Healing of rat mouth mucosa after irradiation with CO2, Nd:YAG, and CO2-Nd:YAG combination lasers.

PubMed

Luomanen, M; Rauhamaa-Mäkinen, R; Meurman, J H; Kosloff, T; Tiitta, O

1994-08-01

The healing process of wounds made by a combination laser was studied in 90 rats. The laser system enabled both separate and combined use of CO2 and Nd:YAG laser irradiations. The laser wounds and the control excision wounds made by alligator forceps appeared on both sides of the tongue. Specimens from the wound sites were taken immediately, 6 h, and 1, 2, 4, 7, 11, 21, 28, and 42 days after surgery. The wound-healing process was studied by macroscopic evaluation before preparing the specimens for light microscopy. Some differences were noted in the wound-healing process among the three groups into which the experimental animals were divided. Tissue coagulation damage was most extensive in the Nd:YAG laser sites, where it was observed in its full extent 4 days after surgery. Epithelial cells were seen to begin to proliferate in all the wounds 6 h after surgery. Re-epithelialization was completed by between 7 (CO2) and 21 days (Nd:YAG) at all the wound sites. The inflammatory cell infiltration was more prominent in the Nd:YAG and the CO2-Nd:YAG combination laser wounds than in the CO2 and excision wounds during healing. Tissue regeneration occurred faster with less contraction in the combination CO2-Nd:YAG wounds than in Nd:YAG wounds. The best macroscopic healing result was seen in the CO2 wound sites. The combination laser was effective both at cutting and at coagulating tissue. Combining the CO2 and Nd:YAG laser irradiation into one beam resulted in a greater incision depth than what could have been expected from using the two lasers separately.

Magnetic properties and magnetocrystalline anisotropy of Nd 2Fe 17, Nd 2Fe 17X 3, and related compounds

DOE PAGES

Pandey, Tribhuwan; Parker, David S.

2018-02-26

The electronic and magnetic properties of Nd 2Fe 17 and Nd 2Fe 17X 3 (X = C or N) compounds have been calculated using the first-principles density functional calculations. Among these, the nitrogen and carbon interstitial compounds exhibit all of the required properties such as a saturation moment of 1.6 T, Curie temperature of 700–750 K, however easy magnetic axis lies in the planar direction making them less attractive for permanent magnet applications. The calculated magnetocrystalline anisotropy energy is found to be -2.7 MJ/m 3 for Nd 2Fe 17C 3 and -4.7 MJ/m 3 for Nd 2Fe 17N 3. Finally,more » we further explored the possibility of changing the easy axis direction through La/Ce alloying at Nd site. Although the MAE is found to be smaller in magnitude for all the La/Ce alloys it still maintains planar direction.« less

Ultrashort Echo Time and Zero Echo Time MRI at 7T

PubMed Central

Larson, Peder E. Z.; Han, Misung; Krug, Roland; Jakary, Angela; Nelson, Sarah J.; Vigneron, Daniel B.; Henry, Roland G.; McKinnon, Graeme; Kelley, Douglas A. C.

2016-01-01

Object Zero echo time (ZTE) and ultrashort echo time (UTE) pulse sequences for MRI offer unique advantages of being able to detect signal from rapidly decaying short-T2 tissue components. In this paper, we applied 3D zero echo time (ZTE) and ultrashort echo time (UTE) pulse sequences at 7T to assess differences between these methods. Materials and Methods We matched the ZTE and UTE pulse sequences closely in terms of readout trajectories and image contrast. Our ZTE used the Water- and fat-suppressed solid-state proton projection imaging (WASPI) method to fill the center of k-space. Images from healthy volunteers obtained at 7T were compared qualitatively as well as with SNR and CNR measurements for various ultrashort, short, and long-T2 tissues. Results We measured nearly identical contrast-to-noise and signal-to-noise ratios (CNR/SNR) in similar scan times between the two approaches for ultrashort, short, and long-T2 components in the brain, knee and ankle. In our protocol, we observed gradient fidelity artifacts in UTE, and our chosen flip angle and readout also resulted as well as shading artifacts in ZTE due to inadvertent spatial selectivity. These can be corrected by advanced reconstruction methods or with different chosen protocol parameters. Conclusion The applied ZTE and UTE pulse sequences achieved similar contrast and SNR efficiency for volumetric imaging of ultrashort-T2 components. Several key differences are that ZTE is limited to volumetric imaging but has substantially reduced acoustic noise levels during the scan. Meanwhile, UTE has higher acoustic noise levels and greater sensitivity to gradient fidelity, but offers more flexibility in image contrast and volume selection. PMID:26702940

Quasi-three level Nd:YLF fundamental and Raman laser operating under 872-nm and 880-nm direct diode pumping

NASA Astrophysics Data System (ADS)

Wetter, Niklaus U.; Bereczki, Allan; Paes, João. Pedro Fonseca

2018-02-01

Nd:YLiF4 is the gain material of choice whenever outstanding beam quality or a birefringent gain material is necessary such as in certain applications for terahertz radiation or dual-frequency mode-locking. However, for high power CW applications the material is hampered by a low thermal fracture threshold. This problem can be mitigated by special 2D pump set-ups or by keeping the quantum defect to a minimum. Direct pumping into the upper laser level of Nd:YLiF4 is usually performed at 880 nm. For quasi-three level laser emission at 908 nm, direct pumping at this wavelength provides a high quantum defect of 0.97, which allows for very high CW pump powers. Although the direct pumping transition to the upper laser state at 872 nm has a slightly smaller quantum defect of 0.96, its pump absorption cross section along the c-axis is 50% higher than at 880 nm, leading to a higher absorption efficiency. In this work we explore, for the first time to our knowledge, 908 nm lasing under 872 nm diode pumping and compare the results with 880 nm pumping for quasicw and cw operation. By inserting a KGW crystal in the cavity, Raman lines at 990 nm and 972 nm were obtained for the first time from a directly pumped 908 nm Nd:YLF fundamental laser for both quasi-cw and cw conditions.

Fracture toughness of ultrashort pulse-bonded fused silica

NASA Astrophysics Data System (ADS)

Richter, S.; Naumann, F.; Zimmermann, F.; Tünnermann, A.; Nolte, S.

2016-02-01

We determined the bond interface strength of ultrashort pulse laser-welded fused silica for different processing parameters. To this end, we used a high repetition rate ultrashort pulse laser system to inscribe parallel welding lines with a specific V-shaped design into optically contacted fused silica samples. Afterward, we applied a micro-chevron test to measure the fracture toughness and surface energy of the laser-inscribed welding seams. We analyzed the influence of different processing parameters such as laser repetition rate and line separation on the fracture toughness and fracture surface energy. Welding the entire surface a fracture toughness of 0.71 {MPa} {m}^{1/2}, about 90 % of the pristine bulk material ({≈ } 0.8 {MPa} {m}^{1/2}), is obtained.

Highly efficient continuous-wave laser operation of LD-pumped Nd,Gd:CaF2 and Nd,Y:CaF2 crystals

NASA Astrophysics Data System (ADS)

Pang, Siyuan; Ma, Fengkai; Yu, Hao; Qian, Xiaobo; Jiang, Dapeng; Wu, Yongjing; Zhang, Feng; Liu, Jie; Xu, Jiayue; Su, Liangbi

2018-05-01

Spectroscopic properties of Nd:CaF2 crystals are investigated. The photoluminescence intensity in the near infrared region is drastically enhanced by co-doping Gd3+ ions and Y3+ in Nd:CaF2 crystals. Preliminary laser experiments are carried out with 0.3%Nd,5%Gd:CaF2 and 0.3%Nd,5%Y:CaF2 crystals under laser diode pumping; true continuous wave laser operation is achieved with slope efficiencies of 42% and 39%, respectively, and the maximum output power reaches 1.188 W.

Ultrashort Pulse (USP) Laser-Matter Interactions

DTIC Science & Technology

2013-03-05

spectroscopy • Frequency/time transfer • High-capacity comms • Coherent LIDAR • Optical clocks • Calibration Material Science ultrashort, high...Laboratory 41 Laser -driven x-rays generation (0.1 – 10 MeV) • Scattering from a 300 MeV electron beam can Doppler shift a 1-eV energy laser ...1 Integrity  Service  Excellence Ultrashort Pulse (USP) Laser – Matter Interactions 5 MAR 2013 Dr. Riq Parra Program Officer AFOSR/RTB

Photon-induced positron annihilation lifetime spectroscopy using ultrashort laser-Compton-scattered gamma-ray pulses

NASA Astrophysics Data System (ADS)

Taira, Y.; Toyokawa, H.; Kuroda, R.; Yamamoto, N.; Adachi, M.; Tanaka, S.; Katoh, M.

2013-05-01

High-energy ultrashort gamma-ray pulses can be generated via laser Compton scattering with 90° collisions at the UVSOR-II electron storage ring. As an applied study of ultrashort gamma-ray pulses, a new photon-induced positron annihilation lifetime spectroscopy approach has been developed. Ultrashort gamma-ray pulses with a maximum energy of 6.6 MeV and pulse width of 2.2 ps created positrons throughout bulk lead via pair production. Annihilation gamma rays were detected by a BaF2 scintillator mounted on a photomultiplier tube. A positron lifetime spectrum was obtained by measuring the time difference between the RF frequency of the electron storage ring and the detection time of the annihilation gamma rays. We calculated the response of the BaF2 scintillator and the time jitter caused by the variation in the total path length of the ultrashort gamma-ray pulses, annihilation gamma rays, and scintillation light using a Monte Carlo simulation code. The positron lifetime for bulk lead was successfully measured.

Electronic structure of layered titanate Nd 2Ti 2O 7

NASA Astrophysics Data System (ADS)

Atuchin, V. V.; Gavrilova, T. A.; Grivel, J.-C.; Kesler, V. G.

2008-10-01

The electronic structure of the binary titanate Nd 2Ti 2O 7 has been studied by X-ray photoelectron spectroscopy (XPS). Spectral features of the valence band and all constituent element core levels have been considered. The Auger parameters of titanium and oxygen in Nd 2Ti 2O 7 are determined as αTi = 873.5 and αO = 1042.2 eV. Chemical bonding effects have been discussed with the binding energies differences ΔTi = (BE O 1s - BE Ti 2p 3/2) = 71.5 eV and ΔNd = (BE Nd 3d 5/2 - BE O 1s) = 452.5 eV as key parameters in comparison with those in other titanium- and neodymium-bearing oxides.

Epitaxial growth of iridate pyrochlore Nd 2Ir 2O 7 films

DOE PAGES

Gallagher, J. C.; Esser, B. D.; Morrow, R.; ...

2016-02-29

Epitaxial films of the pyrochlore Nd 2Ir 2O 7 have been grown on (111)-oriented yttria-stabilized zirconia (YSZ) substrates by off-axis sputtering followed by post-growth annealing. X-ray diffraction (XRD) results demonstrate phase-pure epitaxial growth of the pyrochlore films on YSZ. Scanning transmission electron microscopy (STEM) investigation of an Nd 2Ir 2O 7 film with a short post-annealing provides insight into the mechanism for crystallization of Nd 2Ir 2O 7 during the post-annealing process. STEM images reveal clear pyrochlore ordering of Nd and Ir in the films. As a result, the epitaxial relationship between the YSZ and Nd 2Ir 2O 7 ismore » observed clearly while some interfacial regions show a thin region with polycrystalline Ir nanocrystals.« less

VizieR Online Data Catalog: ND2 rotational spectrum (Melosso+,

NASA Astrophysics Data System (ADS)

Melosso, M.; Degli Esposti, C.; Dore, L.

2018-01-01

files used with the SPFIT/SPCAT program suite. There are 8 files of supplementary material, including a ReadMe, which was created by the AAS data editors. The text files are as follows: 1_Explan.txt = information on the content of the other files. 2ND2.fit = the output file of the fit of spectroscopic data used in the present study. 3ND2.lin = the corresponding line file. 4ND2.par = the corresponding parameter file. 5ND2.cat = the output file of the prediction made with the parameters determined in this study. 6ND2.var = the corresponding parameter file 7ND2.int = the corresponding intensity file (1 data file).

Low temperature magnetic properties of Nd2Ru2O7

NASA Astrophysics Data System (ADS)

Ku, S. T.; Kumar, D.; Lees, M. R.; Lee, W.-T.; Aldus, R.; Studer, A.; Imperia, P.; Asai, S.; Masuda, T.; Chen, S. W.; Chen, J. M.; Chang, L. J.

2018-04-01

We present magnetic susceptibility, heat capacity, and neutron diffraction measurements of polycrystalline Nd2Ru2O7 down to 0.4 K. Three anomalies in the magnetic susceptibility measurements at 146, 21 and 1.8 K are associated with an antiferromagnetic ordering of the Ru4+ moments, a weak ferromagnetic signal attributed to a canting of the Ru4+ and Nd3+ moments, and a long-range-ordering of the Nd3+ moments, respectively. The long-range order of the Nd3+ moments was observed in all the measurements, indicating that the ground state of the compound is not a spin glass. The magnetic entropy of Rln2 accumulated up to 5 K, suggests the Nd3+ has a doublet ground state. Lattice distortions accompany the transitions, as revealed by neutron diffraction measurements, and in agreement with earlier synchrotron x-ray studies. The magnetic moment of the Nd3+ ion at 0.4 K is estimated to be 1.54(2)µ B and the magnetic structure is all-in all-out as determined by our neutron diffraction measurements.

The expression characteristics of mt-ND2 gene in chicken.

PubMed

Zhang, Wenwen; Hou, Lingling; Wang, Ting; Lu, Weiwei; Tao, Yafei; Chen, Wen; Du, Xiaohui; Huang, Yanqun

2016-09-01

Subunit 2 of NADH dehydrogenase (ND2) is encoded by the mt-ND2 gene and plays a critical role in controlling the production of the mitochondrial reactive oxygen species. Our study focused on exploring the mt-ND2 tissue expression patterns and the effects of energy restriction and dietary fat (linseed oil, corn oil, sesame oil or lard) level (2.5% and 5%) on its expression in chicken. The results showed that mt-ND2 gene was expressed in the 15 tissues of hybrid chickens with the highest level in heart and lowest level in pancreas tissue; 30% energy restriction did not significantly affect mt-ND2 mRNA level in chicken liver tissue. Both the mt-ND2 mRNA levels in chicken pectoralis (p < 0.05) and hepatic tissues (p < 0.05) at 42 d-old were affected by the type of dietary fats in 5% level, while not in abdominal fat tissues. The expression of mt-ND2 in hepatic tissues was down-regulated with chicken age (p < 0.01). The interactive effect of dietary fat types with chicken age (p < 0.05) was significant on mt-ND2 mRNA level. The study demonstrated that mt-ND2 gene was extensively expressed in tissues, and the expression was affected by dietary fat types and chicken age.

Textured Nd2Fe14B flakes with enhanced coercivity

NASA Astrophysics Data System (ADS)

Cui, B. Z.; Zheng, L. Y.; Marinescu, M.; Liu, J. F.; Hadjipanayis, G. C.

2012-04-01

Morphology, structure, and magnetic properties of the [001] textured Nd2Fe14B nanocrystalline flakes prepared by surfactant-assisted high energy ball milling (HEBM) and subsequent annealing were studied. These flakes have a thickness of 80-200 nm, a length of 0.5-10 μm, and an average grain size of 10-14 nm. The addition of some amount of Dy, Nd70Cu30 alloy, and an appropriate post annealing increased the coercivity iHc of the Nd2Fe14B flakes. iHc was 3.7, 4.3, and 5.7 kOe for the Nd15.5Fe78.5B6, Nd14Dy1.5Fe78.5B6 and 83.3 wt.% Nd14Dy1.5Fe78.5B6 + 16.7 wt.% Nd70Cu30 flakes prepared by HEBM for 5 h in heptane with 20 wt.% oleylamine, respectively. After annealing at 450 °C for 0.5 h, their iHc increased to 5.1, 6.2, and 7.0 kOe, respectively. Anisotropic magnetic behavior was found in all of the as-milled and annealed flakes. Both, the thickening of Nd-rich phase at grain boundaries via diffusion of Nd70Cu30 and the surface modification of the Nd2Fe14B flake could be the main reasons for the coercivity enhancement in the as-milled and annealed Nd70Cu30-added Nd2Fe14B flakes.

Ultrashort-pulse laser generated nanoparticles of energetic materials

DOEpatents

Welle, Eric J [Niceville, NM; Tappan, Alexander S [Albuquerque, NM; Palmer, Jeremy A [Albuquerque, NM

2010-08-03

A process for generating nanoscale particles of energetic materials, such as explosive materials, using ultrashort-pulse laser irradiation. The use of ultrashort laser pulses in embodiments of this invention enables one to generate particles by laser ablation that retain the chemical identity of the starting material while avoiding ignition, deflagration, and detonation of the explosive material.

Textured Nd2Fe14B flakes with enhanced coercivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cui, BZ; Zheng, LY; Marinescu, M

2012-04-01

Morphology, structure, and magnetic properties of the [001] textured Nd2Fe14B nanocrystalline flakes prepared by surfactant-assisted high energy ball milling (HEBM) and subsequent annealing were studied. These flakes have a thickness of 80-200 nm, a length of 0.5-10 mu m, and an average grain size of 10-14nm. The addition of some amount of Dy, Nd70Cu30 alloy, and an appropriate post annealing increased the coercivity H-i(c) of the Nd2Fe14B flakes. iHc was 3.7, 4.3, and 5.7 kOe for the Nd15.5Fe78.5B6, Nd14Dy1.5Fe78.5B6 and 83.3wt.% Nd14Dy1.5Fe78.5B6+16.7 wt.% Nd70Cu30 flakes prepared by HEBM for 5 h in heptane with 20 wt.% oleylamine, respectively. After annealingmore » at 450 degrees C for 0.5h, their iHc increased to 5.1, 6.2, and 7.0 kOe, respectively. Anisotropic magnetic behavior was found in all of the as-milled and annealed flakes. Both, the thickening of Nd-rich phase at grain boundaries via diffusion of Nd70Cu30 and the surface modification of the Nd2Fe14B flake could be the main reasons for the coercivity enhancement in the as-milled and annealed Nd70Cu30-added Nd2Fe14B flakes. (C) 2012 American Institute of Physics. [doi: 10.1063/1.3679425]« less

Impedance spectroscopy study of SiO2-Li2O:Nd2O3 glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pereia, R.; Gozzo, C B; Guedes, I.

2014-01-01

In the present study, neodymium-doped lithium silicate glasses have been prepared by the conventional melt-quenching technique. The dielectric properties, electric modulus and electrical conductivity of SiO2-Li2O (SiLi-0Nd) and SiO2-Li2O:Nd2O3 (SiLi-1.35Nd) have been studied from 1 Hz to 1 MHz in the 333 423 K temperature range. At a given temperature and frequency, we observe that the resistivity increases while the conductivity accordingly decreases when neodymium ions are added to the glass matrix. The activation energy of two distinct regions was evaluated from the ln( dc)=f(1/T) plot and was found to be E1(T<363K)=0.61(0.66)eV and E2(T>363K)=1.26(1.09)eV for SiLi-0Nd (SiLi-1,35Nd). The dielectric constantmore » ( Re) decreases while the dielectric loss (tan ( )) increases under Nd2O3 doping. We also observe that for both glasses, Re and tan ( ) tend to increase with increasing temperature and decrease with increasing frequency.« less

Hybrid Pulsed Nd:YAG Laser

NASA Astrophysics Data System (ADS)

Miller, Sawyer; Trujillo, Skyler; Fort Lewis College Laser Group Team

This work concerns the novel design of an inexpensive pulsed Nd:YAG laser, consisting of a hybrid Kerr Mode Lock (KLM) and Q-switch pulse. The two pulse generation systems work independently, non simultaneously of each other, thus generating the ability for the user to easily switch between ultra-short pulse widths or large energy density pulses. Traditionally, SF57 glass has been used as the Kerr medium. In this work, novel Kerr mode-locking mediums are being investigated including: tellurite compound glass (TeO2), carbon disulfide (CS2), and chalcogenide glass. These materials have a nonlinear index of refraction orders of magnitude,(n2), larger than SF57 glass. The Q-switched pulse will utilize a Pockels cell. As the two pulse generation systems cannot be operated simultaneously, the Pockels cell and Kerr medium are attached to kinematic mounts, allowing for quick interchange between systems. Pulse widths and repetition rates will vary between the two systems. A goal of 100 picosecond pulse widths are desired for the mode-locked system. A goal of 10 nanosecond pulse widths are desired for the Q-switch system, with a desired repetition rate of 50 Hz. As designed, the laser will be useful in imaging applications.

Biological Damage Threshold Induced by Ultrashort Fundamental, 2nd, and 4th Harmonic Light Pulses from a Mode-Locked Nd: Glass Laser.

DTIC Science & Technology

1980-12-01

media. If any gross astigmatism was evident at any time during an experiment, the data for that eye were rejected. Not all previous work has followed...unlike work reported at longer wavelengths, >325 nm (26,27), no signs of any lenticular opacification were seen in any of the eyes. Retinal examinations

co2amp: A software program for modeling the dynamics of ultrashort pulses in optical systems with CO 2 amplifiers

DOE PAGES

Polyanskiy, Mikhail N.

2015-01-01

We describe a computer code for simulating the amplification of ultrashort mid-infrared laser pulses in CO 2 amplifiers and their propagation through arbitrary optical systems. This code is based on a comprehensive model that includes an accurate consideration of the CO 2 active medium and a physical optics propagation algorithm, and takes into account the interaction of the laser pulse with the material of the optical elements. Finally, the application of the code for optimizing an isotopic regenerative amplifier is described.

Substitution of Nd with other rare earth elements in melt spun Nd{sub 2}Fe{sub 14}B magnets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, D. N.; Lau, D.; Chen, Z.

2016-05-15

This is a contemporary study of rapidly quenched Nd{sub 1.6}X{sub 0.4}Fe{sub 14}B magnetic materials (where X= Nd, Y, Ce, La, Pr, Gd and Ho). A 20% substitution of the Nd component from Nd{sub 2}Fe{sub 14}B can bring about some commercial advantage. However, there will be some compromise to the magnetic performance. Light rare earth elements are definitely more abundant (Y, Ce, La) than the heavier rare earth elements, but when they are included in RE{sub 2}Fe{sub 14}B magnets they tend to lower magnetic performance and thermal stability. Substituting heavy rare earth elements (Gd, Ho) for Nd in Nd{sub 2}Fe{sub 14}Bmore » improves the thermal stability of magnets but causes a loss in magnet remanence.« less

Nd2O3-SiO2 nanocomposites: A simple sonochemical preparation, characterization and photocatalytic activity.

PubMed

Zinatloo-Ajabshir, Sahar; Mortazavi-Derazkola, Sobhan; Salavati-Niasari, Masoud

2018-04-01

Nd 2 O 3 -SiO 2 nanocomposites with enhanced photocatalytic activity have been obtained through simple and rapid sonochemical route in presence of putrescine as a new basic agent, for the first time. The influence of the mole ratio of Si:Nd, basic agent and ultrasonic power have been optimized to obtain the best Nd 2 O 3 -SiO 2 nanocomposites on shape, size and photocatalytic activity. The produced Nd 2 O 3 -SiO 2 nanocomposites have been characterized utilizing XRD, EDX, TEM, FT-IR, DRS and FESEM. Application of the as-formed Nd 2 O 3 -SiO 2 nano and bulk structures as photocatalyst with photodegradation of methyl violet contaminant under ultraviolet illumination was compared. Results demonstrated that SiO 2 has remarkable effect on catalytic performance of Nd 2 O 3 photocatalyst for decomposition. By introducing of SiO 2 to Nd 2 O 3 , decomposition efficiency of Nd 2 O 3 toward methyl violet contaminant under ultraviolet illumination was increased. Copyright © 2017 Elsevier B.V. All rights reserved.

Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives

DTIC Science & Technology

2013-02-01

DTRA-TR-12-65 Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives ...Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives HDTRA1-09-1-0021 Valery...destructive detection of volatile explosives . Moshe Shapiro1, Valery Milner1 and Jun Ye2 1University of British Columbia, Vancouver, Canada 2JILA

2nd International Symposium on Fundamental Aspects of Rare-earth Elements Mining and Separation and Modern Materials Engineering (REES-2015)

NASA Astrophysics Data System (ADS)

Tavadyan, Levon, Prof; Sachkov, Viktor, Prof; Godymchuk, Anna, Dr.; Bogdan, Anna

2016-01-01

The 2nd International Symposium «Fundamental Aspects of Rare-earth Elements Mining and Separation and Modern Materials Engineering» (REES2015) was jointly organized by Tomsk State University (Russia), National Academy of Science (Armenia), Shenyang Polytechnic University (China), Moscow Institute of Physics and Engineering (Russia), Siberian Physical-technical Institute (Russia), and Tomsk Polytechnic University (Russia) in September, 7-15, 2015, Belokuriha, Russia. The Symposium provided a high quality of presentations and gathered engineers, scientists, academicians, and young researchers working in the field of rare and rare earth elements mining, modification, separation, elaboration and application, in order to facilitate aggregation and sharing interests and results for a better collaboration and activity visibility. The goal of the REES2015 was to bring researchers and practitioners together to share the latest knowledge on rare and rare earth elements technologies. The Symposium was aimed at presenting new trends in rare and rare earth elements mining, research and separation and recent achievements in advanced materials elaboration and developments for different purposes, as well as strengthening the already existing contacts between manufactures, highly-qualified specialists and young scientists. The topics of the REES2015 were: (1) Problems of extraction and separation of rare and rare earth elements; (2) Methods and approaches to the separation and isolation of rare and rare earth elements with ultra-high purity; (3) Industrial technologies of production and separation of rare and rare earth elements; (4) Economic aspects in technology of rare and rare earth elements; and (5) Rare and rare earth based materials (application in metallurgy, catalysis, medicine, optoelectronics, etc.). We want to thank the Organizing Committee, the Universities and Sponsors supporting the Symposium, and everyone who contributed to the organization of the event and to

Influence of atomic densities on propagation property for ultrashort pulses in a two-level medium

NASA Astrophysics Data System (ADS)

Liu, Bingxin; Gong, Shangqing; Song, Xiaohong; Jin, Shiqi

2005-05-01

The influence of atomic densities on the propagation property for ultrashort pulses in a two-level atom (TLA) medium is investigated. With higher atomic densities, the self-induced transparency (SIT) cannot be recovered even for 2? ultrashort pulses. New features such as pulse splitting, red-shift and blue-shift of the corresponding spectra arise, and the component of central frequency gradually disappears.

Spectroscopic Properties of B2O3-PbO-Nd2O3 Glasses

NASA Astrophysics Data System (ADS)

Simon, V.; Ardelean, I.; Milea, I.; Peteanu, M.; Simon, S.

Samples belonging to xNd2O3(100-x) [2B2O3·PbO] glass system, with 0≤ x≤ 40 mol%, are investigated by IR and UV-VIS spectroscopies in order to obtain evidence for the influence of Nd2O3 on the local order from 2B2O3·PbO glass matrix. Besides the IR absorption bands characteristic to lead and boron arrangements, typical absorption lines of Nd3+ ions around 4000 cm-1 and 6000 cm-1 are recorded. The 6000 cm-1 band appears only for the samples with x≥25 mol% Nd2O3. The split of some UV-VIS absorption bands arising from transitions of neodymium ions in doublet lines as well as the shift of the absorption bands as the Nd2O3 content increases denote the influence of the lead-borate matrix on the radiative transitions of the lanthanide ion.

Mode-locked Nd:YAG laser with output at 1052, 1061, 1064, and 1074 nm

DOE Office of Scientific and Technical Information (OSTI.GOV)

Badalian, A.A.; Sapondzhian, S.O.; Sarkisian, D.G.

The picosecond Nd:YAG laser with an output radiation at 1064 nm is currently widely used. However, in connection with many applications, picosecond pulses at other wavelengths are also needed. The present study is, therefore, concerned with the development of a picosecond laser which provides pulses at 1052, 1061.5, and 1073.7 nm. Lasing at 1052, 1061.5, 1064, and 1073.7 nm was achieved by varying the angle between the resonator axis and the normal to the etalon by four degrees. Attention is given to the measurement of the lengths of the ultrashort pulses, and the transverse distribution of the energy in themore » second harmonic for the wavelength 1052 nm. The discretely tunable picosecond Nd:YAG laser described appears to be a promising tool for many research applications. 9 references.« less

Genetic diversities of MT-ND1 and MT-ND2 genes are associated with high-altitude adaptation in yak.

PubMed

Shi, Yu; Hu, Yongsong; Wang, Jie; Elzo, Mauricio A; Yang, Xue; Lai, Songjia

2018-04-01

Tibetan yak (Bos grunniens) inhabiting the Qinghai-Tibet Plateau (QTP) where the average altitude is 4000 m, is specially adapted to live at these altitudes. Conversely, cattle (B. taurus) has been found to suffer from high-altitude hypertension or heart failure when exposed to these high altitudes. Two mitochondrial genes, MT-ND1 and MT-ND2, encode two subunits of NADH dehydrogenase play an essential role in the electron transport chain of oxidative phosphorylation (OXPHOS). We sequenced these two mitochondrial genes in two bovine groups (70 Tibetan yaks and 70 Xuanhan cattle) and downloaded 300 sequences of B. taurus (cattle), 93 sequences of B. grunniens (domestic yak), and 2 sequences of B. mutus (wild yak) from NCBI to increase our understanding of the mechanisms of adaptability to hypoxia at high altitudes in yaks compared to cattle. MT-ND1 SNP m.3907 C > T, present in all Tibetan yaks, was positively associated with high-altitude adaptation (p < .0006). Specially, mutation m.3638 A > G present in all cattle, resulting in the termination of transcription, was negatively associated with high-altitude adaptation (p < .0006). Additionally, MT-ND2 SNPs m.4351 G > A and m.5218 C > T also showed positive associations with high-altitude adaptation (p < .0004). MT-ND1 haplotypes H2, H3, H4, H6, and H7 showed positive associations but haplotype H20 had a negative association with high-altitude adaptation (p < .0008). Similarly, MT-ND2 haplotypes Ha1 Ha8, Ha10, and Ha11 were positively associated whereas haplotype Ha2 was negatively associated with adaptability to high-altitudes (p < .0008). Thus, MT-ND1 and MT-ND2 can be considered as candidate genes associated with adaptation to high-altitude environments.

Coercivity enhancement in hot deformed Nd2Fe14B-type magnets by doping low-melting RCu alloys (R = Nd, Dy, Nd + Dy)

NASA Astrophysics Data System (ADS)

Lee, Y. I.; Huang, G. Y.; Shih, C. W.; Chang, W. C.; Chang, H. W.; You, J. S.

2017-10-01

Magnetic properties of the anisotropic NdFeB magnets prepared by hot pressing followed by die-upsetting NdFeB MQU-F powders doped with low-melting RCu alloy powders were explored, where RCu stands for Nd70Cu30, Dy70Cu30 and (Nd0.5Dy0.5)70Cu30, respectively. In addition, the post-annealing at 600 °C was employed to modify the microstructures and the magnetic properties of the hot deformed magnets. It is found that doping RCu alloy powders is effective in enhancing the coercivity of the hot deformed NdFeB magnets from 15.1 kOe to 16.3-19.5 kOe. For Nd70Cu30-doped magnets, the increment of coercivity is only 1.2 kOe. Meanwhile, Dy70Cu30-doped and (Nd0.5Dy0.5)70Cu30-doped magnets show an almost identical enhancement of coercivity of about 4.4 kOe. Importantly, the latter magnet shows a beneficial effect of reducing the usage of Dy from 1.6 wt% to 0.8 wt%. TEM analysis shows that nonmagnetic Nd, Dy and Cu appear at grain boundary and isolate the magnetic grains, leading to an enhancement of coercivity. Doping lower melting point Dy-lean (Nd0.5Dy0.5)70Cu30 powders into commercial MQU-F powders for making high coercivity hot deformed NdFeB magnets might be a potential and economic way for mass production.

37. MILL NO. 2, 2nd FLOOR, CLOSE SHOT OF 2 ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

37. MILL NO. 2, 2nd FLOOR, CLOSE SHOT OF 2 CREEL MACHINES, WHICH FEED YARN INTO KNITTING MACHINES. - Prattville Manufacturing Company, Number One, 242 South Court Street, Prattville, Autauga County, AL

Simultaneous analysis of perfluoroalkyl and polyfluoroalkyl substances including ultrashort-chain C2 and C3 compounds in rain and river water samples by ultra performance convergence chromatography.

PubMed

Yeung, Leo W Y; Stadey, Christopher; Mabury, Scott A

2017-11-03

An analytical method using ultra performance convergence chromatography (UPC 2 ) coupled to a tandem mass spectrometer operated in negative electrospray mode was developed to measure perfluoroalkyl and polyfluoroalkyl substances (PFASs) including the ultrashort-chain PFASs (C2-C3). Compared to the existing liquid chromatography tandem mass spectrometry method using an ion exchange column, the new method has a lower detection limit (0.4pg trifluoroacetate (TFA) on-column), narrower peak width (3-6s), and a shorter run time (8min). Using the same method, different classes of PFASs (e.g., perfluoroalkyl sulfonates (PFSAs) and perfluorinated carboxylates (PFCAs), perfluorinated phosphonates (PFPAs) and phosphinates (PFPiAs), polyfluoroalkyl phosphate diesters (diPAPs)) can be measured in a single analysis. Rain (n=2) and river water (n=2) samples collected in Toronto, ON, were used for method validation and application. Results showed that short-chain PFAS (C2-C7 PFCAs and C4 PFSA) contributed to over 80% of the detectable PFASs in rain samples and the C2-C3 PFASs alone accounted for over 40% of the total. Reports on environmental levels of these ultrashort-chain PFASs are relatively scarce. Relatively large contribution of these ultrashort-chain PFASs to the total PFASs indicate the need to include the measurement of short-chain PFASs, especially C2 and C3 PFASs, in environmental monitoring. The sources of TFA and other short-chain PFASs in the environment are not entirely clear. The newly developed analytical method may help further investigation on the sources and the environmental levels of these ultrashort-chain PFASs. Copyright © 2017 Elsevier B.V. All rights reserved.

Heat input and accumulation for ultrashort pulse processing with high average power

NASA Astrophysics Data System (ADS)

Finger, Johannes; Bornschlegel, Benedikt; Reininghaus, Martin; Dohrn, Andreas; Nießen, Markus; Gillner, Arnold; Poprawe, Reinhart

2018-05-01

Materials processing using ultrashort pulsed laser radiation with pulse durations <10 ps is known to enable very precise processing with negligible thermal load. However, even for the application of picosecond and femtosecond laser radiation, not the full amount of the absorbed energy is converted into ablation products and a distinct fraction of the absorbed energy remains as residual heat in the processed workpiece. For low average power and power densities, this heat is usually not relevant for the processing results and dissipates into the workpiece. In contrast, when higher average powers and repetition rates are applied to increase the throughput and upscale ultrashort pulse processing, this heat input becomes relevant and significantly affects the achieved processing results. In this paper, we outline the relevance of heat input for ultrashort pulse processing, starting with the heat input of a single ultrashort laser pulse. Heat accumulation during ultrashort pulse processing with high repetition rate is discussed as well as heat accumulation for materials processing using pulse bursts. In addition, the relevance of heat accumulation with multiple scanning passes and processing with multiple laser spots is shown.

Wear-reducing Surface Functionalization of Implant Materials Using Ultrashort Laser Pulses

NASA Astrophysics Data System (ADS)

Oldorf, P.; Peters, R.; Reichel, S.; Schulz, A.-P.; Wendlandt, R.

The aim of the project called "EndoLas" is the development of a reproducible and reliable method for a functionalization of articulating surfaces on hip joint endoprostheses due to a reduction of abrasion and wear by the generation of micro structures using ultrashort laser pulses. On the one hand, the microstructures shall ensure the capture of abraded particles, which cause third-body wear and thereby increase aseptic loosening. On the other hand, the structures shall improve or maintain the tribologically important lubricating film. Thereby, the cavities serve as a reservoir for the body's own synovial fluid. The dry friction, which promotes abrasion and is a part of the mixed friction in the joint, shall therefore be reduced. In experimental setups it was shown, that the abrasive wear can be reduced significantly due to micro-structuring the articulating implant surfaces. To shape the fine and deterministic cavities on the surfaces, an ultra-short pulsed laser, which is integrated in a high-precision, 5-axes micro-machining system, was used. The laser system, based on an Yb:YAG thin-disk regenerative amplifier, has an average output power of 50 W at the fundamental wavelength of 1030 nm, a maximum repetition rate of 400 kHz and a pulse duration of 6 ps. Due to this, a maximum pulse energy of 125 μJ is achievable. Furthermore external second and third harmonic generation enables the usage of wavelengths in the green and violet spectral range.

Near-infrared luminescence of Bi2ZnOB2O6:Nd3+/PMMA composite

NASA Astrophysics Data System (ADS)

Jaroszewski, K.; Głuchowski, P.; Chrunik, M.; Jastrząb, R.; Majchrowski, A.; Kasprowicz, D.

2018-01-01

Near-infrared luminescence of a novel polymer composite system: PMMA doped with Bi2ZnOB2O6:Nd3+ microparticles, is reported for the first time. Luminescence properties of Bi2ZnOB2O6:Nd3+/PMMA were analyzed on the basis on excitation and emission spectra as well as fluorescence decay profiles. Excitation spectra monitored at 1062 nm (4F3/2 → 4I11/2) indicate numerous bands related to the optical transition of Nd3+ ions: from the 4I9/2 ground state to the 4D3/2, 2P1/2, 2K15/2, 4G7/2 + 4G9/2, 2K13/2, 4G5/2 + 2G7/2, 2H11/2, 4F9/2, 4F7/2 + 4S3/2, 4F5/2 + 2H9/2, 4F3/2 excited states. Many of them may be utilized to excite near-infrared emission of Nd3+ ions. In particular, distinctive Nd3+ emissions of the 4F3/2 → 4I9/2 and 4F3/2 → 4I11/2 transitions were detected, under excitation at 514 nm. The fluorescence decay profiles monitored at 1062 nm, excited at 514 nm, show relatively long emission lifetime of the 4F3/2 → 4I11/2 transition equal to 85 μs. Raman spectroscopy was used to determine vibrational properties and homogeneity of Bi2ZnOB2O6:Nd3+/PMMA composites. The obtained results suggest that Bi2ZnOB2O6:Nd3+/PMMA composite may be applied as an effective source of near-infrared emission in a new integrated optoelectronic devices.

Modeling ultrashort electromagnetic pulses with a generalized Kadomtsev-Petviashvili equation

NASA Astrophysics Data System (ADS)

Hofstrand, A.; Moloney, J. V.

2018-03-01

In this paper we derive a properly scaled model for the nonlinear propagation of intense, ultrashort, mid-infrared electromagnetic pulses (10-100 femtoseconds) through an arbitrary dispersive medium. The derivation results in a generalized Kadomtsev-Petviashvili (gKP) equation. In contrast to envelope-based models such as the Nonlinear Schrödinger (NLS) equation, the gKP equation describes the dynamics of the field's actual carrier wave. It is important to resolve these dynamics when modeling ultrashort pulses. We proceed by giving an original proof of sufficient conditions on the initial pulse for a singularity to form in the field after a finite propagation distance. The model is then numerically simulated in 2D using a spectral-solver with initial data and physical parameters highlighting our theoretical results.

Monolithic hybrid optics for focusing ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Fuchs, U.

2014-03-01

Almost any application of ultrashort laser pulses involves focusing them in order to reach high intensities and/or small spot sizes as needed for micro-machining or Femto-LASIK. Hence, it is indispensable to be able to understand pulse front distortion caused by real world optics. Focusing causes pulse front distortion due to aberrations, dispersion and diffraction. Thus, the spatio-temporal profile of ultrashort laser is altered, which increases automatically the pulse duration and the focusing spot. Consequently, the main advantage of having ultrashort laser pulses - pulse durations way below 100 fs - can be lost in that one last step of the experimental set-up by focusing them unfavorable. Since compensating for dispersion, aberration and diffraction effects is quite complicated and not always possible, we pursue a different approach. We present a specially designed monolithic hybrid optics comprising refraction and diffraction effects for tight spatial and temporal focusing of ultrashort laser pulses. Both aims can be put into practice by having a high numerical aperture (NA = 0.35) and low internal dispersion at the same time. The focusing properties are very promising, due to a design, which provides diffraction limited focusing for 100 nm bandwidth at 780 nm center wavelength. Thus, pulses with durations as short as 10 fs can be focused without pulse front distortion. The outstanding performance of this optics is shown in theory and experimentally. Above that, such focusing optics are easily adapted to their special purpose - changing the center wavelength, achromatic bandwidth or even correcting for focusing into material is possible.

Post-filament self-trapping of ultrashort laser pulses.

PubMed

Mitrofanov, A V; Voronin, A A; Sidorov-Biryukov, D A; Andriukaitis, G; Flöry, T; Pugžlys, A; Fedotov, A B; Mikhailova, J M; Panchenko, V Ya; Baltuška, A; Zheltikov, A M

2014-08-15

Laser filamentation is understood to be self-channeling of intense ultrashort laser pulses achieved when the self-focusing because of the Kerr nonlinearity is balanced by ionization-induced defocusing. Here, we show that, right behind the ionized region of a laser filament, ultrashort laser pulses can couple into a much longer light channel, where a stable self-guiding spatial mode is sustained by the saturable self-focusing nonlinearity. In the limiting regime of negligibly low ionization, this post-filamentation beam dynamics converges to a large-scale beam self-trapping scenario known since the pioneering work on saturable self-focusing nonlinearities.

