Helium isotopes of the Siberian sub-continental lithospheric mantle: Insights from eclogite xenoliths

NASA Astrophysics Data System (ADS)

Barry, P. H.; Hilton, D. R.; Day, J. M.; Pernet-Fisher, J.; Howarth, G. H.; Taylor, L. A.

2014-12-01

Helium isotopes (3He/4He) have been extensively used to define distinct segments of Earth's mantle and characterize its chemical structure. Specifically, they have been used to illustrate the long-term isolation and preservation of high-3He/4He (≥50 RA; [1]) plume-derived materials from the well-mixed and more-extensively degassed depleted MORB mantle (DMM) (8 RA; [2]). However, the He-isotope signature of the sub-continental lithospheric mantle (SCLM) remains relatively poorly characterized (6.1 RA; [3]). The Siberian craton hosts >1000 kimberlite intrusions, which carry mantle-derived xenoliths - of varying compositions (i.e., peridotites, dunites, and eclogites) - to the Earth's surface, making it an ideal setting for investigating the chemical evolution of the SCLM. Here, we report new He-isotope and concentration data for a suite of eclogitic xenoliths (n=10) from the Udachnaya pipe, Siberia. He-isotopes and [He] contents were determined by crushing garnet and pyroxene mineral separates from 2.7-3.1 Ga Siberian eclogites. 3He/4He values ranged from 0.11 to 1.0 RA, displaying predominantly radiogenic (i.e., low 3He/4He) He-isotope values. In contrast, Siberian flood basalt values extend up to ~13 RA [4]. Helium concentrations span ~4 orders of magnitude from 60 to 569,000 [4He]C ncm3STP/g. The radiogenic nature of Udachnaya eclogites indicate that they have been largely isolated from basaltic metasomatic fluxes over geological time due to position within the lithosphere and/or lithospheric age. Further, low 3He/4He values may reflect the addition of high U-Th material into the lithosphere by accretion of ancient island-arc terrains. These new data add to the growing He-isotope database [5,6] for the Siberian SCLM, and reveal the heterogeneous nature of this region with respect to He-isotopes, as well as the potential importance of crustal recycling and metasomatic processes. [1] Stuart et al., 2003. Nature. [2] Graham, 2002. Reviews in Mineralogy and Geochemistry. [3] Gautheron and Moreira, 2002. Earth and Planetary Science Letters [4] Basu et al., 1995. Science [5] Barry et al., 2013. AGU Abstract. [6] Day et al., 2012, AGU Abstract.

Geochemistry and mineralogy of kimberlites from the Arkhangelsk Region, NW Russia: evidence for transitional kimberlite magma types

NASA Astrophysics Data System (ADS)

Beard, A. D.; Downes, H.; Hegner, E.; Sablukov, S. M.

2000-03-01

The Arkhangelsk kimberlite province (AKP) is situated in the north of the Baltic Shield within the buried southeastern portion of the Kola-Kuloi craton. It forms part of the extensive Devonian magmatic event of the northern Baltic Shield and Kola Peninsula. Two main groups of kimberlites can be distinguished within the province: (1) kimberlites from the diamondiferous Zolotitsa field that have geochemical and isotopic affinities with Group 2 kimberlites and lamproites; (2) diamond-poor Ti-Fe-rich kimberlites from other Arkhangelsk fields that have geochemical and isotopic affinities with Group 1 kimberlites. However, the Zolotitsa and Ti-Fe-rich kimberlites have mineralogical characteristics that are not typical for their respective assigned kimberlite group classifications. Both groups of Arkhangelsk kimberlites are apparently transitional to Group 1 kimberlites, Group 2 kimberlites and lamproites as they are defined elsewhere in the world. An associated kimberlite from the Mela Sill Complex has strong affinities with carbonatites. The low Al 2O 3, high Ni and Cr contents, and high Mg# in both groups of kimberlites indicate strongly depleted lherzolitic-harzburgitic mantle sources. Trace element patterns show a variable enrichment of incompatible elements and strong LREE enrichment. However, kimberlites from the Zolotitsa field have overall lower trace element abundances and less steep REE patterns, suggesting a higher degree of partial melt and/or a less enriched source compared to that of the Ti-Fe-rich kimberlites. A calciocarbonatite of the Mela Sill Complex has trace element and REE patterns typical of other carbonatites closely associated with kimberlites. 87Sr/ 86Sri and 143Nd/ 144Ndi isotope compositions of the Arkhangelsk kimberlites and carbonatite reveal that at least two mantle sources are required to explain the isotopic variation: (1) most of the Zolotitsa and Mela kimberlites and the Mela carbonatite are derived from an ancient enriched lithospheric source (EMI); (2) the Ti-Fe-rich kimberlites are derived from a plume-related asthenospheric mantle source with an isotopic composition close to Bulk Earth. Present-day Pb isotope compositions reveal that the Zolotitsa kimberlites have values close to Group 1 kimberlites. However, the Ti-Fe-rich kimberlites generally have slightly more radiogenic Pb isotope values.

Comparative geochemistry of West African kimberlites: Evidence for a micaceous kimberlite endmember of sublithospheric origin

NASA Astrophysics Data System (ADS)

Taylor, Wayne R.; Tompkins, Linda A.; Haggerty, Stephen E.

1994-10-01

A suite of largely unaltered, aphanitic, mica-bearing hypabyssal kimberlites from the Koidu kimberlite complex of the West African Craton have been investigated to determine their geochemical affinity relative to Group I (nonmicaceous) and Group II (micaceous) kimberlites of southern Africa. Comparison is made with altered kimberlites from Liberia, other West African and global kimberlites. Based on major element oxides, the Koidu kimberlites, though mica-bearing, show closest compositional similarity with the Group IA kimberlites of southern Africa. Based on major and trace elements, the Koidu kimberlites show an unusual geochemical signature. This signature is similar to that of the distinctive, micaceous Aries kimberlite of northwest Australia, and includes high Nb/U (most samples > 46), Ce/Sr(>0.4), Ta/Hf(>2), and Nb/Zr(>1) ratios and low P 2O 5/Ce ∗10 4(<27), Ba/Rb(<32), and U/Th(<0.2) ratios compared with Group I kimberlites. Koidu kimberlites can be readily discriminated from Group II kimberlites by their higher Ti/K(>0.4) and Mb/La(>1) ratios and lower Ba/Nb(<10) and Pb/Ce(<0.06) ratios. The compositions of Liberian kimberlites are leached of mobile incompatible elements, but least affected samples show affinity to Group I. Guinea kimberlites appear to be of two types: one having affinity with Group IA and the other, micaceous variety, having affinity with the Aries kimberlite. Kimberlites with an Aries geochemical signature appear to exist on some other cratons, e.g., the Kundelungu kimberlites (Zaire) and two mica-bearing Group I kimberlites (S. Africa). The Koidu kimberlites exhibit compositionally-dependent isotopic heterogeneity though initial ɛNd and ɛSr values are broadly asthenospheric (i.e., near bulk earth) similar to Group I and Aries. A compositional spectrum appears to exist between nonmicaceous Group I kimberlites through mica-bearing Koidu kimberlites to extreme endmembers of the Aries type. This spectrum can be modelled as partial melts of heterogeneous peridotite sources which incorporate a potassic, high-Nb source component. The component may represent a fluoro-K-richterite-bearing peridotite residue derived by melt extraction from subduction-zone metasomatized peridotites. Such materials may have been trapped, together with former oceanic lithosphere, in the Transition Zone of the mantle. In response to lower mantle upwelling, diapiric uprise accompanying reduced volatile degassing of the kimberlite source may occur. Because of differences in oxidation potential across the 400 km discontinuity, reactions in the ascending diapir will lead to redox melting and ultimately segregation of the kimberlite melt at the base of the thermal boundary layer (P ~ 13 GPa) separating the subcratonic lithosphere from the convective mantle.

Linearity of Mid-Continent Kimberlite-Carbonatite Magmatism, USA: Slab-Edge Focus as Alternative to Hot-Spot Track

NASA Astrophysics Data System (ADS)

Duke, G. I.; Carlson, R. W.

2009-12-01

The fates of subducted oceanic slabs at depth in the mantle are not well known, but linear trends of unusual magmatic products such as kimberlites and carbonatites might be used to track their past existence within the mantle. A N40°W linear trend of kimberlites and carbonatites, and rocks of kimberlitic affinity, from the Black Hills (WY-SD) to Alberta, was suggested to have been caused by upwelling mantle material focused directly above the western edge of the subducted Kula plate stalled in the transition zone, with a slab window or “tear” to the southwest (Duke, 2009). In contrast, a linear zone of similar magmas to the south (a southerly extension of this N40°W linear trend, from Kansas to Louisiana) has been proposed to represent a hot spot trace produced by a mantle plume (“Bermuda Hot Spot”). Ongoing studies of ages and geochemistry of alkalic rocks along the N40°W trend from Louisiana to Alberta provide increasing evidence for a slab-edge model as the cause of the linear trend of kimberlites and carbonatites in the mid-continent. In addition, seismic tomography indicates that the torn Farallon slab currently is stalled in the transition zone below the mid-continent, and an older slab is within the lower mantle farther to the east (Sigloch et al., 2008). These seismic data were interpreted as revealing the presence of the western edge of the Farallon plate trending roughly N40°W. The slab edge as projected to the surface is parallel to, but slightly west of, the trend of kimberlites and carbonatites at the mid-continent. Recently published ages show no clear age progression for the magmatism and thus do not support a hot-spot hypothesis for the linear trend. The isotopic compositions of the alkalic rocks show a genetic similarity among more recent magmas along the trend. There are at least four main pulses of magmatism along the trend at 110-85, 67-64, 55-52, and less than 50 Ma. Kimberlites and carbonatites in the northern section of the N40°W trend are the youngest of the northern group, with ages of ~48 to ≤ 46 Ma. The southern portion of the trend contains the oldest alkalic magmatism in Arkansas, Kansas, and Louisiana, with kimberlites in Kansas and carbonatites in Arkansas. The 67-64 Ma magmatic (or “reheating”) pulse was recorded along the entire trend from Louisiana to northern Montana. Multiple slabs and/or slab segmentation, and irregular convection may account for multiple magmatic pulses, although the 67-64 Ma magmatism across the entire continent is difficult to explain. Importantly, kimberlites and carbonatites represent the most recent, or part of the most recent, magmatism along the N40°W trend. This correlates with a change in proportion of source composition with time, as indicated by increasing positive epsilon Nd and Hf, lower 87Sr/86Sr, and higher 207Pb/204Pb, 206/204Pb, and 208Pb/204Pb. Thus, in each area where there exist precise age and isotopic data, magmatism began with a component that was dominantly lithospheric, followed by increasing proportions of asthenospheric component with time, culminating with kimberlitic or carbonatite magmatism.

The potential for diamond-bearing kimberlite in northern Michigan and Wisconsin

USGS Publications Warehouse

Cannon, William F.; Mudrey, M.G.

1981-01-01

Between 1876 and 1913, diamonds were found in at least seven localities in southern and central Wisconsin. All were found in Pleistocene glacial deposits or Holocene river gravel. The bedrock kimberlite source for the diamonds is unknown but has been presumed to be in northern Canada, the only area north of Wisconsin previously known to contain kimberlites. Recently, a kimberlite pipe, here named the Lake Ellen kimberlite, has been found in Iron County, Michigan. That find suggests the possibility that drift diamonds in Wisconsin have come from a more local source--kimberlites in northern Michigan and Wisconsin. The Lake Ellen kimberlite is very poorly exposed, but a strong positive magnetic anomaly indicates that it is roughly circular in plan and about 200 m in diameter. Although the kimberlite is entirely surrounded by Precambrian rocks, it contains abundant inclusions of fossiliferous dolomite, probably from the Ordovician Black River Group that overlay the area when the kimberlite was intruded. The post-Ordovician age of the kimberlite leads us to suspect that other possible cryptovolcanic structures in Paleozoic rocks in the region were formed over kimberlite pipes that are not yet exposed by erosion. Such structures include Limestone Mountain and Sherman Hill, in Houghton and Baraga Counties, Michigan; Glover Bluff, in Marquette County, Wisconsin; and possibly an area along the Brule River south of Iron River, Michigan. No diamonds are known in the Lake Ellen kimberlite, but it has not been adequately sampled. The cryptovolcanic structures could not be the source of the drift diamonds in Wisconsin because even if the structures are caused by kimberlites, those kimberlites have not yet been exposed by erosion. Elsewhere in the world, kimberlite is seldom found as a single isolated body; clusters of bodies are more common, and the presence of one kimberlite implies that others may exist nearby. The discovery of additional kimberlites may be very difficult because of the extensive cover of glacial drift and the typical small size of kimberlite bodies. If all are magnetic, they might be found by detailed aeromagnetic surveys. However, the magnetism of the Lake Ellen kimberlite appears to be caused by secondary magnetite formed during serpentinization of olivine, so an unserpentinized kimberlite may not be strongly magnetic. We suggest that one or more diamond-bearing kimberlites may exist in northern Michigan or Wisconsin, but the discovery of such bodies is unlikely unless a very thorough search is undertaken.

Synchroneity of cratonic burial phases and gaps in the kimberlite record: Episodic magmatism or preservational bias?

NASA Astrophysics Data System (ADS)

Ault, Alexis K.; Flowers, Rebecca M.; Bowring, Samuel A.

2015-01-01

A variety of models are used to explain an apparent episodicity in kimberlite emplacement. Implicit in these models is the assumption that the preserved kimberlite record is largely complete. However, some cratons now mostly devoid of Phanerozoic cover underwent substantial Phanerozoic burial and erosion episodes that should be considered when evaluating models for global kimberlite distributions. Here we show a broad temporal coincidence between regional burial phases inferred from thermochronology and gaps in the kimberlite record in the Slave craton, Superior craton, and cratonic western Australia. A similar pattern exists in the Kaapvaal craton, although its magmatic, deposition, and erosion history differs in key ways from the other localities. One explanation for these observations is that there is a common cause of cratonic subsidence and suppression of kimberlite magmatism. Another possibility is that some apparent gaps in kimberlite magmatism are preservational artifacts. Even if kimberlites occurred during cratonic burial phases, the largest uppermost portions of the pipes would have been subsequently eroded along with the sedimentary rocks into which they were emplaced. In this model, kimberlite magmatism was more continuous than the preserved record suggests, implying that evidence for episodicity in kimberlite genesis should be carefully evaluated in light of potential preservational bias effects. Either way, the correlation between burial and kimberlite gaps suggests that cratonic surface histories are important for understanding global kimberlite patterns.

Kimberlites of the Man craton, West Africa

NASA Astrophysics Data System (ADS)

Skinner, E. M. W.; Apter, D. B.; Morelli, C.; Smithson, N. K.

2004-09-01

The Man craton in West Africa is an Archaean craton formerly joined to the Guyana craton (South America) that was rifted apart in the Mesozoic. Kimberlites of the Man craton include three Jurassic-aged clusters in Guinea, two Jurassic-aged clusters in Sierra Leone, and in Liberia two clusters of unknown age and one Neoproterozoic cluster recently dated at ∼800 Ma. All of the kimberlites irrespective of age occur as small pipes and prolific dykes. Some of the Banankoro cluster pipes in Guinea, the Koidu pipes in Sierra Leone and small pipes in the Weasua cluster in Liberia contain hypabyssal-facies kimberlite and remnants of the so-called transitional-facies and diatreme-facies kimberlite. Most of the Man craton kimberlites are mineralogically classified as phlogopite kimberlites, although potassium contents are relatively low. They are chemically similar to mica-poor Group 1A Southern African examples. The Jurassic kimberlites are considered to represent one province of kimberlites that track from older bodies in Guinea (Droujba 153 Ma) to progressively younger kimberlites in Sierra Leone (Koidu, 146 Ma and Tongo, 140 Ma). The scarcity of diatreme-facies kimberlites relative to hypabyssal-facies kimberlites and the presence of the so-called transitional-facies indicate that the pipes have been eroded down to the interface between the root and diatreme zones. From this observation, it is concluded that extensive erosion (1-2 km) has occurred since the Jurassic. In addition to erosion, the presence of abundant early crystallizing phlogopite is considered to have had an effect on the relatively small sizes of the Man craton kimberlites.

Nd-isotopes in selected mantle-derived rocks and minerals and their implications for mantle evolution

USGS Publications Warehouse

Basu, A.R.; Tatsumoto, M.

1980-01-01

The Sm-Nd systematics in a variety of mantle-derived samples including kimberlites, alnoite, carbonatite, pyroxene and amphibole inclusions in alkali basalts and xenolithic eclogites, granulites and a pyroxene megacryst in kimberlites are reported. The additional data on kimberlites strengthen our earlier conclusion that kimberlites are derived from a relatively undifferentiated chondritic mantle source. This conclusion is based on the observation that the e{open}Nd values of most of the kimberlites are near zero. In contrast with the kimberlites, their garnet lherzolite inclusions show both time-averaged Nd enrichment and depletion with respect to Sm. Separated clinopyroxenes in eclogite xenoliths from the Roberts Victor kimberlite pipe show both positive and negative e{open}Nd values suggesting different genetic history. A whole rock lower crustal scapolite granulite xenolith from the Matsoku kimberlite pipe shows a negative e{open}Nd value of -4.2, possibly representative of the base of the crust in Lesotho. It appears that all inclusions, mafic and ultramafic, in kimberlites are unrelated to their kimberlite host. The above data and additional Sm-Nd data on xenoliths in alkali basalts, alpine peridotite and alnoite-carbonatites are used to construct a model for the upper 200 km of the earth's mantle - both oceanic and continental. The essential feature of this model is the increasing degree of fertility of the mantle with depth. The kimberlite's source at depths below 200 km in the subcontinental mantle is the most primitive in this model, and this primitive layer is also extended to the suboceanic mantle. However, it is clear from the Nd-isotopic data in the xenoliths of the continental kimberlites that above 200 km the continental mantle is distinctly different from their suboceanic counterpart. ?? 1980 Springer-Verlag.

The Fazenda Largo off-craton kimberlites of Piauí State, Brazil

NASA Astrophysics Data System (ADS)

Kaminsky, Felix V.; Sablukov, Sergei M.; Sablukova, Ludmila I.; Zakharchenko, Olga D.

2009-10-01

In the late 1990s, the Fazenda Largo kimberlite cluster was discovered in the Piauí State of Brazil. As with earlier known kimberlites in this area - Redondão, Santa Filomena-Bom Jesus (Gilbues) and Picos - this cluster is located within the Palaeozoic Parnaiba Sedimentary Basin that separates the São Francisco and the Amazonian Precambrian cratons. Locations of kimberlites are controlled by the 'Transbrasiliano Lineament'. The Fazenda Largo kimberlites are intensely weathered, almost completely altered rocks with a fine-grained clastic structure, and contain variable amounts of terrigene admixture (quartz sand). These rocks represent near-surface volcano-sedimentary deposits of the crater parts of kimberlite pipes. By petrographic, mineralogical and chemical features, the Fazenda Largo kimberlites are similar to average kimberlite. The composition of the deep-seated material in the Fazenda Largo kimberlites is quite diverse: among mantle microxenoliths are amphibolitised pyrope peridotites, garnetised spinel peridotites, ilmenite peridotites, chromian spinel + chromian diopside + pyrope intergrowths, and large xenoliths of pyrope dunite. High-pressure minerals are predominantly of the ultramafic suite, Cr-association minerals (purplish-red and violet pyrope, chromian spinel, chromian diopside, Cr-pargasite and orthopyroxene). The Ti-association minerals of the ultramafic suite (picroilmenite and orange pyrope), as well as rare grains of orange pyrope-almandine of the eclogite association, are subordinate. Kimberlites from all four pipes contain rare grains of G10 pyrope of the diamond association, but chromian spinel of the diamond association was not encountered. By their tectonic position, by geochemical characteristics, and by the composition of kimberlite indicator minerals, the Fazenda Largo kimberlites, like the others of such type, are unlikely to be economic.

Kimberlite emplacement record in diamond morphology

NASA Astrophysics Data System (ADS)

Fedortchouk, Y.; Chinn, I.

2015-12-01

Diamond resorption morphology reflects conditions and events in the host kimberlite magma and in diamond sources in subcratonic mantle. Recent experimental studies on diamond dissolution enable us now to use surface features of diamonds to examine magmatic fluid in kimberlites. This study uses optical and scanning electron microscopy examination of ~750 macro-diamonds from two kimberlites in Orapa cluster, Botswana. Kimberlite A is a simple body filled with coherent kimberlite facies (CK); kimberlite B is a complex body with two facies of coherent kimberlite and a massive volcaniclastic kimberlite facies (MVK). Distinction between kimberlite-induced and mantle-derived resorption was based on: the type of the most abundant resorption style, morphology of crystals with attached kimberlite fragments, and the study of pseudohemimorphic diamonds. Kimberlite-induced resorption is the focus of this work. The three facies in the pipe B show three contrasting diamond resorption types. Resorption in MVK facies leads to glossy rounded surfaces with fine striation and hillocks, and is identical to the resorption style in CK facies of pipe A. This type of resorption is typical for volcaniclastic facies and indicates emplacement in the presence of abundant COH fluid with high H2O:CO2 ratio (>50mol% of H2O). We propose that pipe A is a root zone supplying material to a larger kimberlite body filled with VK. The two CK in pipe B have very different resorption style. One forms similar glossy surfaces but with regular small cavities of rounded outline, while the other seems more corrosive and develops extremely rough features and deep cavities. Comparison to the experimental data suggests that the former had almost pure H2O fluid at low pressure (where solubility of SiO2 is low). The later CK facies was emplaced in the absence or very low abundance of a free fluid, and possibly in melt closer to carbonatitic composition.

Temporal, geomagnetic and related attributes of kimberlite magmatism at Ekati, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Lockhart, Grant; Grütter, Herman; Carlson, Jon

2004-09-01

This paper outlines the development of a multi-disciplinary strategy to focus exploration for economic kimberlites on the Ekati property. High-resolution aeromagnetic data provide an over-arching spatial and magnetostratigraphic framework for exploration and kimberlite discovery at Ekati, and hence also for this investigation. The temporal, geomagnetic, spatial and related attributes of kimberlites with variable diamond content have been constrained by judiciously augmenting the information gathered during routine exploration with detailed, laboratory-based or field-based investigations. The natural remanent magnetisation of 36 Ekati kimberlites has been correlated with their age as determined by isotopic dating techniques, and placed in the context of a well-constrained geomagnetic polarity timescale. Kimberlite magmatism occurred over the period 75 to 45 Ma, in at least five temporally discrete intrusive episodes. Based on current evidence, the older kimberlites (75 to 59 Ma) have low diamond contents and are distributed throughout the property. Younger kimberlites (56 to 45 Ma) have moderate to high diamond contents and occur in three distinct intrusive corridors with NNE to NE orientations. Economic kimberlite pipes erupted at 55.4±0.4 Ma along the A154-Lynx intrusive corridor, which is 7 km wide and oriented at 015°, and at 53.2±0.3 Ma along the Panda intrusive corridor, which is 1 km wide and oriented at 038°. The intrusion ages straddle a paleopole reversal at Chron C24n, consistent with the observation that the older economic kimberlites present as aeromagnetic "low" anomalies while the younger economic pipes are characterised as aeromagnetic "highs". The aeromagnetic responses for these kimberlites are generally muted because they contain volcaniclastic rock types with low magnetic susceptibility. Kimberlites throughout the Ekati property carry a primary natural magnetic remanence (NRM) vector in Ti-bearing groundmass magnetite, and it dominates over vectors related to induced magnetisation. Magnetostratigraphic correlation of Ekati kimberlites may therefore present a powerful adjunct to existing exploration techniques, mainly because the diamond content of Ekati kimberlites apparently is related more to the age of eruption than to any other parameter investigated in this work.

Orapa Diamond Mine, Botswana

NASA Image and Video Library

2015-11-16

This image from NASA Terra spacecraft shows the Orapa diamond mine, the world largest diamond mine by area. The mine is located in Botswana. It is the oldest of four mines operated by the same company, having begun operations in 1971. Orapa is an open pit style of mine, located on two kimberlite pipes. Currently, the Orapa mine annually produces approximately 11 million carats (2200 kg) of diamonds. The Letlhakane diamond mine is also an open pit construction. In 2003, the Letlhakane mine produced 1.06 million carats of diamonds. The Damtshaa diamond mine is the newest of four mines, located on top of four distinct kimberlite pipes of varying ore grade. The mine is forecast to produce about 5 million carats of diamond over the projected 31 year life of the mine. The image was acquired October 5, 2014, covers an area of 28 by 45 km, and is located at 21.3 degrees south, 25.4 degrees east. http://photojournal.jpl.nasa.gov/catalog/PIA20104

Use of high-resolution ground-penetrating radar in kimberlite delineation

USGS Publications Warehouse

Kruger, J.M.; Martinez, A.; Berendsen, P.

1997-01-01

High-resolution ground-penetrating radar (GPR) was used to image the near-surface extent of two exposed Late Cretaceous kimberlites intruded into lower Permian limestone and dolomite host rocks in northeast Kansas. Six parallel GPR profiles identify the margin of the Randolph 1 kimberlite by the up-bending and termination of limestone reflectors. Five radially-intersecting GPR profiles identify the elliptical margin of the Randolph 2 kimberlite by the termination of dolomite reflectors near or below the kimberlite's mushroom-shaped cap. These results suggest GPR may augment magnetic methods for the delineation of kimberlites or other forceful intrusions in a layered host rock where thick, conductive soil or shale is not present at the surface.

A Principal Component Analysis/Fuzzy Comprehensive Evaluation for Rockburst Potential in Kimberlite

NASA Astrophysics Data System (ADS)

Pu, Yuanyuan; Apel, Derek; Xu, Huawei

2018-02-01

Kimberlite is an igneous rock which sometimes bears diamonds. Most of the diamonds mined in the world today are found in kimberlite ores. Burst potential in kimberlite has not been investigated, because kimberlite is mostly mined using open-pit mining, which poses very little threat of rock bursting. However, as the mining depth keeps increasing, the mines convert to underground mining methods, which can pose a threat of rock bursting in kimberlite. This paper focuses on the burst potential of kimberlite at a diamond mine in northern Canada. A combined model with the methods of principal component analysis (PCA) and fuzzy comprehensive evaluation (FCE) is developed to process data from 12 different locations in kimberlite pipes. Based on calculated 12 fuzzy evaluation vectors, 8 locations show a moderate burst potential, 2 locations show no burst potential, and 2 locations show strong and violent burst potential, respectively. Using statistical principles, a Mahalanobis distance is adopted to build a comprehensive fuzzy evaluation vector for the whole mine and the final evaluation for burst potential is moderate, which is verified by a practical rockbursting situation at mine site.

Zn isotopic heterogeneity in the mantle: A melting control?

NASA Astrophysics Data System (ADS)

Doucet, Luc S.; Mattielli, Nadine; Ionov, Dmitri A.; Debouge, Wendy; Golovin, Alexander V.

2016-10-01

We present new Zn elemental and isotope data on seventeen fertile and refractory mantle peridotite xenoliths. Eleven fertile peridotites are garnet and spinel lherzolites from Vitim and Tariat (Siberia and Mongolia) and represent some of the most pristine fertile peridotites available. Six refractory peridotites are spinel harzburgites from the Udachnaya kimberlite (Siberian craton) that are nearly pristine residues of high-degree polybaric melting at high pressure (7-4 GPa). Geochemical data suggest that Zn isotopic compositions in the peridotites have not been affected by post-melting processes such as metasomatism, contamination by the host-magmas or alteration. The fertile peridotites have uniform Zn concentrations (59 ± 2 ppm) and Zn isotopic compositions with δ66Zn (relative to JMC-Lyon-03-0749l) = +0.30 ± 0.03‰ consistent with the Bulk Silicate Earth estimates of δ66Zn = +0.28 ± 0.05‰ (Chen et al., 2013). The refractory peridotites have Zn concentrations ranging from 30 to 48 ppm and δ66Zn from + 0.10 ± 0.01 ‰ to + 0.18 ± 0.01 ‰ with an average of + 0.14 ± 0.03 ‰. Our data suggest that the lithospheric mantle has a heterogeneous Zn isotopic composition. Modeling of Zn isotope partitioning during partial melting of fertile mantle suggests that high degrees of melt extraction (>30%) may significantly fractionate Zn isotopes (up to 0.16‰) and that during mantle melting, Zn concentrations and isotopic compositions are mainly controlled by the stability of clinopyroxene and garnet within the melting residue. Because the stability of clinopyroxene and garnet is mainly pressure dependent we suggest that both the depth and the degrees of melt extraction may control Zn isotope fractionation during mantle melting.

Role of fluid in the mechanism of formation of volcaniclastic and coherent kimberlite facies: a diamond perspective

NASA Astrophysics Data System (ADS)

Fedortchouk, Yana; Chinn, Ingrid

2016-04-01

Dissolution features on diamonds recovered from kimberlites vary depending on the dissolution conditions and can be used as a reliable proxy for volatiles and their role in kimberlite emplacement. Volatiles determine the mechanism of magma emplacement; variation in volatile content and CO2/CO2+H2O ratio may affect the geology of kimberlite bodies and formation of coherent vs. volcaniclastic kimberlite facies. Here we examine the evolution of a kimberlite system during ascent using the resorption morphology of its diamond population. We use 655 macro-diamonds from a complex kimberlite pipe in the Orapa kimberlite field (Botswana) to examine the role of volatiles in the formation of the three facies comprising this pipe: two coherent kimberlite facies (CKA and CKB) and one massive volcaniclastic facies (MVK). The diamonds come from three drillholes through each of the studied kimberlite facies. Separate diamond samples derived from 2 - 13 m intervals were combined into 40 m depth intervals for statistical purposes. Four independent morphological methods allowed us to reliably discriminate products of resorption in kimberlite magma from resorption in the mantle, and use the former in our study. We found that the proportion of diamonds with kimberlitic resorption is the lowest in CKA - 22%, medium in MVK - 50%, and highest in CKB - 73%, and it increases with depth in each of the drillholes. Each kimberlite facies shows its own style of kimberlite-induced resorption on rounded tetrahexahedron (THH) diamonds: glossy surfaces in MVK, rough corroded surfaces in CKB, and combination of glossy surfaces with chains of circular pits in CKA, where these pits represent the initial stages of development of corrosive features observed on CKB diamonds. Based on the results of our previous experimental studies we propose that resorption of MVK diamonds is a product of interaction with COH fluid, resorption of CKB diamonds is a product of interaction with a volatile-undersaturated melt (possibly carbonatitic), and CKA diamonds show an overprint of melt-controlled resorption over a fluid-controlled resorption. We propose an early separation of the fluid phase during the ascent of this kimberlite magma, segregation of this fluid and rise towards the top of the magma column. Over-pressurisation caused by the expansion of this fluid worked as a driving force for the magma ascent acceleration. The magma column has separated into two parts: (1) the bubble-rich magma towards the top, explosive emplacement of which formed the MVK facies, followed by the "tailing" bubble-poor magma quietly arriving to form the CKA facies, and (2) magma that lost volatiles to the upwardly escaping bubbles, in which a slower ascent caused more intensive diamond resorption and delayed emplacement, forming the CKB facie. It is possible that formation, buoyancy, and growth of fluid bubbles controls the ascent of the kimberlite magma, where emplacement of bubble-rich magma forms volcaniclastic kimberlite facies, while fast rise of the bubbles through the magma column separates the fluid-rich phase that moves up preparing the conduit in the surrounding rocks and forms an explosive pipe at the surface, from a volatile-depleted magma, which slowly rises and fills the pipe with CK kimberlite facies.

Application of Fe-Ti oxide dissolution experiments to the petrogenesis of the Ekati Diamond Mine kimberlites, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Kressall, R.; Fedortchouk, Y.; McCammon, C. A.

2015-12-01

Composition of kimberlites is ambiguous due to assimilation and fractional crystallization. We propose that the evolution history of minerals can be used to decipher the magmatic history of kimberlites. We use Fe-Ti oxides (chromite and ilmenite) from six kimberlites from the Ekati Diamond Mine and dissolution experiments to elucidate the petrogenesis of kimberlites. Experiments at 0.1 MPa and variable ƒO2s in a diopside-anorthite melt show that the dissolution rate of ilmenite is highly sensitive to ƒO2. No significant difference was observed in chromite. Zoning in chromite is related to the Fe-content and oxidation state of the melt. Experiments at 1 GPa explore the development of chromite surface resorption features in the system Ca-Mg-Si-H-C-O. Five kimberlites contain a low abundance of ilmenite, owing to a relatively high ƒO2, though ilmenite constituted 65% of oxide macocrysts in one kimberlite. Chromite compositions evolve from Mg-chromite to magnesio-ulvöspinel-magnetite (MUM) in all but one kimberlite where chromite evolves to a pleonaste composition perhaps as a result of rapid emplacement. The high abundance of MUM spinel and low abundance of ilmenite in the matrix could be related to the change in the stable Ti-phase with increasing ƒO2. Core compositions of macrocrysts vary for different mantle sources but rims converge to a composition slightly more oxidized and Mg-rich than chromite from depleted peridotite. Ilmenite commonly has rims composed of perovskite, titanite and MUM. We suggest a model where the kimberlite melt composition is controlled by the co-dissolution and co-precipitation of silicates (predominantly orthopyroxene and olivine) to explain chromite evolution in kimberlites. Resorption-related surface features on chromite macrocrysts show trigon protrusions-depressions on {111} faces and step-like features along the crystal edges resembling products of experiments in H2O fluid. We propose predominantly H2O magmatic fluid in Ekati kimberlites.

Sm-Nd, K-Ar and petrologic study of some kimberlites from eastern United States and their implication for mantle evolution

USGS Publications Warehouse

Basu, A.R.; Rubury, E.; Mehnert, H.; Tatsumoto, M.

1984-01-01

We provide new data on Sm-Nd systematics, K-Ar dating and the major element chemistry of kimberlites from the eastern United States (mostly from central New York State) and their constituent mineral phases of olivine, clinopyroxene, garnet, phlogopite and perovskite. In addition, we report Nd-isotopes in a few kimberlites from South Africa, Lesotho and from the eastern part of China. The major element compositions of the New York dike rocks and of their constituent minerals including a xenolith of eclogite are comparable with those from the Kimberley area in South Africa. The K-Ar age of emplacement of the New York dikes is further established to be 143 Ma. We have analyzed the Nd-isotopic composition of the following kimberlites and related rocks: Nine kimberlite pipes from South Africa and Lesotho, two from southern India; one from the U.S.S.R., fifteen kimberlite pipes and related dike rocks from eastern and central U.S. and two pipes from the Shandong Province of eastern China. The age of emplacement of these kimberlites ranges from 1300 million years to 90 million years. The initial Nd-isotopic compositions of these kimberlitic rocks expressed as e{open}NdIwith respect to a chondritic bulk-earth growth-curve show a range between 0 and +4, with the majority of the kimberlites being in the range 0 to +2. This range is not matched by any other suite of mantle-derived igneous rocks. This result strengthens our earlier conclusion that kimberlitic liquids are derived from a relatively primeval and unique mantle reservoir with a nearly chondritic Sm/Nd ratio. ?? 1984 Springer-Verlag.

Rockbursting Potential of Kimberlite: A Case Study of Diavik Diamond Mine

NASA Astrophysics Data System (ADS)

Leveille, Paul; Sepehri, Mohammadali; Apel, Derek B.

2017-12-01

The research described in this paper provides information about the rockbursting potential of kimberlite. Kimberlite is a diamond-bearing rock found in deposits around the world including northern Canada. This paper outlines three methods for the prediction of rockbursts based on the properties of a rock. The methods include the: strain energy index, strain energy density, and rock brittleness. Kimberlite samples collected from Diavik, a diamond mine in northern Canada, were tested to define the rock's uniaxial compressive strength, tensile strength, and hysteresis loop. The samples were separated into sub-rock types based on their descriptions from the mine geologists. The results indicate that it is possible to produce rockbursts in kimberlite. It was also observed that the sub-rock types had a range of rockbursting properties. Some types of kimberlite exhibited little to no potential for producing bursts, while other types potentially could produce violent bursts. The diverse nature of kimberlite indicates that the rockbursting properties of the rock should not be generalized and are dependent on the sub-rock type being encountered.

Geodynamics of kimberlites on a cooling Earth: Clues to plate tectonic evolution and deep volatile cycles

NASA Astrophysics Data System (ADS)

Tappe, Sebastian; Smart, Katie; Torsvik, Trond; Massuyeau, Malcolm; de Wit, Mike

2018-02-01

Kimberlite magmatism has occurred in cratonic regions on every continent. The global age distribution suggests that this form of mantle melting has been more prominent after 1.2 Ga, and notably between 250-50 Ma, than during early Earth history before 2 Ga (i.e., the Paleoproterozoic and Archean). Although preservation bias has been discussed as a possible reason for the skewed kimberlite age distribution, new treatment of an updated global database suggests that the apparent secular evolution of kimberlite and related CO2-rich ultramafic magmatism is genuine and probably coupled to lowering temperatures of Earth's upper mantle through time. Incipient melting near the CO2- and H2O-bearing peridotite solidus at >200 km depth (1100-1400 °C) is the petrologically most feasible process that can produce high-MgO carbonated silicate melts with enriched trace element concentrations akin to kimberlites. These conditions occur within the convecting asthenospheric mantle directly beneath thick continental lithosphere. In this transient upper mantle source region, variable CHO volatile mixtures control melting of peridotite in the absence of heat anomalies so that low-degree carbonated silicate melts may be permanently present at ambient mantle temperatures below 1400 °C. However, extraction of low-volume melts to Earth's surface requires tectonic triggers. Abrupt changes in the speed and direction of plate motions, such as typified by the dynamics of supercontinent cycles, can be effective in the creation of lithospheric pathways aiding kimberlite magma ascent. Provided that CO2- and H2O-fluxed deep cratonic keels, which formed parts of larger drifting tectonic plates, existed by 3 Ga or even before, kimberlite volcanism could have been frequent during the Archean. However, we argue that frequent kimberlite magmatism had to await establishment of an incipient melting regime beneath the maturing continents, which only became significant after secular mantle cooling to below 1400 °C during post-Archean times, probably sometime shortly after 2 Ga. At around this time kimberlites replace komatiites as the hallmark mantle-derived magmatic feature of continental shields worldwide. The remarkable Mesozoic-Cenozoic 'kimberlite bloom' between 250-50 Ma may represent the ideal circumstance under which the relatively cool and volatile-fluxed cratonic roots of the Pangea supercontinent underwent significant tectonic disturbance. This created more than 60% of world's known kimberlites in a combination of redox- and decompression-related low-degree partial melting. Less than 2% of world's known kimberlites formed after 50 Ma, and the tectonic settings of rare 'young' kimberlites from eastern Africa and western North America demonstrate that far-field stresses on cratonic lithosphere enforced by either continental rifting or cold subduction play a crucial role in enabling kimberlite magma transfer to Earth's surface.

Intensive Variables in Primary Kimberlite Magmas (Lac de Gras, N.W.T., Canada) and Application for Diamond Preservation

NASA Astrophysics Data System (ADS)

Fedortchouk, Y.; Canil, D.; Carlson, J. A.

2002-12-01

Crystallization temperatures (T) and oxygen fugacity (fO2) are not well constrained for kimberlites. Knowledge of these intensive variables of kimberlite melt is important for understanding the origin and evolution of kimberlites and prediction of diamond preservation in the magma. Difficulties in interpreting the equilibrium mineral assemblages in kimberlites and the high degree of secondary alteration usually complicate use of mineral geothermometers and oxygen barometers. Some of Lac de Gras (N.W.T., Canada) kimberlites are extremely fresh and provide opportunity to apply mineral thermobarometers. The presence of numerous chromite inclusions in the rims of olivine phenocrysts allows application of the olivine-spinel thermometer and oxygen barometer to constrain T and fO2 of the melt. We performed T and fO2 calculations on samples from three kimberlite pipes - the Leslie, Aaron and Grizzly. The T obtained from olivine - chromite pairs for crystallization of olivine phenocryst rims are 1050° to 1100°C +/- 50°C (calculated at 1 GPa). Few olivine - chromite pairs from Leslie and Grizzly record higher temperatures of 1250° - 1350°C. The cores of olivine phenocrysts usually lack chromite inclusions and their crystallization T and fO2 could not be estimated. The fO2 recorded by coexisting olivine and chromite are +0.3 to 1.0 +/- 0.4 log units more oxidized than the nickel-nickel oxide (NNO) buffer. The established fO2 of kimberlites would require fO2 in their mantle source to be higher than that of cratonic mantle and oceanic lithosphere producing MORB's but comparable to the source of subduction-related magmas. The T and fO2 for the Lac de Gras kimberlites constrain the path of any mantle material entrained in these magmas in fO2-T-P space and provide limits on diamond destructive processes. Diamonds are not stable in kimberlite magma and are oxidized to CO2 or converted into graphite. The former process is more favorable for their preservation. The results of out thermo-barometric calculations show that at any pressure the Lac de Gras kimberlites were above the Graphite (Diamond)-CCO buffer. Diamonds entrained in these kimberlites were moved into stability field of CO2 without graphitization, favoring better preservation of diamonds.

Asthenospheric kimberlites: Volatile contents and bulk compositions at 7 GPa

NASA Astrophysics Data System (ADS)

Stamm, Natalia; Schmidt, Max W.

2017-09-01

During ascent, kimberlites react with the lithospheric mantle, entrain and assimilate xenolithic material, loose volatiles and suffer from syn- and post-magmatic alteration. Consequently, kimberlite rocks deviate heavily from their primary melt. Experiments at 7 GPa, 1300-1480 °C, 10-30 wt% CO2 and 0.46 wt% H2O on a proposed primitive composition from the Jericho kimberlite show that saturation with a lherzolitic mineral assemblage occurs only at 1300-1350 °C for a carbonatitic melt with <8 wt% SiO2 and >35 wt% CO2. At asthenospheric temperatures of >1400 °C, where the Jericho melt stays kimberlitic, this composition saturates only in low-Ca pyroxene, garnet and partly olivine. We hence forced the primitive Jericho kimberlite into multiple saturation with a lherzolitic assemblage by adding a compound peridotite. Saturation in olivine, low- and high-Ca pyroxene and garnet was obtained at 1400-1650 °C (7 GPa), melts are kimberlitic with 18-29 wt% SiO2 + Al2O3, 22.1-24.6 wt% MgO, 15-27 wt% CO2 and 0.4-7.1 wt% H2O; with a trade-off of H2O vs. CO2 and temperature. Melts in equilibrium with high-Ca pyroxene with typical mantle compositions have ≥2.5 wt% Na2O, much higher than the commonly proposed 0.1-0.2 wt%. The experiments allow for a model of kimberlite origin in the convective upper mantle, which only requires mantle upwelling that causes melting at the depth where elemental carbon (in metal, diamond or carbide) converts to CO2 (at ∼250 km). If primary melts leading to kimberlites contain a few wt% H2O, then adiabatic temperatures of 1400-1500 °C would yield asthenospheric mantle melts that are kimberlitic (>18 wt% SiO2 + Al2O3) but not carbonatitic (<10 wt% SiO2 + Al2O3) in composition, carbonatites only forming 100-200 °C below the adiabat. These kimberlites represent small melt fractions concentrating CO2 and H2O and then acquire part of their chemical signature by assimilation/fractionation during ascent in the subcratonic lithosphere.

Basaltic Diatreme To Root Zone Volcanic Processes In Tuzo Kimberlite Pipe (Gahcho Kué Kimberlite Field, NWT, Canada)

NASA Astrophysics Data System (ADS)

Seghedi, I.; Kurszlaukis, S.; Maicher, D.

2009-05-01

Tuzo pipe is infilled by a series of coherent and fragmental kimberlite facies types typical for a diatreme to root zone transition level. Coherent or transitional coherent kimberlite facies dominate at depth, but also occur at shallow levels, either as dikes or as individual or agglutinated coherent kimberlite clasts (CKC). Several fragmental kimberlite varieties fill the central and shallow portions of the pipe. The definition, geometry and extent of the geological units are complex and are controlled by vertical elements. Specific for Tuzo is: (1) high abundance of locally derived xenoliths (granitoids and minor diabase) between and within the kimberlite phases, varying in size from sub-millimeter to several tens of meters, frequent in a belt-like domain between 120-200 m depth in the pipe; (2) the general presence of CKC, represented by round-subround, irregular to amoeboid-shaped clasts with a macrocrystic or aphanitic texture, mainly derived from fragmentation of erupting magma and less commonly from previously solidified kimberlite, as well as recycled pyroclasts. In addition, some CKC are interpreted to be intersections of a complex dike network. This diversity attests formation by various volcanic processes, extending from intrusive to explosive; (3) the presence of bedded polymict wall- rock and kimberlite breccia occurring mostly in deep levels of the pipe below 345 m depth. The gradational contact relationships of these deposits with the surrounding kimberlite rocks and their location suggest that they formed in situ. The emplacement of Tuzo pipe involved repetitive volcanic explosions alternating with periods of relative quiescence causing at least partial consolidation of some facies. The volume deficit in the diatreme-root zone after each eruption was compensated by gravitational collapse of overlying diatreme tephra and pre-fragmented wall-rock xenoliths. Highly explosive phases were alternating with weak explosions or intrusive phases, suggesting an external factor to control the explosive behaviour of the magma. The overall constant volatile content of the kimberlite does not explain the observed extreme change in emplacement behaviour. The facies architecture of fragmental facies dominated by vertical elements is similar to that in non- kimberlitic diatremes and indicates deposition from debris jets marking separate and repeated explosive volcanic events. In basaltic pipes, such jets are generated by phreatomagmatic explosions in the explosion chamber(s) of the root zone, causing abundant country rock fragmentation and further efficient mixture of the various particles. Phases of high explosivity formed the finely fragmented kimberlites containing a high percentage of wall-rock xenoliths, while the fluidal-shaped and partly welded texturally variable and wall-rock- poor transitional coherent facies suggest phases of repetitive, hot, and low-energy fragmentation forming kimberlite spatter. Peperite hosted in kimberlite tephra is also typically found in basaltic root zones. Time gaps in between volcanic eruptive periods are indicated by cognate pyroclasts and reworked wall-rock deposits emplaced by sporadic sedimentation events in subterranean cavities under the widening roof of the pipe. The presence of temporary caves in the root zone is proposed also by the occurrence of spherical CKC in deep- seated fragmental kimberlite and by spatter found in transitional coherent rocks. Evidence for caves was mostly preserved at deeper pipe levels advocating continuously recurring processes during the life span of Tuzo.

Platinum-group element contents of Karelian kimberlites: Implications for the PGE budget of the sub-continental lithospheric mantle

NASA Astrophysics Data System (ADS)

Maier, W. D.; O'Brien, H.; Peltonen, P.; Barnes, Sarah-Jane

2017-11-01

We present high-precision isotope dilution data for Os, Ir, Ru, Pt, Pd and Re in Group I and Group II kimberlites from the Karelian craton, as well as 2 samples of the Premier Group I kimberlite pipe from the Kaapvaal craton. The samples have, on average, 1.38 ppb Pt and 1.33 ppb Pd, with Pt/Pd around unity. These PGE levels are markedly lower, by as much as 80%, than those reported previously for kimberlites from South Africa, Brazil and India, but overlap with PGE results reported recently from Canadian kimberlites. Primitive-mantle-normalised chalcophile element patterns are relatively flat from Os to Pt, but Cu, Ni and, somewhat less so, Au are enriched relative to the PGE (e.g., Cu/Pd > 25.000). Pd/Ir ratios are 3,6 on average, lower than in most other mantle melts. The PGE systematics can be largely explained by two components, (i) harzburgite/lherzolite detritus of the SCLM with relatively high IPGE (Os-Ir-Ru)/PPGE (Rh-Pt-Pd) ratios, and (ii) a melt component that has high PPGE/IPGE ratios. By using the concentrations of iridium in the kimberlites as a proxy for the proportion of mantle detritus in the magma, we estimate that the analysed kimberlites contain 3-27% entrained and partially dissolved detritus from the sub-continental lithospheric mantle, consistent with previous estimates of kimberlites elsewhere (Tappe S. et al., 2016, Chem. Geol. 10.1016/j.chemgeo.2016.08.019).

3D geological modelling of the Renard 2 kimberlite pipe, Québec, Canada: from exploration to extraction

NASA Astrophysics Data System (ADS)

Lépine, Isabelle; Farrow, Darrell

2018-04-01

The Renard 2 kimberlite pipe is one of nine diamondiferous kimberlite pipes that form a cluster in the south-eastern portion of the Superior Province, Québec, Canada and is presently being extracted at the Renard Mine. It is interpreted as a diatreme-zone kimberlite consisting of two Kimberley-type pyroclastic units and related country rock breccias, all cross-cut by coherent kimberlite dykes and irregular intrusives. Renard 2 has been the subject of numerous diamond drilling campaigns since its discovery in 2001. The first two geological models modelled kimberlite and country rock breccia units separately. A change in modelling philosophy in 2009, which incorporated the emplacement envelope and history, modelled the entire intrusive event and projected the pipe shape to depth allowing for more targeted deep drilling where kimberlite had not yet been discovered. This targeted 2009 drilling resulted in a > 400% increase in the volume of the Indicated Resource. Modelling only the kimberlite units resulted in a significant underestimation of the pipe shape. Current open pit and underground mapping of the pipe shape corresponds well to the final 2015 geological model and contact changes observed are within the expected level of confidence for an Indicated Resource. This study demonstrates that a sound understanding of the geological emplacement is key to developing a reliable 3D geological and resource model that can be used for targeted delineation drilling, feasibility studies and during the initial stages of mining.

Origin of Ti-rich garnets in the groundmass of Wajrakarur field kimberlites, southern India: insights from EPMA and Raman spectroscopy

NASA Astrophysics Data System (ADS)

Dongre, Ashish N.; Viljoen, K. S.; Rao, N. V. Chalapathi; Gucsik, A.

2016-04-01

Although Ti-rich garnets are commonly encountered in the groundmass of many alkaline igneous rocks, they are comparatively rare in kimberlites. Here we report on the occurrence of Ti-rich garnets in the groundmass of the P-15 and KL-3 kimberlites from the diamondiferous Wajrakarur field in the Eastern Dharwar craton of southern India. These garnets contain considerable Ti (11.7-23.9 wt.% TiO2), Ca (31.3-35.8 wt.% CaO), Fe (6.8-15.5 wt.% FeOT) and Cr (0.04-9.7 wt.% Cr2O3), but have low Al (0.2-5.7 wt.% Al2O3). In the case of the P-15 kimberlite they display a range in compositions from andradite to schorlomite, with a low proportion of grossular (andradite(17.7-49.9)schorlomite(34.6-49.5)-grossular(3.7-22.8)-pyrope(1.9-10.4)). A few grains also contain significant chromium and represent a solid solution between schorlomite and uvarovite. The Ti-rich garnets in the KL-3 kimberlite, in contrast, are mostly schorlomitic (54.9-90.9 mol %) in composition. The Ti-rich garnets in the groundmass of these two kimberlites are intimately associated with chromian spinels, perhaps suggesting that the garnet formed through the replacement of spinel. From the textural evidence, it appears unlikely that the garnets could have originated through secondary alteration, but rather seem to have formed through a process in which early magmatic spinels have reacted with late circulating, residual fluids in the final stages of crystallization of the kimberlite magma. Raman spectroscopy provides evidence for low crystallinity in the spinels which is likely to be a result of their partial transformation into andradite during their reaction with a late-stage magmatic (kimberlitic) fluid. The close chemical association of these Ti-rich garnets in TiO2-FeO-CaO space with those reported from ultramafic lamprophyres (UML) is also consistent with results predicted by experimental studies, and possibly implies a genetic link between kimberlite and UML magmas. The occurrence of Ti-rich garnets of similar composition in the Swartruggens orangeite on the Kaapvaal craton in South Africa, as well as in other kimberlites with an orangeitic affinity (e.g. the P-15 kimberlite on the Eastern Dharwar craton in southern India), is inferred to be a reflection of the high Ca- and high Ti-, and the low Al-nature, of the parent magma (i.e. Group II kimberlites).

Some major problems with existing models and terminology associated with kimberlite pipes from a volcanological perspective, and some suggestions

NASA Astrophysics Data System (ADS)

Cas, R. A. F.; Hayman, P.; Pittari, A.; Porritt, L.

2008-06-01

Five significant problems hinder advances in understanding of the volcanology of kimberlites: (1) kimberlite geology is very model driven; (2) a highly genetic terminology drives deposit or facies interpretation; (3) the effects of alteration on preserved depositional textures have been grossly underestimated; (4) the level of understanding of the physical process significance of preserved textures is limited; and, (5) some inferred processes and deposits are not based on actual, modern volcanological processes. These issues need to be addressed in order to advance understanding of kimberlite volcanological pipe forming processes and deposits. The traditional, steep-sided southern African pipe model (Class I) consists of a steep tapering pipe with a deep root zone, a middle diatreme zone and an upper crater zone (if preserved). Each zone is thought to be dominated by distinctive facies, respectively: hypabyssal kimberlite (HK, descriptively called here massive coherent porphyritic kimberlite), tuffisitic kimberlite breccia (TKB, descriptively here called massive, poorly sorted lapilli tuff) and crater zone facies, which include variably bedded pyroclastic kimberlite and resedimented and reworked volcaniclastic kimberlite (RVK). Porphyritic coherent kimberlite may, however, also be emplaced at different levels in the pipe, as later stage intrusions, as well as dykes in the surrounding country rock. The relationship between HK and TKB is not always clear. Sub-terranean fluidisation as an emplacement process is a largely unsubstantiated hypothesis; modern in-vent volcanological processes should initially be considered to explain observed deposits. Crater zone volcaniclastic deposits can occur within the diatreme zone of some pipes, indicating that the pipe was largely empty at the end of the eruption, and subsequently began to fill-in largely through resedimentation and sourcing of pyroclastic deposits from nearby vents. Classes II and III Canadian kimberlite models have a more factual, descriptive basis, but are still inadequately documented given the recency of their discovery. The diversity amongst kimberlite bodies suggests that a three-model classification is an over-simplification. Every kimberlite is altered to varying degrees, which is an intrinsic consequence of the ultrabasic composition of kimberlite and the in-vent context; few preserve original textures. The effects of syn- to post-emplacement alteration on original textures have not been adequately considered to date, and should be back-stripped to identify original textural elements and configurations. Applying sedimentological textural configurations as a guide to emplacement processes would be useful. The traditional terminology has many connotations about spatial position in pipe and of process. Perhaps the traditional terminology can be retained in the industrial situation as a general lithofacies-mining terminological scheme because it is so entrenched. However, for research purposes a more descriptive lithofacies terminology should be adopted to facilitate detailed understanding of deposit characteristics, important variations in these, and the process origins. For example every deposit of TKB is different in componentry, texture, or depositional structure. However, because so many deposits in many different pipes are called TKB, there is an implication that they are all similar and that similar processes were involved, which is far from clear.

The Diamondiferous Lithospheric Mantle Underlying the Eastern Superior Craton: Evidence From Mantle Xenoliths From the Renard Kimberlites, Quebec

NASA Astrophysics Data System (ADS)

Hunt, L.; Stachel, T.; Armstrong, J. P.; Simonetti, A.

2009-05-01

The Renard kimberlite cluster consists of nine pipes located within a 2km2 area in the northern Otish Mountains of Quebec. The pipes are named Renards 1 to 10, with subsequent investigation revealing Renards 5 and 6 to join at depth (now Renard 65). The pipes are located within the eastern portion of the Superior craton, emplaced into Archean granitic and gneissic host rocks of the Opinica Subprovince (Percival, 2007). Amphibolite grade metamorphism, locally passing into the granulite facies (Percival et al., 1994) occurred in late Archean time (Moorhead et al., 2003). Radiometric dating of the hypabyssal Renard 1 kimberlite indicates Neoproterozoic emplacement, with a 206Pb/238U model age of 631.6±3.5 Ma (2σ) (Birkett et al., 2004). A later study on the main phases in Renard 2 and 3 gave a similar emplacement, with a 206Pb/238U model age of 640.5±2.8Ma (Fitzgerald et al., 2008). This makes this kimberlite district one of the oldest in Canada, similar in eruption age to the Wemindji kimberlites (629±29Ma: Letendre et al., 2003). These events are broadly coeval with the conversion from subduction magmatism to rifting in northern Laurentia (Birkett et al., 2004). The bodies are part of a late Neoproterozoic to Cambrian kimberlite field in eastern Canada (Girard, 2001; Moorhead et al, 2002; Letendre et al., 2003) and fit into the north-east of the Eocambrian/Cambrian Labrador Sea Province of Heaman et al. (2004). To better understand the diamondiferous lithospheric mantle beneath the Renard kimberlites, 116 microxenoliths and xenocrysts were analysed. The samples were dominantly peridotitic, composed primarily of purple garnet, emerald green clinopyroxene and olivine, with a few pink and red garnets. A minor eclogitic component comprises predominantly orange garnets and lesser amounts of clinopyroxene. A detailed study on the major, minor and trace element composition of xenolith minerals is currently underway. All but three of the clinopyroxenes analysed to date plot into the on-craton garnet peridotite field of Ramsay (1992), and follow the garnet peridotite trend of Grütter (2008). Using the single pyroxene geothermobarometer of Nimis and Taylor (2000), the clinopyroxene grains fall along a 38mW/m2 model geotherm. However, the majority fall on the low pressure side of the diamond graphite transition. Initial analysis on the garnet grains show that the majority plots in the on craton lherzolite field (G9A) of Grütter et al. (2006). A smaller eclogite population is also present, along with a minor harzburgitic (G10) population. Using the manganese in garnet thermometer of Creighton (2008) the majority of grains fall in the diamond window (T>950°C). This indicates a currently unexplained disconnect between clinopyroxene and garnet geothermobarometry. The newly developed technique of in situ Pb-Pb dating of clinopyroxene xenocrysts (Schmidberger et al. 2007) was applied to the microxenoliths. Initial results indicate an age of ˜2.7 Ga for the subcratonic lithospheric mantle beneath Renard. This date is significant, coinciding with the beginning of the break up of Vaalbara and a major phase of continental crust generation. Also at 2.7 Ga, Kenorland (including the Superior Province) was formed by accretion of granitoid-greenstone terranes at convergent margins (Barley et al., 2005).

Identification of kimberlite bodies in Brazil from a 3D audio-magnetotelluric survey

NASA Astrophysics Data System (ADS)

De Lugao, P. P.; Eric, C. D. O.; Loureiro, F. O.; Arantes, P. R.; Pastana, A. F.

2015-12-01

We report on a succesfull identification of kimberlite bodies in Brazil through the use of the electromagnetic technique audio-magnetotelluric (AMT). Macnae (1979) writes that "In one large survey in South Africa, electromagnetic (EM) techniques have proven to be remarkably effective in detecting the presence of weathered clays or epiclastic kimberlite contained within the pipes." Full tensor AMT data were acquired at 65 points (stations) in a 3D configuration with frequencies ranging from 10kHz to 1Hz. The survey was located in the NW portion of the Mato Grosso state, Brazil, in na area of thick jungle coverage. During the AMT survey, few outcrops were seen because of the dense forest cover. Usually, the occurrences found were of sand deposits, indicating the occurence of Fazenda Casa Branca and Utiariti Formations and gravel from Salto das Nuvens Formation, widely used in paving trails n this region. In the area of the survey, three main targets were confirmed/identified: Kimberlite Area 1 - a classic kimberlite in the region, with the crater facies with different clasts and distinct size. We noted the occurrence of a red-brown soil and an unusual vegetation in this area. The resistivity model provided confirmed the presence of Kimberlite Area 1 and was used to identify other two areas. Area of Interest 1 - area with atypical vegetation along a trail. There is an excavation that displays soil of white color with several blocks present, there are small quartz crystal agglomerates in these blocks. The resistivity model cleary shows a conductive body here, indicative of the presence of a kimberlite. Area of Interest 2 - the presence of a kimberlite was confirmed, not exactly where the targeted Area 2 was, but the southwest of it. Close to this area, there was a very fine rock and a few blocks of pure silica, probably indicating a kimberlitic intrusion. In summary, the 3D resistivity model in depth obtained from inversion of the AMT data confirmed and identified three targets for kimberlites quickly and at a low cost, in na otherwise region of difficult logistics due to the dense jungle cover and remote location.

Volcanology of Tuzo pipe (Gahcho Kué cluster) — Root-diatreme processes re-interpreted

NASA Astrophysics Data System (ADS)

Seghedi, I.; Maicher, D.; Kurszlaukis, S.

2009-11-01

The Middle Cambrian (~ 540 Ma) Gahcho Kué Kimberlite Field is situated about 275 km ENE of Yellowknife, NWT, Canada. The kimberlites were emplaced into 2.6 Ga Archean granitic rocks of the Yellowknife Supergroup. Four larger kimberlite bodies (5034, Tesla, Tuzo, and Hearne) as well as a number of smaller pipes and associated sheets occur in the field. In plan view, the Tuzo pipe has a circular outline at the surface, and it widens towards deeper levels. The pipe infill consists of several types of coherent and fragmental kimberlite facies. Coherent or apparent coherent (possibly welded) kimberlite facies dominate at depth, but also occur at shallow levels, as dikes intruded late in the eruptive sequence or individual coherent kimberlite clasts. The central and shallower portions of the pipe consist of several fragmental kimberlite varieties that are texturally classified as Tuffisitic Kimberlites. The definition, geometry and extent of the geological units are complex and zones controlled by vertical elements are most significant. The fluidal outlines of some of the coherent kimberlite clasts suggest that at least some are the product of disruption of magma that was in a semi-plastic state or even of welded material. Ragged clasts at low levels are inferred to form part of a complex peperite-like system that intrudes the base of the root zone. A variable, often high abundance of local wall-rock xenoliths between and within the kimberlite phases is observed, varying in size from sub-millimeter to several tens of meters. Wall-rock fragments are common at all locations within the pipe but are especially frequent in a domain with a belt-like geometry between 120 and 200 m depth in the pipe. Steeply outward-dipping bedded deposits made up of wall-rock fragments occur in deep levels of the pipe and are especially common under the downward-widening roof segments. The gradational contact relationships of these deposits with the surrounding kimberlite-bearing rocks as well as their location suggest that they formed more-or-less in situ. Different breccia facies inside the pipe suggest an origin by slumping, grain flows, rock fall or pyroclastic deposition. The shape and facies architecture of the Tuzo pipe suggests that the studied section of the pipe lies at a root zone-diatreme transitional structural level. Composite coherent kimberlite clasts imply that recycling processes were active over time, while reworked wall-rock rich deposits and ductily-deformed clasts of welded kimberlite point to the presence of temporary cavities in the root zone. The emplacement of the Tuzo pipe did not occur in a single, violent explosion, but involved repetitive volcanic explosions alternating with periods of relative quiescence. The observed features are typical of phreatomagmatic processes, which may include phases of less-explosive magmatic activity.

Dating kimberlite emplacement with zircon and perovskite (U-Th)/He geochronology

NASA Astrophysics Data System (ADS)

Stanley, Jessica; Flowers, Rebecca

2017-04-01

Kimberlites provide rich information about the composition and evolution of cratonic lithosphere. They can entrain xenoliths and xenocrysts from the entire lithospheric column as they transit rapidly to the surface, providing information on the state of the deep lithosphere as well as any sedimentary units covering the craton at the time of eruption. Accurate geochronology of these eruptions is key for interpreting this information and discerning spatiotemporal trends in lithospheric evolution, but kimberlites can sometimes be difficult to date with available methods. Here we explore whether (U-Th)/He dating of zircon and perovskite can serve as reliable techniques for determining kimberlite emplacement ages by dating a suite of sixteen southern African kimberlites by zircon and/or perovskite (U-Th)/He (ZHe, PHe). Most samples with abundant zircon yielded ZHe dates reproducible to ≤15% dispersion that are in good agreement with published eruption ages, though there were several samples that were more scattered. Since the majority of dated zircon were xenocrystic, zircon with reproducible dates were fully reset during eruption or resided at temperatures above the ZHe closure temperature ( 180 °C) prior to entrainment in the kimberlite magma. We attribute scattered ZHe dates to shallowly sourced zircon that underwent incomplete damage annealing and/or partial He loss during the eruptive process. All seven kimberlites dated with PHe yielded dates reproducible to ≤15% dispersion and reasonable results. As perovskite has not previously been used as a (U-Th)/He chronometer, we conducted two preliminary perovskite 4He diffusion experiments to obtain initial estimates of its temperature sensitivity. These experiments suggest a PHe closure temperature of >300 °C. Perovskite in kimberlites is unlikely to be xenocrystic and its relatively high temperature sensitivity suggests that PHe dates will typically record emplacement rather than post-emplacement processes. ZHe and PHe geochronology can effectively date kimberlite emplacement and provide useful complements to existing techniques.

Composition of primary fluid and melt inclusions in regenerated olivines from hypabyssal kimberlites of the Malokuonapskaya pipe (Yakutia)

NASA Astrophysics Data System (ADS)

Tomilenko, A. A.; Kuzmin, D. V.; Bulbak, T. A.; Timina, T. Yu.; Sobolev, N. V.

2015-11-01

The primary fluid and melt inclusions in regenerated zonal crystals of olivine from kimberlites of the Malokuonapskaya pipe were first examined by means of microthermometry, optic and scanning electron microscopy, and Raman spectroscopy. The high-pressure genesis of homogenous central parts of the olivines was revealed, probably under intense metasomatism at early hypogene stages with subsequent regeneration in the kimberlitic melt. The olivine crystals were regenerated from silicate-carbonate melts at about 1100°C. The composition of the kimberlitic melt was changed by way of an increase in the calcium content.

Kimberlite ascent by assimilation-fuelled buoyancy.

PubMed

Russell, James K; Porritt, Lucy A; Lavallée, Yan; Dingwell, Donald B

2012-01-18

Kimberlite magmas have the deepest origin of all terrestrial magmas and are exclusively associated with cratons. During ascent, they travel through about 150 kilometres of cratonic mantle lithosphere and entrain seemingly prohibitive loads (more than 25 per cent by volume) of mantle-derived xenoliths and xenocrysts (including diamond). Kimberlite magmas also reputedly have higher ascent rates than other xenolith-bearing magmas. Exsolution of dissolved volatiles (carbon dioxide and water) is thought to be essential to provide sufficient buoyancy for the rapid ascent of these dense, crystal-rich magmas. The cause and nature of such exsolution, however, remains elusive and is rarely specified. Here we use a series of high-temperature experiments to demonstrate a mechanism for the spontaneous, efficient and continuous production of this volatile phase. This mechanism requires parental melts of kimberlite to originate as carbonatite-like melts. In transit through the mantle lithosphere, these silica-undersaturated melts assimilate mantle minerals, especially orthopyroxene, driving the melt to more silicic compositions, and causing a marked drop in carbon dioxide solubility. The solubility drop manifests itself immediately in a continuous and vigorous exsolution of a fluid phase, thereby reducing magma density, increasing buoyancy, and driving the rapid and accelerating ascent of the increasingly kimberlitic magma. Our model provides an explanation for continuous ascent of magmas laden with high volumes of dense mantle cargo, an explanation for the chemical diversity of kimberlite, and a connection between kimberlites and cratons.

Hydrothermal alteration of kimberlite by convective flows of external water.

PubMed

Afanasyev, A A; Melnik, O; Porritt, L; Schumacher, J C; Sparks, R S J

Kimberlite volcanism involves the emplacement of olivine-rich volcaniclastic deposits into volcanic vents or pipes. Kimberlite deposits are typically pervasively serpentinised as a result of the reaction of olivine and water within a temperature range of 130-400 °C or less. We present a model for the influx of ground water into hot kimberlite deposits coupled with progressive cooling and serpentisation. Large-pressure gradients cause influx and heating of water within the pipe with horizontal convergent flow in the host rock and along pipe margins, and upward flow within the pipe centre. Complete serpentisation is predicted for wide ranges of permeability of the host rocks and kimberlite deposits. For typical pipe dimensions, cooling times are centuries to a few millennia. Excess volume of serpentine results in filling of pore spaces, eventually inhibiting fluid flow. Fresh olivine is preserved in lithofacies with initial low porosity, and at the base of the pipe where deeper-level host rocks have low permeability, and the pipe is narrower leading to faster cooling. These predictions are consistent with fresh olivine and serpentine distribution in the Diavik A418 kimberlite pipe, (NWT, Canada) and with features of kimberlites of the Yakutian province in Russia affected by influx of ground water brines. Fast reactions and increases in the volume of solid products compared to the reactants result in self-sealing and low water-rock ratios (estimated at <0.2). Such low water-rock ratios result in only small changes in stable isotope compositions; for example, δO 18 is predicted only to change slightly from mantle values. The model supports alteration of kimberlites predominantly by interactions with external non-magmatic fluids.

Kimberlites in western Liberia - An overview of the geological setting in a plate tectonic framework

NASA Astrophysics Data System (ADS)

Haggerty, S. E.

1982-12-01

Evidence which includes Landsat images is presented for prolonged periods of tectonism, marginal to and extending within the intracratonic region of the West African platform. Also found are indications of intermittent, or perhaps even sustained activity, dating back to more than three billion years. The petrology and mineral chemistry of kimberlites, and their associated nodule suites in the present region, are broadly similar to those from kimberlite localities throughout the African continent, and should therefore be considered as part of a major province. Attention is drawn to the lineament control of kimberlites, and the coincidence of these lineaments with the basement fabric and with faults. The proposed interpretation for the distribution of West African kimberlites is in essential agreement with the intraplate and intracratonic model of Dawson (1970) and Sykes (1978), which calls upon the reactivation of paleofaults and sutures during plate tectonism.

Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: Insights from in situ U-Pb and Sr-Nd perovskite isotope analysis

NASA Astrophysics Data System (ADS)

Sun, Jing; Liu, Chuan-Zhou; Tappe, Sebastian; Kostrovitsky, Sergey I.; Wu, Fu-Yuan; Yakovlev, Dmitry; Yang, Yue-Heng; Yang, Jin-Hui

2014-10-01

We report combined U-Pb ages and Sr-Nd isotope compositions of perovskites from 50 kimberlite occurrences, sampled from 9 fields across the Yakutian kimberlite province on the Siberian craton. The new U-Pb ages, together with previously reported geochronological constraints, suggest that kimberlite magmas formed repeatedly during at least 4 episodes: Late Silurian-Early Devonian (419-410 Ma), Late Devonian-Early Carboniferous (376-347 Ma), Late Triassic (231-215 Ma), and Middle/Late Jurassic (171-156 Ma). Recurrent kimberlite melt production beneath the Siberian craton - before and after flood basalt volcanism at 250 Ma - provides a unique opportunity to test existing models for the origin of global kimberlite magmatism. The internally consistent Sr and Nd isotope dataset for perovskites reveals that the Paleozoic and Mesozoic kimberlites of Yakutia have distinctly different initial radiogenic isotope compositions. There exists a notable increase in the initial 143Nd/144Nd ratios through time, with an apparent isotopic evolution that is intermediate between that of Bulk Earth and Depleted MORB Mantle. While the Paleozoic samples range between initial 87Sr/86Sr of 0.7028-0.7034 and 143Nd/144Nd of 0.51229-0.51241, the Mesozoic samples show values between 0.7032-0.7038 and 0.51245-0.51271, respectively. Importantly, perovskites from all studied Yakutian kimberlite fields and age groups have moderately depleted initial εNd values that fall within a relatively narrow range between +1.8 and +5.5. The perovskite isotope systematics of the Yakutian kimberlites are interpreted to reflect magma derivation from the convecting upper mantle, which appears to have a record of continuous melt depletion and crustal recycling throughout the Phanerozoic. The analyzed perovskites neither record highly depleted nor highly enriched isotopic components, which had been previously identified in likely plume-related Siberian Trap basalts. The Siberian craton has frequently been suggested to represent a type example of an association between kimberlite eruptions and flood basaltic volcanism within a single large igneous province (LIP), but our new extensive age and isotopic tracer constraints do not support a genetic link between these contrasting types of mantle-derived magmatism.

Palaeomagnetic Emplacement Temperature Determinations of Pyroclastic and Volcaniclastic Deposits in Southern African Kimberlite Pipes

NASA Astrophysics Data System (ADS)

Fontana, G.; Mac Niocaill, C.; Brown, R.; Sparks, R. S.; Matthew, F.; Gernon, T. M.

2009-12-01

Kimberlites are complex, ultramafic and diamond-bearing volcanic rocks preserved in volcanic pipes, dykes and craters. The formation of kimberlite pipes is a strongly debated issue and two principal theories have been proposed to explain pipe formation: (1) the explosive degassing of magma, and (2) the interaction of rising magma with groundwater (phreatomagmatism). Progressive thermal demagnetization studies are a powerful tool for determining the emplacement temperatures of ancient volcanic deposits and we present the first application of such techniques to kimberlite deposits. Lithic clasts were sampled from a variety of lithofacies, from three pipes for which the internal geology is well constrained (A/K1 pipe, Orapa Mine, Botswana and the K1 and K2 pipes, Venetia Mine, South Africa). The sampled deposits included massive and layered vent-filling breccias with varying abundances of lithic inclusions and layered crater-filling pyroclastic deposits, talus breccias and volcaniclastic breccias. Lithic clasts sampled from layered and massive vent-filling pyroclastic deposits in A/K1 were emplaced at >590° C. Results from K1 and K2 provide a maximum emplacement temperature limit for vent-filling breccias of 420-460° C; and constrain equilibrium deposit temperatures at 300-340° C. Crater-filling volcaniclastic kimberlite breccias and talus deposits from A/K1 were emplaced at ambient temperatures, consistent with infilling of the pipe by post-eruption epiclastic processes. Identified within the epiclastic crater-fill succession is a laterally extensive 15-20 metre thick kimberlite pyroclastic flow deposit emplaced at temperatures of 220-440° C. It overlies the post-eruption epiclastic units and is considered an extraneous pyroclastic kimberlite deposit erupted from another kimberlite vent. The results provide important constraints on kimberlite emplacement mechanisms and eruption dynamics. Emplacement temperatures of >590°C for pipe-filling pyroclastic deposits are consistent with volatile-driven eruptions, and suggest phreatomagmatism did not play a major role in the generation of the deposits. The discovery of an extraneous pyroclastic flow deposit within the Orapa A/K1 epiclastic crater, which was erupted from another vent, suggests kimberlite eruptions are capable of producing sustained eruption columns and thick pyroclastic deposits involving significant transport away from source.

A new approach to reconstructing the composition and evolution of kimberlite melts: A case study of the archetypal Bultfontein kimberlite (Kimberley, South Africa)

NASA Astrophysics Data System (ADS)

Soltys, Ashton; Giuliani, Andrea; Phillips, David

2018-04-01

The compositions of kimberlite melts at depth and upon emplacement in the upper crust remain elusive. This can be attributed to the unquantified effects of multiple processes, such as alteration, assimilation, xenocryst contamination, and fractional crystallisation. The inability to accurately constrain the composition and physical properties of kimberlite melts prevents a comprehensive understanding of their petrogenesis. To improve constraints on the compositions of kimberlite melts, we have combined modal analysis including the discrimination of xenocrystic from magmatic phases, with mineral chemistry determinations to reconstruct a whole-rock composition. We apply this approach to a sample of "fresh" macrocrystic hypabyssal kimberlite (sample BK-1) from the Bultfontein mine (Kimberley, South Africa). The accuracy of this whole-rock reconstruction method is validated by the similarity between reconstructed and measured whole-rock compositions. A series of corrections are then applied to account for the effects of post-emplacement serpentinisation, pre-emplacement olivine crystallisation, and the inclusion and assimilation of mantle material. This approach permits discernment of melt compositions at different stages of kimberlite evolution. The primitive melt parental to the Bultfontein kimberlite is estimated to contain 17.4-19.0 wt% SiO2, 20.2-22.8 wt% MgO, 20.9-21.9 wt% CaO, 2.1-2.3 wt% P2O5, 1.2-1.4 wt% TiO2, 0.9-1.1 wt% Al2O3, and 0.6-0.7 wt% K2O, and has a Mg# of 83.4-84.4. Primary volatile contents (i.e., after an attempt to account for volatile loss) are tentatively estimated at 2.1-2.2 wt% H2O and 22.9-25.4 wt% CO2. This composition is deficient in SiO2, MgO and H2O, but enriched in CaO and CO2 compared with most previous estimates of primitive kimberlite melts. We suggest that the primitive melt parental to the Bultfontein kimberlite was a transitional silicate-carbonate melt, which was progressively enriched in SiO2, MgO, Al2O3, Cr2O3, and Na2O through the assimilation of lithospheric mantle material. Comparisons with experimentally produced low-degree melts of carbonated lherzolite indicate that the Bultfontein kimberlite could have formed by 0.5% melting of asthenospheric mantle at 6.0-8.6 GPa (i.e., 190-285 km) and 1400-1500 °C. The low calculated Na2O contents (<0.2 wt%), which are inconsistent with derivation from low-degree melting of lherzolite, suggest that an alkali-bearing, volatile-rich fluid was exsolved during ascent or released after emplacement, and subsequently removed.

Temperature and pressure dependences of kimberlite melts viscosity (experimental-theoretical study)

NASA Astrophysics Data System (ADS)

Persikov, Eduard; Bykhtiyarov, Pavel; Cokol, Alexsander

2016-04-01

Experimental data on temperature and pressure dependences of viscosity of model kimberlite melts (silicate 82 + carbonate 18, wt. %, 100NBO/T = 313) have been obtained for the first time at 100 MPa of CO2 pressure and at the lithostatic pressures up to 7.5 GPa in the temperature range 1350 oC - 1950 oC using radiation high gas pressure apparatus and press free split-sphere multi - anvil apparatus (BARS). Experimental data obtained on temperature and pressure dependences of viscosity of model kimberlite melts at moderate and high pressures is compared with predicted data on these dependences of viscosity of basaltic melts (100NBO/T = 58) in the same T, P - range. Dependences of the viscosity of model kimberlite and basaltic melts on temperature are consistent to the exponential Arrenian equation in the T, P - range of experimental study. The correct values of activation energies of viscous flow of kimberlite melts have been obtained for the first time. The activation energies of viscous flow of model kimberlite melts exponentially increase with increasing pressure and are equal: E = 130 ± 1.3 kJ/mole at moderate pressure (P = 100 MPa) and E = 160 ± 1.6 kJ/mole at high pressure (P = 5.5 GPa). It has been established too that the viscosity of model kimberlite melts exponentially increases on about half order of magnitude with increasing pressures from 100 MPa to 7.5 GPa at the isothermal condition (1800 oC). It has been established that viscosity of model kimberlite melts at the moderate pressure (100 MPa) is lover on about one order of magnitude to compare with the viscosity of basaltic melts, but at high pressure range (5.5 - 7.5 GPa), on the contrary, is higher on about half order of magnitude at the same values of the temperatures. Here we use both a new experimental data on viscosity of kimberlite melts and our structural chemical model for calculation and prediction the viscosity of magmatic melts [1] to determine the fundamental features of viscosity of kimberlite and basaltic magmas at the T, P - parameters of the Earth's crust and upper mantle. The Russian Foundation for Basic Research (project 15-05-01318) and the Russian Science Foundation (project 14-27-00054) are acknowledged for the financial support. [1] Persikov, E.S. & Bukhtiyarov, P.G. (2009) Russian Geology & Geophysics, 50, No 12, 1079-1090.

Kimberlite-related metasomatism recorded in MARID and PIC mantle xenoliths

NASA Astrophysics Data System (ADS)

Fitzpayne, Angus; Giuliani, Andrea; Phillips, David; Hergt, Janet; Woodhead, Jon D.; Farquhar, James; Fiorentini, Marco L.; Drysdale, Russell N.; Wu, Nanping

2018-05-01

MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) and PIC (Phlogopite-Ilmenite-Clinopyroxene) xenoliths are thought to be formed by intense "primary" mantle metasomatism. These rocks also display secondary features, such as cross-cutting veins and geochemical zonation of matrix minerals, which probably reflect later metasomatic events. To investigate the nature and origin(s) of these secondary features, 28 MARID and PIC xenoliths from southern African kimberlites and orangeites have been studied. MARID-hosted veins contain both carbonate and Ti-rich phases (e.g., titanite, phlogopite), suggesting that they formed by the infiltration of a carbonated silicate melt. Elevated TiO2 contents in MARID matrix mineral rims are spatially associated with carbonate-dominated veins, suggesting a genetic relationship between vein formation and geochemical zonation. Spongy rims around primary MARID and PIC clinopyroxene are depleted in Na2O and Al2O3 relative to their cores, possibly reflecting mineral dissolution in the xenoliths during ascent and emplacement of the entraining kimberlite. The preservation of compositional differences between primary and secondary phases in MARID and PIC xenoliths indicates that metasomatism occurred shortly before, or broadly coeval with, kimberlite/orangeite magmatism; otherwise, at typical mantle temperatures, such features would have quickly re-equilibrated. Increased Na2O in some mineral rims (e.g., K-richterite) may therefore reflect equilibration with a more Na-enriched primitive kimberlite melt composition than is commonly suggested. Vein-hosted clinopyroxene 87Sr/86Sri (0.70539 ± 0.00079) in one MARID sample is intermediate between primary clinopyroxene in the sample (0.70814 ± 0.00002) and the host Bultfontein kimberlite (0.70432 ± 0.00005), suggesting that vein minerals are derived from interactions between primary MARID phases and kimberlite-related melts/fluids. Sulfur isotope compositions of barite (δ34SVCDT = +4.69 ‰) and sulfides (δ34SVCDT = -0.69 ‰) in carbonate veins reflect equilibration at temperatures of 850-900 °C, consistent with sulfur-rich melt/fluid infiltration in the lithospheric mantle. In contrast, vein carbonate C-O isotope systematics (δ13CVPDB = -9.18 ‰; δ18OVSMOW = +17.22 ‰) are not typical of kimberlites or other mantle carbonates (δ13CVPDB = -3 to -8 ‰; δ18OVSMOW = 6 to 9 ‰), and may represent post-emplacement hydrothermal interactions of the cooling kimberlite with crustal fluids. These constraints suggest protracted metasomatism of MARID rocks shortly before and during entrainment by the host kimberlite.

Redox state of earth's upper mantle from kimberlitic ilmenites

NASA Technical Reports Server (NTRS)

Haggerty, S. E.; Tompkins, L. A.

1983-01-01

Temperatures and oxygen fugacities are reported on discrete ilmenite nodules in kimberlites from West Africa which demonstrate that the source region in the upper mantle is moderately oxidized, consistent with other nodule suites in kimberlites from southern Africa and the United States. A model is presented for a variety of tectonic settings, proposing that the upper mantle is profiled in redox potential, oxidized in the fertile asthenosphere but reduced in the depleted lithosphere.

Dating Kimberlite Eruption and Erosion Phases Using Perovskite, Zircon, and Apatite (U-Th)/He Geochronology to Link Cratonic Lithosphere Evolution and Surface Processes

NASA Astrophysics Data System (ADS)

Stanley, J. R.; Flowers, R. M.

