Optical and ultraviolet spectroscopic analysis of SN 2011fe at late times

NASA Astrophysics Data System (ADS)

Friesen, Brian; Baron, E.; Parrent, Jerod T.; Thomas, R. C.; Branch, David; Nugent, Peter E.; Hauschildt, Peter H.; Foley, Ryan J.; Wright, Darryl E.; Pan, Yen-Chen; Filippenko, Alexei V.; Clubb, Kelsey I.; Silverman, Jeffrey M.; Maeda, Keiichi; Shivvers, Isaac; Kelly, Patrick L.; Cohen, Daniel P.; Rest, Armin; Kasen, Daniel

2017-05-01

We present optical spectra of the nearby Type Ia supernova SN 2011fe at 100, 205, 311, 349 and 578 d post-maximum light, as well as an ultraviolet (UV) spectrum obtained with the Hubble Space Telescope at 360 d post-maximum light. We compare these observations with synthetic spectra produced with the radiative transfer code phoenix. The day +100 spectrum can be well fitted with models that neglect collisional and radiative data for forbidden lines. Curiously, including these data and recomputing the fit yields a quite similar spectrum, but with different combinations of lines forming some of the stronger features. At day +205 and later epochs, forbidden lines dominate much of the optical spectrum formation; however, our results indicate that recombination, not collisional excitation, is the most influential physical process driving spectrum formation at these late times. Consequently, our synthetic optical and UV spectra at all epochs presented here are formed almost exclusively through recombination-driven fluorescence. Furthermore, our models suggest that the UV spectrum even as late as day +360 is optically thick and consists of permitted lines from several iron-peak species. These results indicate that the transition to the 'nebular' phase in Type Ia supernovae is complex and highly wavelength dependent.

Optical and ultraviolet spectroscopic analysis of SN 2011fe at late times

DOE PAGES

Friesen, Brian; Baron, E.; Parrent, Jerod T.; ...

2017-02-27

This paper presents optical spectra of the nearby Type Ia supernova SN 2011fe at 100, 205, 311, 349 and 578 d post-maximum light, as well as an ultraviolet (UV) spectrum obtained with the Hubble Space Telescope at 360 d post-maximum light. We compare these observations with synthetic spectra produced with the radiative transfer code PHOENIX. The day +100 spectrum can be well fitted with models that neglect collisional and radiative data for forbidden lines. Curiously, including these data and recomputing the fit yields a quite similar spectrum, but with different combinations of lines forming some of the stronger features. Atmore » day +205 and later epochs, forbidden lines dominate much of the optical spectrum formation; however, our results indicate that recombination, not collisional excitation, is the most influential physical process driving spectrum formation at these late times. Consequently, our synthetic optical and UV spectra at all epochs presented here are formed almost exclusively through recombinationdriven fluorescence. Furthermore, our models suggest that the UV spectrum even as late as day +360 is optically thick and consists of permitted lines from several iron-peak species. These results indicate that the transition to the 'nebular' phase in Type Ia supernovae is complex and highly wavelength dependent.« less

Visual modelling suggests a weak relationship between the evolution of ultraviolet vision and plumage coloration in birds.

PubMed

Lind, O; Delhey, K

2015-03-01

Birds have sophisticated colour vision mediated by four cone types that cover a wide visual spectrum including ultraviolet (UV) wavelengths. Many birds have modest UV sensitivity provided by violet-sensitive (VS) cones with sensitivity maxima between 400 and 425 nm. However, some birds have evolved higher UV sensitivity and a larger visual spectrum given by UV-sensitive (UVS) cones maximally sensitive at 360-370 nm. The reasons for VS-UVS transitions and their relationship to visual ecology remain unclear. It has been hypothesized that the evolution of UVS-cone vision is linked to plumage colours so that visual sensitivity and feather coloration are 'matched'. This leads to the specific prediction that UVS-cone vision enhances the discrimination of plumage colours of UVS birds while such an advantage is absent or less pronounced for VS-bird coloration. We test this hypothesis using knowledge of the complex distribution of UVS cones among birds combined with mathematical modelling of colour discrimination during different viewing conditions. We find no support for the hypothesis, which, combined with previous studies, suggests only a weak relationship between UVS-cone vision and plumage colour evolution. Instead, we suggest that UVS-cone vision generally favours colour discrimination, which creates a nonspecific selection pressure for the evolution of UVS cones. © 2015 European Society For Evolutionary Biology. Journal of Evolutionary Biology © 2015 European Society For Evolutionary Biology.

DichroCalc: Improvements in Computing Protein Circular Dichroism Spectroscopy in the Near-Ultraviolet.

PubMed

Jasim, Sarah B; Li, Zhuo; Guest, Ellen E; Hirst, Jonathan D

2017-12-16

A fully quantitative theory connecting protein conformation and optical spectroscopy would facilitate deeper insights into biophysical and simulation studies of protein dynamics and folding. The web server DichroCalc (http://comp.chem.nottingham.ac.uk/dichrocalc) allows one to compute from first principles the electronic circular dichroism spectrum of a (modeled or experimental) protein structure or ensemble of structures. The regular, repeating, chiral nature of secondary structure elements leads to intense bands in the far-ultraviolet (UV). The near-UV bands are much weaker and have been challenging to compute theoretically. We report some advances in the accuracy of calculations in the near-UV, realized through the consideration of the vibrational structure of the electronic transitions of aromatic side chains. The improvements have been assessed over a set of diverse proteins. We illustrate them using bovine pancreatic trypsin inhibitor and present a new, detailed analysis of the interactions which are most important in determining the near-UV circular dichroism spectrum. Copyright © 2018. Published by Elsevier Ltd.

Incorporation of multiple cloud layers for ultraviolet radiation modeling studies

NASA Technical Reports Server (NTRS)

Charache, Darryl H.; Abreu, Vincent J.; Kuhn, William R.; Skinner, Wilbert R.

1994-01-01

Cloud data sets compiled from surface observations were used to develop an algorithm for incorporating multiple cloud layers into a multiple-scattering radiative transfer model. Aerosol extinction and ozone data sets were also incorporated to estimate the seasonally averaged ultraviolet (UV) flux reaching the surface of the Earth in the Detroit, Michigan, region for the years 1979-1991, corresponding to Total Ozone Mapping Spectrometer (TOMS) version 6 ozone observations. The calculated UV spectrum was convolved with an erythema action spectrum to estimate the effective biological exposure for erythema. Calculations show that decreasing the total column density of ozone by 1% leads to an increase in erythemal exposure by approximately 1.1-1.3%, in good agreement with previous studies. A comparison of the UV radiation budget at the surface between a single cloud layer method and a multiple cloud layer method presented here is discussed, along with limitations of each technique. With improved parameterization of cloud properties, and as knowledge of biological effects of UV exposure increase, inclusion of multiple cloud layers may be important in accurately determining the biologically effective UV budget at the surface of the Earth.

Assessment of UV biological spectral weighting functions for phenolic metabolites and growth responses in silver birch seedlings.

PubMed

Kotilainen, Titta; Venäläinen, Tuulia; Tegelberg, Riitta; Lindfors, Anders; Julkunen-Tiitto, Riitta; Sutinen, Sirkka; O'Hara, Robert B; Aphalo, Pedro J

2009-01-01

In research concerning stratospheric ozone depletion, action spectra are used as biological spectral weighting functions (BSWFs) for describing the effects of UV radiation on plant responses. Our aim was to evaluate the appropriateness of six frequently used BSWFs that differ in effectiveness with increasing wavelength. The evaluation of action spectra was based on calculating the effective UV radiation doses according to 1-2) two formulations of the generalized plant action spectrum, 3) a spectrum for ultraviolet induced erythema in human skin, 4) a spectrum for the accumulation of a flavonol in Mesembryanthemum crystallinum, 5) a spectrum for DNA damage in alfalfa seedlings and 6) the plant growth action spectrum. We monitored effects of UV radiation on the concentration of individual UV absorbing metabolites and chlorophyll concentrations in leaves and growth responses of silver birch (Betula pendula) seedlings. Experiments were conducted outdoors using plastic films attenuating different parts of the UV spectrum. Chlorophyll concentrations and growth were not affected by the UV treatments. The response to UV radiation varied between and within groups of phenolics. In general, the observed responses of phenolic groups and individual flavonoids were best predicted by action spectra extending into the UV-A region with moderate effectiveness.

[The research of UV-responsive sensitivity enhancement of fluorescent coating films by MgF2 layer].

PubMed

Lu, Zhong-Rong; Ni, Zheng-Ji; Tao, Chun-Xian; Hong, Rui-Jin; Zhang, Da-Wei; Huang, Yuan-Shen

2014-03-01

A low cost and less complicated expansion approach of wavelength responses with a Lumogen phosphor coating was adopted, as they increased the quantum efficiency of CCD and CMOS detectors in ultra-violet by absorbing UV light and then re emitting visible light. In this paper, the sensitivity enhancement of fluorescence coatings was studied by adding an anti-reflection film or barrier film to reduce the loss of the scattering and reflection on the incident interface. The Lumogen and MgF2/Lumogen film were deposited on quartz glasses by physical vacuum deposition. The surface morphology, transmittance spectrum, reflectance spectrum and fluorescence emission spectrum were obtained by atomic force microscope (AFM), spectrophotometer and fluorescence spectrometer, respectively. The results indicated that MgF2 film had obvious positive effect on reducing scattering and reflection loss in 500-700 nm, and enhancing the absorption of Lumogen coating in ultraviolet spectrum. Meanwhile, the fluorescent emission intensity had a substantial increase by smoothing the film surface and thus reducing the light scattering. At the same time, the MgF2 layer could protect Lumogen coating from damaging and contamination, which give a prolong lifetime of the UV-responsive CCD sensors with fluorescent coatings.

Investigation of holmium-doped zirconium oxide ceramic phosphor as an ultraviolet wavelength-discriminating laser beam viewer

NASA Astrophysics Data System (ADS)

Yamanoi, Kohei; Hori, Tatsuhiro; Minami, Yuki; Empizo, Melvin John F.; Luong, Mui Viet; Shiro, Atsushi; Watanabe, Jun; Iwano, Keisuke; Iwasa, Yuki; Cadatal-Raduban, Marilou; Gabayno, Jacque Lynn; Shimizu, Toshihiko; Sarukura, Nobuhiko; Norimatsu, Takayoshi

2018-01-01

We report the fluorescence spectra of ZrO2 and trivalent Ho-doped ZrO2 ceramics under ultraviolet (UV) excitation at 213, 266, and 355 nm wavelengths. The Ho3+-doped ZrO2 ceramics exhibited varying fluorescence color tones depending on the excitation wavelength used. The different color tones match the fluorescence spectrum characteristics at each excitation wavelength. Our results demonstrate that Ho3+-doped ZrO2 ceramics can discriminate between UV light, specifically the third, fourth, and fifth harmonics of a Nd:YAG laser. It can potentially be used for developing UV laser beam viewers to aid laser alignment.

First ultraviolet reflectance measurements of several Kuiper Belt objects, Kuiper Belt object satellites, and new ultraviolet measurements of A Centaur

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stern, S. A.; Schindhelm, E.; Cunningham, N. J., E-mail: astern@swri.edu

We observed the 2600-3200 Å (hereafter, mid-UV) reflectance of two Kuiper Belt Objects (KBOs), two KBO satellites, and a Centaur, using the Hubble Space Telescope (HST) Cosmic Origins Spectrograph (COS). Other than measurements of the Pluto system, these constitute the first UV measurements obtained of KBOs, and KBO satellites, and new HST UV measurements of the Centaur 2060 Chiron. We find significant differences among these objects, constrain the sizes and densities of Haumea's satellites, and report the detection of a possible spectral absorption band in Haumea's spectrum near 3050 Å. Comparisons of these objects to previously published UV reflectance measurementsmore » of Pluto and Charon are also made here.« less

Spectral properties of plant leaves pertaining to urban landscape design of broad-spectrum solar ultraviolet radiation reduction

NASA Astrophysics Data System (ADS)

Yoshimura, Haruka; Zhu, Hui; Wu, Yunying; Ma, Ruijun

2010-03-01

Human exposure to harmful ultraviolet (UV) radiation has important public health implications. Actual human exposure to solar UV radiation depends on ambient UV irradiance, and the latter is influenced by ground reflection. In urban areas with higher reflectivity, UV exposure occurs routinely. To discover the solar UV radiation regulation mechanism of vegetation, the spectral reflectance and transmittance of plant leaves were measured with a spectrophotometer. Typically, higher plants have low leaf reflectance (around 5%) and essentially zero transmittance throughout the UV region regardless of plant species and seasonal change. Accordingly, incident UV radiation decreases to 5% by being reflected and is reduced to zero by passing through a leaf. Therefore, stratified structures of vegetation are working as another terminator of UV rays, protecting whole terrestrial ecosystems, while vegetation at waterfronts contributes to protect aquatic ecosystems. It is possible to protect the human population from harmful UV radiation by urban landscape design of tree shade and the botanical environment. Even thin but uniformly distributed canopy is effective in attenuating UV radiation. To intercept diffuse radiation, UV screening by vertical structures such as hedges should be considered. Reflectivity of vegetation is around 2%, as foliage surfaces reduce incident UV radiation via reflection, while also eliminating it by transmittance. Accordingly, vegetation reduces incident UV radiation to around 2% by reflection. Vegetation influence on ambient UV radiation is broad-spectrum throughout the UV region. Only trees provide cool UV protective shade. Urban landscapes aimed at abating urban heat islands integrated with a reduction of human UV over-exposure would contribute to mitigation of climate change.

Ultraviolet absorption spectrum of HOCl

NASA Technical Reports Server (NTRS)

Burkholder, James B.

1993-01-01

The room temperature UV absorption spectrum of HOCl was measured over the wavelength range 200 to 380 nm with a diode array spectrometer. The absorption spectrum was identified from UV absorption spectra recorded following UV photolysis of equilibrium mixtures of Cl2O/H2O/HOCl. The HOCl spectrum is continuous with a maximum at 242 nm and a secondary peak at 304 nm. The measured absorption cross section at 242 nm was (2.1 +/- 0.3) x 10 exp -19/sq cm (2 sigma error limits). These results are in excellent agreement with the work of Knauth et al. (1979) but in poor agreement with the more recent measurements of Mishalanie et al. (1986) and Permien et al. (1988). An HOCl nu2 infrared band intensity of 230 +/- 35/sq cm atm was determined based on this UV absorption cross section. The present results are compared with these previous measurements and the discrepancies are discussed.

Skylab

NASA Image and Video Library

1970-01-01

This 1970 photograph shows the Skylab's Ultraviolet (UV) Spectrograph, an Apollo Telescope Mount instrument. Its telescope, with camera and TV capability, photographed the Sun in selected ultraviolet wavelengths. The spectrograph was used to record the spectrum of UV emissions, such as flares or filaments, from a small individual feature on the solar disc. Real-time TV was used by the crew to monitor the performance of the telescope, transmit to the ground, and record. The exposed films were retrieved by astronaut extravehicular activities. The Marshall Space Flight Center had program management responsibility for the development of the Skylab hardware and experiments.

Skylab

NASA Image and Video Library

1973-01-01

This 1973 chart details Skylab's Ultraviolet (UV) Spectrograph, an Apollo Telescope Mount instrument. Its telescope, with camera and TV capability, photographed the Sun in selected ultraviolet wavelengths. The spectrograph was used to record the spectrum of UV emissions, such as flares or filaments, from a small individual feature on the solar disc. Real-time TV was used by the crew to monitor performance of the telescope, transmit to the ground and record. The exposed films were retrieved by astronaut extravehicular activities. The Marshall Space Flight Center had program management responsibility for the development of the Skylab hardware and experiments.

An estimation methode for measurement of ultraviolet radiation during nondestructive testing

NASA Astrophysics Data System (ADS)

Hosseinipanah, M.; Movafeghi, A.; Farvadin, D.

2018-04-01

Dye penetrant testing and magnetic particle testing are among conventional NDT methods. For increased sensitivity, fluorescence dyes and particles can be used with ultraviolet (black) lights. UV flaw detection lights have different spectra. With the help of photo-filters, the output lights are transferred to UV-A and visible zones. UV-A light can be harmful to human eyes in some conditions. In this research, UV intensity and spectrum were obtained by a Radio-spectrometer for two different UV flaw detector lighting systems. According to the standards such as ASTM E709, UV intensity must be at least 10 W/m2 at a distance of 30 cm. Based on our measurements; these features not achieved in some lamps. On the other hand, intensity and effective intensity of UV lights must be below the some limits for prevention of unprotected eye damage. NDT centers are usually using some type of UV measuring devices. A method for the estimation of effective intensity of UV light has been proposed in this research.

Inhibition of the Induced Formation of Tryptophanase in Escherichia coli by Near-Ultraviolet Radiation

PubMed Central

Swenson, P. A.; Setlow, R. B.

1970-01-01

Induced formation of tryptophanase in Escherichia coli B/r is temporarily inhibited by near-ultraviolet (UV) irradiation. The inhibition is greater when irradiation is at 5 C than when at room temperature. Hence, the inhibition is the result of a photochemical, rather than photoenzymatic, alteration of some cellular component. The action spectrum has a peak in the region of 334 nm and is similar to that for growth delay. However, inhibition of tryptophanase formation is more sensitive to near-UV irradiation than are growth, respiration, and the induced formation of β-galactosidase. Thus, for tryptophanase the lack of formation cannot be due to general inhibition of metabolism. Pyridoxal phosphate absorbs in the near-UV region of the spectrum and is a cofactor for tryptophanase, but this enzyme in induced cells is not inactivated by near UV-radiations. An experiment in which toluene-treated suspensions from irradiated and unirradiated cells were mixed showed that irradiation does not cause the formation of an inhibitor of tryptophanase activity. The possibility remains that the absorption of radiant energy by pyridoxal phosphate interferes with the synthesis of tryptophanase. PMID:4914082

Intrinsic Lyα Profile Reconstructions of the MUSCLES Low-Mass Exoplanet Host Stars

NASA Astrophysics Data System (ADS)

Youngblood, Allison A.; France, Kevin; Loyd, R. O. Parke

2015-12-01

UV stellar radiation can significantly impact planetary atmospheres through heating and photochemistry, even regulating production of potential biomarkers. Cool stars emit the majority of their UV radiation in the form of emission lines, and the incident UV radiation on close-in habitable-zone planets is significant. Lyα (1215.67 Å) dominates the 912 - 3200 Å spectrum of cool stars, but strong absorption from the interstellar medium (ISM) makes direct observations of the intrinsic Lyα emission of even nearby stars challenging. The MUSCLES Hubble Space Telescope Treasury Survey (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems) has completed observations of 7 M and 4 K stars hosting exoplanets (d < 22 pc). We have reconstructed the intrinsic Lyα profiles using an MCMC technique and used the results to estimate the extreme ultraviolet (100 - 911 Å) spectrum. We also present empirical relations between Lyα and chromospheric UV metal lines, e.g., Mg II, for use when ISM absorption prevents direct measurement of Lyα. The spectra presented here will be made publicly available through MAST to support exoplanet atmosphere modeling.

[Using ultraviolet-visible ( UV-Vis) absorption spectrum to estimate the dissolved organic matter (DOM) concentration in water, soils and sediments of typical water-level fluctuation zones of the Three Gorges Reservoir areas].

PubMed

Li, Lu-lu; Jiang, Tao; Lu, Song; Yan, Jin-long; Gao, Jie; Wei, Shi-qiang; Wang, Ding-yong; Guo, Nian; Zhao, Zhena

2014-09-01

Dissolved organic matter (DOM) is a very important component in terrestrial ecosystem. Chromophoric dissolved organic matter (CDOM) is a significant constituent of DOM, which can be measured by ultraviolet-visible (UV-Vis) absorption spectrum. Thus the relationship between CDOM and DOM was investigated and established by several types of models including single-wavelength model, double-wavelength model, absorption spectrum slope (S value) model and three-wavelength model, based on the UV-Vis absorption coefficients of soil and sediment samples (sampled in July of 2012) and water samples (sampled in November of 2012) respectively. The results suggested that the three-wavelength model was the best for fitting, and the determination coefficients of water, soil and sediment data were 0. 788, 0. 933 and 0. 856, respectively. Meanwhile, the nominal best model was validated with the UV-Vis data of 32 soil samples and 36 water samples randomly collected in 2013, showing the RRMSE and MRE were 16. 5% and 16. 9% respectively for soil DOM samples, 10. 32% and 9. 06% respectively for water DOM samples, which further suggested the prediction accuracy was higher in water DOM samples as compared with that in soil DOM samples.

Fine structural dependence of ultraviolet reflections in the King Penguin beak horn.

PubMed

Dresp, Birgitta; Langley, Keith

2006-03-01

The visual perception of many birds extends into the near-ultraviolet (UV) spectrum and ultraviolet is used by some to communicate. The beak horn of the King Penguin (Aptenodytes patagonicus) intensely reflects in the ultraviolet and this appears to be implicated in partner choice. In a preliminary study, we recently demonstrated that this ultraviolet reflectance has a structural basis, resulting from crystal-like photonic structures, capable of reflecting in the near-UV. The present study attempted to define the origin of the photonic elements that produce the UV reflectance and to better understand how the UV signal is optimized by their fine structure. Using light and electron microscopic analysis combined with new spectrophotometric data, we describe here in detail the fine structure of the entire King Penguin beak horn in addition to that of its photonic crystals. The data obtained reveal a one-dimensional structural periodicity within this tissue and demonstrate a direct relationship between its fine structure and its function. In addition, they suggest how the photonic structures are produced and how they are stabilized. The measured lattice dimensions of the photonic crystals, together with morphological data on its composition, permit predictions of the wavelength of reflected light. These correlate well with experimentally observed values. The way the UV signal is optimized by the fine structure of the beak tissue is discussed with regard to its putative biological role.

[Analysis of UV-visible absorption spectrum on the decolorization of industrial wastewater by disinfection].

PubMed

Huang, Xin; Wang, Long-Yong; Gao, Nai-Yun; Li, Wei-Guo

2012-10-01

The UV-Visible absorption spectrum of industrial wastewater was explored to introduce a substituting method determining the color of water, and to compare the decolorization efficacy of different disinfectants. The results show that the visible absorption spectrum(350-600 nm), instead of ultraviolet absorption spectrum, should be applied to characterize the color of wastewater. There is a good correlation between the features of visible absorption spectrum and the true color of wastewater. Both ozone and chlorine dioxide has a better decolorization performance than chlorine. However, the color of chlorine dioxide itself has a negative effect on decolorization. The changes in the features of visible absorption spectrum effectively reflect the variations in the color of wastewater after disinfection.

Protection of Nomex from Ultraviolet Degradation

DTIC Science & Technology

1977-03-01

absorbs UV radiation beginning at approximately 390 nano- meters (nm) and extending into the near UV with a peak at approximately 360 nm. This absorption is...the region near 290 nm [ 5 ]. Sunlight is much richer in radiation at 360 nm than at 290 nm and this fact undoubt- edly accounts for the much greater...function as UV screening agents. The absorption spectrum of Nomex in the near UV and visible region which is responsible for Nomex photodegra- dation is

Ultraviolet reflectance by the cere of raptors

PubMed Central

Mougeot, François; Arroyo, Beatriz E

2006-01-01

Ultraviolet (UV) signals have been shown to play key roles in social and sexual signalling in birds. Using a spectrophotometer, we analysed the colour of the cere (skin above the beak) of a diurnal raptor, the Montagu's harrier (Circus pygargus), and show that it reflects in the UV part of the spectrum. The cere is a well-known sexual signal in raptors, with carotenoid based pigmentation being indicative of quality. We thus hypothesized that UV reflectance also signals quality. Accordingly, we found that in our sample of wild males, the location of the UV peak was related to the orangeness of cere and correlated with male body mass and condition (mass corrected for size). Also, males with brighter UV were mated to females that laid earlier, as expected if UV reflectance relates to a male's quality and attractiveness. Future studies should investigate the relationships between UV reflectance and carotenoid pigmentation of cere, and test how UV reflectance influences mate choice. PMID:17148356

Ultraviolet reflecting photonic microstructures in the King Penguin beak.

PubMed

Dresp, Birgitta; Jouventin, Pierre; Langley, Keith

2005-09-22

King and emperor penguins (Aptenodytes patagonicus and Aptenodytes forsteri) are the only species of marine birds so far known to reflect ultraviolet (UV) light from their beaks. Unlike humans, most birds perceive UV light and several species communicate using the near UV spectrum. Indeed, UV reflectance in addition to the colour of songbird feathers has been recognized as an important signal when choosing a mate. The king penguin is endowed with several highly coloured ornaments, notably its beak horn and breast and auricular plumage, but only its beak reflects UV, a property considered to influence its sexual attraction. Because no avian UV-reflecting pigments have yet been identified, the origin of such reflections is probably structural. In an attempt to identify the structures that give rise to UV reflectance, we combined reflectance spectrophotometry and morphological analysis by both light and electron microscopy, after experimental removal of surface layers of the beak horn. Here, we characterize for the first time a multilayer reflector photonic microstructure that produces the UV reflections in the king penguin beak.

The UV Spectrum of the Ultracool Dwarf LSR J1835+3259 Observed with the Hubble Space Telescope

NASA Astrophysics Data System (ADS)

Saur, Joachim; Fischer, Christian; Wennmacher, Alexandre; Feldman, Paul D.; Roth, Lorenz; Strobel, Darrell F.; Reiners, Ansgar

2018-05-01

An interesting question about ultracool dwarfs recently raised in the literature is whether their emission is purely internally driven or partially powered by external processes similar to planetary aurora known from the solar system. In this work, we present Hubble Space Telescope observations of the energy fluxes of the M8.5 ultracool dwarf LSR J1835+3259 throughout the ultraviolet (UV). The obtained spectra reveal that the object is generally UV-fainter compared with other earlier-type dwarfs. We detect the Mg II doublet at 2800 Å and constrain an average flux throughout the near-UV. In the far-UV without Lyα, the ultracool dwarf is extremely faint with an energy output at least a factor of 250 smaller as expected from auroral emission physically similar to that on Jupiter. We also detect the red wing of the Lyα emission. Our overall finding is that the observed UV spectrum of LSR J1835+3259 resembles the spectrum of mid/late-type M-dwarf stars relatively well, but it is distinct from a spectrum expected from Jupiter-like auroral processes.

Dynamic evolution of the spectrum of long-period fiber Bragg gratings fabricated from hydrogen-loaded optical fiber by ultraviolet laser irradiation.

PubMed

Fujita, Keio; Masuda, Yuji; Nakayama, Keisuke; Ando, Maki; Sakamoto, Kenji; Mohri, Jun-pei; Yamauchi, Makoto; Kimura, Masanori; Mizutani, Yasuo; Kimura, Susumu; Yokouchi, Takashi; Suzaki, Yoshifumi; Ejima, Seiki

2005-11-20

Long-period fiber Bragg gratings fabricated by exposure of hydrogen-loaded fiber to UV laser light exhibit large-scale dynamic evolution for approximately two weeks at room temperature. During this time two distinct features show up in their spectrum: a large upswing in wavelength and a substantial deepening of the transmission minimum. The dynamic evolution of the transmission spectrum is explained quantitatively by use of Malo's theory of UV-induced quenching [Electron. Lett. 30, 442 (1994)] followed by refilling of hydrogen in the fiber core and the theory of hydrogen diffusion in the fiber material. The amount of hydrogen quenched by the UV irradiation is 6% of the loaded hydrogen.

The MUSCLES Treasury Survey: Intrinsic Lyα Profile Reconstructions and UV, X-ray, and Optical Correlations of Low-mass Exoplanet Host Stars

NASA Astrophysics Data System (ADS)

Youngblood, Allison; France, Kevin; Loyd, R. O. Parke

2016-01-01

UV stellar radiation can significantly impact planetary atmospheres through heating and photochemistry, even regulating production of potential biomarkers. Cool stars emit the majority of their UV radiation in the form of emission lines, and the incident UV radiation on close-in habitable-zone planets is significant. Lyα (1215.67 Å) dominates the 912 - 3200 Å spectrum of cool stars, but strong absorption from the interstellar medium (ISM) makes direct observations of the intrinsic Lyα emission of even nearby stars challenging. The MUSCLES Hubble Space Telescope Treasury Survey (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems) has completed observations of 7 M and 4 K stars hosting exoplanets (d < 22 pc) with simultaneous X-ray and ground-based optical spectroscopy for many of the targets. We have reconstructed the intrinsic Lyα profiles using an MCMC technique and used the results to estimate the extreme ultraviolet (100 - 911 Å) spectrum. We also present empirical relations between chromospheric UV and optical lines, e.g., Lyα, Mg II, Ca II H & K, and Hα, for use when direct UV observations of low-mass exoplanet host stars are not possible. The spectra presented here will be made publicly available through MAST to support exoplanet atmosphere modeling.

Detection of ultraviolet radiation using tissue equivalent radiochromic gel materials

NASA Astrophysics Data System (ADS)

Bero, M. A.; Abukassem, I.

2009-05-01

Ferrous Xylenol-orange Gelatin gel (FXG) is known to be sensitive to ionising radiation such as γ and X-rays. The effect of ionising radiation is to produce an increase in the absorption over a wide region of the visible spectrum, which is proportional to the absorbed dose. This study demonstrates that FXG gel is sensitive to ultraviolet radiation and therefore it could functions as UV detector. Short exposure to UV radiation produces linear increase in absorption measured at 550nm, however high doses of UV cause the ion indicator colour to fad away in a manner proportional to the incident UV energy. Light absorbance increase at the rate of 1.1% per minute of irradiation was monitored. The exposure level at which the detector has linear response is comparable to the natural summer UV radiation. Evaluating the UV ability to pass through tissue equivalent gel materials shows that most of the UV gets absorbed in the first 5mm of the gel materials, which demonstrate the damaging effects of this radiation type on human skin and eyes. It was concluded that FXG gel dosimeter has the potential to offer a simple, passive ultraviolet radiation detector with sensitivity suitable to measure and visualises the natural sunlight UV exposure directly by watching the materials colour changes.

How does solar ultraviolet-B radiation improve drought tolerance of silver birch (Betula pendula Roth.) seedlings?

PubMed

Robson, T Matthew; Hartikainen, Saara M; Aphalo, Pedro J

2015-05-01

We hypothesized that solar ultraviolet (UV) radiation would protect silver birch seedlings from the detrimental effects of water stress through a coordinated suite of trait responses, including morphological acclimation, improved control of water loss through gas exchange and hydraulic sufficiency. To better understand how this synergetic interaction works, plants were grown in an experiment under nine treatment combinations attenuating ultraviolet-A and ultraviolet-B (UVB) from solar radiation together with differential watering to create water-deficit conditions. In seedlings under water deficit, UV attenuation reduced height growth, leaf production and leaf length compared with seedlings receiving the full spectrum of solar radiation, whereas the growth and morphology of well-watered seedlings was largely unaffected by UV attenuation. There was an interactive effect of the treatment combination on water relations, which was more apparent as a change in the water potential at which leaves wilted or plants died than through differences in gas exchange. This suggests that changes occur in the cell wall elastic modulus or accumulation of osmolites in cells under UVB. Overall, the strong negative effects of water deficit are partially ameliorated by solar UV radiation, whereas well-watered silver birch seedlings are slightly disadvantaged by the solar UV radiation they receive. © 2014 John Wiley & Sons Ltd.

Reference ultraviolet wavelengths of CrIII measured by Fourier transform spectrometry

NASA Astrophysics Data System (ADS)

Smillie, D. G.; Pickering, J. C.; Smith, P. L.

2008-10-01

We report CrIII ultraviolet (UV) transition wavelengths measured using a high-resolution Fourier transform spectrometer (FTS), for the first time, available for use as wavelength standards. The doubly ionized iron group element spectra dominate the observed opacity of hot B stars in the UV, and improved, accurate, wavelengths are required for the analysis of astronomical spectra. The spectrum was excited using a chromium-neon Penning discharge lamp and measured with the Imperial College vacuum ultraviolet FTS. 140 classified 3d34s-3d34p CrIII transition lines, in the spectral range 38000 to 49000 cm-1 (2632 to 2041 Å), the strongest having wavelength uncertainties less than one part in 107, are presented.

Ultraviolet protective properties of branded and unbranded sunglasses available in the Indian market in UV phototherapy chambers.

PubMed

Dongre, Atul M; Pai, Gitanjali G; Khopkar, Uday S

2007-01-01

Patients receiving phototherapy for various dermatoses are at increased risk of eye damage due to ultraviolet (UV) rays. They are prescribed UV protective sunglasses by dermatologists but their exact protecting effects are not known. To study the ultraviolet protective properties of branded and unbranded UV protective sunglasses available in the Indian market, in UV phototherapy chambers. Sixteen different branded and unbranded UV protective sunglasses were collected from two opticians in Mumbai. Baseline irradiance of the UV chamber was calculated by exposing the photosensitive probe of UV photometer in the chamber. Then, the photosensitive probe of the UV photometer was covered with the UV protective glass to be studied and irradiance was noted. Such readings were taken for each of the UV protective sunglasses. The percentage reduction in the UV rays' penetration of different UV protective sunglasses was calculated. Thirteen sunglasses provided > 80% reduction in UVA rays penetration, of which four were branded (out of the four branded studied) and nine were unbranded (out of the 12 unbranded studied). More than 70% reduction in UVB penetration was provided by 12 sunglasses, which included 10 unbranded and two branded sunglasses. All branded sunglasses provided good protection against UVA penetration, but UVB protection provided by both branded and unbranded sunglasses was not satisfactory. A few unbranded sunglasses had poor efficacy for UVA and UVB spectra; one branded glass had poor efficacy for protection against the UVB spectrum. The efficacy of sunglasses used for phototherapy should be assessed before use.

A Search for Rarely Seen Ultraviolet Coma Emissions and New Species Upper Limits at Comet 67P/Churyumov-Gerasimenko Using the Rosetta-Alice Ultraviolet Spectrograph

NASA Astrophysics Data System (ADS)

Noonan, J.; Stern, S. A.; Parker, J. W.; Keeney, B. A.; Weaver, H. A., Jr.; Feldman, P.; Steffl, A.; Feaga, L. M.; Bertaux, J. L.

2017-12-01

The Alice far/extreme-UV spectrograph aboard Rosetta is one of three US instruments provided by NASA; it is the first UV spectrograph to reach any comet. Numerous scientific results have been obtained regarding 67P/Churyumov-Gerasimenko by this instrument. Here we summarize two new sets of results from a search for rarely appearing atomic and molecular spectral emission features and a grand sum spectrum allowing us to place new atomic and molecular neutral and ionized species upper limits in the comet's coma.

UV Timing and Spectroscopy of the Crab Nebula Pulsar

NASA Technical Reports Server (NTRS)

Gull, Theodore R.; Lunqvist, Peter; Sollerman, Jesper; Lindler, Don; Fisher, Richard R. (Technical Monitor)

2001-01-01

We have used the Hubble Space Telescope and Space Telescope Imaging Spectrograph to obtain Near Ultraviolet (NUV) (1600-3200 Angstroms) and Far Ultraviolet (FUV) (1140-1720 Angstroms) spectra and pulse profiles of the Crab Nebula's pulsar. The pulse period agrees well with the radio predictions. The NUV and FUV pulse profiles are little changed from the visible wavelength profile. Spectra obtained with the Nordic Optical Telescope were combined with the UV spectra for full coverage from 1140-9250Angstoms. Dereddening the spectrum with a standard extinction curve achieves a flat spectrum for E(B-V)=0.52, R=3.1. Lyman alpha absorption indicates a column density of 3.0=/-0.5 x 10(exp 21) cm -2, consistent with the E(B-V) of 0.52. The dereddened spectrum can be fitted by a power law with spectral index alpha=0.11+/-0.04. A broad, blueshifted absorption is seen in CIV (1550Angstroms), reaching a velocity of about 2500 kilometer per second.

Motility and gravitactic orientation of the flagellate, Euglena gracilis, impaired by artificial and solar UV-B radiation.

PubMed

Hader, D P; Liu, S M

1990-09-01

The effects of ultraviolet radiation on the gravitactic orientation of the freshwater flagellate, Euglena gracilis, were determined by a real time image analysis system. Both artificial UV radiation and solar radiation in a temperature-controlled growth chamber were employed. Histograms of gravitaxis showed that the degree of orientation decreased with increasing exposure time; this can be quantified using the Rayleigh test and upper quadrant summation. The effects of artificial UV radiation on the orientation are considerably stronger than those of solar radiation, probably because the radiation source emits higher fluence rates below 300 nm than found in solar radiation. The effects of monochromatic ultraviolet radiation on motility have been determined, and an action spectrum has been calculated.

Far Ultraviolet Spectroscopic Explorer Observations of the Seyfert 1.5 Galaxy NGC 5548 in a Low State

NASA Technical Reports Server (NTRS)

Brotherton, M. S.; Green, R. F.; Kriss, G. A.; Oegerle, W.; Kaiser, M. E.; Zheng, W.; Hutchings, J. B.; Fisher, Richard R. (Technical Monitor)

2001-01-01

We present far-ultraviolet spectra of the Seyfert 1.5 galaxy NGC 5548 obtained in 2000 June with the Far Ultraviolet Spectroscopic Explorer (FUSE). Our data span the observed wavelength range 915-1185 A at a resolution of approximately 20 km s(exp -1). The spectrum shows a weak continuum and emission from O VI (lambda)(lambda)1032, 1038, C III (lambda)977, and He II (lambda)1085. The FUSE data were obtained when the AGN (Active Galactic Nuclei) was in a low state, which has revealed strong, narrow O VI emission lines. We also resolve intrinsic, associated absorption lines of O VI and the Lyman series. Several distinct kinematic components are present, spanning a velocity range of approximately 0 to -1300 km s(exp -1) relative to systemic, with kinematic structure similar to that seen in previous observations of longer wavelength ultraviolet (UV) lines. We explore the relationships between the far-UV (ultraviolet) absorbers and those seen previously in the UV and X-rays. We find that the high-velocity UV absorption component is consistent with being low-ionization, contrary to some previous claims, and is consistent with its non-detection in high-resolution X-ray spectra. The intermediate velocity absorbers, at -300 to -400 km s(exp -1), show H I and O VI column densities consistent with having contributions from both a high-ionization X-ray absorber and a low-ionization UV absorber. No single far-UV absorbing component can be solely identified with the X-ray absorber.

Transmittance of tinted and UV-blocking disposable contact lenses.

PubMed

Harris, M G; Haririfar, M; Hirano, K Y

1999-03-01

Tinted and ultraviolet (UV)-blocking disposable contact lenses have become increasingly popular over the last decade. Wearers of UV-blocking contact lenses could benefit greatly by protecting their eyes from potential UV radiation damage. A Uvikon 930 dual beam spectrophotometer was used to measure three enhancement-tinted lenses (royal blue, evergreen, and aqua), two types of UV-blocking lenses, and two types of non-UV-blocking lenses. Enhancement-tinted lenses did show a decrease in transmittance at certain wavelengths on the visible spectrum, but they did not reduce the transmittance of UV radiation to the extent of the UV-blocking lenses designed specifically for this purpose.

[Experimental research of turbidity influence on water quality monitoring of COD in UV-visible spectroscopy].

PubMed

Tang, Bin; Wei, Biao; Wu, De-Cao; Mi, De-Ling; Zhao, Jing-Xiao; Feng, Peng; Jiang, Shang-Hai; Mao, Ben-Jiang

2014-11-01

Eliminating turbidity is a direct effect spectroscopy detection of COD key technical problems. This stems from the UV-visible spectroscopy detected key quality parameters depend on an accurate and effective analysis of water quality parameters analytical model, and turbidity is an important parameter that affects the modeling. In this paper, we selected formazine turbidity solution and standard solution of potassium hydrogen phthalate to study the turbidity affect of UV--visible absorption spectroscopy detection of COD, at the characteristics wavelength of 245, 300, 360 and 560 nm wavelength point several characteristics with the turbidity change in absorbance method of least squares curve fitting, thus analyzes the variation of absorbance with turbidity. The results show, In the ultraviolet range of 240 to 380 nm, as the turbidity caused by particle produces compounds to the organics, it is relatively complicated to test the turbidity affections on the water Ultraviolet spectra; in the visible region of 380 to 780 nm, the turbidity of the spectrum weakens with wavelength increases. Based on this, this paper we study the multiplicative scatter correction method affected by the turbidity of the water sample spectra calibration test, this method can correct water samples spectral affected by turbidity. After treatment, by comparing the spectra before, the results showed that the turbidity caused by wavelength baseline shift points have been effectively corrected, and features in the ultraviolet region has not diminished. Then we make multiplicative scatter correction for the three selected UV liquid-visible absorption spectroscopy, experimental results shows that on the premise of saving the characteristic of the Ultraviolet-Visible absorption spectrum of water samples, which not only improve the quality of COD spectroscopy detection SNR, but also for providing an efficient data conditioning regimen for establishing an accurate of the chemical measurement methods.

CuS/RGO hybrid photocatalyst for full solar spectrum photoreduction from UV/Vis to near-infrared light.

PubMed

Wu, Jie; Liu, Baibai; Ren, Zhenxing; Ni, Mengying; Li, Can; Gong, Yinyan; Qin, Wei; Huang, Yongli; Sun, Chang Q; Liu, Xinjuan

2018-05-01

To make full use of the solar energy, it remains a great challenge for semiconductor photocatalysts to harvest the full solar light spectrum from ultraviolet (UV) to visible even the near infrared (NIR) wavelength. Here we show firstly the CuS/RGO (reduced graphene oxide) hybrid photocatalyst synthesized via a microwave assisted method with full solar light (UV-Vis-NIR) active for efficient Cr(VI) reduction. The CuS/RGO displays high absorption and catalytic activity in the UV, visible and even the NIR light regions. As co-catalyst, RGO can separate and inhibit the recombination of charge carriers, consequently improving the catalytic activity. Only 1wt% RGO emersions can reduce 90% of Cr(VI) under the radiation of light over the full spectrum. Findings may provide a new strategy and substance to expand the utilization range of solar light from UV to visible even the NIR energy. Copyright © 2017. Published by Elsevier Inc.

Solar-blind ultraviolet optical system design for missile warning

NASA Astrophysics Data System (ADS)

Chen, Yu; Huo, Furong; Zheng, Liqin

2015-03-01

Solar-blind region of Ultraviolet (UV) spectrum has very important application in military field. The spectrum range is from 240nm to 280nm, which can be applied to detect the tail flame from approaching missile. A solar-blind UV optical system is designed to detect the UV radiation, which is an energy system. iKon-L 936 from ANDOR company is selected as the UV detector, which has pixel size 13.5μm x 13.5 μm and active image area 27.6mm x 27.6 mm. CaF2 and F_silica are the chosen materials. The original structure is composed of 6 elements. To reduce the system structure and improve image quality, two aspheric surfaces and one diffractive optical element are adopted in this paper. After optimization and normalization, the designed system is composed of five elements with the maximum spot size 11.988μ m, which is less than the pixel size of the selected CCD detector. Application of aspheric surface and diffractive optical element makes each FOV have similar spot size, which shows the system almost meets the requirements of isoplanatic condition. If the focal length can be decreased, the FOV of the system can be enlarged further.

UNLAMINATED GAFCHROMIC EBT3 FILM FOR ULTRAVIOLET RADIATION MONITORING.

PubMed

Welch, David; Randers-Pehrson, Gerhard; Spotnitz, Henry M; Brenner, David J

2017-11-01

Measurement of ultraviolet (UV) radiation is important for human health, especially with the expanded usage of short wavelength UV for sterilization purposes. This work examines unlaminated Gafchromic EBT3 film for UV radiation monitoring. The authors exposed the film to select wavelengths in the UV spectrum, ranging from 207 to 328 nm, and measured the change in optical density. The response of the film is wavelength dependent, and of the wavelengths tested, the film was most sensitive to 254 nm light, with measurable values as low as 10 µJ/cm2. The film shows a dose-dependent response that extends over more than four orders of magnitude. The response of the film to short wavelength UV is comparable to the daily safe exposure limits for humans, thus making it valuable as a tool for passive UV radiation monitoring. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Effectiveness of eye drops protective against ultraviolet radiation.

PubMed

Daxer, A; Blumthaler, M; Schreder, J; Ettl, A

1998-01-01

To test the effectiveness of commercially available ultraviolet (UV)-protective eye drops (8-hydroxy-1-methylchinolinium methylsulphate) which are recommended for protection against both solar and artificial UV radiation. The spectral transmission in the wavelength range from 250 to 500 nm was investigated in 1-nm steps using a high-resolution double monochromator with holographic gratings of 2,400 lines/mm and a 1,000-watt halogen lamp as light source. The transmission spectrum was measured for different values of the layer thickness. The transmission of a liquid layer of about 10 microns, which corresponds to the thickness of the human tear film, shows a cut-off at 290 nm with a transmission of about 25-50% at shorter wavelengths. For wavelengths longer than 290 nm the transmission is higher than 90%. The threshold time ratio for keratitis formation with and without eye drops is above 0.93 considering solar radiation on the earth's surface and above 0.65 considering radiation from arc-welding, respectively. The transmission spectrum of the eye drops under realistic conditions does not show a protective effect against solar UV radiation. However, there exists reduction of UVC radiation in the spectral range typical of artificial UV sources such as arc-welding. We cannot recommend the application of these eye drops as an UV-protective aid against eye damage by solar UV radiation.

Reference Ultraviolet Wavelengths of Cr III Measured by Fourier Transform Spectrometry

NASA Technical Reports Server (NTRS)

Smillie, D.G.; Pickering, J.C.; Smith, P.L.

2008-01-01

We report Cr III ultraviolet (UV) transition wavelengths measured using a high-resolution Fourier transform spectrometer (FTS), for the first time, available for use as wavelength standards. The doubly ionized iron group element spectra dominate the observed opacity of hot B stars in the UV, and improved, accurate, wavelengths are required for the analysis of astronomical spectra. The spectrum was excited using a chromium-neon Penning discharge lamp and measured with the Imperial College vacuum ultraviolet FTS. 140 classified 3d(exp 3)4s- 3d(exp 3)4p Cr III transition lines, in the spectral range 38,000 to 49,000 cm(exp -1) (2632 to 2041 A), the strongest having wavelength uncertainties less than one part in 10(exp 7), are presented.

Effects of Solar Ultraviolet Radiation on the Potential Efficiency of Photosystem II in Leaves of Tropical Plants1

PubMed Central

Krause, G. Heinrich; Schmude, Claudia; Garden, Hermann; Koroleva, Olga Y.; Winter, Klaus

1999-01-01

The effects of solar ultraviolet (UV)-B and UV-A radiation on the potential efficiency of photosystem II (PSII) in leaves of tropical plants were investigated in Panama (9°N). Shade-grown tree seedlings or detached sun leaves from the outer crown of mature trees were exposed for short periods (up to 75 min) to direct sunlight filtered through plastic or glass filters that absorbed either UV-B or UV-A+B radiation, or transmitted the complete solar spectrum. Persistent changes in potential PSII efficiency were monitored by means of the dark-adapted ratio of variable to maximum chlorophyll a fluorescence. In leaves of shade-grown tree seedlings, exposure to the complete solar spectrum resulted in a strong decrease in potential PSII efficiency, probably involving protein damage. A substantially smaller decline in the dark-adapted ratio of variable to maximum chlorophyll a fluorescence was observed when UV-B irradiation was excluded. The loss in PSII efficiency was further reduced by excluding both UV-B and UV-A light. The photoinactivation of PSII was reversible under shade conditions, but restoration of nearly full activity required at least 10 d. Repeated exposure to direct sunlight induced an increase in the pool size of xanthophyll cycle pigments and in the content of UV-absorbing vacuolar compounds. In sun leaves of mature trees, which contained high levels of UV-absorbing compounds, effects of UV-B on PSII efficiency were observed in several cases and varied with developmental age and acclimation state of the leaves. The results show that natural UV-B and UV-A radiation in the tropics may significantly contribute to photoinhibition of PSII during sun exposure in situ, particularly in shade leaves exposed to full sunlight. PMID:10594122

An Ultraviolet Spectrum of the Tidal Disruption Flare ASASSN-14li

NASA Astrophysics Data System (ADS)

Cenko, S. Bradley; Cucchiara, Antonino; Roth, Nathaniel; Veilleux, Sylvain; Prochaska, J. Xavier; Yan, Lin; Guillochon, James; Maksym, W. Peter; Arcavi, Iair; Butler, Nathaniel R.; Filippenko, Alexei V.; Fruchter, Andrew S.; Gezari, Suvi; Kasen, Daniel; Levan, Andrew J.; Miller, Jon M.; Pasham, Dheeraj R.; Ramirez-Ruiz, Enrico; Strubbe, Linda E.; Tanvir, Nial R.; Tombesi, Francesco

2016-02-01

We present a Hubble Space Telescope Space Telescope Imaging Spectrograph spectrum of ASASSN-14li, the first rest-frame ultraviolet (UV) spectrum of a tidal disruption flare (TDF). The underlying continuum is well fit by a blackbody with {T}{UV}=3.5× {10}4 K, an order of magnitude smaller than the temperature inferred from X-ray spectra (and significantly more precise than previous efforts based on optical and near-UV photometry). Superimposed on this blue continuum, we detect three classes of features: narrow absorption from the Milky Way (probably a high-velocity cloud), and narrow absorption and broad (˜2000-8000 km s-1) emission lines at or near the systemic host velocity. The absorption lines are blueshifted with respect to the emission lines by Δv = -(250-400) km s-1. Due both to this velocity offset and the lack of common low-ionization features (Mg II, Fe II), we argue these arise from the same absorbing material responsible for the low-velocity outflow discovered at X-ray wavelengths. The broad nuclear emission lines display a remarkable abundance pattern: N III], N IV], and He II are quite prominent, while the common quasar emission lines of C III] and Mg II are weak or entirely absent. Detailed modeling of this spectrum will help elucidate fundamental questions regarding the nature of the emission processes at work in TDFs, while future UV spectroscopy of ASASSN-14li would help to confirm (or refute) the previously proposed connection between TDFs and “N-rich” quasars.

An Ultraviolet Spectrum of the Tidal Disruption Flare ASASSN-14li

NASA Technical Reports Server (NTRS)

Cenko, S. Bradley; Cucchiara, Antonio; Roth, Nathaniel; Veilleux, Sylvain; Prochaska, J. Xavier; Yan, Lin; Guillochon, James; Maksym, W. Peter; Arcavi, Iair; Butler, Nathaniel R.

2016-01-01

We present a Hubble Space Telescope Space Telescope Imaging Spectrograph spectrum of ASASSN-14li, the first rest-frame ultraviolet (UV) spectrum of a tidal disruption flare (TDF). The underlying continuum is well fit by a blackbody with T(sub UV) = 3.5 x 10(exp. 4) K, an order of magnitude smaller than the temperature inferred from X-ray spectra (and significantly more precise than previous efforts based on optical and near-UV photometry).Superimposed on this blue continuum, we detect three classes of features: narrow absorption from the Milky Way (probably a high-velocity cloud), and narrow absorption and broad {approx. 2000-8000 km s(exp. -1)} emission lines at or near the systemic host velocity. The absorption lines are blueshifted with respect to the emission lines by Delta(sub v) = -(250-400) km s(exp. -1). Due both to this velocity offset and the lack of common low-ionization features (Mg II, Fe II), we argue these arise from the same absorbing material responsible for the low-velocity outflow discovered at X-ray wavelengths. The broad nuclear emission lines display a remarkable abundance pattern: N III], N IV], and He II are quite prominent, while the common quasar emission lines of C III] and Mg II are weak or entirely absent. Detailed modeling of this spectrum will help elucidate fundamental questions regarding the nature of the emission processes at work in TDFs, while future UV spectroscopy of ASASSN-14li would help to confirm (or refute) the previously proposed connection between TDFs and N-rich quasars.

FIRST ULTRAVIOLET REFLECTANCE SPECTRA OF PLUTO AND CHARON BY THE HUBBLE SPACE TELESCOPE COSMIC ORIGINS SPECTROGRAPH: DETECTION OF ABSORPTION FEATURES AND EVIDENCE FOR TEMPORAL CHANGE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stern, S. A.; Spencer, J. R.; Shinn, A.

We have observed the mid-UV spectra of both Pluto and its large satellite, Charon, at two rotational epochs using the Hubble Space Telescope (HST) Cosmic Origins Spectrograph (COS) in 2010. These are the first HST/COS measurements of Pluto and Charon. Here we describe the observations and our reduction of them, and present the albedo spectra, average mid-UV albedos, and albedo slopes we derive from these data. These data reveal evidence for a strong absorption feature in the mid-UV spectrum of Pluto; evidence for temporal change in Pluto's spectrum since the 1990s is reported, and indirect evidence for a near-UV spectralmore » absorption on Charon is also reported.« less

Towards objective hand hygiene technique assessment: validation of the ultraviolet-dye-based hand-rubbing quality assessment procedure.

PubMed

Lehotsky, Á; Szilágyi, L; Bánsághi, S; Szerémy, P; Wéber, G; Haidegger, T

2017-09-01

Ultraviolet spectrum markers are widely used for hand hygiene quality assessment, although their microbiological validation has not been established. A microbiology-based assessment of the procedure was conducted. Twenty-five artificial hand models underwent initial full contamination, then disinfection with UV-dyed hand-rub solution, digital imaging under UV-light, microbiological sampling and cultivation, and digital imaging of the cultivated flora were performed. Paired images of each hand model were registered by a software tool, then the UV-marked regions were compared with the pathogen-free sites pixel by pixel. Statistical evaluation revealed that the method indicates correctly disinfected areas with 95.05% sensitivity and 98.01% specificity. Copyright © 2017 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

Advanced ultraviolet-resistant silver mirrors for use in solar reflectors

DOEpatents

Jorgensen, Gary J [Pine, CO; Gee, Randy [Arvada, CO

2009-11-03

A silver mirror construction that maintains a high percentage of hemispherical reflectance throughout the UV and visible spectrum when used in solar reflectors, comprising:a) a pressure sensitive adhesive layer positioned beneath a silver overlay;b) a polymer film disposed on the silver overlay;c) an adhesive layer positioned on the polymer film; andd) a UV screening acrylic film disposed on the adhesive layer.

The effects of ultraviolet radiation on growth and bleaching in three species of Hawaiian coral

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goodman, G.D.

1990-01-09

Long term exposure to ultraviolet radiation is harmful to many organisms, including hermatypic corals, which obtain much of their nutrition from photosynthetic zooxanthellae. Therefore, increased UV radiation from atmospheric ozone depletion could inhibit growth of such corals. Moreover, coral bleaching, which has been attributed to loss of pigment and/or expulsion of zooxanthellae, may be a specific response to UV light. Does UV-A reduce skeletal growth or influence population density and pigment content of zooxanthellae In addition, do zooxanthellae migrate to shaded areas of the colony to avoid ultraviolet light Using alizarin red stain and suitable filters, I compared the stainmore » and suitable filters, I compared the effects of UV-A (320-400nm) and full-spectrum UV (280-400nm) on the skeletal growth of two Hawaiian corals, Montipora verrucosa, Pocillopora damicornis, in situ. In the perforate corals, M. Verrucosa and Porites compressa, I measured concentration of zooxanthellae and their chlorophyll content to quantify bleaching in response to UV light. Reduction in skeletal growth by the two corals in response to different ranges of UV light appears to be species specific. Bleaching by UV appears to be characterized by an initial loss of pigment followed by the expulsion and migration of the zooxanthellae to shaded areas of the colony. Differences in tolerance and adaptation to decreasing ozone levels and increasing UV light should confer a competitive advantage on various species and morphologies of reef-building corals.« less

The mean ultraviolet spectrum of a representative sample of faint z ˜ 3 Lyman alpha emitters

NASA Astrophysics Data System (ADS)

Nakajima, Kimihiko; Fletcher, Thomas; Ellis, Richard S.; Robertson, Brant E.; Iwata, Ikuru

2018-06-01

We discuss the rest-frame ultraviolet (UV) emission line spectra of a large (˜100) sample of low luminosity redshift z ˜ 3.1 Lyman alpha emitters (LAEs) drawn from a Subaru imaging survey in the SSA22 survey field. Our earlier work based on smaller samples indicated that such sources have high [O III]/[O II] line ratios possibly arising from a hard ionizing spectrum that may be typical of similar sources in the reionization era. With optical spectra secured from VLT/VIMOS, we re-examine the nature of the ionizing radiation in a larger sample using the strength of the high ionization diagnostic emission lines of CIII]λ1909, CIVλ1549, HEIIλ1640, and O III]λλ1661, 1666 Å in various stacked subsets. Our analysis confirms earlier suggestions of a correlation between the strength of Ly α and CIII] emission and we find similar trends with broad-band UV luminosity and rest-frame UV colour. Using various diagnostic line ratios and our stellar photoionization models, we determine both the gas phase metallicity and hardness of the ionization spectrum characterized by ξion - the number of Lyman continuum photons per UV luminosity. We confirm our earlier suggestion that ξion is significantly larger for LAEs than for continuum-selected Lyman break galaxies, particularly for those LAEs with the faintest UV luminosities. We briefly discuss the implications for cosmic reionization if the metal-poor intensely star-forming systems studied here are representative examples of those at much higher redshift.

Supreme EnLIGHTenment: Damage Recognition and Signaling in the Mammalian UV Response

PubMed Central

Herrlich, Peter; Karin, Michael; Weiss, Carsten

2009-01-01

Like their prokaryotic counterparts, mammalian cells can sense light, especially in the ultraviolet (UV) range of the spectrum. Following UV exposure cells mount an elaborate response – called the UV response, which mimics physiological signaling responses except that it targets multiple pathways thereby lacking the defined specificity of receptor-triggered signal transduction. Despite many years of research it is still not fully clear how UV radiation is sensed and converted into the „language of cells“ - signal reception and transduction. This review focuses on how photonic energy and its primary cellular products are sensed to elicit the UV response. PMID:18280234

Long-term variability and impact on human health of biologically active UV radiation in Moscow

NASA Astrophysics Data System (ADS)

Zhdanova, Ekaterina; Chubarova, Natalia

2014-05-01

Measurements of erythemally weighted UV irradiance (Qer) have been performed at the Meteorological Observatory of Moscow State University since 1999 with the UVB-1 YES pyranometers. These types of devices are broadband with a spectral sensitivity curve close to the action spectrum of erythema. Main uncertainties of UVB-1 YES measurements include the difference in spectral curves of the instrument and the action spectrum of erythema, as well as the deviation from the cosine law. These uncertainties were taken into account in the database of Qer measurements (Chubarova, 2008. Additional corrections of UVB-1 measurements at low ambient temperatures have been made. We analyze interannual, seasonal and diurnal Qer changes over the time period 1999-2012. In addition, the comparisons with the results of UV reconstruction model (Chubarova, 2008) are made. This model allows us to evaluate relative changes in Qer due to variations in total ozone, effective cloud amount transmission, aerosol and cloud optical thickness since 1968. It is important to note that the main reason for UV irradiance monitoring development is the strong influence of UV irradiance on the biosphere and especially on human health mainly on human skin (CIE, 1993, CIE, 2006) and eyes (Oriowo, M. et al., 2001). Based on the detailed studies we have shown the possibility of utilizing UVB-1 pyranometers for measuring the eye-damage UV radiation. Parallel measurements by the Bentham DTM-300 spectrometer and the UVB-1 YES pyranometer at the Innsbruck Medical University (Austria) have provided us the calibration factor in eye-damage units for this broadband instrument. Influence of main geophysical factors on different types of UV irradiance is estimated by means the RAF ideology (Booth, Madronich, 1994). We discuss the responses of different types of biologically active UV radiation to the impact of various atmospheric factors. The UV conditions (deficiency, optimum, excess for human) are analyzed according to the developed classification for Moscow. Booth, C.R. and S. Madronich, 1994: Radiation amplification factors: improved formulation accounts for large increases in ultraviolet radiation associated with Antarctic ozone depletion. In: Ultraviolet Radiation in Antarctica: Measurements and Biological Research [Weiler, C.S. and P.A. Penhale (eds.)]. AGU Antarctic Research Series, 62, Washington, DC, USA, 39-42. Chubarova N.Y., 2008: UV variability in Moscow according to long-term UV measurements and reconstruction model. Atmos.Chem.Phys., 8, 3025-3031 Oriowo, M. et al., 2001:, Action spectrum for in vitro UV-induced cataract using whole lenses. Invest.Ophthalmol.&Vis.Sci, 42, 2596-2602. CIE, 1993: Reference Action Spectra for Ultraviolet Induced Erythema and Pigmentation of Different Human skin Types. CIE Research Note, CIE Technical Collection., N.3 CIE, 2006: Action spectrum for the production of previtamin D3 in human skin, Technical report 174, International commission on illumination

Vertical redistribution of zooplankton in an oligotrophic lake associated with reduction in ultraviolet radiation by wildfire smoke

NASA Astrophysics Data System (ADS)

Urmy, Samuel S.; Williamson, Craig E.; Leach, Taylor H.; Schladow, S. Geoffrey; Overholt, Erin P.; Warren, Joseph D.

2016-04-01

We used a natural experiment to test whether wildfire smoke induced changes in the vertical distribution of zooplankton in Lake Tahoe by decreasing incident ultraviolet radiation (UV). Fires have a variety of effects on aquatic ecosystems, but these impacts are poorly understood and have rarely been observed directly. UV is an important driver of zooplankton vertical migration, and wildfires may alter it over large spatial scales. We measured UV irradiance and the distribution of zooplankton on two successive days. On one day, smoke haze from a nearby wildfire reduced incident UV radiation by up to 9%, but not irradiance in the visible spectrum. Zooplankton responded by positioning themselves, on average, 4.1 m shallower in the lake. While a limited data set such as this requires cautious interpretation, our results suggest that smoke from wildfires can change the UV environment and distribution of zooplankton. This process may be important in drought-prone regions with increasingly frequent wildfires, and globally due to widespread biomass burning.

Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer

NASA Astrophysics Data System (ADS)

Lei, Huibin; He, Deliang; Guo, Yanni; Tang, Yining; Huang, Houqiang

2018-06-01

A series of UV-absorbing fluorine-silicone acrylic resin polymers containing different amount of UV-absorbent were successfully prepared by solution polymerization, with 2-[3-(2H-Benzotriazol-2-yl)-4-hydroxyphenyl] ethyl methacrylate (BHEM), vinyltrimethoxysilane (VTMS) and hexafluorobutyl methacrylate (HFMA) as modifying monomers. The acrylic polymers and the coatings thereof were characterized by Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS), Ultraviolet-visible (UV-vis) absorption spectrum, thermogravimetric analysis (TGA), water contact angle (CA) and Xenon lamp artificial accelerated aging tests. Results indicated that the resin exhibited high UV absorption performance as well as good thermal stability. The hydrophobicity of the coatings was of great improvement because of the bonded fluorine and silicone. Meanwhile, the weather-resistance was promoted through preferably colligating the protective effects of BHEM, organic fluorine and silicone. Also, a fitting formula about the weatherability with the BMHE content was tentatively proposed.

Solar Irradiance from 165 to 400 nm in 2008 and UV Variations in Three Spectral Bands During Solar Cycle 24

NASA Astrophysics Data System (ADS)

Meftah, M.; Bolsée, D.; Damé, L.; Hauchecorne, A.; Pereira, N.; Irbah, A.; Bekki, S.; Cessateur, G.; Foujols, T.; Thiéblemont, R.

2016-12-01

Accurate measurements of the solar spectral irradiance (SSI) and its temporal variations are of primary interest to better understand solar mechanisms, and the links between solar variability and Earth's atmosphere and climate. The SOLar SPECtrum (SOLSPEC) instrument of the Solar Monitoring Observatory (SOLAR) payload onboard the International Space Station (ISS) has been built to carry out SSI measurements from 165 to 3088 nm. We focus here on the ultraviolet (UV) part of the measured solar spectrum (wavelengths less than 400 nm) because the UV part is potentially important for understanding the solar forcing of Earth's atmosphere and climate. We present here SOLAR/SOLSPEC UV data obtained since 2008, and their variations in three spectral bands during Solar Cycle 24. They are compared with previously reported UV measurements and model reconstructions, and differences are discussed.

[The negative temperature effect of UV absorbance on C60 in different solvents].

PubMed

Yang, Tao; Zeng, Fan-qin; Ge, Qi; Xiong, Qian; Guo, Feng; Zhang, Xun-gao

2004-02-01

Ultraviolet Absorption Spectrum of Difference in Temperature (UVSDT) of C60 was studied in different solvents by UV-240 ultraviolet-visible spectrophotometer. Two samples were tested, one of which acted as reference sample and the other as ready test sample. During the period of the experiment, the temperature of the reference sample remained constant, while that of the ready test sample was changed to obtain difference in temperature. The two samples were scanned in succession by UV-240 ultraviolet-visible spectrophotometer using a certain range of wavelength. By changing the temperature of the ready test sample, we can get the ultraviolet absorption spectrum changing curve with temperature differential. In addition, the curve was studied by putting C60 in different solvents (alcohol, cyclohexane, n-hexane and 2-propanol). The curve indicates that the intensity of the absorption peak wavelength of C60 decreased with increasing the temperature of the sample, and a negative peak was observed in UVSDT. And the greater the difference in temperature, the higher the intensity of the negative peak. The result reflects that the structure of C60 depends strongly on its temperature, and the dependent relationship is closely related to the type of pi-pi electron transition. So it's valuable to test the absorption rate of C60 and obtain the changing curve in real time. It'll help us to separate, purify, analyze, and characterize C60. And it'll also help to do research on the mechanism of the chemical reactions, which take place in solvents, as well as to improve veracity.

FogEye UV Sensor System Evaluation : Phase I Report.

DOT National Transportation Integrated Search

2002-09-01

FogEye technology uses the solar-blind reigion of the ultraviolet spectrum to develop sensors or systems that are unaffected by sunlight. The U.S. Congress asked the Federal Aviation Administration to investigate the feasibility of applying FogEye te...

Near-visible light and UV photoprotection in the treatment of melasma: a double-blind randomized trial.

PubMed

Castanedo-Cazares, Juan Pablo; Hernandez-Blanco, Diana; Carlos-Ortega, Blanca; Fuentes-Ahumada, Cornelia; Torres-Álvarez, Bertha

2014-02-01

Melasma is an acquired hyperpigmentation on sun-exposed areas. Multiple approaches are used to treat it, but all include broad ultraviolet (UV)-spectrum sunscreens. Visible light (VL) can induce pigmentary changes similar to those caused by UV radiation on darker-skinned patients. To assess the efficacy of sunscreen with broad-spectrum UV protection that contains iron oxide as a VL-absorbing pigment (UV-VL) compared with a regular UV-only broad-spectrum sunscreen for melasma patients exposed to intense solar conditions. Sixty-eight patients with melasma were randomized in two groups to receive either UV-VL sunscreen or UV-only sunscreen, both with sun protection factor ≥ 50, over 8 weeks. All patients received 4% hydroquinone as a depigmenting treatment. At onset and at conclusion of the study, they were assessed by the Melasma Activity and Severity Index (MASI; a subjective scale), colorimetry (L*) and histological analysis of melanin. Sixty-one patients concluded the study. At 8 weeks, the UV-VL group showed 15%, 28% and 4% greater improvements than the UV-only group in MASI scores, colorimetric values and melanin assessments, respectively. UV-VL sunscreen enhances the depigmenting efficacy of hydroquinone compared with UV-only sunscreen in treatment of melasma. These findings suggest a role for VL in melasma pathogenesis. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

A proposal for in vitro/GFR molecular erythema action spectrum

NASA Astrophysics Data System (ADS)

de Souza, João A. V.; Lorenzini, Fabiane; Rizzatti, Mara R.

2008-08-01

We propose an erythema action spectrum based on experimental molecular measurements named molecular erythema action spectrum or in vitro/GFR, where the acronym GFR represents our research group name, Grupo de Física das Radiaçöes. The in vitro methodology was developed by using a derma tissue simulator (TSD), as a radiation protection shield, and monochromatic ultraviolet (UV) sources of 254, 310, 365, 380, and 400 nm. The irradiance from each source was monitored through spectroradiometry in order to obtain the exposure dose over a period of time. Changes in the chemical structure were monitored by Fourier transform infrared spectroscopy (FTIR) and UV and visible spectroscopy (UV-vis). The samples were analyzed by UV-vis at each 200 up to 1000 J/m2 and at each 400 up to 2000 J/m2. FTIR was performed only for samples exposed to a maximum dose of 2000 J/m2. The in vitro action parameters were obtained by considering the redshift revealed through UV-vis analysis, as being the molecular quantification of minimal erythema, and the chemical bond rupture of TSD molecules associated with erythema, revealed through FTIR. The in vitro/GFR action spectrum shows that UV-A and UV-B radiation are equally responsible for the damage observed in TSD. When this proposal was compared to the CIE erythema action spectrum from ISO [ISO17166 CIE S 007/E, Erythema Reference Action Spectrum and Standard Erythema Dose (CIE Central Bureau, Austria, 1998)], similarities could be observed in wavelengths less than 280 nm in UV-B region. However, for wavelengths higher than 300 nm, the efficiency of this radiation to induce damage, mainly in the UV-A part, was much higher than predicted in CIE model. The increasing concern on UV-A radiation, assumed to be as responsible as UV-B for inducing most of the already observed skin injuries, may be better understood when observing the experimental model presented in in vitro/GFR action spectrum.

Ultraviolet light protection by a sunscreen prevents interferon-driven skin inflammation in cutaneous lupus erythematosus.

PubMed

Zahn, Sabine; Graef, Medina; Patsinakidis, Nikolaos; Landmann, Aysche; Surber, Christian; Wenzel, Joerg; Kuhn, Annegret

2014-07-01

Irradiation with ultraviolet (UV) light is an important exacerbating factor in cutaneous lupus erythematosus (CLE) and induces various effects in the skin of patients with the disease, such as cell death and inflammation. Recently, we demonstrated the ability of a broad-spectrum sunscreen to prevent UV-induced damage both in patients with CLE and healthy controls (HCs). The aim of this study was to evaluate whether the UV-dependent activation of interferon (IFN)-driven inflammation in CLE can also be prevented by application of the sunscreen. In 20 patients with different subtypes of CLE and 10 HCs, defined areas on the upper back were treated with a broad-spectrum liposomal sunscreen 20 min prior to a combined standardized UVA/UVB irradiation. Immunohistological analyses using antibodies directed against MxA, CD11c, CD123 and CD68 were performed from skin biopsies taken from areas before UV irradiation as well as from sunscreen-treated and sunscreen-untreated areas 24 and 72 h after UV irradiation. The expression of MxA was completely prevented by the sunscreen applied prior to UV irradiation in CLE patients and HCs. Additionally, sunscreen protection significantly diminished the number of the CD11c- and CD123-positive dendritic cells, which are suggested to be a major source of type I/III IFNs, in UV-irradiated skin of patients with CLE. Moreover, the application of the sunscreen prevented the increase in CD68-positive macrophages in both groups 72 h after UV irradiation. The data of this study demonstrate that UV protection reduces lesional tissue damage and inhibits the typical IFN-driven inflammatory response in CLE. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

The first linear polarization spectra of Wolf-Rayet stars in the ultraviolet - EZ Canis Majoris and Theta Muscae

NASA Technical Reports Server (NTRS)

Schulte-Ladbeck, R. E.; Nordsieck, K. H.; Code, A. D.; Anderson, C. M.; Babler, B. L.; Bjorkman, K. S.; Clayton, G. C.; Magalhaes, A. M.; Meade, M. R.; Shepherd, D.

1992-01-01

During the 1990 December Astro-1 Space Shuttle mission, spectropolarimetry was conducted in the wavelength region from 1400 to 3200 A of the Wolf-Rayet stars EZ CMa (WN5) and Theta Mus (WC6 + O9.5I) with the Wisconsin Ultraviolet Photo-Polarimeter Experiment. The UV polarization of EZ CMa displays features which correspond to emission lines. This indicates a large, about 0.8 percent, intrinsic UV-continuum polarization, and provides further evidence that the wind of EZ CMa is highly distorted. The polarization of Theta Mus does not change across emission lines, or the strong interstellar 2200 A feature. The polarization decreases smoothly to shorter wavelengths, at constant position angle. The combined UV-optical polarization spectrum of Theta Mus can be described well with interstellar polarization following a Serkowski law.