Generation and measurement of velocity bunched ultrashort bunch of pC charge

NASA Astrophysics Data System (ADS)

Lu, X. H.; Tang, C. X.; Li, R. K.; To, H.; Andonian, G.; Musumeci, P.

2015-03-01

In this paper, we discuss the velocity compression in a short rf linac of an electron bunch from a rf photoinjector operated in the blowout regime. Particle tracking simulations shows that with a beam charge of 2 pC an ultrashort bunch duration of 16 fs can be obtained at a tight longitudinal focus downstream of the linac. A simplified coherent transition radiation (CTR) spectrum method is developed to enable the measurement of ultrashort (sub-50 fs) bunches at low bunch energy (5 MeV) and low bunch charges (<10 pC ). In this method, the ratio of the radiation energy selected by two narrow bandwidth filters is used to estimate the bunch length. The contribution to the coherent form factor of the large transverse size of the bunch suppresses the radiation signal significantly and is included in the analysis. The experiment was performed at the UCLA Pegasus photoinjector laboratory. The measurement results show bunches of sub-40 fs with 2 pC of charge well consistent with the simulation using actual experimental conditions. These results open the way to the generation of ultrashort bunches with time-duration below 10 fs once some of the limitations of the setup (rf phase jitter, amplitude instability and low field in the gun limited by breakdown) are corrected.

2nd & 3rd Generation Vehicle Subsystems

NASA Technical Reports Server (NTRS)

2000-01-01

This paper contains viewgraph presentation on the "2nd & 3rd Generation Vehicle Subsystems" project. The objective behind this project is to design, develop and test advanced avionics, power systems, power control and distribution components and subsystems for insertion into a highly reliable and low-cost system for a Reusable Launch Vehicles (RLV). The project is divided into two sections: 3rd Generation Vehicle Subsystems and 2nd Generation Vehicle Subsystems. The following topics are discussed under the first section, 3rd Generation Vehicle Subsystems: supporting the NASA RLV program; high-performance guidance & control adaptation for future RLVs; Evolvable Hardware (EHW) for 3rd generation avionics description; Scaleable, Fault-tolerant Intelligent Network or X(trans)ducers (SFINIX); advance electric actuation devices and subsystem technology; hybrid power sources and regeneration technology for electric actuators; and intelligent internal thermal control. Topics discussed in the 2nd Generation Vehicle Subsystems program include: design, development and test of a robust, low-maintenance avionics with no active cooling requirements and autonomous rendezvous and docking systems; design and development of a low maintenance, high reliability, intelligent power systems (fuel cells and battery); and design of a low cost, low maintenance high horsepower actuation systems (actuators).

Tuning the frequency of ultrashort laser pulses by a cross-phase-modulation-induced shift in a photonic crystal fiber.

PubMed

Konorov, S O; Akimov, D A; Zheltikov, A M; Ivanov, A A; Alfimov, M V; Scalora, M

2005-06-15

Femtosecond pulses of fundamental Cr:forsterite laser radiation are used as a pump field to tune the frequency of copropagating second-harmonic pulses of the same laser through cross-phase modulation in a photonic crystal fiber. Sub-100-kW femtosecond pump pulses coupled into a photonic crystal fiber with an appropriate dispersion profile can shift the central frequency of the probe field by more than 100 nm, suggesting a convenient way to control propagation and spectral transformations of ultrashort laser pulses.

Nd3+, Y3+-codoped SrF2 laser ceramics

NASA Astrophysics Data System (ADS)

Li, Weiwei; Mei, Bingchu; Song, Jinghong

2015-09-01

0.15 at.% Nd3+, 5 at.% Y3+-codoped SrF2 laser ceramic based on single crystal was prepared by extensive plastic deformation. Microstructure, optical and laser properties of the Nd3+, Y3+:SrF2 ceramic were investigated. The lasing of Nd3+, Y3+-codoped SrF2 ceramics with diode pumping have been observed and true CW laser operation around 1057 nm and 1050 nm was obtained with a slope efficiency of 31.9%. In particular, the fracture toughness of the ceramic is 0.98 MPa m1/2, which is approximately two times higher than that of single crystal.

Synthesis and Characterization of Nd(3+)-Doped CaF2 Nanoparticles.

PubMed

Yuan, Dan; Li, Weiwei; Mei, Bingchu; Song, Jinghong

2015-12-01

The Ca(1-x)F(2+x):Nd(x) nanoparticles were synthesized by chemical direct precipitation method. X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Image analyzer, absorption spectrum and transmittance were taken to characterization the phases, morphologies, sizes, size distribution and optical properties of the samples. The results indicate that the Ca(1-x)F(2+x):Nd(x) samples can be rationally modified in size and morphology by altering the Nd3+ ions doping concentration. With increasing concentration of Nd3+ ions, the particle size decreased from 24 to 14 nm, the intensity of the diffraction peaks decreased, the Ca(1-x)F(2+x):Nd(x) particles aggregated ion of the formed clusters which should have an effect on both speed and orientation of the particles growth. The transmittance of ceramics with a thickness of 2 mm showed that the transmittance can reach 90% when the doping concentration was 5%, which should be profitable for LD pumping.

Progress on the Design of a Perpendicularly Biased 2nd Harmonic Cavity for the Fermilab Booster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madrak, R. L.; Dey, J. E.; Duel, K. L.

2016-10-01

perpendicularly biased 2nd harmonic cavity is being designed and built for the Fermilab Booster. Its purpose is to flatten the bucket at injection and thus change the longitudinal beam distribution to decrease space charge effects. It can also help at extraction. The cavity frequency range is 76 – 106 MHz. The power amplifier will be built using the Y567B tetrode, which is also used for the fundamental mode cavities in the Fermilab Booster. We discuss recent progress on the cavity, the biasing solenoid design and plans for testing the tuner's garnet material

Black-hole evaporation and ultrashort distances

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobson, T.

1991-09-15

The role played by ultrahigh frequencies of ultrashort distances in the usual derivations of the Hawking effect is discussed and criticized. The question would a blackhole radiate if there were a Planck scale cutoff in the rest frame of the hole '' is posed. Guidance is sought from Unruh's fluid-flow analogue of black-hole radiation, by taking into account the atomic nature of the fluid. Two arguments for black-hole radiation are given which assume a Planck length cutoff. One involves the response of static accelerated detectors outside the horizon, and the other involves conservation of the expectation value of the stressmore » tensor. Neither argument is conclusive, but they do strongly suggest that, in spite of reasonable doubt about the usual derivations of black-hole radiation, a safe'' derivation which avoids our ignorance of ultrashort-distance physics can likely be formulated. Remaining open questions are discussed.« less

Intrinsic evolution of novel (Nd, MM)2Fe14B-system magnetic flakes

NASA Astrophysics Data System (ADS)

Yu, Xiaoqiang; Zhu, Minggang; Liu, Weiqiang; Li, Yanfeng; Zhang, Jiuxing; Yue, Ming; Li, Wei

2018-01-01

The Nd-substituted (Nd x MM1- x )-Fe-B strip-casting flakes were prepared by induction melting in the vacuum furnace and then subsequently by strip-casting technology. The microstructure and magnetic properties of (Nd x MM1- x )-Fe-B alloys are related to the Nd substitution. 2:14:1 main phases and minor impure phases coexist in the MM-Fe-B flake. For example, La2O3 and CeFe2 impure phases are obviously detected in the x = 0 specimen. As an increase of the Ce concentration is inversely accompanied with the decrease of the Nd content ( x) in (Nd x MM1- x )2Fe14B main phases (0 ≤ x ≤ 1), XRD analysis shows that the overall diffraction peaks of the main phases shift to right domestically because of smaller radius Ce4+. The melting point, spin reorientation phase transition temperature, Curie temperature, magneto-crystalline anisotropy field (at 300 K), and the magnetization ( M 9T) for MM-Fe-B/(Nd0.4MM0.6)-Fe-B/(Nd0.7MM0.3)-Fe-B/Nd-Fe-B strip-casting alloys are 1376.15/1414.15/1439.15/1458.15 K, 74/113/124/135 K, 493.2/538.4/559.7/582.3 K, 48/55.2/64.4/70.1 kOe and 136.5/143.7/151.5/153.7 emu/g, respectively. Due to the varied composition of hard magnetic main phases, M 9T increases gradually with the increase of Nd content ( x). SEM observation and EDX results demonstrate that more Nd and Pr elements aggregate into the 2:14:1 ferromagnetic phase, while less La and Ce elements are prone to the RE-rich region compared with the nominal ratio. As a result, the growth of M 9T becomes extraordinary under maximum external field 9 T, indicating that the (Nd0.7MM0.3)-Fe-B flake may display relatively good magnetic properties and those with higher Nd content have evident effect on magnetization, compositions, and microstructures of hard magnetic main phases. Therefore, practical application of (Nd x MM1- x )-Fe-B-sintered magnets will be very prospective.

The choice: Welding with CO2 or Nd:YAG lasers

NASA Astrophysics Data System (ADS)

Leong, Keng H.

The recent commercial availability of multi-kilowatt Nd:YAG lasers has opened new avenues for rapid laser processing as well as intensified the competition (cost effectiveness) between CO2 and Nd:YAG laser systems. Vendors offering Nd:YAG laser systems may claim lower operating costs (than CO2) and fiberoptic beam delivery flexibility while CO2 systems vendors may emphasize lower capital cost and well established processing requirements and experience. The capital and operating costs of a laser system are impacted by demand and supply economics and technological advances. Frequently the total cost of a workcell using a laser for processing has to be considered rather than the laser system alone. Consequently it is not very practical to approach the selection of a laser system based on its capital cost and estimated operating cost only. This presentation describes a more pragmatic approach to aid the user in the selection of the optimal multi-kilowatt laser system for a particular processing requirement with emphasis on welding. CO2 laser systems are well established on the factory floor. Consequently, emphasis is given to the comparative application of Nd:YAG lasers, process requirements and performance. Requirements for the laser welding of different metals are examined in the context of hardware (laser system and beam delivery) selection and examples of welding speeds that can be achieved using CO2 and Nd:YAG lasers are examined.

Ultrashort Carbon Nanotubes That Fluoresce Brightly in the Near-Infrared.

PubMed

Danné, Noémie; Kim, Mijin; Godin, Antoine G; Kwon, Hyejin; Gao, Zhenghong; Wu, Xiaojian; Hartmann, Nicolai F; Doorn, Stephen K; Lounis, Brahim; Wang, YuHuang; Cognet, Laurent

2018-06-14

The intrinsic near-infrared photoluminescence observed in long single-walled carbon nanotubes is known to be quenched in ultrashort nanotubes due to their tiny size as compared to the exciton diffusion length in these materials (>100 nm). Here, we show that intense photoluminescence can be created in ultrashort nanotubes (∼40 nm length) upon incorporation of exciton-trapping sp 3 defect sites. Using super-resolution photoluminescence imaging at <25 nm resolution, we directly show the preferential localization of excitons at the nanotube ends, which separate by less than 40 nm and behave as independent emitters. This unexpected observation opens the possibility to synthesize fluorescent ultrashort nanotubes-a goal that has been long thought impossible-for bioimaging applications, where bright near-infrared photoluminescence and small size are highly desirable, and for quantum information science, where high quality and well-controlled near-infrared single photon emitters are needed.

An evolutionary switch in ND2 enables Src kinase regulation of NMDA receptors

NASA Astrophysics Data System (ADS)

Scanlon, David P.; Bah, Alaji; Krzeminski, Mickaël; Zhang, Wenbo; Leduc-Pessah, Heather L.; Dong, Yi Na; Forman-Kay, Julie D.; Salter, Michael W.

2017-05-01

The non-receptor tyrosine kinase Src is a key signalling hub for upregulating the function of N-methyl D-aspartate receptors (NMDARs). Src is anchored within the NMDAR complex via NADH dehydrogenase subunit 2 (ND2), a mitochondrially encoded adaptor protein. The interacting regions between Src and ND2 have been broadly identified, but the interaction between ND2 and the NMDAR has remained elusive. Here we generate a homology model of ND2 and dock it onto the NMDAR via the transmembrane domain of GluN1. This interaction is enabled by the evolutionary loss of three helices in bilaterian ND2 proteins compared to their ancestral homologues. We experimentally validate our model and demonstrate that blocking this interaction with an ND2 fragment identified in our experimental studies prevents Src-mediated upregulation of NMDAR currents in neurons. Our findings establish the mode of interaction between an NMDAR accessory protein with one of the core subunits of the receptor.

Distortion of ultrashort pulses caused by aberrations

NASA Astrophysics Data System (ADS)

Horváth, Z. L.; Kovács, A. P.; Bor, Zs.

The effect of the primary wave aberrations (spherical aberration, astigmatism and coma) on ultrashort pulses is studied by the Nijboer-Zernike theory. The results of the geometrical and the wave optical treatments are compared.

Acousto-optic replication of ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Yushkov, Konstantin B.; Molchanov, Vladimir Ya.; Ovchinnikov, Andrey V.; Chefonov, Oleg V.

2017-10-01

Precisely controlled sequences of ultrashort laser pulses are required in various scientific and engineering applications. We developed a phase-only acousto-optic pulse shaping method for replication of ultrashort laser pulses in a TW laser system. A sequence of several Fourier-transform-limited pulses is generated from a single femtosecond laser pulse by means of applying a piecewise linear phase modulation over the whole emission spectrum. Analysis demonstrates that the main factor which limits maximum delay between the pulse replicas is spectral resolution of the acousto-optic dispersive delay line used for pulse shaping. In experiments with a Cr:forsterite laser system, we obtained delays from 0.3 to 3.5 ps between two replicas of 190 fs transform-limited pulses at the central wavelength of laser emission, 1230 nm.

Generation and measurement of velocity bunched ultrashort bunch of pC charge

DOE PAGES

Lu, X.  H.; Tang, C.  X.; Li, R.  K.; ...

2015-03-01

In this paper, we discuss the velocity compression in a short rf linac of an electron bunch from a rf photoinjector operated in the blowout regime. Particle tracking simulations shows that with a beam charge of 2 pC an ultrashort bunch duration of 16 fs can be obtained at a tight longitudinal focus downstream of the linac. A simplified coherent transition radiation (CTR) spectrum method is developed to enable the measurement of ultrashort (sub-50 fs) bunches at low bunch energy (5 MeV) and low bunch charges (<10 pC). In this method, the ratio of the radiation energy selected by twomore » narrow bandwidth filters is used to estimate the bunch length. The contribution to the coherent form factor of the large transverse size of the bunch suppresses the radiation signal significantly and is included in the analysis. The experiment was performed at the UCLA Pegasus photoinjector laboratory. The measurement results show bunches of sub-40 fs with 2 pC of charge well consistent with the simulation using actual experimental conditions. These results open the way to the generation of ultrashort bunches with time-duration below 10 fs once some of the limitations of the setup (rf phase jitter, amplitude instability and low field in the gun limited by breakdown) are corrected.« less

High Precision 142Nd/144Nd and 143Nd/144Nd Isotope Ratio Measurements in Rock Samples

NASA Astrophysics Data System (ADS)

Ali, A.; Srinivasan, G.

2009-05-01

The long-lived 147Sm-143Nd system with a half-life (T1/2) of 106 Gyr is generally used for geochronology. The short-lived 146Sm-142Nd system (T1/2= 103 Myr) is used as a geological tracer to track early (˜500 Ma) silicate differentiation [1] events in different planetary bodies. The isotope composition measurements by thermal ionization mass spectrometry (TIMS) require purification of Nd using chemical separation methods. This is important as an impure sample will give both a very poor ion yield and cause beam instability in the mass spectrometer, potentially resulting in a poor analysis [2]. The separation of Nd for 143Nd isotope measurement is, fairly straightforward because there is no isobaric interference of any other REE. While 142Nd isotope analysis needs chemically separated Nd fraction to be ˜100% Ce-free as latter is composed of a substantial amount of 142Ce isotope. A 4-steps technique, modified from Caro et al., [3], for the separation of Nd is established at the Cosmochemistry Laboratory of University of Toronto, Canada and applied to the measurement of Nd isotope ratios in geological reference sample BCR-2 (USGS, Columbia River basalt) using TIMS. Results of the isotopic ratios obtained for BCR-2 are in good agreement with published values [e.g., 4]. Analytical work on the samples discovered as the oldest rocks on Earth [5] from Nuvvuagittuq greenstone belt in Québec, Canada and various meteorites is in progress. An account of the procedures involved is briefly described here. All working solutions and acids were prepared using >18.2 MΩ.cm-1 H2O from a Milli-Q water system. Experiments were performed under Class 100 clean work bench with acid-cleaned apparatus and plastic-ware. The whole rock powders were weighed (20-30 mg) and dissolved in a mixture of HF and HNO3 using PFA vials and heated at 110°C. Further decomposition was done in Teflon bomb in the oven at 205°C. Later on contents of the Teflon bomb were transferred to vials and fluorides

High-brightness-solar-pumped Nd:YAG laser design

NASA Astrophysics Data System (ADS)

Lando, Mordechai; Jenkins, David G.; Bernstein, Hana; O'Gallagher, Joseph J.; Winston, Roland; Lewandowski, Allan

1995-06-01

We have designed a Nd:YAG laser to be pumped by the High-Flux Solar Furnace (HFSF) at the National Renewable Energy Laboratory. Based on the unique features of the HFSF, the design objectives are high brightness and superior efficiency in primary mirror area utilization. The HFSF has a primary mirror of 11.5 m2 and a 1.85 f-number. With such a high f-number, the target is set off-axis and does not block incoming solar flux. Moreover, large f-number enables concentration which approaches the theoretical limit, and a two- dimensional non-imaging concentrator deposits the solar flux onto the internal part of a 10 mm diameter laser rod. For high brightness, we plan a wide low-loss fundamental mode and a laser rod aperture that suppresses high order modes. To get a fundamental mode, of up to a 2.5 mm waist, we have designed a convex-concave resonator, following well-known g1g2 equals 0.5 design for resonators with internal beam focusing. We have used the edge ray principle to design the concentrator, and ray traced the deposited power inside the laser rod. A 1.3% Nd doping level supports a maximal power deposition inside a 5 mm diameter.

All-fiber mode-locked erbium-doped ring laser based on a highly-nonlinear resonator with a low-noise ultrashort pulse generation

NASA Astrophysics Data System (ADS)

Kudelin, Igor S.; Dvoretskiy, Dmitriy A.; Sazonkin, Stanislav G.; Orekhov, Ilya O.; Pnev, Alexey B.; Karasik, Valeriy E.; Denisov, Lev K.

2018-04-01

Ultrashort pulse (USP) fiber lasers have found applications in such various fields as frequency metrology and spectroscopy, telecommunication systems, etc. For the last decade, mode-locking (ML) fiber lasers have been under carefully investigations for scientific, medical and industrial applications. Also, USP fiber sources can be treated as an ideal platform to expand future applications due to the complex ML nonlinear dynamics with a presence of high value of group velocity dispersion (GVD) and the third order dispersion in the resonator. For more reliable and robust launching of passive mode-locking based on a nonlinear polarization evolution, we used a highly nonlinear germanosilicate fiber (with germanium oxides concentration in the core 50 mol. %) inside the cavity and we have obtained ultrashort stretched pulses with a high peak power and energy. In this work relative intensity noise and frequency repetition stability is improved by applying isolator-polarizer (ISO-PM) with increased extinction ratio Pext and by compensation of intracavity group-velocity dispersion from the value β2 - 0.021 ps2 to - 0.0053 ps2 at 1550 nm. As a result, we have obtained the low-noise stretched pulse generation with duration 180 fs at a repetition rate 11.3 MHz (with signal-tonoise ratio at fundamental frequency 59 dB) with Allan deviation of a pulse repetition frequency for 1 s interval 5,7 * 10-9 and a relative intensity noise < -101 dBc / Hz.

Phase stabilization of multidimensional amplification architectures for ultrashort pulses

NASA Astrophysics Data System (ADS)

Müller, M.; Kienel, M.; Klenke, A.; Eidam, T.; Limpert, J.; Tünnermann, A.

2015-03-01

The active phase stabilization of spatially and temporally combined ultrashort pulses is investigated theoretically and experimentally. Particularly, considering a combining scheme applying 2 amplifier channels and 4 divided-pulse replicas a bistable behavior is observed. The reason is mutual influence of the optical error signals that is intrinsic to temporal polarization beam combining. A successful mitigation strategy is proposed and is analyzed theoretically and experimentally.

Quantum origins of moment fragmentation in Nd2Zr2O7

NASA Astrophysics Data System (ADS)

Benton, Owen

2016-09-01

Spin-liquid states are often described as the antithesis of magnetic order. Recently, however, it has been proposed that in certain frustrated magnets the magnetic degrees of freedom may "fragment" in such a way as to give rise to a coexistence of spin liquid and ordered phases. Recent neutron-scattering results [S. Petit, E. Lhotel, B. Canals, M. Ciomaga Hatnean, J. Ollivier, H. Muttka, E. Ressouche, A. R. Wildes, M. R. Lees, and G. Balakrishnan, Nat. Phys. 12, 746 (2016), 10.1038/nphys3710] suggest that this scenario may be realized in the pyrochlore magnet Nd2Zr2O7 . These observations show the characteristic pinch-point features of a Coulombic spin liquid occurring alongside the Bragg peaks of an "all-in-all-out" ordered state. Here we explain the quantum origins of this apparent magnetic moment fragmentation, within the framework of a quantum model of nearest-neighbor exchange, appropriate to Nd2Zr2O7 . This model is able to capture both the ground-state order and the pinch points observed at finite energy. The observed fragmentation arises due to the combination of the unusual symmetry properties of the Nd3 + ionic wave functions and the structure of equations of motion of the magnetic degrees of freedom. The results of our analysis suggest that Nd2Zr2O7 is proximate to a U (1 ) spin-liquid phase and is a promising candidate for the observation of a Higgs transition in a magnetic system.

Effects of trace elements on the crystal field parameters of Nd ions at the surface of Nd{sub 2}Fe{sub 14}B grains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Toga, Yuta; Suzuki, Tsuneaki; Sakuma, Akimasa, E-mail: sakuma@solid.apph.tohoku.ac.jp

2015-06-14

Using first-principles calculations, we investigate the positional dependence of trace elements such as O and Cu on the crystal field parameter A{sub 2}{sup 0}, proportional to the magnetic anisotropy constant K{sub u} of Nd ions placed at the surface of Nd{sub 2}Fe{sub 14}B grains. The results suggest the possibility that the A{sub 2}{sup 0} parameter of Nd ions at the (001) surface of Nd{sub 2}Fe{sub 14}B grains exhibits a negative value when the O or Cu atom is located near the surface, closer than its equilibrium position. At the (110) surface, however, O atoms located at the equilibrium position providemore » a negative A{sub 2}{sup 0}, while for Cu additions A{sub 2}{sup 0} remains positive regardless of Cu's position. Thus, Cu atoms are expected to maintain a positive local K{sub u} of surface Nd ions more frequently than O atoms when they approach the grain surfaces in the Nd-Fe-B grains.« less

Pathogen Reduction in Human Plasma Using an Ultrashort Pulsed Laser

PubMed Central

Tsen, Shaw-Wei D.; Kingsley, David H.; Kibler, Karen; Jacobs, Bert; Sizemore, Sara; Vaiana, Sara M.; Anderson, Jeanne; Tsen, Kong-Thon; Achilefu, Samuel

2014-01-01

Pathogen reduction is a viable approach to ensure the continued safety of the blood supply against emerging pathogens. However, the currently licensed pathogen reduction techniques are ineffective against non-enveloped viruses such as hepatitis A virus, and they introduce chemicals with concerns of side effects which prevent their widespread use. In this report, we demonstrate the inactivation of both enveloped and non-enveloped viruses in human plasma using a novel chemical-free method, a visible ultrashort pulsed laser. We found that laser treatment resulted in 2-log, 1-log, and 3-log reductions in human immunodeficiency virus, hepatitis A virus, and murine cytomegalovirus in human plasma, respectively. Laser-treated plasma showed ≥70% retention for most coagulation factors tested. Furthermore, laser treatment did not alter the structure of a model coagulation factor, fibrinogen. Ultrashort pulsed lasers are a promising new method for chemical-free, broad-spectrum pathogen reduction in human plasma. PMID:25372037

Comparison of magnetic and thermoelectric properties of (Nd,Ca)BaCo2O5.5 and (Nd,Ca)CoO3

NASA Astrophysics Data System (ADS)

Kolesnik, S.; Dabrowski, B.; Chmaissem, O.; Wojciechowski, K.; Świerczek, K.

2012-04-01

Magnetic and thermoelectric properties of Nd1-xCaxBaCo2O5.5 and Nd1-xCaxCoO3 have been studied. Ca doping in Nd1-xCaxBaCo2O5.5 (x ≤ 0.2) preserves the metal to insulator transition (MIT) at 340-360 K. While the antiferromagnetic state disappears upon doping, the Curie temperature is increasing and becomes close to MIT for x > 0.12. The magnetic susceptibility of Nd1-xCaxCoO3 is paramagnetic for x up to 0.2, similar to the parent compound, with some indication of cluster-glass-like behavior at temperatures below 30 K. The increasing effective paramagnetic moments with doping suggest a low spin state of Co3+ and a high spin state of Co4+. Maximum observed ZT reaches a value close to 0.2 for x = 0.15 at 800 K, which is one of the highest values for perovskite cobaltites.

Tunability of morphological properties of Nd-doped TiO2 thin films

NASA Astrophysics Data System (ADS)

Rehan, Imran; Sultana, Sabiha; Khan, Nauman; Qamar, Zahid; Rehan, Kamran

2016-11-01

In this work, an endeavor is made toward structural assessment and morphological variation of titanium dioxide (TiO2) thin films when doped with neodymium (Nd). The electron beam deposition technique was employed to fabricate Nd-based TiO2 thin films on n-Type Si substrates. Nd concentration was varied from 0.0 to 2.0 atomic percent (at.%) under identical growth environments. The films were deposited in an oxygen-deficient environment to cause the growth of rutile phases. Energy dispersive x-ray spectroscopy confirmed the presence and variation of Nd dopant in TiO2. X-ray diffraction analysis showed the transformation of amorphous structures of the as-grown samples to anatase polycrystalline after annealing at 500 °C, while atomic force microscopy exposed linearity in grain density in as-grown samples with doping until 1 at.%. Raman spectrums of as-grown and annealed samples revealed the growth of the anatase phase in the annealed samples. Based on these results it can be proposed that Nd doping has pronounced effects on the structural characteristics of TiO2 thin films.

Controlling Plasma Channels through Ultrashort Laser Pulse Filamentation

NASA Astrophysics Data System (ADS)

Ionin, Andrey; Seleznev, Leonid; Sunchugasheva, Elena

2013-09-01

A review of studies fulfilled at the Lebedev Institute in collaboration with the Moscow State University and Institute of Atmospheric Optics in Tomsk on influence of various characteristics of ultrashort laser pulse on plasma channels formed under its filamentation is presented. Filamentation of high-power laser pulses with wavefront controlled by a deformable mirror, with cross-sections spatially formed by various diaphragms and with different wavelengths was experimentally and numerically studied. An application of plasma channels formed due to filamentation of ultrashort laser pulse including a train of such pulses for triggering and guiding long electric discharges is discussed. The research was supported by RFBR Grants 11-02-12061-ofi-m and 11-02-01100, and EOARD Grant 097007 through ISTC Project 4073 P

NIR emitting K2SrCl4:Eu2+, Nd3+ phosphor as a spectral converter for CIGS solar cell

NASA Astrophysics Data System (ADS)

Tawalare, P. K.; Bhatkar, V. B.; Omanwar, S. K.; Moharil, S. V.

2018-05-01

Intense near-infrared emitting phosphor K2SrCl4:Eu2+,Nd3+ with various concentrations of Nd3+ were synthesized. These are characterized with X-ray diffraction, reflectance, photoluminescence emission and photoluminescence excitation spectroscopy, PL lifetime measurements. The emission can be excited by a broad band in near ultra violet region as a consequence of Eu2+→Nd3+ energy transfer. The efficiency of Eu2+→Nd3+ energy transfer is as high as 95%. Fluorescence decay curves for Eu2+ doped samples are almost exponential and described by τ = 500 ns. Eu2+ lifetimes are shortened after Nd3+ doping. Near infrared Emission intensity is limited by Nd3+→Nd3+ energy transfer and the consequent concentration quenching. Nd3+ emission matches well with the spectral response of CIGS and CIS solar cells. Absorption of near ultra violet radiations followed by conversion to near infrared indicates the potential application in solar photovoltaics.

T2* measurements of 3-T MRI with ultrashort TEs: capabilities of pulmonary function assessment and clinical stage classification in smokers.

PubMed

Ohno, Yoshiharu; Koyama, Hisanobu; Yoshikawa, Takeshi; Matsumoto, Keiko; Takahashi, Masaya; Van Cauteren, Marc; Sugimura, Kazuro

2011-08-01

The purpose of this study was to determine the usefulness of MRI with ultrashort TEs on a 3-T system and of thin-section MDCT for pulmonary function assessment and clinical stage classification of chronic obstructive pulmonary disease (COPD) in smokers. Forty smokers (24 men and 16 women; mean age ± SD, 68.0 ± 9.3 years) underwent MRI with ultrashort TEs and thin-section MDCT. Pulmonary function testing was also performed to determine the following: the ratio of forced expiratory volume in 1 second to forced vital capacity (percentage predicted) (FEV(1/)FVC%), percentage predicted forced expiratory volume in 1 second (%FEV(1)), and percentage predicted diffusing capacity of lung for carbon monoxide corrected for alveolar volume (%DLCO/V(A)). All subjects were classified into one of four groups as follows: smokers without COPD, with mild COPD, with moderate COPD, and with severe or very severe COPD. T2(*) maps were expressed using proprietary software. Regional T2(*) values were determined by region of interest measurements and were averaged to determine a mean T2(*) value for each subject. CT-based functional lung volume and the ratio of the wall area to the total airway area were also determined. All indexes were statistically correlated with pulmonary function parameters. Then, all indexes were compared among all groups by means of Tukey's honest significance test. All indexes had significant correlation with FEV(1)/FVC%, %FEV(1), and % DLCO/V(A) (p < 0.05). All indexes except WA% of smokers without COPD and smokers with mild COPD differed significantly from those of smokers with moderate COPD and smokers with severe or very severe COPD (p < 0.05). Moreover, the mean T2(*) value of the moderate COPD group was significantly different from that of the severe or very severe COPD group (p < 0.05). MRI with ultrashort TEs is potentially as useful as quantitatively assessed MDCT for pulmonary function loss assessment and clinical stage classification of COPD in

Magnetic structure of the ferromagnetic new ternary silicide Nd5CoSi2.

PubMed

Mayer, C; Gaudin, E; Gorsse, S; Porcher, F; André, G; Chevalier, B

2012-04-04

Nd(5)CoSi(2) was obtained from the elements by arc-melting followed by annealing at 883 K. Its investigation by single-crystal x-ray and neutron powder diffraction shows that this ternary silicide crystallizes as Nd(5)Si(3) in a tetragonal structure deriving from the Cr(5)B(3)-type (I4/mcm space group; a = 7.7472(2) and c = 13.5981(5) Å as unit cell parameters). The structural refinements confirm the mixed occupancy on the 8h site between Si and Co atoms, as already observed for Gd(5)CoSi(2). Magnetization and specific heat measurements reveal a ferromagnetic behavior below T(C) = 55 K for Nd(5)CoSi(2). This magnetic ordering is further evidenced by neutron powder diffraction investigation revealing between 1.8 K and T(C) a canted ferromagnetic structure in the direction of the c-axis described by a propagation vector k = (0 0 0). At 1.8 K, the two Nd(3+) ions carry ordered magnetic moments equal respectively to 1.67(7) and 2.37(7) μ(B) for Nd1 and Nd2; these two moments exhibit a canting angle of θ = 4.3(6)°. This magnetic structure presents some similarities with that reported for Nd(5)Si(3). © 2012 IOP Publishing Ltd

Ultra-short pulse generator

DOEpatents

McEwan, Thomas E.

1993-01-01

An inexpensive pulse generating circuit is disclosed that generates ultra-short, 200 picosecond, and high voltage 100 kW, pulses suitable for wideband radar and other wideband applications. The circuit implements a nonlinear transmission line with series inductors and variable capacitors coupled to ground made from reverse biased diodes to sharpen and increase the amplitude of a high-voltage power MOSFET driver input pulse until it causes non-destructive transit time breakdown in a final avalanche shockwave diode, which increases and sharpens the pulse even more.

2Flux growth and characterization of Ce-substituted Nd 2 Fe 14 B single crystals

DOE PAGES

Susner, Michael A.; Conner, Benjamin S.; Saparov, Bayrammurad I.; ...

2016-10-27

Single crystals of (Nd 1-xCe x) 2Fe 14B are grown out of Fe-(Nd,Ce) flux. Chemical and structural analysis of the crystals indicate that (Nd 1-xCe x) 2Fe 14B forms a solid solution until at least x = 0.38 with a Vegard-like variation of the lattice constants with x. Refinements of single crystal neutron diffraction data indicate that Ce has a slight site preference (7:3) for the 4g rare earth site over the 4f site. Magnetization measurements at 300 K show only small decreases with increasing Ce content in saturation magnetization (M s) and anisotropy field (H A), and Curie temperaturemore » (T C). First principles calculations are carried out to understand the effect of Ce substitution on the electronic and magnetic properties. For a multitude of applications, it is expected that the advantage of incorporating lower-cost and more abundant Ce will outweigh the small adverse effects on magnetic properties. In conclusion, Ce-substituted Nd 2Fe 14B is therefore a potential high-performance permanent magnet material with substantially reduced Nd content.« less

ICESat-2 laser Nd:YVO4 amplifier

NASA Astrophysics Data System (ADS)

Sawruk, Nicholas W.; Burns, Patrick M.; Edwards, Ryan E.; Litvinovitch, Viatcheslav; Martin, Nigel; Witt, Greg; Fakhoury, Elias; Iskander, John; Pronko, Mark S.; Troupaki, Elisavet; Bay, Michael M.; He, Charles C.; Wang, Liqin L.; Cavanaugh, John F.; Farrokh, Babak; Salem, Jonathan A.; Baker, Eric

2018-02-01

We report on the cause and corrective actions of three amplifier crystal fractures in the space-qualified laser systems used in NASA Goddard Space Flight Center's (GSFC) Ice, Cloud, and Land Elevation Satellite-2 (ICESat-2). The ICESat-2 lasers each contain three end-pumped Nd:YVOO4 amplifier stages. The crystals are clamped between two gold plated copper heat spreaders with an indium foil thermal interface material, and the crystal fractures occurred after multiple years of storage and over a year of operational run-time. The primary contributors are high compressive loading of the NdYVO4 crystals at the beginning of life, a time dependent crystal stress caused by an intermetallic reaction of the gold plating and indium, and slow crack growth resulting in a reduction in crystal strength over time. An updated crystal mounting scheme was designed, analyzed, fabricated and tested. Thee fracture slab failure analysis, finite-element modeling and corrective actions are presented.

Cardio-pulmonary fitness test by ultra-short heart rate variability.

PubMed

Aslani, Arsalan; Aslani, Amir; Kheirkhah, Jalal; Sobhani, Vahid

2011-10-01

It is known that exercise induces cardio-respiratory autonomic modulation. The aim of this study was to assess the cardio-pulmonary fitness by ultra-short heart rate variability. Study population was divided into 3 groups: Group-1 (n = 40) consisted of military sports man. Group-2 (n = 40) were healthy age-matched sedentary male subjects with normal body mass index [BMI = 19 - 25 kg/m(2)). Group-3 (n = 40) were healthy age-matched obese male subjects [BMI > 29 kg/m(2)). Standard deviation of normal-to-normal QRS intervals (SDNN) was recorded over 15 minutes. Bruce protocol treadmill test was used; and, maximum oxygen consumption (VO(2)max) was calculated. WHEN THE STUDY POPULATION WAS DIVIDED INTO QUARTILES OF SDNN (FIRST QUARTILE: < 60 msec; second quartile: > 60 and < 100 msec; third quartile: > 100 and <140 msec; and fourth quartile: >140 msec), progressive increase was found in VO(2)max; and, SDNN was significantly linked with estimated VO(2)max. In conclusion, the results of this study demonstrate that exercise training improves cardio-respiratory autonomic function (and increases heart rate variability). Improvement in cardio-respiratory autonomic function seems to translate into a lower rate of long term mortality. Ultra-short heart rate variability is a simple cardio-pulmonary fitness test which just requires 15 minutes, and involves no exercise such as in the treadmill or cycle test.

Temperature-dependent spectroscopy and microchip laser operation of Nd:KGd(WO4)2

NASA Astrophysics Data System (ADS)

Loiko, P.; Yoon, S. J.; Serres, J. M.; Mateos, X.; Beecher, S. J.; Birch, R. B.; Savitski, V. G.; Kemp, A. J.; Yumashev, K.; Griebner, U.; Petrov, V.; Aguiló, M.; Díaz, F.; Mackenzie, J. I.

2016-08-01

High-resolution absorption and stimulated-emission cross-section spectra are presented for monoclinic Nd:KGd(WO4)2 (Nd:KGW) laser crystals in the temperature range 77-450 K. At room-temperature, the maximum stimulated emission cross-section is σSE = 21.4 × 10-20 cm2 at 1067.3 nm, for light polarization E || Nm. The lifetime of the 4F3/2 state of Nd3+ in KGW is practically temperature independent at 115 ± 5 μs. Measurement of the energy transfer upconversion parameter for a 3 at.% Nd:KGW crystal proved that this was significantly smaller than for alternative hosts, ∼2.5 × 10-17 cm3/s. When cut along the Ng optical indicatrix axis, the Nd:KGW crystal was configured as a microchip laser, generating ∼4 W of continuous-wave output at 1067 nm with a slope efficiency of 61% under diode-pumping. Using a highly-doped (10 at.%) Nd:KGW crystal, the slope efficiency reached 71% and 74% when pumped with a laser diode and a Ti:Sapphire laser, respectively. The concept of an ultrathin (250 μm) Nd:KGW microchip laser sandwiched between two synthetic diamond heat-spreaders is demonstrated.

Editorial: 2nd Special Issue on behavior change, health, and health disparities.

PubMed

Higgins, Stephen T

2015-11-01

This Special Issue of Preventive Medicine (PM) is the 2nd that we have organized on behavior change, health, and health disparities. This is a topic of fundamental importance to improving population health in the U.S. and other industrialized countries that are trying to more effectively manage chronic health conditions. There is broad scientific consensus that personal behavior patterns such as cigarette smoking, other substance abuse, and physical inactivity/obesity are among the most important modifiable causes of chronic disease and its adverse impacts on population health. As such behavior change needs to be a key component of improving population health. There is also broad agreement that while these problems extend across socioeconomic strata, they are overrepresented among more economically disadvantaged populations and contribute directly to the growing problem of health disparities. Hence, behavior change represents an essential step in curtailing that unsettling problem as well. In this 2nd Special Issue, we devote considerable space to the current U.S. prescription opioid addiction epidemic, a crisis that was not addressed in the prior Special Issue. We also continue to devote attention to the two largest contributors to preventable disease and premature death, cigarette smoking and physical inactivity/obesity as well as risks of co-occurrence of these unhealthy behavior patterns. Across each of these topics we included contributions from highly accomplished policy makers and scientists to acquaint readers with recent accomplishments as well as remaining knowledge gaps and challenges to effectively managing these important chronic health problems. Copyright © 2015 Elsevier Inc. All rights reserved.

Modeling HCV cure after an ultra-short duration of therapy with direct acting agents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goyal, Ashish; Lurie, Yoav; Meissner, Eric G.

In cases of sustained-virological response (SVR or cure) after an ultra-short duration (≤ 27 days) of direct-acting antiviral (DAA)-based therapy, despite HCV being detected at end of treatment (EOT), have been reported. Established HCV mathematical models that predict the treatment duration required to achieve cure do not take into account the possibility that the infectivity of virus produced during treatment might be reduced. The aim of this study was to develop a new mathematical model that considers the fundamental and critical concept that HCV RNA in serum represents both infectious virus (V i) and non-infectious virus (V ni) in ordermore » to explain the observation of cure with ultrashort DAA therapy. Established HCV models were compared to the new mathematical model to retrospectively explain cure in 2 patients who achieved cure after 24 or 27 days of paritaprevir, ombitasvir, dasabuvir, ritonavir and ribavirin or sofosbuvir plus ribavirin, respectively. Fitting established models with measured longitudinal HCV viral loads indicated that in both cases, cure would not have been expected without an additional 3–6 weeks of therapy after the actual EOT. In contrast, the new model fits the observed outcome by considering that in addition to blocking V i and V ni production (ε~0.998), these DAA + ribavirin treatments further enhanced the ratio of V ni to V i, thus increasing the log (V ni/V i) from 1 at pretreatment to 6 by EOT, which led to <1 infectious-virus particle in the extracellular body fluid (i.e., cure) prior to EOT. This new model can explain cure after short duration of DAA + ribavirin therapy by suggesting that a minimum 6-fold increase of log (V ni/V i) results from drug-induced enhancement of the V ni/V i.« less

Modeling HCV cure after an ultra-short duration of therapy with direct acting agents

DOE PAGES

Goyal, Ashish; Lurie, Yoav; Meissner, Eric G.; ...