2015-12-01

In many cases it is difficult to evaluate the synchronicity and thus potential connections between disparate geologic events, such as the links between processes in the mantle lithosphere and at the surface. Developing new geochronologic tools and strategies for integrating existing chronologic data with other information is essential for addressing these problems. Here we use (U-Th)/He dating of multiple kimberlitic minerals to date kimberlite eruption and cratonic erosion phases. This approach permits us to more directly assess the link between unroofing and thermomodification of the lithosphere by tying our results to information obtained from mantle-derived clasts in the same pipes. Kimberlites are rich sources of information about the composition of the cratonic lithosphere and its evolution over time. Their xenoliths and xenocrysts can preserve a snapshot of the entire lithosphere and its sedimentary cover at the time of eruption. Accurate geochronology of these eruptions is crucial for interpreting spatiotemporal trends, but kimberlites can be difficult to date using standard techniques. Here we show that the mid-temperature thermochonometers of the zircon and perovskite (U-Th)/He (ZHe, PHe) systems can be viable tools for dating kimberlite eruption. When combined with the low temperature sensitivity of (U-Th)/He in apatite (AHe), the (U-Th)/He system can be used to date both the emplacement and the erosional cooling history of kimberlites. The southern African shield is an ideal location to test the utility of this approach because the region was repeatedly intruded by kimberlites in the Cretaceous, with two major pulses at ~200-110 Ma and ~100-80 Ma. These kimberlites contain a well-studied suite of mantle xenoliths and xenocrysts that document lithospheric heating and metasomatism over this interval. Our ZHe and PHe dates overlap with published eruption ages and add new ages for undated pipes. Our AHe dates constrain the spatial patterns of Cretaceous erosion across the craton, with a phase of erosion that overlaps with when the lithosphere was thermochemically modified, especially in the more heavily altered off-craton regions. These results highlight the value of the (U-Th)/He system for dating a range of geologic events and evaluating elusive links between surface and deeper-earth processes.

Carbonate-silicate liquid immiscibility in the mantle propels kimberlite magma ascent

NASA Astrophysics Data System (ADS)

Kamenetsky, Vadim S.; Yaxley, Gregory M.

2015-06-01

Kimberlite is a rare volcanic rock renowned as the major host of diamonds and originated at the base of the subcontinental lithospheric mantle. Although kimberlite magmas are dense in crystals and deeply-derived rock fragments, they ascend to the surface extremely rapidly, enabling diamonds to survive. The unique physical properties of kimberlite magmas depend on the specific compositions of their parental melts that, in absence of historical eruptions and due to pervasive alteration of kimberlite rocks, remain highly debatable. We explain exceptionally rapid ascent of kimberlite magma from mantle depths by combining empirical data on the essentially carbonatite composition of the kimberlite primary melts and experimental evidence on interaction of the carbonate liquids with mantle minerals. Our experimental study shows that orthopyroxene is completely dissolved in a Na2CO3 melt at 2.0-5.0 GPa and 1000-1200 °C. The dissolution of orthopyroxene results in homogeneous silicate-carbonate melt at 5.0 GPa and 1200 °C, and is followed by unmixing of carbonate and carbonated silicate melts and formation of stable magmatic emulsion at lower pressures and temperatures. The dispersed silicate melt has a significant capacity for storing a carbonate component in the deep mantle (13 wt% CO2 at 2.0 GPa). We envisage that this component reaches saturation and is gradually released as CO2 bubbles, as the silicate melt globules are transported upwards through the lithosphere by the carbonatite magma. The globules of unmixed, CO2-rich silicate melt are continuously produced upon further reaction between the natrocarbonatite melt and mantle peridotite. On decompression the dispersed silicate melt phase ensures a continuous supply of CO2 bubbles that decrease density and increase buoyancy and promote rapid ascent of the magmatic emulsion.

Crystal-Chemical Correlations in Chromites from Kimberlitic and Non-Kimberlitic Sources.

NASA Astrophysics Data System (ADS)

Freckelton, C. N.; Flemming, R. L.

2009-05-01

This study explores the utility of micro X-ray diffraction (μXRD) as a tool for diamond exploration, as a compliment to current industry-standard techniques such as electron probe microanalysis (EPMA). Here we examine chromite. As one of the first phases to crystallize in mantle rocks, it is a useful indicator of upper mantle magmatic conditions in rocks that have been sampled by kimberlites. In addition, chromite does not alter easily from chemical and physical weathering processes. As such, chromite is a useful kimberlite indicator mineral in diamond exploration. We present correlations between crystal structure (unit cell) and chemical composition of chromite, (Fe,Mg)[Cr, Al]2O4, using correlated μXRD and EPMA data for 133 chromites from a three source locations: Two kimberlite sources and one non-kimberlitic source from an Archean granite/greenstone terrain. Quantitative analysis was performed using Electron Probe Microanalysis (EPMA) at Mineral Services, South Africa, prior to the loan of the samples. Randomly-oriented chromite grains, approximately 500 μm in diameter, were analyzed as previously mounted for EPMA. Micro X-ray-diffraction was performed using a Bruker D8-Discover Diffractometer, with θ-θ geometry, with CuKα radiation, operating at 40 kV and 40 mA, with nominal beam diameter of 500 μm. The data were collected in omega scan mode. Two dimensional General Area Detector Diffraction System (GADDS) images were collected for 20 minutes per image, and integrated to produce one-dimensional plots of intensity versus 2θ, for subsequent unit cell refinement using CELREF. Although all samples in this study were considered to be 'chromite', a plot of Cr/(Cr+Al) versus Fe2+/(Fe2++Mg) shows extensive substitution among four dominant members: chromite (FeCr2O4), magnesio-chromite (MgCr2O4), spinel (MgAl2O4), and hercynite (FeAl2O4), where Mg and Fe2+ substitute for one another on the tetrahedral site, and Cr and Al substitute for one another on the octahedral site. Our data are widely variable as compared to the field occupied by chromite inclusions in diamonds (high Cr and Mg (˜60 wt %) and very low Ti (˜0.40 wt %). Plots of the unit cell parameter, ao, versus composition demonstrate a decrease in unit cell size with increasing Al content (and corresponding decrease in Cr content), consistent with a smaller cation radius for Al versus Cr (Al=0.675 Å and Cr=0.905 Å). The trend in unit cell size is unlikely to be effected by Mg-Fe substitution because of the very small difference in their tetrahedral cation radii (Fe2+=0.835 Å and Mg=0.86 Å). Initial plots of composition versus unit cell parameter were clearly able to distinguish a difference between unit cell of kimberlitic chromites and non-kimberlitic chromites. The significantly higher Cr content in kimberlitic chromites (radius=0.905 Å), and correspondingly higher Al content in non-kimberlitic chromites (radius=0.675 Å), results in a striking bimodal distribution in unit cell parameter, ao, where kimberlitic chromites have a larger unit cell (> 8.3 Å) than non-kimberlitic chromites (< 8.3 Å). This preliminary data provides a useful starting point for screening minerals from naturally relevant chromite solid solutions using their corresponding unit cell parameters. Future work will examine which site substitutions (octahedral versus tetrahedral) are affecting the unit cell as well as the effect of cation order-disorder on unit cell parameters.

Invasion of Hydrous Fluids Predates Kimberlite Formation

NASA Astrophysics Data System (ADS)

Kopylova, M. G.; Wang, Q.; Smith, E. M.

2017-12-01

Petrological observations on diamonds and peridotite xenoliths in kimberlites point towards an influx of hydrous metasomatic fluids shortly predating kimberlite formation. Diamonds may grow at different times within the same segment of the cratonic mantle, and diamonds that form shortly before (<5-7 My) the kimberlite entrainment host the more hydrous fluid inclusions. Younger fibrous diamonds typically contain 10-25 wt.% water in fluid inclusions, while older octahedrally-grown diamonds host "dry" N2-CO2 fluids. Our recent studies of fluids in diamond now show that many different kinds of diamonds can contain fluid inclusions. Specifically, we found a new way to observe and analyze fluids in octahedrally-grown, non-fibrous diamonds by examining healed fractures. This is a new textural context for fluid inclusions that reveals a valuable physical record of infiltrating mantle fluids, that postdate diamond growth, but equilibrate within the diamond stability field at depths beyond 150 km. Another sign of the aqueous fluids influx is the formation of distinct peridotite textures shortly predating the kimberlite. Kimberlites entrain peridotite xenoliths with several types of textures: older coarse metamorphic textures and younger, sheared textures. The preserved contrast in grain sizes between porphyroclasts and neoblasts in sheared peridotites constrain the maximum duration of annealing. Experimental estimates of the annealing time vary from 7x107 sec (2 years) to 106 years (1 My) depending on olivine hydration, strain rate, pressure, temperature and, ultimately, the annealing mechanism. Kimberlite sampling of sheared peridotites from the lithosphere- asthenosphere boundary (LAB) implies their formation no earlier than 1 My prior to the kimberlite ascent. Water contents of olivine measured by FTIR spectrometry using polarized light demonstrated contrasting hydration of coarse and sheared samples. Olivine from sheared peridotite samples has the average water content of 78±3 ppm, in contrast to the less hydrated coarse peridotites (33±6 ppm). LAB hydration results in the lower viscosity of the mantle (1-4 orders of magnitude) translating into 10-104- fold increase in strain rate if stress, its duration, pressure, temperature and the deformation mechanism are assumed constant.

Geothermobarometry for ultramafic assemblages from the Emeishan Large Igneous Province, Southwest China and the Nikos and Zulu Kimberlites, Nunavut, Canada

NASA Astrophysics Data System (ADS)

Zhao, D.

2009-05-01

To understand and contrast the origins of ultramafic assemblages from basaltic and kimberlitic rocks and their associated deposits, such as V-Ti magnetite and Ni-Cu-(PGE) sulfide deposits and diamond, applicable thermobarometers were evaluated and applied to the ultramafic assemblages from the Emeishan Large Igneous Province (ELIP), Southwest China and from the Nikos and Zulu Kimberlites of Nunavut, Canada. The ELIP is located in the Yangtze Block, Southwest China and composed of Permian Emeishan Flood basalt (EFB) and associated layered mafic-ultramafic intrusions. Some of these intrusions host V-Ti magnetite deposits; while others contain Ni-Cu-(PGE) sulfide deposits. It is not clear why some intrusions host magnetite deposits and others contain sulfide deposits. The P-T conditions for the ultramafic assemblages from the mafic-ultramafic intrusions in the ELIP were calculated in order to understand the origins and the associated mineral deposits. The ultramafic assemblages are peridotite, olivine pyroxenite, pyroxenite in the layered intrusions and the common minerals include spinel, olivine, clinopyroxene, orthopyroxene, and minor magnetite and ilmenite. Using a two pyroxene thermometer and a Ca-Mg exchange barometer between olivine and clinopyroxene, a spinel-olivine-clinopyroxene-orthopyroxene assemblage from the Xinjie intrusion yields a T-P of 905°C and 17 kbar; and a similar assemblage from the Jinbaoshan intrusion yields a T-P of 1124°C and 31 kbar. The Nikos kimberlite, near Elwin Bay on Somerset Island, is located at the northeast end of the northeast-southwest kimberlite zone; and the Zulu kimberlite is located on the neighboring Brodeur Peninsula of Baffin Island, Nunavut. The ultramafic assemblages from the Canadian Kimberlites include garnet lherzolite, garnet-spinel lherzolite, spinel lherzolite, dunite, garnet websterite, spinel websterite and garnet clinopyroxenite. The calculated P-T conditions are in the range of 760 to 1180°C and 25 to 60 kbar, follow a continental geotherm, and overlap the stability field of diamond. The ultramafic assemblages from the ELIP, Southwest China and from the Canadian Kimberlites were sampled from different depths in the lithosphere.

Attrition in the kimberlite system

NASA Astrophysics Data System (ADS)

Jones, Thomas J.; Russell, James K.

2018-05-01

The sustained transportation of particles in a suspension commonly results in particle attrition leading to grain size reduction and shape modification. Particle attrition is a well-studied phenomenon that has mainly focussed on sediments produced in aeolian or fluvial environments. Here, we present analogue experiments designed to explore processes of attrition in the kimberlite system; we focus on olivine as it is the most abundant constituent of kimberlite. The attrition experiments on olivine use separate experimental set-ups to approximate two natural environments relevant to kimberlites. Tumbling mill experiments feature a low energy system supporting near continual particle-particle contact and are relevant to re-sedimentation and dispersal processes. Experiments performed in a fluidized particle bed constitute a substantially higher energy environment pertinent to kimberlite ascent and eruption. The run-products of each experiment are analysed for grain size reduction and shape modification and these data are used to elucidate the rates and extents of olivine attrition as a function of time and energy. Lastly, we model the two experimental datasets with an empirical rate equation that describes the production of daughter products (fines) with time. Both datasets approach a fines production limit, or plateau, at long particle residence times; the fluidized system is much more efficient producing a substantially higher fines content and reaches the plateau faster. Our experimental results and models provide a way to forensically examine a wide range of processes relevant to kimberlite on the basis of olivine size and shape properties.

Modified ion exchange separation for tungsten isotopic measurements from kimberlite samples using multi-collector inductively coupled plasma mass spectrometry.

PubMed

Sahoo, Yu Vin; Nakai, Shun'ichi; Ali, Arshad

2006-03-01

Tungsten isotope composition of a sample of deep-seated rock can record the influence of core-mantle interaction of the parent magma. Samples of kimberlite, which is known as a carrier of diamond, from the deep mantle might exhibit effects of core-mantle interaction. Although tungsten isotope anomaly was reported for kimberlites from South Africa, a subsequent investigation did not verify the anomaly. The magnesium-rich and calcium-rich chemical composition of kimberlite might engender difficulty during chemical separation of tungsten for isotope analyses. This paper presents a simple, one-step anion exchange technique for precise and accurate determination of tungsten isotopes in kimberlites using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). Large quantities of Ca and Mg in kimberlite samples were precipitated and removed with aqueous H(2)SO(4). Highly pure fractions of tungsten for isotopic measurements were obtained following an anion exchange chromatographic procedure involving mixed acids. That procedure enabled efficient removal of high field strength elements (HFSE), such as Hf, Zr and Ti, which are small ions that carry strong charges and develop intense electrostatic fields. The tungsten yields were 85%-95%. Advantages of this system include less time and less use of reagents. Precise and accurate isotopic measurements are possible using fractions of tungsten that are obtained using this method. The accuracy and precision of these measurements were confirmed using various silicate standard rock samples, JB-2, JB-3 and AGV-1.

Chasing the Late Jurassic APW Monster Shift in Ontario Kimberlites

NASA Astrophysics Data System (ADS)

Kent, D. V.; Muttoni, G.; Gee, J. S.; Kjarsgaard, B. A.

2012-12-01

A 30° gap was recognized in a composite APW path when global poles from predominantly igneous rocks were assembled in North American coordinates using plate reconstructions (Kent & Irving 2010 JGR). The 'monster shift' occurred between a 160-190 Ma cluster of mean poles at 75-80°N 90-110°E to a 140-145 Ma grouping centered at 60-65°N ~200°E. There are hardly any intermediate igneous poles whereas the rather divergent directions from the Late Jurassic Morrison Formation published by Steiner & Helsley (1975 GSA Bulletin) are subject to adjustments for Colorado Plateau rotation and sedimentary inclination error, neither of which are precisely known for this redbed unit sampled in Colorado. On the other hand, similar large rapid swings have been recognized in the Late Jurassic APW path for Adria (Channell et al. 2010 Paleo3), suggesting a global phenomena. In an effort to fill the data gap between ~145 and 160 Ma, we sampled accessible outcrops/subcrops of kimberlites in the Timiskaming area of Ontario, Canada, that are associated with high precision U-Pb perovskite ages (Heamon & Kjarsgaard 2000 EPSL). We report initial results from two of the intrusions: the 153.6±2.4 Ma Peddie kimberlite from outcrop and the Triple B kimberlite that was accessible by trenching and is assumed to be the same age as the nearby 153.7±1.8 Ma Seed kimberlite as delineated by aeromagnetic surveys and borings. Systematic progressive thermal demagnetization indicated in each unit a dominant characteristic component with unblocking temperatures to 575° that presumably reflect a magnetite carrier that will be checked by further rock magnetic experiments. Samples from the Peddie kimberlite had stable downward (normal polarity) magnetizations whose mean direction gives a paleopole at 73°N 184°E. In contrast, samples from the Triple B kimberlite have upward (reverse polarity) magnetizations with a well-grouped direction whose (north) paleopole is 78°N 197°E, proximal to the Peddie pole. The normal and reverse polarities suggest that sufficient time elapsed between emplacement of the Triple B and Peddie to give an opportunity to average secular variation. The combined ~154 Ma Triple B and Peddie pole encouragingly lies about halfway between igneous poles from North America nearest in age: the 169 Ma Moat volcanics and the 142 Ma Ithaca kimberlites. However, preliminary paleomagnetic results from some of the other sampled kimberlite bodies are more problematical and require further paleomagnetic and geochronological work.

Provenance history of detrital diamond deposits, West Coast of Namaqualand, South Africa

NASA Astrophysics Data System (ADS)

Phillips, David; Harris, Jeffrey W.; de Wit, Michiel C. J.; Matchan, Erin L.

2018-05-01

The West Coast of Namaqualand in South Africa hosts extensive detrital diamond deposits, but considerable debate exists as to the provenance of these diamonds. Some researchers have suggested derivation of the diamonds from Cretaceous-Jurassic kimberlites (also termed Group I kimberlites) and orangeites (also termed Group II kimberlites) located on the Kaapvaal Craton. However, others favour erosion of diamonds from the ca.300 Ma Dwyka Group sediments, with older, pre-Karoo kimberlites being the original source(s). Previous work has demonstrated that 40Ar/39Ar analyses of clinopyroxene inclusions, extracted from diamonds, yield ages approaching the time(s) of source kimberlite emplacement, which can be used to constrain the provenance of placer diamond deposits. In the current study, 40Ar/39Ar analyses were conducted on clinopyroxene inclusions from two similar batches of Namaqualand detrital diamonds, yielding (maximum) ages ranging from 117.5 ± 43.6 Ma to 3684 ± 191 Ma (2σ) and 120.6 ± 15.4 Ma to 688.8 ± 4.9 Ma (2σ), respectively. The vast majority of inclusions (88%) produced ages younger than 500 Ma, indicating that most Namaqualand diamonds originated from Cretaceous-Jurassic kimberlites/orangeites, with few, if any, derived from the Dwyka tillites. The provenance of the Namaqualand diamonds from ca.115-200 Ma orangeites is consistent with Late Cretaceous paleo-drainage reconstructions, as these localities could have been sampled by the `paleo-Karoo' River and transported to the West Coast via an outlet close to the current Olifants River mouth. At ca.90 Ma, this drainage system appears to have been captured by the `paleo-Kalahari' River, a precursor to the modern Orange River system. This latter drainage is considered to have transported diamonds eroded from both ca.80-90 Ma kimberlites and ca.115-200 Ma orangeites to the West Coast, which were subsequently reworked along the Namibian coast, forming additional placer deposits.

Pristine Early Eocene wood buried deeply in kimberlite from northern Canada.

PubMed

Wolfe, Alexander P; Csank, Adam Z; Reyes, Alberto V; McKellar, Ryan C; Tappert, Ralf; Muehlenbachs, Karlis

2012-01-01

We report exceptional preservation of fossil wood buried deeply in a kimberlite pipe that intruded northwestern Canada's Slave Province 53.3±0.6 million years ago (Ma), revealed during excavation of diamond source rock. The wood originated from forest surrounding the eruption zone and collapsed into the diatreme before resettling in volcaniclastic kimberlite to depths >300 m, where it was mummified in a sterile environment. Anatomy of the unpermineralized wood permits conclusive identification to the genus Metasequoia (Cupressaceae). The wood yields genuine cellulose and occluded amber, both of which have been characterized spectroscopically and isotopically. From cellulose δ(18)O and δ(2)H measurements, we infer that Early Eocene paleoclimates in the western Canadian subarctic were 12-17°C warmer and four times wetter than present. Canadian kimberlites offer Lagerstätte-quality preservation of wood from a region with limited alternate sources of paleobotanical information.

Pristine Early Eocene Wood Buried Deeply in Kimberlite from Northern Canada

PubMed Central

Wolfe, Alexander P.; Csank, Adam Z.; Reyes, Alberto V.; McKellar, Ryan C.; Tappert, Ralf; Muehlenbachs, Karlis

2012-01-01

We report exceptional preservation of fossil wood buried deeply in a kimberlite pipe that intruded northwestern Canada’s Slave Province 53.3±0.6 million years ago (Ma), revealed during excavation of diamond source rock. The wood originated from forest surrounding the eruption zone and collapsed into the diatreme before resettling in volcaniclastic kimberlite to depths >300 m, where it was mummified in a sterile environment. Anatomy of the unpermineralized wood permits conclusive identification to the genus Metasequoia (Cupressaceae). The wood yields genuine cellulose and occluded amber, both of which have been characterized spectroscopically and isotopically. From cellulose δ18O and δ2H measurements, we infer that Early Eocene paleoclimates in the western Canadian subarctic were 12–17°C warmer and four times wetter than present. Canadian kimberlites offer Lagerstätte-quality preservation of wood from a region with limited alternate sources of paleobotanical information. PMID:23029080

Absolute age Determinations on Diamond by Radioisotopic Methods: NOT the way to Accurately Identify Diamond Provenance

NASA Astrophysics Data System (ADS)

Shirey, S. B.

2002-05-01

Gem-quality diamond contains such low abundances of parent-daughter radionuclides that dating the diamond lattice directly by isotopic measurements has been and will be impossible. Absolute ages on diamonds typically are obtained through measurements of their syngenetic mineral inclusions: Rb-Sr in garnet; Sm-Nd in garnet and pyroxene; Re-Os and U-Th-Pb in sulfide; K-Ar in pyroxene; and U-Pb in zircon. The application of the first two isotope schemes in the list requires putting together many inclusions from many diamonds whereas the latter isotope schemes permit ages on single diamonds. The key limitations on the application of these decay pairs are the availability and size of the inclusions, the abundance levels of the radionuclides, and instrumental sensitivity. Practical complications of radioisotope dating of inclusions are fatal to the application of the technique for diamond provenance. In all mines, the ratio of gem-quality diamonds to stones with datable inclusions is very high. Thus there is no way to date the valuable, marketable stones that are part of the conflict diamond problem, just their rare, flawed cousins. Each analysis destroys the diamond host plus the inclusion and can only be carried out in research labs by highly trained scientists. Thus, these methods can not be automated or applied to the bulk of diamond production. The geological problems with age dating are equally fatal to its application to diamond provenance. From the geological perspective, for age determination to work as a tool for diamond provenance studies, diamond ages would have to be specific to particular kimberlites or kimberlite fields and different between fields. The southern African Kaapvaal-Zimbabwe Craton and Limpopo Mobile Belt is the only cratonic region where age determinations have been applied on a large enough scale to a number of kimberlites to illustrate the geological problems in age measurements for diamond provenance. However, this southern African example is seen as typical of other cratons. Here, the nearly universal occurrence of Archean or Proterozoic diamonds in much younger (often Cretaceous) kimberlites proves that diamonds are xenocrysts inherited from the ancient mantle lithospheric keel by the host kimberlite as it erupts. Differences in diamond ages are on the scale of the geological assembly of the mantle lithospheric keel and relate to geological terranes in the lithosphere; they have little to do with individual kimberlites. In southern Africa, two age groupings of diamonds exist: Archean (3.2 to 2.9 Ga) diamonds associated with initial creation/final stabilization of the mantle lithosphere and Proterozoic (1 to 2 Ga) diamonds associated with compositional changes to the mantle keel from magmatism and metasomatism. The distribution of these two age types is cratonwide, encompasses many kimberlites and both age groupings can occur in an individual kimberlite. One expects a recurrence of similar ages with a possible 2 Ga age spread from many different kimberlites across the craton. Similar old ages are seen on other cratons (e.g. Siberian, Slave); thus age can not even distinguish diamond source at the scale of a craton. A further complication is that both sampling of diamonds from their lithospheric host and the resting position of diamonds at the final solidification level of the kimberlite in the crust are accidental. This can produce significant variability in the diamond population which is further complicated if erosion and deposition of the diamonds to form alluvial deposits has obscured their host kimberlite.

Geochemical typification of kimberlite and related rocks of the North Anabar region, Yakutia

NASA Astrophysics Data System (ADS)

Kargin, A. V.; Golubeva, Yu. Yu.

2017-11-01

The results of geochemical typification of kimberlites and related rocks (alneites and carbonatites) of the North Anabar region are presented with consideration of the geochemical specification of their source and estimation of their potential for diamonds. The content of representative trace elements indicates the predominant contribution of an asthenospheric component (kimberlites and carbonatites) in their source, with a subordinate contribution of vein metasomatic formations containing Cr-diopside and ilmenite. A significant contribution of water-bearing potassium metasomatic parageneses is not recognized. According to the complex of geochemical data, the studied rocks are not industrially diamondiferous.

Reconstruction of a kimberlite eruption, using an integrated volcanological, geochemical and numerical approach: A case study of the Fox Kimberlite, NWT, Canada

NASA Astrophysics Data System (ADS)

Porritt, L. A.; Cas, R. A. F.

2009-01-01

An integrated approach involving volcanology, geochemistry and numerical modelling has enabled the reconstruction of the volcanic history of the Fox kimberlite pipe. The observed deposits within the vent include a basal massive, poorly sorted, matrix supported, lithic fragment rich, eruption column collapse lapilli tuff. Extensive vent widening during the climactic magmatic phase of the eruption led to overloading of the eruption column with cold dense country rock lithic fragments, dense juvenile pyroclasts and olivine crystals, triggering column collapse. > 40% dilution of the kimberlite by granodiorite country rock lithic fragments is observed both in the physical componentry of the rocks and in the geochemical signature, where enrichment in Al 2O 3 and Na 2O compared to average values for coherent kimberlite is seen. The wide, deep, open vent provided a trap for a significant proportion of the collapsing column material, preventing large scale run-away in the form of pyroclastic flow onto the ground surface, although minor flows probably also occurred. A massive to diffusely bedded, poorly sorted, matrix supported, accretionary-lapilli bearing, lithic fragment rich, lapilli tuff overlies the column collapse deposit providing evidence for a late phreatomagmatic eruption stage, caused by the explosive interaction of external water with residual magma. Correlation of pipe morphology and internal stratigraphy indicate that widening of the pipe occurred during this latter stage and a thick granodiorite cobble-boulder breccia was deposited. Ash- and accretionary lapilli-rich tephra, deposited on the crater rim during the late phreatomagmatic stage, was subsequently resedimented into the vent. Incompatible elements such as Nb are used as indicators of the proportion of the melt fraction, or kimberlite ash, retained or removed by eruptive processes. When compared to average coherent kimberlite the ash-rich deposits exhibit ~ 30% loss of fines whereas the column collapse deposit exhibits ~ 50% loss. This shows that despite the poorly sorted nature of the column collapse deposit significant elutriation has occurred during the eruption, indicating the existence of a high sustained eruption column. The deposits within Fox record a complex eruption sequence showing a transition from a probable violent sub-plinian style eruption, driven by instantaneous exsolution of magmatic volatiles, to a late phreatomagmatic eruption phase. Mass eruption rate and duration of the sub-plinian phase of the eruption have been determined based on the dimensions of milled country-rock boulders found within the intra-vent deposits. Calculations show a short lived eruption of one to eleven days for the sub-plinian magmatic phase, which is similar in duration to small volume basaltic eruptions. This is in general agreement with durations of kimberlite eruptions calculated using entirely different approaches and parameters, such as predictions of magma ascent rates in kimberlite dykes.

Conodont geothermometry in pyroclastic kimberlite: constraints on emplacement temperatures and cooling histories

NASA Astrophysics Data System (ADS)

Pell, Jennifer; Russell, James K.; Zhang, Shunxin

2018-03-01

Kimberlite pipes from Chidliak, Baffin Island, Nunavut, Canada host surface-derived Paleozoic carbonate xenoliths containing conodonts. Conodonts are phosphatic marine microfossils that experience progressive, cumulative and irreversible colour changes upon heating that are experimentally calibrated as a conodont colour alteration index (CAI). CAI values permit us to estimate the temperatures to which conodont-bearing rocks have been heated. Conodonts have been recovered from 118 samples from 89 carbonate xenoliths collected from 12 of the pipes and CAI values within individual carbonate xenoliths show four types of CAI distributions: (1) CAI values that are uniform throughout the xenolith; (2) lower CAIs in core of a xenolith than the rim; (3) CAIs that increase from one side of the xenolith to the other; and, (4) in one xenolith, higher CAIs in the xenolith core than at the rim. We have used thermal models for post-emplacement conductive cooling of kimberlite pipes and synchronous heating of conodont-bearing xenoliths to establish the temperature-time history of individual xenoliths within the kimberlite bodies. Model results suggest that the time-spans for xenoliths to reach the peak temperatures recorded by CAIs varies from hours for the smallest xenoliths to 2 or 3 years for the largest xenoliths. The thermal modelling shows the first three CAI patterns to be consistent with in situ conductive heating of the xenoliths coupled to the cooling host kimberlite. The fourth pattern remains an anomaly.

Microbial Response in Peat Overlying Kimberlite Pipes in The Attawapiskat Area, Northern Ontario

NASA Astrophysics Data System (ADS)

Donkervoort, L. J.; Southam, G.

2009-05-01

Exploration for ore deposits occurring under thick, post-mineralized cover requires innovative methods and instrumentation [1]. Buried kimberlite pipes 'produce' geochemical conditions such as increased pH and decreased Eh in overlying peat [2] that intuitively select for bacterial populations that are best able to grow and, which in turn affect the geochemistry producing a linked signal. A microbiological study of peat was conducted over the Zulu kimberlite in the Attawapiskat area of the James Bay Lowlands to determine if the type of underlying rock influences the diversity and populations of microorganisms living in the overlying peat. Peat was sampled along an 800 m transect across the Zulu kimberlite, including samples underlain by limestone. Microbial populations and carbon source utilization patterns of peat samples were compared between the two underlying rock types. Results demonstrate an inverse relationship of increased anaerobic populations and lower biodiversity directly above the kimberlite pipe. These results support a reduced 'column' consistent with the model presented by Hamilton [3]. The combination of traditional bacterial enumeration and community- level profiling represents a cost-effective and efficient exploration technique that can serve to compliment both geophysical and geochemical surveys. [1] Goldberg (1998) J. Geochem. Explor. 61, 191-202 [2] Hattori and Hamilton (2008) Appl. Geochem. 23, 3767-3782 [3] Hamilton (1998) J. Geochem. Explor. 63, 155-172

The importance of the transport system in shaping the growth and form of kimberlite volcanoes

NASA Astrophysics Data System (ADS)

McClintock, Murray; Ross, Pierre-Simon; White, James D. L.

2009-11-01

Understanding the range of transport styles recorded by kimberlite deposits is key to describing the type and style of eruptions. Building a clear picture of the processes that shape deposits is essential for selecting exploration targets and evaluating the grade and value of diamond-bearing kimberlites. Variations in grade reflect differences in the diamond content of different magma parcels erupted during the lifetime of the kimberlite volcano, sorting during transport of eruption products, or reworking of diamonds during crater growth, cone collapse and erosion. The form of the kimberlite volcano is largely determined when the magma arrives near the surface. If magma comes into contact with external water, transport will be driven by a combination of magmatic gases + steam. From a diamond exploration perspective, the resulting deep diatremes make the most attractive targets because they survive erosion and tend to form large geophysical anomalies. If water is too abundant, a tuff cone or tuff ring with no diatreme or a shallow one will form. On the other hand, if external water is very limited or if the conduit is rapidly sealed by chilled melt, the transport system will be driven by magmatic gases alone. The result will then be a spatter cone or cinder cone underlain by a dike, possibly with a related lava flow, but with no diatreme.

Mg-Fe Isotope Systems of Mantle Xenoliths: Constrains on the Evolution of Siberian Craton

NASA Astrophysics Data System (ADS)

An, Y.; Kiseeva, E. S.; Sobolev, N. V.; Zhang, Z.

2017-12-01

Mantle xenoliths bring to the surface a variety of lithologies (dunites, lherzolites, harzburgites, wehrlites, eclogites, pyroxenites, and websterites) and represent snapshots of the geochemical processes that occur deep within the Earth. Recent improvements in the precision of the MC-ICP-MS measurements have allowed us to expand the amount of data on Mg and Fe isotopes for mantle-derived samples. For instance, to constrain the isotopic composition of the Earth based on the study of spinel and garnet peridotites (An et al., 2017; Teng et al., 2010), to trace the origin and to investigate the isotopic fractionation mechanism during metamorphic process using cratonic or orogenic eclogites (Li et al., 2011; Wang et al., 2012) and to reveal the metasomatism-induced mantle heterogeneity by pyroxenites (Hu et al., 2016). Numerous multi-stage modification events and mantle layering are detected in the subcontinental lithospheric mantle under the Siberian craton (Ashchepkov et al., 2008a; Sobolev et al., 1975, etc). Combined analyses of Mg and Fe isotopic systems could provide new constraints on the formation and evolution of the ancient cratonic mantle. In order to better constrain the magnitude and mechanism of inter-mineral Mg and Fe isotopic fractionations at high temperatures, systematic studies of mantle xenoliths are needed. For example, theoretical calculations and natural samples measurements have shown that large equilibrium Mg isotope fractionations controlled by the difference in coordination number of Mg among minerals could exist (Huang et al., 2013; Li et al., 2011). Thus, the Mg isotope geothermometer could help us trace the evolution history of ancient cratons. In this study we present Mg and Fe isotopic data for whole rocks and separated minerals (clinopyroxene (cpx) and garnet (grt)) from different types of mantle xenoliths (garnet pyroxenites, eclogites, grospydites and garnet peridotites) from a number of kimberlite pipes in Siberian craton (Udachnaya, Obnazhennaya, Mir, and Zagadochnaya). The large Mg and Fe isotope fractionations between clinopyroxene and garnet for various mantle rocks (Δ26Mg cpx-gnt= 0.360‰ 0.888‰, Δ56Fe cpx-gnt= 0.018‰ 0.348‰) indicate that the Siberian cratonic lithosphetic mantle has undergone multiple complex metasomatic and re-equilibration events.

Lithospheric scale conductivity anomalies at the Proterozoic-Phanerozoic transition of Australia- Insights from AusLAMP MT data

NASA Astrophysics Data System (ADS)

Robertson, K. E.; Thiel, S.; Heinson, G. S.

2017-12-01

The intraplate deformation of the north-south trending Neoproterozoic Ikara-Flinders Ranges in South Australia, Australia, draws interest due to its high heat flow, elevated seismicity and the presence of diamondiferous kimberlites and mineral deposits. To the west lies the highly prospective Archean-Paleoproterozoic Gawler Craton, boasting the world's largest IOCG-U deposit, Olympic Dam. The Paleo-Mesoproterozoic Curnamona Province lies to the east, thought to have once been connected to the Gawler Craton and host to the world-class Broken Hill Ag-Pb-Zn deposit. A total of 162 long-period (10 s - 10,000 s) magnetotelluric (MT) stations from the Australia-wide AusLAMP (Australian Lithospheric Architecture Magnetotelluric Project) dataset were used to image the electrical resistivity beneath the Ikara-Flinders Ranges and adjacent Curnamona Province. The most recent acquisition extends this survey region northward to an area predominantly covered with Paleo-Mesozoic sedimentary basins including the most significant on-shore oil and gas region in Australia, the Cooper Basin. The resultant model from 3D inversions using ModEM software shows a relatively resistive Ikara-Flinders Ranges, with two parallel arcuate conductors (the WNAC and ENAC) at 20 to 80 km depth in the Nackara Arc. These conductors correlate well with locations of diamondiferous kimberlites which suggests that the conductors may have derived from the ascent of carbon-rich kimberlite-hosting magma and volatiles up large lithospheric scale structures. The conductors appear to have no correlation with regions of intraplate seismicity within the Ikara-Flinders Ranges which may mean that enhanced pore fluid pressure is not the main cause for the seismicity as was recently proposed. A large conductor covering most of the Curnamona Province (the CC) extends over depths of 10-40 km. The Curnamona Province's most recent tectonothermal activity is from Delamerian reworking during the Cambrian at its margins but is thought to exhibit a mostly cratonic core, supported by high wavespeeds imaged using seismic tomography. Given the pervasive nature of the conductor, it is attributed to a widespread fossil fluid flux event, perhaps either a long-lived response from Olarian (1.6 Ga) subduction-related fluids or a more recent event.

Southern African Phanerozoic Carbonatites: Perspectives on Their Sources and Petrogeneses

NASA Astrophysics Data System (ADS)

Janney, P. E.; Ogungbuyi, P. I.; Marageni, M.; Harris, C.; Reid, D. L.

2017-12-01

Found worldwide, carbonatites are particularly numerous in southern Africa and reflect one expression of abundant intraplate alkaline magmatism of Proterozoic to Paleogene age in the region. Phanerozoic southern African carbonatites tend to be concentrated near the margins of the continent (especially the western margin), and near the East African Rift, and often occur in discrete magmatic lineations also containing kimberlites, melilitites, nephelinites and differentiated silica-undersaturated rocks such as phonolites and syenites. We present a synthesis of geochemical and radiogenic and stable isotope results for southern African carbonatites, including new trace element and isotope data from four Phanerozoic carbonatite complexes in South Africa and Namibia: Marinkas Quellen (MQ; southernmost Namibia, ≈525 Ma), Saltpeterkop (SPK; near Sutherland, South Africa, 74 Ma), Zandkopsdrift (ZKD; near Garies, South Africa, 55 Ma, a major REE deposit in development), and Dicker Willem (DW; near Aus, southern Namibia, 49 Ma). All are located in the Early-mid Proterozoic Namaqua-Natal mobile belt. These carbonatite complexes are each associated with linear, NE-SW oriented magmatic provinces, i.e., the Kuboos-Bremen Line of felsic alkaline intrusions and ultramafic lamprophyres (MQ); the Western Cape olivine melilitite province (SPK); the Namaqualand-Bushmanland-Warmbad province of olivine melilitites and kimberlites (ZKD) and the Schwarzeberg-Klinghardt-Gibeon swarm of nephelinites, phonolites and kimberlites (DW), the latter three provinces are of Paleogene to Late Cretaceous age and are clearly age progressive. Each of the four carbonatite complexes contain silica-undersaturated igneous rocks such as potassic trachyte (MQ, SPK & DW), alkaline lamprophyre (ZKD), ijolite (MQ & DW) and olivine melilitite (ZKD and SPK). Most also contain hybrid silicate-carbonate igneous rocks with <35 wt.% SiO2 and ≥20 wt.% CO2 such as nepheline sövite (DW), aillikite (ZKD) and other carbonated ultramafic lamprophyre types (SPK) that could represent magmas parental to the carbonatites. Like the magmatic provinces that host them, the carbonatites span a range of isotopic compositions from strong HIMU to EM1. We will present a model of carbonatite origin and source evolution related to lithospheric setting.

The P3 kimberlite and P4 lamproite, Wajrakarur kimberlite field, India: mineralogy, and major and minor element compositions of olivines as records of their phenocrystic vs xenocrystic origin

NASA Astrophysics Data System (ADS)

Shaikh, Azhar M.; Kumar, Satya P.; Patel, Suresh C.; Thakur, Satyajeet S.; Ravi, Subramanian; Behera, Duryadhan

2018-03-01

Distinctly different groundmass mineralogy characterise the hypabyssal facies, Mesoproterozoic diamondiferous P3 and P4 intrusions from the Wajrakarur Kimberlite Field, southern India. P3 is an archetypal kimberlite with macrocrysts of olivine and phlogopite set in a groundmass dominated by phlogopite and monticellite with subordinate amounts of serpentine, spinel, perovskite, apatite, calcite and rare baddeleyite. P4 contains mega- and macrocrysts of olivine set in a groundmass dominated by clinopyroxene and phlogopite with subordinate amounts of serpentine, spinel, perovskite, apatite, and occasional gittinsite, and is mineralogically interpreted as an olivine lamproite. Three distinct populations of olivine, phlogopite and clinopyroxene are recognized based on their microtextural and compositional characteristics. The first population includes glimmerite and phlogopite-clinopyroxene nodules, and Mg-rich olivine macrocrysts (Fo 90-93) which are interpreted to be derived from disaggregated mantle xenoliths. The second population comprises macrocrysts of phlogopite and Fe-rich olivine (Fo 81-89) from P3, megacrysts and macrocrysts of Fe-rich olivine (Fo 85-87) from P4 and a rare olivine-clinopyroxene nodule from P4 which are suggested to have a genetic link with the precursor melt of the respective intrusions. The third population represents clearly magmatic minerals such as euhedral phenocrysts of Fe-rich olivine (Fo 85-90) crystallised at mantle depths, and olivine overgrowth rims formed contemporaneously with groundmass minerals at crustal levels. Close spatial association and contemporaneous emplacement of P3 kimberlite and P4 lamproite is explained by a unifying petrogenetic model which involves the interaction of a silica-poor carbonatite melt with differently metasomatised wall rocks in the lithospheric mantle. It is proposed that the metasomatised wall rock for lamproite contained abundant MARID-type and phlogopite-rich metasomatic veins, while that for kimberlite was relatively refractory in nature.

The ascent of kimberlite: Insights from olivine

NASA Astrophysics Data System (ADS)

Brett, R. C.; Russell, J. K.; Andrews, G. D. M.; Jones, T. J.

2015-08-01

Olivine xenocrysts are ubiquitous in kimberlite deposits worldwide and derive from the disaggregation of mantle-derived peridotitic xenoliths. Here, we provide descriptions of textural features in xenocrystic olivine from kimberlite deposits at the Diavik Diamond Mine, Canada and at Igwisi Hills volcano, Tanzania. We establish a relative sequence of textural events recorded by olivine during magma ascent through the cratonic mantle lithosphere, including: xenolith disaggregation, decompression fracturing expressed as mineral- and fluid-inclusion-rich sealed and healed cracks, grain size and shape modification by chemical dissolution and abrasion, late-stage crystallization of overgrowths on olivine xenocrysts, and lastly, mechanical milling and rounding of the olivine cargo prior to emplacement. Ascent through the lithosphere operates as a "kimberlite factory" wherein progressive upward dyke propagation of the initial carbonatitic melt fractures the overlying mantle to entrain and disaggregate mantle xenoliths. Preferential assimilation of orthopyroxene (Opx) xenocrysts by the silica-undersaturated carbonatitic melt leads to deep-seated exsolution of CO2-rich fluid generating buoyancy and supporting rapid ascent. Concomitant dissolution of olivine produces irregular-shaped relict grains preserved as cores to most kimberlitic olivine. Multiple generations of decompression cracks in olivine provide evidence for a progression in ambient fluid compositions (e.g., from carbonatitic to silicic) during ascent. Numerical modelling predicts tensile failure of xenoliths (disaggregation) and olivine (cracks) over ascent distances of 2-7 km and 15-25 km, respectively, at velocities of 0.1 to >4 m s-1. Efficient assimilation of Opx during ascent results in a silica-enriched, olivine-saturated kimberlitic melt (i.e. SiO2 >20 wt.%) that crystallizes overgrowths on partially digested and abraded olivine xenocrysts. Olivine saturation is constrained to occur at pressures <1 GPa; an absence of decompression cracks within olivine overgrowths suggests depths <25 km. Late stage (<25 km) resurfacing and reshaping of olivine by particle-particle milling is indicative of turbulent flow conditions within a fully fluidized, gas-charged, crystal-rich magma.

Timescales between mantle metasomatism and kimberlite ascent indicated by diffusion profiles in garnet crystals from peridotite xenoliths

NASA Astrophysics Data System (ADS)

Jollands, Michael C.; Hanger, Brendan J.; Yaxley, Gregory M.; Hermann, Jörg; Kilburn, Matthew R.

2018-01-01

Rare garnet crystals from a peridotite xenolith from the Wesselton kimberlite, South Africa, have distinct zones related to two separate episodes of mantle metasomatism. The garnet cores were firstly depleted through melt extraction, then equilibrated during metasomatism by a potentially diamond-forming carbonate-bearing or proto-kimberlitic fluid at 1100-1300 °C and 4.5-5.5 GPa. The garnet rim chemistry, in contrast, is consistent with later overgrowth in equilibrium with a kimberlite at around 1025 ± 25 °C and 4.2 ± 0.5 GPa. This suggests that the rock was physically moved upwards by up to tens of kilometres between the two metasomatic episodes. Preserved high Ca, Al and Cr contents in orthopyroxenes suggest this uplift was tectonic, rather than magmatic. Diffusion profiles were measured over the transitions between garnet cores and rims using electron microprobe (Mg, Ca, Fe for modelling, plus Cr, Mn, Ti, Na, Al) and nano Secondary Ion Mass Spectrometry (NanoSIMS; 89Y, along with 23Na, Ca, Cr, Fe, Mn and Ti) analyses. The short profile lengths (generally <10 μm) and low Y concentrations (0.2-60 ppm) make the NanoSIMS approach preferable. Diffusion profiles at the interface between the zones yield constraints on the timescale between the second metasomatic event and eruption of the kimberlite magma that brought the xenolith to the surface. The time taken to form the diffusion profiles is on the order of 25 days to 400 yr, primarily based on modelling of Y diffusion along with Ca, Fe and Mg (multicomponent diffusion) profiles. These timescales are too long to be produced by the interaction of the mantle xenolith with the host kimberlite magma during a single-stage ascent to the crust (hours to days). The samples offer a rare opportunity to study metasomatic processes associated with failed eruption attempts in the cratonic lithosphere.

Are diamond-bearing Cretaceous kimberlites related to shallow-angle subduction beneath western North America?

NASA Astrophysics Data System (ADS)

Currie, C. A.; Beaumont, C.

2009-05-01

The origin of deep-seated magmatism (in particular, kimberlites and lamproites) within continental plate interiors remains enigmatic in the context of plate tectonic theory. One hypothesis proposes a relationship between kimberlite occurrence and lithospheric subduction, such that a subducting plate releases fluids below a continental craton, triggering melting of the deep lithosphere and magmatism (Sharp, 1974; McCandless, 1999). This study provides a quantitative evaluation of this hypothesis, focusing on the Late Cretaceous- Eocene (105-50 Ma) kimberlites and lamproites of western North America. These magmas were emplaced along a corridor of Archean and Proterozoic lithosphere, 1000-1500 km inboard of the plate margin separating the subducting Farallon Plate and continental North America Plate. Kimberlite-lamproite magmatism coincides with tectonic events, including the Laramide orogeny, shut-down of the Sierra Nevada arc, and eastward migration of volcanism, that are commonly attributed to a change in Farallon Plate geometry to a shallow-angle trajectory (<25° dip). Thermal-mechanical numerical models demonstrate that rapid Cretaceous plate convergence rates and enhanced westward velocity of North America result in shallow-angle subduction that places the Farallon Plate beneath the western edge of the cratonic interior of North America. This geometry is consistent with the observed continental dynamic subsidence that lead to the development of the Western Interior Seaway. The models also show that the subducting plate has a cool thermal structure, and subducted hydrous minerals (serpentine, phengite and phlogopite) remain stable to more than 1200 km from the trench, where they may break down and release fluids that infiltrate the overlying craton lithosphere. This is supported by geochemical studies that indicate metasomatism of the Colorado Plateau and Wyoming craton mantle lithosphere by an aqueous fluid and/or silicate melt with a subduction signature. Through Cretaceous shallow-angle subduction, the Farallon Plate was in a position to mechanically and chemically interact with North American craton lithosphere at the time of kimberlite-lamproite magmatism, making the subduction hypothesis a viable mechanism for the genesis of these magmas. REFERENCES: McCandless, T.E., Proceedings of the 7th International Kimberlite Conference, v.2, pp.545-549, 1999; Sharp, W.E., Earth Planet. Sci. Lett., v.21, pp.351-354, 1974.

Regional Variations in Composition of Cr-spinel Xenocrysts From Kimberlite

NASA Astrophysics Data System (ADS)

Schulze, D. J.

2001-05-01

Important information on the composition of the upper mantle can be obtained by studying mantle xenocrysts in kimberlite, especially in situations in which intact mantle xenoliths are rare to absent. Spinel-group minerals are especially useful as they can coexist with garnet or represent regions of the mantle shallower than garnet-facies rocks, and chromites can exist in rocks too Al-depleted to form garnet. Xenolith studies have shown that along most typical cratonic geothermal gradients, the maximum Cr/(Cr+Al) (cr#) of spinel coexisting with garnet is 0.88. Cr-spinels with cr# > 0.88 are from Al-depleted rocks or from assemblages in which Al is partitioned into another phase (e.g., metasomatic phlogopite). Approximately 2500 Cr-spinel xenocrysts from 36 kimberlites in southern Africa and North America have been analysed (and some published data used) and evaluated, primarily in terms of cr# and Fe2/(Fe2+Mg) (fe#). Differences from pipe to pipe within and between cratons reflect variations in geologic history and fertility/depletion, only some of which can be related to mantle age. Within southern Africa, pipe average values of spinel xenocryst cr# are highest on the Kaapvaal Craton (0.80-0.89) where fe# varies from 0.36 to 0.47. Suites from the craton margin (e.g., in Lesotho) indicate a less depleted mantle (cr# = 0.75-0.80), similar to those from the Zimbabwe Craton (Orapa and Letlhakane, cr# = 0.80-0.81). Jwaneng (Kaapvaal Craton) is similar to the Zimbabwe Craton pipes (cr# = 0.83). Off-craton South African suites (Kalkput and Rietfontein) have lower cr# (0.72-0.75). Most southern African suites contain a significant population of Cr-spinel with cr# > 0.88 (including off-craton Rietfontein) except Liqhobong on the craton margin in Lesotho. Cr-spinel suites from North American kimberlites are quite different, with most suites being significantly more aluminous than African populations. Most Kirkland Lake kimberlites on the Superior Craton have a very restricted fe# (0.41-0.43) at cr# values below those from Kaapvaal and Zimbabwe Cratons (0.67-0.78). Wyoming Craton kimberlites (Sloan and Kelsey Lake) also have aluminous spinel populations (cr# = 0.70-0.76). High-Cr spinel xenocrysts (cr# > 0.88) are common in Superior Craton populations but less abundant on the Wyoming Craton. Off-craton kimberlites (on Grenville basement) in Kentucky and Pennsylvania are much more aluminous (cr# = 0.62) and have almost no xenocrysts with cr# > 0.88. The general increase in fertility (lower cr# in spinel) from craton centre to margin to off-craton is confirmed, but Cr-spinel populations from all tectonic settings in North American kimberlites appear to be less depleted on average than their equivalents in southern Africa.

Fission track dating of kimberlitic zircons

NASA Astrophysics Data System (ADS)

Haggerty, Stephen E.; Raber, Ellen; Naeser, Charles W.

1983-04-01

The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts 206Pb and 238U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0-1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome. Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ± 6.5 m.y.), Orapa (87.4 ± 5.7 and 92.4 ± 6.1 m.y.), Nzega (51.1 ± 3.8 m.y.), Koffiefontein (90.0 ± 8.2 m.y.), and Val do Queve (133.4 ± 11.5 m.y.). In addition we report the first radiometric ages (707.9 ± 59.6 and 705.5 ± 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption.

Fission track dating of kimberlitic zircons

USGS Publications Warehouse

Haggerty, S.E.; Raber, E.; Naeser, C.W.

1983-01-01

The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts 206Pb and 238U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0-1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome. Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ?? 6.5 m.y.), Orapa (87.4 ?? 5.7 and 92.4 ?? 6.1 m.y.), Nzega (51.1 ?? 3.8 m.y.), Koffiefontein (90.0 ?? 8.2 m.y.), and Val do Queve (133.4 ?? 11.5 m.y.). In addition we report the first radiometric ages (707.9 ?? 59.6 and 705.5 ?? 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption. ?? 1983.

The petrogenesis of oceanic kimberlites and included mantle megacrysts: The Malaitan alnoite

NASA Technical Reports Server (NTRS)

Neal, Clive R.

1988-01-01

The study of unambiguous suboceanic mantle was facilitated by the occurrence of anomalous kimberlite-type intrusives on Malaita in the Solomon Islands. The pseudo-kimberlites were termed alnoites, and are basically mica lamprophyres with melilite in the ground mass. Alnoitic magmas were explosively intruded into the Ontong Java Plateau (OJP) 34 Ma ago. The OJP is a vastly overthickened portion of the Pacific plate which now abuts the Indo-Australian plate. Malaita is considered to be the obducted leading edge of the OJP. Initial diapiric upwelling beneath the OJP produced the proto-alnoite magma. After impingement on the rigid lithosphere, megacrysts fractionation occurred, with augites precipitating first, representing the parental magma. Sea water-altered oceanic crust, which underplated the OJP, was assimilated by the proto-alnoite magma during megacrysts fractionation (AFC).

Regularities of spatial association of major endogenous uranium deposits and kimberlitic dykes in the uranium ore regions of the Ukrainian Shield

NASA Astrophysics Data System (ADS)

Kalashnyk, Anna

2015-04-01

During exploration works we discovered the spatial association and proximity time formation of kimberlite dykes (ages are 1,815 and 1,900 Ga for phlogopite) and major industrial uranium deposits in carbonate-sodium metasomatites (age of the main uranium ore of an albititic formation is 1,85-1,70 Ga according to U-Pb method) in Kirovogradsky, Krivorozhsky and Alekseevsko-Lysogorskiy uranium ore regions of the Ukrainian Shield (UkrSh) [1]. In kimberlites of Kirovogradsky ore region uranium content reaches 18-20 g/t. Carbon dioxide is a major component in the formation of hydrothermal uranium deposits and the formation of the sodium in the process of generating the spectrum of alkaline ultrabasic magmas in the range from picritic to kimberlite and this is the connection between these disparate geochemical processes. For industrial uranium deposits in carbonate-sodium metasomatitics of the Kirovogradsky and Krivorozhsky uranium ore regions are characteristic of uranyl carbonate introduction of uranium, which causes correlation between CO2 content and U in range of "poor - ordinary - rich" uranium ore. In productive areas of uranium-ore fields of the Kirovogradsky ore region for phlogopite-carbonate veinlets of uranium ore albitites deep δ13C values (from -7.9 to -6.9o/oo) are characteristic. Isotope-geochemical investigation of albitites from Novokonstantynovskoe, Dokuchaevskoe, Partyzanskoe uranium deposits allowed obtaining direct evidence of the involvement of mantle material during formation of uranium albitites in Kirovogradsky ore region [2]. Petrological characteristics of kimberlites from uranium ore regions of the UkrSh (presence of nodules of dunite and harzburgite garnet in kimberlites, diamonds of peridotite paragenesis, chemical composition of indicator minerals of kimberlite, in particular Gruzskoy areas pyropes (Cr2O3 = 6,1-7,1%, MgO = 19,33-20,01%, CaO = 4,14-4,38 %, the content of knorringite component of most grains > 50mol%), chromites (Cr2O3 = 45,32-62,17%, MgO = 7,3-12,5%) allow us to estimate the depth of generation of kimberlite magmas more than 170-200 km. Ilmenites show two groups according to MgO, Cr2O3 and TiO2 content. Reconstructions of the mantle sections show also two intervals of pressures divided at 4.5 GPa, the upper part is highly metasomatized This high degree metasomatism is determined for almost all mantle columns. It is suggested that large-scale of uranium-bearing mantle fluids may be associated with the ancient degasation during the subduction which is highly enriched in U component . Analysis of the reasons for the marked association kimberlitic dykes and major industrial uranium deposits in carbonate-sodium metasomatic in the UkrSh led to the conclusion that hydrothermal uranium deposits are confined to the supply mantle fluid systems of mantle fault zones exercising brings sodium carbonate solutions enriched uranium from mantle sources. References: 1. Kalashnik A.A. New prognostic-evaluation criteria in technology prognosis of forming industrial endogenous uranium deposits of the Ukrainian Shield, 2014. Scientific proceedings of UkrSGRI, № 2, p. 27-54 (in Russian) 2. Stepanjuk L.M., Bondarenko S.V., Somka V.O. and other, 2012. Source of uranium and uranium-bearing sodium albitites for example of Dokuchaievskogo field of the Ingulsky megablock of the UkrSh: Abstracts of scientific conference "Theoretical issues and research practice metasomatic rocks and ores" (Kyiv, 14-16 March 2012), IGMOF, p.78-80. (in Ukrainian)

Deep seated inclusions in kimberlites from Kharamai field and some kimberlite fields of Prianabarie.

NASA Astrophysics Data System (ADS)

Ashchepkov, I. V.; Kuligin, S. S.; Afanasiev, V. P.; Vladykin, N. V.; Kostrovitsky, S. I.; Lelyukh, M. I.; Vavilov, M. A.; Nigmatulina, E. N.; Palessky, S. V.

2012-04-01

The problem of the thickness of the lithospheric keel in the northern part of Yakutia is critical for the diamond grade. Reported delamination of the SCLM (Griffin et al., 2005)which is not supported by the geophysical methods (Koulakov et al ., 2011) was checked in number of localities in circum Anabar region. Pyropes, chrome-diopside, omphacites, enstatite, chromites and ilmenites from concentrate three kimberlitic pipes of the Kharamai field revealed compositional variations typical for thick SCLM: pyropes to 13% Of cr2O3 in the association with chromites (to 60% Of cr2O3.) low- Al - Cr diopsides and enstatite, omphacites, Cr-pargasite and K-Na richterite and picroilmenites (to 20% Of MgO). The pyropes belong to lherzolite filed (Sobolev et al., 1973) as those published only in the low-chromium part relate to Ca- Fe to pyroxenite magmatic trend (Tychkov et al., 2008) which is typical for the majority of Mesozoic (especially Jurassic) kimberlitic pipes in Prianabarie and other northern parts of Yakutia. Thermo-barometric reconstructions using four methods of monomineral thermobarometry reveal the thickness of lithospheric keel not less than 200 km which coinsides with the determined thickness of the SCLM beneath nearest Ary- Mastakh filed (Khardakh pipe). Straya Rechka and Kuranakh fields (Universitetskaya, Tudovaya , Los kimberlites etc). But the pipes in Evenkiyskaya kimberlite group (including Malysh and Tuzic pipes) carry material dominantly from the upper part of the SCLM, sub-calcium garnets are rare. Relatively high oxidation state, determined according to chromite, pyroxenes and pyropes are in accord with the rather low diamond grades. However some other Jurassic pipes in northern part of the Siberian craton reveal sufficiently deep mantle roots evidencing about lack of the delamination of mantle keel after Siberian PT superplume. The trace elements determined for the pyropes show variations and belong to the melt metasomatized groups I the middle and lower part of the SCLM But those from upper part correspond to the LREE and LILE enriched melts. The chrome diopsides show dominantly the signs of the refertillization. The influence of the superplume melts for the SCLM in Kharamai field is higher then for the internal part of the Anabar region affected to the low Jurassic kimberlite magmatism. The Cretaceous pipes show the location of the magma derrivatio level near 130 km (Taylor et al ., 2003) Alluvial diamonds in the northern part of Siberian craton can be associated with undiscovered kimberlite II or lamproites which, were carried from the mantle sections of those saturated by eclogite. The relatively small portion of pyropes from thee deep part of the mantle sections in Prianabarie and surroundings is explained by the general exhaustion of mantle peridotite substratum in this region (Griffin et al., 1998). Rare Cr rich pyropes, chromites, orange pyropes referred to the deep eclogitic associations support this idea.

Contrasting eruption styles of the 147 Kimberlite, Fort à la Corne, Saskatchewan, Canada

NASA Astrophysics Data System (ADS)

Lefebvre, Nathalie; Kurszlaukis, Stephan

2008-06-01

The Cretaceous Fort à la Corne (FALC) kimberlite field was active over a time span of ~ 20 Ma with contemporaneous terrestrial (Mannville Group) to marine (Lower Colorado Group) background sedimentation. Steep-sided pipes, craters and positive landform volcanoes such as scoria or tuff cones are thought to have formed during that period. The 147 Kimberlite is located in the SE section of the field's main cluster and is part of the large (~ 377.5 ha) Orion North volcanic complex. Based on logging of 25 drill cores, the morphology of the country rock/kimberlite interface suggests excavation of a complex crater field down to the upper portion of the Mannville Group sedimentary deposits. At least two types of volcaniclastic deposits are identified: a main kimberlite unit that is typically characterized by crustal xenolith-poor (1-2%), normal graded beds possibly deposited as turbidites in a subaqueous environment, originating from the nearby 148 tephra cone and infilling the adjacent 147 crater, and a second unit, located on the NE margin of the 147 Kimberlite, that represents a thick (~ 60 m) sequence of large (up to 22 m) sedimentary country rock blocks located at least 60 m above their original stratigraphic position. We suggest the following time sequence of events: Crater excavation as a consequence of a shallow magma fragmentation level within the uppermost country rock sequences, together with several closely spaced eruptive centres initially formed the complex, intercalated crater field. Subsequently, ongoing eruptions with a fragmentation level above the country rock produced the lithic fragment poor main infill of the 148 Kimberlite. Resedimentation from the outer flanks of the 148 tephra cone resulted in the deposition of turbidites in the 147 area. A consolidation phase solidified the lowermost portion of the main infill in 147. A subsequent explosion(s) occurred within the Mannville Group in the 147 area, ejecting large blocks of sedimentary country rocks and fracturing the overlying volcaniclastic main infill. Finally, blocks of the main infill tilted and possibly slumped into the subsidence structure developed above the emptied explosion chamber of 147. The different volcanic deposits reflect a change in eruption style and fragmentation level from highly explosive to spatter activity with little fragmentation potential. Cap rocks to build up the volatile overpressure necessary to blast the craters were not present at the time of emplacement. No diatremes were observed in the study area. Assuming that the magma properties remained constant over time, the change in eruption style has to be attributed to external factors, such as water access to the rising magma. The volcanic behaviour of the kimberlite magma appears to be comparable to that of other magmatic systems, both in eruptive style and production rate. No evidence was found for a high, possibly Plinian production rate or dispersion.

Tracing the depositional history of Kalimantan diamonds by zircon provenance and diamond morphology studies

NASA Astrophysics Data System (ADS)

Kueter, Nico; Soesilo, Joko; Fedortchouk, Yana; Nestola, Fabrizio; Belluco, Lorenzo; Troch, Juliana; Wälle, Markus; Guillong, Marcel; Von Quadt, Albrecht; Driesner, Thomas

2016-11-01

Diamonds in alluvial deposits in Southeast Asia are not accompanied by indicator minerals suggesting primary kimberlite or lamproite sources. The Meratus Mountains in Southeast Borneo (Province Kalimantan Selatan, Indonesia) provide the largest known deposit of these so-called "headless" diamond deposits. Proposals for the origin of Kalimantan diamonds include the adjacent Meratus ophiolite complex, ultra-high pressure (UHP) metamorphic terranes, obducted subcontinental lithospheric mantle and undiscovered kimberlite-type sources. Here we report results from detailed sediment provenance analysis of diamond-bearing Quaternary river channel material and from representative outcrops of the oldest known formations within the Alino Group, including the diamond-bearing Campanian-Maastrichtian Manunggul Formation. Optical examination of surfaces of diamonds collected from artisanal miners in the Meratus area (247 stones) and in West Borneo (Sanggau Area, Province Kalimantan Barat; 85 stones) points toward a classical kimberlite-type source for the majority of these diamonds. Some of the diamonds host mineral inclusions suitable for deep single-crystal X-ray diffraction investigation. We determined the depth of formation of two olivines, one coesite and one peridotitic garnet inclusion. Pressure of formation estimates for the peridotitic garnet at independently derived temperatures of 930-1250 °C are between 4.8 and 6.0 GPa. Sediment provenance analysis includes petrography coupled to analyses of detrital garnet and glaucophane. The compositions of these key minerals do not indicate kimberlite-derived material. By analyzing almost 1400 zircons for trace element concentrations with laser ablation ICP-MS (LA-ICP-MS) we tested the mineral's potential as an alternative kimberlite indicator. The screening ultimately resulted in a small subset of ten zircons with a kimberlitic affinity. Subsequent U-Pb dating resulting in Cretaceous ages plus a detailed chemical reflection make a kimberlitic origin unfavorable with respect to the regional geological history. Rather, trace elemental analyses (U, Th and Eu) suggest an eclogitic source for these zircons. The age distribution of detrital zircons allows in general a better understanding of collisional events that formed the Meratus orogen and identifies various North Australian Orogens as potential Pre-Mesozoic sediment sources. Our data support a model whereby the majority of Kalimantan diamonds were emplaced within the North Australian Craton by volcanic processes. Partly re-deposited into paleo-collectors or residing in their primary host, these diamond-deposits spread passively throughout Southeast Asia by terrane migration during the Gondwana breakup. Terrane amalgamation events largely metamorphosed these diamond-bearing lithologies while destroying the indicative mineral content. Orogenic uplift finally liberated their diamond-content into new, autochthonous placer deposits.

Lake Ellen kimberlite, Michigan, U.S.A.

USGS Publications Warehouse

McGee, E.S.; Hearn, B.C.

1983-01-01

The recently discovered Lake Ellen kimberlite, in northern Michigan, indicates that bedrock sources of diamonds found in glacial deposits in the Great Lakes area could lie within the northern U.S. Magnetic surveys show a main kimberlite 200 m in diameter and an adjacent body 25 x 90 m(?). The kimberlite cuts Proterozoic volcanic rocks that overlie Archean basement, but is post-Ordovician in age based on abundant Ordovician(?) dolomite inclusions. Xenocrysts and megacrysts are ilmenite (abundant, 12.5-19% MgO), pyropealmandine and Cr-pyrope (up to 9.3% Cr2O3), Cr-diopside (up to 4.5% Cr2O3), olivine (Fo 91), enstatite and phlogopite. The kimberlite contains fragments of crustal schist and granulite, as well as disaggregated crystals and rare xenoliths of eclogites, garnet pyroxenites and garnet peridotites from a heterogeneous upper mantle. Eclogites, up to 3 cm size, show granoblastic equant or tabular textures and consist of jadeitic cpx (up to 8.4% Na20, 15.3% Al2O3), pyrope-almandine, ? rutile ? kyanite ? sanidine ? sulfide. Garnet pyroxenite contains pyrope--(0.44% Cr2O3) + cpx (0.85% Na2O, 0.53% Cr2O3) + Mg-Al spinel. Mineral compositions of rare composite xenocrysts of garnet + cpx are distinctively peridotitic, pyroxenitic or eclogitic. Calculated temperatures of equilibration are 920-1060 ?C for the eclogites and 820-910?C for the garnet pyroxenite using the Ellis-Green method. Five peridotite garnet-clinopyroxene composite xenocrysts have calculated temperatures of 980-1120?C using the Lindsley-Dixon 20 kb solvus. Spinel pyroxenite and clinopyroxene-orthopyroxene composites have lower calculated temperatures of 735?C and 820-900?C, respectively. Kyanite-bearing eclogites must have formed at pressures greater than 18-20 kb. Using the present shield geotherm with a heat flow value of 44mW/m 2 for the time of kimberlite emplacement, the eclogite temperatures imply pressures of 35-48 kb (105-140 km) and the garnet pyroxenite temperatures indicate pressures of 24-29 kb (75-90 km). Temperatures of two peridotitic garnet-cpx composite xenocrysts if on a shield geotherm, imply pressures within the diamond stability field.

Dynamical constraints on kimberlite volcanism

NASA Astrophysics Data System (ADS)

Sparks, R. S. J.; Baker, L.; Brown, R. J.; Field, M.; Schumacher, J.; Stripp, G.; Walters, A.

2006-07-01

Kimberlite volcanism involves the ascent of low viscosity (0.1 to 1 Pa s) and volatile-rich (CO 2 and H 2O) ultrabasic magmas from depths of 150 km or greater. Theoretical models and empirical evidence suggest ascent along narrow (˜1 m) dykes at speeds in the range > 4 to 20 m/s. With typical dyke breadths of 1 to 10 km, magma supply rates are estimated in the range 10 2 to 10 5 m 3/s with eruption durations of many hours to months. Based on observations, theory and experiments we propose a four-stage model for kimberlite eruptions to explain the main geological relationships of kimberlites. In stage I magma reaches the Earth's surface along fissures and erupts explosively due to their high volatile content. The early flow exit conditions are overpressured with choked flow conditions; an exit velocity of ˜200 m/s is estimated as representative. Explosive expansion and near surface overpressures initiate crater and pipe formation from the top downwards. In stage II under-pressures (the difference between the lithostatic pressure and pressure of the erupting mixture) develop within the evolving pipe causing rock bursting at depth, undermining overlying rocks and causing down-faulting and crater rim slumping. Rocks falling into the pipe interior are ejected by the strong explosive flows. Stage II is the erosive stage of pipe formation. As the pipe widens and deepens larger under-pressures develop enhancing pipe wall instability. A critical threshold is reached when the exit pressure falls to one atmosphere. As the pipe widens and deepens further the gas exit velocity declines and ejecta becomes trapped within the pipe, initiating stage III. A fluidised bed of pyroclasts develops within the pipe as the eruption wanes to form typical massive volcaniclastic kimberlite. Marginal breccias represent the transition between stages II and III. After the eruption stage IV is a period of hydrothermal metamorphism (principally serpentinisation) and alteration as the pipe cools and meteoric waters infiltrate the hot pipe fill. Following an eruption an open crater can be filled by kimberlite- and country-rock derived sediments, forming the crater-facies.

Three dimensional inversion of magnetic survey data collected over kimberlite pipes in presence of remanent magnetization

NASA Astrophysics Data System (ADS)

Zhao, Pengzhi

Magnetic method is a common geophysical technique used to explore kimberlites. The analysis and interpretation of measured magnetic data provides the information of magnetic and geometric properties of potential kimberlite pipes. A crucial parameter of kimberlite magnetic interpretation is the remanent magnetization that dominates the classification of kimberlite. However, the measured magnetic data is the total field affected by the remanent magnetization and the susceptibility. The presence of remanent magnetization can pose severe challenges to the quantitative interpretation of magnetic data by skewing or laterally shifting magnetic anomalies relative to the subsurface source (Haney and Li, 2002). Therefore, identification of remanence effects and determination of remanent magnetization are important in magnetic data interpretation. This project presents a new method to determine the magnetic and geometric properties of kimberlite pipes in the presence of strong remanent magnetization. This method consists of two steps. The first step is to estimate the total magnetization and geometric properties of magnetic anomaly. The second step is to separate the remanent magnetization from the total magnetization. In the first step, a joint parametric inversion of total-field magnetic data and its analytic signal (derived from the survey data by Fourier transform method) is used. The algorithm of the joint inversion is based on the Gauss-Newton method and it is more stable and more accurate than the separate inversion method. It has been tested with synthetic data and applied to interpret the field data from the Lac de Gras, North-West Territories of Canada. The results of the synthetic examples and the field data applications show that joint inversion can recovers the total magnetization and geometric properties of magnetic anomaly with a good data fit and stable convergence. In the second step, the remanent magnetization is separated from the total magnetization by using a determined susceptibility. The susceptibility value is estimated by using the frequency domain electromagnetic data. The inversion method is achieved by a code, named “EM1DFM”, developed by University of British Columbia was designed to construct one of four types of 1D model, using any type of geophysical frequency domain loop-loop data with one of four variations of the inversion algorithm. The results show that the susceptibility of magnetic body is recovered, even if the depth and thickness are not well estimated. This two-step process provides a new way to determine magnetic and geometric properties of kimberlite pipes in the presence of strong remanent magnetization. The joint inversion of the total-field magnetic data and its analytic signal obtains the total magnetization and geometric properties. The frequency domain EM method provides the susceptibility. As a result, the remanent magnetization can be separated from the total magnetization accurately.

The Homestead kimberlite, central Montana, USA: Mineralogy, xenocrysts, and upper-mantle xenoliths

USGS Publications Warehouse

Carter, Hearn B.

2004-01-01

The Homestead kimberlite was emplaced in lower Cretaceous marine shale and siltstone in the Grassrange area of central Montana. The Grassrange area includes aillikite, alnoite, carbonatite, kimberlite, and monchiquite and is situated within the Archean Wyoming craton. The kimberlite contains 25-30 modal% olivine as xenocrysts and phenocrysts in a matrix of phlogopite, monticellite, diopside, serpentine, chlorite, hydrous Ca-Al-Na silicates, perovskite, and spinel. The rock is kimberlite based on mineralogy, the presence of atoll-textured groundmass spinels, and kimberlitic core-rim zoning of groundmass spinels and groundmass phlogopites. Garnet xenocrysts are mainly Cr-pyropes, of which 2-12% are G10 compositions, crustal almandines are rare and eclogitic garnets are absent. Spinel xenocrysts have MgO and Cr2O3 contents ranging into the diamond inclusion field. Mg-ilmenite xenocrysts contain 7-11 wt.% MgO and 0.8-1.9 wt.% Cr2O3, with (Fe+3/Fetot) from 0.17-0.31. Olivine is the only obvious megacryst mineral present. One microdiamond was recovered from caustic fusion of a 45-kg sample. Upper-mantle xenoliths up to 70 cm size are abundant and are some of the largest known garnet peridotite xenoliths in North America. The xenolith suite is dominated by dunites, and harzburgites containing garnet and/or spinel. Granulites are rare and eclogites are absent. Among 153 xenoliths, 7% are lherzolites, 61% are harzburgites, 31% are dunites, and 1% are orthopyroxenites. Three of 30 peridotite xenoliths that were analysed are low-Ca garnet-spinel harzburgites containing G10 garnets. Xenolith textures are mainly coarse granular, and only 5% are porphyroclastic. Xenolith modal mineralogy and mineral compositions indicate ancient major-element depletion as observed in other Wyoming craton xenolith assemblages, followed by younger enrichment events evidenced by tectonized or undeformed veins of orthopyroxenite, clinopyroxenite, websterite, and the presence of phlogopite-bearing veins and disseminated phlogopite. Phlogopite-bearing veins may represent kimberlite-related addition and/or earlier K-metasomatism. Xenolith thermobarometry using published two-pyroxene and Al-in-opx methods suggest that garnet-spinel peridotites are derived from 1180 to 1390 ??C and 3.6 to 4.7 GPa, close to the diamond-graphite boundary and above a 38 mW/m2 shield geotherm. Low-Ca garnet-spinel harzburgites with G10 garnets fall in about the same T and P range. Most spinel peridotites with assumed 2.0 GPa pressure are in the same T range, possibly indicating heating of the shallow mantle. Four of 79 Cr diopside xenocrysts have P-T estimates in the diamond stability field using published single-pyroxene P-T calculation methods.

Detecting of the processes of the diamond formation using the monomineral thermobarometry .

NASA Astrophysics Data System (ADS)

Ashchepkov, Igor; Afanasiev, Valentin; Pokhilenko, Lyudmila; Logvinova, Alla; Vladykin, Nikolai

2010-05-01

The methods of the monomineral thermobarometry used for the reconstruction of the mantle sections beneath the kimberlite pipes (Ashchepkov et al., 2009) allow to determined PT range for the diamond inclusions (DI) and diamond bearing associations. They show various conditions for the crystallization of diamond for in mantle lithosphere beneath the Yakutia, Africa, and North America. In Yakutia most DI (Sobolev ea 1997, 2004; Logvinova ea., 2005 and ref their in) (Cr-pyropes, Mg -opx) form Mir and Udachnaya pipes are referred to the cold geotherms 35 (partly 33 mvm-2) at the pressure range from 35 to 80 kbar. Cr- pyropes (Ti-bearing) partly drops the on the heated area near convective branches 40-45 mvm-2 convective geotherms. Most Cr- rich pyroxenes refer to the coldest or heated (metasomatic type) at the deeper parts of the mantle columns while mildly Cr-rich varieties refer to the conditions of the crystallization from the melts related to the protokimberlites and associated carbonatites near the Graphite-Diamond boundary (G-D). They are more widely distributed in mantle beneath the Mir pipe where the essential part of mantle column from 50 to 35kbar was subjected to the refertilization. But chromite PT estimates mostly refer the heated conditions of the convective branch at the lithosphere base (~70-60kbar). They are most typical for the Alakite pipes. Diamond bearing eclogites show the some separate levels of crystallization with the high T-range reflecting conditions 35 to 45 mvm-2 mostly in the 60-50 kbar interval. They coincide with the levels of the intensive heating in the mantle columns. For the South Africa in the Mesozoic pipes beneath Lesotho - Jagersfontein (Viljoen ea. 2005), Finsch (Appleyard ea., 2004; Gurney, Switzer, 1973; She ea., 1983), Koffiefontein (Rickard ea., 1986), diamond bearing associations refer to three geotherm branches. The coldest (Cr-pyropes and Mg-Opx) is related to ancient subduction with the heating at 60 and 75 kbars. The 40 mvm-2 is related to the Diam-eclogites (To according to Krogh, 1988), Fe- Opx and chromites. And hottest (45mvm-2) refers to the magmatic type eclogites (cumulates) and some HT chromites (restites). In mantle columns beneath the Proterozoic pipes like Roberts Victor (Souter, Harte, 1988; Jacob ea, 2004), Premier (Gurney ea., 1985; Viljoin ea, 2009) the eclogitic DI trace mostly 40 mvm-2 geotherm but large amount of PT point drops onto advective hottest branch. Mostly eclogites are separated to several branches according to Mg#. The Fe- rich (ancient trondjemitic cumulates) are commonly low-To (LT). Conditions for the mantle beneath Tanzania (Stachel ea, 1998) and Ghana (Stachel ea, 1997) are close to 40mvm-2 geotherm from the deepest~80 kbar level to 35 kbar. The PT estimates for DI from Guinea (Denies, Harris, 2004), those from Angola kimberlites refer to colder geotherm branch. Similar but hotter conditions are detected for the V-Cm kimberlites from Botswana - Venetia (Viljoen ea 2009; Hin et al., 2009) which in mantle columns reveals subadiabatic branch from 1450oC (45mvm-2) but the Late Mesozoic pipes in this region like Letlhakane (Achtenbergh ea, 2001; Stienfenhofer ea, 1997; Deines, Harris, 2004), Orapa (Denies ea., 2009; Stachel ea., 2004) reveal conditions close to 42 mvm-2. PT for mantle xenoliths from the "of craton" Namibian pipes (Louwrensia, Hanous) (Mitchel, 1984; Boyd ea., 2004) trace the G-D boundary or are plotted above it and only relic associations are correspondent to the levels ~65-70 kbar. The PT for OPx and some Cpx in diamonds (Harris ea, 2004) from placers are close to this boundary but those for hot (1400oC) eclogites (magmatic type) are correspondent to the lower levels of mantle columns or coincides with the hottest PT conditions for peridotites. The location of the PT estimate for DI above the Diam -Graph boundary is probably due to metastable crystallization or mantle diapirism. In North America kimberlites the conditions for the DI are mostly LT. Garnet DI from the Diavic mine (Schultze ea, 2008) locate from 50 to 70 kbar near 36 mvm-2 geotherm. Hi-Mg eclogites demonstrate more LT conditions, while the conditions for Hi-Fe eclogite are close to convective 40 mvm-2 branch similar to those for Chromite DI and several points are lose to 45 mvm-2or locate slightly above Diam-Graph. DI from Panda (Tomlinson ea, 2006; Greighton ea, 2009) kimberlites from the same region reveals close PT but are slightly LT. The PT conditions for diamondiferous eclogites from Jericho (Lac De Gras) (Heaman ea, 2004) are most LT in Slave craton (33 -36 mvm-2) at 50-65 kbar range. The eclogitic Cpx and peridotitic pyrope DI (Aulbach et al., 2004) from Buffalo Heard (Banas ea., 2006) at the west of region also trace 36 heating to 40 mvm-2 geotherm at 70 kbar and some more hot PT points trace D-G line. In Wayoming craton the Cr-pyrope DI from low Paleozoic KL-1 pipe (Coopersmith ea ., 2004; Schultze ea 2008) reflect the range 35-40 mvm-2 of heating at lithosphere base 75-65 kbar and more Fe-rich Opx demonstrate HT conditions probably refer to cumulates. Thus the mantle inclusion in different part of the Earth mantle in general repeats the conditions of the whole mantle column. They reflect higher PT gradients in ancient time. In Africa they are hotter in general and often trace advective branches. While in the thicker and colder lithosphere beneath the Slave craton DI reveal colder and deeper in general conditions. In Siberia many of DI especially Chr as well as Diam- eclogites reflect the conditions of the heating and the influence of the protokimberlite melts.

Garnet peridotites from Williams kimberlites, north-central Montana, U.S.A

USGS Publications Warehouse

Hearn, B.C.; McGee, E.S.

1983-01-01

Two Williams kimberlites, 250x350m and 37x390m, in the eastern part of a swarm of 30 middle Eocene alnoitic diatremes in north-central Montana, USA, contain xenoliths of garnet-bearing lherzolites, harzburgites and dunites, in addition to spinel peridotites and upper and lower crustal amphibolites and granulites. Colluvial purple, red, and pink garnets are dominantly Mg- and Cr-rich, indicating their derivation From peridotites or megacrysts, and have CaO and Cr2O3 contents that fall in the lherzolite trend. Temperatures were calculated by the Lindsley-Dixon 20 kb method for lherzolites and by the O'Neill-Wood method for harzburgites and dunites, and pressures were calculated by the MacGregor method, or were assumed to be 50 kb for dunites. Most peridotites equilibrated at 1220-1350?C and 50-60 kb, well above a 44mW/m2 shield geotherm and on or at higher P than the graphite-diamond boundary. Four lherzolites are low T-P (830-990?C, 23-42 kb) and are close to the shield geotherm. All four low T-P lherzolites have coarse textures whereas the high T-P cluster has both coarse and porphyroclastic textures, indicating a range of conditions of deformation and recrystallization in a restricted high T-P range. The tiny size (0.01-0.2 mm) of granulated and euhedral olivines in several xenoliths shows that deformation was occurring just prior to incorporation in kimberlite and that ascent was rapid enough (40-70 km/hr) to retard Further coarsening of fine-grained olivine. For other high T-P peridotites, cessation of deformation and beginning of recrystallization before or during inclusion in kimberlite is suggested by larger (up to 3mm) euhedral olivines in a matrix of fine granulated olivine or by optical continuity of large and nearby small olivines. Two low T-P lherzolites contain distinctive, phlogopite-rimmed, 5-8mm clots of moderate-Cr garnet + Cr-spinel + Cr-diopside + enstatite that are inferred to have formed by reaction of an initial high-Cr garnet brought into the garnet + spinel stability Field. This suggests a reduction in pressure and temperature prior to inclusion in the kimberlite, followed by metasomatic introduction of phlogopite. These textural and compositional variations of peridotites seem most compatible with kimberlite generation and ascent during dynamic diapiric perturbation of the upper mantle.

Carbonate Mineral Assemblages as Inclusions in Yakutian Diamonds: TEM Verifications

NASA Astrophysics Data System (ADS)

Logvinova, A. M.; Wirth, R.; Sobolev, N. V.; Taylor, L. A.