The application of UV multispectral technology in extract trace evdidence

NASA Astrophysics Data System (ADS)

Guo, Jingjing; Xu, Xiaojing; Li, Zhihui; Xu, Lei; Xie, Lanchi

2015-11-01

Multispectral imaging is becoming more and more important in the field of examination of material evidence, especially the ultraviolet spectral imaging. Fingerprints development, questioned document detection, trace evidence examination-all can used of it. This paper introduce a UV multispectral equipment which was developed by BITU & IFSC, it can extract trace evidence-extract fingerprints. The result showed that this technology can develop latent sweat-sebum mixed fingerprint on photo and ID card blood fingerprint on steel hold. We used the UV spectrum data analysis system to make the UV spectral image clear to identify and analyse.

Ultraviolet and short wavelength visible light exposure: why ultraviolet protection alone is not adequate.

PubMed

Reichow, Alan W; Citek, Karl; Edlich, Richard F

2006-01-01

The danger of exposure to ultraviolet (UV) radiation in both the natural environment and artificial occupational settings has long been recognized by national and international standards committees and worker safety agencies. There is an increasing body of literature that suggests that protection from UV exposure is not enough. Unprotected exposure to the short wavelengths of the visible spectrum, termed the "blue light hazard", is gaining acceptance as a true risk to long-term visual health. Global standards and experts in the field are now warning that those individuals who spend considerable time outdoors should seek sun filter eyewear with high impact resistant lenses that provide 100% UV filtration, high levels of blue light filtration, and full visual field lens/frame coverage as provided by high wrap eyewear. The Skin Cancer Foundation has endorsed certain sunglasses as "product[s]...effective [as] UV filter[s] for the eyes and surrounding skin". However, such endorsement does not necessarily mean that the eyewear meets all the protective needs for outdoor use. There are several brands that offer products with such protective characteristics. Performance sun eyewear by Nike Vision, available in both corrective and plano (nonprescription) forms, is one such brand incorporating these protective features.

Remote sensing of soil moisture using airborne hyperspectral data

USDA-ARS?s Scientific Manuscript database

The Institute for Technology Development (ITD) has developed an airborne hyperspectral sensor system that collects electromagnetic reflectance data of the terrain. The system consists of sensors for three different sections of the electromagnetic spectrum; the Ultra-Violet (UV), Visible/Near Infrare...

Update on Photoprotection

PubMed Central

Rai, Reena; Shanmuga, Sekar C; Srinivas, CR

2012-01-01

Photoprotection by sunscreens, clothing and glasses are important to protect the skin against the detrimental effects of sun exposure. In order to achieve complete protection, topical strategies must shield against the range of solar wavelengths ultraviolet A, ultraviolet B, infrared radiation that can damage the skin. To provide the necessary broad spectrum coverage, combinations of chemical and physical UV filters along with molecules that are capable of interfering with and/or preventing the deleterious effects of sunlight are discussed in this review. PMID:23112351

The UV Spectrum of Phobos as measured by MAVEN/IUVS

NASA Astrophysics Data System (ADS)

Chaffin, M.; Deighan, J.; Schneider, N. M.; Thiemann, E.; Stewart, I. F.; Jain, S.; Lo, D.; Crismani, M. M. J.; Stiepen, A.; Clarke, J. T.; Mayyasi, M.; Montmessin, F.; Holsclaw, G.; McClintock, B.; Epavier, F.; Jakosky, B. M.

2017-12-01

In late 2015, the Mars Atmosphere and Volatile Evolution (MAVEN) mission apoapsis was near the orbit of Phobos and the spacecraft had several close encounters with the moon. Using a specially designed imaging sequence, MAVEN's Imaging Ultraviolet Spectrograph (IUVS) was able to gather the first spectral images of the moon in the mid-ultraviolet. IUVS observed the trailing hemisphere of the moon, producing spectra useful for comparison with the leading hemisphere measurements of the Mariner 9 UV spectrometer and Mars Express SPICAM observations. IUVS shows the trailing side to be bluer than the leading side, potentially revealing differences in the space weathering history of the hemispheres. In addition, there is marginal evidence for an absorption feature longward of 300 nm, potentially produced by organic compounds. Due to short integration times, the FUV spectrum of the moon is limited to some reflectance signal at Lyman alpha, constraining the albedo at this wavelength and placing an upper limit on it elsewhere.

Global Increase in UV Irradiance during the Past 30 Years (1979-2008) Estimated from Satellite Data

NASA Technical Reports Server (NTRS)

Herman, Jay R.

2010-01-01

Zonal average ultraviolet irradiance (flux ultraviolet, F(sub uv)) reaching the Earth's surface has significantly increased since 1979 at all latitudes except the equatorial zone. Changes are estimated in zonal average F(sub uv) caused by ozone and cloud plus aerosol reflectivity using an approach based on Beer's law for monochromatic and action spectrum weighted irradiances. For four different cases, it is shown that Beer's Law leads to a power law form similar to that applied to erythemal action spectrum weighted irradiances. Zonal and annual average increases in F(sub uv) were caused by decreases in ozone amount from 1979 to 1998. After 1998, midlatitude annual average ozone amounts and UV irradiance levels have been approximately constant. In the Southern Hemisphere, zonal and annual average UV increase is partially offset by tropospheric cloud and aerosol transmission decreases (hemispherical dimming), and to a lesser extent in the Northern Hemisphere. Ozone and 340 nm reflectivity changes have been obtained from multiple joined satellite time series from 1978 to 2008. The largest zonal average increases in F(sub uv) have occurred in the Southern Hemisphere. For clear-sky conditions at 50 S, zonal average F(sub uv) changes are estimated (305 nm, 23%; erythemal, 8.5%; 310 nm, 10%; vitamin D production, 12%). These are larger than at 50 N (305 nm, 9%; erythemal, 4%; 310 nm, 4%; vitamin D production, 6%). At the latitude of Buenos Aires, Argentina (34.6 S), the clear-sky Fuv increases are comparable to the increases near Washington, D. C. (38.9 N): 305 nm, 9% and 7%; erythemal, 6% and 4%; and vitamin D production, 7% and 5%, respectively.

Modelling a man-portable air-defence (MANPAD) system with a rosette scan two-colour infrared (IR) and ultraviolet (UV) seeker

NASA Astrophysics Data System (ADS)

Kumar, Devinder; Smith, Leon; Richardson, Mark A.; Ayling, Richard; Barlow, Nick

2014-10-01

The Ultraviolet (UV) band of the electromagnetic (EM) spectrum has the potential to be used as the host medium for the operation of guided weapons. Unlike in the Infrared (IR), a target propelled by an air breathing jet engine produces no detectable radiation in the UV band, and is opaque to the background UV produced by the Sun. Successful engineering of spectral airborne IR countermeasures (CM) against existing two colour IR seekers has encouraged missile counter-countermeasure (CCM) designers to utilise the silhouette signature of an aircraft in the UV as a means of distinguishing between a true target and a flare CM. In this paper we describe the modelling process of a dual band IR and UV rosette scan seeker using CounterSim, a missile engagement and countermeasure simulation software package developed by Chemring Countermeasures Ltd. Results are shown from various simulated engagements of the dual band MANPAD with a C-130 Hercules modelled by Chemring Countermeasures. These results have been used to estimate the aircrafts' vulnerability to this MANPAD threat. A discussion on possible future optical countermeasures against dual band IR-UV seekers is given in conclusion to the simulation results.

Ultraviolet radiation in the Atacama Desert.

PubMed

Cordero, R R; Damiani, A; Jorquera, J; Sepúlveda, E; Caballero, M; Fernandez, S; Feron, S; Llanillo, P J; Carrasco, J; Laroze, D; Labbe, F

2018-03-31

The world's highest levels of surface ultraviolet (UV) irradiance have been measured in the Atacama Desert. This area is characterized by its high altitude, prevalent cloudless conditions, and a relatively low total ozone column. In this paper, we provide estimates of the surface UV (monthly UV index at noon and annual doses of UV-B and UV-A) for all sky conditions in the Atacama Desert. We found that the UV index at noon during the austral summer is expected to be greater than 11 in the whole desert. The annual UV-B (UV-A) doses were found to range from about 3.5 kWh/m 2 (130 kWh/m 2 ) in coastal areas to 5 kWh/m 2 (160 kWh/m 2 ) on the Andean plateau. Our results confirm significant interhemispherical differences. Typical annual UV-B doses in the Atacama Desert are about 40% greater than typical annual UV-B doses in northern Africa. Mostly due to seasonal changes in the ozone, the differences between the Atacama Desert and northern Africa are expected to be about 60% in the case of peak UV-B levels (i.e. the UV-B irradiances at noon close to the summer solstice in each hemisphere). Interhemispherical differences in the UV-A are significantly lower since the effect of the ozone in this part of the spectrum is minor.

Hot electron generation by aluminum oligomers in plasmonic ultraviolet photodetectors.

PubMed

Ahmadivand, Arash; Sinha, Raju; Vabbina, Phani Kiran; Karabiyik, Mustafa; Kaya, Serkan; Pala, Nezih

2016-06-13

We report on an integrated plasmonic ultraviolet (UV) photodetector composed of aluminum Fano-resonant heptamer nanoantennas deposited on a Gallium Nitride (GaN) active layer which is grown on a sapphire substrate to generate significant photocurrent via formation of hot electrons by nanoclusters upon the decay of nonequilibrium plasmons. Using the plasmon hybridization theory and finite-difference time-domain (FDTD) method, it is shown that the generation of hot carriers by metallic clusters illuminated by UV beam leads to a large photocurrent. The induced Fano resonance (FR) minimum across the UV spectrum allows for noticeable enhancement in the absorption of optical power yielding a plasmonic UV photodetector with a high responsivity. It is also shown that varying the thickness of the oxide layer (Al₂O₃) around the nanodisks (tox) in a heptamer assembly adjusted the generated photocurrent and responsivity. The proposed plasmonic structure opens new horizons for designing and fabricating efficient opto-electronics devices with high gain and responsivity.

Evaluation of erythemal UV effective irradiance from UV lamp exposure and the application in shield metal arc welding processing.

PubMed

Chang, Cheng-Ping; Liu, Hung-Hsin; Peng, Chiung-Yu; Fang, Hsin-Yu; Tsao, Ta-Ho; Lan, Cheng-Hang

2008-04-01

Ultraviolet radiation (UVR) exposure is known to cause potential effects such as erythema in skin. For UV-induced erythema (sunburn), the action spectrum from the Commission Internationale de l'Eclairage, International Commission on Illumination (CIE) was adopted. Erythemal UV effects from UVR lamp exposure were investigated with commercial spectroradiometry devices in this research. Three kinds of portable UV germicidal lamps with broadband UVA (BB UVA, 350-400 nm), broadband UVB (BB UVB, 280-350 nm), and narrowband UVC (NB UVC, 254 nm) wavelengths served as the UVR emission sources. An action spectrum expresses the effectiveness of radiation for assessing the hazard of UVR in the erythemal action spectrum from 250-400 nm. The UV Index (UVI) is an irradiance scale computed by multiplying the CIE erythemal irradiance integral in milliwatts per square meter by 0.04 m mW. A comprehensive approach to detecting erythemal UVR magnitude was developed to monitor the effective exposure from UV lamps. The erythemal UVR measurement was established and the exposure assessment was applied to monitor erythemal UVR magnitude from shield metal arc welding (SMAW) processing. From this study, the erythemal UVR exposures were assessed and evaluated with environmental solar simulation of the UVI exposure.

Importance of Vibronic Effects in the UV-Vis Spectrum of the 7,7,8,8-Tetracyanoquinodimethane Anion.

PubMed

Tapavicza, Enrico; Furche, Filipp; Sundholm, Dage

2016-10-11

We present a computational method for simulating vibronic absorption spectra in the ultraviolet-visible (UV-vis) range and apply it to the 7,7,8,8-tetracyanoquinodimethane anion (TCNQ - ), which has been used as a ligand in black absorbers. Gaussian broadening of vertical electronic excitation energies of TCNQ - from linear-response time-dependent density functional theory produces only one band, which is qualitatively incorrect. Thus, the harmonic vibrational modes of the two lowest doublet states were computed, and the vibronic UV-vis spectrum was simulated using the displaced harmonic oscillator approximation, the frequency-shifted harmonic oscillator approximation, and the full Duschinsky formalism. An efficient real-time generating function method was implemented to avoid the exponential complexity of conventional Franck-Condon approaches to vibronic spectra. The obtained UV-vis spectra for TCNQ - agree well with experiment; the Duschinsky rotation is found to have only a minor effect on the spectrum. Born-Oppenheimer molecular dynamics simulations combined with calculations of the electronic excitation energies for a large number of molecular structures were also used for simulating the UV-vis spectrum. The Born-Oppenheimer molecular dynamics simulations yield a broadening of the energetically lowest peak in the absorption spectrum, but additional vibrational bands present in the experimental and simulated quantum harmonic oscillator spectra are not observed in the molecular dynamics simulations. Our results underline the importance of vibronic effects for the UV-vis spectrum of TCNQ - , and they establish an efficient method for obtaining vibronic spectra using a combination of linear-response time-dependent density functional theory and a real-time generating function approach.

Vacuum ultraviolet imagery of the Virgo cluster region

NASA Astrophysics Data System (ADS)

Onaka, T.; Tanaka, W.; Watanabe, T.; Watanabe, J.; Yamaguchi, A.; Nakagiri, M.; Kodaira, K.; Nakano, M.; Sasaki, M.; Tsujimura, T.; Yamashita, K.

1989-07-01

The results are reported of an experiment using the UV imager aboard an attitude-controlled S520 type sounding rocket. The total UV fluxes of galaxies in the Virgo Cluster as well as the flux level of the diffuse UV background around the cluster were measured. The data on NGC 4486 and NGC 4472 confirm the variation in the degree of the 'turnup' below 200 nm in the energy spectrum of the total light of elliptical galaxies. At two-color diagram of galaxies of visual/near-UV/vacuum UV indicates that colors of spiral galaxies are distributed within a strip and well-correlated with the morphological type, while elliptical galaxies are located differently from spiral galaxies.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friesen, Brian; Baron, E.; Parrent, Jerod T.

This paper presents optical spectra of the nearby Type Ia supernova SN 2011fe at 100, 205, 311, 349 and 578 d post-maximum light, as well as an ultraviolet (UV) spectrum obtained with the Hubble Space Telescope at 360 d post-maximum light. We compare these observations with synthetic spectra produced with the radiative transfer code PHOENIX. The day +100 spectrum can be well fitted with models that neglect collisional and radiative data for forbidden lines. Curiously, including these data and recomputing the fit yields a quite similar spectrum, but with different combinations of lines forming some of the stronger features. Atmore » day +205 and later epochs, forbidden lines dominate much of the optical spectrum formation; however, our results indicate that recombination, not collisional excitation, is the most influential physical process driving spectrum formation at these late times. Consequently, our synthetic optical and UV spectra at all epochs presented here are formed almost exclusively through recombinationdriven fluorescence. Furthermore, our models suggest that the UV spectrum even as late as day +360 is optically thick and consists of permitted lines from several iron-peak species. These results indicate that the transition to the 'nebular' phase in Type Ia supernovae is complex and highly wavelength dependent.« less

Holick's rule and vitamin D from sunlight.

PubMed

Dowdy, John C; Sayre, Robert M; Holick, Michael F

2010-07-01

Holick's rule says that sun exposure 1/4 of a minimal erythemal dose (MED) over 1/4 of a body is equivalent to 1000 International Units (IU) oral vitamin D3. Webb and Engelsen recently commented that the ultraviolet (UV) spectrum used to establish Holick's rule is unknown. They consequently used a spring midday Boston solar spectrum to estimate ample sunlight exposures for previtamin D3 (preD3) at various locations. Literature review found the source upon which this rule is based was a fluorescent sunlamp (FS lamp). The FS spectrum is known and its relative weighting against the action spectra for erythema and the preD3 is significantly different from the solar spectrum used to derive the standard vitamin D effective dose (SDD). The preD3 effectiveness of the solar spectrum per unit erythemal hazard is greater than the FS lamp by a factor of 1.32. Consequently, UV exposure estimates based on Boston reference sunlight, instead of the UV lamp employed in the originating experiments, over estimate UV exposure equivalent to approximately 1000 IU orally by approximately 1/3. This redefinition of SDD impacts risk/benefit assessments of optimal/feasible sun exposure for vitamin D maintenance and the application of Holick's rule to rational public health messages. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

STS-93 Tognini and Hawley pose with the SWUIS on the middeck of Columbia

NASA Image and Video Library

2013-11-18

STS093-347-027 (23-27 July 1999) --- Astronauts Steven A. Hawley (left) and Michel Tognini, mission specialists, are pictured with the Southwest Ultraviolet Imaging System (SWUIS) on the middeck of the Space Shuttle Columbia. SWUIS was used during the mission to image planets and other solar system bodies in order to explore their atmospheres and surfaces in ultraviolet (UV) region of the spectrum, which astronomers value for diagnostic work. Tognini represents the Centre National d'Etudes Spatiales (CNES) of France.

UV-vis light transmittance through tinted contact lenses and the effect of color on values.

PubMed

Osuagwu, Uchechukwu L; Ogbuehi, Kelechi C

2014-06-01

To assess the transmittance, in the 200-700nm electromagnetic radiation spectrum, by popularly used tinted soft contact lenses (CLs). The spectra transmittances of ultraviolet (UV)-blocking (I Day Acuvue Define, Freshlook ONE DAY) and non-UV-blocking (Durasoft 3, Tutti, and NeoCosmo) tinted soft CLs were tested. The transmittance of each lens, including nine different colors of Freshlook CL was recorded on spectrophotometer, and the data used to also calculate a UV protection factor (PF) for each lens brand tested, with a higher value indicating a higher level of protection. The UV-blocking CLs significantly reduced UVC, UVB & UVA transmission and thereby meet the American National Standards Institution standard for class 2 UV blockers: a maximum of 30% transmittance of UVA and 5% transmittance of UVB wavelengths. In contrast, the Durasoft 3, Tutti, and NeoCosmo CLs demonstrated negligible UV-blockage. The Acuvue Define CL offered the greatest protection from UVC (PF=69) and UVB (PF=55), but with only 35% luminous transmittance, while the Freshlook CL (especially gemstone green) offered the best protection from UVA (PF=24) and showed about 55% translucency. Overall, the UV-blocking CLs performed equally well across the UV spectrum. Different colors of Freshlook CL transmitted statistically and clinically significantly different amounts of visible light but similar amounts of UVR. Freshlook and Acuvue Define CLs which are designated as UV-blockers significantly reduced UVR transmission to safe levels whereas Tutti, NeoCosmo and Durasoft 3 did not. Transmission within the Freshlook CL family was more dependent on color in the visible light spectrum, but not in the UV-spectrum, where the gemstone green performing best among the tested colors. Copyright © 2013 British Contact Lens Association. Published by Elsevier Ltd. All rights reserved.

Computational Photophysics in the Presence of an Environment

NASA Astrophysics Data System (ADS)

Nogueira, Juan J.; González, Leticia

2018-04-01

Most processes triggered by ultraviolet (UV) or visible (vis) light in nature take place in complex biological environments. The first step in these photophysical events is the excitation of the absorbing system or chromophore to an electronically excited state. Such an excitation can be monitored by the UV-vis absorption spectrum. A precise calculation of the UV-vis spectrum of a chromophore embedded in an environment is a challenging task that requires the consideration of several ingredients, besides an accurate electronic-structure method for the excited states. Two of the most important are an appropriate description of the interactions between the chromophore and the environment and accounting for the vibrational motion of the whole system. In this contribution, we review the most common theoretical methodologies to describe the environment (including quantum mechanics/continuum and quantum mechanics/molecular mechanics models) and to account for vibrational sampling (including Wigner sampling and molecular dynamics). Further, we illustrate in a series of examples how the lack of these ingredients can lead to a wrong interpretation of the electronic features behind the UV-vis absorption spectrum.

Modifying the Standard Disk Model for the Ultraviolet Spectral Analysis of Disk-dominated Cataclysmic Variables. I. The Novalikes MV Lyrae, BZ Camelopardalis, and V592 Cassiopeiae.

PubMed

Godon, Patrick; Sion, Edward M; Balman, Şölen; Blair, William P

2017-09-01

The standard disk is often inadequate to model disk-dominated cataclysmic variables (CVs) and generates a spectrum that is bluer than the observed UV spectra. X-ray observations of these systems reveal an optically thin boundary layer (BL) expected to appear as an inner hole in the disk. Consequently, we truncate the inner disk. However, instead of removing the inner disk, we impose the no-shear boundary condition at the truncation radius, thereby lowering the disk temperature and generating a spectrum that better fits the UV data. With our modified disk, we analyze the archival UV spectra of three novalikes that cannot be fitted with standard disks. For the VY Scl systems MV Lyr and BZ Cam, we fit a hot inflated white dwarf (WD) with a cold modified disk ( [Formula: see text] ~ a few 10 -9 M ⊙ yr -1 ). For V592 Cas, the slightly modified disk ( [Formula: see text] ~ 6 × 10 -9 M ⊙ yr -1 ) completely dominates the UV. These results are consistent with Swift X-ray observations of these systems, revealing BLs merged with ADAF-like flows and/or hot coronae, where the advection of energy is likely launching an outflow and heating the WD, thereby explaining the high WD temperature in VY Scl systems. This is further supported by the fact that the X-ray hardness ratio increases with the shallowness of the UV slope in a small CV sample we examine. Furthermore, for 105 disk-dominated systems, the International Ultraviolet Explorer spectra UV slope decreases in the same order as the ratio of the X-ray flux to optical/UV flux: from SU UMa's, to U Gem's, Z Cam's, UX UMa's, and VY Scl's.

How Good Are Your Sunglasses?

ERIC Educational Resources Information Center

Novak, Igor

1997-01-01

Provides a description of an experiment in which students use a standard ultraviolet and intense blue (UV/VIS) spectrophotometer to measure the amount and energy of light. Explains how a simple measurement of the transmission spectrum of sunglasses can reveal differences between brands and can illustrate the destruction of the earth's ozone layer.…

Combined infrared and ultraviolet-visible spectroscopy matrix-isolated carbon vapor

NASA Technical Reports Server (NTRS)

Kurtz, Joe; Huffman, Donald R.

1990-01-01

Infrared and UV-visible absorption spectra have been measured on the same sample of matrix-isolated carbon vapor in order to establish correlations between absorption intensities of vibrational and electronic transitions as a function of sample annealing. A high degree of correlation has been found between the IR feature at 1998/cm recently assigned to C8 and a UV absorption feature at about 3100 A. Thus, for the first time, direct evidence is given for the assignment of one of the unknown UV-visible features of the long-studied matrix-isolated carbon vapor spectrum.

Observations of Cygnus X-2 with IUE: Ultraviolet results from a multiwavelength campaign

NASA Technical Reports Server (NTRS)

Vrtilek, S. D.; Raymond, J. C.; Garcia, M. R.; Verbunt, F.; Hasinger, Guenther; Kuerster, M.

1989-01-01

The observations of the low-mass x ray binary, Cyg X-2, taken with the International Ultraviolet Explorer (IUE) in a campaign conducted in June and October of 1988 are reported. A direct relationship between the strength of the UV continuum and line emission and the placement of the x ray spectrum in one of three branches of the so-called Z-shaped curve is found by comparison with simultaneous x ray observations. All three previously known x ray spectral states are detected; the UV continuum and line emission increase monotonically along the Z with the least emission in the horizontal branch, and the most in the flaring branch. Emission lines due to HeII, CIV, NIII, NIV, NV, SiIV, and MgII are observed.

EXPERIMENT - APOLLO 16 (UV)

NASA Image and Video Library

1972-06-06

S72-40820 (21 April 1972) --- A color enhancement of a photograph taken on ultra-violet light showing the spectrum of the upper atmosphere of Earth and geocorona. The bright horizontal line is far ultra-violet emission (1216 angstrom) of hydrogen extending 10 degrees (40,000 miles) either side of Earth. The knobby vertical line shows several ultra-violet emissions from Earth's sunlit atmosphere, each "lump" being produced by one type gas (oxygen, nitrogen, helium, etc.). The spectral dispersion is about 10 angstrom per millimeter on this enlargement. The UV camera/spectrograph was operated on the lunar surface by astronaut John W. Young, commander of the Apollo 16 lunar landing mission. It was designed and built at the Naval Research Laboratory, Washington, D.C. While astronauts Young and Charles M. Duke Jr., lunar module pilot, descended in the Lunar Module (LM) "Orion" to explore the Descartes highlands region of the moon, astronaut Thomas K. Mattingly II, command module pilot, remained with the Command and Service Modules (CSM) "Casper" in lunar orbit.

SR-71 Ship #1 - Ultraviolet Experiment

NASA Technical Reports Server (NTRS)

1994-01-01

NASA's SR-71 streaks into the twilight on a night/science flight from the Dryden Flight Research Center, Edwards, California. Mounted in the nose of the SR-71 was an ultraviolet video camera aimed skyward to capture images of stars, asteroids and comets. The science portion of the flight is a project of the Jet Propulsion Laboratory, Pasadena, California. Two SR-71 aircraft have been used by NASA as test beds for high-speed and high-altitude aeronautical research. One early research project flown on one of Dryden's SR-71s consisted of a proposal for a series of flights using the SR-71 as a science camera platform for the Jet Propulsion Laboratory (JPL) of the California Institute of Technology, which operates under contract to NASA in much the way that NASA centers do. In March 1993, an upward-looking ultraviolet (UV) video camera placed in the SR-71's nosebay studied a variety of celestial objects in the ultraviolet light spectrum. The SR-71 was proposed as a test bed for the experiment because it is capable of flying at altitudes above 80,000 feet for an extended length of time. Observation of ultraviolet radiation is not possible from the Earth's surface because the atmosphere's ozone layer absorbs UV rays. Study of UV radiation is important because it is known to cause skin cancer with prolonged exposure. UV radiation is also valuable to study from an astronomical perspective. Satellite study of ultraviolet radiation is very expensive. As a result, the South West Research Institute (SWRI) in Texas developed the hypothesis of using a high-flying aircraft such as the SR-71 to conduct UV observations. The SR-71 is capable of flying above 90 percent of the Earth's atmosphere. The flight program was also designed to test the stability of the aircraft as a test bed for UV observation. A joint flight program was developed between the JPL and NASA's Ames-Dryden Flight Research Facility (redesignated the Dryden Flight Research Center, Edwards, California, in 1994) in conjunction with SWRI to test the hypothesis. Dryden modified the nosebay of the SR-71, creating an upward-observing window to carry SWRI's ultraviolet CCD camera so it could make observations. According to Dryden's SR-71 Project Manager Dave Lux, a single flight of the aircraft confirmed the aircraft's capability and stability as a test bed for UV observations. SWRI's principle investigator was Dr. Allen Stern.

The B3-VLA CSS sample. VIII. New optical identifications from the Sloan Digital Sky Survey The ultraviolet-optical spectral energy distribution of the young radio sources

NASA Astrophysics Data System (ADS)

Fanti, C.; Fanti, R.; Zanichelli, A.; Dallacasa, D.; Stanghellini, C.

2011-04-01

Context. Compact steep-spectrum radio sources and giga-hertz peaked spectrum radio sources (CSS/GPS) are generally considered to be mostly young radio sources. In recent years we studied at many wavelengths a sample of these objects selected from the B3-VLA catalog: the B3-VLA CSS sample. Only ≈60% of the sources were optically identified. Aims: We aim to increase the number of optical identifications and study the properties of the host galaxies of young radio sources. Methods: We cross-correlated the CSS B3-VLA sample with the Sloan Digital Sky Survey (SDSS), DR7, and complemented the SDSS photometry with available GALEX (DR 4/5 and 6) and near-IR data from UKIRT and 2MASS. Results: We obtained new identifications and photometric redshifts for eight faint galaxies and for one quasar and two quasar candidates. Overall we have 27 galaxies with SDSS photometry in five bands, for which we derived the ultraviolet-optical spectral energy distribution (UV-O-SED). We extended our investigation to additional CSS/GPS selected from the literature. Most of the galaxies show an excess of ultra-violet (UV) radiation compared with the UV-O-SED of local radio-quiet ellipticals. We found a strong dependence of the UV excess on redshift and analyzed it assuming that it is generated either from the nucleus (hidden quasar) or from a young stellar population (YSP). We also compare the UV-O-SEDs of our CSS/GPS sources with those of a selection of large size (LSO) powerful radio sources from the literature. Conclusions: If the major process of the UV excess is caused by a YSP, our conclusion is that it is the result of the merger process that also triggered the onset of the radio source with some time delay. We do not see evidence for a major contribution from a YSP triggered by the radio sources itself. Appendices A-G are only available in electronic form at http://www.aanda.org

Photocatalytic reactive oxygen species production and phototoxicity of titanium dioxide nanoparticles are dependent on the solar ultraviolet radiation spectrum.

PubMed

Ma, Hongbo; Brennan, Amanda; Diamond, Stephen A

2012-09-01

Generation of reactive oxygen species (ROS) by titanium dioxide nanoparticles (nano-TiO(2)) and its consequent phototoxicity to Daphnia magna were measured under different solar ultraviolet (UV) spectra by applying a series of optical filters in a solar simulator. Removing UV-B (280-320 nm) from solar radiation had no significant impact on photocatalytic ROS production of nano-TiO(2), whereas removal of UV-A (320-400 nm) decreased ROS production remarkably. Removal of wavelengths below 400 nm resulted in negligible ROS production. A linear correlation between ROS production and D. magna immobilization suggests that photocatalytic ROS production may be a predictor of phototoxicity for nano-TiO(2). Intracellular ROS production within D. magna was consistent with the immobilization of the organism under different solar UV spectra, indicating that oxidative stress was involved in phototoxicity. The dependence of nano-TiO(2) phototoxicity on environmentally realistic variations in solar radiation suggests that risk assessment of these nanomaterials requires careful evaluation of exposure conditions in the environment. Copyright © 2012 SETAC.

Abnormal ultraviolet mutagenic spectrum in plasmid DNA replicated in cultured fibroblasts from a patient with the skin cancer-prone disease, xeroderma pigmentosum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seetharam, S.; Protic-Sabljic, M.; Seidman, M.M.

1987-12-01

A shuttle vector plasmid, pZ189, was utilized to assess the types of mutations that cells from a patient with xeroderma pigmentosum, complementation group D, introduce into ultraviolet (UV) damaged, replicating DNA. Patients with xeroderma pigmentosum have clinical and cellular UV hypersensitivity, increased frequency of sun-induced skin cancer, and deficient DNA repair. In comparison to UV-treated pZ189 replicated in DNA repair-proficient cells, there were fewer surviving plasmids, a higher frequency of plasmids with mutations, fewer plasmids with two or more mutations in the marker gene, and a new mutagenic hotspot. The major type of base substitution mutation was the G:C tomore » A:T transition with both cell lines. These results, together with similar findings published earlier with cells from a xeroderma pigmentosum patient in complementation group A, suggest that isolated G:C to A:T somatic mutations may be particularly important in generation of human skin cancer by UV radiation.« less

Pollen and spores as biological recorders of past ultraviolet irradiance.

NASA Astrophysics Data System (ADS)

Fraser, Wesley; Jardine, Phillip; Lomax, Barry; Sephton, Mark; Shanahan, Timothy; Miller, Charlotte; Gosling, William

2017-04-01

Ultraviolet (UV) irradiance from the Sun is a key driver of climatic and biotic change. UV irradiance modulates processes in the stratosphere, and influences the biosphere from ecosystem-level through to the largest scale patterns of diversification and extinction. Yet our understanding of UV irradiance is limited to the present; no validated empirical method exists to reconstruct UV flux over long, geologically relevant timescales. Here, we show that a recently developed proxy for UV irradiance based on spore and pollen chemistry can be used over long (100,000 years) timescales. First, we demonstrate spatial variation in spore and pollen chemistry correlate with known latitudinal solar irradiance gradients. Second, using this relationship we provide a reconstruction of past changes in solar irradiance based on the pollen record obtained from Lake Bosumtwi in Ghana. Variations in the chemistry of grass pollen from the Lake Bosumtwi record show a link to multiple orbital precessional cycles (19-21,000 years). By providing a unique, local proxy for broad spectrum solar irradiance, the chemical analysis of spores and pollen offers unprecedented opportunities to decouple solar variability, climate and vegetation change through geologic time and a new proxy with which to probe the Earth system.

Far Ultraviolet Spectroscopy of Saturn's Icy Moon Rhea

NASA Astrophysics Data System (ADS)

Elowitz, Mark; Hendrix, Amanda; Mason, Nigel J.; Sivaraman, Bhalamurugan

2018-01-01

We present an analysis of spatially resolved, far-UV reflectance spectra of Saturn’s icy satellite Rhea, collected by the Cassini Ultraviolet Imaging Spectrograph (UVIS). In recent years ultraviolet spectroscopy has become an important tool for analysing the icy satellites of the outer solar system (1Hendrix & Hansen, 2008). Far-UV spectroscopy provides unique information about the molecular structure and electronic transitions of chemical species. Many molecules that are suspected to be present in the icy surfaces of moons in the outer solar system have broad absorption features due to electronic transitions that occur in the far-UV portion of the spectrum. The studies show that Rhea, like the other icy satellites of the Saturnian system are dominated by water-ice as evident by the 165-nm absorption edge, with minor UV absorbing contaminants. Far-UV spectra of several Saturnian icy satellites, including Rhea and Dione, show an unexplained weak absorption feature centered near 184 nm. To carry out the geochemical survey of Rhea’s surface, the UVIS observations are compared with vacuum-UV spectra of thin-ice samples measured in laboratory experiments. Thin film laboratory spectra of water-ice and other molecular compounds in the solid phase were collected at near-vacuum conditions and temperatures identical to those at the surface of Rhea. Comparison between the observed far-UV spectra of Rhea’s surface ice and modelled spectra based on laboratory absorption measurements of different non-water-ice compounds show that two possible chemical compounds could explain the 184-nm absorption feature. The two molecular compounds include simple chlorine molecules and hydrazine monohydrate. Attempts to explain the source(s) of these compounds on Rhea and the scientific implications of their possible discovery will be summarized.[1] Hendrix, A. R. & Hansen, C. J. (2008). Icarus, 193, pp. 323-333.

Fast simulation tool for ultraviolet radiation at the earth's surface

NASA Astrophysics Data System (ADS)

Engelsen, Ola; Kylling, Arve

2005-04-01

FastRT is a fast, yet accurate, UV simulation tool that computes downward surface UV doses, UV indices, and irradiances in the spectral range 290 to 400 nm with a resolution as small as 0.05 nm. It computes a full UV spectrum within a few milliseconds on a standard PC, and enables the user to convolve the spectrum with user-defined and built-in spectral response functions including the International Commission on Illumination (CIE) erythemal response function used for UV index calculations. The program accounts for the main radiative input parameters, i.e., instrumental characteristics, solar zenith angle, ozone column, aerosol loading, clouds, surface albedo, and surface altitude. FastRT is based on look-up tables of carefully selected entries of atmospheric transmittances and spherical albedos, and exploits the smoothness of these quantities with respect to atmospheric, surface, geometrical, and spectral parameters. An interactive site, http://nadir.nilu.no/~olaeng/fastrt/fastrt.html, enables the public to run the FastRT program with most input options. This page also contains updated information about FastRT and links to freely downloadable source codes and binaries.

Ultraviolet Spectroscopy of Supernovae: The First Two Years of Swift Observations

NASA Technical Reports Server (NTRS)

Immler, Stefan

2008-01-01

We present the entire sample of ultraviolet (1JV) spectra of supernovae (SNe) obtained with the Ultraviolet/Optical Telescope (UVOT) on board the Swift satellite during the first 2 years of observations (2005/2006). A total of 31 UV-grism and 22 V-grism spectra of 9 supernovae (SNe) have been collected. of which 6 are thermonuclear (type Ia) and 3 core collapse (type Ibc/II) SNe. All the spectra have been obtained during the photospheric phase. After a comparison of the spectra of our sample with those in the literature (SNe 1992A. 1990N and 1999em). we confirm some degree of diversity in the UV emission of Type Ia SNe and a greater homogeneity in the Type I1 Plateau SN sample. Signatures of interaction between the ejecta and the circumstellar environment have been found in the UV spectrum of SN 2006jc, the only SN Type Ib/c for which UVOT grism data are available. Currently, Swift LJVOT is the best suited instrument for early SN studies in the UV due to its fast response and flexible scheduling capabilities. However. in order to increase the quality of the data and significantly improve our understanding of the lJV properties of SNe and to fully maximize the scientific potential of UVOT grism observations. a larger investment in obsening time and longer exposures are needed.

Towards a high performing UV-A sensor based on Silicon Carbide and hydrogenated Silicon Nitride absorbing layers

NASA Astrophysics Data System (ADS)

Mazzillo, M.; Sciuto, A.; Mannino, G.; Renna, L.; Costa, N.; Badalà, P.

2016-10-01

Exposure to ultraviolet (UV) radiation is a major risk factor for most skin cancers. The sun is our primary natural source of UV radiation. The strength of the sun's ultraviolet radiation is expressed as Solar UV Index (UVI). UV-A (320-400 nm) and UV-B (290-320 nm) rays mostly contribute to UVI. UV-B is typically the most destructive form of UV radiation because it has enough energy to cause photochemical damage to cellular DNA. Also overexposure to UV-A rays, although these are less energetic than UV-B photons, has been associated with toughening of the skin, suppression of the immune system, and cataract formation. The use of preventive measures to decrease sunlight UV radiation absorption is fundamental to reduce acute and irreversible health diseases to skin, eyes and immune system. In this perspective UV sensors able to monitor in a monolithic and compact chip the UV Index and relative UV-A and UV-B components of solar spectrum can play a relevant role for prevention, especially in view of the integration of these detectors in close at hand portable devices. Here we present the preliminary results obtained on our UV-A sensor technology based on the use of hydrogenated Silicon Nitride (SiN:H) thin passivating layers deposited on the surface of thin continuous metal film Ni2Si/4H-SiC Schottky detectors, already used for UV-Index monitoring. The first UV-A detector prototypes exhibit a very low leakage current density of about 0.2 pA/mm2 and a peak responsivity value of 0.027 A/W at 330 nm, both measured at 0V bias.

Invisible ink mark detection in the visible spectrum using absorption difference.

PubMed

Lee, Joong; Kong, Seong G; Kang, Tae-Yi; Kim, Byounghyun; Jeon, Oc-Yeub

2014-03-01

One of popular techniques in gambling fraud involves the use of invisible ink marks printed on the back surface of playing cards. Such covert patterns are transparent in the visible spectrum and therefore invisible to unaided human eyes. Invisible patterns can be made visible with ultraviolet (UV) illumination or a CCD camera installed with an infrared (IR) filter depending on the type of ink materials used. Cheating gamers often wear contact lenses or eyeglasses made of IR or UV filters to recognize the secret marks on the playing cards. This paper presents an image processing technique to reveal invisible ink patterns in the visible spectrum without the aid of special equipment such as UV lighting or IR filters. A printed invisible ink pattern leaves a thin coating on the surface with different refractive index for different wavelengths of light, which results in color dispersion or absorption difference. The proposed method finds the differences of color components caused by absorption difference to detect invisible ink patterns on the surface. Experiment results show that the proposed scheme is effective for both UV-active and IR-active invisible ink materials. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

UV-B radiation amplification factor determined based on the simultaneous observation of total ozone and global spectral irradiance

NASA Technical Reports Server (NTRS)

Ito, T.; Sakoda, Y.; Matsubara, K.; Kajihara, R.; Uekubo, T.; Kobayashi, M.; Shitamichi, M.; Ueno, T.; Ito, M.

1994-01-01

The Japan Meteorological Agency started the spectral observation of solar ultraviolet (UV) irradiance on 1 January 1990 at Tateno, Aerological Observatory in Tsukuba (35 deg N, 140 deg E). The observation has been carried out using the Brewer spectrophotometer for the wavelengths from 290 to 325 nm with a 0.5 nm interval every hour from 30 minutes before sunrise to 30 minutes after sunset throughout a year. Because of remarkable similarity within observed spectra, an observed spectrum can be expressed by a simple combination of a reference spectrum and two parameters expressing the deformation of the observed spectrum from the reference. By use of the relation between one of the deformation parameters and the total ozone simultaneously observed with the Dobson spectrophotometer, the possible increase of UV irradiance due to ozone depletion is estimated. For damaging UV, the irradiance possibly increases about 19 percent with the ozone depletion of 10 percent at noon throughout the year in the northern midlatitudes. DUV at noon on the summer solstice possibly increases about 5.6 percent with the ozone depletion of 10 m atm-cm for all latitudes in the Northern Hemisphere.

Improved intact soil-core carbon determination applying regression shrinkage and variable selection techniques to complete spectrum laser-induced breakdown spectroscopy (LIBS).

PubMed

Bricklemyer, Ross S; Brown, David J; Turk, Philip J; Clegg, Sam M

2013-10-01

Laser-induced breakdown spectroscopy (LIBS) provides a potential method for rapid, in situ soil C measurement. In previous research on the application of LIBS to intact soil cores, we hypothesized that ultraviolet (UV) spectrum LIBS (200-300 nm) might not provide sufficient elemental information to reliably discriminate between soil organic C (SOC) and inorganic C (IC). In this study, using a custom complete spectrum (245-925 nm) core-scanning LIBS instrument, we analyzed 60 intact soil cores from six wheat fields. Predictive multi-response partial least squares (PLS2) models using full and reduced spectrum LIBS were compared for directly determining soil total C (TC), IC, and SOC. Two regression shrinkage and variable selection approaches, the least absolute shrinkage and selection operator (LASSO) and sparse multivariate regression with covariance estimation (MRCE), were tested for soil C predictions and the identification of wavelengths important for soil C prediction. Using complete spectrum LIBS for PLS2 modeling reduced the calibration standard error of prediction (SEP) 15 and 19% for TC and IC, respectively, compared to UV spectrum LIBS. The LASSO and MRCE approaches provided significantly improved calibration accuracy and reduced SEP 32-55% over UV spectrum PLS2 models. We conclude that (1) complete spectrum LIBS is superior to UV spectrum LIBS for predicting soil C for intact soil cores without pretreatment; (2) LASSO and MRCE approaches provide improved calibration prediction accuracy over PLS2 but require additional testing with increased soil and target analyte diversity; and (3) measurement errors associated with analyzing intact cores (e.g., sample density and surface roughness) require further study and quantification.

Horizontal and sun-normal spectral biologically effective ultraviolet irradiances.

PubMed

Parisi, A V; Kimlin, M G

1999-01-01

The dependence of the spectral biologically effective solar UV irradiance on the orientation of the receiver with respect to the sun has been determined for relatively cloud-free days at a sub-tropical Southern Hemisphere latitude for the solar zenith angle range 35-64 degrees. For the UV and biologically effective irradiances, the sun-normal to horizontal ratio for the total UV ranges from 1.18 +/- 0.05 to 1.27 +/- 0.06. The sun-normal to horizontal ratio for biologically effective irradiance is dependent on the relative effectiveness of the relevant action spectrum in the UV-A waveband. In contrast to the total UV, the diffuse UV and diffuse biologically effective irradiances are reduced in a sun-normal compared with a horizontal orientation by a factor ranging from 0.70 +/- 0.05 to 0.76 +/- 0.03.

Skyglow effects in UV and visible spectra: Radiative fluxes

NASA Astrophysics Data System (ADS)

Kocifaj, Miroslav; Solano Lamphar, Hector Antonio

2013-09-01

Several studies have tried to understand the mechanisms and effects of radiative transfer under different night-sky conditions. However, most of these studies are limited to the various effects of visible spectra. Nevertheless, the invisible parts of the electromagnetic spectrum can pose a more profound threat to nature. One visible threat is from what is popularly termed skyglow. Such skyglow is caused by injudiciously situated or designed artificial night lighting systems which degrade desired sky viewing. Therefore, since lamp emissions are not limited to visible electromagnetic spectra, it is necessary to consider the complete spectrum of such lamps in order to understand the physical behaviour of diffuse radiation at terrain level. In this paper, the downward diffuse radiative flux is computed in a two-stream approximation and obtained ultraviolet spectral radiative fluxes are inter-related with luminous fluxes. Such a method then permits an estimate of ultraviolet radiation if the traditionally measured illuminance on a horizontal plane is available. The utility of such a comparison of two spectral bands is shown, using the different lamp types employed in street lighting. The data demonstrate that it is insufficient to specify lamp type and its visible flux production independently of each other. Also the UV emissions have to be treated by modellers and environmental scientists because some light sources can be fairly important pollutants in the near ultraviolet. Such light sources can affect both the living organisms and ambient environment.

Developing an Approach to Model UV Fluxes in Smoke Laden Conditions over Central Asia

NASA Astrophysics Data System (ADS)

Park, Y. H.; Sokolik, I. N.

2016-12-01

The UV characteristics of smoke aerosols are valuable inputs to the UV Index forecasts, air quality studies, and assessments of the impact of regional environmental changes. The wavelength dependence of light absorption by aerosol particles is pronounced throughout the UV spectral region. Also in assumption that smoke consists of BC, OC, and Sulfate, the mass fraction of smoke is different with fire types. The purpose of this study is to introduce an approach to calculate the UV fluxes in the aerosol laden conditions, and investigate the irradiance compared to measured irradiance in the UV spectrum. To compute the spectral optical properties (e.g., the effective single scattering albedo, asymmetry parameter, and aerosol optical thickness) for the selected scenarios, the representative size distribution and the refractive index are selected and used in the Mie code. Smoke aerosol information (e.g. emission injection height, mass concentration of smoke components) from WRF Chem is applied to run tropospheric ultraviolet and visible (TUV) model. Using the TUV model, we make the comparisons between model and measured irradiance in UV spectrum in smoke aerosol conditions. An advantage of this approach and the uncertainty of the evaluation are discussed. Overall, the results of this investigation show that this approach is valuable to estimate UV fluxes in smoke laden conditions.

A refractory metamaterial absorber for ultra-broadband, omnidirectional and polarization-independent absorption in the UV-NIR spectrum.

PubMed

Huang, Yijia; Liu, Ling; Pu, Mingbo; Li, Xiong; Ma, Xiaoliang; Luo, Xiangang

2018-05-03

In this paper, efficient ultra-broadband absorption from ultraviolet (UV) to near infrared (NIR) is achieved using a metamaterial perfect absorber (MPA) with refractory constituents. Both simulated and experimental results indicate that this proposed MPA exhibits an average absorption over 95% at wavelengths ranging from 200 nm to 900 nm. Besides, owing to the ultrathin thickness and symmetrical topology of this device, it exhibits great angular tolerance up to 60° independent of the incident polarizations. Excellent thermal stability is also demonstrated at high operation temperatures. The physical origin of the ultra-broadband characteristics is mainly based on diffraction/interference engineering at short wavelengths and the anti-reflection effect at long wavelengths. We believe that such a device may find potential applications ranging from photodetection and photothermal energy conversion to ultraviolet protection and thermophotovoltaics.

Revealing Invisible Beauty, Ultra Detailed: The Influence of Low Cost UV Exposure on Natural History Specimens in 2D+ Digitization

PubMed Central

Brecko, Jonathan; Mathys, Aurore; Dekoninck, Wouter; De Ceukelaire, Marleen; VandenSpiegel, Didier; Semal, Patrick

2016-01-01

Digitization of the natural history specimens usually occurs by taking detailed pictures from different sides or producing 3D models. Additionally this is normally limited to imaging the specimen while exposed by light of the visual spectrum. However many specimens can see in or react to other spectra as well. Fluorescence is a well known reaction to the ultraviolet (UV) spectrum by animals, plants, minerals etc. but rarely taken into account while examining natural history specimens. Our tests show that museum specimens still fluoresce when exposed to UV light of 395 nm and 365 nm, even after many years of preservation. When the UV exposure is used in the digitization of specimens using our low cost focus stacking (2D+) setup, the resulting pictures reveal more detail than the conventional 2D+ images. Differences in fluorescence using 395 nm or 365 nm UV lights were noticed, however there isn’t a preferred wavelength as some specimens react more to the first, while others have better results with the latter exposure. Given the increased detail and the low cost of the system, UV exposure should be considered while digitizing natural history museum collections. PMID:27536993

Effects of ultraviolet radiation on photosynthetic performance and N2 fixation in Trichodesmium erythraeum IMS 101

NASA Astrophysics Data System (ADS)

Cai, Xiaoni; Hutchins, David A.; Fu, Feixue; Gao, Kunshan

2017-10-01

Biological effects of ultraviolet radiation (UVR; 280-400 nm) on marine primary producers are of general concern, as oceanic carbon fixers that contribute to the marine biological CO2 pump are being exposed to increasing UV irradiance due to global change and ozone depletion. We investigated the effects of UV-B (280-320 nm) and UV-A (320-400 nm) on the biogeochemically critical filamentous marine N2-fixing cyanobacterium Trichodesmium (strain IMS101) using a solar simulator as well as under natural solar radiation. Short exposure to UV-B, UV-A, or integrated total UVR significantly reduced the effective quantum yield of photosystem II (PSII) and photosynthetic carbon and N2 fixation rates. Cells acclimated to low light were more sensitive to UV exposure compared to high-light-grown ones, which had more UV-absorbing compounds, most likely mycosporine-like amino acids (MAAs). After acclimation under natural sunlight, the specific growth rate was lower (by up to 44 %), MAA content was higher, and average trichome length was shorter (by up to 22 %) in the full spectrum of solar radiation with UVR, than under a photosynthetically active radiation (PAR) alone treatment (400-700 nm). These results suggest that prior shipboard experiments in UV-opaque containers may have substantially overestimated in situ nitrogen fixation rates by Trichodesmium, and that natural and anthropogenic elevation of UV radiation intensity could significantly inhibit this vital source of new nitrogen to the current and future oligotrophic oceans.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shamirzaev, V. T., E-mail: tim@isp.nsc.ru; Gaisler, V. A.; Shamirzaev, T. S.

The spectrum of ultraviolet (UV) InGaN/GaN light-emitting diodes and its dependence on the current flowing through the structure are studied. The intensity of the UV contribution to the integrated diode luminescence increases steadily with increasing density of current flowing through the structure, despite a drop in the emission quantum efficiency. The electroluminescence excitation conditions that allow the fraction of UV emission to be increased to 97% are established. It is shown that the nonuniform generation of extended defects, which penetrate the active region of the light-emitting diodes as the structures degrade upon local current overheating, reduces the integrated emission intensitymore » but does not affect the relative intensity of diode emission in the UV (370 nm) and visible (550 nm) spectral ranges.« less

Using an Ongoing Study of Terrestrial Plant Response to Ultraviolet Radiation in Project ALERT

NASA Technical Reports Server (NTRS)

Condon, Estelle; Skiles, J. W.; Seitz, Jeffery C.; Dantoni, Hector L.

1998-01-01

The ALERT (Augmented Learning Environment for Renewable Teaching) Project is a cooperative California-based program with two main partners: California State University (CSU) geoscience and education departments and two NASA Centers, the Jet Propulsion Laboratory (JPL) in Pasadena and the Ames Research Center (ARC) in Mountain View. This paper presents an example of how a NASA research effort can be used in the undergraduate classroom. A study, now in the fourth year, subjects test plants to exposures of varying solar ultraviolet (UV) radiation (280 - 340 nm); a full solar UV exposure, a solar UV exposure less about 14% of ambient UV flux, and a UV-blocked regime. This experiment is simple in that only modest amounts of expense are required yet it is elegant since only one variable, UV-flux is involved. The experiment lends itself to teaching several of the Earth Sciences because it uses information from botany, taxonomy, and ecology. Aspects of physics are inherent in the study since portions of the electromagnetic spectrum are studied. Further, since only one of many variables are manipulated, UV flux, the study demonstrates how the scientific method is used in formulating and testing hypotheses. Based on the ALERT experience this summer, this study will be implemented at a CSU campus with the expectation that it will serve as a pedagogical tool and where it will involve students in actual research.

Modifying the Standard Disk Model for the Ultraviolet Spectral Analysis of Disk-dominated Cataclysmic Variables. I. The Novalikes MV Lyrae, BZ Camelopardalis, and V592 Cassiopeiae

NASA Astrophysics Data System (ADS)

Godon, Patrick; Sion, Edward M.; Balman, Şölen; Blair, William P.

2017-09-01

The standard disk is often inadequate to model disk-dominated cataclysmic variables (CVs) and generates a spectrum that is bluer than the observed UV spectra. X-ray observations of these systems reveal an optically thin boundary layer (BL) expected to appear as an inner hole in the disk. Consequently, we truncate the inner disk. However, instead of removing the inner disk, we impose the no-shear boundary condition at the truncation radius, thereby lowering the disk temperature and generating a spectrum that better fits the UV data. With our modified disk, we analyze the archival UV spectra of three novalikes that cannot be fitted with standard disks. For the VY Scl systems MV Lyr and BZ Cam, we fit a hot inflated white dwarf (WD) with a cold modified disk (\\dot{M} ˜ a few 10-9 M ⊙ yr-1). For V592 Cas, the slightly modified disk (\\dot{M}˜ 6× {10}-9 {M}⊙ {{yr}}-1) completely dominates the UV. These results are consistent with Swift X-ray observations of these systems, revealing BLs merged with ADAF-like flows and/or hot coronae, where the advection of energy is likely launching an outflow and heating the WD, thereby explaining the high WD temperature in VY Scl systems. This is further supported by the fact that the X-ray hardness ratio increases with the shallowness of the UV slope in a small CV sample we examine. Furthermore, for 105 disk-dominated systems, the International Ultraviolet Explorer spectra UV slope decreases in the same order as the ratio of the X-ray flux to optical/UV flux: from SU UMa’s, to U Gem’s, Z Cam’s, UX UMa’s, and VY Scl’s.

Laser spectroscopic study of β-estradiol and its monohydrated clusters in a supersonic jet.

PubMed

Morishima, Fumiya; Inokuchi, Yoshiya; Ebata, Takayuki

2012-08-09

The structures of 17β-estradiol (estradiol) and its 1:1 cluster with water have been investigated in supersonic jets. The S(1)-S(0) electronic spectrum of estradiol monomer shows four strong sharp bands in the 35050-35200 cm(-1) region. Ultraviolet-ultraviolet hole-burning (UV-UV HB) and infrared-ultraviolet double-resonance (IR-UV DR) spectra of these bands indicate that they are due to four different conformers of estradiol originating from the different orientation of the OH groups in the A- and D-rings. The addition of water vapor to the sample gas generates four new bands in the 34700-34800 cm(-1) region, which are assigned to the estradiol-H(2)O 1:1 cluster with the A-ring (phenyl ring) OH acting as a hydrogen(H)-bond donor. In addition, we found very weak bands near the origin bands of bare estradiol upon the addition of water vapor. These bands are assigned to the isomers of estradiol-H(2)O 1:1 cluster having an H-bond at the D-ring OH. We determine the conformation of bare estradiol and the structures of its monohydrated clusters with the aid of density functional theory calculation and discuss the relationship between the stability of hydrated clusters and the conformation of estradiol.

Physical Conditions in the Ultraviolet Absorbers of IRAS F22456-5125

NASA Astrophysics Data System (ADS)

Dunn, Jay P.; Crenshaw, D. Michael; Kraemer, S. B.; Trippe, M. L.

2010-04-01

We present the ultraviolet (UV) and X-ray spectra observed with the Far Ultraviolet Spectroscopic Explorer (FUSE) and the XMM-Newton satellite, respectively, of the low-z Seyfert 1 galaxy IRAS F22456 - 5125. This object shows absorption from five distinct, narrow kinematic components that span a significant range in velocity (~0 to -700 km s-1) and ionization (Lyman series, C III, N III, and O VI). We also show that three of the five kinematic components in these lines appear to be saturated in Lyβ λ1026 and that all five components show evidence of saturation in the O VI doublet lines λλ1032, 1038. Further, all five components show evidence for partial covering due to the absorption seen in the O VI doublet. This object is peculiar because it shows no evidence for corresponding X-ray absorption to the UV absorption in the X-ray spectrum, which violates the 1:1 correlation known for low-z active galactic nuclei (AGNs). We perform photoionization modeling of the UV absorption lines and predict that the O VII column density should be small, which would produce little to no absorption in agreement with the X-ray observation. We also examine the UV variability of the continuum flux for this object (an increase of a factor of 6). As the absorption components lack variability, we find a lower limit of ~20 kpc for the distance for the absorbers from the central AGN. Based on observations made with the NASA-CNES-CSA Far Ultraviolet Spectroscopic Explorer. FUSE is operated for NASA by the Johns Hopkins University under NASA contract NAS5-32985.

Action spectra affect variability of the climatology of biologically effective ultraviolet radiation on cloud-free days.

PubMed

Grifoni, D; Zipoli, G; Sabatini, F; Messeri, G; Bacci, L

2013-12-01

Action spectrum (AS) describes the relative effectiveness of ultraviolet (UV) radiation in producing biological effects and allows spectral UV irradiance to be weighted in order to compute biologically effective UV radiation (UVBE). The aim of this research was to study the seasonal and latitudinal distribution over Europe of daily UVBE doses responsible for various biological effects on humans and plants. Clear sky UV radiation spectra were computed at 30-min time intervals for the first day of each month of the year for Rome, Potsdam and Trondheim using a radiative transfer model fed with climatological data. Spectral data were weighted using AS for erythema, vitamin D synthesis, cataract and photokeratitis for humans, while the generalised plant damage and the plant damage AS were used for plants. The daily UVBE doses for the above-mentioned biological processes were computed and are analysed in this study. The patterns of variation due to season (for each location) and latitude (for each date) resulted as being specific for each adopted AS. The biological implications of these results are briefly discussed highlighting the importance of a specific UVBE climatology for each biological process.

Solar ultraviolet radiation induces biological alterations in human skin in vitro: relevance of a well-balanced UVA/UVB protection.

PubMed

Bernerd, Francoise; Marionnet, Claire; Duval, Christine

2012-06-01

Cutaneous damages such as sunburn, pigmentation, and photoaging are known to be induced by acute as well as repetitive sun exposure. Not only for basic research, but also for the design of the most efficient photoprotection, it is crucial to understand and identify the early biological events occurring after ultraviolet (UV) exposure. Reconstructed human skin models provide excellent and reliable in vitro tools to study the UV-induced alterations of the different skin cell types, keratinocytes, fibroblasts, and melanocytes in a dose- and time-dependent manner. Using different in vitro human skin models, the effects of UV light (UVB and UVA) were investigated. UVB-induced damages are essentially epidermal, with the typical sunburn cells and DNA lesions, whereas UVA radiation-induced damages are mostly located within the dermal compartment. Pigmentation can also be obtained after solar simulated radiation exposure of pigmented reconstructed skin model. Those models are also highly adequate to assess the potential of sunscreens to protect the skin from UV-associated damage, sunburn reaction, photoaging, and pigmentation. The results showed that an effective photoprotection is provided by broad-spectrum sunscreens with a potent absorption in both UVB and UVA ranges.

The role of ultraviolet colour in the assessment of mimetic accuracy between Batesian mimics and their models: a case study using ant-mimicking spiders

NASA Astrophysics Data System (ADS)

Corcobado, Guadalupe; Herberstein, Marie E.; Pekár, Stano

2016-12-01

The use of ultraviolet (UV) cues for intra- and inter-specific communication is common in many animal species. Still, the role of UV signals under some predator-prey contexts, such as Batesian mimicry, is not clear. Batesian mimicry is a defensive strategy by which a palatable species (the mimic) resembles an unpalatable or noxious species (the model) to avoid predation. This strategy has evolved independently in many different taxa that are predated by species capable of UV perception. Moreover, there is considerable variation in how accurately Batesian mimics resemble their models across species. Our aim was to investigate how UV colour contributed to mimetic accuracy using several ant-mimicking spider species as a case study. We measured the reflectance spectrum (300-700 nm) for several species of mimics and models, and we tested whether they differ in visible and UV colour. We modelled whether two different predators could discriminate between mimics and models using colour information. We found that generally, ant-mimicking spiders differed significantly from their ant models in UV colour and that information from the visible range of light cannot be extrapolated into the UV. Our modelling suggested that wasps should be able to discriminate between mimics and models combining information from visible and the UV light, whereas birds may not discriminate between them. Thus, we show that UV colour can influence mimic accuracy and we discuss its potential role in Batesian mimicry. We conclude that colour, especially in the UV range, should be taken into account when measuring mimetic accuracy.

Comparison of Five Modeling Approaches to Quantify and Estimate the Effect of Clouds on the Radiation Amplification Factor (RAF) for Solar Ultraviolet Radiation

EPA Science Inventory

A generally accepted value for the Radiation Amplification Factor (RAF), with respect to the erythemal action spectrum for sunburn of human skin, is −1.1, indicating that a 1.0% increase in stratospheric ozone leads to a 1.1% decrease in the biologically damaging UV radiation in ...

40 CFR 796.1050 - Absorption in aqueous solution: Ultraviolet/visible spectra.

Code of Federal Regulations, 2011 CFR

2011-07-01

....50 λ in nm 235 257 313 350 (2) Fluoranthene (in methanol) from C.R.C. Atlas of Spectral Data...-nitrophenol (in methanol) from C.R.C. Atlas of Spectral Data, paragraph (d)(3) of this section: log ε 3.88 4... to obtain the UV-VIS spectrum of the test compound. Such an instrument should have a photometric...

Why is it advantageous for animals to detect celestial polarization in the ultraviolet? Skylight polarization under clouds and canopies is strongest in the UV.

PubMed

Barta, András; Horváth, Gábor

2004-02-21

The perception of skylight polarization in the ultraviolet (UV) by many insect species for orientation purposes is rather surprising, because both the degree of linear polarization and the radiance of light from the clear sky are considerably lower in the UV than in the blue or green. In this work we call this the "UV-sky-pol paradox". Although in the past, several attempts have been made to resolve this paradox, none of them was convincing. We present here a possible quantitative resolution to the paradox. We show by a model calculation that if the air layer between a cloud and a ground-based observer is partly sunlit, the degree of linear polarization p of skylight originating from the cloudy region is highest in the UV, because in this spectral range the unpolarized UV-deficient cloudlight dilutes least the polarized light scattered in the air beneath the cloud. Similarly, if the air under foliage is partly sunlit, p of downwelling light from the canopied region is maximal in the UV, because in this part of spectrum the unpolarized UV-deficient green canopylight dilutes least the polarized light scattered in the air beneath the canopy. Therefore, the detection of polarization of downwelling light under clouds or canopies is most advantageous in the UV, in which spectral range the risk is the smallest that the degree of polarization p is lower than the threshold p(tr) of polarization sensitivity in animals. On the other hand, under clear skies there is no favoured wavelength for perception of celestial polarization, because p of skylight is high enough (p > p(tr)) at all wavelengths. We show that there is an analogy between the detection of UV skylight polarization and the polarotactic water detection in the UV. However, insects perceive skylight polarization by UV or blue or green receptors. The question, why they differ in the spectral channel used for the detection of celestial polarization cannot be answered at the present time, because data are insufficient. Nevertheless, we present here one possible atmospheric optical reason why certain visual systems involved in detecting celestial polarization, are specifically tuned to the UV part of the spectrum.

The ultraviolet and visible spectrum of the polycyclic aromatic hydrocarbon C10H8(+) - Possible contributions to the diffuse interstellar bands and to the ultraviolet-visible extinction

NASA Technical Reports Server (NTRS)

Salama, F.; Allamandola, L. J.

1992-01-01

The properties of the cation of the PAH naphthalene (C10H8(+)) isolated in inert gas matrices under conditions relevant to astrophysical environments are described. The band at 6741 A is the strongest and falls close to the weak 6742 A diffuse interstellar bands (DIBs). Five other weaker bands also fall remarkably close to the positions of known DIBs. A very intense and broad continuum extended from the UV to the visible, which seems to be associated with the ion, is reported. The molar absorption coefficient at the peak of the continuum is 2.0 x 10 exp 6 cu dm/mol cm. If a continuum is a general property of PAH cations, this characteristic will have a strong impact on the understanding of how PAHs convert interstellar UV and visible radiation into IR radiation.

Quasi-simultaneous observations of the BL Lac object MK 501 in X-ray, UV, visible, IR and radio frequencies

NASA Technical Reports Server (NTRS)

Kondo, D. M.; Worrall, D. M.; Mushotzky, R. F.; Hackney, R. L.; Hackney, K. H.; Oke, J. B.; Yee, H.; Neugebauer, G.; Matthews, K.; Feldman, P. A.

1980-01-01

Quasi-simultaneous observations of the BL Lacertae (Lac) objects MK 501 were performed for the first time at X-ray, ultraviolet, visible, infrared, and radio frequencies. The observed spectral slope from the X-ray to UV regions is positive and continuous, but that from the mid UV to visible light region becomes gradually flat and possibly turns down toward lower frequencies; the optical radio emission can not be accounted for by a single power law. Several theoretical models were considered for the emission mechanism. A quantitative comparison was performed with the synchrotron-self-Compton model; the total spectrum is found consistent with this model. The spectrum from visible light to X-ray is consistent with synchrotron radiation or with inverse-Compton scattering by a hot thermal cloud of electrons. The continuity of the spectral slope from X-ray to UV implied by the current data suggests that the previous estimates of the total luminosity of this BL Lac object is underestimated by a factor of about three or four.

The ultraviolet spectrum of the eclipsing binary IM Aurigae

NASA Technical Reports Server (NTRS)

Bruhweiler, F. C.; Feibelman, W. A.; Kondo, Y.

1986-01-01

Low dispersion IUE spectra have been obtained at primary and secondary minima, together with a high dispersion spectrum near maximum, for the eclipsing Algol-type IM Aurigae system. The weak, sharp absorption features noted at two distinct velocities in the high dispersion data are attributed to circumbinary gaseous shells and/or gas streams between the stellar components. The implications of these results for the recently observed increase in O-C values of the primary minimum, which prompted this UV spectral search for evidence of a recent mass-loss event, are discussed.

Rocket and spacecraft studies of ultraviolet emissions from astrophysical targets

NASA Technical Reports Server (NTRS)

Fastie, W. G.; Moos, H. W.; Feldman, P. D.; Henry, R. C.

1975-01-01

Rocket and spacecraft far-UV spectral measurements of several astrophysical targets are reviewed. These include observations of Ly-alpha emissions from Arcturus, Apollo-17 far-UV spectrometry of eta UMa and five other stars, Apollo-17 observations of the lunar atmosphere and the diffuse UV background, and far-UV spectral studies of Venus, Jupiter, and Comet Kohoutek. The Arcturus observations indicated a chromosphere with neutral atomic-hydrogen and atomic-oxygen emissions as well as a very weak atomic-carbon line. The planetary studies revealed O I and C I emissions in the Venusian spectrum as well as large Ly-alpha emissions and possible molecular-hydrogen emissions in that of Jupiter. The lunar observations demonstrated that solar protons do not produce an atomic-hydrogen atmosphere on the moon.

An operational retrieval algorithm for determining aerosol optical properties in the ultraviolet

NASA Astrophysics Data System (ADS)

Taylor, Thomas E.; L'Ecuyer, Tristan S.; Slusser, James R.; Stephens, Graeme L.; Goering, Christian D.

2008-02-01

This paper describes a number of practical considerations concerning the optimization and operational implementation of an algorithm used to characterize the optical properties of aerosols across part of the ultraviolet (UV) spectrum. The algorithm estimates values of aerosol optical depth (AOD) and aerosol single scattering albedo (SSA) at seven wavelengths in the UV, as well as total column ozone (TOC) and wavelength-independent asymmetry factor (g) using direct and diffuse irradiances measured with a UV multifilter rotating shadowband radiometer (UV-MFRSR). A novel method for cloud screening the irradiance data set is introduced, as well as several improvements and optimizations to the retrieval scheme which yield a more realistic physical model for the inversion and increase the efficiency of the algorithm. Introduction of a wavelength-dependent retrieval error budget generated from rigorous forward model analysis as well as broadened covariances on the a priori values of AOD, SSA and g and tightened covariances of TOC allows sufficient retrieval sensitivity and resolution to obtain unique solutions of aerosol optical properties as demonstrated by synthetic retrievals. Analysis of a cloud screened data set (May 2003) from Panther Junction, Texas, demonstrates that the algorithm produces realistic values of the optical properties that compare favorably with pseudo-independent methods for AOD, TOC and calculated Ångstrom exponents. Retrieval errors of all parameters (except TOC) are shown to be negatively correlated to AOD, while the Shannon information content is positively correlated, indicating that retrieval skill improves with increasing atmospheric turbidity. When implemented operationally on more than thirty instruments in the Ultraviolet Monitoring and Research Program's (UVMRP) network, this retrieval algorithm will provide a comprehensive and internally consistent climatology of ground-based aerosol properties in the UV spectral range that can be used for both validation of satellite measurements as well as regional aerosol and ultraviolet transmission studies.

Photosynthetic carbon reduction by seagrasses exposed to ultraviolet A radiation

NASA Technical Reports Server (NTRS)

1979-01-01

The seagrasses Halophila engelmannii, Halodule wrightii, and Syringodium filiforme were examined for their intrinsic sensitivity to ultraviolet-A-UV-A and ultraviolet-B-UV-B radiation. The effect of UV-A on photosynthetically active radiation (PAR) was also determined. Ultraviolet-A and ultraviolet-B were studied with emphasis on the greater respective environmental consequence in terms of seagrass distribution and abundance. Results indicate that an intrinsic sensitivity to UV-A alone is apparent only in Halophila, while net photosynthesis in Halodule and Syringodium seems unaffected by the level of UV-A provided. The sensitivity of Halophila to UV-A in the absense of (PAR) indicates that the photosynthetic reaction does not need to be in operation for damage to occur. Other significant results are reported.

Determination of 2-alkylcyclobutanones in ultraviolet light-irradiated fatty acids, triglycerides, corn oil, and pork samples: Identifying a new source of 2-alkylcyclobutanones.

PubMed

Meng, Xiangpeng; Chan, Wan

2017-02-15

Previous studies have established that 2-alkylcyclobutanones (2-ACBs) are unique radiolytic products in lipid-containing foods that could only be formed through exposure to ionizing radiation, but not by any other means of physical/heat treatment methods. Therefore, 2-ACBs are currently the marker molecules required by the European Committee for Standardization to be used to identify foods irradiated with ionizing irradiation. Using a spectrum of state-of-the-art analytical instruments, we present in this study for the first time that the generation of 2-ACBs was also possible when fatty acids and triglycerides are exposed to a non-ionizing, short-wavelength ultraviolet (UV-C) light source. An irradiation dosage-dependent formation of 2-ACBs was also observed in UV-C irradiated fatty acids, triglycerides, corn oil, and pork samples. With UV-C irradiation becoming an increasingly common food treatment procedure, it is anticipated that the results from this study will alert food scientists and regulatory officials to a potential new source for 2-ACBs. Copyright © 2016 Elsevier Ltd. All rights reserved.

A simple resonance enhanced laser ionization scheme for CO via the A1Π state

NASA Astrophysics Data System (ADS)

Sun, Z. F.; von Zastrow, A. D.; Parker, D. H.

2017-07-01

We investigate the laser ionization process taking place when the CO molecule is exposed to vacuum ultraviolet (VUV) radiation resonant with the CO A1Π (v = 0) ← X1Σ+ (v = 0) transition around 154 nm, along with the ultraviolet (UV) and visible (Red) radiation used to generate VUV by four-wave difference-frequency mixing. By measuring the CO+ ion recoil and a room temperature gas spectrum, it is possible to assign the ionization process as 1 + 1' + 1'' REMPI where the one-photon steps refer to the VUV, UV, and Red radiation, respectively. Resonance enhanced ionization of rotational states around J = 12 arise due to the overlap of the fixed wavelength UV (˜250 nm) with the R band-head of a transition assigned to CO E1Π (v = 6) ← A1Π (v = 0) with a term value of 104 787.5 cm-1. The REMPI process is efficient and polarization sensitive and should be useful in a wide range of studies involving nascent CO.

