STRUCTURAL GEOMETRY OF AN EXHUMED UHP TERRANE IN THE EASTERN SULU OROGEN, CHINA: IMPLICATIONS FOR CONTINENTAL COLLISIONAL PROCESSES

NASA Astrophysics Data System (ADS)

Wang, L.; Kusky, T.

2009-12-01

High-precision 1:1,000 mapping of Yangkou Bay, eastern Sulu orogen, defines the structural geometry and history of the world’s most significant UHP (Ultrahigh Pressure) rock exposures. Four stages of folds are recognized in the UHP rocks and associated quartzo-feldspathic gneiss. Eclogite facies rootless F1 and isoclinal F2 folds are preserved locally in coesite-eclogite. Mylonitic to ultramylonitic cosesit-eclogite shear zones separate 5-10-meter-thick nappes of ultramafic-mafic UHP rocks from banded quartzo-feldspathic gneiss. These shear zones are folded, and progressively overprinted by amphibolite and greenschist facies shear zones that become wider with lower grade. The deformation sequences is explained by deep subduction of offscraped thrust slices of oceanic or lower continental crust, caught between the colliding North and South China cratons in the Mesozoic. After these slices were structurally isolated along the plate interface, they were rolled like ball-bearings, in the subduction channel during their exhumation, forming several generations of folds, sequentially lower-grade foliations and lineations, and intruded by several generations of in situ and exotically derived melts. The shear zones formed during different generations of deformation are wider with lower grades, suggesting that deep-crustal/upper mantle deformation operates efficiently (perhaps with more active crystallographic slip systems) than deformation at mid to upper crustal levels.

Magnitude of long-term non-lithostatic pressure variations in lithospheric processes: insight from thermo-mechanical subduction/collision models

NASA Astrophysics Data System (ADS)

Gerya, Taras

2014-05-01

On the one hand, the principle of lithostatic pressure is habitually used in metamorphic geology to calculate paleo-depths of metamorphism from mineralogical pressure estimates given by geobarometry. On the other hand, it is obvious that this lithostatic (hydrostatic) pressure principle should only be valid for an ideal case of negligible deviatoric stresses during the long-term development of the entire tectono-metamorphic system - the situation, which newer comes to existence in natural lithospheric processes. The question is therefore not "Do non-lithostatic pressure variations exist?" but " What is the magnitude of long-term non-lithostatic pressure variations in various lithospheric processes, which can be recorded by mineral equilibria of respective metamorphic rocks?". The later question is, in particular, relevant for various types of high-pressure (HP) and ultrahigh-pressure (UHP) rocks, which are often produced in convergent plate boundary settings (e.g., Hacker and Gerya, 2013). This question, can, in particular, be answered with the use of thermo-mechanical models of subduction/collision processes employing realistic P-T-stress-dependent visco-elasto-brittle/plastic rheology of rocks. These models suggest that magnitudes of pressure deviations from lithostatic values can range >50% underpressure to >100% overpressure, mainly in the regions of bending of rheologically strong mantle lithosphere (Burg and Gerya, 2005; Li et al., 2010). In particular, strong undepresures along normal faults forming within outer rise regions of subducting plates can be responsible for downward water suction and deep hydration of oceanic slabs (Faccenda et al., 2009). Weaker HP and UHP rocks of subduction/collision channels are typically subjected to lesser non-lithostatic pressure variations with characteristic magnitudes ranging within 10-20% from the lithostatic values (Burg and Gerya, 2005; Li et al., 2010). The strength of subducted crustal rocks and the degree of

Buoyancy-driven, rapid exhumation of ultrahigh-pressure metamorphosed continental crust

PubMed Central

Ernst, W. G.; Maruyama, S.; Wallis, S.

1997-01-01

Preservation of ultrahigh-pressure (UHP) minerals formed at depths of 90–125 km require unusual conditions. Our subduction model involves underflow of a salient (250 ± 150 km wide, 90–125 km long) of continental crust embedded in cold, largely oceanic crust-capped lithosphere; loss of leading portions of the high-density oceanic lithosphere by slab break-off, as increasing volumes of microcontinental material enter the subduction zone; buoyancy-driven return toward midcrustal levels of a thin (2–15 km thick), low-density slice; finally, uplift, backfolding, normal faulting, and exposure of the UHP terrane. Sustained over ≈20 million years, rapid (≈5 mm/year) exhumation of the thin-aspect ratio UHP sialic sheet caught between cooler hanging-wall plate and refrigerating, downgoing lithosphere allows withdrawal of heat along both its upper and lower surfaces. The intracratonal position of most UHP complexes reflects consumption of an intervening ocean basin and introduction of a sialic promontory into the subduction zone. UHP metamorphic terranes consist chiefly of transformed, yet relatively low-density continental crust compared with displaced mantle material—otherwise such complexes could not return to shallow depths. Relatively rare metabasaltic, metagabbroic, and metacherty lithologies retain traces of phases characteristic of UHP conditions because they are massive, virtually impervious to fluids, and nearly anhydrous. In contrast, H2O-rich quartzofeldspathic, gneissose/schistose, more permeable metasedimentary and metagranitic units have backreacted thoroughly, so coesite and other UHP silicates are exceedingly rare. Because of the initial presence of biogenic carbon, and its especially sluggish transformation rate, UHP paragneisses contain the most abundantly preserved crustal diamonds. PMID:11038569

Mineralogical Evidence for the Bulk Transformation of Continental Crust to Ultrahigh-Pressure Conditions in Subduction Zones

NASA Astrophysics Data System (ADS)

Peterman, E. M.; Hacker, B. R.; Kylander-Clark, A. R.

2005-12-01

Evidence for (ultra)high-pressure --(U)HP-- metamorphism in modern orogenic belts and the preservation of exhumed (U)HP terranes around the world suggest that subduction and exhumation of continental crust plays an important role in Phanerozoic plate tectonics. The Western Gneiss region (WGR) of Norway, a major (U)HP province extending over 60,000 km2, provides an excellent opportunity to study how subduction to depths >100 km affects continental crust. By studying a ~60 km wide transect bounded to the north by Vartdalsfjorden and Rovdefjorden and the south by the Möre og Romsdal county boundary, we are able to examine mineralogical changes that occurred during subduction and exhumation within a rock composed predominantly of orthogneiss and variably transformed mafic bodies, which indicate the depths to which these rocks were subducted. Previous studies (e.g. Hacker et al., 2005) have suggested that Caledonian deformation in WGR host gneisses is primarily limited to brittle-ductile fabrics characterized by greenschist to lower-amphibolite facies metamorphism; the majority of the deformation in the rocks, including the pervasive foliation and foliation-parallel isoclinal folds, occurred between 1200 and 900 Ma. On the northern half of our study area, however, locally occurring neoblastic garnet crosscuts the foliation in the gneiss. The boundary of this garnet zone coincides with the local HP-UHP boundary, as determined by the presence of coesite in eclogite. Because garnet can retain information about changes in pressure and temperature, as well as the availability of water within the crust to catalyze chemical reactions, our findings suggest that 1) portions of the orthogneiss did transform at high pressures, 2) the presence of garnet within the orthogneiss may indicate conditions that approximate UHP and can therefore be useful in defining the boundaries between UHP and HP conditions, and 3) the growth of garnet during (U)HP metamorphism may be controlled by

A crustal model of the ultrahigh-pressure Dabie Shan orogenic belt, China, derived from deep seismic refraction profiling

USGS Publications Warehouse

Wang, Chun-Yong; Zeng, Rong-Sheng; Mooney, W.D.; Hacker, B.R.

2000-01-01

We present a new crustal cross section through the east-west trending ultrahigh-pressure (UHP) Dabie Shan orogenic belt, east central China, based on a 400-km-long seismic refraction profile. Data from our profile reveal that the cratonal blocks north and south of the orogen are composed of 35-km-thick crust consisting of three layers (upper, middle, and lower crust) with average seismic velocities of 6.0±0.2 km/s, 6.5±0.1 km/s, and 6.8±0.1 km/s. The crust reaches a maximum thickness of 41.5 km beneath the northern margin of the orogen, and thus the present-day root beneath the orogen is only 6.5 km thick. The upper mantle velocity is 8.0±0.1 km/s. Modeling of shear wave data indicate that Poisson's ratio increases from 0.24±0.02 in the upper crust to 0.27±0.03 in the lower crust. This result is consistent with a dominantly felsic upper crustal composition and a mafic lower crustal composition within the amphibolite or granulite metamorphic facies. Our seismic model indicates that eclogite, which is abundant in surface exposures within the orogen, is not a volumetrically significant component in the middle or lower crust. Much of the Triassic structure associated with the formation of the UHP rocks of the Dabie Shan has been obscured by post-Triassic igneous activity, extension and large-offset strike-slip faulting. Nevertheless, we can identify a high-velocity (6.3 km/s) zone in the upper (<5 km depth) crustal core of the orogen which we interpret as a zone of ultrahigh-pressure rocks, a north dipping suture, and an apparent Moho offset that marks a likely active strike-slip fault.

Metamorphism of eclogites from the UHP Maksyutov Complex, south Ural Mountains, Russia

NASA Astrophysics Data System (ADS)

Burlick, T. D.; Leech, M. L.

2013-12-01

The Maksyutov Complex is a mid- to late Paleozoic ultrahigh-pressure (UHP) subduction terrane in the south Ural Mountains of Russia. Radial fractures around quartz inclusions in garnet, omphacite, and glaucophane interpreted as pre-existing coesite; and microdiamond aggregates in garnet identified by Raman spectroscopy demonstrate Maksyutov rocks were subducted to UHP conditions (>2.8 GPa for coesite and >3.0 GPa for diamond at 600°C). Peak UHP eclogite-facies metamorphism (Grt+Omp+Ph+Coe+Rt ×Ttn) took place at c. 385 M and Maksyutov rocks were exhumed through retrograde blueschist-facies metamorphism (Grt+Gln+Ph+Qz×Chl×Ep) by 360 Ma. Pseudosections were constructed to constrain the P-T conditions recorded by the equilibrium mineral assemblanges in eclogites and their retrograded equivalents using bulk rock XRF analysis in the system Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2 and the suite of free energy minimization programs, Perple_X 6.6.8 [Connolly 2009] with the internally consistent end-member thermodynamic database from Holland and Powell [1998] (mod 2004); solution models for omphacite (Holland and Powell, 1996), clinoamphibole (Dale et al. 2005), white mica (Coggon & Holland 2002, Auzanneau et al 2010), chlorite and garnet (Holland and Powell 1998; Powell and Holland 1999), and feldspar (Thompson and Hovis 1979; Newton et al. 1980) were used with H2O as a saturated component. Both conventional thermometry, using microprobe analyses and Grt-Cpx cation exchange as well as pseudosection modeling result in higher peak equilibrium temperatures than has been previously been reported in the Maksyutov. Pseudosection modeling gives minimum P-T conditions of 625°-675°C and 2.8-3.1 GPa for peak assemblages from the least retrogressed eclogites, while Fe-Mg exchange thermometry yields temperatures of 775°C × 25°C for pressures ranging from 2.5 to 3.5 GPa.

Origin of retrograde fluid in ultrahigh-pressure metamorphic rocks: Constraints from mineral hydrogen isotope and water content changes in eclogite gneiss transitions in the Sulu orogen

NASA Astrophysics Data System (ADS)

Chen, Ren-Xu; Zheng, Yong-Fei; Gong, Bing; Zhao, Zi-Fu; Gao, Tian-Shan; Chen, Bin; Wu, Yuan-Bao

2007-05-01

By taking advantage of having depth profiles between contrasting lithologies from core samples of the Chinese Continental Scientific Drilling (CCSD) project, a combined study was carried out to examine changes in mineral H isotope, total water and hydroxyl contents in garnet and omphacite across the contacts between ultrahigh-pressure (UHP) eclogite and gneiss in the Sulu orogen, east-central China. The samples of interest were from two continuous core segments from the CCSD main hole at depths of 734.21-737.16 and 929.67-932.86 m, respectively. The results show δD values of -116‰ to - 64‰ for garnet and -104‰ to -82‰ for omphacite, consistent with incorporation of meteoric water into protoliths of UHP metamorphic rocks by high-T alteration. Both equilibrium and disequilibrium H isotope fractionations were observed between garnet and omphacite, suggesting fluid-assisted H isotope exchange at local scales during amphibolite-facies retrogression. While bulk water analysis gave total H 2O concentrations of 522-1584 ppm for garnet and 1170-20745 ppm for omphacite, structural hydroxyl analysis yielded H 2O contents of 80-413 ppm for garnet and 228-412 ppm for omphacite. It appears that significant amounts of molecular H 2O are present in the minerals, pointing to enhanced capacity of water storage in the UHP eclogite minerals. Hydrogen isotope variations in the transition between eclogite and gneiss show correlations with variations in their water contents. Petrographically, the degree of retrograde metamorphism generally increases with decreasing distance from the eclogite-gneiss boundary. Thus, retrograde metamorphism results in mineral reactions and H isotope variation. Because hydroxyl solubility in nominally anhydrous minerals decreases with dropping pressure, significant amounts of water are expected to be released from the minerals during decompression exhumation. Decompression exsolution of structural hydroxyl from 1 m 3 volume of eclogite composed of

Geochronology of multi-stage metamorphic events: Constraints on episodic zircon growth from the UHP eclogite in the South Altyn, NW China

NASA Astrophysics Data System (ADS)

Liu, Liang; Wang, Chao; Cao, Yu-Ting; Chen, Dan-Ling; Kang, Lei; Yang, Wen-Qiang; Zhu, Xiao-Hui

2012-04-01

Petrography, mineral chemistry and pressure-temperature (P-T) estimates were carried out for the eclogite from the South Altyn in NW China. The results suggest three stages of metamorphism: an ultra-high pressure (UHP) eclogite-facies metamorphism at 717-871 °C and ≥ 2.8 GPa, a high pressure (HP) granulite-facies metamorphism at 624-789 °C and 1.42-1.52 GPa, and an amphibolite-facies metamorphism at 597-728 °C and 0.99-1.17 GPa. Cathodoluminescence investigation revealed that zircons from the retrograde eclogite display a distinct core-rim structure. Cores are grey-white luminescent and contain mineral inclusions of Garnet + Omphacite + Rutile + Quartz, suggesting eclogite-facies metamorphic origin. The rims are dark grey luminescent and contain Garnet + Clinopyroxene + Pagioclase inclusions, forming at HP granulite-facies conditions. A few residual zircon grains with mottled internal structure also occur as the metamorphic cores. LA-ICPMS zircon U-Pb dating yielded three discrete age groups: (1) a Neoproterozoic protolith age of 752 ± 7 Ma for the residual grains, (2) an eclogite-facies metamorphic age of 500 ± 7 Ma for the metamorphic cores, and (3) a HP granulite-facies retrograde age of 455 ± 2 Ma for the rims. These ages indicate that the protolith of the Altyn eclogite probably formed in response to breakup of the Rodinia supercontinent during the Neoproterozoic; it was subjected to continental deep subduction and UHP metamorphism during early Paleozoic (~ 500 Ma) and subsequently underwent two stages of retrograde metamorphism during exhumation. The petrological and geochronological data suggest a clockwise P-T-t path for the UHP eclogite. According to pressures and ages for the peak UHP eclogite-facies and the retrograde HP granulite-facies metamorphism, an exhumation rate of 1.2 mm/yr was estimated for the eclogite, which is considerably slower than that of some UHP rocks from other UHP terranes (> 5 mm/yr). While the peak metamorphic age of 500 Ma

Ultrahigh pressure fast size exclusion chromatography for top-down proteomics.

PubMed

Chen, Xin; Ge, Ying

2013-09-01

Top-down MS-based proteomics has gained a solid growth over the past few years but still faces significant challenges in the LC separation of intact proteins. In top-down proteomics, it is essential to separate the high mass proteins from the low mass species due to the exponential decay in S/N as a function of increasing molecular mass. SEC is a favored LC method for size-based separation of proteins but suffers from notoriously low resolution and detrimental dilution. Herein, we reported the use of ultrahigh pressure (UHP) SEC for rapid and high-resolution separation of intact proteins for top-down proteomics. Fast separation of intact proteins (6-669 kDa) was achieved in < 7 min with high resolution and high efficiency. More importantly, we have shown that this UHP-SEC provides high-resolution separation of intact proteins using a MS-friendly volatile solvent system, allowing the direct top-down MS analysis of SEC-eluted proteins without an additional desalting step. Taken together, we have demonstrated that UHP-SEC is an attractive LC strategy for the size separation of proteins with great potential for top-down proteomics. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Provenance of Jurassic sediments in the Hefei Basin, east-central China and the contribution of high-pressure and ultrahigh-pressure metamorphic rocks from the Dabie Shan

NASA Astrophysics Data System (ADS)

Li, Renwei; Wan, Yusheng; Cheng, Zhenyu; Zhou, Jianxiong; Li, Shuangying; Jin, Fuquan; Meng, Qingren; Li, Zhong; Jiang, Maosheng

2005-03-01

The provenance of the Jurassic sediments in the Hefei Basin is constrained by compositions of the detrital K-white micas and garnets, and SHRIMP dating of the detrital zircons, which can help to understand the evolution and to reconstruct the paleogeographic distribution of HP-UHP rocks in the Jurassic Dabie Shan. (1) For the oldest Mesozoic sediments at the bottom of the Fanghushan Formation ( J1), the predominance of the early Paleozoic and Luliang (1700-1900 Ma) zircons indicates a major source from the North China Block. However, Neoproterozoic zircons as the major component in other Jurassic sediments indicate that the source rocks were mainly derived from the exhumed Yangtze Block in the Dabie Shan. (2) The co-occurrence of high-Si phengites and Triassic zircons provides stratigraphic evidence that the first exposure of the UHP rocks at the Earth's surface in the Dabie Shan occurred in the Early Jurassic during deposition of the Fanghushan Formation. (3) From the east to the west of the Hefei Basin, there is a spatial variation in the compositions for detrital micas and garnets, and in the U-Pb ages of detrital zircons. Evidently, HP-UHP rocks were widely distributed at outcrop in the eastern Dabie Shan. In contrast, they were less important in the western Dabie Shan during the Jurassic.

Structure and Activity Changes of Phytohemagglutinin from Red Kidney Bean (Phaseolus vulgaris) Affected by Ultrahigh-Pressure Treatments.

PubMed

Lu, Yunjun; Liu, Cencen; Zhao, Mouming; Cui, Chun; Ren, Jiaoyan

2015-11-04

Phytohemagglutin (PHA), purified from red kidney beans (Phaseolus vulgaris) by Affi-Gel blue affinity chromatography, was subjected to ultrahigh-pressure (UHP) treatment (150, 250, 350, and 450 MPa). The purified PHA lost its hemagglutination activity after 450 MPa treatment and showed less pressure tolerance than crude PHA. However, the saccharide specificity and α-glucosidase inhibition activity of the purified PHA did not change much after UHP treatment. Electrophoresis staining by periodic acid-Schiff (PAS) manifested that the glycone structure of purified PHA remained stable even after 450 MPa pressure treatment. However, electrophoresis staining by Coomassie Blue as well as circular dichroism (CD) and differential scanning calorimetry (DSC) assay proved that the protein unit structure of purified PHA unfolded when treated at 0-250 MPa but reaggregates at 250-450 MPa. Therefore, the hemagglutination activity tends to be affected by the protein unit structure, while the stability of the glycone structure contributed to the remaining α-glucosidase inhibition activity.

UHP metamorphism in Greece: Petrologic data from the Rhodope Mountains

NASA Astrophysics Data System (ADS)

Baziotis, I. P.; Mposkos, E.; Krohe, A.; Wawrzenitz, N. H.; Liu, Y.; Taylor, L. A.

2012-12-01

Metamorphic rocks contain invaluable information for understanding the orogenic mechanisms of a tectonic regime. It is now well recorded and recognized that subduction of oceanic lithosphere and collision of continental blocks can result in sinking of subducted rocks to deeper levels than normal (>100 km). Further, the discovery of coesite and diamond in apparently regionally metamorphosed rocks provoked issues, for returning these rocks to the surface relatively fast, thereby preserving the UHP conditions. These UHPM terrains have been identified in more than twenty provinces worldwide. In Greece, UHPM rocks occur in the Rhodope area, one of the major tectono-metamorphic units located in NE Greece. This region consists of different metamorphic complexes involved in the Alpine collisional history between the Eurasian and African plates (e.g., Krohe & Mposkos, 2002-Geol Soc London Spec Pub, 204, 151). In Rhodope, a Jurassic UHP metamorphism is confirmed in the uppermost Kimi and the underlying Sidironero complexes (Mposkos & Kostopoulos, 2001- EPSL, 192, 497; Perraki et al., 2004-5th ISEMG, T2-35, 2006- EPSL, 241, 672; Liati, 2005- Con Min Pet, 150, 608; Bauer et al., 2007- Lithos, 99, 207). UHP metamorphism is evidenced by the presence of octahedral microdiamond inclusions (3 to 10 μm) in protective garnets, within the metapelitic gneisses. Microdiamonds probably formed from a supercritical fluid under extreme P-T conditions. The latter is strengthened by the presence of composite inclusions consisting of CO2, calcite, and microdiamonds. Other UHP indicators include: 1) quartz rods and rutile needle exsolutions in metapelitic garnet, suggesting a former titaniferous super-silicic (majoritic) garnet formed at P >4GPa; 2) oriented quartz lamellae in eclogitic clinopyroxene having been exsolved from a former super-silicic UHP precursor; and 3) coesite pseudomorphs in garnet, where radial cracks around multi-crystalline-quartz aggregates are indicative of the former

Mantle Lithosphere Rheology, Vertical Tectonics, and the Exhumation of (U)HP Rocks

NASA Astrophysics Data System (ADS)

Bodur, Ömer F.; Göǧüş, Oǧuz H.; Pysklywec, Russell N.; Okay, Aral I.

2018-02-01

Numerical modeling results indicate that mantle lithosphere rheology can influence the pressure-temperature-time (P-T-t) trajectories of continental crust subducted and exhumed during the onset of continental collision. Exhumation of ultrahigh-pressure ( 35 kbar)/high-temperature ( 750°C) metamorphic rocks is more prevalent in models with stronger continental mantle lithosphere (e.g., dry), whereas high-pressure ( 9-22 kbar)/low-temperature (350°C-630°C) metamorphic rocks occur in models with weaker rheology (e.g., hydrated) for the same layer. In the latter case, the buried crustal rocks can remain encased in ablatively subducting mantle lithosphere, reach only moderate temperatures, and exhume by dripping/detachment of the lithospheric root. In this transition from subduction to a dripping style of "vertical tectonics," burial and exhumation of crustal rocks are driven without imposed far-field plate convergence. The model results are compared against thermobarometric P-T estimates from major (ultra)high-pressure metamorphic terranes. We propose that the exhumation of high-pressure/low-temperature metamorphic rocks in Tavşanlı and Afyon zones in western Anatolia may be caused by viscous dripping of mantle lithosphere suggesting a weaker continental mantle lithosphere, whereas (ultra)high-pressure exhumation (e.g., Dabie Shan-eastern China and Dora Maira-western Alps) may be associated with plate-like subduction. In the latter case, the slab is much stronger and deformation is localized to the subduction interface along which rocks are buried to >100 km depth before they are exhumed to the near surface.

Age and duration of eclogite-facies metamorphism, North Qaidam HP/UHP terrane, Western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Liou, J.G.; Bird, D.K.; Wu, C.L.

2006-01-01

Amphibolite-facies para-and orthogneisses near Dulan, at the southeast end of the North Qaidam terrane, enclose minor eclogite and peridotite which record ultra-high pressure (UHP) metamorphism associated with the Early Paleozoic continental collision of the Qilian and Qaidam microplates. Field relations and coesite inclusions in zircons from paragneiss suggest that felsic, mafic, and ultramafic rocks all experienced UHP metamorphism and a common amphibolite-facies retrogression. SHRIMP-RG U-Pb and REE analyses of zircons from four eclogites yield weighted mean ages of 449 to 422 Ma, and REE patterns (flat HREE, no Eu anomaly) and inclusions of garnet, omphacite, and rutile indicate these ages record eclogite-facies metamorphism. The coherent field relations of these samples, and the similar range of individual ages in each sample suggests that the ???25 m.y. age range reflects the duration of eclogite-facies conditions in the studied samples. Analyses from zircon cores in one sample yield scattered 433 to 474 Ma ages, reflecting partial overlap on rims, and constrain the minimum age of eclogite protolith crystallization. Inclusions of Th + REE-rich epidote, and zircon REE patterns are consistent with prograde metamorphic growth. In the Lu??liang Shan, approximately 350 km northwest in the North Qaidam terrane, ages interpreted to record eclogite-facies metamorphism of eclogite and garnet peridotite are as old as 495 Ma and as young as 414 Ma, which suggests that processes responsible for extended high-pressure residence are not restricted to the Dulan region. Evidence of prolonged eclogite-facies metamorphism in HP/UHP localities in the Northeast Greenland eclogite province, the Western Gneiss Region of Norway, and the western Alps suggests that long eclogite-facies residence may be globally significant in continental subduction/collision zones.

Mantle Recycling of Crustal Materials through Study of Ultrahigh-Pressure Minerals in Collisional Orogens, Ophiolites, and Xenoliths

NASA Astrophysics Data System (ADS)

Liou, J. G.; Tsujimori, T.; Yang, J.; Zhang, R. Y.; Ernst, W. G.

2014-12-01

Newly recognized ultrahigh-pressure (UHP) mineral occurrences including diamonds in ultrahigh-temperature (UHT) felsic granulites of orogenic belts, in chromitites associated with ophiolitic complexes, and in mafic/ultramafic xenoliths suggest the recycling of crustal materials through profound subduction, mantle upwelling, and return to the Earth's surface. Recycling is supported by unambiguously crust-derived mineral inclusions in deep-seated zircons, chromites, and diamonds from collision-type orogens, from eclogitic xenoliths, and from ultramafic bodies of several Alpine-Himalayan and Polar Ural ophiolites; some such phases contain low-atomic number elements typified by crustal isotopic signatures. Ophiolite-type diamonds in placer deposits and as inclusions in chromitites together with numerous highly reduced minerals and alloys appear to have formed near the mantle transition zone. In addition to ringwoodite and stishovite, a wide variety of nanometric minerals have been identified as inclusions employing state-of-the-art analysis. Reconstitution of now-exsolved precursor UHP phases and recognition of subtle decompression microstructures produced during exhumation reflect earlier UHP conditions. Some podiform chromitites and associated peridotites contain rare minerals of undoubted crustal origin, including Zrn, corundum, Fls, Grt, Ky, Sil, Qtz, and Rtl; the zircons possess much older U-Pb ages than the formation age of the host ophiolites. These UHP mineral-bearing chromitites had a deep-seated evolution prior to extensional mantle upwelling and its partial melting at shallow depths to form the overlying ophiolite complexes. These new findings plus stable isotopic and inclusion characteristics of diamonds provide compelling evidence for profound underflow of both oceanic and continental lithosphere, recycling of biogenic carbon into the lower mantle, and ascent to the Earth's surface through deep mantle ascent.

On the preservation mechanism of intragranular coesite in the Yangkou, Sulu UHP eclogite

NASA Astrophysics Data System (ADS)

Wang, L.; Zhang, J.; Wang, S.; Shi, F.; Cen, Y.

2012-12-01

appearance of phengite and coesite's transformation into quartz, the water content within phengite bearing eclogite is raised. The average hydrogen concentration of garnet is 26-157 ppm , that of omphacite is 270-405 ppm. This indicates that with the appearance of phengite and retrogression, the water content of eclogite is raised up gradually, but at this stage, the eclogite is still within a localized "dry" environment compared to most water-rich (1000-2000ppm) eclogite in the Dabie-Sulu orogen. Through the structural and petrological analysis, we find that the intragranular coesite is more likely preserved within the F1 rootless isoclinal folds which formed prior to the peak metamorphism. This suggests that F1 rootless folds act as rigid and impervious shells under ultrahigh-pressure conditions, and shelter the eclogite from the surrounding fluid, which is helpful to maintain a relatively dry environment during rapid exhumation of UHP rocks, allowing the intergranular coesite to be preserved. This mechanism may have important implications for understanding the prograde path of continental-continental collision, and understanding the structural setting of the preserved intergranular coesite, which has important implications for the search for the early fabrics and metamorphic assemblages in other UHP-terrains around the world.

Constraining cooling rates of UHP metamorphic rocks with closure temperature geospeedometry: a case study from the Dabie orogen

NASA Astrophysics Data System (ADS)

Lloyd, M. K.; Shimizu, N.; Wang, Z.; Zheng, Y.

2011-12-01

UHP metamorphic rocks can reach peak temperatures and pressures >800°C and >3GPa, and provide unique opportunities for studying geochemical processes in subduction zones. How and how fast they were exhumed are, however, still outstanding questions. Here we report SIMS-based Zr concentrations in rutiles from an eclogite sample from Huangzhen in the South Dabie low-T/UHP zone, east-central China, and present a closure temperature-based approach to constrain the cooling/exhumation rate of UHP rocks. Li et al. (2004) put peak metamorphism at a time prior to 236.1 ± 4.2 Ma., but estimates for peak temperatures and pressures in South Dabie vary wildly depending on the rock suite. The fine-grained eclogites in the Dabie orogen were estimated to have reached conditions of 641-839 °C and 2.00-3.54 GPa (Shi and Wang, 2006) based on Fe-Mg partition thermometry and metamorphic phase equilibria. These samples were reported to contain quartz, zircon, and rutile phases that reached thermodynamic equilibrium with each other. In this study, Zr concentrations of rutiles were obtained using the Cameca IMS 1280 ion microprobe at Northeast National Ion Microprobe Facility, by converting secondary ion intensity ratios, 90Zr/46Ti, to concentrations using rutile standards described by Luvizotto et al. (2009), with analytical uncertainties of 5.1%. Temperatures were then calculated using the method of Ferry and Watson (2007). It was found that Zr concentrations range from 38.6(2.4) to 134.6(4.5) ppm, resulting in a temperature range of 504(24) to 583(27)°C for 72 grains with size spanning from 62 to 440 microns cross in long axis. Minor rim-ward decrease of Zr content was observed with no appreciable temperature decrease. Assuming that the rutiles grew at one stage during the peak metamorphism and that their Zr concentrations were independent of pressure, a cooling rate can be estimated for the target sample. By applying the Dodson (1973) formula for closure temperature in conjunction

Devonian to Carboniferous collision in the Greenland Caledonides: U-Pb zircon and Sm-Nd ages of high-pressure and ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

Gilotti, Jane A.; Nutman, Allen P.; Brueckner, Hannes K.

2004-10-01

A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th

SHRIMP U-Pb zircon dating from eclogite lenses in marble, Dabie-Sulu UHP terrane: restriction on the prograde, UHP and retrograde metamorphic ages

NASA Astrophysics Data System (ADS)

Liu, F.; Gerdes, A.; Xue, H.; Liang, F.

2006-12-01

Eclogite as lenses in impure marbles from Dabie-Sulu UHP terrane, represent parts of deeply subducted meta- sedimentary rocks. To constrain the age of metamorphism during subduction and exhumation, zircons from 2 eclogite samples in Dabie-Sulu impure marbles have been investigated. Beside Inherited (detrital) grains, 3 different metamorphic zircon domains have been identified based on distribution of mineral inclusion, trace elements and cathodoluminescence (CL) imaging: 1. Dark-luminescent rounded cores with quartz eclogite- facies mineral inclusions suggest formation at high-pressure (HP) metamorphic conditions. 2. White- luminescent zircon, either surrounding domain 1 or as rounded to spindly cores with index coesite eclogite- facies mineral inclusions indicates formation at UHP conditions. 3. Grey-luminescent rims around domain 2 with low-pressure mineral inclusions suggest formation during late regional amphibolite-facies retrogression. The three distinct zircon domains were dated by SHRIMP and yielded three discrete and meaningful age groups: 245±4 Ma for prograde HP metamorphism, 235±3 Ma for UHP metamorphism and 215±6 Ma for late amphibolite-facies retrogression from Dabie-Sulu eclogite. This data suggests that subduction and exhumation took place in about 10-11 Myr and 19-20 Myr, respectively. Continental materials was subducted from surface to the deep mantle depth at rates of 10 km/Myr, and subsequently exhumed from the mantle to the base of the crust at rates of 7 km/Myr. Ultrafast exhumation of the Dabie-Sulu UHP terrane from depth of 160 to 30 km was probably driven by buoyancy forces after UHP slab break-off at deep mantle depths.

The role of serpentinite melanges in the unroofing of UHPM rocks: An example from the Western Alps of Italy: Chapter 6

USGS Publications Warehouse

Blake, M. Clark; Moore, D.E.; Jayko, A.S.; Coleman, Robert G.

1995-01-01

The ultrahigh pressure metamorphic rocks (UHPM) of the Dora-Maira continental massif are overlain by a stack of oceanic nappes. Metamorphic grade appears to increase downward but with marked discontinuities between each of the nappes, suggesting that section has been removed along the bounding faults. This apparent omission of section is greatest in the lowest oceanic unit where a serpentinite melange containing blocks and slabs of eclogite, metamorphosed at 12–19 kbar, lies on the UHPM rocks. We suggest that this serpentinite melange represents a highly attenuated upper mantle section that structurally overlay the UHP rocks during subduction. Similar serpentinite melanges are known from other high-pressure (HP) and UHPM areas and may have a similar origin.

Ca. 400 Ma Recrystallization of Norwegian Ultrahigh-pressure Eclogites: an ion Microprobe and Chemical Abrasion Study

NASA Astrophysics Data System (ADS)

Root, D. B.; Mattinson, J. M.; Hacker, B. R.; Wooden, J. L.

2002-12-01

Understanding the formation and exhumation of the ultrahigh-pressure (UHP) rocks of western Norway hinges on precise determination of the time of eclogite recrystallization. Our study consists of SHRIMP analysis, in conjunction with CL imagery, of zircon from four UHP and high-pressure (HP) eclogites; and detailed TIMS analysis of zircon from two samples subjected to combined thermal annealing and multi-step chemical abrasion (CA). SHRIMP analyses of the Otnheim and Langenes eclogites yield Caledonian spot ages of ca. 400 Ma from zircon rims. CL imagery and Th/U ratios from the Langenes eclogite indicate formation of rims by recrystallization of inherited zircon. SHRIMP analysis of the UHP Flatraket eclogite yielded a broad range of apparently concordant Caledonian ages. CA analyses of two fractions yielded moderate Pb loss from the first (lowest T) steps; possible minor Pb loss or minor growth at 400 Ma from the second steps; and a 407-404 Ma cluster of slightly discordant 206Pb/238U ages, most likely free from Pb loss, from the remaining steps. We interpret the latter to reflect recrystallization of inherited zircon, with possible new growth, at ca. 400-395 Ma. Alternatively, the high-temperature CA steps could represent growth at 407-404 Ma, with apparent discordance due to intermediate daughter product effects. HP/UHP zircon recrystallization in the Flatraket eclogite is inferred from three lines of evidence: i) zircon occurs as inclusions in garnet, omphacite, breunnerite, dolomite, and quartz, as well as in symplectites after phengite and omphacite; ii) association of zircon with rutile implies zircon formation during HP breakdown of Zr-ilmenite; and iii) chondrite-normalized ICP-MS analyses of the CA steps reveal small Eu anomalies and shallow HREE profiles, indicating zircon recrystallization in the presence of garnet. CA analysis of the Verpeneset eclogite yielded distinctly discordant step ages from two steps comprising <90% of the sample, with 206Pb/238U

Geochronology and tectonic significance of Middle Proterozoic granitic orthogneiss, North Qaidam HP/UHP terrane, Western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Liou, J.G.; Bird, D.K.; Wu, C.L.

2006-01-01

Amphibolite-facies para- and orthogneisses near Dulan, in the southeast part of the North Qaidam terrane, enclose minor ultra-high pressure (UHP) eclogite and peridotite. Field relations and coesite inclusions in zircons from paragneiss suggest that felsic, mafic, and ultramafic rocks all experienced UHP metamorphism and a common amphibolite-facies retrogression. Ion microprobe U-Pb and REE analyses of zircons from two granitic orthogneisses indicate magmatic crystallization at 927 ?? Ma and 921 ?? 7 Ma. Zircon rims in one of these samples yield younger ages (397-618 Ma) compatible with partial zircon recrystallization during in-situ Ordovician-Silurian eclogite-facies metamorphism previously determined from eclogite and paragneiss in this area. The similarity between a 2496 ?? 18 Ma xenocrystic core and 2.4-2.5 Ga zircon cores in the surrounding paragneiss suggests that the granites intruded the sediments or that the granite is a melt of the older basement which supplied detritus to the sediments. The magmatic ages of the granitic orthogneisses are similar to 920-930 Ma ages of (meta)granitoids described further northwest in the North Qaidam terrane and its correlative west of the Altyn Tagh fault, suggesting that these areas formed a coherent block prior to widespread Mid Proterozoic granitic magmatism. ?? Springer-Verlag 2006.

Modeling the exhumation path of partially melted ultrahigh-pressure metapelites, North-East Greenland Caledonides

NASA Astrophysics Data System (ADS)

Lang, Helen M.; Gilotti, Jane A.

2015-06-01

Pseudosection modeling constrains the pressure-temperature (P-T) exhumation path of partially melted ultrahigh-pressure (UHP) metapelites exposed in the North-East Greenland UHP terrane. A robust peak P and T estimate of 3.6 GPa and 970 °C based on mineral assemblages in nearby kyanite eclogites is the starting point for the P-T path. Although the peak assemblage for the metapelite is not preserved, the calculated modeled peak assemblage contained substantial clinopyroxene, garnet, phengite, K-feldspar and coesite with minor kyanite and rutile. Combining the pseudosection and observed textures, the decompression path crosses the coesite-quartz transition before reaching the dry phengite dehydration melting reaction where phengite is abruptly consumed. In the range of 2.5 to 2.2 GPa, clinopyroxene is completely consumed and garnet grows to its maximum volume and grossular content, matching the high grossular rims of relict megacrysts. Plagioclase joins the assemblage and the pseudosection predicts up to 12-13 vol.% melt in the supersolidus assemblage, which contained garnet, liquid, K-feldspar, plagioclase, kyanite, quartz and rutile. At this stage, the steep decompression path flattened out and became nearly isobaric. The melt crystallization assemblage that formed when the path crossed the solidus with decreasing temperature contains phengite, garnet, biotite, 2 feldspars, kyanite, quartz and rutile. Therefore, the path must have intersected the solidus at approximately 1.2 GPa, 825 °C. The pseudosection predicts that garnet is consumed on the cooling path, but little evidence of late garnet consumption or other retrograde effects is observed. This may be due to partial melt loss from the rock. Isochemical PT-n and PT-X sections calculated along the P-T path display changes in mineral assemblage and composition that are consistent with preserved assemblages.

Constraining Metamorphic Timing and Processes by Dating Garnet, Zircon, Titanite and Monazite in UHP and HP Rocks from Weihai, Sulu UHP Terrane, Eastern China

NASA Astrophysics Data System (ADS)

Wang, D.; Vervoort, J. D.; Fisher, C. M.; Cao, H.

2016-12-01

The Sulu UHP terrane is the extension of the Dabie orogenic belt to the east, offset 500 km to the northeast by the Tanlu fault [1]. The focus of this study, the Weihai area, is located at the northernmost part of the Sulu UHP terrane, and consists mainly of gneisses overprinted by amphibolite-facies assemblages, in addition to minor eclogite, granulite, and some ultramafic rocks [1]. Time constrains are critical to our understanding of the processes of UHP metamorphism, as well as the tectonic evolution of the region. In the last decade, U-Pb dating of metamorphic domains of zircons has been widely applied to determine the history of the UHP metamorphism (240 - 220 Ma) [1]. Recent garnet Lu-Hf dating from the Dabie terrane (240 - 220Ma) suggests the initiation of prograde metamorphism to be prior to ca. 240 Ma [2]. In-situ U-Pb dating of accessary minerals using LA-ICPMS (i.e. monazite, titanite, rutile, etc.), can provide important information to augment and complement the zircon U-Pb metamorphic dates. In this study, we collected samples throughout the Weihai area. Protolith ages of these samples range from Paleoproterozoic to Neoproterozoic ( 1850 - 700 Ma) as indicated by U-Pb dating of zircon cores. Zircon metamorphic rims yield U-Pb ages of 240 - 220 Ma, likely indicating the UHP stage of the Sulu terrane [3]. Four eclogites yield Lu-Hf garnet isochrons with dates between 239 and 224 Ma, consistent with garnet Lu-Hf dates from Dabie UHP terrane [2]. Sm-Nd isochrons indicate systematic younger dates (220 - 210 Ma) interpreted as cooling ages. Titanites extracted from four samples give U-Pb ages ranging from 220 to 200 Ma, in agreement with the titanite dates from the southern Sulu terrane [4]. Monazites from three samples give precise dates between 214 and 211 Ma. Collectively, monazite and titanite U-Pb ages are broadly consistent with the garnet Sm-Nd isochrons, and thus we interpret these as cooling ages. Based on the dates of different systems

Partially Melted UHP Eclogite in the Sulu Orogenic Belt, China and its rheological significance to deep continental subduction: Micro- to Macro-scale Evidence

NASA Astrophysics Data System (ADS)

Wang, Lu; Kusky, Timothy; Polat, Ali; Wang, Songjie; Jiang, Xingfu; Zong, Keqing; Wang, Junpeng; Deng, Hao; Fu, Jianmin

2015-04-01

Partially Melted UHP Eclogite in the Sulu Orogenic Belt, China and its rheological significance to deep continental subduction: Micro- to Macro-scale Evidence Numerous studies have described partial melting processes in low-high pressure meta-sedimentary rocks, some of which may generate melts that coalesce to form plutons. However, migmatized ultrahigh pressure (UHP) eclogite has never been clearly described from the microscale to macroscale, though experimental studies prove dehydration partial melting of eclogite at high pressure condition1 and low degrees of partially melted eclogite have been reported from the Qaidam UHP orogenic belt in NW China2,3 or inferred from multiphase solid (MS) inclusions within eclogite4 in the Sulu UHP belt. We present field-based documentation of decompression partial melting of UHP eclogite from Yangkou and General's Hill, Sulu Orogen. Migmatized eclogite shows successive stages of anatexis, initially starting from intragranular and grain boundary melt droplets, which grow into a 3D interconnected intergranular network, then segregate and accumulate in pressure shadow areas, and finally merge to form melt channels and dikes that transport melts to upper lithospheric levels. In-situ phengite breakdown-induced partial melting is directly identified by MS inclusions of Kfs+ barium-bearing Kfs + Pl in garnet, connected by 4-10 μm wide veinlets consisting of Bt + Kfs + Pl next to the phengite. Intergranular veinlets of plagioclase + K-feldspar first form isolated beads of melt along grain boundaries and triple junctions of quartz, and with higher degrees of melting, eventually form interconnected 3D networks along grain boundaries in the leucosome, allowing melt to escape from the intergranular realm and collect in low-stress areas. U-Pb (zircon) dating and petrological analyses on residue and leucocratic rocks shows that partial melting occurred at 228-219 Ma, shortly after peak UHP metamorphism (~230 Ma), and at depths of 30-90 km

U-Pb SHRIMP geochronology of zircon in garnet peridotite from the Sulu UHP terrane, China: Implications for mantle metasomatism and subduction-zone UHP metamorphism

USGS Publications Warehouse

Zhang, R.Y.; Yang, J.S.; Wooden, J.L.; Liou, J.G.; Li, T.F.

2005-01-01

We studied the Zhimafang ultrahigh-pressure metamorphic (UHP) peridotite from pre-pilot drill hole PP-1 of Chinese Continental Scientific Drilling project in the Sulu UHP terrane, eastern China. The peridotite occurs as lens within quartofeldspathic gneiss, and has an assemblage of Ol + Opx + Cpx + Phl + Ti-clinohumite (Ti-Chu) + Grt (or chromite) ?? magnesite (Mgs). Zircons were separated from cores at depths of 152 m (C24, garnet lhezolite), 160 m (C27, strongly retrograded phlogopite-rich peridotite) and 225 m (C50, banded peridotite), and were dated by SHRIMP mass spectrometer. Isometric zircons without inherited cores contain inclusions of olivine (Fo91-92), enstatite (En91-92), Ti-clinohumite, diopside, phlogopite and apatite. The enstatite inclusions have low Al2O3 contents of only 0.04-0.13 wt.%, indicating a UHP metamorphic origin. The weighted mean 206Pb/238U zircon age for garnet lherzolite (C24) is 221 ?? 3 Ma, and a discordia lower intercept age for peridotite (C50) is 220 ?? 2 Ma. These ages are within error and represent the time of subduction-zone UHP metamorphism. A younger lower intercept age of 212 ?? 3 Ma for a foliated wehrlite (C27) was probably caused by Pb loss during retrograde metamorphism. The source of zirconium may be partially attributed to melt/fluid metasomatism within the mantle wedge. Geochronological and geochemical data confirm that the mantle-derived Zhimafang garnet peridotites (probably the most representative type of Sulu garnet peridotites) were tectonically inserted into a subducting crustal slab and subjected to in situ Triassic subduction-zone UHP metamorphism. ?? 2005 Elsevier B.V. All rights reserved.

Recycling of crustal materials through study of ultrahigh-pressure minerals in collisional orogens, ophiolites, and mantle xenoliths: A review

NASA Astrophysics Data System (ADS)

Liou, Juhn G.; Tsujimori, Tatsuki; Yang, Jingsui; Zhang, R. Y.; Ernst, W. G.

2014-12-01

Newly recognized occurrences of ultrahigh-pressure (UHP) minerals including diamonds in ultrahigh-temperature (UHT) felsic granulites of orogenic belts, in chromitites associated with ophiolitic complexes, and in mantle xenoliths suggest the recycling of crustal materials through deep subduction, mantle upwelling, and return to the Earth's surface. This circulation process is supported by crust-derived mineral inclusions in deep-seated zircons, chromites, and diamonds from collision-type orogens, from eclogitic xenoliths in kimberlites, and from chromitities of several Alpine-Himalayan and Polar Ural ophiolites; some of these minerals contain low-atomic number elements typified by crustal isotopic signatures. Ophiolite-type diamonds in placer deposits and as inclusions in chromitites together with numerous highly reduced minerals and alloys appear to have formed near the mantle transition zone. In addition to ringwoodite and inferred stishovite, a number of nanometric minerals have been identified as inclusions employing state-of-the-art analytical tools. Reconstitution of now-exsolved precursor UHP phases and recognition of subtle decompression microstructures produced during exhumation reflect earlier UHP conditions. For example, Tibetan chromites containing exsolution lamellae of coesite + diopside suggest that the original chromitites formed at P > 9-10 GPa at depths of >250-300 km. The precursor phase most likely had a Ca-ferrite or a Ca-titanite structure; both are polymorphs of chromite and (at 2000 °C) would have formed at minimum pressures of P > 12.5 or 20 GPa respectively. Some podiform chromitites and host peridotites contain rare minerals of undoubted crustal origin, including zircon, feldspars, garnet, kyanite, andalusite, quartz, and rutile; the zircons possess much older U-Pb ages than the time of ophiolite formation. These UHP mineral-bearing chromitite hosts evidently had a deep-seated evolution prior to extensional mantle upwelling and partial

Tectonic exhumation and boundary structure of the Kokchetav HP - UHP metamorphic belt (Northern Kazakhstan): constraints from 40Ar/39Ar geochronology

NASA Astrophysics Data System (ADS)

Zhimulev, Fedor; de Grave, Johan; Travin, Aleksey; Buslov, Mikhail

2010-05-01

The Kokchetav metamorphic belt (KMB) is part of the Early Paleozoic orogenic belt of Northern Kazakhstan and constitutes one of the most famous, classical ultra-high pressure (UHP) metamorphic terranes. The KMB mainly consists of gneisses, mica schists and eclogites. These were formed by Cambrian continental subduction and associated metamorphism of the Precambrian Kokchetav microcontinent and subsequent exhumation of fragments of this metamorphosed continental crust. Several subterranes can be distinguished in the KMB: Barchi, Kumdi-Kol, Sulu-Tube, Enbek-Berlyk, Kulet and Borovoe. These subterranes differ not only in rock composition or in genetic pT conditions, but also in the age of the individual metamorphic events, including the timing of peak, and regressive stages. Most geochronological data indicate a Cambrian age of UHP and HP metamorphism and subsequent exhumation of the KMB. However, there is no field evidence of Cambrian geodynamic processes in the region: Cambrian sediments, volcanic rocks, or large magmatic bodies are completely absent in the KMB setting. The youngest geochronological information in the KMB was obtained on the garnet-mica schists from the Enbek-Berlyk subterrane. The 40Ar/39Ar ages of the muscovite from these schists lies in the range of 490 to 475 Ma (mainly 480-485 Ma). All 40Ar/39Ar stepwise heating experiments yield well-defined plateau and isochron ages. This age is considered to represent the time of emplacement of various heterogeneous nappes, including nappes that consist of HP - UHP metamorphic rocks, to upper crustal levels. To the north, the Kokchetav HP - UHP metamorphic belt is bounded by the Northern Kokchetav tectonic zone (NKTZ). This zone includes thin nappes of (1) Palaeo-Mesoproterozoic gneiss of the metamorphic basement of the Kokchetav microcontinent and Neoproterozoic meta-sandstones and dolomites of its deformed sedimentary cover, (2) pre-Ordovician volcanic rocks of island-arc affinity, (3) Early Ordovician

White mica K-Ar geochronology of HP-UHP units in the Lago di Cignana area, western Alps, Italy: Tectonic implications for exhumation

NASA Astrophysics Data System (ADS)

Gouzu, Chitaro; Yagi, Koshi; Thanh, Ngo Xuan; Itaya, Tetsumaru; Compagnoni, Roberto

2016-04-01

High-pressure and ultra-high pressure (HP-UHP) blueschist- and eclogite-facies metabasaltic and metasedimentary rocks occur in four different tectonic units near Lago di Cignana, western Alps. We have determined K-Ar ages for white micas (matrix phengite and paragonite) from the Lago di Cignana UHP unit (LCU; 39-41 Ma); the lower and upper units of the Zermatt-Saas meta-ophiolite (LU and UU; 37-38 Ma and 38-41 Ma respectively), and the Combin unit (CU; 36-40 Ma). These K-Ar ages overlap with single-grain Ar-Ar plateau ages (36-42 Ma) previously determined for phengites from LCU metasediments. Matrix white micas have been severely deformed during exhumation, and their chemistries differ from those of micas included in garnet. Although individual mica grains in the matrix could have experienced different degrees of deformation which have reset their K-Ar systems, "bulk" white mica separates provide the average age of all the individual grains in the separate. The similarity of ages determined for white micas from the LCU, LU, UU and CU units, regardless of rock type and mineral species, suggests that these four units were metamorphosed together as part of a single metamorphic sequence in the Piemonte-Liguria paleosubduction zone and were subsequently exhumed together. However, present-day structural relationship among those units and the limited occurrence of UHP minerals in LCU suggests that the exhumation of LCU was more rapid than that for LU, UU and CU. The age gaps between the youngest value of white mica K-Ar ages in each unit and the inferred timing of the metamorphic peak (U-Pb age: 44 Ma) is 5, 7, 6 and 8 Myr for LCU, LU, UU and CU, respectively. These intervals are considerably shorter than that determined for the Sanbagawa HP metamorphic belt of Southwest Japan (> 31 Myr). The short interval observed for the Lago di Cignana units that we have studied is consistent with the model of rapid exhumation of the UHP-bearing metamorphic domain, suggesting the

Partial melting of UHP calc-gneiss from the Dabie Mountains

NASA Astrophysics Data System (ADS)

Liu, Penglei; Wu, Yao; Liu, Qiang; Zhang, Junfeng; Zhang, Li; Jin, Zhenmin

2014-04-01

Exhumation melting has been proposed for the ultra-high pressure (UHP) metamorphic rocks in the Dabie Mountains based on melting experiments. We document here the first petrological and mineralogical evidence demonstrating that the UHP calc-gneisses from the Ganjialing area in the Dabie Mountains experienced partial melting during early exhumation. The assemblage of garnet, phengite (Si = 3.65 pfu), coesite, rutile and carbonate preserved in the calc-gneisses indicates a peak metamorphic condition of 692-757 °C and 4.0-4.8 GPa. Partial melting is indicated by several lines of evidence: the melting textures of phengite, the feldspar-dominated films, bands, branches, blebs and veins, the euhedral K-feldspars, the intergrowth film of plagioclase and K-feldspar, the plagioclase + biotite intergrowth after garnet and the epidote poikiloblasts. Polyphase inclusions in garnet are characterized with wedge-like offshoots and serrate outlines whereas those in epidote display negative crystal shapes, which can be best interpreted by entrapment of former melts. We propose a wet melting reaction of Phn + Q ± Na-Cpx + H2O = Bt + Pl + Grt + felsic melts, which likely took place at ca.650-800 °C and ca.1.0-2.0 GPa, to interpret the melting event in the calc-gneisses. Chemical exchanges between garnet and melts produced new garnet domains with higher almandine, spessartine, MREE, HREE and Y but lower grossular, pyrope, P, Sc, Ti, V and Zr contents. Zr-in-rutile thermometer reveals a low temperature of 620-643 °C at 5 GPa, indicating a later reset for Zr in rutile. Healed fractures are suggested to be responsible for the formation of some polyphase inclusions in garnet.

Stable Isotopes, Multidisciplinary Studies, and the Leadership of J.G. Liou in UHP Metamorphism

NASA Astrophysics Data System (ADS)

Rumble, D.

2005-12-01

J.G. Liou has played a crucial role in improving knowledge of UHP metamorphism by leading multi-disciplinary, multi-institutional teams of researchers and by encouraging new investigators and providing them access to samples. Stable isotope geochemistry has made important contributions to understanding UHP metamorphism including: (1) The discovery of O- and H-isotope signatures of meteoric water in UHP rocks from China and Kazakhstan demonstrates that their protoliths originated at or near Earth's surface in a cold climate(a); (2) The mapping of contiguous tracts of outcrops extending over distances of 100 km where both eclogites and their wall rocks retain unusually low d18O and dD is consistent with the subduction and exhumation of UHP slabs as coherent structural units(b); (3) Analysis of samples from the Chinese Continental Scientific Drilling project reveals not only that UHP metamorphic rocks have not exchanged O-isotopes with mantle rocks while they were buried in the upper mantle but also that garnet peridotite slabs from the mantle have not exchanged with crustal wall rocks(c). Recent advances have resulted from multidisciplinary geochemical investigations. The analysis of zircons for both d18O and U-Pb established the age of cold climate, meteoric water alteration of protoliths to be Neoproterozoic for UHP rocks from Dabie and Sulu, China(d). Thus, O-isotopes plus age dating raises the possibility that evidence of snowball Earth conditions has been preserved in an unlikely host: UHP metamorphic rocks. A comparison of U-Pb, Sm-Nd, and Rb-Sr isotope data with analyses for d18O in coexisting minerals shows that discordant age dates correlate with mineral pairs that are not in O-isotope exchange equilibrium(e). It may be seen that multidisciplinary geochemical investigations provide mutually reinforcing data that greatly strengthens interpretations. New discoveries of de novo microdiamonds accompanied by multiphase mineral inclusions in UHP metamorphosed

Geochronology of Zircon in Eclogite Reveals Imbrication of the Ultrahigh-Pressure Western Gneiss Region of Norway.

NASA Astrophysics Data System (ADS)

Young, D. J.; Kylander-Clark, A. R.; Root, D. B.

2014-12-01

Eclogite provides the only record of kinematic events at the deepest levels of orogens. Integrating the U-Pb geochronology and trace element chemistry of zircon in eclogite reveals the most complete view of the PTt history, yet low concentrations of uranium and zirconium and drier compositions that hinder zircon growth at peak conditions render it a challenging rocktype for this approach. The iconic Western Gneiss Region (WGR) in Norway is one of the largest terranes of deeply subducted continental rocks in the world, and contains many indicators of ultrahigh-pressure metamorphic conditions (P>2.8 GPa) that developed during the Siluro-Devonian Caledonian Orogeny. A metamorphic transition from amphibolite-facies to ultrahigh-pressure eclogite facies broadly coincides with a km-scale shear zone that underlies the majority of the WGR. A critical unknown is the timing of movement on this feature, which emplaced allochthonous units above the Baltica basement, but might also have accommodated late-orogenic exhumation of the WGR from mantle depths. We carried out laser ablation split-stream ICPMS (LASS) and selected multigrain TIMS analyses of zircons from eleven eclogites across the southern WGR, of which eight are located within or above the shear zone. LASS spots on polished grains mostly yield weakly discordant Proterozoic intrusive ages, and often minimal indication of a Caledonian (U)HP metamorphic overprint. Direct ablation into unpolished zircon reveals thin rims of Caledonian age in some cases. Overall, the dataset shows that all samples began zircon growth at approximately the same time (ca. 430-420 Ma). Eclogite from lower levels of the shear zone does not contain any dates younger than ca. 410 Ma, however, while eclogite from higher levels continued growth until ca. 400 Ma. We interpret this to result from thrusting of the WGR above cooler basement after 410 Ma, terminating new zircon crystallization within the shear zone but allowing limited further growth in

Genesis of ultra-high pressure garnet pyroxenites in orogenic peridotites and its bearing on the compositional heterogeneity of the Earth's mantle

NASA Astrophysics Data System (ADS)

Varas-Reus, María Isabel; Garrido, Carlos J.; Marchesi, Claudio; Bosch, Delphine; Hidas, Károly

2018-07-01

We present an integrated geochemical study of ultra-high pressure (UHP) garnet pyroxenites from the Ronda and Beni Bousera peridotite massifs (Betic-Rif Belt, westernmost Mediterranean). Based on their Sr-Nd-Pb-Hf isotopic systematics, we classify UHP garnet pyroxenites into three groups: Group A pyroxenites (Al2O3: 15-17.5 wt.%) have low initial 87Sr/86Sr, relatively high εNd, εHf and 206Pb/204Pb ratios, and variable 207Pb/204Pb and 208Pb/204Pb. Group B pyroxenites (Al2O3 < 14 wt.%) are characterized by high initial 87Sr/86Sr and relatively low εNd, εHf and 206Pb/204Pb ratios. Group C pyroxenites (Al2O3 ∼ 15 wt.%) have depleted radiogenic signatures with relatively low initial 87Sr/86Sr and 206Pb/204Pb, high εNd and εHf, and their 207Pb/204Pb and 208Pb/204Pb ratios are similar to those of Group B pyroxenites. The major and trace element and isotopic compositions of UHP garnet pyroxenites support their derivation from ancient (1.5-3.5 Ga) oceanic crust recycled into the mantle and intimately stirred with peridotites by convection. However, the genesis of these pyroxenites requires also the involvement of recycled continental lower crust with an isotopic composition akin to the lower crustal section of the lithosphere where these UHP garnet pyroxenites now reside in. These oceanic and continental crustal components were stirred in different proportions in the convective mantle, originating pyroxenites with a more marked geochemical imprint of either oceanic (Group A) or continental lower crust (Group B), or hybrid compositions (Group C). The pyroxenite protoliths likely underwent several melting events, one of them related to the formation of the subcontinental lithospheric mantle and continental crust, generating restitic UHP garnet pyroxenites now preserved in the Ronda and Beni Bousera orogenic peridotites. The extent of melting was mostly controlled by the bulk Mg-number (Mg#) of the pyroxenite protoliths, where protoliths with low Mg# experienced higher

Mantle wedge exhumation beneath the Dora-Maira (U)HP dome unravelled by local earthquake tomography (Western Alps)

NASA Astrophysics Data System (ADS)

Solarino, Stefano; Malusà, Marco G.; Eva, Elena; Guillot, Stéphane; Paul, Anne; Schwartz, Stéphane; Zhao, Liang; Aubert, Coralie; Dumont, Thierry; Pondrelli, Silvia; Salimbeni, Simone; Wang, Qingchen; Xu, Xiaobing; Zheng, Tianyu; Zhu, Rixiang

2018-01-01

In continental subduction zones, the behaviour of the mantle wedge during exhumation of (ultra)high-pressure [(U)HP] rocks provides a key to distinguish among competing exhumation mechanisms. However, in spite of the relevant implications for understanding orogenic evolution, a high-resolution image of the mantle wedge beneath the Western Alps is still lacking. In order to fill this gap, we perform a detailed analysis of the velocity structure of the Alpine belt beneath the Dora-Maira (U)HP dome, based on local earthquake tomography independently validated by receiver function analysis. Our results point to a composite structure of the mantle wedge above the subducted European lithosphere. We found that the Dora-Maira (U)HP dome lays directly above partly serpentinized peridotites (Vp 7.5 km/s; Vp/Vs = 1.70-1.72), documented from 10 km depth down to the top of the eclogitized lower crust of the European plate. These serpentinized peridotites, possibly formed by fluid release from the subducting European slab to the Alpine mantle wedge, are juxtaposed against dry mantle peridotites of the Adriatic upper plate along an active fault rooted in the lithospheric mantle. We propose that serpentinized mantle-wedge peridotites were exhumed at shallow crustal levels during late Eocene transtensional tectonics, also triggering the rapid exhumation of (U)HP rocks, and were subsequently indented under the Alpine metamorphic wedge in the early Oligocene. Our findings suggest that mantle-wedge exhumation may represent a major feature of the deep structure of exhumed continental subduction zones. The deep orogenic levels here imaged by seismic tomography may be exposed today in older (U)HP belts, where mantle-wedge serpentinites are commonly associated with coesite-bearing continental metamorphic rocks.

Foundering and Exhumation of UHP Terranes: Race Car or School Bus?

NASA Astrophysics Data System (ADS)

Kylander-Clark, A. R.; Hacker, B. R.

2008-12-01

Recent geochronologic data from the giant ultrahigh-pressure (UHP) terrane, in the Western Gneiss Region of Norway, indicate that subduction and exhumation were relatively slow (a few mm/yr), and that the terrane was exhumed to the surface as a relatively thick, coherent body. These conclusions are in stark contrast to those reached in previous studies of some of the best-studied, smaller UHP terranes and suggest that the processes that form and/or exhume small UHP terranes are fundamentally different from the processes that affect large UHP terranes. These differences may be the result of variations in the buoyancy forces of different proportions of subducted felsic crust, mafic crust, and mantle lithosphere. Initial collision occurs via the subduction of smaller portions of continental material, such as microcontinents or ribbon continents. Because the proportion of continental crust is small, the processes involved in early UHP terrane formation are dominated by the oceanic slab; subduction rates are fast because average plate densities are high, and, as a result, subduction angles are steep. Because these smaller, thinner portions of crust are weak, they deform easily and mix readily with the mantle. As the collision matures, thicker and larger portions of continental material-such as a continental margin-are subducted, and the subduction regime changes from one that was ocean dominated to one that is continent dominated. The increased buoyancy of the larger volume of continental crust resists the pull of the leading oceanic lithosphere; subduction shallows and plate rates slow. Because the downgoing continent is thick, it is strong, remains cohesive and has limited interaction with the mantle. Although the subduction regime during early orogenesis is distinct from that during late orogenesis, the degree of mountain building and crustal thickening may be similar in both stages as small volumes and fast flow rates of buoyant material give way to large volumes

Enhanced inactivation of foodborne pathogenic and spoilage bacteria by FD&C Red no. 3 and other xanthene derivatives during ultrahigh pressure processing.

PubMed

Waite, Joy G; Yousef, Ahmed E

2008-09-01

Variability among microorganisms in barotolerance has been demonstrated at genus, species, and strain levels. Identification of conditions and additives that enhance the efficacy of ultrahigh pressure (UHP) against important foodborne microorganisms is crucial for maximizing product safety and stability. Preliminary work indicated that FD&C Red No. 3 (Red 3), a xanthene derivative, was bactericidal and acted synergistically with UHP against Lactobacillus spp. The objective of this study was to determine the antimicrobial efficacy of Red 3 and other xanthene derivatives, alone and combined with UHP, against spoilage and pathogenic bacteria in citrate-phosphate buffer (pH 7.0). Xanthene derivatives tested were fluorescein, Eosin Y, Erythrosin B, Phloxine B, Red 3, and Rose Bengal. Halogenated xanthene derivatives (10 ppm) were effective at reducing Listeria monocytogenes survivors but ineffective against Escherichia coli O157:H7. When combined with UHP (400 MPa, 3 min), the presence of derivatives enhanced inactivation. Because Red 3 was the only xanthene derivative to produce synergistic inactivation of both pathogens, further studies using this colorant were warranted. Efficacy of Red 3 against gram-positive bacteria (Lactobacillus plantarum and L. monocytogenes) was concentration dependent (1 to 10 ppm). E. coi O157: H7 strains were resistant to Red 3 concentrations up to 300 ppm. When Red 3 was combined with UHP, the lethality against gram-positive and gram-negative bacteria was dose dependent, with synergy being significant for most strains at > or = 3 ppm. Additional gram-positive and gram-negative bacteria showed lethalities similar to those observed for L. plantarum or L. monocytogenes, and E. coli O157:H7, respectively. Red 3 is a potentially useful additive to enhance the safety and stability of UHP-treated food products.

Trace-element record in zircons during exhumation from UHP conditions, North-East Greenland Caledonides

USGS Publications Warehouse

McClelland, W.C.; Gilotti, J.A.; Mazdab, F.K.; Wooden, J.L.

2009-01-01

Coesite-bearing zircon formed at ultrahigh-pressure (UHP) conditions share general characteristics of eclogite-facies zircon with trace-element signatures characterized by depleted heavy rare earth elements (HREE), lack of an Eu anomaly, and low Th/ U ratios. Trace-element signatures of zircons from the Caledonian UHP terrane in North-East Greenland were used to examine the possible changes in signature with age during exhumation. Collection and interpretation of age and trace-element analyses of zircon from three samples of quartzofeldspathic gneiss and two leucocratic intrusions were guided by core vs. rim zoning patterns as imaged by cathodoluminesence. Change from igneous to eclogite-facies metamorphic trace-element signature in protolith zircon is characterized by gradual depletion of HREE, whereas newly formed metamorphic rims have flat HREE patterns and REE concentrations that are distinct from the recrystallized inherited cores. The signature associated with eclogite-facies metamorphic zircon is observed in coesite-bearing zircon formed at 358 ?? 4 Ma, metamorphic rims formed at 348 ?? 5 Ma during the initial stages of exhumation, and metamorphic rims formed at 337 ?? 5 Ma. Zircons from a garnet-bearing granite emplaced in the neck of an eclogite boudin and a leucocratic dike that cross-cuts amphibolite-facies structural fabrics have steeply sloping HREE patterns, variably developed negative Eu anomalies, and low Th/U ratios. The granite records initial decompression melting and exhumation at 347 ?? 2 Ma and later zircon rim growth at 329 ?? 5. The leucocratic dike was likely emplaced at amphibolite-facies conditions at 330 ?? 2 Ma, but records additional growth of compositionally similar zircon at 321 ??2 Ma. The difference between the trace-element signature of metamorphic zircon in the gneisses and in part coeval leucocratic intrusions indicates that the zircon signature varies as a function of lithology and context, thus enhancing its ability to aid in

Geology of ultra-high-pressure rocks from the Dabie Shan, Eastern China

NASA Astrophysics Data System (ADS)

Schmid, Robert

2001-02-01

A multidisciplinary study has been carried out to contribute to the understanding of the geologic evolution of the largest known occurrence of ultra-high-pressure (UHP) rocks on Earth, the Dabie Shan of eastern China. Geophysical data, collected along a ca. 20 km E-W trending seismic line in the eastern Dabie Shan, indicate that the crust comprises three layers. The upper crust has a homogeneously low reflectivity and exhibits roughly subhorizontal reflectors down to ca. 15 km. It is therefore interpreted to portray a crustal UHP slab thrust over non-UHP crust. An aprubt change in intensity and geometry of observed reflectors marks the boundary of a mid- to lower crustal zone which is present down to ca. 33 km. This crustal zone likely represents cratonal Yangtze crust that was unaffected by the Triassic UHP event and which has acted as the footwall during exhumation of the crustal wedge. Strong and continuous reflectors occurring at ca. 33-40 km depth most likely trace the Moho at the base of the crust. Any trace of a crustal root, that may have formed in response to collision tectonics, is therefore not preserved. A shollow tomographic velocity modell based on inversion of the first arrivals is constructed additionally. This model clearly images the distinct lithologies on both sides of the Tan Lu fault. Sediments to the east exhibit velocities of about 3.4 - 5.0 km* s^-1, whereas the gneisses have 5.2 - 6.0 km*s^-1. Geometry of velocity isolines may trace the structures present in the rocks. Thus the sediments dip shallowly towards the fault, whereas isoclinal folds are imaged to occur in the gneisses. Field data from the UHP unit of the Dabie Shan enables definition of basement-cover sequences that represent sections of the former passive margin of the Yangtze craton. One of the cover sequences, the Changpu unit, still displays a stratigraphic contact with basement gneisses, while the other, the Ganghe unit, includes no relative basement exposure. The latter

Processes in continental collision zones: Preface

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhang, Lifei; McClelland, William C.; Cuthbert, Simon

2012-04-01

Formation and exhumation of high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks in continental subduction zones are the two fundamental geodynamic aspects of collisional orogensis. This volume is based on the Session 08c titled "Geochemical processes in continental collision zones" at Goldschmidt 2010 in Knoxville, USA. It focuses on micro- to macro-scale processes that are temporally and spatially linked to different depths of crustal subduction/exhumation and associated mineralogical changes. They are a key to understanding a wide spectrum of phenomena, involving HP/UHP metamorphism and syn-/post-collisional magmatism. Papers in this volume report progresses in petrological, geochronological and geochemical studies of UHP metamorphic rocks and their derivatives in China, with tectonic settings varying from arc-continent collision to continent-continent collision. Microbeam in-situ analyses of metamorphic and magmatic minerals are successfully utilized to solve various problems in the study of continental deep subduction and UHP metamorphism. In addition to their geochronological applications to dating of HP to UHP metamorphic events during continental collision, microbeam techniques have also served as an efficient means to recognize different generations of mineral growth during continental subduction-zone metamorphism. Furthermore, metamorphic dehydration and partial melting of UHP metamorphic rocks during subduction and exhumation are highlighted with respect to their effects on fluid action and element mobilization. These have provided new insights into chemical geodynamics in continental subduction zones.

Serpentinite-driven Exhumation of the UHP Lago di Cignana Unit in the Fossil Alpine Plate Interface

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Gilio, M.; Angiboust, S.; Godard, M.; Pettke, T.

2015-12-01

The Lago di Cignana Unit (LCU) is a coesite- [1] and diamond-bearing [2] slice of oceanic-derived eclogites and metasediments recording Alpine UHP metamorphism at 600 °C-3.2 GPa (~110 km depth) [3]. The LCU is tectonically sandwiched between the eclogitic Zermatt-Saas Zone (ZSZ; 540 °C-3.2 GPa) [4] and the blueschist Combin Zone (400 °C-0.9 GPa) [5] along a tectonic structure joining HP units recording a ~1.2 GPa (40 km) pressure difference. So far, the ZSZ has been attributed to normal HP conditions and the mechanism driving exhumation and accretion of the LCU in its present structural position is not fully understood.We performed petrography and bulk-rock trace element analyses of rocks from LCU and ZSZ serpentinites. We observed that, while serpentinites in the core of the ZSZ show normal subduction zone trace elements and REE's patterns, the Ol+Ti-chu+Chl veins and host serpentinites enveloping the LCU are strongly enriched in sediment-derived fluid-mobile elements (U, Th, Nb, Ta, Ce, Y, As, Sb) and REE's: their patterns well match those of the closely associated LCU-UHP rocks.The presence of extremely enriched Ol+Ti-chu+Chl veins in the serpentinites at direct contact with the UHP Lago di Cignana Unit suggests that fluid exchange between serpentinite and LCU crustal rocks occurred at peak metamorphic conditions. Their coupling therefore occurred during subduction burial and/or peak UHP conditions. As such, the buoyancy force originating from the relatively light serpentinites fuelled the exhumation of the Lago di Cignana Unit. In this contest, the tectonic contact between the Zermatt-Saas Zone and the Combin Zone evolved into a true tectonic plate interface surface.1. Reinecke (1998). Lithos 42(3), 147-189; 2. Frezzotti et al. (2011). Nat. Geosci. 4(10), 703-706; 3. Groppo et al. (2009). J. Metam. Geol. 27(3), 207-231; 4. Angiboust et al. (2009). Terra Nova 21(3), 171-180; 5. Reddy et al. (1999). J. Metam. Geol. 17, 573-590.

Raman imaging of fluid inclusions in garnet from UHPM rocks (Kokchetav massif, Northern Kazakhstan).

PubMed

Korsakov, Andrey V; Dieing, Thomas; Golovin, Aleksandr V; Toporski, Jan

2011-10-01

Confocal Raman imaging of fluid inclusions in garnet porphyroblasts from diamond-grade metamorphic calc-silicate rocks from the Kumdy-Kol microdiamond deposit (Kokchetav Massif, Northern Kazakhstan) reveals that these fluid inclusions consist of almost pure water with different step-daughter phases (e.g., calcite, mica and rare quartz). These fluid inclusions are characterized by negative crystal shape of the host-garnet and they exclusively occur within the core of garnet porphyroblasts. These observations are consistent with their primary origin, most likely at ultrahigh-pressure (UHP) metamorphic conditions. The euhedral newly formed garnet, different in color and composition, was found to be associated with these fluid inclusions. It is proposed that newly formed garnet and water fluid inclusions appear by reaction between the hydrous fluid and the garnet-host. These fluid inclusions provide an unequivocal record of almost pure H(2)O fluids, indicating water-saturated conditions within subducted continental crust during prograde stage and/or ultrahigh-P metamorphism. Copyright © 2011 Elsevier B.V. All rights reserved.

Garnet from diamondiferous metamorphic rocks of Kokchetav massif, Kazakhstan as a peak pressure recorder

NASA Astrophysics Data System (ADS)

Sobolev, N. V.; Palyanov, Y. N.; Shatsky, V. S.; Sokol, A. G.; Tomilenko, A. A.

