-lived radioactive nuclei Re-187, Th-232, U-238, and U-235. The nature of the production sites of these and other potential Galactic chronometers is examined along with their production ratios. Age determinations from models of nucleocosmochronology are reviewed and compared with age determination from stellar sources and age constraints form cosmological considerations.

Hunting for eruption ages in accessory minerals

NASA Astrophysics Data System (ADS)

Vazquez, J. A.

2012-12-01

A primary goal in geochronology is to provide precise and accurate ages for tephras that serve as chronostratigraphic markers for constraining the timing and rates of volcanism, sedimentation, climate change, and catastrophic events in Earth history. Zircon remains the most versatile accessory mineral for dating silicic tephras due to its common preservation in distal pyroclastic deposits, as well as the robustness of its U-Pb and U-series systems even after host materials have been hydrothermally altered or weathered. Countless studies document that zircon may be complexly zoned in age due to inheritance, contamination, recycling of antecrysts, protracted crystallization in long-lived magma reservoirs, or any combination of these. Other accessory minerals such as allanite or chevkinite can retain similar records of protracted crystallization. If the goal is to date the durations of magmatic crystallization, differentiation, and/or magma residence, then these protracted chronologies within and between accessory minerals are a blessing. However, if the goal is to date the timing of eruption with high precision, i.e., absolute ages with millennial-scale uncertainties, then this age zoning is a curse. Observations from ion microprobe 238U-230Th dating of Pleistocene zircon and allanite provide insight into the record of near-eruption crystallization in accessory minerals and serve as a guide for high-precision whole-crystal dating. Although imprecise relative to conventional techniques, ion probe analysis allows high-spatial resolution 238U-230Th dating that can document multi-millennial age distributions at the crystal scale. Analysis of unpolished rims and continuous depth profiling of zircon from small and large volume eruptions (e.g., Coso, Mono Craters, Yellowstone) reveals that the final several micrometers of crystallization often yield ages that are indistinguishable from associated eruption ages from the 40Ar/39Ar or (U-Th)/He methods. Using this approach, we have derived relatively precise (± ~ 5%, 2σ) U-Th isochron ages from the unpolished rims of pumice-derived allanite and zircon from late Pleistocene Wilson Creek Formation tephras in eastern California, whose ages are controversial and have been difficult to resolve via 40Ar/39Ar and radiocarbon dating. Allanite and zircon rims from Ashes 7-19 in the lower portion of Wilson Creek sediments yield stratigraphically consistent ages of ca. 27 ka to ca. 62 ka, with a minority of crystals identifiable as xenocrysts from early Mono Craters rhyolites. Model ages for the interiors of allanite crystals are mostly < 10 k.y. older than their rims. Tephra deposited during the geomagnetic excursion debated to be either the Mono Lake or Laschamp event yields a rim isochron age of ca. 41 ka. This age is indistinguishable from an independent age of 41 ka derived at the latter excursion's type locality in France (Singer et al., 2009) as well as from age-models for deep-sea sediments. The results are in excellent agreement with a previously determined chronology derived from magnetostratigraphy (Zimmerman et al., 2006). Refs: Singer et al., 2009, EPSL 286: 80-88; Zimmerman et al., 2006, EPSL 252: 94-106

Sedimentology, petrography and early diagenesis of a travertine-colluvium succession from Chusang (southern Tibet)

NASA Astrophysics Data System (ADS)

Wang, Zhijun; Meyer, Michael C.; Hoffmann, Dirk L.

2016-08-01

The Chusang travertine is situated in southern Tibet at an altitude of ~ 4200 m asl. in a cold-arid, periglacial environment and is characterized by interbedding of hydrothermal carbonate with colluvium. Here we present sedimentological and petrographical data to elucidate the depositional environment and sedimentary processes responsible for hydrothermal carbonate precipitation and early diagenetic alteration as well as clastic sediment accumulation and provide initial 230Th/U ages to constrain the time-depth of this travertine-colluvium succession. Three main travertine lithofacies have been identified: 1) a dense laminated lithofacies, 2) a porous layered lithofacies and 3) an intraclastic lithofacies that results from erosion of pre-existing hot spring carbonate. The colluvium is composed of cohesive debris flow layers that derived from mass-wasting events from the adjacent hillslopes. Micro-fabric analyses suggest that dense laminated travertine forms via rapid calcite precipitation from hot spring water seasonally subjected to severe winter cooling, while porous layered travertine results from seasonal dilution of hot spring water with rain water during the summer monsoon months, which in turn stimulates biological productivity and gives rise to a porous summer layer. Early diagenesis in the form of recrystallization and extensive formation of pore cements is common in the Chusang travertine, but never eradicates the original crystal fabrics completely. The sedimentary architecture of the deposit is conditioned by (i) the gently dipping (~ 10°) pre-existing terrain on which hot spring water is discharged from multiple travertine mounds causing laterally extensive travertine sheets to precipitate, and (ii) the adjacent much steeper (up to 30°) periglacial hillslopes that are the source area of repeated debris flows that accumulate on the travertine surface. The resulting travertine-colluvium succession has a total thickness of ~ 24 m and 230Th/U dating suggests that the base of this succession has a minimum age of ~ 486 ka, while the upper part (top-most ~ 8 m) of the succession started accumulating in the earliest Holocene. We hypothesize that hot spring activity (and thus travertine precipitation) and the occurrence of debris flow events has a climatic nexus, i.e. are both triggered by phases of enhanced Indian summer monsoon.

Diagenesis of fossil coral skeletons: Correlation between trace elements, textures, and [sup 234]U/[sup 238]U

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bar-Matthews, M.; Wasserburg, G.J.; Chen, J.H.

1993-01-01

A comparative study of Pleistocene fossil coral skeletons and of modern coral skeletons was carried out using petrographic and trace element analyses on a suite of Pleistocene samples that had previously been studied from [sup 234]U, [sup 230]Th, and U-[sup 230]Th ages (Chen et al. 1991). Evidence of a range of diagenetic changes can be recognized by optical (OM) and scanning electron microscopy (SEM). Using an electron microprobe and SEM, concentrations of Na, S, Sr, and Mg were measured. No other trace elements were detected. Na, S, and Mg contents of the matrix, the fibrous micropores, and radiating needles aremore » highly variable and well correlated. High concentrations of Na, S, and Mg were found in modern living corals with lower concentrations in fossil corals and fibrous micropores, and the lowest value in the radiating needles. The reason for the correlations of Na, S, and Mg and crystal chemistry and the response to diagenesis of these trace elements is not understood. The average concentrations of Na, S, and Mg for each sample, when plotted against the whole coral initial [delta][sup 234]U, are generally correlated (Chen et al., 1991). As all these diagenetic changes involve the recystallization and deposition of aragonite, the authors infer that the geologic site of diagenesis both for forming the secondary aragonitic phases and for the enhancement of the [sup 234]U content in the fossil corals was the marine environment. It is possible that the textural and Na, S, and Mg trace element contents of fossil corals be used to ascertain the reliability of fossil coral skeletons for U-[sup 230]Th dating. The basic problem of identifying a priori unaltered coral skeletons for [sup 230]Th dating is not yet resolved. 64 refs., 16 figs., 5 tabs.« less

Low-temperature thermochronology of the Laramide Ranges and eastward translation of shortening in the Sevier Belt, Wyoming, Utah and Montana

NASA Astrophysics Data System (ADS)

Peyton, Sara Lynn

This dissertation contains two studies that use very different techniques to investigate the Mesozoic and Cenozoic tectonics of the western USA. The first study investigates shortening in the Sevier thrust belt of northeast Utah and southwest Wyoming using cross sections and seismic reflection data. The second study investigates the low-temperature thermochronology of the Laramide Ranges using apatite (U-Th)/He dating. We used cross sections and seismic reflection data to investigate bed length discrepancies within the hanging wall of the Absaroka thrust in the Sevier thrust belt of northeast Utah and southwest Wyoming. Restoration of cross sections suggests that there was ˜8-14 km of pre-Absaroka-thrust shortening above the Jurassic Preuss salt detachment, but not below it, in the hanging wall of the Absaroka thrust. Reflection seismic data over the hanging wall of the Crawford thrust show that the Crawford thrust is not offset along the Preuss salt detachment, indicating that the additional shortening on the Absaroka plate was transferred east before main movement on the Crawford thrust. Although early displacement on the Crawford thrust cannot be ruled out as the cause of the extra shortening, surface and subsurface geology suggests slip from the western thrust system (Willard and Lost Creek thrusts) was transferred several tens of kilometers east along the Jurassic Preuss salt detachment between ˜102-90 Ma, to the future location of the Absaroka thrust hanging wall. The lack of deformation of the Crawford thrust on the seismic data, along with shortening and extension estimates from cross sections, also indicate that the magnitude of Paleocene and post-early Eocene shortening on the Medicine Butte thrust was essentially offset by subsequent extension on the middle Eocene to late Oligocene Almy-Acocks normal-fault system. For the second study in this dissertation, we dated 91 borehole and surface samples from Laramide-age, basement-cored uplifts of the Rocky Mountain foreland (Wind River, Beartooth, Bighorn and Laramie Ranges) and the Uncompahgre Uplift using the apatite (U-Th)/He system. Apatite (U-Th)/He ages generally decrease with increasing subsurface depth (decreasing elevation) and most samples show age dispersion ranging from tens to hundreds of Myr. Additionally, several samples show correlations between apatite (U-Th)/He age and effective U concentration (eU = [U] + 0.235[Th]) of the crystal, indicating that radiation damage has affected He diffusivity, and hence (U-Th)/ He age. Many surface and near-surface samples have apatite (U-Th)/He ages that are older than corresponding apatite fission-track ages. Forward modeling of Laramide-type thermal histories using a radiation damage diffusion model showed that (U-Th)/He ages may be widely dispersed, and may be older than corresponding apatite fission-track ages within a fossil He partial retention zone. Most of our samples, however, do not show the correlation between (U-Th)/He age and eU predicted by radiation damage diffusion models. We investigated the influence of both grain size and eU content and show that the effects of grain size can obscure (U-Th)/ He age-eU correlations and, similarly, the effect of eU variation can obscure (U-Th)/ He age-grain size correlations. (U-Th)/He ages that are older than fission-track ages from high peaks in the Wind River Range, and from some samples from the Beartooth Range, are most likely the result of He implantation from high eU phases. Best-fit thermal histories from the inversion of age-eU pairs were extrapolated to other elevations to create model age-elevation profiles for a range of eU concentrations. These model profiles approximate our real data. Inverse modeling of (U-Th)/He age data suggests that rapid exhumation within the Laramide province likely began earlier in the Bighorn Mountains (before ˜71 Ma) than the Beartooth Range (before ˜58 Ma), and that the borehole at the northern end of the Laramie Range penetrated a fault sliver at depth.

7. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED 1918, HORIZONAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. PHOTOGRAPHIC COPY OF ORIGINAL CONSTRUCTION DRAWING, DATED 1918, HORIZONAL SLIDING WINDOW DETAIL, WAR DEPARTMENT, MANUAL OF THE CONSTRUCTION DIVISION OF THE ARMY, WAR EMERGENCY CONSTRUCTION, SECTION C, ENGINEERING DIVISION, PLATE 5, CONSOLIDATED SUPPLY COMPANY PRINTERS, WASHINGTON - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

10. PHOTOGRAPHIC COPY OF ORIGINAL PHOTOGRAPH, DATED APRIL 29, 1926, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. PHOTOGRAPHIC COPY OF ORIGINAL PHOTOGRAPH, DATED APRIL 29, 1926, DOUBLE BARRACK, BUILDING 452, (ORIGINAL No. 655), SOUTH FRONT AND RIGHT SIDE, NATIONAL ARCHIVES PHOTOGRAPH, RECORD GROUP 92, GEOGRAPHIC FILE, 1922-1935, No. 600-1, FORT BLISS - Fort Bliss, 7th Cavalry Buildings, U.S. Army Air Defence Artillery Center & Fort Bliss, El Paso, El Paso County, TX

Southern Ocean Circulation: a High Resolution Examination of the Last Deglaciation from Deep-Sea Corals

NASA Astrophysics Data System (ADS)

Robinson, L. F.; Li, T.; Chen, T.; Burke, A.; Pegrum Haram, A.; Stewart, J.; Rae, J. W. B.; van de Flierdt, T.; Struve, T.; Wilson, D. J.

2017-12-01

Two decades ago it was first noted that the skeletal remains of deep-sea corals had the potential to provide absolutely dated archives of past ocean conditions. In the intervening twenty years this field has developed to the point where strategic collections and high throughput dating techniques now allow high resolution, well dated records of past deep sea behaviour to be produced. Likewise, efforts to improve understanding of biomineralisation and growth rates are leading to refinements in proxy tools useful for examining circulation, nutrient and carbon cycling, temperature and weathering processes. Deep-sea corals are particularly valuable archives in high latitude regions where radiocarbon-based age models are susceptible to large changes in surface reservoir ages. In this presentation we show new high resolution multiproxy records of the Southern Ocean (Drake Passage) made on U-Th dated corals spanning the last glacial cycle. With more than seventeen hundred reconnaissance ages, and around 200 precise isotope dilution U-Th ages, subtle changes in ocean behaviour can be identified during times of abrupt climate change. The geochemical signature of corals from the deepest sites, closest to modern day Lower Circumpolar Deep Waters, typically show a gradual shift from glacial to Holocene values during deglaciation, likely related to ventilation of the deep ocean. By contrast for the samples collected shallower in the water column (within sites currently bathed by Upper Circumpolar Deep Waters and Antarctic Intermediate and Mode Waters) the evidence points to a more complicated picture. Vertical zonation in the geochemical data suggests that periods of stratification are interspersed with mixing events within the upper 1500m of the water column. At the same time comparison to U-Th dated records from the low latitude Pacific and Atlantic points to an important role for the Southern Ocean in feeding the intermediate waters of both ocean basins throughout the deglaciation.

Mapping South American Summer Monsoon Changes during Heinrich Event 1 and the LGM: Insights from New Paleolake Records from the Central Andes

NASA Astrophysics Data System (ADS)

Chen, C. Y.; McGee, D.; Quade, J.

2015-12-01

Cave stalagmite records show strong evidence of abrupt changes in summer monsoons during Heinrich events, but we lack rigorous constraints on the amount of wetting or drying occurring in monsoon regions. Studies on shoreline deposits of closed-basin lakes can establish quantitative bounds on water balance changes through mapping-based estimates of lake volume variations. We present new dating constraints on lake level variations in Agua Caliente I and Laguna Loyoques, two closed-basin, high-altitude paleolakes on the Altiplano-Puna plateau of the Central Andes (23.1°S, 67.4°W, 4250 masl). Because this area receives >70% of its total annual precipitation during austral summer, the region is ideally suited to capture a pure response to changes in the South American summer monsoon (SASM). The plateau is home to several small (<40 km2) lakes surrounded by well-preserved paleoshorelines that indicate past wetter conditions. Agua Caliente I is unique, having multiple shorelines encrusted with biologically-mediated calcium carbonate "tufa" deposits. Initial U-Th dating of these massive shoreline tufas reveals that these deposits are dateable to within ±50 to 300 years due to high U concentrations and low initial Th content (as indicated by high 230Th/232Th). Our U-Th dates show that Agua Caliente I was greater in lake surface area during two periods: 17.5-14.5 kyrs BP, coincident with Heinrich Event 1 (HE1), and 24-23 kyrs BP, roughly coincident with the Last Glacial Maximum (LGM). At these times, Agua Caliente I also overflowed into a neighboring lake basin (Loyoques) through an 8-km long southeast-trending stream channel. Thus, during HE1 and the LGM, the lake was ~9 times larger in surface area relative to modern. Hydrologic modeling constrained by paleotemperature estimates is used to provide bounds for these past precipitation changes. We also tentatively explore physical mechanisms linking Heinrich events and the regional hydroclimate by comparing freshwater hosing experiments and transient climate simulations. Our results in Agua Caliente I and Laguna Loyoques act as a proof of concept, and lend us confidence in expanding our U-Th work to other shoreline tufas in the surrounding region to produce a more detailed, spatiotemporal record of water balance changes in South America.

Teens and dating: study of factors that influence attitudes of violence.

PubMed

Ferreira, Manuela; Lopes, Ana; Aparício, Graça; Cabral, Lidia; Duarte, João

2014-11-01

Dating violence is a relevant social problem in adolescent and young adult romantic relationships. Particular attention has begun to be paid to it by the scientific community in the last two decades. It may involve a sexual, physical and psychological dimension, requiring different prevention and intervention strategies. To analyse the effect of socio-demographic and contextual variables on attitudes to dating violence. This is a quantitative, non-experimental, cross-sectional descriptive and correlational study. Questionnaires to characterise socio-demographics and dating context and the Scale of Attitudes about Dating Violence (SADV), were applied to 243 adolescents attending the 10th, 11th and 12th years of schooling in a Portuguese secondary school. The adolescents are over 17 years in age (40.7%), with a predominance of girls (56.0%). They reside mainly in rural areas with most attending the 10th year. More than half live with their parents (91.7%). The vast majority are Catholic. Nearly all of the participants are dating or have dated. We found statistically significant differences in all types of violence with regards to gender, the religion they practice and adolescents who have had sexual relations. The type of violence exerted was mainly psychological. The results point to the need to integrate the topic of dating violence in adolescent education using active methods with the effective participation of everyone involved in the process (adolescents, parents, teachers and health professionals). Only in this way will it be possible to develop healthy emotional relationship skills. Copyright © 2014 Elsevier España, S.L.U. All rights reserved.

Precise Th/U-dating of small and heavily coated samples of deep sea corals

NASA Astrophysics Data System (ADS)

Lomitschka, Michael; Mangini, Augusto

1999-07-01

Marine carbonate skeletons like deep-sea corals are frequently coated with iron and manganese oxides/hydroxides which adsorb additional thorium and uranium out of the sea water. A new cleaning procedure has been developed to reduce this contamination. In this further cleaning step a solution of Na 2EDTA (Na 2H 2T B) and ascorbic acid is used which composition is optimised especially for samples of 20 mg of weight. It was first tested on aliquots of a reef-building coral which had been artificially contaminated with powdered ferromanganese nodule. Applied on heavily contaminated deep-sea corals (scleractinia), it reduced excess 230Th by another order of magnitude in addition to usual cleaning procedures. The measurement of at least three fractions of different contamination, together with an additional standard correction for contaminated carbonates results in Th/U-ages corrected for the authigenic component. A good agreement between Th/U- and 14C-ages can be achieved even for extremely coated corals.

Zircon ages in granulite facies rocks: decoupling from geochemistry above 850 °C?

NASA Astrophysics Data System (ADS)

Kunz, Barbara E.; Regis, Daniele; Engi, Martin

2018-03-01

Granulite facies rocks frequently show a large spread in their zircon ages, the interpretation of which raises questions: Has the isotopic system been disturbed? By what process(es) and conditions did the alteration occur? Can the dates be regarded as real ages, reflecting several growth episodes? Furthermore, under some circumstances of (ultra-)high-temperature metamorphism, decoupling of zircon U-Pb dates from their trace element geochemistry has been reported. Understanding these processes is crucial to help interpret such dates in the context of the P-T history. Our study presents evidence for decoupling in zircon from the highest grade metapelites (> 850 °C) taken along a continuous high-temperature metamorphic field gradient in the Ivrea Zone (NW Italy). These rocks represent a well-characterised segment of Permian lower continental crust with a protracted high-temperature history. Cathodoluminescence images reveal that zircons in the mid-amphibolite facies preserve mainly detrital cores with narrow overgrowths. In the upper amphibolite and granulite facies, preserved detrital cores decrease and metamorphic zircon increases in quantity. Across all samples we document a sequence of four rim generations based on textures. U-Pb dates, Th/U ratios and Ti-in-zircon concentrations show an essentially continuous evolution with increasing metamorphic grade, except in the samples from the granulite facies, which display significant scatter in age and chemistry. We associate the observed decoupling of zircon systematics in high-grade non-metamict zircon with disturbance processes related to differences in behaviour of non-formula elements (i.e. Pb, Th, U, Ti) at high-temperature conditions, notably differences in compatibility within the crystal structure.

Reference Materials for Trace Element Microanalysis of Carbonates by SIMS and other Mass Spectrometric Techniques

NASA Astrophysics Data System (ADS)

Layne, G. D.

2009-12-01

Today, many areas of geochemical research utilize microanalytical determinations of trace elements in carbonate minerals. In particular, there has been an explosion in the application of Secondary Ion Mass Spectrometry (SIMS) to studies of marine biomineralization. SIMS provides highly precise determinations of Mg and Sr at the concentration levels normally encountered in corals, mollusks or fish otoliths. It is also a highly effective means for determining a wide range of other trace elements at ppm levels (e.g., Na, Fe, Mn, Ba, REE, Pb, Th, and U) in a variety of naturally occurring calcite and aragonite matrices - and so is potentially valuable in studies of diagenesis, hydrothermal fluids and carbonatitic magmas. For SIMS, modest time per spot (often <5 min), lateral spatial resolution (<10 μm), sample volume consumption (<10 ng) and overall reproducibility compare extremely favorably with other microanalytical techniques for these applications. However, accuracy and reproducibility are currently wholly limited by the homogeneity of available solid reference material - which is far inferior to the tenths of a percent levels of precision achieved by SIMS. Due to variation in the sputtered ion yields of most elements with the major element composition of the sample matrix, accuracy of SIMS depends intimately on matrix-matched solid reference materials. Despite its rapidly increasing use for trace element analyses of carbonates, there remains a dearth of certified reference materials suitable for calibrating SIMS. The pressed powders used by some analysts to calibrate LA-ICP-MS do not perform well for SIMS - they are not perfectly dense or homogeneous to the desired level at the micron scale of sampling. Further, they often prove incompatible with the sample high vacuum compatibility requirement for stable SIMS analysis (10-8 to 10-9 torr). Some naturally occurring calcite has apparent utility as a reference material. For example, equigranular calcite from some zones of carbonatite intrusions (sovites) and recrystallized calcites from highly metamorphosed metallic ore deposits. Most calcite marbles, though possibly appropriate as Sr standards, show substantial inhomogeneity in Mg, Mn and Ba. Some hydrothermal “Iceland Spar” calcite may prove useful as a reference for extremely low concentrations of Mg, Sr and Ba. The best carbonatitic calcites currently in use appear homogeneous to better than 2-3% for Sr (and somewhat less homogeneous for Mg). But these standards still require numerous replicate analyses during analytical sessions to reduce the overall uncertainty to <<1.0%.The availability of appropriate certified solid reference materials with a high degree of homogeneity would greatly benefit the utilization and inter-comparison of SIMS determinations in carbonates, while substantially reducing the time consumed in calibration. Some studies would also benefit from the extension of this effort to the characterization of appropriate standards of other rhombohedral carbonates (especially dolomite and Fe-rich calcite).

Operation JOSS, Offensive, Deliberate Assault, Amphibious, 10-16 July 1943

DTIC Science & Technology

1984-05-01

German) S-4 •-i-Ile 16 July 1943 ’.-- Prepared by: Staff Group B/Section 3 Staff Group Leader: MAJ (P) Richard M. Colbert , MP MAJ Joseph W. BowabU TC MAJ...US Amy , 49th Siotal Intelliprr Str-ite, .btv’qj.L& Histz, o . iit 49th Signal loeiliunce §Irvice , dated 27 JWy j045. - Page 61 - I.III compromising

78 FR 21607 - Stakeholder Listening Session in Preparation for the 66th World Health Assembly

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-11

... World Health Assembly Time and date: May 6, 2013, 3 p.m.-4:30 p.m. EST. Place: Great Hall of the Hubert... Human Services (HHS)--charged with leading the U.S. delegation to the 66th World Health Assembly-- will... Listening Session will help the HHS's Office of Global Affairs prepare for the World Health Assembly by...

77 FR 19666 - Stakeholder Listening Session in Preparation for the 65th World Health Assembly

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-02

... World Health Assembly Time and Date: April 30, 2012, 3 p.m.-4:30 p.m. EST. Place: Great Hall of the... with leading the U.S. delegation to the 65th World Health Assembly-- will hold an informal Stakeholder... HHS's Office of Global Affairs prepare for the World Health Assembly by taking full advantage of the...

Implications of Smectite Subduction at the Costa Rican Convergent Margin

NASA Astrophysics Data System (ADS)

Cardace, D.; Morris, J. D.; Underwood, M. B.; Spinelli, G.

2003-12-01

Legs 205/170 of the Ocean Drilling Program (ODP) drilled a reference section on the incoming plate and sites at the toe of the sedimentary prism at the Costa Rican convergent margin. Complete sediment subduction has been documented, with the prism described by Leg 205/170 shipboard scientists as a paleoslump prism. Despite sediment subduction, Costa Rican arc lava geochemistry shows little sediment signal. Though subduction erosion has been posited as a mechanism for damping the geochemical sediment signal, this abstract addresses whether the clay content and distribution in the subducting pile can (a) play a role in localizing the decollement and (b) impact subduction of sediment to depth. X-ray diffraction (XRD) analyses of bulk sediment, with biogenic silica determinations, have been carried out for samples from the prism, through the decollement, to the underthrust sediments. Clay fractions have been isolated and silica studied for a subset of these samples. XRD peak areas of bulk samples were transformed into relative abundances via matrix singular value decomposition (Fisher and Underwood, 1995, Proc. ODP, Init. Repts., 156: 29-37), and adjusted following silica determination; volcanic ash has been neglected as a sedimentary component. Average relative weight percents of dominant minerals and biogenic silica (bSiO2) for prism toe units (Site 1040) are: P1A (silty clay, 74.8 m thick) 82 wt% clay, 5 wt% quartz, 13 wt% plagioclase, 0 wt% calcite; P1B (silty clay, 296.4 m thick) 82.1 wt% clay, 6.0 wt% quartz, 10.4 wt% plagioclase, 0 wt% calcite, 1.4 wt% bSiO2. Below the decollement, underthrust abundances are: U1A (clayey diatomite, 13.2 m thick) 82.7 wt% clay, 5.2 wt% quartz, 8.9 wt% plagioclase, 0 wt% calcite, 3.2 wt% bSiO2; U1B (clayey diatomite, 38.2 m thick) 80.7 wt% clay, 4.4 wt% quartz, 6.6 wt% plagioclase, 0 wt% calcite, 8.2 wt% bSiO2; U2 (silty claystone, 57.1 m thick) 84.8 wt% clay, 4.5 wt% quartz, 6.8 wt% plagioclase, 0 wt% calcite, 3.9 wt% bSiO2; U3A (siliceous nannofossil chalk, 18.1 m thick) 44.1 wt% clay, 2.0 wt% quartz, 5.6 wt% plagioclase, 31.8 wt% calcite, 16.5 wt% bSiO2; U3B (siliceous nannofossil chalk, 75.55 m thick) 1.9 wt% clay, 0 wt% quartz, 1.1 wt% plagioclase, 92.4 wt% calcite, 4.7 wt% bSiO2; and U3C (siliceous nannofossil chalk, 80.18 m thick) 6.6 wt% clay, 6.1 wt% quartz, 4.6 wt% plagioclase, 74.1 wt% calcite, 8.7 wt% bSiO2. XRD peak areas for clay fractions of prism samples above and in the decollement (Site 1254 ˜Site 1040, 300-370 mbsf) were transformed into relative weight percent data with Biscaye weighting factors. Smectites ranged from 77-93 wt%, illites ranged from 0-4 wt%, and kaolinites/chlorites ranged from 5-20 wt%. The maximum smectite value was obtained in the lower decollement. Bulk mineralogy data for sediments subducting at Costa Rica show that the prism and uppermost underthrust sediments are 80-93 wt% clay sized minerals. Clay mineralogy suggests that the smectite maximum occurs in the lower decollement and decreases dramatically below. Low biogenic silica abundances persist down core, emphasizing the importance of clays to the subducting section at Costa Rica.

Inter-annual precipitation variabiity inferred from late Holocene speleothem records from Fiji: implications for SPCZ localisation and ENSO behaviour

NASA Astrophysics Data System (ADS)

Mattey, D.; Stephens, M.; Hoffmann, D.; Brett, M.

2015-12-01

The modern tropical Fiji climate is characterised by seasonal rainfall controlled by the position of the South Pacific Convergence Zone (SPCZ). Interannual rainfall is strongly modulated on decadal timescales by ENSO with higher rainfall associated with La Nina events. Voli Voli cave near Sigatoga (Viti Levu) is a stream passage that has been monitored since 2009. A U-Th dated laminated speleothem spans a 1500 year interval across the transition from the Medieval Warm Period into the Little Ice Age marked by a fabric change from finely laminated calcite with thin clay layers, to white well-laminated calcite. The older record is characterised by rising δ13C values followed by a rapid decrease in δ13C around 1200 AD. Evidence from cave monitoring shows that cave air CO2 levels are strongly seasonal as a result of greater ventilation by winter trade winds and high resolution δ13C record shows regularly spaced peaks correlated with paired laminae and cycles in P and S which provide annual markers driven by rainfall and seasonal ventilation. δ18O values remain relatively unchanged throughout the record but micromilling at sub-annual resolution reveals systematic cycles in δ18O that span groups of paired laminae with an inferred periodicity of 3-7 years i.e. a similar frequency to modern ENSO. The presence of these sub-decadal cycles in δ18O may be a result of a combination of factors. The amplitude of 2-3‰ would be equivalent to an amount-effect related change in annual precipitation of around 50% but an additional smoothing process, perhaps a result of aquifer storage, is required to attenuate interannual variance in precipitation. The Voli Voli record provides evidence of an underlying climatic change to more frequent La Niña conditions from 1200 AD and may be associated with increased conflict, shifts in settlements and changes in subsistence strategies on the island. Coeval speleothem isotope records from tropical Pacific Islands provide a provide a powerful means of locating the mean position and intensity of the SPCZ and changes in regional coupling of ocean-atmospheric circulation patterns.

Penultimate Glacial-Interglacial Climate Variability in the Southern Great Plains of North America

NASA Astrophysics Data System (ADS)

Bartow-Gillies, E.; Maupin, C. R.; Roark, E. B.; Chou, Y. C.; White, K.; Kampen-Lewis, S. V.; Shen, C. C.

2017-12-01

Projections of changes in rainfall under future warming scenarios vary in their sign and intensity over the Southern Great Plains (SGP). A scarcity of local paleoclimate information before the Last Glacial Maximum (LGM) limits our understanding of regional climate responses to changes in mean state and forcing. Here, we present absolutely U/Th-dated oxygen and carbon isotope records from a calcite stalagmite near Georgetown, Texas (30°N, 98°W), spanning 98 to 209 kyr before present (kyr BP). SGP moisture is primarily sourced from the Gulf of Mexico, and precipitation exhibits clear seasonality, with a biannual rainy season divided into late boreal spring and fall. We interpret the oxygen isotopic composition of the stalagmite to reflect changes in rainwater δ18O composition, as well as cave temperature, through time. There are no clear kinetic isotope effects observed within the stalagmite. More negative (positive) δ18O values are a reflection of warmer and wetter (cooler and drier) conditions based on modern observations of rainwater δ18O at the study site. Variations in stalagmite δ13C may be driven by shifts in overlying vegetation type and changes in the rates of karst flow and prior calcite precipitation. The stalagmite records include Marine Isotope Stage (MIS) 5e, an interval where global temperatures may have been as much as 2°C warmer and sea level 4-6 m higher than present. Thus, our δ18O record provides context of unique importance for how SGP hydroclimate may respond to future warming. Prominent features in the δ18O record, including a warm and wet MIS 5e appear to be paced by precession, with the timing of δ18O minima (maxima) broadly consistent with that of maxima (minima) in monthly insolation at 30°N. The δ13C record exhibits a striking similarity to canonical, sawtooth records of glacial-interglacial variability, which suggests Great Plains vegetation communities may be sensitive to the status of Northern Hemisphere glaciation. Our SGP stalagmite records help to reveal the fundamental character of SGP climate response to glacial-interglacial forcings and provide evidence for increased precipitation under past warming conditions.

The Asian Monsoon Moisture Transportation Revealed by Two Cave Sites in Myanmar

NASA Astrophysics Data System (ADS)

Liu, G.; Wang, X.; Chiang, H. W.; Maung Maung, P.; Jiang, X.; Aung, L. T.; Tun, S. T.

2014-12-01

Here we present two well-resolved, calcite δ18O records on Myanmar speleothems. The samples were collected from a coastal site in southeastern Myanmar and a plateau site in central Myanmar, respectively. Chronologically determined by high-precision U/Th dating techniques, both records span a large portion of the past 40,000 years. The two records show similar millennial-scale oscillations during the last glacial period, which are also in-phase with the speleothem records from Chinese cave sites located in the downstream of Indian Monsoon trajectories. The δ18O values between the two profiles are virtually the same, ~ -7.5‰, during late Holocene, in concert with the numbers in modern rainfall at the two sites. However, in glacial time, the δ18O value of the central Myanmar record shifts from -6.5‰ to -8‰, approximately 2‰ lower than that in the coastal dataset, which varies from -4.5‰ to -6‰. We interpret the similarly low δ18O values during Holocene in both records as a result of strong monsoonal rainfall and water recycling particularly through forest transpiration. However in glacial time, with a possibly drier and less forested land, water recycling is weaker. Therefore, rainfall δ18O and subsequently speleothem δ18O appear a stronger geographical gradient, possibly dominated by the continental rainout effect. Our interpretation can be supported by the speleothem δ13C records from the two sites. Calcite δ13C from the coastal site varies slightly from ~-7‰ in the last glacial to ~-9‰ in Holocene. Whereas it shares a similar value to the coastal record during Holocene, the δ13C profile from the plateau site shows a much higher value, up to -0.7‰, during the glacial time. This suggests that the mountainous region in central Myanmar was likely dominated by C4 plants (e.g., grass) during the glacial time, while the same region is covered by forests today. Such change on vegetation type and coverage may influence the δ18O of recycling moisture transported further inland.

Biocalcification using B. pasteurii for strengthening brick masonry civil engineering structures.

PubMed

Raut, Supriya H; Sarode, D D; Lele, S S

2014-01-01

Microbiologically induced calcite precipitation in bricks by bacterium Bacillus pasteurii (NCIM 2477) using a media especially optimized for urease production (OptU) was demonstrated in this study. Effect of biocalcification activity on compressive strength and water absorption capacity of bricks was investigated. Various other parameters such as pH, growth profile, urease activity, urea breakdown and calcite precipitated were monitored during the 28 days curing period. Efficiency of B. pasteurii to form microbial aided calcite precipitate in OptU media resulted into 83.9% increase in strength of the bricks as compared to only 24.9% with standard media, nutrient broth (NB). In addition to significant increase in the compressive strength, bricks treated with B. pasteurii grown in OptU media resulted in 48.9 % reduction in water absorption capacity as compared to control bricks immersed in tap water. Thus it was successfully demonstrated that microbial calcification in optimized media by Bacillus pasteurii has good potential for commercial application to improve the life span of structures constructed with bricks, particularly structures of heritage importance.

Wisconsin Glaciation of the Sierra Nevada (79,000-15,000 yr B.P.) as Recorded by Rock Flour in Sediments of Owens Lake, California

NASA Astrophysics Data System (ADS)

Bischoff, James L.; Cummins, Kathleen

2001-01-01

Chemical analyses of the clay-sized fractions of 564 continuous sediment samples (200-yr resolution) from composite core OL90/92 allow quantification of an abundance of glacial rock flour. Rock flour produced during glacier advances is represented by clay-sized plagioclase, K-feldspar, and biotite in homogeneous internal composition. The abundance of rock flour is deemed proportional to the intensity of glacies advances. Age control for the composite section is provided by combining previously published radiocarbon dates on organics, U/Th dates on ostracode shells, and U/Th dates on saline minerals from nearby Searles Lake correlated to OL92 by pollen. The rock flour record displays three levels of variability: (1) a dominant one of about 20,000 yr related to summer insolation and precipitation; (2) an intermediate one of 3000-5000 yr, perhaps related to North Atlantic Heinrich events; and (3) a minor one of 1000-2000 yr, perhaps related to North Atlantic thermohaline-driven air-temperature variation.

Wisconsin Glaciation of the Sierra Nevada (79,000-15,000 yr B.P.) as recorded by rock flour in sediments of Owens Lake, California

USGS Publications Warehouse

Bischoff, J.L.; Cummins, K.

2001-01-01

Chemical analyses of the clay-sized fractions of 564 continuous sediment samples (200-yr resolution) from composite core OL90/92 allow quantification of an abundance of glacial rock flour. Rock flour produced during glacier advances is represented by clay-sized plagioclase, K-feldspar, and biotite in homogeneous internal composition. The abundance of rock flour is deemed proportional to the intensity of glacies advances. Age control for the composite section is provided by combining previously published radiocarbon dates on organics, U/Th dates on ostracode shells, and U/Th dates on saline minerals from nearby Searles Lake correlated to OL92 by pollen. The rock flour record displays three levels of variability: (1) a dominant one of about 20,000 yr related to summer insolation and precipitation; (2) an intermediate one of 3000-5000 yr, perhaps related to North Atlantic Heinrich events; and (3) a minor one of 1000-2000 yr, perhaps related to North Atlantic thermohaline-driven air-temperature variation. ?? 2001 University of Washington.

Determination of U, Th and K in bricks by gamma-ray spectrometry, X-ray fluorescence analysis and neutron activation analysis

NASA Astrophysics Data System (ADS)

Bártová, H.; Kučera, J.; Musílek, L.; Trojek, T.; Gregorová, E.

2017-11-01

Knowledge of the content of natural radionuclides in bricks can be important in some cases in dosimetry and application of ionizing radiation. Dosimetry of naturally occurring radionuclides in matter (NORM) in general is one of them, the other one, related to radiation protection, is radon exposure evaluation, and finally, it is needed for the thermoluminescence (TL) dating method. The internal dose rate inside bricks is caused mostly by contributions of the natural radionuclides 238U, 232Th, radionuclides of their decay chains, and 40K. The decay chain of 235U is usually much less important. The concentrations of 238U, 232Th and 40K were measured by various methods, namely by gamma-ray spectrometry, X-ray fluorescence analysis (XRF), and neutron activation analysis (NAA) which was used as a reference method. These methods were compared from the point of view of accuracy, limit of detection (LOD), amount of sample needed and sample handling, time demands, and instrument availability.

National geochronological and natural radioelement data bases

USGS Publications Warehouse

Zartman, Robert E.; Bush, Charles A.; Abston, C.C.

1995-01-01

This CD-ROM contains both the National Geochronological Data Base [NGDB] and the Natural Radioelement Data Base [NRDB]. Supporting location, geologic, and reference information is provided for both data bases. The NGDB is a compilation of more than 30,000 individual published Pb-alpha, fission-track, K-Ar, Rb-Sr, U-Th-Pb, and Sm-Nd rock and mineral ages reported on approximately 18,000 dated samples from the United States. A program is provided to search the data files by latitude and longitude, state, analytical method, and age range. The NGDB is provided as quote-comma delimited files that can be entered into most commercial spreadsheet programs. The NRDB gives gamma-ray spectrometric analyses of the natural radioelements (U, Th, and K) for more than 8500 whole-rock samples obtained under the USGS Natural Radioelement Distribution Project. A program is provided to search the data files by state, keyword, U content, Th content, and K content.

Ar-40/Ar-39 and U-Th-Pb dating of separated clasts from the Abee E4 chondrite

NASA Technical Reports Server (NTRS)

Bogard, D. D.; Unruh, D. M.; Tatsumoto, M.

1983-01-01

Ar-40/Ar-39 and U-Th-Pb are investigated for three clasts from the Abee (E4) enstatite chondrite, yielding Ar-40/Ar-39 plateau ages (and/or maximum ages) of 4.5 Gy, while two of the clasts give average ages of 4.4 Gy. The 4.4-4.5 Gy range does not resolve possible age differences among the clasts. The U-Th-Pb data are consistent with the interpretation that initial clast formation occurred 4.58 Gy ago, and that the clasts have since remained closed systems which have been contaminated with terrestrial Pb. The thermal history of Abee deduced from Ar data seems consistent with that deduced from magnetic data, suggesting that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, experiencing no significant subsequent heating.

U-Pb-Th geochronology of monazite and zircon in albitite metasomatites of the Rožňava-Nadabula ore field (Western Carpathians, Slovakia): implications for the origin of hydrothermal polymetallic siderite veins

NASA Astrophysics Data System (ADS)

Hurai, V.; Paquette, J.-L.; Lexa, O.; Konečný, P.; Dianiška, I.

2015-10-01

Sodic metasomatites (albitites) occur around and within siderite veins in the southern part of the Gemeric tectonic unit of the Western Carpathians. Accessory minerals of the metasomatites represented by monazite, zircon, apatite, rutile, tourmaline and siderite are basically identical with the quartz-tourmaline stage of other siderite and stibnite veins of the tectonic unit. Statistical analysis of chemical Th-U(total)-Pb isochron method (CHIME) of monazite dating yielded Jurassic-Cretaceous ages subdivided into 3-4 modes, spreading over time interval between 78 and 185 Ma. In contrast, LA-ICPMS 206Pb/238U dating carried out on the same monazite grains revealed a narrow crystallization interval, showing ages of Th-poor cores with phengite inclusions identical within the error limit with Th-rich rims with cauliflower-like structure. The determined lower intercept at 139 ± 1 Ma overlapped the Vallanginian-Berriasian boundary, thus corroborating the model of formation of hydrothermal vein structures within an arcuate deformation front built up in the Variscan basement as a response to Early Cretaceous compression, folding and thrusting. In contrast, associated zircons are considerably older than the surrounding Early-Palaeozoic volcano-sedimentary rocks, showing Neoproterozoic ages. The zircon grains in albitite metasomatites are thus interpreted as fragments of Pan-African magmatic detritus incorporated in the vein structures by buoyant hydrothermal fluids.

187Re - 187Os nuclear geochronometry: age dating with permil precision

NASA Astrophysics Data System (ADS)

Roller, Goetz

2016-04-01

Recently, 187Re - 187Os nuclear geochronometry, a new dating method combining ideas of nuclear astrophysics with geochronology, has successfully been used to calculate two-point-isochron (TPI) ages for Devonian black gas shales using the isotopic signature of an r-process geochronometer as one data point in a TPI diagram [1]. Based upon a nuclear production ratio 187Re/188Os = 5.873, TPI ages were calculated for 12 SDO-1 (Devonian Ohio Shale, Appalachian Basin) aliquants, for which repeated Re-Os measurements are reported in the literature [2]. TPI ages range from 384.5 ± 2.7 Ma (187Os/188Osi = 0.29413 ± 0.00023) to 387.7 ± 2.1 Ma (187Os/188Osi = 0.29407 ± 0.00019) with a mean of 386.67 ± 1.79 Ma). The result is consistent with the isochronous age from the 12 aliquants alone (386 ± 16 Ma, 187Os/188Osi = 0.31±0.31), which is bracketed by U-Pb ages for the Belpre Ash (381.1 ± 3.3 Ma) and the Tioga Ash bed (390.0 ± 2.5 Ma) [3] from the Appalachian Basin. Hence, SDO-1 can be assigned to the Givetian stage (varcus-zone) of the Middle Devonian, close to the Eifelian/Givetian boundary (using the time-scale of [3] or [4]). If an age is calculated from an isochron diagram for the 12 aliquants including the nuclear geochronometer, a permil precision can be achieved, an interesting feature with respect to any effort towards calibrating the Geologic Timescale. Additionally, a Th/U evolution (or: Th/U-time) diagram can be plotted using U-Pb zircon age data and Th/U ratios from volcanic rocks and ashes reported in the literature [3] for specific Devonian samples from the Appalachian Basin. Since the Re-Os age obtained for SDO-1 can also be connected to its Th/U ratio, it turns out, that Th/U ratios might be helpful age indicators, as demonstrated for the Devonian using the U-Pb and Re-Os datasets. [1] Roller (2015), GSA Abstr. with Programs 47, #248-14. [2] Du Vivier et al. (2014), Earth Planet. Sci. Lett. 389, 23 - 33. [3] Tucker et al. (1998), Earth Planet. Sci. Lett. 158, 175 - 186. [4] Kaufmann (2006), Earth-Sci. Revs. 76, 175 - 190.

U-series Chronology of volcanoes in the Central Kenya Peralkaline Province, East African Rift

NASA Astrophysics Data System (ADS)

Negron, L. M.; Ma, L.; Deino, A.; Anthony, E. Y.

2012-12-01

We are studying the East African Rift System (EARS) in the Central Kenya Peralkaline Province (CKPP), and specifically the young volcanoes Mt. Suswa, Longonot, and Menengai. Ar dates by Al Deino on K-feldspar phenocrysts show a strong correlation between older Ar ages and decreasing 230Th/232Th, which we interpret to reflect the age of eruption. This system has been the subject of recent research done by several UTEP alumni including Antony Wamalwa using potential field and magnetotelluric (MT) data to identify and characterize fractures and hydrothermal fluids. Also research on geochemical modeling done by John White, Vanessa Espejel and Peter Omenda led to the hypothesis of possible disequilibrium in these young, mainly obsidian samples in their post eruptive history. A pilot study of 8 samples, (also including W-2a USGS standard and a blank) establish the correlation that was seen between the ages found by Deino along with the 230/232Th ratios. All 8 samples from Mt. Suswa showed a 234U/238U ratio of (1) which indicates secular equilibrium or unity and that these are very fresh samples with no post-eruptive decay or leaching of U isotopes. The pilot set was comprised of four samples from the ring-trench group (RTG) with ages ranging from 7ka-present, two samples from the post-caldera stage ranging from 31-10ka, one sample from the syn-caldera stage dated at 41ka, and one sample from the pre-caldera stage dated at 112ka. The young RTG had a 230/232Th fractionation ratio of 0.8 ranging to the older pre-caldera stage with a 230/232Th ratio of 0.6. From this current data and research of 14C ages by Nick Rogers, the data from Longonot volcano was also similar to the 230/232Th ratio we found. Rogers' data places Longonot volcano ages to be no more than 20ka with the youngest samples also roughly around 0.8 disequilibrium. These strong correlations between the pilot study done for Mt. Suswa, 40Ar ages by Deino, along with 14C ages from Rogers have led to the exploration of present U-series data set of the youngest samples from the rest of the CKPP volcanoes including: Menengai, more from Longonot, and Olkaria. And since it is observed that there is the presence of lateral migration along an axial dike swarm that has operated in other parts of the EARS, we have chosen to run samples from the adjacent mafic fields of Elmenteita, Tandamara, and Ndabibi to see if there is a trend in the correlation of the 230/232Th ratios at the time of eruption as well as observing how close these samples get to unity. This would answer questions as to whether similar 230/232Th ratios imply that the mafic fields feed the calderas.

High-resolution tephrochronology of the Wilson Creek Formation (Mono Lake, California) and Laschamp event using 238U-230Th SIMS dating of accessory mineral rims

NASA Astrophysics Data System (ADS)

Vazquez, Jorge A.; Lidzbarski, Marsha I.

2012-12-01

Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and tephras yield discordant results due to open-system effects and radiocarbon reservoir uncertainties as well as abundant xenocrysts. New ion microprobe 238U-230Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yield ages that effectively date eruption of key tephra beds and delimit the timing of basal Wilson Creek sedimentation to the interval between 26.8±2.1 and 61.7±1.9 ka. Tephra (Ash 15) erupted during the geomagnetic excursion originally designated the Mono Lake excursion yields an age of 40.8±1.9 ka, indicating that the event is instead the Laschamp excursion. The new ages support a depositional chronology from magnetostratigraphy that indicates quasi-synchronous glacial and hydrologic responses in the Sierra Nevada and Mono Basin to regional climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation.

High-resolution tephrochronology of the Wilson Creek Formation (Mono Lake, California) and Laschamp event using 238U-230Th SIMS dating of accessory mineral rims

USGS Publications Warehouse

Vazquez, Jorge A.; Lidzbarski, Marsha I.

2012-01-01

Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and tephras yield discordant results due to open-system effects and radiocarbon reservoir uncertainties as well as abundant xenocrysts. New ion microprobe 238U-230Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yield ages that effectively date eruption of key tephra beds and delimit the timing of basal Wilson Creek sedimentation to the interval between 26.8±2.1 and 61.7±1.9 ka. Tephra (Ash 15) erupted during the geomagnetic excursion originally designated the Mono Lake excursion yields an age of 40.8±1.9 ka, indicating that the event is instead the Laschamp excursion. The new ages support a depositional chronology from magnetostratigraphy that indicates quasi-synchronous glacial and hydrologic responses in the Sierra Nevada and Mono Basin to regional climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation.

Standard Materials for Microbeam Analysis of Lanthanides and Actinides

NASA Astrophysics Data System (ADS)

Ellis, I.; Gorton, M.; Rucklidge, J. C.

2010-12-01

Traces of Th and U in naturally-occuring minerals monazite, xenotime and zircon are used for dating host rocks. Natural variations of actinide concentrations in some rock formations are well documented. Microbeam techniques perform dating in-situ where grains of indicator minerals are left intact in thin sections. Separated individual grains of these minerals are also routinely dated by Pb-isotope mass spectrometry. Ideal calibration materials will be compatible with multiple techniques. Quantitative analysis of low levels of lanthanides (REE), U, Th and Pb found in natural minerals requires standards containing similar concentrations of these elements. The ideal low-level standard suite will have materials with each REE cation present below 5%, similar to natural rare-earth phosphate minerals. In contrast, REE orthophosphates LnPO4 have cation concentrations from 59 to 64%, and ultraphosphates LnP5O14 from 27% to 32%. The concentrations of U and Pb must also be in the 1% range in the host REE phosphate. There are two competing limits to the synthesis of crystals with multiple cations in the REE sites. The crystal structure limits potential cation mixtures to selections within groups (La,Ce, Pr, Nd, Sm, Eu), (Gd, Tb, Dy, Ho), and (Er, Tm,Yb, Lu, Y). Complex L X-ray spectra limit the use of contiguous REE in a single material. There are two general synthetic routes for the preparation of lanthanide/actinide standard materials for beam analysis and dating. Lanthanide orthophosphates (LnPO4) are crystallized from lead-free heterogeneous fluxes; oligomers (metaphosphates LnP3O9 and ultraphosphates LnP5O14) are formed by condensation of phosphoric acid in the presence of cations. All of these trivalent lanthanide phosphate crystal structures are hosts for Th+4 and U+4, and in synthetic materals, Ca+2 is used for charge compensation. Our work focuses on the preparation of mixed-cation lanthanide metaphosphates and ultraphosphates. The solvent (essentially P2O5) provides redox conditions that favour Ce+3, Th+4, and U+4 instead of higher oxidation states. The absence of any cations other than those deliberately added permits positive control of cation mixtures in starting materials. The synthetic pathway—condensation of POx units--provides ideal conditions for the homogeneous distribution of cations including those with different charges. We present the results of synthesis, elemental analysis and imaging by XRF and SEM-EDX for mixed lanthanide-actinide phosphate materials.

Timing of fluid seepage on summits of Quaker and Conical serpentine mud volcanoes, Mariana forearc: Evidence from U/Th dating of carbonate chimneys

NASA Astrophysics Data System (ADS)

Tong, Hongpeng; Fryer, Patricia; Feng, Dong; Chen, Duofu

2017-04-01

Serpetinization of forearc mantle along deep faults in the Mariana convergent plate margin permits formation of large active serpentinite mud volcanoes on the overiding plate within 90 km of the trench. Fluid seepage on summits of the mud volcanoes lead to the formation of authigenic carbonate chimneys close to the seafloor. Such carbonate chimneys are unique archives of past fluid seepage and assciated envrionemtnal parameters. Here, we report U/Th dating and stable carbon and oxygen isotopes of the chimneys from Quaker and Conical serpentine mud volcanoes. The resulting U/Th ages of samples from Quaker Seamount show three time intervals of 11,081 to10,542 yBP, 5,857 to 5,583 yBP, and 781 to 164 yBP, respectively. By comparison, carbonates from Conical Seamount have U/Th ages between 3,070 yBP and 1,623 yBP. Our results suggest that fluid seepage on the summits of serpentine mud volcanoes are episodic and probably locally controlled. Samples from Quaker seamount show depletion of 13C (δ13C=-7.0-0.4‰ V-PDB), indicating contribution of carbon from anoxic oxidation of abiogenic methane. By contrast, samples from Conical seamount have positive δ18O values (0.6-6.3), suggesting enrichment of 18O in the seepage fluid. The data obtained provide time integrated variation of seepage fluids and seepage dynamics that are archived in authigenic carbonates. This finding adds to the ongoing multidisciplinary effort to better constrain the environment in the Mariana forearc region and to determine the locally dominant biogeochemical processes. Acknowlegment: This study was funded by the CAS (Grant No. XDB06030102).

Dating of barite and anhydrite in sea-floor hydrothermal deposits in the Okinawa Trough

NASA Astrophysics Data System (ADS)

Taisei, F.; Toyoda, S.; Uchida, A.; Ishibashi, J. I.; Totsuka, S.; Shimada, K.; Nakai, S.

2016-12-01

Dating of submarine hydrothermal activities has been an important issue in the aspect of the ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). For this purpose, dating methods using radioactive disequilibrium such as U-Th method (e.g. You and Bickle, 1998) for sulfide, 226Ra-210Pb and 228Ra-228Th (e.g. Noguchi et al., 2011), Ra/Ba, and ESR (Electron Spin Resonance) methods for barite (Okumura et al., 2010) have been employed. In this study, firstly, we will report the first successful dating results on anhydrite using 226Ra-210Pb and 228Ra-228Th methods. The anhydrite samples were taken from the Daiyon-Yonaguni knoll field and the Hatoma knoll field and the Iheya North Knoll field of the Okinawa Trough by research cruises operated by JAMSTEC. The anhydrite crystals were physically scratched out of the samples. 226Ra, 228Ra and daughter nuclei were measured in the same samples for the ESR method by the low background gamma ray spectrometry. From the activity ratios, disequilibrium ages were obtained to be about 7.3 years by 226Ra-210Pb method, and to be 0.6-2.5 years by 228Ra-228Th method. Secondly, the ESR ages of barite taken from hydrothermal areas in the Okinawa trough range from 4.1 to 16000 years, filling the age gap of the maximum age, 150 years, of 226Ra-210Pb method and the minimum age, several thousand years of U-Th method, being the most appropriate age range to discuss the evolution of the hydrothermal systems. Interestingly, the 226Ra-210Pb and 228Ra-228Th ages for the same samples are the same or younger than the ESR ages. As for the latter samples, the reason has already been discussed (Uchida et al., 2015) as the deposits had been formed by two or more hydrothermal events. In the present paper, the disequilibrium and ESR ages will be simulated with these multiple hydrothermal events so that the differences in the ages are explained.

(De)coupled zircon metamictization, radiation damage, and He diffusivity

NASA Astrophysics Data System (ADS)

Ault, A. K.; Guenthner, W.; Reiners, P. W.; Moser, A. C.; Miller, G. H.; Refsnider, K. A.

2017-12-01

We develop and apply a new protocol for targeting crystals for the zircon (U-Th)/He (He) thermochronometry to maximize effective U (eU) and corresponding closure temperature variability to develop zircon He date-eU correlations observed in some datasets. Our approach exploits visual proxies for radiation damage accumulation (metamictization) during zircon selection. We show that by purposefully targeting a spectrum of zircon textures from pristine to metamict grains, it is possible to generate broad eU variation in suites of zircon from a single sample and zircon He date-eU-metamictization trends that can be exploited to resolve increasingly complex thermal histories. We present plane light photographs, eU concentration, and zircon He results from 59 individual zircons from nine crystalline rock samples. Six of the nine samples come from exposed Proterozoic granitoids on SE Baffin Island, Canada; Boulder Creek, CO; Sandia Mountains, NM; and Mecca Hills, CA. We report data from three Archean Baffin samples to compare with the Proterozoic Baffin sample date-eU-metamictization trend. In each Proterozoic sample, target zircons display a spectrum of metamictization from pristine, transparent crystals to purple-brown, translucent grains. Progressive loss of transparency and increase in discoloration consistently corresponds to an increase in eU in all samples. Individual zircon eU varies from 89-1885 ppm and, within each sample, the total eU spread is 538 ppm to 1374 ppm. For any given eU value, the Archean zircon appear comparatively more metamict than the Proterozoic Baffin grains and samples collectively define a 1681 ppm range in eU, with more restrictive intrasample eU spreads (199-1120 ppm). Proterozoic samples from Baffin, Sandia, and Front Range yield negative zircon He date-eU correlations with intrasample date ranges of 90-783 Ma. Increasing eU and younger dates correspond with increasing metamictization. In contrast, all three Proterozoic Mecca Hills samples yield uniform 25 Ma zircon He dates over 1800 ppm eU. We apply simple thermal history models that account for the coevolution of zircon radiation damage and He-diffusivity to demonstrate that visible zircon metamictization and He diffusivity can be either coupled or decoupled depending on a sample's thermal history.

The earliest settlers of Mesoamerica date back to the late Pleistocene.

PubMed

Stinnesbeck, Wolfgang; Becker, Julia; Hering, Fabio; Frey, Eberhard; González, Arturo González; Fohlmeister, Jens; Stinnesbeck, Sarah; Frank, Norbert; Terrazas Mata, Alejandro; Benavente, Martha Elena; Avilés Olguín, Jerónimo; Aceves Núñez, Eugenio; Zell, Patrick; Deininger, Michael

2017-01-01

Preceramic human skeletal remains preserved in submerged caves near Tulum in the Mexican state of Quintana Roo, Mexico, reveal conflicting results regarding 14C dating. Here we use U-series techniques for dating a stalagmite overgrowing the pelvis of a human skeleton discovered in the submerged Chan Hol cave. The oldest closed system U/Th age comes from around 21 mm above the pelvis defining the terminus ante quem for the pelvis to 11311±370 y BP. However, the skeleton might be considerable older, probably as old as 13 ky BP as indicated by the speleothem stable isotope data. The Chan Hol individual confirms a late Pleistocene settling of Mesoamerica and represents one of the oldest human osteological remains in America.

