Buoyancy-driven, rapid exhumation of ultrahigh-pressure metamorphosed continental crust.

PubMed

Ernst, W G; Maruyama, S; Wallis, S

1997-09-02

Preservation of ultrahigh-pressure (UHP) minerals formed at depths of 90-125 km require unusual conditions. Our subduction model involves underflow of a salient (250 +/- 150 km wide, 90-125 km long) of continental crust embedded in cold, largely oceanic crust-capped lithosphere; loss of leading portions of the high-density oceanic lithosphere by slab break-off, as increasing volumes of microcontinental material enter the subduction zone; buoyancy-driven return toward midcrustal levels of a thin (2-15 km thick), low-density slice; finally, uplift, backfolding, normal faulting, and exposure of the UHP terrane. Sustained over approximately 20 million years, rapid ( approximately 5 mm/year) exhumation of the thin-aspect ratio UHP sialic sheet caught between cooler hanging-wall plate and refrigerating, downgoing lithosphere allows withdrawal of heat along both its upper and lower surfaces. The intracratonal position of most UHP complexes reflects consumption of an intervening ocean basin and introduction of a sialic promontory into the subduction zone. UHP metamorphic terranes consist chiefly of transformed, yet relatively low-density continental crust compared with displaced mantle material-otherwise such complexes could not return to shallow depths. Relatively rare metabasaltic, metagabbroic, and metacherty lithologies retain traces of phases characteristic of UHP conditions because they are massive, virtually impervious to fluids, and nearly anhydrous. In contrast, H2O-rich quartzofeldspathic, gneissose/schistose, more permeable metasedimentary and metagranitic units have backreacted thoroughly, so coesite and other UHP silicates are exceedingly rare. Because of the initial presence of biogenic carbon, and its especially sluggish transformation rate, UHP paragneisses contain the most abundantly preserved crustal diamonds.

Geochronology of Zircon in Eclogite Reveals Imbrication of the Ultrahigh-Pressure Western Gneiss Region of Norway.

NASA Astrophysics Data System (ADS)

Young, D. J.; Kylander-Clark, A. R.; Root, D. B.

2014-12-01

Eclogite provides the only record of kinematic events at the deepest levels of orogens. Integrating the U-Pb geochronology and trace element chemistry of zircon in eclogite reveals the most complete view of the PTt history, yet low concentrations of uranium and zirconium and drier compositions that hinder zircon growth at peak conditions render it a challenging rocktype for this approach. The iconic Western Gneiss Region (WGR) in Norway is one of the largest terranes of deeply subducted continental rocks in the world, and contains many indicators of ultrahigh-pressure metamorphic conditions (P>2.8 GPa) that developed during the Siluro-Devonian Caledonian Orogeny. A metamorphic transition from amphibolite-facies to ultrahigh-pressure eclogite facies broadly coincides with a km-scale shear zone that underlies the majority of the WGR. A critical unknown is the timing of movement on this feature, which emplaced allochthonous units above the Baltica basement, but might also have accommodated late-orogenic exhumation of the WGR from mantle depths. We carried out laser ablation split-stream ICPMS (LASS) and selected multigrain TIMS analyses of zircons from eleven eclogites across the southern WGR, of which eight are located within or above the shear zone. LASS spots on polished grains mostly yield weakly discordant Proterozoic intrusive ages, and often minimal indication of a Caledonian (U)HP metamorphic overprint. Direct ablation into unpolished zircon reveals thin rims of Caledonian age in some cases. Overall, the dataset shows that all samples began zircon growth at approximately the same time (ca. 430-420 Ma). Eclogite from lower levels of the shear zone does not contain any dates younger than ca. 410 Ma, however, while eclogite from higher levels continued growth until ca. 400 Ma. We interpret this to result from thrusting of the WGR above cooler basement after 410 Ma, terminating new zircon crystallization within the shear zone but allowing limited further growth in

Petrology and fluid inclusions of garnet-clinopyroxene rocks from the Gondwana suture zone in southern India: Implications for prograde high-pressure metamorphism

NASA Astrophysics Data System (ADS)

Tsunogae, T.

2012-04-01

, which is consistent with the occurrence of high-pressure Mg-rich staurolite in Mg-Al-rich rocks from this region. Fluid inclusion study of some garnet-clinopyroxene rock samples identified CO2-rich fluid inclusions trapped as primary phases within garnet, suggesting that prograde high-pressure metamorphism was dominated by CO2-rich fluids. The results therefore confirmed that the PCSZ underwent regional dry high-pressure metamorphism followed by the peak ultrahigh-temperature event probably associated with the continent-continent collisional and suturing history along the PCSZ.

First occurrence of very low pressure ultra-high temperatures metamorphism in the Khondalite Belt, North China Craton.

NASA Astrophysics Data System (ADS)

Lobjoie, Cyril; Lin, Wei; Trap, Pierre; Goncalves, Philippe; Marquer, Didier

2016-04-01

This study report the first occurrence of very low pressure (<0.4GPa) ultra-high temperatures metamorphism within the Paleoproterozoic Khondalite Belt of the North China Craton. This high grade orogenic domain is mostly composed of garnet +/- spinel +/- sapphirine-bearing migmatites, numerous Grt-bearing granites and marbles. These rocks are intruded by numerous metric to kilometric mafic intrusions. Petrological analyses and phase equilibria diagram modeling were performed on garnet and spinel-bearing and olivine-bearing migmatites. Garnet and spinel-bearing migmatites show a quartz, ternary feldspar, garnet, biotite sillimanite and spinel main assemblage. Pseudosection diagram calculations give suprasolidus P-T conditions around ca. 0.7GPa for ca. 900°C that correspond to the peak temperature conditions. Thermometry using ternary feldspar thermometry gives temperatures estimations at ca. 950-1015°C for a pressure of 0.7GPa. The Olivine-bearing migmatite, located at the contact with a mafic intrusion, shows two main assemblages. The first assemblage that makes the rock matrix consists of a micrographic quartz and feldspar domains associated with biotite, sillimanite and spinel. The second assemblage appears within mm-scale pockets with a complex symplectitic texture. Careful investigation revealed that theses pockets formed after garnet pseudomorphosis, with the development of an Opx-Sp-Crd association. Within this assemblage, an olivine-cordierite and Opx-Crd-Bi-Qtz assemblage occurred as smaller pockets. The petrogenetic grid and pseudosection calculations made for this olivine-bearing migmatite give P-T conditions around 0.35GPa for ca. 950°C that correspond to the peak temperature conditions recorded by the olivine-cordierite assemblage. The succession of reactions with garnet pseudomorphosis into an Opx-Spl-Crd followed by the crystallization of an Ol-Crd assemblage is modelled in the petrogenetic grid calculation and correspond to an isobaric clockwise P

Geochronology and tectonic significance of Middle Proterozoic granitic orthogneiss, North Qaidam HP/UHP terrane, Western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Liou, J.G.; Bird, D.K.; Wu, C.L.

2006-01-01

Amphibolite-facies para- and orthogneisses near Dulan, in the southeast part of the North Qaidam terrane, enclose minor ultra-high pressure (UHP) eclogite and peridotite. Field relations and coesite inclusions in zircons from paragneiss suggest that felsic, mafic, and ultramafic rocks all experienced UHP metamorphism and a common amphibolite-facies retrogression. Ion microprobe U-Pb and REE analyses of zircons from two granitic orthogneisses indicate magmatic crystallization at 927 ?? Ma and 921 ?? 7 Ma. Zircon rims in one of these samples yield younger ages (397-618 Ma) compatible with partial zircon recrystallization during in-situ Ordovician-Silurian eclogite-facies metamorphism previously determined from eclogite and paragneiss in this area. The similarity between a 2496 ?? 18 Ma xenocrystic core and 2.4-2.5 Ga zircon cores in the surrounding paragneiss suggests that the granites intruded the sediments or that the granite is a melt of the older basement which supplied detritus to the sediments. The magmatic ages of the granitic orthogneisses are similar to 920-930 Ma ages of (meta)granitoids described further northwest in the North Qaidam terrane and its correlative west of the Altyn Tagh fault, suggesting that these areas formed a coherent block prior to widespread Mid Proterozoic granitic magmatism. ?? Springer-Verlag 2006.

Buoyancy-driven, rapid exhumation of ultrahigh-pressure metamorphosed continental crust

PubMed Central

Ernst, W. G.; Maruyama, S.; Wallis, S.

1997-01-01

Preservation of ultrahigh-pressure (UHP) minerals formed at depths of 90–125 km require unusual conditions. Our subduction model involves underflow of a salient (250 ± 150 km wide, 90–125 km long) of continental crust embedded in cold, largely oceanic crust-capped lithosphere; loss of leading portions of the high-density oceanic lithosphere by slab break-off, as increasing volumes of microcontinental material enter the subduction zone; buoyancy-driven return toward midcrustal levels of a thin (2–15 km thick), low-density slice; finally, uplift, backfolding, normal faulting, and exposure of the UHP terrane. Sustained over ≈20 million years, rapid (≈5 mm/year) exhumation of the thin-aspect ratio UHP sialic sheet caught between cooler hanging-wall plate and refrigerating, downgoing lithosphere allows withdrawal of heat along both its upper and lower surfaces. The intracratonal position of most UHP complexes reflects consumption of an intervening ocean basin and introduction of a sialic promontory into the subduction zone. UHP metamorphic terranes consist chiefly of transformed, yet relatively low-density continental crust compared with displaced mantle material—otherwise such complexes could not return to shallow depths. Relatively rare metabasaltic, metagabbroic, and metacherty lithologies retain traces of phases characteristic of UHP conditions because they are massive, virtually impervious to fluids, and nearly anhydrous. In contrast, H2O-rich quartzofeldspathic, gneissose/schistose, more permeable metasedimentary and metagranitic units have backreacted thoroughly, so coesite and other UHP silicates are exceedingly rare. Because of the initial presence of biogenic carbon, and its especially sluggish transformation rate, UHP paragneisses contain the most abundantly preserved crustal diamonds. PMID:11038569

Metamorphism, Plate Tectonics, and the Supercontinent Cycle

NASA Astrophysics Data System (ADS)

Brown, Michael

Granulite facies ultrahigh temperature metamorphism (G-UHTM) is documented in the rock record predominantly from Neoarchean to Cambrian; G-UHTM facies series rocks may be inferred at depth in younger, particularly Cenozoic orogenic systems. The first occurrence of G-UHTM in the rock record signifies a change in geodynamics that generated transient sites of very high heat flow. Many G-UHTM belts may have developed in settings analogous to modern continental backarcs. On a warmer Earth, the cyclic formation of supercontinents and their breakup, particularly by extroversion, which involved destruction of ocean basins floored by thinner lithosphere, may have generated hotter continental backarcs than those associated with the modern Pacific rim. Medium-temperature eclogite, high-pressure granulite metamorphism (E-HPGM), is also first recognized in the Neoarchean rock record and occurs at intervals throughout the Proterozoic and Paleozoic rock record. E-HPGM belts are complementary to G-UHTM belts and are generally inferred to record subduction-to-collision orogenesis. Blueschists become evident in the Neoproterozoic rock record; they record the low thermal gradients associated with modern subduction. Lawsonite blueschists and eclogites (high-pressure metamorphism, HPM) and ultrahigh pressure metamorphism (UHPM) characterized by coesite (±lawsonite) or diamond are predominantly Phanerozoic phenomena. HPM-UHPM registers the low thermal gradients and deep subduction of continental crust during the early stage of the collision process in Phanerozoic subduction-to-collision orogens. Although perhaps counterintuitive, many HPM-UHPM belts appear to have developed by closure of small ocean basins in the process of accretion of a continental terrane during a period of supercontinent introversion (Wilson cycle ocean basin opening and closing). A duality of metamorphic belts—reflecting a duality of thermal regimes—appears in the record only since the Neoarchean Era. A

Evidence for pre-Taconic metamorphism in the Potomac terrane, Maryland and Virginia: Hornblende and Muscovite [sup 40]Ar/[sup 39]Ar results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Becker, J.L.; Wintsch, R.P.; Kunk, M.J.

1993-03-01

New [sup 40]Ar/[sup 39]Ar age spectra of hornblende and white mica from the Great Falls area of the Potomac terrane of Maryland and Virginia indicate pre-Taconic metamorphism. Age spectra of hornblende samples are interpreted to represent cooling from peak metamorphic conditions through their closure temperatures for argon diffusion ([approximately]500C) at about 490 Ma. These older Ordovician postmetamorphic cooling ages strongly contrast with younger post-Ordovician metamorphic cooling ages now being reported in the Blue Ridge and Goochland terranes to the west and east respectively. A late phyllitic sheen observed on rocks in the field and petrographic observations of undulose plagioclase andmore » amphibole, and older muscovite, and kinked primary muscovite in the Bear Island Granodiorite reflect a younger retrogressive metamorphism involving the growth of secondary muscovite (Fisher's S4 ). [sup 40]Ar/[sup 39]Ar Age spectra of white micas from the Bear Island Granodiorite are complex and probably indicate both primary and secondary white mica, the latter apparently growing below the closure temperature for retention of argon in muscovite ([approximately]350C). The age spectra permit an estimate of a minimum age of 420 Ma for cooling through closure of the older generation of white mica. The above ages of hornblende and muscovite closure imply a minimum cooling rate of [approximately]2C/m.y., and exhumation rate of about 1 mm/yr. The projected time of peak metamorphism at upper amphibolite facies for the Great Falls area clearly predates the Ordovician Taconic orogeny and suggests that these rocks escaped this event and largely escaped younger Paleozoic metamorphic events, which are well documented in adjacent terranes.« less

Cathodoluminescence of diamond as an indicator of its metamorphic history

NASA Astrophysics Data System (ADS)

Kopylova, Maya; Bruce, Loryn; Longo, Micaela; Ryder, John; Dobrzhinetskaya, Larissa

2010-05-01

Diamond displays a supreme resistance to chemical and mechanical weathering, ensuring its survival through complex and prolonged crustal processes, including metamorphism and exhumation. For these reasons, volcanic sources and secondary and tertiary collectors for detrital placer diamonds, like Ural or Bingara diamonds, may be difficult to determine. If metamorphic processes leave their marks on diamond, they can be used to reconstruct crustal geologic processes and ages of primary diamondiferous volcanics. Four diamond suites extracted from metamorphic rocks have been characterized using optical CL, infrared and CL spectroscopy, and photoluminescence at the liquid nitrogen temperature. The studied diamonds are from the ~2.7 Ga sedimentary conglomerate and lamprophyric breccia metamorphosed in the greenschist facies (Wawa, Northern Ontario, Canada) during the 2.67 Ga Kenoran orogeny, and from the ultra-high pressure (UHP) terranes of Kokchetav (Kazakhstan) and Erzgebirge (Germany) exhumated in the Paleozoic. Wawa diamonds (Type IaAB and Type II) displayed green, yellow, orange, and red CL colours controlled by the CL emittance at 520, 576 nm, and between 586 and 664 nm. The UHP terranes diamonds show much weaker CL; few luminescent stones display CL peaks at 395, 498, 528 nm and a broad band at 580-668 nm. In contrast, most common diamonds found in unmetamorphosed rocks, i.e. octahedrally grown Type IaAB stones, luminescence blue emitting light at ~415-440 nm and 480-490 nm. There is a noticeable difference between cathodoluminescence of these diamonds and diamonds in metamorphic rocks. The studied diamonds that experienced metamorphism show a shift of CL emission to longer wavelengths (above 520 nm) and to green, yellow and red CL colours. Photoluminescence has the high resolution necessary to assign luminescence to specific optical centers of diamond. Diamonds in metamorphic rocks contain H3 (pairs of substitutional nitrogen atoms separated by a vacancy) and NVo

Late Cretaceous tectonothermal evolution of the southern Lhasa terrane, South Tibet: Consequence of a Mesozoic Andean-type orogeny

NASA Astrophysics Data System (ADS)

Dong, Xin; Zhang, Ze-ming; Klemd, Reiner; He, Zhen-yu; Tian, Zuo-lin

2018-04-01

The Lhasa terrane of the southern Tibetan Plateau participated in a Mesozoic Andean-type orogeny caused by the northward subduction of the Neo-Tethyan oceanic lithosphere. However, metamorphic rocks, which can unravel details of the geodynamic evolution, are rare and only exposed in the south-eastern part of the Lhasa terrane. Therefore, we conducted a detailed petrological, geochemical and U-Pb zircon geochronological study of the late Cretaceous metamorphic rocks and associated gabbros from the Nyemo inlier of the southern Lhasa terrane. The Nyemo metamorphic rocks including gneisses, schists, marbles and calc-silicate rocks, experienced peak amphibolite-facies contact metamorphism under P-T conditions of 3.5-4.0 kbar and 642-657 °C with a very high geothermal gradient of 45-50 °C/km, revealing a distinct deflection from the steady-state geotherm during low-pressure metamorphism. Inherited magmatic zircon cores from the metamorphic rocks yielded protolith ages of 197-194 Ma, while overgrowth zircon rims yielded metamorphic ages of ca. 86 Ma. Whole-rock chemistry and zircon Hf isotopes suggest that the protoliths of the gneisses and schists are andesites and tuffs of the early Jurassic Sangri Group, which were derived from a depleted mantle source of a continental arc affinity. The coeval intimately-associated gabbro (ca. 86 Ma) crystallized under P-T conditions of 3.5-5.3 kbar and 914-970 °C, supplying the heat flux high enough to cause the contact metamorphism of the Sangri Group rock types. We propose that the intrusion of the gabbro and a simultaneous pressure increase of up to 4.0 kbar, which is related to crustal thickening due to crustal overthrusting and the intrusion of mafic material, resulted in the late Cretaceous metamorphism of the early Jurassic Sangri Group during an Andean-type orogeny. Furthermore the Nyemo metamorphic rocks, which have previously been considered to represent slivers of the Precambrian metamorphic basement of the Lhasa terrane

Zircon U-Pb dating of eclogite from the Qiangtang terrane, north-central Tibet: a case of metamorphic zircon with magmatic geochemical features

NASA Astrophysics Data System (ADS)

Zhai, Qing-guo; Jahn, Bor-ming; Li, Xian-hua; Zhang, Ru-yuan; Li, Qiu-li; Yang, Ya-nan; Wang, Jun; Liu, Tong; Hu, Pei-yuan; Tang, Suo-han

2017-06-01

Zircon is probably the most important mineral used in the dating formation of high-pressure (HP) and ultrahigh-pressure (UHP) metamorphic rocks. The origin of zircon, i.e., magmatic or metamorphic, is commonly assessed by its external morphology, internal structure, mineral inclusions, Th/U ratios and trace element composition. In this study, we present an unusual case of metamorphic zircon from the Qiangtang eclogite, north-central Tibet. The zircon grains contain numerous eclogite-facies mineral inclusions, including omphacite, phengite, garnet and rutile; hence, they are clearly of metamorphic origin. However, they display features similar to common magmatic zircon, including euhedral crystal habit, high Th/U ratios and enriched heavy rare earth elements pattern. We suggest that these zircon grains formed from a different reservoir from that for garnet where no trace elements was present and trace element equilibrium between zircon and garnet was achieved. U-Pb dating of zircon gave an age of 232-237 Ma for the eclogite, and that of rutile yielded a slightly younger age of ca. 217 Ma. These ages are consistent with the reported Lu-Hf mineral isochron and phengite Ar-Ar ages. The zircon U-Pb and mineral Lu-Hf isochron ages are interpreted as the time of the peak eclogite-facies metamorphism, whereas the rutile U-Pb and phengite Ar-Ar ages represent the time of exhumation to the middle crust. Thus, the distinction between metamorphic and magmatic zircons cannot be made using only Th/U ratios and heavy REE compositions for HP-UHP metamorphic rocks of oceanic derivation.

Terrane-Scale Metastability in Subducted Himalayan Continental Crust as Revealed by Integrated Petrological and Geodynamic Modeling

NASA Astrophysics Data System (ADS)

Palin, R. M.; Reuber, G. S.; White, R. W.; Kaus, B. J. P.; Weller, O. M.

2017-12-01

The Tso Morari massif, northwest India, is one of only two regions in the Himalayan Range that exposes subduction-related ultrahigh-pressure (UHP) metamorphic rocks. The tectonic evolution of the massif is strongly debated, however, as reported pressure estimates for peak metamorphism range between 2.4 GPa and 4.8 GPa. Such ambiguity hinders effective lithospheric-scale modeling of the early stages of the orogen's evolution. We present the results of integrated petrological and geodynamic modeling (Palin et al., 2017, EPSL) that provide new quantitative constraints on the prograde-to-peak pressure-temperature-time (P-T-t) path, and predict the parageneses that felsic and mafic components of the massif crust should have formed under equilibrium conditions. Our model shows that peak P-T conditions of 2.6-2.8 GPa and 600-620 °C, representative of subduction to 90-100 km depth (assuming lithostatic pressure), were reached just 3 Myr after the onset of collision. These P-T-t constraints correlate well with those reported for similar UHP eclogite in the along-strike Kaghan Valley, Pakistan, suggesting that the northwest Himalaya contains dismembered remnants of a 400-km long UHP terrane comparable in size to the Western Gneiss Region, Norway, and the Dabie-Sulu belt, China. The extremely high pressures (up to 4.8 GPa) for peak metamorphism reported by some workers are likely to be unreliable due to thermobarometry having been performed on minerals that did not represent equilibrium assemblages. Furthermore, key high-P minerals predicted to form in subducted Tso Morari continental crust (e.g. jadeite, Mg-rich garnet) are absent from natural samples in the region, reflecting the widespread metastable preservation of lower-pressure protolith assemblages during subduction and exhumation. This result questions the reliability of geodynamic simulations of orogenesis that are commonly predicated on equilibrium metamorphism operating continuously throughout tectonic cycles.

Fluid-rock interactions during UHP metamorphism: A review of the Dabie-Sulu orogen, east-central China

NASA Astrophysics Data System (ADS)

Zhang, Z. M.; Shen, K.; Liou, J. G.; Dong, X.; Wang, W.; Yu, F.; Liu, F.

2011-08-01

Comprehensive review on the characteristics of petrology, oxygen isotope, fluid inclusion and nominally anhydrous minerals (NAMs) for many Dabie-Sulu ultrahigh-pressure (UHP) metamorphic rocks including drill-hole core samples reveals that fluid has played important and multiple roles during complicated fluid-rock interactions attending the subduction and exhumation of supracrustal rocks. We have identified several distinct stages of fluid-rock interactions as follows: (1) The Neoproterozoic supercrustal protoliths of UHP rocks experienced variable degrees of hydration through interactions with cold meteoric water with extremely low oxygen isotope compositions during Neoproterozoic Snow-ball Earth time. (2) A series of dehydration reactions took place during Triassic subduction of the Yangtze plate beneath the Sino-Korean plate; the released fluid entered mainly into volatile-bearing high-pressure (HP) and UHP minerals, such as phengite, zoisite-epidote, talc, lawsonite and magnesite, as well as into UHP NAMs, such as garnet, omphacite and rutile. (3) Silicate-rich supercritical fluid (hydrous melt) existed during the UHP metamorphism at mantle depths >100 km which mobilized many normally fluid-immobile elements and caused unusual element fractionation. (4) The fluid exsolved from the NAMs during the early exhumation of the Dabie-Sulu terrane was the main source for HP hydrate retrogression and generation of HP veins. (5) Local amphibolite-facies retrogression at crustal depths took place by infiltration of aqueous fluid of various salinities possibly derived from an external source. (6) The greenschist-facies overprinting and low-pressure (LP) quartz veins were generated by fluid flow along ductile shear zones and brittle faults during late-stage uplift of the UHP terrane.

Devonian to Carboniferous collision in the Greenland Caledonides: U-Pb zircon and Sm-Nd ages of high-pressure and ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

Gilotti, Jane A.; Nutman, Allen P.; Brueckner, Hannes K.

2004-10-01

A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th

Eclogite-facies metamorphism in impure marble from north Qaidam orogenic belt: Geodynamic implications for early Paleozoic continental-arc collision

NASA Astrophysics Data System (ADS)

Chen, Xin; Xu, Rongke; Schertl, Hans-Peter; Zheng, Youye

2018-06-01

In the North Qaidam ultrahigh-pressure (UHP) metamorphic belt, impure marble and interbedded eclogite represent a particular sedimentary provenance and tectonic setting, which have important implications for a controversial problem - the dynamic evolution of early Paleozoic subduction-collision complexes. In this contribution, detailed field work, mineral chemistry, and whole-rock geochemistry are presented for impure marble to provide the first direct evidence for the recycling of carbonate sediments under ultrahigh-pressures during subduction and collision in the Yuka terrane, in the North Qaidam UHP metamorphic belt. According to conventional geothermobarometry, pre-peak subduction to 0.8-1.3 GPa/485-569 °C was followed by peak UHP metamorphism at 2.5-3.3 GPa/567-754 °C and cooling to amphibolite facies conditions at 0.6-0.7 GPa/571-589 °C. U-Pb dating of zircons from impure marble reveals a large group with ages ranging from 441 to 458 Ma (peak at 450 Ma), a smaller group ranging from 770 to 1000 Ma (peak at 780 Ma), and minor >1.8 Ga zircon aged ca. 430 Ma UHP metamorphism. The youngest detrital zircons suggest a maximum depositional age of ca. 442 Ma and a burial rate of ca. 1.0-1.1 cm/yr when combined with P-T conditions and UHP metamorphic age. The REE and trace element patterns of impure marble with positive Sr and U anomalies, negative high field strength elements (Nb, Ta, Zr, Hf, and Ti), and Ce anomalies imply that the marble had a marine limestone precursor. Impure marble intercalated with micaschist and eclogite was similar to limestone and siltstone protoliths deposited in continental fore-arc or arc setting with basic volcanic activity. Therefore, the Yuka terrane most likely evolved in a continental island arc setting during the Paleozoic. These data suggest that metasediments were derived from a mixture of Proterozoic continental crust and juvenile early Paleozoic oceanic and/or island arc crust. In addition, their protoliths were likely

Ar/Ar geochronology in the western Tianshan (northwestern China): from Carboniferous (ultra)high-pressure metamorphism and thrusting to Permian strike-slip deformation and fluid ingress

NASA Astrophysics Data System (ADS)

de Jong, K.; Wang, B.; Ruffet, G.; Shu, L. S.; Faure, M.

2012-04-01

The Tianshan belt (northwestern China) is a major tectonic element of the southern Central Asian Orogenic Belt that contains a number of ophiolitic mélanges and (ultra)high-pressure metamorphic belts formed after closure of oceanic and back-arc basins that resulted in terrane collisions. Deciphering its tectonic evolution is thus crucial for understanding the amalgamation of Central Asia. We produce robust 40Ar/39Ar laser-probe evidence that the Tianshan is a Late Palaeozoic (ultra)high-pressure metamorphic collision belt, not a Triassic one, as suggested by some SHRIMP zircon ages in recent literature. Instead of trying to date the peak pressure conditions we focused on 40Ar/39Ar analysis of white mica formed during retrograde recrystallisation when the (ultra)high-pressure metamorphic rocks of the Changawuzi-Kekesu complex were exhumed. Exhumation was coeval with their northward thrusting over the southern margin of the Yili terrane, the easternmost element of the Kazakhstan composite super-terrane, which produced main phase tectonic structures. The Yili terrane comprises a Proterozoic basement covered by metasediments, intruded by Early Carboniferous granites when it formed part of a continental margin arc. During the Permian deformation was partitioned in vertical brittle-ductile strike-slip fault zones that reactivated these suture zones and in which bimodal magmatism was concentrated. We also investigate the effects of these events on the isotopic ages of mica. 40Ar/39Ar laser-probe dating of white mica reveals that the strongest retrogressed blueschists immediately above the basal thrust fault of the Changawuzi-Kekesu belt gave the youngest plateau age of 316 ± 2 Ma (1σ). White mica in greenschist-facies metamorphic quartzite from the ductilely deformed metasedimentary cover of the Yili terrane's crystalline basement, taken at about 1 km below the thrust contact with the overlying Changawuzi-Kekesu belt, yielded a plateau age of 323 ± 1 Ma (1�

The metamorphic record of subduction-accretion processes in the Neoarchaean: the Nuuk region, southern West Greenland.

NASA Astrophysics Data System (ADS)

Dziggel, Annika; Kolb, Jochen

2013-04-01

The Nuuk region of southern West Greenland exposes an exceptionally well preserved section through Archaean mid- to lower continental crust, and therefore provides a natural laboratory to study the tectonic processes in the Archaean. The area mainly consists of amphibolite to granulite facies TTG gneisses, narrow supracrustal belts, and minor late-tectonic granites. It is made up of several distinct terranes, including, from NW to SE, the Færingehavn, Tre Brødre, and Tasiusarsuaq terranes. Extensive high-grade metamorphism and a clockwise PT evolution of the Færingehavn terrane in the Neoarchaean (2.72-2.71 Ga) have been interpreted as a result of crustal thickening and thrusting of the Tasiusarsuaq terrane on top of the Tre Brødre and Færingehavn terranes (Nutman and Friend, 2007). Prior to final collision, the Tasiusarsuaq terrane (the upper plate in a plate tectonic model) underwent a prolonged period of compressive deformation between 2.8 and 2.72 Ga (Kolb et al., 2012). The structural evolution was associated with near-isobaric cooling from medium-pressure granulite facies conditions of ca. 850°C and 7.5 kbar to amphibolite facies conditions of ca. 700°C and 6.5-7 kbar (Dziggel et al., 2012). Despite this long period of crustal convergence, there is no evidence for exhumation and/or loading, pointing to a rheologically weak and unstable Archaean crust perhaps due to low density differences and ongoing melt extraction. Rocks of the structurally underlying Færingehavn terrane record a distinctly different metamorphic evolution. Although generally more strongly retrogressed, relict higher-pressure mineral assemblages in mafic granulites and felsic gneisses record conditions of > 8-9 kbar and >= 750°C, indicating burial to depths of at least 30 km along an apparent geothermal gradient of 20-25°C/km. The peak of metamorphism was followed by isothermal decompression at ca. 2.715 Ga (Nutman and Friend, 2007), indicating rapid exhumation of lower crustal

Metamorphic and structural evidence for significant vertical displacement along the Ross Lake fault zone, a major orogen-parallel shear zone in the Cordillera of western North America

USGS Publications Warehouse

Baldwin, J.A.; Whitney, D.L.; Hurlow, H.A.

1997-01-01

Results of an investigation of the petrology and structure of the Skymo complex and adjacent terranes constrain the amount, timing, and sense of motion on a segment of the > 600-km-long Late Cretaceous - early Tertiary Ross Lake fault zone (RLFZ), a major orogen-parallel shear zone in the Cordillera of western North America. In the study area in the North Cascades, Washington state, the RLFZ accommodated significant pre-middle Eocene vertical displacement, and it juxtaposes the Skymo complex with upper amphibolite facies (650??-690??C and 6-7 kbar) Skagit Gneiss of the North Cascades crystalline core to the SW and andalusite-bearing phyllite of the Little Jack terrane (Intermontane superterrane) to the NE. The two main lithologic units of the Skymo complex, a primitive mafic intrusion and a fault-bounded block of granulite facies metasedimentary rocks, are unique in the North Cascades. Granulite facies conditions were attained during high-temperature (> 800??C), low pressure (??? 4 kbar) contact metamorphism associated with intrusion of the mafic magma. P-T estimates and reaction textures in garnet-orthopyroxene gneiss suggest that contact metamorphism followed earlier, higher pressure regional metamorphism. There is no evidence that the Skagit Gneiss experienced high-T - low-P contact metamorphism. In the Little Jack terrane, however, texturally late cordierite ?? spinel and partial replacement of andalusite by sillimanite near the terrane's fault contact with Skymo gabbro suggest that the Little Jack terrane experienced high-T (??? 600??C) - low-P (??? 4 kbar) contact metamorphism following earlier low-grade regional metamorphism. Similarities in the protoliths of metasedimentary rocks in the Skymo and Little Jack indicate that they may be part of the same terrane. Differences in pressure estimates for the Little Jack versus Skymo for regional metamorphism that preceded contact metamorphism indicate vertical displacement of ??? 10 km (west side up) on the strand

Subduction and exhumation of a continental margin in the Scandinavian Caledonides: Insights from ultrahigh pressure metamorphism, late orogenic basins and 3D numerical modelling

NASA Astrophysics Data System (ADS)

Cuthbert, Simon

2017-04-01

The Scandinavian Caledonides (SC) represents a plate collision zone of Himalayan style and scale. Three fundamental characteristics of this orogen are: (1) early foreland-directed, tectonic transport and stacking of nappes; (2) late, wholesale reversal of tectonic transport; (3) ultrahigh pressure metamorphism of felsic crust derived from the underthrusting plate at several levels in the orogenic wedge and below the main thrust surface, indicating subduction of continental crust into the mantle. The significance of this for crustal evolution is the profound remodeling of continental crust, direct geochemical interaction of such crust and the mantle and the opening of accommodation space trapping large volumes of clastic detritus within the orogen. The orogenic wedge of the SC was derived from the upper crust of the Baltica continental margin (a hyper-extended passive margin), plus terranes derived from an assemblage of outboard arcs and intra-oceanic basins and, at the highest structural level, elements of the Laurentian margin. Nappe emplacement was driven by Scandian ( 430Ma) collision of Baltica with Laurentia, but emerging Middle Ordovician ages for diamond-facies metamorphism for the most outboard (or rifted) elements of Baltica suggest prior collision with an arc or microcontinent. Nappes derived from Baltica continental crust were subducted, in some cases to depths sufficient to form diamond. These then detached from the upper part of the down-going plate along major thrust faults, at which time they ceased to descend and possibly rose along the subduction channel. Subduction of the remaining continental margin continued below these nappes, possibly driven by slab-pull of the previously subducted Iapetus oceanic lithosphere and metamorphic densification of subducted felsic continental margin. 3D numerical modelling based upon a Caledonide-like plate scenario shows that if a continental corner or promontory enters the subduction zone, the continental margin

Deformation Enhanced Recrystallization of Titanite: Insight from the Western Gneiss Region Ultrahigh-Pressure Terrane

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Reddy, S. M.; Blatchford, H.; Whitney, D. L.; Kirkland, C. L.; Teyssier, C.; Evans, N. J.; McDonald, B.

2017-12-01

Titanite readily recrystallizes due to metamorphism, deformation, and/or fluids making it an ideal chronometer for tracking the exhumation of high-grade rocks. The Western Gneiss Region (WGR), Norway, is a giant UHP terrane exhumed as a fairly coherent slab. Parts of the WGR underwent little deformation during exhumation; however, meters-scale shear zones, located across the WGR, deformed over a range of pressures, from (U)HP to amphibolite facies. Titanite from quartzofeldpathic gneiss within, directly adjacent to, and 300 m away from a mylonitic shear zone within the southern WGR have been analyzed to track exhumation and investigate effects of deformation on recrystallization and trace-element mobility. EBSD was used to characterize the microstructural evolution of the gneisses, and trace-element concentrations and timing of recrystallization were estimated by split-stream LA-ICPMS. Titanite grain size decreases from outside (>200) to inside (<75 µm) the shear zone. Gneiss in and directly adjacent to the shear zone contain partially to completely recrystallized grains, with 207-corrected 206Pb/238U ages of <405 Ma. Gneiss within the shear zone shows a greater percentage of recrystallized grains. EBSD data indicate that some titanite comprises multiple subgrains within an optically coherent single grain. Subgrains in titanite cores show evidence of inherited radiogenic Pb, whereas subgrains in rims and tails of deformed sigma grains were recrystallized. In a gneiss directly adjacent to the shear zone, optically coherent grains are zoned, with increasing Sr and decreasing Zr from core to rim; titanite subgrains within the shear-zone gneiss are too small to analyze. In comparison, titanite from the gneiss outside the shear zone does not show any internal microstructures or evidence for Scandian recrystallization and has low U and high 204Pb. These results show that most trace elements are unaffected by deformation of titanite; however, Pb is mobile. Deformation

Deformation Enhanced Recrystallization of Titanite: Insight from the Western Gneiss Region Ultrahigh-Pressure Terrane

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Reddy, S. M.; Blatchford, H.; Whitney, D. L.; Kirkland, C. L.; Teyssier, C.; Evans, N. J.; McDonald, B.

2016-12-01

Titanite readily recrystallizes due to metamorphism, deformation, and/or fluids making it an ideal chronometer for tracking the exhumation of high-grade rocks. The Western Gneiss Region (WGR), Norway, is a giant UHP terrane exhumed as a fairly coherent slab. Parts of the WGR underwent little deformation during exhumation; however, meters-scale shear zones, located across the WGR, deformed over a range of pressures, from (U)HP to amphibolite facies. Titanite from quartzofeldpathic gneiss within, directly adjacent to, and 300 m away from a mylonitic shear zone within the southern WGR have been analyzed to track exhumation and investigate effects of deformation on recrystallization and trace-element mobility. EBSD was used to characterize the microstructural evolution of the gneisses, and trace-element concentrations and timing of recrystallization were estimated by split-stream LA-ICPMS. Titanite grain size decreases from outside (>200) to inside (<75 µm) the shear zone. Gneiss in and directly adjacent to the shear zone contain partially to completely recrystallized grains, with 207-corrected 206Pb/238U ages of <405 Ma. Gneiss within the shear zone shows a greater percentage of recrystallized grains. EBSD data indicate that some titanite comprises multiple subgrains within an optically coherent single grain. Subgrains in titanite cores show evidence of inherited radiogenic Pb, whereas subgrains in rims and tails of deformed sigma grains were recrystallized. In a gneiss directly adjacent to the shear zone, optically coherent grains are zoned, with increasing Sr and decreasing Zr from core to rim; titanite subgrains within the shear-zone gneiss are too small to analyze. In comparison, titanite from the gneiss outside the shear zone does not show any internal microstructures or evidence for Scandian recrystallization and has low U and high 204Pb. These results show that most trace elements are unaffected by deformation of titanite; however, Pb is mobile. Deformation

Earthquakes, fluid pressures and rapid subduction zone metamorphism

NASA Astrophysics Data System (ADS)

Viete, D. R.

2013-12-01

High-pressure/low-temperature (HP/LT) metamorphism is commonly incomplete, meaning that large tracts of rock can remain metastable at blueschist- and eclogite-facies conditions for timescales up to millions of years [1]. When HP/LT metamorphism does take place, it can occur over extremely short durations (<<1 Myr) [1-2]. HP/LT metamorphism must be associated with processes that allow large volumes of rock to remain unaffected over long periods of time, but then suddenly undergo localized metamorphism. Existing models for HP/LT metamorphism have focussed on the role of fluids in providing heat for metamorphism [2] or catalyzing metamorphic reactions [1]. Earthquakes in subduction zone settings can occur to depths of 100s of km. Metamorphic dehydration and the associated development of elevated pore pressures in HP/LT metamorphic rocks has been identified as a cause of earthquake activity at such great depths [3-4]. The process of fracturing/faulting significantly increases rock permeability, causing channelized fluid flow and dissipation of pore pressures [3-4]. Thus, deep subduction zone earthquakes are thought to reflect an evolution in fluid pressure, involving: (1) an initial increase in pore pressure by heating-related dehydration of subduction zone rocks, and (2) rapid relief of pore pressures by faulting and channelized flow. Models for earthquakes at depth in subduction zones have focussed on the in situ effects of dehydration and then sudden escape of fluids from the rock mass following fracturing [3-4]. On the other hand, existing models for rapid and incomplete metamorphism in subduction zones have focussed only on the effects of heating and/or hydration with the arrival of external fluids [1-2]. Significant changes in pressure over very short timescales should result in rapid mineral growth and/or disequilibrium texture development in response to overstepping of mineral reaction boundaries. The repeated process of dehydration-pore pressure development

Distribution and characteristics of metamorphic belts in the south- eastern Alaska part of the North American Cordillera

USGS Publications Warehouse

Brew, D.A.; Himmelberg, G.R.; Loney, R.A.; Ford, A.B.

1992-01-01

The Cordilleran orogen in south-eastern Alaska includes 14 distinct metamorphic belts that make up three major metamorphic complexes, from east to west: the Coast plutonic-metamorphic complex; the Glacier Bay-Chichagof plutonic-metamorphic complex; and the Chugach plutonic-metamorphic complex. Each of these complexes is related to a major subduction event. The metamorphic history of the Coast complex is lengthy and is related to the Late Cretaceous collision of the Alexander and Wrangellia terranes and the Gravina overlap assemblage to the west against the Stikine terrane to the east. The metamorphic history of the Glacier Bay-Chichagof complex is relatively simple and is related to the roots of a Late Jurassic to late Early Cretaceous island arc. The metamorphic history of the Chugach is complicated and developed during and after the Late Cretaceous collision of the Chugach terrane with the Wrangellia and Alexander terranes. -from Authors

Geochronology of multi-stage metamorphic events: Constraints on episodic zircon growth from the UHP eclogite in the South Altyn, NW China

NASA Astrophysics Data System (ADS)

Liu, Liang; Wang, Chao; Cao, Yu-Ting; Chen, Dan-Ling; Kang, Lei; Yang, Wen-Qiang; Zhu, Xiao-Hui

2012-04-01

Petrography, mineral chemistry and pressure-temperature (P-T) estimates were carried out for the eclogite from the South Altyn in NW China. The results suggest three stages of metamorphism: an ultra-high pressure (UHP) eclogite-facies metamorphism at 717-871 °C and ≥ 2.8 GPa, a high pressure (HP) granulite-facies metamorphism at 624-789 °C and 1.42-1.52 GPa, and an amphibolite-facies metamorphism at 597-728 °C and 0.99-1.17 GPa. Cathodoluminescence investigation revealed that zircons from the retrograde eclogite display a distinct core-rim structure. Cores are grey-white luminescent and contain mineral inclusions of Garnet + Omphacite + Rutile + Quartz, suggesting eclogite-facies metamorphic origin. The rims are dark grey luminescent and contain Garnet + Clinopyroxene + Pagioclase inclusions, forming at HP granulite-facies conditions. A few residual zircon grains with mottled internal structure also occur as the metamorphic cores. LA-ICPMS zircon U-Pb dating yielded three discrete age groups: (1) a Neoproterozoic protolith age of 752 ± 7 Ma for the residual grains, (2) an eclogite-facies metamorphic age of 500 ± 7 Ma for the metamorphic cores, and (3) a HP granulite-facies retrograde age of 455 ± 2 Ma for the rims. These ages indicate that the protolith of the Altyn eclogite probably formed in response to breakup of the Rodinia supercontinent during the Neoproterozoic; it was subjected to continental deep subduction and UHP metamorphism during early Paleozoic (~ 500 Ma) and subsequently underwent two stages of retrograde metamorphism during exhumation. The petrological and geochronological data suggest a clockwise P-T-t path for the UHP eclogite. According to pressures and ages for the peak UHP eclogite-facies and the retrograde HP granulite-facies metamorphism, an exhumation rate of 1.2 mm/yr was estimated for the eclogite, which is considerably slower than that of some UHP rocks from other UHP terranes (> 5 mm/yr). While the peak metamorphic age of 500 Ma

Neoarchean arc magmatism followed by high-temperature, high-pressure metamorphism in the Nilgiri Block, southern India

NASA Astrophysics Data System (ADS)

Samuel, Vinod O.; Sajeev, K.; Hokada, T.; Horie, K.; Itaya, T.

2015-11-01

The Nilgiri Block, southern India is an exhumed lower crust formed through arc magmatic processes in the Neoarchean. The main lithologies in this terrane include charnockites, gneisses, volcanic tuff, metasediments, banded iron formation and mafic-ultramafic bodies. Mafic-ultramafic rocks are present towards the northern and central part of the Nilgiri Block. We examine the evolution of these mafic granulites/metagabbros by phase diagram modeling and U-Pb sensitive high resolution ion microprobe (SHRIMP) dating. They consist of a garnet-clinopyroxene-plagioclase-hornblende-ilmenite ± orthopyroxene ± rutile assemblage. Garnet and clinopyroxene form major constituents with labradorite and orthopyroxene as the main mineral inclusions. Labradorite, identified using Raman analysis, shows typical peaks at 508 cm- 1, 479 cm- 1, 287 cm- 1 and 177 cm- 1. It is stable along with orthopyroxene towards the low-pressure high-temperature region of the granulite facies (M1 stage). Subsequently, orthopyroxene reacted with plagioclase to form the peak garnet + clinopyroxene + rutile assemblage (M2 stage). The final stage is represented by amphibolite facies-hornblende and plagioclase-rim around the garnet-clinopyroxene assemblage (M3 stage). Phase diagram modeling shows that these mafic granulites followed an anticlockwise P-T-t path during their evolution. The initial high-temperature metamorphism (M1 stage) was at 850-900 °C and ~ 9 kbar followed by high-pressure granulite facies metamorphism (M2 stage) at 850-900 °C and 14-15 kbar. U-Pb isotope studies of zircons using SHRIMP revealed late Neoarchean to early paleoproterozoic ages of crystallization and metamorphism respectively. The age data shows that these mafic granulites have undergone arc magmatism at ca. 2539.2 ± 3 Ma and high-temperature, high-pressure metamorphism at ca. 2458.9 ± 8.6 Ma. Thus our results suggests a late Neoarchean arc magmatism followed by early paleoproterozoic high-temperature, high-pressure

On protolith-, metamorphic overprint, microstructure and rheology of mineral assemblages in orogenic peridotites of the central Scandinavian Caledonides

NASA Astrophysics Data System (ADS)

Gilio, Mattia; Clos, Frediano; Van Roermund, Herman L. M.

2013-04-01

The Scandinavian Caledonides (SC) are a deeply eroded Alpine-type orogenic belt formed by closure of the Iapetus ocean and collision between Baltica and Laurentia (500-380 Ma). The SC consists of a stack of Nappe Complexes (from bottom to top called Lower, Middle, Upper and Uppermost Allochthons) thrusted to the east over the Baltic Shield (Brueckner and Van Roermund, 2004; Gee et al., 2008). Fossil lithospheric mantle fragments, called orogenic peridotites, have been found within the (upper part of) middle, upper and uppermost Allochthons, as well as in the reworked basement gneisses (a.o Western Gneiss Complex (WGC)) along the Norwegian west coast. They occur as isolated lenses that contain diverse mineral parageneses and/or bulk rock compositions. Crustal incorporation of orogenic peridotite is classically interpreted to be the result of plate collisional processes related to orogeny (Brueckner and Medaris, 2000). The WGC and parts of the upper part of the Middle Allochthon (a.o. Seve Nappe Complex (SNC) in N Jämtland/S Västerbotten, central Sweden), are well known for the occurrence of high (HP) and ultrahigh pressure (UHP) metamorphic terranes (of Caledonian age). The (U)HPM evidence clearly demonstrates the deep metamorphic origin of these rocks interpreted to be caused by continental subduction and/or collision. Other metamorphic rocks (of Caledonian age) exposed in allochthonous nappes are solely characterised by greenschist-, amphibolite- and/or MP granulite "facies" mineral assemblages that can be interpreted, in the absence of retrogression, to have formed in less deeply subducted (and/or metamorphic) environments. This duality in metamorphic "facies" allows for a discrimination (at least theoretically) between "deep" versus "shallow" rooted nappes (in central parts of the Scandinavian Caledonides). Conform this reasoning, this duality should also be present within the Caledonian mineral assemblages (= metamorphic overprint) of orogenic peridotites (in

Silicate-Oxide Equilibria in the Wilson Lake Terrane, Labrador - Evidence for a Pre- Metamorphic Oxidizing Event

NASA Astrophysics Data System (ADS)

Korhonen, F. J.; Stout, J. H.

2006-05-01

The presence of Fe3+ and Ti in silicates and their presumed equilibration with Fe2+-Fe3+-Ti oxide minerals has long been recognized as an important factor in metamorphic phase equilibria. The Red Wine Mountains massif is a granulite facies unit in the Wilson Lake terrane of central Labrador, where this equilibration is especially important for estimating both temperature and fO2 during peak metamorphism. Peak assemblages are sapphirine + quartz, and orthopyroxene + sillimanite + quartz. The coexisting oxides, which are largely responsible for the pronounced aeromagnetic high of the massif, consist of nearly pure magnetite and an exsolved titanohematite. Estimates of fO2 based on magnetite + integrated titanohematite compositions are slightly below that defined by the pure magnetite-hematite buffer. This assemblage is also responsible for the magnetic signature of metagabbro and metanorite dikes, a fact which challenges the conventional wisdom that the high Fe3+ content of the host paragneisses was inherited from a highly oxidized ferruginous shale. We suggest here that prior to granulite facies metamorphism, an oxidizing hydrothermal event either coeval or following the emplacement of mafic dikes into the paragneiss host was responsible for the highly oxidized nature of the massif as a whole. Subsequent metamorphism then produced the observed assemblages. This scenario is supported by recent U-Pb zircon and monazite ages of ca. 1626 ± 10 Ma, which indicate that both metagabbro dikes and host paragneiss were metamorphosed at the same time. Dike emplacement and the oxidizing event must have preceded 1626 Ma. The implications of this pre-metamorphic oxidizing event is that Fe3+ becomes an inherent and fixed component in the chemical system during metamorphism. Phase relationships, preliminary thermodynamic modeling, and geothermobarometric constraints indicate that peak temperatures are lower than those previously determined for Fe3+-absent systems. More appropriate

Temporal and spatial distribution of Paleozoic metamorphism in the southern Appalachian Blue Ridge and Inner Piedmont delimited by ion microprobe U-Pb ages of metamorphic zircon

USGS Publications Warehouse

Merschat, Arthur J.; Bream, Brendan R.; Huebner, Matthew T.; Hatcher, Robert D.; Miller, Calvin F.

2017-01-01

Ion microprobe U-Pb zircon rim ages from 39 samples from across the accreted terranes of the central Blue Ridge, eastward across the Inner Piedmont, delimit the timing and spatial extent of superposed metamorphism in the southern Appalachian orogen. Metamorphic zircon rims are 10–40 µm wide, mostly unzoned, and dark gray to black or bright white in cathodoluminescence, and truncate and/or embay interior oscillatory zoning. Black unzoned and rounded or ovoid-shaped metamorphic zircon morphologies also occur. Th/U values range from 0.01 to 1.4, with the majority of ratios less than 0.1. Results of 206Pb/238U ages, ±2% discordant, range from 481 to 305 Ma. Clustering within these data reveals that the Blue Ridge and Inner Piedmont terranes were affected by three tectonothermal events: (1) 462–448 Ma (Taconic); (2) 395–340 Ma (Acadian and Neoacadian); and (3) 335–322 Ma, related to the early phase of the Alleghanian orogeny. By combining zircon rim ages with metamorphic isograds and other published isotopic ages, we identify the thermal architecture of the southern Appalachian orogen: juxtaposed and superposed metamorphic domains have younger ages to the east related to the marginward addition of terranes, and these domains can serve as a proxy to delimit terrane accretion. Most 462–448 Ma ages occur in the western and central Blue Ridge and define a continuous progression from greenschist to granulite facies that identifies the intact Taconic core. The extent of 462–448 Ma metamorphism indicates that the central Blue Ridge and Tugaloo terranes were accreted to the western Blue Ridge during the Taconic orogeny. Zircon rim ages in the Inner Piedmont span almost 100 m.y., with peaks at 395–385, 376–340, and 335–322 Ma, and delimit the Acadian-Neoacadian and Alleghanian metamorphic core. The timing and distribution of metamorphism in the Inner Piedmont are consistent with the Devonian to Mississippian oblique collision of the Carolina superterrane

Comparative chronology of Archean HT/UHT crustal metamorphism

NASA Astrophysics Data System (ADS)

Caddick, Mark; Dragovic, Besim; Guevara, Victor

2017-04-01

Attainment of high crustal heat fluxes and consequent partial melting is critical to the stabilization of continental roots. Understanding the processes and timescales behind partial melting of continental crust in the Archean is thus paramount for understanding Archean tectonic modes and how stable cratons formed. High-temperature (HT) to ultrahigh-temperature (UHT) metamorphic rocks can record evidence for dynamic processes that result in advective heat fluxes and a substantial deviation from normal crustal geothermal gradients. Examination of the pressure-temperature conditions and timescales of HT/UHT metamorphism is thus essential to understanding the tectonic processes behind extreme crust heat fluxes and the formation of stable cratonic crust. Here, utilizing both traditional and nontraditional petrologic and geochronologic techniques, we compare the pressure-temperature-time paths of two Neoarchean terranes: the eastern Beartooth Mountains of the Wyoming Craton and the Pikwitonei Granulite Domain of the Superior Province. The Beartooth Mountains of Montana, USA, expose Archean rocks of the Wyoming Craton that are dominated by an ˜2.8 Ga calc-alkaline granitoid batholith known as the Long Lake Magmatic Complex (LLMC). The LLMC contains widespread, up to km-scale metasedimentary roof pendants, with ID-TIMS Sm-Nd garnet geochronology and laser ablation split stream (LASS) monazite geochronology suggesting that metamorphism occurred almost 100 Ma after entrainment by the LLMC [1]. Phase equilibria modeling and Zr-in-rutile thermometry constrain peak pressures and temperatures of ˜6-7 kbar and ˜780-800˚ C. Major element diffusion modeling of garnet suggest that granulite-facies temperatures were only maintained for a short duration, < 2 Ma. In contrast, the Pikwitonei Granulite Domain consists of >150,000 km2 of high-grade metamorphic rocks situated in the NW Superior Province. Phase equilibria modeling and trace element thermometry constrain peak

Geochemistry, Metamorphic Assemblages, and Microstructures in Small Ultramafic Bodies from the Northern Nason Terrane, Washington

NASA Astrophysics Data System (ADS)

Magloughlin, J. F.

2014-12-01

Ultramafic bodies ranging from <1 to 2500 m in length occur in multiple settings across the northern part of the Nason Terrane in the North Cascade Mountains of Washington State. Within the Wenatchee Ridge Orthogneiss (WRO) the bodies are approximately equidimensional, ranging from dm-scale metasomatized lenses up to an exposed diameter of (typically) approximately 40 m. Some bodies are completely serpentinized, but others include dunite, harzburgite, and rare seams of pyroxenite. Many are rimmed by blackwall (talc, phlogopite, tremolite, chlorite, serpentine) coinciding with the Late Cretaceous metamorphism. The Napeequa Ultramafic Body (NUB), cut through and well exposed by the Napeequa River west of Lake Wenatchee, is within the White River Shear Zone (WRSZ, Magloughlin & McEwan, 1988). Though highly variable, it consists of dunite and peridotite and is variably serpentinized with common Mg-amphibole. Assemblages include serp+carb+chl+talc+opq and suggest upper greenschist to low amphibolite facies overprinting. Rare high-strain zones resemble relict pseudotachylyte veins. More common are ultramylonitic zones with olivine grain sizes of <5 microns, suggesting terrane-boundary paleostresses of >250 MPa. The Nine Mile Creek Ultramafic Body (NMCUB) and Grave Ultramafic Body (GUB) are the largest bodies outside of the White River Shear Zone, and are approximately 300 m and 800 long, respectively. Both are characterized by ol+talc+amph along with chlorite pseudomorphs, commonly cut by <40 micron thick ribbons of calcite, and rarely containing Si defined by chromite. These tectonites contain fine-grained olivine, but post-deformational, metamorphic cummingtonite and tremolite. In both bodies, a moderate to strong foliation is developed. It is suggested both bodies are retrogressed garnet peridotites. An interesting problem is why the possible retrogressed garnet peridotite bodies are present south of the WRSZ and surrounded by the metatonalites of the WRO, but none

Stepwise exhumation of the Triassic Lanling high-pressure metamorphic belt in Central Qiangtang, Tibet: Insights from a coupled study of metamorphism, deformation, and geochronology

NASA Astrophysics Data System (ADS)

Liang, Xiao; Wang, Genhou; Yang, Bo; Ran, Hao; Zheng, Yilong; Du, Jinxue; Li, Lingui

2017-04-01

The E-W trending Central Qiangtang metamorphic belt (CQMB) is correlated to the Triassic orogeny of the Paleo-Tethys Ocean prior to Cenozoic growth of the Tibetan Plateau. The well-exposed Lanling high-pressure, low-temperature (HP-LT) metamorphic complex was chosen to decipher the process by which it was exhumed, which thereby provides insights into the origin of the CQMB and Qiangtang terrane. After a detailed petrological and structural mapping, three distinct N-S-trending metamorphic domains were distinguished. Microscopic observations show that core domain garnet (Grt)-bearing blueschist was exhumed in a heating plus depressurization trajectory after peak eclogitic conditions, which is more evident in syntectonic vein form porphyroblastic garnets with zoning typical of a prograde path. Grt-free blueschist of the mantle domain probably underwent an exhumation path of temperature increasing and dehydration, as evidenced by pervasive epidote veins. The compilation of radiometric results of high-pressure mineral separates in Lanling and Central Qiantang, and reassessments on the published phengite data sets of Lanling using Arrhenius plots allow a two-step exhumation model to be formulated. It is suggested that core domain eclogitic rocks were brought onto mantle domain blueschist facies level starting at 244-230 Ma, with exhumation continuing to 227-223.4 Ma, and subsequently were exhumed together starting at 223-220 Ma, reaching lower greenschist facies conditions generally after 222-217 Ma. These new observations indicate that the CQMB formed as a Triassic autochthonous accretionary complex resulting from the northward subdcution of the Paleo-Tethys Ocean and that HP-LT rocks therein were very probably exhumed in an extensional regime.

The timing of metamorphism in the Odenwald-Spessart basement, Mid-German Crystalline Zone

NASA Astrophysics Data System (ADS)

Will, T. M.; Schulz, B.; Schmädicke, E.

2017-07-01

New in situ electron microprobe monazite and white mica 40Ar/39Ar step heating ages support the proposition that the Odenwald-Spessart basement, Mid-German Crystalline Zone, consists of at least two distinct crustal terranes that experienced different geological histories prior to their juxtaposition. The monazite ages constrain tectonothermal events at 430 ± 43 Ma, 349 ± 14 Ma, 331 ± 16 Ma and 317 ± 12 Ma/316 ± 4 Ma, and the 40Ar/39Ar analyses provide white mica ages of 322 ± 3 Ma and 324 ± 3 Ma. Granulite-facies metamorphism occurred in the western Odenwald at c. 430 and 349 Ma, and amphibolite-facies metamorphism affected the eastern Odenwald and the central Spessart basements between c. 324 and 316 Ma. We interpret these data to indicate that the Otzberg-Michelbach Fault Zone, which separates the eastern Odenwald-Spessart basement from the Western Odenwald basement, is part of the Rheic Suture, which marks the position of a major Variscan plate boundary separating Gondwana- and Avalonia-derived crustal terranes. The age of the Carboniferous granulite-facies event in the western Odenwald overlaps with the minimum age of eclogite-facies metamorphism in the adjacent eastern Odenwald. The granulite- and eclogite-facies rocks experienced contrasting pressure-temperature paths but occur in close spatial proximity, being separated by the Rheic Suture. As high-pressure and high-temperature metamorphisms are of similar age, we interpret the Odenwald-Spessart basement as a paired metamorphic belt and propose that the adjacent high-pressure and high-temperature rocks were metamorphosed in the same subduction zone system. Juxtaposition of these rocks occurred during the final stages of the Variscan orogeny along the Rheic Suture.

Divergent plate motion drives rapid exhumation of (ultra)high pressure rocks

NASA Astrophysics Data System (ADS)

Liao, Jie; Malusà, Marco G.; Zhao, Liang; Baldwin, Suzanne L.; Fitzgerald, Paul G.; Gerya, Taras

2018-06-01

Exhumation of (ultra)high pressure [(U)HP] rocks by upper-plate divergent motion above an unbroken slab, first proposed in the Western Alps, has never been tested by numerical methods. We present 2D thermo-mechanical models incorporating subduction of a thinned continental margin beneath either a continental or oceanic upper plate, followed by upper-plate divergent motion away from the lower plate. Results demonstrate how divergent plate motion may trigger rapid exhumation of large volumes of (U)HP rocks directly to the Earth's surface, without the need for significant overburden removal by erosion. Model exhumation paths are fully consistent with natural examples for a wide range of upper-plate divergence rates. Exhumation rates are systematically higher than the divergent rate imposed to the upper plate, and the modeled size of exhumed (U)HP domes is invariant for different rates of upper-plate divergence. Major variations are instead predicted at depth for differing model scenarios, as larger amounts of divergent motion may allow mantle-wedge exhumation to shallow depth under the exhuming domes. The transient temperature increase, due to ascent of mantle-wedge material in the subduction channel, has a limited effect on exhumed continental (U)HP rocks already at the surface. We test two examples, the Cenozoic (U)HP terranes of the Western Alps (continental upper plate) and eastern Papua New Guinea (oceanic upper plate). The good fit between model predictions and the geologic record in these terranes encourages the application of these models globally to pre-Cenozoic (U)HP terranes where the geologic record of exhumation is only partly preserved.

Regional metamorphism at extreme conditions: Implications for orogeny at convergent plate margins

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Chen, Ren-Xu

2017-09-01

Regional metamorphism at extreme conditions refers either to Alpine-type metamorphism at low geothermal gradients of <10 °C/km, or to Buchan-type metamorphism at high geothermal gradients of >30 °C/km. Extreme pressures refer to those above the polymorphic transition of quartz to coesite, so that ultrahigh-pressure (UHP) eclogite-facies metamorphism occurs at mantle depths of >80 km. Extreme temperatures refer to those higher than 900 °C at crustal depths of ≤80 km, so that ultrahigh-temperature (UHT) granulite-facies metamorphism occurs at medium to high pressures. While crustal subduction at the low geothermal gradients results in blueschist-eclogite facies series without arc volcanism, heating of the thinned orogenic lithosphere brings about the high geothermal gradients for amphibolite-granulite facies series with abundant magmatism. Therefore, UHP metamorphic rocks result from cold lithospheric subduction to the mantle depths, whereas UHT metamorphic rocks are produced by hot underplating of the asthenospheric mantle at the crustal depths. Active continental rifting is developed on the thinned lithosphere in response to asthenospheric upwelling, and this tectonism is suggested as a feasible mechanism for regional granulite-facies metamorphism, with the maximum temperature depending on the extent to which the mantle lithosphere is thinned prior to the rifting. While lithospheric compression is associated with subduction metamorphism in accretionary and collisional orogens, the thinned orogenic lithosphere undergoes extension due to the asthenospheric upwelling to result in orogen-parallel rifting metamorphism and magmatism. Thus, the rifting metamorphism provides a complement to the subduction metamorphism and its operation marks the asthenospheric heating of the orogenic lithosphere. Because of the partial melting and melt extraction of the lower continental crust, contemporaneous granite-migmatite-granulite associations may serve as a petrological

Origin of retrograde fluid in ultrahigh-pressure metamorphic rocks: Constraints from mineral hydrogen isotope and water content changes in eclogite gneiss transitions in the Sulu orogen

NASA Astrophysics Data System (ADS)

Chen, Ren-Xu; Zheng, Yong-Fei; Gong, Bing; Zhao, Zi-Fu; Gao, Tian-Shan; Chen, Bin; Wu, Yuan-Bao

2007-05-01

By taking advantage of having depth profiles between contrasting lithologies from core samples of the Chinese Continental Scientific Drilling (CCSD) project, a combined study was carried out to examine changes in mineral H isotope, total water and hydroxyl contents in garnet and omphacite across the contacts between ultrahigh-pressure (UHP) eclogite and gneiss in the Sulu orogen, east-central China. The samples of interest were from two continuous core segments from the CCSD main hole at depths of 734.21-737.16 and 929.67-932.86 m, respectively. The results show δD values of -116‰ to - 64‰ for garnet and -104‰ to -82‰ for omphacite, consistent with incorporation of meteoric water into protoliths of UHP metamorphic rocks by high-T alteration. Both equilibrium and disequilibrium H isotope fractionations were observed between garnet and omphacite, suggesting fluid-assisted H isotope exchange at local scales during amphibolite-facies retrogression. While bulk water analysis gave total H 2O concentrations of 522-1584 ppm for garnet and 1170-20745 ppm for omphacite, structural hydroxyl analysis yielded H 2O contents of 80-413 ppm for garnet and 228-412 ppm for omphacite. It appears that significant amounts of molecular H 2O are present in the minerals, pointing to enhanced capacity of water storage in the UHP eclogite minerals. Hydrogen isotope variations in the transition between eclogite and gneiss show correlations with variations in their water contents. Petrographically, the degree of retrograde metamorphism generally increases with decreasing distance from the eclogite-gneiss boundary. Thus, retrograde metamorphism results in mineral reactions and H isotope variation. Because hydroxyl solubility in nominally anhydrous minerals decreases with dropping pressure, significant amounts of water are expected to be released from the minerals during decompression exhumation. Decompression exsolution of structural hydroxyl from 1 m 3 volume of eclogite composed of

Thermobarometric constraints on mid-Cretaceous to late Cretaceous metamorphic events in the western metamorphic belt of the Coast Mountains complex near Petersburg, southeastern Alaska

USGS Publications Warehouse

Himmelberg, Glen R.; Brew, David A.

2005-01-01

The western metamorphic belt is part of the Coast Mountains Complex of southeastern Alaska and western Canada. This complex formed as a result of mid-Cretaceous through middle Eocene crustal shortening between the previously amalgamated Wrangellia and Alexander terranes (Insular superterrane) and previously accreted terranes of the North American continental margin (Intermontane superterrane). The western metamorphic belt, which ranges from a few kilometers to several tens of kilometers in width, records a complex sequence of contact-metamorphic and regional metamorphic events, the most significant of which are designated M1R, M2C-R, and M3R. The M1R regional metamorphic event ranged in grade from subgreenschist to greenschist facies and was overprinted by the M2C-R and M3R metamorphic events. The M2C-R metamorphic event is recorded in discrete contact-metamorphic aureoles and regional metamorphic-mineral assemblages related to tonalite-granodiorite plutons of the Admiralty-Revillagigedo plutonic belt. The M3R metamorphic belt, which is adjacent to the M2C-R belt, is characterized by regional Barrovian isograds of garnet, staurolite, kyanite, and sillimanite. Using the THERMOCALC program, pressure-temperature (P-T) conditions for the M2C-R metamorphic event are estimated to be in the ranges 5.3-7.5 kbars and 525-640 deg.C and for the M3R metamorphic event in the ranges 9.4-12.6 kbars and 730-895 deg.C. The M2C-R metamorphic event occurred at approximately 90 Ma, but the timing of the M3R metamorphic event is poorly documented and uncertain. On the basis of an 40Ar/39Ar age on actinolitic amphibole and a Sm-Nd age on garnet core, the timing of metamorphism might be constrained between 90+/-1 and 80+/-9 Ma, although the Sm-Nd age of 80+/-9 m.y. possibly reflects postpeak growth. Thermobarometric data suggest that the two events occurred at different crustal levels and followed different P-T paths. No evidence exists that M2C-R metamorphic-mineral assemblages were

Differentiating Metamorphic Events in a Polymetamorphic Terrane using Zr-in-Ttn thermometry and Titanite U-Pb Geochronology

NASA Astrophysics Data System (ADS)

Kenney, M.; Roeske, S.; Mulcahy, S. R.; Cottle, J. M.; Coble, M. A.

2016-12-01

In polymetamorphic terranes, it is problematic to link ages from geochronometers to metamorphic fabrics and, therefore, to a specific deformation event(s). It is necessary to analyze a mineral which may preserve multiple age domains. Titanite has been shown to retain multiple age and elemental domains in single grains through high-grade metamorphism. In this study, titanite U-Pb geochronology is used to examine whether ages are thermally reset along a sample transect towards a mylonitic shear zone in NW Argentina. This work also seeks to understand the conditions under which titanite resists resetting. A combination of petrographic and electron microprobe analyses reveal the textures and compositional domains in titanite, garnet, and hornblende. Titanite are elongate, wrapped by the mylonitic fabric, and have patchy elemental zoning. Garnet has distinct cores with prograde zoning and thin rims, which appear to be in equilibrium with the fabric defining minerals. Hornblende has inclusion rich cores and thin overgrowth rims in equilibrium with the fabric defining minerals. In-situ U-Pb and trace element data was collected in titanite from four samples, which all preserve lower-intercept ages between 900Ma and 1.0Ga. We observed no correlation between age and elemental domains; these domains correlate with Al and Nb variations. Zr-in-titanite temperatures preserve upper amphibolite facies conditions, 660ºC-710ºC. Given these results, we conclude that titanite U-Pb ages and temperatures reflect original Grenville metamorphism. 40Ar/39Ar hornblende cooling ages, of 515 Ma, suggested titanite may be reset near the shear zone but overprinting P-T of 560ºC and 0.8 GPa, fluid infiltration, and deformation did not cause significant Pb loss. Overprinting conditions and cooling ages suggest that rims of garnet and hornblende correlate to Paleozoic metamorphism, while textural evidence and titanite ages suggest garnet and hornblende cores grew during the Proterozoic.

Late Paleozoic orogeny in Alaska's Farewell terrane

USGS Publications Warehouse

Bradley, D.C.; Dumoulin, Julie A.; Layer, P.; Sunderlin, D.; Roeske, S.; McClelland, B.; Harris, A.G.; Abbott, G.; Bundtzen, T.; Kusky, T.

2003-01-01

Evidence is presented for a previously unrecognized late Paleozoic orogeny in two parts of Alaska's Farewell terrane, an event that has not entered into published scenarios for the assembly of Alaska. The Farewell terrane was long regarded as a piece of the early Paleozoic passive margin of western Canada, but is now thought, instead, to have lain between the Siberian and Laurentian (North American) cratons during the early Paleozoic. Evidence for a late Paleozoic orogeny comes from two belts located 100-200 km apart. In the northern belt, metamorphic rocks dated at 284-285 Ma (three 40Ar/39Ar white-mica plateau ages) provide the main evidence for orogeny. The metamorphic rocks are interpreted as part of the hinterland of a late Paleozoic mountain belt, which we name the Browns Fork orogen. In the southern belt, thick accumulations of Pennsylvanian-Permian conglomerate and sandstone provide the main evidence for orogeny. These strata are interpreted as the eroded and deformed remnants of a late Paleozoic foreland basin, which we name the Dall Basin. We suggest that the Browns Fork orogen and Dall Basin comprise a matched pair formed during collision between the Farewell terrane and rocks to the west. The colliding object is largely buried beneath Late Cretaceous flysch to the west of the Farewell terrane, but may have included parts of the so-called Innoko terrane. The late Paleozoic convergent plate boundary represented by the Browns Fork orogen likely connected with other zones of plate convergence now located in Russia, elsewhere in Alaska, and in western Canada. Published by Elsevier B.V.

Structure and metamorphism of the Franciscan Complex, Mt. Hamilton area, Northern California

USGS Publications Warehouse

Blake, M.C.; Wentworth, C.M.

1999-01-01

Truncation of metamorphic isograds and fold axes within coherent terranes of Franciscan metagraywacke by intervening zones of melange indicate that the melange is tectonic and formed after the subduction-related metamorphism and folding. These relations are expressed in two terranes of blueschist-facies rocks of the Franciscan Complex in the Mt. Hamilton area, northern California-the Jurassic Yolla Bolly terrane and the structurally underlying Cretaceous Burnt Hills terrane. Local preservation in both terranes of basal radiolarian chert and oceanic basalt beneath continent-derived metagraywacke and argillite demonstrates thrust repetition within the coherent terranes, although these relations are scarce near Mt. Hamilton. The metagraywackes range from albite-pumpellyite blueschists to those containing well-crystallized jadeitic pyroxene, and a jadeite-in isograd can be defined in parts of the area. Primary bedding defines locally coherent structural orientations and folds within the metagraywacke units. These units are crosscut by thin zones of tectonic melange containing blocks of high-grade blueschist, serpentinite, and other exotic rocks, and a broader, but otherwise identical melange zone marks the discordant boundary between the two terranes.

Middle Proterozoic age for the Montpelier Anorthosite, Goochland terrane, eastern Piedmont, Virginia

USGS Publications Warehouse

Aleinikoff, J.N.; Horton, J. Wright; Walter, M.

1996-01-01

Uranium-lead dating of zircons from the Montpelier Anorthosite confirms previous interpretations, based on equivocal evidence, that the Goochland terrane in the eastern Piedmont of Virginia contains Grenvillian basement rocks of Middle Proterozoic age. A very few prismatic, elongate, euhedral zircons, which contain 12-29 ppm uranium, are interpreted to be igneous in origin. The vast majority of zircons are more equant, subangular to anhedral, contain 38-52 ppm uranium, and are interpreted to be metamorphic in origin. One fraction of elongate zircon, and four fragments of a very large zircon (occurring in a nelsonite segregation) yield an upper intercept age of 1045 ?? 10 Ma, interpreted as the time of anorthosite crystallization. Irregularly shaped metamorphic zircons are dated at 1011 ?? 2 Ma (weighted average of the 207Pb/206Pb ages). The U-Pb isotopic systematics of metamorphic titanite were reset during the Alleghanian orogeny at 297 ?? 5 Ma. These data provide a minimum age for gneisses of the Goochland terrane that are intruded by the anorthosite. Middle Proterozoic basement rocks of the Goochland terrane may be correlative with those in the Shenandoah massif of the Blue Ridge tectonic province, as suggested by similarities between the Montpelier Anorthosite and the Roseland anorthosite. Although the areal extent of Middle Proterozoic basement and basement-cover relations in the eastern Piedmont remain unresolved, results of this investigation indicate that the Goochland terrane is an internal massif of Laurentian crust rather than an exotic accreted terrane.

Stable isotope geochemistry of ultrahigh pressure metamorphic rocks from the Dabie-Sulu orogen in China: implications for geodynamics and fluid regime

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Fu, Bin; Gong, Bing; Li, Long

2003-07-01

Discovery of coesite, diamond, and extreme 18O-depletion in eclogites from the Dabie-Sulu orogen in central-east China has contributed much to our understanding of subduction of continental crust to mantle depths and its subsequent exhumation. Hydrogen, oxygen, and carbon isotope distributions were systematically investigated in the past 8 years for ultrahigh pressure (UHP) eclogites, gneisses, granulites, marbles, and peridotites from this exciting region. The available data show the following characteristic features: (1) variable δ18O values of -11‰ to +10‰ for the eclogites and gneisses, with both equilibrium and disequilibrium fractionations of oxygen isotopes among minerals; (2) disequilibrium fractionation of hydrogen isotopes between mica and epidote from both eclogites and gneisses, with low δD values up to -127‰ to -100‰ for phengite; (3) negative δ13C values of -28‰ to -21‰ for apatite as well as host-eclogites and gneisses; (4) positive δ13C values of +1‰ to +6‰ for coesite-bearing marble associated with eclogites; (5) zircons from metamorphic rocks of different grades show a large variation in δ18O from -11‰ to +9‰, with U-Pb ages of 700 to 800 Ma for the timing of low- δ18O magma crystallization. It appears that the UHP metamorphic rocks exhibit ranges of δ18O values that are typical of potential precursor protolith rocks. Preservation of the oxygen isotope equilibrium fractionations among the minerals of the UHP eclogites and gneisses suggests that these rocks acquired the low δ18O values by meteoric-hydrothermal alteration before the UHP metamorphism. Thus, the UHP metamorphic rocks largely reflect the δ18O values of their premetamorphic igneous or sedimentary precursors. The stable isotope data demonstrate that basaltic, granitic, and sedimentary protoliths of the eclogites, orthogneiss, and paragneiss in the orogen were at or near the earth's surface, and subjected to varying degrees of water-rock interaction at some

Crustal structure and continental dynamics of Central China: A receiver function study and implications for ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

He, Chuansong; Dong, Shuwen; Chen, Xuanhua; Santosh, M.; Li, Qiusheng

2014-01-01

The Qinling-Tongbai-Hong'an-Dabie-Sulu orogenic belt records the tectonic history of Paleozoic convergence between the South China and North China Blocks. In this study, the distribution of crustal thickness and P- and S-wave velocity ratio (Vp/Vs) is obtained by using the H-k stacking technique from the Dabie-Sulu belt in central China. Our results show marked differences in the crustal structure between the Dabie and Sulu segments of the ultrahigh-pressure (UHP) orogen. The lower crust in the Dabie orogenic belt is dominantly of felsic-intermediate composition, whereas the crust beneath the Sulu segment is largely intermediate-mafic. The crust of the Dabie orogenic belt is thicker by ca. 3-5 km as compared to that of the surrounding region with the presence of an ‘orogenic root’. The crustal thickness is nearly uniform in the Dabie orogenic belt with a generally smooth crust-mantle boundary. A symmetrically thickened crust in the absence of any deep-structural features similar to that of the Yangtze block suggests no supportive evidence for the proposed northward subduction of the Yangtze continental block beneath the North China Block. We propose that the collision between the Yangtze and North China Blocks and extrusion caused crustal shortening and thickening, as well as delamination of the lower crust, resulting in asthenospheric upwelling and lower crustal UHP metamorphism along the Dabie Orogen. Our results also reveal the presence of a SE to NW dipping Moho in the North China Block (beneath the Tran-North China Orogen and Eastern Block), suggesting the fossil architecture of the northwestward subduction of the Kula plate.

Metamorphism in the Potomac composite terrane, Virginia-Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drake, A.A. Jr.

1985-01-01

Metamorphic rocks in the Potomac Valley occur in three allochthon-precursory melange pairs unconformably overlain by the Popes Head Formation which is at greenschist facies of metamorphism. The highest motif, the Piney Branch Complex and Yorkshire Formation are also in the greenschist facies. The middle motif, consists of the Peters Creek Schist and the Sykesville Formation. Quartzose schists and metagraywacke of the Peters Creek contain serpentinite debris and have had a complex metamorphic history: Barrovian prograde to amphibolite facies (with sillimanite), a localized retrograde event producing chlorite phyllonite, and a later greenschist prograde event. The Sykeville is at biotite +/- garnetmore » grade and contains deformed olistoliths of Peters Creek, including phyllonite, at various grades. The lower motif consists of the Annandale Group (pelitic schists and metasandstone) and Indian Run Formation. The Annandale has experienced two greenschist metamorphisms. The Indian Run is at biotite +/- garnet grade and contains previously metamorphosed and deformed olistoliths of Annandale. The allochthons have had different histories, but after stacking they were metamorphosed with their melanges and the Popes Head to biotite grade. The Popes Head has experienced three phases of folding, the earliest synkinematic with Occoquan emplacement. These fold phases are superposed on earlier structures in the older rocks and are probably of Late Cambrian age (Penobscotian). Earlier deformation is probably of Late Proterozoic age (Cadomian). Neither of these deformations is recognized in North American rocks.« less

Gondwanan/peri-Gondwanan origin for the Uchee terrane, Alabama and georgia: Carolina zone or Suwannee terrane(?) and its suture with Grenvillian basement of the Pine Mountain window

USGS Publications Warehouse

Steltenpohl, M.G.; Mueller, P.M.; Heatherington, A.L.; Hanley, T.B.; Wooden, J.L.

2008-01-01

The poorly known, suspect, Uchee terrane occupies a critical tectonic position with regard to how and when peri-Gondwanan (Carolina) and Gondwanan (Suwannee) terranes were sutured to Laurentia. It lies sandwiched between Laurentian(?) continental basement exposed in the Pine Mountain window and adjacent buried Gondwanan crust of the Suwannee terrane. The Uchee terrane has been proposed as both a septum of Piedmont rocks that once was continuous across the erosionally breached Pine Mountain window or part of the Carolina zone. To help resolve this issue, we conducted U-Pb (SHRIMP-RG) (sensitive high-resolution ion microprobe-reverse geometry) zircon studies and whole-rock isotopic analyses of principal metasedimentary and metaplutonic units. U-Pb ages for zircons from the Phenix City Gneiss suggest igneous crystallization at ca. 620 Ma, inheritance ca. 1000 to ca. 1700 Ma, and a ca. 300 Ma (Alleghanian) overprint recorded by zircon rims. Zircons from the metasedimentary/metavolcaniclastic Moffits Mill Schist yield bimodal dates at ca. 620 and 640 Ma. The 620 to 640 Ma dates make these rocks age-equivalent to the oldest parts of the Carolina slate belt (Virgilina and Savannah River) and strongly suggest a Gondwanan (Pan-African and/or Trans-Brasiliano) origin for the Uchee terrane. Alternatively, the Uchee terrane may be correlative with metamorphic basement of the Suwannee terrane. The ca. 300 Ma overgrowths on zircons are compatible with previously reported 295 to 288 Ma 40Ar/39Ar hornblende dates on Uchee terrane rocks, which were interpreted to indicate deep tectonic burial of the Uchee terrane contemporaneous with the Alleghanian orogeny recorded in the foreland. Temperature-time paths for the Uchee terrane are similar to that of the Pine Mountain terrane, indicating a minimum age of ca. 295 Ma for docking. In terms of tectono-metamorphic history of the Uchee terrane, it is important to note that no evidence for intermediate "Appalachian" dates (e.g, Acadian or

Onset of the Sveconorwegian orogeny: 1220-1130 Ma bimodal magmatism, sedimentation and granulite-facies metamorphism

NASA Astrophysics Data System (ADS)

Bingen, Bernard; Viola, Giulio; Engvik, Ane K.; Solli, Arne

2013-04-01

indicates that Kongsberg was linked to Telemarkia, before 1147 Ma and before their final tectonic juxtaposition. A similar pattern is known between the Bamble and Telemarkia terranes, indicating similar relations. (4) The classical medium pressure granulite-facies metamorphism in Tromøy-Arendal, Bamble, was redated. Three granulite samples show metamorphic zircon at 1147 +/-18 and 1132 +/-7 Ma. Protolith ages between c. 1553 and 1544 Ma demonstrate a Gothian low-K calc-alkaline orthogneiss protolith and question recent interpretations representing the Tromøy complex as an early Sveconorwegian oceanic volcanic arc accreted to the Bamble terrane. (5) A granulite-facies domain was discovered north of Kragerø in Bamble, in an area generally assigned to amphibolites-facies metamorphism. Geothermobarometry and pseudosection calculation using the Grt +Opx +/-Cpx +Pl +Qtz assemblage yield an estimate of about 1.15 GPa and 800°C for peak granulite facies metamorphism. Late clinopyroxene and garnet zoning are consistent with an anticklockwise P-T path and suggest magma loading and heating of the crust. Soccer ball zircon dates this metamorphism at 1144 ±6 Ma. (6) C. 1193-1183 Ma A-type granite plutonism is reported in the Caledonian Middle-Allochthon Risberget Nappe and c. 1221-1204 Ma syenite plutons are known along the Sveconorwegian Frontal Deformation Zone. C. 1220-1130 Ma magmatism is however entirely lacking in the Idefjorden terrane. Using these constraints, we envisage the 1220-1130 Ma pre- to early-Sveconorwegian event in a trans(?)-tensional continental setting at the margin of Baltica, before final continental collision. The Telemarkia terrane was possibly located in a back arc position above an east dipping subduction system. Abundant magmatism is possibly a consequence of subduction of an oceanic ridge. Inversion took place after 1130 Ma leading to westwards thrusting of the Bamble and Kongsberg terranes.