Surfactant-assisted growth and optical properties of ZnO hexagonal bilayer disk-like microstructures

NASA Astrophysics Data System (ADS)

Zhu, Q. P.; Shen, X. Y.; Wang, L. L.; Zhu, L. P.; Wang, L. J.; Liao, G. H.

2018-01-01

ZnO hexagonal bilayer disk-like microstructures are successfully fabricated using a simple solvothermal method assisted with surfactant. The structure and morphology were investigated by XRD, SEM, and EDS. XRD result indicated that the as-obtained samples were well-crystallized wurtzite hexagonal ZnO structure. SEM images showed that the ZnO hexagonal bilayer disk-like assembles consist of two uniform and smooth disks with an average edge length of 6 μm and thickness of ˜4 μm. UV-vis spectrum reveals that ZnO sampls show an appreciable red shift and the band gap energy of the obtained ZnO samples were about 3.15 eV. A very strong UV emission at the ultraviolet (UV) region was observed in the photoluminescence (PL) spectrum of the as-prepared ZnO samples tested at room-temperature. A possible growth process of the ZnO hexagonal bilayer disk-like microstructures was schematically illustrated.

Quantum chemical investigations on the molecular structure, FTIR, UV-Vis and HOMO-LUMO analysis of 15-16-epoxy-7b, 9a dihydroxylabdane 13(16), 14-dien-6-one

NASA Astrophysics Data System (ADS)

Uppal, Anshul; Pathania, Kamni; Khajuria, Yugal

2018-05-01

The structural, spectroscopic (Fourier Transform Infrared (FT-IR), Ultra-Violet Visible (UV-VIS)) and thermodynamic properties of 15, 16-epoxy-7b, 9a dihydroxylabdane-13(16), 14-dien-6-one were studied by using both experimental techniques and theoretical methods. The FTIR spectrum of the title compound was recorded in the spectral range 4000-400 cm-1. The UV-VIS spectrum was measured in the spectral range 190-800 nm. The quantum chemistry calculations have been performed to compute optimized geometry, molecular parameters, vibrational frequencies along with intensities using Hartree Fock (HF) theory and Density Functional Theory (DFT) with 6-31G basis set. The calculated HOMO-LUMO energies show that the charge transfer occurs within the molecule. The temperature dependence of the thermodynamic properties like heat capacity, entropy and enthalpy of the optimized structure were obtained. Finally, a comparison between the experimental data and the calculated results presented a good agreement.

Leaf expansion and development of photosynthetic capacity and pigments in Liquidambar Styraciflua (Hamamelidaceae)-effects of UV-B radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dillenburg, L.R.; Sullivan, J.H.; Teramura, A.H.

1995-07-01

In order to perform their functions as photosynthetic organs, leaves must cope with excess heat and potentially damaging ultraviolet radiation. Possible increases in the UV-B portion of the solar spectrum may place an additional burden on leaves, and this could be particularly important for young expanding leaves with poorly developed UV-B defense mechanisms. We evaluated the effects of supplemental UV-B radiation on leaf expansion and the development of photosynthetic capacity and pigments in sweetgum (Liquidambar styraciflua L.) seedlings. Seedlings were grown in the field under either ambient or ambient plus 3 or 5.0 kJ of biologically effective supplemental UV-B radiation.more » Although final leaf size was unaffected, the rate of leaf elongation and accumulation of leaf area was slower in leaves exposed to the lower supplemental UV-B irradiance. In contrast, chlorophyll accumulation and the development of photosynthetic capacity was more rapid in plants exposed to the higher, compared to the lower supplemental UV-B irradiance. The accumulation of anthocyanins and other putative flavonoids or UV-absorbing compounds was scarcely affected by exposure to supplemental UV-B radiation. These results suggest that the UV-B portion of the solar spectrum may, in the absence of gross affects on biomass, exert subtle influences on leaf ontogeny and the development of photosynthetic pigments and capacity in sweetgum. 44 refs., 6 figs.« less

Time-Resolved Ultraviolet Spectroscopy of the M-Dwarf GJ 876 Exoplanetary System

NASA Technical Reports Server (NTRS)

France, Kevin; Linsky, Jeffrey L.; Tian, Feng; Froning, Cynthia S.; Roberge, Aki

2012-01-01

Extrasolar planets orbiting M-stars may represent our best chance to discover habitable worlds in the coming decade. The ultraviolet spectrum incident upon both Earth-like and Jovian planets is critically important for proper modeling of their atmospheric heating and chemistry. In order to provide more realistic inputs for atmospheric models of planets orbiting low-mass stars, we present new near- and far-ultraviolet (NUV and FUV) spectroscopy of the M-dwarf exoplanet host GJ 876 (U4V). Using the COS and STIS spectrographs aboard the Hubble Space Telescope, we have measured the 1150 - 3140 Ang. spectrum of GJ 876. We have reconstructed the stellar H I Ly-alpha emission line profile, and find that the integrated Ly-apha flux is roughly equal to the rest of the integrated flux (1150 - 1210 Ang + 1220 - 3140 Ang) in the entire ultraviolet bandpass (F(Ly-alpha)/F(FUV+NUV) approximately equals 0.7). This ratio is approximately 2500 x greater than the solar value. We describe the ultraviolet line spectrum and report surprisingly strong fluorescent emission from hot H2 (T(H2) > 2000 K). We show the light-curve of a chromospheric + transition region flare observed in several far-UV emission lines, with flare/ quiescent flux ratios :2: 10. The strong FUV radiation field of an M-star (and specifically Ly-alpha) is important for determining the abundance of O2 - and the formation of biomarkers - in the lower atmospheres of Earth-like planets in the habitable zones of low-mass stars.

Photoprotection and photoreception of intraocular lenses under xenon and white LED illumination.

PubMed

Artigas, J M; Navea, A; García-Domene, M C; Artigas, C; Lanzagorta, A

2016-05-01

To analyze the photoprotection and phototransmission that various intraocular lenses (IOLs) provide under the illumination of a xenon (Xe) lamp and white LEDs (light emitting diode). The spectral transmission curves of six representative IOLs were measured using a Perkin-Elmer Lambda 35 UV/VIS spectrometer. Various filtering simulations were performed using a Xe lamp and white LEDs. The spectral emissions of these lamps were measured with an ILT-950 spectroradiometer. The IOLs analyzed primarily show transmission of nearly 100% in the visible spectrum. In the ultraviolet (UV) region, the filters incorporated in the various IOLs did not filter equally, and some of them let an appreciable amount of UV through. The Xe lamp presented a strong emission of ultraviolet A (UVA), and its emission under 300nm was not negligible. The white LED did not present an appreciable emission under 380nm. The cut-off wavelength of most filters is between 380 and 400nm (Physiol Hydriol60C(®), IOLTECH E4T(®), Alcon SA60AT(®), Alcon IQ SN60WF(®)), so that their UV protection is very effective. Nonetheless, the IOL OPHTEC Oculaid(®) contains a filter that, when a Xe lamp is used, lets through up to 20% for 350nm and up to 15% for 300nm, which at this point is ultraviolet B (UVB). The OPHTEC(®) Artisan IOL has a transmission peak below 300nm, which must be taken into account under Xe illumination. White LEDs do not emit energy below 380nm, so no special protection is required in the UV region. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

Indium nanoparticles for ultraviolet surface-enhanced Raman spectroscopy

NASA Astrophysics Data System (ADS)

Das, Rupali; Soni, R. K.

2018-05-01

Ultraviolet Surface-enhanced Raman spectroscopy (UVSERS) has emerged as an efficient molecular spectroscopy technique for ultra-sensitive and ultra-low detection of analyte concentration. The generic SERS substrates based on gold and silver nanostructures have been extensively explored for high local electric field enhancement only in visible-NIR region of the electromagnetic spectrum. The template synthesis of controlled nanoscale size metallic nanostructures supporting localized surface plasmon resonance (LSPR) in the UV region have been recently explored due to their ease of synthesis and potential applications in optoelectronic, catalysis and magnetism. Indium (In0) nanoparticles exhibit active surface plasmon resonance (SPR) in ultraviolet (UV) and deep-ultaviolet (DUV) region with optimal absorption losses. This extended accessibility makes indium a promising material for UV plasmonic, chemical sensing and more recently in UV-SERS. In this work, spherical indium nanoparticles (In NPs) were synthesized by modified polyol reduction method using NaBH4 having local surface plasmon resonance near 280 nm. The as-synthesized spherical In0 nanoparticles were then coated with thin silica shells of thickness ˜ 5nm by a modified Stober method protecting the nanoparticles from agglomeration, direct contact with the probed molecules as well as prevent oxidation of the nanoparticles. Morphological evolution of In0 nanoparticles and SiO2 coating were characterized by transmission electron microscope (TEM). An enhanced near resonant shell-isolated SERS activity from thin film of tryptophan (Tryp) molecules deposited on indium coated substrates under 325nm UV excitation was observed. Finite difference time domain (FDTD) method is employed to comprehend the experimental results and simulate the electric field contours which showed amplified electromagnetic field localized around the nanostructures. The comprehensive analysis indicates that indium is a promising alternate exogenous contrast agent for efficient Raman spectroscopy from molecules.

UV irradiance and albedo at Union Glacier Camp (Antarctica): a case study.

PubMed

Cordero, Raul R; Damiani, Alessandro; Ferrer, Jorge; Jorquera, Jose; Tobar, Mario; Labbe, Fernando; Carrasco, Jorge; Laroze, David

2014-01-01

We report on the first spectral measurements of ultraviolet (UV) irradiance and the albedo at a Camp located in the southern Ellsworth Mountains on the broad expanse of Union Glacier (700 m altitude, 79° 46' S; 82° 52'W); about 1,000 km from the South Pole. The measurements were carried out by using a double monochromator-based spectroradiometer during a campaign (in December 2012) meant to weight up the effect of the local albedo on the UV irradiance. We found that the albedo measured at noon was about 0.95 in the UV and the visible part of the spectrum. This high surface reflectivity led to enhancements in the UV index under cloudless conditions of about 50% in comparison with snow free surfaces. Spectral measurements carried out elsewhere as well as estimates retrieved from the Ozone Monitoring Instrument (OMI) were used for further comparisons.

UV Irradiance and Albedo at Union Glacier Camp (Antarctica): A Case Study

PubMed Central

Cordero, Raul R.; Damiani, Alessandro; Ferrer, Jorge; Jorquera, Jose; Tobar, Mario; Labbe, Fernando; Carrasco, Jorge; Laroze, David

2014-01-01

We report on the first spectral measurements of ultraviolet (UV) irradiance and the albedo at a Camp located in the southern Ellsworth Mountains on the broad expanse of Union Glacier (700 m altitude, 79° 46′ S; 82° 52′W); about 1,000 km from the South Pole. The measurements were carried out by using a double monochromator-based spectroradiometer during a campaign (in December 2012) meant to weight up the effect of the local albedo on the UV irradiance. We found that the albedo measured at noon was about 0.95 in the UV and the visible part of the spectrum. This high surface reflectivity led to enhancements in the UV index under cloudless conditions of about 50% in comparison with snow free surfaces. Spectral measurements carried out elsewhere as well as estimates retrieved from the Ozone Monitoring Instrument (OMI) were used for further comparisons. PMID:24598906

Photoreceptor-mediated bending towards UV-B in Arabidopsis.

PubMed

Vandenbussche, Filip; Tilbrook, Kimberley; Fierro, Ana Carolina; Marchal, Kathleen; Poelman, Dirk; Van Der Straeten, Dominique; Ulm, Roman

2014-06-01

Plants reorient their growth towards light to optimize photosynthetic light capture--a process known as phototropism. Phototropins are the photoreceptors essential for phototropic growth towards blue and ultraviolet-A (UV-A) light. Here we detail a phototropic response towards UV-B in etiolated Arabidopsis seedlings. We report that early differential growth is mediated by phototropins but clear phototropic bending to UV-B is maintained in phot1 phot2 double mutants. We further show that this phototropin-independent phototropic response to UV-B requires the UV-B photoreceptor UVR8. Broad UV-B-mediated repression of auxin-responsive genes suggests that UVR8 regulates directional bending by affecting auxin signaling. Kinetic analysis shows that UVR8-dependent directional bending occurs later than the phototropin response. We conclude that plants may use the full short-wavelength spectrum of sunlight to efficiently reorient photosynthetic tissue with incoming light. © The Author 2014. Published by the Molecular Plant Shanghai Editorial Office in association with Oxford University Press on behalf of CSPB and IPPE, SIBS, CAS.

Ultraviolet spectrophotometer for measuring columnar atmospheric ozone from aircraft

NASA Technical Reports Server (NTRS)

Hanser, F. A.; Sellers, B.; Briehl, D. C.

1978-01-01

An ultraviolet spectrophotometer (UVS) to measure downward solar fluxes from an aircraft or other high altitude platform is described. The UVS uses an ultraviolet diffuser to obtain large angular response with no aiming requirement, a twelve-position filter wheel with narrow (2-nm) and broad (20-nm) bandpass filters, and an ultraviolet photodiode. The columnar atmospheric ozone above the UVS (aircraft) is calculated from the ratios of the measured ultraviolet fluxes. Comparison with some Dobson station measurements gives agreement to 2%. Some UVS measured ozone profiles over the Pacific Ocean for November 1976 are shown to illustrate the instrument's performance.

Study on excitation and fluorescence spectrums of Japanese citruses to construct machine vision systems for acquiring fluorescent images

NASA Astrophysics Data System (ADS)

Momin, Md. Abdul; Kondo, Naoshi; Kuramoto, Makoto; Ogawa, Yuichi; Shigi, Tomoo

2011-06-01

Research was conducted to acquire knowledge of the ultraviolet and visible spectrums from 300 -800 nm of some common varieties of Japanese citrus, to investigate the best wave-lengths for fluorescence excitation and the resulting fluorescence wave-lengths and to provide a scientific background for the best quality fluorescent imaging technique for detecting surface defects of citrus. A Hitachi U-4000 PC-based microprocessor controlled spectrophotometer was used to measure the absorption spectrum and a Hitachi F-4500 spectrophotometer was used for the fluorescence and excitation spectrums. We analyzed the spectrums and the selected varieties of citrus were categorized into four groups of known fluorescence level, namely strong, medium, weak and no fluorescence.The level of fluorescence of each variety was also examined by using machine vision system. We found that around 340-380 nm LEDs or UV lamps are appropriate as lighting devices for acquiring the best quality fluorescent image of the citrus varieties to examine their fluorescence intensity. Therefore an image acquisition device was constructed with three different lighting panels with UV LED at peak 365 nm, Blacklight blue lamps (BLB) peak at 350 nm and UV-B lamps at peak 306 nm. The results from fluorescent images also revealed that the findings of the measured spectrums worked properly and can be used for practical applications such as for detecting rotten, injured or damaged parts of a wide variety of citrus.

Multiple UV reflectance peaks in the iridescent neck feathers of pigeons

NASA Astrophysics Data System (ADS)

McGraw, Kevin J.

Recent studies of colorful plumage signals in birds have been aided by the finding that birds can see ultraviolet (UV) light and thus may communicate using colors invisible to humans. Some of the pioneering and more pivotal work on avian color vision was performed with domestic pigeons (Columba livia), yet surprisingly there have been few detailed reports of the UV-reflecting properties of pigeon feathers. Here, I use UV-VIS fiber-optic spectrometry to document the full-spectrum reflectance characteristics of iridescent purple and green neck plumage in pigeons. Neck feathers that appear purple to the human eye exhibit four reflectance peaks-two in the UV and one in the blue and red regions-and thus exhibit a UV-purple hue. Neck feathers that appear green to the human eye are characterized by five spectral peaks: two in the UV (UVA and UVB), a predominant green peak, and secondary violet and red peaks, conferring a UV-purple-green color. Such elaborate UV coloration suggests that birds may use an even more complex and `hidden' UV signaling system than previously thought.

Antiradiation UV Vaccine: UV Radiation, Biological effects, lesions and medical management - immune-therapy and immune-protection.

NASA Astrophysics Data System (ADS)

Popov, Dmitri; Jones, Jeffrey; Maliev, Slava

Key Words: Ultraviolet radiation,Standard Erythema Dose(SED), Minimal Erythema Dose(MED), Sun Burns, Solar Dermatitis, Sun Burned Disease, DNA Damage,Cell Damage, Antiradiation UV Vaccine, Immune-Prophylaxis of Sun Burned Diseases, Immune-Prophylaxis of Sun Burns, Immune-Therapy of Sun-Burned Disease and Sun Burns,Basal Cell Carcinoma (BCC), Squamous Cell Carcinoma (SCC), Toxic Epidermal Necrolysis(TEN). Introduction: High doses of UV generated by solar source and artificial sources create an exposure of mammals and other species which can lead to ultraviolet(UV)radiation- associated disease (including erythema, epilation, keratitis, etc.). UV radiation belongs to the non-ionizing part of the electromagnetic spectrum and ranges between 100 nm and 400 nm with 100 nm having been chosen arbitrarily as the boundary between non-ionizing and ionizing radiation, however EMR is a spectrum and UV can produce molecular ionization. UV radiation is conventionally categorized into 3 areas: UV-A (>315-400 nm),UV-B (>280-315 nm)and UV-C (>100-280 nm) [IARC,Working Group Reports,2005] An important consequence of stratospheric ozone depletion is the increased transmission of solar ultraviolet (UV)radiation to the Earth's lower atmosphere and surface. Stratospheric ozone levels have been falling, in certain areas, for the past several decades, so current surface ultraviolet-B (UV-B) radiation levels are thought to be close to their modern day maximum. [S.Madronich et al.1998] Overexposure of ultraviolet radiation a major cause of skin cancer including basal cell carcinoma (BCC), squamous cell carcinoma (SCC) { collectively referred to as “non-melanoma" skin cancer (NMSC) and melanoma as well, with skin cancers being the most common cancer in North America. [Armstrong et al. 1993, Gallagher et al. 2005] Methods and Experimental Design: Our experiments and testing of a novel UV “Antiradiation Vaccine” have employed a wide variety of laboratory animals which include : Chinchilla rabbits, 11-12 months old, live weight 3.5-3.7 (n=11), Balb mice, 2-3 months old, live weight 20-22 g (n=33), Wistar rats, 3-4 months old, live weight 180-220 g(n=33). The studies were approved by the Animal Care and Use Committee for ethical animal research equivalent, at each institution. Seven rabbits, ten mice, eleven Wistar rats were vaccinated with a UV antiradiation vaccine. A second group of animals was used as biological control which received vaccine but no UV Radiation and a third group of animals was used as control without any interventions. Before and after UV Radiation, Vaccination with the UV antiradiation vaccine were provided 17 days prior to UV exposure. The animals were irradiated by a DRT-1 UV generator lamp. The dose of irradiation for laboratory, experimental animals was 10-12 * Standard Erythema Dose (SED) at L=283,7 Laboratory animals were placed in to the box with ventilation. Results: Ultraviolet irradiation of the skin was performed with high doses and causes an inflammation or erythema in all experimental animals. However the grade of skin damage and inflammation was significantly different between animals protected by vaccination and non-protected, non-vaccinated animals. Animals UV-irradiated, but who did not receive the antiradiation vaccine suffered from extensive UV skin burns of second or third degree (grade 2-3). However, animals protected with the UV antiradiation vaccine demonstrated much mild forms of skin cellular injury - mainly erythema, first degree skin burns and a few small patches with second degree skin burns (grade 1-2). Discussion: The severity of skin damage depended on area of exposed skin, time and dose of UV irradiation. Skin injury could be divided into 4 major grades: 1. Faint erythema with dry desquamation. 2. Moderate to severe erythema. 3. Severe erythema with blistering, moist desquamation. 4. Toxic epidermal necrolysis. Mild doses of UV radiation and ionizing radiation can induce cell death by apoptosis and moderate and high doses of UV and ionizing radiation induce cell death by necrosis and generate systemic inflammatory response syndrome (SIRS), toxic multiple organ injury (TMOI), toxic multiple organ dysfunction syndromes (TMODS),and finally, toxic multiple organ failure (TMOF). [D.Popov et al.2012, Fliedner T.et al. 2005, T. Azizova et al. 2004] UV-B is a complete carcinogen that is absorbed by DNA and directly damages DNA. DNA damage induced by UV-B irradiation typically includes the formation of cyclobutane pyrimidine dimmers (CPD) and 6-4 photoproducts (6-4P)[IARC, Working Group Reports, M.Saraiya et al. 2004]. The pre-vaccinated animals seem to have a blunted injury response relative to the unvaccinated animals, presumably by reduction in the inflammatory response and secondary injury effects. The mechanism of action of the antiradiation vaccine, needs further evaluation. Conclusion: A UV antiradiation vaccine appears to demonstrate efficacy as a prophylactic agent for acute solar burns and toxicity. An antiradiation UV vaccine could be used in conjunction with adjunctive measures, e.g. antioxidants and UV barriers to reduce UV radiation toxicity. The authors of this experiments would like to propose further development work of the antiradiation UV vaccine to enhance the armamentarium for prophylaxis and prevention of the various forms skin cancer.

IUE observations of Comet Halley: Evolution of the UV spectrum between September 1985 and July 1986

NASA Technical Reports Server (NTRS)

Feldman, P. D.; Festou, Michael C.; Ahearn, M. F.; Arpigny, C.; Butterworth, P. S.; Cosmovici, C. B.; Danks, A. C.; Gilmozzi, R.; Jackson, W. M.; Mcfadden, L. A.

1986-01-01

The ultraviolet spectrum of comet P/Halley was monitored with the IUE between 12 September 1985 and 8 July 1986 (r <2.6 AU pre and post-perihelion) at regular time intervals except for a two-month period around the time of perihelion. A complete characterization of the UV spectrum of the comet was obtained to derive coma abundances and to study the light emission mechanisms of the observed species. The Fine Error Sensor (FES) camera of the IUE was used to photometrically investigate the coma brightness variation on time scales of the order of hours. Spectroscopic observations as well as FES measurements show that the activity of the nucleus is highly variable, particularly at the end of December 1985 and during March and April 1986. The production rates of OH, CS and dust are derived for the entire period of the observations. The total water loss rate for this period is estimated to be 150 million metric tons.

Broad-spectrum sunscreens offer protection against urocanic acid photoisomerization by artificial ultraviolet radiation in human skin.

PubMed

van der Molen, R G; Out-Luiting, C; Driller, H; Claas, F H; Koerten, H K; Mommaas, A M

2000-09-01

Cis-urocanic acid (UCA) has been indicated as an important mediator of ultraviolet (UV)-induced immunosuppression. In this study we describe a rapid, noninvasive method for the determination of the protective capacity of various sunscreens against the UV-induced isomerization of trans-UCA into its cis form. For this purpose we applied sunscreens prior to in vivo exposure of human volunteers with single or repeated broadband UVB irradiations of 100 mJ per cm2. We found significant but different levels of protection against UCA photoisomerization by all sunscreens that correlated with the sun protection factor. A comparison of various sunscreens with a sun protection factor of 10, showed that the best protection was offered by the sunscreens (containing organic UV filters or TiO2) with broad absorption spectra. The ability to inhibit cis-UCA formation was not influenced by the penetration characteristics of sunscreens, as determined by application of the sunscreen on quartz glass that was placed on the skin, preventing penetration of sunscreen in the skin. In addition ex vivo UV exposure of human skin was employed to permit other tests of immunomodulation, in this case the mixed epidermal cell lymphocyte reaction. The advantage of this ex vivo method is that there is no need to take biopsies from volunteers. Ex vivo irradiation of human skin with a single dose of 200 mJ per cm2 resulted in similar protection by the sunscreens against cis-UCA formation as in the in vivo system. Furthermore, the mixed epidermal cell lymphocyte reaction data correlated with the cis-UCA findings. We conclude that UCA isomerization is an excellent method to determine sunscreen efficacy and that broad-spectrum sunscreens offer good immunoprotection.

Assessing the effects of ultraviolet radiation on the photosynthetic potential in Archean marine environments

NASA Astrophysics Data System (ADS)

Avila-Alonso, Dailé; Baetens, Jan M.; Cardenas, Rolando; de Baets, Bernard

2017-07-01

In this work, the photosynthesis model presented by Avila et al. in 2013 is extended and more scenarios inhabited by ancient cyanobacteria are investigated to quantify the effects of ultraviolet (UV) radiation on their photosynthetic potential in marine environments of the Archean eon. We consider ferrous ions as blockers of UV during the Early Archean, while the absorption spectrum of chlorophyll a is used to quantify the fraction of photosynthetically active radiation absorbed by photosynthetic organisms. UV could have induced photoinhibition at the water surface, thereby strongly affecting the species with low light use efficiency. A higher photosynthetic potential in early marine environments was shown than in the Late Archean as a consequence of the attenuation of UVC and UVB by iron ions, which probably played an important role in the protection of ancient free-floating bacteria from high-intensity UV radiation. Photosynthetic organisms in Archean coastal and ocean environments were probably abundant in the first 5 and 25 m of the water column, respectively. However, species with a relatively high efficiency in the use of light could have inhabited ocean waters up to a depth of 200 m and show a Deep Chlorophyll Maximum near 60 m depth. We show that the electromagnetic radiation from the Sun, both UV and visible light, could have determined the vertical distribution of Archean marine photosynthetic organisms.

Development of ultraviolet- and visible-light one-shot spectral domain optical coherence tomography and in situ measurements of human skin

NASA Astrophysics Data System (ADS)

Hirayama, Heijiro; Nakamura, Sohichiro

2015-07-01

We have developed ultraviolet (UV)- and visible-light one-shot spectral domain (SD) optical coherence tomography (OCT) that enables in situ imaging of human skin with an arbitrary wavelength in the UV-visible-light region (370-800 nm). We alleviated the computational burden for each color OCT image by physically dispersing the irradiating light with a color filter. The system consists of SD-OCT with multicylindrical lenses; thus, mechanical scanning of the mirror or stage is unnecessary to obtain an OCT image. Therefore, only a few dozens of milliseconds are necessary to obtain single-image data. We acquired OCT images of one subject's skin in vivo and of a skin excision ex vivo for red (R, 650±20 nm), green (G, 550±20 nm), blue (B, 450±20 nm), and UV (397±5 nm) light. In the visible-light spectrum, R light penetrated the skin and was reflected at a lower depth than G or B light. On the skin excision, we demonstrated that UV light reached the dermal layer. We anticipated that basic knowledge about the spectral properties of human skin in the depth direction could be acquired with this system.

Development of ultraviolet- and visible-light one-shot spectral domain optical coherence tomography and in situ measurements of human skin.

PubMed

Hirayama, Heijiro; Nakamura, Sohichiro

2015-07-01

We have developed ultraviolet (UV)- and visible-light one-shot spectral domain (SD) optical coherence tomography (OCT) that enables in situ imaging of human skin with an arbitrary wavelength in the UV-visible-light region (370-800 nm). We alleviated the computational burden for each color OCT image by physically dispersing the irradiating light with a color filter. The system consists of SD-OCT with multicylindrical lenses; thus, mechanical scanning of the mirror or stage is unnecessary to obtain an OCT image. Therefore, only a few dozens of milliseconds are necessary to obtain single-image data. We acquired OCT images of one subject's skin in vivo and of a skin excision ex vivo for red (R, 650 ± 20 nm), green (G, 550 ± 20 nm), blue (B, 450 ± 20 nm), and UV (397 ± 5 nm) light. In the visible-light spectrum, R light penetrated the skin and was reflected at a lower depth than G or B light. On the skin excision, we demonstrated that UV light reached the dermal layer. We anticipated that basic knowledge about the spectral properties of human skin in the depth direction could be acquired with this system.

Microbial diversity of Indian Ocean hydrothermal vent plumes: microbes tolerant of desiccation, peroxide exposure, and ultraviolet and gamma-irradiation.

PubMed

La Duc, Myron T; Benardini, James N; Kempf, Michael J; Newcombe, David A; Lubarsky, Michael; Venkateswaran, Kasthuri

2007-04-01

The microbial diversity of Kali chimney plumes, part of a hydrothermal vent field in the Rodriguez Triple Junction, Indian Ocean (depth approximately 2,240 m), was examined in an attempt to discover "extremotolerant" microorganisms that have evolved unique resistance capabilities to this harsh environment. Water and sediment samples were collected from the vent and from sediments located at various distances (2-20 m) away from and surrounding the chimney. Samples were screened for hypertolerant microbes that are able to withstand multiple stresses. A total of 46 isolates were selected for exposure to a number of perturbations, such as heat shock, desiccation, H(2)O(2), and ultraviolet (UV) and gamma-irradiation. The survival of Psychrobacter sp. L0S3S-03b following exposure to >1,000 J/m(2) UV(254) radiation was particularly intriguing amid a background of varying levels of resistance. Vegetative cells of this non-spore-forming microbe not only survived all of the treatments, but also exhibited a 90% lethal dose of 30 s when exposed to simulated martian UV radiation and a 100% lethal dose of 2 min when exposed to full spectrum UV, which is comparable to findings for bacterial endospores.

UIT Observations of Early-Type Galaxies and Analysis of the FUSE Spectrum of a Subdwarf B Star

NASA Technical Reports Server (NTRS)

Ohl, Raymond G.; Krebs, Carolyn (Technical Monitor)

2001-01-01

This work covers Ultraviolet Imaging Telescope (UIT) observations of early-type galaxies (155 nm) and Far Ultraviolet Spectroscopic Explorer (FUSE) spectra of a Galactic subdwarf B star (sdB). Early UV space astronomy missions revealed that early-type galaxies harbor a population of stars with effective temperatures greater than that of the main sequence turn-off (about 6,000 K) and UV emission that is very sensitive to characteristics of the stellar population. We present UV (155 nm) surface photometry and UV-B color profiles for 8 E and SO galaxies observed by UIT. Some objects have de Vaucouleurs surface brightness profiles, while others have disk-like profiles, but we find no other evidence for the presence of a disk or young, massive stars. There is a wide range of UV-B color gradients, but there is no correlation with metallicity gradients. SdB stars are the leading candidate UV emitters in old, high metallicity stellar populations (e.g., early-type galaxies). We observed the Galactic sdB star PG0749+658 with FUSE and derived abundances with the aim of constraining models of the heavy element distribution in sdB atmospheres. All of the elements measured are depleted with respect to solar, except for Cr and Mn, which are about solar, and Ni, which is enhanced. This work was supported in part by NASA grants NAG5-700 and NAG5-6403 to the University of Virginia and NAS5-32985 to Johns Hopkins University.

Ultraviolet emission enhancement in ZnO thin films modified by nanocrystalline TiO2

NASA Astrophysics Data System (ADS)

Zheng, Gaige; Lu, Xi; Qian, Liming; Xian, Fenglin

2017-05-01

In this study, nanocrystalline TiO2 modified ZnO thin films were prepared by electron beam evaporation. The structural, morphological and optical properties of the samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), UV-visible spectroscopy, fluorescence spectroscopy, respectively. The composition of the films was examined by energy dispersive X-ray spectroscopy (EDX). The photoluminescent spectrum shows that the pure ZnO thin film exhibits an ultraviolet (UV) emission peak and a strong green emission band. Surface analysis indicates that the ZnO thin film contains many oxygen vacancy defects on the surface. After the ZnO thin film is modified by the nanocrystalline TiO2 layer, the UV emission of ZnO is largely enhanced and the green emission is greatly suppressed, which suggests that the surface defects such as oxygen vacancies are passivated by the TiO2 capping layer. As for the UV emission enhancement of the ZnO thin film, the optimized thickness of the TiO2 capping layer is ∼16 nm. When the thickness is larger than 16 nm, the UV emission of the ZnO thin film will decrease because the TiO2 capping layer absorbs most of the excitation energy. The UV emission enhancement in the nanocrystalline TiO2 modified ZnO thin film can be attributed to surface passivation and flat band effect.

An ultraviolet simulator for the incident Martian surface radiation and its applications

NASA Astrophysics Data System (ADS)

Kolb, C.; Abart, R.; Bérces, A.; Garry, J. R. C.; Hansen, A. A.; Hohenau, W.; Kargl, G.; Lammer, H.; Patel, M. R.; Rettberg, P.; Stan-Lotter, H.

2005-10-01

Ultraviolet (UV) radiation can act on putative organic/biological matter at the Martian surface in several ways. Only absorbed, but not transmitted or reflected, radiation energy can be photo-chemically effective. The most important biological UV effects are due to photochemical reactions in nucleic acids, DNA or RNA, which constitute the genetic material of all cellular organisms and viruses. Protein or lipid effects generally play a minor role, but they are also relevant in some cases. UV radiation can induce wavelengths-specific types of DNA damage. At the same time it can also induce the photo-reversion reaction of a UV induced DNA photoproduct of nucleic acid bases, the pyrimidine dimers. Intense UVB and UVC radiation, experienced on early Earth and present-day Mars, has been revealed to be harmful to all organisms, including extremophile bacteria and spores. Moreover, the formation of oxidants, catalytically produced in the Martian environment through UV irradiation, may be responsible for the destruction of organic matter on Mars. Following this, more laboratory simulations are vital in order to investigate and understand UV effects on organic matter in the case of Mars. We have designed a radiation apparatus that simulates the anticipated Martian UV surface spectrum between 200 and 400 nm (UVC UVA). The system comprises a UV enhanced xenon arc lamp, special filter-sets and mirrors to simulate the effects of the Martian atmospheric column and dust loading. We describe the technical setup and performance of the system and discuss its uses for different applications. The design is focused on portability, therefore, the Mars-UV simulator represents a device for several different Mars simulation facilities with specific emphasis on Mars research topics.

Variability of pre-vitamin D3 effectiveness of UV appliances for skin tanning.

PubMed

Sayre, Robert M; Dowdy, John C; Shepherd, James G

2010-07-01

While there is limited documentation that certain indoor tanning lamps effectively produce vitamin D, the diversity of such devices has not been extensively surveyed. This study compares the spectral effectiveness of a variety of tanning units, and solar spectra, for ultraviolet (UV) photosynthesis of pre-vitamin D3 (preD3) and UV induced erythema. Well-established techniques exist for the calculation of spectral effectiveness for photobiological responses that have defined action spectra. Using spectroradiometric data from sunlamp measurements, and standard solar reference spectra, we computed effective irradiances using the CIE action spectrum for the production of preD3 in human skin and the ISO/CIE human erythema reference action spectrum. We found, as with sunlight at different times or latitude, the preD3 and erythemal effectiveness of sunlamps varied as a function of the UV-B proportion of the spectrum. Ratios of sunlamp preD3 to erythemal effectiveness ranged from approximately 0.5 to nearly 2.0, similar to ratios for sunlight. Optimal risk to benefit conditions for preD3 from solar UV exposure occurs under high solar altitude, low zenith angle, midday midsummer sunlight. Analogous optimal preD3 exposure conditions are provided by low to intermediate pressure sunlamps with greater UV-B spectral overlap with the preD3 action spectrum. Similar to low altitude or high latitude sunlight, high pressure tanning units, filtered for negligible UV-B emissions, have insignificant vitamin D benefit. We conclude that while vitamin D can be made by both UVB exposure from indoor tanning units and by exposure UVB from sunlight, the effect is also comparably variable. Unlike sunlight, indoor tanning offers privacy and environmental conditions for practical full body exposure, lowering the requisite exposure per skin surface area, and device timers limit the potential of overexposure. Guidance for optimal use of tanning sources for vitamin D benefit is needed. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

J-SSOD 4 Mission

NASA Image and Video Library

2015-09-17

ISS045E014236 (09/17/2015) – A Japanese Small Satellite is deployed from outside the Japanese Experiment Module on Sept. 17, 2015. Two satellites were sent into Earth orbit by the Small Satellite Orbital Deployer. The first satellite is designed to observe the Ultraviolet (UV) spectrum during the Orionid meteor shower in October. The second satellite, sponsored by the University of Brasilia and the Brazilian government, focuses on meteorological data collection.

UV Spectroscopy of Lucy Mission Targets

NASA Astrophysics Data System (ADS)

Thomas, Cristina

2017-08-01

The Trojan asteroids are a significant population of primitive bodies trapped in Jupiter's stable L4 and L5 Lagrange regions. Their physical properties and existence in these particular orbits constrain the chemical and dynamical processes in our early Solar System. NASA's recently selected Lucy mission will perform the first reconnaissance of these asteroids and will answer many fundamental questions about the population. The compositions of the Trojans are not well understood. Spectroscopy and spectrophotometry in visible and near-infrared wavelengths show red slopes (spectra with reflectivity increasing towards the long wavelength end of the spectrum) and no diagnostic spectral absorption features. However, past spectral and photometric observations suggest there are unobserved features in ultraviolet wavelengths. We propose to obtain ultraviolet spectroscopy with WFC3 of four Trojan asteroids that are targets of the Lucy mission. Lucy will not have the capability to obtain ultraviolet spectra. The proposed observations can only be made using Hubble. We will determine if there are UV spectral features, as suggested by visible wavelength observations, and connect these features to candidate compositional components. These observations will enable connections between the compositions of Trojans and dynamical models of the early Solar System.

ULTRAVIOLET PROTECTIVE PIGMENTS AND DNA DIMER INDUCTION AS RESPONSES TO ULTRAVIOLET RADIATION

EPA Science Inventory

Life on Earth has evolved adaptations to many environmental stresses over the epochs. One consistent stress has been exposure to ultraviolet (UV) radiation. The most basic effect of UV radiation on biological systems is damage to DNA. In response to UV radiation organisms have ad...

Strain induced optical properties of BaReO3

NASA Astrophysics Data System (ADS)

Kumavat, Sandip R.; Kansara, Shivam; Gupta, Sanjeev K.; Sonvane, Yogesh

2018-05-01

Here, we have performed strain induce optical properties of BaReO3 by using density functional theory (DFT). We noticed that after applying intrinsic and extrinsic strain to the BaReO3, it shows the metallic behavior. We also studied optical properties, which show good activity in the ultraviolet region. The results show that after applying intrinsic and extrinsic strain to BaReO3 the absorption peaks are shifted towards the high UV region of the spectrum. Thus, we concluded that, BaReO3 material with extrinsic strain can be useful for high frequency UV device and optoelectronic devices.

Ultraviolet Spectroscopy of Asteroid(4) Vesta

NASA Technical Reports Server (NTRS)

Li, Jian-Yang; Bodewits, Dennis; Feaga, Lori M.; Landsman, Wayne; A'Hearn, Michael F.; Mutchler, Max J.; Russell, Christopher T.; McFadden, Lucy A.; Raymond, Carol A.

2011-01-01

We report a comprehensive review of the UV-visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm arc derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope in the ultraviolet displays a sharp minimum ncar sub-Earth longitude of 20deg, and maximum in the eastern hemisphere. This is completely consistent with the distribution of the spectral slope in the visible wavelength. The uncertainty of the measurement in the ultraviolet is approx.20%, and in the visible wavelengths better than 10%. The amplitude of Vesta's rotational lightcurves is approx.10% throughout the range of wavelengths we observed, but is smaller at 950 nm (approx.6%) ncar the 1-micron mafic band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/ncar-infrared lightcurves with respect to sub-Earth longitude. Vesta's average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible. and ncar-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies lack of global space weathering on Vesta. Keyword,: Asteroid Vesta; Spectrophotometry; Spectroscopy; Ultraviolet observations; Hubble Space Telescope observations

Ultraviolet safety assessments of insect light traps.

PubMed

Sliney, David H; Gilbert, David W; Lyon, Terry

2016-01-01

Near-ultraviolet (UV-A: 315-400 nm), "black-light," electric lamps were invented in 1935 and ultraviolet insect light traps (ILTs) were introduced for use in agriculture around that time. Today ILTs are used indoors in several industries and in food-service as well as in outdoor settings. With recent interest in photobiological lamp safety, safety standards are being developed to test for potentially hazardous ultraviolet emissions. A variety of UV "Black-light" ILTs were measured at a range of distances to assess potential exposures. Realistic time-weighted human exposures are shown to be well below current guidelines for human exposure to ultraviolet radiation. These UV-A exposures would be far less than the typical UV-A exposure in the outdoor environment. Proposals are made for realistic ultraviolet safety standards for ILT products.

Formation of giant H II regions following supernova explosions

NASA Technical Reports Server (NTRS)

Sartori, L.

1971-01-01

The principal optical properties of type I supernovae are summarized. These include the light curve and the spectrum. The spectra consist of broad bands with very little continuum. According to the theory presented, the observed light is principally fluorescence, excited in the medium surrounding the supernova by ultraviolet radiation originating from the explosion. It is proposed that the spectrum that impinges on the fluorescent medium while emission is taking place must fall abruptly across the Lyman edge of He II. Such a filtering action is plausibly provided by a much denser internal region, rich in helium, immediately surrounding the exploding object. This will form a Stromgren sphere during the time the intense UV pulse is passing through it. The dense region also slows down the photons below the edge by Thomson scattering, thereby spreading out the UV pulse in time. Various proposed mechanisms for the production of ionization in the Gum nebula are discussed.

A new study of the interacting binary star V356 Sgr

NASA Technical Reports Server (NTRS)

Polidan, R. S.

1988-01-01

Results on V356 Sgr from IUE and Voyager ultraviolet (500 to 3200 A) observations obtained in 1986 and 1987, primarily during 2 total eclipses are presented. The eclipse of Aug. 15, 1986 was fully covered with IUE low dispersion images and 9 hr of Voyager UVS data. The eclipse of Mar. 25, 1987 was covered with IUE low dispersion images and 1 high dispersion SWP image. During both eclipses the total strength of the emission lines is found to be invariant. An uneclipsed UV continuum is detected at wavelengths shorter than 1500 A. The high dispersion SWP spectrum reveals that the emission lines are extremely broad, almost symmetrical emissions with weak, slightly blue shifted absorption components. No evidence of carbon, C I, C II, C III, or C IV, is seen in the emission or absorption spectrum of V356 Sgr in eclipse. Models for this binary system are presented.

The spectrum of the Jovian dayglow observed at 3 A resolution with the Hopkins ultraviolet telescope

NASA Technical Reports Server (NTRS)

Feldman, P. D.; Mcgrath, M. A.; Moos, H. W.; Durrance, S. T.; Strobel, D. F.; Davidsen, A. F.

1993-01-01

Ultraviolet spectra of the Jovian equatorial dayglow in the spectral range 830-1850 A were obtained at about 3 A resolution. The observed spectrum is dominated by electron impact excitation of the H2 Lyman and Werner band systems. Solar Lyman-beta induced fluorescence in the (6, nu-double prime) Lyman band progression is clearly identified in five distinct P(1) lines, and the contribution of solar fluorescence to the total 2.3 kR slit-averaged H2 emission rate is estimated to be 17-22 percent. The electron excitation spectrum is characterized by a relative weakness of the Werner band system and the absence of cascade contributions to the Lyman system and is very similar to that of the south polar aurora. The integrated H2 emission rate in the 900-1100 A band is a factor of two lower than that measured by the Voyager UVS. Based on model calculations, photoelectron excitation does not appear able to account for the amount of observed electron-excited H2 emission.

The U.S. Rosetta Project at Its First Science Target: Asteroid (2867) Steins, 2008

NASA Technical Reports Server (NTRS)

Alexander, C.; Sweetnam, D.; Gulkis, S.; Weissman, P.; Holmes, D.; Parker, J.; Burch, J.; Goldstein, R.; Mokashi, P.; Fuselier, S.;

The Far-UV Albedo of the Moon Determined from Dayside LAMP Observations

NASA Astrophysics Data System (ADS)

Bullock, Mark A.; Retherford, K. D.; Gladstone, R.; Greathouse, T. K.; Mandt, K. E.; Hendrix, A. R.; Feldman, P. D.; Miles, P. F.; Egan, A. F.

2013-10-01

The Lyman Alpha Mapping Project (LAMP) onboard the Lunar Reconnaissance Orbiter (LRO) has been recording far-UV photons reflected from the lunar surface almost continuously since December 2009 (Gladstone et al., 2010). One photon at a time, LAMP builds up spectra from 575 to 1965 Å with a resolution of 26 Å. We will present 3 years of accumulated LAMP lunar dayside spectral maps and derive the lunar geometric albedo spectrum for a range of phase angles. These LAMP observations can thus be used to reconstruct the lunar far-UV photometric function and refine photometric models of the lunar surface (Hapke, 1963; Lucke et al., 1976). We will also compare LAMP lunar dayside albedo with the albedo from 820-1840 Å obtained by the Hopkins Ultraviolet Telescope (HUT) on the March 1995 Astro-2 Space Shuttle mission (Henry et al., 1995). The improved lunar photometric functions from our analysis of LAMP albedo spectra will enable a better quantitative assessment of how phase angle and composition affect the Moon’s reflectance in the far-UV. Gladstone, G. R., Stern, S. A., Retherford, K. D., Black, R. K., Slater, D. C., Davis, M. W., Versteeg, M. H., Persson, K. B., Parker, J. W., Kaufmann, D. E., Egan, A. F., Greathouse, T. K., Feldman, P. D., Hurley, D., Pryor, W. R., Hendrix, A. R., 2010. LAMP: The lyman alpha mapping project on NASA's lunar reconnaissance orbiter mission. Space Science Reviews. 150, 161-181. Hapke, B. W., 1963. A theoretical photometric function for the lunar surface. Journal of Geophysical Research. 68, 4571-4586. Henry, R. C., Feldman, P. D., Kruk, J. W., Davidsen, A. F., Durrance, S. T., 1995. Ultraviolet Albedo of the Moon with the Hopkins Ultraviolet Telescope. The Astrophysical Journal Letters. 454, L69. Lucke, R. L., Henry, R. C., Fastie, W. G., 1976. Far-ultraviolet albedo of the moon. The Astronomical Journal. 81, 1162-1169.

Metal-Insulator-Semiconductor Photodetectors

PubMed Central

Lin, Chu-Hsuan; Liu, Chee Wee

2010-01-01

The major radiation of the Sun can be roughly divided into three regions: ultraviolet, visible, and infrared light. Detection in these three regions is important to human beings. The metal-insulator-semiconductor photodetector, with a simpler process than the pn-junction photodetector and a lower dark current than the MSM photodetector, has been developed for light detection in these three regions. Ideal UV photodetectors with high UV-to-visible rejection ratio could be demonstrated with III–V metal-insulator-semiconductor UV photodetectors. The visible-light detection and near-infrared optical communications have been implemented with Si and Ge metal-insulator-semiconductor photodetectors. For mid- and long-wavelength infrared detection, metal-insulator-semiconductor SiGe/Si quantum dot infrared photodetectors have been developed, and the detection spectrum covers atmospheric transmission windows. PMID:22163382

Galaxy Morphology From the UV to the FIR: An Intercomparison of Recent Observations From Space With New Radiative Transfer Models

NASA Technical Reports Server (NTRS)

(CIT), Barry Madore

1995-01-01

We will present the latest multiwavelength observations of spiral galaxies made from space and from the ground covering the electromagnetic spectrum from the far ultraviolet (ASTRO-2 UIT observations) through the optical, and out to the far infrared (IRAS). Comparisons with recent theoretical models for the radiative transfer of stellar light through a three-dimensional dusty galaxy will be presented.

A thermal vacuum-UV solar simulator test system for assessing microbiological viability

NASA Technical Reports Server (NTRS)

Ross, D. S.; Wardle, M. D.; Taylor, D. M.

1975-01-01

Microorganisms were exposed to a simulated space environment in order to assess the photobiological effect of broad spectrum, nonionizing solar electromagnetic radiation in terms of viability. A thermal vacuum chamber capable of maintaining a vacuum of 0.000133n/sq m and an ultraviolet rich solar simulator were the main ingredients of the test system. Results to date indicate the system to be capable of providing reliable microbiological data.

Ultraviolet safety assessments of insect light traps

PubMed Central

Sliney, David H.; Gilbert, David W.; Lyon, Terry

2016-01-01

ABSTRACT Near-ultraviolet (UV-A: 315–400 nm), “black-light,” electric lamps were invented in 1935 and ultraviolet insect light traps (ILTs) were introduced for use in agriculture around that time. Today ILTs are used indoors in several industries and in food-service as well as in outdoor settings. With recent interest in photobiological lamp safety, safety standards are being developed to test for potentially hazardous ultraviolet emissions. A variety of UV “Black-light” ILTs were measured at a range of distances to assess potential exposures. Realistic time-weighted human exposures are shown to be well below current guidelines for human exposure to ultraviolet radiation. These UV-A exposures would be far less than the typical UV-A exposure in the outdoor environment. Proposals are made for realistic ultraviolet safety standards for ILT products. PMID:27043058

Distribution and nature of UV absorbers on Trition's surface

NASA Technical Reports Server (NTRS)

Stern, S. Alan

1995-01-01

Substantial evidence suggests that a UV (ultraviolet) Spectrally Absorbing Material (UV-SAM) exists on Triton's surface. This evidence is found in the positive slope in Triton's spectrum from the UV to the near-IR, and the increasing contrast in Triton's light curve in the blue and UV. Although it is now widely-thought that UV-SAM's exist on Triton, little is known about their distribution and spectral properties. The goal of this NDAP Project is to determine the spatial distribution and geological context of the UV-SAM material. We hope to determine if UV-SAM's on Triton are correlated with geologic wind streaks, craters, calderas, geomorphic/topographic units, regions containing (or lacking) volatile frosts, or some other process (e.g., magnetospheric interactions). Once the location and distribution of UV-SAM's has been determined, further constraints on their composition can be made by analyzing the spectrographic data set. To accomplish these goals, various data sets will be used, including Voyager 2 UV and visible images of Triton's surface, IUE and HST spectra of Triton, and a geologic map of the surface based on Voyager 2 and spectrophotometric data. The results of this research will be published in the planetary science literature.

XMM-Newton study of the supersoft symbiotic system Draco C1

NASA Astrophysics Data System (ADS)

Saeedi, Sara; Sasaki, Manami; Ducci, Lorenzo

2018-01-01

We present the results of the analysis of thirty-one XMM-Newton observations of the symbiotic star Draco C1 located in the Draco dwarf spheroidal galaxy. This object had been identified as a supersoft source based on ROSAT data. We analysed X-ray, ultraviolet (UV) and optical data taken with XMM-Newton in order to obtain the physical parameters and the geometry of the system. We have also performed the first X-ray timing analysis of Draco C1. The X-ray spectrum is well fitted with a blackbody model with a temperature of (1.8 ± 0.3) × 105 K. We obtained a bolometric luminosity of ≳1038 erg s-1 for the white dwarf. The X-ray spectrum and luminosity suggest stable nuclear burning on the surface of the white dwarf. The low column density derived from the X-ray spectrum is consistent with the lack of nebular lines found in previous UV studies. The long-term variability in the optical and the UV suggests that the system is not observed face-on and that the variability is caused by the reflection effect. For the red giant companion, we estimate a radius of ∼110 R⊙ and an upper limit ≲1.5 M⊙ for its mass assuming Roche lobe overflow.

Reddened, Redshifted, or Intrinsically Red? Understanding Near-ultraviolet Colors of Type Ia Supernovae

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, Peter J.; Landez, Nancy J.; Milne, Peter A.

The intrinsic colors of Type Ia supernovae (SNe Ia) are important to understanding their use as cosmological standard candles. Understanding the effects of reddening and redshift on the observed colors are complicated and dependent on the intrinsic spectrum, the filter curves, and the wavelength dependence of reddening. We present ultraviolet and optical data of a growing sample of SNe Ia observed with the Ultraviolet/Optical Telescope on the Swift spacecraft and use this sample to re-examine the near-UV (NUV) colors of SNe Ia. We find that a small amount of reddening ( E ( B − V ) = 0.2 mag)more » could account for the difference between groups designated as NUV-blue and NUV-red, and a moderate amount of reddening ( E ( B − V ) = 0.5 mag) could account for the whole NUV-optical differences. The reddening scenario, however, is inconsistent with the mid-UV colors and color evolution. The effect of redshift alone only accounts for part of the variation. Using a spectral template of SN2011fe, we can forward model the effects of redshift and reddening and directly compare those with the observed colors. We find that some SNe are consistent with reddened versions of SN2011fe, but most SNe Ia are much redder in the uvw 1 − v color than SN2011fe reddened to the same b − v color. The absolute magnitudes show that two out of five NUV-blue SNe Ia are blue because their near-UV luminosity is high, and the other three are optically fainter. We also show that SN 2011fe is not a “normal” SN Ia in the UV, but has colors placing it at the blue extreme of our sample.« less

Far-ultraviolet spectrophotometry of Spica

NASA Technical Reports Server (NTRS)

Cook, Timothy A.; Cash, Webster; Snow, Theodore P.

1989-01-01

A spectrum of the star Spica (Alpha Virginis) from 960 to 1270 A was recorded by a rocket-borne spectrograph March 13, 1988. The spectrum, which has 3.4 A resolution, shows a much sharper drop-off in intensity near 1050 A than similar measurements made by the Voyager UVS, but is in good agreement with the spectrum obtained by Brune et al. in a 1977 sounding rocket. The disagreement with Voyager is a factor of 1.5 at 1100 A and grows to a factor of 5.7 at 960 A. This implies that the photometric standards between 912 and 1100 A may need some revision, and that the standard photospheric models for hot stars may err significantly near the Lyman limit.

Deep Ultraviolet Light Emitters Based on (Al,Ga)N/GaN Semiconductor Heterostructures

NASA Astrophysics Data System (ADS)

Liang, Yu-Han

Deep ultraviolet (UV) light sources are useful in a number of applications that include sterilization, medical diagnostics, as well as chemical and biological identification. However, state-of-the-art deep UV light-emitting diodes and lasers made from semiconductors still suffer from low external quantum efficiency and low output powers. These limitations make them costly and ineffective in a wide range of applications. Deep UV sources such as lasers that currently exist are prohibitively bulky, complicated, and expensive. This is typically because they are constituted of an assemblage of two to three other lasers in tandem to facilitate sequential harmonic generation that ultimately results in the desired deep UV wavelength. For semiconductor-based deep UV sources, the most challenging difficulty has been finding ways to optimally dope the (Al,Ga)N/GaN heterostructures essential for UV-C light sources. It has proven to be very difficult to achieve high free carrier concentrations and low resistivities in high-aluminum-containing III-nitrides. As a result, p-type doped aluminum-free III-nitrides are employed as the p-type contact layers in UV light-emitting diode structures. However, because of impedance-mismatch issues, light extraction from the device and consequently the overall external quantum efficiency is drastically reduced. This problem is compounded with high losses and low gain when one tries to make UV nitride lasers. In this thesis, we provide a robust and reproducible approach to resolving most of these challenges. By using a liquid-metal-enabled growth mode in a plasma-assisted molecular beam epitaxy process, we show that highly-doped aluminum containing III-nitride films can be achieved. This growth mode is driven by kinetics. Using this approach, we have been able to achieve extremely high p-type and n-type doping in (Al,Ga)N films with high aluminum content. By incorporating a very high density of Mg atoms in (Al,Ga)N films, we have been able to show, by temperature-dependent photoluminescence, that the activation energy of the acceptors is substantially lower, thus allowing a higher hole concentration than usual to be available for conduction. It is believed that the lower activation energy is a result of an impurity band tail induced by the high Mg concentration. The successful p-type doping of high aluminum-content (Al,Ga)N has allowed us to demonstrate operation of deep ultraviolet LEDs emitting at 274 nm. This achievement paves the way for making lasers that emit in the UV-C region of the spectrum. In this thesis, we performed preliminary work on using our structures to make UV-C lasers based on photonic crystal nanocavity structures. The nanocavity laser structures show that the threshold optical pumping power necessary to reach lasing is much lower than in conventional edge-emitting lasers. Furthermore, the photonic crystal nanocavity structure has a small mode volume and does not need mirrors for optical feedback. These advantages significantly reduce material loss and eliminate mirror loss. This structure therefore potentially opens the door to achieving efficient and compact lasers in the UV-C region of the spectrum.

Ultraviolet Communication for Medical Applications

DTIC Science & Technology

2015-06-01

DEI procured several UVC phosphors and tested them with vacuum UV (VUV) excitation. Available emission peaks include: 226 nm, 230 nm, 234 nm, 242...SUPPLEMENTARY NOTES Report contains color. 14. ABSTRACT Under this Phase II SBIR effort, Directed Energy Inc.’s (DEI) proprietary ultraviolet ( UV ...15. SUBJECT TERMS Non-line-of-sight (NLOS), networking, optical communication, plasma-shells, short range, ultraviolet ( UV ) light 16. SECURITY

Ultraviolet radiation, human health, and the urban forest

Treesearch

Gordon M. Heisler; Richard H. Grant

2000-01-01

Excess exposure to ultraviolet (UV) radiation from the sun, particularly the ultraviolet B (UVB) portion, has been linked with adverse effects on human health ranging from skin cancers to eye diseases such as cataracts. Trees may prevent even greater disease rates in humans by reducing UV exposure. Tree shade greatly reduces UV irradiance when both the sun and sky are...

A full-dimensional multilayer multiconfiguration time-dependent Hartree study on the ultraviolet absorption spectrum of formaldehyde oxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meng, Qingyong, E-mail: mengqingyong@dicp.ac.cn; Meyer, Hans-Dieter, E-mail: hans-dieter.meyer@pci.uni-heidelberg.de

2014-09-28

Employing the multilayer multiconfiguration time-dependent Hartree (ML-MCTDH) method in conjunction with the multistate multimode vibronic coupling Hamiltonian (MMVCH) model, we perform a full dimensional (9D) quantum dynamical study on the simplest Criegee intermediate, formaldehyde oxide, in five lower-lying singlet electronic states. The ultraviolet (UV) spectrum is then simulated by a Fourier transform of the auto-correlation function. The MMVCH model is built based on extensive MRCI(8e,8o)/aug-cc-pVTZ calculations. To ensure a fast convergence of the final calculations, a large number of ML-MCTDH test calculations is performed to find an appropriate multilayer separations (ML-trees) of the ML-MCTDH nuclear wave functions, and the dynamicalmore » calculations are carefully checked to ensure that the calculations are well converged. To compare the computational efficiency, standard MCTDH simulations using the same Hamiltonian are also performed. A comparison of the MCTDH and ML-MCTDH calculations shows that even for the present not-too-large system (9D here) the ML-MCTDH calculations can save a considerable amount of computational resources while producing identical spectra as the MCTDH calculations. Furthermore, the present theoretical B{sup ~} {sup 1}A{sup ′}←X{sup ~} {sup 1}A{sup ′} UV spectral band and the corresponding experimental measurements [J. M. Beames, F. Liu, L. Lu, and M. I. Lester, J. Am. Chem. Soc. 134, 20045–20048 (2012); L. Sheps, J. Phys. Chem. Lett. 4, 4201–4205 (2013); W.-L. Ting, Y.-H. Chen, W. Chao, M. C. Smith, and J. J.-M. Lin, Phys. Chem. Chem. Phys. 16, 10438–10443 (2014)] are discussed. To the best of our knowledge, this is the first theoretical UV spectrum simulated for this molecule including nuclear motion beyond an adiabatic harmonic approximation.« less

Contributions of visible and ultraviolet parts of sunlight to photoinhibition.

PubMed

Hakala-Yatkin, Marja; Mäntysaari, Mika; Mattila, Heta; Tyystjärvi, Esa

2010-10-01

Photoinhibition is light-induced inactivation of PSII, and action spectrum measurements have shown that UV light causes photoinhibition much more efficiently than visible light. In the present study, we quantified the contribution of the UV part of sunlight in photoinhibition of PSII in leaves. Greenhouse-grown pumpkin leaves were pretreated with lincomycin to block the repair of photoinhibited PSII, and exposed to sunlight behind a UV-permeable or UV-blocking filter. Oxygen evolution and Chl fluorescence measurements showed that photoinhibition proceeds 35% more slowly under the UV-blocking than under the UV-permeable filter. Experiments with a filter that blocks UV-B but transmits UV-A and visible light revealed that UV-A light is almost fully responsible for the UV effect. The difference between leaves illuminated through a UV-blocking and UV-transparent filter disappeared when leaves of field-grown pumpkin plants were used. Thylakoids isolated from field-grown and greenhouse-grown plants were equally sensitive to UV light, and measurements of UV-induced fluorescence from leaves indicated that the protection of the field-grown plants was caused by substances that block the passage of UV light to the chloroplasts. Thus, the UV part of sunlight, especially the UV-A part, is potentially highly important in photoinhibition of PSII but the UV-screening compounds of plant leaves may offer almost complete protection against UV-induced photoinhibition.

[Effect of long-wave ultraviolet light (UV-A) and medium-wave ultraviolet rays (UV-B) on human skin. Critical comparison].

PubMed

Raab, W

1980-04-15

When discussing the effects of ultraviolet radiation on human skin, one should carefully distinguish between the long wave ultraviolet light (UV-A) and the short wave radiations (UV-B and UV-C). Ultraviolet A induces immediate pigmentation but, if high energies are applied, a permanent pigmentation is elicited. This type of ultraviolet A-induced pigmentation has been called "spontaneous" pigmentation as no erythematous reaction is necessary to induce or accelerate melanine formation. Ultraviolet B provokes erythema and consecutive pigmentation. Upon chronic exposure, ultraviolet B causes the wellknown actinic damage of the skin and even provokes carcinoma. With exposures to the sunlight (global radiation), one should be most careful. The public must be informed extensively about the dangers of excessive sunbaths. The use of artificial "suns" with spectra between 260 and 400 nm is limited as it may cause the same type of damage as the global radiation. An exact schedule for use of artificial lamps is strongly recommended. After one cycle of exposures, an interruption is necessary until the next cycle of irradiations may start. Upon continual use for tanning of the skin, artificial lamps may provoke irreversible damage of the skin. Radiation sources with emission spectra of wavelengths between 315 and 400 nm exclusively are well suited for the induction of skin pigmentation (cosmetic use). Potent radiation such as UVASUN systems provoke a "pleasant" permanent pigmentation after exposures for less than one hour. The use of ultraviolet A (UV-A) does not carry any risk for the human skin.

Stabilization and enhanced energy gap by Mg doping in ɛ-phase Ga2O3 thin films

NASA Astrophysics Data System (ADS)

Bi, Xiaoyu; Wu, Zhenping; Huang, Yuanqi; Tang, Weihua

2018-02-01

Mg-doped Ga2O3 thin films with different doping concentrations were deposited on sapphire substrates using laser molecular beam epitaxy (L-MBE) technique. X-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS) and ultraviolet-visible (UV-vis) absorption spectrum were used to characterize the crystal structure and optical properties of the as-grown films. Compared to pure Ga2O3 thin film, the Mg-doped thin films have transformed from the most stable β-phase into ɛ-phase. The absorption edge shifted to about 205 nm and the optical bandgap increased to ˜ 6 eV. These properties reveal that Mg-doped Ga2O3 films may have potential applications in the field of deep ultraviolet optoelectronic devices, such as deep ultraviolet photodetectors, short wavelength light emitting devices and so on.

Ultraviolet downconverting phosphor for use with silicon CCD imagers

NASA Technical Reports Server (NTRS)

Blouke, M. M.; Cowens, M. W.; Hall, J. E.; Westphal, J. A.; Christensen, A. B.

1980-01-01

The properties and application of a UV downconverting phosphor (coronene) to silicon charge coupled devices are discussed. Measurements of the absorption spectrum have been extended to below 1000 A, and preliminary results indicate the existence of useful response to at least 584 A. The average conversion efficiency of coronene was measured to be approximately 20% at 2537 A. Imagery at 3650 A using a backside illuminated 800 x 800 CCD coated with coronene is presented.

Ultraviolet to optical spectral distributions of northern star-forming galaxies

NASA Technical Reports Server (NTRS)

Mcquade, Kerry; Calzetti, Daniela; Kinney, Anne L.

1995-01-01

We report spectral energy distribution from the UV to the optical for a sample of 31 northern star-forming galaxies. We also present measurements for emission-line fluxes, continuum levels, and equivalent widths of absorption features for each individual spectrum as well as averages for the eight galactic activity classes, including normal, starburst, Seyfert 2, blue compact dwarf, blue compact, Low-Inonization Nuclear Emission Regions (LINER), H II, and combination LINER-H II galaxies.

Ultraviolet Opacity and Fluorescence in Supernova Envelopes

NASA Technical Reports Server (NTRS)

Li, Hongwei; McCray, Richard

1996-01-01

By the time the expanding envelope of a Type 2 supernova becomes transparent in the optical continuum, most of the gamma-ray luminosity produced by radioactive Fe/Co/Ni clumps propagates into the hydrogen/helium envelope and is deposited there, if at all. The resulting fast electrons excite He 1 and H 1, the two- photon continua of which are the dominant internal sources of ultraviolet radiation. The UV radiation is blocked by scattering in thousands of resonance lines of metals and converted by fluorescence into optical and infrared emission lines that escape freely. We describe results of Monte Carlo calculations that simulate non-LTE scattering and fluorescence in more than five million allowed lines of Ca, Sc, Ti, V, Cr, Mn, Fe, Co, and Ni. For a model approximating conditions in the envelope of SN 1987A, the calculated emergent spectrum resembles the observed one. For the first 2 yr after explosion, the ultraviolet radiation (lambda less than or approximately equals 3000) is largely blocked and converted into a quasi continuum of many thousands of weak optical and infrared emission lines and some prominent emission features, such as the Ca 2 lambdalambda8600 triplet. Later, as the envelope cools and expands, it becomes more transparent, and an increasing fraction of the luminosity emerges in the UV band.

Ultraviolet radiation-blocking characteristics of contact lenses: relevance to eye protection for psoralen-sensitised patients.

PubMed

Anstey, A; Taylor, D; Chalmers, I; Ansari, E

1999-10-01

Nine brands of contact lens marketed as "UV protective" were tested for ultraviolet (UV) transmission in order to assess potential suitability for psoralen-sensitised patients. UV-transmission characteristics of hydrated lenses was tested with a Bentham monochromator spectro-radiometer system. All lenses showed minimal transmission loss in the visible band. The performance of the nine lenses was uniform for ultraviolet B radiation with negligible transmission, but showed variation in transmission for ultraviolet A radiation. None of the lenses complied with UV-transmission criteria used previously to assess UV-blocking spectacles. Only two lenses had UV-blocking characteristics which came close to the arbitrary criteria used. The performance of ordinary soft and hard lenses was very similar, with negligible blocking of UV radiation. None of the nine contact lenses marketed as "UV protective" excluded sufficient UVA to comply with criteria in current use to assess UV protection in spectacles for psoralen-sensitised patients. However, the improved UV-blocking characteristics of contact lenses identified in this paper compared to previous studies suggests that such a contact lens will soon become available. Meanwhile, contact lens-wearing systemically sensitised PUVA patients should continue to wear approved spectacles for eye protection whilst photosensitised with psoralen.

Is there a UV/X-ray connection in IRAS 13224-3809?

NASA Astrophysics Data System (ADS)

Buisson, D. J. K.; Lohfink, A. M.; Alston, W. N.; Cackett, E. M.; Chiang, C.-Y.; Dauser, T.; De Marco, B.; Fabian, A. C.; Gallo, L. C.; García, J. A.; Jiang, J.; Kara, E.; Middleton, M. J.; Miniutti, G.; Parker, M. L.; Pinto, C.; Uttley, P.; Walton, D. J.; Wilkins, D. R.

2018-04-01

We present results from the optical, ultraviolet, and X-ray monitoring of the NLS1 galaxy IRAS 13224-3809 taken with Swift and XMM-Newton during 2016. IRAS 13224-3809 is the most variable bright AGN in the X-ray sky and shows strong X-ray reflection, implying that the X-rays strongly illuminate the inner disc. Therefore, it is a good candidate to study the relationship between coronal X-ray and disc UV emission. However, we find no correlation between the X-ray and UV flux over the available ˜40 d monitoring, despite the presence of strong X-ray variability and the variable part of the UV spectrum being consistent with irradiation of a standard thin disc. This means either that the X-ray flux which irradiates the UV emitting outer disc does not correlate with the X-ray flux in our line of sight and/or that another process drives the majority of the UV variability. The former case may be due to changes in coronal geometry, absorption or scattering between the corona and the disc.

Exploring Mercury's Surface in UltraViolet from Orbit

NASA Astrophysics Data System (ADS)

Izenberg, N.

2017-12-01

The MESSENGER Mission's Ultraviolet and Visible Spectrometer (UVVS) component of its Mercury Atmosphere and Surface Composition Spectrometer (MASCS) instrument obtained approximately 4600 point observations of Mercury's surface in middle ultraviolet (MUV; 210 nm - 300 nm) and far ultraviolet (FUV; 119.1 - 122.5 nm and 129.2 - 131.5 nm) wavelengths over the course of its orbital mission, mostly in Mercury's southern hemisphere. Given the very low (<1 to 2 wt %) average abundance of iron in the silicates of Mercury observed by multiple MESSENGER instruments, the near- to middle-ultraviolet wavelengths encompassing the oxygen metal charge transfer band (<400 nm), which is more sensitive to the presence of iron than the classic 1 micron absorption band, provides potentially useful additional compositional insight into the top layer of Mercury's regolith. The presence of nano- and microphase carbon also has potentially significant expression in the ultraviolet, and the interplay and variation between carbon and iron in mercury surface materials is an active area of investigation. Analysis of middle-UV surface reflectance and parameters appear to support the presence of varying amounts of carbon in different spectral or geologic units on Mercury. Far-UV reflectance data is currently under-utilized, but analysis of lunar surface by the Lunar Reconnaissance Orbiter (LRO) Lyman Alpha Mapping Project (LAMP) indicate that the data are sensitive to both composition and space weathering. The far-UV reflectance from MASCS may provide similar information for the Mercury surface, complementing results from longer wavelengths. MESSENGER data products for surface reflectance include middle-UV reflectance spectra, ultraviolet far-UV reflectance values, combined middle-UV through near-infrared spectra (210 nm - 1450 nm), a global `spectral cube' of near-UV to near-IR, and an upcoming UV spectral cube.

ULTRAVIOLET DISINFECTION STUDIES WITH CCL LISTED MICROORGANISMS

EPA Science Inventory

Resistance to ultraviolet (UV) disinfection is an essential aspect regarding all microbial groups listed on the CCL. The U.S. drinking water industry is interested in including UV light treatment as an amendment to conventional treatment for disinfecting water supplies. UV disi...

Isolation and characterization of ultraviolet light-sensitive mutants of the blue-green alga Anacystis nidulans.

NASA Technical Reports Server (NTRS)

Asato, Y.

1972-01-01

Three independently isolated ultraviolet light sensitive (uvs) mutants of Anacystis nidulans were characterized. Strain uvs-1 showed the highest sensitivity to UV by its greatly reduced photoreactivation capacity following irradiation. Pretreatment with caffeine suppressed the dark-survival curve of strain uvs-1, thus indicating the presence of excision enzymes involved in dark repair. Under 'black' and 'white' illumination, strain uvs-1 shows photorecovery properties comparable with wild-type cultures. Results indicate that strains uvs-1, uvs-35, and uvs-88 are probably genetically distinct UV-sensitive mutants.

Epidermal UV-A absorbance and whole-leaf flavonoid composition in pea respond more to solar blue light than to solar UV radiation.