2003-12-01

Garnet is a key mineral coexisting with diamond both in kimberlite (as xenocrysts, in diamondiferous garnet peridotites and eclogites, as inclusions in diamond) and in UHP metamorphic rocks of Kokchetav massif (diamondiferous gneisses, garnet-pyroxene rocks, dolomitic marbles and diamond facies eclogites). In UHPM rocks garnets are of particular importance as inclusions in zircons protected from retrograde metamorphism. Diamond formation conditions in eclogitic (E-type) upper mantle environment are estimated based upon Grt-Cpx thermometry and coesite barometry (e.g. Sobolev et al., PNAS, 2000, 97:11875) at P=5.5-6.0 GPa and T=1000-1300° C. These data are supported by diamond synthesis in carbonate-silicate fluid (e.g. Palyanov et al., Nature, 1999, 400: 417). E-type garnet may dissolve up to 0.3 wt.% Na2O (Sobolev, Lavrentyev, Contr. Min. Petr., 1971, 31:1) depending on pressure and Na2O contents in coexisting pyroxene and melts (fluids). Majorite component (pyroxene solid solution) was reported in rare garnets from diamonds (e.g. Moore, Gurney, Nature, 1985, 318:553) and UHP conditions were experimentally confirmed for such garnets (Irifune, Phys. Eart. Pl. Int., 1987, 45:324; Gasparik, Phys. Chem. Min., 2002, 29:170; Luth, Am. Miner., 1997, 82:1198). Garnets from Kokchetav diamondiferous metamorphic rocks demonstrate considerably lower Na2O solubility (up to 0.2 wt.% in rare samples) and absence of majorite component. However, coexisting pyroxenes may contain up to 50 mol.% jadeite. Several UHP experiments performed with Kokchetav eclogites and dolomitic marbles using a split-sphere apparatus resulted in detection of up to 0.3-0.4 wt.% Na2O in newly formed eclogitic garnets at P=5.7 and 7.0 GPa, T=1400 and 1700° C respectively. Majorite component was also determined in newly formed garnets reaching about 5% with Si (pfu)=3.05-3.06. Similar garnets without Na2O were also obtained in UHP experiments with diamondiferous dolomitic marbles (e.g. Palyanov et al

Recent progress in recognition of UHP metamorphism in allochthons of the Scandinavian Caledonides (Seve Nappe Complex and Tromsø Nappe)

NASA Astrophysics Data System (ADS)

Janák, Marian; Ravna, Erling; Majka, Jarosław; Klonowska, Iwona; Kullerud, Kåre; Gee, David; Froitzheim, Nikolaus

2017-04-01

During the last ten years, UHP rocks have been discovered within far-travelled allochthons of the Scandinavian Caledonides including the Seve Nappe Complex (SNC) of the Middle Allochthon and Tromsø Nappe within the Uppermost Allochthon. The first evidence for UHP conditions in the SNC was documented in a kyanite-bearing eclogite dike within the Friningen garnet peridotite. Subsequently, UHP conditions were determined for phengite eclogite and garnet pyroxenite from Stor Jougdan and pelitic gneisses from Åreskutan. Finally, diamond was found in metasedimentary rocks of the SNC at three localities (Snasahögarna, Åreskutan and most recently near Saxnäs), c. 250 km apart, confirming regional UHP conditions within this allochthon. In the Tromsø Nappe (northern Norway), evidence for UHP metamorphism comes from phengite- and kyanite-bearing eclogites from Tønsvika and Tromsdalstind, and diamond-bearing gneisses from Tønsvika. Microdiamond occurs in-situ as single and composite (mostly with Mg-Fe carbonate) inclusions within garnet and zircon. The calculated P-T conditions for the diamond-bearing samples are 4.1-4.2 GPa/830-840°C (Åreskutan), and 3.5-4.0 GPa/ 750-800°C (Tønsvika), in the diamond stability field. The UHP metamorphism in the SNC and Tromsø Nappe is probably Late Ordovician (c. 460-450 Ma), i.e. c. 40-50 Ma older than that in the Western Gneiss Region of southwestern Norway. Whereas the latter occurred during the collision between Laurentia and Baltica in the Late Silurian to Early Devonian, the processes leading to Ordovician UHP metamorphism occurred during closure of the Iapetus Ocean and are less well understood. The occurrence of two UHP metamorphic events in the Scandinavian Caledonides implies subduction, exhumation, and re-subduction of continental crust. This is an observation that could be of importance for the understanding of orogeny at convergent plate boundaries in general. The following questions remain to be answered: (1) Was UHP

Subduction metamorphism in the Himalayan ultrahigh-pressure Tso Morari massif: An integrated geodynamic and petrological modelling approach

NASA Astrophysics Data System (ADS)

Palin, Richard M.; Reuber, Georg S.; White, Richard W.; Kaus, Boris J. P.; Weller, Owen M.

2017-06-01

The Tso Morari massif is one of only two regions where ultrahigh-pressure (UHP) metamorphism of subducted crust has been documented in the Himalayan Range. The tectonic evolution of the massif is enigmatic, as reported pressure estimates for peak metamorphism vary from ∼2.4 GPa to ∼4.8 GPa. This uncertainty is problematic for constructing large-scale numerical models of the early stages of India-Asia collision. To address this, we provide new constraints on the tectonothermal evolution of the massif via a combined geodynamic and petrological forward-modelling approach. A prograde-to-peak pressure-temperature-time (P-T-t) path has been derived from thermomechanical simulations tailored for Eocene subduction in the northwestern Himalaya. Phase equilibrium modelling performed along this P-T path has described the petrological evolution of felsic and mafic components of the massif crust, and shows that differences in their fluid contents would have controlled the degree of metamorphic phase transformation in each during subduction. Our model predicts that peak P-T conditions of ∼2.6-2.8 GPa and ∼600-620 ∘C, representative of 90-100 km depth (assuming lithostatic pressure), could have been reached just ∼3 Myr after the onset of subduction of continental crust. This P-T path and subduction duration correlate well with constraints reported for similar UHP eclogite in the Kaghan Valley, Pakistan Himalaya, suggesting that the northwest Himalaya contains dismembered remnants of what may have been a ∼400-km-long UHP terrane comparable in size to the Western Gneiss Region, Norway, and the Dabie-Sulu belt, China. A maximum overpressure of ∼0.5 GPa was calculated in our simulations for a homogeneous crust, although small-scale mechanical heterogeneities may produce overpressures that are larger in magnitude. Nonetheless, the extremely high pressures for peak metamorphism reported by some workers (up to 4.8 GPa) are unreliable owing to conventional thermobarometry

Petrology, geochemistry and isotope data on a ultrahigh-pressure jadeite quartzite from Shuanghe, Dabie Mountains, East-central China

NASA Astrophysics Data System (ADS)

Liou, J. G.; Zhang, R. Y.; Jahn, Bor-ming

1997-08-01

In the Dabie ultrahigh-pressure terrane of east-central China, coesite-bearing jadeite quartzites occur locally as intercalated layers with marble and mafic eclogite. This rock assemblage is, in turn, enclosed within quartzofeldspathic gneisses. Metamorphic parageneses and kelyphitic textures reveal a multistage metamorphic evolution and complex exhumation history. The primary peak metamorphic assemblage consists of jadeite + garnet + coesite + rutile ± apatite. Minor coesite and coesite pseudomorphs occur as inclusions in jadeite and garnet. Three stages of retrograde assemblages are observed in the jadeite quartzites. Stage A is represented by the polymorphic transformation of coesite to quartz aggregates. Stage B is characterized by formation of coronas around jadeite porphyroblasts consisting of an inner layer of oligoclase + amphibole and an outer layer of albite ± aegirine—augite. The last stage (stage C) involved total replacement of jadeite and most garnets by taramitic amphibole + albite + aegirine-augite. Peak metamorphic P-T conditions were > 26 kbar at 660°C and are consistent with the estimates from the adjacent coesite-bearing eclogites. The jadeite quartzites display clockwise P-T path that matches those of the adjacent eclogites. Major and trace element data suggest that the protolith of the jadeite quartzite could have been an albitized siltstone enriched in Na and depleted in K and Ca. The highly negative present-day ɛNd value (-24.7) indicates a very old age for the protolith. Its late Archean model age (TDM) of 2.58 Ga is among the oldest so far identified for rocks from the Dabie UHPM terrane. Concordant field relations and petrogenetic considerations suggest that all mafic, politic, carbonate and gneissic rocks have experienced in-situ UHP metamorphism during Triassic continental collision between the Sino-Korean and Yangtze cratons.

Nature and geodynamic setting of the protoliths of the UHP metamorphic Complex and migmatites in Bixiling area, the Dabie Orogen, China

NASA Astrophysics Data System (ADS)

Li, H.; Jahn, B.; Wang, D.; Yu, H.; Liu, Z.; Hou, G.

2013-12-01

As the largest coesite-bearing mafic-ultramafic body in the Dabie-Sulu orogen, the Bixiling Complex is composed of meta-ultramafic rocks, MgAl-rich eclogites and FeTi-rich eclogites. The FeTi-rich eclogites are further divided into low-Si-high-Fe type (Type I) and high-Si-low-Fe type (Type II) according to their mineral assemblages and bulk chemical composition. Field, petrographic, petrological and geochemical characteristics of these rocks, although suffered an ultra-high pressure metamorphism, still show a magmatic differentiation process among the protoliths of the meta-ultramafic rocks, MgAl-rich eclogites and Type I FeTi-rich eclogites. A small degree of lower crustal contamination occurred during their magma chamber process. Amphibolite is widespread in the periphery of the complex. Non-foliation and fine-grained texture are their obvious characteristics. Geochemical and isotopic affinities suggest that the amphibolites represent a product of complete retrogression from type II FeTi-rich eclogites. The UHP complex is enclosed in granitic gneisses, which variably include two-mica plagioclase gneiss, epidote two-mica plagioclase gneiss, or white-mica plagioclase gneiss. They all show TTG, especially trondjhemitic composition. A migmatite outcrop was found near the northeastern end of the complex. The migmatites consist of dark colored, non-foliated amphibolites and light-colored, fine-grained trondhjemitic gneisses. Field occurrences, microstructures observed under optical microscope and SEM, Sr-Nd isotopic data suggest an origin of partial melting. Chemical composition of two stages of amphiboles occurred in both the amphibolites and the trondhjemitic gneisses also imply a partial melting process occurred. Trace element, Sr-Nd isotope and SHRIMP zircon U-Pb dating of MgAl-rich eclogite, amphibolites and trondhjemite suggest that the migmatites represent a partial melting of crustal materials at about 780Ma, possibly accompanied by the coeval emplacement of a

Genesis of Ultra-High Pressure Garnet Pyroxenite in Orogenic Peridotites and its bearing on the Isotopic Chemical Heterogeneity in the Mantle Source of Oceanic Basalts

NASA Astrophysics Data System (ADS)

Varas Reus, María Isabel; Garrido, Carlos J.; Marchesi, Claudio; Bosch, Delphine; Hidas, Károly

2017-04-01

The genesis of ultra-high pressure (UHP) garnet pyroxenites in orogenic peridotite massifs and its implications on the formation of chemical heterogeneities in the mantle and on basalt petrogenesis are still not fully understood. Some UHP (diamond-bearing) garnet pyroxenites have isotopic, and major and trace element compositions similar to the recycled oceanic crustal component observed in oceanic basalts [1-6]. These pyroxenites hence provide an exceptional opportunity to investigate in situ the nature and scale of the Earth's mantle chemical heterogeneities. Here, we present an integrated geochemical study of UHP garnet pyroxenites from the Ronda (Betic Belt, S. Spain) and Beni Bousera (Rif Belt, N. Morocco) peridotite massifs. This investigation encompasses, in the same sample, bulk rock major and trace elements, as well as Sr-Nd-Pb-Hf isotopic analyses. According to their Al2O3 content, we classify UHP garnet pyroxenites into three groups that have distinct trace elements and Sr-Nd-Pb-Hf isotopic signatures. Group A pyroxenites (Al2O3: 15 - 17.5 wt. %) are characterized by low initial 87Sr/86Sr, relatively high 143Nd/144Nd, 206Pb/204Pb and 176Hf/177Hf ratios, and highly variable 207Pb/204Pb and 208Pb/204Pb ratios. Group B pyroxenites (Al2O3 < 14 wt. %) have isotopic signatures characterized by relatively high initial 87Sr/86Sr and low 143Nd/144Nd, 206Pb/204Pb and 176Hf/177Hf ratios. Group C pyroxenites (Al2O3 ˜ 15 wt. %) display relatively low initial 87Sr/86Sr and 206Pb/204Pb ratios, high 143Nd/144Nd and 176Hf/177Hf ratios, and 207Pb/204Pb and 208Pb/204Pb ratios similar to Group B pyroxenites. The major and trace element, and isotopic compositions of the studied Ronda and Beni Bousera UHP garnet pyroxenites lend support to the "Marble Cake Mantle" model [7] for the genesis of these pyroxenites. This model envisions the mantle source of oceanic basalts as a mélange of subducted, ancient oceanic crust —-represented by garnet pyroxenites in orogenic

Magnetic susceptibility of ultrahigh pressure eclogite: The role of retrogression

NASA Astrophysics Data System (ADS)

Xu, Haijun; Jin, Zhenmin; Mason, Roger; Ou, Xingong

2009-09-01

Retrograde metamorphism played the dominant role in changing the low-field rock magnetic properties and density of 198 specimens of variably retrograded eclogites from the main borehole of the Chinese Continental Scientific Drilling Project (CCSD) and from surface outcrops in the Donghai area in the southern part of the Sulu UHP belt, China. Bulk magnetic susceptibility ( κ) of unretrogressed UHP eclogite is controlled by whole-rock chemical composition and ranges from 397 to 2312 μSI with principal magnetic susceptibility carrying minerals paramagnetic garnet, omphacite, rutile and phengite. Partially retrograded eclogites show large variations in magnetic susceptibility between 804 and 24,277 μSI, with high mean magnetic susceptibility values of 4372 ± 4149 μSI caused by appreciable amounts of Fe-Ti oxide minerals such as magnetite, ilmenite and/or titanohematite produced by retrograde metamorphic reactions. Completely retrograded eclogites have lower susceptibilities of 1094 ± 600 μSI and amphibolite facies mineral assemblages lacking high magnetic susceptibility minerals. Jelínek's corrected anisotropy ( Pj) of eclogites ranges from 1.001 to 1.540, and shows a positive correlation with low-field magnetic susceptibility ( κ). Arithmetic mean bulk density ( ρ) shows a steady decrease from 3.54 ± 0.11 g/cm 3 (fresh eclogite) to 2.98 ± 0.06 g/cm 3 (completely retrograded eclogite). Retrograde metamorphic changes in mineral composition during exhumation appear to be the major factor causing variations in low field magnetic susceptibility and anisotropy. Retrograde processes must be taken into account when interpreting magnetic surveys and geophysical well logs in UHP metamorphic terranes, and petrophysical properties such as density and low-field magnetic susceptibility could provide a means for semi-quantifying the degree of retrogression of eclogite during exhumation.

SHRIMP U-Pb dating, trace elements and the Lu-Hf isotope system of coesite-bearing zircon from amphibolite in the SW Sulu UHP terrane, eastern China

NASA Astrophysics Data System (ADS)

Liu, Fulai; Gerdes, Axel; Zeng, Lingsen; Xue, Huaimin

2008-06-01

In this study, we link mineral inclusion data, trace element analyses, U-Pb age and Hf isotope composition obtained from distinct zircon domains of complex zircon to unravel the origin and multi-stage metamorphic evolution of amphibolites from the Sulu ultrahigh-pressure (UHP) terrane, eastern China. Zircon grains separated from amphibolites from the CCSD-MH drill hole (G12) and Niushan outcrop (G13) were subdivided into two main types based on cathodoluminescence (CL) and Laser Raman spectroscopy: big dusty zircons with inherited cores and UHP metamorphic rims and small clear zircons. Weakly zoned, grey-white luminescent inherited cores preserve mineral inclusions of Cpx + Pl + Ap ± Qtz indicative of a mafic igneous protolith. Dark grey luminescent overgrowth rims contain the coesite eclogite-facies mineral inclusion assemblage Coe + Grt + Omp + Phe + Ap, and formed at T = 732-839 °C and P = 3.0-4.0 GPa. In contrast, white luminescent small clear zircons preserve mineral inclusions formed during retrograde HP quartz eclogite to LP amphibolite-facies metamorphism (T = 612-698 °C and P = 0.70-1.05 GPa). Inherited zircons from both samples yield SHRIMP 206Pb/238U ages of 695-520 Ma with an upper intercept age of 800 ± 31 Ma. The UHP rims yield consistent Triassic ages around 236-225 and 239-225 Ma for G12 and G13 with weighted means of 229 ± 3 and 231 ± 3 Ma, respectively. Small clear zircons from both samples give 206Pb/238U ages around 219-210 Ma with a weighted mean of 214 ± 3 Ma, interpreted as the age of retrograde quartz eclogite-facies metamorphism. Matrix amphibole from both samples indicate Ar-Ar ages of 209 ± 0.7 and 207 ± 0.7 Ma, respectively, probably dating late amphibolite-facies retrogression. The data suggest subduction of Neoproterozoic mafic igneous rocks to UHP conditions in Middle Triassic (∼230 Ma) times and subsequent exhumation to an early HP (∼214 Ma) and a late LP stage (∼208 Ma) over a period of ∼16 and 6 Myr, respectively

Protracted or multiple subduction of metapelites (Rhodope UHP domain, Greece)?

NASA Astrophysics Data System (ADS)

Krohe, A.; Wawrzenitz, N. H.; Mposkos, E.; Romer, R. L.

2012-12-01

The Rhodope domain formed along the suture between the European and the Apulian/Adriatic plate, which collided in the early Tertiary (closure of the Vardar/Axios ocean). Its metamorphic history includes UHP metamorphism documented by diamond inclusions in garnet (Mposkos & Kostopoulos 2001, Perraki et al. 2006, Schmidt et al. 2010), presumably of Jurassic age, and Eocene stages of MP and HP metamorphism. The age of UHPM is still a matter of debate: U-Pb SHRIMP ages extend from 184-172 Ma (monazite in metapelites) to ca. 42 Ma with clusters at 170-160, 150-140, 80-60, 50, 42 Ma, (U-Pb SHRIMP dating of zircon from amphibolitized eclogites and metapelites). These ages are interpreted to date subsequent stages of (U)HP metamorphism and decompression (Liati et al., 2005, Hoinkes et al. 2008, Bauer et al. 2006, Krenn et al 2010). However, these ages are obviously difficult to link with the metamorphic reactions. The metamorphic history has been interpreted in different ways, reflecting: (i) successive accretion of small terranes with rapid subduction and uplift histories (e.g. Liati et al. 2005); (ii) a composite of different tectonic units varying in earlier P-T histories, assembled by shear zones that reflect tectonic erosion and differential exhumation along the plate interface and that are now erased and overprinted (Krohe and Mposkos, 2002, Mposkos et al., 2010). These interpretations imply a different kinematics of the tectonic movements at depths, mechanical processes and process rates. Additionally, a protracted polymetamorphic history of larger volumes of the Rhodope UHP domain may be considered; e.g. the Kimi complex stayed in the lower crust for ca. 50-60 Ma after exhumation of the UHP rocks to this lower crustal level (Mposkos and Krohe, 2006). To constrain a precise age of the HP granulite facies and a minimum age of UHP metamorphism, we conduct an integrated structural, petrologic and geochronological study in a metapelite from the Sidronero Complex. The

Multi-stage barites in partially melted UHP eclogite: implications for fluid/melt activities during deep continental subduction in the Sulu orogenic belt

NASA Astrophysics Data System (ADS)

Wang, Songjie; Wang, Lu

2015-04-01

Barite (BaSO4) is well-known from deep-sea sedimentary environments but has received less attention to its presence in high-grade metamorphic rocks. Recently, barite in ultrahigh pressure (UHP) eclogite has drawn increasing attention from geologists, especially in the Dabie-Sulu orogen, since it is an important indicator for high-salinity fluid events, thus aiding in further understanding HP-UHP fluid / melt evolution. However, its formation time and mechanism in UHP eclogite are still controversial, with three representative viewpoints: (1) Liu et al. (2000) found barite-anhydrite-coesite inclusions in zircon and interpreted them to have formed by UHP metamorphic fluids; (2) Zeng et al. (2007) recognized isolated barite within K-feldspar (Kfs) and Quartz (Qz) surrounded by radial cracks in omphacite, and interpreted Kfs+Qz to be reaction products of potassium-rich fluid/melt and coesite, with the barite formed by prograde metamorphic fluids; (3) Gao et al. (2012) and Chen et al. (2014) found barite-bearing Multiphase Solid (MS) inclusions within garnet and omphacite and assumed that the barite formed by phengite breakdown possibly caused by eclogite partial melting during exhumation, though no direct evidence were proposed. The controversy above is mainly due to the lack of direct formation evidence and absence of a clear link with the metamorphic evolution of UHP eclogite along the subduction-exhumation path. We report detailed petrological and micro-structural analyses revealing four types of barites clearly linked with (1) the prograde, (2) earlier stage of partial melting and (3) later stage of crystallization differentiation, as well as (4) high-grade amphibolite-facies retrogression of a deeply subducted and partially melted intergranular coesite-bearing eclogite from Yangkou Bay, Sulu Orogen. Round barite inclusions (type-I) within UHP-stage garnet and omphacite are formed by internally buffered fluids from mineral dehydration during prograde metamorphism

U-Pb zircon geochronology and Zr-in-rutile thermometry of eclogites from the Dulan area, North Qaidam ultra-high pressure (UHP) terrane, western China

NASA Astrophysics Data System (ADS)

Hernández Uribe, D.; Stubbs, K.; Lehman, M. R.; Gilmore, V.; Kylander-Clark, A. R.; Mattinson, C. G.

2016-12-01

The Dulan area, in the North Qaidam terrane, exposes UHP eclogites and gneisses that experienced a 20 Myr UHP event at P-T conditions of 30 kbar and 700 °C. Two eclogites were analyzed using Zr-in-rutile thermometry and zircon U-Pb + trace element analysis to constrain the metamorphic evolution of the area. A kyanite-phengite eclogite presents a mineral assemblage of grt + omp + ph + ky + rt + zo + qz. Rutile analyses show a Zr concentration of 173-250 ppm with a mean of 207 ± 19 ppm. The calculated temperatures yielded 685-716 °C with an average of 700 ± 7°C. Zircon U-Pb analyses gave an upper intercept age of 880 ± 89 Ma. These analyses from cathodoluminiscence (CL)-dark core zircons show a negative Eu anomaly and a steep HREE slope suggesting a magmatic origin for the protolith. Analyses from CL-bright rims gave a weighted mean age of 427 ± 2 Ma. These zircons show an eclogite facies trace elements pattern suggesting that the age represent the HP-UHP event. Titanium concentration in zircons gave a weighted mean of 4.41 ± 0.25 ppm. This Ti concentration yielded a calculated temperature of 674 °C A phengite eclogite shows a mineral assemblage of grt + omp + ph + rt + zo + qz. Rutile in matrix analyses show a Zr concentration of 123-161 ppm with a mean of 139 ± 9 ppm. Calculated temperatures for these rutiles ranges from 659-680 °C with a mean temperature of 668 ± 5 °C. U-Pb analyses from CL-dark zircon cores gave a weighted mean age of 844 ± 7 Ma. These zircons show a negative Eu anomaly and a steep HREE slope suggesting a magmatic origin for the protolith. Analyses from CL-grey rims gave a weighted mean age of 433 ± 4 Ma. These zircons show an eclogite facies trace elements pattern, representing the timing of the HP-UHP event. Titanium concentration in zircons gave a weighted mean of 3.13 ± 0.34 ppm. This concentration yielded calculated temperature 647 °C. The obtained ages are in the same range as the ones obtained for the northern and southern

Ultrahigh pressure extraction of bioactive compounds from plants-A review.

PubMed

Xi, Jun

2017-04-13

Extraction of bioactive compounds from plants is one of the most important research areas for pharmaceutical and food industries. Conventional extraction techniques are usually associated with longer extraction times, lower yields, more organic solvent consumption, and poor extraction efficiency. A novel extraction technique, ultrahigh pressure extraction, has been developed for the extraction of bioactive compounds from plants, in order to shorten the extraction time, decrease the solvent consumption, increase the extraction yields, and enhance the quality of extracts. The mild processing temperature of ultrahigh pressure extraction may lead to an enhanced extraction of thermolabile bioactive ingredients. A critical review is conducted to introduce the different aspects of ultrahigh pressure extraction of plants bioactive compounds, including principles and mechanisms, the important parameters influencing its performance, comparison of ultrahigh pressure extraction with other extraction techniques, advantages, and disadvantages. The future opportunities of ultrahigh pressure extraction are also discussed.

Role of DNA protection and repair in resistance of Bacillus subtilis spores to ultrahigh shock pressures simulating hypervelocity impacts.

PubMed

Moeller, Ralf; Horneck, Gerda; Rabbow, Elke; Reitz, Günther; Meyer, Cornelia; Hornemann, Ulrich; Stöffler, Dieter

2008-11-01

Impact-induced ejections of rocks from planetary surfaces are frequent events in the early history of the terrestrial planets and have been considered as a possible first step in the potential interplanetary transfer of microorganisms. Spores of Bacillus subtilis were used as a model system to study the effects of a simulated impact-caused ejection on rock-colonizing microorganisms using a high-explosive plane wave setup. Embedded in different types of rock material, spores were subjected to extremely high shock pressures (5 to 50 GPa) lasting for fractions of microseconds to seconds. Nearly exponential pressure response curves were obtained for spore survival and linear dependency for the induction of sporulation-defective mutants. Spores of strains defective in major small, acid-soluble spore proteins (SASP) (alpha/beta-type SASP) that largely protect the spore DNA and spores of strains deficient in nonhomologous-end-joining DNA repair were significantly more sensitive to the applied shock pressure than were wild-type spores. These results indicate that DNA may be the sensitive target of spores exposed to ultrahigh shock pressures. To assess the nature of the critical physical parameter responsible for spore inactivation by ultrahigh shock pressures, the resulting peak temperature was varied by lowering the preshock temperature, changing the rock composition and porosity, or increasing the water content of the samples. Increased peak temperatures led to increased spore inactivation and reduced mutation rates. The data suggested that besides the potential mechanical stress exerted by the shock pressure, the accompanying high peak temperatures were a critical stress parameter that spores had to cope with.

Microbial diversity in ultra-high-pressure rocks and fluids from the Chinese Continental Scientific Drilling Project in China.

PubMed

Zhang, Gengxin; Dong, Hailiang; Xu, Zhiqin; Zhao, Donggao; Zhang, Chuanlun

2005-06-01

Microbial communities in ultra-high-pressure (UHP) rocks and drilling fluids from the Chinese Continental Scientific Drilling Project were characterized. The rocks had a porosity of 1 to 3.5% and a permeability of approximately 0.5 mDarcy. Abundant fluid and gas inclusions were present in the minerals. The rocks contained significant amounts of Fe2O3, FeO, P2O5, and nitrate (3 to 16 ppm). Acridine orange direct counting and phospholipid fatty acid analysis indicated that the total counts in the rocks and the fluids were 5.2 x 10(3) to 2.4 x 10(4) cells/g and 3.5 x 10(8) to 4.2 x 10(9) cells/g, respectively. Enrichment assays resulted in successful growth of thermophilic and alkaliphilic bacteria from the fluids, and some of these bacteria reduced Fe(III) to magnetite. 16S rRNA gene analyses indicated that the rocks were dominated by sequences similar to sequences of Proteobacteria and that most organisms were related to nitrate reducers from a saline, alkaline, cold habitat; however, some phylotypes were either members of a novel lineage or closely related to uncultured clones. The bacterial communities in the fluids were more diverse and included Proteobacteria, Bacteroidetes, gram-positive bacteria, Planctomycetes, and Candidatus taxa. The archaeal diversity was lower, and most sequences were not related to any known cultivated species. Some archaeal sequences were 90 to 95% similar to sequences recovered from ocean sediments or other subsurface environments. Some archaeal sequences from the drilling fluids were >93% similar to sequences of Sulfolobus solfataricus, and the thermophilic nature was consistent with the in situ temperature. We inferred that the microbes in the UHP rocks reside in fluid and gas inclusions, whereas those in the drilling fluids may be derived from subsurface fluids.

Microbial Diversity in Ultra-High-Pressure Rocks and Fluids from the Chinese Continental Scientific Drilling Project in China

PubMed Central

Zhang, Gengxin; Dong, Hailiang; Xu, Zhiqin; Zhao, Donggao; Zhang, Chuanlun

2005-01-01

Microbial communities in ultra-high-pressure (UHP) rocks and drilling fluids from the Chinese Continental Scientific Drilling Project were characterized. The rocks had a porosity of 1 to 3.5% and a permeability of ∼0.5 mDarcy. Abundant fluid and gas inclusions were present in the minerals. The rocks contained significant amounts of Fe2O3, FeO, P2O5, and nitrate (3 to 16 ppm). Acridine orange direct counting and phospholipid fatty acid analysis indicated that the total counts in the rocks and the fluids were 5.2 × 103 to 2.4 × 104 cells/g and 3.5 × 108 to 4.2 × 109 cells/g, respectively. Enrichment assays resulted in successful growth of thermophilic and alkaliphilic bacteria from the fluids, and some of these bacteria reduced Fe(III) to magnetite. 16S rRNA gene analyses indicated that the rocks were dominated by sequences similar to sequences of Proteobacteria and that most organisms were related to nitrate reducers from a saline, alkaline, cold habitat; however, some phylotypes were either members of a novel lineage or closely related to uncultured clones. The bacterial communities in the fluids were more diverse and included Proteobacteria, Bacteroidetes, gram-positive bacteria, Planctomycetes, and Candidatus taxa. The archaeal diversity was lower, and most sequences were not related to any known cultivated species. Some archaeal sequences were 90 to 95% similar to sequences recovered from ocean sediments or other subsurface environments. Some archaeal sequences from the drilling fluids were >93% similar to sequences of Sulfolobus solfataricus, and the thermophilic nature was consistent with the in situ temperature. We inferred that the microbes in the UHP rocks reside in fluid and gas inclusions, whereas those in the drilling fluids may be derived from subsurface fluids. PMID:15933024

The timing of eclogite facies metamorphism and migmatization in the Orlica–Śnieżnik complex, Bohemian Massif: Constraints from a multimethod geochronological study

USGS Publications Warehouse

Brocker, M.; Klemd, R.; Cosca, M.; Brock, W.; Larionov, A.N.; Rodionov, N.

2009-01-01

The Orlica–Śnieżnik complex (OSC) is a key geological element of the eastern Variscides and mainly consists of amphibolite facies orthogneisses and metasedimentary rocks. Sporadic occurrences of eclogites and granulites record high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic conditions. A multimethod geochronological approach (40Ar–39Ar, Rb–Sr, Sm–Nd, U–Pb) has been used to gain further insights into the polymetamorphic evolution of eclogites and associated country rocks. Special attention was given to the unresolved significance of a 370- to 360 Ma age group that was repeatedly described in previous studies. Efforts to verify the accuracy of c.370 Ma K–Ar phengite and biotite dates reported for an eclogite and associated country-rock gneiss from the location Nowa Wieś suggest that these dates are meaningless, due to contamination with extraneous Ar. Extraneous Ar is also considered to be responsible for a significantly older 40Ar–39Ar phengite date of c. 455 Ma for an eclogite from the location Wojtowka. Attempts to further substantiate the importance of 370–360 Ma zircon dates as an indicator for a melt-forming high-temperature (HT) episode did not provide evidence in support of anatectic processes at this time. Instead, SHRIMP U–Pb zircon dating of leucosomes and leucocratic veins within both orthogneisses and (U)HP granulites revealed two age populations (490–450 and 345–330 Ma respectively) that correspond to protolith ages of the magmatic precursors and late Variscan anatexis. The results of this study further underline the importance of Late Carboniferous metamorphic processes for the evolution of the OSC that comprise the waning stages of HP metamorphism and lower pressure HT overprinting with partial melting. Eclogites and their country rocks provided no chronometric evidence for an UHP and ultrahigh-temperature episode at 387–360 Ma, as recently suggested for granulites from the OSC, based on Lu–Hf garnet

Deformation and Metasomatic Evolution at the Subduction Plate Interface As Viewed from Study of HP/UHP Metamorphic Rocks

NASA Astrophysics Data System (ADS)

Bebout, G. E.; Penniston-Dorland, S.

2014-12-01

We provide a view of lithologic makeup, deformation, and fluid-rock interaction along the deep forearc to subarc plate interface, based on insights gained from study of HP/UHP metamorphic rocks. Exposures of plate-boundary shear zones on which we base our perspective represent 30-80 km depths and are on Catalina Island and at Monviso, Syros, and New Caledonia. Each contains highly deformed zones with schistose matrix, commonly with a large ultramafic component, containing bodies of less deformed mafic, sedimentary, and ultramafic rocks. These "blocks" have varying geometries, are up to km-scale, and can preserve disparate P-T histories reflecting dynamics of incorporation and entrainment. Sheared matrices contain high-variance, hydrous mineral assemblages in some cases resembling metasomatic zones ("rinds") at block-matrix contacts, and rinds and matrices have homogenized isotopic compositions reflecting extensive fluid-rock interaction. Shearing and related physical juxtaposition of disparate metasomatic rocks can result in mixed or 'hybrid' chemical compositions. The chlorite-, talc-, and amphibole-rich schists developed by these processes can stabilize H2O to great depth and influence its cycling. Fluids (hydrous fluids, silicate melts) released within slabs necessarily interact with highly deformed, lithologically hybridized zones at the plate interface as they ascend to potentially enter mantle wedges. Fluids bearing chemical/isotopic signatures of hybrid rocks appear capable of producing arc magma compositions interpreted as reflecting multiple, chemically distinct fluids sources. Geophysical signatures of these rheologically weak zones are equivocal but many recognize the presence of zones of low seismic velocity at/near the top of slabs and attribute them to hydrated rocks. Whether rocks from this interface buoyantly ascend into mantle wedges, indicated in some theoretical models, remains largely untested by field and geophysical observations.

Large-Scale, Long-Lived Subduction of Ultrahigh-Pressure Terranes: Western Gneiss Region, Norway

NASA Astrophysics Data System (ADS)

Kylander-Clark, A. R.; Hacker, B. R.; Johnson, C. M.; Beard, B. L.; Corfu, F.; Mahlen, N. J.

2007-12-01

Recent Lu-Hf and Sm-Nd ages of garnets and a U-Pb age of zircon of eclogites from the Western Gneiss Region (WGR) ultrahigh-pressure (UHP) terrane, Norway, demonstrate that eclogite-facies metamorphism occurred over a large area (60,000 km2) for an unexpectedly long time. This observation stands in stark contrast to the general belief that continental subduction, and attendant (U)HP metamorphism, occurs over short timescales. Four HP eclogites (~700-800°C, ~2.0-2.5 GPa) from the central WGR yielded equivalent Lu-Hf ages of ~416 Ma; three of these samples gave Sm-Nd ages of ~400 Ma. Given the distribution coefficients for Lu and Sm, the older Lu-Hf ages reflect prograde growth, but are younger than the initiation of garnet crystallization. The younger Sm-Nd ages represent either eclogite-facies cooling through the blocking temperature of the Sm-Nd system or an 'average' age of garnet growth. Both cases imply >16 m.y. of eclogite- facies conditions. Two UHP eclogites (~750-850°C, ~3 GPa) from the same region yielded significantly younger, but equivalent Lu-Hf and Sm-Nd ages of ~380 Ma, which likely indicate passage through the blocking temperature of both systems up to 20 m.y. after the HP eclogites had passed through the blocking temperature. Because these eclogites are unretrogressed, their ages are the youngest known for eclogite stability in the WGR. An eclogite from the northern WGR yielded a Sm-Nd age of 413.9 ± 3.7 Ma. This could represent a different HP history than that of the central WGR: U/Pb ages in the north are also ~15 m.y. older. Two HP (~650°C, ~2 GPa) eclogites from the southern WGR yielded Lu-Hf ages of 410.2 ± 3.1 and 427.5 ± 7.7 Ma, indicating a similar garnet growth history to the central WGR eclogites. A retrogressed eclogite from the undated eastern portion of the WGR gave a 206Pb/238U age of 408.0 ± 1.7 Ma. Thermal models mirror results from similar studies (Roselle et al., 2002), and confirm that slow subduction likely produced the P

Dual sources of water overprinting on the low zircon δ18O metamorphic country rocks: Disequilibrium constrained through inverse modelling of partial reequilibration

PubMed Central

Wei, Chun-Sheng; Zhao, Zi-Fu

2017-01-01

Since water is only composed of oxygen and hydrogen, δ18O and δ2H values are thus utilized to trace the origin of water(s) and quantify the water-rock interactions. While Triassic high pressure (HP) and ultrahigh pressure (UHP) metamorphic rocks across the Dabie-Sulu orogen in central-eastern China have been well documented, postcollisional magmatism driven hydrothermal systems are little known. Here we show that two sources of externally derived water interactions were revealed by oxygen isotopes for the gneissic country rocks intruded by the early Cretaceous postcollisional granitoids. Inverse modellings indicate that the degree of disequilibrium (doD) of meteoric water interactions was more evident than that of magmatic one (−65 ± 1o vs. −20 ± 2°); the partial reequilibration between quartz and alkali feldspar oxygen isotopes with magmatic water was achieved at 340 °C with a water/rock (W/R) ratio of about 1.2 for an open-hydrothermal system; two-stage meteoric water interactions were unraveled with reequilibration temperatures less than 300 °C and W/R ratios around 0.4. The lifetime of fossil magmatic hydrothermal system overprinted on the low zircon δ18O orthogneissic country rocks was estimated to maintain up to 50 thousand years (Kyr) through oxygen exchange modellings. Four-stage isotopic evolutions were proposed for the magmatic water interacted gneiss. PMID:28091552

Exhumation of high-pressure rocks beneath the Solund Basin, Western Gneiss Region of Norway

USGS Publications Warehouse

Hacker, B.R.; Andersen, T.B.; Root, D.B.; Mehl, L.; Mattinson, J.M.; Wooden, J.L.

2003-01-01

The Solund-Hyllestad-Lavik area affords an excellent opportunity to understand the ultrahigh-pressure Scandian orogeny because it contains a near-complete record of ophiolite emplacement, high-pressure metamorphism and large-scale extension. In this area, the Upper Allochthon was intruded by the c. 434 Ma Sogneskollen granodiorite and thrust eastward over the Middle/Lower Allochthon, probably in the Wenlockian. The Middle/Lower Allochthon was subducted to c. 50 km depth and the structurally lower Western Gneiss Complex was subducted to eclogite facies conditions at c. 80 km depth by c. 410-400 Ma. Within 100. Exhumation to upper crustal levels was complete by c. 403 Ma. The Solund fault produced the last few km of tectonic exhumation, bringing the near-ultrahigh-pressure rocks to within c. 3 km vertical distance from the low-grade Solund Conglomerate.

Crustal structure and continental dynamics of Central China: A receiver function study and implications for ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

He, Chuansong; Dong, Shuwen; Chen, Xuanhua; Santosh, M.; Li, Qiusheng

2014-01-01

The Qinling-Tongbai-Hong'an-Dabie-Sulu orogenic belt records the tectonic history of Paleozoic convergence between the South China and North China Blocks. In this study, the distribution of crustal thickness and P- and S-wave velocity ratio (Vp/Vs) is obtained by using the H-k stacking technique from the Dabie-Sulu belt in central China. Our results show marked differences in the crustal structure between the Dabie and Sulu segments of the ultrahigh-pressure (UHP) orogen. The lower crust in the Dabie orogenic belt is dominantly of felsic-intermediate composition, whereas the crust beneath the Sulu segment is largely intermediate-mafic. The crust of the Dabie orogenic belt is thicker by ca. 3-5 km as compared to that of the surrounding region with the presence of an ‘orogenic root’. The crustal thickness is nearly uniform in the Dabie orogenic belt with a generally smooth crust-mantle boundary. A symmetrically thickened crust in the absence of any deep-structural features similar to that of the Yangtze block suggests no supportive evidence for the proposed northward subduction of the Yangtze continental block beneath the North China Block. We propose that the collision between the Yangtze and North China Blocks and extrusion caused crustal shortening and thickening, as well as delamination of the lower crust, resulting in asthenospheric upwelling and lower crustal UHP metamorphism along the Dabie Orogen. Our results also reveal the presence of a SE to NW dipping Moho in the North China Block (beneath the Tran-North China Orogen and Eastern Block), suggesting the fossil architecture of the northwestward subduction of the Kula plate.

Development of Ultra-high Purity (UHP) Fe-Based Alloys with High Creep and Oxidation Resistance for A-USC Technology

NASA Astrophysics Data System (ADS)

Hamdani, Fethi; Das, Nishith K.; Shoji, Tetsuo

2018-06-01

The design of ultra-high purity (UHP) Fe-based model alloys for advanced ultra-supercritical (A-USC) technology is attempted in this work. Creep testing has been performed in air at 700 °C and a stress level of 150 MPa. Analysis of the fracture surface and cross section of the crept specimen was performed. To evaluate the oxidation resistance in A-USC conditions, oxidation testing was performed in supercritical water (SCW) at 700 °C and 25 MPa. Weight gain (WG) measurements and meticulous characterization of the oxide scale were carried out. Based on thermodynamics and density functional theory calculations, some reactive elements in the Fe-Cr-Ni system were designated to promote precipitation strengthening and to improve the hydrogen-accelerated oxidation resistance. The addition of a 2 wt pct Mo into Fe-22Cr-22Ni-0.6Nb wt pct-based matrix did not significantly improve the creep resistance. The addition of 0.26 wt pct Zr coupled with cold working was effective for improving creep properties. The Mo-modified model alloy showed almost the same WG value as SUS310, while the Zr-modified alloy showed a higher WG value. Meanwhile, a Cr-enriched continuous oxide layer was formed at the oxidation front of the Zr-modified alloy and SUS310S after exposure to SCW conditions.

Development of Ultra-high Purity (UHP) Fe-Based Alloys with High Creep and Oxidation Resistance for A-USC Technology

NASA Astrophysics Data System (ADS)

Hamdani, Fethi; Das, Nishith K.; Shoji, Tetsuo

2018-03-01

The design of ultra-high purity (UHP) Fe-based model alloys for advanced ultra-supercritical (A-USC) technology is attempted in this work. Creep testing has been performed in air at 700 °C and a stress level of 150 MPa. Analysis of the fracture surface and cross section of the crept specimen was performed. To evaluate the oxidation resistance in A-USC conditions, oxidation testing was performed in supercritical water (SCW) at 700 °C and 25 MPa. Weight gain (WG) measurements and meticulous characterization of the oxide scale were carried out. Based on thermodynamics and density functional theory calculations, some reactive elements in the Fe-Cr-Ni system were designated to promote precipitation strengthening and to improve the hydrogen-accelerated oxidation resistance. The addition of a 2 wt pct Mo into Fe-22Cr-22Ni-0.6Nb wt pct-based matrix did not significantly improve the creep resistance. The addition of 0.26 wt pct Zr coupled with cold working was effective for improving creep properties. The Mo-modified model alloy showed almost the same WG value as SUS310, while the Zr-modified alloy showed a higher WG value. Meanwhile, a Cr-enriched continuous oxide layer was formed at the oxidation front of the Zr-modified alloy and SUS310S after exposure to SCW conditions.

Separation of major catechins from green tea by ultrahigh pressure extraction.

PubMed

Jun, Xi; Shuo, Zhao; Bingbing, Lu; Rui, Zhang; Ye, Li; Deji, Shen; Guofeng, Zhou

2010-02-15

This study presents a novel extraction technique, ultrahigh pressure extraction, to obtain major catechins from green tea leaves. The effects of various high pressure level (100, 200, 300, 400, 500, 600 MPa) on the extract are examined. HPLC chromatographic analyses determine the concentration of four major catechins and caffeine. The extraction yields of active ingredients with ultrahigh pressure extraction (400 MPa pressure) for only 15 min were given the same as those of organic solvent extraction for 2h. These excellent results for the ultrahigh pressure extraction are promising for the future separation of active ingredients from traditional Chinese herbal medicine. Copyright 2009 Elsevier B.V. All rights reserved.

Chlorine isotope constraints on fluid-rock interactions during subduction and exhumation of the Zermatt-Saas ophiolite

NASA Astrophysics Data System (ADS)

Selverstone, J.; Sharp, Z. D.

2013-10-01

Chlorine isotope compositions of high-pressure (˜2.3 GPa) serpentinite, rodingite, and hydrothermally altered oceanic crust (AOC) differ significantly from high- and ultrahigh-pressure (> 3.2 GPa) metasedimentary rocks in the Aosta region, Italy. Texturally early serpentinites, rodingites, and AOC have bulk δ37Cl values indistinguishable from those of modern seafloor analogues (δ37Cl = -1.0 to +1.0‰). In contrast, serpentinites and AOC samples that recrystallized during exhumation have low δ37Cl values (-2.7 to -0.5‰); 37Cl depletion correlates with progressive changes in bulk chemistry. HP/UHP metasediments have low δ37Cl values (median = -2.5‰) that differ statistically from modern marine sediments (median = -0.6‰). Cl in metasedimentary rocks is concentrated in texturally early minerals, indicating modification of seafloor compositions early in the subduction history. The data constrain fluid sources during both subduction and exhumation-related phases of fluid-rock interaction: (1) marine sediments at the top of the downgoing plate likely interacted with isotopically light pore fluids from the accretionary wedge in the early stages of subduction. (2) No pervasive interaction with externally derived fluid occurred during subsequent subduction to the maximum depths of burial. (3) Localized mixing between serpentinites and fluids released by previously isotopically modified metasediments occurred during exhumation in the subduction channel. Most samples, however, preserved protolith signatures during subduction to near-arc depths.

An exotic terrane in the Sulu UHP region, China

NASA Astrophysics Data System (ADS)

Chu, W.; Zhang, R.; Tsujimori, T.; Liou, J. G.

2004-12-01

The Haiyangsuo region of about 15 km2 along the coast in the NE part of the Triassic Sulu UHP terrane occurs three major rock types: amphibolitized metagabbro, gneiss and granitic dikes. Three different gneisses were observed in the field: A) Light color felsic gneiss is the dominant country rock and contains Qtz, Pl, Ms and Bi. B) Dark color plagioclase-amphibole gneiss occurs as thin layers within country rock; C) Granulite facies rock occurs as discontinuous lens. The amphibolitized metagabbros intrude into the gneisses as massive bodies (several m to hundreds of m in size) and thin dikes. Both metamorphic intrusives and gneisses are cross-cut by granitic dikes. The amphibolitized metagabbro was divided into three types: coronal metagabbro, transitional rock and garnet amphibolite: 1) Coronal metagabbro preserves gabbroic texture and primary assemblage of Opx+Cpx+Pl+Amp+Ilm. Most pyroxene grains are partially rimmed by thin corona of Amp+Ab+Qtz. Garnet occurs as fine-grained coronas at interface between plagioclase, pyroxene or ilmenite. 2) Transitional rocks contain similar assemblage and texture but most orthopyroxenes were partially or totally replaced by Amp+Qtz; garnet increases in content and size. Some gabbroic textures are preserved, but calcic plagioclase was replaced by zoisite, albite and muscovite. 3) Garnet amphibolite occurs at the margins of intrusive bodies and boudins where only minor relict clinopyroxenes preserve. Garnet coronal chains are not clear any more. Granitic dikes show pronounced deformation with mylonitic texture and contain 40-50% quartz porphyroclasts. Zircon separates from 2 metagabbros, 4 gneisses and 1 granitic rock were dated by using Stanford SHRIMP-RG. Metagabbroic zircons are angular and fractured shapes. The upper-intercept ages of gneisses rang from 1730 to about 2400 Ma, indicating variable protoith age. The 2 garnet amphibolites have upper-intercept ages 1734±5Ma and 1735±21Ma respectively. They are much older than

Regional metamorphism at extreme conditions: Implications for orogeny at convergent plate margins

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Chen, Ren-Xu

2017-09-01

Regional metamorphism at extreme conditions refers either to Alpine-type metamorphism at low geothermal gradients of <10 °C/km, or to Buchan-type metamorphism at high geothermal gradients of >30 °C/km. Extreme pressures refer to those above the polymorphic transition of quartz to coesite, so that ultrahigh-pressure (UHP) eclogite-facies metamorphism occurs at mantle depths of >80 km. Extreme temperatures refer to those higher than 900 °C at crustal depths of ≤80 km, so that ultrahigh-temperature (UHT) granulite-facies metamorphism occurs at medium to high pressures. While crustal subduction at the low geothermal gradients results in blueschist-eclogite facies series without arc volcanism, heating of the thinned orogenic lithosphere brings about the high geothermal gradients for amphibolite-granulite facies series with abundant magmatism. Therefore, UHP metamorphic rocks result from cold lithospheric subduction to the mantle depths, whereas UHT metamorphic rocks are produced by hot underplating of the asthenospheric mantle at the crustal depths. Active continental rifting is developed on the thinned lithosphere in response to asthenospheric upwelling, and this tectonism is suggested as a feasible mechanism for regional granulite-facies metamorphism, with the maximum temperature depending on the extent to which the mantle lithosphere is thinned prior to the rifting. While lithospheric compression is associated with subduction metamorphism in accretionary and collisional orogens, the thinned orogenic lithosphere undergoes extension due to the asthenospheric upwelling to result in orogen-parallel rifting metamorphism and magmatism. Thus, the rifting metamorphism provides a complement to the subduction metamorphism and its operation marks the asthenospheric heating of the orogenic lithosphere. Because of the partial melting and melt extraction of the lower continental crust, contemporaneous granite-migmatite-granulite associations may serve as a petrological

Eclogite-facies metamorphism in impure marble from north Qaidam orogenic belt: Geodynamic implications for early Paleozoic continental-arc collision

NASA Astrophysics Data System (ADS)

Chen, Xin; Xu, Rongke; Schertl, Hans-Peter; Zheng, Youye

2018-06-01

In the North Qaidam ultrahigh-pressure (UHP) metamorphic belt, impure marble and interbedded eclogite represent a particular sedimentary provenance and tectonic setting, which have important implications for a controversial problem - the dynamic evolution of early Paleozoic subduction-collision complexes. In this contribution, detailed field work, mineral chemistry, and whole-rock geochemistry are presented for impure marble to provide the first direct evidence for the recycling of carbonate sediments under ultrahigh-pressures during subduction and collision in the Yuka terrane, in the North Qaidam UHP metamorphic belt. According to conventional geothermobarometry, pre-peak subduction to 0.8-1.3 GPa/485-569 °C was followed by peak UHP metamorphism at 2.5-3.3 GPa/567-754 °C and cooling to amphibolite facies conditions at 0.6-0.7 GPa/571-589 °C. U-Pb dating of zircons from impure marble reveals a large group with ages ranging from 441 to 458 Ma (peak at 450 Ma), a smaller group ranging from 770 to 1000 Ma (peak at 780 Ma), and minor >1.8 Ga zircon aged ca. 430 Ma UHP metamorphism. The youngest detrital zircons suggest a maximum depositional age of ca. 442 Ma and a burial rate of ca. 1.0-1.1 cm/yr when combined with P-T conditions and UHP metamorphic age. The REE and trace element patterns of impure marble with positive Sr and U anomalies, negative high field strength elements (Nb, Ta, Zr, Hf, and Ti), and Ce anomalies imply that the marble had a marine limestone precursor. Impure marble intercalated with micaschist and eclogite was similar to limestone and siltstone protoliths deposited in continental fore-arc or arc setting with basic volcanic activity. Therefore, the Yuka terrane most likely evolved in a continental island arc setting during the Paleozoic. These data suggest that metasediments were derived from a mixture of Proterozoic continental crust and juvenile early Paleozoic oceanic and/or island arc crust. In addition, their protoliths were likely

Minor elements, HREE and d18O distribution in UHP garnets from the Dora-Maira massif (western Alps)

NASA Astrophysics Data System (ADS)

Brunet, F.; Chazot, G.; Vielzeuf, D.; Chopin, C.

2003-04-01

The spatial distribution of minor elements, HREE and δ18O in garnet can be used as a probe of the availability and mobility of those elements and isotopes at the time of crystal growth, provided that the initial record was not significantly modified by intracrystalline diffusion and that growth took place under nearly constant pressure and temperature conditions. Garnets from three different Dora-Maira rock-types have been studied, (1) nearly pure pyrope (GT1) from the magnesian coesite-bearing quartzites, (2) almandine/pyrope dominant garnets (GT2) from jadeite-quartzite veins which crosscut the Mg-quartzite body, (3) almandine/grossular dominant garnets (GT3) from the country-rock gneiss, sampled in the vicinity of the quartzites. In GT1, minor elements are mainly Fe, Na and P. Na and P are incorporated according to a Na^+ + P5+ = Me2+ + Si4+ substitution with P_2O_5 contents up to 2000 to 2500 ppm. HREE concentrations obtained by LA-ICP-MS, vary by 2 orders of magnitude from core to rim. The δ18O ratio (Cameca 1270, Nancy), around 5 ppm (SMOW), is constant within error throughout the analysed crystals. In GT2, the situation is different since HREE concentrations appear remarkably constant within a given crystal and from one crystal to the other. In contrast with GT1, Na in GT2 is partly charge-balanced by yttrium incorporation. The δ18O ratio in GT2 of around 7 ppm is close to that encountered in GT3 (gneiss) between 7 and 8 ppm. In GT3, phosphorus content is close to detection limit (P_2O_5 below 300 ppm). HREE concentrations are highly variable from one crystal to the other and unfortunately, the size of garnet crystals does not allow profiling. Although δ18O ratio in garnet is imposed by the bulk-rock isotopic composition, HREE distribution is dominated by element availability through the fluid composition and/or absence/presence of accessory phases. The decrease in HREE and P concentration from GT1 cores to rims suggest that these elements are

Terapascal static pressure generation with ultrahigh yield strength nanodiamond.

PubMed

Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

2016-07-01

Studies of materials' properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications.

Terapascal static pressure generation with ultrahigh yield strength nanodiamond

PubMed Central

Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B.; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

2016-01-01

Studies of materials’ properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications. PMID:27453944

Geochemistry of continental subduction-zone fluids

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Hermann, Joerg

2014-12-01

The composition of continental subduction-zone fluids varies dramatically from dilute aqueous solutions at subsolidus conditions to hydrous silicate melts at supersolidus conditions, with variable concentrations of fluid-mobile incompatible trace elements. At ultrahigh-pressure (UHP) metamorphic conditions, supercritical fluids may occur with variable compositions. The water component of these fluids primarily derives from structural hydroxyl and molecular water in hydrous and nominally anhydrous minerals at UHP conditions. While the breakdown of hydrous minerals is the predominant water source for fluid activity in the subduction factory, water released from nominally anhydrous minerals provides an additional water source. These different sources of water may accumulate to induce partial melting of UHP metamorphic rocks on and above their wet solidii. Silica is the dominant solute in the deep fluids, followed by aluminum and alkalis. Trace element abundances are low in metamorphic fluids at subsolidus conditions, but become significantly elevated in anatectic melts at supersolidus conditions. The compositions of dissolved and residual minerals are a function of pressure-temperature and whole-rock composition, which exert a strong control on the trace element signature of liberated fluids. The trace element patterns of migmatic leucosomes in UHP rocks and multiphase solid inclusions in UHP minerals exhibit strong enrichment of large ion lithophile elements (LILE) and moderate enrichment of light rare earth elements (LREE) but depletion of high field strength elements (HFSE) and heavy rare earth elements (HREE), demonstrating their crystallization from anatectic melts of crustal protoliths. Interaction of the anatectic melts with the mantle wedge peridotite leads to modal metasomatism with the generation of new mineral phases as well as cryptic metasomatism that is only manifested by the enrichment of fluid-mobile incompatible trace elements in orogenic peridotites

Carbonatitic metasomatism in orogenic dunites from Lijiatun in the Sulu UHP terrane, eastern China

NASA Astrophysics Data System (ADS)

Su, Bin; Chen, Yi; Guo, Shun; Chu, Zhu-Yin; Liu, Jing-Bo; Gao, Yi-Jie

2016-10-01

Among orogenic peridotites, dunites suffer the weakest crustal metasomatism at the slab-mantle interface and are the best lithology to trace the origins of orogenic peridotites and their initial geodynamic processes. Petrological and geochemical investigations of the Lijiatun dunites from the Sulu ultrahigh-pressure (UHP) terrane indicate a complex petrogenetic history involving melt extraction and multistage metasomatism (carbonatitic melt and slab-derived fluid). The Lijiatun dunites consist mainly of olivine (Fo = 92.0-92.6, Ca = 42-115 ppm), porphyroblastic orthopyroxene (En = 91.8-92.8), Cr-spinel (Cr# = 50.4-73.0, TiO2 < 0.2 wt.%) and serpentine. They are characterized by refractory bulk-rock compositions with high MgO (45.31-47.07 wt.%) and Mg# (91.5-91.9), and low Al2O3 (0.48-0.70 wt.%), CaO (0.25-0.44 wt.%) and TiO2 (< 0.03 wt.%) contents. Whole-rock platinum group elements (PGE) are similar to those of cratonic mantle peridotites and Re-Os isotopic data suggest that dunites formed in the early Proterozoic ( 2.2 Ga). These data indicate that the Lijiatun dunites were the residues of 30% partial melting and were derived from the subcontinental lithospheric mantle (SCLM) beneath the North China craton (NCC). Subsequent carbonatitic metasomatism is characterized by the formation of olivine-rich (Fo = 91.6-92.6, Ca = 233-311 ppm), clinopyroxene-bearing (Mg# = 95.9-96.7, Ti/Eu = 104-838) veins cutting orthopyroxene porphyroblasts. Based on the occurrence of dolomite, mass-balance calculation and thermodynamic modeling, carbonatitic metasomatism had occurred within the shallow SCLM (low-P and high-T conditions) before dunites were incorporated into the continental subduction channel. These dunites then suffered weak metasomatism by slab-derived fluids, forming pargasitic amphibole after pyroxene. This work indicates that modification of the SCLM beneath the eastern margin of the NCC had already taken place before the Triassic continental subduction. Orogenic

Influence of mid-crustal rheology on the deformation behavior of continental crust in the continental subduction zone

NASA Astrophysics Data System (ADS)

Li, Fucheng; Sun, Zhen; Zhang, Jiangyang

2018-06-01

Although the presence of low-viscosity middle crustal layer in the continental crust has been detected by both geophysical and geochemical studies, its influence on the deformation behavior of continental crust during subduction remains poorly investigated. To illustrate the crustal deformation associated with layered crust during continental subduction, we conducted a suite of 2-D thermo-mechanical numerical studies with visco-brittle/plastic rheology based on finite-differences and marker-in-cell techniques. In the experiments, we established a three-layer crustal model with a quartz-rich middle crustal layer embedded between the upper and lower continental crust. Results show that the middle crustal layer determines the amount of the accreted upper crust, maximum subduction depth, and exhumation path of the subducted upper crust. By varying the initial effective viscosity and thickness of the middle crustal layer, the further effects can be summarized as: (1) a rheologically weaker and/or thicker middle crustal layer results in a larger percentage of the upper crust detaching from the underlying slab and accreting at the trench zone, thereby leading to more serious crustal deformation. The rest of the upper crust only subducts into the depths of high pressure (HP) conditions, causing the absence of ultra-high pressure (UHP) metamorphic rocks; (2) a rheologically stronger and/or thinner middle crustal layer favors the stable subduction of the continental crust, dragging the upper crust to a maximum depth of ∼100 km and forming UHP rocks; (3) the middle crustal layer flows in a ductile way and acts as an exhumation channel for the HP-UHP rocks in both situations. In addition, the higher convergence velocity decreases the amount of subducted upper crust. A detailed comparison of our modeling results with the Himalayan collisional belt are conducted. Our work suggests that the presence of low-viscosity middle crustal layer may be another possible mechanism for

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alan Black; Arnis Judzis

2004-10-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rockmore » cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alan Black; Arnis Judzis

2004-10-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rockmore » cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining

Atmospheric Ar and Ne returned from mantle depths to the Earth's surface by forearc recycling.

PubMed

Baldwin, Suzanne L; Das, J P

2015-11-17

In subduction zones, sediments, hydrothermally altered lithosphere, fluids, and atmospheric gases are transported into the mantle, where ultrahigh-pressure (UHP) metamorphism takes place. However, the extent to which atmospheric noble gases are trapped in minerals crystallized during UHP metamorphism is unknown. We measured Ar and Ne trapped in phengite and omphacite from the youngest known UHP terrane on Earth to determine the composition of Ar and Ne returned from mantle depths to the surface by forearc recycling. An (40)Ar/(39)Ar age [7.93 ± 0.10 My (1σ)] for phengite is interpreted as the timing of crystallization at mantle depths and indicates that (40)Ar/(39)Ar phengite ages reliably record the timing of UHP metamorphism. Both phengite and omphacite yielded atmospheric (38)Ar/(36)Ar and (20)Ne/(22)Ne. Our study provides the first documentation, to our knowledge, of entrapment of atmospheric Ar and Ne in phengite and omphacite. Results indicate that a subduction barrier for atmospheric-derived noble gases does not exist at mantle depths associated with UHP metamorphism. We show that the crystallization age together with the isotopic composition of nonradiogenic noble gases trapped in minerals formed during subsolidus crystallization at mantle depths can be used to unambiguously assess forearc recycling of atmospheric noble gases. The flux of atmospheric noble gas entering the deep Earth through subduction and returning to the surface cannot be fully realized until the abundances of atmospheric noble gases trapped in exhumed UHP rocks are known.

Experimental system for drilling simulated lunar rock in ultrahigh vacuum

NASA Technical Reports Server (NTRS)

Roepke, W. W.

1975-01-01

An experimental apparatus designed for studying drillability of hard volcanic rock in a simulated lunar vacuum of 5 x 10 to the minus 10th power torr is described. The engineering techniques used to provide suitable drilling torque inside the ultrahigh vacuum chamber while excluding all hydrocarbon are detailed. Totally unlubricated bearings and gears were used to better approximate the true lunar surface conditions within the ultrahigh vacuum system. The drilling system has a starting torque of 30 in-lb with an unloaded running torque of 4 in-lb. Nominal torque increase during drilling is 4.5 in-lb or a total drilling torque of 8.5 in-lb with a 100-lb load on the drill bit at 210 rpm. The research shows conclusively that it is possible to design operational equipment for moderate loads operating under UHV conditions without the use of sealed bearings or any need of lubricants whatsoever.

Age of UHP metamorphism in the Western Mediterranean: Insight from rutile and minute zircon inclusions in a diamond-bearing garnet megacryst (Edough Massif, NE Algeria)

NASA Astrophysics Data System (ADS)

Bruguier, Olivier; Bosch, Delphine; Caby, Renaud; Vitale-Brovarone, Alberto; Fernandez, Laure; Hammor, Dalila; Laouar, Rabah; Ouabadi, Aziouz; Abdallah, Nachida; Mechati, Mehdi

2017-09-01

Diamond-bearing UHP metamorphic rocks witness for subduction of lithospheric slabs into the mantle and their return to shallow levels. In this study we present U-Pb and trace elements analyses of zircon and rutile inclusions from a diamond-bearing garnet megacryst collected in a mélange unit exposed on the northern margin of Africa (Edough Massif, NE Algeria). Large rutile crystals (up to 300 μm in size) analyzed in situ provide a U-Pb age of 32.4 ± 3.3 Ma interpreted as dating the prograde to peak subduction stage of the mafic protolith. Trace element analyses of minute zircons (≤30 μm) indicate that they formed in equilibrium with the garnet megacryst at a temperature of 740-810 °C, most likely during HP retrograde metamorphism. U-Pb analyses provide a significantly younger age of 20.7 ± 2.3 Ma attributed to exhumation of the UHP units. This study allows bracketing the age of UHP metamorphism in the Western Mediterranean Orogen to the Oligocene/early Miocene, thus unambiguously relating UHP metamorphism to the Alpine history. Exhumation of these UHP units is coeval with the counterclockwise rotation of the Corsica-Sardinia block and most likely resulted from subduction rollback that was driven by slab pull.

Evidence for a Mid-Crustal Continental Suture and Implications for Multistage (U)HP exhumation, Liverpool Land, East Greenland

NASA Astrophysics Data System (ADS)

Johnston, S.; Brueckner, H.; Gehrels, G.; Manthei, C.; Hacker, B.; Kylander-Clark, A.; Hartz, E. H.

2008-12-01

The East Greenland Caledonides consists of a series of west-directed sheets that formed from 460-360 Ma as Baltica subducted westward beneath Laurentia, and offer an opportunity to study high- and ultrahigh- pressure exhumation in orogenic hangingwalls. The Liverpool Land (LL) gneiss complex, 100 km east of the nearest Caledonian gneisses, provides a window into the deepest levels of the Greenland Caledonides. From the bottom up, the LL tectonostratigraphy is comprised of the eclogite-bearing Tvaerdal orthogneiss and the granulite-facies Jaettedal paragneiss structurally below the top-N Hurry Inlet Detachment. We present new thermobarometry and U/Pb zircon and titanite geochronology from the LL gneisses to define the tectonostratigraphy, continental affinity, and exhumation histories of the LL gneiss complex. The Tvaerdal orthogneiss consists of felsic orthogneisses that host rare ultramafic bodies (Fo92) and mafic boudins that yield peak pressures of >25 kbar at 800°C. Host gneiss zircons dated using LA-MC- ICPMS yield 1676 ± 17 Ma (2s) cores with 403 ± 6 Ma (2s) rims that suggest Mesoproterozoic emplacement of the original intrusive body followed by late-Caledonian deformation. The Tvaerdal orthogneiss also includes voluminous decompression melts; one yielded a TIMS U/Pb titanite age of 387.5 ± 2.2 Ma (2s). The structurally higher Jaettedal paragneiss consists of pelitic gneisses interlayered with granodioritic-dioritic orthogneisses. The Jaettedal-Tvaerdal contact is petrologically abrupt and concordant to regional foliation and lacks sub-amphibolite-facies displacement. Aluminum silicate-bearing pelitic assemblages within the Jaettedal paragneiss yield peak metamorphic conditions of 10-11 kbar at 750- 800°C. U/Pb age maps made using LA-MC-ICPMS from three paragneisses reveal Mesoproterozoic- Archean detrital cores with Caledonian rim overgrowths that cluster between 439-434 Ma. An amphibolite restite from the Jaettedal paragneiss yielded a TIMS U

Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal

DTIC Science & Technology

2014-04-01

ER D C/ G SL T R- 14 -1 1 Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal G eo te ch ni ca l a nd S tr...Field Evaluation of Ultra-High Pressure Water Systems for Runway Rubber Removal Aaron B. Pullen Applied Research Associates, Inc. 421 Oak Avenue...collaboration with Applied Research Associates, Inc. (ARA). Several types of commercial UHPW water blasting systems were tested on an ungrooved portland cement

Ultrahigh Pressure Dynamic Compression

NASA Astrophysics Data System (ADS)

Duffy, T. S.

2017-12-01

Laser-based dynamic compression provides a new opportunity to study the lattice structure and other properties of geological materials to ultrahigh pressure conditions ranging from 100 - 1000 GPa (1 TPa) and beyond. Such studies have fundamental applications to understanding the Earth's core as well as the interior structure of super-Earths and giant planets. This talk will review recent dynamic compression experiments using high-powered lasers on materials including Fe-Si, MgO, and SiC. Experiments were conducted at the Omega laser (University of Rochester) and the Linac Coherent Light Source (LCLS, Stanford). At Omega, laser drives as large as 2 kJ are applied over 10 ns to samples that are 50 microns thick. At peak compression, the sample is probed with quasi-monochromatic X-rays from a laser-plasma source and diffraction is recorded on image plates. At LCLS, shock waves are driven into the sample using a 40-J laser with a 10-ns pulse. The sample is probed with X-rays form the LCLS free electron laser providing 1012 photons in a monochromatic pulse near 10 keV energy. Diffraction is recorded using pixel array detectors. By varying the delay between the laser and the x-ray beam, the sample can be probed at various times relative to the shock wave transiting the sample. By controlling the shape and duration of the incident laser pulse, either shock or ramp (shockless) loading can be produced. Ramp compression produces less heating than shock compression, allowing samples to be probed to ultrahigh pressures without melting. Results for iron alloys, oxides, and carbides provide new constraints on equations of state and phase transitions that are relevant to the interior structure of large, extrasolar terrestrial-type planets.

Atmospheric Ar and Ne returned from mantle depths to the Earth’s surface by forearc recycling

PubMed Central

Baldwin, Suzanne L.; Das, J. P.

2015-01-01

In subduction zones, sediments, hydrothermally altered lithosphere, fluids, and atmospheric gases are transported into the mantle, where ultrahigh-pressure (UHP) metamorphism takes place. However, the extent to which atmospheric noble gases are trapped in minerals crystallized during UHP metamorphism is unknown. We measured Ar and Ne trapped in phengite and omphacite from the youngest known UHP terrane on Earth to determine the composition of Ar and Ne returned from mantle depths to the surface by forearc recycling. An 40Ar/39Ar age [7.93 ± 0.10 My (1σ)] for phengite is interpreted as the timing of crystallization at mantle depths and indicates that 40Ar/39Ar phengite ages reliably record the timing of UHP metamorphism. Both phengite and omphacite yielded atmospheric 38Ar/36Ar and 20Ne/22Ne. Our study provides the first documentation, to our knowledge, of entrapment of atmospheric Ar and Ne in phengite and omphacite. Results indicate that a subduction barrier for atmospheric-derived noble gases does not exist at mantle depths associated with UHP metamorphism. We show that the crystallization age together with the isotopic composition of nonradiogenic noble gases trapped in minerals formed during subsolidus crystallization at mantle depths can be used to unambiguously assess forearc recycling of atmospheric noble gases. The flux of atmospheric noble gas entering the deep Earth through subduction and returning to the surface cannot be fully realized until the abundances of atmospheric noble gases trapped in exhumed UHP rocks are known. PMID:26542683

Unraveling the Switch from Subduction to Exhumation within a Collisional Orogen: Split-stream U-Pb and Trace-element Results from the Western Gneiss Region, Norway (Invited)

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Whitney, D. L.; Teyssier, C. P.; Fossen, H.; Desormeau, J. W.; Jessen, B.

2013-12-01

During continental collision, crustal material may be subducted to great depths and subsequently exhumed. Ultrahigh-pressure (UHP) terranes preserve a record of the subduction of crustal material during suturing of colliding continents and the exhumation of this material during extension and, in some cases, collapse of the orogen. The UHP rocks of the Western Gneiss Region (WGR), Norway, resulted from the collision of Baltica with Laurentia during the final stages of the Caledonian orogeny. The WGR represents one of the two largest UHP terranes on Earth and consists of a UHP eclogite-bearing domain south of the Møre-Trøndelag strike-slip fault and a HP mafic granulite-bearing domain north of the fault. At least some of the HP granulite is overprinted eclogite. To evaluate the metamorphic and structural relationship of mafic rocks and associated migmatite in both regions, we obtained LA-ICP-MS U-Pb dates and trace-element analyses for zircon from a variety of textural types of leucosome associated with mafic layers and lenses. Five leucosomes within highly deformed migmatite in the HP granulite complex on the Roan Peninsula reveal U-Pb lower-intercept ages from ca. 405 to 409 Ma and upper-intercept Proterozoic dates. These zircons have distinct trace-elements patterns: all of the zircons that yield Proterozoic dates have overall much higher REE concentrations, a more significant negative Eu anomaly (-0.3 to -0.7) and steeper HREE patterns (Lu/Dy = 5-12). In comparison, the Caledonian zircons reveal flatter Eu anomalies (-0.3 to 0.2) and less steep HREE patterns (Lu/Dy = 2-7), although the individual patterns do not seem to correlate with age. The Caledonian zircon patterns suggest crystallization at high-pressures and are distinct from the inherited Proterozoic grains. Similar results were obtained from zircon rims extracted from layer-parallel to crosscutting leucosomes from the UHP domain. Trace elements in zircon in these samples record the transition from high-pressure

High-pressure mechanical instability in rocks

USGS Publications Warehouse

Byerlee, J.D.; Brace, W.F.

1969-01-01

At a confining pressure of a few kilobars, deformation of many sedimentary rocks, altered mafic rocks, porous volcanic rocks, and sand is ductile, in that instabilities leading to audible elastic shocks are absent. At pressures of 7 to 10 kilobars, however, unstable faulting and stick-slip in certain of these rocks was observed. This high pressure-low temperature instability might be responsible for earthquakes in deeply buried sedimentary or volcanic sequences.

High-pressure mechanical instability in rocks.

PubMed

Byerlee, J D; Brace, W F

1969-05-09

At a confining pressure of a few kilobars, deformation of many sedimentary rocks, altered mafic rocks, porous volcanic rocks, and sand is ductile, in that instabilities leading to audible elastic shocks are absent. At pressures of 7 to 10 kilobars, however, unstable faulting and stick-slip in certain of these rocks was observed. This high pressure-low temperature instability might be responsible for earthquakes in deeply buried sedimentary or volcanic sequences.

A Manganin Thin Film Ultra-High Pressure Sensor for Microscale Detonation Pressure Measurement

PubMed Central

Zhang, Guodong; Zhao, Yulong; Zhao, Yun; Wang, Xinchen; Ren, Wei; Li, Hui; Zhao, You

2018-01-01

With the development of energetic materials (EMs) and microelectromechanical systems (MEMS) initiating explosive devices, the measurement of detonation pressure generated by EMs in the microscale has become a pressing need. This paper develops a manganin thin film ultra-high pressure sensor based on MEMS technology for measuring the output pressure from micro-detonator. A reliable coefficient is proposed for designing the sensor’s sensitive element better. The sensor employs sandwich structure: the substrate uses a 0.5 mm thick alumina ceramic, the manganin sensitive element with a size of 0.2 mm × 0.1 mm × 2 μm and copper electrodes of 2 μm thick are sputtered sequentially on the substrate, and a 25 μm thick insulating layer of polyimide is wrapped on the sensitive element. The static test shows that the piezoresistive coefficient of manganin thin film is 0.0125 GPa−1. The dynamic experiment indicates that the detonation pressure of micro-detonator is 12.66 GPa, and the response time of the sensor is 37 ns. In a word, the sensor developed in this study is suitable for measuring ultra-high pressure in microscale and has a shorter response time than that of foil-like manganin gauges. Simultaneously, this study could be beneficial to research on ultra-high-pressure sensors with smaller size. PMID:29494519

Deformation Enhanced Recrystallization of Titanite: Insight from the Western Gneiss Region Ultrahigh-Pressure Terrane

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Reddy, S. M.; Blatchford, H.; Whitney, D. L.; Kirkland, C. L.; Teyssier, C.; Evans, N. J.; McDonald, B.