Protolith relations of the Gravina belt and Yukon-Tanana terrane in central southeastern Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

McClelland, W.C.; Gehrels, G.E.; Patchett, P.J.

1992-01-01

Metamorphic rocks west of the Coast Mountains batholith in central southeastern Alaska are divided into the Gravina belt, Taku terrane, and newly defined Ruth assemblage. The Ruth assemblage comprises metapelite, quartzose metaclastic strata, quartzite, marble, felsic metatuff, mafic metavolcanic rocks, and orthogneiss. Depositional and emplacement ages of 367 {plus minus} 10 Ma and 345 {plus minus} 13 Ma inferred from discordant U/Pb zircon analyses on felsic metatuff and granodioritic orthogneiss, respectively, require that at least portions of the Ruth assemblage be Late Devonian and early Mississippian in age. The assemblage is similar in age and protolith to, and thus correlatedmore » with, the Yukon-Tanana terrane. The Gravina belt is characterized by upper Jurassic and lower Cretaceous mafic volcanic rocks and tuffaceous turbiditic clastic strata that unconformably overlie the Alexander terrane. Metamorphic rocks that structurally underlie the Taku terrane and Rugh assemblage are included in this assemblage. Trace element geochemistry and the abundance of pyroclastic flows associated with tuffaceous turbidites suggest that the Gravina belt evolved in an intra-arc basinal setting. In central southeastern Alaska, the mid-Cretaceous structure that currently separates the Ruth assemblage (Yukon-Tanana correlative) from the Gravina belt marks the fundamental boundary between the Alexander-Wrangellia terrane and inboard Yukon-Tanana and Stikine terranes.« less

Regional metamorphism in the Condrey Mountain Quadrangle, north-central Klamath Mountains, California

USGS Publications Warehouse

Hotz, Preston Enslow

1979-01-01

A subcircular area of about 650 km 2 in northern California and southwestern Oregon is occupied by rocks of the greenschist metamorphic facies called the Condrey Mountain Schist. This greenschist terrane is bordered on the east and west by rocks belonging to the amphibolite metamorphic facies that structurally overlie and are thrust over the Condrey Mountain Schist. The amphibolite facies is succeeded upward by metavolcanic and metasedimentary rocks belonging to the greenschist metamorphic facies. The Condrey Mountain Schist is composed predominantly of quartz-muscovite schist and lesser amounts of actinolite-chlorite schist formed by the metamorphism of graywacke and spilitic volcanic rocks that may have belonged to the Galice Formation of Late Jurassic age. Potassium-argon age determinations of 141?4 m.y. and 155?5 m.y. obtained on these metamorphic rocks seem to be incompatible with the Late Jurassic age usually assigned the Galice. The rocks that border the amphibolite facies are part of an extensive terrane of metavolcanic and metasedimentary rocks belonging to the western Paleozoic and Triassic belt. The metavolcanic rocks include some unmetamorphosed spilite but are mostly of the greenschist metamorphic facies composed of oligoclase (An15-20) and actinolite with subordinate amounts of chlorite and clinozoisiteepidote. The interbedded sedimentary rocks are predominantly argillite and slaty argillite, less commonly siliceous argillite and chert, and a few lenticular beds of marble. On the south, high-angle faults and a tabular granitic pluton separate the greenschist metavolcanic terrane from the amphibolite facies rocks; on the east, nonfoliated amphibolite is succeeded upward, apparently conformably, by metasedimentary rocks belonging to the greenschist metavolcanic terrane. In the southern part of Condrey Mountain quadrangle, an outlier of a thrust plate composed of the Stuart Fork Formation overlies the metavolcanic and metasedimentary rocks. The Stuart

Assembly of the Lhasa and Qiangtang terranes in central Tibet by divergent double subduction

NASA Astrophysics Data System (ADS)

Zhu, Di-Cheng; Li, Shi-Min; Cawood, Peter A.; Wang, Qing; Zhao, Zhi-Dan; Liu, Sheng-Ao; Wang, Li-Quan

2016-02-01

Integration of lithostratigraphic, magmatic, and metamorphic data from the Lhasa-Qiangtang collision zone in central Tibet (including the Bangong suture zone and adjacent regions of the Lhasa and Qiangtang terranes) indicates assembly through divergent double sided subduction. This collision zone is characterized by the absence of Early Cretaceous high-grade metamorphic rocks and the presence of extensive magmatism with enhanced mantle contributions at ca. 120-110 Ma. Two Jurassic-Cretaceous magmatic arcs are identified from the Caima-Duobuza-Rongma-Kangqiong-Amdo magmatic belt in the western Qiangtang Terrane and from the Along Tso-Yanhu-Daguo-Baingoin-Daru Tso magmatic belt in the northern Lhasa Terrane. These two magmatic arcs reflect northward and southward subduction of the Bangong Ocean lithosphere, respectively. Available multidisciplinary data reconcile that the Bangong Ocean may have closed during the Late Jurassic-Early Cretaceous (most likely ca. 140-130 Ma) through arc-arc "soft" collision rather than continent-continent "hard" collision. Subduction zone retreat associated with convergence beneath the Lhasa Terrane may have driven its rifting and separation from the northern margin of Gondwana leading to its accretion within Asia.

Ultrahigh pressure extraction of bioactive compounds from plants-A review.

PubMed

Xi, Jun

2017-04-13

Extraction of bioactive compounds from plants is one of the most important research areas for pharmaceutical and food industries. Conventional extraction techniques are usually associated with longer extraction times, lower yields, more organic solvent consumption, and poor extraction efficiency. A novel extraction technique, ultrahigh pressure extraction, has been developed for the extraction of bioactive compounds from plants, in order to shorten the extraction time, decrease the solvent consumption, increase the extraction yields, and enhance the quality of extracts. The mild processing temperature of ultrahigh pressure extraction may lead to an enhanced extraction of thermolabile bioactive ingredients. A critical review is conducted to introduce the different aspects of ultrahigh pressure extraction of plants bioactive compounds, including principles and mechanisms, the important parameters influencing its performance, comparison of ultrahigh pressure extraction with other extraction techniques, advantages, and disadvantages. The future opportunities of ultrahigh pressure extraction are also discussed.

Origin of narrow terranes and adjacent major terranes occurring along the denali fault in the eastern and central alaska range, alaska

USGS Publications Warehouse

Nokleberg, W.J.; Richter, D.H.

2007-01-01

Several narrow terranes occur along the Denali fault in the Eastern and Central Alaska Range in Southern Alaska. These terranes are the Aurora Peak, Cottonwood Creek, Maclaren, Pingston, and Windy terranes, and a terrane of ultramafic and associated rocks. Exterior to the narrow terranes to the south is the majorWrangellia island arc composite terrane, and to the north is the major Yukon Tanana metamorphosed continental margin terrane. Overlying mainly the northern margin of the Wrangellia composite terrane are the Kahiltna overlap assemblage to the west, and the Gravina- Nutzotin-Gambier volcanic-plutonic- sedimentary belt to the east and southeast. The various narrow terranes are interpreted as the result of translation of fragments of larger terranes during two major tectonic events: (1) Late Jurassic to mid-Cretaceous accretion of the Wrangellia island arc composite terrane (or superterrane composed of the Wrangellia, Peninsular, and Alexander terranes) and associated subduction zone complexes; and (2) starting in about the Late Cretaceous, dextral transport of the Wrangellia composite terrane along the Denali fault. These two major tectonic events caused: (1) entrapment of a lens of oceanic lithosphere along the suture belt between the Wrangellia composite terrane and the North American Craton Margin and outboard accreted terranes to form the ultramafic and mafic part of the terrane of ultramafic and associated rocks, (2) subsequent dextral translation along the Denali fault of the terrane of ultramafic and associated rocks, (3) dextral translation along the Denali fault of the Aurora Peak, Cottonwood Creek, and Maclaren and continental margin arc terranes from part of the Coast plutonic-metamorphic complex (Coast-North Cascade plutonic belt) in the southwest Yukon Territory or Southeastern Alaska, (4) dextral translation along the Denali fault of the Pingston passive continental margin from a locus along the North American Continental Margin, and (5

The Wisconsin magmatic terrane: An Early Proterozoic greenstone-granite terrane formed by plate tectonic processes

NASA Technical Reports Server (NTRS)

Schulz, K. J.; Laberge, G. L.

1986-01-01

The Wisconsin magmatic terrane (WMT) is an east trending belt of dominantly volcanic-plutonic complexes of Early Proterozoic age (approx. 1850 m.y.) that lies to the south of the Archean rocks and Early Proterozoic epicratonic sequence (Marquette Range Supergroup) in Michigan. It is separated from the epicratonic Marquette Range Supergroup by the high-angle Niagara fault, is bounded on the south, in central Wisconsin, by Archean gneisses, is truncated on the west by rocks of the Midcontinent rift system, and is intruded on the east by the post-orogenic Wolf river batholith. The overall lithologic, geochemical, metallogenic, metamorphic, and deformational characteristics of the WMT are similar to those observed in recent volcanic arc terranes formed at sites of plate convergence. It is concluded that the WMT represents an evolved oceanic island-arc terrane accreated to the Superior craton in the Early Proterozoic. This conclusion is strengthened by the apparent absence of Archean basement from most of the WMT, and the recent recognition of the passive margin character of the epicratonic Marquette Range Supergroup.

SHRIMP U-Pb evidence for a Late Silurian age of metasedimentary rocks in the Merrimack and Putnam-Nashoba terranes, eastern New England

USGS Publications Warehouse

Wintsch, R.P.; Aleinikoff, J.N.; Walsh, G.J.; Bothner, Wallace A.; Hussey, A.M.; Fanning, C.M.

2007-01-01

U-Pb ages of detrital, metamorphic, and magmatic zircon and metamorphic monazite and titanite provide evidence for the ages of deposition and metamorphism of metasedimentary rocks from the Merrimack and Putnam-Nashoba terranes of eastern New England. Rocks from these terranes are interpreted here as having been deposited in the middle Paleozoic above Neoproterozoic basement of the Gander terrane and juxtaposed by Late Paleozoic thrusting in thin, fault-bounded slices. The correlative Hebron and Berwick formations (Merrimack terrane) and Tatnic Hill Formation (Putnam-Nashoba terrane), contain detrital zircons with Mesoproterozoic, Ordovician, and Silurian age populations. On the basis of the age of the youngest detrital zircon population (???425 Ma), the Hebron, Berwick and Tatnic Hill formations are no older than Late Silurian (Wenlockian). The minimum deposition ages of the Hebron and Berwick are constrained by ages of cross-cutting plutons (414 ?? 3 and 418 ?? 2 Ma, respectively). The Tatnic Hill Formation must be older than the oldest metamorphic monazite and zircon (???407 Ma). Thus, all three of these units were deposited between ???425 and 418 Ma, probably in the Ludlovian. Age populations of detrital zircons suggest Laurentian and Ordovician arc provenance to the west. High grade metamorphism of the Tatnic Hill Formation soon after deposition probably requires that sedimentation and burial occurred in a fore-arc environment, whereas time-equivalent calcareous sediments of the Hebron and Berwick formations probably originated in a back-arc setting. In contrast to age data from the Berwick Formation, the Kittery Formation contains primarily Mesoproterozoic detrital zircons; only 2 younger grains were identified. The absence of a significant Ordovician population, in addition to paleocurrent directions from the east and structural data indicating thrusting, suggest that the Kittery was derived from peri-Gondwanan sources and deposited in the Fredericton Sea

Metamorphic P-T conditions across the Chugach Metamorphic Complex (Alaska)—A record of focussed exhumation during transpression

NASA Astrophysics Data System (ADS)

Bruand, Emilie; Gasser, Deta; Stüwe, Kurt

2014-03-01

The Chugach Metamorphic Complex (CMC) is a large high-grade metamorphic complex that developed in the Eocene within the Chugach accretionary complex along the margin of Alaska where subduction is still ongoing. The CMC has a conspicuous asymmetric structure with a migmatitic zone flanked in the north and west by amphibolite facies schists and in the south by a metabasite belt. To the north and south, major, crustal-scale fault zones juxtapose the Chugach terrane against much lower-grade and less-deformed sequences belonging to different terranes. Curiously these crustal-scale structures are known to have largely strike slip motion posing the question as to the nature of the exhumation of the high-grade complex between them. However, P-T conditions which would allow an estimation of the amount of exhumation were lacking for large parts of the complex. This paper presents petrographic descriptions, biotite-garnet thermometry, RSCM thermometry, average P-T calculations and pseudosection modelling from three major across-strike transects covering the complex from west to south-east. Our results reveal that, both temperature and pressure vary substantially across the complex. More specifically, peak metamorphic conditions evolve from 4-7 kbar and ~ 550-650 °C in the northern schist zone to 5-11 kbar and ~ 650-750 °C in the migmatite zone in the south of the complex. The higher pressure estimates in the south of the complex indicate that focussed exhumation must have occurred in this area and was probably initiated by the subduction of a high topographic relief (intra-oceanic arc or ridge subduction) and the accretion of the metabasite belt in the south. Exhumation of the CMC occurred in an overall transpressive strain regime, with strike-slip deformation concentrated along the northern Border Range fault zone and thrusting and exhumation focussed within the southern migmatite zone and splay faults of the Contact fault zone. The T/P ratios in the southern migmatite

Precambrian domains in Lithuania: evidence of terrane tectonics

NASA Astrophysics Data System (ADS)

Skridlaite, Grazina; Motuza, Gediminas

2001-09-01

The West Lithuanian Granulite (WLG) and East Lithuanian domains (ELD) form the Proterozoic basement of Lithuania and can be distinguished on the basis of differing structural patterns, lithologies, and evolutionary histories. They are juxtaposed along the Mid-Lithuanian Suture Zone (MLSZ). In the WLG, the main lithotectonic complexes comprise felsic and intermediate, mostly metasedimentary granulites in the south-west and mafic metaigneous granulites in the north-east. The former are interpreted as marine metapelites, while most of the mafic ones have been derived from island-arc tholeiites. These rock complexes trend NW-SE and are marked by contrasting gravity and magnetic anomalies. NE- and E-W-striking faults and shear zones complicate the potential-field patterns. Sets of NW-trending anomalies also extend from Lithuania across the Baltic Sea to south-central Sweden and indicate that the WLG complexes continue into the Baltic/Fennoscandian Shield. Voluminous anatectic granites alternate with the metapelites, whereas the mafic granulites occur together with enderbites and charnockites. In the ELD, the main structures produce strong, NNE-SSW-oriented gravity and magnetic anomalies which trend parallel to the Belarus-Baltic Granulite Belt (BBG) and other terranes situated still farther east. The ELD is composed of metasedimentary rocks interpreted as one-time graywackes, shales and dolomites accumulated in continental-margin arc and shallow-water basinal environments. Amphibolites and gabbros with MORB and IAT characteristics, and voluminous granitoids are also present. The coexistence of juvenile mafic rocks with continental-margin and shelf sediments suggests an oceanic back-arc setting. The two Lithuanian basement domains display contrasting metamorphic histories that suggest separate developments before the eventual amalgamation. In the WLG, the metapelites indicate peak metamorphism at high temperatures (up to 850-900°C) and moderate pressures (8-10 kbar

Stacking and metamorphism of continuous segments of subducted lithosphere in a high-pressure wedge: The example of Alpine Corsica (France)

NASA Astrophysics Data System (ADS)

Vitale Brovarone, Alberto; Beyssac, Olivier; Malavieille, Jacques; Molli, Giancarlo; Beltrando, Marco; Compagnoni, Roberto

2013-01-01

Alpine Corsica consists of a stack of variably metamorphosed units of continental and Tethys-derived rocks. It represents an excellent example of high-pressure (HP) orogenic belt, such as the Western Alps, exposed over a small and accessible area. Compared to the Western Alps, the geology of Alpine Corsica is poorly unraveled. During the 1970s-80s, based on either lithostratigraphic or metamorphic field observations, various classifications of the belt have been proposed, but these classifications have been rarely matched together. Furthermore, through time, the internal complexity of large domains has been progressively left aside in the frame of large-scale geodynamic reconstructions. As a consequence, major open questions on the internal structure of the belt have remained unsolved. Apart from a few local studies, Alpine Corsica has not benefited of modern developments in petrology and basin research. This feature results in several uncertainties when combining lithostratigraphic and metamorphic patterns and, consequently, in the definition of an exhaustive architecture of the belt. In this paper we provide a review on the geology of Alpine Corsica, paying particular attention to the available lithostratigraphic and metamorphic classifications of the metamorphic terranes. These data are completed by a new and exhaustive metamorphic dataset obtained by means of thermometry based on Raman Spectroscopy of Carbonaceous Material (RSCM). This technique provides reliable insights on the peak temperature of the metamorphic history for CM-bearing metasediments. A detailed metamorphic characterization of metasediments, which have been previously largely ignored due to retrogression or to the lack of diagnostic mineralogy, is thus obtained and fruitfully coupled with the available lithostratigraphic data. Nine main tectono-metamorphic units are defined, from subgreenschist (ca. 280-300 °C) to the lawsonite-eclogite-facies (ca. 500-550 °C) condition. These units are

Mineralogical Evidence for the Bulk Transformation of Continental Crust to Ultrahigh-Pressure Conditions in Subduction Zones

NASA Astrophysics Data System (ADS)

Peterman, E. M.; Hacker, B. R.; Kylander-Clark, A. R.

2005-12-01

Evidence for (ultra)high-pressure --(U)HP-- metamorphism in modern orogenic belts and the preservation of exhumed (U)HP terranes around the world suggest that subduction and exhumation of continental crust plays an important role in Phanerozoic plate tectonics. The Western Gneiss region (WGR) of Norway, a major (U)HP province extending over 60,000 km2, provides an excellent opportunity to study how subduction to depths >100 km affects continental crust. By studying a ~60 km wide transect bounded to the north by Vartdalsfjorden and Rovdefjorden and the south by the Möre og Romsdal county boundary, we are able to examine mineralogical changes that occurred during subduction and exhumation within a rock composed predominantly of orthogneiss and variably transformed mafic bodies, which indicate the depths to which these rocks were subducted. Previous studies (e.g. Hacker et al., 2005) have suggested that Caledonian deformation in WGR host gneisses is primarily limited to brittle-ductile fabrics characterized by greenschist to lower-amphibolite facies metamorphism; the majority of the deformation in the rocks, including the pervasive foliation and foliation-parallel isoclinal folds, occurred between 1200 and 900 Ma. On the northern half of our study area, however, locally occurring neoblastic garnet crosscuts the foliation in the gneiss. The boundary of this garnet zone coincides with the local HP-UHP boundary, as determined by the presence of coesite in eclogite. Because garnet can retain information about changes in pressure and temperature, as well as the availability of water within the crust to catalyze chemical reactions, our findings suggest that 1) portions of the orthogneiss did transform at high pressures, 2) the presence of garnet within the orthogneiss may indicate conditions that approximate UHP and can therefore be useful in defining the boundaries between UHP and HP conditions, and 3) the growth of garnet during (U)HP metamorphism may be controlled by

Metamorphism of eclogites from the UHP Maksyutov Complex, south Ural Mountains, Russia

NASA Astrophysics Data System (ADS)

Burlick, T. D.; Leech, M. L.

2013-12-01

The Maksyutov Complex is a mid- to late Paleozoic ultrahigh-pressure (UHP) subduction terrane in the south Ural Mountains of Russia. Radial fractures around quartz inclusions in garnet, omphacite, and glaucophane interpreted as pre-existing coesite; and microdiamond aggregates in garnet identified by Raman spectroscopy demonstrate Maksyutov rocks were subducted to UHP conditions (>2.8 GPa for coesite and >3.0 GPa for diamond at 600°C). Peak UHP eclogite-facies metamorphism (Grt+Omp+Ph+Coe+Rt ×Ttn) took place at c. 385 M and Maksyutov rocks were exhumed through retrograde blueschist-facies metamorphism (Grt+Gln+Ph+Qz×Chl×Ep) by 360 Ma. Pseudosections were constructed to constrain the P-T conditions recorded by the equilibrium mineral assemblanges in eclogites and their retrograded equivalents using bulk rock XRF analysis in the system Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2 and the suite of free energy minimization programs, Perple_X 6.6.8 [Connolly 2009] with the internally consistent end-member thermodynamic database from Holland and Powell [1998] (mod 2004); solution models for omphacite (Holland and Powell, 1996), clinoamphibole (Dale et al. 2005), white mica (Coggon & Holland 2002, Auzanneau et al 2010), chlorite and garnet (Holland and Powell 1998; Powell and Holland 1999), and feldspar (Thompson and Hovis 1979; Newton et al. 1980) were used with H2O as a saturated component. Both conventional thermometry, using microprobe analyses and Grt-Cpx cation exchange as well as pseudosection modeling result in higher peak equilibrium temperatures than has been previously been reported in the Maksyutov. Pseudosection modeling gives minimum P-T conditions of 625°-675°C and 2.8-3.1 GPa for peak assemblages from the least retrogressed eclogites, while Fe-Mg exchange thermometry yields temperatures of 775°C × 25°C for pressures ranging from 2.5 to 3.5 GPa.

Separation of major catechins from green tea by ultrahigh pressure extraction.

PubMed

Jun, Xi; Shuo, Zhao; Bingbing, Lu; Rui, Zhang; Ye, Li; Deji, Shen; Guofeng, Zhou

2010-02-15

This study presents a novel extraction technique, ultrahigh pressure extraction, to obtain major catechins from green tea leaves. The effects of various high pressure level (100, 200, 300, 400, 500, 600 MPa) on the extract are examined. HPLC chromatographic analyses determine the concentration of four major catechins and caffeine. The extraction yields of active ingredients with ultrahigh pressure extraction (400 MPa pressure) for only 15 min were given the same as those of organic solvent extraction for 2h. These excellent results for the ultrahigh pressure extraction are promising for the future separation of active ingredients from traditional Chinese herbal medicine. Copyright 2009 Elsevier B.V. All rights reserved.

Magnetic susceptibility of ultrahigh pressure eclogite: The role of retrogression

NASA Astrophysics Data System (ADS)

Xu, Haijun; Jin, Zhenmin; Mason, Roger; Ou, Xingong

2009-09-01

Retrograde metamorphism played the dominant role in changing the low-field rock magnetic properties and density of 198 specimens of variably retrograded eclogites from the main borehole of the Chinese Continental Scientific Drilling Project (CCSD) and from surface outcrops in the Donghai area in the southern part of the Sulu UHP belt, China. Bulk magnetic susceptibility ( κ) of unretrogressed UHP eclogite is controlled by whole-rock chemical composition and ranges from 397 to 2312 μSI with principal magnetic susceptibility carrying minerals paramagnetic garnet, omphacite, rutile and phengite. Partially retrograded eclogites show large variations in magnetic susceptibility between 804 and 24,277 μSI, with high mean magnetic susceptibility values of 4372 ± 4149 μSI caused by appreciable amounts of Fe-Ti oxide minerals such as magnetite, ilmenite and/or titanohematite produced by retrograde metamorphic reactions. Completely retrograded eclogites have lower susceptibilities of 1094 ± 600 μSI and amphibolite facies mineral assemblages lacking high magnetic susceptibility minerals. Jelínek's corrected anisotropy ( Pj) of eclogites ranges from 1.001 to 1.540, and shows a positive correlation with low-field magnetic susceptibility ( κ). Arithmetic mean bulk density ( ρ) shows a steady decrease from 3.54 ± 0.11 g/cm 3 (fresh eclogite) to 2.98 ± 0.06 g/cm 3 (completely retrograded eclogite). Retrograde metamorphic changes in mineral composition during exhumation appear to be the major factor causing variations in low field magnetic susceptibility and anisotropy. Retrograde processes must be taken into account when interpreting magnetic surveys and geophysical well logs in UHP metamorphic terranes, and petrophysical properties such as density and low-field magnetic susceptibility could provide a means for semi-quantifying the degree of retrogression of eclogite during exhumation.

Far-travelled permian chert of the North Fork terrane, Klamath mountains, California

USGS Publications Warehouse

Mankinen, E.A.; Irwin, W.P.; Blome, C.D.

1996-01-01

Permian chert in the North Fork terrane and correlative rocks of the Klamath Mountains province has a remanent magnetization that is prefolding and presumably primary. Paleomagnetic results indicate that the chert formed at a paleolatitude of 8.6?? ?? 2.5?? but in which hemisphere remains uncertain. This finding requires that these rocks have undergone at least 8.6?? ?? 4.4?? of northward transport relative to Permian North America since their deposition. Paleontological evidence suggests that the Permian limestone of the Eastern Klamath terrane originated thousands of kilometers distant from North America. The limestone of the North Fork terrane may have formed at a similar or even greater distance as suggested by its faunal affinity to the Eastern Klamath terrane and more westerly position. Available evidence indicates that convergence of the North Fork and composite Central Metamorphic-Eastern Klamath terranes occurred during Triassic or Early Jurassic time and that their joining together was a Middle Jurassic event. Primary and secondary magnetizations indicate that the new composite terrane containing these and other rocks of the Western Paleozoic and Triassic belt behaved as a single rigid block that has been latitudinally concordant with the North American craton since Middle Jurassic time.

Pressure-temperature evolution of Neoproterozoic metamorphism in the Welayati Formation (Kabul Block), Afghanistan

NASA Astrophysics Data System (ADS)

Collett, Stephen; Faryad, Shah Wali

2015-11-01

The Welayati Formation, consisting of alternating layers of mica-schist and quartzite with lenses of amphibolite, unconformably overlies the Neoarchean Sherdarwaza Formation of the Kabul Block that underwent Paleoproterozoic granulite-facies and Neoproterozoic amphibolite-facies metamorphic events. To analyze metamorphic history of the Welayati Formation and its relations to the underlying Sherdarwaza Formation, petrographic study and pressure-temperature (P-T) pseudosection modeling were applied to staurolite- and kyanite-bearing mica-schists, which crop out to the south of Kabul City. Prograde metamorphism, identified by inclusion trails and chemical zonation in garnet from the micaschists indicates that the rocks underwent burial from around 6.2 kbar at 525 °C to maximum pressure conditions of around 9.5 kbar at temperatures of around 650 °C. Decompression from peak pressures under isothermal or moderate heating conditions are indicated by formation of biotite and plagioclase porphyroblasts which cross-cut and overgrow the dominant foliation. The lack of sillimanite and/or andalusite suggests that cooling and further decompression occurred in the kyanite stability field. The results of this study indicate a single amphibolite-facies metamorphism that based on P-T conditions and age dating correlates well with the Neoproterozoic metamorphism in the underlying Sherdarwaza Formation. The rocks lack any paragenetic evidence for a preceding granulite-facies overprint or subsequent Paleozoic metamorphism. Owing to the position of the Kabul Block, within the India-Eurasia collision zone, partial replacement of the amphibolite-facies minerals in the micaschist could, in addition to retrogression of the Neoproterozoic metamorphism, relate to deformation associated with the Alpine orogeny.

Foundering and Exhumation of UHP Terranes: Race Car or School Bus?

NASA Astrophysics Data System (ADS)

Kylander-Clark, A. R.; Hacker, B. R.

2008-12-01

Recent geochronologic data from the giant ultrahigh-pressure (UHP) terrane, in the Western Gneiss Region of Norway, indicate that subduction and exhumation were relatively slow (a few mm/yr), and that the terrane was exhumed to the surface as a relatively thick, coherent body. These conclusions are in stark contrast to those reached in previous studies of some of the best-studied, smaller UHP terranes and suggest that the processes that form and/or exhume small UHP terranes are fundamentally different from the processes that affect large UHP terranes. These differences may be the result of variations in the buoyancy forces of different proportions of subducted felsic crust, mafic crust, and mantle lithosphere. Initial collision occurs via the subduction of smaller portions of continental material, such as microcontinents or ribbon continents. Because the proportion of continental crust is small, the processes involved in early UHP terrane formation are dominated by the oceanic slab; subduction rates are fast because average plate densities are high, and, as a result, subduction angles are steep. Because these smaller, thinner portions of crust are weak, they deform easily and mix readily with the mantle. As the collision matures, thicker and larger portions of continental material-such as a continental margin-are subducted, and the subduction regime changes from one that was ocean dominated to one that is continent dominated. The increased buoyancy of the larger volume of continental crust resists the pull of the leading oceanic lithosphere; subduction shallows and plate rates slow. Because the downgoing continent is thick, it is strong, remains cohesive and has limited interaction with the mantle. Although the subduction regime during early orogenesis is distinct from that during late orogenesis, the degree of mountain building and crustal thickening may be similar in both stages as small volumes and fast flow rates of buoyant material give way to large volumes

Tracing collisional route of the Danubian terranes (South Carpathians, Romania), using detrital U-Pb isotopic record

NASA Astrophysics Data System (ADS)

Balica, Constantin; Balintoni, Ioan; Campeanu, Mara

2017-04-01

The Danubian Realm of the South Carpathians, Romania, comprises a set of Alpine tectonic units exposed in a large tectonic window, under the Getic Realm. Each of the Danubian tectonic unit has a pre-Alpine basement composed mainly of high-grade metamorphic rocks, several Neoproterozoic granitoids (e.g. [1]), and low-grade Paleozoic formations. The whole basement is intruded by Variscan plutons. Two pre-Variscan metamorphic rock sequences of Pan-African origin [2] have been identified in the Danubian basement: The Drǎgșan and Lainici Pǎiuș. The relation between these two groups is purely tectonic, since they are separated by a Variscan thrust fault. An oceanic crust fragment, (i.e. Tisovița terrane), of presumably Early Devonian age separates the Drǎgșan and Lainici-Pǎiuș pre-Variscan terranes by the Poiana Mraconia terrane fragment of presumably Getic affinity. Generally, most of the doubts in what concen the origin and provenance of the two main terranes, Lainici-Pǎiuș and Drǎgșan, have been cleared up [3]. According to the latest review, the large metasedimentary Lainici-Pǎiuș tract, extensively crosscutted by a network of heterogranular leucogranite and pierced by Cadomian granitoid plutons correspond to a continental margin volcanic arc of Ganderian origin and Peri-Amazonian provenance. The time of formation is constrained, based on the presence of ca 600 Ma granitoid plutons which is Late Neoproterozoic [3]. On what concerns the Drǎgșan terrane, its main lithology (i.e. banded amphibolites) has oceanic island arc isotopic and geochemical signatures [3]. In fact, its lithostratigraphic composition - a lower orthogneiss assemblage, a median metabasic-ultrabasic assemblage and an upper mica gneiss unit- recommends it as of rather composite nature. One of the key points in constraining the age of the Drǎgșan terrane basement is the 808 Ma, age recorded by an augen gneiss zircons and the 811 Ma age recorded by some meta-rhyolite inherited zircons

Progressive Extensional Exhumation of the Ultrahigh-Pressure Tso Morari Terrain, NW Indian Himalaya

NASA Astrophysics Data System (ADS)

Hodges, K.; Clark, R.; Monteleone, B.; Sachan, H.; Mukherjee, B. K.; Ahmad, T.

2011-12-01

The core of the Tso Morari dome in the Ladakh region of NW India (roughly 33 °10'N; 78°10'E) is one of only two known ultrahigh-pressure (UHP) terrains in the Himalayan-Tibetan orogenic system. The quartzofeldspathic Puga Orthogneiss from the structurally deepest portions of the terrain does not contain UHP mineralogy but surrounds dismembered lenses of mafic eclogite with accessory coesite, confirming that at least the eclogite lenses experienced UHP metamorphic conditions (Mukherjee et al., 2003, International Geology Review; Sachan et al., 2004, European Journal of Mineralogy). U-Pb zircon dates from the Puga orthogneiss (53.3 ± 0.7 Ma: Leech et al., 2007, International Geology Review) provide what appear to be the most precise available constraints on the age of UHP metamorphism at Tso Morari provided we presume that the UHP assemblages in the eclogite lenses developed at the same time as the 53.3 ± 0.7 Ma metamorphic zircon in the orthogneiss. However, other components of the zircon population studied by Leech and co-workers, as well as the results obtained using other thermochronometers and geochronometers (de Sigoyer et al., 2004, Tectonics), demonstrate that a series of lower pressure metamorphic events also affected the Tso Morari terrain between ca. 53 Ma and ca. 45 Ma, implying rapid decompression at elevated temperatures (ca. 800 - 350°C). Our 1:50000-scale geologic mapping at Tso Morari provides evidence that this exhumation was largely accommodated by two previously unrecognized low-angle ductile detachments that separate the terrain into three tectonostratigraphic units with distinctive metamorphic histories. The structurally lowest shear zone (Karla detachment) separates the Puga Orthogneiss from overlying lower amphibolite facies metasedimentary rocks of the Zoboshisha Unit, which contains no UHP assemblages. Structurally higher and demonstrably younger detachments separate the Zoboshisha Unit and the Puga Orthogneiss from greenschist to

Over 400 m.y. metamorphic history of the Fennoscandian lithospheric segment in the Proterozoic (the East European Craton)

NASA Astrophysics Data System (ADS)

Skridlaite, G.; Bogdanova, S.; Taran, L.; Baginski, B.; Krzeminska, E.; Wiszniewska, J.; Whitehouse, M.

2009-04-01

Several Palaeoproterozoic terranes in the Fennoscandian lithospheric segment of the East European Craton (EEC) evolved differently prior to their final amalgamation at c. 1.8 Ga. South-westward younging of the major tectono-thermal events characterizes the Baltic -Belarus region between the Baltic and Ukrainian Shields of the EEC. While at c.1.89-1.87 Ga and 1.85-1.84 Ga rocks of some northern and eastern terranes (Estonia, Belarus and eastern Lithuania) experienced syncollisional, moderate P metamorphism, subduction-related volcanic island arc magmatism still dominated southwestern terranes in Lithuania and Poland. The available age determinations of metamorphic zircon (SIMS/NORDSIM and TIMS methods, Stockholm, SHRIMP method, RSES, ANU, Canberra) and metamorphic monazite (TIMS, Stockholm and EPMA method, Warsaw University) allow to distinguish several metamorphic events related to major orogenic processes: - 1.90-1.87 Ga amphibolite-facies H/MP metamorphism occurred along with emplacements of juvenile TTG-type granitoids in the North Estonian and Lithuanian-Belarus terranes. They are coeval with the main accretionary growth of the crust in the Svecofennian Domain in the Baltic Shield (e.g. Lahtinen et al., 2005). - 1.84-1.79 Ga high-grade metamorphism affected sedimentary and igneous rocks in almost all the terranes and is assumed to have been related to the major aggregation of the EEC (Bogdanova et al, 2006, 2008). In the metasedimentary granulites of western Lithuania, a prograde metamorphism commenced with monazite growth prior garnet at 1.84-1.83 Ga. The sediments and mafic igneous rocks in Lithuania, felsic igneous rocks in NE Poland underwent peak metamorphism and deformation at 1.81-1.79 Ga (zircon and monazite ages). The 1.83-1.79 Ga metamorphism has the same age as a metamorphic imprint and strong shearing of the crust in central Sweden (Andersson et al., 2004). The postcollisional granulite metamorphism of mafic intrusions at 1.80-1.79 Ga in Belarus

Distribution, facies, ages, and proposed tectonic associations of regionally metamorphosed rocks in east- and south-central Alaska

USGS Publications Warehouse

Dusel-Bacon, Cynthia; Csejtey, Bela; Foster, Helen L.; Doyle, Elizabeth O.; Nokleberg, Warren J.; Plafker, George

1993-01-01

Most of the exposed bedrock in east- and south-central Alaska has been regionally metamorphosed and deformed during Mesozoic and early Cenozoic time. All the regionally metamorphosed rocks are assigned to metamorphic-facies units on the basis of their temperature and pressure conditions and metamorphic age. North of the McKinley and Denali faults, the crystalline rocks of the Yukon- Tanana upland and central Alaska Range compose a sequence of dynamothermally metamorphosed Paleozoic and older(?) metasedimentary rocks and metamorphosed products of a Devonian and Mississippian continental-margin magmatic arc. This sequence was extensively intruded by postmetamorphic mid-Cretaceous and younger granitoids. Many metamorphic-unit boundaries in the Yukon-Tanana upland are low-angle faults that juxtapose units of differing metamorphic grade, which indicates that metamorphism predated final emplacement of the fault-bounded units. In some places, the relation of metamorphic grade across a fault is best explained by contractional faulting; in other places, it is suggestive of extensional faulting.Near the United States-Canadian border in the central Yukon- Tanana upland, metamorphism, plutonism, and thrusting occurred during a latest Triassic and Early Jurassic event that presumably resulted from the accretion of a terrane that had affinities to the Stikinia terrane onto the continental margin of North America. Elsewhere in the Yukon-Tanana upland, metamorphic rocks give predominantly late Early Cretaceous isotopic ages. These ages are interpreted to date either the timing of a subsequent Early Cretaceous episode of crustal thickening and metamorphism or, assuming that these other areas were also originally heated during the latest Triassic to Early Jurassic and remained buried, the timing of their uplift and cooling. This uplift and cooling may have resulted from extension.South of the McKinley and Denali faults and north of the Border Ranges fault system, medium

Structural terranes and their relationships in Sierra Leone

NASA Astrophysics Data System (ADS)

Williams, Howard R.; Culver, Stephen J.

Sierra Leone, composed mainly of Archaean granite-greenstone terrane, is bounded in the west by a westward dipping zone of intense, ductile, simple shear deformation which produced very fine-grained, high grade rocks. This zone has been interpreted as a possible Archaean suture developed following the collision of the Guyana Shield and the West African Craton. Granulite facies metamorphic supracrustals of the Kasila Group occur to the west of the sheared zone. Marampa Group lower grade metamorphics were thrust eastwards during the collision event. Late Precambrian rifting, well to the east of the mylonite zone and subsequent compression, preserved very low grade to unmetamorphosed Rokel River Group sediments and volcanics. Limited Pan-African tectonic transport of Archaean and late Precambrian material was again toward the east. All structural and stratigraphic units can be traced northward into Guinea where they disappear beneath the Paleozoic sediments of the Bové Basin. To the south, the Kasila Group, the granite-greenstone terrane and the mylonitized zone can be traced into Liberia. The Gibi Mountain Formation of Liberia is probably laterally equivalent to the lower portions of the Rokel River Group. This interpretation of the geology of Sierra Leone differs greatly from that of Guinea where the mylonitized zone, associated with a positive gravity anomaly, has been interpreted as a suture zone resulting from Pan-African continent-continent collision.

The collision process deciphered form the systematic metamorphic pattern along the Qinling-Dabie-Hongseong collision belt between the North and South China(Korea-China) blocks

NASA Astrophysics Data System (ADS)

Oh, C. W.

2016-12-01

As a last step of formation of the Pangea supercontinent, the North China craton collided with the South China craton during Permo-Triassic time forming the Qinling-Dabie-Sulu collision belt. After the Qinling-Dabie-Sulu collision belt was found, the Imjingang belt in Korean Peninsula was suggested as an extension of the belt but evidences of collision belt such as eclogite and ophiolite, were not found from the belt. Whereas Triassic eclogite (ca. >230 Ma) was found in the Hongseong area and Triassic post collision igneous rocks (with ca. 230 Ma intrusion ages) occurred throughout the Gyeonggi massif locating to the north of the line connecting the Hongseong, Yangpyeong and Odesan areas. These new findings suggest the Permo-Triassic Qinling-Dabie-Sulu collision belt between the North and South China cratons extends into the Hongseong-Yangpyeong-Odesan collision belt in Korean Peninsula. Therefore I would like to suggest the North and South Korea-China cratons instead of the North and South China cratons. The collision had started from Korea at ca. 250 Ma and propagated towards China until late Triassic. The metamorphic conditions change systematically along the collision belt; ultrahigh-temperature metamorphism in the Odesan area (at 245 Ma; 9.0-10.6 kbar, 915-1160°C), high-P/T metamorphism in the Hongseong area (at > 230 Ma; 17.0-21.9 kbar, 835-860°C), ultrahigh-pressure metamorphism in the Dabie and Sulu belts (at 230-220 Ma; 30-40 kbar, 680-880°C), ultrahigh-pressure metamorphism in the Hongan belt (at 225-212 Ma; 31 kbar, 590-650°C) and blueschist facies metamorphism in the Qinling belt. The systematic increasing peak pressure condition and decreasing peak temperature condition from the Odesan to Dabie-Sulu belt, may be due to the increase in the depth of slab break-off towards west, which might be related to the increase of the amounts of subducted oceanic slab towards west. However, after the slab break-off in the Dabie-Sulu area, the depth of slab break

Terapascal static pressure generation with ultrahigh yield strength nanodiamond.

PubMed

Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

2016-07-01

Studies of materials' properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications.

Terapascal static pressure generation with ultrahigh yield strength nanodiamond

PubMed Central

Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B.; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

2016-01-01

Studies of materials’ properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications. PMID:27453944

Pressure Variations in Metamorphic Rocks: Implications for the Interpretation of Petrographic Observations

NASA Astrophysics Data System (ADS)

Tajčmanová, Lucie

2014-05-01

Metamorphic petrologists and structural geologists, using direct measurements, bring the only direct observational constrains for validating geodynamic models. Therefore, petrological and structural geological observations are essential for the quality and reproducibility of geodynamic reconstructions and models. One of the important assumptions for geodynamic reconstructions arises from the pressure and temperature estimates in the petrology analysis. Pressure is commonly converted to depth through the equation for lithostatic pressure and so the original position of the rock sample within the Earth's interior can be constrained. The current assumption that the studied sample corresponds to uniform pressure may not be correct, and if so, it has serious implications. Increasing evidence from analytical data shows that pressure is not constant even on a grain scale, posing new challenges because, if ignored, it leads to an incorrect use of petrology data in constraining geodynamic models. Well known examples of the preservation of coesite and diamond in a host mineral like garnet show that high pressure inclusions are preserved during decompression. Tajčmanová et al. (2014) has shown that grain-scale pressure variations can develop and that these pressure variations allow compositional zoning in minerals preserved over geological time scales. A new unconventional barometric method based on equilibrium under pressure variations has been developed . Such pressure variations are also connected with differences in fluid pressure in open systems and can be thus observed at all scales. Tajčmanová L., Podladchikov Y., Powell R., Moulas E., Vrijmoed J. and Connolly J. (2014). Grain scale pressure variations and chemical equilibrium in high-grade metamorphic rocks.Journal of Metamorphic Geology, doi:10.1111/jmg.12066 This work was supported by ERC starting grant 335577 to Lucie Tajcmanova

Blueschist preservation in a retrograded, high-pressure, low-temperature metamorphic terrane, Tinos, Greece: Implications for fluid flow paths in subduction zones

NASA Astrophysics Data System (ADS)

Breeding, Christopher M.; Ague, Jay J.; BröCker, Michael; Bolton, Edward W.

2003-01-01

The preservation of high-pressure, low-temperature (HP-LT) mineral assemblages adjacent to marble unit contacts on the Cycladic island of Tinos in Greece was investigated using a new type of digital outcrop mapping and numerical modeling of metamorphic fluid infiltration. Mineral assemblage distributions in a large blueschist outcrop, adjacent to the basal contact of a 150-meter thick marble horizon, were mapped at centimeter-scale resolution onto digital photographs using a belt-worn computer and graphics editing software. Digital mapping reveals that while most HP-LT rocks in the outcrop were pervasively retrograded to greenschist facies, the marble-blueschist contact zone underwent an even more intense retrogression. Preservation of HP-LT mineral assemblages was mainly restricted to a 10-15 meter zone (or enclave) adjacent to the intensely retrograded lithologic contact. The degree and distribution of the retrograde overprint suggests that pervasively infiltrating fluids were channelized into the marble-blueschist contact and associated veins and flowed around the preserved HP-LT enclave. Numerical modeling of Darcian flow, based on the field observations, suggests that near the marble horizon, deflections in fluid flow paths caused by flow channelization along the high-permeability marble-blueschist contact zone likely resulted in very large fluid fluxes along the lithologic contact and significantly smaller fluxes (as much as 8 times smaller than the input flux) within the narrow, low-flux regions where HP-LT minerals were preserved adjacent to the contact. Our results indicate that lithologic contacts are important conduits for metamorphic fluid flow in subduction zones. Channelization of retrograde fluids into these discrete flow conduits played a critical role in the preservation of HP-LT assemblages.

Quantifying the timescales of Archean UHT metamorphism through U-Pb monazite and zircon petrochronology

NASA Astrophysics Data System (ADS)

Guevara, V.; MacLennan, S. A.; Schoene, B.; Dragovic, B.; Caddick, M. J.; Kylander-Clark, A. R.; Couëslan, C. G.

2016-12-01

Unraveling the timescales of metamorphism is crucial to understanding the mechanisms behind mass/heat transfer through Earth's crust. Though such mechanisms and their durations are becoming well constrained in modern (Phanerozoic) settings, the drivers of metamorphism in the ancient geologic record remain more enigmatic. The development of accessory phase petrochronology has allowed metamorphic evolution to be closely linked to isotopic dates, ultimately improving quantification of metamorphic durations. While in-situ petrochronological methods preserve textural and spatial context, they often lack the temporal resolution required to accurately quantify metamorphic duration in Archean terranes. Here we combine in-situ U-Pb monazite (mnz) and zircon (zrn) laser ablation split-stream (LASS) and high-precision ID-TIMS-TEA petrochronology of distinct grain domains to resolve the timescales of ultrahigh temperature (UHT) metamorphism in the Archean Pikwitonei granulite domain (PGD). The PGD encompasses >1.5x105 km2 of granulite-facies rocks on the NW edge of the Superior Province. Themodynamic modelling of a pelite from the western part of the PGD suggests peak P-T conditions of >8 kbar, 900-940 °C and UHT decompression to 8 kbar followed by cooling. LASS analysis of zrn inclusions in garnet (grt) yields a date of 2701 Ma, with Ti in zrn thermometry yielding T of 800-900 °C. LASS analysis of mnz yields dates of 2720-2680 Ma for low HREE domains with no to shallow negative Eu anomalies, suggestive of growth during plagioclase (plg) breakdown and grt stability. ID-TIMS analysis of a mnz fragment with a strong negative Eu anomaly, suggestive of growth during plg stability, gives a concordant 207Pb/206Pb date of 2666 Ma, consistent with LASS results of 2660-2640 Ma for chemically similar domains. ID-TIMS analyses of zrn rims yield a range of 207Pb/206Pb dates from 2671 to 2656 Ma (±<1 Ma). Ti in zrn yields 800 °C for these rims, indicating they grew at similar T

The evolution of a Gondwanan collisional orogen: A structural and geochronological appraisal from the Southern Granulite Terrane, South India

NASA Astrophysics Data System (ADS)

Plavsa, Diana; Collins, Alan S.; Foden, John D.; Clark, Chris

2015-05-01

Gondwana amalgamated along a suite of Himalayan-scale collisional orogens, the roots of which lace the continents of Africa, South America, and Antarctica. The Southern Granulite Terrane of India is a generally well-exposed, exhumed, Gondwana-forming orogen that preserves a record of the tectonic evolution of the eastern margin of the East African Orogen during the Ediacaran-Cambrian (circa 600-500 Ma) as central Gondwana formed. The deformation associated with the closure of the Mozambique Ocean and collision of the Indian and East African/Madagascan cratonic domains is believed to have taken place along the southern margin of the Salem Block (the Palghat-Cauvery Shear System, PCSS) in the Southern Granulite Terrane. Investigation of the structural fabrics and the geochronology of the high-grade shear zones within the PCSS system shows that the Moyar-Salem-Attur shear zone to the north of the PCSS system is early Paleoproterozoic in age and associated with dextral strike-slip motion, while the Cauvery shear zone (CSZ) to the south of the PCSS system can be loosely constrained to circa 740-550 Ma and is associated with dip-slip dextral transpression and north side-up motion. To the south of the proposed suture zone (the Cauvery shear zone), the structural fabrics of the Northern Madurai Block suggest four deformational events (D1-D4), some of which are likely to be contemporaneous. The timing of high pressure-ultrahigh temperature metamorphism and deformation (D1-D3) in the Madurai Block (here interpreted as the southern extension of Azania) is constrained to circa 550-500 Ma and interpreted as representing collisional orogeny and subsequent orogenic collapse of the eastern margin of the East African Orogen. The disparity in the nature of the structural fabrics and the timing of the deformation in the Salem and the Madurai Blocks suggest that the two experienced distinct tectonothermal events prior to their amalgamation along the Cauvery shear zone during the

Magnitude of long-term non-lithostatic pressure variations in lithospheric processes: insight from thermo-mechanical subduction/collision models

NASA Astrophysics Data System (ADS)

Gerya, Taras

2014-05-01

On the one hand, the principle of lithostatic pressure is habitually used in metamorphic geology to calculate paleo-depths of metamorphism from mineralogical pressure estimates given by geobarometry. On the other hand, it is obvious that this lithostatic (hydrostatic) pressure principle should only be valid for an ideal case of negligible deviatoric stresses during the long-term development of the entire tectono-metamorphic system - the situation, which newer comes to existence in natural lithospheric processes. The question is therefore not "Do non-lithostatic pressure variations exist?" but " What is the magnitude of long-term non-lithostatic pressure variations in various lithospheric processes, which can be recorded by mineral equilibria of respective metamorphic rocks?". The later question is, in particular, relevant for various types of high-pressure (HP) and ultrahigh-pressure (UHP) rocks, which are often produced in convergent plate boundary settings (e.g., Hacker and Gerya, 2013). This question, can, in particular, be answered with the use of thermo-mechanical models of subduction/collision processes employing realistic P-T-stress-dependent visco-elasto-brittle/plastic rheology of rocks. These models suggest that magnitudes of pressure deviations from lithostatic values can range >50% underpressure to >100% overpressure, mainly in the regions of bending of rheologically strong mantle lithosphere (Burg and Gerya, 2005; Li et al., 2010). In particular, strong undepresures along normal faults forming within outer rise regions of subducting plates can be responsible for downward water suction and deep hydration of oceanic slabs (Faccenda et al., 2009). Weaker HP and UHP rocks of subduction/collision channels are typically subjected to lesser non-lithostatic pressure variations with characteristic magnitudes ranging within 10-20% from the lithostatic values (Burg and Gerya, 2005; Li et al., 2010). The strength of subducted crustal rocks and the degree of

Nature and origin of fluids in granulite facies metamorphism

NASA Technical Reports Server (NTRS)

Newton, R. C.

1988-01-01

The various models for the nature and origin of fluids in granulite facies metamorphism were summarized. Field and petrologic evidence exists for both fluid-absent and fluid-present deep crustal metamorphism. The South Indian granulite province is often cited as a fluid-rich example. The fluids must have been low in H2O and thus high in CO2. Deep crustal and subcrustal sources of CO2 are as yet unproven possibilities. There is much recent discussion of the possible ways in which deep crustal melts and fluids could have interacted in granulite metamorphism. Possible explanations for the characteristically low activity of H2O associated with granulite terranes were discussed. Granulites of the Adirondacks, New York, show evidence for vapor-absent conditions, and thus appear different from those of South India, for which CO2 streaming was proposed. Several features, such as the presence of high-density CO2 fluid inclusions, that may be misleading as evidence for CO2-saturated conditions during metamorphism, were discussed.

U-Pb zircon geochronology and Zr-in-rutile thermometry of eclogites from the Dulan area, North Qaidam ultra-high pressure (UHP) terrane, western China

NASA Astrophysics Data System (ADS)

Hernández Uribe, D.; Stubbs, K.; Lehman, M. R.; Gilmore, V.; Kylander-Clark, A. R.; Mattinson, C. G.

2016-12-01

The Dulan area, in the North Qaidam terrane, exposes UHP eclogites and gneisses that experienced a 20 Myr UHP event at P-T conditions of 30 kbar and 700 °C. Two eclogites were analyzed using Zr-in-rutile thermometry and zircon U-Pb + trace element analysis to constrain the metamorphic evolution of the area. A kyanite-phengite eclogite presents a mineral assemblage of grt + omp + ph + ky + rt + zo + qz. Rutile analyses show a Zr concentration of 173-250 ppm with a mean of 207 ± 19 ppm. The calculated temperatures yielded 685-716 °C with an average of 700 ± 7°C. Zircon U-Pb analyses gave an upper intercept age of 880 ± 89 Ma. These analyses from cathodoluminiscence (CL)-dark core zircons show a negative Eu anomaly and a steep HREE slope suggesting a magmatic origin for the protolith. Analyses from CL-bright rims gave a weighted mean age of 427 ± 2 Ma. These zircons show an eclogite facies trace elements pattern suggesting that the age represent the HP-UHP event. Titanium concentration in zircons gave a weighted mean of 4.41 ± 0.25 ppm. This Ti concentration yielded a calculated temperature of 674 °C A phengite eclogite shows a mineral assemblage of grt + omp + ph + rt + zo + qz. Rutile in matrix analyses show a Zr concentration of 123-161 ppm with a mean of 139 ± 9 ppm. Calculated temperatures for these rutiles ranges from 659-680 °C with a mean temperature of 668 ± 5 °C. U-Pb analyses from CL-dark zircon cores gave a weighted mean age of 844 ± 7 Ma. These zircons show a negative Eu anomaly and a steep HREE slope suggesting a magmatic origin for the protolith. Analyses from CL-grey rims gave a weighted mean age of 433 ± 4 Ma. These zircons show an eclogite facies trace elements pattern, representing the timing of the HP-UHP event. Titanium concentration in zircons gave a weighted mean of 3.13 ± 0.34 ppm. This concentration yielded calculated temperature 647 °C. The obtained ages are in the same range as the ones obtained for the northern and southern

40Ar/39Ar Data for White Mica, Biotite, and K-Feldspar Samples from Low-Grade Metamorphic Rocks in the Westminster Terrane and Adjacent Rocks, Maryland

USGS Publications Warehouse

Kunk, Michael J.; McAleer, Ryan J.

2008-01-01

This report contains reduced 40Ar/39Ar data of white mica and K-feldspar mineral separates and matrix of a whole rock phyllite, all from low-grade metamorphic rocks of the Westminster terrane and adjacent strata in central Maryland. This report presents these data in a preliminary form, but in more detail than can be accommodated in todays professional journals. Also included in this report is information on the location of the samples and a brief description of the samples. The data contained herein are not interpreted in a geological context, and care should be taken by readers unfamiliar with argon isotopic data in the use of these results; many of the individual apparent ages are not geologically meaningful. This report is primarily a detailed source document for subsequent publications that will integrate these data into a geological context.

Geochronology, geochemistry, and petrogenesis of late Permian to early Triassic mafic rocks from Darongshan, South China: Implications for ultrahigh-temperature metamorphism and S-type granite generation

NASA Astrophysics Data System (ADS)

Xu, Wang-Chun; Luo, Bi-Ji; Xu, Ya-Jun; Wang, Lei; Chen, Qi

2018-05-01

The role of the mantle in generating ultrahigh-temperature metamorphism and peraluminous S-type granites, and the extent of crust-mantle interaction are topics fundamental to our understanding of the Earth's evolution. In this study we present geochronological, geochemical, and Sr-Nd-Hf isotopic data for dolerites and mafic volcanic rocks from the Darongshan granite complex belt in western Cathaysia, South China. LA-ICP-MS U-Pb zircon analyses yielded magma crystallization ages of ca. 250-248 Ma for the dolerites, which are coeval with eruption of the mafic volcanic rocks, ultrahigh-temperature metamorphism, and emplacement of S-type granites in the Darongshan granite complex belt. The mafic volcanic rocks are high-K calc-alkaline or shoshonitic, enriched in Th, U, and light rare earth elements, and depleted in Nb, Ta and Ti. The dolerites are characterized by high Fe2O3tot (11.61-20.39 wt%) and TiO2 (1.62-3.17 wt%), and low MgO (1.73-4.38 wt%), Cr (2.8-10.8 ppm) and Ni (2.5-11.4 ppm). Isotopically, the mafic volcanic rocks have negative whole-rock εNd(t) values (-6.7 to -9.0) and high ISr values (0.71232 to 0.71767), which are slightly depleted compared with the dolerite samples (εNd(t) = -10.3 to -10.4 and ISr = 0.71796 to 0.71923). Zircons in the dolerites have εHf(t) values of -7.6 to -10.9. The mafic volcanic rocks are interpreted to have resulted from the partial melting of an enriched lithospheric mantle source with minor crustal contamination during ascent, whereas the dolerites formed by late-stage crystallization of enriched lithospheric mantle-derived magmas after fractionation of olivine and pyroxene. The formation of these mantle-derived mafic rocks may be attributed to transtension along a NE-trending strike-slip fault zone that was related to oblique subduction of the Paleo-Pacific plate beneath South China. Such underplated mafic magmas would provide sufficient heat for the generation of ultrahigh-temperature metamorphism and S-type granites, and

Very high-pressure orogenic garnet peridotites

PubMed Central

Liou, J. G.; Zhang, R. Y.; Ernst, W. G.

2007-01-01

Mantle-derived garnet peridotites are a minor component in many very high-pressure metamorphic terranes that formed during continental subduction and collision. Some of these mantle rocks contain trace amounts of zircon and micrometer-sized inclusions. The constituent minerals exhibit pre- and postsubduction microstructures, including polymorphic transformation and mineral exsolution. Experimental, mineralogical, petrochemical, and geochronological characterizations using novel techniques with high spatial, temporal, and energy resolutions are resulting in unexpected discoveries of new phases, providing better constraints on deep mantle processes. PMID:17519341

Contrasting tectonothermal domains and faulting in the Potomac terrane, Virginia-Maryland - Discrimination by 40Ar/39Ar and fission-track thermochronology

USGS Publications Warehouse

Kunk, Michael J.; Wintsch, R.P.; Naeser, C.W.; Naeser, N.D.; Southworth, C.S.; Drake, Avery A.; Becker, J.L.

2005-01-01

New 40Ar/39Ar data reveal ages and thermal discontinuities that identify mapped and unmapped fault boundaries in the Potomac terrane in northern Virginia, thus confirming previous interpretations that it is a composite terrane. The rocks of the Potomac terrane were examined along the Potomac River, where it has been previously subdivided into three units: the Mather Gorge, Sykesville, and Laurel Formations. In the Mather Gorge Formation, at least two metamorphic thermal domains were identified, the Blockhouse Point and Bear Island domains, separated by a fault active in the late Devonian. Early Ordovician (ca. 475 Ma) cooling ages of amphibole in the Bear Island domain reflect cooling from Taconic metamorphism, whereas the Blockhouse Point domain was first metamorphosed in the Devonian. The 40Ar/39Ar data from muscovites in a third (eastern) domain within the Mather Gorge Formation, the Stubblefield Falls domain, record thrusting of the Sykesville Formation over the Mather Gorge Formation on the Plummers Island fault in the Devonian. The existence of two distinctly different thermal domains separated by a tectonic boundary within the Mather Gorge argues against its status as a formation. Hornblende cooling ages in the Sykesville Formation are Early Devonian (ca. 400 Ma), reflecting cooling from Taconic and Acadian metamorphism. The ages of retrograde and overprinting muscovite in phyllonites from domain-bounding faults are late Devonian (Acadian) and late Pennsylvanian (Alleghanian), marking the time of assembly of these domains and subsequent movement on the Plummers Island fault. Our data indicate that net vertical motion between the Bear Island domain of the Mather Gorge complex and the Sykesville Formation across the Plummers Island fault is east-side-up. Zircon fission-track cooling ages demonstrate thermal equillbrium across the Potomac terrane in the early Permian, and apatite fission-track cooling ages record tilting of the Potomac terrane in the Cretaceous

Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal

DTIC Science & Technology

2014-04-01

ER D C/ G SL T R- 14 -1 1 Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal G eo te ch ni ca l a nd S tr...Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal Aaron B. Pullen Applied Research Associates, Inc. 421 Oak Avenue...collaboration with Applied Research Associates, Inc. (ARA). Several types of commercial UHPW water blasting systems were tested on an ungrooved portland cement

Ultrahigh Pressure Dynamic Compression

NASA Astrophysics Data System (ADS)

Duffy, T. S.

2017-12-01

Laser-based dynamic compression provides a new opportunity to study the lattice structure and other properties of geological materials to ultrahigh pressure conditions ranging from 100 - 1000 GPa (1 TPa) and beyond. Such studies have fundamental applications to understanding the Earth's core as well as the interior structure of super-Earths and giant planets. This talk will review recent dynamic compression experiments using high-powered lasers on materials including Fe-Si, MgO, and SiC. Experiments were conducted at the Omega laser (University of Rochester) and the Linac Coherent Light Source (LCLS, Stanford). At Omega, laser drives as large as 2 kJ are applied over 10 ns to samples that are 50 microns thick. At peak compression, the sample is probed with quasi-monochromatic X-rays from a laser-plasma source and diffraction is recorded on image plates. At LCLS, shock waves are driven into the sample using a 40-J laser with a 10-ns pulse. The sample is probed with X-rays form the LCLS free electron laser providing 1012 photons in a monochromatic pulse near 10 keV energy. Diffraction is recorded using pixel array detectors. By varying the delay between the laser and the x-ray beam, the sample can be probed at various times relative to the shock wave transiting the sample. By controlling the shape and duration of the incident laser pulse, either shock or ramp (shockless) loading can be produced. Ramp compression produces less heating than shock compression, allowing samples to be probed to ultrahigh pressures without melting. Results for iron alloys, oxides, and carbides provide new constraints on equations of state and phase transitions that are relevant to the interior structure of large, extrasolar terrestrial-type planets.

From P-T-age to secular change and global tectonic regimes (or Essene in reverse - from granulites to blueschists and eclogites over time)

NASA Astrophysics Data System (ADS)

Brown, M.

2006-12-01

Essene's contributions began pre-plate tectonics more than 40 years ago; they range from mineralogy to tectonics, from experiments and thermobarometry to elements and isotopes, and from the Phanerozoic to the Precambrian. Eric is a true polymath! Assessing the P-T conditions and age distribution of crustal metamorphism is an important step in evaluating secular change in tectonic regimes and geodynamics. In general, Archean rocks exhibit moderate-P - moderate-to-high-T facies series metamorphism (greenstone belts and granulite terranes); neither blueschists nor any record of deep continental subduction and return are documented and only one example of granulite facies ultrahigh-temperature metamorphism is reported. Granulite facies ultrahigh temperature metamorphism (G-UHTM) is documented in the rock record predominantly from Neoarchean to Cambrian, although G-UHTM facies series rocks may be inferred at depth in younger orogenic systems. The first occurrence of G-UHTM in the rock record signifies a change in geodynamics that generated transient sites of very high heat flow. Many G-UHTM belts may have developed in settings analogous to modern continental backarcs. On a warmer Earth, the formation and breakup of supercontinents, particularly by extroversion, which involved destruction of ocean basins floored by thinner lithosphere, may have generated hotter continental backarcs than those around the modern Pacific rim. Medium-temperature eclogite - high-pressure granulite metamorphism (E-HPGM) also is first recognized in the Neoarchean rock record, and occurs at intervals throughout the Proterozoic and Paleozoic rock record. E- HPGM belts are complementary to G-UHTM belts, and are generally inferred to record subduction-to-collision orogenesis. Blueschists become evident in the Neoproterozoic rock record; lawsonite blueschists and eclogites (high-pressure metamorphism, HPM), and ultrahigh pressure metamorphism (UHPM) characterized by coesite or diamond are

Sapphirine-bearing granulites from the Tongbai orogen, China: Petrology, phase equilibria, zircon U-Pb geochronology and implications for Paleozoic ultrahigh temperature metamorphism

NASA Astrophysics Data System (ADS)

Xiang, Hua; Zhong, Zeng-Qiu; Li, Ye; Qi, Min; Zhou, Han-Wen; Zhang, Li; Zhang, Ze-Ming; Santosh, M.

2014-11-01

We report here for the first time the occurrence of sapphirine-bearing granulites within the Qinling Group of the Qinling-Tongbai orogen and provide robust evidence for extreme crustal metamorphism at ultrahigh-temperature (UHT) conditions. We document the UHT indicator of sapphirine and spinel in a mafic granulite consisting of orthopyroxene, biotite, plagioclase, amphibole and rutile/ilmenite. The ferromagnesian minerals in the sapphirine-bearing granulite have high XMg [Mg/(Mg + Fe)] (orthopyroxene XMg = 0.84-0.95; biotite XMg = 0.81; amphibole XMg = 0.87-0.96). The phase equilibria modeling demonstrates that the early spinel-bearing assemblage is stable at 923-950 °C and 6.7-8.9 kbar, and the peak assemblage of Opx + Pl + Spr/Spl + Amp + Bt + Ilm (+ melt) defines a field at 922-947 °C and 8.4-10.2 kbar. Rutiles have variable Zr concentrations but mostly cluster at ca. 1,500 and 3400 ppm. Zr-in-rutile geothermometry yielded high temperatures of up to 890-940 °C. Zircon U-Pb dating of the granulite constrains the timing of the immediate post-peak and retrograde metamorphic stages as 429 ± 7 Ma and 412 ± 4 Ma, respectively. The UHT metamorphism, together with extensive occurrence of coeval magmatic suites suggests that the Tongbai orogen experienced a Paleozoic Andean-type orogeny probably derived from mid-oceanic ridge subduction of the Qinling Ocean.

The nature of Archean terrane boundaries: an example from the northern Wyoming Province

USGS Publications Warehouse

Mogk, D.W.; Mueller, P.A.; Wooden, J.L.

1992-01-01

The Archean northern Wyoming Province can be subdivided into two geologically distinct terranes, the Beartooth-Bighorn magmatic terrane (BBMT) and the Montana metasedimentary terrane (MMT). The BBMT is characterized by voluminous Late Archean (2.90-2.74 Ga) magmatic rocks (primarily tonalite, trondhjemite, and granite); metasedimentary rocks are preserved only as small, rare enclaves in this magmatic terrane. The magmatic rocks typically have geochemical and isotopic signatures that suggest petrogenesis in a continental magmatic arc environment. The MMT, as exposed in the northern Gallatin and Madison Ranges, is dominated by Middle Archean trondhjemitic gneisses (3.2-3.0 Ga); metasedimentary rocks, however, are significantly more abundant than in the BBMT. Each terrane has experienced a separate and distinct geologic history since at least 3.6 Ga ago based on differences in metamorphic and structural styles, composition of magmatic and metasupracrustal rocks, and isotopic ages; consequently, these may be described as discrete terranes in the Cordilleran sense. Nonetheless, highly radiogenic and distinctive Pb-Pb isotopic signatures in rocks of all ages in both terranes indicate that the two terranes share a significant aspect of their history. This suggests that these two Early to Middle Archean crustal blocks, that initially evolved as part of a larger crustal province, experienced different geologic histories from at least 3.6 Ga until their juxtaposition in the Late Archean (between 2.75 to 2.55 Ga ago). Consequently, the boundary between the BBMT and MMT appears to separate terranes that are not likely to be exotic in the sense of their Phanerozoic counterparts. Other Archean provinces do appear to contain crustal blocks with different isotopic signatures (e.g. West Greenland, India, South Africa). The use of the term exotic, therefore, must be cautious in situations where geographic indicators such as paleontologic and/or paleomagnetic data are not available

Neoproterozoic complexes of the shelf cover of the Dzabkhan terrane basement in the Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Kozakov, I. K.; Kuznetsov, A. B.; Erdenegargal, Ch.; Salnikova, E. B.; Anisimova, I. V.; Plotkina, Ju. V.; Fedoseenko, A. M.

2017-09-01

The formation stages of high-grade metamorphic complexes and the related granitoids of the Dzabkhan terrane basement are considered. The age data (U-Pb method, TIMS) of zircons from the trondhjemite block of the eastern part of the Dzabkhan terrane, which is directly overlain by the dolomite sequence of the Tsagaan Oloom Formation, are given. Trondhjemites yield the U-Pb zircon age of 862 ± 3 Ma. In their structural position, they are assigned to typical postmetamorphic formations that determine the formation and cratonization of rocks of the host block. The geochronological study of trondhjemites gives grounds to distinguish fragments of the continental crust in the Dzabkhan terrane basement, the formation of which occurred at different periods of time: ˜860 and ˜790 Ma. Geological-geochronological and Sm‒Nd isotope-geochemical studies indicate that the Dzabkhan terrane basement is not a single block of the Early Precambrian continental crust, but a composite terrane, comprising Neoproterozoic ensialic and island-arc structural and compositional complexes. Correlation of Sr isotopic characteristics with the 87Sr/86Sr variation curve in the Neoproterozoic and Cambrian seawater shows that carbonate deposits accumulated at the eastern margin of the Dzabkhan terrane near the end of the Neoproterozoic, 700-550 Ma, and in the central part of the terrane in the Early Cambrian, 540-530 Ma.

Fore arc tectonothermal evolution of the El Oro metamorphic province (Ecuador) during the Mesozoic

NASA Astrophysics Data System (ADS)

Riel, Nicolas; Martelat, Jean-Emmanuel; Guillot, Stéphane; Jaillard, Etienne; Monié, Patrick; Yuquilema, Jonatan; Duclaux, Guillaume; Mercier, Jonathan

2014-10-01

The El Oro metamorphic province of SW Ecuador is a composite massif made of juxtaposed terranes of both continental and oceanic affinity that has been located in a fore-arc position since Late Paleozoic times. Various geochemical, geochronological, and metamorphic studies have been undertaken on the El Oro metamorphic province, providing an understanding of the origin and age of the distinct units. However, the internal structures and geodynamic evolution of this area remain poorly understood. Our structural analysis and thermal modeling in the El Oro metamorphic province show that this fore-arc zone underwent four main geological events. (1) During Triassic times (230-225 Ma), the emplacement of the Piedras gabbroic unit at crustal-root level ( 9 kbar) triggered partial melting of the metasedimentary sequence under an E-W extensional regime at pressure-temperature conditions ranging from 4.5 to 8.5 kbar and from 650 to 900°C for the migmatitic unit. (2) At 226 Ma, the tectonic underplating of the Arenillas-Panupalí oceanic unit (9 kbar and 300°C) thermally sealed the fore-arc region. (3) Around the Jurassic-Cretaceous boundary, the shift from trench-normal to trench-parallel subduction triggered the exhumation and underplating of the high-pressure, oceanic Raspas Ophiolitic Complex (18 kbar and 600°C) beneath the El Oro Group (130-120 Ma). This was followed by the opening of a NE-SW pull-apart basin, which tilted the massif along an E-W subhorizontal axis (110 Ma). (4) In Late Cretaceous times, an N-S compressional event generated heterogeneous deformation due to the presence of the Cretaceous Celica volcanic arc, which acted as a buttress and predominantly affected the central and eastern part of the massif.

A Manganin Thin Film Ultra-High Pressure Sensor for Microscale Detonation Pressure Measurement

PubMed Central

Zhang, Guodong; Zhao, Yulong; Zhao, Yun; Wang, Xinchen; Ren, Wei; Li, Hui; Zhao, You

2018-01-01

With the development of energetic materials (EMs) and microelectromechanical systems (MEMS) initiating explosive devices, the measurement of detonation pressure generated by EMs in the microscale has become a pressing need. This paper develops a manganin thin film ultra-high pressure sensor based on MEMS technology for measuring the output pressure from micro-detonator. A reliable coefficient is proposed for designing the sensor’s sensitive element better. The sensor employs sandwich structure: the substrate uses a 0.5 mm thick alumina ceramic, the manganin sensitive element with a size of 0.2 mm × 0.1 mm × 2 μm and copper electrodes of 2 μm thick are sputtered sequentially on the substrate, and a 25 μm thick insulating layer of polyimide is wrapped on the sensitive element. The static test shows that the piezoresistive coefficient of manganin thin film is 0.0125 GPa−1. The dynamic experiment indicates that the detonation pressure of micro-detonator is 12.66 GPa, and the response time of the sensor is 37 ns. In a word, the sensor developed in this study is suitable for measuring ultra-high pressure in microscale and has a shorter response time than that of foil-like manganin gauges. Simultaneously, this study could be beneficial to research on ultra-high-pressure sensors with smaller size. PMID:29494519

Bedrock geology and tectonic evolution of the Wrangellia, Peninsular, and Chugach Terranes along the Trans-Alaska Crustal Transect in the Chugach Mountains and Southern Copper River Basin, Alaska

NASA Astrophysics Data System (ADS)

Plafker, George; Nokleberg, W. J.; Lull, J. S.

1989-04-01

The Trans-Alaskan Crustal Transect in the southern Copper River Basin and Chugach Mountains traverses the margins of the Peninsular and Wrangellia terranes, and the adjacent accretionary oceanic units of the Chugach terrane to the south. The southern Wrangellia terrane margin consists of a polymetamorphosed magmatic arc complex at least in part of Pennsylvanian age (Strelna Metamorphics and metagranodiorite) and tonalitic metaplutonic rocks of the Late Jurassic Chitina magmatic arc. The southern Peninsular terrane margin is underlain by rocks of the Late Triassic (?) and Early Jurassic Talkeetna magmatic arc (Talkeetna Formation and Border Ranges ultra-mafic-mafic assemblage) on Permian or older basement rocks. The Peninsular and Wrangellia terranes are parts of a dominantly oceanic superterrane (composite Terrane II) that was amalgamated by Late Triassic time and was accreted to terranes of continental affinity north of the Denali fault system in the mid- to Late Cretaceous. The Chugach terrane in the transect area consists of three successively accreted units: (1) minor greenschist and intercalated blueschist, the schist of Liberty Creek, of unknown protolith age that was metamorphosed and probably accreted during the Early Jurassic, (2) the McHugh Complex (Late Triassic to mid-Cretaceous protolith age), a melange of mixed oceanic, volcaniclastic, and olistostromal rocks that is metamorphosed to prehnite-pumpellyite and lower greenschist facies that was accreted by middle Cretaceous time, and (3) the Upper Cretaceous Valdez Group, mainly magmatic arc-derived flysch and lesser oceanic volcanic rocks of greenschist facies that was accreted by early Paleocene time. A regional thermal event that culminated in early middle Eocene time (48-52 Ma) resulted in widespread greenschist facies metamorphism and plutonism.

SHRIMP U-Pb dating, trace elements and the Lu-Hf isotope system of coesite-bearing zircon from amphibolite in the SW Sulu UHP terrane, eastern China

NASA Astrophysics Data System (ADS)

Liu, Fulai; Gerdes, Axel; Zeng, Lingsen; Xue, Huaimin

2008-06-01

In this study, we link mineral inclusion data, trace element analyses, U-Pb age and Hf isotope composition obtained from distinct zircon domains of complex zircon to unravel the origin and multi-stage metamorphic evolution of amphibolites from the Sulu ultrahigh-pressure (UHP) terrane, eastern China. Zircon grains separated from amphibolites from the CCSD-MH drill hole (G12) and Niushan outcrop (G13) were subdivided into two main types based on cathodoluminescence (CL) and Laser Raman spectroscopy: big dusty zircons with inherited cores and UHP metamorphic rims and small clear zircons. Weakly zoned, grey-white luminescent inherited cores preserve mineral inclusions of Cpx + Pl + Ap ± Qtz indicative of a mafic igneous protolith. Dark grey luminescent overgrowth rims contain the coesite eclogite-facies mineral inclusion assemblage Coe + Grt + Omp + Phe + Ap, and formed at T = 732-839 °C and P = 3.0-4.0 GPa. In contrast, white luminescent small clear zircons preserve mineral inclusions formed during retrograde HP quartz eclogite to LP amphibolite-facies metamorphism (T = 612-698 °C and P = 0.70-1.05 GPa). Inherited zircons from both samples yield SHRIMP 206Pb/238U ages of 695-520 Ma with an upper intercept age of 800 ± 31 Ma. The UHP rims yield consistent Triassic ages around 236-225 and 239-225 Ma for G12 and G13 with weighted means of 229 ± 3 and 231 ± 3 Ma, respectively. Small clear zircons from both samples give 206Pb/238U ages around 219-210 Ma with a weighted mean of 214 ± 3 Ma, interpreted as the age of retrograde quartz eclogite-facies metamorphism. Matrix amphibole from both samples indicate Ar-Ar ages of 209 ± 0.7 and 207 ± 0.7 Ma, respectively, probably dating late amphibolite-facies retrogression. The data suggest subduction of Neoproterozoic mafic igneous rocks to UHP conditions in Middle Triassic (∼230 Ma) times and subsequent exhumation to an early HP (∼214 Ma) and a late LP stage (∼208 Ma) over a period of ∼16 and 6 Myr, respectively

Age, temperature and pressure of metamorphism in the Tasriwine Ophiolite Complex, Sirwa, Morocco

NASA Astrophysics Data System (ADS)

Samson, S. D.; Inglis, J.; Hefferan, K. P.; Admou, H.; Saquaque, A.

2013-12-01

Sm-Nd garnet-whole rock geochronology and phase equilbria modeling have been used to determine the age and conditions of regional metamorphism within the Tasriwine ophiolite complex,Sirwa, Morocco. Pressure and temperature estimates obtained using a NaCaKFMASHT phase diagram (pseudosection) and garnet core and rim compositions predict that garnet growth began at ~0.72GPa and ~615°C and ended at ~0.8GPa and ~640°C. A bulk garnet Sm-Nd age of 645.6 × 1.6 Ma, calculated from a four point isochron that combines whole rock, garnet full dissolution and two successively more aggressive partial dissolutions, provides a precise date for garnet formation and regional metamorphism. The age is nearly 20 million years younger than a previous age estimate of regional metamorphism of 663 × 14 Ma based upon a SHRIMP U-Pb date from rims on zircon from the Irri migmatite. The new data provide further constraints on the age and nature of regional metamorphism in the Anti-Atlas mountains and emphasizes that garnet growth during regional metamorphism may not necessarily coincide with magmatism/anatexis which predominate the signature witnessed by previous U-Pb studies. The ability to couple PT estimates for garnet formation with high precision Sm- Nd geochronology highlights the utility of garnet studies for uncovering the detailed metamorphic history of the Anti-Atlas mountain belt.

About the age of the Neoproterozoic Lainici-Paius terrane (South Carpathians, Romania)

NASA Astrophysics Data System (ADS)

Balica, C.; Balintoni, I.; Ducea, M. N.; Berza, T.; Stremtan, C.

2009-12-01

The pre-Alpine basement of the Danubian domain nappes from South Carpathians consists of high grade metamorphic groups and late Neoproterozoic plutons, underlying low grade metamorphosed Ordovician to early Carboniferous formations (e.g. Seghedi et al., 2005). Two types of pre-Ordovician metamorphic complexes with contrasting protoliths petrology, metamorphism and associated igneous activity, involved in a pre-Permian nappe structure are separated: Lainici-Paius group, dominated by HT-LP metasediments and Dragsan group, dominated by medium grade metabasites. Based on their distinct lithologic compositions, geologic histories and clear boundaries, we consider these two groups as parts of two different terranes (i.e. Lainici-Paius and Dragsan terranes). The southern part of Lainici-Paius terrane is intruded by elongated plutons up to 100 km long and 15 km wide. Based on the geochemical composition, the plutons are assigned to two distinct suites, (i) medium K, calc-alkaline, mostly granodioritic-tonalitic suite (i.e. Susita type) and (ii) very high K, calc-alkaline and mostly granitic (i.e. Tismana type). The first suite comprises Susita and Oltet granitoid bodies and the second suite consists of Tismana and Novaci granitic plutons. Previous age dating was carried out only on Tismana (567±3 Ma upper intercept, Liégeois et al., 1996) and Novaci (588±5 Ma, Grünenfelder et al., 1983 recalculated by Liégeois et al., 1996) granites. In situ zircon U/Pb LA-ICP-MS analyses performed on all four granitoid plutons yielded 596.3±5.7 Ma for Tismana granite, 592.0±5.1 Ma for Novaci granite, 591.0±3.5 Ma for Susita granite and 588.7±3 Ma for Oltet granite. The same method has been additionally applied for detrital zircons from a metasandstone sequence comprised by the Lainici-Paius complex. Fifty-five ages out of 78 dated grains are ranging between 690.1±5.5 Ma and 811.4±12,7 Ma. Therefore, considering the protolith ages of the four dated granites and the youngest age

Detrital rutile geochemistry and thermometry from the Dabie orogen: Implications for source-sediment links in a UHPM terrane

NASA Astrophysics Data System (ADS)

Liu, Lei; Xiao, Yilin; Wörner, G.; Kronz, A.; Simon, K.; Hou, Zhenhui

2014-08-01

This study explores the potential of detrital rutile geochemistry and thermometry as a provenance tracer in rocks from the Central Dabie ultrahigh-pressure metamorphic (UHPM) zone in east-central China that formed during Triassic continental collision. Trace element data of 176 detrital rutile grains selected from local river sediments and 91 rutile grains from distinct bedrocks in the Shuanghe and Bixiling areas, obtained by both electron microprobe (EMP) and in situ LA-ICP-MS analyses, suggest that geochemical compositions and thermometry of detrital rutiles are comparable to those from their potential source rocks. After certification of the Cr-Nb discrimination method for the Central Dabie UHPM zone, we show that 29% of the detrital rutiles in the Shuanghe area were derived from metamafic sources whereas in the Bixiling area that it is up to 76%. Furthermore, the proportion of distinct types of detrital rutiles combined with modal abundances of rutile in metapelites and metamafic bedrocks can be used to estimate the proportion of different source lithologies. Based on this method the proportion of mafic source rocks was estimated to ∼10% at Shuanghe and >60% at Bixiling, respectively, which is consistent with the proportions of eclogite (the major rutile-bearing metamafic rock) distribution in the field. Therefore, the investigation of detrital rutiles is a potential way to evaluate the proportion of metamafic rocks and even to prospect for metamafic bodies in UHPM terranes. Zr-in-rutile temperatures were calculated at different pressures and compared with temperatures derived from rock-in rutiles and garnet-clinopyroxene Fe-Mg thermometers. Temperatures calculated for detrital rutiles range from 606 °C to 707 °C and 566 °C to 752 °C in Shuanghe and Bixiling, respectively, at P = 3 GPa with an average temperatures of ca. 630 °C for both areas. These temperature averages and ranges are similar to those calculated for rutiles from surrounding source rocks

Principles of Metamorphic Petrology

NASA Astrophysics Data System (ADS)

Williams, Michael L.