PubMed

Siipola, Sari M; Kotilainen, Titta; Sipari, Nina; Morales, Luis O; Lindfors, Anders V; Robson, T Matthew; Aphalo, Pedro J

2015-05-01

Plants synthesize phenolic compounds in response to certain environmental signals or stresses. One large group of phenolics, flavonoids, is considered particularly responsive to ultraviolet (UV) radiation. However, here we demonstrate that solar blue light stimulates flavonoid biosynthesis in the absence of UV-A and UV-B radiation. We grew pea plants (Pisum sativum cv. Meteor) outdoors, in Finland during the summer, under five types of filters differing in their spectral transmittance. These filters were used to (1) attenuate UV-B; (2) attenuate UV-B and UV-A < 370 nm; (3) attenuate UV-B and UV-A; (4) attenuate UV-B, UV-A and blue light; and (5) as a control not attenuating these wavebands. Attenuation of blue light significantly reduced the flavonoid content in leaf adaxial epidermis and reduced the whole-leaf concentrations of quercetin derivatives relative to kaempferol derivatives. In contrast, UV-B responses were not significant. These results show that pea plants regulate epidermal UV-A absorbance and accumulation of individual flavonoids by perceiving complex radiation signals that extend into the visible region of the solar spectrum. Furthermore, solar blue light instead of solar UV-B radiation can be the main regulator of phenolic compound accumulation in plants that germinate and develop outdoors. © 2014 John Wiley & Sons Ltd.

Simultaneous X-ray and Far-Ultraviolet Spectra of AGN with ASCA and HUT

NASA Technical Reports Server (NTRS)

Kriss, Gerard A.

1997-01-01

We obtained ASCA spectra of the Seyfert 1 galaxy NGC 3516 in March 1995. Simultaneous far-UV observations were obtained with the Hopkins Ultraviolet Telescope on the Astro-2 shuttle mission. The ASCA spectrum shows a lightly absorbed power law of energy index 0.78. The low energy absorbing column is significantly less than previously seen. Prominent 0 VII and 0 VIII absorption edges are visible, but, consistent with the much lower total absorbing column, no Fe K absorption edge is detectable. A weak, narrow Fe K(alpha) emission line from cold material is present as well as a broad Fe K(alpha) line. These features are similar to those reported in other Seyfert 1 galaxies. A single warm absorber model provides only an imperfect description of the low energy absorption. In addition to a highly ionized absorber with ionization parameter U = 1.66 and a total column density of 1.4 x 10(exp 22)/sq cm, adding a lower ionization absorber with U = 0.32 and a total column of 6.9 x 10(exp 21)/sq cm significantly improves the fit. The contribution of resonant line scattering to our warm absorber models limits the Doppler parameter to less than 160 km/s at 90% confidence. Turbulence at the sound speed of the photoionized gas provides the best fit. None of the warm absorber models fit to the X-ray spectrum can match the observed equivalent widths of all the UV absorption lines. Accounting for the X-ray and UV absorption simultaneously requires an absorbing region with a broad range of ionization parameters and column densities.

Ultraviolet spectroscopy combined with ultra-fast liquid chromatography and multivariate statistical analysis for quality assessment of wild Wolfiporia extensa from different geographical origins.

PubMed

Li, Yan; Zhang, Ji; Jin, Hang; Liu, Honggao; Wang, Yuanzhong

2016-08-05

A quality assessment system comprised of a tandem technique of ultraviolet (UV) spectroscopy and ultra-fast liquid chromatography (UFLC) aided by multivariate analysis was presented for the determination of geographic origin of Wolfiporia extensa collected from five regions in Yunnan Province of China. Characteristic UV spectroscopic fingerprints of samples were determined based on its methanol extract. UFLC was applied for the determination of pachymic acid (a biomarker) presented in individual test samples. The spectrum data matrix and the content of pachymic acid were integrated and analyzed by partial least squares discriminant analysis (PLS-DA) and hierarchical cluster analysis (HCA). The results showed that chemical properties of samples were clearly dominated by the epidermis and inner part as well as geographical origins. The relationships among samples obtained from these five regions have been also presented. Moreover, an interesting finding implied that geographical origins had much greater influence on the chemical properties of epidermis compared with that of the inner part. This study demonstrated that a rapid tool for accurate discrimination of W. extensa by UV spectroscopy and UFLC could be available for quality control of complicated medicinal mushrooms. Copyright © 2016 Elsevier B.V. All rights reserved.

Singlet and doublet states UV-vis spectrum and electronic properties of 3-methylchrysene and 4-methylchrysene in glass matrix.

PubMed

Husain, Mudassir M; Tandon, H C; Varadwaj, Pradeep R

2008-03-01

The ultraviolet-visual spectrum of 3-methylchrysene, 4-methylchrysene and their radical cations formed by ultraviolet radiations, were measured in glass matrix at the room temperature. In the measured singlet state spectrum we were able to identify the alpha, p, beta, beta' (Clar's) or (1)L(b), (1)L(a)(1)B(b), (1)B(a) (Platt's notation) bands. The presence of alpha, beta or (1)L(b), (1)B(b) was confirmed by calculating their wavelength ratio lambda(alpha)/lambda(beta). Since matrix induces perturbation in the measured spectrum; it becomes necessary to take into account the perturbation while computing the spectrum. An effort has been made in this work to simulate the electronic spectrum in the same environment as is measured. This study presents the first calculated spectrum of these systems and their cations in glass matrix by semi empirical methods. To observe the magnitude of perturbation and hence to see the spectral shift in glass matrix, the spectrum was calculated in the free state as well. Spectral properties such as frontier orbitals gap, dipole moment, mean polarizabilities and its tensors were also computed both in glass matrix and free state using semiemperical method. The measured bands of 3-methylchrysene cation at wavelength 416.50 and 473.85 nm closely match with the available diffuse intersteallar bands (DIBs) at 417.55 and 472.64 nm, respectively. Also the observed 474.85 nm band of 4-methylchrysene cation matches the DIB at 476.00 nm.

Chemical films and monolayers on the water surface and their interactions with ultraviolet radiation: a pilot investigation

NASA Astrophysics Data System (ADS)

Schouten, Peter; Lemckert, Charles; Turnbull, David; Parisi, Alfio; Downs, Nathan; Underhill, Ian; Turner, Geoff

2011-06-01

Over the past 50 years numerous types of chemical films and monolayers have been deployed on top of a wide variety of water reserves in an endeavour to reduce evaporation. To date very little knowledge has been assimilated on how these chemical films and monolayers, once applied to a water surface, influence the underwater UV light field and, in turn, the delicate ecosystems that exist in aquatic environments. This manuscript presents underwater UV exposure profiles weighted to the DNA damage action spectrum measured under an octadecanol/hexadecanol/lime chemical film mixture, a silicone-based chemical film and an octadecanol monolayer applied to the water surface. UV transmission and absorption properties were also evaluated for each of these chemical films and monolayers. From this it was found that when chemical films/monolayers are applied to surface water they can reduce the penetration of biologically effective UV into the water column by up to 85% at a depth as small as 1 cm. This could have a positive influence on the aquatic ecosystem, as harmful UV radiation may be prevented from reaching and consequently damaging a variety of life forms or it could have a negative effect by potentially stopping aquatic organisms from adapting to solar ultraviolet radiation over extended application intervals. Additionally, there is currently no readily applicable system or technique available to readily detect or visualize chemical films and monolayers on the water surface. To overcome this problem a new method of monolayer and chemical film visualization, using a UV camera system, is detailed and tested and its applicability for usage in both laboratory-based trials and real-world operations is evaluated.

Solar-Iss a New Solar Reference Spectrum Covering the Far UV to the Infrared (165 to 3088 Nm) Based on Reanalyzed Solar/solspec Cycle 24 Observations

NASA Astrophysics Data System (ADS)

Damé, L.; Meftah, M.; Irbah, A.; Hauchecorne, A.; Bekki, S.; Bolsée, D.; Pereira, N.; Sluse, D.; Cessateur, G.

2017-12-01

Since April 5, 2008 and until February 15, 2017, the SOLSPEC (SOLar SPECtrometer) spectro-radiometer of the SOLAR facility on the International Space Station performed accurate measurements of Solar Spectral Irradiance (SSI) from the far ultraviolet to the infrared (165 nm to 3088 nm). These measurements, unique by their large spectral coverage and long time range, are of primary importance for a better understanding of solar physics and of the impact of solar variability on climate (via Earth's atmospheric photochemistry), noticeably through the "top-down" mechanism amplifying ultraviolet (UV) solar forcing effects on the climate (UV affects stratospheric dynamics and temperatures, altering interplanetary waves and weather patterns both poleward and downward to the lower stratosphere and troposphere regions). SOLAR/SOLSPEC, with almost 9 years of observations covering the essential of the unusual solar cycle 24 from minimum in 2008 to maximum, allowed to establish new reference solar spectra from UV to IR (165 to 3088 nm) at minimum (beginning of mission) and maximum of activity. The complete reanalysis was possible thanks to revised engineering corrections, improved calibrations and advanced procedures to account for thermal, aging and pointing corrections. The high quality and sensitivity of SOLSPEC data allow to follow temporal variability in UV but also in visible along the cycle. Uncertainties on these measurements are evaluated and results, absolute reference spectra and variability, are compared with other measurements (WHI, ATLAS-3, SCIAMACHY, SORCE/SOLSTICE, SORCE/SIM) and models (SATIRE-S, NRLSSI, NESSY)

Hazards Caused by UV Rays of Xenon Light Based High Performance Solar Simulators.

PubMed

Dibowski, Gerd; Esser, Kai

2017-09-01

Solar furnaces are used worldwide to conduct experiments to demonstrate the feasibility of solar-chemical processes with the aid of concentrated sunlight, or to qualify high temperature-resistant components. In recent years, high-flux solar simulators (HFSSs) based on short-arc xenon lamps are more frequently used. The emitted spectrum is very similar to natural sunlight but with dangerous portions of ultraviolet light as well. Due to special benefits of solar simulators the increase of construction activity for HFSS can be observed worldwide. Hence, it is quite important to protect employees against serious injuries caused by ultraviolet radiation (UVR) in a range of 100 nm to 400 nm. The UV measurements were made at the German Aerospace Center (DLR), Cologne and Paul-Scherrer-Institute (PSI), Switzerland, during normal operations of the HFSS, with a high-precision UV-A/B radiometer using different experiment setups at different power levels. Thus, the measurement results represent UV emissions which are typical when operating a HFSS. Therefore, the biological effects on people exposed to UVR was investigated systematically to identify the existing hazard potential. It should be noted that the permissible workplace exposure limits for UV emissions significantly exceeded after a few seconds. One critical value was strongly exceeded by a factor of 770. The prevention of emissions must first and foremost be carried out by structural measures. Furthermore, unambiguous protocols have to be defined and compliance must be monitored. For short-term activities in the hazard area, measures for the protection of eyes and skin must be taken.

The investigation of O and N2 densities from the OSO-7 extreme UV data

NASA Technical Reports Server (NTRS)

1975-01-01

The results of solar radiation observations in the extreme ultra-violet spectrum from 200 A to 600 A made by the OSO-7 Satellite were studied. The results of the influence of attenuation by the atmosphere in the 250 to 500 km altitude range are presented. Using published molecular absorption cross-sections at 304 A and 256 A, the Jaccia atmospheric model is validated, and shows that a mean exospheric of 1050 K is appropriate for the sunset data.

Enhancement of growth and lipid production from microalgae using fluorescent paint under the solar radiation.

PubMed

Seo, Yeong Hwan; Cho, Changsoon; Lee, Jung-Yong; Han, Jong-In

2014-12-01

Solar radiation has intensity that is too high to inhibit microalgae activity and is composed of wide light spectrum including ultraviolet (UV) range which cannot be utilized for microalgae. For these reasons, the modification of solar radiation is required for effective microalgae cultivation, and to do that, fluorescent paint was used for not only blocking excessive solar energy but also converting UV to visible light. With fluorescent aqueous layer, microalgae was protected from photoinhibition and could grow well, but there was difference in growth and lipid accumulation efficiencies depending on the color; maximum dry weight of 1.7 g/L was achieved in red paint, whereas best lipid content of 30% was obtained in blue one. This phenomenon was due to the different light spectrum made by colors. With simple process using fluorescent paint, modification of light was successfully done and allowing microalgae to grow under strong radiation such as solar radiation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Investigation of UV photocurable microcapsule inner crosslink extent

NASA Astrophysics Data System (ADS)

Li, Xiaowei; Meng, Shuangshuang; Lai, Weidong; Yu, Haiyang; Fu, Guangsheng

2008-11-01

UV photocuring technology has encountered increased applications in recent years, which finds a variety of applications on protective coating of the optical-fiber, ink and optical recording materials. Combined with techniques of photohardenable, microcapsule, heat-sensitive and interface-polymerization method, a novel photoheat sensitive recording material of non-silver salt is explored in this thesis. Microcapsules are particulate substance with a core and shell structure, where photopolymerizable composition, monofunctional/polyfunctional diluents, photopolymerization initiator, photosensitivity enhancing agent and dye precursor are encapsulated as the internal phase. In this paper introduced the characteristics and curing mechanism of photo-sensitive microcapsule materials. The photocuring process may be a complex-function with photopolymerizable compound and photopolymerization initiator. For the sake of high photocuring speed and degree, optimal photo-sensitive materials were selected. In order to match with the light source excitation wavelength and absorb more wider ultraviolet band, combined type of photo-polymerization initiators were employed. With the kinds and dosage of photopolymerization initiator changing, the photocuring speed and quality can be ameliorated. Through studying the UV-visible absorption spectrum and infra-red spectrum of the material , the optical response property of the inner compound can be obtained.

Deep-UV-sensitive high-frame-rate backside-illuminated CCD camera developments

NASA Astrophysics Data System (ADS)

Dawson, Robin M.; Andreas, Robert; Andrews, James T.; Bhaskaran, Mahalingham; Farkas, Robert; Furst, David; Gershstein, Sergey; Grygon, Mark S.; Levine, Peter A.; Meray, Grazyna M.; O'Neal, Michael; Perna, Steve N.; Proefrock, Donald; Reale, Michael; Soydan, Ramazan; Sudol, Thomas M.; Swain, Pradyumna K.; Tower, John R.; Zanzucchi, Pete

2002-04-01

New applications for ultra-violet imaging are emerging in the fields of drug discovery and industrial inspection. High throughput is critical for these applications where millions of drug combinations are analyzed in secondary screenings or high rate inspection of small feature sizes over large areas is required. Sarnoff demonstrated in1990 a back illuminated, 1024 X 1024, 18 um pixel, split-frame-transfer device running at > 150 frames per second with high sensitivity in the visible spectrum. Sarnoff designed, fabricated and delivered cameras based on these CCDs and is now extending this technology to devices with higher pixel counts and higher frame rates through CCD architectural enhancements. The high sensitivities obtained in the visible spectrum are being pushed into the deep UV to support these new medical and industrial inspection applications. Sarnoff has achieved measured quantum efficiencies > 55% at 193 nm, rising to 65% at 300 nm, and remaining almost constant out to 750 nm. Optimization of the sensitivity is being pursued to tailor the quantum efficiency for particular wavelengths. Characteristics of these high frame rate CCDs and cameras will be described and results will be presented demonstrating high UV sensitivity down to 150 nm.

Spectroscopic (FT-IR, FT-Raman and UV-Visible) investigations, NMR chemical shielding anisotropy (CSA) parameters of 2,6-Diamino-4-chloropyrimidine for dye sensitized solar cells using density functional theory.

PubMed

Gladis Anitha, E; Joseph Vedhagiri, S; Parimala, K

2015-02-05

The molecular structure, geometry optimization, vibrational frequencies of organic dye sensitizer 2,6-Diamino-4-chloropyrimidine (DACP) were studied based on Hartree-Fock (HF) and density functional theory (DFT) using B3LYP methods with 6-311++G(d,p) basis set. Ultraviolet-Visible (UV-Vis) spectrum was investigated by time dependent DFT (TD-DFT). Features of the electronic absorption spectrum in the UV-Visible regions were assigned based on TD-DFT calculation. The absorption bands are assigned to transitions. The interfacial electron transfer between semiconductor TiO2 electrode and dye sensitizer DACP is due to an electron injection process from excited dye to the semiconductor's conduction band. The observed and the calculated frequencies are found to be in good agreement. The energies of the frontier molecular orbitals (FMOS) have also been determined. The chemical shielding anisotropic (CSA) parameters are calculated from the NMR analysis, Stability of the molecule arising from hyperconjugative interactions and charge delocalization has been analyzed using natural bond orbital (NBO) analysis. Copyright © 2014 Elsevier B.V. All rights reserved.

High-resolution setup for measuring wavelength sensitivity of photoyellowing of translucent materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaskuri, Anna, E-mail: anna.vaskuri@aalto.fi; Kärhä, Petri; Heikkilä, Anu

2015-10-15

Polystyrene and many other materials turn yellow when exposed to ultraviolet (UV) radiation. All photodegradation mechanisms including photoyellowing are functions of the exposure wavelength, which can be described with an action spectrum. In this work, a new high-resolution transmittance measurement setup based on lasers has been developed for measuring color changes, such as the photoyellowing of translucent materials aged with a spectrograph. The measurement setup includes 14 power-stabilized laser lines between 325 nm and 933 nm wavelengths, of which one at a time is directed on to the aged sample. The power transmitted through the sample is measured with amore » silicon detector utilizing an integrating sphere. The sample is mounted on a high-resolution XY translation stage. Measurement at various locations aged with different wavelengths of exposure radiation gives the transmittance data required for acquiring the action spectrum. The combination of a UV spectrograph and the new high-resolution transmittance measurement setup enables a novel method for studying the UV-induced ageing of translucent materials with a spectral resolution of 3–8 nm, limited by the adjustable spectral bandwidth range of the spectrograph. These achievements form a significant improvement over earlier methods.« less

Accelerated Solar-UV Test Chamber

NASA Technical Reports Server (NTRS)

Gupta, A.; Laue, E. G.

1984-01-01

Medium-pressure mercury-vapor lamps provide high ratio of ultraviolet to total power. Chamber for evaluating solar-ultraviolet (UV) radiation damage permits accelerated testing without overheating test specimens.

Development and future of ultraviolet light-emitting diodes: UV-LED will replace the UV lamp

NASA Astrophysics Data System (ADS)

Muramoto, Yoshihiko; Kimura, Masahiro; Nouda, Suguru

2014-06-01

Ultraviolet light-emitting diodes (UV-LEDs) have started replacing UV lamps. The power per LED of high-power LED products has reached 12 W (14 A), which is 100 times the values observed ten years ago. In addition, the cost of these high-power LEDs has been decreasing. In this study, we attempt to understand the technologies and potential of UV-LEDs.

Ultraviolet radiation properties as applied to photoclimatherapy at the Dead Sea.

PubMed

Kudish, A I; Abels, D; Harari, M

2003-05-01

The Dead Sea basin, the lowest terrestrial point on earth, is recognized as a natural treatment center for patients with various cutaneous and rheumatic diseases. Psoriasis is the major skin disease treated at the Dead Sea with excellent improvement to complete clearance exceeding 85% after 4 weeks of treatment. These results were postulated to be associated with a unique spectrum of ultraviolet radiation present in the Dead Sea area. The UVB and UVA radiation at two sites is measured continuously by identical sets of broad-band Solar Light Co. Inc. meters (Philadelphia, PA). The spectral selectivity within the UVB and UVA spectrum was determined using a narrow-band spectroradiometer, UV-Optronics 742 (Orlando, FL). The optimum exposure time intervals for photoclimatherapy, defined as the minimum ratio of erythema to therapeutic radiation intensities, were also determined using a Solar Light Co. Inc. Microtops II, Ozone Monitor-Sunphotometer. The ultraviolet radiation at the Dead Sea is attenuated relative to Beer Sheva as a result of the increased optical path length and consequent enhanced scattering. The UVB radiation is attenuated to a greater extent than UVA and the shorter erythema UVB spectral range decreased significantly compared with the longer therapeutic UVB wavelengths. It was demonstrated that the relative attenuation within the UVB spectral range is greatest for the shorter erythema rays and less for the longer therapeutic UVB wavelengths, thus producing a greater proportion of the longer therapeutic UVB wavelengths in the ultraviolet spectrum. These measurements can be utilized to minimize the exposure to solar radiation by correlating the cumulative UVB radiation dose to treatment efficacy and by formulating a patient sun exposure treatment protocol for Dead Sea photoclimatherapy.

Prospects for Near Ultraviolet Astronomical Observations from the Lunar Surface — LUCI

NASA Astrophysics Data System (ADS)

Mathew, J.; Kumar, B.; Sarpotdar, M.; Suresh, A.; Nirmal, K.; Sreejith, A. G.; Safonova, M.; Murthy, J.; Brosch, N.

2018-04-01

We have explored the prospects for UV observations from the lunar surface and developed a UV telescope (LUCI-Lunar Ultraviolet Cosmic Imager) to put on the Moon, with the aim to detect bright UV transients such as SNe, novae, TDE, etc.

Ultraviolet Spectra of Two Magnetic White Dwarfs and Ultraviolet Spectra of Subluminous Objects Found in the Kiso Schmidt Survey and Ultraviolet Absorptions in the Spectra of DA White Dwarfds

NASA Technical Reports Server (NTRS)

Wegner, Gary A.

1988-01-01

Research under NASA Grant NAG5-287 has carried out a number of projects in conjunction with the International Ultraviolet Explorer (IUE) satellite. These include: (1) studies of the UV spectra of DA white dwarfs which show quasi-molecular bands of H2 and H2(+); (2) the peculiar star HR6560; (3) the UV spectra of two magnetic white dwarfs that also show the quasi-molecular features; (4) investigations of the UV spectra of subluminous stars, primarily identified from visual wavelength spectroscopy in the Kiso survey of UV excess stars, some of which show interesting metal lines in their UV spectra; and (5) completion of studies of UV spectra of DB stars. The main result of this research has been to further knowledge of the structure and compositions of subluminous stars which helps cast light on their formation and evolution.

Nonthermal combined ultraviolet and vacuum-ultraviolet curing process for organosilicate dielectrics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheng, H.; Guo, X.; Pei, D.

2016-06-13

Porous SiCOH films are of great interest in semiconductor fabrication due to their low-dielectric constant properties. Post-deposition treatments using ultraviolet (UV) light on organosilicate thin films are required to decompose labile pore generators (porogens) and to ensure optimum network formation to improve the electrical and mechanical properties of low-k dielectrics. The goal of this work is to choose the best vacuum-ultraviolet photon energy in conjunction with vacuum ultraviolet (VUV) photons without the need for heating the dielectric to identify those wavelengths that will have the most beneficial effect on improving the dielectric properties and minimizing damage. VUV irradiation between 8.3more » and 8.9 eV was found to increase the hardness and elastic modulus of low-k dielectrics at room temperature. Combined with UV exposures of 6.2 eV, it was found that this “UV/VUV curing” process is improved compared with current UV curing. We show that UV/VUV curing can overcome drawbacks of UV curing and improve the properties of dielectrics more efficiently without the need for high-temperature heating of the dielectric.« less

Communication using eye roll reflective signalling

USGS Publications Warehouse

Flamarique, I.N.; Mueller, G.A.; Cheng, C.L.; Figiel, C.R.

2007-01-01

Body reflections in the ultraviolet (UV) are a common occurrence in nature. Despite the abundance of such signals and the presence of UV cones in the retinas of many vertebrates, the function of UV cones in the majority of taxa remains unclear. Here, we report on an unusual communication system in the razorback sucker, Xyrauchen texanus, that involves flash signals produced by quick eye rolls. Behavioural experiments and field observations indicate that this form of communication is used to signal territorial presence between males. The flash signal shows highest contrast in the UV region of fhe visual spectrum (??max???380 nm), corresponding to the maximum wavelength of absorption of the UV cone mechanism in suckers. Furthermore, these cones are restricted to the dorsal retina of the animal and the upwelling light background is such that their relative sensitivity would be enhanced by chromatic adaptation of the other cone mechanisms. Thus, the UV cones in the sucker have optimal characteristics (both in terms of absorbance and retinal topography) to constitute the main detectors of the flash signal. Our findings provide the first ecological evidence for restricted distribution of UV cones in the retina of a vertebrate. ?? 2007 The Royal Society.

Imaging camera system of OYGBR-phosphor-based white LED lighting

NASA Astrophysics Data System (ADS)

Kobashi, Katsuya; Taguchi, Tsunemasa

2005-03-01

The near-ultraviolet (nUV) white LED approach is analogous to three-color fluorescent lamp technology, which is based on the conversion of nUV radiation to visible light via the photoluminescence process in phosphor materials. The nUV light is not included in the white light generation from nUV-based white LED devices. This technology can thus provide a higher quality of white light than the blue and YAG method. A typical device demonstrates white luminescence with Tc=3,700 K, Ra > 93, K > 40 lm/W and chromaticity (x, y) = (0.39, 0.39), respectively. The orange, yellow, green and blue OYGB) or orange, yellow, red, green and blue (OYRGB) device shows a luminescence spectrum broader than of an RGB white LED and a better color rendering index. Such superior luminous characteristics could be useful for the application of several kinds of endoscope. We have shown the excellent pictures of digestive organs in a stomach of a dog due to the strong green component and high Ra.

Berkeley extreme-ultraviolet airglow rocket spectrometer: BEARS.

PubMed

Cotton, D M; Chakrabarti, S

1992-09-20

We describe the Berkeley extreme-UV airglow rocket spectrometer, which is a payload designed to test several thermospheric remote-sensing concepts by measuring the terrestrial O I far-UV and extreme-UV dayglow and the solar extreme-UV spectrum simultaneously. The instrument consisted of two near-normal Rowland mount spectrometers and a Lyman-alpha photometer. The dayglow spectrometer covered two spectral regions from 980 to 1040 A and from 1300 to 1360 A with 1.5-A resolution. The solar spectrometer had a bandpass of 250-1150 A with an ~ 10-A resolution. All three spectra were accumulated by using a icrochannel-plate-intensified, two-dimensional imaging detector with three separate wedge-and strip anode readouts. The hydrogen Lyman-alpha photometer was included to monitor the solar Lyman-alpha irradiance and geocoronal Lyman-alpha emissions. The instrument was designed, fabricated, and calibrated at the University of California, Berkeley and was successfully launched on 30 September 1988 aboard the first test flight of a four-stage sounding rocket, Black Brant XII.

Dechlorination by ultraviolet radiation: a suitable alternative to activated carbon in dialysis water systems?

PubMed

James, Ray

2009-12-01

Chlorine-based products are widely used in the water supply industry, and the potential for adverse effects in the haemodialysis setting is well documented. To date, the most commonly used method of chlorine removal has been granular activated carbon filters. An increasingly popular method of dechlorination is the use of high intensity, broad-spectrum UV systems to reduce both free chlorine and combined chlorine compounds (chloramines) into easily removed by-products. UV radiation has been successfully used in the pharmaceutical and food industries to destroy free chlorine and/or chloramines present in water, and kill all known spoilage microorganisms including bacteria, viruses, yeasts and moulds (and their spores). This nonchemical method can offer significant advantages and benefits compared to conventional dechlorination technologies currently employed in dialysis water systems. Whilst UV treatment at 254 nm wavelength has been routinely used for disinfection purposes in dialysis water systems, this paper considers whether UV radiation can be used as an alternative to more traditional methods of chlorine removal.

The role of a generalized ultraviolet cue for blackbird food selection.

PubMed

Werner, Scott J; Tupper, Shelagh K; Carlson, James C; Pettit, Susan E; Ellis, Jeremy W; Linz, George M

2012-07-16

Birds utilize ultraviolet (UV) wavelengths for plumage signaling and sexual selection. Ultraviolet cues may also be used for the process of avian food selection. The aim of our study was to investigate whether a UV cue and a postingestive repellent can be used to condition food avoidance in red-winged blackbirds (Agelaius phoeniceus). We found that birds conditioned with an UV-absorbent, postingestive repellent subsequently avoided UV-absorbent food. Thus, the UV-absorbent cue (coupled with 0-20% of the conditioned repellent concentration) was used to maintain avoidance for up to 18 days post-conditioning. Similarly, birds conditioned with the UV-absorbent, postingestive repellent subsequently avoided UV-reflective food. Thus, conditioned avoidance of an UV-absorbent cue can be generalized to an unconditioned, UV-reflective cue for nutrient selection and toxin avoidance. These findings support the hypothesized function of UV vision for avian food selection, the implications of which remain to be explored for the sensory and behavioral ecology within agronomic and natural environments. Published by Elsevier Inc.

Detection of latent fingerprints by ultraviolet spectral imaging

NASA Astrophysics Data System (ADS)

Huang, Wei; Xu, Xiaojing; Wang, Guiqiang

2013-12-01

Spectral imaging technology research is becoming more popular in the field of forensic science. Ultraviolet spectral imaging technology is an especial part of the full spectrum of imaging technology. This paper finished the experiment contents of the ultraviolet spectrum imaging method and image acquisition system based on ultraviolet spectral imaging technology. Ultraviolet spectral imaging experiments explores a wide variety of ultraviolet reflectance spectra of the object material curve and its ultraviolet spectrum of imaging modalities, can not only gives a reference for choosing ultraviolet wavelength to show the object surface potential traces of substances, but also gives important data for the ultraviolet spectrum of imaging technology development.

Ultraviolet Imaging Telescope observations of the Crab Nebula

NASA Technical Reports Server (NTRS)

Hennessy, Gregory S.; O'Connell, Robert W.; Cheng, Kwang P.; Bohlin, Ralph C.; Collins, Nicholas R.; Gull, Theodore P.; Hintzen, Paul; Isensee, Joan E.; Landsman, Wayne B.; Roberts, Morton S.

1992-01-01

We obtained ultraviolet images of the Crab Nebula with the Ultraviolet Imaging Telescope during the Astro-1 Space Shuttle mission in 1990 December. The UV continuum morphology of the Crab is generally similar to that in the optical region, but the wispy structures are less conspicuous in the UV and X-ray. UV line emission from the thermal filaments is not strong. UV spectral index maps with a resolution of 10 arcsecs show a significant gradient across the nebula, with the outer parts being redder, as expected from synchrotron losses. The location of the bluest synchrotron continuum does not coincide with the pulsar.

UV Spectroscopy of Metallic Asteroid (16) Psyche

NASA Astrophysics Data System (ADS)

Cunningham, N. J.; Becker, T. M.; Retherford, K. D.; Roth, L.; Feaga, L. M.; Wahlund, J.-E.; Elkins-Tanton, L. T.

2017-09-01

Asteroid (16) Psyche is the largest M-type asteroid, and the planned destination of the NASA Discovery mission Psyche and the proposed ESA M5 mission Heavy Metal. Psyche is considered to be the exposed core of a differentiated asteroid, whose mantle has been stripped by collisions; but other histories have been proposed. We observed Psyche with the Space Telescope Imaging Spectrograph (STIS) and Cosmic Origins Spectrograph (COS) aboard the Hubble Space Telescope, to obtain a full ultraviolet (UV) spectrum of both of Psyche's hemispheres. We seek to test three possible scenarios for Psyche's origin: Is Psyche the exposed core of a differentiated asteroid? Is it an asteroid with high olivine content that has been space-weathered? Or did Psyche accrete as-is in a highly-reducing environment early in the history of the solar system? We will present the UV spectra and their implications for Psyche's history.

Highlights from 40 Years of Satellite UV Measurements

NASA Technical Reports Server (NTRS)

Bhartia, Pawan K.

2010-01-01

This year we are celebrating the 40th anniversary of the launch of the Backscatter Ultraviolet (BUV) instrument on NASA's Nimbus-4 satellite. The purpose of this instrument was to demonstrate the capability to measure total column ozone and its vertical distribution from space. The success of this instrument led to about a dozen instruments of this type on various NASA and NOAA satellites. These instruments used a single photomultiplier tube (PMT) that restricted the measurements to 6-12 discrete wavelengths in the 250-380 nm range. With the availability of solid-state detector arrays in the past decade it has been possible to make similar measurements but with hyperspectral (contiguous in wavelength) sampling and enhanced spectral resolution. This has allowed global mapping of several weakly-absorbing trace gases including S0 2, NO2, BrO, HCHO, and CIIOCHO. Since these measurements are affected by clouds and aerosols, a great deal of effort has gone into understanding their effect on ultraviolet radiation- both upwelling and downwelling. The downwelling UV radiation is chemically and biologically active and has both negative (genetic damage, air pollution) and positive (production of vitamin D and OH radical) environmental effects. I will discuss how the interaction of Rayleigh-scattered UV radiation with clouds and aerosols produce a variety of interesting effects that are leading to new methods of remote sensing of their properties. The UV measurements can greatly enhance the information that one derives from more traditional methods that use infrared and visible part of the solar spectrum.

Pollen and spores as biological recorders of past ultraviolet irradiance

NASA Astrophysics Data System (ADS)

Jardine, Phillip E.; Fraser, Wesley T.; Lomax, Barry H.; Sephton, Mark A.; Shanahan, Timothy M.; Miller, Charlotte S.; Gosling, William D.

2016-12-01

Solar ultraviolet (UV) irradiance is a key driver of climatic and biotic change. Ultraviolet irradiance modulates stratospheric warming and ozone production, and influences the biosphere from ecosystem-level processes through to the largest scale patterns of diversification and extinction. Yet our understanding of ultraviolet irradiance is limited because no method has been validated to reconstruct its flux over timescales relevant to climatic or biotic processes. Here, we show that a recently developed proxy for ultraviolet irradiance based on spore and pollen chemistry can be used over long (105 years) timescales. Firstly we demonstrate that spatial variations in spore and pollen chemistry correlate with known latitudinal solar irradiance gradients. Using this relationship we provide a reconstruction of past changes in solar irradiance based on the pollen record from Lake Bosumtwi in Ghana. As anticipated, variations in the chemistry of grass pollen from the Lake Bosumtwi record show a link to multiple orbital precessional cycles (19-21 thousand years). By providing a unique, local proxy for broad spectrum solar irradiance, the chemical analysis of spores and pollen offers unprecedented opportunities to decouple solar variability, climate and vegetation change through geologic time and a new proxy with which to probe the Earth system.

Research on the calibration of ultraviolet energy meters

NASA Astrophysics Data System (ADS)

Lin, Fangsheng; Yin, Dejin; Li, Tiecheng; Lai, Lei; Xia, Ming

2016-10-01

Ultraviolet (UV) radiation is a kind of non-lighting radiation with the wavelength range from 100nm to 400nm. Ultraviolet irradiance meters are now widely used in many areas. However, as the development of science and technology, especially in the field of light-curing industry, there are more and more UV energy meters or UV-integrators need to be measured. Because the structure, wavelength band and measured power intensity of UV energy meters are different from traditional UV irradiance meters, it is important for us to take research on the calibration. With reference to JJG879-2002, we SIMT have independently developed the UV energy calibration device and the standard of operation and experimental methods for UV energy calibration in detail. In the calibration process of UV energy meter, many influencing factors will affect the final results, including different UVA-band UV light sources, different spectral response for different brands of UV energy meters, instability and no uniformity of UV light source and temperature. Therefore we need to take all of these factors into consideration to improve accuracy in UV energy calibration.

Design, fabrication, and measurement of two silicon-based ultraviolet and blue-extended photodiodes

NASA Astrophysics Data System (ADS)

Chen, Changping; Wang, Han; Jiang, Zhenyu; Jin, Xiangliang; Luo, Jun

2014-12-01

Two silicon-based ultraviolet (UV) and blue-extended photodiodes are presented, which were fabricated for light detection in the ultraviolet/blue spectral range. Stripe-shaped and octagon-ring-shaped structures were designed to verify parameters of the UV-responsivity, UV-selectivity, breakdown voltage, and response time. The ultra-shallow lateral pn junction had been successfully realized in a standard 0.5-μm complementary metal oxide semiconductor (CMOS) process to enlarge the pn junction area, enhance the absorption of UV light, and improve the responsivity and quantum efficiency. The test results illustrated that the stripe-shaped structure has the lower breakdown voltage, higher UV-responsicity, and higher UV-selectivity. But the octagon-ring-shaped structure has the lower dark current. The response time of both structures was almost the same.

ULTRAVIOLET DISINFECTION OF A SECONDARY EFFLUENT: MEASUREMENT OF DOSE AND EFFECTS OF FILTRATION

EPA Science Inventory

Ultraviolet (UV) disinfection of wastewater secondary effluent was investigated in a two-phase study to develop methods for measuring UV dose and to determine the effects of filtration on UV disinfection. The first phase of this study involved a pilot plant study comparing filtra...

Some Thoughts on Teaching about Ultraviolet Radiation

ERIC Educational Resources Information Center

Thumm, Walter

1975-01-01

Describes the major obstacles in the study of ultraviolet radiation (UV). Presents the beneficial aspects of UV such as vitamin O production, sterilization, clinical treatment of diseases and wounds, and the marking of patients for radiotherapy. Warns of the dangers of UV exposure such as skin cancer and early aging. (GS)

The ever-surprising blazar OJ 287: multi-wavelength study and appearance of a new component in X-rays

NASA Astrophysics Data System (ADS)

Kushwaha, Pankaj; Gupta, Alok C.; Wiita, Paul J.; Pal, Main; Gaur, Haritma; de Gouveia Dal Pino, E. M.; Kurtanidze, O. M.; Semkov, E.; Damljanovic, G.; Hu, S. M.; Uemura, M.; Vince, O.; Darriba, A.; Gu, M. F.; Bachev, R.; Chen, Xu; Itoh, R.; Kawabata, M.; Kurtanidze, S. O.; Nakaoka, T.; Nikolashvili, M. G.; Sigua, L. A.; Strigachev, A.; Zhang, Z.

2018-06-01

We present a multi-wavelength spectral and temporal investigation of OJ 287 emission during its strong optical-to-X-ray activity between July 2016 - July 2017. The daily γ-ray fluxes from Fermi-LAT are consistent with no variability. The strong optical-to-X-ray variability is accompanied by a change in power-law spectral index of the X-ray spectrum from <2 to >2, with variations often associated with changes in optical polarization properties. Cross-correlations between optical-to-X-ray emission during four continuous segments show simultaneous optical-ultraviolet (UV) variations while the X-ray and UV/optical are simultaneous only during the middle two segments. In the first segment, the results suggest X-rays lag the optical/UV, while in the last segment X-rays lead by ˜ 5-6 days. The last segment also shows a systematic trend with variations appearing first at higher energies followed by lower energy ones. The LAT spectrum before the VHE activity is similar to preceding quiescent state spectrum while it hardens during VHE activity period and is consistent with the extrapolated VHE spectrum during the latter. Overall, the broadband spectral energy distributions (SEDs) during high activity periods are a combination of a typical OJ 287 SED and an HBL SED, and can be explained in a two-zone leptonic model, with the second zone located at parsec scales, beyond the broad line region, being responsible for the HBL-like spectrum. The change of polarization properties from systematic to chaotic and back to systematic, before, during and after the VHE activity, suggest dynamic roles for magnetic fields and turbulence.

The research on a novel type of the solar-blind UV head-mounted displays

NASA Astrophysics Data System (ADS)

Zhao, Shun-long

2011-08-01

Ultraviolet technology of detecting is playing a more and more important role in the field of civil application, especially in the corona discharge detection, in modern society. Now the UV imaging detector is one of the most important equipments in power equipment flaws detection. And the modern head-mounted displays (HMDs) have shown the applications in the fields of military, industry production, medical treatment, entertainment, 3D visualization, education and training. We applied the system of head-mounted displays to the UV image detection, and a novel type of head-mounted displays is presented: the solar-blind UV head-mounted displays. And the structure is given. By the solar-blind UV head-mounted displays, a real-time, isometric and visible image of the corona discharge is correctly displayed upon the background scene where it exists. The user will see the visible image of the corona discharge on the real scene rather than on a small screen. Then the user can easily find out the power equipment flaws and repair them. Compared with the traditional UV imaging detector, the introducing of the HMDs simplifies the structure of the whole system. The original visible spectrum optical system is replaced by the eye in the solar-blind UV head-mounted displays. And the optical image fusion technology would be used rather than the digital image fusion system which is necessary in traditional UV imaging detector. That means the visible spectrum optical system and digital image fusion system are not necessary. This makes the whole system cheaper than the traditional UV imaging detector. Another advantage of the solar-blind UV head-mounted displays is that the two hands of user will be free. So while observing the corona discharge the user can do some things about it. Therefore the solar-blind UV head-mounted displays can make the corona discharge expose itself to the user in a better way, and it will play an important role in corona detection in the future.

UV-Vis, infrared, and mass spectroscopy of electron irradiated frozen oxygen and carbon dioxide mixtures with water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, Brant M.; Kaiser, Ralf I.; Strazzulla, Giovanni

2014-02-01

Ozone has been detected on the surface of Ganymede via observation of the Hartley band through the use of ultraviolet spectroscopy and is largely agreed upon to be formed by radiolytic processing via interaction of magnetospheric energetic ions and/or electrons with oxygen-bearing ices on Ganymede's surface. Interestingly, a clearly distinct band near 300 nm within the shoulder of the UV-Vis spectrum of Ganymede was also observed, but currently lacks an acceptable physical or chemical explanation. Consequently, the primary motivation behind this work was the collection of UV-Vis absorption spectroscopy of ozone formation by energetic electron bombardment of a variety ofmore » oxygen-bearing ices (oxygen, carbon dioxide, water) relevant to this moon as well as other solar system. Ozone was indeed synthesized in pure ices of molecular oxygen, carbon dioxide and a mixture of water and oxygen, in agreement with previous studies. The Hartley band of the ozone synthesized in these ice mixtures was observed in the UV-Vis spectra and compared with the spectrum of Ganymede. In addition, a solid state ozone absorption cross section of 6.0 ± 0.6 × 10{sup –17} cm{sup 2} molecule{sup –1} was obtained from the UV-Vis spectral data. Ozone was not produced in the irradiated carbon dioxide-water mixtures; however, a spectrally 'red' UV continuum is observed and appears to reproduce well what is observed in a large number of icy moons such as Europa.« less

Dynamic interferometer alignment and its utility in UV Fourier transform spectrometer systems

NASA Technical Reports Server (NTRS)

Dorval, Rick K.; Engel, James R.; Wyntjes, Geert J.

1993-01-01

Dynamic alignment has been demonstrated as a practical approach to alignment maintenance for systems in the infrared region of the spectrum. On the basis of work done by OPTRA, this technique was introduced in commercial Fourier transform spectrometer systems in 1982 and in various forms is now available from a number of manufacturers. This paper reports on work by OPTRA to extend the basic technique to systems operating in the ultraviolet. In addition, this paper reports the preliminary results of the development of an alignment system using a laser diode in place of a gas laser normally found in dynamic alignment systems. A unique optical system and spatial heterodyne technique allows for achievement of a metrology system with characteristics that fully satisfy the requirements of an ultraviolet spectrometer system.

Ultraviolet and X-ray Variability of the Seyfert 1.5 Galaxy Markarian 817

NASA Astrophysics Data System (ADS)

Winter, Lisa M.; Danforth, Charles; Vasudevan, Ranjan; Brandt, W. N.; Scott, Jennifer; Froning, Cynthia; Keeney, Brian; Shull, J. Michael; Penton, Steve; Mushotzky, Richard; Schneider, Donald P.; Arav, Nahum

2011-02-01

We present an investigation of the ultraviolet and X-ray spectra of the Seyfert 1.5 galaxy Markarian 817. The ultraviolet analysis includes two recent observations taken with the Cosmic Origins Spectrograph (COS) in 2009 August and December, as well as archival spectra from the International Ultraviolet Explorer and the Hubble Space Telescope. Twelve Lyα absorption features are detected in the 1997 Goddard High Resolution Spectrograph (GHRS) and 2009 COS spectra—of these, four are associated with high-velocity clouds in the interstellar medium, four are at low significance, and the remaining four are intrinsic features, which vary between the GHRS and COS observations. The strongest intrinsic absorber in the 1997 spectrum has a systemic velocity of ~-4250 km s-1. The corresponding feature in the COS data is five times weaker than the GHRS absorber. The three additional weak (equivalent width from 13 to 54 mÅ) intrinsic Lyα absorbers are at systemic velocities of -4100 km s-1, -3550 km s-1, and -2600 km s-1. However, intrinsic absorption troughs from highly ionized C IV and N V are not detected in the COS observations. No ionized absorption signatures are detected in the ~14 ks XMM-Newton EPIC spectra. The factor of five change in the intrinsic Lyα absorber is most likely due to bulk motions in the absorber, since there is no drastic change in the UV luminosity of the source from the GHRS to the COS observations. In a study of the variability of Mrk 817, we find that the X-ray luminosity varies by a factor of ~40 over 20 years, while the UV continuum/emission lines vary by at most a factor of ~2.3 over 30 years. The variability of the X-ray luminosity is strongly correlated with the X-ray power-law index, but no correlation is found with the simultaneous optical/UV photometry.

Measurements of cavity ringdown spectroscopy of acetone in the ultraviolet and near-infrared spectral regions: potential for development of a breath analyzer.

PubMed

Wang, Chuji; Scherrer, Susan T; Hossain, Delwar

2004-07-01

We report a study on the cavity ringdown spectroscopy of acetone in both the ultraviolet (UV) and the near-infrared (NIR) spectral regions to explore the potential for development of a breath analyzer for disease diagnostics. The ringdown spectrum of acetone in the UV (282.4-285.0 nm) region is recorded and the spectrum is in good agreement with those obtained by other spectral techniques reported in the literature. The absorption cross-section of the C-H stretching overtone of acetone in the NIR (1632.7-1672.2 nm) is reported for the first time and the maximum absorption cross-section located at 1666.7 nm is 1.2 x 10(-21) cm(2). A novel, compact, atmospheric cavity with a cavity length of 10 cm has been constructed and implemented to investigate the technical feasibility of the potential instrument size, optical configuration, and detection sensitivity. The detection limit of such a mini cavity employing ringdown mirrors of reflectivity of 99.85% at 266 nm, where acetone has the strongest absorption, is approximately 1.5 ppmv based on the standard 3 criteria. No real breath gas samples are used in the present study. Discussions on the detection sensitivity and background spectral interferences for the instrument development are presented. This study demonstrates the potential of developing a portable, sensitive breath analyzer for medical applications using the cavity ringdown spectral technique.

The Effects of Space Weathering at UV Wavelengths: S-Class Asteroids

NASA Technical Reports Server (NTRS)

Hendrix, Amanda R.; Vilas, Faith

2006-01-01

We present evidence that space weathering manifests itself at near-UV wavelengths as a bluing of the spectrum, in contrast with the spectral reddening that has been seen at visible-near-IR wavelengths. Furthermore, the effects of space weathering at UV wavelengths tend to appear with less weathering than do the longer wavelength effects, suggesting that the UV wavelength range is a more sensitive indicator of weathering, and thus age. We report results from analysis of existing near-UV (approx.220-350 nm) measurements of S-type asteroids from the International Ultraviolet Explorer and the Hubble Space Telescope and comparisons with laboratory measurements of meteorites to support this hypothesis. Composite spectra of S asteroids are produced by combining UV spacecraft data with ground-based longer wavelength data. At visible-near-IR wavelengths, S-type asteroids are generally spectrally redder (and darker) than ordinary chondrite meteorites, whereas the opposite is generally true at near-UV wavelengths. Similarly, laboratory measurements of lunar samples show that lunar soils (presumably more weathered) are spectrally redder at longer wavelengths, and spectrally bluer at near-UV wavelengths, than less weathered crushed lunar rocks. The UV spectral bluing may be a result of the addition of nanophase iron to the regolith through the weathering process. The UV bluing is most prominent in the 300-400 nm range, where the strong UV absorption edge is degraded with weathering.

Testing Of An Ultraviolet (UV)-Transparent Polymer-Based Passive Sampler for Rapid, Ultra-Low-Cost EDC Screening Applications

EPA Science Inventory

A new passive sampling method with rapid low-cost spectral detection has recently been developed. The method makes use of an ultraviolet (UV)-transparent polymer which serves as both a concentrator for dissolved compounds, and an optical cell for UV spectral detection. Because ...

Protective mechanisms and acclimation to solar ultraviolet-B radiation in Oenothera stricta

NASA Technical Reports Server (NTRS)

Robberecht, R.; Caldwell, M. M.

1981-01-01

Plant adaptations ameliorating or repairing the damaging effects of ultraviolet-B (UV-B) radiation on plant tissue were investigated. The degree of phenotype plasticity in UV protective mechanisms and acclimation in relation to the natural solar UV-B radiation flux and in an enhanced UV-B irradiance environment was also examined. Mechanisms by which plants avoid radiation, adaptations altering the path of radiation incident on the leaf, and repair processes were considered. Attenuation of UV-B by tissues, UV-B irradiation into the leaf, and the effects of UV-B on photosynthesis were investigated.

Stellar Laboratories II. New Zn Iv and Zn v Oscillator Strengths and Their Validation in the Hot White Dwarfs G191-B2B and RE0503-289

NASA Technical Reports Server (NTRS)

Rauch, T.; Werner, K.; Quinet, P.; Kruk, J. W.

2014-01-01

Context. For the spectral analysis of high-resolution and high-signal-to-noise (SN) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. In a recent analysis of the ultraviolet (UV) spectrum of the DA-type white dwarf G191B2B,21 Zn iv lines were newly identified. Because of the lack of Zn iv data, transition probabilities of the isoelectronic Ge vi were adapted for a first, coarse determination of the photospheric Zn abundance.Aims. Reliable Zn iv and Zn v oscillator strengths are used to improve the Zn abundance determination and to identify more Zn lines in the spectra of G191B2B and the DO-type white dwarf RE 0503289. Methods. We performed new calculations of Zn iv and Zn v oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of the Zn iv v spectrum exhibited in high-resolution and high-SN UV observations of G191B2B and RE 0503289. Results. In the UV spectrum of G191B2B, we identify 31 Zn iv and 16 Zn v lines. Most of these are identified for the first time in any star. We can reproduce well almost all of them at log Zn 5.52 0.2 (mass fraction, about 1.7 times solar). In particular, the Zn iv Zn v ionization equilibrium, which is a very sensitive Teff indicator, is well reproduced with the previously determined Teff 60 000 2000 K and log g 7.60 0.05. In the spectrum of RE 0503289, we identified 128 Zn v lines for the first time and determined log Zn 3.57 0.2 (155 times solar). Conclusions. Reliable measurements and calculations of atomic data are a pre-requisite for stellar-atmosphere modeling. Observed Zn iv and Zn v line profiles in two white dwarf (G191B2B and RE 0503289) ultraviolet spectra were well reproduced with our newly calculated oscillator strengths. This allowed us to determine the photospheric Zn abundance of these two stars precisely.

Ultraviolet spectra of extreme nearby star-forming regions - approaching a local reference sample for JWST

NASA Astrophysics Data System (ADS)

Senchyna, Peter; Stark, Daniel P.; Vidal-García, Alba; Chevallard, Jacopo; Charlot, Stéphane; Mainali, Ramesh; Jones, Tucker; Wofford, Aida; Feltre, Anna; Gutkin, Julia

2017-12-01

Nearby dwarf galaxies provide a unique laboratory in which to test stellar population models below Z⊙/2. Such tests are particularly important for interpreting the surprising high-ionization ultraviolet (UV) line emission detected at z > 6 in recent years. We present HST/COS UV spectra of 10 nearby metal-poor star-forming galaxies selected to show He II emission in SDSS optical spectra. The targets span nearly a dex in gas-phase oxygen abundance (7.8 < 12 + log O/H < 8.5) and present uniformly large specific star formation rates (sSFR ∼102 Gyr-1). The UV spectra confirm that metal-poor stellar populations can power extreme nebular emission in high-ionization UV lines, reaching C III] equivalent widths comparable to those seen in systems at z ∼ 6-7. Our data reveal a marked transition in UV spectral properties with decreasing metallicity, with systems below 12 + log O/H ≲ 8.0 (Z/Z⊙ ≲ 1/5) presenting minimal stellar wind features and prominent nebular emission in He II and C IV. This is consistent with nearly an order of magnitude increase in ionizing photon production beyond the He+-ionizing edge relative to H-ionizing flux as metallicity decreases below a fifth solar, well in excess of standard stellar population synthesis predictions. Our results suggest that often-neglected sources of energetic radiation such as stripped binary products and very massive O-stars produce a sharper change in the ionizing spectrum with decreasing metallicity than expected. Consequently, nebular emission in C IV and He II powered by these stars may provide useful metallicity constraints in the reionization era.

The effect of stellar evolution uncertainties on the rest-frame ultraviolet stellar lines of C IV and He II in high-redshift Lyman-break galaxies

NASA Astrophysics Data System (ADS)

Eldridge, John J.; Stanway, Elizabeth R.

2012-01-01

Young, massive stars dominate the rest-frame ultraviolet (UV) spectra of star-forming galaxies. At high redshifts (z > 2), these rest-frame UV features are shifted into the observed-frame optical and a combination of gravitational lensing, deep spectroscopy and spectral stacking analysis allows the stellar population characteristics of these sources to be investigated. We use our stellar population synthesis code Binary Population and Spectral Synthesis (BPASS) to fit two strong rest-frame UV spectral features in published Lyman-break galaxy spectra, taking into account the effects of binary evolution on the stellar spectrum. In particular, we consider the effects of quasi-homogeneous evolution (arising from the rotational mixing of rapidly rotating stars), metallicity and the relative abundance of carbon and oxygen on the observed strengths of He IIλ1640 Å and C IVλ1548, 1551 Å spectral lines. We find that Lyman-break galaxy spectra at z ˜ 2-3 are best fitted with moderately sub-solar metallicities, and with a depleted carbon-to-oxygen ratio. We also find that the spectra of the lowest metallicity sources are best fitted with model spectra in which the He II emission line is boosted by the inclusion of the effect of massive stars being spun-up during binary mass transfer so these rapidly rotating stars experience quasi-homogeneous evolution.

[A new method for the preparation of potassium ferrate and spectroscopic characterization].

PubMed

Zheng, Huai-li; Deng, Lin-li; Ji, Fang-ying; Jiang, Shao-jie; Zhang, Peng

2010-10-01

Calcium hypochlorite was used as the raw material for preparation of the high purity potassium ferrate. The study includes the effects of reaction temperature, recrystallization temperature, reaction time, Ca(ClO)2 dosage, and the amount of calcium hypochlorite on the yield. It was determined that when the reaction temperature was 25 degrees C, recrystallization temperature 0 degree C and reaction time 40 min, the yield was more than 75%. The purity was detected by direct spectrophotometric method to be more than 92%. The product was characterized by infrated spectrum(IR), X-ray diffraction (XRD) and ultraviolet spectrum (UV) methods and proved to be potassium ferrate that was prepared by calcium hypochlorite as the raw material.

Ultraviolet radiation changes

NASA Technical Reports Server (NTRS)

Mckenzie, Richard L.; Frederick, John E.; Ilyas, Mohammad; Filyushkin, V.; Wahner, Andreas; Stamnes, K.; Muthusubramanian, P.; Blumthaler, M.; Roy, Colin E.; Madronich, Sasha

1991-01-01

A major consequence of ozone depletion is an increase in solar ultraviolet (UV) radiation received at the Earth's surface. This chapter discusses advances that were made since the previous assessment (World Meteorological Organization (WMO)) to our understanding of UV radiation. The impacts of these changes in UV on the biosphere are not included, because they are discussed in the effects assessment.

Ultraviolet emissions from the upper atmospheres of the planets

NASA Technical Reports Server (NTRS)

Moos, H. W.

1981-01-01

Some recent results on planetary upper atmospheres obtained by means of orbiting ultraviolet observatories are reviewed with emphasis on Jupiter and Io torus. Consideration is given to long-term variation in Jovian Ly alpha emission, UV polar auroras on Jupiter, and UV emission from the Io torus. Requirements for UV planetary astronomy are briefly discussed.

Importance of biologically active aurora-like ultraviolet emission: stochastic irradiation of Earth and Mars by flares and explosions.

PubMed

Smith, David S; Scalo, John; Wheeler, J Craig

2004-10-01

Habitable planets will be subject to intense sources of ionizing radiation and fast particles from a variety of sources--from the host star to distant explosions--on a variety of timescales. Monte Carlo calculations of high-energy irradiation suggest that the surfaces of terrestrial-like planets with thick atmospheres (column densities greater than about 100 g cm(-2)) are well protected from directly incident X-rays and gamma-rays, but we find that sizeable fractions of incident ionizing radiation from astrophysical sources can be redistributed to biologically and chemically important ultraviolet wavelengths, a significant fraction of which can reach the surface. This redistribution is mediated by secondary electrons, resulting from Compton scattering and X-ray photoabsorption, the energies of which are low enough to excite and ionize atmospheric molecules and atoms, resulting in a rich aurora-like spectrum. We calculate the fraction of energy redistributed into biologically and chemically important wavelength regions for spectra characteristic of stellar flares and supernovae using a Monte-Carlo transport code and then estimate the fraction of this energy that is transmitted from the atmospheric altitudes of redistribution to the surface for a few illustrative cases. For atmospheric models corresponding to the Archean Earth, we assume no significant ultraviolet absorbers, only Rayleigh scattering, and find that the fraction of incident ionizing radiation that is received at the surface in the form of redistributed ultraviolet in the biologically relevant 200-320 nm region (UV-C and UV-B bands) can be up to 4%. On the present-day Earth with its ultraviolet ozone shield, this fraction is found to be 0.2%. Both values are many orders of magnitude higher than the fraction of direct ionizing radiation reaching the surface. This result implies that planetary organisms will be subject to mutationally significant, if intermittent, fluences of UV-B and harder radiation even in the presence of a narrow-band ultraviolet shield like ozone. We also calculate the surficial transmitted fraction of ionizing radiation and redistributed ultraviolet radiation for two illustrative evolving Mars atmospheres whose initial surface pressures were 1 bar. We discuss the frequency with which redistributed ultraviolet flux from parent star flares exceeds the parent star ultraviolet flux at the planetary surface. We find that the redistributed ultraviolet from parent star flares is probably a fairly rare intermittent event for habitable zone planets orbiting solar-type stars except when they are young, but should completely dominate the direct steady ultraviolet radiation from the parent star for planets orbiting all stars less massive than about 0.5 solar masses. Our results suggest that coding organisms on such planets (and on the early Earth) may evolve very differently than on contemporary Earth, with diversity and evolutionary rate controlled by a stochastically varying mutation rate and frequent hypermutation episodes.

UV-POSIT: Web-Based Tools for Rapid and Facile Structural Interpretation of Ultraviolet Photodissociation (UVPD) Mass Spectra

NASA Astrophysics Data System (ADS)

Rosenberg, Jake; Parker, W. Ryan; Cammarata, Michael B.; Brodbelt, Jennifer S.

2018-04-01

UV-POSIT (Ultraviolet Photodissociation Online Structure Interrogation Tools) is a suite of web-based tools designed to facilitate the rapid interpretation of data from native mass spectrometry experiments making use of 193 nm ultraviolet photodissociation (UVPD). The suite includes four separate utilities which assist in the calculation of fragment ion abundances as a function of backbone cleavage sites and sequence position; the localization of charge sites in intact proteins; the calculation of hydrogen elimination propensity for a-type fragment ions; and mass-offset searching of UVPD spectra to identify unknown modifications and assess false positive fragment identifications. UV-POSIT is implemented as a Python/Flask web application hosted at http://uv-posit.cm.utexas.edu. UV-POSIT is available under the MIT license, and the source code is available at https://github.com/jarosenb/UV_POSIT. [Figure not available: see fulltext.

UV-POSIT: Web-Based Tools for Rapid and Facile Structural Interpretation of Ultraviolet Photodissociation (UVPD) Mass Spectra.

PubMed

Rosenberg, Jake; Parker, W Ryan; Cammarata, Michael B; Brodbelt, Jennifer S

2018-06-01

UV-POSIT (Ultraviolet Photodissociation Online Structure Interrogation Tools) is a suite of web-based tools designed to facilitate the rapid interpretation of data from native mass spectrometry experiments making use of 193 nm ultraviolet photodissociation (UVPD). The suite includes four separate utilities which assist in the calculation of fragment ion abundances as a function of backbone cleavage sites and sequence position; the localization of charge sites in intact proteins; the calculation of hydrogen elimination propensity for a-type fragment ions; and mass-offset searching of UVPD spectra to identify unknown modifications and assess false positive fragment identifications. UV-POSIT is implemented as a Python/Flask web application hosted at http://uv-posit.cm.utexas.edu . UV-POSIT is available under the MIT license, and the source code is available at https://github.com/jarosenb/UV_POSIT . Graphical Abstract.

Investigation of magnesium fluoride crystals for imaging acousto-optic tunable filter applications.

PubMed

Voloshinov, Vitaly B; Gupta, Neelam

2006-05-01

Results of an investigation of acousto-optic (AO) cells using single crystals of magnesium fluoride (MgF2) are presented. Two acousto-optic tunable filter (AOTF) cells for imaging application have been designed and tested in the visible and ultraviolet (UV) regions of the spectrum from 190 to 490 nm. The two imaging filters were developed by using the wide-angle AO interaction geometry in the (010) and (11 0) planes of the crystal. These filters were used to obtain spectral images at the shortest wavelengths achieved so far. Advantages and drawbacks of this crystal are discussed and photoelastic, acoustic, and AO properties of MgF2 are examined. The investigation confirmed that MgF2-based AOTF cells can be used in the deep UV region up to 110 nm.

The Lyman Imaging Telescope Experiment (LITE)

NASA Technical Reports Server (NTRS)

Siegmund, O. H. W.

1997-01-01

The scientific aim of the LITE mission is to carry out the first set of very high spatial resolution (0.2 arc sec), wide field of view (10 arc minute), pointed astronomical observations in several narrow wavelength bands in the far ultraviolet region of the spectrum (900-1600 A). Two wavelength regions in the far UV were chosen to be of prime scientific importance for the LITE mission: 1030A and 1240A. It was therefore decided to design and test novel, narrow band, high reflectance multilayer filters for these observations.

Optical, IUE, and ROSAT observations of the eclipsing nova-like variable V347 Puppis (LB 1800)

NASA Technical Reports Server (NTRS)

Mauche, Christopher W.; Raymond, John C.; Buckley, David A. H.; Mouchet, Martine; Bonnell, Jerry; Sullivan, Denis J.; Bonnet-Bidaud, Jean-Marc; Bunk, Wolfram H.

1994-01-01

Using time-resolved optical spectroscopy and UBVRI and high-speed photometry obtained at Mount Stromlo Observatory, Mount John University Observatory, and the South African Astronomical Observatory; International Ultraviolet Explorer (IUE) ultraviolet spectroscopy; and Roentgen Satellite (ROSAT) survey X-ray fluxes, we present a study of the accretion disk, hot spot, and emission line regions in the bright eclipsing nova-like variable V347 Pup (LB 1800). In the optical and UV, V347 Pup is a strong emission line source with a continuum spectrum which is remarkably red for a high-M cataclysmic variable. Consistent with its high inclination, we interpret the continuum spectrum as the superposition of the spectrum of the cool (T(sub eff) approximately 7000 K) outer edge and the hot (T(sub eff) approximately 100,000 K) inner regions of a self-eclipsed accretion disk. For the assumed parameters, the model matches the level and shape of the observed spectrum for an inclination of approximately 88 and a distance of approximately 300 pc. The prominent hump in the optical and UV light curves just before eclipse manifests the presence of the hot spot where the accretion stream strikes the edge of the disk. The wavelength dependence of the amplitude of the hump is best modeled by a spot having an effective temperature of approximately 25,000 K and an area of approximately 3 x 10(exp 18) sq cm if the spot radiates like a blackbody, or an effective temperatue of approximately 14,000 K and an area of approximately 3 x 10(exp 19) sq cm if it radiates with a stellar spectrum. In either case, the hot spot produces only one-tenth of the predicted luminosity for the assumed mass-transfer rate of 10(exp -8) solar mass/yr. Either the hot spot is 'buried' in the edge of the accretion disk, or a significant fraction of its luminosity is radiated away in lines. The difference in azimuth between the peak of the hump and the dynamically expected location of the hot spot suggests that the spot's emitting surface is rotated forward by approximately 36 deg relative to the edge of the disk.

Optical, IUE, and ROSAT observations of the eclipsing nova-like variable V347 Puppis (LB 1800)

NASA Astrophysics Data System (ADS)

Mauche, Christopher W.; Raymond, John C.; Buckley, David A. H.; Mouchet, Martine; Bonnell, Jerry; Sullivan, Denis J.; Bonnet-Bidaud, Jean-Marc; Bunk, Wolfram H.

1994-03-01

Using time-resolved optical spectroscopy and UBVRI and high-speed photometry obtained at Mount Stromlo Observatory, Mount John University Observatory, and the South African Astronomical Observatory; International Ultraviolet Explorer (IUE) ultraviolet spectroscopy; and Roentgen Satellite (ROSAT) survey X-ray fluxes, we present a study of the accretion disk, hot spot, and emission line regions in the bright eclipsing nova-like variable V347 Pup (LB 1800). In the optical and UV, V347 Pup is a strong emission line source with a continuum spectrum which is remarkably red for a high-M cataclysmic variable. Consistent with its high inclination, we interpret the continuum spectrum as the superposition of the spectrum of the cool (Teff approximately 7000 K) outer edge and the hot (Teff approximately 100,000 K) inner regions of a self-eclipsed accretion disk. For the assumed parameters, the model matches the level and shape of the observed spectrum for an inclination of approximately 88 and a distance of approximately 300 pc. The prominent hump in the optical and UV light curves just before eclipse manifests the presence of the hot spot where the accretion stream strikes the edge of the disk. The wavelength dependence of the amplitude of the hump is best modeled by a spot having an effective temperature of approximately 25,000 K and an area of approximately 3 x 1018 sq cm if the spot radiates like a blackbody, or an effective temperatue of approximately 14,000 K and an area of approximately 3 x 1019 sq cm if it radiates with a stellar spectrum. In either case, the hot spot produces only one-tenth of the predicted luminosity for the assumed mass-transfer rate of 10-8 solar mass/yr. Either the hot spot is 'buried' in the edge of the accretion disk, or a significant fraction of its luminosity is radiated away in lines. The difference in azimuth between the peak of the hump and the dynamically expected location of the hot spot suggests that the spot's emitting surface is rotated forward by approximately 36 deg relative to the edge of the disk.

DNA's Encounter with Ultraviolet Light: An Instinct for Self-Preservation?

PubMed

Barlev, Adam; Sen, Dipankar

2018-02-20

Photochemical modification is the major class of environmental damage suffered by DNA, the genetic material of all free-living organisms. Photolyases are enzymes that carry out direct photochemical repair (photoreactivation) of covalent pyrimidine dimers formed in DNA from exposure to ultraviolet light. The discovery of catalytic RNAs in the 1980s led to the "RNA world hypothesis", which posits that early in evolution RNA or a similar polymer served both genetic and catalytic functions. Intrigued by the RNA world hypothesis, we set out to test whether a catalytic RNA (or a surrogate, a catalytic DNA) with photolyase activity could be contemplated. In vitro selection from a random-sequence DNA pool yielded two DNA enzymes (DNAzymes): Sero1C, which requires serotonin as an obligate cofactor, and UV1C, which is cofactor-independent and optimally uses light of 300-310 nm wavelength to repair cyclobutane thymine dimers within a gapped DNA substrate. Both Sero1C and UV1C show multiple turnover kinetics, and UV1C repairs its substrate with a quantum yield of ∼0.05, on the same order as the quantum yields of certain classes of photolyase enzymes. Intensive study of UV1C has revealed that its catalytic core consists of a guanine quadruplex (G-quadruplex) positioned proximally to the bound substrate's thymine dimer. We hypothesize that electron transfer from photoexcited guanines within UV1C's G-quadruplex is responsible for substrate photoreactivation, analogous to electron transfer to pyrimidine dimers within a DNA substrate from photoexcited flavin cofactors located within natural photolyase enzymes. Though the analogy to evolution is necessarily limited, a comparison of the properties of UV1C and Sero1C, which arose out of the same in vitro selection experiment, reveals that although the two DNAzymes comparably accelerate the rate of thymine dimer repair, Sero1C has a substantially broader substrate repertoire, as it can repair many more kinds of pyrimidine dimers than UV1C. Therefore, the co-opting of an amino acid-like cofactor by a nucleic acid enzyme in this case contributes functional versatility rather than a greater rate enhancement. In recent work on UV1C, we have succeeded in shifting its action spectrum from the UVB into the blue region of the spectrum and determined that although it catalyzes both repair and de novo formation of thymine dimers, UV1C is primarily a catalyst for thymine dimer repair. Our work on photolyase DNAzymes has stimulated broader questions about whether analogous, purely nucleotide-based photoreactivation also occurs in double-helical DNA, the dominant form of DNA in living cells. Recently, a number of different groups have reported that this kind of repair is indeed operational in DNA duplexes, i.e., that there exist nucleotide sequences that actively protect, by way of photoreactivation (rather than by simply preventing their formation), pyrimidine dimers located proximal to them. Nucleotide-based photoreactivation thus appears to be a salient, if unanticipated, property of DNA and RNA. The phenomenon also offers pointers in the direction of how in primordial evolution-in an RNA world-early nucleic acids may have protected themselves from structural and functional damage wrought by ultraviolet light.

Soft Ultraviolet (UV) Photopatterning and Metallization of Self-Assembled Monolayers (SAMs) Formed from the Lipoic Acid Ester of α-Hydroxy-1-acetylpyrene: The Generality of Acid-Catalyzed Removal of Thiol-on-Gold SAMs using Soft UV Light.

PubMed

Pukenas, Laurynas; Prompinit, Panida; Nishitha, Boda; Tate, Daniel J; Singh, N D Pradeep; Wälti, Christoph; Evans, Stephen D; Bushby, Richard J

2017-05-31

Under a layer of 0.1 M HCl in isopropanol, soft ultraviolet (UV) (365 nm) photolysis of the thiol-on-gold self-assembled monolayer (SAM) derived from the lipoic acid ester of α-hydroxy-1-acetylpyrene results in the expected removal of the acetylpyrene protecting group. When photolyzing through a mask, this can be used to produce a patterned surface and, at a controlled electrochemical potential, it is then possible to selectively and reversibly electrodeposit copper on the photolyzed regions. Rather surprisingly, under these photolysis conditions, there is not only the expected photodeprotection of the ester but also partial removal of the lipoic acid layer which has been formed. In further studies, it is shown that this type of acid-catalyzed photoremoval of SAM layers by soft UV is a rather general phenomenon and results in the partial removal of the thiol-on-gold SAM layers derived from other ω-thiolated carboxylic acids. However, this phenomenon is chain-length dependent. Under conditions in which there is a ∼60% reduction in the thickness of the SAM derived from dithiobutyric acid, the SAM derived from mercaptoundecanoic acid is almost unaffected. The process by which the shorter-chain SAM layers are partially removed is not fully understood because these compounds do not absorb significantly in the 365 nm region of the spectrum! Significantly, this study shows that acid catalysis photolysis of thiol-on-gold SAMs needs to be used with caution.

UV-visible-NIR light generation through frequency upconversion in Tm3+-doped low silica calcium aluminosilicate glasses using multiple excitation around 1.2 μm

NASA Astrophysics Data System (ADS)

Trindade, C. M.; Rego-Filho, F. G.; Astrath, N. G. C.; Jacinto, C.; Gouveia-Neto, A. S.

2018-04-01

Intense ultraviolet upconversion emission was produced in single Tm3+-doped OH--free low silica calcium aluminosilicate glasses. A new excitation route based upon multi-Stokes Raman emissions generated in an optical fiber pumped at 1.064 μm, and exploiting the absorption band around 1.2 μm by means of the 3H5 thulium excited state, was used. Furthermore, the other bands of the stimulated Raman scattering spectrum resonantly enhances all the upconversion processes, resulting in efficient ultraviolet (295 nm, 360 nm), blue (456 nm, 480 nm), red (650 nm, 667 nm), and near-infrared (800 nm) emissions. The population of the 1P0, 1D2, 1G4, 3F2 and 3H4 excited-state emitting levels was accomplished through stepwise multi-photon absorption. Results indicate competing cross-relaxation processes involving Tm3+ ion-pairs producing UV emission population quenching Simplified energy-level diagram of Tm3+- doped sample excited using multi-stokes emissions. The λp indication describes all excitation wavelengths, represented by a single arrow for the sake of simplicity.

