Sample records for unconsolidated porous materials

  1. Influence of Oil Saturation Upon Spectral Induced Polarization of Oil Bearing Sands

    EPA Science Inventory

    The presence of oil in an unconsolidated granular porous material such as sand changes both the resistivity of the material and the value of the phase shift between the low-frequency current and the voltage. The resistivity and the phase angle can be written as a complex-valued r...

  2. Successful Sampling Strategy Advances Laboratory Studies of NMR Logging in Unconsolidated Aquifers

    NASA Astrophysics Data System (ADS)

    Behroozmand, Ahmad A.; Knight, Rosemary; Müller-Petke, Mike; Auken, Esben; Barfod, Adrian A. S.; Ferré, Ty P. A.; Vilhelmsen, Troels N.; Johnson, Carole D.; Christiansen, Anders V.

    2017-11-01

    The nuclear magnetic resonance (NMR) technique has become popular in groundwater studies because it responds directly to the presence and mobility of water in a porous medium. There is a need to conduct laboratory experiments to aid in the development of NMR hydraulic conductivity models, as is typically done in the petroleum industry. However, the challenge has been obtaining high-quality laboratory samples from unconsolidated aquifers. At a study site in Denmark, we employed sonic drilling, which minimizes the disturbance of the surrounding material, and extracted twelve 7.6 cm diameter samples for laboratory measurements. We present a detailed comparison of the acquired laboratory and logging NMR data. The agreement observed between the laboratory and logging data suggests that the methodologies proposed in this study provide good conditions for studying NMR measurements of unconsolidated near-surface aquifers. Finally, we show how laboratory sample size and condition impact the NMR measurements.

  3. Multiple scattering by infinitely long cylindrical glass inclusions in a saturated Biot porous medium of glass beads.

    PubMed

    Trabelsi, W; Franklin, H; Tinel, A

    2016-05-01

    The resonance spectrum of sets of two to five infinitely long parallel cylindrical glass inclusions in a fluid saturated porous matrix of unconsolidated glass beads is investigated. The ratio of bead diameters to inclusion diameters is 1/5. The far field form functions and the related phase derivatives are calculated by using an exact multiple scattering formalism and by assuming that the porous medium obeys Biot's model. In order to validate this hypothesis, comparisons between theory and experiments are done in the special case of a fast incident wave on a set of two and three inclusions.

  4. Laboratory investigations of the physics of steam flow in a porous medium

    USGS Publications Warehouse

    Herkelrath, W.N.; Moench, A.F.

    1982-01-01

    Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. This theory is used extensively in modeling pressure-transient behavior in vapor-dominated geothermal systems. Transient, superheated steam-flow experiments were run by bringing a cylinder of porous material to a uniform initial pressure, and then making a step increase in pressure at one end of the sample, while monitoring the pressure-transient breakthrough at the other end. It was found in experiments run at 100?, 125?, and 146?C that the time required for steam-pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10 to 25 times longer than predicted by theory. It is hypothesized that the delay in the steam-pressure transient was caused by adsorption of steam in the porous sample. In order to account for steam adsorption, a sink term was included in the conservation of mass equation. In addition, energy transfer in the system has to be considered because latent heat is released when steam adsorption occurs, increasing the sample temperature by as much as 10?C. Finally, it was recognized that the steam pressure was a function of both the temperature and the amount of adsorption in the sample. For simplicity, this function was assumed to be in equilibrium adsorption isotherm, which was determined by experiment. By solving the modified mass and energy equations numerically, subject to the empirical adsorption isotherm relationship, excellent theoretical simulation of the experiments was achieved. The experiments support the hypothesis that adsorption of steam can strongly influence steam pressure-transient behavior in porous media; the results suggest that the modified steam-flow theory, which includes steam adsorption terms, should be used in modeling steam flow in vapor-dominated geothermal systems.

  5. Laboratory investigations of steam flow in a porous medium

    USGS Publications Warehouse

    Herkelrath, W.N.; Moench, A.F.; O'Neal, II

    1983-01-01

    Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. This theory is used in modeling pressure transient behavior in vapor dominated geothermal systems. Transient, superheated steam flow experiments were run by bringing a cylinder of porous material to a uniform initial pressure and then making a step increase in pressure at one end of the sample while monitoring the pressure transient breakthrough at the other end. It was found in experiments run at 100°, 125°, and 146°C that the time required for steam pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10–25 times longer than predicted by conventional superheated steam flow theory. It is hypothesized that the delay in the steam pressure transient was caused by adsorption of steam in the porous sample. In order to account for steam adsorption, a sink term was included in the conservation of mass equation. In addition, energy transfer in the system has to be considered because latent heat is released when steam adsorption occurs, increasing the sample temperature by as much as 10°C. Finally, it was recognized that the steam pressure was a function of both the temperature and the amount of adsorption in the sample. This function was assumed to be an equilibrium adsorption isotherm, which was determined by experiment. By solving the modified mass and energy equations numerically, subject to the empirical adsorption isotherm relationship, excellent theoretical simulation of the experiments was achieved.

  6. Dynamic regimes of buoyancy-affected two-phase flow in unconsolidated porous media.

    PubMed

    Stöhr, M; Khalili, A

    2006-03-01

    The invasion and subsequent flow of a nonwetting fluid (NWF) in a three-dimensional, unconsolidated porous medium saturated with a wetting fluid of higher density and viscosity have been studied experimentally using a light-transmission technique. Distinct dynamic regimes have been found for different relative magnitudes of viscous, capillary, and gravity forces. It is shown that the ratio of viscous and hydrostatic pressure gradients can be used as a relevant dimensionless number K for the characterization of the different flow regimes. For low values of K, the invasion is characterized by the migration and fragmentation of isolated clusters of the NWF resulting from the prevalence of gravity and capillary forces. At high values of K, the dominance of viscous and gravity forces leads to an anisotropic fingerlike invasion. When the invasion stops after the breakthrough of the NWF at the open upper boundary, the invasion structure retracts under the influence of gravity and transforms into stable vertical channels. It is shown that the stability of these channels is the result of a balance between hydrostatic and viscous pressure gradients.

  7. Brine delineation and monitoring with electrical resistivity tomography and electromagnetic borehole logging at the Fort Knox well field near West Point, Kentucky

    USGS Publications Warehouse

    Henderson, Rory; Unthank, Michael D.; Zettwoch, Douglas D.; Lane, John W.

    2010-01-01

    The potable water system at Fort Knox is threatened by brine contamination from improperly abandoned natural gas exploration wells. The Fort Knox well field is located near the town of West Point, Kentucky, in the flood plain of the Ohio River. At the site, unconsolidated sediments approximately 30 – 40 m thick, overlie shale and porous limestone. Brine is believed to flow vertically from the underlying formations to the unconsolidated aquifer through damaged or leaky well casings under a high hydraulic gradient from the artificially pressurized porous limestone, which is utilized for natural gas storage by a regional energy company. Upon reaching the unconsolidated aquifer, brinecontaminated groundwater enters water supply production wells under the pumping‐induced gradient. As part of the Fort Knox remediation strategy to reduce the impact of brine contamination, electrical resistivity tomography (ERT) and borehole electromagnetic (EM) logs are being collected annually to detect gross changes in subsurface conductivity. The 2009 ERT data show areas of high conductivity on the western (contaminated) side of the site with conductivities more than an order of magnitude higher than on the eastern (uncontaminated) side of the site. The areas of high conductivity are interpreted as brine contamination, consistent with known regions of brine contamination. Conductivities from the EM logs are consistent with the results from the ERT inversions. The EM logs show little change between 2008 and 2009, except for some small changes in the brine distribution in well PZ1. Yearly ERT surveys will be continued to detect new areas of brine contamination and monitor the remediation effort.

  8. Chemical, Mineralogical, and Physical Properties of Martian Dust and Soil

    NASA Technical Reports Server (NTRS)

    Ming, D. W.; Morris, R. V.

    2017-01-01

    Global and regional dust storms on Mars have been observed from Earth-based telescopes, Mars orbiters, and surface rovers and landers. Dust storms can be global and regional. Dust is material that is suspended into the atmosphere by winds and has a particle size of 1-3 micrometer. Planetary scientist refer to loose unconsolidated materials at the surface as "soil." The term ''soil'' is used here to denote any loose, unconsolidated material that can be distinguished from rocks, bedrock, or strongly cohesive sediments. No implication for the presence or absence of organic materials or living matter is intended. Soil contains local and regional materials mixed with the globally distributed dust by aeolian processes. Loose, unconsolidated surface materials (dust and soil) may pose challenges for human exploration on Mars. Dust will no doubt adhere to spacesuits, vehicles, habitats, and other surface systems. What will be the impacts on human activity? The objective of this paper is to review the chemical, mineralogical, and physical properties of the martian dust and soil.

  9. Relationship between P-wave attenuation and water saturation in an homogeneous unconsolidated and partially saturated porous media : An experimental study

    NASA Astrophysics Data System (ADS)

    Barrière, J.; Sénéchal, P.; Bordes, C.; Perroud, H.

    2010-12-01

    Nowadays, it is well known that hydrogeological properties of the porous media (porosity, fluid saturation and permeability) can influence seismic properties. The major theory which links hydrogeological and seismic parameters is poroelasticity proposed by Biot (1956) for saturated porous media in a wetting phase fluid. However the Biot relaxation process can't explain the level of attenuation of seismic waves generally measured on field from seismic to sonic frequency range in the case of partially saturated media. Laboratory experiments are necessary to better understand the effects of fluids on the attenuation of waves but few ones are done in the low frequency range (1Hz to 10 kHz) where the wavelength is greater than heterogeneities size. We propose an experimental study to determine the attenuation of propagative P-wave in the sonic frequency range on unconsolidated and partially saturated porous media, typical of near surface hydrogeological media. 10 accelerometers (0.0001-17kHz) and 6 capacitance probes (soil moisture sensors) are placed in a container (107 cm x 34 cm x 35cm) full of homogeneous sand (99% silica). An acoustic source (0 - 20 kHz) generate seismic waves which are recorded by the accelerometers during three cycles of imbibition-drainage (corresponding to a water saturation range from 0% to 95%). Values of attenuation (quality factor Q) versus water saturation and frequency are calculated with the well-known spectral ratio method. The spectrum of each recorded P-wave is obtained by a continuous wavelet transform, more adapted than Fourier transform for a non-stationary signal, such as seismic signal, whose frequency content varies with time. The first analyses show a strong dependence of the quality factor with frequency and water saturation, notably at high water saturation (above 60 %) where the attenuation is maximum. Knowing some important parameters of the studied media such as porosity and permeability, we interpret physically our results in accordance with some recent poroelastic models.

  10. Heat transfer model and finite element formulation for simulation of selective laser melting

    NASA Astrophysics Data System (ADS)

    Roy, Souvik; Juha, Mario; Shephard, Mark S.; Maniatty, Antoinette M.

    2017-10-01

    A novel approach and finite element formulation for modeling the melting, consolidation, and re-solidification process that occurs in selective laser melting additive manufacturing is presented. Two state variables are introduced to track the phase (melt/solid) and the degree of consolidation (powder/fully dense). The effect of the consolidation on the absorption of the laser energy into the material as it transforms from a porous powder to a dense melt is considered. A Lagrangian finite element formulation, which solves the governing equations on the unconsolidated reference configuration is derived, which naturally considers the effect of the changing geometry as the powder melts without needing to update the simulation domain. The finite element model is implemented into a general-purpose parallel finite element solver. Results are presented comparing to experimental results in the literature for a single laser track with good agreement. Predictions for a spiral laser pattern are also shown.

  11. Pre-Darcy Flow in Porous Media

    NASA Astrophysics Data System (ADS)

    Dejam, Morteza; Hassanzadeh, Hassan; Chen, Zhangxin

    2017-10-01

    Fluid flow in porous media is very important in a wide range of science and engineering applications. The entire establishment of fluid flow application in porous media is based on the use of an experimental law proposed by Darcy (1856). There are evidences in the literature that the flow of a fluid in consolidated and unconsolidated porous media does not follow Darcy law at very low fluxes, which is called pre-Darcy flow. In this paper, the unsteady flow regimes of a slightly compressible fluid under the linear and radial pre-Darcy flow conditions are modeled and the corresponding highly nonlinear diffusivity equations are solved analytically by aid of a generalized Boltzmann transformation technique. The influence of pre-Darcy flow on the pressure diffusion for homogeneous porous media is studied in terms of the nonlinear exponent and the threshold pressure gradient. In addition, the pressure gradient, flux, and cumulative production per unit area are compared with the classical solution of the diffusivity equation based on Darcy flow. The presented results advance our understanding of fluid flow in low-permeability media such as shale and tight formations, where pre-Darcy is the dominant flow regime.

  12. Planetary and Primitive Object Strength Measurements and Sampling Apparatus

    NASA Technical Reports Server (NTRS)

    Ahrens, Thomas J.

    1997-01-01

    We present experimental data and a model for the low-velocity (subsonic, 0 - 1000 m/s) penetration of brittle materials by both solid and hollow (i.e., coring) penetrators. The experiments show that penetration is proportional to momentum/frontal area of the penetrator. Because of the buildup of a cap in front of blunt penetrators, the presence or absence of a streamlined or sharp front end usually has a negligible effect for impact into targets with strength. The model accurately predicts the dependence of penetration depth on the various parameters of the target-penetrator system, as well as the qualitative condition of the target material ingested by a corer. In particular, penetration depth is approximately inversely proportional to the static bearing strength of the target. The bulk density of the target material has only a small effect on penetration, whereas friction can be significant, especially at higher impact velocities, for consolidated materials. This trend is reversed for impacts into unconsolidated materials. The present results suggest that the depth of penetration is a good measure of the strength, but not the density, of a consolidated target. Both experiments and model results show that, if passage through the mouth of a coring penetrator requires initially porous target material to be compressed to less than 26% porosity, the sample collected by the corer will be highly fragmented. If the final porosity remains above 26%, then most materials, except cohesionless materials, such as dry sand, will be collected as a compressed slug of material.

  13. Characterization of shallow unconsolidated aquifers in West Africa using different hydrogeological data sources as a contribution to the promotion of manual drilling and low cost techniques for groundwater exploration

    NASA Astrophysics Data System (ADS)

    Fussi, Fabio; Fumagalli, Letizia; Bonomi, Tullia; Kane, Cheikh H.; Fava, Francesco; Di Mauro, Biagio; Hamidou, Barry; Niang, Magatte; Wade, Souleye; Colombo, Roberto

    2016-04-01

    Manual drilling refers to several drilling methods that rely on human energy to construct a borehole and complete a water supply (Danert, 2015). It can be an effective strategy to increase access to groundwater in low income countries , but manual drilling can be applied only where shallow geological layers are relatively soft and water table is not too deep. It is important therefore to identify those zones where shallow hydrogeological conditions are suitable, investigating the characteristics of shallow porous aquifers. Existing hydrogeological studies are generally focused in the characterization of deep fractures aquifers, more productive and able to ensure water supply for large settlements. Information concerning shallow porous aquifers are limited. This research has been carried out in two different study areas in West Africa (North-Western Senegal and Eastern Guinea). Aim of the research is the characterization of shallow aquifer using different methods and the identification of hydrogeological condition suitable for manual drilling implementation. Three different methods to estimate geometry and hydraulic properties of shallow unconsolidated aquifers have been used: The first method is based on the analysis of stratigraphic data obtained from borehole logs of the national water point database in both countries. The following steps have been implemented on the original information using the software TANGAFRIC, specifically designed for this study: a) identification of most frequent terms used for hydrogeological description in Senegal and Guinea database; b) definition of standard categories and manual codification of data; c) automatic extraction of average distribution of textural classes at different depth intervals in the unconsolidated aquifer; d) estimation of hydraulic parameters using conversion tables between texture and hydraulic conductivity available in the literature. . The second method is based on the interpretation of pump and recovery test in large diameter wells. K values obtained from these tests provide direct information on hydraulic parameters of shallow porous aquifers (while pump tests data obtained from deep mechanized boreholes, exploiting fractured aquifers, cannot be considered representative for the target shallow aquifer of manual drilling). The third method is based on the interpretation of stratigraphic logs and simplified pump test from manual drilled wells carried out since 2012 in Guinea. In this country a standard and systematic procedure to collect hydrogeological data from these wells (therefore indicating properties of shallow aquifer) has been put in place in 2011; it is considered one of the best example worldwide about technical data collection and systematization from manual drilling activities, but its development has been stopped because of the outbreak of Ebola in this country. The integration of these 3 methods allow to estimate geometry and hydraulic behavior of shallow unconsolidated aquifer, identifying those areas where manual drilling is feasible and estimating potential yield that can be extracted. In the mean time this research provides relevant indications concerning the use of data obtained from low cost open hand dug or manually drilled wells (rarely used in hydrogeological research) for groundwater exploration of shallow aquifers.

  14. Healing in Unconsolidated Granular Earth Materials: a Mechanistic Theory

    NASA Astrophysics Data System (ADS)

    Lieou, C.; Daub, E. G.; Ecke, R. E.; Johnson, P. A.

    2017-12-01

    Abstract: Rock materials often display long-time relaxation, commonly termed aging or ``slow dynamics'', after the cessation of acoustic perturbations. In this presentation, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the Shear-Transformation-Zone (STZ) theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow change of positions of constituent grains, and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the fast nonlinear plasticity carriers, log-linear recovery of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady-state behavior at long times. We demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance.

  15. Wave propagation through elastic porous media containing two immiscible fluids

    NASA Astrophysics Data System (ADS)

    Lo, Wei-Cheng; Sposito, Garrison; Majer, Ernest

    2005-02-01

    Acoustic wave phenomena in porous media containing multiphase fluids have received considerable attention in recent years because of an increasing scientific awareness of poroelastic behavior in groundwater aquifers. To improve quantitative understanding of these phenomena, a general set of coupled partial differential equations was derived to describe dilatational wave propagation through an elastic porous medium permeated by two immiscible fluids. These equations, from which previous models of dilatational wave propagation can be recovered as special cases, incorporate both inertial coupling and viscous drag in an Eulerian frame of reference. Two important poroelasticity concepts, the linearized increment of fluid content and the closure relation for porosity change, originally defined for an elastic porous medium containing a single fluid, also are generalized for a two-fluid system. To examine the impact of relative fluid saturation and wave excitation frequency (50, 100, 150, and 200 Hz) on free dilatational wave behavior in unconsolidated porous media, numerical simulations of the three possible modes of wave motion were conducted for Columbia fine sandy loam containing either an air-water or oil-water mixture. The results showed that the propagating (P1) mode, which results from in-phase motions of the solid framework and the two pore fluids, moves with a speed equal to the square root of the ratio of an effective bulk modulus to an effective density of the fluid-containing porous medium, regardless of fluid saturation and for both fluid mixtures. The nature of the pore fluids exerts a significant influence on the attenuation of the P1 wave. In the air-water system, attenuation was controlled by material density differences and the relative mobilities of the pore fluids, whereas in the oil-water system an effective kinematic shear viscosity of the pore fluids was the controlling parameter. On the other hand, the speed and attenuation of the two diffusive modes (P2, resulting from out-of-phase motions of the solid framework and the fluids, and P3, the result of capillary pressure fluctuations) were closely associated with an effective dynamic shear viscosity of the pore fluids. The P2 and P3 waves also had the same constant value of the quality factor, and by comparison of our results with previous research on these two dilatational wave modes in sandstones, both were found to be sensitive to the state of consolidation of the porous medium.

  16. Three-phase fracturing in granular material

    NASA Astrophysics Data System (ADS)

    Campbell, James; Sandnes, Bjornar

    2015-04-01

    There exist numerous geo-engineering scenarios involving the invasion of a gas into a water-saturated porous medium: in fracking, this may occur during the fracking process itself or during subsequent gas penetration into propant beds; the process is also at the heart of carbon dioxide sequestration. We use a bed of water-saturated glass beads confined within a Hele-Shaw cell as a model system to illuminate these processes. Depending on packing density, injection rate and other factors, air injected into this system may invade in a broad variety of patterns, including viscous fingering, capillary invasion, bubble formation and fracturing. Here we focus primarily on the latter case. Fracturing is observed when air is injected into a loosely packed bed of unconsolidated granular material. Our approach allows us to image the complete fracture pattern as it forms, and as such to study both the topographical properties of the resulting pattern (fracture density, braching frequency etc) and the dynamics of its growth. We present an overview of the fracturing phenomenon within the context of pattern formation in granular fluids as a whole. We discuss how fracturing arises from an interplay between frictional, capillary and viscous forces, and demonstrate the influence of various parameters on the result.

  17. Investigation of Single Phase NanoCellulose Transport through Porous Media

    NASA Astrophysics Data System (ADS)

    Dziuba, Carter Jordan

    The application of nanotechnology to the petroleum industry has seen many recent advancements. Nanocellulose is an emerging nanoparticle at the forefront of research. Before nanocellulose can be injected into petroleum reservoirs, further understanding is needed as to the retention mechanisms that occur during nanocellulose transport through porous media. A series of unconsolidated sandpack floods were preformed with nanocellulose and the resulting retention and permeability reduction were measured. The experimental variables include nanocellulose type, sand grain size, flowrate, and salinity. It was found that all types of nanocellulose tested showed significantly different transport properties. Retention and permeability reduction increased as grain size decreased or flowrate decreased. As a general trend, the larger the size of aggregates in bulk solution, the greater the retention and permeability reduction. Salinity was found to be the primary parameter affecting transport. Increased salinity caused additional aggregation which resulted in increased straining and filter cake formation.

  18. Research of Radionuclides Migrating in Porous Media Allowing for the "Solution-Rock" Interaction

    NASA Astrophysics Data System (ADS)

    Drozhko, E.; Aleksakhin, A. I.; Samsanova, L.; Kotchergina, N.; Zinin, A.

    2001-12-01

    Industrial solutions from the surface storage of liquid radioactive waste in Lake Karachay, near the Mayak Production Association in Russia, enter groundwaters through the reservoir loamy bed and have formed a contaminated groundwater plume. In order to predict radionuclide migration with the groundwater flow in porous unconsolidated rocks and to assess the protective mechanism of the natural environment, it is necessary to allow for the "solution-rock" physical and chemical interaction described by the distribution factor (Kd). In order to study radionuclide distribution in porous media, a numerical model was developed which models stontium-90 migration in a uniform unit of loams typical for the Karachay Lake bed. For the migration to be calculated, the results of the in situ and laboratory reasearch on strontium-90 sorption and desorption were used in the code, as well as strontium-90 dependance on sodium nitrate concentration in the solution. The code uses various models of the "solution-rock" interaction, taking into account both sorption/desorption and diffusion processes. Numerical research of strontium-90 migration resulted in data on strontium-90 distribution in solid and liquid phases of the porous loam unit over different time periods. Various models of the "solution-rock" interaction affecting strontium-90 migration are demonstrated.

  19. Surface properties of the Mars Science Laboratory candidate landing sites: characterization from orbit and predictions

    USGS Publications Warehouse

    Fergason, R.L.; Christensen, P.R.; Golombek, M.P.; Parker, T.J.

    2012-01-01

    This work describes the interpretation of THEMIS-derived thermal inertia data at the Eberswalde, Gale, Holden, and Mawrth Vallis Mars Science Laboratory (MSL) candidate landing sites and determines how thermophysical variations correspond to morphology and, when apparent, mineralogical diversity. At Eberswalde, the proportion of likely unconsolidated material relative to exposed bedrock or highly indurated surfaces controls the thermal inertia of a given region. At Gale, the majority of the landing site region has a moderate thermal inertia (250 to 410 J m-2 K-1 s-1/2), which is likely an indurated surface mixed with unconsolidated materials. The primary difference between higher and moderate thermal inertia surfaces may be due to the amount of mantling material present. Within the mound of stratified material in Gale, layers are distinguished in the thermal inertia data; the MSL rover could be traversing through materials that are both thermophysically and compositionally diverse. The majority of the Holden ellipse has a thermal inertia of 340 to 475 J m-2 K-1 s-1/2 and consists of bed forms with some consolidated material intermixed. Mawrth Vallis has a mean thermal inertia of 310 J m-2 K-1 s-1/2 and a wide variety of materials is present contributing to the moderate thermal inertia surfaces, including a mixture of bedrock, indurated surfaces, bed forms, and unconsolidated fines. Phyllosilicates have been identified at all four candidate landing sites, and these clay-bearing units typically have a similar thermal inertia value (400 to 500 J m-2 K-1 s-1/2), suggesting physical properties that are also similar.

  20. Nonlinear softening of unconsolidated granular earth materials

    NASA Astrophysics Data System (ADS)

    Lieou, Charles K. C.; Daub, Eric G.; Guyer, Robert A.; Johnson, Paul A.

    2017-09-01

    Unconsolidated granular earth materials exhibit softening behavior due to external perturbations such as seismic waves, namely, the wave speed and elastic modulus decrease upon increasing the strain amplitude above dynamics strains of about 10-6 under near-surface conditions. In this letter, we describe a theoretical model for such behavior. The model is based on the idea that shear transformation zones—clusters of grains that are loose and susceptible to contact changes, particle displacement, and rearrangement—are responsible for plastic deformation and softening of the material. We apply the theory to experiments on simulated fault gouge composed of glass beads and demonstrate that the theory predicts nonlinear resonance shifts, reduction of the P wave modulus, and attenuation, in agreement with experiments. The theory thus offers insights on the nature of nonlinear elastic properties of a granular medium and potentially into phenomena such as triggering on earthquake faults.

  1. Hydrogeology of the Seldovia area, Alaska

    USGS Publications Warehouse

    Nelson, Gordon L.; Danskin, Wesley R.

    1980-01-01

    Surficial materials in the Seldovia area, Alaska, are mapped as glacial drift over sedimentary bedrock, glacial drift over igneous and metamorphic bedrock, valley-bottom, alluvium, alluvial fan deposits, beach and intertidal deposits, and peat. Unconsolidated materials are generally less than 10 feet thick except in well-drained glacial deposits along the Seldovia-Jakolof Bay Road and in depressions in the bedrock surface. These depressions are poorly drained and commonly contain peat bogs. Development of domestic wells (1-15 gallons per minute) may be possible from unconsolidated materials and sedimentary bedrock, but larger water requirements must be met from surface-water sources. In areas having the water table or top of bedrock at shallow depths, effluent from sewage disposal systems may cause pollution of the land surface and nearby surface water. Seepage from hillside aquifers and unstable land along the coast of Kachemak Bay may adversely affect roads and structures. (USGS)

  2. Initial assessment of the infiltration and overland flow for different rainfall events in land constituted of sandstones of the Botucatu Formation (Guarani Aquifer), State of São Paulo, Brazil

    NASA Astrophysics Data System (ADS)

    Zuquette, Lázaro Valentin; Palma, Janaina Barrios; Pejon, Osni José

    2006-06-01

    This study was carried out in the Córrego do Vaçununga basin constituted of eolic sandstones of Botucatu Formation and residual unconsolidated materials (>90%), considered the most important unconfined aquifer in Brazil, in the city of Luiz Antonio, State of São Paulo, Brazil. Laboratory and in situ tests were performed to characterize the unconsolidated materials in terms of basic physical properties, potential infiltration rate, suction and hydraulic conductivity. The results for infiltration and overland flow depths were obtained according to Morel-Seytoux and Khanji (Water Resour Res 10(4):795-800, 1976) and Chu (Water Resour Res 14(3):461-466, 1978) adaptation of the Green and Ampt [J Agr Sci 4(Part 1):1-24, 1911] model for steady and transient rainfalls, respectively. Rainfall data were collected from January of 2000 to December of 2002, and 12 scenarios were defined considering the intensity and durations. Rather than high homogeneity in terms of the texture of unconsolidated materials, the infiltration and overland flow ratio depends on the type of land use and associated management practices. The results showed that rainfall with high intensity and short duration do not produce high overland flow ratio as we have observed for transient scenarios with long duration and low intensities.

  3. Slow dynamics and strength recovery in unconsolidated granular earth materials: a mechanistic theory

    DOE PAGES

    Lieou, Charles Ka Cheong; Daub, Eric G.; Ecke, Robert E.; ...

    2017-09-08

    Rock materials often display long-time relaxation, commonly termed aging or “slow dynamics”, after the cessation of acoustic perturbations. In this paper, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the Shear-Transformation-Zone (STZ) theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow, irreversible change of positions of constituent grains, and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the subset of local plastic events or grain rearrangements with a short time scale, log-linear recoverymore » of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady-state behavior at long times. Here we demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance. These results may provide insights into observed modulus recovery after strong shaking in the near surface region of earthquake zones.« less

  4. Slow Dynamics and Strength Recovery in Unconsolidated Granular Earth Materials: A Mechanistic Theory

    NASA Astrophysics Data System (ADS)

    Lieou, Charles K. C.; Daub, Eric G.; Ecke, Robert E.; Johnson, Paul A.

    2017-10-01

    Rock materials often display long-time relaxation, commonly termed aging or "slow dynamics," after the cessation of acoustic perturbations. In this paper, we focus on unconsolidated rock materials and propose to explain such nonlinear relaxation through the shear-transformation-zone theory of granular media, adapted for small stresses and strains. The theory attributes the observed relaxation to the slow, irreversible change of positions of constituent grains and posits that the aging process can be described in three stages: fast recovery before some characteristic time associated with the subset of local plastic events or grain rearrangements with a short time scale, log linear recovery of the elastic modulus at intermediate times, and gradual turnover to equilibrium steady state behavior at long times. We demonstrate good agreement with experiments on aging in granular materials such as simulated fault gouge after an external disturbance. These results may provide insights into observed modulus recovery after strong shaking in the near surface region of earthquake zones.

  5. Estimation of Length-Scales in Soils by MRI

    NASA Technical Reports Server (NTRS)

    Daidzic, N. E.; Altobelli, S.; Alexander, J. I. D.

    2004-01-01

    Soil can be best described as an unconsolidated granular media that forms porous structure. The present macroscopic theory of water transport in porous media rests upon the continuum hypothesis that the physical properties of porous media can be associated with continuous, twice-differentiable field variables whose spatial domain is a set of centroids of Representative Elementary Volume (REV) elements. MRI is an ideal technique to estimate various length-scales in porous media. A 0.267 T permanent magnet at NASA GRC was used for this study. A 2D or 3D spatially-resolved porosity distribution were obtained from the NMR signal strength from each voxel and the spin-lattice relaxation time. A classical spin-warp imaging with Multiple Spin Echos (MSE) was used to evaluate proton density in each voxel. Initial resolution of 256 x 256 was subsequently reduced by averaging neighboring voxels and the porosity convergence was observed. A number of engineered "space candidate" soils such as Isolite(trademark), Zeoponics(trademark), Turface(trademark), and Profile(trademark) were used. Glass beads in the size range between 50 microns to 2 mm were used as well. Initial results with saturated porous samples have shown a good estimate of the average porosity consistent with the gravimetric porosity measurement results. For Profile(trademark) samples with particle sizes ranging between 0.25 to 1 mm and characteristic interparticle pore size of 100 microns the characteristic Darcy scale was estimated to be about delta(sub REV) = 10 mm. Glass beads porosity show clear convergence toward a definite REV which stays constant throughout homogeneous sample. Additional information is included in the original extended abstract.

  6. Experimental study of nonlinear ultrasonic behavior of soil materials during the compaction.

    PubMed

    Chen, Jun; Wang, Hao; Yao, Yangping

    2016-07-01

    In this paper, the nonlinear ultrasonic behavior of unconsolidated granular medium - soil during the compaction is experimentally studied. The second harmonic generation technique is adopted to investigate the change of microstructural void in materials during the compaction process of loose soils. The nonlinear parameter is measured with the change of two important environmental factors i.e. moisture content and impact energy of compaction. It is found the nonlinear parameter of soil material presents a similar variation pattern with the void ratio of soil samples, corresponding to the increased moisture content and impact energy. A same optimum moisture content is found by observing the variation of nonlinear parameter and void ratio with respect to moisture content. The results indicate that the unconsolidated soil is manipulated by a strong material nonlinearity during the compaction procedure. The developed experimental technique based on the second harmonic generation could be a fast and convenient testing method for the determination of optimum moisture content of soil materials, which is very useful for the better compaction effect of filled embankment for civil infrastructures in-situ. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Preparation of Unconsolidated Sands for Microscopy Laboratory Exercises.

    ERIC Educational Resources Information Center

    Cameron, Barry; Jones, J. Richard

    1988-01-01

    Describes a technique of impregnating small amounts of sandy sediment in a quick curing resin for microscopic examination. Details the preparation of materials. Suggests laboratory exercises based on this preparation. (CW)

  8. Comparing geophysical measurements to theoretical estimates for soil mixtures at low pressures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wildenschild, D; Berge, P A; Berryman, K G

    1999-01-15

    The authors obtained good estimates of measured velocities of sand-peat samples at low pressures by using a theoretical method, the self-consistent theory of Berryman (1980), using sand and porous peat to represent the microstructure of the mixture. They were unable to obtain useful estimates with several other theoretical approaches, because the properties of the quartz, air and peat components of the samples vary over several orders of magnitude. Methods that are useful for consolidated rock cannot be applied directly to unconsolidated materials. Instead, careful consideration of microstructure is necessary to adapt the methods successfully. Future work includes comparison of themore » measured velocity values to additional theoretical estimates, investigation of Vp/Vs ratios and wave amplitudes, as well as modeling of dry and saturated sand-clay mixtures (e.g., Bonner et al., 1997, 1998). The results suggest that field data can be interpreted by comparing laboratory measurements of soil velocities to theoretical estimates of velocities in order to establish a systematic method for predicting velocities for a full range of sand-organic material mixtures at various pressures. Once the theoretical relationship is obtained, it can be used to estimate the soil composition at various depths from field measurements of seismic velocities. Additional refining of the method for relating velocities to soil characteristics is useful for development inversion algorithms.« less

  9. Environmental Assessment: Implementation of the Tyndall Air Force Base Integrated Natural Resources Management Plan

    DTIC Science & Technology

    2006-04-01

    3-21 TPA060050033/TYNDALLINRMPEAFINAL.DOC VI Acronyms and Abbreviations ACM asbestos-containing materials ...Inventory FONPA Finding of No Practicable Alternative FONSI Finding of No Significant Impact HAZMO Hazardous Materials Management Office ICRMP...land surface (bls) by unconsolidated sands and clayey sands deposited since the Pliocene age. This material is relatively permeable and is underlain

  10. Inverted channel deposits on the floor of Miyamoto crater, Mars

    USGS Publications Warehouse

    Newsom, Horton E.; Lanza, N.L.; Ollila, A.M.; Wiseman, S.M.; Roush, T.L.; Marzo, G.A.; Tornabene, L.L.; Okubo, C.H.; Osterloo, M.M.; Hamilton, V.E.; Crumpler, L.S.

    2010-01-01

    Morphological features on the western floor of Miyamoto crater in southwestern Meridiani Planum, Mars, are suggestive of past fluvial activity. Imagery from the High Resolution Imaging Science Experiment (HiRISE) gives a detailed view of raised curvilinear features that appear to represent inverted paleochannel deposits. The inverted terrain appears to be capped with a resistant, dark-toned deposit that is partially covered by unconsolidated surficial materials. Subsequent to deposition of the capping layer, erosion of the surrounding material has left the capping materials perched on pedestals of uneroded basal unit material. Neither the capping material nor the surrounding terrains show any unambiguous morphological evidence of volcanism or glaciation. The capping deposit may include unconsolidated or cemented stream deposits analogous to terrestrial inverted channels in the Cedar Mountain Formation near Green River, Utah. In addition to this morphological evidence for fluvial activity, phyllosilicates have been identified in the basal material on the floor of Miyamoto crater by orbital spectroscopy, providing mineralogical evidence of past aqueous activity. Based on both the morphological and mineralogical evidence, Miyamoto crater represents an excellent site for in situ examination and sampling of a potentially habitable environment. ?? 2009 Elsevier Inc.

  11. Microwave impregnation of porous materials with thermal energy storage materials

    DOEpatents

    Benson, David K.; Burrows, Richard W.

    1993-01-01

    A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

  12. Microwave impregnation of porous materials with thermal energy storage materials

    DOEpatents

    Benson, D.K.; Burrows, R.W.

    1993-04-13

    A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

  13. 30 CFR 56.3131 - Pit or quarry wall perimeter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Ground Control... performing their assigned tasks, loose or unconsolidated material shall be sloped to the angle of repose or...

  14. 30 CFR 56.3131 - Pit or quarry wall perimeter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Ground Control... performing their assigned tasks, loose or unconsolidated material shall be sloped to the angle of repose or...

  15. 30 CFR 57.16002 - Bins, hoppers, silos, tanks, and surge piles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Bins, hoppers, silos, tanks, and surge piles... NONMETAL MINES Materials Storage and Handling § 57.16002 Bins, hoppers, silos, tanks, and surge piles. (a) Bins, hoppers, silos, tanks, and surge piles, where loose unconsolidated materials are stored, handled...

  16. 30 CFR 56.16002 - Bins, hoppers, silos, tanks, and surge piles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Bins, hoppers, silos, tanks, and surge piles... MINES Materials Storage and Handling § 56.16002 Bins, hoppers, silos, tanks, and surge piles. (a) Bins, hoppers, silos, tanks, and surge piles, where loose unconsolidated materials are stored, handled or...

  17. Preparation of asymmetric porous materials

    DOEpatents

    Coker, Eric N [Albuquerque, NM

    2012-08-07

    A method for preparing an asymmetric porous material by depositing a porous material film on a flexible substrate, and applying an anisotropic stress to the porous media on the flexible substrate, where the anisotropic stress results from a stress such as an applied mechanical force, a thermal gradient, and an applied voltage, to form an asymmetric porous material.

  18. Variably porous structures

    DOEpatents

    Braun, Paul V [Savoy, IL; Yu, Xindi [Urbana, IL

    2011-01-18

    A method of making a monolithic porous structure, comprises electrodepositing a material on a template; removing the template from the material to form a monolithic porous structure comprising the material; and electropolishing the monolithic porous structure.

  19. Evaluation of Cone Penetrometer Testing (CPT) for Use with Transportation Projects Phase 1

    DOT National Transportation Integrated Search

    2008-07-01

    The ODOT Office of Geotechnical Engineering (OGE) currently uses conventional drilling methods (e.g., hollow stem auger, solid stem auger) to perform subsurface investigations in unconsolidated materials. These techniques have been used for decades a...

  20. Catalyst containing oxygen transport membrane

    DOEpatents

    Lane, Jonathan A.; Wilson, Jamie R.; Christie, Gervase Maxwell; Petigny, Nathalie; Sarantopoulos, Christos

    2017-02-07

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  1. Applications of hierarchically structured porous materials from energy storage and conversion, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine.

    PubMed

    Sun, Ming-Hui; Huang, Shao-Zhuan; Chen, Li-Hua; Li, Yu; Yang, Xiao-Yu; Yuan, Zhong-Yong; Su, Bao-Lian

    2016-06-13

    Over the last decade, significant effort has been devoted to the applications of hierarchically structured porous materials owing to their outstanding properties such as high surface area, excellent accessibility to active sites, and enhanced mass transport and diffusion. The hierarchy of porosity, structural, morphological and component levels in these materials is key for their high performance in all kinds of applications. The introduction of hierarchical porosity into materials has led to a significant improvement in the performance of materials. Herein, recent progress in the applications of hierarchically structured porous materials from energy conversion and storage, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine is reviewed. Their potential future applications are also highlighted. We particularly dwell on the relationship between hierarchically porous structures and properties, with examples of each type of hierarchically structured porous material according to its chemical composition and physical characteristics. The present review aims to open up a new avenue to guide the readers to quickly obtain in-depth knowledge of applications of hierarchically porous materials and to have a good idea about selecting and designing suitable hierarchically porous materials for a specific application. In addition to focusing on the applications of hierarchically porous materials, this comprehensive review could stimulate researchers to synthesize new advanced hierarchically porous solids.

  2. Fluid mechanical scaling of impact craters in unconsolidated granular materials

    NASA Astrophysics Data System (ADS)

    Miranda, Colin S.; Dowling, David R.

    2015-11-01

    A single scaling law is proposed for the diameter of simple low- and high-speed impact craters in unconsolidated granular materials where spall is not apparent. The scaling law is based on the assumption that gravity- and shock-wave effects set crater size, and is formulated in terms of a dimensionless crater diameter, and an empirical combination of Froude and Mach numbers. The scaling law involves the kinetic energy and speed of the impactor, the acceleration of gravity, and the density and speed of sound in the target material. The size of the impactor enters the formulation but divides out of the final empirical result. The scaling law achieves a 98% correlation with available measurements from drop tests, ballistic tests, missile impacts, and centrifugally-enhanced gravity impacts for a variety of target materials (sand, alluvium, granulated sugar, and expanded perlite). The available measurements cover more than 10 orders of magnitude in impact energy. For subsonic and supersonic impacts, the crater diameter is found to scale with the 1/4- and 1/6-power, respectively, of the impactor kinetic energy with the exponent crossover occurring near a Mach number of unity. The final empirical formula provides insight into how impact energy partitioning depends on Mach number.

  3. Freeze-drying of “pearl milk tea”: A general strategy for controllable synthesis of porous materials

    PubMed Central

    Zhou, Yingke; Tian, Xiaohui; Wang, Pengcheng; Hu, Min; Du, Guodong

    2016-01-01

    Porous materials have been widely used in many fields, but the large-scale synthesis of materials with controlled pore sizes, pore volumes, and wall thicknesses remains a considerable challenge. Thus, the controllable synthesis of porous materials is of key general importance. Herein, we demonstrate the “pearl milk tea” freeze-drying method to form porous materials with controllable pore characteristics, which is realized by rapidly freezing the uniformly distributed template-containing precursor solution, followed by freeze-drying and suitable calcination. This general and convenient method has been successfully applied to synthesize various porous phosphate and oxide materials using different templates. The method is promising for the development of tunable porous materials for numerous applications of energy, environment, and catalysis, etc. PMID:27193866

  4. Porous graphene nanocages for battery applications

    DOEpatents

    Amine, Khalil; Lu, Jun; Du, Peng; Wen, Jianguo; Curtiss, Larry A.

    2017-03-07

    An active material composition includes a porous graphene nanocage and a source material. The source material may be a sulfur material. The source material may be an anodic material. A lithium-sulfur battery is provided that includes a cathode, an anode, a lithium salt, and an electrolyte, where the cathode of the lithium-sulfur battery includes a porous graphene nanocage and a sulfur material and at least a portion of the sulfur material is entrapped within the porous graphene nanocage. Also provided is a lithium-air battery that includes a cathode, an anode, a lithium salt, and an electrolyte, where the cathode includes a porous graphene nanocage and where the cathode may be free of a cathodic metal catalyst.

  5. Map showing depth to bedrock of the Tacoma and part of the Centralia 30' x 60' quadrangles, Washington

    USGS Publications Warehouse

    Buchanan-Banks, Jane M.; Collins, Donley S.

    1994-01-01

    The heavily populated Puget Sound region in the State of Washington has experienced moderate to large earthquakes in the recent past (Nuttli, 1952; Mullineaux and others, 1967). Maps showing thickness of unconsolidated sedimentary deposits are useful aids in delineating areas where damage to engineered structures can result from increased shaking resulting from these earthquakes. Basins containing thick deposits of unconsolidated materials can amplify earthquakes waves and cause far more damage to structures than the same waves passing through bedrock (Singh and others, 1988; Algermissen and others, 1985). Configurations of deep sedimentary basins can also cause reflection and magnification of earthquake waves in ways still not fully understood and presently under investigation (Frankel and Vidale, 1992).

  6. Thickness of unconsolidated deposits of the Puget Sound aquifer system, Washington and British Columbia

    USGS Publications Warehouse

    Jones, M.A.

    1996-01-01

    The Puget-Willamette Lowland is located in western Washington, western Oregon, and a small part of southwestern British Columbia, Canada. The Puget-Willamette Lowland study area is composed of two distinct subareas, the Puget Sound Lowland and the Willamette Lowland. This report presents the results of mapping the thickness of the unconsolidated deposits in the Puget Sound Lowland. The thickness of the unconsolidated deposits ranges from a discontinuous veneer in areas of bedrock outcrop to more than 3,600 feet. Available information shows that the unconsolidated deposits are thickest in the Fraser-Whatcom, Everett, Seattle, and Tacoma Basins. The mapped thickness of the unconsolidated deposits in the Tacoma Basin is probably underestimated because of the scarcity of wells penetrating the full thickness of the unconsolidated deposits and the lack of sufficient marine-seismic data.

  7. Using the Earth as a guide to martian mass movement processes: From form to process

    NASA Astrophysics Data System (ADS)

    Lanza, N.; Newsom, H. E.; Osterloo, M. M.; Okubo, C. H.

    2011-12-01

    The discovery of gully features on Mars has led to renewed interest in hillslope processes on that planet, in particular mass movement and the morphologies that it produces. Mass movement is a collection of gravity-driven processes that act to move materials down a hillslope. Here, we examine how mass movements on hillslopes may be expected to differ on Earth and Mars as the result of gravity differences between these planets. Downslope movement of unconsolidated materials is generally controlled by the bulk shear strength of these materials. Although the relationship between gravity and shear strength is largely dependent on variables that are independent of gravity, the lower gravity on Mars is expected to produce some systematic changes in mass movement behaviors that may in turn create morphological features that are observably different from their terrestrial counterparts. After scaling for gravity and modifying empirically derived relationships, we may expect the following differences on martian hillslopes when compared to their terrestrial counterparts: ==On Mars, hillslopes may have steeper angles of repose in fine grained (< ~2 mm) materials, even when dry. No change in angle of repose is expected for larger particles; ==An increase in soil moisture content (e.g., excess pore pressure) is expected to weaken unconsolidated slope materials more on Mars for a particular regolith type, which in turn may produce --An increase in creep rates for a given pore pressure, and --An increase in effectiveness of frost heave to transport materials downslope; ==Processes triggered by saturation may occur at lower pore pressures on Mars; --A smaller amount of fluid is needed to achieve failure; ==Shorter runout lengths are expected for rapid mass movements; ==On Mars, overland flow will exert a proportionally lower shear stress on slope materials; --In cohesive materials, the same volume of water will detach sediments of smaller sizes. On Earth, mass movement processes may be directly observed and measured as they occur, whereas on Mars only the resultant landforms may be studied at present. By understanding how martian hillslope processes are expected to be modified by lower gravity, the interpretation of martian landforms may be greatly aided. Examples of observations that support some of these predicted differences will be presented, with a focus on saturation-triggered events in unconsolidated materials.

  8. Head-on collision of normal shock waves with rigid porous materials

    NASA Astrophysics Data System (ADS)

    Levy, A.; Ben-Dor, G.; Skews, B. W.; Sorek, S.

    1993-08-01

    The head-on collision of a planar shock wave with a rigid porous material has been investigated experimentally in a 75 mm × 75 mm shock tube. The experimental study indicated that unlike the reflection from a flexible porous material (e.g., polyurethane foam) where the transmitted compression waves do not converge to a sharp shock wave, in the case of a rigid porous material (e.g., alumina) the transmitted compression waves do converge to a sharp shock wave, which decays as it propagates along the porous material. In addition to this major difference, many other differences were observed. They are outlined in the following sections. Based on these observations a suggestion modifying the phenomenology of the reflection/interaction process in the case a porous material with large permeability is proposed.

  9. Nanostructured materials for hydrogen storage

    DOEpatents

    Williamson, Andrew J.; Reboredo, Fernando A.

    2007-12-04

    A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

  10. Consensus on a new definition for soil?

    USDA-ARS?s Scientific Manuscript database

    Unconsolidated material does not become soil without biological input. Until it is proven that life forms exist on extraterrestrial planets and moons, these should not be considered "soils" in context of soil formation, which includes the organism factor. There is already a perfectly good term for w...

  11. 78 FR 45871 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-30

    ... components: Hydrogeologic study; Surface water sampling study; Stream biological study; Air quality survey... components: Biological survey; Biota survey; Surface water and sediment characterization; Groundwater... impacted groundwater in three water bearing zones at the Site; the unconsolidated materials zone, the upper...

  12. Soils, peatlands, and biomonitoring

    Treesearch

    James Doolittle

    2009-01-01

    Soils are three-dimensional (3D) natural bodies conSlStmg of unconsolidated mineral and organic materials that form a continuous blanket over most of the earth's land sUlface. At all sca les of measurements, soils are exceedingly complex and variable in biological, chemical, physical, mineralogical, and electromagnetic properties....

  13. Porous ionic liquids: synthesis and application.

    PubMed

    Zhang, Shiguo; Dokko, Kaoru; Watanabe, Masayoshi

    2015-07-15

    Solidification of fluidic ionic liquids into porous materials yields porous ionic networks that combine the unique characteristics of ionic liquids with the common features of polymers and porous materials. This minireview reports the most recent advances in the design of porous ionic liquids. A summary of the synthesis of ordered and disordered porous ionic liquid-based nanoparticles or membranes with or without templates is provided, together with the new concept of room temperature porous ionic liquids. As a versatile platform for functional materials, porous ionic liquids have shown widespread applications in catalysis, adsorption, sensing, actuation, etc. This new research direction towards ionic liquids chemistry is still in its early stages but has great potential.

  14. Assessment of porous material anisotropy and its effect on gas permeability

    NASA Astrophysics Data System (ADS)

    Wałowski, Grzegorz

    2017-10-01

    The results of experimental research upon the assessment of porous material anisotropy and its effect on gas permeability of porous materials with respect to the gas flow. The conducted research applied to natural materials with an anisotropic gap-porous structure and - for comparative purposes - to model materials such as coke, pumice and polyamide agglomerates. The research was conducted with the use of a special test stand that enables measuring the gas permeability with respect to three flow orientations compared with symmetric cubic-shaped samples. The research results show an explicit impact of the flow direction on the permeability of materials porous, which results from their anisotropic internal structures. The anisotropy coefficient and permeability effective coefficient of such materials was determined and an experimental evaluation of the value of this coefficient was conducted with respect to the gas stream and the total pressure drop across the porous deposit. The process of gas permeability was considered in the category of hydrodynamics of gas flow through porous deposits. It is important to broaden the knowledge of gas hydrodynamics assessment in porous media so far unrecognised for the development of a new generation of clean energy sources, especially in the context of biogas or raw gas production.

  15. Macroscopically Oriented Porous Materials with Periodic Ordered Structures: From Zeolites and Metal-Organic Frameworks to Liquid-Crystal-Templated Mesoporous Materials.

    PubMed

    Cho, Joonil; Ishida, Yasuhiro

    2017-07-01

    Porous materials with molecular-sized periodic structures, as exemplified by zeolites, metal-organic frameworks, or mesoporous silica, have attracted increasing attention due to their range of applications in storage, sensing, separation, and transformation of small molecules. Although the components of such porous materials have a tendency to pack in unidirectionally oriented periodic structures, such ideal types of packing cannot continue indefinitely, generally ceasing when they reach a micrometer scale. Consequently, most porous materials are composed of multiple randomly oriented domains, and overall behave as isotropic materials from a macroscopic viewpoint. However, if their channels could be unidirectionally oriented over a macroscopic scale, the resultant porous materials might serve as powerful tools for manipulating molecules. Guest molecules captured in macroscopically oriented channels would have their positions and directions well-defined, so that molecular events in the channels would proceed in a highly controlled manner. To realize such an ideal situation, numerous efforts have been made to develop various porous materials with macroscopically oriented channels. An overview of recent studies on the synthesis, properties, and applications of macroscopically oriented porous materials is presented. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Effect of porous material heating on the drag force of a cylinder with gas-permeable porous inserts in a supersonic flow

    NASA Astrophysics Data System (ADS)

    Mironov, S. G.; Poplavskaya, T. V.; Kirilovskiy, S. V.

    2017-10-01

    The paper presents the results of an experimental investigation of supersonic flow around a solid cylinder with a gas-permeable porous insert on its front end and of supersonic flow around a hollow cylinder with internal porous inserts in the presence of heating of the porous material. The experiments were performed in a supersonic wind tunnel with Mach number 4.85 and 7 with porous inserts of cellular-porous nickel. The results of measurements on the filtration stand of the air filtration rate through the cellular-porous nickel when it is heated are also shown. For a number of experiments, numerical modeling based on the skeletal model of a cellular-porous material was carried out.

  17. Groundwater/surface-water interactions in the Tunk, Bonaparte, Antoine, and Tonasket Creek Subbasins, Okanogan River Basin, North-Central Washington, 2008

    USGS Publications Warehouse

    Sumioka, S.S.; Dinicola, R.S.

    2009-01-01

    An investigation into groundwater/surface-water interactions in four tributary subbasins of the Okanogan River determined that streamflows and shallow groundwater levels beneath the streams varied seasonally and by location. Streamflows measured in June 2008 indicated net losses of streamflow along 10 of 17 reaches, and hydraulic gradients measured between streams and shallow groundwater indicated potential recharge of surface water to groundwater at 11 of 21 measurement sites. In September 2008, net losses of streamflow were indicated along 9 of 17 reaches, and potential recharge of surface water to groundwater was indicated at 18 of 21 measurement sites. The greatest losses of streamflow occurred near the confluences with the Okanogan River, likely due to the presence of thick layers of unconsolidated deposits in the flood plain of the Okanogan River. Based on available geologic information compiled from drillers' logs, a surficial geologic map, and streamflow records, the extensive and thick deposits of unconsolidated material in the Tunk and Bonaparte Creek subbasins are factors in sustaining the almost perennial streamflow in those creeks. The less extensive and generally thinner unconsolidated deposits in the Tonasket and Antoine subbasins are contributing factors to the occasional extended periods of zero flow (a dry stream channel) in those creeks. Even though groundwater withdrawals would affect streamflows, relatively low precipitation in the area, along with limited groundwater storage capacity and the presence of permeable, unconsolidated deposits underlying the stream channels, would likely lead to loss of surface water to the groundwater system without any withdrawals.

  18. Fabricating porous materials using interpenetrating inorganic-organic composite gels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Seo, Dong-Kyun; Volosin, Alex

    Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite materialmore » can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.« less

  19. Thermal properties variations in unconsolidated material for very shallow geothermal application (ITER project)

    NASA Astrophysics Data System (ADS)

    Sipio, Eloisa Di; Bertermann, David

    2018-04-01

    In engineering, agricultural and meteorological project design, sediment thermal properties are highly important parameters, and thermal conductivity plays a fundamental role when dimensioning ground heat exchangers, especially in very shallow geothermal systems. Herein, the first 2 m of depth from surface is of critical importance. However, the heat transfer determination in unconsolidated material is difficult to estimate, as it depends on several factors, including particle size, bulk density, water content, mineralogy composition and ground temperature. The performance of a very shallow geothermal system, as a horizontal collector or heat basket, is strongly correlated to the type of sediment at disposal and rapidly decreases in the case of dry-unsaturated conditions. The available experimental data are often scattered, incomplete and do not fully support thermo-active ground structure modeling. The ITER project, funded by the European Union, contributes to a better knowledge of the relationship between thermal conductivity and water content, required for understanding the very shallow geothermal systems behaviour in saturated and unsaturated conditions. So as to enhance the performance of horizontal geothermal heat exchangers, thermally enhanced backfilling material were tested in the laboratory, and an overview of physical-thermal properties variations under several moisture and load conditions for different mixtures of natural material was here presented.

  20. First-order shallow aquifer characteristics across Europe: The International Hydrogeological Map of Europe at scale 1:1.5 Million (IHME1500)

    NASA Astrophysics Data System (ADS)

    Günther, Andreas; Duscher, Klaus; Broda, Stefan; Clos, Patrick; Reichling, Jörg

    2017-04-01

    Since the mid of the last century, pan-European hydrogeological overview-mapping is conducted at the scale 1 : 1.5 Million following common standards and guidelines to interpret suitable geologic mapping units in terms of potential uppermost aquifer (or non-aquifer) characteristics. These comprises potential aquifer productivities and general hydrogeological aquifer conditions (fissured vs. porous). The printed IHME1500 dataset successively elaborated and published from 1970 - 2013 consists of 25 individual map sheets. Besides the potential aquifer characterization grouped in six classes, IHME1500 offers a complete coverage of lithological material properties of potential shallow aquifer assemblages, and tracelines of major fault structures. Regional information on groundwater surfaces, aquifer thicknesses and depths, locations and characteristics of groundwater springs and other punctual information related to European groundwater resources is present for some areas in selected map sheets, however not digitally available. Synoptic IHME1500 vector data consists of a topographically corrected, seamless and harmonized polygon layer with attribute information on potential aquifer productivity and lithology. While the standardized aquifer-classification is relatively easy to harmonize across the entire mapped area, the lithological information of IHME1500 is presented using sheet-specific legend information resulting in more than 1000 aquifer lithology classes. An attempt was made to harmonize this information utilizing a specifically developed taxonomic scheme, treating consolidated, partly consolidated and unconsolidated materials separately. The translation of the original lithological information into this scheme allows for a hierarchical grouping of the mapping units into five generalization levels, where the highest aggregation level displays a ternary map showing the distribution of consolidated, partially consolidated and unconsolidated aquifer materials. The harmonized and hierarchically structured IHME1500 information based on the published map sheet data also allows for the extension of the mapped area in regions where only incomplete, unpublished IHME1500 draft information is available. IHME1500 now covers the entire European continent up to the Urals, the Caucasus region, and parts of the Middle East (Turkey, Cyprus, parts of Syria and Iraq). IHME1500 represents the only digitally available coherent overview information on potential groundwater resources and shallow aquifer characteristics across Europe. The data is therefore of great use for European policy support in terms of e.g. transboundary aquifer identification and characterization, the harmonization of regional European groundwater bodies, and the delineation of hot spot regions for aquifer systems under potential environmental stress with respect to climate change, natural hazards or migratory flows. Additionally, the lithological information of IHME1500 represents the only harmonized pan-European dataset on shallow subsurface geologic materials available and can used for the spatial delineation of soil parent materials and as a spatial predictor for the evaluation of geomorphological hazards at overview scales. IHME1500 GIS data can be downloaded through BGŔs product centre (http://produktcenter.bgr.de).

  1. Sputtering from a Porous Material by Penetrating Ions

    NASA Technical Reports Server (NTRS)

    Rodriguez-Nieva, J. F.; Bringa, E. M.; Cassidy, T. A.; Johnson, R. E.; Caro, A.; Fama, M.; Loeffler, M.; Baragiola, R. A.; Farkas, D.

    2012-01-01

    Porous materials are ubiquitous in the universe and weathering of porous surfaces plays an important role in the evolution of planetary and interstellar materials. Sputtering of porous solids in particular can influence atmosphere formation, surface reflectivity, and the production of the ambient gas around materials in space, Several previous studies and models have shown a large reduction in the sputtering of a porous solid compared to the sputtering of the non-porous solid. Using molecular dynamics simulations we study the sputtering of a nanoporous solid with 55% of the solid density. We calculate the electronic sputtering induced by a fast, penetrating ion, using a thermal spike representation of the deposited energy. We find that sputtering for this porous solid is, surprisingly, the same as that for a full-density solid, even though the sticking coefficient is high.

  2. Silk Fibroin Based Porous Materials

    PubMed Central

    Zhang, Qiang; Yan, Shuqin; Li, Mingzhong

    2009-01-01

    Silk from the Bombyx mori silkworm is a protein-based fiber. Bombyx mori silk fibroin (SF) is one of the most important candidates for biomedical porous material based on its superior machinability, biocompatibility, biodegradation, bioresorbability, and so on. In this paper, we have reviewed the key features of SF. Moreover we have focused on the morphous, technical processing, and biocompatibility of SF porous materials, followed by the application research. Finally, we provide a perspective the potential and problems of SF porous materials.

  3. General Theory of Absorption in Porous Materials: Restricted Multilayer Theory.

    PubMed

    Aduenko, Alexander A; Murray, Andy; Mendoza-Cortes, Jose L

    2018-04-18

    In this article, we present an approach for the generalization of adsorption of light gases in porous materials. This new theory goes beyond Langmuir and Brunauer-Emmett-Teller theories, which are the standard approaches that have a limited application to crystalline porous materials by their unphysical assumptions on the amount of possible adsorption layers. The derivation of a more general equation for any crystalline porous framework is presented, restricted multilayer theory. Our approach allows the determination of gas uptake considering only geometrical constraints of the porous framework and the interaction energy of the guest molecule with the framework. On the basis of this theory, we calculated optimal values for the adsorption enthalpy at different temperatures and pressures. We also present the use of this theory to determine the optimal linker length for a topologically equivalent framework series. We validate this theoretical approach by applying it to metal-organic frameworks (MOFs) and show that it reproduces the experimental results for seven different reported materials. We obtained the universal equation for the optimal linker length, given the topology of a porous framework. This work applied the general equation to MOFs and H 2 to create energy-storage materials; however, this theory can be applied to other crystalline porous materials and light gases, which opens the possibility of designing the next generations of energy-storage materials by first considering only the geometrical constraints of the porous materials.

  4. Porous multi-component material for the capture and separation of species of interest

    DOEpatents

    Addleman, Raymond S.; Chouyyok, Wilaiwan; Li, Xiaohong S.; Cinson, Anthony D.; Gerasimenko, Aleksandr A

    2016-06-21

    A method and porous multi-component material for the capture, separation or chemical reaction of a species of interest is disclosed. The porous multi-component material includes a substrate and a composite thin film. The composite thin film is formed by combining a porous polymer with a nanostructured material. The nanostructured material may include a surface chemistry for the capture of chemicals or particles. The composite thin film is coupled to the support or device surface. The method and material provides a simple, fast, and chemically and physically benign way to integrate nanostructured materials into devices while preserving their chemical activity.

  5. Modulation power of porous materials and usage as ripple filter in particle therapy.

    PubMed

    Printz Ringbæk, Toke; Simeonov, Yuri; Witt, Matthias; Engenhart-Cabillic, Rita; Kraft, Gerhard; Zink, Klemens; Weber, Uli

    2017-04-07

    Porous materials with microscopic structures like foam, sponges, lung tissues and lung substitute materials have particular characteristics, which differ from those of solid materials. Ion beams passing through porous materials show much stronger energy straggling than expected for non-porous solid materials of the same thickness. This effect depends on the microscopic fine structure, the density and the thickness of the porous material. The beam-modulating effect from a porous plate enlarges the Bragg peak, yielding similar benefits in irradiation time reduction as a ripple filter. A porous plate can additionally function as a range shifter, which since a higher energy can be selected for the same penetration depth in the body reduces the scattering at the beam line and therefore improves the lateral fall-off. Bragg curve measurements of ion beams passing through different porous materials have been performed in order to determine the beam modulation effect of each. A mathematical model describing the correlation between the mean material density, the porous pore structure size and the strength of the modulation has been developed and a new material parameter called 'modulation power' is defined as the square of the Gaussian sigma divided by the mean water-equivalent thickness of the porous absorber. Monte Carlo simulations have been performed in order to validate the model and to investigate the Bragg peak enlargement, the scattering effects of porosity and the lateral beam width at the end of the beam range. The porosity is found to only influence the lateral scattering in a negligible way. As an example of a practical application, it is found that a 20 mm and 50 mm plate of Gammex LN300 performs similar to a 3 mm and 6 mm ripple filter, respectively, and at the same time can improve the sharpness of the lateral beam due to its multifunctionality as a ripple filter and a range shifter.