The earliest settlers of Mesoamerica date back to the late Pleistocene

PubMed Central

Becker, Julia; Hering, Fabio; Frey, Eberhard; González, Arturo González; Fohlmeister, Jens; Stinnesbeck, Sarah; Frank, Norbert; Terrazas Mata, Alejandro; Benavente, Martha Elena; Avilés Olguín, Jerónimo; Aceves Núñez, Eugenio; Zell, Patrick; Deininger, Michael

2017-01-01

Preceramic human skeletal remains preserved in submerged caves near Tulum in the Mexican state of Quintana Roo, Mexico, reveal conflicting results regarding 14C dating. Here we use U-series techniques for dating a stalagmite overgrowing the pelvis of a human skeleton discovered in the submerged Chan Hol cave. The oldest closed system U/Th age comes from around 21 mm above the pelvis defining the terminus ante quem for the pelvis to 11311±370 y BP. However, the skeleton might be considerable older, probably as old as 13 ky BP as indicated by the speleothem stable isotope data. The Chan Hol individual confirms a late Pleistocene settling of Mesoamerica and represents one of the oldest human osteological remains in America. PMID:28854194

A Biosignature Suite from Cave Pool Precipitates, Cottonwood Cave, New Mexico

NASA Astrophysics Data System (ADS)

Melim, L. A.; Liescheidt, R.; Northup, D. E.; Spilde, M. N.; Boston, P. J.; Queen, J. M.

2009-11-01

Calcite cave pool precipitates often display a variety of potential biosignatures from the macroscopic to the submicroscopic. A fossil cave pool in Cottonwood Cave, New Mexico, exhibits older stalactites and stalagmites that are completely coated in brown, laminated calcitic crust that extends down as pool fingers and u-loops. The pool fingers and u-loops are mainly micrite to clotted micrite, some recrystallized to microspar, with some isopachous spar layers. Micrite, particularly clotted micrite, is usually interpreted by carbonate workers as microbial in origin. Scanning electron microscopy examination of etched pool fingers, u-loops, and the brown crust revealed abundant calcified microbial filaments and biofilm. Energy dispersive X-ray analysis showed that these features have excess carbon, above that found in pure calcite. Independent carbon analysis indicated that these same samples contain up to 0.2% organic carbon. Since pool fingers hang down but form underwater, we hypothesize they are biogenic with hanging microbial filaments or biofilm acting as nuclei for calcite precipitation. Because of the abundance of micrite and fossil filaments, we further hypothesize that these pendant features formed during a period of plentiful nutrients and active hydrological activity when the pool was literally dripping with microbial slime. Although each of these lines of evidence could be interpreted in other ways, their combined weight strongly suggests the cave pool precipitates in Cottonwood Cave are biogenic. These investigations can be used to help inform extraterrestrial life-detection studies.

A biosignature suite from cave pool precipitates, Cottonwood Cave, New Mexico.

PubMed

Melim, L A; Liescheidt, R; Northup, D E; Spilde, M N; Boston, P J; Queen, J M

2009-11-01

Calcite cave pool precipitates often display a variety of potential biosignatures from the macroscopic to the submicroscopic. A fossil cave pool in Cottonwood Cave, New Mexico, exhibits older stalactites and stalagmites that are completely coated in brown, laminated calcitic crust that extends down as pool fingers and u-loops. The pool fingers and u-loops are mainly micrite to clotted micrite, some recrystallized to microspar, with some isopachous spar layers. Micrite, particularly clotted micrite, is usually interpreted by carbonate workers as microbial in origin. Scanning electron microscopy examination of etched pool fingers, u-loops, and the brown crust revealed abundant calcified microbial filaments and biofilm. Energy dispersive X-ray analysis showed that these features have excess carbon, above that found in pure calcite. Independent carbon analysis indicated that these same samples contain up to 0.2% organic carbon. Since pool fingers hang down but form underwater, we hypothesize they are biogenic with hanging microbial filaments or biofilm acting as nuclei for calcite precipitation. Because of the abundance of micrite and fossil filaments, we further hypothesize that these pendant features formed during a period of plentiful nutrients and active hydrological activity when the pool was literally dripping with microbial slime. Although each of these lines of evidence could be interpreted in other ways, their combined weight strongly suggests the cave pool precipitates in Cottonwood Cave are biogenic. These investigations can be used to help inform extraterrestrial life-detection studies.

Incorporation of Metals into Calcite in a Deep Anoxic Granite Aquifer.

PubMed

Drake, Henrik; Mathurin, Frédéric A; Zack, Thomas; Schäfer, Thorsten; Roberts, Nick Mw; Whitehouse, Martin; Karlsson, Andreas; Broman, Curt; Åström, Mats E

2018-01-16

Understanding metal scavenging by calcite in deep aquifers in granite is of importance for deciphering and modeling hydrochemical fluctuations and water-rock interaction in the upper crust and for retention mechanisms associated with underground repositories for toxic wastes. Metal scavenging into calcite has generally been established in the laboratory or in natural environments that cannot be unreservedly applied to conditions in deep crystalline rocks, an environment of broad interest for nuclear waste repositories. Here, we report a microanalytical study of calcite precipitated over a period of 17 years from anoxic, low-temperature (14 °C), neutral (pH: 7.4-7.7), and brackish (Cl: 1700-7100 mg/L) groundwater flowing in fractures at >400 m depth in granite rock. This enabled assessment of the trace metal uptake by calcite under these deep-seated conditions. Aquatic speciation modeling was carried out to assess influence of metal complexation on the partitioning into calcite. The resulting environment-specific partition coefficients were for several divalent ions in line with values obtained in controlled laboratory experiments, whereas for several other ions they differed substantially. High absolute uptake of rare earth elements and U(IV) suggests that coprecipitation into calcite can be an important sink for these metals and analogousactinides in the vicinity of geological repositories.

ENVIRONMENTALMANAGEMENT SCIENCE PROGRAM PROJECT NUMBER 87016 CO-PRECIPITATION OF TRACEMETALS INGROUNDWATER AND VADOSE ZONE CALCITE: IN SITU CONTAINMENT AND STABILIZATION OF STRONTIUM-90 ANDOTHER DIVALENT METALS AND RADIONUCLIDES AT ARIDWESTERN DOE SITES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferris, F. Grant; Fujita, Yoshiko; Smith, Robert W.

2004-06-15

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. In situ containment and stabilization of these contaminants in vadose zones or groundwater is a cost-effective treatment strategy. Our facilitated approach relies upon the hydrolysis of introduced urea to cause the acceleration of calcium carbonate precipitation (and trace metal coprecipitation) by increasing groundwater pH and alkalinity (Fujita et al., 2000; Warren et al., 2001). Subsurface urea hydrolysis is catalyzed by the urease enzyme, which may be either introduced with the urea or produced in situ by ubiquitous subsurface ureamore » hydrolyzing microorganisms. Because the precipitation processes are irreversible and many western aquifers are saturated with respect to calcite, the co-precipitated metals and radionuclides will be effectively removed from groundwater. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution (Zachara et al., 1991), solid solution properties of the trace metal in calcite (Tesoriero and Pankow, 1996), and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning, and how this occurs in aquifers and vadose environments is lacking. This report summarizes work undertaken during the second year of this project.« less

CONCH: A Visual Basic program for interactive processing of ion-microprobe analytical data

NASA Astrophysics Data System (ADS)

Nelson, David R.

2006-11-01

A Visual Basic program for flexible, interactive processing of ion-microprobe data acquired for quantitative trace element, 26Al- 26Mg, 53Mn- 53Cr, 60Fe- 60Ni and U-Th-Pb geochronology applications is described. Default but editable run-tables enable software identification of secondary ion species analyzed and for characterization of the standard used. Counts obtained for each species may be displayed in plots against analysis time and edited interactively. Count outliers can be automatically identified via a set of editable count-rejection criteria and displayed for assessment. Standard analyses are distinguished from Unknowns by matching of the analysis label with a string specified in the Set-up dialog, and processed separately. A generalized routine writes background-corrected count rates, ratios and uncertainties, plus weighted means and uncertainties for Standards and Unknowns, to a spreadsheet that may be saved as a text-delimited file. Specialized routines process trace-element concentration, 26Al- 26Mg, 53Mn- 53Cr, 60Fe- 60Ni, and Th-U disequilibrium analysis types, and U-Th-Pb isotopic data obtained for zircon, titanite, perovskite, monazite, xenotime and baddeleyite. Correction to measured Pb-isotopic, Pb/U and Pb/Th ratios for the presence of common Pb may be made using measured 204Pb counts, or the 207Pb or 208Pb counts following subtraction from these of the radiogenic component. Common-Pb corrections may be made automatically, using a (user-specified) common-Pb isotopic composition appropriate for that on the sample surface, or for that incorporated within the mineral at the time of its crystallization, depending on whether the 204Pb count rate determined for the Unknown is substantially higher than the average 204Pb count rate for all session standards. Pb/U inter-element fractionation corrections are determined using an interactive log e-log e plot of common-Pb corrected 206Pb/ 238U ratios against any nominated fractionation-sensitive species pair (commonly 238U 16O +/ 238U +) for session standards. Also displayed with this plot are calculated Pb/U and Pb/Th calibration line regression slopes, y-intercepts, calibration uncertainties, standard 204Pb- and 208Pb-corrected 207Pb/ 206Pb dates and other parameters useful for assessment of the calibration-line data. Calibrated data for Unknowns may be automatically grouped according to calculated date and displayed in color on interactive Wetherill Concordia, Tera-Wasserburg Concordia, Linearized Gaussian ("Probability Paper") and Gaussian-summation probability density diagrams.

A >400 kyrs archive of sedimentation in Scladina cave (Belgium)

NASA Astrophysics Data System (ADS)

Vonhof, Hubert; Bonjean, Dominique; Pirson, Stéphane; van der Lubbe, Jeroen; Hellstrom, John; Scholz, Denis; Verheyden, Sophie

2017-04-01

Scladina Cave, near the Meuse River in Belgium, is well-known for its well preserved Neanderthal fossils and stone tools. Cave research started in the 1970's, when archeological findings near the entrance of the cave initiated a long-running excavation programme in the -at that time- almost completely sediment-infilled cave. Over the past decades, a wealth of mammal fossils, stone tools, and a mandible of a Neanderthal child were found, and the complex sedimentary context of the cave strata was reconstructed in high detail. Crucial to understanding the cave stratigraphy is the construction of an absolutely dated age model. Until recently, this age model was based on a number of OSL ages, pollen stratigraphy and a few U-series ages on flowstone and stalagmite calcite. These U-series ages, however, had much lower precision than can be obtained by modern MC-ICP-MS techniques. In this study, we present new and more precise U-series ages for the major flow stone levels in Scladina Cave (upper stratigraphical sequence), and two flowstone levels from Sous-Saint-Paul Cave (lower stratigraphical sequence). The oldest flow stone layer dates back to > 400 ka, and the youngest represents the Holocene. The age model shows that flow stone formation typically occurred during warm climate conditions. These findings help to improve the existing age model for Scladina Cave significantly, and place better constraints on the age of individual fossils, and fossil assemblages in the cave.

Alteration and chemical U-Th-total Pb dating of heterogeneous high-uranium zircon from a pegmatite from the Aduiskii massif, middle Urals, Russia

NASA Astrophysics Data System (ADS)

Zamyatin, Dmitry A.; Shchapova, Yuliya V.; Votyakov, Sergey L.; Nasdala, Lutz; Lenz, Christoph

2017-09-01

The U-Th-Pb isotope system in the accessory mineral zircon may be disturbed, as for instance by the secondary loss of radiogenic lead. The recognition of such alteration is crucial for the sound interpretation of geochronology results, in particular for chemical dating by means of an electron probe micro-analyser (EPMA). Here we present the example of high-U zircon samples from a granite pegmatite from the Aduiskii Massif, Middle Urals, Russia. The structural and chemical heterogeneity of samples was characterised by EPMA, including joint probability distribution (JPD) analysis of back-scattered electrons (BSE), cathodoluminescence (CL) and U M β images, and by Raman and photoluminescence (PL) spectroscopy. We found a high-U interior region (U up to 11.4 wt%) without any obvious indication of alteration. This domain has stoichiometric composition, and its Raman spectrum is similar to that of amorphous ZrSiO4. In addition, altered lower-U regions are present that are non-stoichiometric and contain non-formula elements such as Ca, Al, Fe, and water up to several wt%. Their Raman spectra yielded a band near 760-810 cm-1 which is not related to any ZrSiO4 vibration; we assign it tentatively to the symmetric stretching of (UO2)2+ groups. This assignment is supported by the observation of a fairly intense PL phenomenon whose spectral position and vibrational-coupling structure strongly indicates a uranyl-related emission. Altered zones were formed by both fluid-driven diffusion reaction and coupled dissolution-reprecipitation processes. The variation of BSE and CL intensities in amorphous high-U zircon is controlled by its chemical composition and the presence of water and uranyl groups. We have determined a weighted mean EPMA age of 246 ± 2 Ma, which agrees reasonably well with previous dating results for the Aduiskii Massif.

Radioactive springs geochemical data related to uranium exploration

USGS Publications Warehouse

Cadigan, R.A.; Felmlee, J.K.

1977-01-01

Radioactive mineral springs and wells at 33 localities in the States of Colorado, Utah, Arizona and New Mexico in the United States were sampled and studied to obtain geochemical data which might be used for U exploration. The major source of radioactivity at mineral spring sites is 226Ra. Minor amounts of 228Ra, 238U and 232Th are also present. Ra is presumed to have been selectively removed from possibly quite deep uranium-mineralized rock by hydrothermal solutions and is either precipitated at the surface or added to fresh surface water. In this way, the source rocks influence the geochemistry of the spring waters and precipitates. Characteristics of the spring waters at or near the surface are also affected by variations in total dissolved solids, alkalinity, temperature and co-precipitation. Spring precipitates, both hard and soft, consist of four major types: (1) calcite travertine; (2) iron- and arsenic-rich precipitates; (3) manganese- and barium-rich precipitates; and (4) barite, in some instances accompanied by S, Ra and U, if present in the spring water, are co-precipitated with the barite, Mn-Ba and Fe-As precipitates. Using parameters based on U and Ra concentrations in waters and precipitates springsite areas are tentatively rated for favourability as potential uraniferous areas. ?? 1977.

Atmospheric dust contribution to budget of U-series nuclides in weathering profiles. The Mount Cameroon volcano

NASA Astrophysics Data System (ADS)

Pelt, E.; Chabaux, F. J.; Innocent, C.; Ghaleb, B.

2009-12-01

Analysis of U-series nuclides in weathering profiles is developed today for constraining time scale of soil and weathering profile formation (e.g., Chabaux et al., 2008). These studies require the understanding of U-series nuclides sources and fractionation in weathering systems. For most of these studies the impact of aeolian inputs on U-series nuclides in soils is usually neglected. Here, we propose to discuss such an assumption, i.e., to evaluate the impact of dust deposition on U-series nuclides in soils, by working on present and paleo-soils collected on the Mount Cameroon volcano. Recent Sr, Nd, Pb isotopic analyses performed on these samples have indeed documented significant inputs of Saharan dusts in these soils (Dia et al., 2006). We have therefore analyzed 238U-234U-230Th nuclides in the same samples. Comparison of U-Th isotopic data with Sr-Nd-Pb isotopic data indicates a significant impact of the dust input on the U and Th budget of the soils, around 10% for both U and Th. Using Sr-Nd-Pb isotopic data of Saharan dusts given by Dia et al. (2006) we estimate U-Th concentrations and U-Th isotope ratios of dusts compatible with U-Th data obtained on Saharan dusts collected in Barbados (Rydell H.S. and Prospero J.M., 1972). However, the variations of U/Th ratios along the weathering profiles cannot be explained by a simple mixing scenario between material from basalt and from the defined atmospheric dust pool. A secondary uranium migration associated with chemical weathering has affected the weathering profiles. Mass balance calculation suggests that U in soils from Mount Cameroon is affected at the same order of magnitude by both chemical migration and dust accretion. Nevertheless, the Mount Cameroon is a limit case were large dust inputs from continental crust of Sahara contaminate basaltic terrain from Mount Cameroon volcano. Therefore, this study suggests that in other contexts were dust inputs are lower, or the bedrocks more concentrated in U and Th, the dust contribution will not significantly influence U-series dating. Chabaux F., Bourdon B., Riotte J. (2008). U-series Geochemistry in weathering profiles, river waters and lakes. Radioactivity in the Environment, 13, 49-104. Dia A., Chauvel C., Bulourde M. and Gérard M. (2006). Eolian contribution to soils on Mount Cameroon: Isotopic and trace element records. Chem. Geol. 226, 232-252. Rydell H.S. and Prospero J.M. (1972). Uranium and thorium concentrations in wind-borne Saharan dust over the western equatorial north atlantic ocean. EPSL 14, 397-402.

An absolutely dated high-resolution stalagmite record from Lianhua Cave in central China: Climate forcing and comparison with Wanxiang Cave and Dongge Cave records over the past 2000 years

NASA Astrophysics Data System (ADS)

Li, Hong-Chun; Yin, Jian-Jun; Shen, Chuan-Chou; Mii, Horng-Sheng; Li, Ting-Yong

2015-04-01

A 33-cm long aragonite stalagmite (LHD-1) from Lianhua Cave has been dated by MC-ICPMS 230Th/U method on 41 horizons. Very high U contents (1~6ppm) and low Th contents yield excellent 230Th/U dates which provide reliable chronology of the stalagmite on sub-decadal time scale over the past 3350 years. A total of 1716 samples have been measured for δ18O and δ13C, spanning annual resolution over the past 1820 years. The stalagmite δ18O is not only influenced by the 'amount effect', but also affected by the moisture source. Enhanced the tropical monsoon trough under strong EASM brings higher spring quarter rainfall with isotopically light monsoonal moisture in the cave site, resulting in lighter stalagmite δ18O. On decadal or longer time scales, increased solar activity produces warmer condition and stronger summer monsoon which lead to wet climates. On interannual-to-decadal scales, the Walker Circulation under El Niño conditions during cold periods will shift toward the central Pacific and result in weakening of EASM. Under such a circumstance, dry climates will be prevailed in the study area. Based on the δ18O and δ13C records, we have deciphered climatic and vegetation changes of the study area in decadal scales. The highly precise dated LHD-1 record has been compared with previous published Wanxiang Cave and Dongge Cave records. Although some similarities can be found, there are major discrepancies among the three well-dated records, especially during AD 500-700 and AD 1300-1600. In additional, the major weak monsoon periods defined in the Wanxiang Cave record during late Tang Dynasty, late Yuan Dynasty and late Ming Dynasty are not supported by the LHD-1 record. The heaviest δ18O peaks (more than five continuous heavy values) over the past 2000 years appeared around AD 1990-2003, 1657-1662, 1220-1228, 663-669, 363-370, and 1082-1090 (in the order of heavy to light). None of these periods occurred Chinese dynasty collapse.

U-series dating of impure carbonates: An isochron technique using total-sample dissolution

USGS Publications Warehouse

Bischoff, J.L.; Fitzpatrick, J.A.

1991-01-01

U-series dating is a well-established technique for age determination of Late Quaternary carbonates. Materials of sufficient purity for nominal dating, however, are not as common as materials with mechanically inseparable aluminosilicate detritus. Detritus contaminates the sample with extraneous Th. We propose that correction for contamination is best accomplished with the isochron technique using total sample dissolution (TSD). Experiments were conducted on artificial mixtures of natural detritus and carbonate and on an impure carbonate of known age. Results show that significant and unpredictable transfer of radionuclides occur from the detritus to the leachate in commonly used selective leaching procedures. The effects of correcting via leachate-residue pairs and isochron plots were assessed. Isochrons using TSD gave best results, followed by isochron plots of leachates only. ?? 1991.

Timing of the onset of MIS 11 revealed by speleothem in southern Europe

NASA Astrophysics Data System (ADS)

Hu, Hsun-Ming; Shen, Chuan-Chou; Michel, Véronique; Kano, Akihiro

2017-04-01

The interglacial period, known as Marine Isotope Stage 11 (MIS 11, 428-397 thousand years ago), is often considered as a potential analogue for future climate projection because of the similar patterns of insolation variability. However, studies on mechanisms of the onset of MIS 11 (called Termination V, T-V) in response to insolation increase is still hampered by a lack of good dating materials in paleoclimate archives, despite a stack of East Asian monsoon records with precise U-Th dates has been proposed. Previous studies suggested the δ18O value registered in speleothems in Mediterranean realm can be a good bridge connecting the U-Th-based age model of speleothem to marine cores from Mediterranean sea, which opens a new possibility to detect ocean-atmosphere/internal-external forcing interaction beyond 14C dating limitation. Here we present a new speleothem δ18O record from northern Italy covering 500-300 thousand years ago. The results show a similar pattern with δ18O records of marine cores around Mediterranean. The age model of the speleothem hence provides an opportunity for tuning the marine cores, which could improve our understanding of relationship between global atmosphere and ocean circulations.

Analysis of a Uranium Oxide Sample Interdicted in Slovakia (FSC 12-3-1)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borg, Lars E.; Dai, Zurong; Eppich, Gary R.

2014-01-17

We provide a concise summary of analyses of a natural uranium sample seized in Slovakia in November 2007. Results are presented for compound identification, water content, U assay, trace element abundances, trace organic compounds, isotope compositions for U, Pb, Sr and O, and age determination using the 234U – 230Th and 235U – 231Pa chronometers. The sample is a mixture of two common uranium compounds - schoepite and uraninite. The uranium isotope composition is indistinguishable from natural; 236U was not detected. The O, Sr and Pb isotope compositions and trace element abundances are unremarkable. The 234U – 230Th chronometer givesmore » an age of 15.5 years relative to the date of analysis, indicating the sample was produced in January 1997. A comparison of the data for this sample with data in the Uranium Sourcing database failed to find a match, indicating the sample was not produced at a facility represented in the database.« less

Younger Dryas to Early Holocene paleoclimate in Cantabria (N Spain): Constraints from speleothem Mg, annual fluorescence banding and stable isotope records

NASA Astrophysics Data System (ADS)

Rossi, Carlos; Bajo, Petra; Lozano, Rafael P.; Hellstrom, John

2018-07-01

The Younger Dryas (YD) stadial represents the most abrupt climate change of the Earth's recent history. Thus, understanding its causes and different local responses is relevant for Quaternary paleoclimatology. We present a speleothem high-resolution proxy record of the Lateglacial to Early Holocene paleoclimate of the Cantabrian Cordillera (N Spain), a strategic location to evaluate the influence of North Atlantic events such as the YD on South-Western Europe. Fluorescence lamination, growth-rate, stable-isotope, and [Mg] records from stalagmite SIR-1 were dated using an age-depth model constrained by U-Th dates and annual-lamina counting. The YD is recorded as a prominent positive δ13C excursion whose chronology (12.95 ± 0.14 to 11.62 ± 0.16 ka) and shape closely agree with the GS-1 stadial as defined in Greenland ice, supporting the event synchronicity in both areas. A colder and drier YD climate limited soil productivity and dripwater availability, leading to higher δ13C and [Mg], reduced growth rate, and virtually absent fluorescence lamination. The early YD record (until ∼12.5 ka) reflects increasing aridity, whereas the late YD (from ∼12.2 ka on) shows the opposite trend. At the YD boundaries, temperature changes influenced the [Mg] record by modifying the Mg partition into calcite. However, this effect was superseded by major changes in dripwater Mg/Ca linked to rainfall variations. During the Early Holocene, the Arnero Sierra was forested and had a relatively warm and humid seasonal climate, indicated in SIR-1 by higher growth rates, lower δ13C and [Mg], and well-developed fluorescent lamination. Similar to other high-resolution stalagmitic records of the Cordillera, from ∼8.5 to 8.0 ka SIR-1 reflects a temporary trend of increasing aridity.

The age of Homo naledi and associated sediments in the Rising Star Cave, South Africa

PubMed Central

Dirks, Paul HGM; Roberts, Eric M; Hilbert-Wolf, Hannah; Kramers, Jan D; Hawks, John; Dosseto, Anthony; Duval, Mathieu; Elliott, Marina; Evans, Mary; Grün, Rainer; Hellstrom, John; Herries, Andy IR; Joannes-Boyau, Renaud; Makhubela, Tebogo V; Placzek, Christa J; Robbins, Jessie; Spandler, Carl; Wiersma, Jelle; Woodhead, Jon; Berger, Lee R

2017-01-01

New ages for flowstone, sediments and fossil bones from the Dinaledi Chamber are presented. We combined optically stimulated luminescence dating of sediments with U-Th and palaeomagnetic analyses of flowstones to establish that all sediments containing Homo naledi fossils can be allocated to a single stratigraphic entity (sub-unit 3b), interpreted to be deposited between 236 ka and 414 ka. This result has been confirmed independently by dating three H. naledi teeth with combined U-series and electron spin resonance (US-ESR) dating. Two dating scenarios for the fossils were tested by varying the assumed levels of 222Rn loss in the encasing sediments: a maximum age scenario provides an average age for the two least altered fossil teeth of 253 +82/–70 ka, whilst a minimum age scenario yields an average age of 200 +70/–61 ka. We consider the maximum age scenario to more closely reflect conditions in the cave, and therefore, the true age of the fossils. By combining the US-ESR maximum age estimate obtained from the teeth, with the U-Th age for the oldest flowstone overlying Homo naledi fossils, we have constrained the depositional age of Homo naledi to a period between 236 ka and 335 ka. These age results demonstrate that a morphologically primitive hominin, Homo naledi, survived into the later parts of the Pleistocene in Africa, and indicate a much younger age for the Homo naledi fossils than have previously been hypothesized based on their morphology. DOI: http://dx.doi.org/10.7554/eLife.24231.001 PMID:28483040

Biogeochemical alteration effects on U/Th geochronology of Pleistocene corals, Penguin Bank, Molokai, Hawai`i

NASA Astrophysics Data System (ADS)

Herries, K.; Rubin, K. H.; Hellebrand, E.

2017-12-01

Meltwater Pulse 1a (MWP-1a) is a large, relatively fast sea level rise event that occurred during the last deglaciation. Critical questions remain about the exact timing of MWP-1a and can be answered using high precision geochronology. Coral reefs are able to yield ideal records of sea level and ocean changes during and after deposition. Glacial far-field fossilized coral reefs, such as the well-preserved Penguin Bank reef near Molokai, Hawai'i, provide understandings to past sea level events that are relatively unaffected by local deglacial sea level effects. Using uranium-thorium dating of pristine corals, we are able date sea level events to an error of ±25-50 years. However, most Penguin Bank coral samples have been biogeochemically disturbed by other mesophotic organisms either during their lifetime or after their death. In these samples, the main disturbances observed in hand specimen are (1) overgrowth by coralline algae, (2) bioerosion from boring organisms, (3) living organisms, like sponges, inside coral skeletons, and (4) discoloration due to detrital materials. These disturbances are capable of disrupting the concentration of U in the coral and/or δ 234U measured. Seawater alteration-sensitive ratios, such as Sr/Ca and Mg/Ca, act as a proxy for potential diagenetic effects on U distribution in the corals. U and Th isotopic data acquired on both pristine and altered parts of the corals are being used to determine the impacts of alteration in the measured ages. With these new data, it may be possible to derive a more accurate timing of MWP-1a and provide a more general method of determining the suitability of coral specimens for dating of the last deglaciation and past climate change.

Dioxins, furans, biphenyls, arsenic, thorium and uranium in natural and anthropogenic sources of phosphorus and calcium used in agriculture.

PubMed

Avelar, A C; Ferreira, W M; Pemberthy, D; Abad, E; Amaral, M A

2016-05-01

The aim of this study was to assess the presence of dioxins, furans and biphenyls, and the inorganic contaminants such as arsenic (As), thorium (Th) and uranium (U) in three main products used in Agriculture in Brazil: feed grade dicalcium phosphate, calcined bovine bone meal and calcitic limestone. The first two are anthropogenic sources of phosphorus and calcium, while calcitic limestone is a natural unprocessed mineral. Regarding to dioxin-like substances, all samples analyzed exhibited dioxins (PCDD) and furans (PCDF) and dioxin-like polychlorinated biphenyls (dl-PCBs) concentrations below limit of detection (LOD). In general, achieved is in accordance with regulation in Brazil where is established a maximum limit in limestone used in the citric pulp production (0.50pg WHO-TEQ g(-1)). In addition, reported data revealed very low levels for limestone in comparison with similar materials reported by European legislation. As result for toxic metals, achieved data were obtained using Instrumental Neutron Activation Analysis (INAA). On one hand, limestone sample exhibits the largest arsenic concentration. On another hand, dicalcium phosphate exhibited the largest uranium concentration, which represents a standard in animal nutrition. Therefore, it is phosphorus source in the animal feed industry can be a goal of concern in the feed field. Copyright © 2016 Elsevier B.V. All rights reserved.

Fourier transform Raman spectroscopy and archaeology: a preliminary study of human teeth

NASA Astrophysics Data System (ADS)

Edwards, Howell G.; Farwell, Dennis W.; Roberts, Charlotte A.; Williams, Adrian C.

1994-01-01

The FT-Raman spectra of human bones and teeth in archaeological specimens dating to the 4th and 10th centuries AD from Romano-British and Anglo-Saxon burial sites in the U.K. have been recorded successfully using microscopic and remote sensing techniques. The samples exhibit fluorescence ascribed to mineral absorption from the grave soils but, nevertheless, good quality spectra are obtained. The versatility of the technique for non destructive sampling is demonstrated.

Estimated Marine Residence Times for Drowned Barbadian Paleoreefs

NASA Astrophysics Data System (ADS)

Mey, J. L.

2008-12-01

Fossil corals are used to estimate past sea level and also to calibrate 14C ages with the aid of U-Th and U-Pa dating methods. These coral fossils have often been subaerially exposed and thus are affected by diagenesis during their initial interaction with fresh water. In an effort to understand when such disequilibria in fossil coral reefs occurred, we have quantified our 'dissolution-cum-adsorption' model (Mey, 2008) for the uranium series disequilibria using a geometrical construction, based on the evolution of the activities in a 230Th/238U versus 234U/238U diagram for closed versus open systems. The traditional age equations for the uranium-series with excess daughters have been used to construct a relationship between (i) the angles of the equal age lines in the 230Th/238U versus 234U/238U activity diagrams, and (ii) the quantified angles of the regressed lines of several uranium series disequilibria trends from Barbados. Our results indicate that the severity of the Barbados uranium series disequilibria is not only explained by 234U and 230Th addition, but may also reflect a loss of 238U through dissolution of coral skeletal structure. The net effect is 238U removal, whereas 234U and 230Th remain; thus, the disequilibria for the extant coral increase the excess daughters' ratio. Our results further indicate that the activity of 234U is reduced (compared to 230Th), as would be expected in regard to the lower mobility of trapped 230Th. It is proposed that the major dissolution that caused the uranium series disequilibria occurred during one relatively short-lived event when the paleoreefs experienced the very first freshwater exposure. During this event, the diagenetic potential was at its maximum for redistribution of the uranium series; this then caused the 234U and the 230Th to behave in a systematic way, resulting in linear trends. The linear trends in the open system uranium series were set early, as shown in the 230Th/238U versus 234U/238U activity diagrams. The timing of the first exposure of the freshwater in the reefs is calculated based on the results of our new model. From the relationship between, (i) dissolution, (ii) in-grown 230Th, and (iii) excess 234U, we derived that the 60,000 old Marine Isotope stage 3 (MIS 3) reef was exposed to freshwater 36-38,000 years after growth in the marine environment. We have calculated these 'marine residence times' for the MIS 3 5a, 5c, 5e, 6.0, 7a and 7c reefs; our results correspond with the duration of the sea level high stand in each of the stages. References: Mey, J. L., (2008) The Uranium Series Diagenesis and the Morphology of Drowned Barbadian Paleoreefs, PhD dissertation, 325pp: Graduate Center, City University of New York, New York.

A multidisciplinary analysis to constrain exhumation and recent erosion history of the Tethyan Himalaya, based on apatite (U-Th-Sm)/He and cosmogenic nuclides dates from Central Nepal (Takkhola graben and the Mustang granite)

NASA Astrophysics Data System (ADS)

Rosenkranz, Ruben; Sahragard Sohi, Mohammad; Spiegel, Cornelia

2015-04-01

The exhumation of the Himalayan arc has been studied intensively throughout the last decades. For the Tethyan Himalaya, however, the youngest exhumation history is still unclear, mostly because of the lack of a significant apatite content in most Tethyan sediments (Crouzet et al. 2007). For this study we are using apatite (U-Th-Sm)/He thermochronology and cosmogenic nuclides for investigating exhumation and denudation of the Tethyan Himalaya back through time. Apatite (U-Th-Sm)/He thermochronology is sensitive to temperatures of ~40 to 85°C and thus to movements within the upper ~1.5 to 3 km of the earth's crust. During a recent field campaign, we sampled the Mustang granite, that intrudes the Tethyan marine sediments and the Takkhola-Graben. The graben can be seen as an inusual southern part of the normal faulting system affecting the whole Tibetan Plateau (Colchen, 1999). The timing of the activation of these faulting is still highly debated. The syntectonics filling of the Takkhola-Mustag graben consists of Mio-Pliocene fluvio-lacustrine deposits (Garzione et al. 2003). These were described as containing significant amounts of apatite, derived from the past erosion of the Mustang granitic body (Adhikari and Wagreich, 2011). Being only up to 1km thick, a post depositional thermal resetting of the apatite (U-Th-Sm)/He system is unlikely, so that the (U-Th-Sm)/He dates of the sediments are expected to have retained their information regarding source area exhumation. We took several sand samples from the Kali Gandaki River draining the present-day exposure of the Mustang granite. Furthermore, we sampled different stratigraphic levels of the Mio-Pliocene sedimentary rocks, i.e., from the Tetang and Takkahola formation deposited between 11 and 7 Ma. This sampling approach will not only provide information about the youngest denudation history of the Mustang granite /Tethyan Himalaya, but will also reveal insights into its past denudation and changes of denudation rates through time for the region north to the South Tibetan Detachment. It is our expectation to link the results to the tectonic behavior of the South Tibetan Detachment or to the newly recognized Western Nepal Fault System. Corroborating our results with other ages and diverse methods will provide a robust constraint on the exhumation and erosion history of the Tethyan Himalaya, as well as insights on the U-Th/He dating technique. References Adhikari, B.R. and Wagreich, M., 2011. Provenance evolution of collapse graben fill in the Himalaya-The Miocene to Quaternary Thakkhola-Mustang graben (Nepal). Sedimentary Geology, 233(1), pp.1-14. Blythe, A.E., Burbank, D.W., Carter, A., Schmidt, K., Putkonen, J., 2007. Plio-Quaternary exhumation history of the central Nepalese Himalaya: 1. Apatite and zircon fission track and apatite [U-Th]/He analyses. Tectonics, 26(3). Crouzet, C. et al., 2007. Temperature and age constraints on the metamorphism of the Tethyan Himalaya in Central Nepal: A multidisciplinary approach. Journal of Asian Earth Sciences, 30(1), pp.113-130. Garzione, C.N, DeCelles, P.G., Hokinson, D.G., Ojha, T.P., Upreti, B.N., 2003. East-west extension and Miocene environmental change in the southern Tibetan plateau: Thakkhola graben, central Nepal. Geological Society of America Bulletin, 115(1), pp.3-20. Colchen, M., 1999. The Takkhola-Mustang graben in Nepal and the latee Cenozoic extension in the Higher Himalayas. Journal of Asian Earth Sciences, 17, pp. 683-702.

Hydrothermal karst and associated breccias in Neoproterozoic limestone from the Barker-Villa Cacique area (Tandilia belt), Argentina

NASA Astrophysics Data System (ADS)

Dristas, Jorge A.; Martínez, Juan C.; van den Kerkhof, Alfons M.; Massonne, Hans-Joachim; Theye, Thomas; Frisicale, María C.; Gregori, Daniel A.

2017-07-01

In the Barker-Villa Cacique area (Tandilia belt), remarkable megabreccias, limestone breccias and phosphate-bearing breccias hosted in black limestone and along the contact with the upper section of the sedimentary succession are exposed. These rocks are the result of extensive hydrothermal alteration of the original micritic limestone and other fine-grained clastic sediments. Typical alteration minerals are sericite, chlorite, interstratified chlorite/K-white mica, kaolinite, dickite, pyrite, chalcopyrite, goethite, quartz, calcite, Fe-calcite, dolomite, ankerite, fluor-apatite, barite and aluminium-phosphate-sulfate (APS) minerals. Quartz and calcite cements from hydraulic breccias in the limestone contain low-salinity aqueous fluid inclusions. Corresponding homogenization temperatures display 200-220 °C and 110-140 °C in hydrothermal quartz, and 130-150 °C in late calcite cement. Carbon and oxygen stable isotope analyses of carbonates from the Loma Negra quarry (LNQ) support the major role of hydrothermal activity. A significant difference was found between δ18Ocar values from unaltered micritic limestone (ca. 23.8‰ SMOW) and secondary calcite (ca. 18.5‰ SMOW). The lower δ18Ocar values are interpreted as a result of calcite precipitation from hot hydrothermal fluids. At a late stage, the hydrothermal fluid containing H2S mixed with descending and oxidizing meteoric waters. Circulation of the ensuing acid fluids resulted in the partly dissolution and collapse brecciation of the Loma Negra Formation. The hydrothermal stage can be tentatively dated ca. 590-620 Ma corresponding to the Brasiliano orogeny.

Caves in caves: Post depositional holes in stalagmites

NASA Astrophysics Data System (ADS)

Shtober Zisu, Nurit; Schwarcz, Henry P.; Chow, Tom; Konyer, Norman B.; Noseworthy, Michael D.

2010-05-01

Previous studies of speleothems for the purposes of isotopic analysis and U-series dating have resulted in preparation of stalagmites by sectioning longitudinally along the growth axis. We frequently observe holes in such sections, both along the growth axis, and laterally to it, ranging in size up to several mm in diameter. Our initial supposition was that these holes are produced during the growth of the stalagmite under constant dripping conditions, but it was found that two kinds of holes exist within the stalagmites. "Axial holes" were formed syngenetically as is shown by the depression of growth layers into the holes and the persistence of the axial hole over many cm of the growth history. Some cut the active growth surface of the stalagmite. "Off-axis holes" are seen in many stalagmites (as well as stalactites); they cut discordantly through growth layers, and never terminate at a growth surface. They range in size from a few mm to several cm in maximum dimension, and may not be coaxially oriented. They are lined with micron-sized, randomly oriented calcite crystals and under which lies an organic-rich coating. We used CT (Computed Tomography) and MRI (Magnetic Resonance Imaging) scanning in order to locate holes, and to search for water trapped in these macro-inclusions. These methods, allow us to visualize the holes without destruction of the stalagmite, the holes and the surrounding calcite. To our best knowledge, the present paper is the first to combine CT and MRI methods in the study of fluid inclusions in rocks, or in visualizing the distribution of holes in speleothems. CT scans reveal abundant off-axis holes in some speleothems, while most display at least a few holes. MRI scans shows that, in uncut speleothems, these holes never contain water (although Genty et al. [2002] found water-filled holes in some stalagmites). Off-axis holes may be a result of bioerosion, possibly bacterial, followed by partial refilling of the hole with calcite which is prevented from growing epitaxially on the host calcite.

The U/Th production ratio and the age of the Milky Way from meteorites and Galactic halo stars

NASA Astrophysics Data System (ADS)

Dauphas, Nicolas

2005-06-01

Some heavy elements (with atomic number A > 69) are produced by the `rapid' (r)-process of nucleosynthesis, where lighter elements are bombarded with a massive flux of neutrons. Although this is characteristic of supernovae and neutron star mergers, uncertainties in where the r-process occurs persist because stellar models are too crude to allow precise quantification of this phenomenon. As a result, there are many uncertainties and assumptions in the models used to calculate the production ratios of actinides (like uranium-238 and thorium-232). Current estimates of the U/Th production ratio range from ~0.4 to 0.7. Here I show that the U/Th abundance ratio in meteorites can be used, in conjunction with observations of low-metallicity stars in the halo of the Milky Way, to determine the U/Th production ratio very precisely . This value can be used in future studies to constrain the possible nuclear mass formulae used in r-process calculations, to help determine the source of Galactic cosmic rays, and to date circumstellar grains. I also estimate the age of the Milky Way ( in a way that is independent of the uncertainties associated with fluctuations in the microwave background or models of stellar evolution.

ENVIRONMENTAL MANAGEMENT SCIENCE PROGRAM PROJECT NUMBER 87016 CO-PRECIPITATION OF TRACE METALS IN GROUNDWATER AND VADOSE ZONE CALCITE: IN SITU CONTAINMENT AND STABILIZATION OF STRONTIUM-90 AND OTHER DIVALENT METALS AND RADIONUCLIDES AT ARID WESTERN DOE SITES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferris, F. Grant; Fujita, Yoshiko; Smith, Robert W.

2004-06-15

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. In situ containment and stabilization of these contaminants in vadose zones or groundwater is a cost-effective treatment strategy. Our facilitated approach relies upon the hydrolysis of introduced urea to cause the acceleration of calcium carbonate precipitation (and trace metal coprecipitation) by increasing groundwater pH and alkalinity (Fujita et al., 2000; Warren et al., 2001). Subsurface urea hydrolysis is catalyzed by the urease enzyme, which may be either introduced with the urea or produced in situ by ubiquitous subsurface ureamore » hydrolyzing microorganisms. Because the precipitation processes are irreversible and many western aquifers are saturated with respect to calcite, the co-precipitated metals and radionuclides will be effectively removed from groundwater. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution (Zachara et al., 1991), solid solution properties of the trace metal in calcite (Tesoriero and Pankow, 1996), and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning, and how this occurs in aquifers and vadose environments is lacking. This report summarizes work undertaken during the second year of this project.« less

Geochronology and petrogenesis of MORB from the Juan de Fuca and Gorda ridges by 238U230Th disequilibrium

USGS Publications Warehouse

Goldstein, S.J.; Murrell, M.T.; Janecky, D.R.; Delaney, J.R.; Clague, D.A.

1991-01-01

A highly precise mass spectrometric method of analysis was used to determine 238U234U230Th232Th in axial and off-axis basalt glasses from Juan de Fuca (JDF) and Gorda ridges. Initial 230Th activity excesses in the axial samples range from 3 to 38%, but generally lie within a narrow range of 12 to 15%. Secondary alteration effects were evaluated using ??234U and appear to be negligible; hence the 230Th excesses are magmatic in origin. Direct dating of MORB was accomplished by measuring the decrease in excess 230Th in off-axis samples. 238U230Th ages progressively increase with distance from axis. Uncertainties in age range from 10 to 25 ka for UTh ages of 50 to 200 ka. The full spreading rate based on UTh ages for Endeavour segment of JDF is 5.9 ?? 1/2 cm/yr, with asymmetry in spreading between the Pacific (4.0 ?? 0.6 cm/yr) and JDF (1.9 ?? 0.6 cm/yr) plates. For northern Gorda ridge, the half spreading rate for the JDF plate is found to be 3.0 ?? 0.4 cm/yr. These rates are in agreement with paleomagnetic spreading rates and topographic constraints. This suggests that assumptions used to determine ages, including constancy of initial 230Th 232Th ratio over time, are generally valid for the areas studied. Samples located near the axis of spreading are typically younger than predicted by these spreading rates, which most likely reflects recent volcanism within a 1-3 km wide zone of crustal accretion. Initial 230Th/232Th ratios and 230Th activity were also used to examine the recent Th/U evolution and extent of melting of mantle sources beneath these ridges. A negative anomaly in 230Th 232Th for Axial seamount lavas provides the first geochemical evidence of a mantle plume source for Axial seamount and the Cobb-Eickelberg seamount chain and indicates recent depletion of other JDF segment sources. Large 230Th activity excesses for lavas from northern Gorda ridge and Endeavour segment indicate formation from a lower degree of partial melting than other segments. An inverse correlation between 230Th excess and 230Th 232Th for each ridge indicates that these lower degree melts formed from slightly less depleted sources than higher degree melts. Uniformity in 230Th excess for other segments suggests similarity in processes of melt formation and mixing beneath most of the JDF-Gorda ridge area. The average initial 230Th 232Th activity ratio of 1.31 for the JDF-Gorda ridge area is in agreement with the predicted value of 1.32 from the ThSr isotope mantle array. ?? 1991.

Modeling non-steady state radioisotope transport in the vadose zone--A case study using uranium isotopes at Pena Blanca, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ku, T. L.; Luo, S.; Goldstein, S. J.

2009-06-01

Current models using U- and Th-series disequilibria to study radioisotope transport in groundwater systems mostly consider a steady-state situation. These models have limited applicability to the vadose zone (UZ) where the concentration and migratory behavior of radioisotopes in fluid are often transitory. We present here, as a first attempt of its kind, a model simulating the non-steady state, intermittent fluid transport in vadose layers. It provides quantitative constraints on in-situ migration of dissolved and colloidal radioisotopes in terms of retardation factor and rock-water interaction (or water transit) time. For uranium, the simulation predicts that intermittent flushing in the UZ leadsmore » to a linear relationship between reciprocal U concentration and {sup 234}U/{sup 238}U ratio in percolating waters, with the intercept and slope bearing information on the rates of dissolution and {alpha}-recoil of U isotopes, respectively. The general validity of the model appears to be borne out by the measurement of uranium isotopes in UZ waters collected at various times over a period during 1995-2006 from a site in the Pena Blanca mining district, Mexico, where the Nopal I uranium deposit is located. Enhanced {sup 234}U/{sup 238}U ratios in vadose-zone waters resulting from lengthened non-flushing time as prescribed by the model provide an interpretative basis for using {sup 234}U/{sup 238}U in cave calcites to reconstruct the regional changes in hydrology and climate. We also provide a theoretical account of the model's potential applications using radium isotopes.« less

Modeling non-steady state radioisotope transport in the vadose zone - A case study using uranium isotopes at Peña Blanca, Mexico

NASA Astrophysics Data System (ADS)

Ku, T. L.; Luo, S.; Goldstein, S. J.; Murrell, M. T.; Chu, W. L.; Dobson, P. F.

2009-10-01

Current models using U- and Th-series disequilibria to study radioisotope transport in groundwater systems mostly consider a steady-state situation. These models have limited applicability to the vadose zone (UZ) where the concentration and migratory behavior of radioisotopes in fluid are often transitory. We present here, as a first attempt of its kind, a model simulating the non-steady state, intermittent fluid transport in vadose layers. It provides quantitative constraints on in-situ migration of dissolved and colloidal radioisotopes in terms of retardation factor and rock-water interaction (or water transit) time. For uranium, the simulation predicts that intermittent flushing in the UZ leads to a linear relationship between reciprocal U concentration and 234U/ 238U ratio in percolating waters, with the intercept and slope bearing information on the rates of dissolution and α-recoil of U isotopes, respectively. The general validity of the model appears to be borne out by the measurement of uranium isotopes in UZ waters collected at various times over a period during 1995-2006 from a site in the Peña Blanca mining district, Mexico, where the Nopal I uranium deposit is located. Enhanced 234U/ 238U ratios in vadose-zone waters resulting from lengthened non-flushing time as prescribed by the model provide an interpretative basis for using 234U/ 238U in cave calcites to reconstruct the regional changes in hydrology and climate. We also provide a theoretical account of the model's potential applications using radium isotopes.

76 FR 75870 - Stainless Steel Plate in Coils From Belgium: Notice of Extension of Time Limit for Preliminary...

Federal Register 2010, 2011, 2012, 2013, 2014

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77 FR 56254 - 89th Meeting: RTCA Special Committee 159, Global Positioning Systems (GPS)

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2012-09-12

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Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-27

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Towards Synthesis and Usage of Actinide-Bearing REE Phosphate age Standards: A Progress Report

NASA Astrophysics Data System (ADS)

Pyle, J. M.; Cherniak, D. J.

2006-05-01

Electron microprobe (EMP) dates result from a concentration-time unit conversion, so use of a concentration- based (rather than isotope-ratio based) fictive age standard is warranted. This observation has motivated our mineral synthesis program, aimed at producing actinide-doped REE phosphate EMP dating standards that meet the following criteria: 1) known concentrations of U, Th, and Pb; 2) homogeneous intragrain distribution of all components; 3) of suitable size, either as a single-crystal or polycrystalline sintered ceramic. Single-crystal synthesis of actinide-doped LaPO4 by flux-growth methods results in disproportionation of lanthanide and flux, alkali, and actinide components into phosphate and oxide phases, respectively, and flux- growth methods were abandoned. Actinide-doped La phosphate is successfully prepared by high-T annealing and hydrothermal processing of microcrystalline phosphate; both homogeneity and charge-balance of (Ca, Th, Pb)-bearing LaPO4 increase with increasing solvent acidity during cold-seal hydrothermal synthesis. A combination of pressing and high-T (1400° C) sintering transforms fine-grained (0.1-10 μm) run- products to ceramic pellets with 90-95% theoretical density. Our most recent runs focused on a target composition of La80(CaTh)17(CaU)2(PbTh)1PO4 processed with 6% 2M HCl at 820° C, 0.75 kbar for 1 week. The run products are 0.1-2 μm crystals identified by XRD as La-actinide phosphate solid solution. 2 μm grains (N=16) give a composition (mean±2 sd) of La79.77(1.26)(CaTh)17.87(1.00)(CaU)1.53(0.42)(PbTh)0.82(0.09)PO4. Th (8.07-9.13 wt. %) is homogeneous at the level of analytical precision, and the Pb concentration range (3500-4350 ppm) is restricted relative to untreated precipitate. Uranium concentration values are more variable (6500-10000 ppm). This run yields a fictive age of 702±4 Ma (mean±2 se), compared to the fictive age of 794 Ma for the target composition.

Reconstruction of seasonal temperature variability in the tropical Pacific Ocean from the shell of the scallop, Comptopallium radula

NASA Astrophysics Data System (ADS)

Thébault, Julien; Chauvaud, Laurent; Clavier, Jacques; Guarini, Jennifer; Dunbar, Robert B.; Fichez, Renaud; Mucciarone, David A.; Morize, Eric

2007-02-01

We investigated the oxygen isotope composition (δ 18O) of shell striae from juvenile Comptopallium radula (Mollusca; Pectinidae) specimens collected live in New Caledonia. Bottom-water temperature and salinity were monitored in-situ throughout the study period. External shell striae form with a 2-day periodicity in this scallop, making it possible to estimate the date of precipitation for each calcite sample collected along a growth transect. The oxygen isotope composition of shell calcite (δ 18O shell calcite) measured at almost weekly resolution on calcite accreted between August 2002 and July 2003 accurately tracks bottom-water temperatures. A new empirical paleotemperature equation for this scallop species relates temperature and δ 18O shell calcite: t(°C)=20.00(±0.61)-3.66(±0.39)×(δ18O-δ18O) The mean absolute accuracy of temperature estimated using this equation is 1.0 °C at temperatures between 20 and 30 °C. Uncertainties regarding the precise timing of CaCO 3 deposition and the actual variations in δ 18O water at our study sites probably contribute to this error. Comparison with a previously published empirical paleotemperature equation indicates that C. radula calcite is enriched in 18O by ˜0.7‰ relative to equilibrium. Given the direction of this offset and the lack of correlation between shell growth rate and δ 18O shell calcite, this disequilibrium is unlikely to be related to kinetic isotope effects. We suggest that this enrichment reflects (1) a relatively low pH in the scallop's marginal extrapallial fluid (EPF), (2) an isotopic signature of the EPF different from that of seawater, or (3) Rayleigh fractionation during the biocalcification process. Relative changes in δ 18O shell calcite reflect seawater temperature variability at this location and we suggest that the shell of C. radula may be useful as an archive of past seawater temperatures.

Late-stage magmatic to deuteric/metasomatic accessory minerals from the Cerro Boggiani agpaitic complex (Alto Paraguay Alkaline Province)

NASA Astrophysics Data System (ADS)

Comin-Chiaramonti, Piero; Renzulli, Alberto; Ridolfi, Filippo; Enrich, Gaston E. R.; Gomes, Celso B.; De Min, Angelo; Azzone, Rogério G.; Ruberti, Excelso

2016-11-01

This work describes rare accessory minerals in volcanic and subvolcanic silica-undersaturated peralkaline and agpaitic rocks from the Permo-Triassic Cerro Boggiani complex (Eastern Paraguay) in the Alto Paraguay Alkaline Province. These accessory phases consist of various minerals including Th-U oxides/silicates, Nb-oxide, REE-Sr-Ba bearing carbonates-fluorcarbonates-phosphates-silicates and Zr-Na rich silicates. They form a late-stage magmatic to deuteric/metasomatic assemblage in agpaitic nepheline syenites and phonolite dykes/lava flows made of sodalite, analcime, albite, fluorite, calcite, ilmenite-pyrophanite, titanite and zircon. It is inferred that carbonatitic fluids rich in F, Na and REE percolated into the subvolcanic system and metasomatically interacted with the Cerro Boggiani peralkaline and agpaitic silicate melts at the thermal boundary layers of the magma chamber, during and shortly after their late-stage magmatic crystallization and hydrothermal deuteric alteration.

Induction of calcite precipitation through heightened production of extracellular carbonic anhydrase by CO2 sequestering bacteria.

PubMed

Sundaram, Smita; Thakur, Indu Shekhar

2018-04-01

The thermo-alkalotolerant bacterium exhibiting heightened extracellular carbonic anhydrase (CA) activity, survived at 100 mM sodium bicarbonateand 5% gaseous CO 2 was identified as Bacillus sp. by 16S rRNA sequencing. Extracellular carbonic anhydrase was purified by ammonium sulfate precipitation, gel filtration chromatography and affinity chromatography with a yield of 46.61% and specific activity of 481.66 U/mg. The size of purified carbonic anhydrase was approximately 28 kDa in SDS-PAGE gel filtration and further their role in calcium carbonate production was correlated. The purified enzyme was stable with half-life of 25.36 min at 90 °C and pH 8. K M and Vmax values of the enzyme were 1.77 mg/mL and 385.69 U/mg respectively. The production of calcite was confirmed by Scanning Electron Microscopy (SEM) analysis, FTIR, and Energy-Dispersive X-ray (EDX) analysis. Carbonic anhydrase and calcite deposition coupled with CO 2 fixingbacteria is a significant approach for CO 2 sequestration. Copyright © 2018 Elsevier Ltd. All rights reserved.

Geochemical and sedimentological properties of Heinrich layers H2 and H1 off the Hudson Strait ice-surging source areas: ice-rafting vs water-laid down depositional mechanisms

NASA Astrophysics Data System (ADS)

Nuttin, L.; Hillaire-Marcel, C.

2012-12-01

The ~9 m-long core HU08-029-004PC was raised from the lower Labrador Sea slope (2674 m water-depth), approximately 180 km off Hudson Strait shelf edge. It yielded a high resolution record spanning the last 35 ka. The sequence includes layers with abundant detrital carbonates produced by glacial erosion of Paleozoic rocks and released into the Labrador Sea through ice streaming processes in Hudson Strait and Ungava Bay. These layers are assigned to 'Heinrich events' 3 (at core bottom), 2 and 1. Sedimentological properties and U and Th isotope measurements are used to document depositional mechanisms and durations of these layers. Data suggest: i) intense ice-rafting deposition (IRD) due to iceberg calving at the ice-stream edge, as illustrated by the coarse fraction content of the layers, and ii) sub-glacial meltwater flushing over the Hudson Strait sill, carrying fine silt-size, carbonate-rich glacial flour to the shelf-edge. Such suspended sediment pulses led to the spreading of turbidites mostly into the deep Labrador Sea, through the NAMOC system. Others late-glacial events, such as the ~ 8.2 ka final drainage of Lake Agassiz, are also recorded in the study core, whereas the H0 layer, exclusively observed in the western Labrador Sea is missing. CAT-scan images, mineralogical data, carbonate abundance, %>106 μm fraction (mostly IRD here), U-Th isotope data and 14C ages of planktic foraminifera assemblages (Neogloboquadrina pachyderma, l.) are used to further document H2 (760 to 700 cm) and H1 (588 to 488 cm). The H-layers contain up to 60% of fine detrital carbonates (about 2/3 calcite, 1/3 dolomite). Whereas the fine calcitic material points to sediment sources (basal till/water-laid glacial sediments) in the Hudson Strait and Ungava Bay, i.e., originating from the glacial erosion of Paleozoic carbonates from the area, the dolomitic component might have several origins (from Proterozoic and Paleozoic limestones in the Hudson Bay and Strait, to northwestern Baffin Island Paleozoic dolomite sources). The carbonate-rich layers are characterized by 234U/238U activity ratio <1 and more importantly, by very low initial 230Th excesses (230Thxs)0. Such low values indicate extremely fast deposition. An inventory of the (230Thxs)0 has been made based on 13 calibrated 14C ages and then used for interpolating duration ages for the H2 and H1. Estimated of 1.34 and 2.02 ka (vs 1.64 and 2.03 ka 14C), were respectively obtained. Another rapidly deposited layer of fine detrital carbonates-rich sediment yielded an age of about 8.3 ka, suggesting an assignment to the final drainage age of Lake Agassiz. Above this layer, high (230Thxs)0 values, but low (230Thxs)0-fluxes point to much reduced sedimentation rates and possibly focussing deeper slope during the Holocene.

Thermochronology of the Sulu ultrahigh-pressure metamorphic terrane: Implications for continental collision and lithospheric thinning

NASA Astrophysics Data System (ADS)

Liu, Li-Ping; Li, Zheng-Xiang; Danišík, Martin; Li, Sanzhong; Evans, Noreen; Jourdan, Fred; Tao, Ni

2017-08-01

The thermal history of the Dabie-Sulu orogenic belt provides important constraints on the collision process between the South China and North China blocks during the Mesozoic, and possible lithospheric thinning event(s) in the eastern North China Block. This study reports on the thermal evolution of the Sulu ultrahigh-pressure metamorphic (UHP) terrane using zircon U-Pb geochronology and multiple thermochronology methods such as mica and hornblende 40Ar/39Ar, zircon and apatite fission track, and zircon and apatite (U-Th)/He dating. 40Ar/39Ar and zircon (U-Th)/He data show that the UHP terrane experienced accelerated cooling during 180-160 Ma. This cooling event could be interpreted to have resulted from extensional unroofing of an earlier southward thrusting nappe, or, more likely, an episode of northward thrusting of the UHP rocks as a hanging wall. A subsequent episode of exhumation took place between ca. 125 Ma and 90 Ma as recorded by zircon (U-Th)/He data. This event was more pronounced in the northwest section of the UHP terrane, whereas in the southeast section, the zircon (U-Th)/He system retained Jurassic cooling ages of ca. 180-160 Ma. The mid-Cretaceous episode of exhumation is interpreted to have resulted from crustal extension due to the removal of thickened, enriched mantle. A younger episode of exhumation was recorded by apatite fission track and apatite (U-Th)/He ages at ca. 65-40 Ma. Both latter events were linked to episodic thinning of lithosphere along the Sulu UHP terrane in an extensional environment, likely caused by the roll-back of the Western Pacific subduction system.