The Role of Optical Radiations in Skin Cancer

PubMed Central

Palla, Marco; Di Trolio, Rossella; Mozzillo, Nicola; Ascierto, Paolo A.

2013-01-01

Purpose. Electromagnetic radiation with wavelength in the range 100 nm to 1 mm is known as optical radiation and includes ultraviolet radiation, the visible spectrum, and infrared radiation. The deleterious short- and long-term biological effects of ultraviolet radiation, including melanoma and other skin cancers, are well recognized. Infrared radiation may also have damaging biological effects. Methods. The objective of this review was to assess the literature over the last 15 years and to summarize correlations between exposure to optical radiation and the risk of melanoma and other cancers. Results. There is a clear correlation between exposure to UV radiation and the development of skin cancer. Most importantly, a strong association between artificial UV radiation exposure, for example, tanning devices, and the risk of melanoma and squamous cell carcinoma has been clearly demonstrated. There is no clear evidence that exposure to IR and laser radiation may increase the risk of skin cancer, although negative health effects have been observed. Conclusions. Preventative strategies that involve provision of public information highlighting the risks associated with exposure to sunlight remain important. In addition, precautionary measures that discourage exposure to tanning appliances are required, as is legislation to prevent their use during childhood. PMID:23710365

Detection of Ozone and Nitric Oxide in Decomposition Products of Air-Insulated Switchgear Using Ultraviolet Differential Optical Absorption Spectroscopy (UV-DOAS).

PubMed

Li, Yalong; Zhang, Xiaoxing; Li, Xin; Cui, Zhaolun; Xiao, Hai

2018-01-01

Air-insulated switchgear cabinets play a role in the protection and control of the modern power grid, and partial discharge (PD) switchgear is a long-term process in the non-normal operation of one of the situations; thus, condition monitoring of the switchgear is important. The air-insulated switchgear during PD enables the decomposition of air components, namely, O 3 and NO. A set of experimental platforms was designed on the basis of the principle of ultraviolet differential optical absorption spectroscopy (UV-DOAS) to detect O 3 and NO concentrations in air-insulated switchgear. Differential absorption algorithm and wavelet transform were used to extract effective absorption spectra; a linear relationship between O 3 and NO concentrations and absorption spectrum data were established. O 3 detection linearity was up to 0.9992 and the detection limit was at 3.76 ppm. NO detection linearity was up to 0.9990 and the detection limit was at 0.64 ppm. Results indicate that detection platform is suitable for detecting trace O 3 and NO gases produced by PD of the air-insulated switchgear.

A simple growth method for Nb 2O 5 films and their optical properties

DOE PAGES

Dash, J. K.; Chen, L.; Topka, Michael R.; ...

2015-04-13

A simple method for the synthesis of Nb₂O₅ films of thicknesses ranging from tens to several hundreds of nanometers on amorphous silicon dioxide or quartz substrates is presented. Nb₂O₅ films were formed by annealing the sputter deposited Nb films under an Ar flow and without oxygen plasma in a quartz tube within a furnace at 850 °C. The structural, compositional, optical, and vibrational properties were characterized by grazing incidence X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible spectroscopy, and Raman scattering. Each of the Nb₂O₅ films is polycrystalline with an orthorhombic crystal structure. We observed vibrational modes includingmore » longitudinal optical, transverse optical, and triply degenerate modes, and measured the indirect optical band gap to be ~3.65 eV. The transmittance spectrum of the ~20 nm thick Nb₂O₅ film shows over 90% transmittance below the band gap energy in the visible wavelength range and decreases to less than 20% in the ultraviolet regime. As a result, the optical properties of the films in the UV-vis range show potential applications as UV detectors.« less

Tunable UV-visible absorption of SnS2 layered quantum dots produced by liquid phase exfoliation.

PubMed

Fu, Xiao; Ilanchezhiyan, P; Mohan Kumar, G; Cho, Hak Dong; Zhang, Lei; Chan, A Sattar; Lee, Dong J; Panin, Gennady N; Kang, Tae Won

2017-02-02

4H-SnS 2 layered crystals synthesized by a hydrothermal method were used to obtain via liquid phase exfoliation quantum dots (QDs), consisting of a single layer (SLQDs) or multiple layers (MLQDs). Systematic downshift of the peaks in the Raman spectra of crystals with a decrease in size was observed. The bandgap of layered QDs, estimated by UV-visible absorption spectroscopy and the tunneling current measurements using graphene probes, increases from 2.25 eV to 3.50 eV with decreasing size. 2-4 nm SLQDs, which are transparent in the visible region, show selective absorption and photosensitivity at wavelengths in the ultraviolet region of the spectrum while larger MLQDs (5-90 nm) exhibit a broad band absorption in the visible spectral region and the photoresponse under white light. The results show that the layered quantum dots obtained by liquid phase exfoliation exhibit well-controlled and regulated bandgap absorption in a wide tunable wavelength range. These novel layered quantum dots prepared using an inexpensive method of exfoliation and deposition from solution onto various substrates at room temperature can be used to create highly efficient visible-blind ultraviolet photodetectors and multiple bandgap solar cells.

Temperature Effects of Ultraviolet Irradiation on Material Degradation

NASA Astrophysics Data System (ADS)

Mori, Kazuyuki; Ishizawa, Junichiro

Ultraviolet rays (UV) cause organic materials to deteriorate. UV irradiation ground testing is therefore important to understand the “adequate lifetime assessment” and the “end-of-life (EOL) characteristic” of materials used in space. In previous experiments, high temperatures were found to accelerate the UV degradation of cross-linked ethylene tetrafluoroethylene (X-ETFE). This causes concern of potentially similar effects in other materials. In this study, we evaluated UV degradation at high temperatures and subsequently determined materials usable in space that had shown accelerated degradation due to UV irradiation at high temperatures.

The World Space Observatory Ultraviolet (WSO-UV), as a bridge to future UV astronomy

NASA Astrophysics Data System (ADS)

Shustov, B.; Gómez de Castro, A. I.; Sachkov, M.; Vallejo, J. C.; Marcos-Arenal, P.; Kanev, E.; Savanov, I.; Shugarov, A.; Sichevskii, S.

2018-04-01

Ultraviolet (UV) astronomy is a vital branch of space astronomy. Many dozens of short-term UV-experiments in space, as well as long-term observatories, have brought a very important knowledge on the physics and chemistry of the Universe during the last decades. Unfortunately, no large UV-observatories are planned to be launched by most of space agencies in the coming 10-15 years. Conversely, the large UVOIR observatories of the future will appear not earlier than in 2030s. This paper briefly describes the projects that have been proposed by various groups. We conclude that the World Space Observatory-Ultraviolet (WSO-UV) will be the only 2-m class UV telescope with capabilities similar to those of the HST for the next decade. The WSO-UV has been described in detail in previous publications, and this paper updates the main characteristics of its instruments and the current state of the whole project. It also addresses the major science topics that have been included in the core program of the WSO-UV, making this core program very relevant to the current state of the UV-astronomy. Finally, we also present here the ground segment architecture that will implement this program.

Eta Carinae across the 2003.5 Minimum: Analysis in the Visible and Near Infrared Spectral Region

NASA Technical Reports Server (NTRS)

Nielsen, K. E.; Kober, G. Vieira; Weis, K.; Gull, T.; Stahl, O.; Bomans, D. J.

2008-01-01

We present analysis of the visible through near infrared spectrum of eta Car and its ejecta obtained during the 'eta Car Campaign with the Ultraviolet Visual Echelle Spectrograph (UVES) at the ESO Very Large Telescope (VLT)'. This is a part of larger effort to present a complete eta Car spectrum, and extends the previously presented analyses with the Hubble Space Telescope/Space Telescope Imaging Spectrograph (HST/STIS) in the UV (1240-3159 A) to 10,430 A. The spectrum in the mid and near UV is characterized by the ejecta absorption. At longer wavelengths, stellar wind features from the central source and narrow emission lines from the Weigelt condensations dominate the spectrum. However, narrow absorption lines from the circumstellar shells are present. This paper provides a description of the spectrum between 3060 and 10,430 A, including line identifications of the ejecta absorption spectrum, the emission spectrum from the Weigelt condensations and the P-Cygni stellar wind features. The high spectral resolving power of VLT/UVES enables equivalent width measurements of atomic and molecular absorption lines for elements with no transitions at the shorter wavelengths. However, the ground based seeing and contributions of nebular scattered radiation prevent direct comparison of measured equivalent widths in the VLT/UVES and HST/STIS spectra. Fortunately, HST/STIS and VLT/UVES have a small overlap in wavelength coverage which allows us to compare and adjust for the difference in scattered radiation entering the instruments apertures. This paper provide a complete online VLT/UVES spectrum with line identifications and a spectral comparison between HST/STIS and VLT/UVES between 3060 and 3160 A.

Eta Carinae across the 2003.5 Minimum: Analysis in the Visible and Near Infrared Spectral Region

NASA Technical Reports Server (NTRS)

Nielsen, K. E.; Kober, G. Vieira; Weis, K.; Gull, T. R.; Stahl, O.; Bomans, D. J.

2009-01-01

We present an analysis of the visible through near infrared spectrum of Eta Car and its ejecta obtained during the "Eta Car Campaign with the Ultraviolet and Visual Echelle Spectrograph (UVES) at the ESO Very Large Telescope (VLT)". This is a part of the larger effort to present a complete Eta Car spectrum, and extends the previously presented analyses with the Hubble Space Telescope/Space Telescope Imaging Spectrograph (HST/STIS) in the UV (1240-3159 Angstrom) to 10,430 Angstrom. The spectrum in the mid and near UV is characterized by the ejecta absorption. At longer wavelengths, stellar wind features from the central source and narrow emission lines from the Weigelt condensations dominate the spectrum. However, narrow absorption lines from the circumstellar shells are present. This paper provides a description of the spectrum between 3060 and 10,430 Angstroms, including line identifications of the ejecta absorption spectrum, the emission spectrum from the Weigelt condensations and the P-Cygni stellar wind features. The high spectral resolving power of VLT/UVES enables equivalent width measurements of atomic and molecular absorption lines for elements with no transitions at the shorter wavelengths. However, the ground based seeing and contributions of nebular scattered radiation prevent direct comparison of measured equivalent widths in the VLT/UVES and HST/STIS spectra. Fortunately, HST/STIS and VLT/UVES have a small overlap in wavelength coverage which allows us to compare and adjust for the difference in scattered radiation entering the instruments' apertures. This paper provides a complete online VLT/UVES spectrum with line identifications and a spectral comparison between HST/STIS and VLT/UVES between 3060 and 3160 Angstroms.

Theoretical studies on the structural and spectra properties of two C74 fullerenes and the chlorinated species C74Cl10

NASA Astrophysics Data System (ADS)

Zheng, Mei; Song, Xitong; Li, Xiaoqi; Qi, Jiayuan

2018-07-01

The geometrical/electronic structures, X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure spectroscopy of two especially C74 fullerenes (D3h-C74 and C1-C74) and the chlorinated species C1-C74Cl10, which are newly isolated in the experiment, have been calculated by means of the density functional theory (DFT) method. Effective changes in the electronic structure and simulated X-ray spectra have been observed after chlorination. Strong isomer dependence has been found in both spectra, thus the 'fingerprints' in the spectra can be employed as a tool to identify the isomers. The ultraviolet-visible (UV-vis) absorption spectrum of C1-C74Cl10 has been performed by using the time-dependent DFT method. The generated UV-vis spectrum coincides with the previous experimental counterpart. The results of this work can provide useful information especially for isomer identification and further study on fullerenes by means of the aforementioned spectroscopy techniques.

Theoretical and experimental luminous characteristics of white LEDs composed of multiphosphors and near-UV LED for lighting

NASA Astrophysics Data System (ADS)

Uchida, Yuji; Taguchi, Tsunemasa

2003-07-01

We have performed theoretical studies on the luminous characeristics of white LED light source which composed of multi phosphors and near ultraviolet (UV) LED for general lighting. White LED source for general lighting applications requires the conditions that have high-flux, high luminous efficacy of radiation (> 100 lm/W) in addition to high color rendering index (Ra > 90) and variable color temperatures. Recently, we have proposed a novel type white LED based on multi phosphors and near UV LED system in order to high-Ra (>93). We will describe the excellent luminescence properties of white LED consisting of orange (O), yellow (Y), green (G) and blue (B) phosphor materials, and near UV LED. The color spectral contributions of individual phosphor-coated LED are theoretically analyzed using our multi LED lighting theory calculated the maximum luminous efficacy can be estimated to be approximately 300 lm/W having a high Ra of about 90 taking into account individual radiation spectrum. Illuminance distribution of white LED is in fairly good agreement with the experimental data.

Impact of shortwave ultraviolet (UV-C) radiation on the antioxidant activity of thyme (Thymus vulgaris L.).

PubMed

Dogu-Baykut, Esra; Gunes, Gurbuz; Decker, Eric Andrew

2014-08-15

Thyme is a good source of antioxidant compounds but it can be contaminated by microorganisms. An experimental fluid bed ultraviolet (UV) reactor was designed for microbial decontamination of thyme samples and the effect of shortwave ultraviolet light (UV-C) radiation on antioxidant properties of thyme was studied. Samples were exposed to UV-C radiation for 16 or 64 min. UV-C treatment led to 1.04 and 1.38 log CFU/g reduction of total aerobic mesophilic bacteria (TAMB) counts. Hunter a(∗) value was the most sensitive colour parameter during UV-C treatment. 2,2-Diphenyl-1-picrylhydrazyl (DPPH) scavenging activity of extracts was not significantly affected by UV-C. Addition of thyme extracts at 0.15 and 0.3 μmol GAE/ml emulsion delayed the formation of lipid hydroperoxides and headspace hexanal in the 5.0%(wt) corn oil-in-water emulsion from 4 to 9 and 14 days, respectively. No significant changes in oxidation rates were observed between UV-C treated and untreated samples at same concentrations. Copyright © 2014 Elsevier Ltd. All rights reserved.

DEMONSTRATION BULLETIN - ULTROX INTERNATIONAL, INC. ULTRAVIOLET RADIATION AND OXIDATION

EPA Science Inventory

The ultraviolet (UV) radiation/oxidation treatment technology developed by Ultrox International uses a combination of UV radiation, ozone, and hydrogen peroxide to oxidize organic compounds in water. Various operating parameters can be adjusted in the Ultrox® system to enhan...

BD-22deg3467, a DAO-type Star Exciting the Nebula Abell 35

NASA Technical Reports Server (NTRS)

Ziegler, M.; Rauch, T.; Werner, K.; Koppen, J.; Kruk, J. W.

2013-01-01

Spectral analyses of hot, compact stars with non-local thermodynamical equilibrium (NLTE) model-atmosphere techniques allow the precise determination of photospheric parameters such as the effective temperature (T(sub eff)), the surface gravity (log g), and the chemical composition. The derived photospheric metal abundances are crucial constraints for stellar evolutionary theory. Aims. Previous spectral analyses of the exciting star of the nebula A35, BD-22deg3467, were based on He+C+N+O+Si+Fe models only. For our analysis, we use state-of-the-art fully metal-line blanketed NLTE model atmospheres that consider opacities of 23 elements from hydrogen to nickel. We aim to identify all observed lines in the ultraviolet (UV) spectrum of BD-22deg3467 and to determine the abundances of the respective species precisely. Methods. For the analysis of high-resolution and high signal-to-noise ratio (S/N) far-ultraviolet (FUSE) and UV (HST/STIS) observations, we combined stellar-atmosphere models and interstellar line-absorption models to fully reproduce the entire observed UV spectrum. Results. The best agreement with the UV observation of BD-22deg3467 is achieved at T(sub eff) = 80 +/- 10 kK and log g = 7.2 +/- 0.3. While T(sub eff) of previous analyses is verified, log g is significantly lower. We re-analyzed lines of silicon and iron (1/100 and about solar abundances, respectively) and for the first time in this star identified argon, chromium, manganese, cobalt, and nickel and determined abundances of 12, 70, 35, 150, and 5 times solar, respectively. Our results partially agree with predictions of diffusion models for DA-type white dwarfs. A combination of photospheric and interstellar line-absorption models reproduces more than 90% of the observed absorption features. The stellar mass is M approx. 0.48 Solar Mass. Conclusions. BD.22.3467 may not have been massive enough to ascend the asymptotic giant branch and may have evolved directly from the extended horizontal branch to the white dwarf state. This would explain why it is not surrounded by a planetary nebula. However, the star, ionizes the ambient interstellar matter, mimicking a planetary nebula.

Self-consistent performance modeling for dual band MIS UV photodetectors based on Si/SiO2 multilayer structure.

PubMed

Rostami, A; Leilaeioun, M; Golmmohamadi, S; Rasooli Saghai, H

2012-06-01

In this paper, we present a self-consistent theoretical model for a metal-insulator semiconductor (MIS) dual band ultraviolet (UV) photodetector with a modified structure implying an arbitrarily defined insulating potential barrier as its active region. Utilizing our proposed model, the dark and photocurrent density-voltage (J-V) characteristics of MIS UV photodetectors with multi-quantum wells of silicon (MQWs) are calculated. We demonstrate that dark current is reduced in the suggested structure, because the electron-tunneling probability becomes unity at energies coincident with the peak detection wavelength. This is due to the resonant tunneling and decreases at energies that are significantly smaller than this optimum value. In consequence, the number of carriers contributing to the dark current, which have a broad energy distribution at high temperatures, will decrease. It is also shown that the designed structure could detect two individual UV wavelengths, simultaneously. The width of each Si quantum well has been considered at around 1.2 nm, in order to observe these two absorption peaks in the middle and near UV regions of photon spectrum (about 365 nm, 175 nm).

The endogenous hormones in soybean seedlings under the joint actions of rare earth element La(III) and ultraviolet-B stress.

PubMed

Peng, Qi; Zhou, Qing

2009-12-01

The dynamic state of endogenous hormone content in soybean seedlings was investigated for a further demonstration of alleviating the damage of the ultraviolet ultraviolet-B (UV-B) radiation in the La(III)-treated soybean seedlings under UV-B stress. Using hydroponics culture, the effects of lanthanum(III) on the contents of endogenous hormone under elevated ultraviolet-B radiation (280–320 nm) was studied. The results showed that the content of indole-3-acetic acid (IAA) in soybean seedlings decreased initially and then increased when the seedlings underwent UV-B treatment during the stress and convalescent period; this was compared with a control; acetic acid oxidase (IAAO) activity increased at first (first to fifth day) and then decreased (sixth to 11th day). A similar change of abscisic acid content and IAAO content in soybean seedlings occurred; gibberellic acid (GA) content decreased during the experiment compared with control. The content of IAA and GA in soybean seedlings with La(III) + UV-B treatment was higher than those of UV-B treatment; IAAO activity and GA content in soybean seedlings with La (III) + UV-B treatment were lower than those of UV-B treatment. It suggested that the regulative effect of La(III) at the optimum concentration on endogenous hormone improved the ability of plant stress resistance, and its protective effect against low UV-B radiation was superior to high UV-B radiation. The defensive effect of La(III) on soybean seedlings under UV-B stress was carried out on the layer of defense system.

Experimental determination of photostability and fluorescence-based detection of PAHs on the Martian surface

NASA Astrophysics Data System (ADS)

Dartnell, Lewis R.; Patel, Manish R.; Storrie-Lombardi, Michael C.; Ward, John M.; Muller, Jan-Peter

2012-05-01

Even in the absence of any biosphere on Mars, organic molecules, including polycyclic aromatic hydrocarbons (PAHs), are expected on its surface due to delivery by comets and meteorites of extraterrestrial organics synthesized by astrochemistry, or perhaps in situ synthesis in ancient prebiotic chemistry. Any organic compounds exposed to the unfiltered solar ultraviolet spectrum or oxidizing surface conditions would have been readily destroyed, but discoverable caches of Martian organics may remain shielded in the subsurface or within surface rocks. We have studied the stability of three representative polycyclic aromatic hydrocarbons (PAHs) in a Mars chamber, emulating the ultraviolet spectrum of unfiltered sunlight under temperature and pressure conditions of the Martian surface. Fluorescence spectroscopy is used as a sensitive indicator of remaining PAH concentration for laboratory quantification of molecular degradation rates once exposed on the Martian surface. Fluorescence-based instrumentation has also been proposed as an effective surveying method for prebiotic organics on the Martian surface. We find the representative PAHs, anthracene, pyrene, and perylene, to have persistence half-lives once exposed on the Martian surface of between 25 and 60 h of noontime summer UV irradiation, as measured by fluorescence at their peak excitation wavelength. This equates to between 4 and 9.6 sols when the diurnal cycle of UV light intensity on the Martian surface is taken into account, giving a substantial window of opportunity for detection of organic fluorescence before photodegradation. This study thus supports the use of fluorescence-based instrumentation for surveying recently exposed material (such as from cores or drill tailings) for native Martian organic molecules in rover missions.

CHALLENGES OF COMBINED SEWER OVERFLOW DISINFECTION BY ULTRAVIOLET LIGHT IRRADIATION

EPA Science Inventory

This article examines the performance and effectiveness of ultraviolet (UV) light irradiation for disinfection of combined sewer overflow (CSO). Due to the negative impact of conventional water disinfectants on aquatic life, new agents (e.g., UV light) are being investigated for ...

ULTRAVIOLET RADIATION AND ARSENIC INTERACTIONS: EFFECTS ON CLADOCERANS

EPA Science Inventory

The effects of arsenic and ultraviolet radiation (UV) on cladocerans have been examined separately, however the interaction of these two stresses has not been explored. Potential synergism between these two stresses is possible as arsenic is known to inhibit repair of UV induced ...

Near-UV emission from In-rich InGaN/GaN single quantum well structure with compositional grading

NASA Astrophysics Data System (ADS)

Kwon, S.-Y.; Cho, M.-H.; Moon, P.; Kim, H. J.; Na, H.; Seo, H.-C.; Kim, H. J.; Shin, Y.; Moon, D. W.; Sun, Y.; Cho, Y.-H.; Yoon, E.

2004-09-01

We grew high quality In-rich InGaN/GaN single quantum well (SQW) structures by metal-organic chemical vapor deposition using growth interruption and obtained a sharp photoluminescence peak in near-ultraviolet (UV) region. During In-rich InGaN well layer growth, only TMIn and ammonia were supplied, however, atomic interdiffusion as well as defect generation occurred to relieve large lattice mismatch over 10% between InN and GaN. From medium-energy ion scattering measurement and subsequent fitting of the spectrum, we could find that the InGaN well layer was In-rich and it has 60-70% indium content. We also found the compositional grading of indium at top and bottom InGaN/GaN interfaces. The Fourier series method was used to calculate the energy levels and envelope functions in In-rich InGaN/GaN SQW with compositional grading and we could quantitatively explain the near-UV emission observed from the SQW.

Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications

NASA Astrophysics Data System (ADS)

Xie, Zhiqing; Su, Xin; Ding, Hanqin; Li, Hongyi

2018-06-01

Nonlinear optical materials have attracted worldwide attention owing to their wide range of applications, specially in the laser field. Phosphates with noncentrosymmetric structures are potential candidates for novel ultraviolet (UV)-NLO materials, because they usually display short UV cut-off edges. In this work, a polyphosphate, the LiZnP3O9 polyphosphate crystals were grown through spontaneous crystallization from high-temperature melts. It crystallizes in the orthorhombic space group P212121 with unit cell parameters a = 8.330(3) Å, b = 8.520(3) Å, c = 8.635(3) Å, and Z = 4. In the structure, all the P atoms are coordinated by four oxygen atoms forming the [PO4] tetrahedra and further connected to generate a zig-zag [PO3]∞ anionic framework. Thermal analysis, IR spectroscopy, UV-vis-NIR diffuse reflectance spectrum and powder second harmonic generation measurements are performed. In addition, the first-principles calculation was employed for better understanding the structure-property relationships of LiZnP3O9.

Bias Selectable Dual Band AlGaN Ultra-violet Detectors

NASA Technical Reports Server (NTRS)

Yan, Feng; Miko, Laddawan; Franz, David; Guan, Bing; Stahle, Carl M.

2007-01-01

Bias selectable dual band AlGaN ultra-violet (UV) detectors, which can separate UV-A and UV-B using one detector in the same pixel by bias switching, have been designed, fabricated and characterized. A two-terminal n-p-n photo-transistor-like structure was used. When a forward bias is applied between the top electrode and the bottom electrode, the detectors can successfully detect W-A and reject UV-B. Under reverse bias, they can detect UV-B and reject UV-A. The proof of concept design shows that it is feasible to fabricate high performance dual-band UV detectors based on the current AlGaN material growth and fabrication technologies.

The X-ray and ultraviolet absorbing outflow in 3C 351

NASA Astrophysics Data System (ADS)

Mathur, Smita; Wilkes, Belinda; Elvis, Martin; Fiore, Fabrizio

1994-10-01

3C 351 (z = 0.371), and X-ray-'quiet' quasar, is one of the few quasars showing signs of a 'warm absorber' in its X-ray spectrum; i.e., partially ionized absorbing material in the line of sight whose opacity depends on its ionization structure. The main feature in the X-ray spectrum is a K-edge due to O VII or O VIII. 3C 351 also shows unusually strong, blueshifted, associated, absorption lines in the ultraviolet (Bahcall et al. 1993) including O VI (lambda lambda 1031, 1037). This high ionization state strongly suggests an identification with the X-ray absorber and a site within the active nucleus. In this paper we demonstrate that the X-ray and UV absorption is due to the same material. This is the first confirmed UV/X-ray absorber. Physical conditions of the absorber are determined through the combination of constraints derived from both the X-ray and UV analysis. This highly ionized, outflowing, low-density, high-column density absorber situated outside the broad emission line region (BELR) is a previously unknown component of nuclear material. We rule out the identification of the absorber with a BELR cloud as the physical conditions in the two regions are inconsistent with one another. The effect of the X-ray quietness and IR upturn in the 3C 351 continuum on the BELR is also investigated. The strengths of the high-ionization lines of C IV lambda-1549 and O VI lambda-1034 with respect to Lyman-alpha are systematically lower (up to a factor of 10) in the material ionized by the 3C 351 continuum as compared to those produced by the 'standard' quasar continuum, the strongest effect being on the strength of O VI lambda-1034. We find that for a 3C 351-like continuum, C III) lambda-1909 ceases to be a density indicator.

Stellar laboratories. II. New Zn iv and Zn v oscillator strengths and their validation in the hot white dwarfs G191-B2B and RE 0503-289

NASA Astrophysics Data System (ADS)

Rauch, T.; Werner, K.; Quinet, P.; Kruk, J. W.

2014-04-01

Context. For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. In a recent analysis of the ultraviolet (UV) spectrum of the DA-type white dwarf G191-B2B, 21 Zn iv lines were newly identified. Because of the lack of Zn iv data, transition probabilities of the isoelectronic Ge vi were adapted for a first, coarse determination of the photospheric Zn abundance. Aims: Reliable Zn iv and Zn v oscillator strengths are used to improve the Zn abundance determination and to identify more Zn lines in the spectra of G191-B2B and the DO-type white dwarf RE 0503-289. Methods: We performed new calculations of Zn iv and Zn v oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of the Zn iv - v spectrum exhibited in high-resolution and high-S/N UV observations of G191-B2B and RE 0503-289. Results: In the UV spectrum of G191-B2B, we identify 31 Zn iv and 16 Zn v lines. Most of these are identified for the first time in any star. We can reproduce well almost all of them at log Zn = -5.52 ± 0.2 (mass fraction, about 1.7 times solar). In particular, the Zn iv / Zn v ionization equilibrium, which is a very sensitive Teff indicator, is well reproduced with the previously determined and log g = 7.60 ± 0.05. In the spectrum of RE 0503-289, we identified 128 Zn v lines for the first time and determined log Zn = -3.57 ± 0.2 (155 times solar). Conclusions: Reliable measurements and calculations of atomic data are a pre-requisite for stellar-atmosphere modeling. Observed Zn iv and Zn v line profiles in two white dwarf (G191-B2B and RE 0503-289) ultraviolet spectra were well reproduced with our newly calculated oscillator strengths. This allowed us to determine the photospheric Zn abundance of these two stars precisely. Based on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-26666.Based on observations made with the NASA-CNES-CSA Far Ultraviolet Spectroscopic Explorer.Tables 1 and 2 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/564/A41

ULTRAVIOLET HALOS AROUND SPIRAL GALAXIES. I. MORPHOLOGY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hodges-Kluck, Edmund; Cafmeyer, Julian; Bregman, Joel N., E-mail: hodgeskl@umich.edu

2016-12-10

We examine ultraviolet halos around a sample of highly inclined galaxies within 25 Mpc to measure their morphology and luminosity. Despite contamination from galactic light scattered into the wings of the point-spread function, we find that ultraviolet (UV) halos occur around each galaxy in our sample. Around most galaxies the halos form a thick, diffuse disk-like structure, but starburst galaxies with galactic superwinds have qualitatively different halos that are more extensive and have filamentary structure. The spatial coincidence of the UV halos above star-forming regions, the lack of consistent association with outflows or extraplanar ionized gas, and the strong correlationmore » between the halo and galaxy UV luminosity suggest that the UV light is an extragalactic reflection nebula. UV halos may thus represent 10{sup 6}–10{sup 7} M {sub ⊙} of dust within 2–10 kpc of the disk, whose properties may change with height in starburst galaxies.« less

A novel research model for evaluating sunscreen protection in the UV-A1.

PubMed

Figueiredo, Sônia Aparecida; de Moraes, Dayane Cristina; Vilela, Fernanda Maria Pinto; de Faria, Amanda Natalina; Dos Santos, Marcelo Henrique; Fonseca, Maria José Vieira

2018-01-01

The use of a broad spectrum sunscreen is considered one of the main and most popular measures for preventing the damaging effects of ultraviolet radiation (UVR) on the skin. In this study we have developed a novel in vitro method to assess sunscreens efficacy to protect calcineurin enzyme activity, a skin cell marker. The photoprotective efficacy of sunscreen products was assessed by measuring the UV-A1 radiation-induced depletion of calcineurin (Cn) enzyme activity in primary neonatal human dermal fibroblast (HDFn) cell lysates. After exposure to 24J/cm 2 UV-A1 radiation, the sunscreens containing larger amounts of UV-A1 filters (brand B), the astaxanthin (UV-A1 absorber) and the Tinosorb® M (UV-A1 absorber) were capable of preventing loss of Cn activity when compared to the sunscreens formulations of brand A (low concentration of UV-A1 filters), with the Garcinia brasiliensis extract (UV-B absorber) and with the unprotected cell lysate and exposed to irradiation (Irradiated Control - IC). The Cn activity assay is a reproducible, accurate and selective technique for evaluating the effectiveness of sunscreens against the effects of UV-A1 radiation. The developed method showed that calcineurin activity have the potential to act as a biological indicator of UV-A1 radiation-induced damages in skin and the assay might be used to assess the efficacy of sunscreens agents and plant extracts prior to in vivo tests. Copyright © 2017 Elsevier B.V. All rights reserved.

Next step in Studying the Ultraviolet Universe: WSO-UV

NASA Astrophysics Data System (ADS)

Shustov, Boris M.; Sachkov, Mikhail; Gomez De Castro, Ana

The World Space Observatory-Ultraviolet (WSO-UV) is an international space mission born as a response to the growing up demand for UV facilities by the astronomical community. In the horizon of the next 10 years, the WSO-UV will be the only 2-meters class mission in the after-HST epoch that will guarantee access to UV wavelength domain. The project is managed by an international consortium led by the Federal Space Agency (ROSCOSMOS, Russia). Here we describe the WSO-UV project with its general objectives and main features, the details and status of instrumentation that includes WUVS (spectrographs) and the ISSIS instrument (Field Camera Unit), WSO-UV ground segment, science management plan, the WSO-UV key science issues and prospects of high resolution spectroscopic studies with WSO-UV.

Space Telescope and Optical Reverberation Mapping Project VI. Variations of the Intrinsic Absorption Lines in NGC 5548

NASA Astrophysics Data System (ADS)

Kriss, Gerard A.; Agn Storm Team

2015-01-01

The AGN STORM collaboration monitored the Seyfert 1 galaxy NGC 5548 over a six-month period, with observations spanning the hard X-ray to mid-infrared wavebands. The core of this campaign was an intensive HST COS program, which obtained 170 far-ultraviolet spectra at approximately daily intervals, with twice-per-day monitoring of the X-ray, near-UV, and optical bands during much of the same period using Swift. The broad UV absorption lines discovered by Kaastra et al. (2014) and associated with the new soft X-ray obscurer are continuously present in the STORM campaign COS spectra. Their strength varies with the degree of soft X-ray obscuration as revealed by the Swift X-ray spectra. The narrow associated absorption lines in the UV spectrum of NGC 5548 remain strong. The lower-ionization transitions that appeared concurrently with the soft X-ray obscuration vary in response to the changing UV flux on a daily basis. Their depths over the longer term, however, also respond to the strength of the soft X-ray obscuration, indicating that the soft X-ray obscurer has a significant influence on the ionizing UV continuum that is not directly tracked by the observable UV continuum itself.

Two-photon excitation in chip electrophoresis enabling label-free fluorescence detection in non-UV transparent full-body polymer chips.

PubMed

Geissler, David; Belder, Detlev

2015-12-01

One of the most commonly employed detection methods in microfluidic research is fluorescence detection, due to its ease of integration and excellent sensitivity. Many analytes though do not show luminescence when excited in the visible light spectrum, require suitable dyes. Deep-ultraviolet (UV) excitation (<300 nm) allows label-free detection of a broader range of analytes but also mandates the use of expensive fused silica glass, which is transparent to UV light. Herein, we report the first application of label-free deep UV fluorescence detection in non-UV transparent full-body polymer microfluidic devices. This was achieved by means of two-photon excitation in the visible range (λex = 532 nm). Issues associated with the low optical transmittance of plastics in the UV range were successfully circumvented in this way. The technique was investigated by application to microchip electrophoresis of small aromatic compounds. Various polymers, such as poly(methyl methacrylate), cyclic olefin polymer, and copolymer as well as poly(dimethylsiloxane) were investigated and compared with respect to achievable LOD and ruggedness against photodamage. To demonstrate the applicability of the technique, the method was also applied to the determination of serotonin and tryptamine in fruit samples. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The PUR Experiment on the EXPOSE-R facility: biological dosimetry of solar extraterrestrial UV radiation

NASA Astrophysics Data System (ADS)

Bérces, A.; Egyeki, M.; Fekete, A.; Horneck, G.; Kovács, G.; Panitz, C.

2015-01-01

The aim of our experiment Phage and Uracil Response was to extend the use of bacteriophage T7 and uracil biological dosimeters for measuring the biologically effective ultraviolet (UV) dose in the harsh extraterrestrial radiation conditions. The biological detectors were exposed in vacuum-tightly cases in the European Space Agency (ESA) astrobiological exposure facility attached to the external platform of Zvezda (EXPOSE-R). EXPOSE-R took off to the International Space Station (ISS) in November 2008 and was installed on the External platform of the Russian module Zvezda of the ISS in March 2009. Our goal was to determine the dose-effect relation for the formation of photoproducts (i.e. damage to phage DNA and uracil, respectively). The extraterrestrial solar UV radiation ranges over the whole spectrum from vacuum-UV (λ<200 nm) to UVA (315 nm<λ<400 nm), which causes photolesions (photoproducts) in the nucleic acids/their components either by photoionization or excitation. However, these wavelengths cause not only photolesions but in a wavelength-dependent efficiency the reversion of some photolesions, too. Our biological detectors measured in situ conditions the resultant of both reactions induced by the extraterrestrial UV radiation. From this aspect the role of the photoreversion in the extension of the biological UV dosimetry are discussed.

Enhancement of pectinase production by ultraviolet irradiation and diethyl sulfate mutagenesis of a Fusarium oxysporum isolate.

PubMed

Yin, L B; Zhang, C F; Xia, Q L; Yang, Y; Xiao, K; Zhao, L Z

2016-09-23

Fusarium oxysporum strain BM-201 was treated with ultraviolet (UV) radiation to obtain a high pectinase-producing strain. Mutant UV-10-41 was obtained and then treated by diethyl sulfate. Next, the mutant UV-diethyl sulfate-43 derived from UV-10-41 was selected as high pectinase-producing strain. Mutant UV-diethyl sulfate-43 was incubated on slant for 10 generations, demonstrating that the pectinase-producing genes were stable. Pectinase activity reached 391.2 U/mL, which is 73.6% higher than that of the original strain.

ULTRAVIOLET LIGHT DISINFECTION OF COMBINED SEWER OVERFLOW (NEW ORLEANS)

EPA Science Inventory

The objective of this state-of-the-art review is to examine the performance and effectiveness of ultraviolet (UV) light disinfection for combined sewer overflow (CSO) applications. Topics presented include the use of UV light as a disinfecting agent, its practical applications, d...

LOW PRESSURE ULTRAVIOLET STUDIES FOR INACTIVATION OF GIARDIA MURIS CYSTS

EPA Science Inventory

This research was initiated to confirm and expand the current database for the inactivation of Giardia spp. using ultraviolet (UV) radiation. Initially, previous research that used in vitro excystation as the indicator for UV effectiveness was confirmed. Later, the in vitro excys...

Integrated oxide graphene based device for laser inactivation of pathogenic microorganisms

NASA Astrophysics Data System (ADS)

Grishkanich, Alexsandr; Ruzankina, Julia; Afanasyev, Mikhail; Paklinov, Nikita; Hafizov, Nail

2018-02-01

We develop device for virus disinfection of pathogenic microorganisms. Viral decontamination can be carried out due to hard ultraviolet irradiation and singlet oxygen destroying the genetic material of a virus capsid. UV rays can destroy DNA, leading to the formation of dimers of nucleic acids. This practically does not occur in tissues, tk. UV rays penetrate badly through them, however, the viral particles are small and UV can destroy their genetic material, RNA / DNA and the virus can not replicate. It is with the construction of the ultraviolet laser water disinfection system (UFLOV) based on the continuous and periodic pulsed ultraviolet laser sources (pump) binds to solve sterility and depyrogenation of water. It has been established that small doses of UV irradiation stimulate reproduction, and large doses cause the death of pathogenic microorganisms. The effect of a dose of ultraviolet is the result of photochemical action on the substance of a living bacterial cell or virion. Also complex photodynamic laser inactivation on graphene oxide is realized.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Hengxiao; Gu, Minfeng, E-mail: hxguo@shao.ac.cn, E-mail: gumf@shao.ac.cn

We investigated the optical/ultraviolet (UV) color variations for a sample of 2169 quasars based on multi-epoch spectroscopy in the Sloan Digital Sky Survey data releases seven (DR7) and nine (DR9). To correct the systematic difference between DR7 and DR9 due to the different instrumental setup, we produced a correction spectrum by using a sample of F-stars observed in both DR7 and DR9. The correction spectrum was then applied to quasars when comparing the spectra of DR7 with DR9. In each object, the color variation was explored by comparing the spectral index of the continuum power-law fit on the brightest spectrummore » with the faintest one, and also by the shape of their difference spectrum. In 1876 quasars with consistent color variations from two methods, we found that most sources (1755, ∼94%) show the bluer-when-brighter (BWB) trend, and the redder-when-brighter (RWB) trend is detected in only 121 objects (∼6%). The common BWB trend is supported by the composite spectrum constructed from bright spectra, which is bluer than that from faint spectra, and also by the blue composite difference spectrum. The correction spectrum is proven to be highly reliable by comparing the composite spectrum from corrected DR9 and original DR7 spectra. Assuming that the optical/UV variability is triggered by fluctuations, the RWB trend can likely be explained if the fluctuations occur first in the outer disk region, and the inner disk region has not yet fully responded when the fluctuations are being propagated inward. In contrast, the common BWB trend implies that the fluctuations likely more often happen first in the inner disk region.« less

SOLAR-ISS: A new reference spectrum based on SOLAR/SOLSPEC observations

NASA Astrophysics Data System (ADS)

Meftah, M.; Damé, L.; Bolsée, D.; Hauchecorne, A.; Pereira, N.; Sluse, D.; Cessateur, G.; Irbah, A.; Bureau, J.; Weber, M.; Bramstedt, K.; Hilbig, T.; Thiéblemont, R.; Marchand, M.; Lefèvre, F.; Sarkissian, A.; Bekki, S.

2018-03-01

Context. Since April 5, 2008 and up to February 15, 2017, the SOLar SPECtrometer (SOLSPEC) instrument of the SOLAR payload on board the International Space Station (ISS) has performed accurate measurements of solar spectral irradiance (SSI) from the middle ultraviolet to the infrared (165 to 3088 nm). These measurements are of primary importance for a better understanding of solar physics and the impact of solar variability on climate. In particular, a new reference solar spectrum (SOLAR-ISS) is established in April 2008 during the solar minima of cycles 23-24 thanks to revised engineering corrections, improved calibrations, and advanced procedures to account for thermal and aging corrections of the SOLAR/SOLSPEC instrument. Aims: The main objective of this article is to present a new high-resolution solar spectrum with a mean absolute uncertainty of 1.26% at 1σ from 165 to 3000 nm. This solar spectrum is based on solar observations of the SOLAR/SOLSPEC space-based instrument. Methods: The SOLAR/SOLSPEC instrument consists of three separate double monochromators that use concave holographic gratings to cover the middle ultraviolet (UV), visible (VIS), and infrared (IR) domains. Our best ultraviolet, visible, and infrared spectra are merged into a single absolute solar spectrum covering the 165-3000 nm domain. The resulting solar spectrum has a spectral resolution varying between 0.6 and 9.5 nm in the 165-3000 nm wavelength range. We build a new solar reference spectrum (SOLAR-ISS) by constraining existing high-resolution spectra to SOLAR/SOLSPEC observed spectrum. For that purpose, we account for the difference of resolution between the two spectra using the SOLAR/SOLSPEC instrumental slit functions. Results: Using SOLAR/SOLSPEC data, a new solar spectrum covering the 165-3000 nm wavelength range is built and is representative of the 2008 solar minimum. It has a resolution better than 0.1 nm below 1000 nm and 1 nm in the 1000-3000 nm wavelength range. The new solar spectrum (SOLAR-ISS) highlights significant differences with previous solar reference spectra and with solar spectra based on models. The integral of the SOLAR-ISS solar spectrum yields a total solar irradiance of 1372.3 ± 16.9 Wm-2 at 1σ, that is yet 11 Wm-2 over the value recommended by the International Astronomical Union in 2015. The spectrum shown in Fig. B.1 is available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/611/A1

Evidence for sulphur implantation in Europa's UV absorption band

NASA Technical Reports Server (NTRS)

Lane, A. L.; Nelson, R. M.; Matson, D. L.

1981-01-01

The UV spectral characteristics of the Galilean satellites are investigated (using data from the International Ultraviolet Explorer (IUE) spacecraft) as a function of the orbital position, large-scale areal variability, and temporal dynamics. The discovery of an absorption feature at 280 nm in Europa's reflection spectrum is reported and observations show that the absorption is strongest on the trailing hemisphere (central longitude 270 degrees). The feature resembles SO2 and seems to result from S-O bond formation between deeply implanted sulphur atoms and the adjacent damaged water-ice-lattice. The sulphur supposedly comes from energetic (hundreds of keV) sulphur ions that are present in the Jovian magnetosphere. An appropriate equilibrium condition can be found to match the observed spectral data if sputtering erosion occurs at no greater than approximately 20 meters per one billion years.

Preparation and characterization of functional poly(vinylidene fluoride) (PVDF) membranes with ultraviolet-absorbing property

NASA Astrophysics Data System (ADS)

Dong, Li; Liu, Xiangdong; Xiong, Zhengrong; Sheng, Dekun; Lin, Changhong; Zhou, Yan; Yang, Yuming

2018-06-01

We first reported a strategy to prepare functional poly(vinylidene fluoride) (PVDF) membranes with excellent ultraviolet-absorbing property through chemically induced grafting. Herein, the polymerizable ultraviolet (UV) absorber 2-hydroxy-4-(3-methacryloxy-2-hydroxylpropoxy) benzophenone (BPMA) made by ourselves was grafted onto the PVDF chains that have been pretreated with tetraethylammonium hydroxide (TEAH) alkaline solution. Moreover, the effect of experiment conditions such as the alkali and monomer concentrations, alkali treatment time on the UV-absorbing property of the obtained PVDF-g-PBPMA membranes were studied in detail. The chemical structure of the modified membranes was confirmed by 1H NMR, FT-IR and XPS measurements. Meanwhile, the thermal and UV-absorbing properties were characterized by TGA, DSC and UV-Vis spectrophotometer, respectively. The results indicated that BPMA side chains were successfully introduced onto PVDF backbones. Most importantly, the obtained PVDF-g-PBPMA membranes exhibited excellent UV-absorbing property. The transmittance of UV light at 300 nm decreased to as low as 0.02% and the UV light below 388 nm could be completely absorbed by the PVDF-g-PBPMA membrane made under optimal condition.

Measurement of the solar ultraviolet radiation at ground level in Bangi, Malaysia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aljawi, Ohoud; Gopir, Geri; Duay, Abdul Basit

2015-04-24

Understanding the amount of ultraviolet (UV) radiation received by human, plant, and animal organisms near the earth’s surface is important to a wide range of fields such as cancer research, agriculture and forestry. The solar ultraviolet spectral irradiance at ground level was measured using the Avantes spectrometer for the period of January to March 2014 at Bangi (2°55´N, 101°46´E, 50 m above sea level) in Malaysia. These data were used to estimate the diurnal variation of UV irradiance (300 – 400 nm). The maximum irradiance of UV radiation was 45 W m{sup −2} on horizontal surface. The maximum irradiance ofmore » UV received in the local noon time, and the minimum values of UV irradiance was received in the local morning time. It is found a bigger value of UV radiation was observed on clear sky in January. The estimation of daily flux average of UV irradiance was (921± 91) kJ m{sup −2}.« less

Photocatalytic antibacterial effects on TiO2-anatase upon UV-A and UV-A/VIS threshold irradiation.

PubMed

Wu, Yanyun; Geis-Gerstorfer, Jürgen; Scheideler, Lutz; Rupp, Frank

2016-01-01

Photocatalysis mediated by the anatase modification of titanium dioxide (TiO2) has shown antibacterial effects in medical applications. The aim of this study was to investigate the possibility of expanding the excitation wavelengths for photocatalytic antibacterial effects from ultraviolet (UV) into the visible light range. After deposition of salivary pellicle and adhesion of Streptococcus gordonii on anatase, different irradiation protocols were applied to induce photocatalysis: ultraviolet A (UV-A) > 320 nm; ultraviolet/visible (UV-A/VIS) light > 380 nm and > 390 nm; and VIS light 400-410 nm. A quartz crystal microbalance with dissipation (QCM-D) tests and microscopic examination were used to observe the photoinduced antibacterial effects. Salivary pellicle could be photocatalytically decomposed under all irradiation protocols. In contrast, effective photocatalytic attack of bacteria could be observed by UV-A as well as by UV-A/VIS at 380 nm < λ < 390 nm only. Wavelengths above 380 nm show promise for in situ therapeutic antifouling applications.

Two ultraviolet radiation datasets that cover China

NASA Astrophysics Data System (ADS)

Liu, Hui; Hu, Bo; Wang, Yuesi; Liu, Guangren; Tang, Liqin; Ji, Dongsheng; Bai, Yongfei; Bao, Weikai; Chen, Xin; Chen, Yunming; Ding, Weixin; Han, Xiaozeng; He, Fei; Huang, Hui; Huang, Zhenying; Li, Xinrong; Li, Yan; Liu, Wenzhao; Lin, Luxiang; Ouyang, Zhu; Qin, Boqiang; Shen, Weijun; Shen, Yanjun; Su, Hongxin; Song, Changchun; Sun, Bo; Sun, Song; Wang, Anzhi; Wang, Genxu; Wang, Huimin; Wang, Silong; Wang, Youshao; Wei, Wenxue; Xie, Ping; Xie, Zongqiang; Yan, Xiaoyuan; Zeng, Fanjiang; Zhang, Fawei; Zhang, Yangjian; Zhang, Yiping; Zhao, Chengyi; Zhao, Wenzhi; Zhao, Xueyong; Zhou, Guoyi; Zhu, Bo

2017-07-01

Ultraviolet (UV) radiation has significant effects on ecosystems, environments, and human health, as well as atmospheric processes and climate change. Two ultraviolet radiation datasets are described in this paper. One contains hourly observations of UV radiation measured at 40 Chinese Ecosystem Research Network stations from 2005 to 2015. CUV3 broadband radiometers were used to observe the UV radiation, with an accuracy of 5%, which meets the World Meteorology Organization's measurement standards. The extremum method was used to control the quality of the measured datasets. The other dataset contains daily cumulative UV radiation estimates that were calculated using an all-sky estimation model combined with a hybrid model. The reconstructed daily UV radiation data span from 1961 to 2014. The mean absolute bias error and root-mean-square error are smaller than 30% at most stations, and most of the mean bias error values are negative, which indicates underestimation of the UV radiation intensity. These datasets can improve our basic knowledge of the spatial and temporal variations in UV radiation. Additionally, these datasets can be used in studies of potential ozone formation and atmospheric oxidation, as well as simulations of ecological processes.

Autonomous portable solar ultraviolet spectroradiometer (APSUS) - a new CCD spectrometer system for localized, real-time solar ultraviolet (280-400 nm) radiation measurement.

PubMed

Hooke, Rebecca; Pearson, Andy; O'Hagan, John

2014-01-01

Terrestrial solar ultraviolet (UV) radiation has significant implications for human health and increasing levels are a key concern regarding the impact of climate change. Monitoring solar UV radiation at the earth's surface is therefore of increasing importance. A new prototype portable CCD (charge-coupled device) spectrometer-based system has been developed that monitors UV radiation (280-400 nm) levels at the earth's surface. It has the ability to deliver this information to the public in real time. Since the instrument can operate autonomously, it is called the Autonomous Portable Solar Ultraviolet Spectroradiometer (APSUS). This instrument incorporates an Ocean Optics QE65000 spectrometer which is contained within a robust environmental housing. The APSUS system can gather reliable solar UV spectral data from approximately April to October inclusive (depending on ambient temperature) in the UK. In this study the new APSUS unit and APSUS system are presented. Example solar UV spectra and diurnal UV Index values as measured by the APSUS system in London and Weymouth in the UK in summer 2012 are shown. © 2014 Crown copyright. Photochemistry and Photobiology © 2014 The American Society of Photobiology. This article is published with the permission of the Controller of HMSO and the Queen's Printer for Scotland and Public Health England.

Hydrodynamic cavitation to improve bulk fluid to surface mass transfer in a nonimmersed ultraviolet system for minimal processing of opaque and transparent fluid foods.

PubMed

Milly, P J; Toledo, R T; Chen, J; Kazem, B

2007-11-01

Ultraviolet (UV)-induced chemical reactions and inactivation of microorganisms in transparent and opaque fluids are strongly dependent upon the homogenous exposure of the target species to the UV irradiation. Current UV technologies used in water disinfection and food preservation applications have limited efficacy due to suspended particles shading target species. An Ultraviolet-Shockwave Power Reactor (UV-SPR) consisting of an inner rotating rotor and a stationary quartz housing and 2 end plates was used to induce 'controlled cavitation.' Eight UV low-pressure mercury lamps spaced uniformly were installed lengthwise around the quartz housing periphery. A KI to I(3) (-)chemical dosimeter for UV was used to quantify photons received by fluid in the annular space of the SPR. UV dose (J/m(2)) increased from 97 J/m(2) at 0 rpm to over 700 J/m(2) for SPR speeds above 2400 rpm. Inactivation of E. coli 25922 in apple juice and skim milk in the UV-SPR at exit temperatures below 45 degrees C was greater than 4.5 and 3 logs, respectively. The UV-SPR system proved successful in increasing the mass transfer of transparent and opaque fluid to the UV irradiated surface.

Performance results from in-flight commissioning of the Juno Ultraviolet Spectrograph (Juno-UVS)

NASA Astrophysics Data System (ADS)

Greathouse, T. K.; Gladstone, G. R.; Davis, M. W.; Slater, D. C.; Versteeg, M. H.; Persson, K. B.; Walther, B. C.; Winters, G. S.; Persyn, S. C.; Eterno, J. S.

2013-09-01

We present a description of the Juno ultraviolet spectrograph (Juno-UVS) and results from its in-flight commissioning performed between December 5th and 13th 2011 and its first periodic maintenance between October 10th and 12th 2012. Juno-UVS is a modest power (9.0 W) ultraviolet spectrograph based on the Alice instruments now in flight aboard the European Space Agency's Rosetta spacecraft, NASA's New Horizons spacecraft, and the LAMP instrument aboard NASA's Lunar Reconnaissance Orbiter. However, unlike the other Alice spectrographs, Juno-UVS sits aboard a spin stabilized spacecraft. The Juno-UVS scan mirror allows for pointing of the slit approximately +/-30° from the spacecraft spin plane. This ability gives Juno-UVS access to half the sky at any given spacecraft orientation. The planned 2 rpm spin rate for the primary mission results in integration times per 0.2° spatial resolution element per spin of only ~17 ms. Thus, for calibration purposes, data were retrieved from many spins and then remapped and co-added to build up exposure times on bright stars to measure the effective area, spatial resolution, scan mirror pointing positions, etc. The primary job of Juno-UVS will be to characterize Jupiter's UV auroral emissions and relate them to in-situ particle measurements. The ability to point the slit will make operations more flexible, allowing Juno-UVS to observe the atmospheric footprints of magnetic field lines through which Juno flies, giving a direct connection between energetic particle measurements on the spacecraft and the far-ultraviolet emissions produced by Jupiter's atmosphere in response to those particles.

Development of deep-ultraviolet metal vapor lasers

NASA Astrophysics Data System (ADS)

Sabotinov, Nikola V.

2004-06-01

Deep ultraviolet laser generation is of great interest in connection with both the development of new industrial technologies and applications in medicine, biology, chemistry, etc. The development of metal vapor UV lasers oscillating in the pulsed mode with high pulse repetition frequencies and producing high average output powers is of particular interest for microprocessing of polymers, photolithography and fluorescence applications. At present, metal vapor lasers generate deep-UV radiation on the base of two methods. The first method is non-linear conversion of powerful laser generation from the visible region into the deep ultraviolet region. The second method is direct UV laser action on ion and atomic transitions of different metals.

Rapid modulation of ultraviolet shielding in plants is influenced by solar ultraviolet radiation and linked to alterations in flavonoids.

PubMed

Barnes, Paul W; Tobler, Mark A; Keefover-Ring, Ken; Flint, Stephan D; Barkley, Anne E; Ryel, Ronald J; Lindroth, Richard L

2016-01-01

The accumulation of ultraviolet (UV)-absorbing compounds (flavonoids and related phenylpropanoids) and the resultant decrease in epidermal UV transmittance (TUV ) are primary protective mechanisms employed by plants against potentially damaging solar UV radiation and are critical components of the overall acclimation response of plants to changing solar UV environments. Whether plants can adjust this UV sunscreen protection in response to rapid changes in UV, as occurs on a diurnal basis, is largely unexplored. Here, we use a combination of approaches to demonstrate that plants can modulate their UV-screening properties within minutes to hours, and these changes are driven, in part, by UV radiation. For the cultivated species Abelmoschus esculentus, large (30-50%) and reversible changes in TUV occurred on a diurnal basis, and these adjustments were associated with changes in the concentrations of whole-leaf UV-absorbing compounds and several quercetin glycosides. Similar results were found for two other species (Vicia faba and Solanum lycopersicum), but no such changes were detected in Zea mays. These findings reveal a much more dynamic UV-protection mechanism than previously recognized, raise important questions concerning the costs and benefits of UV-protection strategies in plants and have practical implications for employing UV to enhance crop vigor and quality in controlled environments. © 2015 John Wiley & Sons Ltd.

Graphene Oxide Transparent Hybrid Film and Its Ultraviolet Shielding Property.

PubMed

Xie, Siyuan; Zhao, Jianfeng; Zhang, Bowu; Wang, Ziqiang; Ma, Hongjuan; Yu, Chuhong; Yu, Ming; Li, Linfan; Li, Jingye

2015-08-19

Herein, we first reported a facile strategy to prepare functional Poly(vinyl alcohol) (PVA) hybrid film with well ultraviolet (UV) shielding property and visible light transmittance using graphene oxide nanosheets as UV-absorber. The absorbance of ultraviolet light at 300 nm can be up to 97.5%, while the transmittance of visible light at 500 nm keeps 40% plus. This hybrid film can protect protein from UVA light induced photosensitive damage, remarkably.

Effect of Lot Variability on Ultraviolet Radiation Inactivation Kinetics of Cryptosporidium parvum Oocysts

EPA Science Inventory

Numerous studies have demonstrated the efficiency of ultraviolet (UV) radiation for the inactivation of oocysts of Cryptosporidium parvum. In these studies inactivation is measured as reduction in oocysts. A primary goal is to estimate the UV radiation required to achiev...

Ultraviolet-C light inactivation of Penicillium expansum on fruit surfaces

USDA-ARS?s Scientific Manuscript database

Understanding the influence of fruit surface morphology on ultraviolet-C (UV-C 254 nm) inactivation of microorganisms is required for designing effective treatment systems. In this study, we analyzed UV-C inactivation of Penicillium expansum that was inoculated onto the surface of organic fruits. Re...

LOW PRESSURE ULTRAVIOLET STUDIES FOR INACTIVIATION OF GIARDIA MURIS CYSTS

EPA Science Inventory

This research was initiated to confirm and expand the current database for the inactiviation of Giardia spp. using ultraviolet (UV) radiation. The path taken was to confirm earlier UV research that used excystation as the indication of viability. In this study, an in vitro excyst...

Establishing a ultraviolet radiation observational network and enhancing the study on ultraviolet radiation

NASA Astrophysics Data System (ADS)

Bai, Jianhui; Wang, Gengchen

2003-09-01

On the basis of analyzing observational data on solar radiation, meteorological parameters, and total ozone amount for the period of January 1990 to December 1991 in the Beijing area, an empirical calculation method for ultraviolet radiation (UV) in clear sky is obtained. The results show that the calculated values agree well with the observed, with maximum relative bias of 6.2% and mean relative bias for 24 months of 1.9%. Good results are also obtained when this method is applied in Guangzhou and Mohe districts. The long-term variation of UV radiation in clear sky over the Beijing area from 1979 to 1998 is calculated, and the UV variation trends and causes are discussed: direct and indirect UV energy absorption by increasing pollutants in the troposphere may have caused the UV decrease in clear sky in the last 20 years. With the enhancement of people’s quality of life and awareness of health, it will be valuable and practical to provid UV forecasts for typical cities and rural areas. So, we should develop and enhance UV study in systematic monitoring, forecasting, and developing a good and feasible method for UV radiation reporting in China, especially for big cities.

Extreme ultraviolet explorer satellite observation of Jupiter's Io plasma torus

NASA Technical Reports Server (NTRS)

Hall, D. T; Gladstone, G. R.; Moos, H. W.; Bagenal, F.; Clarke, J. T.; Feldman, P. D.; Mcgrath, M. A.; Schneider, N. M.; Shemansky, D. E.; Strobel, D. F.

1994-01-01

We present the first Extreme Ultraviolet Explorer (EUVE) satellite observation of the Jupiter system, obtained during the 2 day period 1993 March 30 through April 1, which shows a rich emission-line spectrum from the Io plasma torus spanning wavelengths 370 to 735 A. The emission features correspond primarily to known multiplets of oxygen and sulfur ions, but a blended feature near 372 A is a plausible Na II transition. The summed detected energy flux of (7.2 +/- 0.2) x 10(exp -11) ergs/sq cm(s) corresponds to a radiated power of approximately equal to 4 x 10(exp 11) W in this spectral range. All ansa emissions show a distinct dawn-dusk brightness asymmetry and the measured dusk/dawn ratio of the bright S III lambda-680 feature is 2.3 +/- 0.3, significantly larger than the ratio measured by the Voyager spacecraft ultraviolet (UV) instruments. A preliminary estimate of ion partitioning indicates that the oxygen/sulfur ion ratio is approximately equal to 2, compared to the value approximately equal to 1.3 measured by Voyager, and that (Na(+))/(e) greater than 0.01.

Experimental realization of a polarization-independent ultraviolet/visible coaxial plasmonic metamaterial.

PubMed

van de Haar, M A; Maas, R; Schokker, H; Polman, A

2014-11-12

We report the experimental realization of an optical metamaterial composed of a hexagonal array of coaxial plasmonic metal/insulator/metal waveguides that shows strong polarization-independent optical mode index dispersion in the ultraviolet/blue. The metamaterial is composed of silicon coaxes with a well-defined diameter in the range of 150-168 nm with extremely thin sidewalls (13-15 nm), embedded in a silver film, fabricated using a combination of electron beam lithography, physical vapor deposition, reactive ion etching, and focused ion beam polishing. Using a Mach-Zehnder interferometer the phase advance is measured on several metamaterial samples with different dimensions in the UV/visible part of the spectrum. For all geometries the spectral features as well as the geometry dependence of the data correspond well with numerical finite-difference time domain simulations and the calculated waveguide dispersion diagram, showing a negative mode index between 440 and 500 nm.

Observations of two peculiar emission objects in the Large Magellanic Cloud

NASA Technical Reports Server (NTRS)

Kafatos, M.; Michalitsianos, A. G.; Allen, D. A.; Stencel, R. E.

1983-01-01

Ultraviolet and visual wavelength spectra were obtained of two peculiar emission objects, Henize S63 and Sanduleak's star in the Large Magellanic Cloud. Previously not observed in the near- or far-ultraviolet, both objects exhibit strong permitted and semiforbidden line emissions. Estimates based on the absolute continuum flux of the hot companion star in Hen S63 indicate that it rivals the luminosity of the carbon star primary. The emission-line profile structure in both objects does not suggest Wolf-Rayet type emission. Carbon in Sanduleak's star (LMC anonymous) is conspicuously absent, while N V, semiforbidden N IV, and semiforbidden N III dominate the UV emission-line spectrum. Nitrogen is overabundant with respect to carbon and oxygen in both objects. The large overabundance of nitrogen in Sanduleak's star suggests evidence for CNO processes material similar to that seen in Nu Car.

Skylab ultraviolet stellar spectra - A new white dwarf, HD 149499 B

NASA Technical Reports Server (NTRS)

Parsons, S. B.; Wray, J. D.; Benedict, G. F.; Henize, K. G.; Laget, M.

1976-01-01

The letter reports the discovery of a cool star with excess brightness in the vacuum ultraviolet on an objective-prism photograph obtained during the second Skylab mission. This star, HD 149499, is of type K0 V and has a companion with an apparent magnitude of about 11.8; the relatively flat UV spectrum observed at the position of HD 149499 is characteristic of a 10th or 11th magnitude unreddened O- or early B-type star. It is shown that the excess VUV brightness is due to the companion, HD 149499B, which probably lies in the region of the H-R diagram occupied by the hot white dwarfs. Inspection of white dwarf lists indicates that this star is the sixth or seventh brightest white dwarf known. A maximum orbital motion of 0.025 arcsec/yr is estimated along with a period of just under 500 yr.

UV-B Measurements in Mexico City: Comparison with Modeled UVB and Black Carbon

NASA Astrophysics Data System (ADS)

Marley, N. A.; Gaffney, J. S.; Frederick, J. E.

2004-12-01

Ultraviolet-B radiation (UV-B) represents a chemically important region of the sun's spectrum. At the earth's surface, UV-B can initiate a number of important photochemical reactions (e.g., ozone photolysis) that lead to the formation of OH radicals. Where levels of nitrogen oxides are high and reactive hydrocarbons are found, as in Mexico City and other megacities, UV-B can initiate photochemical smog formation. We used a broadband instrument to obtain UV-B measurements in Mexico City during the Mexico City Metropolitan Area 2003/Mexico City Megacity 2003 field study. We then used a simple radiation model for the Mexico City latitude, altitude, and time of year to construct UV-B contours for comparison with our results. Early morning discrepancies involve reductions in UV-B that are consistent with the presence of significant levels of BC in the Mexico City environment. During most afternoons, UV-B reductions were dominated by clouds. The results are discussed in terms of the potential impacts of BC on UV-B and downwind photochemical processes. The authors wish to thank the researchers at Centro Nacional de Investigación en Calidad Ambiental (CENICA), Mexico City. This work was supported by the U.S. Department of Energy, Atmospheric Science Program (Marley and Gaffney), and the U.S. Environmental Protection Agency (Frederick). We also wish to acknowledge Drs. Mario and Luisa Molina for their help in organizing and directing the Mexico City Metropolitan Area 2003 field study, during which these data were collected.

Effects of ultraviolet radiation on 25-hydroxyvitamin D3 synthesis in red-eared slider turtles (Trachemys scripta elegans).

PubMed

Acierno, Mark J; Mitchell, Mark A; Roundtree, Marlana K; Zachariah, Trevor T

2006-12-01

To determine whether there are increased concentrations of 25-hydroxyvitaminn D(3) in red-eared slider turtles (Trachemys scripta elegans) after exposure to UV radiation. 12 yearling turtles recently removed from aestivation. Turtles were randomly allocated to 2 groups (6 turtles/group). An initial blood sample was collected from all turtles for measurement of 25-hydroxyvitamin D(3) concentrations. Turtles of 1 group were then provided no supplemental lighting, whereas turtles of the other group were exposed to full-spectrum coil bulbs at a distance of 22.86 cm. The UV-A and UV-B radiation generated by the supplemental lighting was measured by use of a radiometer-photometer at weekly intervals. Measurements were collected 2.54 and 22.86 cm from the bulb surface. The study was continued for a 4-week period. At the end of the study, a second blood sample was collected from all turtles for measurement of 25-hydroxyvitamin D(3). Mean +/- SD 25-hydroxyvitamin D(3) concentrations differed significantly between turtles provided supplemental UV radiation (71.7 +/- 46.9 nmol/L) and those not provided UV radiation (31.4 +/- 13.2 nmol/L). Appropriate husbandry recommendations for raising and maintaining red-eared slider turtles should include use of sunlight that is unobstructed by UV-B filtering material or provision of an artificial source of UV-B radiation.

Efficient room temperature hydrogen sensor based on UV-activated ZnO nano-network

NASA Astrophysics Data System (ADS)

Kumar, Mohit; Kumar, Rahul; Rajamani, Saravanan; Ranwa, Sapana; Fanetti, Mattia; Valant, Matjaz; Kumar, Mahesh

2017-09-01

Room temperature hydrogen sensors were fabricated from Au embedded ZnO nano-networks using a 30 mW GaN ultraviolet LED. The Au-decorated ZnO nano-networks were deposited on a SiO2/Si substrate by a chemical vapour deposition process. X-ray diffraction (XRD) spectrum analysis revealed a hexagonal wurtzite structure of ZnO and presence of Au. The ZnO nanoparticles were interconnected, forming nano-network structures. Au nanoparticles were uniformly distributed on ZnO surfaces, as confirmed by FESEM imaging. Interdigitated electrodes (IDEs) were fabricated on the ZnO nano-networks using optical lithography. Sensor performances were measured with and without UV illumination, at room temperate, with concentrations of hydrogen varying from 5 ppm to 1%. The sensor response was found to be ˜21.5% under UV illumination and 0% without UV at room temperature for low hydrogen concentration of 5 ppm. The UV-photoactivated mode enhanced the adsorption of photo-induced O- and O2- ions, and the d-band electron transition from the Au nanoparticles to ZnO—which increased the chemisorbed reaction between hydrogen and oxygen. The sensor response was also measured at 150 °C (without UV illumination) and found to be ˜18% at 5 ppm. Energy efficient low cost hydrogen sensors can be designed and fabricated with the combination of GaN UV LEDs and ZnO nanostructures.

An optimal thermal evaporation synthesis of c-axis oriented ZnO nanowires with excellent UV sensing and emission characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saha, Tridib, E-mail: tridib.saha@monash.edu; Achath Mohanan, Ajay, E-mail: ajay.mohanan@monash.edu; Swamy, Varghese, E-mail: varghese.swamy@monash.edu

Highlights: • c-Axis alignment of ZnO nanowires was optimized using self-seeding thermal evaporation method. • Influence of purified air on the morphology and optoelectronic properties were studied. • Nanowires grown under optimal conditions exhibit strong UV emission peak in PL spectrum. • Optimized growth condition establish nanowires of excellent UV sensing characteristics - Abstract: Well-aligned (c-axis oriented) ZnO nanowire arrays were successfully synthesized on Si (1 0 0) substrates through an optimized self-seeding thermal evaporation method. An open-ended chemical vapor deposition (CVD) setup was used in the experiment, with argon and purified air as reaction gases. Epitaxial growth of c-axismore » oriented ZnO nanowires was observed for 5 sccm flow rate of purified air, whereas Zn/Zn suboxide layers and multiple polycrystalline layers of ZnO were obtained for absence and excess of purified air, respectively. Ultraviolet (UV) sensing and emission properties of the as-grown ZnO nanostructures were investigated through the current–voltage (I–V) characteristics of the nanowires under UV (λ = 365 nm) illumination of 8 mW/cm{sup 2} and using photoluminescence spectra. Nanowires grown under optimum flow of air emitted four times higher intensity of 380 nm UV light as well as exhibited 34 times higher UV radiation sensitivity compared to that of other nanostructures synthesized in this study.« less

QUALITY ASSURANCE AND SITE MANAGEMENT FOR PRIMENET AND URBAN ULTRAVIOLET RADIATION RESEARCH MONITORING PROGRAM.

EPA Science Inventory

Because exposure to ultraviolet (UV) radiation is an ecosystem stressor and poses a human health risk, the National Exposure Research Laboratory (NERL) has undertaken a research program to measure the intensity of UV-B radiation at various locations throughout the U.S. In Septem...

Extending the use of ultraviolet light for fruit quality sorting in citrus packinghouses

USDA-ARS?s Scientific Manuscript database

Illumination with ultraviolet light (UV) is commonly used in citrus packinghouses as a means to aid in the identification and removal of decayed oranges from the packline. This technique is effective because areas of decay strongly fluoresce under UV illumination. It was observed that oranges often ...

QUANTIFYING ULTRAVIOLET RADIATION DOSE RELATIVE TO WETLAND HABITAT VARIABLES FOR THE ASSESSMENT OF RISK TO AMPHIBIANS

EPA Science Inventory

Ultraviolet B radiation (UV-B) has increased globally over the last several decades due to reduction of stratospheric ozone. UV-B may also increase when climate change alters cloud cover, rainfall, and distributions of vegetation. In aquatic systems, these factors can also intera...

ASSESSING THE EFFECTIVENESS OF LOW PRESSURE ULTRAVIOLET LIGHT FOR INACTIVATING HELICOBACTER PYLORI

EPA Science Inventory

Three strains of Helicobacter pylori were exposed to ultraviolet (UV) light from a low-pressure source to determine log inactivation versus applied fluence. Results indicate that H. pylori is readily inactivated at UV fluences typically used in water treatment r...

The influence of oxidation reduction potential and water treatment processes on quartz lamp sleeve fouling in ultraviolet disinfection reactors.

PubMed

Wait, Isaac W; Johnston, Cliff T; Blatchley, Ernest R

2007-06-01

Ultraviolet (UV) disinfection systems are incorporated into drinking water production facilities because of their broad-spectrum antimicrobial capabilities, and the minimal disinfection by-product formation that generally accompanies their use. Selection of an optimal location for a UV system within a drinking water treatment facility depends on many factors; a potentially important consideration is the effect of system location on operation and maintenance issues, including the potential for fouling of quartz surfaces. To examine the effect of system location on fouling, experiments were conducted at a groundwater treatment facility, wherein aeration, chlorination, and sand filtration were applied sequentially for treatment. In this facility, access to the water stream was available prior to and following each of the treatment steps. Therefore, it was possible to examine the effects of each of these unit operations on fouling dynamics within a UV system. Results indicated zero-order formation kinetics for the fouling reactions at all locations. Increases in oxidation reduction potential, caused by water treatment steps such as aeration and chlorination, increased the rate of sleeve fouling and the rate of irradiance loss within the reactor. Analysis of metals in the sleeve foulant showed that calcium and iron predominate, and relative comparisons of foulant composition to water chemistry highlighted a high affinity for incorporation into the foulant matrix for both iron and manganese, particularly after oxidizing treatment steps. Fouling behavior was observed to be in qualitative agreement with representations of the degree of saturation, relative to the metal:ligand combinations that are believed to comprise a large fraction of the foulants that accumulate on the surfaces of quartz jackets in UV systems used to treat water.

