Sample records for underground toxic material

  1. Biodegradation of roxarsone by a bacterial community of underground water and its toxic impact.

    PubMed

    Mafla, S; Moraga, R; León, C G; Guzmán-Fierro, V G; Yañez, J; Smith, C T; Mondaca, M A; Campos, V L

    2015-08-01

    Roxarsone is included in chicken food as anticoccidial and mainly excreted unchanged in faeces. Microorganisms biotransform roxarsone into toxic compounds that leach and contaminate underground waters used for human consumption. This study evaluated roxarsone biotransformation by underground water microorganisms and the toxicity of the resulting compounds. Underground water from an agricultural field was used to prepare microcosms, containing 0.05 mM roxarsone, and cultured under aerobic or anaerobic conditions. Bacterial communities of microcosms were characterized by PCR-DGGE. Roxarsone degradation was measured by HPLC/HG/AAS. Toxicity was evaluated using HUVEC cells and the Toxi-ChromoTest kit. Roxarsone degradation analysis, after 15 days, showed that microcosms of underground water with nutrients degraded 90 and 83.3% of roxarsone under anaerobic and aerobic conditions, respectively. Microcosms without nutrients degraded 50 and 33.1% under anaerobic and aerobic conditions, respectively. Microcosms including nutrients showed more roxarsone conversion into toxic inorganic arsenic species. DGGE analyses showed the presence of Proteobacteria, Firmicutes, Actinobacteria, Planctomycetes and Spirochaetes. Toxicity assays showed that roxarsone biotransformation by underground water microorganisms in all microcosms generated degradation products toxic for eukaryotic and prokaryotic cells. Furthermore, toxicity increased when roxarsone leached though a soil column and was further transformed by the bacterial community present in underground water. Therefore, using underground water from areas where roxarsone containing manure is used as fertilizer might be a health risk.

  2. 30 CFR 57.4761 - Underground shops.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and... toxic gases from a fire originating in an underground shop where maintenance work is routinely done on...

  3. STATE-OF-THE-ART PROCEDURES AND EQUIPMENT FOR INTERNAL INSPECTION OF UNDERGROUND STORAGE TANKS

    EPA Science Inventory

    Preventing leaks from underground storage tanks is of paramount importance in this decade as environmental resources are seriously threatened by the release of toxic substances and costs of reparation are exorbitant. Inspecting underground storage tanks is one action that helps p...

  4. Laboratory-scale bioremediation of oil-contaminated soil of Kuwait with soil amendment materials.

    PubMed

    Cho, B H; Chino, H; Tsuji, H; Kunito, T; Nagaoka, K; Otsuka, S; Yamashita, K; Matsumoto, S; Oyaizu, H

    1997-10-01

    A huge amount of oil-contaminated soil remains unremediated in the Kuwait desert. The contaminated oil has the potentiality to cause pollution of underground water and to effect the health of people in the neighborhood. In this study, laboratory scale bioremediation experiments were carried out. Hyponex (Hyponex, Inc.) and bark manure were added as basic nutrients for microorganisms, and twelve kinds of materials (baked diatomite, microporous glass, coconut charcoal, an oil-decomposing bacterial mixture (Formula X from Oppenheimer, Inc.), and eight kinds of surfactants) were applied to accelerate the biodegradation of oil hydrocarbons. 15% to 33% of the contaminated oil was decomposed during 43 weeks' incubation. Among the materials tested, coconut charcoal enhanced the biodegradation. On the contrary, the addition of an oil-decomposing bacterial mixture impeded the biodegradation. The effects of the other materials were very slight. The toxicity of the biodegraded compounds was estimated by the Ames test and the tea pollen tube growth test. Both of the hydrophobic (dichloromethane extracts) and hydrophilic (methanol extracts) fractions showed a very slight toxicity in the Ames test. In the tea pollen tube growth test, the hydrophobic fraction was not toxic and enhanced the growth of pollen tubes.

  5. 30 CFR 57.4760 - Shaft mines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., but without an insulation core, are acceptable if an automatic sprinkler or deluge system is installed... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control... following means to control the spread of fire, smoke, and toxic gases underground in the event of a fire...

  6. Underground Storage Tanks on Indian Lands. Education Moderates an Environmental Threat.

    ERIC Educational Resources Information Center

    Hillger, Robert W.; Small, Matthew C.

    1992-01-01

    Describes problems related to old underground storage tanks (USTs) that may leak toxic contents, focusing on relevance for American Indian reservations. Discusses design, installation, and upgrading of UST systems; federal definitions and regulations; leak detection; legal responsibility; and education for public awareness. Includes Environmental…

  7. Pb uptake and toxicity to Iris halophila tested on Pb mine tailing materials.

    PubMed

    Han, Yulin; Zhang, Lili; Yang, Yongheng; Yuan, Haiyan; Zhao, Jiuzhou; Gu, Jiguang; Huang, Suzhen

    2016-07-01

    Pb tolerant mechanisms, plant physiological response and Pb sub-cellular localization in the root cells of Iris halophila were studied in sand culture and the Pb mine tailings. Results showed that the activities of superoxide dismutase (SOD) and peroxidase (POD) in the underground parts and the activity of catalase (CAT) in the aboveground and underground parts increased as Pb level was enhanced. Glutathione (GSH) and ascorbic acid (AsA) contents increased by Pb treatments. Pb deposits were found in the middle cell walls or along the inner side of epibiotic protoplasm of some cells which accumulated a large quantity of Pb and died. The dry weights (DWs) of aboveground parts under all Pb tailings treatments decreased insignificantly, while the DW of the underground parts growing in the pure Pb tailings decreased significantly. Pb, Cu, Cd, and Zn contents increased significantly as the levels of Pb tailings were enhanced and Pb contents in the aboveground and underground parts reached 64.75 and 751.75 μg/g DW, respectively, at pure Pb tailings treatment. The results indicated that I. halophila is a promising plant in the phytoremediation of Pb contaminated environment. Some antioxidant enzymes, antioxidants and compartmentalization of Pb were played major roles in Pb tolerance of I. halophila. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. 30 CFR 717.15 - Disposal of excess rock and earth materials on surface areas.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ENFORCEMENT, DEPARTMENT OF THE INTERIOR INITIAL PROGRAM REGULATIONS UNDERGROUND MINING GENERAL PERFORMANCE... materials produced from an underground mine and not disposed in underground workings or used in backfilling...