  6. Ultrasonic Nondestructive Characterization of Porous Materials

    NASA Astrophysics Data System (ADS)

    Yang, Ningli

    2011-12-01

    Wave propagation in porous media is studied in a wide range of technological applications. In the manufacturing industry, determining porosity of materials in the manufacturing process is required for strict quality control. In the oil industry, acoustic signals and seismic surveys are used broadly to determine the physical properties of the reservoir rock which is a porous media filled with oil or gas. In porous noise control materials, a precise prediction of sound absorption with frequency and evaluation of tortuosity are necessary. Ultrasonic nondestructive methods are a very important tool for characterization of porous materials. The dissertation deals with two types of porous media: materials with relatively low and closed porosity and materials with comparatively high and open porosity. Numerical modeling, Finite Element simulations and experimental characterization are all discussed in this dissertation. First, ultrasonic scattering is used to determine the porosity in porous media with closed pores. In order get a relationship between the porosity in porous materials and ultrasonic scattering independently and to increase the sensitivity to obtain scattering information, ultrasonic imaging methods are applied and acoustic waves are focused by an acoustic lens. To verify the technique, engineered porous acrylic plates with varying porosity are measured by ultrasonic scanning and ultrasonic array sensors. Secondly, a laser based ultrasonic technique is explored for predicting the mechanical integrity and durability of cementitious materials. The technique used involves the measurement of the phase velocity of fast and slow longitudinal waves in water saturated cement paste. The slow wave velocity is related to the specimen's tortuosity. The fast wave speed is dependent on the elastic properties of porous solid. Experimental results detailing the generation and detection of fast and slow wave waves in freshly prepared and aged water-saturated cement samples with varying water-to-cement ratios are presented in the dissertation. The third part concerns the ultrasonic characterization of air-saturated porous materials. Using airborne reflected and transmitted ultrasonic experimental data, the open porosity and tortuosity value of a porous acrylic plate with graded void content and a polyimide foam are determined simultaneously. Experimental and numerical results of the method are presented.

  7. Simplified method to solve sound transmission through structures lined with elastic porous material.

    PubMed

    Lee, J H; Kim, J

    2001-11-01

    An approximate analysis method is developed to calculate sound transmission through structures lined with porous material. Because the porous material has both the solid phase and fluid phase, three wave components exist in the material, which makes the related analysis very complicated. The main idea in developing the approximate method is very simple: modeling the porous material using only the strongest of the three waves, which in effect idealizes the material as an equivalent fluid. The analysis procedure has to be conducted in two steps. In the first step, sound transmission through a flat double panel with a porous liner of infinite extents, which has the same cross sectional construction as the actual structure, is solved based on the full theory and the strongest wave component is identified. In the second step sound transmission through the actual structure is solved modeling the porous material as an equivalent fluid while using the actual geometry of the structure. The development and validation of the method are discussed in detail. As an application example, the transmission loss through double walled cylindrical shells with a porous core is calculated utilizing the simplified method.

  8. An Evaluation of the Antimicrobial Effects of Gas-Phase Ozone

    EPA Science Inventory

    This project evaluated the effects of exposing a variety of microorganisms on porous and non-porous materials to elevated gaseous ozone concentrations ranging from 100 - 1000 ppm. Gypsum wallboard (porous) and glass slide (non-porous) building materials were used. Two fungi organ...

  9. Infiltration performance of engineered surfaces commonly used for distributed stormwater management

    NASA Astrophysics Data System (ADS)

    Valinski, Nicholas A.

    Engineered porous media are commonly used in low impact development (LID) structures to mitigate excess stormwater in urban environments. Differences in infiltrability of these LID systems arise from the wide variety of materials used to create porous surfaces and subsequent maintenance, debris loading, and physical damage. In this study, infiltration capacity of six common materials was tested by multiple replicate experiments with automated mini-disk infiltrometers. The tested materials included porous asphalt, porous concrete, porous brick pavers, flexible porous pavement, engineered soils, and native soils. Porous asphalt, large porous brick pavers, and curb cutout rain gardens showed the greatest infiltration rates. Most engineered porous pavements and soils performed better than the native silt loam soils. Infiltration performance was found to be related more to site design and environmental factors than material choice. Sediment trap zones in both pavements and engineered soil rain gardens were found to be beneficial to the whole site performance. Winter chloride application had a large negative impact on poured in place concrete, making it a poor choice for heavily salted areas.

  10. Infiltration performance of engineered surfaces commonly used for distributed stormwater management.

    PubMed

    Valinski, N A; Chandler, D G

    2015-09-01

    Engineered porous media are commonly used in low impact development (LID) structures to mitigate excess stormwater in urban environments. Differences in infiltrability of these LID systems arise from the wide variety of materials used to create porous surfaces and subsequent maintenance, debris loading, and physical damage. In this study, the infiltration capacity of six common materials was tested by multiple replicate experiments with automated mini-disk infiltrometers. The tested materials included porous asphalt, porous concrete, porous brick pavers, flexible porous pavement, engineered soils, and native soils. Porous asphalt, large porous brick pavers, and curb cutout rain gardens showed the greatest infiltration rates. Most engineered porous pavements and soils performed better than the native silt loam soils. Infiltration performance was found to be related more to site design and environmental factors than material choice. Sediment trap zones in both pavements and engineered soil rain gardens were found to be beneficial to the whole site performance. Winter chloride application had a large negative impact on poured in place concrete, making it a poor choice for heavily salted areas. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Preparation of the Lentinus edodes-based porous biomass carbon by hydrothermal method for capacitive desalination

    NASA Astrophysics Data System (ADS)

    Yan, Junbin; Zhang, Hexuan; Xie, Zhengzheng; Liu, Jianyun

    2017-08-01

    Biomass carbon materials were prepared by hydrothermal method using Lentinus edodes, followed by activation by ZnCl2 at high carbonization temperature. SEM and contact angle test show that ZnCl2 has a significant effect on the surface morphology and properties of porous carbon materials. Using the porous carbon as electrodes of the capacitor, the specific capacitance of the porous carbon material was found to be 247.6 F/g. The desalination amount of porous carbon material in capacitor cell was 12.9 mg/g, being the 1.9 times of that of the commercial activated carbon.

  12. Progress of Application Researches of Porous Fiber Metals

    PubMed Central

    Xi, Zhengping; Zhu, Jilei; Tang, Huiping; Ao, Qingbo; Zhi, Hao; Wang, Jianyong; Li, Cheng

    2011-01-01

    Metal fiber porous materials with intrinsic properties of metal and functional properties of porous materials have received a great deal of attention in the fundamental research and industry applications. With developments of the preparation technologies and industrial requirements, porous fiber metals with excellent properties are developed and applied in many industry areas, e.g., sound absorption, heat transfer, energy absorption and lightweight structures. The applied research progress of the metal fiber porous materials in such application areas based on the recent work in our group was reviewed in this paper. PMID:28879952

  13. Porous organic cages

    NASA Astrophysics Data System (ADS)

    Tozawa, Tomokazu; Jones, James T. A.; Swamy, Shashikala I.; Jiang, Shan; Adams, Dave J.; Shakespeare, Stephen; Clowes, Rob; Bradshaw, Darren; Hasell, Tom; Chong, Samantha Y.; Tang, Chiu; Thompson, Stephen; Parker, Julia; Trewin, Abbie; Bacsa, John; Slawin, Alexandra M. Z.; Steiner, Alexander; Cooper, Andrew I.

    2009-12-01

    Porous materials are important in a wide range of applications including molecular separations and catalysis. We demonstrate that covalently bonded organic cages can assemble into crystalline microporous materials. The porosity is prefabricated and intrinsic to the molecular cage structure, as opposed to being formed by non-covalent self-assembly of non-porous sub-units. The three-dimensional connectivity between the cage windows is controlled by varying the chemical functionality such that either non-porous or permanently porous assemblies can be produced. Surface areas and gas uptakes for the latter exceed comparable molecular solids. One of the cages can be converted by recrystallization to produce either porous or non-porous polymorphs with apparent Brunauer-Emmett-Teller surface areas of 550 and 23m2g-1, respectively. These results suggest design principles for responsive porous organic solids and for the modular construction of extended materials from prefabricated molecular pores.

  14. Multi-regime transport model for leaching behavior of heterogeneous porous materials.

    PubMed

    Sanchez, F; Massry, I W; Eighmy, T; Kosson, D S

    2003-01-01

    Utilization of secondary materials in civil engineering applications (e.g. as substitutes for natural aggregates or binder constituents) requires assessment of the physical and environment properties of the product. Environmental assessment often necessitates evaluation of the potential for constituent release through leaching. Currently most leaching models used to estimate long-term field performance assume that the species of concern is uniformly dispersed in a homogeneous porous material. However, waste materials are often comprised of distinct components such as coarse or fine aggregates in a cement concrete or waste encapsulated in a stabilized matrix. The specific objectives of the research presented here were to (1) develop a one-dimensional, multi-regime transport model (i.e. MRT model) to describe the release of species from heterogeneous porous materials and, (2) evaluate simple limit cases using the model for species when release is not dependent on pH. Two different idealized model systems were considered: (1) a porous material contaminated with the species of interest and containing inert aggregates and, (2) a porous material containing the contaminant of interest only in the aggregates. The effect of three factors on constituent release were examined: (1) volume fraction of material occupied by the aggregates compared to a homogeneous porous material, (2) aggregate size and, (3) differences in mass transfer rates between the binder and the aggregates. Simulation results confirmed that assuming homogeneous materials to evaluate the release of contaminants from porous waste materials may result in erroneous long-term field performance assessment.

  15. Acoustic Absorption in Porous Materials

    NASA Technical Reports Server (NTRS)

    Kuczmarski, Maria A.; Johnston, James C.

    2011-01-01

    An understanding of both the areas of materials science and acoustics is necessary to successfully develop materials for acoustic absorption applications. This paper presents the basic knowledge and approaches for determining the acoustic performance of porous materials in a manner that will help materials researchers new to this area gain the understanding and skills necessary to make meaningful contributions to this field of study. Beginning with the basics and making as few assumptions as possible, this paper reviews relevant topics in the acoustic performance of porous materials, which are often used to make acoustic bulk absorbers, moving from the physics of sound wave interactions with porous materials to measurement techniques for flow resistivity, characteristic impedance, and wavenumber.

  16. Porous silicon technology for integrated microsystems

    NASA Astrophysics Data System (ADS)

    Wallner, Jin Zheng

    With the development of micro systems, there is an increasing demand for integrable porous materials. In addition to those conventional applications, such as filtration, wicking, and insulating, many new micro devices, including micro reactors, sensors, actuators, and optical components, can benefit from porous materials. Conventional porous materials, such as ceramics and polymers, however, cannot meet the challenges posed by micro systems, due to their incompatibility with standard micro-fabrication processes. In an effort to produce porous materials that can be used in micro systems, porous silicon (PS) generated by anodization of single crystalline silicon has been investigated. In this work, the PS formation process has been extensively studied and characterized as a function of substrate type, crystal orientation, doping concentration, current density and surfactant concentration and type. Anodization conditions have been optimized for producing very thick porous silicon layers with uniform pore size, and for obtaining ideal pore morphologies. Three different types of porous silicon materials: meso porous silicon, macro porous silicon with straight pores, and macro porous silicon with tortuous pores, have been successfully produced. Regular pore arrays with controllable pore size in the range of 2mum to 6mum have been demonstrated as well. Localized PS formation has been achieved by using oxide/nitride/polysilicon stack as masking materials, which can withstand anodization in hydrofluoric acid up to twenty hours. A special etching cell with electrolytic liquid backside contact along with two process flows has been developed to enable the fabrication of thick macro porous silicon membranes with though wafer pores. For device assembly, Si-Au and In-Au bonding technologies have been developed. Very low bonding temperature (˜200°C) and thick/soft bonding layers (˜6mum) have been achieved by In-Au bonding technology, which is able to compensate the potentially rough surface on the porous silicon sample without introducing significant thermal stress. (Abstract shortened by UMI.)

  17. Biot-Gassmann theory for velocities of gas hydrate-bearing sediments

    USGS Publications Warehouse

    Lee, M.W.

    2002-01-01

    Elevated elastic velocities are a distinct physical property of gas hydrate-bearing sediments. A number of velocity models and equations (e.g., pore-filling model, cementation model, effective medium theories, weighted equations, and time-average equations) have been used to describe this effect. In particular, the weighted equation and effective medium theory predict reasonably well the elastic properties of unconsolidated gas hydrate-bearing sediments. A weakness of the weighted equation is its use of the empirical relationship of the time-average equation as one element of the equation. One drawback of the effective medium theory is its prediction of unreasonably higher shear-wave velocity at high porosities, so that the predicted velocity ratio does not agree well with the observed velocity ratio. To overcome these weaknesses, a method is proposed, based on Biot-Gassmann theories and assuming the formation velocity ratio (shear to compressional velocity) of an unconsolidated sediment is related to the velocity ratio of the matrix material of the formation and its porosity. Using the Biot coefficient calculated from either the weighted equation or from the effective medium theory, the proposed method accurately predicts the elastic properties of unconsolidated sediments with or without gas hydrate concentration. This method was applied to the observed velocities at the Mallik 2L-39 well, Mackenzie Delta, Canada.

  18. Silicon quantum dots for energetic material applications

    NASA Astrophysics Data System (ADS)

    Adams, Sarah K.; Piekiel, Nicholas W.; Ervin, Matthew H.; Morris, Christopher J.

    2018-06-01

    In its history as an energetic material, porous silicon has demonstrated flame speeds in excess of 3 km s-1, tunable combustion behavior, and high energy output, which in theory makes it a very attractive energetic system. In practice, its application within the field is limited by porous silicon's typical substrate-adhered form and caustic chemical processing requirements that limit how and when porous silicon is made. In this work, we have relieved porous silicon of these constraints by creating reactive silicon quantum dots from free-standing porous silicon films. The resulting material is composed of crystalline silicon nanoparticles with diameters as small as 2 nm that retain the chemical properties of the original films including the SiH2 termination layer. The fabricated silicon particles were characterized using FTIR Spectroscopy, TEM, and EDS for determining the size and the chemical composition. For testing as an energetic material fuel, porous silicon was mixed with an oft used oxidizer, sodium perchlorate. During open-channel combustion tests, silicon quantum dots mixed with sodium perchlorate demonstrated flame speeds over 2.5 km s-1, while bomb calorimetry tests showed an average heat of combustion of 7.4 kJ g-1. These results demonstrate the ability to retain the porous silicon material properties that allow for highly energetic material reactions to occur, despite the additional processing steps to create silicon quantum dots. This opens the door for the use of porous silicon in the bulk of the energetic material application space, much of which was previously limited due to the substrate-attached nature of typical porous silicon.

  19. Ground-water conditions and quality in the western part of Kenai Peninsula, southcentral Alaska

    USGS Publications Warehouse

    Glass, R.L.

    1996-01-01

    The western part of Kenai Peninsula in southcentral Alaska is bounded by Cook Inlet and the Kenai Mountains. Ground water is the predominant source of water for commercial, industrial, and domestic uses on the peninsula. Mean daily water use in an oil, gas, and chemical processing area north of Kenai is more than 3.5 million gallons. Unconsolidated sediments of glacial and fluvial origin are the most productive aquifers. In the upper (northwestern) peninsula, almost all water used is withdrawn from unconsolidated sediments, which may be as thick as 750 feet. In the lower peninsula, unconsolidated sediments are thinner and are absent on many hills. Water supplies in the lower peninsula are obtained from unconsolidated sediments and bedrock, and a public-water supply in parts of Homer is obtained from Bridge Creek. Throughout the peninsula, ground-water flow occurs primarily as localized flow controlled by permeability of aquifer materials and surface topography. The concentration of constituents analyzed in water from 312 wells indicated that the chemical quality of ground water for human consumption varies from marginal to excellent. Even though the median concentration of dissolved solids is low (152 milligrams per liter), much of the ground water on the peninsula does not meet water-quality regulations for public drinking water established by the U.S. Environmental Protection Agency (USEPA). About 8 percent of wells sampled yielded water having concentrations of dissolved arsenic that exceeded the USEPA primary maximum contaminant level of 50 micrograms per liter. Concentrations of dissolved arsenic were as great as 94 micrograms per liter. Forty-six percent of wells sampled yielded water having concentrations of dissolved iron greater than the USEPA secondary maximum contaminant level of 300 micrograms per liter. Unconsolidated sediments generally yield water having calcium, magnesium, and bicarbonate as its predominant ions. In some areas, ground water at depths greater than a few hundred feet may be naturally too salty for human consumption. The leaking and spilling of fuel and chemical products and the disposal of industrial wastes has degraded the quality of ground water at numerous sites.

  20. Catalyst containing oxygen transport membrane

    DOEpatents

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  1. Impact of physicochemical properties of porous silica materials conjugated with dexamethasone via pH-responsive hydrazone bond on drug loading and release behavior

    NASA Astrophysics Data System (ADS)

    Numpilai, Thanapha; Witoon, Thongthai; Chareonpanich, Metta; Limtrakul, Jumras

    2017-02-01

    The conjugation of dexamethasone (DEX) onto modified-porous silica materials via a pH-responsive hydrazone bond has been reported to be highly efficient method to specifically deliver the DEX to diseased sites. However, the influence of physicochemical properties of porous silica materials has not yet been fully understood. In this paper, the impact of pore sizes, particle sizes and silanol contents on surface functionalization, drug loading and release behavior of porous silica materials conjugated with dexamethasone via pH-responsive hydrazone bond was investigated. The grafting density was found to relate to the number of silanol groups on the surface of porous silica materials. The particle size and macropores of the porous silica materials played an vital role on the drug loading and release behavior. Although the porous silica materials with larger particle sizes possessed a lower grafting density, a larger amount of drug loading could be achieved. Moreover, the porous silica materials with larger particle sizes showed a slower release rate of DEX due to a longer distance for cleaved DEX diffusion out of pores. DEX release rate exhibited pH-dependent, sustained release. At pH 4.5, the amount of DEX release within 10 days could be controlled in the range of 12.74-36.41%, depending on the host material. Meanwhile, less than 1.5% of DEX was released from each of type of the porous silica materials at pH 7.4. The results of silica dissolution suggested that the degradation of silica matrix did not significantly affect the release rate of DEX. In addition, the kinetic modeling studies revealed that the DEX releases followed Korsmeyer-Peppas model with a release exponent (n) ranged from 0.3 to 0.47, indicating a diffusion-controlled release mechanism.

  2. New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior.

    PubMed

    Shan, Weida; Fulvio, Pasquale F; Kong, Liyun; Schott, Jennifer A; Do-Thanh, Chi-Linh; Tian, Tao; Hu, Xunxiang; Mahurin, Shannon M; Xing, Huabin; Dai, Sheng

    2018-01-10

    Porous materials have already manifested their unique properties in a number of fields. Generally, all porous materials are in a solid state other than liquid, in which molecules are closely packed without porosity. "Porous" and "liquid" seem like antonyms. Herein, we report a new class of Type 3 porous liquids based on rational coupling of microporous framework nanoparticles as porous hosts with a bulky ionic liquid as the fluid media. Positron annihilation lifetime spectroscopy (PALS) and CO 2 adsorption measurements confirm the successful engineering of permanent porosity into these liquids. Compared to common porous solid materials, as-synthesized porous liquids exhibited pronounced hysteresis loops in the CO 2 sorption isotherms even at ambient conditions (298 K, 1 bar). The unique features of these novel porous liquids could bring new opportunities in many fields including gas separation and storage, air separation and regeneration, gas transport, and permanent gas storage at ambient conditions.

  3. Light emitting diode with porous SiC substrate and method for fabricating

    DOEpatents

    Li, Ting; Ibbetson, James; Keller, Bernd

    2005-12-06

    A method and apparatus for forming a porous layer on the surface of a semiconductor material wherein an electrolyte is provided and is placed in contact with one or more surfaces of a layer of semiconductor material. The electrolyte is heated and a bias is introduced across said electrolyte and the semiconductor material causing a current to flow between the electrolyte and the semiconductor material. The current forms a porous layer on the one or more surfaces of the semiconductor material in contact with the electrolyte. The semiconductor material with its porous layer can serve as a substrate for a light emitter. A semiconductor emission region can be formed on the substrate. The emission region is capable of emitting light omnidirectionally in response to a bias, with the porous layer enhancing extraction of the emitting region light passing through the substrate.

  4. Gas permeability of ice-templated, unidirectional porous ceramics

    NASA Astrophysics Data System (ADS)

    Seuba, Jordi; Deville, Sylvain; Guizard, Christian; Stevenson, Adam J.

    2016-01-01

    We investigate the gas flow behavior of unidirectional porous ceramics processed by ice-templating. The pore volume ranged between 54% and 72% and pore size between 2.9 ?m and 19.1 ?m. The maximum permeability (?? m?) was measured in samples with the highest total pore volume (72%) and pore size (19.1 ?m). However, we demonstrate that it is possible to achieve a similar permeability (?? m?) at 54% pore volume by modification of the pore shape. These results were compared with those reported and measured for isotropic porous materials processed by conventional techniques. In unidirectional porous materials tortuosity (?) is mainly controlled by pore size, unlike in isotropic porous structures where ? is linked to pore volume. Furthermore, we assessed the applicability of Ergun and capillary model in the prediction of permeability and we found that the capillary model accurately describes the gas flow behavior of unidirectional porous materials. Finally, we combined the permeability data obtained here with strength data for these materials to establish links between strength and permeability of ice-templated materials.

  5. Development of the technology for the fabrication of reliable laminar flow control panels

    NASA Technical Reports Server (NTRS)

    Weiss, D. D.; Lindh, D. V.

    1977-01-01

    Various configurations of porous, perforated and slotted materials were flow tested to determine if they would meet the LFC surface smoothness and flow requirements. The candidate materials were then tested for susceptibility to clogging and for resistance to corrosion. Of the materials tested, perforated titanium, porous polyimide, and slotted assemblies demonstrated a much greater resistance to clogging than other porous materials.

  6. Freeze-Casting of Porous Biomaterials: Structure, Properties and Opportunities

    PubMed Central

    Deville, Sylvain

    2010-01-01

    The freeze-casting of porous materials has received a great deal of attention during the past few years. This simple process, where a material suspension is simply frozen and then sublimated, provides materials with unique porous architectures, where the porosity is almost a direct replica of the frozen solvent crystals. This review focuses on the recent results on the process and the derived porous structures with regards to the biomaterials applications. Of particular interest is the architecture of the materials and the versatility of the process, which can be readily controlled and applied to biomaterials applications. A careful control of the starting formulation and processing conditions is required to control the integrity of the structure and resulting properties. Further in vitro and in vivo investigations are required to validate the potential of this new class of porous materials.

  7. Physicochemical properties affect the synthesis, controlled delivery, degradation and pharmacokinetics of inorganic nanoporous materials.

    PubMed

    Yazdi, Iman K; Ziemys, Arturas; Evangelopoulos, Michael; Martinez, Jonathan O; Kojic, Milos; Tasciotti, Ennio

    2015-10-01

    Controlling size, shape and uniformity of porous constructs remains a major focus of the development of porous materials. Over the past two decades, we have seen significant developments in the fabrication of new, porous-ordered structures using a wide range of materials, resulting in properties well beyond their traditional use. Porous materials have been considered appealing, due to attractive properties such as pore size length, morphology and surface chemistry. Furthermore, their utilization within the life sciences and medicine has resulted in significant developments in pharmaceutics and medical diagnosis. This article focuses on various classes of porous materials, providing an overview of principle concepts with regard to design and fabrication, surface chemistry and loading and release kinetics. Furthermore, predictions from a multiscale mathematical model revealed the role pore length and diameter could have on payload release kinetics.

  8. High-performance supercapacitors of Cu-based porous coordination polymer nanowires and the derived porous CuO nanotubes.

    PubMed

    Wu, Meng-Ke; Zhou, Jiao-Jiao; Yi, Fei-Yan; Chen, Chen; Li, Yan-Li; Li, Qin; Tao, Kai; Han, Lei

    2017-12-12

    Electrode materials for supercapacitors with one-dimensional porous nanostructures, such as nanowires and nanotubes, are very attractive for high-efficiency storage of electrochemical energy. Herein, ultralong Cu-based porous coordination polymer nanowires (copper-l-aspartic acid) were used as the electrode material for supercapacitors, for the first time. The as-prepared material exhibits a high specific capacitance of 367 F g -1 at 0.6 A g -1 and excellent cycling stability (94% retention over 1000 cycles). Moreover, porous CuO nanotubes were successfully fabricated by the thermal decomposition of this nanowire precursor. The CuO nanotube exhibits good electrochemical performance with high rate capacity (77% retention at 12.5 A g -1 ) and long-term stability (96% retention over 1000 cycles). The strategy developed here for the synthesis of porous nanowires and nanotubes can be extended to the construction of other electrode materials for more efficient energy storage.

  9. Proceedings of the wellbore sampling workshop

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Traeger, R.K.; Harding, B.W.

    Representatives from academia, industry and research laboratories participated in an intensive two-day review to identify major technological limitations in obtaining solid and fluid samples from wellbores. Top priorities identified for further development include: coring of hard and unconsolidated materials; flow through fluid samplers with borehole measurements T, P and pH; and nonintrusive interrogation of pressure cores.

  10. Porous Molecular Solids and Liquids

    PubMed Central

    2017-01-01

    Until recently, porous molecular solids were isolated curiosities with properties that were eclipsed by porous frameworks, such as metal–organic frameworks. Now molecules have emerged as a functional materials platform that can have high levels of porosity, good chemical stability, and, uniquely, solution processability. The lack of intermolecular bonding in these materials has also led to new, counterintuitive states of matter, such as porous liquids. Our ability to design these materials has improved significantly due to advances in computational prediction methods. PMID:28691065

  11. Efficiently mapping structure-property relationships of gas adsorption in porous materials: application to Xe adsorption.

    PubMed

    Kaija, A R; Wilmer, C E

    2017-09-08

    Designing better porous materials for gas storage or separations applications frequently leverages known structure-property relationships. Reliable structure-property relationships, however, only reveal themselves when adsorption data on many porous materials are aggregated and compared. Gathering enough data experimentally is prohibitively time consuming, and even approaches based on large-scale computer simulations face challenges. Brute force computational screening approaches that do not efficiently sample the space of porous materials may be ineffective when the number of possible materials is too large. Here we describe a general and efficient computational method for mapping structure-property spaces of porous materials that can be useful for adsorption related applications. We describe an algorithm that generates random porous "pseudomaterials", for which we calculate structural characteristics (e.g., surface area, pore size and void fraction) and also gas adsorption properties via molecular simulations. Here we chose to focus on void fraction and Xe adsorption at 1 bar, 5 bar, and 10 bar. The algorithm then identifies pseudomaterials with rare combinations of void fraction and Xe adsorption and mutates them to generate new pseudomaterials, thereby selectively adding data only to those parts of the structure-property map that are the least explored. Use of this method can help guide the design of new porous materials for gas storage and separations applications in the future.

  12. Examining porous bio-active glass as a potential osteo-odonto-keratoprosthetic skirt material.

    PubMed

    Huhtinen, Reeta; Sandeman, Susan; Rose, Susanna; Fok, Elsie; Howell, Carol; Fröberg, Linda; Moritz, Niko; Hupa, Leena; Lloyd, Andrew

    2013-05-01

    Bio-active glass has been developed for use as a bone substitute with strong osteo-inductive capacity and the ability to form strong bonds with soft and hard tissue. The ability of this material to enhance tissue in-growth suggests its potential use as a substitute for the dental laminate of an osteo-odonto-keratoprosthesis. A preliminary in vitro investigation of porous bio-active glass as an OOKP skirt material was carried out. Porous glass structures were manufactured from bio-active glasses 1-98 and 28-04 containing varying oxide formulation (1-98, 28-04) and particle size range (250-315 μm for 1-98 and 28-04a, 315-500 μm for 28-04b). Dissolution of the porous glass structure and its effect on pH was measured. Structural 2D and 3D analysis of porous structures were performed. Cell culture experiments were carried out to study keratocyte adhesion and the inflammatory response induced by the porous glass materials. The dissolution results suggested that the porous structure made out of 1-98 dissolves faster than the structures made from glass 28-04. pH experiments showed that the dissolution of the porous glass increased the pH of the surrounding solution. The cell culture results showed that keratocytes adhered onto the surface of each of the porous glass structures, but cell adhesion and spreading was greatest for the 98a bio-glass. Cytokine production by all porous glass samples was similar to that of the negative control indicating that the glasses do not induce a cytokine driven inflammatory response. Cell culture results support the potential use of synthetic porous bio-glass as an OOKP skirt material in terms of limited inflammatory potential and capacity to induce and support tissue ingrowth.

  13. Terrestrial Sediments of the Earth: Development of a Global Unconsolidated Sediments Map Database (GUM)

    NASA Astrophysics Data System (ADS)

    Börker, J.; Hartmann, J.; Amann, T.; Romero-Mujalli, G.

    2018-04-01

    Mapped unconsolidated sediments cover half of the global land surface. They are of considerable importance for many Earth surface processes like weathering, hydrological fluxes or biogeochemical cycles. Ignoring their characteristics or spatial extent may lead to misinterpretations in Earth System studies. Therefore, a new Global Unconsolidated Sediments Map database (GUM) was compiled, using regional maps specifically representing unconsolidated and quaternary sediments. The new GUM database provides insights into the regional distribution of unconsolidated sediments and their properties. The GUM comprises 911,551 polygons and describes not only sediment types and subtypes, but also parameters like grain size, mineralogy, age and thickness where available. Previous global lithological maps or databases lacked detail for reported unconsolidated sediment areas or missed large areas, and reported a global coverage of 25 to 30%, considering the ice-free land area. Here, alluvial sediments cover about 23% of the mapped total ice-free area, followed by aeolian sediments (˜21%), glacial sediments (˜20%), and colluvial sediments (˜16%). A specific focus during the creation of the database was on the distribution of loess deposits, since loess is highly reactive and relevant to understand geochemical cycles related to dust deposition and weathering processes. An additional layer compiling pyroclastic sediment is added, which merges consolidated and unconsolidated pyroclastic sediments. The compilation shows latitudinal abundances of sediment types related to climate of the past. The GUM database is available at the PANGAEA database (https://doi.org/10.1594/PANGAEA.884822).

  14. Heterogeneous porous structures for the fastest liquid absorption

    NASA Astrophysics Data System (ADS)

    Shou, Dahua; Ye, Lin; Fan, Jintu

    2013-08-01

    Engineered porous materials, which have fast absorption of liquids under global constraints (e.g. volume, surface area, or cost of the materials), are useful in many applications including moisture management fabrics, medical wound dressings, paper-based analytical devices, liquid molding composites, etc.. The absorption in capillary tubes and porous media is driven by the surface tension of liquid, which is inversely proportional to the pore size. On the contrary, the ability of conduction (or permeability) of liquid in porous materials is linear with the square of pore size. Both mechanisms superimpose with each other leading to a possibility of the fastest absorption for a porous structure. In this work, we explore the flow behaviors for the fastest absorption using heterogeneous porous architectures, from two-portion tubes to two-layer porous media. The absorption time for filling up the voids in these porous materials is expressed in terms of pore size, height and porosity. It is shown that under the given height and void volume, these two-component porous structures with a negative gradient of pore size/porosity against the imbibition direction, have a faster absorption rate than controlled samples with uniform pore size/porosity. Particularly, optimal structural parameters including pore size, height and porosity are found for the minimum absorption time. The obtained results will be used as a priori for the design of porous structures with excellent water absorption and moisture management property in various fields.

  15. Porous materials produced from incineration ash using thermal plasma technology.

    PubMed

    Yang, Sheng-Fu; Chiu, Wen-Tung; Wang, To-Mai; Chen, Ching-Ting; Tzeng, Chin-Ching

    2014-06-01

    This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9-1.2 g cm(-3) and 50-60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m(-1) K(-1). Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

  16. Influences of surface charge, size, and concentration of colloidal nanoparticles on fabrication of self-organized porous silica in film and particle forms.

    PubMed

    Nandiyanto, Asep Bayu Dani; Suhendi, Asep; Arutanti, Osi; Ogi, Takashi; Okuyama, Kikuo

    2013-05-28

    Studies on preparation of porous material have attracted tremendous attention because existence of pores can provide material with excellent performances. However, current preparation reports described successful production of porous material with only partial information on charges, interactions, sizes, and compositions of the template and host materials. In this report, influences of self-assembly parameters (i.e., surface charge, size, and concentration of colloidal nanoparticles) on self-organized porous material fabrication were investigated. Silica nanoparticles (as a host material) and polystyrene (PS) spheres (as a template) were combined to produce self-assembly porous materials in film and particle forms. The experimental results showed that the porous structure and pore size were controllable and strongly depended on the self-assembly parameters. Materials containing highly ordered pores were effectively created only when process parameters fall within appropriate conditions (i.e., PS surface charge ≤ -30 mV; silica-to-PS size ratio ≤0.078; and silica-to-PS mass ratio of about 0.50). The investigation of the self-assembly parameter landscape was also completed using geometric considerations. Because optimization of these parameters provides significant information in regard to practical uses, results of this report could be relevant to other functional properties.

  17. Compaction by impact of unconsolidated lunar fines

    NASA Technical Reports Server (NTRS)

    Ahrens, T. J.

    1975-01-01

    New Hugoniot and release adiabat data for 1.8 g/cu cm lunar fines in the approximately 2 to 70 kbar range demonstrate that upon shock compression intrinsic crystal density (approximately 3.1 g/cu cm) is achieved under shock stress of 15 to 20 kbar. Release adiabat determinations indicate that measurable irreversible compaction occurs upon achieving shock pressures above approximately 4 kbar. For shocks in the approximately 7 to 15 kbar range, the inferred post-shock specific volumes observed decrease nearly linearly with increasing peak shock pressures. Upon shocking to approximately 15 kbar the post-shock density is approximately that of the intrinsic minerals. If the present data are taken to be representative of the response to impact of unconsolidated regolith material on the moon, it is inferred that the formation of appreciable quantities of soil breccia can be associated with the impact of meteoroids or ejecta at speeds as low as approximately 1 km/sec.

  18. On the influence of frequency-dependent elastic properties in vibro-acoustic modelling of porous materials under structural excitation

    NASA Astrophysics Data System (ADS)

    Van der Kelen, C.; Göransson, P.; Pluymers, B.; Desmet, W.

    2014-12-01

    The aspects related to modelling the frequency dependence of the elastic properties of air-saturated porous materials have been largely neglected in the past for several reasons. For acoustic excitation of porous materials, the material behaviour can be quite well represented by models where the properties of the solid frame have little influence. Only recently has the importance of the dynamic moduli of the frame come into focus. This is related to a growing interest in the material behaviour due to structural excitation. Two aspects stand out in connection with the elastic-dynamic behaviour. The first is related to methods for the characterisation of the dynamic moduli of porous materials. The second is a perceived lack of numerical methods able to model the complex material behaviour under structural excitation, in particular at higher frequencies. In the current paper, experimental data from a panel under structural excitation, coated with a porous material, are presented. In an attempt to correlate the experimental data to numerical predictions, it is found that the measured quasi-static material parameters do not suffice for an accurate prediction of the measured results. The elastic material parameters are then estimated by correlating the numerical prediction to the experimental data, following the physical behaviour predicted by the augmented Hooke's law. The change in material behaviour due to the frequency-dependent properties is illustrated in terms of the propagation of the slow wave and the shear wave in the porous material.

  19. Imbedded-Fracture Formulation of THMC Processes in Fractured Media

    NASA Astrophysics Data System (ADS)

    Yeh, G. T.; Tsai, C. H.; Sung, R.

    2016-12-01

    Fractured media consist of porous materials and fracture networks. There exist four approaches to mathematically formulating THMC (Thermal-Hydrology-Mechanics-Chemistry) processes models in the system: (1) Equivalent Porous Media, (2) Dual Porosity or Dual Continuum, (3) Heterogeneous Media, and (4) Discrete Fracture Network. The first approach cannot explicitly explore the interactions between porous materials and fracture networks. The second approach introduces too many extra parameters (namely, exchange coefficients) between two media. The third approach may make the problems too stiff because the order of material heterogeneity may be too much. The fourth approach ignore the interaction between porous materials and fracture networks. This talk presents an alternative approach in which fracture networks are modeled with a lower dimension than the surrounding porous materials. Theoretical derivation of mathematical formulations will be given. An example will be illustrated to show the feasibility of this approach.

  20. Fabrication of Porous Ceramic-Geopolymer Based Material to Improve Water Absorption and Retention in Construction Materials: A Review

    NASA Astrophysics Data System (ADS)

    Jamil, N. H.; Ibrahim, W. M. A. W.; Abdullah, M. M. A. B.; Sandu, A. V.; Tahir, M. F. M.

    2017-06-01

    Porous ceramic nowadays has been investigated for a variety of its application such as filters, lightweight structural component and others due to their specific properties such as high surface area, stability and permeability. Besides, it has the properties of low thermal conductivity. Various formation techniques making these porous ceramic properties can be tailored or further fine-tuned to obtain the optimum characteristic. Porous materials also one of the good candidate for absorption properties. Conventional construction materials are not design to have good water absorption and retention that lead to the poor performance on these criteria. Temperature is a major driving force for moisture movement and influences sorption characteristics of many constructions materials. The effect of elevated temperatures on the water absorption coefficient and retention remain as critical issue that need to be investigated. Therefore, this paper will review the process parameters in fabricating porous ceramic for absorption properties.

  1. Sound absorption of a porous material with a perforated facing at high sound pressure levels

    NASA Astrophysics Data System (ADS)

    Peng, Feng

    2018-07-01

    A semi-empirical model is proposed to predict the sound absorption of an acoustical unit consisting of a rigid-porous material layer with a perforated facing under the normal incidence at high sound pressure levels (SPLs) of pure tones. The nonlinearity of the perforated facing and the porous material, and the interference between them are considered in the model. The sound absorptive performance of the acoustical unit is tested at different incident SPLs and in three typical configurations: 1) when the perforated panel (PP) directly contacts with the porous layer, 2) when the PP is separated from the porous layer by an air gap and 3) when an air cavity is set between the porous material and the hard backing wall. The test results agree well with the corresponding theoretical predictions. Moreover, the results show that the interference effect is correlated to the width of the air gap between the PP and the porous layer, which alters not only the linear acoustic impedance but also the nonlinear acoustic impedance of the unit and hence its sound absorptive properties.

  2. Porous Inorganic Drug Delivery Systems-a Review.

    PubMed

    Sayed, E; Haj-Ahmad, R; Ruparelia, K; Arshad, M S; Chang, M-W; Ahmad, Z

    2017-07-01

    Innovative methods and materials have been developed to overcome limitations associated with current drug delivery systems. Significant developments have led to the use of a variety of materials (as excipients) such as inorganic and metallic structures, marking a transition from conventional polymers. Inorganic materials, especially those possessing significant porosity, are emerging as good candidates for the delivery of a range of drugs (antibiotics, anticancer and anti-inflammatories), providing several advantages in formulation and engineering (encapsulation of drug in amorphous form, controlled delivery and improved targeting). This review focuses on key selected developments in porous drug delivery systems. The review provides a short broad overview of porous polymeric materials for drug delivery before focusing on porous inorganic materials (e.g. Santa Barbara Amorphous (SBA) and Mobil Composition of Matter (MCM)) and their utilisation in drug dosage form development. Methods for their preparation and drug loading thereafter are detailed. Several examples of porous inorganic materials, drugs used and outcomes are discussed providing the reader with an understanding of advances in the field and realistic opportunities.

  3. On the sensitivity analysis of porous material models

    NASA Astrophysics Data System (ADS)

    Ouisse, Morvan; Ichchou, Mohamed; Chedly, Slaheddine; Collet, Manuel

    2012-11-01

    Porous materials are used in many vibroacoustic applications. Different available models describe their behaviors according to materials' intrinsic characteristics. For instance, in the case of porous material with rigid frame, and according to the Champoux-Allard model, five parameters are employed. In this paper, an investigation about this model sensitivity to parameters according to frequency is conducted. Sobol and FAST algorithms are used for sensitivity analysis. A strong parametric frequency dependent hierarchy is shown. Sensitivity investigations confirm that resistivity is the most influent parameter when acoustic absorption and surface impedance of porous materials with rigid frame are considered. The analysis is first performed on a wide category of porous materials, and then restricted to a polyurethane foam analysis in order to illustrate the impact of the reduction of the design space. In a second part, a sensitivity analysis is performed using the Biot-Allard model with nine parameters including mechanical effects of the frame and conclusions are drawn through numerical simulations.

  4. Pore-scale Investigation of Surfactant Induced Mobilization for the Remediation of LNAPL

    NASA Astrophysics Data System (ADS)

    Ghosh, J.; Tick, G. R.

    2011-12-01

    The presence of nonaqueous phase liquids within the subsurface can significantly limit the effectiveness of groundwater remediation. Specifically, light nonaqueous phase liquids (LNAPLs) present unique challenges as they can become "smeared" within zones above and below the water table. The aim of this research is to understand the interfacial phenomena at the pore scale influencing residual saturation of LNAPL distribution as function of media heterogeneity and remediation processes from various aquifer systems. A series of columns were packed with three types of unconsolidated sand of increasing heterogeneity in grain size distribution and were established with residual saturations of light and heavy crude oil fractions, respectively. These columns were then subjected to flooding with 0.1% anionic surfactant solution in various episodes to initiate mobilization and enhanced recovery of NAPL phase contamination. Synchrotron X-ray microtomography (SXM) imaging technology was used to study three-dimensional (3-D) distributions of crude-oil-blobs before and after sequential surfactant flooding events. Results showed that LNAPL blob distributions became more heterogeneous after each subsequent surfactant flooding episode for all porous-media systems. NAPL recovery was most effective from the homogenous porous medium whereby 100% recovery resulted after 5 pore volumes (PVs) of flushing. LNAPL within the mildly heterogeneous porous medium produced a limited but consistent reduction in saturation after each surfactant flooding episode (23% and 43% recovery for light and heavy after the 5-PV flood). The highly heterogeneous porous medium showed greater NAPL recovery potential (42% and 16% for light and heavy) only after multiple pore volumes of flushing, at which point the NAPL blobs become fragmented into the smaller fragments in response to the reduced interfacial tension. The heterogeneity of the porous media (i.e. grain-size distribution) was a dominant control on the NAPL-blob-size-distribution trapped as residual saturation. The mobility of the NAPL blobs, as a result of surfactant flooding, was primarily controlled by the relative permeability of the medium and the reduction of interfacial tension between the wetting phase (water) and NAPL phase.

  5. Electronically and ionically conductive porous material and method for manufacture of resin wafers therefrom

    DOEpatents

    Lin, YuPo J [Naperville, IL; Henry, Michael P [Batavia, IL; Snyder, Seth W [Lincolnwood, IL

    2011-07-12

    An electrically and ionically conductive porous material including a thermoplastic binder and one or more of anion exchange moieties or cation exchange moieties or mixtures thereof and/or one or more of a protein capture resin and an electrically conductive material. The thermoplastic binder immobilizes the moieties with respect to each other but does not substantially coat the moieties and forms the electrically conductive porous material. A wafer of the material and a method of making the material and wafer are disclosed.

  6. Random-walk diffusion and drying of porous materials

    NASA Astrophysics Data System (ADS)

    Mehrafarin, M.; Faghihi, M.

    2001-12-01

    Based on random-walk diffusion, a microscopic model for drying is proposed to explain the characteristic features of the drying-rate curve of porous materials. The constant drying-rate period is considered as a normal diffusion process. The transition to the falling-rate regime is attributed to the fractal nature of porous materials which results in crossover to anomalous diffusion.

  7. Analysis of variability in additive manufactured open cell porous structures.

    PubMed

    Evans, Sam; Jones, Eric; Fox, Pete; Sutcliffe, Chris

    2017-06-01

    In this article, a novel method of analysing build consistency of additively manufactured open cell porous structures is presented. Conventionally, methods such as micro computed tomography or scanning electron microscopy imaging have been applied to the measurement of geometric properties of porous material; however, high costs and low speeds make them unsuitable for analysing high volumes of components. Recent advances in the image-based analysis of open cell structures have opened up the possibility of qualifying variation in manufacturing of porous material. Here, a photogrammetric method of measurement, employing image analysis to extract values for geometric properties, is used to investigate the variation between identically designed porous samples measuring changes in material thickness and pore size, both intra- and inter-build. Following the measurement of 125 samples, intra-build material thickness showed variation of ±12%, and pore size ±4% of the mean measured values across five builds. Inter-build material thickness and pore size showed mean ranges higher than those of intra-build, ±16% and ±6% of the mean material thickness and pore size, respectively. Acquired measurements created baseline variation values and demonstrated techniques suitable for tracking build deviation and inspecting additively manufactured porous structures to indicate unwanted process fluctuations.

  8. Drag Measurements of Porous Plate Acoustic Liners

    NASA Technical Reports Server (NTRS)

    Wolter, John D.

    2005-01-01

    This paper presents the results of direct drag measurements on a variety of porous plate acoustic liners. The existing literature describes numerous studies of drag on porous walls with injection or suction, but relatively few of drag on porous plates with neither injection nor suction. Furthermore, the porosity of the porous plate in existing studies is much lower than typically used in acoustic liners. In the present work, the acoustic liners consisted of a perforated face sheet covering a bulk acoustic absorber material. Factors that were varied in the experiment were hole diameter, hole pattern, face sheet thickness, bulk material type, and size of the gap (if any) between the face sheet and the absorber material.

  9. Isolated and modulated effects of topology and material type on the mechanical properties of additively manufactured porous biomaterials.

    PubMed

    Hedayati, R; Ahmadi, S M; Lietaert, K; Pouran, B; Li, Y; Weinans, H; Rans, C D; Zadpoor, A A

    2018-03-01

    In this study, we tried to quantify the isolated and modulated effects of topological design and material type on the mechanical properties of AM porous biomaterials. Towards this aim, we assembled a large dataset comprising the mechanical properties of AM porous biomaterials with different topological designs (i.e. different unit cell types and relative densities) and material types. Porous structures were additively manufactured from Co-Cr using a selective laser melting (SLM) machine and tested under quasi-static compression. The normalized mechanical properties obtained from those structures were compared with mechanical properties available from our previous studies for porous structures made from Ti-6Al-4V and pure titanium as well as with analytical solutions. The normalized values of elastic modulus and yield stress were found to be relatively close to each other as well as in agreement with analytical solutions regardless of material type. However, the material type was found to systematically affect the mechanical properties of AM porous biomaterials in general and the post-elastic/post-yield range (plateau stress and energy absorption capacity) in particular. To put this in perspective, topological design could cause up to 10-fold difference in the mechanical properties of AM porous biomaterials while up to 2-fold difference was observed as a consequence of changing the material type. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Contaminant Flux Reduction Barriers for Managing Difficult to Treat Source Zones in Unconsolidated Media

    DTIC Science & Technology

    2017-06-20

    39  Table 7.4:  Description of Case Study Site... Research Flux Reduction Materials: Several novel silica gel/vegetable oil- formulations were developed and tested in lab-scale batch and column studies by...Demonstration Results The project demonstration had these results:  Two grout mixtures were selected based on gel tests and a treatability study by

  11. A semi-empirical model relating micro structure to acoustic properties of bimodal porous material

    NASA Astrophysics Data System (ADS)

    Mosanenzadeh, Shahrzad Ghaffari; Doutres, Olivier; Naguib, Hani E.; Park, Chul B.; Atalla, Noureddine

    2015-01-01

    Complex morphology of open cell porous media makes it difficult to link microstructural parameters and acoustic behavior of these materials. While morphology determines the overall sound absorption and noise damping effectiveness of a porous structure, little is known on the influence of microstructural configuration on the macroscopic properties. In the present research, a novel bimodal porous structure was designed and developed solely for modeling purposes. For the developed porous structure, it is possible to have direct control on morphological parameters and avoid complications raised by intricate pore geometries. A semi-empirical model is developed to relate microstructural parameters to macroscopic characteristics of porous material using precise characterization results based on the designed bimodal porous structures. This model specifically links macroscopic parameters including static airflow resistivity ( σ ) , thermal characteristic length ( Λ ' ) , viscous characteristic length ( Λ ) , and dynamic tortuosity ( α ∞ ) to microstructural factors such as cell wall thickness ( 2 t ) and reticulation rate ( R w ) . The developed model makes it possible to design the morphology of porous media to achieve optimum sound absorption performance based on the application in hand. This study makes the base for understanding the role of microstructural geometry and morphological factors on the overall macroscopic parameters of porous materials specifically for acoustic capabilities. The next step is to include other microstructural parameters as well to generalize the developed model. In the present paper, pore size was kept constant for eight categories of bimodal foams to study the effect of secondary porous structure on macroscopic properties and overall acoustic behavior of porous media.

  12. Synthesis and gas adsorption study of porous metal-organic framework materials

    NASA Astrophysics Data System (ADS)

    Mu, Bin

    Metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) have become the focus of intense study over the past decade due to their potential for advancing a variety of applications including air purification, gas storage, adsorption separations, catalysis, gas sensing, drug delivery, and so on. These materials have some distinct advantages over traditional porous materials such as the well-defined structures, uniform pore sizes, chemically functionalized sorption sites, and potential for postsynthetic modification, etc. Thus, synthesis and adsorption studies of porous MOFs have increased substantially in recent years. Among various prospective applications, air purification is one of the most immediate concerns, which has urgent requirements to improve current nuclear, biological, and chemical (NBC) filters involving commercial and military purposes. Thus, the major goal of this funded project is to search, synthesize, and test these novel hybrid porous materials for adsorptive removal of toxic industrial chemicals (TICs) and chemical warfare agents (CWAs), and to install the benchmark for new-generation NBC filters. The objective of this study is three-fold: (i) Advance our understanding of coordination chemistry by synthesizing novel MOFs and characterizing these porous coordination polymers; (ii) Evaluate porous MOF materials for gasadsorption applications including CO2 capture, CH4 storage, other light gas adsorption and separations, and examine the chemical and physical properties of these solid adsorbents including thermal stability and heat capacity of MOFs; (iii) Evaluate porous MOF materials for next-generation NBC filter media by adsorption breakthrough measurements of TICs on MOFs, and advance our understanding about structureproperty relationships of these novel adsorbents.

  13. Simultaneous Contact Sensing and Characterizing of Mechanical and Dynamic Heat Transfer Properties of Porous Polymeric Materials

    PubMed Central

    Yao, Bao-Guo; Peng, Yun-Liang; Zhang, De-Pin

    2017-01-01

    Porous polymeric materials, such as textile fabrics, are elastic and widely used in our daily life for garment and household products. The mechanical and dynamic heat transfer properties of porous polymeric materials, which describe the sensations during the contact process between porous polymeric materials and parts of the human body, such as the hand, primarily influence comfort sensations and aesthetic qualities of clothing. A multi-sensory measurement system and a new method were proposed to simultaneously sense the contact and characterize the mechanical and dynamic heat transfer properties of porous polymeric materials, such as textile fabrics in one instrument, with consideration of the interactions between different aspects of contact feels. The multi-sensory measurement system was developed for simulating the dynamic contact and psychological judgment processes during human hand contact with porous polymeric materials, and measuring the surface smoothness, compression resilience, bending and twisting, and dynamic heat transfer signals simultaneously. The contact sensing principle and the evaluation methods were presented. Twelve typical sample materials with different structural parameters were measured. The results of the experiments and the interpretation of the test results were described. An analysis of the variance and a capacity study were investigated to determine the significance of differences among the test materials and to assess the gage repeatability and reproducibility. A correlation analysis was conducted by comparing the test results of this measurement system with the results of Kawabata Evaluation System (KES) in separate instruments. This multi-sensory measurement system provides a new method for simultaneous contact sensing and characterizing of mechanical and dynamic heat transfer properties of porous polymeric materials. PMID:29084152

  14. Simultaneous Contact Sensing and Characterizing of Mechanical and Dynamic Heat Transfer Properties of Porous Polymeric Materials.

    PubMed

    Yao, Bao-Guo; Peng, Yun-Liang; Zhang, De-Pin

    2017-10-30

    Porous polymeric materials, such as textile fabrics, are elastic and widely used in our daily life for garment and household products. The mechanical and dynamic heat transfer properties of porous polymeric materials, which describe the sensations during the contact process between porous polymeric materials and parts of the human body, such as the hand, primarily influence comfort sensations and aesthetic qualities of clothing. A multi-sensory measurement system and a new method were proposed to simultaneously sense the contact and characterize the mechanical and dynamic heat transfer properties of porous polymeric materials, such as textile fabrics in one instrument, with consideration of the interactions between different aspects of contact feels. The multi-sensory measurement system was developed for simulating the dynamic contact and psychological judgment processes during human hand contact with porous polymeric materials, and measuring the surface smoothness, compression resilience, bending and twisting, and dynamic heat transfer signals simultaneously. The contact sensing principle and the evaluation methods were presented. Twelve typical sample materials with different structural parameters were measured. The results of the experiments and the interpretation of the test results were described. An analysis of the variance and a capacity study were investigated to determine the significance of differences among the test materials and to assess the gage repeatability and reproducibility. A correlation analysis was conducted by comparing the test results of this measurement system with the results of Kawabata Evaluation System (KES) in separate instruments. This multi-sensory measurement system provides a new method for simultaneous contact sensing and characterizing of mechanical and dynamic heat transfer properties of porous polymeric materials.

  15. Electron beam selectively seals porous metal filters

    NASA Technical Reports Server (NTRS)

    Snyder, J. A.; Tulisiak, G.

    1968-01-01

    Electron beam welding selectively seals the outer surfaces of porous metal filters and impedances used in fluid flow systems. The outer surface can be sealed by melting a thin outer layer of the porous material with an electron beam so that the melted material fills all surface pores.

  16. Semi-solid electrode cell having a porous current collector and methods of manufacture

    DOEpatents

    Chiang, Yet-Ming; Carter, William Craig; Cross, III, James C.; Bazzarella, Ricardo; Ota, Naoki

    2017-11-21

    An electrochemical cell includes an anode, a semi-solid cathode, and a separator disposed therebetween. The semi-solid cathode includes a porous current collector and a suspension of an active material and a conductive material disposed in a non-aqueous liquid electrolyte. The porous current collector is at least partially disposed within the suspension such that the suspension substantially encapsulates the porous current collector.

  17. Porous polymer networks and ion-exchange media and metal-polymer composites made therefrom

    DOEpatents

    Kanatzidis, Mercouri G; Katsoulidis, Alexandros

    2015-03-10

    Porous polymeric networks and composite materials comprising metal nanoparticles distributed in the polymeric networks are provided. Also provided are methods for using the polymeric networks and the composite materials in liquid- and vapor-phase waste remediation applications. The porous polymeric networks, are highly porous, three-dimensional structures characterized by high surface areas. The polymeric networks comprise polymers polymerized from aldehydes and phenolic molecules.

  18. Porous polymer networks and ion-exchange media and metal-polymer composites made therefrom

    DOEpatents

    Kanatzidis, Mercouri G.; Katsoulidis, Alexandros

    2016-10-18

    Porous polymeric networks and composite materials comprising metal nanoparticles distributed in the polymeric networks are provided. Also provided are methods for using the polymeric networks and the composite materials in liquid- and vapor-phase waste remediation applications. The porous polymeric networks, are highly porous, three-dimensional structures characterized by high surface areas. The polymeric networks comprise polymers polymerized from aldehydes and phenolic molecules.

  19. Revival of pure titanium for dynamically loaded porous implants using additive manufacturing.

    PubMed

    Wauthle, Ruben; Ahmadi, Seyed Mohammad; Amin Yavari, Saber; Mulier, Michiel; Zadpoor, Amir Abbas; Weinans, Harrie; Van Humbeeck, Jan; Kruth, Jean-Pierre; Schrooten, Jan

    2015-09-01

    Additive manufacturing techniques are getting more and more established as reliable methods for producing porous metal implants thanks to the almost full geometrical and mechanical control of the designed porous biomaterial. Today, Ti6Al4V ELI is still the most widely used material for porous implants, and none or little interest goes to pure titanium for use in orthopedic or load-bearing implants. Given the special mechanical behavior of cellular structures and the material properties inherent to the additive manufacturing of metals, the aim of this study is to investigate the properties of selective laser melted pure unalloyed titanium porous structures. Therefore, the static and dynamic compressive properties of pure titanium structures are determined and compared to previously reported results for identical structures made from Ti6Al4V ELI and tantalum. The results show that porous Ti6Al4V ELI still remains the strongest material for statically loaded applications, whereas pure titanium has a mechanical behavior similar to tantalum and is the material of choice for cyclically loaded porous implants. These findings are considered to be important for future implant developments since it announces a potential revival of the use of pure titanium for additively manufactured porous implants. Copyright © 2015 Elsevier B.V. All rights reserved.

  20. Porous silicon photonic crystals as hosts for polymers, biopolymers, and magnetic nanoparticles

    NASA Astrophysics Data System (ADS)

    Li, Yang Yang

    This thesis describes the construction of one-dimensional photonic crystals of porous silicon by electrochemically etching and the use of these materials as hosts for polymers, biopolymers, and magnetic nanoparticles. The spectral features of the photonic crystals derive from a porosity gradient that is determined by the electrochemical etching parameters. Since the photonic crystals are constructed of a porous material, they can serve as hosts for other materials. The first chapter of the thesis provides an introduction to porous Si, templating techniques and the use of porous materials for controlled release of drugs. This latter section is added because much of the thesis work addresses the application of porous Si hosts for controlled release of drugs. In the second chapter, it is shown that the spectral properties of the porous Si photonic crystal template can be transferred to a variety of organic and biopolymers. It is demonstrated that these castings can be used as vapor sensors and as self-reporting, bioresorbable materials. If the template is not removed, porous Si polymer composites are formed. The third chapter discussed that by spray-coating a fine mist of polymer solution onto the porous Si film, robust and smooth micron-sized cylindrical photonic crystals suitable for bioassays can be prepared. The fourth chapter focuses on using porous Si photonic crystals as a host for magnetic nanoparticles. The magnetic nanoparticles in this work are found to adhere to the surface of the porous Si film as well to infiltrate the pore structure. In a demonstration of optical switching that may be useful for information display applications, flipping between the colored to dark sides by application of a magnetic field is found to occur at rates of as large as 175 Hz. As the host for soluble molecular species, porous Si photonic crystals can be impregnated from solution. The aggregates that form upon evaporation of solvent are found to scatter light from the resonant optical structure over a large solid angle. The spectrum of the scattered light provides a convenient means of monitoring the temporal release characteristics of the guest material. An application of the phenomenon is demonstrated for release of a drug (caffeine) into aqueous solution from a porous Si photonic crystal.

  1. Cermet materials

    DOEpatents

    Kong, Peter C [Idaho Falls, ID

    2008-12-23

    A self-cleaning porous cermet material, filter and system utilizing the same may be used in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The porous cermet filter may be made from a transition metal aluminide phase and an alumina phase. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The porous filter may also be electrically conductive so that a current may be passed therethrough to heat the filter during use. Further, a heating element may be incorporated into the porous cermet filter during manufacture. This heating element can be coated with a ceramic material to electrically insulate the heating element. An external heating element may also be provided to heat the cermet filter during use.

  2. New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun

    Porous materials have already manifested their unique properties in a number of fields. Generally, all porous materials are in a solid state other than liquid, in which molecules are closely packed without porosity. “Porous” and “liquid” seem like antonyms. In this paper, we report a new class of Type 3 porous liquids based on rational coupling of microporous framework nanoparticles as porous hosts with a bulky ionic liquid as the fluid media. Positron annihilation lifetime spectroscopy (PALS) and CO 2 adsorption measurements confirm the successful engineering of permanent porosity into these liquids. Compared to common porous solid materials, as-synthesized porousmore » liquids exhibited pronounced hysteresis loops in the CO 2 sorption isotherms even at ambient conditions (298 K, 1 bar). Finally, the unique features of these novel porous liquids could bring new opportunities in many fields including gas separation and storage, air separation and regeneration, gas transport, and permanent gas storage at ambient conditions.« less

  3. New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior

    DOE PAGES

    Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun; ...

    2017-12-26

    Porous materials have already manifested their unique properties in a number of fields. Generally, all porous materials are in a solid state other than liquid, in which molecules are closely packed without porosity. “Porous” and “liquid” seem like antonyms. In this paper, we report a new class of Type 3 porous liquids based on rational coupling of microporous framework nanoparticles as porous hosts with a bulky ionic liquid as the fluid media. Positron annihilation lifetime spectroscopy (PALS) and CO 2 adsorption measurements confirm the successful engineering of permanent porosity into these liquids. Compared to common porous solid materials, as-synthesized porousmore » liquids exhibited pronounced hysteresis loops in the CO 2 sorption isotherms even at ambient conditions (298 K, 1 bar). Finally, the unique features of these novel porous liquids could bring new opportunities in many fields including gas separation and storage, air separation and regeneration, gas transport, and permanent gas storage at ambient conditions.« less

  4. Ventilation of porous media

    DOEpatents

    Neeper, Donald A.

    1994-01-01

    Methods for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction.

  5. Experimental analysis of the flow near the boundary of random porous media

    NASA Astrophysics Data System (ADS)

    Wu, Zhenxing; Mirbod, Parisa

    2018-04-01

    The aim of this work is to experimentally examine flow over and near random porous media. Different porous materials were chosen to achieve porosity ranging from 0.95 to 0.99. In this study, we report the detailed velocity measurements of the flow over and near random porous material inside a rectangular duct using a planar particle image velocimetry (PIV) technique. By controlling the flow rate, two different Reynolds numbers were achieved. We determined the slip velocity at the interface between the porous media and free flow. Values of the slip velocity normalized either by the maximum flow velocity or by the shear rate at the interface and the screening distance K1/2 were found to depend on porosity. It was also shown that the depth of penetration inside the porous material was larger than the screening length using Brinkman's prediction. Moreover, we examined a model for the laminar coupled flow over and inside porous media and analyzed the permeability of a random porous medium. This study provided detailed analysis of flow over and at the interface of various specific random porous media using the PIV technique. This analysis has the potential to serve as a first step toward using random porous media as a new passive technique to control the flow over smooth surfaces.

  6. Protein adsorption onto nanozeolite: effect of micropore openings.

    PubMed

    Wu, Jiamin; Li, Xiang; Yan, Yueer; Hu, Yuanyuan; Zhang, Yahong; Tang, Yi

    2013-09-15

    A clear and deep understanding of protein adsorption on porous surfaces is desirable for the reasonable design and applications of porous materials. In this study, the effect of surface micropores on protein adsorption was systematically investigated by comparing adsorption behavior of cytochrome c (Cyto-c) and Candida antarctica Lipase B (CALB) on porous and non-porous nanozeolites silicalite-1 and Beta. It was found that micropore openings on the surface of nanozeolites played a key role in determining adsorption affinity, conformations, and activities of proteins. Both Cyto-c and CALB showed higher affinity to porous nanozeolites than to non-porous ones, resulting in greater conformational change of proteins on porous surfaces which in turn affected their bio-catalytic performance. The activity of Cyto-c improved while that of CALB decreased on porous nanozeolites. Recognition of certain amino acid residues or size-matching secondary structures by micropore openings on the surface of nanozeolites was proposed to be the reason. Moreover, the pore opening effect of porous nanozeolites on protein behavior could be altered by changing protein coverage on them. This study gives a novel insight into the interaction between proteins and microporous materials, which will help to guide the rational fabrication and bio-applications of porous materials in the future. Copyright © 2013 Elsevier Inc. All rights reserved.