Space qualification of IR-reflecting coverslides for GaAs solar cells

NASA Technical Reports Server (NTRS)

Meulenberg, Andrew

1995-01-01

Improvements to GaAs solar array performance, from the use on solar cell coverslides of several reflecting coatings that reject unusable portions of the solar spectrum, are quantified. Blue-red-rejection (BRR) coverslides provide both infrared reflection (IRR) and ultraviolet rejection (UVR). BRR coverslides were compared to conventional antireflection (AR) and ultraviolet (UV) coated coverslides. A 2% improvement in peak-power output, relative to that from Ar-coated coverslides, is seen for cells utilizing BRR coverslides with the widest bandpass. Coverslide BRR-filter bandpass width and covered-solar-cell short-circuit current is a function of incident light angle and the observed narrower-bandpass filters are more sensitive to change in angle from the normal than are wide-bandpass filters. The first long-term (3000 hours) UV testing of unirradiated and 1 MeV electron-irradiated GaAs solar cells, with multilayer-coated coverslides to reduce solar array operating temperature, has indicated that all multilayer coatings on coverslides and solar cells will experience degradation from the space environment (UV and/or electrons). Five types of coverslide coatings, designed for GaAs solar cells, were tested as part of a NASA-sponsored space-flight qualification for BRR, multi-layer-coated, coverslides. The reponse to the different radiations varied with the coatings. The extent of degradation and its consequences on the solar cell electrical characteristics depend upon the coatings and the radiation. In some cases, an improved optical coupling was observed during long-term UV exposure to the optical stack. The benefits of multi-layered solar cell optics may depend upon both the duration and the radiation environment of a mission.

Artist concept of Solar Backscatter UV (SBUV) measurement technique on TIROS

NASA Technical Reports Server (NTRS)

1989-01-01

Artist concept titled OZONE MEASUREMENT TECHNIQUE shows how the Solar Backscatter Ultraviolet (UV) 2 (SBUV-2) on the National Oceanic and Atmospheric Administration's (NOAA's) TIROS satellites (NOAA-9 and NOAA-11) works. Ozone is derived from the 'SBUV' instrument from the ratio of the observed backscattered radiance to the solar irradiance in the ultraviolet. This is called the ultraviolet albedo. During STS-34 Shuttle Solar Backscatter Ultraviolet (SSBUV) instruments in Atlantis', Orbiter Vehicle (OV) 104's, payload bay (PLB) will calibrate the instruments onboard the TIROS satellites. SSBUV is managed by Goddard Space Flight Center (GSFC).

REPRESSOR OF ULTRAVIOLET-B PHOTOMORPHOGENESIS function allows efficient phototropin mediated ultraviolet-B phototropism in etiolated seedlings.

PubMed

Vanhaelewyn, Lucas; Schumacher, Paolo; Poelman, Dirk; Fankhauser, Christian; Van Der Straeten, Dominique; Vandenbussche, Filip

2016-11-01

Ultraviolet B (UV-B) light is a part of the solar radiation which has significant effects on plant morphology, even at low doses. In Arabidopsis, many of these morphological changes have been attributed to a specific UV-B receptor, UV resistance locus 8 (UVR8). Recent findings showed that next to phototropin regulated phototropism, UVR8 mediated signaling is able of inducing directional bending towards UV-B light in etiolated seedlings of Arabidopsis, in a phototropin independent manner. In this study, kinetic analysis of phototropic bending was used to evaluate the relative contribution of each of these pathways in UV-B mediated phototropism. Diminishing UV-B light intensity favors the importance of phototropins. Molecular and genetic analyses suggest that UV-B is capable of inducing phototropin signaling relying on phototropin kinase activity and regulation of NPH3. Moreover, enhanced UVR8 responses in the UV-B hypersensitive rup1rup2 mutants interferes with the fast phototropin mediated phototropism. Together the data suggest that phototropins are the most important receptors for UV-B induced phototropism in etiolated seedlings, and a RUP mediated negative feedback pathway prevents UVR8 signaling to interfere with the phototropin dependent response. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Intercalation of anionic organic ultraviolet ray absorbers into layered zinc hydroxide nitrate.

PubMed

Cursino, Ana Cristina Trindade; Gardolinski, José Eduardo Ferreira da Costa; Wypych, Fernando

2010-07-01

Layered zinc hydroxide nitrate (ZHN) was synthesized and nitrate ions were topotactically exchanged with three different anionic species of commercial organic ultraviolet (UV) ray absorbers: 2-mercaptobenzoic acid, 2-aminobenzoic acid, and 4-aminobenzoic acid. The exchange reactions were confirmed by X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR), ultraviolet visible (UV-Vis) spectroscopy, and thermal analysis (thermogravimetry, TGA, and differential thermal analysis, DTA). In all the anionic exchanged products, evidence of grafting of the organic species onto the inorganic matrix was obtained. In general, after intercalation/grafting, the UV absorption ability was improved in relation to the use of the parent organic material, showing that layered hydroxide salts (LHS) can be good alternative matrixes for the immobilization of organic species with UV-blocking properties in cosmetic products. Copyright 2010 Elsevier Inc. All rights reserved.

Discovery of novel solid solution Ca3Si3-x O3+x N4-2x : Eu2+ phosphors: structural evolution and photoluminescence tuning.

PubMed

Wang, Baochen; Liu, Yan-Gai; Huang, Zhaohui; Fang, Minghao; Wu, Xiaowen

2017-12-22

Discovery of novel phosphors is one of the main issues for improving the color rendering index (CRI) and correlated color temperature (CCT) of white light-emitting diodes (w-LEDs). This study mainly presents a systematic research on the synthesis, crystal structure variation and photoluminescence tuning of novel (oxy)nitride solid solution Ca 3 Si 3-x O 3+x N 4-2x : Eu 2+ phosphors. XRD refinements show that lattice distortion occurs when x value diverges the optimum one (x = 1). The lattice distortion causes a widening of emission spectrum and an increase of Stokes shift (ΔSS), which leads to a bigger thermal quenching. With decrease of x value, the emission spectrum shows an obvious red-shift from 505.2 to 540.8 nm, which is attributed to the crystal field splitting. The enhanced crystal field splitting also broadens the excitation spectrum, making it possible to serve as the phosphor for near ultraviolet (n-UV) LEDs. A 3-phosphor-conversion w-LED lamp was fabricated with the as-prepared phosphor, which exhibits high CRI (Ra = 85.29) and suitable CCT (4903.35 K). All these results indicate that the Ca 3 Si 3-x O 3+x N 4-2x : Eu 2+ phosphor can serve as the green phosphor for n-UV w-LEDs, with a tunable spectrum by controlling the crystal structure and morphology.

The Xenon Test Chamber Q-SUN® for testing realistic tolerances of fungi exposed to simulated full spectrum solar radiation.

PubMed

Dias, Luciana P; Araújo, Claudinéia A S; Pupin, Breno; Ferreira, Paulo C; Braga, Gilberto Ú L; Rangel, Drauzio E N

2018-06-01

The low survival of insect-pathogenic fungi when used for insect control in agriculture is mainly due to the deleterious effects of ultraviolet radiation and heat from solar irradiation. In this study, conidia of 15 species of entomopathogenic fungi were exposed to simulated full-spectrum solar radiation emitted by a Xenon Test Chamber Q-SUN XE-3-HC 340S (Q-LAB ® Corporation, Westlake, OH, USA), which very closely simulates full-spectrum solar radiation. A dendrogram obtained from cluster analyses, based on lethal time 50 % and 90 % calculated by Probit analyses, separated the fungi into three clusters: cluster 3 contains species with highest tolerance to simulated full-spectrum solar radiation, included Metarhizium acridum, Cladosporium herbarum, and Trichothecium roseum with LT 50  > 200 min irradiation. Cluster 2 contains eight species with moderate UV tolerance: Aschersonia aleyrodis, Isaria fumosorosea, Mariannaea pruinosa, Metarhizium anisopliae, Metarhizium brunneum, Metarhizium robertsii, Simplicillium lanosoniveum, and Torrubiella homopterorum with LT 50 between 120 and 150 min irradiation. The four species in cluster 1 had the lowest UV tolerance: Lecanicillium aphanocladii, Beauveria bassiana, Tolypocladium cylindrosporum, and Tolypocladium inflatum with LT 50  < 120 min irradiation. The QSUN Xenon Test Chamber XE3 is often used by the pharmaceutical and automotive industry to test light stability and weathering, respectively, but it was never used to evaluate fungal tolerance to full-spectrum solar radiation before. We conclude that the equipment provided an excellent tool for testing realistic tolerances of fungi to full-spectrum solar radiation of microbial agents for insect biological control in agriculture. Copyright © 2018 British Mycological Society. Published by Elsevier Ltd. All rights reserved.

Middle UV to near-IR spectrum of electron-excited SO2

USGS Publications Warehouse

Ajello, J.M.; Aguilar, A.; Mangina, R.S.; James, G.K.; Geissler, P.; Trafton, L.

2008-01-01

We investigated the electron impact–induced fluorescence spectrum of SO2 to provide excitation cross sections for modeling Io's emission spectrum and analyzing Cassini Imaging Science Subsystem observations. The electron-excited middle-ultraviolet visible optical near-infrared (VOIR) emission spectrum of SO2 gas was generated in the laboratory and studied from 2000 to 11,000 Å at a resolution of Δλ ∼ 2.5 Å full width at half maximum (FWHM). The VOIR laboratory spectrum longward of 6000 Å consists entirely of S I, II and O I, II multiplets for electron impact energies above ∼15 eV. Between 2000 and 6000 Å, we find previously identified molecular bands from both SO and SO2. This work represents a significant improvement in spectral resolution over our earlier work done at 18 Å FWHM. From a measurement of the medium-resolution spectrum, we provide detailed 25- and 100-eV emission cross sections for spectral features from 2000 to 11,000 Å. On the basis of these data, we suggest future ground-based and satellite telescopic observations in the VOIR that are of promise for understanding Io's atmosphere.

Middle UV to Near-IR Spectrum of Electron-Excited SO2

NASA Technical Reports Server (NTRS)

Ajello, Joseph M.; Aguilar, Alejandro; Mangina, Rao S.; James, Geoffrey K.; Geissler, Paul; Trafton, Laurence

2008-01-01

We investigated the electron impact-induced fluorescence spectrum of SO2 to provide excitation cross sections for modeling Io's mission spectrum and analyzing Cassini Imaging Science Subsystem observations. The electron-excited middle-ultraviolet visible optical near-infrared (VOIR) emission spectrum of SO2 gas was generated in the laboratory and studied from 2000 to 11,000 A at a resolution of (Delta)(lamda) approximately 2.5 A full width at half maximum (FWHM). The VOIR laboratory spectrum longward of 6000 A consists entirely of S I, II and O I, II multiplets for electron impact energies above approximately 15 eV. Between 2000 and 6000 A, we find previously identified molecular bands from both SO and SO2. This work represents a significant improvement in spectral resolution over our earlier work done at 18 A FWHM. From a measurement of the medium-resolution spectrum, we provide detailed 25- and 100-eV emission cross sections for spectral features from 2000 to 11,000 A . On the basis of these data, we suggest future ground-based and satellite telescopic observations in the VOIR that are of promise for understanding Io's atmosphere.

Ultraviolet spectrophotometry of three LINERs

NASA Technical Reports Server (NTRS)

Goodrich, R. W.; Keel, W. C.

1986-01-01

Three galaxies known to be LINERs were observed spectroscopically in the ultraviolet in an attempt to detect the presumed nonthermal continuum source thought to be the source of photoionization in the nuclei. NGC 4501 was found to be too faint for study with the IUE spectrographs, while NGC 5005 had an extended ultraviolet light profile. Comparison with the optical light profile of NGC 5005 indicates that the ultraviolet source is distributed spatially in the same manner as the optical starlight, probably indicating that the ultraviolet excess is due to a component of hot stars in the nucleus. These stars contribute detectable absorption features longward of 2500 A; together with optical data, the IUE spectra suggest a burst of star formation about 1 billion yr ago, with a lower rate continuing to produce a few OB stars. In NGC 4579, a point source contributing most of the ultraviolet excess is found that is much different than the optical light distribution. Furthermore, the ultraviolet to X-ray spectral index in NGC 4579 is 1.4, compatible with the UV to X-ray indices found for samples of Seyfert galaxies. This provides compelling evidence for the detection of the photoionizing continuum in NGC 4579 and draws the research fields of normal galaxies and active galactic nuclei closer together. The emission-line spectrum of NGC 4579 is compared with calculations from a photoionization code, CLOUDY, and several shock models. The photoionization code is found to give superior results, adding to the increasing weight of evidence that the LINER phenomenon is essentially a scaled-down version of the Seyfert phenomenon.

Microwave assisted scalable synthesis of titanium ferrite nanomaterials

NASA Astrophysics Data System (ADS)

Shukla, Abhishek; Bhardwaj, Abhishek K.; Singh, S. C.; Uttam, K. N.; Gautam, Nisha; Himanshu, A. K.; Shah, Jyoti; Kotnala, R. K.; Gopal, R.

2018-04-01

Titanium ferrite magnetic nanomaterials are synthesized by one-step, one pot, and scalable method assisted by microwave radiation. Effects of titanium content and microwave exposure time on size, shape, morphology, yield, bonding nature, crystalline structure, and magnetic properties of titanium ferrite nanomaterials are studied. As-synthesized nanomaterials are characterized by X-ray diffraction (XRD), ultraviolet-visible absorption spectroscopy (UV-Vis), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), Raman spectroscopy, transmission electron microscopy (TEM), and vibrating sample magnetometer measurements. XRD measurements depict the presence of two phases of titanium ferrite into the same sample, where crystallite size increases from ˜33 nm to 37 nm with the increase in titanium concentration. UV-Vis measurement showed broad spectrum in the spectral range of 250-600 nm which reveals that its characteristic peaks lie between ultraviolet and visible region; ATR-FTIR and Raman measurements predict iron-titanium oxide structures that are consistent with XRD results. The micrographs of TEM and selected area electron diffraction patterns show formation of hexagonal shaped particles with a high degree of crystallinity and presence of multi-phase. Energy dispersive spectroscopy measurements confirm that Ti:Fe compositional mass ratio can be controlled by tuning synthesis conditions. Increase of Ti defects into titanium ferrite lattice, either by increasing titanium precursor or by increasing exposure time, enhances its magnetic properties.

New Fe i Level Energies and Line Identifications from Stellar Spectra. II. Initial Results from New Ultraviolet Spectra of Metal-poor Stars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, Ruth C.; Kurucz, Robert L.; Ayres, Thomas R., E-mail: peterson@ucolick.org

2017-04-01

The Fe i spectrum is critical to many areas of astrophysics, yet many of the high-lying levels remain uncharacterized. To remedy this deficiency, Peterson and Kurucz identified Fe i lines in archival ultraviolet and optical spectra of metal-poor stars, whose warm temperatures favor moderate Fe i excitation. Sixty-five new levels were recovered, with 1500 detectable lines, including several bound levels in the ionization continuum of Fe i. Here, we extend the previous work by identifying 59 additional levels, with 1400 detectable lines, by incorporating new high-resolution UV spectra of warm metal-poor stars recently obtained by the Hubble Space Telescope Imagingmore » Spectrograph. We provide gf values for these transitions, both computed as well as adjusted to fit the stellar spectra. We also expand our spectral calculations to the infrared, confirming three levels by matching high-quality spectra of the Sun and two cool stars in the H -band. The predicted gf values suggest that an additional 3700 Fe i lines should be detectable in existing solar infrared spectra. Extending the empirical line identification work to the infrared would help confirm additional Fe i levels, as would new high-resolution UV spectra of metal-poor turnoff stars below 1900 Å.« less

Augmentation of the IUE Ultraviolet Spectral Atlas

NASA Astrophysics Data System (ADS)

Wu, Chi-Chao

Most likely IUE is the only and last satellite which will support a survey program to record the ultraviolet spectrum of a large number of bright normal stars. It is important to have a library of high quality Low dispersion spectra of sufficient number of stars that provide good coverage in spectral type and luminosity class. Such a library is invaluable for stellar population synthesis of galaxies, studying the nature of distant galaxies, establishing a UV spectral classification system, providing comparison stars for interstellar extinction studies and for peculiar objects or binary systems, studying the effects of temperature, gravity and metallicity on stellar UV spectra, and as a teaching aid. We propose to continue observations of normal stars in order to provide (1) a more complete coverage of the spectral type and luminosity class, and (2) more than one star per spectral typeluminosity class combination to guard against variability and peculiarity, and to allow a finite range of temperature, gravity, and metallicity in a given combination. Our primary goal is to collect the data and make them available to the community immediately (without claiming the 6-month proprietary right). The data will be published in the IUE Newsletter as soon as practical, and the data will be prepared for distribution by the IUE Observatory and the NSSDC.

New Fe I Level Energies and Line Identifications from Stellar Spectra. II. Initial Results from New Ultraviolet Spectra of Metal-poor Stars

NASA Astrophysics Data System (ADS)

Peterson, Ruth C.; Kurucz, Robert L.; Ayres, Thomas R.

2017-04-01

The Fe I spectrum is critical to many areas of astrophysics, yet many of the high-lying levels remain uncharacterized. To remedy this deficiency, Peterson & Kurucz identified Fe I lines in archival ultraviolet and optical spectra of metal-poor stars, whose warm temperatures favor moderate Fe I excitation. Sixty-five new levels were recovered, with 1500 detectable lines, including several bound levels in the ionization continuum of Fe I. Here, we extend the previous work by identifying 59 additional levels, with 1400 detectable lines, by incorporating new high-resolution UV spectra of warm metal-poor stars recently obtained by the Hubble Space Telescope Imaging Spectrograph. We provide gf values for these transitions, both computed as well as adjusted to fit the stellar spectra. We also expand our spectral calculations to the infrared, confirming three levels by matching high-quality spectra of the Sun and two cool stars in the H-band. The predicted gf values suggest that an additional 3700 Fe I lines should be detectable in existing solar infrared spectra. Extending the empirical line identification work to the infrared would help confirm additional Fe I levels, as would new high-resolution UV spectra of metal-poor turnoff stars below 1900 Å.

ADVANCED OXIDATION PROCESS TECHNOLOGY (ULTRAVIOLET RADIATION/OZONE TREATMENT) FOR REMOVAL OF METHYL TERTIARY BUTYL ETHER (MTBE) IN GROUND WATER SUPPLIES.

EPA Science Inventory

U.S. EPA’s Office of Research and Development in Cincinnati, Ohio has been testing and evaluating MTBE removal in dechlorinated tap water using three oxidant combinations: hydrogen peroxide/ozone, ultraviolet irradiation (UV)/ozone, and UV/ozone/hydrogen peroxide. Pilot-scale st...

Spatial and Temporal Variability of Solar Ultraviolet Exposure of Coral Assemblages in the Florida Keys: Importance of Colored Dissolved Organic Matter x

EPA Science Inventory

Solar ultraviolet (UV) radiation can have deleterious effects on coral assemblages in tropical and subtropical marine environments, but little information is available on UV penetration into ocean waters surrounding corals. Here we provide an extensive data set of optical propert...

DISTRIBUTION PATTERNS OF LENTIC-BREEDING AMPHIBIANS IN RELATION OF ULTRAVIOLET RADIATION EXPOSURE IN WESTERN NORTH AMERICA

EPA Science Inventory

An increase in ultraviolet (UV-B) radiation has been posited to be a potential factor in the decline of some amphibian population...Much more work is still needed to determine whether UV-B, either alone or in concert with other factors, is causing widespread population losses in ...

The ultraviolet radiation environment of pollen and its effect on pollen germination

NASA Technical Reports Server (NTRS)

1981-01-01

The damage to pollen caused by natural ultraviolet radiation was investigated. Experimental and literature research into the UV radiation environment is reported. Viability and germination of wind and insect pollinated species were determined. Physiological, developmental, and protective factors influencing UV sensitivity of binucleate, advanced binucleate, and trinucleate pollen grains are compared.

Photosynthetically active radiation (PAR) x ultraviolet radiation (UV) interact to initiate solar injury in apple

USDA-ARS?s Scientific Manuscript database

Sunburn or solar injury (SI) in apple is associated with high temperature, high visible light and ultraviolet radiation (UV). Fruit surface temperature (FST) thresholds for SI related disorders have been developed but there are no thresholds established for solar radiation. The objectives of the s...

Effects of ultraviolet (UV) irradiation in air and under vacuum on low-k dielectrics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choudhury, F. A.; Nguyen, H. M.; Shohet, J. L., E-mail: shohet@engr.wisc.edu

This work addresses the effect of ultraviolet radiation of wavelengths longer than 250 nm on Si-CH{sub 3} bonds in porous low-k dielectrics. Porous low-k films (k = 2.3) were exposed to 4.9 eV (254 nm) ultraviolet (UV) radiation in both air and vacuum for one hour. Using Fourier Transform Infrared (FTIR) spectroscopy, the chemical structures of the dielectric films were analyzed before and after the UV exposure. UV irradiation in air led to Si-CH{sub 3} bond depletion in the low-k material and made the films hydrophilic. However, no change in Si-CH{sub 3} bond concentration was observed when the same samplesmore » were exposed to UV under vacuum with a similar fluence. These results indicate that UV exposures in vacuum with wavelengths longer than ∼250 nm do not result in Si-CH{sub 3} depletion in low-k films. However, if the irradiation takes place in air, the UV irradiation removes Si-CH{sub 3} although direct photolysis of air species does not occur above ∼242 nm. We propose that photons along with molecular oxygen and, water, synergistically demethylate the low-k films.« less

Comparative experimental and simulation studies of high-power AlGaN-based 353 nm ultraviolet flip-chip and top-emitting LEDs

NASA Astrophysics Data System (ADS)

Liu, Mengling; Zhou, Shengjun; Liu, Xingtong; Gao, Yilin; Ding, Xinghuo

2018-03-01

Experimental and simulation studies of high-power AlGaN-based 353 nm ultraviolet (UV) flip-chip (FC) and top-emitting (TE) light-emitting diodes (LEDs) are performed here. To improve the optical and electrical properties of ultraviolet LEDs, we fabricate high-power FC-UV LEDs with Ta2O5/SiO2 distributed Bragg reflectors (DBRs) and a strip-shaped SiO2 current blocking layer (CBL). The reflectance of fourteen pairs of Ta2O5/SiO2 DBRs is 96.4% at 353 nm. The strip-shaped SiO2 CBL underneath the strip-shaped p-electrode can prevent the current concentrating in regions immediately adjacent to the p-electrode where the overlying opaque p-electrode metal layer absorbs the emitted UV light. Moreover, two-level metallization electrodes are used to improve current spreading. Our numerical results show that FC-UV LED has a more favorable current spreading uniformity than TE-UV LED. The light output power of 353 nm FC-UV LED was 23.22 mW at 350 mA, which is 24.7% higher than that of TE-UV LED.

Emulsifying and foaming properties of ultraviolet-irradiated egg white protein and sodium caseinate.

PubMed

Kuan, Yau-Hoong; Bhat, Rajeev; Karim, Alias A

2011-04-27

The physicochemical and functional properties of ultraviolet (UV)-treated egg white protein (EW) and sodium caseinate (SC) were investigated. UV irradiation of the proteins was carried out for 30, 60, 90, and 120 min. However, the SC samples were subjected to extended UV irradiation for 4 and 6 h as no difference was found on the initial UV exposure time. Formol titration, SDS-PAGE, and FTIR analyses indicated that UV irradiation could induce cross-linking on proteins and led to improved emulsifying and foaming properties (P < 0.05). These results indicated that the UV-irradiated EW and SC could be used as novel emulsifier and foaming agents in broad food systems for stabilizing and foaming purposes.

Experimental ultraviolet photocarcinogenesis: wavelength interactions and time-dose relationships.

PubMed

Forbes, P D; Davies, R E; Urbach, F

1978-12-01

Tumors were induced in the skin of SKH hairless mice by exposure to fluorescent FS sun lamps or to a long-arc xenon solar simulator. Tumores developed about equally well with varying amounts of UV-A radiation (lambda greater than 320 nm) given simultaneously. In contrast, incremental changes in the UV-B region (lambda less than 320 nm) led to substantial increases in carcinogenic effectiveness. A tumor-"initiating" dose of UV-B (4-10 wk of daily FS lamp exposures) was rendered less effective by subsequent exposures of the mice to UV-A (6 hr/day, F-40 T12BL lamps). The mechanism for this effect is not known. Most tumors induced by a short course (10 wk) of FS lamp exposure grew slowly or regressed, whereas mice exposed for a longer period (30 wk) developed more tumors, and many of those that appeared early grew aggressively. Effects of daily dose fractionation were less clear, and the subject requires further study. These and other variables are being tested in a program designed to yield useful information on the effects of changing spectrum, dose, and dose delivery rates on sunlight-induced cancer.

Uncovering the Putative B-Star Binary Companion of the SN 1993J Progenitor

NASA Technical Reports Server (NTRS)

Fox, Ori D.; Bostroem, K. Azalee; Van Dyk, Schuyler D.; Filippenko, Alexei V.; Fransson, Claes; Matheson, Thomas; Cenko, S. Bradley; Chandra, Poonam; Dwarkadas, Vikram; Li, Weidong;

A critical assessment of two types of personal UV dosimeters.

PubMed

Seckmeyer, Gunther; Klingebiel, Marcus; Riechelmann, Stefan; Lohse, Insa; McKenzie, Richard L; Liley, J Ben; Allen, Martin W; Siani, Anna-Maria; Casale, Giuseppe R

2012-01-01

Doses of erythemally weighted irradiances derived from polysulphone (PS) and electronic ultraviolet (EUV) dosimeters have been compared with measurements obtained using a reference spectroradiometer. PS dosimeters showed mean absolute deviations of 26% with a maximum deviation of 44%, the calibrated EUV dosimeters showed mean absolute deviations of 15% (maximum 33%) around noon during several test days in the northern hemisphere autumn. In the case of EUV dosimeters, measurements with various cut-off filters showed that part of the deviation from the CIE erythema action spectrum was due to a small, but significant sensitivity to visible radiation that varies between devices and which may be avoided by careful preselection. Usually the method of calibrating UV sensors by direct comparison to a reference instrument leads to reliable results. However, in some circumstances the quality of measurements made with simple sensors may be over-estimated. In the extreme case, a simple pyranometer can be used as a UV instrument, providing acceptable results for cloudless skies, but very poor results under cloudy conditions. It is concluded that while UV dosimeters are useful for their design purpose, namely to estimate personal UV exposures, they should not be regarded as an inexpensive replacement for meteorological grade instruments. © 2011 Wiley Periodicals, Inc. Photochemistry and Photobiology © 2011 The American Society of Photobiology.

Strong composition dependence of adhesive properties of ultraviolet curing adhesives with modified acrylates

NASA Astrophysics Data System (ADS)

Feng, Yefeng; Li, Yandong; Wang, Fupeng; Peng, Cheng; Xu, Zhichao; Hu, Jianbing

2018-05-01

Ultraviolet (UV) curable adhesives have been widely researched in fields of health care and electronic components. UV curing systems with modified acrylic ester prepolymers have been frequently employed. In order to clarify composition dependence of adhesive properties of adhesives containing modified acrylates, in this work, several UV curing adhesives bearing urethane and epoxy acrylates were designed and fabricated. The effects of prepolymer, diluent, feed ratio, initiator and assistant on adhesive performances were investigated. This work might offer a facile route to gain promising high-performance UV curable adhesives with desired adhesive traits through regulating their compositions.

Ultraviolet spectroscopy of the blue supergiant SBW1: the remarkably weak wind of a SN 1987A analogue

NASA Astrophysics Data System (ADS)

Smith, Nathan; Groh, Jose H.; France, Kevin; McCray, Richard

2017-06-01

The Galactic blue supergiant SBW1 with its circumstellar ring nebula represents the best known analogue of the progenitor of SN 1987A. High-resolution imaging has shown Hα and infrared structures arising in an ionized flow that partly fills the ring's interior. To constrain the influence of the stellar wind on this structure, we obtained an ultraviolet (UV) spectrum of the central star of SBW1 with the Hubble Space Telescope Cosmic Origins Spectrograph. The UV spectrum shows none of the typical wind signatures, indicating a very low mass-loss rate. Radiative transfer models suggest an extremely low rate below 10-10 M⊙ yr-1, although we find that cooling time-scales probably become comparable to (or longer than) the flow time below 10-8 M⊙ yr-1. We therefore adopt this latter value as a conservative upper limit. For the central star, the model yields Teff = 21 000 ± 1000 K, log(geff) = 3.0, L ≃ 5 × 104 L⊙, and roughly Solar composition except for enhanced N abundance. SBW1's very low mass-loss rate may hinder the wind's ability to shape its nebula and to shed angular momentum. The spin-down time-scale for magnetic breaking is more than 500 times longer than the age of the ring. This, combined with the star's slow rotation rate, constrains merger scenarios to form ring nebulae. The mass-loss rate is at least 10 times lower than expected from mass-loss recipes, without any account of clumping. The physical explanation for why SBW1's wind is so weak presents an interesting mystery.

Photostability of commercial sunscreens upon sun exposure and irradiation by ultraviolet lamps

PubMed Central

Gonzalez, Helena; Tarras-Wahlberg, Nils; Strömdahl, Birgitta; Juzeniene, Asta; Moan, Johan; Larkö, Olle; Rosén, Arne; Wennberg, Ann-Marie

2007-01-01

Background Sunscreens are being widely used to reduce exposure to harmful ultraviolet (UV) radiation. The fact that some sunscreens are photounstable has been known for many years. Since the UV-absorbing ingredients of sunscreens may be photounstable, especially in the long wavelength region, it is of great interest to determine their degradation during exposure to UV radiation. Our aim was to investigate the photostability of seven commercial sunscreen products after natural UV exposure (UVnat) and artificial UV exposure (UVart). Methods Seven commercial sunscreens were studied with absorption spectroscopy. Sunscreen product, 0.5 mg/cm2, was placed between plates of silica. The area under the curve (AUC) in the spectrum was calculated for UVA (320–400 nm), UVA1 (340–400 nm), UVA2 (320–340 nm) and UVB (290–320 nm) before (AUCbefore) and after (AUCafter) UVart (980 kJ/m2 UVA and 12 kJ/m2 of UVB) and before and after UVnat. If theAUC Index (AUCI), defined as AUCI = AUCafter/AUCbefore, was > 0.80, the sunscreen was considered photostable. Results Three sunscreens were unstable after 90 min of UVnat; in the UVA range the AUCI was between 0.41 and 0.76. In the UVB range one of these sunscreens was unstable with an AUCI of 0.75 after 90 min. Three sunscreens were photostable after 120 min of UVnat; in the UVA range the AUCI was between 0.85 and 0.99 and in the UVB range between 0.92 and 1.0. One sunscreen showed in the UVA range an AUCI of 0.87 after UVnat but an AUCI of 0.72 after UVart. Five of the sunscreens were stable in the UVB region. Conclusion The present study shows that several sunscreens are photounstable in the UVA range after UVnat and UVart. There is a need for a standardized method to measure photostability, and the photostability should be marked on the sunscreen product. PMID:17324264

A new solar reference spectrum from 165 to 3088 nm

NASA Astrophysics Data System (ADS)

Damé, Luc; Meftah, Mustapha; Bolsée, David; Pereira, Nuno; Bekki, Slimane; Hauchecorne, Alain; Irbah, Abdenour; Cessateur, Gaël; Sluse, Dominique

2017-04-01

Since April 5, 2008 and until February 15, 2017 the SOLAR/SOLSPEC spectro-radiometer on the International Space Station performed accurate measurements of Solar Spectral Irradiance (SSI) from the far ultraviolet to the infrared (165 nm to 3088 nm). These measurements are of primary importance for a better understanding of solar physics and of the impact of solar variability on climate (via Earth's atmospheric photochemistry). In particular, a new reference solar spectrum is established covering most of the unusual solar cycle 24 from minimum in 2008 to maximum. Temporal variability in the UV (165 to 400 nm) is presented in several wavelengths bands. These results are possible thanks to revised engineering corrections, improved calibrations and new procedures to account for thermal and aging advanced corrections. Uncertainties on these measurements are evaluated and compare favorably with other instruments.

SLR digital camera for forensic photography

NASA Astrophysics Data System (ADS)

Har, Donghwan; Son, Youngho; Lee, Sungwon

2004-06-01

Forensic photography, which was systematically established in the late 19th century by Alphonse Bertillon of France, has developed a lot for about 100 years. The development will be more accelerated with the development of high technologies, in particular the digital technology. This paper reviews three studies to answer the question: Can the SLR digital camera replace the traditional silver halide type ultraviolet photography and infrared photography? 1. Comparison of relative ultraviolet and infrared sensitivity of SLR digital camera to silver halide photography. 2. How much ultraviolet or infrared sensitivity is improved when removing the UV/IR cutoff filter built in the SLR digital camera? 3. Comparison of relative sensitivity of CCD and CMOS for ultraviolet and infrared. The test result showed that the SLR digital camera has a very low sensitivity for ultraviolet and infrared. The cause was found to be the UV/IR cutoff filter mounted in front of the image sensor. Removing the UV/IR cutoff filter significantly improved the sensitivity for ultraviolet and infrared. Particularly for infrared, the sensitivity of the SLR digital camera was better than that of the silver halide film. This shows the possibility of replacing the silver halide type ultraviolet photography and infrared photography with the SLR digital camera. Thus, the SLR digital camera seems to be useful for forensic photography, which deals with a lot of ultraviolet and infrared photographs.

Photoluminescence in Sm3+ doped Ba2P2O7 phosphor prepared by solution combustion method

NASA Astrophysics Data System (ADS)

Ghawade, Sonal P.; Deshmukh, Kavita A.; Dhoble, S. J.; Deshmukh, Abhay D.

2018-05-01

In this paper, Sm3+ doped Ba2P2O7 phosphors were synthesized via a Solution combustion method. The crystal structure of the phosphor was characterized by XRD. Orange-red emission was observed from these phosphors under near-ultraviolet (UV) excitation at 404 nm. The luminescence properties of the obtained phosphors were characterized by different techniques. The Ba2P2O7:Sm3+ phosphor can be efficiently excited by near-UV and blue light, and their emission spectrum consists of three emission peaks, at 564, 602, and 646 nm, respectively. Based on the results, the as prepared Ba2P2O7:Sm3+ phosphors are promising orange-red-emitting phosphors exhibit great potential may be applicable as a spectral convertor in c-Si solar cell to enhance the efficiency of solar cell in future.

Ultraviolet Spectroscopy of Matrix-isolated Amorphous Carbon Particles

NASA Astrophysics Data System (ADS)

Schnaiter, M.; Mutschke, H.; Henning, Th.; Lindackers, D.; Strecker, M.; Roth, P.

1996-06-01

In view of the interstellar 217.5 nm and the circumstellar 230--250 nm extinction features, the UV extinction behavior of small matrix-isolated amorphous carbon grains is investigated experimentally. The particles were produced in a flame by burning acetylene with oxygen at low pressure. To prevent coagulation, the condensing primary soot grains (average diameter ~6 nm) were extracted by a molecular beam technique into a high-vacuum chamber. There they were deposited into a layer of solid argon, isolated from each other. The particle mass and size were controlled using a particle mass spectrometer. The measured UV extinction of the matrix-isolated particles is compared with measurements on samples produced in the conventional way by collecting carbon smoke on substrate as well as with scattering calculations for small spheres and ellipsoides. The laboratory data give a good representation of the circumstellar extinction feature observed in the spectrum of V348 Sgr.

XMM-Newton confirmation of a new intermediate polar: XMMU J185330.7-012815

NASA Astrophysics Data System (ADS)

Hui, C. Y.; Sriram, K.; Choi, C.-S.

2012-01-01

We report on the results of a detailed spectro-imaging and temporal analysis of an archival XMM-Newton observation of a new intermediate polar XMMU J185330.7-012815. Its X-ray spectrum can be well described by a multitemperature thermal plasma model with the K lines of heavy elements clearly detected. Possible counterparts of XMMU J185330.7-012815 have been identified in optical and ultraviolet (UV) bands. The low values of the inferred X-ray-to-UV and X-ray-to-optical flux ratios safely rule out the possibility of its being an isolated neutron star. We confirm the X-ray periodicity of ˜238 s but, differently from the previous preliminary results, we do not find any convincing evidence of phase shift in this observation. We further investigate its properties through an energy-resolved temporal analysis and find that the pulsed fraction monotonically increases with energy.

Ionization-induced solvent migration in acetanilide-methanol clusters inferred from isomer-selective infrared spectroscopy.

PubMed

Weiler, Martin; Nakamura, Takashi; Sekiya, Hiroshi; Dopfer, Otto; Miyazaki, Mitsuhiko; Fujii, Masaaki

2012-12-07

We present the resonance-enhanced multiphoton ionization, infrared-ultraviolet hole burning (IR-UV HB), and IR dip spectra of the trans-acetanilide-methanol (AA-MeOH) cluster in the S(0), S(1), and cationic ground state (D(0)) in a supersonic jet. The IR-UV HB spectra demonstrate the co-existence of two isomers in S(0,1), in which MeOH binds either to the NH or the CO site of the peptide linkage in AA, denoted as AA(NH)-MeOH and AA(CO)-MeOH. When AA(CO)-MeOH is selectively ionized, its IR spectrum in D(0) is the same as that measured for AA(+) (NH)-MeOH. Thus, photoionization of AA(CO)-MeOH induces migration of MeOH from the CO to the NH site with 100% yield. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

8 years of Solar Spectral Irradiance Observations from the ISS with the SOLAR/SOLSPEC Instrument

NASA Astrophysics Data System (ADS)

Damé, L.; Bolsée, D.; Meftah, M.; Irbah, A.; Hauchecorne, A.; Bekki, S.; Pereira, N.; Cessateur, G.; Marchand, M.; Thiéblemont, R.; Foujols, T.

2016-12-01

Accurate measurements of Solar Spectral Irradiance (SSI) are of primary importance for a better understanding of solar physics and of the impact of solar variability on climate (via Earth's atmospheric photochemistry). The acquisition of a top of atmosphere reference solar spectrum and of its temporal and spectral variability during the unusual solar cycle 24 is of prime interest for these studies. These measurements are performed since April 2008 with the SOLSPEC spectro-radiometer from the far ultraviolet to the infrared (166 nm to 3088 nm). This instrument, developed under a fruitful LATMOS/BIRA-IASB collaboration, is part of the Solar Monitoring Observatory (SOLAR) payload, externally mounted on the Columbus module of the International Space Station (ISS). The SOLAR mission, with its actual 8 years duration, will cover almost the entire solar cycle 24. We present here the in-flight operations and performances of the SOLSPEC instrument, including the engineering corrections, calibrations and improved know-how procedure for aging corrections. Accordingly, a SSI reference spectrum from the UV to the NIR will be presented, together with its UV variability, as measured by SOLAR/SOLSPEC. Uncertainties on these measurements and comparisons with other instruments will be briefly discussed.

DNA damage and repair in plants under ultraviolet and ionizing radiations.

PubMed

Gill, Sarvajeet S; Anjum, Naser A; Gill, Ritu; Jha, Manoranjan; Tuteja, Narendra

2015-01-01

Being sessile, plants are continuously exposed to DNA-damaging agents present in the environment such as ultraviolet (UV) and ionizing radiations (IR). Sunlight acts as an energy source for photosynthetic plants; hence, avoidance of UV radiations (namely, UV-A, 315-400 nm; UV-B, 280-315 nm; and UV-C, <280 nm) is unpreventable. DNA in particular strongly absorbs UV-B; therefore, it is the most important target for UV-B induced damage. On the other hand, IR causes water radiolysis, which generates highly reactive hydroxyl radicals (OH(•)) and causes radiogenic damage to important cellular components. However, to maintain genomic integrity under UV/IR exposure, plants make use of several DNA repair mechanisms. In the light of recent breakthrough, the current minireview (a) introduces UV/IR and overviews UV/IR-mediated DNA damage products and (b) critically discusses the biochemistry and genetics of major pathways responsible for the repair of UV/IR-accrued DNA damage. The outcome of the discussion may be helpful in devising future research in the current context.

Wavelength of ultraviolet radiation that enhances onset of clinical infectious bovine keratoconjunctivitis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kopecky, K.E.; Pugh, G.W. Jr.; Hughes, D.E.

1980-09-01

Cellulose acetate filtered ultraviolet (uv) radiation and unfiltered uv radiation were used on calves that were subsequently challenge exposed with Moraxella bovis. The onset, course, and severity of infectious bovine keratoconjunctivitis (IBK) were studied. Ten calves irradiated with unfiltered uv had the disease 1 to 2 days after M bovis challenge exposure. Ten calves irradiated with filtered uv and 10 calves not irradiated manifested IBK in a similar manner. Evidence is presented to support the contention that the wavelengths (around 270 nm) which are eliminated by cellulose acetate enhance the course of IBK. The effects on IBK of environmentally increasedmore » solar uv radiation is also discussed.« less

Investigation of Ultraviolet Light Curable Polysilsesquioxane Gate Dielectric Layers for Pentacene Thin Film Transistors.

PubMed

Shibao, Hideto; Nakahara, Yoshio; Uno, Kazuyuki; Tanaka, Ichiro

2016-04-01

Polysilsesquioxane (PSQ) comprising 3-methacryloxypropyl groups was investigated as an ultraviolet (UV)-light curable gate dielectric-material for pentacene thin film transistors (TFTs). The surface of UV-light cured PSQ films was smoother than that of thermally cured ones, and the pentacene layers deposited on the UV-Iight cured PSQ films consisted of larger grains. However, carrier mobility of the TFTs using the UV-light cured PSQ films was lower than that of the TFTs using the thermally cured ones. It was shown that the cross-linker molecules, which were only added to the UV-light cured PSQ films, worked as a major mobility-limiting factor for the TFTs.

Studies on Optical and Electrical Properties of Hafnium Oxide Nanoparticles

NASA Astrophysics Data System (ADS)

Jayaraman, Venkatachalam; Sagadevan, Suresh; Sudhakar, Rajesh

2017-07-01

In this paper, the synthesis and physico-chemical properties of hafnium oxide nanoparticles (HfO2 NPs) are analyzed and reported. The synthesis was carried out by the precipitation route by using hafnium tetrachloride (HfCl4) as precursor material with potassium hydroxide (KOH) dissolved in Millipore water. In the precipitation technique, the chemical reaction is comparatively simple, low-cost and non-toxic compared to other synthetic methods. The synthesized HfO2 NPs were characterized by using powder x-ray diffraction (PXRD), ultraviolet-visible (UV-Vis) spectroscopy, Raman analysis, and high-resolution transmission electron microscopy (HRTEM). The monoclinic structure of the HfO2 NPs was resolved utilizing x-ray diffraction (XRD). The optical properties were studied from the UV-Vis absorption spectrum. The optical band gap of the HfO2NPs was observed to be 5.1 eV. The Raman spectrum shows the presence of HfO2 NPs. The HRTEM image showed that the HfO2 NPs were of spherical shape with an average particle size of around 28 nm. The energy-dispersive x-ray spectroscopy (EDS) spectrum obviously demonstrated the presence of HfO2 NPs. Analysis and studies on the dielectric properties of the HfO2 NPs such as the dielectric constant, the dielectric loss, and alternating current (AC) conductivity were carried out at varying frequencies and temperatures.

Ultraviolet Radiation Dose National Standard of México

NASA Astrophysics Data System (ADS)

Cardoso, R.; Rosas, E.

2006-09-01

We present the Ultraviolet (UV) Radiation Dose National Standard for México. The establishment of this measurement reference at Centro Nacional de Metrología (CENAM) eliminates the need of contacting foreign suppliers in the search for traceability towards the SI units when calibrating instruments at 365 nm. Further more, the UV Radiation Dose National Standard constitutes a highly accurate and reliable source for the UV radiation dose measurements performed in medical and cosmetic treatments as in the the food and pharmaceutics disinfection processes, among other.

The influence of UV radiation on protistan evolution

NASA Technical Reports Server (NTRS)

Rothschild, L. J.

1999-01-01

Ultraviolet radiation has provided an evolutionary challenge to life on Earth. Recent increases in surficial ultraviolet B fluxes have focused attention on the role of UV radiation in protistan ecology, cancer, and DNA damage. Exploiting this new wealth of data, I examine the possibility that ultraviolet radiation may have played a significant role in the evolution of the first eukaryotes, that is, protists. Protists probably arose well before the formation of a significant ozone shield, and thus were probably subjected to substantial ultraviolet A, ultraviolet B, and ultraviolet C fluxes early in their evolution. Evolution consists of the generation of heritable variations and the subsequent selection of these variants. Ultraviolet radiation has played a role both as a mutagen and as a selective agent. In its role as a mutagen, it may have been crucial in the origin of sex and as a driver of molecular evolution. As a selective agent, its influence has been broad. Discussed in this paper are the influence of ultraviolet radiation on biogeography, photosynthesis, and desiccation resistance.

Analysis of population inquiry on practices for ultraviolet radiation protection.

PubMed

Celaj, Stela; Deng, Jie; Murphy, Brendan L

2017-10-15

UV radiation exposure is one of the key modifiable risk factors for skin cancer. Hence, patient education regarding skin protection and sunscreen use is of tremendous importance to public health. To better understand patient practices regarding skin protection in a population level, we looked into the Internet search behavior of the US-based population. We investigated patient inquires on the United States Food and Drug Administration (FDA) announcements regarding sunscreen use by quantifying search terms such as "broad spectrum sunscreen", "sunscreen" and "sunblock" with Google Trends, a novel methodology for understanding internet search practices. Our findings show that "broad spectrum sunscreen" searches were significantly increased post 2011 FDA announcements, which suggest increased public awareness regarding the importance of broad spectrum protection. It is encouraging these preliminary results indicate that skin protection practices are being increasingly investigated by the general public and may serve as a novel approach for identifying areas of improvement regarding patient education on the reduction of the risk for skin cancer.

The ultraviolet spectrum of noncoronal late-type stars - The Gamma Crucis (M3.4 III) reference spectrum

NASA Technical Reports Server (NTRS)

Carpenter, Kenneth G.; Pesce, Joseph E.; Stencel, Robert E.; Brown, Alexander; Johansson, Sveneric

1988-01-01

A guide is presented to the UV spectrum of M-type giants and supergiants whose outer atmospheres contain warm chromospheres but not coronae. The M3 giant Gamma Crucis is taken as the archetype of the cooler, oxygen-rich, noncoronal stars. Line identifications and integrated line flux measurements of the chromospheric emission features seen in the 1200-3200 A range of IUE high-resolution spectra are presented. The major fluorescence processes operating in the outer atmosphere of Gamma Crucis, including eight previously unknown pumping processes and 21 new fluorescent line products, are summarized, and the enhancements of selected line strengths by 'line leakage' is discussed. A set of absorption features toward the longer wavelength end of this range is identified which can be used to characterize the radial velocity of the stellar photospheres. The applicability of the results to the spectra of noncoronal stars with different effective temperatures and gravities is discussed.

RW Sextantis, a disk with a hot, high-velocity wind

NASA Astrophysics Data System (ADS)

Greenstein, J. L.; Oke, J. B.

1982-07-01

The continuum spectrum of the flickering blue variable RW Sex was observed from 10,000 to 1150 A. The star is a cataclysmic variable currently stabilized at maximum, and the spectrum is dominated by an accretion disk, with flat spectrum in the ultraviolet, except at more than 5000 A, where a blackbody near 7000 K is seen. A distance of 400 pc is derived, if the latter arises from an F type main sequence star. The accretion rate required is near 10 to the -8th solar masses per year. Only weak emission is seen, except for Lyman alpha; strong, broad UV absorption lines are seen with centers displaced up to -3000 km/s, with terminal velocities up to -4500 km/s, the velocity of escape from a white dwarf. The low X-ray flux may arise from absorption within an unusually dense, hot wind from the innermost portions of the disk. The estimated mass loss rate is nearly 10 to the -12th solar masses per year.

RW Sextantis, a disk with a hot, high-velocity wind

NASA Technical Reports Server (NTRS)

Greenstein, J. L.; Oke, J. B.

1982-01-01

The continuum spectrum of the flickering blue variable RW Sex was observed from 10,000 to 1150 A. The star is a cataclysmic variable currently stabilized at maximum, and the spectrum is dominated by an accretion disk, with flat spectrum in the ultraviolet, except at more than 5000 A, where a blackbody near 7000 K is seen. A distance of 400 pc is derived, if the latter arises from an F type main sequence star. The accretion rate required is near 10 to the -8th solar masses per year. Only weak emission is seen, except for Lyman alpha; strong, broad UV absorption lines are seen with centers displaced up to -3000 km/s, with terminal velocities up to -4500 km/s, the velocity of escape from a white dwarf. The low X-ray flux may arise from absorption within an unusually dense, hot wind from the innermost portions of the disk. The estimated mass loss rate is nearly 10 to the -12th solar masses per year.

Determination of ionic abundances in the Io torus using the Hopkins Ultraviolet Telescope

NASA Technical Reports Server (NTRS)

Moos, H. W.; Feldman, P. D.; Durrance, S. T.; Blair, W. P.; Bowers, C. W.; Davidsen, A. F.; Dixon, W. V.; Henry, R. C.; Ferguson, H. C.; Kimble, R. A.

1991-01-01

Attention is given to a 415-1864-A spectrum of the emissions from the Io torus with about 3-A resolution in first order (830-1864 A) obtained with HUT in December 1990. A list of the 31 strongest features shows that, apart from five features that are totally or partially terrestrial, all are due to O(+), S(+), S(2+), and S(3+). There is no evidence for elements other than oxygen and sulfur. The spectrum shows many additional weaker emission features so that the existence of minor species cannot be ruled out at this time. Because the HUT spectrum contains well-resolved lines for all four of the major species, the mixing ratio (Ni/ne) for each one can be determined without using models of the spectral emissions, or a detailed geometric model of the torus plasma. The relative concentration of O(+) determined from the HUT observation is 38 percent less than that obtained from the Voyager UVS data.

A Real-Time Ultraviolet Radiation Imaging System Using an Organic Photoconductive Image Sensor†

PubMed Central

Okino, Toru; Yamahira, Seiji; Yamada, Shota; Hirose, Yutaka; Odagawa, Akihiro; Kato, Yoshihisa; Tanaka, Tsuyoshi

2018-01-01

We have developed a real time ultraviolet (UV) imaging system that can visualize both invisible UV light and a visible (VIS) background scene in an outdoor environment. As a UV/VIS image sensor, an organic photoconductive film (OPF) imager is employed. The OPF has an intrinsically higher sensitivity in the UV wavelength region than those of conventional consumer Complementary Metal Oxide Semiconductor (CMOS) image sensors (CIS) or Charge Coupled Devices (CCD). As particular examples, imaging of hydrogen flame and of corona discharge is demonstrated. UV images overlapped on background scenes are simply made by on-board background subtraction. The system is capable of imaging weaker UV signals by four orders of magnitude than that of VIS background. It is applicable not only to future hydrogen supply stations but also to other UV/VIS monitor systems requiring UV sensitivity under strong visible radiation environment such as power supply substations. PMID:29361742

Ultraviolet radiation as an ant repellent

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thorvilson, H.G.; Russell, S.A.; Green, B.

1996-12-31

In an effort to repel red imported fire ants (RIFA) from electrical devices, such as transformers, ultraviolet (UV) light was tested. Initial tests determined if RIFA`s tolerate a UV-irradiated environment when given a choice between UV-irradiated and non-irradiated. All replications in this test indicated that RIFA`s are intolerant of UV-irradiation and sought to escape it. RIFA`s moved to shaded environments and transported their brood out its well. A second test sought to determine if long-term UV-irradiation of the entire colonies cause increased RIFA mortality. Queenright colonies were exposed to UV irradiation of 254nm constantly for 115 days and colonies hadmore » a higher mortality rate than did a control colony. RIFA`s attempted to escape UV light and had increased rate when exposed to UV (254nm), but a practical application of this technique may be detrimental to insulation on electrical wiring.« less

Quantifying the effects of corn growth and physiological responses to Ultraviolet-B radiation for modeling

USDA-ARS?s Scientific Manuscript database

To understand the consequences of rising levels of Ultraviolet-B (UV-B) radiation on maize (Zea mays L.), two experiments were conducted using sunlit plant growth chambers at a wide range UV-B radiation. Maize cultivars Terral-2100 and DKC 65-44 were grown in 2003 and 2008, respectively, at four le...

EFFECTS OF ULTRAVIOLET-B IRRADIANCE IN SOYBEAN. 6. INFLUENCE OF PHOSPHORUS NUTRITION ON GROWTH AND FLAVONIID CONTENT

EPA Science Inventory

Soybeans Glycine max Essex were hydroponically grown in a greenhouse at 2 levels of ultraviolet-B(UV-B) radiation and 4 levels of P. Plants were grown in each treatment combination to the complete expansion of the 4th trifoliolate leaf. UV-B radiation and reduced P supply general...

Mission Specialist Hawley works with the SWUIS experiment

NASA Image and Video Library

2013-11-18

STS093-350-022 (22-27 July 1999) --- Astronaut Steven A. Hawley, mission specialist, works with the Southwest Ultraviolet Imaging System (SWUIS) experiment onboard the Earth-orbiting Space Shuttle Columbia. The SWUIS is based around a Maksutov-design Ultraviolet (UV) telescope and a UV-sensitive, image-intensified Charge-Coupled Device (CCD) camera that frames at video frame rates.

Method and apparatus for passive optical dosimeter comprising caged dye molecules

DOEpatents

Sandison, David R.

2001-07-03

A new class of ultraviolet dosimeters is made possible by exposing caged dye molecules, which generate a dye molecule on exposure to ultraviolet radiation, to an exterior environment. Applications include sunburn monitors, characterizing the UV exposure history of UV-sensitive materials, especially including structural plastics, and use in disposable `one-use` optical equipment, especially medical devices.

Impact of enhanced ultraviolet-B irradiance on cotton growth, development, yield, and qualities under field conditions

Treesearch

Wei Gao; Youfei Zheng; James R. Slusser; Gordon M. Heisler

2003-01-01

The stratospheric ozone depletion and enhanced solar ultraviolet-B (UV-B) irradiance may have adverse impacts on the productivity of agricultural crops. The effect of UV-B enhancements on agricultural crops includes reduction in yield, alteration in species competition, decrease in photosynthetic activity, susceptibility to disease, and changes in structure and...

A study of meteor spectroscopy and physics from earth-orbit: A preliminary survey into ultraviolet meteor spectra

NASA Technical Reports Server (NTRS)

Meisel, D. D.

1976-01-01

Preliminary data required to extrapolate available meteor physics information (obtained in the photographic, visual and near ultraviolet spectral regions) into the middle and far ultraviolet are presented. Wavelength tables, telluric attenuation factors, meteor rates, and telluric airglow data are summarized in the context of near-earth observation vehicle parameters using moderate to low spectral resolution instrumentation. Considerable attenuation is given to the problem of meteor excitation temperatures since these are required to predict the strength of UV features. Relative line intensities are computed for an assumed chondritic composition. Features of greatest predicted intensities, the major problems in meteor physics, detectability of UV meteor events, complications of spacecraft motion, and UV instrumentation options are summarized.

Evaluating the impact of LED bulb development on the economic viability of ultraviolet technology for disinfection.

PubMed

Ibrahim, Mohamed A S; MacAdam, Jitka; Autin, Olivier; Jefferson, Bruce

2014-01-01

Ultraviolet (UV) technologies have been very successful in disinfection applications due to their ability to inactivate microorganisms without producing harmful disinfection by-products. However, there have been a number of concerns associated with the use of conventional UV systems such as hazardous mercury content, high capital investment and reduced electrical efficiency. These concerns have set limitations for the use of UV processes. The study evaluates the development of light emitting diode (LED) technology as an alternative UV source over the last 5 years, analyses the projections provided by the researchers and UV LED manufacturers and presents the information in a cost model with the aim to predict the timeline at which UV LED will compete with traditional UV low pressure high output technology in the commercial market at full-scale residential and industrial disinfection applications.

Calibration of the Voyager Ultraviolet Spectrometers and the Composition of the Heliosphere Neutrals: Reassessment

NASA Astrophysics Data System (ADS)

Ben-Jaffel, Lotfi; Holberg, J. B.

2016-06-01

The data harvest from the Voyagers’ (V 1 and V 2) Ultraviolet Spectrometers (UVS) covers encounters with the outer planets, measurements of the heliosphere sky-background, and stellar spectrophotometry. Because their period of operation overlaps with many ultraviolet missions, the calibration of V1 and V2 UVS with other spectrometers is invaluable. Here we revisit the UVS calibration to assess the intriguing sensitivity enhancements of 243% (V1) and 156% (V2) proposed recently. Using the Lyα airglow from Saturn, observed in situ by both Voyagers, and remotely by International Ultraviolet Explorer (IUE), we match the Voyager values to IUE, taking into account the shape of the Saturn Lyα line observed with the Goddard High Resolution Spectrograph on board the Hubble Space Telescope. For all known ranges of the interplanetary hydrogen density, we show that the V1 and V2 UVS sensitivities cannot be enhanced by the amounts thus far proposed. The same diagnostic holds for distinct channels covering the diffuse He I 58.4 nm emission. Our prescription is to keep the original calibration of the Voyager UVS with a maximum uncertainty of 30%, making both instruments some of the most stable EUV/FUV spectrographs in the history of space exploration. In that frame, we reassess the excess Lyα emission detected by Voyager UVS deep in the heliosphere, to show its consistency with a heliospheric but not galactic origin. Our finding confirms results obtained nearly two decades ago—namely, the UVS discovery of the distortion of the heliosphere and the corresponding obliquity of the local interstellar magnetic field (˜ 40^\\circ from upwind) in the solar system neighborhood—without requiring any revision of the Voyager UVS calibration.

Riemann sum method for non-line-of-sight ultraviolet communication in noncoplanar geometry

NASA Astrophysics Data System (ADS)

Song, Peng; Zhou, Xianli; Song, Fei; Zhao, Taifei; Li, Yunhong

2017-12-01

The non-line-of-sight ultraviolet (UV) communication relies on the scattering common volume, however, it is difficult to carry out the triple integral operation of the scattering common volume. Based on UV single-scattering propagation theory and the spherical coordinate, we propose to use the Riemann sum method (RSM) to analyze the link path loss (PL) of UV communication system in noncoplanar geometries, and carried out related simulations. In addition, an outdoor testbed using UV light-emitting diode was set up to provide support for the validity of the RSM. When the elevation angles of the transmitter or the receiver are small, using RSM, the channel PL and temporal response of UV communication systems can be effectively and efficiently calculated. It is useful in UV embedded system design.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Downes, R.A.

Galactic plane ultraviolet-excess (uv-excess) objects covering about 1000 square degrees of sky were surveyed. Photographic plates were obtained with both uv and blue filters, to select the uv-excess candidates, which were then observed spectroscopically to determine their classification. Most of the objects selected were nearby early-type stars with low interstellar reddening; however, a collection of hot white dwarfs, subdwarf O (sdO) stars, subdwarf B (sdB) stars, and cataclysmic variables was also found. Photoelectric photometry was obtained for these stars and a statistical analysis was performed to determine the space densities and scale heights for the four classes of objects. Severalmore » interesting objects (or class of objects) were discovered, and data for some of these stars are presented. Among the peculiar objects found are an emission-line white dwarf similar to the pulsating PG 1159 stars, a Population II Wolf-Rayet star, a previously catalogued object with a strong Fe II emission-line spectrum, and a new class of object, resembling the sdB stars, that shows variable strength H..cap alpha.. absorption, with the H..cap alpha.. line sometimes completely filled in.« less

Resistance of a lizard (the green anole, Anolis carolinensis; Polychridae) to ultraviolet radiation-induced immunosuppression

USGS Publications Warehouse

Cope, R.B.; Fabacher, D.L.; Lieske, C.; Miller, C.A.

2001-01-01

The green anole (Anolis carolinensis) is the most northerly distributed of its Neotropical genus. This lizard avoids a winter hibernation phase by the use of sun basking behaviors. Inevitably, this species is exposed to high doses of ambient solar ultraviolet radiation (UVR). Increases in terrestrial ultraviolet-B (UV-B) radiation secondary to stratospheric ozone depletion and habitat perturbation potentially place this species at risk of UVR-induced immunosuppression. Daily exposure to subinflammatory UVR (8 kJ/m2/day UV-B, 85 kJ/m2/day ultraviolet A [UV-A]), 6 days per week for 4 weeks (total cumulative doses of 192 kJ/m2 UV-B, 2.04 × 103 kJ/m2 UV-A) did not suppress the anole's acute or delayed type hypersensitivity (DTH) response to horseshoe crab hemocyanin. In comparison with the available literature UV-B doses as low as 0.1 and 15.9 kJ/m2 induced suppression of DTH responses in mice and humans, respectively. Exposure of anoles to UVR did not result in the inhibition of ex vivo splenocyte phagocytosis of fluorescein labeled Escherichia coli or ex vivo splenocyte nitric oxide production. Doses of UV-B ranging from 0.35 to 45 kJ/m2 have been reported to suppress murine splenic/peritoneal macrophage phagocytosis and nitric oxide production. These preliminary studies demonstrate the resistance of green anoles to UVR-induced immunosuppression. Methanol extracts of anole skin contained two peaks in the ultraviolet wavelength range that could be indicative of photoprotective substances. However, the resistance of green anoles to UVR is probably not completely attributable to absorption by UVR photoprotective substances in the skin but more likely results from a combination of other factors including absorption by the cutis and absorption and reflectance by various components of the dermis.

Effects of near-ultraviolet light on mutations, intragenic and intergenic recombinations in Saccharomyces cerevisiae.

PubMed

Machida, I; Saeki, T; Nakai, S

1986-03-01

The effects of far (254 nm) and near (290-350 nm) ultraviolet (UV) light on mutations, intragenic and intergenic recombinations were compared in diploid strains of Saccharomyces cerevisiae. At equivalent survival levels there was not much difference in the induction of nonsense and missense mutations between far- and near-UV radiations. However, frameshift mutations were induced more frequently by near-UV than by far-UV radiation. Near-UV radiation induced intragenic recombination (gene conversion) as efficiently as far-UV radiation and the induced levels were similar in both radiations at equitoxic doses. A strikingly higher frequency was observed for the intergenic recombination induced by near-UV radiation than by far-UV radiation when compared at equivalent survival levels. Photoreactivation reduced the frequency only slightly in far-UV induced intergenic recombination and not at all in near-UV induction. These results indicate that near-UV damage involves strand breakage in addition to pyrimidine dimers and other lesions induced, whereas far-UV damage consists largely of photoreactivable lesions, pyrimidine dimers, and near-UV induced damage is more efficient for the induction of crossing-over.

Three-dimensional Ag2O/Bi5O7I p-n heterojunction photocatalyst harnessing UV-vis-NIR broad spectrum for photodegradation of organic pollutants.

PubMed

Chen, Yannan; Zhu, Gangqiang; Hojamberdiev, Mirabbos; Gao, Jianzhi; Zhu, Runliang; Wang, Chenghui; Wei, Xiumei; Liu, Peng

2018-02-15

Ag 2 O nanoparticles-loaded Bi 5 O 7 I microspheres forming a three dimensional Ag 2 O/Bi 5 O 7 I p-n heterojunction photocatalyst with wide-spectrum response were synthesized in this study. The results of transmission electron microscopy observations revealed that the Ag 2 O nanoparticles with the diameter of ca. 10-20nm were distributed on the surfaces of Bi 5 O 7 I nanosheets. The as-synthesized Ag 2 O/Bi 5 O 7 I exhibited an excellent wide-spectrum response to wavelengths ranging from ultraviolet (UV) to near-infrared (NIR), indicating its potential for effective utilization of solar energy. Compared with pure Bi 5 O 7 I, the Ag 2 O/Bi 5 O 7 I composite also demonstrated excellent photocatalytic activity for the degradation of Bisphenol A and phenol in aqueous solution under visible LED light irradiation. Among samples, the 20% Ag 2 O/Bi 5 O 7 I composite photocatalyst showed the highest photocatalytic activity for the degradation of Bisphenol A and phenol in aqueous solution. In addition, the 20% Ag 2 O/Bi 5 O 7 I composite also exhibited a photocatalytic activity for the degradation of Bisphenol A under NIR light irradiation. The improved photocatalytic activity is attributed to the formation of a p-n heterojunction between Ag 2 O and Bi 5 O 7 I, allowing the efficient utilization of solar energy (from UV to NIR) and high separation efficiency of photogenerated electron-hole pairs. The present work is desirable to explore a possible avenue for the full utilization of solar energy. Copyright © 2017 Elsevier B.V. All rights reserved.

Ultraviolet and near-infrared luminescence of LaBO3:Ce3+,Yb3+

NASA Astrophysics Data System (ADS)

Wei, Heng-Wei; Shao, Li-Ming; Jiao, Huan; Jing, Xi-Ping

2018-01-01

Ce3+ or Yb3+ singly doped LaBO3 and Ce3+-Yb3+ co-doped LaBO3 were prepared by conventional solid state reactions at 1100 °C and their photoluminescence (PL) properties were investigated. The emission spectrum of LaBO3:Ce3+,Yb3+ contains both the Ce3+ ultraviolet (UV) emissions (355 nm and 380 nm) and the Yb3+ near infrared (NIR) emission (975 nm) when excited by the UV light at 270 nm. By using the data of the Ce3+ decay curves and the PL intensities of both Ce3+ and Yb3+, the energy transfer efficiency (η) from Ce3+ to Yb3+, the actual energy transfer efficiency (AE) and the quantum efficiency (Q) of the Yb3+ emission were calculated. In the Ce3+-Yb3+ co-doped LaBO3, Ce3+ can transfer its absorbed energy to Yb3+ efficiently (η can be over 60%), and Yb3+ shows the Q value over 50% when it accepts the energy from Ce3+, which results in the low AE value ∼30%. The energy transfer process from Ce3+ to Yb3+ may be understood by the charge transfer mechanism: Ce3+ + Yb3+ ↔ Ce4+ + Yb2+. Particularly the Ce3+-Yb3+ co-doped LaBO3 phosphor gives the emissions mainly in the UV range and the NIR range with a portion of visible emissions in eye-insensitive range. This unique property may be suitable for applications in anti-counterfeiting techniques and public security affairs.

Obtaining titanium dioxide nanoparticles with spherical shape and antimicrobial properties using M. citrifolia leaves extract by hydrothermal method.

PubMed

M, Sundrarajan; K, Bama; M, Bhavani; S, Jegatheeswaran; S, Ambika; A, Sangili; P, Nithya; R, Sumathi

2017-06-01

In this work, we synthesized titanium dioxide (TiO 2 ) nanoparticles using leaf extract of Morinda citrifolia (M. citrifolia) by the advanced hydrothermal method. The synthesized TiO 2 nanoparticles were characterized by X-ray diffraction (XRD), Fourier transmission infrared (FT-IR), Ultraviolet-visible diffuse reflectance (UV-Vis DRS), Ultraviolet-visible spectroscopy (UV-Vis), Raman spectroscopy, and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM with EDX) techniques. The XRD major peak at 27.3° corresponds to the (110) lattice plane of tetragonal rutile TiO 2 phase and average crystalline size of nanoparticles is 10nm. The FT-IR result confirmed that TiO 2 nanoparticles and the presences of very few amount of anthraquinone and phenolic compounds of the leaf extract. The obtained nanoparticles were also characterized by UV-Vis DRS absorption spectroscopy and an intense band at 423nm clearly reveals the formation of nanoparticles. SEM images with EDX spectra clearly reveal the size of the nanoparticles, between 15 and 19nm in excellent quasi-spherical shape, by virtue of stabilization (capping) agent. The presence of elements-titanium and oxygen was verified with EDX spectrum. Furthermore, the inhibitory activity of green synthesized TiO 2 nanoparticles was tested against human pathogens like Staphylococcus aureus, Escherichia coli, Bacillus subtilis, Pseudomonas aeruginosa, Candida albicans, and Aspergillus niger by the agar well-diffusion method. The TiO 2 nanoparticles exhibited superior antimicrobial activity against Gram-positive bacteria, demonstrating their antimicrobial value against pathogenic diseases. Copyright © 2017 Elsevier B.V. All rights reserved.

Far Ultraviolet Spectroscopy of Seven Nova-Like Variables

NASA Astrophysics Data System (ADS)

Mizusawa, Trisha; Merritt, Jason; Ballouz, Ronald-Louis; Bonaro, Michael; Foran, Sean; Plumberg, Christopher; Stewart, Heather; Wiley, Trayer; Sion, Edward M.

2010-03-01

We present the results of a multicomponent synthetic spectral analysis of the archival far ultraviolet spectra of several key nova-like variables including members of the SW Sex, RW Tri, UX UMa, and VY Scl subclasses: KR Aur, RW Tri, V825 Her, V795 Her, BP Lyn, V425 Cas, and HL Aqr. Accretion rates as well as the possible flux contribution of the accreting white dwarf are included in our analysis. Except for RW Tri, which has a reliable trigonometric parallax, we computed the distances to the nova-like systems using the method of Knigge. Our analysis of seven archival IUE spectra of RW Tri at its parallax distance of 341 pc consistently indicates a low mass (˜0.4 M⊙) white dwarf and an average accretion rate, . For KR Aur, we estimate that the white dwarf has Teff = 29,000 ± 2000 K, log g = 8.4, and contributes 18% of the far-UV flux, while an accretion disk with accretion rate at an inclination of 41° contributes the remainder. We find that an accretion disk dominates the far-UV spectrum of V425 Cas but a white dwarf contributes nonnegligibly with approximately 18% of the far-UV flux. For the two high state nova-likes, HL Aqr and V825 Her, their accretion disks totally dominate with and 3 × 10-9 M⊙ yr-1, respectively. For BP Lyn we find while for V795 Her, we find an accretion rate of . We discuss the implications of our results for the evolutionary status of nova-like variables.

Droop-free Al_xGa_1-xN/Al_yGa_1-yN quantum-disks-in-nanowires ultraviolet LED emitting at 337 nm on metal/silicon substrates.

PubMed

Janjua, Bilal; Sun, Haiding; Zhao, Chao; Anjum, Dalaver H; Priante, Davide; Alhamoud, Abdullah A; Wu, Feng; Li, Xiaohang; Albadri, Abdulrahman M; Alyamani, Ahmed Y; El-Desouki, Munir M; Ng, Tien Khee; Ooi, Boon S

2017-01-23

Currently the AlGaN-based ultraviolet (UV) solid-state lighting research suffers from numerous challenges. In particular, low internal quantum efficiency, low extraction efficiency, inefficient doping, large polarization fields, and high dislocation density epitaxy constitute bottlenecks in realizing high power devices. Despite the clear advantage of quantum-confinement nanostructure, it has not been widely utilized in AlGaN-based nanowires. Here we utilize the self-assembled nanowires (NWs) with embedding quantum-disks (Qdisks) to mitigate these issues, and achieve UV emission of 337 nm at 32 A/cm² (80 mA in 0.5 × 0.5 mm² device), a turn-on voltage of ~5.5 V and droop-free behavior up to 120 A/cm² of injection current. The device was grown on a titanium-coated n-type silicon substrate, to improve current injection and heat dissipation. A narrow linewidth of 11.7 nm in the electroluminescence spectrum and a strong wavefunctions overlap factor of 42% confirm strong quantum confinement within uniformly formed AlGaN/AlGaN Qdisks, verified using transmission electron microscopy (TEM). The nitride-based UV nanowires light-emitting diodes (NWs-LEDs) grown on low cost and scalable metal/silicon template substrate, offers a scalable, environment friendly and low cost solution for numerous applications, such as solid-state lighting, spectroscopy, medical science and security.