2017-12-01

Titanite readily recrystallizes due to metamorphism, deformation, and/or fluids making it an ideal chronometer for tracking the exhumation of high-grade rocks. The Western Gneiss Region (WGR), Norway, is a giant UHP terrane exhumed as a fairly coherent slab. Parts of the WGR underwent little deformation during exhumation; however, meters-scale shear zones, located across the WGR, deformed over a range of pressures, from (U)HP to amphibolite facies. Titanite from quartzofeldpathic gneiss within, directly adjacent to, and 300 m away from a mylonitic shear zone within the southern WGR have been analyzed to track exhumation and investigate effects of deformation on recrystallization and trace-element mobility. EBSD was used to characterize the microstructural evolution of the gneisses, and trace-element concentrations and timing of recrystallization were estimated by split-stream LA-ICPMS. Titanite grain size decreases from outside (>200) to inside (<75 µm) the shear zone. Gneiss in and directly adjacent to the shear zone contain partially to completely recrystallized grains, with 207-corrected 206Pb/238U ages of <405 Ma. Gneiss within the shear zone shows a greater percentage of recrystallized grains. EBSD data indicate that some titanite comprises multiple subgrains within an optically coherent single grain. Subgrains in titanite cores show evidence of inherited radiogenic Pb, whereas subgrains in rims and tails of deformed sigma grains were recrystallized. In a gneiss directly adjacent to the shear zone, optically coherent grains are zoned, with increasing Sr and decreasing Zr from core to rim; titanite subgrains within the shear-zone gneiss are too small to analyze. In comparison, titanite from the gneiss outside the shear zone does not show any internal microstructures or evidence for Scandian recrystallization and has low U and high 204Pb. These results show that most trace elements are unaffected by deformation of titanite; however, Pb is mobile. Deformation

Deformation Enhanced Recrystallization of Titanite: Insight from the Western Gneiss Region Ultrahigh-Pressure Terrane

NASA Astrophysics Data System (ADS)

Gordon, S. M.; Reddy, S. M.; Blatchford, H.; Whitney, D. L.; Kirkland, C. L.; Teyssier, C.; Evans, N. J.; McDonald, B.

2016-12-01

Titanite readily recrystallizes due to metamorphism, deformation, and/or fluids making it an ideal chronometer for tracking the exhumation of high-grade rocks. The Western Gneiss Region (WGR), Norway, is a giant UHP terrane exhumed as a fairly coherent slab. Parts of the WGR underwent little deformation during exhumation; however, meters-scale shear zones, located across the WGR, deformed over a range of pressures, from (U)HP to amphibolite facies. Titanite from quartzofeldpathic gneiss within, directly adjacent to, and 300 m away from a mylonitic shear zone within the southern WGR have been analyzed to track exhumation and investigate effects of deformation on recrystallization and trace-element mobility. EBSD was used to characterize the microstructural evolution of the gneisses, and trace-element concentrations and timing of recrystallization were estimated by split-stream LA-ICPMS. Titanite grain size decreases from outside (>200) to inside (<75 µm) the shear zone. Gneiss in and directly adjacent to the shear zone contain partially to completely recrystallized grains, with 207-corrected 206Pb/238U ages of <405 Ma. Gneiss within the shear zone shows a greater percentage of recrystallized grains. EBSD data indicate that some titanite comprises multiple subgrains within an optically coherent single grain. Subgrains in titanite cores show evidence of inherited radiogenic Pb, whereas subgrains in rims and tails of deformed sigma grains were recrystallized. In a gneiss directly adjacent to the shear zone, optically coherent grains are zoned, with increasing Sr and decreasing Zr from core to rim; titanite subgrains within the shear-zone gneiss are too small to analyze. In comparison, titanite from the gneiss outside the shear zone does not show any internal microstructures or evidence for Scandian recrystallization and has low U and high 204Pb. These results show that most trace elements are unaffected by deformation of titanite; however, Pb is mobile. Deformation

Dolomitic marbles from the ultrahigh-pressure metamorphic Kimi complex in Rhodope, N.E. Greece

NASA Astrophysics Data System (ADS)

Mposkos, E.; Baziotis, I.; Proyer, A.; Hoinkes, G.

2006-09-01

Dolomitic marbles from the Organi and Pandrosos areas of the ultrahigh-pressure (UHP) metamorphic Kimi complex in East Rhodope, N.E. Greece have the mineral assemblage: Cal + Dol + Ol + Phl ± Di ± Hbl ± Spl ± Ti Chu + retrograde Srp and Chl. Several generations of calcite and dolomite with variable composition and texture represent different stages of the P T evolution: The first stage is represented by matrix dolomite (X_MgCO_3 = 0.48) and relic domains of homogenous composition in matrix calcite (X_MgCO_3 = 0.11 0.13); the second stage is evident from precipitation of lath-shaped and vermicular dolomite in matrix calcite. The third stage is represented by veinlets of almost pure CaCO3 and domainal replacement of prior calcite by nearly pure CaCO3 + Ca-rich dolomite (X_MgCO_3 = 0.34 0.43). Matrix dolomite adjacent to CaCO3 veinlets also becomes Ca-rich (X_MgCO_3 = 0.42). In fact, Ca-rich dolomites with X_MgCO_3 in the range of 0.40 0.34 are reported for the first time from metamorphic marbles. Coexisting Ca-rich dolomite and Mg-poor calcite cannot be explained by the calcite-dolomite miscibility gap. This assemblage rather suggests that Mg-poor calcite was aragonite originally, which formed together with Ca-rich dolomite according to the reaction Mg Cal → Arg + Dol (1) at ultrahigh pressures and temperatures above at least 850 °C, when dolomite becomes disordered and incorporates more Ca than coexisting aragonite does in terms of Mg. The simplest explanation of these observations probably is to suggest two metamorphic events: The first one represented by relic matrix carbonates at relatively low to moderate pressures and temperatures of ca. 750 °C, and the second one limited by the minimum temperatures for dolomite disorder (ca. 850 °C) and in the aragonite + dolomite stability field, i.e. at a minimum pressure of 3 GPa and, if the presence of diamond-bearing metapelites nearby is considered, at conditions of at least 850 °C and 4.3 GPa in the diamond

Ultrahigh-pressure polyamorphism in GeO2 glass with coordination number >6

NASA Astrophysics Data System (ADS)

Kono, Yoshio; Kenney-Benson, Curtis; Ikuta, Daijo; Shibazaki, Yuki; Wang, Yanbin; Shen, Guoyin

2016-03-01

Knowledge of pressure-induced structural changes in glasses is important in various scientific fields as well as in engineering and industry. However, polyamorphism in glasses under high pressure remains poorly understood because of experimental challenges. Here we report new experimental findings of ultrahigh-pressure polyamorphism in GeO2 glass, investigated using a newly developed double-stage large-volume cell. The Ge-O coordination number (CN) is found to remain constant at ∼6 between 22.6 and 37.9 GPa. At higher pressures, CN begins to increase rapidly and reaches 7.4 at 91.7 GPa. This transformation begins when the oxygen-packing fraction in GeO2 glass is close to the maximal dense-packing state (the Kepler conjecture = ∼0.74), which provides new insights into structural changes in network-forming glasses and liquids with CN higher than 6 at ultrahigh-pressure conditions.

Blueschist- and Eclogite facies Pseudotachylytes: Products of Earthquakes in Collision- and Subduction zones

NASA Astrophysics Data System (ADS)

Andersen, T. B.; Austrheim, H.; John, T.; Medvedev, S.; Mair, K.

2009-04-01

Pseudotachylytes are the products of violent geological processes such as metorite impacts and seismic faulting. The fault-rock weakening processes leading to release of earthquakes are commonly related to phenomena such as grain size reduction and gouge formation, pressurization of pore-fluids and in some cases to melting by frictional heating. Explaining the frequently observed intermediate and deep earthquakes by brittle failure is, however, inherently difficult to reconcile because of extremely high normal stresses occuring at depth. In recent years several mechanisms for seismic events on deep faults have been suggested. These include: a) The most commonly accepted mechanism, dehydration embrittlement coupled to prograde metamorphic dehydration of wet rocks, such as serpentinites, at depth. b) Grain-size dependent flow-laws coupled with shear heating instability has been suggested as an alternative to explain repeated seismic faulting in Wadati-Benioff zones. c) Self-localized-thermal-runaway (SLTR) has been forwarded as a mechanism for ultimate failure of visco-elastic materials and as mechanism to explain the co-existence of shear zones and pseudotachylyte fault veins formed at eclogite facies conditions. All these mechanism point to the importance of metamorphism and/or metasomatism in understanding the mechanism(s) of intermediate- and deep earthquakes. Exhumed high to ultra-high pressure [(U)HP] metamorphic rocks are recognized in many orogenic belts. These complexes provide avenues to study a number of important products of geological processes including earthquakes with hypocentres at great depths. (U)HP co-seismic fault rocks are difficult to find in the field; nevertheless, a number of occurrences of co-seismic fault rocks from such complexes have been described after the initial discovery of such rocks in Norway (see: Austrheim and Boundy, Science 1994). In this talk we review some observations and interpretations based on these hitherto rarely

>2500-km-Long Contemporaneous Deep Continental Subduction in the West Gondwana Orogen

NASA Astrophysics Data System (ADS)

Rubatto, D.; Ganade de Araujo, C. E.; Hermann, J.; Cordani, U. G.; Caby, R.; Basei, M. A. S.

2014-12-01

The 5000-km-long, deeply eroded West Gondwana Orogen (WGO) is a major continental collision zone that exposes numerous occurrences of deeply subducted rocks (i.e. eclogites) along its strike. The position of these eclogites marks the suture zone between colliding cratons and the age of metamorphism constrains the transition from subduction-dominated tectonics to continental collision and mountain building. We investigated the metamorphic conditions and age of high-pressure (HP) and ultrahigh-pressure (UHP) eclogites from Mali, Togo and NE-Brazil . P-T estimates confirm UHP to HP conditions for all these localities. The U-Pb age and trace element composition of metamorphic zircon domains demonstrate that continental subduction in the WGO occurred within 20 m.y. over at least 2500 km during the Ediacaran period (620-610 Ma). We consider this to be the first record of modern, large-scale deep-continental subduction and the consequent appearance of Himalayan-scale mountains in the geological record. The rise of such mountains in the Late Ediacaran is perfectly timed to deliver by erosion the sediments (nutrients) that have been deemed necessary for life sustainability in the following Earth evolution.

Kinetics of the coesite to quartz transformation

USGS Publications Warehouse

Mosenfelder, J.L.; Bohlen, S.R.

1997-01-01

The survival of coesite in ultrahigh-pressure (UHP) rocks has important implications for the exhumation of subducted crustal rocks. We have conducted experiments to study the mechanism and rate of the coesite ??? quartz transformation using polycrystalline coesite aggregates, fabricated by devitrifying silica glass cylinders containing 2850H/106 Si at 1000??C and 3.6 GPa for 24h. Conditions were adjusted following synthesis to transform the samples at 700-1000??C at pressures 190-410 MPa below the quartz-coesite equilibrium boundary. Reaction proceeds via grain-boundary nucleation and interface-controlled growth, with characteristic reaction textures remarkably similar to those seen in natural UHP rocks. We infer that the experimental reaction mechanism is identical to that in nature, a prerequisite for reliable extrapolation of the rate data. Growth rates obtained by direct measurement differ by up to two orders of magnitude from those estimated by fitting a rate equation to the transformation-time data. Fitting the rates to Turnbull's equation for growth therefore yields two distinct sets of parameters with similar activation energies (242 or 269 kJ/mol) but significantly different pre-exponential constants. Extrapolation based on either set of growth rates suggests that coesite should not be preserved on geologic time scales if it reaches the quartz stability field at temperatures above 375-400??C. The survival of coesite has previously been linked to its inclusion in strong phases, such as garnet, that can sustain a high internal pressure during decompression. Other factors that may play a crucial role in preservation are low fluid availability - possibly even less than that of our nominally "dry" experiments - and the development of transformation stress, which inhibits nucleation and growth. These issues are discussed in the context of our experiments as well as recent observations from natural rocks. ?? 1997 Elsevier Science B.V.

Physicochemical properties and storage stability of soybean protein nanoemulsions prepared by ultra-high pressure homogenization.

PubMed

Xu, Jing; Mukherjee, Dipaloke; Chang, Sam K C

2018-02-01

This study investigated the effects of the ultrahigh pressure homogenization (pressure, protein concentration, oil phase fraction, pH, temperature, and ionic strength) and storage on the properties of nanoemulsions (100-500nm range), which were stabilized by laboratory-prepared soybean protein isolate (SPI), β-conglycinin (7S) and glycinin (11S). The nanoemulsions made with SPI, 7S and 11S proteins exhibited considerable stability over various ionic strengths (0-500mM NaCl), pH (<4 or >7), thermal treatments (30-60°C) and storage (0-45days). The far-UV spectra of SPI, 7S, 11S dispersions, and SPI-, 7S-, 11S protein-stabilized nanoemulsions were analyzed for the protein structural changes following lipid removal. The ultra-high pressure homogenization changed the secondary structure of SPI, 7S, 11S proteins in the nanoemulsions, and enhanced their stability. This study demonstrated that SPI, 7S, and 11S proteins can be used as effective emulsifiers in nanoemulsions prepared by ultra-high pressure homogenization. Copyright © 2017. Published by Elsevier Ltd.

Terrane-Scale Metastability in Subducted Himalayan Continental Crust as Revealed by Integrated Petrological and Geodynamic Modeling

NASA Astrophysics Data System (ADS)

Palin, R. M.; Reuber, G. S.; White, R. W.; Kaus, B. J. P.; Weller, O. M.

2017-12-01

The Tso Morari massif, northwest India, is one of only two regions in the Himalayan Range that exposes subduction-related ultrahigh-pressure (UHP) metamorphic rocks. The tectonic evolution of the massif is strongly debated, however, as reported pressure estimates for peak metamorphism range between 2.4 GPa and 4.8 GPa. Such ambiguity hinders effective lithospheric-scale modeling of the early stages of the orogen's evolution. We present the results of integrated petrological and geodynamic modeling (Palin et al., 2017, EPSL) that provide new quantitative constraints on the prograde-to-peak pressure-temperature-time (P-T-t) path, and predict the parageneses that felsic and mafic components of the massif crust should have formed under equilibrium conditions. Our model shows that peak P-T conditions of 2.6-2.8 GPa and 600-620 °C, representative of subduction to 90-100 km depth (assuming lithostatic pressure), were reached just 3 Myr after the onset of collision. These P-T-t constraints correlate well with those reported for similar UHP eclogite in the along-strike Kaghan Valley, Pakistan, suggesting that the northwest Himalaya contains dismembered remnants of a 400-km long UHP terrane comparable in size to the Western Gneiss Region, Norway, and the Dabie-Sulu belt, China. The extremely high pressures (up to 4.8 GPa) for peak metamorphism reported by some workers are likely to be unreliable due to thermobarometry having been performed on minerals that did not represent equilibrium assemblages. Furthermore, key high-P minerals predicted to form in subducted Tso Morari continental crust (e.g. jadeite, Mg-rich garnet) are absent from natural samples in the region, reflecting the widespread metastable preservation of lower-pressure protolith assemblages during subduction and exhumation. This result questions the reliability of geodynamic simulations of orogenesis that are commonly predicated on equilibrium metamorphism operating continuously throughout tectonic cycles.

Ultrahigh pressure deformation of polycrystaline hcp-cobalt

NASA Astrophysics Data System (ADS)

Merkel, S.; Antonangeli, D.; Fiquet, G.; Yagi, T.

2003-12-01

During the past few years, a novel set of methods has been developed allowing direct measurements on elasticity and rheology under static ultrahigh pressures using synchrotron x-ray diffraction and the diamond anvil cell. In particular, the analysis on the development of texture and uniaxial stress in a polycrystalline sample under ultrahigh pressure and non-hydrostatic conditions yielded to very interesting results on the microscopic deformation mechanisms and strength of MgO, silicate perovskite or ɛ -Fe [eg. Merkel et al. 2002, Merkel et al. 2003]. However, our understanding of the properties of the ɛ phase of iron remains poor. There are considerable uncertainties and disagreement on the results of various experiments or first-principles calculations. In particular, the results of the radial diffraction measurement on ɛ -Fe [Mao et al. 1998] have been highly controversial. In order to address this issue, we performed investigations on polycrystalline hcp-cobalt. Its properties such as the bulk modulus and thermal expansion are very close to those of ɛ -Fe and it is readily available under ambient conditions. Thus, it is a well known material and results from the high pressure radial diffraction experiments can be compared with those from well-established techniques. In the present analysis, we performed a new set a measurements between 0 and 20 GPa under ambient temperature conditions at the ESRF synchrotron source using amorphous boron gasket, monochromatic x-ray beam, and imaging plate techniques. From such an experiment, we are able to extract information on non-hydrostatic stress, elasticity, and preferred orientations of the sample in-situ under high pressure and compare them with results obtained previously on ɛ -Fe. Documenting the evolution of stress, elasticity and texture in hcp metals is of great interest for our understanding of the bulk properties and seismic anisotropy of the Earth's inner core. S. Merkel et al., J. Geophys. Res. 107 (2002

Validation of the activity expansion method with ultrahigh pressure shock equations of state

NASA Astrophysics Data System (ADS)

Rogers, Forrest J.; Young, David A.

1997-11-01

Laser shock experiments have recently been used to measure the equation of state (EOS) of matter in the ultrahigh pressure region between condensed matter and a weakly coupled plasma. Some ultrahigh pressure data from nuclear-generated shocks are also available. Matter at these conditions has proven very difficult to treat theoretically. The many-body activity expansion method (ACTEX) has been used for some time to calculate EOS and opacity data in this region, for use in modeling inertial confinement fusion and stellar interior plasmas. In the present work, we carry out a detailed comparison with the available experimental data in order to validate the method. The agreement is good, showing that ACTEX adequately describes strongly shocked matter.

Effects of the ultra-high pressure on structure and α-glucosidase inhibition of polysaccharide from Astragalus.

PubMed

Zhu, Zhen-Yuan; Luo, You; Dong, Guo-Ling; Ren, Yuan-Yuan; Chen, Li-Jing; Guo, Ming-Zhu; Wang, Xiao-Ting; Yang, Xue-Ying; Zhang, Yongmin

2016-06-01

A novel homogeneous polysaccharide fraction (APS) was extracted from Astragalus by hot water and purified by Sephadex G-100 and G-75 column. Its molecular weight was 693kDa. APS and APS with ultra-high pressure treatment exhibited significant inhibitory abilities on a-glucosidase, inhibition rate from high to low in order was 400MPa-APS, 300MPa-APS, 500MPa-APS and APS. The inhibition ​percentage of 400MPa-APS (1.5mg/mL) was 49% (max.). This suggested that the inhibitory activity of APS on a-glucosidase was improved by ultra-high pressure treatment. FT-IR, SEM, CD spectra, atomic force microscope and Congo red test analysis of APS and 400MPa-APS showed ultra-high pressure treatment didn't change the preliminary structure but had an effect on its advanced structure. Copyright © 2016 Elsevier B.V. All rights reserved.

Ultrahigh-Sensitivity Piezoresistive Pressure Sensors for Detection of Tiny Pressure.

PubMed

Li, Hongwei; Wu, Kunjie; Xu, Zeyang; Wang, Zhongwu; Meng, Yancheng; Li, Liqiang

2018-06-20

High-sensitivity pressure sensors are crucial for the ultrasensitive touch technology and E-skin, especially at the tiny-pressure range below 100 Pa. However, it is highly challenging to substantially promote sensitivity beyond the current level at several to 200 kPa -1 and to improve the detection limit lower than 0.1 Pa, which is significant for the development of pressure sensors toward ultrasensitive and highly precise detection. Here, we develop an efficient strategy to greatly improve the sensitivity near to 2000 kPa -1 using short-channel coplanar device structure and sharp microstructure, which is systematically proposed for the first time and rationalized by the mathematic calculation and analysis. Significantly, benefiting from the ultrahigh sensitivity, the detection limit is improved to be as small as 0.075 Pa. The sensitivity and detection limit are both superior to the current levels and far surpass the function of human skin. Furthermore, the sensor shows fast response time (50 μs), excellent reproducibility and stability, and low power consumption. Remarkably, the sensor shows excellent detection capacity in the tiny-pressure range, including light-emitting diode switching with a pressure of 7 Pa, ringtone (2-20 Pa) recognition, and ultrasensitive (0.1 Pa) electronic glove. This work represents a performance and strategic progress in the field of pressure sensing.

Raman spectroscopy of detrital garnet from the (U)HP terrane of eastern Papua New Guinea

NASA Astrophysics Data System (ADS)

Andò, Sergio; Baldwin, Suzanne L.; Fitzgerald, Paul G.; Malusà, Marco G.; Aliatis, Irene; Vezzoli, Giovanni; Garzanti, Eduardo

2013-04-01

Garnet is one of the most widespread heavy minerals in sediments derived from orogenic systems. Its chemical composition varies systematically with temperature and pressure conditions, and thus provides information on the metamorphic evolution of source areas that is crucial in tectonic and geodynamic reconstructions. Garnet is easily identified in mineral grain mounts and is relatively stable during burial diagenesis. Raman spectroscopy allows rapid determination of garnet compositions in grain mounts or thin sections of sand and sandstone samples, and can be used to assess their density and chemical composition quite accurately ("MIRAGEM" method of Bersani et al., 2009; Andò et al., 2009). In the D'Entrecastreaux Islands of southeastern Papua New Guinea, the world's youngest (U)HP rocks are exposed. There, mafic rocks and their felsic host gneisses were metamorphosed under eclogite facies conditions from late Miocene to Pliocene, before being exhumed from depths of ~90 km (Baldwin et al., 2004, 2008). The eclogite preserves a peak assemblage of garnet, omphacite, rutile, phengite and Si02 (Hill and Baldwin, 1993). A coesite-eclogite has been found in one small island outcrop. In order to sample garnet populations representative of a larger geographical area, we sampled and studied a heavy-mineral-dominated placer sand (HMC 80) from a beach from SE Goodenough Island. Garnet grains in beach sand are associated with blue-green to subordinately green-brown amphibole and minor epidote, omphacitic clinopyroxene, titanite, apatite and rutile. The subordinate low-density fraction is feldspatho-quartzose with high-rank metamorphic rock fragments and biotite (Q62 F35 Lm2; MI 360). Detrital garnets are mostly classified as almandine with relatively high Mg and Ca and lacking Mn, typical of the eclogite facies (Win et al., 2007; type Ci garnets of Mange and Morton 2007; Andò et al., 2013). In well-described stratigraphic sequences within syn-and post-tectonic basins

Oblique wedge extrusion of UHP/HP complexes in the Late Triassic: structural analysis and zircon ages of the Atbashi Complex, South Tianshan, Kyrgyzstan

NASA Astrophysics Data System (ADS)

Sang, Miao; Xiao, Wenjiao; Bakirov, Apas

2017-04-01

The exhumation and tectonic emplacement of eclogites and blueschists takes place in forearc accretionary complexes by either forearc- or backarc-directed extrusion, but few examples have been well analysed in detail. Here we present an example of oblique wedge extrusion of UHP/HP rocks in the Atbashi accretionary complex of the Kyrgyz South Tianshan. The Atbashi Eclogite-Blueschist Complex (AEBC) is a conventional, formal name for the Atbashi Formation that contains pelitic to siliceous schists alternating with HP/UHP eclogites and blueschists. The main belt of the AEBC strikes SW-NE mostly parallel to the Atbashi-Inylchek Fault. Our field mapping and structural analysis demonstrate that the Atbashi Eclogite-Blueschist Complex is situated in a complicated duplex formed by a northerly dextral transpression system and a southerly sinistral transtension system, both of which contain a series of strike-slip duplexese at several scales. The two shear systems suggest that the Atbashi Complex underwent a unique oblique south- westward extrusion with a general plunge to the NE, the horizontal projection of which is sub-parallel to the strike of the major structures. This indicates that the Atbashi Complex was extruded obliquely southwestwards during eastward penetration of the southern tip of the Yili- Central Tianshan Arc of the Kazakhstan Orocline during the Late Triassic. Also, to constrain the extrusion of the AEBC and to place it in its temporal framework during docking of the Tarim Craton to the southern margin of the Ili-Tianshan Arc, we report new zircon U-Pb isotopic data for four eclogites and one garnet-bearing quartz-schist, in order to document the timing event during extrusion. The youngest ages of the eclogites and the garnet-bearing quartz-schist may be Late Triassic of 217-221 Ma and 223.9 Ma, respectively, suggesting that the main extrusion was later than previously proposed and that the final orogenesis was not completed until the Late Triassic. The HP/UHP

First principles study of iron-bearing MgO under ultrahigh pressure

NASA Astrophysics Data System (ADS)

Umemoto, K.; Hsu, H.

2017-12-01

Understanding of minerals under ultrahigh pressure is essential to model interiors of super-Earths. Chemical compositions of the super-Earths are expected to be similar to those of the Earth. Computational studies on Mg-Si-O ternary systems under ultrahigh pressures, which are difficult to be achieved by diamond-anvil-cell experiments, have been intensively performed (e.g., [1] for MgO, [2,3] for SiO2, and [4,5] for MgSiO3). However, as far as we know, these studies have been restricted to pure Mg-Si-O systems. In the mantles of super-Earths, we expect that there should be impurities as in the Earth's mantle. Among candidates of impurities, iron is especially important to model interiors of super-Earths. Here, we investigate iron-bearing MgO under ultrahigh pressures by first principles. We clarify effects of iron on the phase transition of MgO and thermodynamic quantities by first principles. The role of the 3d electrons will be elucidated. [1] Z. Wu, R. M. Wentzcovitch, K. Umemoto, B. Li, K. Hirose, and J. C. Zheng, J. Geophys. Res. 113, B06204 (2008). [2] S. Q. Wu, K. Umemoto, M. Ji, C. Z. Wang, K. M. Ho, and R. M. Wentzcovitch, Phys. Rev. B 83, 184102 (2011). [3] T. Tsuchiya and J. Tsuchiya, Proc. Nat. Acad. Sci. 108, 1252 (2011) [4] S. Q. Wu, M. Ji, C. Z. Wang, M. C. Nguye, X. Zhao, K. Umemoto, R. M. Wentzcovitch, and K. M. Ho, J. Phys.: Condens. Matter 26, 035402 (2014). [5] H. Niu, A. R. Oganov, X.-C. Chen, and D. Li, Sci. Rep. 5, 18347 (2015).

Beyond sixfold coordinated Si in SiO2 glass at ultrahigh pressures

PubMed Central

Prescher, Clemens; Prakapenka, Vitali B.; Stefanski, Johannes; Jahn, Sandro; Skinner, Lawrie B.; Wang, Yanbin

2017-01-01

We investigated the structure of SiO2 glass up to 172 GPa using high-energy X-ray diffraction. The combination of a multichannel collimator with diamond anvil cells enabled the measurement of structural changes in silica glass with total X-ray diffraction to previously unachievable pressures. We show that SiO2 first undergoes a change in Si–O coordination number from fourfold to sixfold between 15 and 50 GPa, in agreement with previous investigations. Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8 at 172 GPa. Si–O bond length shows first an increase due to the fourfold to sixfold coordination change and then a smaller linear decrease up to 172 GPa. We reconcile the changes in relation to the oxygen-packing fraction, showing that oxygen packing decreases at ultrahigh pressures to accommodate the higher than sixfold Si–O coordination. These results give experimental insight into the structural changes of silicate glasses as analogue materials for silicate melts at ultrahigh pressures. PMID:28874582

Beyond sixfold coordinated Si in SiO2 glass at ultrahigh pressures.

PubMed

Prescher, Clemens; Prakapenka, Vitali B; Stefanski, Johannes; Jahn, Sandro; Skinner, Lawrie B; Wang, Yanbin

2017-09-19

We investigated the structure of SiO 2 glass up to 172 GPa using high-energy X-ray diffraction. The combination of a multichannel collimator with diamond anvil cells enabled the measurement of structural changes in silica glass with total X-ray diffraction to previously unachievable pressures. We show that SiO 2 first undergoes a change in Si-O coordination number from fourfold to sixfold between 15 and 50 GPa, in agreement with previous investigations. Above 50 GPa, the estimated coordination number continuously increases from 6 to 6.8 at 172 GPa. Si-O bond length shows first an increase due to the fourfold to sixfold coordination change and then a smaller linear decrease up to 172 GPa. We reconcile the changes in relation to the oxygen-packing fraction, showing that oxygen packing decreases at ultrahigh pressures to accommodate the higher than sixfold Si-O coordination. These results give experimental insight into the structural changes of silicate glasses as analogue materials for silicate melts at ultrahigh pressures.

Crustal structure of the Dabie orogenic belt (eastern China) inferred from gravity and magnetic data

NASA Astrophysics Data System (ADS)

Yang, Yu-shan; Li, Yuan-yuan

2018-01-01

In order to better characterize the crustal structure of the Dabie orogen and its tectonic history, we present a crustal structure along a 500 km long profile across the Dabie orogenic belt using various data processing and interpretation of the gravity and magnetic data. Source depth estimations from the spectral analysis by continuous wavelet transform (CWT) provide better constraints for constructing the initial density model. The calculated gravity effects from the initial model show great discrepancy with the observed data, especially at the center of the profile. More practical factors are then incorporated into the gravity modeling. First, we add a high density body right beneath the high pressure metamorphic (HPM) and ultrahigh pressure metamorphic (UHPM) belt considering the exposed HPM and UHPM rocks in the mid of our profile. Then, the anomalous bodies A, B, and C inferred from the CWT-based spectral analysis results are fixed in the model geometry. In the final crustal density structure, two anomalous bodies B and C with high density and low magnetization could possibly be attributed to metasomatised mantle materials by SiO2-rich melt derived from the foundering subducted mafic lower crust. Under the extensional environment in the early Cretaceous, the upwelling metasomatised mantle was partially melted to produce the parental magma of the post-collisional mafic-ultramafic intrusive rocks. As for the low density body A with strong magnetization located in the lower crust right beneath the HP and UHP metamorphic belt, it is more likely to be composed of serpentinized mantle peridotite (SMP). This serpentinized mantle peridotite body (SMPB) represents the emplacement of mantle-derived peridotites in the crust, accompanying the exhumation of the UHP metamorphic rocks.

Optimized ultra-high-pressure-assisted extraction of procyanidins from lychee pericarp improves the antioxidant activity of extracts.

PubMed

Zhang, Ruifen; Su, Dongxiao; Hou, Fangli; Liu, Lei; Huang, Fei; Dong, Lihong; Deng, Yuanyuan; Zhang, Yan; Wei, Zhencheng; Zhang, Mingwei

2017-08-01

To establish optimal ultra-high-pressure (UHP)-assisted extraction conditions for procyanidins from lychee pericarp, a response surface analysis method with four factors and three levels was adopted. The optimum conditions were as follows: 295 MPa pressure, 13 min pressure holding time, 16.0 mL/g liquid-to-solid ratio, and 70% ethanol concentration. Compared with conventional ethanol extraction and ultrasonic-assisted extraction methods, the yields of the total procyanidins, flavonoids, and phenolics extracted using the UHP process were significantly increased; consequently, the oxygen radical absorbance capacity and cellular antioxidant activity of UHP-assisted lychee pericarp extracts were substantially enhanced. LC-MS/MS and high-performance liquid chromatography quantification results for individual phenolic compounds revealed that the yield of procyanidin compounds, including epicatechin, procyanidin A2, and procyanidin B2, from lychee pericarp could be significantly improved by the UHP-assisted extraction process. This UHP-assisted extraction process is thus a practical method for the extraction of procyanidins from lychee pericarp.

U-Pb SHRIMP geochronology and trace-element geochemistry of coesite-bearing zircons, North-East Greenland Caledonides

USGS Publications Warehouse

McClelland, W.C.; Power, S.E.; Gilotti, J.A.; Mazdab, F.K.; Wopenka, B.

2006-01-01

Obtaining reliable estimates for the timing of eclogite-facies metamorphism is critical to establishing models for the formation and exhumation of high-pressure and ultrahigh-pressure (UHP) metamorphic terranes in collisional orogens. The presence of pressure-dependent phases, such as coesite, included in metamorphic zircon is generally regarded as evidence that zircon growth occurred at UHP conditions and, ifdated, should provide the necessary timing information. We report U-Pb sensitive high-resolution ion microprobe (SHRIMP) ages and trace-element SHRIMP data from coesite-bearing zircon suites formed during UHP metamorphism in the North- East Greenland Caledonides. Kyanite eclogite and quartzofeldspathic host gneiss samples from an island in J??kelbugt (78??00'N, 18??04'W) contained subspherical zircons with well-defined domains in cathodoluminescence (CL) images. The presence of coesite is confirmed by Raman spectroscopy in six zircons from four samples. Additional components of the eclogite-facies inclusion suite include kyanite, omphacite, garnet, and rutile. The trace-element signatures in core domains reflect modification of igneous protolith zircon. Rim signatures show flat heavy rare earth element (HREE) patterns that are characteristic of eclogite-facies zircon. The kyanite eclogites generally lack a Eu anomaly, whereas a negative Eu anomaly persists in all domains of the host gneiss. The 207Pb- corrected 206Pb/238U ages range from 330 to 390 Ma for the host gneiss and 330-370 Ma for the kyanite eclogite. Weighted mean 206Pb/238U ages for coesite-bearing domains vary from 364 ?? 8 Ma for the host gneiss to 350 ?? 4 Ma for kyanite eclogite. The combined U-Pb and REE data interpreted in conjunction with observed CL domains and inclusion suites suggest that (1) Caledonian metamorphic zircon formed by both new zircon growth and recrystallization, (2) UHP metamorphism occurred near the end of the Caledonian collision, and (3) the 30-50m.y. span of ages

The duration of prograde garnet crystallization in the UHP eclogites at Lago di Cignana, Italy

NASA Astrophysics Data System (ADS)

Skora, Susanne; Lapen, Thomas J.; Baumgartner, Lukas P.; Johnson, Clark M.; Hellebrand, Eric; Mahlen, Nancy J.

2009-10-01

The distinct core-to-rim zonation of different REEs in garnet in metamorphic rocks, specifically Sm relative to Lu, suggests that Sm-Nd and Lu-Hf isochron ages will record different times along a prograde garnet growth history. Therefore, REE zonations in garnet must be measured in order to correctly interpret the isochron ages in terms of the garnet growth interval, which could span several m.y. New REE profiles, garnet crystal size distributions, and garnet growth modeling, combined with previously published Sm-Nd and Lu-Hf geochronology on a UHP eclogite of the Zermatt-Saas Fee (ZSF) ophiolite, Lago di Cignana (Italy), demonstrate that prograde garnet growth of this sample occurred over a ~ 30 to 40 m.y. interval. Relative to peak metamorphism at 38 to 40 Ma, garnet growth is estimated to have begun at ~ 11 to 14 kbar pressure at ~ 70 to 80 Ma. Although such a protracted garnet growth interval is surprising, this is supported by plate tectonic reconstructions which suggest that subduction of the Liguro-Piemont ocean occurred through slow and oblique convergence. These results demonstrate that REE zonations in garnet, coupled to crystal size distributions, provide a powerful means for understanding prograde metamorphic paths when combined with Sm-Nd and Lu-Hf geochronology.

Thermobaric structure of the Himalayan Metamorphic Belt in Kaghan Valley, Pakistan

NASA Astrophysics Data System (ADS)

Rehman, Hafiz Ur; Yamamoto, Hiroshi; Kaneko, Yoshiyuki; Kausar, Allah Bakhsh; Murata, Mamoru; Ozawa, Hiroaki

2007-02-01

The thermobaric structure of the Himalayan Metamorphic Belt (HMB) has been constructed along the Kaghan Valley transect, Pakistan. The HMB in this valley represents mainly the Lesser Himalayan Sequence (LHS) and Higher Himalayan Crystallines (HHC). Mineral parageneses of 474 samples, from an approximately, 80-km traverse from southwest to northeast, were examined. Microprobe analyses were carried out to quantify the mineral composition. To determine the pressure-temperature (P-T) conditions, 65 thin sections (7 pelites from LHS and 25 pelites, 9 mafic rocks/amphibolites and 19 eclogites from HHC) were selected. Based on field observations and mineral paragenesis, low-grade to high-grade metapelites, show Barrovian-type progressive metamorphic sequence, with chlorite, biotite, garnet and staurolite zones in LHS and staurolite, kyanite and sillimanite zones in HHC. By using well-calibrated geothermobarometers, P-T conditions for pelitic and mafic rocks are estimated. P-T estimates for pelitic rocks from the garnet zone indicate a condition of 534 ± 17 °C at 7.6 ± 1.2 kbar. P-T estimates for rocks from the staurolite and kyanite zones indicate average conditions of 526 ± 17 °C at 9.4 ± 1.2 kbar and 657 ± 54 °C at 10 ± 1.6 kbar, respectively. P-T conditions for mafic rocks (amphibolites) and eclogites from HHC are estimated as 645 ± 54 °C at 10.3 ± 2 kbar and 746 ± 59 °C at 15.5 ± 2.1 kbar, respectively. The coesite-bearing ultrahigh-pressure (UHP) eclogites record a peak P-T condition of 757-786 °C at 28.6 ± 0.4 kbar and retrograde P-T conditions of 825 ± 59 °C at 18.1 ± 1.7 kbar. These results suggest that HMB show a gradual increase in metamorphic grade from southwest to northeast. The P-T conditions from Pelitic and adjacent mafic rocks having identical peak conditions in the same metamorphic zone, while the structural middle in HHC reached the highest P-T condition upto the UHP grade.

Zircon U-Pb dating of eclogite from the Qiangtang terrane, north-central Tibet: a case of metamorphic zircon with magmatic geochemical features

NASA Astrophysics Data System (ADS)

Zhai, Qing-guo; Jahn, Bor-ming; Li, Xian-hua; Zhang, Ru-yuan; Li, Qiu-li; Yang, Ya-nan; Wang, Jun; Liu, Tong; Hu, Pei-yuan; Tang, Suo-han

2017-06-01

Zircon is probably the most important mineral used in the dating formation of high-pressure (HP) and ultrahigh-pressure (UHP) metamorphic rocks. The origin of zircon, i.e., magmatic or metamorphic, is commonly assessed by its external morphology, internal structure, mineral inclusions, Th/U ratios and trace element composition. In this study, we present an unusual case of metamorphic zircon from the Qiangtang eclogite, north-central Tibet. The zircon grains contain numerous eclogite-facies mineral inclusions, including omphacite, phengite, garnet and rutile; hence, they are clearly of metamorphic origin. However, they display features similar to common magmatic zircon, including euhedral crystal habit, high Th/U ratios and enriched heavy rare earth elements pattern. We suggest that these zircon grains formed from a different reservoir from that for garnet where no trace elements was present and trace element equilibrium between zircon and garnet was achieved. U-Pb dating of zircon gave an age of 232-237 Ma for the eclogite, and that of rutile yielded a slightly younger age of ca. 217 Ma. These ages are consistent with the reported Lu-Hf mineral isochron and phengite Ar-Ar ages. The zircon U-Pb and mineral Lu-Hf isochron ages are interpreted as the time of the peak eclogite-facies metamorphism, whereas the rutile U-Pb and phengite Ar-Ar ages represent the time of exhumation to the middle crust. Thus, the distinction between metamorphic and magmatic zircons cannot be made using only Th/U ratios and heavy REE compositions for HP-UHP metamorphic rocks of oceanic derivation.

Preserved anatectic melt in ultrahigh-temperature (or high pressure?) felsic granulites, Connecticut, US

NASA Astrophysics Data System (ADS)

Ferrero, Silvio; Axler, Jennifer; Ague, Jay J.; Wunder, Bernd; Ziemann, Martin A.

2017-04-01

experiments performed at T 1025-1050°C and P <1.7 GPa melt and garnet interacts forming a new garnet with different composition, thus indicating lack of equilibrium between melt and garnet. Such microstructure is absent in the experiment at P ≥1.7 GPa, suggesting that such P values correspond to the conditions of melting with the simultaneous production of melt and garnet. Such values are more consistent with the water content of re-homogenized inclusions, rather high for melts formed at T>1000°C. Such pressures are remarkably higher than those previously proposed for these rocks, and suggest that they experienced indeed high pressure rather than ultrahigh temperature conditions, a possibility also supported by the widespread presence of pseudomorphs of sillimanite after kyanite. References Axler JA, Ague JJ (2015). Oriented multiphase needles in garnet from ultrahigh-temperature granulites. American Mineralogist, 100, 2254-2271. Ferrero S, Wunder B, Walczak K, Ziemann MA, O'Brien PJ (2015). Preserved near ultrahigh-pressure melt from continental crust subducted to mantle depths. Geology, 43, 447-450.

Ultrahigh vacuum/high pressure chamber for surface x-ray diffraction experiments

NASA Astrophysics Data System (ADS)

Bernard, P.; Peters, K.; Alvarez, J.; Ferrer, S.

1999-02-01

We describe an ultrahigh vacuum chamber that can be internally pressurized to several bars and that is designed to perform surface x-ray diffraction experiments on solid-gas interfaces. The chamber has a cylindrical beryllium window that serves as the entrance and exit for the x rays. The sample surface can be ion bombarded with an ancillary ion gun and annealed to 1200 K.

Surface structure of micro-diamond from ultrahigh-pressure felsic granulite, Bohemian Massif: AFM study of growth and resorption phenomena

NASA Astrophysics Data System (ADS)

Kotková, J.; Klapetek, P.

2012-04-01

rounding of crystal edges and corners and development of negative trigons reflect diamond resorption. According to experimental works, such features are attributed to high temperature resorption, i.e. oxidation above ~ 950°C due to interaction with CO2 and/or H2O-bearing fluids (or fluid-bearing melts). Our results are consistent with presence of supercritical C-O-H fluid in the rocks in subduction zones documented from other ultrahigh-pressure metamorphic terranes, the resorption morphology corresponding rather to the interaction with water-rich than CO2-rich fluids. Kotková J., ÓBrien P., Ziemann M. (2011): Diamond and coesite discovered in Saxony-type granulite: Solution to the Variscan garnet peridotite enigma. Geology, 39, 7, 667-670.

Effect of ultra-high pressure on small animals, tardigrades and Artemia

NASA Astrophysics Data System (ADS)

Ono, Fumihisa; Mori, Yoshihisa; Takarabe, Kenichi; Fujii, Akiko; Saigusa, Masayuki; Matsushima, Yasushi; Yamazaki, Daisuke; Ito, Eiji; Galas, Simon; Saini, Naurang L.

2016-12-01

This research shows that small animals, tardigrades (Milnesium tardigradum) in tun (dehydrated) state and Artemia salina cists (dried eggs) can tolerate the very high hydrostatic pressure of 7.5 GPa. It was really surprising that living organisms can survive after exposure to such a high pressure. We extended these studies to the extremely high pressure of 20 GPa by using a Kawai-type octahedral anvil press. After exposure to this pressure for 30 min, the tardigrades were soaked in pure water and investigated under a microscope. Their bodies regained metabolic state and no serious injury could be seen. But they were not alive. A few of Artemia eggs went part of the way to hatching after soaked in sea water, but they never grew any further. Comparing with the case of blue-green alga, these animals are weaker under ultra-high pressure.

Flexible Ferroelectric Sensors with Ultrahigh Pressure Sensitivity and Linear Response over Exceptionally Broad Pressure Range.

PubMed

Lee, Youngoh; Park, Jonghwa; Cho, Soowon; Shin, Young-Eun; Lee, Hochan; Kim, Jinyoung; Myoung, Jinyoung; Cho, Seungse; Kang, Saewon; Baig, Chunggi; Ko, Hyunhyub

2018-04-24

Flexible pressure sensors with a high sensitivity over a broad linear range can simplify wearable sensing systems without additional signal processing for the linear output, enabling device miniaturization and low power consumption. Here, we demonstrate a flexible ferroelectric sensor with ultrahigh pressure sensitivity and linear response over an exceptionally broad pressure range based on the material and structural design of ferroelectric composites with a multilayer interlocked microdome geometry. Due to the stress concentration between interlocked microdome arrays and increased contact area in the multilayer design, the flexible ferroelectric sensors could perceive static/dynamic pressure with high sensitivity (47.7 kPa -1 , 1.3 Pa minimum detection). In addition, efficient stress distribution between stacked multilayers enables linear sensing over exceptionally broad pressure range (0.0013-353 kPa) with fast response time (20 ms) and high reliability over 5000 repetitive cycles even at an extremely high pressure of 272 kPa. Our sensor can be used to monitor diverse stimuli from a low to a high pressure range including weak gas flow, acoustic sound, wrist pulse pressure, respiration, and foot pressure with a single device.

Numerical simulation of rock fragmentation during cutting by conical picks under confining pressure

NASA Astrophysics Data System (ADS)

Li, Xuefeng; Wang, Shibo; Ge, Shirong; Malekian, Reza; Li, Zhixiong

2017-12-01

In this article, the effect of confining pressure on rock fragmentation process during cutting was investigated by numerical simulation with a discrete element method (DEM). Four kinds of sandstones with different physical properties were simulated in the rock cutting models under different confining pressures. The rock fragmentation process, the cutting force, and the specific energy under different confining pressures were analyzed. With the increase in confining pressure and rock strength, the vertical propagation of cracks was restrained. Rock samples were compacted and strengthened by confining pressure resulting in the increase of the cutting force. The specific energy of rock cutting linearly increased with the increase of the confining pressure ratio.

Ultrahigh hydrostatic pressure extraction of flavonoids from Epimedium koreanum Nakai

NASA Astrophysics Data System (ADS)

Hou, Lili; Zhang, Shouqin; Dou, Jianpeng; Zhu, Junjie; Liang, Qing

2011-02-01

Herba Epimedii is one of the most famous Chinese herbal medicines listed in the Pharmacopoeia of the People's Republic of China, as one of the representatives of traditional Chinese herb, it has been widely applied in the field of invigorate the kidney and strengthen 'Yang'. The attention to Epimedium extract has more and more increased in recent years. In this work, a novel extraction technique, ultra-high hydrostatic pressure extraction (UPE) technology was applied to extract the total flavonoids of E. koreanum. Three factors (pressure, ethanol concentration and extraction time) were chosen as the variables of extraction experiments, and the optimum UPE conditions were pressure 350 MPa; ethanol concentration 50% (v/v); extraction time 5 min. Compared with Supercritical CO2 extraction, Reflux extraction and Ultrasonic-assisted extraction, UPE has excellent advantages (shorter extraction time, higher yield, better antioxidant activity, lower energy consumption and eco-friendly).

Techniques for measuring ultrahigh-pressure Hugoniot equation of state on a three-stage gas gun

NASA Astrophysics Data System (ADS)

Wang, Xiang; Hu, Jianbo; Dai, Chengda; Wang, Qiangsong; Bo, Jingsong; Tan, Hua; Yu, Yuying

2011-06-01

A three-stage gas gun was developed by mounting an extending launcher tube on a two-stage gas gun, and was successfully applied to perform ultrahigh-pressure Hugoniot measurements for Ta and Pt by using this three-stage gun. Here we introduced the three-stag gas gun launcher and Hugoniot measurement techniques, including shock front shape diagnosis, shock wave velocity and impact velocity measurement as well as numerical simulation. By using this three-stage gun, Ta or Pt impactors were launched up to ~10 km/s, and the Hugoniot data were respectively measured with high accuracy up to 750 GPa for Ta and 1TPa for Pt. It is demonstrated that the three-stage gas gun is a promising technique for studying the ultrahigh-pressure properties of materials, which never before obtained by utilizing two-stage light-gas-gun.

Geochronology, geochemistry, and petrogenesis of late Permian to early Triassic mafic rocks from Darongshan, South China: Implications for ultrahigh-temperature metamorphism and S-type granite generation

NASA Astrophysics Data System (ADS)

Xu, Wang-Chun; Luo, Bi-Ji; Xu, Ya-Jun; Wang, Lei; Chen, Qi

2018-05-01

The role of the mantle in generating ultrahigh-temperature metamorphism and peraluminous S-type granites, and the extent of crust-mantle interaction are topics fundamental to our understanding of the Earth's evolution. In this study we present geochronological, geochemical, and Sr-Nd-Hf isotopic data for dolerites and mafic volcanic rocks from the Darongshan granite complex belt in western Cathaysia, South China. LA-ICP-MS U-Pb zircon analyses yielded magma crystallization ages of ca. 250-248 Ma for the dolerites, which are coeval with eruption of the mafic volcanic rocks, ultrahigh-temperature metamorphism, and emplacement of S-type granites in the Darongshan granite complex belt. The mafic volcanic rocks are high-K calc-alkaline or shoshonitic, enriched in Th, U, and light rare earth elements, and depleted in Nb, Ta and Ti. The dolerites are characterized by high Fe2O3tot (11.61-20.39 wt%) and TiO2 (1.62-3.17 wt%), and low MgO (1.73-4.38 wt%), Cr (2.8-10.8 ppm) and Ni (2.5-11.4 ppm). Isotopically, the mafic volcanic rocks have negative whole-rock εNd(t) values (-6.7 to -9.0) and high ISr values (0.71232 to 0.71767), which are slightly depleted compared with the dolerite samples (εNd(t) = -10.3 to -10.4 and ISr = 0.71796 to 0.71923). Zircons in the dolerites have εHf(t) values of -7.6 to -10.9. The mafic volcanic rocks are interpreted to have resulted from the partial melting of an enriched lithospheric mantle source with minor crustal contamination during ascent, whereas the dolerites formed by late-stage crystallization of enriched lithospheric mantle-derived magmas after fractionation of olivine and pyroxene. The formation of these mantle-derived mafic rocks may be attributed to transtension along a NE-trending strike-slip fault zone that was related to oblique subduction of the Paleo-Pacific plate beneath South China. Such underplated mafic magmas would provide sufficient heat for the generation of ultrahigh-temperature metamorphism and S-type granites, and

Remelting of nanogranitoids in UHP felsic granulites from Erzgebirge (Bohemian Massif, Germany)

NASA Astrophysics Data System (ADS)

Acosta-vigil, A.; Stöckhert, B.; Hermann, J.; Yaxley, G.; Cesare, B.; Bartoli, O.

2017-12-01

Crustal melting commonly takes place at pressures ≤ 1.5 GPa. Anatexis at UHP conditions, however, can occur during subduction of continental crust down to mantle depths. Understanding the timing, mechanisms and nature of this process is important as it has major mechanical and geochemical implications. One way to address this problem is through the novel studies of nanogranitoids in migmatites and granulites (Cesare et al. 2015). We have remelted crystallized former melt inclusions (nanogranitoids) trapped in garnets of diamond-bearing UHP felsic granulites from Erzgebirge, Bohemian Massif. These rocks are made of Qtz+Phe+Pl+Grt+Ky+Bt+Dia, and their peak conditions have been estimated at P≥4.5 GPa and T≥1000 ºC. Nanogranitoids appear homogeneously distributed throughout the entire garnet crystals, are 5-50 µm across and often isometric, with partially developed negative crystal shape, and were trapped during garnet growth in the presence of melt. The mineral assemblage within nanogranites consists of Qtz+Pl+Phe+Pg+Phl±Ky±Dia±Gr±Ap±Rt (Stöckhert et al. 2009). Fragments of nanogranitoids-bearing garnets were loaded inside gold capsules, enclosed in SiO2 or C powders that acted as cushion, either dry or with H2O in excess, and subjected to conditions between 975-1100 ºC and 2.5-4.5 GPa for 2-24 hrs. Re-homogenization has not been completely achieved. Nanogranitoids partially melt, melt often coexists with Als, diamond or Gr, and Grt grows into the melt to form a higher #Mg and Ti, ≈5 µm fringe. Preliminary EMP analyses indicate that melts are granitic sensu stricto, with low FeOt+MgO (≈2 wt%), moderate to high in ASI, and high in TiO2 (≈0.4-0.8 wt%), P2O5 (up to 1 wt%) and volatiles (100-EMP totals ≈ 10-15 wt%). These preliminary results suggest that (i) anatexis started in the presence of a H2O-rich fluid phase, (ii) melt was present and equilibrated at quite high T (>850-950 ºC, Hayden & Watson 2007) at or close to peak conditions, (iii) Als

Experimental Investigation of Magnetic Superconducting and other Phase Transitions in Novel f-Electron Materials at Ultra-high Pressures using Designer Diamond Anvils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maple, M. Brian; Jeffries, Jason R.; Ho, Pei-Chun

Pressure is often used as a controlled parameter for the investigation of condensed matter systems. In particular, pressure experiments can provide valuable information into the nature of superconductivity, magnetism, and the coexistence of these two phenomena. Some f-electron, heavy-fermion materials display interesting and novel behavior at moderately low pressures achievable with conventional experimental techniques; however, a growing number of condensed matter systems require ultrahigh pressure techniques, techniques that generate significantly higher pressures than conventional methods, to sufficiently explore their important properties. To that end, we have been funded to develop an ultrahigh pressure diamond anvil cell facility at the Universitymore » of California, San Diego (UCSD) in order to investigate superconductivity, magnetism, non-Fermi liquid behavior, and other phenomena. Our goals for the first year of this grant were as follows: (a) set up and test a suitable refrigerator; (b) set up a laser and spectrometer fluorescence system to determine the pressure within the diamond anvil cell; (c) perform initial resistivity measurements at moderate pressures from room temperature to liquid helium temperatures ({approx}1K); (d) investigate f-electron materials within our current pressure capabilities to find candidate materials for high-pressure studies. During the past year, we have ordered almost all the components required to set up a diamond anvil cell facility at UCSD, we have received and implemented many of the components that have been ordered, we have performed low pressure research on several materials, and we have engaged in a collaborative effort with Sam Weir at Lawrence Livermore National Lab (LLNL) to investigate Au4V under ultrahigh pressure in a designer diamond anvil cell (dDAC). This report serves to highlight the progress we have made towards developing an ultrahigh pressure research facility at UCSD, the research performed in the

Water Pressure Effects on Strength and Deformability of Fractured Rocks Under Low Confining Pressures

NASA Astrophysics Data System (ADS)

Noorian Bidgoli, Majid; Jing, Lanru

2015-05-01

The effect of groundwater on strength and deformation behavior of fractured crystalline rocks is one of the important issues for design, performance and safety assessments of surface and subsurface rock engineering problems. However, practical difficulties make the direct in situ and laboratory measurements of these properties of fractured rocks impossible at present, since effects of complex fracture system hidden inside the rock masses cannot be accurately estimated. Therefore, numerical modeling needs to be applied. The overall objective of this paper is to deepen our understanding on the validity of the effective stress concept, and to evaluate the effects of water pressure on strength and deformation parameters. The approach adopted uses discrete element methods to simulate the coupled stress-deformation-flow processes in a fractured rock mass with model dimensions at a representative elementary volume (REV) size and realistic representation of fracture system geometry. The obtained numerical results demonstrate that water pressure has significant influence on the strength, but with minor effects on elastic deformation parameters, compared with significant influence by the lateral confining pressure. Also, the classical effective stress concept to fractured rock can be quite different with that applied in soil mechanics. Therefore, one should be cautious when applying the classical effective stress concept to fractured rock media.

Crustal melting during subduction at mantle depth: anatomy of near-UHP nanogranites (Orlica-Śnieżnik Dome, Bohemian Massif)

NASA Astrophysics Data System (ADS)

Ferrero, Silvio; Ziemann, Martin; Walczak, Katarzyna; Wunder, Bernd; O'Brien, Patrick J.; Hecht, Lutz

2015-04-01

Small volumes (≤ 50µm) of hydrous melt were trapped as primary inclusions in peritectic garnets during partial melting of metagranitoids from the Orlica-Śnieżnik Dome (Bohemian Massif) at mantle depth [1]. Detailed microstructural/microchemical investigation confirmed the occurrence of a granitic assemblage (biotite+feldspars+quartz) in every investigated inclusion, i.e they are nanogranites [2]. MicroRaman mapping of unexposed inclusions showed the occurrence of residual, H2O-rich glass in interstitial position. Despite the oddity of this finding within a classic regional HP/HT terrain, an incomplete crystallization of the melt inclusions (MI) is consistent with the (relatively) rapid exhumation of the Orlica-Śnieżnik Dome proposed by some authors [e.g. 3]. Moreover glassy and partially crystallized MI have been already reported in lower-P (<1 GPa) migmatites [4]. MicroRaman investigation also showed the possible presence of kumdykolite, a high-temperature polymorph of albite reported in UHP rocks from the Kokchetav Massif as well as the Bohemian massif ([5] and references therein). Experimental re-homogenization of nanogranites was achieved using a piston cylinder apparatus at 2.7 GPa and 875°C under dry conditions, in order to investigate melt composition and H2O content with in situ techniques. The trapped melt is granitic, hydrous (6 wt% H2O) and metaluminous (ASI=1.03), and it is similar to those produced experimentally from crustal lithologies at mantle conditions. Re-homogenization conditions are consistent with the results of geothermobarometric calculations on the host rock, suggesting that no H2O loss occurred during exhumation - this would have caused a shift of the inclusion melting T toward higher values. Coupled with the absence of H2O-loss microstructural evidence, e.g. decrepitation cracks and/or vesciculation [4] in re-homogenized nanogranites, this evidence suggests that the nanogranites still preserves the original H2O content of the

UHP metamorphism in the Western Mediterranean : A tale of a Tethys fragment (Edough Massif, NE Algeria) and its geodynamic consequences

NASA Astrophysics Data System (ADS)

Bruguier, Olivier; Bosch, Delphine; Caby, Renaud; Fernandez, Laure; Abdallah, Nachida; Arnaud, Nicolas; Hammor, Dalila; Laouar, Rabah; Mechati, Medhi; Monié, Patrick; Ouabadi, Aziouz; Toubal, Abder

2016-04-01

The Edough Massif of NE Algeria is part of the Maghrebides, a peri-Mediterranean Alpine belt that extends from Morocco to Tunisia. The belt resulted mainly from the eastward retreat of the Tethyan slab and from the drift of continental fragments, some of which finally collided with the north African margin. In this study we report the recent discovery of metamorphic diamonds (5-30 μm in size) included in a garnet megacryst and identified by Raman spectroscopy and the characteristic sharp band at 1332 cm-1 for crystalline diamond. The studied megacryst was taken from a weathered actinolitite horizon inserted within a major mylonite-ultramylonite band, which outcrops at the base of an allochtonous oceanic unit thrust onto the African paleomargin. The host garnet is almandine-dominant with a sharp increase in grossular component in the rim and is rich in exsolution of small acicular rutile needles. Major and trace elements show a gradual but significant zonation from core to rim characterized by a decrease in HREE, Y and Mn, typical of a prograde growth in a closed system. Trace element analyses of large prismatic rutile (up to 300 μm) indicate that the host metamorphic rock was a mafic protolith of MORB affinity and the Zr-in-rutile thermometry indicates a temperature range of 724-778°C for rutile growth. U-Pb analyses of these large rutile crystals provide an age of 32.4 ± 3.3 Ma interpreted as dating the prograde subduction stage of the mafic protolith. Minute zircons (≤ 30μm), disseminated in the garnet, display a multifaceted appearance and low Th/U ratios consistent with a metamorphic origin. The lack of HREE depletion in these zircons indicates that their metamorphic growth was not coeval with garnet. U-Pb analyses and Ti-in-zircon thermometry indicate they nucleated at 20.9 ± 2.2 Ma during near isothermal decompression related to exhumation of the UHP units. This study allows bracketing the age of UHP metamorphism in the Western Mediterranean to the

Mode I Fracture Toughness of Rock - Intrinsic Property or Pressure-Dependent?

NASA Astrophysics Data System (ADS)

Stoeckhert, F.; Brenne, S.; Molenda, M.; Alber, M.

2016-12-01

The mode I fracture toughness of rock is usually regarded as an intrinsic material parameter independent of pressure. However, most fracture toughness laboratory tests are conducted only at ambient pressure. To investigate fracture toughness of rock under elevated pressures, sleeve fracturing laboratory experiments were conducted with various rock types and a new numerical method was developed for the evaluation of these experiments. The sleeve fracturing experiments involve rock cores with central axial boreholes that are placed in a Hoek triaxial pressure cell to apply an isostatic confining pressure. A polymere tube is pressurized inside these hollow rock cylinders until they fail by tensile fracturing. Numerical simulations incorporating fracture mechanical models are used to obtain a relation between tensile fracture propagation and injection pressure. These simulations indicate that the magnitude of the injection pressure at specimen failure is only depending on the fracture toughness of the tested material, the specimen dimensions and the magnitude of external loading. The latter two are known parameters in the experiments. Thus, the fracture toughness can be calculated from the injection pressure recorded at specimen breakdown. All specimens had a borehole diameter to outer diameter ratio of about 1:10 with outer diameters of 40 and 62 mm. The length of the specimens was about two times the diameter. Maximum external loading was 7.5 MPa corresponding to maximum injection pressures at specimen breakdown of about 100 MPa. The sample set tested in this work includes Permian and Carboniferous sandstones, Jurassic limestones, Triassic marble, Permian volcanic rocks and Devonian slate from Central Europe. The fracture toughness values determined from the sleeve fracturing experiments without confinement using the new numerical method were found to be in good agreement with those from Chevron bend testing according to the ISRM suggested methods. At elevated

An investigation of rock fall and pore water pressure using LIDAR in Highway 63 rock cuts.

DOT National Transportation Integrated Search

2014-07-01

The purpose of this research work is compare LIDAR scanning measurements of rock fall with the natural changes in groundwater level to determining the effect of water pressures (levels) on rock fall. To collect the information of rock cut volume chan...

Ultra-high performance size-exclusion chromatography in polar solvents.

PubMed

Vancoillie, Gertjan; Vergaelen, Maarten; Hoogenboom, Richard

2016-12-23

Size-exclusion chromatography (SEC) is amongst the most widely used polymer characterization methods in both academic and industrial polymer research allowing the determination of molecular weight and distribution parameters, i.e. the dispersity (Ɖ), of unknown polymers. The many advantages, including accuracy, reproducibility and low sample consumption, have contributed to the worldwide success of this analytical technique. The current generation of SEC systems have a stationary phase mostly containing highly porous, styrene-divinylbenzene particles allowing for a size-based separation of various polymers in solution but limiting the flow rate and solvent compatibility. Recently, sub-2μm ethylene-bridged hybrid (BEH) packing materials have become available for SEC analysis. These packing materials can not only withstand much higher pressures up to 15000psi but also show high spatial stability towards different solvents. Combining these BEH columns with the ultra-high performance LC (UHPLC) technology opens up UHP-SEC analysis, showing strongly reduced runtimes and unprecedented solvent compatibility. In this work, this novel characterization technique was compared to conventional SEC using both highly viscous and highly polar solvents as eluent, namely N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF) and methanol, focusing on the suitability of the BEH-columns for analysis of highly functional polymers. The results show a high functional group compatibility comparable with conventional SEC with remarkably short runtimes and enhanced resolution in methanol. Copyright © 2016 Elsevier B.V. All rights reserved.

Petrological and zircon evidence for the Early Cretaceous granulite-facies metamorphism in the Dabie orogen, China

NASA Astrophysics Data System (ADS)

Gao, Xiao-Ying; Zhang, Qiang-Qiang; Zheng, Yong-Fei; Chen, Yi-Xiang

2017-07-01

An integrated study of petrology, mineralogy, geochemistry, and geochronology was carried out for contemporaneous mafic granulite and diorite from the Dabie orogen. The results provide evidence for granulite-facies reworking of the ultrahigh-pressure (UHP) metamorphic rock in the collisional orogen. Most zircons from the granulite are new growth, and their U-Pb ages are clearly categorized into two groups at 122-127 Ma and 188 ± 2 Ma. Although these two groups of zircons show similarly steep HREE patterns and variably negative Eu anomalies, the younger group has much higher U, Th and REE contents and Th/U ratios, much lower εHf(t) values than the older group. This suggests their growth is associated with different types of dehydration reactions. The older zircon domains contain mineral inclusions of garnet + clinopyroxene ± quartz, indicating their growth through metamorphic reactions at high pressures. In contrast, the young zircon domains only contain a few quartz inclusions and the garnet-clinopyroxene-plagioclase-quartz barometry yields pressures of 4.9 to 12.5 kb. In addition, the clinopyroxene-garnet Fe-Mg exchange thermometry gives temperatures of 738-951 °C. Therefore, the young zircon domains would have grown through peritectic reaction at low to medium pressures. The younger granulite-facies metamorphic age is in agreement not only with the adjacent diorite at 125 ± 1 Ma in this study but also the voluminous emplacement of coeval mafic and felsic magmas in the Dabie orogen. Mineral separates from both mafic granulite and its adjacent diorite show uniformly lower δ18O values than normal mantle, similar to those for UHP eclogite-facies metaigneous rocks in the Dabie orogen. In combination with major-trace elements and zircon Lu-Hf isotope compositions, it is inferred that the protolith of mafic granulites shares with the source rock of diorites, both being a kind of mafic metasomatites at the slab-mantle interface in the continental subduction channel

An Evaluation of Ultra-High Pressure Regulator for Robotic Lunar Landing Spacecraft

NASA Technical Reports Server (NTRS)

Burnside, Christopher; Trinh, Huu; Pedersen, Kevin

2011-01-01

The Robotic Lunar Lander Development (RLLD) Project Office at NASA Marshall Space Flight Center (MSFC) has studied several lunar surface science mission concepts. These missions focus on spacecraft carrying multiple science instruments and power systems that will allow extended operations on the lunar surface. Initial trade studies of launch vehicle options for these mission concepts indicate that the spacecraft design will be significantly mass-constrained. To minimize mass and facilitate efficient packaging, the notional propulsion system for these landers has a baseline of an ultra-high pressure (10,000 psig) helium pressurization system that has been used on Defense missiles. The qualified regulator is capable of short duration use; however, the hardware has not been previously tested at NASA spacecraft requirements with longer duration. Hence, technical risks exist in using this missile-based propulsion component for spacecraft applications. A 10,000-psig helium pressure regulator test activity is being carried out as part of risk reduction testing for MSFC RLLD project. The goal of the test activity is to assess the feasibility of commercial off-the-shelf ultra-high pressure regulator by testing with a representative flight mission profile. Slam-start, gas blowdown, water expulsion, lock-up, and leak tests are also performed on the regulator to assess performance under various operating conditions. The preliminary test results indicated that the regulator can regulate helium to a stable outlet pressure of 740 psig within the +/- 5% tolerance band and maintain a lock-up pressure less than +5% for all tests conducted. Numerous leak tests demonstrated leakage less than 10-3 standard cubic centimeters per second (SCCS) for internal seat leakage at lock-up and less than10-5 SCCS for external leakage through the regulator ambient reference cavity. The successful tests have shown the potential for 10,000 psig helium systems in NASA spacecraft and have reduced risk

Pressure - temperature estimates of a phengite eclogite from the Grapesvåre Nappe, Norrbotten, Swedish Caledonides

NASA Astrophysics Data System (ADS)

Bukała, Michał; Majka, Jarosław; Walczak, Katarzyna; Barnes, Christopher; Klonowska, Iwona

2017-04-01

The Seve Nappe Complex (SNC) of the Scandinavian Caledonides has well documented history of high pressure (HP) and ultra-high pressure (UHP) metamorphism (e.g. Klonowska et al. 2014). Eclogites of the SNC occur in two areas in Sweden, namely Jämtland and Norrbotten. The Jämtland eclogites and associated rocks are well studied and provide evidence for the Late Ordovician UHP metamorphism, whereas the Norrbotten eclogites, formed during the Late Cambrian/Early Ordovician, have not been studied in detail, especially in terms of pressure-temperature (P-T) conditions of their formation. Within the SNC in Norrbotten, eclogites are limited to two tectonic lenses - Vaimok and Tsäkkok (e.g. Albrecht, 2000). Within the Vaimok Lens three nappes have been distinguished: (1) the eclogite-free Lower Seve Nappe, (2) the Grapesvåre Nappe and (3) the Maddåive Nappe. The two latter nappes are eclogite-bearing. For this study eclogites were collected from the lowermost part of the Grapesvåre Nappe (from the highly heterogeneous Daunasvagge unit dominated by garnet-bearing mica schists, quartzites and marbles). Eclogite boudins (former dolerite dikes and sills) are usually highly altered due to retrogressive recrystallization. Rare fresh eclogites occur within large boudins (>5m in diameter) and display only minor alteration limited to the scarce veinlets composed of amphibole + feldspar + garnet + zoisite + biotite + rutile + titanite. Metamorphic peak conditions mineral assemblage consists of garnet + omphacite + phengite + quartz + rutile. For P-T estimates the geothermobarometric method of Ravna & Terry (2004) has been used. The garnet-clinopyroxene Fe2+-Mg exchange thermometer and the net-transfer reaction barometer based on the garnet-phengite-omphacite equilibrium yielded a maximum pressure of 26.7 kbar and temperature of 677°C. The obtained temperature might be underestimated due to uncertainties in Fe2+/Fe3+ ratio in pyroxene. Therefore Zr-in-rutile geothermometer by

A petro-structural review of the Zermatt-Saas Fee zone

NASA Astrophysics Data System (ADS)

Schenker, Filippo Luca; Markus Schmalholz, Stefan; Baumgartner, Lukas

2014-05-01

The Zermatt-Saas Fee zone (ZSZ) is an imbricate of fragments of blueschist- to eclogite-facies metabasalts and metagabbros, serpentinites and mélange zones containing blocks of the above mentioned rocks. The ZSZ is usually interpreted as a fragment of oceanic crust belonging to the Piemont-Ligurian (Tethyan) Ocean that was accreted into the Alpine nappe pile. In the last decades the discovery of several Ultra-High Pressure (UHP, >2.7 GPa at 550-600 °C from coesite bearing eclogites and diamond-bearing fluid inclusions in garnet) localities lead to the interpretation of deep subduction (> 100 km) of the ZSZ in the Eocene, and subsequent uplift from mantle depth with high exhumation rates (e.g. Amato et al., 1999). However, these high pressures are in apparent contrast to the regional metamorphic conditions that reflect pressures peaking at < 2 GPa for 550-600°C (blueschist and eclogite mineral assemblages in mafic rocks). These latter metamorphic conditions do not need anomalous high burial histories and exhumation velocities higher than the plate velocities. The magnitude and distribution of pressure in the tectonic units of the ZSZ are important for constraining dynamic models for the evolution of the ZSZ and the Western Alps. Before entering into dynamic models, we propose a petro-structural overview where the published petrological data on pressure and temperature are critically reviewed, and positioned on a geological map and cross section in order to integrate them into the proper structural and tectonic framework. The questions we seek to answer are: How is the pressure distributed within the main tectonic units and within the entire ZSZ? Do we observe sharp or gradual pressure gradients within the ZSZ? Can the UHP conditions be averaged/extended to the entire ZSZ? If not, do they correspond to conditions of observable subunits, or do they reflect anomalies in the pressure field? Answering these questions is fundamental to better understand the

Seismic probing of continental subduction zones

NASA Astrophysics Data System (ADS)

Zhao, Liang; Xu, Xiaobing; Malusà, Marco G.

2017-09-01

High-resolution images of Earth's interior provide pivotal information for the understanding of a range of geodynamic processes, including continental subduction and exhumation of ultrahigh-pressure (UHP) metamorphic rocks. Here we present a synthesis of available global seismic observations on continental subduction zones, and selected examples of seismic probing from the European Alps, the Himalaya-Tibet and the Qinling-Dabie orogenic belts. Our synthesis and examples show that slabs recognized beneath exhumed continental UHP terranes generally have shallow dip angles (<45°) at depths <100 km, to become much steeper at depths >100 km. Slabs underlined by a clear high velocity anomaly from Earth's surface to the mantle are generally Cenozoic in age. Some of these slabs are continuous, whereas other continental subduction zones are located above discontinuous high velocity anomalies possibly suggesting slab breakoff. The density of seismic stations and the quality of recordings are of primary importance to get high-resolution images of the upper mantle to be used as a starting point to provide reliable geodynamic interpretations. In some cases, areas previously indicated as possible site of slab breakoff, such as the European Alps, have been later proven to be located above a continuous slab by using higher quality travel time data from denser seismic arrays. Discriminating between oceanic and continental slabs can be challenging, but valuable information can be provided by combining teleseismic tomography and receiver function analysis. The upper mantle beneath most continental UHP terranes generally shows complex seismic anisotropy patterns that are potentially preserved even in pre-Cenozoic subduction zones. These patterns can be used to provide information on continental slabs that are no longer highlighted by a clear high-velocity anomaly.

On the Preservation of Intergranular Coesite in UHP Eclogite at Yangkou Bay, Sulu belt of eastern China

NASA Astrophysics Data System (ADS)

Wang, L.; Wang, S.; Brown, M.

2016-12-01

In contrast to coesite that occurs as inclusions in zircon and rock-forming minerals, intergranular coesite is preserved in UHP eclogite at Yangkou in the Sulu belt. The survival of intergranular coesite is intriguing because the eclogite experienced phengite growth and partial melting during exhumation. The coesite eclogite occurs as rootless isoclinal fold noses within quartz-rich schist which contains 10-20 vol% phengite, whereas phengite is absent from coesite eclogite in the fold noses. To evaluate the factors that control preservation of intergranular coesite, four samples representative of different stages along the retrograde P-T path were selected for study. For each sample we determined the number of intergranular coesite grains per cm2 and the OH content of garnet and omphacite. As the number of coesite grains decreases, the bulk rock OH content increases from <200 ppm in phengite-free coesite eclogite to 200-260 ppm in phengite-bearing (<5 vol%) coesite eclogite and up to a maximum of 430-438 ppm in quartz eclogite ( 10 vol% phengite). However, the OH content drops to a minimum of 59 ppm in residual eclogite resulting from melt drainage. This trend implies that the volume of fluid increased sufficiently during exhumation to facilitate the growth of phengite and the transformation to quartz of intergranular coesite outside of the fold noses. The fluid is inferred to have been a supercritical fluid probably residual from prograde dehydration but also derived by dissolution of nominally anhydrous minerals. Post-metamorphic-peak deformation combined with fluid percolation along sheared fold limbs induced phengite growth during initial exhumation and then facilitated partial melting. In contrast, fold hinges in competent layers are unfavourable sites for fluid penetration. At Yangkou, the intergranular coesite is preserved in the fold noses where it was protected from both penetrative deformation and fluid ingress. Therefore, the fold noses maintained a

Recent advances in capillary ultrahigh pressure liquid chromatography.