Investigation into MIS 11 in the U.S. Great Basin Using Trace Elements and Stable Isotopes from two Lehman Caves Stalagmites

NASA Astrophysics Data System (ADS)

Neary, A.; McGee, D.; Tal, I.; Shakun, J. D.

2015-12-01

Marine Isotope Stage 11 (MIS 11) represents a long interglacial period of high temperatures and muted orbital variability that occurred around 424-374 kya, and is referred to as a 'super-interglacial'. MIS 11 is marked by especially pronounced high latitude warming in the Northern Hemisphere from 410-400 ka and thus presents a natural experiment for investigating the response of Great Basin precipitation to high latitude temperatures.MIS 11 is recorded by stalagmites LC3 and BT1 from Lehman Caves in Great Basin National Park, Nevada. LC3 represents 378-413 ka, while BT1 has a bottom age of 410 ka. Ongoing U-Th dating will refine chronologies from these samples. We will present stable isotope (δ13C and δ18O) and trace element (Mg/Ca and Sr/Ca) data from these stalagmites to study changes in precipitation recorded in them. Previous studies have shown a relationship between Mg/Ca, Sr/Ca, δ13C and prior calcite precipitation, and thus infiltration rates, in the cave system (Cross et al., 2015; Steponaitis et al., 2015). Meanwhile, δ18O has been shown to reflect larger scale atmospheric circulation.We will compare the records to previously published trace element and stable isotope data from more recent interglacials (Lachniet et al., 2014; Cross et al., 2015; Steponaitis et al., 2015) to test whether extensive high-latitude warming during MIS 11 was marked by anomalous precipitation patterns in the Great Basin. As they are coeval, we will also test the reproducibility between the stalagmites.References cited:Cross M., et al. (2015) Great Basin hydrology, paleoclimate, and connections with the North Atlantic: A speleothem stable isotope and trace element record from Lehman Caves, NV. Quaternary Science Reviews, in press.Steponaitis E., et al. (2015) Mid-Holocene drying the U.S. Great Basin recorded in Nevada speleothems. Quaternary Science Reviews, in press.Lachniet M. S., et al. (2014) Orbital control of western North America atmospheric circulation and climate over two glacial cycles. Nature Communications 5, 1-8.

Geochemistry of speleothem records from southern Illinois: Development of (234U)/(238U) as a proxy for paleoprecipitation

USGS Publications Warehouse

Zhou, Juanzuo; Lundstrom, C.C.; Fouke, B.; Panno, S.; Hackley, K.; Curry, B.

2005-01-01

Natural waters universally show fractionation of uranium series (U-series) parent-daughter pairs, with the disequilibrium between 234U and 238U (234U)/(238U) commonly used as a tracer of groundwater flow. Because speleothems provide a temporal record of geochemical variations in groundwater precipitating calcite, (234U)/(238U) variations in speleothems provide a unique method of investigating water-rock interaction processes over millennium time scales. We present high precision Thermal Ionization Mass Spectrometric (TIMS) U-series analyses of speleothems and drip waters from Fogelpole Cave in southern Illinois. Data from all speleothems from the cave show an inverse correlation between (234U)/(238U) and U concentration, following the pattern observed in groundwaters globally. Within a 65-cm-long stalagmite, concordant 234U-238 U-230Th and 235U-231Pa ages for 5 samples indicate accurate chronology from 78.5 ka to 30 ka. Notably, (234U)/(238U)o which differs from most speleothems by having (234U)/(238U)o <1, positively correlates with speleothem growth rate. We generalize this to the observation that speleothems globally show (234U)/ (238U)o deviating farther from secular equilibrium at lower growth rates and approaching secular equilibrium at higher grow rates. Based on the Fogelpole observations, we suggest that groundwater (234U)/(238U) is controlled by the U oxidation state, the U concentration of the water and the fluid velocity. A transport model whereby U-series nuclides react and exchange with mineral surfaces can reproduce the observed trend between growth rate and (234U)/(238U)o. Based on this result, we suggest that (234U)/(238U)o in speleothems may record changes in hydrologic flux with time and thus could provide a useful proxy for long term records of paleoprecipitation. ?? 2005 Elsevier B.V. All rights reserved.

Re-appraisal of the stratigraphy and determination of new U-Pb dates for the Sterkfontein hominin site, South Africa.

PubMed

Pickering, Robyn; Kramers, Jan D

2010-07-01

Sterkfontein Caves is the single richest early hominin site in the world with deposits yielding one or more species of Australopithecus and possible early Homo, as well as an extensive faunal collection. The inability to date the southern African cave sites accurately or precisely has hindered attempts to integrate the hominin fossil evidence into pan-African scenarios about human evolutionary history, and especially hominin biogeography. We have used U-Pb and U-Th techniques to date sheets of calcium carbonate flowstone inter-bedded between the fossiliferous sediments. For the first time, absolute age ranges can be assigned to the fossil-bearing deposits: Member 2 is between 2.8 +/- 0.28 and 2.6 +/- 0.30 Ma and Member 4 between 2.65 +/- 0.30 and 2.01 +/- 0.05 Ma. The age of 2.01 +/- 0.05 Ma for the top of Member 4 constrains the last appearance of Australopithecus africanus to 2 Ma. In the Silberberg Grotto we have reproduced the U-Pb age of approximately 2.2 Ma of for the flowstones associated with StW573. We believe that these deposits, including the fossil and the flowstones, accumulated rapidly around 2.2 Ma. The stratigraphy of the site is complex as sediments are exposed both in the underground chambers and at surface. We present a new interpretation of the stratigraphy based on surface mapping, boreholes logs and U-Pb ages. Every effort was made to retain the Member system, however, only Members 2 and 4 are recognized in the boreholes. We propose that the deposits formally known as Member 3 are in fact the distal equivalents of Member 4. The sediments of Members 2 and 4 consisted of cone-like deposits and probably never filled up the cave. The U-Th ages show that there are substantial deposits younger than 400 ka in the underground cave, underlying the older deposits, highlighting again that these cave fills are not simple layer-cakes.

Composite δ13C and petrographic 195-355 ka record from Frasassi cave (central Italy) stalagmites: investigating drivers of speleothem calcite carbon isotope signals.

NASA Astrophysics Data System (ADS)

Vanghi, V.; Borsato, A.; Frisia, S.; Drysdale, R.; Hellstrom, J. C.; Bajo, P.; Montanari, A.

2016-12-01

Carbon isotope ratio of speleothem calcite is known to be a proxy for climate-dependent soil CO2 production. One of the paradigms is that, ideally, C stable isotope incorporation occurred in equilibrium. Yet, the process of degassing in the cave commonly results in δ13C values more positive than theoretically expected for speleothems formed in temperate-humid settings. Fabrics then provide the benchmark to unravel local, regional and global significance of speleothem δ13C. The δ13C time-series from two precisely U-Th dated Frasassi stalagmites covering the interval from 195 ka to 355 ka (Marine Isotope Stages 7 - 10) were interpreted on the basis of the sequence of fabrics. Columnar fabrics indicated deposition under constant kinetic fractionation, whereby δ13C shifts through time reflected a combination of atmospheric CO2 concentration changes and soil efficiency variability, controlled by regional mean annual temperature. Given that the δ13C values are constantly more-positive-than-expected because of the effect of degassing, shifts to more positive δ13C values above a baseline of -7 permil during glacials are here interpreted as driven by low soil efficiency and higher contribution of atmospheric CO2 (Breecker et al. 2012, Borsato et al. 2015). The comparison of high resolution δ13C curves with atmospheric pCO2 and benthic δ18O records further suggests that hemispheric temperature changes driven by insolation modulated the δ13C shifts above or below the baseline. Thus, a -3‰ shift from glacial to interglacial at terminations IV and III is here ascribed to changes in atmospheric pCO2 (Schubert and Jahren 2012). More open fabrics mark warmer conditions and increased soil productivity and are associated with more negative δ13C. In conclusion, only by coupling petrography and geochemical properties the global and local drivers of δ13C anomalies in stalagmites from this deep cave could be distinguished. Borsato et al. (2015), Earth Surface Processes and Landforms 40 (9), 1158-1170. Breecker et al. (2012), Geochimica et Cosmochimica Acta 96 (1), 230-246. Schubert and Jahren (2012), Geochimica et Cosmochimica Acta 96, 29-43.

Low-threshold collinear parametric Raman comb generation in calcite under 532 and 1064 nm picosecond laser pumping

NASA Astrophysics Data System (ADS)

Smetanin, S. N.; Jelínek, M., Jr.; Kubeček, V.; Jelínková, H.

2015-09-01

Optimal conditions of low-threshold collinear parametric Raman comb generation in calcite (CaCO3) are experimentally investigated under 20 ps laser pulse excitation, in agreement with the theoretical study. The collinear parametric Raman generation of the highest number of Raman components in the short calcite crystals corresponding to the optimal condition of Stokes-anti-Stokes coupling was achieved. At the excitation wavelength of 1064 nm, using the optimum-length crystal resulted in the effective multi-octave frequency Raman comb generation containing up to five anti-Stokes and more than four Stokes components (from 674 nm to 1978 nm). The 532 nm pumping resulted in the frequency Raman comb generation from the 477 nm 2nd anti-Stokes up to the 692 nm 4th Stokes component. Using the crystal with a non-optimal length leads to the Stokes components generation only with higher thresholds because of the cascade-like stimulated Raman scattering with suppressed parametric coupling.

Ediacaran ( 620 Ma) high grade regional metamorphism in the northern Arabian Nubian Shield: U/Th-Pb monazite ages of the Elat schist

NASA Astrophysics Data System (ADS)

Elisha, Bar; Katzir, Yaron; Kylander-Clark, Andrew

2017-04-01

Ediacaran times witnessed a hemisphere-scale orogenesis forming the extensive Pan-African mountain ranges and resulting in the final assembly of Gondwana supercontinent. The Elat metamorphic basement (S Israel) located at the northernmost tip of a major Pan-African orogenic suture, the Arabian Nubian Shield (ANS), comprises amphibolite facies schists and gneisses and was most likely shaped by this major continental collision. However the timing, number and duration of metamorphic events in Elat and elsewhere in the ANS are non-conclusive and a major emphasis was given to pre-Ediacaran island-arc related tectonics. This is mostly because U-Pb dating of zircon, widely used in Elat and elsewhere, is very successful in constraining the ages of the igneous and sedimentary protoliths, but is 'blind' to metamorphism at grades lower than granulite. Here U/Th-Pb dating of monazite, a precise chronometer of metamorphic mineral growth, is systematically applied to the Elat schist and unveils the tectono-metamorphic evolution of the Elat basement. Previous U-Pb dating of detrital zircon has shown that the sedimentary protoliths of the Elat schist are the oldest basement components (≥800 Ma), and detailed structural observations of the schists portrayed a complex deformation history including four successive phases (Shimron, 1972). The earliest three phases were defined as ductile and penetrative, but some of the available geochronological data apparently contradict field relations. In-situ analysis of metamorphic monazites by LASS (Laser Ablation Split Stream) involves simultaneous measurement of U/Th-Pb isotope ratios and REE contents in a single 10 μm sized grain or domain, thus allowing determining the age of specific texture and metamorphic assemblage. Monazite dating of the Elat schist yielded two concordant age clusters at 712±6 and 613±5 Ma. The corresponding REE patterns of the dated monazite grains indicate that porphyroblast growth, either garnet or staurolite, took place only during the younger event (M2). Likewise the regional south dipping penetrative foliation, common to the Elat schist and to all of the rocks of the Elat association, formed during the Ediacaran event (M2). This profound event started at 630 Ma and reached peak conditions of mid amphibolite facies at 620 Ma. Retrogression and stress relaxation shortly followed, involving overprint of staurolite schists by a cordierite-bearing assemblage at 613 Ma (M3), and was contemporaneous with the intrusion of andesitic dykes that were immediately metamorphosed to low-amphibolite. This metamorphic P-T-t path corresponds to the collision of East- and West-Gondwana as constrained by large goechronological database of post collision batholiths from all around the Arabian-Nubian Shield.

ALPHA SPECTROMETRIC EVALUATION OF SRM-995 AS A POTENTIAL URANIUM/THORIUM DOUBLE TRACER SYSTEM FOR AGE-DATING URANIUM MATERIALS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beals, D.

2011-12-06

Uranium-233 (t{sub 1/2} {approx} 1.59E5 years) is an artificial, fissile isotope of uranium that has significant importance in nuclear forensics. The isotope provides a unique signature in determining the origin and provenance of uranium-bearing materials and is valuable as a mass spectrometric tracer. Alpha spectrometry was employed in the critical evaluation of a {sup 233}U standard reference material (SRM-995) as a dual tracer system based on the in-growth of {sup 229}Th (t{sub 1/2} {approx} 7.34E3 years) for {approx}35 years following radiochemical purification. Preliminary investigations focused on the isotopic analysis of standards and unmodified fractions of SRM-995; all samples were separatedmore » and purified using a multi-column anion-exchange scheme. The {sup 229}Th/{sup 233}U atom ratio for SRM-995 was found to be 1.598E-4 ({+-} 4.50%) using recovery-corrected radiochemical methods. Using the Bateman equations and relevant half-lives, this ratio reflects a material that was purified {approx} 36.8 years prior to this analysis. The calculated age is discussed in contrast with both the date of certification and the recorded date of last purification.« less

In-situ growth of calcite at Devils Hole, Nevada: Comparison of field and laboratory rates to a 500,000 year record of near-equilibrium calcite growth

USGS Publications Warehouse

Plummer, Niel; Busenberg, E.; Riggs, A.C.

2000-01-01

Calcite grew continuously for 500,000 years on the submerged walls of an open fault plane (Devils Hole) in southern Nevada, U.S.A. at rates of 0.3 to 1.3 mm/ka, but ceased growing approximately 60,000 years ago, even though the fault plane remained open and was continuously submerged. The maximum initial in-situ growth rate on pre-weighed crystals of Iceland spar placed in Devils Hole (calcite saturation index, SI, is 0.16 to 0.21 at 33.7??C) for growth periods of 0.75 to 4.5 years was 0.22 mm/ka. Calcite growth on seed crystals slowed or ceased following initial contact with Devils Hole groundwater. Growth rates measured in synthetic Ca-HCO3 solutions at 34??C, CO2 partial pressures of 0.101, 0.0156 (similar to Devils Hole groundwater) and 0.00102 atm, and SI values of 0.2 to 1.9 were nearly independent of P(CO)(2), decreased with decreasing saturation state, and extrapolated through the historical Devils Hole rate. The results show that calcite growth rate is highly sensitive to saturation state near equilibrium. A calcite crystal retrieved from Devils Hole, and used without further treatment of its surface, grew in synthetic Devils Hole groundwater when the saturation index was raised nearly 10-fold that of Devils Hole water, but the rate was only 1/4 that of fresh laboratory crystals that had not contacted Devils Hole water. Apparently, inhibiting processes that halted calcite growth in Devils Hole 60,000 years ago continue today.

In-situ growth of calcite at Devils Hole, Nevada--Comparison of field and laboratory rates to a 500,000 year record of near-equilibrium calcite growth

USGS Publications Warehouse

Plummer, Niel; Busenberg, Eurybiades; Riggs, Alan C.

2000-01-01

Calcite grew continuously for 500,000 years on the submerged walls of an open fault plane (Devils Hole) in southern Nevada, U.S.A. at rates of 0.3 to 1.3 mm/ka, but ceased growing approximately 60,000 years ago, even though the fault plane remained open and was continuously submerged. The maximum initial in-situ growth rate on pre-weighed crystals of Iceland spar placed in Devils Hole (calcite saturation index, SI, is 0.16 to 0.21 at 33.7 °C) for growth periods of 0.75 to 4.5 years was 0.22 mm/ka. Calcite growth on seed crystals slowed or ceased following initial contact with Devils Hole groundwater. Growth rates measured in synthetic Ca-HCO3 solutions at 34 °C, CO2 partial pressures of 0.101, 0.0156 (similar to Devils Hole groundwater) and 0.00102 atm, and SI values of 0.2 to 1.9 were nearly independent of PCO2, decreased with decreasing saturation state, and extrapolated through the historical Devils Hole rate. The results show that calcite growth rate is highly sensitive to saturation state near equilibrium. A calcite crystal retrieved from Devils Hole, and used without further treatment of its surface, grew in synthetic Devils Hole groundwater when the saturation index was raised nearly 10-fold that of Devils Hole water, but the rate was only 1/4 that of fresh laboratory crystals that had not contacted Devils Hole water. Apparently, inhibiting processes that halted calcite growth in Devils Hole 60,000 years ago continue today.

C and N Isotopes in Ostrich Eggshell as Proxies of Paleovegetation and Paleoprecipitation: Extraction, Preservation, and Application to Pleistocene Archaeological Samples

NASA Astrophysics Data System (ADS)

Niespolo, E. M.; Sharp, W. D.; Tryon, C. A.; Faith, J. T.; Miller, M.; Dawson, T. E.

2015-12-01

Paleoenvironmental change is commonly invoked as a factor in the development of modern human behaviors and the successful expansion of H. sapiens out of Africa, and paleoenvironmental information from archaeological sequences is central to addressing such questions. Ostrich eggshell (OES) are common in many African archaeological sequences and may be dated by 14C and U-series methods. In modern ratite eggshells (large flightless birds including the ostrich and emu), the δ13C in eggshell calcite and the δ13C and δ15N in eggshell organic fractions have been shown to vary systematically across climate gradients in South Africa and Australia with δ15N varying inversely with mean annual precipitation, and δ13C varying with the C isotopes of vegetation (1,2). Thus, if primary C and N isotopic signatures are preserved, assemblages of OES can provide dated records of paleovegetation and paleoprecipitation at archaeological sites. Since the C isotopic fractionation between calcite and eggshell organics is constant in modern OES (Δ13Ccalcite-organic = 14.7 ± 1.3‰) (3), evaluating that offset in ancient OES provides a test for preservation of primary isotopic signatures. Johnson et al. (3) showed that OES from Equus Cave (South Africa) retained the expected fractionation for up to 17 ka. We present a new protocol to extract C and N of OES organics for online analysis that preserves pristine δ13C and δ15N values and C and N contents. We find that using sodium hydroxide (NaOH), common to many bone collagen extraction procedures, destroys and degrades the organic component of OES, resulting in low C and N and altered δ13C and δ15N values. Analysis of a series of OES samples directly dated by 14C and U-series from the GvJm-22 rockshelter (Lukenya Hill, Kenya) (4,5) will demonstrate the first application of this protocol to OES from the last ~50,000 yr. 1. Johnson, B.J. et al. (1998) Geochim. Cosmochim. Acta 62, 2451-2461. 2. Newsome, S.D. et al. (2011) Oecologia 167, 1151-1162. 3. Johnson, B.J. et al. (1997) Palaeogeog. Palaeoclimatol. Palaeoecol. 136, 121-137. 4. Tryon, C.A. et al. (2015) PNAS 112, 2682-2687. 5. Sharp, W.D. et al. (2015) Abstract for AfQUA, Cape Town, South Africa.

Function of minerals in the natural radioactivity level of Vaigai River sediments, Tamilnadu, India--spectroscopical approach.

PubMed

Ramasamy, V; Paramasivam, K; Suresh, G; Jose, M T

2014-01-03

Using Gamma ray and Fourier Transform Infrared (FTIR) spectroscopic techniques, level of natural radioactivity ((238)U, (232)Th and (40)K) and mineralogical characterization of Vaigai River sediments have been analyzed with the view of evaluating the radiation risk and its relation to available minerals. Different radiological parameters are calculated to know the entire radiological characterization. The average of activity concentrations and all radiological parameters are lower than the recommended safety limit. However, some sites are having higher radioactivity values than the safety limit. From the FTIR spectroscopic technique, the minerals such as quartz, microcline feldspar, orthoclase feldspar, kaolinite, gibbsite, calcite, montmorillonite and organic carbon are identified and they are characterized. The extinction co-efficient values are calculated to know the relative distribution of major minerals such as quartz, microcline feldspar, orthoclase feldspar and kaolinite. The calculated values indicate that the amount of quartz is higher than orthoclase feldspar, microcline feldspar and much higher than kaolinite. Crystallinity index is calculated to know the crystalline nature of quartz and the result indicates that the presence of ordered crystalline quartz in the present sediment. The role of minerals in the level of radioactivity is assessed by multivariate statistical analysis (Pearson's correlation and Cluster analysis). The statistical analysis confirms that the clay mineral kaolinite is the major factor than other major minerals to induce the important radioactivity variables such as absorbed dose rate and concentrations of (232)Th and (238)U. Copyright © 2013 Elsevier B.V. All rights reserved.

New data on carbonatites of the Il'mensky-Vishnevogorsky alkaline complex, the southern Urals, Russia

NASA Astrophysics Data System (ADS)

Nedosekova, I. L.

2007-04-01

Carbonatites that are hosted in metamorphosed ultramafic massifs in the roof of miaskite intrusions of the Il’mensky-Vishnevogorsky alkaline complex are considered. Carbonatites have been revealed in the Buldym, Khaldikha, Spirikha, and Kagan massifs. The geological setting, structure of carbonatite bodies, distribution of accessory rare-metal mineralization, typomorphism of rock-forming minerals, geochemistry, and Sr and Nd isotopic compositions are discussed. Dolomite-calcite carbonatites hosted in ultramafic rocks contain tetraferriphlogopite, richterite, accessory zircon, apatite, magnetite, ilmenite, pyrrhotite, pyrite, and pyrochlore. According to geothermometric data and the composition of rock-forming minerals, the dolomite-calcite carbonatites were formed under K-feldspar-calcite, albite-calcite, and amphibole-dolomite-calcite facies conditions at 575-300°C. The Buldym pyrochlore deposit is related to carbonatites of these facies. In addition, dolomite carbonatites with accessory Nb and REE mineralization (monazite, aeschynite, allanite, REE-pyrochlore, and columbite) are hosted in ultramafic massifs. The dolomite carbonatites were formed under chlorite-sericite-ankerite facies conditions at 300-200°C. The Spirikha REE deposit is related to dolomite carbonatite and alkaline metasomatic rocks. It has been established that carbonatites hosted in ultramafic rocks are characterized by high Sr, Ba, and LREE contents and variable Nb, Zr, Ti, V, and Th contents similar to the geochemical attributes of calcio-and magnesiocarbonatites. The low initial 87Sr/86Sr = 0.7044-0.7045 and ɛNd ranging from 0.65 to -3.3 testify to their derivation from a deep mantle source of EM1 type.

Copper-nickel-rich, amalgamated ferromanganese crust-nodule deposits from Shatsky Rise, NW Pacific

USGS Publications Warehouse

Hein, J.R.; Conrad, T.A.; Frank, M.; Christl, M.; Sager, W.W.

2012-01-01

A unique set of ferromanganese crusts and nodules collected from Shatsky Rise (SR), NW Pacific, were analyzed for mineralogical and chemical compositions, and dated using Be isotopes and cobalt chronometry. The composition of these midlatitude, deep-water deposits is markedly different from northwest-equatorial Pacific (PCZ) crusts, where most studies have been conducted. Crusts and nodules on SR formed in close proximity and some nodule deposits were cemented and overgrown by crusts, forming amalgamated deposits. The deep-water SR crusts are high in Cu, Li, and Th and low in Co, Te, and Tl concentrations compared to PCZ crusts. Thorium concentrations (ppm) are especially striking with a high of 152 (mean 56), compared to PCZ crusts (mean 11). The deep-water SR crusts show a diagenetic chemical signal, but not a diagenetic mineralogy, which together constrain the redox conditions to early oxic diagenesis. Diagenetic input to crusts is rare, but unequivocal in these deep-water crusts. Copper, Ni, and Li are strongly enriched in SR deep-water deposits, but only in layers older than about 3.4 Ma. Diagenetic reactions in the sediment and dissolution of biogenic calcite in the water column are the likely sources of these metals. The highest concentrations of Li are in crust layers that formed near the calcite compensation depth. The onset of Ni, Cu, and Li enrichment in the middle Miocene and cessation at about 3.4 Ma were accompanied by changes in the deep-water environment, especially composition and flow rates of water masses, and location of the carbonate compensation depth.

Applications of detrital geochronology and thermochronology from glacial deposits to the Paleozoic and Mesozoic thermal history of the Ross Embayment, Antarctica

NASA Astrophysics Data System (ADS)

Welke, Bethany; Licht, Kathy; Hennessy, Andrea; Hemming, Sidney; Pierce Davis, Elizabeth; Kassab, Christine

2016-07-01

Till from moraines at the heads of six major outlet glaciers in the Transantarctic Mountains (TAM) and from till beneath three West Antarctic ice streams have a ubiquitous zircon U-Pb age population spanning the time of the Ross/Pan-African Orogenies (610-475 Ma). Geochronology and thermochronology of detrital minerals in these Antarctic glacial tills reveal two different thermal histories for the central and southern TAM. Double-dating of the zircons reveals a geographically widespread (U-Th)/He (ZHe) population of 180-130 Ma in most of the till samples. Sandstone outcrops at Shackleton Glacier, and three Beacon Supergroup sandstone clasts from three moraines, have ZHe ages that fall entirely within this range. The similar population and proximity of many of the till samples to Beacon outcrops lead us to suggest that this extensive ZHe population in the tills is derived from Beacon Supergroup rocks and reflects the thermal response of the Beacon Basin to the breakup of Gondwana. A second population of older (>200 Ma) ZHe ages in tills at the head of Byrd, Nimrod, and Reedy Glaciers. For the tills at the head of the Nimrod and Byrd Glaciers, integrating the double-dated zircon results with 40Ar/39Ar of hornblende, muscovite and biotite, and U-Pb and (U-Th-Sm)/He double-dates on apatite yields a typical pattern of early rapid orogenic cooling (˜4-10°C/Myr) 590-475 Ma after the emplacement of the Granite Harbour Intrusives. Low temperature thermochronometers at these sites yield variable but quite old ages (ZHe 480-70 Ma and AHe 200-70 Ma) that require a long history at low temperature.

Fluids along the North Anatolian Fault, Niksar basin, north central Turkey: Insight from stable isotopic and geochemical analysis of calcite veins

NASA Astrophysics Data System (ADS)

Sturrock, Colin P.; Catlos, Elizabeth J.; Miller, Nathan R.; Akgun, Aykut; Fall, András; Gabitov, Rinat I.; Yilmaz, Ismail Omer; Larson, Toti; Black, Karen N.

2017-08-01

Six limestone assemblages along the North Anatolian Fault (NAF) Niksar pull-apart basin in northern Turkey were analyzed for δ18OPDB and δ13CPDB using bulk isotope ratio mass spectrometry (IRMS). Matrix-vein differences in δ18OPDB (-2.1 to 6.3‰) and δ13CPDB (-0.9 to 4.6‰) suggest a closed fluid system and rock buffering. Veins in one travertine and two limestone assemblages were further subjected to cathodoluminescence, trace element (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) and δ18OPDB (Secondary Ion Mass Spectrometry, SIMS) analyses. Fluid inclusions in one limestone sample yield Th of 83.8 ± 7.3 °C (±1σ, mean average). SIMS δ18OPDB values across veins show fine-scale variations interpreted as evolving thermal conditions during growth and limited rock buffering seen at a higher-resolution than IRMS. Rare earth element data suggest calcite veins precipitated from seawater, whereas the travertine has a hydrothermal source. The δ18OSMOW-fluid for the mineralizing fluid that reproduces Th is +2‰, in range of Cretaceous brines, as opposed to negative δ18OSMOW-fluid from meteoric, groundwater, and geothermal sites in the region and highly positive δ18OSMOW-fluid expected for mantle-derived fluids. Calcite veins at this location do not record evidence for deeply-sourced metamorphic and magmatic fluids, an observation that differs from what is reported for the NAF elsewhere along strike.

76 FR 67019 - Eighty-Seventh: RTCA Special Committee 159: Global Positioning System (GPS)

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-28

... Committee 159: Global Positioning System (GPS) 87th meeting. DATES: The meeting will be held November 14-18... Committee 159, Global Positioning System (GPS). The agenda will include the following: November 14-17, 2011... Committee 159: Global Positioning System (GPS) AGENCY: Federal Aviation Administration (FAA), U.S...

230Th-234U Model-Ages of Some Uranium Standard Reference Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, R W; Gaffney, A M; Kristo, M J

The 'age' of a sample of uranium is an important aspect of a nuclear forensic investigation and of the attribution of the material to its source. To the extent that the sample obeys the standard rules of radiochronometry, then the production ages of even very recent material can be determined using the {sup 230}Th-{sup 234}U chronometer. These standard rules may be summarized as (a) the daughter/parent ratio at time=zero must be known, and (b) there has been no daughter/parent fractionation since production. For most samples of uranium, the 'ages' determined using this chronometer are semantically 'model-ages' because (a) some assumptionmore » of the initial {sup 230}Th content in the sample is required and (b) closed-system behavior is assumed. The uranium standard reference materials originally prepared and distributed by the former US National Bureau of Standards and now distributed by New Brunswick Laboratory as certified reference materials (NBS SRM = NBL CRM) are good candidates for samples where both rules are met. The U isotopic standards have known purification and production dates, and closed-system behavior in the solid form (U{sub 3}O{sub 8}) may be assumed with confidence. We present here {sup 230}Th-{sup 234}U model-ages for several of these standards, determined by isotope dilution mass spectrometry using a multicollector ICP-MS, and compare these ages with their known production history.« less

A Millennial Record of Rainfall And ENSO Variability in Stalagmites From a Mid-Ocean Island in the South Pacific

NASA Astrophysics Data System (ADS)

Aharon, P.; Rasbury, M. S.; Lambert, W. J.; Ghaleb, B.; Lambert, L.

2005-12-01

Improved understanding of ocean-atmosphere interactions that control interdecadal ENSO variability prompted recently a renewed interest in the acquisition of highly resolved proxy ENSO records. Corals possessing annual growth increments have extended the ENSO archive several centuries beyond the existing instrumental data but much longer records are needed to constrain the interdecadal periodicities and unravel their underlying causes. To this end, paleoclimate proxies archived in stalagmites from tropical Pacific settings have not been harnessed to the task of ENSO paleo-reconstructions although stalagmites elsewhere have offered valuable paleoclimate insights. Here we report the results of an investigation of stalagmites from a water-table cave on Niue Island in the South Pacific (19o 00' S; 169o 50' W) located at the epicenter of oceanic ENSO. Century-long instrumental records on Niue provide a frame of reference and indicate that the interannual and interdecadal air temperature variability is negligible but the rainfall is fully engaged in the wheels of ENSO such that El-Niño and La-Niña events correspond with droughts and abundant rainfall, respectively. Seasonal monsoon and trade rainfalls exhibit a marked contrast in their oxygen isotope compositions. Rainfall amount governs microbial soil activities resulting in convergent 18O and 13C depletions and enrichments in the drips that are transferred to the calcite stalagmites in the Niuean caves. A detailed study of four actively growing stalagmites whose chronology overlaps with the instrumental records confirms that interannual and decadal-scale ENSO variability is clearly expressed in the annual couplets widths and stable oxygen and carbon isotope time-series records of continuous layered stalagmites. Acquisition of a chronology for USM1 stalagmite posed radiometric dating challenges. The U concentration, in the range of 44.2 to 97.5 ppb, is relatively low by comparison with typical stalagmite values. Therefore dating by 230Th/234U method was impractical considering the youthfulness of the stalagmite and the amount of available material. Three dating techniques were used to derive a robust chronology: (i) 226Ra/234U by TIMS; (ii) radiocarbon by AMS, and (iii) couplets counting. In conjunction, the three dating methods indicate that the 160 mm stalagmite section spans a time interval from 1540 to 360 years AD. Interannual and interdecadal-scale variability are the largest components of variance in the millennial-long oxygen isotope time series. Processed in the frequency domain to quantify the variance, the data yield mean periodicities of 5.5 yrs and 30 yrs thus matching modern interannual ENSO and interdecadal IPO periodicity bands. Importantly, previously unidentified cycles of about 200 yrs and 500years duration are clearly discerned in both the oxygen and carbon isotope records. The low frequency cycles exhibit phase alternations between strong ENSO events manifested in severe droughts that are succeeded by rare ENSO events and abundant rainfall. Phase transitions occurred at about 1500, 1300, 1100, 900 and 500 yrs AD. The new millennial record of ENSO offers valuable data of interest to the climate dynamics community investigating the factors controlling ENSO variability through time.

Coupled dissolution-precipitation in natural monazite: effect of irradiation damage or fluid mediation?

NASA Astrophysics Data System (ADS)

Seydoux-Guillaume, Anne-Magali; Montel, Jean-Marc; de Parseval, Philippe; Bingen, Bernard; Janots, Emilie

2010-05-01

The LREE orthophosphate monazite is a common accessory mineral, important as a U-Th-Pb geochronometer in both metamorphic and magmatic rocks. In order to correctly interpret measured ages, it is essential to properly understand mechanisms that control them. Few studies have shown that coupled dissolution-crystallisation in the presence of a fluid phase is a mechanism incomparably more efficient that solid state diffusion to reset isotopic signature within monazite grains. It is known that dissolution-precipitation is efficiency enhanced by the presence of defects within crystals. Because of its high actinide contents (U and Th), monazite receives intense self-irradiation doses. In contrast to zircon (a silicate), monazite (a phosphate) is less sensitive to irradiation. Natural amorphous monazite has never been reported and the only proof that monazite lattice was destroyed by irradiation is shown by the presence of lattice distortion (strained lattice); this is because defect healing is more efficient than amorphization. The present study focuses on large (cm) single monazite crystals from five distinct localities in Norway, Madagascar, Srilanka, Zwaziland and Morefield. They have different chemical compositions, especially with regard to U, Th and Pb contents, and have ages ranging from ca. 500 to 1000 Ma. Nevertheless, all of them share the same petrographic features. Optical microscope and SEM images reveal variably intense fracturation. BSE imaging in the SEM indicates that monazite is composed of multiple phases: an unaltered monazite (Mnz1) + an altered monazite (Mnz2) associated with Th-rich phase (Thorium silicate or Thorium oxide) +/- Xenotime, depending on the initial composition of Mnz1. Analogous textures were already described by Seydoux-Guillaume et al. (2007) and Hetherington and Harlov (2008;). The alteration textures are always associated with radial cracks emanating from the high radioactive phase (Th-rich phase). The question addressed in the discussion is the role and the chronology of each process, i.e. irradiation vs coupled dissolution-precipitation. U-Th-Pb ages obtained by chemical dating on electron microprobe from altered and unaltered monazites show no significant differences. Therefore U-Pb dating using SIMS and LA-ICP-MS are in progress to determine precise isotopic age that would refine the alteration chronology. Finally, these results will be compared with experimental work, which are currently investigating the role of structural defects on coupled dissolution-precipitation in monazite. Hetherington and Harlov (2008). Am. Mineral., 93, 806-820. Seydoux-Guillaume et al. (2007). Eur. J. Mineral., 19, 7-14.

The U/Th production ratio and the age of the Milky Way from meteorites and Galactic halo stars.

PubMed

Dauphas, Nicolas

2005-06-30

Some heavy elements (with atomic number A > 69) are produced by the 'rapid' (r)-process of nucleosynthesis, where lighter elements are bombarded with a massive flux of neutrons. Although this is characteristic of supernovae and neutron star mergers, uncertainties in where the r-process occurs persist because stellar models are too crude to allow precise quantification of this phenomenon. As a result, there are many uncertainties and assumptions in the models used to calculate the production ratios of actinides (like uranium-238 and thorium-232). Current estimates of the U/Th production ratio range from approximately 0.4 to 0.7. Here I show that the U/Th abundance ratio in meteorites can be used, in conjunction with observations of low-metallicity stars in the halo of the Milky Way, to determine the U/Th production ratio very precisely (0.57(+0.037)(-0.031). This value can be used in future studies to constrain the possible nuclear mass formulae used in r-process calculations, to help determine the source of Galactic cosmic rays, and to date circumstellar grains. I also estimate the age of the Milky Way (14.5(+2.8)(-2.2)Gyr in a way that is independent of the uncertainties associated with fluctuations in the microwave background or models of stellar evolution.

New precise dates for the ancient and sacred coral pyramidal tombs of Leluh (Kosrae, Micronesia).

PubMed

Richards, Zoe T; Shen, Chuan-Chou; Hobbs, Jean-Paul A; Wu, Chung-Che; Jiang, Xiuyang; Beardsley, Felicia

2015-03-01

Monumental tombs within ancient civilizations worldwide hold precious clues for deciphering the architectural skill, acumen, and industry of prehistoric cultures. Most tombs were constructed from abiotic materials-stone, soil, and/or clay, predominately-and were built to permanently inter royalty or high-status individuals. On the island of Kosrae in the central Pacific, monumental tombs were constructed with scleractinian coral and were confined to the prehistoric island capital of Leluh, where they served as temporary mortuary processing points. Like other prehistoric tombs, the Leluh tombs were dated by association-from the remnants of the temporarily interred. We present new dates for three sacred tombs using high-precision U-Th dates from 24 corals collected directly from the structural materials. The results suggest that the tombs were built about 700 years ago during the 14th century, about three centuries earlier than previously reported. The new dates redefine the peak occupation of Leluh and place its ruling paramountcy at the leading edge of the developing trans-oceanic political hierarchies, as well as the social and economic systems that dominated the civilizations in this part of the world.

The sunstone and polarised skylight: ancient Viking navigational tools?

NASA Astrophysics Data System (ADS)

Ropars, Guy; Lakshminarayanan, Vasudevan; Le Floch, Albert

2014-10-01

Although the polarisation of the light was discovered at the beginning of the nineteenth century, the Vikings could have used the polarised light around the tenth century in their navigation to America, using a 'sunstone' evoked in the Icelandic Sagas. Indeed, the birefringence of the Iceland spar (calcite), a common crystal in Scandinavia, permits a simple observation of the axis of polarisation of the skylight at the zenith. From this, it is possible to guess the azimuth of a hidden Sun below the horizon, for instance. The high sensitivity of the differential method provided by the ordinary and extraordinary beams of calcite at its so-called isotropy point is about two orders higher than that of the best dichroic polariser and permits to reach an accuracy of ±1° for the Sun azimuth (at sunrise and sunset). Unfortunately, due to the relative fragility of calcite, only the so-called Alderney crystal was discovered on board a 16th ancient ship. Curiously, beyond its use as a sunstone by the Vikings, during these last millennia calcite has led to the discovery of the polarisation of the light itself by Malus and is currently being used to detect the atmospheres of exoplanets. Moreover, the differential method for the light polarisation detection is widely used in the animal world.

Deciphering the post-cratonization history of the Kaapvaal craton, South Africa from titanite and zircon (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Baughman, J. S.; Flowers, R. M.

2017-12-01

Cratons are the most stable portions of continents, but the degree to which they are affected by post-cratonization tectonic and magmatic processes is unclear. Complete time-temperature (t-T) histories are necessary to understand the timing, extent, and characteristics of post-cratonization events that disrupted these regions. However, deciphering extended cratonic t-T records is difficult owing to the incomplete stratigraphic records of continental interior settings, and the challenge of accessing the appropriate thermal history range with conventional thermochronometers. The Kaapvaal craton in South Africa is an archetypal craton that initially stabilized in the Archean and was subsequently affected by magmatic and marginal accretionary events. Here we exploit titanite and zircon (U-Th)/He (THe, ZHe) thermochronology to better decipher the somewhat cryptic Proterozoic through early Paleozoic history of the craton. Radiation damage effects on the He diffusivity of these two minerals provides the potential to access a wide temperature window from 200°C to near surface conditions. Existing low-temperature apatite (U-Th)/He and fission-track results constrain Late Paleozoic to Mesozoic burial of the Karoo basin and subsequent Cretaceous unroofing, while 40Ar/39Ar and Rb-Sr data document cooling through temperatures of 300°C by 2 Ga. We obtained THe and ZHe dates from across the northern Kaapvaal craton to fill in the thermal history gap between these constraints. THe and ZHe dates range from 1200 to 200 Ma, and 1000 to 30 Ma, respectively. Both sets of dates are negatively correlated with effective uranium concentration (eU), manifesting the effect of radiation damage on the He retentivity, and therefore closure temperature, of these minerals. The results allow us to assess the Mesoproterozoic through present day thermal history of the northern Kaapvaal craton. The THe data suggest that Mesoproterozoic exhumation and large-scale reheating associated with Namaqua-Natal orogenesis affected the region. While, the ZHe data constrain maximum burial temperatures during Mesozoic Karoo burial. Together the results show the power of exploiting thermochronologic advances to access new information about long-term continental evolution.

Quantifying weathering advance rates in basaltic andesite rinds with uranium-series isotopes: a case study from Guadeloupe

NASA Astrophysics Data System (ADS)

Ma, L.; Chabaux, F. J.; Pelt, E.; Granet, M.; Sak, P. B.; Gaillardet, J.; Brantley, S. L.

2010-12-01

Weathering of basaltic rocks plays an important role in many Earth surface processes. It is thus of great interest to quantify their weathering rates. Because of their well-documented behaviors during water-rock interaction, U-series isotopes have been shown to have utility as a potential chronometer to constrain the formation rates of weathering rinds developed on fresh basaltic rocks. In this study, U-series isotopes and trace element concentrations were analyzed in a basaltic andesite weathering rind collected from the Bras David watershed, Guadeloupe. From the clast, core and rind samples were obtained by drilling along a 63.8 mm linear profile across a low curvature segment of the core-rind boundary. Trace element concentrations reveal: significant loss of REE, Y, Rb, Sr, and Ba in the weathering rind; conservative behaviors of Ti and Th; and external addition of U into the rind during clast weathering. Measured (234U/238U) activity ratios of the rind samples are much higher than the core samples and show excess 234U. Measured (238U/232Th) and (230Th/232Th) activity ratios of the core and rind samples increase gradually from the core into the weathering rind. The observed depletion profiles for the trace elements in the clast suggest that the earliest chemical reaction that creates significant porosity is dissolution of plagioclase, consistent with the previous study [Sak et al., 2010, CG, in press]. The porosity growth within the rind allows for an influx of soil solution that carries dissolved U with (234U/238U) activity ratios >1 into the clast. The deposition of U in the rind is most likely associated with precipication of secondary minerals during clast weathering. Such a continuous U addition is responsible for the observed gradual increase of (238U/232Th) activity ratios in the rind. Subsequent production of 230Th in the rind over time from the decay of excess 234U accounts for the observed continuous increase of (230Th/232Th) activity ratios. The U-series activity ratios in the clast were modeled with a weathering advance rate of ~0.3 mm kyr-1. This represents the rind advance rate at the low curvature segment of the core-rind boundary under tropical climate. This rate is consistent with the previously estimated formation rates of basaltic rinds under similar tropic conditions in Costa Rica [Sak et al., 2004, GCA 68, 1453; Pelt et al., 2008, EPSL 276, 98]. This rate is about one order of magnitude greater than those in temperate regions, documenting the important control of temperature on basalt weathering. This work illustrates that the weathering advance rates of rinds can be successfully estimated by U-series isotopes, demonstrating their great potential as dating tools for Earth surface processes. Furthermore, U-series chronometry provides a suitable method for independently testing the hypothesis that rind advance rates around an individual clast increase with increasing interfacial curvature.

Trace element abundances in major minerals of Late Permian coals from southwestern Guizhou province, China

USGS Publications Warehouse

Zhang, Jiahua; Ren, D.; Zheng, C.; Zeng, R.; Chou, C.-L.; Liu, J.

2002-01-01

Fourteen samples of minerals were separated by handpicking from Late Permian coals in southwestern Guizhou province, China. These 14 minerals were nodular pyrite, massive recrystallized pyrite, pyrite deposited from low-temperature hydrothermal fluid and from ground water; clay minerals; and calcite deposited from low-temperature hydrothermal fluid and from ground water. The mineralogy, elemental composition, and distribution of 33 elements in these samples were studied by optical microscopy, scanning electron microscope equipped with energy-dispersive X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), cold-vapor atomic absorption spectrometry (CV-AAS), atomic fluorescence spectrometry (AFS), inductively coupled-plasma mass spectrometry (ICP-MS), and ion-selective electrode (ISE). The results show that various minerals in coal contain variable amounts of trace elements. Clay minerals have high concentrations of Ba, Be, Cs, F, Ga, Nb, Rb, Th, U, and Zr. Quartz has little contribution to the concentration of trace elements in bulk coal. Arsenic, Mn, and Sr are in high concentrations in calcite. Pyrite has high concentrations of As, Cd, Hg, Mo, Sb, Se, Tl, and Zn. Different genetic types of calcite in coal can accumulate different trace elements; for example Ba, Co, Cr, Hg, Ni, Rb, Sn, Sr, and Zn are in higher concentrations in calcite deposited from low-temperature hydrothermal fluid than in that deposited from ground water. Furthermore, the concentrations of some trace elements are quite variable in pyrite; different genetic types of pyrites (Py-A, B, C, D) have different concentrations of trace elements, and the concentrations of trace elements are also different in pyrite of low-temperature hydrothermal origin collected from different locations. The study shows that elemental concentration is rather uniform in a pyrite vein. There are many micron and submicron mosaic pyrites in a pyrite vein, which is enriched in some trace elements, such as As and Mo. The content of trace element in pyrite vein depends upon the content of mosaic pyrite and of trace elements in it. Many environmentally sensitive trace elements are mainly contained in the minerals in coal, and hence the physical coal cleaning techniques can remove minerals from coal and decrease the emissions of potentially hazardous trace elements. ?? 2002 Elsevier Science B.V. All rights reserved.

Clinical Study of Resuscitative Endovascular Balloon Occlusion of the Aorta (REBOA) for Severe Pelvic Fracture and Intra-Abdominal Hemorrhagic Shock Using Continuous Vital Signs

DTIC Science & Technology

2017-03-01

University of Maryland, Baltimore Baltimore, MD 21201 REPORT DATE: March 2017 TYPE OF REPORT: Annual PREPARED FOR: U.S. Army Medical Research ...ongoing. After FDA approval of a new novel REBOA catheter (ER-REBOATM (Prytime Medical , Boerne, TX )) in October 2015, we incorporated this catheter into...Scalea, MD 39th Annual CONFERENCE ON SHOCK – June 11-14th, Austin , TX 2. REBOA IMPROVES MEAN BLOOD PRESSURE (MBP) AND SHOCK INDEX (SI) AS MEASURED

Petrography, fluid inclusion and isotope studies in Ordovician carbonate reservoirs in the Shunnan area, Tarim basin, NW China: Implications for the nature and timing of silicification

NASA Astrophysics Data System (ADS)

Lu, Ziye; Chen, Honghan; Qing, Hairuo; Chi, Guoxiang; Chen, Qianglu; You, Donghua; Yin, Hang; Zhang, Siyang

2017-08-01

The Shunnan (SN) area, located in the center of the Tarim basin, NW China, is a gas field discovered in 2013, where the gas is hosted from deeply buried Ordovician carbonate reservoirs with burial depth > 6000 m and temperature > 190 °C. The most important reservoir rocks in the SN area are silicified limestones, which are characterized by multiple generations/types of authigenic quartz (Qz1-Qz2) and coarse calcite cement (CC1-CC3), in addition to other diagenetic phases. Qz1 is a replacement quartz postdating burial stylolites in both limestone and strongly silicified limestone, and Qz2 are equant and bladed quartz cements developed in fractures or vugs in strongly silicified limestone, also postdating burial stylolite. CC1 is a coarse calcite cement found in the vugs, which postdates medium crystalline dolomite and predates saddle dolomite. CC2 (including CC2a, CC2b and CC2c) is the calcite postdating Qz1 and burial stylolites. CC2a is found in fractures in limestone or slightly silicified limestone. CC2b, CC2c and CC3 are only identified in strongly silicified limestone. CC2b fills intercrystalline pores of Qz1, and CC2c fills fractures, predating Qz2. CC3 is precipitated in remaining space left by Qz2c in fractures or vugs. Sr isotopes were analyzed in CC2a and CC2c. CC2a has 87Sr/86Sr ratios of 0.70890-0.70917. CC2c is characterized with 87Sr/86Sr ratios of 0.70949-0.70972. Fluid inclusions were studied in all the quartz and coarse calcite cements. Fluid inclusions in CC2a are characterized by Th values of 118-131 °C and salinities of 22.9-25.2 wt% NaCl + CaCl2. Fluid inclusions from Qz2a, Qz2b, CC2b and CC2c have Th values of 143-166 °C and salinities of 14.7-23.7 wt% NaCl + CaCl2. Fluid inclusions in Qz2c are characterized by Th values of 125-132 °C and salinities of 24.8-26.8 wt% NaCl + CaCl2, and those in CC3 by Th values of 86-101 °C and salinities of 22.9-25.2 wt% NaCl + CaCl2. The Th drop, from Qz2a, Qz2b and CC2c to Qz2c and CC3, cannot be explained by normal burial diagenesis, suggesting a hydrothermal event associated with the main phase of silicification. The relatively low temperature recorded by CC3 implies that the hydrothermal event possibly took place in the Devonian rather than Permian as previously thought.

Episodic Holocene eruption of the Salton Buttes rhyolites, California, from paleomagnetic, U-Th, and Ar/Ar dating

USGS Publications Warehouse

Wright, Heather M.; Vazquez, Jorge A.; Champion, Duane E.; Calvert, Andrew T.; Mangan, Margaret T.; Stelten, Mark E.; Cooper, Kari M.; Herzig, Charles; Schriener Jr., Alexander

2015-01-01

In the Salton Trough, CA, five rhyolite domes form the Salton Buttes: Mullet Island, Obsidian Butte, Rock Hill, North and South Red Hill, from oldest to youngest. Results presented here include 40Ar/39Ar anorthoclase ages, 238U-230Th zircon crystallization ages, and comparison of remanent paleomagnetic directions with the secular variation curve, which indicate that all domes are Holocene. 238U-230Th zircon crystallization ages are more precise than but within uncertainty of 40Ar/39Ar anorthoclase ages, suggesting that zircon crystallization proceeded until shortly before eruption in all cases except one. Remanent paleomagnetic directions require three eruption periods: (1) Mullet Island, (2) Obsidian Butte, and (3) Rock Hill, North Red Hill, and South Red Hill. Borehole cuttings logs document up to two shallow tephra layers. North and South Red Hills likely erupted within 100 years of each other, with a combined 238U-230Th zircon isochron age of: 2.83 ± 0.60 ka (2 sigma); paleomagnetic evidence suggests this age predates eruption by hundreds of years (1800 cal BP). Rock Hill erupted closely in time to these eruptions. The Obsidian Butte 238U-230Th isochron age (2.86 ± 0.96 ka) is nearly identical to the combined Red Hill age, but its Virtual Geomagnetic Pole position suggests a slightly older age. The age of aphyric Mullet Island dome is the least well constrained: zircon crystals are resorbed and the paleomagnetic direction is most distinct; possible Mullet Island ages include ca. 2300, 5900, 6900, and 7700 cal BP. Our results constrain the duration of Salton Buttes volcanism to between ca. 5900 and 500 years.

Zircon-pyrochlore ores of Proterozoic Gremyakha-Vyrmes polyphase massif, Kola Peninsula: source and evolution

NASA Astrophysics Data System (ADS)

Sorokhtina, Natalia; Belyatsky, Boris; Antonov, Anton; Kononkova, Natalia; Lepekhina, Elena; Kogarko, Lia

2017-04-01

The alkaline-ultrabasic Gremyakha-Vyrmes massif occurs within the Central Kola terrane in the northern part of the Fennoscandian Shield and consists of diverse rock complexes: basic-ultrabasic rocks, foidolites, alkaline metasomatic rocks and carbonatites, alkaline granites and granosyenites. Nb-Zr ore deposit is confined to alkaline metasomatic rocks developed over foidolites. The metasomatites are represented by albitites and aegirinites occur as submeridionally orientated zones extending up to 6-8 km and several hundred meters thickness. They are mainly composed of albite and aegirine, but amphibole, annite, microcline, fluorapatite, titanite, ilmenite, pyrochlore group minerals, zircon are present [Sorokhtina et al., 2016]. Carbonatites are developed sporadically and accessory zircon but not the pyrochlore is observed only in contact zones with albitites and aegerinites. In metasomatites, zircon and pyrochlore are main rare metal minerals, which are formed at the latest stages of crystallization. Ca-dominant fluorcalcio- and hydroxycalciopyrochlores are the most abundant, whereas U-dominant pyrochlore, oxyuranobetafite, zero-valent-dominant (Ba, Sr-dominant) pyrochlore, hydro- or kenopyrochlore are rare. The pyrochlore-group minerals form heterogeneous metacrystals containing inclusions of host rock minerals, calcite, ilmenite, zircon, sulfides, and graphite. While pyrochlore is replaced by Si-rich "pyrochlore" (SiO2 is up to 18 wt.%.), cation-deficient hydrated pyrochlore, Fe-Si-Nb, U-Si-Nb, and Al-Si-Nb phases along fracture zones and margins. The early generation zircon is represented by large heterogeneous metacrystals filled with inclusions of various host rock minerals, calcite, ilmenite, thorite, thorianite and sulfides, while the late zircons are empty of inclusions. Zircons are nearly stoichiometric in composition; but intermediate zones are enriched in Pb, Y and Th, and overgrowths are enriched Hf only. According to CL and ion-microprobe analysis zircon has polygenetic nature: some relics inherited from foidolite crystallized at about 800°C, whereas the newly formed - at 600°C [Watson et al., 2006]. The time interval of the magmatic massif formation may be estimated as long as 80-100 Ma only. The basic-ultrabasic rocks and foidolites were intruded consistently at 1982 ± 6 Ma and 1894±12 according to SHRIMP-II U-Pb zircon dating, but the whole-rock Sm-Nd isotope dating has resulted in 1879±99 Ma and reflects the impact of alkaline granite intrusion (1871±9 Ma). The late differentiates from alkaline magma crystallization were the main source of rare metals for zircon-pyrochlore ores of alkaline metasomatites. The metasomatic rocks (aegirinites, albitites) and carbonatites were formed as late as 1910 ± 15 Ma (SHRIMP-II U-Pb zircon, titanite, pyrochlore). While some pyrochlore grains from metasomatites are showed that U-Pb age of ore formation is 1766 ± 24 and 1764 ± 19 respectively. That can be attributed to additional source of rare metals connected with fluids formed during regional metamorphism 1750 m.y. ago [Glebovitskii et al., 2014]. The last probable source of rare-metal material and ore-deposit evolution stage (recrystallization) is established by individual pyrochlore grain Sm-Nd and U-Pb systems and evidences tectono-thermal activity at the Paleozoic plume magmatism, which was followed by structural and chemical mineral changes. The research was done within the framework of the scientific program of Russian Academy of Sciences and state contract K41.2014.014 with Sevzapnedra. References: Watson E. B., Wark D. A., Thomas J. B. Crystallization thermometers for zircon and rutile // Contrib. Mineral. Petrol. 2006. 151, 413-433. Glebovitskii V.A., Bushmin S.A., Belyatsky B.V., Bogomolov E.S., Borozdin A.P., Savva E.V., Lebedeva Y.M. Rb-Sr age of metasomatism and ore formation in the low-temperature shear zones of the Fenno-Karelian craton, Baltic Shield // Petrology. 2014. 22(2). 184-204. Sorokhtina N.V., Kogarko L.N., Shpachenko A.K., Senin V. G. Composition and Conditions of Crystallization of zircon from the rare-metal ores of the Gremyakha-Vyrmes massif, Kola Peninsula // Geochemistry International. 2016. 54 (12). 1035-1048.

ESR dating of barite in sulphide deposits formed by the sea-floor hydrothermal activities.

PubMed

Toyoda, Shin; Fujiwara, Taisei; Uchida, Ai; Ishibashi, Jun-ichiro; Nakai, Shun'ichi; Takamasa, Asako

2014-06-01

Barite is a mineral newly found to be practically useful for electron spin resonance (ESR) dating of sulphide deposits formed by the sea-floor hydrothermal activities. The recent studies for the properties of the ESR dating signal in barite are summarised in the present paper as well as the formulas for corrections for accurate dose-rate estimation are developed including the dose-rate conversion factors, shape correction for gamma-ray dose and decay of (226)Ra. Although development of the techniques for ESR dating of barite has been completed, further comparative studies with other dating techniques such as U-Th and (226)Ra-(210)Pb dating are necessary for the technique to be widely used. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

A simple, gravimetric method to quantify inorganic carbon in calcareous soils

USDA-ARS?s Scientific Manuscript database

Total carbon (TC) in calcareous soils has two components: inorganic carbon (IC) as calcite and or dolomite and organic carbon (OC) in the soil organic matter. The IC must be measured and subtracted from TC to obtain OC. Our objective was to develop a simple gravimetric technique to quantify IC. Th...

Bricks in historical buildings of Toledo City: characterisation and restoration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez-Arce, Paula; Garcia-Guinea, Javier; Gracia, Mercedes

2003-01-15

Two different types of ancient bricks (12th to 14th centuries) collected from historical buildings of Toledo (Spain) were characterised by optical microscopy, scanning electron microscopy/energy-dispersive X-ray spectrometers (SEM/EDS), electron probe microanalysis (EM), X-ray diffraction (XRD), differential thermal analysis (DTA) and {sup 57}Fe-Moessbauer spectroscopy. Physical properties such as water absorption and suction, porosity, density and compression strength were also determined. Several minerals found in the brick matrix, such as garnet, let us infer raw material sources; calcite, dolomite, illite and neoformed gehlenite and diopside phases, on temperature reached in firing; secondary calcite, on first cooling scenarios; and manganese micronodules, on latemore » pollution environments. XRD and DTA of original and refired samples supply information about firing temperatures. Additional data on firing conditions and type of the original clay are provided by the Moessbauer study. Physical properties of both types of bricks were compared and correlated with raw materials and fabric and firing technology employed. The physicochemical characterisation of these bricks provides valuable data for restoration purposes to formulate new specific bricks using neighbouring raw materials.« less

New frontiers in coral geochronology: advancing the state of the art

NASA Astrophysics Data System (ADS)

Thompson, William G.