The Rest-frame Ultraviolet Spectra of UV-selected Active Galactic Nuclei at z ~ 2-3

NASA Astrophysics Data System (ADS)

Hainline, Kevin N.; Shapley, Alice E.; Greene, Jenny E.; Steidel, Charles C.

2011-05-01

We present new results for a sample of 33 narrow-lined UV-selected active galactic nuclei (AGNs), identified in the course of a spectroscopic survey for star-forming galaxies at z ~ 2-3. The rest-frame UV composite spectrum for our AGN sample shows several emission lines characteristic of AGNs, as well as interstellar absorption features detected in star-forming Lyman break galaxies (LBGs). We report a detection of N IV] λ1486, which has been observed in high-redshift radio galaxies, as well as in rare optically selected quasars. The UV continuum slope of the composite spectrum is significantly redder than that of a sample of non-AGN UV-selected star-forming galaxies. Blueshifted Si IV absorption provides evidence for outflowing highly ionized gas in these objects at speeds of ~103 km s-1, quantitatively different from what is seen in the outflows of non-AGN LBGs. Grouping the individual AGNs by parameters such as the Lyα equivalent width, redshift, and UV continuum magnitude allows for an analysis of the major spectroscopic trends within the sample. Stronger Lyα emission is coupled with weaker low-ionization absorption, which is similar to what is seen in the non-AGN LBGs, and highlights the role that cool interstellar gas plays in the escape of Lyα photons. However, the AGN composite does not show the same trends between Lyα strength and extinction seen in the non-AGN LBGs. These results represent the first such comparison at high redshift between star-forming galaxies and similar galaxies that host AGN activity. Based, in part, on data obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and NASA, and was made possible by the generous financial support of the W. M. Keck Foundation.

Galileo Ultraviolet Spectrometer experiment

NASA Technical Reports Server (NTRS)

Hord, C. W.; Mcclintock, W. E.; Stewart, A. I. F.; Barth, C. A.; Esposito, L. W.; Thomas, G. E.; Sandel, B. R.; Hunten, D. M.; Broadfoot, A. L.; Shemansky, D. E.

1992-01-01

The Galileo ultraviolet spectrometer experiment uses data obtained by the Ultraviolet Spectrometer (UVS) mounted on the pointed orbiter scan platform and from the Extreme Ultraviolet Spectrometer (EUVS) mounted on the spinning part of the orbiter with the field of view perpendicular to the spin axis. The UVS is a Ebert-Fastie design that covers the range 113-432 nm with a wavelength resolution of 0.7 nm below 190 and 1.3 nm at longer wavelengths. The UVS spatial resolution is 0.4 deg x 0.1 deg for illuminated disk observations and 1 deg x 0.1 deg for limb geometries. The EUVS is a Voyager design objective grating spectrometer, modified to cover the wavelength range from 54 to 128 nm with wavelength resolution 3.5 nm for extended sources and 1.5 nm for point sources and spatial resolution of 0.87 deg x 0.17 deg. The EUVS instrument will follow up on the many Voyager UVS discoveries, particularly the sulfur and oxygen ion emissions in the Io torus and molecular and atomic hydrogen auroral and airglow emissions from Jupiter. The UVS will obtain spectra of emission, absorption, and scattering features in the unexplored, by spacecraft, 170-432 nm wavelength region. The UVS and EUVS instruments will provide a powerful instrument complement to investigate volatile escape and surface composition of the Galilean satellites, the Io plasma torus, micro- and macro-properties of the Jupiter clouds, and the composition structure and evolution of the Jupiter upper atmosphere.

Development of Ultraviolet (UV) Radiation Protective Fabric Using Combined Electrospinning and Electrospraying Technique

NASA Astrophysics Data System (ADS)

Sinha, Mukesh Kumar; Das, B. R.; Kumar, Kamal; Kishore, Brij; Prasad, N. Eswara

2017-06-01

The article reports a novel technique for functionization of nanoweb to develop ultraviolet (UV) radiation protective fabric. UV radiation protection effect is produced by combination of electrospinning and electrospraying technique. A nanofibrous web of polyvinylidene difluoride (PVDF) coated on polypropylene nonwoven fabric is produced by latest nanospider technology. Subsequently, web is functionalized by titanium dioxide (TiO2). The developed web is characterized for evaluation of surface morphology and other functional properties; mechanical, chemical, crystalline and thermal. An optimal (judicious) nanofibre spinning condition is achieved and established. The produced web is uniformly coated by defect free functional nanofibres in a continuous form of useable textile structural membrane for ultraviolet (UV) protective clothing. This research initiative succeeds in preparation and optimization of various nanowebs for UV protection. Field Emission Scanning Electron Microscope (FESEM) result reveals that PVDF webs photo-degradative behavior is non-accelerated, as compared to normal polymeric grade fibres. Functionalization with TiO2 has enhanced the photo-stability of webs. The ultraviolet protection factor of functionalized and non-functionalized nanowebs empirically evaluated to be 65 and 24 respectively. The developed coated layer could be exploited for developing various defence, para-military and civilian UV protective light weight clothing (tent, covers and shelter segments, combat suit, snow bound camouflaging nets). This research therefore, is conducted in an attempt to develop a scientific understanding of PVDF fibre coated webs for photo-degradation and applications for defence protective textiles. This technological research in laboratory scale could be translated into bulk productionization.

Vesta's UV Lightcurve: Hemispheric Variation in Brightness and Spectral Reversal

NASA Technical Reports Server (NTRS)

Hendrix, Amanda R.; Vilas, Faith; Festou, Michael

2003-01-01

Spectra of asteroid 4 Vesta obtained in October 1990 with the International Ultraviolet Explorer are reanalyzed and reinterpreted. A large portion of the eastern hemisphere (based on the prime meridian definition of Thomas et al., 1997a) is darker at UV Wavelengths than much of the western hemisphere. The UV lightcurve is in contrast with the visible lightcurve, which shows that the eastern hemisphere is brighter than the western. These IUE spectra of Vesta thus may be evidence for the "spectral reversal." first seen on the Moon by Apollo 17. where the visibly brighter lunar highlands are darker than the maria at far-UV wavelengths. This effect was linked to space weathering when it was noted (Wagner et al., 1987) that the spectral reversal appears in the laboratory spectra of lunar soils but not powdered lunar rocks. We investigate Vesta's UV lightcurve and spectral reversal, and its possible connection with space weathering. The addition to grain coatings of small amounts of submicroscopic iron (SMFe) through vapor deposition causes drastic spectral changes at UV-visible wavelengths (Hapke, 2001). while the longer wavelength spectrum remains largely unaffected. Other laboratory results (e.g., Hiroi and Pieters, 1998) indicate that the UV-visible wavelength range is affected by simulated weathering processes in a manner similar to what is seen on Vesta. It is likely that Vesta has experienced relatively minor amounts of space weathering, as indicated by the spectral reversal, along with the subtle visible-near infrared weathering effects (e.g., Binzel et al., 1997).

Skylab

NASA Image and Video Library

1973-01-01

This chart describes the Hydrogen-Alpha (H-Alpha) #2 Telescope, one of eight major solar study facilities on the Skylab Apollo Telescope Mount (ATM). There were two H-Alpha telescopes on the ATM that were used primarily to point the ATM and keep a continuous photographic record during solar observation periods. Both telescopes gave the Skylab astronauts a real-time picture of the Sun in the red light of the H-Alpha spectrum through a closed-circuit television. The H-Alpha #1 telescope provided simultaneous photographic and ultraviolet (UV) pictures, while the #2 telescope operated only in the TV mode. The Marshall Space Flight Center was responsible for development of the H-Alpha Telescopes.

Skylab

NASA Image and Video Library

1973-01-01

This chart describes the Hydrogen-Alpha (H-Alpha) #1 Telescope, one of eight major solar study facilities on the Skylab Apollo Telescope Mount (ATM). There were two H-Alpha telescopes on the ATM that were used primarily to point the ATM and keep a continuous photographic record during the solar observation periods. Both telescopes gave the Skylab astronauts a real-time picture of the Sun in the red light of the H-Alpha spectrum through a closed-circuit television. The H-Alpha #1 Telescope provided simultaneous photographic and ultraviolet (UV) pictures, while the #2 Telescope operated only in the TV mode. The Marshall Space Flight Center was responsible for development of the H-Alpha Telescopes.

Dissociative Excitation of Adenine by Electron Impact

NASA Astrophysics Data System (ADS)

McConkey, J. William; Trocchi, Joshuah; Dech, Jeffery; Kedzierski, Wladek

2017-04-01

Dissociative excitation of adenine (C6H5NH2) into excited atomic fragments has been studied in the electron impact energy range from threshold to 300 eV. A crossed beam system coupled to a vacuum ultraviolet (VUV) monochromator is used to study emissions in the wavelength range from 110 to 200 nm. The beam of adenine vapor from a stainless steel oven is crossed at right angles by the electron beam and the resultant UV radiation is detected in a mutually orthogonal direction. The strongest feature in the spectrum is H Lyman- α. Financial support from NSERC and CFI, Canada, is gratefully acknowledged.

Measurement Variation and the Factors Influencing the UV Index

ERIC Educational Resources Information Center

Downs, Nathan; Parisi, Alfio; McDonnell, Brendan; Thornton, Peter

2008-01-01

The article presents a technique to measure the ultraviolet index using a personal hand-held ultraviolet meter to illustrate concepts of physics. Measurements of the erythemally effective (sun-burning) direct solar beam, diffuse skylight, and total global ultraviolet irradiance are converted to daily ultraviolet index measurements. Daily…

Conformationally resolved spectroscopy of jet-cooled methacetin

NASA Astrophysics Data System (ADS)

Moon, Cheol Joo; Ahn, Ahreum; Min, Ahreum; Seong, Yeon Guk; Kim, Ju Hyun; Choi, Myong Yong

2017-11-01

The excitation spectra of jet-cooled methacetin (MA) have been measured using a combination of mass-selected resonant two-photon ionization and ultraviolet-ultraviolet hole-burning (UV-UV HB) spectroscopy in the gas phase. Four different UV-UV HB spectra originating from two conformers of MA (syn- and anti-MA) with their fundamental and hot transitions have been obtained. IR-dip spectroscopy has conclusively confirmed the coexistence of the two conformers with the aid of theoretical calculations. Vibronic band assignments in the low frequency region caused by internal methyl group rotation in the methyl-capped peptide group, which originate from the 1e rotational level, are presented.

An ESR study of the UV degradation of FEP

NASA Technical Reports Server (NTRS)

George, G. A.; Hill, D. J. T.; Odonnell, J. H.; Pomery, P. J.; Rasoul, F.

1992-01-01

Spacecraft in low earth orbit are subjected to significant levels of high energy radiation, including ultraviolet (UV) and visible ultraviolet (VUV) wavelengths. The effects of UV radiation are enhanced over those at the surface of the earth, where the only incident wavelengths are greater than 290 nm. In low earth orbit the incident UV wavelengths extend below 290 nm into the VUV region, where the Lyman alpha-emissions of atomic hydrogen occur at 121 nm. In addition to electromagnetic radiation, in low earth orbit polymer materials may also be subjected to atomic oxygen particle radiation, which will result in direct oxidation of the polymer.

Replicated mesocosm study on the role of natural ultraviolet radiation in high CDOM, shallow lakes.

PubMed

Pérez, A Patricia; Diaz, Mónica M; Ferraro, Marcela A; Cusminsky, Gabriela C; Zagarese, Horacio E

2003-02-01

The role of ultraviolet radiation on shallow, high CDOM (colored dissolved organic matter) lakes was investigated during two consecutive summers (1999 and 2000) in replicated mesocosms (rectangular fiberglass tanks). Each tank (volume: 300 L; depth: 40 cm) was covered with a layer (approximately 3 cm) of sediment from lake El Toro (40 degrees 14' S; 70 degrees 22' W) and filled with filtered water. The experimental design consisted of two treatments: full natural radiation (UV-exposed) and natural radiation without ultraviolet radiation (UV-shielded). UV-exposed and UV-shielded treatments differed in most studied variables as revealed by repeated measures ANOVA. UV-exposed tanks displayed lower CDOM levels (dissolved absorbance) of lower average molecular size (absorbance ratio between 250 and 365 nm), higher bacterial biomass, and lower chlorophyll a concentration. The effect on consumers (rotifers and crustaceans) was less noticeable. The results are consistent with UV stimulation of bacteria production mediated by higher rates of CDOM photobleaching, and the photoinhibition of planktonic algae. Thus, a major effect of UVR in shallow, high CDOM ecosystems appears to be the stimulation of heterotrophic pathways and a simultaneous inhibition of photoautotrophs.

Role of ultraviolet (UV) disinfection in infection control and environmental cleaning.

PubMed

Qureshi, Zubair; Yassin, Mohamed H

2013-06-01

Ultraviolet (UV) radiation is capable of disinfecting surfaces, water and air. The UV technology was used for many years. However, safer and more effective delivery systems of UV radiation, make it a very useful option for disinfection. Effective disinfection of environmental surfaces is a key step in the prevention of spread of infectious agents. The traditional manual cleaning is essential in assuring adequate elimination of contamination. However, terminal cleaning is frequently suboptimal or unpredictable in many circumstances. UV-C radiation is an adjunctive disinfectant new technology that could kill a wide array of microorganisms including both vegetative and spore forming pathogens. The technology is getting more affordable and has produced consistent reproducible significant reduction of bacterial contamination.

High-throughput ultraviolet photoacoustic microscopy with multifocal excitation

NASA Astrophysics Data System (ADS)

Imai, Toru; Shi, Junhui; Wong, Terence T. W.; Li, Lei; Zhu, Liren; Wang, Lihong V.

2018-03-01

Ultraviolet photoacoustic microscopy (UV-PAM) is a promising intraoperative tool for surgical margin assessment (SMA), one that can provide label-free histology-like images with high resolution. In this study, using a microlens array and a one-dimensional (1-D) array ultrasonic transducer, we developed a high-throughput multifocal UV-PAM (MF-UV-PAM). Our new system achieved a 1.6 ± 0.2 μm lateral resolution and produced images 40 times faster than the previously developed point-by-point scanning UV-PAM. MF-UV-PAM provided a readily comprehensible photoacoustic image of a mouse brain slice with specific absorption contrast in ˜16 min, highlighting cell nuclei. Individual cell nuclei could be clearly resolved, showing its practical potential for intraoperative SMA.

Ultraviolet B-Sensitive Rice Cultivar Deficient in Cyclobutyl Pyrimidine Dimer Repair.

PubMed Central

Hidema, J.; Kumagai, T.; Sutherland, J. C.; Sutherland, B. M.

1997-01-01

Repair of cyclobutyl pyrimidine dimers (CPDs) in DNA is essential in most organisms to prevent biological damage by ultraviolet (UV) light. In higher plants tested thus far, UV-sensitive strains had higher initial damage levels or deficient repair of nondimer DNA lesions but normal CPD repair. This suggested that CPDs might not be important for biological lesions. The photosynthetic apparatus has also been proposed as a critical target. We have analyzed CPD induction and repair in the UV-sensitive rice (Oryza sativa L.) cultivar Norin 1 and its close relative UV-resistant Sasanishiki using alkaline agarose gel electrophoresis. Norin 1 is deficient in cyclobutyl pyrimidine dimer photoreactivation and excision; thus, UV sensitivity correlates with deficient dimer repair. PMID:12223592

UV clothing and skin cancer.

PubMed

Tarbuk, Anita; Grancarić, Ana Marija; Situm, Mirna; Martinis, Mladen

2010-04-01

Skin cancer incidence in Croatia is steadily increasing in spite of public and governmental permanently measurements. It is clear that will soon become a major public health problem. The primary cause of skin cancer is believed to be a long exposure to solar ultraviolet (UV) radiation. The future designers of UV protective materials should be able to block totally the ultraviolet radiation. The aim of this paper is to present results of measurements concerning UV protecting ability of garments and sun-screening textiles using transmission spectrophotometer Cary 50 Solarscreen (Varian) according to AS/NZS 4399:1996; to show that standard clothing materials are not always adequate to prevent effect of UV radiation to the human skin; and to suggest the possibilities for its improvement for this purpose.

AlGaN Ultraviolet Detectors for Dual-Band UV Detection

NASA Technical Reports Server (NTRS)

Miko, Laddawan; Franz, David; Stahle, Carl M.; Yan, Feng; Guan, Bing

2010-01-01

This innovation comprises technology that has the ability to measure at least two ultraviolet (UV) bands using one detector without relying on any external optical filters. This allows users to build a miniature UVA and UVB monitor, as well as to develop compact, multicolor imaging technologies for flame temperature sensing, air-quality control, and terrestrial/counter-camouflage/biosensing applications.

Ultraviolet-B radiation in a row-crop canopy: an extended 1-D model

Treesearch

Wei Gao; Richard H. Grant; Gordon M. Heisler; James R. Slusser

2003-01-01

A decrease in stratospheric ozone may result in a serious threat to plants, since biologically active short-wavelength ultraviolet-B (UV-B 280-320 nm) radiation will increase even with a relatively small decrease in ozone. Numerous investigations have demonstrated that the effect of UV-B enhancements on plants includes reduction in grain yield, alteration in species...

A geometric ultraviolet-B radiation transfer model applied to vegetation canopies

Treesearch

Wei Gao; Richard H. Grant; Gordon M. Heisler; James R. Slusser

2002-01-01

The decrease in stratospheric ozone (O3) has prompted continued efforts to assess the potential damage to plant and animal life due to enhanced levels of solar ultraviolet (UV)-B (280-320 nm) radiation. The objective of this study was to develop and evaluate an analytical model to simulate the UV-B irradiance loading on horizontal below- canopy...

Spectrum formation in superluminous supernovae (Type I)

NASA Astrophysics Data System (ADS)

Mazzali, P. A.; Sullivan, M.; Pian, E.; Greiner, J.; Kann, D. A.

2016-06-01

The near-maximum spectra of most superluminous supernovae (SLSNe) that are not dominated by interaction with a H-rich circum-stellar medium (SLSN-I) are characterized by a blue spectral peak and a series of absorption lines which have been identified as O II. SN 2011kl, associated with the ultra-long gamma-ray burst GRB111209A, also had a blue peak but a featureless optical/ultraviolet (UV) spectrum. Radiation transport methods are used to show that the spectra (not including SN 2007bi, which has a redder spectrum at peak, like ordinary SNe Ic) can be explained by a rather steep density distribution of the ejecta, whose composition appears to be typical of carbon-oxygen cores of massive stars which can have low metal content. If the photospheric velocity is ˜10 000-15 000 km s-1, several lines form in the UV. O II lines, however, arise from very highly excited lower levels, which require significant departures from local thermodynamic equilibrium to be populated. These SLSNe are not thought to be powered primarily by 56Ni decay. An appealing scenario is that they are energized by X-rays from the shock driven by a magnetar wind into the SN ejecta. The apparent lack of evolution of line velocity with time that characterizes SLSNe up to about maximum is another argument in favour of the magnetar scenario. The smooth UV continuum of SN 2011kl requires higher ejecta velocities (˜20 000 km s-1): line blanketing leads to an almost featureless spectrum. Helium is observed in some SLSNe after maximum. The high-ionization near-maximum implies that both He and H may be present but not observed at early times. The spectroscopic classification of SLSNe should probably reflect that of SNe Ib/c. Extensive time coverage is required for an accurate classification.

Disinfection of Mycobacterium avium subspecies hominissuis in drinking tap water using ultraviolet germicidal irradiation.

PubMed

Schiavano, Giuditta Fiorella; De Santi, Mauro; Sisti, Maurizio; Amagliani, Giulia; Brandi, Giorgio

2017-09-13

Nontuberculous mycobacteria are resistant to conventional water treatments, and are opportunistic human pathogen, particularly in hospitalized patients. The aim of this investigation was to assess the effectiveness of an ultraviolet UV-C lamp treatment against Mycobacterium avium subspecies hominissuis in drinking tap water. Ultraviolet treatments (0-192 mJ/cm 2 ) were performed using UV lamp immerged onto cylindrical glass tubes containing artificially contaminated water. The results showed that susceptibility to UV varied considerably according to the strains and the diameter of the tube. With a dose of 32 mJ/cm 2 , a significant inactivation (p < .05) of 3 log (99.9%) or more was obtained in only 5 of the 14 strains. To obtain a complete inactivation of all strains an irradiation of 192 mJ/cm 2 was needed, a dose that is much higher than the limits recommended by the international standards for UV disinfection of drinking water. In conclusion, it may be difficult to standardize a UV dose for the elimination of waterborne mycobacteria.

Photomorphogenic responses to ultraviolet-B light.

PubMed

Jenkins, Gareth I

2017-11-01

Exposure to ultraviolet B (UV-B) light regulates numerous aspects of plant metabolism, morphology and physiology through the differential expression of hundreds of genes. Photomorphogenic responses to UV-B are mediated by the photoreceptor UV RESISTANCE LOCUS8 (UVR8). Considerable progress has been made in understanding UVR8 action: the structural basis of photoreceptor function, how interaction with CONSTITUTIVELY PHOTOMORPHOGENIC 1 initiates signaling and how REPRESSOR OF UV-B PHOTOMORPHOGENESIS proteins negatively regulate UVR8 action. In addition, recent research shows that UVR8 mediates several responses through interaction with other signaling pathways, in particular auxin signaling. Nevertheless, many aspects of UVR8 action remain poorly understood. Most research to date has been undertaken with Arabidopsis, and it is important to explore the functions and regulation of UVR8 in diverse plant species. Furthermore, it is essential to understand how UVR8, and UV-B signaling in general, regulates processes under natural growth conditions. Ultraviolet B regulates the expression of many genes through UVR8-independent pathways, but the activity and importance of these pathways in plants growing in sunlight are poorly understood. © 2017 John Wiley & Sons Ltd.

Visible-blind ultraviolet photodetectors on porous silicon carbide substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naderi, N.; Hashim, M.R., E-mail: roslan@usm.my

2013-06-01

Highlights: • Highly reliable UV detectors are fabricated on porous silicon carbide substrates. • The optical properties of samples are enhanced by increasing the current density. • The optimized sample exhibits enhanced sensitivity to the incident UV radiation. - Abstract: Highly reliable visible-blind ultraviolet (UV) photodetectors were successfully fabricated on porous silicon carbide (PSC) substrates. High responsivity and high photoconductive gain were observed in a metal–semiconductor–metal ultraviolet photodetector that was fabricated on an optimized PSC substrate. The PSC samples were prepared via the UV-assisted photo-electrochemical etching of an n-type hexagonal silicon carbide (6H-SiC) substrate using different etching current densities. Themore » optical results showed that the current density is an outstanding etching parameter that controls the porosity and uniformity of PSC substrates. A highly porous substrate was synthesized using a suitable etching current density to enhance its light absorption, thereby improving the sensitivity of UV detector with this substrate. The electrical characteristics of fabricated devices on optimized PSC substrates exhibited enhanced sensitivity and responsivity to the incident radiation.« less

Neuronal Representation of Ultraviolet Visual Stimuli in Mouse Primary Visual Cortex

PubMed Central

Tan, Zhongchao; Sun, Wenzhi; Chen, Tsai-Wen; Kim, Douglas; Ji, Na

2015-01-01

The mouse has become an important model for understanding the neural basis of visual perception. Although it has long been known that mouse lens transmits ultraviolet (UV) light and mouse opsins have absorption in the UV band, little is known about how UV visual information is processed in the mouse brain. Using a custom UV stimulation system and in vivo calcium imaging, we characterized the feature selectivity of layer 2/3 neurons in mouse primary visual cortex (V1). In adult mice, a comparable percentage of the neuronal population responds to UV and visible stimuli, with similar pattern selectivity and receptive field properties. In young mice, the orientation selectivity for UV stimuli increased steadily during development, but not direction selectivity. Our results suggest that, by expanding the spectral window through which the mouse can acquire visual information, UV sensitivity provides an important component for mouse vision. PMID:26219604

The Molecular and Physiological Responses of Physcomitrella patens to Ultraviolet-B Radiation1[W][OA

PubMed Central

Wolf, Luise; Rizzini, Luca; Stracke, Ralf; Ulm, Roman; Rensing, Stefan A.

2010-01-01

Ultraviolet-B (UV-B) radiation present in sunlight is an important trigger of photomorphogenic acclimation and stress responses in sessile land plants. Although numerous moss species grow in unshaded habitats, our understanding of their UV-B responses is very limited. The genome of the model moss Physcomitrella patens, which grows in sun-exposed open areas, encodes signaling and metabolic components that are implicated in the UV-B response in flowering plants. In this study, we describe the response of P. patens to UV-B radiation at the morphological and molecular levels. We find that P. patens is more capable of surviving UV-B stress than Arabidopsis (Arabidopsis thaliana) and describe the differential expression of approximately 400 moss genes in response to UV-B radiation. A comparative analysis of the UV-B response in P. patens and Arabidopsis reveals both distinct and conserved pathways. PMID:20427465

Near-simultaneous ultraviolet and optical spectrophotometry of T Tauri stars

NASA Technical Reports Server (NTRS)

Goodrich, Robert W.; Herbig, G. H.

1986-01-01

A set of near-simultaneous ultraviolet and optical spectra and UBVR(J)I(J) photometry of five T Tauri stars has been analyzed for the shape of the energy distribution shortward of 3000 A. The far-ultraviolet continua of these stars are very much stronger than the level of light scattered from longer wavelengths in the IUE spectrograph. The results, expressed as two-color plots, show that the UV colors of T Tauri stars differ significantly from those expected from their optical spectral types. Although these particular K-type T Tauri stars are not extreme members of the class, they have the UV colors of A stars. The spectral shape of this UV excess is approximately that expected from published chromospheric models of T Tauri stars.

On the change in the spectral composition of solar ultraviolet emission preceding proton flares, and its connection with the preflare fluctuations in the horizontal component of the geomagnetic field

NASA Astrophysics Data System (ADS)

Sheiner, Olga; Snegirev, Sergei; Smirnova, Anna

The importance problem of Solar-terrestrial physics is regular forecasting of solar activity phenomena, which negatively influence the human’s health, operating safety, communication, radar sets and others. We previously reported the existence of long-period pulsations of H component of the geomagnetic field recorded at stations tested 2-3 days before the proton solar flares. There are the increasing of pulsation amplitude of the horizontal component of the magnetic field with periods of 30-60 minutes. The spectrum of the flux of ultraviolet solar radiation on the eve of proton flares was conducted to determine the presence of oscillations - precursors of flares, as one of the possible agents causing amplification of large periods pulsations of H component of the geomagnetic field. Used data on ultraviolet radiation of the sun with a wavelength of 115-127 nm are obtained from a geostationary satellite GOES 15, the method of wavelet analysis is used. It is found the congruence in the behavior of spectral components with periods of 30-60 minutes in the ground-based measurements and in UV emission for 3-1 days before the proton flare.

SiC-based Photo-detectors for UV, VUV, EUV and Soft X-ray Detection

NASA Technical Reports Server (NTRS)

Yan, Feng

2006-01-01

A viewgraph presentation describing an ideal Silicon Carbide detector for ultraviolet, vacuum ultraviolet, extreme ultraviolet and soft x-ray detection is shown. The topics include: 1) An ideal photo-detector; 2) Dark current density of SiC photodiodes at room temperature; 3) Dark current in SiC detectors; 4) Resistive and capacitive feedback trans-impedance amplifier; 5) Avalanche gain; 6) Excess noise; 7) SNR in single photon counting mode; 8) Structure of SiC single photon counting APD and testing structure; 9) Single photon counting waveform and testing circuit; 10) Amplitude of SiC single photon counter; 11) Dark count of SiC APD photon counters; 12) Temperature-dependence of dark count rate; 13) Reduce the dark count rate by reducing the breakdown electric field; 14) Spectrum range for SiC detectors; 15) QE curves of Pt/4H-SiC photodiodes; 16) QE curve of SiC; 17) QE curves of SiC photodiode vs. penetration depth; 18) Visible rejection of SiC photodiodes; 19) Advantages of SiC photodiodes; 20) Competitors of SiC detectors; 21) Extraterrestrial solar spectra; 22) Visible-blind EUV detection; 23) Terrestrial solar spectra; and 24) Less than 1KeV soft x-ray detection.

Postreplication Repair of Ultraviolet Damage in Haemophilus influenzae

PubMed Central

Leclerc, J. Eugene; Setlow, Jane K.

1972-01-01

The deoxyribonucleic acid (DNA) synthesized following ultraviolet (UV) irradiation of wild-type (Rd) and recombination-defective strains of Haemophilus influenzae has been analyzed by alkaline sucrose gradient sedimentation. Strain Rd and a UV-resistant, recombination-defective strain Rd(DB117) rec− are able to carry out postreplication repair, i.e., close the single-strand gaps in the newly synthesized DNA; in the UV-sensitive, recombination-defective strain DB117, the gaps remain open. The lack of postreplication repair in this strain may be the result of degradation of the newly synthesized DNA. PMID:4537422

Assessment of the impact of increased solar ultraviolet radiation upon marine ecosystems

NASA Technical Reports Server (NTRS)

Worrest, R. C.; Vandyke, H.

1978-01-01

Reduction of the earth's ozone layer, with a resultant increase in transmission of solar ultraviolet radiation in the 290 to 320nm waveband (UV-B), via space shuttle operations through the stratosphere is considered. It is shown that simulated solar ultraviolet radiation can, under experimental conditions, detrimentally affect the marine organisms that form the base of the food web of oceanic and estuarine ecosystems. Whether a small increase in biologically harmful ultraviolet radiation might overwhelm these mechanisms and produce changes that will have damaging consequences to the biosphere is discussed. The potential for irreversible damage to the productivity, structure and/or functioning of a model estuarine ecosystem by increased UV-B radiation and whether these ecosystems are highly stable or amenable to adaptive change is studied. Data are provided to assess the potential impact upon marine ecosystems if space shuttle operations contribute to a reduction of the stratospheric ozone layer and the sensitivity of key community components to increased UV-B radiation is examined.

Ultraviolet 320 nm laser excitation for flow cytometry.

PubMed

Telford, William; Stickland, Lynn; Koschorreck, Marco

2017-04-01

Although multiple lasers and high-dimensional analysis capability are now standard on advanced flow cytometers, ultraviolet (UV) lasers (usually 325-365 nm) remain an uncommon excitation source for cytometry. This is primarily due to their cost, and the small number of applications that require this wavelength. The development of the Brilliant Ultraviolet (BUV fluorochromes, however, has increased the importance of this formerly niche excitation wavelength. Historically, UV excitation was usually provided by water-cooled argon- and krypton-ion lasers. Modern flow cytometers primary rely on diode pumped solid state lasers emitting at 355 nm. While useful for all UV-excited applications, DPSS UV lasers are still large by modern solid state laser standards, and remain very expensive. Smaller and cheaper near UV laser diodes (NUVLDs) emitting at 375 nm make adequate substitutes for 355 nm sources in many situations, but do not work as well with very short wavelength probes like the fluorescent calcium chelator indo-1. In this study, we evaluate a newly available UV 320 nm laser for flow cytometry. While shorter in wavelength that conventional UV lasers, 320 is close to the 325 nm helium-cadmium wavelength used in the past on early benchtop cytometers. A UV 320 nm laser was found to excite almost all Brilliant Ultraviolet dyes to nearly the same level as 355 nm sources. Both 320 nm and 355 nm sources worked equally well for Hoechst and DyeCycle Violet side population analysis of stem cells in mouse hematopoetic tissue. The shorter wavelength UV source also showed excellent excitation of indo-1, a probe that is not compatible with NUVLD 375 nm sources. In summary, a 320 nm laser module made a suitable substitute for conventional 355 nm sources. This laser technology is available in a smaller form factor than current 355 nm units, making it useful for small cytometers with space constraints. © 2017 International Society for Advancement of Cytometry. © 2017 International Society for Advancement of Cytometry.

Near-ultraviolet laser diodes for brilliant ultraviolet fluorophore excitation.

PubMed

Telford, William G

2015-12-01

Although multiple lasers are now standard equipment on most modern flow cytometers, ultraviolet (UV) lasers (325-365 nm) remain an uncommon excitation source for cytometry. Nd:YVO4 frequency-tripled diode pumped solid-state lasers emitting at 355 nm are now the primary means of providing UV excitation on multilaser flow cytometers. Although a number of UV excited fluorochromes are available for flow cytometry, the cost of solid-state UV lasers remains prohibitively high, limiting their use to all but the most sophisticated multilaser instruments. The recent introduction of the brilliant ultraviolet (BUV) series of fluorochromes for cell surface marker detection and their importance in increasing the number of simultaneous parameters for high-dimensional analysis has increased the urgency of including UV sources in cytometer designs; however, these lasers remain expensive. Near-UV laser diodes (NUVLDs), a direct diode laser source emitting in the 370-380 nm range, have been previously validated for flow cytometric analysis of most UV-excited probes, including quantum nanocrystals, the Hoechst dyes, and 4',6-diamidino-2-phenylindole. However, they remain a little-used laser source for cytometry, despite their significantly lower cost. In this study, the ability of NUVLDs to excite the BUV dyes was assessed, along with their compatibility with simultaneous brilliant violet (BV) labeling. A NUVLD emitting at 375 nm was found to excite most of the available BUV dyes at least as well as a UV 355 nm source. This slightly longer wavelength did produce some unwanted excitation of BV dyes, but at sufficiently low levels to require minimal additional compensation. NUVLDs are compact, relatively inexpensive lasers that have higher power levels than the newest generation of small 355 nm lasers. They can, therefore, make a useful, cost-effective substitute for traditional UV lasers in multicolor analysis involving the BUV and BV dyes. Published 2015 Wiley Periodicals Inc. on behalf of ISAC.

Reduction of ultraviolet transmission through cotton T-shirt fabrics with low ultraviolet protection by various laundering methods and dyeing: clinical implications.

PubMed

Wang, S Q; Kopf, A W; Marx, J; Bogdan, A; Polsky, D; Bart, R S

2001-05-01

The public has long been instructed to wear protective clothing against ultraviolet (UV) damage. Our purpose was to determine the UV protection factor (UPF) of two cotton fabrics used in the manufacture of summer T-shirts and to explore methods that could improve the UPF of these fabrics. Each of the two types of white cotton fabrics (cotton T-shirt and mercerized cotton print cloth) used in this study was divided into 4 treatment groups: (1) water-only (machine washed with water), (2) detergent-only (washed with detergent), (3) detergent-UV absorber (washed with detergent and a UV absorber), and (4) dyes (dyed fabrics). Ultraviolet transmission through the fabrics was measured with a spectrophotometer before and after laundry and dyeing treatments. Based on UV transmission through these fabrics, the UPF values were calculated. Before any treatments, the mean UPFs were 4.94 for the T-shirt fabric and 3.13 for the print cloth. There was greater UVA (320-400 nm) than UVB (280-320 nm) transmission through these fabrics. After 5 washings with water alone and with detergent alone, UPF increased by 51% and 17%, respectively, for the cotton T-shirt fabric. Washing the T-shirt fabrics with detergent plus the UV-absorbing agent increased the UPF by 407% after 5 treatments. Dyeing the fabric blue or yellow increased the UPF by 544% and 212%, respectively. Similar changes in UPFs were observed for the print cloth fabric. The two cotton fabrics used in this study offered limited protection against UV radiation as determined by spectrophotometric analysis. Laundering with detergent and water improves UPF slightly by causing fabric shrinkage. Dyeing fabrics or adding a UV-absorbing agent during laundering substantially reduces UV transmission and increases UPF. More UVA is transmitted through the fabrics than UVB.

Endonuclease from Micrococcus luteus Which Has Activity Toward Ultraviolet-Irradiated Deoxyribonucleic Acid: Its Action on Transforming Deoxyribonucleic Acid

PubMed Central

Setlow, R. B.; Setlow, Jane K.; Carrier, W. L.

1970-01-01

An endonuclease purified from Micrococcus luteus makes single-strand breaks in ultraviolet (UV)-irradiated, native deoxyribonucleic acid (DNA). The purified endonuclease is able to reactivate UV-inactivated transforming DNA of Haemophilus influenzae, especially when the DNA is assayed on a UV-sensitive mutant of H. influenzae. After extensive endonuclease action, there is a loss of transforming DNA when assayed on both UV-sensitive and -resistant cells. The endonuclease does not affect unirradiated DNA. The results indicate that the endonuclease function is involved in the repair of biological damage resulting from UV irradiation and that the UV-sensitive mutant is deficient in this step. We interpret the data as indicating that the various steps in the repair of DNA must be well coordinated if repair is to be effective. PMID:4314478

Influence of ambient ultraviolet radiation on Bufo calamita egg development in a semiarid zone (Catalonia, Spain).

PubMed

Oromi, Neus; Marquis, Olivier; Miaud, Claude; Sanuy, Delfi

2008-01-01

Several experiments have shown that ambient ultraviolet-B radiation (UV-B) has negative effects on the development of amphibians' embryos. We studied the effects of UV-B radiation on development, survival and frequency of deformity during egg development in the Natterjack toad (Bufo calamita) from a semiarid region of Lleida (Catalonia, Spain). Eggs exposed to ambient levels of UV-B and those protected from UV-B with a filter exhibited similar developmental rate, mortality rate and frequency of developmental anomalies. These experiments show that eggs of Bufo calamita of the studied population are able to develop normally during embryonic period when exposed to current high levels of UV-B observed in Catalonia. These results will be used as reference for future studies on geographic variation in UV-B tolerance in this species.

Early exposure to ultraviolet-B radiation decreases immune function later in life

PubMed Central

Ceccato, Emma; Cramp, Rebecca L.; Seebacher, Frank; Franklin, Craig E.

2016-01-01

Amphibians have declined dramatically worldwide. Many of these declines are occurring in areas where no obvious anthropogenic stressors are present. It is proposed that in these areas, environmental factors such as elevated solar ultraviolet-B (UV-B) radiation could be responsible. Ultraviolet-B levels have increased in many parts of the world as a consequence of the anthropogenic destruction of the ozone layer. Amphibian tadpoles are particularly sensitive to the damaging effects of UV-B radiation, with exposure disrupting growth and fitness in many species. Given that UV-B can disrupt immune function in other animals, we tested the hypothesis that early UV-B exposure suppresses the immune responses of amphibian tadpoles and subsequent juvenile frogs. We exposed Limnodynastes peronii tadpoles to sublethal levels of UV-B radiation for 6 weeks after hatching, then examined indices of immune function in both the tadpoles and the subsequent metamorphs. There was no significant effect of UV-B on tadpole leucocyte counts or on their response to an acute antigen (phytohaemagglutinin) challenge. However, early UV-B exposure resulted in a significant reduction in both metamorph leucocyte abundance and their response to an acute phytohaemagglutinin challenge. These data demonstrate that early UV-B exposure can have carry-over effects on later life-history traits even if the applied stressor has no immediately discernible effect. These findings have important implications for our understanding of the effects of UV-B exposure on amphibian health and susceptibility to diseases such as chytridiomycosis. PMID:27668081

DNA Damage and Repair in Plants under Ultraviolet and Ionizing Radiations

PubMed Central

Gill, Sarvajeet S.; Gill, Ritu; Jha, Manoranjan; Tuteja, Narendra

2015-01-01

Being sessile, plants are continuously exposed to DNA-damaging agents present in the environment such as ultraviolet (UV) and ionizing radiations (IR). Sunlight acts as an energy source for photosynthetic plants; hence, avoidance of UV radiations (namely, UV-A, 315–400 nm; UV-B, 280–315 nm; and UV-C, <280 nm) is unpreventable. DNA in particular strongly absorbs UV-B; therefore, it is the most important target for UV-B induced damage. On the other hand, IR causes water radiolysis, which generates highly reactive hydroxyl radicals (OH•) and causes radiogenic damage to important cellular components. However, to maintain genomic integrity under UV/IR exposure, plants make use of several DNA repair mechanisms. In the light of recent breakthrough, the current minireview (a) introduces UV/IR and overviews UV/IR-mediated DNA damage products and (b) critically discusses the biochemistry and genetics of major pathways responsible for the repair of UV/IR-accrued DNA damage. The outcome of the discussion may be helpful in devising future research in the current context. PMID:25729769

Uv Spectroscopy of Low-Redshift Active Galaxies -- Cyc 4

NASA Astrophysics Data System (ADS)

Boggess, Albert

1994-01-01

FOS will be used to measure the ultraviolet spectrum of active galaxies. Complementary and simultaneous visual and infrared data will also be obtained. The profile of the emission lines will provide information on the broadening mechanism and dynamics of the emitting regions. Comparison of the profile and radial velocity of the emission lines produced by species of different ioni- zation potential will allow the study of the thermal and density stratification of the emitting regions. The degree of asymmetry of lines at different wave- lengths will allow the absorbing material be identified and located. The ratio of the UV to visible lines, such as those for O I and He II will be used to estimate the reddening along the line of sight. Ratio of emission line fluxes will be compared with models in order to derive the ionization mechanism, elec- tron temperature and density, and chemical composition of the emitting gas. The emission line properties of low luminosity will be compared with those of high luminosity objects in order to investigate the covering factor and evolutionary effects. The continumm spectrum from the UV to the IR will be used to establish the emission mechanism and the nature and luminosity of the energy source. The weak absorption lines will be used to establish the physical conditions and the chemical composition of the gas in: our Galaxy, intergalactic medium and the parent galaxy. Absorption produced by broad line clouds will give information on cloud motion and covering factor.

Modeling Ultraviolet (UV) Light Emitting Diode (LED) Energy Propagation in Reactor Vessels

DTIC Science & Technology

2014-03-27

21 Table 4: UV Mercury Lamps , UV LED Bulbs, and Visible LED Bulb Advantages and Disadvantages...over low pressure mercury lamps include smaller size, minimal start up time, and no hazardous material. Projections show UV LEDs will follow similar

Space Weathering Effects at UV Wavelengths: Asteroids and the Moon

NASA Astrophysics Data System (ADS)

Hendrix, Amanda; Vilas, F.

2006-09-01

Space weathering, the bombardment of airless bodies by micrometeoroids and irradiation by solar wind particles, affects spectra of solar system bodies at visible/near IR (VNIR) wavelengths by darkening and reddening their surface materials, as well as degrading absorption features. We present new results detailing space weathering effects at ultraviolet wavelengths. We focus on new spectral modeling results, and also present spacecraft data of asteroids and the Moon, along with new UV measurements of asteroid families from HST, to demonstrate the effects of varying degrees of weathering and the outcome of weathering on surfaces of different compositions. Weathered surfaces are relatively bright and spectrally blue in the UV; these UV effects can be more obvious than the VNIR effects. The cause of these weathering effects is likely vapor deposition of submicroscopic iron (SMFe), through solar wind irradiation and micrometeoroid bombardment of the bodies' surfaces. In silicate minerals, the NUV region is dominated by a decrease in reflectance with wavelength - the "UV absorption edge.” In contrast to silicates, iron is opaque and relatively bright in the UV, so the addition of SMFe to a silicate grains has the effect of making the UV region brighter; this is in opposition to the situation at longer wavelengths, where the addition of SMFe decreases the albedo. Our spectral modeling results show that the addition of SMFe decreases the steepness of the UV dropoff, in effect making the UV spectrum bluer. This can explain the difference in UV spectral behavior seen between S-class asteroids and less-weathered ordinary chondrite meteorites, and between lunar rocks and more weathered lunar soils. This work is funded in part by Hubble Space Telescope Grant #10557.

UV absorption spectrum of allene radical cations in solid argon

NASA Astrophysics Data System (ADS)

Chin, Chih-Hao; Lin, Meng-Yeh; Huang, Tzu-Ping; Wu, Yu-Jong

2018-05-01

Electron bombardment during deposition of an Ar matrix containing a small proportion of allene generated allene cations. Further irradiation of the matrix sample at 385 nm destroyed the allene cations and formed propyne cations in solid Ar. Both cations were identified according to previously reported IR absorption bands. Using a similar technique, we recorded the ultraviolet absorption spectrum of allene cations in solid Ar. The vibrationally resolved progression recorded in the range of 266-237 nm with intervals of about 800 cm-1 was assigned to the A2E ← X2E transition of allene cations, and the broad continuum absorption recorded in the region of 229-214 nm was assigned to their B2A1 ← X2E transition. These assignments were made based on the observed photolytic behavior of the progressions and the vertical excitation energies and oscillator strengths calculated using time-dependent density functional theory.

A novel two-level dielectric barrier discharge reactor for methyl orange degradation.

PubMed

Tao, Xumei; Wang, Guowei; Huang, Liang; Ye, Qingguo; Xu, Dongyan

2016-12-15

A novel pilot two-level dielectric barrier discharge (DBD) reactor has been proposed and applied for degradation of continuous model wastewater. The two-level DBD reactor was skillfully realized with high space utilization efficiency and large contact area between plasma and wastewater. Various conditions such as applied voltage, initial concentration and initial pH value on methyl orange (MO) model wastewater degradation were investigated. The results showed that the appropriate applied voltage was 13.4 kV; low initial concentration and low initial pH value were conducive for MO degradation. The percentage removal of 4 L MO with concentration of 80 mg/L reached 94.1% after plasma treatment for 80min. Based on ultraviolet spectrum (UV), Infrared spectrum (IR), liquid chromatography-mass spectrometry (LC-MS) analysis of degradation intermediates and products, insights in the degradation pathway of MO were proposed. Copyright © 2016 Elsevier Ltd. All rights reserved.

High-velocity winds from a dwarf nova during outburst

NASA Technical Reports Server (NTRS)

Cordova, F. A.; Mason, K. O.

1982-01-01

An ultraviolet spectrum of the dwarf nova TW Vir during an optical outburst shows shortward-shifted absorption features with edge velocities as high as 4800 km/s, about the escape velocity of a white dwarf. A comparison of this spectrum with the UV spectra of other cataclysmic variables suggests that mass loss is evident only for systems with relatively high luminosities (more than about 10 solar luminosities) and low inclination angles with respect to the observer's line of sight. The mass loss rate for cataclysmic variables is of order 10 to the -11th solar mass per yr; this is from 0.01 to 0.001 of the mass accretion rate onto the compact star in the binary. The mass loss may occur by a mechanism similar to that invoked for early-type stars, i.e., radiation absorbed in the lines accelerates the accreting gas to the high velocities observed.

Structural and vibrational analyses of new potential anticancer drug 2-(phenylmethyl)-2-azaspiro[5.11]heptadecane-1,3,7-trione

NASA Astrophysics Data System (ADS)

Vitnik, Željko J.; Popović-Đorđević, Jelena B.; Vitnik, Vesna D.

2017-06-01

The establishment of the most stable structures of 2-(phenylmethyl)-2-azaspiro[5.11]heptadecane-1,3,7-trione, potential anticancer and antimicrobial drug has been investigated in this work. A detailed interpretation of experimental and calculated IR, UV and NMR spectra were reported. The equilibrium geometry, harmonic vibrational frequencies and electronic properties have been investigated with Density Functional Theory using B3LYP/6-311++G(d,p) method. The scaled theoretical wavenumber showed very good agreement with the experimental values. The charge transfer in the molecule was confirmed with NBO analysis. Ultraviolet-visible spectrum was calculated using TD-DFT method and compared with experimental spectrum. The calculated energy and oscillator strength well reproduce the experimental data. The molecular electrostatic potential surface map portrays potential binding sites of the title molecule.

UV photostability of insect repellents evaluated through Raman spectroscopy

NASA Astrophysics Data System (ADS)

Bório, Viviane G.; Fernandes, Adjaci U.; Silveira, Landulfo

2016-02-01

The use of insect repellents either indoors or at places with incidence of solar radiation has been common due to dengue epidemics in Brazil. The lack of studies on the photostability of these substances has motivated this study, where the main goal was to verify the photostability and photodegradation of some of the commercially insect repellents available under the simulated ultraviolet (UV) radiation, by evaluating the molecular changes using dispersive Raman spectroscopy (830 nm excitation). A laboratory-made chamber was used for irradiating the repellents, where UV-A + UV-B radiations (UV-A: 5.5 mW/cm2 and UV-B 1.5 mW/cm2) can be obtained. The chamber internal temperature did not exceed 31 °C during experiments. The compounds n,n-diethyl-m-toluamide (DEET), IR-3535, andiroba and citronella oils, used as active ingredients in insect repellents, and commercial formula containing DEET (14.5% in ethanol and isopropyl myristate) and IR-3535 (16% in carbopol) were continuously irradiated for 8 h. The Raman spectrum of each sample was obtained before and after UV exposure. The compounds and the commercial formula containing IR-3535 showed photo-stability when irradiated, since no changes in the peaks were found. The commercial formula containing DEET showed spectral decrease at 524, 690, 1003 and 1606 cm-1, assigned to the DEET, and increase at 884 cm-1, assigned to the ethanol. These results indicate that the excipient could influence the photostability of the active ingredient. The Raman spectroscopy can be suitable to monitor the photodegradation under UV irradiation rapidly and reliably.

Action spectrum and mechanisms of UV radiation-induced injury in lupus erythematosus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kochevar, I.E.

1985-07-01

Photosensitivity associated with lupus erythematosus (LE) is well established. The photobiologic basis for this abnormal response to ultraviolet radiation, however, has not been determined. This paper summarizes the criteria for elucidating possible photobiologic mechanisms and reviews the literature relevant to the mechanism of photosensitivity in LE. In patients with LE, photosensitivity to wavelengths shorter than 320 nm has been demonstrated; wavelengths longer than 320 nm have not been adequately evaluated. DNA is a possible chromophore for photosensitivity below 320 nm. UV irradiation of skin produces thymine photodimers in DNA. UV-irradiated DNA is more antigenic than native DNA and the antigenicitymore » of UV-irradiated DNA has been proposed, but not proven, to be involved in the development of clinical lesions. UV irradiation of mice previously injected with anti-UV-DNA antibodies produces Ig deposition and complement fixation that appears to be similar to the changes seen in lupus lesions. Antibodies to UV-irradiated DNA occur in the serum of LE patients although a correlation between antibody titers and photosensitivity was not observed. Defective repair of UV-induced DNA damage does not appear to be a mechanism for the photosensitivity in LE. Other mechanisms must also be considered. The chromophore for photosensitivity induced by wavelengths longer than 320 nm has not been investigated in vivo. In vitro studies indicate that 360-400 nm radiation activates a photosensitizing compound in the lymphocytes and serum of LE patients and causes chromosomal aberrations and cell death. The mechanism appears to involve superoxide anion.« less

Dissecting the IRX-β dust attenuation relation: exploring the physical origin of observed variations in galaxies

NASA Astrophysics Data System (ADS)

Popping, Gergö; Puglisi, Annagrazia; Norman, Colin A.

2017-12-01

The use of ultraviolet (UV) emission as a tracer of galaxy star formation rate (SFR) is hampered by dust obscuration. The empirical relationship between UV-slope, β, and the ratio between far-infrared and UV luminosity, IRX, is commonly employed to account for obscured UV emission. We present a simple model that explores the physical origin of variations in the IRX-β dust attenuation relation. A relative increase in FUV compared to NUV attenuation and an increasing stellar population age cause variations towards red UV-slopes for a fixed IRX. Dust geometry effects (turbulence, dust screen with holes, mixing of stars within the dust screen, two-component dust model) cause variations towards blue UV-slopes. Poor photometric sampling of the UV spectrum causes additional observational variations. We provide an analytic approximation for the IRX-β relation invoking a subset of the explored physical processes (dust type, stellar population age, turbulence). We discuss observed variations in the IRX-β relation for local (sub-galactic scales) and high-redshift (normal and dusty star-forming galaxies, galaxies during the epoch of reionization) galaxies in the context of the physical processes explored in our model. High spatial resolution imaging of the UV and sub-mm emission of galaxies can constrain the IRX-β dust attenuation relation for different galaxy types at different epochs, where different processes causing variations may dominate. These constraints will allow the use of the IRX-β relation to estimate intrinsic SFRs of galaxies, despite the lack of a universal relation.

Antioxidant capacity of flavonoid in soybean seedlings under the joint actions of rare earth element La(III) and ultraviolet-B stress.

PubMed

Peng, Qi; Zhou, Qing

2009-01-01

The dynamic state of antioxidant capacity of flavonoid was investigated for a further demonstration of alleviating the damage of the ultraviolet (UV)-B radiation in the La-treated soybean seedlings under UV-B stress. Using hydroponics culture, the effects of lanthanum on the contents of flavonoid and its ability of antioxidant under elevated ultraviolet-B radiation (280-320 nm) was studied. The results showed flavonoid content in soybean seedlings with UV-B treatment during the stress and convalescent period was increased initially and then decreased, compared with control. Membrane permeability and MDA contents increase at first (first to fifth day) and then decrease (6th-11th day). A similar change of flavonoid content and clearance of flavonoid scavenging O2- and *OH in soybean seedlings occurred. Flavonoid content and ability of flavonoid scavenging O2- and *OH in soybean seedlings with La(III) + UV-B treatment were higher than those of UV-B treatment. Meanwhile, membrane permeability and MDA contents in soybean seedlings were lower than those of UV-B treatment. Compared with control, phenylalanine content in soybean seedlings with UV-B treatment is depressed, phenylalanine content in soybean seedlings with La(III) treatment was enhanced. However, phenylalanine content in La(III) + UV-B treatment is not decreased but slightly increased, compared with UV-B treatment. It suggested that the regulative effect of La(III) of the optimum concentration on flavonoid improved the metabolism of ROS, diminished the concentration of MDA and maintained normal plasma membrane permeability, and that its protective effect against low UV-B radiation is superior to that of high UV-B radiation. The defensive effect of La(III) on soybean seedlings under UV-B stress is carried out on the layer of defense system.

Ultraviolet-B Protective Effect of Flavonoids from Eugenia caryophylata on Human Dermal Fibroblast Cells.

PubMed

Patwardhan, Juilee; Bhatt, Purvi

2015-10-01

The exposure of skin to ultraviolet-B (UV-B) radiations leads to deoxyribonucleic acid (DNA) damage and can induce production of free radicals which imbalance the redox status of the cell and lead to increased oxidative stress. Clove has been traditionally used for its analgesic, anti-inflammatory, anti-microbial, anti-viral, and antiseptic effects. To evaluate the UV-B protective activity of flavonoids from Eugenia caryophylata (clove) buds on human dermal fibroblast cells. Protective ability of flavonoid-enriched (FE) fraction of clove was studied against UV-B induced cytotoxicity, anti-oxidant regulation, oxidative DNA damage, intracellular reactive oxygen species (ROS) generation, apoptotic morphological changes, and regulation of heme oxygenase-1 (HO-1) gene through nuclear factor E2-related factor 2 antioxidant response element (Nrf2 ARE) pathway. FE fraction showed a significant antioxidant potential. Pretreatment of cells with FE fraction (10-40 μg/ml) reversed the effects of UV-B induced cytotoxicity, depletion of endogenous enzymatic antioxidants, oxidative DNA damage, intracellular ROS production, apoptotic changes, and overexpression of Nrf2 and HO-1. The present study demonstrated for the first time that the FE fraction from clove could confer UV-B protection probably through the Nrf2-ARE pathway, which included the down-regulation of Nrf2 and HO-1. These findings suggested that the flavonoids from clove could potentially be considered as UV-B protectants and can be explored further for its topical application to the area of the skin requiring protection. Pretreatment of human dermal fibroblast with flavonoid-enriched fraction of Eugenia caryophylata attenuated effects of ultraviolet-B radiationsIt also conferred protection through nuclear factor E2-related factor 2-antioxidant response pathway and increased tolerance of cells against oxidative stressFlavonoid-enriched fraction can be explored further for topical application to the skin as a ultraviolet-B protectant. Abbreviations used: ABTS: 2,2'-azino-bis-(3-ethylbenzothiazoline- 6-sulphonic acid), AO: Acridine orange, Analysis of variance, ARE: Antioxidant response elements, BSA: Bovine serum albumin, CAPE: Caffeic acid phenethyl ester, CAT: Catalase, DCFH-DA: 2',7'-dichlorofluorescein diacetate, DMEM: Dulbecco's Modified Eagle's Medium, DMSO: Dimethyl sulfoxide, DNA: Deoxyribonucleic acid, DPBS: Dulbecco's phosphate buffered saline, DPPH: 2,2-diphenyl-1-picrylhydrazyl, ECL: Enhanced chemiluminescence, EDTA: Ethylenediaminetetraacetic acid, ELISA: Enzyme-linked immunesorbent assay, EtBr: Ethidium bromide, FBS: Fetal bovine serum, FE fraction: Flavonoid-enriched fraction, FRAP: Ferric reducing antioxidant power, GPx: Glutathione peroxidase, GR: Glutathione reductase, GST: Glutathione-S-transferase, GSH: Reduced glutathione, GSSG: Oxidized glutathione, HDF: Human dermal fibroblast, HEPES: 4-(2-hydroxyethyl)-1-piperazineethanesulphonic acid, HRP: Horseradish peroxidase, HO-1: Heme oxygenase-1, HPTLC: High-performance thin layer chromatography, Keap-1: Kelch-like ECH-associated protein-1, MTT: 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide, NaCl: Sodium chloride, NFDM: Nonfat dry milk, Nrf2: Nuclear factor E2-related factor 2, NQO1: NAD (P) H: Quinine oxidoreductase 1, OH: Hydroxyl ions, PBST: Phosphate buffered saline with 0.1% tween 20, PCR: Polymerase chain reaction, PMSF: Phenylmethanesulfonyl fluoride, Rf: Retention factor, ROS: Reactive oxygen species, rRNA: Ribosomal ribonucleic acid, SDS: Sodium dodecyl sulfate, SOD: Superoxide dismutase, TLC: Thin layer chromatography, TLC-DPPH: Thin layer chromatography-2,2-diphenyl-1-picrylhydrazyl, UV: Ultraviolet, UV-A: Ultraviolet-A, UV-B: Ultraviolet-B, UV-C: Ultraviolet-C, and qPCR: Quantitative polymerase chain reaction.

1Mbps NLOS solar-blind ultraviolet communication system based on UV-LED array

NASA Astrophysics Data System (ADS)

Sun, Zhaotian; Zhang, Lijun; Li, Ping'an; Qin, Yu; Bai, Tingzhu

2018-01-01

We proposed and demonstrated a high data rate ultraviolet communication system based on a 266nm UV LED array with 50mW luminous power. The emitting source is driven by a three outputs constant-current control circuit, whose driving speed is up to 2Mbps. At the receiving side, in order to achieve the amplification for high-speed signal, a two-stage differential preamplifier is designed to make I-V conversion. The voltage-current gain is up to 140dB and bandwidth is 1.9MHz. An experiment is conducted to test the performance of the UV communication system. The effects of elevation angles and transmission distance are analyzed. It is shown that the ultraviolet communication system has high data rate of up to 921.6kbps and bit error rate of less than 10-7 in 150m, which can beat the best record created by UV-LED communication system in terms of the transmission rate.

The Ultraviolet Spectrograph on NASA's Juno Mission

NASA Astrophysics Data System (ADS)

Gladstone, G. Randall; Persyn, Steven C.; Eterno, John S.; Walther, Brandon C.; Slater, David C.; Davis, Michael W.; Versteeg, Maarten H.; Persson, Kristian B.; Young, Michael K.; Dirks, Gregory J.; Sawka, Anthony O.; Tumlinson, Jessica; Sykes, Henry; Beshears, John; Rhoad, Cherie L.; Cravens, James P.; Winters, Gregory S.; Klar, Robert A.; Lockhart, Walter; Piepgrass, Benjamin M.; Greathouse, Thomas K.; Trantham, Bradley J.; Wilcox, Philip M.; Jackson, Matthew W.; Siegmund, Oswald H. W.; Vallerga, John V.; Raffanti, Rick; Martin, Adrian; Gérard, J.-C.; Grodent, Denis C.; Bonfond, Bertrand; Marquet, Benoit; Denis, François

2017-11-01

The ultraviolet spectrograph instrument on the Juno mission (Juno-UVS) is a long-slit imaging spectrograph designed to observe and characterize Jupiter's far-ultraviolet (FUV) auroral emissions. These observations will be coordinated and correlated with those from Juno's other remote sensing instruments and used to place in situ measurements made by Juno's particles and fields instruments into a global context, relating the local data with events occurring in more distant regions of Jupiter's magnetosphere. Juno-UVS is based on a series of imaging FUV spectrographs currently in flight—the two Alice instruments on the Rosetta and New Horizons missions, and the Lyman Alpha Mapping Project on the Lunar Reconnaissance Orbiter mission. However, Juno-UVS has several important modifications, including (1) a scan mirror (for targeting specific auroral features), (2) extensive shielding (for mitigation of electronics and data quality degradation by energetic particles), and (3) a cross delay line microchannel plate detector (for both faster photon counting and improved spatial resolution). This paper describes the science objectives, design, and initial performance of the Juno-UVS.

Ultraviolet (UV) Oxidation Final Report CRADA No. TC-0350-92

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, F.; Oster, S.

This CRADA was a collaborative agreement between the above parties to develop a more efficient ultraviolet (UV) oxidation process than the existing commercial processes. The proposed new process would be capable of completely mineralizing the organic constiruents in aqueous mixedwastes (wastes that contain both radioactive and organic constiruents) and converting them into ordinary radioactive wastes, which would mean cheaper and easier disposal.

The Cloud Detection and Ultraviolet Monitoring Experiment (CLUE)

NASA Technical Reports Server (NTRS)

Barbier, Louis M.; Loh, Eugene C.; Krizmanic, John F.; Sokolsky, Pierre; Streitmatter, Robert E.

2004-01-01

In this paper we describe a new balloon instrument - CLUE - which is designed to monitor ultraviolet (uv) nightglow levels and determine cloud cover and cloud heights with a CO2 slicing technique. The CO2 slicing technique is based on the MODIS instrument on NASA's Aqua and Terra spacecraft. CLUE will provide higher spatial resolution (0.5 km) and correlations between the uv and the cloud cover.

Effects of ultraviolet-B radiation on fungal disease development in Cucumis sativus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Orth, A.B.; Teramura, A.H.; Sisler, H.D.

1990-09-01

Stratospheric ozone depletion due to increased atmospheric pollutants has received considerable attention because of the potential increase in ultraviolet-B (UV-B, 280-320 nm) radiation that will reach the earth's surface. Three cucumber (Cucumis sativus L.) cultivars were exposed to a daily dose of 11.6 kJ m{sup {minus}2} biologically effective ultraviolet-B (UV-B{sub BE}) radiation in an unshaded greenhouse before and/or after injection by Colletotrichum lagenarium (Pass.) Ell. and Halst. or Cladosporium cucumerinum Ell. and Arth. and analyzed for disease development. Two of these cultivars, Poinsette and Calypso Hybrid, were disease resistant, while the third cultivar, Straight-8, was disease susceptible. Preinfectional treatment ofmore » 1 to 7 days with UV-B{sub BE} in Straight-8 led to greater severity of both diseases. Postinfectional UV treatment did not lead to increased disease severity caused by C. lagenarium, while preinfectional UV treatment in both Straight-8 and Poinsette substantially increased disease severity. Although resistant cultivars Poinsette and Calypso Hybrid showed increased anthracnose disease severity when exposed to UV-B, this effect was apparent only on the cotyledons. Both higher spore concentration and exposure to UV-B radiation resulted in greater disease severity. Of the cucumber cultivars tested for UV-B sensitivity, growth in Poinsette was most sensitive and Calypso Hybrid was least sensitive. These preliminary results indicate that the effects of UV-B radiation on disease development in cucumber vary depending on cultivar, timing and duration of UV-B exposure, inoculation level, and plant age.« less

Satellite estimation of surface spectral ultraviolet irradiance using OMI data in East Asia

NASA Astrophysics Data System (ADS)

Lee, H.; Kim, J.; Jeong, U.

2017-12-01

Due to a strong influence to the human health and ecosystem environment, continuous monitoring of the surface ultraviolet (UV) irradiance is important nowadays. The amount of UVA (320-400 nm) and UVB (290-320 nm) radiation at the Earth surface depends on the extent of Rayleigh scattering by atmospheric gas molecules, the radiative absorption by ozone, radiative scattering by clouds, and both absorption and scattering by airborne aerosols. Thus advanced consideration of these factors is the essential part to establish the process of UV irradiance estimation. Also UV index (UVI) is a simple parameter to show the strength of surface UV irradiance, therefore UVI has been widely utilized for the purpose of UV monitoring. In this study, we estimate surface UV irradiance at East Asia using realistic input based on OMI Total Ozone and reflectivity, and then validate this estimated comparing to UV irradiance from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) data. In this work, we also try to develop our own retrieval algorithm for better estimation of surface irradiance. We use the Vector Linearized Discrete Ordinate Radiative Transfer (VLIDORT) model version 2.6 for our UV irradiance calculation. The input to the VLIDORT radiative transfer calculations are the total ozone column (TOMS V7 climatology), the surface albedo (Herman and Celarier, 1997) and the cloud optical depth. Based on these, the UV irradiance is calculated based on look-up table (LUT) approach. To correct absorbing aerosol, UV irradiance algorithm added climatological aerosol information (Arola et al., 2009). The further study, we analyze the comprehensive uncertainty analysis based on LUT and all input parameters.

Theoretical simulation of solar spectra in the middle ultraviolet and visible for atmospheric trace constituent measurements

NASA Technical Reports Server (NTRS)

Goldman, A.

1978-01-01

Two balloon flights reaching float altitudes of approximately 30 and 40 km respectively, were used to obtain scans of the ultraviolet and visible solar spectra. Both flights covered the UV (2800-3500A) at approximately 0.3A resolution and the visible at approximately 0.6A. Numerous scans were obtained during ascent and from float for both flights. All spectral scans obtained at float, from high sun to low sun, were calibrated in wavelength by using several standard solar spectra for line position references. Comparisons of low sun scans and high sun scans show significant atmospheric continuum extinction and have the potential of being used to identify atmospheric lines superimposed on the attenuated solar spectrum. The resolution was mathematically degraded to approximately 5A to better see the broad band atmospheric extinction. This low resolution is also appropriate for the available low resolution absorption coefficients of NO2 and O3, allowing the identification of NO2 and O3 features on the sunset spectra.

Medium-resolution far-ultraviolet spectroscopy of PKS 2155-304

NASA Technical Reports Server (NTRS)

Appenzeller, I.; Mandel, H.; Krautter, J.; Bowyer, S.; Hurwitz, M.; Grewing, M.; Kramer, G.; Kappelmann, N.

1995-01-01

Using the Berkeley spectrometer of the Orbiting Retrievable Far and Extreme Ultraviolet Spectrometer (ORFEUS) we observed the 87-117 nm UV spectrum of the BL Lac object PKS 2155-304 with about 0.5 A resolution. In addition to the expected interstellar lines we detected higher quantum number counterparts of the intergalactic Lyman alpha lines discovered earlier with IUE and the Hubble Space Telescope (HST) in the direction of PKS 2155-304. The Lyman discontinuities indicate for three of the redshifted clouds a combined H I column density of 2-5 x 10(exp 16)/sq cm, while the column density for another cloud appears to be well below 5 x 10(exp 15)/sq cm. No siginificant O VI absorption in the galactic halo toward PKS 2155-304 could be detected from our data. Assuming that saturation effects are negligible for these weak features, we obtain for the O VI column density toward PKS 2155-304 a 3 sigma upper limit of 2.7 x 10(exp 14)/sq cm.

UV Tanning Equipment | Radiation Protection | US EPA

EPA Pesticide Factsheets

2017-08-07

Sun lamps and tanning equipment emit ultraviolet (UV) rays. People who are exposed to UV rays over a long period of time are more likely to develop skin cancer. People with light skin are in more danger because their skin is more sensitive to UV rays.

[Effect of ultraviolet radiation on ALDH1 expression in human lens epithelial cells].

PubMed

Shi, Jingming; Jia, Songbai; Chen, Xuan; Tang, Luosheng

2012-06-01

To determine the apoptosis-inducing effect of ultraviolet light (UV) on human lens epithelial cell (HLEC) and to explore the involvement of changes in ALDH1 folowing UV radiation. HLEC was exposed to the same UV light source and was subsequently divided into 6 groups according to UV radiation time of 0 (control group), 5, 10, 15, and 30 min. Apoptosis was detected by AO/EB staining. Changes of ALDH1 in HLEC were detected by immunohistochemical staining and Western blot. The intensity of immunohistochemical staining and the rate of positive cells decreased with increase of UV time (P<0.05). The rate of positive ALDH1 cells was negatively correlated with the rate of apoptosis (r= -0.92, P<0.05). Western blot showed the integrated absorbance values significantly decreased with the increase of UV time (P<0.05). ALDH1 in HLEC decreases with an increase of UV exposure, which may be related to UV induced apoptosis of HLEC.

Pollen sensitivity to ultraviolet-B (UV-B) suggests floral structure evolution in alpine plants.

PubMed

Zhang, Chan; Yang, Yong-Ping; Duan, Yuan-Wen

2014-03-31

Various biotic and abiotic factors are known to exert selection pressures on floral traits, but the influence of ultraviolet-B (UV-B) light on the evolution of flower structure remains relatively unexplored. We have examined the effectiveness of flower structure in blocking radiation and the effects of UV-B on pollen viability in 42 species of alpine plants in the Hengduan Mountains, China. Floral forms were categorized as either protecting or exposing pollen grains to UV-B. The floral materials of plants with exposed and protected pollen grains were able to block UV-B at similar levels. Exposure to UV-B radiation in vitro resulted in a significantly greater loss of viability in pollen from plant species with protective floral structures. The pronounced sensitivity of protected pollen to UV-B radiation was associated with the type of flower structure. These findings demonstrate that UV-B plays an important role in the evolution of protective floral forms in alpine plants.

Effect of ultraviolet light on water- and fat-soluble vitamins in cow and goat milk.

PubMed

Guneser, O; Karagul Yuceer, Y

2012-11-01

The objective of this study was to investigate and compare the effects of UV light and heat treatment on vitamins A, B(2), C, and E in cow and goat milk. Vitamins were analyzed by reverse-phase high-pressure liquid chromatography. Ultraviolet and pasteurization treatments caused loss in vitamin C in milk. Pasteurization did not have any significant effect on vitamin B(2). However, UV light treatment decreased the amount of vitamin B(2) after several passes of milk through the UV system. In addition, UV light treatment decreased the amount of vitamins A and E. Vitamins C and E are more sensitive to UV light. UV light sensitivities of vitamins were C>E>A>B(2). These results show that UV light treatment decreases the vitamin content in milk. Also, the number of passes through the UV system and the initial amount of vitamins in milk are important factors affecting vitamin levels. Copyright © 2012 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Ultraviolet disinfection of potable water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolfe, R.L.

Because of upcoming surface and groundwater regulations regarding the control of microbiological and chemical contaminants, there is a need to evaluate the feasibility and effectiveness of ultraviolet (UV) radiation for primary disinfection of potable water supplies. Data is presented on microbicidal wavelengths of UV and distribution of energy output for low and medium-pressure arc lamps. Both systems were found to perform equally well for inactivating microorganisms, but each had distinct advantages in different applications. Approximate dosages for 90% inactivation of selected microorganisms by UV is presented in a table. Cost analysis for disinfection is presented in two tables as wellmore » as the advantages and disadvantages of UV disinfection. 38 refs.« less

Simple Ultraviolet Short-Pulse Intensity Diagnostic Method Using Atmosphere

NASA Astrophysics Data System (ADS)

Aota, Tatsuya; Takahashi, Eiichi; Losev, Leonid L.; Tabuchi, Takeyuki; Kato, Susumu; Matsumoto, Yuji; Okuda, Isao; Owadano, Yoshiro

2005-05-01

An ultraviolet (UV) short-pulse intensity diagnostic method using atmosphere as a nonlinear medium was developed. This diagnostic method is based on evaluating the ion charge of the two-photon ionization of atmospheric oxygen upon irradiation with a UV (238-299 nm) short-pulse laser. The observed ion signal increased proportionally to the input intensity to the power of ˜2.2, during the two-photon ionization of atmospheric oxygen. An autocorrelator was constructed and used to successfully measure a UV laser pulse of ˜400 fs duration. Since this diagnostic system is used in the open-air under windowless conditions, it can be set along the beam path and used as a UV intensity monitor.