2009-05-01

The field of metamorphic petrology has seen spectacular advances in the past decade, including new X-ray mapping techniques for characterizing metamorphic rocks and minerals, new internally consistent thermobarometers, new software for constructing and viewing phase diagrams, new methods to date metamorphic processes, and perhaps most significant, revised petrologic databases and the ability to calculate accurate phase diagrams and pseudosections. These tools and techniques provide new power and resolution for constraining pressure-temperature (P-T) histories and tectonic events. Two books have been fundamental for empowering petrologists and structural geologists during the past decade. Frank Spear's Metamorphic Phase Equilibria and Pressure-Temperature-Time Paths, published in 1993, builds on his seminal papers to provide a quantitative framework for P-T path analysis. Spear's book lays the foundation for modern quantitative metamorphic analysis. Cees Passchier and Rudolph Trouw's Microtectonics, published in 2005, with its superb photos and figures, provides the tools and the theory for interpreting deformation textures and inferring deformation processes.

Tectonic exhumation and boundary structure of the Kokchetav HP - UHP metamorphic belt (Northern Kazakhstan): constraints from 40Ar/39Ar geochronology

NASA Astrophysics Data System (ADS)

Zhimulev, Fedor; de Grave, Johan; Travin, Aleksey; Buslov, Mikhail

2010-05-01

The Kokchetav metamorphic belt (KMB) is part of the Early Paleozoic orogenic belt of Northern Kazakhstan and constitutes one of the most famous, classical ultra-high pressure (UHP) metamorphic terranes. The KMB mainly consists of gneisses, mica schists and eclogites. These were formed by Cambrian continental subduction and associated metamorphism of the Precambrian Kokchetav microcontinent and subsequent exhumation of fragments of this metamorphosed continental crust. Several subterranes can be distinguished in the KMB: Barchi, Kumdi-Kol, Sulu-Tube, Enbek-Berlyk, Kulet and Borovoe. These subterranes differ not only in rock composition or in genetic pT conditions, but also in the age of the individual metamorphic events, including the timing of peak, and regressive stages. Most geochronological data indicate a Cambrian age of UHP and HP metamorphism and subsequent exhumation of the KMB. However, there is no field evidence of Cambrian geodynamic processes in the region: Cambrian sediments, volcanic rocks, or large magmatic bodies are completely absent in the KMB setting. The youngest geochronological information in the KMB was obtained on the garnet-mica schists from the Enbek-Berlyk subterrane. The 40Ar/39Ar ages of the muscovite from these schists lies in the range of 490 to 475 Ma (mainly 480-485 Ma). All 40Ar/39Ar stepwise heating experiments yield well-defined plateau and isochron ages. This age is considered to represent the time of emplacement of various heterogeneous nappes, including nappes that consist of HP - UHP metamorphic rocks, to upper crustal levels. To the north, the Kokchetav HP - UHP metamorphic belt is bounded by the Northern Kokchetav tectonic zone (NKTZ). This zone includes thin nappes of (1) Palaeo-Mesoproterozoic gneiss of the metamorphic basement of the Kokchetav microcontinent and Neoproterozoic meta-sandstones and dolomites of its deformed sedimentary cover, (2) pre-Ordovician volcanic rocks of island-arc affinity, (3) Early Ordovician

Metamorphic belts of Anatolia

NASA Astrophysics Data System (ADS)

Oberhänsli, Roland; Prouteau, Amaury; Candan, Osman; Bousquet, Romain

2015-04-01

Investigating metamorphic rocks from high-pressure/low-temperature (HP/LT) belts that formed during the closure of several oceanic branches, building up the present Anatolia continental micro-plate gives insight to the palaeogeography of the Neotethys Ocean in Anatolia. Two coherent HP/LT metamorphic belts, the Tavşanlı Zone (distal Gondwana margin) and the Ören-Afyon-Bolkardağ Zone (proximal Gondwana margin), parallel their non-metamorphosed equivalent (the Tauride Carbonate Platform) from the Aegean coast in NW Anatolia to southern Central Anatolia. P-T conditions and timing of metamorphism in the Ören-Afyon-Bolkardağ Zone (>70?-65 Ma; 0.8-1.2 GPa/330-420°C) contrast those published for the overlying Tavşanlı Zone (88-78 Ma; 2.4 GPa/500 °C). These belts trace the southern Neotethys suture connecting the Vardar suture in the Hellenides to the Inner Tauride suture along the southern border of the Kirşehir Complex in Central Anatolia. Eastwards, these belts are capped by the Oligo-Miocene Sivas Basin. Another HP/LT metamorphic belt, in the Alanya and Bitlis regions, outlines the southern flank of the Tauride Carbonate Platform. In the Alanya Nappes, south of the Taurides, eclogites and blueschists yielded metamorphic ages around 82-80 Ma (zircon U-Pb and phengite Ar-Ar data). The Alanya-Bitlis HP belt testifies an additional suture not comparable to the northerly Tavşanlı and Ören-Afyon belts, thus implying an additional oceanic branch of the Neotethys. The most likely eastern lateral continuation of this HP belt is the Bitlis Massif, in SE Turkey. There, eclogites (1.9-2.4 GPa/480-540°C) occur within calc-arenitic meta-sediments and in gneisses of the metamorphic (Barrovian-type) basement. Zircon U-Pb ages revealed 84.4-82.4 Ma for peak metamorphism. Carpholite-bearing HP/LT metasediments representing the stratigraphic cover of the Bitlis Massif underwent 0.8-1.2 GPa/340-400°C at 79-74 Ma (Ar-Ar on white mica). These conditions compares to the Tav

U-Pb detrital zircon geochronology from the basement of the Central Qilian Terrane: implications for tectonic evolution of northeastern Tibetan Plateau

NASA Astrophysics Data System (ADS)

Liu, Changfeng; Wu, Chen; Zhou, Zhiguang; Yan, Zhu; Jiang, Tian; Song, Zhijie; Liu, Wencan; Yang, Xin; Zhang, Hongyuan

2018-03-01

The Tuolai Group dominates the Central Qilian Terrane, and there are different opinions on the age and tectonic attribute of the Tuolai Group. Based on large-scale geologic mapping and zircon dating, the Tuolai Group is divided into four parts: metamorphic supracrustal rocks, Neoproterozoic acid intrusive rocks, early-middle Ordovician acid intrusive rocks and middle Ordovician basic intrusive rocks. The metamorphic supracrustal rocks are the redefined Tuolai complex-group and include gneiss and schist assemblage by faulting contact. Zircon U-Pb LA-MC-ICP-MS dating was conducted on these samples of gneiss and migmatite from the gneiss assemblage, quartzite, two-mica schist and slate from the schist assemblage. The five detrital samples possess similar age spectra; have detrital zircon U-Pb main peak ages of 1.7 Ga with youngest U-Pb ages of 1150 Ma. They are intruded by Neoproterozoic acid intrusive rocks. Therefore, the Tuolai Group belonging to late Mesoproterozoic and early Neoproterozoic. With this caveat in mind, we believe that U-Pb detrital zircon dating, together with the geologic constraints obtained from this study and early work in the neighboring regions. We suggest that the formation age of the entire crystalline basement rocks of metasedimentary sequence from the Central Qilian Terrane should be constrained between the Late Mesoproterozoic and the Late Neoproterozoic, but not the previous Paleoproterozoic. The basement of the Central Qilian Terrane contains the typical Grenville ages, which indicates the Centre Qilian Terrane have been experienced the Grenville orogeny event.

Ultrahigh-pressure polyamorphism in GeO2 glass with coordination number >6

NASA Astrophysics Data System (ADS)

Kono, Yoshio; Kenney-Benson, Curtis; Ikuta, Daijo; Shibazaki, Yuki; Wang, Yanbin; Shen, Guoyin

2016-03-01

Knowledge of pressure-induced structural changes in glasses is important in various scientific fields as well as in engineering and industry. However, polyamorphism in glasses under high pressure remains poorly understood because of experimental challenges. Here we report new experimental findings of ultrahigh-pressure polyamorphism in GeO2 glass, investigated using a newly developed double-stage large-volume cell. The Ge-O coordination number (CN) is found to remain constant at ∼6 between 22.6 and 37.9 GPa. At higher pressures, CN begins to increase rapidly and reaches 7.4 at 91.7 GPa. This transformation begins when the oxygen-packing fraction in GeO2 glass is close to the maximal dense-packing state (the Kepler conjecture = ∼0.74), which provides new insights into structural changes in network-forming glasses and liquids with CN higher than 6 at ultrahigh-pressure conditions.

The systematic change of metamorphism along the Dabie-Sulu-Hongseong-Odesan collision belt between the North and South China blocks

NASA Astrophysics Data System (ADS)

Oh, C. W.

2013-12-01

As a last step of formation of the Pangea supercontinent, the North China block collided with the South China block during Permo-Triassic time forming the Oinling-Dabie-Sulu collision belt which was identified by the finding of ultrahigh- and high-P/T eclogites along the belt. After the Qiling-Dabie-Sulu collision belt was found, the continuation of the collision belt into Korean Peninsula became a hot issue. Although the Imjingang belt in Korean Peninsula was suggested as an extension of the belt, no evidence of collision belt such as eclogite and ophiolite, was found. Whereas recent studies on Korean Peninsula reveal that Triassic eclogite (ca. > 230 Ma) formed in the Hongseong area and Triassic post collision igneous rocks (with ca. 230 Ma intrusion ages) occurred throughout the Gyeonggi Massif locating to the north of the line connecting the Hongseong, Yangpyeong and Odesan areas. These new findings derive the tectonic model in which the Permo-Triassic Qinling-Dabie-Sulu collision belt between the North and South China blocks extends into the Hongseong-Yangpyeong-Odesan collision belt in Korean Peninsula. The belt may be further extended into the late Paleozoic subduction complex in the Yanji belt in North Korea through the Paleozoic subduction complex in the inner part of SW Japan. The collision had started from Korea at ca. 250 Ma and propagated towards China. The collision completed during late Triassic. The metamorphic conditions systematically change along the collision belt; ultrahigh-temperature metamorphism occurred in the Odesan area (at 245-230Ma; 9.0-10.6 kbar, 915-1160°C), high-P/T metamorphism in the Hongseong area (17.0-21.9 kbar, 835-860°C) and ultrahigh-pressure metamorphism in the Dabie and Sulu belts (30-40 kbar, 680-880°C). This systematic increasing peak pressure condition and decreasing peak temperature condition towards west, may be due to the increase in the depth of slab break-off towards west, which might be related to the increase

Late Carboniferous high-pressure metamorphism of the Kassan Metamorphic Complex (Kyrgyz Tianshan) and assembly of the SW Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Mühlberg, M.; Hegner, E.; Klemd, R.; Pfänder, J. A.; Kaliwoda, M.; Biske, Y. S.

2016-11-01

High-pressure (HP) metamorphism of the Kassan Metamorphic Complex (KMC) in the western Kyrgyz Tianshan has been related to either late Ordovician or late Carboniferous-Permian subduction processes. We report Sm-Nd ages for retrogressed eclogite samples and 40Ar/39Ar cooling ages for enclosing garnet-muscovite samples from the KMC as new age constraints on HP metamorphism and rock exhumation. These data will be used for an upgraded paleogeographic model for late Paleozoic crustal consolidation in the southwestern Central Asian Orogenic Belt. The retrogressed eclogite samples have transitional alkaline to tholeiitic affinity and trace-element patterns consistent with protoliths derived from garnet-bearing mantle sources at rifting plate margins. Geothermobarometric data for a retrogressed eclogite sample indicate peak-metamorphic conditions of 540 ± 30 °C at 1.6 ± 0.1 GPa. Samples from different lithotectonic units of the KMC provide coherent Sm-Nd garnet-whole rock ages of 317 ± 4 Ma and 316 ± 3 Ma (2σ). The prograde major-element zoning in the mm-sized garnets in combination with the moderate peak-metamorphic temperature, support our interpretation of the Sm-Nd garnet ages as unambiguous evidence for late Carboniferous HP metamorphism. The Sm-Nd garnet growth ages overlap within-error with the 40Ar/39Ar mica cooling ages of 314 ± 2 Ma and 313 ± 2 Ma (2σ) indicating rapid uplift of the subduction complex after peak metamorphism. The ca. 317-313 Ma HP-exhumation event of the KMC is contemporaneous with those of the Atbashi and Akeyazi (ca. 500 km east in NW China) HP complexes and implies similar collision histories at the South Tianshan Suture to the east and west of the Talas-Fergana Fault (TFF). The exhumation of the KMC and Atbashi HP complexes overlaps with the initiation of the TFF (Rolland et al., 2013) suggesting incipient separation of the Chatkal and Atbashi complexes during rock exhumation and early plate collision.

Development of inverted metamorphic isograds in the western metamorphic belt, Juneau, Alaska

USGS Publications Warehouse

Himmelberg, G.R.; Brew, D.A.; Ford, A.B.

1991-01-01

An inverted metamorphic gradient is preserved in the western metamorphic belt near Juneau, Alaska. Detailed mapping of pelitic single-mineral isograds, systematic changes in mineral assemblages, and silicate geothermometry indicate that thermal peak metamorphic conditions increase structurally upward over a distance of about 8 km. Silicate geobarometry suggests that the thermal peak metamorphism occurred under pressures of 9-11 kbar. Our preferred interpretation of the cause of the inverted gradient is that it formed during compression of a thickened wedge of relatively wet and cool rocks in response to heat flow associated with the formation and emplacement of tonalite sill magma. -from Authors

Mantle Lithosphere Rheology, Vertical Tectonics, and the Exhumation of (U)HP Rocks

NASA Astrophysics Data System (ADS)

Bodur, Ömer F.; Göǧüş, Oǧuz H.; Pysklywec, Russell N.; Okay, Aral I.

2018-02-01

Numerical modeling results indicate that mantle lithosphere rheology can influence the pressure-temperature-time (P-T-t) trajectories of continental crust subducted and exhumed during the onset of continental collision. Exhumation of ultrahigh-pressure ( 35 kbar)/high-temperature ( 750°C) metamorphic rocks is more prevalent in models with stronger continental mantle lithosphere (e.g., dry), whereas high-pressure ( 9-22 kbar)/low-temperature (350°C-630°C) metamorphic rocks occur in models with weaker rheology (e.g., hydrated) for the same layer. In the latter case, the buried crustal rocks can remain encased in ablatively subducting mantle lithosphere, reach only moderate temperatures, and exhume by dripping/detachment of the lithospheric root. In this transition from subduction to a dripping style of "vertical tectonics," burial and exhumation of crustal rocks are driven without imposed far-field plate convergence. The model results are compared against thermobarometric P-T estimates from major (ultra)high-pressure metamorphic terranes. We propose that the exhumation of high-pressure/low-temperature metamorphic rocks in Tavşanlı and Afyon zones in western Anatolia may be caused by viscous dripping of mantle lithosphere suggesting a weaker continental mantle lithosphere, whereas (ultra)high-pressure exhumation (e.g., Dabie Shan-eastern China and Dora Maira-western Alps) may be associated with plate-like subduction. In the latter case, the slab is much stronger and deformation is localized to the subduction interface along which rocks are buried to >100 km depth before they are exhumed to the near surface.

Very low-grade metamorphic rocks in some representative districts in Tibet

NASA Astrophysics Data System (ADS)

Bi, X.; Mo, X.

2011-12-01

*Response author: Bi,Xianmei,bixm10@sina.com Very low grade metamorphic rocks are widely distributed in Tibet, providing an insight into deformation and metamorphism during the evolution of the Tibetan Plateau. Eighty five Samples of clay mineral-bearing rocks has been collected from various strata including D, P1, T1, T2, T3, J1, J3, K1, K2 and N strata in the Qiangtang terrane, the Gangdese, the Yarlung Zangbo suture and the Tethyan Himalaya. Analyses and refining of clay minerals in samples have been conducted in the Laboratory of X-ray Diffraction, Institute of Petroleum Exploration. Index of illite crystallinity (Ic) along with average thickness of crystal layers of illite, reflectivity of vitrinite and of clay mineral association have been employed as indicators of degree of very low-grade metamorphism. The scheme of classification[1,2] of very-low grade metamorphism based on clay mineral indexes ( mainly index of illite crystallinity) has been used in the present work, that is, low metamorphism (Ic<0.25), higher very-low grade metamorphism (Ic = 0.25-0.30), lower very-low grade metamorphism (Ic = 0.30-0.42) and diagenesis (Ic>0.42). The analytical results show interesting information. In the Qiangtang terrane, clay minerals in the Jurassic strata have indexes of illite crystalinity (Ic) 0.47-0.70, indicating higher diagenesis and in favor of petroleum-generation. However, index of illite crystalinity (Ic) for the Devonian is 0.23, indicating low metamorphism. Indexes of illite crystalinity (Ic) for the J-K strata in middle Gangdese are mostly 0.37-0.25 (very-low grade metamorphism) and a few 0.78-0.48 (diagenesis). Indexes of illite crystalinity (Ic) for the C-P strata in eastern Gangdese are mostly 0.25-0.42 (very-low grade metamorphism) and a few 0.20-0.25 (low metamorphism). The Mesozoic and Cenozoic magmatism and related mineralization are very strong in the Gangdese, which may affect in some extent on indexes of illite crystalinity. In Tethyan Himalaya

Sr-isotopic composition of marbles from the Puerto Galera area (Mindoro, Philippines): additional evidence for a Paleozoic age of a metamorphic complex in the Philippine island arc

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knittel, U.; Daniels, U.

1987-02-01

The Sr-isotopic composition of marbles from the Puerto Galera area (Mindoro, Philippines) is compatible with either a Tertiary or a Paleozoic age. The former is considered as unlikely because nonmetamorphic sediments of that age overlie the metamorphic complex. This implies that the metamorphic complex does not represent the basement of the Philippine arc but is an accreted terrane.

Geophysical constraints for terrane boundaries in southern Mongolia

NASA Astrophysics Data System (ADS)

Guy, Alexandra; Schulmann, Karel; Munschy, Marc; Miehe, Jean-Marc; Edel, Jean-Bernard; Lexa, Ondrej; Fairhead, Derek

2014-05-01

The Central Asian Orogenic Belt (CAOB) is a typical accretionary orogen divided into numerous lithostratigraphic terranes corresponding to magmatic arcs, back arcs, continental basement blocks, accretionary wedges and metamorphic blocks. These terranes should be in theory characterized by contrasting magnetic and gravity signatures thanks to their different petrophysical properties. To test this hypothesis, the stratigraphically defined terranes in southern Mongolia were compared with potential field data to constrain their boundaries and extent. The existence of terranes in southern Mongolia cannot be attested by the uniform geophysical fabrics due to the lack of systematic correspondence between the high/low amplitude and high/low frequency geophysical domains and major terranes. Processed magnetic and gravity grids show that both gravity and magnetic lineaments are E-W trending in the west and correlate with direction of some geological units. In the east, both magnetic and gravity lineaments are disrupted by NE-SW trending heterogeneities resulting in complete blurring of the geophysical pattern. Correlation of magnetic signal with geological map shows that the magnetic highs coincide with late Carboniferous-early Permian volcanic and plutonic belts. The matched-filtering shows good continuity of signal to the depth located along the boundaries of these high magnetic anomalies which may imply presence of deeply rooted tectono-magmatic zones. The axes of high density bodies in the western and central part of the studied CAOB are characterized by periodic alternations of NW-SE trending high frequency and high amplitude gravity anomalies corresponding to late Permian to Triassic cleavage fronts up to 20 km wide. The matched-filtering analysis shows that the largest deformation zones are deeply rooted down to 20 km depth. Such a gravity signal is explained by the verticalization of high density mantle and lower crustal rocks due to localized vertical shearing

Modélisation magnétotellurique de la structure géologique profonde de l’unité granulitique de l’In Ouzzal (Hoggar occidental)

NASA Astrophysics Data System (ADS)

Bouzid, Abderrezak; Akacem, Nouredine; Hamoudi, Mohamed; Ouzegane, Khadidja; Abtout, Abdeslam; Kienast, Jean-Robert

2008-11-01

Magnetotelluric modeling of the deep geologic structure of In Ouzzal Granulitic Unit (western Hoggar). The In Ouzzal Granulitic Unit (IOGU) or In Ouzzal Terrane (IOT) is an Archaean block belonging to the Hoggar terrane mosaic. It has been reworked during the Eburnean and is characterized by ultrahigh temperature metamorphism of the structures, which are likely to be old dome and basin structures. The aim of this study, based on a survey of 12 magnetotelluric (MT) soundings, was to characterize the IOGU deep lateral boundaries and to see if it is possible to reconstruct some of these old dome and basin structures after their transformation by metamorphism and deformation. MT data analysis and modeling show that IOGU boundaries extend downwards, at least down to the crust's basement, and may represent suture zones. Inside the terrane, the MT observations do not allow separation between dome and basin structures, because these features are severely stretched. However, the main MT transverse response feature is a deeply rooted great accident, which may be interpreted as a major fault that separates IOGU into two compartments.

Timing of terrane accretion in eastern and east-central Maine

NASA Astrophysics Data System (ADS)

Ludman, Allan

1986-05-01

The Norumbega fault zone is often cited as a post-Acadian suture between exotic blocks, even though stratigraphic, structural, and metamorphic data indicate that there is little offset of the Silurian-Devonian strata that the zone cuts in eastern Maine. Similarly, the Kingman fault zone has been shown by gravity and geochemical studies to separate distinct crustal blocks, whereas mapping shows that it lies entirely within a Silurian turbidite package. These conflicts are resolved if the two fault zones represent boundaries between Ordovician or older crustal blocks that had accreted to form a composite terrane prior to deposition of the cover sequences. The faults now mapped within these younger rocks formed by reactivation of the pre-Silurian boundaries during late Acadian time; movement continued until the late Carboniferous. Most of the accretionary history of Maine had thus ended before the Silurian. A complex composite terrane may have formed during Cambrian-Ordovician time that (1) interacted with cratonic North America during the Taconian orogeny and (2) became the “basement” upon which the Silurian and Lower Devonian strata of eastern Maine were deposited.

Cenozoic extensional tectonics of the Western Anatolia Extended Terrane, Turkey

NASA Astrophysics Data System (ADS)

Çemen, I.; Catlos, E. J.; Gogus, O.; Diniz, E.; Hancer, M.

2008-07-01

The Western Anatolia Extended Terrane in Turkey is located on the eastern side of the Aegean Extended Terrane and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene during the formation of the Izmir-Ankara-Erzincan suture zone. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal-slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the Central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alaşehir and the south-dipping Büyük Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alaşehir, Büyük Menderes, and Simav grabens, containing high

Preserved anatectic melt in ultrahigh-temperature (or high pressure?) felsic granulites, Connecticut, US

NASA Astrophysics Data System (ADS)

Ferrero, Silvio; Axler, Jennifer; Ague, Jay J.; Wunder, Bernd; Ziemann, Martin A.

2017-04-01

experiments performed at T 1025-1050°C and P <1.7 GPa melt and garnet interacts forming a new garnet with different composition, thus indicating lack of equilibrium between melt and garnet. Such microstructure is absent in the experiment at P ≥1.7 GPa, suggesting that such P values correspond to the conditions of melting with the simultaneous production of melt and garnet. Such values are more consistent with the water content of re-homogenized inclusions, rather high for melts formed at T>1000°C. Such pressures are remarkably higher than those previously proposed for these rocks, and suggest that they experienced indeed high pressure rather than ultrahigh temperature conditions, a possibility also supported by the widespread presence of pseudomorphs of sillimanite after kyanite. References Axler JA, Ague JJ (2015). Oriented multiphase needles in garnet from ultrahigh-temperature granulites. American Mineralogist, 100, 2254-2271. Ferrero S, Wunder B, Walczak K, Ziemann MA, O'Brien PJ (2015). Preserved near ultrahigh-pressure melt from continental crust subducted to mantle depths. Geology, 43, 447-450.

A crustal model of the ultrahigh-pressure Dabie Shan orogenic belt, China, derived from deep seismic refraction profiling

USGS Publications Warehouse

Wang, Chun-Yong; Zeng, Rong-Sheng; Mooney, W.D.; Hacker, B.R.

2000-01-01

We present a new crustal cross section through the east-west trending ultrahigh-pressure (UHP) Dabie Shan orogenic belt, east central China, based on a 400-km-long seismic refraction profile. Data from our profile reveal that the cratonal blocks north and south of the orogen are composed of 35-km-thick crust consisting of three layers (upper, middle, and lower crust) with average seismic velocities of 6.0±0.2 km/s, 6.5±0.1 km/s, and 6.8±0.1 km/s. The crust reaches a maximum thickness of 41.5 km beneath the northern margin of the orogen, and thus the present-day root beneath the orogen is only 6.5 km thick. The upper mantle velocity is 8.0±0.1 km/s. Modeling of shear wave data indicate that Poisson's ratio increases from 0.24±0.02 in the upper crust to 0.27±0.03 in the lower crust. This result is consistent with a dominantly felsic upper crustal composition and a mafic lower crustal composition within the amphibolite or granulite metamorphic facies. Our seismic model indicates that eclogite, which is abundant in surface exposures within the orogen, is not a volumetrically significant component in the middle or lower crust. Much of the Triassic structure associated with the formation of the UHP rocks of the Dabie Shan has been obscured by post-Triassic igneous activity, extension and large-offset strike-slip faulting. Nevertheless, we can identify a high-velocity (6.3 km/s) zone in the upper (<5 km depth) crustal core of the orogen which we interpret as a zone of ultrahigh-pressure rocks, a north dipping suture, and an apparent Moho offset that marks a likely active strike-slip fault.

High-pressure metamorphism in the southern New England Orogen: Implications for long-lived accretionary orogenesis in eastern Australia

NASA Astrophysics Data System (ADS)

Phillips, G.; Offler, R.; Rubatto, D.; Phillips, D.

2015-09-01

New geochemical, metamorphic, and isotopic data are presented from high-pressure metamorphic rocks in the southern New England Orogen (eastern Australia). Conventional and optimal thermobarometry are augmented by U-Pb zircon and 40Ar/39Ar phengite dating to define pressure-temperature-time (P-T-t) histories for the rocks. The P-T-t histories are compared with competing geodynamic models for the Tasmanides, which can be summarized as (i) a retreating orogen model, the Tasmanides formed above a continuous, west dipping, and eastward retreating subduction zone, and (ii) a punctuated orogen model, the Tasmanides formed by several arc accretion, subduction flip, and/or transference events. Whereas both scenarios are potentially supported by the new data, an overlap between the timing of metamorphic recrystallization and key stages of Tasmanides evolution favors a relationship between a single, long-lived subduction zone and the formation, exhumation, and exposure of the high-pressure rocks. By comparison with the retreating orogen model, the following links with the P-T-t histories emerge: (i) exhumation and underplating of oceanic eclogite during the Delamerian Orogeny, (ii) recrystallization of underplated and exhuming high-pressure rocks at amphibolite facies conditions coeval with a period of rollback, and (iii) selective recrystallization of high-pressure rocks at blueschist facies conditions, reflecting metamorphism in a cooled subduction zone. The retreating orogen model can also account for the anomalous location of the Cambrian-Ordovician high-pressure rocks in the Devonian-Carboniferous New England Orogen, where sequential rollback cycles detached and translated parts of the leading edge of the overriding plate to the next, younger orogenic cycle.

Carboniferous high-pressure metamorphism of Ordovician protoliths in the Argentera Massif (Italy), Southern European Variscan belt

NASA Astrophysics Data System (ADS)

Rubatto, Daniela; Ferrando, Simona; Compagnoni, Roberto; Lombardo, Bruno

2010-04-01

The age of high-pressure metamorphism is crucial to identify a suitable tectonic model for the vast Variscan orogeny. Banded H P granulites from the Gesso-Stura Terrain in the Argentera Massif, Italy, have been recently described (Ferrando et al., 2008) relicts of high-pressure metamorphism in the western part of the Variscan orogen. Bulk rock chemistry of representative lithologies reveals intermediate silica contents and calc-alkaline affinity of the various cumulate layers. Enrichment in incompatible elements denotes a significant crustal component in line with intrusion during Ordovician rifting. Magmatic zircon cores from a Pl-rich layer yield scattered ages indicating a minimum protolith age of 486 ± 7 Ma. Carboniferous zircons (340.7 ± 4.2 and 336.3 ± 4.1 Ma) are found in a Pl-rich and a Pl-poor layer, respectively. Their zoning, chemical composition (low Th/U, flat HREE pattern and Ti-in-zircon temperature) and deformation indicate that they formed during the high-pressure event before decompression and mylonitisation. The proposed age for high-pressure metamorphism in the Argentera Massif proves that subduction preceded anatexis by less than 20 Ma. The new data allow a first-order comparison with the Bohemian Massif, which is located at the eastern termination of the Variscan orogen. Similarities in evolution at either end of the orogen support a Himalayan-type tectonic model for the entire European Variscides.

Geologic and Geochronologic Studies of the Early Proterozoic Kanektok Metamorphic Complex of Southwestern Alaska

USGS Publications Warehouse

Turner, Donald L.; Forbes, Robert B.; Aleinikoff, John N.; McDougall, Ian; Hedge, Carl E.; Wilson, Frederic H.; Layer, Paul W.; Hults, Chad P.

2009-01-01

The Kanektok complex of southwestern Alaska appears to be a rootless terrane of early Proterozoic sedimentary, volcanic, and intrusive rocks which were metamorphosed to amphibolite and granulite facies and later underwent a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism of overlying sediments. The terrane is structurally complex and exhibits characteristics generally attributed to mantled gneiss domes. U-Th-Pb analyses of zircon and sphene from a core zone granitic orthogneiss indicate that the orthogneiss protolith crystallized about 2.05 b.y. ago and that the protolithic sedimentary, volcanic and granitic intrusive rocks of the core zone were metamorphosed to granulite and amphibolite facies about 1.77 b.y. ago. A Rb-Sr study of 13 whole-rock samples also suggests metamorphism of an early Proterozoic [Paleoproterozoic] protolith at 1.77 Ga, although the data are scattered and difficult to interpret. Seventy-seven conventional 40K/40Ar mineral ages were determined for 58 rocks distributed throughout the outcrop area of the complex. Analysis of the K-Ar data indicate that nearly all of these ages have been totally or partially reset by a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism. Several biotites gave apparent K-Ar ages over 2 Ga. These ages appear to be controlled by excess radiogenic 40Ar produced by the degassing protolith during the 1.77 Ga metamorphism and incorporated by the biotites when they were at temperatures at which Ar could diffuse through the lattice. Five amphibolites yielded apparent Precambrian 40K/40Ar hornblende ages. There is no evidence that these hornblende ages have been increased by excess argon. The oldest 40K/40Ar hornblende age of 1.77 Ga is identical to the sphene 207Pb/206Pb orthogneiss age and to the Rb-Sr 'isochron' age for six of the 13 whole-rock samples. The younger hornblende ages are interpreted as

An exotic terrane in the Sulu UHP region, China

NASA Astrophysics Data System (ADS)

Chu, W.; Zhang, R.; Tsujimori, T.; Liou, J. G.

2004-12-01

The Haiyangsuo region of about 15 km2 along the coast in the NE part of the Triassic Sulu UHP terrane occurs three major rock types: amphibolitized metagabbro, gneiss and granitic dikes. Three different gneisses were observed in the field: A) Light color felsic gneiss is the dominant country rock and contains Qtz, Pl, Ms and Bi. B) Dark color plagioclase-amphibole gneiss occurs as thin layers within country rock; C) Granulite facies rock occurs as discontinuous lens. The amphibolitized metagabbros intrude into the gneisses as massive bodies (several m to hundreds of m in size) and thin dikes. Both metamorphic intrusives and gneisses are cross-cut by granitic dikes. The amphibolitized metagabbro was divided into three types: coronal metagabbro, transitional rock and garnet amphibolite: 1) Coronal metagabbro preserves gabbroic texture and primary assemblage of Opx+Cpx+Pl+Amp+Ilm. Most pyroxene grains are partially rimmed by thin corona of Amp+Ab+Qtz. Garnet occurs as fine-grained coronas at interface between plagioclase, pyroxene or ilmenite. 2) Transitional rocks contain similar assemblage and texture but most orthopyroxenes were partially or totally replaced by Amp+Qtz; garnet increases in content and size. Some gabbroic textures are preserved, but calcic plagioclase was replaced by zoisite, albite and muscovite. 3) Garnet amphibolite occurs at the margins of intrusive bodies and boudins where only minor relict clinopyroxenes preserve. Garnet coronal chains are not clear any more. Granitic dikes show pronounced deformation with mylonitic texture and contain 40-50% quartz porphyroclasts. Zircon separates from 2 metagabbros, 4 gneisses and 1 granitic rock were dated by using Stanford SHRIMP-RG. Metagabbroic zircons are angular and fractured shapes. The upper-intercept ages of gneisses rang from 1730 to about 2400 Ma, indicating variable protoith age. The 2 garnet amphibolites have upper-intercept ages 1734±5Ma and 1735±21Ma respectively. They are much older than

A Comparison of the Raman Spectra and Crystal Chemistry of Norbergite and Clinohumite at High Pressure

NASA Astrophysics Data System (ADS)

Pease, A. M.; Gramsch, S. A.

2017-12-01

Humite group minerals n(Mg.Fe)2SiO4 - (Mg,Fe)(OH)2 have been suggested as possible candidates for water storage and transport in the mantle, and clinohumite in particular has been proposed as the source of ilmenite lamellae in Alpine ultrahigh pressure metamorphic terranes via its decomposition at high pressure and temperature. In this study, a comparison is made between the Raman spectra of norbergite (n = 1) and clinohumite (n = 4) up to 15 GPa to correlate the structural and vibrational properties of these two members of the group. All observed vibrational modes in the Raman spectra of both minerals increase in frequency with pressure, although the change in frequencies with pressure is much steeper in norbergite than for clinohumite. In norbergite, antisymmetric stretching modes of the SiO4 tetrahedra merge, but no such merging of modes occurs in clinohumite. In addition, the intensity of the antisymmetric stretching mode for clinohumite decreases dramatically in pressure compared to the intensity of the symmetric stretching mode. In the spectra of norbergite, these two modes retain their relative intensities with increasing pressure. The most striking difference between the spectra of norbergite and clinohumite is in the deformation modes of the brucite layer, which within the clinohumite structure retain their intensities with increasing pressure, while these modes are not observed in the spectra of norbergite. The nature of the Raman spectra and their evolution with pressure are correlated with the structural properties of the two minerals in terms of the interactions between olivine and brucite layers and the crystal chemistry of the humite group minerals.

Jurassic to Miocene magmatism and metamorphism in the Mogok metamorphic belt and the India-Eurasia collision in Myanmar

NASA Astrophysics Data System (ADS)

Barley, M. E.; Pickard, A. L.; Zaw, Khin; Rak, P.; Doyle, M. G.

2003-06-01

Situated south of the eastern Himalayan syntaxis at the western margin of the Shan-Thai terrane the high-grade Mogok metamorphic belt (MMB) in Myanmar occupies a key position in the tectonic evolution of Southeast Asia. The first sensitive high-resolution ion microprobe U-Pb in zircon geochronology for the MMB shows that strongly deformed granitic orthogneisses near Mandalay contain Jurassic (˜170 Ma) zircons that have partly recrystallized during ˜43 Ma high-grade metamorphism. A hornblende syenite from Mandalay Hill also contains Jurassic zircons with evidence of Eocene metamorphic recrystallization rimmed by thin zones of 30.9 ± 0.7 Ma magmatic zircon. The relative abundance of Jurassic zircons in these rocks is consistent with suggestions that southern Eurasia had an Andean-type margin at that time. Mid-Cretaceous to earliest Eocene (120 to 50 Ma) I-type granitoids in the MMB, Myeik Archipelago, and Western Myanmar confirm that prior to the collision of India, an up to 200 km wide magmatic belt extended along the Eurasian margin from Pakistan to Sumatra. Metamorphic overgrowths to zircons in the orthogneiss near Mandalay date a period of Eocene (˜43 Ma) high-grade metamorphism possibly during crustal thickening related to the initial collision between India and Eurasia (at 65 to 55 Ma). This was followed by emplacement of syntectonic hornblende syenites and leucogranites between 35 and 23 Ma. Similar syntectonic syenites and leucogranites intruded the Ailao Shan-Red River shear belt in southern China and Vietnam during the Eocene-Oligocene to Miocene, and the Wang Chao and Three Pagodas faults in northern Thailand (that most likely link with the MMB) were also active at this time. The complex history of Eocene to early Miocene metamorphism, deformation, and magmatism in the MMB provides evidence that it may have played a key role in the network of deformation zones that accommodated strain during the northwards movement of India and resulting extrusion or

Thermobaric structure of the Himalayan Metamorphic Belt in Kaghan Valley, Pakistan

NASA Astrophysics Data System (ADS)

Rehman, Hafiz Ur; Yamamoto, Hiroshi; Kaneko, Yoshiyuki; Kausar, Allah Bakhsh; Murata, Mamoru; Ozawa, Hiroaki

2007-02-01

The thermobaric structure of the Himalayan Metamorphic Belt (HMB) has been constructed along the Kaghan Valley transect, Pakistan. The HMB in this valley represents mainly the Lesser Himalayan Sequence (LHS) and Higher Himalayan Crystallines (HHC). Mineral parageneses of 474 samples, from an approximately, 80-km traverse from southwest to northeast, were examined. Microprobe analyses were carried out to quantify the mineral composition. To determine the pressure-temperature (P-T) conditions, 65 thin sections (7 pelites from LHS and 25 pelites, 9 mafic rocks/amphibolites and 19 eclogites from HHC) were selected. Based on field observations and mineral paragenesis, low-grade to high-grade metapelites, show Barrovian-type progressive metamorphic sequence, with chlorite, biotite, garnet and staurolite zones in LHS and staurolite, kyanite and sillimanite zones in HHC. By using well-calibrated geothermobarometers, P-T conditions for pelitic and mafic rocks are estimated. P-T estimates for pelitic rocks from the garnet zone indicate a condition of 534 ± 17 °C at 7.6 ± 1.2 kbar. P-T estimates for rocks from the staurolite and kyanite zones indicate average conditions of 526 ± 17 °C at 9.4 ± 1.2 kbar and 657 ± 54 °C at 10 ± 1.6 kbar, respectively. P-T conditions for mafic rocks (amphibolites) and eclogites from HHC are estimated as 645 ± 54 °C at 10.3 ± 2 kbar and 746 ± 59 °C at 15.5 ± 2.1 kbar, respectively. The coesite-bearing ultrahigh-pressure (UHP) eclogites record a peak P-T condition of 757-786 °C at 28.6 ± 0.4 kbar and retrograde P-T conditions of 825 ± 59 °C at 18.1 ± 1.7 kbar. These results suggest that HMB show a gradual increase in metamorphic grade from southwest to northeast. The P-T conditions from Pelitic and adjacent mafic rocks having identical peak conditions in the same metamorphic zone, while the structural middle in HHC reached the highest P-T condition upto the UHP grade.

Physicochemical properties and storage stability of soybean protein nanoemulsions prepared by ultra-high pressure homogenization.

PubMed

Xu, Jing; Mukherjee, Dipaloke; Chang, Sam K C

2018-02-01

This study investigated the effects of the ultrahigh pressure homogenization (pressure, protein concentration, oil phase fraction, pH, temperature, and ionic strength) and storage on the properties of nanoemulsions (100-500nm range), which were stabilized by laboratory-prepared soybean protein isolate (SPI), β-conglycinin (7S) and glycinin (11S). The nanoemulsions made with SPI, 7S and 11S proteins exhibited considerable stability over various ionic strengths (0-500mM NaCl), pH (<4 or >7), thermal treatments (30-60°C) and storage (0-45days). The far-UV spectra of SPI, 7S, 11S dispersions, and SPI-, 7S-, 11S protein-stabilized nanoemulsions were analyzed for the protein structural changes following lipid removal. The ultra-high pressure homogenization changed the secondary structure of SPI, 7S, 11S proteins in the nanoemulsions, and enhanced their stability. This study demonstrated that SPI, 7S, and 11S proteins can be used as effective emulsifiers in nanoemulsions prepared by ultra-high pressure homogenization. Copyright © 2017. Published by Elsevier Ltd.

Age and tectonic implications of some low-grade metamorphic rocks from the Yucatan Channel

USGS Publications Warehouse

Vedder, J.G.; MacLeod, N.S.; Lanphere, M.A.; Dillon, William P.

1973-01-01

Phyllite and marble dredged from the lower part of the continental slope between Cuba and the Yucatan Peninsula seem to support the contention that a pre-early Tertiary metamorphic belt extends from the western Greater Antilles into northern Central America. The minimum K-Ar ages derived from the samples suggest that the metamorphic event was pre-Late Cretaceous, and evaluation of the K-Ar data implies that this metamorphic event is not older than Late Jurassic. Greater antiquity, however, is inferred from structural and stratigraphic relations in British Honduras, where the latest regional metamorphic event was post-Early Permian and pre-Middle Jurassic.  Rifting and extension related to plate motions along the British Honduras Quintana Roo margin through Mesozoic and earliest Cenozoic time presumably would preclude extensive regional metamorphism, permitting only limited development of schistose rocks there during that interval. The timing of metamorphic events in western Cuba is uncertain, but a pre-Middle Jurassic episode possibly is reflected in the phyllite and marble terranes of Isla de Pinos and Sierra de Trinidad. Local incipient metamorphism of Early and Middle Jurassic strata in the Sierra de los Organos may have resulted from severe tectonism that began in Late Cretaceous time and diminished in the Eocene.

Ultrahigh pressure deformation of polycrystaline hcp-cobalt

NASA Astrophysics Data System (ADS)

Merkel, S.; Antonangeli, D.; Fiquet, G.; Yagi, T.

2003-12-01

During the past few years, a novel set of methods has been developed allowing direct measurements on elasticity and rheology under static ultrahigh pressures using synchrotron x-ray diffraction and the diamond anvil cell. In particular, the analysis on the development of texture and uniaxial stress in a polycrystalline sample under ultrahigh pressure and non-hydrostatic conditions yielded to very interesting results on the microscopic deformation mechanisms and strength of MgO, silicate perovskite or ɛ -Fe [eg. Merkel et al. 2002, Merkel et al. 2003]. However, our understanding of the properties of the ɛ phase of iron remains poor. There are considerable uncertainties and disagreement on the results of various experiments or first-principles calculations. In particular, the results of the radial diffraction measurement on ɛ -Fe [Mao et al. 1998] have been highly controversial. In order to address this issue, we performed investigations on polycrystalline hcp-cobalt. Its properties such as the bulk modulus and thermal expansion are very close to those of ɛ -Fe and it is readily available under ambient conditions. Thus, it is a well known material and results from the high pressure radial diffraction experiments can be compared with those from well-established techniques. In the present analysis, we performed a new set a measurements between 0 and 20 GPa under ambient temperature conditions at the ESRF synchrotron source using amorphous boron gasket, monochromatic x-ray beam, and imaging plate techniques. From such an experiment, we are able to extract information on non-hydrostatic stress, elasticity, and preferred orientations of the sample in-situ under high pressure and compare them with results obtained previously on ɛ -Fe. Documenting the evolution of stress, elasticity and texture in hcp metals is of great interest for our understanding of the bulk properties and seismic anisotropy of the Earth's inner core. S. Merkel et al., J. Geophys. Res. 107 (2002

Modeling the exhumation path of partially melted ultrahigh-pressure metapelites, North-East Greenland Caledonides

NASA Astrophysics Data System (ADS)

Lang, Helen M.; Gilotti, Jane A.

2015-06-01

Pseudosection modeling constrains the pressure-temperature (P-T) exhumation path of partially melted ultrahigh-pressure (UHP) metapelites exposed in the North-East Greenland UHP terrane. A robust peak P and T estimate of 3.6 GPa and 970 °C based on mineral assemblages in nearby kyanite eclogites is the starting point for the P-T path. Although the peak assemblage for the metapelite is not preserved, the calculated modeled peak assemblage contained substantial clinopyroxene, garnet, phengite, K-feldspar and coesite with minor kyanite and rutile. Combining the pseudosection and observed textures, the decompression path crosses the coesite-quartz transition before reaching the dry phengite dehydration melting reaction where phengite is abruptly consumed. In the range of 2.5 to 2.2 GPa, clinopyroxene is completely consumed and garnet grows to its maximum volume and grossular content, matching the high grossular rims of relict megacrysts. Plagioclase joins the assemblage and the pseudosection predicts up to 12-13 vol.% melt in the supersolidus assemblage, which contained garnet, liquid, K-feldspar, plagioclase, kyanite, quartz and rutile. At this stage, the steep decompression path flattened out and became nearly isobaric. The melt crystallization assemblage that formed when the path crossed the solidus with decreasing temperature contains phengite, garnet, biotite, 2 feldspars, kyanite, quartz and rutile. Therefore, the path must have intersected the solidus at approximately 1.2 GPa, 825 °C. The pseudosection predicts that garnet is consumed on the cooling path, but little evidence of late garnet consumption or other retrograde effects is observed. This may be due to partial melt loss from the rock. Isochemical PT-n and PT-X sections calculated along the P-T path display changes in mineral assemblage and composition that are consistent with preserved assemblages.

Validation of the activity expansion method with ultrahigh pressure shock equations of state

NASA Astrophysics Data System (ADS)

Rogers, Forrest J.; Young, David A.

1997-11-01

Laser shock experiments have recently been used to measure the equation of state (EOS) of matter in the ultrahigh pressure region between condensed matter and a weakly coupled plasma. Some ultrahigh pressure data from nuclear-generated shocks are also available. Matter at these conditions has proven very difficult to treat theoretically. The many-body activity expansion method (ACTEX) has been used for some time to calculate EOS and opacity data in this region, for use in modeling inertial confinement fusion and stellar interior plasmas. In the present work, we carry out a detailed comparison with the available experimental data in order to validate the method. The agreement is good, showing that ACTEX adequately describes strongly shocked matter.

Mercury's Geochemical Terranes Revisited

NASA Astrophysics Data System (ADS)

Peplowski, P. N.; Stockstill-Cahill, K. R.

2018-05-01

We applied analytical tools to redefine Mercury's major geochemical terranes. The composition and petrology of each terrane will be discussed, along with analyses of gamma-ray data aimed at deriving absolute abundances of Si and Mg in each terrane.

Effects of the ultra-high pressure on structure and α-glucosidase inhibition of polysaccharide from Astragalus.

PubMed

Zhu, Zhen-Yuan; Luo, You; Dong, Guo-Ling; Ren, Yuan-Yuan; Chen, Li-Jing; Guo, Ming-Zhu; Wang, Xiao-Ting; Yang, Xue-Ying; Zhang, Yongmin

2016-06-01

A novel homogeneous polysaccharide fraction (APS) was extracted from Astragalus by hot water and purified by Sephadex G-100 and G-75 column. Its molecular weight was 693kDa. APS and APS with ultra-high pressure treatment exhibited significant inhibitory abilities on a-glucosidase, inhibition rate from high to low in order was 400MPa-APS, 300MPa-APS, 500MPa-APS and APS. The inhibition ​percentage of 400MPa-APS (1.5mg/mL) was 49% (max.). This suggested that the inhibitory activity of APS on a-glucosidase was improved by ultra-high pressure treatment. FT-IR, SEM, CD spectra, atomic force microscope and Congo red test analysis of APS and 400MPa-APS showed ultra-high pressure treatment didn't change the preliminary structure but had an effect on its advanced structure. Copyright © 2016 Elsevier B.V. All rights reserved.

Ultrahigh-Sensitivity Piezoresistive Pressure Sensors for Detection of Tiny Pressure.

PubMed

Li, Hongwei; Wu, Kunjie; Xu, Zeyang; Wang, Zhongwu; Meng, Yancheng; Li, Liqiang

2018-06-20

High-sensitivity pressure sensors are crucial for the ultrasensitive touch technology and E-skin, especially at the tiny-pressure range below 100 Pa. However, it is highly challenging to substantially promote sensitivity beyond the current level at several to 200 kPa -1 and to improve the detection limit lower than 0.1 Pa, which is significant for the development of pressure sensors toward ultrasensitive and highly precise detection. Here, we develop an efficient strategy to greatly improve the sensitivity near to 2000 kPa -1 using short-channel coplanar device structure and sharp microstructure, which is systematically proposed for the first time and rationalized by the mathematic calculation and analysis. Significantly, benefiting from the ultrahigh sensitivity, the detection limit is improved to be as small as 0.075 Pa. The sensitivity and detection limit are both superior to the current levels and far surpass the function of human skin. Furthermore, the sensor shows fast response time (50 μs), excellent reproducibility and stability, and low power consumption. Remarkably, the sensor shows excellent detection capacity in the tiny-pressure range, including light-emitting diode switching with a pressure of 7 Pa, ringtone (2-20 Pa) recognition, and ultrasensitive (0.1 Pa) electronic glove. This work represents a performance and strategic progress in the field of pressure sensing.

First principles study of iron-bearing MgO under ultrahigh pressure

NASA Astrophysics Data System (ADS)

Umemoto, K.; Hsu, H.

2017-12-01

Understanding of minerals under ultrahigh pressure is essential to model interiors of super-Earths. Chemical compositions of the super-Earths are expected to be similar to those of the Earth. Computational studies on Mg-Si-O ternary systems under ultrahigh pressures, which are difficult to be achieved by diamond-anvil-cell experiments, have been intensively performed (e.g., [1] for MgO, [2,3] for SiO2, and [4,5] for MgSiO3). However, as far as we know, these studies have been restricted to pure Mg-Si-O systems. In the mantles of super-Earths, we expect that there should be impurities as in the Earth's mantle. Among candidates of impurities, iron is especially important to model interiors of super-Earths. Here, we investigate iron-bearing MgO under ultrahigh pressures by first principles. We clarify effects of iron on the phase transition of MgO and thermodynamic quantities by first principles. The role of the 3d electrons will be elucidated. [1] Z. Wu, R. M. Wentzcovitch, K. Umemoto, B. Li, K. Hirose, and J. C. Zheng, J. Geophys. Res. 113, B06204 (2008). [2] S. Q. Wu, K. Umemoto, M. Ji, C. Z. Wang, K. M. Ho, and R. M. Wentzcovitch, Phys. Rev. B 83, 184102 (2011). [3] T. Tsuchiya and J. Tsuchiya, Proc. Nat. Acad. Sci. 108, 1252 (2011) [4] S. Q. Wu, M. Ji, C. Z. Wang, M. C. Nguye, X. Zhao, K. Umemoto, R. M. Wentzcovitch, and K. M. Ho, J. Phys.: Condens. Matter 26, 035402 (2014). [5] H. Niu, A. R. Oganov, X.-C. Chen, and D. Li, Sci. Rep. 5, 18347 (2015).

Mobility of gold during metamorphism of the Dalradian in Scotland

NASA Astrophysics Data System (ADS)

Pitcairn, I. K.; Skelton, A. D. L.; Wohlgemuth-Ueberwasser, C. C.

2015-09-01

Mobility of Au and related metals during metamorphism has been suggested to be the source of metals enriched in orogenic Au deposits. This study investigates the mobility of Au, As, and Sb during metamorphism of the Dalradian metasedimentary rocks of Scotland. The metamorphic processes in the Dalradian of Scotland are extremely well studied, and the terrane is an ideal area to investigate mobility of these metals. Our results show that of the 25 major and trace elements analysed, only Au, As, Sb, S and volatile contents as shown by loss on ignition (LOI) values show systematic variation with the metamorphic grade of the samples. Average Au concentrations decrease from 1.1 ± 0.55 ppb and 0.72 ± 0.34 ppb in chlorite and biotite zone rocks down to 0.4 ± 0.22 ppb and 0.34 ± 0.13 ppb in kyanite and sillimanite zone rocks. Average As concentrations decrease from 4.8 ppm (range 0.5 to 17.8 ppm) and 1.96 ± 1.9 ppm in chlorite and biotite zone rocks down to 0.24 ± 0.15 ppm and 0.2 ± 0.12 ppm in kyanite and sillimanite zone rocks. Average Sb concentrations decrease from 0.18 ± 0.15 ppm and 0.11 ± 0.10 ppm in chlorite and biotite zone rocks down to 0.04 ± 0.02 ppm in both kyanite and sillimanite zone rocks. Sulphur and LOI concentrations also show significant decreases. Mass balance calculations indicate that compared to chlorite and biotite zone samples, sillimanite zone samples have an average mass loss of 62 ± 14%, 94 ± 4% and 74 ± 14% for Au, As, and Sb respectively. Every 1 km3 of chlorite-biotite zone mixed psammitic-pelitic protolith rock that is metamorphosed to sillimanite zone conditions would release 1.5 t Au, 8613 t As, 270 t Sb, and 1.02 Mt S. The mobility of these elements is strongly controlled by the paragenesis of sulphide minerals. Pyrite, sphalerite, galena and cobaltite (as well as gersdorffite) decrease in abundance with increasing metamorphic grade in the Dalradian metasedimentary rocks. A critical aspect of the sulphide paragenesis is the

Telescoping metamorphic isograds: Evidence from 40Ar/39A dating in the Orange-Milford belt, southern Connecticut

USGS Publications Warehouse

Kunk, Michael J.; Walsh, Gregory J.; Growdon, Martha L.; Wintsch, Robert P.

2013-01-01

New 40Ar/39Ar ages for hornblende and muscovite from the Orange-Milford belt in southern Connecticut reflect cooling from Acadian amphibolite facies metamorphism between ∼380 to 360 Ma followed by retrograde recrystallization of fabric-forming muscovite and chlorite during lower greenschist facies Alleghanian transpression at ∼280 Ma. Reported field temperature and pressure gradients are improbably high for these rocks and a NW metamorphic field gradient climbing from chlorite-grade to staurolite-grade occurs over less than 5 km. Simple tilting cannot account for this compressed isograd spacing given the geothermal gradient of ∼20 °C/km present at the time of regional metamorphism. However, post-metamorphic transpression could effectively telescope the isograds by stretching the belt at an oblique angle to the isograd traces. Textures in the field and in thin section reveal several older prograde schistosities overprinted by lower greenschist facies fabrics. The late cleavages commonly occur at the scale of ∼100 μm and these samples contain multiple age populations of white mica. 40Ar/39Ar analysis of these poly-metamorphic samples with mixed muscovite populations yield climbing or U-shaped age spectra. The ages of the low temperature steps are late Paleozoic, while the ages of the older steps are late Devonian. These results support our petrologic interpretation that the younger cleavage developed under metamorphic conditions below the closure temperature for Ar diffusion in muscovite, that is, in the lower greenschist facies. The correlation of a younger regionally reproducible age population with a pervasive retrograde muscovite ± chlorite cleavage reveals an Alleghanian (∼280 Ma) overprint on the Acadian metamorphic gradient (∼380 Ma). Outcrop-scale structures including drag folds and imbricate boudins suggest that Alleghanian deformation and cleavage development occurred in response to dextral transpression along a northeast striking boundary

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes in central Iran: New geological data, relationships and tectonic implications

NASA Astrophysics Data System (ADS)

Bagheri, Sasan; Stampfli, Gérard M.

2008-04-01

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian-Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician-Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block. The "Variscan accretionary complex" is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New 40Ar/ 39Ar ages are obtained as 333-320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian-Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some 40Ar/ 39Ar radiometric ages of 163-156 Ma. The "Variscan" accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280-230 Ma 40Ar/ 39Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U

Aleutian terranes from Nd isotopes

NASA Technical Reports Server (NTRS)

Kay, R. W.; Kay, S. M.; Rubenstone, J. L.

1986-01-01

Nd isotope ratios substantiate the identification of oceanic crustal terranes within the continental crustal basement of the Aleutian island arc. The oceanic terranes are exposed in the westernmost Aleutians, but to the east, they are completely buried by isotopically distinct arc-volcanic rocks. Analogous oceanic terranes may be important components of the terrane collages that comprise the continents.

Thermal durations and heating behaviour for the Barrovian metamorphism, Scotland

NASA Astrophysics Data System (ADS)

Viete, D. R.; Lister, G. S.; Hermann, J.; Forster, M. A.; Oliver, G. J.

2008-12-01

Published U/Pb ages for the syn-metamorphic gabbros and granites of the Grampian Terrane, Scotland, that provided heat for the classical Barrovian metamorphism, suggests that they were emplaced between 473.5 and 470 Ma. New SHRIMP U/Pb ages of 472.2 ± 5.8 Ma and 470.4 ± 6.1 Ma for peak metamorphism in the highest-grade units of the Barrovian metamorphic series are consistent with a 473.5 to 470 Ma heating episode in the highest-grade units. U/Pb-calibrated 40Ar/39Ar ages for white mica from the Barrovian metamorphic series vary from c. 465 Ma for the biotite zone to c. 461 Ma for the sillimanite zone and suggest that the Barrovian thermal episode lasted less than 8.5 million years in the biotite zone and less than 12.5 million years in the sillimanite zone. The lowest-grade units of the Barrovian metamorphic series retain detrital ages in white mica 40Ar/39Ar step-heating spectra, while units metamorphosed to temperatures of 475°C or more yield Grampian 40Ar/39Ar plateau ages. Forward modelling of Ar diffusion from white mica grains was carried out for different grain sizes and thermal histories to match the position of the across-metamorphic-grade transition from detrital 40Ar/39Ar patterns to Grampian 40Ar/39Ar plateau ages. The results of Ar diffusion modelling are consistent with thermal durations of between one and 4.5 million years for the Barrovian metamorphism of the biotite zone. Microstructural observations suggest that peak metamorphism and cooling occurred earliest in the lowest-grade units of the Barrovian metamorphic series and metamorphism in the higher-grade units continued for longer. We propose metamorphic durations of between 3.5 and eight million years for the Barrovian metamorphism of the sillimanite zone. Geochemical textures preserved within high-grade garnets from the Barrovian metamorphic series record evidence of Mn diffusion over c. 1000 μm lengthscales during the Barrovian metamorphism. In addition, sillimanite-grade garnets from the

Beyond sixfold coordinated Si in SiO2 glass at ultrahigh pressures

PubMed Central

Prescher, Clemens; Prakapenka, Vitali B.; Stefanski, Johannes; Jahn, Sandro; Skinner, Lawrie B.; Wang, Yanbin

2017-01-01

We investigated the structure of SiO2 glass up to 172 GPa using high-energy X-ray diffraction. The combination of a multichannel collimator with diamond anvil cells enabled the measurement of structural changes in silica glass with total X-ray diffraction to previously unachievable pressures. We show that SiO2 first undergoes a change in Si–O coordination number from fourfold to sixfold between 15 and 50 GPa, in agreement with previous investigations. Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8 at 172 GPa. Si–O bond length shows first an increase due to the fourfold to sixfold coordination change and then a smaller linear decrease up to 172 GPa. We reconcile the changes in relation to the oxygen-packing fraction, showing that oxygen packing decreases at ultrahigh pressures to accommodate the higher than sixfold Si–O coordination. These results give experimental insight into the structural changes of silicate glasses as analogue materials for silicate melts at ultrahigh pressures. PMID:28874582

Beyond sixfold coordinated Si in SiO2 glass at ultrahigh pressures.

PubMed

Prescher, Clemens; Prakapenka, Vitali B; Stefanski, Johannes; Jahn, Sandro; Skinner, Lawrie B; Wang, Yanbin

2017-09-19

We investigated the structure of SiO 2 glass up to 172 GPa using high-energy X-ray diffraction. The combination of a multichannel collimator with diamond anvil cells enabled the measurement of structural changes in silica glass with total X-ray diffraction to previously unachievable pressures. We show that SiO 2 first undergoes a change in Si-O coordination number from fourfold to sixfold between 15 and 50 GPa, in agreement with previous investigations. Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8 at 172 GPa. Si-O bond length shows first an increase due to the fourfold to sixfold coordination change and then a smaller linear decrease up to 172 GPa. We reconcile the changes in relation to the oxygen-packing fraction, showing that oxygen packing decreases at ultrahigh pressures to accommodate the higher than sixfold Si-O coordination. These results give experimental insight into the structural changes of silicate glasses as analogue materials for silicate melts at ultrahigh pressures.

Paragneiss zircon geochronology and trace element geochemistry, North Qaidam HP/UHP terrane, western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Zhang, J.X.; Bird, D.K.

2009-01-01

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ???3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ?? 5 Ma and 426 ?? 4 Ma reflect eclogite-facies zircon growth in two of the samples. Ti-in-zircon thermometry results are tightly grouped at ???660 and ???600 ??C, respectively. Inclusions of metamorphic minerals, scarcity of inherited cores, and lack of isotopic or trace element inheritance demonstrate that significant new metamorphic zircon growth must have occurred. In contrast, zircon in the third sample is dominated by inherited grains, and rims show isotopic and trace element inheritance, suggesting solid-state recrystallization of detrital zircon with only minor new growth. ?? 2009 Elsevier Ltd.

The timing of eclogite facies metamorphism and migmatization in the Orlica–Śnieżnik complex, Bohemian Massif: Constraints from a multimethod geochronological study

USGS Publications Warehouse

Brocker, M.; Klemd, R.; Cosca, M.; Brock, W.; Larionov, A.N.; Rodionov, N.

2009-01-01

The Orlica–Śnieżnik complex (OSC) is a key geological element of the eastern Variscides and mainly consists of amphibolite facies orthogneisses and metasedimentary rocks. Sporadic occurrences of eclogites and granulites record high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic conditions. A multimethod geochronological approach (40Ar–39Ar, Rb–Sr, Sm–Nd, U–Pb) has been used to gain further insights into the polymetamorphic evolution of eclogites and associated country rocks. Special attention was given to the unresolved significance of a 370- to 360 Ma age group that was repeatedly described in previous studies. Efforts to verify the accuracy of c.370 Ma K–Ar phengite and biotite dates reported for an eclogite and associated country-rock gneiss from the location Nowa Wieś suggest that these dates are meaningless, due to contamination with extraneous Ar. Extraneous Ar is also considered to be responsible for a significantly older 40Ar–39Ar phengite date of c. 455 Ma for an eclogite from the location Wojtowka. Attempts to further substantiate the importance of 370–360 Ma zircon dates as an indicator for a melt-forming high-temperature (HT) episode did not provide evidence in support of anatectic processes at this time. Instead, SHRIMP U–Pb zircon dating of leucosomes and leucocratic veins within both orthogneisses and (U)HP granulites revealed two age populations (490–450 and 345–330 Ma respectively) that correspond to protolith ages of the magmatic precursors and late Variscan anatexis. The results of this study further underline the importance of Late Carboniferous metamorphic processes for the evolution of the OSC that comprise the waning stages of HP metamorphism and lower pressure HT overprinting with partial melting. Eclogites and their country rocks provided no chronometric evidence for an UHP and ultrahigh-temperature episode at 387–360 Ma, as recently suggested for granulites from the OSC, based on Lu–Hf garnet

Exhumation of high-pressure rocks beneath the Solund Basin, Western Gneiss Region of Norway

USGS Publications Warehouse

Hacker, B.R.; Andersen, T.B.; Root, D.B.; Mehl, L.; Mattinson, J.M.; Wooden, J.L.

2003-01-01

The Solund-Hyllestad-Lavik area affords an excellent opportunity to understand the ultrahigh-pressure Scandian orogeny because it contains a near-complete record of ophiolite emplacement, high-pressure metamorphism and large-scale extension. In this area, the Upper Allochthon was intruded by the c. 434 Ma Sogneskollen granodiorite and thrust eastward over the Middle/Lower Allochthon, probably in the Wenlockian. The Middle/Lower Allochthon was subducted to c. 50 km depth and the structurally lower Western Gneiss Complex was subducted to eclogite facies conditions at c. 80 km depth by c. 410-400 Ma. Within 100. Exhumation to upper crustal levels was complete by c. 403 Ma. The Solund fault produced the last few km of tectonic exhumation, bringing the near-ultrahigh-pressure rocks to within c. 3 km vertical distance from the low-grade Solund Conglomerate.

Mineral Reactions Involving Sapphirine and Their Application for Characterization of Metamorphic Conditions

NASA Astrophysics Data System (ADS)

Podlesskii, K. K.

2008-05-01

Assemblages of sapphirine, once considered to be a rare mineral, have in recent years been recognized as important indicators of high-temperature metamorphism. They occur in rocks that have undergone different tectono-metamorphic histories, with the P-T range of formation being estimated from below 700°C and 0.5 GPa to above 1100°C and 1.5 GPa. Sapphirine associated with quartz is attributed exclusively to the highest temperature conditions of crustal metamorphism referred to as ultrahigh-temperatiure metamorphism. Although experimental data involving sapphirine extend over an even wider P-T range, the quantitative interpretation of sapphirine-bearing assemblages remains ambiguous. Thermodynamic properties of magnesian sapphirine end-members have been optimized on the basis of experimentally constrained phase relations with the equation of state developed by Gerya et al., 2004. They differ from the model used in THERMOCALC (Kelsey et al., 2004), and the differences in the estimated stability of assemblages of sapphirine with quartz, kyanite and forsterite, to which a special attention have been paid due to their petrologic importance, look dramatic and may change interpretations of petrogenetic processes.

Eclogitization on the way up: Lu-Hf garnet chronology of metasomatic ultrahigh-pressure rocks from the Western Gneiss Complex, Norway

NASA Astrophysics Data System (ADS)

Cutts, J.; Smit, M. A.; Vrijmoed, J. C.

2016-12-01

The Western Gneiss Complex (WGC) is a fragment of continental crust that was subjected to high- and ultrahigh pressure (HP; UHP) conditions as a result of Caledonian continental collision (420-400 Ma). Most eclogite lenses and related high-pressure rocks have yielded petrological and chronological results that are consistent with a generalized model of Caledonian continental subduction. A distinct suite of eclogitic rocks - metasomatized (`Caledonized') Fe-Ti meta-peridotites - indicate extreme pressure conditions that do not fit the regional field gradient. The timing of these excursions is critical to their interpretation; however, so far limited age constraints exist for these rocks. In this study, we subject one such rock - the Magerøy orthopyroxene eclogite on the island of Otrøy - to Lu-Hf garnet chronology; a method that provides precise and robust data for garnet even at extreme temperatures. Conventional barometry indicates equilibration of the main garnet-bearing assemblage at c. 4.3 GPa and garnet geochronology yielded a date of c. 390 Ma. This result overlaps with Sm-Nd garnet and U-Pb zircon ages from the nearby diamond-bearing Svartberget peridotite body and leucosomes in its host gneiss. However, the age is ≥ 10 Ma younger than age data for most other eclogite lenses in WGC and corresponds to a time when the terrane was already exhumed to 30-35 km depth. The discrepancy in P-T-t evolution between the bulk of the WGC, and the (ultra-) mafic rocks at Magerøy and Svartberget indicates that the latter rocks reflect localized fluid-induced re-equilibration at pressures higher than lithostatic. The new data provide new support for the occurrence of this phenomenon in subducted continental crust undergoing exhumation and partial melting.

Terrane accretion: Insights from numerical modelling

NASA Astrophysics Data System (ADS)

Vogt, Katharina; Gerya, Taras

2016-04-01

The oceanic crust is not homogenous, but contains significantly thicker crust than norm, i.e. extinct arcs, spreading ridges, detached continental fragments, volcanic piles or oceanic swells. These (crustal) fragments may collide with continental crust and form accretionary complexes, contributing to its growth. We analyse this process using a thermo-mechanical computer model (i2vis) of an ocean-continent subduction zone. In this model the oceanic plate can bend spontaneously under the control of visco-plastic rheologies. It moreover incorporates effects such as mineralogical phase changes, fluid release and consumption, partial melting and melt extraction. Based on our 2-D experiments we suggest that the lithospheric buoyancy of the downgoing slab and the rheological strength of crustal material may result in a variety of accretionary processes. In addition to terrane subduction, we are able to identify three distinct modes of terrane accretion: frontal accretion, basal accretion and underplating plateaus. We show that crustal fragments may dock onto continental crust and cease subduction, be scrapped off the downgoing plate, or subduct to greater depth prior to slab break off and subsequent exhumation. Direct consequences of these processes include slab break off, subduction zone transference, structural reworking, formation of high-pressure terranes, partial melting and crustal growth.

Metamorphic records of multiple seismic cycles during subduction

PubMed Central

Hacker, Bradley R.; Seward, Gareth G. E.; Kelley, Chris S.

2018-01-01

Large earthquakes occur in rocks undergoing high-pressure/low-temperature metamorphism during subduction. Rhythmic major-element zoning in garnet is a common product of such metamorphism, and one that must record a fundamental subduction process. We argue that rhythmic major-element zoning in subduction zone garnets from the Franciscan Complex, California, developed in response to growth-dissolution cycles driven by pressure pulses. Using electron probe microanalysis and novel techniques in Raman and synchrotron Fourier transform infrared microspectroscopy, we demonstrate that at least four such pressure pulses, of magnitude 100–350 MPa, occurred over less than 300,000 years. These pressure magnitude and time scale constraints are most consistent with the garnet zoning having resulted from periodic overpressure development-dissipation cycles, related to pore-fluid pressure fluctuations linked to earthquake cycles. This study demonstrates that some metamorphic reactions can track individual earthquake cycles and thereby opens new avenues to the study of seismicity. PMID:29568800

On the timing of high-pressure metamorphism in Alpine Corsica: the first Lu-Hf garnet and lawsonite ages

NASA Astrophysics Data System (ADS)

Vitale Brovarone, A.; Herwartz, D.; Castelli, D.; Malavieille, J.

2012-04-01

Timing of HP metamorphism in Alpine Corsica is highly debated. Controversial biostratigraphic and radiometric constraints results in a poor understanding of the evolution of Alpine Corsica and its meaning in the Western Mediterranean dynamics. Age estimates provided by means of several techniques (e.g. Ar-Ar, Sa-Nd, U-Pb) vary form Late Cretaceous to Late Eocene. Some authors favor a Late Cretaceous peak metamorphism under HP conditions followed by Late Eocene and Early Oligocene blueschist and greenschist retrogression, respectively. Others favor a Late Eocene peak metamorphism and consider the older estimates as affected by analytical inaccuracy. In order to unravel this debate, we provide new Lu-Hf constraints on garnet and lawsonite from the lawsonite-eclogite and lawsonite-blueschist units of Alpine Corsica, which represent a part of the so-called Schistes Lustrés complex. The two investigated units are interpreted to represent remnants of the former Corsican ocean-continent transition zone [2]. As Lu concentrates in the cores of the selected minerals during the early stages of growth and blocking temperatures are high, this method provides robust insight on the timing of prograde/peak metamorphism [1]. Garnet and lawsonite separated form three lawsonite-eclogite samples yield systematic Late Eocene ages at ~ 34 Ma, while lawsonite from the lawsonite-blueschist unit yields a slightly older age at ~ 37 Ma. These data are in agreement with U-Pb data on zircon from the lawsonite-eclogite unit (~ 34 Ma) [3], but are in contrast with a recent U-Pb estimate on the Corsican continental margin unit metamorphosed under blueschist condition, yielding an age of ~ 55 Ma [4]. These discrepancies indicate a complex paleogeographic setting and a diachronous metamorphic evolution along the Corsican ocean-continent transition zone. The Late Eocene HP metamorphism in the Schistes Lustrés of Alpine Corsica also provides important constraints in the evolution of the Alps

High-pressure granulites in the Fuping Complex of the central North China Craton: Metamorphic P-T-t evolution and tectonic implications

NASA Astrophysics Data System (ADS)

Qian, Jiahui; Yin, Changqing; Zhang, Jian; Ma, Li; Wang, Luojuan

2018-04-01

Mafic granulites in the Fuping Complex occur as lenses or boudins within high-grade TTG (Trondhjemite-Tonalite-Granodiorite) gneisses. Petrographic observations reveal four generations of mineral assemblage in the granulites: an inclusion assemblage of hornblende + plagioclase + ilmenite + quartz within garnet core; an inferred peak assemblage composed of garnet ± hornblende + plagioclase + clinopyroxene + rutile/ilmenite + quartz; a decompression assemblage characterized by symplectites of clinopyroxene ± orthopyroxene + plagioclase, coronae of plagioclase ± clinopyroxene ± hornblende around embayed garnet porphyroblasts or a two-pyroxene association; and a late amphibolite-facies retrogressive assemblage. Two representative samples were used for pseudosection modeling in NCFMASHTO model system to determine their metamorphic evolution. The results show that these granulites experienced a high-pressure stage of metamorphism with peak P-T conditions of 12-13 kbar and 760-800 °C (Pmax) and a post-peak history under P-T conditions of ∼9.0 kbar and 805-835 °C (Tmax), indicating a nearly isothermal decompression process (ITD) with a slight heating. Metamorphic evolution from the Pmax to the Tmax is predicted to be dominated by garnet breakdown through continuous metamorphic reactions of garnet + quartz ± diopside = hornblende + plagioclase + liquid and garnet + quartz + hornblende = plagioclase + diopside + liquid + orthopyroxene. Further metamorphic evolution after the Tmax is dominated by cooling, suggesting that high-pressure (HP) granulites may also exist in the Fuping Complex. Metamorphic zircons in the Fuping HP mafic granulites have left inclined REE patterns, Ti contents of 1.68-6.88 ppm and crystallization temperatures of 602-712 °C. SIMS zircon U-Pb dating on these zircons yields 207Pb/206Pb ages of 1891 ± 14 Ma and 1849 ± 6 Ma, interpreted to represent the cooling stage of metamorphism. The P-T-t evolution of the Fuping HP mafic granulites records

Ultrahigh vacuum/high pressure chamber for surface x-ray diffraction experiments

NASA Astrophysics Data System (ADS)

Bernard, P.; Peters, K.; Alvarez, J.; Ferrer, S.

1999-02-01

We describe an ultrahigh vacuum chamber that can be internally pressurized to several bars and that is designed to perform surface x-ray diffraction experiments on solid-gas interfaces. The chamber has a cylindrical beryllium window that serves as the entrance and exit for the x rays. The sample surface can be ion bombarded with an ancillary ion gun and annealed to 1200 K.

Terranes and the tectonic assembly of South America: The fifth Circum-Pacific terrane conference

NASA Astrophysics Data System (ADS)

Moore, G. W.

1994-10-01

A central theme of the 5th Circum-Pacific Terrane Conference held at Santiago, Chile, 11-14 November 1991, was the new theory that Australia and Antarctica separated from western North America during the Late Proterozoic, then crashed into Africa and South America to form Gondwana in the Late Cambrian. Particular interest centered on the Precordillera Terrane, which came from central North America and was accreted to Argentina during the Ordovician, and on the Avalon Terrane, derived from northern South American and accreted to Laurasia during the Taconic Orogeny. The mobility of plates and terranes has been so great that before the Mesozoic the Circum-Pacific and Circum-Atlantic regions were one and the same.

Effect of ultra-high pressure on small animals, tardigrades and Artemia

NASA Astrophysics Data System (ADS)

Ono, Fumihisa; Mori, Yoshihisa; Takarabe, Kenichi; Fujii, Akiko; Saigusa, Masayuki; Matsushima, Yasushi; Yamazaki, Daisuke; Ito, Eiji; Galas, Simon; Saini, Naurang L.

2016-12-01

This research shows that small animals, tardigrades (Milnesium tardigradum) in tun (dehydrated) state and Artemia salina cists (dried eggs) can tolerate the very high hydrostatic pressure of 7.5 GPa. It was really surprising that living organisms can survive after exposure to such a high pressure. We extended these studies to the extremely high pressure of 20 GPa by using a Kawai-type octahedral anvil press. After exposure to this pressure for 30 min, the tardigrades were soaked in pure water and investigated under a microscope. Their bodies regained metabolic state and no serious injury could be seen. But they were not alive. A few of Artemia eggs went part of the way to hatching after soaked in sea water, but they never grew any further. Comparing with the case of blue-green alga, these animals are weaker under ultra-high pressure.

Detrital Zircon Signature of Proterozoic Metasedimentary Rocks of the Pearya Terrane, Northern Ellesmere Island: Implications for Terrane Stratigraphy and Circum-Arctic Terrane Correlations

NASA Astrophysics Data System (ADS)

Malone, S. J.; McClelland, W.

2012-12-01

The Pearya Terrane, currently recognized as the only exotic terrane in the Canadian Arctic margin, includes early Tonian metaigneous rocks and a sequence of sedimentary rocks ranging from Proterozoic shallow marine to Silurian arc-accretionary units. Succession II (Trettin, 1987) of the Pearya Terrane represents variably metamorphosed metasedimentary rocks of presumed Neoproterozoic to early Ordocician age. These units are structurally juxtaposed with earliest Neoproterozoic orthogneiss of Succession I and the overlaying sedimentary rocks of the Paleozoic section. Detrital zircon age spectra from seven samples of Neoproterozoic meta-sedimentary rocks define three groups on the basis of dominant age peaks and the age of the youngest peaks. Group I, representing three quartzite samples, contains young zircon age peaks at c. 1050 Ma with numerous c. 1100 Ma to 1800 Ma peaks. Detrital zircon spectra from Group I correlate closely with data from the latest Mesoproterozoic Brennevinsfjorden Group of Northeastern Svalbard, suggesting that the base of Succession II may be older than the Succession I orthogneiss, and that the contact between them is tectonic. Group II is defined by a dominant c. 970 Ma age peak that overlaps with ages determined for basement orthogneiss units and indicates that local sedimentary sources, possibly relating to Tonian igneous activity, dominated. Group III displays a similar pattern of c. 1000 Ma to 1800 Ma age peaks to Group I, but contains a small population of c. 600 Ma to 700 Ma grains that are likely sourced from elements of the Timanide orogen and/or the Arctic Alaska-Chukotka (AAC) microplate. The ubiquitous Mesoproterozoic ages suggest extensive sediment input from the Grenville-Svegonorwegian domains of Laurentia and Baltica, either directly or by sediment recycling. This is consistent with detrital zircon datasets from other North Atlantic-Arctic Caledonide terranes, reinforcing stratigraphic links between the Pearya Terrane

Unravelling the complexities of a high-grade Paleoarchean terrane: Saglek Block, Labrador, Canada

NASA Astrophysics Data System (ADS)

Salacinska, Anna; Kusiak, Monika; Dunkley, Daniel; Whitehouse, Martin; Wilde, Simon

2017-04-01

The Nain Province of Labrador is on the western edge of the Archean North Atlantic Craton, and includes the Saglek Block, where >3.6 Ga Uivak orthogneisses were intercalated with a variety of supracrustals during Neoarchean granulite-grade metamorphism. In order to unravel the complex magmatic and metamorphic history of this terrane, samples of grey orthogneiss mapped as Uivak Gneiss were taken from Tigigakyuk Inlet, where previous studies have suggested the preservation of >3.9 Ga zircons [1]. Samples vary from fine, equigranular felsic-intermediate gneiss, through slightly porphyroblastic metagranitoids to metagabbros. Felsic orthogneises are mostly composed of oligoclase, quartz, biotite and K-feldspar, whereas more mafic samples contain hornblende and augite, with the latter being largely altered to pargasite during post-granulite hydration and lower-grade metamorphism. Geochemically, all samples follow a calc-alkaline differentiation trend, and are metaluminous to slightly peraluminous. Based on the normative albite-anorthite-orthoclase diagram, samples plot within the tonalite and trondhjemite fields; however, according to the normative QAPF classification, they are granodioritic to quartz-monzodioritic. Following the criteria of Moyen and Martin (2012), only one granodioritic sample represents typical Archean TTG gneiss, while the other samples are slightly more K-rich. Although bulk compositions may have been affected by K-enrichment during granulite-facies metamorphism, these samples mostly belong to the "TTG-like" suite. Concordant SIMS U-Pb age data obtained from the zircon cores with characteristic igneous growth textures from TTG-like and quartz monzodioritic gneiss fall within the interval 3.70-3.75 Ga, consistent with previous age estimates for the protoliths of Uivak I gneisses [3,4]. Some quartz monzodioritic gneisses are significantly younger (3.55 Ga), showing that the gneisses at Tigigakyuk Inlet are not of a simple magmatic suite, but are

Detrital zircons from the Tananao metamorphic complex of Taiwan: Implications for sediment provenance and Mesozoic tectonics

NASA Astrophysics Data System (ADS)

Yui, T. F.; Maki, K.; Lan, C. Y.; Hirata, T.; Chu, H. T.; Kon, Y.; Yokoyama, T. D.; Jahn, B. M.; Ernst, W. G.

2012-05-01

Taiwan formed during the Plio-Pleistocene collision of Eurasia with the outboard Luzon arc. Its pre-Tertiary basement, the Tananao metamorphic complex, consists of the western Tailuko belt and the eastern Yuli belt. These circum-Pacific belts have been correlated with the high-temperature/low-pressure (HT/LP) Ryoke belt and the high-pressure/low-temperature (HP/LT) Sanbagawa belt of Japan, respectively. To test this correlation and to reveal the architecture and plate-tectonic history of the Tananao metamorphic basement, detrital zircons were separated from 7 metasedimentary rock samples for U-Pb dating by LA-ICPMS techniques. Results of the present study, coupled with previous data, show that (1) the Tailuko belt consists of a Late Jurassic to earliest Cretaceous accretionary complex sutured against a Permian-Early Jurassic marble ± metabasaltic terrane, invaded in the north by scattered Late Cretaceous granitic plutons; the latter as well as minor Upper Cretaceous cover strata probably formed in a circum-Pacific forearc; (2) the Yuli belt is a mid- to Late Cretaceous accretionary complex containing HP thrust sheets that were emplaced attending the Late Cenozoic Eurasian plate-Luzon arc collision; (3) these two Late Mesozoic belts are not coeval, and in part were overprinted by low-grade metamorphism during the Plio-Pleistocene collision; (4) accreted clastic sediments of the Tailuko belt contain mainly Phanerozoic detrital zircons, indicating that terrigenous sediments were mainly sourced from western Cathaysia, whereas in contrast, clastic rocks of the Yuli accretionary complex contain a significant amount of Paleoproterozoic and distinctive Neoproterozoic zircons, probably derived from the North China craton and the Yangtze block ± eastern Cathaysia, as a result of continent uplift/exhumation after the Permo-Triassic South China-North China collision; and (5) the Late Jurassic-Late Cretaceous formation of the Tananao basement complex precludes the possibility

Flexible Ferroelectric Sensors with Ultrahigh Pressure Sensitivity and Linear Response over Exceptionally Broad Pressure Range.