2010-05-01

New developments in mass spectrometry and a better understanding of open-system processes are ushering in a new era of precision and accuracy in coral geochronology. An effort is underway to develop a uniform set of reference materials and reporting standards to assure age comparability between laboratories and eliminate inter-laboratory and age interpretation biases. PALSEA is a PAGES/IMAGES working group that aims to extract information about ice sheet response to temperature change by examining the history of sea during past interglacials. As reef-building corals are one of the primary archives of past sea levels, the U-series coral dating community is well represented in this group. During workshop discussions, it became clear that further progress on the sea level problem requires engaging the coral dating community in a cooperative standardization effort. Improvements in analytical precision continue to extend the potential precision and range of the U-Th chronometer. As a result, assuring comparability of ages reported by different labs becomes a crucial issue. Ideally, all measurements should be traceable to the same set of reference standards. Unfortunately, internationally recognized standards are not currently available. A widely used U/Th uraninite standard, HU-1, is no longer be suitable, as different aliquots have different isotope ratios and the assumption of radioactive equilibrium no longer appears valid when measured at current levels of precision. The time is ripe for the development of new reference standards. A strategy for their production and distribution has been initiated in collaboration with the NERC Isotope Geosciences Laboratory, UK, and drawing on the experiences of the EARTHTIME initiative (http://www.earth-time.org). Quaternary sea level data is presently scattered across the scientific literature with widely varying reporting formats, screening and correction criteria, and decay constants. Stratigraphic information is often incomplete, and elevations are not tied to consistent benchmarks. It would be highly desirable to compile existing data in a uniform format that can be made available to the wider community, and to adopt a uniform set of standards for future data reporting. While best practices for sample screening and/or age correction are still keenly debated, reported ages depend heavily on assumptions about the 234U/238U history of seawater over the last 800 thousand years. A standard history of ocean 234U/238U for quality and correction criteria, with associated error estimates, would make ages reported by different labs more directly comparable. Data reduction and archiving software has been developed as part of the EARTHTIME project, and discussions are underway to adapt this software for the U-Th chronometer. Standardized reporting through data reduction and databasing software has great potential to make U-series dating of coral sea-level indicators more useful and accessible to the wider paleoclimate community.

Geochemical study of calcite veins in the Silurian and Devonian of the Barrandian Basin (Czech Republic): evidence for widespread post-Variscan fluid flow in the central part of the Bohemian Massif

NASA Astrophysics Data System (ADS)

Suchy, V.; Heijlen, W.; Sykorova, I.; Muchez, Ph; Dobes, P.; Hladikova, J.; Jackova, I.; Safanda, J.; Zeman, A.

2000-03-01

Carbonate fracture cements in limestones have been investigated by fluid inclusion and stable isotope analysis to provide insight into fluid evolution and deformation conditions of the Barrandian Basin (Silurian-Devonian) of the Czech Republic. The fractures strike generally north-south and appear to postdate major Variscan deformation. The most common fracture cement is calcite that is locally accompanied by quartz, natural bitumen, dolomite, Mn-oxides and fluorite. Three successive generations of fracture-filling calcite cements are distinguished based on their petrographical and geochemical characteristics. The oldest calcite cements (Stage 1) are moderate to dull brown cathodoluminescent, Fe-rich and exhibit intense cleavage, subgrain development and other features characteristic of tectonic deformation. Less tectonically deformed, variable luminescent Fe-poor calcite corresponds to a paragenetically younger Stage 2 cement. First melting temperatures, Te, of two-phase aqueous inclusions in Stages 1 and 2 calcites are often around -20°C, suggesting that precipitation of the cements occurred from H 2O-NaCl fluids. The melting temperature, Tm, has values between 0 and -5.8°C, corresponding to a low salinity between 0 and 8.9 eq. wt% NaCl. Homogenization temperatures, Th, from calcite cements are interpreted to indicate precipitation at about 70°C or less. No distinction could be made between the calcite of Stages 1 and 2 based on their fluid inclusion characteristics. In some Stage 2 cements, inclusions of highly saline (up to 23 eq. wt% NaCl) brines appear to coexist with low-salinity inclusions. The low salinity fluid possibly contains Na-, K-, Mg- and Ca-chlorides. The high salinity fluid has a H 2O-NaCl-CaCl 2 composition. Blue-to-yellow-green fluorescing hydrocarbon inclusions composed of medium to higher API gravity oils are also identified in some Stages 1 and 2 calcite cements. Stage 1 and 2 calcites have δ18O values between -13.2‰ and -7.2‰ PDB. The lower range of the calculated δ18O values of the ambient fluids (-3.5‰ to +2.7‰ SMOW) indicate precipitation of these cements from deeply circulating meteoric waters. The presence of petroleum hydrocarbon inclusions in some samples is interpreted to reflect partial mixing with deeper basinal fluids. The paragenetically youngest Stage 3 calcite cement has only been encountered in a few veins. These calcites are characterised by an intensely zoned luminescence pattern, with bright yellow and non-luminescent zones. Inclusions of Mn-oxides and siliceous sinters are commonly associated with Stage 3 calcite, which is interpreted to have precipitated from shallower meteoric waters. Regional structural analysis revealed that the calcite veins of the Barrandian basin belong to a large-scale system of north-south-trending lineaments that run through the territory of the Czech Republic. The veins probably reflect episodes of fluid migration that occurred along these lineaments during late stages of the Variscan orogeny.

Meteoric calcite cementation: diagenetic response to relative fall in sea-level and effect on porosity and permeability, Las Negras area, southeastern Spain

NASA Astrophysics Data System (ADS)

Li, Zhaoqi; Goldstein, Robert H.; Franseen, Evan K.

2017-03-01

A dolomitized Upper Miocene carbonate system in southeast Spain contains extensive upper and lower zones of calcite cementation that cut across the stratigraphy. Cement textures including isopachous and circumgranular, which are consistent with phreatic-zone cementation. Cements in the upper cemented zone are non-luminescent, whereas those in the lower cemented zone exhibit multiple bands of luminescent and non-luminescent cements. In the upper cemented zone, isotopic data show two meteoric calcite lines (MCL) with mean δ18O at - 5.1‰ and - 5.8‰ VPDB, whereas no clear MCL is defined in the lower cemented zone where mean δ18O for calcite cement is at - 6.7‰ VPDB. δ13C values in both cement zones are predominantly negative, ranging from - 10 to + 2‰ VPDB, suggestive of carbon from soil gas or decayed organics. Measurements of Tm ice in primary fluid inclusions yield a mode of 0.0 °C in both zones, indicating calcite cementation from fresh water. These two zones define the positions of two different paleo-water tables that formed during a relative sea-level fall and erosional downcutting during the Plio-Pleistocene. The upper cemented zone pre-dated the lower cemented zone on the basis of known relative sea-level history. Meteoric calcite cementation reduced porosity and permeability, but measured values are inconsistent with simple filling of open pore space. Each texture, boundstone, grainstone, packstone, wackestone, produces a different relationship between percent calcite cement and porosity/permeability. Distribution of cements may be predictable on the basis of known sea-level history, and the effect of the cementation can be incorporated into subsurface geomodels by defining surfaces of rock boundaries that separate cemented zones from uncemented zones, and applying texture-specific relationships among cementation, porosity and permeability.

Fitful and protracted magma assembly leading to a giant eruption, Youngest Toba Tuff, Indonesia

USGS Publications Warehouse

Reid, Mary R; Vazquez, Jorge A.

2017-01-01

The paroxysmal eruption of the 74 ka Youngest Toba Tuff (YTT) of northern Sumatra produced an extraordinary 2800 km3 of non-welded to densely welded ignimbrite and co-ignimbrite ash-fall. We report insights into the duration of YTT magma assembly obtained from ion microprobe U-Th and U-Pb dates, including continuous age spectra over >50% of final zircon growth, for pumices and a welded tuff spanning the compositional range of the YTT. A relatively large subpopulation of zircon crystals nucleated before the penultimate caldera-related eruption at 501 ka, but most zircons yielded interior dates 100-300 ka thereafter. Zircon nucleation and growth was likely episodic and from diverse conditions over protracted time intervals of >100 to >500 ka. Final zircon growth is evident as thin rim plateaus that are in Th/U chemical equilibrium with hosts, and that give crystallization ages within tens of ka of eruption. The longevity and chemical characteristics of the YTT zircons, as well as evidence for intermittent zircon isolation and remobilization associated with magma recharge, is especially favored at the cool and wet eutectoid conditions that characterize at least half of the YTT, wherein heat fluxes could dissolve major phases but have only a minor effect on larger zircon crystals. Repeated magma recharge may have contributed to the development of compositional zoning in the YTT but, considered together with limited allanite, quartz, and other mineral dating and geospeedometry, regular perturbations to the magma reservoir over >400 ka did not lead to eruption until 74 ka ago.

Conventional U-Pb dating versus SHRIMP of the Santa Barbara Granite Massif, Rondonia, Brazil

USGS Publications Warehouse

Sparrenberger, I.; Bettencourt, Jorge S.; Tosdal, R.M.; Wooden, J.L.

2002-01-01

The Santa Ba??rbara Granite Massif is part of the Younger Granites of Rondo??nia (998 - 974 Ma) and is included in the Rondo??nia Tin Province (SW Amazonian Craton). It comprises three highly fractionated metaluminous to peraluminous within-plate A-type granite units emplaced in older medium-grade metamorphic rocks. Sn-mineralization is closely associated with the late-stage unit. U-Pb monazite conventional dating of the early-stage Serra do Cicero facies and late-stage Serra Azul facies yielded ages of 993 ?? 5 Ma and 989 ?? 13 Ma, respectively. Conventional multigrain U-Pb isotope analyses of zircon demonstrate isotopic disturbance (discordance) and the preservation of inherited older zircons of several different ages and thus yield little about the ages of Sn-granite magmatism. SHRIMP U-Pb ages for the Santa Ba??rbara facies association yielded a 207Pb/206Pb weighted-mean age of 978 ?? 13 Ma. The textural complexity of the zircon crystals of the Santa Ba??rbara facies association, the variable concentrations of U, Th and Pb, as well as the mixed inheritance of zircon populations are major obstacles to using conventional multigrain U-Pb isotopic analyses. Sm-Nd model ages and ??Nd (T) values reveal anomalous isotopic data, attesting to the complex isotopic behaviour within these highly fractionated granites. Thus, SHRIMP U-Pb zircon and conventional U-Pb monazite dating methods are the most appropriate to constrain the crystallization age of the Sn-bearing granite systems in the Rondo??nia Tin Province.

Laser ablation U-Th-Sm/He dating of detrital apatite

NASA Astrophysics Data System (ADS)

Guest, B.; Pickering, J. E.; Matthews, W.; Hamilton, B.; Sykes, C.

2016-12-01

Detrital apatite U-Th-Sm/He thermochronology has the potential to be a powerful tool for conducting basin thermal history analyses as well as complementing the well-established detrital zircon U-Pb approach in source to sink studies. A critical roadblock that prevents the routine application of detrital apatite U-Th-Sm/He thermochronology to solving geological problems is the costly and difficult whole grain approach that is generally used to obtain apatite U-Th-Sm/He data. We present a new analytical method for laser ablation thermochronology on apatite. Samples are ablated using a Resonetics™ 193 nm excimer laser and liberated 4He is measured using an ASI (Australian Scientific Instruments) Alphachron™ quadrupole mass spectrometer system; collectively known as the Resochron™. The ablated sites are imaged using a Zygo ZescopeTM optical profilometer and ablated pit volume measured using PitVol, a custom MatLabTM algorithm. The accuracy and precision of the method presented here was confirmed using well-characterized Durango apatite and Fish Canyon Tuff (FCT) apatite reference materials, with Durango apatite used as a primary reference and FCT apatite used as a secondary reference. The weighted average of our laser ablation Durango ages (30.5±0.35 Ma) compare well with ages obtained using conventional whole grain degassing and dissolution U-Th-Sm/He methods (32.56±0.43 Ma) (Jonckheere et.al., 1 993; Farley, 2000; McDowell et.al., 2005) for chips of the same Durango crystal. These Durango ages were used to produce a K-value to correct the secondary references and unknown samples. After correction, FCT apatite has a weighted average age of 28.37 ± 0.96 Ma, which agrees well with published ages. As a further test of this new method we have conducted a case study on a set of samples from the British Mountains of the Yukon Territory in NW Canada. Sandstone samples collected across the British Mountains were analyzed using conventional U-Th-Sm/He whole grain methods and then reanalyzed using our new Laser ablation approach. The laser ablation results are consistent with those obtained using conventional methods, confirming that apatite laser ablation U-Th-Sm/He thermochronology is a viable alternative for collecting large low temperature thermochronology data sets from detrital samples.

76 FR 30827 - Temporary Change of Dates for Recurring Marine Event in the Fifth Coast Guard District; Elizabeth...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-27

... various river boat races and a parade during the ``35th Annual Norfolk Harborfest Celebration.'' Special... Docket Management Facility (M-30), U.S. Department of Transportation, West Building Ground Floor, Room... typically comprise marine events include sailing regattas, power boat races, swim races and holiday boat...

77 FR 12106 - 88th Meeting: RTCA Special Committee 159, Global Positioning System (GPS)

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-28

... 159, Global Positioning System (GPS) AGENCY: Federal Aviation Administration (FAA), U.S. Department of Transportation (DOT). ACTION: Notice of RTCA Special Committee 159, Global Positioning System (GPS). SUMMARY: The..., Global Positioning System (GPS). DATES: The meeting will be held March 13-16, 2012, from 9 a.m.-4:30 p.m...

78 FR 42533 - Collection of Information Under Review by Office of Management and Budget

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-16

..., 725 17th Street NW., Washington, DC 20503, attention Desk Officer for the Coast Guard. (3) Hand.... To ensure your comments are received in a timely manner, mark the fax, attention Desk Officer for the... sold. Dated: July 3, 2013. R. E. Day, Rear Admiral, U. S. Coast Guard, Assistant Commandant for Command...

4. AERIAL VIEW TO SOUTHEAST OF ENTIRE COAST GUARD AIR ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. AERIAL VIEW TO SOUTHEAST OF ENTIRE COAST GUARD AIR STATION SAN FRANCISCO. 8X10 black and white silver gelatin print. United States Coast Guard Official Photograph, 12th District, File No. 62751-22 A.S. Date unknown. - U.S. Coast Guard Air Station San Francisco, 1020 North Access Road, San Francisco, San Francisco County, CA

77 FR 33199 - Marine Mammals; File No. 16124

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-05

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1. Drop Structure on the Arizona Crosscut Canal. Photographer unknown, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Drop Structure on the Arizona Crosscut Canal. Photographer unknown, no date. Note that caption is incorrect: in relation to Camelback Mountain (rear), this can only be the Old Crosscut. Source: reprinted from the 13th Annual Report of the U.S. Geological Survey, 1893. - Old Crosscut Canal, North Side of Salt River, Phoenix, Maricopa County, AZ

77 FR 30500 - Agenda and Notice of Public Meeting of the Maryland Advisory Committee

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-23

.... The comments must be received in the regional office by Thursday, July 5, 2012. Comments may be mailed to the Eastern Regional Office, U.S. Commission on Civil Rights, 624 9th Street NW., Suite 740... date of the meeting. Records generated from this meeting may be inspected and reproduced at the Eastern...

CHIME monazite dating using FE-EPMA equipped with R=100 mm spectrometers

NASA Astrophysics Data System (ADS)

Shibata, K.; Shimizu, M.; Suzuki, K.; Sueoka, S.; Niwa, M.

2015-12-01

The age spectrum of detrital monazite grains is used to unravel the tectono-thermal history of the pre-Neogene terranes, which is required for geological disposal of high-level radioactive waste on tectonically active Japanese Islands. The CHIME (Chemical Th-U-total Pb isochron method, Suzuki and Adachi, 1991) is best suited for dating of detrital monazite whose grains are not chronologically uniform. In the previous studies (eg, Suzuki, 2011), EPMA equipped with conventional R=140 mm spectrometers was used for measurement of U, Th and Pb. However the spectrometers have low count rate of measurement of Pb. The JEOL JXA-8530F FE-EPMA equipped with R=100 mm spectrometers has been applied for the CHIME monazite dating. The intrinsic responses of each of the R=100 mm spectrometers for PbMβ are around ten times higher than that of the R=140 mm spectrometer. The R=100 mm spectrometers permits obtaining high count rate, which enables us to shorten measurement time than before. As these spectrometers have peculiar spectral interference, the method reported by Amli and Griffin (1978) is applied for correction of the interference. In order to verify the dating using the FE-EPMA and the interference correction method, two distinct age groups of monazite were measured. The ages were 425±25 Ma for monazite from Cooma granite in southeastern Australia, which had dated by SHRIMP as 432.8 ± 3.5 Ma (Williams, 2001) and 67 ± 7 Ma for monazite of the Kojaku granite in southwestern Japan, which is corresponding to the LA-ICP-MS U-Pb zircon ages of 68.5 ± 0.7 Ma. These results indicate that the FE-EPMA and the interference correction method are useful for the CHIME monazite dating and for revealing the tectono-thermal history of the terranes. This study was carried out under a contract with Agency of Natural Resources and Energy(ANRE), part of Ministry of Economy, Trade and Industry (METI) of Japan as part of its R&D supporting program for developing geological disposal technology.

Ion-probe U–Pb dating of authigenic and detrital opal from Neogene-Quaternary alluvium

USGS Publications Warehouse

Neymark, Leonid; Paces, James B.

2013-01-01

Knowing depositional ages of alluvial fans is essential for many tectonic, paleoclimatic, and geomorphic studies in arid environments. The use of U–Pb dating on secondary silica to establish the age of Neogene-Quaternary clastic sediments was tested on samples of authigenic and detrital opal and chalcedony from depths of ∼25 to 53 m in boreholes at Midway Valley, Nevada. Dating of authigenic opal present as rinds on rock clasts and in calcite/silica cements establishes minimum ages of alluvium deposition; dating of detrital opal or chalcedony derived from the source volcanic rocks gives the maximum age of sediment deposition.Materials analyzed included 12 samples of authigenic opal, one sample of fracture-coating opal from bedrock, one sample of detrital opal, and two samples of detrital chalcedony. Uranium–lead isotope data were obtained by both thermal ionization mass spectrometry and ion-microprobe. Uranium concentrations ranged from tens to hundreds of μg/g. Relatively large U/Pb allowed calculation of 206Pb/238U ages that ranged from 1.64±0.36 (2σ) to 6.16±0.50 Ma for authigenic opal and from 8.34±0.28 to 11.2±1.3 Ma for detrital opal/chalcedony. Three samples with the most radiogenic Pb isotope compositions also allowed calculation of 207Pb/235U ages, which were concordant with 206Pb/238U ages from the same samples.These results indicate that basin development at Midway Valley was initiated between about 8 and 6 Ma, and that the basin was filled at long-term average deposition rates of less than 1 cm/ka. Because alluvium in Midway Valley was derived from adjacent highlands at Yucca Mountain, the low rates of deposition determined in this study may imply a slow rate of erosion of Yucca Mountain. Volcanic strata underlying the basin are offset by a number of buried faults to a greater degree than the relatively smooth-sloping bedrock/alluvium contact. These geologic relations indicate that movement on most faults ceased prior to erosional planation and burial. Therefore, ages of the authigenic opal from basal alluvium indicate that the last movement on buried faults was older than about 6 Ma.

ECCO: Th/U/Pu/Cm Dating of Galactic Cosmic Ray Nuclei

NASA Technical Reports Server (NTRS)

Westphal, A. J.; Weaver, B. A.; Solarz, M.; Dominquez, G.; Craig, N.; Adams, J. H.; Barbier, L. M.; Christian, E. R.; Mitchell, J. W.; Binns, W. R.;

Is the core top modern? Observations from the eastern equatorial Pacific

NASA Astrophysics Data System (ADS)

Mekik, Figen; Anderson, Robert

2018-04-01

A compilation of ages from 67 core tops in the eastern equatorial Pacific (EEP) does not display an easily discernible regional pattern. The ages range from 790 to over 15,000 years. The youngest core tops with the highest sediment focusing factors are located in the Panama Basin. There are weak but statistically significant inverse relationships between core top age and age-model based mass accumulation rates, bioturbation depth, linear sedimentation rate and sediment focusing factors. However, we found no statistically significant relationship between core top age and calcite dissolution in sediments or 230Th-normalized mass accumulation rates. We found evidence suggesting that greater amount of sediment focusing helps to preserve the carbonate fraction of the sediment where focusing is taking place. When focusing factors are plotted against percent calcite dissolved, we observe a strong inverse relationship, and core tops younger than 4500 years tend to occur where focusing factors are high and percent calcite dissolved values are low. Using labile organic carbon fluxes to estimate bioturbation depth in the sediments results in the observation that where bioturbation depth is shallow (<4 cm), the core top age has a strong, inverse relationship with sediment accumulation rate. We used the Globorotalia menardii Fragmentation Index (MFI) as an indicator of percent calcite dissolved in deep sea sediments. There is a distinct pattern to core top calcite dissolution in the EEP which delineates bands of high surface ocean productivity as well as the clear increase in dissolution downward on the flanks of the East Pacific Rise.

Importance of coccolithophore-associated organic biopolymers for fractionating particle-reactive radionuclides (234Th, 233Pa, 210Pb, 210Po, and 7Be) in the ocean

NASA Astrophysics Data System (ADS)

Lin, Peng; Xu, Chen; Zhang, Saijin; Sun, Luni; Schwehr, Kathleen A.; Bretherton, Laura; Quigg, Antonietta; Santschi, Peter H.

2017-08-01

Laboratory incubation experiments using the coccolithophore Emiliania huxleyi were conducted in the presence of 234Th, 233Pa, 210Pb, 210Po, and 7Be to differentiate radionuclide uptake to the CaCO3 coccosphere from coccolithophore-associated biopolymers. The coccosphere (biogenic calcite exterior and its associated biopolymers), extracellular (nonattached and attached exopolymeric substances), and intracellular (sodium-dodecyl-sulfate extractable and Fe-Mn-associated metabolites) fractions were obtained by sequentially extraction after E. huxleyi reached its stationary growth phase. Radionuclide partitioning and the composition of different organic compound classes, including proteins, total carbohydrates (TCHO), and uronic acids (URA), were assessed. 210Po was closely associated with the more hydrophobic biopolymers (high protein/TCHO ratio, e.g., in attached exopolymeric substances), while 234Th and 233Pa showed similar partitioning behavior with most activity being distributed in URA-enriched, nonattached exopolymeric substances and intracellular biopolymers. 234Th and 233Pa were nearly undetectable in the coccosphere, with a minor abundance of organic components in the associated biopolymers. These findings provide solid evidence that biogenic calcite is not the actual main carrier phase for Th and Pa isotopes in the ocean. In contrast, both 210Pb and 7Be were found to be mostly concentrated in the CaCO3 coccosphere, likely substituting for Ca2+ during coccolith formation. Our results demonstrate that even small cells (E. huxleyi) can play an important role in the scavenging and fractionation of radionuclides. Furthermore, the distinct partitioning behavior of radionuclides in diatoms (previous studies) and coccolithophores (present study) explains the difference in the scavenging of radionuclides between diatom- and coccolithophore-dominated marine environments.

Post Audit of a Field Scale Reactive Transport Model of Uranium at a Former Mill Site

NASA Astrophysics Data System (ADS)

Curtis, G. P.

2015-12-01

Reactive transport of hexavalent uranium (U(VI)) in a shallow alluvial aquifer at a former uranium mill tailings site near Naturita CO has been monitored for nearly 30 years by the US Department of Energy and the US Geological Survey. Groundwater at the site has high concentrations of chloride, alkalinity and U(VI) as a owing to ore processing at the site from 1941 to 1974. We previously calibrated a multicomponent reactive transport model to data collected at the site from 1986 to 2001. A two dimensional nonreactive transport model used a uniform hydraulic conductivity which was estimated from observed chloride concentrations and tritium helium age dates. A reactive transport model for the 2km long site was developed by including an equilibrium U(VI) surface complexation model calibrated to laboratory data and calcite equilibrium. The calibrated model reproduced both nonreactive tracers as well as the observed U(VI), pH and alkalinity. Forward simulations for the period 2002-2015 conducted with the calibrated model predict significantly faster natural attenuation of U(VI) concentrations than has been observed by the persistent high U(VI) concentrations at the site. Alternative modeling approaches are being evaluating evaluated using recent data to determine if the persistence can be explained by multirate mass transfer models developed from experimental observations at the column scale(~0.2m), the laboratory tank scale (~2m), the field tracer test scale (~1-4m) or geophysical observation scale (~1-5m). Results of this comparison should provide insight into the persistence of U(VI) plumes and improved management options.

New U/Th ages for Pleistocene megafauna deposits of southeastern Queensland, Australia

NASA Astrophysics Data System (ADS)

Price, Gilbert J.; Zhao, Jian-xin; Feng, Yue-xing; Hocknull, Scott A.

2009-02-01

Arguments over the extinction of Pleistocene megafauna have become particularly polarised in recent years. Causes for the extinctions are widely debated with climate change, human hunting and/or habitat modification, or a combination of those factors, being the dominant hypotheses. However, a lack of a spatially constrained chronology for many megafauna renders most hypotheses difficult to test. Here, we present several new U/Th dates for a series of previously undated, megafauna-bearing localities from southeastern Queensland, Australia. The sites were previously used to argue for or against various megafauna extinction hypotheses, and are the type localities for two now-extinct Pleistocene marsupials (including the giant koala, Phascolarctos stirtoni). The new dating allows the deposits to be placed in a spatially- and temporally constrained context relevant to the understanding of Australian megafaunal extinctions. The results indicate that The Joint (Texas Caves) megafaunal assemblage is middle Pleistocene or older (>292 ky); the Cement Mills (Gore) megafaunal assemblage is late Pleistocene or older (>53 ky); and the Russenden Cave Bone Chamber (Texas Caves) megafaunal assemblage is late Pleistocene (˜55 ky). Importantly, the new results broadly show that the sites date prior to the hypothesised megafaunal extinction 'window' (i.e., ˜30-50 ky), and therefore, cannot be used to argue exclusively for or against human/climate change extinction models, without first exploring their palaeoecological significance on wider temporal and spatial scales.

Noble Gases in Alpine Gold: U/Th-He Dating and Excesses of Radiogenic He and AR

NASA Astrophysics Data System (ADS)

Eugster, O.; Hofmann, B.; Krahenbuhl, U.; Neuenschwander, J.

1992-07-01

Gold precipitates in hydrothermal fluids along with other heavy elements, such as Ag and Pt. In order to explore the possibility of dating the formation of gold we determined the concentrations of U, Th, and their decay product ^4He, as well as the K and ^40Ar concentrations in vein-type gold and in placer gold samples. The gold-quartz veins at Brusson in the south-western alps were formed approximately 32 Ma ago during an episode of tectonic uplift (Diamond, 1990). Alpine material was deposited as sediment layers in the region of central Switzerland and placer gold is thus relatively abundant in the rivers of the Napf area. We washed placer gold from the river Grosse Fontanne in 1990 and 1991. Placer gold that had been collected from the river Kruempelgraben in 1933 and a sample of vein-type free gold grown on quartz rock from the Brusson area (Val d'Ayas) have been obtained from the Museum of Natural History in Bern. Table 1 gives the results. Most of the ^4He is released above 1050 degrees C, that is when gold melts, indicating that gold is extremely well retentive for He. From the ^4He concentration of (269 +- 20) x 10^-8 cm^3 STP/g, (0.4 +- 0.1) ppm U, and (0.9 +- 0.3) ppm Th for vein-type gold we calculate a U/Th-He age of (36 +- 8)Ma. This age agrees within errors with the proposed age of 32 Ma. The data given in Table 1 show that all placer gold samples contain excesses of radiogenic ^4He and ^40Ar relative to the concentrations expected from the U/Th and K decay, respectively, if we assume a formation age of 32 Ma. The quartz sample is depleted in ^4He but strongly enriched in radiogenic ^40Ar. The excess of ^40Ar(sub)rad is easier to explain than that of ^4He. Vein-type gold and placer gold contain quartz inclusions (Schmid, 1973). The high ^40Ar(sub)rad content of quartz (Table 1) indicates that the ^40Ar(sub)rad excess of gold originates from quartz inclusions. Excess ^4He in gold must be of radiogenic origin. Taking ^20Ne and ^36Ar as a measure for the quantity of trapped atmospheric noble gases we estimate atmospheric ^4He in the gold samples to be three to five orders of magnitude below the observed ^4He concentration. Placer gold is finely distributed in rock material and might be exposed to an alpha-particle irradiation from neighboring U/Th-rich minerals. An alternative He source are inclusions of U/Th-rich minerals, such as zircon, either within the gold material or mechanically worked into the spangles as they were part of the river detritus. Acknowledgement: We thank the Swiss NSF for their support. References: Diamond L.W. (1990) Am. J. of Science 290, 912-958. Schmid K. (1973) Schw. Min. Petr. Mitt. 53, 125-156. Table 1, which in the hard copy appears here, shows concentrations of He, Ne, and Ar (10^-8 cm^3 STP/g) and of K, Th, and U (ppm) in vein-type free gold, placer gold, and quartz. The ^3He and ^21Ne signals were below detection limits, that is ^4He/^3He in gold is >100'000. Average ^20Ne/^22Ne ratios in gold and quartz are 10.2 +- 0.2, that is about 4% larger than in the terrestrial atmosphere. Average ^36Ar/^38Ar = 5.2 +- 0.2 (within errors identical to ^36Ar/^38Ar in air). 1) Sample sizes 50-100 mg. 2) Radiogenic ^40Ar = ^40Ar-295.5 x ^36Ar. 3) Calculated from U/Th and ^40K decay.

Tectono-thermal evolution of north Kuqa Depression and South Tian Shan: constraints from apatite (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Xiao, Y.; Qiu, N.; Chang, J.

2017-12-01

The Kuqa Depression, located between Tarim Basin and South Tian Shan Orogen, is considered the most promising site for study the tectono-thermal evolution of the Central Asia Orogenic Belt (CAOB). (U-Th)/He is a new dating method and apatite He ages can record the cooling histories at low temperature between 40 ° 75°1. At present, the low temperature thermochronological data, especially the (U-Th)/He, from north Kuqa Depression are scarce, resulting in controversial issues regarding the cooling history of the upper crust and the latest uplift of South Tian Shan. We present new apatite (U-Th)/He (AHe) thermochronologic data from kuqa depression, aiming to provide insights into exhumation and thermal history of the north kuqa depression. In this study, we firstly present 43 apatite (U-Th)/He ages of 9 samples in north rim of Kuqa Depression. The (U-Th)/He ages range from 1.4±1.0Ma to 17.9±1.2Ma, which are obviously both younger than both the depositional ages and the corresponding AFT ages. To better understand the deformation evolution and thermal history of north Tarim Basin, we use these thermochronological data as inputs for HeFTy software implemented with radiation damage accumulation and annealing model (RDAAM) for time-temperature reconstruction1,2. The relationship between AHe or AFT ages and the relative stratigraphic ages shows that the AHe ages are young and almost about 10 Ma.Thermal modeling using apatite (U-Th)/He ages and geological background information in the same area allow us to obtain a cooling history. The sample T-03 suffered a cooling between 170 and 130Ma, they were re-heated at around 100° between 100 and 40Ma then rapidly cooled and exhumed to reach the surface temperature at around 5Ma. The thermal modeling results indicated the north Kuqa Depression experienced a Miocene rapid cooling event initialed at 12Ma and continued to 5Ma, resulting from far field effect of India-Asia collision. References1. Ketcham, R.A. Forward and reverse Modeling of Low-Temperature Thermochronometry Data. Reviews in Mineralogy and Geochemistry. 58, 275-314(2005). 2. Flowers, R.M. Ketcham, R.A., Shuster, D.l. & Farley, K.A. Apatite (U-Th)/He thermochronometry using a radiation damage accumulation and annealing model. Geochimica et Cosmochimica Acta. 73, 2347-2365 (2009).

Seasonal variations in modern speleothem calcite growth in Central Texas, U.S.A

USGS Publications Warehouse

Banner, J.L.; Guilfoyle, A.; James, E.W.; Stern, L.A.; Musgrove, M.

2007-01-01

Variations in growth rates of speleothem calcite have been hypothesized to reflect changes in a range of paleoenvironmental variables, including atmospheric temperature and precipitation, drip-water composition, and the rate of soil CO2 delivery to the subsurface. To test these hypotheses, we quantified growth rates of modern speleothem calcite on artificial substrates and monitored concurrent environmental conditions in three caves across the Edwards Plateau in central Texas. Within each of two caves, different drip sites exhibit similar annual cycles in calcite growth rates, even though there are large differences between the mean growth rates at the sites. The growth-rate cycles inversely correlate to seasonal changes in regional air temperature outside the caves, with near-zero growth rates during the warmest summer months, and peak growth rates in fall through spring. Drip sites from caves 130 km apart exhibit similar temporal patterns in calcite growth rate, indicating a controlling mechanism on at least this distance. The seasonal variations in calcite growth rate can be accounted for by a primary control by regional temperature effects on ventilation of cave-air CO2 concentrations and/or drip-water CO2 contents. In contrast, site-to-site differences in the magnitude of calcite growth rates within an individual cave appear to be controlled principally by differences in drip rate. A secondary control by drip rate on the growth rate temporal variations is suggested by interannual variations. No calcite growth was observed in the third cave, which has relatively high values of and small seasonal changes in cave-air CO2. These results indicate that growth-rate variations in ancient speleothems may serve as a paleoenvironmental proxy with seasonal resolution. By applying this approach of monitoring the modern system, speleothem growth rate and geochemical proxies for paleoenviromnental change may be evaluated and calibrated. Copyright ?? 2007, SEPM (Society for Sedimentary Geology).

77 FR 40798 - Safety Zone; Nautical City Festival Air Show, Rogers City MI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-11

...-AA00 Safety Zone; Nautical City Festival Air Show, Rogers City MI AGENCY: Coast Guard, DHS. ACTION...; Nautical City Festival Air Show, Rogers City MI; in the Federal Register (77 FR 29932). We received no... Nautical City Festival will be celebrating Calcite's 100th Anniversary. As part of that celebration, an air...

77 FR 29932 - Safety Zone; Nautical City Festival Air Show, Rogers City, MI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-21

...-AA00 Safety Zone; Nautical City Festival Air Show, Rogers City, MI AGENCY: Coast Guard, DHS. ACTION... City Festival will be celebrating Calcite's 100th Anniversary. As part of that celebration, an air show will be launched to the east of the Rogers City marina. The Captain of the Port Sault Sainte Marie has...

Diagenesis of fossil coral skeletons: Correlation between trace elements, textures, and 234U /238U

NASA Astrophysics Data System (ADS)

Bar-Matthews, M.; Wasserburg, G. J.; Chen, J. H.

1993-01-01

A comparative study of Pleistocene fossil coral skeletons and of modern coral skeletons was carried out using petrographie and trace element analyses on a suite of Pleistocene samples that had previously been studied for 234U, 230Th, and U- 230Th ages ( CHEN et al. 1991). Evidence of a range of diagenetic changes can be recognized by optical (OM) and scanning electron microscopy (SEM). The normal texture exhibited by modern corals under OM consists of fine needles of aragonite forming a radial-fibrous pattern around a central dark line (center of calcification). This pattern can also be seen in many fossil corals. In most cases, the central dark line partially disappears during diagenesis, the radialfibrous pattern is obscured, and there is a distinct coarsening of the radial fabric of aragonite to unoriented platy or equant aragonite crystals. SEM images show diagenetic textures ranging from dense structureless images of the coralline matrix, with sharp boundaries at the septa walls, to the development of (1) a patchy distribution of dissolution micropores partially filled with aragonite fibers in the matrix, (2)aragonite needles coming from selvages in the septa walls which radiate into the septa voids. Using an electron microprobe and SEM, concentrations of Na, S, Sr, and Mg were measured. No other trace elements were detected. Na, S, and Mg contents of the matrix, the fibrous micropores, and radiating needles are highly variable and well correlated. High concentrations of Na, S, and Mg were found in modern living corals with lower concentrations in fossil corals and fibrous micropores, and the lowest value in the radiating needles. The reason for the correlations of Na, S, and Mg and crystal chemistry and the response to diagenesis of these trace elements is not understood. The average concentrations of Na, S, and Mg for each sample, when plotted against the whole coral initial δ 234U, are generally correlated ( CHEN et al., 1991). As all these diagenetic changes involve the recrystallization and deposition of aragonite, we infer that the geologic site of diagenesis both for forming the secondary aragonitic phases and for the enhancement of the 234U content in the fossil corals was the marine environment. It is possible that the textural and Na, S, and Mg trace element contents of fossil corals be used to ascertain the reliability of fossil coral skeletons for U- 230Th dating. The basic problem of identifying a priori unaltered coral skeletons for 230Th dating is not yet resolved.

Historical record of European emissions of heavy metals to the atmosphere since the 1650s from alpine snow/ice cores drilled near Monte Rosa.

PubMed

Barbante, Carlo; Schwikowski, Margit; Döring, Thomas; Gäggeler, Heinz W; Schotterer, Ulrich; Tobler, Leo; van de Velde, Katja; Ferrari, Christophe; Cozzi, Giulio; Turetta, Andrea; Rosman, Kevin; Bolshov, Michael; Capodaglio, Gabriele; Cescon, Paolo; Boutron, Claude

2004-08-01

Cr, Cu, Zn, Co, Ni, Mo, Rh, Pd, Ag, Cd, Sb, Pt, Au, and U have been determined in clean room conditions by inductively coupled plasma sector field mass spectrometry and other analytical techniques, in various sections of two dated snow/ice cores from the high-altitude (4450 m asl) glacier saddle Colle Gnifetti, Monte Rosa massif, located in the Swiss-Italian Alps. These cores cover a 350-year time period, from 1650 to 1994. The results show highly enhanced concentrations for most metals in snow/ice dated from the second half of the 20th century, compared with concentrations in ancient ice dated from the 17th and 18th centuries. The highest increase factors from the pre-1700 period to the post-1970 period are observed for Cd (36), Zn (19), Bi (15), Cu (11), and Ni (9), confirming the importance of atmospheric pollution by heavy metals in Europe. Metal concentrations observed in Colle Gnifetti snow around 1980 appear to be quantitatively related to metal emissions from Italy, Switzerland, Germany, France, Belgium, and Austria at that time, making it possible to reconstruct past changes in metal emission in these countries during the last centuries.

76 FR 1492 - Notice of Final Federal Agency Actions on Proposed Highway in Minnesota

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-10

... Department of Transportation (Mn/DOT): Heather Lukes, PE, Project Manager, District 6, 2900 48th Street NW... meaning of 23 U.S.C. 139(l)(1). The actions relate to a proposed highway project on US Highway 14 from I..., and Eastern Railroad corridor. Those actions grant approvals for the project. DATES: By this notice...

76 FR 72900 - Agenda and Notice of Public Meeting of the Connecticut Advisory Committee

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-28

... Friday, January 6, 2012. Comments may be mailed to the Eastern Regional Office, U.S. Commission on Civil Rights, 624 9th Street NW., Suite 740, Washington, DC 20425, faxed to (202) 376-7548, or emailed to ero... date of the meeting. Records generated from this meeting may be inspected and reproduced at the [[Page...

Detrital zircon U-Pb and (U-Th)/He double-dating of Upper Cretaceous-Cenozoic Zagros foreland basin strata in the Kurdistan Region of northern Iraq

NASA Astrophysics Data System (ADS)

Barber, D. E.; Stockli, D. F.; Koshnaw, R. I.; Horton, B. K.; Tamar-Agha, M. Y.; Kendall, J. J.

2014-12-01

The NW Zagros orogen is the result of the multistage collisional history associated with Late Cretaceous-Cenozoic convergence of the Arabian and Eurasian continents and final closure of Neotethys. Siliciclastic strata preserved within a ~400 km segment of the NW Zagros fold-thrust belt and foreland basin in the Iraqi Kurdistan Region (IKR) provide a widespread record of exhumation and sedimentation. As a means of assessing NW Zagros foreland basin evolution and chronostratigraphy, we present coupled detrital zircon (DZ) U-Pb and (U-Th)/He geo-thermochronometric data of Upper Cretaceous to Pliocene siliciclastic strata from the Duhok, Erbil, and Suleimaniyah provinces of IKR. LA-ICP-MS U-Pb age analyses reveal that the foreland basin fill in IKR in general was dominantly derived from Pan-African/Arabian-Nubian, Peri-Gondwandan, Eurasian, and Cretaceous volcanic arc terrenes. However, the provenance of these strata varies systematically along strike and through time, with an overall increase in complexity upsection. DZ age distribution of Paleocene-Eocene strata is dominated by a ~95 Ma grain age population, likely sourced from the Late Cretaceous Hassanbag-Bitlis volcanic arc complex along the northern margin of Arabia. In contrast, DZ U-Pb age distributions of Neogene strata show a major contribution derived from various Eurasian (e.g., Iranian, Tauride, Pontide; ~45, 150, 300 Ma) and Pan-African (~550, 950 Ma) sources. The introduction of Eurasian DZ ages at the Paleogene-Neogene transition likely records the onset of Arabian-Eurasian collision. Along strike to the southeast, the DZ U-Pb spectra of Neogene strata show a decreased percentage of Pan-African, Peri-Gondwandan, Tauride, and Ordovician ages, coupled with a dramatic increase in 40-50 Ma DZ ages that correspond to Urumieh-Dokhtar magmatic rocks in Iran. Combined with paleocurrent data, this suggests that Neogene sediments were transported longitudinally southeastward through an unbroken foreland basin system and progressively diluted downstream by detritus shed from the Iranian Plateau. Combined (U-Th)/He dating of DZ grains derived from the Hassanbag-Bitlis complex documents a major tectonothermal event at ~75 Ma, corresponding to the timing of proto-Zagros uplift and initial basin development in IKR.

High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardèche, France) using laser ablation ICP-MS

NASA Astrophysics Data System (ADS)

Grün, Rainer; Aubert, Maxime; Joannes-Boyau, Renaud; Moncel, Marie-Hélène

2008-11-01

We have mapped U ( 238U) and Th ( 232Th) elemental concentrations as well as U-series isotope distributions in a Neanderthal tooth from the Middle Palaeolithic site of Payre using laser ablation ICP-MS. The U-concentrations in an enamel section varied between 1 and 1500 ppb. The U-concentration maps show that U-migration through the external enamel surface is minute, the bulk of the uranium having migrated internally via the dentine into the enamel. The uranium migration and uptake is critically dependent on the mineralogical structure of the enamel. Increased U-concentrations are observed along lineaments, some of which are associated with cracks, and others may be related to intra-prismatic zones or structural weaknesses reaching from the dentine into the enamel. The uranium concentrations in the dentine vary between about 25,000 and 45,000 ppb. Our systematic mapping of U-concentration and U-series isotopes provides insight into the time domain of U-accumulation. Most of the uranium was accumulated in an early stage of burial, with some much later overprints. None of the uranium concentration and U-series profiles across the root of the tooth complied with a single stage diffusion-adsorption (D-A) model that is used for quality control in U-series dating of bones and teeth. Nevertheless, in the domains that yielded the oldest apparent U-series age estimates, U-leaching could be excluded. This means that the oldest apparent U-series ages of around 200 ka represent a minimum age for this Neanderthal specimen. This is in good agreement with independent age assessments (200-230 ka) for the archaeological layer, in which it was found. The Th elemental concentrations in the dental tissues were generally low (between about 1 and 20 ppb), and show little relationship with the nature of the tissue.

Parent zonation in thermochronometers - resolving complexity revealed by ID-TIMS U-Pb dates and implications for the application of decay-based thermochronometers

NASA Astrophysics Data System (ADS)

Navin Paul, Andre; Spikings, Richard; Chew, David; Daly, J. Stephen; Ulyanov, Alexey

2017-04-01

High temperature (>350℃) U-Pb thermochronometers primarily use accessory minerals such as apatite, titanite and rutile, and assume that daughter isotopes are lost by thermally activated volume diffusion while the parent remains immobile. Studies exploiting such behaviour have been successfully used to reconstruct thermal histories spanning several hundred million years (e.g. Cochrane et al., 2014). However, outliers in date (ID-TIMS) vs diffusion length space are frequently observed, and grains are frequently found to be either too young or too old for expected thermal history solutions using the diffusion data of Cherniak et al. (2010). These deviations of single grain apatite U-Pb dates from expected behaviour could be caused by a combination of i) metamorphic (over-)growth, ii) fluid-aided Pb mobilisation during alteration/recrystallization, iii) parent isotope zonation, iv) metamictisation, and v) changes in diffusion length with time (e.g. fracturing). We present a large data set from the northern Andes of South America, where we compare apatite U-Pb ID-TIMS-(TEA) data with LA-ICP-MS element maps and in-situ apatite U-Pb LA-(MC)-ICP-MS dates. These are combined with U-Pb zircon and 40Ar/39Ar (muscovite) data to attempt to distinguish between thermally activated volume diffusion and secondary overgrowth/recrystallization. We demonstrate that in young (e.g. Phanerozoic) apatites that have not recrystallized or experienced metasomatic overgrowths, U-Pb dates are dominantly controlled by volume diffusion and intra-crystal uranium zonation. This implies that ID-TIMS analyses of apatites with zoned parent isotope distributions will not usually recover accurate thermal history solutions, and an in-situ dating method is required. Recovering the uranium distribution during in-situ analysis provides a means to account for parent zonation, substantially increasing the accuracy of the modelled t-T-paths. We present in-situ data from apatites where scatter in date v diffusion length scale is observed and compare t-T-paths from single grain and in-situ modelling. Modelling of in-situ data will further show if all apatites from a single hand specimen record the same thermal history using Cherniak et al. (2010) diffusion data, or if the Pb-in-apatite diffusion parameters are a function of composition. U zonation is ubiquitous in the studied rocks (Triassic apatites extracted from peraluminous leucosomes), implying that these conclusions may also apply to lower temperature thermochronometers that are based on uranium decay, such as (U-Th)/He dating.

Combat History Analysis Study Effort (CHASE)

DTIC Science & Technology

1986-08-01

DE ; DEC JAN FEB JUL 2 8 KIMBERLY 11 KIHBERLY 15 LADYSMITH 24 LADYSHITH 18 LADYSHITH 1 SANTIAGO ...dates over time, along with some other des - criptive statistics of the material in the HERO data base, is discussed in Chapter 3. The HERO data base...Engagement O ■’-4 II i *J o ■H -H ^ ^. —1 U It For ce Pr ep on - de ra nc e 1 a V 2 .5 i2S it s o ’Si in’ S tH 71 u ■H 3 iW

Patterns of megaclasts along the coast of Eastern Samar (Philippines) - Implications for Holocene extreme-wave events

NASA Astrophysics Data System (ADS)

Engel, Max; Boesl, Fabian; Narod Eco, Rodrigo; Galang, Jam Albert; Gonzalo, Lia Anne; Llanes, Francesca; Quix, Eva; Schroeder-Ritzrau, Andrea; Frank, Norbert; Mahar Lagmay, Alfredo; Brückner, Helmut

2017-04-01

The Eastern Visayas region in the Philippines is hit by some of the most violent tropical cyclones on Earth on a regular basis, exemplified by Typhoon Haiyan, 7-9 November 2013, and a number of other category 4 and 5 events during the last decades. Moreover, strong earthquakes along the Philippine Trench have triggered several tsunamis in the historical past. Coastal flooding through extreme waves associated with these events represents a significant hazard for communities along the eastern coasts of Samar. However, not much is known about frequency-magnitude relationships of coastal flooding events and the maximum magnitude on centennial and millennial scales, which can be derived from geological traces and which have to be considered in a coastal hazard management process. We investigated a large boulder field in Eastern Samar distributed over an elevated, intertidal palaeo-reef platform in order to understand mechanisms of boulder transport and to derive implications for the maximum spatial extent, height, and velocity of coastal flooding. In the field, we recorded location, shape, morphological features as well as length and orientation of the main axes of more than 250 boulders, the a-axes of which were between 1.5 and 10.7 m. Eight samples were taken for Th/U dating of post-depositional, secondary calcite flowstones and pre-depostional coral, and four samples were taken for radiocarbon dating of pre-depositional, sessil organisms attached to the boulders. We 3D-mapped the most important parts of the boulder field using an unmanned aerial vehicle (UAV) and created structure-from-motion (SfM) models of the most prominent boulders, which will be used for inverse modelling of transport flows. Samples of the most common coralline lithofacies were taken for density estimations. We used interviews with elders of the local community as well as multi-temporal analysis of satellite images to reconstruct recent flooding patterns and boulder movement during recent events; Pléiades and Worldview-3 scenes were acquired for time slices before and after Typhoon Haiyan as well as after Typhoon Hagupit (6 December 2014). First results will be presented.

Birth Weight by Gestational Age for 76,710 Twins Born in the United States as a Result of In Vitro Fertilization: 2006 to 2010.

PubMed

Dickey, Richard P; Pridjian, Gabriella; Xiong, Xu; Klempel, Monica C

2017-01-01

Objective  The objective of this study was to establish twin-specific birth weight percentiles by gestational age using U.S. twin births resulting from in vitro fertilization (IVF). Study Design  A retrospective analysis of birth weight by completed weeks of gestation for 76,710 twin IVF births reported to the Society for Assisted Reproductive Technologies from 2006 to 2010. Mean and median birth weights and 3rd, 5th, 10th, 25th, 50th, 75th, 90th, and 97th percentiles were calculated by completed week of gestation and infant sex. Results  IVF twin birth weight accelerates until term and then declines. The deceleration in twin birth weight occurs at 39 completed weeks of gestation for larger twins, those at or above the 50th percentile in weight. For smaller twins, the growth deceleration occurs earlier, at 38 weeks of gestation. IVF female and male twin birth weights for gestational age were similar to all IVF twins, showing similar decelerations near term. Conclusion  Using U.S. IVF twin-specific growth charts, with known date of conception, twins demonstrate a deceleration in birth weight near term. Larger twins demonstrate a deceleration in birth weight by 39 completed weeks of gestation; smaller twins show a deceleration at 38 weeks. These data may assist in the clinical management of twins near term. Thieme Medical Publishers 333 Seventh Avenue, New York, NY 10001, USA.

Reappraisal of Los Humeros Volcanic Complex by New U/Th Zircon and 40Ar/39Ar Dating: Implications for Greater Geothermal Potential

NASA Astrophysics Data System (ADS)

Carrasco-Núñez, G.; Bernal, J. P.; Dávila, P.; Jicha, B.; Giordano, G.; Hernández, J.

2018-01-01

Longevity and size of magmatic systems are fundamental factors for assessing the potential of a geothermal field. At Los Humeros volcanic complex (LHVC), the first caldera-forming event was reported at 460 ± 40 ka. New zircon U/Th and plagioclase 40Ar/39Ar dates of pre-, syn- and postcaldera volcanics allow a reappraisal of the evolution of the geothermally active LHVC. The age of the voluminous Xaltipan ignimbrite (115 km3 dense rock equivalent [DRE]) associated with the formation of the Los Humeros caldera is now constrained by two geochronometers (zircon U/Th and plagioclase 40Ar/39Ar dating) to 164 ± 4.2 ka, which postdates a long episode of precaldera volcanism (rhyolitic domes), the oldest age of which is 693.0 ± 1.9 ka (40Ar/39Ar). The inferred short residence time (around 5 ka) for the paroxysmal Xaltipan ignimbrite is indicative of rapid assembly of a large magma body and rejuvenation of the system due to recurrent recharge magmas, as it has been occurred in some other large magmatic systems. Younger ages than previously believed have been obtained also for the other voluminous explosive phases of the Faby fall tuff at ˜70 ka and the second caldera-forming Zaragoza ignimbrite with 15 km3 DRE, which erupted immediately after. Thus, the time interval that separates the two caldera-forming episodes at Los Humeros is only 94 kyr, which is a much shorter interval than suggested by previous K-Ar dates (410 kyr). This temporal proximity allows us to propose a caldera stage encompassing the Xaltipan and the Zaragoza ignimbrites, followed by emplacement at 44.8 ± 1.7 ka of rhyolitic magmas interpreted to represent a postcaldera, resurgent stage. Rhyolitic eruptions have also occurred during the Holocene (<7.3 ± 0.1 ka) along with olivine-rich basalts that suggest recharge of the system. The estimated large volume magmatic reservoir for Los Humeros (>˜1,200 km3) and these new ages indicating much younger caldera-forming volcanism than previously believed are fundamental factors in the application of classical conductive models of heat resource, enhancing the heat production capacity and favor a higher geothermal potential.

Uranium/Thorium Dating and Growth Laminae Counting of Stalagmites Reveal a Record of Major Earthquakes in the Midwestern US

NASA Astrophysics Data System (ADS)

Zhang, Z.; Lundstrom, C.; Panno, S.; Hackley, K. C.; Fouke, B. W.; Curry, B.

2009-12-01

The recurrence interval of large New Madrid Seismic Zone (NMSZ) earthquakes is uncertain because of the limited number and likely incomplete nature of the record of dated seismic events. Data on paleoseismicity in this area is necessary for refining estimates of a recurrence interval for these earthquakes and for characterizing the geophysical nature of the NMSZ. Studies of the paleoseismic history of the NMSZ have previously used liquefaction features and flood plain deposits along the Mississippi River to estimate recurrence interval with considerable uncertainties. More precise estimates of the number and ages of paleoseismic events would enhance the ability of federal, state, and local agencies to make critical preparedness decisions. Initiation of new speleothems (cave deposits) has been shown in several localities to record large earthquake events. Our ongoing work in caves of southwestern Illinois, Missouri, Indiana and Arkansas has used both U/Th age dating techniques and growth laminae counting of actively growing stalagmites to determine the age of initiation of stalagmites in caves across the Midwestern U.S. These age initiations cluster around two known events, the great NMSZ earthquakes of 1811-1812 and the Missouri earthquake of 1917, suggesting that cave deposits in this region constitute a unique record of paleo-seismic history of the NMSZ. Furthermore, the U-Th disequilibria growth laminae ages of young, white stalagmites and of older stalagmites on which they grew, plus published Holocene stalagmite ages of initiation and regrowth from Missouri caves, are all coincident with suspected NMSZ earthquakes based on liquefaction and other paleoseimic techniques. We hypothesize that these speleothems were initiated by earthquake-induced opening/closing of fracture-controlled flowpaths in the ceilings of cave passages.

Sediment transport time measured with U-Series isotopes: Resultsfrom ODP North Atlantic Drill Site 984

DOE Office of Scientific and Technical Information (OSTI.GOV)

DePaolo, Donald J.; Maher, Kate; Christensen, John N.

High precision uranium isotope measurements of marineclastic sediments are used to measure the transport and storage time ofsediment from source to site of deposition. The approach is demonstratedon fine-grained, late Pleistocene deep-sea sediments from Ocean DrillingProgram Site 984A on the Bjorn Drift in the North Atlantic. The sedimentsare siliciclastic with up to 30 percent carbonate, and dated by sigma 18Oof benthic foraminifera. Nd and Sr isotopes indicate that provenance hasoscillated between a proximal source during the last three interglacialperiods volcanic rocks from Iceland and a distal continental sourceduring glacial periods. An unexpected finding is that the 234U/238Uratios of the silicatemore » portion of the sediment, isolated by leaching withhydrochloric acid, are significantly less than the secular equilibriumvalue and show large and systematic variations that are correlated withglacial cycles and sediment provenance. The 234U depletions are inferredto be due to alpha-recoil loss of234Th, and are used to calculate"comminution ages" of the sediment -- the time elapsed between thegeneration of the small (<_ 50 mu-m) sediment grains in the sourceareas by comminution of bedrock, and the time of deposition on theseafloor. Transport times, the difference between comminution ages anddepositional ages, vary from less than 10 ky to about 300 to 400 ky forthe Site 984A sediments. Long transport times may reflect prior storagein soils, on continental shelves, or elsewhere on the seafloor. Transporttime may also be a measure of bottom current strength. During the mostrecent interglacial periods the detritus from distal continental sourcesis diluted with sediment from Iceland that is rapidly transported to thesite of deposition. The comminution age approach could be used to dateQuaternary non-marine sediments, soils, and atmospheric dust, and may beenhanced by concomitant measurement of 226Ra/230Th, 230Th/234U, andcosmogenic nuclides.« less

Secondary Fe- and Mn-Oxides Associated with Faults Near Moab, Utah: Records of Past Fluid Flow

NASA Astrophysics Data System (ADS)

Garcia, V. H.; Reiners, P. W.

2015-12-01

Secondary Fe- and Mn-oxides are locally common near faults and fractures, and as cements within sandstones of the Colorado Plateau, and provide evidence of past fluid-flow. Here we describe textural, mineralogic, and geochronologic observations from fault-zone Fe- and Mn-oxide mineralization in Flat Iron Mesa, near Moab, Utah. Several hypotheses have been proposed for their origin, including reactions associated with the mixing of deep reduced and near-surface oxygenated waters. We integrate field observations, detailed SEM and petrographic observations, geochemical models, (U-Th)/He and Ar/Ar dating, and other data to develop interpretations of the formation of these deposits. SEM imaging shows that sandstone matrix cement adjacent to the faults follows two precipitation sequences: Fe-oxide followed by barite and Fe-oxide followed by Mn-oxide. Dense oxide layers also accumulated in cm-scale fractures near faults, and show the following precipitation sequence: Fe-oxide, barite, Ba rich Mn-oxide, and pure Mn-oxide. The latter sequence is observed at larger scale across faults in one site in Flat Iron Mesa. Our new He dates for Mn-oxides are 1.7-2.9 Ma while Fe-oxide dates are 2.7-3.0 Ma. If these dates represent formation ages, they are consistent with the interpreted precipitation sequence but would require protracted mineralization over Ma-timescales. Alternatively, they may represent varying degrees of He retentivity in earlier formed deposits. Previous Ar/Ar dates have been interpreted as a 20-25 Ma formation age. Ongoing Ar/Ar and He diffusion studies will resolve this discordance. Assuming the previous Ar dates do not reflect contamination by detrital K-bearing phases and do reflect oxide formation, potential interpretations for the younger He ages include recent U-Th addition, recrystallization, later oxide growth, or large diffusive He loss at low temperatures.