2017-06-30

In cases of sustained-virological response (SVR or cure) after an ultra-short duration (≤ 27 days) of direct-acting antiviral (DAA)-based therapy, despite HCV being detected at end of treatment (EOT), have been reported. Established HCV mathematical models that predict the treatment duration required to achieve cure do not take into account the possibility that the infectivity of virus produced during treatment might be reduced. The aim of this study was to develop a new mathematical model that considers the fundamental and critical concept that HCV RNA in serum represents both infectious virus (V i) and non-infectious virus (V ni) in ordermore » to explain the observation of cure with ultrashort DAA therapy. Established HCV models were compared to the new mathematical model to retrospectively explain cure in 2 patients who achieved cure after 24 or 27 days of paritaprevir, ombitasvir, dasabuvir, ritonavir and ribavirin or sofosbuvir plus ribavirin, respectively. Fitting established models with measured longitudinal HCV viral loads indicated that in both cases, cure would not have been expected without an additional 3–6 weeks of therapy after the actual EOT. In contrast, the new model fits the observed outcome by considering that in addition to blocking V i and V ni production (ε~0.998), these DAA + ribavirin treatments further enhanced the ratio of V ni to V i, thus increasing the log (V ni/V i) from 1 at pretreatment to 6 by EOT, which led to <1 infectious-virus particle in the extracellular body fluid (i.e., cure) prior to EOT. This new model can explain cure after short duration of DAA + ribavirin therapy by suggesting that a minimum 6-fold increase of log (V ni/V i) results from drug-induced enhancement of the V ni/V i.« less

Progress on the Construction of the Perpendicularly Biased 2nd Harmonic Cavity for the Fermilab Booster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madrak, R.; Dey, J.; Duel, K.

A perpendicularly biased tuneable 2nd harmonic cavity, designed for the Fermilab Booster, is being assembled for testing this summer (2018). The cavity will work at twice the frequency of the fundamental cavities, and will be on only during the injection and transition (or extraction) periods. The main reason for adding this cavity is to improve beam capture and reduce losses as required by Fermilab's Proton Improvement Plan (PIP). After three years optimization and study, the cavity design has now been finalized and all constituent parts have been received. We report on the cavity final design and on the status ofmore » the construction.« less

Ultra-short pulse generator

DOEpatents

McEwan, T.E.

1993-12-28

An inexpensive pulse generating circuit is disclosed that generates ultra-short, 200 picosecond, and high voltage 100 kW, pulses suitable for wideband radar and other wideband applications. The circuit implements a nonlinear transmission line with series inductors and variable capacitors coupled to ground made from reverse biased diodes to sharpen and increase the amplitude of a high-voltage power MOSFET driver input pulse until it causes non-destructive transit time breakdown in a final avalanche shock wave diode, which increases and sharpens the pulse even more. 5 figures.

Mid-infrared beam splitter for ultrashort pulses.

PubMed

Somma, Carmine; Reimann, Klaus; Woerner, Michael; Kiel, Thomas; Busch, Kurt; Braun, Andreas; Matalla, Mathias; Ickert, Karina; Krüger, Olaf

2017-08-01

A design is presented for a beam splitter suitable for ultrashort pulses in the mid-infrared and terahertz spectral range consisting of a structured metal layer on a diamond substrate. Both the theory and experiment show that this beam splitter does not distort the temporal pulse shape.

A neodymium(III)-ammonium complex involving oxalate and carbonate ligands: (NH4)2[Nd2(C2O4)3(CO3)(H2O)].H2O.

PubMed

Trombe, Jean-Christian; Galy, Jean; Enjalbert, Renée

2002-10-01

The title compound, diammonium aqua-mu-carbonato-tri-mu-oxalato-dineodymium(III) hydrate, (NH(4))(2)[Nd(2)(CO(3))(C(2)O(4))(3)(H(2)O)].H(2)O, involving the two ligands oxalate and carbonate, has been prepared hydrothermally as single crystals. The Nd atoms form a tetranuclear unit across the inversion centre at (1/2, 1/2, 1/2). Starting from this tetranuclear unit, the oxalate ligands serve to develop a three-dimensional network. The carbonate group acts as a bis-chelating ligand to two Nd atoms, and is monodentate to a third Nd atom. The oxalate groups are all bis-chelating. The two independent Nd atoms are ninefold coordinated and the coordination polyhedron of these atoms is a distorted monocapped antiprism.

Calculus removal on a root cement surface by ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Kraft, Johan F.; Vestentoft, Kasper; Christensen, Bjarke H.; Løvschall, Henrik; Balling, Peter

2008-01-01

Ultrashort-pulse-laser ablation of dental calculus (tartar) and cement is performed on root surfaces. The investigation shows that the threshold fluence for ablation of calculus is a factor of two to three times smaller than that of a healthy root cement surface. This indicates that ultrashort laser pulses may provide an appropriate tool for selective removal of calculus with minimal damage to the underlying root cement. Future application of an in situ profiling technique allows convenient on-line monitoring of the ablation process.

[Health and environment: the 2nd public health revolution.].

PubMed

Cicolella, André

2010-01-01

As of the mid-19th century, most infectious disease epidemics have been fought and slowed down by taking action on the environment (water, housing, waste) and education. This constitutes the 1st public health revolution paradigm. As we face the current epidemic of chronic diseases and the failure of the dominant biomedical model to stop them, a 2nd public health revolution is needed. The vision for this 2nd public health revolution requires a new paradigm built upon an eco-systemic definition of health and the recognition of the legitimacy for citizen participation based on the precautionary principle.

Generation of UV light by intense ultrashort laser pulses in air

NASA Astrophysics Data System (ADS)

Alexeev, Ilya; Ting, Antonio; Gordon, Daniel; Briscoe, Eldridge; Penano, Joe; Sprangle, Phillip

2004-11-01

The propagation of collimated high-peak-power ultrashort laser pulses in air has attracted considerable attention, which may have a variety of important applications including remote sensing and chemical-biological aerosols standoff detection. Sub-millimeter diameter laser filaments can develop without any focusing optics and instead solely from laser self-focusing and plasma formation in air. These filaments can produce ultraviolet radiations in the form of the 3rd harmonic of the fundamental frequency and also through spectral broadening due to self-phase modulation of the laser pulse. Using femtosecond laser pulses produced by a high power Ti:Sapphire laser (0.8 TW, 50 fs, 800 nm) we observed generation of the third harmonic radiation light in air (centered around 267 nm) by the laser filaments. Characterization of the 3rd harmonic generation with respect to the major gas components of the air will be reported. Supported by the ONR and RDECOM. I. Alexeev is NRC/NRL Post-Doc.

Synthesis, crystal structure, and magnetic properties of novel intermetallic compounds R2Co2SiC (R = Pr, Nd).

PubMed

Zhou, Sixuan; Mishra, Trinath; Wang, Man; Shatruk, Michael; Cao, Huibo; Latturner, Susan E

2014-06-16

The intermetallic compounds R2Co2SiC (R = Pr, Nd) were prepared from the reaction of silicon and carbon in either Pr/Co or Nd/Co eutectic flux. These phases crystallize with a new stuffed variant of the W2CoB2 structure type in orthorhombic space group Immm with unit cell parameters a = 3.978(4) Å, b = 6.094(5) Å, c = 8.903(8) Å (Z = 2; R1 = 0.0302) for Nd2Co2SiC. Silicon, cobalt, and carbon atoms form two-dimensional flat sheets, which are separated by puckered layers of rare-earth cations. Magnetic susceptibility measurements indicate that the rare earth cations in both analogues order ferromagnetically at low temperature (TC ≈ 12 K for Nd2Co2SiC and TC ≈ 20 K for Pr2Co2SiC). Single-crystal neutron diffraction data for Nd2Co2SiC indicate that Nd moments initially align ferromagnetically along the c axis around ∼12 K, but below 11 K, they tilt slightly away from the c axis, in the ac plane. Electronic structure calculations confirm the lack of spin polarization for Co 3d moments.

Observations and Light Curve Solutions of Ultrashort-Period Eclipsing Binaries

NASA Astrophysics Data System (ADS)

Kjurkchieva, Diana P.; Dimitrov, Dinko P.; Ibryamov, Sunay I.; Vasileva, Doroteya L.

2018-02-01

Photometric observations in V and I bands and low-dispersion spectra of 10 ultrashort-period binaries (NSVS 2175434, NSVS 2607629, NSVS 5038135, NSVS 8040227, NSVS 9747584, NSVS 4876238, ASAS 071829-0336.7, SWASP 074658.62+224448.5, NSVS 2729229, NSVS 10632802) are presented. One of them, NSVS 2729229, is newly discovered target. The results from modelling and analysis of our observations revealed that (i) eight targets have overcontact configurations with considerable fill-out factor (up to 0.5), while NSVS 4876238 and ASAS 0718-03 have almost contact configurations; (ii) NSVS 4876238 is rare ultrashort-period binary of detached type; (iii) all stellar components are late dwarfs; (iv) the temperature difference of the components of each target does not exceed 400 K; (v) NSVS 2175434 and SWASP 074658.62 + 224448.5 exhibit total eclipses and their parameters could be assumed as well determined; (v) NSVS 2729229 shows emission in the Hα line. Masses, radii, and luminosities of the stellar components were estimated by the empirical relation `period, orbital axis' for short- and ultrashort-period binaries. We found linear relations mass-luminosity and mass-radius for the stellar components of our targets.

PIRLS 2016 Assessment Framework. 2nd Edition

ERIC Educational Resources Information Center

Mullis, Ina V. S., Ed.; Martin, Michael O., Ed.

2015-01-01

The "PIRLS 2016 Assessment Framework, 2nd Edition" provides the foundation for the three international assessments planned as part of the International Association for the Evaluation of Educational Achievement's Progress in International Reading Literacy Study (PIRLS) 2016: PIRLS, PIRLS Literacy, and ePIRLS. PIRLS represents the…

Observations and light curve solutions of three ultrashort-period W UMa binaries

NASA Astrophysics Data System (ADS)

Kjurkchieva, Diana P.; Michel, Raul; Popov, Velimir A.; Deras, Dan

2018-07-01

Photometric observations in V, Rc and Ic bands of the ultrashort-period W UMa binaries 1SWASP J044132.96+440613.7, 1SWASP J052926.88+461147.5 and NSVS 2175434 are presented. The results from the modeling and analysis of our observations reveal that: (i) All targets undergo total eclipses and their photometric mass ratios should be accepted with confidence; (ii) All stellar components are late-type dwarfs; (iii) The temperature difference of target components does not exceed 150 K; (iv) All targets have overcontact configurations with fill-out factor around 0.24; (v) The orbit of NSVS 2175434 is slightly eccentric which is unusual for such an ultrashort-period binary; (vi) The orbital periods of all targets were improved. Masses, radii and luminosities of the stellar components were estimated by the empirical relation "period, orbital axis" for short- and ultrashort-period binaries.

Combination of CO2 and Q-switched Nd:YAG lasers is more effective than Q-switched Nd:YAG laser alone for eyebrow tattoo removal.

PubMed

Radmanesh, Mohammad; Rafiei, Zohreh

2015-04-01

The eyebrow tattoo removal using Q-switched lasers is usually prolonged. Other modalities may be required to enhance the efficacy and shorten the treatment course. To compare the efficacy of Q-switched neodymium-doped yttrium aluminum garnet (Nd:YAG) laser alone versus combination of Q-switched Nd:YAG and Ultrapulse CO2 lasers for eyebrow tattoo removal after a single session. After local anesthesia, the right eyebrow of 20 patients was treated with Ultrapulse CO2 laser with the parameters of 4 J/cm(2) and 3.2 J/cm(2) for the first and the second passes. Both eyebrows were then treated with 1064-nm and 532-nm Q-switched Nd:YAG laser. The spot size and pulse duration were 3 mm and 5 nanoseconds for both wavelengths, and the fluence was 7 J/cm(2) for 1064 nm and 3 J/cm (2) for 532 nm. The side treated with combination of Q-switched Nd:YAG and CO2 lasers improved 75-100% in 6 of 20 patients versus only 1 of 20 in the side treated with Q-switched Nd:YAG alone. Similarly, the right side in 13 of 20 patients showed more than 50% improvement with combination therapy versus the left side (the monotherapy side), where only 6 of 20 cases showed more than 50% improvement. The Mann-Whitney test was 2.85 for the right side and 1.95 for the left side (P value = 0.007). Using Ultra pulse CO2 laser enhances the efficacy of Q-switched Nd:YAG laser in eyebrow tattoo removal.

Lattice Parameter Behavior with Different Nd and O Concentrations in (U 1-yNd y)O 2±x Solid Solution

DOE PAGES

Lee, Seung Min; Knight, Travis W.; Voit, Stwart L.; ...

2016-02-02

The solid solution of (U1-yFPy)O- 2±x, has the same fluorite structure as UO 2±x lambda, and the lattice parameter is affected by dissolved fission product and oxygen concentrations. We investigated the relation between the lattice parameter and the concentrations of neodymium and oxygen in the fluorite structure of (U 1-yNd y)O 2±x using X-ray diffraction. Moreover, the lattice parameter behavior in the (U 1-yNd y)O 2±x, solid solution shows a linear change as a function of the oxygen-to-metal ratio and solubility of neodymium. The lattice parameter depends on the radii of ions forming the fluorite structure and also can bemore » expressed by a particular rule (modified Vegard's law). Furthermore, the numerical analyses of the lattice parameters for the stoichiometric and nonstoichionietric solid solutions were conducted, and the lattice parameter model for the (U1-yNdy)O 2±x, solid solution was assessed. There is a very linear relationship between the lattice parameter and the Nd and O concentration for the stoichiometry and nonstoichiometry of the (U 1-yNd y)O 2±x solid solution was verified.« less

Cation and Vacancy Disorder in U 1-yNd yO 2.00-X Alloys

DOE PAGES

Barabash, Rozaliya I.; Voit, Stewart L.; Aidhy, Dilpuneet S.; ...

2015-09-14

In this study, the intermixing and clustering of U/Nd, O, and vacancies were studied by both laboratory and synchrotron-based x-ray diffraction in U 1-yNd yO 2-X alloys. It was found that an increased holding time at the high experimental temperature during initial alloy preparation results in a lower disorder of the Nd distribution in the alloys. Adjustment of the oxygen concentration in the U 1-yNd yO 2-X alloys with different Nd concentrations was accompanied by the formation of vacancies on the oxygen sublattice and a nanocrystalline component. The lattice parameters in the U 1-yNd yO 2-X alloys were also foundmore » to deviate significantly from Vegard's law when the Nd concentration was high (53%) and decreased with increasing oxygen concentration. Such changes indicate the formation of large vacancy concentrations during oxygen adjustment at these high temperatures. Finally, the change in the vacancy concentration after the oxygen adjustment was estimated relative to Nd concentration and oxygen stoichiometry.« less

Nd2Fe14C-based magnet with better permanent magnetic properties prepared by a simple mechanochemical method

NASA Astrophysics Data System (ADS)

Geng, Hongmin; Ji, Yuan; Zhang, Jingjing; Gao, Yuchao; Yan, Yu; Wang, Wenquan; Su, Feng; Du, Xiaobo

2017-11-01

Nd2Fe14C-based magnet is prepared by a mechanochemical method, namely high-energy ball-milling Nd2Fe11Bx (x = 0-0.15) alloy in heptane (C7H16), followed by annealing to 850 °C in vacuum. Under the action of high-energy ball-milling, Nd2Fe11Bx react with heptane to form NdH2+δ, Fe-(CB), C, etc. H2 is released and Nd2Fe17, Nd2Fe17Cx (x = 0-3), Nd2Fe14C, Nd carbides and α-Fe are formed in the subsequent annealing. C amount depends on ball-milling time t. Long time ball milling or high C content suppresses the formation of 2:17 phase and favors the formation of 2:14:1 phase in the final products. Excessive ball-milling results in the quick increase of α-Fe. The maximum of magnetically hard Nd2Fe14C is obtained at t = 4 h. For Nd2Fe11 samples, there exists considerable quantity of Nd carbides and α-Fe phase appears earlier and increases rapidly with extending the ball-milling time t. The addition of B element shortens the ball-milling time of the formation of maximum Nd2Fe14C and prominently suppresses the formation of Nd carbide and α-Fe. The optimum magnetic properties, coercivity iHc of 1193.7 kA/m, remanence Mr of 580.9 kA/m, maximum magnetic energy product (BH)max of 91.7 kJ/m3 is approaching to its theoretic value of 99.2 kJ/m3 for isotropic Nd2Fe14C magnet, are obtained in Nd2Fe11B0.06 alloy ball milled for 3.5 h.

Lower periprosthetic bone loss and good fixation of an ultra-short stem compared to a conventional stem in uncemented total hip arthroplasty.

PubMed

Salemyr, Mats; Muren, Olle; Ahl, Torbjörn; Bodén, Henrik; Eisler, Thomas; Stark, André; Sköldenberg, Olof

2015-01-01

We hypothesized that an ultra-short stem would load the proximal femur in a more physiological way and could therefore reduce the adaptive periprosthetic bone loss known as stress shielding. 51 patients with primary hip osteoarthritis were randomized to total hip arthroplasty (THA) with either an ultra-short stem or a conventional tapered stem. The primary endpoint was change in periprosthetic bone mineral density (BMD), measured with dual-energy x-ray absorptiometry (DXA), in Gruen zones 1 and 7, two years after surgery. Secondary endpoints were change in periprosthetic BMD in the entire periprosthetic region, i.e. Gruen zones 1 through 7, stem migration measured with radiostereometric analysis (RSA), and function measured with self-administered functional scores. The periprosthetic decrease in BMD was statistically significantly lower with the ultra-short stem. In Gruen zone 1, the mean difference was 18% (95% CI: -27% to -10%). In zone 7, the difference was 5% (CI: -12% to -3%) and for Gruen zones 1-7 the difference was also 5% (CI: -9% to -2%). During the first 6 weeks postoperatively, the ultra-short stems migrated 0.77 mm more on average than the conventional stems. 3 months after surgery, no further migration was seen. The functional scores improved during the study and were similar in the 2 groups. Up to 2 years after total hip arthroplasty, compared to the conventional tapered stem the ultra-short uncemented anatomical stem induced lower periprosthetic bone loss and had equally excellent stem fixation and clinical outcome.

Medium-power diode-pumped Nd:BaY2F8 laser

NASA Astrophysics Data System (ADS)

Agnesi, Antonio; Guandalini, Annalisa; Lucca, Andrea; Sani, Elisa; Toncelli, Alessandra; Tonelli, Mauro; dell'Acqua, Stefano

2003-05-01

We report what is to our knowledge the first Nd:BaY2F8 (Nd:BaYF) laser pumped with a multiwatt fiber-coupled diode array tuned at approximately 804 nm. As much as 2.4 W were obtained with 6.2 W of absorbed pump power, showing efficient operation (51% slope efficiency), excellent beam quality (M2=1.1), and weak thermal lensing. Small intracavity losses (<1%) were measured, indicating both reduced thermally induced aberrations and good optical quality of the laser crystal.

1st- and 2nd-order motion and texture resolution in central and peripheral vision

NASA Technical Reports Server (NTRS)

Solomon, J. A.; Sperling, G.

1995-01-01

STIMULI. The 1st-order stimuli are moving sine gratings. The 2nd-order stimuli are fields of static visual texture, whose contrasts are modulated by moving sine gratings. Neither the spatial slant (orientation) nor the direction of motion of these 2nd-order (microbalanced) stimuli can be detected by a Fourier analysis; they are invisible to Reichardt and motion-energy detectors. METHOD. For these dynamic stimuli, when presented both centrally and in an annular window extending from 8 to 10 deg in eccentricity, we measured the highest spatial frequency for which discrimination between +/- 45 deg texture slants and discrimination between opposite directions of motion were each possible. RESULTS. For sufficiently low spatial frequencies, slant and direction can be discriminated in both central and peripheral vision, for both 1st- and for 2nd-order stimuli. For both 1st- and 2nd-order stimuli, at both retinal locations, slant discrimination is possible at higher spatial frequencies than direction discrimination. For both 1st- and 2nd-order stimuli, motion resolution decreases 2-3 times more rapidly with eccentricity than does texture resolution. CONCLUSIONS. (1) 1st- and 2nd-order motion scale similarly with eccentricity. (2) 1st- and 2nd-order texture scale similarly with eccentricity. (3) The central/peripheral resolution fall-off is 2-3 times greater for motion than for texture.

Hawking radiation from ultrashort laser pulse filaments.

PubMed

Belgiorno, F; Cacciatori, S L; Clerici, M; Gorini, V; Ortenzi, G; Rizzi, L; Rubino, E; Sala, V G; Faccio, D

2010-11-12

Event horizons of astrophysical black holes and gravitational analogues have been predicted to excite the quantum vacuum and give rise to the emission of quanta, known as Hawking radiation. We experimentally create such a gravitational analogue using ultrashort laser pulse filaments and our measurements demonstrate a spontaneous emission of photons that confirms theoretical predictions.

Physical properties of nanoparticles Nd added Bi1.7Pb0.3Sr2Ca2Cu3Oy superconductors

NASA Astrophysics Data System (ADS)

Abbas, Muna; Abdulridha, Ali; Jassim, Amal; Hashim, Fouad

2018-05-01

Bi1.7Pb0.3Sr2Ca2Cu3Oy bulks were synthesized, with the addition of Nd2O3 nanoparticles, by the solid state reaction method. The concentrations of Nd were varied from 0.1 to 0.6. The superconducting properties of the samples were investigated and studied to determine the influence of Nd2O3 addition on superconducting properties and microstructural development. The structural characteristics of the synthesized superconductor samples were carried out through X-ray diffractions. DC Four point probe method was used to study the electrical resistivity behavior and to evaluate the transition temperature (TC) for all samples. It was found that: 0.2 weight percentage of Nd2O3 yield the highest TC 123 K for highest volume fraction of 2223-phase, while excessive addition decreased both of them. The results point to compelling indications of correlations between charge carriers and superconductivity. Energy-dispersive X-ray spectroscopy (EDX) analysis for Bi1.7Pb0.3Nd0.2Sr2Ca2Cu3Oy superconductor shows that Nd may be substituted at Ca sites creating point defects, which act as flux pinning centers. Scanning electron microscopy (SEM) was employed to examine the microstructure of some samples. Their results showed precipitation of Nd nanoparticles on the surface as plate-like grains.

A CW green laser emission by self-sum-frequency-mixing in Nd:GdCOB crystal

NASA Astrophysics Data System (ADS)

Shao, Y.; Jin, H. J.; Lin, J.; Zhang, D.; Tao, Z. H.; Zhang, T. Y.; Li, Y. L.; Ruan, Q. R.

2011-10-01

A compact and efficient green laser light at 538 nm produced by self-sum-frequency-mixing of both fundamental infrared laser waves (1061 and 1091 nm) in Nd:GdCa4O(BO3)3 (Nd:GdCOB) crystal is demonstrated. With 18.2 W of diode pump power, a maximum output power of 1.73 W in the green spectral range at 538 nm has been achieved, corresponding to an optical-to-optical conversion efficiency of 9.5%; the output power stability over 30 min is better than 3%. To the best of our knowledge, this is first work on self-sum-frequency-mixing of a diode pumped Nd:GdCOB laser.

Laser ablation mechanism of transparent layers on semiconductors with ultrashort laser pulses

NASA Astrophysics Data System (ADS)

Rublack, Tino; Hartnauer, Stefan; Mergner, Michael; Muchow, Markus; Seifert, Gerhard

2011-12-01

Transparent dielectric layers on semiconductors are used as anti-reflection coatings both for photovoltaic applications and for mid-infrared optical elements. We have shown recently that selective ablation of such layers is possible using ultrashort laser pulses at wavelengths being absorbed by the semiconductor. To get a deeper understanding of the ablation mechanism, we have done ablation experiments for different transparent materials, in particular SiO2 and SixNy on silicon, using a broad range of wavelengths ranging from UV to IR, and pulse durations between 50 and 2000 fs. The characterization of the ablated regions was done by light microscopy and atomic force microscopy (AFM). Utilizing laser wavelengths above the silicon band gap, selective ablation of the dielectric layer without noticeable damage of the opened silicon surface is possible. In contrast, ultrashort pulses (1-2 ps) at mid-infrared wavelengths already cause damage in the silicon at lower intensities than in the dielectric layer, even when a vibrational resonance (e.g. at λ = 9.26 μm for SiO2) is addressed. The physical processes behind this, on the first glance counterintuitive, observation will be discussed.

Chemical separation of Nd from geological samples for chronological studies using (146)Sm-(142)Nd and (147)Sm-(143)Nd systematics.

PubMed

Kagami, Saya; Yokoyama, Tetsuya

2016-09-21

Sm-Nd dating, which involves long-lived (147)Sm-(143)Nd and short-lived (146)Sm-(142)Nd systematics, has been widely used in the field of geosciences. To obtain precise and accurate ages of geological samples, the determination of highly precise Nd isotope ratios with nearly complete removal of Ce and Sm is indispensable to avoid mass spectral interference. In this study, we developed a three-step column chemistry procedure for separating Nd from geological samples that includes cation exchange chromatography for separating major elements from rare earth elements (REEs), oxidative extraction chromatography using Ln Resin coupled with HNO3 + KBrO3 for separating tetravalent Ce from the remaining REEs, and final purification of Nd using Ln Resin. This method enables high recovery of Nd (>91%) with effective separation of Nd from Ce and Sm (Ce/Nd < 1.2 × 10(-5) and Sm/Nd < 5.2 × 10(-6)). In addition, we devised a new method for determining Sm/Nd ratios with the isotope dilution inductively coupled plasma mass spectrometry method using (145)Nd- and (149)Sm-enriched spikes coupled with a group separation of REEs using TRU Resin. Applying the techniques developed in this study, we determined the Sm-Nd whole-rock isochron age of basaltic eucrites, yielding 4577 - 88(+ 55) Ma and 4558 ± 300 Ma for (146)Sm-(142)Nd and (147)Sm-(143)Nd systematics, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

Frustrated ground state in the metallic Ising antiferromagnet Nd2Ni2In

NASA Astrophysics Data System (ADS)

Sala, G.; Mašková, S.; Stone, M. B.

2017-10-01

We used inelastic neutron scattering measurements to examine the intermetallic Ising antiferromagnet Nd2Ni2In . The dynamical structure factor displays a spectrum with multiple crystal field excitations. These crystal field excitations consist of a set of four transitions covering a range of energies between 4 and 80 meV. The spectrum is very sensitive to the temperature, and we observed a softening and a shift in the energies above the transition temperature of the system. The analysis of the crystalline electric field scheme confirms the Ising nature of the spins and their orientation as proposed by previous studies. We characterized Nd2Ni2In as a large moment intermetallic antiferromagnet with the potential to support a geometrically frustrated Shastry-Sutherland lattice.

Ultrafast Laser Interaction Processes for Libs and Other Sensing Technologies

DTIC Science & Technology

2013-04-05

Wang. Propagation of ultrashort pulses through water, Optics Express, (02 2007): . doi: 12/02/2009 8.00 Z. Chen, S. Mao. Femtosecond laser -induced...Richardson, "Nd:YAG-CO2 double- pulse laser -induced breakdown spectroscopy for explosive residues detection" SPIE Defense, Security, Sensing; Orlando, FL... Ultrashort Pulse Laser Workshop, Directed Energy Professional Society; Newton, MA, USA; 06/29,2009. 63. Martin C. Richardson, Michael Sigman

Magnetic Field Effect on Ultrashort Two-dimensional Optical Pulse Propagation in Silicon Nanotubes

NASA Astrophysics Data System (ADS)

Konobeeva, N. N.; Evdokimov, R. A.; Belonenko, M. B.

2018-05-01

The paper deals with the magnetic field effect which provides a stable propagation of ultrashort pulses in silicon nanotubes from the viewpoint of their waveform. The equation is derived for the electromagnetic field observed in silicon nanotubes with a glance to the magnetic field for two-dimensional optical pulses. The analysis is given to the dependence between the waveform of ultrashort optical pulses and the magnetic flux passing through the cross-sectional area of the nanotube.

Lower periprosthetic bone loss and good fixation of an ultra-short stem compared to a conventional stem in uncemented total hip arthroplasty

PubMed Central

Salemyr, Mats; Muren, Olle; Ahl, Torbjörn; Bodén, Henrik; Eisler, Thomas; Stark, André; Sköldenberg, Olof

2015-01-01

Background and purpose — We hypothesized that an ultra-short stem would load the proximal femur in a more physiological way and could therefore reduce the adaptive periprosthetic bone loss known as stress shielding. Patients and methods — 51 patients with primary hip osteoarthritis were randomized to total hip arthroplasty (THA) with either an ultra-short stem or a conventional tapered stem. The primary endpoint was change in periprosthetic bone mineral density (BMD), measured with dual-energy x-ray absorptiometry (DXA), in Gruen zones 1 and 7, two years after surgery. Secondary endpoints were change in periprosthetic BMD in the entire periprosthetic region, i.e. Gruen zones 1 through 7, stem migration measured with radiostereometric analysis (RSA), and function measured with self-administered functional scores. Results — The periprosthetic decrease in BMD was statistically significantly lower with the ultra-short stem. In Gruen zone 1, the mean difference was 18% (95% CI: −27% to −10%). In zone 7, the difference was 5% (CI: −12% to −3%) and for Gruen zones 1–7 the difference was also 5% (CI: −9% to −2%). During the first 6 weeks postoperatively, the ultra-short stems migrated 0.77 mm more on average than the conventional stems. 3 months after surgery, no further migration was seen. The functional scores improved during the study and were similar in the 2 groups. Interpretation — Up to 2 years after total hip arthroplasty, compared to the conventional tapered stem the ultra-short uncemented anatomical stem induced lower periprosthetic bone loss and had equally excellent stem fixation and clinical outcome. PMID:26134386

Interaction of ultrashort laser pulses and silicon solar cells under short circuit conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mundus, M., E-mail: markus.mundus@ise.fraunhofer.de; Giesecke, J. A.; Fischer, P.

Ultrashort pulse lasers are promising tools for numerous measurement purposes. Among other benefits their high peak powers allow for efficient generation of wavelengths in broad spectral ranges and at spectral powers that are orders of magnitude higher than in conventional light sources. Very recently this has been exploited for the establishment of sophisticated measurement facilities for electrical characterization of photovoltaic (PV) devices. As the high peak powers of ultrashort pulses promote nonlinear optical effects they might also give rise to nonlinear interactions with the devices under test that possibly manipulate the measurement outcome. In this paper, we present a comprehensivemore » theoretical and experimental study of the nonlinearities affecting short circuit current (I{sub SC}) measurements of silicon (Si) solar cells. We derive a set of coupled differential equations describing the radiation-device interaction and discuss the nonlinearities incorporated in those. By a semi-analytical approach introducing a quasi-steady-state approximation and integrating a Green's function we solve the system of equations and obtain simulated I{sub SC} values. We validate the theoretical model by I{sub SC} ratios obtained from a double ring resonator setup capable for reproducible generation of various ultrashort pulse trains. Finally, we apply the model to conduct the most prominent comparison of I{sub SC} generated by ultrashort pulses versus continuous illumination. We conclude by the important finding that the nonlinearities induced by ultrashort pulses are negligible for the most common I{sub SC} measurements. However, we also find that more specialized measurements (e.g., of concentrating PV or Si-multijunction devices as well as highly localized electrical characterizations) will be biased by two-photon-absorption distorting the I{sub SC} measurement.« less

5 GHz fundamental repetition rate, wavelength tunable, all-fiber passively mode-locked Yb-fiber laser.

PubMed

Cheng, Huihui; Wang, Wenlong; Zhou, Yi; Qiao, Tian; Lin, Wei; Xu, Shanhui; Yang, Zhongmin

2017-10-30

A passively mode-locked Yb 3+ -doped fiber laser with a fundamental repetition rate of 5 GHz and wavelength tunable performance is demonstrated. A piece of heavily Yb 3+ -doped phosphate fiber with a high net gain coefficient of 5.7 dB/cm, in conjunction with a fiber mirror by directly coating the SiO 2 /Ta 2 O 5 dielectric films on a fiber ferrule is exploited for shortening the laser cavity to 2 cm. The mode-locked oscillator has a peak wavelength of 1058.7 nm, pulse duration of 2.6 ps, and the repetition rate signal has a high signal-to-noise ratio of 90 dB. Moreover, the wavelength of the oscillator is found to be continuously tuned from 1056.7 to 1060.9 nm by increasing the temperature of the laser cavity. Simultaneously, the repetition rate correspondingly decreases from 4.945874 to 4.945496 GHz. Furthermore, the long-term stability of the mode-locked operation in the ultrashort laser cavity is realized by exploiting temperature controls. This is, to the best of our knowledge, the highest fundamental pulse repetition rate for 1-μm mode-locked fiber lasers.

Structural and magnetic investigations of single-crystalline neodymium zirconate pyrochlore Nd2Zr2O7

NASA Astrophysics Data System (ADS)

Hatnean, M. Ciomaga; Lees, M. R.; Petrenko, O. A.; Keeble, D. S.; Balakrishnan, G.; Gutmann, M. J.; Klekovkina, V. V.; Malkin, B. Z.

2015-05-01

We report structural and magnetic properties studies of large high-quality single crystals of the frustrated magnet Nd2Zr2O7 . Powder x-ray diffraction analysis confirms that Nd2Zr2O7 adopts the pyrochlore structure. Room-temperature x-ray diffraction and time-of-flight neutron-scattering experiments show that the crystals are stoichiometric in composition with no measurable site disorder. The temperature dependence of the magnetic susceptibility shows no magnetic ordering at temperatures down to 0.5 K. Fits to the magnetic susceptibility data using a Curie-Weiss law reveal a ferromagnetic coupling between the Nd moments. Magnetization versus field measurements show a local Ising anisotropy along the <111 > axes of the Nd3 + ions in the ground state. Specific heat versus temperature measurements in zero applied magnetic field indicate the presence of a thermal anomaly below T ˜7 K, but no evidence of magnetic ordering is observed down to 0.5 K. The experimental temperature dependence of the single-crystal bulk dc susceptibility and isothermal magnetization are analyzed using crystal field theory and the crystal field parameters and exchange coupling constants determined.

Laser and thermal properties of Nd:YGd2Sc2Al2GaO12 garnet ceramic Laser and thermal properties of Nd:YSGG garnet ceramic

NASA Astrophysics Data System (ADS)

Brenier, A.; Alombert-Goget, G.; Guyot, Y.; Boulon, G.

2012-10-01

The absorption and fluorescence properties of the Nd-doped YGd2Sc2Al2GaO12 mixed garnet ceramics have been measured at different temperatures. Under laser diode pumping an efficient laser emission has been demonstrated with 45% slope efficiency. The emission is constituted by two lines at 1058.6 and 1061.3 nm, subjected to a red shift and a variable relative intensity versus pump power. The role of the temperature has been investigated playing with the cavity parameters. The thermal conductivity of the 1% Nd-doped material has been determined (3.2 W/m/K) measuring the radial temperature distribution of the exit face of the sample including the axial heat flow in the analysis. The M2 beam quality factor and the dioptric power of the thermal lens have been investigated versus the pump power. The thermo-optic coefficient χ was determined as 44.4×10-6 K-1.

Plasma-driven ultrashort bunch diagnostics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dornmair, I.; Schroeder, C. B.; Floettmann, K.

2016-06-10

Ultrashort electron bunches are crucial for an increasing number of applications, however, diagnosing their longitudinal phase space remains a challenge. We propose a new method that harnesses the strong electric fields present in a laser driven plasma wakefield. By transversely displacing driver laser and witness bunch, a streaking field is applied to the bunch. This field maps the time information to a transverse momentum change and, consequently, to a change of transverse position. We illustrate our method with simulations where we achieve a time resolution in the attosecond range.

Fluctuations and All-In-All-Out Ordering in Dipole-Octupole Nd2Zr2O7

NASA Astrophysics Data System (ADS)

Lhotel, E.; Petit, S.; Guitteny, S.; Florea, O.; Ciomaga Hatnean, M.; Colin, C.; Ressouche, E.; Lees, M. R.; Balakrishnan, G.

2015-11-01

By means of neutron scattering and magnetization measurements down to 90 mK, we determine the magnetic ground state of the spin-ice candidate Nd2Zr2O7. We show that, despite ferromagnetic interactions, Nd2Zr2O7 undergoes a transition around 285 mK towards an all-in-all-out antiferromagnetic state, with a strongly reduced ordered magnetic moment. We establish the (H ,T ) phase diagram in the three directions of the applied field and reveal a metamagnetic transition around 0.1 T, associated with an unexpected shape of the magnetization curves. We propose that this behavior results from the peculiar nature of the Nd3 + doublet, a dipolar-octupolar doublet, different from the standard Kramers doublet studied to date, thus revealing the importance of multipolar correlations in the properties of pyrochlore oxides.

Ultrashort megaelectronvolt positron beam generation based on laser-accelerated electrons

NASA Astrophysics Data System (ADS)

Xu, Tongjun; Shen, Baifei; Xu, Jiancai; Li, Shun; Yu, Yong; Li, Jinfeng; Lu, Xiaoming; Wang, Cheng; Wang, Xinliang; Liang, Xiaoyan; Leng, Yuxin; Li, Ruxin; Xu, Zhizhan

2016-03-01

Experimental generation of ultrashort MeV positron beams with high intensity and high density using a compact laser-driven setup is reported. A high-density gas jet is employed experimentally to generate MeV electrons with high charge; thus, a charge-neutralized MeV positron beam with high density is obtained during laser-accelerated electrons irradiating high-Z solid targets. It is a novel electron-positron source for the study of laboratory astrophysics. Meanwhile, the MeV positron beam is pulsed with an ultrashort duration of tens of femtoseconds and has a high peak intensity of 7.8 × 1021 s-1, thus allows specific studies of fast kinetics in millimeter-thick materials with a high time resolution and exhibits potential for applications in positron annihilation spectroscopy.

Single-photon ultrashort-lived radionuclides: symposium proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paras, P.; Thiessen, J.W.

1985-01-01

The purpose was to define the current role and state-of-the-art regarding the development, clinical applications, and usefulness of generator-produced single-photon ultrashort-lived radionuclides (SPUSLR's) and to predict their future impact on medicine. Special emphasis was placed on the generator production of iridium-191, gold-195, and krypton-81. This report contains expanded summaries of the included papers. (ACR)

Laser system using ultra-short laser pulses

DOEpatents

Dantus, Marcos [Okemos, MI; Lozovoy, Vadim V [Okemos, MI; Comstock, Matthew [Milford, MI

2009-10-27

A laser system using ultrashort laser pulses is provided. In another aspect of the present invention, the system includes a laser, pulse shaper and detection device. A further aspect of the present invention employs a femtosecond laser and binary pulse shaping (BPS). Still another aspect of the present invention uses a laser beam pulse, a pulse shaper and a SHG crystal.

Structure and magnetic properties of Nd2Fe14B fine particles produced by spark erosion

NASA Astrophysics Data System (ADS)

Wan, H.; Berkowitz, A. E.

1994-11-01

At present Nd2Fe14B is the best permanent magnet because of its extremely high coercivity and energy product. Optimum properties of Nd2Fe14B magnets can be attained by producing single domain particles, and then aligning and compacting them. Due to the reactivity of the Nd constitutent, it is challenging to produce and handle a large amount of fine particles of this material. We have prepared fine particles of Nd2Fe14B by spark erosion with various dielectric media. Yield, size, size distribution, structure, and magnetic properties are discussed. The Nd2Fe14B particles were made by the sharker pot spark erosion method. Relaxation oscillators or a pulse generator were used to power the park erosion. Commercial Neomax 35 was employed as the primary material. The dielectric media were liquid Ar, Ar gas, and hydrocarbons, which provided an oxygen free environment. Structure and size were studied by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and x-ray diffraction. Magnetic properties were measured by vibrating sample magnetometer (VSM) with temperatures in range of 4.2-1200 K. The particles produced in these three different dielectric media had different microstructures and crystal structures. The particles made in Ar gas were pure Nd2Fe14B phase. The particles made in liquid Ar were a mixture of amorphous and crystalline Nd2Fe14B, because the liquid Ar provided a much higher quench rate than Ar gas, which produced some amorphous Nd2Fe14B. Upon annealing, the amorphous particles became crystalline. The fine particles produced in hydrocarbons, such as pentane and dodecane, had more complex mixed phases, since the rare earth reacted with the hydrocarbons during the sparking process. The phases were NdC2, alpha-Fe, and amorphous and crystalline Nd2Fe14B. The effects of power parameters, such as voltage and capacitance, on particle size were investigated. Particle sizes from 20 nm to 50 microns were obtained. Nd2Fe14B

Grain boundary diffusion behaviors in hot-deformed Nd2Fe14B magnets by PrNd-Cu low eutectic alloys

NASA Astrophysics Data System (ADS)

Tang, Xu; Chen, Renjie; Li, Ming; Jin, Chaoxiang; Yin, Wenzong; Lee, Don; Yan, Aru

2018-01-01

High coercivity of hot-deformed Nd2Fe14B magnets was obtained by grain boundary diffusion. Comparable squareness and similar magnetic properties for samples diffusing from side and pole surfaces show little discrepancies if quantities of the infiltrated PrNd-Cu low eutectic alloys is enough to obtain sufficient diffusion. However, the microstructures and higher characteristic peak ratios show preferable orientation of grains near surfaces of the sample diffused from side surfaces than that from pole surfaces. Amorphous Nd-rich phases and crystal Fe-rich phases were both observed in the diffused magnets. The enhancement of coercivity is considered to be resulted from grain boundary optimization and magnetic isolation which is caused by the thickened nonmagnetic intergranular phases.