2014-12-01

Carbonate mineral inclusions are quite rare in diamonds from the upper mantle, but are evidence for a carbonate abundance in the mantle. It is believed that such carbonatitic inclusions originated from high-density fluids (HDFs) that were enclosed in diamond during its growth. Using TEM and EPMA, several kinds of carbonate inclusions have been identified in Yakutian diamonds : aragonite, dolomite, magnesite, Ba-, Sr-, and Fe-rich carbonates. Most of them are represented by multi-phase inclusions of various chemically distinct carbonates, rich in Ca, Mg, and K and associated with minor amounts of silicate, oxide, saline, and volatile phases. Volatiles, leaving some porosity, played a significant role in the diamond growth. A single crystal of aragonite (60μm) is herein reported for the first time. This inclusion is located in the center of a diamond from the Komsomolskaya pipe. Careful CL imaging reveals the total absence of cracks around the aragonite inclusion - i.e., closed system. This inclusion has been identified by X-ray diffraction and microprobe analysis. At temperatures above 1000 0C, aragonite is only stable at high pressures of 5-6 GPa. Inside this aragonite, we observed nanocrystalline inclusions of titanite, Ni-rich sulfide, magnetite, water-bearing Mg-silicate, and fluid bubbles. Dolomite is common in carbonate multi-phase inclusions in diamonds from the Internatsionalnaya, Yubileinaya, and Udachnaya kimberlite pipes. Alluvial diamonds of the northeastern Siberian Platform are divided into two groups based on the composition of HDFs: 1) Mg-rich multi-phase inclusions (60% magnesite + dolomite + Fe-spinel + Ti-silicate + fluid bubbles); and 2) Ca-rich multi-phase inclusions (Ca,Ba-, Ca,Sr-, Ca,Fe-carbonates + Ti-silicate + Ba-apatite + fluid bubbles). High-density fluids also contain K. Volatiles in the fluid bubbles are represented by water, Cl, F, S, CO2, CH4, and heavy hydrocarbons. Origin of the second group of HDFs may be related to the non-silicate carbonatitic melt. We consider the primary hydrous, Сa-rich and Mg-poor carbonate melts as having formed in subducted oceanic crust. Variations of carbonate-inclusion compositions among diamonds indicate the variability in the source media during the formation of diamond and may be the result of metasomatic interaction with host rocks.

Structure and evolution of the mantle beneath the Daldyn terrain the comparison of the Alakite and Daldyn kimberlite fields

NASA Astrophysics Data System (ADS)

Ashchepkov, Igor; Ntaflos, Theodoros; Vladykin, Nikolai; Yudin, Denis; Prokopiev, Sergei; Salikhov, Ravil; Travin, Alexei; Kutnenko, Olga

2014-05-01

The Daldyn terrain include two large kimberlite fields Daldyn and Alakite which are to the East and west part of this area correspondingly and referred to the 367-355Ma. The concentrates and mantle xenoliths from the almost 50 kimberlite pipes allow reconstruct the PTXFO2 sections and transects as well as 3D image for the each kimberlite field as well as the for the whole area. In General the common division to the 6 large layers for each parts of SCLM are close but the composition of the layer and rock sequences are different. The Daldyn SCLM is compiled from the alternation of very cold (33 mwm-2) and relatively heated (37-40 mwm-2) large layers while SCLM of Alakite is more uniform and colder in lower part. The Base of the SCLM is much highly heated in Daldyn terrain and in most studied sections are represented by the deformed or HT porphyroclastic peridotites which are rare in the Alakite field. The pyroxenite layer is more thick and pronounced within the Daldyn SCLM. The amount of eclogites and their Mg' number is also higher in general higher in SCLM of Daldyn field The composition of the peridotites are closer to the abyssal MORB peridotites while from Alakit are in general more depleted and closer to continental back arc environment. But the alkalinity of the pyroxenes and abundant metasomatic mineral such as phlogopites and richterites and pargasites are much higher in the Alakite SCKM. The trace elements of primary peridotite Cpx from Alakite SCLM reveal lower melting degrees in Alakite field The boundary between the fields locate between Sytykanskaya and Zagadochnaya pipes is characterized by upwelling of SCLM Base. SCLM layering in eastern part of Daldyn field near the Zarnitsa and Dalnyaya pipe suggests inflexion and is more permeable allowing high scale melt fluid interaction and metasomatism. NE part of the Alakit mantle SCLM from Sytykan to Molodost and further to Fainshteinovskaya pipe is more fertile and consist from the 4 evident units with the Fe# rising upward. In the central part of Alakite region lying on the line Yubileinya - Aykhal pipes and surrounding pipes in clusters represent the most depleted and relatively low metasomatized dunite core. The thermal structure of the Alakite field is in the base is relatively uniform and colder than in Daldyn SCLM. The thermal gradients are more steeper in Alakit mantle. The metasomatic associations in the Daldyn field are marking mainly Archean history in the upper part (2.3-2.5 Ma) of the SCLM (Pokhilenko et al., 2012 and refer the influence of the protokimbelites to the in the lower part ( Ashchepkov et al 2013; Pokhilenko, Alifirova, 2012) . But also the range of the more modern event refer to the Rodinia history (0.7 -1.2 By ) (Pokhilenko et al., 2012 )while or data for the Alakit SCLM mainly mark the modern event from the disseminated abundant metasomatism in the lower in middle part from (1.3 - 0.6 By ). RFBR 11-05-00060; 11-05-91060-PICS.

Sources and mobility of carbonate melts beneath cratons, with implications for deep carbon cycling, metasomatism and rift initiation

NASA Astrophysics Data System (ADS)

Tappe, Sebastian; Romer, Rolf L.; Stracke, Andreas; Steenfelt, Agnete; Smart, Katie A.; Muehlenbachs, Karlis; Torsvik, Trond H.

2017-05-01

Kimberlite and carbonatite magmas that intrude cratonic lithosphere are among the deepest probes of the terrestrial carbon cycle. Their co-existence on thick continental shields is commonly attributed to continuous partial melting sequences of carbonated peridotite at >150 km depths, possibly as deep as the mantle transition zone. At Tikiusaaq on the North Atlantic craton in West Greenland, approximately 160 Ma old ultrafresh kimberlite dykes and carbonatite sheets provide a rare opportunity to study the origin and evolution of carbonate-rich melts beneath cratons. Although their Sr-Nd-Hf-Pb-Li isotopic compositions suggest a common convecting upper mantle source that includes depleted and recycled oceanic crust components (e.g., negative ΔεHf coupled with > + 5 ‰ δ7Li), incompatible trace element modelling identifies only the kimberlites as near-primary low-degree partial melts (0.05-3%) of carbonated peridotite. In contrast, the trace element systematics of the carbonatites are difficult to reproduce by partial melting of carbonated peridotite, and the heavy carbon isotopic signatures (-3.6 to - 2.4 ‰ δ13C for carbonatites versus -5.7 to - 3.6 ‰ δ13C for kimberlites) require open-system fractionation at magmatic temperatures. Given that the oxidation state of Earth's mantle at >150 km depth is too reduced to enable larger volumes of 'pure' carbonate melt to migrate, it is reasonable to speculate that percolating near-solidus melts of carbonated peridotite must be silicate-dominated with only dilute carbonate contents, similar to the Tikiusaaq kimberlite compositions (e.g., 16-33 wt.% SiO2). This concept is supported by our findings from the North Atlantic craton where kimberlite and other deeply derived carbonated silicate melts, such as aillikites, exsolve their carbonate components within the shallow lithosphere en route to the Earth's surface, thereby producing carbonatite magmas. The relative abundances of trace elements of such highly differentiated 'cratonic carbonatites' have only little in common with those of metasomatic agents that act on the deeper lithosphere. Consequently, carbonatite trace element systematics should only be used with caution when constraining carbon mobility and metasomatism at mantle depths. Regardless of the exact nature of carbonate-bearing melts within the mantle lithosphere, they play an important role in enrichment processes, thereby decreasing the stability of buoyant cratons and promoting rift initiation - as exemplified by the Mesozoic-Cenozoic breakup of the North Atlantic craton.

Reactive Transport of Slab-Derived Carbonatitic Melts in the Deep Upper Mantle and Generation of Kimberlites

NASA Astrophysics Data System (ADS)

Sun, C.; Dasgupta, R.

2017-12-01

Kimberlite is a diamond-bearing CO2-rich ultramafic magma from the mantle at depths of >200 km, featured by enrichment of incompatible elements [1]. It has been considered significant for understanding mantle geochemistry and particularly for providing information of deep carbon cycle. Recent experimental studies suggested that partial melts of carbonated peridotites at high pressures and temperatures could resemble the MgO (>20 wt%) and enriched incompatible elements in kimberlites only when the source experienced refertilization with perhaps prior depletion (e.g., [2]). Although addition of CO2 and incompatible elements in the deep mantle is often linked to subducted components, partial melts directly from carbonated oceanic crusts do not have high enough MgO (e.g., ≤8.2 wt%; [3]). A crucial question is how slab-derived CO2-rich melt evolves in reaction with ambient mantle, which may provide a feasible mechanism for kimberlite generation. To investigate the fate of slab-derived carbonatitic melt in the deep ambient mantle, we have performed multi-anvil experiments at 7-10 GPa and 1400-1450 °C. The starting compositions were synthesized by mixing a fertile peridotite composition, KLB-1, with variable proportions (0-45 wt.%) of Ca-rich carbonatitic melt similar to those derived from a carbonated ocean crust at 13-21 GPa [3]. Experiments were performed in Pt, Pt/Gr, Au-Pd and Au-Pd/Gr capsules, and the experimental phases include olivine ± opx + cpx + majoritic garnet ± carbonated silicate melt. With the increase of melt-rock ratios, experimental melts become progressively enriched in CaO (13.0-23.1 wt%) and CO2 (14.2-38.7 wt%) but depleted in MgO (28.9-19.9 wt%), SiO2 (33.1-7.9 wt%), and Al2O3 (2.7-0.2 wt%). The net flux of melt increases with the increase of infiltrating carbonatitic melt proportion and with the decrease of pressure. Kimberlite melts were produced from experiments with 5-25 wt% infiltrating carbonatitic melts by dissolution of olivine and orthopyroxene and precipitation of clinopyroxene. Thus, a localized influx of slab-derived CO2-rich melts can enlarge the mantle porosity, enhance melt focusing, and initiate a channelized flow of kimberlite melts. [1] Becker & Le Roex (2006) J. Pet. 47: 673-703; [2] Brey et al. (2008) J. Pet. 49: 797-821; [3] Thomson et al. (2016) Nature 529: 76-79.

Use of RADARSAT-1 satellite imagery and geophysical data for oil and kimberlite exploration

NASA Astrophysics Data System (ADS)

Paganelli, Flora

The synergy of RADARSAT-1 and seismic imagery interpretation has been applied in the Blackstone area of the Central Alberta Foothills in the Canadian Cordillera thrust and fold belt to map the continuity of geological structures, which are of importance for oil and gas exploration. The reconstruction of the continuity of thrust-fold related major structures known in the area has been successful. Transverse faults and lineaments with ENE-WSW, NE-SW, and NNE-SSW trends have been delineated on the radar images. The ENE-WSW transverse faults have an extensional character, cut across the inner and outer Foothills and are persistent at the regional scale. The NE-SW and NNE-SSW transverse faults are wrench type faults, which are mainly localized in the inner Foothills. These structures have been identified for the first time in the area and are possibly a third generation fault-play type for oil and gas exploration. Principal Component Analysis (PCA) of RADARSAT-1 images was applied in the Buffalo Head Hills area, in the Western Canada Sedimentary Basin (WCSB), to provide an enhanced image base for structural mapping. North- and NNE-trending lineaments bounding the eastern edge of the Buffalo Head Hills along the Loon River valley, a conjugate set of NW- and NE-trending lineaments, and ENE-trending lineaments identifying the latest features in the area were outlined. The development of these structures has been related to Precambrian terrane assemblage in the WCSB during the Early Proterozoic, the development of the Peace River Arch, and the Laramide Orogeny. In the Buffalo Head Hills area a weights of evidence statistical approach was used to determine the spatial relationship of NNE-, NE-, -NW, and ENE-trending lineaments to known kimberlite locations. This method outlined different degrees of spatial correlation between kimberlites and lineaments, with higher correlations defined for the NNE, NE, and ENE lineament datasets. A weights of evidence model was then constructed using the structural lineament maps, the Buffalo High and Buffalo Utikuma terrane boundary, Bouguer gravity data, and magnetic characteristics of the Buffalo High and Buffalo Utikuma terranes. The model reveals maximum favourability for kimberlite exploration along the Buffalo High and Buffalo Utikuma terrane boundary in correspondence with NNE-trending lineaments and their intersections with NE and ENE lineaments. The relationship of the kimberlite occurrences along the Buffalo High-Buffalo Utikuma terrane boundary and structural lineaments seems to favour an hypothesis of kimberlite emplacement through a major zone of weakness in the basement, here characterized by the boundary between the Buffalo High and Buffalo Utikuma terranes.

Tectonic fault monitoring at open pit mine at Zarnitsa Kimberlite Pipe

NASA Astrophysics Data System (ADS)

Vostrikov, VI; Polotnyanko, NS; Trofimov, AS; Potaka, AA

2018-03-01

The article describes application of Karier instrumentation designed at the Institute of Mining to study fracture formation in rocks. The instrumentation composed of three sensors was used to control widening of a tectonic fault intersecting an open pit mine at Zarnitsa Kimberlite Pipe in Yakutia. The monitoring between 28 November and 28 December in 2016 recorded convergence of the fault walls from one side of the open pit mine and widening from the other side. After production blasts, the fault first grows in width and then recovers.

The x ray microprobe determination of chromium oxidation state in olivine from lunar basalt and kimberlitic diamonds

NASA Technical Reports Server (NTRS)

Sutton, S. R.; Bajt, S.; Rivers, M. L.; Smith, J. V.

1993-01-01

The synchrotron x-ray microprobe is being used to obtain oxidation state information on planetary materials with high spatial resolution. Initial results on chromium in olivine from various sources including laboratory experiments, lunar basalt, and kimberlitic diamonds are reported. The lunar olivine was dominated by Cr(2+) whereas the diamond inclusions had Cr(2+/Cr(3+) ratios up to about 0.3. The simpliest interpretation is that the terrestrial olivine crystallized in a more oxidizing environment than the lunar olivine.

Mantle metasomatism in the Kaapvaal Craton lithosphere: constraints on the composition of the metasomatic agent from fluid inclusions in MARID-type xenoliths

NASA Astrophysics Data System (ADS)

Konzett, J.; Krenn, K.; Hauzenberger, Ch.

2012-04-01

The emplacement of both group I and group II kimberlites in the Kaapvaal Craton of the Kimberley region in South Africa is associated with an intense metasomatic alteration of the country rocks as evidenced by a diverse suite of xenoliths sampled by the kimberlites mainly comprising metasomatized peridotites and minor MARID-type xenoliths. These are characterized by hydrous potassic silicates and LILE-HFSE-rich titanates. Because the metasomatic agent is not preserved in these rocks its composition has to be inferred from that of the metasomatic assemblages. Here we present for the first time data on fluid inclusions from two MARID-xenoliths sampled by group-I kimberlites of the Kimberley cluster. They provide direct evidence for the nature of the metasomatic fluids involved in kimberlite-related metsomatism. The xenoliths contain phlogopite+K-richterite+diopside+ilmenite±rutile±apatite±zircon. Fluid inclusions with 4-10 µm in size were found in diopside, K-richterite and zircon and contain L+V+one-to-several daughter phases. Investigations with the freezing and heating stage indicate two different chemical systems for the fluids: (1) H2O-NaCl dominant fluids found as L+V+S inclusions in zircon together with abundant needle-like apatite, rutile and phlogopite solid inclusions. The fluid inclusions in part occur along zircon host-rutile/apatite inclusion grain boundaries which indicates that the fluids were trapped during zircon growth. They contain 30-32 mass% NaCl and show a density of 0.87-0.94 g/cm3. Halos of tiny fluid inclusions, however, indicate that most if not all zircon inclusions are decrepitated during ascent from depth and/or superheating during entrainment of the xenoliths into the kimberlite. Using EMPA, enstatite and a SiO2 polymorph were identified in opened fluid inclusions exposed at the surface of polished thin sections. Because these phases were exclusively found in the fluid inclusions, they are considered daughter crystals. The enstatite composition is identical to that found in the matrix of other MARID xenoliths. Projection on a 40 mW/m2 geotherm of Ca-in-opx temperatures yields ˜950°C/˜4 GPa which are thought to be P and T of MARID-crystallization and fluid entrapment; (2) H2O-CaCl2 dominant fluids trapped in diopside and K-richterite as tubular to rounded L+V inclusions. These inclusions have 35-45 mass% CaCl2 and densities of 0.51-0.98 g/cm3 without any evidence for significant NaCl. During heating all inclusions of this type show a solid with Tm in the range 0-30°C which is consistent with the solid being CaCl2 x 6 H2O. This study provides physical evidence for the presence of saline brines during metasomatism associated with kimberlite emplacement on the Kaapvaal Craton and contributes to the growing body of evidence for the important role of Cl in kimberlite evolution and diamond genesis.

Syn- and post-eruptive volcanic processes in the Yubileinaya kimberlite pipe, Yakutia, Russia, and implications for the emplacement of South African-style kimberlite pipes

NASA Astrophysics Data System (ADS)

Kurszlaukis, S.; Mahotkin, I.; Rotman, A. Y.; Kolesnikov, G. V.; Makovchuk, I. V.

2009-11-01

The Yubileinaya kimberlite pipe, with a surface area of 59 ha, is one of the largest pipes in the Yakutian kimberlite province. The Devonian pipe was emplaced under structural control into Lower Paleozoic karstic limestone. The pipe complex consists of several smaller precursor pipes which are cut by the large, round Main pipe. While the precursor pipes show many features typical for root zones, Main pipe is younger, cuts into the precursor pipes and exposes well-bedded volcaniclastic sediments. The maximum estimated erosion since emplacement is 250 m. Open pit mapping of a 180 m thick kimberlite sequence documents the waning phases of the volcanic activity in the kimberlite pipe and the onset of its crater infill by resedimentation. Three volcanic lithofacies types can be differentiated. The deepest and oldest facies type is a massive volcaniclastic rock ("AKB") only accessible in drill core. It is equivalent to Tuffisitic Kimberlite in South African pipes and thought to be related to the main volcanic phase which was characterized by violent explosions. The overlying lithofacies type comprises primary and resedimented volcaniclastic sediments as well as rock avalanche deposits sourced from the exposed maar crater collar. It represents the onset of sedimentation onto the crater floor during the waning phase of volcanic eruptions, where primary pyroclastic deposition was contemporaneous with resedimentation from the tephra wall and the widening maar crater. Ongoing volcanic activity is also testified by the presence of a vertical feeder conduit marking the area of the last volcanic eruption clouds piercing through the diatreme. This feeder conduit is overlain by the third and youngest lithofacies type which consists mainly of resedimented volcaniclastic material and lake beds. During the sedimentation of this facies, primary volcanic activity was only minor and finally absent and resedimentation processes dominated the crater infill. The Yubileinaya pipe complex exposes root zones, contact breccias as well as diatreme and crater infill sediments. It has all features typical of large South African-style pipes and much can be learned from Yubileinaya about the emplacement sequence and behaviour of these pipes. Emplacement of the pipe occurred over an extended time span with intermittent phases of volcanic quiescence and consolidation. The AKB reveals little direct evidence of what sort of emplacement process was dominant during the main period of volcanic activity. There is neither textural evidence that violent degassing of a juvenile gas phase has caused pipe excavation, nor that external water was present during the main phase of volcanic eruptions. However, there is clear evidence in rock textures that meteoric surface water was present during crater infill. Base surge deposits forming part of the bedded crater infill sequence indicate that water was present in the eruption clouds and, hence, the root zone of the pipe. There is no reason to assume that groundwater did not also have access to the ascending magma during the main phase of volcanic activity that excavated the pipe and formed the AKB.

Mineral inclusions and geochemical characteristics of microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, Canada

NASA Astrophysics Data System (ADS)

Davies, Rondi M.; Griffin, William L.; O'Reilly, Suzanne Y.; Doyle, Buddy J.

2004-09-01

A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148-155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones. Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040-1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very 13C-depleted C-isotope compositions ( δ13C=-35.8‰ to -2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions ( δ13C mode -4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet TNi=800-1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes ( δ13C av.=-5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (˜670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere. Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060-<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of 13C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments.

Inclusions of crichtonite-group minerals in Cr-pyropes from the Internatsionalnaya kimberlite pipe, Siberian Craton: Crystal chemistry, parageneses and relationships to mantle metasomatism

NASA Astrophysics Data System (ADS)

Rezvukhin, Dmitriy I.; Malkovets, Vladimir G.; Sharygin, Igor S.; Tretiakova, Irina G.; Griffin, William L.; O'Reilly, Suzanne Y.

2018-05-01

Cr-pyrope xenocrysts and associated inclusions of crichtonite-group minerals from the Internatsionalnaya kimberlite pipe were studied to provide new insights into processes in the lithospheric mantle beneath the Mirny kimberlite field, Siberian craton. Pyropes are predominantly of lherzolitic paragenesis (Cr2O3 2-6 wt%) and have trace-element spectra typical for garnets from fertile mantle (gradual increase in chondrite-normalized values from LREE to MREE-HREE). Crichtonite-group minerals commonly occur as monomineralic elongated inclusions, mostly in association with rutile, Mg-ilmenite and Cr-spinel within individual grains of pyrope. Sample INT-266 hosts intergrowth of crichtonite-group mineral and Cl-apatite, while sample INT-324 contains polymineralic apatite- and dolomite-bearing assemblages. Crichtonite-group minerals are Al-rich (1.1-4.5 wt% Al2O3), moderately Zr-enriched (1.3-4.3 wt% ZrO2), and are Ca-, Sr-, and occasionally Ba-dominant in terms of A-site occupancy; they also contain significant amounts of Na and LREE. T-estimates and chemical composition of Cr-pyropes imply that samples represent relatively low-T peridotite assemblages with ambient T ranging from 720 to 820°С. Projected onto the 35 mW/m2 cratonic paleogeotherm for the Mirny kimberlite field (Griffin et al., 1999b. Tectonophysics 310, 1-35), temperature estimates yield a P range of 34-42 kbar ( 110-130 km), which corresponds to a mantle domain in the uppermost part of the diamond stability field. The presence of crichtonite-group minerals in Cr-pyropes has petrological and geochemical implications as evidence for metasomatic enrichment of some incompatible elements in the lithospheric mantle beneath the Mirny kimberlite field. The genesis of Cr-pyropes with inclusions of crichtonite-group minerals is attributed to the percolation of Ca-Sr-Na-LREE-Zr-bearing carbonate-silicate metasomatic agents through Mg- and Cr-rich depleted peridotite protoliths. The findings of several potentially new members of the crichtonite group as inclusions in garnet extend existing knowledge on the compositions and occurrences of exotic titanates stable in the lithospheric mantle.

Spectroscopy of Moses Rock Kimberlite Diatreme

NASA Technical Reports Server (NTRS)

Pieters, C. M.; Mustard, J. F.

1985-01-01

Three types of remote sensing data (Airborne Imaging Spectroscopy (AIS), NS001, Zeiss IR-photographs) were obtained for the Moses Rock kimberlite dike in southern Utah. The goal is to identify and characterize the mantle derived mafic component in such volcanic features. The Zeiss and NS001 images provide information on the regional setting and allow units of the dike to be distinguished from surrounding material. A potential unmapped satellite dike was identified. The AIS data provide characterizing information of the surface composition of the dike. Serpentized olivine-bearing soils are (tentatively) identified from the AIS spectra for a few areas within the dike.

Diamonds in an Archean greenstone belt: Diamond suites in unconventional rocks of Wawa, Northern Ontario (Canada)

NASA Astrophysics Data System (ADS)

Kopylova, Maya; Bruce, Loryn; Ryder, John

2010-05-01

Diamonds typically are found on Archean cratons entrained by younger Phanerozoic kimberlites. In contrast, Wawa diamonds are hosted in "unconventional", non-kimberlitic rocks that formed contemporaneously with the mafic and sedimentary rocks of the Archean Michipicoten Greenstone Belt (MGB). We studied two diamond suites that occur within the 2.9-2.7 Ga greenschist facies rocks of MGB located in the southwest portion of the Superior Craton (E. Canada). The first diamond suite henceforth referred to as the Wawa breccia diamonds (384 stones), are hosted in the 2618-2744 Ma calc-alkaline lamprophyres and volcaniclastic breccias, contemporaneous with pillow basalts and felsic volcanics of MGB. The second suite, the Wawa conglomerate diamonds (80 crystals), are hosted in the 2697-2700 Ma poorly sorted sedimentary polymictic conglomerate which is interpreted as a proximal alluvial fan debris flow in a fan-delta environment. The majority of the diamonds was found within the matrix of the conglomerate. The diamondiferous breccia occurs 20 km north of the town of Wawa, whereas the conglomerate is found 12 km northeast of Wawa. Diamonds from the 2 occurrences were characterized and described for provenance studies. Both the breccia and conglomerate diamonds show similar crystal habits, with the predominance of octahedral single crystals and ~ 10% of cubes. The conglomerate diamonds are significantly less resorbed (no resorbtion in 43% of the stones) than the breccia diamonds (8% non-resorbed stones). In both suites, only 21-24% show high degrees of resorption. The majority of crystals in both suites are colourless, with some yellow, brown and grey stones. Conglomerate diamonds had a wider variety of colours that were not seen in the breccia diamonds, including green and pink. The breccia diamonds contain 0-740 ppm N and show two modes of N aggregation at 0-30 and 60-95%. Among the breccia diamonds, Type IaA stones comprise 17%, whereas IaAB stones make up 49% of the population. Diamonds from the conglomerate have nitrogen contents below 400 ppm N, with 47% of the suite being Type IaA stones. Approximately one third of the conglomerate and breccia diamonds belongs to Type II having no measurable N. The two suites of Wawa diamonds, according to the morphology and nitrogen studies, are deemed to be different. The conglomerate diamonds are significantly less resorbed and contain less aggregated N. The diamonds that occur in the Wawa breccia and conglomerate have different primary volcanic sources. We suggest that the primary volcanic rock of the conglomerate diamonds may be a kimberlite, as kimberlitic indicator minerals are found in the matrix of the conglomerate. These indicator minerals garnet, Cr diopside and ilmenite are absent from the diamoniferous lamprophyric breccias. The hypothetical kimberlites may have occured in proximity to the conglomerates as suggested by low mechanical abrasion of the conglomerate diamonds and indicator minerals, and the preservation of garnet kelyphitic rims and Cr-diopside. Our study infers an episode of the Archean, pre-2.7 Ga kimberlite magmatism in MGB, which also experienced multiple emplacement episodes of the 2.7 Ga syn-orogenic diamondiferous calc-alkaline lamprophyres. Despite the distinct origins of the breccia and conglomerate diamonds, they all have similar red-orange-green cathodoluminescence colours controlled by the CL emission mainly at 520 nm. This contrasts with the prevalent CL emission at 415-440 nm commonly observed in kimberlitic and detrital diamonds. We ascribe the red-orange-green CL colours of the two diamond suites of Wawa to the late imprint of metamorphism.

Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor mine, South Africa

USGS Publications Warehouse

Manton, W.I.; Tatsumoto, M.

1971-01-01

Five nodules of eclogite, one nodule of garnet peridotite and one sample of kimberlite from the Roberts Victor mine were analyzed for concentrations of U, Th, Pb, Rb and Sr and isotopic compositions of Pb and Sr. In the eclogites, U content ranges from 0.09 to 0.26 ppm, Th from 0.35 to 1.1 ppm, Pb from 0.79 to 5.5 ppm, Rb from 2.1 to 28 ppm and Sr from 133 to 346 ppm; 206Pb/204Pb ratios range from 14.8 to 18.5, 207Pb/204Pb from 14.9 to 15.7, 208Pb/204Pb from 35.2 to 38.5. The garnet peridotite contains 0.22 ppm U, 0.97 ppm Th, 1.05 ppm Pb, 6.9 ppm Rb and 108 ppm Sr and the kimberlite contains 2.5 ppm U, 30 ppm Th, 37 ppm Pb, 113 ppm Rb and 2040 ppm Sr. The lead in the eclogites has two components, a lead pyroextractable at 1100-1200?? and a non-pyroextractable residual lead. In three of the eclogites, which are to some extent altered, a proportion of the pyroextractable lead may be contaminating lead from the kimberlite, but an altered kyanite eclogite does not appear to be contaminated by this same kimberlite. The pyroextractable lead from a less altered eclogite contains a much larger proportion of 206Pb. Compositions calculated for the residual leads vary greatly. In many of the pyroextraction runs the primary eclogitic phases disappeared and the new phases plagioclase, clinopyroxene and a magnetic iron compound were formed. Why part of the lead should have been retained by these new phases is not understood. ?? 1971.

Subcalcic diopsides from kimberlites: Chemistry, exsolution microstructures, and thermal history

USGS Publications Warehouse

McCallister, R.H.; Nord, G.L.

1981-01-01

Twenty-six subcalcic diopside megacrysts (Ca/(Ca+ Mg)) = 0.280-0.349, containing approximately 10 mol% jadeite, from 15 kimberlite bodies in South Africa, Botswana, Tanzania, and Lesotho, have been characterized by electron microprobe analysis, X-ray-precession photography, and transmission electron microscopy. Significant exsolution of pigeonite was observed only in those samples for which Ca/(Ca+Mg)???0.320. The exsolution microstructure consists of coherent (001) lamellae with wavelengths ranging from 20 to 31 nm and compositional differences between the hosts and lamellae ranging from 10 to 30 mol% wollastonite. These observations suggest that the exsolution reaction mechanism was spinodal decomposition and that the megacrysts have been quenched at various stages of completion of the decomposition process. Annealing experiments in evacuated SiO2 glass tubes at 1,150?? C for 128 hours failed to homogenize microstructure, whereas, at 5 kbar and 1,150?? C for only 7.25 hours, the two lattices were homogenized. This "pressure effect" suggests that spinodal decomposition in the kimberlitic subcalcic diopside megacrysts can only occur at depths less than ???15 km; the cause of the effect may be the jadeite component in the pyroxene. "Apparent quench" temperatures for the exsolution process in the megacrysts range from 1,250?? C to 990?? C, suggesting that decomposition must have commenced at temperatures of more than ???1,000?? C. These P-T limits lead to the conclusion that, in those kimberlites where spinodal decomposition has occurred in subcalcic diopside megacrysts, such decomposition occurred at shallow levels (<15 km) and, at the present erosion level, temperatures must have been greater than 1,000?? C. ?? 1981 Springer-Verlag.

Mantle transition zone input to kimberlite magmatism near a subduction zone: Origin of anomalous Nd-Hf isotope systematics at Lac de Gras, Canada

NASA Astrophysics Data System (ADS)

Tappe, Sebastian; Graham Pearson, D.; Kjarsgaard, Bruce A.; Nowell, Geoff; Dowall, David

2013-06-01

Late Cretaceous-Eocene kimberlites from the Lac de Gras area, central Slave craton, show the most extreme Nd-Hf isotope decoupling observed for kimberlites worldwide. They are characterized by a narrow range of moderately enriched Nd isotope compositions (ɛNd(i)=-0.4 to -3.5) that contrasts strongly with their moderately depleted to highly enriched ɛHf(i) values (+3.9 to -9.9). Although digestion of cratonic mantle material in proto-kimberlite melt can theoretically produce steep arrays in Nd-Hf isotope space, the amount of contaminant required to explain the Lac de Gras data is unrealistic. Instead, it is more plausible that mixing of compositionally discrete melt components within an isotopically variable source region is responsible for the steep Nd-Hf isotope array. As development of strongly negative ΔɛHf requires isotopic aging of a precursor material with Sm/Nd≫Lu/Hf for billion-year timescales, a number of models have been proposed where ancient MORB crust trapped in the mantle transition zone is the ultimate source of the extreme Hf isotope signature. However, we provide a conceptual modification and demonstrate that OIB-type domains within ancient subducted oceanic lithosphere can produce much stronger negative ΔɛHf during long-term isolation. Provided that these OIB-type domains have lower melting points compared with associated MORB crust, they are among the first material to melt within the transition zone during thermal perturbations. The resulting hydrous alkali silicate melts react strongly with depleted peridotite at the top of the transition zone and transfer negative ΔɛHf signatures to less dense materials, which can be more easily entrained within upward flowing mantle. Once these entrained refertilized domains rise above 300 km depth, they may become involved in CO2- and H2O-fluxed redox melting of upper mantle peridotite beneath a thick cratonic lid. We argue that incorporation of ancient transition zone material, which includes ultradeep diamonds, into the convecting upper mantle source region of Lac de Gras kimberlites was due to vigorous mantle return flow. This occurred in direct response to fast and complex subduction along the western margin of North America during the Late Cretaceous.

Timing of Precambrian melt depletion and Phanerozoic refertilization events in the lithospheric mantle of the Wyoming Craton and adjacent Central Plains Orogen

USGS Publications Warehouse

Carlson, R.W.; Irving, A.J.; Schulze, D.J.; Hearn, B.C.

2004-01-01

Garnet peridotite xenoliths from the Sloan kimberlite (Colorado) are variably depleted in their major magmaphile (Ca, Al) element compositions with whole rock Re-depletion model ages generally consistent with this depletion occurring in the mid-Proterozoic. Unlike many lithospheric peridotites, the Sloan samples are also depleted in incompatible trace elements, as shown by the composition of separated garnet and clinopyroxene. Most of the Sloan peridotites have intermineral Sm-Nd and Lu-Hf isotope systematics consistent with this depletion occurring in the mid-Proterozoic, though the precise age of this event is poorly defined. Thus, when sampled by the Devonian Sloan kimberlite, the compositional characteristics of the lithospheric mantle in this area primarily reflected the initial melt extraction event that presumably is associated with crust formation in the Proterozoic-a relatively simple history that may also explain the cold geotherm measured for the Sloan xenoliths. The Williams and Homestead kimberlites erupted through the Wyoming Craton in the Eocene, near the end of the Laramide Orogeny, the major tectonomagmatic event responsible for the formation of the Rocky Mountains in the late Cretaceous-early Tertiary. Rhenium-depletion model ages for the Homestead peridotites are mostly Archean, consistent with their origin in the Archean lithospheric mantle of the Wyoming Craton. Both the Williams and Homestead peridotites, however, clearly show the consequences of metasomatism by incompatible-element-rich melts. Intermineral isotope systematics in both the Homestead and Williams peridotites are highly disturbed with the Sr and Nd isotopic compositions of the minerals being dominated by the metasomatic component. Some Homestead samples preserve an incompatible element depleted signature in their radiogenic Hf isotopic compositions. Sm-Nd tie lines for garnet and clinopyroxene separates from most Homestead samples provide Mesozoic or younger "ages" suggesting that the metasomatism occurred during the Laramide. Highly variable Rb-Sr and Lu-Hf mineral "ages" for these same samples suggest that the Homestead peridotites did not achieve intermineral equilibrium during this metasomatism. This indicates that the metasomatic overprint likely was introduced shortly before kimberlite eruption through interaction of the peridotites with the host kimberlite, or petrogenetically similar magmas, in the Wyoming Craton lithosphere. ?? 2004 Elsevier B.V. All rights reserved.

Prospecting history leading to the discovery of Botswana's diamond mines: from artefacts to Lesedi La Rona

NASA Astrophysics Data System (ADS)

de Wit, Michiel C. J.

2018-02-01

Bechuanaland/Botswana has a long and colourful history in exploration and mining. Here these activities are subdivided into three phases: pre-historic, historic and modern. Quarrying stone in Botswana was ongoing 500,000 years ago during the Early Stone Age (ESA). Actual mining of stones probably only started during the Middle Stone Age (MSA) i.e. post 250,000 BP, and the first prehistoric hard rock mining of specularite and limonite, likely started during the Late Stone Age (LSA) 20,000 to 2,000 BP. In east Botswana iron and copper were mined from AD 800 onwards; the mining of gold started in the thirteenth century. Historic mining started with the re-discovery of gold close to Francistown in 1865 and lasted until the 1950s. Rumours of diamonds in Bechuanaland had already surfaced in the 1880s, and it was Ngamiland, in the northwest, that was first explored systematically for diamonds and gold between 1896 and 1899. A joint initiative between Anglo American and De Beers started serious prospecting parts of eastern Bechuanaland between 1932 and 1938; and in 1938 the first diamond finds in Bechuanaland were reported. Modern mining and exploration started with the signing of an agreement in 1959, allowing Consolidated African Selection Trust Ltd (CAST) into the Bamangwato Tribal Reserve. CAST found a few diamonds in the Motloutse River, but concluded that these were reworked and dropped the exploration rights. De Beers believed that these diamonds had come from west of the Motloutse headwaters, across the watershed in the Kalahari. This ultimately led to the discovery of the Orapa kimberlite field in 1967, a year after Botswana became independent. This discovery triggered a major exploration boom across Botswana adding important diamond-bearing kimberlites such as at Letlhakane (1968), Jwaneng (1973), Gope (1981) and Lerala (1991).

X-ray topographic study of diamonds: implications for the genetic nature of inclusions in diamond

NASA Astrophysics Data System (ADS)

Agrosì, Giovanna; Nestola, Fabrizio; Tempesta, Gioacchino; Bruno, Marco; Scandale, Eugenio; Harris, Jeff W.

2014-05-01

In recent years, several studies have focused on the growth conditions of the diamonds through the analysis of the mineral inclusions trapped in them (Howell, 2012 and references therein). Nevertheless, to obtain rigorous information about chemical and physical conditions of diamond formation, it is crucial to determine if the crystallization of the inclusions occurred before (protogenetic nature), during (syngenetic nature) or after (epigenetic nature) the growth of diamond (Wiggers de Vries et al., 2011). X-ray topography (XRDT) can be a helpful tool to verify the genetic nature of inclusions in diamond. This technique characterizes the extended defects and reconstructs the growth history of the samples (Agrosì et al., 2013 and references therein) and, consequently contributes to elucidation of the relationship between the inclusions and the host-diamond. With this aim a diamond from the Udachnaya kimberlite, Siberia, was investigated. The diamond crystal was the one previously studied by Nestola et al. (2011) who performed in-situ crystal structure refinement of the inclusions to obtain data about the formation pressure. The inclusions were iso-oriented olivines that did not show evident cracks and subsequently could not be considered epigenetic. Optical observations revealed an anomalous birefringence in the adjacent diamond and the inclusions had typical "diamond-imposed cubo-octahedral" shape for the largest olivine. The diffraction contrast study shows that the diamond exhibits significant deformation fields related to plastic post growth deformation. The crystallographic direction of strains was established applying the extinction criterion. Section topographs were taken to minimize the overlapping of the strain field associate with the different defects and revealed that no dislocations nucleated from the olivine inclusions. Generally, when a solid inclusion has been incorporated in the growing crystal, the associated volume distortion can be minimized by means the nucleation of dislocations and/or twinning (Agrosì et al., 2013). In our case, the specific and significant features - the olivine inclusions showing a "diamond imposed cubo-octahedral shape" and no dislocation nucleation - that characterize this sample will be discussed in detail. References: F Nestola, P Nimis, L Ziberna, M Longo, A Marzoli, JW Harris, MH Manghnani (2011): Earth and Planetary Science Letters 305 (1), 249-255. Howell, D. (2012): Eur. J. Mineral., 24, 575-585. Wiggers de Vries D.F., Drury M.R., de Winter D.A. M., Bulanova G P., Pearson D. G., Davies G. R. (2011): Contrib. Mineral. Petrol. 161, 565-579. Agrosì G., Tempesta G., Scandale E., Harris J.W. (2013): Eur. J. Mineral, 25 (4), 551-559.

Distribution of radioactive isotopes in rock and ore of Arkhangelskaya pipe from the Arkhangelsk diamond province

NASA Astrophysics Data System (ADS)

Kiselev, G. P.; Yakovlev, E. Yu.; Druzhinin, S. V.; Galkin, A. S.

2017-09-01

The contents of radioactive elements and the uranium isotopic composition of kimberlite in the Arkhangelskaya pipe at the M.V. Lomonosov deposit and of nearby country rocks have been studied. A surplus of 234U isotope has been established in rocks from the near-pipe space. The high γ = 234U/238U ratio is controlled by the geological structure of the near-pipe space. A nonequilibrium uranium halo reaches two pipe diameters in size and can be regarded as a local ore guide for kimberlite discovery. The rocks in the nearpipe space are also characterized by elevated or anomalous U, Th, and K contents with respect to the background.

Evolution of diamond resorption in a silicic aqueous fluid at 1-3 GPa: Application to kimberlite emplacement and mantle metasomatism

NASA Astrophysics Data System (ADS)

Zhang, Zhihai; Fedortchouk, Yana; Hanley, Jacob J.

2015-06-01

Natural diamonds grow and partially dissolve during mantle metasomatism and undergo further resorption during the ascent to the Earth's surface in kimberlite magmas. This study uses atomic force microscopy (AFM) for quantitative characterization of diamond resorption morphology in order to provide robust constraints of the composition of kimberlitic and mantle metasomatic fluids. We performed experiments in a piston-cylinder apparatus at pressures (P) of 1-3 GPa and temperatures (T) of 1150-1400 °C to examine the impact of P, T, and silica content of an aqueous fluid on diamond dissolution. Petrographic observation and microthermometry of synthetic fluid inclusions trapped in olivine at the run conditions provide constraints on the composition and density of the fluid reacting with the diamond. Our results confirm an inverse relationship between P and T on diamond dissolution kinetics. A P increase of 1 GPa suppresses diamond oxidation rates by the same value as a T decrease by 50 °C, while the transformation rate of diamond crystal morphology from octahedron to tetrahexahedron increases with both P and T. All dissolved diamonds develop glossy surfaces, ditrigonal {111} faces, sheaf striations, and negative trigons, while circular pits only occur in aqueous fluids with low silica content (≤ 4.2 mol/kg) at 1 GPa. We identify five distinct morphological groups of trigons: two types of point-bottomed (p/b) (trumpet- and V-shaped) and three types of flat-bottomed (f/b) (trumpet-shaped, trapezoid-shaped and rounded). AFM measurements of trigons from two successive runs showed three stages of their evolution. Etch pits nucleate at defects as trumpet p/b trigons with the vertical dissolution rate (Vd) faster than the dissolution rates at the surface free of defects; they further develop by growth of the bottoms in (111) plane to create trumpet-shaped f/b trigons accompanied by decrease in Vd; and finally form trapezoid-shaped f/b trigon with constant wall angles. The diameter of f/b trigons developed in the aqueous fluids depends on the diamond weight loss and dissolution kinetics, and does not correlate with their depth. Integration of our AFM data with the theoretical model for trigon formation suggests that the change from point- to flat-bottomed trigons depends on the defect sizes and dissolution conditions. Application of our results to the diamonds from Ekati diamond Mine, Canada, suggests that variations in diamond rounding in different pipes implies variable depth of fluid exsolution; presence of circular pits on diamonds indicates predominantly aqueous fluid during the latest stages of kimberlite emplacement; and comparison to the mantle-derived morphologies on Ekati diamonds implies the importance of CO2-rich fluids and/or carbonate melts during mantle metasomatism. The constrained effect of P on diamond dissolution kinetics indicates that appreciable diamond weight loss can only happen at P < 1 GPa and therefore the conditions at the latest stages of kimberlite emplacement are very important for assessments of diamond preservation in a kimberlite pipe.

Lunar breccias, petrology, and earth planetary structure

NASA Technical Reports Server (NTRS)

Ridley, W. I.

1978-01-01

Topics covered include: (1) petrologic studies of poikiloblastic textured rocks; (2) petrology of aluminous mare basalts in breccia 14063; (3) petrology of Apollo 15 breccia 15459; (4) high-alumina mare basalts; (5) some petrological aspects of imbrium stratigraphy; (6) petrology of lunar rocks and implication to lunar evolution; (7) the crystallization trends of spinels in Tertiary basalts from Rhum and Muck and their petrogenetic significance; (8) the geology and evolution of the Cayman Trench; (9) The petrochemistry of igneous rocks from the Cayman Trench and the Captains Bay Pluton, Unalaska Island and their relation to tectonic processes at plate margins; and (10) the oxide and silicate mineral chemistry of a Kimberlite from the Premier Mine with implications for the evolution of kimberlitic magma.

Garnet peridotite xenoliths in a Montana, U.S.A., kimberlite

USGS Publications Warehouse

Carter, Hearn B.; Boyd, F.R.

1975-01-01

Within a swarm of late middle Eocene subsilicic-alkalic diatremes, one diatreme 270 by 370 m and an associated dike contain common xenoliths of granulite and rare xenoliths of spinel peridotite and garnet peridotite. Six garnet lherzolite xenoliths have been found and these show a range of textures. Four are granular, and two are intensely sheared. Phlogopite is absent from the intensely sheared xenoliths and is thought to be primary in part in the granular xenoliths. Estimated temperatures and depths of equilibration of xenolith pyroxenes range from 920??C, 106 km (32 kbar) to 1315??C, 148 km (47 kbar). The xenoliths show increasing amounts of deformation with greater inferred depths of origin. The temperature-depth points suggest a segment of an Eocene geotherm for Montana which is similar in slope to the steep portion of the pyroxene-determined Lesotho geotherm (Boyd and Nixon, this volume) and is considerably steeper than typical calculated shield and continental geotherms at present. The steep trend could be a result of plate-tectonic shearing and magma ascension within an Eocene low-velocity zone. Preservation of intensely sheared textures requires rapid transport of material from about 150 km depth during active deformation of relatively dry rock. The occurrence of monticellite peridotite in this kimberlite diatreme suggests that magmas which crystallized to monticellite peridotite at relatively shallow depth could be one of the primitive types of kimberlite magma. ?? 1975.

Kimberlite Wall Rock Fragmentation: Venetia K08 Pipe Development

NASA Astrophysics Data System (ADS)

Barnett, W.; Kurszlaukis, S.; Tait, M.; Dirks, P.

2009-05-01

Volcanic systems impose powerful disrupting forces on the country rock into which they intrude. The nature of the induced brittle deformation or fragmentation can be characteristic of the volcanic processes ongoing within the volcanic system, but are most typically partially removed or obscured by repeated, overprinting volcanic activity in mature pipes. Incompletely evolved pipes may therefore provide important evidence for the types and stages of wall rock fragmentation, and mechanical processes responsible for the fragmentation. Evidence for preserved stages of fragmentation is presented from a detailed study of the K08 pipe within the Cambrian Venetia kimberlite cluster, South Africa. This paper investigates the growth history of the K08 pipe and the mechanics of pipe development based on observations in the pit, drill core and thin sections, from geochemical analyses, particle size distribution analyses, and 3D modeling. Present open pit exposures of the K08 pipe comprise greater than 90% mega-breccia of country rock clasts (gneiss and schist) with <10% intruding, coherent kimberlite. Drill core shows that below about 225 m the CRB includes increasing quantities of kimberlite. The breccia clasts are angular, clast-supported with void or carbonate cement between the clasts. Average clast sizes define sub-horizontal layers tens of metres thick across the pipe. Structural and textural observations indicate the presence of zones of re-fragmentation or zones of brittle shearing. Breccia textural studies and fractal statistics on particle size distributions (PSD) is used to quantify sheared and non- sheared breccia zones. The calculated energy required to form the non-sheared breccia PSD implies an explosive early stage of fragmentation that pre-conditions the rock mass. The pre-conditioning would have been caused by explosions that are either phreatic or phreatomagmatic in nature. The explosions are likely to have been centered on a dyke, or pulses of preceding volatile-fluid phases, which have encountered a local hydrologically active fault. The explosions were inadequate in mechanical energy release (72% of a mine production blast) to eject material from the pipe, and the pipe may not have breached surface. The next stage of fragmentation is interpreted to have been an upward-moving collapse of the pre-conditioned hanging wall of a subterranean volcanic excavation. This would explain the mega-scale layering across the width of the breccia pipe. It must be questioned whether the preserved K08 architecture represents early pipe development in general, or is a special case of a late pipe geometry modification process. Previous literature describes sidewall and hanging wall caving processes elsewhere in the Venetia cluster and other kimberlites world wide. A requirement for emplacement models that include upward pipe growth processes is the availability of space (mass deficit at depth) into which the caving and/or dilating breccia can expand. It is possible that K08 might be connected to adjacent K02 at a depth somewhere below 400m, which would explain the presence of volcaniclastic kimberlite at depth within the K08 pipe. K08 is likely an incomplete ancillary sideward development to K02. The latest stage of brecciation is quantified through an observed evolution in the fractal dimension of the PSD. It is interpreted to be due to complex adjustments in volume in the pipe causing shearing and re-fragmentation of the breccia.

Diffusion of helium, hydrogen and deuterium in diamond: Experiment, theory and geochemical applications

NASA Astrophysics Data System (ADS)

Cherniak, D. J.; Watson, E. B.; Meunier, V.; Kharche, N.

2018-07-01

Diffusivities of helium, deuterium and hydrogen have been characterized in diamond. Polished CVD diamond was implanted with either 3He, 2H, or 1H. Implanted samples were sealed under vacuum in silica glass capsules, and annealed in 1-atm furnaces. 3He, 2H and 1H distributions were measured with Nuclear Reaction Analysis. We obtain these Arrhenius relations: DHe = 4.00 × 10-15 exp(-138 ± 14 kJ mol-1/RT) m2 s-1. D2H = 1.02 × 10-4 exp(-262 ± 17 kJ mol-1/RT) m2 s-1. D1H = 2.60 × 10-4 exp(-267 ± 15 kJ mol-1/RT) m2 s-1. Diffusivities of 1H and 2H agree within experimental uncertainties, indicating little diffusive mass fractionation of hydrogen in diamond. To complement the experimental measurements, we performed calculations using a first-principles quantum mechanical description of diffusion in diamond within the Density Functional Theory (DFT). Differences in 1H and 2H diffusivities from calculations are found to be ∼4.5%, reflected in differences in the pre-exponential factor. This small difference in diffusivities, despite the large relative mass difference between these isotopes, is due to the fact that the atomistic process involved in the transition along the diffusion pathway is dictated by local changes to the diamond structures rather than to vibrations involving 1H/2H. This finding is consistent with the experimental results given experimental uncertainties. In contrast, calculations for helium diffusion in diamond indicate a difference of 15% between diffusivities of 3He and 4He. Calculations of diffusion distances for hydrogen using our data yield a distance of 50 μm in diamond in 300,000 years at 500 °C and ∼30 min at 1400 °C. Diffusion distances for He in diamond are shorter than for H at all temperatures above ∼350 °C, but differences increase dramatically with temperature because of the higher activation energy for H diffusion. For example, a 50 μm diffusion distance for He would be attained in ∼40 Myr at 500 °C and 400 yr at 1400 °C. For comparison, a 50 μm diffusion distance for N in diamond would require nearly 1 billion years at 1400 °C. The experimental data indicate that diamonds equilibrate with ambient H and He in the mantle on timescales brief relative to most geological processes and events. However, He diffusion in diamond is slower than in any other mineral measured to date, including other kimberlite-hosted minerals. Under some circumstances, diamond may provide information about mantle He not recoverable from other minerals. One possibility is diamonds entrained in kimberlites. Since the ascent of kimberlite from the mantle to near-surface is very rapid, entrained diamonds may retain most or all of the H and He acquired in mantle environments. Calculations using reasonable ascent rates and T-t paths indicate that He diffusive loss from kimberlite-hosted diamonds is negligible for grains of 1.0-0.2 mm radius, with fractional losses <0.15% for all ascent rates considered. If the host kimberlite magma is effectively quenched in the near-surface (or is erupted), diamonds should contain a faithful record of [He] and He isotopes from the mantle source region. Preservation of H in kimberlite-hosted diamonds is less clear-cut, with model outcomes depending critically upon rates of ascent and cooling.

Distribution and origin of diamonds in Brazil: An overview

NASA Astrophysics Data System (ADS)

Svisero, Darcy P.

1995-12-01

Brazil was the first western country to produce diamonds from the washing of alluvial deposits found in central Minas Gerais in the early 1700s. For a century the country remained the world's greatest producer, losing its position only after the discovery of the Kimberley field in South Africa. Currently there are placer deposits (garimpos) scattered throughout the majority of the states with official production averaging 1,000,000 ct/y. Mechanized exploitation using modern dredges has succeeded in only two distinct localities: along the Jequitinhonha River (Diamantina) and at the Fazenda Camargo (Mato Grosso). Large diamonds of several hundred carats have been found periodically in the area of the municipalities of Abaeté and Coromandel in western Minas Gerais State. Carbonado, a polycrystalline variety of diamond, was intensively mined in several localities of the Chapada Diamantina in central Bahia State, mainly in the second half of the last century. Kimberlite-type rocks, on the other hand, were discovered only in the late 1960s, first in the Coromandel area in Minas Gerais and later in Goiás, Mato Grosso, Rondônia and Piauí States. Little is yet known about these intrusions, mainly because the discoveries have been made by foreign companies operating in the country. Detailed studies reported during the Kimberlite Conference of Araxá in 1991 revealed that some intrusions of the Coromandel area have mineralogical and petrographical characteristics, as well as major chemical element compositions, similar to worldwide kimberlites. However, their isotopic signatures in terms of Sr and Nd are intermediate between Groups I and II kimberlites of South Africa. As to mineral inclusions, Brazilian diamonds contain the common phases of olivine, garnets, pyroxenes, sulphides and oxides as observed in diamonds elsewhere. Furthermore, diamonds from the São Luis River in northern Mato Grosso contain, in addition to garnet and pyroxene, periclase, ferripericlase, wüstite, nickel, iron-nickel alloy and moissanite. This high-pressure assemblage resembles the mineralogy predicted for depths of ~650 km, thus suggesting an asthenospheric origin for the São Luis diamonds. This paper presents a review of general aspects of the most representative deposits of diamonds in Brazil. Field relationships point to the existence of at least three distinct ages for the secondary source rocks as illustrated by the Upper Proterozoic metaconglomerates of Diamantina, the Permo-Carboniferous diamictites of Tibagi and the Upper Cretaceous conglomerates of the Romaria Mine. The primary sources remain unknown in all localities. Additional comments are provided on the findings of great diamonds, diamond inclusions and on the study of kimberlite-type rocks carried out in the country in the past two decades.

Subducted slab-plume interaction traced by magnesium isotopes in the northern margin of the Tarim Large Igneous Province

NASA Astrophysics Data System (ADS)

Cheng, Zhiguo; Zhang, Zhaochong; Xie, Qiuhong; Hou, Tong; Ke, Shan

2018-05-01

Incorporation of subducted slabs may account for the geochemical and isotopic variations of large igneous provinces (LIPs). However, the mechanism and process by which subducted slabs are involved into magmas is still highly debated. Here, we report a set of high resolution Mg isotopes for a suite of alkaline and Fe-rich rocks (including basalts, mafic-ultramafic layered intrusions, diabase dykes and mantle xenoliths in the kimberlitic rocks) from Tarim Large Igneous Province (TLIP). We observed that δ26 Mg values of basalts range from -0.29 to - 0.45 ‰, -0.31 to - 0.42 ‰ for mafic-ultramafic layered intrusions, -0.28 to - 0.31 ‰ for diabase dykes and -0.29 to - 0.44 ‰ for pyroxenite xenoliths from the kimberlitic rocks, typically lighter than the normal mantle source (- 0.25 ‰ ± 0.04, 2 SD). After carefully precluding other possibilities, we propose that the light Mg isotopic compositions and high FeO contents should be ascribed to the involvement of recycled sedimentary carbonate rocks and pyroxenite/eclogite. Moreover, from basalts, through layered intrusions to diabase dykes, (87Sr/86Sr)i values and δ18OV-SMOW declined, whereas ε (Nd) t and δ26 Mg values increased with progressive partial melting of mantle, indicating that components of carbonate rock and pyroxenite/eclogite in the mantle sources were waning over time. In combination with the previous reported Mg isotopes for carbonatite, nephelinite and kimberlitic rocks in TLIP, two distinct mantle domains are recognized for this province: 1) a lithospheric mantle source for basalts and mafic-ultramafic layered intrusions which were modified by calcite/dolomite and eclogite-derived high-Si melts, as evidenced by enriched Sr-Nd-O and light Mg isotopic compositions; 2) a plume source for carbonatite, nephelinite and kimberlitic rocks which were related to magnesite or periclase/perovskite involvement as reflected by depleted Sr-Nd-O and extremely light Mg isotopes. Ultimately, our study suggests that subducted slabs could make important contributions to LIP generation, and establishes a potential linkage between plate tectonics and mantle plume.

High-pressure behaviour of Cr-Fe-Mg-Al spinels: applications to diamond geobarometry

NASA Astrophysics Data System (ADS)

Periotto, Benedetta; Bruschini, Enrico; Nestola, Fabrizio; Lenaz, Davide; Princivalle, Francesco; Andreozzi, Giovanni B.; Bosi, Ferdinando

2014-05-01

Spinels belonging to the chromite - magnesiochromite - hercynite (FeCr2O4-MgCr2O4-FeAl2O4) system are among the most common inclusions found in diamonds (Stachel and Harris 2008). In particular, although FeCr2O4 and MgCr2O4 components sum to between 85 and 88% of spinels found in diamonds, hercynite FeAl2O4 plays a not negligible role in determining their thermo-elastic properties with concentrations reaching 7-9 % (other minor end-members like MgAl2O4, MgFe2O4 and Fe2O3 rarely reach 2-3% in total, see Lenaz et al. 2009). Recent studies were focused on the determination of the diamond formation pressure by the so-called "elastic method" (see for example Nestola et al. 2011 and references therein). It was demonstrated that accurate and precise thermo-elastic parameters are fundamental to minimize the uncertainty of formation pressure. In this work we have determined the equations of state at room temperature of three synthetic spinel end-members chromite - magnesiochromite - hercynite and one natural spinel crystal extracted from a diamond (from Udachnaya mine, Siberia, Russia) by single-crystal X-ray diffraction in situ at high-pressure. A diamond-anvil cell was mounted on a STADI IV diffractometer equipped with a point detector and motorized by SINGLE software (Angel and Finger 2011). The natural crystal was investigated to test (and possibly validate) the "empirical prediction model", capable to provide bulk modulus and its first pressure derivative only knowing the composition of the spinels found in diamonds. Such prediction model could be used to obtain pressure of formation for the diamond-spinel pair through the elastic method. Details and results will be discussed. The research was funded by the ERC Starting Grant to FN (grant agreement n° 307322). References Angel R.J., Finger L.W. (2011) SINGLE A program to control single-crystal diffractometers. Journal of Applied Crystallography, 44, 247-251. Lenaz D., Logvinova A.M., Princivalle F., Sobolev N. (2009) Structural parameters of chromite included in diamond and kimberlites from Siberia: a new tool for discriminating source. American Mineralogist, 94, 1067-1070. Nestola F., Nimis P., Ziberna L., Longo M., Marzoli A., Harris J.W., Manghnani M.H., Fedortchouk Y. (2011) First crystal-structure determination of olivine in diamond: composition and implications for provenance in the Earth's mantle. Earth and Planetary Science Letters, 305, 249-255. Stachel, T., and Harris, J.W. (2008) The origin of cratonic diamonds - constraints from mineral inclusions. Ore Geology Reviews, 34, 5-32.

Morphological Features of Diamond Crystals Dissolved in Fe0.7S0.3 Melt at 4 GPa and 1400°C

NASA Astrophysics Data System (ADS)

Sonin, V. M.; Zhimulev, E. I.; Pomazanskiy, B. S.; Zemnuhov, A. L.; Chepurov, A. A.; Afanasiev, V. P.; Chepurov, A. I.

2018-01-01

An experimental study of the dissolution of natural and synthetic diamonds in a sulfur-bearing iron melt (Fe0.7S0.3) with high P-T parameters (4 GPa, 1400°C) was performed. The results demonstrated that under these conditions, octahedral crystals with flat faces and rounded tetrahexahedral diamond crystals are transformed into rounded octahedroids, which have morphological characteristics similar to those of natural diamonds from kimberlite. It was suggested that, taking into account the complex history of individual natural diamond crystals, including the dissolution stages, sulfur-bearing metal melts up to sulfide melts were not only diamond-forming media during the early evolution of the Earth, but also natural solvents of diamond in the mantle environment before the formation of kimberlitic melts.

New Constraints on Upper Mantle Structure Underlying the Diamondiferous Central Slave Craton, Canada, from Teleseismic Body Wave Tomography

NASA Astrophysics Data System (ADS)

Esteve, C.; Schaeffer, A. J.; Audet, P.

2017-12-01

Over the past number of decades, the Slave Craton (Canada) has been extensively studied for its diamondiferous kimberlites. Not only are diamonds a valuable resource, but their kimberlitic host rocks provide an otherwise unique direct source of information on the deep upper mantle (and potentially transition zone). Many of the Canadian Diamond mines are located within the Slave Craton. As a result of the propensity for diamondiferous kimberlites, it is imperative to probe the deep mantle structure beneath the Slave Craton. This work is further motivated by the increase in high-quality broadband seismic data across the Northern Canadian Cordillera over the past decade. To this end we have generated a P and S body wave tomography model of the Slave Craton and its surroundings. Furthermore, tomographic inversion techniques are growing ever more capable of producing high resolution Earth models which capture detailed structure and dynamics across a range of scale lengths. Here, we present preliminary results on the structure of the upper mantle underlying the Slave Craton. These results are generated using data from eight different seismic networks such as the Canadian National Seismic Network (CNSN), Yukon Northwest Seismic Network (YNSN), older Portable Observatories for Lithospheric Analysis and Reseach Investigating Seismicity (POLARIS), Regional Alberta Observatory for Earthquake Studies Network (RV), USArray Transportable Array (TA), older Canadian Northwest Experiment (CANOE), Batholith Broadband (XY) and the Yukon Observatory (YO). This regional model brings new insights about the upper mantle structure beneath the Slave Craton, Canada.

Inclusions in diamonds constrain thermo-chemical conditions during Mesozoic metasomatism of the Kaapvaal cratonic mantle

NASA Astrophysics Data System (ADS)

Weiss, Yaakov; Navon, Oded; Goldstein, Steven L.; Harris, Jeff W.

2018-06-01

Fluid/melt inclusions in diamonds, which were encapsulated during a metasomatic event and over a short period of time, are isolated from their surrounding mantle, offering the opportunity to constrain changes in the sub-continental lithospheric mantle (SCLM) that occurred during individual thermo-chemical events, as well as the composition of the fluids involved and their sources. We have analyzed a suite of 8 microinclusion-bearing diamonds from the Group I De Beers Pool kimberlites, South Africa, using FTIR, EPMA and LA-ICP-MS. Seven of the diamonds trapped incompatible-element-enriched saline high density fluids (HDFs), carry peridotitic mineral microinclusions, and substitutional nitrogen almost exclusively in A-centers. This low-aggregation state of nitrogen indicates a short mantle residence times and/or low mantle ambient temperature for these diamonds. A short residence time is favored because, elevated thermal conditions prevailed in the South African lithosphere during and following the Karoo flood basalt volcanism at ∼180 Ma, thus the saline metasomatism must have occurred close to the time of kimberlite eruptions at ∼85 Ma. Another diamond encapsulated incompatible-element-enriched silicic HDFs and has 25% of its nitrogen content residing in B-centers, implying formation during an earlier and different metasomatic event that likely relates to the Karoo magmatism at ca. 180 Ma. Thermometry of mineral microinclusions in the diamonds carrying saline HDFs, based on Mg-Fe exchange between garnet-orthopyroxene (Opx)/clinopyroxene (Cpx)/olivine and the Opx-Cpx thermometer, yield temperatures between 875-1080 °C at 5 GPa. These temperatures overlap with conditions recorded by touching inclusion pairs in diamonds from the De Beers Pool kimberlites, which represent the mantle ambient conditions just before eruption, and are altogether lower by 150-250 °C compared to P-T gradients recorded by peridotite xenoliths from the same locality. Oxygen fugacity (fO2) differs as well. The fO2 calculated for the saline HDF compositions (Δlog ⁡ fO 2 (FMQ) = - 2.47 to -1.34) are higher by about a log unit compared with that recorded by xenoliths at 4-7 GPa. We conclude that enriched saline HDFs mediated the metasomatism that preceded Group I kimberlite eruptions in the southwestern Kaapvaal craton, and that their 'cold and oxidized' nature reflects their derivation from a deep subducting slab. This event had little impact on the temperature and redox state of the Kaapvaal lithosphere as a reservoir, however, it likely affected its properties along limited metasomatized veins and their wall rock. To reconcile the temperature and oxygen fugacity discrepancy between inclusions in diamonds and xenoliths, we argue that xenoliths did not equilibrate during the last saline metasomatic event or kimberlite eruption. Thus the P-T- fO2 gradients they record express pre-existing lithospheric conditions that were likely established during the last major thermal event in the Kaapvaal craton (i.e. the Karoo magmatism at ca. 180 Ma).

Natural occurrence of silicon carbide in a diamondiferous kimberlite from Fuxian

USGS Publications Warehouse

Leung, I.; Guo, W.; Friedman, I.; Gleason, J.

1990-01-01

Considerable debate surrounds the existence of silicon carbide in nature, mostly owing to the problem of possible contamination by man-made SiC. Recently, Gurney1 reviewed reports of rare SiC inclusions in diamonds, and noted that SiC can only be regarded as a probable rather than proven cogenetic mineral. Here we report our observation of clusters of SiC coexisting with diamond in a kimberlite from Fuxian, China. Macrocrysts of ??-SiC are overgrown epitaxially by ??-SiC, and both polymorphs are structurally well ordered. We have also measured the carbon isotope compositions of SiC and diamonds from Fuxian. We find that SiC is more enriched in 12C than diamond by 20% relative to the PDB standard. Isotope fractionation might have occurred through an isotope exchange reaction in a common carbon reservoir. Silicon carbide may thus ultimately provide information on carbon cycling in the Earth's mantle.

Spatial distribution of eclogite in the Slave cratonic mantle: The role of subduction

NASA Astrophysics Data System (ADS)

Kopylova, Maya G.; Beausoleil, Yvette; Goncharov, Alexey; Burgess, Jennifer; Strand, Pamela

2016-03-01

We reconstructed the spatial distribution of eclogites in the cratonic mantle based on thermobarometry for 240 xenoliths in 4 kimberlite pipes from different parts of the Slave craton (Canada). The accuracy of depth estimates is ensured by the use of a recently calibrated thermometer, projection of temperatures onto well-constrained local peridotitic geotherms, petrological screening for unrealistic temperature estimates, and internal consistency of all data. The depth estimates are based on new data on mineral chemistry and petrography of 148 eclogite xenoliths from the Jericho and Muskox kimberlites of the northern Slave craton and previously reported analyses of 95 eclogites from Diavik and Ekati kimberlites (Central Slave). The majority of Northern Slave eclogites of the crustal, subduction origin occurs at 110-170 km, shallower than in the majority of the Central Slave crustal eclogites (120-210 km). The identical geochronological history of these eclogite populations and the absence of steep suture boundaries between the central and northern Slave craton suggest the lateral continuity of the mantle layer relatively rich in eclogites. We explain the distribution of eclogites by partial preservation of an imbricated and plastically dispersed oceanic slab formed by easterly dipping Proterozoic subduction. The depths of eclogite localization do not correlate with geophysically mapped discontinuities. The base of the depleted lithosphere of the Slave craton constrained by thermobarometry of peridotite xenoliths coincides with the base of the thickened lithospheric slab, which supports contribution of the recycled oceanic lithosphere to formation of the cratonic root. Its architecture may have been protected by circum-cratonic subduction and shielding of the shallow Archean lithosphere from the destructive asthenospheric metasomatism.

The first allanite-bearing eclogite xenolith in kimberlite

NASA Astrophysics Data System (ADS)

Trojman-Nichols, S.; Heaman, L.

2015-12-01

Here we report the first allanite-bearing mantle eclogite xenolith, entrained in the 173 Ma Jericho kimberlite pipe, located in the Slave craton, northwestern Canada. This eclogite is unique among the other Jericho eclogites by an extreme LREE enrichment in all phases, and garnet alteration rims that are more calcic than the garnet cores. Allanite is an abundant accessory phase, present as dull orange, subhedral crystals. Other minerals in the paragenesis are garnet, clinopyroxene, apatite and sulfides; two compositionally and texturally distinct generations of phlogopite constitute a secondary paragenesis where allanite is no longer stable. Allanite in this sample is La-, Ce- and Th- rich, with concentrations at the weight % level, while Y is only present at the relatively low concentration of ~100 ppm. Electron backscatter imaging reveals complex zonation within the allanite crystals that is off-centre, non-symmetric, and patchy. It is often asserted that eclogite xenoliths represent subducted oceanic lithosphere, despite significant differences in the composition and mineralogy between mantle-derived eclogite xenoliths and eclogite massif material. Both types of eclogite occurrences can contain quartz/coesite; massif eclogites often have small, sparse allanite inclusions, but allanite has never been reported in eclogite xenoliths in kimberlite. Allanite in massif eclogite is thought to form during subduction by the break-down of lawsonite and the incorporation of LREE into zoisite. Lawsonite breaks down into grossular and H20 at high pressures, which may explain the anomalous high-Ca rims measured in some garnets in this sample. This allanite-bearing eclogite may provide an unprecedented window for exploring a crucial stage of eclogite metamorphism and fluid mobilization in subduction zones. In addition, the U-Pb systematics currently under investigation may constrain the age of eclogitization.

Concepts for diamond exploration in "on/off craton" areas—British Columbia, Canada

NASA Astrophysics Data System (ADS)

Simandl, George J.

2004-09-01

The tectonic setting of British Columbia (BC) differs from classic diamond-bearing intracratonic regions such as the Northwest Territories and South Africa. Nevertheless, several diamond occurrences have been reported in BC. It is also known that parts of the province are underlain by Proterozoic and possibly Archean basement. Because the continents of today are composites of fragments of ancient continents, it is possible that some of the regions underlain by old crystalline basement in eastern British Columbia were associated with a deep crustal keel. The keel may have predated the break-up of the early Neoproterozoic supercontinent called Rodinia and was preserved possibly until the Triassic. Some of these old continental fragments may have been displaced relative to their position of origin and dissociated from their keel, or the keel may have since been destroyed. Such fragments represent favourable exploration grounds in terms of the "Diamondiferous Mantle Root" model (DMR model) if they were intersected by kimberlites or lamproites prior to displacement or destruction of their underlying deep keel. Therefore, extrapolation of fragments of the diamond-bearing Precambrian basement from the Northwest Territories or Alberta to BC provides a sufficient reason for initiating reconnaissance indicator mineral surveys. The "Eclogite Subduction Zone" model (ES model) predicts formation of diamonds at lower pressure (i.e., depth) than required by the DMR model in convergent tectonic settings. Although not proven, this model is supported by thermal modeling of cold subduction zones and recent discoveries of diamonds in areas characterized by convergent tectonic settings. If the ES model is correct, then the parts of BC with a geological history similar to today's "cold" subduction zones, such as Honshu (Japan), or to continental collision zones, such as Kokchetav massif (Kazakhstan) and the Dabie-Sulu Terrane (east central China), may be diamondiferous. The terranes where geological evidences suggest an ultrahigh pressure (UHP) metamorphic event followed by rapid tectonic exhumation (which could have prevented complete resorption of diamonds on their journey to the surface) are worth investigating. If UHP rocks were intercepted at depth by syn- or post-subduction diamond elevators, such as kimberlites, lamproites, lamprophyres, nephelinites or other alkali volcanic rocks of deep-seated origin, the diamond potential of the area would be even higher.

3D investigation of inclusions in diamonds using X-ray micro-tomography

NASA Astrophysics Data System (ADS)

Parisatto, M.; Nestola, F.; Artioli, G.; Nimis, P.; Harris, J. W.; Kopylova, M.; Pearson, G. D.

2012-04-01

The study of mineral inclusions in diamonds is providing invaluable insights into the geochemistry, geodynamics and geophysics of the Earth's mantle. Over the last two decades, the identification of different inclusion assemblages allowed to recognize diamonds deriving from the deep upper mantle, the transition zone and even the lower mantle. In such research field the in-situ investigation of inclusions using non-destructive techniques is often essential but still remains a challenging task. In particular, conventional 2D imaging techniques (e.g. SEM) are limited to the investigation of surfaces and the lack of access to the third dimension represents a major limitation when trying to extract quantitative information. Another critical aspect is related to sample preparation (cutting, polishing) which is typically very invasive. Nowadays, X-ray computed micro-tomography (X-μCT) allows to overcome such limitations, enabling the internal microstructure of totally undisturbed samples to be visualized in a three-dimensional (3D) manner at the sub-micrometric scale. The final output of a micro-tomography experiment is a greyvalue 3D map of the variations of the X-ray attenuation coefficient (µ) within the studied object. The high X-ray absorption contrast between diamond (almost transparent to X-rays) and the typical inclusion-forming minerals (olivines, garnets, pyroxenes, oxides and sulphides) makes X-μCT a straightforward method for the 3D visualization of inclusions and for the study of their spatial relationships with the diamond host. In this work we applied microfocus X-μCT to investigate silicate inclusions still trapped in diamonds, in order to obtain in-situ information on their exact position, crystal size, shape and X-ray absorption coefficient (which is related to their composition). We selected diamond samples from different deposits containing mainly olivine and garnet inclusions. The investigated samples derived from the Udachnaya pipe (Siberia, Russia), the Jericho Kimberlite (Slave Craton, Canada) and São Luiz-Juina (Brazil). The information obtained by tomographic experiments were combined with X-ray single-crystal diffraction data (see Nestola et al 2011) in order to identify the inclusion parageneses (peridotitic, eclogitic or websteritic) and to finally determine the origin of the studied diamonds. Our results showed that, by combining X-μCT with X-ray diffraction data, it is possible to exactly determine the 3D position of each inclusion together with their crystal size, even though they cannot be detected by using an optical microscope. In addition, such method could have strong crystallographic implications for inclusions still trapped in diamonds as it enables the application of a reliable numerical absorption correction to the 3D intensity data collections. REF. Nestola, F., Nimis, P., Ziberna, L., Longo, M., Marzoli, A., Harris, J.W., Manghnani, M.H., Fedortchouk, Y. (2011): First crystal-structure determination of olivine in diamond: composition and implications for provenance in the Earth's mantle. Earth Planet. Sci. Lett., 305, 249-255.

3-D X-ray tomography of diamondiferous mantle eclogite xenoliths, Siberia: A review

NASA Astrophysics Data System (ADS)

Howarth, Geoffrey H.; Sobolev, Nikolay V.; Pernet-Fisher, John F.; Ketcham, Richard A.; Maisano, Jessica A.; Pokhilenko, Lyudmila N.; Taylor, Dawn; Taylor, Lawrence A.

2015-04-01

Diamonds form over billions of years, hundreds of kilometers beneath the Earth's surface, and in combination with inclusions trapped within, provide important constraints on the evolution of the mantle over geological time. Diamonds are generally studied as individual crystals sourced from highly explosive kimberlite pipes, which entrain and subsequently disaggregate mantle fragments (xenoliths) en route to the surface. This has resulted in a general absence of robust textural descriptions of diamonds relative to their hosting mantle protolith. The textural associations of diamonds within their mantle host rocks are reviewed here on the basis of a compilation of X-ray tomographic data for 17 diamondiferous eclogite xenoliths from Siberian kimberlites. This review represents a comprehensive description of diamonds relative to their host silicates. The lack of such descriptions in previous studies is largely due to the rarity of these xenoliths, the difficulty in preparing petrographic thin sections containing diamonds, and their high-monetary value. High-resolution computed X-ray tomography (HRCXT) produces up to 1200 sequential 2-D slices through individual xenoliths, each of which represents a 'pseudo thin-section' with a resolution on the order of 5-20 μm. The improved resolution of X-ray imaging in recent studies allows for the identification of not only primary minerals, but metasomatic minerals assemblages, including: 'spongy' textured clinopyroxene, phlogopite/K-richterite, and hercynitic spinel, allowing for the delineation of distinct metasomatic pathways through the xenoliths and their relationship to diamonds. Diamonds are observed in three distinct textural settings, potentially representing several temporally distinct diamond growth events, these setting includes: (1) diamonds completely enclosed in garnet; (2) diamonds associated with highly embayed silicate grain boundaries; and (3) diamonds contained within distinct metasomatic 'plumbing-systems'. Diamonds observed completely enclosed in garnets suggest an early diamond-forming event prior to major re-crystallization and eclogite formation during subduction. The occurrence of diamond in association with embayed garnets suggests that diamond grew at the expense of the hosting silicate protolith. In addition, the spatial relationships of diamonds with metasomatic pathways, which are generally interpreted to result from late-stage proto-kimberlitic fluid percolation, indicate a period of diamond growth occurring close to, but prior to, the time of kimberlite emplacement. Furthermore, the paragenesis of sulfides within eclogite xenoliths are described using 3-D models for entire xenoliths volumes, providing important constraints of the timing of sulfide mobilization within the mantle. Three-D animations created using X-ray tomography data for ten of the xenoliths can be viewed at the following link: http://eps.utk.edu/faculty/taylor/tomography.php

Mixed fluid sources involved in diamond growth constrained by Sr-Nd-Pb-C-N isotopes and trace elements

NASA Astrophysics Data System (ADS)

Klein-BenDavid, Ofra; Pearson, D. Graham; Nowell, Geoff M.; Ottley, Chris; McNeill, John C. R.; Cartigny, Pierre

2010-01-01

Sub-micrometer inclusions in diamonds carry high-density fluids (HDF) from which the host diamonds have precipitated. The chemistry of these fluids is our best opportunity of characterizing the diamond-forming environment. The trace element patterns of diamond fluids vary within a limited range and are similar to those of carbonatitic/kimberlitic melts that originate from beneath the lithospheric mantle. A convecting mantle origin for the fluid is also implied by C isotopic compositions and by a preliminary Sr isotopic study (Akagi, T., Masuda, A., 1988. Isotopic and elemental evidence for a relationship between kimberlite and Zaire cubic diamonds. Nature 336, 665-667.). Nevertheless, the major element chemistry of HDFs is very different from that of kimberlites and carbonatites, varying widely and being characterized by extreme K enrichment (up to ˜ 39 wt.% on a water and carbonate free basis) and high volatile contents. The broad spectrum of major element compositions in diamond-forming fluids has been related to fluid-rock interaction and to immiscibility processes. Elemental signatures can be easily modified by a variety of mantle processes whereas radiogenic isotopes give a clear fingerprint of the time-integrated evolution of the fluid source region. Here we present the results of the first multi radiogenic-isotope (Sr, Nd, Pb) and trace element study on fluid-rich diamonds, implemented using a newly developed off-line laser sampling technique. The data are combined with N and C isotope analysis of the diamond matrix to better understand the possible sources of fluid involved in the formation of these diamonds. Sr isotope ratios vary significantly within single diamonds. The highly varied but unsupported Sr isotope ratios cannot be explained by immiscibility processes or fluid-mineral elemental fractionations occurring at the time of diamond growth. Our results demonstrate the clear involvement of a mixed fluid, with one component originating from ancient incompatible element-enriched parts of the lithospheric mantle while the trigger for releasing this fluid source was probably carbonatitic/kimberlitic melts derived from greater depths. We suggest that phlogopite mica was an integral part of the enriched lithospheric fluid source and that breakdown of this mica releases K and radiogenic Sr into a fluid phase. The resulting fluids operate as a major metasomatic agent in the sub-continental lithospheric mantle as reflected by the isotopic composition and trace element patterns of G10 garnets.

Mantle eclogites and garnet pyroxenites - the meaning of two-point isochrons, Sm-Nd and Lu-Hf closure temperatures and the cooling of the subcratonic mantle

NASA Astrophysics Data System (ADS)

Shu, Qiao; Brey, Gerhard P.; Gerdes, Axel; Hoefer, Heidi E.

2014-03-01

The Earth's mantle is a huge metamorphic complex which undergoes permanent changes ruled by plate tectonics. It also has enclaves underneath Archean crust which are exempt from the convecting mantle since at least 2.5 Ga. Since then, this mantle may cool slowly as a result of diminishing heat input from the asthenosphere, of declining heat production from radioactive decay and of denudation of the crust. Under such circumstances, two point garnet-clinopyroxene isochrons from mantle xenoliths (here garnet pyroxenites and eclogites) reflect either cooling ages or eruption ages depending on whether the mantle portion under consideration was below or above the closure temperature of a radiogenic system. Available literature data from the Slave and Kaapvaal craton for the Sm-Nd and Lu-Hf isotope systems and our own new data from Bellsbank (Kaapvaal) provide a whole range of two-point isochron ages from younger than the kimberlite eruption age to early Proterozoic. The meaning of ages other than the kimberlite eruption age is unclear. We use here a compilation of Sm-Nd and Lu-Hf two-point isochron age data from this study and the literature, to assess the meaning of such isochrons. This is achieved by plotting the temperature of last equilibration as derived from the Fe-Mg exchange between garnet and clinopyroxene versus the two-point isochron age. There is a low temperature alignment for both systems of increasing age with decreasing temperature and an alignment around the kimberlite eruption ages at high temperatures. We interpret the intersect between the low temperature limb and the kimberlite eruption age as closure temperature which gives about 920 °C for the Lu-Hf system and about 850 °C for the Sm-Nd system. The differences of the cooling ages between the two isotope systems for individual samples combined with the closure temperatures from this study are used to deduce the cooling of the Slave and Kaapvaal subcratonic mantle from the early Proterozoic until today. We deduce that the subcratonic mantle cooled since 2 Ga from a geothermal gradient of 46 mW/m to 38 mW/m at 120 Ma ago with a rate of around 0.1 °C/Ma. This value is in agreement with previous estimates which were based on various geophysical and geological constraints, heat production by radioactive elements and diffusivity of radiogenic elements.

Diamond collecting in northern Colorado.

USGS Publications Warehouse

Collins, D.S.

1982-01-01

The discovery of numerous diamond-bearing kimberlite diatremes in the N Front Range of Colorado and Wyoming is of both scientific and economic interest. Species recovered from heavy-mineral concentrates include Cr-diopside, spinel, Mg-ilmenite, pyrope and diamond. A nodule tentatively identified as a graphite-diamond eclogite was also found. -G.W.R.

Kinematics, mechanics, and potential earthquake hazards for faults in Pottawatomie County, Kansas, USA

USGS Publications Warehouse

Ohlmacher, G.C.; Berendsen, P.

2005-01-01

Many stable continental regions have subregions with poorly defined earthquake hazards. Analysis of minor structures (folds and faults) in these subregions can improve our understanding of the tectonics and earthquake hazards. Detailed structural mapping in Pottawatomie County has revealed a suite consisting of two uplifted blocks aligned along a northeast trend and surrounded by faults. The first uplift is located southwest of the second. The northwest and southeast sides of these uplifts are bounded by northeast-trending right-lateral faults. To the east, both uplifts are bounded by north-trending reverse faults, and the first uplift is bounded by a north-trending high-angle fault to the west. The structural suite occurs above a basement fault that is part of a series of north-northeast-trending faults that delineate the Humboldt Fault Zone of eastern Kansas, an integral part of the Midcontinent Rift System. The favored kinematic model is a contractional stepover (push-up) between echelon strike-slip faults. Mechanical modeling using the boundary element method supports the interpretation of the uplifts as contractional stepovers and indicates that an approximately east-northeast maximum compressive stress trajectory is responsible for the formation of the structural suite. This stress trajectory suggests potential activity during the Laramide Orogeny, which agrees with the age of kimberlite emplacement in adjacent Riley County. The current stress field in Kansas has a N85??W maximum compressive stress trajectory that could potentially produce earthquakes along the basement faults. Several epicenters of seismic events (

Constraints on crustal hydration below the Colorado plateau from Vp measurements on crustal xenoliths

NASA Astrophysics Data System (ADS)

Padovani, Elaine R.; Hall, Jeremy; Simmons, Gene

1982-04-01

Seismic velocities have been measured as a function of confining pressure to 8 kbar for crustal xenoliths from the Moses Rock Dike and Mule Ear Diatreme, two kimberlite pipes on the Colorado Plateau. Rock types measured include rhyolite, granite, diorite, metasedimentary schists and gneisses, mafic amphibolites and granulites. Many of our samples have been hydrothermally altered to greenschist facies mineral assemblages during transport to the earth's surface. The velocity of compressional waves measured on altered amphibolites and granulites are too low by 0.1-0.3 km/s for such rock types to be characteristic of deep crustal levels. A direct correlation exists between progressive alteration and the presence of microcracks extending into the xenoliths from the kimberlitic host rock. Velocities of pristine samples are compatible with existing velocity profiles for the Colorado Plateau and we conclude that the crust at depths greater than 15 km has probably not undergone a greenschist facies metamorphic event. The xenolith suite reflects a crustal profile similar to that exposed in the Ivrea-Verbano and Strona-Ceneri zones in northern Italy.