Glaciation control of melting rates in the mantle: U-Th systematics of young basalts from Southern Siberia and Central Mongolia

NASA Astrophysics Data System (ADS)

Rasskazov, S.; Chebykin, E.

2012-04-01

Eastern Sayans, Siberia and Hangay, Central Mongolia are mountainous uplifts effected by Quaternary volcanism, but only the former area was covered by glaciers that were as thick as 500 m. Glaciation time intervals were marked by moraines and sub-glacial hyaloclastite-bearing volcanic edifices, whereas interglacial ones were exhibited by sub-aerial "valley" flows and cinder cones. To estimate temporal variations of maximum rates of melting and mantle upwelling in the glacial and glacial-free areas, we measured radionuclides of the U-Th system for 74 samples of the Middle-Late Pleistocene through Holocene basalts by ICP-MS technique (Chebykin et al. Russian Geol. Geophys. 2004. 45: 539-556) using mass-spectrometer Agilent 7500ce. The obtained U-Th isochron ages for the Pleistocene volcanic units in the age interval of the last 400 Kyr are mostly consistent with results of K-Ar dating. The measured (230Th/238U) ratios for the Holocene basalts from both areas are within the same range of 1.08-1.16 (parentheses denote units of activity), whereas the 50 Kyr lavas yield, respectively, the higher and lower initial (230Th0/238U) ratios (1.18-1.46 and 1.05-1.13). This discrepancy demonstrates contrast maximum rates of melting in conventional garnet peridotite sources. We suggest that this dynamical feature was provided by the abrupt Late Pleistocene deglaciation that caused the mantle decompression expressed by the earlier increasing melting beneath Eastern Sayans than beneath Hangay. In the last 400 Kyr, magmatic liquids from both Eastern Sayans and Hangay showed the overall temporal decreasing (230Th0/238U) (i.e. relative increasing rates of melting and upwelling of the mantle) with the systematically lower isotopic ratios (i.e. increased mantle activity) in the former area than in the latter. The 400 Kyr phonotephrites in Hangay showed elevated concentrations of Th (6-8 ppm) and Th/U (3.7-3.9). The high (230Th0/238U) (4.3-6.0) reflected slow fractional melting, accompanied by rapid removal of melts. In episodes of 50-35 and ~9 Kyr, the ratio decreased from interval 1.23-1.52 to 1.08-1.22, indicating a relative increase of the porosity, maximum rates of melting, and upwelling of the mantle. The 350 Kyr magmatic melts in Eastern Sayans revealed the lower concentrations of Th (~2 ppm) and Th/U (2.7-2.9) due to more depleted composition of the source region, but their high (230Th0/238U) (2.7-2.9) also demonstrated slow fractional melting and upwelling. The defined maxima of melting and upwelling of the mantle beneath this area at 170 and 50 Kyr (Mmax = 1.1 × 10-3 kg/m3/yr, Wmax = 11 cm yr-1) were separated from each other by a minimum at 150 Kyr. These variations are interpreted in terms of temporal control of the mantle dynamic parameters by growing and thawing glaciers. The work was supported by the Russian Federal Aim Program "Scientific and scientific-pedagogical personnel of innovative Russia" for 2009-2013, the state contract number P736.

A test of uranium-series dating of fossil tooth enamel: results from Tournal Cave, France

USGS Publications Warehouse

Bischoff, J.L.; Rosenbauer, R.J.; Tavoso, A.; de Lumley, Henry

1988-01-01

A series of well preserved mammal bones and horse teeth was analyzed from archaeological levels of Tournal Cave (Magdalenian, Aurignacian, and Mousterain) to test the hypothesis that well-crystallized enamel behaves more as a closed system than does whole bone. The isotopic composition of bones and tooth enamels from this deposit meet criteria for confidence, and gave no reasons to suspect contamination or open-system behavior. Two samples for which 231Pa could be analyzed showed internal concordance with the respective 230Th ages. In spite of the favourable isotopic criteria, however, comparison of the U-series ages of the bones and the tooth enamel with stratigraphic position and 14C control indicated the dates were not meaningful. In general, both bones and tooth enamels gave ages too young, although some were clearly too old. Neither group showed any systematic increase of age with stratigraphic depth. Tooth enamel, therefore, shows no advantage over bone for U-series dating for this site. In Tournal cave both bones and enamel are apparently open to U, which is probably cycling as a consequences of post-depositional groundwater movement. ?? 1988.

Sea level high stand in Marine Isotope Stage 5e: evidence from coral terraces in Sumba Island, Indonesia

NASA Astrophysics Data System (ADS)

LU, Y.; Rigaud, S.; Leclerc, F.; Liu, X.; Chiang, H. W.; Djamil, Y. S.; Meilano, I.; Bijaksana, S.; Abidin, H. Z.; Tapponnier, P.; Wang, X.

2017-12-01

Uplifted coral reef terraces, possibly spanning the last one million years, are extensively exposed along the northern coast of Sumba Island, Indonesia. We collected a suite of fossil coral samples from the inner edges of terraces at Cape Laundi to study past sea level change, particularly that during the marine isotope stage 5e. These samples were dated by the high-precision U/Th disequilibrium dating methods. For those with δ234U-initial values beyond the range of 145±7‰[1,2] , the open-system model by Thompson et al. [3] was then applied to correct their ages. Only less than 20% of the samples could not derive reasonable ages after the correction, and their abnormally high δ234U-initial values (> 180‰) seem to suggest a limitation of open-system correction with the current model. After the correction of long-term uplift rate of 0.3 mm/kyr, we found that the relative sea level at Cape Laundi, Sumba was 7 m during MIS5e and then dropped to -20 m during the MIS5a and 5c. More importantly, our results indicate that sea level reached a high stand at 129±0.6 ka, supported by both U/Th dates on pristine corals and open-system model corrected ages. In line with the sea level reconstruction from western Australia, our results do not support a second and higher sea level during MIS5e. Moreover, there is no significant lead or lag between the timing of sea level high stand in Sumba and the peak of Northern Hemisphere summer insolation. 1. Robinson et al. (2004) Science. 305: 851-854 2. Cheng et al. (2013) Earth and Planetary Science Letters. 371-372: 82-91 3. Thompson et al. (2003) Earth and Planetary Science Letters. 210: 365-381

Combined dendrochronological and radiocarbon dating of six Russian icons from the 15th-17th centuries

NASA Astrophysics Data System (ADS)

Dolgikh, A. V.; Matskovsky, V. V.; Voronin, K. V.; Solomina, O. N.

2017-06-01

The results of dendrochronological and radiocarbon dating by means of accelerator mass spectrometry (AMS) of six medieval icons, originating from northern European Russia and painted on wooden panels made from Scots pine, dated to the 15th to 17th centuries are presented. The panels of each icon were studied using dendrochronology. Five to six AMS dates were obtained for four icons. Although five icons were dendro-dated successfully, one failed to be reliably cross-dated with the existing master tree-ring chronologies and it was dated by radiocarbon wiggle-matching. Dendrochronological dating and wiggle-matching of radiocarbon dates allowed us to determine the narrow chronological intervals of icon creation.

High precision thorium-230 ages of corals and the timing of sea level fluctuations in the late Quaternary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, R.L.

1988-01-01

Mass spectrometric techniques for the measurement of {sup 230}Th and {sup 234}U have been developed. These techniques have made it possible to reduce the analytical errors in {sup 230}Th dating of corals using very small samples (10{sup 7} to 10{sup 10} atoms). The time range over which useful data on corals can now be obtained ranges from 15 to 500,000 years. For young corals, this approach may be preferable to {sup 14}C dating. The precision with which the age of a coral can not be determined makes it possible to determine the timing of sea level fluctuations in the latemore » Quaternary. Analyses of a number of corals that grew during the last interglacial period yield ages of 122 to 130 ky. The ages coincide with or slightly postdate the summer solar insolation high at 65{degree}N latitude, which occurred 128 ky ago. This supports the idea that changes in Pleistocene climate can be the result of orbital forcing. Coral ages may allow us to resolve the ages of individual coseismic uplift events and thereby date prehistoric earthquakes. This possibility has been examined at two localities, northwest Santo Island and north Malekula Island, Vanuatu. The {sup 230}Th growth dates of the surfaces of adjacent emerged coral heads, collected from the same elevation on northwest Santo Island, were, within analytical error, identical (A.D. 1866 {plus minus} 4 and A.D. 1864 {plus minus} 4). This indicates that the corals died at the same time and is consistent with the idea that they were killed by coseismic uplift. Similar adjacent coral heads on north Malekula Island yielded {sup 230}Th growth dates of A.D. 1729 {plus minus} 3 and A.D. 1718 {plus minus} 5. The ages are similar but analytically distinguishable. The difference may be due to erosion of the outer, younger, portion of the latter coral head.« less

Phanerozoic burial and unroofing history of the western Slave craton and Wopmay orogen from apatite (U-Th)/He thermochronometry

NASA Astrophysics Data System (ADS)

Ault, Alexis K.; Flowers, Rebecca M.; Bowring, Samuel A.

2009-06-01

Low temperature thermochronometry of cratonic regions can illuminate relationships among burial and unroofing patterns, surface subsidence and uplift, and lithosphere-asthenosphere interactions. The Slave craton, initially stabilized by the development of a thick lithospheric mantle root in late Archean time, is an excellent location in which to examine these connections. Although the Slave craton currently lacks Phanerozoic cover, Phanerozoic sedimentary xenoliths entrained in ca. 610 to 45 Ma kimberlites indicate that the region underwent a more dynamic history of burial and unroofing than widely recognized. We report new apatite (U-Th)/He thermochronometry data along a southeast to northwest transect from the interior of the Slave craton into the adjacent Paleoproterozoic Wopmay orogen to resolve the region's depositional and denudational history. Six samples from the western Slave craton and three samples from Wopmay orogen yield mean dates from 296 ± 41 Ma to 212 ± 39 Ma. Individual apatite dates are broadly uniform over a wide span of apatite [eU], and this pattern can be used to more tightly restrict the spectrum of viable temperature-time paths that can explain the dataset. When coupled with geologic and stratigraphic information, temperature-time simulations of the thermochronometry results suggest complete He loss from the apatites at minimum peak temperatures of ~ 88 °C in Devonian-Pennsylvanian time, cooling to near-surface conditions by the Early Cretaceous, followed by reheating to ≤ 72 °C during Cretaceous-Early Tertiary time. Consideration of modern and ancient geotherm constraints implies ≥ 3.3 km of burial during the first Phanerozoic heating phase, with an ancillary phase of reburial in late Mesozoic-Cenozoic time. The uniformity of the apatite (U-Th)/He dates indicates that the rocks encompassed by our > 250 km-long sample transect experienced similar Phanerozoic thermal histories. Despite the distinctly different lithospheric architecture on either side of the Paleoproterozoic suture between the Slave craton and Wopmay orogen, the region behaved as a single, broadly coherent cratonic unit since at least ca. 250 Ma. The Phanerozoic burial and unroofing patterns across the craton may be a response to far-field convergent activity at the northern and western margins of North America and processes associated with episodic kimberlite emplacement.

Mineralogy of selected sedimentary interbeds at or near the Idaho National Engineering Laboratory, Idaho

USGS Publications Warehouse

Reed, Michael F.; Bartholomay, Roy C.

1994-01-01

The U.S. Geological Survey (USGS) Project Office at the Idaho National Engineering Laboratory (INEL), in cooperation with the U.S. Department of Energy and Idaho State University, analyzed 66 samples from sedimentary interbed cores during a 38-month period beginning in October 1990 to determine bulk and clay mineralogy. These cores had been collected from 19 sites in the Big Lost River Basin, 2 sites in the Birch Creek Basin, and 1 site in the Mud Lake Basin, and were archived at the USGS lithologic core library at the INEL. Mineralogy data indicate that the core samples from the Big Lost River Basin have larger mean and median percentages of quartz, total feldspar, and total clay minerals, but smaller mean and median percentages of calcite than the core samples from the Birch Creek Basin. Core samples from the Mud Lake Basin have abundant quartz, total feldspar, calcite, and total clay minerals.

Radiometric dating of the Siloam Tunnel, Jerusalem.

PubMed

Frumkin, Amos; Shimron, Aryeh; Rosenbaum, Jeff

2003-09-11

The historical credibility of texts from the Bible is often debated when compared with Iron Age archaeological finds (refs. 1, 2 and references therein). Modern scientific methods may, in principle, be used to independently date structures that seem to be mentioned in the biblical text, to evaluate its historical authenticity. In reality, however, this approach is extremely difficult because of poor archaeological preservation, uncertainty in identification, scarcity of datable materials, and restricted scientific access into well-identified worship sites. Because of these problems, no well-identified Biblical structure has been radiometrically dated until now. Here we report radiocarbon and U-Th dating of the Siloam Tunnel, proving its Iron Age II date; we conclude that the Biblical text presents an accurate historic record of the Siloam Tunnel's construction. Being one of the longest ancient water tunnels lacking intermediate shafts, dating the Siloam Tunnel is a key to determining where and when this technological breakthrough took place. Siloam Tunnel dating also refutes a claim that the tunnel was constructed in the second century bc.

Paleoclimatic Inferences from a 120,000-Yr Calcite Record of Water-Table Fluctuation in Browns Room of Devils Hole, Nevada

USGS Publications Warehouse

Szabo, B. J.; Kolesar, Peter T.; Riggs, A.C.; Winograd, I.J.; Ludwig, K. R.

1994-01-01

The petrographic and morphologic differences between calcite precipitated below, at, or above the present water table and uranium-series dating were used to reconstruct a chronology of water-table fluctuation for the past 120,000 yr in Browns Room, a subterranean air-filled chamber of Devils Hole fissure adjacent to the discharge area of the large Ash Meadows groundwater flow system in southern Nevada. The water table was more than 5 m above present level between about 116,000 and 53,000 yr ago, fluctuated between about +5 and +9 m during the period between about 44,000 and 20,000 yr ago, and declined rapidly from +9 to its present level during the past 20,000 yr. Because the Ash Meadows groundwater basin is greater than 12,000 km2 in extent, these documented water-table fluctuations are likely to be of regional significance. Although different in detail, water-level fluctuation recorded by Browns Room calcites generally correlate with other Great Basin proxy palcoclimatic data.

Raman spectroscopic analysis of a belltower commemorative wall decoration

NASA Astrophysics Data System (ADS)

Fernandes, R. F.; de Oliveira, L. F. C.; Edwards, H. G. M.; Brooke, C. J.; Pepper, M.

2017-02-01

The Raman spectroscopic analysis of a rare wall decoration in a church belltower, depicting the initials of couples married there in circular roundels over some 230 years, since 1777, has been undertaken prior to their impending restoration. The spectral data indicate that the red pigment is exclusively haematite which has been applied to plaster which exhibits the signatures variously of calcite, gypsum, anhydrite, calcium phosphate and dolomitic limestone; evidence of amorphous carbon is attributed to the deposition of soot from candle illumination, which has been recorded in historical documentation. The presence of biosignatures attributed to carotenoids in several samples is evidence of biological colonisation and potential deterioration which requires special treatment in the restoration strategies. The blackened areas near the upper edges of the wall decoration indicate carbon deposition and organic contamination. The latest addition to the decoration accomplished in 2008 shows that haematite has been used over a calcite ground. In earlier dated specimens, the presence of limewash is evident, which has only been partially converted into calcite by aerial attack from carbon dioxide in moist conditions.

Pollen from accurately dated speleothems supports alpine glacier low-stands during the early Holocene

NASA Astrophysics Data System (ADS)

Festi, Daniela; Hoffmann, Dirk L.; Luetscher, Marc

2016-07-01

Deciphering pollen assemblages from alpine speleothems holds potential to provide unique information about past vegetation in rapidly changing environments. Here, we reconstruct subsurface aerosol transport at Milchbach cave (Switzerland, 1840 m asl) based on the pollen content of two Holocene stalagmites. We demonstrate that pollen is chiefly associated with bacterially mediated calcite fabrics, typical of a well-ventilated cave system. In contrast, pollen is absent from columnar calcite fabrics confirming that hydrological transport is not a significant process for the incorporation of pollen into speleothems at Milchbach cave. Our results support significant changes in the subsurface ventilation regime, which can be associated with the waxing and waning of Upper Grindelwald glacier. Pollen assemblages obtained from six carbonate sub-samples attest the presence of a mixed deciduous forest in the Grindelwald valley during the early and middle Holocene, in agreement with coeval regional pollen records. This study demonstrates that even small amounts of calcite (0.3-2.8 cm3) are capable of delivering pollen spectra representative of the original vegetation if sufficiently elevated deposition fluxes are provided.

Tracking the multiple-stage exhumation history and magmatic-hydrothermal events of the West Junggar region, NW China: Evidence from 40Ar/39Ar and (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Yin, Jiyuan; Chen, Wen; Xiao, Wenjiao; Long, Xiaoping; Tao, Ni; Liu, Li-Ping; Yuan, Chao; Sun, Min

2018-06-01

To decipher cooling events in the West Junggar region, biotite and K-feldspar 40Ar/39Ar, and zircon and apatite (U-Th)/He isotopic analyses of intrusive rocks were carried out. Previous U-Pb data showed that intrusive bodies in the Baogutu area were emplaced at 315-310 Ma. U-Pb and zircon (U-Th)/He dating results (313-241 Ma) suggest that a magmatic-hydrothermal event lasted for 72 Ma in the Baogutu area of the West Junggar region. Early-stage high temperature alteration (900-300 °C) lasted for 6-2 Ma and was followed by prolonged phyllic and argillic alteration lasting 67-63 Ma between 350 and 200 °C. Finally, slower cooling occurred between 200 and 70 °C, accompanied by post-mineralization uplift and erosion. In this study, three main episodes of relatively rapid cooling were distinguished in the West Junggar region, i.e. late Carboniferous-early Permian (307-277 Ma), middle Triassic (241-232 Ma) and early Cretaceous (145-120 Ma). The first rapid cooling during the late Carboniferous-early Permian was possibly associated with the release of magmatic heat. The middle Triassic and early Cretaceous cooling and exhumation are interpreted as a response to collision(s) between the Qiangtang and Kunlun-Qaidam or Lhasa blocks. The Cenozoic India-Eurasia collision, however, may have had little or no effect on modern tectonic reactivation of the West Junggar region.

The Submarine 4-km diameter Corossol Crater, Eastern Canada: Evidence for an impact origin

NASA Astrophysics Data System (ADS)

Higgins, Michael D.; Lajeunesse, Patrick; St-Onge, Guillaume; Locat, Jacques; Sanfacon, Richard; Duchesne, Mathieu J.

2014-05-01

The newly-discovered Corossol Crater lies in the northwestern Gulf of St. Lawrence (Eastern Canada; 50°3'N, 66°23'W) and was found in 40-185 metres of water using high-resolution multibeam sonar. It is a 4 km in diameter complex circular structure with a central uplift and concentric rings. Glacial resurfacing indicates that it predates the last phase of glaciation in this area. Dredging on the central uplift recovered many angular clasts of hard grey limestone, which forms the bedrock in much of this area. One 4 cm clast of limestone breccia is somewhat different from the other blocks and has characteristics that suggest that it is an impact breccia. The block comprises fragments of calcite limestone up to 2 mm long. In many parts of the block these fragments have thin black rims. At the edges of the block these rims are brown, presumably reflecting aqueous alteration. Mineral grains in the rims are too small to characterize, but the fact that the ensemble can be oxidized suggests that it contains sulfides. In places the block is cut by veins of fine-grained calcite with euhedral dolomite crystals. The most unusual component is rare droplets up to 2 mm long, commonly fragmented. The droplets comprise a glassy matrix with a composition very close to fluorapatite and opaque crystals that have a composition close to pyrite. A few droplets have up to 5% vesicles. Fluorapatite requires fusion temperatures of about 1600 C, which cannot be achieved at the surface of the Earth by endogenous processes. A single fragmented quartz crystal with planar features was found close to one droplet. Universal stage measurements of the orientation of the planar features give an angle of 42 degrees which is close to that of {10-13} planes. This is the most common set of deformation planes produced during shock metamorphism of quartz. Unfortunately no other grains were found with similar planes. The glassy droplets and shocked quartz together suggest that the clast was produced by an impact, and hence that it is very likely that the Corossol Crater in which the clast was found is an astrobleme. The absolute age of this structure is unknown, but its geological setting indicates that it was formed long after the Mid-Ordovician and possibly before regional pre-Quaternary sea-level lowstand. We are now attempting to obtain a U-Th helium age for the droplets which will date the impact event.

Variations of uranium concentrations in a multi-aquifer system under the impact of surface water-groundwater interaction

NASA Astrophysics Data System (ADS)

Wu, Ya; Li, Junxia; Wang, Yanxin; Xie, Xianjun

2018-04-01

Understanding uranium (U) mobility is vital to minimizing its concentrations in potential drinking water sources. In this study, we report spatial-seasonal variations in U speciation and concentrations in a multi-aquifer system under the impact of Sanggan River in Datong basin, northern China. Hydrochemical and H, O, Sr isotopic data, thermodynamic calculations, and geochemical modeling are used to investigate the mechanisms of surface water-groundwater mixing-induced mobilization and natural attenuation of U. In the study site, groundwater U concentrations are up to 30.2 μg/L, and exhibit strong spatial-seasonal variations that are related to pH and Eh values, as well as dissolved Ca2+, HCO3-, and Fe(III) concentrations. For the alkaline aquifers of this site (pH 7.02-8.44), U mobilization is due to the formation and desorption of Ca2UO2(CO3)30 and CaUO2(CO3)32- caused by groundwater Ca2+ elevation via mineral weathering and Na-Ca exchange, incorporated U(VI) release from calcite, and U(IV) oxidation by Fe(OH)3. U immobilization is linked to the adsorption of CaUO2(CO3)32- and UO2(CO3)34- shifted from Ca2UO2(CO3)30 because of HCO3- elevation and Ca2+ depletion, U(VI) co-precipitation with calcite, and U(VI) reduction by adsorbed Fe2+ and FeS. Those results are of great significance for the groundwater resource management of this and similar other surface water-groundwater interaction zones.

Isotope geochemistry and fluid inclusion study of skarns from Vesuvius

USGS Publications Warehouse

Gilg, H.A.; Lima, A.; Somma, R.; Belkin, H.E.; de Vivo, B.; Ayuso, R.A.

2001-01-01

We present new mineral chemistry, fluid inclusion, stable carbon and oxygen, as well as Pb, Sr, and Nd isotope data of Ca-Mg-silicate-rich ejecta (skarns) and associated cognate and xenolithic nodules from the Mt. Somma-Vesuvius volcanic complex, Italy. The typically zoned skarn ejecta consist mainly of diopsidic and hedenbergitic, sometimes "fassaitic" clinopyroxene, Mg-rich and Ti-poor phlogopite, F-bearing vesuvianite, wollastonite, gehlenite, meionite, forsterite, clinohumite, anorthite and Mg-poor calcite with accessory apatite, spinell, magnetite, perovskite, baddeleyite, and various REE-, U-, Th-, Zr- and Ti-rich minerals. Four major types of fluid inclusions were observed in wollastonite, vesuvianite, gehlenite, clinopyroxene and calcite: a) primary silicate melt inclusions (THOM = 1000-1050??C), b) CO2 ?? H2S-rich fluid inclusions (THOM = 20-31.3??C into the vapor phase), c) multiphase aqueous brine inclusions (THOM = 720-820??C) with mainly sylvite and halite daughter minerals, and d) complex chloride-carbonate-sulfate-fluoride-silicate-bearing saline-melt inclusions (THOM = 870-890??C). The last inclusion type shows evidence for immiscibility between several fluids (silicate melt - aqueous chloride-rich liquid - carbonate/sulfate melt?) during heating and cooling below 870??C. There is no evidence for fluid circulation below 700??C and participation of externally derived meteoric fluids in skarn formation. Skarns have considerably variable 206Pb/204Pb (19.047-19.202), 207Pb/204Pb (15.655-15.670), and 208Pb/204Pb (38.915-39.069) and relatively low 143Nd/144Nd (0.51211-0.51244) ratios. The carbon and oxygen isotope compositions of skarn calcites (??13CV-PDB = -5.4 to -1.1???; ??18OV-SMOW = 11.7 to 16.4???) indicate formation from a 18O- and 13C-enriched fluid. The isotope composition of skarns and the presence of silicate melt inclusion-bearing wollastonite nodules suggests assimilation of carbonate wall rocks by the alkaline magma at moderate depths (< 5 km) and consequent exsolution of CO2-rich vapor and complex saline melts from the contaminated magma that reacted with the carbonate rocks to form skarns.

Petrography, geochemistry and U-Pb zircon age of the Matongo carbonatite Massif (Burundi): Implication for the Neoproterozoic geodynamic evolution of Central Africa

NASA Astrophysics Data System (ADS)

Midende, Gilbert; Boulvais, Philippe; Tack, Luc; Melcher, Frank; Gerdes, Axel; Dewaele, Stijn; Demaiffe, Daniel; Decrée, Sophie

2014-12-01

The Matongo carbonatite intrusion belongs to the Neoproterozoic Upper Ruvubu alkaline plutonic complex (URAPC), that is located in Burundi along the western branch of the East African Rift. Beside the Matongo carbonatite, the URAPC alkaline complex comprises feldspathoidal syenites, diorites, quartz-bearing syenites and granites. Three main facies have been recognized in the Matongo carbonatite: (1) Sövites represent the dominant facies. Two varieties have been recognized. A scarce coarse-grained sövite (sövite I), which is altered and poorly enriched in REE (4 < ΣREE < 8 ppm), is encountered in highly fractured zones. A fine-grained sövite (sövite II), which is made of saccharoidal calcite, commonly associated with apatite, aegirine and amphibole, is abundant in the intrusion. Sövite II is enriched in LREE (442 < ΣREE < 1550 ppm, 49 < LaN/YbN < 175). (2) Ferrocarbonatites, that form decimeter-wide veins crosscutting the sövites, are characterized by a LREE enriched patterns (225 < ΣREE < 1048 ppm, 17 < LaN/YbN < 64). (3) K-feldspar and biotite-rich fenite facies (silicocarbonatites) have been recognized at the contact between the carbonatites and the country rock. They are likewise LREE-enriched (134 < ΣREE < 681 ppm, 25 < LaN/YbN < 46). Additionaly, "late" hydrothermal MREE-rich carbonatite veinlets can be found in sövite I. They are characterized by moderate enrichment in REE (ΣREE = 397 ppm), with a MREE-humped pattern (LaN/YbN = 3.7). The different facies represent the typical magmatic evolution of a carbonatite, while the silicocarbonatites are interpreted as resulting from the fenitisation of the country host-rocks. In addition, the most REE-depleted and fractionated facies, i.e. the coarse-grained sövite facies and the "late" calcite veinlets testify for hydrothermal processes that occurred after carbonatite emplacement and result from REE mobilization and redistribution. Large idiomorphic zircon crystals (megacrysts), found in the vicinity of the carbonatite can directly be related to the carbonatite evolution. They have been dated at 705.5 ± 4.5 Ma (U-Pb concordant age, LA-ICP-MS). Similar zircon megacrysts of the Lueshe carbonatite (DRCongo) have been dated and give a concordant age at 798.5 ± 4.9 Ma (U-Pb, LA-ICP-MS). Considering that an extensional tectonic regime occured at that time in Central Africa - what remains debated - both ages could relate to different stages of Rodinia breakup, with uprise of mantle-derived magmas along Palaeoproterozoic lithospheric zones of weakness.

Environmental evolution records reflected by radionuclides in the sediment of coastal wetlands: A case study in the Yellow River Estuary wetland.

PubMed

Wang, Qidong; Song, Jinming; Li, Xuegang; Yuan, Huamao; Li, Ning; Cao, Lei

2016-10-01

Vertical profiles of environmental radionuclides ( 210 Pb, 137 Cs, 238 U, 232 Th, 226 Ra and 4 0 K) in a sediment core (Y1) of the Yellow River Estuary wetland were investigated to assess whether environmental evolutions in the coastal wetland could be recorded by the distributions of radionuclides. Based on 210 Pb and 137 Cs dating, the average sedimentation rate of core Y1 was estimated to be 1.0 cm y -1 . Vertical distributions of natural radionuclides ( 238 U, 232 Th, 226 Ra and 40 K) changed dramatically, reflecting great changes in sediment input. Concentrations of 238 U, 232 Th, 226 Ra and 40 K all had significant positive relationships with organic matter and clay content, but their distributions were determined by different factors. Factor analysis showed that 238 U was determined by the river sediment input while 226 Ra was mainly affected by the seawater erosion. Environmental changes such as river channel migrations and sediment discharge variations could always cause changes in the concentrations of radionuclides. High concentrations of 238 U and 226 Ra were consistent with high accretion rate. Frequent seawater intrusion decreased the concentration of 226 Ra significantly. The value of 238 U/ 226 Ra tended to be higher when the sedimentation rate was low and tide intrusion was frequent. In summary, environmental evolutions in the estuary coastal wetland could be recorded by the vertical profiles of natural radionuclides. Copyright © 2016 Elsevier Ltd. All rights reserved.

Intra-grain Common Pb Correction and Detrital Apatite U-Pb Dating via LA-ICPMS Depth Profiling

NASA Astrophysics Data System (ADS)

Boyd, P. D.; Galster, F.; Stockli, D. F.

2017-12-01

Apatite is a common accessory phase in igneous and sedimentary rocks. While apatite is widely employed as a low-temperature thermochronometric tool, it has been increasingly utilized to constrain moderate temperature cooling histories by U-Pb dating. Apatite U-Pb is characterized by a thermal sensitivity window of 375-550°C. This unique temperature window recorded by the apatite U-Pb system, and the near-ubiquitous presence of apatite in igneous and clastic sedimentary rocks makes it a powerful tool able to illuminate mid-crustal tectono-thermal processes. However, as apatite incorporates only modest amounts of U and Th (1-10s of ppm) the significant amounts of non-radiogenic "common" Pb incorporated during its formation presents a major hurdle for apatite U-Pb dating. In bedrock samples common Pb in apatite can be corrected for by the measurement of Pb in a cogenetic mineral phase, such as feldspar, that does not incorporate U or from determination of a common Pb composition from multiple analyses in Tera-Wasserburg space. While these methods for common Pb correction in apatite can work for igneous samples, they cannot be applied to detrital apatite in sedimentary rocks with variable common Pb compositions. The obstacle of common Pb in apatite has hindered the application of detrital apatite U-Pb dating in provenance studies, despite the fact that it would be a powerful tool. This study presents a new method for the in situ correction of common Pb in apatite through the utilization of novel LA-ICP-MS depth profiling, which can recover U-Pb ratios at micron-scale spatial resolution during ablation of a grain. Due to the intra-grain U variability in apatite, a mixing line for a single grain can be generated in Tera-Wasserburg Concordia space. As a case study, apatite from a Variscan alpine granite were analyzed using both the single and multi-grain method, with both methods giving identical results. As a second case study the intra-grain method was then performed on detrital apatite from the Swiss Northern Alpine Foreland Basin, where the common Pb composition and age spectra of detrital apatite grains were elucidated. The novel intra-grain apatite method enables the correction for common Pb in detrital apatite, making it feasible to incorporate detrital apatite U-Pb dating in provenance and source-to-sink studies.

Microstructural analysis of calcite-filled fractures inherited from basement structures, southern Ontario, Canada: long term instability of the craton?

NASA Astrophysics Data System (ADS)

Spalding, Jennifer; Schneider, David

2016-04-01

Intra-cratonic regions are generally characterized by tectonic stability and low seismicity. In southern Ontario, Canada, moderate levels of seismicity have been recorded over the last few decades reaching magnitudes of 5 MN, indicating that the geosphere is not as stable as predicted. The stratigraphy of the region consists of Ordovician limestone with a thickness of ~200 m that unconformably overlays the Mesoproterozoic crystalline Grenville Province. Subsequent tectonism including repeated Paleozoic orogenies and rifting along the east coast of North America has reactivated Proterozoic structures that have propagated into the overlying carbonate platform forming mesoscopic-scale brittle structures. Exposed along the shores of Lake Ontario are decameter-scale fracture zones, with a fracture spacing of 0.5 to 10 meters. The dominant fracture set trends E-W, and often forms conjugate sets with less prominent NNE-oriented fractures. More locally, an older NW-oriented fracture set is cross cut by the E-W and NNE oriented fractures. Regionally, there have been six directions of maximum horizontal stress in southern Ontario since the Precambrian, with the current orientation of maximum stress oriented ENE as a consequence of far field Atlantic ridge-push forces generated at distant plate boundaries. Calcite mineralization along fractured surfaces locally form sub-horizontal slickenside fabrics which are covered by a layer of euhedral calcite crystals, suggesting that fracture dilation (and fluid flow) occurred after fracture slip to allow the growth of calcite crystals. Due to the proximity of the carbonate units to the crystalline basement, we expect the calcitic veins to be enriched in rare earth elements and are presently conducting geochemical analyses. The calcite veins and surfaces vary from 2.5 cm to 1 mm thicknesses, often with larger calcite crystals in the center of the vein and smaller crystals at the vein boundaries, likely representing nucleation on small grains of the wall rock. Some veins show minor displacement, including the mm-scale with fractured and displaced fossil fragments, and cm-scale offsets at the outcrop. The calcite veins show evidence of low temperature deformation (~200°C) through undulous extinction, bulging grain boundaries, tension gashes structures, and extensive lamellar twinning. The width and density of twinning (twin planes/mm) provides information regarding the temperature of deformation. The calcite crystals show two populations of twinning: type I (>10 μm), and type II (tabular twinning) with an average thickness of 35 μm, and a maximum thickness of 81 μm. Twinning can only accommodate a limited amount of strain such that the calcite lamellar twinning is often kinked, broken and offset, suggesting reactivation of the calcite-filled fractures. U-Pb calcite ages from calcitic veins in the Ordovician units within the Ottawa graben are c. 400 Ma and within Devonian units at the edge of the Michigan Basin in Canada are c. 110 Ma. Additional geochronology on the calcite from southern Ontario will help resolve the timing of fracture reactivation and is an important factor in consideration of the location of a deep geological repository for Canada's nuclear waste.

Validation of reference materials for uranium radiochronometry in the frame of nuclear forensic investigations

DOE PAGES

Varga, Z.; Mayer, K.; Bonamici, C. E.; ...

2015-05-11

The results of a joint effort by expert nuclear forensic laboratories in the area of age dating of uranium, i.e. the elapsed time since the last chemical purification of the material are presented and discussed. Completely separated uranium materials of known production date were distributed among the laboratories, and the samples were dated according to routine laboratory procedures by the measurement of the ²²⁰Th/²³⁴U ratio. The measurement results were in good agreement with the known production date showing that the concept for preparing uranium age dating reference material based on complete separation is valid. Detailed knowledge of the laboratory proceduresmore » used for uranium age dating allows the identification of possible improvements in the current protocols and the development of improved practice in the future. The availability of age dating reference materials as well as the evolvement of the age dating best-practice protocol will increase the relevance and applicability of age dating as part of the tool-kit available for nuclear forensic investigations.« less

Validation of reference materials for uranium radiochronometry in the frame of nuclear forensic investigations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Varga, Z.; Mayer, K.; Bonamici, C. E.

The results of a joint effort by expert nuclear forensic laboratories in the area of age dating of uranium, i.e. the elapsed time since the last chemical purification of the material are presented and discussed. Completely separated uranium materials of known production date were distributed among the laboratories, and the samples were dated according to routine laboratory procedures by the measurement of the ²²⁰Th/²³⁴U ratio. The measurement results were in good agreement with the known production date showing that the concept for preparing uranium age dating reference material based on complete separation is valid. Detailed knowledge of the laboratory proceduresmore » used for uranium age dating allows the identification of possible improvements in the current protocols and the development of improved practice in the future. The availability of age dating reference materials as well as the evolvement of the age dating best-practice protocol will increase the relevance and applicability of age dating as part of the tool-kit available for nuclear forensic investigations.« less

Hydrothermal titanite from the Chengchao iron skarn deposit: temporal constraints on iron mineralization, and its potential as a reference material for titanite U-Pb dating

NASA Astrophysics Data System (ADS)

Hu, Hao; Li, Jian-Wei; McFarlane, Christopher R. M.

2017-09-01

Uranium-lead isotopes and trace elements of titanite from the Chengchao iron skarn deposit (Daye district, Eastern China), located along the contact zones between Triassic marine carbonates and an early Cretaceous intrusive complex consisting of granite and quartz diorite, were analyzed using laser ablation inductively coupled plasma mass spectrometry to provide temporal constraints on iron mineralization and to evaluate its potential as a reference material for titanite U-Pb geochronology. Titanite grains from mineralized endoskarn have simple growth zoning patterns, exhibit intergrowth with magnetite, diopside, K-feldspar, albite and actinolite, and typically contain abundant primary two-phase fluid inclusions. These paragenetic and textural features suggest that these titanite grains are of hydrothermal origin. Hydrothermal titanite is distinct from the magmatic variety from the ore-related granitic intrusion in that it contains unusually high concentrations of U (up to 2995 ppm), low levels of Th (12.5-453 ppm), and virtually no common Pb. The REE concentrations are much lower, as are the Th/U and Lu/Hf ratios. The hydrothermal titanite grains yield reproducible uncorrected U-Pb ages ranging from 129.7 ± 0.7 to 132.1 ± 2.7 Ma (2σ), with a weighted mean of 131.2 ± 0.2 Ma [mean standard weighted deviation (MSWD) = 1.7] that is interpreted as the timing of iron skarn mineralization. This age closely corresponds to the zircon U-Pb age of 130.9 ± 0.7 Ma (MSWD = 0.7) determined for the quartz diorite, and the U-Pb ages for zircon and titanite (130.1 ± 1.0 Ma and 131.3 ± 0.3 Ma) in the granite, confirming a close temporal and likely genetic relationship between granitic magmatism and iron mineralization. Different hydrothermal titanite grains have virtually identical uncorrected U-Pb ratios suggestive of negligible common Pb in the mineral. The homogeneous textures and U-Pb characteristics of Chengchao hydrothermal titanite suggest that the mineral might be a suitable internal reference material for U-Pb dating.

Weight perceptions, misperceptions, and dating violence victimization among U.S. adolescents.

PubMed

Farhat, Tilda; Haynie, Denise; Summersett-Ringgold, Faith; Brooks-Russell, Ashley; Iannotti, Ronald J

2015-05-01

Dating violence is a major public health issue among youth. Overweight/obese adolescents experience peer victimization and discrimination and may be at increased risk of dating violence victimization. Furthermore, given the stigma associated with overweight/obesity, perceptions and misperceptions of overweight may be more important than actual weight status for dating violence victimization. This study examines the association of three weight indices (weight status, perceived weight, and weight perception accuracy) with psychological and physical dating violence victimization. The 2010 baseline survey of the 7-year NEXT Generation Health Study used a three-stage stratified clustered sampling design to select a nationally representative sample of U.S. 10th-grade students (n = 1,983). Participants who have had a boyfriend/girlfriend reported dating violence victimization and perceived weight. Weight status was computed from measured height/weight. Weight perception accuracy (accurate/underestimate/overestimate) was calculated by comparing weight status and perceived weight. Gender-stratified regressions examined the association of weight indices and dating violence victimization. Racial/ethnic differences were also examined. The association of weight indices with dating violence victimization significantly differed by gender. Overall, among boys, no associations were observed. Among girls, weight status was not associated with dating violence victimization, nor with number of dating violence victimization acts; however, perceived weight and weight perception accuracy were significantly associated with dating violence victimization, type of victimization, and number of victimization acts. Post hoc analyses revealed significant racial/ethnic differences. White girls who perceive themselves (accurately or not) to be overweight, and Hispanic girls who are overweight, may be at increased risk of dating violence victimization. These findings suggest a targeted approach to dating violence victimization prevention. © The Author(s) 2014.

LA-ICP-MS Pb-U Dating of Young Zircons from the Kos-Nisyros Volcanic Centre, SE Aegean Arc (Greece)

NASA Astrophysics Data System (ADS)

Guillong, M.; Von Quadt, A.; Peytcheva, I.; Bachmann, O.

2014-12-01

Zircon Pb-U dating has become a key technique for answering many important questions in geosciences. This paper describes a new LA-ICP-MS approach. We show, using previously dated samples of a large quaternary rhyolitic eruption in the Kos-Nisyros volcanic centre (the 161 ka Kos Plateau Tuff), that the precision of our LA-ICP-MS method is as good as via SHRIMP, while ID-TIMS measurements confirm the accuracy. Gradational age distribution over >140 ka of the Kos zircons and the near-absence of inherited cores indicate near-continuous crystallisation in a growing magma reservoir with little input from wall rocks. Previously undated silicic eruptions from Nisyros volcano (Lower Pumice, Nikia Flow, Upper Pumice), which are stratigraphically constrained to have happened after the Kos Plateau Tuff, are dated to be younger than respectively 124 ± 35 ka, 111 ± 42 ka and 70 ± 24 ka. Samples younger than 1 Ma were corrected for initial thorium disequilibrium using a new formula that also accounts for disequilibrium in 230Th decay. Guillong, M. et al., 2014, JAAS, 29, p. 963-967; doi: 10.1039/c4ja00009a.

Pre-Variscan evolution of the Western Tatra Mountains: new insights from U-Pb zircon dating.

PubMed

Burda, Jolanta; Klötzli, Urs

In situ LA-MC-ICP-MS U-Pb zircon geochronology combined with cathodoluminescence imaging were carried out to determine protolith and metamorphic ages of orthogneisses from the Western Tatra Mountains (Central Western Carpathians). The metamorphic complex is subdivided into two units (the Lower Unit and the Upper Unit). Orthogneisses of the Lower Unit are mostly banded, fine- to medium-grained rocks while in the Upper Unit varieties with augen structures predominate. Orthogneisses show a dynamically recrystallised mineral assemblage of Qz + Pl + Bt ± Grt with accessory zircon and apatite. They are peraluminous (ASI = 1.20-1.27) and interpreted to belong to a high-K calc-alkaline suite of a VAG-type tectonic setting. LA-MC-ICP-MS U-Pb zircon data from samples from both units, from crystals with oscillatory zoning and Th/U > 0.1, yield similar concordia ages of ca. 534 Ma. This is interpreted to reflect the magmatic crystallization age of igneous precursors. These oldest meta-magmatics so far dated in the Western Tatra Mountains could be linked to the fragmentation of the northern margin of Gondwana. In zircons from a gneiss from the Upper Unit, cores with well-developed oscillatory zoning are surrounded by weakly luminescent, low contrast rims (Th/U < 0.1). These yield a concordia age of ca. 387 Ma corresponding to a subsequent, Eo-Variscan, high-grade metamorphic event, connected with the formation of crustal-scale nappe structures and collision-related magmatism.

Spatiotemporal climatic, hydrological, and environmental variations based on records of annually laminated lake sediments from northern Poland

NASA Astrophysics Data System (ADS)

Tylmann, W.; Blanke, L.; Kinder, M.; Loewe, T.; Mayr, C.; Ohlendorf, C.; Zolitschka, B.

2009-12-01

In northern Poland there is the unique opportunity to compare varved lake sediment records with distinct climatic trends along a 700 km long W-E transect. Annually laminated Holocene sediment sequences from Lake Lubinskie, Lake Suminko, Lake Lazduny, and Lake Szurpily were cored for high-resolution multiproxy climate and environmental reconstruction in the framework of the Polish-German project “Northern Polish Lake Research” (NORPOLAR). First results from a 139 cm long gravity core of Lake Lazduny (53°51.4’N, 21°57.3’E) document deposition of an organic (mean organic matter: 13.9%; mean biogenic opal: 9.8%) and highly carbonaceous gyttja (mean calcite content: 61.6%). The finely laminated sediment consists of biochemical varves. Pale spring/summer layers composed of autochthonous carbonates alternate with dark fall/winter layers made of organic and minerogenic detritus. The established chronology for the last 1500 calendar-years is based on thin section analysis supported by independent radiometric dating (C-14, Pb-210). Sedimentological, geochemical and stable isotope analyses were carried out with a decadal temporal resolution. Additionally, non-destructive and high-resolution XRF scanning data reveal a rhythmic variation in the Ca content that reflects seasonal calcite deposition. Redox-sensitive elements like Fe, Mn and S are interpreted to be the response to mean winter temperatures: colder winter temperatures → extended lake ice cover → intensification of meromixis → increased Fe/Mn ratio. In turn, these parameters can be linked to NAO (North Atlantic Oscillation) variability, because a negative NAO is related to colder and drier conditions in northeastern Europe. Climate variability is also mirrored by the δ13C record of the endogenic calcite fraction. In mid-latitude lakes calcite precipitation is dominated by productivity-controlled consumption of the dissolved inorganic carbon (DIC) pool. Thus the δ13C record potentially provides a proxy for lacustrine primary production related to seasonal water temperature. As human land use considerably increased and modified the nutrient availability since the 19th century, this relationship is not applicable for the upper part of the record. Main future goals of NORPOLAR will be to (1) establish absolute chronologies for all available records covering the entire Holocene; (2) provide high-resolution data sets of paleoredox conditions, paleoproductivity, lake water balance, lacustrine carbon cycles and soil erosion in the catchment areas; (3) link paleodata with modern instrumental and monitoring data to improve the understanding of signal generation from forcing factors via processes to proxy records; and (4) provide regional data sets of reconstructed and quantified climate parameters to be compared with the output of regional climate models.

Luminescent microbanding in speleothems: High-resolution chronology and paleoclimate

NASA Astrophysics Data System (ADS)

Shopov, Y. Y.; Ford, D. C.; Schwarcz, H. P.

1994-05-01

When illuminated by ultraviolet light, many calcite speleothems (stalagmites, stalactites, flowstones) display luminescence caused by the presence of organic (humic) substances occluded in the calcite. The amplitude of luminescence varies in a banded pattern parallel to growth layering. Through 14C and thermal ionization mass spectrometry uranium-series dating, we show that cyclical oscillations in the luminescence have periodicities ranging from a few days to ≥105 yr. A well-defined annual cycle is present in many vadose-zone speleothems and can be used to define the chronology of short-term events. This cycle is probably a response to hydrological events in the recharge to the cave. Longer term oscillations are inferred to be controlled by climate, through its effect on organic activity in the overlying soil.

Modern U-Pb chronometry of meteorites: advancing to higher time resolution reveals new problems

USGS Publications Warehouse

Amelin, Y.; Connelly, J.; Zartman, R.E.; Chen, J.-H.; Gopel, C.; Neymark, L.A.

2009-01-01

In this paper, we evaluate the factors that influence the accuracy of lead (Pb)-isotopic ages of meteorites, and may possibly be responsible for inconsistencies between Pb-isotopic and extinct nuclide timescales of the early Solar System: instrumental mass fractionation and other possible analytical sources of error, presence of more than one component of non-radiogenic Pb, migration of ancient radiogenic Pb by diffusion and other mechanisms, possible heterogeneity of the isotopic composition of uranium (U), uncertainties in the decay constants of uranium isotopes, possible presence of "freshly synthesized" actinides with short half-life (e.g. 234U) in the early Solar System, possible initial disequilibrium in the uranium decay chains, and potential fractionation of radiogenic Pb isotopes and U isotopes caused by alpha-recoil and subsequent laboratory treatment. We review the use of 232Th/238U values to assist in making accurate interpretations of the U-Pb ages of meteorite components. We discuss recently published U-Pb dates of calcium-aluminum-rich inclusions (CAIs), and their apparent disagreement with the extinct nuclide dates, in the context of capability and common pitfalls in modern meteorite chronology. Finally, we discuss the requirements of meteorites that are intended to be used as the reference points in building a consistent time scale of the early Solar System, based on the combined use of the U-Pb system and extinct nuclide chronometers.

3. AERIAL VIEW TO NORTH OF NORTH PART OF COAST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. AERIAL VIEW TO NORTH OF NORTH PART OF COAST GUARD AIR STATION SAN FRANCISCO, SHOWING PAN AMERICAN WORLD AIRWAYS HANGAR IN BACKGROUND. 8X10 black and white silver gelatin print. United States Coast Guard Official Photograph, 12th District, File No. 62751-21 A.S. Date unknown. - U.S. Coast Guard Air Station San Francisco, 1020 North Access Road, San Francisco, San Francisco County, CA

Earliest direct evidence of monument building at the archaeological site of Nan Madol (Pohnpei, Micronesia) identified using 230Th/U coral dating and geochemical sourcing of megalithic architectural stone

NASA Astrophysics Data System (ADS)

McCoy, Mark D.; Alderson, Helen A.; Hemi, Richard; Cheng, Hai; Edwards, R. Lawrence

2016-11-01

Archaeologists commonly use the onset of the construction of large burial monuments as a material indicator of a fundamental shift in authority in prehistoric human societies during the Holocene. High- quality direct evidence of this transition is rare. We report new interdisciplinary research at the archaeological site of Nan Madol that allows us to specify where and when people began to construct monumental architecture in the remote islands of the Pacific. Nan Madol is an ancient administrative and mortuary center and the former capital of the island of Pohnpei. It was constructed over 83 ha of lagoon with artificial islets and other architecture built using columnar basalt and coral. We employed geochemical sourcing of basalt used as architectural stone and high-precision uranium-thorium series dates (230Th/U) on coral from the tomb of the first chief of the entire island to identify the beginning of monument building at Nan Madol in AD 1180-1200. Over the next several centuries (AD 1300-1600) monument building began on other islands across Oceania. Future research should be aimed at resolving the causes of these social transformations through higher quality data on monument building.

U-Th dating reveals regional-scale decline of branching Acropora corals on the Great Barrier Reef over the past century

PubMed Central

Clark, Tara R.; Roff, George; Zhao, Jian-xin; Feng, Yue-xing; Done, Terence J.; McCook, Laurence J.; Pandolfi, John M.

2017-01-01

Hard coral cover on the Great Barrier Reef (GBR) is on a trajectory of decline. However, little is known about past coral mortality before the advent of long-term monitoring (circa 1980s). Using paleoecological analysis and high-precision uranium-thorium (U-Th) dating, we reveal an extensive loss of branching Acropora corals and changes in coral community structure in the Palm Islands region of the central GBR over the past century. In 2008, dead coral assemblages were dominated by large, branching Acropora and living coral assemblages by genera typically found in turbid inshore environments. The timing of Acropora mortality was found to be occasionally synchronous among reefs and frequently linked to discrete disturbance events, occurring in the 1920s to 1960s and again in the 1980s to 1990s. Surveys conducted in 2014 revealed low Acropora cover (<5%) across all sites, with very little evidence of change for up to 60 y at some sites. Collectively, our results suggest a loss of resilience of this formerly dominant key framework builder at a regional scale, with recovery severely lagging behind predictions. Our study implies that the management of these reefs may be predicated on a shifted baseline. PMID:28893981

U-Th dating reveals regional-scale decline of branching Acropora corals on the Great Barrier Reef over the past century.

PubMed

Clark, Tara R; Roff, George; Zhao, Jian-Xin; Feng, Yue-Xing; Done, Terence J; McCook, Laurence J; Pandolfi, John M

2017-09-26

Hard coral cover on the Great Barrier Reef (GBR) is on a trajectory of decline. However, little is known about past coral mortality before the advent of long-term monitoring (circa 1980s). Using paleoecological analysis and high-precision uranium-thorium (U-Th) dating, we reveal an extensive loss of branching Acropora corals and changes in coral community structure in the Palm Islands region of the central GBR over the past century. In 2008, dead coral assemblages were dominated by large, branching Acropora and living coral assemblages by genera typically found in turbid inshore environments. The timing of Acropora mortality was found to be occasionally synchronous among reefs and frequently linked to discrete disturbance events, occurring in the 1920s to 1960s and again in the 1980s to 1990s. Surveys conducted in 2014 revealed low Acropora cover (<5%) across all sites, with very little evidence of change for up to 60 y at some sites. Collectively, our results suggest a loss of resilience of this formerly dominant key framework builder at a regional scale, with recovery severely lagging behind predictions. Our study implies that the management of these reefs may be predicated on a shifted baseline.

U-Th dating reveals regional-scale decline of branching Acropora corals on the Great Barrier Reef over the past century

NASA Astrophysics Data System (ADS)

Clark, Tara R.; Roff, George; Zhao, Jian-xin; Feng, Yue-xing; Done, Terence J.; McCook, Laurence J.; Pandolfi, John M.

2017-09-01

Hard coral cover on the Great Barrier Reef (GBR) is on a trajectory of decline. However, little is known about past coral mortality before the advent of long-term monitoring (circa 1980s). Using paleoecological analysis and high-precision uranium-thorium (U-Th) dating, we reveal an extensive loss of branching Acropora corals and changes in coral community structure in the Palm Islands region of the central GBR over the past century. In 2008, dead coral assemblages were dominated by large, branching Acropora and living coral assemblages by genera typically found in turbid inshore environments. The timing of Acropora mortality was found to be occasionally synchronous among reefs and frequently linked to discrete disturbance events, occurring in the 1920s to 1960s and again in the 1980s to 1990s. Surveys conducted in 2014 revealed low Acropora cover (<5%) across all sites, with very little evidence of change for up to 60 y at some sites. Collectively, our results suggest a loss of resilience of this formerly dominant key framework builder at a regional scale, with recovery severely lagging behind predictions. Our study implies that the management of these reefs may be predicated on a shifted baseline.

Snežna jama (Slovenia): Interdisciplinary dating of cave sediments and implication for landscape evolution

PubMed Central

Häuselmann, Philipp; Mihevc, Andrej; Pruner, Petr; Horáček, Ivan; Čermák, Stanislav; Hercman, Helena; Sahy, Diana; Fiebig, Markus; Hajna, Nadja Zupan; Bosák, Pavel

2015-01-01

Caves are important markers of surface evolution, since they are, as a general rule, linked with ancient valley bottoms by their springs. However, caves can only be dated indirectly by means of the sediments they contain. If the sediment is older than common dating methods, one has to use multiple dating approaches in order to get meaningful results. U/Th dating, palaeomagnetic analysis of flowstone and sediment profiles, cosmogenic dating of quartz pebbles, and mammalian dating allowed a robust estimate of speleogenesis, sediment deposition, climatic change at the surface, and uplift history on the Periadriatic fault line during the Plio-Pleistocene. Our dates indicate that Snežna jama was formed in the (Upper) Miocene, received its sedimentary deposits during the Pliocene in a rather low-lying, hilly landscape, and became inactive due to uplift along the Periadriatic and Sava faults and climatic changes at the beginning of the Quaternary. Although it is only a single cave, the information contained within it makes it an important site of the Southern Alps. PMID:26516294

Snežna jama (Slovenia): Interdisciplinary dating of cave sediments and implication for landscape evolution.

PubMed

Häuselmann, Philipp; Mihevc, Andrej; Pruner, Petr; Horáček, Ivan; Čermák, Stanislav; Hercman, Helena; Sahy, Diana; Fiebig, Markus; Hajna, Nadja Zupan; Bosák, Pavel

2015-10-15

Caves are important markers of surface evolution, since they are, as a general rule, linked with ancient valley bottoms by their springs. However, caves can only be dated indirectly by means of the sediments they contain. If the sediment is older than common dating methods, one has to use multiple dating approaches in order to get meaningful results. U/Th dating, palaeomagnetic analysis of flowstone and sediment profiles, cosmogenic dating of quartz pebbles, and mammalian dating allowed a robust estimate of speleogenesis, sediment deposition, climatic change at the surface, and uplift history on the Periadriatic fault line during the Plio-Pleistocene. Our dates indicate that Snežna jama was formed in the (Upper) Miocene, received its sedimentary deposits during the Pliocene in a rather low-lying, hilly landscape, and became inactive due to uplift along the Periadriatic and Sava faults and climatic changes at the beginning of the Quaternary. Although it is only a single cave, the information contained within it makes it an important site of the Southern Alps.

Age estimates for the late quaternary high sea-stands

NASA Astrophysics Data System (ADS)

Smart, Peter L.; Richards, David A.

A database of more than 300 published alpha-counted uranium-series ages has been compiled for coral reef terraces formed by Late Pleistocene high sea-stands. The database was screened to eliminate unreliable age estimates ( {230Th }/{232Th } < 20, calcite > 5%) and those without quoted without quoted errors, and a distributed error frequency curve was produced. This curve can be considered as a finite mixture model comprising k component normal distributions each with a weighting α. By using an expectation maximising algorithm, the mean and standard deviation of the component distributions, each corresponding to a high sea level event, were estimated. Eight high sea-stands with mean and standard deviations of 129.0 ± 33.0, 123.0 ± 13.0, 102.5 ± 2.0, 81.5 ± 5.0, 61.5 ± 6.0, 50.0 ± 1.0, 40.5 ± 5.0 and 33.0 ± 2.5 ka were resolved. The standard deviations are generally larger than the values quoted for individual age estimates. Whilst this may be due to diagenetic effects, especially for the older corals, it is argued that in many cases geological evidence clearly indicates that the high stands are multiple events, often not resolvable at sites with low rates of uplift. The uranium-series dated coral-reef terrace chronology shows good agreement with independent chronologies derived for Antarctic ice cores, although the resolution for the latter is better. Agreement with orbitally-tuned deep-sea core records is also good, but it is argued that Isotope Stage 5e is not a single event, as recorded in the cores, but a multiple event spanning some 12 ka. The much earlier age for Isotope Stage 5e given by Winograd et al. (1988) is not supported by the coral reef data, but further mass-spectrometric uranium-series dating is needed to permit better chronological resolution.