A Channelized 2nd IF/LO Downconverter for the E0S Microwave Limb Sounder

NASA Technical Reports Server (NTRS)

LaBelle, Remi C.

2003-01-01

The Earth Observing System (EOS) Microwave Limb Sounder (MLS) is scheduled for launch in 2004 on the EOS Aura spacecraft. The design, assembly and test of the flight 2nd Intermediate Frequency/ Local Oscillator (2nd IF/LO) subsystem for this instrument has been completed and is presented here. The 2nd IF/LO subsystem consists of 5 separate microwave assemblies, 1 for each of the 5 millimeter wave radiometer front ends, providing a total of 33 separate IF channels. Some key requirements of the subsystem are as follows: provide frequency multiplexing of overlapping or closely spaced 1st IF channels while maintaining low ripple in the passbands; generate 19 different 2nd LO frequencies, in the range of 4-20 GHz, with low phase noise and a placement resolution of 400 KHz; downconvert the 1st IF's to a common 2nd IF frequency centered at 900 MHz; minimize cost and schedule by using common designs for the 5 different assemblies wherever possible.

[INVITED] Laser welding of glasses at high repetition rates - Fundamentals and prospects

NASA Astrophysics Data System (ADS)

Richter, Sören; Zimmermann, Felix; Tünnermann, Andreas; Nolte, Stefan

2016-09-01

We report on the welding of various glasses with ultrashort laser pulses. Femtosecond laser pulses at repetition rates in the MHz range are focused at the interface between two substrates, resulting in multiphoton absorption and heat accumulation from successive pulses. This leads to local melting and subsequent resolidification which can be used to weld the glasses. The fundamental interaction process was studied using an in-situ micro Raman setup to measure the laser induced temperature distribution and its temporal decay. The induced network changes were analyzed by Raman spectrocopy identifying an increase of three and four membered silicon rings within the laser irradiated area. In order to determine the stability of the laser welded samples a three point bending test was used. Thereby, we identified that the maximal achievable breaking strength is limited by laser induced stress surrounding the modified material. To minimize the amount of stress bursts of laser pulses or an post processing annealing step can be applied. Besides fused silica, we welded borosilicate glasses and glasses with a low thermal expansion coefficient. Even the welding of different glass combinations is possible demonstrating the versatility of ultrashort pulse induced laser welding.

Structural properties and sensing performance of high-k Nd2TiO5 thin layer-based electrolyte-insulator-semiconductor for pH detection and urea biosensing.

PubMed

Pan, Tung-Ming; Lin, Jian-Chi; Wu, Min-Hsien; Lai, Chao-Sung

2009-05-15

For high sensitive pH sensing, an electrolyte-insulator-semiconductor (EIS) device with Nd(2)TiO(5) thin layers fabricated on Si substrates by means of reactive sputtering and the subsequent post-deposition annealing (PDA) treatment was proposed. In this work, the effect of thermal annealing (600, 700, 800, and 900 degrees C) on the structural characteristics of Nd(2)TiO(5) thin layer was investigated by X-ray diffraction, X-ray photoelectron spectroscopy, and atomic force microscopy. The observed structural properties were then correlated with the resulting pH sensing performances. For enzymatic field-effect-transistors-based urea biosensing, a hybrid configuration of the proposed Nd(2)TiO(5) thin layer with urease-immobilized alginate film attached was established. Within the experimental conditions investigated, the EIS device with the Nd(2)TiO(5) thin layer annealed at 800 degrees C exhibited a higher pH detection sensitivity of 57.2 mV/pH, a lower hysteresis voltage of 2.33 mV, and a lower drift rate of 1.80 mV/h compared to those at other annealing temperatures. These results are attributed to the formation of a thinner low-k interfacial layer at the oxide/Si interface and the higher surface roughness occurred at this annealing temperature. Furthermore, the presented urea biosensor was also proved to be able to detect urea with good linearity (R(2)=0.99) and reasonable sensitivity of 9.52 mV/mM in the urea concentration range of 3-40 mM. As a whole, the present work has provided some fundamental data for the use of Nd(2)TiO(5) thin layer for EIS-based pH detection and the extended application for biosensing.

Ultrashort Echo-Time Magnetic Resonance Imaging Is a Sensitive Method for the Evaluation of Early Cystic Fibrosis Lung Disease

PubMed Central

Roach, David J.; Crémillieux, Yannick; Fleck, Robert J.; Brody, Alan S.; Serai, Suraj D.; Szczesniak, Rhonda D.; Kerlakian, Stephanie; Clancy, John P.

2016-01-01

Rationale: Recent advancements that have been made in magnetic resonance imaging (MRI) improve our ability to assess pulmonary structure and function in patients with cystic fibrosis (CF). A nonionizing imaging modality that can be used as a serial monitoring tool throughout life can positively affect patient care and outcomes. Objectives: To compare an ultrashort echo-time MRI method with computed tomography (CT) as a biomarker of lung structure abnormalities in young children with early CF lung disease. Methods: Eleven patients with CF (mean age, 31.8 ± 5.7 mo; median age, 33 mo; 7 male and 4 female) were imaged via CT and ultrashort echo-time MRI. Eleven healthy age-matched patients (mean age, 22.5 ± 10.2 mo; median age, 23 mo; 5 male and 6 female) were imaged via ultrashort echo-time MRI. CT scans of 13 additional patients obtained for clinical indications not affecting the heart or lungs and interpreted as normal provided a CT control group (mean age, 24.1 ± 11.7 mo; median age, 24 mo; 6 male and 7 female). Studies were scored by two experienced radiologists using a well-validated CF-specific scoring system for CF lung disease. Measurements and Main Results: Correlations between CT and ultrashort echo-time MRI scores of patients with CF were very strong, with P values ≤0.001 for bronchiectasis (r = 0.96) and overall score (r = 0.90), and moderately strong for bronchial wall thickening (r = 0.62, P = 0.043). MRI easily differentiated CF and control groups via a reader CF-specific scoring system. Conclusions: Ultrashort echo-time MRI detected structural lung disease in very young patients with CF and provided imaging data that correlated well with CT. By quantifying early CF lung disease without using ionizing radiation, ultrashort echo-time MRI appears well suited for pediatric patients requiring longitudinal imaging for clinical care or research studies. Clinical Trial registered with www.clinicaltrials.gov (NCT01832519). PMID

Magnetic structure of the mixed antiferromagnet NdMn0.8Fe0.2O3

NASA Astrophysics Data System (ADS)

Mihalik, Matúš; Mihalik, Marián; Hoser, Andreas; Pajerowski, Daniel M.; Kriegner, Dominik; Legut, Dominik; Lebecki, Kristof M.; Vavra, Martin; Fitta, Magdalena; Meisel, Mark W.

2017-10-01

The magnetic structure of the mixed antiferromagnet NdMn0.8Fe0.2O3 was resolved. Neutron powder diffraction data definitively resolve the Mn sublattice with a magnetic propagation vector k =(000 ) and with the magnetic structure (Ax,Fy,Gz ) for 1.6 K Nd sublattice has a (0 ,fy,0 ) contribution in the same temperature interval. The Mn sublattice undergoes a spin-reorientation transition at T1≈13 K while the Nd magnetic moment abruptly increases at this temperature. Powder x-ray diffraction shows a strong magnetoelastic effect at TN but no additional structural phase transitions from 3 to 300 K. Density functional theory calculations confirm the magnetic structure of the undoped NdMnO3 as part of our analysis. Taken together, these results show that the magnetic structure of the Mn sublattice in NdMn0.8Fe0.2O3 is a combination of the Mn and Fe parent compounds, but the magnetic ordering of the Nd sublattice spans a broader temperature interval than in the case of NdMnO3 and NdFeO3. This result is a consequence of the fact that the Nd ions do not order independently, but via polarization from the Mn/Fe sublattice.

Book Review: Bioassays with Arthropods: 2nd Edition

USDA-ARS?s Scientific Manuscript database

The technical book "Bioassays with Arthropods: 2nd Edition" (2007. Jacqueline L. Robertson, Robert M. Russell, Haiganoush K, Preisler and N. E. Nevin, Eds. CRC Press, Boca Raton, FL, 224 pp.) was reviewed for the scientific readership of the peer-reviewed publication Journal of Economic Entomology. ...

Black phosphorus saturable absorber for ultrashort pulse generation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sotor, J., E-mail: jaroslaw.sotor@pwr.edu.pl; Sobon, G.; Abramski, K. M.

Low-dimensional materials, due to their unique and versatile properties, are very interesting for numerous applications in electronics and optoelectronics. Recently rediscovered black phosphorus, with a graphite-like layered structure, can be effectively exfoliated up to the single atomic layer called phosphorene. Contrary to graphene, it possesses a direct band gap controllable by the number of stacked atomic layers. For those reasons, black phosphorus is now intensively investigated and can complement or replace graphene in various photonics and electronics applications. Here, we demonstrate that black phosphorus can serve as a broadband saturable absorber and can be used for ultrashort optical pulse generation.more » The mechanically exfoliated ∼300 nm thick layers of black phosphorus were transferred onto the fiber core, and under pulsed excitation at 1560 nm wavelength, its transmission increases by 4.6%. We have demonstrated that the saturable absorption of black phosphorus is polarization sensitive. The fabricated device was used to mode-lock an Er-doped fiber laser. The generated optical solitons with the 10.2 nm bandwidth and 272 fs duration were centered at 1550 nm. The obtained results unambiguously show that black phosphorus can be effectively used for ultrashort pulse generation with performances similar or even better than currently used graphene or carbon nanotubes. This application of black phosphorus proves its great potential to future practical use in photonics.« less

Reconfigurable wavefront sensor for ultrashort pulses.

PubMed

Bock, Martin; Das, Susanta Kumar; Fischer, Carsten; Diehl, Michael; Börner, Peter; Grunwald, Ruediger

2012-04-01

A highly flexible Shack-Hartmann wavefront sensor for ultrashort pulse diagnostics is presented. The temporal system performance is studied in detail. Reflective operation is enabled by programming tilt-tolerant microaxicons into a liquid-crystal-on-silicon spatial light modulator. Nearly undistorted pulse transfer is obtained by generating nondiffracting needle beams as subbeams. Reproducible wavefront analysis and spatially resolved second-order autocorrelation are demonstrated at incident angles up to 50° and pulse durations down to 6 fs.

Single-crystal and textured polycrystalline Nd2Fe14B flakes with a submicron or nanosize thickness

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cui, BZ; Zheng, LY; Li, WF

2012-02-01

This paper reports on the fabrication, structure and magnetic property optimization of Nd2Fe14B single-crystal and [0 0 1] textured poly-nanocrystalline flakes prepared by surfactant-assisted high-energy ball milling (HEBM). Single-crystal Nd2Fe14B flakes first with micron and then with submicron thicknesses were formed via continuous basal cleavage along the (1 1 0) planes of the irregularly shaped single-crystal microparticles during the early stage of HEBM. With further milling, [0 0 1] textured polycrystalline submicron Nd2Fe14B flakes were formed. Finally, crystallographically anisotropic polycrystalline Nd2Fe14B nanoflakes were formed after milling for 5-6 h. Anisotropic magnetic behavior was found in all of the flake samples.more » Nd2Fe14B flakes prepared with either oleic acid (OA) or oleylamine (OY) as the surfactant exhibited similar morphology, structure and magnetic properties. Both the addition of some low-melting-point eutectic Nd70Cu30 alloy and an appropriate post-annealing can increase the coercivity of the Nd2Fe14B flakes. The coercivity of Nd2Fe14B nanoflakes with an addition of 16.7 wt.% Nd70Cu30 by milling for 5 h in heptane with 20 wt.% OY increased from 3.7 to 6.8 kOe after annealing at 450 degrees C for 0.5 h. The mechanism for formation and coercivity enhancement of Nd2Fe14B single-crystal and textured poly-nanocrystalline flakes with a submicron or nanosize thickness was discussed. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.« less

Investigation on demagnetization of Nd2Fe14B permanent magnets induced by irradiation

NASA Astrophysics Data System (ADS)

Li, Zhefu; Jia, Yanyan; Liu, Renduo; Xu, Yuhai; Wang, Guanghong; Xia, Xiaobin

2017-12-01

Nd2Fe14B is an important component of insertion devices, which are used in synchrotron radiation sources, and could be demagnetized by irradiation. In the present study, the Monte Carlo code FLUKA was used to analyze the irradiation field of Nd2Fe14B, and it was confirmed that the main demagnetization particle was neutron. Nd2Fe14B permanent magnet samples were irradiated by Ar ions at different doses to simulate neutron irradiation damage. The hysteresis loops were measured using a vibrating sample magnetometer, and the microstructure evolutions were characterized by transmission electron microscopy. Moreover, the relationship between them was discussed. The results indicate that the decrease in saturated magnetization is caused by the changes in microstructure. The evolution of single crystals into an amorphous structure is the reason for the demagnetization phenomenon of Nd2Fe14B permanent magnets when considering its microscopic structure.

Nanoplasmonic generation of ultrashort EUV pulses

NASA Astrophysics Data System (ADS)

Choi, Joonhee; Lee, Dong-Hyub; Han, Seunghwoi; Park, In-Yong; Kim, Seungchul; Kim, Seung-Woo

2012-10-01

Ultrashort extreme-ultraviolet (EUV) light pulses are an important tool for time-resolved pump-probe spectroscopy to investigate the ultrafast dynamics of electrons in atoms and molecules. Among several methods available to generate ultrashort EUV light pulses, the nonlinear frequency upconversion process of high-harmonic generation (HHG) draws attention as it is capable of producing coherent EUV pulses with precise control of burst timing with respect to the driving near-infrared (NIR) femtosecond laser. In this report, we present and discuss our recent experimental data obtained by the plasmon-driven HHG method that generate EUV radiation by means of plasmonic nano-focusing of NIR femtosecond pulses. For experiment, metallic waveguides having a tapered hole of funnel shape inside were fabricated by adopting the focused-ion-beam process on a micro-cantilever substrate. The plasmonic field formed within the funnelwaveguides being coupled with the incident femtosecond pulse permitted intensity enhancement by a factor of ~350, which creates a hot spot of sub-wavelength size with intensities strong enough for HHG. Experimental results showed that with injection of noble gases into the funnel-waveguides, EUV radiation is generated up to wavelengths of 32 nm and 29.6 nm from Ar and Ne gas atoms, respectively. Further, it was observed that lower-order EUV harmonics are cut off in the HHG spectra by the tiny exit aperture of the funnel-waveguide.

Hydrazinium lanthanide oxalates: synthesis, structure and thermal reactivity of N2H5[Ln2(C2O4)4(N2H5)]·4H2O, Ln = Ce, Nd.

PubMed

De Almeida, Lucie; Grandjean, Stéphane; Rivenet, Murielle; Patisson, Fabrice; Abraham, Francis

2014-03-28

New hydrazinium lanthanide oxalates N2H5[Ln2(C2O4)4(N2H5)]·4H2O, Ln = Ce (Ce-HyOx) and Nd (Nd-HyOx), were synthesized by hydrothermal reaction at 150 °C between lanthanide nitrate, oxalic acid and hydrazine solutions. The structure of the Nd compound was determined from single-crystal X-ray diffraction data, space group P2₁/c with a = 16.315(4), b = 12.127(3), c = 11.430(2) Å, β = 116.638(4)°, V = 2021.4(7) Å(3), Z = 4, and R1 = 0.0313 for 4231 independent reflections. Two distinct neodymium polyhedra are formed, NdO9 and NdO8N, an oxygen of one monodentate oxalate in the former being replaced by a nitrogen atom of a coordinated hydrazinium ion in the latter. The infrared absorption band at 1005 cm(-1) confirms the coordination of N2H5(+) to the metal. These polyhedra are connected through μ2 and μ3 oxalate ions to form an anionic three-dimensional neodymium-oxalate arrangement. A non-coordinated charge-compensating hydrazinium ion occupies, with water molecules, the resulting tunnels. The N-N stretching frequencies of the infrared spectra demonstrate the existence of the two types of hydrazine ions. Thermal reactivity of these hydrazinium oxalates and of the mixed isotypic Ce/Nd (CeNd-HyOx) oxalate were studied by using thermogravimetric and differential thermal analyses coupled with gas analyzers, and high temperature X-ray diffraction. Under air, fine particles of CeO2 and Ce(0.5)Nd(0.5)O(1.75) are formed at low temperature from Ce-HyOx and CeNd-HyOx, respectively, thanks to a decomposition/oxidation process. Under argon flow, dioxymonocyanamides Ln2O2CN2 are formed.

Magnetic structure of the mixed antiferromagnet NdMn 0.8 Fe 0.2 O 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mihalik, Matus; Mihalik, Marian; Hoser, Andreas

The magnetic structure of the mixed antiferromagnet NdMn 0.8Fe 0.2O 3 was resolved. Neutron powder diffraction data definitively resolve the Mn sublattice with a magnetic propagation vector k=(000) and with the magnetic structure (A x, F y, G z) for 1.6 K N(≈ 59 K). The Nd sublattice has a (0, f y, 0) contribution in the same temperature interval. The Mn sublattice undergoes a spin-reorientation transition at T 1 ≈ 13 K while the Nd magnetic moment abruptly increases at this temperature. Powder x-ray diffraction shows a strong magnetoelastic effect at T N but no additional structural phase transitionsmore » from 3 to 300 K. Density functional theory calculations confirm the magnetic structure of the undoped NdMnO 3 as part of our analysis. Taken together, these results show that the magnetic structure of the Mn sublattice in NdMn 0.8Fe 0.2O 3 is a combination of the Mn and Fe parent compounds, but the magnetic ordering of the Nd sublattice spans a broader temperature interval than in the case of NdMnO 3 and NdFeO 3. Lastly, this result is a consequence of the fact that the Nd ions do not order independently, but via polarization from the Mn/Fe sublattice.« less

Magnetic structure of the mixed antiferromagnet NdMn 0.8 Fe 0.2 O 3

DOE PAGES

Mihalik, Matus; Mihalik, Marian; Hoser, Andreas; ...

2017-10-27

The magnetic structure of the mixed antiferromagnet NdMn 0.8Fe 0.2O 3 was resolved. Neutron powder diffraction data definitively resolve the Mn sublattice with a magnetic propagation vector k=(000) and with the magnetic structure (A x, F y, G z) for 1.6 K N(≈ 59 K). The Nd sublattice has a (0, f y, 0) contribution in the same temperature interval. The Mn sublattice undergoes a spin-reorientation transition at T 1 ≈ 13 K while the Nd magnetic moment abruptly increases at this temperature. Powder x-ray diffraction shows a strong magnetoelastic effect at T N but no additional structural phase transitionsmore » from 3 to 300 K. Density functional theory calculations confirm the magnetic structure of the undoped NdMnO 3 as part of our analysis. Taken together, these results show that the magnetic structure of the Mn sublattice in NdMn 0.8Fe 0.2O 3 is a combination of the Mn and Fe parent compounds, but the magnetic ordering of the Nd sublattice spans a broader temperature interval than in the case of NdMnO 3 and NdFeO 3. Lastly, this result is a consequence of the fact that the Nd ions do not order independently, but via polarization from the Mn/Fe sublattice.« less

The effects of Nd2O3 concentration in the laser emission of TeO2-ZnO glasses

NASA Astrophysics Data System (ADS)

Moreira, L. M.; Anjos, V.; Bell, M. J. V.; Ramos, C. A. R.; Kassab, L. R. P.; Doualan, D. J. L.; Camy, P.; Moncorgé, R.

2016-08-01

The present work reports the modification introduced by different Nd2O3 concentration on optical properties and the laser operation of Nd3+ doped (TeO2-ZnO) bulk tellurite glass. The spectroscopic data are analyzed within the Judd Ofelt formalism framework and the results are compared to the fluorescence lifetime and emission measurements to derive values for the quantum efficiency and the stimulated emission cross section of the considered 4F3/2 → 4I11/2 infrared laser transition around 1062.5 nm. Continuous-wave laser action is achieved with this bulk tellurite glass by pumping the sample inside a standard plan-concave mirror laser cavity with different output couplers. It is possible to observe coherent emission only for the lower concentration (0.5%(wt.) of Nd2 O3). Also laser action could only be observed for this sample with threshold pump power of 73 mW associated with a laser slope efficiency of 8% for an output coupler transmission of 4% indicating that TeO2-ZnO are potential materials for laser action. The results presented in this work together with those previously reported with higher concentration (1.0% (wt) of Nd2O3) determine the adequate Nd2O3 concentration for laser action and guide the correct experimental procedure for TeO2-ZnO glasses preparation.

Growth and Spectral Assessment of Yb3+-Doped KBaGd(MoO4)3 Crystal: A Candidate for Ultrashort Pulse and Tunable Lasers

PubMed Central

Yu, Yi; Huang, Yisheng; Zhang, Lizhen; Lin, Zhoubin; Wang, Guofu

2013-01-01

In order to explore new more powerful ultrashort pulse laser and tunable laser for diode-pumping, this paper reports the growth and spectral assessment of Yb3+-doped KBaGd(MoO4)3 crystal. An Yb3+:KBaGd(MoO4)3 crystal with dimensions of 50×40×9 mm3 was grown by the TSSG method from the K2Mo2O7 flux. The investigated spectral properties indicated that Yb3+:KBaGd(MoO4)3 crystal exhibits broad absorption and emission bands, except the large emission and gain cross-sections. This feature of the broad absorption and emission bands is not only suitable for the diode pumping, but also for the production of ultrashort pulses and tunability. Therefore, Yb3+:KBaGd(MoO4)3 crystal can be regarded as a candidate for the ultrashort pulse and tunable lasers. PMID:23349892

Growth and spectral assessment of Yb(3+)-doped KBaGd(MoO4)3 crystal: a candidate for ultrashort pulse and tunable lasers.

PubMed

Yu, Yi; Huang, Yisheng; Zhang, Lizhen; Lin, Zhoubin; Wang, Guofu

2013-01-01

In order to explore new more powerful ultrashort pulse laser and tunable laser for diode-pumping, this paper reports the growth and spectral assessment of Yb(3+)-doped KBaGd(MoO(4))(3) crystal. An Yb(3+):KBaGd(MoO(4))(3) crystal with dimensions of 50×40×9 mm(3) was grown by the TSSG method from the K(2)Mo(2)O(7) flux. The investigated spectral properties indicated that Yb(3+):KBaGd(MoO(4))(3) crystal exhibits broad absorption and emission bands, except the large emission and gain cross-sections. This feature of the broad absorption and emission bands is not only suitable for the diode pumping, but also for the production of ultrashort pulses and tunability. Therefore, Yb(3+):KBaGd(MoO(4))(3) crystal can be regarded as a candidate for the ultrashort pulse and tunable lasers.

Ultrashort hybrid metal-insulator plasmonic directional coupler.

PubMed

Noghani, Mahmoud Talafi; Samiei, Mohammad Hashem Vadjed

2013-11-01

An ultrashort plasmonic directional coupler based on the hybrid metal-insulator slab waveguide is proposed and analyzed at the telecommunication wavelength of 1550 nm. It is first analyzed using the supermode theory based on mode analysis via the transfer matrix method in the interaction region. Then the 2D model of the coupler, including transition arms, is analyzed using a commercial finite-element method simulator. The hybrid slab waveguide is composed of a metallic layer of silver and two dielectric layers of silica (SiO2) and silicon (Si). The coupler is optimized to have a minimum coupling length and to transfer maximum power considering the layer thicknesses as optimization variables. The resulting coupling length in the submicrometer region along with a noticeable power transfer efficiency are advantages of the proposed coupler compared to previously reported plasmonic couplers.

Sm-Nd and Rb-Sr Ages for MIL 05035: Implications for Surface and Mantle Sources

NASA Technical Reports Server (NTRS)

Nyquist, L. E.; Shih, C-Y.; Reese, Y. D.

2007-01-01

The Sm-Nd and Rb-Sr ages and also the initial Nd and Sr isotopic compositions of MIL 05035 are the same as those of A-881757. Comparing the radiometric ages of these meteorites to lunar surface ages as modeled from crater size-frequency distributions as well as the TiO2 abundances and initial Sr-isotopic compositions of other basalts places their likely place of origin as within the Australe or Humboldtianum basins. If so, a fundamental west-east lunar asymmetry in compositional and isotopic parameters that likely is due to the PKT is implied.

Coherent π-electron dynamics of (P)-2,2'-biphenol induced by ultrashort linearly polarized UV pulses: angular momentum and ring current.

PubMed

Mineo, H; Lin, S H; Fujimura, Y

2013-02-21

The results of a theoretical investigation of coherent π-electron dynamics for nonplanar (P)-2,2'-biphenol induced by ultrashort linearly polarized UV pulses are presented. Expressions for the time-dependent coherent angular momentum and ring current are derived by using the density matrix method. The time dependence of these coherences is determined by the off-diagonal density matrix element, which can be obtained by solving the coupled equations of motion of the electronic-state density matrix. Dephasing effects on coherent angular momentum and ring current are taken into account within the Markov approximation. The magnitudes of the electronic angular momentum and current are expressed as the sum of expectation values of the corresponding operators in the two phenol rings (L and R rings). Here, L (R) denotes the phenol ring in the left (right)-hand side of (P)-2,2'-biphenol. We define the bond current between the nearest neighbor carbon atoms Ci and Cj as an electric current through a half plane perpendicular to the Ci-Cj bond. The bond current can be expressed in terms of the inter-atomic bond current. The inter-atomic bond current (bond current) depends on the position of the half plane on the bond and has the maximum value at the center. The coherent ring current in each ring is defined by averaging over the bond currents. Since (P)-2,2'-biphenol is nonplanar, the resultant angular momentum is not one-dimensional. Simulations of the time-dependent coherent angular momentum and ring current of (P)-2,2'-biphenol excited by ultrashort linearly polarized UV pulses are carried out using the molecular parameters obtained by the time-dependent density functional theory (TD-DFT) method. Oscillatory behaviors in the time-dependent angular momentum (ring current), which can be called angular momentum (ring current) quantum beats, are classified by the symmetry of the coherent state, symmetric or antisymmetric. The bond current of the bridge bond linking the L and R

Fully phase-encoded MRI near metallic implants using ultrashort echo times and broadband excitation.

PubMed

Wiens, Curtis N; Artz, Nathan S; Jang, Hyungseok; McMillan, Alan B; Koch, Kevin M; Reeder, Scott B

2018-04-01

To develop a fully phase-encoded MRI method for distortion-free imaging near metallic implants, in clinically feasible acquisition times. An accelerated 3D fully phase-encoded acquisition with broadband excitation and ultrashort echo times is presented, which uses a broadband radiofrequency pulse to excite the entire off-resonance induced by the metallic implant. Furthermore, fully phase-encoded imaging is used to prevent distortions caused by frequency encoding, and to obtain ultrashort echo times for rapidly decaying signal. Phantom and in vivo acquisitions were used to describe the relationship among excitation bandwidth, signal loss near metallic implants, and T 1 weighting. Shorter radiofrequency pulses captured signal closer to the implant by improving spectral coverage and allowing shorter echo times, whereas longer pulses improved T 1 weighting through larger maximum attainable flip angles. Comparisons of fully phase-encoded acquisition with broadband excitation and ultrashort echo times to T 1 -weighted multi-acquisition with variable resonance image combination selective were performed in phantoms and subjects with metallic knee and hip prostheses. These acquisitions had similar contrast and acquisition efficiency. Accelerated fully phase-encoded acquisitions with ultrashort echo times and broadband excitation can generate distortion free images near metallic implants in clinically feasible acquisition times. Magn Reson Med 79:2156-2163, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.

Fully Phase-Encoded MRI Near Metallic Implants Using Ultrashort Echo Times and Broadband Excitation

PubMed Central

Wiens, Curtis N.; Artz, Nathan S.; Jang, Hyungseok; McMillan, Alan B.; Koch, Kevin M.; Reeder, Scott B.

2017-01-01

Purpose To develop a fully phase-encoded MRI method for distortion-free imaging near metallic implants, in clinically feasible acquisition times. Theory and Methods An accelerated 3D fully phase-encoded acquisition with broadband excitation and ultrashort echo times is presented, which uses a broadband radiofrequency pulse to excite the entire off-resonance induced by the metallic implant. Furthermore, fully phase-encoded imaging is used to prevent distortions caused by frequency encoding, and to obtain ultrashort echo times for rapidly decaying signal. Results Phantom and in vivo acquisitions were used to describe the relationship among excitation bandwidth, signal loss near metallic implants, and T1 weighting. Shorter radiofrequency pulses captured signal closer to the implant by improving spectral coverage and allowing shorter echo times, whereas longer pulses improved T1 weighting through larger maximum attainable flip angles. Comparisons of fully phase-encoded acquisition with broadband excitation and ultrashort echo times to T1-weighted multi-acquisition with variable resonance image combination selective were performed in phantoms and subjects with metallic knee and hip prostheses. These acquisitions had similar contrast and acquisition efficiency. Conclusions Accelerated fully phase-encoded acquisitions with ultrashort echo times and broadband excitation can generate distortion free images near metallic implants in clinically feasible acquisition times. Magn Reson Med 000:000–000, 2017. PMID:28833407

Collaborative study for the establishment of the 2(nd) International Standard for Bleomycin Complex A2/B2.

PubMed

Jorajuria, S; Raphalen, C; Dujardin, V; Daas, A

2015-01-01

Organization (WHO) International Standard (IS) for bleomycin complex A2/B2. Eight laboratories from different countries participated. Potencies of the candidate material were estimated by microbiological assays with sensitive micro-organisms. To ensure continuity between consecutive batches, the 1(st) IS for bleomycin complex A2/B2 was used as a reference. Based on the results of the study, the 2(nd) IS for bleomycin complex A2/B2 was adopted at the meeting of the WHO Expert Committee for Biological Standardization (ECBS) in 2014 with an assigned potency of 12 500 International Units (IU) per vial. The 2(nd) IS for bleomycin complex A2/B2 is available from the European Directorate for the Quality of Medicines & HealthCare (EDQM).

Magnetic and thermodynamic properties of Nd3NiGe2

NASA Astrophysics Data System (ADS)

Matsumoto, Keisuke T.; Hiraoka, Koichi

2018-05-01

We here report the magnetization, M, and specific heat, C, of Nd3NiGe2 , which crystallizes in the orthorhombic Gd3NiSi2 -type structure. Nd ions occupy three nonequivalent sites in a unit cell. Upon cooling, magnetization divided by magnetic field, M / B , increased sharply at the Curie temperature, TC, of 87 K and below 40 K. The former result indicates that the increase in M / B observed at TC is due to the long-range ferromagnetic order. The increase below 40 K is derived from a short-range correlation because of the absence of clear anomaly in C (T) . At 10 K and 2 K, the values of M undergo metamagnetic transitions. The value of magnetic specific heat divided by temperature shows a shoulder-like anomaly at around 20 K, which is attributed to antiferromagnetic behavior. Furthermore, two peaks in C (T) were observed at 4.5 K and 3.8 K, and these peaks occurred at lower temperatures in the presence of a magnetic field. This behavior is typical of materials with antiferromagnetic order. These observations are attributed to the competition between ferromagnetic and antiferromagnetic interactions, which is a result of the three nonequivalent Nd sites.

The development of ultrashort acting neuromuscular relaxant tropane derivatives.

PubMed

Gyermek, Laszlo; Lee, Chingmuh

2009-03-01

There is a need for neuromuscular relaxant (NMR) agents that are of the "nondepolarizing type" and produce rapidly developing and short-lasting skeletal muscle relaxation in anesthesiology. Many efforts have been directed to produce such agents. Our research focused on the design, synthesis, and evaluation of numerous "bisquaternary" derivatives of the cyclic aminoalkanes: tropane and granatane. Through systematic "steric structure-activity relationship" studies, we arrived at some new bisquaternary tropine and granatanol diesters, which in laboratory studies appeared to be the fastest and shortest acting NMRs recognized so far. Their ultrashort duration action-mechanism was, however, linked to the formation of nephrotoxic metabolites, precluding further development. Even so, we believe that the scientific information gained from more than a thousand such agents, will be useful toward developing the "ideal," ultrashort-acting NMR that could be clinically successful without the use of "reversing" agents, at least until "new biotechnology" may solve all problematic aspects of "transient" muscle relaxation.

Cavity Optical Pulse Extraction: ultra-short pulse generation as seeded Hawking radiation.

PubMed

Eilenberger, Falk; Kabakova, Irina V; de Sterke, C Martijn; Eggleton, Benjamin J; Pertsch, Thomas

2013-01-01

We show that light trapped in an optical cavity can be extracted from that cavity in an ultrashort burst by means of a trigger pulse. We find a simple analytic description of this process and show that while the extracted pulse inherits its pulse length from that of the trigger pulse, its wavelength can be completely different. Cavity Optical Pulse Extraction is thus well suited for the development of ultrashort laser sources in new wavelength ranges. We discuss similarities between this process and the generation of Hawking radiation at the optical analogue of an event horizon with extremely high Hawking temperature. Our analytic predictions are confirmed by thorough numerical simulations.

Crystal-field energy level analysis for Nd(3+) ions at the low symmetry C(1) site in [Nd(hfa)(4)(H(2)O)](N(C(2)H(5))(4)) single crystals.

PubMed

Mech, Agnieszka; Gajek, Zbigniew; Karbowiak, Mirosław; Rudowicz, Czesław

2008-09-24

Optical absorption measurements of Nd(3+) ions in single crystals of [Nd(hfa)(4)(H(2)O)](N(C(2)H(5))(4)) (hfa = hexafluoroacetyloacetonate), denoted Nd(hfa) for short, have been carried out at 4.2 and 298 K. This compound crystallizes in the monoclinic system (space group P 2(1)/n). Each Nd ion is coordinated to eight oxygen atoms that originate from the hexafluoroacetylacetonate ligands and one oxygen atom from the water molecule. A total of 85 experimental crystal-field (CF) energy levels arising from the Nd(3+) (4f(3)) electronic configuration were identified in the optical spectra and assigned. A three-step CF analysis was carried out in terms of a parametric Hamiltonian for the actual C(1) symmetry at the Nd(3+) ion sites. In the first step, a total of 27 CF parameters (CFPs) in the Wybourne notation B(kq), admissible by group theory, were determined in a preliminary fitting constrained by the angular overlap model predictions. The resulting CFP set was reduced to 24 specific independent CFPs using appropriate standardization transformations. Optimizations of the second-rank CFPs and extended scanning of the parameter space were employed in the second step to improve reliability of the CFP sets, which is rather a difficult task in the case of no site symmetry. Finally, seven free-ion parameters and 24 CFPs were freely varied, yielding an rms deviation between the calculated energy levels and the 85 observed ones of 11.1 cm(-1). Our approach also allows prediction of the energy levels of Nd(3+) ions that are hidden in the spectral range overlapping with strong ligand absorption, which is essential for understanding the inter-ionic energy transfer. The orientation of the axis system associated with the fitted CF parameters w.r.t. the crystallographic axes is established. The procedure adopted in our calculations may be considered as a general framework for analysis of CF levels of lanthanide ions at low (triclinic) symmetry sites.

New methods of generation of ultrashort laser pulses for ranging

NASA Technical Reports Server (NTRS)

Jelinkova, Helena; Hamal, Karel; Kubecek, V.; Prochazka, Ivan

1993-01-01

To reach the millimeter satellite laser ranging accuracy, the goal for nineties, new laser ranging techniques have to be applied. To increase the laser ranging precision, the application of the ultrashort laser pulses in connection with the new signal detection and processing techniques, is inevitable. The two wavelength laser ranging is one of the ways to measure the atmospheric dispersion to improve the existing atmospheric correction models and hence, to increase the overall system ranging accuracy to the desired value. We are presenting a review of several nonstandard techniques of ultrashort laser pulses generation, which may be utilized for laser ranging: compression of the nanosecond pulses using stimulated Brillouin and Raman backscattering; compression of the mode-locked pulses using Raman backscattering; passive mode-locking technique with nonlinear mirror; and passive mode-locking technique with the negative feedback.

Ablation enhancement of silicon by ultrashort double-pulse laser ablation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Xin; Shin, Yung C.

In this study, the ultrashort double-pulse ablation of silicon is investigated. An atomistic simulation model is developed to analyze the underlying physics. It is revealed that the double-pulse ablation could significantly increase the ablation rate of silicon, compared with the single pulse ablation with the same total pulse energy, which is totally different from the case of metals. In the long pulse delay range (over 1 ps), the enhancement is caused by the metallic transition of melted silicon with the corresponding absorption efficiency. At ultrashort pulse delay (below 1 ps), the enhancement is due to the electron excitation by the first pulse.more » The enhancement only occurs at low and moderate laser fluence. The ablation is suppressed at high fluence due to the strong plasma shielding effect.« less

Ultrashort megaelectronvolt positron beam generation based on laser-accelerated electrons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Tongjun; Shen, Baifei, E-mail: bfshen@mail.shcnc.ac.cn; Xu, Jiancai, E-mail: jcxu@siom.ac.cn

Experimental generation of ultrashort MeV positron beams with high intensity and high density using a compact laser-driven setup is reported. A high-density gas jet is employed experimentally to generate MeV electrons with high charge; thus, a charge-neutralized MeV positron beam with high density is obtained during laser-accelerated electrons irradiating high-Z solid targets. It is a novel electron–positron source for the study of laboratory astrophysics. Meanwhile, the MeV positron beam is pulsed with an ultrashort duration of tens of femtoseconds and has a high peak intensity of 7.8 × 10{sup 21} s{sup −1}, thus allows specific studies of fast kinetics in millimeter-thick materials withmore » a high time resolution and exhibits potential for applications in positron annihilation spectroscopy.« less

Nanopore formation in neuroblastoma cells following ultrashort electric pulse exposure

NASA Astrophysics Data System (ADS)

Roth, Caleb C.; Payne, Jason A.; Wilmink, Gerald J.; Ibey, Bennett L.

2011-03-01

Ultrashort or nanosecond electrical pulses (USEP) cause repairable damage to the plasma membranes of cells through formation of nanopores. These nanopores are able to pass small ions such as sodium, calcium, and potassium, but remain impermeable to larger molecules like trypan blue and propidium iodide. What remains uncertain is whether generation of nanopores by ultrashort electrical pulses can inhibit action potentials in excitable cells. In this paper, we explored the sensitivity of excitable cells to USEP using Calcium Green AM 1 ester fluorescence to measure calcium uptake indicative of nanopore formation in the plasma membrane. We determined the threshold for nanopore formation in neuroblastoma cells for three pulse parameters (amplitude, pulse width, and pulse number). Measurement of such thresholds will guide future studies to determine if USEP can inhibit action potentials without causing irreversible membrane damage.

Demagnetization of Nd 2Fe 14B, Pr 2Fe 14B, and Sm 2Co 17 Permanent Magnets in Spallation Irradiation Fields

DOE PAGES

Simos, Nikolaos; Ozaki, S.; Mokhov, N.; ...

2018-02-27

Prompted by the need for radiation-resistant permanent magnets for insertion devices (IDs) of high-brilliance next-generation synchrotrons such as the National Synchrotron Light Source II, the demagnetization of Nd 2Fe 14B and Pr 2Fe 14B was studied after exposure to a mixed irradiating field. Degradation and damage of the permanent magnetic material by components of electromagnetic showers induced in magnets by intense high-energy electron beams will alter the magnetic field structure of the IDs. Plate-like Nd 2Fe 14B magnets were irradiated to 1.8 Grad dose and were evaluated against Pr 2Fe 14B magnets irradiated to a lower dose of 20 Mrad.more » In addition, annular Sm 2Co 17 and Nd 2Fe 14B magnets integrated within a ferrofluidic feedthrough (FFFT) rotary seal were also irradiated to dose levels of 2 Grad for Sm 2Co 17 and 20 Mrad for Nd 2Fe 14B. Post-irradiation measurements of the magnetic intensity revealed that severe demagnetization exceeding 85% occurs in Nd 2Fe 14B magnets after only 50 Mrad dose and over 87% for Pr 2Fe 14B after 10 Mrad dose. The annular-shaped Sm 2Co 17 magnets of the FFFTs were almost insensitive to irradiation up to a dose of 2 Grad. Annular-shaped Nd 2Fe 14B magnets also showed resistance to demagnetization, a direct consequence of the annular shape which is characterized by the removal of the stronger demagnetizing field present at the center of a disk-like magnet. As a result, the sensitivity of boron-based permanent magnets to neutron energy (thermal versus fast) was also assessed via specifically designed experiments and discussed.« less

Demagnetization of Nd 2Fe 14B, Pr 2Fe 14B, and Sm 2Co 17 Permanent Magnets in Spallation Irradiation Fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simos, Nikolaos; Ozaki, S.; Mokhov, N.