Radiation-damage-induced phasing: a case study using UV irradiation with light-emitting diodes.

PubMed

de Sanctis, Daniele; Zubieta, Chloe; Felisaz, Franck; Caserotto, Hugo; Nanao, Max H

2016-03-01

Exposure to X-rays, high-intensity visible light or ultraviolet radiation results in alterations to protein structure such as the breakage of disulfide bonds, the loss of electron density at electron-rich centres and the movement of side chains. These specific changes can be exploited in order to obtain phase information. Here, a case study using insulin to illustrate each step of the radiation-damage-induced phasing (RIP) method is presented. Unlike a traditional X-ray-induced damage step, specific damage is introduced via ultraviolet light-emitting diodes (UV-LEDs). In contrast to UV lasers, UV-LEDs have the advantages of small size, low cost and relative ease of use.

High Throughput, High Yield Fabrication of High Quantum Efficiency Back-Illuminated Photon Counting, Far UV, UV, and Visible Detector Arrays

NASA Technical Reports Server (NTRS)

Nikzad, Shouleh; Hoenk, M. E.; Carver, A. G.; Jones, T. J.; Greer, F.; Hamden, E.; Goodsall, T.

2013-01-01

In this paper we discuss the high throughput end-to-end post fabrication processing of high performance delta-doped and superlattice-doped silicon imagers for UV, visible, and NIR applications. As an example, we present our results on far ultraviolet and ultraviolet quantum efficiency (QE) in a photon counting, detector array. We have improved the QE by nearly an order of magnitude over microchannel plates (MCPs) that are the state-of-the-art UV detectors for many NASA space missions as well as defense applications. These achievements are made possible by precision interface band engineering of Molecular Beam Epitaxy (MBE) and Atomic Layer Deposition (ALD).

Effect of surfactant concentration on the ultraviolet sensing properties of ZnO-cellulose nanocomposites

NASA Astrophysics Data System (ADS)

Sahoo, Karunakar; Nayak, J.

2018-05-01

ZnO nanoparticles were grown, on cellulose fiber surfaces, at three different concentrations of hexamethylenetetramine by an aqueous chemical method. A typical ZnO-cellulose nanocomposite showed an enhanced UV sensing activity due to its large surface area. Due to illumination with ultraviolet light, the surface photocurrent of ZnO-cellulose nanocomposite pellet increased from 8.90 × 10‒7 A to 3.18 × 10‒5 A in 15 s. The UV ON to OFF (IUV/IDark) ratio for this sample was 35.73. Hence, an enhancement in the conductivity due to UV illumination shows that our ZnO-cellulose can be used for the fabrication of UV sensors.

Determination of ultraviolet filter activity on coconut oil cosmetic cream

NASA Astrophysics Data System (ADS)

Widiyati, Eni

2017-08-01

A research on determination of ultraviolet (UV) filter activity of cosmetic cream with coconut oil as raw material has been done. The cream was made by mixing the oil phase (coconut oil, stearic acid, lanolin and cetyl alcohol) at 70°C and the water phase (glycerin, aquadest and triethanolamine) at 70°C, while stirring until reached a temperature of 35°C. It was made also a cream with inorganic sunscreen TiO2 and organic sunscreen benzophenone-3 as a comparison. To study the UV filter activity, each cream was determined the UV absorption using UV spectrophotometer. The results show that cosmetic cream with coconut oil as raw material absorbs UV rays in the region of UV-C, whereas the cream with TiO2 absorbs the UV rays from UV-C to UV-A and cream with benzophenone-3 absorbs the UV rays from UV-B to UV-A region. This means that, the cosmetic cream with coconut oil as raw material has an activity as UV-C filter. If this cream is expected to have an activity as a sunscreen, it must be added an inorganic or organic sunscreen or a mixture of both as an active materials.

Influence of ultraviolet light irradiation on the corrosion behavior of carbon steel AISI 1015

NASA Astrophysics Data System (ADS)

Riazi, H. R.; Danaee, I.; Peykari, M.

2013-03-01

Corrosion of carbon steel in sodium chloride solution was studied under ultraviolet illumination using weight loss, polarization, electrochemical impedance spectroscopy and current transient tests. The polarization test revealed an increase in the corrosion current density observed under UV illumination. The impedance spectroscopy indicated that the charge transfer resistance of the system was decreased by irradiation of UV light on a carbon steel electrode. The weight loss of carbon steel in solution increased under UV light, which confirms the results obtained from electrochemical measurements. We propose that the main effect of UV irradiation is on the oxide film, which forms on the surface. Thus, in presence of UV, the conductivity of oxide film might increase and lead to higher metal dissolution and corrosion rate.

Ultraviolet reflectance properties of asteroids

NASA Astrophysics Data System (ADS)

Butterworth, P. S.; Meadows, A. J.

1985-05-01

An analysis of the UV spectra of 28 asteroids obtained with the Internal Ultraviolet Explorer (IUE) satellite is presented. The spectra lie within the range 2100-3200 A. The results are examined in terms of both asteroid classification and of current ideas concerning the surface mineralogy of asteroids. For all the asteroids examined, UV reflectivity declines approximately linearly toward shorter wavelengths. In general, the same taxonomic groups are seen in the UV as in the visible and IR, although there is some evidence for asteroids with anomalous UV properties and for UV subclasses within the S class. No mineral absorption features are reported of strength similar to the strongest features in the visible and IR regions, but a number of shallow absorptions do occur and may provide valuable information on the surface composition of many asteroids.

Galactic Astronomy in the Ultraviolet

NASA Astrophysics Data System (ADS)

Rastorguev, A. S.; Sachkov, M. E.; Zabolotskikh, M. V.

2017-12-01

We propose a number of prospective observational programs for the ultraviolet space observatory WSO-UV, which seem to be of great importance to modern galactic astronomy. The programs include the search for binary Cepheids; the search and detailed photometric study and the analysis of radial distribution of UV-bright stars in globular clusters ("blue stragglers", blue horizontal-branch stars, RR Lyrae variables, white dwarfs, and stars with UV excesses); the investigation of stellar content and kinematics of young open clusters and associations; the study of spectral energy distribution in hot stars, including calculation of the extinction curves in the UV, optical and NIR; and accurate definition of the relations between the UV-colors and effective temperature. The high angular resolution of the observatory allows accurate astrometric measurements of stellar proper motions and their kinematic analysis.

Design of tunable ultraviolet (UV) absorbance by controlling the Agsbnd Al co-sputtering deposition

NASA Astrophysics Data System (ADS)

Zhang, Xin-Yuan; Chen, Lei; Wang, Yaxin; Zhang, Yongjun; Yang, Jinghai; Choi, Hyun Chul; Jung, Young Mee

2018-05-01

Changing the structure and composition of a material can alter its properties; hence, the controlled fabrication of metal nanostructures plays a key role in a wide range of applications. In this study, the structure of Agsbnd Al ordered arrays fabricated by co-sputtering deposition onto a monolayer colloidal crystal significantly increased its ultraviolet (UV) absorbance owing to a tunable localized surface plasmon resonance (LSPR) effect. By increasing the spacing between two nanospheres and the content of aluminum, absorbance in the UV region could be changed from UVA (320-400 nm) to UVC (200-275 nm), and the LSPR peak in the visible region gradually shifted to the UV region. This provides the potential for surface-enhanced Raman scattering (SERS) in both the UV and visible regions.

Impact of nanostructured thin ZnO film in ultraviolet protection

PubMed Central

Sasani Ghamsari, Morteza; Alamdari, Sanaz; Han, Wooje; Park, Hyung-Ho

2017-01-01

Nanoscale ZnO is one of the best choices for ultraviolet (UV) protection, not only because of its antimicrobial properties but also due to its potential application for UV preservation. However, the behavior of nanostructured thin ZnO films and long-term effects of UV-radiation exposure have not been studied yet. In this study, we investigated the UV-protection ability of sol gel-derived thin ZnO films after different exposure times. Scanning electron microscopy, atomic force microscopy, and UV-visible optical spectroscopy were carried out to study the structure and optical properties of the ZnO films as a function of the UV-irradiation time. The results obtained showed that the prepared thin ZnO films were somewhat transparent under the visible wavelength region and protective against UV radiation. The UV-protection factor was 50+ for the prepared samples, indicating that they were excellent UV protectors. The deposited thin ZnO films demonstrated promising antibacterial potential and significant light absorbance in the UV range. The experimental results suggest that the synthesized samples have potential for applications in the health care field. PMID:28096668

Impact of nanostructured thin ZnO film in ultraviolet protection.

PubMed

Sasani Ghamsari, Morteza; Alamdari, Sanaz; Han, Wooje; Park, Hyung-Ho

2017-01-01

Nanoscale ZnO is one of the best choices for ultraviolet (UV) protection, not only because of its antimicrobial properties but also due to its potential application for UV preservation. However, the behavior of nanostructured thin ZnO films and long-term effects of UV-radiation exposure have not been studied yet. In this study, we investigated the UV-protection ability of sol gel-derived thin ZnO films after different exposure times. Scanning electron microscopy, atomic force microscopy, and UV-visible optical spectroscopy were carried out to study the structure and optical properties of the ZnO films as a function of the UV-irradiation time. The results obtained showed that the prepared thin ZnO films were somewhat transparent under the visible wavelength region and protective against UV radiation. The UV-protection factor was 50+ for the prepared samples, indicating that they were excellent UV protectors. The deposited thin ZnO films demonstrated promising antibacterial potential and significant light absorbance in the UV range. The experimental results suggest that the synthesized samples have potential for applications in the health care field.

Experimental evaluation of optimization method for developing ultraviolet barrier coatings

NASA Astrophysics Data System (ADS)

Gonome, Hiroki; Okajima, Junnosuke; Komiya, Atsuki; Maruyama, Shigenao

2014-01-01

Ultraviolet (UV) barrier coatings can be used to protect many industrial products from UV attack. This study introduces a method of optimizing UV barrier coatings using pigment particles. The radiative properties of the pigment particles were evaluated theoretically, and the optimum particle size was decided from the absorption efficiency and the back-scattering efficiency. UV barrier coatings were prepared with zinc oxide (ZnO) and titanium dioxide (TiO2). The transmittance of the UV barrier coating was calculated theoretically. The radiative transfer in the UV barrier coating was modeled using the radiation element method by ray emission model (REM2). In order to validate the calculated results, the transmittances of these coatings were measured by a spectrophotometer. A UV barrier coating with a low UV transmittance and high VIS transmittance could be achieved. The calculated transmittance showed a similar spectral tendency with the measured one. The use of appropriate particles with optimum size, coating thickness and volume fraction will result in effective UV barrier coatings. UV barrier coatings can be achieved by the application of optical engineering.

Testing the relativistic Doppler boost hypothesis for supermassive black hole binary candidates

NASA Astrophysics Data System (ADS)

Charisi, Maria; Haiman, Zoltán; Schiminovich, David; D'Orazio, Daniel J.

2018-06-01

Supermassive black hole binaries (SMBHBs) should be common in galactic nuclei as a result of frequent galaxy mergers. Recently, a large sample of sub-parsec SMBHB candidates was identified as bright periodically variable quasars in optical surveys. If the observed periodicity corresponds to the redshifted binary orbital period, the inferred orbital velocities are relativistic (v/c ≈ 0.1). The optical and ultraviolet (UV) luminosities are expected to arise from gas bound to the individual BHs, and would be modulated by the relativistic Doppler effect. The optical and UV light curves should vary in tandem with relative amplitudes which depend on the respective spectral slopes. We constructed a control sample of 42 quasars with aperiodic variability, to test whether this Doppler colour signature can be distinguished from intrinsic chromatic variability. We found that the Doppler signature can arise by chance in ˜20 per cent (˜37 per cent) of quasars in the nUV (fUV) band. These probabilities reflect the limited quality of the control sample and represent upper limits on how frequently quasars mimic the Doppler brightness+colour variations. We performed separate tests on the periodic quasar candidates, and found that for the majority, the Doppler boost hypothesis requires an unusually steep UV spectrum or an unexpectedly large BH mass and orbital velocity. We conclude that at most approximately one-third of these periodic candidates can harbor Doppler-modulated SMBHBs.

A fully covariant information-theoretic ultraviolet cutoff for scalar fields in expanding Friedmann Robertson Walker spacetimes

NASA Astrophysics Data System (ADS)

Kempf, A.; Chatwin-Davies, A.; Martin, R. T. W.

2013-02-01

While a natural ultraviolet cutoff, presumably at the Planck length, is widely assumed to exist in nature, it is nontrivial to implement a minimum length scale covariantly. This is because the presence of a fixed minimum length needs to be reconciled with the ability of Lorentz transformations to contract lengths. In this paper, we implement a fully covariant Planck scale cutoff by cutting off the spectrum of the d'Alembertian. In this scenario, consistent with Lorentz contractions, wavelengths that are arbitrarily smaller than the Planck length continue to exist. However, the dynamics of modes of wavelengths that are significantly smaller than the Planck length possess a very small bandwidth. This has the effect of freezing the dynamics of such modes. While both wavelengths and bandwidths are frame dependent, Lorentz contraction and time dilation conspire to make the freezing of modes of trans-Planckian wavelengths covariant. In particular, we show that this ultraviolet cutoff can be implemented covariantly also in curved spacetimes. We focus on Friedmann Robertson Walker spacetimes and their much-discussed trans-Planckian question: The physical wavelength of each comoving mode was smaller than the Planck scale at sufficiently early times. What was the mode's dynamics then? Here, we show that in the presence of the covariant UV cutoff, the dynamical bandwidth of a comoving mode is essentially zero up until its physical wavelength starts exceeding the Planck length. In particular, we show that under general assumptions, the number of dynamical degrees of freedom of each comoving mode all the way up to some arbitrary finite time is actually finite. Our results also open the way to calculating the impact of this natural UV cutoff on inflationary predictions for the cosmic microwave background.

Remote Sensing of the Upper Atmosphere and the Ionosphere in the Extreme and Far Ultraviolet: Results from the LITES Experiment aboard the IS

NASA Astrophysics Data System (ADS)

Finn, S. C.; Chakrabarti, S.; Stephan, A. W.; Geddes, G.; Budzien, S. A.; Cook, T.; Aryal, S.; Martel, J.; Galkin, I. A.; Erickson, P. J.

2017-12-01

The Limb-Imaging Ionospheric and Thermospheric Extreme-ultraviolet Spectrograph (LITES) was launched as part of the Space Test Program Houston #5 (STP-H5) payload aboard a commercial resupply flight on February 19, 2017 and was subsequently installed on the International Space Station (ISS). LITES is an imaging spectrograph that spans the 60 - 140 nm wavelength range at 1 nm spectral resolution and samples tangent altitudes 150 - 350 km with 0.2° angular resolution. LITES, in combination with the GPS Radio Occultation and Ultraviolet Photometry - Colocated (GROUP-C) experiment, which includes a GPS receiver and a nadir viewing 135.6 nm photometer, jointly collect new information on the thermosphere and the ionosphere using simultaneous UV and radio emissions. LITES, which uses standard stars to perform in-flight calibration, observes altitude profiles of day and night airglow emissions that are being used to infer thermospheric and ionospheric density profiles. Furthermore, due to the inclination of the ISS, LITES has also observed auroral spectrum and their altitude and spatial variations. Finally, geomagnetic storm effects on its UV emissions can be used to remotely sense their effects on the upper atmospheric morphology. These ISS observations,which are complement to the upcoming ICON and GOLD NASA missions, are focused on ionosphere-atmosphere coupling and global-scale atmospheric response to space weather observed from higher altitudes . We will present an overview of the LITES instrument, some early results from the first few months of operations. We will also summarize the advantages in calibration and validation activities that are possible through space-based LITES, GROUP-C and stellar measurements and simultaneous ground-based optical and radar observations.

Ultraviolet B exposure activates Stat3 signaling via phosphorylation at tyrosine705 in skin of SKH1 hairless mouse: a target for the management of skin cancer?

PubMed

Ahsan, Haseeb; Aziz, Moammir Hasan; Ahmad, Nihal

2005-07-22

Understanding the molecular determinants of ultraviolet (UV) response may lead to the development of novel targets; and therefore, better approaches for the management of cancers, which mainly arise due to the exposure of skin to UV (particularly its UVB spectrum). Signal transducer and activator of transcription (Stat) proteins have been shown to activate multiple signaling pathways to contribute to oncogenesis. Here, we studied the regulation of Stat3 during UVB exposure-mediated responses in the skin of SKH-1 hairless mouse, a model regarded to possess relevance to human situations. Our data demonstrated that a single UVB (180 mJ/cm(2)) exposure to the skin of SKH-1 hairless mice resulted in significant upregulation in (i) protein levels of Stat3 and (ii) phosphorylation of Stat3 at tyrosine(705). Further, the activation of Stat3 was found to be associated with a decrease in apoptotic response of UVB and a gradual time-dependent increase in leukocyte infiltration and hyperplasia. In conclusion, we have demonstrated, for the first time, that UVB exposure to skin resulted in an activation of pro-survival protein Stat3. Based on our observation, we suggest that Stat3 could serve as a target for the management of UVB exposure-mediated damages including skin cancer.

Augmentation of the IUE Ultraviolet Spectral Atlas

NASA Astrophysics Data System (ADS)

Wu, Chi-Chao

IUE is the only and last satellite which will support a survey program to record the ultraviolet spectrum of a large number of bright normal stars. It is important to have a library of high quality low dispersion spectra of sufficient number of stars that provide good coverage in spectral type and luminosity class. Such a library is invaluable for stellar population synthesis of galaxies, studying the nature of distant galaxies, establishing a UV spectral classification system, providing comparison stars for interstellar extinction studies and for peculiar objects or binary systems, studying the effects of temperature, gravity and metallicity on stellar UV spectra, and as a teaching aid. We propose to continue observations of normal stars in order to provide (1) a stellar library as complete as practical, which will be able to support astronomical research by the scientific community long into the future, and (2) a sufficient sample of stars to guard against variability and peculiarity, and to allow a finite range of temperature, gravity, and metallicity in a given spectral type-luminosity class combination. Our primary goal is to collect the data and make them available to the community immediately (without claiming the 6-month proprietary right). The data will be published in the IUE Newsletter as soon as practical, and the data will be prepared for distribution by the IUE Observatory and the NSSDC.

Kr photoionized plasma induced by intense extreme ultraviolet pulses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartnik, A., E-mail: andrzej.bartnik@wat.edu.pl; Wachulak, P.; Fiedorowicz, H.

Irradiation of any gas with an intense EUV (extreme ultraviolet) radiation beam can result in creation of photoionized plasmas. The parameters of such plasmas can be significantly different when compared with those of the laser produced plasmas (LPP) or discharge plasmas. In this work, the photoionized plasmas were created in a krypton gas irradiated using an LPP EUV source operating at a 10 Hz repetition rate. The Kr gas was injected into the vacuum chamber synchronously with the EUV radiation pulses. The EUV beam was focused onto a Kr gas stream using an axisymmetrical ellipsoidal collector. The resulting low temperature Krmore » plasmas emitted electromagnetic radiation in the wide spectral range. The emission spectra were measured either in the EUV or an optical range. The EUV spectrum was dominated by emission lines originating from Kr III and Kr IV ions, and the UV/VIS spectra were composed from Kr II and Kr I lines. The spectral lines recorded in EUV, UV, and VIS ranges were used for the construction of Boltzmann plots to be used for the estimation of the electron temperature. It was shown that for the lowest Kr III and Kr IV levels, the local thermodynamic equilibrium (LTE) conditions were not fulfilled. The electron temperature was thus estimated based on Kr II and Kr I species where the partial LTE conditions could be expected.« less

Kr photoionized plasma induced by intense extreme ultraviolet pulses

NASA Astrophysics Data System (ADS)

Bartnik, A.; Wachulak, P.; Fiedorowicz, H.; Skrzeczanowski, W.

2016-04-01

Irradiation of any gas with an intense EUV (extreme ultraviolet) radiation beam can result in creation of photoionized plasmas. The parameters of such plasmas can be significantly different when compared with those of the laser produced plasmas (LPP) or discharge plasmas. In this work, the photoionized plasmas were created in a krypton gas irradiated using an LPP EUV source operating at a 10 Hz repetition rate. The Kr gas was injected into the vacuum chamber synchronously with the EUV radiation pulses. The EUV beam was focused onto a Kr gas stream using an axisymmetrical ellipsoidal collector. The resulting low temperature Kr plasmas emitted electromagnetic radiation in the wide spectral range. The emission spectra were measured either in the EUV or an optical range. The EUV spectrum was dominated by emission lines originating from Kr III and Kr IV ions, and the UV/VIS spectra were composed from Kr II and Kr I lines. The spectral lines recorded in EUV, UV, and VIS ranges were used for the construction of Boltzmann plots to be used for the estimation of the electron temperature. It was shown that for the lowest Kr III and Kr IV levels, the local thermodynamic equilibrium (LTE) conditions were not fulfilled. The electron temperature was thus estimated based on Kr II and Kr I species where the partial LTE conditions could be expected.

Ultraviolet damage to the eye revisited: eye-sun protection factor (E-SPF®), a new ultraviolet protection label for eyewear.

PubMed

Behar-Cohen, Francine; Baillet, Gilles; de Ayguavives, Tito; Garcia, Paula Ortega; Krutmann, Jean; Peña-García, Pablo; Reme, Charlotte; Wolffsohn, James S

2014-01-01

Ultraviolet (UV) radiation potentially damages the skin, the immune system, and structures of the eye. A useful UV sun protection for the skin has been established. Since a remarkable body of evidence shows an association between UV radiation and damage to structures of the eye, eye protection is important, but a reliable and practical tool to assess and compare the UV-protective properties of lenses has been lacking. Among the general lay public, misconceptions on eye-sun protection have been identified. For example, sun protection is mainly ascribed to sunglasses, but less so to clear lenses. Skin malignancies in the periorbital region are frequent, but usual topical skin protection does not include the lids. Recent research utilized exact dosimetry and demonstrated relevant differences in UV burden to the eye and skin at a given ambient irradiation. Chronic UV effects on the cornea and lens are cumulative, so effective UV protection of the eyes is important for all age groups and should be used systematically. Protection of children's eyes is especially important, because UV transmittance is higher at a very young age, allowing higher levels of UV radiation to reach the crystalline lens and even the retina. Sunglasses as well as clear lenses (plano and prescription) effectively reduce transmittance of UV radiation. However, an important share of the UV burden to the eye is explained by back reflection of radiation from lenses to the eye. UV radiation incident from an angle of 135°-150° behind a lens wearer is reflected from the back side of lenses. The usual antireflective coatings considerably increase reflection of UV radiation. To provide reliable labeling of the protective potential of lenses, an eye-sun protection factor (E-SPF®) has been developed. It integrates UV transmission as well as UV reflectance of lenses. The E-SPF® compares well with established skin-sun protection factors and provides clear messages to eye health care providers and to lay consumers.

Solution-processed nanoparticle super-float-gated organic field-effect transistor as un-cooled ultraviolet and infrared photon counter.

PubMed

Yuan, Yongbo; Dong, Qingfeng; Yang, Bin; Guo, Fawen; Zhang, Qi; Han, Ming; Huang, Jinsong

2013-01-01

High sensitivity photodetectors in ultraviolet (UV) and infrared (IR) range have broad civilian and military applications. Here we report on an un-cooled solution-processed UV-IR photon counter based on modified organic field-effect transistors. This type of UV detectors have light absorbing zinc oxide nanoparticles (NPs) sandwiched between two gate dielectric layers as a floating gate. The photon-generated charges on the floating gate cause high resistance regions in the transistor channel and tune the source-drain output current. This "super-float-gating" mechanism enables very high sensitivity photodetectors with a minimum detectable ultraviolet light intensity of 2.6 photons/μm(2)s at room temperature as well as photon counting capability. Based on same mechansim, infrared photodetectors with lead sulfide NPs as light absorbing materials have also been demonstrated.

ESTIMATION OF UV-B EXPOSURE IN AMPHIBIAN AQUATIC ENVIRONMENTS

EPA Science Inventory

Estimation of ultraviolet radiation B (UV-B; 280 to 320 nm wavelenghts) dose is essential for determining whether UV-B contributes to amphibian population declines and malformations. UV-B dose in wetlands is effected by location, time of day and year, atmospheric levels of ozone,...

UV reflection properties of plumage and skin of domesticated turkeys (Meleagris gallopavo f. dom.) as revealed by UV photography.

PubMed

Bartels, T; Lütgeharm, J-H; Wähner, M; Berk, J

2017-12-01

Reflection and fluorescence properties of feathered and non-feathered body regions of white- and bronze-colored fattening turkeys of various ages were examined by ultraviolet (UV) photography. The examinations were carried out on 20 white-feathered fattening turkeys (B.U.T. 6; 10 males, 10 females) and 20 bronze-feathered fattening turkeys (Grelier 708; 10 males, 10 females) over a period of 21 weeks. The turkeys were photographed once a wk under long-wave UV (UVA) radiation illumination (λ = 344-407 nm) using a digital camera. A bandpass filter was used for UV reflectography to filter out the visible components of the used light source. A longpass filter was used for UV fluorescence photography to avoid blurring in the image due to chromatic aberration as a result of UV illumination. We found that natal down feathers of white-feathered turkeys showed an intense yellowish-green fluorescence under UVA light. UVA fluorescence also was shown by the natal downs of the slightly melanized plumage areas of bronze turkeys. Vaned feathers of white fattening turkeys reflected UVA radiation. Freshly molted feathers were optically distinguishable from the previous feather generation due to their more intense UVA reflection. In bronze turkeys, both the bright end seams of the dark pennaceous feathers and rectrices and the bright banding of primary and secondary remiges reflected UVA radiation. Intense UVA fluorescence was recognizable in day-old chicks of both color variants on the scutellate scales of the legs and toes. In male turkeys of both color variants, UVA-reflecting parts were recognizable with increasing age on the featherless head region. The UVA-fluorescent and UVA-reflective characteristics of the plumage of fattening turkeys were closely related to the plumage color, the feather type, the molting state, and the age of the birds. Further research is needed regarding the UVA-reflecting properties of the turkey plumage and the effects of full-spectrum illumination, including the UVA spectrum, on the behavior and health of fattening turkeys. © 2017 Poultry Science Association Inc.

Whales Use Distinct Strategies to Counteract Solar Ultraviolet Radiation

PubMed Central

Martinez-Levasseur, Laura M.; Birch-Machin, Mark A.; Bowman, Amy; Gendron, Diane; Weatherhead, Elizabeth; Knell, Robert J.; Acevedo-Whitehouse, Karina

2013-01-01

A current threat to the marine ecosystem is the high level of solar ultraviolet radiation (UV). Large whales have recently been shown to suffer sun-induced skin damage from continuous UV exposure. Genotoxic consequences of such exposure remain unknown for these long-lived marine species, as does their capacity to counteract UV-induced insults. We show that UV exposure induces mitochondrial DNA damage in the skin of seasonally sympatric fin, sperm, and blue whales and that this damage accumulates with age. However, counteractive molecular mechanisms are markedly different between species. For example, sperm whales, a species that remains for long periods at the sea surface, activate genotoxic stress pathways in response to UV exposure whereas the paler blue whale relies on increased pigmentation as the season progresses. Our study also shows that whales can modulate their responses to fluctuating levels of UV, and that different evolutionary constraints may have shaped their response strategies. PMID:23989080

A private ultraviolet channel in visual communication.

PubMed Central

Cummings, Molly E; Rosenthal, Gil G; Ryan, Michael J

2003-01-01

Although private communication is considered an important diversifying force in evolution, there is little direct behavioural evidence to support this notion. Here, we show that ultraviolet (UV) signalling in northern swordtails (Xiphophorus) affords a channel for communication that is not accessible to their major predator, Astyanax mexicanus, the Mexican tetra. Laboratory and field behavioural experiments with swordtails (X. nigrensis) and predators (A. mexicanus) demonstrate that male UV ornamentation significantly increases their attractiveness to females but not to this predator, which is less sensitive to UV. UV reflectance among swordtail species correlates positively with tetra densities across habitats, and visual contrast estimates suggest that UV signals are highly conspicuous to swordtails in their natural environment. Cross-species comparisons also support the hypothesis that natural selection drives the use of UV communication. We compared two species, one with high (X. nigrensis) and one with low (X. malinche) Mexican tetra densities. Xiphophorus nigrensis males reflect significantly more UV than X. malinche, exhibit significant UV sexual dimorphism, and UV is a salient component of the sexual communication system. In X. malinche, however, males reflect minimally in the UV, there is no UV sexual dimorphism, and UV does not play a part in its communication system. PMID:12803903

A private ultraviolet channel in visual communication.

PubMed

Cummings, Molly E; Rosenthal, Gil G; Ryan, Michael J

2003-05-07

Although private communication is considered an important diversifying force in evolution, there is little direct behavioural evidence to support this notion. Here, we show that ultraviolet (UV) signalling in northern swordtails (Xiphophorus) affords a channel for communication that is not accessible to their major predator, Astyanax mexicanus, the Mexican tetra. Laboratory and field behavioural experiments with swordtails (X. nigrensis) and predators (A. mexicanus) demonstrate that male UV ornamentation significantly increases their attractiveness to females but not to this predator, which is less sensitive to UV. UV reflectance among swordtail species correlates positively with tetra densities across habitats, and visual contrast estimates suggest that UV signals are highly conspicuous to swordtails in their natural environment. Cross-species comparisons also support the hypothesis that natural selection drives the use of UV communication. We compared two species, one with high (X. nigrensis) and one with low (X. malinche) Mexican tetra densities. Xiphophorus nigrensis males reflect significantly more UV than X. malinche, exhibit significant UV sexual dimorphism, and UV is a salient component of the sexual communication system. In X. malinche, however, males reflect minimally in the UV, there is no UV sexual dimorphism, and UV does not play a part in its communication system.

Ultraviolet absorbing compounds provide a rapid response mechanism for UV protection in some reef fish.

PubMed

Braun, C; Reef, R; Siebeck, U E

2016-07-01

The external mucus surface of reef fish contains ultraviolet absorbing compounds (UVAC), most prominently Mycosporine-like Amino Acids (MAAs). MAAs in the external mucus of reef fish are thought to act as sunscreens by preventing the damaging effects of ultraviolet radiation (UVR), however, direct evidence for their protective role has been missing. We tested the protective function of UVAC's by exposing fish with naturally low, Pomacentrus amboinensis, and high, Thalassoma lunare, mucus absorption properties to a high dose of UVR (UVB: 13.4W∗m(-2), UVA: 6.1W∗m(-2)) and measuring the resulting DNA damage in the form of cyclobutane pyrimidine dimers (CPDs). For both species, the amount of UV induced DNA damage sustained following the exposure to a 1h pulse of high UVR was negatively correlated with mucus absorbance, a proxy for MAA concentration. Furthermore, a rapid and significant increase in UVAC concentration was observed in P. amboinensis following UV exposure, directly after capture and after ten days in captivity. No such increase was observed in T. lunare, which maintained relatively high levels of UV absorbance at all times. P. amboinensis, in contrast to T. lunare, uses UV communication and thus must maintain UV transparent mucus to be able to display its UV patterns. The ability to rapidly alter the transparency of mucus could be an important adaptation in the trade off between protection from harmful UVR and UV communication. Copyright © 2016 Elsevier B.V. All rights reserved.

Old but Still Warm: Far-UV Detection of PSR B0950+08

NASA Astrophysics Data System (ADS)

Pavlov, G. G.; Rangelov, B.; Kargaltsev, O.; Reisenegger, A.; Guillot, S.; Reyes, C.

2017-11-01

We report on a Hubble Space Telescope detection of the nearby, old pulsar B0950+08 (d≃ 262 pc, spin-down age 17.5 Myr) in two far-ultraviolet (FUV) bands. We measured the mean flux densities {\\bar{f}}ν =109+/- 6 nJy and 83 ± 14 nJy in the F125LP and F140LP filters (pivot wavelengths 1438 and 1528 Å). Using the FUV data together with previously obtained optical-UV data, we conclude that the optical-FUV spectrum consists of two components—a nonthermal (presumably magnetospheric) power-law spectrum ({f}ν \\propto {ν }α ) with slope α ˜ -1.2 and a thermal spectrum emitted from the bulk of the neutron star (NS) surface with a temperature in the range of (1-3) × 105 K, depending on interstellar extinction and NS radius. These temperatures are much higher than predicted by NS cooling models for such an old pulsar, which means that some heating mechanisms operate in NSs. A plausible mechanism responsible for the high temperature of PSR B0950+08 is the interaction of vortex lines of the faster rotating neutron superfluid with the slower rotating normal matter in the inner NS crust (vortex creep heating). Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with program #13783.

Ultraviolet Photodissociation Spectroscopy of the Cold K⁺·Calix[4]arene Complex in the Gas Phase.

PubMed

Inokuchi, Yoshiya; Soga, Kazuki; Hirai, Kenta; Kida, Motoki; Morishima, Fumiya; Ebata, Takayuki

2015-08-06

The cooling of ionic species in the gas phase greatly simplifies the UV spectrum, which is of special importance when studying the electronic and geometric structures of large systems, such as biorelated molecules and host-guest complexes. Many efforts have been devoted to achieving ion cooling with a cold, quadrupole Paul ion trap (QIT), but one problem was the insufficient cooling of ions (up to ∼30 K) in the QIT. In this study, we construct a mass spectrometer for the ultraviolet photodissociation (UVPD) spectroscopy of gas-phase cold ions. The instrument consists of an electrospray ion source, a QIT cooled with a He cryostat, and a time-of-flight mass spectrometer. With great care given to the cooling condition, we can achieve ∼10 K for the vibrational temperature of ions in the QIT, which is estimated from UVPD spectra of the benzo-18-crown-6 (B18C6) complex with a potassium ion, K(+)·B18C6. Using this setup, we measure a UVPD spectrum of cold calix[4]arene (C4A) complex with potassium ion, K(+)·C4A. The spectrum shows a very weak band and a strong one at 36018 and 36156 cm(-1), respectively, accompanied by many sharp vibronic bands in the 36000-36600 cm(-1) region. In the geometry optimization of the K(+)·C4A complex, we obtain three stable isomers: one endo and two exo forms. On the basis of the total energy and UV spectral patterns predicted by density functional theory calculations, we attribute the structure of the K(+)·C4A complex to the endo isomer (C2 symmetry), in which the K(+) ion is located inside the cup of C4A. The vibronic bands of K(+)·C4A at 36 018 and 36 156 cm(-1) are assigned to the S1(A)-S0(A) and S2(B)-S0(A) transitions of the endo isomer, respectively.

The budget of biologically active ultraviolet radiation in the earth-atmosphere system

NASA Technical Reports Server (NTRS)

Frederick, John E.; Lubin, Dan

1988-01-01

This study applies the concept of a budget to describe the interaction of solar ultraviolet (UV) radiation with the earth-atmosphere system. The wavelength ranges of interest are the biologically relevant UV-B between 280 and 320 nm and the UV-A from 32000 to 400 nm. The Nimbus 7 solar backscattered ultraviolet (SBUV) instrument provides measurements of total column ozone and information concerning cloud cover which, in combination with a simple model of radiation transfer, define the fractions of incident solar irradiance absorbed in the atmosphere, reflected to space, and absorbed at the ground. Results for the month of July quantify the contribution of fractional cloud cover and cloud optical thickness to the radiation budget's three components. Scattering within a thick cloud layer makes the downward radiation field at the cloud base more isotropic than is the case for clear skies. For small solar zenith angles, typical of summer midday conditions, the effective pathlength of this diffuse irradiance through tropospheric ozone is greater than that under clear-sky conditions. The result is an enhanced absorption of UV-B radiation in the troposphere during cloud-covered conditions. Major changes in global cloud cover or cloud optical thicknesses could alter the ultraviolet radiation received by the biosphere by an amount comparable to that predicted for long-term trends in ozone.

Efficacy and durability of ultraviolet tints in CR-39 ophthalmic lenses.

PubMed

Lee, D Y; Brown, W L; Trachimowicz, R

1997-11-01

Ocular protection from solar ultraviolet (UV) radiation has been emphasized in recent years as a result of the thinning of the ozone layer in the atmosphere. The purpose of this study was to evaluate the absorptive properties of UV tints in CR-39 lenses. We used a spectrophotometer to measure the UV transmittance of three groups of UV tinted CR-39 lenses, including (1) lenses tinted by local optical laboratories: (2) lenses tinted by us, using commercially available dyes: and (3) stock UV lenses that have UV absorptive molecules throughout the lens. We also tested the durability of these tints to daily washing/drying by measuring their UV transmittance characteristics at 3, 6, and 12 months. All the tested lenses absorbed all of the UV-B and at least 99% of UV-A. The durability of these UV tints when exposed to daily washing/drying was excellent: all lenses continued to absorb all of the UV-B and at least 99% of UV-A after 1 year. These data suggest that UV tinted CR-39 lenses provide protection against UV radiation that meets the ANSI Z80.3-1996 Standard for non-prescription sunglasses and fashion eyewear. Furthermore, normal daily washing/drying for 1 year does not cause a significant decrease in the protective effect of the UV tint.

Experimental research and comparison of LDPC and RS channel coding in ultraviolet communication systems.

PubMed

Wu, Menglong; Han, Dahai; Zhang, Xiang; Zhang, Feng; Zhang, Min; Yue, Guangxin

2014-03-10

We have implemented a modified Low-Density Parity-Check (LDPC) codec algorithm in ultraviolet (UV) communication system. Simulations are conducted with measured parameters to evaluate the LDPC-based UV system performance. Moreover, LDPC (960, 480) and RS (18, 10) are implemented and experimented via a non-line-of-sight (NLOS) UV test bed. The experimental results are in agreement with the simulation and suggest that based on the given power and 10(-3)bit error rate (BER), in comparison with an uncoded system, average communication distance increases 32% with RS code, while 78% with LDPC code.

A Study on Ultraviolet Protection of 100% Cotton Knitted Fabric: Effect of Fabric Parameters

PubMed Central

Kan, C. W.

2014-01-01

The effect of fabric parameters such as weight, thickness, and stitch density on the ultraviolet (UV) protection of knitted fabrics was studied. Different knitting structures such as plain, pineapple, lacoste, and other combinations of different knitting stitches of knit, tuck, and miss as well as half milano, full milano, half cardigan, full cardigan, 1 × 1 rib, and interlock were prepared. Experimental results revealed that weight was the most important factor that affected UV protection while thickness and stitch density were not the leading factor in determining UV protection. PMID:24955409

Laboratory Measurements and Modeling of Molecular Photoabsorption Cross Sections in the Ultraviolet: Diatomic Sulfur (S2) and Sulfur Monoxide (SO)

NASA Astrophysics Data System (ADS)

Stark, Glenn; Lyons, James; Herde, Hannah; Nave, Gillian; de Oliveira, Nelson

2015-11-01

Our research program comprises the measurement and modeling of ultraviolet molecular photoabsorption cross sections with the highest practical resolution. It supports efforts to interpret and model observations of planetary atmospheres. Measurement and modeling efforts on diatomic sulfur (S2) and sulfur monoxide (SO) are in progress.S2: Interpretations of atmospheric (Io, Jupiter, cometary comae) S2 absorption features are hindered by a complete lack of laboratory cross section data in the ultraviolet. We are working to quantify the photoabsorption spectrum of S2 from 240 to 300 nm based on laboratory measurements and theoretical calculations. We have constructed an experimental apparatus to produce a stable column of S2 vapor at a temperature of 800 K. High-resolution measurements of the absorption spectrum of the strong B - X system of S2 were completed using the NIST VUV-FTS at Gaithersburg, MD. These measurements are being incorporated into a coupled-channel model of the absorption spectrum of S2 to quantify the contributions from individual bands and to establish the mechanisms responsible for the strong predissociation signature of the B - X system. A successful coupled channels model can then be used to calculate the B - X absorption spectrum at any temperature.SO: There has been a long-standing need for high-resolution cross sections of SO radicals in the UV and VUV regions, where the molecule strongly predissociates, for modeling the atmospheres of Io and Venus, and for understanding sulfur isotope effects in the ancient (pre-O2) atmosphere of Earth. We have produced a measurable column of SO in a continuous-flow DC discharge cell, using SO2 as a parent molecule. Photoabsorption measurements were recently recorded with the high-resolution VUV-FTS on the DESIRS beamline of the SOLEIL synchrotron. A number of strong, predissociated SO bands were measured in the 140 to 200 nm region. Weaker features associated with the SO B - X system were simultaneously recorded, allowing for an approximate determination of the VUV SO band f-values.

8 years of Solar Spectral Irradiance Variability Observed from the ISS with the SOLAR/SOLSPEC Instrument

NASA Astrophysics Data System (ADS)

Damé, Luc; Bolsée, David; Meftah, Mustapha; Irbah, Abdenour; Hauchecorne, Alain; Bekki, Slimane; Pereira, Nuno; Cessateur, Marchand; Gäel; , Marion; et al.

2016-10-01

Accurate measurements of Solar Spectral Irradiance (SSI) are of primary importance for a better understanding of solar physics and of the impact of solar variability on climate (via Earth's atmospheric photochemistry). The acquisition of a top of atmosphere reference solar spectrum and of its temporal and spectral variability during the unusual solar cycle 24 is of prime interest for these studies. These measurements are performed since April 2008 with the SOLSPEC spectro-radiometer from the far ultraviolet to the infrared (166 nm to 3088 nm). This instrument, developed under a fruitful LATMOS/BIRA-IASB collaboration, is part of the Solar Monitoring Observatory (SOLAR) payload, externally mounted on the Columbus module of the International Space Station (ISS). The SOLAR mission, with its actual 8 years duration, will cover almost the entire solar cycle 24. We present here the in-flight operations and performances of the SOLSPEC instrument, including the engineering corrections, calibrations and improved know-how procedure for aging corrections. Accordingly, a SSI reference spectrum from the UV to the NIR will be presented, together with its variability in the UV, as measured by SOLAR/SOLSPEC for 8 years. Uncertainties on these measurements and comparisons with other instruments will be briefly discussed.

Ultraviolet-B-induced DNA damage and ultraviolet-B tolerance mechanisms in species with different functional groups coexisting in subalpine moorlands.

PubMed

Wang, Qing-Wei; Kamiyama, Chiho; Hidema, Jun; Hikosaka, Kouki

2016-08-01

High doses of ultraviolet-B (UV-B; 280-315 nm) radiation can have detrimental effects on plants, and especially damage their DNA. Plants have DNA repair and protection mechanisms to prevent UV-B damage. However, it remains unclear how DNA damage and tolerance mechanisms vary among field species. We studied DNA damage and tolerance mechanisms in 26 species with different functional groups coexisting in two moorlands at two elevations. We collected current-year leaves in July and August, and determined accumulation of cyclobutane pyrimidine dimer (CPD) as UV-B damage and photorepair activity (PRA) and concentrations of UV-absorbing compounds (UACs) and carotenoids (CARs) as UV-B tolerance mechanisms. DNA damage was greater in dicot than in monocot species, and higher in herbaceous than in woody species. Evergreen species accumulated more CPDs than deciduous species. PRA was higher in Poaceae than in species of other families. UACs were significantly higher in woody than in herbaceous species. The CPD level was not explained by the mechanisms across species, but was significantly related to PRA and UACs when we ignored species with low CPD, PRA and UACs, implying the presence of another effective tolerance mechanism. UACs were correlated negatively with PRA and positively with CARs. Our results revealed that UV-induced DNA damage significantly varies among native species, and this variation is related to functional groups. DNA repair, rather than UV-B protection, dominates in UV-B tolerance in the field. Our findings also suggest that UV-B tolerance mechanisms vary among species under evolutionary trade-off and synergism.

On the history of phyto-photo UV science (not to be left in skoto toto and silence).

PubMed

Björn, Lars Olof

2015-08-01

This review of the history of ultraviolet photobiology focuses on the effects of UV-B (280-315 nm) radiation on terrestrial plants. It describes the early history of ultraviolet photobiology, the discovery of DNA as a major ultraviolet target and the discovery of photoreactivation and photolyases, and the later identification of Photosystem II as another important target for damage to plants by UV-B radiation. Some experimental techniques are briefly outlined. The insight that the ozone layer was thinning spurred the interest in physiological and ecological effects of UV-B radiation and resulted in an exponential increase over time in the number of publications and citations until 1998, at which time it was realized by the research community that the Montreal Protocol regulating the pollution of the atmosphere with ozone depleting substances was effective. From then on, the publication and citation rate has continued to rise exponentially, but with an abrupt change to lower exponents. We have now entered a phase when more emphasis is put on the "positive" effects of UV-B radiation, and with more emphasis on regulation than on damage and inhibition. Copyright © 2014 Elsevier Masson SAS. All rights reserved.

Influence of tropospheric ozone control on exposure to ultraviolet radiation at the surface.

PubMed

Madronich, Sasha; Wagner, Mark; Groth, Philip

2011-08-15

Improving air quality by reducing ambient ozone (O(3)) will likely lower O(3) concentrations throughout the troposphere and increase the transmission of solar ultraviolet (UV) radiation to the surface. The changes in surface UV radiation between two control scenarios (nominally 84 and 70 ppb O(3) for summer 2020) in the Eastern two-thirds of the contiguous U.S. are estimated, using tropospheric O(3) profiles calculated with a chemistry-transport model (Community Multi-Scale Air Quality, CMAQ) as inputs to a detailed model of the transfer of solar radiation through the atmosphere (tropospheric ultraviolet-visible, TUV) for clear skies, weighed for the wavelengths known to induce sunburn and skin cancer. Because the incremental emission controls differ according to region, strong spatial variability in O(3) reductions and in corresponding UV radiation increments is seen. The geographically averaged UV increase is 0.11 ± 0.03%, whereas the population-weighted increase is larger, 0.19 ± 0.06%, because O(3) reductions are greater in more densely populated regions. These relative increments in exposure are non-negligible given the already high incidence of UV-related health effects, but are lower by an order of magnitude or more than previous estimates.

The NASA probe-class mission concept, CETUS (Cosmic Evolution Through Ultraviolet Spectroscopy)

NASA Astrophysics Data System (ADS)

Heap, Sara; Danchi, William; Burge, James; Dodson, Kelly; Hull, Anthony; Kendrick, Steven; McCandliss, Stephan; Mehle, Gregory; Purves, Lloyd; Sheikh, David; Valente, Martin; Woodruff, Robert A.

2017-09-01

We report on the early phases of a NASA-sponsored study of CETUS (Cosmic Evolution Through Ultraviolet Spectroscopy), a Probe-class mission concept. By definition, the full lifecycle cost of a Probe mission is greater than 400M (i.e. Explorer missions) and less than 1.00B ("Flagship" missions). The animating idea behind our study is that CETUS can help answer fundamental questions about galaxy evolution by carrying out a massive UV imaging and spectroscopic survey of galaxies and combining its findings with data obtained by other survey telescopes of the 2020's. The CETUS mission concept comprises a 1.5-m wide-field telescope and three scientific instruments: a near-UV multi-object slit spectrograph with a micro-shutter array as the slit device; a near-UV and far-UV camera with angular resolution of 0.42" (near-UV) or 0.55" (far-UV); and a near-UV or far-UV single-object spectrograph aimed at providing access to the UV after Hubble is gone. We describe the scientific rationale for CETUS and the telescope and instruments in their early design phase.

DETECTION OF INFECTIOUS ADENOVIRUS IN TERTIARY TREATED AND UV DISINFECTED WASTEWATER DURING A UV DISINFECTION PILOT STUDY

EPA Science Inventory

An infectious enteric adenovirus was isolated from urban wastewater receiving tertiary treatment and ultraviolet (UV) disinfection. A pilot study was undertaken to investigate the efficacy of UV disinfection (low pressure, high intensity radiation) of total and fecal coliform bac...

Might outdoor heat stress be considered a proxy for the unperceivable effect of the ultraviolet-induced risk of erythema in Florence?

PubMed

Morabito, Marco; Grifoni, Daniele; Crisci, Alfonso; Fibbi, Luca; Orlandini, Simone; Gensini, Gian Franco; Zipoli, Gaetano

2014-01-05

Erythema is the most familiar short-term symptom of human skin associated with overexposure to unperceivable ultraviolet radiation (UV). However, people are able to perceive the warm infrared component of the solar radiation by means of thermal (dis)comfort. This study investigated the potentiality of perceived outdoor heat stress as a valuable proxy for the unperceivable effect of UV-induced risk of erythema in a Mediterranean city. Meteorological data and UVB (280-320nm) measurements were obtained for the 2004-2012 period by a weather station located in the municipality of Florence. Continuous measurements of erythemally effective UV (UVEry) were performed by means of a broadband temperature-corrected radiometer with the spectral response close to the erythemal action spectrum. Hourly UVEry doses were expressed as Standard Erythemal Doses (SEDs). The newly developed Universal Thermal Climate Index (UTCI), that represents the state-of-the-art of outdoor thermal (dis)comfort evaluation, was also assessed. Descriptive analyses of the hourly distribution per month of the frequencies of days with heat stress and UVEry exceeding 2.0, 3.0, 4.5 and 6.0 SEDs were carried out based on the general skin-type characteristics. The association between UVEry and UTCI was analyzed by a two-way contingency table approach. The probability of UVEry exceeding specific SED thresholds when heat stress occurs was often significantly higher than the same probability when no heat stress is perceived. Furthermore, increased magnitudes of the ratios, ranging from the very sensitive to the minimally sensitive skin types, were also found. However, during several months, too many days occur without any signs of heat discomfort, even when people may be exposed to relevant doses of harmful UVEry for the skin of various phototypes. These findings underlie the need for public health authorities to provide differentiated advice per month in relation to potential UV skin damage in the city of Florence. Copyright © 2013 Elsevier B.V. All rights reserved.

Influence of uvA on the erythematogenic and therapeutic effects of uvB irradiation in psoriasis; photoaugmentation effects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boer, J.; Schothorst, A.A.; Suurmond, D.

1981-01-01

The effect of repeated exposure to an additive dose of long ultraviolet (uvA) radiation on the erythemogenic and therapeutic effects of middle ultraviolet (uvB) irradiation was investigated in 8 patients with psoriasis. The surface of the backs of these patients was divided into 2 parts, 1 of which received only uvB irradiation 4 times a week and the other uvA + uvB. uvB was provided by Philips TL-12 lamps and uvA by glass-filtered Philips TL-09 lamps. uvA was held constantly at 10 J/cm2, whereas uvB alone were evaluated by 4 tests during the treatment to determine the minimal erythema dosemore » (MED). Test I (at the start of the therapy) showed a photoaugmentative effect which was no longer apparent in Test III (third week). Test III showed a reversal of the ratios of the MEDs of the sites irradiated with the uvA + uvB and uvB (MED A + B/MED B). This is ascribed to the marked pigmentation which appeared after repeated irradiation with the uvA + uvB combination. Comparison showed for the improvement of the psoriasis no distinct differences between uvA + uvB irradiation and uvB alone, but the former had the cosmetic advantage of giving pleasing tan.« less

Preliminary Study of ZnS:Mn2+ Quantum Dots Response Under UV and X-Ray Irradiation

NASA Astrophysics Data System (ADS)

Saatsakis, G.; Valais, I.; Michail, C.; Fountzoula, C.; Fountos, G.; Koukou, V.; Martini, N.; Kalyvas, N.; Bakas, A.; Sianoudis, I.; Kandarakis, I.; Panayiotakis, G. S.

2017-11-01

Quantum Dots are semiconductor nanocrystals, with their optical properties controlled by their size, shape and material composition. The aim of the present study is to examine the scintillation properties of Manganese Doped Zinc Sulfide (ZnS:Mn 2+) Quantum Dot (QDs) nanocrystals under UV and X-ray irradiation. ZnS:Mn 2+ Quantum Dots, with typical diameter of ZnS dots of 13-20nm (also called scintillation QDs, stQDs), were developed and acquired by Mesolight Inc. The initial stQD sample was a solution of 75mg of ZnS:Mn 2+ dissolved in 100μL of Toluene, having a concentration of 75% w/v. Emission characteristics under UV and X-Ray excitation were examined. Two ultraviolet sources were incorporated (315 nm and 365 nm) as well as a medical X-ray tube with tube voltage from 50 to 130 kVp. Parameters such as Energy Quantum Efficiency under UV excitation and Luminescence Efficiency-LE (light energy flux over exposure rate) under X-ray excitation were examined. Luminescence Efficiency (LE) of ZnS:Mn 2+ was higher than that exhibited by previously examined QDs, (ZnCdSeS:ZnS and ZnCuInS:ZnS). The ability of ZnS:Mn 2+ to transform UV photons energy into optical photons energy, tends to increase while the incident UV wavelength decreases. Energy Quantum Efficiency of the sample exhibited a 6% increase when exposed to 315nm UV light compared to 365 nm. The emission spectrum of the stQDs, exhibited a narrow peak (~585nm) in the yellow range.

Modeling Fe II Emission and Revised Fe II (UV) Empirical Templates for the Seyfert 1 Galaxy I Zw 1

NASA Astrophysics Data System (ADS)

Bruhweiler, F.; Verner, E.

2008-03-01

We use the narrow-lined broad-line region (BLR) of the Seyfert 1 galaxy, I Zw 1, as a laboratory for modeling the ultraviolet (UV) Fe II 2100-3050 Å emission complex. We calculate a grid of Fe II emission spectra representative of BLR clouds and compare them with the observed I Zw 1 spectrum. Our predicted spectrum for log [nH/(cm -3) ] = 11.0, log [ΦH/(cm -2 s-1) ] = 20.5, and ξ/(1 km s-1) = 20, using Cloudy and an 830 level model atom for Fe II with energies up to 14.06 eV, gives a better fit to the UV Fe II emission than models with fewer levels. Our analysis indicates (1) the observed UV Fe II emission must be corrected for an underlying Fe II pseudocontinuum; (2) Fe II emission peaks can be misidentified as that of other ions in active galactic nuclei (AGNs) with narrow-lined BLRs possibly affecting deduced physical parameters; (3) the shape of 4200-4700 Å Fe II emission in I Zw 1 and other AGNs is a relative indicator of narrow-line region (NLR) and BLR Fe II emission; (4) predicted ratios of Lyα, C III], and Fe II emission relative to Mg II λ2800 agree with extinction corrected observed I Zw 1 fluxes, except for C IV λ1549 (5) the sensitivity of Fe II emission strength to microturbulence ξ casts doubt on existing relative Fe/Mg abundances derived from Fe II (UV)/Mg II flux ratios. Our calculated Fe II emission spectra, suitable for BLRs in AGNs, are available at http://iacs.cua.edu/people/verner/FeII. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 05-26555.

Effects of ultraviolet-B exposure of Arabidopsis thaliana on herbivory by two crucifer-feeding insects (Lepidoptera)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant-Petersson, J.; Renwick, J.A.A.

1996-02-01

Larvae of Pieris rapae (L.) (Lepidoptera: Pieridae) and Trichoplusia ni (Huebner) (Lepidoptera: Noctuidae) were fed foliage from Arabidopsis thaliana (L.) Heynh. plants that had received a high dose of ultraviolet-B (UV-B) or from control plants. Treatments were compared using the Student independent t-test. P. rapae larvae consumed less of the foliage exposed to UV-B than control foliage. This difference as significant in older but not younger larvae, and the older P. rapae larvae fed foliage exposed to UV-B weighed significantly less. For T. ni, however, consumption and larval weights were approximately equal for UV-exposed and control foliage. No significant differencesmore » in growth rates per unit consumption on UV-exposed versus control foliage were found for either species. Chemical analysis showed that flavonoid levels increased in response to UV-B. Results suggested that UV-inducible flavonoids may act as feeding deterrents to P. rapae but not to T. ni. 56 refs., 6 figs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Undeen, A.H.; Vander Meer, R.K.

Spores of Nosema algerae Vavra and Undeen were subjected to various dosages of 254 nm ultraviolet radiation (UV). Very high dosages of UV were required to block germination. Germination was normal immediately after UV dosages of 0.2 to 1.0 J/cm2, followed by a delayed effect in which both percentage germination and the intrasporal concentration of trehalose decreased with time after UV exposure. Although a few spores were germinated, most of them were inactivated (rendered temporarily unable to germinate) by exposure to UV of 1.1 J/cm2. Ultraviolet radiation between 1.1 and 3.4 J/cm2 stimulated spores to germinate. However, spores were completelymore » unable to germinate immediately after exposure to dosages above 3.8 J/cm2. Ammonia had little effect on stimulation by UV but was inhibitory to germination after stimulation had occurred. These results demonstrate that UV behaves like a germination stimulus and are discussed in terms of the hypothesis that germination is initiated by the breakdown of barriers between trehalose and trehalase.« less

Effect and mechanism of a High Gradient Magnetic Separation (HGMS) and Ultraviolet (UV) composite process on the inactivation of microbes in ballast water.

PubMed

Ren, Zhijun; Zhang, Lin; Shi, Yue; Leng, Xiaodong; Shao, Jingchao

2016-07-15

The patented technology of a High Gradient Magnetic Separation (HGMS)-Ultraviolet (UV) composite process was used to treat ballast water. Staphylococcus aureus (S. aureus) was selected as the reference bacteria. After treatment by the HGMS-UV process, the concentration of S. aureus on the log 10 scale was lower than 2 at different flow rates, S. aureus suffered the most serious damage, and K(+) leakage of the bacteria was 1.73mg/L higher than separate 60min UV irradiation (1.17mg/L) and HGMS (0.12mg/L) processes. These results demonstrated that the HGMS-UV composite process was an effective approach to treat ballast water. Further, the HGMS process had synergistic action on the subsequent UV irradiation process and accelerated cell membrane damage. Meanwhile, the results of superoxide dismutase (SOD) activities of bacteria and DNA band analyses indicated that the inactivation mechanisms were different for HGMS and UV irradiation. Copyright © 2016 Elsevier Ltd. All rights reserved.

Ultraviolet laser effects on the cornea

NASA Astrophysics Data System (ADS)

Zuclich, Joseph A.

1990-07-01

Ultraviolet radiation in the ambient environment or from artificial sources may pose both acute and chronic hazards to the skin and the ocular tissues. In general terrestrial conditions have evolved such that there are only narrow safety margins between ambient UV levels and exposure levels harmful to the human. Obvious examples of acute consequences ofUV overexposure are sunburn and snowblindness as well as analogous conditions induced by artificial sources such as the welder''s arc mercury vapor lamps and UV-emitting lasers. Further chronic UV exposure is strongly implicated as a causative agent in certain types of cataract and skin cancer. This presentation will summarize a number of specific cases where UV radiation affected the primate cornea. Data presented will include the action spectra for far- and near-UV induced ocular damage the pulsewidth and total energy dependencies of ocular thresholds studies of cumulative effects of repeated UV exposures and quantitative determinations of tissue repair or recovery rates. Depending on the exposure parameters utilized photochemical thermal or photoablative damage mechanisms may prevail. 1.

Preparation and Characterization of UV Emitting Fluoride Phosphors for Phototherapy Lamps

NASA Astrophysics Data System (ADS)

Belsare, P. D.; Moharil, S. V.; Joshi, C. P.; Omanwar, S. K.

2011-10-01

The use of ultraviolet radiation for the treatment of various skin diseases is well known for long time. Phototherapy employs ultraviolet-blue radiation to cure skin diseases. The basis of phototherapy is believed to be the direct interaction of light of certain frequencies with tissue to cause a change in immune response. Currently dermatologists use UV lamps having specific emissions in UV region for treating various skin diseases. The treatment of skin diseases using artificial sources of UV radiation is now well established and more than 50 types of skin diseases are treated by phototherapy. This is an effective treatment for many skin disorders, such as psoriasis, vitiligo, ofujis disease, morphea , scleroderma, cutaneous T-cell lymphoma, lupus erythematosus, hyperbilirubinemia commonly known as infant jaundice, acne vulgaris, This paper reports photoluminescence properties of UV emitting fluoride phosphors prepared by wet chemical method. Emission characteristics of these phosphors are found similar to those of commercial UV lamp phosphors with comparable intensities. The usefulness of UV emitting fluoride phosphor is discussed in the paper.

Ultraviolet radiation and the snow alga Chlamydomonas nivalis (Bauer) Wille.

PubMed

Gorton, Holly L; Vogelmann, Thomas C

2003-06-01

Aplanospores of Chlamydomonas nivalis are frequently found in high-altitude, persistent snowfields where they are photosynthetically active despite cold temperatures and high levels of visible and ultraviolet (UV) radiation. The goals of this work were to characterize the UV environment of the cells in the snow and to investigate the existence and localization of screening compounds that might prevent UV damage. UV irradiance decreased precipitously in snow, with UV radiation of wavelengths 280-315 nm and UV radiation of wavelengths 315-400 nm dropping to 50% of incident levels in the top 1 and 2 cm, respectively. Isolated cell walls exhibited UV absorbance, possibly by sporopollenin, but this absorbance was weak in images of broken or plasmolyzed cells observed through a UV microscope. The cells also contained UV-absorbing cytoplasmic compounds, with the extrachloroplastic carotenoid astaxanthin providing most of the screening. Additional screening compound(s) soluble in aqueous methanol with an absorption maximum at 335 nm played a minor role. Thus, cells are protected against potentially high levels of UV radiation by the snow itself when they live several centimeters beneath the surface, and they rely on cellular screening compounds, chiefly astaxanthin, when located near the surface where UV fluxes are high.

Wavelength dependent recovery of UV-mediated damage: Tying up the loose ends of optical based powdery mildew management.

PubMed

Suthaparan, Aruppillai; Pathak, Ranjana; Solhaug, Knut Asbjørn; Gislerød, Hans Ragnar

2018-01-01

Controlled environment chamber experiments at Petri dish level were conducted to examine the wavelength and dose dependent efficacy of ultraviolet (UV) radiation, the recovery action potential of optical radiation applied concomitantly/subsequently to effective UV treatment, and the lapse time between UV treatment and subsequent exposure to recovery wavelength on germination efficiency of Oidium neolycopersici conidia. Conidia of eight- to nine-day-old colonies were dusted on water agar surface in Petri dishes and exposed to UV treatments (without lid). Immediately after UV treatments, Petri dishes were sealed and incubated in darkness or differing optical environments generated using seven different radiation sources (range 290nm to 780nm). Twenty-four hours after UV treatment, fifty conidia from each sample were assessed for germination. Compared to non-UV controls, <10% of the conidia germinated after 30s of exposure to 254nm or 283nm UV and subsequent dark incubation. Conidia germination was almost negligible if the exposure duration increased to 4min. Germination was about 60% with broad spectrum UV after 1min of exposure, and about 35% after 2 to 4min of exposure. There was no reduction of conidia germination with the exposure of ≤4min with 310nm. With the tested wavelength and dose ranges, germination recovery was effective in the 350nm to 500nm range. Germination efficiency of conidia treated with effective UV was significantly higher (>73%) if incubated subsequently in the 350nm to 500nm range (germination recovery). Furthermore, germination recovery depends on the characteristics of UV treatment (wavelength, and duration of exposure) and the lapse time between UV treatment and subsequent exposure to optical radiation in the recovery range. The findings of this study provide key criteria for wavelength selection, combination and application time in the optical radiation range, enabling improved design of optical based management strategies against powdery mildews. Copyright © 2017 Elsevier B.V. All rights reserved.

Ultraviolet Spectrum And Chemical Reactivity Of CIO Dimer

NASA Technical Reports Server (NTRS)

Demore, William B.; Tschuikow-Roux, E.

1992-01-01

Report describes experimental study of ultraviolet spectrum and chemical reactivity of dimer of chlorine monoxide (CIO). Objectives are to measure absorption cross sections of dimer at near-ultraviolet wavelengths; determine whether asymmetrical isomer (CIOCIO) exists at temperatures relevant to Antarctic stratosphere; and test for certain chemical reactions of dimer. Important in photochemistry of Antarctic stratosphere.

Contrastive Study on the Structure and the Ultraviolet Absorption Property of Multiple-Doped and Element-Doped ZnO Thin Films

NASA Astrophysics Data System (ADS)

Xu, Yunyun; Zhang, Tao; Lin, Zhenrong; Tian, Yanfeng; Zhou, Shandan

Sb2O3- and CeO2-doped ZnO thin films were prepared by RF magnetron sputtering technique. The influence of Sb2O3 and CeO2 on the structure and ultraviolet (UV) absorption properties was studied by X-ray diffraction and UV-Vis spectrophotometry. Results show that multiple doping of films had a prominent effect on the development of crystal grains and the UV absorption property. Ce and Sb exist in many forms in the ZnO film. The multiple-doped films also show enhanced UVA absorption, and the UV absorption peak widens and the absorption intensity increases. Sb plays a dominant role on the structure and UV absorption of ZnO thin films, which are enhanced by Ce.

Effectiveness of automated ultraviolet-C light for decontamination of textiles inoculated with Enterococcus faecium.

PubMed

Smolle, C; Huss, F; Lindblad, M; Reischies, F; Tano, E

2018-01-01

Healthcare textiles are increasingly recognized as potential vehicles for transmission of hospital-acquired infections. This study tested the ability of an automated ultraviolet-C (UV-C) room disinfection device (Tru-D Smart UV-C) to decontaminate textiles inoculated with Enterococcus faecium in a clinical setting. Contaminated polycotton (50/50 polyester/cotton) swatches were distributed to predefined locations in a ward room and exposed to UV-C light. UV-C decontamination reduced E. faecium counts by a mean log 10 reduction factor of 1.37 (all P = 0.005, Wilcoxon signed rank test). UV-C decontamination may be a feasible adjunctive measure to conventional laundering to preserve the cleanliness of healthcare textiles in ward rooms. Copyright © 2017 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

Lanthanum (III) regulates the nitrogen assimilation in soybean seedlings under ultraviolet-B radiation.

PubMed

Huang, Guangrong; Wang, Lihong; Zhou, Qing

2013-01-01

Ultraviolet-B (UV-B, 280-320 nm) radiation has seriously affected the growth of plants. Finding the technology/method to alleviate the damage of UV-B radiation has become a frontal topic in the field of environmental science. The pretreatment with rare earth elements (REEs) is an effective method, but the regulation mechanism of REEs is unknown. Here, the regulation effects of lanthanum (La(III)) on nitrogen assimilation in soybean seedlings (Glycine max L.) under ultraviolet-B radiation were investigated to elucidate the regulation mechanism of REEs on plants under UV-B radiation. UV-B radiation led to the inhibition in the activities of the key enzymes (nitrate reductase, glutamine synthetase, glutamate synthase) in the nitrogen assimilation, the decrease in the contents of nitrate and soluble proteins, as well as the increase in the content of amino acid in soybean seedlings. The change degree of UV-B radiation at the high level (0.45 W m(-2)) was higher than that of UV-B radiation at the low level (0.15 W m(-2)). The pretreatment with 20 mg L(-1) La(III) could alleviate the effects of UV-B radiation on the activities of nitrate reductase, glutamine synthetase, glutamate synthase, and glutamate dehydrogenase, promoting amino acid conversion and protein synthesis in soybean seedlings. The regulation effect of La(III) under UV-B radiation at the low level was better than that of UV-B radiation at the high level. The results indicated that the pretreatment with 20 mg L(-1) La(III) could alleviate the inhibition of UV-B radiation on nitrogen assimilation in soybean seedlings.

Ultraviolet sensor as integrity monitor for enhanced flight vision system (EFVS) approaches to Cat II RVR conditions

NASA Astrophysics Data System (ADS)

McKinley, John B.; Pierson, Roger; Ertem, M. C.; Krone, Norris J., Jr.; Cramer, James A.

2008-04-01

Flight tests were conducted at Greenbrier Valley Airport (KLWB) and Easton Municipal Airport / Newnam Field (KESN) in a Cessna 402B aircraft using a head-up display (HUD) and a Norris Electro Optical Systems Corporation (NEOC) developmental ultraviolet (UV) sensor. These flights were sponsored by NEOC under a Federal Aviation Administration program, and the ultraviolet concepts, technology, system mechanization, and hardware for landing during low visibility landing conditions have been patented by NEOC. Imagery from the UV sensor, HUD guidance cues, and out-the-window videos were separately recorded at the engineering workstation for each approach. Inertial flight path data were also recorded. Various configurations of portable UV emitters were positioned along the runway edge and threshold. The UV imagery of the runway outline was displayed on the HUD along with guidance generated from the mission computer. Enhanced Flight Vision System (EFVS) approaches with the UV sensor were conducted from the initial approach fix to the ILS decision height in both VMC and IMC. Although the availability of low visibility conditions during the flight test period was limited, results from previous fog range testing concluded that UV EFVS has the performance capability to penetrate CAT II runway visual range obscuration. Furthermore, independent analysis has shown that existing runway light emit sufficient UV radiation without the need for augmentation other than lens replacement with UV transmissive quartz lenses. Consequently, UV sensors should qualify as conforming to FAA requirements for EFVS approaches. Combined with Synthetic Vision System (SVS), UV EFVS would function as both a precision landing aid, as well as an integrity monitor for the GPS and SVS database.

On thermal conditions and properties of thallium bromide single crystals grown by the Electro Dynamic Gradient method

NASA Astrophysics Data System (ADS)

Zheng, Zhiping; Yu, Yongtao; Gong, Shuping; Fu, Qiuyun; Zhou, Dongxiang

2013-05-01

The Electro Dynamic Gradient (EDG) method has been proved to be a feasible way to grow TlBr crystals in our previous work. In this research, the influence of thermal conditions such as cooling rate during growth process on the crystal performance was investigated. Crystals of approximately 12 mm diameter were obtained by the EDG method at different cooling rates during the growth process, and the quality of the crystals was routinely evaluated by X-ray diffraction (XRD), infrared (IR) and ultraviolet (UV) transmission, I-V measurement and energy response spectrum. The results proved that thermal conditions during growth had a profound influence on the characteristics of the crystals.

Synthesis of Deoxyribonucleic Acid After Ultraviolet Irradiation of Sensitive and Resistant Haemophilus influenzae

PubMed Central

Modak, Sohan P.; Setlow, Jane K.

1969-01-01

Synthesis of deoxyribonucleic acid (DNA) has been measured as a function of ultraviolet (UV) radiation dose in wild-type and seven UV-sensitive strains of Haemophilus influenzae. At the UV doses used, all strains were able to resume DNA synthesis, even those which are unable to excise pyrimidine dimers from their DNA. These excisionless strains showed longer UV-induced delays in DNA synthesis than all but one of the other strains. The longest delay was shown by DB117, a strain which can excise dimers but which is recombination deficient and unable to rejoin X ray-induced single-strand breaks. All strains showed a progressive decrease in sensitivity as they approached the stationary phase. PMID:5305934

Ultraviolet Light Curves of Gaia16apd in Superluminous Supernova Models

NASA Astrophysics Data System (ADS)

Tolstov, Alexey; Zhiglo, Andrey; Nomoto, Ken'ichi; Sorokina, Elena; Kozyreva, Alexandra; Blinnikov, Sergei

2017-08-01

Observations of Gaia16apd revealed extremely luminous ultraviolet emission among superluminous supernovae (SLSNe). Using radiation hydrodynamics simulations, we perform a comparison of UV light curves, color temperatures, and photospheric velocities between the most popular SLSN models: pair-instability supernova, magnetar, and interaction with circumstellar medium. We find that the interaction model is the most promising to explain the extreme UV luminosity of Gaia16apd. The differences in late-time UV emission and in color evolution found between the models can be used to link an observed SLSN event to the most appropriate model. Observations at UV wavelengths can be used to clarify the nature of SLSNe and more attention should be paid to them in future follow-up observations.