  7. Advances in Porous Biomaterials for Dental and Orthopaedic Applications

    PubMed Central

    Mour, Meenakshi; Das, Debarun; Winkler, Thomas; Hoenig, Elisa; Mielke, Gabriela; Morlock, Michael M.; Schilling, Arndt F.

    2010-01-01

    The connective hard tissues bone and teeth are highly porous on a micrometer scale, but show high values of compression strength at a relatively low weight. The fabrication of porous materials has been actively researched and different processes have been developed that vary in preparation complexity and also in the type of porous material that they produce. Methodologies are available for determination of pore properties. The purpose of the paper is to give an overview of these methods, the role of porosity in natural porous materials and the effect of pore properties on the living tissues. The minimum pore size required to allow the ingrowth of mineralized tissue seems to be in the order of 50 µm: larger pore sizes seem to improve speed and depth of penetration of mineralized tissues into the biomaterial, but on the other hand impair the mechanical properties. The optimal pore size is therefore dependent on the application and the used material.

  8. Non-destructive testing method for determining the solvent diffusion coefficient in the porous materials products

    NASA Astrophysics Data System (ADS)

    Belyaev, V. P.; Mishchenko, S. V.; Belyaev, P. S.

    2018-01-01

    Ensuring non-destructive testing of products in industry is an urgent task. Most of the modern methods for determining the diffusion coefficient in porous materials have been developed for bodies of a given configuration and size. This leads to the need for finished products destruction to make experimental samples from them. The purpose of this study is the development of a dynamic method that allows operatively determine the diffusion coefficient in finished products from porous materials without destroying them. The method is designed to investigate the solvents diffusion coefficient in building constructions from materials having a porous structure: brick, concrete and aerated concrete, gypsum, cement, gypsum or silicate solutions, gas silicate blocks, heat insulators, etc. A mathematical model of the method is constructed. The influence of the design and measuring device operating parameters on the method accuracy is studied. The application results of the developed method for structural porous products are presented.

  9. Mechanical Clogging Processes in Unconsolidated Porous Media Near Pumping Wells

    NASA Astrophysics Data System (ADS)

    de Zwart, B.; Schotting, R.; Hassanizadeh, M.

    2003-12-01

    In the Netherlands water supply companies produce over more than one billion cubic meters of drinking water every year. About 2500 water wells are used to pump up the groundwater from aquifers in the Dutch subsurface. More than 50% of these wells will encounter a number of technical problems during their lifetime. The main problem is the decrease in capacity due to well clogging. Clogging shows up after a number of operation years and results in extra, expensive cleaning operations and in early replacement of the pumping wells. This problem has been acknowledged by other industries, for example the metal, petroleum, beer industry and underground storage projects. Well clogging is the result of a number of interacting mechanisms creating a complex problem in the subsurface. In most clogging cases mechanical mechanisms are involved. A large number of studies have been performed to comprehend these processes. Investigations on mechanical processes are focused on transport of small particles through pores and deposition of particles due to physical or physical-chemical processes. After a period of deposition the particles plug the pores and decrease the permeability of the medium. Particle deposition in porous media is usually modelled using filtration theory. In order to get the dynamics of clogging this theory is not sufficient. The porous media is continuously altered due to deposition and mobilization. Therefore the capture characteristics will also continuously change and deposition rates will change in time. A new formula is derived to describe (re)mobilization of particles and allow changing deposition rates. This approach incorporates detachment and reattachment of deposited particles. This work also includes derivation of the filtration theory in radial coordinates. A comparison between the radial filtration theory and the new formula will be shown.

  10. Non-Darcian flow of shear-thinning fluids through packed beads: Experiments and predictions using Forchheimer's law and Ergun's equation

    NASA Astrophysics Data System (ADS)

    Rodríguez de Castro, Antonio; Radilla, Giovanni

    2017-02-01

    The flow of shear-thinning fluids through unconsolidated porous media is present in a number of important industrial applications such as soil depollution, Enhanced Oil Recovery or filtration of polymeric liquids. Therefore, predicting the pressure drop-flow rate relationship in model porous media has been the scope of major research efforts during the last decades. Although the flow of Newtonian fluids through packs of spherical particles is well understood in most cases, much less is known regarding the flow of shear-thinning fluids as high molecular weight polymer aqueous solutions. In particular, the experimental data for the non-Darcian flow of shear-thinning fluids are scarce and so are the current approaches for their prediction. Given the relevance of non-Darcian shear-thinning flow, the scope of this work is to perform an experimental study to systematically evaluate the effects of fluid shear rheology on the flow rate-pressure drop relationships for the non-Darcian flow through different packs of glass spheres. To do so, xanthan gum aqueous solutions with different polymer concentrations are injected through four packs of glass spheres with uniform size under Darcian and inertial flow regimes. A total of 1560 experimental data are then compared with predictions coming from different methods based on the extension of widely used Ergun's equation and Forchheimer's law to the case of shear thinning fluids, determining the accuracy of these predictions. The use of a proper definition for Reynolds number and a realistic model to represent the rheology of the injected fluids results in the porous media are shown to be key aspects to successfully predict pressure drop-flow rate relationships for the inertial shear-thinning flow in packed beads.

  11. Synthetic microfluidic paper: high surface area and high porosity polymer micropillar arrays.

    PubMed

    Hansson, Jonas; Yasuga, Hiroki; Haraldsson, Tommy; van der Wijngaart, Wouter

    2016-01-21

    We introduce Synthetic Microfluidic Paper, a novel porous material for microfluidic applications that consists of an OSTE polymer that is photostructured in a well-controlled geometry of slanted and interlocked micropillars. We demonstrate the distinct benefits of Synthetic Microfluidic Paper over other porous microfluidic materials, such as nitrocellulose, traditional paper and straight micropillar arrays: in contrast to straight micropillar arrays, the geometry of Synthetic Microfluidic Paper was miniaturized without suffering capillary collapse during manufacturing and fluidic operation, resulting in a six-fold increased internal surface area and a three-fold increased porous fraction. Compared to commercial nitrocellulose materials for capillary assays, Synthetic Microfluidic Paper shows a wider range of capillary pumping speed and four times lower device-to-device variation. Compared to the surfaces of the other porous microfluidic materials that are modified by adsorption, Synthetic Microfluidic Paper contains free thiol groups and has been shown to be suitable for covalent surface chemistry, demonstrated here for increasing the material hydrophilicity. These results illustrate the potential of Synthetic Microfluidic Paper as a porous microfluidic material with improved performance characteristics, especially for bioassay applications such as diagnostic tests.

  12. Gas permeability of ice-templated, unidirectional porous ceramics.

    PubMed

    Seuba, Jordi; Deville, Sylvain; Guizard, Christian; Stevenson, Adam J

    2016-01-01

    We investigate the gas flow behavior of unidirectional porous ceramics processed by ice-templating. The pore volume ranged between 54% and 72% and pore size between 2.9 [Formula: see text]m and 19.1 [Formula: see text]m. The maximum permeability ([Formula: see text] [Formula: see text] m[Formula: see text]) was measured in samples with the highest total pore volume (72%) and pore size (19.1 [Formula: see text]m). However, we demonstrate that it is possible to achieve a similar permeability ([Formula: see text] [Formula: see text] m[Formula: see text]) at 54% pore volume by modification of the pore shape. These results were compared with those reported and measured for isotropic porous materials processed by conventional techniques. In unidirectional porous materials tortuosity ([Formula: see text]) is mainly controlled by pore size, unlike in isotropic porous structures where [Formula: see text] is linked to pore volume. Furthermore, we assessed the applicability of Ergun and capillary model in the prediction of permeability and we found that the capillary model accurately describes the gas flow behavior of unidirectional porous materials. Finally, we combined the permeability data obtained here with strength data for these materials to establish links between strength and permeability of ice-templated materials.

  13. Small-scale, self-propagating combustion realized with on-chip porous silicon.

    PubMed

    Piekiel, Nicholas W; Morris, Christopher J

    2015-05-13

    For small-scale energy applications, energetic materials represent a high energy density source that, in certain cases, can be accessed with a very small amount of energy input. Recent advances in microprocessing techniques allow for the implementation of a porous silicon energetic material onto a crystalline silicon wafer at the microscale; however, combustion at a small length scale remains to be fully investigated, particularly with regards to the limitations of increased relative heat loss during combustion. The present study explores the critical dimensions of an on-chip porous silicon energetic material (porous silicon + sodium perchlorate (NaClO4)) required to propagate combustion. We etched ∼97 μm wide and ∼45 μm deep porous silicon channels that burned at a steady rate of 4.6 m/s, remaining steady across 90° changes in direction. In an effort to minimize the potential on-chip footprint for energetic porous silicon, we also explored the minimum spacing between porous silicon channels. We demonstrated independent burning of porous silicon channels at a spacing of <40 μm. Using this spacing, it was possible to have a flame path length of >0.5 m on a chip surface area of 1.65 cm(2). Smaller porous silicon channels of ∼28 μm wide and ∼14 μm deep were also utilized. These samples propagated combustion, but at times, did so unsteadily. This result may suggest that we are approaching a critical length scale for self-propagating combustion in a porous silicon energetic material.

  14. A soft porous drop in linear flows

    NASA Astrophysics Data System (ADS)

    Young, Yuan-Nan; Miksis, Michael; Mori, Yoichiro; Shelley, Michael

    2017-11-01

    The cellular cytoplasm consists a viscous fluid filled with fibrous networks that also have their own dynamics. Such fluid-structure interactions have been modeled as a soft porous material immersed in a viscous fluid. In this talk we focus on the hydrodynamics of a viscous drop filled with soft porous material inside. Suspended in a Stokes flow, such a porous viscous drop is allowed to deform, both the drop interface and the porous structures inside. Special focus is on the deformation dynamics of both the porosity and the shape of the drop under simple flows such as a uniform streaming flow and linear flows. We examine the effects of flow boundary conditions at interface between the porous drop and the surrounding viscous fluid. We also examine the dynamics of a porous drop with active stress from the porous network.

  15. Influence of groundwater recharge and well characteristics on dissolved arsenic concentrations in southeastern Michigan groundwater

    USGS Publications Warehouse

    Meliker, J.R.; Slotnick, M.J.; Avruskin, G.A.; Haack, S.K.; Nriagu, J.O.

    2009-01-01

    Arsenic concentrations exceeding 10 ??g/l, the United States maximum contaminant level and the World Health Organization guideline value, are frequently reported in groundwater from bedrock and unconsolidated aquifers of southeastern Michigan. Although arsenic-bearing minerals (including arsenian pyrite and oxide/hydroxide phases) have been identified in Marshall Sandstone bedrock of the Mississippian aquifer system and in tills of the unconsolidated aquifer system, mechanisms responsible for arsenic mobilization and subsequent transport in groundwater are equivocal. Recent evidence has begun to suggest that groundwater recharge and characteristics of well construction may affect arsenic mobilization and transport. Therefore, we investigated the relationship between dissolved arsenic concentrations, reported groundwater recharge rates, well construction characteristics, and geology in unconsolidated and bedrock aquifers. Results of multiple linear regression analyses indicate that arsenic contamination is more prevalent in bedrock wells that are cased in proximity to the bedrock-unconsolidated interface; no other factors were associated with arsenic contamination in water drawn from bedrock or unconsolidated aquifers. Conditions appropriate for arsenic mobilization may be found along the bedrock-unconsolidated interface, including changes in reduction/oxidation potential and enhanced biogeochemical activity because of differences between geologic strata. These results are valuable for understanding arsenic mobilization and guiding well construction practices in southeastern Michigan, and may also provide insights for other regions faced with groundwater arsenic contamination. ?? Springer-Verlag 2008.

  16. Compiling and Mapping Global Permeability of the Unconsolidated and Consolidated Earth: GLobal HYdrogeology MaPS 2.0 (GLHYMPS 2.0)

    NASA Astrophysics Data System (ADS)

    Huscroft, Jordan; Gleeson, Tom; Hartmann, Jens; Börker, Janine

    2018-02-01

    The spatial distribution of subsurface parameters such as permeability are increasingly relevant for regional to global climate, land surface, and hydrologic models that are integrating groundwater dynamics and interactions. Despite the large fraction of unconsolidated sediments on Earth's surface with a wide range of permeability values, current global, high-resolution permeability maps distinguish solely fine-grained and coarse-grained unconsolidated sediments. Representative permeability values are derived for a wide variety of unconsolidated sediments and applied to a new global map of unconsolidated sediments to produce the first geologically constrained, two-layer global map of shallower and deeper permeability. The new mean logarithmic permeability of the Earth's surface is -12.7 ± 1.7 m2 being 1 order of magnitude higher than that derived from previous maps, which is consistent with the dominance of the coarser sediments. The new data set will benefit a variety of scientific applications including the next generation of climate, land surface, and hydrology models at regional to global scales.

  17. Sand Waves That Impede Navigation of Coastal Inlet Navigation Channels

    DTIC Science & Technology

    2006-08-01

    Merrymeeting Bay. The bay collects coarse-grained sediment from unconsolidated ice-contact and periglacial deposits (Fenster and FitzGerald 1996). During...bed, which is a layer of denser or larger sized sediment left after finer material has been winnowed by a strong current, can inhibit bed form...Order Descriptors (important) • Superposition: simple or compound. • Sediment Characteristics (size, sorting). Third Order Descriptors (useful

  18. Cermet materials, self-cleaning cermet filters, apparatus and systems employing same

    DOEpatents

    Kong, Peter C.

    2005-07-19

    A self-cleaning porous cermet material, filter and system utilizing the same may be used in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The porous cermet filter may be made from a transition metal aluminide phase and an alumina phase. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The porous filter may also be electrically conductive so that a current may be passed therethrough to heat the filter during use. Further, a heating element may be incorporated into the porous cermet filter during manufacture. This heating element can be coated with a ceramic material to electrically insulate the heating element. An external heating element may also be provided to heat the cermet filter during use.

  19. Modelling and Microstructural Characterization of Sintered Metallic Porous Materials

    PubMed Central

    Depczynski, Wojciech; Kazala, Robert; Ludwinek, Krzysztof; Jedynak, Katarzyna

    2016-01-01

    This paper presents selected characteristics of the metallic porous materials produced by the sintering of metal powders. The authors focus on materials produced from the iron powder (Fe) of ASC 100.29 and Distaloy SE. ASC 100.29 is formed by atomization and has a characteristic morphology. It consists of spherical particles of different sizes forming agglomerates. Distaloy SE is also based on the sponge-iron. The porous material is prepared using the patented method of sintering the mixture of iron powder ASC 100.29, Fe(III) oxide, Distaloy SE and Fe(III) oxide in the reducing atmosphere of dissociated ammonia. As a result, the materials with open pores of micrometer sizes are obtained. The pores are formed between iron particles bonded by diffusion bridges. The modelling of porous materials containing diffusion bridges that allows for three-dimensional (3D) imaging is presented. PMID:28773690

  20. The Importance of the Initial State in Understanding Shocked Porous Materials

    NASA Astrophysics Data System (ADS)

    Mattsson, Thomas R.; Cochrane, Kyle R.; Lane, J. Matthew D.; Weck, Philippe F.; Vogler, Tracy J.; Shulenburger, Luke

    Modeling the response of porous materials to shock loading presents a variety of theoretical challenges, however if done well it can open a whole new area of phase space for probing the equation of state of materials. Shocked porous materials achieve significantly hotter temperatures for the same drive than fully dense ones. By combining ab initio calculations of fully dense material with a model of porosity we show the critical importance of an accurate treatment of the initial state in understanding these experiments. This approach is also directly applicable to present application of tabular equations of state to the modeling of porous material. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  1. Development of a model to assess acoustic treatments to reduce railway noise

    NASA Astrophysics Data System (ADS)

    Jeong, H.; Squicciarini, G.; Thompson, D. J.; Ryue, J.

    2016-09-01

    Porous materials have recently been used in absorptive treatments around railway tracks to reduce noise emissions. To investigate the effect of porous materials, a finite element model has been developed. 2D models for porous materials have been considered either as an equivalent fluid or as a poroelastic material based on the Biot theory. The two models have been validated and compared with each other to check the effect of the skeleton vibration. The poroelastic FE model has been coupled with a 2D acoustic boundary element model for use in railway applications. The results show that it may be necessary to include the frame vibration, especially at low frequencies where a frame resonance occurs. A method for the characterization of porous materials is also discussed. From this it is shown that the elastic properties of the material determine the resonance frequency and the magnitude.

  2. Ventilation of porous media

    DOEpatents

    Neeper, D.A.

    1994-02-22

    Methods are presented for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction. 10 figures.

  3. Incomparable hardness and modulus of biomimetic porous polyurethane films prepared by directional melt crystallization of a solvent

    NASA Astrophysics Data System (ADS)

    An, Suyeong; Kim, Byoungsoo; Lee, Jonghwi

    2017-07-01

    Porous materials with surprisingly diverse structures have been utilized in nature for many functional purposes. However, the structures and applications of porous man-made polymer materials have been limited by the use of processing techniques involving foaming agents. Herein, we demonstrate for the first time the outstanding hardness and modulus properties of an elastomer that originate from the novel processing approach applied. Polyurethane films of 100-μm thickness with biomimetic ordered porous structures were prepared using directional melt crystallization of a solvent and exhibited hardness and modulus values that were 6.8 and 4.3 times higher than those of the random pore structure, respectively. These values surpass the theoretical prediction of the typical model for porous materials, which works reasonably well for random pores but not for directional pores. Both the ordered and random pore structures exhibited similar porosities and pore sizes, which decreased with increasing solution concentration. This unexpectedly significant improvement of the hardness and modulus could open up new application areas for porous polymeric materials using this relatively novel processing technique.

  4. Proton conduction in metal-organic frameworks and related modularly built porous solids.

    PubMed

    Yoon, Minyoung; Suh, Kyungwon; Natarajan, Srinivasan; Kim, Kimoon

    2013-03-04

    Proton-conducting materials are an important component of fuel cells. Development of new types of proton-conducting materials is one of the most important issues in fuel-cell technology. Herein, we present newly developed proton-conducting materials, modularly built porous solids, including coordination polymers (CPs) or metal-organic frameworks (MOFs). The designable and tunable nature of the porous materials allows for fast development in this research field. Design and synthesis of the new types of proton-conducting materials and their unique proton-conduction properties are discussed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Mitigating leaks in membranes

    DOEpatents

    Karnik, Rohit N.; Bose, Suman; Boutilier, Michael S.H.; Hadjiconstantinou, Nicolas G.; Jain, Tarun Kumar; O'Hern, Sean C.; Laoui, Tahar; Atieh, Muataz A.; Jang, Doojoon

    2018-02-27

    Two-dimensional material based filters, their method of manufacture, and their use are disclosed. In one embodiment, a membrane may include an active layer including a plurality of defects and a deposited material associated with the plurality of defects may reduce flow therethrough. Additionally, a majority of the active layer may be free from the material. In another embodiment, a membrane may include a porous substrate and an atomic layer deposited material disposed on a surface of the porous substrate. The atomic layer deposited material may be less hydrophilic than the porous substrate and an atomically thin active layer may be disposed on the atomic layer deposited material.

  6. Root-growth-inhibiting sheet

    DOEpatents

    Burton, Frederick G.; Cataldo, Dominic A.; Cline, John F.; Skiens, W. Eugene; Van Voris, Peter

    1993-01-01

    In accordance with this invention, a porous sheet material is provided at intervals with bodies of a polymer which contain a 2,6-dinitroaniline. The sheet material is made porous to permit free passage of water. It may be either a perforated sheet or a woven or non-woven textile material. A particularly desirable embodiment is a non-woven fabric of non-biodegradable material. This type of material is known as a "geotextile" and is used for weed control, prevention of erosion on slopes, and other landscaping purposes. In order to obtain a root repelling property, a dinitroaniline is blended with a polymer which is attached to the geotextile or other porous material.

  7. Root-growth-inhibiting sheet

    DOEpatents

    Burton, F.G.; Cataldo, D.A.; Cline, J.F.; Skiens, W.E.; Van Voris, P.

    1993-01-26

    In accordance with this invention, a porous sheet material is provided at intervals with bodies of a polymer which contain a 2,6-dinitroaniline. The sheet material is made porous to permit free passage of water. It may be either a perforated sheet or a woven or non-woven textile material. A particularly desirable embodiment is a non-woven fabric of non-biodegradable material. This type of material is known as a geotextile'' and is used for weed control, prevention of erosion on slopes, and other landscaping purposes. In order to obtain a root repelling property, a dinitroaniline is blended with a polymer which is attached to the geotextile or other porous material.

  8. Computational materials chemistry for carbon capture using porous materials

    NASA Astrophysics Data System (ADS)

    Sharma, Abhishek; Huang, Runhong; Malani, Ateeque; Babarao, Ravichandar

    2017-11-01

    Control over carbon dioxide (CO2) release is extremely important to decrease its hazardous effects on the environment such as global warming, ocean acidification, etc. For CO2 capture and storage at industrial point sources, nanoporous materials offer an energetically viable and economically feasible approach compared to chemisorption in amines. There is a growing need to design and synthesize new nanoporous materials with enhanced capability for carbon capture. Computational materials chemistry offers tools to screen and design cost-effective materials for CO2 separation and storage, and it is less time consuming compared to trial and error experimental synthesis. It also provides a guide to synthesize new materials with better properties for real world applications. In this review, we briefly highlight the various carbon capture technologies and the need of computational materials design for carbon capture. This review discusses the commonly used computational chemistry-based simulation methods for structural characterization and prediction of thermodynamic properties of adsorbed gases in porous materials. Finally, simulation studies reported on various potential porous materials, such as zeolites, porous carbon, metal organic frameworks (MOFs) and covalent organic frameworks (COFs), for CO2 capture are discussed.

  9. Gas-Driven Fracturing of Saturated Granular Media

    NASA Astrophysics Data System (ADS)

    Campbell, James M.; Ozturk, Deren; Sandnes, Bjørnar

    2017-12-01

    Multiphase flows in deformable porous materials are important in numerous geological and geotechnical applications; however, the complex flow behavior makes subsurface transport processes difficult to control—or even characterize. Here, we study gas-driven (pneumatic) fracturing of a wet unconsolidated granular packing confined in a Hele-Shaw cell, and we present an in-depth analysis of both pore-scale phenomena and large-scale pattern formation. The process is governed by a complex interplay among pressure, capillary, frictional, and viscous forces. At low gas-injection rates, fractures grow in a stick-slip fashion and branch out to form a simply connected network. We observe the emergence of a characteristic length scale—the separation distance between fracture branches—creating an apparent uniform spatial fracture density. We conclude that the well-defined separation distance is the result of local compaction fronts surrounding fractures and keeping them apart. A scaling argument is presented that predicts fracture density as a function of granular friction, grain size, and capillary interactions. We study the influence of the gas-injection rate and find that the system undergoes a fluidization transition above a critical injection rate, resulting in directional growth of the fractures, and a fracture density that increases with an increasing rate. A dimensionless fluidization number F is defined as the ratio of viscous to frictional forces, and our experiments reveal a frictional regime for F <1 characterized by stick-slip, rate-independent growth, with a transition to a viscous regime (F >1 ) characterized by continuous growth in several fracture branches simultaneously.

  10. Glycol-modified silanes: novel possibilities for the synthesis of hierarchically organized (hybrid) porous materials.

    PubMed

    Hartmann, Sarah; Brandhuber, Doris; Hüsing, Nicola

    2007-09-01

    The preparation of porous hierarchical architectures that have structural features spanning from the nanometer to micrometer and even larger dimensions and that exhibit certain functionalities is one of the new challenging frontiers in materials chemistry. The sol-gel process is one of the most promising synthesis routes toward such materials because it not only offers the possibility to incorporate organic functions into the porous host but also offers the possibility to deliberately tailor the pore structure. In this Account, the opportunities given by the application of novel diol-modified silanes are discussed for the synthesis of hierarchically organized inorganic and also inorganic-organic porous monoliths.

  11. Composite oxygen transport membrane

    DOEpatents

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  12. Composite oxygen transport membrane

    DOEpatents

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2016-11-15

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  13. Sound Transmission Through Multi-Panel Structures Lined with Elastic Porous Materials

    NASA Astrophysics Data System (ADS)

    Bolton, J. S.; Shiau, N.-M.; Kang, Y. J.

    1996-04-01

    Theory and measurements related to sound transmission through double panels lined with elastic porous media are presented. The information has application to the design of noise control barriers and to the optimization of aircraft fuselage transmission loss, for example. The major difference between the work described here and earlier research in this field relates to the treatment of the porous material that is used to line the cavity between the two panels of the double panel structure. Here we have used the porous material theory proposed by Biot since it takes explicit account of all the wave types known to propagate in elastic porous materials. As a result, it is possible to use the theory presented here to calculate the transmission loss of lined double panels at arbitrary angles of incidence; results calculated over a range of incidence angles may then be combined to yield the random incidence transmission loss. In this paper, the equations governing wave propagation in an elastic porous material are first considered briefly and then the general forms for the stresses and displacements within the porous material are given. Those solutions are expressed in terms of a number of constants that can be determined by application of appropriate boundary conditions. The boundary conditions required to model double panels having linings that are either directly attached to the facing panels or separated?!from them by air gaps are presented and discussed. Measurements of the random incidence transmission loss of aluminium double-panel structures lined with polyurethane foam are presented and have been found to be in good agreement with theoretical predictions. Both the theoretical predictions and the measured results have shown that the method by which an elastic porous lining material is attached to the facing panels can have a profound influence on the transmission loss of the panel system. It has been found, for example, that treatments in which the lining material is not directly attached to the facing panels are generally to be preferred to those in which the lining is directly bonded to the panels. These effects may be explained by considering the degree to which the various wave types within the elastic porous material are excited, which in turn can be related to the method by which the lining is mounted to the facing panels.

  14. Morphology-dependent Electrochemical Enhancements of Porous Carbon as Sensitive Determination Platform for Ascorbic Acid, Dopamine and Uric Acid

    NASA Astrophysics Data System (ADS)

    Cheng, Qin; Ji, Liudi; Wu, Kangbing; Zhang, Weikang

    2016-02-01

    Using starch as the carbon precursor and different-sized ZnO naoparticles as the hard template, a series of porous carbon materials for electrochemical sensing were prepared. Experiments of scanning electron microscopy, transmission electron microscopy and Nitrogen adsorption-desorption isotherms reveal that the particle size of ZnO has big impacts on the porous morphology and surface area of the resulting carbon materials. Through ultrasonic dispersion of porous carbon and subsequent solvent evaporation, different sensing interfaces were constructed on the surface of glassy carbon electrode (GCE). The electrochemical behaviors of ascorbic acid (AA), dopamine (DA) and uric acid (UA) were studied. On the surface of porous carbon materials, the accumulation efficiency and electron transfer ability of AA, DA and UA are improved, and consequently their oxidation signals enhance greatly. Moreover, the interface enhancement effects of porous carbon are also controlled by the particle size of hard template. The constructed porous carbon interface displays strong signal amplification ability and holds great promise in constructing a sensitive platform for the simultaneous determination of AA, DA and UA.

  15. Formation and characterization of ZnS/CdS nanocomposite materials into porous silicon

    NASA Astrophysics Data System (ADS)

    Xue, Tao; Lv, Xiao-yi; Jia, Zhen-hong; Hou, Jun-wei; Jian, Ji-kang

    2008-11-01

    ZnS/CdS were deposited by chemical vapor deposition (CVD) technique on porous silicon substrates formed by electrochemical anodization of n-type (100) silicon wafer. The optical properties of ZnS/CdS porous silicon composite materials are studied. The results showed that new luminescence characteristics such as strong and stable visible-light emissions with different colors were observed from the ZnS/CdS-PS nanocomposite materials at room temperature.

  16. Effect of Pressing Parameters on the Structure of Porous Materials Based on Cobalt and Nickel Powders

    NASA Astrophysics Data System (ADS)

    Shustov, V. S.; Rubtsov, N. M.; Alymov, M. I.; Ankudinov, A. B.; Evstratov, E. V.; Zelensky, V. A.

    2018-03-01

    Porous materials with a bulk porosity of more than 68% were synthesized by powder metallurgy methods from a cobalt-nickel mixture. The effect of the ratio of nickel and cobalt powders used in the synthesis of this porous material (including cases when either nickel or cobalt alone was applied) and the conditions of their compaction on structural parameters, such as open and closed porosities and pose size, was established.

  17. Numerical investigation of porous materials composites reinforced with natural fibers

    NASA Astrophysics Data System (ADS)

    Chikhi, M.; Metidji, N.; Mokhtari, F.; Merzouk, N. k.

    2018-05-01

    The present article tends to predict the effective thermal properties of porous biocomposites materials. The composites matrix consists on porous materials namely gypsum and the reinforcement is a natural fiber as date palm fibers. The numerical study is done using Comsol software resolving the heat transfer equation. The results are fitted with theoretical model and experimental results. The results of this study indicate that the porosity has an effect on the Effective thermal conductivity biocompoites.

  18. Hollow glass for insulating layers

    NASA Astrophysics Data System (ADS)

    Merticaru, Andreea R.; Moagar-Poladian, Gabriel

    1999-03-01

    Common porous materials, some of which will be considered in the chapters of this book, include concrete, paper, ceramics, clays, porous semiconductors, chromotography materials, and natural materials like coral, bone, sponges, rocks and shells. Porous materials can also be reactive, such as in charcoal gasification, acid rock dissolution, catalyst deactivation and concrete. This study continues the investigations about the properties of, so-called, hollow glass. In this paper is presented a computer simulation approach in which the thermo-mechanical behavior of a 3D microstructure is directly computed. In this paper a computer modeling approach of porous glass is presented. One way to test the accuracy of the reconstructed microstructures is to computed their physical properties and compare to experimental measurement on equivalent systems. In this view, we imagine a new type of porous type of glass designed as buffer layer in multilayered printed boards in ICs. Our glass is a variable material with a variable pore size and surface area. The porosity could be tailored early from the deposition phases that permitting us to keep in a reasonable balance the dielectric constant and thermal conductivity.

  19. Amplification of earthquake ground motions in Washington, DC, and implications for hazard assessments in central and eastern North America

    USGS Publications Warehouse

    Pratt, Thomas L.; Horton, J. Wright; Munoz, Jessica; Hough, Susan E.; Chapman, Martin C.; Olgun, C. Guney

    2017-01-01

    The extent of damage in Washington, DC, from the 2011 Mw 5.8 Mineral, VA, earthquake was surprising for an epicenter 130 km away; U.S. Geological Survey “Did-You-Feel-It” reports suggest that Atlantic Coastal Plain and other unconsolidated sediments amplified ground motions in the city. We measure this amplification relative to bedrock sites using earthquake signals recorded on a temporary seismometer array. The spectral ratios show strong amplification in the 0.7 to 4 Hz frequency range for sites on sediments. This range overlaps with resonant frequencies of buildings in the city as inferred from their heights, suggesting amplification at frequencies to which many buildings are vulnerable to damage. Our results emphasize that local amplification can raise moderate ground motions to damaging levels in stable continental regions, where low attenuation extends shaking levels over wide areas and unconsolidated deposits on crystalline metamorphic or igneous bedrock can result in strong contrasts in near-surface material properties.

  20. Porous titanium bases for osteochondral tissue engineering

    PubMed Central

    Nover, Adam B.; Lee, Stephanie L.; Georgescu, Maria S.; Howard, Daniel R.; Saunders, Reuben A.; Yu, William T.; Klein, Robert W.; Napolitano, Anthony P.; Ateshian, Gerard A.

    2015-01-01

    Tissue engineering of osteochondral grafts may offer a cell-based alternative to native allografts, which are in short supply. Previous studies promote the fabrication of grafts consisting of a viable cell-seeded hydrogel integrated atop a porous, bone-like metal. Advantages of the manufacturing process have led to the evaluation of porous titanium as the bone-like base material. Here, porous titanium was shown to support the growth of cartilage to produce native levels of Young’s modulus, using a clinically relevant cell source. Mechanical and biochemical properties were similar or higher for the osteochondral constructs compared to chondral-only controls. Further investigation into the mechanical influence of the base on the composite material suggests that underlying pores may decrease interstitial fluid pressurization and applied strains, which may be overcome by alterations to the base structure. Future studies aim to optimize titanium-based tissue engineered osteochondral constructs to best match the structural architecture and strength of native grafts. Statement of Significance The studies described in this manuscript follow up on previous studies from our lab pertaining to the fabrication of osteochondral grafts that consist of a bone-like porous metal and a chondrocyte-seeded hydrogel. Here, tissue engineered osteochondral grafts were cultured to native stiffness using adult chondrocytes, a clinically relevant cell source, and a porous titanium base, a material currently used in clinical implants. This porous titanium is manufactured via selective laser melting, offering the advantages of precise control over shape, pore size, and orientation. Additionally, this manuscript describes the mechanical influence of the porous base, which may have applicability to porous bases derived from other materials. PMID:26320541

  1. Porous titanium bases for osteochondral tissue engineering.

    PubMed

    Nover, Adam B; Lee, Stephanie L; Georgescu, Maria S; Howard, Daniel R; Saunders, Reuben A; Yu, William T; Klein, Robert W; Napolitano, Anthony P; Ateshian, Gerard A; Hung, Clark T

    2015-11-01

    Tissue engineering of osteochondral grafts may offer a cell-based alternative to native allografts, which are in short supply. Previous studies promote the fabrication of grafts consisting of a viable cell-seeded hydrogel integrated atop a porous, bone-like metal. Advantages of the manufacturing process have led to the evaluation of porous titanium as the bone-like base material. Here, porous titanium was shown to support the growth of cartilage to produce native levels of Young's modulus, using a clinically relevant cell source. Mechanical and biochemical properties were similar or higher for the osteochondral constructs compared to chondral-only controls. Further investigation into the mechanical influence of the base on the composite material suggests that underlying pores may decrease interstitial fluid pressurization and applied strains, which may be overcome by alterations to the base structure. Future studies aim to optimize titanium-based tissue engineered osteochondral constructs to best match the structural architecture and strength of native grafts. The studies described in this manuscript follow up on previous studies from our lab pertaining to the fabrication of osteochondral grafts that consist of a bone-like porous metal and a chondrocyte-seeded hydrogel. Here, tissue engineered osteochondral grafts were cultured to native stiffness using adult chondrocytes, a clinically relevant cell source, and a porous titanium base, a material currently used in clinical implants. This porous titanium is manufactured via selective laser melting, offering the advantages of precise control over shape, pore size, and orientation. Additionally, this manuscript describes the mechanical influence of the porous base, which may have applicability to porous bases derived from other materials. Copyright © 2015. Published by Elsevier Ltd.

  2. Porous material neutron detector

    DOEpatents

    Diawara, Yacouba [Oak Ridge, TN; Kocsis, Menyhert [Venon, FR

    2012-04-10

    A neutron detector employs a porous material layer including pores between nanoparticles. The composition of the nanoparticles is selected to cause emission of electrons upon detection of a neutron. The nanoparticles have a maximum dimension that is in the range from 0.1 micron to 1 millimeter, and can be sintered with pores thereamongst. A passing radiation generates electrons at one or more nanoparticles, some of which are scattered into a pore and directed toward a direction opposite to the applied electrical field. These electrons travel through the pore and collide with additional nanoparticles, which generate more electrons. The electrons are amplified in a cascade reaction that occurs along the pores behind the initial detection point. An electron amplification device may be placed behind the porous material layer to further amplify the electrons exiting the porous material layer.

  3. Hollow porous-wall glass microspheres for hydrogen storage

    DOEpatents

    Heung, Leung K.; Schumacher, Ray F.; Wicks, George G.

    2010-02-23

    A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

  4. Open-cell glass crystalline porous material

    DOEpatents

    Anshits, Alexander G.; Sharonova, Olga M.; Vereshchagina, Tatiana A.; Zykova, Irina D.; Revenko, Yurii A.; Tretyakov, Alexander A.; Aloy, Albert S.; Lubtsev, Rem I.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2002-01-01

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  5. Open-cell glass crystalline porous material

    DOEpatents

    Anshits, Alexander G.; Sharonova, Olga M.; Vereshchagina, Tatiana A.; Zykova, Irina D.; Revenko, Yurii A.; Tretyakov, Alexander A.; Aloy, Albert S.; Lubtsev, Rem I.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2003-12-23

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  6. Graded porous inorganic materials derived from self-assembled block copolymer templates.

    PubMed

    Gu, Yibei; Werner, Jörg G; Dorin, Rachel M; Robbins, Spencer W; Wiesner, Ulrich

    2015-03-19

    Graded porous inorganic materials directed by macromolecular self-assembly are expected to offer unique structural platforms relative to conventional porous inorganic materials. Their preparation to date remains a challenge, however, based on the sparsity of viable synthetic self-assembly pathways to control structural asymmetry. Here we demonstrate the fabrication of graded porous carbon, metal, and metal oxide film structures from self-assembled block copolymer templates by using various backfilling techniques in combination with thermal treatments for template removal and chemical transformations. The asymmetric inorganic structures display mesopores in the film top layers and a gradual pore size increase along the film normal in the macroporous sponge-like support structure. Substructure walls between macropores are themselves mesoporous, constituting a structural hierarchy in addition to the pore gradation. Final graded structures can be tailored by tuning casting conditions of self-assembled templates as well as the backfilling processes. We expect that these graded porous inorganic materials may find use in applications including separation, catalysis, biomedical implants, and energy conversion and storage.

  7. An Overview of Recent Development in Composite Catalysts from Porous Materials for Various Reactions and Processes

    PubMed Central

    Xie, Zaiku; Liu, Zhicheng; Wang, Yangdong; Yang, Qihua; Xu, Longya; Ding, Weiping

    2010-01-01

    Catalysts are important to the chemical industry and environmental remediation due to their effective conversion of one chemical into another. Among them, composite catalysts have attracted continuous attention during the past decades. Nowadays, composite catalysts are being used more and more to meet the practical catalytic performance requirements in the chemical industry of high activity, high selectivity and good stability. In this paper, we reviewed our recent work on development of composite catalysts, mainly focusing on the composite catalysts obtained from porous materials such as zeolites, mesoporous materials, carbon nanotubes (CNT), etc. Six types of porous composite catalysts are discussed, including amorphous oxide modified zeolite composite catalysts, zeolite composites prepared by co-crystallization or overgrowth, hierarchical porous catalysts, host-guest porous composites, inorganic and organic mesoporous composite catalysts, and polymer/CNT composite catalysts. PMID:20559508

  8. Cell and current collector felt arrangement for solid oxide electrochemical cell combinations

    DOEpatents

    Reichner, Philip

    1988-01-01

    A solid electrolyte electrochemical cell combination 1 is made, comprising an annular, axially elongated, inner electrode 2 containing at least one interior gas feed conduit 3; annular solid electrolyte segments 4 around and covering portions of the inner electrode; annular outer electrode segments 6 around and covering portions of the electrolyte segments; electronically conducting, non-porous, interconnection material 5 disposed between electrolyte segments and in contact with the inner electrode, and electronically conducting, porous, metal fiber current collector felts 7 disposed on top of the non-porous interconnect material and outer electrode segments, where both the non-porous interconnect material and the porous metal felts are disposed circumferentially about the cell, transversely to the axial length of the cell and the inner electrode is continuous for the entire axial length of the cell combination.

  9. The application of porous tantalum cylinder to the repair of comminuted bone defects: a study of rabbit firearm injuries

    PubMed Central

    Ren, Bo; Zhai, Zhenbo; Guo, Kai; Liu, Yanpu; Hou, Weihuan; Zhu, Qingsheng; Zhu, Jinyu

    2015-01-01

    The aim of this study is to investigate the effect of porous tantalum material in repair tibial defects caused by firearm injuries in a rabbit model. A multifunctional biological impact machine was used to establish a rabbit tibial defect model of firearm injury. Porous tantalum rods were processed into a hollow cylinder. Kirschner wires were used for intramedullary fixation. We compared the differences of the bone ingrowth of the porous tantalum material by gross observations, X-rays and histological evaluations. The radiographic observations revealed that fibrous tissue covered the material surface after 4 weeks, and periosteal reactions and new bone callus extending materials appeared after 8 weeks. After 16 weeks, the calluses of the firearm injury group were completely wrapped around a porous tantalum material. The group with the highest Lane-Sandhu X-rays cores was the firearm injury and tantalum implant group, and the blank control group exhibited the lowest scores. The histological evaluations revealed that the presence of new bone around the biomaterial had grown into the porous tantalum. By the 16th week, the areas of bone tissue of the firearm injury group was significant higher than that of non-firearm injury group (P<0.05). The comminuted fractures treated with tantalum cylinders exhibited greater bone ingrowth in the firearm injury group. In conditions of firearm injuries, the porous tantalum biomaterial exhibited bone ingrowth that was beneficial to the treatment of bone defects. PMID:26131078

  10. Recent Advances in Porous Carbon Materials for Electrochemical Energy Storage.

    PubMed

    Wang, Libin; Hu, Xianluo

    2018-06-18

    Climate change and the energy crisis have promoted the rapid development of electrochemical energy-storage devices. Owing to many intriguing physicochemical properties, such as excellent chemical stability, high electronic conductivity, and a large specific surface area, porous carbon materials have always been considering as a promising candidate for electrochemical energy storage. To date, a wide variety of porous carbon materials based upon molecular design, pore control, and compositional tailoring have been proposed for energy-storage applications. This focus review summarizes recent advances in the synthesis of various porous carbon materials from the view of energy storage, particularly in the past three years. Their applications in representative electrochemical energy-storage devices, such as lithium-ion batteries, supercapacitors, and lithium-ion hybrid capacitors, are discussed in this review, with a look forward to offer some inspiration and guidelines for the exploitation of advanced carbon-based energy-storage materials. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Enhanced densification under shock compression in porous silicon

    DOE PAGES

    Lane, J. Matthew; Thompson, Aidan Patrick; Vogler, Tracy

    2014-10-27

    Under shock compression, most porous materials exhibit lower densities for a given pressure than that of a full-dense sample of the same material. However, some porous materials exhibit an anomalous, or enhanced, densification under shock compression. The mechanism driving this behavior was not completely determined. We present evidence from atomistic simulation that pure silicon belongs to this anomalous class of materials and demonstrate the associated mechanisms responsible for the effect in porous silicon. Atomistic response indicates that local shear strain in the neighborhood of collapsing pores catalyzes a local solid-solid phase transformation even when bulk pressures are below the thermodynamicmore » phase transformation pressure. This metastable, local, and partial, solid-solid phase transformation, which accounts for the enhanced densification in silicon, is driven by the local stress state near the void, not equilibrium thermodynamics. This mechanism may also explain the phenomenon in other covalently bonded materials.« less

  12. Dimpled elastic sheets: a new class of non-porous negative Poisson’s ratio materials

    NASA Astrophysics Data System (ADS)

    Javid, Farhad; Smith-Roberge, Evelyne; Innes, Matthew C.; Shanian, Ali; Weaver, James C.; Bertoldi, Katia

    2015-12-01

    In this study, we report a novel periodic material with negative Poisson’s ratio (also called auxetic materials) fabricated by denting spherical dimples in an elastic flat sheet. While previously reported auxetic materials are either porous or comprise at least two phases, the material proposed here is non-porous and made of a homogeneous elastic sheet. Importantly, the auxetic behavior is induced by a novel mechanism which exploits the out-of-plane deformation of the spherical dimples. Through a combination of experiments and numerical analyses, we demonstrate the robustness of the proposed concept, paving the way for developing a new class of auxetic materials that significantly expand their design space and possible applications.

  13. Porous ceramic scaffolds with complex architectures

    NASA Astrophysics Data System (ADS)

    Munch, E.; Franco, J.; Deville, S.; Hunger, P.; Saiz, E.; Tomsia, A. P.

    2008-06-01

    This work compares two novel techniques for the fabrication of ceramic scaffolds for bone tissue engineering with complex porosity: robocasting and freeze casting. Both techniques are based on the preparation of concentrated ceramic suspensions with suitable properties for the process. In robocasting, the computer-guided deposition of the suspensions is used to build porous materials with designed three dimensional geometries and microstructures. Freeze casting uses ice crystals as a template to form porous lamellar ceramic materials. Preliminary results on the compressive strengths of the materials are also reported.

  14. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOEpatents

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  15. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Padaki, S.; Drzal, L.T.

    The consolidation process in composites made out of powder impregnated tapes differs from that of other material forms because of the distribution of fiber and matrix in the unconsolidated state. A number of factors (e.g. time, pressure, particle size, volume fraction and viscosity) affect the efficiency of the consolidation of these tapes. This paper describes the development of a mathematical process model that describes the best set of parameters required for the consolidation of a given prepreg tape.

  16. Fabrication of a porous material with a porosity gradient by a pulsed electric current sintering process

    NASA Astrophysics Data System (ADS)

    Suk, Myung-Jin; Choi, Sung-II; Kim, Ji-Soon; Kim, Young Do; Kwon, Young-Soon

    2003-12-01

    A porous structure with a porosity gradient can be applied to the preparation of continuous FGM, where liquid or chemical vapor of the second phase is infiltrated into the graded pores. It also has applications in skeletal implant materials and ultrafiltration media. An attempt was made to fabricate a porous material with a porosity gradient by means of a pulsed electric current sintering (PECS) process. The present work describes not only the measured value of the temperature difference between the upper and lower part of the specimen, which brings about a gradual change in pore distribution, but also the sintering characteristics of the porous structure obtained by the pressureless PECS process.

  17. Soft porous silicone rubbers with ultra-low sound speeds in acoustic metamaterials

    PubMed Central

    Ba, Abdoulaye; Kovalenko, Artem; Aristégui, Christophe; Mondain-Monval, Olivier; Brunet, Thomas

    2017-01-01

    Soft porous silicone rubbers are demonstrated to exhibit extremely low sound speeds of tens of m/s for these dense materials, even for low porosities of the order of a few percent. Our ultrasonic experiments show a sudden drop of the longitudinal sound speed with the porosity, while the transverse sound speed remains constant. For such porous elastomeric materials, we propose simple analytical expressions for these two sound speeds, derived in the framework of Kuster and Toksöz, revealing an excellent agreement between the theoretical predictions and the experimental results for both longitudinal and shear waves. Acoustic attenuation measurements also complete the characterization of these soft porous materials. PMID:28054661

  18. Formation of porous networks on polymeric surfaces by femtosecond laser micromachining

    NASA Astrophysics Data System (ADS)

    Assaf, Youssef; Kietzig, Anne-Marie

    2017-02-01

    In this study, porous network structures were successfully created on various polymer surfaces by femtosecond laser micromachining. Six different polymers (poly(tetrafluoroethylene) (PTFE), poly(methyl methacrylate) (PMMA), high density poly(ethylene) (HDPE), poly(lactic acid) (PLA), poly(carbonate) (PC), and poly(ethylene terephthalate) (PET)) were machined at different fluences and pulse numbers, and the resulting structures were identified and compared by lacunarity analysis. At low fluence and pulse numbers, porous networks were confirmed to form on all materials except PLA. Furthermore, all networks except for PMMA were shown to bundle up at high fluence and pulse numbers. In the case of PC, a complete breakdown of the structure at such conditions was observed. Operation slightly above threshold fluence and at low pulse numbers is therefore recommended for porous network formation. Finally, the thickness over which these structures formed was measured and compared to two intrinsic material dependent parameters: the single pulse threshold fluence and the incubation coefficient. Results indicate that a lower threshold fluence at operating conditions favors material removal over structure formation and is hence detrimental to porous network formation. Favorable machining conditions and material-dependent parameters for the formation of porous networks on polymer surfaces have thus been identified.

  19. Electrochemical cell method

    DOEpatents

    Kaun, T.D.; Eshman, P.F.

    1980-05-09

    A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

  20. Porous zirconia ceramic as an alternative to dentin for in vitro dentin barriers cytotoxicity test.

    PubMed

    Hu, Meng-Long; Lin, Hong; Jiang, Ruo-Dan; Dong, Li-Min; Huang, Lin; Zheng, Gang

    2018-06-01

    This study assessed the potential of porous zirconia ceramic as an alternative to dentin via an in vitro dentin barrier cytotoxicity test. The permeability of dentin and porous zirconia ceramic was measured using a hydraulic-conductance system, and their permeability was divided into two groups: high and low. Using an in vitro dentin barrier test, the cytotoxicity of dental materials by dentin and porous zirconia ceramic was compared within the same permeability group. The L-929 cell viability was assessed by MTT assay. The mean (SD) permeability of the high and low group for dentin was 0.334 (0.0873) and 0.147 (0.0377) μl min -1  cm -2  cm H 2 O -1 and for zirconia porous ceramic was 0.336 (0.0609) and 0.146 (0.0340) μl min -1  cm -2  cm H 2 O -1 . The cell viability of experimental groups which are the low permeability group was higher than that of the high permeability group for both dentin and porous zirconia ceramic as a barrier except for Maxcem Elite ™ by porous zirconia ceramic. There was no significant difference between dentin and porous zirconia ceramic in cell viability, within either the high or low permeability group for all materials. The SD for cell viability of the porous zirconia ceramic was less than that of the dentin, across all materials within each permeability group, except for Maxcem Elite ™ in the high permeability group. Porous zirconia ceramic, having similar permeability to dentin at the same thickness, can be used as an alternative to dentin for in vitro dentin barrier cytotoxicity tests. In vitro dentin barrier cytotoxicity tests when a standardized porous zirconia ceramic was used as a barrier could be useful for assessing the potential toxicity of new dental materials applied to dentin before applying in clinical and may resolve the issue of procuring human teeth when testing proceeds.

  1. Comet 67P/Churyumov-Gerasimenko, is the pristine material present anywhere close to the surface?

    NASA Astrophysics Data System (ADS)

    Kossacki, Konrad

    2016-10-01

    Observations of the nucleus of comet 67P/Churyumov-Gerasimenko indicate high complexity of the topography (Thomas et al., 2015). Presence of numerous pits, and depressions, as well as scarps suggests complex evolution of the nucleus. This in turn makes uncertain presence of the pristine material anywhere close to the surface. However, non-uniformity of the mechanical strength of the nucleus suggests, that in some locations material can retain initial structure. This should be expected neither in the final Philae landing site Abydos, where the compressive strength of the material is about 2 MPa (Spohn et al., 2015), neither in the location of the first touch down, where beneath a layer of unconsolidated material possibly is a hard material (Biele et al., 2015). Both locations are at low latitudes, where the flux of solar energy is much higher than northern parts of the lobes, illuminated when the comet is far form perihelion. Groussin et al. (2015) investigated what inclination of slopes corresponds to the presence of falling-out boulders and have found, that the average strength is probably lower than 1.5 kPa.I attempted to answer the question, whether in poorly illuminated regions of the nucleus of comet 67P/Churyumov-Gerasimenko are possible thermal conditions suitable for preservation of a pristine unconsolidated ice-dust material. For this purpose I calculated evolution of the temperature and structure of the material versus depth in selected locations in region Ma'at. This region is in general smooth (El-Maary et al., 2015), which may indicate presence of a loose dust mantle on the surface. The applied shape model is SHAP4s v1.0 (Preuskner et al., 2015). The performed simulations indicate, that in Scenario A preservation of low uni-axial compressive strength is possible, but only in shadowed locations, beneath a dust mantle of low thermal conductivity, at least few centimeters thick.

  2. Porous Materials from Thermally Activated Kaolinite: Preparation, Characterization and Application

    PubMed Central

    Luo, Jun; Jiang, Tao; Li, Guanghui; Peng, Zhiwei; Rao, Mingjun; Zhang, Yuanbo

    2017-01-01

    In the present study, porous alumina/silica materials were prepared by selective leaching of silicon/aluminum constituents from thermal-activated kaolinite in inorganic acid or alkali liquor. The correlations between the characteristics of the prepared porous materials and the dissolution properties of activated kaolinite were also investigated. The results show that the specific surface area (SSA) of porous alumina/silica increases with silica/alumina dissolution, but without marked change of the BJH pore size. Furthermore, change in pore volume is more dependent on activation temperature. The porous alumina and silica obtained from alkali leaching of kaolinite activated at 1150 °C for 15 min and acid leaching of kaolinite activated at 850 °C for 15 min are mesoporous, with SSAs, BJH pore sizes and pore volumes of 55.8 m2/g and 280.3 m2/g, 6.06 nm and 3.06 nm, 0.1455 mL/g and 0.1945 mL/g, respectively. According to the adsorption tests, porous alumina has superior adsorption capacities for Cu2+, Pb2+ and Cd2+ compared with porous silica and activated carbon. The maximum capacities of porous alumina for Cu2+, Pb2+ and Cd2+ are 134 mg/g, 183 mg/g and 195 mg/g, respectively, at 30 °C. PMID:28773002

  3. Porous, S-bearing silica in metal-sulfide nodules and in the interchondrule clastic matrix in two EH3 chondrites

    NASA Astrophysics Data System (ADS)

    Lehner, S. W.; Németh, P.; Petaev, M. I.; Buseck, P. R.

    2017-11-01

    Two new occurrences of porous, S-bearing, amorphous silica are described within metal-sulfide nodules (MSN) and as interchondrule patches in EH3 chondrites SAH 97072 and ALH 84170. This porous amorphous material, which was first reported from sulfide-bearing chondrules, consists of sinewy SiO2-rich areas containing S with minor Na or Ca as well as Fe, Mg, and Al. Some pores contain minerals including pyrite, pyrrhotite, and anhydrite. Most pores appear vacant or contain unidentified material that is unstable under analytical conditions. Niningerite, olivine, enstatite, albite, and kumdykolite occur enclosed within porous silica patches. Porous silica is commonly interfingered with cristobalite suggesting its amorphous structure resulted from high-temperature quenching. We interpret the S-bearing porous silica to be a product of silicate sulfidation, and the Na, Ca, Fe, Mg, and Al detectable within this material are chemical residues of sulfidized silicates and metal. The occurrence of porous silica in the cores of MSN, which are considered to be pre-accretionary objects, suggests the sulfidizing conditions occurred prior to final parent-body solidification. Ubiquitous S-bearing porous silica among sulfide-bearing chondrules, MSN, and in the interchondrule clastic matrix, suggests that similar sulfidizing conditions affected all the constituents of these EH3 chondrites.

  4. Functional porous composites by blending with solution-processable molecular pores.

    PubMed

    Jiang, S; Chen, L; Briggs, M E; Hasell, T; Cooper, A I

    2016-05-25

    We present a simple method for rendering non-porous materials porous by solution co-processing with organic cage molecules. This method can be used both for small functional molecules and for polymers, thus creating porous composites by molecular blending, rather than the more traditional approach of supporting functional molecules on pre-frabricated porous supports.

  5. Hierarchical porous carbon microspheres derived from porous starch for use in high-rate electrochemical double-layer capacitors.

    PubMed

    Du, Si-Hong; Wang, Li-Qun; Fu, Xiao-Ting; Chen, Ming-Ming; Wang, Cheng-Yang

    2013-07-01

    Porous starch was used as a precursor for hierarchical porous carbon microspheres. The preparation consisted of stabilisation, carbonisation and KOH activation, and the resultant hierarchical porous carbon microspheres had a large BET surface area of 3251 m(2)g(-1). Due to the large surface area and the hierarchical pore structure, electrodes made of the hierarchical porous carbon microsphere materials had high specific capacitances of 304 Fg(-1) at a current density of 0.05 Ag(-1) and 197 Fg(-1) at a current density of 180 Ag(-1) when used in a symmetric capacitor with 6M KOH as the electrolyte. After 10,000 cycles, the capacitor still exhibited a stable performance with a capacitance retention of 98%. These results indicate that porous starch is an excellent precursor to prepare high performance electrode materials for EDLCs. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. Mathematical Simulation of Drying Process of Fibrous Material

    NASA Astrophysics Data System (ADS)

    Blejchař, Tomáš; Raška, Jiří; Jablonská, Jana

    2018-06-01

    The article describes mathematical simulation of flowing air through porous zone and water vaporisation from mentioned porous area which actually represents dried fibrous material - cotton towel. Simulation is based on finite volume method. Wet towel is placed in pipe and hot air flow through the towel. Water from towel is evaporated. Simulation of airflow through porous element is described first. Eulerian multiphase model is then used for simulation of water vaporisation from porous medium. Results of simulation are compared with experiment. Ansys Fluent 13.0 was used for calculation.

  7. Porous hollow Co3O4 with rhombic dodecahedral structures for high-performance supercapacitors

    NASA Astrophysics Data System (ADS)

    Zhang, Yi-Zhou; Wang, Yang; Xie, Ye-Lei; Cheng, Tao; Lai, Wen-Yong; Pang, Huan; Huang, Wei

    2014-11-01

    Porous hollow Co3O4 with rhombic dodecahedral structures were prepared by the calcination of ZIF-67 ([Co(mim)2; mim = 2-methylimidazolate]) rhombic dodecahedral microcrystals. A supercapacitor was successfully constructed by adopting the resulting porous hollow Co3O4 rhombic dodecahedral structure as the electrode material, which showed a large specific capacitance of 1100 F g-1 and retained more than 95.1% of the specific capacitance after 6000 continuous charge-discharge cycles. The excellent capacitive properties and stability mark the porous hollow Co3O4 with the rhombic dodecahedral structure as one of the most promising electrode materials for high-performance supercapacitors.Porous hollow Co3O4 with rhombic dodecahedral structures were prepared by the calcination of ZIF-67 ([Co(mim)2; mim = 2-methylimidazolate]) rhombic dodecahedral microcrystals. A supercapacitor was successfully constructed by adopting the resulting porous hollow Co3O4 rhombic dodecahedral structure as the electrode material, which showed a large specific capacitance of 1100 F g-1 and retained more than 95.1% of the specific capacitance after 6000 continuous charge-discharge cycles. The excellent capacitive properties and stability mark the porous hollow Co3O4 with the rhombic dodecahedral structure as one of the most promising electrode materials for high-performance supercapacitors. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr04782f

  8. Processing and Modeling of Porous Copper Using Sintering Dissolution Process

    NASA Astrophysics Data System (ADS)

    Salih, Mustafa Abualgasim Abdalhakam

    The growth of porous metal has produced materials with improved properties as compared to non-metals and solid metals. Porous metal can be classified as either open cell or closed cell. Open cell allows a fluid media to pass through it. Closed cell is made up of adjacent sealed pores with shared cell walls. Metal foams offer higher strength to weight ratios, increased impact energy absorption, and a greater tolerance to high temperatures and adverse environmental conditions when compared to bulk materials. Copper and its alloys are examples of these, well known for high strength and good mechanical, thermal and electrical properties. In the present study, the porous Cu was made by a powder metallurgy process, using three different space holders, sodium chloride, sodium carbonate and potassium carbonate. Several different samples have been produced, using different ratios of volume fraction. The densities of the porous metals have been measured and compared to the theoretical density calculated using an equation developed for these foams. The porous structure was determined with the removal of spacer materials through sintering process. The sintering process of each spacer material depends on the melting point of the spacer material. Processing, characterization, and mechanical properties were completed. These tests include density measurements, compression tests, computed tomography (CT) and scanning electron microscopy (SEM). The captured morphological images are utilized to generate the object-oriented finite element (OOF) analysis for the porous copper. Porous copper was formed with porosities in the range of 40-66% with density ranges from 3 to 5.2 g/cm3. A study of two different methods to measure porosity was completed. OOF (Object Oriented Finite Elements) is a desktop software application for studying the relationship between the microstructure of a material and its overall mechanical, dielectric, or thermal properties using finite element models based on real or simulated micrographs. OOF provides methods for segmenting images, creating meshes and solving of complex geometries using finite element models, and visualizing 2D results.

  9. Porous Hard Carbon Derived from Walnut Shell as an Anode Material for Sodium-Ion Batteries

    NASA Astrophysics Data System (ADS)

    Zhang, Sensen; Li, Ying; Li, Min

    2018-02-01

    Porous hard carbon with large interlayer distance was fabricated from walnut shells through a facile high-temperature pyrolysis process and investigated as an anode material for sodium-ion batteries (SIBs). The results show that the electrochemical performance is mainly dependent on the pyrolysis temperature. The porous hard carbon, which was carbonized at 1300°C, displays the highest reversible capacity of 230 mAh g-1 at 20 mA g-1 and an excellent cycling stability (96% capacity retained over 200 cycles). The promising electrochemical performances are attributed to the porous structure reducing distances for sodium ion diffusion and expanded interlayer spacing, which is beneficial for sodium reversible insertion/extraction. The excellent electrochemical performance as well as the low-cost and environmental friendliness demonstrates that walnut shell-derived porous hard carbon is a promising anode material candidate for SIBs.

  10. Porous silicon in drug delivery devices and materials☆

    PubMed Central

    Anglin, Emily J.; Cheng, Lingyun; Freeman, William R.; Sailor, Michael J.

    2009-01-01

    Porous Si exhibits a number of properties that make it an attractive material for controlled drug delivery applications: The electrochemical synthesis allows construction of tailored pore sizes and volumes that are controllable from the scale of microns to nanometers; a number of convenient chemistries exist for the modification of porous Si surfaces that can be used to control the amount, identity, and in vivo release rate of drug payloads and the resorption rate of the porous host matrix; the material can be used as a template for organic and biopolymers, to prepare composites with a designed nanostructure; and finally, the optical properties of photonic structures prepared from this material provide a self-reporting feature that can be monitored in vivo. This paper reviews the preparation, chemistry, and properties of electrochemically prepared porous Si or SiO2 hosts relevant to drug delivery applications. PMID:18508154

  11. Composite material

    DOEpatents

    Hutchens, Stacy A [Knoxville, TN; Woodward, Jonathan [Solihull, GB; Evans, Barbara R [Oak Ridge, TN; O'Neill, Hugh M [Knoxville, TN

    2012-02-07

    A composite biocompatible hydrogel material includes a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa. A calcium comprising salt is disposed in at least some of the pores. The porous polymer matrix can comprise cellulose, including bacterial cellulose. The composite can be used as a bone graft material. A method of tissue repair within the body of animals includes the steps of providing a composite biocompatible hydrogel material including a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa, and inserting the hydrogel material into cartilage or bone tissue of an animal, wherein the hydrogel material supports cell colonization in vitro for autologous cell seeding.