Prompted by the need for radiation-resistant permanent magnets for insertion devices (IDs) of high-brilliance next-generation synchrotrons such as the National Synchrotron Light Source II, the demagnetization of Nd 2Fe 14B and Pr 2Fe 14B was studied after exposure to a mixed irradiating field. Degradation and damage of the permanent magnetic material by components of electromagnetic showers induced in magnets by intense high-energy electron beams will alter the magnetic field structure of the IDs. Plate-like Nd 2Fe 14B magnets were irradiated to 1.8 Grad dose and were evaluated against Pr 2Fe 14B magnets irradiated to a lower dose of 20 Mrad.more » In addition, annular Sm 2Co 17 and Nd 2Fe 14B magnets integrated within a ferrofluidic feedthrough (FFFT) rotary seal were also irradiated to dose levels of 2 Grad for Sm 2Co 17 and 20 Mrad for Nd 2Fe 14B. Post-irradiation measurements of the magnetic intensity revealed that severe demagnetization exceeding 85% occurs in Nd 2Fe 14B magnets after only 50 Mrad dose and over 87% for Pr 2Fe 14B after 10 Mrad dose. The annular-shaped Sm 2Co 17 magnets of the FFFTs were almost insensitive to irradiation up to a dose of 2 Grad. Annular-shaped Nd 2Fe 14B magnets also showed resistance to demagnetization, a direct consequence of the annular shape which is characterized by the removal of the stronger demagnetizing field present at the center of a disk-like magnet. As a result, the sensitivity of boron-based permanent magnets to neutron energy (thermal versus fast) was also assessed via specifically designed experiments and discussed.« less

Randomized, Controlled Trial of Fractional Carbon Dioxide Laser Resurfacing Followed by Ultrashort Incubation Aminolevulinic Acid Blue Light Photodynamic Therapy for Actinic Keratosis.

PubMed

Alexiades, Macrene

2017-08-01

Aminolevulinic acid (ALA) photodynamic therapy (PDT) is an established treatment option for actinic keratosis (AK), and recently fractional carbon dioxide (CO2) laser was shown to improve outcomes; but studies of short incubation photosensitizer are lacking. Assess the efficacy of short incubation ALA followed by blue light PDT with and without previous fractional CO2 treatment for the treatment of AK. Randomized, paired split-design, controlled trial of fractional CO2 followed by ultrashort 15-minute versus 30-minute incubation ALA and blue light PDT for the treatment of AK on the face. The complete clearance rates (CRs) at 8 weeks after ALA PDT with and without FxCO2 at 30- and 15-minute ALA incubation times were 89.78% (+FxCO2) versus 71.20% CR (-FxCO2) at 30', and 86.38% (+FxCO2) versus 69.23% (-FxCO2) at 15' ALA incubation. All lesion improvements were statistically significant. This randomized, comparative paired group controlled clinical study demonstrates that ultrashort 15- and 30-minute incubation ALA PDTs are of limited efficacy for the treatment of AK. Pretreatment with fractional ablative resurfacing yields statistically significant greater AK clearance with ALA-PDT at ultrashort ALA incubations followed by blue light.

Four-wave-mixing and nonlinear cavity dumping of 280 picosecond 2nd Stokes pulse at 1.3 μm from Nd:SrMoO4 self-Raman laser

NASA Astrophysics Data System (ADS)

Smetanin, S. N.; Jelínek, M., Jr.; Kubeček, V.; Jelínková, H.; Ivleva, L. I.; Shurygin, A. S.

2016-01-01

The 280 picosecond 2nd Stokes Raman pulses at 1.3 μm were generated directly from the miniature diode-pumped Nd:SrMoO4 self-Raman laser. Using the 90° phase matching insensitive to the angular mismatch, the self-Raman laser allowed for the achievement of the four-wave-mixing generation of the 2nd Stokes Raman pulse directly in the active Nd:SrMoO4 crystal at stimulated Raman scattering (SRS) self-conversion of the laser radiation. The passive Cr:YAG Q-switching and nonlinear cavity dumping was used without any phase locking device.

Anomalous magnetoelastic behaviour near morphotropic phase boundary in ferromagnetic Tb 1-xNd xCo 2 system

DOE PAGES

Murtaza, Adil; Yang, Sen; Zhou, Chao; ...

2016-08-04

In this study, we report a morphotropic phase boundary (MPB) involved ferromagnetic system Tb 1-xNd xCo 2 and reveal the corresponding structural and magnetoelastic properties of this system. With high resolution synchrotron X-ray diffractometry, the crystal structure of the TbCo 2-rich side is detected to be rhombohedral and that of NdCo 2-rich side is tetragonal below their respective Curie temperatures TC. The MPB composition Tb 0.35Nd 0.65Co 2 corresponds to the coexistence of the rhombohedral phase (R-phase) and tetragonal phase ( T-phase). Contrary to previously reported MPB involved ferromagnetic systems, the MPB composition of Tb 0.35Nd 0.65Co 2 shows minimummore » magnetization which can be understood as compensation of sublattice moments between the R-phase and the T-phase. Furthermore, magnetostriction of Tb 1-xNd xCo 2 decreases with increasing Nd concentration until x = 0.8 and then increases in the negative direction with further increasing Nd concentration; the optimum point for magnetoelastic properties lies towards the rhombohedral phase. Finally, our work not only shows an anomalous type of ferromagnetic MPB but also provides an effective way to design functional materials.« less

Nd2-xCexCuO4-y/Nd2-xCexOy boundary and resistive switchings in mesoscopic structures on base of epitaxial Nd1.86Ce0.14CuO4-у films

NASA Astrophysics Data System (ADS)

Tulina, N. A.; Rossolenko, A. N.; Ivanov, A. A.; Sirotkin, V. V.; Shmytko, I. M.; Borisenko, I. Yu.; Ionov, A. M.

2016-08-01

Reverse and stable bipolar resistive switching effect (BRSE) was observed in planar Nd2-xCex CuO4-y/Nd2-xCexOx/Ag heterostructure. It was shown that the СVС of the BRSE observed has a diode character. Simulations were used to consider the influence of the nonuniform distribution of an electric field at the interface of a heterojunction on the effect of bipolar resistive switching in investigated structures. The inhomogeneous distribution of the electric field near the contact edge creates regions of higher electric field strength which, in turn, stimulates motion and redistribution of defects, changes of the resistive properties of the whole structure and formation of a percolation channel.

An ultrashort throw ratio projection lens design based on a catadioptric structure

NASA Astrophysics Data System (ADS)

Wang, Hsiu-Cheng; Pan, Jui-Wen

2018-07-01

In this paper, we present a rotational symmetry for an ultrashort throw (UST) lens with offset field. The UST lens has a throw ratio of 0.23 and a total track of 195 mm. The optical elements of the UST lens are comprised of two parts. First, a catadioptric projection lens where the catadioptric function permits reaching an ultrashort throw ratio, short total track, while at the same time requiring fewer lens elements. The second part is a collimating lens which takes advantage of the telecentric condition to generate uniform total internal reflection (TIR) in the TIR prism. With this design, an effective focal length of -1.96 mm and a f-number of 2.4 can be obtained. The root mean square spot size and lateral colour of all fields are smaller than one pixel in size. The maximum optical distortion of -0.97% and TV distortion of 0.2% are acceptable. In terms of image quality, the modulation transfer function (MTF) values for all fields are above 0.65 at 0.245 line pairs/mm. Even when the tolerance error is considered, the MTF values for all fields are still above 0.3. The suitability of the novel UST lens design for projection applications is discussed.

Spatiotemporal characterization of ultrashort optical vortex pulses

NASA Astrophysics Data System (ADS)

Miranda, Miguel; Kotur, Marija; Rudawski, Piotr; Guo, Chen; Harth, Anne; L'Huillier, Anne; Arnold, Cord L.

2017-12-01

We use a spiral phase plate to generate few-cycle optical vortices from an ultrafast titanium:sapphire oscillator and characterize them in the spatiotemporal domain with a recently introduced technique based on spatially resolved Fourier transform spectrometry. The performance of this simple approach to the generation of optical vortices is analysed from a wavelength-dependent perspective as well as in the spatiotemporal domain, allowing us to characterize ultrashort vortex pulses in space, frequency and time.

Development of a Hydrologic Characterization Technology for Fault Zones Phase II 2nd Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karasaki, Kenzi; Doughty, Christine; Gasperikova, Erika

2011-03-31

This is the 2nd report on the three-year program of the 2nd phase of the NUMO-LBNL collaborative project: Development of Hydrologic Characterization Technology for Fault Zones under NUMO-DOE/LBNL collaboration agreement. As such, this report is a compendium of the results by Kiho et al. (2011) and those by LBNL.

Phase equilibria and crystal chemistry of the CaO-1/2 >Nd2O3-CoOz system at 885 °C in air

NASA Astrophysics Data System (ADS)

Wong-Ng, W.; Laws, W.; Talley, K. R.; Huang, Q.; Yan, Y.; Martin, J.; Kaduk, J. A.

2014-07-01

The phase diagram of the CaO-1/2 >Nd2O3-CoOz system at 885 °C in air has been determined. The system consists of two calcium cobaltate compounds that have promising thermoelectric properties, namely, the 2D thermoelectric oxide solid solution, (Ca3-xNdx)Co4O9-z (0≤x≤0.5), which has a misfit layered structure, and Ca3Co2O6 which consists of 1D chains of alternating CoO6 trigonal prisms and CoO6 octahedra. Ca3Co2O6 was found to be a point compound without the substitution of Nd on the Ca site. The reported Nd2CoO4 phase was not observed at 885 °C. A ternary (Ca1-xNd1+x)CoO4-z (x=0) phase, or (CaNdCo)O4-z, was found to be stable at this temperature. A solid solution region of distorted perovskite (Nd1-xCax)CoO3-z (0≤x≤0.25, space group Pnma) was established. In the peripheral binary systems, while a solid solution region was identified for (Nd1-xCax)2O3-z (0≤x≤0.2), Nd was not found to substitute in the Ca site of CaO. Six solid solution tie-line regions and six three-phase regions were determined in the CaO-Nd2O3-CoOz system in air.

Multi-wavelength Yb:YAG/Nd³⁺:YVO₄ continuous-wave microchip Raman laser.

PubMed

Wang, Xiao-Lei; Dong, Jun; Wang, Xiao-Jie; Xu, Jie; Ueda, Ken-Ichi; Kaminskii, Alexander A

2016-08-01

Multi-wavelength continuous-wave (CW) Raman lasers in a laser diode pumped Yb:YAG/Nd³⁺:YVO₄ microchip Raman laser have been demonstrated for the first time to our best knowledge. The multi-wavelength laser of the first Stokes radiation around 1.08 μm has been achieved with a Raman shift of 261  cm^-1 for a-cut Nd:YVO₄ crystal corresponding to the fundamental wavelength at 1.05 μm. Multi-wavelength laser operation simultaneously around 1.05 and 1.08 μm has been achieved under the incident pump power between 1.5 and 1.7 W. Multi-wavelength Raman laser with frequency separation of 1 THz around 1.08 μm has been obtained when the incident pump power is higher than 1.7 W. The maximum Raman laser output power of 260 mW at 1.08 μm is obtained and the corresponding optical-to-optical conversion efficiency is 4.2%. Elliptically polarized fundamental laser and linearly polarized Raman laser were observed in an Yb:YAG/Nd:YVO₄ CW microchip Raman laser. The experimental results of linearly polarized, multi-wavelength Yb:YAG/Nd:YVO₄ CW microchip Raman laser with adjustable frequency separation provide a novel approach for developing potential compact laser sources for Terahertz generation.

2ND FLOOR HALLWAY LOOKING EAST, NOTE PRESSED TIN CEILING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2ND FLOOR HALLWAY LOOKING EAST, NOTE PRESSED TIN CEILING - New York State Soldiers & Sailors Home, Building No. 29, Department of Veterans Affairs Medical Center, 76 Veterans Avenue, Bath, Steuben County, NY

Coercivity enhancement of Nd-Fe-B hot-deformed magnets by the eutectic grain boundary diffusion process using Nd-Ga-Cu and Nd-Fe-Ga-Cu alloys

NASA Astrophysics Data System (ADS)

Liu, Lihua; Sepehri-Amin, H.; Sasaki, T. T.; Ohkubo, T.; Yano, M.; Sakuma, N.; Kato, A.; Shoji, T.; Hono, K.

2018-05-01

Nd80Ga15Cu5 and Nd62Fe14Ga20Cu4 alloys were used as diffusion sources for the eutectic grain boundary diffusion process, applying to 4 mm-thick Nd-Fe-B hot-deformed magnets. Both samples showed nearly same coercivity of 2.2 T, while the sample processed with Nd62Fe14Ga20Cu4 showed smaller remanence deterioration from 1.50 T to 1.30 T, in contrast to that of the sample processed with Nd80Ga15Cu5 to 1.08 T. Mr/Ms of the initial sample and the samples processed with Nd62Fe14Ga20Cu4 and Nd80Ga15Cu5 were 0.946, 0.934 and 0.917, respectively, suggesting that the sample processed with Nd62Fe14Ga20Cu4 retains stronger c-axis texture after the diffusion process. Nd-rich phases with Ia3 ¯ and fcc structures were observed in the sample processed with Nd80Ga15Cu5, while the Nd-rich phases with the Ia3 ¯ and hcp structures were found in the sample processed with Nd62Fe14Ga20Cu4, all of which are the phases commonly observed in Nd-Fe-B sintered magnets.

Mode-locking peculiarities in an all-fiber erbium-doped ring ultrashort pulse laser with a highly-nonlinear resonator

NASA Astrophysics Data System (ADS)

Dvoretskiy, Dmitriy A.; Sazonkin, Stanislav G.; Kudelin, Igor S.; Orekhov, Ilya O.; Pnev, Alexey B.; Karasik, Valeriy E.; Denisov, Lev K.

2017-12-01

Today ultrashort pulse (USP) fiber lasers are in great demand in a frequency metrology field, THz pulse spectroscopy, optical communication, quantum optics application, etc. Therefore mode-locked (ML) fiber lasers have been extensively investigated over the last decade due the number of scientific, medical and industrial applications. It should be noted, that USP fiber lasers can be treated as an ideal platform to expand future applications due to the complex ML nonlinear dynamics in a laser resonator. Up to now a series of novel ML regimes have been investigated e.g. self-similar pulses, noise-like pulses, multi-bound solitons and soliton rain generation. Recently, we have used a highly nonlinear germanosilicate fiber (with germanium oxides concentration in the core 50 mol. %) inside the resonator for more reliable and robust launching of passive mode-locking based on the nonlinear polarization evolution effect in fibers. In this work we have measured promising and stable ML regimes such as stretched pulses, soliton rain and multi-bound solitons formed in a highly-nonlinear ring laser and obtained by intracavity group velocity dispersion (GVD) variation in slightly negative region. As a result, we have obtained the low noise ultrashort pulse generation with duration < 250 fs (more than 20 bound pulses when obtained multi-bound soliton generation with intertemporal width 5 ps) at a repetition rate 11.3 MHz (with signal-to-noise ratio at fundamental frequency > 59 dB) and relative intensity noise <-101 dBc / Hz.

Cavity Optical Pulse Extraction: ultra-short pulse generation as seeded Hawking radiation

PubMed Central

Eilenberger, Falk; Kabakova, Irina V.; de Sterke, C. Martijn; Eggleton, Benjamin J.; Pertsch, Thomas

2013-01-01

We show that light trapped in an optical cavity can be extracted from that cavity in an ultrashort burst by means of a trigger pulse. We find a simple analytic description of this process and show that while the extracted pulse inherits its pulse length from that of the trigger pulse, its wavelength can be completely different. Cavity Optical Pulse Extraction is thus well suited for the development of ultrashort laser sources in new wavelength ranges. We discuss similarities between this process and the generation of Hawking radiation at the optical analogue of an event horizon with extremely high Hawking temperature. Our analytic predictions are confirmed by thorough numerical simulations. PMID:24060831

Crystal-field energy level analysis for Nd3+ ions at the low symmetry C1 site in [Nd(hfa)4(H2O)](N(C2H5)4) single crystals

NASA Astrophysics Data System (ADS)

Mech, Agnieszka; Gajek, Zbigniew; Karbowiak, Mirosław; Rudowicz, Czesław

2008-09-01

Optical absorption measurements of Nd3+ ions in single crystals of [Nd(hfa)4(H2O)](N(C2H5)4) (hfa = hexafluoroacetyloacetonate), denoted Nd(hfa) for short, have been carried out at 4.2 and 298 K. This compound crystallizes in the monoclinic system (space group P 21/n). Each Nd ion is coordinated to eight oxygen atoms that originate from the hexafluoroacetylacetonate ligands and one oxygen atom from the water molecule. A total of 85 experimental crystal-field (CF) energy levels arising from the Nd3+ (4f3) electronic configuration were identified in the optical spectra and assigned. A three-step CF analysis was carried out in terms of a parametric Hamiltonian for the actual C1 symmetry at the Nd3+ ion sites. In the first step, a total of 27 CF parameters (CFPs) in the Wybourne notation Bkq, admissible by group theory, were determined in a preliminary fitting constrained by the angular overlap model predictions. The resulting CFP set was reduced to 24 specific independent CFPs using appropriate standardization transformations. Optimizations of the second-rank CFPs and extended scanning of the parameter space were employed in the second step to improve reliability of the CFP sets, which is rather a difficult task in the case of no site symmetry. Finally, seven free-ion parameters and 24 CFPs were freely varied, yielding an rms deviation between the calculated energy levels and the 85 observed ones of 11.1 cm-1. Our approach also allows prediction of the energy levels of Nd3+ ions that are hidden in the spectral range overlapping with strong ligand absorption, which is essential for understanding the inter-ionic energy transfer. The orientation of the axis system associated with the fitted CF parameters w.r.t. the crystallographic axes is established. The procedure adopted in our calculations may be considered as a general framework for analysis of CF levels of lanthanide ions at low (triclinic) symmetry sites.

Numerical calculation of nonlinear ultrashort laser pulse propagation in transparent Kerr media

NASA Astrophysics Data System (ADS)

Arnold, Cord L.; Heisterkamp, Alexander; Ertmer, Wolfgang; Lubatschowski, Holger

2005-03-01

In the focal region of tightly focused ultrashort laser pulses, sufficient high intensities to initialize nonlinear ionization processes are easily achieved. Due to these nonlinear ionization processes, mainly multiphoton ionization and cascade ionization, free electrons are generated in the focus resulting in optical breakdown. A model including both nonlinear pulse propagation and plasma generation is used to calculate numerically the interaction of ultrashort pulses with their self-induced plasma in the vicinity of the focus. The model is based on a (3+1)-dimensional nonlinear Schroedinger equation describing the pulse propagation coupled to a system of rate equations covering the generation of free electrons. It is applicable to any transparent Kerr medium, whose linear and nonlinear optical parameters are known. Numerical calculations based on this model are used to understand nonlinear side effects, such as streak formation, occurring in addition to optical breakdown during short pulse refractive eye surgeries like fs-LASIK. Since the optical parameters of water are a good first-order approximation to those of corneal tissue, water is used as model substance. The free electron density distribution induced by focused ultrashort pulses as well as the pulses spatio-temporal behavior are studied in the low-power regime around the critical power for self-focusing.

Nd:YAG-CO(2) double-pulse laser induced breakdown spectroscopy of organic films.

PubMed

Weidman, Matthew; Baudelet, Matthieu; Palanco, Santiago; Sigman, Michael; Dagdigian, Paul J; Richardson, Martin

2010-01-04

Laser-induced breakdown spectroscopy (LIBS) using double-pulse irradiation with Nd:YAG and CO(2) lasers was applied to the analysis of a polystyrene film on a silicon substrate. An enhanced emission signal, compared to single-pulse LIBS using a Nd:YAG laser, was observed from atomic carbon, as well as enhanced molecular emission from C(2) and CN. This double-pulse technique was further applied to 2,4,6-trinitrotoluene residues, and enhanced LIBS signals for both atomic carbon and molecular CN emission were observed; however, no molecular C(2) emission was detected.

Single-pass, efficient type-I phase-matched frequency doubling of high-power ultrashort-pulse Yb-fiber laser using LiB_3O_5

NASA Astrophysics Data System (ADS)

Shukla, Mukesh Kumar; Kumar, Samir; Das, Ritwick

2016-05-01

We report 48 % efficient single-pass second harmonic generation of high-power ultrashort-pulse ({≈ }250 fs) Yb-fiber laser by utilizing type-I phase matching in LiB_3O_5 (LBO) crystal. The choice of LBO among other borate crystals for high-power frequency doubling is essentially motivated by large thermal conductivity, low birefringence and weak group velocity dispersion. By optimally focussing the beam in a 4-mm-long LBO crystal, we have generated about 2.3 W of average power at 532 nm using 4.8 W of available pump power at 1064 nm. The ultrashort green pulses were found out to be near-transform limited sech^2 pulses with a pulse width of Δ τ ≈ 150 fs and being delivered at 78 MHz repetition rate. Due to appreciably low spatial walk-off angle for LBO ({≈ }0.4°), we obtain M^2<1.26 for the SH beam which signifies marginal distortion in comparison with the pump beam (M^2<1.15). We also discuss the impact of third-order optical nonlinearity of the LBO crystal on the generated ultrashort SH pulses.

Ultrashort soliton switching based on coherent energy hiding.

PubMed

Romagnoli, M; Wabnitz, S; Zoccolotti, L

1991-08-15

Coherent coupling between light and atoms may be exploited for conceiving a novel class of all-optical signalprocessing devices without a direct counterpart in the continuous-wave regime. We show that the self-switching of ultrashort soliton pulses on resonance with a transition of doping centers in a slab waveguide directional coupler is based on nonlinear group-velocity (instead of the usual phase-velocity) changes.

Interfacial magnetic coupling in hetero-structure of Fe/double-perovskite NdBaMn2O6 single crystal

NASA Astrophysics Data System (ADS)

Lin, W. C.; Tsai, C. L.; Ogawa, K.; Yamada, S.; Gandhi, Ashish C.; Lin, J. G.

2018-04-01

The interfacial magnetic coupling between metallic Fe and the double-perovskite NdBaMn2O6 single crystal was investigated in the heterostructure of 4-nm Pd/10-nm Fe/NdBaMn2O6. A considerable magnetic coupling effect was observed in the temperature range coincident with the magnetic phase transition of NdBaMn2O6. When the temperature was elevated above 270 K, NdBaMn2O6 transformed from a state of antiferromagnetic fluctuating domains to a superparamagnetism-like (ferromagnetic fluctuation) state with high magnetic susceptibility. Concurrently, the interfacial magnetic coupling between the Fe layer and the NdBaMn2O6 crystal was observed, as indicated by the considerable squareness reduction and coercivity enhancement in the Fe layer. Moreover, the presence of the Fe layer changed the magnetic structure of NdBaMn2O6 from conventional 4-fold symmetry to 2-fold symmetry. These observations offer applicable insights into the mutual magnetic interaction in the heterostructures of metallic ferromagnetism/perovskite materials.

Nd3+-doped TeO2-Bi2O3-ZnO transparent glass ceramics for laser application at 1.06 μm

NASA Astrophysics Data System (ADS)

Hu, Xiaolin; Luo, Zhiwei; Liu, Taoyong; Lu, Anxian

2017-04-01

The high crystallinity transparent glass ceramics based on Nd3+-doped 70TeO2-15Bi2O3-15ZnO (TBZ) compositions were successfully prepared by two-step heat treatment process. The effects of Nd2O3 content on the thermal, structural, mechanical, and optical properties of TBZ glass ceramics were studied. The incorporation of Nd2O3 enhanced the crystallization tendency in the matrix glass composition. The crystal phase and morphology of Bi2Te4O11 in the glass ceramics were confirmed by X-ray diffraction and field emission scanning electron microscopy. Due to precipitate more crystal phase, the hardness values increased from 3.21 to 3.66 GPa. Eight absorption peaks were observed from 400 to 900 nm and three emission bands appeared in the range of 850-1400 nm. With the increasing of Nd2O3 content from 0.5 to 2.5 wt%, the intensity of absorption peaks enhanced and the emission intensity increased up to 1.0 wt% and then fell down for further dopant concentration. The fluorescence decay lifetime decreased rapidly starting from 1.5 wt% Nd2O3 content due to the obvious energy migration among Nd3+. According to the extreme strong emission band around 1062 nm and the optimum Nd2O3 content (1.0 wt%), N10 glass ceramic was considered as a potential material for 1.06 μm laser applications.

Effect of Stretching Combined With Ultrashort Wave Diathermy on Joint Function and Its Possible Mechanism in a Rabbit Knee Contracture Model.

PubMed

Zhang, Quan Bing; Zhou, Yun; Zhong, Hua Zhang; Liu, Yi

2018-05-01

The aim of this study was to investigate the therapeutic effect of stretching combined with ultrashort wave on joint contracture and explore its possible mechanism. Thirty-two rabbits underwent unilateral immobilization of a knee joint at full extension to cause joint contracture. At 6 wks after immobilization, the rabbits were randomly divided into the following four groups: natural recovery group, stretching treatment group, ultrashort wave treatment group, and combined treatment group. For comparison, eight control group animals of corresponding age were also examined. The effect of stretching and ultrashort wave treatment on joint contracture was assessed by measuring the joint range of motion, evaluating the collagen deposition of joint capsule and assessing the mRNA and protein levels for transforming growth factor β1 in the joint capsule. The combined treatment group led to the best recovery of joint function. The combined treatment with stretching and ultrashort wave was more effective than stretching or ultrashort wave treatment alone against the synovial thickening of suprapatellar joint capsule, the collagen deposition of anterior joint capsule, and the elevated expression of transforming growth factor β1 in the joint capsule. Stretching combined with ultrashort wave treatment was effective in improving joint range of motion, reducing the biomechanical, histological, and molecular manifestations of joint capsule fibrosis in a rabbit model of extending joint contracture.

The relationship between perceived physical competence and fundamental motor skills in preschool children.

PubMed

Robinson, Leah E

2011-07-01

The purpose of this investigation had two folds. First, it aimed to discover the relationship between perceived physical competence and fundamental motor skills in preschoolers. Secondly, it examined the effect of sex on perceived physical competence and fundamental motor skills within the sample. A total of 119 children (mean age 4.00, SD 0.55 years) participated in this study. The Test of Gross Motor Development--2nd Edition was used to assess fundamental motor skills and the Pictorial Scale of Perceived Competence and Social Acceptance was used to assess perceived physical competence. The results show a moderate and significant correlation between perceived physical competence and fundamental motor skills. Sex differences were also found with boys demonstrating more proficient motor skills and reporting higher perceived physical competence compared with girls. The findings provide relevant information to the child development literature and suggest that a positive relationship exist between preschoolers' self-perceptions of the physical ability and fundamental motor skills. © 2010 Blackwell Publishing Ltd.

Generation of ultrashort pulses with minimum duration of 90\\ {\\text{fs}} in a hybrid mode-locked erbium-doped all-fibre ring laser

NASA Astrophysics Data System (ADS)

Dvoretskiy, D. A.; Sazonkin, S. G.; Voropaev, V. S.; Negin, M. A.; Leonov, S. O.; Pnev, A. B.; Karasik, V. E.; Denisov, L. K.; Krylov, A. A.; Davydov, V. A.; Obraztsova, E. D.

2016-11-01

Regimes of ultrashort pulse generation in an erbium-doped all-fibre ring laser with hybrid mode locking based on single-wall carbon - boron nitride nanotubes and the nonlinear Kerr effect in fibre waveguides are studied. Stable dechirped ultrashort pulses are obtained with a duration of ˜ 90 {\\text{fs}}, a repetition rate of ˜ 42.2 {\\text{MHz}}, and an average output power of ˜ 16.7 {\\text{mW}}, which corresponds to a pulse energy of ˜ 0.4 {\\text{nJ}} and a peak laser power of ˜ 4.4 {\\text{kW}}.

Coherent π-electron dynamics of (P)-2,2'-biphenol induced by ultrashort linearly polarized UV pulses: Angular momentum and ring current

NASA Astrophysics Data System (ADS)

Mineo, H.; Lin, S. H.; Fujimura, Y.

2013-02-01

The results of a theoretical investigation of coherent π-electron dynamics for nonplanar (P)-2,2'-biphenol induced by ultrashort linearly polarized UV pulses are presented. Expressions for the time-dependent coherent angular momentum and ring current are derived by using the density matrix method. The time dependence of these coherences is determined by the off-diagonal density matrix element, which can be obtained by solving the coupled equations of motion of the electronic-state density matrix. Dephasing effects on coherent angular momentum and ring current are taken into account within the Markov approximation. The magnitudes of the electronic angular momentum and current are expressed as the sum of expectation values of the corresponding operators in the two phenol rings (L and R rings). Here, L (R) denotes the phenol ring in the left (right)-hand side of (P)-2,2'-biphenol. We define the bond current between the nearest neighbor carbon atoms Ci and Cj as an electric current through a half plane perpendicular to the Ci-Cj bond. The bond current can be expressed in terms of the inter-atomic bond current. The inter-atomic bond current (bond current) depends on the position of the half plane on the bond and has the maximum value at the center. The coherent ring current in each ring is defined by averaging over the bond currents. Since (P)-2,2'-biphenol is nonplanar, the resultant angular momentum is not one-dimensional. Simulations of the time-dependent coherent angular momentum and ring current of (P)-2,2'-biphenol excited by ultrashort linearly polarized UV pulses are carried out using the molecular parameters obtained by the time-dependent density functional theory (TD-DFT) method. Oscillatory behaviors in the time-dependent angular momentum (ring current), which can be called angular momentum (ring current) quantum beats, are classified by the symmetry of the coherent state, symmetric or antisymmetric. The bond current of the bridge bond linking the L and R

Study on magnetic properties of (Nd0.8Ce0.2)2-xFe12Co2B (x = 0-0.6) alloys

NASA Astrophysics Data System (ADS)

Tan, G. S.; Xu, H.; Yu, L. Y.; Tan, X. H.; Zhang, Q.; Gu, Y.; Hou, X. L.

2017-09-01

In the present work, (Nd0.8Ce0.2)2-xFe12Co2B (x = 0-0.6) permanent alloys are prepared by melt-spinning method. The hard magnetic properties of (Nd0.8Ce0.2)2-xFe12Co2B (x = 0-0.6) alloys annealed at optimum temperatures have been investigated systematically. Depending on the Nd, Ce concentration, the maximum energy product ((BH)max) and remanence (Br) increase gradually with x in the range of 0 ≤ x ≤ 0.4, whereas decrease gradually in the alloys with 0.4 < x ≤ 0.6. It is found that the optimum magnetic properties are obtained at x = 0.4: Hci = 4.9 kOe, Br = 10.1 kG, (BH)max = 13.7 MGOe. Specifically, magnetic field heat treatment below the Curie temperature is applied for (Nd0.8Ce0.2)1.6Fe12Co2B (x = 0.4) annealed ribbons. The magnetic properties Br, (BH)max and squareness are all enhanced after the magnetic field heat treatment. The (BH)max shows a substantial increase from 13.7 MGOe to 16.0 MGOe after the heat treatment at 623 K with a magnetic field of 1 T, which gets 17% improvement compared with that of the sample without a magnetic field heat treatment. We demonstrate that the magnetic field heat treatment plays a certain role in the magnetization reversal behavior and can improve the microstructure of (Nd0.8Ce0.2)1.6Fe12Co2B alloy.

Collapse of ultrashort spatiotemporal pulses described by the cubic generalized Kadomtsev-Petviashvili equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leblond, Herve; Kremer, David; Mihalache, Dumitru

2010-03-15

By using a reductive perturbation method, we derive from Maxwell-Bloch equations a cubic generalized Kadomtsev-Petviashvili equation for ultrashort spatiotemporal optical pulse propagation in cubic (Kerr-like) media without the use of the slowly varying envelope approximation. We calculate the collapse threshold for the propagation of few-cycle spatiotemporal pulses described by the generic cubic generalized Kadomtsev-Petviashvili equation by a direct numerical method and compare it to analytic results based on a rigorous virial theorem. Besides, typical evolution of the spectrum (integrated over the transverse spatial coordinate) is given and a strongly asymmetric spectral broadening of ultrashort spatiotemporal pulses during collapse is evidenced.

Ultra-high precision 142Nd/144Nd measurements of the Proterozoic and implications for mixing in the Earth's mantle through time

NASA Astrophysics Data System (ADS)

Hyung, E.; Jacobsen, S. B.

2017-12-01

The decay of 146Sm to 142Nd is an excellent a tracer for early silicate differentiation events in the terrestrial planets, as the Sm/Nd ratio is usually fractionated during mantle partial melting and magma ocean crystallization. The short half-life (103 or 68 Ma) renders the system extinct within the first 500 Ma of Solar System formation. Samples with 142Nd/144Nd ratios that are substantially different from the bulk silicate Earth value of 142Nd/144Nd provide clear evidence for mantle differentiation in the Hadean. Published data for the 3.4 to 3.8 Ga old Isua supracrustal rocks and dykes have demonstrated both positive and negative 142Nd/144Nd anomalies (30 ppm range) providing clear evidence for Hadean enriched and depleted mantle reservoirs. In contrast, no 142Nd/144Nd anomalies have been found in modern day terrestrial samples with data that have 2σ uncertainties of about 5 ppm or more. Last year we reported improvements in 142Nd/144Nd measurements, using our IsotopX thermal ionization mass spectrometer, and obtained reproducibility of 142Nd/144Nd ratios to better than 2 ppm at the 2σ level. With this external reproducibility we found that all except one modern mantle-derived basalt had within error identical 142Nd/144Nd ratios. One sample is about 3.4 ppm lower than the rest of the modern basalt samples, providing evidence for some limited Hadean mantle differentiation signatures preserved up to present. We have also measured 142Nd/144Nd ratios for Proterozoic and Phanerozoic samples, whose ages range from 300 Ma to 2 Ga, to better than 2 ppm external reproducibility (2σ). Most of these samples also have 142Nd/144Nd ratios that cluster around the modern day value, but there are some samples that are either marginally high by 2 ppm or low by 2 ppm. Thus, while a 20 to 30 ppm range in 142Nd/144Nd is well resolved in the Archean, such large variability is not present in the Proterozoic and Phanerozoic. The relatively rapid changeover at the end of the Archean

Neutron Powder Diffraction Study on the Magnetic Structure of NdPd 5 Al 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Metoki, Naoto; Yamauchi, Hiroki; Kitazawa, Hideaki

The magnetic structure of NdPd 5Al 2 has been studied by neutron powder diffraction. Here, we observed the magnetic reflections with the modulation vector q=(1/2,0,0)q=(1/2,0,0) below the ordering temperature T N. We also found a collinear magnetic structure with a Nd moment of 2.7(3) μB at 0.5 K parallel to the c-axis, where the ferromagnetically ordered a-planes stack with a four-Nd-layer period having a ++-- sequence along the a-direction with the distance between adjacent Nd layers equal to a/2 (magnetic space group P anma). This “stripe”-like modulation is very similar to that in CePd 5Al 2 with q=(0.235,0.235,0)q=(0.235,0.235,0) with themore » Ce moment parallel to the c-axis. These structures with in-plane modulation are a consequence of the two-dimensional nature of the Fermi surface topology in this family, originating from the unique crystal structure with a very long tetragonal unit cell and a large distance of >7 Å between the rare-earth layers separated by two Pd and one Al layers.« less

Neutron Powder Diffraction Study on the Magnetic Structure of NdPd 5 Al 2

DOE PAGES

Metoki, Naoto; Yamauchi, Hiroki; Kitazawa, Hideaki; ...

2017-02-24

The magnetic structure of NdPd 5Al 2 has been studied by neutron powder diffraction. Here, we observed the magnetic reflections with the modulation vector q=(1/2,0,0)q=(1/2,0,0) below the ordering temperature T N. We also found a collinear magnetic structure with a Nd moment of 2.7(3) μB at 0.5 K parallel to the c-axis, where the ferromagnetically ordered a-planes stack with a four-Nd-layer period having a ++-- sequence along the a-direction with the distance between adjacent Nd layers equal to a/2 (magnetic space group P anma). This “stripe”-like modulation is very similar to that in CePd 5Al 2 with q=(0.235,0.235,0)q=(0.235,0.235,0) with themore » Ce moment parallel to the c-axis. These structures with in-plane modulation are a consequence of the two-dimensional nature of the Fermi surface topology in this family, originating from the unique crystal structure with a very long tetragonal unit cell and a large distance of >7 Å between the rare-earth layers separated by two Pd and one Al layers.« less

1-mJ Q-switched diode-pumped Nd:BaY2F8 laser

NASA Astrophysics Data System (ADS)

Agnesi, Antonio; Carraro, Giovanni; Guandalini, Annalisa; Reali, Giancarlo; Sani, Elisa; Toncelli, Alessandra; Tonelli, Mauro

2004-08-01

We report what is to our knowledge the first high repetition rate Q-switched Nd:BaY2F8 (Nd:BaYF) laser pumped with a multiwatt fiber-coupled diode array tuned at 806 nm. As much as 2.42 W of average power and up to 1.05 mJ of pulse energy were obtained with 6.1 W of absorbed pump power, with excellent beam quality (M2<1.2) and linear polarization.

Actively Q-switched laser with novel Nd:YAG/YAG polygonal active-mirror

NASA Astrophysics Data System (ADS)

Lang, Ye; Chen, Yanzhong; Ge, Wenqi; He, Jianguo; Zhang, Hongbo; Liao, Lifen; Xin, Jianguo; Zhang, Jian; Fan, Zhongwei

2018-03-01

In this work, we demonstrate an efficient actively Q-switched laser based on a novel crystal Nd:YAG/YAG polygonal active mirror. A passively cooled crystal Nd:YAG/YAG polygonal active mirror with an end pump scheme was used as the gain medium. For the overlap between the TEM00 laser mode and large gain profile, a cavity was carefully designed with a large fundamental mode volume. With a maximum absorbed power of 3.1 W, a 685 mW average output power with a pulse repetition of 5 kHz was attained, and the corresponding optical-optical and slope efficiency were 22.1% and 27.7%, respectively. The pulse width was 133.9 ns. The beam quality (M 2) was 1.561 in the horizontal direction and 1.261 in the vertical direction.

First detection of ND in the solar-mass protostar IRAS16293-2422

NASA Astrophysics Data System (ADS)

Bacmann, A.; Caux, E.; Hily-Blant, P.; Parise, B.; Pagani, L.; Bottinelli, S.; Maret, S.; Vastel, C.; Ceccarelli, C.; Cernicharo, J.; Henning, T.; Castets, A.; Coutens, A.; Bergin, E. A.; Blake, G. A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Kahane, C.; Klotz, A.; Melnick, G.; Schilke, P.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Pearson, J.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F. F. S.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H.; Faure, A.; Benz, A.; Coeur-Joly, O.; Cros, A.; Güsten, R.; Ravera, L.

2010-10-01

Context. In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar envelopes. Very high molecular D/H ratios have been found for saturated molecules and ions. However, little is known about the deuterium fractionation in radicals, even though simple radicals often represent an intermediate stage in the formation of more complex, saturated molecules. The imidogen radical NH is such an intermediate species for the ammonia synthesis in the gas phase. Many of these light molecules however have their fundamental transitions in the submillimetre domain and their detection is hampered by the opacity of the atmosphere at these wavelengths. Herschel/HIFI represents a unique opportunity to study the deuteration and formation mechanisms of species not observable from the ground. Aims: We searched here for the deuterated radical ND in order to determine the deuterium fractionation of imidogen and constrain the deuteration mechanism of this species. Methods: We observed the solar-mass Class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI in Bands 1a (480-560 GHz), 3b (858-961 GHz), and 4a (949-1061 GHz) as part of the Herschel key programme CHESS (Chemical HErschel Survey of Star forming regions). Results: The deuterated form of the imidogen radical ND was detected and securely identified with 2 hyperfine component groups of its fundamental transition (N = 0-1) at 522.1 and 546.2 GHz, in absorption against the continuum background emitted from the nascent protostar. The 3 groups of hyperfine components of its hydrogenated counterpart NH were also detected in absorption. The absorption arises from the cold envelope, where many deuterated species have been shown to be abundant. The estimated column densities are ~2 × 1014 cm-2 for NH and ~ 1.3 × 1014 cm-2 for ND. We derive a very high

Nonlinear scattering of ultrashort laser pulses on two-level system

NASA Astrophysics Data System (ADS)

Astapenko, Valery A.; Sakhno, Sergey V.

2015-05-01

The presentation is devoted to the theoretical investigation of nonlinear scattering of ultrashort electromagnetic pulses (USP) on two-level quantum system. We consider the scattering of several types of USP, namely, so called corrected Gaussian pulse (CGP) and cosine wavelet pulse. Such pulses have no constant component in their spectrum in contrast with traditional Gaussian pulse. It should be noted that the presence of constant component in the limit of ultrashort pulse durations leads to unphysical results. The main purpose of the present work is the investigation of the change of pulse temporal shape after scattering as a function of initial phase at different distances from the target. Numerical calculations are based on the solution of Bloch equations and expression for scattering field strength via dipole moment of two-level system exposed by the action of incident USP. In our calculation we also account for the influence of refracting index of the air on electric field strength in the pulse after scattering.