High-resolution reconstruction of Arctic paleoclimate derived from 53 million year old kimberlite-hosted Metasequoia wood

NASA Astrophysics Data System (ADS)

Walker, J. J.; Halfar, J.; Schulze, D.; Gedalof, Z.; Moore, G. W. K.

2009-04-01

The recovery of exceptionally well preserved Eocene wood from kimberlite pipes in the Lac de Gras region of the Northwest Territories, Canada, has allowed for the characterization of the local temperature and hydrologic patterns on an annual scale for this arctic ecosystem (present day latitude: 64 deg N). Wood fragments of ancient Metasequoia sp. trees mixed into the crater facies during kimberlite emplacement were recovered from the Ekati and Diavik diamond mines. Wood recovered from the Ekati "Panda" pipe, which has been dated using Rb-Sr age determination at 53.3 +/- 0.6 million years, is unique in that it exhibits extremely low vitrinite reflectance values, comparable to that of modern near-surface peats. The implication is that the wood has undergone minimal thermal or compressional alteration, thus preserving the geochemical signatures originally formed during growth. Ring width measurements representing over 100 years of climate data show congruence between multiple samples, thus enabling the development of a floating master chronology. Patterns contained in this chronology are of particular interest as the early Eocene was characterized by a period of unusual warming that has been compared to modern day climate change. Wood cellulose does not exchange atoms with its surroundings after formation, making it an ideal candidate for stable isotope analysis once it has been separated from associated whole-wood components. A robotic micromilling device was used to collect whole wood samples of latewood from annual tree rings. The α-cellulose in the samples will be isolated and analyzed for δ13C and δ18O, generating a 34-year floating chronology that can be used to reconstruct decadal scale temperature and humidity patterns. Successful application of this technique suggests that a longer Eocene chronology, using additional wood samples recovered from the Panda pipe as well as samples from neighbouring pipes in the Lac de Gras region, can be developed.

Petrogenesis of a Mesoproterozoic shoshonitic lamprophyre dyke from the Wajrakarur kimberlite field, eastern Dharwar craton, southern India: Geochemical and Sr-Nd isotopic evidence for a modified sub-continental lithospheric mantle source

NASA Astrophysics Data System (ADS)

Pandey, Ashutosh; Chalapathi Rao, N. V.; Chakrabarti, Ramananda; Pandit, Dinesh; Pankaj, Praveer; Kumar, Alok; Sahoo, Samarendra

2017-11-01

Mineralogy and geochemistry of the Udirpikonda lamprophyre, located within the Mesoproterozoic diamondiferous Wajrakarur kimberlite field (WKF), towards the western margin of the Paleo-Mesoproterozoic Cuddapah basin are presented. The lamprophyre is characterised by a panidiomorphic-porphyritic texture imparted by clinopyroxene, olivine and biotite set in a groundmass of feldspar and spinel. Olivine occurs as the microphenocrysts with a composition range of Fo87-78. Clinopyroxenes display reverse as well as oscillatory optical zoning and are diopsidic in nature with a variation in the composition from core (Wo47 En28 Fs20Ac5) to rim (Wo46En41Fs11Ac3). Biotite (Mg# < 0.6) is the only mica present and spinels are titano-magnetites showing ulvospinel- magnetite solid solution. Plagioclase is the dominant feldspar with a variable compositional range of An41-8Ab82-56Or33-3. Based on the mineralogy, the lamprophyre can be classified to be of calc-alkaline variety but its geochemistry display mixed signals of both alkaline and calc-alkaline lamprophyres. K2O/Na2O ranges from 1.49 to 2.79, making it distinctly potassic and highlights its shoshonitic character. Moderate Mg# (60-65), Ni (110-200 ppm) and Cr (110-260 ppm) contents in the bulk-rock indicate substantial fractional crystallization of olivine and clinopyroxene. Fractionated chondrite normalized REE patterns (average (La/Yb)N = 37.56) indicates involvement of an enriched mantle source from within the garnet stability field whereas slightly negative Ta-Nb-Ti and Hf anomalies displayed on the primitive mantle normalized multi-element spider gram highlight involvement of a subducted component in the mantle source. Given the spatial disposition of the studied lamprophyre, the age of the emplacement is considered to be coeval with WKF kimberlites ( 1.1 Ga) and the initial 143Nd/144Nd (0.510065-0.510192) and 87Sr/86Sr (0.705333-0.706223) are strikingly similar to those observed for the Smoky Butte lamproites, Montana, USA. Fluid-related subduction enrichment of the mantle source is apparent from the enriched ratios of La/Nb, Ba/Nb and (Hf/Sm)N, (Ta/La)N < 1. Petrogenetic modelling reveals melt generation from 1 to 2% partial melting of an enriched mantle source that subsequently underwent fractional crystallization. Our study provides geochemical and isotopic evidence for a sub-continental lithospheric mantle (SCLM) modified by subduction and asthenospheric upwelling in the Eastern Dharwar Craton. The partial melting of a resulting heterogeneous Eastern Dharwar Craton SCLM to generate Udiripikonda lamprophyre and Wajrakarur kimberlites has been attributed to the Mesoproterozoic regional lithospheric extension event.

Mesoproterozoic orangeites of Karelia (Kostomuksha-Lentiira): evidence for composition of mantle lithosphere

NASA Astrophysics Data System (ADS)

Kargin, Alexey; Nosova, Anna; Larionova, Yulia; Kononova, Voctoria; Borisovskiy, Sergey; Kovalchuk, Elena; Griboedova, Irina

2014-05-01

The 1.23-1.20 Ga old diamondiferous lamproites and orangeites (kimberlites of II group) of the Kostomuksha-Taloveys and the Lentiira-Kuhmo dyke fields intrude the Archaean crust of the Karelian craton, NE of the East European Platform. Mineral (a trend of compositional evolution of mica, presence of carbonate minerals in basis, composition of olivine) and geochemical (major elements, ratio of trace elements, primitive mantle normalized trace elements patterns) characteristics of these rocks suggest an orangeitic rather than lamproitic or lamprophyric nature. The composition of Phl-Ol orangeites suggests intensive processes of fractional crystallization for their melts. Cpx-Phl-Ol orangeites indicate higher intensity of lithospheric mantle assimilation then other orangeitic types. Phl-Carb orangeites of the Taloveys area and Cpx-Phl-Ol one of the Lentiira area are closest to primary melts. The Ol-Phl-Cpx orangeites of the Lentiira area contain three generations of unaltered olivine that vary in composition and origin: a) xenocryst derived from depleted mantle peridotite; b) orangeitic olivine phenocryst and c) and olivine like early stage crystallization of megacryst assemblage or a product of metasomatic interaction between mantle peridotite and protokimberlitic melt. Orangeites of Kostomuksha-Lentiira have low- and medium-radiogenic value of (87Sr/86Sr)1200 that range from 0.7038 to 0.7067. Phl-Carb orangeites of Taloveys have less radiogenic isotopic composition of Nd (eNd -11 ... -12) then Cpx-Phl-Ol and Phl-Ol orangeites of Kostomuksha (eNd -6.9 ... -9.4). The study of Sm-Nd and Rb-Sr isotopic systems suggests that an ancient metasomatic mantle source took part in origin of orangeites. We propose a two-steps model of origin of their source (Kargin et al., 2014): 1) The metasomatic component of mantle source (like as MARID-type veins) formed during Lapland-Kola and/or Svecofennian orogeny events (2.1-1.8 Ga ago). 2) The intrusion of orangeites is comparable by time and geological setting with back-arc extensions (such as magmatism of CSDG) during the first stage of Sveconorwegian orogeny, initial stage of assembly of the supercontinent Rodinia (1.31-1.14 Ga). These back-arc extensions inspired of asthenosphere-derived melts to metasomatic lithospheric mantle and a generation of orangeitic melts. Kargin A.V., Nosova A.A., Larionova Yu.O. et al. Mesoproterozoic orangeites (kimberlites II) of Western Karelia: mineralogical, geochemical and Nd-Sr isotopic-geochemical characteristics // Petrology. 2014. V.2. in press.

Intracontinental Rifts As Glorious Failures

NASA Astrophysics Data System (ADS)

Burke, K.

2012-12-01

Rifts: "Elongate depressions overlying places where the lithosphere has ruptured in extension" develop in many environments because rocks are weak in extension (Sengor 2nd edn. Springer Encycl. Solid Earth Geophys.). I focus on intra-continental rifts in which the Wilson Cycle failed to develop but in which that failure has led to glory because rocks and structures in those rifts throw exceptional light on how Earth's complex continental evolution can operate: The best studied record of human evolution is in the East African Rift; The Ventersdorp rifts (2.7 Ga) have yielded superb crustal-scale rift seismic reflection records; "Upside-down drainage" (Sleep 1997) has guided supra-plume-head partial melt into older continental rifts leading Deccan basalt of ~66Ma to erupt into a Late Paleozoic (~ 300Ma) rift and the CAMP basalts of ~201 Ma into Ladinian, ~230 Ma, rifts. Nepheline syenites and carbonatites, which are abundant in rifts that overlie sutures in the underlying mantle lithosphere, form by decompression melting of deformed nepheline syenites and carbonatites ornamenting those sutures (Burke et al.2003). Folding, faulting and igneous episodes involving decompression melting in old rifts can relate to collision at a remote plate margin (Guiraud and Bosworth 1997, Dewey and Burke 1974) or to passage of the rift over a plume generation zone (PGZ Burke et al.2008) on the Core Mantle Boundary (e.g.Lake Ellen MI kimberlites at ~206 Ma).

Multi-proxy Paleoclimate and CO2 Reconstruction from the Latest Middle Eocene Sedimentary Fill of a Subarctic Kimberlitic Maar Crater

NASA Astrophysics Data System (ADS)

Reyes, A. V.; Wolfe, A. P.; Royer, D. L.; Greenwood, D. R.; Tierney, J. E.; Doria, G.; Gagen, M. H.; Siver, P.; Westgate, J.

2016-12-01

Eocene paleoclimate reconstructions are rarely accompanied by parallel estimates of CO2, complicating assessment of the equilibrium climate responses to CO2. We reconstruct temperature, precipitation, and CO2 from latest middle Eocene ( 38 Myrs ago) peats in subarctic Canada, preserved in sediments that record infilling of a kimberlite pipe maar crater. Mutual climatic range analyses of pollen, together with oxygen isotope analyses of a-cellulose from unpermineralized wood and inferenecs from branched glycerol diakyl glycerol tetraethers (GDGTs), reveal a high-latitude humid-temperate forest ecosystem with mean annual temperatures (MATs) >17 °C warmer than present, mean coldest month temperatures above 0 °C, and mean annual precipitation 4x present. Metasequoia stomatal indices and gas-exchange modeling produce median CO2 concentrations of 634 and 432 ppm, respectively, with a consensus median estimate of 494 ppm. Reconstructed MATs are >6 °C warmer than those produced by Eocene climate models forced at 560 ppm CO2, underscoring the capacity for exceptional polar amplification of warming and hydrological intensification under relatively modest CO2 concentrations, once both fast and slow feedbacks become expressed.

Physical Cause of Kimberlite Occurrences Clustering

NASA Astrophysics Data System (ADS)

Khazan, Y.; Aryasova, O.

2011-12-01

High abundances of incompatible elements in kimberlites are indicative of low or even infinitesimal melting degree in a source. This means that initially protokimberlite melts exist as a system of dispersed small inclusions while the kimberlite transportation to the surface assumes formation of macroscopic melt pools. In other words, an inevitable stage of the protokimberlite melt evolution is its segregation from the porous matrix inside a partially molten zone and accumulation to the zone top where the melt fraction greatly exceeds the initial melting degree. Khazan (2010), Khazan, Aryasova (2011) demonstrated that the characteristic segregation time, τ, depends on the ratio L/δ of the molten zone thickness, L, to the compaction length, δ, (McKenzie, 1984), which in its turn is defined by melt and matrix viscosities and matrix permeability. For low-viscosity melts the segregation time decreases with increasing molten zone thickness as τ≈19.5(η/ΔρgL) (η is the matrix viscosity, Δρ is the density contrast) and is independent of poorly known melt viscosity, matrix permeability, and melting degree. Since no system can exist longer than its decay time is, the decreasing segregation time dependence on the molten zone thickness constrains the latter. To illustrate, assume that the melting is due to decompression and accompanies ascent of a mantle diapir with a velocity V. In this case the molten zone thickness increases linearly with time L=Vt where t is measured from the onset of melting and cannot exceed the segregation time, so that t≤τ (Fig. 1) and L≤L*=4.4(Vη/Δρg)^0.5. Under a robust parameter choice (η=10^19 Pa s, Δρ=300 kg/m^3, V=3 cm/year) L* is about 8 km, with the corresponding segregation time τ being of 0.3 Myear (Fig. 1). After the first segregation, a new partially molten zone grows resulting in the next segregation when its thickness reaches the maximum possible value L*. This sequence of events repeats until the whole diapir passes by the melting level. One may estimate a diapir diameter D of 30 to 80 km based upon a size of low-amplitude uplifts associated with the kimberlite fields (e. g., Kaminsky et al., 1995). So the diapir ascent results in a cluster of ~D/L*=3-10 same age and composition eruptions. A total activity accociated with the cluster continues of τD/L*=1 to 3 Myear as it is really observed (Heaman et al.,2004). The described sequence of events is schematic(lly illustrated in Fig. 2. Heaman L et al., Lithos, 2004, 76, 377. Kaminsky F et al., J. Geochem. Explor. 1995, 53, 167. Khazan Y, Geoph. J. Int. 2010, 183, 601. Khazan Y, Aryasona O, Izvestiya, Phys. Solid Earth. 2011, 47, No. 5, 425. McKenzie D, J Petrol. 1984, 25, 713.

Water and Metasomatism in the Slave Cratonic Lithosphere (Canada): An FTIR Study

NASA Technical Reports Server (NTRS)

Kilgore, McKensie; Peslier, Anne H.; Brandon, Alan D.; Schaffer, Lillian Aurora; Pearson, D. Graham; O'Reilly, Suzanne Yvette; Kopylova, Maya G.; Griffin, William L.

2017-01-01

Water in the mantle influences melting, viscosity, seismic velocity, and electrical conductivity. The role played by water in the long-term stabilization of cratonic roots is currently being debated. This study focuses on water contents of mantle minerals (olivine, pyroxene and garnet) from xenoliths found in kimberlites of the Archean Slave craton. 19 mantle xenoliths from central Lac de Gras, and 10 from northern Jericho were analyzed by FTIR for water, and their equilibration depths span the several compositional layers identified beneath the region. At both locations, the shallow peridotites have lower water contents in their olivines (11-30 ppm H2O) than those from the deeper layers (28-300 ppm H2O). The driest olivines, however, are not at the base of the cratonic lithosphere (>6 GPa) as in the Kaapvaal craton. Instead, the deepest olivines are hydrous (31-72 ppm H2O at Lac de Gras and 275 ppm H2O at Jericho). Correlations of water in clinopyroxene and garnet with their other trace element contents are consistent with water being added by metasomatism by melts resembling kimberlite precursors in the mantle approx.0.35 Ga ago beneath Lac de Gras. The northern Jericho xenoliths are derived from a region of the Slave craton that is even more chemically stratified, and was affected at depth by the 1.27 Ga Mackenzie igneous events. Metasomatism at Jericho may be responsible for the particularly high olivine water contents (up to 300 ppm H2O) compared to those at Lac de Gras, which will be investigated by acquiring trace-element data on these xenoliths. These data indicate that several episodes of metasomatic rehydration occurred in the deep part of the Slave craton mantle lithosphere, with the process being more intense in the northern part beneath Jericho, likely related to a translithospheric suture serving as a channel to introduce fluids and/or melts in the northern region. Consequently, rehydration of the lithosphere does not necessarily cause cratonic root delamination and these peridotites may represent localized metasomatic zones - the wall rocks to kimberlite magma passage.

Hotspots in Hindsight

NASA Astrophysics Data System (ADS)

Julian, B. R.; Foulger, G. R.; Hatfield, O.; Jackson, S.; Simpson, E.; Einbeck, J.; Moore, A.

2014-12-01

Torsvik et al. [2006] suggest that the original locations of large igneous provinces ("LIPs") and kimberlites, and current locations of melting anomalies (hot-spots) lie preferentially above the margins of two Large Lower-Mantle Shear Velocity Provinces" (LLSVPs), at the base of the mantle, and that the correlation has a high significance level (> 99.9999%). They conclude the LLSVP margins are Plume-Generation Zones, and deep-mantle plumes cause hotspots and LIPs. This conclusion raises questions about what physical processes could be responsible, because, for example the LLSVPs are likely dense and not abnormally hot [Trampert et al., 2004]. The supposed LIP-hotspot-LLSVP correlations probably are examples of the "Hindsight Heresy" [Acton, 1959], of basing a statistical test upon the same data sample that led to the initial formulation of a hypothesis. In doing this, many competing hypotheses will have been considered and rejected, but this fact will not be taken into account in statistical assessments. Furthermore, probabilities will be computed for many subsets and combinations of the data, and the best-correlated cases will be cited, but this fact will not be taken into account either. Tests using independent hot-spot catalogs and mantle models suggest that the actual significance levels of the correlations are two or three orders of magnitude smaller than claimed. These tests also show that hot spots correlate well with presumably shallowly rooted features such as spreading plate boundaries. Consideration of the kimberlite dataset in the context of geological setting suggests that their apparent association with the LLSVP margins results from the fact that the Kaapvaal craton, the site of most of the kimberlites considered, lies in Southern Africa. These observations raise questions about the distinction between correlation and causation and underline the necessity to take geological factors into account. Fig: Left: Cumulative distributions of distances from hotspots to nearest ridge for 5 hotspot lists; heavy red curve: Distribution function for a random point on Earth's surface. Hotspots are closer to ridges than expected at random. Right: For each list, the probability of at least as many random points being as close to a ridge. Values to right have higher significance.

Timescales of Crustal Cooling of the Superior Craton near Attawapiskat, Ontario, Canada, and Implications for Extent of Keweenawan Plume Heating.

NASA Astrophysics Data System (ADS)

Edwards, G. H.; Blackburn, T.; Smit, K.

2017-12-01

The thermal history of the Superior Craton was punctuated by a period of mantle plume heating at 1.1 Ga associated with the Keweenawan Rift, though the plume's spatial extent, temperature, and duration of heating remain unresolved. Kimberlites of Mesoproterozoic and Jurassic age in the Attawapiskat area, Northern Ontario contain lithospheric mantle and lower crustal xenoliths that record the thermal history 600km to the north of exposed 1.1 Ga Keweenawan volcanics and the topographically and gravimetrically defined plume center. Previous work on Attawapiskat kimberlites identified two populations of diamonds with differing thermal histories, suggesting two distinct phases of diamond growth. Corresponding geothermobarometric data indicate geotherm relaxation and broadening of the diamond stability field between the Mesoproterozoic and Jurassic. These data, however, do not uniquely resolve whether the region experienced significant heating coincident with Keweenawan rifting ( 1.1 Ga) or prolonged, unperturbed cooling since amalgamation of the Superior Craton ( 2.6 Ga). To discern between these two possible histories, we use accessory phase U-Pb thermochronology to construct a continuous thermal record of the lower crust. Here we present a dataset of U-Pb ID-TIMS measurements of rutile and apatite from xenoliths (n=8) sourced from the Jurassic age Victor Kimberlite. The U/Pb and Pb isotopic compositions of rutile and apatite from shallow-residing amphibolite xenoliths exhibit Proterozoic dates with a high degree of U-Pb discordance, reflecting slow cooling of the middle crust prior to 1.1 Ga. Granulite and eclogite xenoliths record younger dates consistent with their deeper sample residence, but with a high degree of U-Pb concordance that is inconsistent with continuous cooling through the Proterozoic. Reproducing the measured trend with numerical models requires a reheating event at 1.1 Ga. Imposing a 60-70mW/m2 geotherm at 1.1 Ga is high enough to replicate the observed U-Pb data but low enough to permit cooling that satisfies diamond thermal data. This indicates that the Keweenawan plume head extended to at least the Attawapiskat area, where plume heating abutted, and likely extended beyond, the associated topographic and gravity anomalies of the Superior Region.

A Lithospheric Origin for the Elk Creek Carbonatite Complex, SE Nebraska?

NASA Astrophysics Data System (ADS)

Farmer, G. L.

2015-12-01

The Elk Creek carbonatite complex in southeastern Nebraska is part of a widespread Cambrian-Ordovician alkali igneous event that affected much of North America during and after the break-up of the Rodinian supercontinent. We conducted whole rock and mineral Nd, Sr, Pb and Hf isotopic analyses of drill cores obtained from this complex in order to assess the source regions of the parental carbonatite magma. Low precision laser ablation U-Pb age determinations from individual zircon grains separated from carbonate-rich "syenites" range from 480 +/- 20 Ma to 540+/- 14 Ma. Whole rock Nd, Sr and Pb isotopic compositions all plot on Cambrian (~550 Ma) isochrons, implying that the carbonatites crystallized from melts with homogeneous radiogenic isotopic compositions. Initial ɛNd and ɛHf are well defined at ~+2 and ~0, respectively, while initial 87Sr/86Sr values are more variable and range from 0.7028 to 0.7058. The contemporaneously emplaced State Line kimberlites in the Front Range of north central Colorado share the same Nd and Sr isotopic compositions imply that sources of these rocks were similar and geographically widespread. Overall, the isotopic compositions are those expected from "Group 1" alkaline igneous rocks, usually interpreted as derivates from the sublithospheric mantle. Cretaceous-Tertiary alkaline rocks in North America generally belong to "Group 1" and may have originated in this fashion (Genet et al., 2014, Earth Planet. Sci. Lett.). An alternative possibility is that the Cambrian-Ordovician carbonatites and kimberlites were derived from underlying, carbonated portions of the lithospheric mantle that formed after the original stabilization of the latter in the Paleoproterozoic. Nd and Hf depleted mantle model ages for the Elk Creek and State Line alkaline rocks range from ~0.8 Ga to ~1.1 Ga and allow the possibility that both sets of intrusive rocks represent melting of mantle metasomatized either during or after the assembly of Rodinia. Widespread thinning and heating of the metasomatized mantle during the subsequent breakup of Rodinia could have led to the widespread kimberlite and carbonatite magmatism observed in North America during the Cambrian.

Olivine inclusions in Siberian diamonds and mantle xenoliths: Contrasting water and trace-element contents

NASA Astrophysics Data System (ADS)

Jean, M. M.; Taylor, L. A.; Howarth, G. H.; Peslier, A. H.; Fedele, L.; Bodnar, R. J.; Guan, Y.; Doucet, L. S.; Ionov, D. A.; Logvinova, A. M.; Golovin, A. V.; Sobolev, N. V.

2016-11-01

A subject of continuing debate is how the Earth's lithospheric portion of the upper mantle has remained the thickest (> 200 km) and oldest (> 3 Gy) beneath cratons and is yet surrounded by a vigorously convecting asthenosphere. It is generally admitted that water is a key parameter in the strength and longevity of cratonic roots, because olivine, the main phase of the lithospheric mantle, becomes stronger if its water content decreases. Expanding upon the work presented in Novella et al. (2015) and Taylor et al. (2016), we report new water contents for additional olivine inclusions in diamonds together with the trace-element composition for all olivine inclusions, as well as for mantle xenoliths from various kimberlite pipes located on the Siberian craton. The olivine diamond inclusions from this study have systematically low-water contents (< 50 ppmw H2O), moderate to high forsterite (e.g., Fo91-94) contents and low Ni, Co, and Zn ppm contents (e.g., < 2848, < 108, and < 47 ppm, respectively). In contrast, olivines from Siberian craton mantle xenoliths have a wide range of water contents (6-323 ppmw H2O) and extend to lower-Fo (91-92), Ni, Co, and Zn-rich compositions, compared to the diamond inclusions. Depleted incompatible trace-element concentrations in olivine (0.1-0.001 × Primitive Mantle) advance our hypothesis for the protogenetic origins for the majority of Siberian diamond inclusions. These observations are consistent with the peridotite xenoliths as representing a part of the cratonic lithosphere that has experienced melt re-fertilization, which has also transported water. The olivine diamond inclusions, on the other hand, preserve "micro-samples" of an initial, dry cratonic lithosphere, mostly resulting from melting events. These inclusions are likely sourced from the initial cratonic mantle lithosphere, which thereby, resisted delamination over time, due to its buoyancy and strength, imparted from melt and water depletion, respectively. And thus, our data provides a major argument that the kimberlite-hosted mantle xenoliths may be more metasomatized than common rocks at the base of the Siberian and other cratonic roots away from kimberlite fields.

On the tectonics and metallogenesis of West Africa: a model incorporating new geophysical data

USGS Publications Warehouse

Hastings, David A.

1982-01-01

The gold, diamond and manganese deposits of Ghana have attracted commercial interest, but appropriate geophysical data to delineate the tectonic setting of these and other deposits have been lacking until recently. Recent gravity surveys, however, now cover about 75% of the country. When used in a synthesis of the sometimes contradictory existing theories about the geology and metallogenesis of West Africa, the available gravity, magnetic, and seismic data lead to a preliminary tectonic model that postulates rifting at the time of the (1800-2000 m.y. old) Eburnean orogeny and is consistent with the occurrences of mineral deposits in the region. In this model, diamond-bearing kimberlites formed during the commencement of rifting during the Eburnean orogenesis. Later emplacement of kimberlites was associated with the initiation of Mesozoic rifting of Gondwanaland. Primary gold vein deposits were probably formed by the migration of hydrothermal fluids (associated with the formation of granitoids) into dilatant zones, such as rift-related faults and anticlinal axial areas, toward the end of the Eburnean orogeny. At this time, the major concordant granitoids were formed, with smaller plutonic granitoids forming on the fringes of the concordant masses as partial melting fractions of the latter. Sedimentary manganese deposits were formed along the margins of rift lakes toward the end of the orogeny.

A new garnet-orthopyroxene thermometer developed: method, results and applications

NASA Astrophysics Data System (ADS)

Olivotos, Spyros-Christos; Kostopoulos, Dimitrios

2014-05-01

The Fe-Mg exchange reaction between garnet and orthopyroxene is a robust geothermometer that has extensively been used to retrieve metamorphic temperatures from granulitic and peridotitic/pyroxenitic lithologies with important implications on the thermal state of the continental lithosphere. More than 800 experimental mineral pairs from both simple and complex systems were gleaned from the literature covering the P-T range 0.5-15 GPa / 800-1800°C. Grt was treated as a senary (Py, Alm, Grs, Sps, Kno and Uv), whereas Opx as a septenary (En, Fs, Di, Hd, FeTs, MgTs and MgCrTs) solid solution. For Opx, Al in the M1 site was calculated following Carswell (1991) and Fe/Mg equipartitioning between sites was assumed. A mixing on sites model was employed to calculate mole fractions of components for both minerals. With regard to the excess free energy of solution and activity coefficients the formalism of Mukhopadhyay et al. (1993) was adopted treating both minerals as symmetric regular solutions. Calibration was achieved in multiple steps; in each step ΔS was allowed to vary until the standard deviation of the differences between experimental and calculated temperature for all experiments was minimised. The experiment with the largest absolute relative deviation in temperature was then eliminated and the process was repeated. The new thermometer reproduces the experimental data to within 50°C and is independent of P-T-X variations within the bounds of the calibrant data set. Application of our new calibration to metamorphosed crustal and mantle rocks that occur both as massifs and xenoliths in volcanics suggested the following results. Granulite terranes have recorded differences in temperature between peak and re-equilibration conditions in the range 100-340°C, primarily depending on the mechanism and rate of exhumation. Several provinces retain memory of discrete cooling pulses (e.g. Palni Hills, South Harris, Adirondacks, E. Antarctic Belt, Aldan Shield) whereas others are dominated by a single thermal event (Lisof Massif, SW Greenland, Eifel). UHT granulites appear to be more common than previously thought. There are a considerable number of localities in Europe that have recorded temperatures in excess of 950°C (South Harris, Schwarzwald, Pannonian Basin, Sudetes, Rogaland, Massif Central, Iberian Hercynian Belt), with the first four listed peaking over 1000°C. In settings such as South Harris, the model of Schmalholz & Podladchikov (2013) for heat generation within a crustal-scale shear zone is most appealing. Mafic/ultramafic xenoliths from Deccan conform to geotherms with surface heat flow between 60 and 90 mW.m-2 signifying a reduction in lithospheric thickness of the order of 43 km. Similar xenoliths from the Tariat Depression testify to a 20 km thinning beneath Mongolia. Mantle xenoliths from Canadian and Russian kimberlites demonstrate the great diamond potential of the Lac des Gras, Jericho, Udachnaya and Mir pipes but the limited potential of the Somerset Isl. and Obnazhennaya pipes. UHP mantle peridotites from the Dabie-SuLu orogen are characterised by the coldest geotherm identified so far (33mW.m-2) implying a minimum removal of 110 km from the lithospheric keel underneath E. China. References: Carswell, D. A., 1991. Min. Mag. 55, 19-31; Mukhopadhyay, B., et al., 1993. GCA 57, 277-283; Schmalholz, S. M., & Podladchikov, Y. Y., 2013. GRL 40, 1984-1988.

The sources and time-integrated evolution of diamond-forming fluids - Trace elements and isotopic evidence

NASA Astrophysics Data System (ADS)

Klein-BenDavid, Ofra; Pearson, D. Graham; Nowell, Geoff M.; Ottley, Chris; McNeill, John C. R.; Logvinova, Alla; Sobolev, Nikolay V.

2014-01-01

Sub-micrometer inclusions in fibrous diamond growth zones carry high-density fluids (HDF) from which the host diamonds have precipitated. The chemistry of these fluids is our best opportunity of characterizing the diamond-forming environment. The major and trace element patterns of diamond-forming fluids vary widely. Such elemental signatures can be easily modified by a variety of mantle processes whereas radiogenic isotopes give a clear fingerprint of the time-integrated evolution of the fluid source region. Thus, the combination of elemental and isotope data is a powerful tool in constraining the origin of fluids from which diamonds precipitate. Here we present combined trace element composition (34 diamonds) and Sr isotopic data (23 diamonds) for fluid-rich diamonds from six worldwide locations. The Nd and Pb isotopic composition of two of the diamonds were also obtained. Several of the samples were analyzed in at least 2 locations to investigate variations in the fluid during diamond growth. The data was acquired using an off-line laser sampling technique followed by solution ICPMS and TIMS analysis. The Sr isotopic compositions of diamond fluids from the different suites range between convecting mantle values for Udachnaya (87Sr/86Sr363 = 0.70300 ± 16 to 0.70361 ± 4), to highly enriched values, up to 87Sr/86Sr = 0.72330 ± 3, for a diamond from Congo. No isochronous relationships were observed in any of the suites. The lowest Nd isotopic composition recorded so far in a diamond is from Congo (εNd71 = -40.4), which also contains the most radiogenic Sr isotopic composition. In contrast, a less enriched but still rather unradiogenic Nd isotope composition (εNd540 = -11) was obtained for a diamond from Snap Lake, which has moderately radiogenic Sr isotopic enrichment (87Sr/86Sr540 = 0.70821 ± 1). The Pb isotopic system measured in one diamond indicates a complex evolution for the fluid source, with extreme 207Pb/204Pb ratio (15.810 ± 3) and moderate, kimberlite-like 206Pb/204Pb and 208Pb/204Pb ratios. A multi-stage evolution of the diamond-forming fluids source can be constrained from our new isotopic data, indicating an Achaean enrichment event resulting in elevated U/Pb, Rb/Sr ratios and enrichment in LREEs. This source underwent a more recent fractionation, in the last 500 Myr that may have been related to the diamond-forming event. There is a strong correspondence between fluids with relatively unradiogenic Sr isotopes and relatively low (La, Nd, Sm)/(Nb, Zr) and (Ba, Th)/(Nb) ratios. Sr isotopic enrichment is accompanied by an increase in these ratios. The least trace element enriched and most isotopically depleted fluids are from the high-Mg carbonatitic suite. Thus, HDFs could be derived from asthenospheric mantle as low degree melts that interact to varying degrees with an ancient, metasomatized, rutile- and phlogopite bearing, sub continental lithosphere mantle. The internal heterogeneity in the Sr isotopic ratios within a single diamond suite and even within single diamonds may indicate fluid-mixing processes. Such mixing may occur during migration through preferred mantle veins and may be affected by the small-scale geochemical variability within them.

Evidence of mantle metasomatism in garnet peridotites from V. Grib kimberlite pipe (Arkhangelsk region, Russia)

NASA Astrophysics Data System (ADS)

Shchukina, Elena; Agashev, Alexey; Golovin, Nikolai; Pokhilenko, Nikolai

2013-04-01

We have studied 26 samples of garnet peridotite xenoliths from V.Grib pipe and 17 of them are phlogopite bearing. Studied peridotites have features of two types of modal metasomatism: low-temperature (˜ 1100 C°) and high-temperature (˜ 1100 C°). Low-temperature modal metasomatism: 17 samples contain modal phlogopite, which is present in the form of tabular grains (to 3 mm in size) and rims around pyrope grains. Chemical composition of minerals from phlogopite-garnet peridotites and phlogopite free peridotites is distinctly different. Olivine, garnet, orthopyroxene and clinopyroxene have higher concentration of FeO relative to these minerals in phlogopite free peridotites. Occurrence of phlogopite in peridotites indicates the influence of melt enriched in K2O, H2O, FeO and other incompatible elements. Two types of phlogopite have difference in chemical composition that indicates two different sources. High-temperature modal metasomatism: Reconstructed V.Grib pipe peridotite whole-rocks composition and high Mg# of peridotite olivines indicates that these samples are residues after 30-40 % partial melting of primitive mantle. At those high degree of partial melting all clinopyroxene and probably all garnet should be exhausted from residue. Character of REE patterns in garnets and clinopyroxenes indicates that the most garnets and all clinopyroxene in studied peridotites are of metasomatic origin. We used the method of geochemical modeling of fractional crystallization to establish the source's composition for garnets and clinopyroxenes. For geochemical modeling we used the composition of tholeitic basalts, picrites and carbonatites which occurred in Arkhangelsk diamondiferous province (ADP) and have emplacement ages similar to that of kimberlites. Modeling result indicates that garnets could be crystallized from alkali picrite and tholeite basalts compositions. Peridotites containing garnets equilibrated with picritic melt have a different position in lithospheric mantle section from that of peridotites with tholeitic originated garnets. Two geochemically distinct types of clinopyroxenes could be the products of crystallization of tholeite basalts (type 1) and carbonatites (type 2). Overall, the lithospheric mantle beneath V. Grib kimberlite pipe experienced a complex history including multiply metasomatic events. Metasomatic agents parental to peridotitic garnets and clinopyroxenes are similar in composition to basalts and carbonatites located within the ADP indicating that magmatic events within the province are interconnected.

History of the Colorado-Wyoming state line diatremes.

USGS Publications Warehouse

Collins, D.S.; Heyl, A.V.

1984-01-01

Although >90 kimberlite diatremes have been found in the area, it was not until after 1963 that these bodies were correctly identified. The presence of large inclusions of sedimentary rocks had hindered their recognition. In 1975 a diamond crystal 3.5 carats). They are usually colourless, but light-brown, blue-white, pale orange, pale to bright yellow and nearly black crystals occur. Associated minerals, including chrome-diopside, chromite, magnesian ilmenite, pyrope and omphacite, are described.-R.S.M.

Relationships between oxygen fugacity and metasomatism in the Kaapvaal subcratonic mantle, represented by garnet peridotite xenoliths in the Wesselton kimberlite, South Africa

NASA Astrophysics Data System (ADS)

Hanger, Brendan J.; Yaxley, Gregory M.; Berry, Andrew J.; Kamenetsky, Vadim S.

2015-01-01

A suite of 12 peridotite xenoliths from the Wesselton kimberlite was studied and found to sample the subcratonic lithospheric mantle over a pressure range from 3.6 to 4.7 GPa and a temperature range of 880 to 1120 °C. Major, minor and trace element compositions indicate that both metasomatised and un-metasomatised samples are present over this pressure range. Fe3 +/∑ Fe in garnet from four xenoliths was determined using Fe K-edge XANES spectroscopy, enabling the redox state of the sampled subcratonic mantle to be determined for three garnet bearing samples. ΔlogfO2[FMQ] varied from 0 to - 3.3 over the sampled pressure interval, with the un-metasomatised samples falling within the global trend of decreasing ΔlogfO2[FMQ] with increasing depth. Superimposed on this was an oxidation trend, at higher pressures (≥ 4.5 GPa), with ΔlogfO2 increasing by 1.5 to 2 units in the metasomatically enriched samples, indicating a clear link between metasomatism and oxidation. One potential source of this oxidation is a carbonated silicate melt, which will increase in carbonate content as ΔlogfO2 increases. Mantle minerals affected by such a melt have the potential to shift from the field of diamond stability into that of carbonate, threatening the stability of diamond.

Deep mantle structure as a reference frame for movements in and on the Earth

PubMed Central

Torsvik, Trond H.; van der Voo, Rob; Doubrovine, Pavel V.; Burke, Kevin; Steinberger, Bernhard; Ashwal, Lewis D.; Trønnes, Reidar G.; Webb, Susan J.; Bull, Abigail L.

2014-01-01

Earth’s residual geoid is dominated by a degree-2 mode, with elevated regions above large low shear-wave velocity provinces on the core–mantle boundary beneath Africa and the Pacific. The edges of these deep mantle bodies, when projected radially to the Earth’s surface, correlate with the reconstructed positions of large igneous provinces and kimberlites since Pangea formed about 320 million years ago. Using this surface-to-core–mantle boundary correlation to locate continents in longitude and a novel iterative approach for defining a paleomagnetic reference frame corrected for true polar wander, we have developed a model for absolute plate motion back to earliest Paleozoic time (540 Ma). For the Paleozoic, we have identified six phases of slow, oscillatory true polar wander during which the Earth’s axis of minimum moment of inertia was similar to that of Mesozoic times. The rates of Paleozoic true polar wander (<1°/My) are compatible with those in the Mesozoic, but absolute plate velocities are, on average, twice as high. Our reconstructions generate geologically plausible scenarios, with large igneous provinces and kimberlites sourced from the margins of the large low shear-wave velocity provinces, as in Mesozoic and Cenozoic times. This absolute kinematic model suggests that a degree-2 convection mode within the Earth’s mantle may have operated throughout the entire Phanerozoic. PMID:24889632

Deep mantle structure as a reference frame for movements in and on the Earth.

PubMed

Torsvik, Trond H; van der Voo, Rob; Doubrovine, Pavel V; Burke, Kevin; Steinberger, Bernhard; Ashwal, Lewis D; Trønnes, Reidar G; Webb, Susan J; Bull, Abigail L

2014-06-17

Earth's residual geoid is dominated by a degree-2 mode, with elevated regions above large low shear-wave velocity provinces on the core-mantle boundary beneath Africa and the Pacific. The edges of these deep mantle bodies, when projected radially to the Earth's surface, correlate with the reconstructed positions of large igneous provinces and kimberlites since Pangea formed about 320 million years ago. Using this surface-to-core-mantle boundary correlation to locate continents in longitude and a novel iterative approach for defining a paleomagnetic reference frame corrected for true polar wander, we have developed a model for absolute plate motion back to earliest Paleozoic time (540 Ma). For the Paleozoic, we have identified six phases of slow, oscillatory true polar wander during which the Earth's axis of minimum moment of inertia was similar to that of Mesozoic times. The rates of Paleozoic true polar wander (<1°/My) are compatible with those in the Mesozoic, but absolute plate velocities are, on average, twice as high. Our reconstructions generate geologically plausible scenarios, with large igneous provinces and kimberlites sourced from the margins of the large low shear-wave velocity provinces, as in Mesozoic and Cenozoic times. This absolute kinematic model suggests that a degree-2 convection mode within the Earth's mantle may have operated throughout the entire Phanerozoic.

Preservation of an Archaean whole rock Re-Os isochron for the Venetia lithospheric mantle: Evidence for rapid crustal recycling and lithosphere stabilisation at 3.3 Ga

NASA Astrophysics Data System (ADS)

van der Meer, Quinten H. A.; Klaver, Martijn; Reisberg, Laurie; Riches, Amy J. V.; Davies, Gareth R.

2017-11-01

Re-Os and platinum group element analyses are reported for peridotite xenoliths from the 533 Ma Venetia kimberlite cluster situated in the Limpopo Mobile Belt, the Neoarchaean collision zone between the Kaapvaal and Zimbabwe Cratons. The Venetian xenoliths provide a rare opportunity to examine the state of the cratonic lithosphere prior to major regional metasomatic disturbance of Re-Os systematics throughout the Phanerozoic. The 32 studied xenoliths record Si-enrichment that is characteristic of the Kaapvaal lithospheric mantle and can be subdivided into five groups based on Re-Os analyses. The most pristine group I samples (n = 13) display an approximately isochronous relationship and fall on a 3.28 ± 0.17 Ga (95 % conf. int.) reference line that is based on their mean TMA age. This age overlaps with the formation age of the Limpopo crust at 3.35-3.28 Ga. The group I samples derive from ∼50 to ∼170 km depth, suggesting coeval melt depletion of the majority of the Venetia lithospheric mantle column. Group II and III samples have elevated Re/Os due to Re addition during kimberlite magmatism. Group II has otherwise undergone a similar evolution as the group I samples with overlapping 187Os/188Os at eruption age: 187Os/188OsEA, while group III samples have low Os concentrations, unradiogenic 187Os/188OsEA and were effectively Re-free prior to kimberlite magmatism. The other sample groups (IV and V) have disturbed Re-Os systematics and provide no reliable age information. A strong positive correlation is recorded between Os and Re concentrations for group I samples, which is extended to groups II and III after correction for kimberlite addition. This positive correlation precludes a single stage melt depletion history and indicates coupled remobilisation of Re and Os. The combination of Re-Os mobility, preservation of the isochronous relationship, correlation of 187Os/188Os with degree of melt depletion and lack of radiogenic Os addition puts tight constraints on the formation and subsequent evolution of Venetia lithosphere. First, melt depletion and remobilisation of Re and Os must have occurred within error of the 3.28 Ga mean TMA age. Second, the refractory peridotites contain significant Re despite recording >40 % melt extraction. Third, assuming that Si-enrichment and Re-Os mobility in the Venetia lithospheric mantle were linked, this process must have occurred within ∼100 Myr of initial melt depletion in order to preserve the isochronous relationship. Based on the regional geological evolution, we propose a rapid recycling model with initial melt depletion at ∼3.35 Ga to form a tholeiitic mafic crust that is recycled at ∼3.28 Ga, resulting in the intrusion of a TTG suite and Si-enrichment of the lithospheric mantle. The non-zero primary Re contents of the Venetia xenoliths imply that TRD model ages significantly underestimate the true depletion age even for highly depleted peridotites. The overlap of the ∼2.6 Ga TRD ages with the time of the Kaapvaal-Limpopo collision is purely fortuitous and has no geological significance. Hence, this study underlines the importance of scrutiny if age information is to be derived from whole rock Re-Os analyses.

Diamond brecciation and annealing accompanying major metasomatism in eclogite xenoliths from the Sask Craton, Canada

NASA Astrophysics Data System (ADS)

Czas, Janina; Stachel, Thomas; Pearson, D. Graham; Stern, Richard A.; Read, George H.

2018-05-01

We studied eclogite xenoliths (diamond-free n = 28; diamondiferous n = 22) from the Cretaceous Fort à la Corne Kimberlite Field in Western Canada for their major element, trace element and oxygen isotope compositions to assess their origin and metasomatic history, and possible relationships between metasomatism and diamond formation. All eclogites have major element and oxygen isotope compositions consistent with a derivation from different levels of subducted, seawater altered oceanic crust. While barren xenoliths are more likely to be of gabbroic origin, diamond-bearing samples commonly have signatures consistent with shallow basaltic protoliths. The mineral chemistry in bimineralic diamond-free eclogites spans a wide compositional range, yet it is typically homogenous within individual xenoliths. Temperatures calculated from Mg-Fe exchange between garnet and clinopyroxene range widely for these eclogites, from 740 to 1300 °C, indicating the presence of eclogite through most of the lithospheric mantle. Diamondiferous samples are restricted to high temperatures (1180-1390 °C), consistent with derivation from the zone of diamond stability. Compositionally, diamond-bearing eclogites span a broad range similar to their barren counterparts, but there is also heterogeneity in mineral chemistry on the intra-sample level and in particular garnets are characterised by strong internal chemical gradients. This intra-sample heterogeneity is interpreted as the result of intense melt metasomatism, which occurred in temporal proximity to host kimberlite magmatism, strongly affected major, trace and even oxygen isotope values and resulted in diamond brecciation and annealing.

Structural analysis and implicit 3D modelling of high-grade host rocks to the Venetia kimberlite diatremes, Central Zone, Limpopo Belt, South Africa

NASA Astrophysics Data System (ADS)

Basson, I. J.; Creus, P. K.; Anthonissen, C. J.; Stoch, B.; Ekkerd, J.

2016-05-01

The Beit Bridge Complex of the Central Zone (CZ) of the Limpopo Belt hosts the 519 ± 6 Ma Venetia kimberlite diatremes. Deformed shelf- or platform-type supracrustal sequences include the Mount Dowe, Malala Drift and Gumbu Groups, comprising quartzofeldspathic units, biotite-bearing gneiss, quartzite, metapelite, metacalcsilicate and ortho- and para-amphibolite. Previous studies define tectonometamorphic events at 3.3-3.1 Ga, 2.7-2.5 Ga and 2.04 Ga. Detailed structural mapping over 10 years highlights four deformation events at Venetia. Rules-based implicit 3D modelling in Leapfrog Geo™ provides an unprecedented insight into CZ ductile deformation and sheath folding. D1 juxtaposed gneisses against metasediments. D2 produced a pervasive axial planar foliation (S2) to isoclinal F2 folds. Sheared lithological contacts and S2 were refolded into regional, open, predominantly southward-verging, E-W trending F3 folds. Intrusion of a hornblendite protolith occurred at high angles to incipient S2. Constrictional-prolate D4 shows moderately NE-plunging azimuths defined by elongated hornblendite lenses, andalusite crystals in metapelite, crenulations in fuchsitic quartzite and sheath folding. D4 overlaps with a: 1) 2.03-2.01 Ga regional M3 metamorphic overprint; b) transpressional deformation at 2.2-1.9 Ga and c) 2.03 Ga transpressional, dextral shearing and thrusting around the CZ and d) formation of the Avoca, Bellavue and Baklykraal sheath folds and parallel lineations.

Mineral inclusions in diamonds from the Kelsey Lake Mine, Colorado, USA: Depleted Archean mantle beneath the Proterozoic Yavapai province

NASA Astrophysics Data System (ADS)

Schulze, Daniel J.; Coopersmith, Howard G.; Harte, Ben; Pizzolato, Lori-Ann

2008-03-01

Thirty-four silicate and oxide inclusions large enough for in situ WDS electron microprobe analysis were exposed by grinding/polishing of 19 diamonds from the Kelsey Lake Mine in the Colorado-Wyoming State Line Kimberlite district. Eighteen olivines, seven Cr-pyropes, four Mg-chromites, and one orthopyroxene in 15 stones belong to the peridotite (P) suite and three garnets and one omphacite in three stones belong to the eclogite (E) suite. The fact that this suite is dominated by the peridotite population is in stark contrast to the other diamond suites studied in the State Line district (Sloan, George Creek), which are overwhelmingly eclogitic. Kelsey Lake olivine inclusions are magnesian (17 of 18 grains in 9 stones are in the range Fo 92.7-93.1), typical of harzburgitic P-suite stones worldwide, but unlike the more Fe-rich (lherzolitic) Sloan olivine suite. Mg-chromites (wt% MgO = 12.8-13.8; wt% Cr 2O 3 = 61.4-66.6) are in the lower MgO range of diamond inclusion chromites worldwide. Seven harzburgitic Cr-pyropes in five stones have moderately low calcium contents (wt% CaO = 3.3-4.3) but are very Cr-rich (wt% Cr 2O 3 = 9.7-16.7). A few stones have been analyzed by SIMS for carbon isotope composition and nitrogen abundance. One peridotitic stone is apparently homogeneous in carbon isotope composition (δ 13C PDB = -6.2‰) but with variable nitrogen abundance (1296-2550 ppm). Carbon isotopes in eclogitic stones range from "normal" for the upper mantle (δ 13C PDB = -5.5‰) to somewhat low (δ 13C PDB = -10.2‰), with little internal variation in individual stones (maximum difference is 3.6‰). Nitrogen contents (2-779 ppm) are lower than in the peridotitic stone, and are lower in cores than in rims. As, worldwide, harzburgite-suite diamonds have been shown to have formed in Archean time, we suggest that the Kelsey Lake diamond population was derived from a block of Archean lithosphere that, at the time of kimberlite eruption, existed beneath the Proterozoic Yavapai province. The mixed diamond inclusion populations from the State Line kimberlites appear to support models in which volumes of Wyoming Craton Archean mantle survive buried beneath Proterozoic continental crust. Such material may be mixed with eclogitic/lherzolitic regimes emplaced beneath or intermingled with the Archean rocks by Proterozoic subduction.

High pressure Raman and single crystal X-ray diffraction of the alkali/calcium carbonate, shortite

NASA Astrophysics Data System (ADS)

Williams, Q. C.; Vennari, C.; O'Bannon, E. F., III

2015-12-01

Raman and synchrotron-based single crystal x-ray diffraction data have been collected on shortite (Na2Ca2(CO3)3) up to 10 GPa at 300 K. Shortite is of geological importance due to its presence in the ground-mass of kimberlites, and the alkaline-/carbon-rich character of kimberlitic eruptions. This investigation focuses on shortite's high pressure behavior and is relevant to the behavior of alkali-carbonate systems within Earth's upper mantle. X-ray data demonstrate that shortite's symmetry remains stable at high pressures—retaining orthorhombic C crystal system (Amm2) up to 10 GPa; diffraction data show a 12% volume decrease from room pressure, and a bulk modulus of 71.0(3) GPa. These also demonstrate that the c-axis is twice as compressible as the a- and b-axes. This anisotropic compression is likely due to the orientation of the relatively stiff carbonate groups, a third of which are oriented close to the plane of the a- and b-axes, c axis compression primarily involves the compaction of the 9-fold coordinate sodium and calcium polyhedral. The two distinct carbonate sites within the unit cell give rise to two Raman symmetric stretching modes of the symmetric stretch; the carbonate group stretching vibration which is close to in plane with the a- and b-axes shifts at 3.75 cm-1/GPa as opposed to the carbonate groups which is closer to in plane with the b- and c-axes which shift at 4.25 cm-1/GPa. This furthers evidence for anisotropic compression observed using x-ray diffraction--as the carbonate in plane with the a- and b-axes is compressed, the strength of oxygen bonds along the c-axis with the cations increases, thus decreasing the pressure shift of the mode. The out of plane bending vibration shifts at -0.48 cm-1/GPa, indicating an enhanced interaction of the oxygens with the cations. The multiple in plane bending modes all shift positively, as do at the low frequency lattice modes, indicating that major changes in bonding do not occur up to 10 GPa. The data collected indicates that this phase is stable at 300 K to 10 GPa. The anisotropic compaction of this alkali-rich carbonate appears to be governed by the orientation of the sodium sites, thus the behavior of alkali-rich carbonates within the kimberlitic systems is likely dependent on the bonding and local geometry of alkali cations.

Diamond ages from Victor (Superior Craton): Intra-mantle cycling of volatiles (C, N, S) during supercontinent reorganisation

NASA Astrophysics Data System (ADS)

Aulbach, S.; Creaser, Robert A.; Stachel, Thomas; Heaman, Larry M.; Chinn, Ingrid L.; Kong, Julie

2018-05-01

The central Superior Craton hosts both the diamondiferous 1.1 Ga Kyle Lake and Jurassic Attawapiskat kimberlites. A major thermal event related to the Midcontinent Rift at ca. 1.1 Ga induced an elevated geothermal gradient that largely destroyed an older generation of diamonds, raising the question of when, and how, the diamond inventory beneath Attawapiskat was formed. We determined Re-Os isotope systematics of sulphides included in diamonds from Victor by isotope dilution negative thermal ionisation mass spectrometry in order to obtain insights into the age and nature of the diamond source in the context of regional tectonothermal evolution. Regression of the peridotitic inclusion data (n = 14 of 16) yields a 718 ± 49 Ma age, with an initial 187Os/188Os ratio of 0.1177 ± 0.0016, i.e. depleted at the time of formation (γOs -3.7 ± 1.3). Consequently, Re depletion model ages calculated for these samples are systematically overestimated. Given that reported 187Os/188Os in olivine from Attawapiskat xenoliths varies strongly (0.1012-0.1821), the low and nearly identical initial Os of sulphide inclusions combined with their high 187Re/188Os (median 0.34) suggest metasomatic formation from a mixed source. This was likely facilitated by percolation of amounts of melt sufficient to homogenise Os, (re)crystallise sulphide and (co)precipitate diamond; that is, the sulphide inclusions and their diamond host are synchronous if not syngenetic. The ∼720 Ma age corresponds to rifting beyond the northern craton margin during Rodinia break-up. This suggests mobilisation of volatiles (C, N, S) and Os due to attendant mantle stretching and metasomatism by initially oxidising and S-undersaturated melts, which ultimately produced lherzolitic diamonds with high N contents compared to older Kyle Lake diamonds. Thus, some rift-influenced settings are prospective with respect to diamond formation. They are also important sites of hidden, intra-lithospheric volatile redistribution that can be revealed by diamond studies. Later emplacement of the Attawapiskat kimberlites, linking the carbon cycle to the surface, was associated with renewed disturbance during passage of the Great Meteor Hotspot. Lherzolitic diamond formation from oxidising small-volume melts may be the expression of an early and deep stage of the lithospheric conditioning required for the successful eruption of kimberlites, which complements the late and shallow emplacement of volatile-rich metasomes after upward displacement of a redox freezing front.

Coesite-Diamond Assemblage in Ultrahigh Pressure Crustal and Mantle rocks: Evidence for Carbon Recycling

NASA Astrophysics Data System (ADS)

Sobolev, N. V.

2010-12-01

Coesite, a high-pressure polymorph of silica, was first discovered as part of a coesite-eclogite assemblage (coesite, garnet, omphacite) in equilibrium with diamond as diamond inclusion (DI) in Siberian diamond placers (Sobolev et al., 1976, Dokl. Akad. Nauk SSSR, 230: 1442). In recent years, coesite has become a key mineral coexisting with diamond both in kimberlite (DIs) and in UHP metamorphic rocks of the Kokchetav massif, Kazakhstan (diamondiferous gneisses and calcsilicate rocks). In the UHPM rocks of Kokchetav massif, coesite was first detected as inclusions in zircon associated with diamonds (Sobolev et al., 1991, Dokl. Akad. Nauk SSSR, 321: 184), as a result of the initial studies that had identified diamonds as inclusions in garnets and zircons (Sobolev, Shatsky, 1990, Nature, 343: 742). Garnet and omphacitic clinopyroxene are the principal primary minerals associated with coesite and diamond in UHP mantle and crustal rocks. Their compositions plot distinctly within the eclogitic compositional field and substantiate the existence of coesite presence as DIs in eclogitic (E-type) diamonds, as well as sometimes in xenoliths of diamondiferous eclogites (Shatsky et al., 2008, Lithos, 105:289). One of the major significant features of these eclogitic minerals in both UHPM and kimberlitic mantle occurrences is the K2O contents of the clinopyroxenes, reaching 1.6 wt.%, with Na2O and MnO in Ca-Mg-Fe garnets reaching 0.3 and 6.0 wt.%, respectively. Stable isotope data for C in diamonds and O in garnet, pyroxene and coesite have resulted in establishing a very wide range for these isotopes most typical for crustal conditions - i.e., atypical of mantle values. This is clearly shown for coesite DIs (Schulze et al., 2003, Nature, 428:68), garnets from diamondiferous eclogite xenoliths from Siberian kimberlites (Spetsius et al., 2008, Eur. J. Min., 20:375), garnets and clinopyroxenes from UHP calcsilicate diamondiferous rocks of the Kokchetav massif (Sobolev et al., in press, Contr. Min. Petr.). This extensive wide range in δ13C (PDB) for coesite-bearing diamonds, from -28 to +1.5 ‰, along with common crustal δ18O (SMOW) values from the principal rock-forming minerals (garnet and clinopyroxene) and accessory mineral (coesite), is typical for diamondiferous mantle eclogites, crustal UHPM rocks, and DIs. The petrogenetic evidences from all these rocks and minerals are indicative of major subduction of crustal protoliths (Ringwood, 1972, EPSL, 14:233), including the recycling of crustal carbon into diamonds in mantle eclogites, first speculated on by V.S. Sobolev and N.V. Sobolev (1980, Dokl. Akad. Nauk SSSR, 249: 1217).

Magma ascent, fragmentation and depositional characteristics of "dry" maar volcanoes: Similarities with vent-facies kimberlite deposits

NASA Astrophysics Data System (ADS)

Berghuijs, Jaap F.; Mattsson, Hannes B.

2013-02-01

Several maar craters within the Lake Natron-Engaruka monogenetic volcanic field (LNE-MVF) of northern Tanzania show compelling evidence for magmatic fragmentation and dry deposition. This is in contradiction of the common belief that most maars are formed through the explosive interaction between ascending magma and ground- or surface water. We here present a detailed study on the eruptive and depositional characteristics of the Loolmurwak and Eledoi maar volcanoes, two of the largest craters in the LNE-MVF, focusing on high-resolution stratigraphy, sedimentology, grain size distribution, pyroclast textures and morphologies, bulk geochemistry and mineral chemistry. At both maars, ejected material has been emplaced by a combination of pyroclastic surges and fallout. Indicators of phreatomagmatic fragmentation and wet deposition, such as impact sags, accretionary lapilli, vesiculated tuffs and plastering against obstacles, are absent in the deposits. Juvenile material predominantly occurs as fluidal-shaped vesicular melt droplets and contains no glass shards produced by the breakage of bubble walls. The Eledoi deposits comprise a large amount of inversely graded beds and lenses, which result from grain flow in a dry depositional environment. Preferential deposition of fine material toward the northern side of its crater can be related to effective wind winnowing in a dry eruption plume. This large variety of observations testifies to the dominance of magmatic fragmentation as well as dry deposition at the Loolmurwak and Eledoi maars, which is in line with what has been found for other structures in the LNE-MVF but contrasts with current ideas on maar formation. We infer that a volatile-rich, olivine melilitic magma was formed by small amounts of partial melting at upper mantle depths. With minimum average ascent rates of 5.3 m s- 1 for Loolmurwak and 26.2 m s- 1 for Eledoi, this magma rapidly moved toward the surface and exsolved a substantial amount of volatiles, sufficiently large to drive magmatic fragmentation. Both eruptions were pulsating in intensity and relatively short-lived, with estimated durations of 23 and 10 h for Loolmurwak and Eledoi, respectively. The depositional characteristics of these maars, including the abundant occurrence of mantle xenoliths in the deposits, as well as their envisaged mode of emplacement show a strong similarity to the often poorly preserved vent-facies of kimberlitic diatremes. Therefore, future research on well-preserved melilititic maar-diatreme deposits may provide valuable insights into kimberlite emplacement processes.

Water and metasomatism in the Slave cratonic lithosphere (Canada): an FTIR study

NASA Astrophysics Data System (ADS)

Kilgore, M.; Peslier, A. H.; Brandon, A. D.; Schaffer, L. A.; Pearson, D. G.; O'Reilly, S. Y.; Kopylova, M. G.; Griffin, W. L.

2017-12-01

Water in the mantle influences melting, viscosity, seismic velocity, and electrical conductivity. The role played by water in the long-term stabilization of cratonic roots is currently being debated [1]. This study focuses on water contents of mantle minerals (olivine, pyroxene and garnet) from xenoliths found in kimberlites of the Archean Slave craton. 19 mantle xenoliths from central Lac de Gras, and 10 from northern Jericho were analyzed by FTIR for water, and their equilibration depths span the several compositional layers identified beneath the region [2]. At both locations, the shallow peridotites have lower water contents in their olivines (11-30 ppm H2O) than those from the deeper layers (28-300 ppm H2O). The driest olivines, however, are not at the base of the cratonic lithosphere (>6 GPa) as in the Kaapvaal craton [1]. Instead, the deepest olivines are hydrous (31-72 ppm H2O at Lac de Gras and 275 ppm H2O at Jericho). Correlations of water in clinopyroxene and garnet with their other trace element contents are consistent with water being added by metasomatism by melts resembling kimberlite precursors in the mantle 0.35 Ga ago beneath Lac de Gras [1]. The northern Jericho xenoliths are derived from a region of the Slave craton that is even more chemically stratified, and was affected at depth by the 1.27 Ga Mackenzie igneous events [3,4]. Metasomatism at Jericho may be responsible for the particularly high olivine water contents (up to 300 ppm H2O) compared to those at Lac de Gras, which will be investigated by acquiring trace-element data on these xenoliths. These data indicate that several episodes of metasomatic rehydration occurred in the deep part of the Slave craton mantle lithosphere, with the process being more intense in the northern part beneath Jericho, likely related to a translithospheric suture serving as a channel to introduce fluids and/or melts in the northern region [5]. Consequently, rehydration of the lithosphere does not necessarily cause cratonic root delamination and these peridotites may represent localized metasomatic zones - the wall rocks to kimberlite magma passage. [1] Peslier et al. 2010 Nature 467, p78; [2] Aulbach et al. 2013 CG 352, p153; [3] Heaman et al. 2010 CJES 47, p369; [4] Kopylova et al. 2000 EPSL 181, p71; [5] Poudjom Djomani et al. 2005 GGG 6, n10.

The thermal regimes of the upper mantle beneath Precambrian and Phanerozoic structures up to the thermobarometry data of mantle xenoliths

NASA Astrophysics Data System (ADS)

Glebovitsky, V. A.; Nikitina, L. P.; Khiltova, V. Ya.; Ovchinnikov, N. O.

2004-05-01

The thermal state of the upper mantle beneath tectonic structures of various ages and types (Archaean cratons, Early Proterozoic accretionary and collisional orogens, and Phanerozoic structures) is characterized by geotherms and by thermal gradients (TG) derived from data on the P- T conditions of mineral equilibria in garnet and garnet-spinel peridotite xenoliths from kimberlites (East Siberia, Northeastern Europe, India, Central Africa, North America, and Canada) and alkali basalts (Southeastern Siberia, Mongolia, southeastern China, southeastern Australia, Central Africa, South America, and the Solomon and Hawaiian islands). The use of the same garnet-orthopyroxene thermobarometer (Theophrastus Contributions to Advanced Studies in Geology. 3: Capricious Earth: Models and Modelling of Geologic Processes and Objects 2000 44) for all xenoliths allowed us to avoid discrepancies in estimation of the P- T conditions, which may be a result of the mismatch between different thermometers and barometers, and to compare the thermal regimes in the mantle in various regions. Thus, it was established that (1) mantle geotherms and geothermal gradients, obtained from the estimation of P- T equilibrium conditions of deep xenoliths, correspond to the age of crust tectonic structures and respectively to the time of lithosphere stabilization; it can be suggested that the ancient structures of the upper mantle were preserved within continental roots; (2) thermal regimes under continental mantle between the Archaean cratons and Palaeoproterozoic belts are different today; (3) the continental mantle under Neoproterozoic and Phanerozoic belts is characterized by significantly higher values of geothermal gradient compared to the mantle under Early Precambrian structures; (4) lithosphere dynamics seems to change at the boundary between Early and Mezo-Neoproterozoic and Precambrian and Phanerozoic.

Microdiamond grade as a regionalised variable - some basic requirements for successful local microdiamond resource estimation of kimberlites

NASA Astrophysics Data System (ADS)

Stiefenhofer, Johann; Thurston, Malcolm L.; Bush, David E.

2018-04-01

Microdiamonds offer several advantages as a resource estimation tool, such as access to deeper parts of a deposit which may be beyond the reach of large diameter drilling (LDD) techniques, the recovery of the total diamond content in the kimberlite, and a cost benefit due to the cheaper treatment cost compared to large diameter samples. In this paper we take the first step towards local estimation by showing that micro-diamond samples can be treated as a regionalised variable suitable for use in geostatistical applications and we show examples of such output. Examples of microdiamond variograms are presented, the variance-support relationship for microdiamonds is demonstrated and consistency of the diamond size frequency distribution (SFD) is shown with the aid of real datasets. The focus therefore is on why local microdiamond estimation should be possible, not how to generate such estimates. Data from our case studies and examples demonstrate a positive correlation between micro- and macrodiamond sample grades as well as block estimates. This relationship can be demonstrated repeatedly across multiple mining operations. The smaller sample support size for microdiamond samples is a key difference between micro- and macrodiamond estimates and this aspect must be taken into account during the estimation process. We discuss three methods which can be used to validate or reconcile the estimates against macrodiamond data, either as estimates or in the form of production grades: (i) reconcilliation using production data, (ii) by comparing LDD-based grade estimates against microdiamond-based estimates and (iii) using simulation techniques.

Cretaceous potassic intrusives with affinities to aillikites from Jharia area: Magmatic expression of metasomatically veined and thinned lithospheric mantle beneath Singhbhum Craton, Eastern India

NASA Astrophysics Data System (ADS)

Srivastava, Rajesh K.; Chalapathi Rao, N. V.; Sinha, Anup K.

2009-11-01

Cretaceous potassic dykes and sills at the Jharia area intrude the Permo-carboniferous coal-bearing Gondwana sediments of the Eastern Damodar Valley, Singhbhum craton. These intrusives are widely regarded as a part of the Mesozoic alkaline and Rajmahal flood basalt magmatism in the Eastern Indian shield. Jharia intrusives display a wide petrographic diversity; olivine, phlogopite and carbonate are the predominant phases whereas apatite and rutile constitute important accessories. Impoverishment in sodium, silica and alumina and enrichment in potassium, titanium and phosphorous are the hallmark of these rocks and in this aspect they are strikingly similar to the rift-related aillikites (ultramafic lamprophyres) of Aillik Bay, Labrador. Crustal contamination of the Jharia magmas is minimal and the incompatible trace element ratios demonstrate (i) their generation by greater degrees of partial melting of a sub-continental lithospheric mantle (SCLM) source similar to that of the kimberlites of Dharwar craton, southern India, and (ii) retention of long-term memories of ancient (Archaean) subduction experienced by their source regions. We infer that a metasomatically veined and thinned lithosphere located at the margin of the Singhbhum craton and the inheritance of an ancient (Archaean) subducted component has played a significant role in deciding the diverging petrological and geochemical characters displayed by the Jharia potassic intrusives: those of kimberlites (orangeites) and lamproites (cratonic signature) and those of aillikites (rift-related signature). A substantial melt component of Jharia potassic intrusives was derived from the SCLM and the melt contribution of the Kerguelen plume is inferred to be minimal.

A shear-wave velocity model of the European upper mantle from automated inversion of seismic shear and surface waveforms

NASA Astrophysics Data System (ADS)

Legendre, C.; Meier, T.; Lebedev, S.; Friederich, W.; Viereck-Götte, L.

2012-04-01

Broadband waveforms recorded at stations in Europe and surrounding regions were inverted for shear-wave velocity of the European upper mantle. For events between 1995 and 2007 seismograms were collected from all permanent stations for which data are available via the data centers ORFEUS, GEOFON, ReNaSs and IRIS. In addition, we incorporated data from temporary experiments, including SVEKALAPKO, TOR, Eifel Plume, EGELADOS and other projects. Automated Multimode Inversion of surface and S-wave forms was applied to extract structural information from the seismograms, in the form of linear equations with uncorrelated uncertainties. Successful waveform fits for about 70,000 seismograms yielded over 300,000 independent linear equations that were solved together for a three-dimensional tomographic model. Resolution of the imaging is particularly high in the mantle lithosphere and asthenosphere. The highest velocities in the mantle lithosphere of the East European Craton are found at about 150 km depth. There are no indications for a large scale deep cratonic root below about 330 km depth. Lateral variations within the cratonic mantle lithosphere are resolved by our model as well. The locations of diamond bearing kimberlites correlate with reduced S-wave velocities in the cratonic mantle lithosphere. This anomaly is present in regions of both Proterozoic and Archean crust, pointing to an alteration of the mantle lithosphere after the formation of the craton. Strong lateral changes in S-wave velocity are found at the western margin of the East European Craton and hint to erosion of cratonic mantle lithosphere beneath the Scandes by hot asthenosphere. The mantle lithosphere beneath Western Europe and between the Tornquist-Teyissere Zone and the Elbe Line shows moderately high velocities and is of an intermediate character, between cratonic lithosphere and the thin lithosphere of central Europe. In central Europe, Caledonian and Variscian sutures are not associated with strong lateral changes in the lithosphere-asthenosphere system. Cenozoic anorogenic intraplate volcanism in central Europe and the Circum Mediterranean is found in regions of shallow asthenosphere and close to sharp gradients in the depth of the lithosphere-asthenosphere boundary. Low-velocity anomalies extending vertically from shallow upper mantle down to the transition zone are found beneath the Massive Central, Sinai, Canary Islands and Iceland.

Orientation relationship between diamond and magnesiochromite inclusions

NASA Astrophysics Data System (ADS)

Alvaro, Matteo; Angel, Ross; Nimis, Paolo; Milani, Sula; Harris, Jeff; Nestola, Fabrizio

2017-04-01

The correct determination of the relative crystallographic orientations of single crystals has many applications. When single crystals undergo phase transitions, especially at high pressures, the relative orientations of the two phases yields insights into transition mechanisms (Dobson et al 2013). On the other hand, determination of the crystallographic orientations of minerals included in diamonds can provide insights into the mechanisms of their entrapment and the timing of their formation relative to the host diamond (e.g. Nestola et al. 2014, Milani et al. 2016). The reported occurrence of non-trivial orientations for some minerals in diamonds, suggesting an epitaxial relationship, has long been considered to reflect contemporaneous growth of the diamond and the inclusion (e.g. syngenesis). Correct interpretation of such orientations requires (i) a statistically significant crystallographic data set for single and multiple inclusions in a large number of diamonds, and (ii) a robust data-processing method, capable of removing ambiguities derived from the high symmetry of the diamond and the inclusion. We have developed a software to perform such processing (OrientXplot, Angel et al. 2015), starting from crystallographic orientation matrixes obtained by X-ray diffractometry or EBSD data. Previous studies of inclusions in lithospheric diamonds, by single-crystal X-ray diffraction and EBSD, indicate a wide variety in the orientations of different inclusion phases with respect to their diamond host (Futergendler & Frank-Kamenetsky 1961; Frank-Kamenetsky 1964; Wiggers de Vries et al. 2011; Nestola et al. 2014, Milani et al. 2016). For example, olivine inclusions in lithospheric diamonds from Udachnaya do not show any preferred orientations with respect to their diamond hosts, but multiple inclusions in a single diamond often show very similar orientations within few degrees. In the present work on magnesiochromite inclusions in diamonds from Udachnaya, there is a partial orientation between inclusion and host. A (111) plane of each inclusion is sub-parallel to a {111} plane of their diamond host, but with random orientations of the magnesiochromite [100], [010] and [001] relative to the diamond. In one case, where a single inclusion comprised a magnesiochromite-olivine touching pair, the magnesiochromite was oriented as noted above and the olivine showed a random orientation. The implications of these observations for the mechanisms of diamond growth will be explored and the results will be compared and combined with previous work. This work was supported by ERC starting grant "INDIMEDEA" (307322) to F. Nestola and by the MIUR-SIR grant "MILE DEEp" (RBSI140351) to M. Alvaro. References Angel R. J. et al., J. Appl. Crystallogr. 48, 1330-1334 (2015). Wiggers de Vries D.F. et al., Contrib Mineral Petr 161, 565-579 (2011). Dobson D. P. et al., Nat. Geosci. 6, 575-578 (2013). Frank-Kamenetsky V.A. The nature of structural impurities and inclusions in minerals. Leningrad, Gos. Univ. (1964) Futergendler S.I. and Frank-Kamenetsky V.A. Zap Vsesoyuzn Mineral Obs 90, 230 (1961). Nestola F. et al., Int. Geol. Rev. 56(13), 1658-1667 (2014).

MARID-type Glimmerites from Kimberley, South Africa: Metasomes or high-pressure cumulates?

NASA Astrophysics Data System (ADS)

Förster, Michael W.; Prelevic, Dejan; Buhre, Stephan; Jacob, Dorrit E.

2015-04-01

Mica- amphibole- rutile- ilmenite- diopside (MARID) xenoliths are alkali-rich, coarse-grained ultramafic rocks, typical for heavily metasomatized subcontinental lithospheric mantle (Dawson & Smith, 1977). They are produced either by interaction of mantle wall rock with lamproitic melts that percolate through the mantle (Dawson and Smith 1977; Sweeney 1993), or as direct crystallization products of those melts (Waters 1987). Two rock samples of mica-rich (>90% phlogopite) xenoliths from the Boshof Road Dump of the Bultfontein kimberlite diamond mine in Kimberley, South Africa were analyzed for major and trace elements of minerals. Millimeter sized phlogopite is the dominant mineral, making up more than 90% of the rock. Other phases are in descending order: diopside, K-richterite, rutile and ilmenite. Phlogopite is homogenous in composition and appears without zonation. They are perpotassic with K/Al between 1.1 and 1.2 at an Mg#-value of 84.5-86.5. Clinopyroxene is low in Al2O3 with values <0.8%, but high in SiO2 with values around 55% and CaO values of 21% for both samples. Clinopyroxene show a slight zonation with Cr2O3 values rising towards the rim from 0.4 to 0.8%. All clinopyroxenes lie within the field of diopsides. REE to pyrolite normed pattern for diopsides show enrichment in LREE compared to HREE and a pronounced low in Ti. The examined specimens are classified as Glimmerite-type xenoliths as they comprise >90% phlogopite. Perpotassic phlogopites with K/Al >1 values are typical for MARID-type xenoliths by comprising low Mg# of 82-88 (Dawson 1987). We performed thermobarometric calculations on the clinopyroxenes, by using the equations of Putirka (2008). With a proposed lamproitic melt, like Waters (1987) suggested for a MARID parental magma, a pressure of 13 kbar (39 km) and a temperature of 1300 C was calculated. This depth coincides with the crustal thickness of the Kaapvaal craton (Nguuri et al. 2001). However, the pressure calculations depend on the fractionation of Al between melt and mineral and are not realistic for low-Al diopsides. Calculations by Konzett et al. (2014) yielded 4.2 GPa (155 km) by using a Ca-in-opx thermometer and a cratonic geotherm of 40 mW/m² and seem to be more realistic. By applying a sandwich experimental approach, mixing glimmerite samples with harzburgitic peridotites, we hope to achieve deeper insights into the origin of MARID-type glimmerites. References Dawson, J. B., & Smith, J. V. (1977). The MARID (mica-amphibole-rutile-ilmenite-diopside) suite of xenoliths in kimberlite. Geochimica et Cosmochimica Acta, 41(2), 309-323. Dawson, J. B. (1987). The MARID suite of xenoliths in kimberlite: relationship to veined and metasomatised peridotite xenoliths. Mantle Xenoliths. Chichester: John Wiley, 465-474. Konzett, J., Krenn, K., Rubatto, D., Hauzenberger, C., & Stalder, R. (2014). The formation of saline mantle fluids by open-system crystallization of hydrous silicate-rich vein assemblages-Evidence from fluid inclusions and their host phases in MARID xenoliths from the central Kaapvaal Craton, South Africa. Geochimica et Cosmochimica Acta, 147, 1-25. Nguuri, T. K., Gore, J., James, D. E., Webb, S. J., Wright, C., Zengeni, T. G., Gwavava, O. & Snoke, J. A. (2001). Crustal structure beneath southern Africa and its implications for the formation and evolution of the Kaapvaal and Zimbabwe cratons. Geophysical Research Letters, 28(13), 2501-2504. Putirka, K. D. (2008). Thermometers and barometers for volcanic systems. Reviews in Mineralogy and Geochemistry, 69(1), 61-120. Sweeney, R. J., Thompson, A. B., & Ulmer, P. (1993). Phase relations of a natural MARID composition and implications for MARID genesis, lithospheric melting and mantle metasomatism. Contributions to Mineralogy and Petrology, 115(2), 225-241. Waters, F. G. (1987). A suggested origin of MARID xenoliths in kimberlites by high pressure crystallization of an ultrapotassic rock such as lamproite. Contributions to Mineralogy and Petrology, 95(4), 523-533.

Widespread refertilization of cratonic and circum-cratonic lithospheric mantle

NASA Astrophysics Data System (ADS)

Tang, Yan-Jie; Zhang, Hong-Fu; Ying, Ji-Feng; Su, Ben-Xun

2013-03-01

Studies of mantle xenoliths have confirmed that Archean subcontinental lithospheric mantle (SCLM) is highly depleted in basaltic components (such as Al, Ca and Na) due to high-degree extraction of mafic and ultramafic melts and thus is refractory and buoyant, which made it chronically stable as tectonically independent units. However, increasing studies show that ancient SCLM can be refertilized by episodic rejuvenation events like infiltration of upwelling fertile material. The North China Craton is one of the most typical cases for relatively complete destruction of its Archean keel since the eruption of Paleozoic kimberlites, as is evidenced by a dramatic change in the compositions of mantle xenoliths sampled by Paleozoic to Cenozoic magmas, reflecting significant lithospheric thinning and the change in the character of the SCLM. The compositional change has been interpreted as the result of refertilization of Archean SCLM via multiple-stage peridotite-melt reactions, suggested by linear correlations between MgO and indices of fertility, covariations of Al2O3 with CaO, La/Yb, 87Sr/86Sr, 143Nd/144Nd, 187Os/188Os and Re-depletion ages (TRD), high Re abundances, scatter in Re-Os isotopic plot, variable in situ TRD ages of sulfides, and correlation between TRD ages and olivine Fo of peridotite xenoliths in Paleozoic kimberlites and Cenozoic basalts on the craton. By integrating major and trace element, Sr, Nd and Os isotopic compositions of peridotite xenoliths and orogenic massif peridotites from the continents of Europe, Asia, America, Africa and Australia, together with previous studies of petrology and geochemistry of global peridotites, we suggest that (1) refertilization of cratonic and circum-cratonic lithospheric mantle is widespread; (2) Archean SCLM worldwide has experienced a multi-stage history of melt depletion and refertilization since segregation from the convecting mantle; (3) cratonic SCLM may be more susceptible to compositional change caused by refertilization than is generally assumed; (4) the original character of much Archean cratonic mantle has been partly overprinted, or even erased by varying degrees of refertilization, which may play a key role in the rejuvenation and erosion of the SCLM beneath the Archean cratons. Due to the refertilization of ancient SCLM, (1) many published whole-rock Re-depletion ages cannot represent the formation ages of peridotites, but the mixtures of different generations of sulfides. Thus, the chronological significance of the Re-Os isotopic composition in individual peridotite should be cautiously interpreted; (2) many kimberlite- and intraplate basalt-borne lherzolite xenoliths, with major element compositions close to primitive mantle, may be the fragments of the ancient SCLM, strongly refertilized by infiltration of asthenosphere-derived melts, rather than newly-accreted SCLM. Consequently, new accretion of SCLM beneath ancient cratons such as the North China Craton may be less than was previously assumed.

Reconciling Electromagnetic and Seismic Constraints on Lithospheric Thickness and Composition of the Kaapvaal Craton, South Africa

NASA Astrophysics Data System (ADS)

Muller, M. R.; Fullea, J.; Jones, A. G.

2010-12-01

Much of the long-running debate regarding the depth extent of the continental lithosphere beneath Archean shield areas has focussed on the Kaapvaal Craton of South Africa. Our recent magnetotelluric surveys across the Kaapvaal Craton, as part of the Southern African Magnetotelluric Experiment (SAMTEX), indicate a lithospheric thickness of the order of 220 km or greater for the central core of the craton. In contrast, a recently published S-wave receiver function study and several surface wave studies suggest that the Kaapvaal lithosphere is characterized by an approximately 160 km thick high-velocity “lid” underlain by a low-velocity layer that is between 65 - 150 km thick, with the base of the high-velocity lid inferred to represent the “lithosphere-asthenosphere boundary”. Other body-wave, surface wave and S-wave receiver function studies in the area suggest that the (high-velocity) lithosphere is substantially thicker, in excess of 250 km for the most part. Evidence from mantle xenolith pressure-temperature arrays derived from Mesozoic kimberlites found across the Kaapvaal Craton requires that the base of the lithosphere (i.e., the base of the thermal boundary layer above which a conductive geotherm is maintained) be at least 220 km deep, if observed mantle geotherms in the range 35 - 38 mWm-2 are to be accounted for. The presence of richly diamondiferous kimberlites across the Kaapvaal Craton is also impossible to reconcile with a 160 km lithospheric thickness: the top of the diamond (pressure-temperature) stability field is deeper than 160 km for the mantle geotherm associated with a 160 km lithospheric thickness. In the work presented here, we use the recently developed LitMOD software package to derive both seismic velocity and electrical resistivity models for the lithosphere that are fully chemically, petrologically and thermodynamically consistent, and assess whether these apparently disparate views of the Kaapvaal lithosphere - provided by seismic, magnetotelluric and xenolith studies - can be reconciled. We address directly several key issues: (i) whether a 160 km lithospheric thickness (and its associated temperature and pressure variation with depth) is “internally” consistent with the high (> 4.7 km/s) S-wave velocities predicted for the seismic high-velocity lid, given typical Kaapvaal geochemical compositions from xenolith analyses, (ii) whether a 160 km lithospheric thickness and its associated electrical resistivity variation with depth is consistent with observed magnetotelluric responses, and (iii) whether the observed (negative) mantle conversion event at 160 km depth in one S-wave receiver function study can be explained by compositional layering within the Kaapvaal Craton, given that the geochemistry of xenoliths from younger Group I kimberlites provides evidence for chemical refertilization of the lithosphere in the depth range 160 - 200 km.