  12. Evaluation of Toluene Adsorption Performance of Mortar Adhesives Using Porous Carbon Material as Adsorbent.

    PubMed

    Wi, Seunghwan; Chang, Seong Jin; Jeong, Su-Gwang; Lee, Jongki; Kim, Taeyeon; Park, Kyung-Won; Lee, Dong Ryeol; Kim, Sumin

    2017-07-26

    Porous carbon materials are advantageous in adsorbing pollutants due to their wide range of specific surface areas, pore diameter, and pore volume. Among the porous carbon materials in the current study, expanded graphite, xGnP, xGnP C-300, xGnP C-500, and xGnP C-750 were prepared as adsorbent materials. Brunauer-Emmett-Teller (BET) analysis was conducted to select the adsorbent material through the analysis of the specific surface area, pore size, and pore volume of the prepared porous carbon materials. Morphological analysis using SEM was also performed. The xGnP C-500 as adsorbent material was applied to a mortar adhesive that is widely used in the installation of interior building materials. The toluene adsorption performances of the specimens were evaluated using 20 L small chamber. Furthermore, the performance of the mortar adhesive, as indicated by the shear bond strength, length change rate, and water retention rate, was analyzed according to the required test method specified in the Korean standards. It was confirmed that for the mortar adhesives prepared using the xGnP C-500 as adsorbent material, the toluene adsorption performance was excellent and satisfied the required physical properties.

  13. Tuneable porous carbonaceous materials from renewable resources.

    PubMed

    White, Robin J; Budarin, Vitaly; Luque, Rafael; Clark, James H; Macquarrie, Duncan J

    2009-12-01

    Porous carbon materials are ubiquitous with a wide range of technologically important applications, including separation science, heterogeneous catalyst supports, water purification filters, stationary phase materials, as well as the developing future areas of energy generation and storage applications. Hard template routes to ordered mesoporous carbons are well established, but whilst offering different mesoscopic textural phases, the surface of the material is difficult to chemically post-modify and processing is energy, resource and step intensive. The production of carbon materials from biomass (i.e. sugars or polysaccharides) is a relatively new but rapidly expanding research area. In this tutorial review, we compare and contrast recently reported routes to the preparation of porous carbon materials derived from renewable resources, with examples of our previously reported mesoporous polysaccharide-derived "Starbon" carbonaceous material technology.

  14. Particulate-free porous silicon networks for efficient capacitive deionization water desalination

    PubMed Central

    Metke, Thomas; Westover, Andrew S.; Carter, Rachel; Oakes, Landon; Douglas, Anna; Pint, Cary L.

    2016-01-01

    Energy efficient water desalination processes employing low-cost and earth-abundant materials is a critical step to sustainably manage future human needs for clean water resources. Here we demonstrate that porous silicon – a material harnessing earth abundance, cost, and environmental/biological compatibility is a candidate material for water desalination. With appropriate surface passivation of the porous silicon material to prevent surface corrosion in aqueous environments, we show that porous silicon templates can enable salt removal in capacitive deionization (CDI) ranging from 0.36% by mass at the onset from fresh to brackish water (10 mM, or 0.06% salinity) to 0.52% in ocean water salt concentrations (500 mM, or ~0.3% salinity). This is on par with reports of most carbon nanomaterial based CDI systems based on particulate electrodes and covers the full salinity range required of a CDI system with a total ocean-to-fresh water required energy input of ~1.45 Wh/L. The use of porous silicon for CDI enables new routes to directly couple water desalination technology with microfluidic systems and photovoltaics that natively use silicon materials, while mitigating adverse effects of water contamination occurring from nanoparticulate-based CDI electrodes. PMID:27101809

  15. Novel hierarchically porous carbon materials obtained from natural biopolymer as host matrixes for lithium-sulfur battery applications.

    PubMed

    Zhang, Bin; Xiao, Min; Wang, Shuanjin; Han, Dongmei; Song, Shuqin; Chen, Guohua; Meng, Yuezhong

    2014-08-13

    Novel hierarchically porous carbon materials with very high surface areas, large pore volumes and high electron conductivities were prepared from silk cocoon by carbonization with KOH activation. The prepared novel porous carbon-encapsulated sulfur composites were fabricated by a simple melting process and used as cathodes for lithium sulfur batteries. Because of the large surface area and hierarchically porous structure of the carbon material, soluble polysulfide intermediates can be trapped within the cathode and the volume expansion can be alleviated effectively. Moreover, the electron transport properties of the carbon materials can provide an electron conductive network and promote the utilization rate of sulfur in cathode. The prepared carbon-sulfur composite exhibited a high specific capacity and excellent cycle stability. The results show a high initial discharge capacity of 1443 mAh g(-1) and retain 804 mAh g(-1) after 80 discharge/charge cycles at a rate of 0.5 C. A Coulombic efficiency retained up to 92% after 80 cycles. The prepared hierarchically porous carbon materials were proven to be an effective host matrix for sulfur encapsulation to improve the sulfur utilization rate and restrain the dissolution of polysulfides into lithium-sulfur battery electrolytes.

  16. Particulate-free porous silicon networks for efficient capacitive deionization water desalination.

    PubMed

    Metke, Thomas; Westover, Andrew S; Carter, Rachel; Oakes, Landon; Douglas, Anna; Pint, Cary L

    2016-04-22

    Energy efficient water desalination processes employing low-cost and earth-abundant materials is a critical step to sustainably manage future human needs for clean water resources. Here we demonstrate that porous silicon - a material harnessing earth abundance, cost, and environmental/biological compatibility is a candidate material for water desalination. With appropriate surface passivation of the porous silicon material to prevent surface corrosion in aqueous environments, we show that porous silicon templates can enable salt removal in capacitive deionization (CDI) ranging from 0.36% by mass at the onset from fresh to brackish water (10 mM, or 0.06% salinity) to 0.52% in ocean water salt concentrations (500 mM, or ~0.3% salinity). This is on par with reports of most carbon nanomaterial based CDI systems based on particulate electrodes and covers the full salinity range required of a CDI system with a total ocean-to-fresh water required energy input of ~1.45 Wh/L. The use of porous silicon for CDI enables new routes to directly couple water desalination technology with microfluidic systems and photovoltaics that natively use silicon materials, while mitigating adverse effects of water contamination occurring from nanoparticulate-based CDI electrodes.

  17. Prediction of the niche effect for single flat panels with or without attached sound absorbing materials.

    PubMed

    Sgard, Franck; Atalla, Noureddine; Nélisse, Hugues

    2015-01-01

    The sound transmission loss (STL) of a test sample measured in sound transmission facilities is affected by the opening in which it is located. This is called the niche effect. This paper uses a modal approach to study the STL of a rectangular plate with or without an attached porous material located inside a box-shaped niche. The porous material is modeled as a limp equivalent fluid. The proposed model is validated by comparison with finite element/boundary element computations. Using a condensation of the pressure fields in the niche, the niche effect is interpreted in terms of a modification of the modal blocked pressure fields acting on the panel induced by the front cavity and by a modification of the radiation efficiency of the panel modes due to the presence of the back cavity. The modal approach is then used to investigate the impact of (1) the presence of a porous material attached to the panel on the niche effect and (2) the niche effect on the assessment of the porous material insertion loss. A simplified model for the porous material based on a transfer matrix approach is also proposed to predict the STL of the system and its validity is discussed.

  18. Meteoritic and other constraints on the internal structure and impact history of small asteroids

    NASA Astrophysics Data System (ADS)

    Scott, Edward R. D.; Wilson, Lionel

    2005-03-01

    Studies of the internal structure of asteroids, which are crucial for understanding their impact history and for hazard mitigation, appear to be in conflict for the S-type asteroids, Eros, Gaspra, and Ida. Spacecraft images and geophysical data show that they are fractured, coherent bodies, whereas models of catastrophic asteroidal impacts, family and satellite formation, and studies of asteroid spin rates, and other diverse properties of asteroids and planetary craters suggest that such asteroids are gravitationally bound aggregates of rubble. These conflicting views may be reconciled if 10-50 km S-type asteroids formed as rubble piles, but were later consolidated into coherent bodies. Many meteorites are breccias that testify to a long history of impact fragmentation and consolidation by alteration, metamorphism, igneous and impact processes. Ordinary chondrites, which are the best analogs for S asteroids, are commonly breccias. Some may have formed in cratering events, but many appear to have formed during disruption and reaccretion of their parent asteroids. Some breccias were lithified during metamorphism, and a few were lithified by injected impact melt, but most are regolith and fragmental breccias that were lithified by mild or moderate shock, like their lunar analogs. Shock experiments show that porous chondritic powders can be consolidated during mild shock by small amounts of silicate melt that glues grains together, and by friction and pressure welding of silicate and metallic Fe,Ni grains. We suggest that the same processes that converted impact debris into meteorite breccias also consolidated asteroidal rubble. Internal voids would be partly filled with regolith by impact-induced seismic shaking. Consolidation of this material beneath large craters would lithify asteroidal rubble to form a more coherent body. Fractures on Ida that were created by antipodal impacts and are concentrated in and near large craters, and small positive gravity anomalies associated with the Psyche and Himeros craters on Eros, are consistent with this concept. Spin data suggest that smaller asteroids 0.6-6 km in size are unconsolidated rubble piles. C-type asteroids, which are more porous than S-types, and their analogs, the volatile-rich carbonaceous chondrites, were probably not lithified by shock.

  19. Ash-flow tuffs: Their origin, geologic relations, and identification

    USGS Publications Warehouse

    Ross, Clarence S.; Smith, Robert L.

    1961-01-01

    Pyroclastic materials, which are interpreted as having been deposited by flowage as a suspension of ash in volcanic gas, are becoming widely recognized as major geologic episodes. These may be unconsolidated, indurated by partial welding, or welded into a compact rock. Many students are working on these materials and the interest in them is so widespread that need for a coordinated treatise on them has developed. This report deals with the history of the concept of their origin; gives detailed descriptions of their character and mode of occurrence; gives criteria for their recognition; and considers their distribution and consolidation.

  20. Reproducibility experiments on measuring acoustical properties of rigid-frame porous media (round-robin tests).

    PubMed

    Horoshenkov, Kirill V; Khan, Amir; Bécot, François-Xavier; Jaouen, Luc; Sgard, Franck; Renault, Amélie; Amirouche, Nesrine; Pompoli, Francesco; Prodi, Nicola; Bonfiglio, Paolo; Pispola, Giulio; Asdrubali, Francesco; Hübelt, Jörn; Atalla, Noureddine; Amédin, Celse K; Lauriks, Walter; Boeckx, Laurens

    2007-07-01

    This paper reports the results of reproducibility experiments on the interlaboratory characterization of the acoustical properties of three types of consolidated porous media: granulated porous rubber, reticulated foam, and fiberglass. The measurements are conducted in several independent laboratories in Europe and North America. The studied acoustical characteristics are the surface complex acoustic impedance at normal incidence and plane wave absorption coefficient which are determined using the standard impedance tube method. The paper provides detailed procedures related to sample preparation and installation and it discusses the dispersion in the acoustical material property observed between individual material samples and laboratories. The importance of the boundary conditions, homogeneity of the porous material structure, and stability of the adopted signal processing method are highlighted.

  1. Method for fabrication of electrodes

    DOEpatents

    Jankowski, Alan F.; Morse, Jeffrey D.; Barksdale, Randy

    2004-06-22

    Described herein is a method to fabricate porous thin-film electrodes for fuel cells and fuel cell stacks. Furthermore, the method can be used for all fuel cell electrolyte materials which utilize a continuous electrolyte layer. An electrode layer is deposited on a porous host structure by flowing gas (for example, Argon) from the bottomside of the host structure while simultaneously depositing a conductive material onto the topside of the host structure. By controlling the gas flow rate through the pores, along with the process conditions and deposition rate of the thin-film electrode material, a film of a pre-determined thickness can be formed. Once the porous electrode is formed, a continuous electrolyte thin-film is deposited, followed by a second porous electrode to complete the fuel cell structure.

  2. Porous Networks Through Colloidal Templates

    NASA Astrophysics Data System (ADS)

    Li, Qin; Retsch, Markus; Wang, Jianjun; Knoll, Wolfgang; Jonas, Ulrich

    Porous networks represent a class of materials with interconnected voids with specific properties concerning adsorption, mass and heat transport, and spatial confinement, which lead to a wide range of applications ranging from oil recovery and water purification to tissue engineering. Porous networks with well-defined, highly ordered structure and periodicities around the wavelength of light can furthermore show very sophisticated optical properties. Such networks can be fabricated from a very large range of materials by infiltration of a sacrificial colloidal crystal template and subsequent removal of the template. The preparation procedures reported in the literature are discussed in this review and the resulting porous networks are presented with respect to the underlying material class. Furthermore, methods for hierarchical superstructure formation and functionalization of the network walls are discussed.

  3. Methods for removing contaminant matter from a porous material

    DOEpatents

    Fox, Robert V [Idaho Falls, ID; Avci, Recep [Bozeman, MT; Groenewold, Gary S [Idaho Falls, ID

    2010-11-16

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  4. Systems and strippable coatings for decontaminating structures that include porous material

    DOEpatents

    Fox, Robert V [Idaho Falls, ID; Avci, Recep [Bozeman, MT; Groenewold, Gary S [Idaho Falls, ID

    2011-12-06

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  5. Porous nitrogen-doped carbon derived from silk fibroin protein encapsulating sulfur as a superior cathode material for high-performance lithium-sulfur batteries.

    PubMed

    Zhang, Jiawei; Cai, Yurong; Zhong, Qiwei; Lai, Dongzhi; Yao, Juming

    2015-11-14

    The features of a carbon substrate are crucial for the electrochemical performance of lithium-sulfur (Li-S) batteries. Nitrogen doping of carbon materials is assumed to play an important role in sulfur immobilisation. In this study, natural silk fibroin protein is used as a precursor of nitrogen-rich carbon to fabricate a novel, porous, nitrogen-doped carbon material through facile carbonisation and activation. Porous carbon, with a reversible capacity of 815 mA h g(-1) at 0.2 C after 60 cycles, serves as the cathode material in Li-S batteries. Porous carbon retains a reversible capacity of 567 mA h g(-1), which corresponds to a capacity retention of 98% at 1 C after 200 cycles. The promising electrochemical performance of porous carbon is attributed to its mesoporous structure, high specific surface area and nitrogen doping into the carbon skeleton. This study provides a general strategy to synthesise nitrogen-doped carbons with a high specific surface area, which is crucial to improve the energy density and electrochemical performance of Li-S batteries.

  6. Experimental and numerical investigations on freeze-drying of porous media with prebuilt porosity

    NASA Astrophysics Data System (ADS)

    Wang, Wei; Yang, Jing; Hu, Dapeng; Pan, Yanqiu; Wang, Shihao; Chen, Guohua

    2018-05-01

    Freeze-drying of initially porous frozen material was investigated aimed at improving the process economics by reducing drying time and raising productivity. Experimental results showed that freeze-drying can be significantly enhanced by the frozen material with prebuilt porosity, and about 31% of drying time can be saved compared with the conventionally solid frozen material under the tested operating conditions. A multiphase transport model was formulated based on the local mass non-equilibrium assumption. Numerical results showed excellent agreements between measured and predicted drying curves. Analyses of saturation and temperature profiles displayed that volumetric sublimation-desorption can occur for the initially porous frozen material.

  7. Metal recovery from porous materials

    DOEpatents

    Sturcken, Edward F.

    1992-01-01

    A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

  8. Metal recovery from porous materials

    DOEpatents

    Sturcken, E.F.

    1992-10-13

    A method is described for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF[sub 4] and HNO[sub 3] and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200 C. The porous material can be pulverized before immersion to further increase the leach rate.

  9. Open framework metal chalcogenides as efficient photocatalysts for reduction of CO2 into renewable hydrocarbon fuel.

    PubMed

    Sasan, Koroush; Lin, Qipu; Mao, Chengyu; Feng, Pingyun

    2016-06-07

    Open framework metal chalcogenides are a family of porous semiconducting materials with diverse chemical compositions. Here we show that these materials containing covalent three-dimensional superlattices of nanosized supertetrahedral clusters can function as efficient photocatalysts for the reduction of CO2 to CH4. Unlike dense semiconductors, metal cations are successfully incorporated into the channels of the porous semiconducting materials to further tune the physical properties of the materials such as electrical conductivity and band gaps. In terms of the photocatalytic properties, the metal-incorporated porous chalcogenides demonstrated enhanced solar energy absorption and higher electrical conductivity and improved photocatalytic activity.

  10. Method for removing organic liquids from aqueous solutions and mixtures

    DOEpatents

    Hrubesh, Lawrence W.; Coronado, Paul R.; Dow, Jerome P.

    2004-03-23

    A method for removing organic liquids from aqueous solutions and mixtures. The method employs any porous material preferably in granular form and having small pores and a large specific surface area, that is hydrophobic so that liquid water does not readily wet its surface. In this method, organics, especially organic solvents that mix with and are more volatile than water, are separated from aqueous solution by preferentially evaporating across the liquid/solid boundary formed at the surfaces of the hydrophobic porous materials. Also, organic solvents that are immiscible with water, preferentially wet the surfaces of the hydrophobic material and are drawn within the porous materials by capillary action.

  11. Properties of porous magnesium prepared by powder metallurgy.

    PubMed

    Čapek, Jaroslav; Vojtěch, Dalibor

    2013-01-01

    Porous magnesium-based materials are biodegradable and promising for use in orthopaedic applications, but their applications are hampered by their difficult fabrication. This work reports the preparation of porous magnesium materials by a powder metallurgy technique using ammonium bicarbonate as spacer particles. The porosity of the materials depended on the amount of ammonium bicarbonate and was found to have strong negative effects on flexural strength and corrosion behaviour. However, the flexural strength of materials with porosities of up to 28 vol.% was higher than the flexural strength of non-metallic biomaterials and comparable with that of natural bone. Copyright © 2012 Elsevier B.V. All rights reserved.

  12. Method for manufacturing an electrochemical cell

    DOEpatents

    Kaun, Thomas D.; Eshman, Paul F.

    1982-01-01

    A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

  13. 3D printed porous stainless steel for potential use in medicine

    NASA Astrophysics Data System (ADS)

    Fousová, M.; Kubásek, J.; Vojtěch, D.; Fojt, J.; Čapek, J.

    2017-02-01

    3D printing technologies like Selective Laser Melting (SLM) or Electron Beam Melting (EBM) produce components of very complicated shapes from various kinds of materials. In this work a highly porous (porosity of almost 90 vol. %) stainless steel component was manufactured by SLM. The material was characterized in terms of structure, surface chemistry and mechanical properties. It was observed that mechanical properties of the material were similar to those of trabecular human bone. The tests realized in this work confirmed suitability of the porous material prepared by SLM for the use in medicine, for example, for scaffolds designed to repair bone defects.

  14. Coordination Covalent Frameworks: A New Route for Synthesis and Expansion of Functional Porous Materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Elsaidi, Sameh K.; Mohamed, Mona H.; Loring, John S.

    The synthetic approaches for fine-tuning the structural properties of coordination polymers or metal organic frameworks have exponentially grown during the last decade. This is due to the control over the properties of the resulting structures such as stability, pore size, pore chemis-try and surface area for myriad possible applications. Herein, we present a new class of porous materials called Covalent Coordination Frameworks (CCFs) that were designed and effectively synthesized using a two-step reticular chemistry approach. During the first step, trigonal prismatic molecular building block was isolated using 4-aminobenazoic acid and Cr (III) salt, subsequently in the second step the polymerizationmore » of the isolated molecular building blocks (MBBs) takes place by the formation of strong covalent bonds where small organic molecules can connect the MBBs forming extended porous CCF materials. All the isolated CCFs were found to be permanently porous while the discrete MBB were non-porous. This approach would inevitably open a feasible path for the applications of reticular chemistry and the synthesis of novel porous materials with various topologies under ambient conditions using simple organic molecules and versatile MBBs with different functionalities which would not be possible using the traditional one step approach« less

  15. Effect of sintering conditions on the microstructural and mechanical characteristics of porous magnesium materials prepared by powder metallurgy.

    PubMed

    Čapek, Jaroslav; Vojtěch, Dalibor

    2014-02-01

    There has recently been an increased demand for porous magnesium materials in many applications, especially in the medical field. Powder metallurgy appears to be a promising approach for the preparation of such materials. Many works have dealt with the preparation of porous magnesium; however, the effect of sintering conditions on material properties has rarely been investigated. In this work, we investigated porous magnesium samples that were prepared by powder metallurgy using ammonium bicarbonate spacer particles. The effects of the purity of the argon atmosphere and sintering time on the microstructure (SEM, EDX and XRD) and mechanical behaviour (universal loading machine and Vickers hardness tester) of porous magnesium were studied. The porosities of the prepared samples ranged from 24 to 29 vol.% depending on the sintering conditions. The purity of atmosphere played a significant role when the sintering time exceeded 6h. Under a gettered argon atmosphere, a prolonged sintering time enhanced diffusion connections between magnesium particles and improved the mechanical properties of the samples, whereas under a technical argon atmosphere, oxidation at the particle surfaces caused deterioration in the mechanical properties of the samples. These results suggest that a refined atmosphere is required to improve the mechanical properties of porous magnesium. © 2013.

  16. Microbial ranking of porous packaging materials (exposure chamber method), ASTM method: collaborative study.

    PubMed

    Placencia, A M; Peeler, J T

    1999-01-01

    A collaborative study involving 11 laboratories was conducted to measure the microbial barrier effectiveness of porous medical packaging. Two randomly cut samples from each of 6 commercially available porous materials and one positive and one negative control were tested by one operator in each of 11 laboratories. Microbial barrier effectiveness was measured in terms of logarithm reduction value (LRV), which reflects the log10 microbial penetration of the material being tested. The logarithm of the final concentration is subtracted from that of the initial concentration to obtain the LRV. Thus the higher the LRV, the better the barrier. Repeatability standard deviations ranged from 6.42 to 16.40; reproducibility standard deviations ranged from 15.50 to 22.70. Materials B(53), C(50), D(CT), and E(45MF) differ significantly from the positive control. The microbial ranking of porous packaging materials (exposure chamber method), ASTM method, has been adopted First Action by AOAC INTERNATIONAL.

  17. Hierarchically Porous Carbon Materials for CO 2 Capture: The Role of Pore Structure

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Estevez, Luis; Barpaga, Dushyant; Zheng, Jian

    2018-01-17

    With advances in porous carbon synthesis techniques, hierarchically porous carbon (HPC) materials are being utilized as relatively new porous carbon sorbents for CO2 capture applications. These HPC materials were used as a platform to prepare samples with differing textural properties and morphologies to elucidate structure-property relationships. It was found that high microporous content, rather than overall surface area was of primary importance for predicting good CO2 capture performance. Two HPC materials were analyzed, each with near identical high surface area (~2700 m2/g) and colossally high pore volume (~10 cm3/g), but with different microporous content and pore size distributions, which ledmore » to dramatically different CO2 capture performance. Overall, large pore volumes obtained from distinct mesopores were found to significantly impact adsorption performance. From these results, an optimized HPC material was synthesized that achieved a high CO2 capacity of ~3.7 mmol/g at 25°C and 1 bar.« less

  18. Attachment system for silica tiles. [thermal protection for space shuttle orbiter

    NASA Technical Reports Server (NTRS)

    Dotts, R. L.; Holt, J. W. (Inventor)

    1982-01-01

    An improved method for markedly increasing the bond strength between a rigid, porous refractory material and non-rigid substrate by densifying the face of the rigid material opposing the substrate is discussed. Densification is accomplished by wetting the refractory material and then impregnating it with a composite slurry having a particle size to fill voids of the porous material.

  19. The Evaluation of Hydroxyapatite (HA) Coated and Uncoated Porous Tantalum for Biomedical Material Applications

    NASA Astrophysics Data System (ADS)

    Safuan, Nadia; Sukmana, Irza; Kadir, Mohammed Rafiq Abdul; Noviana, Deni

    2014-04-01

    Porous tantalum has been used as an orthopedic implant for bone defects as it has a good corrosion resistance and fatigue behaviour properties. However, there are some reports on the rejection of porous Ta after the implantation. Those clinical cases refer to the less bioactivity of metallic-based materials. This study aims to evaluate hydroxyapatite coated and uncoated porous Tantalum in order to improve the biocompatibility of porous tantalum implant and osseointegration. Porous tantalum was used as metallic-base substrate and hydroxyapatite coating has been done using plasma-spraying technique. Scanning Electron Microscopy (SEM) and Field Emission Scanning Electron Microscopy (FESEM) techniques were utilizes to investigate the coating characteristics while Confocal Raman Microscopy to investigate the interface and image. The effect of coating to the corrosion behaviour was assessed by employing potentiodynamic polarization tests in simulated body fluid at 37±1 °C. Based on SEM and FESEM results, the morphologies as well the weight element consists in the uncoated and hydroxyapatite coated porous tantalum were revealed. The results indicated that the decrease in corrosion current density for HA coated porous Ta compared to the uncoated porous Ta. This study concluded that by coating porous tantalum with HA supports to decrease the corrosion rate of pure porous.

  20. Effect Of Gravity On Porous Tricalcium Phosphate And Nonstoichiometric Titanium Carbide Produced Via Combustion Synthesis

    NASA Technical Reports Server (NTRS)

    Castillo, M.; Moore, J. J.; Schowengerdt, F. D.; Ayers, R. A.

    2003-01-01

    Novel processing techniques, such as self-propagating high temperature synthesis (SHS), have the capability to rapidly produce advanced porous materials that are difficult to fabricate by other methods. This processing technique is also capable of near net shape synthesis, while variable gravity allows the manipulation of the structure and composition of the material. The creation of porous tricalcium phosphate (TCP) is advantageous in the biomaterials field, since it is both a biocompatible material and an osteoconductive material. Porous tricalcium phosphate produced via SHS is an excellent candidate for bone scaffold material in the bone regeneration process. The porosity allows for great vascularization and ingrowth of tissue. Titanium Carbide is a nonstoichiometric biocompatible material that can be incorporated into a TiC-Ti composite system using combustion synthesis. The TiC-Ti composite exhibits a wide range of mechanical and chemical properties. Both of these material systems (TCP and TiC-Ti) can be used to advantage in designing novel bone replacement materials. Gravity plays an important role in both the pore structure and the chemical uniformity of these composite systems and offers considerable potential in advanced bone engineering.

  1. Gas storage materials, including hydrogen storage materials

    DOEpatents

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  2. Gas storage materials, including hydrogen storage materials

    DOEpatents

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  3. Modelling of Imbibition Phenomena in Fluid Flow through Heterogeneous Inclined Porous Media with different porous materials

    NASA Astrophysics Data System (ADS)

    Patel, Hardik S.; Meher, Ramakanta

    2017-12-01

    In this paper, the counter - current imbibition phenomenon is discussed in an inclined heterogeneous porous media with the consideration of two types of porous materials like volcanic sand and fine sand. Adomian decomposition method is applied to find the saturation of wetting phase and the recovery rate of the reservoir. Finally, a simulation result is developed to study the saturation of wetting phase and the optimum recovery rate of reservoir with the choices of some interesting parametric values. This problem has a great importance in the field of oil recovery process.

  4. Investigating the binding properties of porous drug delivery systems using nuclear sensors (radiotracers) and positron annihilation lifetime spectroscopy--predicting conditions for optimum performance.

    PubMed

    Mume, Eskender; Lynch, Daniel E; Uedono, Akira; Smith, Suzanne V

    2011-06-21

    Understanding how the size, charge and number of available pores in porous material influences the uptake and release properties is important for optimising their design and ultimately their application. Unfortunately there are no standard methods for screening porous materials in solution and therefore formulations must be developed for each encapsulated agent. This study investigates the potential of a library of radiotracers (nuclear sensors) for assessing the binding properties of hollow silica shell materials. Uptake and release of Cu(2+) and Co(2+) and their respective complexes with polyazacarboxylate macrocycles (dota and teta) and a series of hexa aza cages (diamsar, sarar and bis-(p-aminobenzyl)-diamsar) from the hollow silica shells was monitored using their radioisotopic analogues. Coordination chemistry of the metal (M) species, subtle alterations in the molecular architecture of ligands (Ligand) and their resultant complexes (M-Ligand) were found to significantly influence their uptake over pH 3 to 9 at room temperature. Positively charged species were selectively and rapidly (within 10 min) absorbed at pH 7 to 9. Negatively charged species were preferentially absorbed at low pH (3 to 5). Rates of release varied for each nuclear sensor, and time to establish equilibrium varied from minutes to days. The subtle changes in design of the nuclear sensors proved to be a valuable tool for determining the binding properties of porous materials. The data support the development of a library of nuclear sensors for screening porous materials for use in optimising the design of porous materials and the potential of nuclear sensors for high through-put screening of materials.

  5. Method of tissue repair using a composite material

    DOEpatents

    Hutchens, Stacy A.; Woodward, Jonathan; Evans, Barbara R.; O'Neill, Hugh M.

    2016-03-01

    A composite biocompatible hydrogel material includes a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa. A calcium comprising salt is disposed in at least some of the pores. The porous polymer matrix can comprise cellulose, including bacterial cellulose. The composite can be used as a bone graft material. A method of tissue repair within the body of animals includes the steps of providing a composite biocompatible hydrogel material including a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa, and inserting the hydrogel material into cartilage or bone tissue of an animal, wherein the hydrogel material supports cell colonization in vitro for autologous cell seeding.

  6. Method of tissue repair using a composite material

    DOEpatents

    Hutchens, Stacy A; Woodward, Jonathan; Evans, Barbara R; O'Neill, Hugh M

    2014-03-18

    A composite biocompatible hydrogel material includes a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa. A calcium comprising salt is disposed in at least some of the pores. The porous polymer matrix can comprise cellulose, including bacterial cellulose. The composite can be used as a bone graft material. A method of tissue repair within the body of animals includes the steps of providing a composite biocompatible hydrogel material including a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa, and inserting the hydrogel material into cartilage or bone tissue of an animal, wherein the hydrogel material supports cell colonization in vitro for autologous cell seeding.

  7. Klinkenberg effect in hydrodynamics of gas flow through anisotropic porous materials

    NASA Astrophysics Data System (ADS)

    Wałowski, Grzegorz; Filipczak, Gabriel

    2017-10-01

    This study discusses results of experiments on hydrodynamic assessment of gas flow through backbone (skeletal) porous materials with an anisotropic structure. The research was conducted upon materials of diversified petrographic characteristics, both natural origin (rocky, pumice) and process materials (char and coke). The study was conducted for a variety of hydrodynamic conditions, using air, as well as for nitrogen and carbon dioxide. The basis for assessing hydrodynamics of gas flow through porous material was a gas stream that results from the pressure forcing such flow. The results of measurements indicate a clear impact of the type of material on the gas permeability, and additionally - as a result of their anisotropic internal structure - to a significant effect of the flow direction on the value of gas stream.

  8. A novel and facile synthesis approach for a porous carbon/graphene composite for high-performance supercapacitors.

    PubMed

    Liu, Ting; Zhang, Xuesha; Liu, Kang; Liu, Yanyan; Liu, Mengjie; Wu, Wenyu; Gu, Yu; Zhang, Ruijun

    2018-03-02

    We propose a novel and facile synthesis approach to a porous carbon/graphene composite. Graphene is obtained from room-temperature expanded graphite (RTEG), not involving the use of graphite oxide (GO). Porous carbon is acquired by carbonization and KOH-activation of polyvinylpyrrolidone (PVP), which is used to exfoliate RTEG into graphene and inhibit the restacking of the resultant graphene in the present work. The prepared porous carbon/graphene composite has a high specific surface area (SSA) (3008 m 2 g -1 ) and a hierarchical micro- and meso- pore structure (dominant pores in the range of 1-5 nm). Electrochemical measurement demonstrates that the as-prepared porous carbon/graphene composite can deliver an outstanding specific capacitance of up to 340 F g -1 at 5 mV s -1 in 6 M KOH electrolyte. This specific capacitance is among the highest reported so far for porous carbon/graphene materials. Moreover, the prepared composite as an electrode material also exhibits excellent cycling stability (94.4% capacitance retention over 10 000 cycles). The as-fabricated symmetrical supercapacitor exhibits a high energy density of 10.9 W h kg -1 (based on total mass of electrode materials) and an outstanding energy density retention, even at high power density. Compared with conventional preparation routes for porous carbon/graphene composites, the present approach is significantly simple, convenient and cost-effective, which will make it more competent in the development of electrode materials for high-performance supercapacitors.

  9. Propagation of acoustic waves in a one-dimensional macroscopically inhomogeneous poroelastic material.

    PubMed

    Gautier, G; Kelders, L; Groby, J P; Dazel, O; De Ryck, L; Leclaire, P

    2011-09-01

    Wave propagation in macroscopically inhomogeneous porous materials has received much attention in recent years. The wave equation, derived from the alternative formulation of Biot's theory of 1962, was reduced and solved recently in the case of rigid frame inhomogeneous porous materials. This paper focuses on the solution of the full wave equation in which the acoustic and the elastic properties of the poroelastic material vary in one-dimension. The reflection coefficient of a one-dimensional macroscopically inhomogeneous porous material on a rigid backing is obtained numerically using the state vector (or the so-called Stroh) formalism and Peano series. This coefficient can then be used to straightforwardly calculate the scattered field. To validate the method of resolution, results obtained by the present method are compared to those calculated by the classical transfer matrix method at both normal and oblique incidence and to experimental measurements at normal incidence for a known two-layers porous material, considered as a single inhomogeneous layer. Finally, discussion about the absorption coefficient for various inhomogeneity profiles gives further perspectives. © 2011 Acoustical Society of America

  10. Method of making dense, conformal, ultra-thin cap layers for nanoporous low-k ILD by plasma assisted atomic layer deposition

    DOEpatents

    Jiang, Ying-Bing [Albuquerque, NM; Cecchi, Joseph L [Albuquerque, NM; Brinker, C Jeffrey [Albuquerque, NM

    2011-05-24

    Barrier layers and methods for forming barrier layers on a porous layer are provided. The methods can include chemically adsorbing a plurality of first molecules on a surface of the porous layer in a chamber and forming a first layer of the first molecules on the surface of the porous layer. A plasma can then be used to react a plurality of second molecules with the first layer of first molecules to form a first layer of a barrier layer. The barrier layers can seal the pores of the porous material, function as a diffusion barrier, be conformal, and/or have a negligible impact on the overall ILD k value of the porous material.

  11. Porous graphene materials for water remediation.

    PubMed

    Niu, Zhiqiang; Liu, Lili; Zhang, Li; Chen, Xiaodong

    2014-09-10

    Water remediation has been a critical issue over the past decades due to the expansion of wastewater discharge to the environment. Currently, a variety of functional materials have been successfully prepared for water remediation applications. Among them, graphene is an attractive candidate due to its high specific surface area, tunable surface behavior, and high strength. This Concept paper summarizes the design strategy of porous graphene materials and their applications in water remediation, such as the cleanup of oil, removal of heavy metal ions, and elimination of water soluble organic contaminants. The progress made so far will guide further development in structure design strategy of porous materials based on graphene and exploration of such materials in environmental remediation. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Method and apparatus for measuring surface changes, in porous materials, using multiple differently-configured acoustic sensors

    DOEpatents

    Hietala, Susan Leslie; Hietala, Vincent Mark; Tigges, Chris Phillip

    2001-01-01

    A method and apparatus for measuring surface changes, such as mass uptake at various pressures, in a thin-film material, in particular porous membranes, using multiple differently-configured acoustic sensors.

  13. In situ vibrational spectroscopy of adsorbed nitrogen in porous carbon materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ray, Paramita; Xu, Enshi; Crespi, Vincent H.

    This study uses in situ vibrational spectroscopy to probe nitrogen adsorption to porous carbon materials, including single-wall carbon nanotubes and Maxsorb super-activated carbon, demonstrating how the nitrogen Raman stretch mode is perturbed by adsorption.

  14. In situ vibrational spectroscopy of adsorbed nitrogen in porous carbon materials

    DOE PAGES

    Ray, Paramita; Xu, Enshi; Crespi, Vincent H.; ...

    2018-01-01

    This study uses in situ vibrational spectroscopy to probe nitrogen adsorption to porous carbon materials, including single-wall carbon nanotubes and Maxsorb super-activated carbon, demonstrating how the nitrogen Raman stretch mode is perturbed by adsorption.

  15. Reconnaissance of the geology and ground-water resources in the Aurora area, St. Louis county, Minnesota

    USGS Publications Warehouse

    Maclay, Robert W.

    1966-01-01

    Ground water from the unconsolidated deposits is hard and commonly contains large, undesirable amounts of iron and manganese. Water from the 'bedrock aquifers contains less iron and manganese than does water from the unconsolidated deposits.

  16. Structural parameter effect of porous material on sound absorption performance of double-resonance material

    NASA Astrophysics Data System (ADS)

    Fan, C.; Tian, Y.; Wang, Z. Q.; Nie, J. K.; Wang, G. K.; Liu, X. S.

    2017-06-01

    In view of the noise feature and service environment of urban power substations, this paper explores the idea of compound impedance, fills some porous sound-absorption material in the first resonance cavity of the double-resonance sound-absorption material, and designs a new-type of composite acoustic board. We conduct some acoustic characterizations according to the standard test of impedance tube, and research on the influence of assembly order, the thickness and area density of the filling material, and back cavity on material sound-absorption performance. The results show that the new-type of acoustic board consisting of aluminum fibrous material as inner structure, micro-porous board as outer structure, and polyester-filled space between them, has good sound-absorption performance for low frequency and full frequency noise. When the thickness, area density of filling material and thickness of back cavity increase, the sound absorption coefficient curve peak will move toward low frequency.

  17. Microstructural and mechanical characteristics of porous iron prepared by powder metallurgy.

    PubMed

    Capek, Jaroslav; Vojtěch, Dalibor

    2014-10-01

    The demand for porous biodegradable load-bearing implants has been increasing recently. Based on investigations of biodegradable stents, porous iron may be a suitable material for such applications. In this study, we prepared porous iron samples with porosities of 34-51 vol.% by powder metallurgy using ammonium bicarbonate as a space-holder material. We studied sample microstructure (SEM-EDX and XRD), flexural and compressive behaviors (universal loading machine) and hardness HV5 (hardness tester) of the prepared samples. Sample porosity increased with the amount of spacer in the initial mixtures. Only the pore surfaces had insignificant oxidation and no other contamination was observed. Increasing porosity decreased the mechanical properties of the samples; although, the properties were still comparable with human bone and higher than those of porous non-metallic biomaterials and porous magnesium prepared in a similar way. Based on these results, powder metallurgy appears to be a suitable method for the preparation of porous iron for orthopedic applications. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Structural characterization of porous low-k thin films prepared by different techniques using x-ray porosimetry

    NASA Astrophysics Data System (ADS)

    Lee, Hae-Jeong; Soles, Christopher L.; Liu, Da-Wei; Bauer, Barry J.; Lin, Eric K.; Wu, Wen-li; Grill, Alfred

    2004-03-01

    Three different types of porous low-k dielectric films, with similar dielectric constants, are characterized using x-ray porosimetry (XRP). XRP is used to extract critical structural information, such as the average density, wall density, porosity, and pore size distribution. The materials include a plasma-enhanced-chemical-vapor-deposited carbon-doped oxide film composed of Si, C, O, and H (SiCOH) and two spin cast silsesquioxane type films—methylsilsesquioxane with a polymeric porogen (porous MSQ) and hydrogensilsesquioxane with a high boiling point solvent (porous HSQ). The porous SiCOH film displays the smallest pore sizes, while porous HSQ film has both the highest density wall material and porosity. The porous MSQ film exhibits a broad range of pores with the largest average pore size. We demonstrate that the average pore size obtained by the well-established method of neutron scattering and x-ray reflectivity is in good agreement with the XRP results.

  19. Evaluation of Toluene Adsorption Performance of Mortar Adhesives Using Porous Carbon Material as Adsorbent

    PubMed Central

    Chang, Seong Jin; Jeong, Su-Gwang; Lee, Jongki; Kim, Taeyeon; Park, Kyung-Won; Lee, Dong Ryeol; Kim, Sumin

    2017-01-01

    Porous carbon materials are advantageous in adsorbing pollutants due to their wide range of specific surface areas, pore diameter, and pore volume. Among the porous carbon materials in the current study, expanded graphite, xGnP, xGnP C-300, xGnP C-500, and xGnP C-750 were prepared as adsorbent materials. Brunauer–Emmett–Teller (BET) analysis was conducted to select the adsorbent material through the analysis of the specific surface area, pore size, and pore volume of the prepared porous carbon materials. Morphological analysis using SEM was also performed. The xGnP C-500 as adsorbent material was applied to a mortar adhesive that is widely used in the installation of interior building materials. The toluene adsorption performances of the specimens were evaluated using 20 L small chamber. Furthermore, the performance of the mortar adhesive, as indicated by the shear bond strength, length change rate, and water retention rate, was analyzed according to the required test method specified in the Korean standards. It was confirmed that for the mortar adhesives prepared using the xGnP C-500 as adsorbent material, the toluene adsorption performance was excellent and satisfied the required physical properties. PMID:28773214

  20. Porous silicon based anode material formed using metal reduction

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anguchamy, Yogesh Kumar; Masarapu, Charan; Deng, Haixia

    A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m.sup.2/g to about 200 m.sup.2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V tomore » 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm.sup.2 to about 3.5 mg/cm.sup.2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.« less

  1. Mixed Cassie-Baxter wetting states on a porous material stabilized by electrowetting

    NASA Astrophysics Data System (ADS)

    Lambert, Jérôme; Gauchet, Lucien; Crassous, Jérôme

    2017-07-01

    Electrowetting is used to force imbibition in model porous plates. These porous plates are sintered disordered bronze bead packings that are homogeneously coated with a constant-thickness layer of parylene. Cycles of increasing and decreasing voltage trigger the imbibition of a ionized water sessile drop by changing its contact angle with the porous material from non-wetting to wetting shapes. During a cycle, a drop experiences partial imbibition and a strong hysteresis of its contact angle with the porous plate. Since the imbibition process quickly stabilizes, we adopt an equilibrium description of the wetting properties of the drop on the porous plate. Our model, based on the Cassie-Baxter approach, shows that three different wetting states are experienced by the drop, one of which being made possible only by the modification of the contact angle inside the pores. Our model describes the experimental results very well.

  2. Molecular Blends of Methylated-Poly(ethylenimine) and Amorphous Porous Organic Cages for SO 2 Adsorption

    DOE PAGES

    Zhu, Guanghui; Carrillo, Jan-Michael Y.; Sujan, Achintya; ...

    2018-05-30

    Porous organic cages (POCs) are emerging porous materials that exhibit intriguing properties in the areas of self-assembly, host-guest interaction, and solution processability. Here in this work, we explore the applicability of POCs as molecular porous supports for polymeric amines. We find that primary amines in poly(ethylenimine) (PEI) can undergo metathesis with the imine bonds present in POCs, resulting in non-porous products. This problem can be overcome by transforming the primary amines in PEI to tertiary amines via methylation. The methylated PEI (mPEI) forms homogeneous composites with amorphous scrambled porous organic cages (ASPOCs) without undesired reactions or phase separation. The microscopicmore » structure of the composites is studied using molecular dynamics simulations. Finally, these composite materials are evaluated as adsorbents for low concentration SO2 (200 ppm) adsorption and show good thermal and cyclic stability.« less

  3. Molecular Blends of Methylated-Poly(ethylenimine) and Amorphous Porous Organic Cages for SO 2 Adsorption

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhu, Guanghui; Carrillo, Jan-Michael Y.; Sujan, Achintya

    Porous organic cages (POCs) are emerging porous materials that exhibit intriguing properties in the areas of self-assembly, host-guest interaction, and solution processability. Here in this work, we explore the applicability of POCs as molecular porous supports for polymeric amines. We find that primary amines in poly(ethylenimine) (PEI) can undergo metathesis with the imine bonds present in POCs, resulting in non-porous products. This problem can be overcome by transforming the primary amines in PEI to tertiary amines via methylation. The methylated PEI (mPEI) forms homogeneous composites with amorphous scrambled porous organic cages (ASPOCs) without undesired reactions or phase separation. The microscopicmore » structure of the composites is studied using molecular dynamics simulations. Finally, these composite materials are evaluated as adsorbents for low concentration SO2 (200 ppm) adsorption and show good thermal and cyclic stability.« less

  4. Geology of the San Francisco Peaks, Northern Arizona.

    DTIC Science & Technology

    geology of the volcanic rocks and ash and (2) surficial geology, the study of the unconsolidated fluvial, glacial, periglacial and mass movement... sediments derived from the San Francisco Peaks volcanics. The study of the consolidated and unconsolidated rocks provides the basis for inferences on the

  5. Numerical Analysis of a Class of THM Coupled Model for Porous Materials

    NASA Astrophysics Data System (ADS)

    Liu, Tangwei; Zhou, Jingying; Lu, Hongzhi

    2018-01-01

    We consider the coupled models of the Thermo-hydro-mechanical (THM) problem for porous materials which arises in many engineering applications. Firstly, mathematical models of the THM coupled problem for porous materials were discussed. Secondly, for different cases, some numerical difference schemes of coupled model were constructed, respectively. Finally, aassuming that the original water vapour effect is neglectable and that the volume fraction of liquid phase and the solid phase are constants, the nonlinear equations can be reduced to linear equations. The discrete equations corresponding to the linear equations were solved by the Arnodli method.

  6. Transient Infrared Measurement of Laser Absorption Properties of Porous Materials

    NASA Astrophysics Data System (ADS)

    Marynowicz, Andrzej

    2016-06-01

    The infrared thermography measurements of porous building materials have become more frequent in recent years. Many accompanying techniques for the thermal field generation have been developed, including one based on laser radiation. This work presents a simple optimization technique for estimation of the laser beam absorption for selected porous building materials, namely clinker brick and cement mortar. The transient temperature measurements were performed with the use of infrared camera during laser-induced heating-up of the samples' surfaces. As the results, the absorbed fractions of the incident laser beam together with its shape parameter are reported.

  7. Immobilization of Bacillus subtilis lipase on a Cu-BTC based hierarchically porous metal-organic framework material: a biocatalyst for esterification.

    PubMed

    Cao, Yu; Wu, Zhuofu; Wang, Tao; Xiao, Yu; Huo, Qisheng; Liu, Yunling

    2016-04-28

    Bacillus subtilis lipase (BSL2) has been successfully immobilized into a Cu-BTC based hierarchically porous metal-organic framework material for the first time. The Cu-BTC hierarchically porous MOF material with large mesopore apertures is prepared conveniently by using a template-free strategy under mild conditions. The immobilized BSL2 presents high enzymatic activity and perfect reusability during the esterification reaction. After 10 cycles, the immobilized BSL2 still exhibits 90.7% of its initial enzymatic activity and 99.6% of its initial conversion.

  8. [Preparation of elastic porous cell scaffold fabricated with combined polydimethylsiloxane (PDMS) and hydroxyapatite (HA)].

    PubMed

    Yang, Yang; Lan, Ding; Huang, Yan; Li, Yanming; Wang, Yuren; Sun, Lianwen; Fan, Yubo

    2014-06-01

    Polydimethylsiloxane (PDMS) and hydroxyapatite (HA) were combined in our laboratory to fabricate an elastic porous cell scaffold with pore-forming agent, and then the scaffold was used as culture media for rat bone marrow derived mesenchymal stem cells (rBMSCs). Different porous materials (square and circular in shape) were prepared by different pore-forming agents (NaCl or paraffin spheres) with adjustable porosity (62%-76%). The HA crystals grew on the wall of hole when the material was exposed to SBF solutions, showing its biocompatibility and ability to support the cells to attach on the materials.

  9. Effect of Steam Activation on Development of Light Weight Biomorphic Porous SiC from Pine Wood Precursor

    NASA Astrophysics Data System (ADS)

    Manocha, Satish M.; Patel, Hemang; Manocha, L. M.

    2013-02-01

    Biomorphic SiC materials with tailor-made microstructure and properties similar to ceramic materials manufactured by conventional method are a new class of materials derived from natural biopolymeric cellulose templates (wood). Porous silicon carbide (SiC) ceramics with wood-like microstructure have been prepared by carbothermal reduction of charcoal/silica composites at 1300-1600 °C in inert Ar atmosphere. The C/SiO2 composites were fabricated by infiltrating silica sol into porous activated biocarbon template. Silica in the charcoal/silica composite, preferentially in the cellular pores, was found to get transformed in forms of fibers and rods due to shrinkage during drying. The changes in the morphology of resulting porous SiC ceramics after heat treatment to 1600 °C, as well as the conversion mechanism of wood to activated carbon and then to porous SiC ceramic have been investigated using scanning electron microscope, x-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Activation of carbon prior to silica infiltration has been found to enhance conversion of charcoal to SiC. The pore structure is found to be uniform in these materials than in those made from as-such charcoal/silica composites. This provides a low-cost and eco-friendly route to advanced ceramic materials, with near-net shape potential.

  10. Electrodes for microfluidic applications

    DOEpatents

    Crocker, Robert W [Fremont, CA; Harnett, Cindy K [Livermore, CA; Rognlien, Judith L [Livermore, CA

    2006-08-22

    An electrode device for high pressure applications. These electrodes, designed to withstand pressure of greater than 10,000 psi, are adapted for use in microfluidic devices that employ electrokinetic or electrophoretic flow. The electrode is composed, generally, of an outer electrically insulating tubular body having a porous ceramic frit material disposed in one end of the outer body. The pores of the porous ceramic material are filled with an ion conductive polymer resin. A conductive material situated on the upper surface of the porous ceramic frit material and, thus isolated from direct contact with the electrolyte, forms a gas diffusion electrode. A metal current collector, in contact with the gas diffusion electrode, provides connection to a voltage source.

  11. Heat transfer enhancement of flow insulator by combined stainless steel fibrous and wire net porous materials

    NASA Astrophysics Data System (ADS)

    Khantikomol, P.; Polsongkram, M.; Apisitpinyo, W.; Poowadin, T.

    2018-01-01

    The present research article aims to propose the heat transfer enhancement of the flow insulator using combined fibrous and wire net stainless steel porous material. The stainless fibrous plate with porosity of 0.9292 was combined to the stainless steel wire net having pore per inch (PPI) of 16 and total thickness of 30 mm. Two models of the arranging porous plates were prepared, which were model BA and model AB. Each porous plate segment had the same thickness. The examined porous plate model have porosities of 0.8452. The porous plate was placed normal to the flow direction. The air was used as working fluid heated by 5 kW electric heater, which was controlled by the automatic temperature control. Type-K thermocouples were employed to measure the air temperatures. The temperature at front of the porous plate was varied to be 350, 450, and 550°C. The air flow rate was varied in the range of 4-12 m3/hr. The experimental result showed that the temperature drop across the porous plate and the thermal efficiency increase with the inlet temperature. The air velocity slightly affects the temperature profile inside the test section at the upstream side of the porous plate but greatly affects temperature inside the porous plate. In consideration of the arranging porous plate, placing of the stainless steel wire net at the upstream side and placing the stainless steel fibrous at downstream side (model BA) results in the highest temperature drop and the highest thermal efficiency. At Re 733 and inlet temperature 550°C for model BA at 30 mm thickness, the thermal efficiency was 50%. It was shown that the combined stainless steel fibrous and stainless steel wire net porous material could be a good flow insulator.

  12. Fabrication and evaluation of interconnected porous carbonate apatite from alpha tricalcium phosphate spheres.

    PubMed

    Ishikawa, Kunio; Arifta, Tya Indah; Hayashi, Koichiro; Tsuru, Kanji

    2018-03-26

    Carbonate apatite (CO 3 Ap) blocks have attracted considerable attention as an artificial bone substitute material because CO 3 Ap is a component of and shares properties with bone, including high osteoconductivity and replacement by bone similar to autografts. In this study, we fabricated an interconnected porous CO 3 Ap block using α-tricalcium phosphate (TCP) spheres and evaluated the tissue response to this material in a rabbit tibial bone defect model. Interconnected porous α-TCP, the precursor of interconnected porous CO 3 Ap, could not be fabricated directly by sintering α-TCP spheres. It was therefore made via a setting reaction with α-TCP spheres, yielding interconnected porous calcium-deficient hydroxyapatite that was subjected to heat treatment. Immersing the interconnected porous α-TCP in Na-CO 3 -PO 4 solution produced CO 3 Ap, which retained the interconnected porous structure after the dissolution-precipitation reaction. The diametral tensile strength and porosity of the porous CO 3 Ap were 1.8 ± 0.4 MPa and 55% ± 3.2%, respectively. Both porous and dense (control) CO 3 Ap showed excellent tissue response and good osteoconductivity. At 4 weeks after surgery, approximately 15% ± 4.9% of the tibial bone defect was filled with new bone when reconstruction was performed using porous CO 3 Ap; this amount was five times greater than that obtained with dense CO 3 Ap. At 12 weeks after surgery, for porous CO 3 Ap, approximately 47% of the defect was filled with new bone as compared to 16% for dense CO 3 Ap. Thus, the interconnected porous CO 3 Ap block is a promising artificial bone substitute material for the treatment of bone defects caused by large fractures or bone tumor resection. © 2018 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2018. © 2018 Wiley Periodicals, Inc.

  13. Porous Shape Memory Polymers

    PubMed Central

    Hearon, Keith; Singhal, Pooja; Horn, John; Small, Ward; Olsovsky, Cory; Maitland, Kristen C.; Wilson, Thomas S.; Maitland, Duncan J.

    2013-01-01

    Porous shape memory polymers (SMPs) include foams, scaffolds, meshes, and other polymeric substrates that possess porous three-dimensional macrostructures. Porous SMPs exhibit active structural and volumetric transformations and have driven investigations in fields ranging from biomedical engineering to aerospace engineering to the clothing industry. The present review article examines recent developments in porous SMPs, with focus given to structural and chemical classification, methods of characterization, and applications. We conclude that the current body of literature presents porous SMPs as highly interesting smart materials with potential for industrial use. PMID:23646038

  14. Constitutive model for porous materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weston, A.M.; Lee, E.L.

    1982-01-01

    A simple pressure versus porosity compaction model is developed to calculate the response of granular porous bed materials to shock impact. The model provides a scheme for calculating compaction behavior when relatively limited material data are available. While the model was developed to study porous explosives and propellants, it has been applied to a much wider range of materials. The early development of porous material models, such as that of Hermann, required empirical dynamic compaction data. Erkman and Edwards successfully applied the early theory to unreacted porous high explosives using a Gruneisen equation of state without yield behavior and withoutmore » trapped gas in the pores. Butcher included viscoelastic rate dependance in pore collapse. The theoretical treatment of Carroll and Holt is centered on the collapse of a circular pore and includes radial inertia terms and a complex set of stress, strain and strain rate constitutive parameters. Unfortunately data required for these parameters are generally not available. The model described here is also centered on the collapse of a circular pore, but utilizes a simpler elastic-plastic static equilibrium pore collapse mechanism without strain rate dependence, or radial inertia terms. It does include trapped gas inside the pore, a solid material flow stress that creates both a yield point and a variation in solid material pressure with radius. The solid is described by a Mie-Gruneisen type EOS. Comparisons show that this model will accurately estimate major mechanical features which have been observed in compaction experiments.« less

  15. Utilization of Porous Media for Condensing Heat Exchangers

    NASA Technical Reports Server (NTRS)

    Tuan, George C.

    2006-01-01

    The use of porous media as a mean of separating liquid condensate from the air stream in condensing heat exchangers has been explored in the past inside small plant growth chambers and in the Apollo Command Module. Both applications used a cooled porous media made of sintered stainless steel to cool and separate condensation from the air stream. However, the main issues with the utilization of porous media in the past have been the deterioration of the porous media over long duration, such as clogging and changes in surface wetting characteristics. In addition, for long duration usage, biofilm growth from microorganisms on the porous medial would also be an issue. In developing Porous Media Condensing Heat Exchangers (PMCHX) for future space applications, different porous materials and microbial growth control methods will need to be explored. This paper explores the work performed at JSC and GRC to evaluate different porous materials and microbial control methods to support the development of a Porous Media Condensing Heat Exchanger. It outlines the basic principles for designing a PMCHX and issues that were encountered and ways to resolve those issues. The PMCHX has potential of mass, volume, and power savings over current CHX and water separator technology and would be beneficial for long duration space missions.

  16. Water resources of the Kodiak-Shelikof subregion, south-central Alaska

    USGS Publications Warehouse

    Jones, Stanley H.; Madison, R.J.; Zenone, Chester

    1978-01-01

    Hydrologic data for the Kodiak-Shelikof subregion of south-central Alaska are summarized to provide a basis for planning water resources development, identifying water problems and evaluating existing water quality and availability. Average annual precipitation, measured at a few coastal locations in this maritime climatic zone, ranges from 23 to 127 inches. Mean annual runoff for the Kodiak Island group ranges from 4 to 8 cfs/sq mi. A maximum instantaneous runoff of 457 cfs/sq mi has been determined from a small basin on Kodiak Island. Lowest measured stream discharges range from no flow to 0.91 cfs/sq mi. Surface water is the primary source of water supplies for the city of Kodiak and other communities. The geology of the subregion is characterized by metamorphosed sedimentary and volcanic rocks with only a thin mantle of unconsolidated material. A few small, alluvium-filled coastal valleys offer the most favorable conditions for ground-water development, but moderate yields (50-100 gal/min) have been obtained from wells in fractured bedrock. Water in streams and lakes generally has a dissolved-solids concentration less than 60 mg/L, and the water varies from a calcium-bicarbonate type to a sodium-chloride type. The chemical composition of ground waters has a dilute calcium-bicarbonate type in unconsolidated materials and a sodium-bicarbonate type in bedrock. The dissolved solids in the groundwater ranges from 170 to 250 mg/L. (Woodard-USGS)

  17. Dynamic Compressibility of High-Porosity Dampers of Thermal and Shock Loadings:. Modeling and Experiment

    NASA Astrophysics Data System (ADS)

    Bragov, Anatoly; Konstantinov, Alexander; Lomunov, Andrey; Sadyrin, Anatoly; Sergeichev, Ivan; Kruszka, Leopold

    High-porosity materials, such as chamotte and mullite, possess a heat of fusion. Owing to their properties, these materials can be used with success as damping materials in containers for airplane, automobile, etc. transportation of radioactive or highly toxic materials. Experimental studies of the dynamic properties have been executed with using some original modifications of the Kolsky method. These modified experiments have allowed studying the dynamic compressibility of high-porosity chamotte at deformations up to 80% and amplitudes up to 50 MPa. The equations of the mathematical model describing shock compacting of chamotte as a highly porous, fragile, collapsing material are presented. Deformation of high-porous materials at non-stationary loadings is usually accompanied by fragile destruction of interpore partitions as observed in other porous ceramic materials. Comparison of numerical and experimental results has shown their good conformity.

  18. Lithium air batteries having ether-based electrolytes

    DOEpatents

    Amine, Khalil; Curtiss, Larry A.; Lu, Jun; Lau, Kah Chun; Zhang, Zhengcheng; Sun, Yang-Kook

    2016-10-25

    A lithium-air battery includes a cathode including a porous active carbon material, a separator, an anode including lithium, and an electrolyte including a lithium salt and polyalkylene glycol ether, where the porous active carbon material is free of a metal-based catalyst.

  19. Li-air batteries having ether-based electrolytes

    DOEpatents

    Amine, Khalil; Curtiss, Larry A; Lu, Jun; Lau, Kah Chun; Zhang, Zhengcheng; Sun, Yang-Kook

    2015-03-03

    A lithium-air battery includes a cathode including a porous active carbon material, a separator, an anode including lithium, and an electrolyte including a lithium salt and polyalkylene glycol ether, where the porous active carbon material is free of a metal-based catalyst.

  20. Porous polymeric materials for hydrogen storage

    DOEpatents

    Yu, Luping [Hoffman Estates, IL; Liu, Di-Jia [Naperville, IL; Yuan, Shengwen [Chicago, IL; Yang, Junbing [Westmont, IL

    2011-12-13

    Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

  1. Porous polymeric materials for hydrogen storage

    DOEpatents

    Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

    2013-04-02

    A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

  2. Construction of porous cationic frameworks by crosslinking polyhedral oligomeric silsesquioxane units with N-heterocyclic linkers

    NASA Astrophysics Data System (ADS)

    Chen, Guojian; Zhou, Yu; Wang, Xiaochen; Li, Jing; Xue, Shuang; Liu, Yangqing; Wang, Qian; Wang, Jun

    2015-06-01

    In fields of materials science and chemistry, ionic-type porous materials attract increasing attention due to significant ion-exchanging capacity for accessing diversified applications. Facing the fact that porous cationic materials with robust and stable frameworks are very rare, novel tactics that can create new type members are highly desired. Here we report the first family of polyhedral oligomeric silsesquioxane (POSS) based porous cationic frameworks (PCIF-n) with enriched poly(ionic liquid)-like cationic structures, tunable mesoporosities, high surface areas (up to 1,025 m2 g-1) and large pore volumes (up to 0.90 cm3 g-1). Our strategy is designing the new rigid POSS unit of octakis(chloromethyl)silsesquioxane and reacting it with the rigid N-heterocyclic cross-linkers (typically 4,4‧-bipyridine) for preparing the desired porous cationic frameworks. The PCIF-n materials possess large surface area, hydrophobic and special anion-exchanging property, and thus are used as the supports for loading guest species PMo10V2O405- the resultant hybrid behaves as an efficient heterogeneous catalyst for aerobic oxidation of benzene and H2O2-mediated oxidation of cyclohexane.

  3. Construction of porous cationic frameworks by crosslinking polyhedral oligomeric silsesquioxane units with N-heterocyclic linkers

    PubMed Central

    Chen, Guojian; Zhou, Yu; Wang, Xiaochen; Li, Jing; Xue, Shuang; Liu, Yangqing; Wang, Qian; Wang, Jun

    2015-01-01

    In fields of materials science and chemistry, ionic-type porous materials attract increasing attention due to significant ion-exchanging capacity for accessing diversified applications. Facing the fact that porous cationic materials with robust and stable frameworks are very rare, novel tactics that can create new type members are highly desired. Here we report the first family of polyhedral oligomeric silsesquioxane (POSS) based porous cationic frameworks (PCIF-n) with enriched poly(ionic liquid)-like cationic structures, tunable mesoporosities, high surface areas (up to 1,025 m2 g−1) and large pore volumes (up to 0.90 cm3 g−1). Our strategy is designing the new rigid POSS unit of octakis(chloromethyl)silsesquioxane and reacting it with the rigid N-heterocyclic cross-linkers (typically 4,4′-bipyridine) for preparing the desired porous cationic frameworks. The PCIF-n materials possess large surface area, hydrophobic and special anion-exchanging property, and thus are used as the supports for loading guest species PMo10V2O405−; the resultant hybrid behaves as an efficient heterogeneous catalyst for aerobic oxidation of benzene and H2O2-mediated oxidation of cyclohexane. PMID:26062725

  4. Construction of porous cationic frameworks by crosslinking polyhedral oligomeric silsesquioxane units with N-heterocyclic linkers.