Late-stage anhydrite-gypsum-siderite-dolomite-calcite assemblages record the transition from a deep to a shallow hydrothermal system in the Schwarzwald mining district, SW Germany

NASA Astrophysics Data System (ADS)

Burisch, Mathias; Walter, Benjamin F.; Gerdes, Axel; Lanz, Maximilian; Markl, Gregor

2018-02-01

The majority of hydrothermal vein systems of economic interest occur at relatively shallow crustal levels, although many of them formed at significantly greater depths. Their present position is a consequence of uplift and erosion. Although, many aspects of their formation are well constrained, the temporal chemical evolution of such systems during uplift and erosion is still poorly understood. These vein minerals comprise calcite, dolomite-ankerite, siderite-magnesite, anhydrite and gypsum forming the last gangue assemblages in Jurassic and Tertiary sulphide-fluorite-quartz-barite veins of the Schwarzwald mining district, SW Germany. Mineral textures of samples from nine localities reveal that in these sequences, mineral precipitation follows a recurring pattern: early calcite is followed by anhydrite or gypsum, siderite and/or dolomite. This succession may repeat up to three times. In-situ (LA-ICP-MS) U-Pb age dating of 15 carbonates from three subsequent generations of the late-stage vein assemblage yield robust ages between 20 and 0.6 Ma. Each mineral sequence forms in a distinctive period of about 2-5 Ma. These ages clearly relate these late-stage mineral phases to the youngest geological episode of the Schwarzwald, which is associated with the Cenozoic Rhine Graben rifting and basement uplift. Based on thermodynamic modelling, the formation of the observed mineral assemblages required an deeply sourced Mg-, Fe- and SO4-rich fluid (b), which was episodically mixed with a shallow crustal HCO3-rich fluid (a). As a consequence of fluid mixing, concentrations of Mg, Fe and SO4 temporarily increased and initiated the formation of the observed sulphate-carbonate mineral sequences. This discontinuous large-scale vertical fluid mixing was presumably directly related to episodes of active tectonics associated with the Cenozoic strike-slip regime of the Upper Rhine Graben. Analogously, episodic fluid mixing is a major key in the formation of older (Jurassic to early Tertiary) Pb-Zn-fluorite-quartz-barite assemblages in the same specific vein systems, albeit involving different fluid compositions. Late-stage hydrothermal (∼20-70 °C) vein assemblages reported in this study record the transition from deep (>2 km) to very shallow (0-1 km) crustal conditions. As a consequence of successive uplift, increasing proportions of shallower and cooler (∼50-70 °C) fluids could take part in such mixing processes. Associated changes in the fluid composition caused the vein mineralogy to change from sulphide-quartz-fluorite-barite to calcite-anhydrite/gypsum-siderite-dolomite, as the system passively ascended closer to the surface.

Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada

USGS Publications Warehouse

Watts, Kathryn E.; Coble, Matthew A.; Vazquez, Jorge A.; Henry, Christopher D.; Colgan, Joseph P.; John, David A.

2016-01-01

Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206Pb/238U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2–4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4–0.6 Myr older than the 40Ar/39Ar sanidine eruption age (34.00 ± 0.03 Ma; error-weighted mean, 2σ), whereas non-CA zircons have ages that are 0.7–1.3 Myr younger. U-Pb ages do not correlate with U (~ 100–800 ppm), Th (~ 50–300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6 μm for CA and non-CA Caetano, R33 and TEMORA-2 zircons, and do not indicate variations in secondary ion sputtering rates due to chemical or structural changes from the CA treatment. Our new data underscore the potential for cryptic Pb-loss to go unrecognized in other geologically young magmatic centers that do not have zircons with high U, statistically discordant isotope ratios, high common Pb, or metamict textures.

Uranium metallogenesis of the peraluminous leucogranite from the Pontivy-Rostrenen magmatic complex (French Armorican Variscan belt): the result of long-term oxidized hydrothermal alteration during strike-slip deformation

NASA Astrophysics Data System (ADS)

Ballouard, C.; Poujol, M.; Mercadier, J.; Deloule, E.; Boulvais, P.; Baele, J. M.; Cuney, M.; Cathelineau, M.

2018-06-01

In the French Armorican Variscan belt, most of the economically significant hydrothermal U deposits are spatially associated with peraluminous leucogranites emplaced along the south Armorican shear zone (SASZ), a dextral lithospheric scale wrench fault that recorded ductile deformation from ca. 315 to 300 Ma. In the Pontivy-Rostrenen complex, a composite intrusion, the U mineralization is spatially associated with brittle structures related to deformation along the SASZ. In contrast to monzogranite and quartz monzodiorite (3 < U < 9 ppm; Th/U > 3), the leucogranite samples are characterized by highly variable U contents ( 3 to 27 ppm) and Th/U ratios ( 0.1 to 5) suggesting that the crystallization of magmatic uranium oxide in the more evolved facies was followed by uranium oxide leaching during hydrothermal alteration and/or surface weathering. U-Pb dating of uranium oxides from the deposits reveals that they mostly formed between ca. 300 and 270 Ma. In monzogranite and quartz monzodiorite, apatite grains display magmatic textures and provide U-Pb ages of ca. 315 Ma reflecting the time of emplacement of the intrusions. In contrast, apatite grains from the leucogranite display textural, geochemical, and geochronological evidences for interaction with U-rich oxidized hydrothermal fluids contemporaneously with U mineralizing events. From 300 to 270 Ma, infiltration of surface-derived oxidized fluids leached magmatic uranium oxide from fertile leucogranite and formed U deposits. This phenomenon was sustained by brittle deformation and by the persistence of thermal anomalies associated with U-rich granitic bodies.

Water-table decline in the south-central Great Basin during the Quaternary Period; implications for toxic-waste disposal

USGS Publications Warehouse

Winograd, I.J.; Szabo, B. J.

1986-01-01

The distribution of vein calcite, tufa, and other features indicative of paleo-groundwater discharge, indicates that during the early to middle Pleistocene, the water table at Ash Meadows, in the Amargosa Desert, Nevada, and at Furnace Creek Wash, in east-central Death Valley, California, was tens to hundreds of meters above the modern water table, and that groundwater discharge occurred up to 18 km up-the-hydraulic gradient from modern discharge areas. Uranium series dating of the calcitic veins permits calculation of rates of apparent water table decline; rates of 0.02 to 0.08 m/1000 yr are indicated for Ash meadows and 0.2 to 0.6 m/1000 yr for Furnace Creek Wash. The rates for Furnace Creek Wash closely match a published estimate of vertical crustal offset for this area, suggesting that tectonism is a major cause for the displacement observed. In general, displacements of the paleo-water table probably reflect a combination of: (a) tectonic uplift of vein calcite and tufa, unaccompanied by a change in water table altitude; (b) decline in water table altitude in response to tectonic depression of areas adjacent to dated veins and associated tufa; (c) decline in water table altitude in response to increasing aridity caused by major uplift of the Sierra Nevada and Transverse Ranges during the Quaternary; and (d) decline in water altitude in response to erosion triggered by increasing aridity and/or tectonism. A synthesis of geohydrologic, neotectonic, and paleoclimatologic information with the vein-calcite data permits the inference that the water table in the south-central Great Basin progressively lowered throughout the Quaternary. This inference is pertinent to an evaluation of the utility of thick (200-600 m) unsaturated zones of the region for isolating solidified radioactive wastes from the hydrosphere for hundreds of millenia. Wastes buried a few tens to perhaps 100 m above the modern water table--that is above possible water level rises due to future pluvial climates--are unlikely to be inundated by a rising water table in the foreseeable geologic future. (Author 's abstract)

Carbonate speleothems from western Mediterranean gypsum karst: palaeoclimate implications

NASA Astrophysics Data System (ADS)

Columbu, Andrea; Drysdale, Russell; Woodhead, Jon; Chiarini, Veronica; De Waele, Jo; Hellstrom, John; Forti, Paolo; Sanna, Laura

2016-04-01

Gypsum caves are uncommon environments for carbonate speleothems (cave deposits). Contrary to limestone caves, the only source of non-atmospheric carbon is from biogenic CO2 produced by the overlying soils. Enhanced CO2 content in soils is in turn related with climate, where warm temperatures and high humidity favour plant activity .().....(Fairchild and Baker, 2012). Although poorly decorated, the exploration of northern Italian and Spanish gypsum karst systems reveals the existence of several generations of carbonate speleothems, which have been dated with the U-Th series method .()......(Hellstrom, 2003; Scholz and Hoffmann, 2008). Their ages coincide with current and previous two interglacials (MIS 1, 5e and 7e and Greenland interstadials (GIS) 19, 20, 21 and 24. Considering that these periods are amongst the most pronounced warm-wet pulsations over the last 250,000 ...(Martrat et al., 2007; NGRIP, 2004), and that CO2 has a fundamental role in this karst process, this study explores the climate-driven hydrogeological conditions necessary to trigger carbonate deposition in gypsum voids. The further correlation with sapropel events 5, 4, 3 and 1, considered symptomatic of enhanced rainfall across the whole Mediterranean basin .(.)(Emeis et al., 1991), highlights the importance of flow-rate in the fracture network and infiltration of meteoric water into the caves. The combination of high CO2 and a phreatic status of the fracture network is thus indispensable for the formation of carbonate speleothems in gypsum karst. This condition appears to be triggered by periods of orbital precession minimum, when the monsoonal activity peaked in the Atlantic area. Stable oxygen isotope signatures suggest that the speleothems did not grow during any interglacial-glacial or main interstadial-stadial transitions, confirming that variations from optimum climate conditions may hamper the formation of this category of speleothems. New speleological exploration and sampling campaign may extend this model in space (extra-Mediterranean regions) and time (500,000 BP - the limit of U-Th dating), enhancing knowledge on the latitudinal impact and timing of such climate variability. References .Emeis, K.-C., Camerlenghi, A., McKenzie, J. A., Rio, D., and Sprovieri, R., 1991, The occurrence and significance of Pleistocene and Upper Pliocene sapropels in the Tyrrhenian Sea: Marine geology, v. 100, no. 1, p. 155-182. Fairchild, I. J., and Baker, A., 2012, Speleothem science: from process to past environments: John Wiley & Sons, Chichester. Hellstrom, J., 2003, Rapid and accurate U/Th dating using parallel ion-counting multi-collector ICP-MS.: Journal of Analytical Atomic Spectrometry, v. 18. Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F., 2007, Four climate cycles of recurring deep and surface water destabilizations on the Iberian margin: Science, v. 317, no. 5837, p. 502-507. NGRIP, N. G. I. C. P. M., 2004, High-resolution record of Northern Hemisphere climate extending into the last interglacial period: Nature, v. 431, no. 7005, p. 147-151. Scholz, D., and Hoffmann, D., 2008, 230Th/U-dating of fossil corals and speleothems: Quat. Sci. J, v. 57, p. 52.

Neoproterozoic transpression and granite magmatism in the Gavilgarh-Tan Shear Zone, central India: Tectonic significance of U-Pb zircon and U-Th-total Pb monazite ages

NASA Astrophysics Data System (ADS)

Chattopadhyay, Anupam; Chatterjee, Amitava; Das, Kaushik; Sarkar, Arindam

2017-10-01

The Gavilgarh-Tan Shear Zone (GTSZ) is a crustal-scale shear/fault zone that dissects the unclassified basement gneisses separating two major supracrustal belts, viz. the Paleo- to Mesoproterozoic (≥1.5 Ga) Betul Belt and the Neoproterozoic (∼1.0 Ga) Sausar Belt, of the Central Indian Tectonic Zone (CITZ). The GTSZ extends for more than 300 km strike length, partly covered by the Deccan Trap flows. Granitoid rocks ranging from syenogranite to granodiorite in composition, sheared at temperatures corresponding to the amphibolite facies metamorphic condition, define the GTSZ in the Kanhan River Valley. Earlier geological studies have suggested that the GTSZ underwent a sinistral-sense partitioned transpression in response to an oblique collision between two continental fragments, possibly related to crustal thickening and high-pressure granulite metamorphism (the Ramakona-Katangi granulite: RKG) in the northern part of the Sausar Belt. LA-ICP-MS U-Pb dating of zircon and EPMA U-Th-total Pb dating of monazite grains from four different types of syn-tectonic granitoids of the GTSZ carried out in the present study show that granitoids intruded the basement gneisses between 1.2 Ga and 0.95 Ga, given the error limit of the calculated ages. The age of transpression and mylonitization is more definitely bracketed between 1.0 Ga and 0.95 Ga, which correlates well with the published ages of deformation and metamorphism in the Sausar Belt. This age data strongly supports the suggested collisional tectonic model involving the GTSZ and the RKG granulites of the Sausar Belt and underlines a Grenvillian-age tectonic history for the southern part of the Central Indian Tectonic Zone (CITZ), which possibly culminated in the crustal assembly of the Neoproterozoic supercontinent Rodinia.

Origin and significance of postore dissolution collapse breccias cemented with calcite and barite at the Meikle gold deposit, Northern Carlin trend, Nevada

USGS Publications Warehouse

Emsbo, P.; Hofstra, A.H.

2003-01-01

The final event in a complicated hydrothermal history at the Meikle gold deposit was gold deficient but caused extensive postore dissolution of carbonate, collapse brecciation, and precipitation of calcite and barite crystals in the resulting cavities. Although previously interpreted to be part of the Carlin-type hydrothermal system, crosscutting relationships and U-Th-Pb geochronology constrain this hydrothermal event to late Pliocene time (ca. 2 Ma), nearly 36 Ma after ore formation. Mineralogic, fluid inclusion, and stable isotope data indicate that postore hydrothermal fluids were reduced, H2S-rich, unevolved meteoric waters ((??18O = -17???) of low temperature (ca. 65??C). The ??18O values of barite and calcite indicate that these minerals were in isotopic equilibrium, requiring that barite SO4 was derived from the oxidation of reduced sulfur; however, preexisting sulfides in breccia cavities were not oxidized. The ??34S (15???) values of barite are higher than those of local bulk sulfide and supergene alunite indicating that SO4 was not derived from supergene oxidation of local sulfide minerals. The 15 per mil ??34S value suggests that the H2S in the fluids may have been leached from sulfur-rich organic matter in the local carbonaceous sedimentary rocks. A reduced H2S-rich fluid is also supported by the bright cathodoluminescence of calcite which indicates that it is Mn rich and Fe poor. Calcite has a narrow range of ??13C values (0.3-1.8???) that are indistinguishable from those of the host Bootstrap limestone, indicating that CO2 in the fluid was from dissolution of the local limestone. These data suggest that dissolution and brecciation of the Bootstrap limestone occurred where H2S-rich fluids encountered more oxidizing fluids and formed sulfuric acid (H2SO4). Intense fracturing in the mine area by previous structural and hydrothermal events probably provided conduits for the descent of oxidized surface water which mixed with the underlying H2S-rich waters to form the dissolving acid. The surface-derived fluid apparently contained sufficient oxygen to produce H2SO4 from H2S but not enough to alter pyrite to Fe oxide. Although H2S is an important gold-transporting ligand, the temperature was too low to transport a significant amount of gold. The presence of analogous calcite- and barite-lined cavities in other Carlin-type deposits suggests that the generation (and oxidation) of H2S-rich meteoric waters was a common phenomenon in north-central Nevada. Previous sulfur isotope studies have also shown that the Paleozoic sedimentary rocks were the principal source of H2S in Devonian sedimentary exhalative-type, Jurassic intrusion-related, Eocene Carlin-type, and Miocene low-sulfidation gold deposits in the region. The similar sulfur source in all of these systems suggests that basin brines, magmatic fluids, and meteoric waters all evolved to be H2S-rich ore fluids by circulation through Paleozoic sedimentary rocks. Thus, although not directly related to gold mineralization, the recent hydrologic history of the deposit provides important clues to earlier ore-forming processes that were responsible for gold mineralization.

On-line Raman spectroscopy of calcite and malachite during irradiation with swift heavy ions

NASA Astrophysics Data System (ADS)

Dedera, Sebastian; Burchard, Michael; Glasmacher, Ulrich A.; Schöppner, Nicole; Trautmann, Christina; Severin, Daniel; Romanenko, Anton; Hubert, Christian

2015-12-01

A new on-line Raman System, which was installed at the M3-beamline at the UNILAC, GSI Helmholtzzentrum für Schwerionenforschung Darmstadt was used for first "in situ" spectroscopic measurements. Calcite and malachite samples were irradiated in steps between 1 × 109 and 1 × 1012 ions/cm2 with Au ions (calcite) and Xe ions (malachite) at an energy of 4.8 MeV/u. After irradiation, calcite revealed a new Raman band at 437 cm-1 and change of the full width at half maximum for the 1087 cm-1 Raman band. The Raman bands of malachite change significantly with increasing fluence. Up to a fluence of 7 × 1010 ions/cm2, all existing bands decrease in intensity. Between 8 × 1010 and 1 × 1011 ions/cm2 a broad Cu2O band between 110 and 220 cm-1 occurs, which superimposes the pre-existing Raman bands. Additionally, a new broad band between 1000 and 1750 cm-1 is formed, which is interpreted as a carbon coating. In contrast to the Cu2O band, the carbon band vanished when further irradiating the sample. The installations as well as first in situ measurements at room temperature are presented.

Helium diffusion in carbonates

NASA Astrophysics Data System (ADS)

Amidon, W. H.; Cherniak, D. J.; Watson, E. B.; Hobbs, D.

2013-12-01

The abundance and large grain size of carbonate minerals make them a potentially attractive target for 4He thermochronology and 3He cosmogenic dating, although the diffusive properties of helium in carbonates remain poorly understood. This work characterizes helium diffusion in calcite and dolomite to better understand the crystal-chemical factors controlling He transport and retentivity. Slabs of cleaved natural calcite and dolomite, and polished sections of calcite cut parallel or normal to c, were implanted with 3He at 3 MeV with a dose of 5x1015/cm2. Implanted carbonates were heated in 1-atm furnaces, and 3He distributions following diffusion anneals were profiled with Nuclear Reaction Analysis using the reaction 3He(d,p)4He. For 3He transport normal to cleavage surfaces in calcite, we obtain the following Arrhenius relation over the temperature range 78-300°C: Dcalcite = 9.0x10-9exp(-55 × 6 kJ mol-1/RT) m2sec-1. Diffusion in calcite exhibits marked anisotropy, with diffusion parallel to c about two orders of magnitude slower than diffusion normal to cleavage faces. He diffusivities for transport normal to the c-axis are similar in value to those normal to cleavage surfaces. Our findings are broadly consistent with helium diffusivities from step-heating measurements of calcite by Copeland et al. (2007); these bulk degassing data may reflect varying effects of diffusional anisotropy. Helium diffusion normal to cleavage surfaces in dolomite is significantly slower than diffusion in calcite, and has a much higher activation energy for diffusion. For dolomite, we obtain the following Arrhenius relation for He diffusion over the temperature range 150-400°C: Ddolomite = 9.0x10-8exp(-92 × 9 kJ mol-1/RT) m2sec-1. The role of crystallographic structure in influencing these differences among diffusivities was evaluated using the maximum aperture approach of Cherniak and Watson (2011), in which crystallographic structures are sectioned along possible diffusion directions and the maximum interstitial apertures in each 'slice' in the structure are identified. Preliminary results show that observed differences in diffusivities are consistent with the size of the smallest maximum aperture along each diffusion direction. In calcite, the smallest maximum apertures are ~0.92 and ~0.66 angstroms for cleavage-normal and c-axis parallel directions respectively. In dolomite, the smallest maximum aperture is ~0.78 angstroms for the cleavage normal direction. Work is in progress on characterizing helium diffusion for other orientations in dolomite, and in other carbonates, including aragonite and magnesite, and in implementing these diffusion findings in the interpretation and modeling of bulk volume diffusion in heterogeneous calcite crystals common in many geologic applications. Copeland et al. (2007) GCA 71, 4488-4511 Cherniak and Watson, (2011) Chem. Geo. 288, 149-161

U-Th age evidence from carbonate veins for episodic crustal deformation of Central Anatolian Volcanic Province

NASA Astrophysics Data System (ADS)

Karabacak, Volkan; Uysal, I. Tonguç; Ünal-İmer, Ezgi; Mutlu, Halim; Zhao, Jian-xin

2017-12-01

Central Anatolia represents one of the most outstanding examples of intraplate deformation related to both continental collision and back-arc extension generating non-uniformly distributed stress fields. In this study, we provide direct field evidence of various stress directions and investigate carbonate-filled fracture systems in the Central Anatolian Volcanic Province using U/Th geochronology and isotope geochemistry for evaluating the episodes of latest volcanic activity under regional stress. Field data reveal two independent fracture systems in the region. Successive fracture development has been controlled by two different volcanic eruption centers (Hasandağ Composite Volcano and Acıgöl Caldera). Trace element, and stable (C and O) and radiogenic (Sr) isotope compositions of carbonate veins indicate different fluid migration pathways for two different fracture systems. The U/Th age data for carbonate veins of two independent fracture systems indicate that the crustal deformation intensified during 7 episodic periods in the last 150 ka. The NNE-trending first fracture system was formed as a result of strain cycles in a period from 149 ± 2.5, through 91 ± 1.5 to 83 ± 2.5 ka BP. Subsequent deformation events represented by the ENE-trending second fracture zone have been triggered during the period of 53 ± 3.5, 44 ± 0.6 and 34 ± 1 ka BP before the first fracture zone resumed the activity at about 4.7 ± 0.15 ka BP. Although further studies are needed to evaluate statistical significance of age correlations, the periods of carbonate precipitation inferred from U-Th age distributions in this study are comparable with the previous dating results of surrounding volcanic eruption events.

Two-phase Neogene extension in the northwestern basin and range recorded in a single thermochronology sample

USGS Publications Warehouse

Colgan, J.P.; Shuster, D.L.; Reiners, P.W.

2008-01-01

We use a combination of apatite 4He/3He, (U-Th)/ He, and fission-track thermochronology to date slip on the Surprise Valley fault in northeastern California by analyzing a single sample from the Warner Range in the footwall of the fault. This sample, a granitic clast from a conglomerate, yielded a fission-track age of 11.6 ?? 2.8 Ma and a (U-Th)/He age of 3.02 ?? 0.52 Ma. Geologic relationships indicate that this sample was buried to a depth of ???3.3 km prior to exhumation during slip on the Surprise Valley fault. Fission-track age and length data indicate that the sample was fully reset (>120 ??C) prior to exhumation, which began sometime after 14 Ma. A single aliquot of nine apatite grains was step-heated for 4He/3He analysis; modeling of the resulting 4He distribution indicates that cooling from <80 ??C to ???20 ??C occurred between 3 and 1 Ma. Interconsistent time-temperature (t-T) solutions to the combined 4He/3He, (U-Th)/He, and fission-track data require two distinct periods of cooling, consistent with non-continuous slip on the Surprise Valley fault. Early cooling and fault slip took place between 14 and 8 Ma, followed by more recent fault slip ca. 3 Ma. This timing is consistent with both local geologic relationships and with the regional timing of faulting along the western margin of the Basin and Range Province. These data demonstrate the resolving power of combined fission-track, (U-Th)/He, and 4He/3He thermochronometric data to extract low-temperature t-T information from a single sample close to Earth's surface. ?? 2008 The Geological Society of America.

U/Th dating by SHRIMP RG ion-microprobe mass spectrometry using single ion-exchange beads

NASA Astrophysics Data System (ADS)

Bischoff, James L.; Wooden, Joe; Murphy, Fred; Williams, Ross W.

2005-04-01

We present a new analytical method for U-series isotopes using the SHRIMP RG (Sensitive High mass Resolution Ion MicroProbe) mass spectrometer that utilizes the preconcentration of the U-series isotopes from a sample onto a single ion-exchange bead. Ion-microprobe mass spectrometry is capable of producing Th ionization efficiencies in excess of 2%. Analytical precision is typically better than alpha spectroscopy, but not as good as thermal ionization mass spectroscopy (TIMS) and inductively coupled plasma multicollector mass spectrometry (ICP-MS). Like TIMS and ICP-MS the method allows analysis of small samples sizes, but also adds the advantage of rapidity of analysis. A major advantage of ion-microprobe analysis is that U and Th isotopes are analyzed in the same bead, simplifying the process of chemical separation. Analytical time on the instrument is ˜60 min per sample, and a single instrument-loading can accommodate 15-20 samples to be analyzed in a 24-h day. An additional advantage is that the method allows multiple reanalyses of the same bead and that samples can be archived for reanalysis at a later time. Because the ion beam excavates a pit only a few μm deep, the mount can later be repolished and reanalyzed numerous times. The method described of preconcentrating a low concentration sample onto a small conductive substrate to allow ion-microprobe mass spectrometry is potentially applicable to many other systems.

U/Th dating by SHRIMP RG ion-microprobe mass spectrometry using single ion-exchange beads

USGS Publications Warehouse

Bischoff, J.L.; Wooden, J.; Murphy, F.; Williams, Ross W.

2005-01-01

We present a new analytical method for U-series isotopes using the SHRIMP RG (Sensitive High mass Resolution Ion MicroProbe) mass spectrometer that utilizes the preconcentration of the U-series isotopes from a sample onto a single ion-exchange bead. Ion-microprobe mass spectrometry is capable of producing Th ionization efficiencies in excess of 2%. Analytical precision is typically better than alpha spectroscopy, but not as good as thermal ionization mass spectroscopy (TIMS) and inductively coupled plasma multicollector mass spectrometry (ICP-MS). Like TIMS and ICP-MS the method allows analysis of small samples sizes, but also adds the advantage of rapidity of analysis. A major advantage of ion-microprobe analysis is that U and Th isotopes are analyzed in the same bead, simplifying the process of chemical separation. Analytical time on the instrument is ???60 min per sample, and a single instrument-loading can accommodate 15-20 samples to be analyzed in a 24-h day. An additional advantage is that the method allows multiple reanalyses of the same bead and that samples can be archived for reanalysis at a later time. Because the ion beam excavates a pit only a few ??m deep, the mount can later be repolished and reanalyzed numerous times. The method described of preconcentrating a low concentration sample onto a small conductive substrate to allow ion-microprobe mass spectrometry is potentially applicable to many other systems. Copyright ?? 2005 Elsevier Ltd.

International Aerospace and Ground Conference on Lightning and Static Electricity (8th), Lightning Technology Roundup. Held in Fort Worth, Texas on 21-23 June 1983. Addendum

DTIC Science & Technology

1983-10-01

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Integrative investigations on sediments in the Belauer See catchment (northern Germany)

NASA Astrophysics Data System (ADS)

Dreibrodt, Stefan

2015-04-01

The Holocene history of lake development, catchment vegetation, soil formation and human impact since the onset of the Neolithic period was reconstructed via the analysis of sediment sequences at Lake Belau (northern Germany). The chronology of the annually laminated lake sediment sequence was established via varve counts, radiocarbon dating and tephra analysis. Sequences of colluvial sediments and buried soils studied in 19 large exposures and supplementing auger cores within the lake catchment area were dated via radiocarbon dating and archaeological dating of embedded artifacts. The long term development of the lake status was found to be strongly influenced by local human activity. This is indicated by coincidence of phases of landscape openness deduced from pollen data with input of detritus and solutes into the lake. A comparison with palaeo-climate reconstructions reveals that calcite precipitation in the lake reflects climate variability at least to a certain degree. Calibrating the sediment record of the sub-recent lake sediments (micro-facies) on limnological and meteorological records discovered the influence of the NAO as well as solar activity on the limnological processes during the last century reflected by distinguished sedimentation patterns. A comparative study of additional laminated surface sediment sequences from northern Germany corroborates the results. A high resolution reconstruction of Neolithic weather conditions in northern Germany based on the varves of Lake Belau and Lake Poggensee was facilitated by the calibration. The quantitative records of sediments originating from soil erosion (colluvial sediments, allochthonous input into the lake) illustrate the dominance of short distance surface processes (slopes) acting in Holocene mid-latitude landscapes. Coincidence of gully incision in the lake catchment area and increased allochthonous input into the lake indicates the former occurrence of hydrological high energy runoff events (e. g. in the 14th century or at ca. 200 cal BC) whose regional significance is testable via comparative investigations in additional lake catchments.

The Marble Types of Thassos Island through the Ages

NASA Astrophysics Data System (ADS)

Laskaridis, Kostas; Patronis, Michael; Papatrechas, Christos; Schouenborg, Björn

2013-04-01

The first references to the "white whole-grain" marble of Thassos Island, Greece, date back to the 6th century BC when stones were quarried at Alyki peninsula and at Fanari and Vathy capes. Since that time, Thassos marble was exported to Samothraki and other neighbouring islands, Asia Minor coastal cities, Southern Greece and Rome. In ancient times, there were two principal types of marble quarries in Thassos: (a) those producing material for the construction of temples and for the creation of various art pieces, i.e. ornamental stones, and (b) those for extraction of rough blocks for export. This paper aims at describing the Thassos marble, the geological setting in brief, its historic use and future supply possibilities and other reasons why it is a time-enduring ornamental stone. The aesthetical characteristics and the physical mechanical properties of its two main types (i.e. calcitic and dolomitic) are described and evaluated. The relevant results justify the wide application range and the continuous use of Thassos marble from ancient to present times and confirm the ability of this stone to survive over time. Keywords: Thassos, Marble, Ornamental Stones, Physical Mechanical Properties, Historic use

Human papillomavirus vaccination coverage using two-dose or three-dose schedule criteria.

PubMed

Lin, Xia; Rodgers, Loren; Zhu, Liping; Stokley, Shannon; Meites, Elissa; Markowitz, Lauri E

2017-10-13

In October 2016, the Advisory Committee on Immunization Practices (ACIP) updated the human papillomavirus (HPV) vaccination recommendation to include a 2-dose schedule for U.S. adolescents initiating the vaccine series before their 15th birthday. We analyzed records for >4million persons aged 9-17years receiving any HPV vaccine by the end of each quarter during January 1, 2014-September 30, 2016 from six Immunization Information Systems Sentinel Sites, and reclassified HPV vaccination up-to-date coverage according to the updated recommendations. Compared with HPV vaccination up-to-date coverage by the 3-dose schedule only, including criteria for either a 2-dose or 3-dose schedule increased up-to-date coverage in 11-12, 13-14, and 15-17 year-olds by 4.5-8.5 percentage points. The difference between 3-dose up-to-date coverage and 2- or 3-dose up-to-date coverage was greatest in late 2016. These data provide baseline HPV vaccination coverage using current ACIP recommendations. Published by Elsevier Ltd.

Identifying the Volcanic Eruption Depicted in a Neolithic Painting at Çatalhöyük, Central Anatolia, Turkey

PubMed Central

Schmitt, Axel K.; Danišík, Martin; Aydar, Erkan; Şen, Erdal; Ulusoy, İnan; Lovera, Oscar M.

2014-01-01

A mural excavated at the Neolithic Çatalhöyük site (Central Anatolia, Turkey) has been interpreted as the oldest known map. Dating to ∼6600 BCE, it putatively depicts an explosive summit eruption of the Hasan Dağı twin-peaks volcano located ∼130 km northeast of Çatalhöyük, and a birds-eye view of a town plan in the foreground. This interpretation, however, has remained controversial not least because independent evidence for a contemporaneous explosive volcanic eruption of Hasan Dağı has been lacking. Here, we document the presence of andesitic pumice veneer on the summit of Hasan Dağı, which we dated using (U-Th)/He zircon geochronology. The (U-Th)/He zircon eruption age of 8.97±0.64 ka (or 6960±640 BCE; uncertainties 2σ) overlaps closely with 14C ages for cultural strata at Çatalhöyük, including level VII containing the “map” mural. A second pumice sample from a surficial deposit near the base of Hasan Dağı records an older explosive eruption at 28.9±1.5 ka. U-Th zircon crystallization ages in both samples range from near-eruption to secular equilibrium (>380 ka). Collectively, our results reveal protracted intrusive activity at Hasan Dağı punctuated by explosive venting, and provide the first radiometric ages for a Holocene explosive eruption which was most likely witnessed by humans in the area. Geologic and geochronologic lines of evidence thus support previous interpretations that residents of Çatalhöyük artistically represented an explosive eruption of Hasan Dağı volcano. The magmatic longevity recorded by quasi-continuous zircon crystallization coupled with new evidence for late-Pleistocene and Holocene explosive eruptions implicates Hasan Dağı as a potential volcanic hazard. PMID:24416270

Thermochronological modeling of the age of Vologda crystalline basement of the Russian platform

NASA Astrophysics Data System (ADS)

Gerasimov, V. Yu.; Petrov, D. B.; Lebedev, V. A.

2010-05-01

The results of the complex petrological and isotope-geochronological study of the crystalline rock from the deep drilling hall of the south of Vologda segment are presented in this work. The crystalline basement of the platform in Vologda region lie in a depth 2.5 km and represented by high alumina mica schist. The thick sedimentary cover consists of vendian and phanerozoic sediments. Upper level covered by quaternary glacial deposits up to 50 m. A core sample from the borehole of Fedotovo village was obtained from the depth 2600 m. It is fine-medium grained metamorphic mica schist with sillimanite. The mineral assemblage represented by association: Pl-Bt-Ms-Sil-Qtz-Mag +Zrn +Mnz. The metamorphic schist of the crystalline basement contains several radio isotope sensors. There are two rock forming potassium reach mica, - biotite (Bt) and muscovite (Ms) and accessories monazite (Mnz), - the phosphate of REE enriched by Th and U. It was a reason why traditional K-Ar isotope dating method in the combination with electron microprobe U-Th-Pb dating method CHIME [Suzuki et al. 1991] was used for Vologda metapelite rocks dating. In addition to geochronology, the detailed petrological investigation using electron microprobe allowed also to determine thermodynamic parameters of metamorphic system with a help of the mineral thermobarometry and finally estimate the age of the metamorphic thermal event using experimental diffusion data of Ar and Pb in minerals [Gerasimov et al. 2004]. The temperature of the regional metamorphism was estimated using Bt+Mag+Qtz and Bt+Ms geothermometers [Glassley 1983, Hoisch 1989]. Taking into account the field of the sillimanite P-T stability it is possible to conclude that the peak of metamorphism was reached at temperature about ТоС=550+/-30° C and pressure Р=4+/-1 kbar. Isotope thermochronology of the sample demonstrate nearly Svecofenian age 1.7-1.8 Ga of Vologda crystalline basement. K-Ar isotope dating of black and white mica demonstrates regular progression of ages in a concordance with closure temperature of each mineral. The apparent Bt age is about 1670 Ma and Ms age is 1710 Ma. The estimation of closure temperature (Tc) for each of the minerals using Dodsn's theory [Dodson 1973] and DCT computer program with concordance procedure of cooling rate simulation for the two coexisting minerals demonstrate value 340° C and и 460° C for Bt and Ms respectively. The rate of cooling in this temperature range is about 3° C/Ma and time span between closure temperatures of the two micas is about 40 Ma. The value of the cooling rate is a very typical for regional metamorphism conditions. The linear extrapolation of the simulated time-temperature trend to the thermal peak of the regional metamorphism (estimated by mineral equilibriums at 550° C) demonstrates that cooling of the metamorphic system from the thermal peak to 460° C(closure temperature of Ms) takes about 30-40 Ma. It is a value of systematic thermochronological correction to the muscovite apparent K-Ar age which has to be added to estimate the age of regional metamorphism, after that we finally receive the age 1750+/-40 Ma. U-Th-Pb system of monazite grains was tested by electron microprobe JEOL 8200 in IGEM RAS using CHIME method. The analysis of 8 grains demonstrated averaged value of age 1790+/-55 Ma. It is in a very good agreement with K-Ar isotope dating results. Moreover, the estimation of monazite closure temperature using experimental data of Pb diffusion [Smith & Giletti 1997] shows the value Tc=540-560° C which almost exactly corresponds to the peak temperature of regional metamorphism. It is also an explanation of the very close results of dating in different isotope systems (conservative U-Th-Pb system of monazite and flexible K-Ar system) in the condition of slow cooling and demonstrates the thermochronological modeling effectiveness.

Measuring Uranium Decay Rates for Advancement of Nuclear Forensics and Geochronology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parsons-Davis, Tashi

Radioisotopic dating techniques are highly valuable tools for understanding the history of physical and chemical processes in materials related to planetary sciences and nuclear forensics, and rely on accurate knowledge of decay constants and their uncertainties. The decay constants of U-238 and U-235 are particularly important to Earth science, and often the measured values with lowest reported uncertainties are applied, although they have not been independently verified with similar precision. New direct measurements of the decay constants of U-238, Th-234, U-235, and U-234 were completed, using a range of analytical approaches. An overarching goal of the project was to ensuremore » the quality of results, including metrological traceability to facilitate implementation across diverse disciplines. This report presents preliminary results of these experiments, as a few final measurements and calculations are still in progress.« less

Radiochronometry in the CMX-4 Exercise-Draft

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kristo, M. J.; Williams, R.; Gaffney, A. M.

In a recent international exercise, 10 international nuclear forensics laboratories successfully performed radiochronometry on 3 low-enriched uranium oxide samples, providing 12 analytical results using 3 different parent-daughter pairs serving as independent chronometers. The vast majority of the results were consistent with one another and consistent with the known processing history of the materials. In general, for these particular samples, mass spectrometry gave more accurate and more precise analytical results than decay counting measurements. In addition, the concordance of the 235U- 231Pa and 234U- 230Th chronometers confirmed the validity of the age dating assumption, increasing our confidence in the resulting conclusions.

Auspicious birth dates among Chinese in California.

PubMed

Almond, Douglas; Chee, Christine Pal; Sviatschi, Maria Micaela; Zhong, Nan

2015-07-01

The number eight is considered lucky in Chinese culture, e.g. the Beijing Olympics began at 8:08 pm on 8/8/2008. Given the potential for discretion in selecting particular dates of labor induction or scheduled Cesarean section (C-section), we consider whether Chinese-American births in California occur disproportionately on the 8th, 18th, or 28th day of the month. We find 2.3% "too many" Chinese births on these auspicious birth dates, whereas Whites show no corresponding increase. The increase in Chinese births is driven by higher parity C-sections: the number of repeat C-sections is 6% "too high" on auspicious birth dates. Sons born to Chinese parents account for the entire increase; daughter deliveries do not seem to be timed to achieve "lucky" birth dates. We also find avoidance of repeat C-section deliveries on the 4th, 14th, and 24th of the month, considered unlucky in Chinese culture. Finally, we replicate earlier work finding that Friday the 13th delivery dates are avoided and document a particularly large decrease among Chinese. For Whites and Chinese in California, mothers with higher levels of education are particularly likely to avoid delivering on the 13th. Copyright © 2015 Elsevier B.V. All rights reserved.

U-series vs 14C ages of deep-sea corals from the southern Labrador Sea: Sporadic development of corals and geochemical processes hampering estimation of ambient water ventilation ages

NASA Astrophysics Data System (ADS)

Hillaire-Marcel, Claude; Maccali, Jenny; Ménabréaz, Lucie; Ghaleb, Bassam; Blénet, Aurélien; Edinger, Evan

2017-04-01

Deep-sea scleractinian corals were collected with the remotely operated ROPOS vehicle off Newfounland. Fossil specimens of Desmophyllum dianthus were raised from coral graveyards at Orphan Knoll (˜1700m depth) and Flemish cap (˜2200 m depth), while live specimens were collected directly in overlying steep rock slopes. D. dianthus has an aragonitic skeleton and is thus particularly suited for U-Th dating. We obtained > 70 U-series ages along with > 20 14C measurements. Results display a discrete age distribution with two age clusters: a Bølling-Allerød and Holocene cluster with > 20 samples, and a Marine Isotope Stage (MIS) 5c cluster with ˜50 samples. Only two samples lay outside these clusters, at ˜ 64 ka and at ˜181 ka. Contrary to the New England seamounts where coral presence seems to have been continue through the last 70 ka, Orphan Knoll and Flemish Cap graveyards are marked by the absence of preserved specimens from MIS 2 to MIS 4 and throughout MIS 6. For filter-feeding deep-sea corals, access to food-rich waters is essential. Hence the Holocene and MIS 5 clusters observed in the Labrador basin might represent intervals linked to high food availability, either through production in the overlying water column, more effectively in relation to particulate and dissolved organic carbon transport via an active Western Boundary Undercurrent. Comparison of 230Th-ages vs 14C-ages in order to document changes in ventilation ages of the ambient water masses is equivocal due to the presence of some diagenetic and/or initial 230Th-excess. In addition, discrete diagenetic U-fluxes can be documented from 234U/238U vs 230Th/238U data. They point to a recent winnowing of sediment overlying the fossil corals that we link to the Holocene intensification of the Western Boundary Undercurrent, which resulted in driving Fe-Mn coatings.

Paleoenvironmental History of Long Island Sound, CT, USA

NASA Astrophysics Data System (ADS)

Varekamp, J. C.; Thomas, E.; Lugolobi, F.; Buchholtz Ten Brink, M. R.

2002-12-01

Western Long Island Sound (LIS) is an urban estuary heavily impacted by waste water effluents from CT and New York city. The estuary has suffered seasonal hypoxia since the 1970s, and in 1999 lobsters suffered > 90% mortality. We used short sediment cores that cover the last several 100 years to reconstruct the temperature/salinity history of LIS, as well as its history of hypoxic episodes. We measured oxygen and carbon isotopic compositions and Mg/Ca and Sr/Ca in calcite tests of the benthic foraminifer Elphidium excavatum, collected alive (Rose Bengal stained) in grab samples and in core samples, as proxies for bottom water temperature and salinity. The level of bottom water oxygenation is derived from the carbon isotope values in foraminiferal calcite, after correction for paleosalinity. The strong seasonal temperature fluctuation in Long Island Sound bottom waters (about 20oC) and the long livespan of the foraminifer make precise paleotemperature estimates difficult. The oxygen isotope data (in vivo effect 1.1 o/_{oo} of the foraminiferal tests were recalculated at constant mean-annual water temperature (12.5^{o}C) into paleosalinities, ranging between 18 and 33 ^{o}/oo. The oxygen and carbon isotope ratios of river water, Long Island Sound water and dissolved inorganic carbon were used to construct a mixing model for the Sound. From calculated paleosalinities and the modern mixing model we derived expected carbon isotope ratios, which were subtracted from the observed values. We argue that the residuals (excess carbon isotope values) are proportional to the amount of organic carbon that was oxidized in these waters, and as such represent a proxy for paleohypoxia. Data from nine cores show no long term trends in salinity over the last 1000 years, but show more pronounced variations over the last 100 years. Several low salinity events could be correlated with wet climate periods documented in Southern New England. The excess carbon isotope values were between 0 and -1 o/_{oo} for most of the last millennium but became much more negative in the mid 18^{th} to 19^{th} century, with strong variability in the 20^{th} century. The low salinity events of the last 100 years correlate strongly with strongly negative excess carbon isotope values, suggesting a linkage between the wet periods and oxidation of organic matter on the bottom of the Sound (algal blooms, warm periods?). This linkage between low salinity events and strongly negative excess carbon isotope values did not occur prior to 1900 AD. More detailed dating (^{210}Pb, ^{137}$Cs) will improve the time resolution and correlation between cores of the various documented events.

U-Pb (SHRIMP) Ages of Be and U-rich Opal in Tuffaceous Breccia at Spor Mountain, Utah: Interpreting a Record of Continuous Opal Formation, Episodic Be-U Mineralization, and Remobilization Events

NASA Astrophysics Data System (ADS)

Ayuso, R. A.; Vazquez, J. A.; Foley, N.; Lederer, G.; Jaskula, B.

2016-12-01

The Spor Mountain Fm. (SMF, ca. 21 Ma; Lindsey, 1977, Eco. Geol., v. 72, 219-232; Foley et al., 2012, USGS SIR 2010-5070-F, 1-43) hosts the largest deposit of volcanogenic-epithermal Be in the world (proven reserves 15,700 t/contained Be). Ore occurs mainly in cm-to-m-wide irregularly layered nodules of calcite, chalcedony, opal, fluorite, and bertrandite (Be4Si2O7(OH)2) in tuff breccias. U-Pb SHRIMP dating (adapted from Paces et al., 2004, GCA v. 68, 1591-1606; Neymark and Paces, 2013, EPSL v. 361, 98-109) of opal in nodules from SMF yielded 206Pb/238U ages coupled with multi-element analyses, e.g., Be, F, P, Si, Ti, REE, etc. The ages reveal periods of prolonged massive and fracture-filling opal formation that range from 55 Ma to 2 Ma. Age gaps are not prominent (a previous study of bulk samples identified opal ages of 21.8 Ma, 13-16 Ma, 8-9 Ma in SMF and 3.5 Ma in the overlying 6 Ma Topaz Mountain Fm.; Ludwig et al., 1980, EPSL, v. 46, 221-232). High values of Be/Si ( 5,000-20,000), Be/F, Be/P, and Be/U and oldest ages ( 55 to 28 Ma) occur in opal in nodule cores; outward, younger opal layers ( 28 to 7 Ma) decline in Be/Si but also include spikes of >5,000. A prominent U/Si spike (>300) occurs in opal between 6 Ma and 4 Ma, which may establish the age of U mineralization that occurs immediately east of Spor Mountain (the Yellow Chief U deposit). The occurrence of Be-rich opal older than 25 Ma in nodules within the 21 Ma (K-Ar date) tuff suggests that nodule formation may also be associated with older volcanism in the region. Opal that is younger than 21 Ma is thought to have formed by hydrothermal fluid interacting with Be-rich tuff. Geochemical modeling shows leaching of Be and other elements from volcanic glass and deposition of bertrandite upon reaction of the fluid with carbonate clasts in the tuff are viable mechanisms for the observed assemblages. Be concentrations in late nodular opal (<6 Ma) may reflect redistribution of earlier mineralization. The world-class deposits at Spor Mountain likely formed by prolonged magmatic-hydrothermal processes that include multiple Be mineralization and remobilization events.

Treatment Of Metal-Mine Effluents By Limestone Neutralization And Calcite Co-Precipitation

EPA Science Inventory

The U.S. Geological Survey - Leetown Science Center and the Colorado School of Mines have developed a remediation process for the treatment of metals in circumneutral mining influenced waters. The process involves treatment with a pulsed limestone bed (PLB) system, followed by c...

Radium isotopes in groundwater around Fuji Volcano, Japan -application for groundwater dating on volcanic area-

NASA Astrophysics Data System (ADS)

Ohta, T.; Mahara, Y.

2010-12-01

Young groundwater dating less than 100 years is possible to be obtained from environmental radioactivity with short half life, 3H+3He, 85Kr, or chemical material, CFC-12. The 3H+3He dating method is excellent method to estimate the residence time of shallow groundwater. The one of advantage of the method is small sample volume. The 3He in groundwater is originated by 3 sources, tritiogenic He, mantle He, radiogenic He produced in rock. Especially, as the contribution of the mantle He is greater than the radiogenic and triogenic, when 3H+3He dating apply for groundwater dating on volcanic area, we have to determine ratio of 3 sources. On the other hand, as 85Kr is only originated from atmosphere, it is excellent groundwater dating tracer on volcanic area. However, as 85Kr is ultra low concentration in groundwater, 85Kr is needed to separate from large amount of ground water about 10^5 L. Young groundwater dating by these methods has both advantages and disadvantages, but the disadvantages of the individual methods can be offset by using multiple tracers. Development of a lot of groundwater dating techniques is desired. Therefore, an application of radium isotopes which is simple origin to groundwater dating on volcanic area was tried. Ra-228 and Ra-226 are progenies of Th and U, respectively. The 228Ra/226Ra in ground waters depends on the Th/U in the relevant rocks. As the 228Ra and 226Ra in shallow groundwater on volcanic area are originated from only rock, and the collection of radium isotopes from groundwater is easier than that of 85Kr, implying that it is possible to be good tracer for volcanic area. We aim that groundwater age obtain from 228Ra/226Ra in groundwater and relevant rock on volcanic area. We determined that 228Ra/226Ra observed with river waters and the relevant rocks. The method applied for Kakitagawa around Fuji Volcano, Japan. The relevant rock of Kakitagawa is Mishima lava flow. Our method compared with 3H+3He dating. The residence time of Kakitagawa river water estimated from the 228Ra/226Ra activity ratio in river water and relevant rock is from 12-20 years, and agree well with 3H+3He age, suggesting that 228Ra/226Ra of groundwater could be used as a tool of residence time estimation of groundwater on volcanic area.

Experience from a (U-Th)/He thermochronology CAREER grant

NASA Astrophysics Data System (ADS)

Reiners, P. W.

2011-12-01

An accomplished demigod of geosciences once offered advice on strategizing a research career: "Do a combination of things: something conventional and safe, something better than anyone else, and something weird and risky." Balancing precious effort along these lines may be an ideal strategy, but reality often makes it difficult at best. One of the greatest benefits of a CAREER grant is the opportunity to implement a strategy integrating a stable base of different approaches like this, especially the weird and risky. My CAREER grant started with realization that the then resurgent radiogenic He dating technique had potential in an enormous range of problems outside traditional cookie-cutter approaches. Exploring applications ranging well beyond conventional tectonic and detrital studies, to meteorite histories, magmatic ascent rates, biogenic phosphates, wildfire, and multi-method dating may not have revolutionized geosciences, but some of the unique insights that resulted are both conceptually and practically valuable and could not have been achieved through traditional funding avenues. Moreover, weird and risky adaptations, in this case of a versatile geochronologic tool, are well suited for student involvement as student side projects, which are scientifically and intellectually nourishing for both student and faculty. Some of these relatively short term explorations (e.g., dating turquoise, travertine, cassiterite, Neolithic pottery, pseudotachylite, mammoth teeth, fault gouge, impact craters, etc.) end up not leading far, or pointing to a route that requires much more work to explore fully. But there is value in cliffed-out side canyons, not the least of which is showing students that it is ok to eschew formulaic karaoke geology. The strategic career advice above accommodates outreach/education. In my experience, the more organic the synthesis between outreach and research, the more naturally functional, rewarding, and sustainable the efforts. One way to incorporate outreach is simply to open one's lab to the community to provide basic but valuable analyses. In my case this was routine (U-Th)/He dating for tectonic and geomorphic studies. This requires significant commitment to training and analytical reliability, but also provides broad scientific enrichment to the lab. In addition to a huge number of rocks-in-the-mailbox users, during the grant our lab hosted >50 visiting users from >35 institutions, generating thousands of analyses for outside users alone. But simply opening one's lab is not particularly distinctive outreach. A more important and consuming initiative was our summer workshops on thermochronology. These featured teaching and a fieldtrip but, most importantly, the chance for 8 or 9 visiting students to analyze as many (U-Th)/He (and recently, with help from colleagues, U/Pb and FT) dates as they could cram into a two-week period, interpret them, and present their results. The high-intensity workshops generated large amounts of data, many meeting abstracts, a few papers, valuable collaborations with advisors, and rewarding experiences with diverse students. They require a lot of time and effort, including stress of insuring continuous smooth analytical performance. One nugget of experience from these is that they are more rewarding when centered on a theme (e.g., Antarctichron 2011).

Interaction between U and Th on their uptake, distribution, and toxicity in V S. alfredii based on the phytoremediation of U and Th.

PubMed

Huang, Zhenling; Tang, Siqun; Zhang, Lu; Ma, Lijian; Ding, Songdong; Du, Liang; Zhang, Dong; Jin, Yongdong; Wang, Ruibing; Huang, Chao; Xia, Chuanqin

2017-01-01

Variant Sedum alfredii Hance (V S. alfredii) could simultaneously take up U and Th from water with the highest concentrations recorded as 1.84 × 10 4 and 6.72 × 10 3  mg/kg in the roots, respectively. Th stimulated U uptake by V S. alfredii roots at Th 10 (10 μM of Th), however, the opposite was observed at Th 100 (100 μM of Th). A similar result was found in the effect of U on the uptake of Th by V S. alfredii. Subcellular fractionation studies of V S. alfredii indicated that U and Th were mainly stored in cell wall fraction, and much less was found in organelle and soluble fractions. Chemical form examination results showed that water-soluble U and Th were the predominant chemical forms in this plant. Addition of the other radionuclide in aqueous solutions altered the concentration and percentage of U or Th in cell wall fraction and in water-soluble form, resulting in the change of the uptake capacity of U or Th by V S. alfredii roots. Comparing with single U or Th treatment, the plant cells revealed more swollen chloroplasts and enhanced thickening in cell walls under the U 100  + Th 100 treatment, as observed by TEM. Those results collectively displayed that V S. alfredii may be utilized as a potential plant to simultaneously remove U and Th from aqueous solutions (rhizofiltration).

Uranium isotope fractionation in biogenic carbonates: biological effects

NASA Astrophysics Data System (ADS)

Chen, X.; Romaniello, S. J.; Herrmann, A. D.; Anbar, A. D.

2017-12-01

Recent laboratory experiments have demonstrated small but potentially significant isotope fractionation ( 0.10 ‰ for 238U/235U) during uranium (U) incorporation into abiotic calcite and aragonite, with heavier U isotopes preferentially enriched in the precipitates [1]. In contrast, measurements of natural biogenic carbonates to date have not been able to resolve significant U isotopic fractionation from seawater although this might be expected given a typical measurement precision of ± 0.10 ‰. Determining whether or not biogenic carbonates display U isotope fractionation similar to abiotic carbonates could have important implications for understanding the mechanisms of U incorporation into various biogenic carbonates. Furthermore, because most marine carbonates are biogenic, the extent of isotopic fractionation, if any, could have important implications for the interpretation of sedimentary carbonates record similar to effects observed for Cr and B isotopes [2, 3]. To resolve this discrepancy, we utilized a higher precision 238U/235U method which uses larger sample sizes to improve measurement precision of natural samples to ± 0.02 ‰ (2 se, N = 6) [4]. Using this method, we have surveyed 238U/235U in primary biogenic skeletal carbonates including scleractinian corals, green and red algae, and mollusks, as well as non-skeletal carbonates such as stromatolites, ooids, and carbonate sands from the Bahamas, Gulf of California, and French Polynesia. New high-precision U isotopes measurements reveal that biogenic skeletal carbonates are typically 0.02 - 0.08 ‰ heavier than modern seawater. Scleractinian corals display values closest to seawater (- 0.37 ‰), while green algae, red algae, mollusks, and echinoderms display variable but larger extents of fractionation up to 0.08 ‰. The direction and magnitude of U isotope fractionation in these biogenic precipitates are generally consistent with results from abiotic coprecipitation experiments, but may be subject to variations in U speciation and carbonate chemistry at calcification sites. [1] Chen et a., (2016), GCA, 188, 189-207. [2] Wang et a., (2016), Geobiology, 5, 51-64. [3] Pagani et al., (2005) GCA, 69, 953-961. [4] Andersen et al., (2016) CG, 420, 11-22.

History of the Seattle District, 1896-1968: 72 Years in Peace and War

DTIC Science & Technology

1969-03-01

WILLIAMS - CHIEF ENGINEER CORPS OF TOPOGRAPHICAL ENGINEERS ESTABLISHED - 5 JULY 1838 JOHN J. ABERT - CHIEF (1838-1861) STEPHEN H. LONG - CHIEF (1861...1863) CONSOLIDATED WITH CORPS OF ENGINEERS 3 MARCH 1863 WILLIAM F. CASSIDY LIEUTENANT GENERAL: CHIEF OF ENGINEERS (1 JULY 1965 to date) 1-2...of the great Northwest territories was done by Army officers--Captains Merriwether Lewis and William Clark, 1804-06; 1/u.S. Army Engineers, l70th

White-Light Optical Information Processing and Holography.

DTIC Science & Technology

1987-01-23

is now with Martin Marietta Laboratories, 1450 S. Rolling Rd., Baltimore, Maryland 21227. Abstract Computer simulation and experimental results lof c...Final Report on Contracts AFOSR-81-0148 and AFOSR-83-01 .40 Period Covered (February 15, 1981 - May 14, 1986) Date: December 16, 1986 E T [C E LECTE 87...4Unclassified SEPC-U41Ty CLASSIFICATION 0; TH!S~ PAGE REPORT DOCUMENTATION PAGE IREPORT SECURITY C1ASSIFICATION Io. RESTRICTIVEq* Unclassified R 1 J 1

Reunification of Korea: A Forty Year Stalemate,

DTIC Science & Technology

1986-04-07

TASK AREA & WORK UNIT NUMBERS U.S. Army War College Carlisle Barracks, PA 17013 I. CONTROLLING OFFICE NAME AND ADDRESS 12. REPORT DATE 7 April 1986 SAME...South Korea, the north have proposed that they co-h.’,cst these games. This cannot work as South Korca i:: not th: hcst of the 1988 Olympic Games--the...events is enormous. The President of the International Olympic Committee must work very closely with all countries in an attempt to gain maximum

230Th/238U dating of hydrothermal sulfides from Duanqiao hydrothermal field, Southwest Indian Ridge

NASA Astrophysics Data System (ADS)

Yang, Weifang; Tao, Chunhui; Li, Huaiming; Liang, Jin; Liao, Shili; Long, Jiangping; Ma, Zhibang; Wang, Lisheng

2017-06-01

Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones at the central volcano, at 50°28'E in the ultraslow-spreading Southwest Indian Ridge (SWIR). Twenty-eight subsamples from a relict chimney and massive sulfides were dated using the 230Th/238U method. Four main episodes of hydrothermal activity were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. The periodic character of hydrothermal activity may be related to the heat source provided by the interaction of local magmatism and tectonism. The estimated mean growth rate of the sulfide chimney is <0.02 mm/yr. This study is the first to estimate the growth rate of chimneys in the SWIR. The maximum age of the relict chimney in Duanqiao hydrothermal filed is close to that of the chimneys from Mt. Jourdanne (70 kyrs). The hydrothermal activity in Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. The preliminarily estimated reserves of sulfide ores of Duanqiao are approximately 0.5-2.9 million tons.

A 500-year seasonally resolved δ18O and δ13C, layer thickness and calcite aspect record from a speleothem deposited in the Han-sur-Lesse cave, Belgium

NASA Astrophysics Data System (ADS)

Van Rampelbergh, M.; Verheyden, S.; Allan, M.; Quinif, Y.; Cheng, H.; Edwards, L. R.; Keppens, E.; Claeys, P.