Noble gas isotopes and halogens in volatile-rich inclusions in diamonds

NASA Technical Reports Server (NTRS)

Burgess, Raymond; Turner, Grenville

1994-01-01

Application of the (40)Ar-(39)Ar method and noble gas studies to diamonds has increased our understanding of their age relationships to the host kimberlite or lamproite, and of the source and composition of volatile-rich fluids in the upper mantle. The properties of diamond (inert, high mechanical strength and low gas diffusivities) means they are especially useful samples for studying gases trapped deep within the earth (less than 150 km) as they are unlikely to have undergone loss or exchange of entrapped material since formation. Volatile-rich fluids (H2O-CO2) are important agents for metasomatic processes in the upper mantle, and the noble gases and halogens preferentially partition into this phase leading to a strong geochemical coherence between these groups of elements. The abundances of the halogens in the major reservoirs of the Earth shows a marked progression from chlorine, concentrated in the oceans, through to iodine which, through its affinity to organic material, is concentrated mainly in sediments. Abundances in the upper mantle are low. This is particularly true for iodine which is of special interest in view of its potential significance as an indicator of sediment recycling and by way of its link to (129)Xe amomalies in the mantle through the low extinct isotope (129)I. Extensions of the (40)Ar-(39)Ar technique enable measurements of halogens and other elements (K, Ca, Ba, U) by production of noble gas isotopes from these species during neutron irradiation. Samples analyzed in this way include 15 coated stones from an unknown source in Zaire, 3 boarts from the Jwaneng and 1 boart from the Orapa kimberlites, both in Botswana.

Cr-rich rutile: A powerful tool for diamond exploration

NASA Astrophysics Data System (ADS)

Malkovets, V. G.; Rezvukhin, D. I.; Belousova, E. A.; Griffin, W. L.; Sharygin, I. S.; Tretiakova, I. G.; Gibsher, A. A.; O'Reilly, S. Y.; Kuzmin, D. V.; Litasov, K. D.; Logvinova, A. M.; Pokhilenko, N. P.; Sobolev, N. V.

2016-11-01

Mineralogical studies and U-Pb dating have been carried out on rutile included in peridotitic and eclogitic garnets from the Internatsionalnaya pipe, Mirny field, Siberian craton. We also describe a unique peridotitic paragenesis (rutile + forsterite + enstatite + Cr-diopside + Cr-pyrope) preserved in diamond from the Mir pipe, Mirny field. Compositions of rutile from the heavy mineral concentrates of the Internatsionalnaya pipe and rutile inclusions in crustal almandine-rich garnets from the Mayskaya pipe (Nakyn field), as well as from a range of different lithologies, are presented for comparison. Rutile from cratonic mantle peridotites shows characteristic enrichment in Cr, in contrast to lower-Cr rutile from crustal rocks and off-craton mantle. Rutile with Cr2O3 > 1.7 wt% is commonly derived from cratonic mantle, while rutiles with lower Cr2O3 may be both of cratonic and off-cratonic origin. New analytical developments and availability of standards have made rutile accessible to in situ U-Pb dating by laser ablation ICP-MS. A U-Pb age of 369 ± 10 Ma for 9 rutile grains in 6 garnets from the Internatsionalnaya pipe is consistent with the accepted eruption age of the pipe (360 Ma). The equilibrium temperatures of pyropes with rutile inclusions calculated using Ni-in-Gar thermometer range between 725 and 1030 °C, corresponding to a depth range of ca 100-165 km. At the time of entrainment in the kimberlite, garnets with Cr-rich rutile inclusions resided at temperatures well above the closure temperature for Pb in rutile, and thus U-Pb ages on mantle-derived rutile most likely record the emplacement age of the kimberlites. The synthesis of distinctive rutile compositions and U-Pb dating opens new perspectives for using rutile in diamond exploration in cratonic areas.

Calcium Isotopic Composition of Bulk Silicate Earth

NASA Astrophysics Data System (ADS)

Kang, J.; Ionov, D. A.; Liu, F.; Zhang, C.; Zhang, Z.; Huang, F.

2016-12-01

Ca isotopes are used to study the accretion history of the Earth and terrestrial planets, but, Ca isotopic composition of the Bulk Silicate Earth (BSE) remains poorly constrained [1]. To better understand the Ca isotopic composition of BSE, we analyzed 22 well studied peridotite xenoliths from Tariat (Mongolia), Vitim (southern Siberia) and Udachnaya (Siberian Craton). These samples include both fertile and highly depleted garnet and spinel peridotites that show no or only minor post-melting metasomatism or alteration. Ca isotope measurements were done on a Triton-TIMS using double spike method at the Guangzhou Institute of Geochemistry, CAS. The data are reported as δ44/40Ca (relative to NIST SRM 915a). Results for geostandards are consistent with those from other laboratories. 2 standard deviations of SRM 915a analyses are 0.13‰ (n=48). δ44/40Ca of both and fertile and refractory peridotites range from 0.79 to 1.07‰ producing an average of 0.93±0.12‰ (2SD). This value defines the Ca isotopic composition of the BSE, which is consistent with the average δ44/40Ca of oceanic basalts ( 0.90‰)[2,3]. [1] Huang et al (2010) EPSL 292; [2] Valdes et al (2014) EPSL 394; [3]DePaolo (2004) RMG 55.

Native iron in the continental lower crust - Petrological and geophysical implications

NASA Technical Reports Server (NTRS)

Haggerty, S. E.; Toft, P. B.

1985-01-01

Lower crustal granulite xenoliths recovered from a kimberlite pipe in western Africa contain native iron (Fe) as a decomposition product of garnet and ilmenite. Magnetic measurements show that less than 0.1 percent (by volume) of iron metal is present. Data from geothermometry and oxygen geobarometry indicate that the oxide and metal phases equilibrated between iron-wuestite and magnetite-wuestite buffers, which may represent the oxidation state of the continental lower crust, and the depleted lithospheric upper mantle. Ferromagnetic native iron could be stable to a depth of about 95 kilometers and should be considered in the interpretation of long-wavelength static magnetic anomalies.

Native iron in the continental lower crust - Petrological and geophysical implications

NASA Astrophysics Data System (ADS)

Haggerty, S. E.; Toft, P. B.

1985-08-01

Lower crustal granulite xenoliths recovered from a kimberlite pipe in western Africa contain native iron (Fe) as a decomposition product of garnet and ilmenite. Magnetic measurements show that less than 0.1 percent (by volume) of iron metal is present. Data from geothermometry and oxygen geobarometry indicate that the oxide and metal phases equilibrated between iron-wuestite and magnetite-wuestite buffers, which may represent the oxidation state of the continental lower crust, and the depleted lithospheric upper mantle. Ferromagnetic native iron could be stable to a depth of about 95 kilometers and should be considered in the interpretation of long-wavelength static magnetic anomalies.

Diavik Mine, Canada

NASA Image and Video Library

2017-04-13

This image from NASA Terra spacecraft shows the Diavik Mine in northern Canada.The largest diamond found in North America came from the Diavik Mine. The Foxfire diamond weighs an impressive 187 carats, and was discovered in August 2015; it has been displayed in several museums throughout North America. The Diavik mine is located on an island in Lac de Gras, within the Lac de Gras kimberlite field, among other diamond mines. The image was acquired September 23, 2016, covers an area of 13.8 by 19.4 km, and is located at 64.5 degrees north, 110.2 degrees west. https://photojournal.jpl.nasa.gov/catalog/PIA21536

The sponge genus Ephydatia from the high-latitude middle Eocene: environmental and evolutionary significance.

PubMed

Pisera, Andrzej; Manconi, Renata; Siver, Peter A; Wolfe, Alexander P

2016-01-01

The freshwater sponge species Ephydatia cf. facunda Weltner, 1895 (Spongillida, Spongillidae) is reported for the first time as a fossil from middle Eocene lake sediments of the Giraffe kimberlite maar in northern Canada. The sponge is represented by birotule gemmuloscleres as well as oxea megascleres. Today, E. facunda inhabits warm-water bodies, so its presence in the Giraffe locality provides evidence of a warm climate at high latitudes during the middle Eocene. The morphological similarity of the birotules to modern conspecific forms suggests protracted morphological stasis, comparable to that reported for other siliceous microfossils from the same locality.

Cavitations synthesis of carbon nanostructures

NASA Astrophysics Data System (ADS)

Voropaev, S.

2011-04-01

Originally an idea of diamonds production by hydrodynamical cavitation was presented by academician E M Galimov. He supposed the possibility of nature diamonds formation at fast magma flowing in kimberlitic pipes during bubbles collapse. This hypothesis assumes a number of processes, which were not under consideration until now. It concerns cavitation under high pressure, growth and stability of the gas- and vapors bubbles, their evolution, and corresponding physical- and chemical processes inside. Experimental setup to reproduce the high pressure and temperature reaction centers by means of the cavitation following the above idea was created. A few crystalline nanocarbon forms were successfully recovered after treatment of benzene (C6H6).

Petrology of the Northern Anabar alkaline-ultramafic rocks (the Siberian Craton, Russia) and the role of metasomatized lithospheric mantle in their genesis

NASA Astrophysics Data System (ADS)

Kargin, Alexey; Golubeva, Yulia; Demonterova, Elena

2017-04-01

The southeastern margin of the Anabar shield (the Siberian Craton) in Mesozoic was characterized by intense alkaline-ultramafic (include diamondiferous kimberlite) magmatism. This zone is located within the Archean-Proterozoic Hapchan terrane and includes several fields of alkaline-ultramafic rocks that formed during three main episodes (Zaytsev and Smelov, 2010; Sun et al., 2014): Late Triassic (235-205 Ma), Middle-Late Jurassic (171-149 Ma), Cretaceous (105 Ma). Following the revised classification scheme of Tappe et al. (2005), the alkaline-ultramafic rocks of the Anabar region were identified, correspondingly, as 1) Late Triassic aillikites, damtjernites, and orangeites; 2) Middle-Late Jurassic silicocarbonatites and 3) Cretaceous carbonatites. According to mineralogical, geochemical and isotopic (Sm-Nd, Rb-Sr) data on the alkaline-ultramafic rocks of the Anabar region, the following scheme of the mantle source evolution is suggested: 1). Ascent of the asthenospheric (or plume) material to the base of the lithospheric mantle containing numerous carbonate- and phlogopite-rich veins in Late Triassic led to the generation of orangeite and aillikite magmas; 2). Evolution of aillikite magmas during their ascent and interaction with the surrounding lithospheric mantle (e.g. mantle-rock assimilation and/or melt differentiation) resulted in the accumulation of Mg-Si components in alkaline-ultramafic magmas and was accompanied by a change in liquidus minerals (from apatite-carbonate to olivine and Ca-silicate). Exsolution of carbonate-rich fluid at this stage was responsible for the formation of damtjernite magmas. 3). The tectonothermal activation within the Anabar region in Jurassic was marked by the generation of silicocarbonatitic magmas. Their geochemical composition suggests decreasing abundance of phlogopite-rich veins in the lithospheric mantle source. 4). In Cretaceous, the alkaline-ultramafic magmatism shifted into the central part of the Hapchan terrane where produced several carbonatite pipes and dykes. Their geochemical composition indicates the predominance of the carbonate component in the source region and a decrease of the thickness of the lithospheric mantle. This study was supported by Russian Science Foundation №16-17-10068. Tappe S., Foley S.F., Jenner G.A. et al. 2006. Genesis of Ultramafic Lamprophyres and Carbonatites at Aillik Bay, Labrador: a Consequence of Incipient Lithospheric Thinning beneath the North Atlantic Craton // J. Petrology. V. 47 (7). P. 1261-1315. Sun J., Liu C.Z., Tappe S. et al. 2014. Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: Insights from in situ U-Pb and Sr-Nd perovskite isotope analysis // Earth Planet. Sci. Lett. V. 404. P. 283-295. Zaytsev A.I., Smelov A.P., 2010. Isotope Geochronology of Kimberlite Formation Rocks from Yakutian Province // Publication of the Institute of Diamonds Geology, Siberian branch of the Russian Academy of Sciences, Yakutsk (107 pp. (in Russian)).

Magnesium isotope fractionation in co-existing clino-pyroxene and garnet: implications for geothermometry and mantle source characterization

NASA Astrophysics Data System (ADS)

Chakrabarti, R.; Jacobsen, S. B.; Basu, A. R.

2011-12-01

It is now well established that the Mg isotopic composition of the bulk silicate Earth, as represented by olivines, peridotites and basalts is identical to bulk meteorites and the Moon. However, small differences have been documented between co-existing olivines and clino-pyroxenes in mantle xenoliths as well as co-existing hornblendes and biotites in granitoids; spinels show some of the heaviest δ26Mg (deviation of the 26Mg/24Mg ratio from the Dead Sea Metal standard). A recent study has documented a large Mg isotopic fractionation between co-existing omphacite and garnet (Δ26MgOMP-GT = δ26MgOMP - δ26MgGT ~1.14) from eclogites in the Dabie orogen of China. This large equilibrium Mg isotope fractionation is explained by the difference in coordination number of Mg in omphacite (six) and garnet (eight). We report stable Mg isotopic compositions of co-existing garnet and clino-pyroxenes from different mantle-derived rocks. Garnet-omphacite pairs analyzed are from an eclogite xenolith from the Roberts Victor kimberlite pipe, the ultra-high pressure Tso Morari eclogite from the Ladakh Himalayas and the Healdsburg eclogite from the Franciscan Subduction Complex, which have a wide range in estimated temperatures of equilibration. Although, the latter two eclogites were exhumed in orogenic belts, our selective picking of the mineral cores for analysis avoided retrograded compositions. We have also analyzed Cr-diopside and pyrope-rich garnet pairs from several southern African kimberlite pipes. These include granular garnet peridotite xenoliths (P = 30-40 kbar, T =950-10500C) as well as the deeper sheared xenoliths (P = 50-60 kbar, T = 13500C). Rapid quenching of the kimberlite-hosted xenoliths ensures minimal low temperature pervasive alteration of these samples. Also analyzed are samples from the Gore Mt. amphibolite and a wollastonite-diopside-garnet skarn from the Adirondacks with equilibration temperatures of 700-7260C. Minerals were separated by hand-picking under a binocular microscope. Mg was quantitatively separated from other matrix elements using cation exchange chromatography. All three Mg isotopes were simultaneously measured using the IsoProbe-P MC-ICPMS at Harvard University by sample-standard bracketing. Our results from 11 garnet-clinopyroxene mineral pairs with widely varying temperatures of equilibration indicate that δ26Mg in garnet (-0.6 to -2.3) is much lower than that in co-existing clino-pyroxenes (-0.1 to -0.6 and -1.3 in the wollastonite skarn). This result is consistent with theoretical predictions as well as recent results from the Dabie orogen. Δ26Mg between clino-pyroxene and garnet ranges from 0.7 to 2.3. Our results suggest a temperature dependence of Δ26Mg between clino-pyroxene and garnet in mantle-derived rocks which can potentially be used as a geothermometer. Large Mg isotopic fractionation between co-existing garnet and clino-pyroxenes has implications for source characterization (garnet peridotite versus eclogite) of mantle-derived melts.

Tectonic Activity and Processes Preceding the Formation of the Dead Sea Fault Zone

NASA Astrophysics Data System (ADS)

Eppelbaum, L. V.; Pilchin, A. N.

2007-12-01

Analysis of geological-geophysical data indicates that at the end of the Proterozoic, blocks of the Arabian Shield (AS) were thrust to the north-west onto the crust of the proto-Mediterranean (PM). This was caused by the pushing of oceanic crust from the south-east forming the Najd faults system (NF). This thrusting took place between 630 and 590 Ma, and is confirmed by the offsets between the Yanbu suture of the AS and Allaqi-Sol Hamid suture of the Nubian Shield (NS), the Bi'r Umq suture of AS and Nakasib suture of NS, and parts of the Yanbu and Nabitah sutures of AS. This caused the separation of AS from NS, and AS from the continental crust to north-east of it with its north-western displacement, resulting in opening of the Persian Gulf. This caused the start of deposition of huge amounts of Vendian-Cambrian evaporites in Saudi Arabia, Oman, Persian Gulf, Zagros, central Iran and other regions. The fact of the formation and preservation of the evaporites, and the common similarities in Vendian-Triassic sedimentary cover of Central Iran, Zagros, Taurus, and Arabian Plate (AP) and common Late Proterozoic-Early Paleozioc magmatic activity, show that these regions did not change their position significantly since then. Results of the DESERT project show that the lowermost part of the crust is present east of the Dead Sea Fault Zone (DSFZ), but it is absent west of it. This could be explained by detachment of the bottom part of the crust west of DSFZ during AP thrusting onto the crust of PM. The lithospheric slice discovered by seismic data between Moho and depth of about 55 km in S. Israel could be a remnant of that crust. During the thrusting, the AP overrode the detached slice. The slice was later remelted during formation of the postorogenic magmatic rocks of 590-530 Ma widespread in Jordan. The formation of three dyke swarms in S. Israel (600-540 Ma), widespread dykes in Sinai (590-530 Ma) and AP (590-530 Ma), as well as high-T-low-P metamorphism between 600 and 530 Ma, point to a huge release of heat likely caused by friction during the thrusting. Presence of giant quantities of K-rich granites also points to reworking of continental crust in the region. Small amount of magmatic formations younger than Cambrian age west of DSFZ and significant amount of magmatic formations of this period east of DSFZ also indicate to presence of the plate beneath Israel. Offset of suture zones within AS shows that displacement was maximal for the northern blocks of AS. This is in agreement with known separation of Israel's crust into three blocks: Negev, Judea-Samaria and Galilee- Lebanon. Numerous markers of high to ultra-high pressure conditions signify to collision between the AP and the PM. These markers are: iron rich aegerine-augite and olivine-rich phenocrysts in S. Israel; peridotite xenoliths in S. Israel equilibrated at depth ~33-34 km; discovery of diamonds, micro-diamonds and indicator minerals (Cr- diopside, orange garnet, pyrope, coesite, picroilmenite, moissanite, carbonado, corundum, olivine, perovskite, aegerine, Ti-augite) in S. Israel; garnet clinopyroxenites, garnet granulites, indicator minerals, and eclogite-like rocks in Mt. Carmel area of N. Israel; iron-rich garnets in Sinai; eclogites, diamonds and indicator minerals in non-kimberlite environments in Syria; ophiolites exposed in Syria at northern extension of the DSFZ; ophiolite-like rocks in Sinai. These markers are located along or in close proximity to the DSFZ. Different isostatic conditions east of the edge of- and above- the underlying plate, along with the eventual activation of the plate caused the later formation of the DSFZ.

Convection pattern and stress system under the African plate

NASA Technical Reports Server (NTRS)

Liu, H.-S.

1977-01-01

Studies on tectonic forces from satellite-derived gravity data have revealed a subcrustal stress system which provides a unifying mechanism for uplift, depression, rifting, plate motion and ore formation in Africa. The subcrustal stresses are due to mantle convection. Seismicity, volcanicity and kimberlite magmatism in Africa and the development of the African tectonic and magnetic features are explained in terms of this single stress system. The tensional stress fields in the crust exerted by the upwelling mantle flows are shown to be regions of structural kinship characterized by major concentration of mineral deposits. It is probable that the space techniques are capable of detecting and determining the tectonic forces in the crust of Africa.

In situ analysis of carbon isotopes in North American diamonds

NASA Astrophysics Data System (ADS)

van Rythoven, A. D.; Hauri, E. H.; Wang, J.; McCandless, T.; Shirey, S. B.; Schulze, D. J.

2010-12-01

Diamonds from three North American kimberlite occurrences were investigated with cathodoluminescence (CL) and secondary ion mass spectrometry (SIMS) to determine their growth history and carbon isotope composition. Diamonds analyzed include fourteen from Lynx (Quebec), twelve from Kelsey Lake (Colorado) and eleven from A154 South (Diavik mine, Northwest Territories). Growth histories for the diamonds vary from simple to highly complex based on their CL images and depending on the individual stone. Deformation laminae are evident in CL images of the Lynx diamonds that typically are brownish in color. Two to five points per diamond were analyzed by SIMS for carbon isotope composition. Sample heterogeneity is minimal in terms of δ13C (vs. PDB) values. Points within single diamond had a maximum range of approximately 1 ‰. The results for the A154 South (-6.4 to -3 ‰) and Kelsey Lake (-11.2 to -2.6 ‰) stones were in accordance with earlier reported values. The Lynx kimberlite stones have anomalously high ratios and range from -3.5 to +0.2 ‰ (average: -1.4 ‰). No previous carbon isotope analyses on diamonds from Lynx or any other eastern Superior craton occurrence have been published. The diamonds possess carbon isotope ratios higher than those for the only other reported analyses of Superior craton diamonds at Wawa, Ontario (-5.5 to -1.1 ‰). In global terms, the only published analyses of diamonds that consistently contain even higher values are those from New South Wales (Australia). However, these diamonds are alluvial and contain eclogitic and/or exotic mineral inclusions. The Lynx diamonds are entirely peridotitic and from a primary deposit. The unusually low (i.e. >-5‰) δ13C values of the Lynx (and Wawa) diamonds may indicate a different carbon reservoir for the Superior craton mantle as compared to other cratons.

A subduction wedge origin for Paleoarchean peridotitic diamonds and harzburgites from the Panda kimberlite, Slave craton: evidence from Re-Os isotope systematics

NASA Astrophysics Data System (ADS)

Westerlund, K. J.; Shirey, S. B.; Richardson, S. H.; Carlson, R. W.; Gurney, J. J.; Harris, J. W.

2006-09-01

An extensive study of peridotitic sulfide inclusion bearing diamonds and their prospective harzburgitic host rocks from the 53 Ma Panda kimberlite pipe, Ekati Mine, NWT Canada, has been undertaken with the Re-Os system to establish their age and petrogenesis. Diamonds with peridotitic sulfide inclusions have poorly aggregated nitrogen (<30% N as B centers) at N contents of 200-800 ppm which differs from that of chromite and silicate bearing diamonds and indicates residence in the cooler portion of the Slave craton lithospheric mantle. For most of the sulfide inclusions, relatively low Re contents (average 0.457 ppm) and high Os contents (average 339 ppm) lead to extremely low 187Re/188Os, typically << 0.05. An age of 3.52 ± 0.17 Ga (MSWD = 0.46) and a precise initial 187Os/188Os of 0.1093 ± 0.0001 are given by a single regression of 11 inclusions from five diamonds that individually provide coincident internal isochrons. This initial Os isotopic composition is 6% enriched in 187Os over 3.5 Ga chondritic or primitive mantle. Sulfide inclusions with less radiogenic initial Os isotopic compositions reflect isotopic heterogeneity in diamond forming fluids. The harzburgites have even lower initial 187Os/188Os than the sulfide inclusions, some approaching the isotopic composition of 3.5 Ga chondritic mantle. In several cases isotopically distinct sulfides occur in different growth zones of the same diamond. This supports a model where C-O-H-S fluids carrying a radiogenic Os signature were introduced into depleted harzburgite and produced diamonds containing sulfides conforming to the 3.5 Ga isochron. Reaction of this fluid with harzburgite led to diamonds with less radiogenic inclusions while elevating the Os isotope ratios of some harzburgites. Subduction is a viable way of introducing such fluids. This implies a role for subduction in creating early continental nuclei at 3.5 Ga and generating peridotitic diamonds.

Volatile composition of microinclusions in diamonds from the Panda kimberlite, Canada: Implications for chemical and isotopic heterogeneity in the mantle

NASA Astrophysics Data System (ADS)

Burgess, Ray; Cartigny, Pierre; Harrison, Darrell; Hobson, Emily; Harris, Jeff

2009-03-01

In order to better investigate the compositions and the origins of fluids associated with diamond growth, we have carried-out combined noble gas (He and Ar), C and N isotope, K, Ca and halogen (Cl, Br, I) determinations on fragments of individual microinclusion-bearing diamonds from the Panda kimberlite, North West Territories, Canada. The fluid concentrations of halogens and noble gases in Panda diamonds are enriched by several orders of magnitude over typical upper mantle abundances. However, noble gas, C and N isotopic ratios ( 3He/ 4He = 4-6 Ra, 40Ar/ 36Ar = 20,000-30,000, δ 13C = -4.5‰ to -6.9‰ and δ 15N = -1.2‰ to -8.8‰) are within the worldwide range determined for fibrous diamonds and similar to the mid ocean ridge basalt (MORB) source value. The high 36Ar content of the diamonds (>1 × 10 -9 cm 3/g) is at least an order of magnitude higher than any previously reported mantle sample and enables the 36Ar content of the subcontinental lithospheric mantle to be estimated at ˜0.6 × 10 -12 cm 3/g, again similar to estimates for the MORB source. Three fluid types distinguished on the basis of Ca-K-Cl compositions are consistent with carbonatitic, silicic and saline end-members identified in previous studies of diamonds from worldwide sources. These fluid end-members also have distinct halogen ratios (Br/Cl and I/Cl). The role of subducted seawater-derived halogens, originally invoked to explain some of the halogen ratio variations in diamonds, is not considered an essential component in the formation of the fluids. In contrast, it is considered that large halogen fractionation of a primitive mantle ratio occurs during fluid-melt partitioning in forming silicic fluids, and during separation of an immiscible saline fluid.

Lu-Hf, in-situ Sr and Pb isotope and trace element systematics for mantle eclogites from the Diavik diamond mine: Evidence for Paleoproterozoic subduction beneath the Slave craton, Canada

NASA Astrophysics Data System (ADS)

Schmidberger, Stefanie S.; Simonetti, Antonio; Heaman, Larry M.; Creaser, Robert A.; Whiteford, Sean

2007-02-01

Lu-Hf, Sm-Nd and in-situ clinopyroxene Sr and Pb isotope systematics, and mineral major and in-situ trace element compositions were obtained for a suite of non-diamond and diamond-bearing eclogites from the Diavik kimberlites (A154; 55 Ma old), Slave craton (Canada). Temperature estimates of last equilibration in the lithosphere for the non-diamond-bearing Diavik eclogites define two groups; low-temperature (800-1050 °C) and high-temperature eclogites (1100-1300 °C). Most diamond-eclogites indicate temperatures similar to those of the high-temperature eclogites. Isotopic and major and trace element systematics for the non-diamond- and diamond-bearing eclogites indicate overlapping chemical compositions suggesting similar rock formational histories. Calculated whole rock major and trace element abundances using chemical and modal abundances for constituent minerals exhibit broad similarities with mafic cumulates from ophiolite sequences. Most importantly the calculated whole rock eclogite compositions display positive Sr and Eu anomalies, typically interpreted as the result of plagioclase accumulation in cumulate rocks of oceanic crust sequences. Initial whole rock Hf isotopic values and in-situ Sr isotope data from clinopyroxene grains provide evidence that the eclogites were derived from precursor rocks with depleted mantle isotope characteristics. These combined results support the interpretation that the eclogites from Diavik represent remnants of subducted oceanic crust. Lu-Hf isotope systematics indicate that the oceanic protolith for the eclogites formed in the Paleoproterozoic at ˜ 2.1 Ga, which is in agreement with the in-situ Pb isotope data from clinopyroxene. This result also corroborates the ˜ 2.1 Ga Lu-Hf model ages recorded by mantle zircons from eclogite found within the Jericho kimberlite in the northern Slave Province (˜ 200 km northwest of Diavik). The results from both studies indicate a link between eclogite formation and Paleoproterozoic subduction of oceanic lithosphere along the present-day western margin of the Archean Slave craton.

Origin of zircon-bearing mantle eclogites entrained in the V. Grib kimberlite (Arkhangelsk region, NW Russia): Evidence from mineral geochemistry and the U-Pb and Lu-Hf isotope compositions of zircon

NASA Astrophysics Data System (ADS)

Shchukina, Elena V.; Agashev, Alexey M.; Zedgenizov, Dmitry A.

2018-05-01

The concentrations of major and trace elements in minerals, reconstructed whole-rock compositions of zircon-bearing equigranular eclogites from the V. Grib kimberlite pipe located within the Arkhangelsk Diamondiferous Province (North-Western Russia), and results of the U-Pb and Lu-Hf isotope analyses of zircon grains from eclogites and granulite xenoliths are reported. These data suggest that the equigranular eclogites could represent the fragments of mid-ocean-ridge basalt that were metamorphosed during Paleoproterozoic subduction at 1.7-1.9 Ga. The Hf isotope compositions of the eclogitic zircon display uniformity and indicate corresponding Hf-depleted mantle model ages of 2.2-2.3 Ga. The formation of zircon in eclogites could have resulted from interactions with metasomatic/subduction-related fluids just prior to, but associated with, Paleoproterozoic eclogite formation. A link between eclogitic zircon formation and continental lower-crustal rocks can be excluded based on differences in the Hf isotope compositions of eclogitic and granulitic zircon grains. The U-Pb upper intercept age of granulitic zircon of 2716 ± 61 Ma provides a new minimum age constraint for zircon crystallisation and granulite formation. The U-Pb ages obtained from granulitic zircon show two stages of Pb loss at 2.2-2.6 Ga and 1.7-2.0 Ga. The late Paleoproterozoic stage of Pb loss recorded in granulitic zircon is due to the intensive reworking of basement crustal rocks, which was caused by a tectonic process/subduction event associated with equigranular eclogite formation. Our data, along with evidence previously obtained from the V. Grib pipe coarse-granular eclogites, show at least two main subduction events in the lithospheric mantle of the Arkhangelsk region: the Archean (2.8 Ga) and Paleoproterozoic (1.7-1.9 Ga) subductions, which correspond to major magmatic and metamorphic events in the Baltic Shield.

Chemical stratification of cratonic lithosphere: constraints from the Northern Slave craton, Canada

NASA Astrophysics Data System (ADS)

Kopylova, Maya G.; Russell, James K.

2000-08-01

We describe the mineralogical and chemical composition of the Northern Slave mantle as deduced from xenoliths of peridotite within the Jericho kimberlite, Northwest Territories. Our data set includes modal, major, trace and rare earth element compositions of bulk samples of spinel peridotite, low-T and high-T garnet peridotite and minor pyroxenite. Compared to primitive upper mantle, Jericho peridotite shows depletion in the major elements and enrichment in incompatible elements (except for HREE). The Slave mantle is also uniquely stratified. Older, depleted spinel peridotite extends to a depth of 80-100 km and is underlain by garnet peridotite which shows a gradual decrease in Mg# with depth to 200 km. The youngest layer of fertile garnet peridotite, enriched in clinopyroxene and garnet, is underlain by a pyroxenite-rich horizon at the base of the petrological lithosphere. The Northern Slave is further distinguished from the Kaapvaal and Siberian upper mantle by a marked vertical stratification in Mg#, lower abundances of orthopyroxene and higher abundances of clinopyroxene. In addition, a deeper layer of garnet peridotite below Jericho shows less depletion than low-T peridotite from other cratons. The Northern Slave peridotite results from a series of chemical events that include: (i) high-degree melting of pyrolite at P>3 Gpa for low-T peridotite and lower pressure melting for high-T peridotite, (ii) enrichment of low-T spinel peridotite in orthopyroxene, and (iii) pervasive metasomatic enrichment in alkali and LREE's by kimberlite-related fluids. The chemical stratification described for two of the three lithospheric domains of the Slave craton makes this craton an exception among cratons with commonly unstratified lithospheres. The gradual increase in fertility with depth below the Slave craton is related to age stratification and may have formed by incremental downward growth of mantle lithosphere with time, and/or later re-fertilization of deeper mantle horizons.

Reworking of Archean mantle in the NE Siberian craton by carbonatite and silicate melt metasomatism: Evidence from a carbonate-bearing, dunite-to-websterite xenolith suite from the Obnazhennaya kimberlite

NASA Astrophysics Data System (ADS)

Ionov, Dmitri A.; Doucet, Luc S.; Xu, Yigang; Golovin, Alexander V.; Oleinikov, Oleg B.

2018-03-01

The Obnazhennaya kimberlite in the NE Siberian craton hosts a most unusual cratonic xenolith suite, with common rocks rich in pyroxenes and garnet, and no sheared peridotites. We report petrographic and chemical data for whole rocks (WR) and minerals of 20 spinel and garnet peridotites from Obnazhennaya with Re-depletion Os isotope ages of 1.8-2.9 Ga (Ionov et al., 2015a) as well as 2 pyroxenites. The garnet-bearing rocks equilibrated at 1.6-2.8 GPa and 710-1050 °C. Some xenoliths contain vermicular spinel-pyroxene aggregates with REE patterns in clinopyroxene mimicking those of garnet. The peridotites show significant scatter of Mg# (0.888-0.924), Cr2O3 (0.2-1.4 wt.%) and high NiO (0.3-0.4 wt.%). None are pristine melting residues. Low-CaO-Al2O3 (≤0.9 wt.%) dunites and harzburgites are melt-channel materials. Peridotites with low to moderate Al2O3 (0.4-1.8 wt.%) usually have CaO > Al2O3, and some have pockets of calcite texturally equilibrated with olivine and garnet. Such carbonates, exceptional in mantle xenoliths and reported here for the first time for the Siberian mantle, provide direct evidence for modal makeover and Ca and LREE enrichments by ephemeral carbonate-rich melts. Peridotites rich in CaO and Al2O3 (2.7-8.0 wt.%) formed by reaction with silicate melts. We infer that the mantle lithosphere beneath Obnazhennaya, initially formed in the Mesoarchean, has been profoundly modified. Pervasive inter-granular percolation of highly mobile and reactive carbonate-rich liquids may have reduced the strength of the mantle lithosphere leading the way for reworking by silicate melts. The latest events before the kimberlite eruption were the formation of the carbonate-phlogopite pockets, fine-grained pyroxenite veins and spinel-pyroxene symplectites. The reworked lithospheric sections are preserved at Obnazhennaya, but similar processes could erode lithospheric roots in the SE Siberian craton (Tok) and the North China craton, where ancient melting residues and reworked garnet-bearing peridotites are absent. The modal, chemical and Os-isotope compositions of the Obnazhennaya xenoliths produced by reaction of refractory peridotites with melts are very particular (high Ca/Al, no Mg#-Al correlations, highly variable Cr, low 187Os/188Os, continuous modal range from olivine-rich to low-olivine peridotites, wehrlites and websterites) and distinct from those of fertile lherzolites in off-craton xenoliths and peridotite massifs. These features argue against the concept of 'refertilization' of cratonic and other refractory peridotites by mantle-derived melts as a major mechanism to form fertile to moderately depleted lherzolites in continental lithosphere. The Obnazhennaya xenoliths represent a natural rock series produced by 'refertilization', but include no rocks equivalent in modal, major and trace element to the fertile lherzolites. This study shows that 'refertilization' yields broad, continuous ranges of modal and chemical compositions with common wehrlites and websterites that are rare among off-craton xenoliths.

In situ crystal chemical study of solid diamond inclusions from Quaternary alluvial deposit in the Siberian craton

NASA Astrophysics Data System (ADS)

Dera, P. K.; Manghnani, M. H.; Hushur, A.; Sobolev, N. V.; Logvinova, A. M.; Newville, M.; Lanzirotti, A.

2013-12-01

Kimberlites belong to rare rock type available only within the Earth's cratonic areas and have been a subject of detailed studies because of the great depth of their origin in the mantle. Kimberlitic diamonds often contain pristine inclusions derived from significant depths with different histories of their origins. Many of kimberlitic diamonds were formed in ultramafic (peridotitic) and mafic (eclogitic) environments of the upper mantle. Thus far only a handful of comprehensive in situ studies including single-crystal X-ray diffraction characterization of pristine diamond solid inclusions have been reported (e.g. Kunz et al. 2001, Nestola et al. 2011). In this study five single-crystal solid inclusions from diamonds found in the Quaternary alluvial deposit in NW of the Siberian craton have been investigated using a combination of in situ single-crystal X-ray diffraction, Raman spectroscopy, synchrotron X-ray microfluorescence and X-ray Absorption Near Edge Spectroscopy (XANES). The grains were identified to be a suite of major upper mantle minerals including olivine, enstatite orthopyroxene (opx), C2/c omphacite clinopyroxene (cpx) and majoritic garnet (two grains), indicating eclogitic origin. All five inclusions are chemically homogeneous, do not show compositional zoning, and exhibit very similar major element chemistry, with significant amounts of Mn2+, Ni2+ and Cr3+ incorporated into the crystal structures, suggesting common geologic origin. All samples were studied in situ, while still embedded in the diamond crystals. High quality single-crystal X-ray diffraction data was collected at the Advanced Photon Source, Argonne National Laboratory to reveal details of the crystal structures and provide crystal chemical information. Some of the structural characteristics of the solid inclusions were found to be fairly uncommon, e.g. the orthoenstatite exhibits an unusually high Ca2+ content (Carlson et al. 1988), and omphacite occurs as the less common C2/c polymorph (Banno, 1970), both of which are considered signatures of eclogitic high-temperature facies. Fe Ka-edge XANES was used to investigate the oxidation state of iron in the solid inclusions. All of the inclusions show predominantly Fe2+, indicating reducing conditions of formation. The combined results of our spectroscopic and diffraction experiments will be interpreted in the context of the conditions and mechanism of formation (syngenesis vs. protogenesis) and possible retrograde transformation the inclusions may have experienced when transported to the surface. References Carlson, W.D. J.S. Swinnea, D.E. Miser (1988) 'Stability of orthoenstatite at high temperature and low pressure' Amer. Mineral. 73: 1255-1263. Banno, S. (1970) 'Classification of eclogites in terms of physical condition of their origin' Phys. Earth. Planet. Interiors 3: 405-421. Kunz, M., P. Gillet, et al. (2002). "Combined in situ X-ray diffraction and Raman spectroscopy on majoritic garnet inclusions in diamonds." Earth and Planet. Sci. Lett. 198: 485-493. Nestola, F., P. Nimis, et al. (2011). "First crystal-structure determination of olivine in diamond: Composition and implications for provenance in the Earth's mantle." Earth and Planet. Sci. Lett. 305: 249-255.

Metal films on the surfaces and within diamond crystals from Arkhangelskaya and Yakutian diamond provinces

NASA Astrophysics Data System (ADS)

Makeev, A. B.; Kriulina, G. Yu.

2012-12-01

Representative samples of diamonds from five kimberlite pipes (Lomonosovskaya, Archangel'sk, Snegurochka, XXIII Congress of the Communist Party of the Soviet Union (CPSU), and Internationalnaya) of the Arkhangelskaya and Yakutian diamond provinces in Russia have been studied. Thirty-three varieties of metal films have been identified as syngenetic associated minerals. The films consist of 15 chemical elements that occur in the form of native metals and their natural alloys. Remnants of metal films were detected within diamond crystals. The metal films coating diamonds are a worldwide phenomenon. To date, these films have been described from Europe, Asia, South America, and Africa. Native metals, their alloys, and intermetallides are actual companion minerals of diamond.

Limiting depth of magnetization in cratonic lithosphere

NASA Technical Reports Server (NTRS)

Toft, Paul B.; Haggerty, Stephen E.

1988-01-01

Values of magnetic susceptibility and natural remanent magnetization (NRM) of clino-pyroxene-garnet-plagioclase granulite facies lower crustal xenoliths from a kimberlite in west Africa are correlated to bulk geochemistry and specific gravity. Thermomagnetic and alternating-field demagnetization analyses identify magnetite (Mt) and native iron as the dominant magnetic phases (totaling not more than 0.1 vol pct of the rocks) along with subsidiary sulfides. Oxidation states of the granulites are not greater than MW, observed Mt occurs as rims on coarse (about 1 micron) Fe particles, and inferred single domain-pseudosingle domain Mt may be a result of oxidation of fine-grained Fe. The deepest limit of lithospheric ferromagnetism is 95 km, but a limit of 70 km is most reasonable for the West African Craton and for modeling Magsat anomalies over exposed Precambrian shields.

Petrochemical and petrophysical characterization of the lower crust and the Moho beneath the West African Craton, based on Xenoliths from Kimberlites

NASA Technical Reports Server (NTRS)

Haggerty, Stephen E.; Toft, Paul B.

1988-01-01

Additional evidence to the composition of the lower crust and uppermost mantle was presented in the form of xenolith data. Xenoliths from the 2.7-Ga West African Craton indicate that the Moho beneath this shield is a chemically and physically gradational boundary, with intercalations of garnet granulite and garnet eclogite. Inclusions in diamonds indicate a depleted upper mantle source, and zenolith barometry and thermometry data suggest a high mantle geotherm with a kink near the Moho. Metallic iron in the xenoliths indicates that the uppermost mantle has a significant magnetization, and that the depth to the Curie isotherm, which is usually considered to be at or above the Moho, may be deeper than the Moho.

Deep mantle cycling of oceanic crust: evidence from diamonds and their mineral inclusions.

PubMed

Walter, M J; Kohn, S C; Araujo, D; Bulanova, G P; Smith, C B; Gaillou, E; Wang, J; Steele, A; Shirey, S B

2011-10-07

A primary consequence of plate tectonics is that basaltic oceanic crust subducts with lithospheric slabs into the mantle. Seismological studies extend this process to the lower mantle, and geochemical observations indicate return of oceanic crust to the upper mantle in plumes. There has been no direct petrologic evidence, however, of the return of subducted oceanic crustal components from the lower mantle. We analyzed superdeep diamonds from Juina-5 kimberlite, Brazil, which host inclusions with compositions comprising the entire phase assemblage expected to crystallize from basalt under lower-mantle conditions. The inclusion mineralogies require exhumation from the lower to upper mantle. Because the diamond hosts have carbon isotope signatures consistent with surface-derived carbon, we conclude that the deep carbon cycle extends into the lower mantle.

Concentrates and mantle xenocrysts from the Lao river Guinea and reconstructions of the mantle structure

NASA Astrophysics Data System (ADS)

Afanasiev, Valentin; Ashchepkov, Igor; Nikolenko, Eeugeny

2015-04-01

The discovery of the kimberlite dykes in Quinea in the basin of the Lao river means finding of the new diamondiferous kimberlite field in the West Africa. It is locating 100 km SW from Bubudu and contains large dykes and placers in Lao river. The kimberlite concentrate and diamondiferous placers are containing pyropes, chromites, Ilmenites and Cr diosides and low Cr- pyroxenes. Two river placers in Lao and Bobeko and newly discovered dyke slightly differ in compositions of minerals. mainly in representatives of the minerals though their compositional trends are in general similar. The concentrates from and Druzhba pipe (Bunudu) contains mainly ilmenite and more are pyropes. Garnets from all localities are close and belong mainly to the lherzolite field to 10 wt%Cr2O3. But the dyke contains essential amount of harzburgitic garnets starting from 2 %wt Cr2O3 and they became prevailing from 6 wt %Cr2O3. There are also megacrystic low - Cr pyropes in dyke concentrate. Dyke is rich in peridotites and coarse grained garnet pyroxenite xenoliths which are ranging from the low Cr -to Cr -diopside type Chromites from Dyke are Ti - low but are often Al rich. While chromites from Bobeko and especially Lao placers define the Cr- rich trend from 60 to 40 wt%Cr2O3 and demonstrate the deviation to ulvospinel trends with increasing of Al2O3 . Cr - Diopsides clinopyroxenites trace the Fe- Ti-Na-Al enrichment trend. Ilmenites from three localities - define close trends splitting to the two intervals 60-40 wt% TiO2 and 33-27 TiO2 which are enriched in Cr2O3 to 5wt% reflecting the crystallization of megacrystalline association at the lithosphere base and Ilm metasomatic vein stockwark near the Moho in pre-eruption feeding system. The Dyke ilmenites are Mg rich and mainly are captured from the deep part of the mantle section. Babeko and Druzhba localities are similar variations of ilmenite trends. Some ilmenites from Lao and Druzhba are Mn - rich and are less in Cr possibly reflecting the interaction protokimberlite magma with subducted material. The calculated PTXFO2 diagrams with monominreral methods (Ashchepkov et al ., 2010 -2014) the layered structure and presence of thick pyroxenite enriched lens in the middle part of mantle section which also contain harzburgite associations. He interval 4.5-5.5 GPa contains the Crromite bearing peridotites together with Ga- harburghites. Cr- low pyroxenites probablly are associated with the ilmenites while some of them are more Fe rich and reflects the de -eclogitization. The typical deformed peridotite association were not detected but heating for the garnets is found along the magma feeder traced by ilmenites. The TRE geochemistry show that most of Cr clinopyroxenes are typical for Ga- bearing peridotites with concave upward REE patterns. They are also are rich in Nb - Ba- U and extremely depleted in Zr suggesting probably the preceding depletion with the H2O rich melts . Zircon is abundant in concentrates what corresponds to large scale H2O bearing metasomatism. Garnets demonstrates semi round HREE - high patterns with MREE humper typical for pyroxenites and small LREE- enrichment. RFBR grants 05-05-64718, 03-05-64146; 11 -05-00060a 11-05-91060-PICSа

Phenocrysts and megacrysts of olivines from ultramafic lamprophyres of the Chadobets and Il'bokich uplifts, Southwestern Siberia

NASA Astrophysics Data System (ADS)

Smirnova, Maria; Sazonova, Lyudmila; Nosova, Anna; Kargin, Alexey; Shcherbakov, Vasiliy

2017-04-01

The study of composition and zoning of olivines from ultramafic lamprophyres of the SW Siberian craton allowed us to distinguish their main types (phenocrysts and megacrysts) and to estimate the possible P-T conditions of phenocryst crystallization. The studied rocks occur as sills and dikes in the Chadobets and Il'bokich uplifts of the Irkeneeva-Chadobets trough. The ultramafic lamprophyres of these uplifts are spaced around 80 km apart and differ in age by more than 150 Ma. The rocks of the Il'bokich Uplift are dated at Devonian, while the age of the Chadobets Complex is restricted to the Triassic. The episodes of these complexes formation were separated by the large flood basalt event. According to classification (Tappe et al., 2005), the studied rocks are aillikite and damtjernite. Olivine phenocrysts from the rocks of the Il'bokich and Chadobets complexes are represented by sub- and euhedral grains. They are composed of core, transitional zone, and rim. Olivine cores in the aillikites of the Il'bokich Complex are characterized by Mg# 89; CaO - 0.13-0.14 wt %; TiO2 around 0.03 wt %, Al - 200-380 ppm, and Cr - 130-340 ppm. The cores of phenocrysts from the Chadobets lamprophyres have Mg# 85-87, CaO varying within 0.1-0.2 wt %, and TiO2 - 0.02-0.05 wt %. The megacrysts differ from the phenocrysts of these rocks in the lower Mg# 83-84 and CaO - 0.08-0.14 wt % at higher TiO2 - 0.04-0.05 wt %. Al - 100-700 ppm, Cr - 20-65 ppm. The most striking difference between olivines of the two complexes is observed between their Mg#-Ni relations. The cores of olivine phenocrysts from the Il'bokich lamprophyres are characterized by the high Mg number (Mg# = 89) and Ni content (2800-3000 ppm), whereas olivine cores of the Chadobets aillikites have higher contents of Ni (3000-3500 ppm) at lowered (Mg# = 86-88). These characteristics reflect the compositions of their protolith. The temperature was estimated using monomineral olivine thermometer based on the contents of Cr and Al in olivine (De Hooge et al., 2010). This geothermometer was calibrated for a wide compositional range, including kimberlites, and correspondingly, may be used for alkaline-ultrabasic lamprophyres. At pressures above 4 GPa, olivine phenocrysts fall in the field of olivine-kimberlite melt equilibrium (Girnis et al., 1995). The Il'bokich olivine phenocrysts were formed at higher temperature than the Chadobets phenocrysts: from 1240 to 1340oC for the Il'bokich rocks and from 1080 to 1225oC for the Chadobets rocks. In the P-T diagram showing the geotherm of 40 mV/m2, olivines from the Il'bokich and Chadobets lamprophyres lie to the right of the geotherm, which excludes the presence of xenogenic lithospheric mantle olivine in these rocks. De Hoog J.C.M., Gall L., Cornell D.H. 2010. Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry // Chem. Geol. 270.1: 196-21. Girnis A.V., Brey G.P., Ryabchikov I.D. 1995. Origin of group 1A kimberlites: fluid-saturated melting experiments at 45-55 kbar // EPSL. 134.3: 283-296. Tappe S., Foley S.F., Jenner G.A. et al. 2006. Genesis of Ultramafic Lamprophyres and Carbonatites at Aillik Bay, Labrador: a Consequence of Incipient Lithospheric Thinning beneath the North Atlantic Craton // J. Petrology. 47 (7). 1261-1315.

Non-Potassic Melts In CMAS-CO2-H2O-K2O Model Peridotite

NASA Astrophysics Data System (ADS)

Buisman, I.; Walter, M. J.; Keshav, S.

2009-12-01

Volatile mediated model systems have been fundamental in shaping our knowledge about the way we view melting phase relations of peridotite at various depths in the Earth. Volatiles not only affect the melting temperatures, but the resulting liquids are, in some case, dramatically different than those witnessed in melting of dry peridotite. For example, the influence of CO2 and H2O on the melting phase relations of model peridotite shows a remarkable decrease in the solidus temperatures when compared to the dry peridotite (Gudfinnsson and Presnall, 2005). These model systems illustrate a gradational change above the solidus from carbonatites to kimberlites over several hundreds of degrees. Group-II kimberlites are ultrapotassic rocks with high water content where the mineral phlogopite is abundant. To get a better understanding of the melting phase relations related to carbonatitic and kimberlitic magmas, K2O was added to the system CMAS-CO2-H2O. In these systems, fluid and melt can co-exist in P-T space. However, from past studies, it is also known that in hydrous systems, both the fluid and melt will become indistinguishable from one another creating a singularity (second critical endpoint). Starting from the solidus located in six components (Keshav and Gudfinnsson, AGU abstract, 2009), with seven phases, melting phase relations in CMAS-CO2-H2O-K2O involving, fo-opx-cpx-garnet-carbonate-melt-fluid, are divariant. Fluid was recognized with the observation of large cavities seen in exposed capsules. Moreover, the presence of bright, needle-like grains found in large cavities in backscattered images implies the presence of solute in the fluid phase. Significantly, liquids on this divariant region have about 1000 ppm K2O, and so is the case with accompanying cpx. Hence, with this non-interesting amount of K2O in the mentioned phases, fluid must have all the potassium. At 30 kbar/1100C, with fo-opx-cpx-garnet-carbonate-phlogopite-melt-fluid, the melting phase relations become isobarically invariant. In contrast, the solidus in CMAS-CO2-H2O at 30 kbar is at 1000C. Above 1100C, phlogopite is no longer in equilibrium with the phase assemblage. In all the experimental charges, capsules were pierced, and a hydrous solution was seen escaping. When tested with litmus paper, in all cases at 25-50 kbar, this solution was determined to be highly basic (pH>10). Upon evaporation of the hydrous solution, a white precipitate was left behind around the piercing on the capsule wall. In CMAS-CO2-H2O, the fluid was found to be almost neutral (pH 7-8). The melt present in our experiments is carbonatitic in nature and does not contain any significant amounts of K2O. This contradicts a recent study on K2O in a natural composition (Foley et al, 2009) where carbonatitic melt had up to 13 wt% of K2O. Significantly, since K2O is perhaps all in the fluid, source regions for potassic magmas in the Earth’s mantle could not be created by metasomatism of alkali-rich, carbonatitic melts.

The uniquely high-temperature character of Cullinan diamonds: A signature of the Bushveld mantle plume?

NASA Astrophysics Data System (ADS)

Korolev, N. M.; Kopylova, M.; Bussweiler, Y.; Pearson, D. G.; Gurney, J.; Davidson, J.

2018-04-01

The mantle beneath the Cullinan kimberlite (formerly known as "Premier") is a unique occurrence of diamondiferous cratonic mantle where diamonds were generated contemporaneously and shortly following a mantle upwelling that led to the formation of a Large Igneous Province that produced the world's largest igneous intrusion - the 2056 Ma Bushveld Igneous Complex (BIC). We studied 332 diamond inclusions from 202 Cullinan diamonds to investigate mantle thermal effects imposed by the formation of the BIC. The overwhelming majority of diamonds come from three parageneses: (1) lithospheric eclogitic (69%), (2) lithospheric peridotitic (21%), and (3) sublithospheric mafic (9%). The lithospheric eclogitic paragenesis is represented by clinopyroxene, garnet, coesite and kyanite. Main minerals of the lithospheric peridotitic paragenesis are forsterite, enstatite, Cr-pyrope, Cr-augite and spinel; the sublithospheric mafic association includes majorite, CaSiO3 phases and omphacite. Diamond formation conditions were calculated using an Al-in-olivine thermometer, a garnet-clinopyroxene thermometer, as well as majorite and Raman barometers. The Cullinan diamonds may be unique on the global stage in recording a cold geotherm of 40 mW/m2 in cratonic lithosphere that was in contact with underlying convecting mantle at temperatures of 1450-1550 °C. The studied Cullinan diamonds contain a high proportion of inclusions equilibrated at temperatures exceeding the ambient 1327 °C adiabat, i.e. 54% of eclogitic diamonds and 41% of peridotitic diamonds. By contrast, ≤ 1% of peridotitic diamond inclusions globally yield equally high temperatures. We propose that the Cullinan diamond inclusions recorded transient, slow-dissipating thermal perturbations associated with the plume-related formation of the 2 Ga Bushveld igneous province. The presence of inclusions in diamond from the mantle transition zone at 300-650 km supports this view. Cullinan xenoliths indicative of the thermal state of the cratonic lithosphere at 1.2 Ga are equilibrated at the relatively low temperatures, not exceeding adiabatic. The ability of diamonds to record super-adiabatic temperatures may relate to their entrainment from the deeper, hotter parts of the upper mantle un-sampled by the kimberlite in the form of xenoliths or their equilibration in a younger lithosphere after a decay of the thermal disturbance.

Density of alkali carbonate melts in the upper mantle and implications for the mobility of carbon at depth

NASA Astrophysics Data System (ADS)

Ritter, X.; Sanchez-Valle, C.; Laumonier, M.; King, A.; Guignot, N.; Gaillard, F.; Sifre, D.; Perrillat, J. P.

2017-12-01

The occurrence of carbonate-rich mantle rocks and diamonds in kimberlite rocks provide evidence for the presence of CO2 in the mantle. Carbon is recycled into the mantle via subduction and released through volcanic outgassing. An important fraction is retained at depth where partial melting of subducted lithologies produce alkali-rich carbonates along the CaCO3-MgCO3-K2CO3 join that infiltrate the mantle wedge [1]. Although volumetrically minor, these melts act as effective metasomatic agents that are related to source regions for diamond-bearing kimberlites [2]. The mobility of carbon at depth is controlled by the physical properties of carbonate liquids that remain largely unknown [3,4]. Here we report in-situ density measurements of alkaline carbonates at crustal and upper mantle conditions using synchrotron X-ray absorption in a Paris-Edinburgh press at beamline Psiché (Synchrotron Soleil). Experiments were conducted in several compositions along the CaCO3-K2CO3 and MgCO3-K2CO3 join up to 1400 K and 3 GPa. The starting materials included a mixture of synthetic K2CO3 and natural calcite and K2Mg(CO3)2 glasses synthesized at 0.15 GPa and 1098 K in an internally heated pressure vessel. The samples were cold pressurized and heated until the molten stage was confirmed by X-ray diffraction. The results were fitted to derive the first robust model for the density of alkali carbonates that mimic liquids from the incipient melting of subducted lithologies at crustal and upper mantle conditions. We combine the results of the present study with available data on the viscosity of carbonate liquids and molecular dynamic predictions to discuss the mobility and migration rates of carbonate liquids in the upper mantle.[1] Litasov et al. 2012 Geology 41, 79-82. [2] Grassi and Schmidt 2011, Contrib Min Petr 162, 169-191. [3] Dobson et al. 1996, EPSL 143, 207-215. [4] Kono et al. 2014 Nature Communications 5:5091.

The effect of CO2 on the water-saturated solidus of K-poor peridotite between 4 and 6 GPa

NASA Astrophysics Data System (ADS)

Dvir, Omri; Kessel, Ronit

2017-06-01

The effect of various amounts of CO2 on the solidus of H2O-CO2-bearing peridotite was examined by determining the composition of H2O-CO2-bearing fluids and melts in equilibrium with garnet peridotite at 4-6 GPa and 900-1100 °C. Two capsules were placed in a rocking multi-anvil apparatus in each experiment. Both capsules contained a fertile peridotite with 10 wt% H2O, one with 1 (CLZ1) and the other with 5 wt% CO2 (CLZ5). In both capsules a diamond trap was placed on one end of the capsule as a fluid/melt trap. The H2O and CO2 content in the fluid or melt trapped in between the diamonds were measured using the quartz-tube-system technique by releasing the volatiles through infrared gas analyzer. The total dissolved solids in these phases were determined using the cryogenic laser-ablation - inductive couple plasma - mass spectrometry technique. The residual lherzolite consists of olivine, orthopyroxene, ±clinopyroxene, garnet, and ±magnesite as carbonate phase. The solidus of CLZ1 peridotite was located between 900 and 1000 °C at 4 GPa and between 1000 and 1100 °C at 5 and 6 GPa. CLZ5 peridotite melts below 900 °C at 4 GPa and between 900 and 1000 °C at 5 and 6 GPa. The results demonstrate a decrease in melting temperature of hydrous peridotite at pressures between 4 and 6 GPa with increasing amount of CO2. The H2O-CO2-bearing fluids found in this study at 900-1000 °C are similar in composition to low-Mg carbonatitic to silicic high-density fluids found in fluid inclusions in diamonds. With increasing temperature, the melts approach type II kimberlites. We propose that H2O-CO2-induced partial melting of metasomatized garnet lherzolite at 4-6 GPa is a possible origin for group II kimberlites.

Infrared spectral and carbon isotopic characteristics of micro- and macro-diamonds from the Panda kimberlite (Central Slave Craton, Canada)

NASA Astrophysics Data System (ADS)

Melton, G. L.; Stachel, T.; Stern, R. A.; Carlson, J.; Harris, J. W.

2013-09-01

One hundred and twenty-one micro-diamonds (< 1 mm) and 90 macro-diamonds (2.5 mm to 3.4 mm) from the Panda kimberlite (Ekati mine, Central Slave Craton, Canada) were analyzed for nitrogen content, nitrogen aggregation state (%B) and platelet and hydrogen peak areas (cm- 2). Micro-diamond nitrogen concentrations range from < 10 at. ppm to 1696 at. ppm (median = 805 at. ppm) and the median aggregation state is 23%B. Macro-diamonds range from < 10 at. ppm to 1260 at. ppm (median = 187 at. ppm) nitrogen and have a median nitrogen aggregation of 26%B. Platelet and hydrogen peaks were observed in 37% and 79% of the micro-diamonds and 79% and 56% of the macro-diamonds, respectively. Nitrogen based time averaged residence temperatures indicate that micro- and macro-diamonds experienced similar thermal mantle residence histories, both populations displaying bimodal residence temperature distributions with a gap between 1130 °C and 1160 °C (at 3.5 Ga residence). In addition, SIMS carbon isotopic analyses for the micro-diamonds were obtained: δ13C compositions range from - 6.9‰ to + 1.8‰ (median = - 4.3‰). CL imaging reveals distinct growth layers that in some samples differ by > 2‰, but mostly vary by < 0.5‰. Comparison of only the “gem-quality” samples (n = 49 micro- and 90 macro-diamonds) between the two diamond sets, indicates a statistically significant shift of + 1.3‰ in average δ13C from macro- to micro-diamonds and this shift documents distinct diamond forming fluids, fractionation process or growth histories. A broad transition to heavier isotopic values is also observed in connection to decreasing mantle residence temperatures. The bimodal mantle residence temperature distribution may coincide with the transition from highly depleted shallow to more fertile deep lithospheric mantle observed beneath the Central Slave Craton. The increase in δ13C with decreasing residence temperature (proxy for decreasing depth) is interpreted to reflect diamond formation from a carbonate-bearing metasomatic fluid/melt that isotopically evolves as it percolates upward through the lithosphere.

Regional patterns in the paragenesis and age of inclusions in diamond, diamond composition, and the lithospheric seismic structure of Southern Africa

NASA Astrophysics Data System (ADS)

Shirey, Steven B.; Harris, Jeffrey W.; Richardson, Stephen H.; Fouch, Matthew; James, David E.; Cartigny, Pierre; Deines, Peter; Viljoen, Fanus

2003-12-01

The Archean lithospheric mantle beneath the Kaapvaal-Zimbabwe craton of Southern Africa shows ±1% variations in seismic P-wave velocity at depths within the diamond stability field (150-250 km) that correlate regionally with differences in the composition of diamonds and their syngenetic inclusions. Seismically slower mantle trends from the mantle below Swaziland to that below southeastern Botswana, roughly following the surface outcrop pattern of the Bushveld-Molopo Farms Complex. Seismically slower mantle also is evident under the southwestern side of the Zimbabwe craton below crust metamorphosed around 2 Ga. Individual eclogitic sulfide inclusions in diamonds from the Kimberley area kimberlites, Koffiefontein, Orapa, and Jwaneng have Re-Os isotopic ages that range from circa 2.9 Ga to the Proterozoic and show little correspondence with these lithospheric variations. However, silicate inclusions in diamonds and their host diamond compositions for the above kimberlites, Finsch, Jagersfontein, Roberts Victor, Premier, Venetia, and Letlhakane do show some regional relationship to the seismic velocity of the lithosphere. Mantle lithosphere with slower P-wave velocity correlates with a greater proportion of eclogitic versus peridotitic silicate inclusions in diamond, a greater incidence of younger Sm-Nd ages of silicate inclusions, a greater proportion of diamonds with lighter C isotopic composition, and a lower percentage of low-N diamonds whereas the converse is true for diamonds from higher velocity mantle. The oldest formation ages of diamonds indicate that the mantle keels which became continental nuclei were created by middle Archean (3.2-3.3 Ga) mantle depletion events with high degrees of melting and early harzburgite formation. The predominance of sulfide inclusions that are eclogitic in the 2.9 Ga age population links late Archean (2.9 Ga) subduction-accretion events involving an oceanic lithosphere component to craton stabilization. These events resulted in a widely distributed younger Archean generation of eclogitic diamonds in the lithospheric mantle. Subsequent Proterozoic tectonic and magmatic events altered the composition of the continental lithosphere and added new lherzolitic and eclogitic diamonds to the already extensive Archean diamond suite.

Diamonds: Exploration, mines and marketing

NASA Astrophysics Data System (ADS)

Read, George H.; Janse, A. J. A. (Bram)

2009-11-01

The beauty, value and mystique of exceptional quality diamonds such as the 603 carat Lesotho Promise, recovered from the Letseng Mine in 2006, help to drive a multi-billion dollar diamond exploration, mining and marketing industry that operates in some 45 countries across the globe. Five countries, Botswana, Russia, Canada, South Africa and Angola account for 83% by value and 65% by weight of annual diamond production, which is mainly produced by four major companies, De Beers, Alrosa, Rio Tinto and BHP Billiton (BHPB), which together account for 78% by value and 72% by weight of annual diamond production for 2007. During the last twelve years 16 new diamond mines commenced production and 4 re-opened. In addition, 11 projects are in advanced evaluation and may begin operations within the next five years. Exploration for diamondiferous kimberlites was still energetic up to the last quarter of 2008 with most work carried out in Canada, Angola, Democratic Republic of the Congo (DRC) and Botswana. Many kimberlites were discovered but no new economic deposits were outlined as a result of this work, except for the discovery and possible development of the Bunder project by Rio Tinto in India. Exploration methods have benefitted greatly from improved techniques of high resolution geophysical aerial surveying, new research into the geochemistry of indicator minerals and further insights into the formation of diamonds and the relation to tectonic/structural events in the crust and mantle. Recent trends in diamond marketing indicate that prices for rough diamonds and polished goods were still rising up to the last quarter of 2008 and subsequently abruptly sank in line with the worldwide financial crisis. Most analysts predict that prices will rise again in the long term as the gap between supply and demand will widen because no new economic diamond discoveries have been made recently. The disparity between high rough and polished prices and low share prices of publicly traded diamond companies may be due to investors losing patience with the slow pace or absence of new promising discoveries and switching into shares of base metals and fertilizers for agriculture (potash and phosphates).

Tectonic Mechanism for the Mid-Cretaceous - Early Paleogene Intraplate Magmatism from the Gulf of Mexico to Northwestern Canada

NASA Astrophysics Data System (ADS)

Liu, Y.; Murphy, M. A.; Snow, J. E.; van Wijk, J.; Cannon, J. M.; Parsons, C.

2017-12-01

Tectonic mechanisms have remained controversial for a number of intraplate igneous suites of mid-Cretaceous - early Paleogene age across North America. They span the northern Gulf of Mexico (GoM), through Arkansas and Kansas in the US, to Saskatchewan and Northwestern Territories in Canada, resembling a belt that is located 1000+ km inboard from, and aligned sub-parallel to, the western margin of North America. The northern GoM magmatism is characterized by lamproites, carbonatites, nephelinites, with other alkaline rocks, whereas the rest igneous provinces are dominated by kimberlites. Their geochemical signatures, in general, point to a sub-lithospheric mantle origin. Hypotheses that explain the tectonic origin of these magmatic rocks include: (1) hotspots and mantle plumes, (2) edge-driven convection, (3) lithospheric reactivation, and (4) low-angle subduction. Evaluation based on our integration of published geological and geophysical data shows that contradictions exist in each model between observations and predictions. To explain this plate-scale phenomenon, we propose that the Farallon slab may have stagnated within or around the mantle transition zone during the Early Cretaceous, with its leading edge reaching ca. 1600 km inland beneath the North American plate. Dehydration and decarbonation of the slab produces sporadic, dense, low-degree partial melts at the mantle transition zone depths. As the slab descends into the lower mantle, Rayleigh-Taylor instabilities are induced at slab edges, causing passive upwelling that brings alkali-rich carbonate silicate melts to the base of the overriding plate. Subsequently, the North American lithosphere with varying thicknesses, discontinuities, and compositions interacts with the rising partial melts, generating a spectrum of igneous rocks. Fragments of the once-stagnated slab may still be detectable in the lower mantle beneath eastern US in seismic tomography models. This study highlights a profound plate-scale relationship between the intraplate magmatism and the subduction factory down to the transition zone depth, and anticipates future discoveries of kimberlites, potentially diamondiferous, in the mid-west of the North American continent.

Gravel deposits of the Caddo Gap and De Queen quadrangles, Arkansas: Chapter B in Contributions to economic geology, 1918, Part I, Metals and nonmetals except fuels

USGS Publications Warehouse

Miser, Hugh D.; Purdue, Albert Homer

1919-01-01

Several thick deposits of gravel are widely distributed along the north edge of the Gulf Coastal Plain, of which a narrow belt is embraced in the southern parts of the Caddo Gap and De Queen quadrangles, Ark. This belt is shown on Plate I, and its location is shown on figure 5, a key map of this region. It comprises parts of Pike, Howard, and Sevier counties and a narrow strip of Hemp- stead County, in southwestern Arkansas, and a strip along the east edge of McCurtain County, in southeastern Oklahoma. The gravels are of Lower Cretaceous, Upper Cretaceous, and Quaternary age, and are composed mainly of pebbles of novaculite (a variety of chert) derived from the Arkansas novaculite exposed in the Ouachita Mountain region, which is north of the Gulf Coastal Plain. They are used in making concrete, in ballasting railroads, and in the construction of wagon roads. Very small quantities of pebbles are also used in the washing plant of the Kimberlite Diamond Mining & Washing Co., at Murfreesboro, to assist in the disintegration of the altered peridotite which carries the diamonds.Interest in possible American sources of flint pebbles or substitutes therefor to be used in tube mills, in which minerals, ores, cement materials, and clinker are extensively ground in this country, has been aroused since the beginning of the present world war. This interest is due to the partial interruption of imports of flint pebbles from Denmark and France, which have supplied most of the pebbles used in this country. The main reasons for the preparation of this report are to present a description of the gravels under discussion and to indicate the possibility of their use in tube mills.The information for this report is the result of detailed field studies in the Caddo Gap and De Queen quadrangles by the authors in 1908 and 1911 and by the senior author in 1912 and 1916. Mr. E, D. Mesler rendered valuable assistance in 1912. Much of the information is abstracted from the De Queen-Caddo Gap folio, which is nearing completion.

Hydrogen and Carbon Groups in the Structures of Rock-Forming Minerals of Rocks of the Lithospheric Mantle: FTIR and STA + QMS Data

NASA Astrophysics Data System (ADS)

Babushkina, M. S.; Ugolkov, V. L.; Marin, Yu. B.; Nikitina, L. P.; Goncharov, A. G.

2018-04-01

Using IR-Fourier spectrometry (FTIR) and simultaneous thermal analysis combined with quadrupole mass spectrometry of thermal decomposition products (STA + QMS), olivines and clinopyroxene from xenolites of spinel and garnet lherzolites contained in kimberlites and alkaline basalts were studied to confirm the occurrence of hydrogen and carbon within the structure of the minerals, as well as to specify the forms of H and C. The presence of hydroxyl ions (OH-) and molecules of crystal hydrate water (H2Ocryst) along with CO2, CH, CH2, and CH3 groups was detected, which remained within the structures of mantle minerals up to 1300°C (by the data of both techniques). The total water (OH-and H2Ocryst) was the prevailing component of the C-O-H system.

Goat paddock cryptoexplosion crater, Western Australia

USGS Publications Warehouse

Harms, J.E.; Milton, D.J.; Ferguson, J.; Gilbert, D.J.; Harris, W.K.; Goleby, B.

1980-01-01

Goat Paddock, a crater slightly over 5 km in diameter (18??20??? S, 126??40???E), lies at the north edge of the King Leopold Range/Mueller Range junction in the Kimberley district, Western Australia (Fig. 1). It was noted as a geological anomaly in 1964 during regional mapping by the Bureau of Mineral Resources, Geology and Geophysics and the Geological Survey of Western Australia. The possibility of its being a meteorite impact crater has been discussed1, although this suggestion was subsequently ignored2. Two holes were drilled by a mining corporation in 1972 to test whether kimberlite underlay the structure. Here we report the findings of five days of reconnaissance in August 1979 which established that Goat Paddock is a cryptoexplosion crater containing shocked rocks and an unusually well exposed set of structural features. ?? 1980 Nature Publishing Group.

Chromatographic study of formation conditions of rhombododecahedral diamond crystals

NASA Astrophysics Data System (ADS)

Zhimulev, E. I.; Sonin, V. M.; Chepurov, A. I.; Tomilenko, A. A.

2009-06-01

The results of chromatographic study of the formation of rhombododecahedral diamonds synthesized in the Fe-Ni-(Ti)-C system at 5.5-6.0 GPa and 1350-1450°C are presented, including crystals with rounded surfaces of the rhombododecahedron with parallel striation, which are morphological analogues of natural diamonds abundant at various kimberlite, lamproite, and placer deposits. Chromatography was performed at 150°C with mechanical breakup of diamonds. The stable release of methane when diamonds of habit {110} are crushed is established. It is concluded that the appearance of the habit rhombododecahedron may be related not only to the effect of temperature and pressure on crystal growth but also to reductive conditions of crystallization. At the same time, the appearance of significant amounts of hydrocarbons in the system probably results in stopping of the growth of faces {110} and {100} and, instead, formation of specific surfaces that are composed of microscopic accessories faced by planes {111}.

Unusual paired pattern of radiohaloes on a diamond crystal from Guaniamo (Venezuela)

NASA Astrophysics Data System (ADS)

Schulze, Daniel J.; Nasdala, Lutz

2016-11-01

An octahedral diamond crystal from Guaniamo, Venezuela shows a multitude of round radiocolouration spots that indicate a remarkable formation history. Spots always occur in pairs, with similar spacing and intensity ratio between the two spots of each pair. We interpret this pattern to be the result of long-term irradiation of the stone emanating from a multitude of radioactive point sources. At some point during the irradiation, the stone must have experienced a translational movement which shifted it ca. 50 μm relative to the adjacent material [i.e., the (111) crystal face was a fault plane], after which irradiation continued. The Neoproterozoic age of the Guaniamo kimberlites and the high degree of radiation damage suggest that both of the two irradiation periods lasted over hundreds of millions of years. This interpretation is supported by results of He-irradiation experiments.

Peridotite-suite dominated mineral inclusions in diamonds from Kelsey Lake Mine, Colorado U.S.A.

NASA Astrophysics Data System (ADS)

Schulze, D. J.; Coopersmith, H. G.

2005-12-01

Thirty silicate and oxide inclusions large enough for in situ WDS electron microprobe analysis were exposed by grinding/polishing of 16 diamonds from the Kelsey Lake Mine in the Colorado-Wyoming State Line kimberlite district. Three garnets in two stones belong to the eclogite (E) suite, and 18 olivines, three Mg-chromites and six Cr-pyropes in the other 14 stones belong to the peridotite (P) suite. The peridotite-dominated population is in stark contrast to the other suites studied in the State Line district. The reported inclusion population from George Creek is completely eclogitic and that of the Sloan pipe is overwhelmingly eclogitic, with only a minor, relatively Fe-rich peridotite component. Multiple inclusions are common in single stones, with 12 olivines (of uniform composition) exposed in one example. Kelsey Lake olivine inclusions are magnesian (17 of 18 grains in 9 stones are in the range Fo 92.7-93.1), typical of P-suite stones worldwide, but unlike the more Fe-rich Sloan olivine suite (13 of 14 in the range Fo 91.3-92.2). Mg-chromites (wt percent MgO = 12.8-13.8, wt percent Cr2O3 = 61.4-66.6) are in the lower MgO range of diamond inclusion chromites worldwide. Six Cr-pyropes in four stones have moderately low calcium contents (wt percent CaO = 3.5-4.5) but are very Cr-rich (wt percent Cr2O3 = 10.5-16.7). An olivine-garnet pair in one stone yields a Mg-Fe exchange temperature of 895 degrees C, possibly indicating disequilibrium, whereas an olivine-chromite pair yields an Mg-Fe exchange temperature of 1035 degrees C, cool but reasonable for equilibration within the diamond stability field. Comparison with diamond inclusion minerals worldwide reveals that the Kesley Lake suite is most similar to those from the Slave Craton in Canada, especially in terms of Cr-pyrope compositions. Both suites are somewhat less depleted than suites from southern Africa or Siberian kimberlites. By analogy with the Slave P-suite diamonds of Archean age and a Proterozoic eclogitic component in the Slave mantle, the mixed diamond inclusion populations from the State Line district may support models in which blocks of Archean mantle survive buried beneath Proterozoic continental crust, mixed with eclogitic regimes emplaced by Proterozoic subduction.

In situ Analysis of North American Diamond: Implications for Diamond Growth Modeling

NASA Astrophysics Data System (ADS)

Schulze, D. J.; Van Rythoven, A. D.; Hauri, E.; Wang, J.

2014-12-01

Diamond crystals from three North American kimberlite occurrences were investigated with cathodoluminescence (CL) and secondary ion mass spectrometry (SIMS) to determine their growth history, carbon isotope composition and nitrogen content. Samples analyzed include sixteen from Lynx (Quebec), twelve from Kelsey Lake (Colorado) and eighteen from A154 South (Diavik mine, Northwest Territories). Growth histories for the samples vary from simple to highly complex based on their CL images and depending on the individual stone. Deformation lamellae are evident in CL images of the Lynx crystals which typically are brownish in color. Two to five points per diamond were analyzed by SIMS for carbon isotope composition (δ13CPDB) and three to seven points for nitrogen content. The results for the A154 South (δ13CPDB = -6.76 to -1.68 ‰) and Kelsey Lake (δ13CPDB = -11.81 to -2.43 ‰) stones (mixed peridotitic and eclogitic suites) are similar to earlier reported values. The Lynx kimberlite stones have anomalously high carbon isotope ratios and range from -3.58 to +1.74 ‰. The Lynx diamond suite is almost entirely peridotitic. The unusually high (i.e. >-5‰) δ13C values of the Lynx diamonds, as well as those from Wawa, Ontario and Renard, Quebec, may indicate an anomalous carbon reservoir for the Superior cratonic mantle relative to other cratons. In addition to the heavier carbon isotope values, the Lynx samples have very low nitrogen contents (<100 ppm). Nitrogen contents for Kelsey Lake and Diavik samples are more typical and range to ~1100 ppm. Comparison of observed core to rim variations in nitrogen content and carbon isotopes with modeled Rayleigh fractionation trends for published diamond growth mechanisms allows for evaluation of carbon speciation and other parent fluid conditions. Observed trends that closely follow modeled data are rare, but appear to suggest diamond growth from carbonate-bearing fluids at Lynx and Diavik, and growth from a methane-bearing fluid at Kelsey Lake. However the majority of crystals appear to have very complex growth histories that are clearly the result of multiple growth and resorption events. Trends observed in most of the samples from this study are chaotic and no consistent patterns are seen.

Alluvial diamond resource potential and production capacity assessment of Mali

USGS Publications Warehouse

Chirico, Peter G.; Barthelemy, Francis; Kone, Fatiaga

2010-01-01

In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflictual concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. Over 70 countries were included as members of the KPCS at the end of 2007. To prevent trade in "conflict diamonds" while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was (1) to assess the naturally occurring endowment of diamonds in Mali (potential resources) based on geological evidence, previous studies, and recent field data and (2) to assess the diamond-production capacity and measure the intensity of mining activity. Several possible methods can be used to estimate the potential diamond resource. However, because there is generally a lack of sufficient and consistent data recording all diamond mining in Mali and because time to conduct fieldwork and accessibility to the diamond mining areas are limited, four different methodologies were used: the cylindrical calculation of the primary kimberlitic deposits, the surface area methodology, the volume and grade approach, and the content per kilometer approach. Approximately 700,000 carats are estimated to be in the alluvial deposits of the Kenieba region, with 540,000 carats calculated to lie within the concentration grade deposits. Additionally, 580,000 carats are estimated to have been released from the primary kimberlites in the region. Therefore, the total estimated diamond resources in the Kenieba region are thought to be nearly 1,300,000 carats. The Bougouni zones are estimated to have 1,000,000 carats with more than half, 630,000 carats, contained in concentrated deposits. When combined, the Kenieba and Bougouni regions of Mali are estimated to be host to 2,300,000 carats of diamonds.

Mantle Evolution Beneath The Colorado Palteau: Interpreta-tion of The Study of Mineral Concentrate From Kimberlite Pipe Kl-1 Colorado.

NASA Astrophysics Data System (ADS)

Ashchepkov, I.; Vladykin, N.; Mitchell, R.; Coopersmith, H.; Garanin, V.; Saprykin, A. I.; Khmelnikova, O. S.

Mineral grains and their intergrowth from the concentrate form the KL1- kimberlite pipe Colorado plateau was analyzed by EPMA and LAM ICP MS in Analytic Center of UIGGM. Garnets reveal nearly continuous trend of the compositions divided into 5 intervals. 1 cumulates from the crust and Sp facie mantle; 2. Gar-Sp lherzolites; 3- Gar- wehrlites, lherzolites and harzburgites; 4- Gar lherzolites and harzburgites; 4. Pyroxenites and Il peri-dotites . They reveal three trend of Ti decrease with the ris- ing Cr content. Those in the inter-growth with the pyroxenes are less in Tio2 as well as the pyroxenes. Discrete large Cpx grains are richer in Na, Al, Cr. TP conditions determined for the clinopyroxenes with Nimis- Taylor, 2001 thermobarometer and barometer Ashchepkov, 2001 reveal the heating from 35 to 40-42 mv/m2 in 30-50kbar interval. The spinels show two compositional intervals 64-50% Cr2O3 and 47-30%. The branch with the essential enrichment to 8% TiO2with the Cr decrease what also suppose the peridotite alteration due to rising of evolving Ti-rich melts. Two descend- ing crystallization lines for the ilmenites suggest the (polybaric) differentiation in two magmatic chambers. The Cr-rich ilmenites and most Cr-rich subcalcis garnets were found in the serpentinized ilmenite harzburgites that probably surround the most deep mag-matic chamber. The Ilm -Q (coesite) intergrowth suggests the deep differenti- ation. Several ilmenites contain up to 11%MnO. Trace elements determined for the clinopyroxenes suppose small decree melting possibly under influence of subducted- related melts having definite U peak and Ta-Nb minimums. Their reaction with peri- dotites with garnet dissolution according to AFC model decrease La/Ybn ration as well as the Pb* and U peak. Two stages of the Ti-rich melt percolations suggested to be accompanied the plum- re-lated melts influence on the peridotite of Wyoming craton keel which was followed with fur-ther followed by submelting of the subducted essentially eclogitic Na-Ti material. The de-formations assist the melt percolation at the final stage. Supported by RBEF grants 05-99-65688, 00-05-65288

Silicon Carbide in Heavy-Mineral Samples: Indicator of Diamond Deposits

NASA Astrophysics Data System (ADS)

Leung, I. S.; Wang, W.

2013-12-01

Since kimberlite Pipe 50 of Wafangdian, 120 km northeast of the port city Dalian in Liaoning Province, ceased production in 2002, exploration programs have been conducted along tributaries of the Fuzhou River south of Wafangdian. The heavy-mineral method is often based on finding deep red G10 pyrope garnets which can be identified accurately by means of microprobe analysis to confirm their particular range of composition: high chromium, low calcium. Garnets are prone to hydrothermal alteration during kimberlite eruption, oxidation on Earth's surface, or be broken during mass transport. Unlike garnet, silicon carbide (SiC) resists chemical and mechanical alterations, but it crystallized at similarly high temperatures as diamond in Earth's mantle, and has the same atomic structure as diamond. Thus, SiC seems to be an ideal diamond indicator, although it is one of the rarest minerals in nature. Because of its characteristic blue-green color and adamantine luster, it can be recognized easily, no matter how minute the grains may be. We decided to re-examine small samples of heavy minerals collected and previously studied by exploration geologists, respectively from 3 tributaries of the Fuzhou River (Laogugao, Saocentun, Pingiaying), and from 3 ravines in the vicinity of Wafangdian (Songiagao, Dlitun, Lidianzhun), among which Songiagao, flowing into Qingnian Reservoir, is apparently a pristine water system, unpolluted by human activities. We found one grain of SiC in all the samples. From Fuzhou River: (1) Blue-green, euhedral, hexagonal shape, water-clear, one edge slightly chipped. (2) Light green, slightly corroded edges. (3) Green, half of the crystal's surface is covered by a blister-like yellow overgrowth; this material protrudes out on one side like a thick tapering paint brush. From Wafandian Vicinity: (1) Blue-green, with patchy black edges. (2) Green, with deep green rims and one brown inclusion. (3) Pale green, subhedral with one beige inclusion. All the crystals show various hues of green and blue, variable color saturation both within itself and between different grains. All crystals have different shapes, forms, coatings, types of reaction rims, while two crystals carry one or two inclusions, The multitude of features suggests a history of intricacies in the growth environment, an implication worthy of our contemplation as we try to understand the problem of diamond genesis.

Phanerozoic burial and unroofing history of the western Slave craton and Wopmay orogen from apatite (U-Th)/He thermochronometry

NASA Astrophysics Data System (ADS)

Ault, Alexis K.; Flowers, Rebecca M.; Bowring, Samuel A.