    PubMed

    Chen, Guojian; Zhou, Yu; Wang, Xiaochen; Li, Jing; Xue, Shuang; Liu, Yangqing; Wang, Qian; Wang, Jun

    2015-06-11

    In fields of materials science and chemistry, ionic-type porous materials attract increasing attention due to significant ion-exchanging capacity for accessing diversified applications. Facing the fact that porous cationic materials with robust and stable frameworks are very rare, novel tactics that can create new type members are highly desired. Here we report the first family of polyhedral oligomeric silsesquioxane (POSS) based porous cationic frameworks (PCIF-n) with enriched poly(ionic liquid)-like cationic structures, tunable mesoporosities, high surface areas (up to 1,025 m(2) g(-1)) and large pore volumes (up to 0.90 cm(3) g(-1)). Our strategy is designing the new rigid POSS unit of octakis(chloromethyl)silsesquioxane and reacting it with the rigid N-heterocyclic cross-linkers (typically 4,4'-bipyridine) for preparing the desired porous cationic frameworks. The PCIF-n materials possess large surface area, hydrophobic and special anion-exchanging property, and thus are used as the supports for loading guest species PMo10V2O40(5-); the resultant hybrid behaves as an efficient heterogeneous catalyst for aerobic oxidation of benzene and H2O2-mediated oxidation of cyclohexane.

  5. 3D reconstruction of the porous microstructure of Al2O3-coatings based on sequentially revealed surface data

    NASA Astrophysics Data System (ADS)

    Loftfield, Nina; Kästner, Markus; Reithmeier, Eduard

    2018-06-01

    Local and global liquid transport properties correlate strongly with the morphology of porous materials. Therefore, by characterizing the porous network information is indirectly gained on the materials properties. Properties like the open-porosity are easily accessible with techniques like mercury porosimetry. However, the 3D image reconstruction, destructive or non-destructive, holds advantages like an accurate spatially resolved representation of the investigated material. Common 3D data acquisition is done by x-ray microtomography or a combination of focused ion beam based milling and scanning electron microscopy. In this work a reconstruction approach similar to the latter one is implemented. The porous network is reconstructed based on an alternating process of milling the surface by fly cutting and measuring the surface data with a confocal laser scanning microscope. This has the benefit of reconstructing the pore network on the basis of surface height data, measuring the structure boundaries directly. The stack of milled surface height data needs to be registered and the pore structure to be segmented. The segmented pore structure is connected throughout each height layer and afterwards meshed. The investigated materials are porous surface coatings of aluminum oxide for the usage in tribological pairings.

  6. Hyper-elastic modeling and mechanical behavior investigation of porous poly-D-L-lactide/nano-hydroxyapatite scaffold material.

    PubMed

    Han, Quan Feng; Wang, Ze Wu; Tang, Chak Yin; Chen, Ling; Tsui, Chi Pong; Law, Wing Cheung

    2017-07-01

    Poly-D-L-lactide/nano-hydroxyapatite (PDLLA/nano-HA) can be used as the biological scaffold material in bone tissue engineering as it can be readily made into a porous composite material with excellent performance. However, constitutive modeling for the mechanical response of porous PDLLA/nano-HA under various stress conditions has been very limited so far. In this work, four types of fundamental compressible hyper-elastic constitutive models were introduced for constitutive modeling and investigation of mechanical behaviors of porous PDLLA/nano-HA. Moreover, the unitary expressions of Cauchy stress tensor have been derived for the PDLLA/nano-HA under uniaxial compression (or stretch), biaxial compression (or stretch), pure shear and simple shear load by using the theory of continuum mechanics. The theoretical results determined from the approach based on the Ogden compressible hyper-elastic constitutive model were in good agreement with the experimental data from the uniaxial compression tests. Furthermore, this approach can also be used to predict the mechanical behaviors of the porous PDLLA/nano-HA material under the biaxial compression (or stretch), pure shear and simple shear. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Porous hollow Co₃O₄ with rhombic dodecahedral structures for high-performance supercapacitors.

    PubMed

    Zhang, Yi-Zhou; Wang, Yang; Xie, Ye-Lei; Cheng, Tao; Lai, Wen-Yong; Pang, Huan; Huang, Wei

    2014-11-06

    Porous hollow Co₃O₄ with rhombic dodecahedral structures were prepared by the calcination of ZIF-67 ([Co(mim)2; mim = 2-methylimidazolate]) rhombic dodecahedral microcrystals. A supercapacitor was successfully constructed by adopting the resulting porous hollow Co₃O₄ rhombic dodecahedral structure as the electrode material, which showed a large specific capacitance of 1100 F g(-1) and retained more than 95.1% of the specific capacitance after 6000 continuous charge-discharge cycles. The excellent capacitive properties and stability mark the porous hollow Co₃O₄ with the rhombic dodecahedral structure as one of the most promising electrode materials for high-performance supercapacitors.

  8. Preparation of porous carbons from polymeric precursors modified with acrylated kraft lignin

    NASA Astrophysics Data System (ADS)

    Sobiesiak, M.

    2016-04-01

    The presented studies concern the preparation of porous carbons from a BPA.DA-St polymer containing acrylated kraft lignin as a monomer. The porous polymeric precursor in the form of microspheres was synthesized in suspension polymerization process. Next samples of the polymer were impregnated with acetic acid or aqueous solution of acetates (potassium or ammonia), dried and carbonised in nitrogen atmosphere at 450°C. After carbonization microspherical shape of the materials was remained, that is desired feature for potential application in chromatography or SPE technique. Chemical and textural properties of the porous carbon adsorbents were characterized using infrared spectroscopy (ATR-FTIR), thermogravimetry analyses with mass spectrometry of released gases (TG-MS) and nitrogen sorption experiments. The presented studies revealed the impregnation is useful method for development of porous structure of carbonaceous materials. The highest values of porous structure parameters were obtained when acetic acid and ammonium acetate were used as impregnating substances. On the surface of the materials oxygen functional groups are present that is important for specific interactions during sorption processes. The highest contents of functionalities were observed for carbon BPA.DA-St-LA-C-AcNH4.

  9. Luminescent Porous Polymers Based on Aggregation-Induced Mechanism: Design, Synthesis and Functions.

    PubMed

    Dalapati, Sasanka; Gu, Cheng; Jiang, Donglin

    2016-12-01

    Enormous research efforts are focusing on the design and synthesis of advanced luminescent systems, owing to their diverse capability in scientific studies and technological developments. In particular, fluorescence systems based on aggregation-induced emission (AIE) have emerged to show great potential for sensing, bio-imaging, and optoelectronic applications. Among them, integrating AIE mechanisms to design porous polymers is unique because it enables the combination of porosity and luminescence activity in one molecular skeleton for functional design. In recent years rapid progress in exploring AIE-based porous polymers has developed a new class of luminescent materials that exhibit broad structural diversity, outstanding properties and functions and promising applications. By classifying the structural nature of the skeleton, herein the design principle, synthetic development and structural features of different porous luminescent materials are elucidated, including crystalline covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and amorphous porous organic polymers (POPs). The functional exploration of these luminescent porous polymers are highlighted by emphasizing electronic interplay within the confined nanospace, fundamental issues to be addressed are disclosed, and future directions from chemistry, physics and materials science perspectives are proposed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Characterization and antibacterial properties of porous fibers containing silver ions

    NASA Astrophysics Data System (ADS)

    Sun, Zhaoyang; Fan, Chenxu; Tang, Xiaopeng; Zhao, Jianghui; Song, Yanhua; Shao, Zhongbiao; Xu, Lan

    2016-11-01

    Materials prepared on the base of bioactive silver compounds have become more and more popular. In the present work, the surface morphology, structure and properties, of electrospun Polylactide Polylactic acid (PLA) porous fibers containing various ratios of silver ions were investigated by a combination of X-ray photoelectron spectroscopy (XPS), universal testing machine, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and et al. The biological activities of the proposed porous fibers were discussed in view of the released silver ions concentration. Antibacterial properties of these porous fibers were studied using two bacterial strains: Escherichia coli (E. coli) and Methicillin-resistant Staphylococcus aureus (MRSA). Results of the antibacterial testing suggested that PLA porous fibers containing silver ions could be used as potent antibacterial wound dressing materials in the biomedical field.

  11. Enhanced densification under shock compression in porous silicon

    NASA Astrophysics Data System (ADS)

    Lane, J. Matthew D.; Thompson, Aidan P.; Vogler, Tracy J.

    2014-10-01

    Under shock compression, most porous materials exhibit lower densities for a given pressure than that of a full-dense sample of the same material. However, some porous materials exhibit an anomalous, or enhanced, densification under shock compression. We demonstrate a molecular mechanism that drives this behavior. We also present evidence from atomistic simulation that silicon belongs to this anomalous class of materials. Atomistic simulations indicate that local shear strain in the neighborhood of collapsing pores nucleates a local solid-solid phase transformation even when bulk pressures are below the thermodynamic phase transformation pressure. This metastable, local, and partial, solid-solid phase transformation, which accounts for the enhanced densification in silicon, is driven by the local stress state near the void, not equilibrium thermodynamics. This mechanism may also explain the phenomenon in other covalently bonded materials.

  12. Fully porous 3D printed titanium femoral stem to reduce stress-shielding following total hip arthroplasty.

    PubMed

    Arabnejad, Sajad; Johnston, Burnett; Tanzer, Michael; Pasini, Damiano

    2017-08-01

    Current hip replacement femoral implants are made of fully solid materials which all have stiffness considerably higher than that of bone. This mechanical mismatch can cause significant bone resorption secondary to stress shielding, which can lead to serious complications such as peri-prosthetic fracture during or after revision surgery. In this work, a high strength fully porous material with tunable mechanical properties is introduced for use in hip replacement design. The implant macro geometry is based off of a short stem taper-wedge implant compatible with minimally invasive hip replacement surgery. The implant micro-architecture is fine-tuned to locally mimic bone tissue properties which results in minimum bone resorption secondary to stress shielding. We present a systematic approach for the design of a 3D printed fully porous hip implant that encompasses the whole activity spectrum of implant development, from concept generation, multiscale mechanics of porous materials, material architecture tailoring, to additive manufacturing, and performance assessment via in vitro experiments in composite femurs. We show that the fully porous implant with an optimized material micro-structure can reduce the amount of bone loss secondary to stress shielding by 75% compared to a fully solid implant. This result also agrees with those of the in vitro quasi-physiological experimental model and the corresponding finite element model for both the optimized fully porous and fully solid implant. These studies demonstrate the merit and the potential of tuning material architecture to achieve a substantial reduction of bone resorption secondary to stress shielding. © 2016 Orthopaedic Research Society. Published by Wiley Periodicals, Inc. J Orthop Res 35:1774-1783, 2017. © 2016 Orthopaedic Research Society. Published by Wiley Periodicals, Inc.

  13. Brazing method

    DOEpatents

    McCormick, James T.; Ferry, Paul B.; Hall, John C.

    1981-10-06

    There is disclosed a positive cathode electrode structure formed by brazing a thin porous membrane to a backing material by preselecting a predetermined area of the thin porous membrane and thereafter providing a braze flow barrier throughout the remainder of the membrane and electrolessly plating a nickel-phosphide alloy on the backing material, or in this case the honeycomb structure. The preselected area of the thin porous membrane is placed in intimate contact with the electrolessly plated portion of the backing material and heated to elevated temperatures in the absence of oxygen to form a brazed joint limited to a preselected area. If the braze flow barrier is provided by application of a liquid organic solvent, then the organic solvent is driven off by maintaining the thin porous membrane at elevated temperatures for an extended period of time prior to the brazing operation.

  14. Bipolar plate/diffuser for a proton exchange membrane fuel cell

    DOEpatents

    Besmann, Theodore M.; Burchell, Timothy D.

    2001-01-01

    A combination bipolar plate/diffuser fuel cell component includes an electrically conducting solid material having: a porous region having a porous surface; and a hermetic region, the hermetic region defining at least a portion of at least one coolant channel, the porous region defining at least a portion of at least one reactant channel, the porous region defining a flow field medium for diffusing the reactant to the porous surface.

  15. Bipolar plate/diffuser for a proton exchange membrane fuel cell

    DOEpatents

    Besmann, Theodore M.; Burchell, Timothy D.

    2000-01-01

    A combination bipolar plate/diffuser fuel cell component includes an electrically conducting solid material having: a porous region having a porous surface; and a hermetic region, the hermetic region defining at least a portion of at least one coolant channel, the porous region defining at least a portion of at least one reactant channel, the porous region defining a flow field medium for diffusing the reactant to the porous surface.

  16. Porous carbon material containing CaO for acidic gas capture: preparation and properties.

    PubMed

    Przepiórski, Jacek; Czyżewski, Adam; Pietrzak, Robert; Toyoda, Masahiro; Morawski, Antoni W

    2013-12-15

    A one-step process for the preparation of CaO-containing porous carbons is described. Mixtures of poly(ethylene terephthalate) with natural limestone were pyrolyzed and thus hybrid sorbents could be easily obtained. The polymeric material and the mineral served as a carbon precursor and CaO delivering agent, respectively. We discuss effects of the preparation conditions and the relative amounts of the raw materials used for the preparations on the porosity of the hybrid products. The micropore areas and volumes of the obtained products tended to decrease with increasing CaO contents. Increase in the preparation temperature entailed a decrease in the micropore volume, whereas the mesopore volume increased. The pore creation mechanism is proposed on the basis of thermogravimetric and temperature-programmed desorption measurements. The prepared CaO-containing porous carbons efficiently captured SO2 and CO2 from air. Washing out of CaO from the hybrid materials was confirmed as a suitable method to obtain highly porous carbon materials. Copyright © 2013 Elsevier B.V. All rights reserved.

  17. Gravitational Effects on Combustion Synthesis of Advanced Porous Materials

    NASA Technical Reports Server (NTRS)

    Zhang, X.; Moore, J. J.; Schowengerdt, F. D.; Thorne, K.

    2000-01-01

    Combustion Synthesis (self-Propagating high-temperature synthesis-(SHS)) of porous Ti-TiB(x), composite materials has been studied with respect to the sensitivity to the SHS reaction parameters of stoichiometry, green density, gasifying agents, ambient pressure, diluents and gravity. The main objective of this research program is to engineer the required porosity and mechanical properties into the composite materials to meet the requirements of a consumer, such as for the application of bone replacement materials. Gravity serves to restrict the gas expansion and the liquid movement during SHS reaction. As a result, gravitational forces affect the microstructure and properties of the SHS products. Reacting these SHS systems in low gravity in the KC-135 aircraft has extended the ability to form porous products. This paper will emphasize the effects of gravity (low g, 1g and 2g) on the SHS reaction process, and the microstructure and properties of the porous composite. Some of biomedical results are also discussed.

  18. A wave model for rigid-frame porous materials using lumped parameter concepts

    NASA Astrophysics Data System (ADS)

    Rossetti, S.; Gardonio, P.; Brennan, M. J.

    2005-08-01

    The work presented in this paper concerns the behaviour of porous media when exposed to a normal incidence sound field. A propagating wave model based on lumped parameter concepts of acoustic mass, stiffness and damping is used to investigate the absorption phenomena due to the wave propagation in the layer(s) and interference effects due to the wave reflection-transmission at the interfaces of the layer(s). Results from the theoretical model have been validated by measurements on samples of consolidated rubber granulate material. Two typical installations where a layer of porous material is placed next to a rigid wall, and where it is placed at a distance from a rigid wall are used as reference cases. The geometrical and physical properties of porous materials can be described by such parameters as the non-dimensional shape factor and the porosity. The propagating model introduced is used to investigate the effect of these two parameters on acoustic absorption and thus relate the physical properties to the acoustic behaviour.

  19. Modeling the Shock Hugoniot in Porous Materials

    NASA Astrophysics Data System (ADS)

    Cochrane, Kyle R.; Shulenburger, Luke; Mattsson, Thomas R.; Lane, J. Matthew D.; Weck, Philippe F.; Vogler, Tracy J.; Desjarlais, Michael P.

    2017-06-01

    Porous materials are present in many scenarios from planetary science to ICF. Understanding how porosity modifies the behavior of the shock Hugoniot in an equation of state is key to being able to predictively simulate experiments. For example, modeling shocks in under-dense iron oxide can aid in understanding planetary formation and silica aerogel can be used to approximate the shock response of deuterium. Simulating the shock response of porous materials presents a variety of theoretical challenges, but by combining ab initio calculations with a surface energy and porosity model, we are able to accurately represent the shock Hugoniot. Finally, we show that this new approach can be used to calculate the Hugoniot of porous materials using existing tabular equations of state. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  20. Accurate van der Waals force field for gas adsorption in porous materials.

    PubMed

    Sun, Lei; Yang, Li; Zhang, Ya-Dong; Shi, Qi; Lu, Rui-Feng; Deng, Wei-Qiao

    2017-09-05

    An accurate van der Waals force field (VDW FF) was derived from highly precise quantum mechanical (QM) calculations. Small molecular clusters were used to explore van der Waals interactions between gas molecules and porous materials. The parameters of the accurate van der Waals force field were determined by QM calculations. To validate the force field, the prediction results from the VDW FF were compared with standard FFs, such as UFF, Dreiding, Pcff, and Compass. The results from the VDW FF were in excellent agreement with the experimental measurements. This force field can be applied to the prediction of the gas density (H 2 , CO 2 , C 2 H 4 , CH 4 , N 2 , O 2 ) and adsorption performance inside porous materials, such as covalent organic frameworks (COFs), zeolites and metal organic frameworks (MOFs), consisting of H, B, N, C, O, S, Si, Al, Zn, Mg, Ni, and Co. This work provides a solid basis for studying gas adsorption in porous materials. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  1. Mineralogy and Elemental Composition of Wind Drift Soil at Rocknest, Gale Crater

    NASA Technical Reports Server (NTRS)

    Blake, D. F.; Bish, D. L.; Morris, R. V.; Downs, R. T.; Trieman, A. H.; Morrison, S. M.; Chipera, S. J.; Ming, D. W.; Yen, A. S.; Vaniman, D. T.; hide

    2013-01-01

    The Mars Science Laboratory rover Curiosity has been exploring Mars since August 5, 2012, conducting engineering and first-time activities with its mobility system, arm, sample acquisition and processing system (SA/SPaH-CHIMRA) and science instruments. Curiosity spent 54 sols at a location named "Rocknest," collecting and processing five scoops of loose, unconsolidated materials ("soil") acquired from an aeolian bedform (Fig. 1). The Chemistry and Mineralogy (CheMin) instrument analyzed portions of scoops 3, 4, and 5, to obtain the first quantitative mineralogical analysis of Mars soil, and to provide context for Sample Analysis at Mars (SAM) measurements of volatiles, isotopes and possible organic materials.

  2. The efficacy of post porosity plasma protection against vacuum-ultraviolet damage in porous low-k materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lionti, K.; Volksen, W.; Darnon, M.

    2015-03-21

    As of today, plasma damage remains as one of the main challenges to the reliable integration of porous low-k materials into microelectronic devices at the most aggressive node. One promising strategy to limit damage of porous low-k materials during plasma processing is an approach we refer to as post porosity plasma protection (P4). In this approach, the pores of the low-k material are filled with a sacrificial agent prior to any plasma treatment, greatly minimizing the total damage by limiting the physical interactions between plasma species and the low-k material. Interestingly, the contribution of the individual plasma species to themore » total plasma damage is not fully understood. In this study, we investigated the specific damaging effect of vacuum-ultraviolet (v-UV) photons on a highly porous, k = 2.0 low-k material and we assessed the P4 protective effect against them. It was found that the impact of the v-UV radiation varied depending upon the v-UV emission lines of the plasma. More importantly, we successfully demonstrated that the P4 process provides excellent protection against v-UV damage.« less

  3. Porous Materials with Ultralow Optical Constants for Integrated Optical Device Applications

    NASA Astrophysics Data System (ADS)

    Chen, Hsuen-Li; Hsieh, Chung-I; Cheng, Chao-Chia; Chang, Chia-Pin; Hsu, Wen-Hau; Wang, Way-Seen; Liu, Po-Tsun

    2005-07-01

    Ultralow dielectric constant (<2.0) porous materials have received much attention as next-generation dielectric materials. In this study, optical properties of porous-methyl-silsesquioxane(MSQ)-like films (porous polysilazane, PPSZ) were characterized for optical waveguide devices applications. Measured results indicate that the refractive index is decreased to approximately 1.320 as the hydration time exceeds 24 h. The measured refractive index is about 1.163 at a wavelength of 1550 nm. PPSZ films have low absorption in the 500 to 2000 nm wavelength regime. Because of their relatively low refractive index and low absorption over a large spectral regime, PPSZ films can be good cladding materials for use in optically integrated devices with many high-refractive-index materials such as silicon oxide, silicon nitride, silicon, and polymers. We demonstrate two structures, ridge waveguides and large-angle Y-branch power splitters, composed of PPSZ and SU8 films to illustrate the use of low dielectric constant (K) cladding materials. The simulation results indicate that the PPSZ films provide better confinement of light. Experimentally, a large-angle Y-branch power splitter with PPSZ cladding can be used to guide waves with the large branching angle of 33.58°.

  4. Symmetric supercapacitors using urea-modified lignin derived N-doped porous carbon as electrode materials in liquid and solid electrolytes

    NASA Astrophysics Data System (ADS)

    Wang, Keliang; Xu, Ming; Gu, Yan; Gu, Zhengrong; Fan, Qi Hua

    2016-11-01

    N-doped porous carbon materials derived from urea-modified lignin were prepared via efficient KOH activation under carbonization. The synthesized N-doped carbon materials, which displayed a well-developed porous morphology with high specific surface area of 3130 m2 g-1, were used as electrode materials in symmetric supercapacitors with aqueous and solid electrolytes. In consistent with the observed physical structures and properties, the supercapacitors exhibited specific capacitances of 273 and 306 F g-1, small resistances of 2.6 and 7.7 Ω, stable charge/discharge at different current densities for over 5000 cycles and comparable energy and power density in 6 mol L-1 KOH liquid and KOH-PVA solid electrolytes, respectively.

  5. Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process.

    PubMed

    Kongpatpanich, Kanokwan; Horike, Satoshi; Fujiwara, Yu-Ichi; Ogiwara, Naoki; Nishihara, Hirotomo; Kitagawa, Susumu

    2015-09-14

    Porous carbon material with a foam-like microstructure has been synthesized by direct carbonization of porous coordination polymer (PCP). In situ generation of foaming agents by chemical reactions of ligands in PCP during carbonization provides a simple way to create lightweight carbon material with a foam-like microstructure. Among several substituents investigated, the nitro group has been shown to be the key to obtain the unique foam-like microstructure, which is due to the fast kinetics of gas evolution during carbonization. Foam-like microstructural carbon materials showed higher pore volume and specific capacitance compared to a microporous carbon. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Electrode including porous particles with embedded active material for use in a secondary electrochemical cell

    DOEpatents

    Vissers, Donald R.; Nelson, Paul A.; Kaun, Thomas D.; Tomczuk, Zygmunt

    1978-04-25

    Particles of carbonaceous matrices containing embedded electrode active material are prepared for vibratory loading within a porous electrically conductive substrate. In preparing the particles, active materials such as metal chalcogenides, solid alloys of alkali or alkaline earth metals along with other metals and their oxides in powdered or particulate form are blended with a thermosetting resin and particles of a volatile to form a paste mixture. The paste is heated to a temperature at which the volatile transforms into vapor to impart porosity at about the same time as the resin begins to cure into a rigid, solid structure. The solid structure is then comminuted into porous, carbonaceous particles with the embedded active material.

  7. Method of preparing porous, active material for use in electrodes of secondary electrochemical cells

    DOEpatents

    Vissers, Donald R.; Nelson, Paul A.; Kaun, Thomas D.; Tomczuk, Zygmunt

    1977-01-01

    Particles of carbonaceous matrices containing embedded electrode active material are prepared for vibratory loading within a porous electrically conductive substrate. In preparing the particles, active materials such as metal chalcogenides, solid alloys of alkali or alkaline earth metals along with other metals and their oxides in powdered or particulate form are blended with a thermosetting resin and particles of a volatile to form a paste mixture. The paste is heated to a temperature at which the volatile transforms into vapor to impart porosity at about the same time as the resin begins to cure into a rigid, solid structure.The solid structure is then comminuted into porous, carbonaceous particles with the embedded active material.

  8. Method for reducing pressure drop through filters, and filter exhibiting reduced pressure drop

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sappok, Alexander; Wong, Victor

    Methods for generating and applying coatings to filters with porous material in order to reduce large pressure drop increases as material accumulates in a filter, as well as the filter exhibiting reduced and/or more uniform pressure drop. The filter can be a diesel particulate trap for removing particulate matter such as soot from the exhaust of a diesel engine. Porous material such as ash is loaded on the surface of the substrate or filter walls, such as by coating, depositing, distributing or layering the porous material along the channel walls of the filter in an amount effective for minimizing ormore » preventing depth filtration during use of the filter. Efficient filtration at acceptable flow rates is achieved.« less

  9. Science and Engineering of Carbon Foams

    DTIC Science & Technology

    2006-07-17

    production process tends to vary, many processes start with a compacted, porous pre-form of pitch material. The pitch pre-form is then melted under high...Foams 1.11 Theory for thermal transport Carbon foam can be modeled in the manner of a porous media. Many of these models are based on the analysis of...intrinsic density of the solid, P is the porosity of the porous material, and R is the relative density. The value of thermal conductivity of foam with

  10. Chemically Layered Porous Solids

    NASA Technical Reports Server (NTRS)

    Koontz, Steve

    1991-01-01

    Aerogels and other porous solids in which surfaces of pores have chemical properties varying with depth below macroscopic surfaces prepared by sequences of chemical treatments. Porous glass or silica bead treated to make two depth zones having different chemical properties. Beads dropped along tube filled with flowing gas containing atomic oxygen, generated in microwave discharge. General class of materials treatable include oxides of aluminum, silicon, zirconium, tin, titanium, and nickel, and mixtures of these oxides. Potential uses of treated materials include chromatographic separations, membrane separations, controlled releases of chemicals, and catalysis.

  11. Porous polymer media

    DOEpatents

    Shepodd, Timothy J.

    2002-01-01

    Highly crosslinked monolithic porous polymer materials for chromatographic applications. By using solvent compositions that provide not only for polymerization of acrylate monomers in such a fashion that a porous polymer network is formed prior to phase separation but also for exchanging the polymerization solvent for a running buffer using electroosmotic flow, the need for high pressure purging is eliminated. The polymer materials have been shown to be an effective capillary electrochromatographic separations medium at lower field strengths than conventional polymer media. Further, because of their highly crosslinked nature these polymer materials are structurally stable in a wide range of organic and aqueous solvents and over a pH range of 2-12.

  12. Experimental Simulations of Large-Scale Collisions

    NASA Technical Reports Server (NTRS)

    Housen, Kevin R.

    2002-01-01

    This report summarizes research on the effects of target porosity on the mechanics of impact cratering. Impact experiments conducted on a centrifuge provide direct simulations of large-scale cratering on porous asteroids. The experiments show that large craters in porous materials form mostly by compaction, with essentially no deposition of material into the ejecta blanket that is a signature of cratering in less-porous materials. The ratio of ejecta mass to crater mass is shown to decrease with increasing crater size or target porosity. These results are consistent with the observation that large closely-packed craters on asteroid Mathilde appear to have formed without degradation to earlier craters.

  13. Preparation of amorphous sulfide sieves

    DOEpatents

    Siadati, Mohammad H.; Alonso, Gabriel; Chianelli, Russell R.

    2006-11-07

    The present invention involves methods and compositions for synthesizing catalysts/porous materials. In some embodiments, the resulting materials are amorphous sulfide sieves that can be mass-produced for a variety of uses. In some embodiments, methods of the invention concern any suitable precursor (such as thiomolybdate salt) that is exposed to a high pressure pre-compaction, if need be. For instance, in some cases the final bulk shape (but highly porous) may be same as the original bulk shape. The compacted/uncompacted precursor is then subjected to an open-flow hot isostatic pressing, which causes the precursor to decompose and convert to a highly porous material/catalyst.

  14. Production of porous Calcium Phosphate (CaP) ceramics with aligned pores using ceramic/camphene-based co-extrusion.

    PubMed

    Choi, Won-Young; Kim, Hyoun-Ee; Moon, Young-Wook; Shin, Kwan-Ha; Koh, Young-Hag

    2015-01-01

    Calcium phosphate (CaP) ceramics are one of the most valuable biomaterials for uses as the bone scaffold owing to their outstanding biocompatability, bioactivity, and biodegradation nature. In particular, these materials with an open porous structure can stimulate bone ingrowth into their 3-dimensionally interconnected pores. However, the creation of pores in bulk materials would inevitably cause a severe reduction in mechanical properties. Thus, it is a challenge to explore new ways of improving the mechanical properties of porous CaP scaffolds without scarifying their high porosity. Porous CaP ceramic scaffolds with aligned pores were successfully produced using ceramic/camphene-based co-extrusion. This aligned porous structure allowed for the achievement of high compressive strength when tested parallel to the direction of aligned pores. In addition, the overall porosity and mechanical properties of the aligned porous CaP ceramic scaffolds could be tailored simply by adjusting the initial CaP content in the CaP/camphene slurry. The porous CaP scaffolds showed excellent in vitro biocompatibility, suggesting their potential as the bone scaffold. Aligned porous CaP ceramic scaffolds with considerably enhanced mechanical properties and tailorable porosity would find very useful applications as the bone scaffold.

  15. Fabrication and durable antibacterial properties of 3D porous wet electrospun RCSC/PCL nanofibrous scaffold with silver nanoparticles

    NASA Astrophysics Data System (ADS)

    Zhang, Mei; Lin, Han; Wang, Yilong; Yang, Guang; Zhao, He; Sun, Dahui

    2017-08-01

    Electrospunnanofibers are used as three-dimensional (3D) scaffold materials that can alter cell attachment and cell proliferation, change the antibacterial properties of materials, and can be used as wound dressings. But the fabrication of porous 3D scaffold structure and the antibacterial properties enhancing are challenges remained to improve. With the states here, a Ranachensinensis skin collagen (RCSC)/poly(ɛ-caprolactone) (PCL)AgNP-loaded3D nanofiber scaffold is fabricated as a wound dressing material by using an improved wet electrospinning method (blending). The nanoscale of the AgNPs is proved. The 3D porous morphologies of the materials with different AgNP loadings, are determined with field emission scanning electron microscopy (FESEM) and the presence and uniformity distribution of AgNPs is confirmed by Energy dispersive X-ray (EDX) spectroscopy. The silver-ion release rates, antibacterial properties, and cytotoxicities of dressing materials with different AgNP contents are evaluated using ICP-AES, the zone inhibition method, and MTT testing. These results showed that the improved wet electrospun is an effective way to fabricate AgNP loaded 3D scaffold materials with porous structure and nearly 90% porosity and the presence of AgNPs in dressing materials strengthen the antibacterial properties. The RCSC/PCL 3D scaffold materials containing 2.0%AgNP would be promising for dressing materials application nearly without cytotoxicities.

  16. Porous carbon derived from aniline-modified fungus for symmetrical supercapacitor electrodes

    DOE PAGES

    Wang, Keliang; Xu, Ming; Wang, Xiaomin; ...

    2017-01-23

    N incorporated carbon materials are proven to be efficient EDLCs electrode materials. In this work, aniline modified fungus served as a raw material, and N-doped porous activated carbon is prepared via an efficient KOH activation method. A porous network with a high specific surface area of 2339 m 2g -1 is displayed by the prepared carbon material, resulting in a high accessible surface area and low ion diffusion resistance which is desirable for EDLC electrode materials. In assembled EDLCs, the N–AC based electrode exhibits a specific capacitance of 218 F g -1 at a current density of 0.1 A gmore » -1. Besides, excellent stability is displayed after 5000 continuous cycles at different current densities ranging from 0.1 to 10 A g -1. Thus, the present work reveals a promising candidate for electrode materials of EDLCs.« less

  17. Measurements of Acoustic Properties of Porous and Granular Materials and Application to Vibration Control

    NASA Technical Reports Server (NTRS)

    Park, Junhong; Palumbo, Daniel L.

    2004-01-01

    For application of porous and granular materials to vibro-acoustic controls, a finite dynamic strength of the solid component (frame) is an important design factor. The primary goal of this study was to investigate structural vibration damping through this frame wave propagation for various poroelastic materials. A measurement method to investigate the vibration characteristics of the frame was proposed. The measured properties were found to follow closely the characteristics of the viscoelastic materials - the dynamic modulus increased with frequency and the degree of the frequency dependence was determined by its loss factor. The dynamic stiffness of hollow cylindrical beams containing porous and granular materials as damping treatment was measured also. The data were used to extract the damping materials characteristics using the Rayleigh-Ritz method. The results suggested that the acoustic structure interaction between the frame and the structure enhances the dissipation of the vibration energy significantly.

  18. Progress in the Development of SERS-Active Substrates Based on Metal-Coated Porous Silicon

    PubMed Central

    Girel, Kseniya V.; Panarin, Andrei; Terekhov, Sergei N.

    2018-01-01

    The present work gives an overview of the developments in surface-enhanced Raman scattering (SERS) with metal-coated porous silicon used as an active substrate. We focused this review on the research referenced to SERS-active materials based on porous silicon, beginning from the patent application in 2002 and enclosing the studies of this year. Porous silicon and metal deposition technologies are discussed. Since the earliest studies, a number of fundamentally different plasmonic nanostructures including metallic dendrites, quasi-ordered arrays of metallic nanoparticles (NPs), and metallic nanovoids have been grown on porous silicon, defined by the morphology of this host material. SERS-active substrates based on porous silicon have been found to combine a high and well-reproducible signal level, storage stability, cost-effective technology and handy use. They make it possible to identify and study many compounds including biomolecules with a detection limit varying from milli- to femtomolar concentrations. The progress reviewed here demonstrates the great prospects for the extensive use of the metal-coated porous silicon for bioanalysis by SERS-spectroscopy. PMID:29883382

  19. Two-Dimensional Porous Carbon: Synthesis and Ion-Transport Properties.

    PubMed

    Zheng, Xiaoyu; Luo, Jiayan; Lv, Wei; Wang, Da-Wei; Yang, Quan-Hong

    2015-09-23

    Their chemical stability, high specific surface area, and electric conductivity enable porous carbon materials to be the most commonly used electrode materials for electrochemical capacitors (also known as supercapacitors). To further increase the energy and power density, engineering of the pore structures with a higher electrochemical accessible surface area, faster ion-transport path and a more-robust interface with the electrolyte is widely investigated. Compared with traditional porous carbons, two-dimensional (2D) porous carbon sheets with an interlinked hierarchical porous structure are a good candidate for supercapacitors due to their advantages in high aspect ratio for electrode packing and electron transport, hierarchical pore structures for ion transport, and short ion-transport length. Recent progress on the synthesis of 2D porous carbons is reported here, along with the improved electrochemical behavior due to enhanced ion transport. Challenges for the controlled preparation of 2D porous carbons with desired properties are also discussed; these require precise tuning of the hierarchical structure and a clarification of the formation mechanisms. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Response of murine bone marrow-derived mesenchymal stromal cells to dry-etched porous silicon scaffolds.

    PubMed

    Hajj-Hassan, Mohamad; Khayyat-Kholghi, Maedeh; Wang, Huifen; Chodavarapu, Vamsy; Henderson, Janet E

    2011-11-01

    Porous silicon shows great promise as a bio-interface material due to its large surface to volume ratio, its stability in aqueous solutions and to the ability to precisely regulate its pore characteristics. In the current study, porous silicon scaffolds were fabricated from single crystalline silicon wafers by a novel xenon difluoride dry etching technique. This simplified dry etch fabrication process allows selective formation of porous silicon using a standard photoresist as mask material and eliminates the post-formation drying step typically required for the wet etching techniques, thereby reducing the risk of damaging the newly formed porous silicon. The porous silicon scaffolds supported the growth of primary cultures of bone marrow derived mesenchymal stromal cells (MSC) plated at high density for up to 21 days in culture with no significant loss of viability, assessed using Alamar Blue. Scanning electron micrographs confirmed a dense lawn of cells at 9 days of culture and the presence of MSC within the pores of the porous silicon scaffolds. Copyright © 2011 Wiley Periodicals, Inc.

  1. Progress in the Development of SERS-Active Substrates Based on Metal-Coated Porous Silicon.

    PubMed

    Bandarenka, Hanna V; Girel, Kseniya V; Zavatski, Sergey A; Panarin, Andrei; Terekhov, Sergei N

    2018-05-21

    The present work gives an overview of the developments in surface-enhanced Raman scattering (SERS) with metal-coated porous silicon used as an active substrate. We focused this review on the research referenced to SERS-active materials based on porous silicon, beginning from the patent application in 2002 and enclosing the studies of this year. Porous silicon and metal deposition technologies are discussed. Since the earliest studies, a number of fundamentally different plasmonic nanostructures including metallic dendrites, quasi-ordered arrays of metallic nanoparticles (NPs), and metallic nanovoids have been grown on porous silicon, defined by the morphology of this host material. SERS-active substrates based on porous silicon have been found to combine a high and well-reproducible signal level, storage stability, cost-effective technology and handy use. They make it possible to identify and study many compounds including biomolecules with a detection limit varying from milli- to femtomolar concentrations. The progress reviewed here demonstrates the great prospects for the extensive use of the metal-coated porous silicon for bioanalysis by SERS-spectroscopy.

  2. Porous and Microporous Honeycomb Composites as Potential Boundary-Layer Bleed Materials

    NASA Technical Reports Server (NTRS)

    Davis, D. O.; Willis, B. P.; Schoenenberger, M.

    1997-01-01

    Results of an experimental investigation are presented in which the use of porous and microporous honeycomb composite materials is evaluated as an alternate to perforated solid plates for boundary-layer bleed in supersonic aircraft inlets. The terms "porous" and "microporous," respectively, refer to bleed orifice diameters roughly equal to and much less than the displacement thickness of the approach boundary-layer. A Baseline porous solid plate, two porous honeycomb, and three microporous honeycomb configurations are evaluated. The performance of the plates is characterized by the flow coefficient and relative change in boundary-layer profile parameters across the bleed region. The tests were conducted at Mach numbers of 1.27 and 1.98. The results show the porous honeycomb is not as efficient at removing mass compared to the baseline. The microporous plates were about equal to the baseline with one plate demonstrating a significantly higher efficiency. The microporous plates produced significantly fuller boundary-layer profiles downstream of the bleed region for a given mass flow removal rate than either the baseline or the porous honeycomb plates.

  3. Preparation of ultrasmall porous carbon nanospheres by reverse microemulsion-hydrothermal method

    NASA Astrophysics Data System (ADS)

    Wang, Jiasheng; Zhao, Yahong; Wang, Wan-Hui; Bao, Ming

    Porous carbon nanospheres (CNSs) have wide applications. A big challenge in materials science is synthesis of discrete ultrasmall porous carbon nanospheres. Herein, we report a facile reverse microemulsion-hydrothermal method to prepare discrete porous CNSs. The obtained CNSs possess an average diameter of 20nm and pores of 0.7nm and 3.4nm. Our work has provided a convenient method for the controllable synthesis of ultrasmall porous CNSs with potential applications.

  4. Graphene-based porous materials with tunable surface area and CO2 adsorption properties synthesized by fluorine displacement reaction with various diamines.

    PubMed

    Li, Baoyin; Fan, Kun; Ma, Xin; Liu, Yang; Chen, Teng; Cheng, Zheng; Wang, Xu; Jiang, Jiaxing; Liu, Xiangyang

    2016-09-15

    A mild, operationally simple and controllable protocol for preparing graphene-based porous materials is essential to achieve a good pore-design development. In this paper, graphene-based porous materials with tunable surface area were constructed by the intercalation of fluorinated graphene (FG) based on the reaction of reactive CF bonds attached to graphene sheets with various amine-terminated molecules. In the porous materials, graphene sheets are like building blocks, and the diamines covalently grafted onto graphene framework act as pillars. Various diamines are successfully grafted onto graphene sheets, but the grafting ratio of diamines and reduction degree of FG differ greatly and depend on the chemical reactivity of diamines. Pillared diamine molecules chemically anchor at one end and are capable of undergoing a different reaction on the other end, resulting in three different conformations of graphene derivatives. Nitrogen sorption isotherms revealed that the surface area and pore distribution of the obtained porous materials depend heavily on the size and structure of diamine pillars. CO2 uptake capacity characterization showed that ethylenediamine intercalated FG achieved a high CO2 uptake density of 18.0 CO2 molecules per nm(2) at 0°C and 1.1bars, and high adsorption heat, up to 46.1kJmol(-1) at zero coverage. Copyright © 2016 Elsevier Inc. All rights reserved.

  5. Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode.

    PubMed

    Hao, Pin; Zhao, Zhenhuan; Tian, Jian; Li, Haidong; Sang, Yuanhua; Yu, Guangwei; Cai, Huaqiang; Liu, Hong; Wong, C P; Umar, Ahmad

    2014-10-21

    Renewable, cost-effective and eco-friendly electrode materials have attracted much attention in the energy conversion and storage fields. Bagasse, the waste product from sugarcane that mainly contains cellulose derivatives, can be a promising candidate to manufacture supercapacitor electrode materials. This study demonstrates the fabrication and characterization of highly porous carbon aerogels by using bagasse as a raw material. Macro and mesoporous carbon was first prepared by carbonizing the freeze-dried bagasse aerogel; consequently, microporous structure was created on the walls of the mesoporous carbon by chemical activation. Interestingly, it was observed that the specific surface area, the pore size and distribution of the hierarchical porous carbon were affected by the activation temperature. In order to evaluate the ability of the hierarchical porous carbon towards the supercapacitor electrode performance, solid state symmetric supercapacitors were assembled, and a comparable high specific capacitance of 142.1 F g(-1) at a discharge current density of 0.5 A g(-1) was demonstrated. The fabricated solid state supercapacitor displayed excellent capacitance retention of 93.9% over 5000 cycles. The high energy storage ability of the hierarchical porous carbon was attributed to the specially designed pore structures, i.e., co-existence of the micropores and mesopores. This research has demonstrated that utilization of sustainable biopolymers as the raw materials for high performance supercapacitor electrode materials is an effective way to fabricate low-cost energy storage devices.

  6. Joint inversion of high resolution S-wave velocity structure underneath North China Basin

    NASA Astrophysics Data System (ADS)

    Yang, C.; Li, G.; Niu, F.

    2017-12-01

    North China basin is one of earthquake prone areas in China. Many devastating earthquakes occurred in the last century and before, such as the 1937 M7.0 Heze Earthquake in Shandong province, the 1966 M7.2 Xingtai Earthquake and 1976 Tangshan Earthquake in Hebei province. Knowing the structure of the sediment cover is of great importance to predict strong ground motion caused by earthquakes. Unconsolidated sediments are loose materials, ranging from clay to sand to gravel. Earthquakes can liquefy unconsolidated sediments, thus knowing the distribution and thickness of the unconsolidated sediments has significant implication in seismic hazard analysis of the area. Quantitative estimates of the amount of extension of the North China basin is important to understand the thinning and evolution of the eastern North China craton and the underlying mechanism. In principle, the amount of lithospheric stretching can be estimated from sediment and crustal thickness. Therefore an accurate estimate of the sediment and crustal thickness of the area is also important in understanding regional tectonics. In this study, we jointly invert the Rayleigh wave phase-velocity dispersion and Z/H ratio data to construct a 3-D S-wave velocity model beneath North China area. We use 4-year ambient noise data recorded from 249 temporary stations, and 139 earthquake events to extract Rayleigh wave Z/H ratios. The Z/H ratios obtained from ambient noise data and earthquake data show a good agreement within the overlapped periods. The phase velocity dispersion curve was estimated from the same ambient noise data. The preliminary result shows a relatively low Z/H ratio and low velocity anomaly at the shallow part of sediment basins.

  7. Porous mixed metal oxides: design, formation mechanism, and application in lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Wu, Fangfang; Bai, Jing; Feng, Jinkui; Xiong, Shenglin

    2015-10-01

    The relentless pursuit of new electrode materials for lithium ion batteries (LIBs) has been conducted for decades. Structures with either porous or nanostructure configurations have been confirmed as advantageous candidates for energy storage/conversion applications. The integration of the two features into one structure can provide another chance to improve the electroactivities. Recently, single-phased mixed metal oxides (MMOs) containing different metal cations, in particular, have confirmed high electrochemical activities because of their complex chemical composition, interfacial effects, and the synergic effects of the multiple metal species. In this review, we will focus on recent research advances of MMOs with porous architectures as anode materials in the matter of structural arrangement and compositional manipulation. Moreover, the application of self-supported MMO-based porous structures as LIB anodes is also explained herein. More importantly, investigations on the synthetic system and formation mechanism of porous MMOs will be highlighted. Some future trends for the innovative design of new electrode materials are also discussed in this review. The challenges and prospects will draw many researchers' attention.

  8. A coupled deformation-diffusion theory for fluid-saturated porous solids

    NASA Astrophysics Data System (ADS)

    Henann, David; Kamrin, Ken; Anand, Lallit

    2012-02-01

    Fluid-saturated porous materials are important in several familiar applications, such as the response of soils in geomechanics, food processing, pharmaceuticals, and the biomechanics of living bone tissue. An appropriate constitutive theory describing the coupling of the mechanical behavior of the porous solid with the transport of the fluid is a crucial ingredient towards understanding the material behavior in these varied applications. In this work, we formulate and numerically implement in a finite-element framework a large-deformation theory for coupled deformation-diffusion in isotropic, fluid-saturated porous solids. The theory synthesizes the classical Biot theory of linear poroelasticity and the more-recent Coussy theory of poroplasticity in a large deformation framework. In this talk, we highlight several salient features of our theory and discuss representative examples of the application of our numerical simulation capability to problems of consolidation as well as deformation localization in granular materials.

  9. Equilibrium stability of a cylindrical body subject to the internal structure of the material and inelastic behaviour of the completely compressed matrix

    NASA Astrophysics Data System (ADS)

    Gotsev, D. V.; Perunov, N. S.; Sviridova, E. N.

    2018-03-01

    The mathematical model describing the stress-strain state of a cylindrical body under the uniform radial compression effect is constructed. The model of the material is the porous medium model. The compressed skeleton of the porous medium possesses hardening elastic-plastic properties. Deforming of the porous medium under the specified compressive loads is divided into two stages: elastic deforming of the porous medium and further elastic-plastic deforming of the material with completely compressed matrix. The analytical relations that define the fields of stress and displacement at each stage of the deforming are obtained. The influence of the porosity and other physical, mechanical and geometric parameters of the construction on the size of the plastic zone is evaluated. The question of the ground state equilibrium instability is investigated within the framework of the three-dimensional linearized relationships of the stability theory of deformed bodies.

  10. The Effect of Gravity on the Combustion Synthesis of Porous Biomaterials

    NASA Technical Reports Server (NTRS)

    Castillo, M.; Zhang, X.; Moore, J. J.; Schowengerdt, F. D.; Ayers, R. A.

    2003-01-01

    Production of highly porous composite materials by traditional materials processing is limited by difficult processing techniques. This work investigates the use of self propagating high temperature (combustion) synthesis (SHS) to create porous tricalcium phosphate (Ca3(PO4)2), TiB-Ti, and NiTi in low and microgravity. Combustion synthesis provides the ability to use set processing parameters to engineer the required porous structure suitable for bone repair or replacement. The processing parameters include green density, particle size, gasifying agents, composition, and gravity. The advantage of the TiB-Ti system is the high level of porosity achieved together with a modulus that can be controlled by both composition (TiB-Ti) and porosity. At the same time, NiTi exhibits shape memory properties. SHS of biomaterials allows the engineering of required porosity coupled with resorbtion properties and specific mechanical properties into the composite materials to allow for a better biomaterial.

  11. Absorbate-induced piezochromism in a porous molecular crystal

    DOE PAGES

    Hendon, Christopher H.; Wittering, Kate E.; Chen, Teng -Hao; ...

    2015-02-23

    Atmospherically stable porous frameworks and materials are interesting for heterogeneous solid–gas applications. One motivation is the direct and selective uptake of pollutant/hazardous gases, where the material produces a measurable response in the presence of the analyte. In this report, we present a combined experimental and theoretical rationalization for the piezochromic response of a robust and porous molecular crystal built from an extensively fluorinated trispyrazole. The electronic response of the material is directly determined by analyte uptake, which provokes a subtle lattice contraction and an observable bathochromic shift in the optical absorption onset. Selectivity for fluorinated absorbates is demonstrated, and toluenemore » is also found to crystallize within the pore. Lastly, we demonstrate the application of electronic structure calculations to predict a physicochemical response, providing the foundations for the design of electronically tunable porous solids with the chemical properties required for development of novel gas-uptake media.« less

  12. Enhancement of a dynamic porous model considering compression-release hysteresis behavior: application to graphite

    NASA Astrophysics Data System (ADS)

    Jodar, B.; Seisson, G.; Hébert, D.; Bertron, I.; Boustie, M.; Berthe, L.

    2016-08-01

    Because of their shock wave attenuation properties, porous materials and foams are increasingly used for various applications such as graphite in the aerospace industry and polyurethane (PU) foams in biomedical engineering. For these two materials, the absence of residual compaction after compression and release cycles limits the efficiency of the usual numerical dynamic porous models such as P-α and POREQST. In this paper, we suggest a simple enhancement of the latter in order to take into account the compression-release hysteresis behavior experimentally observed for the considered materials. The new model, named H-POREQST, was implemented into a Lagrangian hydrocode and tested for simulating plate impact experiments at moderate pressure onto a commercial grade of porous graphite (EDM3). It proved to be in far better agreement with experimental data than the original model which encourages us to pursue numerical tests and developments.

  13. Environmental Assessment of 2005 Base Closure and Realignment Actions at Buckley Air Force Base, Colorado

    DTIC Science & Technology

    2008-05-01

    5,500 feet in the northwestern corner of the base (BAFB 2004). Soils. Soils are the unconsolidated materials overlying bedrock or other parent ...consultation with this office. We request being invol \\l’ed in the consultation process "~th the local go\\l’crnment, which as stipulated in 36 CFR 800.3...35000 10 Bowling Center and Community Activities (Peterson)_ 5274 11 Education Center/Library 4000 11 Arts, Crafts, Auto Skills Development Ctr 2000

  14. MX Siting Investigation. Geotechnical Evaluation of Luke Bombing and Gunnery Range. Geotechnical Report, Lechuguilla Desert, Arizona. Volume I.

    DTIC Science & Technology

    1978-01-20

    8217-5000 -150 C KILOETERS , 1 2 V i asagerat- EXPLANATION i SURFICIAL BASIN FILL; Alluvial tans and playa lacustrine deposits; average seismic velocity...Undetermined e Velocity zone I represents alluvial fan deposits and possible playa /lacustrine materials underlying the unconsolidated, thin 1younger...alluvial fan unit (A5y, A5yf). Velocity zone 2 seems to represert older, playa /lacustrine deposits overlying Veloc- ity zone 3, which may be the well

  15. Asphalt-derived high surface area activated porous carbons for carbon dioxide capture.

    PubMed

    Jalilov, Almaz S; Ruan, Gedeng; Hwang, Chih-Chau; Schipper, Desmond E; Tour, Josiah J; Li, Yilun; Fei, Huilong; Samuel, Errol L G; Tour, James M

    2015-01-21

    Research activity toward the development of new sorbents for carbon dioxide (CO2) capture have been increasing quickly. Despite the variety of existing materials with high surface areas and high CO2 uptake performances, the cost of the materials remains a dominant factor in slowing their industrial applications. Here we report preparation and CO2 uptake performance of microporous carbon materials synthesized from asphalt, a very inexpensive carbon source. Carbonization of asphalt with potassium hydroxide (KOH) at high temperatures (>600 °C) yields porous carbon materials (A-PC) with high surface areas of up to 2780 m(2) g(-1) and high CO2 uptake performance of 21 mmol g(-1) or 93 wt % at 30 bar and 25 °C. Furthermore, nitrogen doping and reduction with hydrogen yields active N-doped materials (A-NPC and A-rNPC) containing up to 9.3% nitrogen, making them nucleophilic porous carbons with further increase in the Brunauer-Emmett-Teller (BET) surface areas up to 2860 m(2) g(-1) for A-NPC and CO2 uptake to 26 mmol g(-1) or 114 wt % at 30 bar and 25 °C for A-rNPC. This is the highest reported CO2 uptake among the family of the activated porous carbonaceous materials. Thus, the porous carbon materials from asphalt have excellent properties for reversibly capturing CO2 at the well-head during the extraction of natural gas, a naturally occurring high pressure source of CO2. Through a pressure swing sorption process, when the asphalt-derived material is returned to 1 bar, the CO2 is released, thereby rendering a reversible capture medium that is highly efficient yet very inexpensive.

  16. The effect of different surface materials on runoff quality in permeable pavement systems.

    PubMed

    Li, Haiyan; Li, Zhifei; Zhang, Xiaoran; Li, Zhuorong; Liu, Dongqing; Li, Tanghu; Zhang, Ziyang

    2017-09-01

    To investigate the effect of different permeable pavement surface materials on the removal of pollutants from urban storm-runoff, six commonly surface materials (porous asphalt, porous concrete, cement brick, ceramic brick, sand base brick, and shale brick) were selected in this study and the research was carried out by column experiments. Except the concentrations of total suspended solids (TSS), chemical oxygen demand (COD), ammonia nitrogen (NH 4 -N), nitrate nitrogen (NO 3 -N), total nitrogen (TN), and total phosphorus (TP) in the influent and effluent that were measured, the removal mechanism of pollutants was discussed further. The results indicate that the surface materials influence the removal efficiency of pollutants greatly and have different effects on certain pollutant. Furthermore, the physical interception and adsorption would be the main mechanism for the removal of pollutants from runoff. For example, for all surface materials, the average removal efficiency of TSS is nearly about 90.0% because of physical interception. Due to the amount of iron oxide, the removal efficiency of COD, NO 3 -N, and TN of shale brick was 88.2, 35.1, and 17.5%, respectively. NH 4 -N and TN can be easily removed by porous asphalt due to the high content of organic matter. By lacking of useful adsorption sites, all the surface materials had little effect on the removal of TP from runoff. This research could offer useful guidelines for the better design of permeable pavement system and promote the insight into the removal mechanism of pollutants in permeable pavement system. Graphical abstract Different types of materials for the different types of pollutants in the runoff purification capacity were significantly different, overall, shale brick and porous asphalt Shale bricks and porous asphalt have a better purification effect according to the six kinds of materials.

  17. Ultracapacitor separator

    DOEpatents

    Wei, Chang; Jerabek, Elihu Calvin; LeBlanc, Jr., Oliver Harris

    2001-03-06

    An ultracapacitor includes two solid, nonporous current collectors, two porous electrodes separating the collectors, a porous separator between the electrodes and an electrolyte occupying the pores in the electrodes and separator. The electrolyte is a polar aprotic organic solvent and a salt. The porous separator comprises a wet laid cellulosic material.

  18. Scalable synthesis of interconnected porous silicon/carbon composites by the Rochow reaction as high-performance anodes of lithium ion batteries.

    PubMed

    Zhang, Zailei; Wang, Yanhong; Ren, Wenfeng; Tan, Qiangqiang; Chen, Yunfa; Li, Hong; Zhong, Ziyi; Su, Fabing

    2014-05-12

    Despite the promising application of porous Si-based anodes in future Li ion batteries, the large-scale synthesis of these materials is still a great challenge. A scalable synthesis of porous Si materials is presented by the Rochow reaction, which is commonly used to produce organosilane monomers for synthesizing organosilane products in chemical industry. Commercial Si microparticles reacted with gas CH3 Cl over various Cu-based catalyst particles to substantially create macropores within the unreacted Si accompanying with carbon deposition to generate porous Si/C composites. Taking advantage of the interconnected porous structure and conductive carbon-coated layer after simple post treatment, these composites as anodes exhibit high reversible capacity and long cycle life. It is expected that by integrating the organosilane synthesis process and controlling reaction conditions, the manufacture of porous Si-based anodes on an industrial scale is highly possible. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Branched nanostructures and method of synthesizing the same

    NASA Technical Reports Server (NTRS)

    Fonseca, Luis F. (Inventor); Sola, Francisco (Inventor); Resto, Oscar (Inventor)

    2009-01-01

    A branched nanostructure is synthesized. A porous material, with pores having a diameter of approximately 1 .mu.m or less, is placed in a vacuum. It is irradiated with an electron beam. This causes a trunk to grow from the porous material and further causes branches to grow from the trunk.

  20. Methyl alcohol used as penetrant inspection medium for porous materials

    NASA Technical Reports Server (NTRS)

    Hendron, J. A.

    1971-01-01

    Porous material thoroughly wetted with alcohol shows persistent wet line or area at locations of cracks or porosity. Inspection is qualitative and repeatable, but is used quantitatively with select samples to grade density variations in graphite blocks. Photography is employed to achieve permanent record of results.

  1. Modeling of nanostructured porous thermoelastic composites with surface effects

    NASA Astrophysics Data System (ADS)

    Nasedkin, A. V.; Nasedkina, A. A.; Kornievsky, A. S.

    2017-01-01

    The paper presents an integrated approach for determination of effective properties of anisotropic porous thermoelastic materials with a nanoscale stochastic porosity structure. This approach includes the effective moduli method for composite me-chanics, the simulation of representative volumes and the finite element method. In order to take into account nanoscale sizes of pores, the Gurtin-Murdoch model of surface stresses and the highly conducting interface model are used at the borders between material and pores. The general methodology for determination of effective properties of porous composites is demonstrated for a two-phase composite with special conditions for stresses and heat flux discontinuities at the phase interfaces. The mathematical statements of boundary value problems and the resulting formulas to determine the complete set of effective constants of the two-phase composites with arbitrary anisotropy and with surface properties are described; the generalized statements are formulated and the finite element approximations are given. It is shown that the homogenization procedures for porous composites with surface effects can be considered as special cases of the corresponding procedures for the two-phase composites with interphase stresses and heat fluxes if the moduli of nanoinclusions are negligibly small. These approaches have been implemented in the finite element package ANSYS for a model of porous material with cubic crystal system for various values of surface moduli, porosity and number of pores. It has been noted that the magnitude of the area of the interphase boundaries has influence on the effective moduli of the porous materials with nanosized structure.

  2. Well-crystalline porous ZnO-SnO2 nanosheets: an effective visible-light driven photocatalyst and highly sensitive smart sensor material.

    PubMed

    Lamba, Randeep; Umar, Ahmad; Mehta, S K; Kansal, Sushil Kumar

    2015-01-01

    This work demonstrates the synthesis and characterization of porous ZnO-SnO2 nanosheets prepared by the simple and facile hydrothermal method at low-temperature. The prepared nanosheets were characterized by several techniques which revealed the well-crystallinity, porous and well-defined nanosheet morphology for the prepared material. The synthesized porous ZnO-SnO2 nanosheets were used as an efficient photocatalyst for the photocatalytic degradation of highly hazardous dye, i.e., direct blue 15 (DB 15), under visible-light irradiation. The excellent photocatalytic degradation of prepared material towards DB 15 dye could be ascribed to the formation of ZnO-SnO2 heterojunction which effectively separates the photogenerated electron-hole pairs and possess high surface area. Further, the prepared porous ZnO-SnO2 nanosheets were utilized to fabricate a robust chemical sensor to detect 4-nitrophenol in aqueous medium. The fabricated sensor exhibited extremely high sensitivity of ~ 1285.76 µA/mmol L(-1)cm(-2) and an experimental detection limit of 0.078 mmol L(-1) with a linear dynamic range of 0.078-1.25 mmol L(-1). The obtained results confirmed that the prepared porous ZnO-SnO2 nanosheets are potential material for the removal of organic pollutants under visible light irradiation and efficient chemical sensing applications. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. Nitrogen-Doped Porous Carbon Nanosheets from Eco-Friendly Eucalyptus Leaves as High Performance Electrode Materials for Supercapacitors and Lithium Ion Batteries.

    PubMed

    Mondal, Anjon Kumar; Kretschmer, Katja; Zhao, Yufei; Liu, Hao; Wang, Chengyin; Sun, Bing; Wang, Guoxiu

    2017-03-13

    Nitrogen-doped porous carbon nanosheets were prepared from eucalyptus tree leaves by simply mixing the leaf powders with KHCO 3 and subsequent carbonisation. Porous carbon nanosheets with a high specific surface area of 2133 m 2  g -1 were obtained and applied as electrode materials for supercapacitors and lithium ion batteries. For supercapacitor applications, the porous carbon nanosheet electrode exhibited a supercapacitance of 372 F g -1 at a current density of 500 mA g -1 in 1 m H 2 SO 4 aqueous electrolyte and excellent cycling stability over 15 000 cycles. In organic electrolyte, the nanosheet electrode showed a specific capacitance of 71 F g -1 at a current density of 2 Ag -1 and stable cycling performance. When applied as the anode material for lithium ion batteries, the as-prepared porous carbon nanosheets also demonstrated a high specific capacity of 819 mA h g -1 at a current density of 100 mA g -1 , good rate capability, and stable cycling performance. The outstanding electrochemical performances for both supercapacitors and lithium ion batteries are derived from the large specific surface area, porous nanosheet structure and nitrogen doping effects. The strategy developed in this paper provides a novel route to utilise biomass-derived materials for low-cost energy storage systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Vertically porous nickel thin film supported Mn3O4 for enhanced energy storage performance.

    PubMed

    Li, Xiao-Jun; Song, Zhi-Wei; Zhao, Yong; Wang, Yue; Zhao, Xiu-Chen; Liang, Minghui; Chu, Wei-Guo; Jiang, Peng; Liu, Ying

    2016-12-01

    Three-dimensionally porous metal materials are often used as the current collectors and support for the active materials of supercapacitors. However, the applications of vertically porous metal materials in supercapacitors are rarely reported, and the effect of vertically porous metal materials on the energy storage performance of supported metal oxides is not explored. To this end, the Mn3O4-vertically porous nickel (VPN) electrodes are fabricated via a template-free method. The Mn3O4-VPN electrode shows much higher volumetric specific capacitances than that of flat nickel film supported Mn3O4 with the same loading under the same measurement conditions. The volumetric specific capacitance of the vertically porous nickel supported Mn3O4 electrode can reach 533Fcm(-3) at the scan rate of 2mVs(-1). The fabricated flexible all-solid microsupercapacitor based on the interdigital Mn3O4-VPN electrode has a volumetric specific capacitance of 110Fcm(-3) at the current density of 20μAcm(-2). The capacitance retention rate of this microsupercapacitor reaches 95% after 5000 cycles under the current density of 20μAcm(-2). The vertical pores in the nickel electrode not only fit the micro/nanofabrication process of the Mn3O4-VPN electrode, but also play an important role in enhancing the capacitive performances of supported Mn3O4 particles. Copyright © 2016 Elsevier Inc. All rights reserved.

  5. Spectral characterization of porous dielectric subwavelength THz fibers fabricated using a microstructured molding technique.