PubMed

Lee, Youngoh; Park, Jonghwa; Cho, Soowon; Shin, Young-Eun; Lee, Hochan; Kim, Jinyoung; Myoung, Jinyoung; Cho, Seungse; Kang, Saewon; Baig, Chunggi; Ko, Hyunhyub

2018-04-24

Flexible pressure sensors with a high sensitivity over a broad linear range can simplify wearable sensing systems without additional signal processing for the linear output, enabling device miniaturization and low power consumption. Here, we demonstrate a flexible ferroelectric sensor with ultrahigh pressure sensitivity and linear response over an exceptionally broad pressure range based on the material and structural design of ferroelectric composites with a multilayer interlocked microdome geometry. Due to the stress concentration between interlocked microdome arrays and increased contact area in the multilayer design, the flexible ferroelectric sensors could perceive static/dynamic pressure with high sensitivity (47.7 kPa -1 , 1.3 Pa minimum detection). In addition, efficient stress distribution between stacked multilayers enables linear sensing over exceptionally broad pressure range (0.0013-353 kPa) with fast response time (20 ms) and high reliability over 5000 repetitive cycles even at an extremely high pressure of 272 kPa. Our sensor can be used to monitor diverse stimuli from a low to a high pressure range including weak gas flow, acoustic sound, wrist pulse pressure, respiration, and foot pressure with a single device.

Petrological and zircon evidence for the Early Cretaceous granulite-facies metamorphism in the Dabie orogen, China

NASA Astrophysics Data System (ADS)

Gao, Xiao-Ying; Zhang, Qiang-Qiang; Zheng, Yong-Fei; Chen, Yi-Xiang

2017-07-01

An integrated study of petrology, mineralogy, geochemistry, and geochronology was carried out for contemporaneous mafic granulite and diorite from the Dabie orogen. The results provide evidence for granulite-facies reworking of the ultrahigh-pressure (UHP) metamorphic rock in the collisional orogen. Most zircons from the granulite are new growth, and their U-Pb ages are clearly categorized into two groups at 122-127 Ma and 188 ± 2 Ma. Although these two groups of zircons show similarly steep HREE patterns and variably negative Eu anomalies, the younger group has much higher U, Th and REE contents and Th/U ratios, much lower εHf(t) values than the older group. This suggests their growth is associated with different types of dehydration reactions. The older zircon domains contain mineral inclusions of garnet + clinopyroxene ± quartz, indicating their growth through metamorphic reactions at high pressures. In contrast, the young zircon domains only contain a few quartz inclusions and the garnet-clinopyroxene-plagioclase-quartz barometry yields pressures of 4.9 to 12.5 kb. In addition, the clinopyroxene-garnet Fe-Mg exchange thermometry gives temperatures of 738-951 °C. Therefore, the young zircon domains would have grown through peritectic reaction at low to medium pressures. The younger granulite-facies metamorphic age is in agreement not only with the adjacent diorite at 125 ± 1 Ma in this study but also the voluminous emplacement of coeval mafic and felsic magmas in the Dabie orogen. Mineral separates from both mafic granulite and its adjacent diorite show uniformly lower δ18O values than normal mantle, similar to those for UHP eclogite-facies metaigneous rocks in the Dabie orogen. In combination with major-trace elements and zircon Lu-Hf isotope compositions, it is inferred that the protolith of mafic granulites shares with the source rock of diorites, both being a kind of mafic metasomatites at the slab-mantle interface in the continental subduction channel

Neoarchean high-pressure metamorphism from the northern margin of the Palghat-Cauvery Suture Zone, southern India: Petrology and zircon SHRIMP geochronology

NASA Astrophysics Data System (ADS)

Saitoh, Yohsuke; Tsunogae, Toshiaki; Santosh, M.; Chetty, T. R. K.; Horie, Kenji

2011-08-01

We report the metamorphic pressure-temperature ( P- T) history of mafic granulites from two localities in southern India, one from Kanja Malai in the northern margin and the other from Perundurai in the central domain of the Palghat-Cauvery Suture Zone (PCSZ). The PCSZ is described in recent models as the trace of the suture along which crustal blocks were amalgamated within the Gondwana supercontinent during Late Neoproterozoic-Cambrian. The mafic granulite from Kanja Malai yields P- T conditions of 750-800 °C and 8-12 kbar reflecting the partially retrograded conditions following a peak high-pressure (HP) metamorphic event. The common Grt + Cpx + Qtz assemblage in these rocks and lack of decompression texture suggest that peak metamorphism was probably buffered by Grt + Cpx + Opx + Pl + Qtz assemblage, following which the rocks were exhumed through a gradual P- T decrease. The mafic granulite from Perundurai (Grt + Cpx + Pl) contains Opx + Pl symplectite commonly occurring between garnet and clinopyroxene, suggesting the progress of reaction: Grt + Cpx + Qtz → Opx + Pl, with the Grt + Cpx + Qtz representing the peak metamorphic assemblage. The reaction microstructures and calculated P- T conditions suggest that the mafic granulites from Perundurai underwent peak HP metamorphism at P > 12 kbar and T = 800-900 °C and subsequent isothermal decompression along a clockwise P- T path, in contrast to the P- T path inferred for Kanja Malai. The contrasting P- T paths obtained from the two localities suggest that whereas Perundurai is a part of the metamorphic orogen developed within the PCSZ during Gondwana assembly, the high-pressure granulites of Kanja Malai belong to a different orogenic regime. In order to evaluate this aspect further, we analyzed zircons in a charnockite and garnet-bearing quartzo-feldspathic gneiss associated with the HP granulites from Kanja Malai which yielded mean 207Pb/ 206Pb magmatic protolith emplacement ages of 2536.1 ± 1.4 Ma and 2532

Exhumation rates of high pressure metamorphic rocks in subduction channels: The effect of Rheology

NASA Astrophysics Data System (ADS)

Gerya, T. V.; Stöckhert, B.

2002-04-01

Exhumation of high-pressure metamorphic rocks can take place with typical plate velocities of cm/year. This is consistent with a model of forced flow in a subduction channel. The (micro)structural record of exhumed metamorphic rocks indicates that stresses are generally too low to drive deformation of the bulk material by dislocation creep, according to a power-law rheology. Instead deformation appears to be localized in low-strength shear zones, and is dominated by dissolution precipitation creep or fluid assisted granular flow, implying a Newtonian rheology. 1D modeling shows that the effective rheology of the material in the subduction channel has a significant influence on the rate of exhumation. When the subduction flux either equals or exceeds the return flux, the maximum exhumation rate for Newtonian behavior of the material is at least twice as high (~1/3 of the subduction burial rate) compared to that for power-law creep (~1/6 of the subduction burial rate).

Water dynamics and retrogradation of ultrahigh pressurized wheat starch.

PubMed

Doona, Christopher J; Feeherry, Florence E; Baik, Moo-Yeol

2006-09-06

The water dynamics and retrogradation kinetics behavior of gelatinized wheat starch by either ultrahigh pressure (UHP) processing or heat are investigated. Wheat starch completely gelatinized in the condition of 90, 000 psi at 25 degrees C for 30 min (pressurized gel) or 100 degrees C for 30 min (heated gel). The physical properties of the wheat starches were characterized in terms of proton relaxation times (T2 times) measured using time-domain nuclear magnetic resonance spectroscopy and evaluated using commercially available continuous distribution modeling software. Different T2 distributions in both micro- and millisecond ranges between pressurized and heated wheat starch gels suggest distinctively different water dynamics between pressurized and heated wheat starch gels. Smaller water self-diffusion coefficients were observed for pressurized wheat starch gels and are indicative of more restricted translational proton mobility than is observed with heated wheat starch gels. The physical characteristics associated with changes taking place during retrogradation were evaluated using melting curves obtained with differential scanning calorimetry. Less retrogradation was observed in pressurized wheat starch, and it may be related to a smaller quantity of freezable water in pressurized wheat starch. Starches comprise a major constituent of many foods proposed for commercial potential using UHP, and the present results furnish insight into the effect of UHP on starch gelatinization and the mechanism of retrogradation during storage.

Thermal contraints on high-pressure granulite metamorphism of supracrustal rocks

NASA Technical Reports Server (NTRS)

Ashwal, L. D.; Morgan, P.; Leslie, W. W.

1983-01-01

The circumstances leading to the formation and exposure at the Earth's surface of supracrustal granulites are examined. These are defined as sediments, volcanics, and other rock units which originally formed at the surface of the Earth, were metamorphosed to high-pressure granulite facies (T = 700-900 C, P = 5-10 kbar), and reexposed at the Earth's surface, in many cases underlain by normal thicknesses of continental crust (30-40 km). Five possible heating mechanisms to account for granulite metamorphism of supracrustal rocks are discussed: magnetic heating, thermal relaxation of perturbed temperature profiles following underthrusting of the continental crust, thermal relaxation after underthrusting of thin slivers of supracrustal rocks below continental crust of normal thickness, major preheating of the upper plate, and shear heating caused by frictional stress along the thrust plane.

Ultrahigh hydrostatic pressure extraction of flavonoids from Epimedium koreanum Nakai

NASA Astrophysics Data System (ADS)

Hou, Lili; Zhang, Shouqin; Dou, Jianpeng; Zhu, Junjie; Liang, Qing

2011-02-01

Herba Epimedii is one of the most famous Chinese herbal medicines listed in the Pharmacopoeia of the People's Republic of China, as one of the representatives of traditional Chinese herb, it has been widely applied in the field of invigorate the kidney and strengthen 'Yang'. The attention to Epimedium extract has more and more increased in recent years. In this work, a novel extraction technique, ultra-high hydrostatic pressure extraction (UPE) technology was applied to extract the total flavonoids of E. koreanum. Three factors (pressure, ethanol concentration and extraction time) were chosen as the variables of extraction experiments, and the optimum UPE conditions were pressure 350 MPa; ethanol concentration 50% (v/v); extraction time 5 min. Compared with Supercritical CO2 extraction, Reflux extraction and Ultrasonic-assisted extraction, UPE has excellent advantages (shorter extraction time, higher yield, better antioxidant activity, lower energy consumption and eco-friendly).

Techniques for measuring ultrahigh-pressure Hugoniot equation of state on a three-stage gas gun

NASA Astrophysics Data System (ADS)

Wang, Xiang; Hu, Jianbo; Dai, Chengda; Wang, Qiangsong; Bo, Jingsong; Tan, Hua; Yu, Yuying

2011-06-01

A three-stage gas gun was developed by mounting an extending launcher tube on a two-stage gas gun, and was successfully applied to perform ultrahigh-pressure Hugoniot measurements for Ta and Pt by using this three-stage gun. Here we introduced the three-stag gas gun launcher and Hugoniot measurement techniques, including shock front shape diagnosis, shock wave velocity and impact velocity measurement as well as numerical simulation. By using this three-stage gun, Ta or Pt impactors were launched up to ~10 km/s, and the Hugoniot data were respectively measured with high accuracy up to 750 GPa for Ta and 1TPa for Pt. It is demonstrated that the three-stage gas gun is a promising technique for studying the ultrahigh-pressure properties of materials, which never before obtained by utilizing two-stage light-gas-gun.

U-Pb Geochronology of Devonian Granites in the Meguma Terrane of Nova Scotia, Canada: Evidence for Hotspot Melting of a Neoproterozoic Source.

PubMed

Keppie; Krogh

1999-09-01

U-Pb isotopic analyses of monazite and zircon from six granitic plutons in the Meguma Terrane yield nearly concordant ages of 373+/-3 Ma, interpreted as the time of intrusion. U-Pb analyses of euhedral zircons with thick rims overgrowing cores, which were abraded to remove all or most of the rim, plot on chords between 370+/-3 and 628+/-33 Ma (Larrys River and Halfway Cove plutons), 372+/-3 and approximately 660 Ma (Shelburne pluton), and 373+/-2 and approximately 732 Ma (Barrington Passage pluton). The upper intercepts are interpreted as the age of magma source, correlatives of which are present in the Avalon Composite Terrane to the north. This basement may be either in depositional or tectonic contact with the overlying Cambro-Ordovician Meguma Group. Other zircons in the granites are generally irregular-euhedral with thin rims, and most U-Pb isotopic analyses fall between two chords from 373-2040 and 373-2300 Ma, with a few lying outside this field. These zircons are probably derived from the country rock (Goldenville Formation), which a previous study has shown contains detrital zircons with concordant U-Pb ages of 3000, 2000, and 600 Ma, and numerous intermediate discordant ages. These new ages, along with published data, document a relatively short (5-10 m.yr.) but voluminous period of magmatism. This age is approximately synchronous with intrusion of mafic rocks and lamprophyre dikes and regional low-pressure metamorphism and was followed by rapid denudation of 5-12 km. These observations may be interpreted in terms of shallowly dipping subduction and overriding of a mantle plume that eventually penetrates through the subducting plate to melt the overriding continental plate. Subsequent northward migration of the plume could explain both the approximately 360 Ma magmatism in the Cobequid Highlands (Avalon Composite Terrane) and the mid-Carboniferous plume-related intrusions around the Magdalen Basin.

Metamorphic geology: Why should we care?

NASA Astrophysics Data System (ADS)

Tajcmanova, Lucie; Moulas, Evangelos; Vrijmoed, Johannes

2016-04-01

Estimation of pressure-temperature (P-T) from petrographic observations in metamorphic rocks has become a common practice in petrology studies during the last 50 years. This data then often serves as a key input in geodynamic reconstructions and thus directly influences our understanding of lithospheric processes. Such an approach might have led the metamorphic geology field to a certain level of quiescence. Obtaining high-quality analytical data from metamorphic rocks has become a standard part of geology studies. The numerical tools for geodynamic reconstructions have evolved to a great extend as well. Furthermore, the increasing demand on using the Earth's interior for sustainable energy or nuclear waste disposal requires a better understanding of the physical processes involved in fluid-rock interaction. However, nowadays, metamorphic data have apparently lost their importance in the "bigger picture" of the Earth sciences. Interestingly, the suppression of the metamorphic geology discipline limits the potential for understanding the aforementioned physical processes that could have been exploited. In fact, those phenomena must be considered in the development of new generations of fully coupled numerical codes that involve reacting materials with changing porosity while obeying conservation of mass, momentum and energy. In our contribution, we would like to discuss the current role of metamorphic geology. We will bring food for thoughts and specifically touch upon the following questions: How can we revitalize metamorphic geology? How can we increase the importance of it? How can metamorphic geology contribute to societal issues?

Punctuated HT/UHT metamorphism during prolonged Archean orogenesis in the Pikwitonei Granulite Domain revealed by garnet petrochronology

NASA Astrophysics Data System (ADS)

Dragovic, Besim; Guevara, Victor; Caddick, Mark; Couëslan, Chris; Baxter, Ethan

2017-04-01

Fundamental to every modern continent's early (Archean) history is the generation of high temperature conditions required to produce the dense, strong, relatively anhydrous rocks that comprise most of Earth's stable cratonic crust. While the thermal gradients supported in Archean terranes are better understood, the timescales over which these conditions occur are more enigmatic. Garnet petrochronology allows for the interrogation of a semi-continuous record of these tectonometamorphic conditions, by linking pressure-temperature-fluid conditions (using phase equilibria modeling, trace element thermometry, stable isotope geochemistry) to a precise chronologic/chronometric record (e.g. high-precision Sm-Nd geochronology, geospeedometry of major and trace element diffusion profiles). Here, we utilize techniques from this burgeoning field of study to elucidate the rates and conditions of high temperature/ultra-high temperature (HT/UHT) metamorphism in the 2.7 Ga Pikwitonei Granulite Domain (PGD). The PGD represents over 150,000 km2 of dominantly granulite-facies metamorphic rocks situated at the NW edge of the Superior Province. Peak temperatures in the region range from 760°C in the southernmost part of the PGD, to 900-960˚C in the central/western PGD ( 40-60 km apart). Previous studies have suggested that metamorphism was long-lived in the region, occurring over 100 Ma, from 2.71-2.60 Ga [1, 2, 3]. High-precision garnet geochronology on microsampled garnets provides a detailed growth history of several lithologies across the region. Where necessary, bulk garnet analysis (i.e. dating based upon multiple whole garnet crystals rather than portions thereof) was also performed. While cooling from HT/UHT will result in some degree of intra-mineral age resetting, a detailed isotopic study of a range of large garnet porphyroblasts from the PGD (those which would be variably reset depending on peak T, grain size, and initial cooling rate) can retain information about both

Experimental Investigation of Magnetic Superconducting and other Phase Transitions in Novel f-Electron Materials at Ultra-high Pressures using Designer Diamond Anvils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maple, M. Brian; Jeffries, Jason R.; Ho, Pei-Chun

Pressure is often used as a controlled parameter for the investigation of condensed matter systems. In particular, pressure experiments can provide valuable information into the nature of superconductivity, magnetism, and the coexistence of these two phenomena. Some f-electron, heavy-fermion materials display interesting and novel behavior at moderately low pressures achievable with conventional experimental techniques; however, a growing number of condensed matter systems require ultrahigh pressure techniques, techniques that generate significantly higher pressures than conventional methods, to sufficiently explore their important properties. To that end, we have been funded to develop an ultrahigh pressure diamond anvil cell facility at the Universitymore » of California, San Diego (UCSD) in order to investigate superconductivity, magnetism, non-Fermi liquid behavior, and other phenomena. Our goals for the first year of this grant were as follows: (a) set up and test a suitable refrigerator; (b) set up a laser and spectrometer fluorescence system to determine the pressure within the diamond anvil cell; (c) perform initial resistivity measurements at moderate pressures from room temperature to liquid helium temperatures ({approx}1K); (d) investigate f-electron materials within our current pressure capabilities to find candidate materials for high-pressure studies. During the past year, we have ordered almost all the components required to set up a diamond anvil cell facility at UCSD, we have received and implemented many of the components that have been ordered, we have performed low pressure research on several materials, and we have engaged in a collaborative effort with Sam Weir at Lawrence Livermore National Lab (LLNL) to investigate Au4V under ultrahigh pressure in a designer diamond anvil cell (dDAC). This report serves to highlight the progress we have made towards developing an ultrahigh pressure research facility at UCSD, the research performed in the

Geophysical interpretation of the gneiss terrane of northern Washington and southern British Columbia, and its implications for uranium exploration

USGS Publications Warehouse

Cady, John W.; Fox, Kenneth F.

1984-01-01

The Omineca crystalline belt of northeastern Washington and southern British Columbia has a regional Bouguer gravity high, and individual gneiss domes within the terrane are marked by local gravity highs. Models of crustal structure that satisfy the limited available seismic-refraction data and explain the gravity high over the gneiss terrane permit the hypothesis that the core metamorphic complexes are the surface expression of a zone of dense infrastructure that makes up the upper 20 km (kilometers) of the crust within the crystalline belt. The Omineca crystalline belt is characterized regionally by low aeromagnetic relief. The gneiss domes and biotite- and biotite-muscovite granites are generally marked by low magnetic relief, whereas hornblende-biotite granites often cause magnetic highs. Exceptional magnetic highs mark zones of magnetic rock within the biotite- and biotite-muscovite granites and the gneiss domes; these areas are worthy of study, both to determine the origin and disposition of the magnetite and to explore the possible existence of uraniferous magnetite deposits.

[sup 40]Ar/[sup 39]Ar mineral ages from southwestern Penobscot Bay, Maine: Evidence for Silurian metamorphism

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, D.P. Jr.; Guidotti, C.V.; Lux, D.R.

1992-01-01

The nature and timing of metamorphic events in the Coastal Lithotectonic Block of Maine remain poorly understood. Immediately west and southwest of Penobscot Bay the rocks are polymetamorphic showing evidence for at least two episodes of amphibolite facies metamorphism and later, perhaps regionally extensive, retrograde events. Hornblende mineral separates from two amphibolites din the Port Clyde area have identical Ar-40/Ar-39 plateau ages of 414.0 [+-] 3.3 and 414.0 [+-] 3.9 Ma. These ages are interpreted to reflect the time of cooling following the last significant thermal event in this area. Biotite from an amphibolite in the Port Clyde area givesmore » a total gas age of 346.5 [+-] 3.2 Ma. Hornblende from an amphibolite 7 km to the west near Friendship gives a nearly concordant release spectrum with a plateau age of 369.0 [+-] 3.7 Ma. Coexisting biotite from this amphibolite gives a total gas age of 289.2 [+-] 2.7 Ma. Muscovite from the Waldoboro pluton has a nearly concordant release spectrum with a plateau age of 306.3 [+-] 2.2 Ma. Biotite from this sample gives a total gas age of 288.9 [+-] 2.2 Ma. The 414.0 Ma hornblende cooling ages from the Port Clyde area reflect cooling following a significant high grade Silurian thermal event. This Silurian metamorphism is the same age as tectonothermal events in the Nashoba Terrane in eastern Massachusetts, the Kingston Complex in southern New Brunswick, the Aspy Terrane in Cape Breton island, Nova Scotia, and the Hermitage Flexure in southern Newfoundland.d Thus a distinctive Silurian tectonothermal province located along the western edge of the Avalon Zone appears to extend discontinuously from Massachusetts to Newfoundland.« less

Exotic island arc Paleozoic terranes on the eastern margin of Gondwana: Geochemical whole rock and zircon U-Pb-Hf isotope evidence from Barry Station, New South Wales, Australia

NASA Astrophysics Data System (ADS)

Manton, Ryan J.; Buckman, Solomon; Nutman, Allen P.; Bennett, Vickie C.

2017-08-01

Early Paleozoic intra-oceanic terranes crop out along the Peel-Manning Fault System, in the southern New England Orogen, NSW Australia. These are the Cambrian ophiolitic Weraerai terrane and the Siluro-Devonian island arc Gamilaroi terrane. There has been debate whether these terranes formed at the Gondwana margin or if they are intra-oceanic, and were accreted to Gondwana later in the Paleozoic. Major-trace-REE elemental data indicate Weraerai terrane formed in a supra-subduction environment. Rare zircons extracted from Weraerai terrane gabbro-plagiogranite suites at Barry Station yield a U-Pb zircon date of 504.9 ± 3.5 Ma with initial εHf values of + 11.1 indicating a juvenile source. Amphibole-bearing felsic dykes and net-vein complexes are also found within the gabbro with a U-Pb zircon date of 503.2 ± 5.7 Ma and initial εHf values of + 11.6. These are coeval in age with their host rocks and we propose they represent partial melts of the mafic crust during the circulation of seawater. The Gamilaroi trondhjemites of prehnite-pumpellyite-greenschist metamorphic grade terrane yielded very few zircons with an age of 413 ± 8.7 Ma. Zircon initial εHf values range from + 5.0 to + 2.9, indicating an input from an evolved crustal source, unlike the purely oceanic Weraerai terrane. Gamilaroi terrane trondhjemites are enriched in LREE have low K2O and K2O/Na2O ratios and strong negative Nb anomalies consistent with supra-subduction zone environments. Multiple subduction zones may well have existed within the Panthalassa Ocean during the early-mid Paleozoic with the Weraerai-Gamilaroi being accreted onto the Gondwanan margin during the latest Devonian.

Oman metamorphic sole formation reveals early subduction dynamics

NASA Astrophysics Data System (ADS)

Soret, Mathieu; Agard, Philippe; Dubacq, Benoît; Plunder, Alexis; Ildefonse, Benoît; Yamato, Philippe; Prigent, Cécile

2016-04-01

Metamorphic soles correspond to m to ~500m thick tectonic slices welded beneath most of the large-scale ophiolites. They typically show a steep inverted metamorphic structure where the pressure and temperature conditions of crystallization increase upward (from 500±100°C at 0.5±0.2 GPa to 800±100°C at 1.0±0.2 GPa), with isograds subparallel to the contact with the overlying ophiolitic peridotite. The proportion of mafic rocks in metamorphic soles also increases from the bottom (meta-sediments rich) to the top (approaching the ophiolite peridotites). These soles are interpreted as the result of heat transfer from the incipient mantle wedge toward the nascent slab (associated with large-scale fluid transfer and possible shear heating) during the first My of intra-oceanic subduction (as indicated by radiometric ages). Metamorphic soles provide therefore major constraints on early subduction dynamics (i.e., thermal structure, fluid migration and rheology along the nascent slab interface). We present a detailed structural and petrological study of the metamorphic sole from 4 major cross-sections along the Oman ophiolite. We show precise pressure-temperature estimates obtained by pseudosection modelling and EBSD measurements performed on both the garnet-bearing and garnet-free high-grade sole. Results allow quantification of the micro-scale deformation and highlight differences in pressure-temperature-deformation conditions between the 4 different locations, showing that the inverted metamorphic gradient through the sole is not continuous in all locations. Based on these new constraints, we suggest a new tectonic-petrological model for the formation of metamorphic soles below ophiolites. This model involves the stacking of several homogeneous slivers of oceanic crust leading to the present-day structure of the sole. In this view, these thrusts are the result of rheological contrasts between the sole and the peridotite as the plate interface progressively cools down

Metamorphic reprocessing of a serpentinized carbonate-bearing peridotite after detachment from the mantle wedge: A P-T path constrained from textures and phase diagrams in the system CaO-MgO-Al 2O 3-SiO 2-CO 2-H 2O

NASA Astrophysics Data System (ADS)

Mposkos, E.; Baziotis, I.; Proyer, A.

2010-08-01

In the central Rhodope mountains of Greece a carbonate-bearing metaperidotite lens ˜ 200 × 500 m in size crops out as part of the high- to ultrahigh-pressure metamorphic Upper Sidironero Complex ˜ 500 m SE of the Gorgona Village, north of Xanthi town. It is composed primarily of coarse grained (3-20 mm in size) olivine and orthopyroxene, medium grained clinohumite and medium to fine grained tremolite, chlorite, dolomite, magnesite, talc, antigorite and various spinel phases. Whole-rock chemistry, mineral textures and compositions, and phase diagram calculations show that the metaperidotite was subjected to a prograde HP metamorphism, isofacial with the surrounding migmatitic gneisses, metapelites and amphibolites. The prograde character of metamorphism is demonstrated by inclusions of talc, antigorite, chlorite, dolomite, magnesite and Ti-clinohumite in ferrit-chromite, olivine, and orthopyroxene, as well as of olivine in orthopyroxene, and by the typical change in composition of zoned spinel minerals from ferrit-chromite in the core to chromian spinel at the rim. The prograde path is characterized by successive growth of amphibole, Ti-clinohumite, olivine and orthopyroxene, followed by the breakdown of Ti-clinohumite to olivine + Mg-ilmenite and of chlorite to olivine + spinel, probably during exhumation. The construction of a partial petrogenetic P- T grid in the system CaO-MgO-Al 2O 3-SiO 2-CO 2-H 2O (CMASCH) for Ca-poor ultramafic bulk compositions has proven highly useful for the reconstruction of the metamorphic evolution and a P- T path, indicating that the use of univariant reactions in mixed volatile systems is highly warranted. The P- T path is clearly constrained to pressures below 1.5-1.7 GPa by the absence of clinopyroxene. These pressures are slightly lower than those recorded in the closely associated Jurassic eclogites and much lower than those recorded in the diamond-bearing gneisses 5 km to the south in the same tectonic unit. The carbonate

Orogenesis, high-T thermal events, and gold vein formation within metamorphic rocks of the Alaskan Cordillera

USGS Publications Warehouse

Goldfarb, R.J.; Snee, L.W.; Pickthorn, W.J.

1993-01-01

Mesothermal, gold-bearing quartz veins are widespread within allochthonous terranes of Alaska that are composed dominantly of greenschist-facies metasedimentary rocks. The most productive lode deposits are concentrated in south-central and southeastern Alaska; small and generally nonproductive gold-bearing veins occur upstream from major placer deposits in interior and northern Alaska. Ore-forming fluids in all areas are consistent with derivation from metamorphic devolatilisation reactions, and a close temporal relationship exists between high-T tectonic deformation, igneous activity, and gold mineralization. Ore fluids were of consistently low salinity, CO2-rich, and had ??18O values of 7 ???-12??? and ??D values between -15??? and -35???. Upper-crustal temperatures within the metamorphosed terranes reached at least 450-500??C before onset of significant gold-forming hydrothermal activity. In southern Alaska, gold deposits formed during latter stages of Tertiary, subduction-related, collisional orogenesis and were often temporally coeval with calc-alkaline magmatism. -from Authors

Atmospheric Ar and Ne returned from mantle depths to the Earth's surface by forearc recycling.

PubMed

Baldwin, Suzanne L; Das, J P

2015-11-17

In subduction zones, sediments, hydrothermally altered lithosphere, fluids, and atmospheric gases are transported into the mantle, where ultrahigh-pressure (UHP) metamorphism takes place. However, the extent to which atmospheric noble gases are trapped in minerals crystallized during UHP metamorphism is unknown. We measured Ar and Ne trapped in phengite and omphacite from the youngest known UHP terrane on Earth to determine the composition of Ar and Ne returned from mantle depths to the surface by forearc recycling. An (40)Ar/(39)Ar age [7.93 ± 0.10 My (1σ)] for phengite is interpreted as the timing of crystallization at mantle depths and indicates that (40)Ar/(39)Ar phengite ages reliably record the timing of UHP metamorphism. Both phengite and omphacite yielded atmospheric (38)Ar/(36)Ar and (20)Ne/(22)Ne. Our study provides the first documentation, to our knowledge, of entrapment of atmospheric Ar and Ne in phengite and omphacite. Results indicate that a subduction barrier for atmospheric-derived noble gases does not exist at mantle depths associated with UHP metamorphism. We show that the crystallization age together with the isotopic composition of nonradiogenic noble gases trapped in minerals formed during subsolidus crystallization at mantle depths can be used to unambiguously assess forearc recycling of atmospheric noble gases. The flux of atmospheric noble gas entering the deep Earth through subduction and returning to the surface cannot be fully realized until the abundances of atmospheric noble gases trapped in exhumed UHP rocks are known.

Metamorphic core complexes: Expression of crustal extension by ductile-brittle shearing of the geologic column

NASA Technical Reports Server (NTRS)

Davis, G. H.

1985-01-01

Metamorphic core complexes and detachment fault terranes in the American Southwest are products of stretching of continental crust in the Tertiary. The physical and geometric properties of the structures, fault rocks, and contact relationships that developed as a consequence of the extension are especially well displayed in southeastern Arizona. The structures and fault rocks, as a system, reflect a ductile-through-brittle continuum of deformation, with individual structures and faults rocks showing remarkably coordinated strain and displacement patterns. Careful mapping and analysis of the structural system has led to the realization that strain and displacement were partitioned across a host of structures, through a spectrum of scales, in rocks of progressively changing rheology. By integrating observations made in different parts of the extensional system, especially at different inferred depth levels, it has been possible to construct a descriptive/kinematic model of the progressive deformation that achieved continental crustal extension in general, and the development of metamorphic core complexes in particular.

An Evaluation of Ultra-High Pressure Regulator for Robotic Lunar Landing Spacecraft

NASA Technical Reports Server (NTRS)

Burnside, Christopher; Trinh, Huu; Pedersen, Kevin

2011-01-01

The Robotic Lunar Lander Development (RLLD) Project Office at NASA Marshall Space Flight Center (MSFC) has studied several lunar surface science mission concepts. These missions focus on spacecraft carrying multiple science instruments and power systems that will allow extended operations on the lunar surface. Initial trade studies of launch vehicle options for these mission concepts indicate that the spacecraft design will be significantly mass-constrained. To minimize mass and facilitate efficient packaging, the notional propulsion system for these landers has a baseline of an ultra-high pressure (10,000 psig) helium pressurization system that has been used on Defense missiles. The qualified regulator is capable of short duration use; however, the hardware has not been previously tested at NASA spacecraft requirements with longer duration. Hence, technical risks exist in using this missile-based propulsion component for spacecraft applications. A 10,000-psig helium pressure regulator test activity is being carried out as part of risk reduction testing for MSFC RLLD project. The goal of the test activity is to assess the feasibility of commercial off-the-shelf ultra-high pressure regulator by testing with a representative flight mission profile. Slam-start, gas blowdown, water expulsion, lock-up, and leak tests are also performed on the regulator to assess performance under various operating conditions. The preliminary test results indicated that the regulator can regulate helium to a stable outlet pressure of 740 psig within the +/- 5% tolerance band and maintain a lock-up pressure less than +5% for all tests conducted. Numerous leak tests demonstrated leakage less than 10-3 standard cubic centimeters per second (SCCS) for internal seat leakage at lock-up and less than10-5 SCCS for external leakage through the regulator ambient reference cavity. The successful tests have shown the potential for 10,000 psig helium systems in NASA spacecraft and have reduced risk

Microstructural evidence for dissolution precipitation creep in high pressure metamorphic serpentinites from subduction zones

NASA Astrophysics Data System (ADS)

Wassmann, S.; Trepmann, C.; Krohe, A.; Stoeckhert, B.

2009-12-01

Serpentinite is generally believed to constitute weak material in subduction zones and to play an essential role for the development of a subduction channel. Information on deformation mechanisms and appropriate rheological models to describe these large scale flow processes is obtained from natural serpentinites exhumed from ancient subduction zones. In this study, we investigate the microstructural record of serpentinites exposed in the Zermatt-Saas-Zone, Western Alps. The metamorphic mineral assemblage comprises antigorite, forsterite, diopside, tremolite, chlorite, oxide phases, and in places titanclinohumite. Original mantle minerals are only locally preserved as relics. The conditions of Alpine metamorphism can be estimated from associated eclogites; the pressures are mostly between 1.5 and 2.5 GPa at temperatures of c. 500-600°C. The serpentinites show a complex structure with several generations of folds and foliations. An early foliation is defined by the combined shape and crystallographic preferred orientation (SPO and CPO) of antigorite and metamorphic diopside. These patterns are undistinguishable from the SPO and CPO of the same minerals in strain shadows, where the CPO must be developed by oriented growth from an aqueous solution. Therefore we suspect that the SPO and CPO in the polyphase matrix layers also result from oriented growth. Also, there is no microstructural evidence for any crystal plastic deformation of diopside. In places, antigorite flakes with SPO and CPO are overgrown by single crystals or aggregates of metamorphic forsterite, locally titanoclinohumite, and tremolite. The aggregates of forsterite exhibit a foam structure without CPO. All microfabrics indicate that dissolution precipitation creep was predominant in the investigated serpentinites, and most finite strain was accumulated by this mechanism. We see no evidence for a significant contribution of dislocation creep, both based on microstructure and on the CPO patterns. This

Development and application of laser microprobe techniques for oxygen isotope analysis of silicates, and, fluid/rock interaction during and after granulite-facies metamorphism, highland southwestern complex, Sri Lanka

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elsenheimer, D.W.

1992-01-01

The extent of fluid/rock interaction within the crust is a function of crustal depth, with large hydrothermal systems common in the brittle, hydrostatically pressured upper crust, but restricted fluid flow in the lithostatically pressured lower crust. To quantify this fluid/rock interaction, a Nd-YAG/CO[sub 2] laser microprobe system was constructed to analyze oxygen isotope ratios in silicates. Developed protocols produce high precision in [sigma][sup 18]O ([+-]0.2, 1[sigma]) and accuracy comparable to conventional extraction techniques on samples of feldspar and quartz as small as 0.3mg. Analysis of sub-millimeter domains in quartz and feldspar in granite from the Isle of Skye, Scotland, revealsmore » complex intragranular zonation. Contrasting heterogeneous and homogeneous [sigma][sup 18]O zonation patterns are revealed in samples <10m apart. These differences suggest fluid flow and isotopic exchange was highly heterogeneous. It has been proposed that granulite-facies metamorphism in the Highland Southwestern Complex (HSWC), Sri Lanka, resulted from the pervasive influx of CO[sub 2], with the marbles and calc-silicates within the HSWC a proposed fluid source. The petrologic and stable isotopic characteristic of HSWC marbles are inconsistent with extensive decarbonation. Wollastonite calc-silicates occur as deformed bands and as post-metamorphis veins with isotopic compositions that suggest vein fluids that are at least in part magmatic. Post-metamorphic magmatic activity is responsible for the formation of secondary disseminated graphite growth in the HSWC. This graphite has magmatic isotopic compositions and is associated with vein graphite and amphibolite-granulite facies transitions zones. Similar features in Kerela Khondalite Belt, South India, may suggest a common metamorphic history for the two terranes.« less

On the role of horizontal displacements in the exhumation of high pressure metamorphic rocks

NASA Astrophysics Data System (ADS)

Brun, J.-P.; Tirel, C.; Philippon, M.; Burov, E.; Faccenna, C.; Gueydan, F.; Lebedev, S.

2012-04-01

High pressure metamorphic rocks exposed in the core of many mountain belts correspond to various types of upper crustal materials that have been buried to mantle depths and, soon after, brought back to surface at mean displacement rates up to few cm/y, comparable to those of plate boundaries. The vertical component of HP rock exhumation velocity back to surface is commonly well constrained by pressure estimates from petrology and geochronological data whereas the horizontal component remains generally difficult or impossible to estimate. Consequently, most available models, if not all, attempt to simulate exhumation with a minimal horizontal component of displacement. Such models, require that the viscosity of HP rocks is low and/or the erosion rate large -i.e. at least equal to the rate of exhumation. However, in some regions like the Aegean, where the exhumation of blueschists and eclogites is driven by slab rollback, it can be shown that the horizontal component of exhumation related displacement, obtained from map view restoration, is 5 to 7 times larger than the vertical one, deduced from metamorphic pressure estimates. Using finite element models performed with FLAMAR, we show that such a situation simply results from the subduction of small continental blocks (< 500km) that stimulate subduction rollback. The continental block is dragged downward and sheared off the downgoing mantle slab by buoyancy force. Exhumation of the crustal block occurs through a one step Caterpillar-type walk, with the block's tail slipping along a basal décollement, approaching the head and making a large buckle, which then unrolls at surface as soon as the entire block is delaminated. Finally, the crustal block emplaces at surface in the space created by trench retreat. This process of exhumation requires neither rheological weakening of HP rocks nor high rates of erosion.

The metamorphic sole of New Caledonia ophiolite: 40Ar/39Ar, U-Pb, and geochemical evidence for subduction inception at a spreading ridge

NASA Astrophysics Data System (ADS)

Cluzel, Dominique; Jourdan, Fred; Meffre, SéBastien; Maurizot, Pierre; Lesimple, StéPhane

2012-06-01

Amphibolite lenses that locally crop out below the serpentinite sole at the base of the ophiolite of New Caledonia (termed Peridotite Nappe) recrystallized in the high-temperature amphibolite facies and thus sharply contrast with blueschists and eclogites of the Eocene metamorphic complex. Amphibolites mostly display the geochemical features of MORB with a slight Nb depletion and thus are similar to the youngest (Late Paleocene-Eocene) BABB components of the allochthonous Poya Terrane. Thermochronological data from hornblende (40Ar/39Ar), zircon, and sphene (U-Pb) suggest that these mafic rocks recrystallized at ˜56 Ma. Using various geothermobarometers provides a rough estimate of peak recrystallization conditions of ˜0.5 GPa at ˜800-950°C. The thermal gradient inferred from the metamorphic assemblage (˜60°C km-1), geometrical relationships, and geochemical similarity suggest that these mafic rocks belong to the oceanic crust of the lower plate of the subduction/obduction system and recrystallized when they subducted below young and hot oceanic lithosphere. They were detached from the down-going plate and finally thrust onto unmetamorphosed Poya Terrane basalts. This and the occurrence of slab melts at ˜53 Ma suggest that subduction inception occurred at or near to the spreading ridge of the South Loyalty Basin at ˜56 Ma.

Contrasting styles of sedimentation and deformation in the Chugach Terrane accretionary complex, south-central Alaska

NASA Astrophysics Data System (ADS)

Amato, J. M.; Pavlis, T. L.; Worthman, C.; Kochelek, E.; Day, E. M.; Clift, P. D.; Hecker, J.

2011-12-01

In southeast Alaska the Chugach terrane represents an accretionary complex associated with several arcs active at 200-65 Ma. This lithostratigraphic unit consists of blueschists with Early Jurassic metamorphic ages and uncertain depositional ages; the Jurassic-Cretaceous McHugh Complex; and the Late Cretaceous Valdez Group. Detrital zircon ages from densely sampled transects reveals patterns in the assembly of the complex. Blueschists are almost totally barren of zircon, suggesting protoliths derived from mafic-intermediate volcanic protoliths far from a continental source. There is an age gap between the blueschists and the McHugh complex interpreted to be caused by an episode of tectonic erosion. The McHugh Complex is two separate units that are lithologically and geochronologically distinct. The older McHugh is a melange is dominated by stratally disrupted volcanic rocks, chert, and argillite. The oldest McHugh rocks have maximum depositional ages (MDA) of 177-150 Ma at Seldovia and 157-145 Ma at Turnagain Arm; the lack of older rocks at Turnagain Arm suggests removal of structural section by faulting. The MDAs of the older McHugh rocks do not decrease progressively away from the arc. There is a 45 m.y. gap in MDA between the older McHugh and the Late Cretaceous McHugh rocks. The younger McHugh rocks are dominated by volcanogenic sandstone and coarse conglomerate and MDA decreases from 100 Ma near the boundary with the older McHugh mesomelange to 85 Ma near the Valdez Group. The Valdez Group consists of coherently bedded turbidites with a MDA range of 85-60 Ma that decreases progressively outboard of the arc source. A sample from the Orca Group of the Prince William terrane is lithologically similar to the Valdez Group and there is no gap in MDA between Valdez and Orca Groups. 55 Ma dikes cut the McHugh and Valdez Groups in the western Chugach and Kenai Mountains. The oldest units of the Chugach terrane are the most deformed, with deformation and metamorphism

U-Pb SHRIMP geochronology and trace-element geochemistry of coesite-bearing zircons, North-East Greenland Caledonides

USGS Publications Warehouse

McClelland, W.C.; Power, S.E.; Gilotti, J.A.; Mazdab, F.K.; Wopenka, B.

2006-01-01

Obtaining reliable estimates for the timing of eclogite-facies metamorphism is critical to establishing models for the formation and exhumation of high-pressure and ultrahigh-pressure (UHP) metamorphic terranes in collisional orogens. The presence of pressure-dependent phases, such as coesite, included in metamorphic zircon is generally regarded as evidence that zircon growth occurred at UHP conditions and, ifdated, should provide the necessary timing information. We report U-Pb sensitive high-resolution ion microprobe (SHRIMP) ages and trace-element SHRIMP data from coesite-bearing zircon suites formed during UHP metamorphism in the North- East Greenland Caledonides. Kyanite eclogite and quartzofeldspathic host gneiss samples from an island in J??kelbugt (78??00'N, 18??04'W) contained subspherical zircons with well-defined domains in cathodoluminescence (CL) images. The presence of coesite is confirmed by Raman spectroscopy in six zircons from four samples. Additional components of the eclogite-facies inclusion suite include kyanite, omphacite, garnet, and rutile. The trace-element signatures in core domains reflect modification of igneous protolith zircon. Rim signatures show flat heavy rare earth element (HREE) patterns that are characteristic of eclogite-facies zircon. The kyanite eclogites generally lack a Eu anomaly, whereas a negative Eu anomaly persists in all domains of the host gneiss. The 207Pb- corrected 206Pb/238U ages range from 330 to 390 Ma for the host gneiss and 330-370 Ma for the kyanite eclogite. Weighted mean 206Pb/238U ages for coesite-bearing domains vary from 364 ?? 8 Ma for the host gneiss to 350 ?? 4 Ma for kyanite eclogite. The combined U-Pb and REE data interpreted in conjunction with observed CL domains and inclusion suites suggest that (1) Caledonian metamorphic zircon formed by both new zircon growth and recrystallization, (2) UHP metamorphism occurred near the end of the Caledonian collision, and (3) the 30-50m.y. span of ages

Metamorphism within the Chugach accretionary complex on southern Baranof Island, southeastern Alaska

USGS Publications Warehouse

Zumsteg, Cathy L.; Himmelberg, Glen R.; Karl, Susan M.; Haeussler, Peter J.

2003-01-01

On Baranof Island, southeastern Alaska, we identify four metamorphic events that affect rocks associated with the Chugach accretionary complex. This study focuses on the M1 and M4 metamorphic events. Mesozoic schists, gneisses, and migmatitic gneisses exposed near the Kasnyku pluton on central Baranof Island represent the M1 metamorphic rocks. These rocks underwent amphibolite facies metamorphism. Calculated temperatures and pressures range from about 620 to 780 ºC and 5.5 to 6.6 kbar and are compatible with the observed metamorphic mineral assemblages.The M4 metamorphism affected rocks of the Sitka Graywacke on southern Baranof Island, producing extensive biotite and garnet zones as well as andalusite and sillimanite zones at the contacts of the Crawfish Inlet and Redfish Bay plutons. Calculated M4 temperatures and pressures from the andalusite and sillimanite zones range from 575 to 755 ºC and 3.4 to 6.9 kbar. These results fall within the sillimanite stability field, at pressures higher than andalusite stability. These results may indicate the M4 metamorphic event occurred along a P-T path along which the equilibration of aluminosilicate-garnet-plagioclase-quartz did not occur or was not maintained. This interpretation is supported by the occurrence of andalusite and sillimanite within the same sample. We propose the data reflect a clockwise P-T path with peak M4 metamorphism of the sillimanite-bearing samples adjacent to the intrusions at an approximate depth of 15 to 20 km, followed by rapid uplift without reequilibration of garnet-plagioclase-aluminosilicate-quartz.The large extent of the biotite zone, and possibly the garnet zone, suggests that an additional heat source must have existed to regionally metamorphose these rocks during the M4 event. We suggest the M4 regional thermal metamorphism and intrusion of the Crawfish Inlet and Redfish Bay plutons were synchronous and the result of heat flux from a slab window beneath the accretionary complex at that

Gold deposits in metamorphic belts: Overview of current understanding, outstanding problems, future research, and exploration significance

USGS Publications Warehouse

Groves, D.I.; Goldfarb, R.J.; Robert, F.; Hart, C.J.R.

2003-01-01

Metamorphic belts are complex regions where accretion or collision has added to, or thickened, continental crust. Gold-rich deposits can be formed at all stages of orogen evolution, so that evolving metamorphic belts contain diverse gold deposit types that may be juxtaposed or overprint each other. This partly explains the high level of controversy on the origin of some deposit types, particularly those formed or overprinted/remobilized during the major compressional orogeny that shaped the final geometry of the hosting metamorphic belts. These include gold-dominated orogenic and intrusion-related deposits, but also particularly controversial gold deposits with atypical metal associations. There are a number of outstanding problems for all types of gold deposits in metamorphc belts. These include the following: (1) definitive classifications, (2) unequivocal recognition of fluid and metal sources, (3) understanding of fluid migration and focusing at all scales, (4) resolution of the precise role of granitoid magmatism, (5) precise gold-depositional mechanisms, particularly those producing high gold grades, and (6) understanding of the release of CO2-rich fluids from subducting slabs and subcreted oceanic crust and granitoid magmas at different crustal levels. Research needs to be better coordinated and more integrated, such that detailed fluid-inclusion, trace-element, and isotopic studies of both gold deposits and potential source rocks, using cutting-edge technology, are embedded in a firm geological framework at terrane to deposit scales. Ultimately, four-dimensional models need to be developed, involving high-quality, three-dimensional geological data combined with integrated chemical and fluid-flow modeling, to understand the total history of the hydrothermal systems involved. Such research, particularly that which can predict superior targets visible in data sets available to exploration companies before discovery, has obvious spin-offs for global- to deposit

Circum-North Pacific tectonostratigraphic terrane map

USGS Publications Warehouse

Nokleberg, Warren J.; Parfenov, Leonid M.; Monger, James W.H.; Baranov, Boris B.; Byalobzhesky, Stanislav G.; Bundtzen, Thomas K.; Feeney, Tracey D.; Fujita, Kazuya; Gordey, Steven P.; Grantz, Arthur; Khanchuk, Alexander I.; Natal'in, Boris A.; Natapov, Lev M.; Norton, Ian O.; Patton, William W.; Plafker, George; Scholl, David W.; Sokolov, Sergei D.; Sosunov, Gleb M.; Stone, David B.; Tabor, Rowland W.; Tsukanov, Nickolai V.; Vallier, Tracy L.; Wakita, Koji

1994-01-01

after accretion of most terranes in the region; (2) Cenozoic and Mesozoic basinal deposits that occur within a terrane or on the craton; (3) plutonic rocks. The postaccretion igneous units are identified by age-lithologic abbreviations and by name. These overlap assemblages and basinal deposits formed mainly during sedimentation and magmatism that occurred after accretion of terranes to each other or to a continental margin. Overlap assemblages provide minimum ages on the timing of accretion of terranes. Some Cenozoic and Mesozoic overlap assemblages and basinal deposits, as well as fragments of terranes, are extensively offset by movement along postaccretion faults. In addition, in onshore areas, the map depicts major preaccretion plutonic rocks that are limited to individual terranes. and in offshore areas. the map depicts major oceanic plates,-ocean floor magnetic lineations. oceanic spreading ridges, and seamounts. The map consists of five sheets. Sheets I and 2 depict, at a scale of I :5.000.000. the tectonostratigraphic terranes. preaccretion plutonic rocks, and postaccretion Cenozoic and Mesozoic overlap sedimentary, volcanic. and plutonic assemblages, and basinal deposits for the Circum- orth Pacific including the Russian Far East, northern Hokkaido Island of Japan, Alaska. the Canadian Cordillera, part of the U.S.A. Pacific Northwest. and adjacent offshore areas. Sheet 3 provides the list of map units for Sheets I and 2. Sheet 4 is a index map showing generalized onshore terranes and overlap assemblages for onshore parts of the Circum-North Pacific at a scale of I: I 0,000,000. Sheet 4 is a guide to the more complicated onshore features depicted on Sheets I and 2. Sheet 5 is an index map showing the major geographic regions for the Circum-North Pacific. Significant differences exist between the representation of onshore and offshore geology on Sheets I and 2. These are: (I) compared to the onshore part of the map, the offshore part is depicted in a more

Ar-Ar and Rb-Sr dating of very low-/low-grade metamorphism along the main Iapetus suture, Newfoundland

NASA Astrophysics Data System (ADS)

Willner, Arne P.; Glodny, Johannes; Massonne, Hans-Joachim; Romer, Rolf L.; Sudo, Masafumi; Van Staal, Cees R.; Zagorevski, Alexandre

2013-04-01

The Late Ordovician closure of the main tract of Iapetus resulted in juxtaposition of the leading edge of the peri-Gondwanan microplate Ganderia and the composite Laurentian margin. The suture is the Red Indian Line, which separates the Iapetan realm into peri-Gondwanan and peri-Laurentian arc-backarc complexes. The discrete Red Indian Line forms part of a wider collision zone that has a protracted and complicated tectonic history starting with underplating of oceanic terranes beneath the composite margin of Laurentia at ca. 471 Ma during the early stages of the Taconic orogeny. Final collision along the Red Indian Line and closure of the Iapetus ocean occurred at 455 Ma with the underthrusting of the peri-Gondwanan Victoria arc and its Ganderian basement beneath the composite Laurentian margin. The accreted Iapetan realm terranes were progressively deformed during the closure of a remaining Iapetan marginal basin, resulting locally in significant overprint and reactivation during the Silurian (Salinic orogeny). Metamorphic overprint in the deformed Laurentia margin (Notre Dame Zone) above the Red Indian Line is mainly of very low grade to low grade and very heterogeneous. PT-conditions cluster at 3-5 kbar, 300-400°C and 6-7 kbar, 270-330°C. Medium grade conditions are related to local contact metamorphism. Ages of the local peak metamorphism in the peri-Laurentian Iapetan realm were determined by dating white mica with the Ar-Ar system and white mica-bearing assemblages with the Rb-Sr mineral isochron method. Both methods yielded ages that postdate the closure of the main tract of Iapetus. These generally belong to two age ranges: 418-430 Ma (Salinic events) and 350-390 Ma Neoacadian events). Partly two overprints can be detected in one and the same sample. Metamorphism is related to (1) reactivation of deformation in shear zones which partly cause further crustal thickening or strike slip-related deformation, (2) to external fluid influx, (3) to advective

Tertiary plate tectonics and high-pressure metamorphism in New Caledonia

USGS Publications Warehouse

Brothers, R.N.; Blake, M.C.

1973-01-01

The sialic basement of New Caledonia is a Permian-Jurassic greywacke sequence which was folded and metamorphosed to prehnite-pumpellyite or low-grade greenschist facies by the Late Jurassic. Succeeding Cretaceous-Eocene sediments unconformably overlie this basement and extend outwards onto oceanic crust. Tertiary tectonism occurred in three distinct phases. 1. (1) During the Late Eocene a nappe of peridotite was obducted onto southern New Caledonia from northeast to southwest, but without causing significant metamorphism in the underlying sialic rocks. 2. (2) Oligocene compressive thrust tectonics in the northern part of the island accompanied a major east-west subduction zone, at least 30 km wide, which is identified by an imbricate system of tectonically intruded melanges and by development of lawsonite-bearing assemblages in adjacent country rocks; this high-pressure mineralogy constituted a primary metamorphism for the Cretaceous-Eocene sedimentary pile, but was overprinted on the Mesozoic prehnite-pumpellyite metagreywackes. 3. (3) Post-Oligocene transcurrent faulting along a northwest-southeast line (the sillon) parallel to the west coast caused at least 150 km of dextral offset of the southwest frontal margin of the Eocene ultramafic nappe. At the present time, the tectonics of the southwest Pacific are related to a series of opposite facing subduction (Benioff) zones connected by transform faults extending from New Britain-Solomon Islands south through the New Hebrides to New Zealand and marking the boundary between the Australian and Pacific plates. Available geologic data from this region suggest that a similar geometry existed during the Tertiary and that the microcontinents of New Guinea, New Caledonia and New Zealand all lay along the former plate boundary which has since migrated north and east by a complex process of sea-floor spreading behind the active island arcs. ?? 1973.

Kinematics of Post-Collisional Extensional Tectonics and Exhumation of the Menderes Massif in the Western Anatolia Extended Terrane, Turkey

NASA Astrophysics Data System (ADS)

Cemen, I.; Catlos, E. J.; Diniz, E.; Gogus, O.; Ozerdem, C.; Baker, C.; Kohn, M. J.; Goncuoglu, C.; Hancer, M.

2006-12-01

The Western Anatolia Extended Terrane in Turkey is one of the best-developed examples of post-collisional extended terranes and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene as the Neotethys Ocean closed and the Izmir-Ankara-Erzincan suture zone was formed. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive, uninterrupted stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal- slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alasehir and the south-dipping Buyuk Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alasehir, Buyuk

Prograde and retrograde metamorphic processes in high-pressure subduction zone serpentinites from East Thessaly, Greece

NASA Astrophysics Data System (ADS)

Koutsovitis, Petros

2016-04-01

The East Thessaly region, Central Greece, includes metaophiolitic mélange formations which extend from the eastern foothills of Mt. Olympus and Ossa, throughout the Agia basin, Mt. Mavrovouni (Sklithro region), South Pelion and reaching up to northeast Othris (regions of Aerino and Velestino). They appear in the form of dispersed and deformed thrust sheets having been variably emplaced onto Mesozoic platform series rocks of the Pelagonian tectonostratigraphic zone[1]. These formations consist mainly of serpentinites, as well as metasediments, metagabbros, metadolerites, rodingites, ophicalcites, talc-schists and chromitites. Based upon petrographic observations, mineral chemistry data and XRD patterns, the subduction zone-related serpentinites from the regions of Potamia, Anavra, Aetolofos and Kalochori-Chasanbali (Agia basin), as well as from the regions of Aerino and Velestino, are characterized by the progressive transformation of lizardite to antigorite and are distinguished into two groups. The first group includes serpentinites from the metaophiolitic formations of Potamia, Anavra, Aerino and Velestino, which are marked by destibillization of lizardite to antigorite, mostly along the grain boundaries of the lizardite mesh textured relics. The presence of lizardite and antigorite in almost equal amounts indicates medium-temperature blueschist facies metamorphic conditions (˜340-370 ° C; P≈10-11 kbar)[2,3,4]. The second serpentinite group appears in the regions of Aetolofos and Kalochori, characterized by the predominance of antigorite, the minor occurrence of lizardite and the complete replacement of spinel by Cr-magnetite. The absence of metamorphic olivine suggests that these serpentinites were most likely formed at slightly higher temperature and pressure conditions compared to the first serpentinite group, corresponding to medium or high temperature blueschist facies metamorphism (˜360-380 ° C; P≈12 kbar)[2,3,4]. These metamorphic conditions are

Kilbuck terrane: Oldest known rocks in Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Box, S.E.; Moll-Stalcup, E.J.; Wooden, J.L.

1990-12-01

The Kilbuck terrane in southwestern Alaska is a narrow, thin crustal sliver or flake of amphibolite facies orthogneiss. The igneous protolith of this gneiss was a suite of subduction-related plutonic rocks. U-Pb data on zircons from trondhjemitic and granitic samples yield upper-intercept (igneous) ages of 2,070 {plus minus}16 and 2,040 {plus minus}74 Ma, respectively. Nd isotope data from these rocks suggest that a diorite-tonalite-trondhjemite suite ({epsilon}{sub Nd}(T) = +2.1 to +2.7; T is time of crystallization) evolved from partial melts of depleted mantle with no discernible contamination by older crust, whereas a coeval granitic pluton ({epsilon}{sub Nd}(T) = {minus}5.7) containsmore » a significant component derived from Archean crust. Orthogneisses with similar age and Nd isotope characteristics are found in the Idono complex 250 km to the north. Early Proterozoic rocks are unknown elsewhere in Alaska. However, Phanerozoic plutons cutting several continental terranes in Alaska (southern Brooks Range and Ruby, Seward, and Yukon-Tanana terranes) have Nd isotope compositions indicative of Early Proterozoic (or older) crustal components that could be correlative with rocks of the Kilbuck terrane. Rocks with similar igneous ages in cratonal North America are rare, and those few that are known have Nd isotope compositions distinct from those of the Kilbuck terrane. Conversely, provinces with Nd model ages of 2.0-2.1 Ga are characterized by extensive 1.8 Ga or younger plutonism, which is unknown in the Kilbuck terrane. At present the case for a North American parentage of the Kilbuck terrane is not compelling. The possibility that the Kilbuck terrane was displaced from provinces of similar age in other cratons (e.g., Australian, Baltic, Guiana, and west African shields), or from the poorly dated Siberian craton, cannot be excluded.« less

Petrology and geochemistry of the high-pressure Nilgiri Granulite Terrane, Southern India

NASA Technical Reports Server (NTRS)

Srikantappa, C.; Ashamanjari, K. G.; Raith, M.

1988-01-01

The Nilgiri granulite terrane in Southern India is predominantly composed of late Archaean medium- to coarse-grained enderbitic to charnockitic rocks. The dominant regional foliation strikes N60 to 70E with generally steep dips. Tight minor isoclinal folds have been observed in places. Granoblastic polygonal micro-structures are common and indicate thorough post-kinematic textural and chemical equilibration at conditions of the granulite facies (2.5 Ga ago). Late compressional deformation in connection with the formation of the Moyar and Bhavani shear zones to the north and south of the Nilgiri block, resulted in wide-spread development of weakly to strongly strained fabrics and was accompanied by minor rehydration. Enderbites and charnockites range from tonalitic to granodioritic in composition. A magmatogenic origin of the protoliths is inferred from their chemical characteristics which resemble those of the andesitic to dacitic members of Cordillera-type calc-alkaline igneous suites. A significant lithological feature of the Nilgiri granulite terrane are numerous extended bodies, lenses and pods of gabbroic and pyroxenitic rocks which are aligned conformable to the foliation of the enderbite-charnockite complex and which have also been deformed and metamorphosed at granulite facies conditions.

Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska

USGS Publications Warehouse

Bacon, Charles R.; Vazquez, Jorge A.; Wooden, Joseph L.

2012-01-01

Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular

Metamorphic and geochronogical study of the Triassic El Oro metamorphic complex, Ecuador: Implications for high-temperature metamorphism in a forearc zone

NASA Astrophysics Data System (ADS)

Riel, N.; Guillot, S.; Jaillard, E.; Martelat, J.-E.; Paquette, J.-L.; Schwartz, S.; Goncalves, P.; Duclaux, G.; Thebaud, N.; Lanari, P.; Janots, E.; Yuquilema, J.

2013-01-01

In the forearc of the Andean active margin in southwest Ecuador, the El Oro metamorphic complex exhibits a well exposed tilted forearc section partially migmatized. We used Raman spectroscopy on carbonaceous matter (RSCM) thermometry and pseudosections coupled with mineralogical and textural studies to constrain the pressure-temperature (P-T) evolution of the El Oro metamorphic complex during Triassic times. Our results show that anatexis of the continental crust occurred by white-mica and biotite dehydration melting along a 10 km thick crustal domain (from 4.5 to 8 kbar) with increasing temperature from 650 to 700 °C. In the biotite dehydration melting zone, temperature was buffered at 750-820 °C in a 5 km thick layer. The estimated average thermal gradient during peak metamorphism is of 30 °C/km within the migmatitic domain can be partitioned into two apparent gradients parts. The upper part from surface to 7 km depth records a 40-45 °C/km gradient. The lower part records a quasi-adiabatic geotherm with a 10 °C/km gradient consistent with an isothermal melting zone. Migmatites U-Th-Pb geochronology yielded zircon and monazite ages of 229.3 ± 2.1 Ma and 224.5 ± 2.3 Ma, respectively. This thermal event generated S-type magmatism (the Marcabeli granitoid) and was immediately followed by underplating of the high-pressure low-temperature (HP-LT) Arenillas-Panupalí unit at 225.8 ± 1.8 Ma. The association of high-temperature low-pressure (HT-LP) migmatites with HP-LT unit constitutes a new example of a paired metamorphic belt along the South American margin. We propose that in addition to crustal thinning, underplating of the Piedras gabbroic unit before 230 Ma provided the heat source necessary to foster crustal anatexis. Furthermore, its MORB signature shows that the asthenosphere was involved as the source of the heat anomaly. S-type felsic magmatism is widespread during this time and suggests that a large-scale thermal anomaly affected a large part of the

Isotope and chemical age of the Greater Caucasus basement metamorphic rocks

NASA Astrophysics Data System (ADS)

Konilov, A. N.; Somin, M. L.; Mukhanova, A. A.

2009-04-01

complexes independently of baric type seem to be formed roughly synchronously during Variscan epoch. References: Gamkrelidze I.P., Shengelia D.M. ( 2005).The Precambrian-Paleozoic Regional Metamorphism, Granitoid Magmatism, and Geodynamics of the Caucasus. M: Nauchnyi Mir [in Russian]. Pyle J.M., Frank S. Spear F.S. et al. (2001). Monazite-Xenotime-Garnet Equilibrium in Metapelites and a New Monazite-Garnet Thermometer. Journal of Petrology, , 42, 2083-2107. Slagstad T. (2006).Chemical (U-Th-Pb) dating of monazite: Analytical protocol for a LEO 1450VP scanning electron microscope and examples from Rogaland and Finnmark, Norway. Norges geologiske undersøkelse Bulletin, 446, 11-18. Somin M.L. (2007a). Pre-Alpine basement of the Greater Caucasus: main features. In: Alpine history of the Greater Caucasus (Yu.G. Leonovб Ed.). GEOS. Moscow. P.15-38. Somin M.L., Lepekhina E.N., Konilov A.N. ( 2007b). Age of the High-Temperature Gneiss Core of the Central Caucasus. Doklady Earth Sciences, 415, 690-694. Somin M.L., Levchenkov O.A., Kotov A.B. et al. (2007c). The Paleozoic Age of High-Pressure Metamorphic Rocks in the Dakhov Salient, North-Western Caucasus: Results of U-Pb Geochronological Investigations. Doklady Earth Sciences, 416, 1018-1021. Suzuki K., Adachi M. (1991). Precambrian provenance and Silurian metamorphism of the Tsunosava paragneiss in South Kitakami terrane, northeast Japan, revealed by the chemical Th-U-total Pb isochron ages of monazite, zircon and xenotime. Journal of Geochemistry, 25, 357-376.

High-pressure/low-temperature metamorphism in the collision zone between the Chilenia and Cuyania microcontinents (western Precordillera, Argentina)

NASA Astrophysics Data System (ADS)

Boedo, F. L.; Willner, A. P.; Vujovich, G. I.; Massonne, H.-J.

2016-12-01

In central-western Argentina, an Early Paleozoic belt including mafic-ultramafic bodies, marine metasedimentary rocks and high-pressure rocks occur along the western margin of the Precordillera and in the Frontal Cordillera. First pressure-temperature estimates are presented here for low-grade rocks of the southern sector of this belt based on two metasedimentary and one metabasaltic sample from the Peñasco Formation. Peak metamorphic conditions resulted within the range of 345-395 °C and 7.0-9.3 kbar within the high-pressure greenschist facies. The corresponding low metamorphic gradient of 13 °C/km is comparable with subduction related geothermal gradients. Comparison between these results and data from other localities of the same collision zone (Guarguaraz and Colohuincul complexes) confirms a collision between Chilenia and the composite margin of western Gondwana and suggests a stronger crustal thickening in the south of the belt, causing exhumation of more deeply buried sequences. During the Early Paleozoic a long-lived marine sedimentation coupled with the intrusion of MORB-like basalts occurred along a stable margin before the collision event. This contrasts with the almost contemporaneous sedimentation registered during accretion in accretionary prism settings and additionally proves the development of a collision zone along western Precordillera and the eastern Frontal Cordillera as well as the existence of Chilenia as a separate microcontinent.

Geophysical modeling of the northern Appalachian Brompton-Cameron, Central Maine, and Avalon terranes under the New Jersey Coastal Plain

USGS Publications Warehouse

Maguire, T.J.; Sheridan, R.E.; Volkert, R.A.

2004-01-01

A regional terrane map of the New Jersey Coastal Plain basement was constructed using seismic, drilling, gravity and magnetic data. The Brompton-Cameron and Central Maine terranes were coalesced as one volcanic island arc terrane before obducting onto Laurentian, Grenville age, continental crust in the Taconian orogeny [Rankin, D.W., 1994. Continental margin of the eastern United States: past and present. In: Speed, R.C., (Ed.), Phanerozoic Evolution of North American Continent-Ocean Transitions. DNAG Continent-Ocean Transect Volume. Geological Society of America, Boulder, Colorado, pp. 129-218]. Volcanic island-arc rocks of the Avalon terrane are in contact with Central Maine terrane rocks in southern Connecticut where the latter are overthrust onto the Brompton-Cameron terrane, which is thrust over Laurentian basement. Similarities of these allochthonous island arc terranes (Brompton-Cameron, Central Maine, Avalon) in lithology, fauna and age suggest that they are faulted segments of the margin of one major late Precambrian to early Paleozoic, high latitude peri-Gondwana island arc designated as "Avalonia", which collided with Laurentia in the early to middle Paleozoic. The Brompton Cameron, Central Maine, and Avalon terranes are projected as the basement under the eastern New Jersey Coastal Plain based on drill core samples of metamorphic rocks of active margin/magmatic arc origin. A seismic reflection profile across the New York Bight traces the gentle dipping (approximately 20 degrees) Cameron's Line Taconian suture southeast beneath allochthonous Avalon and other terranes to a 4 sec TWTT depth (approximately 9 km) where the Avalonian rocks are over Laurentian crust. Gentle up-plunge (approximately 5 degrees) projections to the southwest bring the Laurentian Grenville age basement and the drift-stage early Paleozoic cover rocks to windows in Burlington Co. at approximately 1 km depth and Cape May Co. at approximately 2 km depths. The antiformal Shellburne

Atmospheric Ar and Ne returned from mantle depths to the Earth’s surface by forearc recycling

PubMed Central

Baldwin, Suzanne L.; Das, J. P.

2015-01-01

In subduction zones, sediments, hydrothermally altered lithosphere, fluids, and atmospheric gases are transported into the mantle, where ultrahigh-pressure (UHP) metamorphism takes place. However, the extent to which atmospheric noble gases are trapped in minerals crystallized during UHP metamorphism is unknown. We measured Ar and Ne trapped in phengite and omphacite from the youngest known UHP terrane on Earth to determine the composition of Ar and Ne returned from mantle depths to the surface by forearc recycling. An 40Ar/39Ar age [7.93 ± 0.10 My (1σ)] for phengite is interpreted as the timing of crystallization at mantle depths and indicates that 40Ar/39Ar phengite ages reliably record the timing of UHP metamorphism. Both phengite and omphacite yielded atmospheric 38Ar/36Ar and 20Ne/22Ne. Our study provides the first documentation, to our knowledge, of entrapment of atmospheric Ar and Ne in phengite and omphacite. Results indicate that a subduction barrier for atmospheric-derived noble gases does not exist at mantle depths associated with UHP metamorphism. We show that the crystallization age together with the isotopic composition of nonradiogenic noble gases trapped in minerals formed during subsolidus crystallization at mantle depths can be used to unambiguously assess forearc recycling of atmospheric noble gases. The flux of atmospheric noble gas entering the deep Earth through subduction and returning to the surface cannot be fully realized until the abundances of atmospheric noble gases trapped in exhumed UHP rocks are known. PMID:26542683

Detrital zircon ages in Korean mid-Paleozoic meta-sandstones (Imjingang Belt and Taean Formation): Constraints on tectonic and depositional setting, source regions and possible affinity with Chinese terranes

NASA Astrophysics Data System (ADS)

Han, Seokyoung; de Jong, Koen; Yi, Keewook

2017-08-01

Sensitive High-Resolution Ion Microprobe (SHRIMP) U-Th-Pb isotopic data of detrital zircons from mature, quartz-rich meta-sandstones are used to constrain possible tectonic affinities and source regions of the rhythmically layered and graded-bedded series in the Yeoncheon Complex (Imjingang Belt) and the correlative Taean Formation. These metamorphic marine turbidite sequences presently occur along the Paleoproterozoic (1.93-1.83 Ga) Gyeonggi Massif, central Korea's main high-grade metamorphic gneiss terrane. Yet, detrital zircons yielded highly similar multimodal age spectra with peaks that do not match the age repartition in these basement rocks, as late (1.9-1.8 Ga) and earliest (∼ 2.5 Ga) Paleoproterozoic detrital modes are subordinate but, in contrast, Paleozoic (440-425 Ma) and Neoproterozoic (980-920 Ma) spikes are prominent, yet the basement essentially lacks lithologies with such ages. The youngest concordant zircon ages in each sample are: 378, 394 and 423 Ma. The maturity of the meta-sandstones and the general roundness of zircons of magmatic signature, irrespective of their age, suggest that sediments underwent considerable transport from source to sink, and possibly important weathering and recycling, which may have filtered out irradiation-weakened metamorphic zircon grains. In combination with these isotopic data, presence of a low-angle ductile fault contact between the Yeoncheon Complex and the Taean Formation and the underlying mylonitized Precambrian basement implies that they are in tectonic contact and do not have a stratigraphic relationship, as often assumed. Consequently, in all likelihood, both meta-sedimentary formations: (1) are at least of early Late Devonian age, (2) received much of their detritus from distant (reworked) Silurian-Devonian and Early Neoproterozoic magmatic sources, not present in the Gyeonggi Massif, (3) and not from Paleoproterozoic crystalline rocks of this massif, or other Korean Precambrian basement terranes, and

Recent progress in recognition of UHP metamorphism in allochthons of the Scandinavian Caledonides (Seve Nappe Complex and Tromsø Nappe)

NASA Astrophysics Data System (ADS)

Janák, Marian; Ravna, Erling; Majka, Jarosław; Klonowska, Iwona; Kullerud, Kåre; Gee, David; Froitzheim, Nikolaus

2017-04-01

metamorphism in the SNC related to continent-continent or arc-continent collision? (2) Which processes lead to the emplacement of peridotite bodies with subcontinental mantle affinity into Baltican continental crust? (3) Was the Tromsø Nappe of Laurentian origin, or a part of the Baltoscandian margin emplaced by out-of-sequence thrusting, or a terrane of unknown affinity? Therefore, it is important to constrain the areal extent, pressure-temperature conditions, timing, and kinematics of UHP metamorphism in these allochthonous units.

Trace-element record in zircons during exhumation from UHP conditions, North-East Greenland Caledonides

USGS Publications Warehouse

McClelland, W.C.; Gilotti, J.A.; Mazdab, F.K.; Wooden, J.L.

2009-01-01

Coesite-bearing zircon formed at ultrahigh-pressure (UHP) conditions share general characteristics of eclogite-facies zircon with trace-element signatures characterized by depleted heavy rare earth elements (HREE), lack of an Eu anomaly, and low Th/ U ratios. Trace-element signatures of zircons from the Caledonian UHP terrane in North-East Greenland were used to examine the possible changes in signature with age during exhumation. Collection and interpretation of age and trace-element analyses of zircon from three samples of quartzofeldspathic gneiss and two leucocratic intrusions were guided by core vs. rim zoning patterns as imaged by cathodoluminesence. Change from igneous to eclogite-facies metamorphic trace-element signature in protolith zircon is characterized by gradual depletion of HREE, whereas newly formed metamorphic rims have flat HREE patterns and REE concentrations that are distinct from the recrystallized inherited cores. The signature associated with eclogite-facies metamorphic zircon is observed in coesite-bearing zircon formed at 358 ?? 4 Ma, metamorphic rims formed at 348 ?? 5 Ma during the initial stages of exhumation, and metamorphic rims formed at 337 ?? 5 Ma. Zircons from a garnet-bearing granite emplaced in the neck of an eclogite boudin and a leucocratic dike that cross-cuts amphibolite-facies structural fabrics have steeply sloping HREE patterns, variably developed negative Eu anomalies, and low Th/U ratios. The granite records initial decompression melting and exhumation at 347 ?? 2 Ma and later zircon rim growth at 329 ?? 5. The leucocratic dike was likely emplaced at amphibolite-facies conditions at 330 ?? 2 Ma, but records additional growth of compositionally similar zircon at 321 ??2 Ma. The difference between the trace-element signature of metamorphic zircon in the gneisses and in part coeval leucocratic intrusions indicates that the zircon signature varies as a function of lithology and context, thus enhancing its ability to aid in

Geology and geochronology of granitoid and metamorphic rocks of late Archean age in northwestern Wisconsin

USGS Publications Warehouse

Sims, P.K.; Peterman, Z.E.; Zartman, R.E.; Benedict, F.C.

1985-01-01

Granitoid rocks of the Puritan Quartz Monzonite and associated biotite gneiss and amphibolite in northwestern Wisconsin compose the southwestern part of the Puritan batholith of Late Archean age. They differ from rocks in the Michigan segment of the batholith in having been deformed by brittle-ductile deformation and partly recrystallized during shearing accompanying development of the midcontinent rift system of Keweenawan (Middle Proterozoic) age. Granitoid rocks ranging in composition from granite to tonalite are dominant in the Wisconsin part of the batholith. To the north of the Mineral Lake fault zone, they are massive to weakly foliated and dominantly of granite composition, whereas south of the fault zone they are more strongly foliated and mainly of tonalite composition. Massive granite, leucogranite, and granite pegmatite cut the dominant granitoid rocks. Intercalated with the granitoid rocks in small to large conformable bodies are biotite gneiss, amphibolite, and local tonalite gneiss. Metagabbro dikes of probable Early Proterozoic age as much as 15 m thick cut the Archean rocks. Rubidium-strontium whole-rock data indicate a Late Archean age for the granitoids and gneisses, but data points are scattered and do not define a single isochron. Zircon from two samples of tonalitic gneiss for uranium-thorium-Iead dating define a single chord on a concordia diagram, establishing an age of 2,735?16 m.y. The lower intercept age of 1,052?70 m.y. is in close agreement with rubidium-strontium and potassium-argon biotite ages from the gneisses. Two episodes of deformation and metamorphism are recorded in the Archean rocks. Deformation during the Late Archean produced a steep west-northwest-oriented foliation and gently plunging fold axes and was accompanied by low amphibolite-facies metamorphism of the bedded rocks. A younger deformation resulting from largely brittle fracture was accompanied by retrogressive metamorphism; this deformation is most evident adjacent

Recent advances in capillary ultrahigh pressure liquid chromatography.

PubMed

Blue, Laura E; Franklin, Edward G; Godinho, Justin M; Grinias, James P; Grinias, Kaitlin M; Lunn, Daniel B; Moore, Stephanie M

2017-11-10

In the twenty years since its initial demonstration, capillary ultrahigh pressure liquid chromatography (UHPLC) has proven to be one of most powerful separation techniques for the analysis of complex mixtures. This review focuses on the most recent advances made since 2010 towards increasing the performance of such separations. Improvements in capillary column preparation techniques that have led to columns with unprecedented performance are described. New stationary phases and phase supports that have been reported over the past decade are detailed, with a focus on their use in capillary formats. A discussion on the instrument developments that have been required to ensure that extra-column effects do not diminish the intrinsic efficiency of these columns during analysis is also included. Finally, the impact of these capillary UHPLC topics on the field of proteomics and ways in which capillary UHPLC may continue to be applied to the separation of complex samples are addressed. Copyright © 2017 Elsevier B.V. All rights reserved.

Isotopic and trace element variations in the Ruby Batholith, Alaska, and the nature of the deep crust beneath the Ruby and Angayucham Terranes

USGS Publications Warehouse

Arth, Joseph G.; Zmuda, Clara C.; Foley, Nora K.; Criss, Robert E.; Patton, W.W.; Miller, T.P.

1989-01-01

to mafic crustal rocks. The inferred sources could well have been the higher-metamorphic-grade lithologic equivalents of the exposed Proterozoic(?) to Paleozoic schists, orthogneisses, and metavolcanic rocks of Ruby terrane, the silicic portions of which are quite radiogenic. The deeper crustal sources that gave rise to most of the batholithic magmas are inferred to be similar under both the Ruby metamorphic terrane and the Angayucham ophiolitic terrane.

Metamorphism and partial melting of ordinary chondrites: Calculated phase equilibria

NASA Astrophysics Data System (ADS)

Johnson, T. E.; Benedix, G. K.; Bland, P. A.

2016-01-01

Constraining the metamorphic pressures (P) and temperatures (T) recorded by meteorites is key to understanding the size and thermal history of their asteroid parent bodies. New thermodynamic models calibrated to very low P for minerals and melt in terrestrial mantle peridotite permit quantitative investigation of high-T metamorphism in ordinary chondrites using phase equilibria modelling. Isochemical P-T phase diagrams based on the average composition of H, L and LL chondrite falls and contoured for the composition and abundance of olivine, ortho- and clinopyroxene, plagioclase and chromite provide a good match with values measured in so-called equilibrated (petrologic type 4-6) samples. Some compositional variables, in particular Al in orthopyroxene and Na in clinopyroxene, exhibit a strong pressure dependence when considered over a range of several kilobars, providing a means of recognising meteorites derived from the cores of asteroids with radii of several hundred kilometres, if such bodies existed at that time. At the low pressures (<1 kbar) that typify thermal metamorphism, several compositional variables are good thermometers. Although those based on Fe-Mg exchange are likely to have been reset during slow cooling, those based on coupled substitution, in particular Ca and Al in orthopyroxene and Na in clinopyroxene, are less susceptible to retrograde diffusion and are potentially more faithful recorders of peak conditions. The intersection of isopleths of these variables may allow pressures to be quantified, even at low P, permitting constraints on the minimum size of parent asteroid bodies. The phase diagrams predict the onset of partial melting at 1050-1100 °C by incongruent reactions consuming plagioclase, clinopyroxene and orthopyroxene, whose compositions change abruptly as melting proceeds. These predictions match natural observations well and support the view that type 7 chondrites represent a suprasolidus continuation of the established petrologic

The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis

USGS Publications Warehouse

Price, L.C.; Wenger, L.M.

1992-01-01

Because fluid pressures are transient in sedimentary basins over geologic time, the effect of increasing fluid pressure on organic-matter metamorphism is difficult to determine, and conflicting opinions exist concerning its influence. Properly-performed aqueous-pyrolysis experiments can closely simulate hydrocarbon generation and maturation in nature, and thus offer an excellent way to study the influence of pressure. Such experiments, carried out on the Retort Phosphatic Shale Member of the Lower Permian Phosphoria Formation (type II-S organic matter) at different constant temperatures, demonstrated that increasing pressure significantly retards all aspects of organic matter metamorphism, including hydrocarbon generation, maturation and thermal destruction. This conclusion results from detailed quantitative and qualitative analyses of all products from hydrocarbon generation, from the C1 to C4 hydrocarbon gases to the asphaltenes, and also from analyses of the reacted rocks. We have documented that our aqueous-pyrolysis experiments closely simulated natural hydrocarbon generation and maturation. Thus the data taken as a function of pressure have relevance to the influence of normal and abnormal fluid pressures as related to: 1) depths and temperatures of mainstage hydrocarbon generation; 2) the thermal destruction of deposits of gas or light oil, or their preservation to unexpectedly high maturation ranks; and 3) the persistence of measurable to moderate concentrations of C15+ hydrocarbons in fine-grained rocks even to ultra-high maturation ranks. ?? 1992.