2009-06-01

Low temperature thermochronometry of cratonic regions can illuminate relationships among burial and unroofing patterns, surface subsidence and uplift, and lithosphere-asthenosphere interactions. The Slave craton, initially stabilized by the development of a thick lithospheric mantle root in late Archean time, is an excellent location in which to examine these connections. Although the Slave craton currently lacks Phanerozoic cover, Phanerozoic sedimentary xenoliths entrained in ca. 610 to 45 Ma kimberlites indicate that the region underwent a more dynamic history of burial and unroofing than widely recognized. We report new apatite (U-Th)/He thermochronometry data along a southeast to northwest transect from the interior of the Slave craton into the adjacent Paleoproterozoic Wopmay orogen to resolve the region's depositional and denudational history. Six samples from the western Slave craton and three samples from Wopmay orogen yield mean dates from 296 ± 41 Ma to 212 ± 39 Ma. Individual apatite dates are broadly uniform over a wide span of apatite [eU], and this pattern can be used to more tightly restrict the spectrum of viable temperature-time paths that can explain the dataset. When coupled with geologic and stratigraphic information, temperature-time simulations of the thermochronometry results suggest complete He loss from the apatites at minimum peak temperatures of ~ 88 °C in Devonian-Pennsylvanian time, cooling to near-surface conditions by the Early Cretaceous, followed by reheating to ≤ 72 °C during Cretaceous-Early Tertiary time. Consideration of modern and ancient geotherm constraints implies ≥ 3.3 km of burial during the first Phanerozoic heating phase, with an ancillary phase of reburial in late Mesozoic-Cenozoic time. The uniformity of the apatite (U-Th)/He dates indicates that the rocks encompassed by our > 250 km-long sample transect experienced similar Phanerozoic thermal histories. Despite the distinctly different lithospheric architecture on either side of the Paleoproterozoic suture between the Slave craton and Wopmay orogen, the region behaved as a single, broadly coherent cratonic unit since at least ca. 250 Ma. The Phanerozoic burial and unroofing patterns across the craton may be a response to far-field convergent activity at the northern and western margins of North America and processes associated with episodic kimberlite emplacement.

The Universal Cpx Jd-Di barometer for mantle peridotite eclogite and pyroxenites and it using for the mantle petrology

NASA Astrophysics Data System (ADS)

Ashchepkov, Igor

2015-04-01

The Jd-Di exchange in clinopyroxenes used for the calibration of pyroxene barometer (Ashchepkov, 2000;2002; Ashchepkov et al 2010;2011;2012) was transformed to make one universal equation for mantle peridotite eclogites and pyroxenites. The original barometer (Ashchepkov, 2002) calibrated on pressures produced by Opx barometry (McGregor , 1974) was transformed (Ashchepkov et al ., 2004; 2010; 2011) to satisfy the increasing data bases for the mantle xenoliths and experimental values 530 in peridotitic and 650 in elcogitic systems . The obtained difference Pd =Pcpx- Pexp were studied for the dependence on each component and their combination . Instead of the common activities we used the temperature-dependent empirical equations. The three separate equations for the common peridotites, pyroxenites and eclogites (Ashchepkov et al., 2010) were checked and complex To and Al-Na-Fe dependent universal coefficients were received. The KD is determined as follows: KD=Na/AlCr*Mg/Ca The logarithmic dependence between P and KD was transformed to a linear one. Final pressure equations are: AlCr=(Al-0.01) *((T-600)/700)**0.75+Cr*(ToK-100)/1000+(4*Ti-0.0125)/ (T0-801)*650 +0.55*((Fe-0.23) *(T0-900)/10000-K) P=0.26*(5+12*(Al+0.30*Na)KD* ToK**0.75 /(1+Fe+ Fe*(ToK-600)/1000)-ln(1273/ ToK))*40*(7*Na-Al-15*Ti+10*Cr+Mg/4)+7.5*Si-20*( Al*Na*Mg/Ca/(Al-2*Ti+Na-2*Fe/(Fe+Mg))+50*(Na+0.1*Al-2*Ti+0.05*Mg-0.22*Ca-0.7*Na)/Ca). Obtained equation in combination with the (Nimis,Taylor, 2000) thermometer allow to reconstruct position of the magma feeder systems of the alkali basaltic magma withing the mantle diapirs in modern platforms like in Vitim plateau (Ashchepkov et al., 2011) and now was applicated to reconstruct the deep seated magma conduits beneath the mountain collision systems, island arcs ocean plateaus etc. This equation allows to receive the positions of the major groups of eclogites mantle sections and to find out the regularities of their behavior. The Fe rich eclogites commonly trace he boundary between the lower upper part of subcontinental lithospheric mantle (SCLM) at 3 -4 GPa marking pyroxenite eclogites layer. Ca- rich eclogites and especially grospydites in SCLM beneath Precambrian kimberlites occurs near pyroxenite layer but in younger mantle sections they became common in the lower parts marking presence of the subducted sediments. The Mg Cr- less group eclogites commonly diamondiferous and referring to the ancient island arc complexes are also common in the middle part of mantle sections and near 5-6 GPa. The group is often dominated in the young kimberlites and sometimes is highly diamondiferous. Commonly P-Fe# for eclogites in the lower SCLM part show rising Fe# with decreasing pressures which very of then reflect the differentiation of the magmatic systems commonly rather significant. Commonly the Fe#-values for the eclogites show that they can't be simple subucted oceanic basalts but material remelted not only during the low angle "hot"subduction but also under the influence of the kimberlite melts including protokimberlite magmas. The Mg - rich and Fe rich pyroxenites also show the extending in pressures trends which suggest the anatexic melting under the influence of volatiles or under the plum magma hybridization. RBRF grants 05-05-64718, 03-05-64146; 11 -05-00060a; 11-05-91060-PICS. Projects 77-2, 65-03, 02-05 IGM SD RAS and ALROSA Stock Company.

Provenance analysis of heavy minerals in beach sands (Falkland Islands/Islas Malvinas) - A view to mineral deposits and the geodynamics of the South Atlantic Ocean

NASA Astrophysics Data System (ADS)

Dill, Harald G.; Skoda, Radek

2017-10-01

Beach sands are ideal traps to collect heavy minerals (HM) from different geodynamic settings and mineral deposits. The coastal sediments contain a mixture of HM derived from the submarine shelf and from source rocks in the hinterland. This is true in a transgressive periglacial regime, where drowned valleys and estuaries are instrumental in draining HM to the arenaceous beach sediments from more distal basement lithologies. A scenario like this can be found in the Falkland Islands/Islas Malvinas. The site under study is the missing link between South Africa and South America, the splitting-apart of which is mirrored by the HM distribution predominantly concentrated in the backshore and dune belt along the coast. The HM are subdivided into three HM associations reflecting the geodynamic evolution of the South Atlantic Ocean and of some of the prominent mineral deposits on the Gondwana Continent: (1) Gondwana cratons and Proterozoic orogens, with Cr and BIF deposits (rutile, zircon, ilmenite, tourmaline, garnet, Cr spinel), (2) rift-related and break-apart magmatic lithologies with mantle-derived pipe rocks such as kimberlites (zircon, pyroxene, spinel, Mg ilmenite), (3) Cordillera-type lithologies with polymetallic stratabound deposits (tourmaline, amphibole, chlorite, REE phosphates). The variation of the major HM from the stable craton (Kalahari-Kaapvaal Craton) in the East to the mobile fold belt (Andes) in the West follows the order of stability of HM. In addition to these 3 geodynamic HM groups, sporadic occurrences of HM originating from alteration (leucoxene, chlorite s.s.s. (= solid solution series)) are part of armored relics such as "nigrine" which on transport disintegrated and thereby released these HM. The major ultrastable and stable HM zircon, rutile, tourmaline s.s.s., spinel s.s.s., and garnet s.s.s. are displayed in a synoptical x-y plot showing the mantle and crustal trends of fractionation and formation of cumulates by means of particular mineral associations as well as the chemical composition of their s.s.s. Five different geodynamic-lithological patterns, each represented by a set of type-lithologies are established for the cratonic magmatic-metamorphic lithosphere. Based on the HM, the geodynamic setting under study is dominated by source rocks typical of a primitive, cratonic setting.

Exsolution lamellae as fast diffusion pathways in rutile: implications for U-Pb thermochronology and Zr thermometry

NASA Astrophysics Data System (ADS)

Smye, A.; Seman, S.; Roberts, N. M. W.; Condon, D. J.; Davis, B.

2017-12-01

Geophysical processes impart characteristic thermal signatures to the lithosphere. Near-continuous thermal histories can be obtained from inversion of intracrystalline U-Pb age profiles in rutile and apatite provided that it can be shown that profile formed in response to Fickian-type diffusion. Here, we present the results of a combined LA-ICPMS and ID-TIMS U-Pb study on rutile grains from two garnet-bearing granulite xenoliths from a kimberlite in the Archean Slave province. Interpreted using numerical models, we show that the rutile U-Pb isotope systematics are consistent with slow-cooling following crystallization at 1.2 Ga, contemporaneous with the Mackenzie dike swarm. However, inversion of rutile U-Pb age gradients is complicated by the ubiquitous presence of ilmenite exsolution lamellae. We show that these lamellae act as fast diffusion pathways for Pb and High Field Strength Elements, including Zr. This has important implications for the use of rutile as a U-Pb themochronometer and as a single-phase thermometer.

Deformation-related spectroscopic features in natural Type Ib-IaA diamonds from Zimmi (West African craton)

NASA Astrophysics Data System (ADS)

Smit, Karen V.; D'Haenens-Johansson, Ulrika F. S.; Howell, Daniel; Loudin, Lorne C.; Wang, Wuyi

2018-06-01

Zimmi diamonds (Sierra Leone) have 500 million year mantle residency times whose origin is best explained by rapid tectonic exhumation to shallower depths in the mantle, associated with continental collision but prior to kimberlite eruption. Here we present spectroscopic data for a new suite of Zimmi sulphide-bearing diamonds that allow us to evaluate the link between their spectroscopic features and their unusual geological history. Cathodoluminesence (CL) imaging of these diamonds revealed irregular patterns with abundant deformation lamellae, associated with the diamonds' tectonic exhumation. Vacancies formed during deformation were subsequently naturally annealed to form vacancy clusters, NV0/- centres and H3 (NVN0). The brownish-yellow to greenish-yellow colours observed in Zimmi Ib-IaA diamonds result from visible absorption by a combination of isolated substitutional nitrogen ( {N}S^0 ) and deformation-related vacancy clusters. Colour-forming centres and other spectroscopic features can all be attributed to the unique geological history of Zimmi Ib-IaA diamonds and their rapid exhumation after formation.

Diamond and moissanite in ophiolitic mantle rocks and podiform chromitites: A deep carbon source?

NASA Astrophysics Data System (ADS)

Yang, J.; Xu, X.; Wiedenbeck, M.; Trumbull, R. B.; Robinson, P. T.

2010-12-01

Diamonds are known from a variety of occurreces, mainly from mantle-derived kimberlites, meteorite impact craters, and continental deep subduction and collision zones. Recently, an unusual mineral group was discovered in the Luobusa ophiolitic chromitites from the Yarlung Zangbu suture, Tibet, which probably originated from a depth of over 300 km in the mantle. Minerals of deep origin include coesite apparently pseudomorphing stishovite, and diamond as individual grains or inclusions in OsIr alloy. To determine if such UHP and unusual minerals occur elsewhere, we collected about 1.5 t of chromitite from two orebodies in an ultramafic body in the Polar Urals. Thus far, more than 60 different mineral species have been separated from these ores. The most exciting discovery is the common occurrence of diamond, a typical UHP mineral in the Luobusa chromitites. These minerals are very similar in composition and structure to those reported from the Luobusa chromitites. So far diamond and/or moissanite have been discovered from many different ophiolitic ultramafic rocks, including in-situ grains in polished chromitite fragments. These discoveries demonstrate that the Luobusa ophiolite is not a unique diamond-bearing massif. Secondary ion mass spectrometric (SIMS) analysis shows that the ophiolite-hosted diamond has a distinctive 13C-depleted isotopic composition (δ13C from -18 to -28‰, n=70), compatible to the ophiolite-hosted moissanite (δ13C from -18 to -35‰, n=36), both are much lighter than the main carbon reservoir in the upper mantle (δ13C near -5‰). The compiled data from moissanite from kimberlites and other mantle settings share the characteristic of strongly 13C-depleted isotopic composition. This suggests that diamond and moissanite originates from a separate carbon reservoir in the mantle or that its formation involved strong isotopic fractionation. Subduction of biogenic carbonaceous material could potentially satisfy both the unusual isotopic and redox constraints on diamond and moissanite formation, but this material would need to stay chemically isolated from the upper mantle until it reached the high-T stability field of diamond and moissanite. The origin of diamond and moissanite in the mantle is still unsolved, but all evidence from the upper mantle indicates that they cannot have formed there, except under special and local redox conditions. We suggest, alternatively, that diamond and moissanite may have formed in the lower mantle, where the existence of 13C-depleted carbon is strongly suspected.

A mantle origin for Paleoarchean peridotitic diamonds from the Panda kimberlite, Slave Craton: Evidence from 13C-, 15N- and 33,34S-stable isotope systematics

NASA Astrophysics Data System (ADS)

Cartigny, Pierre; Farquhar, James; Thomassot, Emilie; Harris, Jeffrey W.; Wing, Bozwell; Masterson, Andy; McKeegan, Kevin; Stachel, Thomas

2009-11-01

In order to address diamond formation and origin in the lithospheric mantle underlying the Central Slave Craton, we report N- and C-stable isotopic compositions and N-contents and aggregation states for 85 diamonds of known paragenesis (73 peridotitic, 8 eclogitic and 4 from lower mantle) from the Panda kimberlite (Ekati Mine, Lac de Gras Area, Canada). For 12 peridotitic and two eclogitic sulfide inclusion-bearing diamonds from this sample set, we also report multiple-sulfur isotope ratios. The 73 peridotitic diamonds have a mean δ13C-value of - 5.2‰ and range from - 6.9 to - 3.0‰, with one extreme value at - 14.1‰. The associated δ15N-values range from - 17.0 to + 8.5‰ with a mean value of - 4.0‰. N-contents range from 0 to 1280 ppm. The 8 eclogitic diamonds have δ13C-values ranging from - 11.2 to - 4.4‰ with one extreme value at - 19.4‰. Their δ15N ranges from - 2.1 to + 7.9‰ and N-contents fall between 0 and 3452 ppm. Four diamonds with an inferred lower mantle origin are all Type II (i.e. nitrogen-free) and have a narrow range of δ13C values, between - 4.5 and - 3.5‰. The δ34S of the 14 analyzed peridotitic and eclogitic sulfide inclusions ranges from - 3.5 to +5.7‰. None of them provide evidence for anomalous δ33S-values; observed variations in δ33S are from +0.19 to - 0.33‰, i.e. within the 2 sigma uncertainties of mantle sulfur ( δ33S = 0‰). At Panda, the N contents and the δ13C of sulfide-bearing peridotitic diamonds show narrower ranges than silicate-bearing peridotitic diamonds. This evidence supports the earlier suggestion established from eclogitic diamonds from the Kaapvaal that sulfide-(±silicate) bearing diamonds sample a more restricted portion of sublithospheric mantle than silicate-(no sulfide) bearing diamonds. Our findings at Panda suggest that sulfide-bearing diamonds should be considered as a specific diamond population on a global-scale. Based on our study of δ34S, Δ 33S, δ15N and δ13C, we find no evidence for subduction-related isotopic signatures in the mantle sampled by Panda diamonds.

Diamond growth from oxidized carbon sources beneath the Northern Slave Craton, Canada: A δ 13C-N study of eclogite-hosted diamonds from the Jericho kimberlite

NASA Astrophysics Data System (ADS)

Smart, Katie A.; Chacko, Thomas; Stachel, Thomas; Muehlenbachs, Karlis; Stern, Richard A.; Heaman, Larry M.

2011-10-01

Diamonds from high- and low-MgO groups of eclogite xenoliths from the Jericho kimberlite, Slave Craton, Canada were analyzed for carbon isotope compositions and nitrogen contents. Diamonds extracted from the two groups show remarkably different nitrogen abundances and δ 13C values. While diamonds from high-MgO eclogites have low nitrogen contents (5-82 ppm) and extremely low δ 13C values clustering at ˜-40‰, diamonds from the low-MgO eclogites have high nitrogen contents (>1200 ppm) and δ 13C values from -3.5‰ to -5.3‰. Coupled cathodoluminescence (CL) imaging and SIMS analysis of the Jericho diamonds provides insight into diamond growth processes. Diamonds from the high-MgO eclogites display little CL structure and generally have constant δ 13C values and nitrogen contents. Some of these diamonds have secondary rims with increasing δ 13C values from -40‰ to ˜-34‰, which suggests secondary diamond growth occurred from an oxidized growth medium. The extreme negative δ 13C values of the high-MgO eclogite diamonds cannot be produced by Rayleigh isotopic fractionation of average mantle-derived carbon (-5‰) or carbon derived from typical organic matter (˜-25‰). However, excursions in δ 13C values to -60‰ are known in the organic sedimentary record at ca. 2.7 and 2.0 Ga, such that diamonds from the high-MgO eclogites could have formed from similar organic matter brought into the Slave lithospheric mantle by subduction. SIMS analyses of a diamond from a low-MgO eclogite show an outer core with systematic rimwards increases in δ 13C values coupled with decreases in nitrogen contents, and a rim with pronounced alternating growth zones. The coupled δ 13C-nitrogen data suggest that the diamond precipitated during fractional crystallization from an oxidized fluid/melt from which nitrogen was progressively depleted during growth. Model calculations of the co-variation of δ 13C-N yielded a partition coefficient ( KN) value of 5, indicating that nitrogen is strongly compatible in diamond relative to the growth medium. δ 13C values of diamond cores (-4‰) dictate the growth medium had higher δ 13C values than primary mantle-derived carbon. Therefore, possible carbon sources for the low-MgO eclogite diamonds include oxidized mantle-derived (e.g. protokimberlite or carbonatite) fluids/melts that underwent some fractionation during migration or, devolatilized subducted carbonates.

Super-reducing conditions in ancient and modern volcanic systems: sources and behaviour of carbon-rich fluids in the lithospheric mantle

NASA Astrophysics Data System (ADS)

Griffin, William L.; Huang, Jin-Xiang; Thomassot, Emilie; Gain, Sarah E. M.; Toledo, Vered; O'Reilly, Suzanne Y.

2018-05-01

Oxygen fugacity (ƒO2) is a key parameter of Earth's mantle, because it controls the speciation of the fluids migrating at depth; a major question is whether the sublithospheric mantle is metal-saturated, keeping ƒO2 near the Iron-Wustite (IW) buffer reaction. Cretaceous basaltic pyroclastic rocks on Mt. Carmel, Israel erupted in an intraplate environment with a thin, hot lithosphere. They contain abundant aggregates of hopper-shaped crystals of Ti-rich corundum, which have trapped melts with phenocryst assemblages (Ti2O3, SiC, TiC, silicides, native V) requiring extremely low ƒO2. These assemblages are interpreted to reflect interaction between basaltic melts and mantle-derived fluids dominated by CH4 + H2. Similar highly reduced assemblages are found associated with volcanism in a range of tectonic situations including subduction zones, major continental collisions, intraplate settings, craton margins and the cratons sampled by kimberlites. This distribution, and the worldwide similarity of δ13C in mantle-derived SiC and associated diamonds, suggest a widespread process, involving similar sources and independent of tectonic setting. We suggest that the common factor is the ascent of abiotic (CH4 + H2) fluids from the sublithospheric mantle; this would imply that much of the mantle is metal-saturated, consistent with observations of metallic inclusions in sublithospheric diamonds (e.g. Smith et al. 2016). Such fluids, perhaps carried in rapidly ascending deep-seated magmas, could penetrate high up into a depleted cratonic root, establishing the observed trend of decreasing ƒO2 with depth (e.g. Yaxley et al. in Lithos 140:142-151, 2012). However, repeated metasomatism (associated with the intrusion of silicate melts) will raise the FeO content near the base of the craton over time, developing a carapace of oxidizing material that would prevent the rise of CH4-rich fluids into higher levels of the subcontinental lithospheric mantle (SCLM). Oxidation of these fluids would release CO2 and H2O to drive metasomatism and low-degree melting both in the carapace and higher in the SCLM. This model can explain the genesis of cratonic diamonds from both reduced and oxidized fluids, the existence of SiC as inclusions in diamonds, and the abundance of SiC in some kimberlites. It should encourage further study of the fine fractions of heavy-mineral concentrates from all types of explosive volcanism.

Petrophysical constraints on the seismic properties of the Kaapvaal craton mantle root

NASA Astrophysics Data System (ADS)

Baptiste, V.; Tommasi, A.

2013-07-01

We calculated the seismic properties of 47 mantle xenoliths from 9 kimberlitic pipes in the Kaapvaal craton based on their modal composition, the crystal preferred orientations (CPO) of olivine, ortho- and clinopyroxene, and garnet, the Fe content of olivine, and the pressures and temperatures at which the rocks were equilibrated. These data allow constraining the variation of seismic anisotropy and velocities with depth. The fastest P wave and fast split shear wave (S1) polarization direction is always close to olivine [100] maximum. Changes in olivine CPO symmetry result in minor variations in the seismic anisotropy patterns. Seismic anisotropy is higher for high olivine contents and stronger CPO. Maximum P waves azimuthal anisotropy (AVp) ranges between 2.5 and 10.2% and S waves polarization anisotropy (AVs) between 2.7 and 8%. Seismic properties averaged in 20 km thick intervals depth are, however, very homogeneous. Based on these data, we predict the anisotropy that would be measured by SKS, Rayleigh (SV) and Love (SH) waves for 5 end-member orientations of the foliation and lineation. Comparison to seismic anisotropy data in the Kaapvaal shows that the coherent fast directions, but low delay times imaged by SKS studies and the low azimuthal anisotropy and SH faster than SV measured using surface waves may only be consistently explained by dipping foliations and lineations. The strong compositional heterogeneity of the Kaapvaal peridotite xenoliths results in up to 3% variation in density and in up to 2.3% of variation Vp, Vs and the Vp/Vs ratio. Fe depletion by melt extraction increases Vp and Vs, but decreases the Vp/Vs ratio and density. Orthopyroxene enrichment decreases the density and Vp, but increases Vs, strongly reducing the Vp/Vs ratio. Garnet enrichment increases the density, and in a lesser manner Vp and the Vp/Vs ratio, but it has little to no effect on Vs. These compositionally-induced variations are slightly higher than the velocity perturbations imaged by body-wave tomography, but cannot explain the strong velocity anomalies reported by surface wave studies. Comparison of density and seismic velocity profiles calculated using the xenoliths' compositions and equilibrium conditions to seismological data in the Kaapvaal highlights that: (i) the thickness of the craton is underestimated in some seismic studies and reaches at least 180 km, (ii) the deep sheared peridotites represent very local modifications caused and oversampled by kimberlites, and (iii) seismological models probably underestimate the compositional heterogeneity in the Kaapvaal mantle root, which occurs at a scale much smaller than the one that may be sampled seismologically.

The neural network approximation method for solving multidimensional nonlinear inverse problems of geophysics

NASA Astrophysics Data System (ADS)

Shimelevich, M. I.; Obornev, E. A.; Obornev, I. E.; Rodionov, E. A.

2017-07-01

The iterative approximation neural network method for solving conditionally well-posed nonlinear inverse problems of geophysics is presented. The method is based on the neural network approximation of the inverse operator. The inverse problem is solved in the class of grid (block) models of the medium on a regularized parameterization grid. The construction principle of this grid relies on using the calculated values of the continuity modulus of the inverse operator and its modifications determining the degree of ambiguity of the solutions. The method provides approximate solutions of inverse problems with the maximal degree of detail given the specified degree of ambiguity with the total number of the sought parameters n × 103 of the medium. The a priori and a posteriori estimates of the degree of ambiguity of the approximated solutions are calculated. The work of the method is illustrated by the example of the three-dimensional (3D) inversion of the synthesized 2D areal geoelectrical (audio magnetotelluric sounding, AMTS) data corresponding to the schematic model of a kimberlite pipe.

Shock Re-equilibration of Fluid Inclusions

NASA Technical Reports Server (NTRS)

Madden, M. E. Elwood; Horz, F.; Bodnar, R. J.

2004-01-01

Fluid inclusions (microscopic volumes of fluid trapped within minerals as they precipitate) are extremely common in terrestrial minerals formed under a wide range of geological conditions from surface evaporite deposits to kimberlite pipes. While fluid inclusions in terrestrial rocks are nearly ubiquitous, only a few fluid inclusion-bearing meteorites have been documented. The scarcity of fluid inclusions in meteoritic materials may be a result of (a) the absence of fluids when the mineral was formed on the meteorite parent body or (b) the destruction of fluid inclusions originally contained in meteoritic materials by subsequent shock metamorphism. However, the effects of impact events on pre-existing fluid inclusions trapped in target and projectile rocks has received little study. Fluid inclusions trapped prior to the shock event may be altered (re-equilibrated) or destroyed due to the high pressures, temperatures, and strain rates associated with impact events. By examining the effects of shock deformation on fluid inclusion properties and textures we may be able to better constrain the pressure-temperature path experienced by terrestrial and meteoritic shocked materials and also gain a clearer understanding of why fluid inclusions are rarely found in meteorite samples.

Thermal anomalies and magmatism due to lithospheric doubling and shifting

NASA Astrophysics Data System (ADS)

Vlaar, N. J.

1983-11-01

We present some thermal and magmatic consequences of the processes of lithospheric doubling and lithospheric shifting. Lithospheric doubling concerns the obduction of a cold continental or old oceanic lithospheric plate over a young and hot oceanic lithosphere/upper mantle system, including an oceanic ridge. Lithospheric shifting concerns the translation and rotation of a lithospheric plate relative to the upper mantle. In both cases the resulting thermal state of the upper mantle below the obducting or shifting lithosphere may be perturbed relative to a "normal" continental or oceanic geothermal situation. The perturbed geothermal state gives rise to a density inversion at depth and thus induces a vertical gravitational instability which favours magmatism. We speculate about the magmatic consequences of this situation and infer that in the case of lithospheric doubling our model may account for the petrology and geochemistry of the resulting magma. The original layering and composition of the overridden young oceanic lithosphere may strongly influence magmatic processes. We dwell shortly on the genesis of kimberlites within the framework of our lithospheric doubling model and on magmatism in general. Lithospheric recycling is inherent to the mechanism of lithospheric doubling.

Linking craton stability and deep earth processes using thermochronology; a case study in the Superior Province of the Canadian Shield.

NASA Astrophysics Data System (ADS)

Sturrock, C. P.; Flowers, R. M.; Zhong, S.; Metcalf, J. R.; Kohn, B. P.

2017-12-01

Ancient, cratonic continental interiors are often presumed to be stable in the long term, neither accumulating nor shedding significant amounts of overlying sediment. However, recent low-temperature thermochronologic work suggests that such long term stability is an overly simplistic view and that forces besides plate tectonics, such as dynamic topography, may play a significant role. New apatite (U-Th)/He (AHe) and apatite fission track (AFT) data from Archean-Proterozoic basement rocks along a 1400km NW-SE transect in the Superior Province of the Canadian Shield record a spatially variable thermal history for the craton in Paleozoic through the end of Mesozoic time. Dates range from 600­­­­­­±60 Ma (AHe) and 529­±48 Ma (AFT) in the west to 184±14 Ma (AHe) and 174±9 Ma (AFT) in the east. Tectonic activity within the Superior Province ceased by 1.8 Ga, with the latest activity at the margins ending at 1 Ga. Widespread resetting of both AHe and AFT systems post 1 Ga is most likely due to regional scale burial at one or more times since the Cambrian. The temperature sensitivity of the AHe and AFT systems (30-90°C and 60-120°C, respectively) require at least a few km of burial across the craton that has since been stripped away. Preliminary inverse thermal history models, utilizing geologic constraints and radiation damage effects on He diffusion in apatite, indicate significant reheating in the Paleozoic-early Mesozoic (37 to >120°C) and a possible lesser reheating event since the mid Mesozoic (<100°C). Making the simplified assumption of a 25°C/km geothermal gradient and 0°C surface temperature, burial in some areas must have been at least 2-5km in the Paleozoic and was <4km in the Mesozoic. These burial and denudation patterns do not correlate with global sea level changes, making dynamic topography a good candidate for a driving mechanism. New AHe data from kimberlites emplaced in the early to mid-Jurassic will provide an important new constraint on the post-Jurassic thermal history of the Superior Province and result in better temperature/burial estimates for the earlier history. Ongoing work will compare these histories with dynamic topography predictions from geodynamic models back into the Paleozoic.

Elemental abundance anomalies in the late Cenomanian extinction interval: a search for the source(s)

USGS Publications Warehouse

Orth, C.J.; Attrep, M.; Quintana, L.R.; Elder, W.P.; Kauffman, E.G.; Diner, R.; Villamil, T.

1993-01-01

Elemental abundances have been measured by neutron activation methods across the Cenomanian-Turonian (late Cretaceous) extinction interval in samples collected from sixteen sites in the Western Interior Basin of North America and from twelve widely separated locations around the globe, including six ODP/DSDP sites. In most Western Interior Basin sites, in Colombia, and in western Europe (weaker), two closely spaced elemental abundance peaks occur in the upper Cenomanian (??? 92 m.y.), spanning the ammonite zones of Sciponoceras gracile through Neocardioceras juddii. Elements with anomalously high concentrations include Sc, Ti, V, Cr, Mn, Co, Ni, Ir, Pt and Au. The lower peak coincides with the disappearance (extinction) of the foraminifer Rotalipora cushmani. In North American sections R. greenhornensis also disappears at or just below this horizon, but in Europe it disappears considerably earlier than R. cushmani. A series of molluscan extinction and speciation or migration events also begins near the stratigraphic level of the lower elemental abundance peak. The well-documented positive ?? 13C excursion begins just before the extinctions and the elemental anomalies, and continues into the lower Turonian, well above the upper anomaly. This carbon isotope excursion has been observed in East European sections where we find little or no evidence of the elemental anomalies, suggesting that the two phenomena may not be tightly coupled. Elemental abundance ratios in the anomalies closely resemble those of Mid-Atlantic Ridge basalt or Hawaiian lava (tholeiitic), but not those of C1 chondrite, black shale, average crustal rocks, or lamproite and kimberlite of roughly similar age in southeastern Kansas. The excess Ir and other siderophiles hint at possible large-body impact(s) for the source. However, we have not located microspherules (other than biogenic calcispheres) or shocked mineral grains in any of our samples. Furthermore, Sc, Ti, V and Mn are not enriched in differentiated Solar-System bodies. Although the weak geochemical signal from comet impact(s) could be masked by the strong terrestrial-like overprint, these anomalies more likely resulted either from intense seafloor spreading activity or merely from increased circulation of deep, metal-rich water associated with the large late Cenomanian through early Turonian eustatic rise and deep-water opening of the South Atlantic. The flooding of continental seaways and margins also could have contributed to the anomalies by preventing much continental detritus from diluting the normal background marine geochemical component. ?? 1993.

Quantitative analysis of trace element concentrations in some gem-quality diamonds

NASA Astrophysics Data System (ADS)

McNeill, J.; Pearson, D. G.; Klein-Ben David, O.; Nowell, G. M.; Ottley, C. J.; Chinn, I.

2009-09-01

The geochemical signature of diamond-forming fluids can be used to unravel diamond-forming processes and is of potential use in the detection of so-called 'conflict' diamonds. While fluid-rich fibrous diamonds can be analyzed by a variety of techniques, very few data have been published for fluid-poor, gem-quality diamonds because of their very low impurity levels. Here we present a new ICPMS-based (ICPMS: inductively coupled plasma mass spectrometry) method for the analysis of trace element concentrations within fluid-poor, gem-quality diamonds. The method employs a closed-system laser ablation cell. Diamonds are ablated and the products trapped for later pre-concentration into solutions that are analyzed by sector-field ICPMS. We show that our limits of quantification for a wide range of elements are at the sub-pg to low pg level. The method is applied to a suite of 10 diamonds from the Cullinan Mine (previously known as Premier), South Africa, along with other diamonds from Siberia (Mir and Udachnaya) and Venezuela. The concentrations of a wide range of elements for all the samples (expressed by weight in the solid) are very low, with rare earth elements along with Y, Nb, Cs ranging from 0.01 to 2 ppb. Large ion lithophile elements (LILE) such as Rb and Ba vary from 1 to 30 ppb. Ti ranges from ppb levels up to 2 ppm. From the combined, currently small data set we observe two kinds of diamond-forming fluids within gem diamonds. One group has enrichments in LILE over Nb, whereas a second group has normalized LILE abundances more similar to those of Nb. These two groups bear some similarity to different groups of fluid-rich diamonds, providing some supporting evidence of a link between the parental fluids for both fluid-inclusion-rich and gem diamonds.

Diamond exploration and regional prospectivity of Western Australia

NASA Astrophysics Data System (ADS)

Hutchison, Mark T.

2018-06-01

Pre-1.6 Ga rocks comprise around 45% of the onshore area of Western Australia (WA), constituting the West Australian Craton (WAC) (including the Archean Yilgarn and Pilbara Cratons) and the western part of the North Australian Craton (NAC). These areas provide the conditions suitable for diamond formation at depth, and numerous diamondiferous lamproite and kimberlite fields are known. As emplacement ages span close to 2500 Ma, there are significant opportunities for diamond-affinity rocks being present near-surface in much of the State, including amongst Phanerozoic rocks. WA's size, terrain, infrastructure and climate, mean that many areas remain underexplored. However, continuous diamond exploration since the 1970s has resulted in abundant data. In order to advance future exploration, a comprehensive database of results of diamond exploration sampling (Geological Survey of Western Australia 2018) has been assessed. The Yilgarn and Pilbara Cratons have spinel indicators almost exclusively dominated by chromite (>90% of grains), whereas (Mg,Fe,Ti)-bearing Al-chromites account for more of the indicator spinels in the NAC, up to 50% of grains at the Northern Territory (NT) border. Increasing dominance of Al in chromites is interpreted as a sign of weathering or a shallower source than Al-depleted Mg-chromites. Garnet compositions across the State also correlate with geological subdivisions, with lherzolitic garnets showing more prospective compositions (Ca-depleted) in WAC samples compared to the NAC. WAC samples also show a much broader scatter into strongly diamond-prospective G10 and G10D compositions. Ilmenites from the NAC show Mg-enriched compositions (consistent with kimberlites), over and above those present in NT data. However, ilmenites from the WAC again show the most diamond-prospective trends. Numerous indicator mineral concentrations throughout the State have unknown sources. Due in part to the presence of diamondiferous lamproites, it is cautioned that some accepted indicator mineral criteria do not apply in parts of WA. For example Ca-depleted garnets, Mg-depleted ilmenites and Cr-depleted and Al-absent clinopyroxenes are all sometimes associated with strongly diamondiferous localities. Quantitative prospectivity analysis has also been carried out based on the extent and results of sampling, age of surface rocks relative to ages of diamond-prospective rocks, and the underlying mantle structure. Results show that locations within the NAC and with proximity to WA's diamond mines score well. However, results point to parts of the WAC being more prospective, consistent with mineral chemical data. Most notable are the Hamersley Basin, Eastern Goldfields Superterrane and the Goodin Inlier of the Yilgarn Craton. Despite prolific diamond exploration, WA is considerably underexplored and the ageing Argyle mine and recent closure of operations at Ellendale warrant a re-evaluation of diamond potential. Results of mineral chemistry and prospectivity analysis make a compelling case for renewed exploration.

X-Ray Tomography of Diamondiferous Eclogites: Clues to the Origin of Diamonds.

NASA Astrophysics Data System (ADS)

Taylor, L. A.; Ketcham, R. A.

2009-05-01

During the last decade or so, considerable new and significant data have been gathered concerning the origin of diamonds. This has come from the mantle xenoliths that are the rocks in which the diamonds originated, namely eclogites and peridotites, the host rocks for diamonds in the mantle. Upon rising through the crust to the surface in their kimberlite magmatic carriers and subsequent weathering on the surface, the weak olivine commonly alters, thereby reducing the crushing strength of the peridotite xenoliths. However, the eclogite xenoliths often retain enough toughness to resist total shattering after initial crushing during diamond recovery process. Subjecting these eclogite nodules to X-rays (e.g., 1.54 Å Cu K) can reveal the bright-blue fluorescence of any diamonds exposed at the surface of the xenoliths. Slow and careful extraction can result in recovery of large diamonds. Many of these unique rocks are the ones upon which we have performed High- Resolution X-ray Computed Tomography (HRXCT) at UT Austin. These data have formed the basis for further eclogite dissections and diamond polishing at UT Knoxville. The size of the diamondiferous eclogites that were scanned by HRXCT are from 20 g to 8.8 kg, all with many diamonds ranging from <1 mm to >1 cm, most octahedral, several with mineral inclusions. These diamondiferous eclogites have both textures and fabrics that provide evidence indicating the secondary formation of the diamonds. These include lineations of diamonds along zones of metasomatic alteration, former zones of enhanced permeability; the non-association of sulfides (po, pn, cpy) with the diamonds, versus sulfide-immiscible melt for the diamond origin; lack of any diamonds in direct contact with the primary garnets or clinopyroxenes; and the presence of some dodecahedral diamonds, indicative of resorption processes, typically attributed to the kimberlite melt. Indeed, these eclogites are not igneous in origin, but metamorphic products of their subducted oceanic crustal protoliths. In addition, detailed studies of the extracted diamonds supply more unexpected results. Polished diamonds examined with cathodoluminescence show evidence for a torturous life of cubic nucleation, growth, resorption, octahedral growth, resorption, and even plastic deformation. These are anomalous observations of diamonds supposedly formed along with the primary minerals in their eclogite hosts. The mineral inclusions in the diamonds reveal additional compelling clues of their origin. Multiple clinopyroxene inclusions can have different compositions within a single diamond, different between diamonds, and even different from that of the host. It is proposed that diamonds present in mantle eclogite xenoliths are secondary, having little to do with their hosts, formed by metasomatic fluids penetrating the eclogites along zones of permeability, and causing extensive secondary alteration and even partial melting of the primary garnets and omphacites.

Carbon isotopic composition and origin of SiC from kimberlites of Yakutia, Russia

NASA Astrophysics Data System (ADS)

Mathez, E. A.; Fogel, R. A.; Hutcheon, I. D.; Marshintsev, V. K.

1995-02-01

The stability of moissanite (SiC) has been computed for upper mantle conditions using the internally optimized thermodynamic dataset for the MgSiO compounds of Fei et al. (1990). The computations consider the effects of pressure and temperature on the elastic properties of phases involved in the reactions. The maximum stability of moissanite throughout the upper mantle is typically five to six orders of magnitude lower in oxygen fugacity ( fO2) than the Fe metal-wüstite oxygen buffer at equivalent temperature and pressure, in agreement with previous calculations. Under conditions of SiC stability, silicates will be Fe-free, Fe metal will contain substantial amounts of Si but little C in solution, and Mg-rich sulfides will be stable. Moissanite from the heavy mineral concentrate of the Mir and Aikhal kimberlite pipes, Yakutia, has been studied. Moissanite crystals are gemmy and vary in color from a characteristic blue-green to pale green to nearly colorless to blue-black. Most exhibit crystallographic faces and are in the size range 0.5 to 1 mm in long dimension. Their compositions include small quantities of Fe, which is ubiquitous, Al, Ca, V, Cr, and Mn, all of which may be present in concentrations > 100 ppmwt. Mineral inclusions are present in some crystals. Silicon metal is the most common; inclusions of ferrosilicite (Fe 3Si 7), FeTi silicides, REE silicate, and sinoite (Si 2N 2O) have also been observed. The carbon isotopic compositions of individual moissanite grains have been determined by ion microprobe. The nine analyzed crystals from Aikhal and fourteen from Mir are characterized by a narrow range in δ 13C values of -22 to -29‰; the majority of crystals fall within a more restricted range of -24 to -27‰. Two grains were analyzed for N and found to have a δ 15N of +9.7 ± 4.0 and +5.6 ± 2.0‰. Five mechanisms for the formation of moissanite are considered. Moissanite may be a relict of a reduced, primordial Earth and now present only as a trace phase in an otherwise oxidized mantle. Alternatively, there may be present-day global regions of the Earth that are both highly reduced and characterized by light carbon isotopic compositions. Although these possiblities cannot be disproved, they are not supported by observations. Two other possibilities, namely that moissanite stability extends to more oxidized conditions at pressures of the lower mantle or that it may form metastably, cannot be evaluated with present knowledge. The possibility most consistent with, although not proven by, the isotopic data is that moissanite formed by metamorphism of reduced, carbonaceous sediments during subduction.

Origins of cratonic mantle discontinuities: A view from petrology, geochemistry and thermodynamic models

NASA Astrophysics Data System (ADS)

Aulbach, Sonja; Massuyeau, Malcolm; Gaillard, Fabrice

2017-01-01

Geophysically detectible mid-lithospheric discontinuities (MLD) and lithosphere-asthenosphere boundaries (LAB) beneath cratons have received much attention over recent years, but a consensus on their origin has not yet emerged. Cratonic lithosphere composition and origin is peculiar due to its ultra-depletion during plume or accretionary tectonics, cool present-day geothermal gradients, compositional and rheological stratification and multiple metasomatic overprints. Bearing this in mind, we integrate current knowledge on the physical properties, chemical composition, mineralogy and fabric of cratonic mantle with experimental and thermodynamic constraints on the formation and migration of melts, both below and within cratonic lithosphere, in order to find petrologically viable explanations for cratonic mantle discontinuities. LABs characterised by strong seismic velocity gradients and increased conductivity require the presence of melts, which can form beneath intact cratonic roots reaching to 200-250 km depth only in exceptionally warm and/or volatile-rich mantle, thus explaining the paucity of seismical LAB observations beneath cratons. When present, pervasive interaction of these - typically carbonated - melts with the deep lithosphere leads to densification and thermochemical erosion, which generates topography at the LAB and results in intermittent seismic LAB signals or conflicting seismic, petrologic and thermal LAB depths. In rare cases (e.g. Tanzanian craton), the tops of live melt percolation fronts may appear as MLDs and, after complete lithosphere rejuvenation, may be sites of future, shallower LABs (e.g. North China craton). Since intact cratons are presently tectonomagmatically quiescent, and since MLDs produce both positive and negative velocity gradients, in some cases with anisotropy, most MLDs may be best explained by accumulations (metasomes) of seismically slow minerals (pyroxenes, phlogopite, amphibole, carbonates) deposited during past magmatic-metasomatic activity, or fabric inherited from cratonisation. They may accumulate as layers at, or as subvertical veins above, the depth at which melt flow transitions from pervasive to focussed flow at the mechanical boundary layer, causing azimuthal and radial anisotropy. Thermodynamic calculations investigating the depth range in which small-volume melts can be produced relative to the field of phlogopite stability and the presence of MLDs show that phlogopite precipitates at various pressures as a function of age-dependent thermal state of the cratonic mantle, thus explaining variable MLD depths. Even if not directly observed, such metasomes have been shown to be important ingredients in small-volume volatile-rich melts typically penetrating cratonic lithospheres. The apparent sparseness of evidence for phlogopite-rich assemblages in the mantle xenolith record at geophysically imaged MLD depths, if not due to preferential disaggregation in the kimberlite or alteration, may relate to vagaries of both kimberlite and human sampling.

The geological record of base metal sulfides in the cratonic mantle: A microscale 187Os/188Os study of peridotite xenoliths from Somerset Island, Rae Craton (Canada)

NASA Astrophysics Data System (ADS)

Bragagni, A.; Luguet, A.; Fonseca, R. O. C.; Pearson, D. G.; Lorand, J.-P.; Nowell, G. M.; Kjarsgaard, B. A.

2017-11-01

We report detailed petrographic investigations along with 187Os/188Os data in Base Metal Sulfide (BMS) on four cratonic mantle xenoliths from Somerset Island (Rae Craton, Canada). The results shed light on the processes affecting the Re-Os systematics and provide time constraints on the formation and evolution of the cratonic lithospheric mantle beneath the Rae craton. When devoid of alteration, BMS grains mainly consist of pentlandite + pyrrhotite ± chalcopyrite. The relatively high BMS modal abundance of the four investigated xenoliths cannot be reconciled with the residual nature of these peridotites, but requires addition of metasomatic BMS. This is especially evident in the two peridotites with the highest bulk Pd/Ir and Pd/Pt. Metasomatic BMS likely formed during melt/fluid percolation in the Sub Continental Lithospheric Mantle (SCLM) as well as during infiltration of the host kimberlite magma, when djerfisherite crystallized around older Fe-Ni-sulfides. On the whole-rock scale, kimberlite metasomatism is visible in a subset of bulk xenoliths, which defines a Re-Os errorchron that dates the host magma emplacement. The 187Os/188Os measured in the twenty analysed BMS grains vary from 0.1084 to >0.17 and it shows no systematic variation depending on the sulfide mineralogical assemblage. The largest range in 187Os/188Os is observed in BMS grains from the two xenoliths with the highest Pd/Ir, Pd/Pt, and sulfide modal abundance. The whole-rock TRD ages of these two samples underestimate the melting age obtained from BMS, demonstrating that bulk Re-Os model ages from peridotites with clear evidence of metasomatism should be treated with caution. The TRD ages determined in BMS grains are clustered around 2.8-2.7, ∼2.2 and ∼1.9 Ga. The 2.8-2.7 Ga TRD ages document the main SCLM building event in the Rae craton, which is likely related to the formation of the local greenstone belts in a continental rift setting. The Paleoproterozoic TRD ages can be explained by addition of metasomatic BMS during (i) major lithospheric rifting at ∼2.2 Ga and (ii) the Taltson-Thelon orogeny at ∼1.9 Ga. The data suggest that even metasomatic BMS can inherit 187Os/188Os from their original mantle source. The lack of isotopic equilibration, even at the micro-scale, allowed the preservation of different populations of BMS grains with distinct 187Os/188Os, providing age information on multiple magmatic events that affected the SCLM.

Garnet from diamondiferous metamorphic rocks of Kokchetav massif, Kazakhstan as a peak pressure recorder

NASA Astrophysics Data System (ADS)

Sobolev, N. V.; Palyanov, Y. N.; Shatsky, V. S.; Sokol, A. G.; Tomilenko, A. A.

2003-12-01

Garnet is a key mineral coexisting with diamond both in kimberlite (as xenocrysts, in diamondiferous garnet peridotites and eclogites, as inclusions in diamond) and in UHP metamorphic rocks of Kokchetav massif (diamondiferous gneisses, garnet-pyroxene rocks, dolomitic marbles and diamond facies eclogites). In UHPM rocks garnets are of particular importance as inclusions in zircons protected from retrograde metamorphism. Diamond formation conditions in eclogitic (E-type) upper mantle environment are estimated based upon Grt-Cpx thermometry and coesite barometry (e.g. Sobolev et al., PNAS, 2000, 97:11875) at P=5.5-6.0 GPa and T=1000-1300° C. These data are supported by diamond synthesis in carbonate-silicate fluid (e.g. Palyanov et al., Nature, 1999, 400: 417). E-type garnet may dissolve up to 0.3 wt.% Na2O (Sobolev, Lavrentyev, Contr. Min. Petr., 1971, 31:1) depending on pressure and Na2O contents in coexisting pyroxene and melts (fluids). Majorite component (pyroxene solid solution) was reported in rare garnets from diamonds (e.g. Moore, Gurney, Nature, 1985, 318:553) and UHP conditions were experimentally confirmed for such garnets (Irifune, Phys. Eart. Pl. Int., 1987, 45:324; Gasparik, Phys. Chem. Min., 2002, 29:170; Luth, Am. Miner., 1997, 82:1198). Garnets from Kokchetav diamondiferous metamorphic rocks demonstrate considerably lower Na2O solubility (up to 0.2 wt.% in rare samples) and absence of majorite component. However, coexisting pyroxenes may contain up to 50 mol.% jadeite. Several UHP experiments performed with Kokchetav eclogites and dolomitic marbles using a split-sphere apparatus resulted in detection of up to 0.3-0.4 wt.% Na2O in newly formed eclogitic garnets at P=5.7 and 7.0 GPa, T=1400 and 1700° C respectively. Majorite component was also determined in newly formed garnets reaching about 5% with Si (pfu)=3.05-3.06. Similar garnets without Na2O were also obtained in UHP experiments with diamondiferous dolomitic marbles (e.g. Palyanov et al., Dokl. Earth. Sci., 2001, 380:671). Based on the difference in Na2O and majorite contents in natural Kokchetav garnets, and those coexisting with diamonds in kimberlite and obtained in UHP experiments, we conclude that the peak of metamorphism at Kokchetav massif occurred at P about 4.5-5.0 GPa and T=900-1000° C (Sobolev, Shatsky, Nature, 1990, 343:742; Shatsky et al., Contr. Min. Petr., 1999, 137:185; Sobolev et al., Dokl. Earth. Sci., 2001, 380:237) but not exceeding 6.0 GPa (e.g. Ogasawara et al., Island Arc, 2000, 9:400).

A billion years of metasomatic alteration of the Kaapvaal SCLM encapsulated in fibrous diamonds

NASA Astrophysics Data System (ADS)

Weiss, Yaakov; Goldstein, Steven; Class, Cornelia; Winckler, Gisela

2017-04-01

Constraining the nature and timing of metasomatic events by C-O-H fluids in the sub-continental lithospheric mantle (SCLM) is an ongoing challenge in our understanding of the SCLM history. 'Fibrous' diamonds, which rapidly grow during such fluid-rock interaction, commonly encapsulate the C-O-H fluid metasomatic agents, which are trapped and encapsulated as μm-scale high-density fluid (HDF) inclusions and can be directly sampled. They thus offer a unique opportunity to investigate metasomatic events involving C-O-H fluids in the SCLM. We analyzed major and trace elements and the helium content and isotopic composition of the HDFs included in a set of diamonds from the DeBeers-Pool and Finsch kimberlites in the Kaapvaal craton, South Africa. Saline HDF micro-inclusions in 3 of the DeBeers diamonds and in 2 from Finsch have very similar major and trace element compositions, suggesting they formed in related metasomatic events. They are characterized by high alkalis (K, Rb and Cs), Ba and LREEs compared to Th, U, Nb and Ta, and by Ti, Zr, Hf and Y negative anomalies relative to REEs of similar compatibility. Their 3He/4He ratios vary between 3-4 Ra. Plotting the 3 DeBeers-Pool diamonds on an 4He/3He vs 238U/3He diagram defines an 'isochron' with an age of 96±45 Ma. This result represents the first radiometric age reported for fibrous diamonds and the C-O-H mantle fluids they carry. In addition, 1 diamond from DeBeers-Pool has silicic microinclusion compositions while 2 diamonds from Finsch carry carbonatitic HDFs. These diamonds display more radiogenic 3He/4He ratios between 0.07-0.6 Ra, which suggests formation during earlier and different metasomatic events. Using the measured U, Th, 4He and 3He content of these diamonds, and the equation for 4He production by U and Th, we calculate 3He/4He ratios as a function of time. Assuming that the HDFs initial R/Ra values varied between 3-11, representing common values for MORB, the SCLM and subducted components, the silicic and carbonatitic HDFs signify two older metasomatic events that took place in the Kaapvaal lithosphere at 350 and 850 Ma, respectively. Thus, our new data reveal 3 episodes of chemical changes in the Kaapvaal craton SCLM during the last 1 Ga, each by a different metasomatic agent. The youngest episodes indicate direct relationships between highly-saline fluid metasomatism, fibrous diamond formation and late-Mesozoic kimberlite eruptions, while the older silicic and carbonatitic metasomatic events may be related to the regional Namaqua-Natal Orogeny and Damara Orogeny at 1 Ga and 500 Ma, respectively.

25. First floor, east wall bathroom, looking east Veterans ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

25. First floor, east wall bathroom, looking east - Veterans Administration Center, Officers Duplex Quarters, 5302 East Kellogg (Legal Address); 5500 East Kellogg (Common Address), Wichita, Sedgwick County, KS

The Victor Mine (Superior Craton, Canada): Neoproterozoic lherzolitic diamonds from a thermally-modified cratonic root

NASA Astrophysics Data System (ADS)

Stachel, Thomas; Banas, Anetta; Aulbach, Sonja; Smit, Karen V.; Wescott, Pamela; Chinn, Ingrid L.; Kong, Julie

2018-05-01

The Jurassic Victor kimberlite (Attawapiskat Field) was emplaced into an area of the central Superior Craton that was affected by a lithosphere-scale thermal event at 1.1 Ga. Victor diamonds formed ca. 400 million years after this event, in a lithospheric mantle characterized by an unusually cool model geotherm (37-38 mW/m2; Hasterok and Chapman 2011). The bulk of Victor diamonds derives from a thin (<10 km thick) layer that is located at about 180 km depth and represents lherzolitic substrates (for 85% of diamonds). Geothermobarometric calculations (average pressure and temperature at the 1 sigma level are 57 ± 2 kbar and 1129 ± 16 °C) coupled with typical fluid metasomatism-associated trace element patterns for garnet inclusions indicate diamond precipitation under sub-solidus (lherzolite + H2O) conditions. This conclusion links the presence of a diamond-rich lherzolitic layer in the lithospheric mantle, just above the depth where ascending melts would freeze, to the unusually low paleogeotherm beneath Attawapiskat, because along an average cratonic geotherm (40 mW/m2) lherzolite in the presence of hydrous fluid would melt at depths >140 km.

Tiny timekeepers witnessing high-rate exhumation processes.

PubMed

Zhong, Xin; Moulas, Evangelos; Tajčmanová, Lucie

2018-02-02

Tectonic forces and surface erosion lead to the exhumation of rocks from the Earth's interior. Those rocks can be characterized by many variables including peak pressure and temperature, composition and exhumation duration. Among them, the duration of exhumation in different geological settings can vary by more than ten orders of magnitude (from hours to billion years). Constraining the duration is critical and often challenging in geological studies particularly for rapid magma ascent. Here, we show that the time information can be reconstructed using a simple combination of laser Raman spectroscopic data from mineral inclusions with mechanical solutions for viscous relaxation of the host. The application of our model to several representative geological settings yields best results for short events such as kimberlite magma ascent (less than ~4,500 hours) and a decompression lasting up to ~17 million years for high-pressure metamorphic rocks. This is the first precise time information obtained from direct microstructural observations applying a purely mechanical perspective. We show an unprecedented geological value of tiny mineral inclusions as timekeepers that contributes to a better understanding on the large-scale tectonic history and thus has significant implications for a new generation of geodynamic models.

Pre-subduction metasomatic enrichment of the oceanic lithosphere induced by plate flexure

NASA Astrophysics Data System (ADS)

Pilet, S.; Abe, N.; Rochat, L.; Kaczmarek, M.-A.; Hirano, N.; Machida, S.; Buchs, D. M.; Baumgartner, P. O.; Müntener, O.

2016-12-01

Oceanic lithospheric mantle is generally interpreted as depleted mantle residue after mid-ocean ridge basalt extraction. Several models have suggested that metasomatic processes can refertilize portions of the lithospheric mantle before subduction. Here, we report mantle xenocrysts and xenoliths in petit-spot lavas that provide direct evidence that the lower oceanic lithosphere is affected by metasomatic processes. We find a chemical similarity between clinopyroxene observed in petit-spot mantle xenoliths and clinopyroxene from melt-metasomatized garnet or spinel peridotites, which are sampled by kimberlites and intracontinental basalts respectively. We suggest that extensional stresses in oceanic lithosphere, such as plate bending in front of subduction zones, allow low-degree melts from the seismic low-velocity zone to percolate, interact and weaken the oceanic lithospheric mantle. Thus, metasomatism is not limited to mantle upwelling zones such as mid-ocean ridges or mantle plumes, but could be initiated by tectonic processes. Since plate flexure is a global mechanism in subduction zones, a significant portion of oceanic lithospheric mantle is likely to be metasomatized. Recycling of metasomatic domains into the convecting mantle is fundamental to understanding the generation of small-scale mantle isotopic and volatile heterogeneities sampled by oceanic island and mid-ocean ridge basalts.

A global geochemical model for the evolution of the mantle

NASA Technical Reports Server (NTRS)

Anderson, D. L.

1979-01-01

It is proposed that the upper mantle transition region, 220 to 670 km, is composed of eclogite which has been derived from primitive mantle by about 20 percent partial melting and that this is the source and sink of oceanic crust. The remainder of the upper mantle is garnet peridotite which is the source of continental basalts and hotspot magmas. This region is enriched in incompatible elements by hydrous and CO2 rich metasomatic fluids which have depleted the underlying layers in the L.I.L. elements and L.R.E.E. The volatiles make this a low-velocity, high attenuation, low viscosity region. The eclogite layer is internally heated and its controls the convection pattern in the upper mantle. Plate tectonics is intermittent. The continental thermal anomaly at a depth of 150-220 km triggers kimberlite and carbonatite activity, alkali and flood basalt volcanism, vertical tectonics and continental breakup. Hot spots remain active after the continents leave and build the oceanic islands. Mantle plumes rise from a depth of about 220 km. Midocean ridge basalts rise from the depleted layer below this depth. Material from this layer can also be displaced upwards by subducted oceanic lithosphere to form back-arc basins.

A snapshot of mantle metasomatism: Trace element analysis of coexisting fluid (LA-ICP-MS) and silicate (SIMS) inclusions in fibrous diamonds

NASA Astrophysics Data System (ADS)

Tomlinson, E. L.; Müller, W.; EIMF

2009-03-01

We have determined the trace element compositions of coexisting fluid (carbonate-K-chloride-H 2O) and single-phase mineral inclusions in peridotitic (Cr-diopside) and eclogitic (omphacite, garnet) inclusions in fibrous diamonds from the Panda kimberlite (Slave craton, Canada). These diamonds provide a unique insight into the nature of the metasomatic agent, the metasomatised minerals and the pre-metasomatic protolith. The fluid component is strongly enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE). Co-existing peridotitic minerals record a melt extraction event (high Cr and Ni) in the protolith prior to the influx of the trapped metasomatic fluid. The silicate minerals are also strongly enriched in LREE. Calculated partition coefficients agree with experimentally determined values in the literature, despite the complex composition of the natural fluid. This indicates that the minerals have re-equilibrated with the metasomatic fluid. The trace element compositions of the mineral inclusions are comparable to many equivalent phases in monocrystalline diamonds. This suggests that the metasomatic fluid and the process recorded in these samples may also be responsible for the growth of some types of monocrystalline diamonds.

The Hadean-Archaean Environment

PubMed Central

Sleep, Norman H.

2010-01-01

A sparse geological record combined with physics and molecular phylogeny constrains the environmental conditions on the early Earth. The Earth began hot after the moon-forming impact and cooled to the point where liquid water was present in ∼10 million years Subsequently, a few asteroid impacts may have briefly heated surface environments, leaving only thermophile survivors in kilometer-deep rocks. A warm 500 K, 100 bar CO2 greenhouse persisted until subducted oceanic crust sequestered CO2 into the mantle. It is not known whether the Earth's surface lingered in a ∼70°C thermophile environment well into the Archaean or cooled to clement or freezing conditions in the Hadean. Recently discovered ∼4.3 Ga rocks near Hudson Bay may have formed during the warm greenhouse. Alkalic rocks in India indicate carbonate subduction by 4.26 Ga. The presence of 3.8 Ga black shales in Greenland indicates that S-based photosynthesis had evolved in the oceans and likely Fe-based photosynthesis and efficient chemical weathering on land. Overall, mantle derived rocks, especially kimberlites and similar CO2-rich magmas, preserve evidence of subducted upper oceanic crust, ancient surface environments, and biosignatures of photosynthesis. PMID:20516134

Petrophysical constraints on the seismic properties of the Kaapvaal craton mantle root

NASA Astrophysics Data System (ADS)

Virginie, Baptiste; Andrea, Tommasi

2014-05-01

We calculated the seismic properties of 47 mantle xenoliths from 9 kimberlitic pipes in the Kaapvaal craton based on their modal composition, the crystal preferred orientations (CPO) of olivine, ortho- and clinopyroxene, and garnet, the Fe content of olivine, and the pressures and temperatures at which the rocks were equilibrated. These data allow constraining the variation of seismic anisotropy and velocities within the cratonic mantle. The fastest P and S2 waves propagation direction and the polarization of fast split shear wave (S1) are always subparallel to olivine [100] axes maximum concentration, which marks the lineation (fossil flow direction). Seismic anisotropy is higher for high olivine contents and stronger CPO. Maximum P-wave azimuthal anisotropy (AVp) ranges between 2.5 and 10.2% and the maximum S-wave polarization anisotropy (AVs), between 2.7 and 8%. Changes in olivine CPO symmetry result in minor variations in the seismic anisotropy patterns, mainly in the apparent isotropy directions for shear wave splitting. Seismic properties averaged over 20 km thick depth sections are, therefore, very homogeneous. Based on these data, we predict the anisotropy that would be measured by SKS, Rayleigh (SV) and Love (SH) waves for 5 end-member orientations of the foliation and lineation. Comparison to seismic anisotropy data in the Kaapvaal shows that the coherent fast directions, but low delay times imaged by SKS studies and the low azimuthal anisotropy with SH faster than SV measured using surface waves are best explained by a homogeneously dipping (45°) foliation and lineation in the cratonic mantle lithosphere. Laterally or vertically varying foliation and lineation orientations with a dominantly NW-SE trend might also explain the low measured anisotropies, but this model should also result in backazimuthal variability of the SKS splitting data, not reported in the seismological data. The strong compositional heterogeneity of the Kaapvaal peridotite xenoliths results in up to 3% variation in density and in up to 2.3% variation of Vp, Vs, and Vp/Vs ratio. Fe depletion by melt extraction increases Vp and Vs, but decreases the Vp/Vs ratio and density. Orthopyroxene enrichment due to metasomatism decreases the density and Vp, strongly reducing the Vp/Vs ratio. Garnet enrichment, which was also attributed to metasomatism, increases the density, and in a lesser extent Vp and the Vp/Vs ratio. Comparison of density and seismic velocity profiles calculated using the xenoliths' compositions and equilibration conditions to seismological data in the Kaapvaal highlights that: (i) the thickness of the craton is underestimated in some seismic studies and reaches at least 180 km, (ii) the deep sheared peridotites represent very local modifications caused and oversampled by kimberlites, and (iii) seismological models probably underestimate the compositional heterogeneity in the Kaapvaal mantle root, which occurs at a scale much smaller than the one that may be sampled seismologically.

Petrophysical constraints on the seismic properties of the Kaapvaal craton mantle root

NASA Astrophysics Data System (ADS)

Baptiste, V.; Tommasi, A.

2014-01-01

We calculated the seismic properties of 47 mantle xenoliths from 9 kimberlitic pipes in the Kaapvaal craton based on their modal composition, the crystal-preferred orientations (CPO) of olivine, ortho- and clinopyroxene, and garnet, the Fe content of olivine, and the pressures and temperatures at which the rocks were equilibrated. These data allow constraining the variation of seismic anisotropy and velocities within the cratonic mantle. The fastest P and S2 wave propagation directions and the polarization of fast split shear waves (S1) are always subparallel to olivine [100] axes of maximum concentration, which marks the lineation (fossil flow direction). Seismic anisotropy is higher for high olivine contents and stronger CPO. Maximum P wave azimuthal anisotropy (AVp) ranges between 2.5 and 10.2% and the maximum S wave polarization anisotropy (AVs), between 2.7 and 8%. Changes in olivine CPO symmetry result in minor variations in the seismic anisotropy patterns, mainly in the apparent isotropy directions for shear wave splitting. Seismic properties averaged over 20 km-thick depth sections are, therefore, very homogeneous. Based on these data, we predict the anisotropy that would be measured by SKS, Rayleigh (SV) and Love (SH) waves for five endmember orientations of the foliation and lineation. Comparison to seismic anisotropy data from the Kaapvaal shows that the coherent fast directions, but low delay times imaged by SKS studies, and the low azimuthal anisotropy with with the horizontally polarized S waves (SH) faster than the vertically polarized S wave (SV) measured using surface waves are best explained by homogeneously dipping (45°) foliations and lineations in the cratonic mantle lithosphere. Laterally or vertically varying foliation and lineation orientations with a dominantly NW-SE trend might also explain the low measured anisotropies, but this model should also result in backazimuthal variability of the SKS splitting data, not reported in the seismological data. The strong compositional heterogeneity of the Kaapvaal peridotite xenoliths results in up to 3% variation in density and in up to 2.3% variation of Vp, Vs, and Vp / Vs ratio. Fe depletion by melt extraction increases Vp and Vs, but decreases the Vp / Vs ratio and density. Orthopyroxene enrichment due to metasomatism decreases the density and Vp, strongly reducing the Vp / Vs ratio. Garnet enrichment, which was also attributed to metasomatism, increases the density, and in a lesser extent Vp and the Vp / Vs ratio. Comparison of density and seismic velocity profiles calculated using the xenoliths' compositions and equilibration conditions to seismological data in the Kaapvaal highlights that (i) the thickness of the craton is underestimated in some seismic studies and reaches at least 180 km, (ii) the deep sheared peridotites represent very local modifications caused and oversampled by kimberlites, and (iii) seismological models probably underestimate the compositional heterogeneity in the Kaapvaal mantle root, which occurs at a scale much smaller than the one that may be sampled seismologically.

Lithospheric-Mantle Structure of the Kaapvaal Craton, South Africa, Derived From Thermodynamically Self-Consistent Modelling of Seismic Surface-Wave and S-wave Receiver Function, Heat-flow, Elevation, Xenolith and Magnetotelluric Observations

NASA Astrophysics Data System (ADS)

Muller, M. R.; Fullea, J.; Jones, A. G.; Adam, J.; Lebedev, S.; Piana Agostinetti, N.

2012-12-01

Results from recent geophysical and mantle-xenolith geochemistry studies of the Kaapvaal Craton appear, at times, to provide disparate views of the physical, chemical and thermal structure of the lithosphere. Models from our recent SAMTEX magnetotelluric (MT) surveys across the Kaapvaal Craton indicate a resistive, 220-240 km thick lithosphere for the central core of the craton. One published S-wave receiver function (SRF) study and other surface-wave studies suggest a thinner lithosphere characterised by a ~160 km thick high-velocity "lid" underlain by a low-velocity zone (LVZ) of between 65-150 km in thickness. Other seismic studies suggest that the (high-velocity) lithosphere is thicker, in excess of 220 km. Mantle xenolith pressure-temperature arrays from Mesozoic kimberlites require that the base of the "thermal" lithosphere (i.e., the depth above which a conductive geotherm is maintained) is at least 220 km deep, to account for mantle geotherms in the range 35-38 mWm-2. Richly diamondiferous kimberlites across the Kaapvaal Craton require a lithospheric thickness substantially greater than 160 km - the depth of the top of the diamond stability field. In this paper we use the recently developed LitMod software code to derive, thermodynamically consistently, a range of 1-D seismic velocity, density, electrical resistivity and temperature models from layered geochemical models of the lithosphere based on mantle xenolith compositions. In our work, the "petrological" lithosphere-asthenosphere boundary (pLAB) (i.e., the top of the fertile asthenospheric-mantle) and the "thermal" LAB (tLAB as defined above) are coincident. Lithospheric-mantle models are found simultaneously satisfying all geophysical observables: new surface-wave dispersion data, published SRFs, MT responses, surface elevation and heat-flow. Our results show: 1. All lithospheric-mantle models are characterised by a seismic LVZ with a minimum velocity at the depth of the petrological/thermal LAB. The top of the LVZ does not correspond with the LAB. 2. Thin (~160 km-thick) lithospheric-mantle models are consistent with surface elevation and heat-flow observations only for unreasonably low average crustal heat production values (~0.4 μWm-3). However, such models are inconsistent both with the surface-wave dispersion data and youngest (Group I) palaeo-geotherms defined by xenolith P-T arrays. 3. A three-layered geochemical model (consistent with mantle xenoliths), with lithospheric thickness in excess of 220 km, is required to match all geophysical constraints. 4. The chemical transition from a depleted harzburgitic composition (above) to a refertilised high-T lherzolitic composition (below) at 160 km depth produces a sharp onset of the seismic LVZ and a sharp increase in density. Synthetic SRFs will assess whether this chemical transition may account for the reported S-to-P conversion event at 160 km depth. However, in this this instance the SRF conversion event would not represent the petrological/thermal LAB.

Lithospheric-Mantle Structure of the Kaapvaal Craton, South Africa, Derived from Thermodynamically Self-Consistent Modelling of Magnetotelluric, Surface-Wave Dispersion, S-wave Receiver Function, Heat-flow, Elevation and Xenolith Observations

NASA Astrophysics Data System (ADS)

Muller, Mark; Fullea, Javier; Jones, Alan G.; Adam, Joanne; Lebedev, Sergei; Piana Agostinetti, Nicola

2013-04-01

Results from recent geophysical and mantle-xenolith geochemistry studies of the Kaapvaal Craton appear, at times, to provide disparate views of the physical, chemical and thermal structure of the lithosphere. Models from our recent SAMTEX magnetotelluric (MT) surveys across the Kaapvaal Craton indicate a resistive, 220-240 km thick lithosphere for the central core of the craton. One published S-wave receiver function (SRF) study and other surface-wave studies suggest a thinner lithosphere characterised by a ~160 km thick high-velocity "lid" underlain by a low-velocity zone (LVZ) of between 65-150 km in thickness. Other seismic studies suggest that the (high-velocity) lithosphere is thicker, in excess of 220 km. Mantle xenolith pressure-temperature arrays from Mesozoic kimberlites require that the base of the "thermal" lithosphere (i.e., the depth above which a conductive geotherm is maintained - the tLAB) is at least 220 km deep, to account for mantle geotherms in the range 35-38 mWm-2. Richly diamondiferous kimberlites across the Kaapvaal Craton require a lithospheric thickness substantially greater than 160 km - the depth of the top of the diamond stability field. In this paper we use the recently developed LitMod software code to derive, thermodynamically consistently, a range of 1-D electrical resistivity, seismic velocity, density and temperature models from layered geochemical models of the lithosphere based on mantle xenolith compositions. In our work, the "petrological" lithosphere-asthenosphere boundary (pLAB) (i.e., the top of the fertile asthenospheric-mantle) and the "thermal" LAB (tLAB) are coincident. Lithospheric-mantle models are found simultaneously satisfying all geophysical observables: MT responses, new surface-wave dispersion data, published SRFs, surface elevation and heat-flow. Our results show: 1. All lithospheric-mantle models are characterised by a seismic LVZ with a minimum velocity at the depth of the petrological/thermal LAB. The top of the LVZ does not correspond with the LAB. 2. Thin (~160 km-thick) lithospheric-mantle models are consistent with surface elevation and heat-flow observations only for unreasonably low average crustal heat production values (~0.4 µWm-3). However, such models are inconsistent both with the surface-wave dispersion data and youngest (Group I) palaeo-geotherms defined by xenolith P-T arrays. 3. A three-layered geochemical model, with lithospheric thickness in excess of 230 km, is required to match all geophysical and xenolith constraints. 4. The chemical transition from a depleted harzburgitic composition (above) to a refertilised high-T lherzolitic composition (below) at 160 km depth produces a sharp onset of the seismic LVZ and a sharp increase in density. Synthetic SRFs indicate that this chemical transition is able to account for the reported S-to-P conversion event at 160 km depth. In this this instance the 160 km deep SRF event does not represent the petrological/thermal LAB.

19. VIEW OF CRUDE ORE BINS FROM EAST. EAST CRUDE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

19. VIEW OF CRUDE ORE BINS FROM EAST. EAST CRUDE ORE BIN IN FOREGROUND WITH DISCHARGE TO GRIZZLY AT BOTTOM OF VIEW. CONCRETE RETAINING WALL TO LEFT (SOUTH) AND BOTTOM (EAST EDGE OF EAST BIN). - Bald Mountain Gold Mill, Nevada Gulch at head of False Bottom Creek, Lead, Lawrence County, SD

2. VIEW EAST, East Control Area, west radar tower in ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. VIEW EAST, East Control Area, west radar tower in foreground, east radar lower in background - Newport NIKE Missile Battery D-57/58, Integrated Fire Control Area, Newport Road, Carleton, Monroe County, MI

1. EAST FACING SIDE EAST AND SOUTH SOUTH FACING SIDE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. EAST FACING SIDE EAST AND SOUTH SOUTH FACING SIDE RESIDENTIAL AREA AROUND BUILDINGS 136, 137, & 138 - Hill Field, Non-Commissioned Officers' Quarters, North side of Fourth street, East side of E Avenue, Layton, Davis County, UT

Pathways to an East Asian Higher Education Area: A Comparative Analysis of East Asian and European Regionalization Processes

ERIC Educational Resources Information Center

Chao, Roger Y., Jr.

2014-01-01

The Author argues that historical regional developments in Europe and East Asia greatly influence the formation of an East Asian Higher Education Area. As such, this article compares European and East Asian regionalization and higher education regionalization processes to show this path dependency in East Asian regionalization of higher education…

55. LOOKING EAST FROM HEAD OF PLANE 2 EAST. POWER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

55. LOOKING EAST FROM HEAD OF PLANE 2 EAST. POWER HOUSE AND FLUME VISIBLE TO RIGHT, TAILRACE RUNNING THROUGH CENTER OF PHOTOGRAPH. CRADLE TO INCLINED PLANE 3 EAST IS VISIBLE IN BACKGROUND TO LEFT. - Morris Canal, Phillipsburg, Warren County, NJ

2. View of north side of East Ward Street east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. View of north side of East Ward Street east of North Coweta Avenue, facing northeast. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

13. View of south side of East Ward Street east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. View of south side of East Ward Street east of Sibett Avenue, facing southwest. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

7. View of south side of East Ward Street east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. View of south side of East Ward Street east of South Coweta Avenue, facing southwest. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

17. View of north side of East Ward Street east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

17. View of north side of East Ward Street east of North McDonald Avenue, facing northwest. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

20. View of south side of East Ward Street east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

20. View of south side of East Ward Street east of South McDonald Avenue, facing southeast. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

22. View of east side of South Gaskin Avenue at ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. View of east side of South Gaskin Avenue at the intersection with East Ashley Street, facing east. - Gaskin Avenue Neighborhood, Bounded by Dart Street to east, CSX Railroad to south, Pearl & Madison Avenues to west, & Wilson & Gordon Streets to north, Douglas, Coffee County, GA

4. Engine room, east end looking east toward engine #4 ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. Engine room, east end looking east toward engine #4 (Enterprise Diesel; reduction gear in foreground; in left rear, two D.C. generators with Ames Ironworks horizontal engine and sturtevant vertical engine - East Boston Pumping Station, Chelsea Street at Chelsea Creek, Boston, Suffolk County, MA

The Extrachromosomal EAST Protein of Drosophila Can Associate with Polytene Chromosomes and Regulate Gene Expression

PubMed Central

Wasser, Martin; Chia, William

2007-01-01

The EAST protein of Drosophila is a component of an expandable extrachromosomal domain of the nucleus. To better understand its function, we studied the dynamics and localization of GFP-tagged EAST. In live larval salivary glands, EAST-GFP is highly mobile and localizes to the extrachromosomal nucleoplasm. When these cells are permeabilized, EAST-GFP rapidly associated with polytene chromosomes. The affinity to chromatin increases and mobility decreases with decreasing salt concentration. Deleting the C-terminal residues 1535 to 2301 of EAST strongly reduces the affinity to polytene chromosomes. The bulk of EAST-GFP co-localizes with heterochromatin and is absent from transcriptionally active chromosomal regions. The predominantly chromosomal localization of EAST-GFP can be detected in non-detergent treated salivary glands of pupae as they undergo apoptosis, however not in earlier stages of development. Consistent with this chromosomal pattern of localization, genetic evidence indicates a role for EAST in the repression of gene expression, since a lethal east mutation is allelic to the viable mutation suppressor of white-spotted. We propose that EAST acts as an ion sensor that modulates gene expression in response to changing intracellular ion concentrations. PMID:17476334

22. First floor, staircase, looking east Veterans Administration Center, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. First floor, staircase, looking east - Veterans Administration Center, Officers Duplex Quarters, 5302 East Kellogg (Legal Address); 5500 East Kellogg (Common Address), Wichita, Sedgwick County, KS

How robust is the IAT? Measuring and manipulating implicit attitudes of East- and West-Germans.

PubMed

Kühnen, U; Schiessl, M; Bauer, N; Paulig, N; Pöhlmann, C; Schmidthals, K

2001-01-01

We investigated consequences of priming East-West-German related self-knowledge for the strength of implicit, ingroup-directed positive evaluations among East- and West-Germans. Based on previous studies we predicted opposite effects of self-knowledge priming for East- and West-Germans. Since in general the East-German stereotype is regarded as more negative than the West-German one, bringing to mind East-West-related self-knowledge (relative to neutral priming) was expected to attenuate ingroup favoritism for East-Germans, but to increase it for West-Germans. After having fulfilled the priming tasks, participants worked on an IAT-version in which the to be classified stimuli were East- or West-German city names (dimension 1) and positive or negative adjectives (dimension 2). Results of Experiment 1 showed (a) that East- and West-German students implicitly evaluated their ingroups as more positive than the outgroups and (b) confirmed the predictions of the priming influence. Experiment 2 replicated these findings with more representative samples from East- and West-Germany. The results are discussed with regard to underlying processes of implicit attitudes in intergroup contexts.

4. View east, front side (Building 8 on right) ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. View east, front side (Building 8 on right) - Veterans Administration Center, Officers Duplex Quarters, 5302 East Kellogg (Legal Address); 5500 East Kellogg (Common Address), Wichita, Sedgwick County, KS

Subarctic weathering of mineral wastes provides a sink for atmospheric CO(2).

PubMed

Wilson, Siobhan A; Dipple, Gregory M; Power, Ian M; Barker, Shaun L L; Fallon, Stewart J; Southam, Gordon

2011-09-15

The mineral waste from some mines has the capacity to trap and store CO(2) within secondary carbonate minerals via the process of silicate weathering. Nesquehonite [MgCO(3)·3H(2)O] forms by weathering of Mg-silicate minerals in kimberlitic mine tailings at the Diavik Diamond Mine, Northwest Territories, Canada. Less abundant Na- and Ca-carbonate minerals precipitate from sewage treatment effluent deposited in the tailings storage facility. Radiocarbon and stable carbon and oxygen isotopes are used to assess the ability of mine tailings to trap and store modern CO(2) within these minerals in the arid, subarctic climate at Diavik. Stable isotopic data cannot always uniquely identify the source of carbon stored within minerals in this setting; however, radiocarbon isotopic data provide a reliable quantitative estimate for sequestration of modern carbon. At least 89% of the carbon trapped within secondary carbonate minerals at Diavik is derived from a modern source, either by direct uptake of atmospheric CO(2) or indirect uptake though the biosphere. Silicate weathering at Diavik is trapping 102-114 g C/m(2)/y within nesquehonite, which corresponds to a 2 orders of magnitude increase over the background rate of CO(2) uptake predicted from arctic and subarctic river catchment data.

Seismic evidence for silicate melt atop the 410-km mantle discontinuity

USGS Publications Warehouse

Revenaugh, Justin; Sipkin, S.A.

1994-01-01

LABORATORY results demonstrating that basic to ultrabasic melts become denser than olivine-rich mantle at pressures above 6 GPa (refs 1-3) have important implications for basalt petrogenesis, mantle differentiation and the storage of volatiles deep in the Earth. A density cross-over between melt and solid in the extensively molten Archaean mantle has been inferred from komatiitic volcanism and major-element mass balances, but present-day evidence of dense melt below the seismic low-velocity zone is lacking. Here we present mantle shear-wave impedance profiles obtained from multiple-ScS reverberation mapping for corridors connecting western Pacific subduction zone earthquakes with digital seismograph stations in eastern China, imaging a ~5.8% impedance decrease roughly 330 km beneath the Sea of Japan, Yellow Sea and easternmost Asia. We propose that this represents the upper surface of a layer of negatively buoyant melt lying on top of the olivine ??? ??- phase transition (the 410-km seismic discontinuity). Volatile-rich fluids expelled from the partial melt zone as it freezes may migrate upwards, acting as metasomatic agents and perhaps as the deep 'proto-source' of kimberlites. The remaining, dense, crystalline fraction would then concentrate above 410 km, producing a garnet-rich layer that may flush into the transition zone.

Isotopic constraints on the cooling of the continental lithosphere

NASA Astrophysics Data System (ADS)

Bedini, R.-M.; Blichert-Toft, J.; Boyet, M.; Albarède, F.

2004-06-01

A new model of continuous diffusion of radiogenic isotopes was applied to mineral 147Sm- 143Nd and 176Lu- 176Hf data on low-temperature garnet-peridotite xenoliths from Cretaceous South African kimberlites. The radiometric ages are younger than the Archean whole-rock Re-Os and U-Pb ages and reflect that both the Sm-Nd and Lu-Hf chronometric systems remained open under the thermal conditions of the lithospheric mantle. The radiogenic character of Hf in garnets, however, indicates that even if essentially no pyroxene remained immune to the effects of metasomatic events, the core of many garnets may preserve memory of the long history of this mineral in the subcontinental lithosphere. The cooling rates deduced from the garnet Sm-Nd ages in the South African lithosphere are fairly low (40-105 °C Gy -1), but compare well with values obtained on similar samples from different regions. These unexpectedly low values imply that the heat flow at the base of the subcontinental lithospheric mantle has changed only very slowly through time. They further support the recent suggestion that, as a result of viscous dissipation by plate bending, convection vigor and heat flow are to some extent decoupled, which argues against a thermal feedback on geodynamics. Modern convection may still be mining fossil heat stored in the lower mantle.

Aperçu de precambrien de côte d'Ivoire: geologie-metallogenie

NASA Astrophysics Data System (ADS)

Angoran, Y.; Kadio, E.

The Ivory Coast is situated at the southern limits of the West African Craton and constitute a part of the 'Dorsale de Man'. The precambrian rocks occupy 97% of the superficial area of the country and include rocks of two orogenic episodes: the Liberian (3000-2580 Ma) and the Eburnian of lower Proterozoic (2400-1550 Ma). Liberian Orogeny, which is the most ancient, consists of gneisses, amphibo-pyroxinites, fine-grained itabirites and coarse-grained ferruginous quartzites. The aluminous gneisses, amphibo-pyroxinites and ferruginous quartzites are supracrustals that have been transformed by a high grade Catasonal metamorphism resulting in highly folded rocks. The Liberian plutons are infracrustals consisting of complex basic and ultrabasic rocks, migmatites, charnockites and granites associated with magmatites. This Liberian complex is intruded by some dolerites (2200 Ma), and kimberlites with diamond (2210-2500 Ma) which have been eroded to produce Birrimian placer deposits of Tortiya and Birrim in Ghana. The eburnian geosyncline consists of alternating subparallel intrageosynclines and intrageanticlines. The volcano-sedimentary complexes were intruded by eburnian plutons of 2100-1550 Ma. About 20 different types of mineralisations are common within the Pre-Cambrian rocks of the Ivory Coast and they are of Archaen to lower Proterozoic age. Examples of these mineral concentrations are cited in this paper.

A New Global Model Of Plates Motion Over The Mantle For The Last 300MA: Link Between Mantle Structures, Volcanism and Plate Tectonics.

NASA Astrophysics Data System (ADS)

Jean, B.; Sophie, V. D. G.; Greff-Lefftz, M.; Frizon de Lamotte, D.; Lescanne, M.; Leparmentier, F.