    PubMed

    Dupuis, Alexandre; Mazhorova, Anna; Désévédavy, Frédéric; Rozé, Mathieu; Skorobogatiy, Maksim

    2010-06-21

    We report two novel fabrication techniques, as well as THz spectral transmission and propagation loss measurements of subwavelength plastic wires with highly porous (up to 86%) and non-porous transverse geometries. The two fabrication techniques we describe are based on the microstructured molding approach. In one technique the mold is made completely from silica by stacking and fusing silica capillaries to the bottom of a silica ampoule. The melted material is then poured into the silica mold to cast the microstructured preform. Another approach uses a microstructured mold made of a sacrificial plastic which is co-drawn with a cast preform. Material from the sacrificial mold is then dissolved after fi ber drawing. We also describe a novel THz-TDS setup with an easily adjustable optical path length, designed to perform cutback measurements using THz fibers of up to 50 cm in length. We fi nd that while both porous and non-porous subwavelength fibers of the same outside diameter have low propagation losses (alpha

  6. Ultrafast triggered transient energy storage by atomic layer deposition into porous silicon for integrated transient electronics

    NASA Astrophysics Data System (ADS)

    Douglas, Anna; Muralidharan, Nitin; Carter, Rachel; Share, Keith; Pint, Cary L.

    2016-03-01

    Here we demonstrate the first on-chip silicon-integrated rechargeable transient power source based on atomic layer deposition (ALD) coating of vanadium oxide (VOx) into porous silicon. A stable specific capacitance above 20 F g-1 is achieved until the device is triggered with alkaline solutions. Due to the rational design of the active VOx coating enabled by ALD, transience occurs through a rapid disabling step that occurs within seconds, followed by full dissolution of all active materials within 30 minutes of the initial trigger. This work demonstrates how engineered materials for energy storage can provide a basis for next-generation transient systems and highlights porous silicon as a versatile scaffold to integrate transient energy storage into transient electronics.Here we demonstrate the first on-chip silicon-integrated rechargeable transient power source based on atomic layer deposition (ALD) coating of vanadium oxide (VOx) into porous silicon. A stable specific capacitance above 20 F g-1 is achieved until the device is triggered with alkaline solutions. Due to the rational design of the active VOx coating enabled by ALD, transience occurs through a rapid disabling step that occurs within seconds, followed by full dissolution of all active materials within 30 minutes of the initial trigger. This work demonstrates how engineered materials for energy storage can provide a basis for next-generation transient systems and highlights porous silicon as a versatile scaffold to integrate transient energy storage into transient electronics. Electronic supplementary information (ESI) available: (i) Experimental details for ALD and material fabrication, ellipsometry film thickness, preparation of gel electrolyte and separator, details for electrochemical measurements, HRTEM image of VOx coated porous silicon, Raman spectroscopy for VOx as-deposited as well as annealed in air for 1 hour at 450 °C, SEM and transient behavior dissolution tests of uniformly coated VOx on porous silicon, dissolution tests for 0.1 M and 0.01 M NaOH trigger solutions, EIS analysis for VOx coated devices, and EDS compositional analysis of VOx. (ii) Video showing transient behavior of integrated VOx/porous silicon scaffolds. See DOI: 10.1039/c5nr09095d

  7. Asteroid deflection using a kinetic impactor: Insights from hypervelocity impact experiments

    NASA Astrophysics Data System (ADS)

    Hoerth, Tobias; Schäfer, Frank

    2016-04-01

    Within the framework of the planned AIDA mission [1], an impactor spacecraft (DART) hits the second component of the asteroid Didymos at hypervelocity. The impact crater will be observed from the AIM spacecraft and an observation of the ejecta plume is possible [1]. This allows conclusions to be drawn about the physical properties of the target material, and the momentum transfer will be studied [1]. In preparation for this mission, hypervelocity impact experiments can provide valuable information about the outcome of an impact event as a function of impactor and target material properties and, thus, support the interpretation of the data from the DART impact. In addition, these impact experiments provide an important means to validate numerical impact simulations required to simulate large-scale impacts that cannot be studied in laboratory experiments. Impact experiments have shown that crater morphology and size, crater growth and ejecta dynamics strongly depend on the physical properties of the target material [2]. For example, porous materials like sandstone lead to a shallower and slower ejection than low-porous materials like quartzite, and the cratering efficiency is reduced in porous targets leading to a smaller amount of ejected mass [3]. These phenomena result in a reduced momentum multiplication factor (often called "beta-value"), i.e. the ratio of the change in target momentum after the impact and the momentum of the projectile is smaller for porous materials. Hypervelocity impact experiments into target materials with different porosities and densities such as quartzite (2.9 %, 2.6 g/cm3), sandstone (25.3 %, 2 g/cm3), limestone (31 %, 1.8 g/cm3), and highly porous aerated concrete (87.5 %, 0.4 g/cm3) were conducted. Projectile velocities were varied between about 3 km/s and almost 7 km/s. A ballistic pendulum was used to measure the momentum transfer. The material strength required for scaling laws was determined for all target materials. The highest beta values were measured for the low-porous quartzite (e.g., beta ~ 3 for a projectile velocity of about 4.05 km/s). Porous materials like sandstone, on the other hand, show lower beta values (e.g., beta ~ 1.8 for a projectile velocity of about 4.11 km/s). [1] Cheng A. F. et al. 2015 Acta Astronaut 115:262-269 [2] Hoerth T. et al. 2013 Meteorit Planet Sci 48:23-32 [3] Hoerth T. et al. 2015 Proc Engin 103:197-204

  8. Surface modification of porous titanium with rice husk as space holder

    NASA Astrophysics Data System (ADS)

    Wang, Xinsheng; Hou, Junjian; Liu, Yanpei

    2018-06-01

    Porous titanium was characterized after its surface modification by acid and alkali solution immersion. The results show that the acid surface treatment caused the emergence of flocculent sodium titanate and induced apatite formation. The surface modification of porous titanium promotes biological activation, and the application of porous titanium is also improved as an implant material because of the existence of C and Si.

  9. Popcorn-Derived Porous Carbon Flakes with an Ultrahigh Specific Surface Area for Superior Performance Supercapacitors.

    PubMed

    Hou, Jianhua; Jiang, Kun; Wei, Rui; Tahir, Muhammad; Wu, Xiaoge; Shen, Ming; Wang, Xiaozhi; Cao, Chuanbao

    2017-09-13

    Popcorn-derived porous carbon flakes have been successfully fabricated from the biomass of maize. Utilizing the "puffing effect", the nubby maize grain turned into materials with an interconnected honeycomb-like porous structure composed of carbon flakes. The following chemical activation method enabled the as-prepared products to possess optimized porous structures for electrochemical energy-storage devices, such as multilayer flake-like structures, ultrahigh specific surface area (S BET : 3301 m 2 g -1 ), and a high content of micropores (microporous surface area of 95%, especially the optimized sub-nanopores with the size of 0.69 nm) that can increase the specific capacitance. The as-obtained sample displayed excellent specific capacitance of 286 F g -1 at 90 A g -1 for supercapacitors. Moreover, the unique porous structure demonstrated an ideal way to improve the volumetric energy density performance. A high energy density of 103 Wh kg -1 or 53 Wh L -1 has been obtained in the case of ionic liquid electrolyte, which is the highest among reported biomass-derived carbon materials and will satisfy the urgent requirements of a primary power source for electric vehicles. This work may prove to be a fast, green, and large-scale synthesis route by using the large nubby granular materials to synthesize applicable porous carbons in energy-storage devices.

  10. An agent-based method for simulating porous fluid-saturated structures with indistinguishable components

    NASA Astrophysics Data System (ADS)

    Kashani, Jamal; Pettet, Graeme John; Gu, YuanTong; Zhang, Lihai; Oloyede, Adekunle

    2017-10-01

    Single-phase porous materials contain multiple components that intermingle up to the ultramicroscopic level. Although the structures of the porous materials have been simulated with agent-based methods, the results of the available methods continue to provide patterns of distinguishable solid and fluid agents which do not represent materials with indistinguishable phases. This paper introduces a new agent (hybrid agent) and category of rules (intra-agent rule) that can be used to create emergent structures that would more accurately represent single-phase structures and materials. The novel hybrid agent carries the characteristics of system's elements and it is capable of changing within itself, while also responding to its neighbours as they also change. As an example, the hybrid agent under one-dimensional cellular automata formalism in a two-dimensional domain is used to generate patterns that demonstrate the striking morphological and characteristic similarities with the porous saturated single-phase structures where each agent of the ;structure; carries semi-permeability property and consists of both fluid and solid in space and at all times. We conclude that the ability of the hybrid agent to change locally provides an enhanced protocol to simulate complex porous structures such as biological tissues which could facilitate models for agent-based techniques and numerical methods.

  11. A facile and green approach for the controlled synthesis of porous SnO₂ nanospheres: application as an efficient photocatalyst and an excellent gas sensing material.

    PubMed

    Manjula, P; Boppella, Ramireddy; Manorama, Sunkara V

    2012-11-01

    A facile and elegant methodology invoking the principles of Green Chemistry for the synthesis of porous tin dioxide nanospheres has been described. The low-temperature (∼50 °C) synthesis of SnO₂ nanoparticles and their self-assembly into organized, uniform, and monodispersed porous nanospheres with high surface area is facilitated by controlling the concentration of glucose, which acts as a stabilizing as well as structure-directing agent. A systematic control on the stannate to glucose molar concentration ratio determines the exact conditions to obtain monodispersed nanospheres, preferentially over random aggregation. Detailed characterization of the structure, morphology, and chemical composition reveals that the synthesized material, 50 nm SnO₂ porous nanospheres possess BET surface area of about 160 m²/g. Each porous nanosphere consists of a few hundred nanoparticles ∼2-3 nm in diameter with tetragonal cassiterite crystal structure. The SnO₂ nanospheres exhibit elevated photocatalytic activity toward methyl orange with good recyclability. Because of the high activity and stability of this photocatalyst, the material is ideal for applications in environmental remediation. Moreover, SnO₂ nanospheres display excellent gas sensing capabilities toward hydrogen. Surface modification of the nanospheres with Pd transforms this sensing material into a highly sensitive and selective room-temperature hydrogen sensor.

  12. Comprehensive Utilization of Biomass Process Residues Rich in Cellulose

    NASA Astrophysics Data System (ADS)

    Zhong, Mei; Li, Qiang; Yu, Jian; Dong, Li; Wang, Yin; Xu, Guangwen

    2010-11-01

    This article investigated the method preparing porous material (PM) with VL and SL. Applications of the prepared material was tested in removal aqueous phenol and COD in tarry water and as the catalyst support for selective catalytic reduction (SCR) of NO in flue gas. The results showed that the optimal activation condition in CO2 for the carbonized VL at 800° C was at 875° C for 1 h, which provided large BET surface area and micropore volume. This material exhibited the highest adsorption to aqueous phenol among all the tested materials including a commercial activated carbon made from coconut shell, showing the potential application of the VL-base porous material in wastewater treatment. The study demonstrated also that the vanadium-base selective catalytic reduction (SCR) catalyst supported on the VL-base porous material (V2O5/VL-PM) provided fairly good activity as well SO2 resistance at temperatures round 200° C for SCR of NO. The activation of the carbonized SL material in H2O was better than that in CO2 for developing the pore structure of the porous material. Steam can improve the formation of mesopore than CO2. This was confirmed by the conclusion that higher COD removal rate was occurred on the PM-1 from SL when H2O was used as an activator.

  13. Hydrology and simulation of ground-water flow in Kamas Valley, Summit County, Utah

    USGS Publications Warehouse

    Brooks, L.E.; Stolp, B.J.; Spangler, L.E.

    2003-01-01

    Kamas Valley, Utah, is located about 50 miles east of Salt Lake City and is undergoing residential development. The increasing number of wells and septic systems raised concerns of water managers and prompted this hydrologic study. About 350,000 acre-feet per year of surface water flows through Kamas Valley in the Weber River, Beaver Creek, and Provo River, which originate in the Uinta Mountains east of the study area. The ground-water system in this area consists of water in unconsolidated deposits and consolidated rock; water budgets indicate very little interaction between consolidated rock and unconsolidated deposits. Most recharge to consolidated rock occurs at higher altitudes in the mountains and discharges to streams and springs upgradient of Kamas Valley. About 38,000 acre-feet per year of water flows through the unconsolidated deposits in Kamas Valley. Most recharge is from irrigation and seepage from major streams; most discharge is to Beaver Creek in the middle part of the valley. Long-term water-level fluctuations range from about 3 to 17 feet. Seasonal fluctuations exceed 50 feet. Transmissivity varies over four orders of magnitude in both the unconsolidated deposits and consolidated rock and is typically 1,000 to 10,000 feet squared per day in unconsolidated deposits and 100 feet squared per day in consolidated rock as determined from specific capacity. Water samples collected from wells, streams, and springs had nitrate plus nitrite concentrations (as N) substantially less than 10 mg/L. Total and fecal coliform bacteria were detected in some surface-water samples and probably originate from livestock. Septic systems do not appear to be degrading water quality. A numerical ground-water flow model developed to test the conceptual understanding of the ground-water system adequately simulates water levels and flow in the unconsolidated deposits. Analyses of model fit and sensitivity were used to refine the conceptual and numerical models.

  14. Carbon composition with hierarchical porosity, and methods of preparation

    DOEpatents

    Mayes, Richard T; Dai, Sheng

    2014-10-21

    A method for fabricating a porous carbon material possessing a hierarchical porosity, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic component, (iii) a dione component in which carbonyl groups are adjacent, and (iv) an acidic component, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a carbon material possessing a hierarchical porosity comprised of mesopores and macropores. Also described are the resulting hierarchical porous carbon material, a capacitive deionization device in which the porous carbon material is incorporated, as well as methods for desalinating water by use of said capacitive deionization device.

  15. The Effects of Terrain Properties on Determining Crater Model Ages of Lunar Surfaces

    NASA Astrophysics Data System (ADS)

    Kirchoff, M. R.; Marchi, S.

    2017-12-01

    Analyzing crater size-frequency distributions (SFDs) and using them to determine model ages of surfaces is an important technique for understanding the Moon's geologic history and evolution. Small craters with diameters (D) < 1 km are frequently used, especially given the very high resolution imaging now available from Lunar Reconnaissance Orbiter Narrow and Wide Angle Cameras (LROC-NAC/WAC) and the Selene Terrain Camera. However, for these diameters, final crater sizes and shapes are affected by the properties of the terrains on which they are formed [1], which alters crater SFD shapes [2]. We use the Model Production Function (MPF; [2]), which includes terrain properties in computing crater production functions, to explore how incorporating terrain properties affects the estimation of crater model ages. First, crater SFDs are compiled utilizing LROC-WAC/NAC images to measure craters with diameters from 10 m up to 20 km (size of largest crater measured depends on the terrain). A nested technique is used to obtain this wide diameter range: D ≥ 0.5 km craters are measured in the largest area, D = 0.09-0.5 km craters are measured in a smaller area within the largest area, and D = 0.01-0.1 km craters are measured in the smallest area located in both of the larger areas. Then, we quantitatively fit the crater SFD with distinct MPFs that use broadly different terrain properties. Terrain properties are varied through coarsely altering the parameters in the crater scaling law [1] that represent material type (consolidated, unconsolidated, porous), material tensile strength, and material density (for further details see [2]). We also discuss the effect of changing terrain properties with depth (i.e., layering). Finally, fits are used to compute the D = 1 km crater model ages for the terrains. We discuss the new constraints on how terrain properties affect crater model ages from our analyses of a variety of lunar terrains from highlands to mare and impact melt to continuous ejecta deposits. References: [1] Holsapple, K. A & Housen, K. R., Icarus 187, 345-356, 2007. [2] Marchi, S., et al., AJ 137, 4936-4948, 2009.

  16. Designed porosity materials in nuclear reactor components

    DOEpatents

    Yacout, A. M.; Pellin, Michael J.; Stan, Marius

    2016-09-06

    A nuclear fuel pellet with a porous substrate, such as a carbon or tungsten aerogel, on which at least one layer of a fuel containing material is deposited via atomic layer deposition, and wherein the layer deposition is controlled to prevent agglomeration of defects. Further, a method of fabricating a nuclear fuel pellet, wherein the method features the steps of selecting a porous substrate, depositing at least one layer of a fuel containing material, and terminating the deposition when the desired porosity is achieved. Also provided is a nuclear reactor fuel cladding made of a porous substrate, such as silicon carbide aerogel or silicon carbide cloth, upon which layers of silicon carbide are deposited.

  17. Fabrication of Porous Materials from Natural/Synthetic Biopolymers and Their Composites.

    PubMed

    Sampath, Udeni Gunathilake T M; Ching, Yern Chee; Chuah, Cheng Hock; Sabariah, Johari J; Lin, Pai-Chen

    2016-12-07

    Biopolymers and their applications have been widely studied in recent years. Replacing the oil based polymer materials with biopolymers in a sustainable manner might give not only a competitive advantage but, in addition, they possess unique properties which cannot be emulated by conventional polymers. This review covers the fabrication of porous materials from natural biopolymers (cellulose, chitosan, collagen), synthetic biopolymers (poly(lactic acid), poly(lactic- co -glycolic acid)) and their composite materials. Properties of biopolymers strongly depend on the polymer structure and are of great importance when fabricating the polymer into intended applications. Biopolymers find a large spectrum of application in the medical field. Other fields such as packaging, technical, environmental, agricultural and food are also gaining importance. The introduction of porosity into a biomaterial broadens the scope of applications. There are many techniques used to fabricate porous polymers. Fabrication methods, including the basic and conventional techniques to the more recent ones, are reviewed. Advantages and limitations of each method are discussed in detail. Special emphasis is placed on the pore characteristics of biomaterials used for various applications. This review can aid in furthering our understanding of the fabrication methods and about controlling the porosity and microarchitecture of porous biopolymer materials.

  18. Fabrication of Porous Materials from Natural/Synthetic Biopolymers and Their Composites

    PubMed Central

    Sampath, Udeni Gunathilake T.M.; Ching, Yern Chee; Chuah, Cheng Hock; Sabariah, Johari J.; Lin, Pai-Chen

    2016-01-01

    Biopolymers and their applications have been widely studied in recent years. Replacing the oil based polymer materials with biopolymers in a sustainable manner might give not only a competitive advantage but, in addition, they possess unique properties which cannot be emulated by conventional polymers. This review covers the fabrication of porous materials from natural biopolymers (cellulose, chitosan, collagen), synthetic biopolymers (poly(lactic acid), poly(lactic-co-glycolic acid)) and their composite materials. Properties of biopolymers strongly depend on the polymer structure and are of great importance when fabricating the polymer into intended applications. Biopolymers find a large spectrum of application in the medical field. Other fields such as packaging, technical, environmental, agricultural and food are also gaining importance. The introduction of porosity into a biomaterial broadens the scope of applications. There are many techniques used to fabricate porous polymers. Fabrication methods, including the basic and conventional techniques to the more recent ones, are reviewed. Advantages and limitations of each method are discussed in detail. Special emphasis is placed on the pore characteristics of biomaterials used for various applications. This review can aid in furthering our understanding of the fabrication methods and about controlling the porosity and microarchitecture of porous biopolymer materials. PMID:28774113

  19. Preparation and characterization of porous Mg-Zn-Ca alloy by space holder technique

    NASA Astrophysics Data System (ADS)

    Annur, D.; Lestari, Franciska P.; Erryani, A.; Sijabat, Fernando A.; G. P. Astawa, I. N.; Kartika, I.

    2018-04-01

    Magnesium had been recently researched as a future biodegradable implant material. In the recent study, porous Mg-Zn-Ca alloys were developed using space holder technique in powder metallurgy process. Carbamide (10-20%wt) was added into Mg-6Zn-1Ca (in wt%) alloy system as a space holder to create porous structure material. Sintering process was done in a tube furnace under Argon atmosphere in 610 °C for 5 hours. Porous structure of the resulted alloy was examined using Scanning Electron Microscope (SEM), while the phase formation was characterized by X-ray diffraction analysis (XRD). Further, mechanical properties of porous Mg-Zn-Ca alloy was examined through compression testing. Microstructure characterization showed higher content of Carbamide in the alloy would give different type of pores. However, compression test showed that mechanical properties of Mg-Zn-Ca alloy would decrease significantly when higher content of carbamide was added.

  20. Sound transmission through stiffened double-panel structures lined with elastic porous materials

    NASA Astrophysics Data System (ADS)

    Mathur, Gopal P.; Tran, Boi N.; Bolton, J. S.; Shiau, Nae-Ming

    This paper presents transmission loss prediction models for a periodically stiffened panel and stiffened double-panel structures using the periodic structure theory. The inter-panel cavity in the double-panels structures can be modeled as being separated by an airspace or filled with an elastic porous layer in various configurations. The acoustic behavior of elastic porous layer is described by a theory capable of accounting fully for multi-dimensional wave propagation in such materials. The predicted transmission loss of a single stiffened panel is compared with the measured data.

  1. Electronic Chemical Potentials of Porous Metal–Organic Frameworks

    PubMed Central

    2014-01-01

    The binding energy of an electron in a material is a fundamental characteristic, which determines a wealth of important chemical and physical properties. For metal–organic frameworks this quantity is hitherto unknown. We present a general approach for determining the vacuum level of porous metal–organic frameworks and apply it to obtain the first ionization energy for six prototype materials including zeolitic, covalent, and ionic frameworks. This approach for valence band alignment can explain observations relating to the electrochemical, optical, and electrical properties of porous frameworks. PMID:24447027

  2. Effects of applied stress ratio on the fatigue behavior of additively manufactured porous biomaterials under compressive loading.

    PubMed

    de Krijger, Joep; Rans, Calvin; Van Hooreweder, Brecht; Lietaert, Karel; Pouran, Behdad; Zadpoor, Amir A

    2017-06-01

    Additively manufactured (AM) porous metallic biomaterials are considered promising candidates for bone substitution. In particular, AM porous titanium can be designed to exhibit mechanical properties similar to bone. There is some experimental data available in the literature regarding the fatigue behavior of AM porous titanium, but the effect of stress ratio on the fatigue behavior of those materials has not been studied before. In this paper, we study the effect of applied stress ratio on the compression-compression fatigue behavior of selective laser melted porous titanium (Ti-6Al-4V) based on the diamond unit cell. The porous titanium biomaterial is treated as a meta-material in the context of this work, meaning that R-ratios are calculated based on the applied stresses acting on a homogenized volume. After morphological characterization using micro computed tomography and quasi-static mechanical testing, the porous structures were tested under cyclic loading using five different stress ratios, i.e. R = 0.1, 0.3, 0.5, 0.7 and 0.8, to determine their S-N curves. Feature tracking algorithms were used for full-field deformation measurements during the fatigue tests. It was observed that the S-N curves of the porous structures shift upwards as the stress ratio increases. The stress amplitude was the most important factor determining the fatigue life. Constant fatigue life diagrams were constructed and compared with similar diagrams for bulk Ti-6Al-4V. Contrary to the bulk material, there was limited dependency of the constant life diagrams to mean stress. The notches present in the AM biomaterials were the sites of crack initiation. This observation and other evidence suggest that the notches created by the AM process cause the insensitivity of the fatigue life diagrams to mean stress. Feature tracking algorithms visualized the deformation during fatigue tests and demonstrated the root cause of inclined (45°) planes of specimen failure. In conclusion, the R-ratio behavior of AM porous biomaterials is both quantitatively and qualitatively different from that of bulk materials. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Conductive polymer layers to limit transfer of fuel reactants to catalysts of fuel cells to reduce reactant crossover

    DOEpatents

    Stanis, Ronald J.; Lambert, Timothy N.

    2016-12-06

    An apparatus of an aspect includes a fuel cell catalyst layer. The fuel cell catalyst layer is operable to catalyze a reaction involving a fuel reactant. A fuel cell gas diffusion layer is coupled with the fuel cell catalyst layer. The fuel cell gas diffusion layer includes a porous electrically conductive material. The porous electrically conductive material is operable to allow the fuel reactant to transfer through the fuel cell gas diffusion layer to reach the fuel cell catalyst layer. The porous electrically conductive material is also operable to conduct electrons associated with the reaction through the fuel cell gas diffusion layer. An electrically conductive polymer material is coupled with the fuel cell gas diffusion layer. The electrically conductive polymer material is operable to limit transfer of the fuel reactant to the fuel cell catalyst layer.

  4. Preparation of porous PLA/DBM composite biomaterials and experimental research of repair rabbit radius segmental bone defect.

    PubMed

    Zhang, Yumin; Wang, Jianru; Wang, Jue; Niu, Xiaojun; Liu, Jianchun; Gao, Lan; Zhai, Xiaoyan; Chu, Kaibo

    2015-12-01

    Bone substitutes are used in wide range of orthopaedic application. An ideal bone substitute should exhibit superior osteoinductive and osteoconductive properties. Neither bio-derived materials nor synthetic materials can meet the needs of an ideal bone substitute. Preparation of composite materials is a promising way to improve properties of biomaterial. In this study, the porous poly lactic acid (PLA)/demineralized bone matrix (DBM) composite biomaterials prepared by supercritical CO2 technique were implanted to repair rabbit radius segmental bone defect. By comparing with PLA and bone autograft, the X-ray result and histological analysis showed the repair effect of PLA/DBM porous composite materials is significantly better than that of the PLA group and the blank control group, and is similar to autologous bone. The PLA/DBM can promote the healing of bone defects and can be used as a kind of ideal alternative materials to repair bone defects.

  5. Experimental determination of the viscous flow permeability of porous materials by measuring reflected low frequency acoustic waves

    NASA Astrophysics Data System (ADS)

    Berbiche, A.; Sadouki, M.; Fellah, Z. E. A.; Ogam, E.; Fellah, M.; Mitri, F. G.; Depollier, C.

    2016-01-01

    An acoustic reflectivity method is proposed for measuring the permeability or flow resistivity of air-saturated porous materials. In this method, a simplified expression of the reflection coefficient is derived in the Darcy's regime (low frequency range), which does not depend on frequency and porosity. Numerical simulations show that the reflection coefficient of a porous material can be approximated by its simplified expression obtained from its Taylor development to the first order. This approximation is good especially for resistive materials (of low permeability) and for the lower frequencies. The permeability is reconstructed by solving the inverse problem using waves reflected by plastic foam samples, at different frequency bandwidths in the Darcy regime. The proposed method has the advantage of being simple compared to the conventional methods that use experimental reflected data, and is complementary to the transmissivity method, which is more adapted to low resistive materials (high permeability).

  6. Constitutive Models Based on Compressible Plastic Flows

    NASA Technical Reports Server (NTRS)

    Rajendran, A. M.

    1983-01-01

    The need for describing materials under time or cycle dependent loading conditions has been emphasized in recent years by several investigators. In response to the need, various constitutive models describing the nonlinear behavior of materials under creep, fatigue, or other complex loading conditions were developed. The developed models for describing the fully dense (non-porous) materials were mostly based on uncoupled plasticity theory. The improved characterization of materials provides a better understanding of the structual response under complex loading conditions. The pesent studies demonstrate that the rate or time dependency of the response of a porous aggregate can be incorporated into the nonlinear constitutive behavior of a porous solid by appropriately modeling the incompressible matrix behavior. It is also sown that the yield function which wads determined by a continuum mechanics approach must be verified by appropriate experiments on void containing sintered materials in order to obtain meaningful numbers for the constants that appear in the yield function.

  7. Ceramic TBS/porous metal compliant layer

    NASA Technical Reports Server (NTRS)

    Tolokan, Robert P.; Jarrabet, G. P.

    1992-01-01

    Technetics Corporation manufactures metal fiber materials and components used in aerospace applications. Our technology base is fiber metal porous sheet material made from sinter bonded metal fibers. Fiber metals have percent densities (metal content by volume) from 10 to 65 percent. Various topics are covered and include the following: fiber metal materials, compliant layer thermal bayer coatings (TBC's), pad properties, ceramic/pad TBC design, thermal shock rig, fabrication, and applications.

  8. Biological evaluation and finite-element modeling of porous poly(para-phenylene) for orthopaedic implants.

    PubMed

    Ahn, Hyunhee; Patel, Ravi R; Hoyt, Anthony J; Lin, Angela S P; Torstrick, F Brennan; Guldberg, Robert E; Frick, Carl P; Carpenter, R Dana; Yakacki, Christopher M; Willett, Nick J

    2018-05-01

    Poly(para-phenylene) (PPP) is a novel aromatic polymer with higher strength and stiffness than polyetheretherketone (PEEK), the gold standard material for polymeric load-bearing orthopaedic implants. The amorphous structure of PPP makes it relatively straightforward to manufacture different architectures, while maintaining mechanical properties. PPP is promising as a potential orthopaedic material; however, the biocompatibility and osseointegration have not been well investigated. The objective of this study was to evaluate biological and mechanical behavior of PPP, with or without porosity, in comparison to PEEK. We examined four specific constructs: 1) solid PPP, 2) solid PEEK, 3) porous PPP and 4) porous PEEK. Pre-osteoblasts (MC3T3) exhibited similar cell proliferation among the materials. Osteogenic potential was significantly increased in the porous PPP scaffold as assessed by ALP activity and calcium mineralization. In vivo osseointegration was assessed by implanting the cylindrical materials into a defect in the metaphysis region of rat tibiae. Significantly more mineral ingrowth was observed in both porous scaffolds compared to the solid scaffolds, and porous PPP had a further increase compared to porous PEEK. Additionally, porous PPP implants showed bone formation throughout the porous structure when observed via histology. A computational simulation of mechanical push-out strength showed approximately 50% higher interfacial strength in the porous PPP implants compared to the porous PEEK implants and similar stress dissipation. These data demonstrate the potential utility of PPP for orthopaedic applications and show improved osseointegration when compared to the currently available polymeric material. PEEK has been widely used in orthopaedic surgery; however, the ability to utilize PEEK for advanced fabrication methods, such as 3D printing and tailored porosity, remain challenging. We present a promising new orthopaedic biomaterial, Poly(para-phenylene) (PPP), which is a novel class of aromatic polymers with higher strength and stiffness than polyetheretherketone (PEEK). PPP has exceptional mechanical strength and stiffness due to its repeating aromatic rings that provide strong anti-rotational biaryl bonds. Furthermore, PPP has an amorphous structure making it relatively easier to manufacture (via molding or solvent-casting techniques) into different geometries with and without porosity. This ability to manufacture different architectures and use different processes while maintaining mechanical properties makes PPP a very promising potential orthopaedic biomaterial which may allow for closer matching of mechanical properties between the host bone tissue while also allowing for enhanced osseointegration. In this manuscript, we look at the potential of porous and solid PPP in comparison to PEEK. We measured the mechanical properties of PPP and PEEK scaffolds, tested these scaffolds in vitro for osteocompatibility with MC3T3 cells, and then tested the osseointegration and subsequent functional integration in vivo in a metaphyseal drill hole model in rat tibia. We found that PPP permits cell adhesion, growth, and mineralization in vitro. In vivo it was found that porous PPP significantly enhanced mineralization into the construct and increased the mechanical strength required to push out the scaffold in comparison to PEEK. This is the first study to investigate the performance of PPP as an orthopaedic biomaterial in vivo. PPP is an attractive material for orthopaedic implants due to the ease of manufacturing and superior mechanical strength. Copyright © 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  9. Porous wall hollow glass microspheres as a medium or substrate for storage and formation of novel materials

    DOEpatents

    Wicks, George G; Serkiz, Steven M.; Zidan, Ragaiy; Heung, Leung K.

    2014-06-24

    Porous wall hollow glass microspheres are provided as a template for formation of nanostructures such as carbon nanotubes, In addition, the carbon nanotubes in combination with the porous wall hollow glass microsphere provides an additional reaction template with respect to carbon nanotubes.

  10. Disorder-induced stiffness degradation of highly disordered porous materials

    NASA Astrophysics Data System (ADS)

    Laubie, Hadrien; Monfared, Siavash; Radjaï, Farhang; Pellenq, Roland; Ulm, Franz-Josef

    2017-09-01

    The effective mechanical behavior of multiphase solid materials is generally modeled by means of homogenization techniques that account for phase volume fractions and elastic moduli without considering the spatial distribution of the different phases. By means of extensive numerical simulations of randomly generated porous materials using the lattice element method, the role of local textural properties on the effective elastic properties of disordered porous materials is investigated and compared with different continuum micromechanics-based models. It is found that the pronounced disorder-induced stiffness degradation originates from stress concentrations around pore clusters in highly disordered porous materials. We identify a single disorder parameter, φsa, which combines a measure of the spatial disorder of pores (the clustering index, sa) with the pore volume fraction (the porosity, φ) to scale the disorder-induced stiffness degradation. Thus, we conclude that the classical continuum micromechanics models with one spherical pore phase, due to their underlying homogeneity assumption fall short of addressing the clustering effect, unless additional texture information is introduced, e.g. in form of the shift of the percolation threshold with disorder, or other functional relations between volume fractions and spatial disorder; as illustrated herein for a differential scheme model representative of a two-phase (solid-pore) composite model material.

  11. Quasi-optic millimeter-wave device application of liquid crystal material by using porous PMMA matrix

    NASA Astrophysics Data System (ADS)

    Nose, T.; Watanabe, Y.; Kon, A.; Ito, R.; Honma, M.

    2018-02-01

    Recently, millimeter-waves (MMWs) have become indispensable for application in next-generation high-speed wireless communication i.e., 5G, in addition to conventional applications such as in automobile collision avoidance radars and airport security inspection systems. Some manageable devices to control MMW propagation will be necessary with the development of this new technology field. We believe that liquid crystal (LC) devices are one of the major candidates for such applications because it is known that LC materials are excellent electro-optic materials. However, as the wavelength of MMWs is extremely longer than the optics region, extremely thick LC layers are necessary if we choose the quasioptic approach to attain LC MMW control devices. Therefore, we adopt a PDLC structure to attain the extremely thick LC layers by using porous (polymethyl methacrylate) PMMA materials, which can be easily obtained using a solvent consisting of a mixture of ethanol/water and a little heating. In this work, we focus on Fresnel lens, which is an important quasi-optic device for MMW application, to introduce a tunable property by using LC materials. Here, we adopt the thin film deposition method to obtain a porous PMMA matrix with the aim of obtaining final composite structure based on the Fresnel substrate. First, the fundamental material properties of porous PMMA are investigated to control the microscopic porous structure. Then, the LC-MMW Fresnel lens substrate is prepared using a 3D printer, and the fundamental MMW focusing properties of the prototype composite Fresnel structure are investigated.

  12. Gas hydrate formation rates from dissolved-phase methane in porous laboratory specimens

    USGS Publications Warehouse

    Waite, William F.; Spangenberg, E.K.

    2013-01-01

    Marine sands highly saturated with gas hydrates are potential energy resources, likely forming from methane dissolved in pore water. Laboratory fabrication of gas hydrate-bearing sands formed from dissolved-phase methane usually requires 1–2 months to attain the high hydrate saturations characteristic of naturally occurring energy resource targets. A series of gas hydrate formation tests, in which methane-supersaturated water circulates through 100, 240, and 200,000 cm3 vessels containing glass beads or unconsolidated sand, show that the rate-limiting step is dissolving gaseous-phase methane into the circulating water to form methane-supersaturated fluid. This implies that laboratory and natural hydrate formation rates are primarily limited by methane availability. Developing effective techniques for dissolving gaseous methane into water will increase formation rates above our observed (1 ± 0.5) × 10−7 mol of methane consumed for hydrate formation per minute per cubic centimeter of pore space, which corresponds to a hydrate saturation increase of 2 ± 1% per day, regardless of specimen size.

  13. Measurement and modeling of CO2 mass transfer in brine at reservoir conditions

    NASA Astrophysics Data System (ADS)

    Shi, Z.; Wen, B.; Hesse, M. A.; Tsotsis, T. T.; Jessen, K.

    2018-03-01

    In this work, we combine measurements and modeling to investigate the application of pressure-decay experiments towards delineation and interpretation of CO2 solubility, uptake and mass transfer in water/brine systems at elevated pressures of relevance to CO2 storage operations in saline aquifers. Accurate measurements and modeling of mass transfer in this context are crucial to an improved understanding of the longer-term fate of CO2 that is injected into the subsurface for storage purposes. Pressure-decay experiments are presented for CO2/water and CO2/brine systems with and without the presence of unconsolidated porous media. We demonstrate, via high-resolution numerical calculations in 2-D, that natural convection will complicate the interpretation of the experimental observations if the particle size is not sufficiently small. In such settings, we demonstrate that simple 1-D interpretations can result in an overestimation of the uptake (diffusivity) by two orders of magnitude. Furthermore, we demonstrate that high-resolution numerical calculations agree well with the experimental observations for settings where natural convection contributes substantially to the overall mass transfer process.

  14. Computer design of porous active materials at different dimensional scales

    NASA Astrophysics Data System (ADS)

    Nasedkin, Andrey

    2017-12-01

    The paper presents a mathematical and computer modeling of effective properties of porous piezoelectric materials of three types: with ordinary porosity, with metallized pore surfaces, and with nanoscale porosity structure. The described integrated approach includes the effective moduli method of composite mechanics, simulation of representative volumes, and finite element method.

  15. Hyper-crosslinked cyclodextrin porous polymer: An efficient CO 2 capturing material with tunable porosity

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Meng, Bo; Li, Haiyang; East China Univ. of Science and Technology, Shanghai

    We designed and synthesized the cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) for selective CO 2 adsorption and storage. We also explored the effect of monomer size on micropore formation, and determined a feasible way to tailor the porosity of the materials during the hyper-crosslinking process.

  16. Hyper-crosslinked cyclodextrin porous polymer: An efficient CO 2 capturing material with tunable porosity

    DOE PAGES

    Meng, Bo; Li, Haiyang; East China Univ. of Science and Technology, Shanghai; ...

    2016-11-11

    We designed and synthesized the cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) for selective CO 2 adsorption and storage. We also explored the effect of monomer size on micropore formation, and determined a feasible way to tailor the porosity of the materials during the hyper-crosslinking process.

  17. Metal recovery from porous materials

    DOEpatents

    Sturcken, E.F.

    1991-01-01

    The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  18. Water Adsorption in Porous Metal-Organic Frameworks and Related Materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Furukawa, H; Gandara, F; Zhang, YB

    2014-03-19

    Water adsorption in porous materials is important for many applications such as dehumidification, thermal batteries, and delivery of drinking water in remote areas. In this study, we have identified three criteria for achieving high performing porous materials for water adsorption. These criteria deal with condensation pressure of water in the pores, uptake capacity, and recyclability and water stability of the material. In search of an excellently performing porous material, we have studied and compared the water adsorption properties of 23 materials, 20 of which are metal organic frameworks (MOFs). Among the MOFs are 10 zirconium(IV) MOFs with a subset ofmore » these, MOF-801-SC (single crystal form), -802, -805, -806, -808, -812, and -841 reported for the first time. MOF-801-P (microcrystalline powder form) was reported earlier and studied here for its water adsorption properties. MOF-812 was only made and structurally characterized but not examined for water adsorption because it is a byproduct of MOF-841 synthesis. All the new zirconium MOFs are made from the Zr6O4(OH)(4)(-CO2)(n) secondary building units (n = 6, 8, 10, or 12) and variously shaped carboxyl organic linkers to make extended porous frameworks. The permanent porosity of all 23 materials was confirmed and their water adsorption measured to reveal that MOF-801-P and MOF-841 are the highest performers based on the three criteria stated above; they are water stable, do not lose capacity after five adsorption/desorption cycles, and are easily regenerated at room temperature. An X-ray single-crystal study and a powder neutron diffraction study reveal the position of the water adsorption sites in MOF-801 and highlight the importance of the intermolecular interaction between adsorbed water molecules within the pores.« less

  19. Water adsorption in porous metal-organic frameworks and related materials.

    PubMed

    Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao; Jiang, Juncong; Queen, Wendy L; Hudson, Matthew R; Yaghi, Omar M

    2014-03-19

    Water adsorption in porous materials is important for many applications such as dehumidification, thermal batteries, and delivery of drinking water in remote areas. In this study, we have identified three criteria for achieving high performing porous materials for water adsorption. These criteria deal with condensation pressure of water in the pores, uptake capacity, and recyclability and water stability of the material. In search of an excellently performing porous material, we have studied and compared the water adsorption properties of 23 materials, 20 of which are metal-organic frameworks (MOFs). Among the MOFs are 10 zirconium(IV) MOFs with a subset of these, MOF-801-SC (single crystal form), -802, -805, -806, -808, -812, and -841 reported for the first time. MOF-801-P (microcrystalline powder form) was reported earlier and studied here for its water adsorption properties. MOF-812 was only made and structurally characterized but not examined for water adsorption because it is a byproduct of MOF-841 synthesis. All the new zirconium MOFs are made from the Zr6O4(OH)4(-CO2)n secondary building units (n = 6, 8, 10, or 12) and variously shaped carboxyl organic linkers to make extended porous frameworks. The permanent porosity of all 23 materials was confirmed and their water adsorption measured to reveal that MOF-801-P and MOF-841 are the highest performers based on the three criteria stated above; they are water stable, do not lose capacity after five adsorption/desorption cycles, and are easily regenerated at room temperature. An X-ray single-crystal study and a powder neutron diffraction study reveal the position of the water adsorption sites in MOF-801 and highlight the importance of the intermolecular interaction between adsorbed water molecules within the pores.

  20. Oxidation resistant porous material for transpiration cooled vanes

    NASA Technical Reports Server (NTRS)

    Madsen, P.; Rusnak, R. M.

    1972-01-01

    Porous metal sheet with controlled permeability was made by space winding and diffusion bonding fine wire. Two iron-chromium-aluminum alloys and three-chromium alloys were used: GE 1541 (Fe-Cr-Al-Y), H 875 (Fe-Cr-Al-Si), TD Ni Cr, DH 245 (Ni-Cr-Al-Si) and DH 242 (Ni-Cr-Si-Cb). GE 1541 and H 875 were shown in initial tests to have greater oxidation resistance than the other candidate alloys and were therefore tested more extensively. These two materials were cyclic furnace oxidation tested in air at 1800 and 2000 F for accumulated exposure times of 4, 16, 64, 100, 200, 300, 400, 500, and and 600 hours. Oxidation weight gain, permeability change and mechanical properties were determined after exposure. Metallographic examination was performed to determine effects of exposure on the porous metal and electron beam weld joints of porous sheet to IN 100 strut material. Hundred hour stress rupture life and tensile tests were performed at 1800 F. Both alloys had excellent oxidation resistance and retention of mechanical properties and appear suitable for use as transpiration cooling materials in high temperature gas turbine engines.

  1. Development and Applications of Porous Tantalum Trabecular Metal Enhanced Titanium Dental Implants

    PubMed Central

    Bencharit, Sompop; Byrd, Warren C.; Altarawneh, Sandra; Hosseini, Bashir; Leong, Austin; Reside, Glenn; Morelli, Thiago; Offenbacher, Steven

    2013-01-01

    Statement of Problem Porous tantalum trabecular metal has recently been incorporated in titanium dental implants as a new form of implant surface enhancement. However, there is little information on the applications of this material in implant dentistry. Methods We, therefore review the current literature on the basic science and clinical uses of this material. Results Porous tantalum metal is used to improve the contact between osseous structure and dental implants; and therefore presumably facilitate osseointegration. Success of porous tantalum metal in orthopedic implants led to the incorporation of porous tantalum metal in the design of root-from endosseous titanium implants. The porous tantalum three-dimensional enhancement of titanium dental implant surface allows for combining bone ongrowth together with bone ingrowth, or osseoincorporation. While little is known about the biological aspect of the porous tantalum in the oral cavity, there seems to be several possible advantages of this implant design. This article reviews the biological aspects of porous tantalum enhanced titanium dental implants, in particular the effects of anatomical consideration and oral environment to implant designs. Conclusions We propose here possible clinical situations and applications for this type of dental implant. Advantages and disadvantages of the implants as well as needed future clinical studies are discussed. PMID:23527899

  2. Sintered wire cathode

    DOEpatents

    Falce, Louis R [San Jose, CA; Ives, R Lawrence [Saratoga, CA

    2009-06-09

    A porous cathode structure is fabricated from a plurality of wires which are placed in proximity to each other in elevated temperature and pressure for a sintering time. The sintering process produces the porous cathode structure which may be divided into a plurality of individual porous cathodes, one of which may be placed into a dispenser cathode support which includes a cavity for containing a work function reduction material such as BaO, CaO, and Al.sub.2O.sub.3. The work function reduction material migrates through the pores of the porous cathode from a work replenishment surface adjacent to the cavity of the dispenser cathode support to an emitting cathode surface, thereby providing a dispenser cathode which has a uniform work function and therefore a uniform electron emission.

  3. Fate and Transport of Chemical Warfare Agents VX and HD ...

    EPA Pesticide Factsheets

    Report The intent of this investigation was to study the fate and transport of CWA applied to painted/sealed materials including the potential partitioning of CWA into permeable paints/sealants and subsequently into underlying porous materials. Based on the results obtained from this investigation, VX and sulfur mustard (HD) have the ability to permeate into paints and sealants, including in some cases the underlying porous materials. It is likely that other permeable materials besides paints and sealants may also show similar behavior.

  4. Porous Silicon—A Versatile Host Material

    PubMed Central

    Granitzer, Petra; Rumpf, Klemens

    2010-01-01

    This work reviews the use of porous silicon (PS) as a nanomaterial which is extensively investigated and utilized for various applications, e.g., in the fields of optics, sensor technology and biomedicine. Furthermore the combination of PS with one or more materials which are also nanostructured due to their deposition within the porous matrix is discussed. Such nanocompounds offer a broad avenue of new and interesting properties depending on the kind of involved materials as well as on their morphology. The filling of the pores performed by electroless or electrochemical deposition is described, whereas different morphologies, reaching from micro- to macro pores are utilized as host material which can be self-organized or fabricated by prestructuring. For metal-deposition within the porous structures, both ferromagnetic and non-magnetic metals are used. Emphasis will be put on self-arranged mesoporous silicon, offering a quasi-regular pore arrangement, employed as template for filling with ferromagnetic metals. By varying the deposition parameters the precipitation of the metal structures within the pores can be tuned in geometry and spatial distribution leading to samples with desired magnetic properties. The correlation between morphology and magnetic behaviour of such semiconducting/magnetic systems will be determined. Porous silicon and its combination with a variety of filling materials leads to nanocomposites with specific physical properties caused by the nanometric size and give rise to a multiplicity of potential applications in spintronics, magnetic and magneto-optic devices, nutritional food additives as well as drug delivery.

  5. Lightweight and efficient microwave absorbing materials based on walnut shell-derived nano-porous carbon.

    PubMed

    Qiu, Xu; Wang, Lixi; Zhu, Hongli; Guan, Yongkang; Zhang, Qitu

    2017-06-08

    Lightweight microwave absorbing materials have drawn tremendous attention. Herein, nano-porous biomass carbon materials have been prepared by carbonization with a subsequent potassium hydroxide activation of walnut shells and the microwave absorption properties have also been investigated. The obtained samples have large specific surface areas with numerous micropores and nanopores. The sample activated at 600 °C with a specific surface area of 736.2 m 2 g -1 exhibits the most enhanced microwave absorption performance. It has the maximum reflection loss of -42.4 dB at 8.88 GHz and the effective absorption bandwidth (reflection loss below -10 dB) is 1.76 GHz (from 8.08 GHz to 9.84 GHz), corresponding to a thickness of 2 mm. Additionally, the effective absorption bandwidth can reach 2.24 GHz (from 10.48 GHz to 12.72 GHz) when the absorber thickness is 1.5 mm. Three-dimensional porous architecture, interfacial polarization relaxation loss, and the dipolar relaxation loss make a great contribution to the excellent microwave absorption performance. In contrast, the non-activated sample with lower specific surface area (435.3 m 2 g -1 ) has poor microwave absorption performance due to a poor dielectric loss capacity. This comparison highlights the role of micropores and nanopores in improving the dielectric loss property of porous carbon materials. To sum up, porous biomass carbon has great potential to become lightweight microwave absorbers. Moreover, KOH is an efficient activation agent in the fabrication of carbonaceous materials.

  6. Nanostructured mesoporous materials for lithium-ion battery applications

    NASA Astrophysics Data System (ADS)

    Balaya, P.; Saravanan, K.; Hariharan, S.; Ramar, V.; Lee, H. S.; Kuezma, M.; Devaraj, S.; Nagaraju, D. H.; Ananthanarayanan, K.; Mason, C. W.

    2011-06-01

    The Energy crisis happens to be one of the greatest challenges we are facing today. In this view, much effort has been made in developing new, cost effective, environmentally friendly energy conversion and storage devices. The performance of such devices is fundamentally related to material properties. Hence, innovative materials engineering is important in solving the energy crisis problem. One such innovation in materials engineering is porous materials for energy storage. Porous electrode materials for lithium-ion batteries (LIBs) offer a high degree of electrolyte-electrode wettability, thus enhancing the electrochemical activity within the material. Among the porous materials, mesoporous materials draw special attention, owing to shorter diffusion lengths for Li+ and electronic movement. Nanostructured mesoporous materials also offer better packing density compared to their nanostructured counterparts such as nanopowders, nanowires, nanotubes etc., thus opening a window for developing electrode materials with high volumetric energy densities. This would directly translate into a scenario of building batteries which are much lighter than today's commercial LIBs. In this article, the authors present a simple, soft template approach for preparing both cathode and anode materials with high packing density for LIBs. The impact of porosity on the electrochemical storage performance is highlighted.

  7. Impact and Collisional Processes in the Solar System

    NASA Technical Reports Server (NTRS)

    Ahrens, Thomas J.

    2001-01-01

    In the past year, we have successfully developed the techniques necessary to conduct impact experiments on ice at very low temperatures. We employ the method of embedding gauges within a target to measure the shock wave and material properties. This means that our data are not model dependent; we directly measure the essential parameters needed for numerical simulations of impact cratering. Since then we have developed a new method for temperature control of icy targets that ensures temperature equilibrium throughout a porous target. Graduate student, Sarah Stewart-Mukhopadhyay, is leading the work on ices and porous materials as the main thrust of her thesis research. Our previous work has focused on icy materials with no porosity, and we propose to extend our research to include porous ice and porous ice-silicate mixtures. There is little shockwave data for porous ice, and none of the data was acquired under conditions applicable to the outer solar system. The solid ice Hugoniot is only defined for initial temperatures above -20 C. Our program uniquely measures the properties of ice at temperatures directly applicable to the solar system. Previous experiments were conducted at ambient temperatures soon after removing the target from a cold environment, usually just below freezing, or in a room just below freezing. Since ice has an extremely complicated phase diagram, it is important to conduct experiments at lower temperatures to determine the true outcome of impacts in the outer solar system. This research is complementary to other programs on icy materials. Our work focuses on the inherent material properties by measuring the shock wave directly; this complements the macroscopic observations and immediately provides the parameters necessary to extend this research to the gravity regime. Our numerical simulations of impacts in porous ice under very low gravity conditions, such as found on comets, show that the final crater size and shape is very dependent on the dynamic strength of the material.

  8. Statistical Inference for Porous Materials using Persistent Homology.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moon, Chul; Heath, Jason E.; Mitchell, Scott A.

    2017-12-01

    We propose a porous materials analysis pipeline using persistent homology. We rst compute persistent homology of binarized 3D images of sampled material subvolumes. For each image we compute sets of homology intervals, which are represented as summary graphics called persistence diagrams. We convert persistence diagrams into image vectors in order to analyze the similarity of the homology of the material images using the mature tools for image analysis. Each image is treated as a vector and we compute its principal components to extract features. We t a statistical model using the loadings of principal components to estimate material porosity, permeability,more » anisotropy, and tortuosity. We also propose an adaptive version of the structural similarity index (SSIM), a similarity metric for images, as a measure to determine the statistical representative elementary volumes (sREV) for persistence homology. Thus we provide a capability for making a statistical inference of the uid ow and transport properties of porous materials based on their geometry and connectivity.« less

  9. Measurements of the frame acoustic properties of porous and granular materials

    NASA Astrophysics Data System (ADS)

    Park, Junhong

    2005-12-01

    For porous and granular materials, the dynamic characteristics of the solid component (frame) are important design factors that significantly affect the material's acoustic properties. The primary goal of this study was to present an experimental method for measuring the vibration characteristics of this frame. The experimental setup was designed to induce controlled vibration of the solid component while minimizing the influence from coupling between vibrations of the fluid and the solid component. The Biot theory was used to verify this assumption, taking the two dilatational wave propagations and interactions into account. The experimental method was applied to measure the dynamic properties of glass spheres, lightweight microspheres, acoustic foams, and fiberglass. A continuous variation of the frame vibration characteristics with frequency similar to that of typical viscoelastic materials was measured. The vibration amplitude had minimal effects on the dynamic characteristics of the porous material compared to those of the granular material. For the granular material, materials comprised of larger particles and those under larger vibration amplitudes exhibited lower frame wave speeds and larger decay rates.

  10. Oxygen-rich hierarchical porous carbon made from pomelo peel fiber as electrode material for supercapacitor

    NASA Astrophysics Data System (ADS)

    Li, Jing; Liu, Wenlong; Xiao, Dan; Wang, Xinhui

    2017-09-01

    Oxygen-rich hierarchical porous carbon has been fabricated using pomelo peel fiber as a carbon source via an improved KOH activation method. The morphology and chemical composition of the obtained carbon materials were characterized by X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), electron microscopy (EM), Raman spectra and elemental analysis. The unique porous structure with abundant oxygen functional groups is favorable to capacitive behavior, and the as-prepared carbon material exhibits high specific capacitance of 222.6 F g-1 at 0.5 A g-1 in 6 M KOH and superior stability over 5000 cycles. This work not only describes a simple way to prepare high-performance carbon material from the discarded pomelo peel, but also provides a strategy for its disposal issue and contributes to the environmental improvement.

  11. Recent advances in porous nanoparticles for drug delivery in antitumoral applications: inorganic nanoparticles and nanoscale metal-organic frameworks.

    PubMed

    Baeza, Alejandro; Ruiz-Molina, Daniel; Vallet-Regí, María

    2017-06-01

    Nanotechnology has provided new tools for addressing unmet clinical situations, especially in the oncology field. The development of smart nanocarriers able to deliver chemotherapeutic agents specifically to the diseased cells and to release them in a controlled way has offered a paramount advantage over conventional therapy. Areas covered: Among the different types of nanoparticle that can be employed for this purpose, inorganic porous materials have received significant attention in the last decade due to their unique properties such as high loading capacity, chemical and physical robustness, low toxicity and easy and cheap production in the laboratory. This review discuss the recent advances performed in the application of porous inorganic and metal-organic materials for antitumoral therapy, paying special attention to the application of mesoporous silica, porous silicon and metal-organic nanoparticles. Expert opinion: The use of porous inorganic nanoparticles as drug carriers for cancer therapy has the potential to improve the life expectancy of the patients affected by this disease. However, much work is needed to overcome their drawbacks, which are aggravated by their hard nature, exploiting the advantages offered by highly the ordered pore network of these materials.

  12. One-step chemical vapor deposition synthesis and supercapacitor performance of nitrogen-doped porous carbon–carbon nanotube hybrids

    PubMed Central

    Bulusheva, Lyubov G; Fedorovskaya, Ekaterina O; Shubin, Yury V; Plyusnin, Pavel E; Lonchambon, Pierre; Senkovskiy, Boris V; Ismagilov, Zinfer R; Flahaut, Emmanuel; Okotrub, Alexander V

    2017-01-01

    Novel nitrogen-doped carbon hybrid materials consisting of multiwalled nanotubes and porous graphitic layers have been produced by chemical vapor deposition over magnesium-oxide-supported metal catalysts. CNx nanotubes were grown on Co/Mo, Ni/Mo, or Fe/Mo alloy nanoparticles, and MgO grains served as a template for the porous carbon. The simultaneous formation of morphologically different carbon structures was due to the slow activation of catalysts for the nanotube growth in a carbon-containing gas environment. An analysis of the obtained products by means of transmission electron microscopy, thermogravimetry and X-ray photoelectron spectroscopy methods revealed that the catalyst's composition influences the nanotube/porous carbon ratio and concentration of incorporated nitrogen. The hybrid materials were tested as electrodes in a 1M H2SO4 electrolyte and the best performance was found for a nitrogen-enriched material produced using the Fe/Mo catalyst. From the electrochemical impedance spectroscopy data, it was concluded that the nitrogen doping reduces the resistance at the carbon surface/electrolyte interface and the nanotubes permeating the porous carbon provide fast charge transport in the cell. PMID:29354339

  13. Burning to Detonation Transition in Porous Beds of a High Energy Propellant

    DTIC Science & Technology

    1979-11-01

    deflagration to detonation transition (DDT) behavior of porous charges of a high-energy propellant (VL-U) has been stualed at both high and low...transition (DDT) behavior of porous charges of a high-eneryy propellant (VLU) has been studied at both high confinement (steel tube) and low confinement...plastic tube). The physical nature of thet propellant ised to construct the porous beds was varied: shredded, powdered CI ,-: and cuboid materials were

  14. Unifying Pore Network Modeling, Continuous Time Random Walk Theory and Experiment - Accomplishments and Future Directions

    NASA Astrophysics Data System (ADS)

    Bijeljic, B.

    2008-05-01

    This talk will describe and highlight the advantages offered by a methodology that unifies pore network modeling, CTRW theory and experiment in description of solute dispersion in porous media. Solute transport in a porous medium is characterized by the interplay of advection and diffusion (described by Peclet number, Pe) that cause spreading of solute particles. This spreading is traditionally described by dispersion coefficients, D, defined by σ 2 = 2Dt, where σ 2 is the variance of the solute position and t is the time. Using a pore-scale network model based on particle tracking, the rich Peclet- number dependence of dispersion coefficient is predicted from first principles and is shown to compare well with experimental data for restricted diffusion, transition, power-law and mechanical dispersion regimes in the asymptotic limit. In the asymptotic limit D is constant and can be used in an averaged advection-dispersion equation. However, it is highly important to recognize that, until the velocity field is fully sampled, the particle transport is non-Gaussian and D possesses temporal or spatial variation. Furthermore, temporal probability density functions (PDF) of tracer particles are studied in pore networks and an excellent agreement for the spectrum of transition times for particles from pore to pore is obtained between network model results and CTRW theory. Based on the truncated power-law interpretation of PDF-s, the physical origin of the power-law scaling of dispersion coefficient vs. Peclet number has been explained for unconsolidated porous media, sands and a number of sandstones, arriving at the same conclusion from numerical network modelling, analytic CTRW theory and experiment. Future directions for further applications of the methodology presented are discussed in relation to the scale- dependent solute dispersion and reactive transport. Significance of pre-asymptotic dispersion in porous media is addressed from pore-scale upwards and the impact of heterogeneity is discussed. The length traveled by solute plumes before Gaussian behaviour is reached increases with an increase in heterogeneity and/or Pe. This opens up the question on the nature of dispersion in natural systems where the heterogeneities at the larger scales will profoundly increase the range of velocities in the aquifer, thus considerably delaying the asymptotic approach to Gaussian behaviour. As a consequence, the asymptotic behaviour might not be reached at the field scale.

  15. Measuring the DC electrokinetic coupling coefficient of porous rock samples in the laboratory : a new apparatus

    NASA Astrophysics Data System (ADS)

    Walker, E.; Tardif, E.; Glover, P. W.; Ruel, J.; Hadjigeorgiou, J.

    2009-12-01

    Electro-kinetic properties of rocks allow the generation of an electric potential by the flow of an aqueous fluid through a porous media. The electrical potential is called the streaming potential, and the streaming potential coupling coefficient Cs is the ratio of the generated electric potential to the pressure difference that causes the fluid flow. The streaming potential coupling coefficient for rocks is described in the steady-state regime by the well known Helmholtz-Smoluchowski equation, and is supported by a relatively small body of experimental data. However, the electrokinetic coupling coefficient measurement is important for the further development of different area of expertise such as reservoir prospection and monitoring, volcano and earthquake monitoring and the underground sequestration of CO2. We have designed, constructed and tested a new experimental cell that is capable of measuring the DC streaming potential of consolidated and unconsolidated porous media. The new cell is made from stainless steel, perspex and other engineering polymers. Cylindrical samples of 25.4 mm can be placed in a deformable rubber sleeve and subjected to a radial confining pressure of compressed nitrogen up to 4.5 MPa. Actively degassed aqueous fluids can be flowed by an Agilent 1200 series binary pump (2 to 10 mL/min). A maximum input fluid pressure of 2.5 MPa can be applied, with a maximum exit pressure of 1 MPa to ensure sample saturation is stable and to reduce gas bubbles. The pressures each side of the sample are measured by high stability pressure transducers (Omega PX302-300GV), previously calibrated by a high precision differential pressure transducer Endress and Hauser Deltabar S PMD75. The streaming potentials are measured with Harvard Apparatus LF-1 and LF-2 Ag/AgCl non-polarising miniature electrodes. An axial pressure is applied (1 to 6.5 MPa) to counteract the radial pressure and provide additional axial load with a hydraulic piston. It is our intention to complete the testing of the cell and to use it to measure the electrokinetic properties of porous rocks in the DC regime in order to provide sufficient data to improve the theories and models of DC streaming potentials.

  16. Measuring the DC electrokinetic coupling coefficient of porous rock samples in the laboratory : A new apparatus

    NASA Astrophysics Data System (ADS)

    Walker, Emilie; Tardif, Eric; Glover, Paul; Ruel, Jean; Lalande, Guillaume; Hadjigeorgiou, John

    2010-05-01

    Electro-kinetic properties of rocks allow the generation of an electric potential by the flow of an aqueous fluid through a porous media. The electrical potential is called the streaming potential, and the streaming potential coupling coefficient is the ratio of the generated electric potential to the pressure difference that causes the fluid flow. The streaming potential coupling coefficient for rocks is described in the steady-state regime by the well known Helmholtz-Smoluchowski equation, and is supported by a relatively small body of experimental data. However, the electrokinetic coupling coefficient measurement is important for the further development of different area of expertise such as reservoir prospection and monitoring, volcano and earthquake monitoring and the underground sequestration of carbon dioxide. We have designed, constructed and tested a new experimental cell that is capable of measuring the DC streaming potential of consolidated and unconsolidated porous media. The new cell is made from stainless steel, perspex and other engineering polymers. Cylindrical samples of 25.4 mm can be placed in a deformable rubber sleeve and subjected to a radial confining pressure of compressed nitrogen up to 4.5 MPa. Actively degassed aqueous fluids can be flowed by an Agilent 1200 series binary pump (2 to 10 mL/min). A maximum input fluid pressure of 2.5 MPa can be applied, with a maximum exit pressure of 1 MPa to ensure sample saturation is stable and to reduce gas bubbles. The pressures each side of the sample are measured by high stability pressure transducers (Omega PX302-300GV), previously calibrated by a high precision differential pressure transducer Endress and Hauser Deltabar S PMD75. The streaming potentials are measured with Harvard Apparatus LF-1 and LF-2 Ag/AgCl non-polarising miniature electrodes. An axial pressure is applied (1 to 6.5 MPa) to counteract the radial pressure and provide additional axial load with a hydraulic piston. It is our intention to complete the testing of the cell and to use it to measure the electrokinetic properties of porous rocks in the DC regime in order to provide sufficient data to improve the theories and models of DC streaming potentials.