Linking Tengchong Terrane in SW Yunnan with Lhasa Terrane in southern Tibet through magmatic correlation

NASA Astrophysics Data System (ADS)

Xie, Jincheng; Zhu, Dicheng; Dong, Guochen; Zhao, Zhidan; Wang, Qing

2016-04-01

New zircon U-Pb data, along with the data reported in the literature, reveal five phases of magmatic activity in the Tengchong Terrane since the Early Paleozoic with spatial and temporal variations summarized as: Cambrian-Ordovician (500-460 Ma) to the eastern, minor Triassic (245-206 Ma) in the eastern and western, abundant Early Cretaceous (131-114 Ma) in the eastern, extensive Late Cretaceous (77-65 Ma) in the central, and Paleocene-Eocene (65-49 Ma) in the central and western Tengchong Terrane, in which the Cretaceous-Eocene magmatism was migrated from east to west (Xu et al., 2012). The increased zircon eHf(t) of the Early Cretaceous granitoids from -12.3 to -1.4 at ca. 131-122 Ma to -4.6 to +7.1 at ca. 122-114 Ma identified for the first time in this study and the magmatic flare-up at ca. 53 Ma in the central and western Tengchong Terrane (Wang et al., 2014, Ma et al., 2015) indicate the increased contributions from mantle- or juvenile crust-derived components. The spatial and temporal variations and changing magmatic compositions with time in the Tengchong Terrane closely resemble the Lhasa Terrane in southern Tibet. Such similarities, together with the data of stratigraphy and paleobiogeography (Zhang et al., 2013), enable us to propose that the Tengchong Terrane in SW Yunnan is most likely linked with the Lhasa Terrane in southern Tibet, both of which experience similar tectonomagmatic histories since the Early Paleozoic. References Ma, L.Y., Wang, Y.J., Fan, W.M., Geng, H.Y., Cai, Y.F., Zhong, H., Liu, H.C., Xing, X.W., 2014. Petrogenesis of the early Eocene I-type granites in west Yingjiang (SW Yunnan) and its implication for the eastern extension of the Gangdese batholiths. Gondwana Research 25, 401-419. Wang, Y.J., Zhang, L.M., Cawood, P.A., Ma, L.Y., Fan, W.M., Zhang, A.M., Zhang, Y.Z., Bi, X.W., 2014. Eocene supra-subduction zone mafic magmatism in the Sibumasu Block of SW Yunnan: Implications for Neotethyan subduction and India-Asia collision

Ultra-high pressure waterjets efficient in removing coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-06-01

Little if any thought was given to pipeline rehabilitation 50 years, a time when pipe manufacturers often coated the external diameter of pipe with coal tar to help eliminate corrosion. Unfortunately, contractors rehabilitating these pipelines today encounter major difficulties when attempting to remove coal tar with traditional removal processes. A leading pipeline rehabilitation firm, F.F. Yockey Company, Inc. of Magnolia, Texas, faced a constant challenge stripping coal tar with rotating knives and brushes. The process generated heat that melted the tar and caused the machines to jam. Another problem was the damage to the substrate caused by the friction-based cleaningmore » techniques of rotating knives and brushes. The knives also failed to completely clean the substrate, leaving behind a significant amount of residue. Contractors learned that new coating bonded poorly to the substrates covered with residual contaminants, thus yielding unsatisfactory results. As he looked for a solution, Dick Yockey, president and CEO of R.F. Yockey, began exploring the use of ultra-high pressure waterjet surface preparation equipment. This system involved water pressurized at levels ranging from 35,000 to 55,000 psi. The water travels through small orifices in a high-speed rotating nozzle, forming a cohesive stream of water. This paper reviews the design and performance of this system.« less

Metamorphic reactions in the Chaunskij mesosiderite

NASA Astrophysics Data System (ADS)

Petaev, M. I.; Brearley, A. J.

1994-07-01

The Chaunskij meteorite, found in 1985, recently has been found to be the most highly metamorphosed, shock-modified, and metal-rich mesosiderite. It contains approximately 10 vol% mono- and polymineralic troilite-phosphate-silicate inclusions, micrometers to centimeters in size. Two dominant silicate lithologies have been found in the inclusions. The primary 'igneous' lithology, making up the largest inclusion studied, is generally a microophitic fine-grained aggregate of pyroxene, plagioclase, and minor silica, with scattered coarser-grained granoblastic spots enriched in silica and troilite. The secondary 'metamorphic' lithology occurs as separate small inclusions and as larger areas in intimate contact with the 'igneous' lithology, separated by highly irregular boundaries from each other, in the largest inclusion. In small inclusions the metamorphic lithology consists of a fine-grained hornfelsic to granoblastic aggregate of cordierite, orthopyroxene, quartz, and whitlockite with variable amounts of opaque minerals. In the largest inclusion the metamorphic lithology is a generally granoblastic to poikiloblastic aggregate of cordierite and quartz with minor amounts of other minerals. The Opx-Chr mineral thermometer and the Cord-Sp barometer have been applied to estimate the conditions of Chaunskij metamorphism. The data for 16 Opx-Chr pairs from different inclusions and lithologies correspond to a temperature of 590 +/- 30 C. The data for 9 Cord-Chr pairs from different inclusions correspond to a pressure of 6.0 +/- 0.2 kbar. While the composition of spinel in Chaunskij much richer in Cr than were the spinels used to calibrate Cord-Sp barometer the estimated pressure is consistent with the occurrence in the igneous lithology of two small pyroxene grains enriched in the CaAl2SiO6 molecule, coexisting with quartz and plagioclase. This mineral assemblage is unstable below approximately 5 kbar at 600 C.

Pseudolinear gradient ultrahigh-pressure liquid chromatography using an injection valve assembly.

PubMed

Xiang, Yanqiao; Liu, Yansheng; Stearns, Stanley D; Plistil, Alex; Brisbin, Martin P; Lee, Milton L

2006-02-01

The use of ultrahigh pressures in liquid chromatography (UHPLC) imposes stringent requirements on hardware such as pumps, valves, injectors, connecting tubing, and columns. One of the most difficult components of the UHPLC system to develop has been the sample injector. Static-split injection, which can be performed at pressures up to 6900 bar (100,000 psi), consumes a large sample volume and is very irreproducible. A pressure-balanced injection valve provided better reproducibility, shorter injection time, reduced sample consumption, and greater ease of use; however, it could only withstand pressures up to approximately 1000 bar (15,000 psi). In this study, a new injection valve assembly that can operate at pressures as high as 2070 bar (30,000 psi) was evaluated for UHPLC. This assembly contains six miniature electronically controlled needle valves to provide accurate and precise volumes for introduction into the capillary LC column. It was found that sample volumes as small as several tenths of a nanoliter can be injected, which are comparable to the results obtained from the static-split injector. The reproducibilities of retention time, efficiency, and peak area were investigated, and the results showed that the relative standard deviations of these parameters were small enough for quantitative analyses. Separation experiments using the UHPLC system with this new injection valve assembly showed that this new injector is suitable for both isocratic and gradient operation modes. A newly designed capillary connector was used at a pressure as high as 2070 bar (30,000 psi).

Combined Detrital U/Pb Zircon and 40Ar/39Ar Mica Geoochronology to Test Structural Models for a Devonian Orogenic Collapse Basin in the Norwegian Caledonides

NASA Astrophysics Data System (ADS)

Templeton, J.; Anders, M.; Fossen, H.

2014-12-01

The Hornelen basin is the largest of the Devonian 'Old Red' sandstone basins in Norway, comprising 25 km of alluvial-fluvial deposits which are organized into basin-wide, coarsening-upward megacycles. Hornelen sits with several smaller basins in the hanging wall a major extensional shear zone along which the ultra-high pressure metamorphic core of subducted Baltican crust was rapidly exhumed during the extensional collapse of the Caledonian orogeny. The timing of orogenic collapse corresponds closely to the timing of the basins, which are loosely constrained by sparse trace-fossil assemblages to a mid-Devonian age. Further, the basins are now in brittle fault contact with the underlying mylonitic shear zone and the metamorphic core, implying that they are the upper-crustal expression of large-scale extension and deep-crustal exhumation. Two distinct structural models have been proposed for Hornelen to account for these observations. The strike-slip model juxtaposes different source terranes across the basin-controlling fault and predicts spatially changing provenance within chronostratigraphic units. The supradetachment model links the filling of the basin directly to unroofing of the metamorphic core on a low-angle detachment fault, and predicts basin-wide changes in provenance through time with progressive exhumation of the metamorphic hinterland. We present an extensive new provenance dataset, spanning the Hornelen basin strata through space and time. Detrital zircon U/Pb ages from 18 new samples comprise three distinct populations (1.6, 1.0, and 0.43 Ga) with the Caledonian-aged zircons (ca 0.43 Ga) present mainly along the northern margin of the basin, representing an Upper Allochthon source not found on the southern or eastern margins of the basin. Juxtaposition of different source terranes across the basin supports the strike-slip model. 40Ar/39Ar detrital white mica from the same sample set documents a younging of the dominant age peak from 432 Ma in the

Nd, Pb, Sr, and O isotopic characterization of Saudi Arabian Shield terranes

USGS Publications Warehouse

Stoeser, D.B.; Frost, C.D.

2006-01-01

New Nd, Sr and O isotopic data for granitoid rocks of the Saudi Arabian Shield are presented together with published Nd, Pb, Sr and O isotopic data and all available geologic and geochronologic information to re-evaluate the terranes defined for the Saudi Arabian part of the Arabian-Nubian Shield. Three groups of terranes are identified: 1) the western arc terranes, 2) the eastern arc terranes, and 3) the Khida terrane. The Khida terrane is the only terrane composed of pre-Neoproterozoic continental crust. The western arc terranes are of oceanic arc affinity, and have the least radiogenic Pb and Sr and most radiogenic Nd isotopic compositions and some of the lowest ??18O values of any rocks of the Saudi Arabian Shield. Although some previous studies have characterized the eastern arc terranes as of continental affinity, this study shows that they too are composed of Neoproterozoic oceanic arcs, although their sources have slightly elevated 208Pb/204Pb, Nd, Sri, and ??18O values compared to the western arc terranes. These data suggest that either the isotopic composition of the mantle source for the western arc terranes is more depleted than that of the eastern arc terranes or the eastern arc terranes have been mixed with a small amount of cratonic source material, or both. We further elaborate on the Hulayfah-Ad Dafinah fault zone as a major boundary within the Saudi Arabian portion of the East African Orogen. With further study, its northern extension may be shown to pass through what has been defined as the Hail terrane, and its southern extension appears to lie under cover east of the Tathlith-Malahah terrane and extend into Yemen. It may represent the collision zone between East and West Gondwana, and at the very least it is an important suture between groups of arc terranes of contrasting isotopic composition caught between two converging continents.

The Hardwood Gneiss: Evidence for high P-T Archean metamorphism in the southern province of the Lake Superior region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, J.W.; Geiger, C.A.

1990-03-01

The Hardwood Gneiss is an areally small unit of Precambrian granulite-grade rocks exposed in the Archean gneiss terrane of the southern Lake Superior region. The rocks are located in the southwestern portion of the Upper Peninsula of Michigan and consist of a structurally conformable package of quartzitic, metapelitic, amphibolitic, and metabasic units. Three texturally distinct garnet types are present in the metabasites and are interpreted to represent two metamorphic events. Geothermobarometry indicates conditions of {approximately}8.2-11.6 kbar and {approximately}770C for M1, and conditions of {approximately}6.0-10.1 kbar and {approximately}610-740C for M2. It is proposed that M1 was Archean and contemporaneous with amore » high-grade metamorphic event recorded in the Minnesota River Valley. The M2 event was probably Early Proterozoic and pre-Penokean, with metamorphic conditions more intense than those generally ascribed to the Penokean Orogeny in Michigan, but similar to the conditions reported for the Kapuskasing zone of Ontario. The high paleopressures and temperatures of the M1 event make the Hardwood Gneiss distinct from any rocks previously described in the southern Lake Superior region, and suggest intense tectonic activity during the Archean.« less

Titanite chronology, thermometry, and speedometry of ultrahigh-temperature (UHT) calc-silicates from south Madagascar: U-Pb dates, Zr temperatures, and lengthscales of trace-element diffusion

NASA Astrophysics Data System (ADS)

Holder, R. M.; Hacker, B. R.

2017-12-01

Calc-silicate rocks are often overlooked as sources of pressure-temperature-time data in granulite-UHT metamorphic terranes due to the strong dependence of calc-silicate mineral assemblages on complex fluid compositions and a lack of thermodynamic data on common high-temperature calc-silicate minerals such as scapolite. In the Ediacaran-Cambrian UHT rocks of southern Madagascar, clinopyroxene-scapolite-feldspar-quartz-zircon-titanite calc-silicate rocks are wide-spread. U-Pb dates of 540-520 Ma from unaltered portions of titanite correspond to cooling of the rocks through upper-amphibolite facies and indicate UHT metamorphism occurred before 540 Ma. Zr concentrations in these domains preserve growth temperatures of 900-950 °C, consistent with peak temperatures calculated by pseudosection modeling of nearby osumilite-bearing gneisses. Younger U-Pb dates (510-490 Ma) correspond to fluid-mediated Pb loss from titanite grains, which occurred below their diffusive Pb-closure temperature, along fractures. The extent of fluid alteration is seen clearly in back-scattered electron images and Zr-, Al-, Fe-, Ce-, and Nb-concentration maps. Laser-ablation depth profiling of idioblastic titanite grains shows preserved Pb diffusion profiles at grain rims, but there is no evidence for Zr diffusion, indicating that it was effectively immobile even at UHT.

Geochemical Constraints for Mercury's PCA-Derived Geochemical Terranes

NASA Astrophysics Data System (ADS)

Stockstill-Cahill, K. R.; Peplowski, P. N.

2018-05-01

PCA-derived geochemical terranes provide a robust, analytical means of defining these terranes using strictly geochemical inputs. Using the end members derived in this way, we are able to assess the geochemical implications for Mercury.

Proterozoic geochronological links between the Farewell, Kilbuck, and Arctic Alaska terranes

USGS Publications Warehouse

Bradley, Dwight C.; McClelland, William C.; Friedman, Richard M.; O'Sullivan, Paul B.; Layer, Paul; Miller, Marti L.; Dumoulin, Julie A.; Till, Alison B.; Abbott, J. Grant; Bradley, Dan B.; Wooden, Joseph L.

2014-01-01

New U-Pb igneous and detrital zircon ages reveal that despite being separated by younger orogens, three of Alaska’s terranes that contain Precambrian rocks—Farewell, Kilbuck, and Arctic Alaska—are related. The Farewell and Kilbuck terranes can be linked by felsic magmatism at ca. 850 Ma and by abundant detrital zircons in the Farewell that overlap the ca. 2010–2085 Ma age range of granitoids in the Kilbuck. The Farewell and Arctic Alaska terranes have already been linked via correlative Neoproterozoic to Devonian carbonate platform deposits that share nearly identical faunas of mixed Siberian and Laurentian affinity. New igneous ages strengthen these ties. Specifically, 988, 979, and 979 Ma metafelsites in the Farewell terrane are close in age to a 971 Ma granitic orthogneiss in the Arctic Alaska terrane. Likewise, 852, 850, 845, and 837 Ma granitic orthogneisses, metafelsite, and rhyolite in the Farewell terrane are similar to the reported 874 to 848 Ma age range of metarhyolites in the Arctic Alaska terrane. The Kilbuck and Arctic Alaska terranes have been previously linked on the basis of provenance: detrital zircons from the Carboniferous Nuka Formation in the Arctic Alaska terrane range from 2013 to 2078 Ma, overlapping the age of Kilbuck granitoids. A new 849 Ma age of a Kilbuck granitoid strengthens the proposed connection. Among the other new results from Kilbuck terrane is a 2085 Ma zircon from a granitoid that now stands as the oldest tightly dated rock in Alaska. We conclude that the Kilbuck, Farewell, and Arctic Alaska terranes were not independent entities with unique geologic histories but instead are related pieces of the circum-Arctic tectonic puzzle.

Ultrahigh Pressure Processing Produces Alterations in the Metabolite Profiles of Panax ginseng.

PubMed

Lee, Mee Youn; Singh, Digar; Kim, Sung Han; Lee, Sang Jun; Lee, Choong Hwan

2016-06-22

Ultrahigh pressure (UHP) treatments are non-thermal processing methods that have customarily been employed to enhance the quality and productivity of plant consumables. We aimed to evaluate the effects of UHP treatments on ginseng samples (white ginseng: WG; UHP-treated WG: UWG; red ginseng: RG; UHP-treated RG: URG; ginseng berries: GB; and UHP-treated GB: UGB) using metabolite profiling based on ultrahigh performance liquid chromatography-linear trap quadrupole-ion trap-tandem mass spectrometry (UHPLC-LTQ-IT-MS/MS) and gas chromatography time-of-flight mass spectrometry (GC-TOF-MS). Multivariate data analyses revealed a clear demarcation among the GB and UGB samples, and the phenotypic evaluations correlated the highest antioxidant activities and the total phenolic and flavonoid compositions with the UGB samples. Overall, eight amino acids, seven organic acids, seven sugars and sugar derivatives, two fatty acids, three notoginsenosides, three malonylginsenosides, and three ginsenosides, were identified as significantly discriminant metabolites between the GB and UGB samples, with relatively higher proportions in the latter. Ideally, these metabolites can be used as quality biomarkers for the assessment of ginseng products and our results indicate that UHP treatment likely led to an elevation in the proportions of total extractable metabolites in ginseng samples.

Migmatization and low-pressure overprinting metamorphism as record of two pre-Cretaceous tectonic episodes in the Santander Massif of the Andean basement in northern Colombia (NW South America)

NASA Astrophysics Data System (ADS)

Zuluaga, C. A.; Amaya, S.; Urueña, C.; Bernet, M.

2017-03-01

The core of the Santander Massif in the northern Andes of Colombia is dominated by migmatitic gneisses with a < 1.71 Ga protolith and was affected by continuous interactions of oceanic plates to the west and the northwestern corner of the South American continental plate. The exposed metamorphic core of the massif offers a unique opportunity to understand the tectonic evolution of northwestern South America. We present new metamorphic petrology and geochemistry data from the Bucaramanga Gneiss in the Santander Massif to document part of this tectonic evolution from late Proterozoic to Jurassic times. Metapelitic migmatite gneiss, quartz-feldspathic gneiss, and amphibolite from the Bucaramanga Gneiss recorded metamorphic peak conditions in the range of 660-850 °C at pressures of > 7.5 kbar. Lithologies are overprinted by low-pressure metamorphism, related to extensive Jurassic intrusions and linked with growth of cordierite and equilibration of low-pressure mineral assemblages, recorded metamorphic conditions are < 750 °C and < 6.5 kbar. Observed leucosomes display significant compositional variations and can be grouped in three groups: i) Group One leucosomes with high total REE content, high LREE/HREE, and negative Eu anomaly, ii) Group Two leucosomes with low total REE, low LREE/HREE, and positive Eu anomalies, and iii) Group Three leucosomes with relatively low LREE/HREE and strong positive Eu anomaly. Geochemical data support the interpretation that Group Two leucosomes crystallized from melts originated in a partial melting event affecting mostly pelitic and quartz-feldspathic lithologies with fluid-present melting reactions. The evaluation of mesosomes (amphibolite, pelitic and quartz-feldspathic rocks) as potential protoliths or restites indicates that at least two pelitic samples of the analyzed lithologies have characteristics consistent with the occurrence of fluid-present melting reactions involving quartz and feldspar. The leucosomes produced by

Metamorphic sole formation and early plate interface rheology: Insights from Griggs apparatus experiments

NASA Astrophysics Data System (ADS)

Soret, Mathieu; Agard, Philippe; Dubacq, Benoît; Hirth, Greg; Yamato, Philippe; Ildefonse, Benoît; Prigent, Cécile

2016-04-01

Metamorphic soles correspond to m to ~500 m thick highly strained metamorphic rock units found beneath mylonitic banded peridotites at the base of large-scale ophiolites, as exemplified in Oman. Metamorphic soles are mainly composed of metabasalts deriving from the downgoing oceanic lithosphere and metamorphosed up to granulite-facies conditions by heat transfer from the mantle wedge. Pressure-temperature peak conditions are usually estimated at 1.0±0.2 GPa and 800±100°C. The absence of HP-LT metamorphism overprint implies that metamorphic soles have been formed and exhumed during subduction infancy. In this view, metamorphic soles were strongly deformed during their accretion to the mantle wedge (corresponding, now, to the base of the ophiolite). Therefore, metamorphic soles and banded peridotites are direct witnesses of the dynamics of early subduction zones, in terms of thermal structure, fluid migration and rheology evolution across the nascent slab interface. Based on fieldwork and EBSD analyses, we present a detailed (micro-) structural study performed on samples coming from the Sumeini window, the better-preserved cross-section of the metamorphic sole of Oman. Large differences are found in the deformation (CPO, grain size, aspect ratio) of clinopyroxene, amphibole and plagioclase, related to mineralogical changes linked with the distance to the peridotite contact (e.g., hardening due to the appearance of garnet and clinopyroxene). To model the incipient slab interface in laboratory, we carried out 5 hydrostatic annealing and simple-shear experiments on Griggs solid-medium apparatus. Deformation experiments were conducted at axial strain rates of 10-6 s-1. Fine-grained amphibolite was synthetized by adding 1 wt.% water to a (Mid-Ocean Ridge) basalt powder as a proxy for the metamorphic sole (amphibole + plagioclase + clinopyroxene ± garnet assemblage). To synthetize garnet, 2 experiments were carried out in hydrostatic conditions and with deformation at

Structural evolution and tectonic context of the Mfongosi Group, Natal thrust front, Tugela terrane, South Africa

NASA Astrophysics Data System (ADS)

Basson, I. J.; Watkeys, M. K.; Phillips, D.

2005-11-01

The Mesoproterozoic Natal Metamorphic Province of Kwazulu-Natal in South Africa is an assemblage of several tectonic units, including accreted oceanic island arcs, obducted oceanic crust and deformed basin material. The highly deformed Mfongosi Group occurs at the leading edge of collision (the Natal thrust front), against and directly overlying the southern margin of the Kaapvaal Craton. Structures within the Mfongosi Group record "local" D1 and D2 events, the first of which was "oblique obduction", with predominantly N- to NNE-verging thrusting ( D1). This was followed by sinistral transpression combined with vertical constriction, forming SW-plunging kink folds and SW-plunging prolate pillow basalts ( D2). The third and final event ( D3) was E-W to ESE-WNW extension in a post-thrusting phase, defined by fibrous antitaxial quartz-calcite veining. The westernmost portion of the Mfongosi Group, the Ngubevu area, shows significantly higher finite strains (up to Rf = 12) compared to central Mfongosi and eastern Nkandlha areas ( Rf = 1.5 and less), suggesting highly oblique, largely NE-directed initial collision. Deformation of the NTF in the context of nappe emplacement is constrained by 40Ar/ 39Ar dating of post-cataclastic nematoblastic/porphyroblastic hornblende of the Manyane amphibolite close to the thrust between the Tugela nappe and the Mfongosi Group in the Mfongosi area. Hornblende overgrew the products of low-temperature deformation during the "local" D1 and D2. A minimum age of 1171 ± 16 Ma (95% conf., including J-error; weighted by √MSWD; MSWD = 4.3) is obtained for the tectonic juxtaposition of the Tugela nappe against the southern portions of the "Mfongosi Basin". This "local" D1 and D2 of the Mfongosi Group pre-dates the regional "oblique D1" and "left-lateral D2" previously determined for the central and southern terranes of the Natal Metamorphic Province by other researchers. Comparison of the 1171 ± 16 Ma age, with ages for shearing and

Garnet from diamondiferous metamorphic rocks of Kokchetav massif, Kazakhstan as a peak pressure recorder

NASA Astrophysics Data System (ADS)

Sobolev, N. V.; Palyanov, Y. N.; Shatsky, V. S.; Sokol, A. G.; Tomilenko, A. A.

2003-12-01

Garnet is a key mineral coexisting with diamond both in kimberlite (as xenocrysts, in diamondiferous garnet peridotites and eclogites, as inclusions in diamond) and in UHP metamorphic rocks of Kokchetav massif (diamondiferous gneisses, garnet-pyroxene rocks, dolomitic marbles and diamond facies eclogites). In UHPM rocks garnets are of particular importance as inclusions in zircons protected from retrograde metamorphism. Diamond formation conditions in eclogitic (E-type) upper mantle environment are estimated based upon Grt-Cpx thermometry and coesite barometry (e.g. Sobolev et al., PNAS, 2000, 97:11875) at P=5.5-6.0 GPa and T=1000-1300° C. These data are supported by diamond synthesis in carbonate-silicate fluid (e.g. Palyanov et al., Nature, 1999, 400: 417). E-type garnet may dissolve up to 0.3 wt.% Na2O (Sobolev, Lavrentyev, Contr. Min. Petr., 1971, 31:1) depending on pressure and Na2O contents in coexisting pyroxene and melts (fluids). Majorite component (pyroxene solid solution) was reported in rare garnets from diamonds (e.g. Moore, Gurney, Nature, 1985, 318:553) and UHP conditions were experimentally confirmed for such garnets (Irifune, Phys. Eart. Pl. Int., 1987, 45:324; Gasparik, Phys. Chem. Min., 2002, 29:170; Luth, Am. Miner., 1997, 82:1198). Garnets from Kokchetav diamondiferous metamorphic rocks demonstrate considerably lower Na2O solubility (up to 0.2 wt.% in rare samples) and absence of majorite component. However, coexisting pyroxenes may contain up to 50 mol.% jadeite. Several UHP experiments performed with Kokchetav eclogites and dolomitic marbles using a split-sphere apparatus resulted in detection of up to 0.3-0.4 wt.% Na2O in newly formed eclogitic garnets at P=5.7 and 7.0 GPa, T=1400 and 1700° C respectively. Majorite component was also determined in newly formed garnets reaching about 5% with Si (pfu)=3.05-3.06. Similar garnets without Na2O were also obtained in UHP experiments with diamondiferous dolomitic marbles (e.g. Palyanov et al

First evidence of the Ellesmerian metamorphism on Svalbard

NASA Astrophysics Data System (ADS)

Kośmińska, Karolina; Majka, Jarosław; Manecki, Maciej; Schneider, David A.

2016-04-01

The Ellesmerian fold-and-thrust belt is exposed in the High Arctic from Ellesmere Island in the east, through North Greenland, to Svalbard in the west (e.g. Piepjohn et al., 2015). It developed during Late Devonian - Early Carboniferous, and overprinted older (mainly Caledonian) structures. It is thought that this fold-and-thrust belt was formed due to collision of the Pearya Terrane and Svalbard with the Franklinian Basin of Laurentia. Traditionally, the Ellesmerian fold-and-thrust belt comprises a passive continental margin affected by foreland deformation processes, but the exact larger scale tectonic context of this belt is disputable. It is partly because the Eocene Eurekan deformation superimposed significantly the Ellesmerian structures, thus making the reconstruction of the pre-Eurekan history very difficult. Here we present for the first time evidence for Ellesmerian metamorphism within the crystalline basement of Svalbard. These rocks are exposed in the Pinkie unit on Prins Karls Forland (W-Svalbard), which exhibits tectonic contacts with the overlying sequences. The Pinkie unit is mainly composed of strongly deformed lithologies such as laminated quartzites, siliciclastic rocks and garnet-bearing mica schists. Detrital zircon dating yielded ages as young as Neoproterozoic (0.95-1.05 Ga), thus the Pinkie unit is considered to be Neoproterozoic (Kośmińska et al., 2015a). The M1 assemblages and D1 structures are affected by D2 mylonitization (cf. Faehnrich et al., 2016, this meeting). Petrological characterization and Th-U-total Pb chemical monazite dating have been performed on the Pinkie metapelites. These rocks exhibit an apparent inverted Barrovian metamorphic sequence, within which three metamorphic zones have been distinguished: garnet+staurolite+muscovite+biotite, garnet+staurolite+kyanite+muscovite+biotite, garnet+kyanite+muscovite+biotite. The P-T estimates using the QuiG barometry coupled with thermodynamic modelling revealed that the

A New Model of the Early Paleozoic Tectonics and Evolutionary History in the Northern Qinling, China

NASA Astrophysics Data System (ADS)

Dong, Yunpeng; Zhang, Guowei; Yang, Zhao; Qu, Hongjun; Liu, Xiaoming

2010-05-01

The Qinling Orogenic Belt extends from the Qinling Mountains in the west to the Dabie Mountains in the east. It lies between the North China and South China Blocks, and is bounded on the north by the Lushan fault and on the south by the Mianlue-Bashan-Xiangguang fault (Zhang et al., 2000). The Qinling Orogenic Belt itself is divided into the North and South Qinling Terranes by the Shangdan suture zone. Although the Shangdan zone is thought to represent the major suture separating the two blocks, there still exists debate about the timing and mechanism of convergence between these two blocks. For instance, some authors suggested an Early Paleozoic collision between the North China Block and South China Block (Ren et al., 1991; Kroner et al., 1993; Zhai et al., 1998). Others postulated left-lateral strike-slip faulting along the Shangdan suture at ca. 315 Ma and inferred a pre-Devonian collision between the two blocks (Mattauer et al., 1985; Xu et al., 1988). Geochemistry of fine-grained sediments in the Qinling Mountains was used to argue for a Silurian-Devonian collision (Gao et al., 1995). A Late Triassic collision has also been proposed (Sengor, 1985; Hsu et al., 1987; Wang et al., 1989), based on the formation of ultrahigh-pressure metamorphic rocks in the easternmost part of the Qinling Orogenic Belt at ~230 Ma (e.g., Li et al., 1993; Ames et al., 1996). Paleomagnetic data favor a Late Triassic-Middle Jurassic amalgamation of the North China and South China Blocks (Zhao and Coe, 1987; Enkin et al., 1992). It is clear that most authors thought that the Qinling Mountains are a collisional orogen, even they have different methods about the timing of the orogeny. Based on new detailed investigations, we propose a new model of the Early Paleozoic Tectonics and Evolutionary History between the North China and South China Blocks along the Shangdan Suture. The Shangdan suture is marked by a great number of ophiolites, island-arc volcanic rocks and other related rock

Thermomagnetic and thermoelectric properties of semiconductors (PbTe, PbSe) at ultrahigh pressures

NASA Astrophysics Data System (ADS)

Ovsyannikov, Sergey V.; Shchennikov, Vladimir V.

2004-02-01

The longitudinal and transverse thermomagnetic Nernst-Ettingshausen (LNE, TNE) effects and the Maggi-Reghi-Leduc (MRL) effect were measured on PbTe and PbSe micro-samples at ultrahigh pressures upto 20 GPa. Values of the mobility of charge carriers as well as the scattering parameter were estimated both for the low- and high-pressure phase of PbTe and PbSe. At about 3 GPa, the maxima of both Nernst-Ettingshausen effects and magnetoresistance (MR) (and hence of the mobility of charge carriers μ), attributed to the gapless state of PbTe and PbSe were established. The TNE effect was found to be the largest among the effects measured, while the MRL was hardly visible even at the highest mobility values of the charge carriers. The possibilities for using thermomagnetic effects in micro-device technologies are discussed.

High pressure reaction cell and transfer mechanism for ultrahigh vacuum spectroscopic chambers

NASA Astrophysics Data System (ADS)

Nelson, A. E.; Schulz, K. H.

2000-06-01

A novel high pressure reaction cell and sample transfer mechanism for ultrahigh vacuum (UHV) spectroscopic chambers is described. The design employs a unique modification of a commercial load-lock transfer system to emulate a tractable microreactor. The reaction cell has an operating pressure range of <1×10-4 to 1000 Torr and can be evacuated to UHV conditions to enable sample transfer into the spectroscopic chamber. Additionally, a newly designed sample holder equipped with electrical and thermocouple contacts is described. The sample holder is capable of resistive specimen heating to 400 and 800 °C with current requirements of 14 A (2 V) and 25 A (3.5 V), respectively. The design enables thorough material science characterization of catalytic reactions and the surface chemistry of catalytic materials without exposing the specimen to atmospheric contaminants. The system is constructed primarily from readily available commercial equipment allowing its rapid implementation into existing laboratories.

Late Mesoproterozoic to Early Paleozoic history of metamorphic basement from the southeastern Chiapas Massif Complex, Mexico, and implications for the evolution of NW Gondwana

NASA Astrophysics Data System (ADS)

Weber, Bodo; González-Guzmán, Reneé; Manjarrez-Juárez, Román; Cisneros de León, Alejandro; Martens, Uwe; Solari, Luigi; Hecht, Lutz; Valencia, Victor

2018-02-01

In this paper, U-Pb zircon geochronology, Lu-Hf and Sm-Nd isotope systematics, geochemistry and geothermobarometry of metaigneous basement rocks exposed in the southeastern Chiapas Massif Complex are presented. Geologic mapping of the newly defined "El Triunfo Complex" located at the southeastern edge of the Chiapas Massif reveals (1) partial melting of a metamorphic basement mainly constituted by mafic metaigneous rocks (Candelaria unit), (2) an Ediacaran metasedimentary sequence (Jocote unit), and (3) occurrence of massif-type anorthosite. All these units are intruded by undeformed Ordovician plutonic rocks of the Motozintla suite. Pressure and temperature estimates using Ca-amphiboles, plagioclase and phengite revealed prograde metamorphism that reached peak conditions at 650 °C and 6 kbar, sufficient for partial melting under water saturated conditions. Relict rutile in titanite and clinopyroxene in amphibolite further indicate a previous metamorphic event at higher P-T conditions. U-Pb zircon ages from felsic orthogneiss boudins hosted in deformed amphibolite and migmatite yield crystallization ages of 1.0 Ga, indicating that dry granitic protoliths represent remnants of Rodinia-type basement. Additionally, a mid-Tonian ( 920 Ma) metamorphic overprint is suggested by recrystallized zircon from a banded gneiss. Zircon from folded amphibolite samples yield mainly Ordovician ages ranging from 457 to 444 Ma that are indistinguishable from the age of the undeformed Motozintla plutonic suite. Similar ages between igneous- and metamorphic- zircon suggest a coeval formation during a high-grade metamorphic event, in which textural discrepancies are explained in terms of differing zircon formation mechanisms such as sub-solidus recrystallization and precipitation from anatectic melts. In addition, some amphibolite samples contain inherited zircon yielding Stenian-Tonian ages around 1.0 Ga. Lu-Hf and Sm-Nd isotopes and geochemical data indicate that the protoliths of

Unravelling the pre-Variscan evolution of the Habach terrane (Tauern Window, Austria) by U-Pb SHRIMP zircon data

NASA Astrophysics Data System (ADS)

Eichhorn, Roland; Loth, Georg; Kennedy, Allen

2001-08-01

The U-Pb SHRIMP age determinations of zircons from the Habach terrane (Tauern Window, Austria) reveal a complex evolution of this basement unit, which is exposed in the Penninic domain of the Alpine orogen. The oldest components are found in zircons of a metamorphosed granitoid clast, of a migmatitic leucosome, and of a meta-rhyolitic (Variscan) tuff which bear cores of Archean age. The U-Pb ages of discordant zircon cores of the same rocks range between 540 and 520 Ma. It is assumed that the latter zircons were originally also of Archean origin and suffered severe lead loss, whilst being incorporated into Early-Cambrian volcanic arc magmas. The provenance region of the Archean (2.64-2.06 Ga) zircons is assumed to be a terrane of Gondwana affinity: i.e., the West African craton (Hoggar Shield, Reguibat Shield). The Caledonian metamorphism left a pervasive structural imprint in amphibolite facies on rocks of the Habach terrane; it is postdated by discordant zircons of a migmatitic leucosome at <440 Ma (presumably ca. 420 Ma). Alpine and Variscan upper greenschist- to amphibolite-facies conditions caused partial lead loss in zircons of a muscovite gneiss ('white schist') only, where extensive fluid flow and brittle deformation due to its position near a nappe-sole thrust enhanced the grains' susceptibility to isotopic disturbance. The Habach terrane - an active continental margin with ensialic back-arc development - showed subduction-induced magmatic activity approx. between 550 and 507 Ma. Back-arc diorites and arc basalts were intruded by ultramafic sills and subsequently by small patches of mantle-dominated unaltered and (in the vicinity of a major tungsten deposit) altered granitoids. Fore-arc (shales) and back-arc (greywackes, cherts) basin sediments as well as arc and back-arc magmatites were not only nappe-stacked by the Caledonian compressional regime closing the presumably narrow oceanic back-arc basin and squeezing mafic to ultramafic cumulates out of high

Siberia, the wandering northern terrane, and its changing geography through the Palaeozoic

NASA Astrophysics Data System (ADS)

Cocks, L. Robin M.; Torsvik, Trond H.

2007-05-01

The old terrane of Siberia occupied a very substantial area in the centre of today's political Siberia and also adjacent areas of Mongolia, eastern Kazakhstan, and northwestern China. Siberia's location within the Early Neoproterozoic Rodinia Superterrane is contentious (since few if any reliable palaeomagnetic data exist between about 1.0 Ga and 540 Ma), but Siberia probably became independent during the breakup of Rodinia soon after 800 Ma and continued to be so until very near the end of the Palaeozoic, when it became an integral part of the Pangea Supercontinent. The boundaries of the cratonic core of the Siberian Terrane (including the Patom area) are briefly described, together with summaries of some of the geologically complex surrounding areas, and it is concluded that all of the Palaeozoic underlying the West Siberian Basin (including the Ob-Saisan Surgut area), Tomsk Terrane, Altai-Sayan Terranes (including Salair, Kuznetsk Alatau, Batenov, Kobdin and West Sayan), Ertix Terrane, Barguzin Terrane, Tuva-Mongol Terrane, Central Mongolia Terrane Assemblage, Gobi Altai and Mandalovoo Terranes, Okhotsk Terrane and much of the Verkhoyansk-Kolyma region all formed parts of peri-Siberia, and thus rotated with the main Siberian Craton as those areas were progressively accreted to the main Siberian Terrane at various times during the latest Neoproterozoic and Palaeozoic. The Ertix Terrane is a new term combining what has been termed the "Altay Terrane" or "NE Xinjiang" area of China, and the Baytag, Baaran and Bidz terranes of Mongolia. The Silurian Tuvaella brachiopod fauna is restricted only to today's southern parts of peri-Siberia. Thus, allowing for subsequent rotation, the fauna occurs only in the N of the Siberian Terrane, and, as well as being a helpful indicator of what marginal terranes made up peri-Siberia, is distinctive as being the only Silurian fauna known from northern higher latitudes globally. In contrast, the other terranes adjacent to peri

Flavor characterization of sugar-added pennywort (Centella asiatica L.) juices treated with ultra-high pressure and thermal processes.

PubMed

Apichartsrangkoon, Arunee; Wongfhun, Pronprapa; Gordon, Michael H

2009-01-01

The flavor characteristics of pennywort juices with added sugar treated by ultra-high pressure, pasteurization, and sterilization were investigated using solid phase microextraction combined with gas chromatography-mass spectrometry. It was found that sesquiterpene hydrocarbons comprised the major class of volatile components present and the juices had a characteristic aroma due to the presence of volatiles including beta-caryophyllene and humulene and alpha-copaene. In comparison with heated juices, HPP-treated samples could retain more volatile compounds such as linalool and geraniol similar to those present in fresh juice, whereas some volatiles such as alpha-terpinene and ketone class were apparently formed by thermal treatment. All processing operations produced juice that was not significantly different in the concentration of total volatiles. Practical Application: Pennywort juice is considered a nutraceutical drink for health benefits. Therefore, to preserve all aroma and active components in this juice, a nonthermal process such as ultra-high pressure should be a more appropriate technique for retention of its nutritive values than pasteurization and sterilization.

In situ study of maize starch gelatinization under ultra-high hydrostatic pressure using X-ray diffraction.

PubMed

Yang, Zhi; Gu, Qinfen; Hemar, Yacine

2013-08-14

The gelatinization of waxy (very low amylose) and high-amylose maize starches by ultra-high hydrostatic pressure (up to 6 GPa) was investigated in situ using synchrotron X-ray powder diffraction on samples held in a diamond anvil cell (DAC). The starch pastes, made by mixing starch and water in a 1:1 ratio, were pressurized and measured at room temperature. X-ray diffraction pattern showed that at 2.7 GPa waxy starch, which displayed A-type XRD pattern at atmospheric pressure, exhibited a faint B-type-like pattern. The B-type crystalline structures of high-amylose starch were not affected even when 1.5 GPa pressure was applied. However, both waxy and high-amylose maize starches can be fully gelatinized at 5.9 GPa and 5.1 GPa, respectively. In the case of waxy maize starch, upon release of pressure (to atmospheric pressure) crystalline structure appeared as a result of amylopectin aggregation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Silurian Gastropoda from the Alexander terrane, southeast Alaska

USGS Publications Warehouse

Rohr, D.M.; Blodgett, R.B.

2008-01-01

Gastropods are described from Ludlow-age strata of the Heceta Limestone on Prince of Wales Island, southeast Alaska. They are part of a diverse megabenthic fauna of the Alexander terrane, an accreted terrane of Siberian or Uralian affinities. Heceta Limestone gastropods with Uralian affinities include Kirkospira glacialis, which closely resembles "Pleurotomaria" lindstromi Oehlert of Chernyshev, 1893, Retispira cf. R. volgulica (Chernyshev, 1893), and Medfracaulus turriformis (Chernyshev, 1893). Medfracaulus and similar morphotypes such as Coelocaulus karlae are unknown from rocks that are unquestionably part of the North American continent (Laurentia) during Late Silurian time. Beraunia is previously known only from the Silurian of Bohemia. Pachystrophia has previously been reported only from western North American terranes (Eastern Klamath, York, and Farewell terranes) and Europe. Bathmopterus Kirk, 1928, is resurrected and is only known from the Silurian of southeast Alaska. Newly described taxa include Hecetastoma gehrelsi n. gen. and n. sp. and Baichtalia tongassensis n. gen. and n. sp. ??2008 The Geological Society of America.

Geologic Map of the Weaverville 15' Quadrangle, Trinity County, California

USGS Publications Warehouse

Irwin, William P.

2009-01-01

The Weaverville 15' quadrangle spans parts of five generally north-northwest-trending accreted terranes. From east to west, these are the Eastern Klamath, Central Metamorphic, North Fork, Eastern Hayfork, and Western Hayfork terranes. The Eastern Klamath terrane was thrust westward over the Central Metamorphic terrane during early Paleozoic (Devonian?) time and, in Early Cretaceous time (approx. 136 Ma), was intruded along its length by the massive Shasta Bally batholith. Remnants of overlap assemblages of the Early Cretaceous (Hauterivian) Great Valley sequence and the Tertiary Weaverville Formation cover nearly 10 percent of the quadrangle. The base of the Eastern Klamath terrane in the Weaverville quadrangle is a peridotite-gabbro complex that probably is correlative to the Trinity ophiolite (Ordovician), which is widely exposed farther north beyond the quadrangle. In the northeast part of the Weaverville quadrangle, the peridotite-gabbro complex is overlain by the Devonian Copley Greenstone and the Mississippian Bragdon Formation. Where these formations were intruded by the Shasta Bally batholith, they formed an aureole of gneissic and other metamorphic rocks around the batholith. Westward thrusting of the Eastern Klamath terrane over an adjacent body of mafic volcanic and overlying quartzose sedimentary rocks during Devonian time formed the Salmon Hornblende Schist and the Abrams Mica Schist of the Central Metamorphic terrane. Substantial beds of limestone in the quartzose sedimentary unit, generally found near the underlying volcanic rock, are too metamorphosed for fossils to have survived. Rb-Sr analysis of the Abrams Mica Schist indicates a metamorphic age of approx. 380 Ma. West of Weavervillle, the Oregon Mountain outlier of the Eastern Klamath terrane consists mainly of Bragdon Formation(?) and is largely separated from the underlying Central Metamorphic terrane by serpentinized peridotite that may be a remnant of the Trinity ophiolite. The North Fork

Effect of chemical composition on the electrical conductivity of gneiss at high temperatures and pressures

NASA Astrophysics Data System (ADS)

Dai, Lidong; Sun, Wenqing; Li, Heping; Hu, Haiying; Wu, Lei; Jiang, Jianjun

2018-03-01

The electrical conductivity of gneiss samples with different chemical compositions (WA = Na2O + K2O + CaO = 7.12, 7.27 and 7.64 % weight percent) was measured using a complex impedance spectroscopic technique at 623-1073 K and 1.5 GPa and a frequency range of 10-1 to 106 Hz. Simultaneously, a pressure effect on the electrical conductivity was also determined for the WA = 7.12 % gneiss. The results indicated that the gneiss conductivities markedly increase with total alkali and calcium ion content. The sample conductivity and temperature conform to an Arrhenius relationship within a certain temperature range. The influence of pressure on gneiss conductivity is weaker than temperature, although conductivity still increases with pressure. According to various ranges of activation enthalpy (0.35-0.52 and 0.76-0.87 eV) at 1.5 GPa, two main conduction mechanisms are suggested that dominate the electrical conductivity of gneiss: impurity conduction in the lower-temperature region and ionic conduction (charge carriers are K+, Na+ and Ca2+) in the higher-temperature region. The electrical conductivity of gneiss with various chemical compositions cannot be used to interpret the high conductivity anomalies in the Dabie-Sulu ultrahigh-pressure metamorphic belt. However, the conductivity-depth profiles for gneiss may provide an important constraint on the interpretation of field magnetotelluric conductivity results in the regional metamorphic belt.

Ultra-high pressure water jetting for coating removal and surface preparation

NASA Technical Reports Server (NTRS)

Johnson, Spencer T.

1995-01-01

This paper shall examine the basics of water technology with particular attention paid to systems currently in use and some select new applications. By providing an overview of commercially available water jet systems in the context of recent case histories, potential users may evaluate the process for future applications. With the on going introduction of regulations prohibiting the use of chemical paint strippers, manual scrapping and dry abrasive media blasting, the need for an environmentally compliant coating removal process has been mandated. Water jet cleaning has been a traditional part of many industrial processed for year, although it has only been in the last few years that reliable pumping equipment capable of ultra-high pressure operation have become available. With the advent of water jet pumping equipment capable of sustaining pressures in excess of 36,000 psi. there has been shift away from lower pressure, high water volume systems. One of the major factors in driving industry to seek higher pressures is the ability to offer higher productivity rates while lowering the quantity of water used and subsequently reprocessed. Among benefits of the trend toward higher pressure/lower volume systems is the corresponding reduction in water jet reaction forces making hand held water jetting practical and safe. Other unique applications made possible by these new generation pumping systems include the use of alternative fluids including liquid ammonia for specialized and hazardous material removal applications. A review of the equipment used and the required modifications will be presented along with the conclusions reached reached during this test program.

Dry Snow Metamorphism

DTIC Science & Technology

2012-09-19

behavior of snow during metamorphism and grain sintering using mathematical models. 2 Approach Our approach involved the collection and...examination of both types of specimens at various stages of metamorphism using the SEM and micro-CT. More specifically, the above approach involved...than 10ºC·m-1). 5. High-resolution images and X-ray spectra of snow specimens at various metamorphism stages were obtained using an SEM and EDS. 6

Two types of gneisses associated with eclogite at Shuanghe in the Dabie terrane: carbon isotope, zircon U-Pb dating and oxygen isotope

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Gong, Bing; Zhao, Zi-Fu; Fu, Bin; Li, Yi-Liang

2003-10-01

There are two types of gneisses, biotite paragneiss and granitic orthogneiss, to be closely associated with UHP eclogite at Shuanghe in the Dabie terrane. Both concentration and isotope composition of bulk carbon in apatite and host gneisses were determined by the EA-MS online technique. Structural carbonate within the apatite was detected by the XRD and FTIR techniques. Significant 13C-depletion was observed in the apatite with δ13C values of -28.6‰ to -22.3‰ and the carbon concentrations of 0.70-4.98 wt.% CO 2 despite a large variation in δ18O from -4.3‰ to +10.6‰ for these gneisses. There is significant heterogeneity in both δ13C and δ18O within the gneisses on the scale of several tens meters, pointing to the presence of secondary processes after the UHP metamorphism. Considerable amounts of carbonate carbon occur in some of the gneisses that were also depleted in 13C primarily, but subjected to overprint of 13C-rich CO 2-bearing fluid after the UHP metamorphism. The 13C-depleted carbon in the gneisses is interpreted to be inherited from their precursors that suffered meteoric-hydrothermal alteration before plate subduction. Both low δ13C values and structural carbonate in the apatite suggest the presence of 13C-poor CO 2 in the UHP metamorphic fluid. The 13C-poor CO 2 is undoubtedly derived from oxidation of organic matter in the subsurface fluid during the prograde UHP metamorphism. Zircons from two samples of the granitic orthogneiss exhibit low δ18O values of -4.1‰ to -1.1‰, demonstrating that its protolith was significantly depleted in 18O prior to magma crystallization. U-Pb discordia datings for the 18O-depleted zircons yield Neoproterozoic ages of 724-768 Ma for the protolith of the granitic orthogneiss, consistent with protolith ages of most eclogites and orthogneisses from the other regions in the Dabie-Sulu orogen. Therefore, the meteoric-hydrothermal alteration is directly dated to occur at mid-Neoproterozoic, and may be correlated

Tectono-metamorphic evolution of the Chinese Altai, central Asia: new insights from microstructures

NASA Astrophysics Data System (ADS)

Jiang, Yingde; Zhang, Jian; Schulmann, Karel; Sun, Min; Zhao, Guochun

2013-04-01

The Altai Orogen, extending from Russia, through northeast Kazakhstan and northwest China, to western and southern Mongolia, occupies a pivotal position in understanding the accretionary process of the Central Asian Orogenic Belt and has drawn much attention in recent years. However, its orogenic evolution remains poorly constrained, because previous studies were mainly focused on the geochronological and geochemical signatures and much less work has been done on metamorphic and structural studies. Metamorphic rocks widely occur in the southern Altai Range and have previously been separated into high-T/low-P and medium-P types. Recent studies demonstrated that these two kinds of rocks may have similar protoliths, i.e. early Paleozoic arc-related assemblages, but experienced different metamorphic histories. The development of biotite, garnet, staurolite and kyanite metamorphic zonal sequences in the low- to medium- grade rocks, demonstrate typical medium-pressure metamorphism that has been suggested as a major consequence of the orogenesis. The high-T/low-P metamorphism, represented by the growth of garnet+cordierite+sillimanite+k-feldspar and was accompanied by extensive anatexis, remains its tectonic significance poorly constrained. Field structural investigation in the Chinese Altai reveals that the high-T/low-P metamorphic rocks have major S-L fabrics (defined by the strongly aligned biotite and sillimanite) exactly in the same orientations as those developed in the associated medium-P grade rocks. Geochronological studies constrain the major fabrics in both kinds of rocks developed during mid-Devonian, coeval with the strong magmatism in the region. Micro-structural investigation on both kinds of rocks show similar prograde metamorphic history featured by clockwise P-T path evolution. Phase equilibrium modeling in the MnNCKFMASH system indicates that the development of major fabrics in the medium-P metamorphic rocks mainly recorded the notable increase of

New petrological and age data from the eclogite province in the central segment of the Greenlandic Caledonides

NASA Astrophysics Data System (ADS)

Nagel, Thorsten; Fassmer, Kathrin; Froitzheim, Niko; Fonseca, Raul; Sprung, Peter

2017-04-01

The Caledonian orogen in northeastern Greenland is a 1200 km long, west-vergent nappe pile mirroring the much better explored Caledonides in Scandinavia. The Greenlandic orogen has traditionally been viewed as the retro-wedge of the Scandinavian Caledonides, which is generally accepted to be the result of west-directed subduction of the Iapetus oceanic realm and the Baltic continental margin. This concept, however, is challenged by the finding of widely distributed high-pressure metamorphism as well as the large amount of horizontal shortening accommodated in the Greenlandic nappe pile (Gasser 2014, and references therein). While eclogites in Liverpool Land in the very south have been interpreted to belong to a window into Baltica, the vast domains of eclogite-bearing basement in the central segment of the orogen are attributed to the Lauretian continental margin. Existing ages for high-pressure metamorphism in this area using U-Pb-zircon and Sm-Nd-garnet dating scatter at 420-390 Ma with an exceptionally young age of 370-330 Ma found for the so far only ultrahigh-pressure location in a very internal position of the orogen (e.g. Gilotti et al. 2004). Eclogite-facies metamorphism in Greenland seems thus coeval to or even younger than the main Scandian orogeny in Scandinavia. However, the relatively high temperatures of metamorphism leave room for the interpretation of the Sm-Nd ages as cooling ages. We present petrologic and Lu-Hf-garnet-age data from three locations in the central eclogite province in Greenland and discuss the implications for tectonic scenarios. Investigated rocks are high-temperature eclogites/high-pressure mafic granulites, and garnet pyroxenites. Samples from the well-known location Danmarkshavn record ultra-high-pressure metamorphic conditions by means of SiO2-exsolutions in clinopyroxene and thermobarometric results. An eclogite yielded a Lu-Hf garnet-whole-rock age of 360 Ma thus confirming the existing young age for ultrahigh-pressure

Role of DNA protection and repair in resistance of Bacillus subtilis spores to ultrahigh shock pressures simulating hypervelocity impacts.

PubMed

Moeller, Ralf; Horneck, Gerda; Rabbow, Elke; Reitz, Günther; Meyer, Cornelia; Hornemann, Ulrich; Stöffler, Dieter

2008-11-01

Impact-induced ejections of rocks from planetary surfaces are frequent events in the early history of the terrestrial planets and have been considered as a possible first step in the potential interplanetary transfer of microorganisms. Spores of Bacillus subtilis were used as a model system to study the effects of a simulated impact-caused ejection on rock-colonizing microorganisms using a high-explosive plane wave setup. Embedded in different types of rock material, spores were subjected to extremely high shock pressures (5 to 50 GPa) lasting for fractions of microseconds to seconds. Nearly exponential pressure response curves were obtained for spore survival and linear dependency for the induction of sporulation-defective mutants. Spores of strains defective in major small, acid-soluble spore proteins (SASP) (alpha/beta-type SASP) that largely protect the spore DNA and spores of strains deficient in nonhomologous-end-joining DNA repair were significantly more sensitive to the applied shock pressure than were wild-type spores. These results indicate that DNA may be the sensitive target of spores exposed to ultrahigh shock pressures. To assess the nature of the critical physical parameter responsible for spore inactivation by ultrahigh shock pressures, the resulting peak temperature was varied by lowering the preshock temperature, changing the rock composition and porosity, or increasing the water content of the samples. Increased peak temperatures led to increased spore inactivation and reduced mutation rates. The data suggested that besides the potential mechanical stress exerted by the shock pressure, the accompanying high peak temperatures were a critical stress parameter that spores had to cope with.

Nature and geodynamic setting of the protoliths of the UHP metamorphic Complex and migmatites in Bixiling area, the Dabie Orogen, China

NASA Astrophysics Data System (ADS)

Li, H.; Jahn, B.; Wang, D.; Yu, H.; Liu, Z.; Hou, G.

2013-12-01

As the largest coesite-bearing mafic-ultramafic body in the Dabie-Sulu orogen, the Bixiling Complex is composed of meta-ultramafic rocks, MgAl-rich eclogites and FeTi-rich eclogites. The FeTi-rich eclogites are further divided into low-Si-high-Fe type (Type I) and high-Si-low-Fe type (Type II) according to their mineral assemblages and bulk chemical composition. Field, petrographic, petrological and geochemical characteristics of these rocks, although suffered an ultra-high pressure metamorphism, still show a magmatic differentiation process among the protoliths of the meta-ultramafic rocks, MgAl-rich eclogites and Type I FeTi-rich eclogites. A small degree of lower crustal contamination occurred during their magma chamber process. Amphibolite is widespread in the periphery of the complex. Non-foliation and fine-grained texture are their obvious characteristics. Geochemical and isotopic affinities suggest that the amphibolites represent a product of complete retrogression from type II FeTi-rich eclogites. The UHP complex is enclosed in granitic gneisses, which variably include two-mica plagioclase gneiss, epidote two-mica plagioclase gneiss, or white-mica plagioclase gneiss. They all show TTG, especially trondjhemitic composition. A migmatite outcrop was found near the northeastern end of the complex. The migmatites consist of dark colored, non-foliated amphibolites and light-colored, fine-grained trondhjemitic gneisses. Field occurrences, microstructures observed under optical microscope and SEM, Sr-Nd isotopic data suggest an origin of partial melting. Chemical composition of two stages of amphiboles occurred in both the amphibolites and the trondhjemitic gneisses also imply a partial melting process occurred. Trace element, Sr-Nd isotope and SHRIMP zircon U-Pb dating of MgAl-rich eclogite, amphibolites and trondhjemite suggest that the migmatites represent a partial melting of crustal materials at about 780Ma, possibly accompanied by the coeval emplacement of a

The dehydration, rehydration and tectonic setting of greenstone belts in a portion of the northern Kaapvaal Craton, South Africa

NASA Technical Reports Server (NTRS)

Vanreenen, D. D.; Barton, J. M., Jr.; Roering, C.; Vanschalkwyk, J. C.; Smit, C. A.; Debeer, J. D.; Stettler, E. H.

1986-01-01

High-grade gneiss terranes and low-grade granite-greenstone terranes are well known in several Archaean domains. The geological relationship between these different crustal regions, however, is still controversial. One school of thought favors fundamental genetic differences between high-grade and low-grade terranes while others argue for a depth-controlled crustal evolution. The detailed examination of well-exposed Archaean terranes at different metamorphic grades, therefore, is not only an important source of information about the crustal levels exposed, but also is critical to the understanding of the possible tectonic and metamorphic evolution of greenstone belts with time. Three South African greenstone belts are compared.

Near-isothermal conditions in the middle and lower crust induced by melt migration.

PubMed

Depine, Gabriela V; Andronicos, Christopher L; Phipps-Morgan, Jason

2008-03-06

The thermal structure of the crust strongly influences deformation, metamorphism and plutonism. Models for the geothermal gradient in stable crust predict a steady increase of temperature with depth. This thermal structure, however, is incompatible with observations from high-temperature metamorphic terranes exhumed in orogens. Global compilations of peak conditions in high-temperature metamorphic terranes define relatively narrow ranges of peak temperatures over a wide range in pressure, for both isothermal decompression and isobaric cooling paths. Here we develop simple one-dimensional thermal models that include the effects of melt migration. These models show that long-lived plutonism results in a quasi-steady-state geotherm with a rapid temperature increase in the upper crust and nearly isothermal conditions in the middle and lower crust. The models also predict that the upward advection of heat by melt generates granulite facies metamorphism, and widespread andalusite-sillimanite metamorphism in the upper crust. Once the quasi-steady-state thermal profile is reached, the middle and lower crust are greatly weakened due to high temperatures and anatectic conditions, thus setting the stage for gravitational collapse, exhumation and isothermal decompression after the onset of plutonism. Near-isothermal conditions in the middle and lower crust result from the thermal buffering effect of dehydration melting reactions that, in part, control the shape of the geotherm.

The case for simultaneous deformation, metamorphism and plutonism: an example from Proterozoic rocks in central Arizona

NASA Astrophysics Data System (ADS)

Karlstrom, K. E.; Williams, M. L.

1995-01-01

The syntectonic 1.70 Ga Crazy Basin Monzogranite provides an example of the complex spatial and temporal interactions between metamorphism, deformation, and plutonism. Synchronous plutonism and deformation is indicated by syn-shortening dikes, sills, and veins; parallel magmatic and solid state fabrics; fabrics in xenoliths; and a foliation triple point. Synchronous plutonism and metamorphism is indicated by a systematic increase from 400 °C to 630 °C towards the pluton at a constant pressure of 300 MPa (3 kb). Temperatures are consistent with a conductive cooling model in which a 700 °C pluton was emplaced into country rocks undergoing greenschist facies regional metamorphism. Synchronous deformation and metamorphism is indicated by porphyroblast inclusion geometries that document the synmetamorphic development of the S2 cleavage. The pluton was emplaced adjacent to the Shylock shear zone during progressive shortening. Emplacement of granite as NE-trending sheets was facilitated by temporal partitioning of transpressional convergence into strike-slip and dip-slip components. At the scale of the pluton's aureole and on the relatively rapid time scale of 10 3-10 6 y, regional deformation and metamorphism were punctuated by thermal softening and increased diffusion rates. Data suggests that accretion of Proterozoic arcs in Arizona involved diachronous pluton-enhanced deformation and associated high temperature-low pressure regional metamorphism.

Oxygen Isotope and Microtextural Evidence for Fluctuations in Fluid Pressure During Contact Metamorphism, Alta Aureole, Utah, USA

NASA Astrophysics Data System (ADS)

Bowman, J. R.; Valley, J. W.; Kita, N.

2006-12-01

Thin section-scale textures record a detailed history of prograde and retrograde reactions in the periclase (Per) zone of the Alta Stock aureole. New ion microprobe (SIMS) measurements (10 micron spot, ±0.2 permil, 1sd) of the oxygen isotope compositions of the carbonates preserving these textures provide evidence for at least two cycles of oscillation of fluid pressure (Pfl) between lithostatic (PL) and hydrostatic (Phyd) conditions during evolution of the inner aureole. Infiltration of water-rich fluids during prograde metamorphism converted dolomite (Dol) to Per + calcite (Cal) marble and caused significant 18O/16O depletion in the Dol protolith (Initial δ18O (Cal) > +25 permil), producing Cal with δ18O values of +11 permil. The SIMS values approximate oxygen isotope exchange equilibrium with the Alta stock, indicating that infiltrating fluids were likely magmatic. Exsolution of fluid from the crystallizing magma, coupled with geothermometry from the periclase zone marbles, requires Pfl> PL. Horizontally-oriented expansion cracks filled with brucite (Br) extend from Br pseudomorphs after periclase, and cut retrograde Dol that partially to completely rims the Br pseudomorphs. This earlier retrograde Dol is significantly depleted in 18O/16O relative to matrix Cal, with δ18O of +5 to +7.1 permil. These lower δ18O values indicate that meteoric water infiltrated into the Per marbles during cooling and resulting partial back reaction of Per + Cal to Dol, prior to the hydration of the remaining Per to Br. Influx of meteoric water requires sufficient increase in permeability to permit surface- derived meteoric water to penetrate to the estimated 4.5 km depth of this structural level of the Alta aureole, and suggests a resulting decrease in Pfl to hydrostatic pressure conditions. The horizontally-oriented expansion cracks associated with the Br pseudomorphs indicate that sub-vertical expansion accompanied hydration of Per to Br, requiring that Pfl increase again to

PREFACE: Rheology and Elasticity Studies at Ultra-High Pressures and Temperatures

NASA Astrophysics Data System (ADS)

Liu, Haozhe; Wenk, Hans-Rudolf; Duffy, Thomas S.

2006-06-01

One of the major goals of geophysical research is to understand deformation in the deep Earth. The COMPRES (Consortium for Materials Properties Research in Earth Sciences) workshop on `Rheology and Elasticity Studies at Ultra-High Pressures and Temperatures' was held on 21-23 October 2005 at the Advanced Photon Source, Argonne National Laboratory, organized by Haozhe Liu, Hans-Rudolf Wenk and Thomas S Duffy, and provided an opportunity to assemble more than 50 scientists from six countries. Experts in diamond anvil cell (DAC) design, large-volume high-pressure apparatus and data analysis defined the current state of ultra-high pressure deformation studies and explored initiatives to push the technological frontier. The DAC, when used in radial diffraction geometry, emerges as a powerful tool for investigation of plasticity and elasticity of materials at high pressures. More information regarding this workshop can be found at the website: http://www.hpcat.aps.anl.gov/Hliu/Workshop/Index1.htm. In this special issue of Journal of Physics: Condensed Matter, 17 manuscripts review the state-of-the-art and we hope they will stimulate researchers to participate in this field and take it forward to a new level. A major incentive for high-pressure research has been the need of geophysicists to understand composition, physical properties and deformation in the deep Earth in order to interpret the macroscopically observed seismic anisotropy. In the mantle and core, materials deform largely in a ductile manner at low stresses and strain rates. From observational inferences and experiments at lower pressures, it is considered plausible that deformation occurs in the field of dislocation creep or diffusion creep and deformation mechanisms depend in a complex way on stress, strain rate, pressure, temperature, grain size and hydration state. With novel apparatus such as the rotational Drickamer press or deformation DIA (D-DIA) multianvil apparatus, large volumes (approximately 10

X-ray diffraction investigation of amorphous calcium phosphate and hydroxyapatite under ultra-high hydrostatic pressure

NASA Astrophysics Data System (ADS)

Lam, Elisa; Gu, Qinfen; Swedlund, Peter J.; Marchesseau, Sylvie; Hemar, Yacine

2015-11-01

The changes in the crystal structures of synthetically prepared amorphous calcium phosphate (ACP) and hydroxyapatite (HAP) in water (1:1 mass ratio) were studied by synchrotron X-ray diffraction (XRD) under ultra-high hydrostatic pressures as high as 2.34 GPa for ACP and 4 GPa for HAP. At ambient pressure, the XRD patterns of the ACP and HAP samples in capillary tubes and their environmental scanning electron micrographs indicated amorphous and crystalline characteristics for ACP and HAP, respectively. At pressures greater than 0.25 GPa, an additional broad peak was observed in the XRD pattern of the ACP phase, indicating a partial phase transition from an amorphous phase to a new high-pressure amorphous phase. The peak areas and positions of the ACP phase, as obtained through fitting of the experimental data, indicated that the ACP exhibited increased pseudo-crystalline behavior at pressures greater than 0.96 GPa. Conversely, no structural changes were observed for the HAP phase up to the highest applied pressure of 4 GPa. For HAP, a unit-cell reduction during compression was evidenced by a reduction in both refined lattice parameters a and c. Both ACP and HAP reverted to their original structures when the pressure was fully released to ambient pressure.

Timing and duration of Variscan high-pressure metamorphism in the French Massif Central: A multimethod geochronological study from the Najac Massif

NASA Astrophysics Data System (ADS)

Lotout, Caroline; Pitra, Pavel; Poujol, Marc; Anczkiewicz, Robert; Van Den Driessche, Jean

2018-05-01

Accurate dating of eclogite-facies metamorphism is of paramount importance in order to understand the tectonic evolution of an orogen. An eclogite sample from the Najac Massif (French Massif Central, Variscan belt) displays a zircon-bearing garnet-omphacite-amphibole-rutile-quartz peak assemblage. Pseudosection modeling suggests peak pressure conditions of 15-20 kbar, 560-630 °C. Eclogite-facies garnet displays Lu-enriched cores and Sm-rich rims and yields a Lu-Hf age of 382.8 ± 1.0 Ma and a Sm-Nd age of 376.7 ± 3.3 Ma. The ages are interpreted as marking the beginning of the prograde garnet growth during the initial stages of the eclogite-facies metamorphism, and the high-pressure (and temperature) peak reached by the rock, respectively. Zircon grains display chondrite-normalized REE spectra with variably negative, positive or no Eu anomalies and are characterized by either enriched or flat HREE patterns. However, they yield a well constrained in situ LA-ICP-MS U-Pb age of 385.5 ± 2.3 Ma, despite this REE pattern variability. Zr zonation in garnet, Y content in zircon and the diversity of zircon HREE spectra may suggest that zircon crystallized prior to and during incipient garnet growth on the prograde P-T path, recording the initial stages of the eclogite-facies conditions. Consequently, the zircon age of 385.5 ± 2.3 Ma, comparable within error with the Lu-Hf age obtained on garnet, is interpreted as dating the beginning of the eclogite-facies metamorphism. Accordingly, the duration of the prograde part of the eclogite-facies event is estimated at 6.1 ± 4.3 Myr. Subsequent exhumation is constrained by an apatite U-Pb age at 369 ± 13 Ma.

Inheritance, Variscan tectonometamorphic evolution and Permian to Mesozoic rejuvenations in the metamorphic basement complexes of the Romanian Carpathians revealed by monazite microprobe geochronology

NASA Astrophysics Data System (ADS)

Săbău, Gavril; Negulescu, Elena

2014-05-01

Monazite U-Th-Pb chemical dating reaches an acceptable compromise between precision and accuracy on one side, and spatial resolution and textural constraints on the other side. Thus it has a powerful potential in testing the coherence of individual metamorphic basement units, and enabling correlations among them. Yet, sensitivity and specificity issues in monazite response to thermotectonic events, especially in the case of superposed effects, remain still unclear. Monazite dating at informative to detailed scale in the main metamorphic basement units of the Carpathians resulted in complex age spectra. In the main, the spectra are dominated by the most pervasive thermal and structural overprint, as checked against independent geochronological data. Post-peak age resetting is mostly present, but statistically subordinate. Resetting in case of superposed events is correlated with the degree of textural and paragenetic overprinting, inheritances being always indicated by more or less well-defined age clusters. The lack of relict ages correlating with prograde structural and porphyroblast zonation patterns is indicative for juvenile formations. Age data distribution in the Carpathians allowed distinction of pre-Variscan events, syn-metamorphic Variscan tectonic stacking of juvenile and reworked basement, post-Variscan differential tectonic uplift, as well as prograde metamorphic units ranging down to Upper Cretaceous ages. In the South Carpathians, the Alpine Danubian domain consists of several Variscan and Alpine thrust sheets containing a metamorphic complex dominated by Upper Proterozoic to Lower Cambrian metamorphic and magmatic ages (Lainici-Păiuş), and several complexes with metamorphic overprints ranging from Carboniferous to Lower Permian. Any correlation among these units, as well as geotectonic models placing a Lower Paleozoic oceanic domain between pre-existing Lainici-Păiuş and Drăgşan terranes are precluded by the age data. Other basement of the

Modelling Metamorphism by Abstract Interpretation

NASA Astrophysics Data System (ADS)

Dalla Preda, Mila; Giacobazzi, Roberto; Debray, Saumya; Coogan, Kevin; Townsend, Gregg M.

Metamorphic malware apply semantics-preserving transformations to their own code in order to foil detection systems based on signature matching. In this paper we consider the problem of automatically extract metamorphic signatures from these malware. We introduce a semantics for self-modifying code, later called phase semantics, and prove its correctness by showing that it is an abstract interpretation of the standard trace semantics. Phase semantics precisely models the metamorphic code behavior by providing a set of traces of programs which correspond to the possible evolutions of the metamorphic code during execution. We show that metamorphic signatures can be automatically extracted by abstract interpretation of the phase semantics, and that regular metamorphism can be modelled as finite state automata abstraction of the phase semantics.

Coupling of Oceanic and Continental Crust During Eocene Eclogite-Facies Metamorphism: Evidence From the Monte Rosa Nappe, Western Alps, Italy

NASA Astrophysics Data System (ADS)

Lapen, T. J.; Johnson, C. M.; Baumgartner, L. P.; Skora, S.; Mahlen, N. J.; Beard, B. L.

2006-12-01

Subduction of continental crust to HP-UHP metamorphic conditions requires overcoming density contrasts that are unfavorable to deep burial, whereas exhumation of these rocks can be reasonably explained through buoyancy-assisted transport in the subduction channel to more shallow depths. In the western Alps, both continental and oceanic lithosphere has been subducted to eclogite-facies metamorphic conditions. The burial and exhumation histories of these sections of lithosphere bear directly on the dynamics of subduction and the stacking of units within the subduction channel. We address the burial history of the continental crust with high precision U-Pb rutile and Lu-Hf garnet geochronology of the eclogite-facies Monte Rosa nappe (MR), western Alps, Italy. U-Pb rutile ages from quartz-carbonate-white mica-rutile veins that are hosted within eclogite and schist of the MR, Gressoney Valley, Italy, indicate that it was at eclogite-facies metamorphic conditions at 42.6 +/- 0.6 Ma. The sample area (Indren glacier, Furgg zone; Dal Piaz, 2001) consists of eclogite boudins that are surrounded by micaceous schist. Associated with the eclogite and schist are quartz-carbonate-white mica-rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins occurred at eclogite-facies metamorphic conditions (480-570°C, >1.3-1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. Lu-Hf geochronology of garnet from a chloritoid-talc-garnet-phengite-quartz-calcite-pyrite - chalcopyrite bearing boudin within talc-chloritoid whiteschists of the MR, Val d'Ayas, Italy (Chopin and Monie, 1984; Pawlig, 2001) yields an age of 40.54 +/- 0.36 Ma. The talc-chloritoid whiteschists from the area record pressures and temperatures of 1.6-2.4 GPa and 500-530°C (Chopin and Monie, 1984; Le Bayon et al., 2006) indicating near UHP metamorphic conditions. Based on the age, P-T, and textural

What can blueschists tell about the Deep? High Pressure in the Anatolide - Taurid Belt

NASA Astrophysics Data System (ADS)

Oberhaensli, R.

2011-12-01

High-pressure metamorphic terranes in the Anatolide - Taurid belt document the complex distribution of paleo-sutures in the Tethyan realm. Field based petrologic studies of metapelites in the Anatolide-Taurid realm allow to trace HP-LT metamorphism not only in the well known ophiolitic Tavsanli Zone (2.4 GPa/500 °C) but also in the Afyon Zone (0.9 GPa/350 °C), the Menderes Massif (1.2 Gpa/500 °C;) and in the Lycian Nappes (1.0 Gpa/400 °C) - all situated north of the so called Taurid Platform. While the HP metamorphism is dated to 90-80 Ma (Rb/Sr; Ar/Ar) in the Tavsanli Zone, it ranges from 60-70 Ma (Ar/Ar) in the Afyon Zone and its tectonic equivalent, the Lycian Nappes. The Afyon Zone s.l. is closely related to the glaucophane- lawsonite-bearing rocks of the Tavsanli Zone and its eastward extension. Blueschist-facies metamorphism is documented by Fe,Mg-carpholite in regionally distributed metapelites and glaucophane in sparse mafic rocks (Afyon, Menderes, Lycia). Since observations of HP are based on Fe,Mg-carpholite bearing metasediments and not on mafic blueschists new thermodynamic data and petrologic modelling was elaborated to match P-T data and field-based observations. Moreover, newly formed phengitic mica allows precise dating. Both, Tavsanli and Afyon Zones can be followed along strike over more than 600 km and around the southern edge of the Central Anatolian Crystalline Complex. The two zones are situated north of the Taurid Platform and correlate with the Amasia Zone in Armenia. To the extreme East the Bitlis Complex underwent a LT - HP metamorphic blueschist evolution (1,1 GPa/ 350 °C; glaucophane, Fe,Mg-carpholite) in its sedimentary cover while the basement is eclogitic. Depending on the structural position and mineral association of phengitic mica metamorphic ages of the Bitlis blueschists scatter around 70-80 Ma. Eclogites from the basement are slightly older. These LT-HP units cannot be correlated with the Tavsanli - Afyon blueschist belts

Metamorphic P-T-t path retrieved from metapelites in the southeastern Taihua metamorphic complex, and the Paleoproterozoic tectonic evolution of the southern North China Craton

NASA Astrophysics Data System (ADS)

Lu, Jun-Sheng; Zhai, Ming-Guo; Lu, Lin-Sheng; Wang, Hao Y. C.; Chen, Hong-Xu; Peng, Tao; Wu, Chun-Ming; Zhao, Tai-Ping

2017-02-01

The Taihua metamorphic complex in the southern part of the North China Craton is composed of tonalite-trondhjemite-granodiorite (TTG) gneisses, amphibolites, metapelitic gneisses, marbles, quartzites, and banded iron formations (BIFs). The protoliths of the complex have ages ranging from ∼2.1 to ∼2.9 Ga and was metamorphosed under the upper amphibolite to granulite facies conditions with NWW-SEE-striking gneissosity. Metapelitites from the Wugang area have three stages of metamorphic mineral assemblages. The prograde metamorphic mineral assemblage (M1) includes biotite + plagioclase + quartz + ilmenite preserved as inclusions in garnet porphyroblasts. The peak mineral assemblage (M2) consists of garnet porphyroblasts and matrix minerals of sillimanite + biotite + plagioclase + quartz + K-feldspar + ilmenite + rutile + pyrite. The retrograde mineral assemblage (M3), biotite + plagioclase + quartz, occurs as symplectic assemblages surrounding embayed garnet porphyroblasts. Garnet porphyroblasts are chemically zoned. Pseudosection calculated in the NCKFMASHTO model system suggests that mantles of garnet porphyroblasts define high-pressure granulites facies P-T conditions of 12.2 kbar and 830 °C, whereas garnet rims record P-T conditions of 10.2 kbar and 840 °C. Integrating the prograde mineral assemblages, zoning of garnet porphyroblasts with symplectic assemblages, a clockwise metamorphic P-T path can be retrieved. High resolution SIMS U-Pb dating and LA-ICP-MS trace element measurements of the metamorphic zircons demonstrate that metapelites in Wugang possibly record the peak or near peak metamorphic ages of ∼1.92 Ga. Furthermore, 40Ar/39Ar dating of biotite in metapelites suggests that the cooling of the Taihua complex may have lasted until ∼1.83 Ga. Therefore, a long-lived Palaeoproterozoic metamorphic event may define a slow exhumation process. Field relationship and new metamorphic data for the Taihua metamorphic complex does not support the previous

Study on the Pressure Pulsation inside Runner with Splitter Blades in Ultra-High Head Turbine

NASA Astrophysics Data System (ADS)

Meng, L.; Zhang, S. P.; Zhou, L. J.; Wang, Z. W.

2014-03-01

Runners with splitter blades were used widely for the high efficiency and stability. In this paper, the unsteady simulation of an ultra-high head turbine at the best efficiency point, 50% and 75% discharge points were established, to analyze the pressure pulsation in the vaneless space, rotating domain and the draft tube. First of all, runners with different length splitter blades and without splitter blades were compared to learn the efficiency and the pressure distribution on the blade surface. And then the amplitude of the pressure pulsation was analysed. The peak efficiency of the runner with splitter blades is remarkably higher than that of the corresponding impeller without splitter blades. And the efficiency of the turbine is the highest when the length ratio of the splitter blades is 0.75 times the main blades. The pressure pulsation characteristics were also influenced, because the amplitudes of the pulsation induced by the RSI phenomenon were changed as a result of more blades. At last, the best design plan of the length of the splitter blades (length ratio=0.825) was obtained, which improved the pressure pulsation characteristics without significant prejudice to the efficiency.

Tectono-metamorphic evolution of the Jomolhari massif: Variations in timing of syn-collisional metamorphism across western Bhutan

NASA Astrophysics Data System (ADS)

Regis, Daniele; Warren, Clare J.; Young, David; Roberts, Nick M. W.

2014-03-01

Our current understanding of the rates and timescales of mountain-building processes is largely based on information recorded in U-bearing accessory minerals such as monazite, which is found in low abundance but which hosts the majority of the trace element budget. Monazite petrochronology was used to investigate the timing of crustal melting in migmatitic metasedimentary rocks from the Jomolhari massif (NW Bhutan). The samples were metamorphosed at upper amphibolite to granulite facies conditions (~ 0.85 GPa, ~ 800 °C), after an earlier High-Pressure stage (P > 1.4 GPa), and underwent partial melting through dehydration melting reactions involving muscovite and biotite. In order to link the timing of monazite growth/dissolution to the pressure-temperature (P-T) evolution of the samples, we identified 'chemical fingerprints' in major and accessory phases that were used to back-trace specific metamorphic reactions. Variations in Eu anomaly and Ti in garnet were linked to the growth and dissolution of major phases (e.g. growth of K-feldspar and dehydration melting of muscovite/biotite). Differences in M/HREE and Y from garnet core to rim were instead related to apatite breakdown and monazite-forming reactions. Chemically zoned monazite crystals reacted multiple times during the metamorphic evolution suggesting that the Jomolhari massif experienced a prolonged high-temperature metamorphic evolution from 36 Ma to 18 Ma, significantly different from the P-T-time path recorded in other portions of the Greater Himalayan Sequence (GHS) in Bhutan. Our data demonstrate unequivocally that the GHS in Bhutan consists of units that experienced independent high-grade histories and that were juxtaposed across different tectonic structures during exhumation. The GHS may have been exhumed in response to (pulsed) mid-crustal flow but cannot be considered a coherent block.

GPR Imaging of Fault Related Folds in a Gold-Bearing Metasedimentary Sequence, Carolina Terrane, Southern Appalachian Mountains

NASA Astrophysics Data System (ADS)

Diemer, J. A.; Bobyarchick, A. R.

2015-12-01

The Carolina terrane comprises Ediacaran to earliest Paleozoic mixed magmatic and sedimentary assemblages in the central and eastern Piedmont of the Southern Appalachian Mountains. The terrane was primarily deformed during the Late Ordovician Cherokee orogeny, that reached greenschist facies metamorphism. The Albemarle arc, a younger component of the Carolina terrane, contains volcanogenic metasedimentary rocks with intercalated mainly rhyolitic volcanic rocks. Regional inclined to overturned folds with axial planar cleavage verge southeast. At mesoscopic scales (exposures of a few square meters), folds sympathetic with regional folds are attenuated or truncated by ductile shear zones or contractional faults. Shear and fault zones are most abundant near highly silicified strataform zones in metagraywacke of the Tillery Formation; these zones are also auriferous. GPR profiles were collected across strike of two silicified, gold-bearing zones and enclosing metagraywacke to characterize the scale and extent of folding in the vicinity of ore horizons. Several GSSI SIR-3000 / 100 MHz monostatic GPR profiles were collected in profiles up to 260 meters long. In pre-migration lines processed for time zero and background removal, several clusters of shallow, rolling sigmoidal reflectors appeared separated by sets of parallel, northwest-dipping reflective discontinuities. These features are inferred to be reverse faults carrying contractional folds. After migration with an average velocity of 0.105 m/ns, vertical heights of the inferred folds became attenuated but not removed, and contractional fault reflections remained prominent. After migration, a highly convex-up cluster of reflections initially assumed to be a fold culmination resolved to an elliptical patch of high amplitudes. The patch is likely an undisclosed shaft or covered trench left by earlier gold prospecting. In this survey, useful detail appeared to a depth of 7.5 meters, and only a few gently inclined

Confirmation of the southwest continuation of the Cat Square terrane, southern Appalachian Inner Piedmont, with implications for middle Paleozoic collisional orogenesis

USGS Publications Warehouse

Huebner, Matthew T.; Hatcher, Robert D.; Merschat, Arthur J.