2017-12-01

We compare several models of hot spot reference frames published in the litterature retracing the kinematics of the lithosphere over the mantle for the last 120Ma. We then propose a new model between 130 and 300Ma, based on the comparison of various surface indicators (geological, thermal data from boreholes and compilation of global surface volcanism), a reassessment of hot spots classification and paleomagnetic data. We discuss the implication of our model on the location and timing of several types of surface volcanism (subductions, intracontinental volcanism, rifting and LIPS, kimberlites) that we link to deep structures interpreted from tomographic images. A clear degree two permanent organization of mantle convection during this period of time is obvious, and the subduction rate appears to be episodic. We finally deduce from our model mantle TPW (True Polar Wander), the shifting of the entire mantle relative to the earth's spin axis over the last 300 million years. The inferred global motion of the mantle deduced occurs around a Euler pole which axis is close to the earth equator but varies significantly in longitude with respect to time showing complex tridimensional mass reorganizations in the mantle, probably linked to both LLSVPs and slabs effect.

Counselling Expectations of a Sample of East Asian and Caucasian Canadian Undergraduates in Canada

ERIC Educational Resources Information Center

Fowler, Darren M.; Glenwright, Brittni J.; Bhatia, Maneet; Drapeau, Martin

2011-01-01

This study investigated whether East Asians differ from Caucasian Canadians in their expectations about counselling. Participants in this study included 31 East Asian and 53 Caucasian Canadian university students. The East Asian participants were all first-generation East Asians living in Canada, originally from China, Korea, Japan, or Vietnam.…

Geochemical characteristics of Antarctic magmatism connected with Karoo-Maud and Kerguelen mantle plumes

NASA Astrophysics Data System (ADS)

Sushchevskaya, Nadezhda; Krymsky, Robert; Belyatsky, Boris; Antonov, Anton; Migdisova, Natalya

2013-04-01

Emplacement (130-115 m.y. ago) of dikes and sills of alkaline-ultrabasic composition within Jetty oasis (East Antarctica) is suggested as a later appearance of plume magmatism within the East-Antarctic Shield [Andronikov et al., 1993, 2001; Laiba et al., 1987]. This region is located opposite Kerguelen Islands and possibly could be properly connected with activity of the Kerguelen-plume [Foley et al., 2001, 2006]. Jurassic-Cretaceous dykes, stocks and sills of alkaline-ultrabasic rocks, relatively close to kimberlite-type, are exposed within Jetty oasis and on the southern shore of the Raddock Lake. This alkaline-ultrabasic magmatism has appeared to be connected with the main Mesozoic stage of the evolution of the Lambert and Amery glaciers riftogenic structure [Kurinin et al., 1980, 1988]. The alkaline-ultrabasic dikes and sills within Jetty oasis cut the rocks of the Beaver complex, Permo-Triassic terrigeneous successions of the Amery complex, and late Paleozoic low-alkaline basic dikes as well. Dashed chain of 6 stock bodies spread out on 15 km along the eastern shore of the Beaver Lake, marked their allocation with submeridianal zone of the deep cracks, boarded of the eastern side of the Beaver Lake trough. At the same time, new data upon Quaternary magmatism of the mountain Gaussberg has confirmed the unique features of ultra-potassium alkaline magmatism (up to 14-17% K2O) formed under exclusively continental conditions [Murphy et al., 2002]. Volcanic cone is located at the continuation of Gaussberg rift zone which is possibly a part of Lambert fracture zone. Its formation is connected with the early stages of Gondwana development, perhaps, reactivated in different Precambrian events and according to numerous data is a single rift zone which is traced Indian inland (Indrani graben, [Golynsky, 2011]). The time of lamproitic magmas eruption is estimated at 56000±5000 yeas ago [Tingey et al., 1983]. Earlier it had been shown the Mesozoic (about 170 Ma) basaltic dykes of the Schirmacher Oasis and basalts and dolerites of the Queen Maud Land (180 Ma) are identical in petrology and geochemistry terms and supposedly could be interpreted as the manifestation of the Karoo-Maud plume activity in Antarctica [Sushchevskaya et al., 2012]. The spatial distribution of the dikes indicates the eastward spreading of the plume material from DML to the Schirmacher Oasis within at least 10 Ma (up to ~35 Ma, taking into account the uncertainty of age determination). On the other hand, the considerable duration and multistage character of plume magmatism related to the activity of the Karoo-Maud plume in Antarctica and Africa [Leat et al., 2007; Luttinen et al., 2002] may indicate that the Mesozoic dikes of the oasis correspond to a single stage of plume magmatism. On the basis of obtained isotopic data it has been determined two magmatic melt evolution trends for basalts from: Queen Maud Land - Kerguelen Archipelago - Afanasy Nikitin Rise (Indian Ocean) and Jetty - Schirmacher oasises which mantle sources are quite different. Thus the Jetty - Schirmacher oasises magmatic melt sources are characterized by prevalence of the matter of moderately enriched or primitive chondritic mantle source and lithospheric mantle of Proterozoic ages but the substances of depleted mantle source similar to MORB-type and ancient mantle are absent. New data obtained on Nd, Sr, Pb isotopic and lithophile elements compositions of the alkaline-ultrabasic rocks from the Jetty oasis and Gaussberg volcano completed imagine of the Kerguelen-plume evolution. It has been confirmed unique character of the alkaline lamproiites of the Gaussberg volcano enrichments. Highly radiogenic Sr and Pb isotope ratios of these lamproiites reflect melting of the ancient sublithospheric depleted mantle which was stored from the Archean till nowadays unaffected by metasomatic-enrichment processes. During modern melting of this mantle part there is input of additional substances (crustal fluid of sediment origins, subducted sediments etc.) with high Rb/Sr ratio.

11. Interior view of first floor east administrative/support office block ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. Interior view of first floor east administrative/support office block looking north. - Manchester Airport, Large Hangar, East edge of airport between East Apron & Kelly Avenue, Manchester, Hillsborough County, NH

13. Interior view of second floor east administrative/support office block ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. Interior view of second floor east administrative/support office block looking north. - Manchester Airport, Large Hangar, East edge of airport between East Apron & Kelly Avenue, Manchester, Hillsborough County, NH

Current status of the East Sea Ecosystem in a changing world

NASA Astrophysics Data System (ADS)

Lee, Sang Heon; Kang, Chang-Keun; Lee, Chung IL; Kwak, Jung Hyun

2017-12-01

The East/Japan Sea (hereafter the East Sea) is changing quickly. Warming and structural changes in the East Sea have been reported by CREAMS, an acronym of ″Circulation Research of the East Asian Marginal Seas″, which began in 1993 as an international research program to understand the water mass structure and circulation in the East Sea (Kim and Kim, 1996; Kim, 1997; Kim et al., 2001, 2002). A subsequent research program of the EAST-I, an acronym of ″the East Asian Seas Time-series″, was launched by PICES (North Pacific Marine Science Organization) and financially supported by the Korean government, allowing us to deepen our knowledge about rapidly changing processes in the East Sea (Chang et al., 2010). Although there has been considerable progress in developing a mechanistic understanding of the East Sea ecosystem responses to disturbances, more comprehensive studies are needed to address the impacts of the frequency and intensity of disturbances on marine ecosystems. The most important question of the research has been: how do environmental changes affect structural and functional biodiversity? Recently launched research on ″Long-term change of structure and function in marine ecosystems of Korea″, which has been supported by the Korean government since 2011, has given an unprecedented insight into the ecosystem dynamics in the East Sea. It therefore seems an appropriate time to devote a special issue to the topic of ″Current status of the East Sea ecosystem in a changing world″.

Rivaroxaban for stroke prevention in East Asian patients from the ROCKET AF trial.

PubMed

Wong, Ka Sing Lawrence; Hu, Dai Yi; Oomman, Abraham; Tan, Ru-San; Patel, Manesh R; Singer, Daniel E; Breithardt, Günter; Mahaffey, Kenneth W; Becker, Richard C; Califf, Robert; Fox, Keith A A; Berkowitz, Scott D; Hacke, Werner; Hankey, Graeme J

2014-06-01

In Rivaroxaban Once Daily Oral Direct Factor Xa Inhibitor Compared With Vitamin K Antagonism for Prevention of Stroke and Embolism Trial in Atrial Fibrillation (ROCKET AF) trial, rivaroxaban was noninferior to dose-adjusted warfarin in preventing stroke or systemic embolism among patients with nonvalvular atrial fibrillation at moderate to high stroke risk. Because of differences in patient demographics, epidemiology, and stroke risk management in East Asia, outcomes and relative effects of rivaroxaban versus warfarin were assessed to determine consistency among East Asians versus other ROCKET AF participants. Baseline demographics and interaction of treatment effects of rivaroxaban and warfarin among patients within East Asia and outside were assessed. A total of 932 (6.5%) ROCKET AF participants resided in East Asia. At baseline, East Asians had lower weight, creatinine clearance, and prior vitamin K antagonist use; higher prevalence of prior stroke; and less congestive heart failure and prior myocardial infarction than other participants. Despite higher absolute event rates for efficacy and safety outcomes in East Asians, the relative efficacy of rivaroxaban (20 mg once daily; 15 mg once daily for creatinine clearance of 30-49 mL/min) versus warfarin with respect to the primary efficacy end point (stroke/systemic embolism) was consistent among East Asians and non-East Asians (interaction P=0.666). Relative event rates for the major or nonmajor clinically relevant bleeding in patients treated with rivaroxaban and warfarin were consistent among East Asians and non-East Asians (interaction P=0.867). Observed relative efficacy and safety of rivaroxaban versus warfarin were similar among patients within and outside East Asia. Rivaroxaban, 20 mg once daily, is an alternative to warfarin for stroke prevention in East Asians with nonvalvular atrial fibrillation. © 2014 American Heart Association, Inc.

48. AUXILIARY CHAMBER (EAST END), VIEW LOOKING EAST SHOWING ELECTRICAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

48. AUXILIARY CHAMBER (EAST END), VIEW LOOKING EAST SHOWING ELECTRICAL PENETRATION AND AIR LOCK (LOCATION GGG) - Shippingport Atomic Power Station, On Ohio River, 25 miles Northwest of Pittsburgh, Shippingport, Beaver County, PA

39. Attic, detail of builtin cabinet on interior east wall ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

39. Attic, detail of built-in cabinet on interior east wall supports - Veterans Administration Center, Officers Duplex Quarters, 5302 East Kellogg (Legal Address); 5500 East Kellogg (Common Address), Wichita, Sedgwick County, KS

East Java Maritime Connectivity and Its Regional Development Support

NASA Astrophysics Data System (ADS)

Purboyo, H.; Ibad, M. Z.

2017-07-01

The study presents an evolution of maritime connectivity index of East Java which is associated with accessibility and mobility index of regions in East Java. The findings show that East Java increased connectivity more than three times from 1996 to 2011. Initially, the East Java is importer but then become exporter to national territory. For accessibility, the inland regions of East Java in general is higher than the coastal areas. And for mobility, inland regions initially have a small index, but in subsequent years its index is greater than the coastal areas.

Efficacy and safety of apixaban compared with warfarin for stroke prevention in patients with atrial fibrillation from East Asia: a subanalysis of the Apixaban for Reduction in Stroke and Other Thromboembolic Events in Atrial Fibrillation (ARISTOTLE) Trial.

PubMed

Goto, Shinya; Zhu, Jun; Liu, Lisheng; Oh, Byung-Hee; Wojdyla, Daniel M; Aylward, Philip; Bahit, M Cecilia; Gersh, Bernard J; Hanna, Michael; Horowitz, John; Lopes, Renato D; Wallentin, Lars; Xavier, Denis; Alexander, John H

2014-09-01

The perceived risk of serious bleeding is an obstacle to the use of oral anticoagulation in East Asia. The efficacy and safety of apixaban in East Asian patients with atrial fibrillation are unknown. ARISTOTLE included 18,201 patients with nonvalvular atrial fibrillation randomized to apixaban 5mg twice daily or warfarin. The efficacy and safety of apixaban and warfarin among patients recruited from East Asia (n = 1,993) were compared with those recruited from outside East Asia (n = 16,208). Compared with warfarin, apixaban resulted in a consistent reduction in stroke or systemic embolism in East Asian (hazard ratio [HR] 0.74, 95% CI 0.50-1.10) and non-East Asian (HR 0.81, 95% CI 0.66-0.99) patients (interaction P = .70). Consistent benefits of apixaban over warfarin were also seen for major bleeding in East Asian (HR 0.53, 95% CI 0.35-0.80) and non-East Asian (HR 0.72, 95% CI 0.62-0.83) patients (interaction P = .17). There was a greater reduction in major or clinically relevant nonmajor bleeding with apixaban compared with warfarin in East Asian (HR 0.49, 95% CI 0.35-0.67) than in non-East Asian (HR 0.71, 95% CI 0.63-0.79) patients (interaction P = .03). Numerically higher rates of intracranial bleeding were seen in East Asian patients with warfarin but not with apixaban. Apixaban resulted in similar reductions in stroke or systemic embolism and major bleeding and greater reductions in major or clinically relevant nonmajor bleeding in patients from East Asia. Warfarin is associated with more intracranial bleeding, particularly in patients from East Asia. Copyright © 2014 Mosby, Inc. All rights reserved.

35. EAST FRONT OF POWERHOUSE AND CAR BARN: East front ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

35. EAST FRONT OF POWERHOUSE AND CAR BARN: East front of powerhouse and car barn. 'Annex' is right end of building. - San Francisco Cable Railway, Washington & Mason Streets, San Francisco, San Francisco County, CA

10. BUILDING: SECOND FLOOR (East Section), VIEW SOUTH: EAST, SOUTH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. BUILDING: SECOND FLOOR (East Section), VIEW SOUTH: EAST, SOUTH AND WEST WALLS OF COLD STORAGE, ALSO SHOWING REMNANTS OF COOLING PIPES - Boston Beer Company, 225-249 West Second Street, South Boston, Suffolk County, MA

29. SECOND FLOOR EAST SIDE APARTMENT EAST BEDROOM INTERIOR. ALUMINUMFRAME ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

29. SECOND FLOOR EAST SIDE APARTMENT EAST BEDROOM INTERIOR. ALUMINUM-FRAME SLIDING-GLASS WINDOWS ARE REPLACEMENTS. VIEW TO NORTHEAST. - Lee Vining Creek Hydroelectric System, Triplex Cottage, Lee Vining Creek, Lee Vining, Mono County, CA

3. East side, details of north half of east web; ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. East side, details of north half of east web; also details of roadway, railing and overhead bracing; looking northeast - Dodd Ford Bridge, County Road 147 Spanning Blue Earth River, Amboy, Blue Earth County, MN

East side, showing ruin of brownstone column capital that originally ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

East side, showing ruin of brownstone column capital that originally supported the east side portico, a feature that was destroyed in the 1886 earthquake - William Ravenel House, 13 East Battery Street, Charleston, Charleston County, SC

Inferring human history in East Asia from Y chromosomes.

PubMed

Wang, Chuan-Chao; Li, Hui

2013-06-03

East Asia harbors substantial genetic, physical, cultural and linguistic diversity, but the detailed structures and interrelationships of those aspects remain enigmatic. This question has begun to be addressed by a rapid accumulation of molecular anthropological studies of the populations in and around East Asia, especially by Y chromosome studies. The current Y chromosome evidence suggests multiple early migrations of modern humans from Africa via Southeast Asia to East Asia. After the initial settlements, the northward migrations during the Paleolithic Age shaped the genetic structure in East Asia. Subsequently, recent admixtures between Central Asian immigrants and northern East Asians enlarged the genetic divergence between southern and northern East Asia populations. Cultural practices, such as languages, agriculture, military affairs and social prestige, also have impacts on the genetic patterns in East Asia. Furthermore, application of Y chromosome analyses in the family genealogy studies offers successful showcases of the utility of genetics in studying the ancient history.

Inferring human history in East Asia from Y chromosomes

PubMed Central

2013-01-01

East Asia harbors substantial genetic, physical, cultural and linguistic diversity, but the detailed structures and interrelationships of those aspects remain enigmatic. This question has begun to be addressed by a rapid accumulation of molecular anthropological studies of the populations in and around East Asia, especially by Y chromosome studies. The current Y chromosome evidence suggests multiple early migrations of modern humans from Africa via Southeast Asia to East Asia. After the initial settlements, the northward migrations during the Paleolithic Age shaped the genetic structure in East Asia. Subsequently, recent admixtures between Central Asian immigrants and northern East Asians enlarged the genetic divergence between southern and northern East Asia populations. Cultural practices, such as languages, agriculture, military affairs and social prestige, also have impacts on the genetic patterns in East Asia. Furthermore, application of Y chromosome analyses in the family genealogy studies offers successful showcases of the utility of genetics in studying the ancient history. PMID:23731529

Paralysis at the Top of a Roaring Volcano: Israel and the Schooling of Palestinians in East Jerusalem

ERIC Educational Resources Information Center

Yair, Gad; Alayan, Samira

2009-01-01

Conflicts over East Jerusalem are often thought to reflect larger conflicts in the Middle East. In this article, the authors focus on schooling in East Jerusalem in order to provide a better appreciation of the protracted conflict in the area. This close examination of schooling in East Jerusalem can illuminate reasons for the political paralysis…

6. East portal of Bridge Number 210.52, contextual view to ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. East portal of Bridge Number 210.52, contextual view to east, 210mm lens. This structure underscores the inconsistencies with the railroad's use of 'east' and 'west' as opposed to actual direction; in this case the railroad 'east' end of the bridge faces actual west. - Southern Pacific Railroad Shasta Route, Bridge No. 210.52, Milepost 210.52, Tehama, Tehama County, CA

2. EAST END PLANT 5 POWERHOUSE AND EAST TAILRACE. STONE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EAST END PLANT 5 POWERHOUSE AND EAST TAILRACE. STONE RETAINING WALLS BEHIND POWERHOUSE DELINEATE FORMER RESIDENTIAL AREA. VIEW TO WEST ACROSS PLANT 6 INTAKE. - Bishop Creek Hydroelectric System, Plant 5, Bishop Creek, Bishop, Inyo County, CA

4. DETAIL VIEW OF TRIPLE TONGUE AND GROOVE CRIBBING USED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. DETAIL VIEW OF TRIPLE TONGUE AND GROOVE CRIBBING USED IN DAM CONSTRUCTION, NORTH EAST OF EAST DAM, LOOKING NORTH - Three Bears Lake & Dams, East Dam, North of Marias Pass, East Glacier Park, Glacier County, MT

12. VIEW EAST, ROUTE 30 EAST FROM ROUTE 130 SOUTH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. VIEW EAST, ROUTE 30 EAST FROM ROUTE 130 SOUTH ISLAND - White Horse Pike Rond Point, Intersection of Crescent Boulevard (U.S. Route 130), White Horse Pike (U.S. Route 30), & Clay Avenue, Collingswood, Camden County, NJ

Fractional ultrabasic-basic evolution of upper-mantle magmatism: Evidence from xenoliths in kimberlites, inclusions in diamonds and experiments

NASA Astrophysics Data System (ADS)

Litvin, Yuriy; Kuzyura, Anastasia

2017-04-01

Ultrabasic peridotites and pyroxenites together with basic eclogites are the upper-mantle in situ rocks among xenoliths in kimberlites. Occasionally their diamond-bearing varieties have revealed within the xenoliths. Therewith the compositions of rock-forming minerals demonstrate features characteristic for primary diamond-included minerals of peridotite and eclogite parageneses (the elevated contents of Cr-component in peridotitic garnets and Na-jadeitic component in eclogitic clinopyroxenes). High-pressure experimental study of melting equilibria on the multicomponent peridotie-pyroxenite system olivine Ol - orthopyroxene Opx - clinopyroxene Cpx - garnet Grt showed that Opx disappeared in the peritectic reaction Opx+L→Cpx (Litvin, 1991). As a result, the invariant peritectic equilibrium Ol+Opx+Cpx+Grt+L of the ultrabasic system was found to transform into the univariant cotectic assemblage Ol+Cpx+Grt+L. Further experimental investigation showed that olivine reacts with jadeitic component (Jd) with formation of garnet at higher 4.5 GPa (Gasparik, Litvin, 1997). Study of melting relations in the multicomponent system Ol - Cpx - Jd permits to discover the peritectic point Ol+Omph+Grt+L (where Omph - omphacitic clinopyroxene) at concentration 3-4 wt.% Jd-component in the system. The reactionary loss of Opx and Ol makes it possible to transform the 4-phase garnet lherzolite ultrabasic association into the bimineral eclogite assemblage. The regime of fractional Ol, Cpx and Grt crystallization must be accompanied by increasing content of jadeitic component in residual melts that causes the complete "garnetization of olivine". In the subsequent evolution, the melts would have to fractionate for basic SiO2-saturated compositions responsible for petrogenesis of eclogite varieties marked with accessory corundum Crn, kyanite Ky and coesite Coe. Both the peritectic mechanisms occur in regime of fractional crystallization. The sequence of the upper-mantle fractional ultrabasic-basic magmatic evolution and petrogenesis may be controlled by the following melting relations: from Ol, Opx, L field to cotectic curve Ol, Opx, Cpx, L, peritectic point Ol, Opx, Cpx, Grt, L (loss of Opx), cotectic curve Ol, (Cpx+Jd), Grt, L, peritectic point Ol, (Cpx→Omph), Grt, L (loss of Ol), divariant field Omph,Grt,L, cotectic curve Ky, Omph, Grt, L, eutectic point Ky,Coe,Omph, Grt,L, subsolidus assemblage Ky,Coe,Omph, Grt. The fractional ultrabasic-basic evolution of the upper-mantle silicate-carbonate-carbon melts-solutions, which are responsible for genesis of diamond-and-inclusions associations and diamond-bearing peridotites and eclogites, follows the similar physico-chemical mechanisms (Litvin et al., 2016). This is illustrated by fractional syngenesis diagram for diamonds and associated minerals which construction is based on evidence from high pressure experiments. References Gasparik T., Litvin Yu.A (1997). Stability of Na2Mg2Si2O7 and melting relations on the forsterite - jadeite join at pressures up to 22 GPa. Eur, J. Mineral. 9(2), 311-326. Litvin Yu.A. (1991). Physico-Chemical Study of Melting of Materials from the Deep Earth. Moscow: Nauka. 312 p. Litvin Yu.A., Spivak A.V., Kuzyura A.V. (2016). Fundamentals of the mantle-carbonatite concept of diamond genesis, Geochemistry Internat. 34(10), 839-857.

Polar amplification of the early Eocene indicated by δ2H values of lignin methoxyl groups of mummified wood

NASA Astrophysics Data System (ADS)

Anhäuser, Tobias; Hook, Benjamin; Halfar, Jochen; Greule, Markus; Keppler, Frank

2017-04-01

A number of well-preserved mummified wood samples have been excavated during diamond mining operations in early Eocene (55-50 Ma) kimberlite deposits located near the Arctic Circle (64° N, 110° W) in the Canadian Northwest Territories. The preserved wood, containing multi-decadal length tree-ring information, therefore allows the reconstruction of an unprecedented snapshot of terrestrial high-latitude climate during the early Eocene. Here we used wood-derived stable hydrogen isotopes (δ2H) as proxy for paleoclimatic interpretations. While cellulose extractions are commonly used for the analysis of modern wood-derived δ2H values, the mummified wood samples had been affected by selective degradation leading to a strong or even complete loss of cellulose while leaving a lignin-rich material behind. We have therefore analyzed δ2H values of the lignin methoxyl groups that have previously been shown to reflect the δ2H values of the local precipitation and can thus be used to infer paleoclimate information such as temperature changes. We applied this proxy to specimens found in three adjacent kimberlite pipes (30 km apart) which represent a range of early Eocene ages (Rb/Sr dating: 55.5 ± 0.7, 55.2 ± 0.3 and 53.3 ± 0.6 Ma [2σ standard deviation]). The δ2H values were measured at annual resolution for the three mummified wood series (length of individual time series: 82, 62 and 40 years) and the mean δ2H value of precipitation for the three decadal-scale time slices was reconstructed. Finally, we used existing relationships between early Eocene temperatures and stable isotopes in precipitation to quantify temperature changes. Warming phases such as the one covered here (culminating in the Early Eocene Climatic Optimum [52 to 50 Ma]) are commonly accompanied by a stronger increase in arctic/subarctic surface air temperatures in comparison to the global average (the ratio of these temperature differences is referred to as the polar amplification). Our estimation shows for the period between 55.5 and 53.3 Ma a mean subarctic temperature increase of 7.3 ± 3.7 °C. Globally, for the same period, a mean temperature increase of 1.5 °C has previously been derived from the δ18O values of benthic foraminifera. This suggests a polar amplification with a magnitude of 5 (±3). Despite uncertainties regarding both the age determination and the temperature reconstructions, the magnitude of our estimation is broadly in line with polar amplifications estimated for other Cenozoic global warming intervals, which have shown magnitudes of 3 to 4. Even though occurring on a much shorter time scale, the current global warming shows a similar polar amplification pattern as post industrial revolution Arctic temperatures, which are projected to amplify significantly in the near future, have already increased up to 3 °C as compared to a lower latitude temperature increase of 1 °C.

11. OBLIQUE VIEW OF EAST TRUSS AND EAST SIDE OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. OBLIQUE VIEW OF EAST TRUSS AND EAST SIDE OF SOUTH ABUTMENT, SEEN FROM SOUTH BANK OF WINTER'S RUN. - Mitchell's Mill Bridge, Spanning Winter's Run on Carrs Mill Road, west of Bel Air, Bel Air, Harford County, MD

Perspective view looking from the east to the east northeast ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Perspective view looking from the east to the east northeast facade, with Swiss Chalet in background, to replicate the view shown in MD-1109-J-18 - National Park Seminary, Japanese Pagoda, 2805 Linden Lane, Silver Spring, Montgomery County, MD

10. EAST SIDE CANAL Photographic copy of historic photo, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. EAST SIDE CANAL - Photographic copy of historic photo, December 3, 1940 (original print in '1940 Annual Report of the Carlsbad Project,' located at the Carlsbad Irrigation District offices, Carlsbad, New Mexico) photographer unknown 'LOOKING DOWN FROM STA. #22 LATERAL #8, EAST CANAL. AFTER CCC ENROLLEES FINISHED ROCK LINING' - Carlsbad Irrigation District, East Side Canal, 1 mile North to 2 miles East of Carlsbad, Carlsbad, Eddy County, NM

9. EAST SIDE CANAL Photographic copy of historic photo, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. EAST SIDE CANAL - Photographic copy of historic photo, September 17, 1940 (original print in '1940 Annual Report of the Carlsbad Project,' located at the Carlsbad Irrigation District offices, Carlsbad, New Mexico) photographer unknown 'CCC ENROLLEES STARTING EXCAVATION FOR ROCK LINING DOWNSTREAM FROM STA. 22. EAST CANAL, LAT. #8' - Carlsbad Irrigation District, East Side Canal, 1 mile North to 2 miles East of Carlsbad, Carlsbad, Eddy County, NM

1. AERIAL VIEW OF SHOPS COMPLEX LOOKING EAST SHOWING WEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. AERIAL VIEW OF SHOPS COMPLEX LOOKING EAST SHOWING WEST AND EAST ROUNDHOUSES, FROG AND SWITCH SHOP, AND MACHINE SHOP. - Baltimore & Ohio Railroad, Martinsburg Repair Shops, West Side of Tuscarora Creek Opposite East End of Race Street, Martinsburg, Berkeley County, WV

The Dispersal of East Gondwana from Continental Breakup to the Start of the Cretaceous Quiet Zone

NASA Astrophysics Data System (ADS)

Davis, J. K.; Lawver, L. A.; Norton, I. O.; Gahagan, L.

2014-12-01

Existing plate models for the breakup of Africa and East Gondwana (Australia, East Antarctica, India, Madagascar, the Seychelles, and Sri Lanka) are problematic and require revision. Specific problems include the utilization of dubious Gondwana configurations, improbable plate motion, and/or a failure to satisfy the holistic marine magnetic anomaly data. I present here a new model for the breakup of East Gondwana. This new model begins from a constrained, pre-breakup, Gondwana configuration. Out of this initial "tight-fit" configuration, East Gondwana rifts from West Gondwana (Africa & South America) as a cohesive unit. During this breakup and subsequent seafloor spreading, East Gondwana is devoid of any internal compression or anomalous plate motion. The overall motion of East Gondwana is constrained by seafloor spreading in the coeval Somali Basin and Mozambique/Riiser Larsen Basins. Seafloor spreading in these basins is modeled using existing marine magnetic anomaly interpretations and satellite-derived gravity data. Our model is uniquely able to satisfy the magnetic anomaly observations in both of the aforementioned basins without invoking improbable plate motion or configurations. Additionally, our plate model provides valuable insight into the breakup of India and East Antarctica. In this model, we fix India to Madagascar from breakup to 90 Ma, thus eventual separation between India and East Antarctica is an output, not an input of our model. We suggest that this separation occurred diachronously from ~140 Ma in the east to ~120 Ma in the west. This modeled motion between India and East Antarctica agrees well with geophysical observations from the margin of East Antarctica and our preliminary analysis of margin character and variability.

Cancer control programs in East Asia: evidence from the international literature.

PubMed

Moore, Malcolm A

2014-07-01

Cancer is a major cause of mortality and morbidity throughout the world, including the countries of North-East and South-East Asia. Assessment of burden through cancer registration, determination of risk and protective factors, early detection and screening, clinical practice, interventions for example in vaccination, tobacco cessation efforts and palliative care all should be included in comprehensive cancer control programs. The degree to which this is possible naturally depends on the resources available at local, national and international levels. The present review concerns elements of cancer control programs established in China, Taiwan, Korea, and Japan in North-East Asia, Viet Nam, Thailand, Malaysia, and Indonesia as representative larger countries of South-East Asia for comparison, using the published literature as a guide. While major advances have been made, there are still areas which need more attention, especially in South-East Asia, and international cooperation is essential if standard guidelines are to be generated to allow effective cancer control efforts throughout the Far East. Cancer is a major cause of mortality and morbidity throughout the world, including the countries of North-East and South-East Asia. Assessment of burden through cancer registration, determination of risk and protective factors, early detection and screening, clinical practice, interventions for example in vaccination, tobacco cessation efforts and palliative care all should be included in comprehensive cancer control programs. The degree to which this is possible naturally depends on the resources available at local, national and international levels. The present review concerns elements of cancer control programs established in China, Taiwan, Korea, and Japan in North-East Asia, Viet Nam, Thailand, Malaysia, and Indonesia as representative larger countries of South-East Asia for comparison, using the published literature as a guide. While major advances have been made, there are still areas which need more attention, especially in South-East Asia, and international cooperation is essential if standard guidelines are to be generated to allow effective cancer control efforts throughout the Far East.

VIEW SOUTHWEST, NORTH AND EAST SIDE OF OFFICE BUILDING, EAST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW SOUTHWEST, NORTH AND EAST SIDE OF OFFICE BUILDING, EAST SIDE OF FOSTER HANGAR AND FRANCIS HANGAR, AND NORTH SIDE OF DAVIS HANGAR AND METAL STORAGE HANGAR - Capital City Airport, Francis Aviation, North side of Grand River Avenue, Lansing, Ingham County, MI

33 CFR 162.255 - Wrangell Narrows, Alaska; use, administration, and navigation.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Channel Buoy 1 TC. East of Tow Channel Buoy 3 TC. West of Tow Channel Buoy 4 TC. East of Colorado Reef... Tow Channel Buoy 5 TC. East of Tow Channel Buoy 7 TC. West of Petersburg: East of Wrangell Narrows...

7. GENERAL VIEW EAST FROM ROOFTOP OF POPLAR FOREST TOWARDS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. GENERAL VIEW EAST FROM ROOFTOP OF POPLAR FOREST TOWARDS SUMMER KITCHEN (FOREGROUND) AND DAIRY; CHIMNEY OF SOUTH TENANT HOUSE BARELY VISIBLE THROUGH TREES; EAST PRIVY RARELY VISIBLE OVER EAST MOUND (1987) - Poplar Forest, Summer Kitchen, State Route 661, Forest, Bedford County, VA

Assessing the contributions of East African and West Pacific warming to the 2014 boreal spring East African drought

USGS Publications Warehouse

Funk, Christopher C.; Shukla, Shraddhanand; Hoell, Andrew; Livneh, Ben

2015-01-01

Anthropogenic warming contributed to the 2014 East African drought by increasing East African and west Pacific temperatures, and increasing the gradient between standardized western and central Pacific SST causing reduced rainfall, evapotranspiration, and soil moisture.

33 CFR 162.255 - Wrangell Narrows, Alaska; use, administration, and navigation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Channel Buoy 1 TC. East of Tow Channel Buoy 3 TC. West of Tow Channel Buoy 4 TC. East of Colorado Reef... Tow Channel Buoy 5 TC. East of Tow Channel Buoy 7 TC. West of Petersburg: East of Wrangell Narrows...

1. Photocpy of early 20th century photograph, looking east, of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Photocpy of early 20th century photograph, looking east, of east facade of assembly building on Euclid Ave. Photo owned by the Cleveland Public Library. - Ford Motor Company, Cleveland Branch Assembly Plant, Euclid Avenue & East 116th Street, Cleveland, Cuyahoga County, OH

Middle East respiratory syndrome: knowledge to date.

PubMed

Alsolamy, Sami

2015-06-01

To provide a conceptual and clinical review of Middle East respiratory syndrome. Peer-reviewed articles were identified through searches of PubMed using the terms "Middle East respiratory syndrome," "coronavirus respiratory illness in Saudi Arabia," and "novel (beta) coronavirus and human coronavirus Erasmus Medical Center". In addition, articles were searched on the websites of the World Health Organization and the U.S. Centers for Disease Control and Prevention using the terms "Middle East respiratory syndrome" and "novel coronavirus in Middle East." The reference lists of these articles and relevant review articles were also reviewed. Final references were selected for inclusion in the review on the basis of their relevance. The emerging Middle East respiratory syndrome coronavirus causes severe pulmonary disease with multiorgan involvement and a high fatality rate. Within months after its emergence, Middle East respiratory syndrome coronavirus was reported in several countries worldwide in people who had traveled from the Middle East. Middle East respiratory syndrome coronavirus is considered a zoonotic virus that has crossed the species barrier to humans, but the pathogenesis and the routes of transmission are not completely understood. There is currently no recommended treatment for Middle East respiratory syndrome coronavirus, although supportive treatment has played an important role. This syndrome has raised global public health concerns about the dissemination of an emerging infectious disease and highlights the need for a coordinated global response to contain such a disease threat.

Assessment of conventional oil resources of the East African Rift Province, East Africa, 2016

USGS Publications Warehouse

Brownfield, Michael E.; Schenk, Christopher J.; Klett, Timothy R.; Mercier, Tracey J.; Gaswirth, Stephanie B.; Marra, Kristen R.; Finn, Thomas M.; Le, Phuong A.; Leathers-Miller, Heidi M.

2017-03-27

Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 13.4 billion barrels of oil and 4.6 trillion cubic feet of gas in the East African Rift Province of east Africa.

75 FR 15426 - East Tennessee Natural Gas, LLC; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-29

...] East Tennessee Natural Gas, LLC; Notice of Application March 22, 2010. Take notice that on March 8, 2010, East Tennessee Natural Gas, LLC (East Tennessee), 5400 Westheimer Court, Houston, Texas 77056... Natural Gas Act (NGA) for authorization to: (i) Install an approximately 8.4-mile, 24-inch diameter...

Karaoke and Interpersonal Communication in East Asia.

ERIC Educational Resources Information Center

Ma, Ringo

An exploratory study investigated the interpersonal meaning of karaoke to its participants in East Asia. Current research suggests that the popularity of karaoke in East Asia is associated with the cultural value of harmony and the indirect mode of communication in this region. Subjects, 51 East Asian undergraduate-level students who had…

6. VIEW OF NORTH END OF EAST DAM, LOOKING SOUTH. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. VIEW OF NORTH END OF EAST DAM, LOOKING SOUTH. (View is taken from lakeside with lowered water level. This view encompasses the same area as MT-88-A-5 above.) - Three Bears Lake & Dams, East Dam, North of Marias Pass, East Glacier Park, Glacier County, MT

4. View of Clovelley Farm tenant house, back side (east) ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. View of Clovelley Farm tenant house, back side (east) area of two room addition. Note dark metal heating oil tank against rear wall and silver maple trees to shade house from south and east. - Clovelley Farm Tenant House, 4958 Paris Road (east side), Paris, Bourbon County, KY

Research on energy strategy and Chinese energy investment in the middle east

NASA Astrophysics Data System (ADS)

Huang, Yiling

2017-08-01

The Middle East is a key node of “One Belt and One Road strategy”. Energy investment is an important part of Chinese investment in the Middle East. The political turmoil in the Middle East has brought the political risks to Chinese investors. In the future, with the globalization of Chinese resource distribution and the expansion of Chinese outward investment, it is significant for China to ensure its energy security. Based on the analysis of the situation of Chinese energy strategy in the Middle East, this paper tries to put forward some suggestion about Chinese energy investment in the Middle East in order to protect Chinese energy security effectively.

[The trend and prospect of studies of East Asian medical history in Korea].

PubMed

Sihn, Kyuhwan

2010-06-30

Studies of East Asian medical history in Korea have progressively accumulated in the last twenty years. First, Korean scholars broadened the focus of research from China-centered research to East Asian research. Studies of Toyo medical history in Korea mainly concentrated on Chinese medical history. Toyo medical history originated from Japanese orientalism and imperialism. Today the studies of East Asian medical history in Korea include Korea, China and Japan, and attempt to deal with East Asia as a single conceptual category. Second, researchers in East Asian medical history are steadily increasing. They study Chinese medical history or Japanese medical history from universities. As they continue their research in academic positions, successive researchers emerge. Third, the number of Korean scholars remains relatively small, but they pursue original research. Their interests are in the discourse of East Asian medical history, colonial modernity, environmental history, oral history, and history of disease.

77 FR 75701 - Landisville Railroad, LLC-Operation Exemption-Buckeye East Chicago Railroad LLC

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-21

... Railroad, LLC--Operation Exemption--Buckeye East Chicago Railroad LLC Landisville Railroad, LLC... operate approximately 7,065 feet (1.34 miles) of track,\\1\\ existing railroad right-of-way, and bulk liquid transloading facilities owned by Buckeye East Chicago Railroad, LLC, a Class III rail carrier, in East Chicago...

78 FR 53744 - East Tennessee Natural Gas, LLC; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-30

...] East Tennessee Natural Gas, LLC; Notice of Application Take notice that on August 14, 2013, East Tennessee Natural Gas, LLC (East Tennessee), 5400 Westheimer Court, Houston, Texas 77056-5310, filed an application pursuant to Section 7(b) and 7(c) of the Natural Gas Act (NGA) and Part 157 of the Commission's...

View from northeast of Car Shop showing east wall and ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

View from northeast of Car Shop showing east wall and north end; also a portion of (east facade) of Foundry building. Structure between houses the boilers and stationary steam engine - East Broad Top Railroad & Coal Company, State Route 994, West of U.S. Route 522, Rockhill Furnace, Huntingdon County, PA

India’s British Army: the Honorable East India Company’s Lasting Military Impact

DTIC Science & Technology

2017-06-09

Company’s critical events ....................................3 Figure 2. The East India Company’s Administrative Structure ...26 Figure 3. The East India Company’s Administrative Structure ......................................35 1 CHAPTER 1...sustainment (Bryant 1985, 468). Figure 2. The East India Company’s Administrative Structure . Source: Kaushik Roy, “Military Synthesis in

RAND's Impact in the Middle East. Corporate Publication

ERIC Educational Resources Information Center

RAND Corporation, 2015

2015-01-01

The RAND Corporation works throughout the Middle East to analyze complex policy problems and help policymakers create enduring solutions. RAND's work in the Middle East focuses on the issues that drive economic development. This brief report provides an overview of RAND's impact in the Middle East in the areas of supporting youth, health and…

7 CFR 905.16 - Regulation Area II.

Code of Federal Regulations, 2011 CFR

2011-01-01

... counties to the Southwest corner of Section 23, Township 14 South, Range 31 East; thence continue South to the Southwest corner of Section 35, Township 14 South, Range 31 East; thence East to the Northwest corner of Township 15 South, Range 32 East; thence South to the Southwest corner of Township 17 South...

27 CFR 9.39 - Paicines.

Code of Federal Regulations, 2010 CFR

2010-04-01

.... The beginning point is the northwestern-most point of the proposed area at Township 14 South, Range 6... beginning point the boundary runs east along the north border of Sections 3, 2, and 1, Township 14 South, Range 6 East; (2) Thence south along the east border of Section 1, Township 14 South, Range 6 East...

27 CFR 9.39 - Paicines.

Code of Federal Regulations, 2011 CFR

2011-04-01

.... The beginning point is the northwestern-most point of the proposed area at Township 14 South, Range 6... beginning point the boundary runs east along the north border of Sections 3, 2, and 1, Township 14 South, Range 6 East; (2) Thence south along the east border of Section 1, Township 14 South, Range 6 East...

76 FR 81924 - East Cheyenne Gas Storage, LLC; Notice of Amendment

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-29

... Gas Storage, LLC; Notice of Amendment Take notice that on December 16, 2011, East Cheyenne Gas Storage... the West Peetz Field of its East Cheyenne Gas Storage Project to a maximum bottom-hole pressure of 2..., East Cheyenne Gas Storage, LLC, 10370 Richmond Avenue, Suite 510, Houston, Texas 77042, by Telephone...

Broadband Access for Students at East Tennessee State University

ERIC Educational Resources Information Center

Sawyer, Thomas Scott

2013-01-01

The purpose of this study was to determine the availability of Internet access for students attending East Tennessee State University during the fall semester 2013. It has been unknown to what degree broadband access is available in the East Tennessee State University service area that includes counties in East Tennessee, Southwest Virginia, and…

77 FR 28253 - Safety Zone; America's Cup World Series, East Passage, Narragansett Bay, RI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-14

...-AA00 Safety Zone; America's Cup World Series, East Passage, Narragansett Bay, RI AGENCY: Coast Guard... navigable waters of the East Passage, Narragansett Bay, Rhode Island, during the America's Cup World Series... rulemaking (NPRM) entitled ``Safety Zones; America's Cup World Series, East Passage, Narragansett Bay, RI...

75 FR 2896 - Order of Suspension of Trading; East Delta Resources Corp.

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-19

... SECURITIES AND EXCHANGE COMMISSION [File No. 500-1] Order of Suspension of Trading; East Delta... trading in the securities of East Delta. Therefore, it is ordered, pursuant to Section 12(k) of the Securities Exchange Act of 1934, that trading in the securities of East Delta is suspended for the period...

The Geology of East Butte, a Rhyolitic Volcanic Dome on the Eastern Snake River Plain, Idaho

NASA Technical Reports Server (NTRS)

Bretches, J. E.; King, J. S.

1985-01-01

East Butte is a prominent volcanic dome located on the eastern Snake River Plain. It is situated 51 km west of Idaho Fallls in the southeast corner of the Idaho National Engineering facility. East Butte rises 350 meters above the Quaternary basalt flows which encircle its 2.4 kilometer diameter base. Its maximum elevation is 2003 meters above sea level. East Butte is composed dominantly of rhyolite. Armstrong and others (1975) determined a K-Ar age of 0.6 +/- m.y. for a rhyolite sample from East Butte. Detailed geologic mapping revealed East Butte to be a single, large cumulo-dome composed dominantly of rhyolite. Major element geochemical analyses indicate that the rhyolite of East Butte is mildly peralkaline (molecular excess of Na2O and K2O over Al2O3 and compositionally homogeneous. Color variations in the East Butte rhyolite result from varying amounts of chemical and physical weathering and to the degree of devitrification that the glass in the groundmass of the rhyolite underwent.

Simulated East-west differences in F-region peak electron density at Far East mid-latitude region

NASA Astrophysics Data System (ADS)

Ren, Zhipeng; Zhao, Biqiang; Wan, Weixing; Liu, Libo

2017-04-01

In the present work, using Three-Dimensional Theoretical Ionospheric Model of the Earth in Institute of Geology and Geophysics, Chinese Academy of Sciences (TIME3D-IGGCAS), we simulated the east-west differences in Fregion peak electron density (NmF2) at Far East mid-latitude region.We found that, after removing the longitudinal variations of neutral parameters, TIME3D-IGGCAS can better represent the observed relative east-west difference (Rew) features. Rew is mainly negative (West NmF2 > East NmF2) at noon and positive (East NmF2 >West NmF2) at evening-night. The magnitude of daytime negative Rew is weak at local winter and strong at local summer, and the daytime Rew show two negative peaks around two equinoxes. With the increasing of solar flux level, the magnitude of Rew mainly become larger, and two daytime negative peaks slight shifts to June Solstice. With the decreasing of geographical latitude, Rew mainly become positive, and two daytime negative peaks slight shifts to June Solstice. Our simulation also suggested that the thermospheric zonal wind combined with the geomagnetic field configuration play a pivotal role in the formation of the ionospheric east-west differences at Far East midlatitude region.

Simulated East-west differences in F-region peak electron density at Far East mid-latitude region

NASA Astrophysics Data System (ADS)

Ren, Z.; Wan, W.

2017-12-01

In the present work, using Three-Dimensional Theoretical Ionospheric Model of the Earth in Institute of Geology and Geophysics, Chinese Academy of Sciences (TIME3D-IGGCAS), we simulated the east-west differences in Fregion peak electron density (NmF2) at Far East mid-latitude region.We found that, after removing the longitudinal variations of neutral parameters, TIME3D-IGGCAS can better represent the observed relative east-west difference (Rew) features. Rew is mainly negative (West NmF2 > East NmF2) at noon and positive (East NmF2 >West NmF2) at evening-night. The magnitude of daytime negative Rew is weak at local winter and strong at local summer, and the daytime Rew show two negative peaks around two equinoxes. With the increasing of solar flux level, the magnitude of Rew mainly become larger, and two daytime negative peaks slight shifts to June Solstice. With the decreasing of geographical latitude, Rew mainly become positive, and two daytime negative peaks slight shifts to June Solstice. Our simulation also suggested that the thermospheric zonal wind combined with the geomagnetic field configuration play a pivotal role in the formation of the ionospheric east-west differences at Far East midlatitude region.

Human migration through bottlenecks from Southeast Asia into East Asia during Last Glacial Maximum revealed by Y chromosomes.

PubMed

Cai, Xiaoyun; Qin, Zhendong; Wen, Bo; Xu, Shuhua; Wang, Yi; Lu, Yan; Wei, Lanhai; Wang, Chuanchao; Li, Shilin; Huang, Xingqiu; Jin, Li; Li, Hui

2011-01-01

Molecular anthropological studies of the populations in and around East Asia have resulted in the discovery that most of the Y-chromosome lineages of East Asians came from Southeast Asia. However, very few Southeast Asian populations had been investigated, and therefore, little was known about the purported migrations from Southeast Asia into East Asia and their roles in shaping the genetic structure of East Asian populations. Here, we present the Y-chromosome data from 1,652 individuals belonging to 47 Mon-Khmer (MK) and Hmong-Mien (HM) speaking populations that are distributed primarily across Southeast Asia and extend into East Asia. Haplogroup O3a3b-M7, which appears mainly in MK and HM, indicates a strong tie between the two groups. The short tandem repeat network of O3a3b-M7 displayed a hierarchical expansion structure (annual ring shape), with MK haplotypes being located at the original point, and the HM and the Tibeto-Burman haplotypes distributed further away from core of the network. Moreover, the East Asian dominant haplogroup O3a3c1-M117 shows a network structure similar to that of O3a3b-M7. These patterns indicate an early unidirectional diffusion from Southeast Asia into East Asia, which might have resulted from the genetic drift of East Asian ancestors carrying these two haplogroups through many small bottle-necks formed by the complicated landscape between Southeast Asia and East Asia. The ages of O3a3b-M7 and O3a3c1-M117 were estimated to be approximately 19 thousand years, followed by the emergence of the ancestors of HM lineages out of MK and the unidirectional northward migrations into East Asia.

Seroprevalence and molecular epidemiology of EAST1 gene-carrying Escherichia coli from diarrheal patients and raw meats.

PubMed

Sukkua, Kannika; Manothong, Somruthai; Sukhumungoon, Pharanai

2017-03-31

Several Escherichia coli pathotypes have been reported in Thailand; however, information on enteroaggregative heat-stable enterotoxin 1 (EAST1)-carrying E. coli (EAST1-EC) is insufficient. Previous reports show that consumption of raw meats causes diarrheagenic E. coli infections. In this study, we investigated the seroprevalence and genetic relationship of EAST1-EC from clinical and raw meat samples. Diarrheal patients and raw meat samples were investigated for the presence of EAST1-EC by performing polymerase chain reaction (PCR) to detect astA. Serotyping, antimicrobial susceptibility tests, and PCR-based phylogenetic group assay were performed. Molecular epidemiology of E. coli strains from clinical and raw meat samples was determined using repetitive element-PCR typing, BOX-PCR, and ERIC2-PCR. Results showed that 11.2% (17/152) of clinical samples and 53.3% (16/30) of raw meat samples had EAST1-EC. In all, 24 and 36 EAST1-EC strains were successfully isolated from 17 clinical and 16 raw meat samples, respectively. These strains had astA but did not possess the indicative genes of other E. coli pathotypes and were therefore classified as EAST1-EC. Most of these strains were multidrug resistant and were classified into nine serogroups. Molecular genotyping showed identical DNA fingerprint among EAST1-EC serotype O15 strains from clinical and raw chicken samples, suggesting that they were derived from the same bacterial clone. Our results indicated a high prevalence of multidrug-resistant EAST1-EC strains in clinical and environmental samples in Thailand belonging to nine serogroups. Moreover, the study highlighted the close association between infections caused by EAST1-EC serotype O15 and raw meat consumption.

Enhancement of seasonal prediction of East Asian summer rainfall related to western tropical Pacific convection

NASA Astrophysics Data System (ADS)

Lee, Doo Young; Ahn, Joong-Bae; Yoo, Jin-Ho

2015-08-01

The prediction skills of climate model simulations in the western tropical Pacific (WTP) and East Asian region are assessed using the retrospective forecasts of seven state-of-the-art coupled models and their multi-model ensemble (MME) for boreal summers (June-August) during the period 1983-2005, along with corresponding observed and reanalyzed data. The prediction of summer rainfall anomalies in East Asia is difficult, while the WTP has a strong correlation between model prediction and observation. We focus on developing a new approach to further enhance the seasonal prediction skill for summer rainfall in East Asia and investigate the influence of convective activity in the WTP on East Asian summer rainfall. By analyzing the characteristics of the WTP convection, two distinct patterns associated with El Niño-Southern Oscillation developing and decaying modes are identified. Based on the multiple linear regression method, the East Asia Rainfall Index (EARI) is developed by using the interannual variability of the normalized Maritime continent-WTP Indices (MPIs), as potentially useful predictors for rainfall prediction over East Asia, obtained from the above two main patterns. For East Asian summer rainfall, the EARI has superior performance to the East Asia summer monsoon index or each MPI. Therefore, the regressed rainfall from EARI also shows a strong relationship with the observed East Asian summer rainfall pattern. In addition, we evaluate the prediction skill of the East Asia reconstructed rainfall obtained by hybrid dynamical-statistical approach using the cross-validated EARI from the individual models and their MME. The results show that the rainfalls reconstructed from simulations capture the general features of observed precipitation in East Asia quite well. This study convincingly demonstrates that rainfall prediction skill is considerably improved by using a hybrid dynamical-statistical approach compared to the dynamical forecast alone.

Seasonal prediction of East Asian summer rainfall using a multi-model ensemble system

NASA Astrophysics Data System (ADS)

Ahn, Joong-Bae; Lee, Doo-Young; Yoo, Jin‑Ho

2015-04-01

Using the retrospective forecasts of seven state-of-the-art coupled models and their multi-model ensemble (MME) for boreal summers, the prediction skills of climate models in the western tropical Pacific (WTP) and East Asian region are assessed. The prediction of summer rainfall anomalies in East Asia is difficult, while the WTP has a strong correlation between model prediction and observation. We focus on developing a new approach to further enhance the seasonal prediction skill for summer rainfall in East Asia and investigate the influence of convective activity in the WTP on East Asian summer rainfall. By analyzing the characteristics of the WTP convection, two distinct patterns associated with El Niño-Southern Oscillation developing and decaying modes are identified. Based on the multiple linear regression method, the East Asia Rainfall Index (EARI) is developed by using the interannual variability of the normalized Maritime continent-WTP Indices (MPIs), as potentially useful predictors for rainfall prediction over East Asia, obtained from the above two main patterns. For East Asian summer rainfall, the EARI has superior performance to the East Asia summer monsoon index or each MPI. Therefore, the regressed rainfall from EARI also shows a strong relationship with the observed East Asian summer rainfall pattern. In addition, we evaluate the prediction skill of the East Asia reconstructed rainfall obtained by hybrid dynamical-statistical approach using the cross-validated EARI from the individual models and their MME. The results show that the rainfalls reconstructed from simulations capture the general features of observed precipitation in East Asia quite well. This study convincingly demonstrates that rainfall prediction skill is considerably improved by using a hybrid dynamical-statistical approach compared to the dynamical forecast alone. Acknowledgements This work was carried out with the support of Rural Development Administration Cooperative Research Program for Agriculture Science and Technology Development under grant project PJ009353 and Korea Meteorological Administration Research and Development Program under grant CATER 2012-3100, Republic of Korea.

Fatality risks for nosocomial outbreaks of Middle East respiratory syndrome coronavirus in the Middle East and South Korea.

PubMed

Sha, Jianping; Li, Yuan; Chen, Xiaowen; Hu, Yan; Ren, Yajin; Geng, Xingyi; Zhang, Zhiruo; Liu, Shelan

2017-01-01

Middle East respiratory syndrome coronavirus (MERS-CoV) was first isolated in 2012. The largest known outbreak outside the Middle East occurred in South Korea in 2015. As of 29 June 2016, 1769 laboratory-confirmed cases (630 deaths; 35.6 % case fatality rate [CFR]) had been reported from 26 countries, particularly in the Middle East. However, the CFR for hospital outbreaks was higher than that of family clusters in the Middle East and Korea. Here, we compared the mortality rates for 51 nosocomial outbreaks in the Middle East and one outbreak of MERS-CoV in South Korea. Our findings showed the CFR in the Middle East was much higher than that in South Korea (25.9 % [56/216] vs. 13.8 % [24/174], p = 0.003). Infected individuals who died were, on average, older than those who survived in both the Middle East (64 years [25-98] vs. 46 years [2-85], p = 0.000) and South Korea (68 years [49-82] vs. 53.5 years [16-87], p = 0.000). Similarly, the co-morbidity rates for the fatal cases were statistically higher than for the nonfatal cases in both the Middle East (64.3 % [36/56] vs. 28.1 % [45/160], p = 0.000) and South Korea (45.8 % [11/24] vs. 12.0 % [18/150], p = 0.000). The median number of days from onset to confirmation of infection in the fatal cases was longer than that for survivors from the Middle East (8 days [1-47] vs. 4 days [0-14], p = 0.009). Thus, older age, pre-existing concurrent diseases, and delayed confirmation increase the odds of a fatal outcome in nosocomial MERS-CoV outbreaks in the Middle East and South Korea.

Pazopanib Maintenance Therapy in East Asian Women With Advanced Epithelial Ovarian Cancer: Results From AGO-OVAR16 and an East Asian Study.

PubMed

Kim, Jae-Weon; Mahner, Sven; Wu, Ling-Ying; Shoji, Tadahiro; Kim, Byoung-Gie; Zhu, Jian-Qing; Takano, Tadao; Park, Sang-Yoon; Kong, Bei-Hua; Wu, Qiang; Wang, Kung-Liahng; Ngan, Hextan Ys; Liu, Ji-Hong; Wei, Li-Hui; Mitrica, Ionel; Zhang, Pingkuan; Crescenzo, Rocco; Wang, Qiong; Cox, Charles J; Harter, Philipp; du Bois, Andreas

2018-01-01

The recent phase 3 trial AGO-OVAR16 demonstrated that pazopanib maintenance improved median progression-free survival in patients with ovarian cancer whose disease did not progress during first-line treatment. However, this improvement was not seen in the subset of East Asian patients. The current analysis evaluated the efficacy and safety of pazopanib maintenance in East Asian patients from AGO-OVAR16 and a separate East Asian study. East Asian patients from AGO-OVAR16 (n = 209) and the East Asian study (N = 145) were randomized 1:1 to receive pazopanib 800 mg/d or placebo for up to 24 months. The primary end point for each study was progression-free survival by RECIST (Response Evaluation Criteria in Solid Tumors) based on investigator assessment. Clinical and genetics data were analyzed separately by study or pooled according to separate predetermined statistical plans. Pazopanib maintenance had a detrimental effect on median progression-free survival versus placebo in East Asian patients from the combined studies (n = 354; 17.9 vs 21.5 months; hazard ratio, 1.114; 95% confidence interval, 0.818-1.518; P = 0.4928). Pazopanib maintenance showed a disadvantage in overall survival in East Asian patients from AGO-OVAR16 versus placebo (hazard ratio, 1.706; 95% confidence interval, 1.010-2.883; P = 0.0465); overall survival analysis was not performed in the East Asian study because of insufficient event numbers. Pazopanib-treated patients had a significantly higher incidence of grade 3 or higher hypertension (27%) and neutropenia (13%) versus placebo. The treatment effect of maintenance pazopanib in East Asian patients seemed to differ from that in non-Asian patients. In study-specific and pooled analyses, none of the potential factors analyzed could satisfactorily explain the different efficacy results of pazopanib in East Asian patients.

77 FR 38823 - Notice of Availability of the Alta East Wind Project Draft Environmental Impact Statement...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-29

..., LVRWB11B4520] Notice of Availability of the Alta East Wind Project Draft Environmental Impact Statement... California Desert Conservation Area (CDCA) Plan Amendment (PA) for the Alta East Wind Project (AEWP), and by.../en/fo/ridgecrest/alta_east_wind_project.html . Email: [email protected] . Fax: 951 697-5299. Mail...

Andreas Goes to Africa: A Comparative Historical Study of the Teachers for East Africa Programs

ERIC Educational Resources Information Center

Vavrus, Frances

2018-01-01

This article uses a comparative historical approach to examine the Teachers for East Africa (TEA) and the Teacher Education in East Africa (TEEA) programs, an influential educational development effort that involved U.S. and British college graduates in East African schools and colleges during the decade of 1961-1971. Drawing on postcolonial…

8. Freight Warehouse, looking east into the east section. Projecting ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. Freight Warehouse, looking east into the east section. Projecting into the warehouse space are: (a) A loading dock with slatted walls (b) An office space above it and (c) A toilet and utility area. (b) and (c) are accessed through the Ticket Office. - Curtis Wharf, Freight Warehouse, O & Second Streets, Anacortes, Skagit County, WA

VIEW OF UPSTREAM (EAST) SIDES OF UPPER (EAST) END OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF UPSTREAM (EAST) SIDES OF UPPER (EAST) END OF LOCK, SOUTHEAST AND NORTHEAST CONTROL HOUSES, LOCK UNDER REPAIR, BUILDING NOS. 51, 52 AND SOUTHWEST CONTROL HOUSE IN BACKGROUND, VIEW TOWARDS WEST-NORTHWEST - Ortona Lock, Lock No. 2, Machinery and Control Houses, Caloosahatchee River, Cross-State Canal, Okeechobee Intracoastal Waterway, Ortona, Glades County, FL

Middle East and North African Oil.

ERIC Educational Resources Information Center

Al-Quazzaz, Ayad

1981-01-01

Traces the history of oil and natural gas in the Middle East and relates the importance of the Middle East's current stores of oil to economic development. Information is presented on the relationship of major oil companies and local governments, OPEC, rate of production, and the impact of oil on the societies of the Middle East and North Africa.…

10. TROJAN MILL, EXTERIOR FROM EAST, c. 191928. ADDITION TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. TROJAN MILL, EXTERIOR FROM EAST, c. 1919-28. ADDITION TO THE EAST END OF MILLING FLOOR VISIBLE WITH TRAM ENTRY DOOR. ALSO SEEN ARE THE ADDITIONS FOR MILL SOLUTION TANKS AND THE EAST SIDE OF SAMPLING ROOMS. CREDIT JW. - Bald Mountain Gold Mill, Nevada Gulch at head of False Bottom Creek, Lead, Lawrence County, SD

5. VIEW TO THE EAST NORTH EAST FROM PEAK OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. VIEW TO THE EAST NORTH EAST FROM PEAK OF THE TURBINE HALL. THE BRICK STACK TO THE RIGHT EXHAUSTED BOILER 904 WHICH WAS INSTALLED IN 1944. STEEL SHEATHED STRUCTURE IN CENTER OF PHOTOGRAPH HOUSED BOILERS 902 AND 903. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

Autumn Cooling of Western East Antarctica Linked to the Tropical Pacific

NASA Astrophysics Data System (ADS)

Clem, Kyle R.; Renwick, James A.; McGregor, James

2018-01-01

Over the past 60 years, the climate of East Antarctica cooled while portions of West Antarctica were among the most rapidly warming regions on the planet. The East Antarctic cooling is attributed to a positive trend in the Southern Annular Mode (SAM) and a strengthening of the westerlies, while West Antarctic warming is tied to zonally asymmetric circulation changes forced by the tropics. This study finds recent (post-1979) surface cooling of East Antarctica during austral autumn to also be tied to tropical forcing, namely, an increase in La Niña events. The recent increase in La Niña conditions forces a Rossby wave into the Southern Hemisphere that increases anticyclonic circulation over the South Atlantic. The South Atlantic anticyclone is associated with cold air advection, weakened northerlies, and increased sea ice concentrations across the western East Antarctic coast, which has increased the rate of cooling at Novolazarevskaya and Syowa stations after 1979. This enhanced cooling over western East Antarctica is tied more broadly to a zonally asymmetric temperature trend pattern across East Antarctica during autumn that is consistent with a tropically forced Rossby wave rather than a SAM pattern; the positive SAM pattern is associated with ubiquitous cooling across East Antarctica, which is not seen in temperature observations after 1979. We conclude that El Niño-Southern Oscillation-related circulation anomalies, particularly zonal asymmetries that locally enhance meridional wind, are an important component of East Antarctic climate variability during autumn, and future changes in tropical Pacific climate will likely have implications for East Antarctica.

Middle East Respiratory Syndrome (MERS)

MedlinePlus

Middle East Respiratory Syndrome Coronavirus; MERS-CoV; Novel coronavirus; nCoV ... for Disease Control and Prevention website. Middle East Respiratory Syndrome (MERS): Frequently asked questions and answers. www. ...

66. CORBELS, BLIND ARCHES & SHIELDS, COMMONS EAST WALL, LOOKING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

66. CORBELS, BLIND ARCHES & SHIELDS, COMMONS EAST WALL, LOOKING EAST - Smithsonian Institution Building, 1000 Jefferson Drive, between Ninth & Twelfth Streets, Southwest, Washington, District of Columbia, DC

Publications - GMC 364 | Alaska Division of Geological & Geophysical

Science.gov Websites

Alaska: Drew Pt #1, East Simpson Test Well #1, East Simpson #2, Ikpikpuk #1, J.W. Dalton #1, Seabee #1 , Topogoruk Test #1, and W. Dease #1 Authors: Talisman Energy Inc., and Core Laboratories Publication Date Properties Study on Core samples from 8 wells in Alaska: Drew Pt #1, East Simpson Test Well #1, East Simpson

35. VIEW LOOKING EAST IN SOUTH END OF EAST BOILER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

35. VIEW LOOKING EAST IN SOUTH END OF EAST BOILER ROOM. CYLINDRICAL TANKS ARE WORTHINGTON DEAERATORS. THESE REMOVED AIR FROM BOILER FEED WATER TO MINIMIZE CORROSION AND PITTING OF THE BOILER TUBES. AIR REMOVAL ALSO HELPED AVOID THE FORMATION OF FOAM IN THE SYSTEM. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

76 FR 58298 - Notice of Filing of Plats of Survey; Alaska

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-20

..., along a portion of the west boundary of Township 7 North, Range 9 East, the corrective dependent... survey of Townships 7 North, Ranges 8 and 9 East and the survey of Tract 37, Township 7 North, Range 9... Fairbanks, within Township 7 North, Range 9 East and Townships 8 North, Ranges 9, 10 and 11 East, of the...

76 FR 53939 - Notice of Filing of Plats of Survey; Alaska

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-30

..., along a portion of the west boundary of Township 7 North, Range 9 East, the corrective dependent... survey of Townships 7 North, Ranges 8 and 9 East and the survey of Tract 37, Township 7 North, Range 9... Fairbanks, within Township 7 North, Range 9 East and Townships 8 North, Ranges 9, 10 and 11 East, of the...

After the Wall: Parental Attitudes to Child Rearing in East and West Germany

ERIC Educational Resources Information Center

Uhlendorff, Harald

2004-01-01

In the years following German reunification, East and West German parents (282 mothers and 207 fathers) were interviewed about attitudes to the rearing of their 7- to 13-year-old children and about their social networks. Path analyses show that East German parents engage in more protective and less permissive parenting, and that East German…

Alternative Fuels Data Center: Clean Cities Coalitions Bring LNG to the

Science.gov Websites

East Coast Clean Cities Coalitions Bring LNG to the East Coast to someone by E-mail Share Alternative Fuels Data Center: Clean Cities Coalitions Bring LNG to the East Coast on Facebook Tweet about Alternative Fuels Data Center: Clean Cities Coalitions Bring LNG to the East Coast on Twitter Bookmark

76 FR 49666 - Safety Zone; East Coast Drag Boat Bucksport Blowout Boat Race, Waccamaw River, Bucksport, SC

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-11

...-AA00 Safety Zone; East Coast Drag Boat Bucksport Blowout Boat Race, Waccamaw River, Bucksport, SC... temporary safety zone on the waters of the Waccamaw River during the East Coast Drag Boat Bucksport Blowout in Bucksport, South Carolina. The East Coast Drag Boat Bucksport Blowout will consist of a series of...

Efficacy and safety of dasatinib versus imatinib in the East Asian subpopulation of the DASISION trial of newly diagnosed chronic myeloid leukemia in chronic phase

PubMed Central

Chuah, Charles T.; Nakamae, Hirohisa; Shen, Zhixiang X.; Bradley-Garelik, M. Brigid

2014-01-01

Asian patients with chronic myeloid leukemia (CML) tend to have different characteristics compared with patients from other regions, including younger age and smaller body size. The phase 3, open-label, randomized DASISION trial (NCT00481247), comparing dasatinib 100 mg once daily (QD) (n = 259) with imatinib 400 mg QD (n = 260) in newly diagnosed chronic phase CML (CML-CP), included a sizeable East Asian population (n = 60: dasatinib; n = 48: imatinib). In East Asian patients, dasatinib showed favorable 24-month rates of major molecular response (68% vs. 50% for imatinib) and complete cytogenetic response (92% vs. 88%), and more patients achieved BCR–ABL1 transcript levels ≤ 10% at 3 months with dasatinib (91% vs. 69%), similar to the overall population. Relative to non-East Asian patients, the incidence of rash, fluid-related events and grade 3/4 neutropenia and thrombocytopenia appeared to be higher in East Asians, regardless of treatment. Pharmacokinetic analysis revealed statistically non-significant increased dasatinib exposure among East Asian patients. Results support the use of dasatinib 100 mg QD as first-line CML treatment in both East Asian and non-East Asian patients. PMID:24289108

Cancer Control Programs in East Asia: Evidence From the International Literature

PubMed Central

Moore, Malcolm A.

2014-01-01

Cancer is a major cause of mortality and morbidity throughout the world, including the countries of North-East and South-East Asia. Assessment of burden through cancer registration, determination of risk and protective factors, early detection and screening, clinical practice, interventions for example in vaccination, tobacco cessation efforts and palliative care all should be included in comprehensive cancer control programs. The degree to which this is possible naturally depends on the resources available at local, national and international levels. The present review concerns elements of cancer control programs established in China, Taiwan, Korea, and Japan in North-East Asia, Viet Nam, Thailand, Malaysia, and Indonesia as representative larger countries of South-East Asia for comparison, using the published literature as a guide. While major advances have been made, there are still areas which need more attention, especially in South-East Asia, and international cooperation is essential if standard guidelines are to be generated to allow effective cancer control efforts throughout the Far East. PMID:25139165

South-East Asian strains of Plasmodium falciparum display higher ratio of non-synonymous to synonymous polymorphisms compared to African strains

PubMed Central

Singh, Gajinder Pal; Sharma, Amit

2016-01-01

Resistance to frontline anti-malarial drugs, including artemisinin, has repeatedly arisen in South-East Asia, but the reasons for this are not understood. Here we test whether evolutionary constraints on Plasmodium falciparum strains from South-East Asia differ from African strains. We find a significantly higher ratio of non-synonymous to synonymous polymorphisms in P. falciparum from South-East Asia compared to Africa, suggesting differences in the selective constraints on P. falciparum genome in these geographical regions. Furthermore, South-East Asian strains showed a higher proportion of non-synonymous polymorphism at conserved positions, suggesting reduced negative selection. There was a lower rate of mixed infection by multiple genotypes in samples from South-East Asia compared to Africa. We propose that a lower mixed infection rate in South-East Asia reduces intra-host competition between the parasite clones, reducing the efficiency of natural selection. This might increase the probability of fixation of fitness-reducing mutations including drug resistant ones. PMID:27853513

1D Cole-Cole inversion of TEM transients influenced by induced polarization

NASA Astrophysics Data System (ADS)

Seidel, Marc; Tezkan, Bülent

2017-03-01

Effects of induced polarization (IP) can have an impact on time-domain electromagnetic measurements (TEM) and may lead to sign reversals in the recorded transients. To study these IP effects on TEM data, a new 1D inversion algorithm was developed for both, the central-loop and the separate-loop TEM configurations using the Cole-Cole relaxation model. 1D forward calculations for a homogeneous half-space were conducted with the aim of analyzing the impacts of the Cole-Cole parameters on TEM transients with respect to possible sign reversals. The forward modelings showed that the variation of different parameters have comparable effects on the TEM transients. This leads to an increasing number of equivalent models as a result of inversion calculations. Subsequently, 1D inversions of synthetic data were performed to study the potentials and limitations of the algorithm regarding the resolution of the Cole-Cole parameters. In order to achieve optimal inversion results, it was essential to error-weight the data points in the direct vicinity of sign reversals. The obtained findings were eventually adopted on the inversion of real field data which contained considerable IP signatures such as sign reversals. One field data set was recorded at the Nakyn kimberlite field in Western Yakutiya, Russia, in the central-loop configuration. Another field data set originates from a waste site in Cologne, Germany, and was measured utilizing the separate-loop configuration.

Seismic anisotropy of the Slave craton, NW Canada, from joint interpretation of SKS and Rayleigh waves

NASA Astrophysics Data System (ADS)

Snyder, David; Bruneton, Marianne

2007-04-01

Teleseismic events recorded at a 25-element array in NW Canada between 2001 and 2006 provided sufficient distribution in back azimuth to demonstrate birefringence in SKS and SKKS waves as well as directional dependence of Rayleigh-wave phase velocities. Typical delays between orthogonally polarized SKS waves are 0.8-1.2 s, and modelling of azimuthal dependence indicates two nearly horizontal layers of anisotropy within the mantle. Anisotropy of Rayleigh waves is generally consistent with models of layered Vs anisotropies that increase with depth from 1 per cent at the Moho to 9 per cent at 200 km but vary between subarrays. Consistency between the SKS and Rayleigh wave anisotropies in one subarray suggests that the assumption of symmetry about a horizontal axis is valid there but is not fully valid in other parts of the craton. The upper layer of anisotropy occupies approximately the uppermost 120 km in which the fast polarization direction strikes generally north-south, coinciding with regional-scale fold axes mapped at the surface. The fast polarization direction of the deeper layer aligns with current North America plate motion, but its correlation with trends of coeval kimberlite eruptions within the Lac de Gras field suggests it can be at least partly attributed to structural preferred orientation of vertical dykes inferred to exist to depths of 200 km.

The effect of temperature and pressure on the distribution of iron group elements between metal and olivine phases in the process of differentiation of protoplanetary material

NASA Technical Reports Server (NTRS)

Vinogradov, A. P.; Ilyin, N. P.; Kolomeytsava, L. N.

1977-01-01

The distribution patterns of Ni, Co, Mn, and Cr were studied in olivines of various origins: from meteorites (chondrites, achondrites, pallasites), which are likely analogs of the protoplanetary material, to peridotite inclusions in kimberlite pipes, which are analogs of mantle material. According to X-ray microanalysis data, nickel is concentrated in peridotite olivines, while manganese is concentrated in meteoritic olivines. The maximum chromium content was found in ureilites, which were formed under reducing conditions. Experiments at pressures of 20 to 70 kbar and temperatures of 1100 to 2000 C have shown that in a mixture of olivine and Ni metal or NiO, nickel enters the silicate phase, displacing Fe into the metallic phase. Equilibrium temperatures were estimated from the Fe, Ni distribution coefficients between the metal and olivine: 1500 K for pallasites, 1600 K for olivine-bronzite H6 chondrites, 1200 K for olivine-hypersthene L6, 900 K for LL6, and 1900 K for ureilites (at P = 1 atm). The equilibrium conditions of peridotites are close to T = 1800 K and P over 100 kbar. It is concluded that there is a sharp difference between the conditions of differentiation of the protoplanetary material at the time meteorites were formed and the conditions of differentiation of the planets into concentric layers.

Progress of beam diagnosis system for EAST neutral beam injector

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Y. J., E-mail: yjxu@ipp.ac.cn; Hu, C. D.; Yu, L.

Neutral beam injection has been recognized as one of the most effective means for plasma heating. According to the research plan of the EAST physics experiment, two sets of neutral beam injector (NBI) were built and operational in 2014. The paper presents the development of beam diagnosis system for EAST NBI and the latest experiment results obtained on the test-stand and EAST-NBI-1 and 2. The results show that the optimal divergence angle is (0.62°, 1.57°) and the full energy particle is up to 77%. They indicate that EAST NBI work properly and all targets reach or almost reach the designmore » targets. All these lay a solid foundation for the achievement of high quality plasma heating for EAST.« less

3. East portal of Tunnel 27, view to northeast from ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. East portal of Tunnel 27, view to northeast from atop cut bank, 210mm lens. This view shows to good effect the original construction of the Harriman period tunnels, which were concreted fifty feet in from the portals with the balance being timber lined. In 1965 the east end of the tunnel collapsed, with the result that approximately 115 feet of the east end was 'daylighted' and the original east portal and concreted end were left in place, free-standing as seen here. - Central Pacific Transcontinental Railroad, Tunnel No. 27, Milepost 133.9, Applegate, Placer County, CA

Genetic population structure of the malaria vector Anopheles baimaii in north-east India using mitochondrial DNA

PubMed Central

2012-01-01

Background Anopheles baimaii is a primary vector of human malaria in the forest settings of Southeast Asia including the north-eastern region of India. Here, the genetic population structure and the basic population genetic parameters of An. baimaii in north-east India were estimated using DNA sequences of the mitochondrial cytochrome oxidase sub unit II (COII) gene. Methods Anopheles baimaii were collected from 26 geo-referenced locations across the seven north-east Indian states and the COII gene was sequenced from 176 individuals across these sites. Fifty-seven COII sequences of An. baimaii from six locations in Bangladesh, Myanmar and Thailand from a previous study were added to this dataset. Altogether, 233 sequences were grouped into eight population groups, to facilitate analyses of genetic diversity, population structure and population history. Results A star-shaped median joining haplotype network, unimodal mismatch distribution and significantly negative neutrality tests indicated population expansion in An. baimaii with the start of expansion estimated to be ~0.243 million years before present (MYBP) in north-east India. The populations of An. baimaii from north-east India had the highest haplotype and nucleotide diversity with all other populations having a subset of this diversity, likely as the result of range expansion from north-east India. The north-east Indian populations were genetically distinct from those in Bangladesh, Myanmar and Thailand, indicating that mountains, such as the Arakan mountain range between north-east India and Myanmar, are a significant barrier to gene flow. Within north-east India, there was no genetic differentiation among populations with the exception of the Central 2 population in the Barail hills area that was significantly differentiated from other populations. Conclusions The high genetic distinctiveness of the Central 2 population in the Barail hills area of the north-east India should be confirmed and its epidemiological significance further investigated. The lack of genetic population structure in the other north-east Indian populations likely reflects large population sizes of An. baimaii that, historically, were able to disperse through continuous forest habitats in the north-east India. Additional markers and analytical approaches are required to determine if recent deforestation is now preventing ongoing gene flow. Until such information is acquired, An. baimaii in north-east India should be treated as a single unit for the implementation of vector control measures. PMID:22429500

How Much Is Learned when We're Not Looking: The Promise of CES Elementary Schools

ERIC Educational Resources Information Center

Meier, Deborah

2007-01-01

In the mid-1980s, the author discovered the soon-to-be-Coalition of Essential Schools as she was contemplating starting a secondary school in East Harlem, a follow-up to their successful little network of progressive-minded elementary schools: Central Park East, Central Park East II, and River East. Through a series of lucky connections, she and…

33 CFR 334.1480 - Vieques Passage and Atlantic Ocean, off east coast of Puerto Rico and coast of Vieques Island...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Ocean, off east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. 334.1480... east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. (a) The restricted areas. (1) A strip, 1,500 yards wide, off the naval reservation shoreline along the east coast of Puerto...

33 CFR 334.1480 - Vieques Passage and Atlantic Ocean, off east coast of Puerto Rico and coast of Vieques Island...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Ocean, off east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. 334.1480... east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. (a) The restricted areas. (1) A strip, 1,500 yards wide, off the naval reservation shoreline along the east coast of Puerto...

33 CFR 334.1480 - Vieques Passage and Atlantic Ocean, off east coast of Puerto Rico and coast of Vieques Island...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Ocean, off east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. 334.1480... east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. (a) The restricted areas. (1) A strip, 1,500 yards wide, off the naval reservation shoreline along the east coast of Puerto...

33 CFR 334.1480 - Vieques Passage and Atlantic Ocean, off east coast of Puerto Rico and coast of Vieques Island...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Ocean, off east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. 334.1480... east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. (a) The restricted areas. (1) A strip, 1,500 yards wide, off the naval reservation shoreline along the east coast of Puerto...

33 CFR 334.1480 - Vieques Passage and Atlantic Ocean, off east coast of Puerto Rico and coast of Vieques Island...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Ocean, off east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. 334.1480... east coast of Puerto Rico and coast of Vieques Island; naval restricted areas. (a) The restricted areas. (1) A strip, 1,500 yards wide, off the naval reservation shoreline along the east coast of Puerto...

Agreement on Water and a Watered-Down Agreement: The Political Ecology of Contested Coastal Development in Down East, North Carolina

ERIC Educational Resources Information Center

Campbell, Lisa M.; Meletis, Zoe A.

2011-01-01

In 2006, land use planning emerged as a contested issue in the rural area known as "Down East", Carteret County, in eastern North Carolina, USA. Down East is experiencing a transition from a commercial fishing to an amenity economy and concerns about related changes led to the formation of "Down East Tomorrow" (DET), a…

75 FR 34362 - Safety Zone; Festivals & Fireworks Celebration, East Moran Bay, Lake Huron, St. Ignace, MI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-17

...-AA00 Safety Zone; Festivals & Fireworks Celebration, East Moran Bay, Lake Huron, St. Ignace, MI AGENCY... safety zone on East Moran Bay, Lake Huron, St. Ignace, MI. This zone is intended to restrict vessels from... portion of East Moran Bay, Lake Huron, St. Ignace, MI between 9 p.m. and 11 p.m. on June 26, July 10, July...

Fifteen-Years-Old Students of Seven East Asian Cities in PISA 2009: A Secondary Analysis

ERIC Educational Resources Information Center

Soh, Kay Cheng

2012-01-01

Background: In PISA 2009, seven East Asian countries rank high among the 65 participating countries, but some of the differences among the seven countries are small to be of substantive meaning. Aims: This paper is an attempt to fine tune the comparisons for better understanding of the situation in East Asian. Sample: Data of the seven East Asian…

Enhancement of seasonal prediction of East Asian summer rainfall related to the western tropical Pacific convection

NASA Astrophysics Data System (ADS)

Lee, D. Y.; Ahn, J. B.; Yoo, J. H.

2014-12-01

The prediction skills of climate model simulations in the western tropical Pacific (WTP) and East Asian region are assessed using the retrospective forecasts of seven state-of-the-art coupled models and their multi-model ensemble (MME) for boreal summers (June-August) during the period 1983-2005, along with corresponding observed and reanalyzed data. The prediction of summer rainfall anomalies in East Asia is difficult, while the WTP has a strong correlation between model prediction and observation. We focus on developing a new approach to further enhance the seasonal prediction skill for summer rainfall in East Asia and investigate the influence of convective activity in the WTP on East Asian summer rainfall. By analyzing the characteristics of the WTP convection, two distinct patterns associated with El Niño-Southern Oscillation (ENSO) developing and decaying modes are identified. Based on the multiple linear regression method, the East Asia Rainfall Index (EARI) is developed by using the interannual variability of the normalized Maritime continent-WTP indices (MPIs), as potentially useful predictors for rainfall prediction over East Asia, obtained from the above two main patterns. For East Asian summer rainfall, the EARI has superior performance to the East Asia summer monsoon index (EASMI) or each MP index (MPI). Therefore, the regressed rainfall from EARI also shows a strong relationship with the observed East Asian summer rainfall pattern. In addition, we evaluate the prediction skill of the East Asia reconstructed rainfall obtained by statistical-empirical approach using the cross-validated EARI from the individual models and their MME. The results show that the rainfalls reconstructed from simulations capture the general features of observed precipitation in East Asia quite well. This study convincingly demonstrates that rainfall prediction skill is considerably improved by using the statistical-empirical method compared to the dynamical models. Acknowledgements This work was carried out with the support of the Rural Development Administration Cooperative Research Program for Agriculture Science and Technology Development under Grant Project No. PJ009953, Republic of Korea.