PubMed

Blue, Laura E; Franklin, Edward G; Godinho, Justin M; Grinias, James P; Grinias, Kaitlin M; Lunn, Daniel B; Moore, Stephanie M

2017-11-10

In the twenty years since its initial demonstration, capillary ultrahigh pressure liquid chromatography (UHPLC) has proven to be one of most powerful separation techniques for the analysis of complex mixtures. This review focuses on the most recent advances made since 2010 towards increasing the performance of such separations. Improvements in capillary column preparation techniques that have led to columns with unprecedented performance are described. New stationary phases and phase supports that have been reported over the past decade are detailed, with a focus on their use in capillary formats. A discussion on the instrument developments that have been required to ensure that extra-column effects do not diminish the intrinsic efficiency of these columns during analysis is also included. Finally, the impact of these capillary UHPLC topics on the field of proteomics and ways in which capillary UHPLC may continue to be applied to the separation of complex samples are addressed. Copyright © 2017 Elsevier B.V. All rights reserved.

Ultra-high pressure waterjets efficient in removing coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-06-01

Little if any thought was given to pipeline rehabilitation 50 years, a time when pipe manufacturers often coated the external diameter of pipe with coal tar to help eliminate corrosion. Unfortunately, contractors rehabilitating these pipelines today encounter major difficulties when attempting to remove coal tar with traditional removal processes. A leading pipeline rehabilitation firm, F.F. Yockey Company, Inc. of Magnolia, Texas, faced a constant challenge stripping coal tar with rotating knives and brushes. The process generated heat that melted the tar and caused the machines to jam. Another problem was the damage to the substrate caused by the friction-based cleaningmore » techniques of rotating knives and brushes. The knives also failed to completely clean the substrate, leaving behind a significant amount of residue. Contractors learned that new coating bonded poorly to the substrates covered with residual contaminants, thus yielding unsatisfactory results. As he looked for a solution, Dick Yockey, president and CEO of R.F. Yockey, began exploring the use of ultra-high pressure waterjet surface preparation equipment. This system involved water pressurized at levels ranging from 35,000 to 55,000 psi. The water travels through small orifices in a high-speed rotating nozzle, forming a cohesive stream of water. This paper reviews the design and performance of this system.« less

Pseudolinear gradient ultrahigh-pressure liquid chromatography using an injection valve assembly.

PubMed

Xiang, Yanqiao; Liu, Yansheng; Stearns, Stanley D; Plistil, Alex; Brisbin, Martin P; Lee, Milton L

2006-02-01

The use of ultrahigh pressures in liquid chromatography (UHPLC) imposes stringent requirements on hardware such as pumps, valves, injectors, connecting tubing, and columns. One of the most difficult components of the UHPLC system to develop has been the sample injector. Static-split injection, which can be performed at pressures up to 6900 bar (100,000 psi), consumes a large sample volume and is very irreproducible. A pressure-balanced injection valve provided better reproducibility, shorter injection time, reduced sample consumption, and greater ease of use; however, it could only withstand pressures up to approximately 1000 bar (15,000 psi). In this study, a new injection valve assembly that can operate at pressures as high as 2070 bar (30,000 psi) was evaluated for UHPLC. This assembly contains six miniature electronically controlled needle valves to provide accurate and precise volumes for introduction into the capillary LC column. It was found that sample volumes as small as several tenths of a nanoliter can be injected, which are comparable to the results obtained from the static-split injector. The reproducibilities of retention time, efficiency, and peak area were investigated, and the results showed that the relative standard deviations of these parameters were small enough for quantitative analyses. Separation experiments using the UHPLC system with this new injection valve assembly showed that this new injector is suitable for both isocratic and gradient operation modes. A newly designed capillary connector was used at a pressure as high as 2070 bar (30,000 psi).

Elasticity of water-saturated rocks as a function of temperature and pressure.

NASA Technical Reports Server (NTRS)

Takeuchi, S.; Simmons, G.

1973-01-01

Compressional and shear wave velocities of water-saturated rocks were measured as a function of both pressure and temperature near the melting point of ice to confining pressure of 2 kb. The pore pressure was kept at about 1 bar before the water froze. The presence of a liquid phase (rather than ice) in microcracks of about 0.3% porosity affected the compressional wave velocity by about 5% and the shear wave velocity by about 10%. The calculated effective bulk modulus of the rocks changes rapidly over a narrow range of temperature near the melting point of ice, but the effective shear modulus changes gradually over a wider range of temperature. This phenomenon, termed elastic anomaly, is attributed to the existence of liquid on the boundary between rock and ice due to local stresses and anomalous melting of ice under pressure.

Paragneiss zircon geochronology and trace element geochemistry, North Qaidam HP/UHP terrane, western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Zhang, J.X.; Bird, D.K.

2009-01-01

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ???3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ?? 5 Ma and 426 ?? 4 Ma reflect eclogite-facies zircon growth in two of the samples. Ti-in-zircon thermometry results are tightly grouped at ???660 and ???600 ??C, respectively. Inclusions of metamorphic minerals, scarcity of inherited cores, and lack of isotopic or trace element inheritance demonstrate that significant new metamorphic zircon growth must have occurred. In contrast, zircon in the third sample is dominated by inherited grains, and rims show isotopic and trace element inheritance, suggesting solid-state recrystallization of detrital zircon with only minor new growth. ?? 2009 Elsevier Ltd.

Wave Shape and Impact Pressure Measurements at a Rock Coast Cliff

NASA Astrophysics Data System (ADS)

Varley, S. J.; Rosser, N. J.; Brain, M.; Vann Jones, E. C.

2016-02-01

Rock coast research focuses largely on wave behaviour across beaches and shore platforms but rarely considers direct wave interaction with cliffs. Hydraulic action is one of the most important drivers of erosion along rock coasts. The magnitude of wave impact pressure has been shown by numerical and laboratory studies to be related to the wave shape. In deep water, a structure is only subjected to the hydrostatic pressure due to the oscillating clapotis. Dynamic pressures, related to the wave celerity, are exerted in shallower water when the wave is breaking at the point of impact; very high magnitude, short duration shock pressures are theorised to occur when the approaching wavefront is vertical. As such, wave shape may directly influence the potential of the impact to weaken rock and cause erosion. Measurements of impact pressure at coastal cliffs are limited, and the occurrence and influence of this phenomenon is currently poorly constrained. To address this, we have undertaken a field monitoring study on the magnitude and vertical distribution of wave impact pressures at the rocky, macro-tidal coastline of Staithes, North Yorkshire, UK. A series of piezo-resistive pressure transducers and a camera were installed at the base of the cliff during low tide. Transducers were deployed vertically up the cliff face and aligned shore-normal to capture the variation in static and dynamic pressure with height during a full spring tidal cycle. Five minute bursts of 5 kHz pressure readings and 4 Hz wave imaging were sampled every 30 minutes for six hours during high tide. Pressure measurements were then compensated for temperature and combined with wave imaging to produce a pressure time series and qualitative wave shape category for each wave impact. Results indicate the presence of a non-linear relationship between pressure impact magnitude, the occurrence of shock pressures, wave shape and tidal stage, and suggest that breaker type on impact (and controls thereof) may

Petrology and fluid inclusions of garnet-clinopyroxene rocks from the Gondwana suture zone in southern India: Implications for prograde high-pressure metamorphism

NASA Astrophysics Data System (ADS)

Tsunogae, T.

2012-04-01

, which is consistent with the occurrence of high-pressure Mg-rich staurolite in Mg-Al-rich rocks from this region. Fluid inclusion study of some garnet-clinopyroxene rock samples identified CO2-rich fluid inclusions trapped as primary phases within garnet, suggesting that prograde high-pressure metamorphism was dominated by CO2-rich fluids. The results therefore confirmed that the PCSZ underwent regional dry high-pressure metamorphism followed by the peak ultrahigh-temperature event probably associated with the continent-continent collisional and suturing history along the PCSZ.

Experimental Studies on Permeability of Intact and Singly Jointed Meta-Sedimentary Rocks Under Confining Pressure

NASA Astrophysics Data System (ADS)

Wong, Louis Ngai Yuen; Li, Diyuan; Liu, Gang

2013-01-01

Three different types of permeability tests were conducted on 23 intact and singly jointed rock specimens, which were cored from rock blocks collected from a rock cavern under construction in Singapore. The studied rock types belong to inter-bedded meta-sandstone and meta-siltstone with very low porosity and high uniaxial compressive strength. The transient pulse water flow method was employed to measure the permeability of intact meta-sandstone under a confining pressure up to 30 MPa. It showed that the magnitude order of meta-sandstone's intrinsic permeability is about 10-18 m2. The steady-state gas flow method was used to measure the permeability of both intact meta-siltstone and meta-sandstone in a triaxial cell under different confining pressures spanning from 2.5 to 10 MPa. The measured permeability of both rock types ranged from 10-21 to 10-20 m2. The influence of a single natural joint on the permeability of both rock types was studied by using the steady-state water flow method under different confining pressures spanning from 1.25 to 5.0 MPa, including loading and unloading phases. The measured permeability of both jointed rocks ranged from 10-13 to 10-11 m2, where the permeability of jointed meta-siltstone was usually slightly lower than that of jointed meta-sandstone. The permeability of jointed rocks decreases with increasing confining pressure, which can be well fitted by an empirical power law relationship between the permeability and confining pressure or effective pressure. The permeability of partly open cracked specimens is lower than that of open cracked specimens, but it is higher than that of the specimen with a dominant vein for the meta-sandstone under the same confining pressure. The permeability of open cracked rock specimens will partially recover during the unloading confining pressure process. The equivalent crack (joint) aperture is as narrow as a magnitude order of 10-6 m (1 μm) in the rock specimens under confining pressures

Thermomagnetic and thermoelectric properties of semiconductors (PbTe, PbSe) at ultrahigh pressures

NASA Astrophysics Data System (ADS)

Ovsyannikov, Sergey V.; Shchennikov, Vladimir V.

2004-02-01

The longitudinal and transverse thermomagnetic Nernst-Ettingshausen (LNE, TNE) effects and the Maggi-Reghi-Leduc (MRL) effect were measured on PbTe and PbSe micro-samples at ultrahigh pressures upto 20 GPa. Values of the mobility of charge carriers as well as the scattering parameter were estimated both for the low- and high-pressure phase of PbTe and PbSe. At about 3 GPa, the maxima of both Nernst-Ettingshausen effects and magnetoresistance (MR) (and hence of the mobility of charge carriers μ), attributed to the gapless state of PbTe and PbSe were established. The TNE effect was found to be the largest among the effects measured, while the MRL was hardly visible even at the highest mobility values of the charge carriers. The possibilities for using thermomagnetic effects in micro-device technologies are discussed.

High pressure reaction cell and transfer mechanism for ultrahigh vacuum spectroscopic chambers

NASA Astrophysics Data System (ADS)

Nelson, A. E.; Schulz, K. H.

2000-06-01

A novel high pressure reaction cell and sample transfer mechanism for ultrahigh vacuum (UHV) spectroscopic chambers is described. The design employs a unique modification of a commercial load-lock transfer system to emulate a tractable microreactor. The reaction cell has an operating pressure range of <1×10-4 to 1000 Torr and can be evacuated to UHV conditions to enable sample transfer into the spectroscopic chamber. Additionally, a newly designed sample holder equipped with electrical and thermocouple contacts is described. The sample holder is capable of resistive specimen heating to 400 and 800 °C with current requirements of 14 A (2 V) and 25 A (3.5 V), respectively. The design enables thorough material science characterization of catalytic reactions and the surface chemistry of catalytic materials without exposing the specimen to atmospheric contaminants. The system is constructed primarily from readily available commercial equipment allowing its rapid implementation into existing laboratories.

First occurrence of very low pressure ultra-high temperatures metamorphism in the Khondalite Belt, North China Craton.

NASA Astrophysics Data System (ADS)

Lobjoie, Cyril; Lin, Wei; Trap, Pierre; Goncalves, Philippe; Marquer, Didier

2016-04-01

This study report the first occurrence of very low pressure (<0.4GPa) ultra-high temperatures metamorphism within the Paleoproterozoic Khondalite Belt of the North China Craton. This high grade orogenic domain is mostly composed of garnet +/- spinel +/- sapphirine-bearing migmatites, numerous Grt-bearing granites and marbles. These rocks are intruded by numerous metric to kilometric mafic intrusions. Petrological analyses and phase equilibria diagram modeling were performed on garnet and spinel-bearing and olivine-bearing migmatites. Garnet and spinel-bearing migmatites show a quartz, ternary feldspar, garnet, biotite sillimanite and spinel main assemblage. Pseudosection diagram calculations give suprasolidus P-T conditions around ca. 0.7GPa for ca. 900°C that correspond to the peak temperature conditions. Thermometry using ternary feldspar thermometry gives temperatures estimations at ca. 950-1015°C for a pressure of 0.7GPa. The Olivine-bearing migmatite, located at the contact with a mafic intrusion, shows two main assemblages. The first assemblage that makes the rock matrix consists of a micrographic quartz and feldspar domains associated with biotite, sillimanite and spinel. The second assemblage appears within mm-scale pockets with a complex symplectitic texture. Careful investigation revealed that theses pockets formed after garnet pseudomorphosis, with the development of an Opx-Sp-Crd association. Within this assemblage, an olivine-cordierite and Opx-Crd-Bi-Qtz assemblage occurred as smaller pockets. The petrogenetic grid and pseudosection calculations made for this olivine-bearing migmatite give P-T conditions around 0.35GPa for ca. 950°C that correspond to the peak temperature conditions recorded by the olivine-cordierite assemblage. The succession of reactions with garnet pseudomorphosis into an Opx-Spl-Crd followed by the crystallization of an Ol-Crd assemblage is modelled in the petrogenetic grid calculation and correspond to an isobaric clockwise P

Flavor characterization of sugar-added pennywort (Centella asiatica L.) juices treated with ultra-high pressure and thermal processes.

PubMed

Apichartsrangkoon, Arunee; Wongfhun, Pronprapa; Gordon, Michael H

2009-01-01

The flavor characteristics of pennywort juices with added sugar treated by ultra-high pressure, pasteurization, and sterilization were investigated using solid phase microextraction combined with gas chromatography-mass spectrometry. It was found that sesquiterpene hydrocarbons comprised the major class of volatile components present and the juices had a characteristic aroma due to the presence of volatiles including beta-caryophyllene and humulene and alpha-copaene. In comparison with heated juices, HPP-treated samples could retain more volatile compounds such as linalool and geraniol similar to those present in fresh juice, whereas some volatiles such as alpha-terpinene and ketone class were apparently formed by thermal treatment. All processing operations produced juice that was not significantly different in the concentration of total volatiles. Practical Application: Pennywort juice is considered a nutraceutical drink for health benefits. Therefore, to preserve all aroma and active components in this juice, a nonthermal process such as ultra-high pressure should be a more appropriate technique for retention of its nutritive values than pasteurization and sterilization.

Oxygen Fugacity Variation From Mantle Transition Zone To Ocean Ridges Recorded By In Situ Diamond-Bearing Peridotite Of Indus Ophiolite

NASA Astrophysics Data System (ADS)

Das, S.; Basu, A. R.

2017-12-01

Our recently discovered transition zone ( 410 - 660 Km) -derived peridotites in the Indus Ophiolite, Ladakh Himalaya [1] provide a unique opportunity to study changes in oxygen fugacity from shallow mantle beneath ocean ridges to mantle transition zone. We found in situ diamond, graphite pseudomorphs after diamond crystals, hydrocarbon (C - H) and hydrogen (H2) fluid inclusions in ultra-high pressure (UHP) peridotites that occur in the mantle - section of the Indus ophiolite and sourced from the mantle transition zone [2]. Diamond occurs as octahedral inclusion in orthoenstatite of one of these peridotites. The graphite pseudomorphs after diamond crystals and primary hydrocarbon (C-H), and hydrogen (H2) fluids are included in olivine of this rock. Hydrocarbon fluids are also present as inclusions in high pressure clinoenstatite (> 8 GPa). The association of primary hydrocarbon and hydrogen fluid inclusions in the UHP peridotites suggest that their source-environment was highly reduced at the base of the upper mantle. We suggest that during mantle upwelling beneath Neo Tethyan spreading center, the hydrocarbon fluid was oxidized and precipitated diamond. The smaller diamonds converted to graphite at shallower depth due to size, high temperature and elevated oxygen fugacity. This process explains how deep mantle upwelling can oxidize reduced fluid carried from the transition zone to produce H2O - CO2. The H2O - CO2 fluids induce deep melting in the source of the mid oceanic ridge basalts (MORB) that create the oceanic crust. References: [1] Das S, Mukherjee B K, Basu A R, Sen K, Geol Soc London, Sp 412, 271 - 286; 2015. [2] Das S, Basu A R, Mukherjee B K, Geology 45 (8), 755 - 758; 2017.

Electrical conductivity of rocks at high pressures and temperatures

NASA Technical Reports Server (NTRS)

Parkhomenko, E. I.; Bondarenko, A. T.

1986-01-01

The results of studies of the electrical conductivity in the most widely distributed types of igneous rocks, at temperatures of up to 1200 C, at atmospheric pressure, and also at temperatures of up to 700 C and at pressures of up to 20,000 kg/sq cm are described. The figures of electrical conductivity, of activaation energy and of the preexponential coefficient are presented and the dependence of these parameters on the petrochemical parameters of the rocks are reviewed. The possible electrical conductivities for the depository, granite and basalt layers of the Earth's crust and of the upper mantle are presented, as well as the electrical conductivity distribution to the depth of 200 to 240 km for different geological structures.

In situ study of maize starch gelatinization under ultra-high hydrostatic pressure using X-ray diffraction.

PubMed

Yang, Zhi; Gu, Qinfen; Hemar, Yacine

2013-08-14

The gelatinization of waxy (very low amylose) and high-amylose maize starches by ultra-high hydrostatic pressure (up to 6 GPa) was investigated in situ using synchrotron X-ray powder diffraction on samples held in a diamond anvil cell (DAC). The starch pastes, made by mixing starch and water in a 1:1 ratio, were pressurized and measured at room temperature. X-ray diffraction pattern showed that at 2.7 GPa waxy starch, which displayed A-type XRD pattern at atmospheric pressure, exhibited a faint B-type-like pattern. The B-type crystalline structures of high-amylose starch were not affected even when 1.5 GPa pressure was applied. However, both waxy and high-amylose maize starches can be fully gelatinized at 5.9 GPa and 5.1 GPa, respectively. In the case of waxy maize starch, upon release of pressure (to atmospheric pressure) crystalline structure appeared as a result of amylopectin aggregation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Ultra-high pressure water jetting for coating removal and surface preparation

NASA Technical Reports Server (NTRS)

Johnson, Spencer T.

1995-01-01

This paper shall examine the basics of water technology with particular attention paid to systems currently in use and some select new applications. By providing an overview of commercially available water jet systems in the context of recent case histories, potential users may evaluate the process for future applications. With the on going introduction of regulations prohibiting the use of chemical paint strippers, manual scrapping and dry abrasive media blasting, the need for an environmentally compliant coating removal process has been mandated. Water jet cleaning has been a traditional part of many industrial processed for year, although it has only been in the last few years that reliable pumping equipment capable of ultra-high pressure operation have become available. With the advent of water jet pumping equipment capable of sustaining pressures in excess of 36,000 psi. there has been shift away from lower pressure, high water volume systems. One of the major factors in driving industry to seek higher pressures is the ability to offer higher productivity rates while lowering the quantity of water used and subsequently reprocessed. Among benefits of the trend toward higher pressure/lower volume systems is the corresponding reduction in water jet reaction forces making hand held water jetting practical and safe. Other unique applications made possible by these new generation pumping systems include the use of alternative fluids including liquid ammonia for specialized and hazardous material removal applications. A review of the equipment used and the required modifications will be presented along with the conclusions reached reached during this test program.

Activation of the E1 Ultra High Pressure Propulsion Test Facility at Stennis Space Center

NASA Technical Reports Server (NTRS)

Messer, Bradley; Messer, Elisabeth; Sewell, Dale; Sass, Jared; Lott, Jeff; Dutreix, Lionel, III

2001-01-01

After a decade of construction and a year of activation the El Ultra High Pressure Propulsion Test Facility at NASA's Stennis Space Center is fully operational. The El UHP Propulsion Test Facility is a multi-cell, multi-purpose component and engine test facility . The facility is capable of delivering cryogenic propellants at low, high, and ultra high pressures with flow rates ranging from a few pounds per second up to two thousand pounds per second. Facility activation is defined as a series of tasks required to transition between completion of construction and facility operational readiness. Activating the El UHP Propulsion Test Facility involved independent system checkouts, propellant system leak checks, fluid and gas sampling, gaseous system blow downs, pressurization and vent system checkouts, valve stability testing, valve tuning cryogenic cold flows, and functional readiness tests.

Constraints on the Amount of deeply subducted Water from numerical Models in comparison with natural Samples

NASA Astrophysics Data System (ADS)

Konrad-Schmolke, M.; Halama, R.

2014-12-01

The subduction of hydrated slab mantle to beyond-arc depths is the most important and yet weakly constrained factor in the quantification of the Earth's deep geologic water cycle. During subduction of hydrated oceanic lithosphere, dehydration reactions in the downgoing plate lead to a partitioning of water between upper and lower plate. Water retained in the slab is recycled into the mantle where it controls its rheology and thus plate tectonic velocities. Hence, quantification of the water partitioning in subduction zones is crucial for the understanding of mass transfer between the Earth's surface and the mantle. Combined thermomechanical and thermodynamic models yield quantitative constraints on the water cycle in subduction zones, but unless model results can be linked to natural observations, the reliability of such models remains speculative. We present combined thermomechanical, thermodynamic and geochemical models of active and paleo-subduction zones, whose results can be tested with independent geochemical features in natural rocks. In active subduction zones, evidence for the validity of our model comes from the agreement between modeled and observed across-arc trends of boron concentrations and isotopic compositions in arc volcanic rocks. In the Kamchatkan subduction zone, for example, the model successfully predicts complex geochemical patterns and the spatial distribution of arc volcanoes. In paleo-subduction zones (e.g. Western Gneiss Region and Western Alps), constraints on the water budget and dehydration behavior of the subducting slab come from trace element zoning patterns in ultra-high pressure (UHP) garnets. Distinct enrichments of Cr, Ni and REE in the UHP zones of the garnets can be reconciled by our models that predict intense rehydration and trace element re-enrichment of the eclogites at UHP conditions by fluids released from the underlying slab mantle. Models of present-day subduction zones indicate the presence of 2.5-6 wt.% of water

Petrology, geochemistry and isotopic ages of eclogites from the Dulan UHPM Terrane, the North Qaidam, NW China

NASA Astrophysics Data System (ADS)

Song, Shuguang; Yang, Jingsui; Liou, J. G.; Wu, Cailai; Shi, Rendeng; Xu, Zhiqin

2003-10-01

The Dulan eclogite-gneiss region is located in the eastern part of the North Qaidam eclogite belt, NW China. Widespread evidence demonstrates that this region is a typical ultrahigh-pressure (UHP) metamorphic terrane. Eclogites occur as lenses or layers in both granitic and pelitic gneisses. Two distinguished sub-belts can be recognized and differ in mineralogy, petrology and geochemistry. The North Dulan Belt (NDB) has tholeiitic protoliths with high TiO 2 and lower Al 2O 3 and MgO contents. REE patterns and trace element contents resemble those of N-type and E-type MORB. In contrast, eclogites in the South Dulan Belt (SDB) are of island arc protoliths with low TiO 2, high Al 2O 3 and show LREE-enriched and HFSE-depleted patterns. Sm-Nd isotope analyses give isochron ages of 458-497 Ma for eclogite-facies metamorphism for the two sub-belts. The ages are similar to those of Yuka and Altun eclogites in the western extension of the North Qaidam-Altun eclogite belt. The Dulan UHP metamorphic terrane, together with several other recently recognized eclogite-bearing terrenes within the North Qaidam-Altun HP-UHP belt, constitute the key to the understanding of the tectonic evolution of the northern Tibetan Plateau. The entire UHP belt extends for more than 1000 km from the Dulan UHP terrane in the southeast to the Altun eclogite-gneiss terrane in the west. This super-belt marks an early Paleozoic continental collision zone between the Qaidam Massif and the Qilian Massif.

PREFACE: Rheology and Elasticity Studies at Ultra-High Pressures and Temperatures

NASA Astrophysics Data System (ADS)

Liu, Haozhe; Wenk, Hans-Rudolf; Duffy, Thomas S.

2006-06-01

One of the major goals of geophysical research is to understand deformation in the deep Earth. The COMPRES (Consortium for Materials Properties Research in Earth Sciences) workshop on `Rheology and Elasticity Studies at Ultra-High Pressures and Temperatures' was held on 21-23 October 2005 at the Advanced Photon Source, Argonne National Laboratory, organized by Haozhe Liu, Hans-Rudolf Wenk and Thomas S Duffy, and provided an opportunity to assemble more than 50 scientists from six countries. Experts in diamond anvil cell (DAC) design, large-volume high-pressure apparatus and data analysis defined the current state of ultra-high pressure deformation studies and explored initiatives to push the technological frontier. The DAC, when used in radial diffraction geometry, emerges as a powerful tool for investigation of plasticity and elasticity of materials at high pressures. More information regarding this workshop can be found at the website: http://www.hpcat.aps.anl.gov/Hliu/Workshop/Index1.htm. In this special issue of Journal of Physics: Condensed Matter, 17 manuscripts review the state-of-the-art and we hope they will stimulate researchers to participate in this field and take it forward to a new level. A major incentive for high-pressure research has been the need of geophysicists to understand composition, physical properties and deformation in the deep Earth in order to interpret the macroscopically observed seismic anisotropy. In the mantle and core, materials deform largely in a ductile manner at low stresses and strain rates. From observational inferences and experiments at lower pressures, it is considered plausible that deformation occurs in the field of dislocation creep or diffusion creep and deformation mechanisms depend in a complex way on stress, strain rate, pressure, temperature, grain size and hydration state. With novel apparatus such as the rotational Drickamer press or deformation DIA (D-DIA) multianvil apparatus, large volumes (approximately 10

X-ray diffraction investigation of amorphous calcium phosphate and hydroxyapatite under ultra-high hydrostatic pressure

NASA Astrophysics Data System (ADS)

Lam, Elisa; Gu, Qinfen; Swedlund, Peter J.; Marchesseau, Sylvie; Hemar, Yacine

2015-11-01

The changes in the crystal structures of synthetically prepared amorphous calcium phosphate (ACP) and hydroxyapatite (HAP) in water (1:1 mass ratio) were studied by synchrotron X-ray diffraction (XRD) under ultra-high hydrostatic pressures as high as 2.34 GPa for ACP and 4 GPa for HAP. At ambient pressure, the XRD patterns of the ACP and HAP samples in capillary tubes and their environmental scanning electron micrographs indicated amorphous and crystalline characteristics for ACP and HAP, respectively. At pressures greater than 0.25 GPa, an additional broad peak was observed in the XRD pattern of the ACP phase, indicating a partial phase transition from an amorphous phase to a new high-pressure amorphous phase. The peak areas and positions of the ACP phase, as obtained through fitting of the experimental data, indicated that the ACP exhibited increased pseudo-crystalline behavior at pressures greater than 0.96 GPa. Conversely, no structural changes were observed for the HAP phase up to the highest applied pressure of 4 GPa. For HAP, a unit-cell reduction during compression was evidenced by a reduction in both refined lattice parameters a and c. Both ACP and HAP reverted to their original structures when the pressure was fully released to ambient pressure.

Mechanical and Thermophysical Properties of Cubic Rock-Salt AlN Under High Pressure

NASA Astrophysics Data System (ADS)

Lebga, Noudjoud; Daoud, Salah; Sun, Xiao-Wei; Bioud, Nadhira; Latreche, Abdelhakim

2018-03-01

Density functional theory, density functional perturbation theory, and the Debye model have been used to investigate the structural, elastic, sound velocity, and thermodynamic properties of AlN with cubic rock-salt structure under high pressure, yielding the equilibrium structural parameters, equation of state, and elastic constants of this interesting material. The isotropic shear modulus, Pugh ratio, and Poisson's ratio were also investigated carefully. In addition, the longitudinal, transverse, and average elastic wave velocities, phonon contribution to the thermal conductivity, and interesting thermodynamic properties were predicted and analyzed in detail. The results demonstrate that the behavior of the elastic wave velocities under increasing hydrostatic pressure explains the hardening of the corresponding phonons. Based on the elastic stability criteria under pressure, it is found that AlN with cubic rock-salt structure is mechanically stable, even at pressures up to 100 GPa. Analysis of the Pugh ratio and Poisson's ratio revealed that AlN with cubic rock-salt structure behaves in brittle manner.

Pore Pressure and Stress Distributions Around a Hydraulic Fracture in Heterogeneous Rock

NASA Astrophysics Data System (ADS)

Gao, Qian; Ghassemi, Ahmad

2017-12-01

One of the most significant characteristics of unconventional petroleum bearing formations is their heterogeneity, which affects the stress distribution, hydraulic fracture propagation and also fluid flow. This study focuses on the stress and pore pressure redistributions during hydraulic stimulation in a heterogeneous poroelastic rock. Lognormal random distributions of Young's modulus and permeability are generated to simulate the heterogeneous distributions of material properties. A 3D fully coupled poroelastic model based on the finite element method is presented utilizing a displacement-pressure formulation. In order to verify the model, numerical results are compared with analytical solutions showing excellent agreements. The effects of heterogeneities on stress and pore pressure distributions around a penny-shaped fracture in poroelastic rock are then analyzed. Results indicate that the stress and pore pressure distributions are more complex in a heterogeneous reservoir than in a homogeneous one. The spatial extent of stress reorientation during hydraulic stimulations is a function of time and is continuously changing due to the diffusion of pore pressure in the heterogeneous system. In contrast to the stress distributions in homogeneous media, irregular distributions of stresses and pore pressure are observed. Due to the change of material properties, shear stresses and nonuniform deformations are generated. The induced shear stresses in heterogeneous rock cause the initial horizontal principal stresses to rotate out of horizontal planes.

Insights into a fossil plate interface of an erosional subduction zone: a tectono-metamorphic study of the Tianshan metamorphic belt.

NASA Astrophysics Data System (ADS)

Bayet, Lea; Moritz, Lowen; Li, Jilei; Zhou, Tan; Agard, Philippe; John, Timm; Gao, Jun

2016-04-01

Subduction zone seismicity and volcanism are triggered by processes occurring at the slab-wedge interface as a consequence of metamorphic reactions, mass-transfer and deformation. Although the shallow parts of subduction zones (<30-40 km) can be partly accessed by geophysical methods, the resolution of these techniques is insufficient to characterize and image the plate interface at greater depths (>60km). In order to better understand the plate interface dynamics at these greater depths, one has to rely on the rock record from fossil subduction zones. The Chinese Tianshan metamorphic belt (TMB) represents an ideal candidate for such studies, because structures are well exposed with exceptionally fresh high-pressure rocks. Since previous studies from this area focused on fluid-related processes and its metamorphic evolution was assessed on single outcrops, the geodynamic setting of this metamorphic belt is unfortunately heavily debated. Here, we present a new geodynamic concept for the TMB based on detailed structural and petrological investigations on a more regional scale. A ~11km x 13km area was extensively covered, together with E-W and N-S transects, in order to produce a detailed map of the TMB. Overall, the belt is composed of two greenschist-facies units that constitute the northern and southern border of a large high-pressure (HP) to ultra high-pressure (UHP) unit in the center. This HP-UHP unit is mainly composed of metasediments and volcanoclastic rocks, with blueschist, eclogite and carbonate lenses. Only the southern part of the HP-UHP unit is composed of the uppermost part of an oceanic crust (e.g., pillow basalts and deep-sea carbonates). From south to north, the relative abundance and size of blueschist massive boudins and layers (as well as eclogite boudins) decreases and the sequence is increasingly interlayered with metasedimentary and carbonate-rich horizons. This indicates that the subducted material was dominated by trench filling made of

On protolith-, metamorphic overprint, microstructure and rheology of mineral assemblages in orogenic peridotites of the central Scandinavian Caledonides

NASA Astrophysics Data System (ADS)

Gilio, Mattia; Clos, Frediano; Van Roermund, Herman L. M.

2013-04-01

The Scandinavian Caledonides (SC) are a deeply eroded Alpine-type orogenic belt formed by closure of the Iapetus ocean and collision between Baltica and Laurentia (500-380 Ma). The SC consists of a stack of Nappe Complexes (from bottom to top called Lower, Middle, Upper and Uppermost Allochthons) thrusted to the east over the Baltic Shield (Brueckner and Van Roermund, 2004; Gee et al., 2008). Fossil lithospheric mantle fragments, called orogenic peridotites, have been found within the (upper part of) middle, upper and uppermost Allochthons, as well as in the reworked basement gneisses (a.o Western Gneiss Complex (WGC)) along the Norwegian west coast. They occur as isolated lenses that contain diverse mineral parageneses and/or bulk rock compositions. Crustal incorporation of orogenic peridotite is classically interpreted to be the result of plate collisional processes related to orogeny (Brueckner and Medaris, 2000). The WGC and parts of the upper part of the Middle Allochthon (a.o. Seve Nappe Complex (SNC) in N Jämtland/S Västerbotten, central Sweden), are well known for the occurrence of high (HP) and ultrahigh pressure (UHP) metamorphic terranes (of Caledonian age). The (U)HPM evidence clearly demonstrates the deep metamorphic origin of these rocks interpreted to be caused by continental subduction and/or collision. Other metamorphic rocks (of Caledonian age) exposed in allochthonous nappes are solely characterised by greenschist-, amphibolite- and/or MP granulite "facies" mineral assemblages that can be interpreted, in the absence of retrogression, to have formed in less deeply subducted (and/or metamorphic) environments. This duality in metamorphic "facies" allows for a discrimination (at least theoretically) between "deep" versus "shallow" rooted nappes (in central parts of the Scandinavian Caledonides). Conform this reasoning, this duality should also be present within the Caledonian mineral assemblages (= metamorphic overprint) of orogenic peridotites (in

How does recycling of sediment components in arc magmatism really work?

NASA Astrophysics Data System (ADS)

Kelemen, P.; Hacker, B.; Austin, N.

2007-12-01

Past work indicates substantial recycling of a sediment component rich in LILE, Th, Sr, Pb and LREE in arcs. For example, in the relatively well-constrained case of Central America, Plank et al (Geology 02) estimate that 80% of subducted, sedimentary Th is recycled in arc magmas. To understand how such a component is transferred from subducted sediment to arc lava, we examined trace-element variation in (a) mid-crustal (0.4 GPa) contact metamorphic rocks (Austin & Kelemen, Fall 06 AGU) and (b) ultrahigh-pressure (UHP, > 3 GPa) metasediments. Most UHP samples were metamorphosed along subduction-zone geotherms (Hacker, Int Geol Rev 06), but some record substantially higher T (e.g., Erzgebirge & Kokchetav, Massone EPSL 03). Unmelted, mid-crustal metapelites are indistinguishable from pelitic sediments for the entire suite of elements analyzed by ICP-MS at WSU. Melt extraction from the mid-crustal metapelites led to systematic depletion of incompatible elements in high-grade hornfels. Depletion increases with decreasing distance to the contact with a mafic pluton, most clearly at peak T > 750°C. In contrast, although many UHP metapelites record PT above the aqueous fluid-saturated solidus, and have fluid inclusions and/or hydrous phases, compared to pelites they show no detectable depletion of "fluid-mobile" elements such as LILE (Cs, Rb, Ba, U, K), Sr and Pb, no depletion of "fluid-immobile, incompatible" elements such as Th and LREE, and no systematic change in key soluble/insoluble ratios such as Ba/Th or K/Zr up to ~1000 C. Mobility of incompatible elements is evident for T > 1000 C, well above PT for subduction-zone geotherms. Presumably, trace phases rich in LILE, Th and LREE persist to ~1050 C in metapelites at UHP conditions.How can our observations be reconciled with the recycled sediment component in arc lavas? Our preferred hypothesis is that low-density metasediments rise into the mantle wedge when heating yields viscosities low enough for density

Diamonds in ophiolitic mantle rocks and podiform chromitites: An unsolved mystery

NASA Astrophysics Data System (ADS)

Yang, J.; Zhang, Z.; Xu, X.; Ba, D.; Bai, W.; Fabg, Q.; Meng, F.; Chen, S.; Robinson, P. T.; Dobrzhinetskaya, L.

2009-05-01

In recent years ultrahigh pressure minerals, such as diamond and coesite, and other unusual minerals were discovered in chromitites of the Luobusa ophiolite in Tibet, and 4 new minerals have been approved by the CNMMN. These results have raised many questionsWhat are the occurrences of the diamonds, what is the source of their carbon and how were they formed? What is the origin of the chromites hosting the diamonds and at what depth did they form? What is the genetic relationship between the diamonds and the host chromitites? In what geological, geophysical and geochemical environments can the diamonds be formed and how are they preserved? The UHP minerals from Luobusa are controversial because they have not been found in situ and because ophiolites are currently believed to form at shallow levels above oceanic spreading centers in suprasubduction zone environments. More detailed study and experimental work are needed to understand the origin and significance of these unusual minerals and investigations of other ophiolites are needed to determine if such minerals occur elsewhere To approach these problems, we have collected two one-ton samples of harzburgite hosting chromitite orebodies in the Luobusa ophiolite in Tibet. The harzburgite samples were taken close to chromitite orebody 31, from which the diamonds, coesite and other unusual minerals were recovered. We processed these two samples in the same manner as the chromitites and discovered numerous diamonds and more than 50 other mineral species. These preliminary results show that the minerals in the harzburgites are similar to those in the chromitites, suggesting a genetic relationship between them. To determine if such UHP and unusual minerals occur elsewhere, we collected about 1.5 t of chromitite from two orebodies in an ultramafic body in the Polar Urals. Thus far, more than 60 different mineral species have been separated from these ores. The most exciting discovery is the common occurrence of diamond, a

Lithology and mineralogy recognition from geochemical logging tool data using multivariate statistical analysis.

PubMed

Konaté, Ahmed Amara; Ma, Huolin; Pan, Heping; Qin, Zhen; Ahmed, Hafizullah Abba; Dembele, N'dji Dit Jacques

2017-10-01

The availability of a deep well that penetrates deep into the Ultra High Pressure (UHP) metamorphic rocks is unusual and consequently offers a unique chance to study the metamorphic rocks. One such borehole is located in the southern part of Donghai County in the Sulu UHP metamorphic belt of Eastern China, from the Chinese Continental Scientific Drilling Main hole. This study reports the results obtained from the analysis of oxide log data. A geochemical logging tool provides in situ, gamma ray spectroscopy measurements of major and trace elements in the borehole. Dry weight percent oxide concentration logs obtained for this study were SiO 2 , K 2 O, TiO 2 , H 2 O, CO 2 , Na 2 O, Fe 2 O 3 , FeO, CaO, MnO, MgO, P 2 O 5 and Al 2 O 3 . Cross plot and Principal Component Analysis methods were applied for lithology characterization and mineralogy description respectively. Cross plot analysis allows lithological variations to be characterized. Principal Component Analysis shows that the oxide logs can be summarized by two components related to the feldspar and hydrous minerals. This study has shown that geochemical logging tool data is accurate and adequate to be tremendously useful in UHP metamorphic rocks analysis. Copyright © 2017 Elsevier Ltd. All rights reserved.

A Novel Layered Sedimentary Rocks Structure of the Oxygen-Enriched Carbon for Ultrahigh-Rate-Performance Supercapacitors.

PubMed

Zhang, Lin-Lin; Li, Huan-Huan; Shi, Yan-Hong; Fan, Chao-Ying; Wu, Xing-Long; Wang, Hai-Feng; Sun, Hai-Zhu; Zhang, Jing-Ping

2016-02-17

In this paper, gelatin as a natural biomass was selected to successfully prepare an oxygen-enriched carbon with layered sedimentary rocks structure, which exhibited ultrahigh-rate performance and excellent cycling stability as supercapacitors. The specific capacitance reached 272.6 F g(-1) at 1 A g(-1) and still retained 197.0 F g(-1) even at 100 A g(-1) (with high capacitance retention of 72.3%). The outstanding electrochemical performance resulted from the special layered structure with large surface area (827.8 m(2) g(-1)) and high content of oxygen (16.215 wt %), which effectively realized the synergistic effects of the electrical double-layer capacitance and pseudocapacitance. Moreover, it delivered an energy density of 25.3 Wh kg(-1) even with a high power density of 34.7 kW kg(-1) and ultralong cycling stability (with no capacitance decay even over 10,000 cycles at 2 A g(-1)) in a symmetric supercapacitor, which are highly desirable for their practical application in energy storage devices and conversion.

Study on the Pressure Pulsation inside Runner with Splitter Blades in Ultra-High Head Turbine

NASA Astrophysics Data System (ADS)

Meng, L.; Zhang, S. P.; Zhou, L. J.; Wang, Z. W.

2014-03-01

Runners with splitter blades were used widely for the high efficiency and stability. In this paper, the unsteady simulation of an ultra-high head turbine at the best efficiency point, 50% and 75% discharge points were established, to analyze the pressure pulsation in the vaneless space, rotating domain and the draft tube. First of all, runners with different length splitter blades and without splitter blades were compared to learn the efficiency and the pressure distribution on the blade surface. And then the amplitude of the pressure pulsation was analysed. The peak efficiency of the runner with splitter blades is remarkably higher than that of the corresponding impeller without splitter blades. And the efficiency of the turbine is the highest when the length ratio of the splitter blades is 0.75 times the main blades. The pressure pulsation characteristics were also influenced, because the amplitudes of the pulsation induced by the RSI phenomenon were changed as a result of more blades. At last, the best design plan of the length of the splitter blades (length ratio=0.825) was obtained, which improved the pressure pulsation characteristics without significant prejudice to the efficiency.

An effective medium approach to modelling the pressure-dependent electrical properties of porous rocks

NASA Astrophysics Data System (ADS)

Han, Tongcheng

2018-07-01

Understanding the electrical properties of rocks under varying pressure is important for a variety of geophysical applications. This study proposes an approach to modelling the pressure-dependent electrical properties of porous rocks based on an effective medium model. The so-named Textural model uses the aspect ratios and pressure-dependent volume fractions of the pores and the aspect ratio and electrical conductivity of the matrix grains. The pores were represented by randomly oriented stiff and compliant spheroidal shapes with constant aspect ratios, and their pressure-dependent volume fractions were inverted from the measured variation of total porosity with differential pressure using a dual porosity model. The unknown constant stiff and compliant pore aspect ratios and the aspect ratio and electrical conductivity of the matrix grains were inverted by best fitting the modelled electrical formation factor to the measured data. Application of the approach to three sandstone samples covering a broad porosity range showed that the pressure-dependent electrical properties can be satisfactorily modelled by the proposed approach. The results demonstrate that the dual porosity concept is sufficient to explain the electrical properties of porous rocks under pressure through the effective medium model scheme.

Timing of metamorphism and exhumation in the Nordøyane ultra-high-pressure domain, Western Gneiss Region, Norway: New constraints from complementary CA-ID-TIMS and LA-MC-ICP-MS geochronology

NASA Astrophysics Data System (ADS)

Butler, J. P.; Jamieson, R. A.; Dunning, G. R.; Pecha, M. E.; Robinson, P.; Steenkamp, H. M.

2018-06-01

We present the results of a combined CA-ID-TIMS and LA-MC-ICP-MS U-Pb geochronology study of zircon and associated rutile and titanite from the Nordøyane ultra-high-pressure (UHP) domain in the Western Gneiss Region (WGR) of Norway. The dated samples include 4 eclogite bodies, 2 host-rock migmatites, and 2 cross-cutting pegmatites and leucosomes, all from the island of Harøya. Zircon from a coesite eclogite yielded an age of ca. 413 Ma, interpreted as the time of UHP metamorphism in this sample. Zircon data from the other eclogite bodies yielded metamorphic ages of ca. 413 Ma, 407 Ma, and 406 Ma; zircon trace-element data associated with 413 Ma and 407 Ma ages are consistent with eclogite-facies crystallization. In all of the eclogites, U-Pb dates from zircon cores, interpreted as the times of protolith crystallization, range from ca. 1680-1586 Ma, consistent with Gothian ages from orthogneisses in Nordøyane and elsewhere in the WGR. A zircon core age of ca. 943 Ma from one sample agrees with Sveconorwegian ages of felsic gneisses and pegmatites in the western part of the area. Migmatites hosting the eclogite bodies yielded zircon core ages of ca. 1657-1591 Ma and rim ages of ca. 395-392 Ma, interpreted as the times of Gothian protolith formation and Scandian partial melt crystallization, respectively. Pegmatite in an eclogite boudin neck yielded a crystallization age of ca. 388 Ma, interpreted as the time of melt crystallization. Rutile and titanite from 3 samples (an eclogite and two migmatites) yielded concordant ID-TIMS ages of 378-376 Ma. The results are similar to existing U-Pb data from other Nordøyane eclogites (415-405 Ma). In combination with previous pressure-temperature data from the coesite eclogite, these ages indicate that peak metamorphic conditions of 3 GPa/760 °C were reached ca. 413 Ma, followed by decompression to 1 GPa/810 °C by ca. 397 Ma and cooling below ca. 600 °C by ca. 375 Ma. The results are compatible with protracted UHP

Remanent magnetization and coercivity of rocks under hydrostatic pressure up to 1.4 GPa

NASA Astrophysics Data System (ADS)

Demory, F.; Rochette, P.; Gattacceca, J.; Gabriel, T.; Bezaeva, N. S.

2013-08-01

We designed an Isothermal Remanent Magnetization (IRM) acquisition system based on permanent magnets and sized to accommodate an amagnetic hydrostatic pressure cell. This pressure cell fits in a superconducting rock magnetometer, allowing for the measurement of remanent magnetization of pressurized samples. With this system, we determined the coercivity of remanence (Bcr) at different hydrostatic pressures up to 1.4 GPa for rock and dispersed mineral samples with various magnetic mineralogy and domain state. IRM and Bcr are nearly identical before compression and after decompression, indicating no permanent changes in the magnetic properties during pressure cycling. Hydrostatic pressure up to 1.4 GPa does not significantly increases IRM under pressure except for multidomain pyrrhotite and magnetite which show an increase of about 40%. Relative increase of Bcr under pressure is mild, except for a near single domain titanomagnetite where Bcr doubles.

Ultrahigh pressure extraction of lignan compounds from Dysosma versipellis and purification by high-speed counter-current chromatography.

PubMed

Zhu, Qing; Liu, Feng; Xu, Meixia; Lin, Xiaojing; Wang, Xiao

2012-09-15

Ultrahigh pressure extraction (UPE) was employed to extract podophyllotoxin and 4'-demethylpodophyllotoxin from Dysosma versipellis. The effects of extraction parameters including extraction solvents, pressure, time and solid/liquid ratio were investigated using a High Hydrostatic Pressure Processor. The optimal condition for UPE of the target compounds was 80% methanol, 200 MPa of pressure, 1 min of extraction time and 1:12 (g/mL) of solid/liquid ratio. Podophyllotoxin and 4'-demethylpodophyllotoxin in the crude extract were purified by high-speed counter-current chromatography (HSCCC) with a two-phase solvent system composed of petroleum ether-ethyl acetate-methanol-water (10:10:8:12, v/v), and the fractions were analyzed by HPLC, ESI-MS and (1)H NMR. As a result, 73.7 mg podophyllotoxin and 16.5mg 4'-demethylpodophyllotoxin with purities over 96% were obtained from 260 mg crude sample in one-step separation. Copyright © 2012 Elsevier B.V. All rights reserved.

Internal friction quality-factor Q under confining pressure. [of lunar rocks

NASA Technical Reports Server (NTRS)

Tittmann, B. R.; Ahlberg, L.; Nadler, H.; Curnow, J.; Smith, T.; Cohen, E. R.

1977-01-01

It has been found in previous studies that small amounts of adsorbed volatiles can have a profound effect on the internal friction quality-factor Q of rocks and other porous media. Pandit and Tozer (1970) have suggested that the laboratory-measured Q of volatile-free rocks should be similar to the in situ seismic Q values of near-surface lunar rocks which according to Latham et al. (1970) are in the range of 3000-5000. Observations of dramatic increases in Q with outgassing up to values approaching 2000 in the seismic frequency range confirm this supposition. Measurements under confining pressures with the sample encapsulated under hard vacuum are reported to aid in the interpretation of seismic data obtained below the lunar surface. It has been possible to achieve in the experiments Q values just under 2000 at about 1 kbar for a terrestrial analog of lunar basalt. It was found that a well-outgassed sample maintains a high Q whereas one exposed to moisture maintains a low Q as the confining pressure is raised to 2.5 kbar. This result suggests that volatiles can indeed affect Q when cracks are partially closed and the high lunar seismic Q values reported are concomitant with very dry rock down to depths of at least 50 km.

Image analysis method to quantify the effect of different treatments on the visual meat/shell ratio of half-shelled green lipped mussels (Perna canaliculus).

PubMed

Kim, Min Geun; Alçiçek, Zayde; Balaban, Murat O; Atar, Hasan Huseyin

2014-04-01

Aquacultured green lipped mussel (Perna canaliculus) is the New Zealand export leader of seafood in terms of weight. Different treatments shrink mussel meat differently and affect the consumer perception of half-shelled mussels. In order to quantify this, digital images of half-shelled green lipped mussels subjected to two postharvest treatments (ultrahigh pressure (UHP) and heat treatment (HT)) and raw controls were taken. The ratio of the view area of the meat to that of the shell (labelled as 'visual condition index' (VCI)) was measured using image analysis. A polygonal region of interest was defined on the image to depict the boundary of the meat and to calculate the view area. Raw mussels had a VCI of 85%. HT mussels had a much reduced VCI of 41%, indicating shrinkage of the meat due to heat. UHP treatment used as a shucking method resulted in a VCI of 83%. Since VCI is one measure of quality for the consumer, this quantitative method can be used in the optimization of shucking treatment (HT or UHP). VCI can be used to optimize postharvest treatments to minimize meat shrinkage. This method can also be applied to other shellfish such as oysters and clams. © 2013 Society of Chemical Industry.

Geochronologic Constraints on the Location of the Sino-Korean/Yangtze Suture and Evolution of the Northern Dabie Shan

NASA Astrophysics Data System (ADS)

Bryant, D. L.; Ayers, J. C.; Gao, S.; Miller, C. F.; Zhang, H.

2002-05-01

The Northern Dabie Complex (NDC) has been proposed to be either a Paleozoic magmatic arc, an exhumed piece of subducted continental crust, or young crust produced almost entirely by Cretaceous extensional magmatism. Ion microprobe zircon 238U-206Pb ages of separates from NDC gneisses center around 689Ma (+/- 31(95%CL)), consistent with the characteristic zircon dates of the Yangtze Craton [1]. Field observations also show that these gneisses, ranging from granitic to dioritic composition, make up a sizeable area ( ~30%) of the NDC. Zircon separates from the Baimajian granitoid, the largest of the widespread Cretaceous intrusions in the NDC, have yielded ages clustered around 677Ma (+/- 79), and 120Ma (+/- 3.4), the latter of which agrees with ion probe Th-Pb monazite ages. The ~700Ma age indicates that this intrusion may be linked with partial melting of underlying Yangtze crust, while the 120Ma age is the age of its crystallization. Granitic intrusions from Sanzushi and Yerenshai in the Dabie ultrahigh-pressure (UHP) region also show clusters of ages at 714Ma (+/- 55) from zircon cores, as well as rims around 250Ma (+/- 38), which is interpreted as the time of collision of the two continental blocks. These age data support the hypothesis set forth by Zhang et al. [2] using Sm-Nd and Pb isotopic data, that the Yangtze block lies beneath the exhumed UHP belt and outcrops as the NDC, which lies between the UHP belt and the Sino-Korean/Yangtze suture. The Baimajian granitoid, however, also shows a range of older zircon core ages from 1.4-2.0Ga, which may represent the early stages of formation of the Yangtze craton. Zhang et al. [2] suggested craton formation at 1.6-2.4Ga but few such ages have been reported for rocks of the Yangtze or Sino-Korean cratons. 1. Hacker, et al. (2000) Journal of Geophysical Research. Vol. 105. p. 13,339. 2. Zhang, et al. (In press) Chemical Geology.

Hydromechanical Rock Mass Fatigue in Deep-Seated Landslides Accompanying Seasonal Variations in Pore Pressures

NASA Astrophysics Data System (ADS)

Preisig, Giona; Eberhardt, Erik; Smithyman, Megan; Preh, Alexander; Bonzanigo, Luca

2016-06-01

The episodic movement of deep-seated landslides is often governed by the presence of high pore pressures and reduced effective stresses along active shear surfaces. Pore pressures are subject to cyclic fluctuation under seasonal variations of groundwater recharge, resulting in an intermittent movement characterized by acceleration-deceleration phases. However, it is not always clear why certain acceleration phases reach alarming levels without a clear trigger (i.e., in the absence of an exceptional pore pressure event). This paper presents a conceptual framework linking hydromechanical cycling, progressive failure and fatigue to investigate and explain the episodic behavior of deep-seated landslides using the Campo Vallemaggia landslide in Switzerland as a case study. A combination of monitoring data and advanced numerical modeling is used. The principal processes forcing the slope into a critical disequilibrium state are analyzed as a function of rock mass damage and fatigue. Modeling results suggest that during periods of slope acceleration, the rock slope experiences localized fatigue and gradual weakening through slip along pre-existing natural fractures and yield of critically stressed intact rock bridges. At certain intervals, pockets of critically weakened rock may produce a period of enhanced slope movement in response to a small pore pressure increase similar to those routinely experienced each year. Accordingly, the distribution and connectivity of pre-existing permeable planes of weakness play a central role. These structures are often related to the rock mass's tectonic history or initiate (and dilate) in response to stress changes that disturb the entire slope, such as glacial unloading or seismic loading via large earthquakes. The latter is discussed in detail in a companion paper to this (Gischig et al., Rock Mech Rock Eng, 2015). The results and framework presented further demonstrate that episodic movement and progressive failure of deep

Fractured Rock Permeability as a Function of Temperature and Confining Pressure

NASA Astrophysics Data System (ADS)

Alam, A. K. M. Badrul; Fujii, Yoshiaki; Fukuda, Daisuke; Kodama, Jun-ichi; Kaneko, Katsuhiko

2015-10-01

Triaxial compression tests were carried out on Shikotsu welded tuff, Kimachi sandstone, and Inada granite under confining pressures of 1-15 MPa at 295 and 353 K. The permeability of the tuff declined monotonically with axial compression. The post-compression permeability became smaller than that before axial compression. The permeability of Kimachi sandstone and Inada granite declined at first, then began to increase before the peak load, and showed values that were almost constant in the residual strength state. The post-compression permeability of Kimachi sandstone was higher than that before axial compression under low confining pressures, but lower under higher confining pressures. On the other hand, the permeability of Inada granite was higher than that before axial compression regardless of the confining pressure values. For the all rock types, the post-compression permeability at 353 K was lower than at 295 K and the influence of the confining pressure was less at 353 K than at 295 K. The above temperature effects were observed apparently for Inada granite, only the latter effect was apparent for Shikotsu welded tuff, and they were not so obvious for Kimachi sandstone. The mechanisms causing the variation in rock permeability and sealability of underground openings were discussed.

Thermo-mechanical pressurization of experimental faults in cohesive rocks during seismic slip

NASA Astrophysics Data System (ADS)

Violay, M.; Di Toro, G.; Nielsen, S.; Spagnuolo, E.; Burg, J. P.

2015-11-01

Earthquakes occur because fault friction weakens with increasing slip and slip rates. Since the slipping zones of faults are often fluid-saturated, thermo-mechanical pressurization of pore fluids has been invoked as a mechanism responsible for frictional dynamic weakening, but experimental evidence is lacking. We performed friction experiments (normal stress 25 MPa, maximal slip-rate ∼3 ms-1) on cohesive basalt and marble under (1) room-humidity and (2) immersed in liquid water (drained and undrained) conditions. In both rock types and independently of the presence of fluids, up to 80% of frictional weakening was measured in the first 5 cm of slip. Modest pressurization-related weakening appears only at later stages of slip. Thermo-mechanical pressurization weakening of cohesive rocks can be negligible during earthquakes due to the triggering of more efficient fault lubrication mechanisms (flash heating, frictional melting, etc.).

Thermal contraints on high-pressure granulite metamorphism of supracrustal rocks

NASA Technical Reports Server (NTRS)

Ashwal, L. D.; Morgan, P.; Leslie, W. W.

1983-01-01

The circumstances leading to the formation and exposure at the Earth's surface of supracrustal granulites are examined. These are defined as sediments, volcanics, and other rock units which originally formed at the surface of the Earth, were metamorphosed to high-pressure granulite facies (T = 700-900 C, P = 5-10 kbar), and reexposed at the Earth's surface, in many cases underlain by normal thicknesses of continental crust (30-40 km). Five possible heating mechanisms to account for granulite metamorphism of supracrustal rocks are discussed: magnetic heating, thermal relaxation of perturbed temperature profiles following underthrusting of the continental crust, thermal relaxation after underthrusting of thin slivers of supracrustal rocks below continental crust of normal thickness, major preheating of the upper plate, and shear heating caused by frictional stress along the thrust plane.

Ultrahigh vacuum gauge having two collector electrodes

NASA Technical Reports Server (NTRS)

Torney, F. L., Jr. (Inventor)

1967-01-01

A gauge for measuring ultrahigh vacuums with great accuracy is described. It provides a means for ionizing the gas whose pressure is being measured, and consists of a collector electrode, a suppressor, radiation shielding, and a second collector.

Acoustic and mechanical response of reservoir rocks under variable saturation and effective pressure.

PubMed

Ravazzoli, C L; Santos, J E; Carcione, J M

2003-04-01

We investigate the acoustic and mechanical properties of a reservoir sandstone saturated by two immiscible hydrocarbon fluids, under different saturations and pressure conditions. The modeling of static and dynamic deformation processes in porous rocks saturated by immiscible fluids depends on many parameters such as, for instance, porosity, permeability, pore fluid, fluid saturation, fluid pressures, capillary pressure, and effective stress. We use a formulation based on an extension of Biot's theory, which allows us to compute the coefficients of the stress-strain relations and the equations of motion in terms of the properties of the single phases at the in situ conditions. The dry-rock moduli are obtained from laboratory measurements for variable confining pressures. We obtain the bulk compressibilities, the effective pressure, and the ultrasonic phase velocities and quality factors for different saturations and pore-fluid pressures ranging from normal to abnormally high values. The objective is to relate the seismic and ultrasonic velocity and attenuation to the microstructural properties and pressure conditions of the reservoir. The problem has an application in the field of seismic exploration for predicting pore-fluid pressures and saturation regimes.

The impact law of confining pressure and plastic parameter on Dilatancy of rock

NASA Astrophysics Data System (ADS)

Wang, Bin; Zhang, Zhenjie; Zhu, Jiebing

2017-08-01

Based on cyclic loading-unloading triaxle test of marble, the double parameter dilation angle model is established considering confining pressure effect and plastic parameter. Research shows that not only the strength but also the militancy behavior is highly depended on its confining pressure and plastic parameter during process of failure. Dilation angle evolution law shows obvious nonlinear characteristic almost with a rapid increase to the peak and then decrease gradually with plastic increasing, and the peak dilation angle value is inversely proportional with confining pressure. The proposed double parameter nonlinear dilation angle model can be used to well describe the Dilatancy of rock, which helps to understand the failure mechanism of surrounding rock mass and predict the range of plastic zone.

Grain-scale Sr isotope heterogeneity in amphibolite (retrograded UHP eclogite, Dabie terrane): Implications for the origin and flow behavior of retrograde fluids during slab exhumation

NASA Astrophysics Data System (ADS)

Guo, Shun; Yang, Yueheng; Chen, Yi; Su, Bin; Gao, Yijie; Zhang, Lingmin; Liu, Jingbo; Mao, Qian

2016-12-01

To constrain the origin and flow behavior of amphibolite-facies retrograde fluids during slab exhumation, we investigate the textures, trace element contents, and in situ strontium (Sr) isotopic compositions (using LA-MC-ICP-MS) of multiple types of epidote and apatite in the UHP eclogite and amphibolites from the Hualiangting area (Dabie terrane, China). The UHP epidote porphyroblasts in the eclogite (Ep-E), which formed at 28-30 kbar and 660-720 °C, contain high amounts of Sr, Pb, Th, Ba, and light rare earth elements (LREEs) and have a narrow range of initial 87Sr/86Sr ratios (0.70431 ± 0.00012 to 0.70454 ± 0.00010). Two types of amphibolite-facies epidote were recognized in the amphibolites. The first type of epidote (Ep-AI) developed in all the amphibolites and has slightly lower trace element contents than Ep-E. The Ep-AI has a same initial 87Sr/86Sr ratio range as the Ep-E and represents the primary amphibolite-facies retrograde product that is associated with an internally buffered fluid at 8.0-10.3 kbar and 646-674 °C. The other type of epidote (Ep-AII) occurs as irregular fragments, veins/veinlets, or reaction rims on the Ep-AI in certain amphibolites. Elemental X-ray maps reveal the presence of Ep-AI relics in the Ep-AII domains (appearing as a patchy texture), which indicates that Ep-AII most likely formed by the partial replacement of the Ep-AI in the presence of an infiltrating fluid. The distinctly lower trace element contents of Ep-AII are ascribed to element scavenging by a mechanism of dissolution-transport-precipitation during replacement. The Ep-AII in an individual amphibolite exhibits large intra- and inter-grain variations in the initial 87Sr/86Sr ratios (0.70493 ± 0.00030 to 0.70907 ± 0.00022), which are between those of the Ep-AI and granitic gneisses (wall rock of the amphibolites, 0.7097-0.7108). These results verify that the infiltrating fluid was externally derived from granitic gneisses. The matrix apatite in the amphibolites has

Shock pressure estimation in basement rocks of the Chicxulub impact crater using cathodoluminescence spectroscopy of quartz

NASA Astrophysics Data System (ADS)

Tomioka, N.; Tani, R.; Kayama, M.; Chang, Y.; Nishido, H.; Kaushik, D.; Rae, A.; Ferrière, L.; Gulick, S. P. S.; Morgan, J. V.

2017-12-01

The Chicxulub impact structure, located in the northern Yucatan Peninsula, Mexico, was drilled by the joint IODP-ICDP Expedition 364 in April-May 2016. This expedition is the first attempt to obtain materials from the topographic peak ring within the crater previously identified by seismic imaging. A continuous core was successfully recovered from the peak ring at depths between 505.7 and 1334.7 mbsf. Uplifted, fractured, and shocked granitic basement rocks forming the peak ring were found below, in the impact breccia and impact melt rock unit (747.0-1334.7 mbsf; Morgan et al. 2016). In order to constrain impact crater formation, we investigated shock pressure distribution in the peak-ring basement rocks. Thin sections of the granitic rocks were prepared at intervals of 60 m. All the samples contains shocked minerals, with quartz grains frequently showing planar deformation features (PDFs). We determined shock pressures based on the cathodoluminescence (CL) spectroscopy of quartz. The strong advantage of the CL method is its applicability to shock pressure estimation for individual grains for both quartz and diaplectic SiO2 glass with high-spatial resolution ( 1 μm) (Chang et al. 2016). CL spectra of quartz shows a blue emission band caused by shock-induced defect centers, where its intensity increases with shock pressure. A total of 108 quartz grains in ten thin sections were analyzed using a scanning electron microscope with a CL spectrometer attached (an acceleration voltage of 15 kV and a beam current of 2 nA were used). Natural quartz single crystals, which were experimentally shocked at 0-30 GPa, were used for pressure calibration. CL spectra of all the quartz grains in the basement rocks showed broad blue emission band at the wavelength range of 300-500 nm and estimated shock pressures were in the range of 15-20 GPa. The result is consistent with values obtained from PDFs analysis in quartz using the universal stage (Ferrière et al. 2017; Rae et al. 2017

Structures of dolomite at ultrahigh pressure and their influence on the deep carbon cycle

PubMed Central

Merlini, Marco; Crichton, Wilson A.; Hanfland, Michael; Gemmi, Mauro; Müller, Harald; Kupenko, Ilya; Dubrovinsky, Leonid

2012-01-01

Carbon-bearing solids, fluids, and melts in the Earth's deep interior may play an important role in the long-term carbon cycle. Here we apply synchrotron X-ray single crystal micro-diffraction techniques to identify and characterize the high-pressure polymorphs of dolomite. Dolomite-II, observed above 17 GPa, is triclinic, and its structure is topologically related to CaCO3-II. It transforms above 35 GPa to dolomite-III, also triclinic, which features carbon in [3 + 1] coordination at the highest pressures investigated (60 GPa). The structure is therefore representative of an intermediate between the low-pressure carbonates and the predicted ultra-high pressure carbonates, with carbon in tetrahedral coordination. Dolomite-III does not decompose up to the melting point (2,600 K at 43 GPa) and its thermodynamic stability demonstrates that this complex phase can transport carbon to depths of at least up to 1,700 km. Dolomite-III, therefore, is a likely occurring phase in areas containing recycled crustal slabs, which are more oxidized and Ca-enriched than the primitive lower mantle. Indeed, these phases may play an important role as carbon carriers in the whole mantle carbon cycling. As such, they are expected to participate in the fundamental petrological processes which, through carbon-bearing fluids and carbonate melts, will return carbon back to the Earth’s surface. PMID:22869705

An Ultrahigh CO2-Loaded Silicalite-1 Zeolite: Structural Stability and Physical Properties at High Pressures and Temperatures.

PubMed

Marqueño, Tomas; Santamaria-Perez, David; Ruiz-Fuertes, Javier; Chuliá-Jordán, Raquel; Jordá, Jose L; Rey, Fernando; McGuire, Chris; Kavner, Abby; MacLeod, Simon; Daisenberger, Dominik; Popescu, Catalin; Rodriguez-Hernandez, Placida; Muñoz, Alfonso

2018-06-04

We report the formation of an ultrahigh CO 2 -loaded pure-SiO 2 silicalite-1 structure at high pressure (0.7 GPa) from the interaction of empty zeolite and fluid CO 2 medium. The CO 2 -filled structure was characterized in situ by means of synchrotron powder X-ray diffraction. Rietveld refinements and Fourier recycling allowed the location of 16 guest carbon dioxide molecules per unit cell within the straight and sinusoidal channels of the porous framework to be analyzed. The complete filling of pores by CO 2 molecules favors structural stability under compression, avoiding pressure-induced amorphization below 20 GPa, and significantly reduces the compressibility of the system compared to that of the parental empty one. The structure of CO 2 -loaded silicalite-1 was also monitored at high pressures and temperatures, and its thermal expansivity was estimated.

Preservation of Partial Melt Textures in Inclusions in Garnet Megacrysts of Pelitic Paragneiss, UHP Terrane, North-East Greenland Eclogite Province

NASA Astrophysics Data System (ADS)

Lang, H. M.; Gilotti, J. A.

2005-12-01

Although paragneiss is not common in the North-East Greenland Eclogite Province (NEGEP), of the few paragneiss samples collected in the UHP zone, some contain inclusion-rich garnet megacrysts (to 2 cm) in an anatectic matrix. In the matrix, quartz ribbons are segregated from anatectic melt layers and lenses that contain plagioclase, antiperthitic alkali-feldspar, white mica, biotite, small garnets, rutile and minor kyanite. In addition to one-phase and two-phase inclusions of quartz, polycrystalline quartz (no definitive coesite-replacement textures), and phengitic white mica, the garnet megacrysts contain some relatively large polyphase inclusions with all or most of the following phases: kyanite, rutile, phengitic white mica, biotite, quartz, Na-rich plagioclase, K-feldspar and zircon. Textures in these complex, polyphase inclusions suggest that their constituent minerals crystallized from a melt. Crystals are randomly oriented with early crystallizing minerals (kyanite, rutile, micas) forming euhedral grains and later crystallizing minerals (quartz and feldspars) filling the interstitial spaces. The textures and mineral assemblages are consistent with dehydration melting of phengitic white mica + quartz (enclosed in garnet) during decompression of the rocks from UHP metamorphic conditions. Although anatectic minerals in the matrix may have experienced extensive retrograde re-equilibration subsequent to crystallizing from a melt, the minerals trapped in the crystallized melt inclusions in garnet are likely to preserve their original textures and compositions. Microtextures in the melt inclusions and surrounding garnet suggest that partial melting was accompanied by volume expansion and that some melt penetrated garnets. Some radial fractures extend from inclusion margins into surrounding garnet. Individual fractures may have formed by volume expansion on melting or expansion accompanying the coesite-quartz transformation. Small and large polycrystalline quartz

Concepts for diamond exploration in "on/off craton" areas—British Columbia, Canada

NASA Astrophysics Data System (ADS)

Simandl, George J.

2004-09-01

where geological evidences suggest an ultrahigh pressure (UHP) metamorphic event followed by rapid tectonic exhumation (which could have prevented complete resorption of diamonds on their journey to the surface) are worth investigating. If UHP rocks were intercepted at depth by syn- or post-subduction diamond elevators, such as kimberlites, lamproites, lamprophyres, nephelinites or other alkali volcanic rocks of deep-seated origin, the diamond potential of the area would be even higher.

Ginsenoside extraction from Panax quinquefolium L. (American ginseng) root by using ultrahigh pressure.

PubMed

Zhang, Shouqin; Chen, Ruizhan; Wu, Hua; Wang, Changzheng

2006-04-11

A new method of ultrahigh pressure extraction (UPE) was used to extract the ginsenosides from Panax quinquefolium L. (American ginseng) root at room temperature. Several solvents, including water, ethanol, methanol, and n-butanol were used in the UPE. The ginsenosides were quantified by a HPLC equipped with UV-vis detector. The results showed that ethanol is the most efficient solvent among the used ones. Compared with other methods, i.e., Soxhlet extraction, heat reflux extraction, ultrasound-assisted extraction, microwave-assisted extraction, and supercritical CO2 extraction, the UPE has the highest extraction yield in the shortest time. The extraction yield of 0.861% ginsenoside-Rc in 2 min was achieved by the UPE, while the yields of 0.284% and 0.661% were obtained in several hours by supercritical CO2 extraction and the heat reflux extraction, respectively.

Acoustic emission from a solidifying aluminum-lithium alloy

NASA Technical Reports Server (NTRS)

Henkel, D. P.; Wood, J. D.

1992-01-01

Physical phenomena associated with the solidification of an AA2090 Al-Li alloy have been characterized by AE methods. Repeatable patterns of AE activity as a function of solidification time are recorded and explained for ultrahigh-purity (UHP) aluminum and an Al-4.7 wt pct Cu binary alloy, in addition to the AA2090 Al-Li alloy, by the complementary utilization of thermal, AE, and metallographic methods. One result shows that the solidification of UHP aluminum produces one discrete period of high AE activity as the last 10 percent of solid forms.

An ultrahigh pressure homogenization technique for easily exfoliating few-layer phosphorene from bulk black phosphorus

NASA Astrophysics Data System (ADS)

Guan, Qing-Qing; Zhou, Hua-Jing; Ning, Ping; Lian, Pei-Chao; Wang, Bo; He, Liang; Chai, Xin-Sheng

2018-05-01

We have developed an easy and efficient method for exfoliating few-layer sheets of black phosphorus (BP) in N-methyl-2-pyrrolidone, using ultra-high pressure homogenization (UPH). The BP was first exfoliated into sheets that were a few atomic layers thick, using a homogenizer for only 30 min. Next, a double centrifugation procedure was used to separate the material into few-layer nanosheets that were examined by X-ray diffraction, atomic force microscopy (AFM), transmission electron microscopy (TEM), high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM), and energy-dispersive X-ray (EDX) spectroscopy. The results show that the products are specimens of phosphorene that are only a few-layer thick.

Ultra-High Pressure Driver and Nozzle Survivability in the RDHWT/MARIAH II Hypersonic Wind Tunnel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Costantino, M.; Brown, G.; Raman, K.

2000-06-02

An ultra-high pressure device provides a high enthalpy (> 2500 kJ/kg), low entropy (< 5 kJ/kg-K) air source for the RDHWT/MARIAH II Program Medium Scale Hypersonic Wind Tunnel. The design uses stagnation conditions of 2300 MPa (330,000 Psi) and 750 K (900 F) in a radial configuration of intensifiers around an axial manifold to deliver pure air at 100 kg/s mass flow rates for run times suitable for aerodynamic, combustion, and test and evaluation applications. Helium injection upstream of the nozzle throat reduces the throat wall recovery temperature to about 1200 K and reduces the oxygen concentration at the nozzlemore » wall.« less

The use of ultra-high pressure liquid chromatography with tandem mass spectrometric detection of analysis of agrochemical residues and mycotoxines in food - challenges and applications

USDA-ARS?s Scientific Manuscript database

In the field of food contaminant analysis, the most significant development of recent years has been the integration of ultra-high pressure liquid chromatography (UHPLC), coupled to tandem quadrupole mass spectrometry (MS/MS), into analytical applications. In this review, we describe the emergence o...

Alpine Serpentinite Geochemistry As Key To Define Timing Of Oceanic Lithosphere Accretion To The Subduction Plate Interface

NASA Astrophysics Data System (ADS)

Gilio, M.; Scambelluri, M.; Agostini, S.; Godard, M.; Pettke, D. T.; Angiboust, S.