2017-01-01

Detailed geologic mapping, U-Pb zircon geochronology and whole-rock geochemical analyses were conducted to test the hypothesis that the southwestern extent of the Cat Square terrane continues from the northern Inner Piedmont (western Carolinas) into central Georgia. Geologic mapping revealed the Jackson Lake fault, a ∼15 m-thick, steeply dipping sillimanite-grade fault zone that truncates lithologically distinct granitoids and metasedimentary units, and roughly corresponds with a prominent aeromagnetic lineament hypothesized to represent the southern continuation of the terrane-bounding Brindle Creek fault. Results of U-Pb SHRIMP geochronology indicate Late Ordovician to Silurian granitoids (444–439 Ma) occur exclusively northwest of the fault, whereas Devonian (404–371 Ma) granitoids only occur southeast of the fault. The relatively undeformed Indian Springs granodiorite (three individual bodies dated 317–298 Ma) crosscuts the fault and occurs on both sides, which indicates the Jackson Lake fault is a pre-Alleghanian structure. However, detrital zircon signatures from samples southeast of the Jackson Lake fault reveal dominant Grenville provenance, in contrast to Cat Square terrane detrital zircon samples from the northern Inner Piedmont, which include peri-Gondwanan (600–500 Ma) and a prominent Ordovician-Silurian (∼430 Ma) signature. We interpret the rocks southeast of the Jackson Lake fault to represent the southwestern extension of the Cat Square terrane primarily based on the partitioning of granitoid ages and lithologic distinctions similar to the northern Inner Piedmont.Data suggest Cat Square terrane metasedimentary rocks were initially deposited in a remnant ocean basin setting and developed into an accretionary prism in front of the approaching Carolina superterrane, ultimately overridden by it in Late Devonian to Early Mississippian time. Burial to >20 km resulted in migmatization of lower plate rocks, forming an infrastructure beneath the

Metamorphic density controls on early-stage subduction dynamics

NASA Astrophysics Data System (ADS)

Duesterhoeft, Erik; Oberhänsli, Roland; Bousquet, Romain

2013-04-01

Subduction is primarily driven by the densification of the downgoing oceanic slab, due to dynamic P-T-fields in subduction zones. It is crucial to unravel slab densification induced by metamorphic reactions to understand the influence on plate dynamics. By analyzing the density and metamorphic structure of subduction zones, we may gain knowledge about the driving, metamorphic processes in a subduction zone like the eclogitization (i.e., the transformation of a MORB to an eclogite), the breakdown of hydrous minerals and the release of fluid or the generation of partial melts. We have therefore developed a 2D subduction zone model down to 250 km that is based on thermodynamic equilibrium assemblage computations. Our model computes the "metamorphic density" of rocks as a function of pressure, temperature and chemical composition using the Theriak-Domino software package at different time stages. We have used this model to investigate how the hydration, dehydration, partial melting and fractionation processes of rocks all influence the metamorphic density and greatly depend on the temperature field within subduction systems. These processes are commonly neglected by other approaches (e.g., gravitational or thermomechanical in nature) reproducing the density distribution within this tectonic setting. The process of eclogitization is assumed as being important to subduction dynamics, based on the very high density (3.6 g/cm3) of eclogitic rocks. The eclogitization in a MORB-type crust is possible only if the rock reaches the garnet phase stability field. This process is primarily temperature driven. Our model demonstrates that the initiation of eclogitization of the slab is not the only significant process that makes the descending slab denser and is responsible for the slab pull force. Indeed, our results show that the densification of the downgoing lithospheric mantle (due to an increase of pressure) starts in the early subduction stage and makes a significant

Metamorphic conditions and CHIME monazite ages of Late Eocene to Late Oligocene high-temperature Mogok metamorphic rocks in central Myanmar

NASA Astrophysics Data System (ADS)

Maw Maw Win; Enami, Masaki; Kato, Takenori

2016-03-01

The high temperature (T)/pressure (P) regional Mogok metamorphic belt is situated in central Myanmar, and is mainly composed of pelitic gneisses, amphibolites, marbles, and calc-silicate rocks. The garnet-biotite-plagioclase-sillimanite-quartz assemblage and its partial system suggest equilibrium P/T conditions of 0.6-1.0 GPa/780-850 °C for the peak metamorphic stage, and 0.3-0.5 GPa/600-680 °C for the exhumation and hydration stage. Monazite grains show complex compositional zoning consisting of three segments-I, II, and III. Taking into consideration the monazite zoning and relative misfit curves, the calculated chemical Th-U-total Pb isochron method (CHIME) monazite age data (284 spot analyses) indicated four age components: 49.3 ± 2.6-49.9 ± 7.9, 37.8 ± 1.0-38.1 ± 1.7, 28.0 ± 0.8-28.8 ± 1.6, and 23.7 ± 1.3 Ma (2σ level). The ages of the Late Eocene and Late Oligocene epochs were interpreted as the peak metamorphic stage of upper-amphibolite and/or granulite facies and the postdated hydration stage, respectively.

A tectonic linkage between the Rodelide orogen (Sierra Leone) and the St. Lucie metamorphic complex in the Florida subsurface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dallmeyer, R.D.

1989-03-01

Hornblende concentrates prepared from cuttings from two deep test wells penetrating the complex display internally concordant {sup 40}Ar/{sup 39}Ar incremental-release spectra defining plateau ages of 510.8 {plus minus} 1.1 Ma and 513.1 {plus minus} 1.8 Ma, which are interpreted to date post-metamorphic cooling through temperatures required for intracrystalline argon retention. The Kasila Group constitutes the western segment of the Rokelide orogen in Sierra Leone. Four hornblende concentrations prepared for amphibolite within the Kasila Group yield {sup 40}Ar/{sup 39}Ar plateau ages of 505.0 {plus minus} 5.2, 508.2 {plus minus} 2.1, 510.5 {plus minus} 2.6, and 546.1 {plus minus} 6.8 Ma. Theymore » are interpreted to date post-metamorphic cooling through appropriate argon closure temperature following a ca. 550-560 Ma, Pan-African II phase of tectonothermal activity. A biotite concentrate from paragneiss within the Kasila Group displays an internally concordant {sup 40}/Ar{sup 39}Ar release spectrum defining a plateau age of 524.7 {plus minus} 1.3 Ma, which likely reflects slight contamination with extraneous (excess) argon. Muscovite from the Marampa Group yields a {sup 40}Ar/{sup 39}Ar plateau age of 561.1 {plus minus} 2.3 Ma, which is interpreted to date cooling through appropriate argon closure temperatures. Although these temperatures are generally considered to be lower than those for hornblenede, the muscovite records an older cooling age, suggesting that the Marampa Group experienced slightly earlier post-metamorphic uplift and cooling relative to the Kasila Group. Lithologic comparison combined with similarities in post-metamorphic thermal evolution suggest that the St. Lucie Metamorphic Complex originated within the Rockelide orogen. This and other lithotectonic elements of the Suwannee terrane appear to represent a fragment of Gondwana which accreted to Laurentia during late Paleozoic amalgamation of Pangea.« less

Continental collision with a sandwiched accreted terrane: Insights into Himalayan-Tibetan lithospheric mantle tectonics?

NASA Astrophysics Data System (ADS)

Kelly, Sean; Butler, Jared P.; Beaumont, Christopher

2016-12-01

Many collisional orogens contain exotic terranes that were accreted to either the subducting or overriding plate prior to terminal continent-continent collision. The ways in which the physical properties of these terranes influence collision remain poorly understood. We use 2D thermomechanical finite element models to examine the effects of prior 'soft' terrane accretion to a continental upper plate (retro-lithosphere) on the ensuing continent-continent collision. The experiments explore how the style of collision changes in response to variations in the density and viscosity of the accreted terrane lithospheric mantle, as well as the density of the pro-lithospheric mantle, which determines its propensity to subduct or compress the accreted terrane and retro-lithosphere. The models evolve self-consistently through several emergent phases: breakoff of subducted oceanic lithosphere; pro-continent subduction; shortening of the retro-lithosphere accreted terrane, sometimes accompanied by lithospheric delamination; and, terminal underthrusting of pro-lithospheric mantle beneath the accreted terrane crust or mantle. The modeled variations in the properties of the accreted terrane lithospheric mantle can be interpreted to reflect metasomatism during earlier oceanic subduction beneath the terrane. Strongly metasomatized (i.e., dense and weak) mantle is easily removed by delamination or entrainment by the subducting pro-lithosphere, and facilitates later flat-slab underthrusting. The models are a prototype representation of the Himalayan-Tibetan orogeny in which there is only one accreted terrane, representing the Lhasa terrane, but they nonetheless exhibit processes like those inferred for the more complex Himalayan-Tibetan system. Present-day underthrusting of the Tibetan Plateau crust by Indian mantle lithosphere requires that the Lhasa terrane lithospheric mantle has been removed. Some of the model results support previous conceptual interpretations that Tibetan

Metamorphic sole formation reveals plate interface rheology during early subduction

NASA Astrophysics Data System (ADS)

Mathieu, S.; Agard, P.; Dubacq, B.; Plunder, A.; Prigent, C.

2015-12-01

Metamorphic soles are m to ~500m thick tectonic slices welded beneath most large ophiolites. They correspond to highly to mildly deformed portions of oceanic lithosphere metamorphosed at amphibolite to granulite facies peak conditions. Metamorphic soles are interpreted as formed ≤1-2Ma after intraoceanic subduction initiation by heat transfer from the hot, incipient mantle wegde to the underthrusting lower plate. Their early accretion and exhumation together with the future ophiolite implies at least one jump of the subduction plate interface from above to below the metamorphic sole. Metamorphic soles thus represent one of the few remnants of the very early evolution of the subduction plate interface and provide major constraints on the thermal structure and the effective rheology of the crust and mantle along the nascent slab interface.We herein present a structural and petrological detailed description of the Oman and Turkey metamorphic soles. Both soles present a steep inverted metamorphic structure, with isograds subparallel to the peridotite contact, in which the proportion of mafic rocks, pressure and temperature conditions increase upward. They comprise, as most metamorphic soles worldwide, two main units: (1) a high-grade unit adjacent to the overlying peridotite composed of granulitized to amphibolized metabasalts, with rare metasedimentary interlayers (~800±100ºC at 10±2kbar) and (2) a low-grade greenschist facies unit composed of metasedimentary rocks with rare metatuffs (~500±100ºC at 5±2kbar). We provide for the first time refined P-T peak condition estimations by means of pseudosection modelling and maximum temperature constraints for the Oman low-grade sole by RAMAN thermometry. In order to quantify micro-scale deformations trough the sole, we also present EBSD data on the Oman garnet-bearing and garnet-free high-grade sole.With these new constraints, we finally propose a new conceptual mechanical model for metamorphic sole formation. This

Ultrahigh pressure extraction of lignan compounds from Dysosma versipellis and purification by high-speed counter-current chromatography.

PubMed

Zhu, Qing; Liu, Feng; Xu, Meixia; Lin, Xiaojing; Wang, Xiao

2012-09-15

Ultrahigh pressure extraction (UPE) was employed to extract podophyllotoxin and 4'-demethylpodophyllotoxin from Dysosma versipellis. The effects of extraction parameters including extraction solvents, pressure, time and solid/liquid ratio were investigated using a High Hydrostatic Pressure Processor. The optimal condition for UPE of the target compounds was 80% methanol, 200 MPa of pressure, 1 min of extraction time and 1:12 (g/mL) of solid/liquid ratio. Podophyllotoxin and 4'-demethylpodophyllotoxin in the crude extract were purified by high-speed counter-current chromatography (HSCCC) with a two-phase solvent system composed of petroleum ether-ethyl acetate-methanol-water (10:10:8:12, v/v), and the fractions were analyzed by HPLC, ESI-MS and (1)H NMR. As a result, 73.7 mg podophyllotoxin and 16.5mg 4'-demethylpodophyllotoxin with purities over 96% were obtained from 260 mg crude sample in one-step separation. Copyright © 2012 Elsevier B.V. All rights reserved.

Deformation during terrane accretion in the Saint Elias orogen, Alaska

USGS Publications Warehouse

Bruhn, R.L.; Pavlis, T.L.; Plafker, G.; Serpa, L.

2004-01-01

The Saint Elias orogen of southern Alaska and adjacent Canada is a complex belt of mountains formed by collision and accretion of the Yakutat terrane into the transition zone from transform faulting to subduction in the northeast Pacific. The orogen is an active analog for tectonic processes that formed much of the North American Cordillera, and is also an important site to study (1) the relationships between climate and tectonics, and (2) structures that generate large- to great-magnitude earthquakes. The Yakutat terrane is a fragment of the North American plate margin that is partly subducted beneath and partly accreted to the continental margin of southern Alaska. Interaction between the Yakutat terrane and the North American and Pacific plates causes significant differences in the style of deformation within the terrane. Deformation in the eastern part of the terrane is caused by strike-slip faulting along the Fairweather transform fault and by reverse faulting beneath the coastal mountains, but there is little deformation immediately offshore. The central part of the orogen is marked by thrusting of the Yakutat terrane beneath the North American plate along the Chugach-Saint Elias fault and development of a wide, thin-skinned fold-and-thrust belt. Strike-slip faulting in this segment may he localized in the hanging wall of the Chugach-Saint Elias fault, or dissipated by thrust faulting beneath a north-northeast-trending belt of active deformation that cuts obliquely across the eastern end of the fold-and-thrust belt. Superimposed folds with complex shapes and plunging hinge lines accommodate horizontal shortening and extension in the western part of the orogen, where the sedimentary cover of the Yakutat terrane is accreted into the upper plate of the Aleutian subduction zone. These three structural segments are separated by transverse tectonic boundaries that cut across the Yakutat terrane and also coincide with the courses of piedmont glaciers that flow from

Geologic framework of the Alaska Peninsula, southwest Alaska, and the Alaska Peninsula terrane

USGS Publications Warehouse

Wilson, Frederic H.; Detterman, Robert L.; DuBois, Gregory D.

2015-01-01

The boundaries separating the Alaska Peninsula terrane from other terranes are commonly indistinct or poorly defined. A few boundaries have been defined at major faults, although the extensions of these faults are speculative through some areas. The west side of the Alaska Peninsula terrane is overlapped by Tertiary sedimentary and volcanic rocks and Quaternary deposits.

Some contrasting biostratigraphic links between the Baker and Olds Ferry Terranes, eastern Oregon

USGS Publications Warehouse

Nestell, Merlynd K.; Blome, Charles D.

2016-01-01

New stratigraphic and paleontologic data indicate that ophiolitic melange windows in the Olds Ferry terrane of eastern Oregon contain limestone blocks and chert that are somewhat different in age than those present in the adjacent Baker terrane melange. The melange windows in the Olds Ferry terrane occur as inliers in the flyschoid Early and Middle Jurassic age Weatherby Formation, which depositionally overlies the contact between the melange-rich Devonian to Upper Triassic rocks of the Baker terrane on the north, and Upper Triassic and Early Jurassic volcanic arc rocks of the Huntington Formation on the south. The Baker terrane and Huntington Formation represent fragments of a subduction complex and related volcanic island arc, whereas the Weatherby Formation consists of forearc basin sedimentary deposits. The tectonic blocks in the melange windows of the Weatherby Formation (in the Olds Ferry terrane) are dated by scarce biostratigraphic evidence as Upper Pennsylvanian to Lower Permian and Upper Triassic. In contrast, tectonic blocks of limestone in theBaker terrane yield mostly fusulinids and small foraminifers of Middle Pennsylvanian Moscovian age at one locality.Middle Permian (Guadalupian) Tethyan fusulinids and smaller foraminifers (neoschwagerinids and other Middle Permian genera) are present at a few other localities. Late Triassic conodonts and bryozoans are also present in a few of the Baker terrane tectonic blocks. These limestone blocks are generally embedded in Permian and Triassic radiolarian bearing chert or argillite. Based on conodont, radiolarian and fusulinid data, the age limits of the meange blocks in the Weatherby Formation range from Pennsylvanian to Late Triassic.

Geologic map of the Chelan 30-minute by 60-minute quadrangle, Washington

USGS Publications Warehouse

Tabor, R.W.; Frizzell, V.A.; Whetten, J.T.; Waitt, R.B.; Swanson, D.A.; Byerly, G.R.; Booth, D.B.; Hetherington, M.J.; Zartman, R.E.

1987-01-01

Summary -- The Chelan quadrangle hosts a wide variety of rocks and deposits and display a long geologic history ranging from possible Precambrian to Recent. Two major structures, the Leavenworth and Entiat faults divide cross the quadrangle from southeast to northwest and bound the Chiwaukum 'graben', a structural low preserving Tertiary sedimentary rocks between blocks of older, metamorphic and igneous rocks. Pre-Tertiary metamorphic rocks in the quadrangle are subdivided into five major tectonostratigraphic terranes: (1) the Ingalls terrane, equivalent to the Jurassic Ingalls Tectonic Complex of probable mantle and deep oceanic rocks origin, (2) the Nason terrane, composed of the Chiwaukum Schist and related gneiss, (3) the Swakane terrane, made up entirely of the Swakane Biotite Gneiss, a metamorphosed, possibly Precambrian, sedimentary and/or volcanic rock, (4) the Mad River terrane composed mostly of the rocks of the Napeequa River area (Napeequa Schist), a unit of oceanic protolith now considered part of the Chelan Mountains terrane (the Mad River terrane has been abandoned, 2001), and (5) the Chelan Mountains terrane, dominated by the Chelan Complex of Hopson and Mattinson (1971) which is composed of migmatite and gneissic to tonalite of deep-seated igneous and metamorphic origin.During an episode of Late Cretaceous regional metamorphism, all the terranes were intruded by deepseated tonalite to granodiorite plutons, including the Mount Stuart batholith, Ten Peak and Dirty Face plutons, and the Entiat pluton and massive granitoid rocks of the Chelan Complex. The Duncan Hill pluton intruded rocks of the Chelan Mountains terrane in the Middle Eocene. At about the same time fluvial arkosic sediment of the Chumstick Formation was deposited in a depression. The outpouring of basalt lavas to the southeast of the quadrangle during the Miocene built up the Columbia River Basalt Group. These now slightly warped lavas lapped onto the uplifted older rocks. Deformation

Cretaceous crust beneath SW Borneo: U-Pb dating of zircons from metamorphic and granitic rocks

NASA Astrophysics Data System (ADS)

Davies, L.; Hall, R.; Armstrong, R.

2012-12-01

Metamorphic basement rocks from SW Borneo are undated but have been suggested to be Palaeozoic. This study shows they record low pressure 'Buchan-type' metamorphism and U-Pb SHRIMP dating of zircons indicates a mid-Cretaceous (volcaniclastic) protolith. SW Borneo is the southeast promontory of Sundaland, the continental core of SE Asia. It has no sedimentary cover and the exposed basement has been widely assumed to be a crustal fragment from the Indochina-China margin. Metamorphic rocks of the Pinoh Group in Kalimantan (Indonesian Borneo) are intruded by granitoid rocks of Jurassic-Cretaceous age, based on K-Ar dating, suggesting emplacement mainly between 130 and 80 Ma. The Pinoh metamorphic rocks have been described as a suite of pelitic schists, slates, phyllites, and hornfelses, and have not been dated, although they have been correlated with rocks elsewhere in Borneo of supposed Palaeozoic age. Pelitic schists contain biotite, chlorite, cordierite, andalusite, quartz, plagioclase and in some cases high-Mn almandine-rich garnet. Many have a shear fabric associated with biotite and fibrolite intergrowth. Contact metamorphism due to intrusion of the granitoid rocks produced hornfelses with abundant andalusite and cordierite porphyroblasts. Granitoids range from alkali-granite to tonalite and contain abundant hornblende and biotite, with rare white mica. Zircons from granitoid rocks exhibit sector- and concentric- zoning; some have xenocrystic cores mantled by magmatic zircon. There are four important age populations at c. 112, 98, 84 and 84 Ma broadly confirming earlier dating studies. There is a single granite body with a Jurassic age (186 ± 2.3 Ma). Zircons from pelitic metamorphic rocks are typically euhedral, with no evidence of rounding or resorbing of grains; a few preserve volcanic textures. They record older ages than those from igneous rocks; U-Pb ages are Cretaceous with a major population between 134 and 110 Ma. A single sample contains Proterozoic

Paleobiogeographic affinities of emsian (late early devonian) gastropods from farewell terrane (west-central Alaska)

USGS Publications Warehouse

Fryda, J.; Blodgett, R.B.

2008-01-01

The vast majority of Emsian gastropods from Limestone Mountain, Medfra B-4 quadrangle, west-central Alaska (Farewell terrane) belong to species with lecithotrophic larval strategy. The present data show that there is no significant difference in the paleobiogeo-graphic distribution of Emsian gastropod genera with lecithotrophic and planktotrophic larval strategies. Numerical analysis of the faunal affinities of the Emsian gastropod fauna from the Farewell terrane reveals that this terrane has much stronger faunal connections to regions like Variscan Europe, eastern Australia, and the Alexander terrane of southeast Alaska than to cratonic North America (Laurentia). The Canadian Arctic Islands is the only region of cratonic North America (Laurentia) that shows significant faunal affinities to the Emsian gastropod faunas of the Farewell terrane. The analysis also indicates a close faunal link between the Farewell and Alexander terranes. Published paleontological and geological data suggest that the Farewell and Alexander terranes represents tectonic entities that have been rifted away from the Siberia, Baltica, or the paleo-Pacific margin of Australia. The results of the present numerical analysis are not in conflict with any of these possibilities. However, the principle of spatial continuity of the wandering path prefers Siberia as the most probable "parental" paleocontinent for the derivation of both the Farewell and Alexander terranes. ?? 2008 The Geological Society of America.

The Late Triassic bivalve Monotis in accreted terranes of Alaska

USGS Publications Warehouse

Silberling, Norman J.; Grant-Mackie, J. A.; Nichols, K.M.

1997-01-01

Late Triassic bivalves of the genus Monotis occur in at least 16 of the lithotectonic terranes and subterranes that together comprise nearly all of Alaska, and they also occur in the Upper Yukon region of Alaska where Triassic strata are regarded as representing non-accretionary North America. On the basis of collections made thus far, 14 kinds of Monotis that differ at the species or subspecies level can be recognized from alaska. These are grouped into the subgenera Monotis (Monotis), M. (Pacimonotis), M. (Entomonotis), and M. (Eomonotis). In places, Monotis shells of one kind or another occur in rock-forming abundance. On the basis of superpositional data from Alaska, as well as from elsewhere in North America and Far Eastern Russia, at least four distince biostratigraphic levels can be discriminated utilizing Monotis species. Different species of M. (Eomonotis) characterize two middle Norian levels, both probably within the supper middle Norian Columbianus Ammonite Zone. Two additional levels are recognized in the lower upper Norian Cordilleranus Ammonite Zone utilizing species of M. (Monotis) or M. (Entomonotis), both of which subgenera are restricted to the late Norian. An attached-floating mode of life is commonly attributed to Monotis; thus, these bivalves would have been pseudoplanktonic surface dwellers that were sensitive to surface-water temperature and paleolatitude. Distinctly different kinds of Monotis occur at different paleolatitudes along the Pacific and Arctic margins of the North American craton inboard of the accreted terranes. Comparison between thse craton-bound Monotis faunas and those of the Alaskan terranes in southern Alaska south of the Denali fault were paleoequatorial in latitude during Late Triassic time. Among these terranes, the Alexander terrane was possibly in the southern hemisphere at that time. Terranes of northern Alaska, on the other hand, represent middle, possibly high-middle, northern paleolatitudes.

Ultrahigh vacuum gauge having two collector electrodes

NASA Technical Reports Server (NTRS)

Torney, F. L., Jr. (Inventor)

1967-01-01

A gauge for measuring ultrahigh vacuums with great accuracy is described. It provides a means for ionizing the gas whose pressure is being measured, and consists of a collector electrode, a suppressor, radiation shielding, and a second collector.

Extensional unroofing of the metamorphic core of the southern Appalachian orogen prior to the breakup of Pangea: Insights from 40Ar/39Ar thermochronology

NASA Astrophysics Data System (ADS)

Ma, C.; Foster, D. A.; Hames, W. E.; Mueller, P. A.

2017-12-01

Orogenic collapse commonly occurs following the collisional phase of an orogeny and often leads to exhumation of deep crustal metamorphic rocks. The Alleghanian orogeny in the southern Appalachian orogen (SAO) occurred during final assembly of Pangea. 40Ar/39Ar data of hornblende, muscovite, and biotite from Alleghanian granitic plutons in Georgia, Alabama, and Florida of the SAO give cooling ages that progressively young toward the south-southeast prior to ca. 280 Ma and young locally toward the north-northwest after ca. 280 Ma. These cooling-age gradients, along with geometry of the Suwannee suture zone and timing/structures of the South Georgia basin, suggest that metamorphic rocks north of the Suwannee suture in the study area formed the lower plate of a metamorphic core complex. The faults of the Suwannee suture zone were reactivated to form a master extensional detachment fault with the Suwannee terrane comprising the upper plate. Thermochronologic data show that rapid extension of the metamorphic core complex footwall started at ca. 300-295 Ma and the extension continued to at least ca. 240 Ma. The maximum average extension rate is estimated to be 10.3 km/m.y. during ca. 300-280 Ma along the master detachment fault and 2.4 km/m.y. during ca. 280-240 Ma along a secondary detachment fault, reflecting differential extension over time. Main cooling rates of 10‒85˚C/m.y. and exhumation rates of 0.3‒2.8 km/m.y. are calculated for the Alleghanian granitic plutons studied. This work shows that, in the southernmost Appalachians, orogenic collapse resulted in metamorphic core complex-style extension between about 300 and 240 Ma. The horst-and-graben systems of the South Georgia basin formed within the upper plate in this tectonic setting. Metamorphic core complex-style extension, therefore, played a critical role in initial rifting that led to the eventual breakup of Pangea and formation of the Atlantic Ocean and the Gulf of Mexico.

Structures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle

PubMed Central

Merlini, Marco; Crichton, Wilson A.; Hanfland, Michael; Gemmi, Mauro; Müller, Harald; Kupenko, Ilya; Dubrovinsky, Leonid

2012-01-01

Carbon-bearing solids, fluids, and melts in the Earth's deep interior may play an important role in the long-term carbon cycle. Here we apply synchrotron X-ray single crystal micro-diffraction techniques to identify and characterize the high-pressure polymorphs of dolomite. Dolomite-II, observed above 17 GPa, is triclinic, and its structure is topologically related to CaCO3-II. It transforms above 35 GPa to dolomite-III, also triclinic, which features carbon in [3 + 1] coordination at the highest pressures investigated (60 GPa). The structure is therefore representative of an intermediate between the low-pressure carbonates and the predicted ultra-high pressure carbonates, with carbon in tetrahedral coordination. Dolomite-III does not decompose up to the melting point (2,600 K at 43 GPa) and its thermodynamic stability demonstrates that this complex phase can transport carbon to depths of at least up to 1,700 km. Dolomite-III, therefore, is a likely occurring phase in areas containing recycled crustal slabs, which are more oxidized and Ca-enriched than the primitive lower mantle. Indeed, these phases may play an important role as carbon carriers in the whole mantle carbon cycling. As such, they are expected to participate in the fundamental petrological processes which, through carbon-bearing fluids and carbonate melts, will return carbon back to the Earth’s surface. PMID:22869705

Role of strike-slip faulting in the evolution of allochthonous terranes in the Philippines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karig, D.E.; Sarewitz, D.R.; Haeck, G.D.

1986-10-01

Concepts of allochthonous terrane transport and emplacement are dominated by the assumption that most terranes originate on the subducting plate, collide with the upper plate, and are emplaced there. Movement of terranes along the convergent margin is recognized but is generally attributed to postcollision slip. In the northern Philippines, allochthonous terranes originate primarily within the arc system, have been translated along it by strike-slip faults, and were emplaced by cessation of that slip. The authors suggest that in the Philippines some originally vertical strike-slip boundaries may have evolved into shallow-dipping sutures marked by fold and thrust systems. This mode ofmore » terrane evolution may be more common than generally appreciated, particularly in orogenic belts developed in response to oblique convergence.« less

Proterozoic orogens in southern Peninsular India: Contiguities and complexities

NASA Astrophysics Data System (ADS)

Chetty, T. R. K.; Santosh, M.

2013-12-01

The Precambrian terranes of southern Peninsular India have been central to discussions on the history of formation and breakup of supercontinents. Of particular interest are the Proterozoic high grade metamorphic orogens at the southern and eastern margins of the Indian shield, skirting the 3.4 Ga Dharwar craton which not only preserve important records of lower crustal processes and lithospheric geodynamics, but also carry imprints of the tectonic framework related to the assembly of the major Neoproterozoic supercontinents - Rodinia and Gondwana. These Proterozoic orogens are described as Southern Granulite Terrane (SGT) in the southern tip and the Eastern Ghats Mobile Belt (EGMB) in the eastern domains of the peninsula. The contiguity of these orogens is broken for a distance of ˜400 km and disappears in the Bay of Bengal. These orogens expose windows of middle to lower crust with well-preserved rock records displaying multiple tectonothermal events and multiphase exhumation paths.Recent studies in these orogens have led to the recognition of discrete crustal blocks or terranes separated by major shear zone systems, some of which represent collisional sutures. The SGT and EGMB carry several important features such as fold-thrust tectonics, regional granulite facies metamorphism of up to ultrahigh-temperature conditions in some cases, multiple P-T paths, development of lithospheric shear zones, emplacement of ophiolites, presence of alkaline and anorthositic complexes, development of crustal-scale "flower structures", transpressional strains, and reactivation tectonics. A heterogeneous distribution of different metamorphic and magmatic assemblages with distinct spatial and temporal strain variations in shaping the fabric elements in different blocks is identified. Both EGMB and SGT share a common transpressional deformation history during the latest Neoproterozoic characterized by the steepening of the initial low angle crustal scale structures leading to a

An Ultrahigh CO2-Loaded Silicalite-1 Zeolite: Structural Stability and Physical Properties at High Pressures and Temperatures.

PubMed

Marqueño, Tomas; Santamaria-Perez, David; Ruiz-Fuertes, Javier; Chuliá-Jordán, Raquel; Jordá, Jose L; Rey, Fernando; McGuire, Chris; Kavner, Abby; MacLeod, Simon; Daisenberger, Dominik; Popescu, Catalin; Rodriguez-Hernandez, Placida; Muñoz, Alfonso

2018-06-04

We report the formation of an ultrahigh CO 2 -loaded pure-SiO 2 silicalite-1 structure at high pressure (0.7 GPa) from the interaction of empty zeolite and fluid CO 2 medium. The CO 2 -filled structure was characterized in situ by means of synchrotron powder X-ray diffraction. Rietveld refinements and Fourier recycling allowed the location of 16 guest carbon dioxide molecules per unit cell within the straight and sinusoidal channels of the porous framework to be analyzed. The complete filling of pores by CO 2 molecules favors structural stability under compression, avoiding pressure-induced amorphization below 20 GPa, and significantly reduces the compressibility of the system compared to that of the parental empty one. The structure of CO 2 -loaded silicalite-1 was also monitored at high pressures and temperatures, and its thermal expansivity was estimated.

Ca. 400 Ma Recrystallization of Norwegian Ultrahigh-pressure Eclogites: an ion Microprobe and Chemical Abrasion Study

NASA Astrophysics Data System (ADS)

Root, D. B.; Mattinson, J. M.; Hacker, B. R.; Wooden, J. L.

2002-12-01

Understanding the formation and exhumation of the ultrahigh-pressure (UHP) rocks of western Norway hinges on precise determination of the time of eclogite recrystallization. Our study consists of SHRIMP analysis, in conjunction with CL imagery, of zircon from four UHP and high-pressure (HP) eclogites; and detailed TIMS analysis of zircon from two samples subjected to combined thermal annealing and multi-step chemical abrasion (CA). SHRIMP analyses of the Otnheim and Langenes eclogites yield Caledonian spot ages of ca. 400 Ma from zircon rims. CL imagery and Th/U ratios from the Langenes eclogite indicate formation of rims by recrystallization of inherited zircon. SHRIMP analysis of the UHP Flatraket eclogite yielded a broad range of apparently concordant Caledonian ages. CA analyses of two fractions yielded moderate Pb loss from the first (lowest T) steps; possible minor Pb loss or minor growth at 400 Ma from the second steps; and a 407-404 Ma cluster of slightly discordant 206Pb/238U ages, most likely free from Pb loss, from the remaining steps. We interpret the latter to reflect recrystallization of inherited zircon, with possible new growth, at ca. 400-395 Ma. Alternatively, the high-temperature CA steps could represent growth at 407-404 Ma, with apparent discordance due to intermediate daughter product effects. HP/UHP zircon recrystallization in the Flatraket eclogite is inferred from three lines of evidence: i) zircon occurs as inclusions in garnet, omphacite, breunnerite, dolomite, and quartz, as well as in symplectites after phengite and omphacite; ii) association of zircon with rutile implies zircon formation during HP breakdown of Zr-ilmenite; and iii) chondrite-normalized ICP-MS analyses of the CA steps reveal small Eu anomalies and shallow HREE profiles, indicating zircon recrystallization in the presence of garnet. CA analysis of the Verpeneset eclogite yielded distinctly discordant step ages from two steps comprising <90% of the sample, with 206Pb/238U

Early Precambrian gneiss terranes and Pan-African island arcs in Yemen: Crustal accretion of the eastern Arabian Shield

NASA Astrophysics Data System (ADS)

Windley, Brian F.; Whitehouse, Martin J.; Ba-Bttat, Mahfood A. O.

1996-02-01

Within the Precambrian of Yemen, we have identified four gneiss terranes and two island-arc terranes on the basis of existing literature, mapping, and our own field observations, together with new Sm-Nd isotopic data. The two western gneiss terranes can be correlated with well-documented terranes (Asir and Afif) in Saudi Arabia. To the east of these, the Abas and Al-Mahfid gneiss terranes yield Sm-Nd model ages (tDM) of 1.7 2.3 Ga and 1.3 2.7 Ga, respectively, and cannot be correlated with any documented terranes in Saudi Arabia. These two terranes are separated by a Pan-African island-arc terrane that has been obducted onto one or both of the gneiss terranes, and a second arc bounds the Al-Mahfid gneiss terrane to the east. Our discovery of extensive Proterozoic to late Archean gneisses in Yemen provides important constraints upon the much-discussed tectonic framework of northeast Gondwana and the rate of Pan-African crustal growth. The terranes in Yemen may be correlated with comparable terranes on the eastern margin of the Arabian Shield and in northern Somalia. Thus Yemen provides a link between the arc collage of the Arabian Shield and the gneissic Mozambique belt of East Africa.

Evolution of the Archean continental crust in the nucleus of the Yangtze block: Evidence from geochemistry of 3.0 Ga TTG gneisses in the Kongling high-grade metamorphic terrane, South China

NASA Astrophysics Data System (ADS)

Qiu, Xiao-Fei; Ling, Wen-Li; Liu, Xiao-Ming; Lu, Shan-Song; Jiang, Tuo; Wei, Yun-Xu; Peng, Lian-Hong; Tan, Juan-Juan

2018-04-01

Archean Tonalite-Trondhjemite-Granodiorite (TTG) rocks are scattered within the Kongling high-grade metamorphic terrane (KHMT) in the northern South China block. A comprehensive geochronological and geochemical study is carried out on the Taoyuan granitic gneisses, a newly recognized TTG suite in the northwestern KHMT. This suite has long been regarded as a Mesoproterozoic magmatic pluton, but U-Pb zircon ages of 2994 ± 22 Ma and 2970 ± 15 Ma are obtained by LA-ICP-MS method in this study. The Taoyuan gneiss suite is trondhjemitic in composition, and has high SiO2 (67.80-74.93 wt.%), Na2O (5.11-5.81 wt.%) contents with Na2O/K2O ratios greater than unity, and low Ni (2.56-7.61 ppm), Cr (1.26-7.67 ppm), Yb (0.32-0.82 ppm) and Y (4.48-11.5 ppm) contents. Plots show large variation in La/Yb and Sr/Y ratios and pronounced depletion in Nb, Ta and Ti in the primitive mantle-normalized spiderdiagram. The gneiss suite also displays two-stage Nd model ages close to its crystallization age with corresponding εNd(t) values of -2.5 to +3.5. It is thus suggested that the Taoyuan gneisses, in fact, is part of the Archean Kongling basement complex. Geochemical evidence implies that the TTG rocks may be derived from partial melting of subducted oceanic crust from a garnetiferous amphibolite source with residual assemblage of garnet + amphibole + plagioclase. Our study further indicates that the nucleus of the Yangtze block might experience a juvenile continental crustal growth during Mesoarchean. We also suggest that the Yangtze block may have its own crustal evolutionary history independent from the North China craton and the Tarim block before Paleoproterozoic.

Thondhjemite of the Talkeetna Mountains: An unusually large low-K pluton in Alaska's Peninsular terrane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ford, A.B.; Arth, J.G.; Csejtey, B.

1993-04-01

An unusually large, elongate Jurassic pluton of trondhjemite, about 120- by 10--15 km in dimensions, intruded Jurassic plutonic and metamorphic rocks of the Peninsular terrane in the central Talkeetna Mountains of south-central Alaska. Muscovite and biotite yield minimum ages of 150--145 Ma. The N40[degree]E-trending body is concordant with regional structures. It is the youngest member of a subduction-related Jurassic plutonic suite in the Peninsular terrane that, along with Wrangellia, was accreted to the North American continent in the middle Cretaceous. Rocks, commonly sheared, are medium to coarse grained and leucocratic (CI = 3--9). Biotite is the chief mafic mineral. Minormore » muscovite and garnet are common and green hornblende rare. Samples (n = 27) from the body's entire length have an average Mg[number sign] of 45 and an SiO[sub 2] continuum of 67--74% (avg. 70.7%). High Al[sub 2]O[sub 3] (14.4--17.9%, avg. 16.5%) is typical of continental trondhjemite. Averages for Zr (109 ppm) and Nb (3.5 ppm) and the ratios K/Rb (491) and Zr/Nb (34) are typical of orogenic igneous rocks of subduction origin. Four samples analyzed have low ([sup 87]Sr/[sup 86]Sr)[sub i] (avg. 0.7036). Very low Rb/Sr (avg. 0.027) is similar to Idaho batholith trondhjemites. REE patterns with low to moderate LREE and HREE with flat patterns and low contents suggest residual garnet or hornblende during partial melting or fractionation. The pluton appears homogeneous in outcrop. However, some geographic variations in chemistry, as in SiO[sub 2] contents and especially in Eu/Eu[sup *], suggest existence of perhaps three regionally separate plumbing systems, or chambers in which different processes such as plagioclase accumulation or hornblende fractionation were active.« less

Structure and Activity Changes of Phytohemagglutinin from Red Kidney Bean (Phaseolus vulgaris) Affected by Ultrahigh-Pressure Treatments.

PubMed

Lu, Yunjun; Liu, Cencen; Zhao, Mouming; Cui, Chun; Ren, Jiaoyan

2015-11-04

Phytohemagglutin (PHA), purified from red kidney beans (Phaseolus vulgaris) by Affi-Gel blue affinity chromatography, was subjected to ultrahigh-pressure (UHP) treatment (150, 250, 350, and 450 MPa). The purified PHA lost its hemagglutination activity after 450 MPa treatment and showed less pressure tolerance than crude PHA. However, the saccharide specificity and α-glucosidase inhibition activity of the purified PHA did not change much after UHP treatment. Electrophoresis staining by periodic acid-Schiff (PAS) manifested that the glycone structure of purified PHA remained stable even after 450 MPa pressure treatment. However, electrophoresis staining by Coomassie Blue as well as circular dichroism (CD) and differential scanning calorimetry (DSC) assay proved that the protein unit structure of purified PHA unfolded when treated at 0-250 MPa but reaggregates at 250-450 MPa. Therefore, the hemagglutination activity tends to be affected by the protein unit structure, while the stability of the glycone structure contributed to the remaining α-glucosidase inhibition activity.

Ginsenoside extraction from Panax quinquefolium L. (American ginseng) root by using ultrahigh pressure.

PubMed

Zhang, Shouqin; Chen, Ruizhan; Wu, Hua; Wang, Changzheng

2006-04-11

A new method of ultrahigh pressure extraction (UPE) was used to extract the ginsenosides from Panax quinquefolium L. (American ginseng) root at room temperature. Several solvents, including water, ethanol, methanol, and n-butanol were used in the UPE. The ginsenosides were quantified by a HPLC equipped with UV-vis detector. The results showed that ethanol is the most efficient solvent among the used ones. Compared with other methods, i.e., Soxhlet extraction, heat reflux extraction, ultrasound-assisted extraction, microwave-assisted extraction, and supercritical CO2 extraction, the UPE has the highest extraction yield in the shortest time. The extraction yield of 0.861% ginsenoside-Rc in 2 min was achieved by the UPE, while the yields of 0.284% and 0.661% were obtained in several hours by supercritical CO2 extraction and the heat reflux extraction, respectively.

Pliocene eclogite exhumation at plate tectonic rates in eastern Papua New Guinea.

PubMed

Baldwin, Suzanne L; Monteleone, Brian D; Webb, Laura E; Fitzgerald, Paul G; Grove, Marty; Hill, E June

2004-09-16

As lithospheric plates are subducted, rocks are metamorphosed under high-pressure and ultrahigh-pressure conditions to produce eclogites and eclogite facies metamorphic rocks. Because chemical equilibrium is rarely fully achieved, eclogites may preserve in their distinctive mineral assemblages and textures a record of the pressures, temperatures and deformation the rock was subjected to during subduction and subsequent exhumation. Radioactive parent-daughter isotopic variations within minerals reveal the timing of these events. Here we present in situ zircon U/Pb ion microprobe data that dates the timing of eclogite facies metamorphism in eastern Papua New Guinea at 4.3 +/- 0.4 Myr ago, making this the youngest documented eclogite exposed at the Earth's surface. Eclogite exhumation from depths of approximately 75 km was extremely rapid and occurred at plate tectonic rates (cm yr(-1)). The eclogite was exhumed within a portion of the obliquely convergent Australian-Pacific plate boundary zone, in an extending region located west of the Woodlark basin sea floor spreading centre. Such rapid exhumation (> 1 cm yr(-1)) of high-pressure and, we infer, ultrahigh-pressure rocks is facilitated by extension within transient plate boundary zones associated with rapid oblique plate convergence.

An ultrahigh pressure homogenization technique for easily exfoliating few-layer phosphorene from bulk black phosphorus

NASA Astrophysics Data System (ADS)

Guan, Qing-Qing; Zhou, Hua-Jing; Ning, Ping; Lian, Pei-Chao; Wang, Bo; He, Liang; Chai, Xin-Sheng

2018-05-01

We have developed an easy and efficient method for exfoliating few-layer sheets of black phosphorus (BP) in N-methyl-2-pyrrolidone, using ultra-high pressure homogenization (UPH). The BP was first exfoliated into sheets that were a few atomic layers thick, using a homogenizer for only 30 min. Next, a double centrifugation procedure was used to separate the material into few-layer nanosheets that were examined by X-ray diffraction, atomic force microscopy (AFM), transmission electron microscopy (TEM), high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM), and energy-dispersive X-ray (EDX) spectroscopy. The results show that the products are specimens of phosphorene that are only a few-layer thick.

Ultra-High Pressure Driver and Nozzle Survivability in the RDHWT/MARIAH II Hypersonic Wind Tunnel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Costantino, M.; Brown, G.; Raman, K.

2000-06-02

An ultra-high pressure device provides a high enthalpy (> 2500 kJ/kg), low entropy (< 5 kJ/kg-K) air source for the RDHWT/MARIAH II Program Medium Scale Hypersonic Wind Tunnel. The design uses stagnation conditions of 2300 MPa (330,000 Psi) and 750 K (900 F) in a radial configuration of intensifiers around an axial manifold to deliver pure air at 100 kg/s mass flow rates for run times suitable for aerodynamic, combustion, and test and evaluation applications. Helium injection upstream of the nozzle throat reduces the throat wall recovery temperature to about 1200 K and reduces the oxygen concentration at the nozzlemore » wall.« less

P-T and structural constraints of lawsonite and epidote blueschists from Liberty Creek and Seldovia: Tectonic implications for early stages of subduction along the southern Alaska convergent margin

NASA Astrophysics Data System (ADS)

López-Carmona, Alicia; Kusky, Timothy M.; Santosh, M.; Abati, Jacobo

2011-01-01

The southern Alaska convergent margin contains several small belts of sedimentary and volcanic rocks metamorphosed to blueschist facies, located along the Border Ranges fault on the contact between the Wrangellia and Chugach terranes. These belts are significant in that they are the most inboard, and thus probably contain the oldest record of Triassic-Jurassic northward-directed subduction beneath Wrangellia. The Liberty Creek HP-LT schist belt is the oldest and the innermost section of the Chugach terrane. Within this belt lawsonite blueschists contains an initial high-pressure assemblage formed by lawsonite + phengite + chlorite + sphene + albite ± apatite ± carbonates and quartz. Epidote blueschists are composed of sodic, sodic-calcic and calcic amphiboles + epidote + phengite + chlorite + albite + sphene ± carbonates and quartz. P-T pseudosections computed from four representative samples constrain maximum pressures at 16 kbar and 250-280 °C for the Lawsonite-bearing blueschists, and 15 kbar and 400-500 °C for the epidote-bearing blueschists, suggesting a initial subduction stage of 50-55 km depth. The growth of late albite porphyroblasts in all samples suggests a dramatic decompression from ca. 9 kbar to 5 kbar. The Liberty Creek schists can be correlated with the Seldovia blueschist belt on the Kenai Peninsula. Metamorphism in both terranes took place in the Early Jurassic (191-192 Ma), recording an early stage of subduction beneath Wrangellia. In the nearby terranes of the same margin, the age of metamorphism records an early stage of subduction at 230 Ma. Based on this difference in age, a maximum of 40 Ma were necessary to subduct the protoliths of the Seldovia and Liberty Creek blueschists to depths of circa 50-55 km, suggesting a minimum vertical component of subduction of 1.2-1.5 cm/year.

Significance of the Nestos Shearzone in the southern Rhodopes (Northern Greece/Southern Bulgaria)

NASA Astrophysics Data System (ADS)

Nagel, Thorsten; Schmidt, Silke; Janak, Marian; Jahn-Awe, Silke; Froitzheim, Niko; Georgiev, Neven

2010-05-01

The Nestos Shearzone can be traced over 100 kilometers and separates the two main units of the Rhodopes, the Rhodope Terrane in the hangingwall from the Pangaion-Pirin Unit in the footwall. The Rhodope Terrane consists of mingled continental and oceanic basement rocks, intruded by granitic bodies of Cenozoic age. It underwent at least amphibolite facies conditions during the Alpine orogenic cycle and several localities with preserved highpressure and/or ultrahigh-pressure rocks have been found. The age of orogenesis and metamorphism is ambiguous and several Mesozoic and Tertiary cycles may be recorded in that unit. The lowermost level immediately on top of the Nestos Shearzone (Sidironero subunit) mainly consists of rocks derived from a Jurassic arc and appears to show the youngest reported (i.e. Eocene) high-grade metamorphism (including ultra-high-pressure conditions and a subsequent migmatic stage). The underlying Pangaion-Pirin Unit beneath the Nestos Shearzone is build of marbles and Variscan gneisses of disputed Mesozoic paleogeographic position. It is intruded by Oligocene granitoids, which also crosscut the Nestos Shearzone. The Pangaion-Pirin Unit experienced a clockwise PT-path culminating at upper greenschist facies conditions during the Alpine cycle. The Nestos Shearzone is defined by top-to-the-southwest-directed mylonites formed under upper greenschist facies conditions. So far, it has been viewed as a thrust. We present structural and petrological data suggesting that the Nestos Shearzone instead represents a major detachment horizon related to late Eo-Oligocene normal faults in the overlying units. Mylonitisation along the shear zone occurred under conditions postdating peak pressures. The shear zone formed between about 40 Ma and 34 Ma as indicated by the age of high temperature conditions in the hangingwall and the age of Oligocene granitoids crosscutting the mylonites. During this time, pronounced extension and basin formation took place in the

Late-Paleozoic-Mesozoic deformational and deformation related metamorphic structures of Kuznetsk-Altai region

NASA Astrophysics Data System (ADS)

Zinoviev, Sergei

2014-05-01

Kuznetsk-Altai region is a part of the Central Asian Orogenic Belt. The nature and formation mechanisms of the observed structure of Kuznetsk-Altai region are interpreted by the author as the consequence of convergence of Tuva-Mongolian and Junggar lithospheric block structures and energy of collision interaction between the blocks of crust in Late-Paleozoic-Mesozoic period. Tectonic zoning of Kuznetsk-Altai region is based on the principle of adequate description of geological medium (without methods of 'primary' state recovery). The initial indication of this convergence is the crust thickening in the zone of collision. On the surface the mechanisms of lateral compression form a regional elevation; with this elevation growth the 'mountain roots' start growing. With an approach of blocks an interblock elevation is divided into various fragments, and these fragments interact in the manner of collision. The physical expression of collision mechanisms are periodic pulses of seismic activity. The main tectonic consequence of the block convergence and collision of interblock units is formation of an ensemble of regional structures of the deformation type on the basis of previous 'pre-collision' geological substratum [Chikov et al., 2012]. This ensemble includes: 1) allochthonous and autochthonous blocks of weakly deformed substratum; 2) folded (folded-thrust) systems; 3) dynamic metamorphism zones of regional shears and main faults. Characteristic of the main structures includes: the position of sedimentary, magmatic and PT-metamorphic rocks, the degree of rock dynamometamorphism and variety rock body deformation, as well as the styles and concentrations of mechanic deformations. 1) block terranes have weakly elongated or isometric shape in plane, and they are the systems of block structures of pre-collision substratum separated by the younger zones of interblock deformations. They stand out among the main deformation systems, and the smallest are included into the

Raman imaging of fluid inclusions in garnet from UHPM rocks (Kokchetav massif, Northern Kazakhstan).

PubMed

Korsakov, Andrey V; Dieing, Thomas; Golovin, Aleksandr V; Toporski, Jan

2011-10-01

Confocal Raman imaging of fluid inclusions in garnet porphyroblasts from diamond-grade metamorphic calc-silicate rocks from the Kumdy-Kol microdiamond deposit (Kokchetav Massif, Northern Kazakhstan) reveals that these fluid inclusions consist of almost pure water with different step-daughter phases (e.g., calcite, mica and rare quartz). These fluid inclusions are characterized by negative crystal shape of the host-garnet and they exclusively occur within the core of garnet porphyroblasts. These observations are consistent with their primary origin, most likely at ultrahigh-pressure (UHP) metamorphic conditions. The euhedral newly formed garnet, different in color and composition, was found to be associated with these fluid inclusions. It is proposed that newly formed garnet and water fluid inclusions appear by reaction between the hydrous fluid and the garnet-host. These fluid inclusions provide an unequivocal record of almost pure H(2)O fluids, indicating water-saturated conditions within subducted continental crust during prograde stage and/or ultrahigh-P metamorphism. Copyright © 2011 Elsevier B.V. All rights reserved.

Metamorphic P-T paths and Precambrian crustal growth in East Antarctica

NASA Technical Reports Server (NTRS)

Harley, S. L.

1988-01-01

The metamorphic constraints on crustal thicknesses in Archean and post-Archean terranes are summarized along with possible implications for tectonic processes. It is important to recognize that P-T estimates represent perturbed conditions and should not be used to estimate steady state geothermal gradients or crustal thicknesses. The example is cited of the Dora Maira complex in the French Alps, where crustal rocks record conditions of 35 kbar and 800 C, implying their subduction to depths of 100 km or more, followed by subsequent uplift to the surface. Therefore such P-T estimates tell more about processes than crustal thicknesses. More importantly, according to the author, are determinations of P-T paths, particularly coupled with age measurements, because these may provide constraints on how and when perturbed conditions relax back to steady state conditions. P-T paths are illustrated that should be expected from specific tectonic processes, including Tibetan style collision, with and without subsequent extension, rifting of thin or thickened crust, and magmatic accretion. Growth of new crust, associated with magmatic accretion, for example, could possibly be monitored with these P-T paths.

Provenance of sandstones in the Golconda terrane, north central Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, E.A.

1991-02-01

The upper Paleozoic Golconda terrane of north-central Nevada is a composite of several structurally bounded subterranes made of clastic, volcanic, and carbonate rocks. The clastic rocks provide important clues for the interpretation of the provenance and paleogeographic settings of the different lithologic assemblages found in these subterranes. Two petrographically distinct sandstones are identified in the Golconda terrane in the Osgood Mountains and the Hot springs Range of north-central Nevada. The sandstone of the Mississippian Farrel Canyon Formation, part of the Dry Hills subterrane, is characterized by quartzose and sedimentary and lithic-rich clasts with a small feldspar component. in contrast, themore » sandstone of the Permian Poverty Peak (II) subterrane is a silty quartzarenite with no lithic component, and a very limited feldspar component. The sandstone of the Farrel Canyon Formation is similar to nonvolcanic sandstones reported from elsewhere in the Golconda terrane. Modal data reflect a provenance of a recycled orogen and permit the interpretation that it could have been derived from the antler orogen as has been proposed for other sandstones of the golconda terrane. The sandstone of the Poverty Peak (II) subterrane is more mature than any of the other sandstones in either the Golconda terrane, the Antler overlap sequence, or the Antler foreland basin sequence. Modal data put the Poverty Peak (II) sandstone in the continental block provenance category. The distinct extrabasinal provenances represented in these different sandstones support the idea that the Golconda basin was made up of complex paleogeographic settings, which included multiple sources of extrabasinal sediment.« less

P-T-t conditions, Nd and Pb isotopic compositions and detrital zircon geochronology of the Massabesic Gneiss Complex, New Hampshire: isotopic and metamorphic evidence for the identification of Gander basement, central New England

USGS Publications Warehouse

Dorais, Michael J.; Wintsch, Robert P.; Kunk, Michael J.; Aleinikoff, John; Burton, William; Underdown, Christine; Kerwin, Charles M.

2012-01-01

We present new evidence for the assignment of the Neoproterozoic Massabesic Gneiss Complex of New Hampshire to the Gander terrane rather than the Avalon terrane. The majority of Avalonian (sensu stricto) igneous and meta-igneous rocks as defined in Maritime Canada have positive whole-rock ɛNd compared to more negative values for Gander rocks, although there is a region of overlap in ɛNd between the two terranes. Our samples from areas in Connecticut previously thought to be Avalonian and samples from the Willimantic dome have the same isotopic signatures as Maritime Canada Avalon. In contrast, samples from the Clinton dome of southern Connecticut plots exclusively in the Gander field. The majority of the orthogneiss samples from Lyme dome (coastal Connecticut), Pelham dome (central Massachusetts) and Massabesic Gneiss Complex also plot in the Gander field, with a few samples plotting in the overlap zone between Gander and Avalon. U-Pb age distributions of detrital zircon populations from quartzites from the Massabesic Gneiss Complex more closely approximate the data from the Lyme Dome rather than Avalon. Additionally, the similarity of the P-T-t path for the rocks of the Massabesic Gneiss Complex (established by thermobarometry and 40Ar/39Ar dating of amphibole, muscovite, biotite and K-feldspar) with that established in the Ganderian Lyme dome of southern Connecticut strengthens the assignment of these rocks to a single Gander block that docked to Laurentia during the Salinic Orogeny. The identification of Ganderian isotopic signatures for these rocks all of which show evidence for Alleghanian metamorphism, supports the hypothesis that Neoproterozoic Gander lower crustal rocks underlie southern New Hampshire, Massachusetts, and Connecticut, and that all rocks of the overlying Central Maine trough that largely escaped high-grade Alleghanian metamorphism are allochthonous. We suggest that during the Alleghanian, the docking of Gondwana caused Avalon to wedge into

P-T evolution of metasedimentary rocks of the Santa Filomena Complex, Riacho do Pontal Orogen, Borborema Province (NE Brazil): Geothermobarometry and metamorphic modelling

NASA Astrophysics Data System (ADS)

Santos, Felipe H.; Amaral, Wagner S.; Luvizotto, George L.; Martins de Sousa, Daniel F.

2018-03-01

We present in this paper petrologic data and discuss the pressure-temperature (P-T) metamorphic history of the neoproterozoic metasedimentary rocks of the Santa Filomena Complex, Riacho do Pontal Orogen, which is inserted in the southern portion of the Borborema Province (Northeast Brazil). Therefore, the data provide constraints on metamorphic evolution during Neoproterozoic Brasiliano Orogeny in Northeast Brazil. The rocks studied are aluminous schists and paragneisses. Silver-gray and red pelitic schists are intensely deformed, biotite-muscovite rich, contain centimeter-sized garnet, staurolite and kyanite porphyroblasts, and subordinately plagioclase and quartz. Paragneisses are from light gray to dark gray colored, medium to coarse-grained and display a well-spaced foliated matrix of biotite, and kyanite and garnet porphyroblasts. Locally, the schists and paragneisses are migmatized. Pressure-temperature modelling based on thermobarometric calculations indicate that metamorphism reached 643 °C with pressures estimated in 12 kbar. Pre-peak and post-peak metamorphic conditions are constrained by mineralogical and textural relationships: garnet inclusion-rich and inclusion-free (possible of higher T) are documented and the inclusion-rich core probably indicates a Sn-1 foliation that was transposed by Sn. The pre-peak stage most probably occurred close to 500 °C and 8 kbar, in upper greenschist to lower amphibolite facies metamorphism along kyanite stability field. We also propose that post-peak stage was associated with isothermal decompression along a possible path of tectonic exhumation in conditions of 600 °C and 7 kbar. To further evaluate the equilibrium condition, pressure-temperature pseudosections were calculated for the metasedimentary rocks. Thus, the estimated metamorphic peak took place in the upper amphibolite facies. A suggested clockwise pressure-temperature path is compatible with the regional tectonic setting of continent-continent collision

The use of ultra-high pressure liquid chromatography with tandem mass spectrometric detection of analysis of agrochemical residues and mycotoxines in food - challenges and applications

USDA-ARS?s Scientific Manuscript database

In the field of food contaminant analysis, the most significant development of recent years has been the integration of ultra-high pressure liquid chromatography (UHPLC), coupled to tandem quadrupole mass spectrometry (MS/MS), into analytical applications. In this review, we describe the emergence o...

An inverted metamorphic field gradient in the central Brooks Range, Alaska and implications for exhumation of high-pressure/low-temperature metamorphic rocks

USGS Publications Warehouse

Patrick, B.; Till, A.B.; Dinklage, W.S.

1994-01-01

During exhumation of the Brooks Range internal zone, amphibolite-facies rocks were emplaced atop the blueschist/greenschist facies schist belt. The resultant inverted metamorphic field gradient is mappable as a series of isograds encountered as one traverses up structural section. Amphibolite-facies metamorphism occurred at ??? 110 Ma as determined from 40Ar 39Ar analysis of hornblende. This contrasts with 40Ar 39Ar phengite cooling ages from the uderlying schist belt, which are clearly older (by 17-22 m.y.). Fabrics in both the amphibolite-facies rocks and schist belt are characterized by repeated cycles of N-vergent crenulation and transposition that was likely associated with out-of-sequence ductile thrusting in the internal zone of the Brooks Range orogen. Contractional deformation occurred in an overall environment of foreland-directed tectonic transport, broadly synchronous with exhumation of the internal zone, and shortening within the thin-skinned fold and thrust belt. These data are inconsistent with a recently postulated mid-Cretaceous episode of lithospheric extension in northern Alaska. ?? 1994.

Low Pressure-High Temperature Metamorphism and the Advection of Heat to the Continental Crust: A Case Study from Northwest New Guinea

NASA Astrophysics Data System (ADS)

Jost, B.; Webb, M.; White, L. T.

2017-12-01

In northwest New Guinea, Palaeozoic basement rocks forming part of the northern margin of the Australian continent are exposed in a rugged mountain range. This remote and understudied region provides a unique window into the complex Palaeozoic evolution and tectonic history of this region, which we help unravel with new field, petrographic, geochemical, and geochronological data. The basement rocks consist of extensive meta-turbidites that were subject to low pressure-high temperature metamorphism along their eastern margin. They are cross-cut by predominantly acidic granitoids. U-Pb zircon dating reveals that these granitoids intruded in three episodes in the Devonian-Carboniferous, the Carboniferous, and the Triassic. The first episode has not previously been reported in the region. The granitoids are strongly peraluminous, suggesting that partial melting of the meta-sedimentary country rock contributed to their petrogenesis (S-type). The occurrence and character of country rock xenoliths and migmatites supports this interpretation. Equilibrium thermodynamic modelling of the metapelites and the migmatites indicates that a substantial amount of heat was added to the lower and middle crust to cause partial melting and regional metamorphism at relatively low pressure. We propose repeated intrusion of hot magma as the mechanism responsible for advecting the necessary heat from the mantle. This likely occurred in an active continental margin setting during the Devonian-Carboniferous and the Triassic, possibly separated by an interval of magmatic quiescence during most of the Permian. New biostratigraphic and low-temperature thermochronological data reveal very recent Pliocene-Pleistocene uplift and unroofing of these basement rocks.

Geochemistry, petrography, and zircon U-Pb geochronology of Paleozoic metaigneous rocks in the Mount Veta area of east-central Alaska: implications for the evolution of the westernmost part of the Yukon-Tanana terrane

USGS Publications Warehouse

Dusel-Bacon, Cynthia; Day, Warren C.; Aleinikoff, John N.

2013-01-01

We report the results of new mapping, whole-rock major, minor, and trace-element geochemistry, and petrography for metaigneous rocks from the Mount Veta area in the westernmost part of the allochthonous Yukon–Tanana terrane (YTT) in east-central Alaska. These rocks include tonalitic mylonite gneiss and mafic metaigneous rocks from the Chicken metamorphic complex and the Nasina and Fortymile River assemblages. Whole-rock trace-element data from the tonalitic gneiss, whose igneous protolith was dated by SHRIMP U–Pb zircon geochronology at 332.6 ± 5.6 Ma, indicate derivation from tholeiitic arc basalt. Whole-rock analyses of the mafic rocks suggest that greenschist-facies rocks from the Chicken metamorphic complex, a mafic metavolcanic rock from the Nasina assemblage, and an amphibolite from the Fortymile River assemblage formed as island-arc tholeiite in a back-arc setting; another Nasina assemblage greenschist has MORB geochemical characteristics, and another mafic metaigneous rock from the Fortymile River assemblage has geochemical characteristics of calc-alkaline basalt. Our geochemical results imply derivation in an arc and back-arc spreading region within the allochthonous YTT crustal fragment, as previously proposed for correlative units in other parts of the terrane. We also describe the petrography and geochemistry of a newly discovered tectonic lens of Alpine-type metaharzburgite. The metaharzburgite is interpreted to be a sliver of lithospheric mantle from beneath the Seventymile ocean basin or from sub-continental mantle lithosphere of the allochthonous YTT or the western margin of Laurentia that was tectonically emplaced within crustal rocks during closure of the Seventymile ocean basin and subsequently displaced and fragmented by faults.

Raman spectroscopy of detrital garnet from the (U)HP terrane of eastern Papua New Guinea

NASA Astrophysics Data System (ADS)

Andò, Sergio; Baldwin, Suzanne L.; Fitzgerald, Paul G.; Malusà, Marco G.; Aliatis, Irene; Vezzoli, Giovanni; Garzanti, Eduardo

2013-04-01

adjacent to orogenic systems, Raman-assisted heavy-mineral studies allow us to detect the first arrival of eclogitic garnet, and thus to assess the minimum age of exhumation and final unroofing of high-pressure rocks (Malusà et al., 2011; Malusà and Garzanti, 2012). However, in the (U)HP terrane of southeastern Papua New Guinea, sediments derived from the actively exhuming D'Entrecasteaux Island core complexes are still being deposited offshore, are rarely preserved sub-aerially, and as such stratigraphic constraints are limited. Raman analysis of detrital garnets from placer sand thus provides invaluable constraints to compare with mineral assemblages preserved in exhumed eclogites. REFERENCES Andò S., Bersani D., Vignola P., Garzanti E. 2009. Raman spectroscopy as an effective tool for high-resolution heavy-mineral analysis: Examples from major Himalayan and Alpine fluvio-deltaic systems. Spectrochim. Acta A73:450-455. Andò S., Morton A., Garzanti E. 2013. Metamorphic grade of source rocks revealed by chemical fingerprints of detrital amphibole and garnet. Geol. Soc. London Spec. Publ. Sediment Provenance Studies in Hydrocarbon Exploration & Production. Baldwin S.L., Monteleone B., Webb L.E., Fitzgerald P.G., Grove M., Hill E.J. 2004. Pliocene eclogite exhumation at plate tectonic rates in eastern Papua New Guinea. Nature 431:263-267. Baldwin S.L., Webb L.E., Monteleone B.D. 2008. Late Miocene coesite-eclogite exhumed in the Woodlark Rift. Geology 36:735-738 Bersani D., Andò S., Vignola P., Moltifiori G., Marino I.G., Lottici P.P., Diella V., 2009. Micro-Raman spectroscopy as a routine tool for garnet analysis. Spectrochim. Acta A73:484-491. Hill E.J., Baldwin S.L. 1993. Exhumation of high-pressure metamorphic rocks during crustal extension in the D'Entrecasteaux region, Papua New Guinea. J. Metam. Geol. 11:261-277. Malusà M.G., Faccenna C., Garzanti E., Polino R. 2011. Divergence in subduction zones and exhumation of high-pressure rocks (Eocene Western Alps

40Ar/39Ar thermochronology of mesoproterozoic metamorphism in the Colorado Front Range

USGS Publications Warehouse

Shaw, C.A.; Snee, L.W.; Selverstone, J.; Reed, J.C.

1999-01-01

A low-pressure metamorphic episode in the Colorado Front Range has been identified by the presence of staurolite, andalusite, cordierite, and garnet porphyroblasts overprinting earlier assemblages. The overprinting assemblages and reaction textures are most consistent with porphyroblast growth on a prograde metamorphic path with peak temperatures exceeding ~525??C. Twenty-eight 40Ar/39Ar dates on hornblende, muscovite, biotite, and microcline were used to infer the age and thermal conditions of metamorphism. Muscovite and biotite 40Ar/39Ar ages fall mainly in the interval 1400-1340 Ma, consistent with cooling through the closure temperature interval of micas (~400??-300??C) after about 1400 Ma. In contrast, hornblende apparent ages (T(c)~500??-550??C) between 1600 and 1390 Ma reflect variable retention of radiogenic argon. Forward modeling of argon diffusion shows that the distribution of hornblende and mica ages is consistent with the partial resetting of argon systematics ca. 1400 Ma by a thermal pulse reaching maximum temperatures around 550??C and decaying within <20 m.yr. These temperatures match the conditions inferred from the overprinting assemblage; thus, muscovite and biotite ages are interpreted to date the cooling phase of this metamorphic event. This late metamorphism is broadly coeval with the intrusion of ca. 1400-Ma granitic plutons in the study area and throughout the southwestern United States. However, thermal effects are observed far from pluton margins, suggesting pervasive, regional crustal heating rather than restricted contact metamorphism. Our results suggest that ca. 1400-Ma metamorphism and plutonism are manifestations of a regional thermal episode that both partially melted the lower crust and pervasively metamorphosed middle crustal rocks.

Metamorphic Epitaxy for Multijunction Solar Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

France, Ryan M.; Dimroth, Frank; Grassman, Tyler J.

Multijunction solar cells have proven to be capable of extremely high efficiencies by combining multiple semiconductor materials with bandgaps tuned to the solar spectrum. Reaching the optimum set of semiconductors often requires combining high-quality materials with different lattice constants into a single device, a challenge particularly suited for metamorphic epitaxy. In this article, we describe different approaches to metamorphic multijunction solar cells, including traditional upright metamorphic, state-of-the-art inverted metamorphic, and forward-looking multijunction designs on silicon. We also describe the underlying materials science of graded buffers that enables metamorphic subcells with low dislocation densities. Following nearly two decades of research, recentmore » efforts have demonstrated high-quality lattice-mismatched multijunction solar cells with very little performance loss related to the mismatch, enabling solar-to-electric conversion efficiencies over 45%.« less

The relationship between continental collision process and metamorphic pattern in the Himalayan collision belts

NASA Astrophysics Data System (ADS)

Oh, Chang-Whan

2015-04-01

Both UHP and HP eclogites are reported from the Kaghan Valley and Tso Morari Massif in the western part of the Himalayan collision belt (Ghazanfar and Chaudhry, 1987; Thakur, 1983). UHP eclogites in the Kaghan record peak metamorphic conditions of 770 °C and 30 kbar (O'Brien et al., 2001) and was retrograded into the epidote-amphibolite or blueschist (580-610 °C, 10-13 kbar; Lombardo and Rolfo, 2000). Sensitive high-resolution ion microprobe dating of zircon reveals that the UHP eclogite formed at ca. 46 Ma (Kaneko et al., 2003; Parrish et al., 2006). The Tso Morari UHP eclogite had formed at 750 °C, > 39 kbar (Mukheerjee et al., 2003; Bundy, 1980) and underwent amphibolite facies retro-grade metamorphism (580 °C, 11 kbar) during uplift (Guillot et al., 2008). Peak metamorphism of the Tso Morari Massif was dated at ca. 53-55 Ma (Leech et al., 2005). Only HP eclogites have been reported from the mid-eastern part of the Himalayan collision belt (Lombardo and Rolfo, 2000; Corrie et al., 2010). The HP eclogite in the mid-eastern part may have formed at ca. > 780 °C and 20 kbar and was overprinted by high-pressure granulite facies metamorphism (780-750°C, 12-10 kbar) at ca. 30 Ma (Groppo et al. 2007; Corrie et al., 2010). HP granulite (890 °C, 17-18 kbar) is reported from the NBS, at the eastern terminus of the Himalayan collision belt; the granulite was subjected to retrograde metamorphism to produce lower-pressure granulite (875-850°C, 10-5 kbar), representing near-isothermal decompression (Liu and Zhong, 1997). The HP granulite metamorphism may have occurred at ca. 22-25 Ma. Along the Himalayan collision belt, peak metamorphism changes eastward from UHP eclogite facies through HP eclogite facies to high-pressure granulite facies, indicating a progressive eastwards decrease in the depth of subduction of continental crust and an eastwards increase in the geothermal gradient. The peak metamorphic ages also decrease from 53-46 Ma in the west to 22-25 Ma in the

PTt path in metamorphic rocks of the Khoy region (northwest Iran) and their tectonic significance for Cretaceous Tertiary continental collision

NASA Astrophysics Data System (ADS)

Azizi, H.; Moinevaziri, H.; Mohajjel, M.; Yagobpoor, A.

2006-06-01

Metamorphic rocks in the Khoy region are exposed between obducted ophiolites to the southwest and sedimentary rocks of Precambrian-Paleozoic age to the northeast. The Qom formation (Oligocene-Miocene) with a basal conglomerate transgressively overlies all of these rocks. The metamorphic rocks consist of both metasediments and metabasites. The metasediments are micaschist, garnet-staurolite schist and garnet-staurolite sillimanite schist with some meta-arkose, marble and quartzite. The metabasites are metamorphosed to greenschist and amphibolite facies from a basaltic and gabbroic protolith of tholeiitic and calc-alkaline rocks. Geothermobarometry based on the equivalence of minerals stability and their paragenesis in these rocks and microprobe analyses by several different methods indicate that metamorphism occurred in a temperature range between 450 and 680 °C at 5.5 and 7.5 kb pressure. Rims of minerals reveal a considerable decrease of pressure (<2 kb) and insignificant decrease of temperature. The PTt path of this metamorphism is normal. The MFG line passes above the triple junction of Al 2SiO 5 polymorphs, and the average geothermal gradient during metamorphism was from 27 to 37 °C/km, which is more concordant with the temperature regime of collision zones. We infer that crustal thickening during post-Cretaceous (possibly Eocene) collision of the Arabian plate and the Azerbaijan-Albourz block was the main factor that caused the metamorphism in the studied area.

Metamorphic records for subduction erosion and subsequent underplating processes revealed by garnet-staurolite-muscovite schists in central Qiangtang, Tibet

NASA Astrophysics Data System (ADS)

Zhang, Xiu-Zheng; Dong, Yong-Sheng; Wang, Qiang; Dan, Wei; Zhang, Chunfu; Xu, Wang; Huang, Ming-Liang

2017-01-01

Subduction erosion is confirmed as a crucial geodynamic process of crustal recycling based on geological, geochemical, and geophysical observations at modern convergent plate margins. So far, not a single metamorphic record has been used for constraining a general tectonic evolution for subduction erosion. Here we first revealed metamorphic records for a subduction erosion process based on our study of the Late Paleozoic garnet-staurolite-muscovite schists in the central Qiangtang block, Tibet. Provenance analyses suggest that the protoliths of garnet-staurolite-muscovite schists have the Northern Qiangtang-affinity and were deposited in an active continental margin setting. Mineral inclusion data show that the early metamorphic stage (M1) recorded blueschist facies pressure-temperature (P-T) conditions of 0.8-1.1 GPa and 402-441°C, indicating that a part of the material from the overriding plate had been abraded into the subduction channel and undergone high-pressure/low-temperature metamorphism. The peak metamorphic stage (M2) recorded amphibolite facies P-T conditions of 0.3-0.5 GPa and 470-520°C. The 40Ar/39Ar cooling ages (263-259 Ma) yielded from muscovite suggest the amphibolite facies metamorphism (>263 Ma) occurred at oceanic subduction stage. The distinctly staged metamorphism defines a clockwise and warming decompression P-T-t path which reveals an underplating process following the early subduction erosion. During the tectonic process, the eroded low-density material escaped from the cold subduction channel and rise upward into the warm middle-lower crust of the upper plate, undergoing amphibolite facies metamorphism. Our new results revealed a complete evolutional process from the early subduction erosion to the subsequent underplating during the northward subduction of the Paleo-Tethys Ocean.

Shear heating and metamorphism in subduction zones, 1. Thermal models

NASA Astrophysics Data System (ADS)

Kohn, M. J.; Castro, A. E.; Spear, F. S.

2017-12-01

Popular thermal-mechanical models of modern subduction systems are 100-500 °C colder at c. 50 km depth than pressure-temperature (P-T) conditions determined from exhumed metamorphic rocks. This discrepancy has been ascribed by some to profound bias in the rock record, i.e. metamorphic rocks reflect only anomalously warm subduction, not normal subduction. Accurately inferring subduction zone thermal structure, whether from models or rocks, is crucial for predicting depths of seismicity, fluid release, and sub-arc melting conditions. Here, we show that adding realistic shear stresses to thermal models implies P-T conditions quantitatively consistent with those recorded by exhumed metamorphic rocks, suggesting that metamorphic rock P-T conditions are not anomalously warm. Heat flow measurements from subduction zone fore-arcs typically indicate effective coefficients of friction (µ) ranging from 0.025 to 0.1. We included these coefficients of friction in analytical models of subduction zone interface temperatures. Using global averages of subducting plate age (50 Ma), subduction velocity (6 cm/yr), and subducting plate geometry (central Chile), temperatures at 50 km depth (1.5 GPa) increase by c. 200 °C for µ=0.025 to 700 °C for µ=0.1. However, at high temperatures, thermal softening will reduce frictional heating, and temperatures will not increase as much with depth. Including initial weakening of materials ranging from wet quartz (c. 300 °C) to diabase (c. 600 °C) in the analytical models produces concave-upward P-T distributions on P-T diagrams, with temperatures c. 100 to 500 °C higher than models with no shear heating. The absolute P-T conditions and concave-upward shape of the shear-heating + thermal softening models almost perfectly matches the distribution of P-T conditions derived from a compilation of exhumed metamorphic rocks. Numerical models of modern subduction zones that include shear heating also overlap metamorphic data. Thus, excepting the

New Insights from Seismic Imaging over the Youanmi Terrane, Western Australia

NASA Astrophysics Data System (ADS)

Ahmadi, Omid; Juhlin, Christopher

2014-05-01

The Youanmi terrane is located in the central parts of the Yilgarn craton, Western Australia, an Archean granite-greenstone unit containing numerous mineral deposits such as gold, base metals, nickel, uranium and gemstones. The terrane is surrounded by the Kalgoorlie and Narryer terranes to the east and west, respectively. To the southwest it is bounded by the South West terrane. In order to study the transitions between the Youanmi terrane and the surrounding terranes, as well as identifying potential mineral rich areas, the Geological Survey of Western Australia acquired three deep crustal 2D seismic profiles with a total length of about 700 km in 2010. Correlated record lengths of 20 seconds allow the deep structure of the crust to be investigated with the data, down to Moho depths and greater. Initial processing using a conventional 2D flow show a highly reflective crust with several interesting features. We have now reprocessed the data following mainly the previous processing flow, but with a focus on the shallower crust, less than 10 seconds (about 27 km). Due to the complex geology in the region, 3D aspects of the structures need to be considered in the data processing. Therefore, we investigated the effect of cross-dip corrections to the data. The cross-dip correction has two advantages; (i) reflections are more coherent and enhanced after the correction and (ii) the orientation and dip angle of the geological structures of the corresponding reflections can be identified in the cross-line direction. Where the profiles intersect each other sparse 3D processing can be performed. First arrival travel-time tomography was also tested on parts of the dataset. Travel-time inversion may provide better velocity models at shallow depths than standard reflection seismic processing provides. Preliminary results show that the travel-time tomography has a depth of investigation of about 1 km, a depth that is of interest for mining purposes. Therefore, the tomography

Ultrahigh pressure fast size exclusion chromatography for top-down proteomics.

PubMed

Chen, Xin; Ge, Ying

2013-09-01

Top-down MS-based proteomics has gained a solid growth over the past few years but still faces significant challenges in the LC separation of intact proteins. In top-down proteomics, it is essential to separate the high mass proteins from the low mass species due to the exponential decay in S/N as a function of increasing molecular mass. SEC is a favored LC method for size-based separation of proteins but suffers from notoriously low resolution and detrimental dilution. Herein, we reported the use of ultrahigh pressure (UHP) SEC for rapid and high-resolution separation of intact proteins for top-down proteomics. Fast separation of intact proteins (6-669 kDa) was achieved in < 7 min with high resolution and high efficiency. More importantly, we have shown that this UHP-SEC provides high-resolution separation of intact proteins using a MS-friendly volatile solvent system, allowing the direct top-down MS analysis of SEC-eluted proteins without an additional desalting step. Taken together, we have demonstrated that UHP-SEC is an attractive LC strategy for the size separation of proteins with great potential for top-down proteomics. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Regional geophysical expression of a carbonatite terrane in the eastern Mojave Desert, California

USGS Publications Warehouse

Ponce, David A.; Denton, Kevin M.; Miller, David M.

2013-01-01

, magnetic, and radiometric signatures because these deposits are relatively dense, have primary magnetite, and are enriched in thorium or uranium. In this case, because the carbonatite rocks in this Proterozoic terrane are themselves essentially nonmagnetic, they are not the source of the magnetic high associated with the Clark Mountain and Mescal Ranges. Instead, we suggest that weakly to moderately magnetic syenite intrusions or other granitic or metamorphic rocks in the region are the source of the magnetic high. Gravity data indicate that basins within the eastern Mojave carbonatite terrane are complicated. For example, a gravity high in the northern part of Ivanapah Valley suggest that the basin is underlain by shallow basement rocks, whereas the southern part of Ivanpah Valley extends to a depth of about 2 km. Combined gravity, magnetic, and geologic studies improve the current geophysical framework and structural interpretation of the eastern Mojave Desert carbonatite terrane.

Fluid-absent metamorphism in the Adirondacks

NASA Technical Reports Server (NTRS)

Valley, J. W.

1986-01-01

Results on late Proterozoic metamorphism of granulite in the Adirondacks are presented. There more than 20,000 sq km of rock are at granulite facies. Low water fugacites are implied by orthopyroxene bearing assemblages and by stability of k'spar-plag-quartz assemblages. After mentioning the popular concept of infiltration of carbon dioxide into Precambrian rocks and attendent generation of granulite facies assemblages, several features of Adirondack rocks pertinent to carbon dioxide and water during their metamorphism are summarized: wollastonite occurs in the western lowlands; contact metamorphism by anorthosite preceeding granulite metamorphism is indicated by oxygen isotopes. Oxygen fugacity lies below that of the QFM buffer; total P sub water + P sub carbon dioxide determined from monticellite bearing assemblages are much less than P sub total (7 to 7.6 kb). These and other features indicate close spatial association of high- and low-P sub carbon dioxide assemblages and that a vapor phase was not present during metamorphism. Thus Adirondack rocks were not infiltrated by carbon dioxide vapor. Their metamorphism, at 625 to 775 C, occurred either when the protoliths were relatively dry or after dessication occurred by removal of a partial melt phase.

Origin and tectonic evolution of early Paleozoic arc terranes abutting the northern margin of North China Craton

NASA Astrophysics Data System (ADS)

Zhou, Hao; Pei, Fu-Ping; Zhang, Ying; Zhou, Zhong-Biao; Xu, Wen-Liang; Wang, Zhi-Wei; Cao, Hua-Hua; Yang, Chuan

2017-12-01

The origin and tectonic evolution of the early Paleozoic arc terranes abutting the northern margin of the North China Craton (NCC) are widely debated. This paper presents detrital zircon U-Pb and Hf isotopic data of early Paleozoic strata in the Zhangjiatun arc terrane of central Jilin Province, northeast (NE) China, and compares them with the Bainaimiao and Jiangyu arc terranes abutting the northern margin of the NCC. Detrital zircons from early Paleozoic strata in three arc terranes exhibit comparable age groupings of 539-430, 1250-577, and 2800-1600 Ma. The Paleoproterozoic to Neoarchean ages and Hf isotopic composition of the detrital zircons imply the existence of the Precambrian fragments beneath the arc terranes. Given the evidences from geology, igneous rocks, and detrital zircons, we proposed that the early Paleozoic arc terranes abutting the northern margin of the NCC are a united arc terrane including the exotic Precambrian fragments, and these fragments shared a common evolutionary history from Neoproterozoic to early-middle Paleozoic.

Accretion of Grenvillian terranes to the southwestern border of the Río de la Plata craton, western Argentina

NASA Astrophysics Data System (ADS)

Varela, Ricardo; Basei, Miguel A. S.; González, Pablo D.; Sato, Ana M.; Naipauer, Maximiliano; Campos Neto, Mario; Cingolani, Carlos A.; Meira, Vinicius T.

2011-04-01

A comprehensive review of the geological, geochronological, and isotopic features of the Mesoproterozoic Grenvillian terranes attached to the southwest of the Río de la Plata craton in Early Paleozoic times is presented in this paper. They are grouped into the northern (sierras de Umango, Maz and del Espinal and surroundings), central (Sierra de Pie de Palo, southern Precordillera and Frontal Cordillera), and southern (San Rafael and Las Matras Blocks) segments. The Mesoproterozoic basement consists mainly of arc related, intermediate to acidic and mafic-ultramafic rocks of 1,244-1,027 Ma, with juvenile, Laurentian affinity. Exception to it is the Maz Group, with a protracted history and reworked character. They are affected by 846-570 Ma, extensional magmatism in the northern and central segments, which represents the Neoproterozoic breakup of the Rodinia supercontinent. Successive passive margin sedimentation is registered in Late Neoproterozoic (~640-580 Ma) and Cambro-Ordovician (~550-470 Ma) times. The southern segment is noted for the younger sedimentation alone, and for showing the exclusive primary unconformable relationship between the Mesoproterozoic basement and Early Ordovician cover. The effects of Early Paleozoic Famatinian orogeny, associated with the collisions of Cuyania and Chilenia terranes, are recorded as main phase (480-450 Ma), late phase (440-420 Ma), and Chanic phase (400-360 Ma). Among them, the tectonothermal climax is the Ordovician main phase, to which klippe and nappe structures typical of collisional orogens are related in the northern and central segments. Preliminary data allow us to suggest a set of paired metamorphic belts, with an outboard high-P/T belt, and an inboard Barrowian P/T belt.