Picosecond Nd:BaY2F8 laser discretely tunable around 1 μm

NASA Astrophysics Data System (ADS)

Agnesi, A.; Pirzio, F.; Reali, G.; Toncelli, A.; Tonelli, M.

2010-09-01

Passive mode-locking of a diode-pumped Nd:BaY2F8 (Nd:BaYF) was achieved on four lines in the range 1040-1074 nm, employing a semiconductor saturable absorber mirror (SAM). Nearly Fourier-limited pulses with durations of 2.6 to 7.2 ps and output power ≈50 mW were generated in a dispersion-controlled resonator using a single prism for wavelength selection, tuning and dispersion management.

Test Review: The Profile of Mood States 2nd Edition

ERIC Educational Resources Information Center

Lin, Shuqiong; Hsiao, Yu-Yu; Wang, Miao

2014-01-01

The "Profile of Mood States 2nd Edition" (POMS 2) was published in 2012 by Multi-Health Systems (MHS) to assess transient feelings and mood among individuals aged 13 years and above. Evolving from the original POMS (McNair, Lorr, & Droppleman, 1971, 1992), the POMS 2 was designed for youth (13-17 years old) and adults (18 years old…

Ultrashort polarization-tailored bichromatic fields

NASA Astrophysics Data System (ADS)

Kerbstadt, Stefanie; Englert, Lars; Bayer, Tim; Wollenhaupt, Matthias

2017-06-01

We present a novel concept for the generation of ultrashort polarization-shaped bichromatic laser fields. The scheme utilizes a 4f polarization pulse shaper based on a liquid crystal spatial light modulator for independent amplitude and phase modulation of femtosecond laser pulses. By choice of either a conventional (p) or a composite (p-s) polarizer in the Fourier plane, the shaper setup enables the generation of parallel linearly and orthogonal linearly polarized bichromatic fields. Additional use of a ? wave plate behind the setup yields co-rotating and counter-rotating circularly polarized bichromatic fields. The scheme allows to independently control the spectral amplitude, phase and polarization profile of the output fields, offering an enormous versatility of bichromatic waveforms.

Evaluation of Nd-Loaded SnO2:F Films Coated via Spray Pyrolysis

NASA Astrophysics Data System (ADS)

Turgut, G.

2018-05-01

Thin layers of single (F)- and double (F/Nd)-incorporated tin oxide have been coated on glass substrate via spray pyrolysis. The structural, morphological, electrical, and optical features of F-incorporated samples were evaluated depending on the Nd loading. X-ray diffraction analysis revealed that samples had tetragonal tin oxide structure with (211) and (200) preferential directions. The crystallite size and strain values varied from 37.98 nm and 1.21 × 10-3 to 52.12 nm and 1.88 × 10-3. Scanning electron microscopy analysis showed that the samples consisted of pyramidal, polyhedral, and needle-shaped granules. The lowest sheet resistance value of 1.22 Ω was found for 1.8 at.% Nd + 25 at.% F-coloaded SnO2. However, the widest optical bandgap of 4.01 eV was observed for the single 25 at.% F-loaded sample. The Urbach tail and figure of merit also changed in the ranges of 664 meV to 1296 meV and 6.4 × 10-2 Ω-1 to 2.3 × 10-3 Ω-1, respectively. The results presented herein indicate that the character of F-doped tin oxide films can be controlled by Nd loading and that these films could be useful for technological applications.

Evaluation of Nd-Loaded SnO2:F Films Coated via Spray Pyrolysis

NASA Astrophysics Data System (ADS)

Turgut, G.

2018-07-01

Thin layers of single (F)- and double (F/Nd)-incorporated tin oxide have been coated on glass substrate via spray pyrolysis. The structural, morphological, electrical, and optical features of F-incorporated samples were evaluated depending on the Nd loading. X-ray diffraction analysis revealed that samples had tetragonal tin oxide structure with (211) and (200) preferential directions. The crystallite size and strain values varied from 37.98 nm and 1.21 × 10-3 to 52.12 nm and 1.88 × 10-3. Scanning electron microscopy analysis showed that the samples consisted of pyramidal, polyhedral, and needle-shaped granules. The lowest sheet resistance value of 1.22 Ω was found for 1.8 at.% Nd + 25 at.% F-coloaded SnO2. However, the widest optical bandgap of 4.01 eV was observed for the single 25 at.% F-loaded sample. The Urbach tail and figure of merit also changed in the ranges of 664 meV to 1296 meV and 6.4 × 10-2 Ω-1 to 2.3 × 10-3 Ω-1, respectively. The results presented herein indicate that the character of F-doped tin oxide films can be controlled by Nd loading and that these films could be useful for technological applications.

NASA 2nd Generation RLV Program Introduction, Status and Future Plans

NASA Technical Reports Server (NTRS)

Dumbacher, Dan L.; Smith, Dennis E. (Technical Monitor)

2002-01-01

The Space Launch Initiative (SLI), managed by the Second Generation Reusable Launch Vehicle (2ndGen RLV) Program, was established to examine the possibility of revolutionizing space launch capabilities, define conceptual architectures, and concurrently identify the advanced technologies required to support a next-generation system. Initial Program funds have been allocated to design, evaluate, and formulate realistic plans leading to a 2nd Gen RLV full-scale development (FSD) decision by 2006. Program goals are to reduce both risk and cost for accessing the limitless opportunities afforded outside Earth's atmosphere fo civil, defense, and commercial enterprises. A 2nd Gen RLV architecture includes a reusable Earth-to-orbit launch vehicle, an on-orbit transport and return vehicle, ground and flight operations, mission planning, and both on-orbit and on-the-ground support infrastructures All segments of the architecture must advance in step with development of the RLV if a next-generation system is to be fully operational early next decade. However, experience shows that propulsion is the single largest contributor to unreliability during ascent, requires the largest expenditure of time for maintenance, and takes a long time to develop; therefore, propulsion is the key to meeting safety, reliability, and cost goals. For these reasons, propulsion is SLI's top technology investment area.

Fractional-order Fourier analysis for ultrashort pulse characterization.

PubMed

Brunel, Marc; Coetmellec, Sébastien; Lelek, Mickael; Louradour, Frédéric

2007-06-01

We report what we believe to be the first experimental demonstration of ultrashort pulse characterization using fractional-order Fourier analysis. The analysis is applied to the interpretation of spectral interferometry resolved in time (SPIRIT) traces [which are spectral phase interferometry for direct electric field reconstruction (SPIDER)-like interferograms]. First, the fractional-order Fourier transformation is shown to naturally allow the determination of the cubic spectral phase coefficient of pulses to be analyzed. A simultaneous determination of both cubic and quadratic spectral phase coefficients of the pulses using the fractional-order Fourier series expansion is further demonstrated. This latter technique consists of localizing relative maxima in a 2D cartography representing decomposition coefficients. It is further used to reconstruct or filter SPIRIT traces.

Field curvature correction method for ultrashort throw ratio projection optics design using an odd polynomial mirror surface.

PubMed

Zhuang, Zhenfeng; Chen, Yanting; Yu, Feihong; Sun, Xiaowei

2014-08-01

This paper presents a field curvature correction method of designing an ultrashort throw ratio (TR) projection lens for an imaging system. The projection lens is composed of several refractive optical elements and an odd polynomial mirror surface. A curved image is formed in a direction away from the odd polynomial mirror surface by the refractive optical elements from the image formed on the digital micromirror device (DMD) panel, and the curved image formed is its virtual image. Then the odd polynomial mirror surface enlarges the curved image and a plane image is formed on the screen. Based on the relationship between the chief ray from the exit pupil of each field of view (FOV) and the corresponding predescribed position on the screen, the initial profile of the freeform mirror surface is calculated by using segments of the hyperbolic according to the laws of reflection. For further optimization, the value of the high-order odd polynomial surface is used to express the freeform mirror surface through a least-squares fitting method. As an example, an ultrashort TR projection lens that realizes projection onto a large 50 in. screen at a distance of only 510 mm is presented. The optical performance for the designed projection lens is analyzed by ray tracing method. Results show that an ultrashort TR projection lens modulation transfer function of over 60% at 0.5 cycles/mm for all optimization fields is achievable with f-number of 2.0, 126° full FOV, <1% distortion, and 0.46 TR. Moreover, in comparing the proposed projection lens' optical specifications to that of traditional projection lenses, aspheric mirror projection lenses, and conventional short TR projection lenses, results indicate that this projection lens has the advantages of ultrashort TR, low f-number, wide full FOV, and small distortion.

Ultra-short screening instruments for major depressive episode and generalized anxiety disorder in epilepsy: The NDDIE-2 and the GAD-SI.

PubMed

Micoulaud-Franchi, Jean-Arthur; Bartolomei, Fabrice; McGonigal, Aileen

2017-03-01

Systematic screening is recommended for major depressive episode (MDE) with the Neurological Disorders Depression Inventory for Epilepsy NDDI-E, 6 items and generalized anxiety disorder (GAD) with the GAD 7 items in patients with epilepsy (PWE). Shorter versions of the NDDI-E and the GAD-7 could facilitate increased screening by busy clinicians and be more accessible to patients with mild cognitive and/or language impairments. The effectiveness of ultra-short versions of the NDDI-E (2 items) and the GAD-7 (the GAD-2, 2 items, and the GAD-SI with a single item) in comparison with the original versions were statistically tested using ROC analysis. ROC analysis of the NDDIE-2 showed an AUC of 0.926 (p<0.001), a sensitivity of 81.82% and a specificity of 89.16%, without significant difference with the NDDI-E (z=1.582, p=0.11). ROC analysis of the GAD-SI showed an AUC of 0.872 (p<0.001), a sensitivity of 83.67% and a specificity of 82.29%, without significant difference with the GAD-7 (z=1.281, p=0.2). The GAD-2 showed poorer psychometric properties. The limitation is the use of data from previously reported subjects in a single language version, the NDDIE-2 that lacks detection of dysphoric symptoms in comparison with the NDDIE-6 and the GAD-SI that exhibited a more than 10% lower sensitivity than the GAD-7. This study highlights the potential utility of the NDDIE-2 and the GAD-SI as ultra-short screening tools for MDE and GAD respectively in PWE. Further studies in a larger population, including multi-lingual versions, could be a valuable next step. However, the brevity and simplicity of this tool could be an advantage in PWE who present cognitive difficulties, especially attentional or language deficits. Copyright © 2017 Elsevier B.V. All rights reserved.

Luminescence mechanism and energy transfer in doubly-doped BaY2F8:Tm,Nd VUV scintillator

NASA Astrophysics Data System (ADS)

Pejchal, J.; Nikl, M.; Moretti, F.; Vedda, A.; Fukuda, K.; Kawaguchi, N.; Yanagida, T.; Yokota, Y.; Yoshikawa, A.

2010-11-01

Doubly-doped BaY2F8:Tm,Nd scintillation crystals were grown by modified micro-pulling-down method. Nd co-doping was chosen to enhance the energy transfer from the host lattice to the Nd3+ luminescence center via the 5d-levels of Tm3+, due to the overlap of Tm3+ 5d-4f emission spectrum with the Nd3+ 4f-5d absorption. The energy transfer was clearly evidenced in the BaY2F8:Tm,Nd. This process is not complicated by an energy migration to killer centers and/or cross-relaxation. The radioluminescence process is complicated by an energy transfer from the host lattice exciton states to the lower f-levels of Tm3+ ion.

Influence of Nd and Y on texture of as-extruded Mg-5Li-3Al-2Zn alloy

NASA Astrophysics Data System (ADS)

Wu, Liqun; Zhang, Tianlong; Cui, Chongliang; Wu, Ruizhi; Zhang, Milin; Hou, Legan

2016-07-01

Mg-5Li-3Al-2Zn alloys with the additions of Y and Nd were prepared using induction melting furnace under the atmosphere of pure argon; then they were extruded. The textures of the as-extruded alloys were analyzed by pole figures and electron backscatter diffraction. Results show that the addition of a small amount of Nd can weaken the basal texture. The further increase of Nd content has no corresponding further influence on texture. When a small amount of Y is used to replace Nd, the basal texture can be further weakened and the prismatic slip system can be further activated. In the alloy of Mg-5Li-3Al-2Zn-1.2Y-0.8Nd, the basal textures almost vanish.

Two-photon momentum density in La2-xSrxCuO4 and Nd2-xCexCuO4

NASA Astrophysics Data System (ADS)

Blandin, P.; Massidda, S.; Barbiellini, B.; Jarlborg, T.; Lerch, P.; Manuel, A. A.; Hoffmann, L.; Gauthier, M.; Sadowski, W.; Walker, E.; Peter, M.; Yu, Jaejun; Freeman, A. J.

1992-07-01

We present calculations of the electron-positron momentum density for the high-Tc superconductors La2-xSrxCuO4 and Nd2-xCexCuO4, together with experimental two-dimensional angular correlation of annihilation radiation (2D-ACAR) for Nd2-xCexCuO4. The calculations are based on first-principles electronic structure obtained using the full-potential linearized augmented-plane-wave and the linear muffin-tin orbital methods. Our results indicate a non-negligible overlap of the positron wave function with the CuO2 plane electrons responsible for the Fermi surfaces in these compounds. Therefore, these compounds may be well suited for investigating Fermi-surface-related effects. After the folding of umklapp terms according to Lock, Crisp, and West, the predicted Fermi-surface breaks are mixed with strong effects induced by the positron wave function in La2-xSrxCuO4, while their resolution is better in Nd2-xCexCuO4. A comparison of our calculations with the most recent experimental results for La2-xSrxCuO4 shows good agreement. For Nd2-xCexCuO4 good agreement is observed between theoretical and experimental 2D-ACAR profiles.

Low temperature texture development in Nd2Fe14B/α-Fe nanocomposite magnets via equal channel angular pressing

NASA Astrophysics Data System (ADS)

Besley, L.; Garitaonandia, J. S.; Molotnikov, A.; Kishimoto, H.; Kato, A.; Davies, C.; Suzuki, K.

2018-05-01

While suitable texture has been developed in Nd2Fe14B/α-Fe nanocomposites via thermomechanical processing methods such as die upsetting by incorporating low melting point eutectic Nd-Cu additives, significant grain coarsening occurs during this process due to the high temperature and long timescales involved, resulting in a loss of exchange coupling. Equal channel angular pressing (ECAP) is a severe plastic deformation technique which has been successfully used to produce a suitable texture in single-phase Nd2Fe14B at temperatures on the order of 500°C while preserving grain sizes on the order of 20-30nm. We investigate the development of texture in a commercial Nd2Fe14B/α-Fe nanocomposite alloy with added Nd90Cu10 produced via ECAP and then characterise it using texture x-ray diffraction and magnetic measurements. It is found that initial texture can be developed in this nanocomposite system at T = 520°C via ECAP. The average grain size of Nd2Fe14B as measured via X-ray diffraction after ECAP remains below 50nm with a developed texture. The effect of varying the amount of Nd90Cu10 additive is also investigated. It is found that with decreasing Nd90Cu10, the degree of texture is reduced while the volume fraction of α-Fe increases. This work demonstrates the development of texture in nanocomposite Nd2Fe14B/α-Fe with Nd-Cu additives whilst maintaining a grain size of approximately 50nm.

Czochralski and modified Bridgman-Stockbarger growth of pure, Cd 2+ and Nd 3+ doped benzil single crystals

NASA Astrophysics Data System (ADS)

Aggarwal, M. D.; Wang, W. S.; Tambwe, M.

1993-03-01

Pure, Cd2+ and Nd3+-doped benzil C6H5COCOC6H5 have been grown from melt using the Czochralski and modified Bridgman-Stockbarger methods. Angle-tuned second harmonic generation of pure benzil from Nd:YAG laser radiation of λ = 1.06 μm with a conversion efficiency η = I2w/Iw = 0.4% has been demonstrated. We have used a Nd:YAG pulse laser to measure the radiation damage threshold as 15.9 MW/cm2 (c-axis) and 23.9 MW/cm2 (a-axis) under the conditions that laser pulse width is 10 ns. Under the same conditions, the conversion efficiency of Nd3+ and Cd2+-doped benzil, η= I2w/Iw = 1.1%, has been demonstrated. The radiation threshold is higher than for pure benzil crystals.

2nd Generation RLV: Program Goals and Acquisition Strategy

NASA Technical Reports Server (NTRS)

Graham, J. Bart; Dumbacher, D. L. (Technical Monitor)

2001-01-01

The risk to loss of life for Space Shuttle crewmembers is approximately one in 245 missions. U.S. launch service providers captured nearly 100%, of the commercial launch market revenues in the mid 1980s. Today, the U.S. captures less than 50% of that market. A launch system architecture is needed that will dramatically increase the safety of space flight while significantly reducing the cost. NASA's Space Launch Initiative, which is implemented by the 2nd Generation RLV Program Office at Marshall Space Flight Center, seeks to develop technology and reusable launch vehicle concepts which satisfy the commercial launch market needs and the unique needs of NASA. Presented in this paper are the five primary elements of NASA's Integrated Space Transportation Plan along with the highest level goals and the acquisition strategy of the 2nd Generation RLV Program. Approval of the Space Launch Initiative FY01 budget of $290M is seen as a major commitment by the Agency and the Nation to realize the commercial potential that space offers and to move forward in the exploration of space.

Microstructure evolution and coercivity enhancement in Nd-Fe-B thin films diffusion-processed by R-Al alloys (R=Nd, Pr)

NASA Astrophysics Data System (ADS)

Xie, Yigao; Yang, Yang; Zhang, Tongbo; Fu, Yanqing; Jiang, Qingzheng; Ma, Shengcan; Zhong, Zhenchen; Cui, Weibin; Wang, Qiang

2018-05-01

Diffusion process by Nd-Al and Pr-Al alloys was compared and investigated in Nd-Fe-B thin films. Enhanced coercivity 2.06T and good squareness was obtained by using Pr85Al15 and Nd85Al15 alloys as diffusion sources. But the coercivity of diffusion-processed thin films by Pr70Al30 and Pr55Al45 alloys decreased to 2.04T and 1.82T. High ambient coercivity of 2.26T was achieved in diffusion-processed thin film by Nd70Al30 leading to an improved coercivity thermal stability because Nd2Fe14B grains were enveloped by Nd-rich phase as seen by transmission electron microscopy Nd-loss image. Meanwhile, microstructure-dependent parameters α and Neff were improved. However, high content of Al in diffusion-processed thin film by Nd55Al45 lead to degraded texture and coercivity.

Effect of V-Nd co-doping on phase transformation and grain growth process of TiO2

NASA Astrophysics Data System (ADS)

Khatun, Nasima; Amin, Ruhul; Anita, Sen, Somaditya

2018-05-01

The pure and V-Nd co-doped TiO2 samples are prepared by the modified sol-gel process. The phase formation is confirmed by XRD spectrum. Phase transformation is delayed in V-Nd co-doped TiO2 (TVN) samples compared to pure TiO2. The particle size is comparatively small in TVN samples at both the temperature 450 °C and 900 °C. Hence the effect of Nd doping is dominated over V doping in both phase transformation and grain growth process of TiO2.

Scattering of ultrashort electromagnetic pulses on metal clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Astapenko, V. A., E-mail: astval@mail.ru; Sakhno, S. V.

We have calculated and analyzed the probability of ultrashort electromagnetic pulse (USP) scattering on small metal clusters in the frequency range of plasmon resonances during the field action. The main attention is devoted to dependence of the probability of scattering on the pulse duration for various detunings of the USP carrier frequency from the plasmon resonance frequency. Peculiarities of the USP scattering from plasmon resonances with various figures of merit are revealed.

Scattering of ultrashort electromagnetic pulses on metal clusters

NASA Astrophysics Data System (ADS)

Astapenko, V. A.; Sakhno, S. V.

2016-12-01

We have calculated and analyzed the probability of ultrashort electromagnetic pulse (USP) scattering on small metal clusters in the frequency range of plasmon resonances during the field action. The main attention is devoted to dependence of the probability of scattering on the pulse duration for various detunings of the USP carrier frequency from the plasmon resonance frequency. Peculiarities of the USP scattering from plasmon resonances with various figures of merit are revealed.

Histologic comparison of the CO2 laser and Nd:YAG with and without water/air surface cooling on tooth root structure

NASA Astrophysics Data System (ADS)

Cobb, Charles M.; Spencer, Paulette; McCollum, Mark H.

1995-05-01

Specimens consisted of 18 extracted single rooted teeth unaffected by periodontal disease. After debriding roots, specimens were randomly divided into 4 treatment groups and subjected to a single pass, at varying energy densities, of a CO2, Nd:YAG, and Nd:YAG with air/water surface cooling (Nd:YAG-C). The rate of exposure was controlled at 4 mm/sec. Approximate energy densities were: CO2, 138, 206, 275, and 344 J/cm2; Nd:YAG, 114, 171, 229, and 286 J/cm2; Nd:YAG-C, 286, 343, 514, and 571 J/cm2. The CO2 laser was used both in continuous and pulsed beam modes (20 Hz, 0.01 sec pulse length and 0.8 mm dia spot size) whereas the Nd:YAG and Nd:YAG-C were preset at 50 Hz, 0.08 sec pulse length and 0.6 mm dia spot size. Specimen examination by SEM revealed, for all lasers, a direct correlation between increasing energy densities and depth of tissue ablation and width of tissue damage. However, to achieve the same relative dept of tissue ablation, the Nd:YAG-C required higher energy densities than either the CO2 or Nd:YAG lasers. The Nd:YAG-C generated a cavitation with sharply defined margins. Furthermore, regardless of energy density, and in contrast with other laser types, areas treated with the Nd:YAG-C did not exhibit collateral zones of heat damaged surface tissue.

Interplay of structural chemistry and magnetism in perovskites; A study of CaLn2Ni2WO9; Ln=La, Pr, Nd

NASA Astrophysics Data System (ADS)

Chin, Chun-Mann; Paria Sena, Robert; Hunter, Emily C.; Hadermann, Joke; Battle, Peter D.

2017-07-01

Polycrystalline samples of CaLn2Ni2WO9 (Ln=La, Pr, Nd) have been synthesized and characterised by a combination of X-ray and neutron diffraction, electron microscopy and magnetometry. Each composition adopts a perovskite-like structure with a 5.50, b 5.56, c 7.78 Å, β 90.1° in space group P21/n. Of the two crystallographically distinct six-coordinate sites, one is occupied entirely (Ln=Pr) or predominantly (Ln=La, Nd) by Ni2+ and the other by Ni2+ and W6+ in a ratio of approximately 1:2. None of the compounds shows long-range magnetic order at 5 K. The magnetometry data show that the magnetic moments of the Ni2+ cations form a spin glass below 30 K in each case. The Pr3+ moments in CaPr2Ni2WO9 also freeze but the Nd3+ moments in CaNd2Ni2WO9 do not. This behaviour is contrasted with that observed in other (A,A')B2B'O9 perovskites.

47 CFR 36.2 - Fundamental principles underlying procedures.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 47 Telecommunication 2 2010-10-01 2010-10-01 false Fundamental principles underlying procedures... Fundamental principles underlying procedures. (a) The following general principles underlie the procedures... operating forces on a unit basis (e.g., conversation-minute-kilometers per message, weighted standard work...

Large positive magnetoresistance in intermetallic compound NdCo2Si2

NASA Astrophysics Data System (ADS)

Roy Chowdhury, R.; Dhara, S.; Das, I.; Bandyopadhyay, B.; Rawat, R.

2018-04-01

The magnetic, magneto-transport and magnetocaloric properties of antiferromagnetic intermetallic compound NdCo2Si2 (TN = 32K) have been studied. The compound yields a positive magnetoresistance (MR) of about ∼ 123 % at ∼ 5K in 8 T magnetic field. The MR value is significantly large vis - a - vis earlier reports of large MR in intermetallic compounds, and possibly associated with the changes in magnetic structure of the compound. The large MR value can be explained in terms of field induced pseudo-gaps on Fermi surface.

Testing Models for the Origin of the Earth-Moon System with 142Nd/144Nd Measurements

NASA Astrophysics Data System (ADS)

Hyung, E.; Jacobsen, S. B.; Zeng, L.

2015-12-01

The Sm-Nd system is widely used for tracking the differentiation and evolution of planetary silicate reservoirs, due to the well understood, strong Sm-Nd fractionation between melt and mantle minerals. The short-lived 146Sm-142Nd system with a half-life of 103 Ma or 68 Ma has been used to constrain early planetary differentiation events based on early Archean terrestrial rocks, lunar rocks and meteorites. Early Archean terrestrial rocks show significant variations in 142Nd/144Nd of about 30 ppm, demonstrating very early differentiation of the Earth's mantle and crust. In contrast, present day 142Nd/144Nd ratios of mantle-derived ocean island basalts and MORBs show almost no variation at the reported analytical precision level (2σ = ± 6 ppm), suggesting that such early variations have been erased with time due to crustal recycling and mantle mixing. The 142Nd/144Nd ratio of the lunar mantle has been reported to be offset from terrestrial standards by about -5 ppm, barely resolvable with the reported analytical uncertainties. Differences in the 142Nd/144Nd ratios between the bulk Earth and Moon may suggest early large scale silicate differentiation events on the Earth that predate the Giant Moon forming impact. To address this problem, we carry out new 142Nd/144Nd measurements of terrestrial rocks, and lunar rocks and meteorites with a TIMS (Isoprobe T) equipped with new Xact Faraday amplifiers provided by Isotopx. We find that the Xact amplifiers provide lower noise than the earlier generation preamplifiers and operate close to the theoretical thermodynamic noise limit calculated from the Johnson equation. So far we have been able to improve multidynamic measurements to be reproducible to within ± 2 ppm at the 2σ level, and with this precision we find no variations in a few young terrestrial rocks. Our next step is measurements of lunar rocks and E-chondrites. If these turn out to be identical to the modern Earth, then the Nd isotope system may tell the same

Nd:YAG and CO2 laser therapy of oral mucosal lesions.

PubMed

White, J M; Chaudhry, S I; Kudler, J J; Sekandari, N; Schoelch, M L; Silverman, S

1998-12-01

Experiences gained in the management of oral mucosal lesions by CO2 and Nd:YAG laser therapy in an outpatient clinic treated over an 80-year period are described. Lasers have indications for use in dentistry for incision, excision, and coagulation of intraoral soft tissue. Advances in laser technology have provided delivery systems for site-specific delivery of laser energy with short interaction items on tissue to be ablated. This study retrospectively evaluates a series of clinical case studies. Sixty-four patients with a variety of benign oral soft tissue lesions were treated by laser excision. Thirty-five patients were treated by a pulsed fiberoptic delivered Nd:YAG contact laser, and 29 by a continuous free-beam CO2 non-contact laser. The largest group of lesions treated were leukoplakia (39 cases). Other lesions excised and biopsied were lichen planus, squamous papilloma, pyogenic granuloma, focal melanosis, nonhealing traumatic ulceration, hemangioma, and lymphangioma. All patients were followed postoperatively (mean 6.8 months, range 1-36 months). Laser excision was well tolerated by patients with no intraoperative or postoperative adverse effects. All patients healed postsurgically with no loss of function. CO2 and Nd:YAG lasers are successful surgical options when performing excision of benign intraoral lesions. Advantages of laser therapy include minimal postoperative pain, conservative site-specific minimally invasive surgeries, and elimination of need for sutures.

CW and passively Q-switched laser performance of Nd:Lu2SiO5 crystal

NASA Astrophysics Data System (ADS)

Xu, Xiaodong; Di, Juqing; Zhang, Jian; Tang, Dingyuan; Xu, Jun

2016-01-01

We demonstrated an efficient and controllable dual-wavelength continuous-wave (CW) laser of Nd:Lu2SiO5 (Nd:LSO) crystal. The maximum output power was 3.02 W at wavelength of 1075 nm and 1079 nm, and with increasing of absorbed pump power, the ratio of 1079 nm laser rose. The slope efficiency of 65.6% and optical-to-optical conversion efficiency of 63.3% were obtained. The passively Q-switched laser properties of Nd:LSO were investigated for the first time. The shortest pulse, maximum pulse energy and peak power were 11.58 ns, 29.05 μJ and 2.34 kW, respectively.

Structural and optical properties of nano-sized K3Nd(PO4)2:Yb3+ orthophosphate.

PubMed

Mizer, D; Macalik, L; Tomaszewski, P E; Lisiecki, R; Godlewska, P; Matraszek, A; Szczygieł, I; Zawadzki, M; Hanuza, J

2009-09-01

Nanocrystals of tripotassium neodymium bis-phosphate(V) doped with ytterbium ions, K3Nd(PO4)2: Yb3+, were synthesized by Pechini method. The obtained grains, having an average size of about 40 nm, were characterised by X-ray, electron microscopic, electron absorption, luminescence and IR studies. Moreover, fluorescence decay studies were carried out at room temperature. The energy transfer from the Nd3+ to Yb3+ was described and discussed. The results were compared to those of the K3Nd(PO4)2 bulk crystal.

Diode-pumped femtosecond mode-locked Nd, Y-codoped CaF2 laser

NASA Astrophysics Data System (ADS)

Zhu, Jiangfeng; Zhang, Lijuan; Gao, Ziye; Wang, Junli; Wang, Zhaohua; Su, Liangbi; Zheng, Lihe; Wang, Jingya; Xu, Jun; Wei, Zhiyi

2015-03-01

A passively mode-locked femtosecond laser based on an Nd, Y-codoped CaF2 disordered crystal was demonstrated. The Y3+-codoping in Nd : CaF2 markedly suppressed the quenching effect and improved the fluorescence quantum efficiency and emission spectra. With a fiber-coupled laser diode as the pump source, the continuous wave tuning range covering from 1042 to 1076 nm was realized, while the mode-locked operation generated 264 fs pulses with an average output power of 180 mW at a repetition rate of 85 MHz. The experimental results show that the Nd, Y-codoped CaF2 disordered crystal has potential in a new generation diode-pumped high repetition rate chirped pulse amplifier.

Enhanced light emission near 2.7 μm from Er-Nd co-doped germanate glass

NASA Astrophysics Data System (ADS)

Bai, Gongxun; Tao, Lili; Li, Kefeng; Hu, Lili; Tsang, Yuen Hong

2013-04-01

Laser glass gain medium that can convert low cost 808 nm diode laser into 2.7 μm has attracted considerable interest due to its potential application for medical surgery fiber laser system. In this study, enhanced 2.7 μm emission has been achieved in Er3+:germanate glass by co-doping with Nd3+ ions under the excitation of an 808 nm diode laser. In the co-doped sample, the experimental results show that the harmful visible emissions via up-conversion were effectively restricted. The reduction of 1.5 μm emission was also detected in the co-doped sample, which indicates significant de-excitation of 4I13/2 Er3+ ion through energy transfer and non-radiative decay in Nd3+ ions. In conclusion, the 2.7 μm emission enhancement achieved was due to the increased optical absorption of 808 nm, efficient energy transfer (ET) with efficiency of 81.73% between Er3+ and Nd3+ ions, and shortening the lifetime of the lower lasing level 4I13/2 Er3+ in the co-doped sample. Therefore, Er3+/Nd3+ co-doped germanate glass could be used to fabricate fiber optical gain media for 2.7 μm laser generation.

Superhyperfine Structure of the EPR Spectra of Nd3+ Impurity Ions in Fluorite CaF2

NASA Astrophysics Data System (ADS)

Aminov, L. K.; Gafurov, M. R.; Kurkin, I. N.; Malkin, B. Z.; Rodionov, A. A.

2018-05-01

EPR spectra of a CaF2 single crystal that was grown from melt containing a small addition of NdF3 were studied. Signals corresponding to tetragonal centers of Nd3+ ions and cubic centers of Er3+ and Yb3+ ions were found. Superhyperfine structure (SHFS) in the spectra of the Nd3+ ions was observed for the first time in this crystal; parameters of the superhyperfine interaction of the Nd3+ ions with the nearest nine fluorine ions were determined. The dependence of the resolution of the Nd3+ EPR spectrum SHFS on the incident microwave power at the temperature of T ≈ 6 K was studied. Obtained results are discussed and compared with the literature data.

Laser-Material Interaction of Powerful Ultrashort Laser Pulses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Komashko, A

2003-01-06

Laser-material interaction of powerful (up to a terawatt) ultrashort (several picoseconds or shorter) laser pulses and laser-induced effects were investigated theoretically in this dissertation. Since the ultrashort laser pulse (USLP) duration time is much smaller than the characteristic time of the hydrodynamic expansion and thermal diffusion, the interaction occurs at a solid-like material density with most of the light energy absorbed in a thin surface layer. Powerful USLP creates hot, high-pressure plasma, which is quickly ejected without significant energy diffusion into the bulk of the material, Thus collateral damage is reduced. These and other features make USLPs attractive for amore » variety of applications. The purpose of this dissertation was development of the physical models and numerical tools for improvement of our understanding of the process and as an aid in optimization of the USLP applications. The study is concentrated on two types of materials - simple metals (materials like aluminum or copper) and wide-bandgap dielectrics (fused silica, water). First, key physical phenomena of the ultrashort light interaction with metals and the models needed to describe it are presented. Then, employing one-dimensional plasma hydrodynamics code enhanced with models for laser energy deposition and material properties at low and moderate temperatures, light absorption was self-consistently simulated as a function of laser wavelength, pulse energy and length, angle of incidence and polarization. Next, material response on time scales much longer than the pulse duration was studied using the hydrocode and analytical models. These studies include examination of evolution of the pressure pulses, effects of the shock waves, material ablation and removal and three-dimensional dynamics of the ablation plume. Investigation of the interaction with wide-bandgap dielectrics was stimulated by the experimental studies of the USLP surface ablation of water (water is a

Interaction of intense ultrashort pulse lasers with clusters.

NASA Astrophysics Data System (ADS)

Petrov, George

2007-11-01

The last ten years have witnessed an explosion of activity involving the interaction of clusters with intense ultrashort pulse lasers. Atomic or molecular clusters are targets with unique properties, as they are halfway between solid and gases. The intense laser radiation creates hot dense plasma, which can provide a compact source of x-rays and energetic particles. The focus of this investigation is to understand the salient features of energy absorption and Coulomb explosion by clusters. The evolution of clusters is modeled with a relativistic time-dependent 3D Molecular Dynamics (MD) model [1]. The Coulomb interaction between particles is handled by a fast tree algorithm, which allows large number of particles to be used in simulations [2]. The time histories of all particles in a cluster are followed in time and space. The model accounts for ionization-ignition effects (enhancement of the laser field in the vicinity of ions) and a variety of elementary processes for free electrons and charged ions, such as optical field and collisional ionization, outer ionization and electron recapture. The MD model was applied to study small clusters (1-20 nm) irradiated by a high-intensity (10^16-10^20 W/cm^2) sub-picosecond laser pulse. We studied fundamental cluster features such as energy absorption, x-ray emission, particle distribution, average charge per atom, and cluster explosion as a function of initial cluster radius, laser peak intensity and wavelength. Simulations of novel applications, such as table-top nuclear fusion from exploding deuterium clusters [3] and high power synchrotron radiation for biological applications and imaging [4] have been performed. The application for nuclear fusion was motivated by the efficient absorption of laser energy (˜100%) and its high conversion efficiency into ion kinetic energy (˜50%), resulting in neutron yield of 10^6 neutrons/Joule laser energy. Contributors: J. Davis and A. L. Velikovich. [1] G. M. Petrov, et al Phys

Fluorescence properties of Nd3+-doped tellurite glasses.

PubMed

Kumar, K Upendra; Prathyusha, V A; Babu, P; Jayasankar, C K; Joshi, A S; Speghini, A; Bettinelli, M

2007-07-01

The compositional and concentration dependence of luminescence of the (4)F(3/2)-->(4)I(J) (J=13/2, 11/2 and 9/2) transitions in four Nd(3+)-doped tellurite based glasses has been studied. The free-ion energy levels obtained for 60TeO(2)+39ZnO(2)+1.0Nd(2)O(3) (TZN10) glass have been analysed using the free-ion Hamiltonian model and compared with similar results obtained for Nd(3+):glass systems. The absorption spectrum of TZN10 glass has been analysed using the Judd-Ofelt theory. Relatively longer decay rates have been obtained for Nd(3+)-doped phosphotellurite glasses. The emission characteristics of the (4)F(3/2)-->(4)I(11/2) transition, of the Nd(3+):TZN10 glass, are found to be comparable to those obtained for Nd(3+):phosphate laser glasses. The non-exponential shape of the emission decay curves for the (4)F(3/2)-->(4)I(11/2) transition is attributed to the presence of energy transfer processes between the Nd(3+) ions.

Nd:GdVO4 ring laser pumped by laser diodes

NASA Astrophysics Data System (ADS)

Hao, E. J.; Li, T.; Wang, Z. D.; Zhang, Y.

2013-02-01

The design and operation of a laser diode-pumped Nd:GdVO4 ring laser is described. A composite crystal (Nd:GdVO4/YVO4) with undoped ends is single-end pumped by a fiber-coupled laser diode (LD) at 808 nm. A four-mirror ring cavity is designed to keep the laser operating unidirectionally, which eliminates spatial hole burning in the standing-wave cavity. This laser can operate either as continuous wave (CW) or Q-switched. The single-frequency power obtained was 9.1 W at 1063 nm. Q-switched operation produced 0.23 mJ/pulse at 20 kHz in the fundamental laser.

2nd Annual Postdoc Research Day: US Army Research Laboratory PosterSymposia and Activities

DTIC Science & Technology

2018-04-12

ARL-SR-0394•APR 2018 US Army Research Laboratory 2nd Annual Postdoc Research Day: US Army Research Laboratory Poster Symposia and Activities by...Do not return it to the originator. ARL-SR-0394•APR 2018 US Army Research Laboratory 2nd Annual Postdoc Research Day: US Army Research Laboratory...Poster Symposia and Activities by Efraín Hernández–Rivera Weapons and Materials Research Directorate, ARL Julia Cline Oak Ridge Institute for Science and

SU(2) with fundamental fermions and scalars

NASA Astrophysics Data System (ADS)

Hansen, Martin; Janowski, Tadeusz; Pica, Claudio; Toniato, Arianna

2018-03-01

We present preliminary results on the lattice simulation of an SU(2) gauge theory with two fermion flavors and one strongly interacting scalar field, all in the fundamental representation of SU(2). The motivation for this study comes from the recent proposal of "fundamental" partial compositeness models featuring strongly interacting scalar fields in addition to fermions. Here we describe the lattice setup for our study of this class of models and a first exploration of the lattice phase diagram. In particular we then investigate how the presence of a strongly coupled scalar field affects the properties of light meson resonances previously obtained for the SU(2) model. Preprint: CP3-Origins-2017-047 DNRF90

Fabrication of Nb/Pb structures through ultrashort pulsed laser deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gontad, Francisco; Lorusso, Antonella, E-mail: antonella.lorusso@le.infn.it; Perrone, Alessio

This work reports the fabrication of Nb/Pb structures with an application as photocathode devices. The use of relatively low energy densities for the ablation of Nb with ultrashort pulses favors the reduction of droplets during the growth of the film. However, the use of laser fluences in this ablation regime results in a consequent reduction in the average deposition rate. On the other hand, despite the low deposition rate, the films present a superior adherence to the substrate and an excellent coverage of the irregular substrate surface, avoiding the appearance of voids or discontinuities on the film surface. Moreover, themore » low energy densities used for the ablation favor the growth of nanocrystalline films with a similar crystalline structure to the bulk material. Therefore, the use of low ablation energy densities with ultrashort pulses for the deposition of the Nb thin films allows the growth of very adherent and nanocrystalline films with adequate properties for the fabrication of Nb/Pb structures to be included in superconducting radiofrequency cavities.« less

Delivery of ultrashort spatially focused pulses through a multimode fiber

NASA Astrophysics Data System (ADS)

Morales-Delgado, Edgar E.; Papadopoulos, Ioannis N.; Farahi, Salma; Psaltis, Demetri; Moser, Christophe

2015-08-01

Multimode optical fibers potentially allow the transmission of larger amounts of information than their single mode counterparts because of their high number of supported modes. However, propagation of a light pulse through a multimode fiber suffers from spatial distortions due to the superposition of the various exited modes and from time broadening due to modal dispersion. We present a method based on digital phase conjugation to selectively excite in a multimode fiber specific optical fiber modes that follow similar optical paths as they travel through the fiber. The excited modes interfere constructively at the fiber output generating an ultrashort spatially focused pulse. The excitation of a limited number of modes following similar optical paths limits modal dispersion, allowing the transmission of the ultrashort pulse. We have experimentally demonstrated the delivery of a focused spot of pulse width equal to 500 fs through a 30 cm, 200 micrometer core step index multimode fiber. The results of this study show that two-photon imaging capability can be added to ultra-thin lensless endoscopy using commercial multimode fibers.

Spelling performance of 2nd to 5th grade students from public school.