2016-12-01

Isotopic (Pb, Sr and B) and trace element (B, Be, As, Sb, U, Th) signatures of serpentinites are useful geochemical tools to assess element exchange and fluid-rock interactions in subduction zone settings. They help to unravel geological history and tectonic evolution of subduction serpentinites and associated meta-oceanic crust. Sedimentary-derived fluid influx within HP plate interface environments strongly enriches serpentinites in As, Sb, B, U and Th and resets their B, Sr and Pb isotopic compositions. This HP metasomatic signature is preserved during exhumation and/or released at higher PT through de-serpentinization, fueling partial melting in the sub-arc mantle and recycling such fingerprint into arc magmas. This study focuses on the subduction recrystallization, geochemical diversity and fluid-rock interaction recorded by high- to ultra-high pressure (HP, UHP) Alpine serpentinites from the subducted oceanic plate (Cignana Unit, Zermatt-Saas Complex, Monviso and Lanzo Ultramafic Massifs). The As and Sb compositions of the HP-UHP Alpine ophiolitic rocks reveal the interaction between serpentinite and crust-derived fluids during their emplacement along the plate interface. This enables to define a hypothetical architecture of the Alpine subduction interface, considering large ultramafic slices. In this scenario, the Lanzo peridotite and serpentinite retain an As-Sb composition comparable to DM and PM: i.e. they experienced little exchange with sediment-derived fluids. Lanzo thus belonged to sections of the subducting plate, afar from the plate interface. Serpentinites from the Lago di Cignana Unit and Monviso and Voltri are richer in As and Sb, showing moderate to strong interaction with sediment- and crust-derived fluids during subduction (i.e. they behaved as open systems). These serpentinite slices accreted at the plate interface and exchanged with slab-derived fluids at different depths during Alpine subduction: Voltri accreted at shallower conditions (50

Geochemical and geochronological constraints on the origin and evolution of rocks in the active Woodlark Rift of Papua New Guinea

NASA Astrophysics Data System (ADS)

Zirakparvar, Nasser Alexander

Tectonically active regions provide important natural laboratories to glean information that is applicable to developing a better understanding of the geologic record. One such area of the World is Papua New Guinea, much of which is situated in an active and transient plate boundary zone. The focus of this PhD research is to develop a better understanding of rocks in the active Woodlark Rift, situated in Papua New Guinea's southernmost reaches. In this region, rifting and lithospheric rupture is occurring within a former subduction complex where there is a history of continental subduction and (U)HP metamorphism. The lithostratigraphic units exposed in the Woodlark Rift provide an opportunity to better understand the records of plate boundary processes at many scales from micron-sized domains within individual minerals to regional geological relationships. This thesis is composed of three chapters that are independent of one another but are all related to the overall goal of developing a better understanding of the record of plate boundary processes in the rocks currently exposed in the Woodlark Rift. The first chapter, published in its entirety in Earth and Planetary Science Letters (2011 v. 309, p. 56 - 66), is entitled 'Lu-Hf garnet geochronology applied to plate boundary zones: Insights from the (U)HP terrane exhumed within the Woodlark Rift'. This chapter focuses on the use of the Lu-Hf isotopic system to date garnets in the Woodlark Rift. Major findings of this study are that some of the rocks in the Woodlark Rift preserve a Lu-Hf garnet isotopic record of initial metamorphism and continental subduction occurring in the Late Mesozoic, whereas others only preserve a record of tectonic processes related to lithospheric rupture during the initiation of rifting in the Late Cenozoic. The second chapter is entitled 'Geochemical and geochronological constraints on the origin of rocks in the active Woodlark Rift of Papua New Guinea: Recognizing the dispersed

Role of the Prospect Rock Fault in the Exhumation of High Pressure Rocks in North-Central Vermont

NASA Astrophysics Data System (ADS)

Tam, E.; Webb, L. E.; Aiken, C. L.

2017-12-01

The Prospect Rock Fault (PRF) is key to our interpretation of regional deformation and exhumation of blueschist and eclogite-facies rocks in the Tillotson Peak Complex (TPC) during the Taconic Orogeny. The TPC is in the footwall of the PRF in the eastern limb of the Green Mountain Anticlinorium. In the TPC, the dominant foliation is S2 and E-W trending F2 folds parallel L2 lineations, which run orthogonal to regional N-S trending folds associated with the Taconic Orogeny. This structural trend has possible analogies with HP-UHP terranes in Papua New Guinea and China. The PRF itself is folded by F2 folds. Presently, there is a lack of consensus about the structural evolution of the PRF and its role in the exhumation of the TPC, and studies have not reconciled the formation of the E-W folds and lineations to a regional model. Oriented samples and structural data were collected from the footwall of the PRF over several transects. Samples were processed into orthogonal thin sections for microstructural analyses and for 40Ar/39Ar step-heating of white mica. Preliminary results show a range of ages from 458.6 ± 2.0 Ma to 420.0 ± 2.7 Ma. The oldest ages are just slightly younger, yet concordant, with published and new 40Ar/39Ar ages from the TPC. The dominant foliation in the PRF samples, S2, is defined in thin section by mica and quartz microlithons, and oriented mica grains. S1 is only locally preserved in some mica domains and albite/garnet inclusion trails. S3 appears as crenulations of S2, with no significant new mineral crystallization. In the field, L2 lineations are defined by mineral and quartz rods, and L3 lineations are defined as intersection lineations on S2 surfaces. The relationships between ages and microstructures are consistent younger ages being associated with increased presence of S3 crenulation foliations, which appeared in structurally lower areas. Samples with older ages display dominant S2 foliations and lack S3 crenulations, and were sourced

Dynamic Stability of the Rate, State, Temperature, and Pore Pressure Friction Model at a Rock Interface

NASA Astrophysics Data System (ADS)

Sinha, Nitish; Singh, Arun K.; Singh, Trilok N.

2018-05-01

In this article, we study numerically the dynamic stability of the rate, state, temperature, and pore pressure friction (RSTPF) model at a rock interface using standard spring-mass sliding system. This particular friction model is a basically modified form of the previously studied friction model namely the rate, state, and temperature friction (RSTF). The RSTPF takes into account the role of thermal pressurization including dilatancy and permeability of the pore fluid due to shear heating at the slip interface. The linear stability analysis shows that the critical stiffness, at which the sliding becomes stable to unstable or vice versa, increases with the coefficient of thermal pressurization. Critical stiffness, on the other hand, remains constant for small values of either dilatancy factor or hydraulic diffusivity, but the same decreases as their values are increased further from dilatancy factor (˜ 10^{ - 4} ) and hydraulic diffusivity (˜ 10^{ - 9} {m}2 {s}^{ - 1} ) . Moreover, steady-state friction is independent of the coefficient of thermal pressurization, hydraulic diffusivity, and dilatancy factor. The proposed model is also used for predicting time of failure of a creeping interface of a rock slope under the constant gravitational force. It is observed that time of failure decreases with increase in coefficient of thermal pressurization and hydraulic diffusivity, but the dilatancy factor delays the failure of the rock fault under the condition of heat accumulation at the creeping interface. Moreover, stiffness of the rock-mass also stabilizes the failure process of the interface as the strain energy due to the gravitational force accumulates in the rock-mass before it transfers to the sliding interface. Practical implications of the present study are also discussed.

Pressure Variations in Metamorphic Rocks: Implications for the Interpretation of Petrographic Observations

NASA Astrophysics Data System (ADS)

Tajčmanová, Lucie

2014-05-01

Metamorphic petrologists and structural geologists, using direct measurements, bring the only direct observational constrains for validating geodynamic models. Therefore, petrological and structural geological observations are essential for the quality and reproducibility of geodynamic reconstructions and models. One of the important assumptions for geodynamic reconstructions arises from the pressure and temperature estimates in the petrology analysis. Pressure is commonly converted to depth through the equation for lithostatic pressure and so the original position of the rock sample within the Earth's interior can be constrained. The current assumption that the studied sample corresponds to uniform pressure may not be correct, and if so, it has serious implications. Increasing evidence from analytical data shows that pressure is not constant even on a grain scale, posing new challenges because, if ignored, it leads to an incorrect use of petrology data in constraining geodynamic models. Well known examples of the preservation of coesite and diamond in a host mineral like garnet show that high pressure inclusions are preserved during decompression. Tajčmanová et al. (2014) has shown that grain-scale pressure variations can develop and that these pressure variations allow compositional zoning in minerals preserved over geological time scales. A new unconventional barometric method based on equilibrium under pressure variations has been developed . Such pressure variations are also connected with differences in fluid pressure in open systems and can be thus observed at all scales. Tajčmanová L., Podladchikov Y., Powell R., Moulas E., Vrijmoed J. and Connolly J. (2014). Grain scale pressure variations and chemical equilibrium in high-grade metamorphic rocks.Journal of Metamorphic Geology, doi:10.1111/jmg.12066 This work was supported by ERC starting grant 335577 to Lucie Tajcmanova

Fate of Subducting Organic Carbon: Evidence from HP/UHP Metasedimentary Suites

NASA Astrophysics Data System (ADS)

Kraft, K.; Bebout, G. E.

2017-12-01

Community interest in deep-Earth C cycling has focused attention on extents of C release from subducting oceanic lithosphere and sediment and the fate of this released C. Many have suggested that, based on isotopic and other arguments, 20% of the C subducted into the deeper mantle is in reduced form (organic); however, individual margins show large variation in carbonate to organic C ratios. Despite the size of the potentially deeply subducted organic C reservoir, its fate in subducting sections remains largely unexplored, with most attention paid to release of carbonate C. To characterize the forearc behavior of organic C, metamorphosed to P-T as high as that beneath volcanic fronts, we evaluated records of reduced C (RC) contents and isotope compositions in HP/UHP metasediments: 1) Schistes Lustres/Cignana (SLC) suite (Alps; Cook-Kollars et al., 2014, Chem Geol) with abundant carbonate and resembling sediment entering the East Sunda trench; and (2) Franciscan Complex (FC), W. Baja Terrain (WBT), Catalina Schist (CS) metasediments (Sadofsky and Bebout, 2003, G3), largely sandstone-shale sequences containing very little carbonate. In general, more Al-rich samples (shaley) in the terrigenous metasedimentary suites have higher concentrations of RC, which in low-grade units preserves δ13C of its organic protoliths. Carbonate-poor rocks in the SLC suite, and at ODP Site 765, show correlated major element (Al, Mg, Mn, Ti, P) and RC contents (up to 1.2 wt.%) reflecting sandstone-shale mixture. In the FC, WBT, and CS, the more Al-rich samples contain up to 2 wt. % RC. In high-grade Catalina Schist, RC has elevated δ13C due to C loss in CH4 and high-grade Alps rocks show reduced RC wt. % normalized to Al content. We consider processes that could alter contents and isotopic compositions of RC in sediment, e.g., devolatilization, closed-system exchange with carbonate, redox reactions, isotopic exchange with C in externally-derived fluids. It appears that, on modern Earth

Effect of extra-column volume on practical chromatographic parameters of sub-2-μm particle-packed columns in ultra-high pressure liquid chromatography.

PubMed

Wu, Naijun; Bradley, Ashley C; Welch, Christopher J; Zhang, Li

2012-08-01

Effects of extra-column volume on apparent separation parameters were studied in ultra-high pressure liquid chromatography with columns and inlet connection tubings of various internal diameters (id) using 50-mm long columns packed with 1.8-μm particles under isocratic conditions. The results showed that apparent retention factors were on average 5, 11, 18, and 41% lower than those corrected with extra-column volumes for 4.6-, 3.0-, 2.1-, and 1.0-mm id columns, respectively, when the extra-column volume (11.3 μL) was kept constant. Also, apparent pressures were 31, 16, 12, and 10% higher than those corrected with pressures from extra-column volumes for 4.6-, 3.0-, 2.1-, and 1.0-mm id columns at the respective optimum flow rate for a typical ultra-high pressure liquid chromatography system. The loss in apparent efficiency increased dramatically from 4.6- to 3.0- to 2.1- to 1.0-mm id columns, less significantly as retention factors increased. The column efficiency was significantly improved as the inlet tubing id was decreased for a given column. The results suggest that maximum ratio of extra-column volume to column void volume should be approximately 1:10 for column porosity more than 0.6 and a retention factor more than 5, where 80% or higher of theoretically predicted efficiency could be achieved. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Super earth interiors and validity of Birch's Law for ultra-high pressure metals and ionic solids

NASA Astrophysics Data System (ADS)

Ware, Lucas Andrew

2015-01-01

Super Earths, recently detected by the Kepler Mission, expand the ensemble of known terrestrial planets beyond our Solar System's limited group. Birch's Law and velocity-density systematics have been crucial in constraining our knowledge of the composition of Earth's mantle and core. Recently published static diamond anvil cell experimental measurements of sound velocities in iron, a key deep element in most super Earth models, are inconsistent with each other with regard to the validity of Birch's Law. We examine the range of validity of Birch's Law for several metallic elements, including iron, and ionic solids shocked with a two-stage light gas gun into the ultra-high pressure, temperature fluid state and make comparisons to the recent static data.

Effects of Ultra-High Pressure Homogenization and Hydrocolloids on Physicochemical and Storage Properties of Soymilk.

PubMed

Mukherjee, Dipaloke; Chang, Sam K C; Zhang, Yin; Mukherjee, Soma

2017-10-01

This study investigated the efficacy of ultra-high pressure homogenization (UHPH) in the presence or absence of added hydrocolloids for enhancing a range of physic-chemical properties of soymilk-which are important for extending shelf-life. Soymilk preparations containing different concentrations (0.01%, 0.02%, and 0.05%, w/v) of 2 different hydrocolloids (κ-carrageenan, κ-C, and gum Arabic, GA) were subjected to 3 different levels of UHPH (70, 140, and 210 MPa) and stored in sterilized containers at 4 °C. Emulsion properties of the soymilk preparations were analyzed over a period of 5 weeks. The results showed that soymilk with 0.05% κ-C had markedly improved storage properties, evident by significantly (P < 0.05) enhanced surface energy and absolute ζ potential values compared to the unhomogenized soymilk with no hydrocolloid (16% and 39% augmentations, respectively) at the 1st week of storage. This trend continued throughout the entire period of study. The soymilk containing 0.05% κ-C also exhibited significantly (P < 0.05) lower (60%) mean globular particle size at the initial week compared to the latter ones and maintained the trend throughout the 3rd week of storage. The study can potentially lead to a considerable economic benefit to the soymilk industry by providing valuable information to extend shelf-life of soymilk. Soymilk is one of the most important soy products, and as a beverage, it is rapidly gaining popularity in the Western markets. However, it tends to form precipitates during storage to affect quality of the product. This study used a 2-prong approach of ultra-high pressure homogenization and addition of hydrocolloids to prevent aggregation of soymilk particles and the retention of antioxidant capacity. The results showed enhancement of the quality of soymilk during storage. The techniques developed can be adopted by the food industry. © 2017 Institute of Food Technologists®.

High Strain Rate Testing of Rocks using a Split-Hopkinson-Pressure Bar

NASA Astrophysics Data System (ADS)

Zwiessler, Ruprecht; Kenkmann, Thomas; Poelchau, Michael; Nau, Siegfried; Hess, Sebastian

2016-04-01

Dynamic mechanical testing of rocks is important to define the onset of rate dependency of brittle failure. The strain rate dependency occurs through the propagation velocity limit (Rayleigh wave speed) of cracks and their reduced ability to coalesce, which, in turn, significantly increases the strength of the rock. We use a newly developed pressurized air driven Split-Hopkinson-Pressure Bar (SHPB), that is specifically designed for the investigation of high strain rate testing of rocks, consisting of several 10 to 50 cm long strikers and bar components of 50 mm in diameter and 2.5 meters in length each. The whole set up, composed of striker, incident- and transmission bar is available in aluminum, titanium and maraging steel to minimize the acoustic impedance contrast, determined by the change of density and speed of sound, to the specific rock of investigation. Dynamic mechanical parameters are obtained in compression as well as in spallation configuration, covering a wide spectrum from intermediate to high strain rates (100-103 s-1). In SHPB experiments [1] one-dimensional longitudinal compressive pulses of diverse shapes and lengths - formed with pulse shapers - are used to generate a variety of loading histories under 1D states of stress in cylindrical rock samples, in order to measure the respective stress-strain response at specific strain rates. Subsequent microstructural analysis of the deformed samples is aimed at quantification fracture orientation, fracture pattern, fracture density, and fracture surface properties as a function of the loading rate. Linking mechanical and microstructural data to natural dynamic deformation processes has relevance for the understanding of earthquakes, landslides, impacts, and has several rock engineering applications. For instance, experiments on dynamic fragmentation help to unravel super-shear rupture events that pervasively pulverize rocks up to several hundred meters from the fault core [2, 3, 4]. The dynamic, strain

Detrital zircon provenance from three turbidite depocenters of the Middle-Upper Triassic Songpan-Ganzi complex, central China: Record of collisional tectonics, erosional exhumation, and sediment production

USGS Publications Warehouse

Weislogel, A.L.; Graham, S.A.; Chang, E.Z.; Wooden, J.L.; Gehrels, G.E.

2010-01-01

To test the idea that the voluminous upper Middle to Upper Triassic turbidite strata in the Songpan-Ganzi complex of central China archive a detrital record of Dabie ultrahigh-pressure (UHP) terrane unroofing, we report 2080 single detrital U-Pb zircon ages by sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis from 29 eastern Songpan-Ganzi complex sandstone samples. Low (<0.07) Th/U zircons, consistent with crystallization under UHP conditions, are rare in eastern Songpan-Ganzi complex zircon, and U-Pb ages of low Th/U zircons are incompatible with a Dabie terrane source. An unweighted pair group method with arithmetic mean nearest-neighbor analysis of Kolmogorov-Smirnov two-sample test results reveals that the eastern Songpan-Ganzi complex is not a single contiguous turbidite system but is instead composed of three subsidiary depocenters, each associated with distinct sediment sources. The northeastern depocenter contains zircon ages characterized by Paleozoic and bimodally distributed Precambrian zircon populations, which, together with south-to southeast-directed paleocurrent data, indicate derivation from the retro-side of the Qinling-Dabie (Q-D) collisional orogen wedge. In the central depocenter, the dominantly Paleozoic detrital zircon signature and south-to southwest-oriented paleocurrent indicators reflect a profusion of Paleozoic zircon grains. These data are interpreted to reflect an influx of material derived from erosion of Paleozoic supra-UHP rocks of the Dabie terrane in the eastern Qinling-Dabie orogen, which we speculate may have been enhanced by development of a monsoonal climate. This suggests that erosional unroofing played a significant role in the initial phase of UHP exhumation and likely influenced the petrotectonic and structural evolution of the Qinling-Dabie orogen, as evidenced by compressed Triassic isotherms/grads reported in the

Micromechanics of pressure-induced grain crushing in porous rocks

NASA Astrophysics Data System (ADS)

Davis, Daniel M.

1990-01-01

The hydrostatic compaction behavior of a suite of porous sandstones was investigated at confining pressures up to 600 MPa and constant pore pressures ranging up to 50 MPa. These five sandstones (Boise, Kayenta, St. Peter, Berea, and Weber) were selected because of their wide range of porosity (5-35%) and grain size (60-460 μm). We tested the law of effective stress for the porosity change as a function of pressure. Except for Weber sandstone (which has the lowest porosity and smallest grain size), the hydrostat of each sandstone shows an inflection point corresponding to a critical effective pressure beyond which an accelerated, irrecoverable compaction occurs. Our microstructural observations show that brittle grain crushing initiates at this critical pressure. We also observed distributed cleavage cracking in calcite and intensive kinking in mica. The critical pressures for grain crushing in our sandstones range from 75 to 380 MPa. In general, a sandstone with higher porosity and larger grain size has a critical pressure which is lower than that of a sandstone with lower porosity and smaller grain size. We formulate a Hertzian fracture model to analyze the micromechanics of grain crushing. Assuming that the solid grains have preexisting microcracks with dimensions which scale with grain size, we derive an expression for the critical pressure which depends on the porosity, grain size, and fracture toughness of the solid matrix. The theoretical prediction is in reasonable agreement with our experimental data as well as other data from soil and rock mechanics studies for which the critical pressures range over 3 orders of magnitude.

Evolution of supercritical fluid in deeply subducted continental crust: a case study of composite granite-quartz veins in the Sulu belt, China

NASA Astrophysics Data System (ADS)

Wang, S.; Wang, L.; Brown, M.

2016-12-01

Although fluid plays a key role in element transport and rock strength during subduction to and exhumation from ultrahigh pressure (UHP) metamorphic conditions, the source of supercritical fluid at P above the second critical endpoints (SCE) and the subsequent evolution are not well constrained. To provide insight into the evolution of supercritical fluid in continental subduction zones, we undertook an integrated study of composite granite-quartz veins in retrogressed and migmatitic UHP eclogite at General's Hill, N of Qingdao, in the central Sulu belt. The composite veins are irregularly distributed in the eclogite, which occurs as blocks within gneiss. The granite component is enriched in large ion lithophile elements and light rare earth elements but depleted in high field strength elements and heavy rare earth elements, indicating crystallization from a melt phase of crustal origin. Additionally, the granite contains high modal phengite (22-30 vol%) and clinozoisite/epidote (3-10 vol%), implying precipitation from a H2O-rich silicate melt. By contrast, the quartz component is dominated by SiO2 (99.10 wt%), and contains low total rare earth elements (ΣREE = 0.46 ppm), indicating precipitation from an aqueous fluid. The crystallization age of the composite veins is 221 ± 2 Ma, which is younger than the UHP metamorphism in the Sulu belt at ca 230 Ma, consistent with formation during exhumation. Initial 176Hf/177Hf ratios and δ18O values of metamorphic zircons from the composite veins, and Sr-Nd isotope compositions of the granites all lie between values for eclogite and gneiss, indicating a mixed source. Accordingly, we propose that a supercritical fluid generated from the gneiss and the included blocks of eclogite at P-T conditions above the SCE for both compositions became trapped in the eclogite during exhumation. At P below the SCE for the hydrous granite system, the mixed supercritical fluid separated into immiscible aqueous melt and aqueous fluid and

The role of high-pressure metamorphic rocks in collisional processes with a microplate involved

NASA Astrophysics Data System (ADS)

Massonne, Hans-Joachim

2013-04-01

High-pressure (HP: p >10 kbar) rocks, especially easily recognizable eclogite lenses, are markers of a collision of major continental plates in Phanerozoic times, but how about a collison with a microplate? To answer this question, petrological studies were undertaken on garnet-bearing metamorphic rocks. Especially pressure (P) - temperature (T) pseudosections were calculated to reconstruct the P-T path of such rocks. Areas in the Andes and their eastern foreland (Argentina, Ecuador) and the Carboniferous realm of western and central Europe were studied, where microplates either had collided with the South American plate or had been located between colliding Laurussia and Gondwana. The following features resulted: (1) laterally extended zones of HP rocks mark collisional sutures, but eclogite lenses are virtually absent; (2) these HP rocks are dominantly metapelites which have experienced pressures as high as 1.2 to 1.5 GPa; (3) these pressures were reached between 450 to 550°C, followed by a P release at increasing T; (4) the T peak in the range of 500-650°C at P between 0.5 and 0.8 GPa is often characterized by the blastesis of plagioclase occasionally together with staurolite; (5) this event was pre-dated by two deformational events. The second deformation occurred during the early exhumation. Considering the regional geology of the study areas, these features are interpreted as follows: Prior to the collision a basin, extending over at most some hundred kilometers perpendicular to the basin axis, existed between the colliding microplate and the major plate. Eventually, a rifting event had caused the separation of the microplate from the major continental plate. The basin, which was opened by this event and filled with sediments, could have developed further to a back-arc basin. Then, the extensional regime turned to a compressional one. During compression the basin sediments on top of thinned continental crust were buried beneath the overriding major plate

Continental Subduction: Mass Fluxes and Interactions with the Wider Earth System

NASA Astrophysics Data System (ADS)

Cuthbert, S. J.

2011-12-01

Substantial parts of ultra-high pressure (UHP) terrains probably represent subducted passive continental margins (PCM). This contribution reviews and synthesises research on processes operating in such systems and their implication for the wider Earth system. PCM sediments are large repositories of volatiles including hydrates, nitrogen species, carbonates and hydrocarbons. Sediments and upper/ mid-crustal basement are rich in incompatible elements and are fertile for melting. Lower crust may be more mafic and refractory. Juvenile rift-related mafic rocks also have the potential to generate substantial volumes of granitoid melts, especially if they have been hydrated. Exposed UHP terrains demonstrate the return of continental crust from mantle depths, show evidence for substantial fluxes of aqueous fluid, anatexis and, in entrained orogenic peridotites, metasomatism of mantle rocks by crust- derived C-O-H fluids. However, substantial bodies of continental material may never return to the surface as coherent masses of rock, but remain sequestered in the mantle where they melt or become entrained in the deeper mantle circulation. Hence during subduction, PCM's become partitioned by a range of mechanisms. Mechanical partitioning strips away weaker sediment and middle/upper crust, which circulate back up the subduction channel, while denser, stronger transitional pro-crust and lower crust may "stall" near the base of the lithosphere or be irreversibly subducted to join the global mantle circulation. Under certain conditions sediment and upper crustal basement may reach depths for UHPM. Further partitioning takes place by anatexis, which either aids stripping and exhumation of the more melt-prone rock-masses through mechanical softening, or separates melt from residuum so that melt escapes and is accreted to the upper plate leading to "undercrusting", late-orogenic magmatism and further refinement of the crust. Melt that traverses sections of mantle will interact with

Cathodoluminescence of diamond as an indicator of its metamorphic history

NASA Astrophysics Data System (ADS)

Kopylova, Maya; Bruce, Loryn; Longo, Micaela; Ryder, John; Dobrzhinetskaya, Larissa

2010-05-01

Diamond displays a supreme resistance to chemical and mechanical weathering, ensuring its survival through complex and prolonged crustal processes, including metamorphism and exhumation. For these reasons, volcanic sources and secondary and tertiary collectors for detrital placer diamonds, like Ural or Bingara diamonds, may be difficult to determine. If metamorphic processes leave their marks on diamond, they can be used to reconstruct crustal geologic processes and ages of primary diamondiferous volcanics. Four diamond suites extracted from metamorphic rocks have been characterized using optical CL, infrared and CL spectroscopy, and photoluminescence at the liquid nitrogen temperature. The studied diamonds are from the ~2.7 Ga sedimentary conglomerate and lamprophyric breccia metamorphosed in the greenschist facies (Wawa, Northern Ontario, Canada) during the 2.67 Ga Kenoran orogeny, and from the ultra-high pressure (UHP) terranes of Kokchetav (Kazakhstan) and Erzgebirge (Germany) exhumated in the Paleozoic. Wawa diamonds (Type IaAB and Type II) displayed green, yellow, orange, and red CL colours controlled by the CL emittance at 520, 576 nm, and between 586 and 664 nm. The UHP terranes diamonds show much weaker CL; few luminescent stones display CL peaks at 395, 498, 528 nm and a broad band at 580-668 nm. In contrast, most common diamonds found in unmetamorphosed rocks, i.e. octahedrally grown Type IaAB stones, luminescence blue emitting light at ~415-440 nm and 480-490 nm. There is a noticeable difference between cathodoluminescence of these diamonds and diamonds in metamorphic rocks. The studied diamonds that experienced metamorphism show a shift of CL emission to longer wavelengths (above 520 nm) and to green, yellow and red CL colours. Photoluminescence has the high resolution necessary to assign luminescence to specific optical centers of diamond. Diamonds in metamorphic rocks contain H3 (pairs of substitutional nitrogen atoms separated by a vacancy) and NVo

Cracked rocks with positive and negative Poisson's ratio: real-crack properties extracted from pressure dependence of elastic-wave velocities

NASA Astrophysics Data System (ADS)

Zaitsev, Vladimir Y.; Radostin, Andrey V.; Dyskin, Arcady V.; Pasternak, Elena

2017-04-01

We report results of analysis of literature data on P- and S-wave velocities of rocks subjected to variable hydrostatic pressure. Out of about 90 examined samples, in more than 40% of the samples the reconstructed Poisson's ratios are negative for lowest confining pressure with gradual transition to the conventional positive values at higher pressure. The portion of rocks exhibiting negative Poisson's ratio appeared to be unexpectedly high. To understand the mechanism of negative Poisson's ratio, pressure dependences of P- and S-wave velocities were analyzed using the effective medium model in which the reduction in the elastic moduli due to cracks is described in terms of compliances with respect to shear and normal loading that are imparted to the rock by the presence of cracks. This is in contrast to widely used descriptions of effective cracked medium based on a specific crack model (e.g., penny-shape crack) in which the ratio between normal and shear compliances of such a crack is strictly predetermined. The analysis of pressure-dependences of the elastic wave velocities makes it possible to reveal the ratio between pure normal and shear compliances (called q-ratio below) for real defects and quantify their integral content in the rock. The examination performed demonstrates that a significant portion (over 50%) of cracks exhibit q-ratio several times higher than that assumed for the conventional penny-shape cracks. This leads to faster reduction of the Poisson's ratio with increasing the crack concentration. Samples with negative Poisson's ratio are characterized by elevated q-ratio and simultaneously crack concentration. Our results clearly indicate that the traditional crack model is not adequate for a significant portion of rocks and that the interaction between the opposite crack faces leading to domination of the normal compliance and reduced shear displacement discontinuity can play an important role in the mechanical behavior of rocks.

The effect of pressure and mobile phase velocity on the retention properties of small analytes and large biomolecules in ultra-high pressure liquid chromatography.

PubMed

Fekete, Szabolcs; Veuthey, Jean-Luc; McCalley, David V; Guillarme, Davy

2012-12-28

A possible complication of ultra-high pressure liquid chromatography (UHPLC) is related to the effect of pressure and mobile phase velocity on the retention properties of the analytes. In the present work, numerous model compounds have been selected including small molecules, peptides, and proteins (such as monoclonal antibodies). Two instrumental setups were considered to attain elevated pressure drops, firstly the use of a post-column restrictor capillary at low mobile phase flow rate (pure effect of pressure) and secondly the increase of mobile phase flow rate without restrictor (i.e. a combined effect of pressure and frictional heating). In both conditions, the goal was to assess differences in retention behaviour, depending on the type or character of the analyte. An important conclusion is that the effect of pressure and mobile phase velocity on retention varied in proportion with the size of the molecule and in some cases showed very different behaviour. In isocratic mode, the pure effect of pressure (experiments with a post-column restrictor capillary) induces an increase in retention by 25-100% on small molecules (MW<300 g/mol), 150% for peptides (~1.3 kDa), 800% for insulin (~6 kDa) and up to >3000% for myoglobin (~17 kDa) for an increase in pressure from 100 bar up to 1100 bar. The important effect observed for the isocratic elution of proteins is probably related to conformational changes of the protein in addition to the effect of molecular size. Working in gradient elution mode, the pressure related effects on retention were found to be less pronounced but still present (an increase of apparent retention factor between 0.2 and 2.5 was observed). Copyright © 2012 Elsevier B.V. All rights reserved.

Rock burst governance of working face under igneous rock

NASA Astrophysics Data System (ADS)

Chang, Zhenxing; Yu, Yue

2017-01-01

As a typical failure phenomenon, rock burst occurs in many mines. It can not only cause the working face to cease production, but also cause serious damage to production equipment, and even result in casualties. To explore how to govern rock burst of working face under igneous rock, the 10416 working face in some mine is taken as engineering background. The supports damaged extensively and rock burst took place when the working face advanced. This paper establishes the mechanical model and conducts theoretical analysis and calculation to predict the fracture and migration mechanism and energy release of the thick hard igneous rock above the working face, and to obtain the advancing distance of the working face when the igneous rock fractures and critical value of the energy when rock burst occurs. Based on the specific conditions of the mine, this paper put forward three kinds of governance measures, which are borehole pressure relief, coal seam water injection and blasting pressure relief.

On the role of horizontal displacements in the exhumation of high pressure metamorphic rocks

NASA Astrophysics Data System (ADS)

Brun, J.-P.; Tirel, C.; Philippon, M.; Burov, E.; Faccenna, C.; Gueydan, F.; Lebedev, S.

2012-04-01

High pressure metamorphic rocks exposed in the core of many mountain belts correspond to various types of upper crustal materials that have been buried to mantle depths and, soon after, brought back to surface at mean displacement rates up to few cm/y, comparable to those of plate boundaries. The vertical component of HP rock exhumation velocity back to surface is commonly well constrained by pressure estimates from petrology and geochronological data whereas the horizontal component remains generally difficult or impossible to estimate. Consequently, most available models, if not all, attempt to simulate exhumation with a minimal horizontal component of displacement. Such models, require that the viscosity of HP rocks is low and/or the erosion rate large -i.e. at least equal to the rate of exhumation. However, in some regions like the Aegean, where the exhumation of blueschists and eclogites is driven by slab rollback, it can be shown that the horizontal component of exhumation related displacement, obtained from map view restoration, is 5 to 7 times larger than the vertical one, deduced from metamorphic pressure estimates. Using finite element models performed with FLAMAR, we show that such a situation simply results from the subduction of small continental blocks (< 500km) that stimulate subduction rollback. The continental block is dragged downward and sheared off the downgoing mantle slab by buoyancy force. Exhumation of the crustal block occurs through a one step Caterpillar-type walk, with the block's tail slipping along a basal décollement, approaching the head and making a large buckle, which then unrolls at surface as soon as the entire block is delaminated. Finally, the crustal block emplaces at surface in the space created by trench retreat. This process of exhumation requires neither rheological weakening of HP rocks nor high rates of erosion.

Combined garnet and zircon geochronology and trace elements studies - constraints of the UHP-(U)HT evolution of Orlica-Śnieżnik Dome (NE Bohemian Massif).

NASA Astrophysics Data System (ADS)

Walczak, Katarzyna; Anczkiewicz, Robert; Szczepański, Jacek; Rubatto, Daniela

2017-04-01

The Orlica-Śnieżnik Dome (OSD), located on the NE margin of the Bohemian Massif, is predominantly composed of amphibolite-facies orthogneiss that contain bodies of HP and UHP eclogites and granulites. Numerous geochronological studies have been undertaken to constrain the timing of the ultra-high grade metamorphic event. Despite this, the exact timing of UHP-(U)HT conditions remain dubious (e.g. Brueckner et al., 1991; Anczkiewicz et al., 2007; Bröcker et al., 2009 & 2010). We have utilized garnet and zircon geochronology to provide time constraints on the evolution of the UHT-(U)HP rocks of the OSD. We have combined the ages with trace element analyses in garnet and zircon to better understand the significance of the obtained ages in petrological context. Lu-Hf grt-wr dating of peritectic garnet from two felsic granulites constrained the time of its initial growth at 346.9 ± 1.2 and 348.3 ± 2.0 Ma, recording peak conditions of 2.7 GPa and 950°C (e.g. Ferrero et al., 2015). In situ U-Pb SHRIMP dating of zircon from the same granulite gave a younger age of 342.2 ± 3.4 Ma. HREE partitioning between garnet rim and metamorphic zircon indicate their growth in equilibrium, hence, the U-Pb zircon date constrains the terminal phase of garnet crystallization. Similar ages were obtained from two eclogite bodies from Międzygórze and Nowa Wieś localities; Lu-Hf (grt-cpx-wr) dating provided ages of 346.5 ± 2.4 and 348.1 ± 9.1 Ma for samples from Międzygórze and Nowa Wieś, respectively. The same age (within error) of 346.3 ± 5.2 Ma was reported by Bröcker et al. (2010) for zircon from the Międzygórze eclogite. Comparison of REE concentrations in garnet (this study) and in metamorphic zircon (reported in Bröcker et al., 2010) indicate that garnet and zircon crystallized in equilibrium. Furthermore, M-HREE patterns observed in both garnet and zircon strongly suggest their growth at eclogite facies conditions. Sm-Nd garnet ages obtained for both felsic and mafic

Effect of ultra-high pressure homogenization on the interaction between bovine casein micelles and ritonavir.

PubMed

Corzo-Martínez, M; Mohan, M; Dunlap, J; Harte, F

2015-03-01

The aim of this work was to develop a milk-based powder formulation appropriate for pediatric delivery of ritonavir (RIT). Ultra-high pressure homogenization (UHPH) at 0.1, 300 and 500 MPa was used to process a dispersion of pasteurized skim milk (SM) and ritonavir. Loading efficiency was determined by RP-HPLC-UV; characterization of RIT:SM systems was carried out by apparent average hydrodynamic diameter and rheological measurements as well as different analytical techniques including Trp fluorescence, UV spectroscopy, DSC, FTIR and SEM; and delivery capacity of casein micelles was determined by in vitro experiments promoting ritonavir release. Ritonavir interacted efficiently with milk proteins, especially, casein micelles, regardless of the processing pressure; however, results suggest that, at 0.1 MPa, ritonavir interacts with caseins at the micellar surface, whilst, at 300 and 500 MPa, ritonavir is integrated to the protein matrix during UHPH treatment. Likewise, in vitro experiments showed that ritonavir release from micellar casein systems is pH dependent; with a high retention of ritonavir during simulated gastric digestion and a rapid delivery under conditions simulating the small intestine environment. Skim milk powder, especially, casein micelles are potentially suitable and efficient carrier systems to develop novel milk-based and low-ethanol powder formulations of ritonavir appropriate for pediatric applications.

Amphibole equilibria as monitors of P-T path and process in the exhumation of HP/UHP terranes

NASA Astrophysics Data System (ADS)

Waters, David; Airaghi, Laura; Czertowicz, Thomas

2014-05-01

trend between actinolite and pargasite, with low glaucophane component. Pressures and temperatures for matrix and spongy amphiboles are constrained by mapping phase compositions and proportions on P-T phase diagrams calculated for a range of water contents in bulk rock and local systems. In HP eclogites they define near-isothermal decompression trajectories from ~20 to ~12 kbar at ~630-670°C. Matrix and spongy amphiboles from UHP eclogites lacking significant hydrous minerals require influx of external fluid in the interval 16-12 kbar. In symplectites conditions are derived from an internal equilibrium among amphibole, pyroxene and plagioclase. In a number of cases the variation along lamellae in a symplectite colony defines a P-T array covering ~60°C of cooling over ~3 kbar decompression down to 12-10 kbar. In many cases amphibole development can be linked to both external and local sources of aqueous fluid. Microstructural and chemical evidence links symplectite formation to the breakdown of phengite. The near-isothermal earlier stages of P-T paths in these slices dominated by continental units suggest that exhumation did not take place in a cold subduction channel, but may reflect a post-collisional mechanism. The lower P-T slope of paths associated with later symplectite arrays may reflect the loss of buoyancy contrast as exhuming slices reach crustal levels.

Unsteady surface pressure measurements on a slender delta wing undergoing limit cycle wing rock

NASA Technical Reports Server (NTRS)

Arena, Andrew S., Jr.; Nelson, Robert C.

1991-01-01

An experimental investigation of slender wing limit cycle motion known as wing rock was investigated using two unique experimental systems. Dynamic roll moment measurements and visualization data on the leading edge vortices were obtained using a free to roll apparatus that incorporates an airbearing spindle. In addition, both static and unsteady surface pressure data was measured on the top and bottom surfaces of the model. To obtain the unsteady surface pressure data a new computer controller drive system was developed to accurately reproduce the free to roll time history motions. The data from these experiments include, roll angle time histories, vortex trajectory data on the position of the vortices relative to the model's surface, and surface pressure measurements as a function of roll angle when the model is stationary or undergoing a wing rock motion. The roll time history data was numerically differentiated to determine the dynamic roll moment coefficient. An analysis of these data revealed that the primary mechanism for the limit cycle behavior was a time lag in the position of the vortices normal to the wing surface.

Salt Neutrino Detector for Ultrahigh-Energy Neutrinos

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiba, M.; Yasuda, O.; Kamijo, T.

2004-11-01

Rock salt and limestone are studied to determine their suitability for use as a radio-wave transmission medium in an ultrahigh energy (UHE) cosmic neutrino detector. A sensible radio wave would be emitted by the coherent Cherenkov radiation from negative excess charges inside an electromagnetic shower upon interaction of a UHE neutrino in a high-density medium (Askar'yan effect). If the attenuation length for the radio wave in the material is large, a relatively small number of radio-wave sensors could detect the interaction occurring in the massive material. We measured the complex permittivity of the rock salt and limestone by the perturbedmore » cavity resonator method at 9.4 and 1 GHz to good precision. We obtained new results of measurements at the frequency at 1.0 GHz. The measured value of the radio-wave attenuation length of synthetic rock salt samples is 1080 m. The samples from the Hockley salt mine in the United States show attenuation length of 180 m at 1 GHz, and then we estimate it by extrapolation to be as long as 900 m at 200 MHz. The results show that there is a possibility of utilizing natural massive deposits of rock salt for a UHE neutrino detector. A salt neutrino detector with a size of 2 x 2 x 2 km would detect 10 UHE neutrino/yr generated through the GZK process.« less

The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis

USGS Publications Warehouse

Price, L.C.; Wenger, L.M.

1992-01-01

Because fluid pressures are transient in sedimentary basins over geologic time, the effect of increasing fluid pressure on organic-matter metamorphism is difficult to determine, and conflicting opinions exist concerning its influence. Properly-performed aqueous-pyrolysis experiments can closely simulate hydrocarbon generation and maturation in nature, and thus offer an excellent way to study the influence of pressure. Such experiments, carried out on the Retort Phosphatic Shale Member of the Lower Permian Phosphoria Formation (type II-S organic matter) at different constant temperatures, demonstrated that increasing pressure significantly retards all aspects of organic matter metamorphism, including hydrocarbon generation, maturation and thermal destruction. This conclusion results from detailed quantitative and qualitative analyses of all products from hydrocarbon generation, from the C1 to C4 hydrocarbon gases to the asphaltenes, and also from analyses of the reacted rocks. We have documented that our aqueous-pyrolysis experiments closely simulated natural hydrocarbon generation and maturation. Thus the data taken as a function of pressure have relevance to the influence of normal and abnormal fluid pressures as related to: 1) depths and temperatures of mainstage hydrocarbon generation; 2) the thermal destruction of deposits of gas or light oil, or their preservation to unexpectedly high maturation ranks; and 3) the persistence of measurable to moderate concentrations of C15+ hydrocarbons in fine-grained rocks even to ultra-high maturation ranks. ?? 1992.

Artificial neural network modeling and optimization of ultrahigh pressure extraction of green tea polyphenols.

PubMed

Xi, Jun; Xue, Yujing; Xu, Yinxiang; Shen, Yuhong

2013-11-01

In this study, the ultrahigh pressure extraction of green tea polyphenols was modeled and optimized by a three-layer artificial neural network. A feed-forward neural network trained with an error back-propagation algorithm was used to evaluate the effects of pressure, liquid/solid ratio and ethanol concentration on the total phenolic content of green tea extracts. The neural network coupled with genetic algorithms was also used to optimize the conditions needed to obtain the highest yield of tea polyphenols. The obtained optimal architecture of artificial neural network model involved a feed-forward neural network with three input neurons, one hidden layer with eight neurons and one output layer including single neuron. The trained network gave the minimum value in the MSE of 0.03 and the maximum value in the R(2) of 0.9571, which implied a good agreement between the predicted value and the actual value, and confirmed a good generalization of the network. Based on the combination of neural network and genetic algorithms, the optimum extraction conditions for the highest yield of green tea polyphenols were determined as follows: 498.8 MPa for pressure, 20.8 mL/g for liquid/solid ratio and 53.6% for ethanol concentration. The total phenolic content of the actual measurement under the optimum predicated extraction conditions was 582.4 ± 0.63 mg/g DW, which was well matched with the predicted value (597.2mg/g DW). This suggests that the artificial neural network model described in this work is an efficient quantitative tool to predict the extraction efficiency of green tea polyphenols. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Imaging high-pressure rock exhumation along the arc-continent suture in eastern Taiwan

NASA Astrophysics Data System (ADS)

Brown, Dennis; Feng, Kuan-Fu; Wu, Yih-Min; Huang, Hsin-Hua

2015-04-01

Imaging high-pressure rock exhumation in active tectonic settings is considered to be one of the important observations that could potentially help to move forward the understanding of how this process works. Petrophysical analyses carried out along a high velocity zone imaged by seismic travel time tomography along the suture zone between the actively colliding Luzon Arc and the southeastern margin of Eurasia in Taiwan suggests that high-pressure rocks are being exhumed from at least a depth of 50 km below the arc-continent suture to the shallow subsurface where they coincide with an outcropping tectonic mélange called the Yuli Belt. The Yuli Belt comprises mainly greenschist facies quartz-mica schist, with lesser metabasite, metamorphosed mantle fragments and, importantly, minor blueschist. Modeling of published data bases of measured seismic velocities for a large suite of rocks suggests that all of the Yuli belt lithologies fit well with the measured Vp, Vs, and Vp/Vs at ambient pressures and temperatures (a 20 oC/km geotherm is used) from 10 to about 20 km depth. With the exception of hornblendite, mantle rocks need 30% to 40 % serpentinization to approximate the in situ range of Vp and and Vs at these depths. From about 20 km to 30 km, most continental crust and volcanic arc lithologies move out of the range of velocities measured by the tomography model at these depths. Blueschist (including the calculated Vp and Vs for the Yuli Belt samples), pyroxenite, and harzburgite, lherzolite, and dunite with around 20% to 30% serpentinization now enter into the range of velocities for these depths. From 40 km to 50 km depth, the mantle rocks pyroxenite, and weakly to unserpentinized harzburgite, lherzolite, and dunite, together with mafic eclogite velocities best fit the range of Vp, Vs and Vp/Vs at these depths. Seismicity along the arc-continent suture, the upper bounding fault of the high velocity zone examined here, indicate that it is a moderately oblique

Chlorine Isotope Evidence for Syn-Subduction Modification of Serpentinites by Interaction with Sediment-Derived Fluid

NASA Astrophysics Data System (ADS)

Selverstone, J.; Sharp, Z. D.

2012-12-01

High-pressure serpentinites and rodingites and high- to ultrahigh-pressure metasedimentary rocks from the Aosta region, Italy, preserve strikingly different chlorine isotope compositions that can be used to constrain the nature of fluid-rock interactions during subduction. Serpentinites and rodingitized gabbroic dikes subducted to 70-80 km have bulk δ37Cl values between -1.6 and +0.9‰ (median= -0.5‰, n=26 plus 5 replicates; one amphibole-vein outlier at -2.9‰). Serpentinite δ37Cl values are positively correlated with Cr ± Cl contents (r2= 0.97 and 0.58) and negatively correlated with CaO (r2=0.72). BSE imaging and X-ray mapping reveal up to three generations of compositionally distinct serpentine and chlorite in single samples. The youngest generation, which is most abundant, has the lowest chlorine content. Three rodingite samples contain abundant texturally early fluid inclusions. These samples were finely crushed and leached in 18 MΩ H2O to extract water-soluble chlorides. The leachates, which are assumed to record the compositions of the fluid inclusions, have δ37Cl values that are 0.7-1.5‰ lower than the corresponding bulk rock values. Leachate from the outlier amph-magnesite vein is indistinguishable from the bulk value at -2.7‰. There is almost no overlap between the Cl isotope compositions of HP serp/rod samples and associated HP/UHP metasedimentary rocks. Calcmica schists, diamond-bearing Mn nodules, and impure marbles subducted to >130 km and calcmica schists and Mn crusts transported to 70-80 km have δ37Cl values between -4.5 and -1.5‰ (median= -2.7‰, n=25 plus 7 replicates; two outlier points at -0.5‰). Primary fluid inclusions in the diamondiferous samples contain carbonate- and silicate-bearing aqueous fluids with very low chloride contents (Frezzotti et al., 2011, Nature Geosci). Taken together, these data record a history of progressive modification of serpentinites and rodingites by mixing with low-δ37Cl, low-Cl, high

Reproducing early Martian atmospheric carbon dioxide partial pressure by modeling the formation of Mg-Fe-Ca carbonate identified in the Comanche rock outcrops on Mars

NASA Astrophysics Data System (ADS)

Berk, Wolfgang; Fu, Yunjiao; Ilger, Jan-Michael

2012-10-01

The well defined composition of the Comanche rock's carbonate (Magnesite0.62Siderite0.25Calcite0.11Rhodochrosite0.02) and its host rock's composition, dominated by Mg-rich olivine, enable us to reproduce the atmospheric CO2partial pressure that may have triggered the formation of these carbonates. Hydrogeochemical one-dimensional transport modeling reveals that similar aqueous rock alteration conditions (including CO2partial pressure) may have led to the formation of Mg-Fe-Ca carbonate identified in the Comanche rock outcrops (Gusev Crater) and also in the ultramafic rocks exposed in the Nili Fossae region. Hydrogeochemical conditions enabling the formation of Mg-rich solid solution carbonate result from equilibrium species distributions involving (1) ultramafic rocks (ca. 32 wt% olivine; Fo0.72Fa0.28), (2) pure water, and (3) CO2partial pressures of ca. 0.5 to 2.0 bar at water-to-rock ratios of ca. 500 molH2O mol-1rock and ca. 5°C (278 K). Our modeled carbonate composition (Magnesite0.64Siderite0.28Calcite0.08) matches the measured composition of carbonates preserved in the Comanche rocks. Considerably different carbonate compositions are achieved at (1) higher temperature (85°C), (2) water-to-rock ratios considerably higher and lower than 500 mol mol-1 and (3) CO2partial pressures differing from 1.0 bar in the model set up. The Comanche rocks, hosting the carbonate, may have been subjected to long-lasting (>104 to 105 years) aqueous alteration processes triggered by atmospheric CO2partial pressures of ca. 1.0 bar at low temperature. Their outcrop may represent a fragment of the upper layers of an altered olivine-rich rock column, which is characterized by newly formed Mg-Fe-Ca solid solution carbonate, and phyllosilicate-rich alteration assemblages within deeper (unexposed) units.

Dewaterability of five sewage sludges in Guangzhou conditioned with Fenton's reagent/lime and pilot-scale experiments using ultrahigh pressure filtration system.

PubMed

Liang, Jialin; Huang, Shaosong; Dai, Yongkang; Li, Lei; Sun, Shuiyu

2015-11-01

Sludge conditioning with Fenton's reagent and lime is a valid method for sludge dewatering. This study investigated the influence of different organic matter content sludge on sludge dewatering and discussed the main mechanism of sludge conditioning by combined Fenton's reagent and lime. The results indicated that the specific resistance to filterability (SRF) of sludge was reduced efficiently by approximately 90%, when conditioned with Fenton's reagent and lime. Through single factor experiments, the optimal conditioning combinations were found. In addition, the relationship between VSS% and consumption of the reagents was detected. Furthermore, it was also demonstrated that the SRF and filtrate TOC values had a significant correlation with VSS% of sludge (including raw and conditioned). The main mechanism of sludge dewatering was also investigated. Firstly, it revealed that the dewaterability of sludge was closely correlated to extracellular polymeric substances (EPS) and bound water contents. Secondly, the results of scanning electron microscopy (SEM) stated that sludge particles were to be smaller and thinner after conditioning. And this structure could easily form outflow channels for releasing free water. Additionally, with the ultrahigh pressure filtration system, the water content of sludge cake conditioned with Fenton's reagent and lime could be reduced to below 50%. Moreover, the economic assessment shows that Fenton's reagent and lime combined with ultrahigh pressure filtration system can be an economical and viable technology for sewage sludge dewatering. Finally, three types of sludge were classified: (1) Fast to dewater; (2) Moderately fast to dewater; (3) Slow to dewater sludge. Copyright © 2015 Elsevier Ltd. All rights reserved.

A simple dual online ultra-high pressure liquid chromatography system (sDO-UHPLC) for high throughput proteome analysis.

PubMed

Lee, Hangyeore; Mun, Dong-Gi; Bae, Jingi; Kim, Hokeun; Oh, Se Yeon; Park, Young Soo; Lee, Jae-Hyuk; Lee, Sang-Won

2015-08-21

We report a new and simple design of a fully automated dual-online ultra-high pressure liquid chromatography system. The system employs only two nano-volume switching valves (a two-position four port valve and a two-position ten port valve) that direct solvent flows from two binary nano-pumps for parallel operation of two analytical columns and two solid phase extraction (SPE) columns. Despite the simple design, the sDO-UHPLC offers many advantageous features that include high duty cycle, back flushing sample injection for fast and narrow zone sample injection, online desalting, high separation resolution and high intra/inter-column reproducibility. This system was applied to analyze proteome samples not only in high throughput deep proteome profiling experiments but also in high throughput MRM experiments.

Implementation of high slurry concentration and sonication to pack high-efficiency, meter-long capillary ultrahigh pressure liquid chromatography columns.

PubMed

Godinho, Justin M; Reising, Arved E; Tallarek, Ulrich; Jorgenson, James W

2016-09-02

Slurry packing capillary columns for ultrahigh pressure liquid chromatography is complicated by many interdependent experimental variables. Previous results have suggested that combination of high slurry concentration and sonication during packing would create homogeneous bed microstructures and yield highly efficient capillary columns. Herein, the effect of sonication while packing very high slurry concentrations is presented. A series of six, 1m×75μm internal diameter columns were packed with 200mg/mL slurries of 2.02μm bridged-ethyl hybrid silica particles. Three of the columns underwent sonication during packing and yielded highly efficient separations with reduced plate heights as low as 1.05. Copyright © 2016 Elsevier B.V. All rights reserved.

Ultra-High Pressure Homogenization improves oxidative stability and interfacial properties of soy protein isolate-stabilized emulsions.

PubMed

Fernandez-Avila, C; Trujillo, A J

2016-10-15

Ultra-High Pressure Homogenization (100-300MPa) has great potential for technological, microbiological and nutritional aspects of fluid processing. Its effect on the oxidative stability and interfacial properties of oil-in-water emulsions prepared with 4% (w/v) of soy protein isolate and soybean oil (10 and 20%, v/v) were studied and compared to emulsions treated by conventional homogenization (15MPa). Emulsions were characterized by particle size, emulsifying activity index, surface protein concentration at the interface and by transmission electron microscopy. Primary and secondary lipid oxidation products were evaluated in emulsions upon storage. Emulsions with 20% oil treated at 100 and 200MPa exhibited the most oxidative stability due to higher amount of oil and protein surface load at the interface. This manuscript addresses the improvement in oxidative stability in emulsions treated by UHPH when compared to conventional emulsions. Copyright © 2016 Elsevier Ltd. All rights reserved.

The origin of oceanic crust and metabasic rocks protolith, the Luk Ulo Mélange Complex, Indonesia

NASA Astrophysics Data System (ADS)

Permana, H.; Munasri; Mukti, Maruf M.; Nurhidayati, A. U.; Aribowo, S.

2018-02-01

The Luk Ulo Mélange Complex (LUMC) is composed of tectonic slices of rocks that surrounded by scaly clay matrix. These rocks consist of serpentinite, gabbro, diabase, and basalt, eclogite, blueschist, amphibolite, schist, gneiss, phylite and slate, granite, chert, red limestone, claystone and sandstone. The LUMC was formed since Paleocene to Eocene, gradually uplifted of HP-UHP metabasic-metapelite (P: 20-27kbar; T: 410-628°C) to near surface mixed with hemipelagic sedimentary rocks. The metamorphic rocks were formed during 101-125 Ma (Early Cretaceous) within 70 to 100 km depth and ∼6°C/km thermal gradient. It took about 50-57 Myr for these rocks to reach the near surface during Paleocene-Eocene, with an uplift rate at ∼1.4-1.8 km/year to form the mélange complex. The low thermal gradient was due to subduction of old and cold oceanic crust. The subducted oceanic crust (MORB) as protolith of Cretaceous metabasic rocks must be older than Cretaceous. The data show that the basalt of oceanic crust is Cretaceous (130-81 Ma) comparable to the age of the cherts (Early to Late Cretaceous). Therefore, we consider that neither oceanic crust exposed in LUMC nor all of part of the old oceanic crust is the protolith of LUMC metabasic subducted beneath the Eurasian Plate. These oceanic rocks possibly originated or part of the edge of micro-continental that merged as a part of the LUMC during the collision with the Eurasian margin.

EFFECT OF ULTRA-HIGH PRESSURE HOMOGENIZATION ON THE INTERACTION BETWEEN BOVINE CASEIN MICELLES AND RITONAVIR

PubMed Central

Corzo-Martínez, M.; Mohan, M.; Dunlap, J.; Harte, F.

2014-01-01

Purpose The aim of this work was to develop a milk-based powder formulation appropriate for pediatric delivery of ritonavir (RIT). Methods Ultra-high pressure homogenization (UHPH) at 0.1, 300 and 500 MPa was used to process a dispersion of pasteurized skim milk (SM) and ritonavir. Loading efficiency was determined by RP-HPLC-UV; characterization of RIT:SM systems was carried out by apparent average hydrodynamic diameter and rheological measurements as well as different analytical techniques including Trp fluorescence, UV spectroscopy, DSC, FTIR and SEM; and delivery capacity of casein micelles was determined by in vitro experiments promoting ritonavir release. Results Ritonavir interacted efficiently with milk proteins, especially, casein micelles, regardless of the processing pressure; however, results suggest that, at 0.1 MPa, ritonavir interacts with caseins at the micellar surface, whilst, at 300 and 500 MPa, ritonavir is integrated to the protein matrix during UHPH treatment. Likewise, in vitro experiments showed that ritonavir release from micellar casein systems is pH dependent; with a high retention of ritonavir during simulated gastric digestion and a rapid delivery under conditions simulating the small intestine environment. Conclusions Skim milk powder, especially, casein micelles are potentially suitable and efficient carrier systems to develop novel milk-based and low-ethanol powder formulations of ritonavir appropriate for pediatric applications. PMID:25270571

Redistribution of Iron and Titanium in High-Pressure Ultramafic Rocks

NASA Astrophysics Data System (ADS)

Crossley, Rosalind J.; Evans, Katy A.; Reddy, Steven M.; Lester, Gregory W.

2017-11-01

The redox state of iron in high-pressure serpentinites, which host a significant proportion of Fe3+ in subduction zones, can be used to provide an insight into iron cycling and constrain the composition of subduction zone fluids. In this study, we use oxide and silicate mineral textures, interpretation of mineral parageneses, mineral composition data, and whole rock geochemistry of high-pressure retrogressed ultramafic rocks from the Zermatt-Saas Zone to constrain the distribution of iron and titanium, and iron oxidation state. These data provide an insight on the oxidation state and composition of fluids at depth in subduction zones. Oxide minerals host the bulk of iron, particularly Fe3+. The increase in mode of magnetite and observation of magnetite within antigorite veins in the investigated ultramafic samples during initial retrogression is most consistent with oxidation of existing iron within the samples during the infiltration of an oxidizing fluid since it is difficult to reconcile addition of Fe3+ with the known limited solubility of this species. However, high Ti contents are not typical of serpentinites and also cannot be accounted for by simple mixing of a depleted mantle protolith with the nearby Allalin gabbro. Titanium-rich phases coincide with prograde metamorphism and initial exhumation, implying the early seafloor and/or prograde addition and late mobilization of Ti. If Ti addition has occurred, then the introduction of Fe3+, also generally considered to be immobile, cannot be disregarded. We explore possible transport vectors for Ti and Fe through mineral texture analysis.

Pliocene eclogite exhumation at plate tectonic rates in eastern Papua New Guinea.

PubMed

Baldwin, Suzanne L; Monteleone, Brian D; Webb, Laura E; Fitzgerald, Paul G; Grove, Marty; Hill, E June

2004-09-16

As lithospheric plates are subducted, rocks are metamorphosed under high-pressure and ultrahigh-pressure conditions to produce eclogites and eclogite facies metamorphic rocks. Because chemical equilibrium is rarely fully achieved, eclogites may preserve in their distinctive mineral assemblages and textures a record of the pressures, temperatures and deformation the rock was subjected to during subduction and subsequent exhumation. Radioactive parent-daughter isotopic variations within minerals reveal the timing of these events. Here we present in situ zircon U/Pb ion microprobe data that dates the timing of eclogite facies metamorphism in eastern Papua New Guinea at 4.3 +/- 0.4 Myr ago, making this the youngest documented eclogite exposed at the Earth's surface. Eclogite exhumation from depths of approximately 75 km was extremely rapid and occurred at plate tectonic rates (cm yr(-1)). The eclogite was exhumed within a portion of the obliquely convergent Australian-Pacific plate boundary zone, in an extending region located west of the Woodlark basin sea floor spreading centre. Such rapid exhumation (> 1 cm yr(-1)) of high-pressure and, we infer, ultrahigh-pressure rocks is facilitated by extension within transient plate boundary zones associated with rapid oblique plate convergence.

Unusual properties of high-compliance porosity extracted from measurements of pressure-dependent wave velocities in rocks

NASA Astrophysics Data System (ADS)

Zaitsev, Vladimir Y.; Radostin, Andrey V.; Pasternak, Elena; Dyskin, Arcady

2016-04-01

Conventionally the interpretation of wave velocities and their variations under load is conducted assuming that closable cracks have simple planar shapes, like the popular model of penny-shape cracks. For such cracks, the proportion between complementary variations in different elastic parameters of rocks (such as S- and P-wave velocities) is strictly pre-determined, in particular, it is independent of the crack aspect ratio and rather weakly dependent on the Poisson's ratio of the intact rock. Real rocks, however, contain multitude of cracks of different geometry. Faces of such cracks can exhibit complex modes of interaction when closed by external load, which may result in very different ratios between normal- and shear compliances of such defects. In order to describe the reduction of different elastic moduli, we propose a model in which the compliances of crack-like defects are explicitly decoupled and are not predetermined, so that the ratio q between total normal- and shear- compliances imparted to the rock mass (as well as individual values of these compliances) can be estimated from experimental data on reduction of different elastic moduli (e.g., pressure dependences of P- and S-wave velocities). Physically, the so-extracted ratio q can be interpreted as intrinsic property of individual crack-like defects similar to each other, or as a characteristic of proportion between concentrations of pure normal cracks with very large q and pure shear cracks with q→0. The latter case can correspond, e.g., to saturated cracks in which weakly-compressible liquid prevents crack closing under normal loading. It can be shown that for conventional dry planar cracks, the compliance ratio is q ˜2. The developed model applied to the data on wave-velocity variations with external pressure indicates that elastic properties of the real crack-like defects in rocks can differ considerably from the usually assumed ones. Comparison with experimental data on variations P- and S

Ultrahigh vacuum and high-pressure coadsorption of CO and H2 on Pd(111): A combined SFG, TDS, and LEED study

NASA Astrophysics Data System (ADS)

Morkel, Matthias; Rupprechter, Günther; Freund, Hans-Joachim

2003-11-01

Sum frequency generation (SFG) vibrational spectroscopy was carried out in conjunction with thermal desorption spectroscopy, low-energy electron diffraction, and Auger electron spectroscopy to examine the coadsorption of CO and H2 on Pd(111). Sequential dosing as well as various CO/H2 mixtures was utilized to study intermolecular interactions between CO and H2. Preadsorbed CO effectively prevented the dissociative adsorption of hydrogen for CO coverages ⩾0.33 ML. While preadsorbed hydrogen was able to hinder CO adsorption at low temperature (100 K), hydrogen was replaced from the surface by CO at 150 K. When 1:1 mixtures of CO/H2 were used at 100 K, hydrogen selectively hindered CO adsorption on on-top sites, while above ˜125 K no blocking of CO adsorption was observed. The observations are explained in terms of mutual site blocking, of a CO-H phase separation, and of a CO-assisted hydrogen dissolution in the Pd bulk. The temperature-dependent site blocking effect of hydrogen is attributed to the ability (inability) of surface hydrogen to diffuse into the Pd bulk above (below) ˜125 K. Nonlinear optical SFG spectroscopy allowed us to study these effects not only in ultrahigh vacuum but also in a high-pressure environment. Using an SFG-compatible ultrahigh vacuum-high-pressure cell, spectra of 1:10 CO/H2 mixtures were acquired up to 55 mbar and 550 K, with simultaneous gas chromatographic and mass spectrometric gas phase analysis. Under reaction conditions, CO coverages ⩾0.5 ML were observed which strongly limit H2 adsorption and thus may be partly responsible for the low CO hydrogenation rate. The high-pressure and high-temperature SFG spectra also showed indications of a reversible surface roughening or a highly dynamic (not perfectly ordered) CO adsorbate phase. Implications of the observed adsorbate structures on catalytic CO hydrogenation on supported Pd nanoparticles are discussed.

Carbonation by fluid-rock interactions at high-pressure conditions: Implications for carbon cycling in subduction zones

NASA Astrophysics Data System (ADS)

Piccoli, Francesca; Vitale Brovarone, Alberto; Beyssac, Olivier; Martinez, Isabelle; Ague, Jay J.; Chaduteau, Carine

2016-07-01

Carbonate-bearing lithologies are the main carbon carrier into subduction zones. Their evolution during metamorphism largely controls the fate of carbon, regulating its fluxes between shallow and deep reservoirs. Recent estimates predict that almost all subducted carbon is transferred into the crust and lithospheric mantle during subduction metamorphism via decarbonation and dissolution reactions at high-pressure conditions. Here we report the occurrence of eclogite-facies marbles associated with metasomatic systems in Alpine Corsica (France). The occurrence of these marbles along major fluid-conduits as well as textural, geochemical and isotopic data indicating fluid-mineral reactions are compelling evidence for the precipitation of these carbonate-rich assemblages from carbonic fluids during metamorphism. The discovery of metasomatic marbles brings new insights into the fate of carbonic fluids formed in subducting slabs. We infer that rock carbonation can occur at high-pressure conditions by either vein-injection or chemical replacement mechanisms. This indicates that carbonic fluids produced by decarbonation reactions and carbonate dissolution may not be directly transferred to the mantle wedge, but can interact with slab and mantle-forming rocks. Rock-carbonation by fluid-rock interactions may have an important impact on the residence time of carbon and oxygen in subduction zones and lithospheric mantle reservoirs as well as carbonate isotopic signatures in subduction zones. Furthermore, carbonation may modulate the emission of CO2 at volcanic arcs over geological time scales.

Maruyamaite, a new K-dominant tourmaline coexisting with diamond -an important accessory mineral in UHP rocks

NASA Astrophysics Data System (ADS)

Stock, M. J.; Humphreys, M.; Smith, V.; Pyle, D. M.; Isaia, R.

2014-12-01

The apatite crystal structure is capable of incorporating H2O, F and Cl, as well as trace CO2 and sulphur. These can be related to parental magma compositions through application of a series of pressure and temperature-dependent exchange reactions (Piccoli and Candela, 1994), permitting apatite crystals to preserve a record of all major volatile species in the melt. Furthermore, due to the general incompatibility of P in other rock-forming minerals, apatite is ubiquitous in igneous systems and often begins crystallising early, such that apatite inclusions within phenocrysts record melt volatile contents throughout magmatic differentiation. In this work, we compare the compositions of apatite inclusions and microphenocrysts with pyroxene-hosted melt inclusions from the Astroni 1 eruption of Campi Flegrei, Italy. These data are coupled with magmatic differentiation models (Gualda et al., 2012), experimental volatile solubility data (Webster et al., 2014) and thermodynamic models of apatite compositional variations (Piccoli and Candela, 1994) to determine a time-series of magmatic volatile evolution in the build-up to eruption. We find that apatite halogen/OH ratios decreased through magmatic differentiation, while melt inclusion F and Cl concentrations increased. Melt inclusion H2O contents are constant at ~2.5 wt%. These data are best explained by volatile-undersaturated differentiation over most of the crystallisation history of the Astroni 1 melt, with melt inclusion H2O contents reset during ascent, due to rapid H diffusion through the phenocryst hosts (Woods et al., 2000). Given the rapid diffusivity of volatiles in apatite (Brenan, 1993), preservation of undersaturated compositions in microphenocrysts suggests that saturation was only achieved a few days to months before eruption and that it may have been the transition into a volatile-saturated state that ultimately triggered eruption. Piccoli and Candela, 1994. Am. J. of Sc., 294, 92-135. Gualda et al., 2012

Atmospheric pressure reaction cell for operando sum frequency generation spectroscopy of ultrahigh vacuum grown model catalysts

NASA Astrophysics Data System (ADS)

Roiaz, Matteo; Pramhaas, Verena; Li, Xia; Rameshan, Christoph; Rupprechter, Günther

2018-04-01

A new custom-designed ultrahigh vacuum (UHV) chamber coupled to a UHV and atmospheric-pressure-compatible spectroscopic and catalytic reaction cell is described, which allows us to perform IR-vis sum frequency generation (SFG) vibrational spectroscopy during catalytic (kinetic) measurements. SFG spectroscopy is an exceptional tool to study vibrational properties of surface adsorbates under operando conditions, close to those of technical catalysis. This versatile setup allows performing surface science, SFG spectroscopy, catalysis, and electrochemical investigations on model systems, including single crystals, thin films, and deposited metal nanoparticles, under well-controlled conditions of gas composition, pressure, temperature, and potential. The UHV chamber enables us to prepare the model catalysts and to analyze their surface structure and composition by low energy electron diffraction and Auger electron spectroscopy, respectively. Thereafter, a sample transfer mechanism moves samples under UHV to the spectroscopic cell, avoiding air exposure. In the catalytic cell, SFG spectroscopy and catalytic tests (reactant/product analysis by mass spectrometry or gas chromatography) are performed simultaneously. A dedicated sample manipulation stage allows the model catalysts to be examined from LN2 temperature to 1273 K, with gaseous reactants in a pressure range from UHV to atmospheric. For post-reaction analysis, the SFG cell is rapidly evacuated and samples are transferred back to the UHV chamber. The capabilities of this new setup are demonstrated by benchmark results of CO adsorption on Pt and Pd(111) single crystal surfaces and of CO adsorption and oxidation on a ZrO2 supported Pt nanoparticle model catalyst grown by atomic layer deposition.

Ultrahigh Temperature Capacitive Pressure Sensor

NASA Technical Reports Server (NTRS)

Harsh, Kevin

2014-01-01

Robust, miniaturized sensing systems are needed to improve performance, increase efficiency, and track system health status and failure modes of advanced propulsion systems. Because microsensors must operate in extremely harsh environments, there are many technical challenges involved in developing reliable systems. In addition to high temperatures and pressures, sensing systems are exposed to oxidation, corrosion, thermal shock, fatigue, fouling, and abrasive wear. In these harsh conditions, sensors must be able to withstand high flow rates, vibration, jet fuel, and exhaust. In order for existing and future aeropropulsion turbine engines to improve safety and reduce cost and emissions while controlling engine instabilities, more accurate and complete sensor information is necessary. High-temperature (300 to 1,350 C) capacitive pressure sensors are of particular interest due to their high measurement bandwidth and inherent suitability for wireless readout schemes. The objective of this project is to develop a capacitive pressure sensor based on silicon carbon nitride (SiCN), a new class of high-temperature ceramic materials, which possesses excellent mechanical and electric properties at temperatures up to 1,600 C.

Rapid and quantitative determination of 10 major active components in Lonicera japonica Thunb. by ultrahigh pressure extraction-HPLC/DAD

NASA Astrophysics Data System (ADS)

Fan, Li; Lin, Changhu; Duan, Wenjuan; Wang, Xiao; Liu, Jianhua; Liu, Feng

2015-01-01

An ultrahigh pressure extraction (UPE)-high performance liquid chromatography (HPLC)/diode array detector (DAD) method was established to evaluate the quality of Lonicera japonica Thunb. Ten active components, including neochlorogenic acid, chlorogenic acid, 4-dicaffeoylquinic acid, caffeic acid, rutin, luteoloside, isochlorogenic acid B, isochlorogenic acid A, isochlorogenic acid C, and quercetin, were qualitatively evaluated and quantitatively determined. Scanning electron microscope images elucidated the bud surface microstructure and extraction mechanism. The optimal extraction conditions of the UPE were 60% methanol solution, 400 MPa of extraction pressure, 3 min of extraction time, and 1:30 (g/mL) solid:liquid ratio. Under the optimized conditions, the total extraction yield of 10 active components was 57.62 mg/g. All the components showed good linearity (r2 ≥ 0.9994) and recoveries. This method was successfully applied to quantify 10 components in 22 batches of L. japonica samples from different areas. Compared with heat reflux extraction and ultrasonic-assisted extraction, UPE can be considered as an alternative extraction technique for fast extraction of active ingredient from L. japonica.

Extrapolation of bulk rock elastic moduli of different rock types to high pressure conditions and comparison with texture-derived elastic moduli

NASA Astrophysics Data System (ADS)

Ullemeyer, Klaus; Lokajíček, Tomás; Vasin, Roman N.; Keppler, Ruth; Behrmann, Jan H.

2018-02-01

In this study elastic moduli of three different rock types of simple (calcite marble) and more complex (amphibolite, micaschist) mineralogical compositions were determined by modeling of elastic moduli using texture (crystallographic preferred orientation; CPO) data, experimental investigation and extrapolation. 3D models were calculated using single crystal elastic moduli, and CPO measured using time-of-flight neutron diffraction at the SKAT diffractometer in Dubna (Russia) and subsequently analyzed using Rietveld Texture Analysis. To define extrinsic factors influencing elastic behaviour, P-wave and S-wave velocity anisotropies were experimentally determined at 200, 400 and 600 MPa confining pressure. Functions describing variations of the elastic moduli with confining pressure were then used to predict elastic properties at 1000 MPa, revealing anisotropies in a supposedly crack-free medium. In the calcite marble elastic anisotropy is dominated by the CPO. Velocities continuously increase, while anisotropies decrease from measured, over extrapolated to CPO derived data. Differences in velocity patterns with sample orientation suggest that the foliation forms an important mechanical anisotropy. The amphibolite sample shows similar magnitudes of extrapolated and CPO derived velocities, however the pattern of CPO derived velocity is closer to that measured at 200 MPa. Anisotropy decreases from the extrapolated to the CPO derived data. In the micaschist, velocities are higher and anisotropies are lower in the extrapolated data, in comparison to the data from measurements at lower pressures. Generally our results show that predictions for the elastic behavior of rocks at great depths are possible based on experimental data and those computed from CPO. The elastic properties of the lower crust can, thus, be characterized with an improved degree of confidence using extrapolations. Anisotropically distributed spherical micro-pores are likely to be preserved, affecting

Diapir versus along-channel ascent of crustal material during plate convergence: constrained by the thermal structure of subduction zones

NASA Astrophysics Data System (ADS)

Liu, M. Q.; Li, Z. H.