Shock metamorphism of planetary silicate rocks and sediments: Proposal for an updated classification system

NASA Astrophysics Data System (ADS)

Stöffler, Dieter; Hamann, Christopher; Metzler, Knut

2018-01-01

We reevaluate the systematics and geologic setting of terrestrial, lunar, Martian, and asteroidal "impactites" resulting from single or multiple impacts. For impactites derived from silicate rocks and sediments, we propose a unified and updated system of progressive shock metamorphism. "Shock-metamorphosed rocks" occur as lithic clasts or melt particles in proximal impactites at impact craters, and rarely in distal impactites. They represent a wide range of metamorphism, typically ranging from unshocked to shock melted. As the degree of shock metamorphism, at a given shock pressure, depends primarily on the mineralogical composition and the porosity of a rock or sediment sample, different shock classification systems are required for different types of planetary rocks and sediments. We define shock classification systems for eight rock and sediment classes which are assigned to three major groups of rocks and sediments (1) crystalline rocks with classes F, M, A, and U; (2) chondritic rocks (class C); and (3) sedimentary rocks and sediments with classes SR, SE, and RE. The abbreviations stand for felsic (F), mafic (M), anorthositic (A), ultramafic (U), sedimentary rocks (SR), unconsolidated sediments (SE), and regoliths (RE). In each class, the progressive stages of shock metamorphism are denominated S1 to Sx. These progressive shock stages are introduced as: S1-S7 for F, S1-S7 for M, S1-S6 for A, S1-S7 for U, S1-S7 for C, S1-S7 for SR, S1-S5 for SE, and S1-S6 for RE. S1 stands for "unshocked" and Sx (variable between S5 and S7) stands for "whole rock melting." We propose a sequence of symbols characterizing the degree of shock metamorphism of a sample, i.e., F-S1 to F-S7 with the option to add the tabulated pressure ranges (in GPa) in parentheses.

Geochemistry of granitoid rocks from the western Superior Province: Evidence for 2- and 3-stage crustal evolution models

NASA Technical Reports Server (NTRS)

Beakhouse, G. P.; errane) are discussed.

1986-01-01

The Superior Province is divisible into subprovinces that can be classified as greenstone-tonalite, paragneiss, or batholitic terranes and are distinguished by differences in lithologic proportions, metamorphic grade, and structural style. The origin and significance of contrasting geochemical characteristics of plutonic rocks from the Winnipeg River subprovince (a batholithic terrane) and the Wabigoon subprovince (a greenstone-tonalite terrane) are discussed.

Effect of extra-column volume on practical chromatographic parameters of sub-2-μm particle-packed columns in ultra-high pressure liquid chromatography.

PubMed

Wu, Naijun; Bradley, Ashley C; Welch, Christopher J; Zhang, Li

2012-08-01

Effects of extra-column volume on apparent separation parameters were studied in ultra-high pressure liquid chromatography with columns and inlet connection tubings of various internal diameters (id) using 50-mm long columns packed with 1.8-μm particles under isocratic conditions. The results showed that apparent retention factors were on average 5, 11, 18, and 41% lower than those corrected with extra-column volumes for 4.6-, 3.0-, 2.1-, and 1.0-mm id columns, respectively, when the extra-column volume (11.3 μL) was kept constant. Also, apparent pressures were 31, 16, 12, and 10% higher than those corrected with pressures from extra-column volumes for 4.6-, 3.0-, 2.1-, and 1.0-mm id columns at the respective optimum flow rate for a typical ultra-high pressure liquid chromatography system. The loss in apparent efficiency increased dramatically from 4.6- to 3.0- to 2.1- to 1.0-mm id columns, less significantly as retention factors increased. The column efficiency was significantly improved as the inlet tubing id was decreased for a given column. The results suggest that maximum ratio of extra-column volume to column void volume should be approximately 1:10 for column porosity more than 0.6 and a retention factor more than 5, where 80% or higher of theoretically predicted efficiency could be achieved. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Regional fluid and metal mobility in the Dalradian metamorphic belt, Southern Grampian Highlands, Scotland

NASA Astrophysics Data System (ADS)

Craw, D.

1990-10-01

A prominent set of veins was formed during post-metamorphic deformation of the Caledonian Dalradian metamorphic belt. These veins are concentrated in dilational zones in fold hinges, but apophyses follow schistosity and fold axial surface fractures. The veins are most common in the cores of regional structures, especially the Dalradian Downbend and consist of quartz, calcite, chlorite and metallic sulphides and oxides. Metals, including gold, have been concentrated in the veins. The fluid which formed the veins was low salinity (1 5 wt% NaCl and KCl) CO2-bearing (3 16 wt% CO2) water of metamorphic origin. The fluid varies slightly in composition within and between samples, but is essentially uniform in composition over several hundred km2. Vein formation occurred at about 350±50 °C and 200 300 MPa pressure. Further quartz mineralization occurred in some dilational zones at lower temperatures (160 180 °C). This later mineralization was accompanied by CO2 immiscibility. Dilution and oxidation of the metamorphic fluid occurred due to mixing with meteoric water as the rocks passed through the brittle-ductile transition. A similar metamorphic fluid is thought to have been responsible for gold mineralization in the nearby Tyndrum Fault at a later stage in the Dalradian uplift.

Super earth interiors and validity of Birch's Law for ultra-high pressure metals and ionic solids

NASA Astrophysics Data System (ADS)

Ware, Lucas Andrew

2015-01-01

Super Earths, recently detected by the Kepler Mission, expand the ensemble of known terrestrial planets beyond our Solar System's limited group. Birch's Law and velocity-density systematics have been crucial in constraining our knowledge of the composition of Earth's mantle and core. Recently published static diamond anvil cell experimental measurements of sound velocities in iron, a key deep element in most super Earth models, are inconsistent with each other with regard to the validity of Birch's Law. We examine the range of validity of Birch's Law for several metallic elements, including iron, and ionic solids shocked with a two-stage light gas gun into the ultra-high pressure, temperature fluid state and make comparisons to the recent static data.

Pressure - temperature estimates of a phengite eclogite from the Grapesvåre Nappe, Norrbotten, Swedish Caledonides

NASA Astrophysics Data System (ADS)

Bukała, Michał; Majka, Jarosław; Walczak, Katarzyna; Barnes, Christopher; Klonowska, Iwona

2017-04-01

The Seve Nappe Complex (SNC) of the Scandinavian Caledonides has well documented history of high pressure (HP) and ultra-high pressure (UHP) metamorphism (e.g. Klonowska et al. 2014). Eclogites of the SNC occur in two areas in Sweden, namely Jämtland and Norrbotten. The Jämtland eclogites and associated rocks are well studied and provide evidence for the Late Ordovician UHP metamorphism, whereas the Norrbotten eclogites, formed during the Late Cambrian/Early Ordovician, have not been studied in detail, especially in terms of pressure-temperature (P-T) conditions of their formation. Within the SNC in Norrbotten, eclogites are limited to two tectonic lenses - Vaimok and Tsäkkok (e.g. Albrecht, 2000). Within the Vaimok Lens three nappes have been distinguished: (1) the eclogite-free Lower Seve Nappe, (2) the Grapesvåre Nappe and (3) the Maddåive Nappe. The two latter nappes are eclogite-bearing. For this study eclogites were collected from the lowermost part of the Grapesvåre Nappe (from the highly heterogeneous Daunasvagge unit dominated by garnet-bearing mica schists, quartzites and marbles). Eclogite boudins (former dolerite dikes and sills) are usually highly altered due to retrogressive recrystallization. Rare fresh eclogites occur within large boudins (>5m in diameter) and display only minor alteration limited to the scarce veinlets composed of amphibole + feldspar + garnet + zoisite + biotite + rutile + titanite. Metamorphic peak conditions mineral assemblage consists of garnet + omphacite + phengite + quartz + rutile. For P-T estimates the geothermobarometric method of Ravna & Terry (2004) has been used. The garnet-clinopyroxene Fe2+-Mg exchange thermometer and the net-transfer reaction barometer based on the garnet-phengite-omphacite equilibrium yielded a maximum pressure of 26.7 kbar and temperature of 677°C. The obtained temperature might be underestimated due to uncertainties in Fe2+/Fe3+ ratio in pyroxene. Therefore Zr-in-rutile geothermometer by

Insights into a fossil plate interface of an erosional subduction zone: a tectono-metamorphic study of the Tianshan metamorphic belt.

NASA Astrophysics Data System (ADS)

Bayet, Lea; Moritz, Lowen; Li, Jilei; Zhou, Tan; Agard, Philippe; John, Timm; Gao, Jun

2016-04-01

Subduction zone seismicity and volcanism are triggered by processes occurring at the slab-wedge interface as a consequence of metamorphic reactions, mass-transfer and deformation. Although the shallow parts of subduction zones (<30-40 km) can be partly accessed by geophysical methods, the resolution of these techniques is insufficient to characterize and image the plate interface at greater depths (>60km). In order to better understand the plate interface dynamics at these greater depths, one has to rely on the rock record from fossil subduction zones. The Chinese Tianshan metamorphic belt (TMB) represents an ideal candidate for such studies, because structures are well exposed with exceptionally fresh high-pressure rocks. Since previous studies from this area focused on fluid-related processes and its metamorphic evolution was assessed on single outcrops, the geodynamic setting of this metamorphic belt is unfortunately heavily debated. Here, we present a new geodynamic concept for the TMB based on detailed structural and petrological investigations on a more regional scale. A ~11km x 13km area was extensively covered, together with E-W and N-S transects, in order to produce a detailed map of the TMB. Overall, the belt is composed of two greenschist-facies units that constitute the northern and southern border of a large high-pressure (HP) to ultra high-pressure (UHP) unit in the center. This HP-UHP unit is mainly composed of metasediments and volcanoclastic rocks, with blueschist, eclogite and carbonate lenses. Only the southern part of the HP-UHP unit is composed of the uppermost part of an oceanic crust (e.g., pillow basalts and deep-sea carbonates). From south to north, the relative abundance and size of blueschist massive boudins and layers (as well as eclogite boudins) decreases and the sequence is increasingly interlayered with metasedimentary and carbonate-rich horizons. This indicates that the subducted material was dominated by trench filling made of

P-T paths of ophiolite-related metamorphic rocks from the Dinaride ophiolite zone in Bosnia

NASA Astrophysics Data System (ADS)

Balen, Dražen; Massonne, Hans-Joachim; Koller, Friedrich; Theye, Thomas; Opitz, Joachim; Hrvatović, Hazim; Premužak, Lucija

2017-04-01

The Dinarides, an Alpine mountain chain in south-eastern Europe, is characterized by complex fold, thrust, and imbricate structures. Partially dismembered ophiolites, a regular part of the Inner Dinarides, are considered as separate ultramafic massifs. The large Krivaja-Konjuh ultramafic massif (KKUM) within the Dinaride Ophiolite Zone (DOZ), composed of tectonic spinel lherzolite, occurs as NE-dipping thrust sheet underlain by gradually decreasing, up to 1200 m thick, high- to medium-grade metamorphic rocks. The metamorphic rocks geochemically resemble MORB-like rocks with tholeiitic signature. Such metamorphic rocks, which originated from cumulate gabbro and/or troctolite, are mainly represented by granulite and amphibolite varieties (subordinate eclogite and epidote-amphibolite facies metamafic rocks are also present) with various proportions of amphibole, plagioclase, pyroxenes (diopside and hypersthene), garnet, corundum, sapphirine, spinel and quartz. These rocks vary in textures (granoblastic, porphyroblastic and nematoblastic) and grain size (coarse- to fine-grain varieties). Conventional thermobarometry of garnet- and clinopyroxene-bearing amphibolites directly beneath the contact to the overlying peridotite resulted in peak pressure (P) - temperature (T) conditions of 10-12 kbar (depth of ca. 35-40 km) and 745-830°C. Those amphibolites without clinopyroxene but with garnet experienced peak conditions of 7 kbar and 630°C. Amphibole + plagioclase amphibolite gave temperatures of 670-730 °C and lowermost-grade amphibolites yielded peak temperatures of 550°C. These estimates are thought to reflect the metamorphic conditions during the Late Jurassic obduction of the hot upper mantle part of the KKUM onto the ophiolite mélange. The hot obducted ultramafic fragments acted as a heat source for metamorphism that transformed cumulate gabbroic protolith into high- to medium-grade amphibolites and granulites. P-T pseudosections constructed for various

Effects of Ultra-High Pressure Homogenization and Hydrocolloids on Physicochemical and Storage Properties of Soymilk.

PubMed

Mukherjee, Dipaloke; Chang, Sam K C; Zhang, Yin; Mukherjee, Soma

2017-10-01

This study investigated the efficacy of ultra-high pressure homogenization (UHPH) in the presence or absence of added hydrocolloids for enhancing a range of physic-chemical properties of soymilk-which are important for extending shelf-life. Soymilk preparations containing different concentrations (0.01%, 0.02%, and 0.05%, w/v) of 2 different hydrocolloids (κ-carrageenan, κ-C, and gum Arabic, GA) were subjected to 3 different levels of UHPH (70, 140, and 210 MPa) and stored in sterilized containers at 4 °C. Emulsion properties of the soymilk preparations were analyzed over a period of 5 weeks. The results showed that soymilk with 0.05% κ-C had markedly improved storage properties, evident by significantly (P < 0.05) enhanced surface energy and absolute ζ potential values compared to the unhomogenized soymilk with no hydrocolloid (16% and 39% augmentations, respectively) at the 1st week of storage. This trend continued throughout the entire period of study. The soymilk containing 0.05% κ-C also exhibited significantly (P < 0.05) lower (60%) mean globular particle size at the initial week compared to the latter ones and maintained the trend throughout the 3rd week of storage. The study can potentially lead to a considerable economic benefit to the soymilk industry by providing valuable information to extend shelf-life of soymilk. Soymilk is one of the most important soy products, and as a beverage, it is rapidly gaining popularity in the Western markets. However, it tends to form precipitates during storage to affect quality of the product. This study used a 2-prong approach of ultra-high pressure homogenization and addition of hydrocolloids to prevent aggregation of soymilk particles and the retention of antioxidant capacity. The results showed enhancement of the quality of soymilk during storage. The techniques developed can be adopted by the food industry. © 2017 Institute of Food Technologists®.

Cenozoic oblique collision of South American and Caribbean plates: New evidence in the Coastal Cordillera of Venezuela and Trinidad

DOE Office of Scientific and Technical Information (OSTI.GOV)

Speed, R.C.; Russo, R.M.; Foland, K.A.

The hinterland of the Caribbean Mts. orogen in Trinidad and Venezuela contains schist and gneiss whole protoliths are wholly or partly of continental provenance. The hinterland lies between the foreland thrust belt and terranes. The terranes are alien to continental South America (SA) and may have proto-Caribbean or Caribbean plate origins. The hinterland rocks were widely thought to come from sediments and granitoids of Mesozoic protolithic ages and to be of Cretaceous metamorphic age. Such rocks are now know to be of at least two or more types, as follows: (1) low grade, protoliths of pre-Mesozoic basement and shelfal covermore » of uncertain age range, inboard locus, Oligocene to mid-Miocene metamorphic ages younging eastward (Caracas, Paria, and Northern Range belts), and (2) higher grade including high P/T, varies protoliths of uncertain age range, Cretaceous and ( )early Paleogene metamorphic ages (Tacagua, Araya, Margarita). The geometry, protoliths, structures, and metamorphic ages of type 1 parautochthoneity and an origin as a thickened wedge of crust-cored passive margin cover. The wedge grew by accretion between about 35 and 20 Ma during oblique transport toward the foreland. The diachroneity of metamorphism implies, as does the timing of foreland deformation, that the wedge evolved in a right-oblique collision between northern SA and terranes moving wholly or partly with the Caribbean plate since the Eocene. Type 2 rocks probably came with the terranes and are products of convergent zone tectonics, either in the proto-Caribbean plate. The hinterland boundaries are brittle thrusts that are out of sequence and imply progressive contraction from mid-Cenozoic to the present.« less

Lithium, boron and chlorine as tracers for metasomatism in high-pressure metamorphic rocks: a case study from Syros (Greece)

NASA Astrophysics Data System (ADS)

Marschall, Horst R.; Altherr, Rainer; Gméling, Katalin; Kasztovszky, Zsolt

2009-03-01

High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H2O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B /Be and Cl /Be ratios correlate with H2O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B /Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl /Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H2O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies.

Metamorphic P-T conditions and CO2 influx history of medium-grade metapelites from Karakorum, Trans-Himalaya, India

NASA Astrophysics Data System (ADS)

Sachan, Himanshu K.; Santosh, M.; Prakash, Divya; Kharya, Aditya; Chandra Singh, P.; Rai, Santosh K.

2016-07-01

The medium grade metapelites of Pangong-Tso area in the trans-Himalayan region underwent sillimanite-grade metamorphism initiated during the Cretaceous, associated with the collision of the Kohistan arc and the Indian plate with Asia. This paper present results from a petrological and fluid inclusion study to understand the metamorphic P-T conditions and fluid history of these rocks. The calculated phase equilibria in the Na2O-CaO-K2O-FeO-MgO-MnO-Al2O3-SiO2-H2O-TiO2 (NCKFMMnASHT) system suggest P-T conditions of 8 kbar and 650 °C for the peak metamorphic event. Primary fluid inclusions occur in staurolite and garnet, whereas quartz carries mostly secondary fluid inclusions. The trapped fluids in primary inclusions show initial melting temperatures in the range of -56.9 to -56.6 °C, suggesting nearly pure CO2 composition. The secondary fluids are of mixed carbonic-aqueous nature. The re-equilibrated inclusions show annular morphology as well as necking phenomena. The CO2 isochores for the primary inclusions indicate pressures of 6.1-6.7 kbar, suggesting that the CO2-rich fluids were trapped during post-peak exhumation of the rocks, or that synmetamorphic carbonic fluids underwent density reversal during isothermal decompression. The secondary CO2-H2O fluids must have been trapped during the late exhumation stage, as their isochores define further lower pressures of 4.8 kbar. The morphology of re-equilibrated fluid inclusions and the rapid decrease in pressure are consistent with a near-isothermal decompression trajectory following the peak metamorphism. The carbonic fluids were probably derived locally from decarbonation reactions of the associated carbonate rocks during metamorphism or from a deep-seated reservoir through Karakorum fault.

Gravity signatures of terrane accretion

NASA Astrophysics Data System (ADS)

Franco, Heather; Abbott, Dallas

1999-01-01

In modern collisional environments, accreted terranes are bracketed by forearc gravity lows, a gravitational feature which results from the abandonment of the original trench and the initiation of a new trench seaward of the accreted terrane. The size and shape of the gravity low depends on the type of accreted feature and the strength of the formerly subducting plate. Along the Central American trench, the accretion of Gorgona Island caused a seaward trench jump of 48 to 66 km. The relict trench axes show up as gravity lows behind the trench with minimum values of -78 mgal (N of Gorgona) and -49 mgal (S of Gorgona) respectively. These forearc gravity lows have little or no topographic expression. The active trench immediately seaward of these forearc gravity lows has minimum gravity values of -59 mgal (N of Gorgona) and -58 mgal (S of Gorgona), respectively. In the north, the active trench has a less pronounced gravity low than the sediment covered forearc. In the Mariana arc, two Cretaceous seamounts have been accreted to the Eocene arc. The northern seamount is most likely a large block, the southern seamount may be a thrust slice. These more recent accretion events have produced modest forearc topographic and gravity lows in comparison with the topographic and gravity lows within the active trench. However, the minimum values of the Mariana forearc gravity lows are modest only by comparison to the Mariana Trench (-216 mgal); their absolute values are more negative than at Gorgona Island (-145 to -146 mgal). We speculate that the forearc gravity lows and seaward trench jumps near Gorgona Island were produced by the accretion of a hotspot island from a strong plate. The Mariana gravity lows and seaward trench jumps (or thrust slices) were the result of breaking a relatively weak plate close to the seamount edifice. These gravity lows resulting from accretion events should be preserved in older accreted terranes.

Post-metamorphic brecciation in type 3 ordinary chondrites

NASA Technical Reports Server (NTRS)

Scott, E. R. D.; Mccoy, T. J.; Keil, K.

1993-01-01

Type 3.1-3.9 ordinary chondrites can be divided into two kinds: those in which the compositions of chondrule silicates are entirely consistent with metamorphism of type 3.0 material, and those in which the computational heterogeneity appears to be too extreme for in situ metamorphism. We present petrologic data for three LL3 chondrites of the second kind--Ngawi, ALH A77278 (both type 3.6), and Hamlet (type 3.9)--and compare these data with results for the first kind of LL3-4 chondrites. Given that chondrules form in the nebula and that metamorphic equilibration occurs in asteroids, our new data imply that Ngawi, A77278, Hamlet, and many other type 3 ordinary chondrites are post-metamorphic breccias containing materials with diverse metamorphic histories; they are not metamorphic rocks or special kinds of 'primitive breccias.' We infer also that metamorphism to type 3.1-3.9 levels produces very friable material that is easily remixed into breccias and lithified by mild shock. Thus, petrologic types and subtypes of chondrites indicate the mean metamorphic history of the ingredients, not the thermal history of the rock. The metamorphic history of individual type 1 or 2 porphyritic chondrules in type 3 breccias is best derived from olivine and pyroxene analyses and the data of McCoy et al. for unbrecciated chondrites. The new chondrule classification schemes of Sears, DeHart et al., appears to provide less information about the original state and metamorphic history of individual porphyritic chondrules and should not replace existing classification schemes.

Post-metamorphic brecciation in type 3 ordinary chondrites

NASA Astrophysics Data System (ADS)

Scott, E. R. D.; McCoy, T. J.; Keil, K.

1993-03-01

Type 3.1-3.9 ordinary chondrites can be divided into two kinds: those in which the compositions of chondrule silicates are entirely consistent with metamorphism of type 3.0 material, and those in which the computational heterogeneity appears to be too extreme for in situ metamorphism. We present petrologic data for three LL3 chondrites of the second kind--Ngawi, ALH A77278 (both type 3.6), and Hamlet (type 3.9)--and compare these data with results for the first kind of LL3-4 chondrites. Given that chondrules form in the nebula and that metamorphic equilibration occurs in asteroids, our new data imply that Ngawi, A77278, Hamlet, and many other type 3 ordinary chondrites are post-metamorphic breccias containing materials with diverse metamorphic histories; they are not metamorphic rocks or special kinds of 'primitive breccias.' We infer also that metamorphism to type 3.1-3.9 levels produces very friable material that is easily remixed into breccias and lithified by mild shock. Thus, petrologic types and subtypes of chondrites indicate the mean metamorphic history of the ingredients, not the thermal history of the rock. The metamorphic history of individual type 1 or 2 porphyritic chondrules in type 3 breccias is best derived from olivine and pyroxene analyses and the data of McCoy et al. for unbrecciated chondrites. The new chondrule classification schemes of Sears, DeHart et al., appears to provide less information about the original state and metamorphic history of individual porphyritic chondrules and should not replace existing classification schemes.

Peak Metamorphic Temperature Profile across Eastern Belt Franciscan, Northern California Coast Ranges

NASA Astrophysics Data System (ADS)

Schmidt, W. L.; Platt, J. P.

2017-12-01

Previous work done on metamorphic temperatures across the lawsonite-albite to blueschist facies rocks of the Eastern Belt of the Franciscan accretionary complex has relied on a combination of many methods, and suggests that temperature broadly increases from west to east. The Taliaferro Metamorphic Complex is an exception to this pattern and shows higher pressures, and possibly higher temperatures, than its surroundings. The exact location and nature of the faults separating accreted packets in the Eastern Belt is somewhat controversial. A recently calibrated low-temperature laser Raman geothermometer for use on carbonaceous material provides a uniform method of estimating peak metamorphic temperature across the eastern Franciscan and is here used to identify the position of major tectonic boundaries. Temperatures were obtained from exposures in Thomes Creek, Cottonwood Creek, Grindstone Creek, and the middle fork of the Eel River. Peak T in the South Fork Mountain Schist, the highest grade and easternmost unit in the Franciscan, is 310-375°C, whereas in immediately underlying lawsonite-albite facies rocks below the Log Springs thrust, peak T is 270 - 300°C. The Taliaferro Metamorphic Complex reached a peak temperature of 336°C, whereas the surrounding lawsonite-albite facies rocks yield peak temperatures as low as 232°C. Preliminary temperature profiles clearly allow the major faults bounding the Taliaferro Metamorphic Complex and the South Fork Mountain Schist to be located. Extension of the temperature profile has the potential to reveal further detail within these units and the lower grade rocks surrounding them.

Monazite behaviours during high-temperature metamorphism: a case study from Dinggye region, Tibetan Himalaya

NASA Astrophysics Data System (ADS)

Wang, Jia-Min; Wu, Fu-Yuan; Rubatto, Daniela; Liu, Shi-Ran; Zhang, Jin-Jiang

2017-04-01

Monazite is a key accessory mineral for metamorphic geochronology, but its growth mechanisms during melt-bearing high-temperature metamorphism is not well understood. Therefore, the petrology, pressure-temperature and timing of metamorphism have been investigated in pelitic and psammitic granulites from the Greater Himalayan Crystalline Complex (GHC) in Dinggye, southern Tibet. These rocks underwent an isothermal decompression process from pressure conditions of >10 kbar to <5 kbar with constant temperatures of 750-830°C, and recorded three metamorphic stages of kyanite-grade (M1), sillimanite-grade (M2) and cordierite-spinel grade (M3). Monazite and zircon crystals were analyzed for ages by microbeam techniques either in mounts or thin sections. Ages were linked to specific conditions of mineral growth by comprehensive studies on zoning patterns, trace element signatures, index mineral inclusions (melt inclusions, sillimanite and K-feldspar) in dated domains and textural correlations with coexisting minerals. The results show that inherited domains (500-400 Ma) are common in monazite even at granulite-facies conditions. Few monazites formed at the M1-stage ( 30-29 Ma) and recorded heterogeneous Th, Y, and HREE compositions, which formed by recrystallization related to muscovite dehydration melting reaction. These monazite grains were protected from dissolution or lateral overprinting mainly by the armour effect of matrix crystals (biotite and quartz). Most monazite grains formed at the M3-stage (21-19 Ma) through either dissolution-reprecipitation or recrystallization that was related to biotite dehydration melting reaction. These monazite grains record HREE and Y signatures in local equilibrium with different reactions involving either garnet breakdown or peritectic garnet growth. Another peak of monazite growth occurs during melt crystallization ( 15 Ma), and these monazites are unzoned and have homogeneous compositions. Our results documented the widespread

Seismic probing of continental subduction zones

NASA Astrophysics Data System (ADS)

Zhao, Liang; Xu, Xiaobing; Malusà, Marco G.

2017-09-01

High-resolution images of Earth's interior provide pivotal information for the understanding of a range of geodynamic processes, including continental subduction and exhumation of ultrahigh-pressure (UHP) metamorphic rocks. Here we present a synthesis of available global seismic observations on continental subduction zones, and selected examples of seismic probing from the European Alps, the Himalaya-Tibet and the Qinling-Dabie orogenic belts. Our synthesis and examples show that slabs recognized beneath exhumed continental UHP terranes generally have shallow dip angles (<45°) at depths <100 km, to become much steeper at depths >100 km. Slabs underlined by a clear high velocity anomaly from Earth's surface to the mantle are generally Cenozoic in age. Some of these slabs are continuous, whereas other continental subduction zones are located above discontinuous high velocity anomalies possibly suggesting slab breakoff. The density of seismic stations and the quality of recordings are of primary importance to get high-resolution images of the upper mantle to be used as a starting point to provide reliable geodynamic interpretations. In some cases, areas previously indicated as possible site of slab breakoff, such as the European Alps, have been later proven to be located above a continuous slab by using higher quality travel time data from denser seismic arrays. Discriminating between oceanic and continental slabs can be challenging, but valuable information can be provided by combining teleseismic tomography and receiver function analysis. The upper mantle beneath most continental UHP terranes generally shows complex seismic anisotropy patterns that are potentially preserved even in pre-Cenozoic subduction zones. These patterns can be used to provide information on continental slabs that are no longer highlighted by a clear high-velocity anomaly.

Dynamics of Metamorphic Core Complexes Inferred From Modeling and Metamorphic Petrology

NASA Astrophysics Data System (ADS)

Whitney, D. L.; Rey, P.; Teyssier, C.

2008-12-01

Orogenic collapse involves extension and thinning of thick, hot, and in some cases partially molten, crust, leading to the formation of metamorphic core complexes (MCC) that are commonly cored by migmatite domes. 2D numerical modeling predicts that the geometry and P-T-t history of MCC varies as a function of the presence/absence of a partially molten layer in the deep crust; the nature of heterogeneities that localize the MCC (e.g. normal fault in upper crust vs. point-like anomaly in the deep crust); and extensional strain rate. The presence of melt in particular has a significant effect on the thermal and structural history of MCC because the presence of partially molten crust or magma bodies at depth enhances upward advection of material and heat. At high extension rate (cm/year in the region of the MCC), partially molten crust crystallizes as migmatite and cools along a high geothermal gradient (35-65 C/km); material remains partially molten during ascent, forming a migmatite dome when it crystallizes at shallower crustal levels (e.g. cordierite/sillimanite stability field). At low strain rate (mm/yr in the MCC region), the partially molten crust crystallizes at high pressure (e.g. kyanite zone); this material is subsequently deformed in the solid-state along a cooler geothermal gradient (20-35 C/km) during ascent. MCC that develop during extension of partially molten crust may therefore record distinct crystallization versus exhumation histories as a function of extensional strain rate. The mineral assemblages, metamorphic reaction histories, and structures of migmatite-cored (Mc) MCC can therefore be used to interpret the dynamics of MCC formation, e.g. "fast" McMCC in the northern N American Cordillera and Aegean regions.

Kinematics of the mosquito terrane, Coldfoot Area, Alaska: Keys to Brooks Range tectonics: Final report, Project No. 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harms, T.A.; Coney, P.J.

1988-04-01

Within the large-scale geometry of the Brooks Range, the Angayucham terrane occurs as a vast overthrust sheet. From the north flank of the Ruby terrane it underlies the Koyukuk basin and stretches north as the roof thrust to the various nappe terranes of the Brooks Range. The tectonic relationship of the Ruby terrane to the south flank of the Brooks Range lies largely obscured beneath the Angayucham in the eastern apex of the Koyukuk basin. The Mosquito terrane occurs as a window through the Angayucham at this juncture. The composition and structures of the Mosquito terrane reveal that is themore » result of shear along a sub-horizontal step or flange within the prominent, through-going dextral strike-slip fault system which cuts across the eastern Koyukuk basin and southeastern Brooks Range. Units of the Mosquito were derived from both the Angayucham and Ruby terranes. A consistent tectonic fabric imposed upon them is kinematically linked to the strike-slip system and indicates a northeasterly direction of transport across the terrane. The presence of Ruby-correlative units within the Mosquito suggests the Ruby underlies the Angayucham and that it is in contact with terrances of the southern Brooks Range at that structural level along high-angle strike-slip faults. These relationships demonstrate that an episode of dextral transpression is the latest in the history of terrane accretion and tectonic evolution of the Brooks Range. 35 refs.« less

Basaltic Martian analogues from the Baikal Rift Zone and Mongolian terranes

NASA Astrophysics Data System (ADS)

Gurgurewicz, J.; Kostylew, J.

2007-08-01

In order to compare the results of studies of the western part of the Valles Marineris canyon on Mars there have been done field works on terrestrial surface areas similar with regard to geological setting and environmental conditions. One of the possible terrestrial analogues of the Valles Marineris canyon is the Baikal Rift Zone [1]. Field investigations have been done on the south end of the Baikal Lake, in the Khamar-Daban massif, where the outcrops of volcanic rocks occur. The second part of the field works has been done in the Mongolian terranes: Mandalovoo, Gobi Altay and Bayanhongor, because of environmental conditions being similar to those on Mars. The Mandalovoo terrane comprises a nearly continuous Paleozoic islandarc sequence [2]. In the Gobi Altay terrane an older sequence is capped by younger Devonian-Triassic volcanic-sedimentary deposits [2]. The Bayanhongor terrane forms a northwest-trending, discontinuous, narrow belt that consists of a large ophiolite allochton [3]. The collected samples of basalts derive from various geologic environments. The CORONA satellite-images have been used for the imaging of the Khamar-Daban massif and the Mandalovoo terrane. These images have the same spatial resolution and range as the Mars Orbiter Camera images of the Mars Global Surveyor mission. In the Mandalovoo terrane these images allowed to find an area with large amounts of tectonic structures, mainly faults (part of the Ongi massif), similar to the studied area on Mars. Microscopic observations in thin sections show diversification of composition and structures of basalts. These rocks have mostly a porphyric structure, rarely aphyric. The main components are plagioclases, pyroxenes and olivines phenocrysts, in different proportions. The groundmass usually consist of plagioclases, pyroxenes and opaques. The most diversified are basalts from the Mandalovoo terrane. Infrared spectroscopy has been used to analyse the composition of the rock material and compare

Zircon geochronology and ca. 400 Ma exhumation of Norwegian ultrahigh-pressure rocks: An ion microprobe and chemical abrasion study

USGS Publications Warehouse

Root, D.B.; Hacker, B.R.; Mattinson, J.M.; Wooden, J.L.

2004-01-01

Understanding the formation and exhumation of the remarkable ultrahigh-pressure (UHP) rocks of the Western Gneiss Region, Norway, hinges on precise determination of the time of eclogite recrystallization. We conducted detailed thermal ionization mass spectrometry, chemical abrasion analysis and sensitive high-resolution ion-microprobe analysis of zircons from four ultrahigh- and high-pressure (HP) rocks. Ion-microprobe analyses from the Flatraket eclogite yielded a broad range of apparently concordant Caledonian ages, suggesting long-term growth. In contrast, higher precision thermal ionization mass spectrometry analysis of zircon subject to combined thermal annealing and multi-step chemical abrasion yielded moderate Pb loss from the first (lowest temperature) abrasion step, possible minor Pb loss or minor growth at 400 Ma from the second step and a 407-404 Ma cluster of slightly discordant 206Pb/238U ages, most likely free from Pb loss, from the remaining abrasion steps. We interpret the latter to reflect zircon crystallization at ???405-400 Ma with minor discordance from inherited cores. Zircon crystallization occurred at eclogite-facies, possibly post-peak conditions, based on compositions of garnet inclusions in zircon as well as nearly flat HREE profiles and lack of Eu anomalies in zircon fractions subjected to chemical abrasion. These ages are significantly younger than the 425 Ma age often cited for western Norway eclogite recrystallization, implying faster rates of exhumation (>2.5-8.5 km/Myr), and coeval formation of eclogites across the UHP portion of the Western Gneiss Region. ?? 2004 Published by Elsevier B.V.

Linking monazite geochronology with fluid infiltration and metamorphic histories: Nature and experiment

NASA Astrophysics Data System (ADS)

Shazia, J. R.; Harlov, D. E.; Suzuki, K.; Kim, S. W.; Girish-Kumar, M.; Hayasaka, Y.; Ishwar-Kumar, C.; Windley, B. F.; Sajeev, K.

2015-11-01

Migmatised metapelites from the Kodaikanal region, central Madurai Block, southern India have undergone ultrahigh-temperature metamorphism (950-1000 °C; 7-8 kbar). In-situ electron microprobe Th-U-Pb isochron (CHIME) dating of monazites in a leucosome and surrounding silica-saturated and silica-poor restites from the same outcrop indicates three principal ages that can be linked to the evolutionary history of these rocks. Monazite grains from the silica-saturated restite have well-defined, inherited cores with thick rims that yield an age of ca. 1684 Ma. This either dates the metamorphism of the original metapelite or is a detrital age of inherited monazite. Monazite grains from the silica-poor restite, thick rims from the silica-saturated restite, and monazite cores from the leucosome have ages ranging from 520 to 540 Ma suggesting a mean age of 530 Ma within the error bars. In the leucosome the altered rim of the monazite gives an age of ca. 502 Ma. Alteration takes the form of Th-depleted lobes of monazite with sharp curvilinear boundaries extending from the monazite grain rim into the core. We have replicated experimentally these altered rims in a monazite-leucosome experiment at 800 °C and 2 kbar. This experiment, coupled with earlier published monazite-fluid experiments involving high pH alkali-bearing fluids at high P-T, helps to confirm the idea that alkali-bearing fluids, in the melt and along grain boundaries during crystallization, were responsible for the formation of the altered monazite grain rims via the process of coupled dissolution-reprecipitation.

Using SHRIMP zircon dating to unravel tectonothermal events in arc environments. The early Palaeozoic arc of NW Iberia revisited

USGS Publications Warehouse

Abati, J.; Castineiras, P.G.; Arenas, R.; Fernandez-Suarez, J.; Barreiro, J.G.; Wooden, J.L.

2007-01-01

Dating of zircon cores and rims from granulites developed in a shear zone provides insights into the complex relationship between magmatism and metamorphism in the deep roots of arc environments. The granulites belong to the uppermost allochthonous terrane of the NW Iberian Massif, which forms part of a Cambro-Ordovician magmatic arc developed in the peri-Gondwanan realm. The obtained zircon ages confirm that voluminous calc-alkaline magmatism peaked around 500Ma and was shortly followed by granulite facies metamorphism accompanied by deformation at c. 480Ma, giving a time framework for crustal heating, regional metamorphism, deformation and partial melting, the main processes that control the tectonothermal evolution of arc systems. Traces of this arc can be discontinuously followed in different massifs throughout the European Variscan Belt, and we propose that the uppermost allochthonous units of the NW Iberian Massif, together with the related terranes in Europe, constitute an independent and coherent terrane that drifted away from northern Gondwana prior to the Variscan collisional orogenesis. ?? 2007 Blackwell Publishing Ltd.

Paleoproterozoic high-pressure metamorphism in the northern North China Craton and implications for the Nuna supercontinent

PubMed Central

Wan, Bo; Windley, Brian F.; Xiao, Wenjiao; Feng, Jianyun; Zhang, Ji'en

2015-01-01

The connection between the North China Craton (NCC) and contiguous cratons is important for the configuration of the Nuna supercontinent. Here we document a new Paleoproterozoic high-pressure (HP) complex dominated by garnet websterite on the northern margin of the NCC. The peak metamorphism of the garnet websterite was after ∼1.90 Ga when it was subducted to eclogite facies at ∼2.4 GPa, then exhumed back to granulite facies at ∼0.9 GPa before ∼1.82 Ga. The rock associations with their structural relationships and geochemical affinities are comparable to those of supra-subduction zone ophiolites, and supported by subduction-related signatures of gabbros and basalts. We propose that a ∼1.90 Ga oceanic fragment was subducted and exhumed into an accretionary complex along the northern margin of the NCC. Presence of the coeval Sharyzhalgai complex with comparable HP garnet websterites in the southern Siberian active margin favours juxtaposition against the NCC in the Paleoproterozoic. PMID:26388458

Zircon U-Pb Ages from an Ultra-High Temperature Metapelite, Rauer Group, East Antarctica: Implications for Overprints by Grenvillian and Pan-African Events

USGS Publications Warehouse

Wang, Yanbin; Tong, Laixi; Liu, Dunyi

2007-01-01

SHRIMP U-Pb dating of zircon from an ultra-high temperature (UHT, ~1000 °C) granulite-facies metapelite from the Rauer Group, Mather Peninsula, east Antarctica, has yielded evidence for two episodes of metamorphic zircon growth, at ~1.00 Ga and ~530 Ma, and two episodes of magmatism in the source region for the protolith sediment, at ~2.53 and ~2.65 Ga, were identified from the zircon cores. Successive zircon growth at ~1.00 Ga and ~530 Ma records a sequence of distinct, widely spaced high-temperature metamorphic and/or anatectic events related to Grenvillian and Pan-African orogenesis. This study presents the first robust geochronological evidence for the timing of UHT metamorphism of the Rauer Group, supporting arguments that the peak UHT metamorphic event occurred at ~1.00 Ga and was overprinted by a separate high-grade event at ~530 Ma. The new age data indicate that the UHT granulites of the Rauer Group experienced a complex, multi-stage tectonothermal history, which cannot simply be explained via a single Pan-African (~500 Ma) high-grade tectonic event. This is critical in understanding the role of the eastern Prydz Bay region during the assembly of the east Gondwana supercontinent, and the newly recognized inherited Archaean ages (~2.53 and ~2.65 Ga) suggest a close tectonic relationship between the Rauer Group and the adjacent Archaean of the Vestfold Hills

Archaean and Palaeoproterozoic metamorphic events in the Orekhov-Pavlograd compressional zone, Ukrainian Shield

NASA Astrophysics Data System (ADS)

Yurchenko, A. V.

2012-04-01

The Orekhov-Pavlograd zone (OPZ) is located between the Mesoarchaean-Neoarchaean Middle Dnieper Province and the Mesoarchaean-Palaeoproterozoic Azov Province in the eastern Ukrainian Shield. The OPZ consists of Archaean and Palaeoproterozoic high-grade metamorphic rocks. According U-Pb isotope analyses Archaean methaigneous rocks have age of 3.5-3.3 Ga, and latest AR events dated form both individual grains and metamorphic rims in the tonalite and the granitic vein occurred at about 2.88 Ga ego. Paleoproterozoic zircons from a hornblende granulite have a concordia age of 2.08 Ga [1]. P-T conditions of the 3.5-3.3 Ga processes calculated from the Ti content in zircon are of 730-760°C. Metamorphic event dated as 2.88 Ga is more preserved and detected in some amphibolites after mafic dykes. According to different methods of hornblende-plagioclase geothermometry along with Al- and Ti-geobarometry of hornblende, the amphibolites have formed at temperature of 735-749 °C and pressure of 5.2 to 7.8 kbar. P-T conditions of Paleoproterozoic metamorphic processes have been calculated for a Paleoproterozoic high-Al paragneiss and mafic rocks. On the base of the computer software THERIAK-DOMINO [2], near-isothermal decompression from ca. 8.5 to 6.0 kbar at 650 °C and then to 5.8 kbar at 740 °C has been determined for small irregular garnet grains (grs 4-7% and XMg 0.36-0.37) associated with the same biotite and plagioclase. P-T conditions obtained by means of the P-T pseudosection calculation are identical within errors to those defined by the Grt + Bt + Pl + Ozt geothermometer by [3] and the geobarometer by [4], T = 675 °C and P = 5.6 kbar. Temperature and pressure calculated for assemblage Grt-Pl-Opx-Amph-Ilm-Ru (mafic rock) by using the TWEEQU method shows: 1) high values of pressure and temperature (ca. 7 kbar and 800 °C) are linked with the first metamorphic event with Opx-Cpx assemblage, 2) moderate values (ca. 5 kbar and ca. 600 °C) are referred to the second

Early Paleozoic tectonics for the New Siberian Islands terrane (Eastern Arctic)

NASA Astrophysics Data System (ADS)

Metelkin, D. V.; Chernova, A. I.; Vernikovsky, V. A.; Matushkin, N. Yu.

2017-11-01

The New Siberian Islands archipelago is one of the few research objects accessible for direct study on the eastern Arctic shelf. There are several models that have different interpretations of the Paleozoic tectonic history and the structural affinity of the New Siberian Islands terrane. Some infer a direct relationship with the passive continental margin of the Siberian paleocontinent. Others connect it with the marginal basins of Baltica and Laurentia, or the Chukotka-Alaska microplate. Our paleomagnetic investigation led us to create an apparent polar wander path for the early Paleozoic interval of geological history. Based on it we can conclude that the New Siberian Islands terrane could not have been a part of these continental plates. This study considers the possible tectonic scenarios of the Paleozoic history of the Earth, presents and discusses the corresponding global reconstructions describing the paleogeography and probable mutual kinematics of the terranes of the Eastern Arctic.

Processes in continental collision zones: Preface

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhang, Lifei; McClelland, William C.; Cuthbert, Simon

2012-04-01

Formation and exhumation of high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks in continental subduction zones are the two fundamental geodynamic aspects of collisional orogensis. This volume is based on the Session 08c titled "Geochemical processes in continental collision zones" at Goldschmidt 2010 in Knoxville, USA. It focuses on micro- to macro-scale processes that are temporally and spatially linked to different depths of crustal subduction/exhumation and associated mineralogical changes. They are a key to understanding a wide spectrum of phenomena, involving HP/UHP metamorphism and syn-/post-collisional magmatism. Papers in this volume report progresses in petrological, geochronological and geochemical studies of UHP metamorphic rocks and their derivatives in China, with tectonic settings varying from arc-continent collision to continent-continent collision. Microbeam in-situ analyses of metamorphic and magmatic minerals are successfully utilized to solve various problems in the study of continental deep subduction and UHP metamorphism. In addition to their geochronological applications to dating of HP to UHP metamorphic events during continental collision, microbeam techniques have also served as an efficient means to recognize different generations of mineral growth during continental subduction-zone metamorphism. Furthermore, metamorphic dehydration and partial melting of UHP metamorphic rocks during subduction and exhumation are highlighted with respect to their effects on fluid action and element mobilization. These have provided new insights into chemical geodynamics in continental subduction zones.

Three-dimensional velocity structure of Siletzia and other accreted terranes in the Cascadia forearc of Washington

USGS Publications Warehouse

Parsons, T.; Wells, R.E.; Fisher, M.A.; Flueh, E.; ten Brink, Uri S.

1999-01-01

Eocene mafic crust with high seismic velocities underlies much of the Oregon and Washington forearc and acts as a backstop for accretion of marine sedimentary rocks from the obliquely subducting Juan de Fuca slab. Arc-parallel migration of relatively strong blocks of this terrane, known as Siletzia, focuses upper crustal deformation along block boundaries, which are potential sources of earthquakes. In a three-dimensional velocity model of coastal Washington, we have combined surface geology, well data, and travel times from earthquakes and controlled source seismic experiments to resolve the major boundaries of the Siletz terrane with the adjacent accreted sedimentary prism and volcanic arc. In southern Washington and northern Oregon the Siletz terrane appears to be a thick block (???20 km) that extends west of the coastline and makes a high-angle contact with the offshore accreted sedimentary prism. On its east flank the high-velocity Siletz terrane boundary coincides with an en echelon zone of seismicity in the arc. In northern Washington the western edge of Siletzia makes a lower-angled, fault-bound contact with the accretionary prism. In addition, alternating, east-west trending uplifts and downwarps of the Siletz terrane centered on the antiformal Olympic Mountains may reflect focusing of north-south compression in the northern part of the Siletz terrane. This compressional strain may result from northward transport and clockwise rotation of the Siletz terrane into the relatively fixed Canadian Coast Mountains restraining bend along the coast.

Pre-Alpine contrasting tectono-metamorphic evolutions within the Southern Steep Belt, Central Alps

NASA Astrophysics Data System (ADS)

Roda, Manuel; Zucali, Michele; Li, Zheng-Xiang; Spalla, Maria Iole; Yao, Weihua

2018-06-01

In the Southern Steep Belt, Italian Central Alps, relicts of the pre-Alpine continental crust are preserved. Between Valtellina and Val Camonica, a poly-metamorphic rock association occurs, which belongs to the Austroalpine units and includes two classically subdivided units: the Languard-Campo nappe (LCN) and the Tonale Series (TS). The outcropping rocks are low to medium grade muscovite, biotite and minor staurolite-bearing gneisses and micaschists, which include interlayered garnet- and biotite-bearing amphibolites, marbles, quartzites and pegmatites, as well as sillimanite-bearing gneisses and micaschists. Permian intrusives (granitoids, diorites and minor gabbros) emplaced in the metamorphic rocks. We performed a detailed structural, petrological and geochronological analysis focusing on the two main lithotypes, namely, staurolite-bearing micaschists and sillimanite-bearing paragneisses, to reconstruct the Variscan and Permian-Triassic history of this crustal section. The reconstruction of the tectono-metamorphic evolution allows for the distinction between two different tectono-metamorphic units during the early pre-Alpine evolution (D1) and predates the Permian intrusives, which comprise rocks from both TS and LCN. In the staurolite-bearing micaschists, D1 developed under amphibolite facies conditions (P = 0.7-1.1 GPa, T = 580-660 °C), while in the sillimanite-bearing paragneisses formed under granulite facies conditions (P = 0.6-1.0 GPa, T> 780 °C). The two tectono-metamorphic units coupled together during the second pre-Alpine stage (D2) under granulite-amphibolite facies conditions at a lower pressure (P = 0.4-0.6 GPa, T = 620-750 °C) forming a single tectono-metamorphic unit (Languard-Tonale Tectono-Metamorphic Unit), which comprised the previously distinguished LCN and TS. Geochronological analyses on zircon rims indicate ages ranging between 250 and 275 Ma for D2, contemporaneous with the emplacement of Permian intrusives. This event developed under

The role of serpentinite melanges in the unroofing of UHPM rocks: An example from the Western Alps of Italy: Chapter 6

USGS Publications Warehouse

Blake, M. Clark; Moore, D.E.; Jayko, A.S.; Coleman, Robert G.

1995-01-01

The ultrahigh pressure metamorphic rocks (UHPM) of the Dora-Maira continental massif are overlain by a stack of oceanic nappes. Metamorphic grade appears to increase downward but with marked discontinuities between each of the nappes, suggesting that section has been removed along the bounding faults. This apparent omission of section is greatest in the lowest oceanic unit where a serpentinite melange containing blocks and slabs of eclogite, metamorphosed at 12–19 kbar, lies on the UHPM rocks. We suggest that this serpentinite melange represents a highly attenuated upper mantle section that structurally overlay the UHP rocks during subduction. Similar serpentinite melanges are known from other high-pressure (HP) and UHPM areas and may have a similar origin.

Nature and probable age of metamorphism in northern New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grambling, J.A.; Daniel, C.D.; Dallmeyer, R.D.

1993-02-01

Metamorphic conditions near the Al[sub 2]SiO[sub 5] triple point are unusually common in northern New Mexico. This observation is supported by mineralogy (Ky + And + Sil, Cld + Sil, Sil + Pg + Qz) and Grt-Bt-Pl-Ms thermobarometry (4--5 kb and 500--550 C). Isograds cut across tight folds (overturned to the north) in the Pecos, Rio Mora, Truchas and Picuris areas. Some deformation also accompanied or preceded metamorphism in the Rincon and Cimarron ranges. P-T paths derived from zoning in Grt and Pl, in Mn-andalusite, and the textural transition Ky to Sil to And reflect up to 2 kb ofmore » decompression, at constant temperature in the more southerly ranges but during cooling toward the north. These 500--550 C rocks are in direct contact with gneisses in the Rincon and Cimarron Ranges. Metaplutonic gneisses record hornblende pressures of 6--8 kb. Metasedimentary gneisses are migmatitic. Assemblages include Sil + Kfs, Hc + Qz and Alm + Bt + Sil, whereas Grt-Sil-Pl-Bt yields 6.5--7 kb and 700--725 C. Pressures increase northward from the Cimarrron Mountains. The gneisses display retrograde P-T paths with 2.5--3 kb of decompression and cooling through the Al[sub 2]SiO[sub 5] triple point. Geometric relationships between gneisses and 500--550 C rocks are best constrained in the Cimarron Mountains, where a folded but initially low-angle contact separates the two metamorphic grades. Gneisses are structurally beneath this contact. Other regions may display a similar geometry. The structurally-highest gneisses are locally mylonitic, suggesting that contacts between gneisses and 500--550 C rocks are ductile shear zones. Monazite U-Pb ages from gneisses of the Cimarron Range are 1420-1425 Ma, whereas hornblende argon ages are 1,395--1,397 Ma.« less

High-pressure granulite-facies metamorphism in central Dronning Maud Land (East Antarctica): Implications for Gondwana assembly

NASA Astrophysics Data System (ADS)

Palmeri, Rosaria; Godard, Gaston; Di Vincenzo, Gianfranco; Sandroni, Sonia; Talarico, Franco M.

2018-02-01

Central Dronning Maud Land (DML; East Antarctica) is located in a key region of the Gondwana supercontinent. The Conradgebirge area (central DML) consists of orthogneisses, derived from both volcanic and plutonic protoliths, and minor metasedimentary rocks, intruded by Cambrian syn- to post-metamorphic plutons and dykes. Mafic-ultramafic boudins in the metavolcanic and metaplutonic gneisses from Conradgebirge consist of amphibolites and high-grade garnet-bearing pyroxene- and amphibole-rich granofels. They occur either as discontinuous levels or as pods boudinaged within highly-strained and strongly-migmatized gneisses. Bulk-rock major and trace-element compositions, together with geochemical discriminant diagrams (e.g., Th/Yb versus Ta/Yb and V versus Ti), suggest derivation from enriched mantle source for the mafic rocks boudinaged in metaplutonic gneisses, whereas a calc-alkaline signature is common for the mafic boudins in metavolcanic rocks. The microstructural study and P-T modelling of an ultramafic metagabbroic rock reveal a prograde metamorphic evolution from amphibolite-facies (ca. 0.5 GPa; 500 °C) up to high-P granulite-facies conditions (ca. 1.5-1.7 GPa; 960-970 °C). Partial melting is testified by "nanogranitoid" inclusions enclosed in garnet. An almost isothermal decompression down to ca. 0.4 GPa and 750-850 °C produced well-developed An + Opx-bearing symplectites around garnet. A final isobaric cooling at nearly 0.4 GPa is testified by Grt coronas around high-T symplectites. The above reconstruction traces a clockwise loading-heating P-T evolution with a peak metamorphism at high-P granulite-facies conditions suggesting crustal thickening at nearly 570 Ma, followed by a tectonically assisted rapid exhumation, and then, by an isobaric cooling. 40Ar-39Ar dating of amphibole and biotite at 505-480 Ma testify mineral re-equilibration at upper crustal level (T < 650 °C) during the isobaric cooling. This tectono-metamorphic scenario seems

Late Neoproterozoic metamorphic assemblages along the Pan-African Hamisana Shear Zone, southeastern Egypt: Metamorphism, geochemistry and petrogenesis

NASA Astrophysics Data System (ADS)

Ali-Bik, Mohamed W.; Sadek, Mohamed F.; Ghabrial, Doris Sadek

2014-11-01

A variety of Late Neoproterozoic gneisses and amphibolites are distributed along the N-S trending Hamisana Shear Zone (HSZ), in southeastern Egypt. The HSZ originated after the accretion of the Arabian-Nubian Shield (ANS) and covers an area of about 1500 km2 in southeastern Egypt and northeastern Sudan. The architecture of the northern part of the HSZ is best explained as a tectono-stratigraphic column, in which allochthonous ophiolitic mélange was thrusted onto metamorphosed island-arc assemblages (gneisses and amphibolites). The latter rock units were generally subjected to two successive phases of amphibolite facies metamorphism, followed by a thermal phase and retrograde overprint. The early penetrative, low- to medium-pressure metamorphism (M1) was synchronous with D1-gneissosity and N-S trending lineation, demarcating the high strain HSZ. The mineral assemblages formed during the M1 phase include quartz + andesine + hornblende (I) + biotite (I) in hornblende-biotite gneiss, quartz + andesine + pargasitic hornblende (I) + ferroan pargasitic hornblende (I) + edenitic hornblende (I) in hornblende-schist, quartz + plagioclase + biotite + muscovite in psammopelitic gneiss, and diopside + tremolite + calcite + sphene ± garnet in calc-silicates, being characteristic for amphibolite facies with metamorphic conditions of 600 ± 50 °C and 5-6.5 kbar. The second metamorphic phase (M2) is related to the crystallization of biotite and/or hornblende in S2 foliation demarcating the NE-SW trending dextral shear deformation (D2). The calculated temperature for this M2 phase is about 592 °C. Subsequent thermal events are documented by growth of spinel and scapolite in calc-silicate rocks and of cordierite in psammopelitic gneiss in response to uplift, decomposition and heat provided by the nearby late-formed igneous intrusions. Finally, the rocks reached a temperature of about 530 °C during the cooling retrogressive stage. Based on geological, petrological and geochemical

Birth, life, and demise of the Andean-syn-collisional Gissar arc: Late Paleozoic tectono-magmatic-metamorphic evolution of the southwestern Tian Shan, Tajikistan

NASA Astrophysics Data System (ADS)

Worthington, James R.; Kapp, Paul; Minaev, Vladislav; Chapman, James B.; Mazdab, Frank K.; Ducea, Mihai N.; Oimahmadov, Ilhomjon; Gadoev, Mustafo

2017-10-01

The amalgamation of the Central Asian Orogenic Belt in the southwestern Tian Shan in Tajikistan is represented by tectono-magmatic-metamorphic processes that accompanied late Paleozoic ocean closure and collision between the Karakum-Tarim and Kazakh-Kyrgyz terranes. Integrated U-Pb geochronology, thermobarometry, pseudosection modeling, and Hf geochemistry constrain the timing and petro-tectonic nature of these processes. The Gissar batholith and the Garm massif represent an eastward, along-strike increase in paleodepth from upper-batholith ( 21-7 km) to arc-root ( 36-19 km) levels of the Andean-syn-collisional Gissar arc, which developed from 323-288 Ma in two stages: (i) Andean, I-type granitoid magmatism from 323-306 Ma due to northward subduction of the Gissar back-arc ocean basin under the Gissar microcontinent, which was immediately followed by (ii) syn-collisional, I-S-type granitoid magmatism in the Gissar batholith and the Garm massif from 304-288 Ma due to northward subduction/underthrusting of Karakum marginal-continental crust under the Gissar microcontinent. A rapid isotopic pull-up from 288-286 Ma signals the onset of juvenile, alkaline-syenitic, post-collisional magmatism by 280 Ma, which was driven by delamination of the Gissar arclogite root and consequent convective asthenospheric upwelling. Whereas M-HT/LP prograde metamorphism in the Garm massif (650-750°C/6-7 kbar) from 310-288 Ma was associated with subduction-magma inundation and crustal thickening, HT/LP heating and decompression to peak-metamorphic temperatures ( 800-820°C/6-4 kbar) at 288 ± 6 Ma was driven by the transmission of a post-collisional, mantle-derived heat wave through the Garm-massif crust.

Timing and heat sources for the Barrovian metamorphism, Scotland

NASA Astrophysics Data System (ADS)

Viete, Daniel R.; Oliver, Grahame J. H.; Fraser, Geoff L.; Forster, Marnie A.; Lister, Gordon S.

2013-09-01

New SHRIMP U/Pb zircon ages of 472.2 ± 5.8 Ma and 471.2 ± 5.9 Ma are presented for the age of peak metamorphism of Barrovian migmatites. 40Ar/39Ar ages for white mica from the Barrovian metamorphic series are presented, and are recalculated using recently-proposed revisions to the 40K decay constants to allow more precise and accurate comparison with U/Pb ages. The 40Ar/39Ar ages are found to vary systematically with increasing metamorphic grade, between c. 465 Ma for the biotite zone and c. 461 Ma for the sillimanite zone. There is no evidence for any significant metamorphic heating during the first 15 Myr of the Grampian Orogeny (before c. 473 Ma) or the final 4 Myr (after c. 465 Ma). The Barrovian metamorphism occurred over a period of ~ 8 Myr within the ~ 27-Myr Grampian Orogeny. The Barrovian metamorphism records punctuated heating, was temporally and spatially associated with large-scale bimodal magmatism, and developed within crust that was not overthickened. The temporally distinct nature of the Barrovian metamorphic episode within the Grampian Orogeny, and its heating pattern and tectonic context, are not consistent with significant heat contribution from thermal equilibration of overthickened crust. Rather, the Barrovian metamorphism records a transient phase of crustal thermal disequilibrium during the Grampian Orogeny. Temporal and spatial association with Grampian bimodal magmatism is consistent with production of the Barrovian metamorphic series within the middle crust as the result of advection of heat from the lower crust and/or mantle. The Barrovian metamorphic series - the classic example of ‘orogenic regional metamorphism’ - did not form in response to crustal thickening and thermal relaxation, but appears to record large-scale contact metamorphism.

The effect of pressure and mobile phase velocity on the retention properties of small analytes and large biomolecules in ultra-high pressure liquid chromatography.

PubMed

Fekete, Szabolcs; Veuthey, Jean-Luc; McCalley, David V; Guillarme, Davy

2012-12-28

A possible complication of ultra-high pressure liquid chromatography (UHPLC) is related to the effect of pressure and mobile phase velocity on the retention properties of the analytes. In the present work, numerous model compounds have been selected including small molecules, peptides, and proteins (such as monoclonal antibodies). Two instrumental setups were considered to attain elevated pressure drops, firstly the use of a post-column restrictor capillary at low mobile phase flow rate (pure effect of pressure) and secondly the increase of mobile phase flow rate without restrictor (i.e. a combined effect of pressure and frictional heating). In both conditions, the goal was to assess differences in retention behaviour, depending on the type or character of the analyte. An important conclusion is that the effect of pressure and mobile phase velocity on retention varied in proportion with the size of the molecule and in some cases showed very different behaviour. In isocratic mode, the pure effect of pressure (experiments with a post-column restrictor capillary) induces an increase in retention by 25-100% on small molecules (MW<300 g/mol), 150% for peptides (~1.3 kDa), 800% for insulin (~6 kDa) and up to >3000% for myoglobin (~17 kDa) for an increase in pressure from 100 bar up to 1100 bar. The important effect observed for the isocratic elution of proteins is probably related to conformational changes of the protein in addition to the effect of molecular size. Working in gradient elution mode, the pressure related effects on retention were found to be less pronounced but still present (an increase of apparent retention factor between 0.2 and 2.5 was observed). Copyright © 2012 Elsevier B.V. All rights reserved.

Introduction to the structures and processes of subduction zones

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhao, Zi-Fu

2017-09-01

Subduction zones have been the focus of many studies since the advent of plate tectonics in 1960s. Workings within subduction zones beneath volcanic arcs have been of particular interest because they prime the source of arc magmas. The results from magmatic products have been used to decipher the structures and processes of subduction zones. In doing so, many progresses have been made on modern oceanic subduction zones, but less progresses on ancient oceanic subduction zones. On the other hand, continental subduction zones have been studied since findings of coesite in metamorphic rocks of supracrustal origin in 1980s. It turns out that high-pressure to ultrahigh-pressure metamorphic rocks in collisional orogens provide a direct target to investigate the tectonism of subduction zones, whereas oceanic and continental arc volcanic rocks in accretionary orogens provide an indirect target to investigate the geochemistry of subduction zones. Nevertheless, metamorphic dehydration and partial melting at high-pressure to ultrahigh-pressure conditions are tectonically applicable to subduction zone processes at forearc to subarc depths, and crustal metasomatism is the physicochemical mechanism for geochemical transfer from the slab to the mantle in subduction channels. Taken together, these provide us with an excellent opportunity to find how the metamorphic, metasomatic and magmatic products are a function of the structures and processes in both oceanic and continental subduction zones. Because of the change in the thermal structures of subduction zones, different styles of metamorphism, metasomatism and magmatism are produced at convergent plate margins. In addition, juvenile and ancient crustal rocks have often suffered reworking in episodes independent of either accretionary or collisional orogeny, leading to continental rifting metamorphism and thus rifting orogeny for mountain building in intracontinental settings. This brings complexity to distinguish the syn

Introduction to the structures and processes of subduction zones

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhao, Zi-Fu

2017-09-01

Subduction zones have been the focus of many studies since the advent of plate tectonics in 1960s. Workings within subduction zones beneath volcanic arcs have been of particular interest because they prime the source of arc magmas. The results from magmatic products have been used to decipher the structures and processes of subduction zones. In doing so, many progresses have been made on modern oceanic subduction zones, but less progresses on ancient oceanic subduction zones. On the other hand, continental subduction zones have been studied since findings of coesite in metamorphic rocks of supracrustal origin in 1980s. It turns out that high-pressure to ultrahigh-pressure metamorphic rocks in collisional orogens provide a direct target to investigate the tectonism of subduction zones, whereas oceanic and continental arc volcanic rocks in accretionary orogens provide an indirect target to investigate the geochemistry of subduction zones. Nevertheless, metamorphic dehydration and partial melting at high-pressure to ultrahigh-pressure conditions are tectonically applicable to subduction zone processes at forearc to subarc depths, and crustal metasomatism is the physicochemical mechanism for geochemical transfer from the slab to the mantle in subduction channels. Taken together, these provide us with an excellent opportunity to find how the metamorphic, metasomatic and magmatic products are a function of the structures and processes in both oceanic and continental subduction zones. Because of the change in the thermal structures of subduction zones, different styles of metamorphism, metasomatism and magmatism are produced at convergent plate margins. In addition, juvenile and ancient crustal rocks have often suffered reworking in episodes independent of either accretionary or collisional orogeny, leading to continental rifting metamorphism and thus rifting orogeny for mountain building in intracontinental settings. This brings complexity to distinguish the syn

Timing, Controls and Tectonic Context of Gold Mineralisation in the Southern Uplands-Longford-Down Terrane, Caledonides, Scotland and Ireland.

NASA Astrophysics Data System (ADS)

Rice, Samuel; Cuthbert, Simon; Hursthouse, Andrew

2017-04-01

The relationships between regional tectonic, magmatic and metamorphic events and hydrothermal mineralisation in orogenic settings are controversial [1]. The geotectonic development of the Caledonian orogenic belt of the northern British Isles, which hosts some significant gold deposits, is well-constrained and provides an excellent framework for investigating these relationships. Gold mineralisation at two of the best known deposits, Curraghinalt and Cononish, located in the Grampian Terrane, has recently been shown to have occurred between 462.7 and 452.8 Ma, during the Late Ordovician Grampian event of the Caledonian orogeny [2]. In the Southern Uplands-Longford-Down Terrane syn and post-kinnematic intrusions constrain the age of mineralisation to between 418 and 397 Ma. Mineralisation is hosted by late Caledonian transverse D3 structures of Early Devonian age [3]. Fluid inclusion data indicate that the auriferous quartz veins were deposited from a low salinity carbonic mesothermal ( 330°C) fluid of apparently mixed magmatic-metamorphic origin, consistent with a Caledonian orogenic origin [4-6]. Gold mineralisation is associated with contemporaneous minor intrusions at several localities [7-9] exhibiting comparable mineralogy, geochemistry, fluid inclusion types and structural relationships, indicating that coeval regional magmatism may have been a significant factor for all of the deposits. Gold mineralisation in the SULDT occurred during a transition from compression to strike-slip deformation coeval with a regional pulse of orogenic magmatism [10]. The common association between gold deposits in Phanerozoic orogenic settings and intrusions may explain overlapping characteristics between orogenic, intrusion-related and porphyry gold deposits and may reflect the important role of magmatism in conveying the heat to drive hydrothermal systems at shallow crustal levels. Further work will focus on constraining the sources of mineralising fluids and metals. 1

Co-axial superposed folding and inverted regional metamorphism in the Tonga Formation: Cretaceous accretionary thrust tectonics in the Cascades crystalline core

NASA Astrophysics Data System (ADS)

Luke, Jensen; Lebit, Hermann; Paterson, Scott; Miller, Robert; Vernon, Ron

2017-04-01

The Cascades crystalline core forms part of the Cretaceous magmatic belt of western North America and exposes a crustal section composed of primarily tonalitic plutons that intruded siliciclastic metasediments of an arc-derived accretional system, and local meta-basalt/chert sequences. This study is the first attempt to correlate the well understood intrusive and P-T-t history of the metasedimentary and plutonic terrane with the kinematics and tectonic boundary conditions by rigorous analysis of structures documented in the Tonga Formation exposed at the western edge of the core. The Tonga Formation comprises pelite-psammite metasediments, which increase from greenschist ( 300-350° C) to amphibolite grade ( 500-600° C) from south to north. This metamorphic gradient is inverted relative to a major westward verging and downward facing fold system that dominates the internal architecture of the formation and implies that the initial regional metamorphic signature was established prior to the early fold generation. Subsequent co-axial fold superposition is seen as a consequence of the persistent accretional west-vergent thrusting in the foreland of the magmatic arc. The central section of the Cascades Range, exposed in western Washington, forms part of the Cretaceous accretional/magmatic arc extending over 4,000 km along western North America from Baja California to British Columbia (Fig. 1a) (e.g. Misch, 1966; Brown, 1987; Tabor et al., 1989). Two models exist for the evolution of the Cascades crystalline core with one invoking magmatic loading (e.g. Brown and Walker, 1993) as the major cause for rapid loading, consequent regional metamorphism and vertical uplift (Evans and Berti, 1986). Conversely, other workers favor a model that suggests loading as a consequence of tectonic, thrust-related thickening, followed by rapid exhumation of the exposed crustal section of 10 to 40 km paleodepth (e.g. Matzel, 2004; Patterson et al., 2004; Stowell et al., 2007). In this

Early Proterozoic ties between two suspect terranes and the Mojave crustal block of the Southwestern U.S

USGS Publications Warehouse

Bender, E. Erik; Morrison, Jean; Anderson, J. Lawford; Wooden, Joseph L.

1993-01-01

Southern California and adjacent areas contain two suspect or exotic terranes comprised largely of ancient continental crust, namely the Tujunga (San Gabriel) and Joshua Tree terranes, that have been considered part of a larger displaced terrane, the Santa Lucia-Orocopia allochthon. Paleomagnetic data for the allochthon indicate northward transport in excess of 2000 km and, thus, an origin extraneous to North America. However, Early Proterozoic plutons of the Mojave crustal block and the Joshua Tree and Tujunga terranes have strikingly comparable features, including: (1) crystallization ages of 1.63 to 1.68 Ga; (2) biotite + sphene + magnetite hornblende garnet mineralogy; (3) high LIL and enriched HFS elemental composition; (4) WPG (within-plate granite) trace element chemistry; (5) similar and unique oxygen isotopic compositions; and (6) distinct Pb and Nd isotopic signatures. These features of the Mojave block, which clearly originated as part of native North America, nevertheless distinguish it from crust elsewhere in North America. On the basis of data presented here, we conclude that the Tujunga terrane is a disrupted portion of the Mojave crustal block and is neither far-traveled nor exotic to North America. Its apparent "exotic" nature stems from derivation out of the middle crust. We also conclude that the Joshua Tree terrane is correlative to the Mojave block. We have found no significant evidence for its displacement and consider Joshua Tree to be contiguous with the Mojave block and thus not a valid terrane. The Tujunga (San Gabriel) and Joshua Tree terranes should not be considered as part of, or having shared the same transport as, the Santa Lucia-Orocopia allocthon.

Intracontinental subduction and hinged unroofing along the Salmon River Suture Zone, west central Idaho

NASA Astrophysics Data System (ADS)

Selverstone, Jane; Wernicke, Brian P.; Aliberti, Elaine A.

1992-02-01

The Salmon River suture zone in west central Idaho juxtaposes volcanic arc rocks of the Wallowa terrane directly against cratonic North America. Detailed metamorphic studies along a 10 km traverse perpendicular to the suture indicate that the arc and two crystalline fragments thrust upon it each record different pressure-temperature (P-T) histories. From lowest to highest structural level: the Wallowa terrane shows only subgreenschist metamorphism, the Rapid River plate (RRP) records unroofing and cooling from ˜8 kbar and 550°C to 6 kbar and 475°-500°C, and the Pollock Mountain plate (PMP) shows evidence for polymetamorphism and records burial and heating paths to final equilibration conditions of 9-11 kbar and 600°-625° C. Ar-Ar hornblende ages combined with the P-T data suggest that currently exposed levels of the RRP and PMP were juxtaposed against one another at 15-20 km depth at or prior to 118 Ma, indicating that 10-20 km of uplift, and hence also the onset of collision-related metamorphism, occurred before ˜118 Ma. Correlation of the metamorphic and age data with geometric constraints from the initial Sr 0.706 line and the dimensions of the RRP and PMP permit construction of large-scale retrodeformable sections of the west side of the suture from Late Jurassic through Late Cretaceous time. The abrupt nature of the Sr 0.706 line implies that the arc-continent boundary extends vertically through most of the crust, which requires sharp downwarping of the arc lithosphere in order to account for the PMP metamorphic data. Narrow zoned overgrowths on PMP garnets record this burial event and require initially rapid (≥3 km/m.y.) uplift rates in order to be preserved. We suggest that the onset of rapid uplift resulted from the separation of the negatively buoyant lithospheric root from the downwarped arc, allowing buoyant rise of fragments of thickened crust. Detachment of the root is suggested to change the environment of crustal shortening from one in which

Metamorphic origin of ore-forming fluids for orogenic gold-bearing quartz vein systems in the North American Cordillera: constraints from a reconnaissance study of δ15N, δD, and δ18O

USGS Publications Warehouse

Jia, Y.; Kerrich, R.; Goldfarb, R.

2003-01-01

The western North American Cordillera hosts a large number of gold-bearing quartz vein systems from the Mother Lode of southern California, through counterparts in British Columbia and southeastern Alaska, to the Klondike district in central Yukon. These vein systems are structurally controlled by major fault zones, which are often reactivated terrane-bounding sutures that formed in orogens built during accretion and subduction of terranes along the continental margin of North America. Mineralization ages span mid-Jurassic to early Tertiary and encompass much of the evolution ofthe Cordilleran orogen. Nitrogen contents and δ15N values of hydrothermal micas from veins are between 130 and 3,500 ppm and 1.7 to 5.5 per mil, respectively. These values are consistent with fluids derived from metamorphic dehydration reactions within the Phanerozoic accretion-subduction complexes, which have δ15N values of 1 to 6 per mil. The δ18O values of gold-bearing vein quartz from different locations in the Cordillera are between 14.6 and 22.2 per mil but are uniform for individual vein systems. The δD values of hydrothermal micas are between -110 and -60 per mil. Ore fluids have calculated δ18O values of 8 to 16 per mil and δD values of -65 to -10 per mil at an estimated temperature of 300δC; δD values of ore fluids do not show any latitudinal control. These results indicate a deep crustal source for the ore-forming fluids, most likely of metamorphic origin. Low δDH2O values of -120 to -130 per mil for a hydrous muscovite from the Sheba vein in the Klondike district reflect secondary exchange between recrystallizing mica and meteoric waters. Collectively, the N, H, and O isotope compositions of ore-related hydrothermal minerals indicate that the formation of these gold-bearing veins involved dilute, aqueous carbonic, and nitrogen-bearing fluids that were generated from metamorphic dehydration reactions at deep crustal levels. These data are not consistent with either mantle

Metamorphic Proteins: Emergence of Dual Protein Folds from One Primary Sequence.

PubMed

Lella, Muralikrishna; Mahalakshmi, Radhakrishnan

2017-06-20

Every amino acid exhibits a different propensity for distinct structural conformations. Hence, decoding how the primary amino acid sequence undergoes the transition to a defined secondary structure and its final three-dimensional fold is presently considered predictable with reasonable certainty. However, protein sequences that defy the first principles of secondary structure prediction (they attain two different folds) have recently been discovered. Such proteins, aptly named metamorphic proteins, decrease the conformational constraint by increasing flexibility in the secondary structure and thereby result in efficient functionality. In this review, we discuss the major factors driving the conformational switch related both to protein sequence and to structure using illustrative examples. We discuss the concept of an evolutionary transition in sequence and structure, the functional impact of the tertiary fold, and the pressure of intrinsic and external factors that give rise to metamorphic proteins. We mainly focus on the major components of protein architecture, namely, the α-helix and β-sheet segments, which are involved in conformational switching within the same or highly similar sequences. These chameleonic sequences are widespread in both cytosolic and membrane proteins, and these folds are equally important for protein structure and function. We discuss the implications of metamorphic proteins and chameleonic peptide sequences in de novo peptide design.

Color Me Metamorphic.

ERIC Educational Resources Information Center

Birdd, Donald L.

1990-01-01

Described are five activities using crayons to demonstrate the rock cycle including weathering, erosion and sedimentation, and sedimentary, metamorphic, and igneous rock formation. Discussed are materials, procedures, and probable results. (CW)

Paleomagnetic Progress in Peri-Gondwanan Terranes of Cape Breton Island, Nova Scotia

NASA Astrophysics Data System (ADS)

Grunow, A. M.; Thompson, M. D.; Barr, S. M.; White, C. E.

2009-05-01

Paleopoles from primary Ediacaran magnetization directions established the Gondwanan origin of northern Appalachian Avalonian terranes, but magnetic overprints in the same rocks also provide useful tectonic information. Thus, in the Southeastern New England Avalon Zone, virtual geomagnetic poles (VGPs) calculated from magnetic B and C components in both 595 Ma Lynn-Mattapan volcanic rocks and 490-488 Ma Nahant Gabbro track mid- and late Paleozoic segments of the North American apparent polar wander path (APWP), suggesting the influence of Acadian and Neo-Acadian accretionary events. We report here on multi- vectorial magnetizations in pilot samples from Cape Breton Island, Nova Scotia where the Bras d'Or and Mira terranes represent both Ganderian and Avalonian elements transferred from Gondwana. Overprint relationships in these terranes may constrain their amalgamation with each other as well their docking with Laurentia. As in southeastern New England, secondary remanences can be identified in Cape Breton Island as consistent magnetization directions in rocks of differing ages. The S- to SSE-trending and gently downward pointing direction reported in 1985 by Johnson and Van der Voo in Middle Cambrian sedimentary rocks of the Bourinot Group (Bras d'Or terrane), for example, is also present in the 563 Ma Main à Dieu Formation and in 620 Ma Chisholm Brook Granite and East Bay Hill rhyolite (Mira terrane). This magnetization represents the C component already found around Boston, MA. The resulting VGPs in both areas occupy positions on the North American APWP consistent with a Neo-Acadian overprint, possibly related to the docking of the Meguma terrane against previously accreted Avalonia. Other overprint directions encountered in this investigation give rise to VGPs that do not coincide with the North American APWP, hence appear to reflect tectonic events independent of Laurentia. One such cluster comprising both Mira and Bras d'Or VGPs includes the paleopole also

Investigating the response of biotite to impact metamorphism: Examples from the Steen River impact structure, Canada

NASA Astrophysics Data System (ADS)

Walton, E. L.; Sharp, T. G.; Hu, J.; Tschauner, O.

2018-01-01

Impact metamorphic effects from quartz and feldspar and to a lesser extent olivine and pyroxene have been studied in detail. Comparatively, studies documenting shock effects in other minerals, such as double chain inosilicates, phyllosilicates, carbonates, and sulfates, are lacking. In this study, we investigate impact metamorphism recorded in crystalline basement rocks from the Steen River impact structure (SRIS), a 25 km diameter complex crater in NW Alberta, Canada. An array of advanced analytical techniques was used to characterize the breakdown of biotite in two distinct settings: along the margins of localized regions of shock melting and within granitic target rocks entrained as clasts in a breccia. In response to elevated temperature gradients along shock vein margins, biotite transformed at high pressure to an almandine-Ca/Fe majorite-rich garnet with a density of 4.2 g cm-3. The shock-produced garnets are poikilitic, with oxide and silicate glass inclusions. Areas interstitial to garnets are vesiculated, in support of models for the formation of shock veins via oscillatory slip, with deformation continuing during pressure release. Biotite within granitic clasts entrained within the hot breccia matrix thermally decomposed at ambient pressure to produce a fine-grained mineral assemblage of orthopyroxene + sanidine + titanomagnetite. These minerals are aligned to the (001) cleavage plane of the original crystal. In this and previous work, the transformation of an inosilicate (pargasite) and a phyllosilicate (biotite) to form garnet, an easily identifiable, robust mineral, has been documented. We contend that in deeply eroded astroblemes, high-pressure minerals that form within or in the environs of shock veins may serve as one of the possibly few surviving indicators of impact metamorphism.

Velocity Structure of the Subducted Yakutat Terrane, Alaska: Insights from Guided Waves

NASA Astrophysics Data System (ADS)

Coulson, S.; Garth, T.; Rietbrock, A.

2017-12-01

the YT reducing the bulk velocity of the LVL. Increased velocities seen at the northern edge of the YT can be explained by reacted MORB or gabbro assemblages. This may be explained by a lack of interbedded sediments in this part of the YT, or the warmer conditions at the edge of the subducted terrane causing a faster pace of metamorphic reaction in this part of the slab.

A tectonic reconstruction of accreted terranes along the paleo-Pacific margin of Gondwana

NASA Astrophysics Data System (ADS)

Bammel, Brandon

The southern oceanic margin of Gondwana was nearly 40,000 km long or 24,854.8 miles. The southern margin was the result of the Terra Australis orogen. Spanning 18,000 km or 11,184.7 miles and is proposed as one of the largest and longest lived orogens in Earth history. The paleo-Pacific margin of Gondwana consisted of segments of the Australian-Antarctic craton, southern South America (modern Argentina and Chile), southern South Africa, Marie Byrdland, New Zealand and its adjacent continental shelf, the Ellsworth Mountains, and the Transantarctic Mountains. The process of terrane accretion has played a substantial part in the assembly of the continents as they look today. The paleo-Pacific margin of Gondwana was an active region of terrane accretion from the Neoproterozoic to the Late Mesozoic. This research study examines the accretion of terranes across the paleo-Pacific Gondwana margin to provide a comprehensive reconstruction. A paleogeographic basemap was created using PALEOMAP Project maps and the geology data was provided by the School of Geoscience from the University of Witwatersrand of South Africa. Location and data analyzed for terranes were collected building a PDF library of journal articles across numerous geological publications.

Effect of ultra-high pressure homogenization on the interaction between bovine casein micelles and ritonavir.

PubMed

Corzo-Martínez, M; Mohan, M; Dunlap, J; Harte, F

2015-03-01

The aim of this work was to develop a milk-based powder formulation appropriate for pediatric delivery of ritonavir (RIT). Ultra-high pressure homogenization (UHPH) at 0.1, 300 and 500 MPa was used to process a dispersion of pasteurized skim milk (SM) and ritonavir. Loading efficiency was determined by RP-HPLC-UV; characterization of RIT:SM systems was carried out by apparent average hydrodynamic diameter and rheological measurements as well as different analytical techniques including Trp fluorescence, UV spectroscopy, DSC, FTIR and SEM; and delivery capacity of casein micelles was determined by in vitro experiments promoting ritonavir release. Ritonavir interacted efficiently with milk proteins, especially, casein micelles, regardless of the processing pressure; however, results suggest that, at 0.1 MPa, ritonavir interacts with caseins at the micellar surface, whilst, at 300 and 500 MPa, ritonavir is integrated to the protein matrix during UHPH treatment. Likewise, in vitro experiments showed that ritonavir release from micellar casein systems is pH dependent; with a high retention of ritonavir during simulated gastric digestion and a rapid delivery under conditions simulating the small intestine environment. Skim milk powder, especially, casein micelles are potentially suitable and efficient carrier systems to develop novel milk-based and low-ethanol powder formulations of ritonavir appropriate for pediatric applications.

Can the Metamorphic Basement of Northwestern Guatemala be Correlated with the Chuacús Complex?

NASA Astrophysics Data System (ADS)

Cacao, N.; Martens, U.