  17. Application of drilling, coring, and sampling techniques to test holes and wells

    USGS Publications Warehouse

    Shuter, Eugene; Teasdale, Warren E.

    1989-01-01

    The purpose of this manual is to provide ground-water hydrologists with a working knowledge of the techniques of test drilling, auger drilling, coring and sampling, and the related drilling and sampling equipment. For the most part, the techniques discussed deal with drilling, sampling, and completion of test holes in unconsolidated sediments because a hydrologist is interested primarily in shallow-aquifer data in this type of lithology. Successful drilling and coring of these materials usually is difficult, and published research information on the subject is not readily available. The authors emphasize in-situ sampling of unconsolidated sediments to obtain virtually undisturbed samples. Particular attention is given to auger drilling and hydraulic-rotary methods of drilling because these are the principal means of test drilling performed by the U.S. Geological Survey during hydrologic studies. Techniques for sampling areas contaminated by solid or liquid waste are discussed. Basic concepts of well development and a detailed discussion of drilling muds, as related to hole conditioning, also are included in the report. The information contained in this manual is intended to help ground-water hydrologists obtain useful subsurface data and samples from their drilling programs.

  18. Porous Ni-Co-Mn oxides prisms for high performance electrochemical energy storage

    NASA Astrophysics Data System (ADS)

    Zhao, Jianbo; Li, Man; Li, Junru; Wei, Chengzhen; He, Yuyue; Huang, Yixuan; Li, Qiaoling

    2017-12-01

    Porous Ni-Co-Mn oxides prisms have been successfully synthesized via a facile route. The process involves the preparation of nickel-cobalt-manganese acetate hydroxide by a simple co-precipitation method and subsequently the thermal treatment. The as-synthesized Ni-Co-Mn oxides prisms had a large surface area (96.53 m2 g-1) and porous structure. As electrode materials for supercapacitors, porous Ni-Co-Mn oxides prisms showed a high specific capacitance of 1623.5 F g-1 at 1.0 A g-1. Moreover, the porous Ni-Co-Mn oxides prisms were also employed as positive electrode materials to assemble flexible solid-state asymmetric supercapacitors. The resulting flexible device had a maximum volumetric energy density (0.885 mW h cm-3) and power density (48.9 mW cm-3). Encouragingly, the flexible device exhibited good cycling stability with only about 2.2% loss after 5000 charge-discharge cycles and excellent mechanical stability. These results indicate that porous Ni-Co-Mn oxides prisms have the promising application in high performance electrochemical energy storage.

  19. Inward Lithium-Ion Breathing of Hierarchically Porous Silicon Anodes

    DOE PAGES

    Xiao, Qiangfeng; Gu, Meng; Yang, Hui; ...

    2015-11-05

    Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-levelmore » outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. We find the low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.« less

  20. Digital material laboratory: Considerations on high-porous volcanic rock

    NASA Astrophysics Data System (ADS)

    Saenger, Erik H.; Stöckhert, Ferdinand; Duda, Mandy; Fischer, Laura; Osorno, Maria; Steeb, Holger

    2017-04-01

    Digital material methodology combines modern microscopic imaging with advanced numerical simulations of the physical properties of materials. One goal is to complement physical laboratory investigations for a deeper understanding of relevant physical processes. Large-scale numerical modeling of elastic wave propagation directly from the microstructure of the porous material is integral to this technology. The parallelized finite-difference-based Stokes solver is suitable for the calculation of effective hydraulic parameters for low and high porous materials. Reticulite is formed in very high Hawaiian fire fountaining events. Hawaiian fire fountaining eruptions produce columns or fountains of lava, which can last for a few hours to days. Reticulite was originally thought to have formed from further expanded hot scoria foam. However, some researchers believe reticulite forms from magma that formed vesicles instantly, which expanded rapidly and uniformly to produce the polyhedral vesicle walls. These walls then ruptured and cooled rapidly. The (open) honeycomb network of bubbles is held together by glassy threads and forms a structure with a porosity higher than 80%. The fragile rock sample is difficult to characterize with classical experimental methods and we show how to determine porosity, effective elastic properties and Darcy permeability by using digital material methodology. A technical challenge will be to image with the CT technique the thin skin between the glassy threads visible on the microscopy image. A numerical challenge will be determination of effective material properties and viscous fluid effects on wave propagation in such a high porous material.

  1. Simulations of defense strategies for Bennu: Material characterization and impulse delivery

    DOE PAGES

    Herbold, E. B.; Owen, J. M.; Swift, D. C.; ...

    2015-05-19

    Assessments of asteroid deflection strategies depend on material characterization to reduce the uncertainty in predictions of the deflection velocity resulting from impulsive loading. In addition to strength, equation of state, the initial state of the material including its competency (i.e. fractured or monolithic) and the amount of micro- or macroscopic porosity are important considerations to predict the thermomechanical response. There is recent interest in observing near-Earth asteroid (101955) Bennu due to its classification of being potentially hazardous with close approaches occurring every 6 years. Bennu is relatively large with a nominal diameter of 492 m, density estimates ranging from 0.9-1.26more » g/cm³ and is composed mainly of carbonaceous chondrite. There is a lack of data for highly porous carbonaceous chondrite at very large pressures and temperatures. In the absence of the specific material composition and state (e.g. layering, porosity as a function of depth) on Bennu we introduce a continuum constitutive model based on the response of granular materials and provide impact and standoff explosion simulations to investigate the response of highly porous materials to these types of impulsive loading scenarios. Simulations with impact speeds of 5 km/s show that the shock wave emanating from the impact site is highly dispersive and that a 10% porous material has a larger compacted volume compared with a 40% porous material with the same bulk density due to differences in compaction response.« less

  2. Porous-Nickel-Scaffolded Tin-Antimony Anodes with Enhanced Electrochemical Properties for Li/Na-Ion Batteries.

    PubMed

    Li, Jiachen; Pu, Jun; Liu, Ziqiang; Wang, Jian; Wu, Wenlu; Zhang, Huigang; Ma, Haixia

    2017-08-02

    The energy and power densities of rechargeable batteries urgently need to be increased to meet the ever-increasing demands of consumer electronics and electric vehicles. Alloy anodes are among the most promising candidates for next-generation high-capacity battery materials. However, the high capacities of alloy anodes usually suffer from some serious difficulties related to the volume changes of active materials. Porous supports and nanostructured alloy materials have been explored to address these issues. However, these approaches seemingly increase the active material-based properties and actually decrease the electrode-based capacity because of the oversized pores and heavy mass of mechanical supports. In this study, we developed an ultralight porous nickel to scaffold with high-capacity SnSb alloy anodes. The porous-nickel-supported SnSb alloy demonstrates a high specific capacity and good cyclability for both Li-ion and Na-ion batteries. Its capacity retains 580 mA h g -1 at 2 A g -1 after 100 cycles in Li-ion batteries. For a Na-ion battery, the composite electrode can even deliver a capacity of 275 mA h g -1 at 1 A g -1 after 1000 cycles. This study demonstrates that combining the scaffolding function of ultralight porous nickel and the high capacity of the SnSb alloy can significantly enhance the electrochemical performances of Li/Na-ion batteries.

  3. Shear wave velocities of unconsolidated shallow sediments in the Gulf of Mexico

    USGS Publications Warehouse

    Lee, Myung W.

    2013-01-01

    Accurate shear-wave velocities for shallow sediments are important for a variety of seismic applications such as inver-sion and amplitude versus offset analysis. During the U.S. Department of Energy-sponsored Gas Hydrate Joint Industry Project Leg II, shear-wave velocities were measured at six wells in the Gulf of Mexico using the logging-while-drilling SonicScope acoustic tool. Because the tool measurement point was only 35 feet from the drill bit, the adverse effect of the borehole condition, which is severe for the shallow unconsolidated sediments in the Gulf of Mexico, was mini-mized and accurate shear-wave velocities of unconsolidated sediments were measured. Measured shear-wave velocities were compared with the shear-wave velocities predicted from the compressional-wave velocities using empirical formulas and the rock physics models based on the Biot-Gassmann theory, and the effectiveness of the two prediction methods was evaluated. Although the empirical equation derived from measured shear-wave data is accurate for predicting shear-wave velocities for depths greater than 500 feet in these wells, the three-phase Biot-Gassmann-theory -based theory appears to be optimum for predicting shear-wave velocities for shallow unconsolidated sediments in the Gulf of Mexico.

  4. Porous Metal Carboxylate Boron Imidazolate Frameworks (MC-BIFs)

    PubMed Central

    Zheng, Shoutian; Wu, Tao; Zhang, Jian; Chow, Mina; Nieto, Ruben A.

    2011-01-01

    Integrated Material for Efficient CO2 Storage A new family of porous materials with tunable gas sorption properties have been made by integrating metal carboxylates and boron imidazolates under hydro- or solvothermal conditions. One hydrothermally synthesized phase exhibits a very high volumetric CO2 storage capacity at 81 L/L (273K, 1atm). PMID:20583020

  5. Generalization of experimental data on heat transfer in permeable shells made of porous reticular materials

    NASA Astrophysics Data System (ADS)

    Polyakov, A. F.; Strat'ev, V. K.; Tret'yakov, A. F.; Shekhter, Yu. L.

    2010-06-01

    Heat transfer from six samples of porous reticular material to cooling gas (air) at small Reynolds numbers is experimentally studied. The specific features pertinent to heat transfer essentially affected by longitudinal heat conductivity along gas flow are analyzed. The experimental results are generalized in the form of dimensionless empirical relations.

  6. Sidewall tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOEpatents

    Hubbell, Joel M.; Sisson, James B.

    2001-01-01

    A sidewall tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body adapted for insertion into an opening in earthen soil below grade, the body having lateral sidewalls; b) a laterally oriented porous material provided relative to the body lateral sidewalls, the laterally oriented porous material at least in part defining a fluid chamber within the body; c) a pressure a sensor in fluid communication with the fluid chamber; and d) sidewall engaging means for engaging a portion of a sidewall of an earth opening to laterally urge the porous material into hydraulic communication with earthen soil of another portion of the opening sidewall. Methods of taking tensiometric measurements are also disclosed.

  7. Ballistic Performance of Porous Ceramic Thermal Protection Systems at 9 km/s

    NASA Technical Reports Server (NTRS)

    Miller, Joshua E.; Bohl, W. E.; Foreman, C. D.; Christiansen, Eric L.; Davis, B. A.

    2009-01-01

    Porous-ceramic, thermal-protection-systems are used heavily in current reentry vehicles like the Orbiter, and they are currently being proposed for the next generation of manned spacecraft, Orion. These materials insulate the structural components and sensitive electronic components of a spacecraft against the intense thermal environments of atmospheric reentry. Furthermore, these materials are also highly exposed to space environmental hazards like meteoroid and orbital debris impacts. This paper discusses recent impact testing up to 9 km/s on ceramic tiles similar to those used on the Orbiter. These tiles have a porous-batting of nominally 8 lb/cubic ft alumina-fiber-enhanced-thermal-barrier (AETB8) insulating material coated with a damage-resistant, toughened-unipiece-fibrous-insulation (TUFI) layer.

  8. Normal shock wave reflection on porous compressible material

    NASA Astrophysics Data System (ADS)

    Gvozdeva, L. G.; Faresov, Iu. M.; Brossard, J.; Charpentier, N.

    The present experimental investigation of the interaction of plane shock waves in air and a rigid wall coated with flat layers of expanded polymers was conducted in a standard shock tube and a diaphragm with an initial test section pressure of 100,000 Pa. The Mach number of the incident shock wave was varied from 1.1 to 2.7; the peak pressures measured on the wall behind polyurethane at various incident wave Mach numbers are compared with calculated values, with the ideal model of propagation, and with the reflection of shock waves in a porous material that is understood as a homogeneous mixture. The effect of elasticity and permeability of the porous material structure on the rigid wall's pressure pulse parameters is qualitatively studied.

  9. 3D printing process of oxidized nanocellulose and gelatin scaffold.

    PubMed

    Xu, Xiaodong; Zhou, Jiping; Jiang, Yani; Zhang, Qi; Shi, Hongcan; Liu, Dongfang

    2018-08-01

    For tissue engineering applications tissue scaffolds need to have a porous structure to meet the needs of cell proliferation/differentiation, vascularisation and sufficient mechanical strength for the specific tissue. Here we report the results of a study of the 3D printing process for composite materials based on oxidized nanocellulose and gelatin, that was optimised through measuring rheological properties of different batches of materials after different crosslinking times, simulation of the pneumatic extrusion process and 3D scaffolds fabrication with Solidworks Flow Simulation, observation of its porous structure by SEM, measurement of pressure-pull performance, and experiments aimed at finding out the vitro cytotoxicity and cell morphology. The materials printed are highly porous scaffolds with good mechanical properties.

  10. A porous carbon material from pyrolysis of fructus cannabis’s shells for supercapacitor electrode application

    NASA Astrophysics Data System (ADS)

    Li, Kai; Zhang, Wei-Bin; Zhao, Zhi-Yun; Zhao, Yue; Chen, Xi-Wen; Kong, Ling-Bin

    2018-02-01

    The porous carbon material is obtained via pyrolysis and activation of fructus cannabis’s shells, an easy-to-get biomass source, and is used as an active electrode material for supercapacitors. The obtained carbon exhibit a high specific surface area of 2389 m2 g-1. And the result of x-ray photoelectron spectroscopy (XPS) shows that the obtained porous carbon possess numerous oxygen groups, which can facilitate the wettability of the electrode. The prepared porous carbon also exhibit remarkable electrochemical properties, such as high specific capacitance of 357 F g-1 at a current density of 0.5 A g-1 in 6 mol L-1 aqueous KOH electrolyte, good rate capability of 77% capacitance retention as the current density increase from 0.5 A g-1 to 10 A g-1. In addition, it also presents a superior cycling stability of 100% capacitance retention after 10 000 cycles at the current density of 1 A g-1.

  11. 3D porous polyurethanes featured by different mechanical properties: Characterization and interaction with skeletal muscle cells.

    PubMed

    Vannozzi, Lorenzo; Ricotti, Leonardo; Santaniello, Tommaso; Terencio, Tercio; Oropesa-Nunez, Reinier; Canale, Claudio; Borghi, Francesca; Menciassi, Arianna; Lenardi, Cristina; Gerges, Irini

    2017-11-01

    The fabrication of biomaterials for interaction with muscle cells has attracted significant interest in the last decades. However, 3D porous scaffolds featured by a relatively low stiffness (almost matching the natural muscle one) and highly stable in response to cyclic loadings are not available at present, in this context. This work describes 3D polyurethane-based porous scaffolds featured by different mechanical properties. Biomaterial stiffness was finely tuned by varying the cross-linking degree of the starting foam. Compression tests revealed, for the softest material formulation, stiffness values close to the ones possessed by natural skeletal muscles. The materials were also characterized in terms of local nanoindenting, rheometric properties and long-term stability through cyclic compressions, in a strain range reflecting the contraction extent of natural muscles. Preliminary in vitro tests revealed a preferential adhesion of C2C12 skeletal muscle cells over the softer, rougher and more porous structures. All the material formulations showed low cytotoxicity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Europium (III) Organic Complexes in Porous Boron Nitride Microfibers: Efficient Hybrid Luminescent Material

    NASA Astrophysics Data System (ADS)

    Lin, Jing; Feng, Congcong; He, Xin; Wang, Weijia; Fang, Yi; Liu, Zhenya; Li, Jie; Tang, Chengchun; Huang, Yang

    2016-09-01

    We report the design and synthesis of a novel kind of organic-inorganic hybrid material via the incorporation of europium (III) β-diketonate complexes (Eu(TTA)3, TTA = 2-thenoyltrifluoroacetone) into one-dimensional (1D) porous boron nitride (BN) microfibers. The developed Eu(TTA)3@BN hybrid composites with typical 1D fibrous morphology exhibit bright visible red-light emission on UV illumination. The confinement of Eu(TTA)3 within pores of BN microfibers not only decreases the aggregation-caused quenching in solid Eu(TTA)3, but also improves their thermal stabilities. Moreover, The strong interactions between Eu(TTA)3 and porous BN matrix result in an interesting energy transfer process from BN host to TTA ligand and TTA ligand to Eu3+ ions, leading to the remarkable increase of red emission. The synthetic approach should be a very promising strategy which can be easily expanded to other hybrid luminescent materials based on porous BN.

  13. Europium (III) Organic Complexes in Porous Boron Nitride Microfibers: Efficient Hybrid Luminescent Material

    PubMed Central

    Lin, Jing; Feng, Congcong; He, Xin; Wang, Weijia; Fang, Yi; Liu, Zhenya; Li, Jie; Tang, Chengchun; Huang, Yang

    2016-01-01

    We report the design and synthesis of a novel kind of organic-inorganic hybrid material via the incorporation of europium (III) β-diketonate complexes (Eu(TTA)3, TTA = 2-thenoyltrifluoroacetone) into one-dimensional (1D) porous boron nitride (BN) microfibers. The developed Eu(TTA)3@BN hybrid composites with typical 1D fibrous morphology exhibit bright visible red-light emission on UV illumination. The confinement of Eu(TTA)3 within pores of BN microfibers not only decreases the aggregation-caused quenching in solid Eu(TTA)3, but also improves their thermal stabilities. Moreover, The strong interactions between Eu(TTA)3 and porous BN matrix result in an interesting energy transfer process from BN host to TTA ligand and TTA ligand to Eu3+ ions, leading to the remarkable increase of red emission. The synthetic approach should be a very promising strategy which can be easily expanded to other hybrid luminescent materials based on porous BN. PMID:27687246

  14. Application research on the sensitivity of porous silicon

    NASA Astrophysics Data System (ADS)

    Xu, Gaobin; Xi, Ye; Chen, Xing; Ma, Yuanming

    2017-09-01

    Applications based on sensitive property of porous silicon (PSi) were researched. As a kind of porous material, the feasibility of PSi as a getter material was studied. Five groups of samples with different parameters were prepared. The gas-sensing property of PSi was studied by the test system and suitable parameters of PSi were also discussed. Meanwhile a novel structure of humidity sensor, using porous silicon as humidity-sensitive material, based on MEMS process has been successfully designed. The humidity-sensing properties were studied by a test system. Because of the polysilicon layer deposited upon the PSi layer, the humidity sensor can realize a quick dehumidification by itself. To extend service life and reduce the effect of the environment, a passivation layer (Si3N4) was also deposited on the surface of electrodes. The result indicated the novel humidity sensor presented high sensitivity (1.1 pF/RH%), low hysteresis, low temperature coefficient (0.5%RH/°C) and high stability.

  15. In vivo outcomes of tissue-engineered osteochondral grafts.

    PubMed

    Bal, B Sonny; Rahaman, Mohamed N; Jayabalan, Prakash; Kuroki, Keiichi; Cockrell, Mary K; Yao, Jian Q; Cook, James L

    2010-04-01

    Tissue-engineered osteochondral grafts have been synthesized from a variety of materials, with some success at repairing chondral defects in animal models. We hypothesized that in tissue-engineered osteochondral grafts synthesized by bonding mesenchymal stem cell-loaded hydrogels to a porous material, the choice of the porous scaffold would affect graft healing to host bone, and the quality of cell restoration at the hyaline cartilage surface. Bone marrow-derived allogeneic mesenchymal stem cells were suspended in hydrogels that were attached to cylinders of porous tantalum metal, allograft bone, or a bioactive glass. The tissue-engineered osteochondral grafts, thus created were implanted into experimental defects in rabbit knees. Subchondral bone restoration, defect fill, bone ingrowth-implant integration, and articular tissue quality were compared between the three subchondral materials at 6 and 12 weeks. Bioactive glass and porous tantalum were superior to bone allograft in integrating to adjacent host bone, regenerating hyaline-like tissue at the graft surface, and expressing type II collagen in the articular cartilage.

  16. Simulation of a supersonic flow around a body with a frontal gas-permeable insert by using a skeleton model of a highly porous cellular material

    NASA Astrophysics Data System (ADS)

    Poplavskaya, T. V.; Kirilovskiy, S. V.; Mironov, S. G.

    2017-10-01

    Numerical simulation of supersonic flow past a cylinder with a frontal gas-permeable insert is performed using the skeleton model of a highly porous cellular material. Numerical simulation was carried out within the framework of two-dimensional RANS equations written in an axisymmetric form. The skeleton model is a system of coaxial rings of different diameters, arranged in staggered order. The calculations were carried out in a wide range of determining parameters: Mach numbers M∞ = 3, 4.85 and 7, unit Reynolds numbers Re1∞ = 13.8×105 ÷ 13.8×106 m-1, the cylinder diameter 6÷40mm, the length of the porous insert 3÷45mm, the cell diameter of 1 and 3 mm. The results of the calculations are consistent with the available experimental data. The applicability of the skeleton model for the description of supersonic flow around axisymmetric bodies with front inserts from cellular-porous materials is shown.

  17. Graded porous polyurethane foam: a potential scaffold for oro-maxillary bone regeneration.

    PubMed

    Giannitelli, S M; Basoli, F; Mozetic, P; Piva, P; Bartuli, F N; Luciani, F; Arcuri, C; Trombetta, M; Rainer, A; Licoccia, S

    2015-06-01

    Bone tissue engineering applications demand for biomaterials offering a substrate for cell adhesion, migration, and proliferation, while inferring suitable mechanical properties to the construct. In the present study, polyurethane (PU) foams were synthesized to develop a graded porous material-characterized by a dense shell and a porous core-for the treatment of oro-maxillary bone defects. Foam was synthesized via a one-pot reaction starting from a polyisocyanate and a biocompatible polyester diol, using water as a foaming agent. Different foaming conditions were examined, with the aim of creating a dense/porous functional graded material that would perform at the same time as an osteoconductive scaffold for bone defect regeneration and as a membrane-barrier to gingival tissue ingrowth. The obtained PU was characterized in terms of morphological and mechanical properties. Biocompatibility assessment was performed in combination with bone-marrow-derived human mesenchymal stromal cells (hBMSCs). Our findings confirm that the material is potentially suitable for guided bone regeneration applications. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Mechanical properties of porous and cellular materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sieradzki, K.; Green, D.J.; Gibson, L.J.

    1991-01-01

    This symposium successfully brought scientists together from a wide variety of disciplines to focus on the mechanical behavior of porous and cellular solids composed of metals, ceramics, polymers, or biological materials. For cellular materials, papers ranged from processing techniques through microstructure-mechanical property relationships to design. In an overview talk, Mike Ashby (Cambridge Univ.) showed how porous cellular materials can be more efficient than dense materials in designs that require minimum weight. He indicated that many biological materials have been able to accomplish such efficiency but there exists an opportunity to design even more efficient, manmade materials controlling microstructures at differentmore » scale levels. In the area of processing, James Aubert (Sandia National Laboratories) discussed techiques for manipulating polymersolvent phase equilibria to control the microstructure of microcellular foams. Other papers on processing discussed the production of cellular ceramics by CVD, HIPing and sol- gel techniques. Papers on the mechanical behavior of cellular materials considered various ceramics microcellular polymers, conventional polymer foams and apples. There were also contributions that considered optimum design procedures for cellular materials. Steven Cowin (City Univ. of New York) discussed procedures to match the discrete microstructural aspects of cellular materials with the continuum mechanics approach to their elastic behavior.« less

  19. Method for producing flame retardant porous products and products produced thereby

    DOEpatents

    Salyer, Ival O.

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame.

  20. Method for producing flame retardant porous products and products produced thereby

    DOEpatents

    Salyer, I.O.

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame. 1 fig.

  1. Method for Producing Flame Retardant Porous Products and Products Produced Thereby

    DOEpatents

    Salyer, Ival O.

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame.

  2. Porous carbon derived from Sunflower as a host matrix for ultra-stable lithium-selenium battery.

    PubMed

    Jia, Min; Niu, Yubin; Mao, Cuiping; Liu, Sangui; Zhang, Yan; Bao, Shu-Juan; Xu, Maowen

    2017-03-15

    A novel porous carbon material using the spongy tissue of sunflower as raw material is reported for the first time. The obtained porous carbon has an extremely high surface area of 2493.0m 2 g -1 , which is beneficial to focus on encapsulating selenium in it and have an inhibiting effect about diffusion of polyselenides over the charge/discharge processes used as the host matrix for Li-Se battery. The porous carbon/Se composite electrode with 63wt% selenium delivers a high specific capacitance of 319mAhg -1 of the initial capacity, and maintains 290mAhg -1 , representing an extremely high capacity retention of 90.9% after 840 cycles with the rate of 1C. Copyright © 2016. Published by Elsevier Inc.

  3. New porous titanium–niobium oxide for photocatalytic degradation of bromocresol green dye in aqueous solution

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chaleshtori, Maryam Zarei, E-mail: mzarei@utep.edu; Hosseini, Mahsa; Edalatpour, Roya

    2013-10-15

    Graphical abstract: The photocatalytic activity of different porous titanium–niobium oxides was evaluated toward degradation of bromocresol green (BG) under UV light. A better catalytic activity was observed for all samples at lower pH. Catalysts have a stronger ability for degradation of BG in acid media than in alkaline media. - Highlights: • Different highly structured titanium–niobium oxides have been prepared using improved methods of synthesis. • Photo-degradation of bromocresol green dye (BG) with nanostructure titanium–niobium oxide catalysts was carried out under UV light. • The photo-catalytic activity of all catalysts was higher in lower pH. • Titanium–niobium oxide catalysts aremore » considerably stable and reusable. - Abstract: In this study, high surface area semiconductors, non porous and porous titanium–niobium oxides derived from KTiNbO{sub 5} were synthesized, characterized and developed for their utility as photocatalysts for decontamination with sunlight. These materials were then used in the photocatalytic degradation of bromocresol green dye (BG) in aqueous solution using UV light and their catalytic activities were evaluated at various pHs. For all catalysts, the photocatalytic degradation of BG was most efficient in acidic solutions. Results show that the new porous oxides have large porous and high surface areas and high catalytic activity. A topotactic dehydration treatment greatly improves catalyst performance at various pHs. Stability and long term activity of porous materials (topo and non-topo) in photocatalysis reactions was also tested. These results suggest that the new materials can be used to efficiently purify contaminated water.« less

  4. Nanostructured carbon materials for adsorption of methane and other gases

    DOEpatents

    Stadie, Nicholas P.; Fultz, Brent T.; Ahn, Channing; Murialdo, Maxwell

    2015-06-30

    Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.

  5. Tortuosity Computations of Porous Materials using the Direct Simulation Monte Carlo

    NASA Technical Reports Server (NTRS)

    Borner, A.; Ferguson, C.; Panerai, F.; Mansour, Nagi N.

    2017-01-01

    Low-density carbon fiber preforms, used as thermal protection systems (TPS) materials for planetary entry systems, have permeable, highly porous microstructures consisting of interlaced fibers. Internal gas transport in TPS is important in modeling the penetration of hot boundary-layer gases and the in-depth transport of pyrolysis and ablation products. The gas effective diffusion coefficient of a porous material must be known before the gas transport can be modeled in material response solvers; however, there are very little available data for rigid fibrous insulators used in heritage TPS.The tortuosity factor, which reflects the efficiency of the percolation paths, can be computed from the effective diffusion coefficient of a gas inside a porous material and is based on the micro-structure of the material. It is well known, that the tortuosity factor is a strong function of the Knudsen number. Due to the small characteristic scales of porous media used in TPS applications (typical pore size of the order of 50 micron), the transport of gases can occur in the rarefied and transitional regimes, at Knudsen numbers above 1. A proper way to model the gas dynamics at these conditions consists in solving the Boltzmann equation using particle-based methods that account for movement and collisions of atoms and molecules.In this work we adopt, for the first time, the Direct Simulation Monte Carlo (DSMC) method to compute the tortuosity factor of fibrous media in the rarefied regime. To enable realistic simulations of the actual transport of gases in the porous medium, digitized computational grids are obtained from X-ray micro-tomography imaging of real TPS materials. The SPARTA DSMC solver is used for simulations. Effective diffusion coefficients and tortuosity factors are obtained by computing the mean-square displacement of diffusing particles.We first apply the method to compute the tortuosity factors as a function of the Knudsen number for computationally designed materials such as random cylindrical fibers and packed bed of spheres with prescribed porosity. Results are compared to literature values obtained using random walk methods in the rarefied and transitional regime and a finite-volume method for the continuum regime. We then compute tortuosity factors for a real carbon fiber material with a transverse isotropic structure (FiberForm), quantifying differences between through-thickness and in-plain tortuosities at various Knudsen regimes.

  6. Optimal design of porous structures for the fastest liquid absorption.

    PubMed

    Shou, Dahua; Ye, Lin; Fan, Jintu; Fu, Kunkun

    2014-01-14

    Porous materials engineered for rapid liquid absorption are useful in many applications, including oil recovery, spacecraft life-support systems, moisture management fabrics, medical wound dressings, and microfluidic devices. Dynamic absorption in capillary tubes and porous media is driven by the capillary pressure, which is inversely proportional to the pore size. On the other hand, the permeability of porous materials scales with the square of the pore size. The dynamic competition between these two superimposed mechanisms for liquid absorption through a heterogeneous porous structure may lead to an overall minimum absorption time. In this work, we explore liquid absorption in two different heterogeneous porous structures [three-dimensional (3D) circular tubes and porous layers], which are composed of two sections with variations in radius/porosity and height. The absorption time to fill the voids of porous constructs is expressed as a function of radius/porosity and height of local sections, and the absorption process does not follow the classic Washburn's law. Under given height and void volume, these two-section structures with a negative gradient of radius/porosity against the absorption direction are shown to have faster absorption rates than control samples with uniform radius/porosity. In particular, optimal structural parameters, including radius/porosity and height, are found that account for the minimum absorption time. The liquid absorption in the optimized porous structure is up to 38% faster than in a control sample. The results obtained can be used a priori for the design of porous structures with excellent liquid management property in various fields.

  7. Impact of physical properties on ozone removal by several porous materials.

    PubMed

    Gall, Elliott T; Corsi, Richard L; Siegel, Jeffrey A

    2014-04-01

    Models of reactive uptake of ozone in indoor environments generally describe materials through aerial (horizontal) projections of surface area, a potentially limiting assumption for porous materials. We investigated the effect of changing porosity/pore size, material thickness, and chamber fluid mechanic conditions on the reactive uptake of ozone to five materials: two cellulose filter papers, two cementitious materials, and an activated carbon cloth. Results include (1) material porosity and pore size distributions, (2) effective diffusion coefficients for ozone in materials, and (3) material-ozone deposition velocities and reaction probabilities. At small length scales (0.02-0.16 cm) increasing thickness caused increases in estimated reaction probabilities from 1 × 10(-6) to 5 × 10(-6) for one type of filter paper and from 1 × 10(-6) to 1 × 10(-5) for a second type of filter paper, an effect not observed for materials tested at larger thicknesses. For high porosity materials, increasing chamber transport-limited deposition velocities resulted in increases in reaction probabilities by factors of 1.4-2.0. The impact of physical properties and transport effects on values of the Thiele modulus, ranging across all materials from 0.03 to 13, is discussed in terms of the challenges in estimating reaction probabilities to porous materials in scenarios relevant to indoor environments.

  8. A diffusivity model for predicting VOC diffusion in porous building materials based on fractal theory.

    PubMed

    Liu, Yanfeng; Zhou, Xiaojun; Wang, Dengjia; Song, Cong; Liu, Jiaping

    2015-12-15

    Most building materials are porous media, and the internal diffusion coefficients of such materials have an important influences on the emission characteristics of volatile organic compounds (VOCs). The pore structure of porous building materials has a significant impact on the diffusion coefficient. However, the complex structural characteristics bring great difficulties to the model development. The existing prediction models of the diffusion coefficient are flawed and need to be improved. Using scanning electron microscope (SEM) observations and mercury intrusion porosimetry (MIP) tests of typical porous building materials, this study developed a new diffusivity model: the multistage series-connection fractal capillary-bundle (MSFC) model. The model considers the variable-diameter capillaries formed by macropores connected in series as the main mass transfer paths, and the diameter distribution of the capillary bundles obeys a fractal power law in the cross section. In addition, the tortuosity of the macrocapillary segments with different diameters is obtained by the fractal theory. Mesopores serve as the connections between the macrocapillary segments rather than as the main mass transfer paths. The theoretical results obtained using the MSFC model yielded a highly accurate prediction of the diffusion coefficients and were in a good agreement with the VOC concentration measurements in the environmental test chamber. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Potential of hybrid functionalized meso-porous materials for the separation and immobilization of radionuclides

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Luca, V.

    2013-07-01

    Functionalized meso-porous materials are a class of hybrid organic-inorganic material in which a meso-porous metal oxide framework is functionalized with multifunctional organic molecules. These molecules may contain one or more anchor groups that form strong bonds to the pore surfaces of the metal oxide framework and free functional groups that can impart and or modify the functionality of the material such as for binding metal ions in solution. Such materials have been extensively studied over the past decade and are of particular interest in absorption applications because of the tremendous versatility in choosing the composition and architecture of the metalmore » oxide framework and the nature of the functional organic molecule as well as the efficient mass transfer that can occur through a well-designed hierarchically porous network. A sorbent for nuclear applications would have to be highly selective for particular radio nuclides, it would need to be hydrolytically and radiolytically stable, and it would have to possess reasonable capacity and fast kinetics. The sorbent would also have to be available in a form suitable for use in a column. Finally, it would also be desirable if once saturated with radio nuclides, the sorbent could be recycled or converted directly into a ceramic or glass waste form suitable for direct repository disposal or even converted directly into a material that could be used as a transmutation target. Such a cradle-to- grave strategy could have many benefits in so far as process efficiency and the generation of secondary wastes are concerned.This paper will provide an overview of work done on all of the above mentioned aspects of the development of functionalized meso-porous adsorbent materials for the selective separation of lanthanides and actinides and discuss the prospects for future implementation of a cradle-to-grave strategy with such materials. (author)« less

  10. Comparative Kinetic Analysis of Closed-Ended and Open-Ended Porous Sensors

    NASA Astrophysics Data System (ADS)

    Zhao, Yiliang; Gaur, Girija; Mernaugh, Raymond L.; Laibinis, Paul E.; Weiss, Sharon M.

    2016-09-01

    Efficient mass transport through porous networks is essential for achieving rapid response times in sensing applications utilizing porous materials. In this work, we show that open-ended porous membranes can overcome diffusion challenges experienced by closed-ended porous materials in a microfluidic environment. A theoretical model including both transport and reaction kinetics is employed to study the influence of flow velocity, bulk analyte concentration, analyte diffusivity, and adsorption rate on the performance of open-ended and closed-ended porous sensors integrated with flow cells. The analysis shows that open-ended pores enable analyte flow through the pores and greatly reduce the response time and analyte consumption for detecting large molecules with slow diffusivities compared with closed-ended pores for which analytes largely flow over the pores. Experimental confirmation of the results was carried out with open- and closed-ended porous silicon (PSi) microcavities fabricated in flow-through and flow-over sensor configurations, respectively. The adsorption behavior of small analytes onto the inner surfaces of closed-ended and open-ended PSi membrane microcavities was similar. However, for large analytes, PSi membranes in a flow-through scheme showed significant improvement in response times due to more efficient convective transport of analytes. The experimental results and theoretical analysis provide quantitative estimates of the benefits offered by open-ended porous membranes for different analyte systems.

  11. Template-Free Synthesis of Highly Porous Boron Nitride: Insights into Pore Network Design and Impact on Gas Sorption.

    PubMed

    Marchesini, Sofia; McGilvery, Catriona M; Bailey, Josh; Petit, Camille

    2017-10-24

    Production of biocompatible and stable porous materials, e.g., boron nitride, exhibiting tunable and enhanced porosity is a prerequisite if they are to be employed to address challenges such as drug delivery, molecular separations, or catalysis. However, there is currently very limited understanding of the formation mechanisms of porous boron nitride and the parameters controlling its porosity, which ultimately prevents exploiting the material's full potential. Herein, we produce boron nitride with high and tunable surface area and micro/mesoporosity via a facile template-free method using multiple readily available N-containing precursors with different thermal decomposition patterns. The gases are gradually released, creating hierarchical pores, high surface areas (>1900 m 2 /g), and micropore volumes. We use 3D tomography techniques to reconstruct the pore structure, allowing direct visualization of the mesopore network. Additional imaging and analytical tools are employed to characterize the materials from the micro- down to the nanoscale. The CO 2 uptake of the materials rivals or surpasses those of commercial benchmarks or other boron nitride materials reported to date (up to 4 times higher), even after pelletizing. Overall, the approach provides a scalable route to porous boron nitride production as well as fundamental insights into the material's formation, which can be used to design a variety of boron nitride structures.

  12. Porous titanium materials with entangled wire structure for load-bearing biomedical applications.

    PubMed

    He, Guo; Liu, Ping; Tan, Qingbiao

    2012-01-01

    A kind of porous metal-entangled titanium wire material has been investigated in terms of the pore structure (size and distribution), the strength, the elastic modulus, and the mechanical behavior under uniaxial tensile loading. Its functions and potentials for surgical application have been explained. In particular, its advantages over competitors (e.g., conventional porous titanium) have been reviewed. In the study, a group of entangled titanium wire materials with non-woven structure were fabricated by using 12-180 MPa forming pressure, which have porosity in a range of 48%-82%. The pores in the materials are irregular in shape, which have a nearly half-normal distribution in size range. The yield strength, ultimate tensile strength, and elastic modulus are 75 MPa, 108 MPa, and 1.05 GPa, respectively, when its porosity is 44.7%. The mechanical properties decrease significantly as the porosity increases. When the porosity is 57.9%, these values become 24 MPa, 47.5 MPa, and 0.33 GPa, respectively. The low elastic modulus is due to the structural flexibility of the entangled titanium wire materials. For practical reference, a group of detailed data of the porous structure and the mechanical properties are reported. This kind of material is very promising for implant applications because of their very good toughness, perfect flexibility, high strength, adequate elastic modulus, and low cost. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. Method of preparing electrodes with porous current collector structures and solid reactants for secondary electrochemical cells

    DOEpatents

    Gay, Eddie C.; Martino, Fredric J.

    1976-01-01

    Particulate electrode reactants, for instance transition metal sulfides for the positive electrodes and lithium alloys for the negative electrodes, are vibratorily compacted into porous, electrically conductive structures. Structures of high porosity support sufficient reactant material to provide high cell capacity per unit weight while serving as an electrical current collector to improve the utilization of reactant materials. Pore sizes of the structure and particle sizes of the reactant material are selected to permit uniform vibratory loading of the substrate without settling of the reactant material during cycling.

  14. A dynamic experimental study on the evaporative cooling performance of porous building materials

    NASA Astrophysics Data System (ADS)

    Zhang, Yu; Zhang, Lei; Meng, Qinglin; Feng, Yanshan; Chen, Yuanrui

    2017-08-01

    Conventional outdoor dynamic and indoor steady-state experiments have certain limitations in regard to investigating the evaporative cooling performance of porous building materials. The present study investigated the evaporative cooling performance of a porous building material using a special wind tunnel apparatus. First, the composition and control principles of the wind tunnel environment control system were elucidated. Then, the meteorological environment on a typical summer day in Guangzhou was reproduced in the wind tunnel and the evaporation process and thermal parameters of specimens composed of a porous building material were continuously measured. Finally, the experimental results were analysed to evaluate the accuracy of the wind tunnel environment control system, the heat budget of the external surface of the specimens and the total thermal resistance of the specimens and its uncertainty. The analysis results indicated that the normalized root-mean-square error between the measured value of each environmental parameter in the wind tunnel test section and the corresponding value input into the environment control system was <4%, indicating that the wind tunnel apparatus had relatively high accuracy in reproducing outdoor meteorological environments. In addition, the wet specimen could cumulatively consume approximately 80% of the shortwave radiation heat during the day, thereby reducing the temperature of the external surface and the heat flow on the internal surface of the specimen. Compared to the dry specimen, the total thermal resistance of the wet specimen was approximately doubled, indicating that the evaporation process of the porous building material could significantly improve the thermal insulation performance of the specimen.

  15. A review on chemical methodologies for preparation of mesoporous silica and alumina based materials.

    PubMed

    Naik, Bhanudas; Ghosh, Narendra Nath

    2009-01-01

    The discovery of novel family of molecular sieves called M41S aroused a worldwide resurgence in the field of porous materials. According to IUPAC definition inorganic solids that contain pores with diameter in the size range of 20-500 A are considered mesoporous materials. Mesoporous silica and alumina based materials find applications in catalysis, adsorption, host- guest encapsulation etc. This article reviews the current state of art and outline the recent patents in mesoporous materials research in three general areas: Synthesis, various mechanisms involved for porous structure formation and applications of silica and alumina based mesoporous materials.

  16. Cathodes for secondary electrochemical power-producing cells. [layers of porous substrates impregnated with S alternate with layers containing electrolyte

    DOEpatents

    Cairns, E.J.; Kyle, M.; Shimotake, H.

    1973-02-13

    A secondary electrochemical power-producing cell includes an anode containing lithium, an electrolyte containing lithium ions, and a cathode containing sulfur. The cathode comprises plates of a porous substrate material impregnated with sulfur alternating with layers (which may also comprise porous substrate plates) containing electrolyte.

  17. Disintegration of porous polyethylene prostheses.

    PubMed

    Kerr, A G; Riley, D N

    1999-06-01

    A Plastipore (porous polyethylene) Total Ossicular Replacement Prosthesis gave an excellent initial hearing result which was maintained for 14 years. Hearing then began to deteriorate and revision surgery showed disintegration of the prosthesis and a defect in the stapes footplate. Histological examination confirmed previous findings in porous polyethylene with multinucleated foreign body giant cells and breakdown of the material.

  18. Quaternary geologic map of the Lake Erie 4 degrees x 6 degrees quadrangle, United States and Canada

    USGS Publications Warehouse

    Fullerton, David S.; Richmond, Gerald M.; state compilations by Fullerton, David S.; Cowan, W.R.; Sevon, W.D.; Goldthwait, R.P.; Farrand, W.R.; Muller, E.H.; Behling, R.E.; Stravers, J.A.; edited and integrated by Fullerton, David S.; Richmond, Gerald Martin

    1991-01-01

    The Quaternary Geologic Map of the Lake Erie 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  19. Quaternary geologic map of the Quebec 4 degrees x 6 degrees quadrangle, United States and Canada

    USGS Publications Warehouse

    State compilations by Borns, H. W.; Gadd, N.R.; LaSalle, Pierre; Martineau, Ghismond; Chauvin, Luc; Fulton, R.J.; Chapman, W.F.; Wagner, W.P.; Grant, D.R.; edited and integrated by Richmond, Gerald Martin; Fullerton, David S.

    1987-01-01

    The Quaternary Geologic Map of the Quebec 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  20. Quaternary geologic map of the Chicago 4 degrees x 6 degrees quadrangle, United States

    USGS Publications Warehouse

    State compilations by Lineback, Jerry A.; Bleuer, Ned K.; Mickelson, David M.; Farrand, William R.; Goldthwait, Richard P.; Edited and integrated by Richmond, Gerald M.; Fullerton, David S.

    1983-01-01

    The Quaternary Geologic Map of the Chicago 4 degree x 6 degree Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  1. Quaternary geologic map of the Sudbury 4 degree by 6 degree quadrangle, United States and Canada

    USGS Publications Warehouse

    Fullerton, David S.; Sado, Edward V.; Baker, C.L.; Farrand, William R.

    2004-01-01

    The Quaternary Geologic Map of the Sudbury 4 degrees x 6 degrees Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  2. Quaternary geologic map of the Ottawa 4 degrees x 6 degrees quadrangle, United States and Canada

    USGS Publications Warehouse

    Fullerton, David S.; Gadd, N. R.; Veillette, J.J.; Wagner, P.W.; Chapman, W.F.

    1993-01-01

    The Quaternary Geologic Map of the Ottawa 4 degree x 6 degree Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  3. Quaternary geologic map of the Dallas 4° x 6° quadrangle, United States

    USGS Publications Warehouse

    State compilations by Luza, Kenneth V.; Jensen, Kathryn M.; Fishman, W.D.; Wermund, E.G.; Richmond, Gerald Martin; edited and integrated by Richmond, Gerald Martin; Christiansen, Ann Coe; Bush, Charles A.

    1994-01-01

    The Quaternary Geologic Map of the Dallas 4° x 6° Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the ground on which we walk, the dirt in which we dig foundations, and the soil in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  4. Quaternary geologic map of the Chesapeake Bay 4 degrees x 6 degrees quadrangle, United States

    USGS Publications Warehouse

    State compilations by Cleaves, Emery T.; Glaser, John D.; Howard, Alan D.; Johnson, Gerald H.; Wheeler, Walter H.; Sevon, William D.; Judson, Sheldon; Owens, James P.; Peebles, Pamela C.; edited and integrated by Richmond, Gerald Martin; Fullerton, David S.; Weide, David L.

    1987-01-01

    The Quaternary Geologic Map of the Chesapeake Bay 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  5. Quaternary geologic map of the Lake Superior 4 degrees x 6 degrees quadrangle, United States and Canada

    USGS Publications Warehouse

    Richmond, Gerald M.; Fullerton, David S.; state compilations by Farrand, William R.; Mickelson, D.M.; Cowan, W.R.; Goebel, J.E.; edited and integrated by Richmond, Gerald Martin

    1984-01-01

    The Quaternary Geologic Map of the Lake Superior 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  6. Quaternary geologic map of the Hudson River 4 degree x 6 degree quadrangle, United States and Canada

    USGS Publications Warehouse

    State and province compilations by Fullerton, David S.; Sevon, William D.; Muller, Ernest H.; Judson, Sheldon; Black, Robert F.; Wagner, Phillip W.; Hartshorn, Joseph H.; Chapman, William F.; Cowan, William D.; edited and integrated by Fullerton, David S.

    1992-01-01

    The Quaternary Geologic Map of the Hudson River 4? x 6? Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  7. Quaternary geologic map of the Ozark Plateau 4 ° x 6 ° quadrangle, United States

    USGS Publications Warehouse

    State compilations by Whitfield, John William; Ward, R.A.; Denne, J.E.; Holbrook, D.F.; Bush, W.V.; Lineback, J.A.; Luza, K.V.; Jensen, Kathleen M.; Fishman, W.D.; Richmond, Gerald Martin; Weide, David L.; Bush, Charles A.

    1993-01-01

    The Quaternary Geologic Map of the Ozark Plateau 4° x 6° Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the "ground" on which we walk, the "dirt" in which we dig foundations, and the "soil" in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  8. Quaternary geologic map of the Boston 4 degrees x 6 degrees quadrangle, United States and Canada

    USGS Publications Warehouse

    State compilations by Hartshorn, Joseph H.; Thompson, W.B.; Chapman, W.F.; Black, R.F.; Richmond, Gerald Martin; Grant, D.R.; Fullerton, David S.; edited and integrated by Richmond, Gerald Martin

    1991-01-01

    The Quaternary Geologic Map of the Boston 4 deg x 6 deg Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  9. Porous Biodegradable Metals for Hard Tissue Scaffolds: A Review

    PubMed Central

    Yusop, A. H.; Bakir, A. A.; Shaharom, N. A.; Abdul Kadir, M. R.; Hermawan, H.

    2012-01-01

    Scaffolds have been utilized in tissue regeneration to facilitate the formation and maturation of new tissues or organs where a balance between temporary mechanical support and mass transport (degradation and cell growth) is ideally achieved. Polymers have been widely chosen as tissue scaffolding material having a good combination of biodegradability, biocompatibility, and porous structure. Metals that can degrade in physiological environment, namely, biodegradable metals, are proposed as potential materials for hard tissue scaffolding where biodegradable polymers are often considered as having poor mechanical properties. Biodegradable metal scaffolds have showed interesting mechanical property that was close to that of human bone with tailored degradation behaviour. The current promising fabrication technique for making scaffolds, such as computation-aided solid free-form method, can be easily applied to metals. With further optimization in topologically ordered porosity design exploiting material property and fabrication technique, porous biodegradable metals could be the potential materials for making hard tissue scaffolds. PMID:22919393

  10. Unreacted Hugoniots for porous and liquid explosives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gustavsen, R.L.; Sheffield, S.A.

    1993-08-01

    Numerous authors have measured the Hugoniots of a variety of granular explosives pressed to different densities. Each explosive at each density was typically then treated as a unique material having its own Hugoniot. By combining methods used by Hayes, Sheffield and Mitchell (for describing the Hugoniot of HNS at various densities) with Hermann`s P-{alpha} model, it is only necessary to know some thermodynamic constants or the Hugoniot of the initially solid material and the porous material sound speed to obtain accurate unreacted Hugoniots for the porous explosive. We discuss application of this method to several materials including HMX, PETN, TNT,more » and Tetryl, as well as HNS. We also show that the ``Universal Liquid Hugoniot`` can be used to calculate the unreacted Hugoniot for liquid explosives. With this method only the ambient pressure sound speed and density are needed to predict the Hugoniot. Applications presented include nitromethane and liquid TNT.« less

  11. Artificial 3D hierarchical and isotropic porous polymeric materials

    PubMed Central

    Musteata, Valentina-Elena; Behzad, Ali Reza

    2018-01-01

    Hierarchical porous materials that replicate complex living structures are attractive for a wide variety of applications, ranging from storage and catalysis to biological and artificial systems. However, the preparation of structures with a high level of complexity and long-range order at the mesoscale and microscale is challenging. We report a simple, nonextractive, and nonreactive method used to prepare three-dimensional porous materials that mimic biological systems such as marine skeletons and honeycombs. This method exploits the concurrent occurrence of the self-assembly of block copolymers in solution and macrophase separation by nucleation and growth. We obtained a long-range order of micrometer-sized compartments. These compartments are interconnected by ordered cylindrical nanochannels. The new approach is demonstrated using polystyrene-b-poly(t-butyl acrylate), which can be further explored for a broad range of applications, such as air purification filters for viruses and pollution particle removal or growth of bioinspired materials for bone regeneration.

  12. Artificial 3D hierarchical and isotropic porous polymeric materials.

    PubMed

    Chisca, Stefan; Musteata, Valentina-Elena; Sougrat, Rachid; Behzad, Ali Reza; Nunes, Suzana P

    2018-05-01

    Hierarchical porous materials that replicate complex living structures are attractive for a wide variety of applications, ranging from storage and catalysis to biological and artificial systems. However, the preparation of structures with a high level of complexity and long-range order at the mesoscale and microscale is challenging. We report a simple, nonextractive, and nonreactive method used to prepare three-dimensional porous materials that mimic biological systems such as marine skeletons and honeycombs. This method exploits the concurrent occurrence of the self-assembly of block copolymers in solution and macrophase separation by nucleation and growth. We obtained a long-range order of micrometer-sized compartments. These compartments are interconnected by ordered cylindrical nanochannels. The new approach is demonstrated using polystyrene- b -poly( t -butyl acrylate), which can be further explored for a broad range of applications, such as air purification filters for viruses and pollution particle removal or growth of bioinspired materials for bone regeneration.

  13. Hyaluronan based materials with catanionic sugar-derived surfactants as drug delivery systems.

    PubMed

    Roig, F; Blanzat, M; Solans, C; Esquena, J; García-Celma, M J

    2018-04-01

    In the present work novel drug delivery systems consisting in highly porous Hyaluronan foams for the administration of a non-steroidal anti-inflammatory drug (NSAID), ketoprofen, have been obtained. A sugar-derived surfactant associated with ketoprofen was prepared and incorporated into the porous hyaluronan materials. The association between a lactose derived surfactant, Lhyd 12 , and ketoprofen was obtained by acid-base reaction and its physicochemical properties were studied. Tensiometric and dynamic light scattering (DLS) determinations showed the formation of catanionic surfactant aggregates, Lhyd 12 /ketoprofen, in aqueous solution. Furthermore, the catanionic surfactants allowed greater solubilisation of ketoprofen. Hyaluronan porous materials were developed using butanediol diglycidyl ether as crosslinking agent. The profile release of Lhyd 12 /ketoprofen from hyaluronan based materials shows differences as a function of the aggregation state of catanionic surfactant. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Evaluation of the effect of custom burr holes on a surgeon's sense of screw fixation in revision porous metal cups.

    PubMed

    Nyland, Mark A; Lanting, Brent A; Nikolov, Hristo N; Somerville, Lyndsay E; Teeter, Matthew G; Howard, James L

    2016-12-01

    It is common practice to burr custom holes in revision porous metal cups for screw insertion. The objective of this study was to determine how different hole types affect a surgeon's sense of screw fixation. Porous revision cups were prepared with pre-drilled and custom burred holes. Cups were held in place adjacent to synthetic bone material of varying density. Surgeons inserted screws through the different holes and materials. Surgeon subjective rating, compression, and torque was recorded. The torque achieved was greater ( p  = 0.002) for screws through custom holes than pre-fabricated holes in low and medium density material, with no difference for high density. Peak compression was greater ( p  = 0.026) through the pre-fabricated holes only in high density material. Use of burred holes affects the torque generated, and may decrease the amount of cup-acetabulum compression achieved.

  15. Bio-templated synthesis of highly ordered macro-mesoporous silica material for sustained drug delivery

    NASA Astrophysics Data System (ADS)

    Qu, Fengyu; Lin, Huiming; Wu, Xiang; Li, Xiaofeng; Qiu, Shilun; Zhu, Guangshan

    2010-05-01

    The bimodal porous structured silica materials consisting of macropores with the diameter of 5-20 μm and framework-like mesopores with the diameter of 4.7-6.0 nm were prepared using natural Manchurian ash and mango linin as macropored hard templates and P123 as mesopore soft templates, respectively. The macroporous structures of Manchurian ash and mango linin were replicated with the walls containing highly ordered mesoporous silica as well. As-synthesized dual porous silica was characterized by scanning electron microscope (SEM), powder X-ray diffraction (XRD), transmission electron microscope (TEM) and nitrogen adsorption/desorption, fourier transform IR (FTIR) spectroscopy, and thermo-gravimetric analyzer (TGA). Ibuprofen (Ibu) was employed as a model drug and the release profiles showed that the dual porous material had a sustained drug delivery capability. And such highly ordered dual pore silica materials may have potential applications for bimolecular adsorption/separation and tissue repairing.

  16. Thermoacoustic refrigerator

    DOEpatents

    Moss, W.C.

    1997-10-07

    A thermoacoustic device is described having a thermal stack made from a piece of porous material which provides a desirable ratio of thermoacoustic area to viscous area, which has a low resistance to flow, which minimizes acoustic streaming and which has a high specific heat and low thermal conductivity. The thermal stack is easy and cheap to form and it can be formed in small sizes. Specifically, in one embodiment, a thermal stack which is formed by the natural structure of a porous material such as reticulated vitreous carbon is disclosed. The thermal stack is formed by machining a block of reticulated vitreous carbon into the required shape of the thermal stack. In a second embodiment, a micro-thermoacoustic device is disclosed which includes a thermal stack made of a piece of porous material such as reticulated vitreous carbon. In another embodiment, a heat exchanger is disclosed which is formed of a block of heat conductive open cell foam material. 13 figs.

  17. Thermoacoustic refrigerator

    DOEpatents

    Moss, William C.

    1997-01-01

    A thermoacoustic device having a thermal stack made from a piece of porous material which provides a desirable ratio of thermoacoustic area to viscous area, which has a low resistance to flow, which minimizes acoustic streaming and which has a high specific heat and low thermal conductivity is disclosed. The thermal stack is easy and cheap to form and it can be formed in small sizes. Specifically, in one embodiment, a thermal stack which is formed by the natural structure of a porous material such as reticulated vitreous carbon is disclosed. The thermal stack is formed by machining a block of reticulated vitreous carbon into the required shape of the thermal stack. In a second embodiment, a micro-thermoacoustic device is disclosed which includes a thermal stack made of a piece of porous material such as reticulated vitreous carbon. In another embodiment, a heat exchanger is disclosed which is formed of a block of heat conductive open cell foam material.

  18. Porous silicon carbide (SIC) semiconductor device

    NASA Technical Reports Server (NTRS)

    Shor, Joseph S. (Inventor); Kurtz, Anthony D. (Inventor)

    1996-01-01

    Porous silicon carbide is fabricated according to techniques which result in a significant portion of nanocrystallites within the material in a sub 10 nanometer regime. There is described techniques for passivating porous silicon carbide which result in the fabrication of optoelectronic devices which exhibit brighter blue luminescence and exhibit improved qualities. Based on certain of the techniques described porous silicon carbide is used as a sacrificial layer for the patterning of silicon carbide. Porous silicon carbide is then removed from the bulk substrate by oxidation and other methods. The techniques described employ a two-step process which is used to pattern bulk silicon carbide where selected areas of the wafer are then made porous and then the porous layer is subsequently removed. The process to form porous silicon carbide exhibits dopant selectivity and a two-step etching procedure is implemented for silicon carbide multilayers.

  19. Micropore engineering of carbonized porous aromatic framework (PAF-1) for supercapacitors application.

    PubMed

    Li, Yanqiang; Roy, Soumyajit; Ben, Teng; Xu, Shixian; Qiu, Shilun

    2014-07-07

    Micropore engineering of porous carbons on the effect of capacitance was explored using a carbonized porous aromatic framework (PAF-1). The porous carbons obtained through different carbonization methods show different pore structures enabling us to do this. The capacitance was measured both in aqueous electrolyte and different organic electrolytes. The porous carbons prepared by KOH activation show both high microporous volume, which is beneficial for charge storage, and mesoporous volume, which is devoted to fast ion diffusion in the pores; properties which are highly desirable. It shows a capacitance as high as 280 F g(-1) and 203 F g(-1) at a current density of 1 A g(-1) in 6.0 M KOH and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMImTFSI), respectively. We also demonstrate the effect of diffusion and that of geometric packing of the electrolyte ions in the pores, where a commensurate match of the electrolyte ions with the pores of carbonized materials control and influence significantly the capacitance of these materials.

  20. Molecules with polymerizable ligands as precursors to porous doped materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hubert-Pfalzgraf, L.G.; Pajot, N.; Papiernik, R.

    1996-12-31

    Titanium and aluminum alkoxide derivatives with polymerizable ligands such as 2-(methacryloyloxy)ethylacetoacetate (HAAEMA), oleic acid and geraniol (HOGE) have been obtained. The various compounds have been characterized by FT-IR and NMR {sup 1}H. Copolymerization with styrene and divinylbenzene affords porous doped organic materials which have been characterized by scanning electron microscopy (SEM), elemental analysis, density measurements.

  1. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOEpatents

    Hubbell, Joel M.; Sisson, James B.

    1997-01-01

    A portable tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; c) a degassed liquid received within the fluid chamber; d) a pressure transducer mounted in fluid communication with the fluid chamber; e) the body, pressure transducer and degassed liquid having a combined mass; f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and c) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed.

  2. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOEpatents

    Hubbell, J.M.; Sisson, J.B.

    1997-07-08

    A portable tensiometer to in-situ determine below-grade soil moisture potential of earthen soil includes, (a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; (b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; (c) a degassed liquid received within the fluid chamber; (d) a pressure transducer mounted in fluid communication with the fluid chamber; (e) the body, pressure transducer and degassed liquid having a combined mass; (f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and (g) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed. 12 figs.

  3. Porous coordination polymers as novel sorption materials for heat transformation processes.

    PubMed

    Janiak, Christoph; Henninger, Stefan K

    2013-01-01

    Porous coordination polymers (PCPs)/metal-organic frameworks (MOFs) are inorganic-organic hybrid materials with a permanent three-dimensional porous metal-ligand network. PCPs or MOFs are inorganic-organic analogs of zeolites in terms of porosity and reversible guest exchange properties. Microporous water-stable PCPs with high water uptake capacity are gaining attention for low temperature heat transformation applications in thermally driven adsorption chillers (TDCs) or adsorption heat pumps (AHPs). TDCs or AHPs are an alternative to traditional air conditioners or heat pumps operating on electricity or fossil fuels. By using solar or waste heat as the operating energy TDCs or AHPs can significantly help to minimize primary energy consumption and greenhouse gas emissions generated by industrial or domestic heating and cooling processes. TDCs and AHPs are based on the evaporation and consecutive adsorption of coolant liquids, preferably water, under specific conditions. The process is driven and controlled by the microporosity and hydrophilicity of the employed sorption material. Here we summarize the current investigations, developments and possibilities of PCPs/MOFs for use in low-temperature heat transformation applications as alternative materials for the traditional inorganic porous substances like silica gel, aluminophosphates or zeolites.

  4. Digested sludge-derived three-dimensional hierarchical porous carbon for high-performance supercapacitor electrode.

    PubMed

    Zhang, Jia-Jia; Fan, Hao-Xiang; Dai, Xiao-Hu; Yuan, Shi-Jie

    2018-04-01

    Digested sludge, as the main by-product of the sewage sludge anaerobic digestion process, still contains considerable organic compounds. In this protocol, we report a facile method for preparing digested sludge-derived self-doped porous carbon material for high-performance supercapacitor electrodes via a sustainable pyrolysis/activation process. The obtained digested sludge-derived carbon material (HPDSC) exhibits versatile O-, N-doped hierarchical porous framework, high specific surface area (2103.6 m 2  g -1 ) and partial graphitization phase, which can facilitate ion transport, provide more storage sites for electrolyte ions and enhance the conductivity of active electrode materials. The HPDSC-based supercapacitor electrodes show favourable energy storage performance, with a specific capacitance of 245 F g -1 at 1.0 A g -1 in 0.5 M Na 2 SO 4 ; outstanding cycling stability, with 98.4% capacitance retention after 2000 cycles; and good rate performance (211 F g -1 at 11 A g -1 ). This work provides a unique self-doped three-dimensional hierarchical porous carbon material with a favourable charge storage capacity and at the same time finds a high value-added and environment-friendly strategy for disposal and recycling of digested sludge.

  5. High performance aqueous symmetric supercapacitors based on advanced carbon electrodes and hydrophilic poly(vinylidene fluoride) porous separator

    NASA Astrophysics Data System (ADS)

    Xie, Qinxing; Huang, Xiaolin; Zhang, Yufeng; Wu, Shihua; Zhao, Peng

    2018-06-01

    The main components of a supercapacitor include two electrodes, electrolyte, and a separator, which are all essential to specify the energy storage capability of the device. In this work, two kinds of porous carbon materials have been fabricated via different routes using pomelo peel as raw material. The specific surface area are 1187 m2 g-1 for the nanosized worm-like carbon, and 1744 m2 g-1 for the nitrogen-enriched microsized carbon. Both carbon materials demonstrate excellent energy storage capability as electrodes for aqueous supercapacitors. According to the three-electrode measurements, the worm-like carbon exhibits a high specific capacitance of 316 F g-1 at 0.2 A g-1 in 6 M KOH, while the other exhibits 471 F g-1 due to the highly enriched nitrogen atoms in structure. In addition, two-electrode coin-type cells have been assembled with the carbon materials as electrodes and hydrophilic poly(vinylidene fluoride) porous membrane as the separator. The assembled cells exhibit high specific capacitances, excellent rate performance and superior cycling durability because of a synergistic effect of the high performance carbon electrodes and hydrophilic porous separator.