2017-12-01

Crustal rocks can be subducted to mantle depths, interact with the mantle wedge, and then exhume to the crustal depth again, which is generally considered as the mechanism for the formation of ultrahigh-pressure metamorphic rocks in nature. The crustal rocks undergo dehydration and melting at subarc depths, giving rise to fluids that metasomatize and weaken the overlying mantle wedge. There are generally two ways for the material ascent from subarc depths: one is along subduction channel; the other is through the mantle wedge by diapir. In order to study the conditions and dynamics of these contrasting material ascent modes, systematic petrological-thermo-mechanical numerical models are constructed with variable thicknesses of the overriding and subducting continental plates, ages of the subducting oceanic plate, as well as the plate convergence rates. The model results suggest that the thermal structures of subduction zones control the thermal condition and fluid/melt activity at the slab-mantle interface in subcontinental subduction channels, which further strongly affect the material transportation and ascent mode. Thick overriding continental plate and low-angle subduction style induced by young subducting oceanic plate both contribute to the formation of relatively cold subduction channels with strong overriding mantle wedge, where the along-channel exhumation occurs exclusively to result in the exhumation of HP-UHP metamorphic rocks. In contrast, thin overriding lithosphere and steep subduction style induced by old subducting oceanic plate are the favorable conditions for hot subduction channels, which lead to significant hydration and metasomatism, melting and weakening of the overriding mantle wedge and thus cause the ascent of mantle wedge-derived melts by diapir through the mantle wedge. This may corresponds to the origination of continental arc volcanism from mafic to ultramafic metasomatites in the bottom of the mantle wedge. In addition, the plate

Formation and modification of chromitites in the mantle

NASA Astrophysics Data System (ADS)

Arai, Shoji; Miura, Makoto

2016-11-01

Podiform chromitites have long supplied us with unrivaled information on various mantle processes, including the peridotite-magma reaction, deep-seated magmatic evolution, and mantle dynamics. The recent discovery of ultrahigh-pressure (UHP) chromitites not only sheds light on a different aspect of podiform chromitites, but also changes our understanding of the whole picture of podiform chromitite genesis. In addition, new evidence was recently presented for hydrothermal modification/formation chromite/chromitite in the mantle, which is a classical but innovative issue. In this context, we present here an urgently needed comprehensive review of podiform chromitites in the upper mantle. Wall-rock control on podiform chromitite genesis demonstrates that the peridotite-magma reaction at the upper mantle condition is an indispensable process. We may need a large system in the mantle, far larger than the size of outcrops or mining areas, to fulfill the Cr budget requirement for podiform chromitite genesis. The peridotite-magma reaction over a large area may form a melt enriched with Na and other incompatible elements, which mixes with a less evolved magma supplied from the depth to create chromite-oversaturated magma. The incompatible-element-rich magma trapped by the chromite mainly precipitates pargasite and aspidolite (Na analogue of phlogopite), which are stable under upper mantle conditions. Moderately depleted harzburgites, which contain chromite with a moderate Cr# (0.4-0.6) and a small amount of clinopyroxene, are the best reactants for the chromitite-forming reaction, and are the best hosts for podiform chromitites. Arc-type chromitites are dominant in ophiolites, but some are of the mid-ocean ridge type; chromitites may be common beneath the ocean floor, although it has not yet been explored for chromitite. The low-pressure (upper mantle) igneous chromitites were conveyed through mantle convection or subduction down to the mantle transition zone to form

Repeatability of gradient ultrahigh pressure liquid chromatography-tandem mass spectrometry methods in instrument-controlled thermal environments.

PubMed

Grinias, James P; Wong, Jenny-Marie T; Kennedy, Robert T

2016-08-26

The impact of viscous friction on eluent temperature and column efficiency in liquid chromatography is of renewed interest as the need for pressures exceeding 1000bar to use with columns packed with sub-2μm particles has grown. One way the development of axial and radial temperature gradients that arise due to viscous friction can be affected is by the thermal environment the column is placed in. In this study, a new column oven integrated into an ultrahigh pressure liquid chromatograph that enables both still-air and forced-air operating modes is investigated to find the magnitude of the effect of the axial thermal gradient that forms in 2.1×100mm columns packed with sub-2μm particles in these modes. Temperature increases of nearly 30K were observed when the generated power of the column exceeded 25W/m. The impact of the heating due to viscous friction on the repeatability of peak capacity, elution time, and peak area ratio to an internal standard for a gradient UHPLC-MS/MS method to analyze neurotransmitters was found to be limited. This result indicates that high speed UHPLC-MS/MS gradient methods under conditions of high viscous friction may be possible without the negative effects typically observed with isocratic separations under similar conditions. Copyright © 2016 Elsevier B.V. All rights reserved.

Theoretical Analysis of Pore Pressure Diffusion in Some Basic Rock Mechanics Experiments

NASA Astrophysics Data System (ADS)

Braun, Philipp; Ghabezloo, Siavash; Delage, Pierre; Sulem, Jean; Conil, Nathalie

2018-05-01

Non-homogeneity of the pore pressure field in a specimen is an issue for characterization of the thermo-poromechanical behaviour of low-permeability geomaterials, as in the case of the Callovo-Oxfordian claystone ( k < 10-20 m2), a possible host rock for deep radioactive waste disposal in France. In tests with drained boundary conditions, excess pore pressure can result in significant errors in the measurement of material parameters. Analytical solutions are presented for the change in time of the pore pressure field in a specimen submitted to various loading paths and different rates. The pore pressure field in mechanical and thermal undrained tests is simulated with a 1D finite difference model taking into account the dead volume of the drainage system of the triaxial cell connected to the specimen. These solutions provide a simple and efficient tool for the estimation of the conditions that must hold for reliable determination of material parameters and for optimization of various test conditions to minimize the experimental duration, while keeping the measurement errors at an acceptable level.

Modeling Rock Alteration at the Water-Rock Interface of Icy Moons

NASA Astrophysics Data System (ADS)

Semprich, J.; Treiman, A. H.; Schwenzer, S. P.

2018-05-01

Alteration phases of a CM rock core are modeled with variations in fluid composition at the water-rock interface of icy moons. In the presence of H2O, CO2, CH4, and H2 serpentinization of the rock core is very likely at low pressures and 200–400 °C.

Successful Cleaning and Study of Contamination of Si(001) in Ultrahigh Vacuum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gheorghe, N. G.; Lungu, G. A.; Husanu, M. A.

2011-10-03

This paper presents the very first surface physics experiment performed in ultrahigh vacuum (UHV) in Romania, using a new molecular beam epitaxy (MBE) installation. Cleaning of a Si(001) wafer was achieved by using a very simple technique: sequences of annealing at 900-1000 deg. C in ultrahigh vacuum: low 10{sup -8} mbar, with a base pressure of 1.5x10{sup -10} mbar. The preparation procedure is quite reproducible and allows repeated cleaning of the Si(001) after contamination in ultrahigh vacuum. The Si(001) single crystal surface is characterized by low energy electron diffraction (LEED), reflection high energy electron diffraction (RHEED), and Auger electron spectroscopymore » (AES). The latter technique is utilized in order to investigate the sample contamination by the residual gas in the UHV chamber, as determined by a residual gas analyzer (RGA). Unambiguous assignment of oxidized and unoxidized silicon is provided; also, an important feature is that the LVV Auger peak at 90-92 eV cannot be solely attributed to clean Si (i.e. Si surrounded only by Si), but also to silicon atoms bounded with carbon. Even with a sum of partial pressures of oxygen and carbon containing molecules in the range of 5x10{sup -10} mbar, the sample is contaminated very quickly, having a (1/e) lifetime of about 76 minutes.« less

Ultrahigh pressure superconductivity in molybdenum disulfide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chi, Zhenhua; Yen, Feihsiang; Peng, Feng

2015-03-18

Superconductivity commonly appears under pressure in charge densit wave (CDW)-bearing transition metal dichalcogenides (TMDs) 1,2, but ha emerged so far only via either intercalation with electron donors 3 or electrostati doping 4 in CDW-free TMDs. Theoretical calculations have predicted that th latter should be metallized through bandgap closure under pressure 5,6, bu superconductivity remained elusive in pristine 2H-MoS 2 upon substantia compression, where a pressure of up to 60 GPa only evidenced the metalli state 7,8. Here we report the emergence of superconductivity in pristine 2H-MoS at 90 GPa. The maximum onset transition temperature T c (onset) of 11.5 K,more » th highest value among TMDs and nearly constant from 120 up to 200 GPa, is wel above that obtained by chemical doping3 but comparable to that obtained b electrostatic doping4. T c (onset) is more than an order of magnitude larger tha present theoretical expectations, raising questions on either the curren calculation methodologies or the mechanism of the pressure-induced pairin state. Lastly, our findings strongly suggest further experimental and theoretical effort directed toward the study of the pressure-induced superconductivity in all CDWfre TMDs.« less

Small-volume, ultrahigh-vacuum-compatible high-pressure reaction cell for combined kinetic and in situ IR spectroscopic measurements on planar model catalysts

NASA Astrophysics Data System (ADS)

Zhao, Z.; Diemant, T.; Häring, T.; Rauscher, H.; Behm, R. J.

2005-12-01

We describe the design and performance of a high-pressure reaction cell for simultaneous kinetic and in situ infrared reflection (IR) spectroscopic measurements on model catalysts at elevated pressures, between 10-3 and 103mbars, which can be operated both as batch reactor and as flow reactor with defined gas flow. The cell is attached to an ultrahigh-vacuum (UHV) system, which is used for sample preparation and also contains facilities for sample characterization. Specific for this design is the combination of a small cell volume, which allows kinetic measurements with high sensitivity under batch or continuous flow conditions, the complete isolation of the cell from the UHV part during UHV measurements, continuous temperature control during both UHV and high-pressure operation, and rapid transfer between UHV and high-pressure stage. Gas dosing is performed by a designed gas-handling system, which allows operation as flow reactor with calibrated gas flows at adjustable pressures. To study the kinetics of reactions on the model catalysts, a quadrupole mass spectrometer is connected to the high-pressure cell. IR measurements are possible in situ by polarization-modulation infrared reflection-absorption spectroscopy, which also allows measurements at elevated pressures. The performance of the setup is demonstrated by test measurements on the kinetics for CO oxidation and the CO adsorption on a Au /TiO2/Ru(0001) model catalyst film at 1-50 mbar total pressure.

Ultrahigh vacuum process for the deposition of nanotubes and nanowires

DOEpatents

Das, Biswajit; Lee, Myung B

2015-02-03

A system and method A method of growing an elongate nanoelement from a growth surface includes: a) cleaning a growth surface on a base element; b) providing an ultrahigh vacuum reaction environment over the cleaned growth surface; c) generating a reactive gas of an atomic material to be used in forming the nanoelement; d) projecting a stream of the reactive gas at the growth surface within the reactive environment while maintaining a vacuum of at most 1.times.10.sup.-4 Pascal; e) growing the elongate nanoelement from the growth surface within the environment while maintaining the pressure of step c); f) after a desired length of nanoelement is attained within the environment, stopping direction of reactive gas into the environment; and g) returning the environment to an ultrahigh vacuum condition.

Enticed by the punschrulle: Preliminary investigation of the Seve Nappe Complex's incorporation into the Scandinavian Caledonides via 'vacuum-cleaner' exhumation.

NASA Astrophysics Data System (ADS)

Barnes, Chris; Majka, Jaroslaw; Schneider, David; Bukala, Michal; Walczak, Katarzyna

2017-04-01

Recent discoveries of ultra-high pressure (UHP) metamorphism in the Seve Nappe Complex (SNC) of the Scandinavian Caledonides provide the basis for new investigations into the subduction - exhumation dynamics of the Baltoscandian margin during Caledonian tectonism. Specifically, exhumation of (U)HP complexes during subduction remains enigmatic. The recently proposed 'vacuum-cleaner' model details a method of exhumation for the SNC driven by conditions of underpressure within the subduction channel. This model, however, still requires extensive testing. Metasedimentary rocks hosting eclogite boudins of the SNC in Norrbotten, Sweden, preserve both metre-scale folding and a pervasive foliation which were developed during exhumation, as purposed by previous studies. Thus, the SNC host-rock offers an excellent region to test the vacuum-cleaner exhumation model. Preliminary investigation of the host-rock reveals a regional mineral assemblage of Qz + Ms + Grt + Bt + Ksp + Pl + Czo + Aln + Ttn (+ Tur + St). Garnet inclusions (Qz + Rt + Ms) are interpreted to represent the peak pressure assemblage. Chemical profiles of Grt show homogenization of the cores with thin retrogressive rims. Homogenization of Grt requires temperatures >700°C, interpreted to represent peak temperature conditions. Field observations of exhumation-related folds uncovered an axial-planar alignment of mica within the fold hinges, and an abundance of Aln and Czo requires upper-greenschist to lower-amphibolite facies conditions and presence of fluids. The current host-rock mineral assemblage is representative of retrogressive metamorphism at <550-600°C contemporaneous with deformation. Microstructures of the metasedimentary rocks are variable and strongly correlated with competency of the rock. Competent domains abundant in e.g. Qz, Grt, Czo, Ksp etc. exhibit coarse-grained subgrain and bulging-grain recrystallized Qz and development of micrometer-scale shear bands. Less competent domains, dominated by

Ultra-High Pressure Homogenization enhances physicochemical properties of soy protein isolate-stabilized emulsions.

PubMed

Fernández-Ávila, C; Escriu, R; Trujillo, A J

2015-09-01

The effect of Ultra-High Pressure Homogenization (UHPH, 100-300MPa) on the physicochemical properties of oil-in-water emulsions prepared with 4.0% (w/v) of soy protein isolate (SPI) and soybean oil (10 and 20%, v/v) was studied and compared to emulsions treated by conventional homogenization (CH, 15MPa). CH emulsions were prepared with non-heated and heated (95°C for 15min) SPI dispersions. Emulsions were characterized by particle size determination with laser diffraction, rheological properties using a rotational rheometer by applying measurements of flow curve and by transmission electron microscopy. The variation on particle size and creaming was assessed by Turbiscan® analysis, and visual observation of the emulsions was also carried out. UHPH emulsions showed much smaller d 3.2 values and greater physical stability than CH emulsions. The thermal treatment of SPI prior CH process did not improve physical stability properties. In addition, emulsions containing 20% of oil exhibited greater physical stability compared to emulsions containing 10% of oil. Particularly, UHPH emulsions treated at 100 and 200MPa with 20% of oil were the most stable due to low particle size values (d 3.2 and Span), greater viscosity and partial protein denaturation. These results address the physical stability improvement of protein isolate-stabilized emulsions by using the emerging UHPH technology. Copyright © 2015 Elsevier Ltd. All rights reserved.

Effect of confining pressure on diffusion coefficients in clay-rich, low-permeability sedimentary rocks.

PubMed

Xiang, Y; Al, T; Mazurek, M

2016-12-01

The effect of confining pressure (CP) on the diffusion of tritiated-water (HTO) and iodide (I - ) tracers through Ordovician rocks from the Michigan Basin, southwestern Ontario, Canada, and Opalinus Clay from Schlattingen, Switzerland was investigated in laboratory experiments. Four samples representing different formations and lithologies in the Michigan Basin were studied: Queenston Formation shale, Georgian Bay Formation shale, Cobourg Formation limestone and Cobourg Formation argillaceous limestone. Estimated in situ vertical stresses at the depths from which the samples were retrieved range from 12.0 to 17.4MPa (Michigan Basin) and from 21 to 23MPa (Opalinus Clay). Effective diffusion coefficients (D e ) were determined in through-diffusion experiments. With HTO tracer, applying CP resulted in decreases in D e of 12.5% for the Queenston Formation shale (CP max =12MPa), 30% for the Georgian Bay Formation shale (15MPa), 34% for the Cobourg Formation limestone (17.4MPa), 31% for the Cobourg Formation argillaceous limestone (17.4MPa) and 43-46% for the Opalinus Clay (15MPa). Decreases in D e were larger for the I - tracer: 13.8% for the Queenston shale, 42% for the Georgian Bay shale, 50% for the Cobourg Formation limestone, 55% for the Cobourg Formation argillaceous limestone and 63-68% for the Opalinus Clay. The tracer-specific nature of the response is attributed to an increasing influence of anion exclusion as the pore size decreases at higher CP. Results from the shales (including Opalinus Clay) indicate that the pressure effect on D e can be represented by a linear relationship between D e and ln(CP), which provides valuable predictive capability. The nonlinearity results in a relatively small change in D e at high CP, suggesting that it is not necessary to apply the exact in situ pressure conditions in order to obtain a good estimate of the in situ diffusion coefficient. Most importantly, the CP effect on shale is reversible (±12%) suggesting that, for

Cost-effectiveness analysis of alternative factor VIII products in treatment of haemophilia A.

PubMed

Hay, J W; Ernst, R L; Kessler, C M

1999-05-01

Manufactured factor VIII (FVIII) concentrates of varying purity are available for managing patients with haemophilia A. This study is a cost-effectiveness analysis of ultra-high purity and recombinant (UHP/R) FVIII products relative to intermediate and very-high purity (IP/VHP) preparations. Because the societal (including research and development) costs of FVIII products are unknown and product prices vary with market conditions, we conducted the analysis with treatment cost as a variable quantity. We estimated the largest price premium that could be paid for a UHP/R concentrate relative to an IP/VHP concentrate such that the UHP/R product is the more cost-effective preparation. In the analysis haemophilic patients were assumed to be seropositive for human immunodeficiency virus, seropositive for hepatitis C (HCV), or at risk for seroconversion of hepatitis A (HAV) or hepatitis B (HBV). The results showed that the maximum cost-effective UHP/R price premium is essentially zero if the patient is only at risk of HAV or HBV infection, positive but small for the base-case HCV+ patient, and positive and large for the base-case HIV+ patient having a short life expectancy. Thus UHP/R preparations are not uniformly more cost-effective than IP/VHP products across the spectrum of haemophilic patients' health problems, and the relative cost-effectiveness of the two classes of prepared FVIII products is sensitive to product prices. The methodology employed here can be used in other circumstances where multiple treatments exist for illnesses for which there are significant multiple comorbidities or health risks.

Ultra-high pressure LC for astaxanthin determination in shrimp by-products and active food packaging.

PubMed

Sanches-Silva, A; Ribeiro, T; Albuquerque, T G; Paseiro, P; Sendón, R; de Quirós, A Bernaldo; López-Cervantes, J; Sánchez-Machado, D I; Soto Valdez, H; Angulo, I; Aurrekoetxea, G P; Costa, H S

2013-06-01

Nowadays, there is increasing interest in natural antioxidants from food by-products. Astaxanthin is a potent antioxidant and one of the major carotenoids in crustaceans and salmonids. An ultra-high pressure liquid chromatographic method was developed and validated for the determination of astaxanthin in shrimp by-products, and its migration from new packaging materials to food simulants was also studied. The method uses an UPLC® BEH guard-column (2.1 × 5 mm, 1.7 µm particle size) and an UPLC® BEH analytical column (2.1 × 50 mm, 1.7 µm particle size). Chromatographic separation was achieved using a programmed gradient mobile phase consisting of (A) acetonitrile-methanol (containing 0.05 m ammonium acetate)-dichloromethane (75:20:5, v/v/v) and (B) ultrapure water. This method was evaluated with respect to validation parameters such as linearity, precision, limit of detection, limit of quantification and recovery. Low-density polyethylene films were prepared with different amounts of the lipid fraction of fermented shrimp waste by extrusion, and migration was evaluated into food simulants (isooctane and ethanol 95%, v/v). Migration was not detected under the tested conditions. Copyright © 2012 John Wiley & Sons, Ltd.

Multistage evolution of UHT granulites from the southernmost part of the Gföhl Nappe, Bohemian Massif, Lower Austria

NASA Astrophysics Data System (ADS)

Schantl, Philip; Hauzenberger, Christoph; Linner, Manfred

2016-04-01

A detailed petrological investigation has been undertaken in leucocratic kyanite-garnet bearing and mesocratic orthopyroxene bearing granulites from the Dunkelsteiner Wald, Pöchlarn-Wieselburg and Zöbing granulite bodies from the Moldanubian Zone in the Bohemian Massif (Austria). A combination of textural observations, conventional geothermobarometry, phase equilibrium modelling as well as major and trace element analyses in garnet enables us to confirm a multistage Variscan metamorphic history. Chemically homogenous garnet cores with near constant grossular-rich plateaus are considered to reflect garnet growth during an early HP/UHP metamorphic evolution. Crystallographically oriented rutile exsolutions restricted to those grossular-rich garnet cores point to a subsequent isothermal decompression of the HP/UHP rocks. Overgrowing garnet rims show a pronounced zonation and are interpreted as the result of dehydration melting reactions during an isobaric heating phase which could have taken place near the base of an overthickened continental crust, where the previously deeply subducted rocks were exhumed to. For this HP granulite facies event maximum PT conditions of ~1050 °C and 1.6 GPa have been estimated from leucocratic granulites comprising the peak mineral assemblage quartz, ternary feldspar, garnet, kyanite and rutile. The pronounced zoning of garnet rims indicates that the HP granulite facies event must have been short lived since diffusion in this temperature region is usually sufficient fast to homogenize a zoning pattern in garnet. A retrogressive metamorphic stage is documented in these rocks by the replacement of kyanite to sillimanite and the growth of biotite. This retrograde event took place within the granulite facies but at significantly lower pressures and temperatures with ~0.8 GPa and ~760 °C. This final stage of re-equilibration is thought to be linked with a second exhumation phase into middle crustal levels accompanied by intensive

Ultra-high speed vacuum pump system with first stage turbofan and second stage turbomolecular pump

DOEpatents

Jostlein, Hans

2006-04-04

An ultra-high speed vacuum pump evacuation system includes a first stage ultra-high speed turbofan and a second stage conventional turbomolecular pump. The turbofan is either connected in series to a chamber to be evacuated, or is optionally disposed entirely within the chamber. The turbofan employs large diameter rotor blades operating at high linear blade velocity to impart an ultra-high pumping speed to a fluid. The second stage turbomolecular pump is fluidly connected downstream from the first stage turbofan. In operation, the first stage turbofan operates in a pre-existing vacuum, with the fluid asserting only small axial forces upon the rotor blades. The turbofan imparts a velocity to fluid particles towards an outlet at a high volume rate, but moderate compression ratio. The second stage conventional turbomolecular pump then compresses the fluid to pressures for evacuation by a roughing pump.

Influence of Pore-Fluid Pressure on Elastic Wave Velocity and Electrical Conductivity in Water-Saturated Rocks

NASA Astrophysics Data System (ADS)

Higuchi, A.; Watanabe, T.

2013-12-01

Pore-fluid pressure in seismogenic zones can play a key role in the occurrence of earthquakes (e.g., Sibson, 2009). Its evaluation via geophysical observations can lead to a good understanding of seismic activities. The evaluation requires a thorough understanding of the influence of the pore-fluid pressure on geophysical observables like seismic velocity and electrical conductivity. We have studied the influence of pore-fluid pressure on elastic wave velocity and electrical conductivity in water-saturated rocks. Fine grained (100-500μm) biotite granite (Aji, Kagawa pref., Japan) was used as rock samples. The density is 2.658-2.668 g/cm3, and the porosity 0.68-0.87%. The sample is composed of 52.8% plagioclase, 36.0% Quartz, 3.0% K-feldspar, 8.2% biotite. SEM images show that a lot of grain boundaries are open. Few intracrystalline cracks were observed. Following the method proposed by David and Zimmerman (2012), the distribution function of crack aspect ratio was evaluated from the pressure dependence of compressional and shear wave velocities in a dry sample. Cylindrical sample has dimensions of 25 mm in diameter and 30 mm in length, and saturated with 0.01 mol/l KCl aqueous solution. Compressional and shear wave velocities were measured with the pulse transmission technique (PZT transducers, f=2 MHz), and electrical conductivity the two-electrode method (Ag-AgCl electrodes, f=1 Hz-100 kHz). Simultaneous measurements of velocities and conductivity were made using a 200 MPa hydrostatic pressure vessel, in which confining and pore-fluid pressures can be separately controlled. The pore-fluid is electrically insulated from the metal work of the pressure vessel by using a newly designed plastic device (Watanabe and Higuchi, 2013). The confining pressure was progressively increased up to 25 MPa, while the pore-fluid pressure was kept at 0.1 MPa. It took five days or longer for the electrical conductivity to become stationary after increasing the confining pressure

Development of a 45kpsi ultrahigh pressure liquid chromatography instrument for gradient separations of peptides using long microcapillary columns and sub-2μm particles.

PubMed

Grinias, Kaitlin M; Godinho, Justin M; Franklin, Edward G; Stobaugh, Jordan T; Jorgenson, James W

2016-10-21

Commercial chromatographic instrumentation for bottom-up proteomics is often inadequate to resolve the number of peptides in many samples. This has inspired a number of complex approaches to increase peak capacity, including various multidimensional approaches, and reliance on advancements in mass spectrometry. One-dimensional reversed phase separations are limited by the pressure capabilities of commercial instruments and prevent the realization of greater separation power in terms of speed and resolution inherent to smaller sorbents and ultrahigh pressure liquid chromatography. Many applications with complex samples could benefit from the increased separation performance of long capillary columns packed with sub-2μm sorbents. Here, we introduce a system that operates at a constant pressure and is capable of separations at pressures up to 45kpsi. The system consists of a commercially available capillary liquid chromatography instrument, for sample management and gradient creation, and is modified with a storage loop and isolated pneumatic amplifier pump for elevated separation pressure. The system's performance is assessed with a complex peptide mixture and a range of microcapillary columns packed with sub-2μm C18 particles. Copyright © 2016 Elsevier B.V. All rights reserved.

Ultra-high vacuum compatible induction-heated rod casting furnace

NASA Astrophysics Data System (ADS)

Bauer, A.; Neubauer, A.; Münzer, W.; Regnat, A.; Benka, G.; Meven, M.; Pedersen, B.; Pfleiderer, C.

2016-06-01

We report the design of a radio-frequency induction-heated rod casting furnace that permits the preparation of polycrystalline ingots of intermetallic compounds under ultra-high vacuum compatible conditions. The central part of the system is a bespoke water-cooled Hukin crucible supporting a casting mold. Depending on the choice of the mold, typical rods have a diameter between 6 mm and 10 mm and a length up to 90 mm, suitable for single-crystal growth by means of float-zoning. The setup is all-metal sealed and may be baked out. We find that the resulting ultra-high vacuum represents an important precondition for processing compounds with high vapor pressures under a high-purity argon atmosphere up to 3 bars. Using the rod casting furnace, we succeeded to prepare large high-quality single crystals of two half-Heusler compounds, namely, the itinerant antiferromagnet CuMnSb and the half-metallic ferromagnet NiMnSb.

Ultra-high vacuum compatible induction-heated rod casting furnace.

PubMed

Bauer, A; Neubauer, A; Münzer, W; Regnat, A; Benka, G; Meven, M; Pedersen, B; Pfleiderer, C

2016-06-01

We report the design of a radio-frequency induction-heated rod casting furnace that permits the preparation of polycrystalline ingots of intermetallic compounds under ultra-high vacuum compatible conditions. The central part of the system is a bespoke water-cooled Hukin crucible supporting a casting mold. Depending on the choice of the mold, typical rods have a diameter between 6 mm and 10 mm and a length up to 90 mm, suitable for single-crystal growth by means of float-zoning. The setup is all-metal sealed and may be baked out. We find that the resulting ultra-high vacuum represents an important precondition for processing compounds with high vapor pressures under a high-purity argon atmosphere up to 3 bars. Using the rod casting furnace, we succeeded to prepare large high-quality single crystals of two half-Heusler compounds, namely, the itinerant antiferromagnet CuMnSb and the half-metallic ferromagnet NiMnSb.

Hydrogen storage properties of nanosized MgH2-0.1TiH2 prepared by ultrahigh-energy-high-pressure milling.

PubMed

Lu, Jun; Choi, Young Joon; Fang, Zhigang Zak; Sohn, Hong Yong; Rönnebro, Ewa

2009-11-04

Magnesium hydride (MgH(2)) is an attractive candidate for solid-state hydrogen storage applications. To improve the kinetics and thermodynamic properties of MgH(2) during dehydrogenation-rehydrogenation cycles, a nanostructured MgH(2)-0.1TiH(2) material system prepared by ultrahigh-energy-high-pressure mechanical milling was investigated. High-resolution transmission electron microscope (TEM) and scanning TEM analysis showed that the grain size of the milled MgH(2)-0.1TiH(2) powder is approximately 5-10 nm with uniform distributions of TiH(2) among MgH(2) particles. Pressure-composition-temperature (PCT) analysis demonstrated that both the nanosize and the addition of TiH(2) contributed to the significant improvement of the kinetics of dehydrogenation and hydrogenation compared to commercial MgH(2). More importantly, PCT cycle analysis demonstrated that the MgH(2)-0.1TiH(2) material system showed excellent cycle stability. The results also showed that the DeltaH value for the dehydrogenation of nanostructured MgH(2)-0.1TiH(2) is significantly lower than that of commercial MgH(2). However, the DeltaS value of the reaction was also lower, which results in minimum net effects of the nanosize and the addition of TiH(2) on the equilibrium pressure of dehydrogenation reaction of MgH(2).

The analysis of creep characteristics of the surrounding rock of the carbonaceous rock tunnel based on Singh-Mitchell model

NASA Astrophysics Data System (ADS)

Luo, Junhui; Mi, Decai; Ye, Qiongyao; Deng, Shengqiang; Zeng, Fuquan; Zeng, Yongjun

2018-01-01

Carbonaceous rock has the characteristics of easy disintegration, softening, swelling and environmental sensitivity, which belongs to soft surrounding rock, and the deformation during excavation and long-term stability of the surrounding rock of carbonaceous rock tunnel are common problems in the construction of carbonaceous rock tunnel. According to the above, the Monitor and measure the displacement, temperature and osmotic pressure of the surrounding carbonaceous rock of the tunnel of Guangxi Hebai highway. Then it based on the obtaining data to study the creep mechanism of surrounding rock using Singh-Mitchell model and predict the deformation of surrounding rock before the tunnel is operation. The results show that the Singh-Mitchell creep model can effectively analyse and predict the deformation development law of surrounding rock of tunnel without considering temperature and osmotic pressure, it can provide reference for the construction of carbonaceous rock tunnel and the measures to prevent and reinforce it..

Highly informative multiclass profiling of lipids by ultra-high performance liquid chromatography - Low resolution (quadrupole) mass spectrometry by using electrospray ionization and atmospheric pressure chemical ionization interfaces.

PubMed

Beccaria, Marco; Inferrera, Veronica; Rigano, Francesca; Gorynski, Krzysztof; Purcaro, Giorgia; Pawliszyn, Janusz; Dugo, Paola; Mondello, Luigi

2017-08-04

A simple, fast, and versatile method, using an ultra-high performance liquid chromatography system coupled with a low resolution (single quadrupole) mass spectrometer was optimized to perform multiclass lipid profiling of human plasma. Particular attention was made to develop a method suitable for both electrospray ionization and atmospheric pressure chemical ionization interfaces (sequentially in positive- and negative-ion mode), without any modification of the chromatographic conditions (mobile phase, flow-rate, gradient, etc.). Emphasis was given to the extrapolation of the structural information based on the fragmentation pattern obtained using atmospheric pressure chemical ionization interface, under each different ionization condition, highlighting the complementary information obtained using the electrospray ionization interface, of support for related molecule ions identification. Furthermore, mass spectra of phosphatidylserine and phosphatidylinositol obtained using the atmospheric pressure chemical ionization interface are reported and discussed for the first time. Copyright © 2017 Elsevier B.V. All rights reserved.

Control of Hydrogen Environment Embrittlement of Ultra-High Strength Steel for Naval Application

DTIC Science & Technology

2005-07-01

load cracking behavior of maraging steels in hydrogen. Corrosion , 29, 1973, 299-304. D.A. Jones, A.F. Jankowski and G.A. Davidson, "Diffusion of...short crack case. This behavior is relevant to small surface cracks in coated UHSS components such as a landing gear. IV.B. Effect of Steel Composition ...PRESSURE (k N /m 2) Figure 26. The effect of H2 pressure on the HEAC growth rate for a ultra-high strength 18Ni Maraging steel stressed in a highly

Microstructures Developed During Natural and Experimental Decompression of Peridotite From Pressures of 10-15 GPa

NASA Astrophysics Data System (ADS)

Green, H. W.; Dobrzhinetskaya, L. F.

2004-12-01

Evidence is now robust that continental rocks and sediments can be subducted to P > 6 GPa during continental collision and returned to the surface. Moreover, mantle rocks exhumed with this subducted material carry evidence of P > 9 GPa and perhaps much more. We present a short review of natural examples and discuss them in the context of decompression experiments conducted on garnet lherzolite over the range 14 -> 5 GPa. Experiments at 14 GPa dissolved all enstatite (En) and about 85% diopside (Di) into garnet, yielding run products of 40% Ol + 55% Grt + 5% Di. Re-annealing this product at 13 or 12 GPa resulted in exsolution of Di as blebs at garnet grain boundaries and oriented platelets of Ol chemistry within grt. Specimens first equilibrated at 8 GPa dissolved abundant En but little Di. When re-annealed at 5 GPa, En exsolved as blebs at garnet boundaries -- very similar to interstitial blebs of enstatite along grt grain boundaries in UHP (>200 km) Norwegian grt-harzburgite. In the latter rocks, abundant En and rare Di exsolution lamellae are also found in the cores of large garnets. Our experiments do not show such lamellae, supporting the arguments of van Roermund and Drury (1998) that they are produced only in the cores of large grains and that the interstitial pyroxenes found in their specimens are also exsolution products. Ol has not been reported with exsolution morphology in natural UHP products, nor did we observe it in our experiments at P = 5 GPa. On the other hand, our observation that Ol may be exsolved during decompression of majoritic garnet during decompression at higher P is consistent with expansion of the garnet field at the expense of wadsleyite at P > 13 GPa reported by Ringwood (1991). Di, En, and/or Ol do occur along grain boundaries within larger polycrystalline garnets and within embayments at the margins of smaller amoeboid garnets in subduction zone garnet peridotites. Such garnets also may contain rounded, non-oriented, inclusions of

Hard-rock jetting. Part 2. Rock type decides jetting economics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pols, A.C.

1977-02-07

In Part 2, Koninklijke Shell Exploratie en Produktie Laboratorium presents the results of jet-drilling laminated formations. Shell concludes that (1) hard, laminated rock cannot be jet-drilled satisfactorily without additional mechanical cutting aids, (2) the increase in penetration rate with bit-pressure drop is much lower for impermeable rock than it is for permeable rock, (3) drilling mud can have either a positive or a negative effect on penetration rate in comparison with water, depending on the material drilled, and (4) hard, isotropic, sedimentary, impermeable rock can be drilled using jets at higher rates than with conventional means. However, jetting becomes profitablemore » only in the case of expensive rigs.« less

An experimental platform for triaxial high-pressure/high-temperature testing of rocks using computed tomography

NASA Astrophysics Data System (ADS)

Glatz, Guenther; Lapene, Alexandre; Castanier, Louis M.; Kovscek, Anthony R.

2018-04-01

A conventional high-pressure/high-temperature experimental apparatus for combined geomechanical and flow-through testing of rocks is not X-ray compatible. Additionally, current X-ray transparent systems for computed tomography (CT) of cm-sized samples are limited to design temperatures below 180 °C. We describe a novel, high-temperature (>400 °C), high-pressure (>2000 psi/>13.8 MPa confining, >10 000 psi/>68.9 MPa vertical load) triaxial core holder suitable for X-ray CT scanning. The new triaxial system permits time-lapse imaging to capture the role of effective stress on fluid distribution and porous medium mechanics. System capabilities are demonstrated using ultimate compressive strength (UCS) tests of Castlegate sandstone. In this case, flooding the porous medium with a radio-opaque gas such as krypton before and after the UCS test improves the discrimination of rock features such as fractures. The results of high-temperature tests are also presented. A Uintah Basin sample of immature oil shale is heated from room temperature to 459 °C under uniaxial compression. The sample contains kerogen that pyrolyzes as temperature rises, releasing hydrocarbons. Imaging reveals the formation of stress bands as well as the evolution and connectivity of the fracture network within the sample as a function of time.

An experimental platform for triaxial high-pressure/high-temperature testing of rocks using computed tomography.

PubMed

Glatz, Guenther; Lapene, Alexandre; Castanier, Louis M; Kovscek, Anthony R

2018-04-01

A conventional high-pressure/high-temperature experimental apparatus for combined geomechanical and flow-through testing of rocks is not X-ray compatible. Additionally, current X-ray transparent systems for computed tomography (CT) of cm-sized samples are limited to design temperatures below 180 °C. We describe a novel, high-temperature (>400 °C), high-pressure (>2000 psi/>13.8 MPa confining, >10 000 psi/>68.9 MPa vertical load) triaxial core holder suitable for X-ray CT scanning. The new triaxial system permits time-lapse imaging to capture the role of effective stress on fluid distribution and porous medium mechanics. System capabilities are demonstrated using ultimate compressive strength (UCS) tests of Castlegate sandstone. In this case, flooding the porous medium with a radio-opaque gas such as krypton before and after the UCS test improves the discrimination of rock features such as fractures. The results of high-temperature tests are also presented. A Uintah Basin sample of immature oil shale is heated from room temperature to 459 °C under uniaxial compression. The sample contains kerogen that pyrolyzes as temperature rises, releasing hydrocarbons. Imaging reveals the formation of stress bands as well as the evolution and connectivity of the fracture network within the sample as a function of time.

Investigation of steady and fluctuating pressures associated with the transonic buffeting and wing rock of a one-seventh scale model of the F-5A aircraft

NASA Technical Reports Server (NTRS)

Hwang, C.; Pi, W. S.

1978-01-01

A wind tunnel test of a 1/7 scale F-5A model is described. The pressure, force, and dynamic response measurements during buffet and wing rock are evaluated. Effects of Mach number, angle of attack, sideslip angle, and control surface settings were investigated. The mean and fluctuating static pressure data are presented and correlated with some corresponding flight test data of a F-5A aircraft. Details of the instrumentation and the specially designed support system which allowed the model to oscillate in roll to simulate wing rock are also described. A limit cycle mechanism causing wing rock was identified from this study, and this mechanism is presented.

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnis Judzis; Alan Black; Homer Robertson

2006-03-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energymore » and loads. The significance of the ultra-high rotary speed drilling system is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 October 2004 through 30 September 2005. Additionally, research activity from 1 October 2005 through 28 February 2006 is included in this report: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance. (2) TerraTek designed and planned Phase I bench scale experiments. Some difficulties continue in obtaining ultra-high speed motors. Improvements have been made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs have been provided to vendors for production. A more consistent product is required to minimize the differences in bit performance. A test matrix for the final core bit testing program

Ultra-high speed visualization of the flashing instability under vacuum conditions

NASA Astrophysics Data System (ADS)

Hernández Sánchez, Jose Federico; Al-Ghamdi, Tariq; Thoroddsen, Sigurdur T.

2017-11-01

We investigated experimentally the flashing instability of a jet of perfluoro-n-hexane (PFnH) released into a low-pressure environment. Using a ultra-high speed camera we observed the jet fragmentation occurring close to the nozzle. Using a fixed total driving pressure, we decreased systematically the vacuum pressure, investigating the transition from a laminar jet to a fully flashing jet. Our high temporal resolution allowed to visualize the detailed dynamics of external flash-boiling for the first time. We identified different mechanisms of jet break-up. At chamber pressures lower than the vapor pressure the laminar jet evolves to a meandering stream. In this stage, bubbles start to nucleate and violently expand upstream the nozzle. At lower vacuum pressures the initially cylindrical jet elongates, forming a liquid sheet that breaks in branches and later in drops. At very low pressures both mechanisms are responsible for the jet breaking. We calculated the size distribution of the ejected droplets, their individual trajectories, velocities as well as the spray angle as a function of the dimensionless vacuum pressure.

Diapir versus along-channel ascent of crustal material during plate convergence: Constrained by the thermal structure of subduction zones

NASA Astrophysics Data System (ADS)

Liu, Ming-Qi; Li, Zhong-Hai; Yang, Shao-Hua

2017-09-01

Subduction channel processes are crucial for understanding the material and energy exchange between the Earth's crust and mantle. Crustal rocks can be subducted to mantle depths, interact with the mantle wedge, and then exhume to the crustal depth again, which is generally considered as the mechanism for the formation of ultrahigh-pressure metamorphic rocks in nature. In addition, the crustal rocks generally undergo dehydration and melting at subarc depths, giving rise to fluids that metasomatize and weaken the overlying mantle wedge. There are generally two ways for the material ascent from subarc depths: one is along subduction channels; the other is through the mantle wedge by diapir. In order to study the conditions and dynamics of these contrasting material ascent modes, systematic petrological-thermo-mechanical numerical models are constructed with variable thicknesses of the overriding and subducting continental plates, ages of the subducting oceanic plate, as well as the plate convergence rates. The model results suggest that the thermal structures of subduction zones control the thermal condition and fluid/melt activity at the slab-mantle interface in subcontinental subduction channels, which further strongly affect the material transportation and ascent mode. The thick overriding continental plate and the low-angle subduction style induced by young subducting oceanic plate both contribute to the formation of relatively cold subduction channels with strong overriding mantle wedge, where the along-channel exhumation occurs exclusively to result in the exhumation of HP-UHP metamorphic rocks. In contrast, the thin overriding lithosphere and the steep subduction style induced by old subducting oceanic plate are the favorable conditions for hot subduction channels, which lead to significant hydration and metasomatism, melting and weakening of the overriding mantle wedge and thus cause the ascent of mantle wedge-derived melts by diapir through the mantle wedge

Exhumation rates of high pressure metamorphic rocks in subduction channels: The effect of Rheology

NASA Astrophysics Data System (ADS)

Gerya, T. V.; Stöckhert, B.

2002-04-01

Exhumation of high-pressure metamorphic rocks can take place with typical plate velocities of cm/year. This is consistent with a model of forced flow in a subduction channel. The (micro)structural record of exhumed metamorphic rocks indicates that stresses are generally too low to drive deformation of the bulk material by dislocation creep, according to a power-law rheology. Instead deformation appears to be localized in low-strength shear zones, and is dominated by dissolution precipitation creep or fluid assisted granular flow, implying a Newtonian rheology. 1D modeling shows that the effective rheology of the material in the subduction channel has a significant influence on the rate of exhumation. When the subduction flux either equals or exceeds the return flux, the maximum exhumation rate for Newtonian behavior of the material is at least twice as high (~1/3 of the subduction burial rate) compared to that for power-law creep (~1/6 of the subduction burial rate).

Magnetic interactions in NiO at ultrahigh pressure

DOE PAGES

Potapkin, Vasily; Dubrovinsky, Leonid; Sergueev, I.; ...

2016-05-24

Here, magnetic properties of NiO have been studied in the multimegabar pressure range by nuclear forward scattering of synchrotron radiation using the 67.4 keV M ssbauer transition of 61Ni. The observed magnetic hyperfine splitting confirms the antiferromagnetic state of NiO up to 280 GPa, the highest pressure where magnetism has been observed so far, in any material. Remarkably, the hyperfine field increases from 8.47 T at ambient pressure to ~24 T at the highest pressure, ruling out the possibility of a magnetic collapse. A joint x-ray diffraction and extended x-ray-absorption fine structure investigation reveals that NiO remains in a distortedmore » sodium chloride structure in the entire studied pressure range. Ab initio calculations support the experimental observations, and further indicate a complete absence of Mott transition in NiO up to at least 280 GPa.« less

Quantifying rock mass strength degradation in coastal rock cliffs

NASA Astrophysics Data System (ADS)

Brain, Matthew; Lim, Michael; Rosser, Nick; Petley, David; Norman, Emma; Barlow, John

2010-05-01

Although rock cliffs are generally perceived to evolve through undercutting and cantilever collapse of material, the recent application of high-resolution three-dimensional monitoring techniques has suggested that the volumetric losses recorded from layers above the intertidal zone produce an equally significant contribution to cliff behaviour. It is therefore important to understand the controls on rockfalls in such layers. Here we investigate the progressive influence of subaerial exposure and weathering on the geotechnical properties of the rocks encountered within the geologically complex coastal cliffs of the northeast coast of England, UK. Through a program of continuous in situ monitoring of local environmental and tidal conditions and laboratory rock strength testing, we aim to better quantify the relationships between environmental processes and the geotechnical response of the cliff materials. We have cut fresh (not previously exposed) samples from the three main rock types (sandstone, mudstone and shale) found within the cliff to uniform size, shape and volume, thus minimizing variability and removing previous surface weathering effects. In order to characterise the intact strength of the rocks, we have undertaken unconfined compressive strength and triaxial strength tests using high pressure (400 kN maximum axial load; 64 MPa maximum cell pressure) triaxial testing apparatus. The results outline the peak strength characteristics of the unweathered materials. We then divided the samples of each lithology into different experimental groups. The first set of samples remained in the laboratory at constant temperature and humidity; this group provides our control. Samples from each of the three rock types were located at heights on the cliff face corresponding with the different lithologies: at the base (mudstone), in the mid cliff (shale) and at the top of the cliff (sandstone). This subjected them to the same conditions experienced by the in situ cliff

Magnetic properties and anomalies related to eclogite- and high-pressure granulite-facies mafic rocks: What do they tell about magnetization of deep-crustal lithosphere?

NASA Astrophysics Data System (ADS)

McEnroe, S. A.; Robinson, P.

2012-12-01

The magnetic response of crustal rocks is directly related to type and abundance of oxides in the rock bodies. About 800 samples from mafic bodies and mantle peridotites from the eclogite-facies part of the Western Gneiss Region, Norway, were studied for magnetic properties and oxide mineralogy, and show strong variations. Many eclogites are paramagnetic, while adjacent gabbros from which the eclogites were derived during high-pressure (HP) recrystallization, either preserved or formed magnetite during HP metamorphism or during the following exhumation. Phase petrology indicates many of these rocks were subjected to 4 Gpa and possibly to 6 Gpa equivalent to depths of 125 and 200 km during the Scandian (Upper Silurian - Lower Devonian) continental subduction. Likely conditions in intermediate stages of exhumation were temperature (T) > 700C and pressure (P) of 1 GPa. When magnetite dominates in these samples, the primary control on magnetization is abundance, because magnetite in coarse-grained igneous and high-grade metamorphic rocks is commonly of multi-domain size, close to end-member, and with few microstructures. With few features to stabilize the NRM, the magnetic response is dominated by induced magnetization (Ji). When exsolved members of the rhombohedral ilmenite-hematite solid solution are present, commonly in more oxidized rocks, the response is dominated by the NRM (Jr), and NRM intensity is more complicated than in magnetite-bearing rocks. Important here, in addition to the amount of oxide, are the orientation of the oxide grains relative to the magnetizing field, and the amount of exsolution lamellae, mostly produced during cooling from HP conditions, leading to lamellar magnetism. Where there is no coexisting magnetite, these rocks have high Q values (Jr/Ji) because the induced magnetization (Ji) is low. For such more oxidized rocks, remanent anomalies are generally more common than for more reduced magnetite-bearing rocks formed under the same

Felsic granulite with layers of eclogite facies rocks in the Bohemian Massif; did they share a common metamorphic history?

NASA Astrophysics Data System (ADS)

Jedlicka, Radim; Faryad, Shah Wali

2017-08-01

High pressure granulite and granulite gneiss from the Rychleby Mountains in the East Sudetes form an approximately 7 km long and 0.8 km wide body, which is enclosed by amphibolite facies orthogneiss with a steep foliation. Well preserved felsic granulite is located in the central part of the body, where several small bodies of mafic granulite are also present. In comparison to other high pressure granulites in the Bohemian Massif, which show strong mineral and textural re-equilibration under granulite facies conditions, the mafic granulite samples preserve eclogite facies minerals (garnet, omphacite, kyanite, rutile and phengite) and their field and textural relations indicate that both mafic and felsic granulites shared common metamorphic history during prograde eclogite facies and subsequent granulite facies events. Garnet from both granulite varieties shows prograde compositional zoning and contains inclusions of phengite. Yttrium and REEs in garnet show typical bell-shaped distributions with no annular peaks near the grain rims. Investigation of major and trace elements zoning, including REEs distribution in garnet, was combined with thermodynamic modelling to constrain the early eclogite facies metamorphism and to estimate pressure-temperature conditions of the subsequent granulite facies overprint. The first (U)HP metamorphism occurred along a low geothermal gradient in a subduction-related environment from its initial stage at 0.8 GPa/460 °C and reached pressures up to 2.5 GPa at 550 °C. The subsequent granulite facies overprint (1.6-1.8 GPa/800-880 °C) affected the rocks only partially; by replacement of omphacite into diopside + plagioclase symplectite and by compositional modification of garnet rims. The mineral textures and the preservation of the eclogite facies prograde compositional zoning in garnet cores confirm that the granulite facies overprint was either too short or too faint to cause recrystallisation and homogenisation of the eclogite

The lower-temperature-pressure stability of pyrope in the presence of quartz in the system MgO-Al2O3-SiO2

NASA Astrophysics Data System (ADS)

Cheng, N.; Jenkins, D. M.

2017-12-01

Pyrope (Mg3Al2Si3O12) is the dominant component in garnets from type A eclogites. Determining the lower-pressure-temperature (P-T) stability of pyrope in the presence of quartz helps put constraints on the stability of quartz-bearing eclogites and therefore the depths to which crustal rocks in high pressure/ultra-high pressure (HP/UHP) terranes can be transferred. It also defines the lower-pressure stability of the nearly pure pyrope-bearing quartzites of the Dora Maira massif of the Western Alps (Chopin, 1984, Contrib. Min. Pet.). Aside from the approximate boundary proposed by Hensen & Essene (1971, Contrib. Min. Pet.), there has been no detailed study of the lower P-T stability of pyrope + quartz. A reversed determination of the reaction 3 enstatite + 2 kyanite = 2 pyrope + 2 quartz has been done in the system MgO-Al2O3-SiO2 over the P-T range of 900-1100 °C and 1.6-2.5 GPa for durations of 24 hours. Double capsules, one using pure enstatite and the other Al-rich (10 wt% Al2O3) enstatite in the starting mixtures, were used to obtain reversals on the Al content in the orthopyroxene (Opx). Experiments were done using a ½-inch diameter piston-cylinder press and NaCl-pyrex-MgO pressure media. Run products were analyzed using powder XRD and electron microprobe. Reaction direction was readily determined from peak height changes on XRD patterns. The reaction has been bracketed at 1.65 GPa at 1100 °C with > 12 wt% Al2O3 in Opx; 2.05 GPa at 1000 °C with 10 wt% Al2O3 in Opx; and 2.4 GPa at 930 °C with 5 wt% Al2O3 in Opx. The reaction boundary is slightly curved to higher P with increasing T caused by increasing Al in Opx. The boundary observed in this study is about 100 °C or 0.4 GPa higher than previously proposed by Hensen & Essene (1971) and 70-170 °C or 0.6-0.7 GPa higher than the boundary calculated in this system using THERMOCALC ds6.22 (Holland & Powell, 2011, J. Meta. Geol.) and about 1-4 wt% higher Al2O3 contents in Opx. Higher pressure runs in the field

Measurements of unjacketed moduli of porous rock

NASA Astrophysics Data System (ADS)

Tarokh, A.; Makhnenko, R. Y.; Labuz, J.

2017-12-01

Coupling of stress and pore pressure appears in a number of applications dealing with subsurface (sedimentary) rock, including petroleum exploration and waste storage. Poroelastic analyses consider the compressibility of the solid constituents forming the rock, and often times solid bulk modulus Ks is assumed to be the same as the dominant mineral bulk modulus. In fact, there are two different parameters describing solid compressibility of a porous rock: the unjacketed bulk modulus Ks' and the unjacketed pore modulus Ks". Experimental techniques are developed to measure the two poroelastic parameters of fluid-saturated porous rock under the unjacketed condition. In an unjacketed experiment, the rock without a membrane is loaded by the fluid in a pressure vessel. The confining fluid permeates the connected pore space throughout the interior of the rock. Therefore, changes in mean stress P will produce equal changes in pore pressure p, i.e. ΔP = Δp. The test can also be performed with a jacketed rock specimen by applying equal increments of mean stress and pore pressure. The unjacketed bulk modulus, Ks', is obtained by measuring the bulk strain with resistive strain gages. The unjacketed pore modulus, Ks", the pore volume counterpart to Ks', is a measure of the change in pore pressure per unit pore volume strain under the unjacketed condition. Several indirect estimates of Ks" have been reported but limitations of these approaches do not provide an accurate value. We present direct measurements of Ks" with detailed calibration on the system volumetric response. The results indicate that for Dunnville sandstone Ks' and Ks" are equal while for Berea sandstone, a difference between the two moduli exists, which is explained by the presence of non-connected pores. The experiments also strongly suggest that both Ks' and Ks" are independent of effective stress.

Discrimination of Thermal versus Mechanical Effects of Shock on Rock Magnetic Properties of Spherically Shocked up to 10-160 GPa Basalt and Diabase

NASA Astrophysics Data System (ADS)

Bezaeva, N. S.; Swanson-Hysell, N.; Tikoo, S.; Badyukov, D. D.; Kars, M. A. C.; Egli, R.; Chareev, D. A.; Fairchild, L. M.

2016-12-01

Understanding how shock waves generated during hypervelocity impacts affect rock magnetic properties is key for interpreting the paleomagnetic records of lunar rocks, meteorites, and cratered planetary surfaces. Laboratory simulations of impacts show that ultra-high shocks may induce substantial post-shock heating of the target material. At high pressures (>10 GPa), shock heating occurs in tandem with mechanical effects, such as grain fracturing and creation of crystallographic defects and dislocations within magnetic grains. This makes it difficult to conclude whether shock-induced changes in the rock magnetic properties of target materials are primarily associated with mechanical or thermal effects. Here we present novel experimental methods to discriminate between mechanical and thermal effects of shock on magnetic properties and illustrate it with two examples of spherically shocked terrestrial basalt and diabase [1], which were shocked to pressures of 10 to >160 GPa, and investigate possible explanations for the observed shock-induced magnetic hardening (i.e., increase in remanent coercivity Bcr). The methods consist of i) conducting extra heating experiments at temperatures resembling those experienced during high-pressure shock events on untreated equivalents of shocked rocks (with further comparison of Bcr of shocked and heated samples) and ii) quantitative comparison of high-resolution first-order reversal curve (FORC) diagrams (field step: 0.5-0.7 mT) for shocked, heated and untreated specimens. Using this approach, we demonstrated that the shock-induced coercivity hardening in our samples is predominantly due to solid-state, mechanical effects of shock rather than alteration associated with shock heating. Indeed, heating-induced changes in Bcr in the post-shock temperature range were minor. Visual inspection of FORC contours (in addition to detailed analyses) reveals a stretching of the FORC distribution of shocked sample towards higher coercivities

FOREWORD: The 4th CCM International Conference on Pressure Metrology from Ultra-High Vacuum to Very High Pressures (10-9 Pa to 109 Pa)

NASA Astrophysics Data System (ADS)

Legras, Jean-Claude; Jousten, Karl; Severn, Ian

2005-12-01

The fourth CCM (Consultative Committee for Mass and related quantities) International Conference on Pressure Metrology from Ultra-High Vacuum to Very High Pressures (10-9 Pa to 109 Pa) was held at the Institute of Physics in London from 19-21 April 2005. The event, which was organized by the Low, Medium and High Pressure working groups of the CCM, was attended by in excess of one hundred participants with representatives from five continents and every regional metrology organization. The purpose of this conference is to review all the work that is devoted to the highest quality of pressure measurement by primary standards as well as the dissemination of the pressure scale. A total of 52 papers were presented orally, and 26 as posters, in sessions that covered the following topics: Latest scientific advances in pressure and vacuum metrology Innovative transfer standards, advanced sensors and new instrument development Primary (top-level) measurement standards International and regional key comparisons New approaches to calibration It is interesting the note that since the third conference in 1999 the pressure range covered has increased by two orders of magnitude to 109 Pa, to take into account more exacting scientific and industrial demands for traceable vacuum measurement. A further feature of the conference was the increased range of instrumentation and techniques used in the realization and potential realization of pressure standards. Seton Bennett, Director of International Metrology at the National Physical Laboratory, opened the conference and Andrew Wallard, Director of the Bureau International des Poids et Mesures (BIPM), gave the keynote address which described the implementation of the mutual recognition arrangement and the resulting removal of metrological barriers to international trade. Many experts have contributed significant amounts of their time to organize the event and to review the submitted papers. Thanks are due to all of these people

Accessing Ultrahigh-Pressure, Quasi-Isentropic States of Matter

NASA Astrophysics Data System (ADS)

Lorenz, Thomas

2004-11-01

A new approach to materials science at extreme pressures has been developed on the OMEGA laser, using a ramped plasma piston drive. The laser drives a shock through a solid plastic reservoir that unloads at the rear free surface, expands across a vacuum gap, and stagnates on the metal sample under study. This produces a gently increasing ram pressure, compressing the sample nearly isentropically. The peak pressure on the sample, diagnosed with VISAR measurements, can be varied by adjusting the laser energy and pulse length, gap size, and reservoir density, and obeys a simple scaling relation. [1] This has been demonstrated at OMEGA at pressures of P = 0.1-2.0 Mbar in Al foils. [2] In an important application, using in-flight x-ray radiography, the material strength of solid-state samples at high pressure can be inferred by measuring the reductions in the growth rates (stabilization) of Rayleigh-Taylor (RT) unstable interfaces. The material strength is predicted to be as much as an order of magnitude higher at P ˜ 1 Mbar than at ambient pressures. Initial RT measurements testing this prediction in foils of Al and V will be shown. We also use TEM microscopy of recovered targets to show that the samples never melted, and the presence of pressure-induced structural defects. [3,4] Experimental designs based on this drive have been developed for the NIF laser, predicting that solid-state samples can be quasi-isentropically driven to pressures an order of magnitude higher than on Omega - accessing new regimes of dense, high-pressure matter. [5] [1] J. Edwards et al., Phys. Rev. Lett., 92, 075002 (2004). [2] K.T. Lorenz et al., submitted, J. Appl. Phys. (2004). [3] J. McNaney et al., in press, Met. Mat. Trans. 35A (2004). [4] E.M. Bringa et al., to be submitted, Nature (2004). [5] B.A. Remington et al., in press, Met. Mat. Trans. 35A (2004). This work was performed under the auspices of the U.S. Department of Energy by the University of California, Lawrence Livermore

Ultra-flattened nearly-zero dispersion and ultrahigh nonlinear slot silicon photonic crystal fibers with ultrahigh birefringence

NASA Astrophysics Data System (ADS)

Liao, Jianfei; Xie, Yingmao; Wang, Xinghua; Li, Dongbo; Huang, Tianye

2017-07-01

A slot silicon photonic crystal fiber (PCF) is proposed to simultaneously achieve ultrahigh birefringence, large nonlinearity and ultra-flattened nearly-zero dispersion over a wide wavelength range. By taking advantage on the slot effect, ultrahigh birefringence up to 0.0736 and ultrahigh nonlinear coefficient up to 211.48 W-1 m-1 for quasi-TE mode can be obtained at the wavelength of 1.55 μm. Moreover, ultra-flattened dispersion of 0.49 ps/(nm km) for quasi-TE mode can be achieved over a 180 nm wavelength range with low dispersion slope of 1.85 × 10-3 ps/(nm2 km) at 1.55 μm. Leveraging on these advantages, the proposed slot PCF has great potential for efficient all-optical signal processing applications.

A Chlorine-Centric Perspective on Fluid-Mediated Processes at Convergent Plate Boundaries

NASA Astrophysics Data System (ADS)

Selverstone, J.

2014-12-01

The release and migration of metamorphic fluids from subducting slabs into overlying mantle is widely recognized as a major mechanism in producing arc geochemical signatures and returning fluid-mobile elements to earth's crust and surface environments. Although the magnitudes of many geochemical fluxes are well constrained, the processes whereby mass transfer occurs in different portions of the subduction system are less well known. Chlorine stable isotopes provide a new perspective on some of these processes: Cl is hydrophilic, but decarbonation reactions favor Cl retention in minerals. Cl also shows less isotopic fractionation than other fluid-sensitive systems and may thus preserve evidence of specific fluid sources and/or fluid mixing events. Detailed studies of sedimentary sequences show that individual beds are isotopically homogeneous but large heterogeneities in δ37Cl exist across beds on a cm to m scale and vary as a function of depositional environment. Compositionally correlative medium-, high-, and ultrahigh-pressure metamorphic sequences in the Alps record decreases of 30-50% in Cl contents in the earliest stages of metamorphism, but little change thereafter. No statistically significant change in isotopic composition occurs during prograde metamorphism of individual horizons, and the same large degree of isotopic heterogeneity (up to 6‰) persists throughout the prograde devolatilization history of the rocks. Likewise, analysis of HP/UHP serpentinites and altered oceanic crust show that heterogeneous protolith compositions are preserved during transport to sub-arc depths, despite large-scale devolatilization. However, upward transport of rocks within the subduction channel results in highly localized interaction with isotopically distinct, Cl-bearing fluid packets. Overlying forearc wedge rocks also record heterogeneous and channelized interaction with distinct fluid components with different δ37Cl. Within-layer fluid compartmentalization during

Accessing ultrahigh-pressure, quasi-isentropic states of mattera)

NASA Astrophysics Data System (ADS)

Lorenz, K. T.; Edwards, M. J.; Glendinning, S. G.; Jankowski, A. F.; McNaney, J.; Pollaine, S. M.; Remington, B. A.

2005-05-01

A new approach to the study of material strength of metals at extreme pressures has been developed on the Omega laser, using a ramped plasma piston drive. The laser drives a shock through a solid plastic reservoir that unloads at the rear free surface, expands across a vacuum gap, and stagnates on the metal sample under study. This produces a gently increasing ram pressure, compressing the sample nearly isentropically. The peak pressure on the sample, inferred from interferometric measurements of velocity, can be varied by adjusting the laser energy and pulse length, gap size, and reservoir density, and obeys a simple scaling relation [J. Edwards et al., Phys. Rev. Lett. 92, 075002 (2004)]. In an important application, using in-flight x-ray radiography, the material strength of solid-state samples at high pressure can be inferred by measuring the reductions in the growth rates (stabilization) of Rayleigh-Taylor unstable interfaces. This paper reports the first attempt to use this new laser-driven, quasi-isentropic technique for determining material strength in high-pressure solids. Modulated foils of Al-6061-T6 were accelerated and compressed to peak pressures of ˜200kbar. Modulation growth was recorded at a series of times after peak acceleration and well into the release phase. Fits to the growth data, using a Steinberg-Guinan constitutive strength model, give yield strengths 38% greater than those given by the nominal parameters for Al-6061-T6. Calculations indicate that the dynamic enhancement to the yield strength at ˜200kbar is a factor of ˜3.6× over the ambient yield strength of 2.9kbar. Experimental designs based on this drive developed for the National Ignition Facility laser [W. Hogan, E. Moses, B. Warner, M. Sorem, and J. Soures, Nuclear Fusion 41, 567 (2001)] predict that solid-state samples can be quasi-isentropically driven to pressures an order of magnitude higher than on Omega, accessing new regimes of dense, high-pressure matter.

An ultra-high pressure liquid chromatography-tandem mass spectrometry method for the quantification of teicoplanin in plasma of neonates.

PubMed

Begou, O; Kontou, A; Raikos, N; Sarafidis, K; Roilides, E; Papadoyannis, I N; Gika, H G

2017-03-15

The development and validation of an ultra-high pressure liquid chromatography (UHPLC) tandem mass spectrometry (MS/MS) method was performed with the aim to be applied for the quantification of plasma teicoplanin concentrations in neonates. Pharmacokinetic data of teicoplanin in the neonatal population is very limited, therefore, a sensitive and reliable method for the determination of all isoforms of teicoplanin applied in a low volume of sample is of real importance. Teicoplanin main components were extracted by a simple acetonitrile precipitation step and analysed on a C18 chromatographic column by a triple quadrupole MS with electrospray ionization. The method provides quantitative data over a linear range of 25-6400ng/mL with LOD 8.5ng/mL and LOQ 25ng/mL for total teicoplanin. The method was applied in plasma samples from neonates to support pharmacokinetic data and proved to be a reliable and fast method for the quantification of teicoplanin concentration levels in plasma of infants during therapy in Intensive Care Unit. Copyright © 2016 Elsevier B.V. All rights reserved.

Lithium, boron and chlorine as tracers for metasomatism in high-pressure metamorphic rocks: a case study from Syros (Greece)

NASA Astrophysics Data System (ADS)

Marschall, Horst R.; Altherr, Rainer; Gméling, Katalin; Kasztovszky, Zsolt

2009-03-01

High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H2O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B /Be and Cl /Be ratios correlate with H2O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B /Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl /Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H2O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies.

The permeability of fractured rocks in pressurised volcanic and geothermal systems.

PubMed

Lamur, A; Kendrick, J E; Eggertsson, G H; Wall, R J; Ashworth, J D; Lavallée, Y

2017-07-21

The connectivity of rocks' porous structure and the presence of fractures influence the transfer of fluids in the Earth's crust. Here, we employed laboratory experiments to measure the influence of macro-fractures and effective pressure on the permeability of volcanic rocks with a wide range of initial porosities (1-41 vol. %) comprised of both vesicles and micro-cracks. We used a hand-held permeameter and hydrostatic cell to measure the permeability of intact rock cores at effective pressures up to 30 MPa; we then induced a macro-fracture to each sample using Brazilian tensile tests and measured the permeability of these macro-fractured rocks again. We show that intact rock permeability increases non-linearly with increasing porosity and decreases with increasing effective pressure due to compactional closure of micro-fractures. Imparting a macro-fracture both increases the permeability of rocks and their sensitivity to effective pressure. The magnitude of permeability increase induced by the macro-fracture is more significant for dense rocks. We finally provide a general equation to estimate the permeability of intact and fractured rocks, forming a basis to constrain fluid flow in volcanic and geothermal systems.

Influence of ultra-high pressure homogenisation on antioxidant capacity, polyphenol and vitamin content of clear apple juice.

PubMed

Suárez-Jacobo, Angela; Rüfer, Corinna E; Gervilla, Ramón; Guamis, Buenaventura; Roig-Sagués, Artur X; Saldo, Jordi

2011-07-15

Ultra-high pressure homogenisation (UHPH) is a recently developed technology and is still under study to evaluate its effect on different aspects of its application to food products. The aim of this research work was to evaluate the effect of UHPH treatments on quality characteristics of apple juice such as antioxidant capacity, polyphenol composition, vitamin C and provitamin A contents, in comparison with raw (R) and pasteurised (PA) apple juice. Several UHPH treatments that include combinations of pressure (100, 200 and 300MPa) and inlet temperatures (4 and 20°C) were assayed. Apple juice was pasteurised at 90°C for 4min. Antioxidant capacity was analysed using the oxygen radical antioxidant capacity (ORAC), 2,2-diphenyl-1-picrylhydrazyl (DPPH), trolox equivalent antioxidant capacity (TEAC), ferric reducing antioxidant power (FRAP) assay while total phenolic content was determined by the Folin-Ciocalteau assay. According to the FRAP and DPPH assays, UHPH processing did not change apple juice antioxidant capacity. However, significant differences were detected between samples analysed by TEAC and ORAC assays. In spite of these differences, high correlation values were found between the four antioxidant capacity assays, and also with total polyphenol content. The analysis and quantification of individual phenols by HPLC/DAD analytical technique reflects that UHPH-treatment prevented degradation of these compounds. Vitamin C concentrations did not change in UHPH treated samples, retaining the same value as in raw juice. However, significant losses were observed for provitamin A content, but lower than in PA samples. UHPH-treatments at 300MPa can be an alternative to thermal treatment in order to preserve apple juice quality. Copyright © 2011 Elsevier Ltd. All rights reserved.

Microstructural record of pressure solution and crystal plastic deformation in carbonate fault rocks from a shallow crustal strike-slip fault, Northern Calcareous Alps (Austria)

NASA Astrophysics Data System (ADS)

Bauer, Helene; Rogowitz, Anna; Grasemann, Benhard; Decker, Kurt

2017-04-01

This study presents microstructural investigations of natural carbonate fault rocks that formed by a suite of different deformation processes, involving hydro-fracturing, dissolution-precipitation creep and cataclasis. Some fault rocks show also clear indications of crystal plastic deformation, which is quite unexpected, as the fault rocks were formed in an upper crustal setting, raising the question of possible strongly localised, low temperature ductile deformation in carbonate rocks. The investigated carbonate fault rocks are from an exhumed, sinistral strike-slip fault at the eastern segment of the Salzachtal-Ennstal-Mariazell-Puchberg (SEMP) fault system in the Northern Calcareous Alps (Austria). The SEMP fault system formed during eastward lateral extrusion of the Eastern Alps in the Oligocene to Lower Miocene. Based on vitrinite reflectance data form intramontane Teritary basins within the Northern Calcareous Alps, a maximum burial depth of 4 km for the investigated fault segment is estimated. The investigated fault accommodated sinistral slip of several hundreds of meters. Microstructural analysis of fault rocks includes scanning electron microscopy, optical microscopy and electron backscattered diffraction mapping. The data show that fault rocks underwent various stages of evolution including early intense veining (hydro-fracturing) and stylolite formation reworked by localised shear zones. Cross cutting relationship reveals that veins never cross cut clay seams accumulated along stylolites. We conclude that pressure solution processes occured after hydro-fracturing. Clay enriched zones localized further deformation, producing a network of small-scale clay-rich shear zones of up to 1 mm thickness anastomosing around carbonate microlithons, varying from several mm down to some µm in size. Clay seams consist of kaolinit, chlorite and illite matrix and form (sub) parallel zones in which calcite was dissolved. Beside pressure solution, calcite microlithons

Subduction and exhumation of a continental margin in the Scandinavian Caledonides: Insights from ultrahigh pressure metamorphism, late orogenic basins and 3D numerical modelling

NASA Astrophysics Data System (ADS)

Cuthbert, Simon

2017-04-01

The Scandinavian Caledonides (SC) represents a plate collision zone of Himalayan style and scale. Three fundamental characteristics of this orogen are: (1) early foreland-directed, tectonic transport and stacking of nappes; (2) late, wholesale reversal of tectonic transport; (3) ultrahigh pressure metamorphism of felsic crust derived from the underthrusting plate at several levels in the orogenic wedge and below the main thrust surface, indicating subduction of continental crust into the mantle. The significance of this for crustal evolution is the profound remodeling of continental crust, direct geochemical interaction of such crust and the mantle and the opening of accommodation space trapping large volumes of clastic detritus within the orogen. The orogenic wedge of the SC was derived from the upper crust of the Baltica continental margin (a hyper-extended passive margin), plus terranes derived from an assemblage of outboard arcs and intra-oceanic basins and, at the highest structural level, elements of the Laurentian margin. Nappe emplacement was driven by Scandian ( 430Ma) collision of Baltica with Laurentia, but emerging Middle Ordovician ages for diamond-facies metamorphism for the most outboard (or rifted) elements of Baltica suggest prior collision with an arc or microcontinent. Nappes derived from Baltica continental crust were subducted, in some cases to depths sufficient to form diamond. These then detached from the upper part of the down-going plate along major thrust faults, at which time they ceased to descend and possibly rose along the subduction channel. Subduction of the remaining continental margin continued below these nappes, possibly driven by slab-pull of the previously subducted Iapetus oceanic lithosphere and metamorphic densification of subducted felsic continental margin. 3D numerical modelling based upon a Caledonide-like plate scenario shows that if a continental corner or promontory enters the subduction zone, the continental margin

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnis Judzis; Homer Robertson; Alan Black

2006-06-22

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energymore » and loads. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm-usually well below 5,000 rpm. This document details the progress at the end of Phase 1 on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 March 2006 and concluding 30 June 2006. (Note: Results from 1 September 2005 through 28 February 2006 were included in the previous report (see Judzis, Black, and Robertson)). Summarizing the accomplished during Phase 1: {lg_bullet} TerraTek reviewed applicable literature and documentation and convened a project kickoff meeting with Industry Advisors in attendance (see Black and Judzis). {lg_bullet} TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Some difficulties continued in obtaining ultra-high speed motors. Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more

Summary of results of frictional sliding studies, at confining pressures up to 6.98 kb, in selected rock materials

USGS Publications Warehouse

Summers, R.; Byerlee, J.

1977-01-01

This report is a collection of stress-strain charts which were produced by deforming selected simuiated fault gouge materials. Several sets of samples consisted of intact cylinders, 1.000 inch in diameter and 2.500 inches long. The majority of the samples consisted of thin layers of the selected sample material, inserted within a diagonal sawcut in a 1.000-inch by 2.500-inch Westerly Granite cylinder. Two sorts of inserts were used. The first consisted of thin wafers cut from 1.000-inch-diameter cores of the rock being tested. The other consisted of thin layers of crushed material packed onto the sawcut surface. In several groups of tests using various thicknesses (0.010 inch to 0.160 inch) of a given type material there were variations in the stress level and/or stability of sliding as a function of the fault zone width. Because of this we elected to use a standard 0.025-inch width fault zone to compare the frictional properties of many of the different types of rock materials. This 0.025-inch thickness was chosen partially because this thickness of crushed granite behaves approximately the same as a fractured sample of initially intact granite, and also because this is near the lower limit at which we could cut intact wafers for those samples that were prepared from thin slices of rock. One series of tests was done with saw cut granite cylinders without fault gouge inserts. All of these tests were done in a hydraulically operated triaxial testing machine. The confining pressure (δ1, least principal stress) was applied by pumping petroleum ether into a pressure vessel. The differential stress (δ3-δ1) was applied by a hydraulically operated ram that could be advanced into the pressure vessel at any of several strain rates (10-4sec-1, 10-5sec-1, 10-6sec-1, 10-7sec-1, or 10-8sec-1). All samples were jacketed in polyurethane tubing to exclude the confining pressure medium from the samples. The majority of the samples, with the exception of some of the initially

Magnetic Resonance Imaging at Ultrahigh Fields

PubMed Central

Uğurbil, Kamil

2014-01-01

Since the introduction of 4 T human systems in three academic laboratories circa 1990, rapid progress in imaging and spectroscopy studies in humans at 4 T and animal model systems at 9.4 T have led to the introduction of 7 T and higher magnetic fields for human investigation at about the turn of the century. Work conducted on these platforms has demonstrated the existence of significant advantages in SNR and biological information content at these ultrahigh fields, as well as the presence of numerous challenges. Primary difference from lower fields is the deviation from the near field regime; at the frequencies corresponding to hydrogen resonance conditions at ultrahigh fields, the RF is characterized by attenuated traveling waves in the human body, which leads to image nonuniformities for a given sample-coil configuration because of interferences. These nonuniformities were considered detrimental to the progress of imaging at high field strengths. However, they are advantageous for parallel imaging for signal reception and parallel transmission, two critical technologies that account, to a large extend, for the success of ultrahigh fields. With these technologies, and improvements in instrumentation and imaging methods, ultra-high fields have provided unprecedented gains in imaging of brain function and anatomy, and started to make inroads into investigation of the human torso and extremities. As extensive as they are, these gains still constitute a prelude to what is to come given the increasingly larger effort committed to ultrahigh field research and development of ever better instrumentation and techniques. PMID:24686229

Simulation of crack propagation in rock in plasma blasting technology

NASA Astrophysics Data System (ADS)

Ikkurthi, V. R.; Tahiliani, K.; Chaturvedi, S.

Plasma Blasting Technology (PBT) involves the production of a pulsed electrical discharge by inserting a blasting probe in a water-filled cavity drilled in a rock, which produces shocks or pressure waves in the water. These pulses then propagate into the rock, leading to fracture. In this paper, we present the results of two-dimensional hydrodynamic simulations using the SHALE code to study crack propagation in rock. Three separate issues have been examined. Firstly, assuming that a constant pressure P is maintained in the cavity for a time τ , we have determined the P- τ curve that just cracks a given rock into at least two large-sized parts. This study shows that there exists an optimal pressure level for cracking a given rock-type and geometry. Secondly, we have varied the volume of water in which the initial energy E is deposited, which corresponds to different initial peak pressures Ppeak. We have determined the E- Ppeak curve that just breaks the rock into four large-sized parts. It is found that there must be an optimal Ppeak that lowers the energy consumption, but with acceptable probe damage. Thirdly, we have attempted to identify the dominant mechanism of rock fracture. We also highlight some numerical errors that must be kept in mind in such simulations.