2015-06-01

Speleothem δ18O and δ13C signals enable climate reconstructions at high resolution. However, scarce decadal and seasonally resolved speleothem records are often difficult to interpret in terms of climate due to the multitude of factors that affect the proxy signals. In this paper, a fast-growing (up to 2 mm yr-1) seasonally laminated speleothem from the Han-sur-Lesse cave (Belgium) is analyzed for its δ18O and δ13C values, layer thickness and changes in calcite aspect. The studied record covers the period between AD 2001 and 1479 as indicated by layer counting and confirmed by 20 U / Th ages. The Proserpine proxies are seasonally biased and document drier (and colder) winters on multidecadal scales. Higher δ13C signals reflect increased prior calcite precipitation (PCP) and lower soil activity during drier (and colder) winters. Thinner layers and darker calcite relate to slower growth and exist during drier (and colder) winter periods. Exceptionally dry (and cold) winter periods occur from 1565 to 1610, at 1730, from 1770 to 1800, from 1810 to 1860, and from 1880 to 1895 and correspond to exceptionally cold periods in historical and instrumental records as well as European winter temperature reconstructions. More relative climate variations, during which the four measured proxies vary independently and display lower amplitude variations, occur between 1479 and 1565, between 1610 and 1730, and between 1730 and 1770. The winters during the first and last periods are interpreted as relatively wetter (and warmer) and correspond to warmer periods in historical data and in winter temperature reconstructions in Europe. The winters in the period between 1610 and 1730 are interpreted as relatively drier (and cooler) and correspond to generally colder conditions in Europe. Interpretation of the seasonal variations in δ18O and δ13C signals differs from that on a decadal and multidecadal scale. Seasonal δ18O variations reflect cave air temperature variations and suggest a 2.5 °C seasonality in cave air temperature during the two relatively wetter (and warmer) winter periods (1479-1565 and 1730-1770), which corresponds to the cave air temperature seasonality observed today. Between 1610 and 1730, the δ18O values suggest a 1.5 °C seasonality in cave air temperature, indicating colder summer temperatures during this drier (and cooler) interval. The δ13C seasonality is driven by PCP and suggests generally lower PCP seasonal effects between 1479 and 1810 compared to today. A short interval of increased PCP seasonality occurs between 1600 and 1660, and reflects increased PCP in summer due to decreased winter recharge.

Laser depth profiling of diffusion and alpha ejection profiles in Durango apatite: testing the fundamental parameters of apatite (U-Th)/He dating

NASA Astrophysics Data System (ADS)

van Soest, M. C.; Monteleone, B. D.; Boyce, J. W.; Hodges, K.

2009-12-01

Since its development (e.g. Zeitler et al., 1987, Lippolt et al., 1994, Farley et al., 1996, Wolf et al., 1996) as a viable low temperature thermochronological method (U-Th)/He dating of apatite has become a popular and widely applied low temperature thermochronometer. The method has been applied with success to a great variety of geological problems, and the fundamental parameters of the method: the bulk diffusion parameters of helium in apatite, and the calculated theoretical helium stopping distance in apatite used to correct the ages for the effects of alpha ejection appear sound. However, the development of the UV laser microprobe technique for the (U-Th)/He method (Boyce et al., 2006) allows for in-situ testing of the helium bulk diffusion parameters (Farley, 2000) and can provide a direct measurement of the alpha ejection distance in apatite. So, with the ultimate goal of further developing the in-situ (U-Th)/He dating method and micro-analytical depth profiling techniques to constrain cooling histories in natural grains, we conducted a helium depth profiling study of induced diffusion and natural alpha ejection profiles in Durango apatite. For the diffusion depth profiling, a Durango crystal was cut in slabs oriented parallel and perpendicular to the crystal c-axis. The slabs were polished and heated using different temperature and time schedules to induce predictable diffusion profiles based on the bulk helium diffusion parameters in apatite. Depth profiling of the 4He diffusion profiles was done using an ArF excimer laser. The measured diffusion depth profiles at 350°, 400°, and 450° C coincide well with the predicted bulk diffusion curves, independent of slab orientation, but the 300° C profiles consistently deviate significantly. The possible cause for this deviation is currently being investigated. Alpha ejection profiling was carried out on crystal margins from two different Durango apatite crystals, several faces from each crystal were analyzed to evaluate the potential effects of crystallographic orientation on alpha ejection. The results from both crystals were very reproducible irrespective of crystal surface used and confirm the findings of Monteleone et al. (2008) that the measured alpha ejection profiles deviate significantly from and are shorter than the calculated theoretical average value. Efforts are currently underway to better constrain the measured alpha ejection distance and measure alpha ejection profiles in apatite crystals other than Durango apatite. References: Boyce, J. et al. (2006) GCA 70, pp. 3031-3039. Farley, K. et al. (1996) GCA 60, pp. 4223-4229. Farley, K. (2006) JGR SE 105, p. 2903-2914. Lippolt, H. et al. (1994) Chem Geol 112, pp. 179-191. Monteleone, B. et al. (2008) Eos Trans AGU, 89 Fall Meeting V53B-2162. Wolf, R. et al. (1996) GCA 60, pp. 4231-4240. Zeitler, P. et al. (1987) GCA 51, pp. 2865-2868.

Treatment Of Metal-Mine Effluents By Limestone Neutralization And Calcite Co-Precipitation (Presentation)

EPA Science Inventory

The U.S. Geological Survey - Leetown Science Center and the Colorado School of Mines have developed a remediation process for the treatment of metals in circumneutral mining influenced waters. The process involves treatment with a pulsed limestone bed (PLB) system, followed by c...

Experimental determination of U and Th partitioning between clinopyroxene and natural and synthetic basaltic liquid

NASA Technical Reports Server (NTRS)

Latourrette, T. Z.; Burnett, D. S.

1992-01-01

Experimental measurements of U and the partition coefficients between clinopyroxene and synthetic and natural basaltic liquid are presented. The results demonstrate that crystal-liquid U-Th fractionation is fO2-dependent and that U in terrestrial magmas is not entirely tetravalent. During partial melting, the liquid will have a Th/U ratio less than the clinopyroxene in the source. The observed U-238 - Th-230 disequilibrium in MORB requires that the partial melt should have a U/Th ratio greater than the bulk source and therefore cannot result from clinopyroxene-liquid partitioning. Further, the magnitudes of the measured partition coefficients are too small to generate significant U-Th fractionation in either direction. Assuming that clinopyroxene contains the bulk of the U and Th in the MORB source, the results indicate that U-238 - Th-230 disequilibrium in MORB may not be caused by partial melting at all.

Mineral chemistry and shrimp U-Pb Geochronology of mesoproterozoic polycrase-titanite veins in the sullivan Pb-Zn-Ag Deposit, British Columbia

USGS Publications Warehouse

Slack, J.F.; Aleinikoff, J.N.; Belkin, H.E.; Fanning, C.M.; Ransom, P.W.

2008-01-01

Small polycrase-titanite veins 0.1-2 mm thick cut the tourmalinite feeder zone in the deep footwall of the Sullivan Pb-Zn-Ag deposit, southeastern British Columbia. Unaltered, euhedral crystals of polycrase and titanite 50-100 ??m in diameter are variably replaced by a finer-grained alteration-induced assemblage composed of anhedral polycrase and titanite with local calcite, albite, epidote, allanite, and thorite or uranothorite (or both). Average compositions of the unaltered and altered polycrase, as determined by electron-microprobe analysis, are (Y0.38 REE0.49 Th0.10 Ca0.04 Pb0.03 Fe0.01U0.01) (Ti1.48 Nb0.54 W0.04 Ta0.02)O6 and (Y0.42 REE0.32 Th0.15 U0.06 Ca0.04 Pb0.01 Fe0.01) (Ti1.57 Nb0.44 W0.04 Ta0.02)O6, respectively. The unaltered titanite has, in some areas, appreciable F (to 0.15 apfu), Y (to 0.40 apfu), and Nb (to 0.13 apfu). SHRIMP U-Pb geochronology of eight grains of unaltered polycrase yields a weighted 207Pb/206Pb age of 1413 ?? 4 Ma (2??) that is interpreted to be the age of vein formation. This age is 50-60 m.y. younger than the ca. 1470 Ma age of synsedimentary Pb-Zn-Ag mineralization in the Sullivan deposit, which is based on combined geological and geochronological data. SHRIMP ages for altered polycrase and titanite suggest later growth of minerals during the ???1370-1320 Ma East Kootenay and ???1150-1050 Ma Grenvillian orogenies. The 1413 ?? 4 Ma age for the unaltered polycrase in the veins records a previously unrecognized post-ore (1370 Ma) mineralizing event in the Sullivan deposit and vicinity. The SHRIMP U-Pb age of the polycrase and high concentrations of REE, Y, Ti, Nb, and Th in the veins, together with elevated F in titanite and the absence of associated sulfides, suggest transport of these high-field-strength elements (HFSE) by F-rich and S-poor hydrothermal fluids unrelated to the fluids that formed the older Fe-Pb-Zn-Ag sulfide ores of the Sullivan deposit. Fluids containing abundant REE, HFSE, and F may have been derived from a geochemically specialized magma such as those that form alkaline granites, pegmatites, or carbonatites. In an alternative model. preferred here, these fluids were associated with a rift-related, crustal metasomatic event in the region. Determination of a Mesoproterozoic age for the polycrase-titanite veins establishes the first known occurrence of pre-Grenvillian REE-rich mineralization in the Belt-Purcell basin.

Palaeohydrology of a 3D-maze cave (Hermannshöhle, Lower Austria)

NASA Astrophysics Data System (ADS)

Schober, Andrea; Plan, Lukas

2013-04-01

The 4.4 km-long Hermannshöhle (located in Kirchberg/Wechsel, Lower Austria) is one of the largest caves in the Lower Austroalpine Unit. It is developed in an isolated block of carbonate marble, taking up only 140 x 160 m of ground area and 73 m of elevation difference. The cave is unusual in two respects: (a) its dense network of corridors is arranged in a three-dimensional maze and (b) the most outstanding macro- and micromorphologic features were caused by paragenesis. Speleothems are abundant throughout the cave comprising flowstones, dripstones, helictites, popcorn, calcite rafts, a shield, and moonmilk. Even though most passages are canyon-shaped, the cave shows exclusively phreatic features. Sediment fills are abundant as well, mostly covering the floor of passages to an unknown depth, containing mainly allochthonous material, i.e. schists and gneisses. Besides some vadose dripwater the cave is dry today. A conspicuous feature is the lack of a single water path and instead a maze with multiple flow paths formed. Another interesting feature is that one part of the cave developed below the nearby Ramsbach brook but is still dry. There are small ponors reported from the Ramsbach brook (which were observed during river regulation) indicating an actively draining karst system, which is not yet explored. The aim of this study was to enlighten the palaeohydrology of this cave using morphological and sedimentological observations as well as U/Th dating of speleothems. First results show that the palaeo-environment and the hydrologic setting of the Hermannshöhle were drastically different from today. Undersaturated water sourced from nearby non-karstic gneisses and schists gave rise to well-developed contact karst features. Surprisingly the palaeo flow direction deduced from indicators like scallops and sediment structures was opposite to the flow direction of the present nearby brooks (Rams- and Feistrizbach). Following pulses of clastic sediment input a distinct system of paragenetic canyons developed creating the unique maze character of the cave.

Stable isotope records of convection variability in the West Pacific Warm Pool from fast-growing stalagmites

NASA Astrophysics Data System (ADS)

Maupin, C. R.; Partin, J. W.; Quinn, T. M.; Shen, C.; Lin, K.; Taylor, F. W.; Sinclair, D. J.; Banner, J. L.

2010-12-01

The potential response of the tropical Pacific to ongoing anthropogenic global warming conditions is informed by instrumental data, model predictions and climate proxy evidence. However, these distinct lines of evidence lead to opposing predictions in terms of the nature of interannual (ENSO) variability in a warming world. Interpreted in an ENSO framework, warming in the tropical Pacific may elicit a zonally asymmetrical response and lead to an intensified Walker Circulation (more ‘La Niña - like’). Alternatively, discrepancies in the increasing rates of latent heat flux and rainfall due to warming conditions may in fact reduce Walker Circulation (more ‘El Niño - like’). However, in order for such a framework to be useful in the context of future climate change, some knowledge of the natural variability in the strength of Walker Circulation components is required. The extant instrumental data are not of sufficient temporal length to fully assess the spectrum of natural variability in such climate components. Oxygen isotope records from tropical speleothems have been successfully used to document the nature of precessional forcing on precipitation and atmospheric circulation patterns throughout the tropics. Typical stalagmite growth rates of 10-100 μm yr-1 allow decadally resolved records of δ18O variability on time scales of centuries to millennia and beyond. Here we present the initial results from calcite stalagmites of heretofore unprecedented growth rates (~1-4 mm yr-1) in a cave in northwest Guadalcanal, Solomon Islands (~9°S, 160°E). These stalagmites have been absolutely dated by U-Th techniques and indicate stalagmite growth spanning ~1650 to 2010 CE. The δ18O records from stalagmites provide evidence for changes in convection in the equatorial WPWP region of the SPCZ: the rising limb of the Pacific Walker Circulation, and therefore provide critical insight into changes in zonal atmospheric circulation across the Pacific.

40Ar/ 39Ar, K-Ar and 230Th- 238U dating of the Laschamp excursion: A radioisotopic tie-point for ice core and climate chronologies

NASA Astrophysics Data System (ADS)

Singer, Brad S.; Guillou, Hervé; Jicha, Brian R.; Laj, Carlo; Kissel, Catherine; Beard, Brian L.; Johnson, Clark M.

2009-08-01

A brief period of enhanced 10Be flux that straddles the interstadial warm period known as Dansgaard-Oeschger event 10 in Greenland and its counterpart in Antarctica, the Antarctic Isotope Maximum 10 is but one consequence of the weakening of Earth's magnetic field associated with the Laschamp excursion. This 10Be peak measured in the GRIP ice core is dated at 41,250 y b2k (= before year 2000 AD) in the most recent GICC05 age model obtained from the NorthGRIP core via multi-parameter counting of annual layers. Uncertainty in the age of the 10Be peak is, however, no better than ± 1630 y at the 95% confidence level, reflecting accumulated error in identifying annual layers. The age of the Laschamp excursion [Guillou, H., Singer, B.S., Laj, C., Kissel, C., Scaillet, S., Jicha, B., 2004. On the age of the Laschamp geomagnetic excursion. Earth Planet. Sci. Lett. 227, 331-343.] is revised on the basis of new 40Ar/ 39Ar, unspiked K-Ar and 238U- 230Th data from three lava flows in the Massif Central, France, together with the 40Ar/ 39Ar age of a transitionally magnetized lava flow at Auckland, New Zealand. Combined, these data yield an age of 40,700 ± 950 y b2k, where the uncertainty includes both analytical and systematic ( 40K and 230Th decay constant) errors. Taking the radioisotopic age as a calibration tie point suggests that the layer-counting chronologies for the NorthGRIP and GISP2 ice cores are more accurate and precise than previously thought at depths corresponding to the Laschamp excursion.

600 yr High-Resolution Climate Reconstruction of the Atlantic Multidecadal Oscillation deduced from a Puerto Rican Speleothem

NASA Astrophysics Data System (ADS)

Vieten, Rolf; Winter, Amos; Scholz, Denis; Black, David; Spoetl, Christoph; Winterhalder, Sophie; Koltai, Gabriella; Schroeder-Ritzrau, Andrea; Terzer, Stefan; Zanchettin, Davide; Mangini, Augusto

2016-04-01

A multi-proxy speleothem study tracks the regional hydrological variability in Puerto Rico and highlights its close relation to the Atlantic Multidecadal Oscillation (AMO) describing low-frequency sea-surface temperature (SST) variability in the North Atlantic ocean. Our proxy record extends instrumental observations 600 years into the past, and reveals the range of natural hydrologic variability for the region. A detailed interpretation and understanding of the speleothem climate record is achieved by the combination of multi-proxy measurements, thin section petrography, XRD analysis and cave monitoring results. The speleothem was collected in Cueva Larga, a one mile-long cave system that has been monitored since 2012. MC-ICPMS 230Th/U-dating reveals that the speleothem grew constantly over the last 600 years. Trace element ratios (Sr/Ca and Mg/Ca) as well as stable isotope ratios (δ18O and δ13C) elucidate significant changes in atmospheric precipitation at the site. Monthly cave monitoring results demonstrate that the epikarst system responds to multi-annual changes in seepage water recharge. The drip water isotope and trace element composition lack short term or seasonal variability. This hydrological system creates favorable conditions to deduce decadal climate variability from Cueva Larga's climate record. The speleothem time series mimics the most recent AMO reconstruction over the last 200 years (Svendsen et al., 2014) with a time lag of 10-20 years. The lag seems to results from slow atmospheric signal transmission through the epikarst but the effect of dating uncertainties cannot be ruled out. Warm SSTs in the North Atlantic are related to drier conditions in Puerto Rico. During times of decreased rainfall a relative increase in prior calcite precipitation seems to be the main process causing increased Mg/Ca trace element ratios. High trace element ratios correlate to higher δ13C values. The increase in both proxies indicates a shift towards time periods of decreased rainfall. Before 1800 there were two intervals of increased Mg/Ca and δ13C values (dryer conditions) lasting several decades in our speleothem record centered around 1680 CE and 1470 CE. The elevated ratios indicate that drier conditions than present may have occurred in the region during periods of warm Atlantic surface waters.

A High-Resolution ENSO-Driven Rainfall Record Derived From an Exceptionally Fast Growing Stalagmite From Niue Island (South Pacific)

NASA Astrophysics Data System (ADS)

Troy, S.; Aharon, P.; Lambert, W. J.

2012-12-01

El Niño-Southern Oscillation's (ENSO) dominant control over the present global climate and its unpredictable response to a global warming makes the study of paleo-ENSO important. So far corals, spanning the Tropical Pacific Ocean, are the most commonly used geological archives of paleo-ENSO. This is because corals typically exhibit high growth rates (>1 cm/yr), and reproduce reliably surface water temperatures at sub-annual resolution. However there are limitations to coral archives because their time span is relatively brief (in the order of centuries), thus far making a long and continuous ENSO record difficult to achieve. On the other hand stalagmites from island settings can offer long and continuous records of ENSO-driven rainfall. Niue Island caves offer an unusual opportunity to investigate ENSO-driven paleo-rainfall because the island is isolated from other large land masses, making it untainted by continental climate artifacts, and its geographical location is within the Tropical Pacific "rain pool" (South Pacific Convergence Zone; SPCZ) that makes the rainfall variability particularly sensitive to the ENSO phase switches. We present here a δ18O and δ13C time series from a stalagmite sampled on Niue Island (19°00' S, 169°50' W) that exhibits exceptionally high growth rates (~1.2 mm/yr) thus affording a resolution comparable to corals but for much longer time spans. A precise chronology, dating back to several millennia, was achieved by U/Th dating of the stalagmite. The stalagmite was sampled using a Computer Automated Mill (CAM) at 300 μm increments in order to receive sub-annual resolution (every 3 months) and calcite powders of 50-100 μg weight were analyzed for δ18O and δ13C using a Continuous Flow Isotope Ratio Mass Spectrometer (CF-IRMS). The isotope time series contains variable shifts at seasonal, inter-annual, and inter-decadal periodicities. The δ13C and δ18O yield ranges of -3.0 to -13.0 (‰ VPDB) and -3.2 to -6.2 (‰ VPDB), respectively. The presentation will describe the factors impacting the seasonal, inter-annual and inter-decadal variability in a highly resolved ENSO record.

600 yr High-Resolution Climate Reconstruction of the Atlantic Multidecadal Variability deduced from a Puerto Rican Speleothem

NASA Astrophysics Data System (ADS)

Winter, A.; Vieten, R.

2015-12-01

A multi-proxy speleothem study tracks the regional hydrological variability in Puerto Rico and highlights its close relation to the Atlantic Multidecadal Oscillation. Our proxy record extends instrumental observations 600 years into the past, and reveals the range of natural hydrologic variability for the region. A detailed interpretation and understanding of the speleothem climate record is achieved by the combination of multi-proxy measurements, thin section petrography, XRD analysis and cave monitoring results. The speleothem was collected in Cueva Larga, a one mile-long cave system that has been monitored since 2012. MC-ICPMS 230Th/U-dating reveals that the speleothem grew constantly over the last 600 years. Trace element ratios (Sr/Ca and Mg/Ca) as well as stable isotope ratios (δ18O and δ13C) elucidate significant changes in atmospheric precipitation at the site. Monthly cave monitoring results demonstrate that the epikarst system responds to multi-annual changes in seepage water recharge. The drip water isotope and trace element composition lack short term or seasonal variability. This hydrological system creates favorable conditions to deduce decadal climate variability from Cueva Larga's climate record. The speleothem time series mimics the most-recently published AMO reconstruction over the last 200 years with a time lag of 10-20 years. The time lag seems to results from slow atmospheric signal transmission through the epikarst but the effect of dating uncertainties cannot be ruled out. Warm SSTs in the North Atlantic are related to drier conditions in Puerto Rico. During times of decreased rainfall a relative increase in prior calcite precipitation seems to be the main process causing increased Mg/Ca trace element ratios. High trace element ratios correlate to higher δ13C values. The increase in both proxies indicates a shift towards time periods of decreased rainfall. Over the past 600 years there are two intervals of increased Mg/Ca and δ13C values lasting several decades in our speleothem record. They are centered around 1680 CE and 1470 CE. The elevated ratios indicate that drier conditions than present occurred in the region during periods of warm Atlantic surface waters. This may be a precursor of conditions now and to come.

KSC-06pd2047

NASA Image and Video Library

2006-09-06

KENNEDY SPACE CENTER, FLA. - Space Shuttle Atlantis is bathed in light on Launch Pad 39B. Atlantis was originally scheduled to launch at 12:29 p.m. EDT on this date, but a 24-hour scrub was called by mission managers due to a concern with Fuel Cell 1. During the STS-115 mission, Atlantis' astronauts will deliver and install the 17.5-ton, bus-sized P3/P4 integrated truss segment on the station. The girder-like truss includes a set of giant solar arrays, batteries and associated electronics and will provide one-fourth of the total power-generation capability for the completed station. This mission is the 116th space shuttle flight, the 27th flight for orbiter Atlantis, and the 19th U.S. flight to the International Space Station. STS-115 is scheduled to last 11 days with a planned landing at KSC. Photo credit: NASA/Jim Grossmann

Finding the "true" age: ways to read high-precision U-Pb zircon dates

NASA Astrophysics Data System (ADS)

Schaltegger, U.; Schoene, B.; Ovtcharova, M.; Sell, B. K.; Broderick, C. A.; Wotzlaw, J.

2011-12-01

Refined U-Pb dating techniques, applying an empirical chemical abrasion treatment prior to analysis [1], and using a precisely calibrated double isotope Pb, U EARTHTIME tracer solution, have led to an unprecedented <0.1% precision and accuracy of obtained 206Pb/238U dates of single zircon crystals or fragments. Results very often range over 10e4 to 10e6 years and cannot be treated as statistically singular age populations. The interpretation of precise zircon U-Pb ages is biased by two problems: (A) Post-crystallization Pb loss from decay damaged areas is considered to be mitigated by applying chemical abrasion techniques. The success of such treatment can, however, not be assumed a priori. The following examples demonstrate that youngest zircons are not biased by lead loss but represent close-to-youngest zircon growth: (i) coincidence of youngest zircon dates with co-magmatic titanite in tonalite; (ii) coincidence with statistically equivalent clusters of 206Pb/238U dates from zircon in residual melts of cogenetic mafic magmas; (iii) youngest zircons in ash beds of sedimentary sequences do not violate the stratigraphic superposition, whereas conventional statistical interpretation (mean or median values) does; (iv) results of published inter-laboratory cross-calibration tests using chemical abrasion on natural zircon crystals of the same sample arrive at the same 206Pb/238U result within <0.1% (e.g., [2]); (v) Youngest crystals coincide in age with the astronomical age of hosting cyclic sediments. Residual lead loss may, however, still be identified in the case of single, significantly younger dates (>3 sigma), and are common in many pre-Triassic and hydrothermally altered rocks. (B) Pre-eruptive/pre-intrusive growth is found to be the main reason for scattered zircon ages in igneous rocks. Zircons crystallizing from the final magma batch are called autocrystic [3]. Autocrystic growth will happen in a moving or stagnant magma shortly before or after the rheological lockup by the crystals. Last crystallizing zircons in the interstitial melt may therefore postdate emplacement of the magma. The range of 206Pb/238U ages may yield a time frame for the cooling of a given magma batch, which could be added to quantitative thermal models of magma emplacement and cooling. Hf isotopes and trace elements of the dated zircon are used to trace the nature of the dated grains [4], specifically for identification of crystals that form earlier at lower crustal levels (antecrysts). Autocrystic zircons typically show, e.g., distinctly different (higher or lower) Th/U ratios. Cautiously interpreted high-precision U-Pb data of chemically abraded zircons may resolve the evolution of a magmatic system from its roots to final emplacement or eruption, trace fractional crystallization of zircon and other accessory and major phases in a magma batch, and add quantitative temporal constraints to thermal models. The proposed interpretation scheme thus adds significant information compared to conventional statistics. [1] Mattinson J., 2005, Chem. Geol. 200, 47-66; ; [2] Slama et al., 2008, Chem. Geol. 249, 1-35; [3] Miller et al., 2007, J. Volc. Geotherm. Res. 167, 282-299; [4] Schoene et al., 2010, Geochim. Cosmochim. Acta 74, 7144-7159

Diagenesis of Upper Carboniferous rocks in the Ouachita foreland shelf in mid-continent USA: an overview of widespread effects of a Variscan-equivalent orogeny

USGS Publications Warehouse

Walton, A.W.; Wojcik, K.M.; Goldstein, R.H.; Barker, C.E.

1995-01-01

Diagenesis of Upper Carboniferous foreland shelf rocks in southeastern Kansas took place at temperatures as high as 100-150?? C at a depth of less than 2 km. High temperatures are the result of the long distance (hundreds of kilometers) advection of groundwater related to collisional orogeny in the Ouachita tectonic belt to the south. Orogenic activity in the Ouachita area was broadly Late Carboniferous, equivalent to the Variscan activity of Europe. Mississippi Valley-type Pb-Zn deposits and oil and gas fields in the US midcontinent and elsewhere are commonly attributed to regional groundwater flow resulting from such collisional events. This paper describes the diagenesis and thermal effects in sandstone and limestone of Upper Carboniferous siliciclastic and limestone-shale cyclothems, the purported confining layer of a supposed regional aquifer. Diagenesis took place in early, intermediate, and late stages. Many intermediate and late stage events in the sandstones have equivalents in the limestones, suggesting that the causes were regional. The sandstone paragenesis includes siderite cement (early stage), quartz overgrowths (intermediate stage), dissolution of feldspar and carbonates, followed by minor Fe calcite, pore-filling kaolinite and sub-poikilotopic Ca ankerite (late stage). The limestone paragenesis includes calcite cement (early stage); megaquartz, chalcedony, and Fe calcite spar (intermediate stage); and dissolution, Ca-Fe dolomite and kaolinite (late stage). The Rm value of vitrinite shows a regional average of 0.6-0.7%; Rock-Eval TmaX suggests a comparable degree of organic maturity. The Th of aqueous fluid inclusions in late stage Ca-Fe-Mg carbonates ranges from 90 to 160?? and Tmice indicates very saline water (>200000 ppm NaCl equivalent); ??18O suggests that the water is of basinal origin. Local warm spots have higher Rm, Tmax, and Th. The results constrain numerical models of regional fluid migration, which is widely viewed as an artesian flow from recharge areas in the Ouachita belt across the foreland basin onto the foreland shelf area. Such models must account for heating effects that extend at least 500 km from the orogenic front and affect both supposed aquifer beds and the overlying supposed confining layer. Warm spots indicate either more rapid or more prolonged flow locally. Th and Tmice data show the highest temperatures coincided with high salinity fluids. ?? 1995 Springer-Verlag.

Identification of spectrally similar materials using the USGS Tetracorder algorithm: The calcite-epidote-chlorite problem

USGS Publications Warehouse

Dalton, J.B.; Bove, D.J.; Mladinich, C.S.; Rockwell, B.W.

2004-01-01

A scheme to discriminate and identify materials having overlapping spectral absorption features has been developed and tested based on the U.S. Geological Survey (USGS) Tetracorder system. The scheme has been applied to remotely sensed imaging spectroscopy data acquired by the Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) instrument. This approach was used to identify the minerals calcite, epidote, and chlorite in the upper Animas River watershed, Colorado. The study was motivated by the need to characterize the distribution of calcite in the watershed and assess its acid-neutralizing potential with regard to acidic mine drainage. Identification of these three minerals is difficult because their diagnostic spectral features are all centered at 2.3 ??m, and have similar shapes and widths. Previous studies overestimated calcite abundance as a result of these spectral overlaps. The use of a reference library containing synthetic mixtures of the three minerals in varying proportions was found to simplify the task of identifying these minerals when used in conjunction with a rule-based expert system. Some inaccuracies in the mineral distribution maps remain, however, due to the influence of a fourth spectral component, sericite, which exhibits spectral absorption features at 2.2 and 2.4 ??m that overlap the 2.3-??m absorption features of the other three minerals. Whereas the endmember minerals calcite, epidote, chlorite, and sericite can be identified by the method presented here, discrepancies occur in areas where all four occur together as intimate mixtures. It is expected that future work will be able to reduce these discrepancies by including reference mixtures containing sericite. ?? 2004 Elsevier Inc. All rights reserved.

Is the Core Top Really Modern? A Story of Chemical Erosion, Bioturbation, and Lateral Sediment Redistribution from the Eastern Equatorial Pacific

NASA Astrophysics Data System (ADS)

Mekik, F.

2016-12-01

Paleoceanographic work is based on calibrating paleo-environmental proxies using well-preserved core top sediments which represent the last one thousand years or less. However, core top sediments may be in places as old as 9000 years due to various sedimentary and diagenetic processes, such as chemical erosion, bioturbation and lateral sediment redistribution. We hypothesize that in regions with high surface ocean productivity, high organic carbon to calcite ratios reaching the seabed promote calcite dissolution in sediments, even in regions above the lysocline. This process may lead to chemical erosion of core tops which in turn may result in core top aging. The eastern equatorial Pacific (EEP), a popular site for calibration of paleoceanographic proxies, is such a place. Better understanding the relationship between core top age and dissolution will help correct biases inherent in proxy calibration because dissolution of foraminifers alters shell chemistry, and wholesale dissolution of sediments leads to core top aging and loss. We present both new and literature-based core top data of radiocarbon ages from the EEP. We created regional maps of both core top radiocarbon age and calcite preservation measured with the Globorotalia menardii Fragmentation Index (MFI; over 100 core tops). Our maps show a clear pattern of deep sea sedimentary calcite dissolution mimicking the pattern of surface ocean productivity observed from satellites and sediment traps in the EEP. Core top radiocarbon ages generally parallel the dissolution patterns observed in the region. Where this relationship does not hold true, bioturbation and/or lateral sediment redistribution may play a role. Down core radiocarbon and 230Th-normalized sediment accumulation rate data from several cores in the EEP support this hypothesis. Better understanding the role of diagenesis promotes the development of more reliable paleo-environmental proxies.

U-Th-Ra variations in Himalayan river sediments (Gandak river, India): Weathering fractionation and/or grain-size sorting?

NASA Astrophysics Data System (ADS)

Bosia, Clio; Chabaux, François; Pelt, Eric; France-Lanord, Christian; Morin, Guillaume; Lavé, Jérôme; Stille, Peter

2016-11-01

Understanding the origin of U-Th-Ra variations in the Ganga river sediments is a prerequisite for correctly using U-series nuclides to constrain the sediment transport times in Himalayan rivers. For this purpose, U, Th, and Ra concentrations, along with 238U-234U-230Th-226Ra radioactive disequilibria, were analyzed in bank, bedload and suspended sediments from the Gandak river, one of the main tributaries of the Ganga river. The data confirm that U and Th budgets of the Himalayan sediments are significantly influenced by minor resistant minerals, such as zircon, garnet and Ti-bearing minerals, the dissolution of which required the use of a high-pressure acid digestion process. Most importantly, the results indicate that the variations in (238U/232Th) and (230Th/232Th) activity ratios and 238U-234U-230Th-226Ra disequilibria in sediments along the river alluvial plain mainly reflect modifications in the mineralogical and grain-size compositions rather than the degree of weathering during transport. The (238U/232Th) and (230Th/232Th) activity ratios in the bank and bed sediments are related to variations in the minor primary minerals strongly enriched in U and Th (i.e., zircon, REE-bearing minerals and Ti-bearing minerals), whereas the activity ratios in the suspended load are related to variations in the proportions of clay, Fe-oxyhydroxides and the silt-sand fraction, which contains U- and Th-bearing minor minerals. The data also indicate that 238U-234U-230Th-226Ra disequilibria are strongly influenced by secondary mineral phases: the 230Th budget is likely mainly controlled by Fe-oxyhydroxides, and the 226Ra budget is likely mainly controlled by clay minerals. Therefore, the variations in the 238U-234U-230Th-232Th system in the sediments of the Gandak river cannot simply be interpreted as the result of fractionation due to chemical transformation of the bulk sediment during its transport within the alluvial plain and/or the result of radioactive decay. Consequently, they cannot be used to infer long sediment transport times within the Gandak plain (10-100 ka), as previously proposed. Such analytical and interpretative artifacts are certainly not specific to the present study on the Gandak basin. These issues will certainly be encountered anytime this technique is applied to alluvial systems in which the U and Th budgets of the sediments are influenced by ;heavy; minerals that can be sorted during the transport of sediments within the plain.

First identification of baddeleyite related/linked to contact metamorphism from carbonatites in the world's largest REE deposit, Bayan Obo in North China Craton

NASA Astrophysics Data System (ADS)

Zhang, Shuan-Hong; Zhao, Yue; Li, Qiu-Li; Hu, Zhao-Chu; Chen, Zhen-Yu

2017-07-01

Baddeleyite has been recognized as a key mineral to determine the crystallization age of silica-undersaturated igneous rocks. Here we report a new occurrence of baddeleyite identified from REE-Nb-Th-rich carbonatite in the world's largest REE deposit, Bayan Obo, in the North China Craton (China). U-Th-Pb dating of three baddeleyite samples yields crystallization ages of 310-270 Ma with the best estimated crystallization age of ca. 280 Ma. These ages are significantly younger than the ca. 1300 Ma Bayan Obo carbonatites, but broadly coeval to nearby Permian granitoids intruding into the carbonatites. Hence, the Bayan Obo baddeleyite did not crystallize from the carbonatitic magma that led to the formation of the Bayan Obo carbonatites and related REE-Nb-Th deposit. Instead, it crystallized from hydrothermal fluids and/or a reaction involving zircon and dolomite during contact metamorphism related to the Permian granitoid emplacement. This is in agreement with the results of electron microprobe analysis that show humite inclusions in baddeleyite, since humite is a typical magnesian skarn mineral and occurs in close proximity to the intrusive contacts between carbonatites and granitoids. Our results show that baddeleyite can be used for dating hydrothermal and contact metamorphic processes.

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Méndez-García, C.; Renteria-Villalobos, M.; García-Tenorio, R.; Montero-Cabrera, M. E.

2014-07-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232Th-series, 238U-series, 40K and 137Cs activity concentrations (AC, Bq kg-1) were determined by gamma spectrometry with a high purity Ge detector. 238U and 234U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210Pb activities. Results were verified by 137Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento - Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234U/overflow="scroll">238U and 238U/overflow="scroll">226Ra in sediments have values between 0.9-1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232Th/overflow="scroll">238U, 228Ra/overflow="scroll">226Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

Geochemistry of the Birch Creek Drainage Basin, Idaho

USGS Publications Warehouse

Swanson, Shawn A.; Rosentreter, Jeffrey J.; Bartholomay, Roy C.; Knobel, LeRoy L.

2003-01-01

The U.S. Survey and Idaho State University, in cooperation with the U.S. Department of Energy, are conducting studies to describe the chemical character of ground water that moves as underflow from drainage basins into the eastern Snake River Plain aquifer (ESRPA) system at and near the Idaho National Engineering and Environmental Laboratory (INEEL) and the effects of these recharge waters on the geochemistry of the ESRPA system. Each of these recharge waters has a hydrochemical character related to geochemical processes, especially water-rock interactions, that occur during migration to the ESRPA. Results of these studies will benefit ongoing and planned geochemical modeling of the ESRPA at the INEEL by providing model input on the hydrochemical character of water from each drainage basin. During 2000, water samples were collected from five wells and one surface-water site in the Birch Creek drainage basin and analyzed for selected inorganic constituents, nutrients, dissolved organic carbon, tritium, measurements of gross alpha and beta radioactivity, and stable isotopes. Four duplicate samples also were collected for quality assurance. Results, which include analyses of samples previously collected from four other sites, in the basin, show that most water from the Birch Creek drainage basin has a calcium-magnesium bicarbonate character. The Birch Creek Valley can be divided roughly into three hydrologic areas. In the northern part, ground water is forced to the surface by a basalt barrier and the sampling sites were either surface water or shallow wells. Water chemistry in this area was characterized by simple evaporation models, simple calcite-carbon dioxide models, or complex models involving carbonate and silicate minerals. The central part of the valley is filled by sedimentary material and the sampling sites were wells that are deeper than those in the northern part. Water chemistry in this area was characterized by simple calcite-dolomite-carbon dioxide models. In the southern part, ground water enters the ESRPA. In this area, the sampling sites were wells with depths and water levels much deeper than those in the northern and central parts of the valley. The calcium and carbon water chemistry in this area was characterized by a simple calcite-carbon dioxide model, but complex calcite-silicate models more accurately accounted for mass transfer in these areas. Throughout the geochemical system, calcite precipitated if it was an active phase in the models. Carbon dioxide either precipitated (outgassed) or dissolved depending on the partial pressure of carbon dioxide in water from the modeled sites. Dolomite was an active phase only in models from the central part of the system. Generally the entire geochemical system could be modeled with either evaporative models, carbonate models, or carbonate-silicate models. In both of the latter types of models, a significant amount of calcite precipitated relative to the mass transfer to and from the other active phases. The amount of calcite precipitated in the more complex models was consistent with the amount of calcite precipitated in the simpler models. This consistency suggests that, although the simpler models can predict calcium and carbon concentrations in Birch Creek Valley ground and surface water, silicate-mineral-based models are required to account for the other constituents. The amount of mass transfer to and from the silicate mineral phases was generally small compared with that in the carbonate phases. It appears that the water chemistry of well USGS 126B represents the chemistry of water recharging the ESRPA by means of underflow from the Birch Creek Valley.

Apatite (U-Th)/He thermochronology dataset interpretation: New insights from physical point of view

NASA Astrophysics Data System (ADS)

Gautheron, Cécile; Mbongo-Djimbi, Duval; Gerin, Chloé; Roques, Jérôme; Bachelet, Cyril; Oliviero, Erwan; Tassan-Got, Laurent

2015-04-01

The apatite (U-Th)/He (AHe) system has rapidly become a very popular thermochronometer to constrain burial and exhumation phases in a variety of geological contexts. However, the interpretation of AHe data depends on a precise knowledge of He diffusion in apatite. Several studies suggest that radiation damage generated by U and Th decay can create traps for He atoms, increasing He retention for irradiated minerals. The radiation damage also anneals with temperature and the amount of damage in an apatite crystal is at any time a balance between production and annealing, controlled by U-Th concentration, grain chemistry and thermal history (Flowers et al., 2009; Gautheron et al., 2009; 2013). However the models are not well constrained and do not fully explain the mechanism of He retention. In order to have a deeper insight on this issue, multidisciplinary studies on apatite combining diffusion experiments by Elastic Recoil Diffusion Analysis (ERDA) with a multi-scale theoretical diffusion calculation based on Density Functional Theory (DFT) and Kinetic Monte Carlo were performed. ERDA experiments were conducted on different macro-crystals, and we probed the shape of a He profile implanted into a planar and polished surface of the crystal. The helium profile evolves with temperature and allows quantifying the He diffusivity and damage impact. Additionally, DFT calculations of a damage-free crystal of apatite with different F and Cl compositions, in similar proportion as natural ones, have been run to find the favored paths of a helium atom between interstitial sites, leading to a computation of the activation energy and the diffusion coefficient. We show that damage free apatite crystals are characterized by low retention behavior and closure temperature range from 33-36°C for pure F-apatite to higher value for Cl riche apatite (up to 12°C higher), for typical grain size and cooling rate (Mbongo-Djimbi et al., in review). Using ERDA and DFT approaches, we demonstrate that in addition to grain chemistry, He diffusivity will be strongly influenced by damage and propose a new physical model. Finally, we propose a new way of interpreting AHe datasets and practical geological examples will be given. Flowers, R., Ketcham, R.A., Shuster, D., Farley, K.A., 2009. Apatite (U-Th)/He thermochronology using a radiation damage accumulation and annealing model. Geochimica et Cosmochimica Acta 73, 2347-2365. Gautheron, C., Tassan-got, L., Barbarand, J., Pagel, M., 2009. Effect of alpha-damage annealing on apatite (U-Th)/He thermochronology. Chemical Geology 266, 166-179. Gautheron, C., Barbarand, J., Ketcham R.A., Tassan-got, L., van der Beek, P., Pagel, M., Pinna-Jamme, R., Couffignal, F., Fialin, M., 2013. Chemical influence on α-recoil damage annealing in apatite: implications for (U-Th)/He dating. Chemical Geology 351, 257-267. Mbongo-Djimbi D., Gautheron C., Roques, J., Tassan-Got, L., Gerin, C., Simoni, E.. Apatite composition effect on (U-Th)/He thermochronometer: an atomistic point of view. In review at Geochimica Cosmochimica Acta.

Correction to: selected articles from Belyaev Conference 2017: structural biology.

PubMed

Alemasov, Nikolay A; Ivanisenko, Nikita V; Ramachandran, Srinivasan; Ivanisenko, Vladimir A

2018-03-21

After publication of the article [1], it has been brought to our attention that there is a discrepancy between the publication date on the pdf and online formats. The date on the pdf is 6th February 2018 and online is 5th February 2018. The correct publication date is the one on the pdf, 6th February 2018.

Allanite age-dating: Non-matrix-matched standardization in quadrupole LA-ICP-MS

NASA Astrophysics Data System (ADS)

Burn, M.; Lanari, P.; Pettke, T.; Engi, M.

2014-12-01

Allanite Th-U-Pb age-dating has recently been found to be powerful in unraveling the timing of geological processes such as the metamorphic dynamics in subduction zones and crystallization velocity of magmas. However, inconsistencies among analytical techniques have raised doubts about the accuracy of allanite age data. Spot analysis techniques such as LA-ICP-MS are claimed to be crucially dependent on matrix-matched standards, the quality of which is variable. We present a new approach in LA-ICP-MS data reduction that allows non-matrix-matched standardization via well constrained zircon reference materials as primary standards. Our data were obtained using a GeoLas Pro 193 nm ArF excimer laser ablation system coupled to an ELAN DRC-e quadrupole ICP-MS. We use 32 μm and 24 μm spot sizes; laser operating conditions of 9 Hz repetition rate and 2.5 J/cm2 fluence have proven advantageous. Matrix dependent downhole fractionation evolution is empirically determined by analyzing 208Pb/232Th and 206Pb/238U and applied prior to standardization. The new data reduction technique was tested on three magmatic allanite reference materials (SISSb, CAPb, TARA); within error these show the same downhole fractionation evolution for all allanite types and in different analytical sessions, provided measurement conditions remain the same. Although the downhole evolution of allanite and zircon differs significantly, a link between zircon and allanite matrix is established by assuming CAPb and TARA to be fixed at the corresponding reference ages. Our weighted mean 208Pb/232Th ages are 30.06 ± 0.22 (2σ) for SISSb, 275.4 ± 1.3 (2σ) for CAPb, and 409.9 ± 1.8 (2σ) for TARA. Precision of single spot age data varies between 1.5 and 8 % (2σ), dependent on spot size and common lead concentrations. Quadrupole LA-ICP-MS allanite age-dating has thus similar uncertainties as do other spot analysis techniques. The new data reduction technique is much less dependent on quality and homogeneity of allanite standard reference materials. This method of correcting for matrix-dependent downhole fractionation evolution opens new possibilities in the field of LA-ICP-MS data acquisition, e.g. the use of a NIST standard glass to date all material types given a set of well constrained reference materials.

Rapid Removal of Atmospheric CO2 by Urban Soils.

PubMed

Washbourne, Carla-Leanne; Lopez-Capel, Elisa; Renforth, Phil; Ascough, Philippa L; Manning, David A C

2015-05-05

The measured calcium carbonate content of soils to a depth of 100 mm at a large urban development site has increased over 18 months at a rate that corresponds to the sequestration of 85 t of CO2/ha (8.5 kg of CO2 m(-2)) annually. This is a consequence of rapid weathering of calcium silicate and hydroxide minerals derived from the demolition of concrete structures, which releases Ca that combines with CO2 ultimately derived from the atmosphere, precipitating as calcite. Stable isotope data confirm an atmospheric origin for carbonate carbon, and 14C dating indicates the predominance of modern carbon in the pedogenic calcite. Trial pits show that carbonation extends to depths of ≥1 m. Work at other sites shows that the occurrence of pedogenic carbonates is widespread in artificially created urban soils containing Ca and Mg silicate minerals. Appropriate management of fewer than 12000 ha of urban land to maximize calcite precipitation has the potential to remove 1 million t of CO2 from the atmosphere annually. The maximal global potential is estimated to be approximately 700-1200 Mt of CO2 per year (representing 2.0-3.7% of total emissions from fossil fuel combustion) based on current rates of production of industry-derived Ca- and Mg-bearing materials.

Ultrasonic Monitoring of CO2 Uptake and Release from Sand Packs*

NASA Astrophysics Data System (ADS)

Toffelmier, D. A.; Dufrane, W. L.; Bonner, B. P.; Viani, B. E.; Berge, P. A.

2002-12-01

Sequestration of atmospheric CO2 occurs naturally during the formation of calcite cement in sedimentary rock. Acceleration of this process has been proposed as a means of reducing the atmospheric concentration of CO2, which is a major cause of global warming. Calcite may also be precipitated when highly alkaline waste fluid is introduced into the vadose zone from leaking storage tanks. Seismic methods have potential for monitoring these processes. We devised an experiment, guided by geochemical modeling, to determine how the formation of calcite cement in unsaturated sand affects wave propagation. We used the ultrasonic pulse transmission method to measure compressional (P) and shear (S) wave velocities at ultrasonic frequencies (100-500 kHz) through packs of Ottawa sand containing chemically active pore fluids. The samples were saturated with water containing 0.1mol/L of Ca(OH)2 and 0.1mol/L of NaCl and then drained by flowing water saturated, CO2 free N2 gas, to a residual saturation of ~5%, so that the remaining pore fluid resides mainly in pendular spaces between the sand grains. Ambient air saturated with water and containing atmospheric concentration of CO2 was then passed through the sample to effect the precipitation of calcite. Finally, pure water saturated CO2, was flushed through the sample to dissolve most of the precipitated calcite. Over a three day period, measurable changes in Vp and Vs were observed following water saturation, desaturation, calcite precipitation, and calcite dissolution treatments. Changes in the contents of the pore space require waveforms to be recorded before and after each stage of the experiment so both the short and long range effects can be seen. Wave velocities were slow, as is typical for unconsolidated materials, for the dry sand, with values of 365m/s for Vp and 163m/s for Vs. Compressional velocities increased upon desaturation (443m/s), and again following calcite precipitation (460m/s). The compressional velocity measured following the CO2 flush to dissolve the calcite decreased (451m/s). The shear velocities varied similarly to the compressional velocities except that the dry sand shear velocity was faster than the other shear velocities. These preliminary results suggest that ultrasonics could provide a tool to locate the path of certain types of waste fluid in the vadose zone. *This work was performed under the auspices of the U.S. Department of Energy by the University of California, Lawrence Livermore National Laboratory under contract number W-7405-ENG-48 and was supported specifically by the Environmental Management Science Program of the Office of Environmental Management and the Office of Energy Research.

Zircon U-Th and U-Pb Ages From Quaternary Silicic Volcanic and Plutonic Rocks, and Their Bearing on Granitoid Batholiths

NASA Astrophysics Data System (ADS)

Bacon, C. R.

2007-12-01

In the ten years since publication of M. Reid et al.'s seminal paper on zircon ages from rhyolites (EPSL 150:2-39, 1997) >20 papers have appeared on SIMS 238U-230Th and 238U-206Pb geochronology of zircon from silicic volcanic rocks, plutonic xenoliths, and young intrusions. In some cases, as well as for U-Pb studies of Tertiary granitoids, plutonic samples are interpreted in the context of related volcanism. These geochronologic data have advanced conceptual models of silicic magma genesis and pluton construction. Of fundamental importance are discoveries that zircons in volcanic rocks typically pre-date eruption by 10's to 100's of kyr and that multiple zircon populations are common; these crystals are "antecrysts" recycled from intrusive rocks or crystal mush of the system that vented. Resolving such age differences is possible with U-Th at <300 ka but is challenging with U-Pb, where SIMS precision limits resolution of differences on the order of 100 kyr for Pleistocene-Miocene zircons. Cathodoluminescence (CL) imaging of polished crystals guides beam placement but leads to sampling bias that favors high-U regions. Thus, although model-age histograms and relative probability plots identify zircon age populations, they are unlikely to accurately define relative abundances of age groups. Microbeam analysis collects data for the entire volume sampled but only SIMS depth-profiling into crystal faces can spatially resolve fine zones. ID-TIMS analysis of CL-imaged zircon fragments can improve U-Pb precision. SIMS complements geochronology with trace element fingerprints of zircon growth environments and enables Ti-in-zircon thermometry. Literature examples illustrate recent findings: (1) rhyodacite lava at Crater Lake contains zircons derived from late Pleistocene granodiorite represented by blocks ejected in the caldera-forming eruption; (2) zircons in Mount St. Helens dacites grew at sub-eruption temperatures and pre-date eruptions by up to 250 kyr; (3) Miocene plutons near Mount Rainier and the Colorado River were emplaced and crystallized in pulses over ~2-3-Myr periods, some with coeval volcanics; and (4) Cretaceous batholiths in the Sierra Nevada and North Cascades preserve evidence of assembly over as much as 10 Myr; individual samples contain zircons that crystallized during intervals of >1 Myr. Zircon ages and wide-ranging trace element concentrations suggest crystallization mainly in differentiated melt pockets in high-crystallinity magmas that may repeatedly freeze and thaw. Some high-Th/U, incompatible-element rich, spongy textured zircons grew very late, in the presence of oxidizing fluid. Not all zircons survive recycling into undersaturated magmas, in which zircon will dissolve given enough time, depending on temperature and dissolved volatiles. Recent zircon geochronologic results for volcanic and plutonic rocks lend credence to the "mush model" of rhyolite genesis and batholith consolidation. Crystal-poor rhyolites and leucogranites are melts segregated by compaction or gas-driven filter pressing from granitoid crystal mush emplaced incrementally in the middle to upper crust and powered by basaltic magma repeatedly injected into the lower reaches of the mush column. Balance between heat loss and basaltic influx determines whether the mush freezes or partially thaws at any given time, blurs internal contacts in resulting plutons, and can produce large volumes of crystal-rich ignimbrite or rapid separation and eruption of crystal-poor rhyolite. Lifetimes of the largest volcano-plutonic systems, such as the Altiplano-Puna or Southern Rocky Mountains volcanic fields, are comparable to the ~10 Myr of the Tuolumne Intrusive Suite.

Paleoenvironmental signals and paleoclimatic condition of the Early Maastrichtian oil shales from Central Eastern Desert, Egypt

NASA Astrophysics Data System (ADS)

Fathy, Douaa; Wagreich, Michael; Zaki, Rafat; Mohamed, Ramadan S. A.

2016-04-01

Early Maastrichtian oil shales are hosted in the Duwi Formation of the Central Eastern Desert, Egypt. The examined member represents up to 20% of the total Duwi Formation. This interval is mainly composed of siliciclastic facies, phosphorites facies and carbonate facies. Oil shales microfacies is mainly composed of smectite, kaolinite, calcite, fluorapatite, quartz and pyrite. They are enriched in a number of major elements and trace metals in particular Ca, P, V, Ni, Cr, Sr, Zn, Mo, Nb, U and Y compared to the post-Archaean Australian shale (PAAS). Chondrite-normalized REEs patterns of oil shales for the studied area display light rare earth elements enrichment relatively to heavy rare earth elements with negative Ce/Ce* and Eu/Eu* anomalies. The most remarkable indicators for redox conditions are enrichments of V, Mo, Ni, Cr, U content and depletion of Mn content. Besides, V/V+Ni, V/Ni, U/Th, Ni/Co, authigentic uranium ratios with presence of framboidal shape of pyrite and its size are reflecting the deposition of these shales under marine anoxic to euxinic environmental conditions. Additionally, the ratio of Strontium (Sr) to Barium (Ba) Sr/Ba reflected highly saline water during deposition. Elemental ratios critical to paleoclimate and paleoweathering (Rb /Sr, Al2O3/TiO2), CIA values, binary diagram between (Al2O3+K2O+Na2O) and SiO2 and types of clay minerals dominated reflect warm to humid climate conditions prevailing during the accumulation of these organic-rich petroleum source rocks.

Methods for processing and imaging marsh foraminifera

USGS Publications Warehouse

Dreher, Chandra A.; Flocks, James G.

2011-01-01

This study is part of a larger U.S. Geological Survey (USGS) project to characterize the physical conditions of wetlands in southwestern Louisiana. Within these wetlands, groups of benthic foraminifera-shelled amoeboid protists living near or on the sea floor-can be used as agents to measure land subsidence, relative sea-level rise, and storm impact. In the Mississippi River Delta region, intertidal-marsh foraminiferal assemblages and biofacies were established in studies that pre-date the 1970s, with a very limited number of more recent studies. This fact sheet outlines this project's improved methods, handling, and modified preparations for the use of Scanning Electron Microscope (SEM) imaging of these foraminifera. The objective is to identify marsh foraminifera to the taxonomic species level by using improved processing methods and SEM imaging for morphological characterization in order to evaluate changes in distribution and frequency relative to other environmental variables. The majority of benthic marsh foraminifera consists of agglutinated forms, which can be more delicate than porcelaneous forms. Agglutinated tests (shells) are made of particles such as sand grains or silt and clay material, whereas porcelaneous tests consist of calcite.

Statistical U-Th dating results of speleothem from south Europe and the orbital-scale implication

NASA Astrophysics Data System (ADS)

Hu, H. M.

2016-12-01

Reconstructing of hydroclimate in the Mediterranean on an orbital time scale helps improve our understanding of interaction between orbital forcing and north hemisphere climate. We collected 180 speleothem subsamples from Observatoire Cave (Monaco), Prince Cave (south France), Chateaueuf Cave (South France), Arago Cave (South France), and Basura Cave (North Italy) during 2013 to 2015 C.E. Uranium-thorium dating were conducted in the High-Precision Mass Spectrometry and Environment Change Laboratory (HISPEC), National Taiwan University. The results show that most of the speleothem formed during interglacial periods, particularly in marine isotope stage (MIS) 1, 5, and 11. However, only a few speleothem were dated between 180 to 250 thousand years ago (ka). The interval is approximately equivalent to MIS 7, which is a period with contrasting orbital parameters compared to MIS1, 5, and 11. Our statistical dating result implies that the orbital-scale humid/dry condition in southern Europe could be dominantly controlled by orbital forcing.

The r-Process in the Neutrino Winds of Core-Collapse Supernovae and U-Th Cosmochronology

NASA Astrophysics Data System (ADS)

Wanajo, Shinya; Itoh, Naoki; Ishimaru, Yuhri; Nozawa, Satoshi; Beers, Timothy C.

2002-10-01

The discovery of the second highly r-process-enhanced, extremely metal poor star, CS 31082-001 ([Fe/H]=-2.9) has provided a powerful new tool for age determination by virtue of the detection and measurement of the radioactive species uranium and thorium. Because the half-life of 238U is one-third that of 232Th, the U-Th pair can, in principle, provide a far more precise cosmochronometer than the Th-Eu pair that has been used in previous investigations. In the application of this chronometer, the age of (the progenitor of) CS 31082-001 can be regarded as the minimum age of the Galaxy, and hence of the universe. One of the serious limitations of this approach, however, is that predictions of the production ratio of U and Th have not been made in the context of a realistic astrophysical model of the r-process. We have endeavored to produce such a model, based on the ``neutrino winds'' that are expected to arise from the nascent neutron star of a core-collapse supernova. In this model, the proto-neutron star mass and the (asymptotic) neutrino sphere radius are assumed to be 2.0 Msolar and 10 km, respectively. Recent hydrodynamic studies indicate that there may exist difficulties in obtaining such a compact (massive and/or small in radius) remnant. Nevertheless, we utilize this set of parameter choices since previous work suggests that the third r-process peak (and thus U and Th) is hardly reached when one adopts a less compact proto-neutron star in the framework of the neutrino-wind scenario. The temperature and density histories of the material involved in the neutron-capture processes are obtained with the assumption of a steady flow of the neutrino-powered winds, with general relativistic effects taken into account. The electron fraction is taken to be a free parameter, constant with time. The r-process nucleosynthesis in these trajectories is calculated with a nuclear reaction network code including actinides up to Z=100. The mass-integrated r-process yields, obtained by assuming a simple time evolution of the neutrino luminosity, are compared to the available spectroscopic elemental abundance data of CS 31082-001. As a result, the ``age'' of this star is determined to be 14.1+/-2.5 Gyr, in excellent agreement with lower limits on the age of the universe estimated by other dating techniques, as well as with other stellar radioactive age estimates. Future measurements of Pt and Pb in this star, as well as expansion of searches for additional r-process-enhanced, metal-poor stars (especially those in which both U and Th are measurable), are of special importance to constrain the current astrophysical models for the r-process.

Ion Implantation Studies of Titanium Metal Surfaces.

DTIC Science & Technology

1981-01-01

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Ion microprobe mass analysis of lunar samples. Lunar sample program

NASA Technical Reports Server (NTRS)

Anderson, C. A.; Hinthorne, J. R.

1971-01-01

Mass analyses of selected minerals, glasses and soil particles of lunar, meteoritic and terrestrial rocks have been made with the ion microprobe mass analyzer. Major, minor and trace element concentrations have been determined in situ in major and accessory mineral phases in polished rock thin sections. The Pb isotope ratios have been measured in U and Th bearing accessory minerals to yield radiometric age dates and heavy volatile elements have been sought on the surfaces of free particles from Apollo soil samples.