Human Migration through Bottlenecks from Southeast Asia into East Asia during Last Glacial Maximum Revealed by Y Chromosomes

PubMed Central

Wen, Bo; Xu, Shuhua; Wang, Yi; Lu, Yan; Wei, Lanhai; Wang, Chuanchao; Li, Shilin; Huang, Xingqiu; Jin, Li; Li, Hui

2011-01-01

Molecular anthropological studies of the populations in and around East Asia have resulted in the discovery that most of the Y-chromosome lineages of East Asians came from Southeast Asia. However, very few Southeast Asian populations had been investigated, and therefore, little was known about the purported migrations from Southeast Asia into East Asia and their roles in shaping the genetic structure of East Asian populations. Here, we present the Y-chromosome data from 1,652 individuals belonging to 47 Mon-Khmer (MK) and Hmong-Mien (HM) speaking populations that are distributed primarily across Southeast Asia and extend into East Asia. Haplogroup O3a3b-M7, which appears mainly in MK and HM, indicates a strong tie between the two groups. The short tandem repeat network of O3a3b-M7 displayed a hierarchical expansion structure (annual ring shape), with MK haplotypes being located at the original point, and the HM and the Tibeto-Burman haplotypes distributed further away from core of the network. Moreover, the East Asian dominant haplogroup O3a3c1-M117 shows a network structure similar to that of O3a3b-M7. These patterns indicate an early unidirectional diffusion from Southeast Asia into East Asia, which might have resulted from the genetic drift of East Asian ancestors carrying these two haplogroups through many small bottle-necks formed by the complicated landscape between Southeast Asia and East Asia. The ages of O3a3b-M7 and O3a3c1-M117 were estimated to be approximately 19 thousand years, followed by the emergence of the ancestors of HM lineages out of MK and the unidirectional northward migrations into East Asia. PMID:21904623

General view, kitchen and living/dining area of secondfloor apartment, east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

General view, kitchen and living/dining area of second-floor apartment, east wing, looking southeast. - Lazaretto Quarantine Station, Wanamaker Avenue and East Second Street, Essington, Delaware County, PA

INTERIOR VIEW, EASTWEST CORRIDOR SEEN THROUGH EAST SIDE ENTRY (NOTE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR VIEW, EAST-WEST CORRIDOR SEEN THROUGH EAST SIDE ENTRY (NOTE GLASS BLOCK TRANSOM PROVIDING LIGHT INTO CORRIDOR) - Greenbelt Community Building, 15 Crescent Road, Greenbelt, Prince George's County, MD

Fireplace detail, east wall, northeast secondfloor room, main block, showing ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Fireplace detail, east wall, northeast second-floor room, main block, showing ghost of surround and mantle. - Lazaretto Quarantine Station, Wanamaker Avenue and East Second Street, Essington, Delaware County, PA

Middle East Respiratory Syndrome (MERS)

MedlinePlus

... Controls Cancel Submit Search The CDC Middle East Respiratory Syndrome (MERS) Note: Javascript is disabled or is ... Recommend on Facebook Tweet Share Compartir Middle East Respiratory Syndrome (MERS) is viral respiratory illness that was ...

BRONXWHITESTONE OVER THE EAST RIVER, NOTE CONSIDERABLE AIR POLLUTION OVER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

BRONX-WHITESTONE OVER THE EAST RIVER, NOTE CONSIDERABLE AIR POLLUTION OVER CITY IN BACKGROUND - Bronx-Whitestone Bridge, Spanning East River between Whitestone, Queens & the Bronx, Bronx, Bronx County, NY

Comparison of the Impact of the Arctic Oscillation and East Atlantic - West Russia Teleconnection on Interannual Variation in East Asian Winter Temperatures and Monsoon

NASA Technical Reports Server (NTRS)

Lim, Young-Kwon; Kim, Hae-Dong

2014-01-01

The large-scale impacts of the Arctic Oscillation (AO) and the East Atlantic/West Russia (EA/WR) teleconnection on the East Asian winter climate anomalies are compared for the past 34 winters focusing on 1) interannual monthly to seasonal temperature variability, 2) East Asian winter monsoon (EAWM), and 3) the Siberian high (SH) and cold surge. Regression analysis reveals warming by AO and EA/WR over mid-latitude East Asia during their positive phase and vice versa. The EA/WR impact is found to be comparable to the AO impact in affecting the East Asian temperature and monsoon. For example, warm (cold) months over mid-latitude East Asia during the positive (negative) AO are clearly seen when the AO and EA/WR are in the same phase. Near zero correlation is found between temperature and the AO phase when both teleconnections are in an opposite phase. The well-known negative relationship between SH and the AO phase is observed significantly more often when the AO is in the same phase with the EA/WR. Also, the indices of EAWM, cold surge, and SH are found to be more highly negative-correlated with the EA/WR rather than with the AO. The advective temperature change and associated circulation demonstrate that the anomalous large-scale field including the SH over the mid-latitude Asian inland is better represented by the EA/WR, influencing the East Asian winter climates. These results suggest that the impact of EA/WR should be considered more important than previously thought for a better understanding of East Asian winter temperature and monsoon variability.

Maternal Asian ethnicity and obstetric intrapartum intervention: a retrospective cohort study.

PubMed

Reddy, Maya; Wallace, Euan M; Mockler, Joanne C; Stewart, Lynne; Knight, Michelle; Hodges, Ryan; Skinner, Sasha; Davies-Tuck, Miranda

2017-01-05

Maternal ethnicity is a recognized risk factor for stillbirth, such that South Asian women have higher rates than their Caucasian counterparts. However, whether maternal ethnicity is a risk factor for intrapartum outcomes is less clear. The aim of this study is to explore associations between maternal country of birth, operative vaginal delivery and emergency cesarean section, and to identify possible mechanisms underlying any such associations. We performed a retrospective cohort study of singleton term births among South Asian, South East/East Asian and Australian/New Zealand born women at an Australian tertiary hospital in 2009-2013. The association between maternal country of birth, operative vaginal birth and emergency cesarean was assessed using multivariate logistic regression. Of the 31,932 births, 54% (17,149) were to Australian/New Zealand-born women, 25% (7874) to South Asian, and 22% (6879) to South East/East Asian born women. Compared to Australian/New Zealand women, South Asian and South East/East Asian women had an increased rate of both operative vaginal birth (OR 1.43 [1.30-1.57] and 1.22 [1.11-1.35] respectively, p < 0.001 for both) and emergency cesarean section (OR 1.67 [1.53-1.82] and 1.16 [1.04-1.26] respectively, p < 0.001 and p = 0.007 respectively). While prolonged labor was the predominant reason for cesarean section among Australian/New Zealand and South East/East Asian women, fetal compromise accounted for the majority of operative births in South Asian women. South Asian and South East/East Asian women experience higher rates of both operative vaginal birth and cesarean section in comparison to Australian/New Zealand women, independent of other risk factors for intrapartum interventions.

Closet located in the east wall to the south of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Closet located in the east wall to the south of the fireplace, northeast second-floor room, main block. - Lazaretto Quarantine Station, Wanamaker Avenue and East Second Street, Essington, Delaware County, PA

4. MESS HALL, FRONT DETAIL OVER DOOR, LOOKING EAST. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. MESS HALL, FRONT DETAIL OVER DOOR, LOOKING EAST. - NIKE Missile Base C-84, Mess Hall, North of Launch Area Entrance Drive, east of Officers' Quarters & Administration Building, Barrington, Cook County, IL

2. MESS HALL, RIGHT SIDE, LOOKING EAST. NIKE Missile ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. MESS HALL, RIGHT SIDE, LOOKING EAST. - NIKE Missile Base SL-40, Mess Hall, East central portion of base, southeast of Barracks No. 2, northwest of Administration Building, Hecker, Monroe County, IL

19. First floor, room south of second floor landing, looking ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

19. First floor, room south of second floor landing, looking east - Veterans Administration Center, Officers Duplex Quarters, 5302 East Kellogg (Legal Address); 5500 East Kellogg (Common Address), Wichita, Sedgwick County, KS

Historic view of penstock repair following 1910's landslide just east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Historic view of penstock repair following 1910's landslide just east of powerhouse; looking east. (photographer unknown, ca. 1910's) - Nooksack Falls Hydroelectric Plant, Route 542, Glacier, Whatcom County, WA

East yard, north elevation of car department tool house (converted ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

East yard, north elevation of car department tool house (converted from express car). - Chesapeake & Ohio Railroad, Thurmond Yards, East side New River, mouths of Arbuckle & Dunlop Circles, Thurmond, Fayette County, WV

22. Launch Area, Missile Assembly Building VIEW SOUTHWEST, EAST AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

22. Launch Area, Missile Assembly Building VIEW SOUTHWEST, EAST AND NORTH ELEVATION - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

DETAIL OF MAIN ENTRANCE ON EAST (FRONT) ELEVATION OF BUILDING. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

DETAIL OF MAIN ENTRANCE ON EAST (FRONT) ELEVATION OF BUILDING. VIEW TO SOUTHWEST. - Plattsburgh Air Force Base, Education Center, Off Connecticut Road, east of Idaho Avenue, Plattsburgh, Clinton County, NY

23. Historic American Buildings Survey Alex Bush, Photographer, February 2, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

23. Historic American Buildings Survey Alex Bush, Photographer, February 2, 1937 LOOKING EAST IN GIRL'S DORMITORY, FOURTH FLOOR - East Alabama Masonic Female Institute, 205 East South Street, Talladega, Talladega County, AL

1. VIEW EAST, COMPONENTS TEST LABORATORY SHOWING CATCH BASINS, TURBINE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. VIEW EAST, COMPONENTS TEST LABORATORY SHOWING CATCH BASINS, TURBINE TESTING AREA, AND PUMP TESTING TOWER. - Marshall Space Flight Center, East Test Area, Components Test Laboratory, Huntsville, Madison County, AL

DETAIL OF LAMP ABOVE SOUTH SIDE ENTRANCE; CAMERA FACING EAST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

DETAIL OF LAMP ABOVE SOUTH SIDE ENTRANCE; CAMERA FACING EAST - Mare Island Naval Shipyard, Bachelor Enlisted Quarters & Offices, Walnut Avenue, east side between D Street & C Street, Vallejo, Solano County, CA

Detail, east side, north end, showing door and overhead rail ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Detail, east side, north end, showing door and overhead rail for refrigeration room. - Fitzsimons General Hospital, Ice Plant, Southwest Corner of East I Avenue & North Thirteenth Street, Aurora, Adams County, CO

1. CONTEXT VIEW OF BUILDING 746 FROM EAST K STREET, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. CONTEXT VIEW OF BUILDING 746 FROM EAST K STREET, LOOKING SOUTHEAST. - Oakland Naval Supply Center, Gymnasium-Cafeteria-Theater, East K Street between Eleventh & Twelfth Streets, Oakland, Alameda County, CA

2. EXTERIOR OBLIQUE VIEW OF BUILDING 746 FROM EAST K ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EXTERIOR OBLIQUE VIEW OF BUILDING 746 FROM EAST K STREET, LOOKING SOUTHEAST. - Oakland Naval Supply Center, Gymnasium-Cafeteria-Theater, East K Street between Eleventh & Twelfth Streets, Oakland, Alameda County, CA

2. ADMINISTRATION BUILDING, REAR SIDE, LOOKING EAST. NIKE Missile ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. ADMINISTRATION BUILDING, REAR SIDE, LOOKING EAST. - NIKE Missile Base SL-40, Administration Building, East central portion of base, southeast of Mess Hall, northeast of HIPAR Equipment Building, Hecker, Monroe County, IL

Cultural influences on stigmatization of problem gambling: East Asian and Caucasian canadians.

PubMed

Dhillon, Jasmin; Horch, Jenny D; Hodgins, David C

2011-12-01

Cultural influences on problem gambling stigma were examined using a between subject vignette study design. Students of East Asian (n = 64) and Caucasian (n = 50) ancestry recruited from a Canadian University rated a vignette describing either an East Asian problem gambler or a Caucasian problem gambler on a measure of attitudinal social distance. In accordance with the hypothesis, a factorial ANOVA revealed that East Asian Canadians stigmatize problem gambling more than Caucasian Canadians. Moreover, East Asian participants stigmatized the East Asian individual described in the vignette more than they did the Caucasian individual. Individuals with gambling problems were generally not perceived as being dangerous. However, participants who perceived problem gambling as a dangerous condition wanted more social distance than those who did not perceive individuals with a gambling problem as dangerous.

Nonmetric cranial trait variation and population history of medieval East Slavic tribes.

PubMed

Movsesian, Alla A

2013-12-01

The population history of the East Slavs is complicated. There are still many unanswered questions relating to the origins and formation of the East Slavic gene pool. The aims of the current study were as follows: (1) to assess the degree of biological affinity in medieval East Slavic tribes and to test the hypothesis that East Slavic peoples have a common origin; (2) to show their genetic connections to the autochthonous populations of the northern part of Eastern Europe (Baltic and Finno-Ugric tribes); and (3) to identify a genetic continuity between the bearers of Chernyakhov culture and medieval Eastern Slavs. In this study, nonmetric cranial trait data for medieval East Slavic tribes and comparative samples from unrelated groups were examined. Analyzes of phenotypic differentiation were based on Nei's standard genetic distance and hierarchical GST statistics. The results obtained suggest that the genetic affinity of the East Slavic tribes is due not only to inter-tribal gene flow, but is, more importantly, a result of their common population history. Evidence of gene flow from the Baltic and Finno-Ugric groups was showed in the gene pool of Eastern Slavs, as was genetic continuity between medieval East Slavic tribes and the populations of the preceding Chernyakhov culture. These findings support a "generalizing" hypothesis of East Slavic origin, in which a Slavic community was formed in some particular ancestral area, and subsequently spread throughout Eastern Europe. Copyright © 2013 Wiley Periodicals, Inc.

Give-and-take in an ecumenical system. HealthEast St. Joseph's shared its traditions and gained a better balance.

PubMed

Louwagie, M; Hertel, M

1997-01-01

When St. Joseph's Hospital in St. Paul, MN, owned and operated by the Sisters of St. Joseph of Carondelet, joined the ecumenical HealthEast healthcare system in 1987, many observers were skeptical of the venture's success. But an emphasis on their shared Judeo-Christian values has enabled the Catholic, Lutheran, and Baptist facilities to build a strong system. The beginnings of the merger were difficult, as facilities closed, others expanded their services, and staff shifted between them. An open communications policy between HealthEast leaders and staff members and dedication to the mission of healthcare that all the system facilities shared helped blend denominational identity and traditions at each member hospital and establish a corporate identity. The HealthEast system has adopted some of St. Joseph's policies and practices, particularly in the areas of mission, ethics, and spiritual care. HealthEast St. Joseph's has also benefited from being part of the HealthEast system, gaining a more diverse staff respectful of each others' beliefs, expanded spiritual care, and the means to continue serving its community. HealthEast plans to discontinue inpatient services at HealthEast St. Joseph's in downtown St. Paul and build a suburban facility, but the Sisters of St. Joseph of Carondelet are working with HealthEast to assess the downtown community's healthcare needs, especially among the homeless and immigrant populations, and ensure those needs will continue to be met.

Sub-seasonal prediction over East Asia during boreal summer using the ECCC monthly forecasting system

NASA Astrophysics Data System (ADS)

Liang, Ping; Lin, Hai

2018-02-01

A useful sub-seasonal forecast is of great societal and economical value in the highly populated East Asian region, especially during boreal summer when frequent extreme events such as heat waves and persistent heavy rainfalls occur. Despite recent interest and development in sub-seasonal prediction, it is still unclear how skillful dynamical forecasting systems are in East Asia beyond 2 weeks. In this study we evaluate the sub-seasonal prediction over East Asia during boreal summer in the operational monthly forecasting system of Environment and Climate Change Canada (ECCC).Results show that the climatological intra-seasonal oscillation (CISO) of East Asian summer monsoonis reasonably well captured. Statistically significant forecast skill of 2-meter air temperature (T2m) is achieved for all lead times up to week 4 (days 26-32) over East China and Northeast Asia, which is consistent with the skill in 500 hPa geopotential height (Z500). Significant forecast skill of precipitation, however, is limited to the week of days 5-11. Possible sources of predictability on the sub-seasonal time scale are analyzed. The weekly mean T2m anomaly over East China is found to be linked to an eastward propagating extratropical Rossby wave from the North Atlantic across Europe to East Asia. The Madden-Julian Oscillation (MJO) and El Nino-Southern Oscillation (ENSO) are also likely to influence the forecast skill of T2m at the sub-seasonal timescale over East Asia.

Discharge, water-quality characteristics, and nutrient loads from McKay Bay, Delaney Creek, and East Bay, Tampa, Florida, 1991-1993

USGS Publications Warehouse

Stoker, Y.E.; Levesque, V.A.; Fritz, E.M.

1996-01-01

Nutrient enrichment in Tampa Bay has caused a decline in water quality in the estuary. Efforts to reduce the nutrient loading to Tampa Bay have resulted in improvement in water quality from 1981 to 1991. However, Tampa Bay still is onsidered enriched with nutrients. Water quality in East Bay (located at the northeastern part of Hillsborough Bay, which is an embayment in Tampa Bay) is not improving at the same rate as the rest of the bay. East Bay is the center of shipping activity in Tampa Bay and the seventh largest port in the United States. One of the primary cargoes is phosphate ore and related products such as fertilizer. The potential for nutrient loading to East Bay from shipping activities is high and has not previously been measured. Nitrogen and phosphorus loads from East Bay to Hillsborough Bay were measured during selected time periods during June 1992 through May 1993; these data were used to estimate seasonal and annual loads. These loads were evaluated to determine whether the loss of fertilizer products from shipping activities resulted in increased nutrient loading to Hillsborough Bay. Discharge was measured, and water-quality samples were collected at the head of East Bay (exiting McKay Bay), and at the mouth of East Bay. Discharge and nitrogen and phosphorus concentrations for the period June 1992 through May 1993 were used to compute loads. Discharges from McKay Bay, Delaney Creek, and East Bay are highly variable because of the effect of tide. Flow patterns during discharge measurements generally were unidirectional in McKay Bay and Delaney Creek, but more complex, bidirectional patterns were observed at the mouth of East Bay. Tidally affected discharge data were digitally filtered with the Godin filter to remove the effects of tide so that residual, or net, discharge could be determined. Daily mean discharge from McKay Bay ranged from -1,900 to 2,420 cubic feet per second; from Delaney Creek, -3.8 to 162 cubic feet per second; and from East Bay, -437 to 3,780 cubic feet per second. Water quality in McKay Bay, Delaney Creek, and East Bay varies vertically, areally, and seasonally. Specific conductance and concentrations of phosphorus and ammonia nitrogen were greater near the bottom than near the surface at the head and mouth of East Bay. Concentrations of total nitrogen and ammonia plus organic nitrogen generally were greater at the head of East Bay than at the mouth, indicating that McKay Bay is the primary source of nitrogen to East Bay. Concentrations of total ammonia nitrogen, nitrite plus nitrate nitrogen, phosphorus, orthophosphorus, and suspended solids and values of turbidity and specific conductance generally were greater at the mouth of East Bay than at the head. The greatest concentrations of nitrogen and phosphorus were measured in Delaney Creek. In East Bay and McKay Bay, the greatest concentrations of nitrogen, phosphorus, and ammonia plus organic nitrogen occurred in summer, whereas turbidity, specific conductance, and concentrations of suspended solids were greater in winter. The greatest daily mean loads from McKay Bay and East Bay occurred in late June 1992 and April and May 1993 and coincided with periods of daily mean discharge greater than about 2,000 cubic feet per second. Although concentrations of nitrogen and phosphorus were greater in Delaney Creek than in McKay Bay and East Bay, loads were minimal because of minimal discharges from Delaney Creek. Monthly loads of total nitrogen ranged from about 20 tons to about 83 tons at McKay Bay; from about 1 ton to 4.2 tons at Delaney Creek; and from about 17 tons to 76 tons at the mouth of East Bay. Monthly loads of phosphorus ranged from about 11 tons to about 45 tons at McKay Bay; from about 0.62 ton to 2.6 tons at Delaney Creek; and from about 10 tons to about 45 tons at the mouth of East Bay. The results of this study indicate that nitrogen and phosphorus loads from the basin draining directly to East Bay (excluding loads from the McKa

76 FR 53166 - Public Notice for Waiver of Aeronautical Land-Use Assurance; Lake in the Hills Airport, Lake in...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-25

... Corner of said Section 16, thence South 0[deg]-37'-12'' East (bearings assumed for description purposes... bearing South 24[deg]-42'-06'' East 241.85 feet; thence South 32[deg]-38'-43'' East 560.59 feet; thence... and a chord bearing of South 12[deg]-05'- 56'' East 747.55 feet; thence South 8[deg]-26'-51'' West 293...

6. North wall and east end of air brake shop ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. North wall and east end of air brake shop section of roundhouse at center. East end of boiler shop section of roundhouse to the right of air brake shop. East end of blacksmith shop section of roundhouse at far right. View to southeast. - Duluth & Iron Range Rail Road Company Shops, Roundhouse, Southwest of downtown Two Harbors, northwest of Agate Bay, Two Harbors, Lake County, MN

Kuroshio Transport East of Taiwan and the Effect of Mesoscale Eddies

DTIC Science & Technology

2015-09-30

1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Kuroshio Transport East of Taiwan and the Effect of...The objective of this project is to characterize variability in the Kuroshio east of Taiwan and to understand (1) how this variability is related to...Mindanao Current and (2) how westward-propagating mesoscale eddies that arrive east of Taiwan from the ocean interior affect Kuroshio variability. This

JPRS Report, Near East & South Asia, Kuwait

DTIC Science & Technology

1991-08-21

in the stock market in the country, it is necessary to ascertain the number of [istimarat musa"arah] or direct investments [istimarat], foreign workers...commercial or industrial activities, [Al-Fassam] My view is simply that industry has a large or expanding foreign investment , for example? role in all...States from NTIS or Friday in eight volumes: China , East Europe, Soviet appointed foreign dealers. New subscribers should Union, East Asia, Near East

Why Do East Asian Children Perform so well in PISA? An Investigation of Western-Born Children of East Asian Descent

ERIC Educational Resources Information Center

Jerrim, John

2015-01-01

A small group of high-performing East Asian economies dominate the top of the Programme for International Student Assessment (PISA) rankings. This has caught the attention of Western policymakers, who want to know why East Asian children obtain such high PISA scores, and what can be done to replicate their success. In this paper I investigate…

75 FR 38723 - Safety Zone; St. Ignace 4th of July Fireworks, East Moran Bay, Lake Huron, St. Ignace, MI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-06

...-AA00 Safety Zone; St. Ignace 4th of July Fireworks, East Moran Bay, Lake Huron, St. Ignace, MI AGENCY... safety zone on East Moran Bay, Lake Huron, St. Ignace, Michigan. This zone is intended to restrict vessels from a portion of East Moran Bay during the St. Ignace 4th of July Fireworks display, July 4, 2010...

View from the East: Arab Perceptions of United States Presence and Policy

DTIC Science & Technology

2003-02-01

View from the East: Arab Perceptions of United States Presence and Policy Brent J . Talbot and Michael B. Meyer INSS...IMPLICATIONS FOR US POLICY IN THE MIDDLE EAST, Brent J . Talbot Introduction 1 The Perception Problem 3 The Consensus Issue 11...THE ARAB PERCEPTION AND CONSENSUS PROBLEMS: IMPLICATIONS FOR US POLICY IN THE MIDDLE EAST, Brent J . Talbot EXECUTIVE SUMMARY This paper is a

Annotated list of Tettigoniidae (Orthoptera) from the East Usambara Mountains, Tanzania and new Tettigoniidae species from East Africa.

PubMed

Hemp, Claudia

2013-12-21

A list of the Tettigoniidae (Orthoptera) of the East Usambara Mountains is presented and 16 new species are described from East Africa. A total number of 29 Tettigoniidae species is recorded for the East Usambara Mountains. New species are described from the Shimba Hills in Kenya, coastal Tanzania from the Kazimzumbwi forest reserve, Mt Kilimanjaro, the East and West Usambara and Uluguru Mountains in Tanzania, namely in Conocephalinae Afroagraecia pwania n. sp., Afroagraecia shimbaensis n. sp., Afroanthracites discolor n. sp., Afroanthracites jagoi n. sp. and Afroanthracites viridis n. sp., in Meconematinae Afrophisis flagellata n. sp., Afrophisis kisarawe n. sp., Afrophisis mazumbaiensis n. sp. and Afrophisis pseudoflagellata n. sp., in Hexacentrinae Aerotegmina megaloptera n. sp., in Mecopodinae Apteroscirtus cristatus n. sp., and A. planidorsatus n. sp., in Phaneropterinae Gelotopoia amabilis n. sp., and in Pseudophyllinae Cymatomerella pardopunctata n. sp. and Cymatomera viridimaculata n. sp. Seven species are endemic to the East Usambara Mountains which are 25% of the recorded forest-bound bush crickets. The Tettigoniidae fauna is compared between the East Usambara Mountains and Mt Kilimanjaro and mechanisms of speciation discussed in Orthoptera for the area. New Tettigoniidae records are given for Mt Kilimanjaro (Oxyecous apertus Ragge, Tropidonotacris grandis Ragge and Eurycorypha conclusa Hemp).

Genetic diversity of Diaphorina citri and its endosymbionts across east and south-east Asia.

PubMed

Wang, Yanjing; Xu, Changbao; Tian, Mingyi; Deng, Xiaoling; Cen, Yijing; He, Yurong

2017-10-01

Diaphorina citri is the vector of 'Candidatus Liberibacter asiaticus', the most widespread pathogen associated huanglongbing, the most serious disease of citrus. To enhance our understanding of the distribution and origin of the psyllid, we investigated the genetic diversity and population structures of 24 populations in Asia and one from Florida based on the mtCOI gene. Simultaneously, genetic diversity and population structures of the primary endosymbiont (P-endosymbiont) 'Candidatus Carsonella ruddii' and secondary endosymbiont (S-endosymbiont) 'Candidatus Profftella armatura' of D. citri were determined with the housekeeping genes. AMOVA analysis indicated that populations of D. citri and its endosymbionts in east and south-east Asia were genetically distinct from populations in Pakistan and Florida. Furthermore, P-endosymbiont populations displayed a strong geographical structure across east and south-east Asia, while low genetic diversity indicated the absence of genetic structure among the populations of D. citri and its S-endosymbiont across these regions. The 'Ca. C. ruddii' is more diverse and structured than the D. citri and the 'Ca. P. armatura' across east and south-east Asia. Multiple introductions of the psyllid have occurred in China. Management application for controlling the pest is proposed based on the genetic information of D. citri and its endosymbionts. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Deep History of East Asian Populations Revealed Through Genetic Analysis of the Ainu

PubMed Central

Jeong, Choongwon; Nakagome, Shigeki; Di Rienzo, Anna

2016-01-01

Despite recent advances in population genomics, much remains to be elucidated with regard to East Asian population history. The Ainu, a hunter–gatherer population of northern Japan and Sakhalin island of Russia, are thought to be key to elucidating the prehistory of Japan and the peopling of East Asia. Here, we study the genetic relationship of the Ainu with other East Asian and Siberian populations outside the Japanese archipelago using genome-wide genotyping data. We find that the Ainu represent a deep branch of East Asian diversity more basal than all present-day East Asian farmers. However, we did not find a genetic connection between the Ainu and populations of the Tibetan plateau, rejecting their long-held hypothetical connection based on Y chromosome data. Unlike all other East Asian populations investigated, the Ainu have a closer genetic relationship with northeast Siberians than with central Siberians, suggesting ancient connections among populations around the Sea of Okhotsk. We also detect a recent genetic contribution of the Ainu to nearby populations, but no evidence for reciprocal recent gene flow is observed. Whole genome sequencing of contemporary and ancient Ainu individuals will be helpful to understand the details of the deep history of East Asians. PMID:26500257

Mantle xenocrysts of Chompolo field of the alkaline volcanics, Aldan shield, South Yakutia.

NASA Astrophysics Data System (ADS)

Nikolenko, Evgeny; Tychkov, Nikolay; Afanasiev, Valentin

2015-04-01

New mineralogical and chemical constraints for 10 dikes, veins (360-800m) and pipes (60-110 m) of Chompolo field discovered in 1957-1958 are discussed. Feld is located within Central Aldan Archean and Paleoproterozoic granulite-orthogneiss superterrane of Aldan-Stanovoy Shield, with peak of metamorphism - 2.1-1.9 Ga (Smelov, Timofeev, 2007). Originally (Shilina and Zeitlin 1959) and later (Kostrovitsky and Garanin 1992, Ashchepkov, Vladykin et al. 2001) these rocks were classified as kimberlites by mineralogy including pyrope, Cr spinel, and Cr diopside. Panina and Vladykin (1994), Davies et al, (2006) identified them as lamprophyres and lamproites. The age of Chompolo rocks is pre-Jurassic (Vladimirov et. al., 1989) dated by 40Ar/39Ar as 164.7±1 Ma (233.7±2.2 next plato)(unpublished Ashchepkov). The Rb-Sr isochron for lamprophyre "intrusions 104" indicate later age of 131±4 Ma (Zaitsev, Smelov, 2010). Magmatic bodies (Aldanskaya, Sputnik, Gornaya, Ogonek, Perevalnaya, Kilier-E) were studied during 2012-2013 fieldworks. Most of igneous rocks occur as inequigranular volcanic breccias with micro- or crypto-crystalline groundmass of K feldspar (up to 16.3 wt.% K2O, up to 3.2 wt.% FeO), chlorite, opaque minerals, melanocratic xenocrysts and phenocrysts (garnet, pyroxene, amphibole, Cr spinel, apatite, zircon, mica), and abundant xenogenic fragments of wallrock and crystalline basement. Garnet chemistry records the presence of mantle and crustal material. Mantle garnets lack the common megacryst, wehrlite, and high-temperature lherzolite varieties. Mantle mineralization prevails in the Aldan dike and the Sputnik, Gornaya, and Ogonek pipes, while crustal and elcogitic material is in the Perevalnaya and Kilier-E pipes. The Cr spinel consists of (in wt%) 3.5 to 50.9 Al2O3, 18.6-63.5 wt% Cr2O3, 6.1 to 19.1 MgO, and 0 to 1.61 TiO2. Al and Cr in spinels are in inverse proportion. The Chompolo alkaline volcanic rocks are most similar to the Central Aldan lamproites in trace-element compositions. Anomalously low HFSE (Nb, Ta, Ti), low HREE, and high La/Nb ratios in multi-element spectra indicate high oxygen fugacity and possible crustal contamination (or influence of fluids). Cpx thermobarometry (Nimis et al., 2001) indicate a lithospheric thickness beneath Chompolo field > 130 km (4.1 GPa) supported by P38 monomineral garnet barometer (Grütter et al., 2006). We infer that the Chompolo alkali volcanic rocks are not kimberlites but rather low-Ti alkaline rocks similar to those in the Aldan province. Unlike the Aldan lamproite (Tobuk-Khatystyr field, etc.), the Chompolo rocks contain both crustal and mantle minerals. The compositions of pyrope and Cr spinel, as well as thermobarmetry estimates of lithospheric thickness at the time of magmatic activity, indicate that the Chompolo rocks are diamond-barren. RFBR 15-05-04885. Smelov A.P., Timofeev V.F. Gondwana Research. 2007, 12:279-288 Zaitsev A.I., Smelov A.P. DPMGI SB RAS. Y akutsk. 2010, p. 108 Kostrovitsky S.I., Garanin V.K. Zapiski RMO. 1992, 1: 67-72 Shilin, G., S. Zeitlin, Sov.Geol. 1959, 10:132-136. Panina, L. and N. Vladykin, Russian Geology and Geophysics. 1994, 35(12): 100-113. Davies G. et al. Journal of Petrology, 2006, 47(6): 1119-1146.

Ti-in-zircon thermometry: applications and limitations

NASA Astrophysics Data System (ADS)

Fu, Bin; Page, F. Zeb; Cavosie, Aaron J.; Fournelle, John; Kita, Noriko T.; Lackey, Jade Star; Wilde, Simon A.; Valley, John W.

2008-08-01

The titanium concentrations of 484 zircons with U-Pb ages of ˜1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413-433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (˜15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced a_{TiO2} or a_{SiO2}, variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10-15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio, or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and a_{TiO2}, are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock SiO2 and HfO2 for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO2 and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition.

Ti-in-Zircon Thermometer: Preliminary Results

NASA Astrophysics Data System (ADS)

Fu, B.; Cavosie, A. J.; Clechenko, C. C.; Fournelle, J.; Kita, N. T.; Lackey, J.; Page, F.; Wilde, S. A.; Valley, J. W.

2005-12-01

The titanium in zircon thermometer has been applied to 167 zircons from diverse rock types. These rocks include metamorphosed anorthosite and gabbro (1.15 Ga, intrusion age), and unmetamorphosed granitic pegmatite (0.9 Ga) from the Adirondack Highlands; metaluminous and peraluminous granites (114-90 Ma) of the Sierra Nevada Batholith; megacrysts from kimberlite pipes in southern Africa, Brazil, and Siberia; and detrital zircons (4.4-3.9 Ga) of metaconglomerate from Jack Hills, Western Australia. Titanium concentration in zircon was analysed using a CAMECA IMS-1280 ion microprobe (see Page et al., this volume). Spot analyses were correlated to U-Pb SHRIMP pits especially for Adirondack and Jack Hills zircons. The majority of zircons have Ti-content less than 10 ppm. Variability, in excess of analytical precision, within individual zircons is observed in about one-third of crystals. In general, there is no systematic change in Ti from core to rim (identified by cathodoluminescence) of zircons, or with regard to age, U content, Th/U ratio, or U-Pb age concordance for these non-metamict grains. The average temperatures for zircon crystallization in different rock suites using the experimental/empirical calibration of Watson and Harrison (W&H, 2005, Science 308:841), assuming the presence of rutile and quartz, are estimated to be: anorthosite 735±41°C (1SD, n=24; Ti = 10±5 ppm); metagabbro 714±31°C (n=19; Ti = 8±4 ppm); Adirondack pegmatite 500±16°C (n=5; Ti = 0.3±0.1 ppm); metaluminous and peraluminous granites from Sierra Nevada 681±67°C (n=53; Ti = 6±5 ppm) and 613±75°C (n=68; Ti = 3±3 ppm); kimberlite megacrysts 740±64°C (n=169; Ti = 14±13 ppm) (Page et al., this volume); and detrital zircons from Jack Hills metaconglomerate 718±63°C (n=64; Ti = 10±9 ppm). Most of the host rocks contain ilmenite or titanite suggesting that α(TiO2)>0.5, but rutile activity is unknown for megacrysts and detrital zircons. Pegmatite contains no Ti-rich minerals, permissive of low rutile activity. Peraluminous granites have lower whole-rock TiO2 content (0.02-0.21 wt.%) than metaluminous granites (0.54-0.91 wt.%), and both have similar zircon saturation temperatures (710-780°C). The low Ti content and apparent temperature in zircons from anorthosite and metagabbro (magmatic T = ca. 1000-1100°C) and the homogeneity of igneous zircon cores vs. metamorphic rims in metagabbro suggest that Ti content was reset during granulite-facies metamorphism (750°C, 1.0 Ga), in contrast to the current estimate of extremely low diffusivity of Ti in zircon. The Ti contents of >3.9 Ga Jack Hills detrital zircons are consistent with previously published data that were used to constrain magmatic temperature and thus the composition of unknown host rocks (W&H, 2005, Science 308:841). However, these values overlap those from both felsic and mafic rocks, and the Ti data are not sufficient to independently identify parent melt chemistry unless post-crystallization changes can be ruled out. The best evidence of pre-4 Ga evolved crust is provided by previously reported oxygen isotope ratios and felsic mineral inclusions in zircon (see Cavosie et al., 2005, EPSL 235:663).

Diamond growth beneath Letlhakane established by Re-Os and Sm-Nd systematics of individual eclogitic sulphide, garnet and clinopyroxene inclusions

NASA Astrophysics Data System (ADS)

Gress, Michael U.; Pearson, D. Graham; Timmerman, Suzette; Chinn, Ingrid L.; Koornneef, Janne M.; Davies, Gareth R.

2017-04-01

The diamondiferous Letlhakane kimberlites are part of the Orapa kimberlite cluster (˜ 93.1 Ma) in north-eastern Botswana, located on the edge of the Zimbabwe Craton, close to the Proterozoic Magondi Mobile Belt. Here we report the first Re-Os ages of six individual eclogitic sulphide inclusions (3.0 to 35.7μg) from Letlhakane diamonds along with their rhenium, osmium, iridium and platinum concentrations, and carbon isotope, nitrogen content and N-aggregation data from the corresponding growth zones of the host diamonds. For the first time, Re-Os data will be compared to Sm-Nd ages of individual eclogitic silicate inclusions recovered from the same diamonds using a Triton Plus equipped with four 1013Ω amplifiers. The analysed inclusion set currently encompasses pairs of individual sulphides from two diamonds (LK040 sf4 & 5, LK113 sf1 & 2) and two sulphide inclusions from separate diamonds (LK048, LK362). Ongoing work will determine the Sm-Nd ages and element composition of multiple individual eclogitic garnets (LK113/LK362, n=4) and an eclogitic clinopyroxene (LK040) inclusion. TMA ages of the six sulphides range from 1.06 to 2.38 Ga (± 0.1 to 0.54 Ga) with Re and Os contents between 7 and 68 ppb and 0.03 and 0.3 ppb, respectively. The host diamond growth zones have low nitrogen abundances (21 to 43 ppm N) and high N-aggregation (53 to 90% IaB). Carbon isotope data suggests the involvement of crustal carbon (δ13C between -19.3 to -22.7 ± 0.2 per mill) during diamond precipitation. Cathodoluminescence imaging of central plates from LK040 and LK113 displays homogenous internal structure with no distinct zonation. The two sulphide inclusions from LK040 define an 'isochron' of 0.92 ± 0.23 Ga (2SD) with initial 187Os/188Os = 1.31 ± 0.24. Sulphides from LK113 have clear imposed diamond morphology and indicate diamond formation at 0.93 ± 0.36 Ga (2SD) with initial 187Os/188Os = 0.69 ± 0.44. The variation in the initial 187Os/188Os does not justify including these inclusions (or any from other diamonds) on the same isochron and implies an extremely heterogeneous diamond crystallisation environment that incorporated recycled Os. C1-normalized osmium, iridium and platinum (PGE) compositions from the analysed sulphide inclusions display enrichment in Ir (3.4 to 33) and Pt (2.3 to 28.1) in comparison to eclogitic xenolith data from Orapa that are depleted relative to chondrite. The Re-Os isochrons determined in this study are within error of previously reported ages from the adjacent (˜40km) Orapa diamond mine (1.0 to 2.9 Ga) based on sulphide inclusions and a multi-point 990 ± 50 Ma (2SD) isochron for composite (n=730) silicate inclusions. Together with additional new Sm-Nd isochron age determinations from individual silicate inclusions from Letlhakane (2.3 ± 0.02 (n = 3); 1.0 ± 0.14 (n = 4) and 0.25 ± 0.04 Ga (n = 3), all 2SE) these data suggest a phase of Mesoproterozoic diamond formation as well as Neoarchean/Paleoproterozoic and Mesozoic diamond growth, in punctuated events spanning >2.0 Ga.

High-Precision U-Pb Geochronology of Ice River Perovskite: A Possible Interlaboratory and Intertechnique EARTHTIME Standard

NASA Astrophysics Data System (ADS)

Burgess, S. D.; Bowring, S. A.; Heaman, L. M.

2012-12-01

Accurate and precise U-Pb geochronology of accessory phases other than zircon are required for dating some LIP basalts or determining the temporal patterns of kimberlite pipes, for example. Advances in precision and accuracy lead directly to an increase in the complexity of questions that can be posed. U-Pb geochronology of perovskite (CaTiO3) has been applied to silica-undersaturated basalts, carbonatites, alkaline igneous rocks, and kimberlites. Most published IDTIMS perovskite dates have 2-sigma precisions at the ~0.2% level for weighted mean 206Pb/238U dates, much less than possible with IDTIMS analyses of zircons, which limits the applicability of perovskite in high-precision applications. Precision on perovskite dates is lower than zircon because of common Pb, which in some cases can be up to 50% of the total Pb and must be corrected for and accurately partitioned between blank and initial. Relatively small changes in the composition of common Pb can result in inaccurate but precise dates. In many cases minerals with significant common Pb are corrected using Stacey and Kramers (1975) two stage Pb evolution model. This can be done without serious consequence to the final date for minerals with high U/Pb ratios. In the more common case where U/Pb ratios are relatively low and the proportion of common Pb is large, applying a model-derived Pb isotopic composition rather than measuring it directly can introduce percent-level inaccuracy to dates calculated with precisely known U/Pb ratios. Direct measurement of the common Pb composition can be done on a U-poor mineral that co-crystallized with perovskite; feldspar and clinopyroxene are commonly used. Clinopyroxene can contain significant in-grown radiogenic Pb and our experiments indicate that it is not eliminated by aggressive step-wise leaching. The U/Pb ratio in clinopyroxene is generally low (20 < mu < 50) but significant. Other workers (e.g. Kamo et al., 2003; Corfu and Dahlgren, 2008), have used two methods to determine the amount of ingrown Pb. First, by measuring the U/Pb ratio in clinopyroxene and assuming a crystallization age the amount of ingrown Pb can be calculated. Second, by assuming that perovskite and clinopyroxene (± other phases) are isochronous, the initial Pb isotopic composition can be calculated using the y-intercept on 206Pb/238U, 207Pb/235U, and 3-D isochron diagrams. To further develop a perovskite mineral standard for use in high-precision dating applications, we have focused on single grains/fragments of perovskite and multi-grain clinopyroxene fractions from a melteigite sample (IR90.3) within the Ice River complex, a zoned alkaline-ultramafic intrusion in southeastern British Columbia. Perovskite from this sample has variable measured 206Pb/204Pb (22-263), making this an ideal sample on which to test the sensitivity of the date on grains with variable amounts of radiogenic Pb to changes in common Pb composition. Using co-existing clinopyroxene for the initial common Pb composition by both direct measurement and by the isochron method allows us to calculate an accurate weighted-mean 206Pb/238U date on perovskite at the < 0.1% level, which overlaps within uncertainty for the two different methods. We recommend the Ice River 90.3 perovskite as a suitable EARTHTIME standard for interlaboratory and intertechnique comparison.

Iron speciation and redox state of mantle eclogites: Implications for ancient volatile cycles during mantle melting and oceanic crust subduction

NASA Astrophysics Data System (ADS)

Aulbach, Sonja; Woodand, Alan; Vasilyev, Prokopiy; Viljoen, Fanus

2017-04-01

Kimberlite-borne mantle eclogite xenoliths of Archaean and Palaeoproterozoic age are commonly interpreted as representing former oceanic crust. As such, they may retain a memory of the redox state of the ancient convecting mantle sources that gave rise to their magmatic protoliths and which controls the speciation of volatiles in planetary interiors. Mantle eclogite suites commonly include both cumulate and variably evolved extrusive varieties [1], which may be characterised by initial differences in Fe3+/Fetotal. Recent Fe-based oxybarometry shows mantle eclogites to have fO2 relative to the fayalite-magnetite-quartz buffer (ΔFMQ) of -3 to 0, whereby low fO2 relative to modern MORB may relate to subduction of more reducing Archaean oceanic crust or loss of ferric Fe during partial melt loss [2]. Indeed, using V/Sc as a redox proxy, it was recently shown that Archaean mantle eclogites are more reduced than modern MORB (ΔFMQ-1.3 vs. ΔFMQ -0.4) [3]. However, in the warmer ancient mantle, they were also subject to modification due to partial melt loss upon recycling and, after capture in the cratonic mantle lithosphere, may be overprinted by interaction with metasomatic melts and fluids. In order to help further constrain the redox state of mantle eclogites and unravel the effect of primary and secondary processes, we measured Fe3+/Fetotal by Mössbauer in garnet from mantle eclogites from the Lace kimberlite (Kaapvaal craton), comprising samples with melt- and cumulate-like oceanic crustal protoliths as well as metasomatised samples. Fe3+/ΣFe in garnet shows a strong negative correlation with jadeite content and bulk-rock Li and Cu abundances, suggesting increased partitioning of Fe3+ into jadeite in the presence of monovalent cations with which it can form coupled substitutions. Broad negative correlation with whole-rock Al2O3/TiO2 and positive correlation with ΣREE are interpreted as incompatible behaviour of Fe3+ during olivine-plagioclase accumulation (exclusion of TiO2 and REE). NMORB-normalised Nd/Yb, as a proxy of partial melt loss from subducting oceanic crust (<1) and metasomatism by typically LREE-enriched liquids (>1), shows no relationship with Fe3+/ΣFe. ΔFMQ, calculated using recently calibrated oxybarometers [2,4], broadly decreases with increasing pressure, which is ascribed to increasing garnet modes in metabasalts into which Fe3+ can be sequestered, similar to peridotite. The very low Fe3+/ΣFe, like V/Sc, appears to be a relatively robust indicator of low-pressure igneous processes and, potentially, the redox state of the ambient convecting mantle source to the protoliths of mantle eclogites. In contrast, Fe-based fO2 predominantly reflects pressure and bulk composition, and controls the speciation and mobility of volatiles in mafic heterogeneities during subduction and after emplacement in the cratonic mantle. The highly reduced nature of Archaean oceanic crust combined with further reduction upon pressure increase suggests that refractory graphite/diamond will be the stable carbon species. This may have prevented significant carbon output in Archaean subduction zones. [1] Aulbach and Jacob (2016) Lithos 262: 586-605; [2] Stagno et al. (2015) Contrib Mineral Petrol 42: 207-219; [3] Aulbach and Stagno (2016) Geology 44: 751-754; [4] Vasilyev (2016) PhD Thesis, Australian Nat Univ

EAST (FRONT) AND NORTH (SIDE) ELEVATIONS OF BUILDING. view TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

EAST (FRONT) AND NORTH (SIDE) ELEVATIONS OF BUILDING. view TO SOUTHWEST. - Plattsburgh Air Force Base, Target Intelligence Training Building-Combat Center, Off Connecticut Road, east of Idaho Avenue, Plattsburgh, Clinton County, NY

NORTH (SIDE) AND EAST (FRONT) ELEVATIONS OF BUILDING. view TO ...

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NORTH (SIDE) AND EAST (FRONT) ELEVATIONS OF BUILDING. view TO SOUTH. - Plattsburgh Air Force Base, Target Intelligence Training Building-Combat Center, Off Connecticut Road, east of Idaho Avenue, Plattsburgh, Clinton County, NY

EAST (FRONT) AND SOUTH (SIDE) ELEVATIONS OF BUILDING. view TO ...

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EAST (FRONT) AND SOUTH (SIDE) ELEVATIONS OF BUILDING. view TO WEST. - Plattsburgh Air Force Base, Target Intelligence Training Building-Combat Center, Off Connecticut Road, east of Idaho Avenue, Plattsburgh, Clinton County, NY

2. WEST (FRONT) ELEVATION, LOOKING EAST, WITH SCALE (AND TOM ...

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2. WEST (FRONT) ELEVATION, LOOKING EAST, WITH SCALE (AND TOM SHAW, S.C.ARCHIVES & HISTORY) - Cowpens Iron Furnace, 1000 feet East of County Road 34 & Cherokee Creek Bridge, Gaffney, Cherokee County, SC

4. INTERIOR OF BUILDING 313, SHOWING LABORATORY. VIEW TO EAST. ...

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4. INTERIOR OF BUILDING 313, SHOWING LABORATORY. VIEW TO EAST. - Rocky Mountain Arsenal, Laboratory Building, 510 feet South of December Seventh Avenue; 175 feet East of D Street, Commerce City, Adams County, CO

DETAIL OF VALVE TOWER SHOWING SLUICE GATE ON EAST SIDE ...

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DETAIL OF VALVE TOWER SHOWING SLUICE GATE ON EAST SIDE OF TOWER. VIEW FACING WEST - Schofield Barracks Military Reservation, Ku Tree Reservoir, Valve Tower, Kalakoa Stream, East Range, Wahiawa, Honolulu County, HI

Looking East at Motor Control System, Clarity Columns and Blend ...

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Looking East at Motor Control System, Clarity Columns and Blend Tank Along East Side of Recycle Recovery Building - Hematite Fuel Fabrication Facility, Recycle Recovery Building, 3300 State Road P, Festus, Jefferson County, MO

2. Building J oblique, showing south and east elevations from ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. Building J oblique, showing south and east elevations from Lena Street. View looking northwest. - Daniel F. Waters Germantown Dye Works, Building J, 37-55 East Wister Street, Philadelphia, Philadelphia County, PA

The Smokey Hollow Community, Informal boundaries by street name: North ...

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The Smokey Hollow Community, Informal boundaries by street name: North to South: East Jefferson Street to East Van Buren Street. West to East: South Gadsden Street to Marvin Street., Tallahassee, Leon County, FL

1. Historic American Buildings Survey, Bill Engdahl for HedrichBlessing, Photographers, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. Historic American Buildings Survey, Bill Engdahl for Hedrich-Blessing, Photographers, February, 1979 DISTANT VIEW FROM EAST. - Sacred Heart Roman Catholic Church, East Sixth & East Elizabeth Streets, Brownsville, Cameron County, TX

1. WILLIAM ELLIOT CABIN AND OUTBUILDING, CABIN EAST FRONT AND ...

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1. WILLIAM ELLIOT CABIN AND OUTBUILDING, CABIN EAST FRONT AND SOUTH SIDE, OUTBUILDING EAST REAR AND SOUTH SIDES - Liberty Historic District, William Elliot Cabin, Route 2, Cle Elum, Liberty, Kittitas County, WA

7. ORIGINAL SOUTH SIDE, EAST PART, ALSO SHOWING PATH FROM ...

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7. ORIGINAL SOUTH SIDE, EAST PART, ALSO SHOWING PATH FROM EAST FRONT LEADING TO CENTRAL CAMPUS. - U.S. Geological Survey, Rock Magnetics Laboratory, 345 Middlefield Road, Menlo Park, San Mateo County, CA

Differences in sexual guilt and desire in east Asian and Euro-Canadian men.

PubMed

Brotto, Lori A; Woo, Jane S T; Gorzalka, Boris B

2012-01-01

Differences in sexual desire between individuals of East Asian and European descent are well-documented, with East Asian individuals reporting lower sexual desire. The mechanisms that underlie this disparity have received little empirical attention. Recent research has found that sex guilt, "a generalized expectancy for self-mediated punishment for violating or for anticipating violating standards of proper sexual conduct" (Mosher & Cross, 1971 , p. 27), mediates the relationship between culture and sexual desire in East Asian and Euro-Canadian women. The goal of this study was to explore this role of sex guilt in men. Male Euro-Canadian (n = 38) and East Asian (n = 45) university students completed online questionnaires. The East Asian men reported significantly lower sexual desire and significantly higher sex guilt. Sex guilt was a significant mediator of the relationship between ethnicity and sexual desire, as well as a significant mediator between mainstream acculturation and sexual desire. Among the East Asian men, mainstream acculturation was significantly and negatively correlated with sex guilt such that increasing mainstream acculturation was associated with less sex guilt. The diagnostic and clinical implications of the findings are discussed.

Winter monsoon variability and its impact on aerosol concentrations in East Asia.

PubMed

Jeong, Jaein I; Park, Rokjin J

2017-02-01

We investigate the relationship between winter aerosol concentrations over East Asia and variability in the East Asian winter monsoon (EAWM) using GEOS-Chem 3-D global chemical transport model simulations and ground-based aerosol concentration data. We find that both observed and modeled surface aerosol concentrations have strong relationships with the intensity of the EAWM over northern (30-50°N, 100-140°E) and southern (20-30°N, 100-140°E) East Asia. In strong winter monsoon years, compared to weak winter monsoon years, lower and higher surface PM 2.5 concentrations by up to 25% are shown over northern and southern East Asia, respectively. Analysis of the simulated results indicates that the southward transport of aerosols is a key process controlling changes in aerosol concentrations over East Asia associated with the EAWM. Variability in the EAWM is found to play a major role in interannual variations in aerosol concentrations; consequently, changes in the EAWM will be important for understanding future changes in wintertime air quality over East Asia. Copyright © 2016 Elsevier Ltd. All rights reserved.

A Review of Marine Geophysical Constraints on the Motion Between East and West Antarctica in the Cenozoic (Invited)

NASA Astrophysics Data System (ADS)

Cande, S. C.; Stock, J. M.

2010-12-01

Motion between East and West Antarctica in the Late Cretaceous and Cenozoic is derived by summing the plate circuit(s) linking East Antarctica to Australia to the Lord Howe Rise to the Pacific plate to West Antarctica (the Aus-Pac plate circuit). We discuss this motion in two parts: motion before and after 42 Ma. For the younger time interval, motion is directly constrained by magnetic anomalies in the Adare Basin, which opened by ultraslow seafloor spreading between 42 and 26 Ma (anomalies 18 to 9). The Adare Basin magnetic anomaly constraints can be combined with magnetic anomaly and fracture zone data from the SEIR (Aus-East Ant to the west of the Balleny FZ and Aus - West Ant to the east) to set up an Aus-East Ant - West Ant three-plate problem. The original solution of this three-plate configuration (Cande et al., 2000) only had data from a very short section of the Adare Basin and obtained an answer with very large uncertainties on the East-West Ant rotation. Better estimates of the East-West Ant rotation have been calculated by adding constraints based on seismically controlled estimates of extension in the Victoria Land Basin (Davey et al., 2006) and constraints from Damaske et al’s (2007) detailed aeromagnetic survey of the Adare Basin and adjacent Northern Basin (Granot et al., 2010). Currently, we are working on improving the accuracy of rotations for the post-42 Ma time interval by taking advantage of an unusual plate geometry that enables us to solve a five-boundary, four-plate configuration. Specifically, motion between the four plates (East Ant, West Ant, Aus and Pac) encompasses two related triple junction systems with five spreading ridge segments (Aus-East Ant, Aus-West Ant, Aus-Pac, Pac-West Ant and East Ant-West Ant) which can be combined and solved simultaneously. For the older, pre-42 Ma time interval, the only way to calculate motion between East and West Antarctica is via the long Aus-Pac plate circuit (although it is possible that magnetic anomalies formed by direct spreading between East and West Antarctica, akin to the Adare Basin anomalies, may exist in the poorly mapped Central Basin between the Hallett Ridge and the Iselin Bank). The weakest link in this time interval is the Aus - East Ant boundary; for the time interval from 84 to 42 Ma there are distinctly different results depending on how the tectonic constraints are prioritized (Royer and Rollett, 1997; Tikku and Cande, 1999; Whittaker et al., 2007). The disagreement over the pre-42 Ma motion between Australia and East Antarctica leads to large differences in the predicted motion in the Western Ross Sea and near Ellsworth Land. Another weak link in this circuit is the pattern of sea floor spreading in the Tasman Sea, which is difficult to unravel because of the complex history of motion between Australia, the Lord Howe Rise, and Tasmania (Gaina et al., 1999). Resolution of these issues is required before a well constrained history of East -West Antarctic motion back to the Late Cretaceous is obtained

Meteorological Station, showing east and south sides; view to northwest ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Meteorological Station, showing east and south sides; view to northwest - Fort McKinley, Meteorological Station, East side of Weymouth Way, approximately 225 feet south of Cove Side Drive, Great Diamond Island, Portland, Cumberland County, ME

12. NORTH WALL, SOUTH SIDE, EAST SECTION (WEST SIDE OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. NORTH WALL, SOUTH SIDE, EAST SECTION (WEST SIDE OF EAST WING IN BACKGROUND) - Fort Sam Houston, San Antonio Quartermaster Depot, Northwest corner of New Braunfels Avenue & Grayson Street, San Antonio, Bexar County, TX

6. GENERAL WIDE VIEW SHOWING EAST (SOUTHEAST) SIDE, LOOKING WEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. GENERAL WIDE VIEW SHOWING EAST (SOUTHEAST) SIDE, LOOKING WEST ACROSS TURNING BASIN; FREIGHTER LOADING IN FOREGROUND - Oakland Army Base, Transit Shed, East of Dunkirk Street & South of Burma Road, Oakland, Alameda County, CA

3. OBLIQUE GENERAL VIEW SHOWING EAST CORNER OF SHED, WITH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. OBLIQUE GENERAL VIEW SHOWING EAST CORNER OF SHED, WITH RAILROAD TRACKS PASSING UNDER DERRICK ALONG WHARF - Oakland Army Base, Transit Shed, East of Dunkirk Street & South of Burma Road, Oakland, Alameda County, CA

3. VIEW EAST OF TAILINGS OF MERCURY RETORT. SCOOP FOR ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. VIEW EAST OF TAILINGS OF MERCURY RETORT. SCOOP FOR EXTRACTING MERCURY VISIBLE IN CENTER OF PHOTOGRAPH. (OCTOBER, 1995) - McCormick Group Mine, Mercury Retort, East slope of Buckskin Mountain, Paradise Valley, Humboldt County, NV

2. View to east. Oblique view of downstream side of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. View to east. Oblique view of downstream side of bridge and east pier. (135mm lens) - South Fork Trinity River Bridge, State Highway 299 spanning South Fork Trinity River, Salyer, Trinity County, CA

20. VIEW OF EAST END OF SPERRY OCEAN DOCK, SHOWING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

20. VIEW OF EAST END OF SPERRY OCEAN DOCK, SHOWING SOUTH AND EAST ELEVATION, INCLUDING PORTION OF THE SPERRY OCEAN DOCK DECK, LOOKING NORTH - Puget Sound Flouring Mills, 611 Schuster Parkway, Tacoma, Pierce County, WA

4. SOUTH AND EAST SIDES OF BUILDING 724. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. SOUTH AND EAST SIDES OF BUILDING 724. VIEW TO NORTHWEST. - Rocky Mountain Arsenal, Pesticide Incinerator-Precipitator, 260 feet South of December Seventh Avenue; 1840 feet East of D Street, Commerce City, Adams County, CO

2. EAST AND SOUTH SIDES OF BUILDING 724. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EAST AND SOUTH SIDES OF BUILDING 724. VIEW TO NORTHWEST. - Rocky Mountain Arsenal, Pesticide Incinerator-Precipitator, 260 feet South of December Seventh Avenue; 1840 feet East of D Street, Commerce City, Adams County, CO

DETAIL OF MAIN ENTRANCE ON EAST (FRONT) ELEVATION OF BUILDING. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

DETAIL OF MAIN ENTRANCE ON EAST (FRONT) ELEVATION OF BUILDING. view TO SOUTHWEST. - Plattsburgh Air Force Base, Target Intelligence Training Building-Combat Center, Off Connecticut Road, east of Idaho Avenue, Plattsburgh, Clinton County, NY

1. SOUTH AND EAST SIDES OF BUILDING 1605. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. SOUTH AND EAST SIDES OF BUILDING 1605. VIEW TO NORTHWEST. - Rocky Mountain Arsenal, Fuse Detonater Magazine, 166 feet South of Ninth Avenue; 2500 feet East of D Street, Commerce City, Adams County, CO

2. EAST ELEVATION OF POWER PLANT TEST STAND (HORIZONTAL TEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EAST ELEVATION OF POWER PLANT TEST STAND (HORIZONTAL TEST STAND REMNANTS OF BUILDING-BLANK WHITE WALL ONLY ORIGINAL REMAINS. - Marshall Space Flight Center, East Test Area, Power Plant Test Stand, Huntsville, Madison County, AL

8. INTERIOR VIEW, FIRST FLOOR, NORTHEAST ROOM, EAST WALL, ORIGINAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. INTERIOR VIEW, FIRST FLOOR, NORTHEAST ROOM, EAST WALL, ORIGINAL KITCHEN FIREPLACE AND BAKE OVEN, WITH SCALE - Edgemont, 212 Bridgetown Pike, 1/4 mile East of PA 413 (Middletown Township), Langhorne, Bucks County, PA

44. Detail view looking east along sidewalk on the south ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

44. Detail view looking east along sidewalk on the south side of the 300 block of East Washington Street - Washington Street Downtown Corridor, Washington Street between Alabama Street & Senate Avenue, Indianapolis, Marion County, IN

4. EAST SIDE OF BUILDING 514. VIEW TO WEST. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. EAST SIDE OF BUILDING 514. VIEW TO WEST. - Rocky Mountain Arsenal, Lewisite Reactor & Distilled Mustard Distillation Building, 420 feet South of December Seventh Avenue; 1070 feet East of D Street, Commerce City, Adams County, CO

8. INTERIOR OF BUILDING 514. VIEW TO EAST. Rocky ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. INTERIOR OF BUILDING 514. VIEW TO EAST. - Rocky Mountain Arsenal, Lewisite Reactor & Distilled Mustard Distillation Building, 420 feet South of December Seventh Avenue; 1070 feet East of D Street, Commerce City, Adams County, CO

COMBINATION SUMMER KITCHEN AND SMOKE HOUSE, VIEW TO EAST/NORTHEAST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

COMBINATION SUMMER KITCHEN AND SMOKE HOUSE, VIEW TO EAST/NORTHEAST - Kiel Farmstead, Summer Kitchen & Smokehouse, East side State Route 4, one half mile south of U.S. Route 64, Mascoutah, St. Clair County, IL

20. Living room, view to east wall and pocket doors ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

20. Living room, view to east wall and pocket doors to front parlor; view to east; 65mm lens with electronic flash illumination. - Warner Hutton House, 13495 Sousa Lane, Saratoga, Santa Clara County, CA

5. Engine room, general view looking east, engine #2 in ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Engine room, general view looking east, engine #2 in foreground (1895, now cannibalized for parts), engine #3 is in the background - East Boston Pumping Station, Chelsea Street at Chelsea Creek, Boston, Suffolk County, MA

INTERIOR DETAIL OF WINDOWS AT SOUTHERN END OF EAST WALL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR DETAIL OF WINDOWS AT SOUTHERN END OF EAST WALL OF LIVING ROOM OF PAULINE KILKER HOUSE, FACING EAST. - Pauline Kilker House, 1410 North Lincoln Avenue-3300 West Laurel Street, Tampa, Hillsborough County, FL

General view of thurmond, looking east from tracks, showing signal ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

General view of thurmond, looking east from tracks, showing signal tower in foreground and depot in background. - Chesapeake & Ohio Railroad, Thurmond Yards, East side New River, mouths of Arbuckle & Dunlop Circles, Thurmond, Fayette County, WV

East African Rift Valley, Kenya

NASA Technical Reports Server (NTRS)

1990-01-01

This rare, cloud free view of the East African Rift Valley, Kenya (1.5N, 35.5E) shows a clear view of the Turkwell River Valley, an offshoot of the African REift System. The East African Rift is part of a vast plate fracture which extends from southern Turkey, through the Red Sea, East Africa and into Mozambique. Dark green patches of forests are seen along the rift margin and tea plantations occupy the cooler higher ground.

JPRS Report East Europe.

DTIC Science & Technology

1993-01-22

Latin America to West Europe. This has been made easier by the opening of our borders, the weakness of our customs and police ser- vices, Poland’s...past two years, two large drug shipments from Latin America were seized. They may have been the first attempts to open a route. UN experts who toured...Friday in eight volumes: China, East Europe, Central Eurasia, East Asia, Near East & South Asia, Sub- Saharan Africa, Latin America , and West

Guided Socialization: Using U.S. Influence to Establish an Inter Elite Culture of Cooperation in East Asia

DTIC Science & Technology

2014-04-01

the use of bilateral agreements and alliances to isolate and power balance in East Asia constitutes a schizophrenic presentation of strategy...military posture, despite prohibitions in the Japanese constitution .17 Importantly, this process is not limited to Japan. Nationalist and anti- Great...though some motivation exists to create an effective East Asian economic order, similar in structure to NAFTA , powerful East Asian actors

Guidelines on Hair Restoration for East Asian Patients.

PubMed

Lee, In-Joon; Jung, Jae Heon; Lee, Young-Ran; Kim, Jung Chul; Hwang, Sungjoo Tommy

2016-07-01

In East Asian countries, hair transplantation is a quite common procedure for treating pattern hair loss, cosmetically correcting the hairline, and correcting eyebrow and pubic hair defects. Although there are general guidelines concerning hair transplantation, certain factors need to be addressed to make the guidelines more specific and suitable to East Asian requirements. To provide guidelines for hairline design, donor harvesting, graft preparation and placement, and medical treatment that are appropriate for hair transplantation in East Asian patients. Recommendations are based on the experience of the authors, surgeons who perform hair transplantation, and a comprehensive review of the available literature on hair transplantation in East Asians. Data on hair thickness and graft density, hairline design, and graft creation and placement techniques have been collaboratively evaluated and used to establish overall guidelines. The use of the proposed guidelines by surgeons will hopefully enhance outcomes and bring greater consistency to hair transplantation procedures for East Asian patients.

East China plains: a "basin" of ozone pollution.

PubMed

Zhao, Chun; Wang, Yuhang; Zeng, Tao

2009-03-15

Economic growth and associated pollution emissions in China are concentrated over three connected plains to the east In this work, we analyze an episode of highly elevated ozone over East China on June 9-14, 2004, using a 3-D chemical transport model. During this episode, the East China plains were under a high-pressure system, which suppressed the ventilation of pollutants from the boundary layer. Simulated ozone concentrations over a major fraction of East China reached high levels, all the way down to the Pearl River Delta region in the southern border. The convergence of pollutant emissions and population over the vast stretch of the geographically flat plains of East China makes the region susceptible to high-ozone exposure. During this episode, the high-03 region extended over an area >1 million km2, which hosts a population of >800 million people. Model results indicate that controlling anthropogenic NOx emissions effectively reduces the area with high-ozone exposure.

Distinct Geographical Distribution of the Miscanthus Accessions with Varied Biomass Enzymatic Saccharification

PubMed Central

Li, Xukai; Liao, Haofeng; Fan, Chunfen; Hu, Huizhen; Li, Ying; Li, Jing; Yi, Zili; Cai, Xiwen; Peng, Liangcai; Tu, Yuanyuan

2016-01-01

Miscanthus is a leading bioenergy candidate for biofuels, and it thus becomes essential to characterize the desire natural Miscanthus germplasm accessions with high biomass saccharification. In this study, total 171 natural Miscanthus accessions were geographically mapped using public database. According to the equation [P(H/L| East) = P(H/L∩East)/P(East)], the probability (P) parameters were calculated on relationships between geographical distributions of Miscanthus accessions in the East of China, and related factors with high(H) or low(L) values including biomass saccahrification under 1% NaOH and 1% H2SO4 pretreatments, lignocellulose features and climate conditions. Based on the maximum P value, a golden cutting line was generated from 42°25’ N, 108°22’ E to 22°58’ N, 116°28’ E on the original locations of Miscanthus accessions with high P(H|East) values (0.800–0.813), indicating that more than 90% Miscanthus accessions were originally located in the East with high biomass saccharification. Furthermore, the averaged insolation showed high P (H|East) and P(East|H) values at 0.782 and 0.754, whereas other climate factors had low P(East|H) values, suggesting that the averaged insolation is unique factor on Miscanthus distributions for biomass saccharification. In terms of cell wall compositions and wall polymer features, both hemicelluloses level and cellulose crystallinity (CrI) of Miscanthus accessions exhibited relative high P values, suggesting that they should be the major factors accounting for geographic distributions of Miscanthus accessions with high biomass digestibility. PMID:27532636

Pelvic floor muscle biometry and pelvic organ mobility in East Asian and Caucasian nulliparae.

PubMed

Cheung, R Y K; Shek, K L; Chan, S S C; Chung, T K H; Dietz, H P

2015-05-01

To compare the differences in levator ani muscle biometry and hiatal dimensions between pregnant nulliparous Caucasian and East Asian women. Offline analysis of three/four-dimensional ultrasound volume data obtained from two groups of pregnant nulliparous women, Caucasian and East Asian, was performed. Volume acquisition was performed in the late third trimester using the same method in both groups, in the context of two prospective observational studies with identical entry criteria. Pelvic organ descent and levator hiatal dimensions were assessed using the volumes acquired on Valsalva maneuver, and pubovisceral muscle thickness was measured from the volumes obtained on pelvic floor muscle contraction (PFMC). Datasets of 200 East Asian and 168 Caucasian women were analyzed. Compared with Caucasian women, East Asian women had a significantly lower body mass index. All indices of pelvic organ descent were significantly higher in the Caucasian group than in the East Asian group. The difference, expressed as a percentage, in levator hiatal area on both Valsalva maneuver and PFMC was markedly greater in Caucasian (32% vs. 19%; P < 0.001) than in East Asian (24% vs. 20%; P = 0.01) women. After controlling for potential confounders using multivariate regression analysis, racial origin remained the only significant factor associated with differences in pelvic organ descent and hiatal dimensions. The thickness and area of pubovisceral muscle were significantly higher in the East Asian group. Pregnant women of East Asian racial origin have a thicker pubovisceral muscle, smaller hiatus and less mobility of pelvic organs than do pregnant Caucasian women. Copyright © 2014 ISUOG. Published by John Wiley & Sons Ltd.

South Fork Latrine, east elevation showing structure in context, view ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

South Fork Latrine, east elevation showing structure in context, view west - Fort McKinley, South Fork Latrine, West side of East Side Drive, approximately 225 feet south of Weymouth Way, Great Diamond Island, Portland, Cumberland County, ME

East side, view of onehalf of the (open) carriage gate ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

East side, view of one-half of the (open) carriage gate (note: gate dates to CA. 1960, designed by Sam G. Stoney, fabricated by Philip Simons) - Morris-Gadsden House, 329 East Bay Street, Charleston, Charleston County, SC

2. EAST ELEVATION OF BRIDGE SEEN FROM THE NORTHEAST, SHOWING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. EAST ELEVATION OF BRIDGE SEEN FROM THE NORTHEAST, SHOWING APPROACH OF CARRS MILL ROAD FROM EAST. - Mitchell's Mill Bridge, Spanning Winter's Run on Carrs Mill Road, west of Bel Air, Bel Air, Harford County, MD

East yard, looking southwest at car repairer's locker house (left), ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

East yard, looking southwest at car repairer's locker house (left), switchment shanty (center), and material storage rack (right). - Chesapeake & Ohio Railroad, Thurmond Yards, East side New River, mouths of Arbuckle & Dunlop Circles, Thurmond, Fayette County, WV

1. NORTH AND EAST SIDES OF BUILDING 429. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. NORTH AND EAST SIDES OF BUILDING 429. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Mustard Brine Mixing Building, 1180 feet South of December Seventh Avenue; 440 feet East of D Street, Commerce City, Adams County, CO

2. NORTH AND EAST SIDES OF BUILDING 532. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. NORTH AND EAST SIDES OF BUILDING 532. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Pesticide Filling & Storage Building, 390 feet South of December Seventh Avenue; 200 feet East of D Street, Commerce City, Adams County, CO

2. D Street facade and rear (east) blank wall of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. D Street facade and rear (east) blank wall of parking garage. Farther east is 408 8th Street (National Art And Frame Company). - PMI Parking Garage, 403-407 Ninth Street, Northwest, Washington, District of Columbia, DC

LEANTO INTERIOR, LOOKING EAST. Image shows: ladder attached to south ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

LEAN-TO INTERIOR, LOOKING EAST. Image shows: ladder attached to south façade, gate separating hay storage from animal pens, and east wall construction. - Boyer Farm, Barn, 711 South Fort Casey Road, Coupeville, Island County, WA

3. NORTH AND EAST SIDES OF BUILDING 515. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. NORTH AND EAST SIDES OF BUILDING 515. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Crude Mustard Distillation Building, 550 feet South of December Seventh Avenue; 400 feet East of D Street, Commerce City, Adams County, CO

133. 24 EAST 51ST STREET, FRONT DRAWING ROOM, NORTH WALL, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

133. 24 EAST 51ST STREET, FRONT DRAWING ROOM, NORTH WALL, LEADED GLASS WINDOW WITH CARVED WOOD REVEAL AND SURROUND - Villard Houses, 451-457 Madison Avenue & 24 East Fifty-first Street, New York County, NY

10. WEST SIDE OF BRIDGE, LOOKING EAST, WITH TOM SHAW, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. WEST SIDE OF BRIDGE, LOOKING EAST, WITH TOM SHAW, SC DEPT ARCHIVES & HISTORY - Poinsett Bridge, SC Route 42, 2 miles Northwest of Route 11, 2.5 miles East of SC Route 25, Tigerville, Greenville, SC

1. NORTH AND EAST SIDES OF BUILDING 751. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. NORTH AND EAST SIDES OF BUILDING 751. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Paint & Process Shop-Surveillance Magazine, 1070 feet South of December Seventh Avenue; 2200 feet East of D Street, Commerce City, Adams County, CO

18. A southeastward aerial view of entire complex. Area east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

18. A southeastward aerial view of entire complex. Area east of Cherles Street (behind water tower in view) is not part of this project. - American Chain & Cable Company, East Princess Street (400 Block), York, York County, PA

CCC Stencil on center of east wall, interior of carpenter/blacksmith ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

CCC Stencil on center of east wall, interior of carpenter/blacksmith shop, facing east. - Camp Tulelake, Shop-Storage Building, West Side of Hill Road, 2 miles South of State Highway 161, Tulelake, Siskiyou County, CA

Is it possible to receive information about the historical geomagnetic declination from church orientations?

NASA Astrophysics Data System (ADS)

Draxler, Andrea; Rauch, Roman; Gruber, Karin; Leohardt, Roman

2013-04-01

It is widely known that the main structure of many churches was planned and built in an east-ward direction. This procedure, called "easting", was used for centuries especially in catholic structures. "Easting" usually refers to the direction of sunrise at the church patron's day. Assuming however that this direction is estimated by compasses there could be a significant correlation between the geographic orientation of the churches and the value of magnetic declination at the date of building. In Europe compasses are known since the 11th century. For this study altogether 124 churches located in lower Austria and built between 1100 to 1900 were analysed. Of primary interest is the geographic orientation of the churches, which was extracted out of georeferenced satellite images in Google Earth and the NO Atlas. The measured orientation of the church's nave is then compared to the geographic east direction as well as to the magnetic east direction, according to the magnetic field in the church's construction year which is determined by published geomagnetic field models. The resulting deviations for the geographic east direction split our data into two groups: churches that were built before 1500 and churches that were constructed after 1500. The boundary between these two data sets is marked by the Ottoman wars in the 16th century, where a lot of churches were destroyed. After 1500 the differences between the church's orientation and the geographic east direction are significantly bigger than before the Ottoman wars, so we shifted our focus for the following calculations on the time span from 1100 to 1500, where we found quite small deviations for both the geographic and the magnetic east direction. The principle idea of church orientation, usually referred to as "Easting" is to direct the church to the point of sunrise on the patron saint's day. Therefore we also calculated the solar azimuth on the patron saint's day and compared it to the orientation of the church. The differences we found were bigger than the deviations we got from the comparisons to the geographic and magnetic east directions, so this indicates that practically the solar azimuth was not used for the church's direction. Furthermore, our investigations indicate that the orientation of the investigated churches is more likely to be related to the geographic east direction than to magnetic east.

Clinical and diagnostic features of East Coast fever (Theileria parva) infection of cattle.

PubMed

Irvin, A D; Mwamachi, D M

1983-08-27

East Coast fever is a tick-borne protozoal disease affecting cattle in a large part of East and Central Africa. Since the vector occurs over an even wider range there is considerable potential for the disease to spread to countries which are currently disease free. This article, describing the clinical and diagnostic features of East Coast fever, may remind authorities in these countries of the potential hazards posed by the disease.

Archaeological Investigations on the East Fork of the Salmon River, Custer County, Idaho.

DTIC Science & Technology

1984-01-01

coniferous environment in addition to pine marten (Martes americana), red squirrel (Tamiasciurus hudsonicus), porcupine (Erithizon dorsatum), mountain vole...can be seen in small herds throughout the East Fork valley from the Salmon River to Big Boulder Creek. Two bands of Rocky Mountain bighorn sheep...utilize the Challis Planning Unit, one on the East Fork and the other in the Birch Creek area. The East Fork herd is comprised of approximately 50-70

Geochemical provenance of sediments from the northern East China Sea document a gradual migration of the Asian Monsoon belt over the past 400,000 years

NASA Astrophysics Data System (ADS)

Beny, François; Toucanne, Samuel; Skonieczny, Charlotte; Bayon, Germain; Ziegler, Martin

2018-06-01

The reconstruction of the long-term evolution of the East Asian Monsoon remains controversial. In this study, we aim to give a new outlook on this evolution by studying a 400 kyr long sediment record (U1429) from the northern East China Sea recovered during IODP Expedition 346. Neodymium isotopic ratios and rare earth element concentrations of different grain-size fractions reveal significant provenance changes of the sediments in the East China Sea between East Asian continental sources (mainly Yellow River) and sediment contributions from the Japanese Archipelago. These provenance changes are interpreted as the direct impact of sea level changes, due to the reorganization of East Asian river mouth locations and ocean circulation on the East China Sea shelf, and latitudinal shifts of the intertropical convergence zone (ITCZ) from the interior of Asia to the western North Pacific Ocean. Our data reveal the dominance of winter and summer monsoons during glacial and interglacial periods, respectively, except for glacial MIS 6d (∼150-180 ka) during which unexpected summer monsoon dominated conditions prevailed. Finally, our data suggests a possible strengthening of the interglacial summer monsoon rainfalls over the East Asian continent and Japan throughout the past 400 kyr, and between MIS 11 and MIS 5 in particular. This could result from a gradual northward migration of the ITCZ.

Summertime land-sea thermal contrast and atmospheric circulation over East Asia in a warming climate—Part I: Past changes and future projections

NASA Astrophysics Data System (ADS)

Kamae, Youichi; Watanabe, Masahiro; Kimoto, Masahide; Shiogama, Hideo

2014-11-01

Land-sea surface air temperature (SAT) contrast, an index of tropospheric thermodynamic structure and dynamical circulation, has shown a significant increase in recent decades over East Asia during the boreal summer. In Part I of this two-part paper, observational data and the results of transient warming experiments conducted using coupled atmosphere-ocean general circulation models (GCMs) are analyzed to examine changes in land-sea thermal contrast and the associated atmospheric circulation over East Asia from the past to the future. The interannual variability of the land-sea SAT contrast over the Far East for 1950-2012 was found to be tightly coupled with a characteristic tripolar pattern of tropospheric circulation over East Asia, which manifests as anticyclonic anomalies over the Okhotsk Sea and around the Philippines, and a cyclonic anomaly over Japan during a positive phase, and vice versa. In response to CO2 increase, the cold northeasterly winds off the east coast of northern Japan and the East Asian rainband were strengthened with the circulation pattern well projected on the observed interannual variability. These results are commonly found in GCMs regardless of future forcing scenarios, indicating the robustness of the East Asian climate response to global warming. The physical mechanisms responsible for the increase of the land-sea contrast are examined in Part II.

South Fork Latrine, oblique view showing south and east sides; ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

South Fork Latrine, oblique view showing south and east sides; view northwest - Fort McKinley, South Fork Latrine, West side of East Side Drive, approximately 225 feet south of Weymouth Way, Great Diamond Island, Portland, Cumberland County, ME

1. SOUTH AND EAST SIDES OF BUILDING 522. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. SOUTH AND EAST SIDES OF BUILDING 522. VIEW TO NORTHWEST. - Rocky Mountain Arsenal, White Phosphorous Filling-Acetylene Generation Building-Warehouse, 840 feet South of December Seventh Avenue; 1030 feet East of D Street, Commerce City, Adams County, CO

2. NORTH AND EAST SIDES OF BUILDING 525. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. NORTH AND EAST SIDES OF BUILDING 525. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Acetylene Scrubbing Building-Product Development Laboratory, 700 feet South of December Seventh Avenue; 1030 feet East of D Street, Commerce City, Adams County, CO

1. SOUTH AND EAST SIDES OF BUILDING 525. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. SOUTH AND EAST SIDES OF BUILDING 525. VIEW TO NORTHWEST. - Rocky Mountain Arsenal, Acetylene Scrubbing Building-Product Development Laboratory, 700 feet South of December Seventh Avenue; 1030 feet East of D Street, Commerce City, Adams County, CO

View of east elevation of Building No. 23. Parking Area ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

View of east elevation of Building No. 23. Parking Area No. 25 in foreground. Looking west-northwest - Easter Hill Village, Building No. 23, North side of South Twenty-sixth Street, east of Corto Square, Richmond, Contra Costa County, CA

30. ELEVATION EAST FACE BLDG. 27. Fafnir Bearing Plant, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

30. ELEVATION EAST FACE BLDG. 27. - Fafnir Bearing Plant, Bounded on North side by Myrtle Street, on South side by Orange Street, on East side by Booth Street & on West side by Grove Street, New Britain, Hartford County, CT

13. FIRST FLOOR BLDG. 28 LOOKING EAST. Fafnir Bearing ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. FIRST FLOOR BLDG. 28 LOOKING EAST. - Fafnir Bearing Plant, Bounded on North side by Myrtle Street, on South side by Orange Street, on East side by Booth Street & on West side by Grove Street, New Britain, Hartford County, CT

VIEW OF EAST TEST SITE FROM TOP OF STATIC TEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF EAST TEST SITE FROM TOP OF STATIC TEST TOWER VIEW INCLUDES STRUCTURAL DYNAMICS TEST STAND COLD CALIBRATION TEST STAND AND COMPONENTS TEST LAB. - Marshall Space Flight Center, East Test Area, Dodd Road, Huntsville, Madison County, AL

9. INTERIOR VIEW, FIRST FLOOR, NORTHEAST ROOM, EAST WALL, ORIGINAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

9. INTERIOR VIEW, FIRST FLOOR, NORTHEAST ROOM, EAST WALL, ORIGINAL KITCHEN FIREPLACE AND BAKE OVEN, WITH OPEN DOORWAY INTO CURRENT KITCHEN - Edgemont, 212 Bridgetown Pike, 1/4 mile East of PA 413 (Middletown Township), Langhorne, Bucks County, PA

1. NORTH AND EAST SIDES OF BUILDING 514. VIEW TO ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. NORTH AND EAST SIDES OF BUILDING 514. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Lewisite Reactor & Distilled Mustard Distillation Building, 420 feet South of December Seventh Avenue; 1070 feet East of D Street, Commerce City, Adams County, CO

Detail of diagonal end post support bracket mounted to east ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Detail of diagonal end post support bracket mounted to east face of track girder, east span. View south - New York, New Haven & Hartford Railroad, Fort Point Channel Rolling Lift Bridge, Spanning Fort Point Channel, Boston, Suffolk County, MA

INTERIOR OF BOILER BUILDING, FIRST LEVEL, EAST SIDE, SHOWING STEAMDRIVEN ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR OF BOILER BUILDING, FIRST LEVEL, EAST SIDE, SHOWING STEAM-DRIVEN PISTON PUMPS FOR FUEL OIL, CAMERA FACING EAST. - New Haven Rail Yard, Central Steam Plant and Oil Storage, Vicinity of Union Avenue, New Haven, New Haven County, CT

17. THE INDIAN HOUSE. EAST AND SOUTH WALLS. FRANK K. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

17. THE INDIAN HOUSE. EAST AND SOUTH WALLS. FRANK K. SWAIN'S OFFICE IS BEYOND THE GLASS PARTITION. - Moravian Pottery & Tile Works, Southwest side of State Route 313 (Swamp Road), Northwest of East Court Street, Doylestown, Bucks County, PA

5. WEST SIDE, FROM ACROSS 3RD STREET, LOOKING EAST, WITH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. WEST SIDE, FROM ACROSS 3RD STREET, LOOKING EAST, WITH NAVY EXCHANGE RETAIL SERVICE AT TOP OF STAIRS. - Oakland Naval Supply Center, Administration Building-Cafeteria, East of Third Street between D & E Streets, Oakland, Alameda County, CA

1. VIEW OF EAST FRONT OF BREAKER, WITH SCALE STICK, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. VIEW OF EAST FRONT OF BREAKER, WITH SCALE STICK, SHOWING FOUNDATIONS OF RETAIL SCALES IN FOREGROUND, LOOKING WEST - Marvine Colliery, Breaker No. 2, West side Boulevard Avenue, between East Parker Street & Route 380, Scranton, Lackawanna County, PA

76. TILE WORKS COURTYARD, EAST WING ARCADE, FROM NORTH, c. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

76. TILE WORKS COURTYARD, EAST WING ARCADE, FROM NORTH, c. 1915. FONTHILL MANUSCRIPTS, SL/BCHS. UNCATALOGED POSTCARD. - Moravian Pottery & Tile Works, Southwest side of State Route 313 (Swamp Road), Northwest of East Court Street, Doylestown, Bucks County, PA