PubMed

Capellini, Simone Aparecida; Amaral, Amanda Corrêa do; Oliveira, Andrea Batista; Sampaio, Maria Nobre; Fusco, Natália; Cervera-Mérida, José Francisco; Ygual-Fernández, Amparo

2011-09-01

To characterize, compare and classify the performance of 2nd to 5th grade students from public schools according to the semiology of spelling errors. Participants were 120 students from 2nd to 5th grades of a public school in Marília (SP), Brazil, 30 students from each grade, who were divided into four groups: GI (2nd grade), GII (3rd grade), GIII (4th grade), and GIV (5th grade). The tasks of the Pro-Ortografia test were applied: collective version (writing of alphabet letters, randomized dictation of letters, words dictation, nonwords dictation, dictation with pictures, thematic writing induced by picture) and individual version (dictation of sentences, purposeful error, spelled dictation, orthographic lexical memory). Significant difference was found in the between-group comparison indicating better performance of students in every subsequent grade in most of the individual and collective version tasks. With the increase of grade level, the groups decreased the average of writing errors. The profile of spelling acquisition of the Portuguese writing system found in these public school students indicates normal writing development in this population.

Rotationally inelastic scattering of ND3 with H2 as a probe of the intermolecular potential energy surface

NASA Astrophysics Data System (ADS)

Tkáč, Ondřej; Saha, Ashim K.; Loreau, Jérôme; Ma, Qianli; Dagdigian, Paul J.; Parker, David H.; van der Avoird, Ad; Orr-Ewing, Andrew J.

2015-12-01

Differential cross sections (DCSs) are reported for rotationally inelastic scattering of ND3 with H2, measured using a crossed molecular beam apparatus with velocity map imaging (VMI). ND3 molecules were quantum-state selected in the ground electronic and vibrational levels and, optionally, in the j±k = 11- rotation-inversion level prior to collisions. Inelastic scattering of state-selected ND3 with H2 was measured at the mean collision energy of 580 cm-1 by resonance-enhanced multiphoton ionisation spectroscopy and VMI of ND3 in selected single final j'±k' levels. Comparison of experimental DCSs with close-coupling quantum-mechanical scattering calculations serves as a test of a recently reported ab initio potential energy surface. Calculated integral cross sections reveal the propensities for scattering into various final j'±k' levels of ND3 and differences between scattering by ortho and para H2. Integral and differential cross sections are also computed at a mean collision energy of 430 cm-1 and compared to our recent results for inelastic scattering of state-selected ND3 with He.

Critical dimension control using ultrashort laser for improving wafer critical dimension uniformity

NASA Astrophysics Data System (ADS)

Avizemer, Dan; Sharoni, Ofir; Oshemkov, Sergey; Cohen, Avi; Dayan, Asaf; Khurana, Ranjan; Kewley, Dave

2015-07-01

Requirements for control of critical dimension (CD) become more demanding as the integrated circuit (IC) feature size specifications become tighter and tighter. Critical dimension control, also known as CDC, is a well-known laser-based process in the IC industry that has proven to be robust, repeatable, and efficient in adjusting wafer CD uniformity (CDU) [Proc. SPIE 6152, 615225 (2006)]. The process involves locally and selectively attenuating the deep ultraviolet light which goes through the photomask to the wafer. The input data for the CDC process in the wafer fab is typically taken from wafer CDU data, which is measured by metrology tools such as wafer-critical dimension-scanning electron microscopy (CD-SEM), wafer optical scatterometry, or wafer level CD (WLCD). The CD correction process uses the CDU data in order to create an attenuation correction contour, which is later applied by the in-situ ultrashort laser system of the CDC to locally change the transmission of the photomask. The ultrashort pulsed laser system creates small, partially scattered, Shade-In-Elements (also known as pixels) by focusing the laser beam inside the quartz bulk of the photomask. This results in the formation of a localized, intravolume, quartz modified area, which has a different refractive index than the quartz bulk itself. The CDC process flow for improving wafer CDU in a wafer fab with detailed explanations of the shading elements formation inside the quartz by the ultrashort pulsed laser is reviewed.

Macromolecule mapping of the brain using ultrashort-TE acquisition and reference-based metabolite removal.

PubMed

Lam, Fan; Li, Yudu; Clifford, Bryan; Liang, Zhi-Pei

2018-05-01

To develop a practical method for mapping macromolecule distribution in the brain using ultrashort-TE MRSI data. An FID-based chemical shift imaging acquisition without metabolite-nulling pulses was used to acquire ultrashort-TE MRSI data that capture the macromolecule signals with high signal-to-noise-ratio (SNR) efficiency. To remove the metabolite signals from the ultrashort-TE data, single voxel spectroscopy data were obtained to determine a set of high-quality metabolite reference spectra. These spectra were then incorporated into a generalized series (GS) model to represent general metabolite spatiospectral distributions. A time-segmented algorithm was developed to back-extrapolate the GS model-based metabolite distribution from truncated FIDs and remove it from the MRSI data. Numerical simulations and in vivo experiments have been performed to evaluate the proposed method. Simulation results demonstrate accurate metabolite signal extrapolation by the proposed method given a high-quality reference. For in vivo experiments, the proposed method is able to produce spatiospectral distributions of macromolecules in the brain with high SNR from data acquired in about 10 minutes. We further demonstrate that the high-dimensional macromolecule spatiospectral distribution resides in a low-dimensional subspace. This finding provides a new opportunity to use subspace models for quantification and accelerated macromolecule mapping. Robustness of the proposed method is also demonstrated using multiple data sets from the same and different subjects. The proposed method is able to obtain macromolecule distributions in the brain from ultrashort-TE acquisitions. It can also be used for acquiring training data to determine a low-dimensional subspace to represent the macromolecule signals for subspace-based MRSI. Magn Reson Med 79:2460-2469, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.

Generation of 103 fs mode-locked pulses by a gain linewidth-variable Nd,Y:CaF2 disordered crystal.

PubMed

Qin, Z P; Xie, G Q; Ma, J; Ge, W Y; Yuan, P; Qian, L J; Su, L B; Jiang, D P; Ma, F K; Zhang, Q; Cao, Y X; Xu, J

2014-04-01

We have demonstrated a diode-pumped passively mode-locked femtosecond Nd,Y:CaF2 disordered crystal laser for the first time to our knowledge. By choosing appropriate Y-doping concentration, a broad fluorescence linewidth of 31 nm has been obtained from the gain linewidth-variable Nd,Y:CaF2 crystal. With the Nd,Y:CaF2 disordered crystal as gain medium, the mode-locked laser generated pulses with pulse duration as short as 103 fs, average output power of 89 mW, and repetition rate of 100 MHz. To our best knowledge, this is the shortest pulse generated from Nd-doped crystal lasers so far. The research results show that the Nd,Y:CaF2 disordered crystal will be a potential alternative as gain medium of repetitive chirped pulse amplification for high-peak-power lasers.

Ultrashort-pulse lasers treating the crystalline lens: will they cause vision-threatening cataract? (An American Ophthalmological Society thesis).

PubMed

Krueger, Ronald R; Uy, Harvey; McDonald, Jared; Edwards, Keith

2012-12-01

To demonstrate that ultrashort-pulse laser treatment in the crystalline lens does not form a focal, progressive, or vision-threatening cataract. An Nd:vanadate picosecond laser (10 ps) with prototype delivery system was used. Primates: 11 rhesus monkey eyes were prospectively treated at the University of Wisconsin (energy 25-45 μJ/pulse and 2.0-11.3M pulses per lens). Analysis of lens clarity and fundus imaging was assessed postoperatively for up to 4½ years (5 eyes). Humans: 80 presbyopic patients were prospectively treated in one eye at the Asian Eye Institute in the Philippines (energy 10 μJ/pulse and 0.45-1.45M pulses per lens). Analysis of lens clarity, best-corrected visual acuity, and subjective symptoms was performed at 1 month, prior to elective lens extraction. Bubbles were immediately seen, with resolution within the first 24 to 48 hours. Afterwards, the laser pattern could be seen with faint, noncoalescing, pinpoint micro-opacities in both primate and human eyes. In primates, long-term follow-up at 4½ years showed no focal or progressive cataract, except in 2 eyes with preexisting cataract. In humans, <25% of patients with central sparing (0.75 and 1.0 mm radius) lost 2 or more lines of best spectacle-corrected visual acuity at 1 month, and >70% reported acceptable or better distance vision and no or mild symptoms. Meanwhile, >70% without sparing (0 and 0.5 mm radius) lost 2 or more lines, and most reported poor or severe vision and symptoms. Focal, progressive, and vision-threatening cataracts can be avoided by lowering the laser energy, avoiding prior cataract, and sparing the center of the lens.

Fundamental Movement Skill Proficiency and Body Composition Measured by Dual Energy X-Ray Absorptiometry in Eight-Year-Old Children

ERIC Educational Resources Information Center

Slotte, Sari; Sääkslahti, Arja; Metsämuuronen, Jari; Rintala, Pauli

2015-01-01

Objective: The main aim was to examine the association between fundamental movement skills (FMS) and objectively measured body composition using dual energy X-ray absorptiometry (DXA). Methods: A study of 304 eight-year-old children in Finland. FMS were assessed with the "Test of gross motor development," 2nd ed. Total body fat…

Thermodynamic Modeling of the Ge-Nd Binary System

NASA Astrophysics Data System (ADS)

Liu, Miao; Li, Changrong; Du, Zhenmin; Guo, Cuiping; Niu, Chunju

The Ge-Nd has been critically assessed by means of the CALculation of PHAse Diagram (CALPHAD) technique. For the liquid phase, the associate model was used with the constituent species Ge, Nd, Ge3Nd5 and Ge1.6Nd in the Ge-Nd system. The terminal solid solution diamond-(Ge), dhcp-(Nd) and bcc_A2-(Nd) in the Ge-Nd system were described using the substitutional model, in which the excess Gibbs energy was formulated with the Redlich-Kister equation. The compounds with homogeneity ranges, α(Ge1.6Nd), β(Ge1.6Nd), (GeNd), (Ge4Nd5) and (Ge3Nd5) were modeled using two sublattices as α(Ge,Nd)1.6Nd, β(Ge,Nd)1.6Nd, (Ge,Nd)Nd, (Ge,Nd)4Nd5 and (Ge,Nd)3Nd5, respectively. A set of self-consistent thermodynamic parameters for each of the Ge-Nd binary systems was obtained. The calculation results agree well with the available experimental data from literatures.

6. 2nd floor where stables used to be; note bottom ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

6. 2nd floor where stables used to be; note bottom of truss with suspension rods for floor which results in clear span on 1st level - Diebolt Brewing Company Stable, 2695 Pittsburgh Avenue, Cleveland, Cuyahoga County, OH

Cutaneous pain effects induced by Nd:YAG and CO2 laser stimuli

NASA Astrophysics Data System (ADS)

Wang, Jia-Rui; Yu, Guang-Yuan; Yang, Zai-Fu; Chen, Hong-Xia; Hu, Dong-Dong; Zou, Xian-Biao

2012-12-01

The near infrared laser technique can activate cutaneous nociceptors with high specificity and reproducibility and be used in anti-riot equipment. This study aimed to explore cutaneous pain effect and determine the threshold induced by Nd:YAG and CO2 laser stimuli. The corresponding wavelength was 1.32μm and 10.6μm. The pain effect was assessed in three healthy subjects (1 woman and 2 men) on the skin of dorsum of both hands. The energy of each pulse and whether the subjects felt a painful sensation after each stimulus were recorded. A simplified Bliss Method was used to calculate the pain threshold which were determined under three pulse durations for Nd:YAG laser and one pulse duration for CO2 laser. As a result the pain thresholds were determined to be 5.6J/cm2, 5.4J/cm2 and 5.0J/cm2 respectively when using Nd:YAG laser, 4.0mm beam diameter, 8ms, 0.1s and 1s pulse duration. The pain threshold was 1.0J/cm2 when using CO2 laser, 4.0mm beam diameter and 0.1s pulse duration. We concluded that the threshold of cutaneous pain elicited by 1.32μm laser was independent upon the pulse duration when the exposure time ranged from 8ms to 1s. Under the same exposure condition, the threshold of cutaneous pain elicited by 1.32μm laser was higher than that elicited by 10.6μm laser.

Self-Raman Nd:YVO4 laser and electro-optic technology for space-based sodium lidar instrument

NASA Astrophysics Data System (ADS)

Krainak, Michael A.; Yu, Anthony W.; Janches, Diego; Jones, Sarah L.; Blagojevic, Branimir; Chen, Jeffrey

2014-02-01

We are developing a laser and electro-optic technology to remotely measure Sodium (Na) by adapting existing lidar technology with space flight heritage. The developed instrumentation will serve as the core for the planning of an Heliophysics mission targeted to study the composition and dynamics of Earth's mesosphere based on a spaceborne lidar that will measure the mesospheric Na layer. We present performance results from our diode-pumped tunable Q-switched self-Raman c-cut Nd:YVO4 laser with intra-cavity frequency doubling that produces multi-watt 589 nm wavelength output. The c-cut Nd:YVO4 laser has a fundamental wavelength that is tunable from 1063-1067 nm. A CW External Cavity diode laser is used as a injection seeder to provide single-frequency grating tunable output around 1066 nm. The injection-seeded self-Raman shifted Nd:VO4 laser is tuned across the sodium vapor D2 line at 589 nm. We will review technologies that provide strong leverage for the sodium lidar laser system with strong heritage from the Ice Cloud and Land Elevation Satellite-2 (ICESat-2) Advanced Topographic Laser Altimeter System (ATLAS). These include a space-qualified frequency-doubled 9W @ 532 nm wavelength Nd:YVO4 laser, a tandem interference filter temperature-stabilized fused-silica-etalon receiver and high-bandwidth photon-counting detectors.

Self-Raman Nd:YVO4 Laser and Electro-Optic Technology for Space-Based Sodium Lidar Instrument

NASA Technical Reports Server (NTRS)

Krainak, Michael A.; Yu, Anthony W.; Janches, Diego; Jones, Sarah L.; Blagojevic, Branimir; Chen, Jeffrey

2014-01-01

We are developing a laser and electro-optic technology to remotely measure Sodium (Na) by adapting existing lidar technology with space flight heritage. The developed instrumentation will serve as the core for the planning of an Heliophysics mission targeted to study the composition and dynamics of Earth's mesosphere based on a spaceborne lidar that will measure the mesospheric Na layer. We present performance results from our diode-pumped tunable Q-switched self-Raman c-cut Nd:YVO4 laser with intra-cavity frequency doubling that produces multi-watt 589 nm wavelength output. The c-cut Nd:YVO4 laser has a fundamental wavelength that is tunable from 1063-1067 nanometers. A CW (Continuous Wave) External Cavity diode laser is used as a injection seeder to provide single-frequency grating tunable output around 1066 nanometers. The injection-seeded self-Raman shifted Nd:VO4 laser is tuned across the sodium vapor D2 line at 589 nanometers. We will review technologies that provide strong leverage for the sodium lidar laser system with strong heritage from the Ice Cloud and Land Elevation Satellite-2 (ICESat-2) Advanced Topographic Laser Altimeter System (ATLAS). These include a space-qualified frequency-doubled 9 watts-at-532-nanometer wavelength Nd:YVO4 laser, a tandem interference filter temperature-stabilized fused-silica-etalon receiver and high-bandwidth photon-counting detectors.

2nd Generation RLV Risk Definition Program

NASA Technical Reports Server (NTRS)

Davis, Robert M.; Stucker, Mark (Technical Monitor)

2000-01-01

The 2nd Generation RLV Risk Reduction Mid-Term Report summarizes the status of Kelly Space & Technology's activities during the first two and one half months of the program. This report was presented to the cognoscente Contracting Officer's Technical Representative (COTR) and selected Marshall Space Flight Center staff members on 26 September 2000. The report has been approved and is distributed on CD-ROM (as a PowerPoint file) in accordance with the terms of the subject contract, and contains information and data addressing the following: (1) Launch services demand and requirements; (2) Architecture, alternatives, and requirements; (3) Costs, pricing, and business cases analysis; (4) Commercial financing requirements, plans, and strategy; (5) System engineering processes and derived requirements; and (6) RLV system trade studies and design analysis.

Magnetic interactions at Ce impurities in REMn2Ge2 (RE = La, Ce, Pr, Nd) compounds

NASA Astrophysics Data System (ADS)

Bosch-Santos, B.; Cabrera-Pasca, G. A.; Saxena, R. N.; Burimova, A. N.; Carbonari, A. W.

2018-05-01

In the work reported in this paper, the temperature dependence of the magnetic hyperfine field (Bh f) at 140Ce nuclei replacing Pr atoms in PrMn2Ge2 compound was measured by the perturbed angular correlation technique to complete the sequence of measurements in REMn2Ge2 (RE = La, Ce, Pr, Nd). Results show an anomalous behavior different from the expected Brillouin curve. A model was used to fit the data showing that the Ce impurity contribution (Bhfimp) to Bhf is negative for NdMn2Ge2 below 210 K. The impurity contribution (Bhfimp) at 0 K for all compounds is much smaller than that for the free Ce3+, showing that the 4f band of Ce is more likely highly hybridized with 5d band of the host. Results show that direction of the localized magnetic moment at Mn atoms strongly affects the exchange interaction at Ce impurities.

Ultrashort x-ray backlighters and applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Umstadter, D., University of Michigan

Previously, using ultrashort laser pulses focused onto solid targets, we have experimentally studied a controllable ultrafast broadband radiation source in the extreme ultraviolet for time-resolved dynamical studies in ultrafast science [J. Workman, A. Maksimchuk, X. Llu, U. Ellenberger, J. S. Coe, C.-Y. Chien, and D. Umstadter, ``Control of Bright Picosecond X-Ray Emission from Intense Sub- Picosecond Laser-Plasma Interactions,`` Phys. Rev. Lett. 75, 2324 (1995)]. Once armed with a bright ultrafast broadband continuum x-ray source and appropriate detectors, we used the source as a backlighter to study a remotely produced plasma. The application of the source to a problem relevant tomore » high-density matter completes the triad: creating and controlling, efficiently detecting, and applying the source. This work represented the first use of an ultrafast laser- produced x-ray source as a time-resolving probe in an application relevant to atomic, plasma and high-energy-density matter physics. Using the x-ray source as a backlighter, we adopted a pump-probe geometry to investigate the dynamic changes in electronic structure of a thin metallic film as it is perturbed by an ultrashort laser pulse. Because the laser deposits its energy in a skin depth of about 100 {Angstrom} before expansion occurs, up to gigabar pressure shock waves lasting picosecond in duration have been predicted to form in these novel plasmas. This raises the possibility of studying high- energy-density matter relevant to inertial confinement fusion (ICF) and astrophysics in small-scale laboratory experiments. In the past, time-resolved measurements of K-edge shifts in plasmas driven by nanosecond pulses have been used to infer conditions in highly compressed materials. In this study, we used 100-fs laser pulses to impulsively drive shocks into a sample (an untamped 1000 {Angstrom} aluminum film on 2000 {Angstrom} of parylene-n), measuring L-edge shifts.« less

An animal model for Norrie disease (ND): gene targeting of the mouse ND gene.

PubMed

Berger, W; van de Pol, D; Bächner, D; Oerlemans, F; Winkens, H; Hameister, H; Wieringa, B; Hendriks, W; Ropers, H H

1996-01-01

In order to elucidate the cellular and molecular processes which are involved in Norrie disease (ND), we have used gene targeting technology to generate ND mutant mice. The murine homologue of the ND gene was cloned and shown to encode a polypeptide that shares 94% of the amino acid sequence with its human counterpart. RNA in situ hybridization revealed expression in retina, brain and the olfactory bulb and epithelium of 2 week old mice. Hemizygous mice carrying a replacement mutation in exon 2 of the ND gene developed retrolental structures in the vitreous body and showed an overall disorganization of the retinal ganglion cell layer. The outer plexiform layer disappears occasionally, resulting in a juxtaposed inner and outer nuclear layer. At the same regions, the outer segments of the photoreceptor cell layer are no longer present. These ocular findings are consistent with observations in ND patients and the generated mouse line provides a faithful model for study of early pathogenic events in this severe X-linked recessive neurological disorder.

Terahertz Spectroscopy and Global Analysis of the Rotational Spectrum of Doubly Deuterated Amidogen Radical ND2

NASA Astrophysics Data System (ADS)

Melosso, Mattia; Degli Esposti, Claudio; Dore, Luca

2017-11-01

The deuteration mechanism of molecules in the interstellar medium is still being debated. Observations of deuterium-bearing species in several astronomical sources represent a powerful tool to improve our understanding of the interstellar chemistry. The doubly deuterated form of the astrophysically interesting amidogen radical could be a target of detection in space. In this work, the rotational spectrum of the ND2 radical in its ground vibrational and electronic {X}2{B}1 state has been investigated between 588 and 1131 GHz using a frequency modulation millimeter/submillimeter-wave spectrometer. The ND2 molecule has been produced in a free-space glass absorption cell by discharging a mixture of ND3 and Ar. Sixty-four new transition frequencies involving J values from 2 to 5 and K a values from 0 to 4 have been measured. A global analysis including all the previous field-free pure rotational data has been performed, allowing for a more precise determination of a very large number of spectroscopic parameters. Accurate predictions of rotational transition frequencies of ND2 are now available from a few gigahertz up to several terahertz.

12. SW corner of 2nd floor of Tender Frame Shop ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. SW corner of 2nd floor of Tender Frame Shop showing heating duct and diffuser. - Central of Georgia Railway, Savannah Repair Shops & Terminal Facilities, Tender Frame Shop, Bounded by West Broad, Jones, West Boundary & Hull Streets, Savannah, Chatham County, GA

One pot synthesis of exchange coupled Nd2Fe14B/alpha-Fe by pechini type sol-gel method.

PubMed

Hussain, Abid; Jadhav, Abhijit P; Baek, Yeon Kyung; Choi, Hul Jin; Lee, Jaeho; Kang, Young Soo

2013-11-01

In this work, a combination of nanoparticles of Nd2Fe14B hard magnetic phase and alpha-Fe soft magnetic phase were synthesized by one pot chemical synthesis technique using sol-gel method. A gel of Nd-Fe-B was prepared using NdCl3 x 6H2O, FeCl3 x 6H2O, H3BO3, citric acid, and ethylene glycol by pechini type sol-gel method. The gel was subsequently calcined and annealed to obtain the mixed oxide powders. The produced metal oxide particles were identified with XRD, SEM, TEM to obtain the crystal structure, shape and domain structure of them. The nanoparticles of mixed phase of Nd2Fe14B/alpha-Fe were obtained from these oxides by a process of reduction-diffusion in vacuum by employing CaH2 as reducing agent. During this process it was optimized by controlling temperature, reaction time and concentration of the reducing agent (CaH2). The phase formation of Nd2Fe14B was resulted by the direct diffusion of NdH2, Fe and B. The magnetic property of produced hard and soft phases was successfully identified with vibrating sample magnetometer (VSM). The mixed domains of the hard and soft phases were identified with selected area electron diffraction method (SAED) patterns.

Comparison of the ultrashort gonadotropin-releasing hormone agonist-antagonist protocol with microdose flare -up protocol in poor responders: a preliminary study

PubMed Central

Berker, Bülent; Duvan, Candan İltemir; Kaya, Cemil; Aytaç, Ruşen; Şatıroğlu, Hakan

2010-01-01

Objective To determine the potential effect of the ultrashort gonadotropin-releasing hormone (GnRH) agonist/GnRH antagonist protocol versus the microdose GnRH agonist protocol in poor responders undergoing intracytoplasmic sperm injection (ICSI). Material and Methods The patients in the Agonist-Antagonist Group (n=41) were administered the ultrashort GnRH-agonist/ antagonist protocol, while the patients in the Microdose Group (n=41) were stimulated according to the microdose flare-up protocol. The mean number of mature oocytes retrieved was the primary outcome measure. Fertilization rate, implantation rate per embryo and clinical pregnancy rates were secondary outcome measures. Results There was no differenc between the mean number of mature oocytes retrieved in the two groups. There were also no statistical differences between the two groups in terms of peak serum E2 level, canceled cycles, endometrial thickness on hCG day, number of 2 pronucleus and number of embryos transferred. However, the total gonadotropin consumption and duration of stimulation were significantly higher with the Agonist-Antagonist Group compared with the Microdose Group. The implantation and clinical pregnancy rates were similar between the two groups. Conclusion Despite the high dose of gonadotropin consumption and longer duration of stimulation with the ultrashort GnRH agonist/ antagonist protocol, it seems that the Agonist-Antagonist Protocol is not inferior to the microdose protocol in poor responders undergoing ICSI. PMID:24591934

Comparison of the ultrashort gonadotropin-releasing hormone agonist-antagonist protocol with microdose flare -up protocol in poor responders: a preliminary study.

PubMed

Berker, Bülent; Duvan, Candan İltemir; Kaya, Cemil; Aytaç, Ruşen; Satıroğlu, Hakan

2010-01-01

To determine the potential effect of the ultrashort gonadotropin-releasing hormone (GnRH) agonist/GnRH antagonist protocol versus the microdose GnRH agonist protocol in poor responders undergoing intracytoplasmic sperm injection (ICSI). The patients in the Agonist-Antagonist Group (n=41) were administered the ultrashort GnRH-agonist/ antagonist protocol, while the patients in the Microdose Group (n=41) were stimulated according to the microdose flare-up protocol. The mean number of mature oocytes retrieved was the primary outcome measure. Fertilization rate, implantation rate per embryo and clinical pregnancy rates were secondary outcome measures. There was no differenc between the mean number of mature oocytes retrieved in the two groups. There were also no statistical differences between the two groups in terms of peak serum E2 level, canceled cycles, endometrial thickness on hCG day, number of 2 pronucleus and number of embryos transferred. However, the total gonadotropin consumption and duration of stimulation were significantly higher with the Agonist-Antagonist Group compared with the Microdose Group. The implantation and clinical pregnancy rates were similar between the two groups. Despite the high dose of gonadotropin consumption and longer duration of stimulation with the ultrashort GnRH agonist/ antagonist protocol, it seems that the Agonist-Antagonist Protocol is not inferior to the microdose protocol in poor responders undergoing ICSI.

Treatment of spinal tuberculosis with ultrashort-course chemotherapy in conjunction with partial excision of pathologic vertebrae.

PubMed

Wang, Zili; Ge, Zhaohui; Jin, Weidong; Qiao, Yongdong; Ding, Huiqiang; Zhao, Haoning; Lin, Zhikai; Chen, Jun; Yang, Weiyu

2007-01-01

The ultrashort-course chemotherapeutical scheme of less than 6 months has been used for part of patients with pulmonary tuberculosis and satisfactory curative effects have already been achieved. However, few systematic and clinical reports so far about medical treatment of spinal tuberculosis by using ultrashort-course chemotherapeutical schemes have been published in the spine-care literature. To assess the results of ultrashort-course chemotherapy (UCC) in conjunction with partial excision of pathological vertebrae for spinal tuberculosis. This is a retrospective comparative study of case series from a single center. Seventy-six cases of spinal tuberculosis, treated during 1998 and 2003 by senior author, were reviewed. All the cases underwent chemotherapies in conjunction with the uniform partial excision of pathological vertebra and had a minimum follow-up of 2 years. Clinical manifestations, laboratory tests, imaging examination, examination by ultrasonic wave B, drug complications, and clinical effects based on the previously described evaluative measures. Of the 76 cases, 28 had UCC with the scheme of 2SHRZ/2.5H(2)R(2)Z(2), 23 had short-course chemotherapy (SCC) with the scheme of 3SHRZ/5H(2)R(2)Z(2), and 25 had standard chemotherapy (SC) with the scheme of 3SHRZ/9H(2)R(2)Z(2). All the patients had anterior partial excisions of pathological vertebrae, large iliac strut graft, and anterior or posterior fixation. The mean time of follow-up surveys for the ultrashort-course, short-course, and standard chemotherapy cases was 42.3 m, 46.5 m, and 55.4 m, respectively. The observance indices included 1) clinical manifestations: disappearance of tuberculosis symptoms, no CC pains, recovery of normal life or work, no percussion pains on pathologic sites, and recovery of neural functions; 2) laboratory tests: normal or close to normal test results of both erythrocyte sedimentation rate (ESR) and C-reactive protein (CRP) or one of them; 3) imaging examinations: X

Causes of 142Nd Variation in Earth

NASA Astrophysics Data System (ADS)

Boyet, M.; Bouvier, A.; Gannoun, A.; Carlson, R.

2015-12-01

Variability of the 142Nd/144Nd ratio can reflect Sm/Nd fractionation during the lifetime of 146Sm, i.e. the first 500 Ma of Solar System history1 and nucleosynthetic heterogeneity inherited from the solar nebula. Deciphering the message carried by 142Nd variability requires a detailed examination of the data for Earth and meteorites. The elevated 142Nd/144Nd in terrestrial samples relative to average chondrites suggests that all terrestrial rocks sampled by volcanism over the Earth's history come from a geochemical reservoir characterized by a superchondritic Sm/Nd ratio. The chemical compliment to this reservoir, however, has never been seen, so it either was lost during Earth's accretion2,3, or is preserved in a deep hidden reservoir 1,4. These models are based on a comparison of Earth rocks and O-chondrites because they do not show any variation in stable Sm and Nd isotopic composition compared to Earth6-8. The first analyzed E-chondrites with terrestrial 142Nd/144Nd showed 144Sm excesses that reflect an excess p-process contribution. Although 142Nd is mainly produced by s-process, there is a direct p-process component estimated to be lower than 4 %. We will present new Sm and Nd isotopic data on meteoritic materials. CAIs show deficits in both r- and p-process isotopes that would lead to elevated 142Nd, yet the bulk C-chondrites in which they are contained show excesses in r-process isotopes and hence 142Nd/144Nd lower than terrestrial. The new E-chondrites data do not confirm the 142Nd-144Sm correlation observed in bulk chondrites In light of these results and using 146Sm-142Nd isochrons for constraining the bulk 142Nd/144Nd ratio of planetary bodies, we will discuss the 142Nd signature of terrestrial samples (from Hadean to present). 1Boyet & Carlson, Science 2005; 2O'Neill & Palme, Phil. Trans. R. Soc 2008; 3Caro et al. Nature 2008; 4Andreasen et al. EPSL 2008; 6Andreasen & Sharma, Science 2006; 7Carlson et al., Science 2007; 8Gannoun et al. PNAS 2011.

Controlled synthesis, characterization and photoluminescence property of olive-like tetragonal α-Nd{sub 2}(MoO{sub 4}){sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Youjin, E-mail: zyj@ustc.edu.cn; Zheng, Ao; Yang, Xiaozhi

2012-09-15

Highlights: ► The olive-like tetragonal α-Nd{sub 2}(MoO{sub 4}){sub 3} was gained with EDTA assisted hydrothermal method. ► The product was characterized by XRD, XPS, FTIR, FESEM, and PL. ► The possible formation mechanism for olive-like α-Nd{sub 2}(MoO{sub 4}){sub 3} was proposed. ► The PL in visible region of the olive-like α-Nd{sub 2}(MoO{sub 4}){sub 3} was studied. -- Abstract: The olive-like tetragonal α-Nd{sub 2}(MoO{sub 4}){sub 3} was obtained by a convenient and facile complex agent assisted hydrothermal method. The product was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, field-emission scanning electron microscopy (FESEM) andmore » photoluminescence (PL). The possible formation mechanism of the olive-like α-Nd{sub 2}(MoO{sub 4}){sub 3} was proposed. The photoluminescence property in visible region of the olive-like tetragonal α-Nd{sub 2}(MoO{sub 4}){sub 3} was studied.« less

Anomalous magnetoelastic behaviour near morphotropic phase boundary in ferromagnetic Tb{sub 1-x}Nd{sub x}Co{sub 2} system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murtaza, Adil; Yang, Sen, E-mail: yang.sen@mail.xjtu.edu.cn; Zhou, Chao

2016-08-01

In this work, we report a morphotropic phase boundary (MPB) involved ferromagnetic system Tb{sub 1-x}Nd{sub x}Co{sub 2} and reveal the corresponding structural and magnetoelastic properties of this system. With high resolution synchrotron X-ray diffractometry, the crystal structure of the TbCo{sub 2}-rich side is detected to be rhombohedral and that of NdCo{sub 2}-rich side is tetragonal below their respective Curie temperatures T{sub C}. The MPB composition Tb{sub 0.35}Nd{sub 0.65}Co{sub 2} corresponds to the coexistence of the rhombohedral phase (R-phase) and tetragonal phase (T-phase). Contrary to previously reported MPB involved ferromagnetic systems, the MPB composition of Tb{sub 0.35}Nd{sub 0.65}Co{sub 2} shows minimummore » magnetization which can be understood as compensation of sublattice moments between the R-phase and the T-phase. Furthermore, magnetostriction of Tb{sub 1-x}Nd{sub x}Co{sub 2} decreases with increasing Nd concentration until x = 0.8 and then increases in the negative direction with further increasing Nd concentration; the optimum point for magnetoelastic properties lies towards the rhombohedral phase. Our work not only shows an anomalous type of ferromagnetic MPB but also provides an effective way to design functional materials.« less

[Combined CO2 and Nd-YAG laser in neurosurgical practice. A 1st experience apropos of 40 intracranial procedures].

PubMed

Roux, F X; Leriche, B; Cioloca, C; Devaux, B; Turak, B; Nohra, G

1992-01-01

The authors present their experience concerning the use of Combolaser (Lasermatic, Finland), in neurosurgery. This laser-unit combines two wavelengths (CO2 and 1.06 Nd-YAG) which are emitted simultaneously and coaxially. During the last 12 months, 40 patients harbouring an intracranial tumor were operated upon with such a combolaser unit: 8 infra-tentorial, 32 supra-tentorial, 17 were meningiomas. The mean output power used during the procedures was 3-5 w for both CO2 and Nd-YAG beams. The authors discuss the advantages and inconveniences of such a laser; and they compare it with the other laser-units they have been using for the last 10 years: CO2-Laser, 1.06 Nd-YAG and 1.32 Nd-YAG laser. The main inconvenience of this unit is linked to the utilization of the articulated arm which conducts the CO2 laser beam. This drawback should be avoided or limited by the use of a fiber microguide, which will conduct both CO2 and Nd-YAG beams simultaneously. The principal contribution of a combined-laser unit is the quality of the haemostasis associated to a very good vaporization and cutting effect. When both wavelengths are synchronized, the combined laser beams penetrate into the nervous parenchyma more deeply than the only CO2 laser beam would with the same parameters. The vaporization effect is identical to that obtained with the isolated CO2 laser; the quality of haemostasis is limited to the effects of the Nd-YAG laser. Another advantage must be emphasized: the possibility of utilizing separately the CO2 laser and the 1.06 Nd-YAG.

Tannic acid alleviates bulk and nanoparticle Nd2O3 toxicity in pumpkin: a physiological and molecular response.

PubMed

Chen, Guangcai; Ma, Chuanxin; Mukherjee, Arnab; Musante, Craig; Zhang, Jianfeng; White, Jason C; Dhankher, Om Parkash; Xing, Baoshan

2016-11-01

The effect of dissolved organic matter (DOM) on nanoparticle toxicity to plants is poorly understood. In this study, tannic acid (TA) was selected as a DOM surrogate to explore the mechanisms of neodymium oxide NPs (Nd2O3 NPs) phytotoxicity to pumpkin (Cucurbita maxima). The results from the tested concentrations showed that 100 mg L(-1) Nd2O3 NPs were significantly toxic to pumpkin in term of fresh biomass, and the similar results from the bulk particles and the ionic treatments were also evident. Exposure to 100 mg L(-1) of Nd2O3 NPs and BPs in 1/5 strength Hoagland's solution not only significantly inhibited pumpkin growth, but also decreased the S, Ca, K and Mg levels in plant tissues. However, 60 mg L(-1) TA significantly moderated the observed phytotoxicity, decreased Nd accumulation in the roots, and notably restored S, Ca, K and Mg levels in NPs and BPs treated pumpkin. TA at 60 mg L(-1) increased superoxide dismutase (SOD) activity in both roots (17.5%) and leaves (42.9%), and catalase (CAT) activity (243.1%) in the roots exposed to Nd2O3 NPs. This finding was confirmed by the observed up-regulation of transcript levels of SOD and CAT in Nd2O3 NPs treated pumpkin analyzed by quantitative reverse transcription polymerase chain reaction. These results suggest that TA alleviates Nd2O3 BPs/NPs toxicity through alteration of the particle surface charge, thus reducing the contact and uptake of NPs by pumpkin. In addition, TA promotes antioxidant enzymatic activity by elevating the transcript levels of genes involved in ROS scavenging. Our results shed light on the mechanisms underlying the influence of DOM on the bioavailability and toxicity of NPs to terrestrial plants.

Evaluation of a Hand Washing Program for 2nd-Graders

ERIC Educational Resources Information Center

Tousman, Stuart; Arnold, Dani; Helland, Wealtha; Roth, Ruth; Heshelman, Nannatte; Castaneda, Oralia; Fischer, Emily; O'Neil, Kristen; Bileto, Stephanie

2007-01-01

The purpose of this project was to determine if a multiple-week learner-centered hand washing program could improve hand hygiene behaviors of 2nd-graders in a northern Illinois public school system. Volunteers from the Rockford Hand Washing Coalition went into 19 different classrooms for 4 consecutive weeks and taught a learner-centered program.…

Highly efficient passive mode locking of Nd:Lu2.9Gd0.1Al5O12 garnet crystal

NASA Astrophysics Data System (ADS)

Di, J. Q.; Xu, X. D.; Xia, C. T.; Tan, W. D.; Zhang, J.; Tang, D. Y.; Li, D. Z.; Zhou, D. H.; Wu, F.; Xu, J.

2013-05-01

Passive mode locking of Nd:Lu2.9Gd0.1Al5O12 (Nd:LuGdAG) crystal lasers was experimentally investigated. Stable mode-locked pulses with pulse widths as short as 9.7 ps were obtained for the Nd:LuGdAG crystal; the corresponding maximum output powers were 0.93 W while the mode-locked slope efficiencies were 43%, among the highest efficiencies ever reported for Nd3+ ps lasers. The results demonstrate that Nd:LuGdAG garnet crystal is a promising gain medium for efficient picosecond laser use.

Nd3+-doped TeO2-PbF2-AlF3 glasses for laser applications

NASA Astrophysics Data System (ADS)

Lalla, E. A.; Rodríguez-Mendoza, U. R.; Lozano-Gorrín, A. D.; Sanz-Arranz, A.; Rull, F.; Lavín, V.

2016-01-01

A study of the optical properties of Nd3+ ion in TeO2-PbF2-AlF3 glasses has been carried out for different Nd3+ concentrations. Based on the Judd-Ofelt theory, intensity parameters and radiative properties were determined from the absorption spectra. Focusing on the suitability of this host for laser applications, the spectroscopic quality factor χ was obtained with a value of 1.07, a value of the order of other compositions proposed as laser hosts. For the most intense emission corresponding with the 4F3/2 → 4I11/2 transition (1.06 μm), the absorption and emission and have been calculated with values of 1.20 × 10-20 cm2, 2.08 × 10-20 cm2. A positive value for the gain cross-sections has been found for a population inversion factor γ of 0.4 in the spectral range from 1060 to 1110 nm. All these results suggest the potentially use of this system as a laser host.

2nd International Gliomatosis Cerebri Working Group Conference | Center for Cancer Research

Cancer.gov

On June 22-23, the NIH hosted the 2nd Gliomatosis Cerebri International Conference that brought together leading neuro-oncologists, neuroscientists and families who have lost a child to the disease. Learn more...

Propagation and spatiotemporal coupling characteristics of ultra-short Gaussian vortex pulse

NASA Astrophysics Data System (ADS)

Nie, Jianye; Liu, Guodong; Zhang, Rongzhu

2018-05-01

Based on Collins diffraction integral formula, the propagation equation of ultra-short Gaussian vortex pulse beam has been derived. Using the equation, the intensity distribution variations of vortex pulse in the propagation process are calculated. Specially, the spatiotemporal coupling characteristics of ultra-short vortex beams are discussed in detail. The results show that some key parameters, such as transverse distance, transmission distance, pulse width and topological charge number will influence the spatiotemporal coupling characteristics significantly. With the increasing of transverse distance, the waveforms of the pulses distort obviously. And when transmission distance is far than 50 mm, the distribution curve of transverse intensity gradually changes into a Gaussian type. In addition, initial pulse width will affect the distribution of light field, however, when initial pulse width is larger than 3 fs, the spatiotemporal coupling effect will be insignificant. Topological charge number does not affect the time delay characteristics, since with the increasing of topological charge number, the waveform of the pulse distorts gradually but the time delay does not occur.

Laser Applications in Microelectronic and Optoelectronic Manufacturing IV

DTIC Science & Technology

1999-07-15

laser irradiation of the clusters with 6000 laser pulses of X...insulating ma- terials during and after irradiation by tunable, ultrashort pulses from a mid-infrared laser . The three salient examples we con- sider...with ultrashort pulses re- sembles the rear-side ablation seen in irradiation of calcite by Nd:YAG lasers (1064 nm), while the off-resonance FEL

Effects of Nd:YAG and CO2 lasers on cerebral microvasculature. Study in normal rabbit brain.

PubMed

Kuroiwa, T; Tsuyumu, M; Takei, H; Inaba, Y

1986-01-01

The effect of Nd:YAG and CO2 laser beams on cerebral microvasculature was examined in experimental animals. Soft x-ray microangiography and histological examination of the brain after Nd:YAG laser exposure revealed broad avascular or oligovascular zones in the irradiated and the surrounding edematous tissue, in which the surviving vessels were narrowed and tapered without significant leakage of blood. After CO2 laser exposure, a wedge-shaped tissue defect surrounded by layers of charring, coagulation, and edema was observed. The main finding in the surrounding coagulation and edematous layers was dilatation of the vessels. Hemorrhage was sometimes observed, mainly in the edematous layer. These findings seem to explain the effective hemostatic capability of the Nd:YAG laser and the occasional hemorrhage following CO2 laser exposure, especially at high energy output.