Navy Ship Names: Background for Congress

DTIC Science & Technology

2011-04-01

1973. It is the only Naval vessel to date to have received a Papal blessing by Pope John Paul II in Naples, Italy, on September 4, 1981. (9) The...Congressman John F. ‘‘Honey Fitz ’’ Fitzgerald introduced legislation to return ‘‘Old Ironsides’’ from the Portsmouth Naval Shipyard in New Hampshire, where...Secretary of the Navy announced that SSN-785, the 12th ship in the class, would be named for former Senator John Warner. Destroyers are named for U.S

U enrichment and Th/U fractionation in Archean boninites: Implications for paleo-ocean oxygenation and U cycling at juvenile subduction zones

NASA Astrophysics Data System (ADS)

Manikyamba, C.; Said, Nuru; Santosh, M.; Saha, Abhishek; Ganguly, Sohini; Subramanyam, K. S. V.

2018-05-01

Phanerozoic boninites record enrichments of U over Th, giving Th/U: 0.5-1.6, relative to intraoceanic island arc tholeiites (IAT) where Th/U averages 2.6. Uranium enrichment is attributed to incorporation of shallow, oxidized fluids, U-rich but Th-poor, from the slab into the melt column of boninites which form in near-trench to forearc settings of suprasubduction zone ophiolites. Well preserved Archean komatiite-tholeiite, plume-derived, oceanic volcanic sequences have primary magmatic Th/U ratios of 4.4-3.6, and Archean convergent margin IAT volcanic sequences, having REE and HFSE compositions similar to Phanerozoic IAT equivalents, preserve primary Th/U of 4-3.6. The best preserved Archean boninites of the 3.0 Ga Olondo and 2.7 Ga Gadwal greenstone belts, hosted in convergent margin ophiolite sequences, also show relative enrichments of U over Th, with low average Th/U ∼3 relative to coeval IAT, and Phanerozoic counterparts which are devoid of crustal contamination and therefore erupted in an intraoceanic setting, with minimal contemporaneous submarine hydrothermal alteration. Later enrichment of U is unlikely as Th-U-Nb-LREE patterns are coherent in these boninites whereas secondary effects induce dispersion of Th/U ratios. The variation in Th/U ratios from Archean to Phanerozoic boninites of greenstone belts to ophiolitic sequences reflect on genesis of boninitic lavas at different tectono-thermal regimes. Consequently, if the explanation for U enrichment in Phanerozoic boninites also applies to Archean examples, the implication is that U was soluble in oxygenated Archean marine water up to 600 Ma before the proposed great oxygenation event (GOE) at ∼2.4 Ga. This interpretation is consistent with large Ce anomalies in some hydrothermally altered Archean volcanic sequences aged 3.0-2.7 Ga.

TL, OSL and C-14 dating results of the sediments and bricks from mummified nuns' grave.

PubMed

Tudela, Diego R G; Tatumi, Sonia H; Yee, Márcio; Brito, Silvio L M; Morais, José L; Morais, Daisy de; Piedade, Silvia C; Munita, Casimiro S P; Hazenfratz, Roberto

2012-06-01

This paper presents the results of TL and OSL dating of soil and fragments of bricks from a grave, which was occupied by two mummified nuns, found at "Luz" Monastery, located in the state of São Paulo, Brazil. The TL and OSL ages were compared to C-14 dating ones obtained from bone collagens of the mummies. The majority of the ages is related to the eighteenth century. The gamma-ray spectroscopy was used to evaluate natural radioisotope concentrations in the samples, and by using these concentrations the annual dose rates, from 3.0 to 5.3 Gy/kyr, were obtained. Neutron activation analysis was performed and the radioisotope contents results are in agreement with those obtained by gamma-ray spectroscopy. The contents of U, Th and Ce elements were higher than those found in usual sediments.

Sulphate incorporation in monazite lattice and dating the cycle of sulphur in metamorphic belts

NASA Astrophysics Data System (ADS)

Laurent, Antonin T.; Seydoux-Guillaume, Anne-Magali; Duchene, Stéphanie; Bingen, Bernard; Bosse, Valérie; Datas, Lucien

2016-11-01

Microgeochemical data and transmission electron microscope (TEM) imaging of S-rich monazite crystals demonstrate that S has been incorporated in the lattice of monazite as a clino-anhydrite component via the following exchange Ca2+ + S6+ = REE3+ + P5+, and that it is now partly exsolved in nanoclusters (5-10 nm) of CaSO4. The sample, an osumilite-bearing ultra-high-temperature granulite from Rogaland, Norway, is characterized by complexly patchy zoned monazite crystals. Three chemical domains are distinguished as (1) a sulphate-rich core (0.45-0.72 wt% SO2, Th incorporated as cheralite component), (2) secondary sulphate-bearing domains (SO2 >0.05 wt%, partly clouded with solid inclusions), and (3) late S-free, Y-rich domains (0.8-2.5 wt% Y2O3, Th accommodated as the huttonite component). These three domains yield distinct isotopic U-Pb ages of 1034 ± 6, 1005 ± 7, and 935 ± 7 Ma, respectively. Uranium-Th-Pb EPMA dating independently confirms these ages. This study illustrates that it is possible to discriminate different generations of monazite based on their S contents. From the petrological context, we propose that sulphate-rich monazite reflects high-temperature Fe-sulphide breakdown under oxidizing conditions, coeval with biotite dehydration melting. Monazite may therefore reveal the presence of S in anatectic melts from high-grade terrains at a specific point in time and date S mobilization from a reduced to an oxidized state. This property can be used to investigate the mineralization potential of a given geological event within a larger orogenic framework.

238U-234U-230Th disequilibrium in hydrogenous oceanic Fe-Mn crusts: Palaeoceanographic record or diagenetic alteration?

USGS Publications Warehouse

Chabaux, F.; O'Nions, R. K.; Cohen, A.S.; Hein, J.R.

1997-01-01

A detailed TIMS study of (234Uexc/238U), (230Th/232Th), and Th/U ratios have been performed on the outermost margin of ten hydrogenous Fe-Mn crusts from the equatorial Pacific Ocean and west-central Indian Ocean. Th/U concentration ratios generally decrease from the crust's surface down to 0.5-1 mm depth and growth rates estimated by uranium and thorium isotope ratios are significantly different in Fe-Mn crusts from the Peru Basin and the west-central Indian Ocean. Fe-Mn crusts from the same geographical area define a single trend in plots of Ln (234Uexc/238U) vs. Ln(230Th/232Th) and Th/U ratios vs. age of the analysed fractions. Results suggest that (1) hydrogenous Fe-Mn crusts remain closed-systems after formation, and consequently (2) the discrepancy observed between the 230Th and 234U chronometers in Fe-Mn crusts, and the variations of the Th/U ratios through the margin of Fe-Mn crusts, are not due to redistribution of uranium and thorium isotopes after oxyhydroxide precipitation, but rather to temporal variations of both Th/U and initial thorium activity ratios recorded by the Fe-Mn layers. Implications of these observations for determination of Fe-Mn crust growth-rates are discussed. Variations of both Th/U and initial Th activity ratios in Fe-Mn crusts might be related to changes in particle input to seawater and/or changes in ocean circulation during the last 150 ka. Copyright ?? 1997 Elsevier Science Ltd.

Cross-sectional and temporal associations between cyber dating abuse victimization and mental health and substance use outcomes.

PubMed

Lu, Yu; Van Ouytsel, Joris; Walrave, Michel; Ponnet, Koen; Temple, Jeff R

2018-06-01

The purpose of this study was to investigate the cross-sectional and temporal associations between cyber dating abuse victimization (CDAV) and mental health (i.e., anxiety, PTSD, and depression), and substance use (i.e., alcohol, cigarettes, marijuana and hard drugs). We used data from the 5th and 6th waves of an ongoing longitudinal study of ethnically diverse adolescents from seven public high schools in Texas, U.S. Participants were 641 adolescents (63.3% female) with a mean age of 19.1 years (SD = .79) at Wave 5. Analyses suggested that while CDAV was associated with mental health and substance use cross-sectionally, when examining over time, it was only associated with past year hard drug and past month marijuana use. Although long-term mental health effects of CDAV did not emerge in the current study, we identified a temporal link to marijuana and hard drugs, highlighting the need for prevention efforts to incorporate messages about substance use. Copyright © 2018 The Foundation for Professionals in Services for Adolescents. Published by Elsevier Ltd. All rights reserved.

Flowstone compositions as indicators of centennial fluctuations of hydrological balance in Central Europe during the late Holocene

NASA Astrophysics Data System (ADS)

Demény, Attila; Kern, Zoltán; Molnár, Mihály; Czuppon, György; Leél-Őssy, Szabolcs; Surányi, Gergely; Gilli, Adrian

2017-04-01

Flowstones formed from springs in the Baradla and Béke Caves, North-east Hungary were drilled at several locations, and their sites were monitored for temperature, CO2 level in cave air, water and carbonate compositions for three years. The monitoring results suggest that the carbonate precipitated close to equilibrium with the local water. The non-systematic distribution of stable isotope and chemical compositions along sections on the surfaces of flowstone occurrences indicate irregular formation and the possibility of hiatuses within the flowstones' edifices. Approximately 40 cm long drill cores were extracted from the „Nagy-tufa" flowstone of the Béke Cave (BNT-2 core) and the Havasok flowstone of the Baradla Cave. U-Th dating efforts resulted in very large age uncertainties for the BNT-2 core, owing to detrital Th contamination. Therefore, in addition to the U-Th dating, AMS radiocarbon analyses were conducted to establish reliable age-depth models. The raw 14C ages were corrected for the dead carbon fraction (dfc) using radiocarbon results obtained for samples that yielded also accurate U-Th ages. Calibration and age-depth modeling have been performed using the OxCal v4.2.4. software. The data prove that the flowstones in the studied caves were formed contemporarily, covering the last 4 ka with two major hiatuses around 3.5 and 1 ka BP. Inclusion-hosted water contents, stable carbon and oxygen isotope compositions of carbonate, and hydrogen isotope composition of inclusion-hosted water as well as Si contents were determined for the two cores and compared with regional paleoclimate records for the period of 3.5 to 1 ka BP. The water contents, δ13Ccarb values and Si contents show correspondence with paleoprecipitation proxies from Central Europe to western Anatolia, while the paleotemperature estimates obtained using the δDwater values were in agreement with temperature reconstructions derived from paleobiological proxies from nearby lake sediments. The inferred paleohumidity variations agree also with water level changes of Lake Balaton (Western Hungary) assumed on the base of settlement migrations revealed by archeological excavations. These correlations indicate that the flowstone data provide valuable information about the regional water balance fluctuations for the late Holocene. The study was financed by the Hungarian Research Fund (OTKA NK 101664).

The thermal evolution of Chinese central Tianshan and its implications: Insights from multi-method chronometry

NASA Astrophysics Data System (ADS)

Yin, Jiyuan; Chen, Wen; Hodges, Kip V.; Xiao, Wenjiao; Cai, Keda; Yuan, Chao; Sun, Min; Liu, Li-Ping; van Soest, Matthijs C.

2018-01-01

The Chinese Tianshan is located in the south of the Central Asian Orogenic Belt and formed during final consumption of the Paleo-Asian Ocean in the late Palaeozoic. In order to further elucidate the tectonic evolution of the Chinese Tianshan, we have established the temperature-time history of granitic rocks from the Chinese Tianshan through a multi-chronological approach that includes U/Pb (zircon), 40Ar/39Ar (biotite and K-feldspar), and (U-Th)/He (zircon and apatite) dating. Our data show that the central Tianshan experienced accelerated cooling during the late Carboniferous- to early Permian. Multiple sequences of complex multiple accretionary, subduction and collisional events could have induced the cooling in the Tianshan Orogenic Belt. The new 40Ar/39Ar and (U-Th)/He data, in combination with thermal history modeling results, reveal that several tectonic reactivation and exhumation episodes affected the Chinese central Tianshan during middle Triassic (245-210 Ma), early Cretaceous (140-100 Ma), late Oligocene-early Miocene (35-20 Ma) and late Miocene (12-9 Ma). The middle Triassic cooling dates was only found in the central Tianshan. Strong uplift and deformation in the Chinese Tianshan has been limited and localized. It have been concentrated in around major fault zone and the foreland thrust belt since the early Cretaceous. The middle Triassic and early Cretaceous exhumation is interpreted as distal effects of the Cimmerian collisions (i.e. the Qiangtang and Kunlun-Qaidam collision and Lhasa-Qiangtang collision) at the southern Eurasian margin. The Cenozoic reactivation and exhumation is interpreted as a far field response to the India-Eurasia collision and represents the beginning of modern mountain building and denudation in the Chinese Tianshan.

The double-edged sword of high-precision U-Pb geochronology or be careful what you wish for. (Invited)

NASA Astrophysics Data System (ADS)

Bowring, S. A.

2010-12-01

Over the past two decades, U-Pb geochronology by ID-TIMS has been refined to achieve internal (analytical) uncertainties on a single grain analysis of ± ~ 0.1-0.2%, and 0.05% or better on weighted mean dates. This level of precision enables unprecedented evaluation of the rates and durations of geological processes, from magma chamber evolution to mass extinctions and recoveries. The increased precision, however, exposes complexity in magmatic/volcanic systems and highlights the importance of corrections related to disequilibrium partitioning of intermediate daughter products, and raises questions as to how best to interpret the complex spectrum of dates characteristic of many volcanic rocks. In addition, the increased precision requires renewed emphasis on the accuracy of U decay constants, the isotopic composition of U, the calibration of isotopic tracers, and the accurate propagation of uncertainties It is now commonplace in the high precision dating of volcanic ash-beds to analyze 5-20 single grains of zircon in an attempt to resolve the eruption/depositional age. Data sets with dispersion far in excess of analytical uncertainties are interpreted to reflect Pb-loss, inheritance, and protracted crystallization, often supported with zircon chemistry. In most cases, a weighted mean of the youngest reproducible dates is interpreted as the time of eruption/deposition. Crystallization histories of silicic magmatic systems recovered from plutonic rocks may also be protracted, though may not be directly applicable to silicic eruptions; each sample must be evaluated independently. A key to robust interpretations is the integration high-spatial resolution zircon trace element geochemistry with high-precision ID-TIMS analyses. The EARTHTIME initiative has focused on many of these issues, and the larger subject of constructing a timeline for earth history using both U-Pb and Ar-Ar chronometers. Despite continuing improvements in both, comparing dates for the same rock with both chronometers is not straightforward. Compelling issues range from pre-eruptive magma chamber residence, recognizing open system behavior, accurately correcting for disequilibrium amounts of 230Th and 231Pa, precise and accurate dates of fluence monitors for 40Ar/39Ar, and inter-laboratory biases. At present, despite the level of internal precision achievable by each technique, obstacles remain to combining both chronometers.

Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt, NW China: Constraints on the initiation of a magmatic arc in the southern Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Du, Long; Long, Xiaoping; Yuan, Chao; Zhang, Yunying; Huang, Zongying; Sun, Min; Zhao, Guochun; Xiao, Wenjiao

2018-03-01

Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt (ETOB) have been studied in order to constraint the initiation of a magmatic arc formed in this region. Zircon U-Pb dating indicates that two dioritic plutons in the northern ETOB were generated in the Late Ordovician (452 ± 4 Ma) and the Early Silurian (442 ± 3 Ma), respectively. Diorites from the two plutons are characterized by enrichments in large ion lithophile elements (LILE) and highly incompatible elements, with depletions in high field strength elements (HSFE) displaying typical geochemical features of a subduction-related origin. They have positive εNd(t) values (+5.08-+6.58), relatively young Nd model ages (TDM = 0.71-1.08 Ga), with Ta/Yb (0.05-0.09) and Nb/Ta ratios (12.06-15.19) similar to those of depleted mantle, suggesting a juvenile mantle origin. Their high Ba/La (13.3-35.9), low Th/Yb (0.72-2.02), and relatively low Ce/Th (4.57-14.7) and Ba/Th (47.8-235) ratios indicate that these diorites were probably produced by partial melting of a depleted mantle wedge metasomatized by both subducted sediment-derived melts and slab-derived aqueous fluids. Zircon U-Pb dating of a granitic pluton in the northern ETOB yielded a Late Ordovician intrusion age of 447 ± 5 Ma. Granites from this pluton show calc-alkaline compositions with geochemical characteristics of I-type granites. They also show positive εNd(t) values (+6.49-+6.95) and young Nd model ages (TDM = 0.69-0.87 Ga), indicating that the granites were most likely derived from juvenile lower crust. Our new dating results on the dioritic and granitic plutons suggest that arc-type magmatism in the northern ETOB began prior to or at the Late Ordovician (452-442 Ma). In addition, north-dipping subduction of the Kangguertage oceanic lithosphere may account for the arc-type magmatism and the geodynamic process of the ETOB in the Early Paleozoic.

Ba, B, and U element partitioning in magnesian calcite skeletons of Octocorallia corals

NASA Astrophysics Data System (ADS)

Yoshimura, T.; Suzuki, A.; Iwasaki, N.

2015-01-01

Barium, boron and uranium element partitioning and oxygen and carbon isotope fractionation of high-Mg calcite skeletons of Octocorallia corals were investigated. The dissolved Ba concentration in seawater and the coral Ba/Ca ratio showed a clear positive correlation. The empirically derived barium partition coefficient is comparable to previous data for not only calcitic corals but also intermediate- to deep-water-dwelling scleractinian corals whose skeletons are composed of aragonite. Octocorallia corals are geologically important producers of biominerals, and they provide long-term records (up to hundreds of years) of environmental conditions in the deep ocean. Our data suggest that Ba/Ca ratios in Octocorallia corals may be a useful proxy for nutrients in intermediate and deep waters. The Ba/Ca ratio, a possible proxy for pH or carbonate ion concentration in seawater, showed the largest correlation with δ13C among the examined parameters. This result implies that the pH of the extracytoplasmic calcifying fluid (ECF) simultaneously influences δ18O, δ13C, and Ba/Ca by influencing the relative contributions of dissolved carbon sources in the ECF. Positive correlations of Ba/Ca with δ18 and δ13C suggest that δ18 and δ13C are enriched in light isotopes when conditions are less alkaline, suggesting a potential role of biological alkalinity pumping becomes more favorable with decreasing calcifying fluid pH. Substantial inter- and intra-specimen variations in Ba/Ca suggest that physicochemical factors do not exert a dominant systematic control on U incorporation.

Trace Metals in Groundwater and Vadose Zone Calcite: In Situ Containment and Stabilization of Stronthium-90 and Other Divalent Metals and Radionuclides at Arid Western DOE Sites: Final Report for Award Number DE-FG07-02ER63486 to the University of Idaho (RW Smith) Environmental Management Science Program Project Number 87016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Robert W.; Fujita, Yoshiko

2007-11-07

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) energy research and weapons complex. In situ containment and stabilization of these contaminants represents a cost-effective treatment strategy that minimizes workers’ exposure to hazardous substances, does not require removal or transport of contaminants, and generally does not generate a secondary waste stream. We have investigated an in situ bioremediation approach that immobilizes radionuclides or contaminant metals (e.g., strontium-90) by their microbially facilitated co-precipitation with calcium carbonate in groundwater and vadose zone systems. Calcite, a common mineral in many aquifers and vadosemore » zones in the arid west, can incorporate divalent metals such as strontium, cadmium, lead, and cobalt into its crystal structure by the formation of a solid solution. Collaborative research undertaken by the Idaho National Laboratory (INL), University of Idaho, and University of Toronto as part of this Environmental Management Science Program project has focused on in situ microbially-catalyzed urea hydrolysis, which results in an increase in pH, carbonate alkalinity, ammonium, calcite precipitation, and co-precipitation of divalent cations. In calcite-saturated aquifers, microbially facilitated co-precipitation with calcium carbonate represents a potential long-term contaminant sequestration mechanism. Key results of the project include: **Demonstrating the linkage between urea hydrolysis and calcite precipitation in field and laboratory experiments **Observing strontium incorporation into calcite precipitate by urea hydrolyzers with higher distribution coefficient than in abiotic **Developing and applying molecular methods for characterizing microbial urease activity in groundwater including a quantitative PCR method for enumerating ureolytic bacteria **Applying the suite of developed molecular methods to assess the feasibility of the proposed bioremediation technique at a contaminated site located within the 100-N area of the Hanford, Washington site **Assessing the role of nitrification on the persistence of precipitated calcite by modifying primers for identification of the amoA gene region of various ammonia oxidizing bacteria (AOB) for characterizing AOB in the field« less

Sequence stratigraphic controls on synsedimentary cementation and preservation of dinosaur tracks: Example from the lower Cretaceous, (Upper Albian) Dakota Formation, Southeastern Nebraska, U.S.A.

USGS Publications Warehouse

Phillips, P.L.; Ludvigson, Greg A.; Matthew, Joeckel R.; Gonzalez, Luis A.; Brenner, Richard L.; Witzke, B.J.

2007-01-01

A thin cemented sandstone bed in the Upper Albian Dakota Formation of southeastern Nebraska contains the first dinosaur tracks to be described from the state. Of equal importance to the tracks are stable-isotope (C, O) analyses of cements in the track bed, especially in the context of data derived from generally correlative strata (sandstones and sphaerosiderite-bearing paleosols) in the region. These data provide the framework for interpretations of paleoenvironmental conditions, as well as a novel approach to understanding mechanisms of terrestrial vertebrate track preservation. High minus-cement-porosity (> 47%) and low grain-to-grain contacts (???2.5) in the track bed indicate early (pre-compaction) lithification. Although phreatic cements dominate, the history of cementation within this stratigraphic interval is complex. Cathodoluminescence petrography reveals two distinct calcite zones in the track-bearing horizon and four cement zones in stratigraphically equivalent strata from a nearby section. The earliest calcite cements from both localities are likely coeval because they exhibit identical positive covariant trends (??18O values of - 9.89 to - 6.32??? and ??13C values of - 28.01 to - 19.33??? VPDB) and record mixing of brackish and meteoric groundwaters. All other calcite cements define meteoric calcite lines with ??18O values clustering around - 9.42??? and - 8.21??? VPDB from the track-bearing horizon, and - 7.74???, - 5.81???, and - 3.95??? VPDB from the neighboring section. Distinct meteoric sphaerosiderite lines from roughly correlative paleosols serve as a proxy for locally recharged groundwaters. Back-calculated paleogroundwater ??18O estimates from paleosol sphaerosiderites range from - 7.4 to - 4.2??? SMOW; whereas, meteoric calcite lines from the track horizon are generally more depleted. Differences in cement ??18O values record changes in paleogroundwater recharge areas over time. Early calcite cements indicate mixing of fresh and brackish groundwaters during the syndepositional lithification of the track horizon. Later calcite cements, however, indicate recharge from a larger catchment basin that extended far inland. Therefore, the cements likely record a rise and subsequent fall in relative sea level. We conclude that scrutiny of the cement isotope geochemistry of genetically significant surfaces, especially track beds, can provide new data for interpreting sea level change. ?? 2006 Elsevier B.V. All rights reserved.

Constraints on the timing of multiple thermal events and re-equilibration recorded by high-U zircon and xenotime: Case study of pegmatite from Piława Górna (Góry Sowie Block, SW Poland)

NASA Astrophysics Data System (ADS)

Budzyń, Bartosz; Sláma, Jiří; Kozub-Budzyń, Gabriela A.; Konečný, Patrik; Holický, Ivan; Rzepa, Grzegorz; Jastrzębski, Mirosław

2018-06-01

The application of zircon and xenotime geochronometers requires knowledge of their potential and limitations related to possible disturbance of the age record. The alteration of the intergrown zircon and xenotime in pegmatite from the Góry Sowie Block (SW Poland) was studied using the electron microprobe analysis, X-ray WDS compositional mapping, micro-Raman analysis, and LA-ICP-MS U-Pb dating of zircon and xenotime, as well as the U-Th-total Pb dating of uraninite. These microanalytical techniques were applied to understand the formation mechanisms of the secondary textures related to post-magmatic processes in the zircon and xenotime intergrowth, and to constrain their timing. Textural and compositional features combined with U-Pb data indicate that the pegmatite-related crystallization of the zircon and xenotime intergrowth occurred ca. 2.09 Ga (2086 ± 35 Ma for zircon and 2093 ± 52 Ma for xenotime), followed by the re-equilibration of zircon and xenotime ca. 370 Ma (373 ± 18 Ma and 368 ± 6 Ma, respectively) during the formation of the younger pegmatite. The zircon and xenotime were most likely derived from Precambrian basement rocks and emplaced in the pegmatite as a restite. The zircon preserved textures related to diffusion-reaction processes that affected its high-U core (up to ca. 9.6 wt% UO2), which underwent further metamictization and amorphization due to self-radiation damage. The zircon rim and xenotime were affected by coupled dissolution-reprecipitation processes that resulted in patchy zoning, age disturbance and sponge-like textures. Xenotime was also partially replaced by fluorapatite or hingganite-(Y) and Y-enriched allanite-(Ce). The termination of the low-temperature alteration was constrained by the U-Th-total Pb age of the uraninite inclusions that crystallized in zircon at 281 ± 2 Ma, which is consistent with the age of 278 ± 15 Ma obtained from the youngest cluster of U-Pb ages in the re-equilibrated high-U zircon domains. This study demonstrates the importance of the careful examination of compositional, microtextural and geochronological data obtained using microanalytical techniques to reconstruct the complex thermal histories recorded by accessory minerals.

Age of metamorphic events : petrochronology and hygrochronology

NASA Astrophysics Data System (ADS)

Bosse, Valerie; Villa, Igor M.

2017-04-01

Geodynamic models of the lithosphere require quantitative data from natural samples. Time is a key parameter: it allows to calculate rates and duration of geological processes and provides informations about the involved physical processes (Vance et al. 2003). Large-scale orogenic models require linking geochronological data with other parameters: structures, kinematics, magmatic and metamorphic petrology (P-T-A-X conditions), thermobarometric evolution of the lithosphere, chemical dynamics (Muller, 2003). This requires geochronometers that are both powerful chemical and petrological tracers. In-situ techniques allow dating a mineral in its petrological-microstructural environment. Getting a "date" has become quite easy... But what do we date in the end ? What is the link between the numbers obtained from the mass spectrometer and the age of the metamorphic event we are trying to date ? How can we transform the date into a geological meaningful age ? What do we learn about the behavior of the geochronometer minerals? Now that we can perform precise dating on very small samples directly in the studied rock, it is important to improve the way we interpret the ages to give them more pertinence in the geodynamic context. We propose to discuss the Th/U/Pb system isotopic closure in various metamorphic contexts using our published examples of in situ dating on monazite and zircon (Bosse et al. 2009; Didier et al. 2014, 2015). The studied examples show that (i) fluid assisted dissolution-precipitation processes rather than temperature-dependent solid diffusion predominantly govern the closure of the Th/U/Pb system (ii) monazite and zircon are sensitive to the interaction with fluids of specific composition (F, CO2, K ...), even at low temperature (iii) in the absence of fluids, monazite is able to record HT events and to retain this information in poly-orogenic contexts or during partial melting events (iv) complex chemical and isotopic zonations, well known in monazite, reflect the interaction with the surrounding mineral assemblages. An often neglected observation is that the K-Ar chronometer minerals show similar patterns of isotopic inheritance closely tied to relict patches and heterochemical retrogression phases (Villa and Williams 2013). Isotopic closure in the U-Pb and K-Ar systems follows the same principle: thermal diffusion is very slow, dissolution and reprecipitation are several orders of magnitude faster. This means that both U-Pb and K-Ar mineral chronometers are hygrochronometers. The interpretation of the ages of the different domains cannot be decoupled from the geochemical and petrological context. The focus on petrology also requires, following Villa (1998, 2016), that the ages measured in metamorphic rocks no longer can be used in geodynamic models according to the "closure temperature" concept as originally defined by Dodson (1973). Bosse et al. (2009) Chem Geol 261: 286 Didier et al. (2014) Chem Geol 381: 206 Didier et al. (2015) Contrib Mineral Petrol 170: 45 Dodson (1973) Contrib Mineral Petrol 40: 259 Muller (2003) EPSL, 206: 237 Villa (1998) Terra Nova 10: 42 Villa (2016) Chem Geol 420: 1 Villa & Williams (2013) In: Harlov & Austrheim (eds.), Metasomatism and the Chemical Transformation of Rock. Springer, p171

Minor elements incorporation control by ionic radius and growth rate on a stalagmite from the Chauvet Cave (SE-France)

NASA Astrophysics Data System (ADS)

Bourdin, C.; Douville, E.; Genty, D.

2009-12-01

A multi-elemental study focusing on earth-alkalis (Mg, Ca, Sr and Ba), uranium and rare-earth elements (REE) in the calcite of a stalagmite from the Chauvet Cave (SE of France) has been achieved by ICP-MS. The Chau-stm6 stalagmite which grew from 33 to 11.5 ky had already been dated and the published d13C and d18O profile is used as a paleoclimatic benchmark. Ba and Sr profiles show an abrupt concentration increase at the beginning of the last deglaciation whereas U and Mg feature a decreasing trend. REY (REE+yttrium) concentrations decrease markedly during early deglaciation (between 15 and 14.5 ky). The transition corresponds to a change from a slow to a fast growth rate. These variations can be explained by the crystallographic control of ionic radii of the minor elements: incorporation of small ions compared to Ca such as U, Mg, heavy REE are favoured during slow growth period (i.e. glacial) whereas large ions such as Ba, Sr and light REE are preferentially precipitated during fast growth period (i.e. Bolling-Allerod). This crystallographic effect seems to be dominant here because the soil above the cave is sparse. And may not have played a major role on the opposite to the water-limestone interaction.

Geological and geochronological evidence for the effect of Paleogene and Miocene uplift of the Northern Ordos Basin on the formation of the Dongsheng uranium district, China

NASA Astrophysics Data System (ADS)

Zhang, Chuang; Yi, Chao; Dong, Qian; Cai, Yu-Qi; Liu, Hong-Xu

2018-02-01

The Dongsheng uranium district, located in the northern part of the Ordos Basin, contains the largest known sandstone-hosted uranium deposit in China. This district contains (from west to east) the Daying, Nalinggou, and Dongsheng uranium deposits that host tens of thousands of metric tonnes of estimated recoverable uranium resources at an average grade of 0.05% U. These uranium orebodies are generally hosted by the lower member of the Zhiluo Formation and are dominantly roll or tabular in shape. The uranium deposits in this district formed during two stages of mineralization (as evidenced by U-Pb dating) that occurred at 65-60 and 25 Ma. Both stages generated coffinite, pitchblende, anatase, pyrite, and quartz, with or without sericite, chlorite, calcite, fluorite, and hematite. The post-Late Cretaceous uplift of the Northern Ordos Basin exposed the northern margins of the Zhiluo Formation within the Hetao depression at 65-60 Ma, introducing groundwater into the formation and generating the first stage of uranium mineralization. The Oligocene (∼25 Ma) uplift of this northern margin exposed either the entirety of the southern flank of the Hetao depression or only the clastic sedimentary part of this region, causing a second gravitational influx of groundwater into the Zhiluo Formation and forming the second stage of uranium mineralization.

Large-Scale Experiments in Microbially Induced Calcite Precipitation (MICP): Reactive Transport Model Development and Prediction

NASA Astrophysics Data System (ADS)

Nassar, Mohamed K.; Gurung, Deviyani; Bastani, Mehrdad; Ginn, Timothy R.; Shafei, Babak; Gomez, Michael G.; Graddy, Charles M. R.; Nelson, Doug C.; DeJong, Jason T.

2018-01-01

Design of in situ microbially induced calcite precipitation (MICP) strategies relies on a predictive capability. To date much of the mathematical modeling of MICP has focused on small-scale experiments and/or one-dimensional flow in porous media, and successful parameterizations of models in these settings may not pertain to larger scales or to nonuniform, transient flows. Our objective in this article is to report on modeling to test our ability to predict behavior of MICP under controlled conditions in a meter-scale tank experiment with transient nonuniform transport in a natural soil, using independently determined parameters. Flow in the tank was controlled by three wells, via a complex cycle of injection/withdrawals followed by no-flow intervals. Different injection solution recipes were used in sequence for transport characterization, biostimulation, cementation, and groundwater rinse phases of the 17 day experiment. Reaction kinetics were calibrated using separate column experiments designed with a similar sequence of phases. This allowed for a parsimonious modeling approach with zero fitting parameters for the tank experiment. These experiments and data were simulated using PHT3-D, involving transient nonuniform flow, alternating low and high Damköhler reactive transport, and combined equilibrium and kinetically controlled biogeochemical reactions. The assumption that microbes mediating the reaction were exclusively sessile, and with constant activity, in conjunction with the foregoing treatment of the reaction network, provided for efficient and accurate modeling of the entire process leading to nonuniform calcite precipitation. This analysis suggests that under the biostimulation conditions applied here the assumption of steady state sessile biocatalyst suffices to describe the microbially mediated calcite precipitation.

Studies of the mobility of uranium and thorium in Nevada Test Site tuff

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wollenberg, H.A.; Flexser, S.; Smith, A.R.

1991-06-01

Hydro-geochemical processes must be understood if the movement of radionuclides away from a breached radioactive waste canister is to be modeled and predicted. In this respect, occurrences of uranium and thorium in hydrothermal systems are under investigation in tuff and in rhyolitic tuff that was heated to simulate the effects of introduction of radioactive waste. In these studies, high-resolution gamma spectrometry and fission-track radiography are coupled with observations of alteration mineralogy and thermal history to deduce the evidence of, or potential for movement of, U and Th in response to the thermal environment. Observations to date suggest that U wasmore » mobile in the vicinity of the heater but that localized reducing environments provided by Fe-Ti-Mn-oxide minerals concentrated U and thus attenuated its migration.« less

Stratigraphic constraints on the timing and emplacement of the Alika 2 giant Hawaiian submarine landslide

USGS Publications Warehouse

McMurtry, Gary M.; Herrero-Bervera, Emilio; Cremer, Maximilian D.; Smith, John R.; Resig, Johanna; Sherman, Clark; Torresan, Michael E.

1999-01-01

Previous work has found evidence for giant tsunami waves that impacted the coasts of Lanai, Molokai and other southern Hawaiian Islands, tentatively dated at 100 + and 200 + ka by U-series methods on uplifted coral clasts. Seafloor imaging and related work off Hawaii Island has suggested the Alika phase 2 debris avalanche as the source of the ~ 100 ka "giant wave deposits", although its precise age has been elusive. More recently, a basaltic sand bed in ODP site 842 (~ 300 km west of Hawaii) estimated at 100 ?? 20 ka has been suggested to correlate with this or another large Hawaiian landslide. Our approach to the timing and linkage of giant submarine landslides and paleo-tsunami deposits is a detailed stratigraphic survey of pelagic deposits proximal to the landslide feature, beginning with a suite of seven piston, gravity and box cores collected in the vicinity of the Alika 2 slide. We used U-series dating techniques, including excess 230Th and 210Pb profiling, high-resolution paleomagnetic stratigraphy, including continuous, U-channel analysis, δ18O stratigraphy, visual and X-ray sediment lithology, and the petrology and geochemistry of the included turbidites and ash layers. Minimum ages for the Alika phase 2a slide from detailed investigation of two of the cores are 112 ± 15 ka and 125 ± 24 ka (2σ) based on excess 230Th dating. A less precise age for the Alika phase 1 and/or South Kona slide is 242 ± 80 ka (2σ), consistent with previous geological estimates. Oxygen isotope analyses of entrained planktonic foraminifera better constrain the Alika phase 2a maximum age at 127 ± 5 ka, which corresponds to the beginning of the stage 5e interglacial period. It is proposed that triggering of these giant landslides may be related to climate change when wetter periods increase the possibility of groundwater intrusion and consequent phreatomagmatic eruptions of shallow magma chambers. Our study indicates the contemporaneity of the Alika giant submarine landslides and distal deposits from enormous turbidity currents as well as coral clasts reported to be tsunami deposits on Lanai and Molokai through direct dating and compositional analysis of the landslide deposits.

Stratigraphic constraints on the timing and emplacement of the Alika 2 giant Hawaiian submarine landslide

NASA Astrophysics Data System (ADS)

McMurtry, Gary M.; Herrero-Bervera, Emilio; Cremer, Maximilian D.; Smith, John R.; Resig, Johanna; Sherman, Clark; Torresan, Michael E.

1999-12-01

Previous work has found evidence for giant tsunami waves that impacted the coasts of Lanai, Molokai and other southern Hawaiian Islands, tentatively dated at 100+ and 200+ ka by U-series methods on uplifted coral clasts. Seafloor imaging and related work off Hawaii Island has suggested the Alika phase 2 debris avalanche as the source of the ˜100 ka "giant wave deposits", although its precise age has been elusive. More recently, a basaltic sand bed in ODP site 842 (˜300 km west of Hawaii) estimated at 100±20 ka has been suggested to correlate with this or another large Hawaiian landslide. Our approach to the timing and linkage of giant submarine landslides and paleo-tsunami deposits is a detailed stratigraphic survey of pelagic deposits proximal to the landslide feature, beginning with a suite of seven piston, gravity and box cores collected in the vicinity of the Alika 2 slide. We used U-series dating techniques, including excess 230Th and 210Pb profiling, high-resolution paleomagnetic stratigraphy, including continuous, U-channel analysis, δ 18O stratigraphy, visual and X-ray sediment lithology, and the petrology and geochemistry of the included turbidites and ash layers. Minimum ages for the Alika phase 2a slide from detailed investigation of two of the cores are 112±15 ka and 125±24 ka (2 σ) based on excess 230Th dating. A less precise age for the Alika phase 1 and/or South Kona slide is 242±80 ka (2 σ), consistent with previous geological estimates. Oxygen isotope analyses of entrained planktonic foraminifera better constrain the Alika phase 2a maximum age at 127±5 ka, which corresponds to the beginning of the stage 5e interglacial period. It is proposed that triggering of these giant landslides may be related to climate change when wetter periods increase the possibility of groundwater intrusion and consequent phreatomagmatic eruptions of shallow magma chambers. Our study indicates the contemporaneity of the Alika giant submarine landslides and distal deposits from enormous turbidity currents as well as coral clasts reported to be tsunami deposits on Lanai and Molokai through direct dating and compositional analysis of the landslide deposits.

Origin of an unusual monazite-xenotime gneiss, Hudson Highlands, New York: SHRIMP U-Pb geochronology and trace element geochemistry

USGS Publications Warehouse

Aleinikoff, John N.; Grauch, Richard I.; Mazdab, Frank K.; Kwak, Loretta; Fanning, C. Mark; Kamo, Sandra L.

2012-01-01

A pod of monazite-xenotime gneiss (MXG) occurs within Mesoproterozoic paragneiss, Hudson Highlands, New York. This outcrop also contains granite of the Crystal Lake pluton, which migmatized the paragneiss. Previously, monazite, xenotime, and zircon from MXG, plus detrital zircon from the paragneiss, and igneous zircon from the granite, were dated using multi-grain thermal ionization mass spectrometry (TIMS). New SEM imagery of dated samples reveals that all minerals contain cores and rims. Thus TIMS analyses comprise mixtures of age components and are geologically meaningless. New spot analyses by sensitive high resolution ion microprobe (SHRIMP) of small homogeneous areas on individual grains allows deconvolution of ages within complexly zoned grains. Xenotime cores from MXG formed during two episodes (1034 ± 10 and 1014 ± 3 Ma), whereas three episodes of rim formation are recorded (999 ± 7, 961 ± 11, and 874 ± 11 Ma). Monazite cores from MXG mostly formed at 1004 ± 4 Ma; rims formed at 994 ± 4, 913 ± 7, and 890 ± 7 Ma. Zircon from MXG is composed of oscillatory-zoned detrital cores (2000-1170 Ma), plus metamorphic rims (1008 ± 7, 985 ± 5, and ∼950 Ma). In addition, MXG contains an unusual zircon population composed of irregularly-zoned elongate cores dated at 1036 ± 5 Ma, considered to be the time of formation of MXG. The time of granite emplacement is dated by oscillatory-zoned igneous cores at 1058 ± 4 Ma, which provides a minimum age constraint for the time of deposition of the paragneiss. Selected trace elements, including all REE plus U and Th, provide geochemical evidence for the origin of MXG. MREE-enriched xenotime from MXG are dissimilar from typical HREE-enriched patterns of igneous xenotime. The presence of large negative Eu anomalies and high U and Th in monazite and xenotime are uncharacteristic of typical ore-forming hydrothermal processes. We conclude that MXG is the result of unusual metasomatic processes during high grade metamorphism that was initiated at about 1035 Ma. This rock was then subjected to repeated episodes of dissolution/reprecipitation for about 150 m.y. during regional cooling of the Hudson Highlands.

Origin of an unusual monazite-xenotime gneiss, Hudson Highlands, New York: SHRIMP U-Pb geochronology and trace element geochemistry

USGS Publications Warehouse

Aleinikoff, John N.; Grauch, Richard I.; Mazdab, Frank K.; Kwak, Loretta; Fanning, C. Mark; Kamo, Sandra L.

2012-01-01

A pod of monazite-xenotime gneiss (MXG) occurs within Mesoproterozoic paragneiss, Hudson Highlands, New York. This outcrop also contains granite of the Crystal Lake pluton, which migmatized the paragneiss. Previously, monazite, xenotime, and zircon from MXG, plus detrital zircon from the paragneiss, and igneous zircon from the granite, were dated using multi-grain thermal ionization mass spectrometry (TIMS). New SEM imagery of dated samples reveals that all minerals contain cores and rims. Thus TIMS analyses comprise mixtures of age components and are geologically meaningless. New spot analyses by sensitive high resolution ion microprobe (SHRIMP) of small homogeneous areas on individual grains allows deconvolution of ages within complexly zoned grains.Xenotime cores from MXG formed during two episodes (1034 ± 10 and 1014 ± 3 Ma), whereas three episodes of rim formation are recorded (999 ± 7, 961 ± 11, and 874 ± 11 Ma). Monazite cores from MXG mostly formed at 1004 ± 4 Ma; rims formed at 994 ± 4, 913 ± 7, and 890 ± 7 Ma. Zircon from MXG is composed of oscillatory-zoned detrital cores (2000-1170 Ma), plus metamorphic rims (1008 ± 7, 985 ± 5, and ∼950 Ma). In addition, MXG contains an unusual zircon population composed of irregularly-zoned elongate cores dated at 1036 ± 5 Ma, considered to be the time of formation of MXG. The time of granite emplacement is dated by oscillatory-zoned igneous cores at 1058 ± 4 Ma, which provides a minimum age constraint for the time of deposition of the paragneiss.Selected trace elements, including all REE plus U and Th, provide geochemical evidence for the origin of MXG. MREE-enriched xenotime from MXG are dissimilar from typical HREE-enriched patterns of igneous xenotime. The presence of large negative Eu anomalies and high U and Th in monazite and xenotime are uncharacteristic of typical ore-forming hydrothermal processes. We conclude that MXG is the result of unusual metasomatic processes during high grade metamorphism that was initiated at about 1035 Ma. This rock was then subjected to repeated episodes of dissolution/reprecipitation for about 150 m.y. during regional cooling of the Hudson Highlands.

Modelling the evolution of complex conductivity during calcite precipitation on glass beads

NASA Astrophysics Data System (ADS)

Leroy, Philippe; Li, Shuai; Jougnot, Damien; Revil, André; Wu, Yuxin

2017-04-01

When pH and alkalinity increase, calcite frequently precipitates and hence modifies the petrophysical properties of porous media. The complex conductivity method can be used to directly monitor calcite precipitation in porous media because it is sensitive to the evolution of the mineralogy, pore structure and its connectivity. We have developed a mechanistic grain polarization model considering the electrochemical polarization of the Stern and diffuse layers surrounding calcite particles. Our complex conductivity model depends on the surface charge density of the Stern layer and on the electrical potential at the onset of the diffuse layer, which are computed using a basic Stern model of the calcite/water interface. The complex conductivity measurements of Wu et al. on a column packed with glass beads where calcite precipitation occurs are reproduced by our surface complexation and complex conductivity models. The evolution of the size and shape of calcite particles during the calcite precipitation experiment is estimated by our complex conductivity model. At the early stage of the calcite precipitation experiment, modelled particles sizes increase and calcite particles flatten with time because calcite crystals nucleate at the surface of glass beads and grow into larger calcite grains. At the later stage of the calcite precipitation experiment, modelled sizes and cementation exponents of calcite particles decrease with time because large calcite grains aggregate over multiple glass beads and only small calcite crystals polarize.

An aminostratigraphy for the British Quaternary based on Bithynia opercula

PubMed Central

Penkman, Kirsty E.H.; Preece, Richard C.; Bridgland, David R.; Keen, David H.; Meijer, Tom; Parfitt, Simon A.; White, Tom S.; Collins, Matthew J.

2013-01-01

Aminostratigraphies of Quaternary non-marine deposits in Europe have been previously based on the racemization of a single amino acid in aragonitic shells from land and freshwater molluscs. The value of analysing multiple amino acids from the opercula of the freshwater gastropod Bithynia, which are composed of calcite, has been demonstrated. The protocol used for the isolation of intra-crystalline proteins from shells has been applied to these calcitic opercula, which have been shown to more closely approximate a closed system for indigenous protein residues. Original amino acids are even preserved in bithyniid opercula from the Eocene, showing persistence of indigenous organics for over 30 million years. Geochronological data from opercula are superior to those from shells in two respects: first, in showing less natural variability, and second, in the far better preservation of the intra-crystalline proteins, possibly resulting from the greater stability of calcite. These features allow greater temporal resolution and an extension of the dating range beyond the early Middle Pleistocene. Here we provide full details of the analyses for 480 samples from 100 horizons (75 sites), ranging from Late Pliocene to modern. These show that the dating technique is applicable to the entire Quaternary. Data are provided from all the stratotypes from British stages to have yielded opercula, which are shown to be clearly separable using this revised method. Further checks on the data are provided by reference to other type-sites for different stages (including some not formally defined). Additional tests are provided by sites with independent geochronology, or which can be associated with a terrace stratigraphy or biostratigraphy. This new aminostratigraphy for the non-marine Quaternary deposits of southern Britain provides a framework for understanding the regional geological and archaeological record. Comparison with reference to sites yielding independent geochronology, in combination with other lines of evidence, allows tentative correlation with the marine oxygen isotope record. PMID:23396683

A high-precision chronological model for the decorated Upper Paleolithic cave of Chauvet-Pont d'Arc, Ardèche, France.

PubMed

Quiles, Anita; Valladas, Hélène; Bocherens, Hervé; Delqué-Količ, Emmanuelle; Kaltnecker, Evelyne; van der Plicht, Johannes; Delannoy, Jean-Jacques; Feruglio, Valérie; Fritz, Carole; Monney, Julien; Philippe, Michel; Tosello, Gilles; Clottes, Jean; Geneste, Jean-Michel

2016-04-26

Radiocarbon dates for the ancient drawings in the Chauvet-Pont d'Arc Cave revealed ages much older than expected. These early ages and nature of this Paleolithic art make this United Nations Educational, Scientific and Cultural Organization (UNESCO) site indisputably unique. A large, multidisciplinary dating program has recently mapped the anthropological evolution associated with the cave. More than 350 dates (by (14)C, U-Th, TL and (36)Cl) were obtained over the last 15 y. They include 259 radiocarbon dates, mainly related to the rock art and human activity in the cave. We present here more than 80 previously unpublished dates. All of the dates were integrated into a high-precision Bayesian model based on archaeological evidence to securely reconstruct the complete history of the Chauvet-Pont d'Arc Cave on an absolute timescale. It shows that there were two distinct periods of human activity in the cave, one from 37 to 33,500 y ago, and the other from 31 to 28,000 y ago. Cave bears also took refuge in the cave until 33,000 y ago.

A high-precision chronological model for the decorated Upper Paleolithic cave of Chauvet-Pont d’Arc, Ardèche, France

PubMed Central

Quiles, Anita; Valladas, Hélène; Bocherens, Hervé; Delqué-Količ, Emmanuelle; Kaltnecker, Evelyne; van der Plicht, Johannes; Delannoy, Jean-Jacques; Feruglio, Valérie; Fritz, Carole; Monney, Julien; Philippe, Michel; Tosello, Gilles; Clottes, Jean; Geneste, Jean-Michel

2016-01-01

Radiocarbon dates for the ancient drawings in the Chauvet-Pont d’Arc Cave revealed ages much older than expected. These early ages and nature of this Paleolithic art make this United Nations Educational, Scientific and Cultural Organization (UNESCO) site indisputably unique. A large, multidisciplinary dating program has recently mapped the anthropological evolution associated with the cave. More than 350 dates (by 14C, U-Th, TL and 36Cl) were obtained over the last 15 y. They include 259 radiocarbon dates, mainly related to the rock art and human activity in the cave. We present here more than 80 previously unpublished dates. All of the dates were integrated into a high-precision Bayesian model based on archaeological evidence to securely reconstruct the complete history of the Chauvet-Pont d’Arc Cave on an absolute timescale. It shows that there were two distinct periods of human activity in the cave, one from 37 to 33,500 y ago, and the other from 31 to 28,000 y ago. Cave bears also took refuge in the cave until 33,000 y ago. PMID:27071106

Determination of the half-life of the ground state of {sup 229}Th by using {sup 232}U and {sup 233}U decay series

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kikunaga, H.; Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198; Suzuki, T.

2011-07-15

The half-life of the ground state of {sup 229}Th ({sup 229}Th{sup g}) has become an important factor in nuclear technology, for example, in the geological disposal of nuclear spent fuel. However, the values reported in two previous studies are not in agreement. This study reevaluates the half-life of {sup 229}Th{sup g} by using a simple and reliable method. The {sup 232}U/{sup 233}U activity ratio of a {sup 232,233}U sample was measured by high-resolution {alpha}-particle spectrometry. Next, the {sup 228}Th/{sup 229}Th{sup g} activity ratio of the Th sample, which was grown from the {sup 232,233}U sample, was also measured. The half-lifemore » of {sup 229}Th{sup g} was calculated from these activity ratios, the growth time, and the half-lives of {sup 232}U, {sup 233}U, and {sup 228}Th. From the results of these five measurements, the half-life of {sup 229}Th{sup g} is determined to be 7932 {+-} 55 yr at a confidence level of 2{sigma}.« less

Ocean-Ice Sheet Interactions in the Norwegian Sea and Teleconnections to Low Latitude Hydrology and Atmospheric Circulation

NASA Astrophysics Data System (ADS)

Brendryen, J.; Hannisdal, B.; Haaga, K. A.; Haflidason, H.; Castro, D. D.; Grasmo, K. J.; Sejrup, H. P.; Edwards, R. L.; Cheng, H.; Kelly, M. J.; Lu, Y.

2016-12-01

Abrupt millennial scale climatic events known as Dansgaard-Oeschger events are a defining feature of the Quaternary climate system dynamics in the North Atlantic and beyond. We present a high-resolution multi-proxy record of ocean-ice sheet interactions in the Norwegian Sea spanning the interval between 50 and 150 ka BP. A comparison with low latitude records indicates a very close connection between the high northern latitude ocean-ice sheet interactions and large scale changes in low latitude atmospheric circulation and hydrology even on sub-millennial scales. The records are placed on a common precise radiometric chronology based on correlations to U/Th dated speleothem records from China and the Alps. This enables a comparison of the records to orbital and other climatically important parameters such as U/Th dated sea-level data from corals and speleothems. We explore the drive-response relationships in these coupled systems with the information transfer (IT) and the convergent cross mapping (CCM) analytical techniques. These methods employ conceptually different approaches to detect the relative strength and directionality of potentially chaotic and nonlinearly coupled systems. IT is a non-parametric measure of information transfer between data records based on transfer entropy, while CCM relies on delay reconstructions using Takens' theorem. This approach enables us to address how the climate system processes interact and how this interaction is affected by external forcing from for example greenhouse gases and orbital variability.

A high-resolved record of the Asian Summer Monsoon from Dongge Cave, China for the past 1200 years

NASA Astrophysics Data System (ADS)

Zhao, Kan; Wang, Yongjin; Edwards, R. Lawrence; Cheng, Hai; Liu, Dianbing; Kong, Xinggong

2015-08-01

Two annually-laminated and 230Th-dated stalagmite oxygen isotope (δ18O) records from Dongge Cave, China, provided a high-resolution Asian Summer Monsoon (ASM) history for the past 1200 years. A close similarity between annual band thickness and stable isotope analyses (δ13C and δ18O) suggests the calcite δ18O is most likely a proxy associated with ASM precipitation. The two duplicated stalagmite δ18O records show that the ASM varies at a periodicity of ∼220 years, concordant with a dominant cycle of solar activity. A period of strong ASM activity occurred during the Spörer Minimum (1450-1550 A.D.), followed by a striking drop circa 1580 A.D., potentially consistent with the social unrest in the final decades of China's Ming Dynasty (1368-1644 A.D.). Centennial-scale changes in ASM precipitation over the last millennium match well with changes in tropical Atlantic sea surface temperatures (SSTs) and South American summer monsoon precipitation. Our findings suggest that variations in low-latitude monsoon precipitation are probably driven by shifts in the mean position of the intertropical convergence zone (ITCZ), which is further mediated by solar activity and tropical SSTs.

Final report for DOE Grant No. DE-SC0006609 - Persistence of Microbially Facilitated Calcite Precipitation as an in situ Treatment for Strontium-90

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Robert W.; Fujita, Yoshiko; Hubbard, Susan S.

2013-11-15

Subsurface radionuclide and metal contaminants throughout the U.S. Department of Energy (DOE) complex pose one of DOE's greatest challenges for long-term stewardship. One promising stabilization mechanism for divalent ions, such as the short-lived radionuclide 90Sr, is co-precipitation in calcite. We have previously found that nutrient addition can stimulate microbial ureolytic activity, that this activity accelerates calcite precipitation and co-precipitation of Sr, and that higher calcite precipitation rates can result in increased Sr partitioning. We have conducted integrated field, laboratory, and computational research to evaluate the relationships between ureolysis and calcite precipitation rates and trace metal partitioning under environmentally relevant conditions,more » and investigated the coupling between flow/flux manipulations and precipitate distribution. A field experimental campaign conducted at the Integrated Field Research Challenge (IFRC) site located at Rifle, CO was based on a continuous recirculation design; water extracted from a down-gradient well was amended with urea and molasses (a carbon and electron donor) and re-injected into an up-gradient well. The goal of the recirculation design and simultaneous injection of urea and molasses was to uniformly accelerate the hydrolysis of urea and calcite precipitation over the entire inter-wellbore zone. The urea-molasses recirculation phase lasted, with brief interruptions for geophysical surveys, for 12 days and was followed by long-term monitoring which continued for 13 months. A post experiment core located within the inter-wellbore zone was collected on day 321 and characterized with respect to cation exchange capacity, mineral carbonate content, urease activity, ureC gene abundance, extractable ammonium (a urea hydrolysis product) content, and the 13C isotopic composition of solid carbonates. It was also subjected to selective extractions for strontium and uranium. Result of the core characterization suggest that urea hydrolysis occurred primarily within the upper portion of the inter-wellbore zone and that strontium was mobilized from cation exchange sites and subsequently co-precipitated with new calcium carbonate.« less

Resolving the age of Wilson Creek Formation tephras and the Mono Lake excursion using high-resolution SIMS dating of allanite and zircon rims

NASA Astrophysics Data System (ADS)

Vazquez, J. A.; Lidzbarski, M. I.

2012-12-01

Sediments of the Wilson Creek Formation surrounding Mono Lake preserve a high-resolution archive of glacial and pluvial responses along the eastern Sierra Nevada due to late Pleistocene climate change. An absolute chronology for the Wilson Creek stratigraphy is critical for correlating the paleoclimate record to other archives in the western U.S. and the North Atlantic region. However, multiple attempts to date the Wilson Creek stratigraphy using carbonates and interbedded rhyolitic tephras yield discordant 14C and 40Ar/39Ar results due to open-system effects, carbon reservoir uncertainties, as well as abundant xenocrysts entrained during eruption. Ion microprobe (SIMS) 238U-230Th dating of the final increments of crystallization recorded by allanite and zircon autocrysts from juvenile pyroclasts yields ages that effectively date eruption of key tephra beds and resolve age uncertainties about the Wilson Creek stratigraphy. To date the final several micrometers of crystal growth, individual allanite and zircon crystals were embedded in soft indium to allow sampling of unpolished rims. Isochron ages derived from rims on coexisting allanite and zircon (± glass) from hand-selected pumiceous pyroclasts delimit the timing of Wilson Creek sedimentation between Ashes 7 and 19 (numbering of Lajoie, 1968) to the interval between ca. 27 to ca. 62 ka. The interiors of individual allanite and zircon crystals sectioned in standard SIMS mounts yield model 238U-230Th ages that are mostly <10 k.y. older than their corresponding rim age, suggesting a relatively brief interval of allanite + zircon crystallization before eruption. A minority of allanite and zircon crystals yield rim and interior model ages of ca. 90-100 ka, and are likely to be antecrysts recycled from relatively early Mono Craters volcanism and/or intrusions. Tephra (Ash 15) erupted during the geomagnetic excursion originally designated the Mono Lake excursion yields a rim isochron age of ca. 41 ka indicating that the recorded event is instead the Laschamp excursion. The results are consistent with a depositional chronology from correlation of relative paleointensity (Zimmerman et al., 2006) that indicates quasi-synchronous glacial and hydrologic responses in the Sierra Nevada and Mono Basin to climate change, with intervals of lake filling and glacial-snowpack melting that are in phase with peaks in spring insolation. Moreover, the results demonstrate that high-spatial resolution SIMS dating of accessory mineral rims is an alternative and promising approach for resolving the depositional ages of silicic tephras containing minerals that crystallized over protracted intervals or that are plagued by incorporation of xenocrysts and/or antecrysts. References: Lajoie, K., 1968, PhD Dissertation, UC Berkeley; Zimmerman et al., 2006, EPSL 252: 94-106.

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Méndez-García, C.; Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx; Renteria-Villalobos, M.

2008-01-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. ²³²Th-series, ²³⁸U-series, ⁴⁰K and ¹³⁷Cs activity concentrations (AC, Bq kg⁻¹) were determined by gamma spectrometry with a high purity Ge detector. ²³⁸U and ²³⁴U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating ofmore » core sediments was performed applying CRS method to ²¹⁰Pb activities. Results were verified by ¹³⁷Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High ²³⁸U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) ²³⁴U/²³⁸U and ²³⁸U/²²⁶Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. ²³²Th/²³⁸U, ²²⁸Ra/²²⁶Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.« less