2007-05-01

The Chuacús complex constitutes a northward concave metamorphic belt that stretches ca. 150 km south of the Cuilco-Chixoy-Polochic (CCP) fault system in central and central-eastern Guatemala. It represents the basement of the southern edge of the Maya block, being well exposed in the sierra de Chuacús and the sierra de Las Minas. It is composed of high-Al metapelites, amphibolites, quartzofeldspathic gneisses, and migmatites. In central Guatemala the Chuacús complex contains ubiquitous epidote-amphibolite mineral associations, and local relics of eclogite reveal a previous high-pressure metamorphic event. North of the CCP, in the Sierra de Los Cuchumatanes area of western Guatemala, metamorphic rocks have been considered the equivalent of the Chuacús complex and hence been given the name Western Chuacús group, These rocks, which were intruded by granitic rocks and later mylonitized, include chloritic schist and gneiss, biotite-garnet schist, migmatites, and amphibolites. No eclogitic relics have been found within metamorphic rocks in northwestern Guatemala. Petrographic analyses of garnet-biotite schist reveal abundant retrogression and the formation of abundant zeolite-bearing veins associated with intrusion. Although metamorphic conditions in the greenschist and amphibolite facies are similar to those in the sierra de Chuacús, the association with deformed intrusive granites is unique for western Guatemala. Hence a correlation with metasediments intruded by the Rabinal granite in the San Gabriel area of Baja Verapaz seems more feasible than a correlation with the Chuacús complex. This idea is supported by reintegration of the Cenozoic left-lateral displacement along the CCP, which would place the metamorphic basement of western Guatemala north of Baja Verapaz, adjacent to metasediments intruded by granites in the San Gabriel-Rabinal area.

Petrological evolution of subducted rodingite from seafloor metamorphism to dehydration of enclosing antigorite-serpentinite (Cerro del Almirez massif, southern Spain)

NASA Astrophysics Data System (ADS)

Laborda-López, Casto; López Sánchez-Vizcaíno, Vicente; Marchesi, Claudio; Gómez-Pugnaire, María Teresa; Garrido, Carlos J.; Jabaloy-Sánchez, Antonio; Padrón-Navarta, José Alberto

2016-04-01

Rodingites are common rocks associated with serpentinites in exhumed terrains that experienced subduction and high pressure metamorphism. However, the response of these rocks to devolatilization and redox reactions in subduction settings is not well constrained. In the Cerro del Almirez ultramafic massif (southern Spain) rodingites constitute about 1-2% of the total volume of exposed rocks. Metarodingites are enclosed in antigorite-serpentinite and chlorite-harzburgite separated by a transitional zone that represents the front of prograde serpentinite-dehydration in a paleo-subduction setting (Padrón-Navarta et al., 2011). Metarodingites occur as boudin lenses, 1 to 20 m in length and 30 cm to 2 m in thickness. During serpentinization of peridotite host rocks, dolerites and basalts precursor of rodingites underwent intense seafloor metasomatism, causing the enrichment in Ca and remobilization of Na and K. Subsequent metamorphism during subduction transformed the original igneous and seafloor metamorphic mineralogy into an assemblage of garnet (Ti-rich hydrogrossular), diopside, chlorite, and epidote. During prograde metamorphism, garnet composition changed towards higher andradite contents. High-pressure transformation of enclosing antigorite-serpentinite to chlorite-harzburgite released fluids which induced breakdown of garnet to epidote in metarodingites. Ti liberation by this latter reaction produced abundant titanite. Released fluids also triggered the formation of amphibole by alkalis addition. Highly recrystallized metarodingites in chlorite-harzburgite present a new generation of idiomorphic garnet with composition equal to 10-30% pyrope, 30-40% grossular and 35-55% almandine + spessartine. This garnet has titanite inclusions in the core and rutile inclusions in the rim. The contact between metarodingites and ultramafic rocks consists of a metasomatic zone (blackwall) with variable thickness (7 to 40 cm) constituted by chlorite, diopside, and titanite

Reconnaissance Geologic Map of the Hayfork 15' Quadrangle, Trinity County, California

USGS Publications Warehouse

Irwin, William P.

2010-01-01

The Hayfork 15' quadrangle is located just west of the Weaverville 15' quadrangle in the southern part of the Klamath Mountains geologic province of northern California. It spans parts of six generally north-northwest-trending tectonostratigraphic terranes that are, from east to west, the Eastern Klamath, Central Metamorphic, North Fork, Eastern Hayfork, Western Hayfork, and Rattlesnake Creek terranes. Remnants of a once-widespread postaccretionary overlap assemblage, the Cretaceous Great Valley sequence, crop out at three localities in the southern part of the Hayfork quadrangle. The Tertiary fluvial and lacustrine Weaverville Formation occupies a large, shallow, east-northeast-trending graben in the south half of the quadrangle. The small area of Eastern Klamath terrane is part of the Oregon Mountain outlier, which is more widely exposed to the east in the Weaverville 15' quadrangle. It was originally mapped as a thrust plate of Bragdon(?) Formation, but it is now thought by some to be part of an outlier of Yreka terrane that has been dislocated 60 km southward by the La Grange Fault. The Central Metamorphic terrane, which forms the footwall of the La Grange Fault, was formed by the eastward subduction of oceanic crustal basalt (the Salmon Hornblende Schist) and its overlying siliceous sediments with interbedded limestone (the Abrams Mica Schist) beneath the Eastern Klamath terrane. Rb-Sr analysis of the Abrams Mica Schist indicates a Middle Devonian metamorphic age of approximately 380 Ma, which probably represents the age of subduction. The North Fork terrane, which is faulted against the western boundary of the Central Metamorphic terrane, consists of the Permian(?) North Fork ophiolite and overlying broken formation and melange of Permian to Early Jurassic (Pliensbachian) marine metasedimentary and metavolcanic rocks. The ophiolite, which crops out along the western border of the terrane, is thrust westward over the Eastern Hayfork terrane. The Eastern

Mesoproterozoic syntectonic garnet within Belt Supergroup metamorphic tectonites: Evidence of Grenville-age metamorphism and deformation along northwest Laurentia

USGS Publications Warehouse

Nesheim, T.O.; Vervoort, J.D.; McClelland, W.C.; Gilotti, J.A.; Lang, H.M.

2012-01-01

Northern Idaho contains Belt-Purcell Supergroup equivalent metamorphic tectonites that underwent two regional deformational and metamorphic events during the Mesoproterozoic. Garnet-bearing pelitic schists from the Snow Peak area of northern Idaho yield Lu-Hf garnet-whole rock ages of 1085??2. Ma, 1198??79. Ma, 1207??8. Ma, 1255??28. Ma, and 1314??2. Ma. Garnet from one sample, collected from the Clarkia area, was micro-drilled to obtain separate core and rim material that produced ages of 1347??10. Ma and 1102??47. Ma. The core versus rim ages from the micro-drilled sample along with the textural and spatial evidence of the other Lu-Hf garnet ages indicate two metamorphic garnet growth events at ~. 1330. Ma (M1) and ~. 1080. Ma (M2) with the intermediate ages representing mixed ages. Some garnet likely nucleated and grew M1 garnet cores that were later overgrown by younger M2 garnet rims. Most garnet throughout the Clarkia and Snow Peak areas are syntectonic with a regional penetrative deformational fabric, preserved as a strong preferred orientation of metamorphic matrix minerals (e.g., muscovite and biotite). The syntectonic garnets are interpreted to represent one regional, coeval metamorphic and deformation event at ~. 1080. Ma, which overlaps in time with the Grenville Orogeny. The older ~. 1330. Ma ages may represent an extension of the East Kootenay Orogeny described in western Canada. These deformational and metamorphic events indicate that western Laurentia (North America) was tectonically active in the Mesoproterozoic and during the assembly of the supercontinent Rodinia. ?? 2011 Elsevier B.V.

Assessment of Paleozoic terrane accretion along the southern central Andes using detrital zircon geochronology

NASA Astrophysics Data System (ADS)

McKenzie, R.; Horton, B. K.; Fuentes, F.; Fosdick, J. C.; Capaldi, T.; Stockli, D. F.; Alvarado, P. M.

2015-12-01

Two distinct Paleozoic terranes known as Cuyania and Chilenia occupy the southern central Andes of Argentina and Chile. Because the proposed terrane boundaries coincide with major structural elements of the modern Andean system at 30-36°S, it is important to understand their origins and potential role in guiding later Andean deformation. The Cuyania terrane of western Argentina encompasses the Precordillera (PC) and a thick-skinned thrust block of the western Sierras Pampeanas, persisting southward to the San Rafael Basin (SRB). Although recently challenged, Cuyania has been long considered a piece of southern Laurentia that rifted away during the early Cambrian and collided with the Argentine margin during the Ordovician. Chilenia is situated west of Cuyania and includes the Frontal Cordillera (FC) and Andean magmatic arc. This less-studied terrane was potentially accreted during an enigmatic Devonian orogenic event. We present new detrital zircon U-Pb age data from siliciclastic sedimentary rocks that span the entire Paleozoic to Triassic from the FC, PC, and SRB. Cambrian rocks of the PC exhibit similar zircon age distributions with prominent ~1.4 and subordinate ~1.1 Ga populations, which are distinct from other Paleozoic strata. Plutonic rocks with these ages are common in southern Laurentia, whereas ~1.4 Ga zircons are uncommon in South American age distributions. This supports a Laurentian origin for Cuyania in isolation from Argentina during the Cambrian. Upper Paleozoic strata from the PC, FC, and SRB all yield similar age data suggesting shared provenance across the proposed Cuyania-Chilenia suture. Age distributions also notably lack Devonian-age grains. The regional paucity of Devonian plutonic rocks and detrital zircon casts doubt on a possible arc system between these terranes at this time, a key requisite for the mid-Paleozoic transfer and accretion of Chilenia to the Argentine margin. Collectively, these data question the precise boundaries of the

Dual sources of water overprinting on the low zircon δ18O metamorphic country rocks: Disequilibrium constrained through inverse modelling of partial reequilibration

PubMed Central

Wei, Chun-Sheng; Zhao, Zi-Fu

2017-01-01

Since water is only composed of oxygen and hydrogen, δ18O and δ2H values are thus utilized to trace the origin of water(s) and quantify the water-rock interactions. While Triassic high pressure (HP) and ultrahigh pressure (UHP) metamorphic rocks across the Dabie-Sulu orogen in central-eastern China have been well documented, postcollisional magmatism driven hydrothermal systems are little known. Here we show that two sources of externally derived water interactions were revealed by oxygen isotopes for the gneissic country rocks intruded by the early Cretaceous postcollisional granitoids. Inverse modellings indicate that the degree of disequilibrium (doD) of meteoric water interactions was more evident than that of magmatic one (−65 ± 1o vs. −20 ± 2°); the partial reequilibration between quartz and alkali feldspar oxygen isotopes with magmatic water was achieved at 340 °C with a water/rock (W/R) ratio of about 1.2 for an open-hydrothermal system; two-stage meteoric water interactions were unraveled with reequilibration temperatures less than 300 °C and W/R ratios around 0.4. The lifetime of fossil magmatic hydrothermal system overprinted on the low zircon δ18O orthogneissic country rocks was estimated to maintain up to 50 thousand years (Kyr) through oxygen exchange modellings. Four-stage isotopic evolutions were proposed for the magmatic water interacted gneiss. PMID:28091552

The Hadean to Paleoarchean geodynamo: microconglomerate tests from siliciclastic metasedimentary rocks from the Southern Cross Terrane of Western Australia

NASA Astrophysics Data System (ADS)

Cottrell, R. D.; Tarduno, J. A.; Bono, R. K.; Thern, E. R.; Chhibber, S. K.

2016-12-01

Detrital zircons found within metasedimentary rocks of the Yilgarn Craton (Western Austrlia) contain information about the early history of the geodynamo. Recently reported single crystal paleointensity (SCP) values obtained from zircon grains of the Jack Hills (JH) belt (Tarduno et al., 2015) suggest the presence of a core dynamo to times as old as 4.2 Ga. Magnetizations carried by zircons within these rocks have been preserved despite multiple reheating events of the host metasedimentary unit. Two positive conglomerate tests (Tarduno and Cottrell, 2013; Tarduno et al., 2015) as well as interlaboratory studies reproducing a prior positive conglomerate test (Dare et al., 2015; 2016) attest to the primary nature of the remanence carried by these zircons. Moreover, new Li data limit heating after zircon formation to < 500 oC. Similarly, the metasedimentary rocks of the Southern Cross Terrane, more than 400 kilometers away from the Discovery Site of the Jack Hills, contain detrital Eoarchean to Hadean age zircons (Nelson, 2005; Wyche, 2007). Following Tarduno et al. (2015), a micro-conglomerate test of oriented, small ( 500-700 mm) samples centered on single zircons ( 200-350 mm) was performed using the University of Rochester's ultra-high resolution 3-component DC SQUID magnetometer that affords an order of magnitude greater sensitivity than other high-resolution SQUID rock magnetometers. The characteristic remanences from oriented zircons (N=10; R=0.81) that unblock between 565 and 580 °C, consistent with a magnetite carrier, are well defined but together cannot be distinguished from those drawn from a random distribution (Ro=5.03) at the 95% confidence level; this indicates a positive microconglomerate test. Preliminary paleointensity determinations range between 4-27 μT. Additional studies of hand samples from the Southern Cross Terrane are underway.

Accretion in the wake of terrane collision: The Neogene accretionary wedge off Kenai Peninsula, Alaska

USGS Publications Warehouse

Fruehn, J.; von Huene, Roland E.; Fisher, M.A.

1999-01-01

Subduction accretion and repeated terrane collision shaped the Alaskan convergent margin. The Yakutat Terrane is currently colliding with the continental margin below the central Gulf of Alaska. During the Neogene the terrane's western part was subducted after which a sediment wedge accreted along the northeast Aleutian Trench. This wedge incorporates sediment eroded from the continental margin and marine sediments carried into the subduction zone on the Pacific plate. Prestack depth migration was performed on six seismic reflection lines to resolve the structure within this accretionary wedge and its backstop. The lateral extent of the structures is constrained by high-resolution swath bathymetry and seismic lines collected along strike. Accretionary structure consists of variably sized thrust slices that were deformed against a backstop during frontal accretion and underplating. Toward the northeast the lower slope steepens, the wedge narrows, and the accreted volume decreases notwith-standing a doubling of sediments thickness in the trench. In the northeasternmost transect, near the area where the terrane's trailing edge subducts, no frontal accretion is observed and the slope is eroded. The structures imaged along the seismic lines discussed here most likely result from progressive evolution from erosion to accretion, as the trailing edge of the Yakutat Terrane is subducting.

Kilbuck terrane: oldest known rocks in Alaska

USGS Publications Warehouse

Box, S.E.; Moll-Stalcup, E. J.; Wooden, J.L.; Bradshaw, J.Y.

1990-01-01

The Kilbuck terrane in southwestern Alaska is a narrow, thin crustal sliver or flake of amphibolite facies orthogneiss. The igneous protolith of this gneiss was a suite of subduction-related plutonic rocks. U-Pb data on zircons from trondhjemitic and granitic samples yield upper-intercept (igneous) ages of 2070 ?? 16 and 2040 ?? 74 Ma, respectively. Nd isotope data from these rocks suggest that a diorite-tonalite-trondhjemite suite (??Nd[T] = +2.1 to +2.7; T is time of crystallization) evolved from partial melts of depleted mantle with no discernible contamination by older crust, whereas a coeval granitic pluton (??Nd[T] = -5.7) contains a significant component derived from Archean crust. Orthogneisses with similar age and Nd isotope characteristics are found in the Idono complex 250 km to the north. Early Proterozoic rocks are unknown elsewhere in Alaska. The possibility that the Kilbuck terrane was displaced from provinces of similar age in other cratons (e.g., Australian, Baltic, Guiana, and west African shields), or from the poorly dated Siberian craton, cannot be excluded. -from Authors

Artificial neural network modeling and optimization of ultrahigh pressure extraction of green tea polyphenols.

PubMed

Xi, Jun; Xue, Yujing; Xu, Yinxiang; Shen, Yuhong

2013-11-01

In this study, the ultrahigh pressure extraction of green tea polyphenols was modeled and optimized by a three-layer artificial neural network. A feed-forward neural network trained with an error back-propagation algorithm was used to evaluate the effects of pressure, liquid/solid ratio and ethanol concentration on the total phenolic content of green tea extracts. The neural network coupled with genetic algorithms was also used to optimize the conditions needed to obtain the highest yield of tea polyphenols. The obtained optimal architecture of artificial neural network model involved a feed-forward neural network with three input neurons, one hidden layer with eight neurons and one output layer including single neuron. The trained network gave the minimum value in the MSE of 0.03 and the maximum value in the R(2) of 0.9571, which implied a good agreement between the predicted value and the actual value, and confirmed a good generalization of the network. Based on the combination of neural network and genetic algorithms, the optimum extraction conditions for the highest yield of green tea polyphenols were determined as follows: 498.8 MPa for pressure, 20.8 mL/g for liquid/solid ratio and 53.6% for ethanol concentration. The total phenolic content of the actual measurement under the optimum predicated extraction conditions was 582.4 ± 0.63 mg/g DW, which was well matched with the predicted value (597.2mg/g DW). This suggests that the artificial neural network model described in this work is an efficient quantitative tool to predict the extraction efficiency of green tea polyphenols. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Characterising the metamorphic discontinuity across the Main Central Thrust Zone of eastern-central Nepal

NASA Astrophysics Data System (ADS)

Wang, Jiamin; Zhang, Jinjiang; Wei, Chunjing; Rai, SantaMan; Wang, Meng; Qian, Jiahui

2015-04-01

The Main Central Thrust Zone (MCTZ) is a top-to-south shear zone that has exhumed the high-grade Himalayan metamorphic core during the orogeny. Identifying the location of the MCTZ is a major challenge and the characteristics of the metamorphic discontinuity remain under debate. To clarify this issue, petrologic and thermobarometric studies were carried out on metapelites and metapsammites that were collected from the basal Nyalam transect in eastern-central Nepal. Results reveal that the metamorphic discontinuity across the MCTZ is characterised by a continuous increase in peak P-T conditions toward higher structural levels, a relatively high field temperature gradient (25-50 °C km-1) and different types of P-T paths. Specifically, representative rocks in the MCTZ record sub-solidus peak conditions (637 ± 16 °C and 9.2 ± 1.0 kbar) and a hairpin-type P-T path. The lower GHC rocks record supra-solidus peak conditions (690 ± 32 °C and 10.3 + 1.1/-1.4 kbar) and a prograde loading path with a small segment of decompression. The presence of a high field pressure gradient across the MCTZ is debatable in the Nyalam transect due to the large uncertainties in pressure estimates. Comparison between obtained P-T results and model predictions indicates that a multiple thrusting process dominated exhumation of the MCTZ and lower GHC rocks, while crustal flow contributed partly to exhumation of the lower GHC rocks.

Provenance and metamorphic PT conditions of Cryogenian-Ediacaran metasediments from the Kid metamorphic complex, Sinai, NE Arabian-Nubian Shield: Insights from detrital zircon geochemistry and mineral chemistry

NASA Astrophysics Data System (ADS)

El-Bialy, Mohammed Z.; Ali, Kamal A.; Abu El-Enen, Mahrous M.; Ahmed, Ahmed H.

2015-12-01

The Malhaq and Um Zariq formations occupy the northern part of the Neoproterozoic Kid metamorphic complex of SE Sinai, NE Arabian-Nubian Shield. This study presents new mineral chemistry data and LA-ICP-MS analyses of the trace element concentrations on zircons separated from metapelites from these formations. The detrital zircons of Um Zariq Formation are more enriched in ΣREE, whereas Malhaq Formation zircons are markedly HREE-enriched with strongly fractionated HREE patterns. The quite differences in the overall slope and size of the Eu and Ce anomalies between REE patterns of the two zircon suites provide a robust indication of different sources. The Ti-in-zircon thermometer has revealed that the zircons separated from Malhaq Formation were crystallized within the 916-1018 °C range, while those from Um Zariq Formation exhibit higher range of crystallization temperatures (1084-1154 °C). The detrital zircons of Malhaq Formation were derived mainly from mafic source rocks (basalt and dolerite), whereas Um Zariq Formation zircons have varied and more evolved parent rocks. Most of the investigated zircons from both formations are concluded to be unaltered magmatic that were lately crystallized from a high LREE/HREE melt. All the studied detrital zircon grains show typical trace elements features of crustal-derived zircons. All of the Um Zariq Formation and most of Malhaq Formation detrital zircons are geochemically discriminated as continental zircons. Both formation metapelites record similar, overlapping peak metamorphic temperatures (537-602 °C and 550-579 °C, respectively), and pressures (3.83-4.93 kbar and 3.69-4.07 kbar, respectively). The geothermal gradient, at the peak metamorphic conditions, was quite high (37-41 °C/km) corresponding to metamorphism at burial depth of 14-16 km. The peak regional metamorphism of Um Zariq and Malhaq formations is concluded to be generated during extensional regime and thinning of the lithosphere in an island arc

Middle Jurassic strata link Wallowa, Olds Ferry, and Izee terranes in the accreted Blue Mountains island arc, northeastern Oregon

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, J.D.L.; Vallier, T.; Stanley, G.D. Jr.

1992-08-01

Middle Jurassic strata atop the Wallowa terrane in northeastern Oregon link the Wallowa, Izee, and Olds Ferry terranes as related elements of a single long-lived and complex oceanic feature, the Blue Mountains island arc. Middle Jurassic strata in the Wallowa terrane include a dacitic ash-flow deposit and contain fossil corals and bivalves of North American affinity. Plant fossils in fluvial sandstones support a Jurassic age and indicate a seasonal temperate climate. Corals in a transgressive sequence traditionally overlying the fluvial units are of Bajocian age and are closely related to endemic varieties of the Western Interior embayment. They are unlikemore » Middle Jurassic corals in other Cordilleran terranes; their presence suggests that the Blue Mountains island arc first approached the North American craton at high paleolatitudes in Middle Jurassic time. The authors consider the Bajocian marine strata and underlying fluvial volcaniclastic units to be a basin-margin equivalent of the Izee terrane, a largely Middle Jurassic (Bajocian) succession of basinal volcaniclastic and volcanic rocks known to overlie the Olds Ferry and Baker terranes.« less

Organic matter and metamorphic history of CO chondrites

NASA Astrophysics Data System (ADS)

Bonal, Lydie; Bourot-Denise, Michèle; Quirico, Eric; Montagnac, Gilles; Lewin, Eric

2007-03-01

The metamorphic grades of a series of eight CO3 chondrites (ALHA77307, Colony, Kainsaz, Felix, Lancé, Ornans, Warrenton and Isna) have been quantified. The method used was based on the structural grade of the organic matter trapped in the matrix, which is irreversibly transformed by thermal metamorphism. The maturation of the organic matter is independent with respect to the mineralogical context and aqueous alteration. This metamorphic tracer is thus valid whatever the chemical class of chondrites. Moreover, it is sensitive to the peak metamorphic temperature. The structural grade of the organic matter was used along with other metamorphic tracers such as petrography of opaque minerals, Fa and Fs silicate composition in type I chondrules, presolar grains and noble gas (P3 component) abundance. The deduced metamorphic hierarchy and the attributed petrographic types are the following: ALHA77307 (3.03) < Colony (3.1) < Kainsaz (3.6) < Felix (3.6 (1)) < Ornans (3.6 (2)) < Lancé (3.6 (3)) < Warrenton (3.7 (1)) < Isna (3.7 (2)). For most metamorphosed objects, the peak metamorphic temperature can be estimated using a geothermometer calibrated with terrestrial metasediments [Beyssac O., Goffe B., Chopin C., and Rouzaud J. N. (2002) Raman spectrum of carbonaceous material in metasediments: a new geothermometer. J. Metamorph. Geol., 20, 859-871]. A value of 330 °C was obtained for Allende (CV chondrite), Warrenton and Isna, consistent with temperatures estimated from Fe diffusion [Weinbruch S., Armstrong J., and Palme H. (1994). Constraints on the thermal history of the Allende parent body as derive from olivine-spinel thermometry and Fe/Mg interdiffusion in olivine. Geochim. Cosmochim. Acta58(2), 1019-1030.], from the Ni content in sulfide-metal assemblages [Zanda B., Bourot-Denise M., and Hewins R. (1995) Condensate sulfide and its metamorphic transformations in primitive chondrites. Meteorit. Planet. Sci.30, A605.] and from the d002 interlayer spacing in poorly

Crustal structure of norther Oaxaca terrane; The Oaxaca and caltepec faults, and the Tehuacan Valley. A gravity study.

NASA Astrophysics Data System (ADS)

Campos-Enriquez, J. O.; Alatorre-Zamora, M. A.; Ramón, V. M.; Belmonte, S.

2014-12-01

Northern Oaxaca terrane, southern Mexico, is bound by the Caltepec and Oaxaca faults to the west and east, respectively. These faults juxtapose the Oaxaca terrane against the Mixteca and Juarez terranes, respectively. The Oaxaca Fault also forms the eastern boundary of the Cenozoic Tehuacan depression. Several gravity profiles across these faults and the Oaxaca terrane (including the Tehuacan Valley) enables us to establish the upper crustal structure of this region. Accordingly, the Oaxaca terrane is downward displaced to the east in two steps. First the Santa Lucia Fault puts into contact the granulitic basamental rocks with Phanerozoic volcanic and sedimentary rocks. Finally, the Gavilan Fault puts into contact the Oaxaca terrane basement (Oaxaca Complex) into contact with the volcano-sedimentary infill of the valley. This gravity study reveals that the Oaxaca Fault system gives rise to a series of east tilted basamental blocks (Oaxaca Complex?). A structural high at the western Tehuacan depression accomadates the east dipping faults (Santa Lucia and Gavilan faults) and the west dipping faults of the Oaxaca Fault System. To the west of this high structural we have the depper depocenters. The Oaxaca Complex, the Caltepec and Santa Lucia faults continue northwestwards beneath Phanerozoic rocks. The faults are regional tectonic structures. They seem to continue northwards below the Trans-Mexican Volcanic Belt. A major E-W to NE-SW discontinuity on the Oaxaca terrane is inferred to exist between profiles 1 and 2. The Tehuacan Valley posses a large groundwater potential.

Dewaterability of five sewage sludges in Guangzhou conditioned with Fenton's reagent/lime and pilot-scale experiments using ultrahigh pressure filtration system.

PubMed

Liang, Jialin; Huang, Shaosong; Dai, Yongkang; Li, Lei; Sun, Shuiyu

2015-11-01

Sludge conditioning with Fenton's reagent and lime is a valid method for sludge dewatering. This study investigated the influence of different organic matter content sludge on sludge dewatering and discussed the main mechanism of sludge conditioning by combined Fenton's reagent and lime. The results indicated that the specific resistance to filterability (SRF) of sludge was reduced efficiently by approximately 90%, when conditioned with Fenton's reagent and lime. Through single factor experiments, the optimal conditioning combinations were found. In addition, the relationship between VSS% and consumption of the reagents was detected. Furthermore, it was also demonstrated that the SRF and filtrate TOC values had a significant correlation with VSS% of sludge (including raw and conditioned). The main mechanism of sludge dewatering was also investigated. Firstly, it revealed that the dewaterability of sludge was closely correlated to extracellular polymeric substances (EPS) and bound water contents. Secondly, the results of scanning electron microscopy (SEM) stated that sludge particles were to be smaller and thinner after conditioning. And this structure could easily form outflow channels for releasing free water. Additionally, with the ultrahigh pressure filtration system, the water content of sludge cake conditioned with Fenton's reagent and lime could be reduced to below 50%. Moreover, the economic assessment shows that Fenton's reagent and lime combined with ultrahigh pressure filtration system can be an economical and viable technology for sewage sludge dewatering. Finally, three types of sludge were classified: (1) Fast to dewater; (2) Moderately fast to dewater; (3) Slow to dewater sludge. Copyright © 2015 Elsevier Ltd. All rights reserved.

A simple dual online ultra-high pressure liquid chromatography system (sDO-UHPLC) for high throughput proteome analysis.

PubMed

Lee, Hangyeore; Mun, Dong-Gi; Bae, Jingi; Kim, Hokeun; Oh, Se Yeon; Park, Young Soo; Lee, Jae-Hyuk; Lee, Sang-Won

2015-08-21

We report a new and simple design of a fully automated dual-online ultra-high pressure liquid chromatography system. The system employs only two nano-volume switching valves (a two-position four port valve and a two-position ten port valve) that direct solvent flows from two binary nano-pumps for parallel operation of two analytical columns and two solid phase extraction (SPE) columns. Despite the simple design, the sDO-UHPLC offers many advantageous features that include high duty cycle, back flushing sample injection for fast and narrow zone sample injection, online desalting, high separation resolution and high intra/inter-column reproducibility. This system was applied to analyze proteome samples not only in high throughput deep proteome profiling experiments but also in high throughput MRM experiments.

First application of the revised Ti-in-zircon geothermometer to Paleoproterozoic ultrahigh-temperature granulites of Tuguiwula, Inner Mongolia, North China Craton

NASA Astrophysics Data System (ADS)

Liu, S. J.; Li, J. H.; Santosh, M.

2010-02-01

The revised titanium-in-zircon geothermometer was applied to Paleoproterozoic ultrahigh-temperature (UHT) granulites at Tuguiwula, Inner Mongolia, North China Craton. The Tuguiwula granulites contain diagnostic UHT mineral assemblages such as sapphirine + quartz and high alumina orthopyroxene + sillimanite + quartz, suggesting formation under temperatures of ca. 1,000°C and pressures of up to 10 kbar. Here, we report detailed petrographic studies and ICP-MS data on titanium concentration in zircons associated with the UHT assemblages. The zircons associated with sapphirine-spinel-sillimanite-magnetite assemblages have the highest Ti concentration of up to 57 ppm, yielding a temperature of 941°C, and suggesting that the growth of zircons occurred under ultrahigh-temperature conditions. The maximum temperatures obtained by the revised Ti-in-zircon geothermometer is lower than the equilibrium temperature of sapphirine + quartz, indicating an interval of cooling history of the granulites from UHT condition to ca. 940°C. Many of the zircons have Ti concentrations ranging from 10 to 33 ppm, indicating their growth or recrystallization under lower temperatures of ca. 745-870°C. These zircons are interpreted to have recrystallized during the retrograde stage indicated by microstructures such as cordierite rim or corona between spinel and quartz, and orthopyroxene-cordierite symplectite around garnet. Previous geochronological study on the zircons of the Tuguiwula UHT granulites gave a mean U-Pb SHRIMP age of 1.92 Ga. However, based on the Ti-in-zircon geothermometer results reported in this work, and considering the relatively slow thermal relaxation of these rocks, we infer that the timing of peak UHT metamorphism in the Tuguiwula area could be slightly older than 1.92 Ga.

Metamorphic quantum dots: Quite different nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seravalli, L.; Frigeri, P.; Nasi, L.

In this work, we present a study of InAs quantum dots deposited on InGaAs metamorphic buffers by molecular beam epitaxy. By comparing morphological, structural, and optical properties of such nanostructures with those of InAs/GaAs quantum dot ones, we were able to evidence characteristics that are typical of metamorphic InAs/InGaAs structures. The more relevant are: the cross-hatched InGaAs surface overgrown by dots, the change in critical coverages for island nucleation and ripening, the nucleation of new defects in the capping layers, and the redshift in the emission energy. The discussion on experimental results allowed us to conclude that metamorphic InAs/InGaAs quantummore » dots are rather different nanostructures, where attention must be put to some issues not present in InAs/GaAs structures, namely, buffer-related defects, surface morphology, different dislocation mobility, and stacking fault energies. On the other hand, we show that metamorphic quantum dot nanostructures can provide new possibilities of tailoring various properties, such as dot positioning and emission energy, that could be very useful for innovative dot-based devices.« less

Cretaceous-Eocene provenance connections between the Palawan Continental Terrane and the northern South China Sea margin

NASA Astrophysics Data System (ADS)

Shao, Lei; Cao, Licheng; Qiao, Peijun; Zhang, Xiangtao; Li, Qianyu; van Hinsbergen, Douwe J. J.

2017-11-01

The plate kinematic history of the South China Sea opening is key to reconstructing how the Mesozoic configuration of Panthalassa and Tethyan subduction systems evolved into today's complex Southeast Asian tectonic collage. The South China Sea is currently flanked by the Palawan Continental Terrane in the south and South China in the north and the two blocks have long been assumed to be conjugate margins. However, the paleogeographic history of the Palawan Continental Terrane remains an issue of uncertainty and controversy, especially regarding the questions of where and when it was separated from South China. Here we employ detrital zircon U-Pb geochronology and heavy mineral analysis on Cretaceous and Eocene strata from the northern South China Sea and Palawan to constrain the Late Mesozoic-Early Cenozoic provenance and paleogeographic evolution of the region testing possible connection between the Palawan Continental Terrane and the northern South China Sea margin. In addition to a revision of the regional stratigraphic framework using the youngest zircon U-Pb ages, these analyses show that while the Upper Cretaceous strata from the Palawan Continental Terrane are characterized by a dominance of zircon with crystallization ages clustering around the Cretaceous, the Eocene strata feature a large range of zircon ages and a new mineral group of rutile, anatase, and monazite. On the one hand, this change of sediment compositions seems to exclude the possibility of a latest Cretaceous drift of the Palawan Continental Terrane in response to the Proto-South China Sea opening as previously inferred. On the other hand, the zircon age signatures of the Cretaceous-Eocene strata from the Palawan Continental Terrane are largely comparable to those of contemporary samples from the northeastern South China Sea region, suggesting a possible conjugate relationship between the Palawan Continental Terrane and the eastern Pearl River Mouth Basin. Thus, the Palawan Continental

The effect of thermal resetting and recrystallisation on white mica 40Ar/39Ar ages during retrograde metamorphism on Syros, Greece

NASA Astrophysics Data System (ADS)

Uunk, Bertram; Wijbrans, Jan; Brouwer, Fraukje

2015-04-01

White mica 40Ar/39Ar dating is a proven powerful tool for constraining timing of metamorphism, deformation and exhumation. However, in high-pressure metamorphic rocks, dating often results in wide age ranges which are not in agreement with constraints from other isotopic systems, indicating that geological and chemical processes complicate straightforward 40Ar/39Ar dating. In this research project, white mica ages from rocks of the Cycladic Blueschist Unit on Syros, Greece with contrasting rheology and strain mechanisms are compared, in order to better understand the role of deformation, recrystallization and fluid flow on 40Ar/39Ar ages of white mica during retrograde metamorphism. Resulting ages vary along different sections on the island, inconsistent with other isotopic constraints on eclogite-blueschist metamorphism (55-50 Ma) and greenschist overprinting (41-30 Ma). Two end-member models are possible: 1) Results represent continuous crystallization of white mica while moving from blueschist to greenschist conditions in the metamorphic P-T loop, or 2) white mica equilibrated in eclogite-blueschist conditions and their diffusion systematics were progressively perturbed during greenschist overprinting. The single grain fusion analyses yielded contrasting age distributions, which indicate contrasts in degree of re-equilibration during retrograde metamorphism. Step wise heating of larger grain populations resulted in flat plateau shapes, providing no evidence for partial resetting. Electron microprobe measurements of Si per formula unit, as a proxy for pressure during crystallisation, do not explain age variation within sections or on the island scale. The previously unreported north-south age trend and age ranges per sample, as shown only in the 40Ar/39Ar system of the metapelitic and marble lithologies, contains key information that will allow us to test between different scenarios for age formation. Excess argon infiltration at this stage seems to have been of

The role of high-pressure metamorphic rocks in collisional processes with a microplate involved

NASA Astrophysics Data System (ADS)

Massonne, Hans-Joachim

2013-04-01

High-pressure (HP: p >10 kbar) rocks, especially easily recognizable eclogite lenses, are markers of a collision of major continental plates in Phanerozoic times, but how about a collison with a microplate? To answer this question, petrological studies were undertaken on garnet-bearing metamorphic rocks. Especially pressure (P) - temperature (T) pseudosections were calculated to reconstruct the P-T path of such rocks. Areas in the Andes and their eastern foreland (Argentina, Ecuador) and the Carboniferous realm of western and central Europe were studied, where microplates either had collided with the South American plate or had been located between colliding Laurussia and Gondwana. The following features resulted: (1) laterally extended zones of HP rocks mark collisional sutures, but eclogite lenses are virtually absent; (2) these HP rocks are dominantly metapelites which have experienced pressures as high as 1.2 to 1.5 GPa; (3) these pressures were reached between 450 to 550°C, followed by a P release at increasing T; (4) the T peak in the range of 500-650°C at P between 0.5 and 0.8 GPa is often characterized by the blastesis of plagioclase occasionally together with staurolite; (5) this event was pre-dated by two deformational events. The second deformation occurred during the early exhumation. Considering the regional geology of the study areas, these features are interpreted as follows: Prior to the collision a basin, extending over at most some hundred kilometers perpendicular to the basin axis, existed between the colliding microplate and the major plate. Eventually, a rifting event had caused the separation of the microplate from the major continental plate. The basin, which was opened by this event and filled with sediments, could have developed further to a back-arc basin. Then, the extensional regime turned to a compressional one. During compression the basin sediments on top of thinned continental crust were buried beneath the overriding major plate

Unraveling the Switch from Subduction to Exhumation within a Collisional Orogen: Split-stream U-Pb and Trace-element Results from the Western Gneiss Region, Norway (Invited)

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Whitney, D. L.; Teyssier, C. P.; Fossen, H.; Desormeau, J. W.; Jessen, B.

2013-12-01

During continental collision, crustal material may be subducted to great depths and subsequently exhumed. Ultrahigh-pressure (UHP) terranes preserve a record of the subduction of crustal material during suturing of colliding continents and the exhumation of this material during extension and, in some cases, collapse of the orogen. The UHP rocks of the Western Gneiss Region (WGR), Norway, resulted from the collision of Baltica with Laurentia during the final stages of the Caledonian orogeny. The WGR represents one of the two largest UHP terranes on Earth and consists of a UHP eclogite-bearing domain south of the Møre-Trøndelag strike-slip fault and a HP mafic granulite-bearing domain north of the fault. At least some of the HP granulite is overprinted eclogite. To evaluate the metamorphic and structural relationship of mafic rocks and associated migmatite in both regions, we obtained LA-ICP-MS U-Pb dates and trace-element analyses for zircon from a variety of textural types of leucosome associated with mafic layers and lenses. Five leucosomes within highly deformed migmatite in the HP granulite complex on the Roan Peninsula reveal U-Pb lower-intercept ages from ca. 405 to 409 Ma and upper-intercept Proterozoic dates. These zircons have distinct trace-elements patterns: all of the zircons that yield Proterozoic dates have overall much higher REE concentrations, a more significant negative Eu anomaly (-0.3 to -0.7) and steeper HREE patterns (Lu/Dy = 5-12). In comparison, the Caledonian zircons reveal flatter Eu anomalies (-0.3 to 0.2) and less steep HREE patterns (Lu/Dy = 2-7), although the individual patterns do not seem to correlate with age. The Caledonian zircon patterns suggest crystallization at high-pressures and are distinct from the inherited Proterozoic grains. Similar results were obtained from zircon rims extracted from layer-parallel to crosscutting leucosomes from the UHP domain. Trace elements in zircon in these samples record the transition from high-pressure

Implementation of high slurry concentration and sonication to pack high-efficiency, meter-long capillary ultrahigh pressure liquid chromatography columns.

PubMed

Godinho, Justin M; Reising, Arved E; Tallarek, Ulrich; Jorgenson, James W

2016-09-02

Slurry packing capillary columns for ultrahigh pressure liquid chromatography is complicated by many interdependent experimental variables. Previous results have suggested that combination of high slurry concentration and sonication during packing would create homogeneous bed microstructures and yield highly efficient capillary columns. Herein, the effect of sonication while packing very high slurry concentrations is presented. A series of six, 1m×75μm internal diameter columns were packed with 200mg/mL slurries of 2.02μm bridged-ethyl hybrid silica particles. Three of the columns underwent sonication during packing and yielded highly efficient separations with reduced plate heights as low as 1.05. Copyright © 2016 Elsevier B.V. All rights reserved.

Archean metamorphic sequence and surfaces, Kangerdlugssuaq Fjord, East Greenland

NASA Technical Reports Server (NTRS)

Kays, M. A.

1986-01-01

The characteristics of Archean metamorphic surfaces and fabrics of a mapped sequence of rocks older than about 3000 Ma provide information basic to an understanding of the structural evolution and metamorphic history in Kangerdlugssuaq Fjord, east Greenland. This information and the additional results of petrologic and geochemical studies have culminated in an extended chronology of Archean plutonic, metamorphic, and tectonic events. The basis for the chronology is considered, especially the nature of the metamorphic fabrics and surfaces in the Archean sequence. The surfaces, which are planar mineral parageneses, may prove to be mappable outside Kangerdlugssuaq Fjord, and if so, will be helpful in extending the events that they represent to other Archean sequences in east Greenland. The surfaces will become especially important reference planes if the absolute ages of their metamorphic assemblages can be determined in at least one location where strain was low subsequent to their recrystallization. Once an isochron is obtained, the dynamothermal age of the regionally identifiable metamorphic surface is determined everywhere it can be mapped.

Ultra-High Pressure Homogenization improves oxidative stability and interfacial properties of soy protein isolate-stabilized emulsions.

PubMed

Fernandez-Avila, C; Trujillo, A J

2016-10-15

Ultra-High Pressure Homogenization (100-300MPa) has great potential for technological, microbiological and nutritional aspects of fluid processing. Its effect on the oxidative stability and interfacial properties of oil-in-water emulsions prepared with 4% (w/v) of soy protein isolate and soybean oil (10 and 20%, v/v) were studied and compared to emulsions treated by conventional homogenization (15MPa). Emulsions were characterized by particle size, emulsifying activity index, surface protein concentration at the interface and by transmission electron microscopy. Primary and secondary lipid oxidation products were evaluated in emulsions upon storage. Emulsions with 20% oil treated at 100 and 200MPa exhibited the most oxidative stability due to higher amount of oil and protein surface load at the interface. This manuscript addresses the improvement in oxidative stability in emulsions treated by UHPH when compared to conventional emulsions. Copyright © 2016 Elsevier Ltd. All rights reserved.

The problem of the age and structural position of the Blyb metamorphic complex (Fore Range zone, Great Caucasus) granitoids.

NASA Astrophysics Data System (ADS)

Kamzolkin, Vladimir; Latyshev, Anton; Ivanov, Stanislav

2016-04-01

The Blyb metamorphic complex (BMC) of the Fore Range zone is one of the most high-grade metamorphosed element of the Great Caucasus fold belt. Determination of the timing and the mechanism of formation of the Fore Range fold-thrust structures are not possible without investigation of the BMC located at the basement of its section. At the same time, the conceptions about its structure and age are outdated and need revision. Somin (2011) determined the age of the protolith and metamorphism of the Blyb complex as the Late Devonian - Early Carboniferous. We have recently shown that the BMC has not the dome, as previously thought, but nappe structure (Vidjapin, Kamzolkin, 2015), and is metamorphically coherent with the peak metamorphism pressures up to 22 kbar (Kamzolkin et al., 2015; Konilov et al., 2013). Considering the age and structure of the Blyb complex it is necessary to revise the age of granitoid intrusions and their relations with gneisses and schists, which constitute the main part of the section of the complex. Most authors (Gamkrelidze, Shengelia, 2007; Lavrischev, 2002; Baranov, 1967) adheres to Early Paleozoic age of intrusives, which is doubtful, considering the younger age of metamorphic rocks. We suppose, that the intrusive bodies broke through a BMC nappe structure during the exhumation of the complex (Perchuk, 1991) at the Devonian - Carboniferous boundary. Seemingly, the massive monzodiorites body (Lavrischev, 2002), intruding garnet-muscovite schists and amphibolite gneisses of the Blyb complex and cut by the Main Caucasian fault (MCF), are younger. Given the timing of termination of the MCF movement activity as the Middle Jurassic (Greater Caucasus..., 2005), their age should be in the Early Carboniferous - Middle Jurassic interval. At the same time, on the modern geological map (Lavrischev, 2002) monzodiorites body is assigned to the Middle Paleozoic. The study of the BMC granitoids and monzodiorites will help in determining of the mechanism and

Intermediate P/T-type regional metamorphism of the Isua Supracrustal Belt, southern west Greenland: The oldest Pacific-type orogenic belt?

NASA Astrophysics Data System (ADS)

Arai, Tatsuyuki; Omori, Soichi; Komiya, Tsuyoshi; Maruyama, Shigenori

2015-11-01

The 3.7-3.8 Ga Isua Supracrustal Belt (ISB), southwest Greenland, might be the oldest accretionary complex on Earth. Regional metamorphism of the ISB has a potential to constrain the tectonothermal history of the Earth during the Eoarchean. Chemical and modal analyses of metabasite in the study area (i.e., the northeast part of the ISB) show that the metamorphic grade increases from greenschist facies in the northern part of the study area to amphibolite facies in the southern part. To determine the precise metamorphic P-T ranges, isochemical phase diagrams of minerals of metabasite were made using Perple_X. A synthesis of the estimated metamorphic P-T ranges of the ISB indicates that both the metamorphic pressure and temperature increase systematically to the south in the study area from 3 kbar and 380 °C to 6 kbar and 560 °C. The monotonous metamorphic P-T change suggests that the northeast part of the ISB preserves regional metamorphism resulting from the subduction of an accretionary complex although the ISB experienced metamorphic overprints during the Neoarchean. Both the presence of the regional metamorphism and an accretionary complex having originating at subduction zone suggest that the ISB may be the oldest Pacific-type orogenic belt. The progressive metamorphism can be considered as a record of intermediate-P/T type geothermal gradient at the subduction zone in the Eoarchean. Intermediate-P/T type geothermal gradient is typical at the current zones of subducting young oceanic crust, such as in the case of the Philippine Sea Plate in the southwest part of Japan. Considering the fact that almost all metamorphisms in the Archean are greenschist-amphibolite facies, the intermediate-P/T type geothermal gradient at the ISB might have been worldwide in the Archean. This would indicate that the subduction of young micro-plates was common because of the vigorous convection of hot mantle in the Archean.

Timing of metamorphism and exhumation in the Nordøyane ultra-high-pressure domain, Western Gneiss Region, Norway: New constraints from complementary CA-ID-TIMS and LA-MC-ICP-MS geochronology

NASA Astrophysics Data System (ADS)

Butler, J. P.; Jamieson, R. A.; Dunning, G. R.; Pecha, M. E.; Robinson, P.; Steenkamp, H. M.

2018-06-01

We present the results of a combined CA-ID-TIMS and LA-MC-ICP-MS U-Pb geochronology study of zircon and associated rutile and titanite from the Nordøyane ultra-high-pressure (UHP) domain in the Western Gneiss Region (WGR) of Norway. The dated samples include 4 eclogite bodies, 2 host-rock migmatites, and 2 cross-cutting pegmatites and leucosomes, all from the island of Harøya. Zircon from a coesite eclogite yielded an age of ca. 413 Ma, interpreted as the time of UHP metamorphism in this sample. Zircon data from the other eclogite bodies yielded metamorphic ages of ca. 413 Ma, 407 Ma, and 406 Ma; zircon trace-element data associated with 413 Ma and 407 Ma ages are consistent with eclogite-facies crystallization. In all of the eclogites, U-Pb dates from zircon cores, interpreted as the times of protolith crystallization, range from ca. 1680-1586 Ma, consistent with Gothian ages from orthogneisses in Nordøyane and elsewhere in the WGR. A zircon core age of ca. 943 Ma from one sample agrees with Sveconorwegian ages of felsic gneisses and pegmatites in the western part of the area. Migmatites hosting the eclogite bodies yielded zircon core ages of ca. 1657-1591 Ma and rim ages of ca. 395-392 Ma, interpreted as the times of Gothian protolith formation and Scandian partial melt crystallization, respectively. Pegmatite in an eclogite boudin neck yielded a crystallization age of ca. 388 Ma, interpreted as the time of melt crystallization. Rutile and titanite from 3 samples (an eclogite and two migmatites) yielded concordant ID-TIMS ages of 378-376 Ma. The results are similar to existing U-Pb data from other Nordøyane eclogites (415-405 Ma). In combination with previous pressure-temperature data from the coesite eclogite, these ages indicate that peak metamorphic conditions of 3 GPa/760 °C were reached ca. 413 Ma, followed by decompression to 1 GPa/810 °C by ca. 397 Ma and cooling below ca. 600 °C by ca. 375 Ma. The results are compatible with protracted UHP

Timing and duration of garnet granulite metamorphism in magmatic arc crust, Fiordland, New Zealand

USGS Publications Warehouse

Stowell, H.; Tulloch, A.; Zuluaga, C.; Koenig, A.

2010-01-01

Pembroke Granulite from Fiordland, New Zealand provides a window into the mid- to lower crust of magmatic arcs. Garnet Sm-Nd and zircon U-Pb ages constrain the timing and duration of high-P partial melting that produced trondhjemitic high Sr/Y magma. Trace element zoning in large, euhedral garnet is compatible with little post growth modification and supports the interpretation that garnet Sm-Nd ages of 126.1??2.0 and 122.6??2.0. Ma date crystal growth. Integration of the garnet ages with U-Pb zircon ages elucidates a history of intrusion(?) and a protracted period of high-temperature metamorphism and partial melting. The oldest zircon ages of 163 to 150. Ma reflect inheritance or intrusion and a cluster of zircon ages ca. 134. Ma date orthopyroxene-bearing mineral assemblages that may be magmatic or metamorphic in origin. Zircon and garnet ages from unmelted gneiss and garnet reaction zones record garnet granulite facies metamorphism at 128 to 126. Ma. Peritectic garnet and additional zircon ages from trondhjemite veins and garnet reaction zones indicate that garnet growth and partial melting lasted until ca. 123. Ma. Two single fraction garnet ages and young zircon ages suggest continued high-temperature re-equilibration until ca. 95. Ma. Phase diagram sections constrain orthopyroxene assemblages to <0.6 GPa @ 650??C, peak garnet granulite facies metamorphic conditions to 680-815??C @ 1.1-1.4. GPa, and a P-T path with a P increase of???0.5. GPa. These sections are compatible with water contents???0.28wt.%, local dehydration during garnet granulite metamorphism, and <0.3. GPa P increases during garnet growth. Results demonstrate the utility of integrated U-Pb zircon and Sm-Nd garnet ages, and phase diagram sections for understanding the nature, duration, and conditions of deep crustal metamorphism and melting. Geochronologic and thermobarometric data for garnet granulite indicate that thickening of arc crust, which caused high-pressure metamorphism in northern

Workshop on Techtonic Evolution of Greenstone Belts

NASA Technical Reports Server (NTRS)

Dewit, M. J. (Editor); Ashwal, Lewis D. (Editor)

1986-01-01

Topics addressed include: greenstone belt externalities; boundaries; rock terranes; synthesis and destiny; tectonic evolution; rock components and structure; sedimentology; stratigraphy; volcanism; metamorphism; and geophysics.

Felsic granulite with layers of eclogite facies rocks in the Bohemian Massif; did they share a common metamorphic history?

NASA Astrophysics Data System (ADS)

Jedlicka, Radim; Faryad, Shah Wali

2017-08-01

High pressure granulite and granulite gneiss from the Rychleby Mountains in the East Sudetes form an approximately 7 km long and 0.8 km wide body, which is enclosed by amphibolite facies orthogneiss with a steep foliation. Well preserved felsic granulite is located in the central part of the body, where several small bodies of mafic granulite are also present. In comparison to other high pressure granulites in the Bohemian Massif, which show strong mineral and textural re-equilibration under granulite facies conditions, the mafic granulite samples preserve eclogite facies minerals (garnet, omphacite, kyanite, rutile and phengite) and their field and textural relations indicate that both mafic and felsic granulites shared common metamorphic history during prograde eclogite facies and subsequent granulite facies events. Garnet from both granulite varieties shows prograde compositional zoning and contains inclusions of phengite. Yttrium and REEs in garnet show typical bell-shaped distributions with no annular peaks near the grain rims. Investigation of major and trace elements zoning, including REEs distribution in garnet, was combined with thermodynamic modelling to constrain the early eclogite facies metamorphism and to estimate pressure-temperature conditions of the subsequent granulite facies overprint. The first (U)HP metamorphism occurred along a low geothermal gradient in a subduction-related environment from its initial stage at 0.8 GPa/460 °C and reached pressures up to 2.5 GPa at 550 °C. The subsequent granulite facies overprint (1.6-1.8 GPa/800-880 °C) affected the rocks only partially; by replacement of omphacite into diopside + plagioclase symplectite and by compositional modification of garnet rims. The mineral textures and the preservation of the eclogite facies prograde compositional zoning in garnet cores confirm that the granulite facies overprint was either too short or too faint to cause recrystallisation and homogenisation of the eclogite

EFFECT OF ULTRA-HIGH PRESSURE HOMOGENIZATION ON THE INTERACTION BETWEEN BOVINE CASEIN MICELLES AND RITONAVIR

PubMed Central

Corzo-Martínez, M.; Mohan, M.; Dunlap, J.; Harte, F.

2014-01-01

Purpose The aim of this work was to develop a milk-based powder formulation appropriate for pediatric delivery of ritonavir (RIT). Methods Ultra-high pressure homogenization (UHPH) at 0.1, 300 and 500 MPa was used to process a dispersion of pasteurized skim milk (SM) and ritonavir. Loading efficiency was determined by RP-HPLC-UV; characterization of RIT:SM systems was carried out by apparent average hydrodynamic diameter and rheological measurements as well as different analytical techniques including Trp fluorescence, UV spectroscopy, DSC, FTIR and SEM; and delivery capacity of casein micelles was determined by in vitro experiments promoting ritonavir release. Results Ritonavir interacted efficiently with milk proteins, especially, casein micelles, regardless of the processing pressure; however, results suggest that, at 0.1 MPa, ritonavir interacts with caseins at the micellar surface, whilst, at 300 and 500 MPa, ritonavir is integrated to the protein matrix during UHPH treatment. Likewise, in vitro experiments showed that ritonavir release from micellar casein systems is pH dependent; with a high retention of ritonavir during simulated gastric digestion and a rapid delivery under conditions simulating the small intestine environment. Conclusions Skim milk powder, especially, casein micelles are potentially suitable and efficient carrier systems to develop novel milk-based and low-ethanol powder formulations of ritonavir appropriate for pediatric applications. PMID:25270571

The Khida terrane - Geology of Paleoproterozoic rocks in the Muhayil area, eastern Arabian Shield, Saudi Arabia

USGS Publications Warehouse

Stoeser, D.B.; Whitehouse, M.J.; Stacey, J.S.

2001-01-01

The bulk of the Arabian Shield of Saudi Arabia is underlain by Neoproterozoic terranes of oceanic affinity that were accreted during Pan-African time (about 680- 640Ma). Geologicalmappingandisotopicinvestigations during the 1980’s,however, provided the first evidence for Paleoproterozoic continental crust within the east- central part of the shield in Saudi Arabia. These studies delineated an older basement domain, herein referred to as the Khida terrane (Fig. l), which is defined as that part of the southern Afif composite terrane underlain by Paleoproterozoicto Archean continental crust (Stoeser and Stacey, 1988). The isotopic and geochronologic work to support our current studies within the Khida terrane are discussed in a companion abstract (Whitehouse et al., this volume). The regional geology and geochronology of the region has been summarized in detail by Johnson (1996). The current study is based on the continued use of samples previously collected in the Khida area by the authors and others as well as new field work conducted by us in 1999. This work further defines the occurrence of late Paleoproterozoic rocks at Jabal Muhayil, which is located at the eastern margin of the exposed terrane (Fig. 1). Our isotopic work is at an early stage and this abstract partly relates geologic problems that remain to be resolved. 

The ophiolitic North Fork terrane in the Salmon River region, central Klamath Mountains, California

USGS Publications Warehouse

Ando, C.J.; Irwin, W.P.; Jones, D.L.; Saleeby, J.B.

1983-01-01

The North Fork terrane is an assemblage of ophiolitic and other oceanic volcanic and sedimentary rocks that has been internally imbricated and folded. The ophiolitic rocks form a north-trending belt through the central part of the region and consist of a disrupted sequence of homogeneous gabbro, diabase, massive to pillowed basalt, and interleaved tectonitic harzburgite. U-Pb zircon age data on a plagiogranite pod from the gabbroic unit indicate that at least this part of the igneous sequence is late Paleozoic in age.The ophiolitic belt is flanked on either side by mafic volcanic and volcaniclastic rocks, limestone, bedded chert, and argillite. Most of the chert is Triassic, including much of Late Triassic age, but chert with uncertain stratigraphic relations at one locality is Permian. The strata flanking the east side of the ophiolitic belt face eastward, and depositional contacts between units are for the most part preserved. The strata on the west side of the ophiolitic belt are more highly disrupted than those on the east side, contain chert-argillite melange, and have unproven stratigraphic relation to either the ophiolitic rocks or the eastern strata.Rocks of the North Fork terrane do not show widespread evidence of penetrative deformation at elevated temperatures, except an early tectonitic fabric in the harzburgite. Slip-fiber foliation in serpentinite, phacoidal foliation in chert and mafic rocks, scaly foliation in argillite, and mesoscopic folds in bedded chert are consistent with an interpretation of large-scale anti-formal folding of the terrane about a north-south hinge found along the ophiolitic belt, but other structural interpretations are tenable. The age of folding of North Fork rocks is constrained by the involvement of Triassic and younger cherts and crosscutting Late Jurassic plutons. Deformation in the North Fork terrane must have spanned a short period of time because the terrane is bounded structurally above and below by Middle or Late

Isotopic and geothermometric constraints on the structural and metamorphic evolution of Homestake gold deposit, Black Hills, South Dakota (USA)

NASA Astrophysics Data System (ADS)

Terry, M.; Dahl, P.; Frei, R.

2003-04-01

The Homestake Deposit, located in the northern Black Hills and host for 40 million ounces of gold, shows evidence for extensive remobilization of gold related to regional metamorphism deformation associated with the Early Proterozoic assembly of supercontinent Laurentia. Field and petrographic evidence for gold remobilization includes the occurrence of abundant quartz veins associated with selvages of chlorite-siderite-ankerite-pyrrhotite-arsenopyrite-gold in the Homestake Fm. The deposit is located on the western limb of a major anticlinorium that coincides with a vertical N-S-striking garnet isograd, and garnet-biotite geothermometry of metapelites sampled across the anticlinorium indicates a steep metamorphic field gradient of 150^oC/km (east side warmer). This gradient is mirrored by a pronounced fractionation of oxygen isotopes observed in the vein quartz, with δ18O ranging from 10 to 18 ppm. The isograd is parallel with a major N-S-striking shear zone, and kinematic indicators predominantly indicate oblique sinistral motion with east-side up. Garnet was separated from a subsurface sample of the Homestake Fm. collected from the nose of the so-called "main ledge" synform and subjected to Pb stepwise leaching (PbSL) to determine the age of garnet growth and thus metamorphism. PbSL analysis revealed a 207Pb/206Pb age of 1746 ± 10 Ma (± 2σ). Recent work in the southern Black Hills indicates that almandine does not contain sufficient Pb to be dated directly by this method; instead, the PbSL result represents the bulk age of abundant allanite inclusions observed in the garnet. Thus, 1746 Ma is interpreted as a maximum age of prograde garnet growth during regional thermotectonism. Mineral assemblages from selvages in Main Ledge indicate that mineralization occurred at or after peak metamorph, which indicates that 1746 Ma also represents a maximum age for gold remobilization. A minimum 1715 Ma age of these events is indicated by published ages of post

Two possibilities for New Siberian Islands terrane tectonic history during the Early Paleozoic based on paleomagnetic data

NASA Astrophysics Data System (ADS)

Metelkin, Dmitry V.; Chernova, Anna I.; Vernikovsky, Valery A.; Matushkin, Nikolay Yu.

2017-04-01

The New Siberian Islands (NSI), located in the East Siberian Sea in the junction region of various structural elements, are a key target for deciphering the tectonic evolution of the Eastern Arctic. In recent years, we went on several expeditions and gathered an extensive geological material for this territory. Among other things, we could prove that the basement of the De Long and Anjou archipelagos structures is Precambrian and the overlying Paleozoic sections formed within the same terrane. The form of the boundaries of the NSI terrane are actively debated and are probably continued from the Lyakhovsky islands in the south-west to the southern parts of the submerged Mendeleev Ridge, for which there is increasing evidence of continental crust. Today there are several models that interpret the Paleozoic-Mesozoic tectonic history and structural affiliation of the NSI terrane. Some propose that the Paleozoic sedimentary section formed in a passive margin setting of the Siberian paleocontinent. Others compare its history with marginal basins of the Baltica and Laurentia continents or consider the NSI terrane as an element of the Chukotka-Alaska microplate. These models are mainly based on results of paleobiogeographical and lithological-facies analyses, including explanations of probable sources for detrital zircons. Our paleomagnetic research on sedimentary, volcanogenic-sedimentary and igneous rocks of the Anjou (Kotelny and Bel'kovsky islands) and De Long (Bennett, Jeannette and Henrietta islands) archipelagos let us calculate an apparent polar wander path for the early Paleozoic interval of geological history, which allows us to conclude that the NSI terrane could not have been a part of the continental plates listed above, but rather had active tectonic boundaries with them. Our paleomagnetic data indicate that the NSI terrane drifted slowly and steadily in the tropical and subtropical regions no higher than 40 degrees. However, the main uncertainty for the

Future accreted terranes: a compilation of island arcs, oceanic plateaus, submarine ridges, seamounts, and continental fragments

NASA Astrophysics Data System (ADS)

Tetreault, J. L.; Buiter, S. J. H.

2014-12-01

Allochthonous accreted terranes are exotic geologic units that originated from anomalous crustal regions on a subducting oceanic plate and were transferred to the overriding plate by accretionary processes during subduction. The geographical regions that eventually become accreted allochthonous terranes include island arcs, oceanic plateaus, submarine ridges, seamounts, continental fragments, and microcontinents. These future allochthonous terranes (FATs) contribute to continental crustal growth, subduction dynamics, and crustal recycling in the mantle. We present a review of modern FATs and their accreted counterparts based on available geological, seismic, and gravity studies and discuss their crustal structure, geological origin, and bulk crustal density. Island arcs have an average crustal thickness of 26 km, average bulk crustal density of 2.79 g cm-3, and three distinct crustal units overlying a crust-mantle transition zone. Oceanic plateaus and submarine ridges have an average crustal thickness of 21 km and average bulk crustal density of 2.84 g cm-3. Continental fragments presently on the ocean floor have an average crustal thickness of 25 km and bulk crustal density of 2.81 g cm-3. Accreted allochthonous terranes can be compared to these crustal compilations to better understand which units of crust are accreted or subducted. In general, most accreted terranes are thin crustal units sheared off of FATs and added onto the accretionary prism, with thicknesses on the order of hundreds of meters to a few kilometers. However, many island arcs, oceanic plateaus, and submarine ridges were sheared off in the subduction interface and underplated onto the overlying continent. Other times we find evidence of terrane-continent collision leaving behind accreted terranes 25-40 km thick. We posit that rheologically weak crustal layers or shear zones that were formed when the FATs were produced can be activated as detachments during subduction, allowing parts of the FAT

Modulation of Crustal Faulting in the Crescent Terrane by the Volume of Underthrust Accretionary Complex Along the Washington Cascadia Forearc

NASA Astrophysics Data System (ADS)

Brocher, T. M.

2017-12-01

Amphibious seismic experiments reveal widespread underthrusting of Cascadia accretionary rocks beneath basalts of the Crescent terrane, a large igneous province in the Washington forearc. Along margin variations in the volumes of the underthrust accretionary rocks appear to modulate the faulting within the overlying Crescent terrane, which hosts nearly all of the seismicity in the Washington forearc: the underlying accretionary rocks appear to deform aseismically. The underthrusting and underplating of large volumes of accretionary rocks on the Olympic Peninsula have uplifted and completely eroded a significant volume of the Crescent terrane, affecting the load-bearing strength of the forearc. I propose that as a consequence, the remnant Crescent terrane is actively deforming, as evidenced by the concentrated seismicity within it beneath Puget Lowland. This seismicity, focal mechanisms, fault geometries, and seismic tomography indicate that clockwise rotation and north-south compression of the forearc crust inferred from GPS data are accommodated by numerous thrust and strike slip faults in the remnant Crescent terrane. In addition to the spatial association between the erosion of the Crescent terrane on the Olympic Peninsula and the crustal faulting beneath Puget Lowland, support for the interpretation that the two are related also derives from the temporal coincidence between the mid to late Miocene uplift of the Crescent terrane on the peninsula and the mid-Miocene initiation of the thrust faulting in the lowland. In contrast, the underthrusting and underplating of lower volumes of accretionary rocks in the Washington forearc south of the Olympic Peninsula correlate with lower rates of crustal seismicity. These lower volumes of accretionary rocks have not caused the removal of a significant fraction of the Crescent terrane, resulting in a stronger, more structurally coherent Crescent terrane that deforms at lower rate than to the north.

Fi Investigations On Hp-Rocks From The Lower Engadine Window New Insights On Its Late Tectono-Metamorphic Evolution

NASA Astrophysics Data System (ADS)

Bertle, R. J.; Götzinger, M. A.; Koller, F.

2003-04-01

the host rock (blueschist) epidote-clinozoisite cristalls. Futheron amphibole is visible. It is common at the base of the vein quarz and decreases towards the middle of the vein. FI are H2O-rich and indicate high pressure of trapping. Quarzes from the upper most part of the Zone of Pfunds from S of Zeblasjoch (W of Samnaun Dorf) show two main groups of primary FI which could be differentiated at room temperature: homogenous FI and such with a bubble. All FI were frozen at max. temperatures of ca. -56 ^oC. Bigger FI show cracking due to cristallisation pressure (build up of "wings"), the cracks however closed again during heating, so that the FI remained closed. Initial melting started between -20 ^oC (first recristallisation signs) and -9 ^oC, final melting was observable at -1 ^oC to 0 ^oC. Then the FI was a.) homogenous or b.) showed a bubble. Homogenisation Temp. of the inclusions with bubble were in the range of 70 to 150 ^oC , most of them between 70 and 80 ^oC and 110 - 125 ^oC. The data indicate a more or less pure H_2O-system for the FI under high pressure. Assuming a cristallisation temperature of the cristalls of about 200 to 250 ^oC and a density of the FI between 0,97 and 1,0 g/cm^3 pressures of 2,5 to 4,5 Kbar are indicated. The same P-T-conditions (same chemistry and melting & homog. Temp.) could be derived from FI in quarz from the Salaaser Kopf (Idalpe) for the late metamorphic evolution of the Fimber unit, indicating that the late metamorphic history of both units is the same. It is concluded that opening of the veins and first cristallisation of vein quarz corresponds to the first signs of updoming of the Engadine anticlinal structure. Updoming of the anticline started when the whole nappe stack was covered by the Austroalpine nappes. Therefore FI show such high pressures for trapping of the fluid. Acknowledgements: Data partly result from FWF-project P. 15278 "Bündnerschieferakkretion in the westlichen Ostalpen". Financal support is greatly

Paleomagnetic study of the Eastern Klamath terrane, California, and implications for the tectonic history of the Klamath Mountains Province

USGS Publications Warehouse

Mankinen, Edward A.; Irwin, William P.; Gromme, C. Sherman

1989-01-01

Paleomagnetic study of Permian through Jurassic volcanic and sedimentary strata of the Eastern Klamath terrane has shown the remanent magnetization of many of these rocks to be prefolding and most likely primary. Similarities in magnetic declinations recorded by coeval strata over a broad area are consistent with the hypothesis that the terrane, in general, has behaved as a single rigid block. Paleomagnetic data indicate that the volcanic island arc represented by this terrane, the nucleus of the province, was facing toward the present southwest during late Paleozoic time, although its orientation during earlier periods is unknown. Whether the arc was separated from the North American craton by a small marginal basin or originated far offshore cannot be determined from paleomagnetic data. The declination anomalies for both Permian and Triassic strata are similar (average = 106° ± 12°), so we infer that clockwise rotation of the late Paleozoic arc did not begin until latest Triassic or earliest Jurassic time. The arc may have completed its initial rotation with respect to stable North America by Middle Jurassic time. After some retrograde motion, the arc was again facing west by the Late Jurassic, by which time some of the more westerly terranes of the province had become attached to the Eastern Klamath terrane. The composite Klamath Mountains terranes continued to rotate until the final 60° of clockwise rotation was nearly complete by the Early Cretaceous. Coincidence of the waning stages of rotation, at about 136 Ma, with the beginning of deposition of the basal Great Valley sequence onto the Klamath basement probably represents the completion of accretion of the Klamath Mountains terranes to the North American continent. Nearly all the rotation occurred while the Klamath Mountains terranes were part of a converging oceanic plate, with only about 20° of rotation in mid‐Tertiary time during Basin and Range extension. No data currently available show evidence

Radiolarian biostratigraphy of the Quinn River Formation, Black Rock terrane, north-central Nevada: correlations with eastern Klamath terrane geology

USGS Publications Warehouse

Blome, C.D.; Reed, K.M.

1995-01-01

The Quinn River Formation, Black Rock terrane, Quinn River Crossing, is one of the few Nevadan sections of Permian and Triassic strata that are unaffected by Sonoman deformation. The formation consists of: 1) a basal tuff overlain by limestone and ferruginous dolomite, 2) interbedded radiolarian-bearing chert and argillite, 3) siltstone and carbonaceous shale, and 4) partly volcaniclastic rocks. All but the uppermost (barren) chert samples contain Late Permian radiolarian taxa. These radiolarians suggest that early Wordian conodonts reported from near the top of the chert and argillite unit are reworked. Poorly preserved Early(?) or Middle triassic radiolarians and Middle Triassic ammonites and pectenacid bivalves from the middle part of the volcaniclastic unit indicate the Early Triassic deposition cannot be documented at Quinn River. The ages of the Quinn River brachiopod, conodont, and radiolarian faunas resemble those of the Dekkas and Pit Formations, eastern Klamath terrane, northern California. The analogous Quinn River and eastern Klamath rock types and faunal ages, as well as similar hiatuses in their stratigraphic records, suggest that they may be lateral equivalents that formed in the same island-arc sedimentary basin. -from Authors

Petrology and zircon U-Pb geochronology of metagabbros from a mafic-ultramafic suite at Aniyapuram: Neoarchean to Early Paleoproterozoic convergent margin magmatism and Middle Neoproterozoic high-grade metamorphism in southern India

NASA Astrophysics Data System (ADS)

Koizumi, Tatsuya; Tsunogae, Toshiaki; Santosh, M.; Tsutsumi, Yukiyasu; Chetty, T. R. K.; Saitoh, Yohsuke

2014-12-01

Several mafic-ultramafic complexes occur within the Palghat-Cauvery Suture Zone (PCSZ) in southern India. The PCSZ is regarded in recent models as the zone along which crustal blocks were amalgamated during the Late Neoproterozoic-Cambrian (550-530 Ma) Gondwana assembly. Here we report petrologic and zircon U-Pb geochronologic data from gabbros associated with the Aniyapuram mafic-ultramafic suite in the central domain of the PCSZ. Geothermobarometry and pseudosection approach in the system NCFMASHTO for the metagabbro (Grt + Cpx + Opx + Hbl + Pl + Qtz + Ilm + Rt) yield peak P-T condition of 9.8-10.6 kbar and 730-790 °C, which was followed by decompression to 6.5-8.0 kbar and ca. 750 °C as inferred from the formation of Opx + Pl symplectite around garnet, probably along a clockwise P-T path. Zircon U-Pb data analyzed by LA-ICP-MS plot along a well-defined discordia with upper and lower intercepts in the concordia at 2436 ± 22 Ma and 731 ± 11 Ma respectively, suggesting Neoarchean-Early Paleoproterozoic magmatic emplacement of the protolith and progressive Pb loss related to the Middle Neoproterozoic (Cryogenian) thermal event (or high-grade metamorphism). These results closely compare with the available Neoarchean magmatic ages of mafic-ultramafic complexes (e.g., Sittampundi, Devanur, Agali Hills, and Kanja Malai) and Middle Neoproterozoic magmatic event (e.g., Manamedu and Kadavur) in the PCSZ and adjacent granulite blocks. The 650 Ma concordia ages obtained from unzoned zircons might indicate the timing of high-grade metamorphism or post-peak hydration event. The P-T conditions obtained from Aniyapuram are significantly lower than the high-pressure and ultrahigh-temperature conditions of the 550-530 Ma final collisional event (P > 14 kbar and T > 950 °C). The Middle Neoproterozoic (ca. 730 Ma or 650 Ma) high-grade metamorphism in Aniyapuram reported for the first time from the PCSZ is possibly associated with magmatism in arc tectonic setting.

Calculation of metamorphic two-dimensional quantum energy system: Application to wetting layer states in InAs/InGaAs metamorphic quantum dot nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seravalli, L.; Trevisi, G.; Frigeri, P.

In this work, we calculate the two-dimensional quantum energy system of the In(Ga)As wetting layer that arises in InAs/InGaAs/GaAs metamorphic quantum dot structures. Model calculations were carried on the basis of realistic material parameters taking in consideration their dependence on the strain relaxation of the metamorphic buffer; results of the calculations were validated against available literature data. Model results confirmed previous hypothesis on the extrinsic nature of the disappearance of wetting layer emission in metamorphic structures with high In composition. We also show how, by adjusting InGaAs metamorphic buffer parameters, it could be possible: (i) to spatially separate carriers confinedmore » in quantum dots from wetting layer carriers, (ii) to create an hybrid 0D-2D system, by tuning quantum dot and wetting layer levels. These results are interesting not only for the engineering of quantum dot structures but also for other applications of metamorphic structures, as the two design parameters of the metamorphic InGaAs buffer (thickness and composition) provide additional degrees of freedom to control properties of interest.« less

Two flysch belts having distinctly different provenance suggest no stratigraphic link between the Wrangellia composite terrane and the paleo-Alaskan margin

USGS Publications Warehouse

Hults, Chad P.; Wilson, Frederic H.; Donelick, Raymond A.; O'Sullivan, Paul B.

2013-01-01

The provenance of Jurassic to Cretaceous flysch along the northern boundary of the allochthonous Wrangellia composite terrane, exposed from the Lake Clark region of southwest Alaska to the Nutzotin Mountains in eastern Alaska, suggests that the flysch can be divided into two belts having different sources. On the north, the Kahiltna flysch and Kuskokwim Group overlie and were derived from the Farwell and Yukon-Tanana terranes, as well as smaller related terranes that were part of the paleo-Alaskan margin. Paleocurrent indicators for these two units suggest that they derived sediment from the north and west. Sandstones are predominantly lithic wacke that contain abundant quartz grains, lithic rock fragments, and detrital mica, which suggest that these rocks were derived from recycled orogen and arc sources. Conglomerates contain limestone clasts that have fossils matching terranes that made up the paleo-Alaskan margin. In contrast, flysch units on the south overlie and were derived from the Wrangellia composite terrane. Paleocurrent indicators for these units suggest that they derived sediment from the south. Sandstones are predominantly feldspathic wackes that contain abundant plagioclase grains and volcanic rock fragments, which suggest these rocks were derived from an arc. Clast compositions in conglomerate south of the boundary match rock types of the Wrangellia composite terrane. The distributions of detrital zircon ages also differentiate the flysch units. Flysch units on the north average 54% Mesozoic, 14% Paleozoic, and 32% Precambrian detrital zircons, reflecting derivation from the older Yukon-Tanana, Farewell, and other terranes that made up the paleo-Alaskan margin. In comparison, flysch units on the south average 94% Mesozoic, 1% Paleozoic, and 5% Precambrian zircons, which are consistent with derivation from the Mesozoic oceanic magmatic arc rocks in the Wrangellia composite terrane. In particular, the flysch units on the south contain a large

The Athabasca Granulite Terrane and Evidence for Dynamic Behavior of Lower Continental Crust

NASA Astrophysics Data System (ADS)

Dumond, Gregory; Williams, Michael L.; Regan, Sean P.

2018-05-01

Deeply exhumed granulite terranes have long been considered nonrepresentative of lower continental crust largely because their bulk compositions do not match the lower crustal xenolith record. A paradigm shift in our understanding of deep crust has since occurred with new evidence for a more felsic and compositionally heterogeneous lower crust than previously recognized. The >20,000-km2 Athabasca granulite terrane locally provides a >700-Myr-old window into this type of lower crust, prior to being exhumed and uplifted to the surface between 1.9 and 1.7 Ga. We review over 20 years of research on this terrane with an emphasis on what these findings may tell us about the origin and behavior of lower continental crust, in general, in addition to placing constraints on the tectonic evolution of the western Canadian Shield between 2.6 and 1.7 Ga. The results reveal a dynamic lower continental crust that evolved compositionally and rheologically with time.

Is Absence of Evidence of UHPM Evidence of Absence: Did Conditions on Earth Before the Ediacaran Period Allow Formation of UHP Rocks but Only Rarely Their Exhumation?

NASA Astrophysics Data System (ADS)

Brown, M.

2008-12-01

UHPM provides petrologic evidence of transport of continental lithosphere to asthenospheric depth and return of some of these materials to crustal depth. The rock record registers UHPM since the Ediacaran Period, and studies of inclusion assemblages in zircon have increased the evidence of UHPM in Phanerozoic orogens and enabled an assessment of the real estate involved. Plots of apparent thermal gradient vs. age of metamorphism and P vs. age of metamorphism reveal two dramatic changes in inferred thermal environment and inferred depth of metamorphism from which continental lithosphere has been recovered during Earth evolution. First, from the Mesoarchean Era to the Neoproterozoic Era, sutures in subduction-to- collision orogens are marked by eclogite and high-pressure granulite metamorphism (characterized by apparent thermal gradients of 750-350 C/GPa). The P of metamorphism in sutures jumped from <1 GPa during the Eoarchean-Paleoarchean up to 2 GPa during the Paleoproterozoic. Second, from the Cryogenian- Ediacaran to the present, many sutures in subduction-to-collision orogens, and sometimes intracratonic sutures in the overriding plate, are marked by UHPM (characterized by apparent thermal gradients of <350 C/GPa) with P of metamorphism >2.7GPa. Given this pattern of secular change to colder apparent thermal gradients in sutures, the recent discovery of diamonds in zircons of crustal paragenesis in Neoarchean sedimentary rocks is surprising. Maybe UHPM has been possible since the Neoarchean but the evidence was rarely exhumed or if exhumed maybe the evidence was rarely preserved? The Appalachian/Caledonian-Variscide-Altaid and the Cimmerian-Himalayan-Alpine orogenic systems were formed by successive closure of short-lived oceans by transfer and suturing of ribbon-continent terranes derived from the Gondwanan side. Subduction of young ocean lithosphere followed by choking of the subduction channel by arc or terrane collision limited transport of water to the

The importance of intracrustal magmatic heat advection in large hot orogens: the Ediacaran-Cambrian ultrahigh-temperature domain of southern Madagascar.

NASA Astrophysics Data System (ADS)

Holder, R. M.; Hacker, B. R.

2016-12-01

Ultrahigh temperature metamorphism (UHTM) represents the thermal extremes of crustal metamorphism and is integral to our understanding of orogenic systems and continental evolution. The relative importance of advective and radiogenic heating in UHTM is often unclear, however, due to retrogression of UHT mineral assemblages and lack of robust chronology. We report the first observation of osumilite, pseudosections, feldspar thermometry, and monazite LASS U-Th-Pb chronology from the Ediacaran-Cambrian Anosyen domain of southern Madagascar to evaluate P-T-time paths and assess the relative importance of advective and radiogenic heating. Pseudosections of an osumilite-bearing assemblage, a garnet-orthopyroxene gneiss, and a garnet-spinel leucogneiss indicate peak conditions of 930-1010 C, 4-6 kbar; 900-950 C, 6-7 kbar; and 970-1000 C, 4.5-5.5 kbar, respectively. Feldspar thermometry indicates T > 915 ± 30 C. These conditions were reached along a low-P prograde path, as implied by cordierite and sillimanite inclusions in garnet. Monazite and zircon U/Th-Pb dating indicates that prograde metamorphism began 625 Ma and lasted 60 Myr. The timing of peak metamorphism is constrained to a 16 ± 2.5 Myr period between 566 ± 2 and 550 ± 1.5 Ma, by monazite inclusions in pseudomorphs after osumilite and monazite from a leucosome in the same outcrop. Peak T was achieved immediately following emplacement of voluminous charnockites (emplaced 1000-1100 C) and related magmas of the Anosyen Batholith. Crystallization of pegmatite dikes, leucosomes, and smaller plutons during cooling lasted from 550 to 510 Ma. This broad thermal history is also recorded by metamorphic monazite Eu/Eu*, which indicate progressive melt generation and extraction prior to 550 Ma followed by melt accumulation and crystallization after 550 Ma. Although the duration of prograde metamorphism is consistent with radiogenic heating models of large hot orogens, peak T was 100-200 C higher in southern Madagascar

New palaeomagnetic data from Argun terrane. Testing its association with Amuria and the Mongol-Okhotsk Ocean

NASA Astrophysics Data System (ADS)

Gordienko, I. V.; Metelkin, D. V.; Vetluzhskikh, L. I.; Mikhaltsov, N. E.; Kulakov, E. V.

2018-06-01

In this study, we present new palaeomagnetic and geological data obtained from Ediacaran and Cambrian sedimentary rocks of Argun terrane, which is traditionally considered a key element of the hypothetical Amuria composite continent. Since 1990, when Amuria was first proposed in palaeogeographic reconstructions, it became one of the principle members in the global palaeotectonic schemes. A scenario when collision of Amuria with Siberian margin resulted in formation of the Mongol-Okhotsk Ocean is universally accepted and supported by majority of researchers. However, time of Amuria's final assembly and relative position of the blocks within Amuria before the collision with Siberia is still a topic of debate. Questions about principal allocation of Argun terrane and its relation to Amuria during the late Neoroterozoic-Cambrian are addressed in this study. Palaeomagnetic poles for the Ediacaran-early Cambrian rocks of Argun terrane differ within an error from coeval poles from Siberia indicating that Argun terrane could have been located similar to its present-day position with respect to Siberia already at 560-525 Ma. This observation calls into question association of Argun terrane with Amuria, which in classic reconstructions is usually placed close to the North China Craton. It also questions our current understanding of the Amuria palaeocontinent and consequently, accuracy of global palaeogeographic reconstructions for the late Neoproterozoic-Cambrian in general, and those of the eastern part of the Central Asia in particular.