Shear-enhanced compaction in viscoplastic rocks

NASA Astrophysics Data System (ADS)

Yarushina, V. M.; Podladchikov, Y. Y.

2012-04-01

The phenomenon of mutual influence of compaction and shear deformation was repeatedly reported in the literature over the past years. Dilatancy and shear-enhanced compaction of porous rocks were experimentally observed during both rate-independent and rate-dependent inelastic deformation. Plastic pore collapse was preceding the onset of dilatancy and shear-enhanced compaction. Effective bulk viscosity is commonly used to describe compaction driven fluid flow in porous rocks. Experimental data suggest that bulk viscosity of a fluid saturated rock might be a function of both the effective pressure and the shear stress. Dilatancy and shear-enhanced compaction can alter the transport properties of rocks through their influence on permeability and compaction length scale. Recent investigations show that shear stresses in deep mantle rocks can be responsible for spontaneous development of localized melt-rich bands and segregation of small amounts of melt from the solid rock matrix through shear channeling instability. Usually it is assumed that effective viscosity is a function of porosity only. Thus coupling between compaction and shear deformation is ignored. Spherical model which considers a hollow sphere subjected to homogeneous tractions on the outer boundary as a representative elementary volume succeeded in predicting the volumetric compaction behavior of porous rocks and metals to a hydrostatic pressure in a wide range of porosities. Following the success of this simple model we propose a cylindrical model of void compaction and decompaction due to the non-hydrostatic load. The infinite viscoplastic layer with a cylindrical hole is considered as a representative volume element. The remote boundary of the volume is subjected to a homogeneous non-hydrostatic load such that plane strain conditions are fulfilled through the volume. At some critical values of remote stresses plastic zone develops around the hole. The dependence of the effective bulk viscosity on the

DaDyn-RS: a tool for the time-dependent simulation of damage, fluid pressure and long-term instability in alpine rock slopes

NASA Astrophysics Data System (ADS)

Riva, Federico; Agliardi, Federico; Amitrano, David; Crosta, Giovanni B.

2017-04-01

Large mountain slopes in alpine environments undergo a complex long-term evolution from glacial to postglacial environments, through a transient period of paraglacial readjustment. During and after this transition, the interplay among rock strength, topographic relief, and morpho-climatic drivers varying in space and time can lead to the development of different types of slope instability, from sudden catastrophic failures to large, slow, long-lasting yet potentially catastrophic rockslides. Understanding the long-term evolution of large rock slopes requires accounting for the time-dependence of deglaciation unloading, permeability and fluid pressure distribution, displacements and failure mechanisms. In turn, this is related to a convincing description of rock mass damage processes and to their transition from a sub-critical (progressive failure) to a critical (catastrophic failure) character. Although mechanisms of damage occurrence in rocks have been extensively studied in the laboratory, the description of time-dependent damage under gravitational load and variable external actions remains difficult. In this perspective, starting from a time-dependent model conceived for laboratory rock deformation, we developed Dadyn-RS, a tool to simulate the long-term evolution of real, large rock slopes. Dadyn-RS is a 2D, FEM model programmed in Matlab, which combines damage and time-to-failure laws to reproduce both diffused damage and strain localization meanwhile tracking long-term slope displacements from primary to tertiary creep stages. We implemented in the model the ability to account for rock mass heterogeneity and property upscaling, time-dependent deglaciation, as well as damage-dependent fluid pressure occurrence and stress corrosion. We first tested DaDyn-RS performance on synthetic case studies, to investigate the effect of the different model parameters on the mechanisms and timing of long-term slope behavior. The model reproduces complex interactions between

Ultrahigh-yield growth of GaN via halogen-free vapor-phase epitaxy

NASA Astrophysics Data System (ADS)

Nakamura, Daisuke; Kimura, Taishi

2018-06-01

The material yield of Ga during GaN growth via halogen-free vapor-phase epitaxy (HF-VPE) was systematically investigated and found to be much higher than that obtained using conventional hydride VPE. This is attributed to the much lower process pressure and shorter seed-to-source distance, owing to the inherent chemical reactions and corresponding reactor design used for HF-VPE growth. Ultrahigh-yield GaN growth was demonstrated on a 4-in.-diameter sapphire seed substrate.

Abnormally high formation pressures, Potwar Plateau, Pakistan

USGS Publications Warehouse

Law, B.E.; Shah, S.H.A.; Malik, M.A.

1998-01-01

Abnormally high formation pressures in the Potwar Plateau of north-central Pakistan are major obstacles to oil and gas exploration. Severe drilling problems associated with high pressures have, in some cases, prevented adequate evaluation of reservoirs and significantly increased drilling costs. Previous investigations of abnormal pressure in the Potwar Plateau have only identified abnormal pressures in Neogene rocks. We have identified two distinct pressure regimes in this Himalayan foreland fold and thrust belt basin: one in Neogene rocks and another in pre-Neogene rocks. Pore pressures in Neogene rocks are as high as lithostatic and are interpreted to be due to tectonic compression and compaction disequilibrium associated with high rates of sedimentation. Pore pressure gradients in pre-Neogene rocks are generally less than those in Neogene rocks, commonly ranging from 0.5 to 0.7 psi/ft (11.3 to 15.8 kPa/m) and are most likely due to a combination of tectonic compression and hydrocarbon generation. The top of abnormally high pressure is highly variable and doesn't appear to be related to any specific lithologic seal. Consequently, attempts to predict the depth to the top of overpressure prior to drilling are precluded.

Frictional property of rocks in the Izu-Bonin-Mariana Forearc under high temperature and pressure conditions

NASA Astrophysics Data System (ADS)

Hyodo, G.; Takahashi, M.; Saito, S.; Hirose, T.

2014-12-01

The Kanto region in central Japan lies atop of three tectonic plates: the North American Plate, the Pacific Plate, and the Philippine Sea Plate. The collision and subduction of the Izu-Bonin-Mariana (IBM) arc on the Philippine Sea Plate into the Kanto region results in occurring the different type of earthquakes, including seismic slip (e.g., the Kanto earthquake) and aseismic creep (i.e., slow earthquakes around the Boso peninsula). The seismic and aseismic slip seems to generate side by side at almost same depth (probably nearly same P-T conditions). This study focus on frictional property of incoming materials to be subducted into the Kanto region, in order to examine a hypothesis that the different types of slips arise from different input materials. Thus, we have performed friction experiments on rocks that constitute the IBM forearc using a high P-T gas medium apparatus at AIST. We sampled five rocks (marl, boninite, andesite, sheared serpentinite and serpentinized dunite) recovered from the IBM forearc by Leg 125, Ocean Drilling Program (ODP Site 784, 786). The rocks were crushed and sieved into 10˜50 µm in grain size. Experiments were conducted at temperature of 300○C, confining pressure of 156 MPa, pore pressure of 60 MPa and axial displacement rates of 0.1 and 1 µm/s. For marl, andesite and boninite, a periodic stick-slip behavior appears at 1 µm/s. Rise time of the stick-slip behaviors are quite long (3.1, 9.9 and 14.2 sec, for marl, andesite and boninite, respectively). We called such events as a "slow stick-slip". Similar slow stick-slip behaviors were observed in previous studies (Noda and Shimamoto, 2010; Okazaki, 2013; Kaproth and Marone, 2013), but this is first time to recognize this characteristic slip behavior in sedimentary and igneous rocks. Although it is difficult to discuss the diverse slip behaviors observed at the Kanto region based on our limited experimental results, we will examine the conditions where the transition between

First application of the revised Ti-in-zircon geothermometer to Paleoproterozoic ultrahigh-temperature granulites of Tuguiwula, Inner Mongolia, North China Craton

NASA Astrophysics Data System (ADS)

Liu, S. J.; Li, J. H.; Santosh, M.

2010-02-01

The revised titanium-in-zircon geothermometer was applied to Paleoproterozoic ultrahigh-temperature (UHT) granulites at Tuguiwula, Inner Mongolia, North China Craton. The Tuguiwula granulites contain diagnostic UHT mineral assemblages such as sapphirine + quartz and high alumina orthopyroxene + sillimanite + quartz, suggesting formation under temperatures of ca. 1,000°C and pressures of up to 10 kbar. Here, we report detailed petrographic studies and ICP-MS data on titanium concentration in zircons associated with the UHT assemblages. The zircons associated with sapphirine-spinel-sillimanite-magnetite assemblages have the highest Ti concentration of up to 57 ppm, yielding a temperature of 941°C, and suggesting that the growth of zircons occurred under ultrahigh-temperature conditions. The maximum temperatures obtained by the revised Ti-in-zircon geothermometer is lower than the equilibrium temperature of sapphirine + quartz, indicating an interval of cooling history of the granulites from UHT condition to ca. 940°C. Many of the zircons have Ti concentrations ranging from 10 to 33 ppm, indicating their growth or recrystallization under lower temperatures of ca. 745-870°C. These zircons are interpreted to have recrystallized during the retrograde stage indicated by microstructures such as cordierite rim or corona between spinel and quartz, and orthopyroxene-cordierite symplectite around garnet. Previous geochronological study on the zircons of the Tuguiwula UHT granulites gave a mean U-Pb SHRIMP age of 1.92 Ga. However, based on the Ti-in-zircon geothermometer results reported in this work, and considering the relatively slow thermal relaxation of these rocks, we infer that the timing of peak UHT metamorphism in the Tuguiwula area could be slightly older than 1.92 Ga.

Structural styles and zircon ages of the South Tianshan accretionary complex, Atbashi Ridge, Kyrgyzstan: Insights for the anatomy of ocean plate stratigraphy and accretionary processes

NASA Astrophysics Data System (ADS)

Sang, Miao; Xiao, Wenjiao; Orozbaev, Rustam; Bakirov, Apas; Sakiev, Kadyrbek; Pak, Nikolay; Ivleva, Elena; Zhou, Kefa; Ao, Songjian; Qiao, Qingqing; Zhang, Zhixin

2018-03-01

The anatomy of an ancient accretionary complex has a significance for a better understanding of the tectonic processes of accretionary orogens and complex because of its complicated compositions and strong deformation. With a thorough structural and geochronological study of a fossil accretionary complex in the Atbashi Ridge, South Tianshan (Kyrgyzstan), we analyze the structure and architecture of ocean plate stratigraphy in the western Central Asian Orogenic Belt. The architecture of the Atbashi accretionary complex is subdivisible into four lithotectonic assemblages, some of which are mélanges with "block-in-matrix" structure: (1) North Ophiolitic Mélange; (2) High-pressure (HP)/Ultra-high-pressure (UHP) Metamorphic Assemblage; (3) Coherent & Mélange Assemblage; and (4) South Ophiolitic Mélange. Relationships between main units are tectonic contacts presented by faults. The major structures and lithostratigraphy of these units are thrust-fold nappes, thrusted duplexes, and imbricated ocean plate stratigraphy. All these rock units are complicatedly stacked in 3-D with the HP/UHP rocks being obliquely southwestward extruded. Detrital zircon ages of meta-sediments provide robust constraints on their provenance from the Ili-Central Tianshan Arc. The isotopic ages of the youngest components of the four units are Late Permian, Early-Middle Triassic, Early Carboniferous, and Early Triassic, respectively. We present a new tectonic model of the South Tianshan; a general northward subduction polarity led to final closure of the South Tianshan Ocean in the End-Permian to Late Triassic. These results help to resolve the long-standing controversy regarding the subduction polarity and the timing of the final closure of the South Tianshan Ocean. Finally, our work sheds lights on the use of ocean plate stratigraphy in the analysis of the tectonic evolution of accretionary orogens.

Implications of elastic wave velocities for Apollo 17 rock powders

NASA Technical Reports Server (NTRS)

Talwani, P.; Nur, A.; Kovach, R. L.

1974-01-01

Ultrasonic P- and S-wave velocities of lunar rock powders 172701, 172161, 170051, and 175081 were measured at room temperature and to 2.5 kb confining pressure. The results compare well with those of terrestrial volcanic ash and powdered basalt. P-wave velocity values up to pressures corresponding to a lunar depth of 1.4 km preclude cold compaction alone as an explanation for the observed seismic velocity structure at the Apollo 17 site. Application of small amounts of heat with simultaneous application of pressure causes rock powders to achieve equivalence of seismic velocities for competent rocks.

Some observations on the mechanism of aircraft wing rock

NASA Technical Reports Server (NTRS)

Hwang, C.; Pi, W. S.

1978-01-01

A pressure scale model of Northrop F-5A was tested in NASA Ames Research Center Eleven-Foot Transonic Tunnel to simulate the wing rock oscillations in a transonic maneuver. For this purpose, a flexible model support device was designed and fabricated which allowed the model to oscillate in roll at the scaled wing rock frequency. Two tunnel entries were performed to acquire the pressure (steady state and fluctuating) and response data when the model was held fixed and when it was excited by flow to oscillate in roll. Based on these data, a limit cycle mechanism was identified which supplied energy to the aircraft model and caused the Dutch roll type oscillations, commonly called wing rock. The major origin of the fluctuating pressures which contributed to the limit cycle was traced to the wing surface leading edge stall and the subsequent lift recovery. For typical wing rock oscillations, the energy balance between the pressure work input and the energy consumed by the model aerodynamic and mechanical damping was formulated and numerical data presented.

The role of fluids in rock layering development: a pressure solution self-organized process revealed by laboratory experiments

NASA Astrophysics Data System (ADS)

Gratier, Jean-Pierre; Noiriel, Catherine; Renard, Francois

2015-04-01

Natural deformation of rocks is often associated with stress-driven differentiation processes leading to irreversible transformations of their microstructures. The development mechanisms of such processes during diagenesis, tectonic, metamorphism or fault differentiation are poorly known as they are difficult to reproduce experimentally due to the very slow kinetics of stress-driven chemical processes. Here, we show that experimental compaction with development of differentiated layering, similar to what happens in natural deformation, can be obtained by indenter techniques in laboratory conditions. Samples of plaster mixed with clay and of diatomite loosely interbedded with volcanic dust were loaded in presence of their saturated aqueous solutions during several months at 40°C and 150°C, respectively. High-resolution X-ray microtomography and scanning electron microscopy observations show that the layering development is a pressure solution self-organized process. Stress-driven dissolution of the soluble minerals (either gypsum or silica) is initiated in the areas initially richer in insoluble minerals (clays or volcanic dust) because the kinetics of diffusive mass transfer along the soluble/insoluble mineral interfaces is much faster than along the healed boundaries of the soluble minerals. The passive concentration of insoluble minerals amplifies the localization of dissolution along some layers oriented perpendicular to the maximum compressive stress. Conversely, in the areas with initial low content in insoluble minerals and clustered soluble minerals, dissolution is slower. Consequently, these areas are less deformed, they host the re-deposition of the soluble species and they act as rigid objects that concentrate the dissolution near their boundaries thus amplifying the differentiation. A crucial parameter required for self-organized process of pressure solution is the presence of a fluid that is a good solvent of at least some of the rock-forming minerals

Rockin' around the Rock Cycle

ERIC Educational Resources Information Center

Frack, Susan; Blanchard, Scott Alan

2005-01-01

In this activity students will simulate how sedimentary rocks can be changed into metamorphic rocks by intense pressure. The materials needed are two small pieces of white bread, one piece of wheat bread, and one piece of a dark bread (such as pumpernickel or dark rye) per student, two pieces of waxed paper, scissors, a ruler, and heavy books.…

Quantile Regression for Analyzing Heterogeneity in Ultra-high Dimension

PubMed Central

Wang, Lan; Wu, Yichao

2012-01-01

Ultra-high dimensional data often display heterogeneity due to either heteroscedastic variance or other forms of non-location-scale covariate effects. To accommodate heterogeneity, we advocate a more general interpretation of sparsity which assumes that only a small number of covariates influence the conditional distribution of the response variable given all candidate covariates; however, the sets of relevant covariates may differ when we consider different segments of the conditional distribution. In this framework, we investigate the methodology and theory of nonconvex penalized quantile regression in ultra-high dimension. The proposed approach has two distinctive features: (1) it enables us to explore the entire conditional distribution of the response variable given the ultra-high dimensional covariates and provides a more realistic picture of the sparsity pattern; (2) it requires substantially weaker conditions compared with alternative methods in the literature; thus, it greatly alleviates the difficulty of model checking in the ultra-high dimension. In theoretic development, it is challenging to deal with both the nonsmooth loss function and the nonconvex penalty function in ultra-high dimensional parameter space. We introduce a novel sufficient optimality condition which relies on a convex differencing representation of the penalized loss function and the subdifferential calculus. Exploring this optimality condition enables us to establish the oracle property for sparse quantile regression in the ultra-high dimension under relaxed conditions. The proposed method greatly enhances existing tools for ultra-high dimensional data analysis. Monte Carlo simulations demonstrate the usefulness of the proposed procedure. The real data example we analyzed demonstrates that the new approach reveals substantially more information compared with alternative methods. PMID:23082036

The Rapid Formation of Localized Compaction Bands Under Hydrostatic Load Leading to Pore-pressure Transients in Compacting Rocks

NASA Astrophysics Data System (ADS)

Faulkner, D.; Leclere, H.; Bedford, J. D.; Behnsen, J.; Wheeler, J.

2017-12-01

Compaction of porous rocks can occur uniformly or within localized deformation bands. The formation of compaction bands and their effects on deformation behaviour are poorly understood. Porosity may be primary and compaction can occur with burial, or it can be produced by metamorphic reactions with a solid volume reduction, that can then undergo collapse. We report results from hydrostatic compaction experiments on porous bassanite (CaSO4.0.5H2O) aggregates. Gypsum (CaSO4.2H2O) is first dehydrated under low effective pressure, 4 MPa, to produce a bassanite aggregate with a porosity of 27%. Compaction is induced by increasing confining pressure at rates from 0.001 MPa/s to 0.02 MPa/s while the sample is maintained at a temperature of 115°C. At slow compaction rates, porosity collapse proceeds smoothly. At higher compaction rates, sudden increases in the pore-fluid pressure occur with a magnitude of 5 MPa. Microstructural investigations using X-ray microtomography and SEM observations show that randomly oriented localized compaction features occur in all samples, where the bulk porosity of 18% outside the band is reduced to 5% inside the band. Previous work on deformation bands has suggested that localized compactive features only form under an elevated differential stress and not under a hydrostatic stress state. The magnitude of the pore-pressure pulses can be explained by the formation of compaction bands. The results indicate that the compaction bands can form by rapid (unstable) propagation across the sample above a critical strain rate, or quasi-statically at low compaction rates without pore-fluid pressure bursts. The absence of pore-fluid pressure bursts at slow compaction rates can be explained by viscous deformation of the bassanite aggregate around the tip of a propagating compaction band, relaxing stress, and promoting stable propagation. Conversely, at higher compaction rates, viscous deformation cannot relax the stress sufficiently and unstable

Standoff Detection of Geological Samples of Metal, Rock, and Soil at Low Pressures Using Laser-Induced Breakdown Spectroscopy.

PubMed

Choi, Jae-Jun; Choi, Soo-Jin; Yoh, Jack J

2016-09-01

Categorized certified reference materials simulating metal, rock, soils, or dusts are used to demonstrate the standoff detection capability of laser-induced breakdown spectroscopy (LIBS) at severely low pressure conditions. A Q-switched Nd:YAG laser operating at 1064 nm with 17.2-50 mJ energy per pulse was used to obtain sample signals from a distance of 5.5 m; the detection sensitivity at pressures down to 0.01 torr was also analyzed. The signal intensity response to pressure changes is explained by the ionization energy and electronegativity of elements, and from the estimated full width half-maximum (FWHM) and electron density, the decrease in both background noise and line broadening makes it suitable for low pressure detection using the current standoff LIBS configuration. The univariate analyses further showed high correlation coefficients for geological samples. Therefore, the present work has extended the current state-of-the-art of standoff LIBS aimed at harsh environment detection. © The Author(s) 2016.

Metamorphic Perspectives of Subduction Zone Volatiles Cycling

NASA Astrophysics Data System (ADS)

Bebout, G. E.

2008-12-01

Field study of HP/UHP metamorphic rocks provides "ground-truthing" for experimental and theoretical petrologic studies estimating extents of deep volatiles subduction, and provides information regarding devolatilization and deep subduction-zone fluid flow that can be used to reconcile estimates of subduction inputs and arc volcanic outputs for volatiles such as H2O, N, and C. Considerable attention has been paid to H2O subduction in various bulk compositions, and, based on calculated phase assemblages, it is thought that a large fraction of the initially structurally bound H2O is subducted to, and beyond, subarc regions in most modern subduction zones (Hacker, 2008, G-cubed). Field studies of HP/UHP mafic and sedimentary rocks demonstrate the impressive retention of volatiles (and fluid-mobile elements) to depths approaching those beneath arcs. At the slab-mantle interface, high-variance lithologies containing hydrous phases such as mica, amphibole, talc, and chlorite could further stabilize H2O to great depth. Trench hydration in sub-crustal parts of oceanic lithosphere could profoundly increase subduction inputs of particularly H2O, and massive flux of H2O-rich fluids from these regions into the slab-mantle interface could lead to extensive metasomatism. Consideration of sedimentary N concentrations and δ15N at ODP Site 1039 (Li and Bebout, 2005, JGR), together with estimates of the N concentration of subducting altered oceanic crust (AOC), indicates that ~42% of the N subducting beneath Nicaragua is returned in the corresponding volcanic arc (Elkins et al., 2006, GCA). Study of N in HP/UHP sedimentary and basaltic rocks indicates that much of the N initially subducted in these lithologies would be retained to depths approaching 100 km and thus available for addition to arcs. The more altered upper part of subducting oceanic crust most likely to contribute to arcs has sediment-like δ15NAir (0 to +10 per mil; Li et al., 2007, GCA), and study of HP/UHP eclogites

A novel high-pressure vessel for simultaneous observations of seismic velocity and in situ CO2 distribution in a porous rock using a medical X-ray CT scanner

NASA Astrophysics Data System (ADS)

Jiang, Lanlan; Nishizawa, Osamu; Zhang, Yi; Park, Hyuck; Xue, Ziqiu

2016-12-01

Understanding the relationship between seismic wave velocity or attenuation and CO2 saturation is essential for CO2 storage in deep saline formations. In the present study, we describe a novel upright high-pressure vessel that is designed to keep a rock sample under reservoir conditions and simultaneously image the entire sample using a medical X-ray CT scanner. The pressure vessel is composed of low X-ray absorption materials: a carbon-fibre-enhanced polyetheretherketone (PEEK) cylinder and PEEK vessel closures supported by carbon-fibre-reinforced plastic (CFRP) joists. The temperature was controlled by a carbon-coated film heater and an aramid fibre thermal insulator. The assembled sample cell allows us to obtain high-resolution images of rock samples during CO2 drainage and brine imbibition under reservoir conditions. The rock sample was oriented vertical to the rotation axis of the CT scanner, and seismic wave paths were aligned parallel to the rotation axis to avoid shadows from the acoustic transducers. The reconstructed CO2 distribution images allow us to calculate the CO2 saturation in the first Fresnel zone along the ray path between transducers. A robust relationship between the seismic wave velocity or attenuation and the CO2 saturation in porous rock was obtained from experiments using this pressure vessel.

Tightness of Salt Rocks and Fluid Percolation

NASA Astrophysics Data System (ADS)

Lüdeling, C.; Minkley, W.; Brückner, D.

2016-12-01

Salt formations are used for storage of oil and gas and as waste repositiories because of their excellent barrier properties. We summarise the current knowledge regarding fluid tightness of saliferous rocks, in particular rock salt. Laboratory results, in-situ observations and natural analogues, as well as theoretical and numerical investigations, indicate that pressure-driven percolation is the most important mechanism for fluid transport: If the fluid pressure exceeds the percolation threshold, i.e. the minor principal stress, the fluid can open up grain boundaries, create connected flow paths and initiate directed migration in the direction of major principal stress. Hence, this mechanism provides the main failure mode for rock salt barriers, where integrity can be lost if the minor principal stress is lowered, e.g. due to excavations or thermomechanical uplift. We present new laboratory experiments showing that there is no fluid permeation below the percolation threshold also at high temperatures and pressures, contrary to recent claims in the literature.

Pore Characterization of Shale Rock and Shale Interaction with Fluids at Reservoir Pressure-Temperature Conditions Using Small-Angle Neutron Scattering

NASA Astrophysics Data System (ADS)

Ding, M.; Hjelm, R.; Watkins, E.; Xu, H.; Pawar, R.

2015-12-01

Oil/gas produced from unconventional reservoirs has become strategically important for the US domestic energy independence. In unconventional realm, hydrocarbons are generated and stored in nanopores media ranging from a few to hundreds of nanometers. Fundamental knowledge of coupled thermo-hydro-mechanical-chemical (THMC) processes that control fluid flow and propagation within nano-pore confinement is critical for maximizing unconventional oil/gas production. The size and confinement of the nanometer pores creates many complex rock-fluid interface interactions. It is imperative to promote innovative experimental studies to decipher physical and chemical processes at the nanopore scale that govern hydrocarbon generation and mass transport of hydrocarbon mixtures in tight shale and other low permeability formations at reservoir pressure-temperature conditions. We have carried out laboratory investigations exploring quantitative relationship between pore characteristics of the Wolfcamp shale from Western Texas and the shale interaction with fluids at reservoir P-T conditions using small-angle neutron scattering (SANS). We have performed SANS measurements of the shale rock in single fluid (e.g., H2O and D2O) and multifluid (CH4/(30% H2O+70% D2O)) systems at various pressures up to 20000 psi and temperature up to 150 oF. Figure 1 shows our SANS data at different pressures with H2O as the pressure medium. Our data analysis using IRENA software suggests that the principal changes of pore volume in the shale occurred on smaller than 50 nm pores and pressure at 5000 psi (Figure 2). Our results also suggest that with increasing P, more water flows into pores; with decreasing P, water is retained in the pores.

Advanced Photon Source accelerator ultrahigh vacuum guide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, C.; Noonan, J.

1994-03-01

In this document the authors summarize the following: (1) an overview of basic concepts of ultrahigh vacuum needed for the APS project, (2) a description of vacuum design and calculations for major parts of APS, including linac, linac waveguide, low energy undulator test line, positron accumulator ring (PAR), booster synchrotron ring, storage ring, and insertion devices, and (3) cleaning procedures of ultrahigh vacuum (UHV) components presently used at APS.

Petrology of gabbroic rocks from the Mid-Cayman rise spreading center

NASA Technical Reports Server (NTRS)

Elthon, Don

1987-01-01

Mineral analyses of oxide and silicate phases from a suite (collected with the DSRV Alvin in January 1976 and July 1977) of 48 gabbroic rocks collected from the vicinity of the Mid-Cayman Rise spreading center are reported. Mineral compositions of these anorthosites, leuco-troctolite, leuco-olivine gabbros, olivine gabbros, leuco-gabbros, and gabbros indicate the cumulate rocks have been produced by the crystal fractionation of basaltic liquids. Certain features of these rocks are inconsistent with the occurrence of this fractionation at low pressures (1 atm to 2 kbar). Although the experimental data are not available to conclusively demonstrate that the effects seen were produced at moderate pressures (5-10 kbar), the effects are similar to those predicted thermodynamically and to those observed in limited experimental studies within this pressure range. It is therefore suggested that the most likely scenario for the production of these gabbroic rocks is the moderate-pressure crystallization of basaltic magmas within deep-seated magma chambers underneath this slow-spreading center.

Abnormal pressure in hydrocarbon environments

USGS Publications Warehouse

Law, B.E.; Spencer, C.W.

1998-01-01

Abnormal pressures, pressures above or below hydrostatic pressures, occur on all continents in a wide range of geological conditions. According to a survey of published literature on abnormal pressures, compaction disequilibrium and hydrocarbon generation are the two most commonly cited causes of abnormally high pressure in petroleum provinces. In young (Tertiary) deltaic sequences, compaction disequilibrium is the dominant cause of abnormal pressure. In older (pre-Tertiary) lithified rocks, hydrocarbon generation, aquathermal expansion, and tectonics are most often cited as the causes of abnormal pressure. The association of abnormal pressures with hydrocarbon accumulations is statistically significant. Within abnormally pressured reservoirs, empirical evidence indicates that the bulk of economically recoverable oil and gas occurs in reservoirs with pressure gradients less than 0.75 psi/ft (17.4 kPa/m) and there is very little production potential from reservoirs that exceed 0.85 psi/ft (19.6 kPa/m). Abnormally pressured rocks are also commonly associated with unconventional gas accumulations where the pressuring phase is gas of either a thermal or microbial origin. In underpressured, thermally mature rocks, the affected reservoirs have most often experienced a significant cooling history and probably evolved from an originally overpressured system.

Structural phase transitions in yttrium under ultrahigh pressures

NASA Astrophysics Data System (ADS)

Samudrala, Gopi K.; Tsoi, Georgiy M.; Vohra, Yogesh K.

2012-09-01

X-ray diffraction studies were carried out on the rare earth metal yttrium up to 177 GPa in a diamond anvil cell at room temperature. Yttrium was compressed to 37% of its initial volume at the highest pressure. The rare earth crystal structure sequence hcp → Sm type → dhcp → mixed(dhcp + fcc) → distorted fcc (dfcc) is observed in yttrium below 50 GPa. The dfcc (hR24) phase has been observed to persist in the pressure range of 50-95 GPa. A structural transition from dfcc to a low symmetry phase has been observed in yttrium at 99 ± 4 GPa with a volume change of - 2.6%. This low symmetry phase has been identified as a monoclinic C2/m phase, which has also been observed in other rare earth elements under high pressures. The appearance of this low symmetry monoclinic phase in yttrium shows that its electronic structure under extreme conditions resembles that of heavy rare earth metals, with a significant increase in d-band character of the valence electrons and possibly some f-electron states near the Fermi level.

Structural phase transitions in yttrium under ultrahigh pressures.

PubMed

Samudrala, Gopi K; Tsoi, Georgiy M; Vohra, Yogesh K

2012-09-12

X-ray diffraction studies were carried out on the rare earth metal yttrium up to 177 GPa in a diamond anvil cell at room temperature. Yttrium was compressed to 37% of its initial volume at the highest pressure. The rare earth crystal structure sequence hcp → Sm type → dhcp → mixed(dhcp + fcc) → distorted fcc (dfcc) is observed in yttrium below 50 GPa. The dfcc (hR24) phase has been observed to persist in the pressure range of 50-95 GPa. A structural transition from dfcc to a low symmetry phase has been observed in yttrium at 99 ± 4 GPa with a volume change of - 2.6%. This low symmetry phase has been identified as a monoclinic C2/m phase, which has also been observed in other rare earth elements under high pressures. The appearance of this low symmetry monoclinic phase in yttrium shows that its electronic structure under extreme conditions resembles that of heavy rare earth metals, with a significant increase in d-band character of the valence electrons and possibly some f-electron states near the Fermi level.

Ultrahigh-speed ultrahigh-resolution adaptive optics: optical coherence tomography system for in-vivo small animal retinal imaging

NASA Astrophysics Data System (ADS)

Jian, Yifan; Xu, Jing; Zawadzki, Robert J.; Sarunic, Marinko V.

2013-03-01

Small animal models of human retinal diseases are a critical component of vision research. In this report, we present an ultrahigh-resolution ultrahigh-speed adaptive optics optical coherence tomography (AO-OCT) system for small animal retinal imaging (mouse, fish, etc.). We adapted our imaging system to different types of small animals in accordance with the optical properties of their eyes. Results of AO-OCT images of small animal retinas acquired with AO correction are presented. Cellular structures including nerve fiber bundles, capillary networks and detailed double-cone photoreceptors are visualized.

Development of a 300,000-pixel ultrahigh-speed high-sensitivity CCD

NASA Astrophysics Data System (ADS)

Ohtake, H.; Hayashida, T.; Kitamura, K.; Arai, T.; Yonai, J.; Tanioka, K.; Maruyama, H.; Etoh, T. Goji; Poggemann, D.; Ruckelshausen, A.; van Kuijk, H.; Bosiers, Jan T.

2006-02-01

We are developing an ultrahigh-speed, high-sensitivity broadcast camera that is capable of capturing clear, smooth slow-motion videos even where lighting is limited, such as at professional baseball games played at night. In earlier work, we developed an ultrahigh-speed broadcast color camera1) using three 80,000-pixel ultrahigh-speed, highsensitivity CCDs2). This camera had about ten times the sensitivity of standard high-speed cameras, and enabled an entirely new style of presentation for sports broadcasts and science programs. Most notably, increasing the pixel count is crucially important for applying ultrahigh-speed, high-sensitivity CCDs to HDTV broadcasting. This paper provides a summary of our experimental development aimed at improving the resolution of CCD even further: a new ultrahigh-speed high-sensitivity CCD that increases the pixel count four-fold to 300,000 pixels.

Geochemical and tectonic implications on plate-interface evolution achieved from high-pressure ultramafic rocks in mélange settings

NASA Astrophysics Data System (ADS)

Cannaò, E.; Agostini, S.; Scambelluri, M.; Tonarini, S.

2014-12-01

Geochemical studies of fluid-mobile elements (FME) joined with B, Sr and Pb isotopic analyses of high-pressure mélanges terranes help constraining tectonic processes and mass transfer during accretion of slab and suprasubduction mantle in plate-interface domains. Here we focus on ultramafic rocks from two plate interface settings: (I) metasediment-dominated mélange (Cima di Gagnone, CdG, Adula Unit), where eclogite-facies de-serpentinized garnet peridotite and chlorite harzburgite lenses are embedded in paraschist; (II) dominated by high-pressure serpentinite (Erro-Tobbio, ET, and Voltri Units, VU, Ligurian Alps). CdG metaperidotite shows low [B], negative δ 11B and high Sr and Pb isotopic ratios. As, Sb loss from metasediment and gain by garnet and chlorite metaperidotite points to exchange between the two systems. Presence of As and Sb in eclogite-facies peridotite minerals and preferential low-T mobility of such elements suggest that exchange was during early subduction burial and prior to eclogitization. Based on high [B], positive δ11B, oxygen and hydrogen isotope, the ET serpentinties were recently interpreted as supra-subduction mantle flushed by slab fluids (Scambelluri & Tonarini, 2012, Geology, 40, 907-910). Their 206Pb/204Pb and 87Sr/86Sr isotope ratios range between 18.300-18.514 and 0.7048-0.7060, respectively. Compared with ET rocks, VU serpentinites have higher As, Sb (up to 1.3 and 0.39 ppm, respectively) and are enriched in radiogenic Sr (up to 0.7105 87Sr/86Sr). This signature reflects interaction with fluids that exchanged with sedimentary rocks, either in outer rise environments or during accretion atop the slab. In the above cases, the serpentinized mantle rocks fingerprint interaction with fluids from different sources, indicating a timing of accretion to plate interface domains. We provide evidence that serpentinized mantle slices of different size and provenance (slab or wedge) accreted to plate interface domains since early subduction

Effects of ultrahigh pressure extraction on yield and antioxidant activity of chlorogenic acid and cynaroside extracted from flower buds of Lonicera japonica.

PubMed

Hu, Wen; Guo, Ting; Jiang, Wen-Jun; Dong, Guang-Li; Chen, Da-Wei; Yang, Shi-Lin; Li, He-Ran

2015-06-01

The present study was designed to establish and optimize a new method for extracting chlorogenic acid and cynaroside from Lonicera japonica Thunb. through orthogonal experimental designl. A new ultrahigh pressure extraction (UPE) technology was applied to extract chlorogenic acid and cynaroside from L. japonica. The influential factors, including solvent type, ethanol concentration, extraction pressure, time, and temperature, and the solid/liquid ratio, have been studied to optimize the extraction process. The optimal conditions for the UPE were developed by quantitative analysis of the extraction products by HPLC-DAD in comparison with standard samples. In addition, the microstructures of the medicinal materials before and after extraction were studied by scanning electron microscopy (SEM). Furthermore, the extraction efficiency of different extraction methods and the 2, 2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activities of the extracts were investigated. The optimal conditions for extracting chlorogenic acid and cynaroside were as follows: ethanol concentration, 60%; extraction pressure, 400 MPa; extraction time, 2 min; extraction temperature, 30 °C; and the solid/liquid ratio, 1 : 50. Under these conditions, the yields of chlorogenic acid and cynaroside were raised to 4.863% and 0.080%, respectively. Compared with other extraction methods, such as heat reflux extraction (HRE), ultrasonic extraction (UE), and Sohxlet extraction (SE), the UPE method showed several advantages, including higher extraction yield, shorter extraction time, lower energy consumption, and higher purity of the extracts. This study could help better utilize L. japonica flower buds as a readily accessible source of natural antioxidants in food and pharmaceutical industries. Copyright © 2015 China Pharmaceutical University. Published by Elsevier B.V. All rights reserved.

A Multi-physics Approach to Understanding Low Porosity Soils and Reservoir Rocks

NASA Astrophysics Data System (ADS)

Prasad, M.; Mapeli, C.; Livo, K.; Hasanov, A.; Schindler, M.; Ou, L.

2017-12-01

We present recent results on our multiphysics approach to rock physics. Thus, we evaluate geophysical measurements by simultaneously measuring petrophysical properties or imaging strains. In this paper, we present simultaneously measured acoustic and electrical anisotropy data as functions of pressure. Similarly, we present strains and strain localization images simultaneously acquired with acoustic measurements as well as NMR T2 relaxations on pressurized fluids as well as rocks saturated with these pressurized fluids. Such multiphysics experiments allow us to constrain and assign appropriate causative mechanisms to development rock physics models. They also allow us to decouple various effects, for example, fluid versus pressure, on geophysical measurements. We show applications towards reservoir characterization as well as CO2 sequestration applications.

Some observations on the mechanism of aircraft wing rock

NASA Technical Reports Server (NTRS)

Hwang, C.; Pi, W. S.

1979-01-01

A scale model of the Northrop F-5A was tested in NASA Ames Research Center Eleven-Foot Transonic Tunnel to simulate the wing rock oscillations in a transonic maneuver. For this purpose, a flexible model support device was designed and fabricated, which allowed the model to oscillate in roll at the scaled wing rock frequency. Two tunnel entries were performed to acquire the pressure (steady state and fluctuating) and response data when the model was held fixed and when it was excited by flow to oscillate in roll. Based on these data, a limit cycle mechanism was identified, which supplied energy to the aircraft model and caused the Dutch roll type oscillations, commonly called wing rock. The major origin of the fluctuating pressures that contributed to the limit cycle was traced to the wing surface leading edge stall and the subsequent lift recovery. For typical wing rock oscillations, the energy balance between the pressure work input and the energy consumed by the model's aerodynamic and mechanical damping was formulated and numerical data presented.

Hydromechanical coupling in fractured rock masses: mechanisms and processes of selected case studies

NASA Astrophysics Data System (ADS)

Zangerl, Christian

2015-04-01

Hydromechanical (HM) coupling in fractured rock play an important role when events including dam failures, landslides, surface subsidences due to water withdrawal or drainage, injection-induced earthquakes and others are analysed. Generally, hydromechanical coupling occurs when a rock mass contain interconnected pores and fractures which are filled with water and pore/fracture pressures evolves. In the on hand changes in the fluid pressure can lead to stress changes, deformations and failures of the rock mass. In the other hand rock mass stress changes and deformations can alter the hydraulic properties and fluid pressures of the rock mass. Herein well documented case studies focussing on surface subsidence due to water withdrawal, reversible deformations of large-scale valley flanks and failure as well as deformation processes of deep-seated rock slides in fractured rock masses are presented. Due to pore pressure variations HM coupling can lead to predominantly reversible rock mass deformations. Such processes can be considered by the theory of poroelasticity. Surface subsidence reaching magnitudes of few centimetres and are caused by water drainage into deep tunnels are phenomenas which can be assigned to processes of poroelasticity. Recently, particular focus was given on large tunnelling projects to monitor and predict surface subsidence in fractured rock mass in oder to avoid damage of surface structures such as dams of large reservoirs. It was found that surface subsidence due to tunnel drainage can adversely effect infrastructure when pore pressure drawdown is sufficiently large and spatially extended and differential displacements which can be amplified due to topographical effects e.g. valley closure are occurring. Reversible surface deformations were also ascertained on large mountain slopes and summits with the help of precise deformation measurements i.e. permanent GPS or episodic levelling/tacheometric methods. These reversible deformations are often

Fluid-induced Crystallization of Majoritic Garnet During Deep Continental Subduction (Western Gneiss Region, Norway)

NASA Astrophysics Data System (ADS)

Scambelluri, M.; Pettke, T.; van Roermund, H. L.

2008-12-01

In ultrahigh pressure (UHP) rocks, garnet containing pyroxene exsolutions derives from breakdown of majorite crystallized at depths > 200 km. Presence of microdiamonds in some of these rocks [1], including those of the Western Gneiss Region (WGR) of Norway [2], may suggest a fluid-bearing environment for the genesis of majorite. The WGR UHP gneisses host garnet peridotite and websterite recording uplift from extraordinary depths prior to uptake in a subducting slab [2]. These ultramafic rocks (islands of Otrøy and Bardane) derive from depleted Archean transition-zone mantle (350 km depth) upwelled and accreted to a cratonic lithosphere (M2 stage). Evidence for this are decimetric garnets (grt) preserved in Otrøy, hosting up to 20 volume% orthopyroxene (opx) and clinopyroxene (cpx) exsolved from precursor majoritic garnet (M1 stage). The pyroxene lamellae (20-30 ¥ìm thick, hundreds of ¥ìm long) [3] were exsolved under high-T, as shown by the garnet/cpx REE distribution [4]. This Archean-mid Proterozoic record is overprinted by the 425- 390 Ma Scandian continental subduction (M3 stage), forming new grt + cpx + opx + phlogopite (phl) + spinel (sp) that contain diamond-bearing micro-inclusions witnessing deep COH subduction fluids [2]. Here we document formation of new majoritic garnet in the M3 assemblage and in veins at Bardane [5]. Textural characteristics, together with the LREE and LILE enrichments of the M3 minerals, indicate that the new majorite is linked to infiltration of subduction fluids during renewed burial towards sub-lithospheric depths. It represents the deepest occurrence of fluid-related microstructures in mantle rocks. The new majoritic garnet crystallized at grain boundaries and in micro-veins at 7 Gpa and 900-1000 °C. It hosts thin pyroxene needles (5 mm thick, 100 mm long) exsolved under comparatively low-T, as indicated by the garnet/cpx REE distribution. The trace element signature of the majorite-bearing subduction assemblage is LREE

Petrofabrics of high-pressure rocks exhumed at the slab-mantle interface from the "point of no return" in a subduction zone (Sivrihisar, Turkey)

NASA Astrophysics Data System (ADS)

Whitney, Donna L.; Teyssier, Christian; Seaton, Nicholas C. A.; Fornash, Katherine F.

2014-12-01

The highest pressure recorded by metamorphic rocks exhumed from oceanic subduction zones is 2.5 GPa, corresponding to the maximum decoupling depth (MDD) (80 ± 10 km) identified in active subduction zones; beyond the MDD (the "point of no return") exhumation is unlikely. The Sivrihisar massif (Turkey) is a coherent terrane of lawsonite eclogite and blueschist facies rocks in which assemblages and fabrics record P-T-fluid-deformation conditions during exhumation from 80 to 45 km. Crystallographic fabrics and other features of high-pressure metasedimentary and metabasaltic rocks record transitions during exhumation. In quartzite, microstructures and crystallographic fabrics record deformation in the dislocation creep regime, including dynamic recrystallization during decompression, and a transition from prism slip to activation of rhomb and basal slip that may be related to a decrease in water fugacity during decompression ( 2.5 to 1.5 GPa). Phengite, lawsonite, and omphacite or glaucophane in quartzite and metabasalt remained stable during deformation, and omphacite developed an L-type crystallographic fabric. In marble, aragonite developed columnar textures with strong crystallographic fabrics that persisted during partial to complete dynamic recrystallization that was likely achieved in the stability field of aragonite (P > 1.2 GPa). Results of kinematic vorticity analysis based on lawsonite shape fabrics are consistent with shear criteria in quartzite and metabasalt and indicate a large component of coaxial deformation in the exhuming channel beneath a simple shear dominated interface. This large coaxial component may have multiplied the exhuming power of the subduction channel and forced deeply subducted rocks to flow back from the point of no return.

Ultrahigh-Resolution Optical Coherence Tomography in Glaucoma

PubMed Central

Wollstein, Gadi; Paunescu, Leila A.; Ko, Tony H.; Fujimoto, James G.; Kowalevicz, Andrew; Hartl, Ingmar; Beaton, Siobahn; Ishikawa, Hiroshi; Mattox, Cynthia; Singh, Omah; Duker, Jay; Drexler, Wolfgang; Schuman, Joel S.

2007-01-01

Objective Optical coherence tomography (OCT) has been shown to be a valuable tool in glaucoma assessment. We investigated a new ultrahigh-resolution OCT (UHR-OCT) imaging system in glaucoma patients and compared the findings with those obtained by conventional-resolution OCT. Design Retrospective comparative case series. Participants A normal subject and 4 glaucoma patients representing various stages of glaucomatous damage. Testing All participants were scanned with StratusOCT (axial resolution of ~10 μm) and UHR-OCT (axial resolution of ~3 μm) at the same visit. Main Outcome Measure Comparison of OCT findings detected with StratusOCT and UHR-OCT. Results Ultrahigh-resolution OCT provides a detailed cross-sectional view of the scanned retinal area that allows differentiation between retinal layers. These UHR images were markedly better than those obtained by the conventional-resolution OCT. Conclusions Ultrahigh-resolution OCT provides high-resolution images of the ocular posterior segment, which improves the ability to detect retinal abnormalities due to glaucoma. PMID:15691556

Experimental Investigation of the Influence of Confining Stress on Hard Rock Fragmentation Using a Conical Pick

NASA Astrophysics Data System (ADS)

Li, Xibing; Wang, Shaofeng; Wang, Shanyong

2018-01-01

High geostress is a prominent condition in deep excavations and affects the cuttability of deep hard rock. This study aims to determine the influence of confining stress on hard rock fragmentation as applied by a conical pick. Using a true triaxial test apparatus, static and coupled static and dynamic loadings from pick forces were applied to end faces of cubic rock specimens to break them under biaxial, uniaxial and stress-free confining stress conditions. The cuttability indices (peak pick force, insertion depth and disturbance duration), failure patterns and fragment sizes were measured and compared to estimate the effects of confining stress. The results show that the rock cuttabilities decreased in order from rock breakages under stress-free conditions to uniaxial confining stress and then to biaxial confining stress. Under biaxial confining stress, only flake-shaped fragments were stripped from the rock surfaces under the requirements of large pick forces or disturbance durations. As the level of uniaxial confining stress increased, the peak pick force and the insertion depth initially increased and then decreased, and the failure patterns varied from splitting to partial splitting and then to rock bursts with decreasing average fragment sizes. Rock bursts will occur under elastic compression via ultra-high uniaxial confining stresses. There are two critical uniaxial confining stress levels, namely stress values at which peak pick forces begin to decrease and improve rock cuttability, and those at which rock bursts initially occur and cutting safety decreases. In particular, hard rock is easiest to split safely and efficiently under stress-free conditions. Moreover, coupled static preloading and dynamic disturbance can increase the efficiency of rock fragmentation with increasing preloading levels and disturbance amplitudes. The concluding remarks confirm hard rock cuttability using conical pick, which can improve the applicability of mechanical excavation in

GRAAL - Griggs-type Apparatus equipped with Acoustics in the Laboratory: a new instrument to explore the rheology of rocks at high pressure

NASA Astrophysics Data System (ADS)

Schubnel, A.; Champallier, R.; Precigout, J.; Pinquier, Y.; Ferrand, T. P.; Incel, S.; Hilairet, N.; Labrousse, L.; Renner, J.; Green, H. W., II; Stunitz, H.; Jolivet, L.

2015-12-01

Two new generation solid-medium Griggs-type apparatus have been set up at the Laboratoire de Géologie of ENS PARIS, and the Institut des Sciences de la Terre d'Orléans (ISTO). These new set-ups allow to perform controlled rock deformation experiments on large volume samples, up to 5 GPa and 1300°C. Careful pressure - stress calibration will be performed (using D-DIA and/or Paterson-type experiments as standards), strain-stress-pressure will be measured using modern techniques and state of the art salt assemblies. Focusing on rheology, the pressure vessel at ISTO has been designed in a goal of deforming large sample diameter (8 mm) at confining pressure of up to 3 GPa. Thanks to this large sample size, this new vessel will allow to explore the microstructures related to the deformation processes occurring at pressures of the deep lithosphere and in subduction zones. In this new apparatus, we moreover included a room below the pressure vessel in order to develop a basal load cell as close as possible to the sample. This new design, in progress, aims at significantly improving the accuracy of stress measurements in the Griggs-type apparatus. The ultimate goal is to set up a new technique able to routinely quantify the rheology of natural rocks between 0.5 and 5 GPa. Although fundamental to document the rheology of the lithosphere, such a technique is still missing in rock mechanics. Focusing on the evolution of physical and mechanical properties during mineral phase transformations, the vessel at ENS is equipped with continuous acoustic emission (AE) multi-sensor monitoring in order to "listen" to the sample during deformation. Indeed, these continuous recordings enable to detect regular AE like signals during dynamic crack propagation, as well as non-impulsive signals, which might be instrumental to identify laboratory analogs to non-volcanic tremor and low frequency earthquake signals. P and S elastic wave velocities will also be measured contemporaneously during

The development of a portable ultrahigh vacuum chamber via silicon block.

PubMed

Chuang, Ho-Chiao; Huang, Chia-Shiuan

2014-05-01

This paper describes a nonmetallic, light weight portable chamber for ultra-high vacuum (UHV) applications. The chamber consists of a processed silicon block anodically bonding five polished Pyrex glass windows and a Pyrex glass adapter, without using any screws, bolts or vacuum adhesives. The design features provide an alternative chamber for UHV applications which require nonmetallic components. We have cyclically baked the chamber up to 180 °C for 160 h and have achieved an ultimate pressure of 1.4 × 10(-9) Torr (limited by our pumping station), with no leak detected. Both Pyrex glass windows and Pyrex glass adapter have been used successfully.

New petrological and age data from the eclogite province in the central segment of the Greenlandic Caledonides

NASA Astrophysics Data System (ADS)

Nagel, Thorsten; Fassmer, Kathrin; Froitzheim, Niko; Fonseca, Raul; Sprung, Peter

2017-04-01

The Caledonian orogen in northeastern Greenland is a 1200 km long, west-vergent nappe pile mirroring the much better explored Caledonides in Scandinavia. The Greenlandic orogen has traditionally been viewed as the retro-wedge of the Scandinavian Caledonides, which is generally accepted to be the result of west-directed subduction of the Iapetus oceanic realm and the Baltic continental margin. This concept, however, is challenged by the finding of widely distributed high-pressure metamorphism as well as the large amount of horizontal shortening accommodated in the Greenlandic nappe pile (Gasser 2014, and references therein). While eclogites in Liverpool Land in the very south have been interpreted to belong to a window into Baltica, the vast domains of eclogite-bearing basement in the central segment of the orogen are attributed to the Lauretian continental margin. Existing ages for high-pressure metamorphism in this area using U-Pb-zircon and Sm-Nd-garnet dating scatter at 420-390 Ma with an exceptionally young age of 370-330 Ma found for the so far only ultrahigh-pressure location in a very internal position of the orogen (e.g. Gilotti et al. 2004). Eclogite-facies metamorphism in Greenland seems thus coeval to or even younger than the main Scandian orogeny in Scandinavia. However, the relatively high temperatures of metamorphism leave room for the interpretation of the Sm-Nd ages as cooling ages. We present petrologic and Lu-Hf-garnet-age data from three locations in the central eclogite province in Greenland and discuss the implications for tectonic scenarios. Investigated rocks are high-temperature eclogites/high-pressure mafic granulites, and garnet pyroxenites. Samples from the well-known location Danmarkshavn record ultra-high-pressure metamorphic conditions by means of SiO2-exsolutions in clinopyroxene and thermobarometric results. An eclogite yielded a Lu-Hf garnet-whole-rock age of 360 Ma thus confirming the existing young age for ultrahigh-pressure

Ultra High Pressure (UHP) Technology (BRIEFING SLIDES)

DTIC Science & Technology

2008-08-25

to operate in close (15 to 30 ft) proximity to burning JP 8 fuel. In these experiments, three to four gallons of 3% Aqueous Film Forming Foam ( AFFF ...technology provides more that 20X improvement in performance. 5 Steam Formation and Foam / Film capping are also major contributors to the extinguishing...insulates the fuel from the flames and acts as a thermal radiation barrier. In addition, the foam puts a film of water on top of the fuel, sealing the

An ionization gauge for ultrahigh vacuum measurement based on a carbon nanotube cathode

NASA Astrophysics Data System (ADS)

Zhang, Huzhong; Cheng, Yongjun; Sun, Jian; Wang, Yongjun; Xi, Zhenhua; Dong, Meng; Li, Detian

2017-10-01

This work reports on the complete design and the properties of an ionization gauge based on a carbon nanotube cathode, which can measure ultrahigh vacuum without thermal effects. The gauge is composed of a pressure sensor and an electronic controller. This pressure sensor is constructed based on a hot-cathode ionization gauge, where the traditional hot filament is replaced by an electron source prepared with multi-wall nanotubes. Besides, an electronic controller was developed for bias voltage supply, low current detection, and pressure indication. The gauge was calibrated in the pressure range of 10-8 to 10-4 Pa in a XHV/UHV calibration apparatus. The gauge shows good linear characteristics in different gases. The calibrated sensitivity is 0.035 Pa-1 in N2, and the standard deviation of the sensitivity is about 1.1%. In addition, the stability of the sensitivity was learned in a long period. The standard deviation of the sensitivity factor "S" during one year is 2.0% for Ar and 1.6% for N2.

Coal-rock interface detector

NASA Technical Reports Server (NTRS)

Rose, S. D.; Crouch, C. E.; Jones, E. W. (Inventor)

1979-01-01

A coal-rock interface detector is presented which employs a radioactive source and radiation sensor. The source and sensor are separately and independently suspended and positioned against a mine surface of hydraulic pistons, which are biased from an air cushioned source of pressurized hydraulic fluid.

Evaluation between ultrahigh pressure liquid chromatography and high-performance liquid chromatography analytical methods for characterizing natural dyestuffs.

PubMed

Serrano, Ana; van Bommel, Maarten; Hallett, Jessica

2013-11-29

An evaluation was undertaken of ultrahigh pressure liquid chromatography (UHPLC) in comparison to high-performance liquid chromatography (HPLC) for characterizing natural dyes in cultural heritage objects. A new UHPLC method was optimized by testing several analytical parameters adapted from prior UHPLC studies developed in diverse fields of research. Different gradient elution programs were tested on seven UHPLC columns with different dimensions and stationary phase compositions by applying several mobile phases, flow rates, temperatures, and runtimes. The UHPLC method successfully provided more improved data than that achieved by the HPLC method. Indeed, even though carminic acid has shown circa 146% higher resolution with HPLC, UHPLC resulted in an increase of 41-61% resolution and a decrease of 91-422% limit of detection, depending on the dye compound. The optimized method was subsequently assigned to analyse 59 natural reference materials, in which 85 different components were ascribed with different physicochemical properties, in order to create a spectral database for future characterization of dyes in cultural heritage objects. The majority of these reference samples could be successfully distinguished with one single method through the examination of these compounds' retention times and their spectra acquired with a photodiode array detector. These results demonstrate that UHPLC analyses are extremely valuable for the acquisition of more precise chromatographic information concerning natural dyes with complex mixtures of different and/or closely related physicochemical properties, essential for distinguishing similar species of plants and animals used to colour cultural heritage objects. Copyright © 2013 Elsevier B.V. All rights reserved.

Recycling of ancient subduction-modified mantle domains in the Purang ophiolite (southwestern Tibet)

NASA Astrophysics Data System (ADS)

Gong, Xiao-Han; Shi, Ren-Deng; Griffin, W. L.; Huang, Qi-Shuai; Xiong, Qing; Chen, Sheng-Sheng; Zhang, Ming; O'Reilly, Suzanne Y.

2016-10-01

Ophiolites in the Indus-Yarlung Zangbo (IYZ) suture (southern Tibet) have been interpreted as remnants of the Neo-Tethyan lithosphere. However, the discovery of diamonds and super-reducing, ultra-high pressure (SuR-UHP) mineral assemblages (e.g., coesite after stishovite, olivine after wadsleyite, native metals, alloys, and moissanite) in some of these massifs and associated chromitites requires a re-evaluation of their origin and evolution. A new petrological and geochemical study of the Purang ophiolite in the western IYZ suture sheds new lights on these issues. The depleted harzburgites of the Purang massif have low modal contents of clinopyroxene (< 2%), and high Cr# [100*Cr3 +/(Cr3 + + Al3 +)] in spinel (> 40 70) and pyroxenes (> 16 in orthopyroxene, and > 20 in clinopyroxene), suggesting high degrees of melt extraction (> 20%). These features are not consistent with formation in a (ultra-) slow-spreading mid-ocean ridge. These peridotites have high modal contents of orthopyroxene; this, and the extremely high Cr# of spinels in these peridotites, suggests modification in a subduction zone. The clinopyroxene-rich harzburgites and lherzolites contain rare spinel-pyroxene symplectites after garnet. Their clinopyroxenes have low MREE-to-HREE ratios ((Sm/Yb)N < 0.1) at relatively high HREE concentrations, and are Na-rich but Nd-poor. The relatively enrichment of Na but depletion of Nd in clinopyroxene cannot be explained by refertilization with MORB melts but are consistent with an origin from Na-rich subcontinental lithospheric mantle (SCLM). All lines of evidence suggest that these peridotites underwent initial melting in the stability field of garnet-facies peridotites, followed by additional melting in the spinel-facies mantle. Whole-rock Os isotopic compositions of the Purang peridotites give ancient TRD model ages (up to 1.3 Ga), indicating that the formation of these ancient depletion residues predated the opening of Neo-Tethyan Ocean. These observations

Poisson's Ratio and Auxetic Properties of Natural Rocks

NASA Astrophysics Data System (ADS)

Ji, Shaocheng; Li, Le; Motra, Hem Bahadur; Wuttke, Frank; Sun, Shengsi; Michibayashi, Katsuyoshi; Salisbury, Matthew H.

2018-02-01

Here we provide an appraisal of the Poisson's ratios (υ) for natural elements, common oxides, silicate minerals, and rocks with the purpose of searching for naturally auxetic materials. The Poisson's ratios of equivalently isotropic polycrystalline aggregates were calculated from dynamically measured elastic properties. Alpha-cristobalite is currently the only known naturally occurring mineral that has exclusively negative υ values at 20-1,500°C. Quartz and potentially berlinite (AlPO4) display auxetic behavior in the vicinity of their α-β structure transition. None of the crystalline igneous and metamorphic rocks (e.g., amphibolite, gabbro, granite, peridotite, and schist) display auxetic behavior at pressures of >5 MPa and room temperature. Our experimental measurements showed that quartz-rich sedimentary rocks (i.e., sandstone and siltstone) are most likely to be the only rocks with negative Poisson's ratios at low confining pressures (≤200 MPa) because their main constituent mineral, α-quartz, already has extremely low Poisson's ratio (υ = 0.08) and they contain microcracks, micropores, and secondary minerals. This finding may provide a new explanation for formation of dome-and-basin structures in quartz-rich sedimentary rocks in response to a horizontal compressional stress in the upper crust.

Application of ultra-high pressure liquid chromatography linear ion-trap orbitrap to qualitative and quantitative assessment of pesticide residues.

PubMed

Farré, M; Picó, Y; Barceló, D

2014-02-07

The analysis of pesticides residues using a last generation high resolution and high mass accuracy hybrid linear ion trap-Orbitrap mass spectrometer (LTQ-Orbitrap-MS) was explored. Pesticides were extracted from fruits, fish, bees and sediments by QuEChERS and from water by solid-phase with Oasis HLB cartridges. Ultra-high pressure liquid chromatography (UHPLC)-LTQ-Orbitrap mass spectrometer acquired full scan MS data for quantification, and data dependent (dd) MS(2) and MS(3) product ion spectra for identification and/or confirmation. The regression coefficients (r(2)) for the calibration curves (two order of magnitude up to the lowest calibration level) in the study were ≥0.99. The LODs for 54 validated compounds were ≤2ngmL(-1) (analytical standards). The relative standard deviation (RSD), which was used to estimate precision, was always lower than 22%. The recovery of extraction and matrix effects ranged from 58 to 120% and from -92 to 52%, respectively. Mass accuracy was always ≤4ppm, corresponding to a maximum mass error of 1.6millimass units (mmu). This procedure was then successfully applied to pesticide residues in a set of the above-mentioned food and environmental samples. In addition to target analytes, this method enables the simultaneous detection/identification of non-target pesticides, pharmaceuticals, drugs of abuse, mycotoxins, and their metabolites. Copyright © 2013 Elsevier B.V. All rights reserved.

Analytical interference of 4-hydroxy-3-methoxymethamphetamine with the measurement of plasma free normetanephrine by ultra-high pressure liquid chromatography-tandem mass spectrometry.

PubMed

Dunand, Marielle; Donzelli, Massimiliano; Rickli, Anna; Hysek, Cédric M; Liechti, Matthias E; Grouzmann, Eric

2014-08-01

The diagnosis of pheochromocytoma relies on the measurement of plasma free metanephrines assay whose reliability has been considerably improved by ultra-high pressure liquid chromatography tandem mass spectrometry (UHPLC-MS/MS). Here we report an analytical interference occurring between 4-hydroxy-3-methoxymethamphetamine (HMMA), a metabolite of 3,4-methylenedioxymethamphetamine (MDMA, "Ecstasy"), and normetanephrine (NMN) since they share a common pharmacophore resulting in the same product ion after fragmentation. Synthetic HMMA was spiked into plasma samples containing various concentrations of NMN and the intensity of the interference was determined by UPLC-MS/MS before and after improvement of the analytical method. Using a careful adjustment of chromatographic conditions including the change of the UPLC analytical column, we were able to distinguish both compounds. HMMA interference for NMN determination should be seriously considered since MDMA activates the sympathetic nervous system and if confounded with NMN may lead to false-positive tests when performing a differential diagnostic of pheochromocytoma. Copyright © 2014 The Canadian Society of Clinical Chemists. Published by Elsevier Inc. All rights reserved.

Experimental petrology and origin of Fra Mauro rocks and soil

NASA Technical Reports Server (NTRS)

Walker, D.; Longhi, J.; Hays, J. F.

1972-01-01

Melting experiments over the pressure range 0 to 20 kilobars were conducted on Apollo 14 igneous rocks 14310 and 14072 and on comprehensive fines 14259. The mineralogy and textures of rocks 14310 and 14072 are presumed to be the result of near-surface crystallization. The chemical compositions of the samples show special relationships to multiply-saturated liquids in the system: anorthite-forsterite-fayalite-silica at low pressure. Partial melting of a lunar crust consisting largely of plagioclase, low calcium pyroxene, and olivine, followed by crystal fractionation at the lunar surface is proposed as a mechanism for the production of the igneous rocks and soil glasses sampled by Apollo 14.

On the effective stress law for rock-on-rock frictional sliding, and fault slip triggered by means of fluid injection.

PubMed

Rutter, Ernest; Hackston, Abigail

2017-09-28

Fluid injection into rocks is increasingly used for energy extraction and for fluid wastes disposal, and can trigger/induce small- to medium-scale seismicity. Fluctuations in pore fluid pressure may also be associated with natural seismicity. The energy release in anthropogenically induced seismicity is sensitive to amount and pressure of fluid injected, through the way that seismic moment release is related to slipped area, and is strongly affected by the hydraulic conductance of the faulted rock mass. Bearing in mind the scaling issues that apply, fluid injection-driven fault motion can be studied on laboratory-sized samples. Here, we investigate both stable and unstable induced fault slip on pre-cut planar surfaces in Darley Dale and Pennant sandstones, with or without granular gouge. They display contrasting permeabilities, differing by a factor of 10 5 , but mineralogies are broadly comparable. In permeable Darley Dale sandstone, fluid can access the fault plane through the rock matrix and the effective stress law is followed closely. Pore pressure change shifts the whole Mohr circle laterally. In tight Pennant sandstone, fluid only injects into the fault plane itself; stress state in the rock matrix is unaffected. Sudden access by overpressured fluid to the fault plane via hydrofracture causes seismogenic fault slips.This article is part of the themed issue 'Faulting, friction and weakening: from slow to fast motion'. © 2017 The Authors.

On the effective stress law for rock-on-rock frictional sliding, and fault slip triggered by means of fluid injection

NASA Astrophysics Data System (ADS)

Rutter, Ernest; Hackston, Abigail

2017-08-01

Fluid injection into rocks is increasingly used for energy extraction and for fluid wastes disposal, and can trigger/induce small- to medium-scale seismicity. Fluctuations in pore fluid pressure may also be associated with natural seismicity. The energy release in anthropogenically induced seismicity is sensitive to amount and pressure of fluid injected, through the way that seismic moment release is related to slipped area, and is strongly affected by the hydraulic conductance of the faulted rock mass. Bearing in mind the scaling issues that apply, fluid injection-driven fault motion can be studied on laboratory-sized samples. Here, we investigate both stable and unstable induced fault slip on pre-cut planar surfaces in Darley Dale and Pennant sandstones, with or without granular gouge. They display contrasting permeabilities, differing by a factor of 105, but mineralogies are broadly comparable. In permeable Darley Dale sandstone, fluid can access the fault plane through the rock matrix and the effective stress law is followed closely. Pore pressure change shifts the whole Mohr circle laterally. In tight Pennant sandstone, fluid only injects into the fault plane itself; stress state in the rock matrix is unaffected. Sudden access by overpressured fluid to the fault plane via hydrofracture causes seismogenic fault slips. This article is part of the themed issue 'Faulting, friction and weakening: from slow to fast motion'.

On the effective stress law for rock-on-rock frictional sliding, and fault slip triggered by means of fluid injection

PubMed Central

Hackston, Abigail

2017-01-01

Fluid injection into rocks is increasingly used for energy extraction and for fluid wastes disposal, and can trigger/induce small- to medium-scale seismicity. Fluctuations in pore fluid pressure may also be associated with natural seismicity. The energy release in anthropogenically induced seismicity is sensitive to amount and pressure of fluid injected, through the way that seismic moment release is related to slipped area, and is strongly affected by the hydraulic conductance of the faulted rock mass. Bearing in mind the scaling issues that apply, fluid injection-driven fault motion can be studied on laboratory-sized samples. Here, we investigate both stable and unstable induced fault slip on pre-cut planar surfaces in Darley Dale and Pennant sandstones, with or without granular gouge. They display contrasting permeabilities, differing by a factor of 105, but mineralogies are broadly comparable. In permeable Darley Dale sandstone, fluid can access the fault plane through the rock matrix and the effective stress law is followed closely. Pore pressure change shifts the whole Mohr circle laterally. In tight Pennant sandstone, fluid only injects into the fault plane itself; stress state in the rock matrix is unaffected. Sudden access by overpressured fluid to the fault plane via hydrofracture causes seismogenic fault slips. This article is part of the themed issue ‘Faulting, friction and weakening: from slow to fast motion’. PMID:28827423

The Chemical Behavior of Fluids Released during Deep Subduction Based on Fluid Inclusions

NASA Astrophysics Data System (ADS)

Frezzotti, M. L.; Ferrando, S.

2014-12-01

We present a review of current research on fluid inclusions in (HP-) UHP metamorphic rocks that, combined with existing experimental research and thermodynamic models, allow us to investigate the chemical and physical properties of fluids released during deep subduction, their solvent and element transport capacity, and the subsequent implications for the element recycling in the mantle wedge. An impressive number of fluid inclusion studies indicate three main populations of fluid inclusions in HP and UHP metamorphic rocks: i) aqueous and/or non-polar gaseous fluid inclusions (FI), ii) multiphase solid inclusions (MSI), and iii) melt inclusions (MI). Chemical data from preserved fluid inclusions in rocks match with and implement "model" fluids by experiments and thermodynamics, revealing a continuity behind the extreme variations of physico-chemical properties of subduction-zone fluids. From fore-arc to sub-arc depths, fluids released by progressive devolatilization reactions from slab lithologies change from relatively diluted chloride-bearing aqueous solutions (± N2), mainly influenced by halide ligands, to (alkali) aluminosilicate-rich aqueous fluids, in which polymerization probably governs the solubility and transport of major (e.g., Si and Al) and trace elements (including C). Fluid inclusion data implement the petrological models explaining deep volatile liberation in subduction zones, and their flux into the mantle wedge.

Water permeability of nanoporous graphene at realistic pressures for reverse osmosis desalination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cohen-Tanugi, David; Grossman, Jeffrey C.

Nanoporous graphene (NPG) shows tremendous promise as an ultra-permeable membrane for water desalination thanks to its atomic thickness and precise sieving properties. However, a significant gap exists in the literature between the ideal conditions assumed for NPG desalination and the physical environment inherent to reverse osmosis (RO) systems. In particular, the water permeability of NPG has been calculated previously based on very high pressures (1000–2000 bars). Does NPG maintain its ultrahigh water permeability under real-world RO pressures (<100 bars)? Here, we answer this question by drawing results from molecular dynamics simulations. Our results indicate that NPG maintains its ultrahigh permeabilitymore » even at low pressures, allowing a permeate water flux of 6.0 l/h-bar per pore, or equivalently 1041 ± 20 l/m{sup 2}-h-bar assuming a nanopore density of 1.7 × 10{sup 13} cm{sup −2}.« less

An eclogite-bearing continental tectonic slice in the Zermatt-Saas high-pressure ophiolites at Trockener Steg (Zermatt, Swiss Western Alps)

NASA Astrophysics Data System (ADS)

Weber, Sebastian; Bucher, Kurt

2015-09-01

The Theodul Glacier Unit (TGU) at "Trockener Steg" represents a continental slice, embedded within the ophiolitic Zermatt-Saas Zone. The Zermatt-Saas Zone is the remnant of the Piemonte-Liguria oceanic lithosphere, formed in the middle Jurassic and subducted up to eclogite facies conditions in the Early Tertiary. The close spatial association of the TGU to the Zermatt-Saas Zone permits a comparison of the metamorphic evolution of the units by detailed field mapping and a petrological investigation of eclogites. The eclogites from both tectono-metamorphic units can be clearly distinguished by their textures, mineral assemblages and by mineral and bulk-rock composition. Geothermobarometry and computed assemblage stability diagrams for the TGU eclogites indicate P-T conditions of 2.2 ± 0.1 GPa and 580 ± 50 °C. These derived P-T conditions must be considered as minimum peak metamorphic conditions the rocks achieved during subduction. The P-T data are different from those derived for eclogites of Zermatt-Saas Zone adjacent to the Theodul Glacier Unit, that reached maximal burial depths at 2.3-2.4 GPa and 500 ± 50 °C. While the estimates of the eclogites of Zermatt-Saas Zone are in good agreement with some of the previous studies, the contrasting P-T estimates for the TGU eclogites suggest that the Zermatt-Saas complex must be subdivided into several tectonic subunits. The non-uniform peak conditions over the "Trockener Steg" area and the maximum pressures conditions reported from ultra-high pressure localities within Zermatt-Saas Zone suggest, that individual tectonic slices have been assembled after detachment from the slab at the return-point, i.e. along the exhumation path. Detached packages of rocks may range from small tectonic slices up to several kilometer-sized fragments. The TGU is separated from the surrounding rocks of the ophiolite unit by two major tectonic contacts. In addition, the formation of biotite-rich crusts along the basal contact of the TGU

Influence of Mineralogy, Pressure, Temperature and Stress on Mechanical roperties of shale Rocks

NASA Astrophysics Data System (ADS)

Herrmann, J.; Rybacki, E.; Sone, H.; Dresen, G. H.

2017-12-01

The production of hydrocarbons from unconventional reservoirs, like tight shale plays increased tremendously over the past decade. Hydraulic fracturing is a common method to increase the productivity of a well drilled in these reservoirs. Unfortunately, the production rate decreases over time presumably due to fracture healing. The healing rate induced by proppant embedment depends on pressure (p), temperature (T), stress (σ) - conditions and on shale composition. To improve understanding of the influence of these parameters on fracture healing, we conducted constant strain rate experiments (p = 50 - 100 MPa, T = 50 - 125 °C, ɛ/t = 5 * 10-4 - 5 * 10-6 s-1) on porous ( 8 %), quartz - rich ( 72 vol %) Bowland shale (UK) and on low porosity ( 3 %), clay - rich ( 33 vol %) Posidonia shale (GER), deformed perpendicular to bedding and with as-is water content. Bowland shale showed mainly brittle behaviour with predominantly elastic deformation before failure and a high strength (280 - 350 MPa). In contrast, Posidonia shale deformed semibrittle with pronounced inelastic deformation and low peak strength (165 - 220 MPa). For both shale rocks, static Young's moduli vary between 12 - 18 GPa. In addition, we performed a series of constant stress tests on both shales at p = 30 - 115 MPa, T = 75 - 150 °C and σ = 160 - 450 MPa. Samples showed transient (primary) creep with increasing strain rates for increasing temperature and stress and decreasing pressure. An empirical power law in the form of ɛ = A*tm is used to describe the observed relation between inelastic strain (ɛ) and time (t), where the constant A is mainly affected by temperature and stress and the exponent m accounts for the influence of pressure. Compared to quartz - rich, strong Bowland shale, the creep behaviour of clay - rich, weak Posidonia shale is much more sensitive to changes in pressure, temperature and stress. Electron microscopy suggests that creep was mainly accommodated by deformation of weak

Mechanical study of the Chartreuse Fold-and-Thrust Belt: relationships between fluids overpressure and decollement within the Toarcian source-rock

NASA Astrophysics Data System (ADS)

Berthelon, Josselin; Sassi, William; Burov, Evgueni

2016-04-01

the decollement layer. In turn, with the FLAMAR geo-mechanical models it is shown that for key mechanical parameters within the Chartreuse mechanical stratigraphy (such as friction coefficient, cohesion and viscosity properties), the mechanical boundary conditions to activate, localize and propagate shear thrust in the toarcian source-rock can be found to discuss on the hydro-mechanics of the structural evolution: the very weak mechanical properties that must be attributed to the source-rock to promote the formation of a decollement tend to justify the hypothesis of high fluids pressures in it. In FLAMAR, the evolution of the toarcian source-rock mechanical properties, calibrated on the temperature of kerogen-to-gas transformation, can be introduced to allow its activation as a decollement at a burial threshold. However, without hydro-mechanical coupling, it is not possible to predict where the overpressured regions that localised these changes are positioned. As such, this work also highlights the need for a fully-coupled hydro-mechanical model to further investigate the relationship between fluids and deformations in FTB and accretionary prisms. Burov, E., Francois, T., Yamato, P., & Wolf, S. (2014). Mechanisms of continental subduction and exhumation of HP and UHP rocks. Gondwana Research, 25(2), 464-493. Faille, I., Thibaut, M., Cacas, M.-C., Havé, P., Willien, F., Wolf, S., Agelas, L., Pegaz-Fiornet, S., 2014. Modeling Fluid Flow in Faulted Basins. Oil Gas Sci. Technol. - Rev. d'IFP Energies Nouv. 69, 529-553.