The Particle Adventure | What is fundamental? | Fundamental

Science.gov Websites

fundamental The atom Is the atom fundamental? Is the nucleus fundamental? Are protons and neutrons fundamental decay What is the Mechanism giving mass to fundamental particles? What is the Mechanism giving mass to fundamental particles? Part 2 How Does the Higgs Boson get its Mass? Finding the Mass of the Higgs Boson

Recycling and Mantle Stirring Determined by 142Nd/144Nd Isotopic Ratios

NASA Astrophysics Data System (ADS)

Jacobsen, S. B.; Ranen, M. C.

2004-12-01

It is now well established that 146Sm was live in the early solar system with an initial uniform 146Sm/144Sm ratio of ~0.008. Harper and Jacobsen (1992) discovered that a sample from Isua (~3.8 Ga old) had a positive 142Nd/144Nd anomaly of 33 ppm when compared to normal terrestrial and chondritic Nd. Furthermore, Jacobsen and Harper (1996) reported results from other Isua as well as Acasta (~4 Ga old) samples. Three other Isua samples had a possible small range (about -15 to +15), while two Acasta samples had no anomalies (normal to within 5 ppm). The presence of 142Nd anomalies at Isua has recently been confirmed by two other groups (Boyet et al. 2003; Caro et al. 2003). The available data demonstrate both the existence of early depleted mantle and that the early mantle was isotopically heterogeneous. As discussed by Jacobsen and Harper (1996), the recycling rate can be determined by tracing the decay of the average 142Nd/144Nd value of the depleted mantle. In addition, by using the 142Nd/144Nd heterogeneity in the depleted mantle through time we can determine the stirring rate of the mantle (Kellogg, Jacobsen and O'Connell, 2002) as a function of time. For this project our goal is to obtain a resolution in 142Nd/144Nd measurements of ~1 ppm. We have thus compared results obtained for the Nd isotope composition and 142Nd enriched standards for three different TIMS instruments: The Finnigan MAT 262 at Harvard, the Isoprobe-T and Finnigan TRITON mass spectrometers in GV Instrument's and Thermo Electron's demo laboratories in Manchester and Bremen, respectively. The Finnigan TRITON was designed in response to a request from the senior author for such an instrument. The results obtained so far demonstrate that all three instruments yield the same 142Nd/144Nd, 143Nd/144Nd and 145Nd/144Nd isotopic ratios to within a few ppm, while 148Nd/144Nd and 150Nd/144Nd ratios agree to within 10-20 ppm, when all ratios are normalized to 146Nd/144Nd using the exponential law. Due to

Crystalline Structure, Defect Chemistry and Room Temperature Colossal Permittivity of Nd-doped Barium Titanate

NASA Astrophysics Data System (ADS)

Sun, Qiaomei; Gu, Qilin; Zhu, Kongjun; Jin, Rongying; Liu, Jinsong; Wang, Jing; Qiu, Jinhao

2017-02-01

Dielectric materials with high permittivity are strongly demanded for various technological applications. While polarization inherently exists in ferroelectric barium titanate (BaTiO3), its high permittivity can only be achieved by chemical and/or structural modification. Here, we report the room-temperature colossal permittivity (~760,000) obtained in xNd: BaTiO3 (x = 0.5 mol%) ceramics derived from the counterpart nanoparticles followed by conventional pressureless sintering process. Through the systematic analysis of chemical composition, crystalline structure and defect chemistry, the substitution mechanism involving the occupation of Nd3+ in Ba2+ -site associated with the generation of Ba vacancies and oxygen vacancies for charge compensation has been firstly demonstrated. The present study serves as a precedent and fundamental step toward further improvement of the permittivity of BaTiO3-based ceramics.

Crystalline Structure, Defect Chemistry and Room Temperature Colossal Permittivity of Nd-doped Barium Titanate.

PubMed

Sun, Qiaomei; Gu, Qilin; Zhu, Kongjun; Jin, Rongying; Liu, Jinsong; Wang, Jing; Qiu, Jinhao

2017-02-13

Dielectric materials with high permittivity are strongly demanded for various technological applications. While polarization inherently exists in ferroelectric barium titanate (BaTiO 3 ), its high permittivity can only be achieved by chemical and/or structural modification. Here, we report the room-temperature colossal permittivity (~760,000) obtained in xNd: BaTiO 3 (x = 0.5 mol%) ceramics derived from the counterpart nanoparticles followed by conventional pressureless sintering process. Through the systematic analysis of chemical composition, crystalline structure and defect chemistry, the substitution mechanism involving the occupation of Nd 3+ in Ba 2+ -site associated with the generation of Ba vacancies and oxygen vacancies for charge compensation has been firstly demonstrated. The present study serves as a precedent and fundamental step toward further improvement of the permittivity of BaTiO 3 -based ceramics.

Crystalline Structure, Defect Chemistry and Room Temperature Colossal Permittivity of Nd-doped Barium Titanate

PubMed Central

Sun, Qiaomei; Gu, Qilin; Zhu, Kongjun; Jin, Rongying; Liu, Jinsong; Wang, Jing; Qiu, Jinhao

2017-01-01

Dielectric materials with high permittivity are strongly demanded for various technological applications. While polarization inherently exists in ferroelectric barium titanate (BaTiO3), its high permittivity can only be achieved by chemical and/or structural modification. Here, we report the room-temperature colossal permittivity (~760,000) obtained in xNd: BaTiO3 (x = 0.5 mol%) ceramics derived from the counterpart nanoparticles followed by conventional pressureless sintering process. Through the systematic analysis of chemical composition, crystalline structure and defect chemistry, the substitution mechanism involving the occupation of Nd3+ in Ba2+ -site associated with the generation of Ba vacancies and oxygen vacancies for charge compensation has been firstly demonstrated. The present study serves as a precedent and fundamental step toward further improvement of the permittivity of BaTiO3-based ceramics. PMID:28205559

International Symposium on Halide Glasses (2nd) (Extended Abstracts).

DTIC Science & Technology

1983-08-05

of these materials. It is hoped that the atmosphere of the 1st Symposium will be maintained at the 2nd Symposium. The meeting will be held in a...purification of HfF4 and ZrFo by sublimation in a hydrogen fluoride atmosphere and purification of individual components and glasses by reactive atmosphere ...Tregoat and G. Fonteneau, U. Rennes, Rennes, France Reactive atmosphere processing developed by Mort Robinson at Hughes Research Labs. for the

Validity of (Ultra-)Short Recordings for Heart Rate Variability Measurements

PubMed Central

Munoz, M. Loretto; van Roon, Arie; Riese, Harriëtte; Thio, Chris; Oostenbroek, Emma; Westrik, Iris; de Geus, Eco J. C.; Gansevoort, Ron; Lefrandt, Joop

2015-01-01

Objectives In order to investigate the applicability of routine 10s electrocardiogram (ECG) recordings for time-domain heart rate variability (HRV) calculation we explored to what extent these (ultra-)short recordings capture the “actual” HRV. Methods The standard deviation of normal-to-normal intervals (SDNN) and the root mean square of successive differences (RMSSD) were measured in 3,387 adults. SDNN and RMSSD were assessed from (ultra)short recordings of 10s(3x), 30s, and 120s and compared to 240s–300s (gold standard) measurements. Pearson’s correlation coefficients (r), Bland-Altman 95% limits of agreement and Cohen’s d statistics were used as agreement analysis techniques. Results Agreement between the separate 10s recordings and the 240s-300s recording was already substantial (r = 0.758–0.764/Bias = 0.398–0.416/d = 0.855–0.894 for SDNN; r = 0.853–0.862/Bias = 0.079–0.096/d = 0.150–0.171 for RMSSD), and improved further when three 10s periods were averaged (r = 0.863/Bias = 0.406/d = 0.874 for SDNN; r = 0.941/Bias = 0.088/d = 0.167 for RMSSD). Agreement increased with recording length and reached near perfect agreement at 120s (r = 0.956/Bias = 0.064/d = 0.137 for SDNN; r = 0.986/Bias = 0.014/d = 0.027 for RMSSD). For all recording lengths and agreement measures, RMSSD outperformed SDNN. Conclusions Our results confirm that it is unnecessary to use recordings longer than 120s to obtain accurate measures of RMSSD and SDNN in the time domain. Even a single 10s (standard ECG) recording yields a valid RMSSD measurement, although an average over multiple 10s ECGs is preferable. For SDNN we would recommend either 30s or multiple 10s ECGs. Future research projects using time-domain HRV parameters, e.g. genetic epidemiological studies, could calculate HRV from (ultra-)short ECGs enabling such projects to be performed at a large scale. PMID:26414314

Defining Simple nD Operations Based on Prosmatic nD Objects

NASA Astrophysics Data System (ADS)

Arroyo Ohori, K.; Ledoux, H.; Stoter, J.

2016-10-01

An alternative to the traditional approaches to model separately 2D/3D space, time, scale and other parametrisable characteristics in GIS lies in the higher-dimensional modelling of geographic information, in which a chosen set of non-spatial characteristics, e.g. time and scale, are modelled as extra geometric dimensions perpendicular to the spatial ones, thus creating a higher-dimensional model. While higher-dimensional models are undoubtedly powerful, they are also hard to create and manipulate due to our lack of an intuitive understanding in dimensions higher than three. As a solution to this problem, this paper proposes a methodology that makes nD object generation easier by splitting the creation and manipulation process into three steps: (i) constructing simple nD objects based on nD prismatic polytopes - analogous to prisms in 3D -, (ii) defining simple modification operations at the vertex level, and (iii) simple postprocessing to fix errors introduced in the model. As a use case, we show how two sets of operations can be defined and implemented in a dimension-independent manner using this methodology: the most common transformations (i.e. translation, scaling and rotation) and the collapse of objects. The nD objects generated in this manner can then be used as a basis for an nD GIS.

Dynamic target ionization using an ultrashort pulse of a laser field

NASA Astrophysics Data System (ADS)

Makarov, D. N.; Matveev, V. I.; Makarova, K. A.

2014-09-01

Ionization processes under the interaction of an ultrashort pulse of an electromagnetic field with atoms in nonstationary states are considered. As an example, the ionization probability of the hydrogen-like atom upon the decay of quasi-stationary state is calculated. The method developed can be applied to complex systems, including targets in collisional states and various chemical reactions.

Evolution of optical force on two-level atom by ultrashort time-domain dark hollow Gaussian pulse

NASA Astrophysics Data System (ADS)

Cao, Xiaochao; Wang, Zhaoying; Lin, Qiang

2017-09-01

Based on the analytical expression of the ultrashort time-domain dark hollow Gaussian (TDHG) pulse, the optical force on two-level atoms induced by a TDHG pulse is calculated in this paper. The phenomena of focusing or defocusing of the light force is numerical analyzed for different detuning, various duration time, and different order of the ultrashort pulse. The transverse optical force can change from a focusing force to a defocusing force depending on the spatial-temporal coupling effect as the TDHG pulses propagating in free space. Our results also show that the initial phase of the TDHG pulse can significantly changes the envelope of the optical force.

Magnetocaloric effect in layered NdMn2Ge0.4Si1.6

NASA Astrophysics Data System (ADS)

Wang, J. L.; Campbell, S. J.; Cadogan, J. M.; Studer, A. J.; Zeng, R.; Dou, S. X.

2011-06-01

A giant magnetocaloric effect has been observed in NdMn2Ge0.4Si1.6 associated with the first-order magnetic phase transition from antiferromagnetism to ferromagnetism around TC=36K. The magnetic entropy change -ΔSM and adiabatic temperature change ΔTad have been determined from magnetization and specific heat measurements (B =0-5 T) with -ΔSM calculated by the Maxwell relation and Clausius-Clapeyron method. The values -ΔSMmax=12.3 J kg-1 K-1 and refrigerant capacity ˜95 J/kg for ΔB =0-2 T as derived from the Maxwell relation, together with the small hysteresis (thermal <0.5 K; magnetic field <0.1 T), indicate the potential of NdMn2Ge0.4Si1.6 for refrigeration applications.

Ultrashort-Pulse Lasers Treating the Crystalline Lens: Will They Cause Vision-Threatening Cataract? (An American Ophthalmological Society Thesis)

PubMed Central

Krueger, Ronald R.; Uy, Harvey; McDonald, Jared; Edwards, Keith

2012-01-01

Purpose: To demonstrate that ultrashort-pulse laser treatment in the crystalline lens does not form a focal, progressive, or vision-threatening cataract. Methods: An Nd:vanadate picosecond laser (10 ps) with prototype delivery system was used. Primates: 11 rhesus monkey eyes were prospectively treated at the University of Wisconsin (energy 25–45 μJ/pulse and 2.0–11.3M pulses per lens). Analysis of lens clarity and fundus imaging was assessed postoperatively for up to 4½ years (5 eyes). Humans: 80 presbyopic patients were prospectively treated in one eye at the Asian Eye Institute in the Philippines (energy 10 μJ/pulse and 0.45–1.45M pulses per lens). Analysis of lens clarity, best-corrected visual acuity, and subjective symptoms was performed at 1 month, prior to elective lens extraction. Results: Bubbles were immediately seen, with resolution within the first 24 to 48 hours. Afterwards, the laser pattern could be seen with faint, noncoalescing, pinpoint micro-opacities in both primate and human eyes. In primates, long-term follow-up at 4½ years showed no focal or progressive cataract, except in 2 eyes with preexisting cataract. In humans, <25% of patients with central sparing (0.75 and 1.0 mm radius) lost 2 or more lines of best spectacle-corrected visual acuity at 1 month, and >70% reported acceptable or better distance vision and no or mild symptoms. Meanwhile, >70% without sparing (0 and 0.5 mm radius) lost 2 or more lines, and most reported poor or severe vision and symptoms. Conclusions: Focal, progressive, and vision-threatening cataracts can be avoided by lowering the laser energy, avoiding prior cataract, and sparing the center of the lens. PMID:23818739

Nd-doped Bi2O3 nanocomposites: simple synthesis and improved photocatalytic activity for hydrogen production under visible light

NASA Astrophysics Data System (ADS)

Al-Namshah, Khadijah S.; Mohamed, Reda M.

2018-04-01

Bi2O3 has 2.4 eV band gap energy, which means it absorb in visible region. Though the photocatalytic activity of Bi2O3 is extremely little due to rapid rate of photogenerated electron-hole recombination. To face the economical and practical needs, the photocatalytic efficiency of Bi2O3 should be upgraded. In this paper, this was achieved by addition of neodymium to Bi2O3 nanosheets and Nd/Bi2O3 nanocomposites were prepared by a easy process at room temperature using a surfactant of Pluronic F127. The Bi2O3 nanosheets and Nd/Bi2O3 nanocomposites were investigated by many tools. The photocatalytic activity of Nd/Bi2O3 samples is better than Bi2O3 due to reduced band gap and reduced electron-hole recombination of Bi2O3 with addition of neodymium. In addition, Nd/Bi2O3 nanocomposites exhibit photocatalytic stability for hydrogen production which enables it to be reused on other occasions also.

Probing structural changes in Ca(1-x)Nd2x/3TiO3 ceramics by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Lowndes, Robert; Deluca, Marco; Azough, Feridoon; Freer, Robert

2013-01-01

Ceramics in the system Ca(1-x)Nd2x/3TiO3, intended for mobile communication applications, exhibit grossly non-linear variations in microwave dielectric properties with composition. There is evidence of a structural transition and the formation of vacancies on the A-site of the perovskite structure. High density, single phase perovskite Ca(1-x)Nd2x/3TiO3 ceramics have been prepared by the mixed oxide route. Raman spectroscopy was used to investigate the structural variations, which impact on dielectric properties. The Raman spectra show that with increasing Nd content, there is a transition from an ordered structure, to a disordered arrangement of cations and vacancies, and back to an ordered arrangement in Ca0.1Nd0.6TiO3. A structural phase transition from orthorhombic Pbnm to monoclinic C2/m coincides with the order-disorder transition at Ca0.1Nd0.6TiO3. Polarized Raman spectroscopy facilitated the assignment of the Raman modes and investigation of the role of importance of domain structures. Large variation in the plane angles was attributed to differences in domain structures. Differences in the angular dependence of the Raman modes with Nd content reflect changes in the preferred orientation of the domains from lamellar twins, to wedge shaped and back to lamellar twins.

Bond-selective photodissociation of partially deuterated ammonia molecules: Photodissociations of vibrationally excited NHD2 in the 5νNH state and NH2D in the 5νND state

NASA Astrophysics Data System (ADS)

Akagi, Hiroshi; Yokoyama, Keiichi; Yokoyama, Atsushi

2004-03-01

Ultraviolet photodissociation of NHD2 excited to the fourth overtone state of the NH stretching mode (5νNH) and NH2D excited to that of the ND stretching mode (5νND) has been investigated by using a crossed laser and molecular beams method. Branching ratio between the NH and ND bond dissociations has been determined by utilizing a (2+1) resonance enhanced multiphoton ionization scheme of H and D atoms. For the photolysis of NHD2 in the 5νNH state, the NH dissociation cross section is 5.1±1.4 times as large as the ND dissociation cross section per bond. On the other hand, for the photolysis of NH2D in the 5νND state, the ratio of the NH dissociation cross section per bond to the ND dissociation cross section decreases to 0.68±0.16. In comparison with the branching ratios for the photolysis of vibrationally unexcited NH2D and NHD2 [Koda and Back, Can. J. Chem. 55, 1380 (1977)], the present results indicate that the excitation of the NH stretching mode enhances the NH dissociation with ca. two times larger NH/ND branching ratio, whereas the excitation of the ND stretching mode results in the preferential ND dissociation with ca. 3-4 times larger ND/NH branching ratio than that for the vibrational ground states. The mechanism of the bond-selective enhancement has been discussed in terms of the energetics and dynamics of wave packet.

Magnetic Force Microscopy Investigation of Magnetic Domains in Nd2Fe14B

NASA Astrophysics Data System (ADS)

Talari, Mahesh Kumar; Markandeyulu, G.; Rao, K. Prasad

2010-07-01

Remenance and coercivity in Nd2Fe14B materials are strongly dependent on the microstructural aspects like phases morphology and grain size. The coercivity (Hc) of a magnetic material varies inversely with the grain size (D) and there is a critical size below which Hc∝D6. Domain wall pinning by grain boundaries and foreign phases is the important mechanism in explaining the improvement in coercivity and remenance. Nd2Fe14B intermetallic compound with stochiometric composition was prepared from pure elements (Nd -99.5%, Fe—99.95%, B -99.99%) by arc melting in argon atmosphere. Magnetic Force Microscope (MFM) gives high-resolution magnetic domain structural information of ferromagnetic samples. DI-3100 Scanning Probe Microscope with MESP probes was used For MFM characterization of the samples. Magnetic domains observed in cast ingots were very long (up to 40 μm were observed) and approximately 1-5 μm wide due to high anisotropy of the compounds. Magnetic domains have displayed different image contrast and morphologies at different locations of the samples. The domain morphologies and image contrast obtained in this analysis were explained in this paper.

Structural and magnetic properties of RTiNO{sub 2} (R=Ce, Pr, Nd) perovskite nitride oxides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porter, Spencer H.; Huang, Zhenguo, E-mail: zhenguo@uow.edu.au; Cheng, Zhenxiang

2015-03-15

Neutron powder diffraction indicates that CeTiNO{sub 2} and PrTiNO{sub 2} crystallize with orthorhombic Pnma symmetry (Ce: a=5.5580(5), b=7.8369(7), and c=5.5830(4) Å; Pr: a=5.5468(5), b=7.8142(5), and c=5.5514(5) Å) as a result of a{sup –}b{sup +}a{sup –} tilting of the titanium-centered octahedra. Careful examination of the NPD data, confirms the absence of long range anion order in both compounds, while apparent superstructure reflections seen in electron diffraction patterns provide evidence for short range anion order. Inverse magnetic susceptibility plots reveal that the RTiNO{sub 2} (R=Ce, Pr, Nd) compounds are paramagnetic with Weiss constants that vary from −28 to −42 K. Effective magneticmore » moments for RTiNO{sub 2} (R=Ce, Pr, Nd) are 2.43 μ{sub B}, 3.63 μ{sub B}, and 3.47 μ{sub B}, respectively, in line with values expected for free rare-earth ions. Deviations from Curie–Weiss behavior that occur below 150 K for CeTiNO{sub 2} and below 30 K for NdTiNO{sub 2} are driven by magnetic anisotropy, spin–orbit coupling, and crystal field effects. - Graphical abstract: The structure and magnetism of the oxide nitride perovskites RTiNO{sub 2} (R=Ce, Pr, Nd) have been explored. The average symmetry is shown to be Pnma with a random distribution of oxide and nitride ions and a{sup −}b{sup +}a{sup −} tilting of the titanium-centered octahedra, but electron diffraction shows evidence for short range anion order. All three compounds are paramagnetic but deviations from the Curie Weiss law are seen below 150 K for R=Ce and below 30 K for R=Nd. - Highlights: • The oxide nitride perovskites RTiNO{sub 2} (R=Ce, Pr) have been prepared and their structures determined. • Diffraction measurements indicate short range cis-order of O and N, but no long range order. • Compounds are paramagnetic with Weiss constants that vary from −28 to −42 K. • CeTiO{sub 2}N and NdTiO{sub 2}N deviate from Curie–Weiss behavior below 150 and 30 K

Ultra-short wavelength operation in Thulium-doped silica fiber laser with bidirectional pumping

NASA Astrophysics Data System (ADS)

Xiao, Xusheng; Guo, Haitao; Yan, Zhijun; Wang, Hushan; Xu, Yantao; Lu, Min; Wang, Yishan; Peng, Bo

2017-02-01

An ultra-short wavelength operation of Tm-doped all fiber laser based on fiber Bragg gratings (FBGs) was developed. A bi-directional pump configuration for the ultra-short wavelength operation was designed and investigated for the first time. the laser yielded 3.15W of continuous-wave output at 1706.75nm with a narrow-linewidth of 50pm and a maximum slope efficiency of 42.1%. The dependencies of the slope efficiencies and pump threshold of the laser versus the length of active fiber and reflectivity of the output mirror (FBG) were investigated in detail. An experimental comparative study between two Thulium-doped fiber lasers (TDFLs) with two different pumping configuration(forward unidirectional pumping and bidirectional pumping) was presented. It is indisputable that the development of 1.7μm silicate fiber lasers with Watt-level output power open up a number of heart-stirring and tempting application windows.

Stratified NH and ND emission in the prestellar core 16293E in L1689N

NASA Astrophysics Data System (ADS)

Bacmann, A.; Daniel, F.; Caselli, P.; Ceccarelli, C.; Lis, D.; Vastel, C.; Dumouchel, F.; Lique, F.; Caux, E.

2016-03-01

Context. High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or molecule formation pathways. Whereas a large number of observations are available regarding interstellar deuterated stable molecules, relatively little is known about the deuteration of hydride radicals, as their fundamental rotational transitions are at high frequencies where the atmosphere is mostly opaque. Aims: Nitrogen hydride radicals are important species in nitrogen chemistry, as they are thought to be related to ammonia formation. Observations have shown that ammonia is strongly deuterated, with [NH2D]/[NH3] ~ 10%. Models predict similarly high [ND]/[NH] ratios, but so far only one observational determination of this ratio is available, towards the envelope of the protostar IRAS16293-2422. To test model predictions, we aim here to determine [ND]/[NH] in a dense, starless core. Methods: We observed NH and ND in 16293E with the HIFI spectrometer on board the Herschel Space Observatory as part of the CHESS guaranteed time key programme, and derived the abundances of these two species using a non local thermodynamic equilibrium radiative transfer model. Results: Both NH and ND are detected in the source, with ND in emission and NH in absorption against the continuum that arises from the cold dust emission. Our model shows, however, that the ND emission and the NH absorption originate from different layers in the cloud, as further evidenced by their different velocities. In the central region of the core, we can set a lower limit to the [ND]/[NH] ratio of ≳2%. This estimate is consistent with recent pure gas-phase models of nitrogen chemistry. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

Photocatalytic Water Splitting for O2 Production under Visible Light Irradiation Using NdVO4-V2O5 Hybrid Powders

PubMed Central

Chiang, Tzu Hsuan; Chen, Tso-Ming

2017-01-01

The study investigated photocatalytic water splitting for O2 production under visible light irradiation using neodymium vanadium oxide (NdVO4) and vanadium oxide (V2O5) hybrid powders. The results in a sacrificial agent of 0.01 M AgNO3 solution were obtained, and the highest photocatalytic O2 evolution was 2.63 μmol/h, when the hybrid powders were prepared by mixing Nd and V at a volume ratio of 1:3 at a calcination temperature of 350 °C for 1 h. The hybrid powders were synthesized by neodymium nitrate and ammonium metavanadate using the glycothermal method in ethylene glycol at 120 °C for 1 h. The hybrid powders consisted of two shapes, NdVO4 nanoparticles and the cylindrical V2O5 particles, and they possessed the ability for photocatalytic oxygen (O2) evolution during irradiation with visible light. The band gaps and structures of the hybrid powders were analyzed using UV-visible spectroscopy and transmission electron microscopy. PMID:28772692

Low threshold diode-pumped picosecond mode-locked Nd:YAG laser with a semiconductor saturable absorber mirror

NASA Astrophysics Data System (ADS)

Eshghi, M. J.; Majdabadi, A.; Koohian, A.

2017-01-01

In this paper, a low threshold diode pumped passively mode-locked Nd:YAG laser has been demonstrated by using a semiconductor saturable absorber mirror. The threshold power for continuous-wave mode-locking is relatively low, about 3.2 W. The resonator stability across the pump power has been analytically examined. Moreover, the mode overlap between the pump beam and the laser fundamental mode has been simulated by MATLAB software. Adopting Z-shaped resonator configuration and suitable design of the resonator’s arm lengths, has enabled the author to prepare mode-locking conditions, and obtain 40 ps pulses with 112 MHz pulse repetition rate. The laser output was stable without any Q switched instability. To the best of our knowledge, this is the lowest threshold for CW mode-locking operation of a Nd:YAG laser.

Efficient laser operation of Nd3+:Lu2O3 at various wavelengths between 917 nm and 1463 nm

NASA Astrophysics Data System (ADS)

von Brunn, P.; Heuer, A. M.; Fornasiero, L.; Huber, G.; Kränkel, C.

2016-08-01

Even though the first Nd3+-doped sesquioxide lasers have been realized more than 50 years ago, up to now no reports on efficient laser operation of Nd3+:doped sesquioxides can be found. In this work, we review the favorable spectroscopic properties of the sesquioxide Nd3+:Lu2O3 in terms of ground state absorption, stimulated emission, and excited state absorption cross sections as well as the upper level lifetime. Making use of these properties, we achieved efficient laser performance on eight different laser transitions in the wavelength range between 917 nm and 1463 nm under Ti:sapphire laser pumping using state-of-the-art HEM-grown Nd3+:Lu2O3 crystals with good optical quality. At the strongest transition around 1076 nm we determined a slope efficiency of 69%, which represents the highest efficiency ever obtained for a Nd3+-doped sesquioxide. Furthermore, we could generate watt level output powers and high slope efficiencies for seven other transitions. Lasers at 917 nm, 1053 nm, 1108 nm and 1463 nm were realized for the first time and the latter represents one of the longest laser wavelengths obtained on the 4F3/2  →  4I13/2 transition in Nd3+-doped materials.

Effect of CO2, Nd:YAG and Er:YAG Lasers on Microtensile Bond Strength of Composite to Bleached-Enamel.

PubMed

Basir, Mahshid Mohammadi; Rezvani, Mohammad Bagher; Chiniforush, Nasim; Moradi, Zohreh

2016-01-01

Tooth restoration immediately after bleaching is challenging due to the potential problems in achieving adequate bond strength. The aim of this study was to evaluate the effect of surface treatment with ER:YAG, ND:YAG, CO2 lasers and 10% sodium ascorbate solution on immediate microtensile bond strength of composite resin to recently bleached enamel. Ninety sound molar teeth were randomly divided into three main groups (n:30) : NB (without bleaching), HB (bleached with 38% carbamide peroxide) and OB (bleached with Heydent bleaching gel assisted by diode laser). Each group was divided into five subgroups (n:6) : Si (without surface treatment), Er (Er:YAG laser), CO2 (CO2 laser), Nd (Nd:YAG laser) and As (Immersion in 10% sodium ascorbate solution). The bonding system was then applied and composite build-ups were constructed. The teeth were sectioned by low speed saw to obtain enamel- resin sticks and submitted to microtensile bond testing. Statistical analyses were done using two- way ANOVA, Tukey and Tamhane tests. µTBS of bleached teeth irradiated with ND:YAG laser was not significantly different from NB-Nd group. Microtensile bond strength of OB-Er group was higher than NB-Er and HB-Er groups. The mean µTBS of HB-CO2 group was higher than NB-CO2 group; the average µTBS of HB-As and OB-As groups was also higher than NB-As group. Use of Nd:YAG, CO2 lasers and 10% sodium ascorbate solution could improve the bond strength in home-bleached specimens. Application of ND:YAG laser on nonbleached specimens and Er:YAG laser on office-bleached specimens led to the highest µTBS in comparison to other surface treatments in each main group.

Reemission spectra and interference effects at the interaction of multiatomic targets with ultrashort electromagnetic pulses

NASA Astrophysics Data System (ADS)

Matveev, V. I.; Matrasulov, D. U.

2013-01-01

The processes of reemission of ultrashort electromagnetic pulses by linear chains consisting of isolated multielectron atoms have been considered. The developed method makes it possible to accurately take into account the spatial inhomogeneity of the field of an ultrashort pulse and the momenta of photons in reemission processes. The angular distributions of reemission spectra have been obtained for an arbitrary number of atoms in a chain. It has been shown that the interference of the photon emission amplitudes leads to the appearance of characteristic "diffraction" maxima. The results allow standard generalization to the cases of rescattering from two-dimensional (graphene-like) and three-dimensional lattices, as well as to the case of the inclusion of thermal vibrations of the atoms of lattices.

Characterization of a fused protein specified by the adenovirus type 2-simian virus 40 hybrid Ad2+ND1 dp2.

PubMed Central

Fey, G; Lewis, J B; Grodzicker, T; Bothwell, A

1979-01-01

The adenovirus type 2-simian virus 40 (SV40) hybrid virus Ad2+ND1 dp2 (E. Lukanidin, manuscript in preparation) specified two proteins (molecular weights, 24,000 and 23,000) that are, in part, products of an insertion of SV40 early DNA sequences. This was demonstrated by translation in vitro from viral mRNA that had been selected by hybridization to SV40 DNA. These two phosphorylated, nonvirion proteins were produced late in infection in amounts similar to adenovirus 2 structural proteins and were closely related to each other in tryptic peptide composition. The portion of SV40 DNA (map units 0.17 to 0.22 on the SV40 genome) coding for these proteins was joined to sequences coding for the amino-terminal part of the adenovirus type 2 structural protein IV (fiber). The Ad2+ND1 dp2 23,000- and 24,000-molecular-weight proteins were hybrid polypeptides, with about two-thirds of their tryptic peptides contributed by the fiber protein and the remainder contributed by SV40 T-antigen. They shared with T-antigen (molecular weight, 96,000) a carboxy-terminal proline-rich tryptic peptide. Together, the tryptic peptide composition of these proteins and the known SV40 DNA sequences suggested the reading frame for the translation of T-antigen. The carboxy terminus for T-anigen would then be located on the SV40 genome map next to the TAA terminator triplet at position 0.175, 910 bases away from the cleavage site of the restriction endonuclease EcoRI. Seven host range mutants from Ad2+ND1 dp2 were isolated that had lost the capacity to propagate on monkey cells. They did not induce detectable levels of the hybrid proteins. Three of these mutants had lost the SV40 DNA insertion that codes in part for these proteins. Thus, in analogy to the Ad2+ND1 30,000-molecular-weight protein, the presence of these proteins correlates with the presence of the helper function for adenovirus replication on monkey cells. Images PMID:225516

Scoping analysis of the Advanced Test Reactor using SN2ND

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolters, E.; Smith, M.; SC)

2012-07-26

A detailed set of calculations was carried out for the Advanced Test Reactor (ATR) using the SN2ND solver of the UNIC code which is part of the SHARP multi-physics code being developed under the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program in DOE-NE. The primary motivation of this work is to assess whether high fidelity deterministic transport codes can tackle coupled dynamics simulations of the ATR. The successful use of such codes in a coupled dynamics simulation can impact what experiments are performed and what power levels are permitted during those experiments at the ATR. The advantages of themore » SN2ND solver over comparable neutronics tools are its superior parallel performance and demonstrated accuracy on large scale homogeneous and heterogeneous reactor geometries. However, it should be noted that virtually no effort from this project was spent constructing a proper cross section generation methodology for the ATR usable in the SN2ND solver. While attempts were made to use cross section data derived from SCALE, the minimal number of compositional cross section sets were generated to be consistent with the reference Monte Carlo input specification. The accuracy of any deterministic transport solver is impacted by such an approach and clearly it causes substantial errors in this work. The reasoning behind this decision is justified given the overall funding dedicated to the task (two months) and the real focus of the work: can modern deterministic tools actually treat complex facilities like the ATR with heterogeneous geometry modeling. SN2ND has been demonstrated to solve problems with upwards of one trillion degrees of freedom which translates to tens of millions of finite elements, hundreds of angles, and hundreds of energy groups, resulting in a very high-fidelity model of the system unachievable by most deterministic transport codes today. A space-angle convergence study was conducted to determine the meshing and angular cubature

Selective laser melting of hypereutectic Al-Si40-powder using ultra-short laser pulses

NASA Astrophysics Data System (ADS)

Ullsperger, T.; Matthäus, G.; Kaden, L.; Engelhardt, H.; Rettenmayr, M.; Risse, S.; Tünnermann, A.; Nolte, S.

2017-12-01

We investigate the use of ultra-short laser pulses for the selective melting of Al-Si40-powder to fabricate complex light-weight structures with wall sizes below 100 μ {m} combined with higher tensile strength and lower thermal expansion coefficient in comparison to standard Al-Si alloys. During the cooling process using conventional techniques, large primary silicon particles are formed which impairs the mechanical and thermal properties. We demonstrate that these limitations can be overcome using ultra-short laser pulses enabling the rapid heating and cooling in a non-thermal equilibrium process. We analyze the morphology characteristics and micro-structures of single tracks and thin-walled structures depending on pulse energy, repetition rate and scanning velocity utilizing pulses with a duration of 500 {fs} at a wavelength of 1030 {nm}. The possibility to specifically change and optimize the microstructure is shown.

Effects of thickness and annealing condition on magnetic properties and thermal stabilities of Ta/Nd/NdFeB/Nd/Ta sandwiched films

NASA Astrophysics Data System (ADS)

Liu, Wen-Feng; Zhang, Min-Gang; Zhang, Ke-Wei; Zhang, Hai-Jie; Xu, Xiao-Hong; Chai, Yue-Sheng

2016-11-01

Ta/Nd/NdFeB/Nd/Ta sandwiched films are deposited by magnetron sputtering on Si (100) substrates, and subsequently annealed in vacuum at different temperatures for different time. It is found that both the thickness of NdFeB and Nd layer and the annealing condition can affect the magnetic properties of Ta/Nd/NdFeB/Nd/Ta films. Interestingly, the thickness and annealing temperature show the relevant behaviors that can affect the magnetic properties of the film. The high coercivity of 24.1 kOe (1 Oe = 79.5775 A/m) and remanence ratio (remanent magnetization/saturation magnetization) of 0.94 can be obtained in a Ta/Nd(250 nm)/NdFeB(600 nm)/Nd(250 nm)/Ta film annealed for 3 min at 1023 K. In addition, the thermal stability of the film is also linked to the thickness of NdFeB and Nd layer and the annealing temperature as well. The excellent thermal stability can be achieved in a Ta/Nd(250 nm)/NdFeB(600 nm)/Nd(250 nm)/Ta film annealed at 1023 K. Program supported by the National Natural Science Foundation of China (Grant No. 51305290), the Higher Education Technical Innovation Project of Shanxi Province, China (Grant No. 2013133), the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals of Shanxi Province, China (Grant No. 2015003), and the Program for the Key Team of Scientific and Technological Innovation of Shanxi Province, China (Grant No. 2013131009).

X-ray absorption studies of gamma irradiated Nd doped phosphate glass

NASA Astrophysics Data System (ADS)

Rai, V. N.; Rajput, Parasmani; Jha, S. N.; Bhattacharyya, D.

2015-06-01

This paper presents the X-ray absorption near edge structure (XANES) studies of Nd doped phosphate glasses before and after gamma irradiation. The intensity and location of LIII edge white line peak of Nd changes depending on its concentration as well as on the ratio of O/Nd in the glass matrix. The decrease in the peak intensity of white line after gamma irradiation indicates towards reduction of Nd3+ to Nd2+ in the glass matrix, which increases with an increase in the doses of gamma irradiation. Similarity in the XANES spectra of Nd doped phosphate glasses and Nd2O3 suggests that coordination geometry around Nd3+ in glass samples may be identical to that of Nd2O3.

Induced emission cross section of a possible laser line in Nd:Y2O3 ceramics at 1.095 μm

NASA Astrophysics Data System (ADS)

Fukabori, Akihiro; Sekita, Masami; Ikegami, Takayasu; Iyi, Nobuo; Komatsu, Toshiki; Kawamura, Masayuki; Suzuki, Makoto

2007-02-01

In this study, we measured the change of the optical transmittance for calcination temperatures, in steps of 10°, at two different sintering temperatures. It was found that the optical transmittance is highly dependent on the calcination temperature. The highest optical transmittance obtained was 70% for the transparent Y2O3 (yttria) ceramics produced without the use of additives and high injection presure in this study, higher than the highest reported value of 65%. Optical absorption and emission spectra of Nd :Y2O3 obtained from a low temperature synthesis process were measured. The energy level structure of Nd3+ in the Y2O3 ceramics was determined for a 1mol% Nd concentration. The induced emission cross section was calculated to be in the range of 3.2×10-19-1.1×10-17cm2 for the 1mol% Nd-doped Y2O3 ceramics. Furthermore, a laser line possibly has been identified in this study, in the Nd :Y2O3 ceramic at 1.095μm.

Ultrashort pulse laser processing of hard tissue, dental restoration materials, and biocompatibles

NASA Astrophysics Data System (ADS)

Yousif, A.; Strassl, M.; Beer, F.; Verhagen, L.; Wittschier, M.; Wintner, E.

2007-07-01

During the last few years, ultra-short laser pulses have proven their potential for application in medical tissue treatment in many ways. In hard tissue ablation, their aptitude for material ablation with negligible collateral damage provides many advantages. Especially teeth representing an anatomically and physiologically very special region with less blood circulation and lower healing rates than other tissues require most careful treatment. Hence, overheating of the pulp and induction of microcracks are some of the most problematic issues in dental preparation. Up till now it was shown by many authors that the application of picosecond or femtosecond pulses allows to perform ablation with very low damaging potential also fitting to the physiological requirements indicated. Beside the short interaction time with the irradiated matter, scanning of the ultra-short pulse trains turned out to be crucial for ablating cavities of the required quality. One main reason for this can be seen in the fact that during scanning the time period between two subsequent pulses incident on the same spot is so much extended that no heat accumulation effects occur and each pulse can be treated as a first one with respect to its local impact. Extension of this advantageous technique to biocompatible materials, i.e. in this case dental restoration materials and titanium plasma-sprayed implants, is just a matter of consequence. Recently published results on composites fit well with earlier data on dental hard tissue. In case of plaque which has to be removed from implants, it turns out that removal of at least the calcified version is harder than tissue removal. Therefore, besides ultra-short lasers, also Diode and Neodymium lasers, in cw and pulsed modes, have been studied with respect to plaque removal and sterilization. The temperature increase during laser exposure has been experimentally evaluated in parallel.

Refraction data survey: 2nd generation correlation of myopia.

PubMed

Greene, Peter R; Medina, Antonio

2016-10-01

The objective herein is to provide refraction data, myopia progression rate, prevalence, and 1st and 2nd generation correlations, relevant to whether myopia is random or inherited. First- and second-generation ocular refraction data are assembled from N = 34 families, average of 2.8 children per family. From this group, data are available from N = 165 subjects. Inter-generation regressions are performed on all the data sets, including correlation coefficient r, and myopia prevalence [%]. Prevalence of myopia is [M] = 38.5 %. Prevalence of high myopes with |R| >6 D is [M-] = 20.5 %. Average refraction is  = -1.84 D ± 3.22 (N = 165). For the high myopes, |R| >6 D, prevalence for the parents is [M-] = 25 %, for the 2nd generation [M-] = 16.5 %. Average myopia level for the high myopes, both generations, is  = -7.52 D ± 1.31 D (N = 33). Regression parameters are calculated for all the data sets, yielding correlation coefficients in the range r = 0.48-0.72 for some groups of myopes and high myopes, fathers to daughters, and mothers to sons. Also of interest, some categories show essentially no correlation, -0.20 < r < 0.20, indicating that the refractive errors occur randomly. Time series results show myopia diopter rates = -0.50 D/year.