  6. Digested sludge-derived three-dimensional hierarchical porous carbon for high-performance supercapacitor electrode

    NASA Astrophysics Data System (ADS)

    Zhang, Jia-Jia; Fan, Hao-Xiang; Dai, Xiao-Hu; Yuan, Shi-Jie

    2018-04-01

    Digested sludge, as the main by-product of the sewage sludge anaerobic digestion process, still contains considerable organic compounds. In this protocol, we report a facile method for preparing digested sludge-derived self-doped porous carbon material for high-performance supercapacitor electrodes via a sustainable pyrolysis/activation process. The obtained digested sludge-derived carbon material (HPDSC) exhibits versatile O-, N-doped hierarchical porous framework, high specific surface area (2103.6 m2 g-1) and partial graphitization phase, which can facilitate ion transport, provide more storage sites for electrolyte ions and enhance the conductivity of active electrode materials. The HPDSC-based supercapacitor electrodes show favourable energy storage performance, with a specific capacitance of 245 F g-1 at 1.0 A g-1 in 0.5 M Na2SO4; outstanding cycling stability, with 98.4% capacitance retention after 2000 cycles; and good rate performance (211 F g-1 at 11 A g-1). This work provides a unique self-doped three-dimensional hierarchical porous carbon material with a favourable charge storage capacity and at the same time finds a high value-added and environment-friendly strategy for disposal and recycling of digested sludge.

  7. Tailored synthesis of monodispersed nano/submicron porous silicon oxycarbide (SiOC) spheres with improved Li-storage performance as an anode material for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Shi, Huimin; Yuan, Anbao; Xu, Jiaqiang

    2017-10-01

    A spherical silicon oxycarbide (SiOC) material (monodispersed nano/submicron porous SiOC spheres) is successfully synthesized via a specially designed synthetic strategy involving pyrolysis of phenyltriethoxysilane derived pre-ceramic polymer spheres at 900 °C. In order to prevent sintering of the pre-ceramic polymer spheres upon heating, a given amount of hollow porous SiO2 nanobelts which are separately prepared from tetraethyl orthosilicate with CuO nanobelts as templates are introduced into the pre-ceramic polymer spheres before pyrolysis. This material is investigated as an anode for lithium-ion batteries in comparison with the large-size bulk SiOC material synthesized under the similar conditions but without hollow SiO2 nanobelts. The maximum reversible specific capacity of ca. 900 mAh g-1 is delivered at the current density of 100 mA g-1 and ca. 98% of the initial capacity is remained after 100 cycles at 100 mA g-1 for the SiOC spheres material, which are much superior to the bulk SiOC material. The improved lithium storage performance in terms of specific capacity and cyclability is attributed to its particular morphology of monodisperse nano/submicron porous spheres as well as its modified composition and microstructure. This SiOC material has higher Li-storage activity and better stability against volume expansion during repeated lithiation and delithiation cycling.

  8. On the examination of Darcy permeability of soft fibrous porous media; New correlations

    NASA Astrophysics Data System (ADS)

    Zhu, Zenghao; Wang, Qiuyun; Wu, Qianhong

    2017-11-01

    In this presentation, we report a novel experimental approach to investigate the compression-dependent Darcy permeability of soft porous media. Especially, we are proposing new correlations that describe the change of the permeability of random fibrous porous media as a function of its compression. A special device was developed that consisted of a rectangular flow channel with adjustable gap thickness ranging from 3 mm to 20 mm. Air was forced through the thin gap filled with testing fibrous materials. By measuring the flow rate and the pressure gradient, we have successfully obtained the Darcy permeability of different fibrous porous materials at different compression ratios. Theoretical or semi-empirical models have been compared with the experimental results, indicating various degrees of disagreement. The new correlations were then proposed which fit with experimental data very well. The study presented herein provides a useful approach to evaluate the change of the permeability of fibrous porous media as a function of its compression. It will be valuable for examining fluid flow in fibrous porous media where the permeability is difficult to be measured directly. This kind of porous media widely exists in biological systems. This research was supported by the National Science Foundation under Award No. 1511096.

  9. Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents

    DOEpatents

    Taylor-Pashow, Kathryn M. L.; Lin, Wenbin; Abney, Carter W.

    2017-03-21

    A novel metal-organic framework (MOF) templated process for the synthesis of highly porous inorganic sorbents for removing radionuclides, actinides, and heavy metals is disclosed. The highly porous nature of the MOFs leads to highly porous inorganic sorbents (such as oxides, phosphates, sulfides, etc) with accessible surface binding sites that are suitable for removing radionuclides from high level nuclear wastes, extracting uranium from acid mine drainage and seawater, and sequestering heavy metals from waste streams. In some cases, MOFs can be directly used for removing these metal ions as MOFs are converted to highly porous inorganic sorbents in situ.

  10. Mechanical performance of porous concrete pavement containing nano black rice husk ash

    NASA Astrophysics Data System (ADS)

    Ibrahim, M. Y. Mohd; Ramadhansyah, P. J.; Rosli, H. Mohd; Ibrahim, M. H. Wan

    2018-01-01

    This paper presents an experimental research on the performance of nano black rice husk ash on the porous concrete pavement properties. The performance of the porous concrete pavement mixtures was investigated based on their compressive strength, flexural strength, and splitting tensile strength. The results indicated that using nano material from black rice husk ash improved the mechanical properties of porous concrete pavement. In addition, the result of compressive, flexural, and splitting tensile strength was increased with increasing in curing age. Finally, porous concrete pavement with 10% replacement levels exhibited an excellent performance with good strength compared to others.

  11. Bioinspired large-scale aligned porous materials assembled with dual temperature gradients

    PubMed Central

    Bai, Hao; Chen, Yuan; Delattre, Benjamin; Tomsia, Antoni P.; Ritchie, Robert O.

    2015-01-01

    Natural materials, such as bone, teeth, shells, and wood, exhibit outstanding properties despite being porous and made of weak constituents. Frequently, they represent a source of inspiration to design strong, tough, and lightweight materials. Although many techniques have been introduced to create such structures, a long-range order of the porosity as well as a precise control of the final architecture remain difficult to achieve. These limitations severely hinder the scale-up fabrication of layered structures aimed for larger applications. We report on a bidirectional freezing technique to successfully assemble ceramic particles into scaffolds with large-scale aligned, lamellar, porous, nacre-like structure and long-range order at the centimeter scale. This is achieved by modifying the cold finger with a polydimethylsiloxane (PDMS) wedge to control the nucleation and growth of ice crystals under dual temperature gradients. Our approach could provide an effective way of manufacturing novel bioinspired structural materials, in particular advanced materials such as composites, where a higher level of control over the structure is required. PMID:26824062

  12. Ordered porous mesostructured materials from nanoparticle-block copolymer self-assembly

    DOEpatents

    Warren, Scott; Wiesner, Ulrich; DiSalvo, Jr., Francis J

    2013-10-29

    The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

  13. Model simulation and experiments of flow and mass transport through a nano-material gas filter

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Xiaofan; Zheng, Zhongquan C.; Winecki, Slawomir

    2013-11-01

    A computational model for evaluating the performance of nano-material packed-bed filters was developed. The porous effects of the momentum and mass transport within the filter bed were simulated. For the momentum transport, an extended Ergun-type model was employed and the energy loss (pressure drop) along the packed-bed was simulated and compared with measurement. For the mass transport, a bulk dsorption model was developed to study the adsorption process (breakthrough behavior). Various types of porous materials and gas flows were tested in the filter system where the mathematical models used in the porous substrate were implemented and validated by comparing withmore » experimental data and analytical solutions under similar conditions. Good agreements were obtained between experiments and model predictions.« less

  14. Hierarchically interconnected porous scaffolds for phase change materials with improved thermal conductivity and efficient solar-to-electric energy conversion.

    PubMed

    Yang, Jie; Yu, Peng; Tang, Li-Sheng; Bao, Rui-Ying; Liu, Zheng-Ying; Yang, Ming-Bo; Yang, Wei

    2017-11-23

    An ice-templating self-assembly strategy and a vacuum impregnation method were used to fabricate polyethylene glycol (PEG)/hierarchical porous scaffold composite phase change materials (PCMs). Hierarchically interconnected porous scaffolds of boron nitride (BN), with the aid of a small amount of graphene oxide (GO), endow the composite PCMs with high thermal conductivity, excellent shape-stability and efficient solar-to-electric energy conversion. The formation of a three-dimensional (3D) thermally conductive pathway in the composites contributes to improving the thermal conductivity up to 2.36 W m -1 K -1 at a relatively low content of BN (ca. 23 wt%). This work provides a route for thermally conductive and shape-stabilized composite PCMs used as energy storage materials.

  15. Freeze cast porous barium titanate for enhanced piezoelectric energy harvesting

    NASA Astrophysics Data System (ADS)

    Roscow, J. I.; Zhang, Y.; Kraśny, M. J.; Lewis, R. W. C.; Taylor, J.; Bowen, C. R.

    2018-06-01

    Energy harvesting is an important developing technology for a new generation of self-powered sensor networks. This paper demonstrates the significant improvement in the piezoelectric energy harvesting performance of barium titanate by forming highly aligned porosity using freeze casting. Firstly, a finite element model demonstrating the effect of pore morphology and angle with respect to poling field on the poling behaviour of porous ferroelectrics was developed. A second model was then developed to understand the influence of microstructure-property relationships on the poling behaviour of porous freeze cast ferroelectric materials and their resultant piezoelectric and energy harvesting properties. To compare with model predictions, porous barium titanate was fabricated using freeze casting to form highly aligned microstructures with excellent longitudinal piezoelectric strain coefficients, d 33. The freeze cast barium titanate with 45 vol.% porosity had a d 33  =  134.5 pC N‑1 compared to d 33  =  144.5 pC N‑1 for dense barium titanate. The d 33 coefficients of the freeze cast materials were also higher than materials with uniformly distributed spherical porosity due to improved poling of the aligned microstructures, as predicted by the models. Both model and experimental data indicated that introducing porosity provides a large reduction in the permittivity () of barium titanate, which leads to a substantial increase in energy harvesting figure of merit, , with a maximum of 3.79 pm2 N‑1 for barium titanate with 45 vol.% porosity, compared to only 1.40 pm2 N‑1 for dense barium titanate. Dense and porous barium titanate materials were then used to harvest energy from a mechanical excitation by rectification and storage of the piezoelectric charge on a capacitor. The porous barium titanate charged the capacitor to a voltage of 234 mV compared to 96 mV for the dense material, indicating a 2.4-fold increase that was similar to that predicted by the energy harvesting figures of merit.

  16. Study on the preparation process of cross-linked porous cassava starch

    NASA Astrophysics Data System (ADS)

    Yin, Xiulian; You, Qinghong; Wan, Miaomiao; Zhang, Xuejuan; Dai, Chunhua

    2017-04-01

    Using cassava starch as raw material, preparation process of porous cross-linked cassava starch was studied. Using TSTP as cross-linking agents, Orthogonal design was applied for the optimization of cross-linked porous starch preparation process. The results showed that the opitmal conditions of cross-linked porous cassava starch were as follows: reaction temperature 45°C, reaction time 20 h, 1% of the amount of the enzyme, the enzyme ratio of 1:5, pH 5.50, substrate concentration of 40%.

  17. Effect of Pore Structure and Chemistry on the Performance of Activated Oil Sands Petroleum Coke Electrodes for use in Electrochemical Double-Layer Capacitors

    NASA Astrophysics Data System (ADS)

    Zuliani, Jocelyn Ellen

    Electrical energy storage is a limiting barrier to widespread usage and commercialization of sustainable and renewable energy sources, such as wind and solar energy, as well as integration of electric vehicles. Electrochemical double-layer capacitors (EDLCs) are a promising energy storage technology that offers the benefits of high power density, long cycle life, rapid charging rates, and moderate energy density. The energy storage mechanism of EDLCs is physical ion adsorption on the surface of porous carbon electrodes. This thesis is an investigation of three different sections relating to EDLCs: 1) techniques to properly characterize novel porous carbon electrode materials, 2) investigation of activated oil sands petroleum coke (APC) as the electrode material for EDLCs, and 3) a systematic study of the effects of porous carbon structure and chemistry on EDLC performance. In the first section, it was shown that variations in operating conditions and testing techniques can lead to discrepancies in measured and reported capacitance. Therefore, it was concluded that a standardized approach is necessary in order to properly compare different porous carbon electrodes. In the second section, APC was investigated as a novel electrode material for EDLCs. PetCoke is a carbon dense material that can be activated with potassium hydroxide to generate high surface area porous carbon materials. These materials show promising electrochemical performance in EDLCs, with capacitance values up to 400 Fg-1 in 4M potassium hydroxide aqueous electrolytes, depending on the operating conditions. Additionally, the power density of these materials is comparable to that of other carbon nanomaterials, which are more costly and challenging to produce. Finally, the third section investigates the relationship between measured capacitance, and carbon macrostructure, meso-structure, microstructure, and oxygen content. In each of these studies, the desired parameter was varied, while all others (surface area, pore size, chemistry) were maintained constant. Through this systematic approach, this thesis investigates and quantifies the relationship between EDLC performance and important characteristic parameters through isolation of each individual parameter. By understanding the key structural and chemical features that improve EDLC performance, focus can be placed on engineering a sustainable and economic porous carbon material that has these desired features.

  18. Numerical Simulation of the Motion of Aerosol Particles in Open Cell Foam Materials

    NASA Astrophysics Data System (ADS)

    Solovev, S. A.; Soloveva, O. V.; Popkova, O. S.

    2018-03-01

    The motion of aerosol particles in open cell foam material is studied. The porous medium is investigated for a three-dimensional case with detailed simulation of cellular structures within an ordered geometry. Numerical calculations of the motion of particles and their deposition due to inertial and gravitational mechanisms are performed. Deposition efficiency curves for a broad range of particle sizes are constructed. The effect deposition mechanisms have on the efficiency of the porous material as a filter is analyzed.

  19. Structural colored gels for tunable soft photonic crystals.

    PubMed

    Harun-Ur-Rashid, Mohammad; Seki, Takahiro; Takeoka, Yukikazu

    2009-01-01

    A periodically ordered interconnecting porous structure can be embodied in chemical gels by using closest-packed colloidal crystals as templates. The interconnecting porosity not only provides a quick response but also endows the porous gels with structural color arising from coherent Bragg optical diffraction. The structural colors revealed by porous gels can be regulated by several techniques, and thus, it is feasible to obtain desirable, smart, soft materials. A well-known thermosensitive monomer, N-isopropylacrylamide (NIPA), and other minor monomers were used to fabricate various structural colored gels. The selection of minor monomers depended on the targeted properties. This review focuses on the synthesis of templates, structural colored porous gels, and the applications of structural colored gel as smart soft materials for tunable photonic crystals. (c) 2009 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.

  20. Hierarchical Co-based Porous Layered Double Hydroxide Arrays Derived via Alkali Etching for High-performance Supercapacitors

    NASA Astrophysics Data System (ADS)

    Abushrenta, Nasser; Wu, Xiaochao; Wang, Junnan; Liu, Junfeng; Sun, Xiaoming

    2015-08-01

    Hierarchical nanoarchitecture and porous structure can both provide advantages for improving the electrochemical performance in energy storage electrodes. Here we report a novel strategy to synthesize new electrode materials, hierarchical Co-based porous layered double hydroxide (PLDH) arrays derived via alkali etching from Co(OH)2@CoAl LDH nanoarrays. This structure not only has the benefits of hierarchical nanoarrays including short ion diffusion path and good charge transport, but also possesses a large contact surface area owing to its porous structure which lead to a high specific capacitance (23.75 F cm-2 or 1734 F g-1 at 5 mA cm-2) and excellent cycling performance (over 85% after 5000 cycles). The enhanced electrode material is a promising candidate for supercapacitors in future application.

  1. Hierarchical Co-based Porous Layered Double Hydroxide Arrays Derived via Alkali Etching for High-performance Supercapacitors

    PubMed Central

    Abushrenta, Nasser; Wu, Xiaochao; Wang, Junnan; Liu, Junfeng; Sun, Xiaoming

    2015-01-01

    Hierarchical nanoarchitecture and porous structure can both provide advantages for improving the electrochemical performance in energy storage electrodes. Here we report a novel strategy to synthesize new electrode materials, hierarchical Co-based porous layered double hydroxide (PLDH) arrays derived via alkali etching from Co(OH)2@CoAl LDH nanoarrays. This structure not only has the benefits of hierarchical nanoarrays including short ion diffusion path and good charge transport, but also possesses a large contact surface area owing to its porous structure which lead to a high specific capacitance (23.75 F cm−2 or 1734 F g−1 at 5 mA cm−2) and excellent cycling performance (over 85% after 5000 cycles). The enhanced electrode material is a promising candidate for supercapacitors in future application. PMID:26278334

  2. Global sensitivity analysis of multiscale properties of porous materials

    NASA Astrophysics Data System (ADS)

    Um, Kimoon; Zhang, Xuan; Katsoulakis, Markos; Plechac, Petr; Tartakovsky, Daniel M.

    2018-02-01

    Ubiquitous uncertainty about pore geometry inevitably undermines the veracity of pore- and multi-scale simulations of transport phenomena in porous media. It raises two fundamental issues: sensitivity of effective material properties to pore-scale parameters and statistical parameterization of Darcy-scale models that accounts for pore-scale uncertainty. Homogenization-based maps of pore-scale parameters onto their Darcy-scale counterparts facilitate both sensitivity analysis (SA) and uncertainty quantification. We treat uncertain geometric characteristics of a hierarchical porous medium as random variables to conduct global SA and to derive probabilistic descriptors of effective diffusion coefficients and effective sorption rate. Our analysis is formulated in terms of solute transport diffusing through a fluid-filled pore space, while sorbing to the solid matrix. Yet it is sufficiently general to be applied to other multiscale porous media phenomena that are amenable to homogenization.

  3. Compressible pulsating convection through regular and random porous media: the thermoacoustic case

    NASA Astrophysics Data System (ADS)

    Tasnim, Syeda Humaira; Mahmud, Shohel; Fraser, Roydon Andrew

    2012-02-01

    The effects of material, geometry, length and position of the porous channels on energy transfer in air-filled enclosures carrying a compressible pulsating wave are investigated. The pulsating fluid motion is created by an acoustic driver in a resonant chamber. Three different porous materials (Corning Celcor, Reticulated Vitreous Carbon (RVC), and Mylar plastic), three different geometries (square, open foam, and circular cross-section), six different lengths, " L" (varying between 1 and 6.5 cm, L = 0.01-0.068 λ, where λ is the wavelength of the fundamental acoustic mode), and eight different positions (hot end of the channel, varying between 0.5 and 8 cm) of the channels from the pressure anti-node is experimentally measured. The surface temperature distribution on the channel wall and temperature difference generated across the channel walls are measured while energy flow along the channel walls is calculated analytically. The experimental results are compared with a 1-D numerical code and found excellent agreement. The material, geometry, length, and position of the porous channel strongly affect the energy interactions between the porous channel and the working fluid. The temperature difference generated across the porous RVC channel increases as the porosity increases form 20 to 80 PPI; but decreases if the porosity increases further. Corning Celcor shows improved temperature difference generated across the channel as the length of the channel increases; but then decreases if the length is further increased. The results of this study are applicable to the design of thermoacoustic devices.

  4. Graphitic Carbon Materials Tailored for the Rapid Adsorption of Biomolecules

    NASA Astrophysics Data System (ADS)

    Pescatore, Nicholas A.

    Sepsis is an overactive inflammatory response to an infection, with 19 million cases estimated worldwide and causing organ dysfunction if left untreated. Three pro-inflammatory cytokines are seen from literature review as vital biomarkers for sepsis and are interleukin-6 (IL-6), interleukin-8 (IL-8) and tumor necrosis factor-alpha (TNF-alpha), which have the potential to be removed by hemoperfusion. This thesis examines carbon nanomaterials for their adsorption capabilities in the search for an optimal material for blood cleansing hemoperfusion application, such as mediating the effects of sepsis. Non-porous and porous carbon polymorphs and their properties are investigated in this thesis for their protein adsorption capabilities. Polymer-derived mesoporous carbons were compared to non-porous graphene nanoplatelets (GNP's) to observe changes in adsorption capacity for cytokines between porous and non-porous materials. GNP's were functionalized via high temperature vacuum annealing, air oxidation, acid oxidation and amination treatments to understand the effect of surface chemistry on adsorption. For practical use in a hemoperfusion column, polymer-derived carbon beads and composite materials such as cryogel and PTFE-GNP composites were designed and tested for their adsorption capacity. At concentrations of IL-6, IL-8, and TNF-alpha seen in septic patients, these cytokines were completely removed from the blood after 5 minutes of incubation with GNP's. Overall, a low-cost, scalable carbon adsorbent was found to provide a novel approach of rapidly removing pro-inflammatory cytokines from septic patients.

  5. In silico design of porous polymer networks: high-throughput screening for methane storage materials.

    PubMed

    Martin, Richard L; Simon, Cory M; Smit, Berend; Haranczyk, Maciej

    2014-04-02

    Porous polymer networks (PPNs) are a class of advanced porous materials that combine the advantages of cheap and stable polymers with the high surface areas and tunable chemistry of metal-organic frameworks. They are of particular interest for gas separation or storage applications, for instance, as methane adsorbents for a vehicular natural gas tank or other portable applications. PPNs are self-assembled from distinct building units; here, we utilize commercially available chemical fragments and two experimentally known synthetic routes to design in silico a large database of synthetically realistic PPN materials. All structures from our database of 18,000 materials have been relaxed with semiempirical electronic structure methods and characterized with Grand-canonical Monte Carlo simulations for methane uptake and deliverable (working) capacity. A number of novel structure-property relationships that govern methane storage performance were identified. The relationships are translated into experimental guidelines to realize the ideal PPN structure. We found that cooperative methane-methane attractions were present in all of the best-performing materials, highlighting the importance of guest interaction in the design of optimal materials for methane storage.

  6. Numerical investigation of active porous composites with enhanced acoustic absorption

    NASA Astrophysics Data System (ADS)

    Zieliński, Tomasz G.

    2011-10-01

    The paper presents numerical analysis - involving an advanced multiphysics modeling - of the concept of active porous composite sound absorbers. Such absorbers should be made up of a layer or layers of poroelastic material (porous foams) with embedded elastic inclusions having active (piezoelectric) elements. The purpose of such active composite material is to significantly absorb the energy of acoustic waves in a wide frequency range, particularly, at lower frequencies. At the same time the total thickness of composite should be very moderate. The active parts of composites are used to adapt the absorbing properties of porous layers to different noise conditions by affecting the so-called solid-borne wave - originating mainly from the vibrations of elastic skeleton of porous medium - to counteract the fluid-borne wave - resulting mainly from the vibrations of air in the pores; both waves are strongly coupled, especially, at lower frequencies. In fact, since the traction between the air and the solid frame of porous medium is the main absorption mechanism, the elastic skeleton is actively vibrated in order to adapt and improve the dissipative interaction of the skeleton and air in the pores. Passive and active performance of such absorbers is analyzed to test the feasibility of this approach.

  7. A multi-scale homogenization model for fine-grained porous viscoplastic polycrystals: II - Applications to FCC and HCP materials

    NASA Astrophysics Data System (ADS)

    Song, Dawei; Ponte Castañeda, P.

    2018-06-01

    In Part I of this work (Song and Ponte Castañeda, 2018a), a new homogenization model was developed for the macroscopic behavior of three-scale porous polycrystals consisting of random distributions of large pores in a fine-grained polycrystalline matrix. In this second part, the model is used to investigate both the instantaneous effective behavior and the finite-strain macroscopic response of porous FCC and HCP polycrystals for axisymmetric loading conditions. The stress triaxiality and Lode parameter are found to have significant effects on the evolution of the substructure, which in turn have important implications for the overall hardening/softening behavior of the porous polycrystal. The intrinsic effect of the texture evolution of the polycrystalline matrix is inferred by appropriate comparisons with corresponding results for porous isotropic materials, and found to be significant, especially at low triaxialities. In particular, the predictions of the model identify, for the first time, two disparate regimes for the macroscopic response of porous polycrystals: a porosity-controlled regime at high triaxialities, and a texture-controlled regime at low triaxialities. The transition between these two regimes is found to be quite sharp, taking place between triaxialities of 1 and 2.

  8. Buried anti resonant reflecting optical waveguide based on porous silicon material for an integrated Mach Zehnder structure

    NASA Astrophysics Data System (ADS)

    Hiraoui, M.; Guendouz, M.; Lorrain, N.; Haji, L.; Oueslati, M.

    2012-11-01

    A buried anti resonant reflecting optical waveguide for an integrated Mach Zehnder structure based on porous silicon material is achieved using a classical photolithography process. Three distinct porous silicon layers are then elaborated in a single step, by varying the porosity (thus the refractive index) and the thickness while respecting the anti-resonance conditions. Simulations and experimental results clearly show the antiresonant character of the buried waveguides. Significant variation of the reflectance and light propagation with different behavior depending on the polarization and the Mach Zehnder dimensions is obtained. Finally, we confirm the feasibility of this structure for sensing applications.

  9. Measuring surface-area-to-volume ratios in soft porous materials using laser-polarized xenon interphase exchange nuclear magnetic resonance

    NASA Technical Reports Server (NTRS)

    Butler, J. P.; Mair, R. W.; Hoffmann, D.; Hrovat, M. I.; Rogers, R. A.; Topulos, G. P.; Walsworth, R. L.; Patz, S.

    2002-01-01

    We demonstrate a minimally invasive nuclear magnetic resonance (NMR) technique that enables determination of the surface-area-to-volume ratio (S/V) of soft porous materials from measurements of the diffusive exchange of laser-polarized 129Xe between gas in the pore space and 129Xe dissolved in the solid phase. We apply this NMR technique to porous polymer samples and find approximate agreement with destructive stereological measurements of S/V obtained with optical confocal microscopy. Potential applications of laser-polarized xenon interphase exchange NMR include measurements of in vivo lung function in humans and characterization of gas chromatography columns.

  10. Top-down solid-phase fabrication of nanoporous cadmium oxide architectures.

    PubMed

    Yu, Haidong; Wang, Deshen; Han, Ming-Yong

    2007-02-28

    In this article, we have demonstrated one-step solid-phase transformation from high-quality cadmium carbonate microcrystals into highly nanoporous cadmium oxide. The high crystal quality of cadmium carbonate is critical for the successful fabrication of porous nanoarchitectures with predetermined morphology and well-controlled internal structure. This novel strategy has a good potential to prepare nanoporous materials at a large scale by using perfect monolithic carbonate crystals, and it is also useful to synthesize different nanoporous materials on metal-oxide-coated substrates. Meanwhile, this simple thermal transformation of cadmium carbonate into porous structures has further been extended to convert calcium carbonate into such porous structures.

  11. Infiltration of MHD liquid into a deformable porous material

    NASA Astrophysics Data System (ADS)

    Naseem, Anum; Mahmood, Asif; Siddique, J. I.; Zhao, Lifeng

    2018-03-01

    We analyze the capillary rise dynamics for magnetohydrodynamics (MHD) fluid flow through deformable porous material in the presence of gravity effects. The modeling is performed using mixture theory approach and mathematical manipulation yields a nonlinear free boundary problem. Due to the capillary rise action, the pressure gradient in the liquid generates a stress gradient that results in the deformation of porous substrate. The capillary rise process for MHD fluid slows down as compared to Newtonian fluid case. Numerical solutions are obtained using a method of lines approach. The graphical results are presented for important physical parameters, and comparison is presented with Newtonian fluid case.

  12. Factors affecting the pullout strength of cancellous bone screws.

    PubMed

    Chapman, J R; Harrington, R M; Lee, K M; Anderson, P A; Tencer, A F; Kowalski, D

    1996-08-01

    Screws placed into cancellous bone in orthopedic surgical applications, such as fixation of fractures of the femoral neck or the lumbar spine, can be subjected to high loads. Screw pullout is a possibility, especially if low density osteoporotic bone is encountered. The overall goal of this study was to determine how screw thread geometry, tapping, and cannulation affect the holding power of screws in cancellous bone and determine whether current designs achieve maximum purchase strength. Twelve types of commercially available cannulated and noncannulated cancellous bone screws were tested for pullout strength in rigid unicellular polyurethane foams of apparent densities and shear strengths within the range reported for human cancellous bone. The experimentally derived pullout strength was compared to a predicted shear failure force of the internal threads formed in the polyurethane foam. Screws embedded in porous materials pullout by shearing the internal threads in the porous material. Experimental pullout force was highly correlated to the predicted shear failure force (slope = 1.05, R2 = 0.947) demonstrating that it is controlled by the major diameter of the screw, the length of engagement of the thread, the shear strength of the material into which the screw is embedded, and a thread shape factor (TSF) which accounts for screw thread depth and pitch. The average TSF for cannulated screws was 17 percent lower than that of noncannulated cancellous screws, and the pullout force was correspondingly less. Increasing the TSF, a result of decreasing thread pitch or increasing thread depth, increases screw purchase strength in porous materials. Tapping was found to reduce pullout force by an average of 8 percent compared with nontapped holes (p = 0.0001). Tapping in porous materials decreases screw pullout strength because the removal of material by the tap enlarges hole volume by an average of 27 percent, in effect decreasing the depth and shear area of the internal threads in the porous material.

  13. Biogenic porous silica and silicon sourced from Mexican Giant Horsetail (Equisetum myriochaetum) and their application as supports for enzyme immobilization.

    PubMed

    Sola-Rabada, Anna; Sahare, Padma; Hickman, Graham J; Vasquez, Marco; Canham, Leigh T; Perry, Carole C; Agarwal, Vivechana

    2018-06-01

    Porous silica-based materials are attractive for biomedical applications due to their biocompatibility and biodegradable character. In addition, inorganic supports such as porous silicon are being developed due to integrated circuit chip compatibility and tunable properties leading to a wide range of multidisciplinary applications. In this contribution, biosilica extracted from a rarely studied plant material (Equisetum Myriochaetum), its conversion to silicon and the potential for both materials to be used as supports for enzyme immobilization are investigated. E. myriochaetum was subject to conventional acid digestion to extract biogenic silica with a% yield remarkably higher (up to 3 times) than for other Equisetum sp. (i.e. E. Arvense). The surface area of the isolated silica was ∼400 m 2 /g, suitable for biotechnological applications. Biogenic silicon was obtained by magnesiothermic reduction. The materials were characterized by SEM-EDX, XRD, FT-IR, ICP-OES, TGA and BET analysis and did not contain significant levels of class 1 heavy elements (such as Pb, Cd, Hg and As). Two commercial peroxidases, horseradish peroxidase (HRP) and Coprinus cinereus peroxidase (CiP) were immobilized onto the biogenic materials using three different functionalization routes: (A) carbodiimide, (B) amine + glutaraldehyde and (C) amine + carbodiimide. Although both biogenic silica and porous silicon could be used as supports differences in behaviour were observed for the two enzymes. For HRP, loading onto biogenic silica via the glutaraldehyde immobilization technique (route B) was most effective. The loading of CiP showed a much higher peroxidase activity onto porous silicon than silica functionalized by the carbodiimide method (route A). From the properties of the extracted materials obtained from Equisetum Myriochaetum and the immobilization results observed, these materials appear to be promising for industrial and biomedical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Collagen-grafted porous HDPE/PEAA scaffolds for bone reconstruction.

    PubMed

    Kim, Chang-Shik; Jung, Kyung-Hye; Kim, Hun; Kim, Chan-Bong; Kang, Inn-Kyu

    2016-01-01

    After tumor resection, bone reconstruction such as skull base reconstruction using interconnected porous structure is absolutely necessary. In this study, porous scaffolds for bone reconstruction were prepared using heat-pressing and salt-leaching methods. High-density polyethylene (HDPE) and poly(ethylene-co-acrylic acid) (PEAA) were chosen as the polymer composites for producing a porous scaffold of high mechanical strength and having high reactivity with biomaterials such as collagen, respectively. The porous structure was observed through surface images, and its intrusion volume and porosity were measured. Owing to the carboxylic acids on PEAA, collagen was successfully grafted onto the porous HDPE/PEAA scaffold, which was confirmed by FT-IR spectroscopy and electron spectroscopy for chemical analysis. Osteoblasts were cultured on the collagen-grafted porous scaffold, and their adhesion, proliferation, and differentiation were investigated. The high viability and growth of the osteoblasts suggest that the collagen-grafted porous HDPE/PEAA is a promising scaffold material for bone generation.

  15. Electrostatic-Assisted Liquefaction of Porous Carbons

    DOE PAGES

    Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui; ...

    2017-10-10

    Porous liquids are a newly developed porous material that combine unique fluidity with permanent porosity, which exhibit promising functionalities for a variety of applications. However, the apparent incompatibility between fluidity and permanent porosity makes the stabilization of porous nanoparticle with still empty pores in the dense liquid phase a significant challenging. For this study, by exploiting the electrostatic interaction between carbon networks and polymerized ionic liquids, we demonstrate that carbon-based porous nanoarchitectures can be well stabilized in liquids to afford permanent porosity, and thus opens up a new approach to prepare porous carbon liquids. Furthermore, we hope this facile synthesismore » strategy can be widely applicated to fabricate other types of porous liquids, such as those (e.g., carbon nitride, boron nitride, metal–organic frameworks, covalent organic frameworks etc.) also having the electrostatic interaction with polymerized ionic liquids, evidently advancing the development and understanding of porous liquids.« less

  16. Method of fabricating porous silicon carbide (SiC)

    NASA Technical Reports Server (NTRS)

    Shor, Joseph S. (Inventor); Kurtz, Anthony D. (Inventor)

    1995-01-01

    Porous silicon carbide is fabricated according to techniques which result in a significant portion of nanocrystallites within the material in a sub 10 nanometer regime. There is described techniques for passivating porous silicon carbide which result in the fabrication of optoelectronic devices which exhibit brighter blue luminescence and exhibit improved qualities. Based on certain of the techniques described porous silicon carbide is used as a sacrificial layer for the patterning of silicon carbide. Porous silicon carbide is then removed from the bulk substrate by oxidation and other methods. The techniques described employ a two-step process which is used to pattern bulk silicon carbide where selected areas of the wafer are then made porous and then the porous layer is subsequently removed. The process to form porous silicon carbide exhibits dopant selectivity and a two-step etching procedure is implemented for silicon carbide multilayers.

  17. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hu, Michael Z.; Simpson, John T.; Aytug, Tolga

    Superhydrophobic membrane structures having a beneficial combination of throughput and a selectivity. The membrane structure can include a porous support substrate; and a membrane layer adherently disposed on and in contact with the porous support substrate. The membrane layer can include a nanoporous material having a superhydrophobic surface. The superhydrophobic surface can include a textured surface, and a modifying material disposed on the textured surface. Methods of making and using the membrane structures.

  18. Flow Control about an Airborne Laser Turret

    DTIC Science & Technology

    1982-06-01

    that houses the laser telescope• Afterbody f=airing and f•iselage boundary layer suction were employed with porous material added when necessary to...Thesis Advisor Chairman, D partment of Aeronautics Dean of Scienci arnd Engineering 3 ABSTRACT This thesis project is the latest in a series of...that houses the laser telescope. Afterbody fairing and fuselage boundary layer suction were employed with porous material added when necessary to

  19. Radiative Heat Transfer Modeling in Fibrous Porous Media

    NASA Technical Reports Server (NTRS)

    Sobhani, Sadaf; Panerai, Francesco; Borner, Arnaud; Ferguson, Joseph C.; Wray, Alan; Mansour, Nagi N.

    2017-01-01

    Phenolic-Impregnated Carbon Ablator (PICA) was developed at NASA Ames Research Center as a lightweight thermal protection system material for successful atmospheric entries. The objective of the current work is to compute the effective radiative conductivity of fibrous porous media, such as preforms used to make PICA, to enable the efficient design of materials that can meet the thermal performance goals of forthcoming space exploration missions.

  20. Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials

    PubMed Central

    Stadie, Nicholas P.; Callini, Elsa; Mauron, Philippe; Borgschulte, Andreas; Züttel, Andreas

    2015-01-01

    Supercritical fluid extraction and drying methods are well established in numerous applications for the synthesis and processing of porous materials. Herein, nitrogen is presented as a novel supercritical drying fluid for specialized applications such as in the processing of reactive porous materials, where carbon dioxide and other fluids are not appropriate due to their higher chemical reactivity. Nitrogen exhibits similar physical properties in the near-critical region of its phase diagram as compared to carbon dioxide: a widely tunable density up to ~1 g ml-1, modest critical pressure (3.4 MPa), and small molecular diameter of ~3.6 Å. The key to achieving a high solvation power of nitrogen is to apply a processing temperature in the range of 80-150 K, where the density of nitrogen is an order of magnitude higher than at similar pressures near ambient temperature. The detailed solvation properties of nitrogen, and especially its selectivity, across a wide range of common target species of extraction still require further investigation. Herein we describe a protocol for the supercritical nitrogen processing of porous magnesium borohydride. PMID:26066492

  1. Visible photoluminescence of porous Si(1-x)Ge(x) obtained by stain etching

    NASA Technical Reports Server (NTRS)

    Ksendzov, A.; Fathauer, R. W.; George, T.; Pike, W. T.; Vasquez, R. P.; Taylor, A. P.

    1993-01-01

    We have investigated visible photoluminescence (PL) from thin porous Si(1-x)Ge(x) alloy layers prepared by stain etching of molecular-beam-epitaxy-grown material. Seven samples with nominal Ge fraction x varying from 0.04 to 0.41 were studied at room temperature and 80 K. Samples of bulk stain etched Si and Ge were also investigated. The composition of the porous material was determined using X-ray photoemission spectroscopy and Rutherford backscattering techniques to be considerably more Ge-rich than the starting epitaxial layers. While the luminescence intensity drops significantly with the increasing Ge fraction, we observe no significant variation in the PL wavelength at room temperature. This is clearly in contradiction to the popular model based on quantum confinement in crystalline silicon which predicts that the PL energy should follow the bandgap variation of the starting material. However, our data are consistent with small active units containing only a few Si atoms that are responsible for the light emission. Such units are present in many compounds proposed in the literature as the cause of the visible PL in porous Si.

  2. Microwave assisted synthesis of camellia oleifera shell-derived porous carbon with rich oxygen functionalities and superior supercapacitor performance

    NASA Astrophysics Data System (ADS)

    Liang, Jiyuan; Qu, Tingting; Kun, Xiang; Zhang, Yu; Chen, Shanyong; Cao, Yuan-Cheng; Xie, Mingjiang; Guo, Xuefeng

    2018-04-01

    Biomass-derived carbon (BDCs) materials are receiving extensive attention as electrode materials for energy storage because of the considerable economic value offering possibility for practical applications, but the electrochemical capacitance of BDCs are usually relatively low resulted from limited electric double layer capacitance. Herein, an oxygen-rich porous carbon (KMAC) was fabricated through a rapid and convenient microwave assisted carbonization and KOH activation of camellia oleifera shell. The obtained KMAC possesses three-dimensional porous architecture, large surface area (1229 m2/g) and rich oxygen functionalities (C/O ratio of 1.66). As the electrode materials for supercapacitor, KMAC exhibits superior supercapacitive performances as compared to the activated carbon (KAC) derived from direct carbonization/KOH activation method in 2.0 M H2SO4 (315 F/g vs. 202 F/g) and 6.0 M KOH (251 F/g vs. 214 F/g) electrolyte due to the rich oxygen-containing functional groups on the surface of porous carbon resulted from the developed microwave-assisted carbonization/activation approach.

  3. Highly stable porous silicon-carbon composites as label-free optical biosensors.

    PubMed

    Tsang, Chun Kwan; Kelly, Timothy L; Sailor, Michael J; Li, Yang Yang

    2012-12-21

    A stable, label-free optical biosensor based on a porous silicon-carbon (pSi-C) composite is demonstrated. The material is prepared by electrochemical anodization of crystalline Si in an HF-containing electrolyte to generate a porous Si template, followed by infiltration of poly(furfuryl) alcohol (PFA) and subsequent carbonization to generate the pSi-C composite as an optically smooth thin film. The pSi-C sensor is significantly more stable toward aqueous buffer solutions (pH 7.4 or 12) compared to thermally oxidized (in air, 800 °C), hydrosilylated (with undecylenic acid), or hydrocarbonized (with acetylene, 700 °C) porous Si samples prepared and tested under similar conditions. Aqueous stability of the pSi-C sensor is comparable to related optical biosensors based on porous TiO(2) or porous Al(2)O(3). Label-free optical interferometric biosensing with the pSi-C composite is demonstrated by detection of rabbit IgG on a protein-A-modified chip and confirmed with control experiments using chicken IgG (which shows no affinity for protein A). The pSi-C sensor binds significantly more of the protein A capture probe than porous TiO(2) or porous Al(2)O(3), and the sensitivity of the protein-A-modified pSi-C sensor to rabbit IgG is found to be ~2× greater than label-free optical biosensors constructed from these other two materials.

  4. Flower-like NiO structures: Controlled hydrothermal synthesis and electrochemical characteristic

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chai, Hui; Chen, Xuan; Key Laboratory of Advanced Functional Materials, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, Xinjiang

    Graphical abstract: Flower-like porous NiO was obtained via thermal decomposition of the precursor prepared by a hydrothermal process using hexamethylenetetramine and polyethylene glycol as hydrolysis-controlling agent and surfactant, respectively. The morphology and microstructure of as-synthesized NiO were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results of electrochemical measurements demonstrated that the flower-like porous NiO has high capacity (340 F g{sup −1}) with excellent cycling performance as electrode materials of electrochemical capacitors (ECs), which may be attributed to the unique microstrcture of NiO. Data analyses indicated that NiO with novel porousmore » structure attractive for practical and large-scale applications in electrochemical capacitors. Display Omitted Highlights: ► Synthesis and characterization of NiO with novel porous structure is presented in this work. ► The electrochemical performance of product was examined. ► NiO with excellent performance as electrode materials may be due to the unique microstrcture. ► NiO with novel porous structure attractive for practical with high capacity (340 F g{sup −1}). -- Abstract: Flower-like porous NiO was obtained by thermal decomposition of the precursor prepared by a hydrothermal process with hexamethylenetetramine and polyethylene glycol as hydrolysis-controlling agent and surfactant, respectively. The morphology and microstructure of as-synthesized NiO were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The resulting structures of NiO exhibited porous like petal building blocks. The electrochemical measurements’ results demonstrated that flower-like porous NiO has high capacity (340 F g{sup −1}) with excellent cycling performance as electrode materials for electrochemical capacitors, which may be attributed to the unique structure of NiO. The results indicated that NiO with novel porous structure has been attractive for practical and large-scale applications in electrochemical capacitors.« less

  5. Theoretical and numerical aspects of fluid-saturated elasto-plastic soils

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ehlers, W.

    1995-12-31

    The theoretical and numerical treatment of fluid-saturated porous solid materials generally falls into the category of porous media models, which are described within the framework of the classical theory of mixtures extended by the concept of volume fractions (porous media theories). In particular, this concept allows for the description of saturated, unsaturated and empty porous matrix materials, thus offering a well-founded theoretical background for a lot of engineering problems occurring, for instance, in the fields of geomechanics (soil and rock mechanics as well as glacier and rock ice mechanics), oil producing industries, sintering technologies, biomechanics, etc. In the present contribution,more » theoretical and numerical studies are outlined to describe a two-phase material composed of an incompressible elasto-plastic soil matrix saturated by an incompressible viscous pore fluid. In this context, the phenomenon of phase incompressibility is well known as a microscopic effect not implying bulk incompressibility in the macro regime. This is seen from the fact that even if the material density functions of the individual constituents are constant during deformation, the corresponding bulk densities can still change through changes in the volume fractions. Within the framework of a pure mechanical theory, constitutive equations are given for both the solid and the fluid partial stress tensors and for the interaction force acting between the two materials. Concerning the porous soil matrix, the elastic properties are described by an elasticity law of Hookean type, while the plastic range is governed by a {open_quote}single surface{close_quote} yield function exhibiting a smooth and closed shape in the principal stress space together with a non-associated flow rule. The viscosity effects of the pore fluid are included in the fluid stress tensor and in the drag force.« less

  6. High frequency acoustic reflections from an air-snow interface

    NASA Astrophysics Data System (ADS)

    Courville, Z.; Albert, D. G.; Lieb-Lappen, R.; Fegyveresi, J. M.

    2016-12-01

    High frequency wave propagation methods can be used to determine in situ near surface micro-pore geometry parameters in real Earth materials including snow. To this end, we have been developing a portable ultrasonic transducer rig to make measurements of acoustic reflections from a variety of natural porous media. Fresh natural snow, in particular, is a difficult material to characterize, as any mechanical interaction is likely to damage the fragile pores and grain bonds. Because acoustic waves are sensitive to the porous material properties, they potentially can be used to measure snow properties in a non-destructive manner. Such methods have already been demonstrated on cohesive porous materials including manufactured foams, porous metals, and sintered glass beads. We conducted high frequency, oblique-angle and near vertical reflection measurements on snow samples in a cold room. We then compare the acoustically derived snow physical parameters, including porosity, with values determined from micro-computed tomography (μCT) and with standard (but destructive) laboratory measurements. Preliminary results using a manufactured open cell foam following previous work by Fellah et al., (2003) shows very good agreement between values of porosity determined from the acoustic measurements and the values determined from μCT image analysis and gravimetric determination. Similarly, preliminary results comparing acoustic measurements of natural, dry snow samples prepared in the laboratory show good agreement between acoustically-derived porosity values and porosity values derived through independent means. Fellah, Z.E.A., S. Berger, W. Lauriks, C. Depollier, C. Aristegui, and J.Y. Chapelon, (2003b), Measuring the porosity and tortuosity of porous materials via reflected waves at oblique incidence, J. Acous. Soc. Am., 113, 2424-2433.

  7. Controlling porosity in lignin-derived nanoporous carbon for supercapacitor applications

    DOE PAGES

    Jeon, Ju-Won; Zhang, Libing; Lutkenhaus, Jodie L.; ...

    2015-02-01

    Low-cost renewable lignin has been used as a precursor to produce porous carbons. However, to date, it has not been easy to obtain high surface area porous carbon without activation processes or templating agents. Here, we demonstrate that low molecular weight lignin yields highly porous carbon (1092 m² g⁻¹) with more graphitization through direct carbonization without additional activation processes or templating agents. We found that molecular weight and oxygen consumption during carbonization are critical factors to obtain high surface area, graphitized porous carbons. This highly porous carbon from low-cost renewable lignin sources is a good candidate for supercapacitor electrode materials.

  8. Controlling porosity in lignin-derived nanoporous carbon for supercapacitor applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jeon, Ju-Won; Zhang, Libing; Lutkenhaus, Jodie L.

    Low-cost renewable lignin has been used as a precursor to produce porous carbons. However, to date, it has not been easy to obtain high surface area porous carbon without activation processes or templating agents. Here, we demonstrate that low molecular weight lignin yields highly porous carbon (1092 m² g⁻¹) with more graphitization through direct carbonization without additional activation processes or templating agents. We found that molecular weight and oxygen consumption during carbonization are critical factors to obtain high surface area, graphitized porous carbons. This highly porous carbon from low-cost renewable lignin sources is a good candidate for supercapacitor electrode materials.

  9. Soil Moisture Flow and Nitrate Movement Simulation through Deep and Heterogeneous Vadose Zone using Dual-porosity Approach

    NASA Astrophysics Data System (ADS)

    Yadav, B. K.; Tomar, J.; Harter, T.

    2014-12-01

    We investigate nitrate movement from non-point sources in deep, heterogeneous vadose zones, using multi-dimensional variably saturated flow and transport simulations. We hypothesize that porous media heterogeneity causes saturation variability that leads to preferential flow systems such that a significant portion of the vadose zone does not significantly contribute to flow. We solve Richards' equation and the advection-dispersion equation to simulate soil moisture and nitrate transport regimes in plot-scale experiments conducted in the San Joaquin Valley, California. We compare equilibrium against non-equilibrium (dual-porosity) approaches. In the equilibrium approach we consider each soil layer to have unique hydraulic properties as a whole, while in the dual-porosity approach we assume that large fractions of the porous flow domain are immobile. However we consider exchange of water and solute between mobile and immobile zone using the appropriate mass transfer terms. The results indicate that flow and transport in a nearly 16 m deep stratified vadose zone comprised of eight layers of unconsolidated alluvium experiences highly non-uniform, localized preferential flow and transport patterns leading to accelerated nitrate transfer. The equilibrium approach largely under-predicted the leaching of nitrate to groundwater while the dual-porosity approach showed higher rates of nitrate leaching, consistent with field observations. The dual-porosity approach slightly over-predicted nitrogen storage in the vadose zone, which may be the result of limited matrix flow or denitrification not accounted for in the model. Results of this study may be helpful to better predict fertilizer and pesticide retention times in deep vadose zone, prior to recharge into the groundwater flow system. Keywords: Nitrate, Preferential flow, Heterogeneous vadose zone, Dual-porosity approach

  10. Comparison of comet 81P/Wild 2 dust with interplanetary dust from comets.

    PubMed

    Ishii, Hope A; Bradley, John P; Dai, Zu Rong; Chi, Miaofang; Kearsley, Anton T; Burchell, Mark J; Browning, Nigel D; Molster, Frank

    2008-01-25

    The Stardust mission returned the first sample of a known outer solar system body, comet 81P/Wild 2, to Earth. The sample was expected to resemble chondritic porous interplanetary dust particles because many, and possibly all, such particles are derived from comets. Here, we report that the most abundant and most recognizable silicate materials in chondritic porous interplanetary dust particles appear to be absent from the returned sample, indicating that indigenous outer nebula material is probably rare in 81P/Wild 2. Instead, the sample resembles chondritic meteorites from the asteroid belt, composed mostly of inner solar nebula materials. This surprising finding emphasizes the petrogenetic continuum between comets and asteroids and elevates the astrophysical importance of stratospheric chondritic porous interplanetary dust particles as a precious source of the most cosmically primitive astromaterials.

  11. High-gradient permanent magnet apparatus and its use in particle collection

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cheng, Mengdawn; Ludtka, Gerard Michael; Avens, Larry R.

    A high-gradient permanent magnet apparatus for capturing paramagnetic particles, the apparatus comprising: (i) at least two permanent magnets positioned with like poles facing each other; (ii) a ferromagnetic spacer separating the like poles; and (iii) a magnetizable porous filling material in close proximity to the at least two permanent magnets. Also described is a method for capturing paramagnetic particles in which a gas or liquid sample containing the paramagnetic particles is contacted with the high-gradient permanent magnet apparatus described above; wherein, during the contacting step, the gas or liquid sample contacts the magnetizable porous filling material of the high-gradient permanentmore » magnet apparatus, and at least a portion of the paramagnetic particles in the gas or liquid sample is captured on the magnetizable porous filling material.« less

  12. Porous silicon and diatoms micro-shells: an example of inverse biomimetic

    NASA Astrophysics Data System (ADS)

    De Tommasi, Edoardo; Rea, Ilaria; Rendina, Ivo; De Stefano, Luca

    2011-05-01

    Porous silicon (PSi) is by far a very useful technological platform for optical monitoring of chemical and biological substances and due to its peculiar physical and morphological properties it is worldwide used in sensing experiments. On the other hand, we have discovered a natural material, the micro-shells of marine diatoms, ubiquitous unicellular algae, which are made of hydrated amorphous silica, but, most of all, show geometrical structures made of complex patterns of pores which are surprisingly similar to those of porous silicon. Moreover, under laser irradiation, this material is photoluminescent and the photoluminescence is very sensitive to the surrounding atmosphere, which means that the material can act as a transducer. Starting from our experience on PSi devices, we explore the optical and photonic properties of marine diatoms micro-shells in a sort of inverse biomimicry.

  13. Microfluidic Foaming: A Powerful Tool for Tailoring the Morphological and Permeability Properties of Sponge-like Biopolymeric Scaffolds.

    PubMed

    Costantini, Marco; Colosi, Cristina; Jaroszewicz, Jakub; Tosato, Alessia; Święszkowski, Wojciech; Dentini, Mariella; Garstecki, Piotr; Barbetta, Andrea

    2015-10-28

    Ordered porous polymeric materials can be engineered to present highly ordered pore arrays and uniform and tunable pore size. These features prompted a number of applications in tissue engineering, generation of meta materials, and separation and purification of biomolecules and cells. Designing new and efficient vistas for the generation of ordered porous materials is an active area of research. Here we investigate the potential of microfluidic foaming within a flow-focusing (FF) geometry in producing 3D regular sponge-like polymeric matrices with tailored morphological and permeability properties. The challenge in using microfluidic systems for the generation of polymeric foams is in the high viscosity of the continuous phase. We demonstrate that as the viscosity of the aqueous solution increases, the accessible range of foam bubble fraction (Φb) and bubble diameter (Db) inside the microfluidic chip tend to narrow progressively. This effect limits the accessible range of geometric properties of the resulting materials. We further show that this problem can be rationally tackled by appropriate choice of the concentration of the polymer. We demonstrate that via such optimization, the microfluidic assisted synthesis of porous materials becomes a facile and versatile tool for generation of porous materials with a wide range of pore size and pore volume. Moreover, we demonstrate that the size of interconnects among pores-for a given value of the gas fraction-can be tailored through the variation of surfactant concentration. This, in turn, affects the permeability of the materials, a factor of key importance in flow-through applications and in tissue engineering.

  14. X-ray Micro-Tomography of Ablative Heat Shield Materials

    NASA Technical Reports Server (NTRS)

    Panerai, Francesco; Ferguson, Joseph; Borner, Arnaud; Mansour, Nagi N.; Barnard, Harold S.; MacDowell, Alastair A.; Parkinson, Dilworth Y.

    2016-01-01

    X-ray micro-tomography is a non-destructive characterization technique that allows imaging of materials structures with voxel sizes in the micrometer range. This level of resolution makes the technique very attractive for imaging porous ablators used in hypersonic entry systems. Besides providing a high fidelity description of the material architecture, micro-tomography enables computations of bulk material properties and simulations of micro-scale phenomena. This presentation provides an overview of a collaborative effort between NASA Ames Research Center and Lawrence Berkeley National Laboratory, aimed at developing micro-tomography experiments and simulations for porous ablative materials. Measurements are carried using x-rays from the Advanced Light Source at Berkeley Lab on different classes of ablative materials used in NASA entry systems. Challenges, strengths and limitations of the technique for imaging materials such as lightweight carbon-phenolic systems and woven textiles are discussed. Computational tools developed to perform numerical simulations based on micro-tomography are described. These enable computations of material properties such as permeability, thermal and radiative conductivity, tortuosity and other parameters that are used in ablator response models. Finally, we present the design of environmental cells that enable imaging materials under simulated operational conditions, such as high temperature, mechanical loads and oxidizing atmospheres.Keywords: Micro-tomography, Porous media, Ablation

  15. Porous composite with negative thermal expansion obtained by photopolymer additive manufacturing

    NASA Astrophysics Data System (ADS)

    Takezawa, Akihiro; Kobashi, Makoto; Kitamura, Mitsuru

    2015-07-01

    Additive manufacturing (AM) could be a novel method of fabricating composite and porous materials having various effective performances based on mechanisms of their internal geometries. Materials fabricated by AM could rapidly be used in industrial application since they could easily be embedded in the target part employing the same AM process used for the bulk material. Furthermore, multi-material AM has greater potential than usual single-material AM in producing materials with effective properties. Negative thermal expansion is a representative effective material property realized by designing a composite made of two materials with different coefficients of thermal expansion. In this study, we developed a porous composite having planar negative thermal expansion by employing multi-material photopolymer AM. After measurement of the physical properties of bulk photopolymers, the internal geometry was designed by topology optimization, which is the most effective structural optimization in terms of both minimizing thermal stress and maximizing stiffness. The designed structure was converted to a three-dimensional stereolithography (STL) model, which is a native digital format of AM, and assembled as a test piece. The thermal expansions of the specimens were measured using a laser scanning dilatometer. Negative thermal expansion corresponding to less than -1 × 10-4 K-1 was observed for each test piece of the N = 3 experiment.

  16. Effect of Hydrodynamics on Particle Transport in Saturated Fractures: Experimental and Simulation Results

    NASA Astrophysics Data System (ADS)

    Cianflone, S.; Lakhian, V.; Dickson, S. E.

    2014-12-01

    Approximately one third of Canadians and Americans use groundwater as their source of drinking water. Porous media aquifers typically provide significant filtration of particulate contaminants (e.g., viruses, bacteria, protozoa). Fractured media, however, does not provide the same degree of filtration, and in fact often acts as a pathway for particulates to migrate, typically at much greater velocities than in porous media. Fractured aquifers, therefore, are significantly more vulnerable to particulate contamination than unconsolidated porous media. Thus, understanding in the mechanisms of particle migration and retention in fractures is important for the protection and management of these drinking water sources. The purpose of this work was to investigate the role of hydrodynamics on particle transport in saturated, variable aperture fractures. A 2D fracture was randomly generated with an average aperture of approximately 2mm. The fracture was inscribed into pieces of poly(methyl methacrylate), thus creating a pseudo-2D fracture (the xy fracture domain is invariant in z). Transport experiments using fluorescent microspheres (0.05 um, 0.5 um, and 0.75 um) were performed at 2.6 m/day, 26 m/day and 113 m/day and the resulting breakthrough curves were measured. These breakthrough curves included various shoulders and artifacts that were repeatable and could be used to evaluate the quality of a model. COMSOL Multiphysics, was used to generate an average flow field through the 2D fracture by numerically solving the steady-state Navier-Stokes equation. In order to have a 3D realization of the flow field, a parabolic flow regime was assumed in the z-axis and used to scale the average flow field. Random walk particle tracking was utilized to generate breakthrough curves; however, the Brownian motion and local fluid shear mechanisms needed to be considered in addition to the standard movement of particles via the local flow field in order to appropriately model the experimental results. These results suggest that local hydrodynamics are important in defining the transport of particles through a fracture. We plan to discuss further applications, general statistics, and particle retention in fractures due to hydrodynamics and ultimately the role of fracture geometry in particle transport.

  17. The abrupt installation of the euxinic environment as reflected by the unconsolidated sediments of the western slope of the Black Sea off the Romanian shore

    NASA Astrophysics Data System (ADS)

    Duliu, Octavian G.; Oaie, Gheorghe; Bojar, Ana-Voica; Zinicovscaia, Inga; Culicov, Otilia-Ana; Frontasyeva, Marina V.; Gradinaru, Janet

    2016-04-01

    A 4,5 m long core containing unconsolidated sediments collected at a depth of 500 m on the western slope of the Black Sea, off Romanian shore was analyzed by Computed Tomography (CT), X-ray Diffraction (XRD), X-ray Fluorescence (XRF) and Instrumental Neutron Activation Analysis (INAA) in order to investigate the changes in the Black Sea environment during the past 10.5 - 12 ky. The most relevant information regarding unconsolidated sediments was furnished by the CT images, clearly indicating the moment when the euxinic environment settled on this sector of the Black Sea, presumably 2.7 ky ago. This event is represented by the sedimentation of a coccolithic mud consisting of alternation of dark and light thin laminae composed of terigenous and respectively coccoliths rich material. This type of mud is characteristic for the sedimentary unit 1, filling the uppermost 50 cm of the core. The observation was confirmed by subsequent XRF and INAA determinations, which show a high content of calcium carbonate related to accumulation of Emilliania huxley coccoliths as well as of minor elements such as iron, molybdenum and uranium, a typical characteristic of euxinic environment. For instance, the average content of Mo and U is 28 and respectively 4 time higher than the corresponding content of the Upper Continental Core (UCC), while the Fe/Al ratio is around 0.52. Moreover, the average chondrite normalized Ce content of sedimentary unite 1 is 1.37 ± 0.17, slightly higher than 1.22, the characteristic value for the UCC. The Ce data indicate a weak positive anomaly, characteristic also for an euxinic reducing environment. All these investigations confirm the abrupt installation at a depth of 500 m of an euxinic environment on the western slope of the Black Sea, euxinic environment persisting to present time.

  18. Imidazolium salt-modified porous hypercrosslinked polymers for synergistic CO2 capture and conversion.

    PubMed

    Wang, Jinquan; Sng, Waihong; Yi, Guangshun; Zhang, Yugen

    2015-08-04

    A new type of imidazolium salt-modified porous hypercrosslinked polymer (BET surface area up to 926 m(2) g(-1)) was reported. These porous materials exhibited good CO2 capture capacities (14.5 wt%) and catalytic activities for the conversion of CO2 into various cyclic carbonates under metal-free conditions. The synergistic effect of CO2 capture and conversion was observed.

  19. Method for removing particulate matter from a gas stream

    DOEpatents

    Postma, Arlin K.

    1984-01-01

    Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

  20. Cratering at the Icy Satellites: Experimental Insights

    NASA Astrophysics Data System (ADS)

    Bruck Syal, M.; Schultz, P. H.

    2013-12-01

    Impact cratering processes play a central role in shaping the evolution of icy satellites and in guiding interpretations of various geologic features at these bodies. Accurate reconstruction of icy satellite histories depends in large part upon observed impact crater size-frequency distributions. Determining the extent of impact-induced thermal processing and the retention rates for impact-delivered materials of interest, e.g. organics, at these outer solar system moons is of fundamental importance for assessing their habitability and explaining differing geophysical histories. Hence, knowledge of how the impact process operates in ices or ice-rich materials is critically important. Recent progress in the development of water equations of state, coupled with increasingly efficient 3-D hydrocode calculations, has been used to construct careful numerical studies of melt and vapor generation for water ice targets. Complementary to this approach is experimental work to constrain the effects of differing ice target conditions, including porosity, rock mass fraction, and impact angle. Here we report on results from hypervelocity impact experiments (v~5.5 km/s) into water ice targets, performed at the NASA Ames Vertical Gun Range (AVGR). The setup at the AVGR allows for the use of particulate targets, which is useful for examining the effects of target porosity. Photometry and geophysical modeling both suggest that regolith porosity at the icy satellites is significant. We use a combination of half-space and quarter-space geometries, enabling analysis of the impact-generated vapor plume (half-space geometry), along with shock wave and transient crater growth tracking in a cross-sectional view (quarter-space geometry). Evaluating the impact-generated vapor from porous (φ = 0.5) and non-porous water ice targets provides an extension to previously published vapor production results for dolomite and CO2 ice targets. For the case of a 90 degree impact into porous ice, we calculate that 0.6% of the initial kinetic energy of the impactor is partitioned into the internal energy of the vapor plume. This is slightly higher than values determined in prior studies for non-porous CO2 ice (0.2%) [Schultz, 1996]. As CO2 ice possesses a lower vaporization temperature than water ice, this effect strongly suggests a role for porosity in enhancing vaporization. This is expected, as the compaction of porous materials performs additional, irreversible PdV work on the target, causing enhanced partitioning of kinetic energy into internal energy. At oblique impact angles, plume morphology changes dramatically while vaporization is enhanced. Comparing shock wave velocity attenuation in porous materials, including mixes of materials (e.g., quartz sand and porous ice), to numerical results obtained from shock physics codes such as CTH, provides insight into how impacts into porous ice-rich materials can be most accurately numerically modeled.

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