"Fullerene-like" Raman bands in UHP metamorphic diamonds: Metastable intermediate phases for diamond formation

NASA Astrophysics Data System (ADS)

Harada, Y.; Igarashi, M.; Hashiguchi, Y.; Ogasawara, Y.

2011-12-01

Mysterious Raman bands at 1430-1480 cm-1 suggesting carbon (or carbon-bearing) species have been discovered in UHP metamorphic microdiamonds entirely enclosed in dolomite marble from Kokchetav Massif (Igarashi et al., 2011). Such Raman bands first discovered at some domains in a T-type (see Ishida et al., 2003) diamond in dolomite marble in 2005, but we have not reported this because of the possibility of misidentification by contamination. Later, similar bands were also found in the rim and the core of S-type and R-type. The relative intensities of these Raman bands to diamond (at 1332 cm-1) were 10-40 % in average (max. 90-110 %) and FWHMs are broad (25-45 cm-1). The possibility of the appearance of these Raman bands was low. As we used ordinary polished thin sections (thickness: 25 μm) and the organic materials used in thin section making have Raman bands at ca. 1450 cm-1, we carefully examined observed Raman spectra and the positions of the source materials of these bands to exclude the possibility of contaminations. Examined microdiamond grains are entirely enclosed in the host garnet, and no crack was observed in the host. We conducted 2D Raman mappings at different depths with 2 μm intervals. The result showed that the domains having these Raman bands were located within diamond grains and limited area (1-3 μm). These bands were never detected from outside diamond grains (e.g., host garnet). Thus, the unknown Raman bands at 1430-1480 cm-1 were attributed to some materials inside microdiamonds entirely included in the host garnet. The possibility of contamination was denied. Recently, we found similar Raman bands in the microdiamonds in garnet in Grt-Bt gneiss. Examined microdiamonds are entirely enclosed in garnet grain and no extra phase observed near laser spots in these microdiamond grains under an optical microscope. The Raman bands at 1430-1480 cm-1 were found from 4 microdiamond grains. The peak positions and FWHMs of these bands were as follows: (a

Specific Adaptation of Gas Atomization Processing for Al-Based Alloy Powder for Additive Manufacturing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, Iver; Siemon, John

The charge for each gas atomization experiment was provided by Alcoa and consisted of cast blocks cut into 1 inch by 1 inch square rods of the chosen aluminum alloys. The atmosphere in the melting chamber and connected atomization system was evacuated with a mechanical pump prior to backfilling with ultrahigh purity (UHP grade) Ar. The melt was contained in a bottom tapped alumina crucible with an alumina stopper rod to seal the exit while heating to a pouring temperature of 1000 – 1400°C. When the desired superheat was reached, the stopper rod was lifted and melt flowed through pourmore » tube and was atomized with Ar from a 45-22-052-409 gas atomization nozzle (or atomization die), having a jet apex angle of 45 degrees with 22 cylindrical gas jets (each with diameter of 1.32 mm or 0.052 inches) arrayed around the axis of a 10.4 mm central bore. The Ar atomization gas supply regulator pressure was set to produce nozzle manifold pressures for the series of runs at pressures of 250-650 psi. Secondary gas halos of Ar+O 2 and He also were added to the interior of the spray chamber at various downstream locations for additional cooling of the atomized droplets, surface passivation, and to prevent coalescence of the resulting powder.« less

Diamond and Unusual Minerals Discovered from the Chromitite in Polar Ural: A First Report

NASA Astrophysics Data System (ADS)

Yang, J.; Bai, W.; Fang, Q.; Meng, F.; Chen, S.; Zhang, Z.

2007-12-01

Ultrahigh pressure (UHP) minerals, such as diamond, coesite, and pseudomorphs of octahedral olivine, and as well as about 80 other mineral species have been recovered from podiform chromitites of the Luobusa ophiolite, southern Tibet, and a new mineral, Luobusaite (Fe0.82Si2), has been approved recently by CNMMN. The UHP minerals from Luobusa are controversial because they have not found in situ and because ophiolites are currently believed to form at shallow levels above oceanic spreading centers. More detailed study and experimental work are needed to understand the origin and significance of these unusual minerals and investigations of other ophiolites are needed to determine if such minerals occur elsewhere. For this purpose, we collected about 1500 kg of chromitite from two orebodies in an ultramafic body in the Polar Urals. Thus far, more than 60 different mineral species have been separated from these ores. The most exciting discovery is the common occurrence of diamond, a typical UHP mineral in the Luobusa chromitites. Diamonds from Ural chromitite are clear, colorless, well-developed crystals with octahedral morphology, generally 0.2-0.3 mm in size. Attached with the diamonds and perhaps also occurring as inclusions within them are many minerals as chromite, MnNiCrFe alloy, native Si and Ta, corundum, zircon, feldspar, garnet, moissanite, confirming their natural origin and suggesting a long residence time in the mantle. Other mineral group include: (1) native elements: Cr, W, Ni, Co, Si, Al and Ta; (2) carbides: SiC and WC; (3) alloys: Cr-Fe, Si-Al-Fe, Ni-Cu, Ag-Au, Ag-Sn, Fe-Si, Fe-P, and Ag-Zn-Sn; (4) oxides: NiCrFe, PbSn, REE, rutile and Si- bearing rutile, ilmenite, corundum, chromite, MgO, and SnO2; (5) silicates: kyanite, pseudomorphs of octahedral olivine, zircon, garnet, feldspar, and quartz,; (6) sulfides of Fe, Ni, Cu, Mo, Pb, Ab, AsFe, FeNi, CuZn, and CoFeNi; and (7) iron groups: native Fe, FeO, and Fe2O3. These minerals are very similar in

Understanding physical rock properties and their relation to fluid-rock interactions under supercritical conditions

NASA Astrophysics Data System (ADS)

Kummerow, Juliane; Raab, Siegfried; Meyer, Romain

2017-04-01

The electrical conductivity of rocks is, in addition to lithological factors (mineralogy, porosity) and physical parameters (temperature, pressure) sensitive to the nature of pore fluids (phase, salinity), and thus may be an indicative measure for fluid-rock interactions. Especially near the critical point, which is at 374.21° C and 22.12 MPa for pure water, the physico-chemical properties of aqueous fluids change dramatically and mass transfer and diffusion-controlled chemical reactivity are enhanced, which in turn leads to the formation of element depletion/ enrichment patterns or cause mineral dissolution. At the same time, the reduction of the dielectric constant of water promotes ion association and consequently mineral precipitation. All this cause changes in the electrical conductivity of geothermal fluids and may have considerable effects on the porosity and hydraulic properties of the rocks with which they are in contact. In order to study the impact of fluid-rock interactions on the physical properties of fluids and rocks in near- and supercritical geological settings in more detail, in the framework of the EU-funded project "IMAGE" (Integrated Methods for Advanced Geothermal Exploration) hydraulic and electrical properties of rock cores from different active and exhumed geothermal areas on Iceland were measured up to supercritical conditions (Tmax = 380° C, pfluid = 23 MPa) during long-term (2-3 weeks) flow-through experiments in an internally heated gas pressure vessel at a maximum confining pressure of 42 MPa. In a second flow-through facility both the intrinsic T-dependent electrical fluid properties as well as the effect of mineral dissolution/ precipitation on the fluid conductivity were measured for increasing temperatures in a range of 24 - 422° C at a constant fluid pressure of 31 MPa. Petro- and fluid physical measurements were supplemented by a number of additional tests, comprising microstructural investigations as well as the chemical

Progress of the LASL dry hot rock geothermal energy project

NASA Technical Reports Server (NTRS)

Smith, M. C.

1974-01-01

The possibilities and problems of extracting energy from geothermal reservoirs which do not spontaneously yield useful amounts of steam or hot water are discussed. The system for accomplishing this which is being developed first is a pressurized-water circulation loop intended for use in relatively impermeable hot rock. It will consist of two holes connected through the hot rock by a very large hydraulic fracture and connected at the surface through the primary heat exchanger of an energy utilization system. Preliminary experiments in a hole 2576 ft (0.7852 km) deep, extending about 470 ft (143 m) into the Precambrian basement rock underlying the Jemez Plateau of north-central New Mexico, revealed no unexpected difficulties in drilling or hydraulically fracturing such rock at a temperature of approximately 100 C, and demonstrated a permeability low enough so that it appeared probable that pressurized water could be contained by the basement rock. Similar experiments are in progress in a second hole, now 6701 ft (2.043 km) deep, about 1.5 miles (2.4 km) south of the first one.

Microbiological stabilization of tiger nuts' milk beverage using ultra-high pressure homogenization. A preliminary study on microbial shelf-life extension.

PubMed

Codina-Torrella, I; Guamis, B; Zamora, A; Quevedo, J M; Trujillo, A J

2018-02-01

Tiger nuts' milk beverages are highly perishable products. For this reason, the interest of food industry for their commercialization makes necessary the application of preservation treatments to prolong their shelf-life. In the current study, the effect of ultra-high pressure homogenization (UHPH) on the microbiological and sensory qualities of tiger nuts' milk beverage was evaluated. Characteristics of UHPH-treated products (at 200 and 300 MPa, with inlet temperature of 40 °C) were compared with those of raw (RP) and conventionally homogenized-pasteurized (H-P) beverages, after treatment and during cold storage at 4 °C. Microbiological quality of beverages was studied by enumerating total counts, psychrotrophic bacteria, lactobacilli, enterobacteria, molds and yeasts, and mesophilic spores. Evolution of color and sensory characteristics of beverages were also determined. Microbiological shelf-life of the tiger nuts' milk beverages was extended from 3 to 25, 30 and 57 days by applying H-P and UHPH treatments at 200 and 300 MPa, respectively. Color of beverages was the only attribute that differentiated UHPH samples from the others, with greater luminosity and whiteness. Hence, UHPH treatments showed to be an alternative to the conventional H-P for obtaining tiger nuts' milk beverages with an improved microbiological shelf-life and good sensorial characteristics. Copyright © 2017 Elsevier Ltd. All rights reserved.

Experimental investigation of flow-induced fabrics in rocks at upper-mantle pressures: Application to understanding mantle dynamics and seismic anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kohlstedt, David L.

2016-04-26

The goal of this collaborative research effort between W.B. Durham at the Massachusetts Institute of Technology (MIT) and D.L. Kohlstedt and S. Mei at the University of Minnesota (UMN) was to exploit a newly developed technology for high-pressure, high-temperature deformation experimentation, namely, the deformation DIA (D-DIA) to determine the deformation behavior of a number of important upper mantle rock types including olivine, garnet, enstatite, and periclase. Experiments were carried out under both hydrous and anhydrous conditions and at both lithospheric and asthenospheric stress and temperature conditions. The result was a group of flow laws for Earth’s upper mantle that quantitativelymore » describe the viscosity of mantle rocks from shallow depths (the lithosphere) to great depths (the asthenosphere). These flow laws are fundamental for modeling the geodynamic behavior and heat transport from depth to Earth’s surface.« less

Experimental investigation of flow-induced fabrics in rocks at upper-mantle pressures. Application to understanding mantle dynamics and seismic anisotropy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Durham, William B.

2016-05-02

The goal of this collaborative research effort between W.B. Durham at the Massachusetts Institute of Technology (MIT) and D.L. Kohlstedt and S. Mei at the University of Minnesota (UMN) was to exploit a newly developed technology for high-pressure, high-temperature deformation experimentation, namely, the deformation DIA (D-DIA), to determine the deformation behavior of a number of important upper mantle rock types including olivine, garnet, enstatite, and periclase. Experiments were carried out under both hydrous and anhydrous conditions and at both lithospheric and asthenospheric stress and temperature conditions. The result was a group of flow laws for Earth’s upper mantle that quantitativelymore » describe the viscosity of mantle rocks from shallow depths (the lithosphere) to great depths (the asthenosphere). These flow laws are fundamental for modeling the geodynamic behavior and heat transport from depth to Earth’s surface.-« less

Metamorphic style and development of the blueschist- to eclogite-facies rocks, Cyclades, Greece

NASA Astrophysics Data System (ADS)

Schumacher, J. C.; Brady, J. B.; Cheney, J. T.

2008-07-01

The island of Syros, Greece is part of the Attic-Cycladic blueschist belt, formed during Mesozoic Eurasia-Africa subduction. The rocks of Syros can be broadly divided into three tectono-stratigraphic units: (I) metamorphosed sedimentary and volcanic rocks (marble-schist sequence), (II) remnants of oceanic crust with fault-bounded packages of blueschist/eclogite-facies mafic rocks and serpentinite (mafic-ultramafic rocks) and (III) the Vari gneiss, which is a tectonic klippe. Low-temperature, high-pressure assemblages are found on several islands in the Cyclades. The best preserved of these rocks are on Syros and Sifnos islands. Mineral compositions and peak metamorphic assemblages are similar on both islands. Both islands are considered to share similar P-T histories with highest-pressure mineral assemblages reflecting conditions of at least 15 kbar and about 500°C.

Investigation of rock samples by neutron diffraction and ultrasonic sounding

NASA Astrophysics Data System (ADS)

Burilichev, D. E.; Ivankina, T. I.; Klima, K.; Locajicek, T.; Nikitin, A. N.; Pros, Z.

2000-03-01

The interpretation of large-scale geophysical anisotropies largely depends upon the knowledge of rock anisotropies of any kind (compositions, foliations, grain shape, physical properties). Almost all physical rock properties (e.g. elastic, thermal, magnetic properties) are related to the textures of the rock constituents since they are anisotropic for the single crystal. Although anisotropy determinations are numerous, systematic investigations are scarce. Therefore, several rock samples with different microfabrics were selected for texture analysis and to determine its P-wave distributions at various confining pressures.

Molecular Retrofitting Adapts a Metal–Organic Framework to Extreme Pressure

DOE PAGES

Kapustin, Eugene A.; Lee, Seungkyu; Alshammari, Ahmad S.; ...

2017-06-07

Despite numerous studies on chemical and thermal stability of metal-organic frameworks (MOFs), mechanical stability remains largely undeveloped. No strategy exists to control the mechanical deformation of MOFs under ultrahigh pressure, to date. We show that the mechanically unstable MOF-520 can be retrofitted by precise placement of a rigid 4,4'-biphenyldicarboxylate (BPDC) linker as a "girder" to afford a mechanically robust framework: MOF-520-BPDC. This retrofitting alters how the structure deforms under ultrahigh pressure and thus leads to a drastic enhancement of its mechanical robustness. While in the parent MOF-520 the pressure transmitting medium molecules diffuse into the pore and expand the structuremore » from the inside upon compression, the girder in the new retrofitted MOF-520-BPDC prevents the framework from expansion by linking two adjacent secondary building units together. As a result, the modified MOF is stable under hydrostatic compression in a diamond-anvil cell up to 5.5 gigapascal. The increased mechanical stability of MOF-520-BPDC prohibits the typical amorphization observed for MOFs in this pressure range. Direct correlation between the orientation of these girders within the framework and its linear strain was estimated, providing new insights for the design of MOFs with optimized mechanical properties.« less

Study of Volumetrically Heated Ultra-High Energy Density Plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rocca, Jorge J.

2016-10-27

Heating dense matter to millions of degrees is important for applications, but requires complex and expensive methods. The major goal of the project was to demonstrate using a compact laser the creation of a new ultra-high energy density plasma regime characterized by simultaneous extremely high temperature and high density, and to study it combining experimental measurements and advanced simulations. We have demonstrated that trapping of intense femtosecond laser pulses deep within ordered nanowire arrays can heat near solid density matter into a new ultra hot plasma regime. Extreme electron densities, and temperatures of several tens of million degrees were achievedmore » using laser pulses of only 0.5 J energy from a compact laser. Our x-ray spectra and simulations showed that extremely highly ionized plasma volumes several micrometers in depth are generated by irradiation of gold and Nickel nanowire arrays with femtosecond laser pulses of relativistic intensities. We obtained extraordinarily high degrees of ionization (e.g. we peeled 52 electrons from gold atoms, and up to 26 electrons from nickel atoms). In the process we generated Gigabar pressures only exceeded in the central hot spot of highly compressed thermonuclear fusion plasmas.. The plasma created after the dissolved wires expand, collide, and thermalize, is computed to have a thermal energy density of 0.3 GJ cm -3 and a pressure of 1-2 Gigabar. These are pressures only exceeded in highly compressed thermonuclear fusion plasmas. Scaling these results to higher laser intensities promises to create plasmas with temperatures and pressures exceeding those in the center of the sun.« less

Raman spectroscopy in transition metals and alloys at ultrahigh pressures.

NASA Astrophysics Data System (ADS)

Goncharov, Alexander; Gregoryanz, Eugene; Struzhkin, Viktor; Hemley, Russell; Mao, Ho-Kwang; Merkel, Sebastien; Huang, Eugene

2001-03-01

We present the results of Raman measurements of hexagonal close-packed phases of Fe, Fe_(1-x)Nix (x=0.01-0.2), Re up to megabar pressures (>100 GPa). We compare frequencies and their pressure dependences of the Raman-active E_2g mode for different compositions. We find a substantial decrease in the phonon frequency for Fe:Ne alloy compared to pure Fe, which is tentatively attributed to magneto-elastic coupling. We also determine the mode Grüneisen parameters and compare them to other experimental results and theoretical calculations. The data for pure Fe and Re are used to determine the pressure dependence of the C_44 shear elastic modulus [1,2]. [1] A. P. Jephcoat, H. Olijnyk, K. Refson, Eos 80, F929 (1999). [2] S. Merkel et al., Science 288, 1626 (2000).

Superconductivity in Pristine 2 Ha-MoS2 at Ultrahigh Pressure

NASA Astrophysics Data System (ADS)

Chi, Zhenhua; Chen, Xuliang; Yen, Fei; Peng, Feng; Zhou, Yonghui; Zhu, Jinlong; Zhang, Yijin; Liu, Xiaodi; Lin, Chuanlong; Chu, Shengqi; Li, Yanchun; Zhao, Jinggeng; Kagayama, Tomoko; Ma, Yanming; Yang, Zhaorong

2018-01-01

As a follow-up of our previous work on pressure-induced metallization of the 2 Hc-MoS2 [Chi et al., Phys. Rev. Lett. 113, 036802 (2014), 10.1103/PhysRevLett.113.036802], here we extend pressure beyond the megabar range to seek after superconductivity via electrical transport measurements. We found that superconductivity emerges in the 2 Ha-MoS2 with an onset critical temperature Tc of ca. 3 K at ca. 90 GPa. Upon further increasing the pressure, Tc is rapidly enhanced beyond 10 K and stabilized at ca. 12 K over a wide pressure range up to 220 GPa. Synchrotron x-ray diffraction measurements evidenced no further structural phase transition, decomposition, and amorphization up to 155 GPa, implying an intrinsic superconductivity in the 2 Ha-MoS2 . DFT calculations suggest that the emergence of pressure-induced superconductivity is intimately linked to the emergence of a new flat Fermi pocket in the electronic structure. Our finding represents an alternative strategy for achieving superconductivity in 2 H -MoS2 in addition to chemical intercalation and electrostatic gating.

Rock falls from Glacier Point above Camp Curry, Yosemite National Park, California

USGS Publications Warehouse

Wieczorek, Gerald F.; Snyder, James B.

1999-01-01

A series of rock falls from the north face of Glacier Point above Camp Curry, Yosemite National Park, California, have caused reexamination of the rock-fall hazard because beginning in June, 1999 a system of cracks propagated through a nearby rock mass outlining a future potential rock fall. If the estimated volume of the potential rock fall fails as a single piece, there could be a risk from rock-fall impact and airborne rock debris to cabins in Camp Curry. The role of joint plane orientation and groundwater pressure in the fractured rock mass are discussed in light of the pattern of developing cracks and potential modes of failure.

Method of pressurizing and stabilizing rock by periodic and repeated injections of a settable fluid of finite gel strength

DOEpatents

Colgate, Stirling A.

1983-01-01

A finite region of overpressure can be created in solid underground formations by the periodic injection of a fluid that has finite gel strength that subsequently, after each injection, partially sets--i.e., equivalently becomes a very much stronger gel. A region of overpressure is a region in which the static, locked in pressure is larger than what was there before. A region of overpressure can be used to prevent a roof of a tunnel from caving by adding compressive stresses in the roof. A sequence of regions of overpressure can be used to lift an arch or dome underground, squeeze off water or gas flows, stabilize dams, foundations, large underground rooms, etc. In general, the stress or pressure distribution in rock can be altered and engineered in a fashion that is more advantageous than what would have been the case without overstressing.

Note: reliable and reusable ultrahigh vacuum optical viewports.

PubMed

Arora, P; Sen Gupta, A

2012-04-01

We report a simple technique for the realization of ultrahigh vacuum optical viewports. The technique relies on using specially designed thin copper knife-edges and using a thin layer of Vacseal(®) on tip of the knife-edges between the optical flat and the ConFlat(®) (CF) flange. The design of the windows is such that it gives uniform pressure on the flat without breaking it. The assembled window is a complete unit, which can be mounted directly onto a CF flange of the vacuum chamber. It can be removed and reused without breaking the window seal. The design is reliable as more than a dozen such windows have survived several bake out and cooling cycles and have been leak tested up to 10(-11) Torr l/s level with a commercial Helium leak detector. The advantages of this technique are ease of assembly and leak proof sealing that survives multiple temperature cycling making the windows reliable and reusable. © 2012 American Institute of Physics

The Time-Dependency of Deformation in Porous Carbonate Rocks

NASA Astrophysics Data System (ADS)

Kibikas, W. M.; Lisabeth, H. P.; Zhu, W.

2016-12-01

Porous carbonate rocks are natural reservoirs for freshwater and hydrocarbons. More recently, due to their potential for geothermal energy generation as well as carbon sequestration, there are renewed interests in better understanding of the deformation behavior of carbonate rocks. We conducted a series of deformation experiments to investigate the effects of strain rate and pore fluid chemistry on rock strength and transport properties of porous limestones. Indiana limestone samples with initial porosity of 16% are deformed at 25 °C under effective pressures of 10, 30, and 50 MPa. Under nominally dry conditions, the limestone samples are deformed under 3 different strain rates, 1.5 x 10-4 s-1, 1.5 x 10-5 s-1 and 1.5 x 10-6 s-1 respectively. The experimental results indicate that the mechanical behavior is both rate- and pressure-dependent. At low confining pressures, post-yielding deformation changes from predominantly strain softening to strain hardening as strain rate decreases. At high confining pressures, while all samples exhibit shear-enhanced compaction, decreasing strain rate leads to an increase in compaction. Slower strain rates enhance compaction at all confining pressure conditions. The rate-dependence of deformation behaviors of porous carbonate rocks at dry conditions indicates there is a strong visco-elastic coupling for the degradation of elastic modulus with increasing plastic deformation. In fluid saturated samples, inelastic strain of limestone is partitioned among low temperature plasticity, cataclasis and solution transport. Comparison of inelastic behaviors of samples deformed with distilled water and CO2-saturated aqueous solution as pore fluids provide experimental constraints on the relative activities of the various mechanisms. Detailed microstructural analysis is conducted to take into account the links between stress, microstructure and the inelastic behavior and failure mechanisms.

Imaging at ultrahigh magnetic fields: History, challenges, and solutions.

PubMed

Uğurbil, Kamil

2018-03-01

Following early efforts in applying nuclear magnetic resonance (NMR) spectroscopy to study biological processes in intact systems, and particularly since the introduction of 4 T human scanners circa 1990, rapid progress was made in imaging and spectroscopy studies of humans at 4 T and animal models at 9.4 T, leading to the introduction of 7 T and higher magnetic fields for human investigation at about the turn of the century. Work conducted on these platforms has provided numerous technological solutions to challenges posed at these ultrahigh fields, and demonstrated the existence of significant advantages in signal-to-noise ratio and biological information content. Primary difference from lower fields is the deviation from the near field regime at the radiofrequencies (RF) corresponding to hydrogen resonance conditions. At such ultrahigh fields, the RF is characterized by attenuated traveling waves in the human body, which leads to image non-uniformities for a given sample-coil configuration because of destructive and constructive interferences. These non-uniformities were initially considered detrimental to progress of imaging at high field strengths. However, they are advantageous for parallel imaging in signal reception and transmission, two critical technologies that account, to a large extend, for the success of ultrahigh fields. With these technologies and improvements in instrumentation and imaging methods, today ultrahigh fields have provided unprecedented gains in imaging of brain function and anatomy, and started to make inroads into investigation of the human torso and extremities. As extensive as they are, these gains still constitute a prelude to what is to come given the increasingly larger effort committed to ultrahigh field research and development of ever better instrumentation and techniques. Copyright © 2017 Elsevier Inc. All rights reserved.

Imaging of cartilage degeneration progression in vivo using ultrahigh-resolution OCT

NASA Astrophysics Data System (ADS)

Herz, Paul R.; Bourquin, Stephane; Hsiung, Pei-lin; Ko, Tony H.; Schneider, Karl; Fujimoto, James G.; Adams, Samuel, Jr.; Roberts, Mark; Patel, Nirlep; Brezinski, Mark

2003-10-01

Ultrahigh resolution OCT is used to visualize experimentally induced osteoarthritis in a rat knee model. Using a Cr4+:Forsterite laser, ultrahigh image resolutions of 5um are achieved. Progression of osteoarthritic remodeling and cartilage degeneration are quantified. The utility of OCT for the assessment of cartilage integrity is demonstrated.

Hayward Fault rocks: porosity, density, and strength measurements

USGS Publications Warehouse

Morrow, C.A.; Lockner, D.A.

2001-01-01

Porosity, density and strength measurements were conducted on rock samples collected from the Hayward Fault region in Northern California as part of the Hayward Fault Working Group’s efforts to create a working model of the Hayward Fault. The rocks included in this study were both fine and coarse grained gabbros, altered keratophyre, basalt, sandstone, and serpentinite from various rock formations adjacent to the Hayward Fault. Densities ranged from a low of 2.25 gm/cc (altered keratophyre) to 3.05 gm/cc (fine gabbro), with an average of 2.6 gm/cc, typical of many other rocks. Porosities were generally around 1% or less, with the exception of the sandstone (7.6%) and altered keratophyre (13.5%). Failure and frictional sliding tests were conducted on intact rock cylinders at room temperature under effective pressure conditions of up to 192 MPa, simulating depths of burial to 12 km. Axial shortening of the samples progressed at a rate of 0.1 µm/sec (fine samples) or 0.2 µm/sec (porous samples) for 6 mm of displacement. Velocity stepping tests were then conducted for an additional 2 mm of displacement, for a total of 8 mm. Both peak strength (usually failure strength) and frictional strength, determined at 8 mm of displacement, increased systematically with effective pressure. Coefficients of friction, based on the observed fracture angles, ranged from 0.6 to 0.85, consistent with Byerlee’s Law. Possible secondary influences on the strength of the Hayward rock samples may be surface weathering, or a larger number of pre-existing fractures due to the proximity to the Hayward Fault. All samples showed velocity strengthening, so that the average a-b values were all strongly positive. There was no systematic relation between a-b values and effective pressure. Velocity strengthening behavior is associated with stable sliding (creep), as observed in the shallow portions of the Hayward Fault.

A Discrete Element Method Approach to Progressive Localization of Damage in Granular Rocks and Associated Seismicity

NASA Astrophysics Data System (ADS)

Vora, H.; Morgan, J.

2017-12-01

Brittle failure in rock under confined biaxial conditions is accompanied by release of seismic energy, known as acoustic emissions (AE). The objective our study is to understand the influence of elastic properties of rock and its stress state on deformation patterns, and associated seismicity in granular rocks. Discrete Element Modeling is used to simulate biaxial tests on granular rocks of defined grain size distribution. Acoustic Energy and seismic moments are calculated from microfracture events as rock is taken to conditions of failure under different confining pressure states. Dimensionless parameters such as seismic b-value and fractal parameter for deformation, D-value, are used to quantify seismic character and distribution of damage in rock. Initial results suggest that confining pressure has the largest control on distribution of induced microfracturing, while fracture energy and seismic magnitudes are highly sensitive to elastic properties of rock. At low confining pressures, localized deformation (low D-values) and high seismic b-values are observed. Deformation at high confining pressures is distributed in nature (high D-values) and exhibit low seismic b-values as shearing becomes the dominant mode of microfracturing. Seismic b-values and fractal D-values obtained from microfracturing exhibit a linear inverse relationship, similar to trends observed in earthquakes. Mode of microfracturing in our simulations of biaxial compression tests show mechanistic similarities to propagation of fractures and faults in nature.

New Laboratory Observations of Thermal Pressurization Weakening

NASA Astrophysics Data System (ADS)

Badt, N.; Tullis, T. E.; Hirth, G.

2017-12-01

Dynamic frictional weakening due to pore fluid thermal pressurization has been studied under elevated confining pressure in the laboratory, using a rotary-shear apparatus having a sample with independent pore pressure and confining pressure systems. Thermal pressurization is directly controlled by the permeability of the rocks, not only for the initiation of high-speed frictional weakening but also for a subsequent sequence of high-speed sliding events. First, the permeability is evaluated at different effective pressures using a method where the pore pressure drop and the flow-through rate are compared using Darcy's Law as well as a pore fluid oscillation method, the latter method also permitting measurement of the storage capacity. Then, the samples undergo a series of high-speed frictional sliding segments at a velocity of 2.5 mm/s, under an applied confining pressure and normal stress of 45 MPa and 50 MPa, respectively, and an initial pore pressure of 25 MPa. Finally the rock permeability and storage capacity are measured again to assess the evolution of the rock's pore fluid properties. For samples with a permeability of 10-20 m2 thermal pressurization promotes a 40% decrease in strength. However, after a sequence of three high-speed sliding events, the magnitude of weakening diminishes progressively from 40% to 15%. The weakening events coincide with dilation of the sliding interface. Moreover, the decrease in the weakening degree with progressive fast-slip events suggest that the hydraulic diffusivity may increase locally near the sliding interface during thermal pressurization-enhanced slip. This could result from stress- or thermally-induced damage to the host rock, which would perhaps increase both permeability and storage capacity, and so possibly decrease the susceptibility of dynamic weakening due to thermal pressurization in subsequent high-speed sliding events.

Achieving ultrahigh vacuum in an unbaked chamber with glow discharge conditioning

NASA Astrophysics Data System (ADS)

Khan, Ziauddin; Semwal, Pratibha; Dhanani, Kalpesh R.; Raval, Dilip C.; Pradhan, Subrata

2017-01-01

Glow discharge conditioning (GDC) has long been accepted as one of the basic wall conditioning techniques for achieving ultrahigh vacuum in an unbaked chamber. As a part of this fundamental experimental study, a test chamber has been fabricated from stainless steel 304 L with its inner surface electropolished on which a detailed investigation has been carried out. Both helium and hydrogen gases have been employed as discharge cleaning medium. The discharge cleaning was carried out at 0.1 A / m 2 current density with working pressure maintained at 1.0 × 10 -2 mbar. It was experimentally observed that the pump-down time to attain the base pressure 10 -8 mbar was reduced by 62% compared to the unbaked chamber being pumped to this ultimate vacuum. The results were similar irrespective of whether the discharge cleaning medium is either hydrogen or helium. It was also experimentally established that a better ultimate vacuum could be achieved as compared to theoretically calculated ultimate vacuum with the help of discharge cleaning.

[Extreme (complicated, ultra-high) refractive errors: terminological misconceptions!?

PubMed

Avetisov, S E

2018-01-01

The article reviews development mechanisms of different refractive errors accompanied by marked defocus of light rays reaching the retina. Terminology used for such ametropias includes terms extreme, ultra-high and complicated. Justification of their usage for primary ametropias, whose symptom complex is based on changes in axial eye length, is an ongoing discussion. To comply with thesaurus definitions of 'diagnosis' and 'pathogenesis', to characterize refractive and anatomical-functional disorders in patients with primary ametropias it is proposed to use the terms 'hyperaxial and hypoaxial syndromes' with elaboration of specific symptoms instead of such expressions as extreme (ultra-high) myopia and hypermetropia.

Ultra-High Surface Speed for Metal Removal, Artillery Shell

DTIC Science & Technology

1981-07-01

TECHNICAL LIBRARY "y/a^^cr^ AD-E400 660 CONTRACTOR REPORT ARLCD-CR- 81019 ULTRA-HIGH SURFACE SPEED FOR METAL REMOVAL, ARTILLERY SHELL RICHARD F...Report ARLCD-CR- 81019 2. GOVT ACCESSION NO. 3. RECIPIENT’S CATALOG NUMBER 4. TITLE (and Subtitle) ULTRA-HIGH SURFACE SPEED FOR METAL...UNIT* tuiPPtO 1 MIL -STD-43CA i, ASTM A-274-64 EF A1SI~1340 SEHI FIN FORGING STEEL 6 RC SQ ■ IP 120093* a LIFTS 38 PCS

Diamond and moissanite in ophiolitic mantle rocks and podiform chromitites: A deep carbon source?

NASA Astrophysics Data System (ADS)

Yang, J.; Xu, X.; Wiedenbeck, M.; Trumbull, R. B.; Robinson, P. T.

2010-12-01

Diamonds are known from a variety of occurreces, mainly from mantle-derived kimberlites, meteorite impact craters, and continental deep subduction and collision zones. Recently, an unusual mineral group was discovered in the Luobusa ophiolitic chromitites from the Yarlung Zangbu suture, Tibet, which probably originated from a depth of over 300 km in the mantle. Minerals of deep origin include coesite apparently pseudomorphing stishovite, and diamond as individual grains or inclusions in OsIr alloy. To determine if such UHP and unusual minerals occur elsewhere, we collected about 1.5 t of chromitite from two orebodies in an ultramafic body in the Polar Urals. Thus far, more than 60 different mineral species have been separated from these ores. The most exciting discovery is the common occurrence of diamond, a typical UHP mineral in the Luobusa chromitites. These minerals are very similar in composition and structure to those reported from the Luobusa chromitites. So far diamond and/or moissanite have been discovered from many different ophiolitic ultramafic rocks, including in-situ grains in polished chromitite fragments. These discoveries demonstrate that the Luobusa ophiolite is not a unique diamond-bearing massif. Secondary ion mass spectrometric (SIMS) analysis shows that the ophiolite-hosted diamond has a distinctive 13C-depleted isotopic composition (δ13C from -18 to -28‰, n=70), compatible to the ophiolite-hosted moissanite (δ13C from -18 to -35‰, n=36), both are much lighter than the main carbon reservoir in the upper mantle (δ13C near -5‰). The compiled data from moissanite from kimberlites and other mantle settings share the characteristic of strongly 13C-depleted isotopic composition. This suggests that diamond and moissanite originates from a separate carbon reservoir in the mantle or that its formation involved strong isotopic fractionation. Subduction of biogenic carbonaceous material could potentially satisfy both the unusual isotopic and

Laboratory measurements of the effective-stress law of carbonate rocks under deformation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warpinski, N.R.; Teufel, L.W.

The behavior of rocks under the combined effects of confining stress and pore pressure is an important issue for any in situ petroleum process. In order to simplify the difficulties in dealing with two independent parameters, it is customary to introduce an effective-stress law which relates a net, or effective, stress to some combination of confining stress and pore pressure. This report documents laboratory tests of mechanical properties of five carbonate rocks.

[Application study of qualitatively diagnosing prostate cancer using ultrahigh b-value DWI].

PubMed

Ji, L B; Lu, Z H; Yao, H H; Cao, Y; Lu, W W; Qian, W X; Wang, X M; Hu, C H

2017-07-18

Objective: To explore the value of ultrahigh b-value DWI in diagnosis of prostate cancer. Methods: From October 2015 to October 2016, a total of 84 cases from Affiliated Changshu Hospital of Soochow University(39 cases of prostate cancer with a total of 57 lesions, 45 cases of benign prostate hyperplasia) were examined with T(2)WI, high b-value DWI (b=1 000 s/mm(2)) and ultrahigh b-value DWI (b=2 000 s/mm(2)) .Three image sets were rated respectively based on PI-RADS V2 by two radiologists and the scores were compared with biopsy results.The differences of the area under the ROC curve (AUC) among the three groups of each observer were compared by Z test. Results: The difference of AUC between ultrahigh b-value DWI and T(2)WI in the diagnosis of peripheral and transitional zone cancer was statistically significant between the two observers ( P =0.009 9, 0.008 2, 0.010 8 and 0.004 5 respectively), and there was no significant difference of AUC between ultrahigh b-value DWI and high b-value DWI in the diagnosis of peripheral and transitional zone cancer.The inter-reader agreement was found to be perfect for all lesions, peripheral zone lesions and transition zone lesions at ultrahigh b-value DWI ( kappa values were 0.738, 0.709 and 0.768 respectively). Conclusion: The diagnostic performance of ultrahigh b-value DWI is superior to high b-value DWI and T(2)WI in both peripheral zone and transition zone cancers.

Subduction-Zone Metamorphic Pathway for Deep Carbon Cycling: Evidence from the Italian Alps and the Tianshan

NASA Astrophysics Data System (ADS)

Bebout, G. E.; Collins, N.; Cook-Kollars, J.; Angiboust, S.; Agard, P.; Scambelluri, M.; John, T.; Kump, L. R.

2013-12-01

Depending on the magnitude of the poorly constrained C flux in ultramafic rocks, on a global basis, sediments and altered oceanic crust (AOC) together deliver 70-95% of the C currently entering subduction zones. We are investigating extents of retention and metamorphic release of C in deeply subducted AOC and carbonate-rich sediment represented by HP/UHP meta-ophiolitic and metasedimentary rocks in the Italian Alps and in the Tianshan. Study of metapelite devolatilization in the same W. Alps suite (Bebout et al., 2013, Chem. Geol.) provides a geochemical framework for study of C behavior along prograde P-T paths similar to those experienced in forearcs of most modern subduction margins. Study of veins in the Tianshan affords examination of C mobility in UHP fluids, in later stages as metabasaltic rocks were fragmented in the subduction channel. Our results for sediments and AOC indicate impressive retention of oxidized C (carbonate) and reduced C (variably metamorphosed organic matter) to depths approaching those beneath arc volcanic fronts. In metasedimentary rocks, extensive isotopic exchange between the oxidized and reduced C resulted in shifts in both reservoirs toward upper mantle compositions. Much of the carbonate in metabasalts has C and O isotopic compositions overlapping with those for carbonate in AOC, with some HP/UHP metamorphic veins showing greater influence of organic C signatures from metasedimentary rocks. Calculations of prograde devolatilization histories using Perple-X demonstrate that, in most forearcs, very little decarbonation occurs in the more carbonate-rich rocks unless they are flushed by H2O-rich fluids from an external source, for example, from the hydrated ultramafic section of subducting slabs (cf. Gorman et al., 2006; G3) or from more nearby rocks experiencing dehydration (e.g., metapelites). A comparison of the most recently published thermal models for modern subduction zones (van Keken et al., 2011, JGR) with calculated and

Permeability of intact and fractured rocks in Krafla geothermal reservoir, Iceland

NASA Astrophysics Data System (ADS)

Eggertsson, Gudjon; Lavallée, Yan; Markusson, Sigurdur

2016-04-01

The magmatic-hydrothermal system at Krafla Volcano, North-East Iceland, has been the source of an important geothermal fluids, exploited by Landsvirkjun National Power since 1977 to generate electricity (~60 MW). In the last decade, the energy was extracted from fluids of moderate temperature (200-300°C), but in order to satisfy the demand for sustainable, environmentally-safe energy, Landsvirkjun is aiming to source fluids in the super high-enthalpy hydrothermal system (400°-600°C and <220 bar). In relation to this, IDDP-1 was drilled in 2009. Drilling was terminated at a depth of 2100m when the drill string penetrated rhyolite magma. The rock around this rhyolite magma body shows great potential for production, as its temperatures are very high and it is located at shallow depth. Here, we present the results of mechanical and permeability tests carried out on the main lithologies forming the geothermal reservoir rock. During a field survey in fall 2015, and through information gathered from previous drilling exercises, five main rock types were identified and sampled to carry out this study: that is, basalts (10% to 60% porosity), hyaloclastites (35% to 45% porosity), obsidians (0,25% to 5% porosity), ignimbrites (13% to 18% porosity), and intrusive felsites and microgabbros (10% to 16% porosity). The only rock type not found in outcrops on the surface is the felsite and microgabbros which are thought to be directly above the rhyolite magma (~80m thick). The reason they can be found on the surface is that during the Mývatns-fires, an explosion creating the Víti crater and scattered these rocks around the area. For all these lithologies, the porosity was determined using helium pycnometry. On-going permeability measurements are made using a classic hydrostatic cell. To simulate the stress conditions extant in the hydrothermal field, we performed permeability measurements at a range of confining pressure (1 to 100 MPa), using a pore pressure differential of 0

Estimation Criteria for Rock Brittleness Based on Energy Analysis During the Rupturing Process

NASA Astrophysics Data System (ADS)

Ai, Chi; Zhang, Jun; Li, Yu-wei; Zeng, Jia; Yang, Xin-liang; Wang, Ji-gang

2016-12-01

Brittleness is one of the most important mechanical properties of rock: it plays a significant role in evaluating the risk of rock bursts and in analysis of borehole-wall stability during shale gas development. Brittleness is also a critical parameter in the design of hydraulic fracturing. However, there is still no widely accepted definition of the concept of brittleness in rock mechanics. Although many criteria have been proposed to characterize rock brittleness, their applicability and reliability have yet to be verified. In this paper, the brittleness of rock under compression is defined as the ability of a rock to accumulate elastic energy during the pre-peak stage and to self-sustain fracture propagation in the post-peak stage. This ability is related to three types of energy: fracture energy, post-peak released energy and pre-peak dissipation energy. New brittleness evaluation indices B 1 and B 2 are proposed based on the stress-strain curve from the viewpoint of energy. The new indices can describe the entire transition of rock from absolute plasticity to absolute brittleness. In addition, the brittle characteristics reflected by other brittleness indices can be described, and the calculation results of B 1 and B 2 are continuous and monotonic. Triaxial compression tests on different types of rock were carried out under different confining pressures. Based on B 1 and B 2, the brittleness of different rocks shows different trends with rising confining pressure. The brittleness of red sandstone decreases with increasing confining pressure, whereas for black shale it initially increases and then decreases in a certain range of confining pressure. Granite displays a constant increasing trend. The brittleness anisotropy of black shale is discussed. The smaller the angle between the loading direction and the bedding plane, the greater the brittleness. The calculation B 1 and B 2 requires experimental data, and the values of these two indices represent only

A nanofiber based artificial electronic skin with high pressure sensitivity and 3D conformability

NASA Astrophysics Data System (ADS)

Zhong, Weibin; Liu, Qiongzhen; Wu, Yongzhi; Wang, Yuedan; Qing, Xing; Li, Mufang; Liu, Ke; Wang, Wenwen; Wang, Dong

2016-06-01

Pressure sensors with 3D conformability are highly desirable components for artificial electronic skin or e-textiles that can mimic natural skin, especially for application in real-time monitoring of human physiological signals. Here, a nanofiber based electronic skin with ultra-high pressure sensitivity and 3D conformability is designed and built by interlocking two elastic patterned nanofibrous membranes. The patterned membrane is facilely prepared by casting conductive nanofiber ink into a silicon mould to form an array of semi-spheroid-like protuberances. The protuberances composed of intertwined elastic POE nanofibers and PPy@PVA-co-PE nanofibers afford a tunable effective elastic modulus that is capable of capturing varied strains and stresses, thereby contributing to a high sensitivity for pressure sensing. This electronic skin-like sensor demonstrates an ultra-high sensitivity (1.24 kPa-1) below 150 Pa with a detection limit as low as about 1.3 Pa. The pixelated sensor array and a RGB-LED light are then assembled into a circuit and show a feasibility for visual detection of spatial pressure. Furthermore, a nanofiber based proof-of-concept wireless pressure sensor with a bluetooth module as a signal transmitter is proposed and has demonstrated great promise for wireless monitoring of human physiological signals, indicating a potential for large scale wearable electronic devices or e-skin.Pressure sensors with 3D conformability are highly desirable components for artificial electronic skin or e-textiles that can mimic natural skin, especially for application in real-time monitoring of human physiological signals. Here, a nanofiber based electronic skin with ultra-high pressure sensitivity and 3D conformability is designed and built by interlocking two elastic patterned nanofibrous membranes. The patterned membrane is facilely prepared by casting conductive nanofiber ink into a silicon mould to form an array of semi-spheroid-like protuberances. The

Method of pressurizing and stabilizing rock by periodic and repeated injections of a settable fluid of finite gel strength

DOEpatents

Colgate, S.A.

1983-01-25

A finite region of overpressure can be created in solid underground formations by the periodic injection of a fluid that has finite gel strength that subsequently, after each injection, partially sets--i.e., equivalently becomes a very much stronger gel. A region of overpressure is a region in which the static, locked in pressure is larger than what was there before. A region of overpressure can be used to prevent a roof of a tunnel from caving by adding compressive stresses in the roof. A sequence of regions of overpressure can be used to lift an arch or dome underground, squeeze off water or gas flows, stabilize dams, foundations, large underground rooms, etc. In general, the stress or pressure distribution in rock can be altered and engineered in a fashion that is more advantageous than what would have been the case without overstressing. 3 figs.

An ultrahigh vacuum multipurpose specimen chamber with sample introduction system for in situ transmission electron microscopy investigations

NASA Technical Reports Server (NTRS)

Heinemann, K.; Poppa, H.

1986-01-01

A commercial transmission electron microscope (TEM), with flat-plate upper pole piece configuration of the objective lens, and top-entry specimen introduction was modified by introducing an ultrahigh vacuum (UHV) specimen chamber for in situ TEM experimentation. The pumping and design principles and special features of this UHV chamber, which makes it possible to obtain 5 x 10 to the -10th mbar pressure at the site of the specimen, while maintaining the airlock system that allows operation in the 10 to the -10th mbar range within 15 min after specimen change, are described. Design operating pressures and image quality (resolution of metal particles smaller than 1 nm in size) were achieved. Schematic drawings and design dimensions are included.

Effect of rock rheology on fluid leak- off during hydraulic fracturing

NASA Astrophysics Data System (ADS)

Yarushina, V. M.; Bercovici, D.; Oristaglio, M. L.

2012-04-01

In this communication, we evaluate the effect of rock rheology on fluid leak­off during hydraulic fracturing of reservoirs. Fluid leak-off in hydraulic fracturing is often nonlinear. The simple linear model developed by Carter (1957) for flow of fracturing fluid into a reservoir has three different regions in the fractured zone: a filter cake on the fracture face, formed by solid additives from the fracturing fluid; a filtrate zone affected by invasion of the fracturing fluid; and a reservoir zone with the original formation fluid. The width of each zone, as well as its permeability and pressure drop, is assumed to remain constant. Physical intuition suggests some straightforward corrections to this classical theory to take into account the pressure dependence of permeability, the compressibility or non-Newtonian rheology of fracturing fluid, and the radial (versus linear) geometry of fluid leak­off from the borehole. All of these refinements, however, still assume that the reservoir rock adjacent to the fracture face is non­deformable. Although the effect of poroelastic stress changes on leak-off is usually thought to be negligible, at the very high fluid pressures used in hydraulic fracturing, where the stresses exceed the rock strength, elastic rheology may not be the best choice. For example, calculations show that perfectly elastic rock formations do not undergo the degree of compaction typically seen in sedimentary basins. Therefore, pseudo-elastic or elastoplastic models are used to fit observed porosity profiles with depth. Starting from balance equations for mass and momentum for fluid and rock, we derive a hydraulic flow equation coupled with a porosity equation describing rock compaction. The result resembles a pressure diffusion equation with the total compressibility being a sum of fluid, rock and pore-space compressibilities. With linear elastic rheology, the bulk formation compressibility is dominated by fluid compressibility. But the possibility

Permeability Measurements of Rock Samples from Conduit Drilling at Unzen Volcano, Japan

NASA Astrophysics Data System (ADS)

Watanabe, T.; Shimizu, Y.; Noguchi, S.; Nakada, S.

2006-12-01

The last eruption of Unzen Volcano (1990-1995) was effusive to form lava domes, though magmas at depths are estimated to have contained volatile materials enough to cause explosive eruptions [e.g., Sato et al., 1995]. Most of volatile materials should have escaped from ascending magmas. The escape of gas is controlled by permeability of magmas and country rocks. Unzen Scientific Drilling Project sampled both the latest conduit and its country rock (USDP-4). In order to understand degassing processes, we have measured the permeability of these rock samples. Four cube samples with edges of 25 mm were cut from USDP-4 cores C1, C12 (country rock), C13 and C14 (conduit). Sample C1 is considered as Old Unzen Lava, and Sample C12 volcanic breccia. The transient pulse method was employed to measure the permeability. It applies a step of the fluid pressure difference across a specimen, and measures the decay rate of the fluid pressure difference. This method can be applied to samples with very low permeability, since it determines the permeability without measuring the fluid flux. Nitrogen gas was used as a pore fluid. Our permeametry system is built in a pressure vessel, and the confining pressure and the pore fluid pressure can be controlled independently. The temperature of the measurement system is kept constant within 0.1 degree. The temperature control and the background leak rate limit the measurable permeability to be higher than 10^{-20} m2. Measurements were first conducted under the atmospheric pressure. The permeability in a rock sample varies with the direction by a factor less than 5. Sample C1 has the lowest permeability (10^{-19} m2), and Sample C12 the highest value (10^{-17 m2). The permeability of C13 and C14 is of the order of 10^{- 18} m2. Though only a trace of vesicles can be seen in conduit samples, the interconnection is still maintained. The pressure dependence of the permeability is now investigated up to 50 MPa. The permeability of C13 and C14

Scattering from Rock and Rock Outcrops

DTIC Science & Technology

2015-09-30

Scattering from Rock and Rock Outcrops Derek R. Olson The Pennsylvania State University Applied Research Laboratory, P.O. Box 30 State...In terms of target detection and classification, scattering from exposed rock on the seafloor, (i.e., individual rocks and rock outcrops) presents...levels, and other statistical measures of acoustic scattering from rocks and rock outcrops is therefore critical. Unfortunately (and curiously

Design Method For Ultra-High Resolution Linear CCD Imagers

NASA Astrophysics Data System (ADS)

Sheu, Larry S.; Truong, Thanh; Yuzuki, Larry; Elhatem, Abdul; Kadekodi, Narayan

1984-11-01

This paper presents the design method to achieve ultra-high resolution linear imagers. This method utilizes advanced design rules and novel staggered bilinear photo sensor arrays with quadrilinear shift registers. Design constraint in the detector arrays and shift registers are analyzed. Imager architecture to achieve ultra-high resolution is presented. The characteristics of MTF, aliasing, speed, transfer efficiency and fine photolithography requirements associated with this architecture are also discussed. A CCD imager with advanced 1.5 um minimum feature size was fabricated. It is intended as a test vehicle for the next generation small sampling pitch ultra-high resolution CCD imager. Standard double-poly, two-phase shift registers were fabricated at an 8 um pitch using the advanced design rules. A special process step that blocked the source-drain implant from the shift register area was invented. This guaranteed excellent performance of the shift registers regardless of the small poly overlaps. A charge transfer efficiency of better than 0.99995 and maximum transfer speed of 8 MHz were achieved. The imager showed excellent performance. The dark current was less than 0.2 mV/ms, saturation 250 mV, adjacent photoresponse non-uniformity ± 4% and responsivity 0.7 V/ μJ/cm2 for the 8 μm x 6 μm photosensor size. The MTF was 0.6 at 62.5 cycles/mm. These results confirm the feasibility of the next generation ultra-high resolution CCD imagers.

Permeability of volcanic rocks to gas and water

NASA Astrophysics Data System (ADS)

Heap, M. J.; Reuschlé, T.; Farquharson, J. I.; Baud, P.

2018-04-01

The phase (gas or liquid) of the fluids within a porous volcanic system varies in both time and space. Laboratory experiments have shown that gas and water permeabilities can differ for the same rock sample, but experiments are biased towards rocks that contain minerals that are expected react with the pore fluid (such as the reaction between liquid water and clay). We present here the first study that systematically compares the gas and water permeability of volcanic rocks. Our data show that permeabilities to argon gas and deionised water can differ by a factor between two and five in two volcanic rocks (basalt and andesite) over a confining pressure range from 2 to 50 MPa. We suggest here that the microstructural elements that offer the shortest route through the sample-estimated to have an average radius 0.1-0.5 μm using the Klinkenberg slip factor-are accessible to gas, but restricted or inaccessible to water. We speculate that water adsorption on the surface of these thin microstructural elements, assumed here to be tortuous/rough microcracks, reduces their effective radius and/or prevents access. These data have important implications for fluid flow and therefore the distribution and build-up of pore pressure within volcanic systems.

Numerical simulation of abutment pressure redistribution during face advance

NASA Astrophysics Data System (ADS)

Klishin, S. V.; Lavrikov, S. V.; Revuzhenko, A. F.

2017-12-01

The paper presents numerical simulation data on the abutment pressure redistribution in rock mass during face advance, including isolines of maximum shear stress and pressure epures. The stress state of rock in the vicinity of a breakage heading is calculated by the finite element method using a 2D nonlinear model of a structurally heterogeneous medium with regard to plasticity and internal self-balancing stress. The thus calculated stress field is used as input data for 3D discrete element modeling of the process. The study shows that the abutment pressure increases as the roof span extends and that the distance between the face breast and the peak point of this pressure depends on the elastoplastic properties and internal self-balancing stress of a rock medium.

Extracting real-crack properties from non-linear elastic behaviour of rocks: abundance of cracks with dominating normal compliance and rocks with negative Poisson ratios

NASA Astrophysics Data System (ADS)

Zaitsev, Vladimir Y.; Radostin, Andrey V.; Pasternak, Elena; Dyskin, Arcady

2017-09-01

Results of examination of experimental data on non-linear elasticity of rocks using experimentally determined pressure dependences of P- and S-wave velocities from various literature sources are presented. Overall, over 90 rock samples are considered. Interpretation of the data is performed using an effective-medium description in which cracks are considered as compliant defects with explicitly introduced shear and normal compliances without specifying a particular crack model with an a priori given ratio of the compliances. Comparison with the experimental data indicated abundance (˜ 80 %) of cracks with the normal-to-shear compliance ratios that significantly exceed the values typical of conventionally used crack models (such as penny-shaped cuts or thin ellipsoidal cracks). Correspondingly, rocks with such cracks demonstrate a strongly decreased Poisson ratio including a significant (˜ 45 %) portion of rocks exhibiting negative Poisson ratios at lower pressures, for which the concentration of not yet closed cracks is maximal. The obtained results indicate the necessity for further development of crack models to account for the revealed numerous examples of cracks with strong domination of normal compliance. Discovering such a significant number of naturally auxetic rocks is in contrast to the conventional viewpoint that occurrence of a negative Poisson ratio is an exotic fact that is mostly discussed for artificial structures.

Model test study on propagation law of plane stress wave in jointed rock mass under different in-situ stresses

NASA Astrophysics Data System (ADS)

Dong, Qian

2017-12-01

The study of propagation law of plane stress wave in jointed rock mass under in-situ stress has important significance for safety excavation of underground rock mass engineering. A model test of the blasting stress waves propagating in the intact rock and jointed rock mass under different in-situ stresses was carried out, and the influencing factors on the propagation law, such as the scale of static loads and the number of joints were studied respectively. The results show that the transmission coefficient of intact rock is larger than that of jointed rock mass under the same loading condition. With the increase of confining pressure, the transmission coefficients of intact rock and jointed rock mass both show an trend of increasing first and then decreasing, and the variation of transmission coefficients in intact rock is smaller than that of jointed rock mass. Transmission coefficient of jointed rock mass decreases with the increase of the number of joints under the same loading condition, when the confining pressure is relatively small, the reduction of transmission coefficients decreases with the increasing of the number of joints, and the variation law of the reduction of transmission coefficients is contrary when the confining pressure is large.

Permeability measurements on rock samples from Unzen Scientific Drilling Project Drill Hole 4 (USDP-4)

NASA Astrophysics Data System (ADS)

Watanabe, Tohru; Shimizu, Yuhta; Noguchi, Satoshi; Nakada, Setsuya

2008-07-01

Permeability measurement was made on five rock samples from USDP-4 cores. Rock samples were collected from the conduit zone and its country rock. One sample (C14-1-1) is considered as a part of the feeder dyke for the 1991-1995 eruption. The transient pulse method was employed under confining pressure up to 50 MPa. Compressional wave velocity was measured along with permeability. The measured permeability ranges from 10 - 19 to 10 - 17 m 2 at the atmospheric pressure, and is as low as that reported for tight rocks such as granite. The permeability decreases with increasing confining pressure, while the compressional wave velocity increases. Assuming that pores are parallel elliptical tubes, the pressure dependence of permeability requires aspect ratio of 10 - 4 -10 - 2 at the atmospheric pressure. The pore aperture is estimated to be less than 1 μm. The estimated aspect ratio and pore aperture suggest that connectivity of pores is maintained by narrow cracks. The existence of cracks is supported by the pressure dependence of compressional wave velocity. Narrow cracks (< 1 μm) are observed in dyke samples, and they must have been created after solidification. Dyke samples do not provide us information of pore structures during degassing, since exsolved gas has mostly escaped and pores governing the gas permeable flow should have been lost. Both dyke and country rock samples provide us information of materials around ascending magma. Although the measured small-scale permeability cannot be directly applied to geological-scale processes, it gives constrains on studies of large-scale permeability.

Determination of rock properties by low-frequency AC electrokinetics

NASA Astrophysics Data System (ADS)

Pengra, David B.; Xi Li, Sidney; Wong, Po-Zen

1999-12-01

In brine-saturated rock the existence of a mobile space charge at the fluid/solid interface leads to the electrokinetic phenomena of electroosmotic pressure and streaming potential. The coupling coefficients of these electrokinetic effects, when combined with the conductivity of the brine-saturated rock, determine the brine permeability of rock exactly. A sensitive low-frequency AC technique has been used to measure electrokinetic response of a collection of eight rock and four glass bead samples saturated with NaCl brine as a function of salt concentration (fluid conductivity of 0.5 to 6.38 S/m); the response of four of the original 12 samples has also been measured as a function of temperature from 0° to 50°C. All data verify the predicted permeability relationship. Additionally, the frequency response of the electroosmotic pressure signal alone can also be used to determine the permeability, given knowledge of experimental parameters. The concentration and temperature dependence of electroosmosis and streaming potential is found to mostly conform to the predictions of a simple model based on the Helmholtz-Smoluchowski equation, the Stern model of the electrochemical double layer, and an elementary theory of ionic conduction.

Replacement processes in crystalline rocks

NASA Astrophysics Data System (ADS)

John, Timm; Putnis, Andrew

2010-05-01

A substantial question in metamorphism is what is the mechanism that dominates the conversion of one mineral assemblage to another in response to a change in the ambient physical and/or chemical conditions. Petrological, microstructural, and isotopic data indicate that aqueous fluids must be involved even in the reequilibration of large-scale systems. Fluid-mineral reactions take place by dissolution - precipitation processes, but converting one solid rock to another requires pervasive, either dominantly advective or diffusive fluid-mediated transport through the entire rock. The generation of reaction-induced porosity and the spatial and temporal coupling of dissolution and precipitation can account for fluid and element transport through rocks and the replacement of one mineral assemblage by another. To determine the mechanism of metamorphic reactions we refer to examples of interfaces and reaction textures which contain both the "before" (precursor) and "after" mineral assemblages - case studies where the process of conversion is frozen in. We will illustrate some aspects of the role of fluids in metamorphic reactions and discuss how reactive fluids can pervasively infiltrate a rock. The examples we will use are focussed on crystalline rocks and include reactions from the lower continental crust, the subducting oceanic crust, and the continental upper crust to show that except at very high-temperature conditions, essentially the same mechanisms are responsible for converting rocks to thermodynamically more stable mineral assemblages for given Pressure-Temperature-fluid composition (P-T-X) conditions.

Fabric symmetry of low anisotropic rocks inferred from ultrasonic sounding: Implications for the geomechanical models

NASA Astrophysics Data System (ADS)

Přikryl, Richard; Lokajíček, Tomáš; Pros, Zdeněk; Klíma, Karel

2007-02-01

The geomechanical models were established based on the absence or presence of certain rock fabric elements — texture (crystallographic preferred orientation), microstructure (shape preferred orientation) and microcracks (flat voids). The proposed models include both (i) the ideal material showing random texture and structure but no microcracks, i.e. the material which is hardly to be found in nature, and (ii) the materials possessing various combinations of fabric elements that show different spatial arrangements. The mutual relationship between those parameters and seismic and geomechanical properties are discussed. Selected models were experimentally verified during laboratory experiments. These consist of measurement of P-wave velocities in 132 independent directions under several confining pressures in the range 0.1-400 MPa. From measured data 3D P-wave patterns can be constructed and the influence of microcracks and of texture and structure on the rock seismic anisotropy can be determined. The seismic anisotropy established at different levels of confining pressure can be used for the interpretation of rock fabric symmetry of rocks showing low anisotropy in macroscale and for the selection of directions in which the geomechanical test can be performed. The measured P-wave velocities were then mathematically processed by using a fitting function V=V+k·P-v·10 which reflects contribution of P-wave velocity in the mineral skeleton of an ideal sample without microcracks extrapolated to the atmospheric pressure level from high confining pressure interval (ca. 200-400 MPa) ( v0), linear compressibility of the samples ( kv), and confining pressure during which most of the cracks are closed ( P0). These parameters improve the understanding of the response of various rock fabric elements on increasing confinement and corresponding changes in elasticity. The observed seismic and geomechanical anisotropies reflect intensity of the fabric of rock-forming minerals and

A multi-particle crushing apparatus for studying rock fragmentation due to repeated impacts

NASA Astrophysics Data System (ADS)

Huang, S.; Mohanty, B.; Xia, K.

2017-12-01

Rock crushing is a common process in mining and related operations. Although a number of particle crushing tests have been proposed in the literature, most of them are concerned with single-particle crushing, i.e., a single rock sample is crushed in each test. Considering the realistic scenario in crushers where many fragments are involved, a laboratory crushing apparatus is developed in this study. This device consists of a Hopkinson pressure bar system and a piston-holder system. The Hopkinson pressure bar system is used to apply calibrated dynamic loads to the piston-holder system, and the piston-holder system is used to hold rock samples and to recover fragments for subsequent particle size analysis. The rock samples are subjected to three to seven impacts under three impact velocities (2.2, 3.8, and 5.0 m/s), with the feed size of the rock particle samples limited between 9.5 and 12.7 mm. Several key parameters are determined from this test, including particle size distribution parameters, impact velocity, loading pressure, and total work. The results show that the total work correlates well with resulting fragmentation size distribution, and the apparatus provides a useful tool for studying the mechanism of crushing, which further provides guidelines for the design of commercial crushers.

Is Absence of Evidence of UHPM Evidence of Absence: Did Conditions on Earth Before the Ediacaran Period Allow Formation of UHP Rocks but Only Rarely Their Exhumation?

NASA Astrophysics Data System (ADS)

Brown, M.

2008-12-01

UHPM provides petrologic evidence of transport of continental lithosphere to asthenospheric depth and return of some of these materials to crustal depth. The rock record registers UHPM since the Ediacaran Period, and studies of inclusion assemblages in zircon have increased the evidence of UHPM in Phanerozoic orogens and enabled an assessment of the real estate involved. Plots of apparent thermal gradient vs. age of metamorphism and P vs. age of metamorphism reveal two dramatic changes in inferred thermal environment and inferred depth of metamorphism from which continental lithosphere has been recovered during Earth evolution. First, from the Mesoarchean Era to the Neoproterozoic Era, sutures in subduction-to- collision orogens are marked by eclogite and high-pressure granulite metamorphism (characterized by apparent thermal gradients of 750-350 C/GPa). The P of metamorphism in sutures jumped from <1 GPa during the Eoarchean-Paleoarchean up to 2 GPa during the Paleoproterozoic. Second, from the Cryogenian- Ediacaran to the present, many sutures in subduction-to-collision orogens, and sometimes intracratonic sutures in the overriding plate, are marked by UHPM (characterized by apparent thermal gradients of <350 C/GPa) with P of metamorphism >2.7GPa. Given this pattern of secular change to colder apparent thermal gradients in sutures, the recent discovery of diamonds in zircons of crustal paragenesis in Neoarchean sedimentary rocks is surprising. Maybe UHPM has been possible since the Neoarchean but the evidence was rarely exhumed or if exhumed maybe the evidence was rarely preserved? The Appalachian/Caledonian-Variscide-Altaid and the Cimmerian-Himalayan-Alpine orogenic systems were formed by successive closure of short-lived oceans by transfer and suturing of ribbon-continent terranes derived from the Gondwanan side. Subduction of young ocean lithosphere followed by choking of the subduction channel by arc or terrane collision limited transport of water to the

Ultra-high vacuum compatible preparation chain for intermetallic compounds

NASA Astrophysics Data System (ADS)

Bauer, A.; Benka, G.; Regnat, A.; Franz, C.; Pfleiderer, C.

2016-11-01

We report the development of a versatile material preparation chain for intermetallic compounds, which focuses on the realization of a high-purity growth environment. The preparation chain comprises an argon glovebox, an inductively heated horizontal cold boat furnace, an arc melting furnace, an inductively heated rod casting furnace, an optically heated floating-zone furnace, a resistively heated annealing furnace, and an inductively heated annealing furnace. The cold boat furnace and the arc melting furnace may be loaded from the glovebox by means of a load-lock permitting to synthesize compounds starting with air-sensitive elements while handling the constituents exclusively in an inert gas atmosphere. All furnaces are all-metal sealed, bakeable, and may be pumped to ultra-high vacuum. We find that the latter represents an important prerequisite for handling compounds with high vapor pressure under high-purity argon atmosphere. We illustrate the operational aspects of the preparation chain in terms of the single-crystal growth of the heavy-fermion compound CeNi2Ge2.

The Influence of Lithology on the Formation of Reaction Infiltration Instabilities in Mantle Rocks

NASA Astrophysics Data System (ADS)

Pec, M.; Holtzman, B. K.; Zimmerman, M. E.; Kohlstedt, D. L.

2017-12-01

The formation of oceanic plates requires extraction of large volumes of melt from the mantle. Several lines of evidence suggest that melt extraction is rapid and, therefore, necessitates high-permeability pathways. Such pathways may form as a result of melt-rock reactions. We report the results of a series of Darcy-type experiments designed to study the development of channels due to melt-solid reactions in mantle lithologies. We sandwiched a partially molten rock between a melt source and a porous sink and annealed it at high pressure (P = 300 MPa) and high temperatures (T = 1200° or 1250°C) with a controlled pressure gradient (∂P/∂z = 0-100 MPa/mm). To study the influence of lithology on the channel formation, we synthesized partially molten rocks of harzburgitic (40:40:20 Ol - Opx - basalt), wehrlitic (40:40:20 Ol - Cpx - basalt) and lherzolitic (65:25:10 Ol - Opx - Cpx) composition. The melt source was a disk of alkali basalt. In all experiments, irrespective of the exact mineralogy, melt - undersaturated in silica - from the source dissolved pyroxene in the partially molten rock and precipitated olivine ( Fo82), thereby forming a dunite reaction layer at the interface between the source and the partially molten rock. In samples annealed under a small pressure gradient, the reaction layer was roughly planar. However, if the velocity of melt due to porous flow exceeded 0.1 µm/s, the reaction layer locally protruded into the partially molten rock forming finger-like, melt-rich channels in rocks of wehrlitic and harzburgitic composition. The lherzolitic rocks were generally impermeable to the melt except at highest-pressure gradients where a narrow fracture developed, forming a dyke which drained the melt reservoir. Three-dimensional reconstructions using micro-CT images revealed clear differences between the dyke (a narrow, through-going planar feature) and the channels formed by reactive infiltration (multiple sinuous finger-like features). Apparently

Ultrahigh 6D-brightness electron beams for the light sources of the next generation

NASA Astrophysics Data System (ADS)

Habib, Fahim; Manahan, Grace G.; Scherkl, Paul; Heinemann, Thomas; Sheng, Z. M.; Bruhwiler, D. L.; Cary, J. R.; Rosenzweig, J. B.; Hidding, Bernhard

2017-10-01

The plasma photocathode mechanism (aka Trojan Horse) enables a path towards electron beams with nm-level normalized emittance and kA range peak currents, hence ultrahigh 5D-brightness. This ultrahigh 5D-brightness beams hold great prospects to realize laboratory scale free-electron-lasers. However, the GV/m-accelerating gradient in plasma accelerators leads to substantial energy chirp and spread. The large energy spread is a major show-stopper towards key application such as the free-electron-laser. Here we present a novel method for energy chirp compensation which takes advantage of tailored beam loading due to a second ``escort'' bunch released via plasma photocathode. The escort bunch reverses the accelerating field locally at the trapping position of the ultrahigh 5D-brightness beam. This induces a counter-clockwise rotation within the longitudinal phase space and allows to compensate the chirp completely. Analytical scaling predicts energy spread values below 0.01 percentage level. Ultrahigh 5D-brightness combined with minimized energy spread opens a path towards witness beams with unprecedented ultrahigh 6D-brightness.

Pressure-induced phase transition in GaN nanocrystals

NASA Astrophysics Data System (ADS)

Cui, Q.; Pan, Y.; Zhang, W.; Wang, X.; Zhang, J.; Cui, T.; Xie, Y.; Liu, J.; Zou, G.

2002-11-01

High-pressure in situ energy-dispersive x-ray diffraction experiments on GaN nanocrystals with 50 nm diameter have been carried out using a synchrotron x-ray source and a diamond-anvil cell up to about 79 GPa at room temperature. A pressure-induced first-order structural phase transition from the wurtzite-type structure to the rock-salt-type structure starts at about 48.8 GPa. The rock-salt-type phase persists to the highest pressure in our experimental range.

APS 6BM-B Large Volume High Pressure Beamline: A Workhorse for Rock and Mineral Physics

NASA Astrophysics Data System (ADS)

Chen, H.; Whitaker, M. L.; Baldwin, K. J.; Huebsch, W. R.; Vaughan, M. T.; Weidner, D. J.

2017-12-01

With the inheritance of decades of technical innovations at the NSLS X17B2 Beamline, APS 6BM-B Beamline was established in 2015 and is a dedicated beamline for synchrotron-based large volume high pressure research in earth sciences, especially rock and mineral physics. Currently a 250-ton hydraulic press equipped with a D-DIA module is installed and a Rotational Drickamer Apparatus from Yale University is hosted every cycle, covering a pressure range from crust to lower mantle. 6BM-B operates in white beam mode with an effective energy range of 20-100 keV. Energy dispersive X-ray diffraction data is collected using a 10-element solid state Ge array detector arranged in a circular geometry to allow for the real time assessment of stress. Direct radiographic imaging using Prosillica CCD camera and scintillating YAG crystals yields sample strain and strain rate. In addition to applications in phase transitions, equation of states measurements, sound velocity measurements, this setup is ideal for studies of steady state and dynamic deformation process. In this presentation, technical features and strengths of 6BM-B will be discussed. Most recent progress and science highlights of our user community will be showcased.

Characterization of Gas Transport Properties of Fractured Rocks By Borehole and Chamber Tests.

NASA Astrophysics Data System (ADS)

Shimo, M.; Shimaya, S.; Maejima, T.

2014-12-01

Gas transport characteristics of fractured rocks is a great concern to variety of engineering applications such as underground storage of LPG, nuclear waste disposal, CCS and gas flooding in the oil field. Besides absolute permeability, relative permeability and capillary pressure as a function of water saturation have direct influences to the results of two phase flow simulation. However, number of the reported gas flow tests for fractured rocks are limited, therefore, the applicability of the conventional two-phase flow functions used for porous media, such as Mualem-van Genuchten model, to prediction of the gas transport in the fractured rock mass are not well understood. The authors conducted the two types of in-situ tests, with different scales, a borehole gas-injection test and a chamber gas-injection test in fractured granitic rock. These tests were conducted in the Cretaceous granitic rocks at the Namikata underground LPG storage cavern construction site in Ehime Prefecture in Japan, preceding to the cavern scale gas-tightness test. A borehole injection test was conducted using vertical and sub-vertical boreholes drilled from the water injection tunnel nearly at the depth of the top of the cavern, EL-150m. A new type downhole gas injection equipment that is capable to create a small 'cavern' within a borehole was developed. After performing a series of preliminary tests to investigate the hydraulic conductivity and gas-tightness, i.e. threshold pressure, gas injection tests were conducted under different gas pressure. Fig.1 shows an example of the test results From a chamber test using a air pressurizing chamber with volume of approximately166m3, the gas-tightness was confirmed within the uncertainty of 22Pa under the storage pressure of 0.7MPa, however, significant air leakage occurred possibly through an open fracture intersecting the chamber just after cavern pressure exceeds the initial hydrostatic pressure at the ceiling level of the chamber. Anomalies

Feature Screening for Ultrahigh Dimensional Categorical Data with Applications.

PubMed

Huang, Danyang; Li, Runze; Wang, Hansheng

2014-01-01

Ultrahigh dimensional data with both categorical responses and categorical covariates are frequently encountered in the analysis of big data, for which feature screening has become an indispensable statistical tool. We propose a Pearson chi-square based feature screening procedure for categorical response with ultrahigh dimensional categorical covariates. The proposed procedure can be directly applied for detection of important interaction effects. We further show that the proposed procedure possesses screening consistency property in the terminology of Fan and Lv (2008). We investigate the finite sample performance of the proposed procedure by Monte Carlo simulation studies, and illustrate the proposed method by two empirical datasets.