  9. Basic features of waste material storage in underground space in relation to geomechanics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Konecny, P.

    1994-12-31

    It is logical to consider utilizing underground cavities for waste material disposal because, during mining, great volumes of rock materials are extracted, and underground hollow areas and communicating workings are created that can, in general, be utilized for waste disposal. Additionally, in many cases, underground waste disposal favorably supports mining process technology (for instance, application of power plant fly ash and preparation plant tailings as hardened backfill). However, it is necessary to give particular attention to the preparation, operation, and isolation of underground tip areas; errors and, in extreme cases, emergencies in underground tips are generally more difficult to dealmore » with than those in surface tips. A tip place constructed underground becomes part of the rock massif; therefore, all natural laws that rule the rock massif must be respected. Of course, such an approach requires knowledge of processes and natural regularities that will occur in rock strata where tip places have been constructed. Such knowledge is gained through familiarity with contemporary geomechanical science. The paper discusses basic geomechanical principles of underground waste disposal; geomechanical aspects of rock massif evaluation in view of waste material storage in mine workings; and plans for an experimental project for waste disposal in the Dul Ostrava underground mine.« less

  10. Method for making generally cylindrical underground openings

    DOEpatents

    Routh, J.W.

    1983-05-26

    A rapid, economical and safe method for making a generally cylindrical underground opening such as a shaft or a tunnel is described. A borehole is formed along the approximate center line of where it is desired to make the underground opening. The borehole is loaded with an explodable material and the explodable material is detonated. An enlarged cavity is formed by the explosive action of the detonated explodable material forcing outward and compacting the original walls of the borehole. The enlarged cavity may be increased in size by loading it with a second explodable material, and detonating the second explodable material. The process may be repeated as required until the desired underground opening is made. The explodable material used in the method may be free-flowing, and it may be contained in a pipe.

  11. 75 FR 52978 - Submission for OMB Review; Comment Request

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-30

    ... collection. Title of Collection: Program to Prevent Smoking Underground and in Hazardous Surface Areas. OMB... smoking or carrying smoking materials underground or in places where there is a fire or explosion hazard... persons from carrying smoking materials, matches, or lighters underground and to prevent smoking in...

  12. Review of toxicity studies performed on an underground coal gasification condensate water

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barker, F.P.

    1987-09-01

    Three studies related to the toxicity of underground coal gasification (UCG) waters have bee conducted: (1) toxicity study of UCG water and its fractions as determined by the Microtox test, (2) toxicity study of biotreated UCG water as determined by the Microtox test, and (3) toxicity study of UCG water to macroinvertebrates. The results of these studies are summarized herein. The gas condensate water from the UCG process is extremely toxic as determined by assays with photoluminescent bacteria (Microtox), benthic (bottom-dwelling) macroinvertebrates (mayflies), and Daphnia magna (water flea). Microtox bioassays reveal that the toxic components of the water reside inmore » both the organophilic and hydrophilic fractions, although the organophilic fraction is notably more toxic. A sequential treatment process reduced the toxicity of the UCG water, as measured by the Microtox test. Solvent extraction (to remove phenols) followed by ammonia stripping yielded a less toxic water. Additional treatment by activated sludge further reduced toxicity. Finally, the addition of powdered activated carbon to the activated sludge yielded the least toxic water. A bioassay technique was developed for lotic (running water) macroinvertebrates (Drunella doddsi and Iron longimanus). The toxicity results were compared with results from the traditional test animal, Daphnia magna. Short-term exposures to the UCG waters were more toxic to Daphnia magna than to Drunella doddsi or Iron longimanus, although the toxicity values begin to merge with longer test exposure. The greater toxicity seems to be related to a thinner exoskeleton. 26 refs., 2 figs., 6 tabs.« less

  13. Indiana Underground Railroad Folklore: Western Route and Daviess County.

    ERIC Educational Resources Information Center

    Shelton, Lois G.

    Materials for teaching a unit about the Underground Railroad (the system set up to assist fleeing, runaway slaves heading north) in Indiana are presented. Specifically, the Western Route that passed through Daviess County in Indiana is examined. The materials provide background on the Underground Railroad and the Western Route, plans for teaching…

  14. 30 CFR 57.6960 - Mixing of explosive material.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Mixing of explosive material. 57.6960 Section... General Requirements-Underground Only § 57.6960 Mixing of explosive material. (a) The mixing of... to the hazards associated with the mixing of the bulk explosive material underground. (b) Storage...

  15. 30 CFR 57.6960 - Mixing of explosive material.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Mixing of explosive material. 57.6960 Section... General Requirements-Underground Only § 57.6960 Mixing of explosive material. (a) The mixing of... to the hazards associated with the mixing of the bulk explosive material underground. (b) Storage...

  16. 30 CFR 57.6960 - Mixing of explosive material.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Mixing of explosive material. 57.6960 Section... General Requirements-Underground Only § 57.6960 Mixing of explosive material. (a) The mixing of... to the hazards associated with the mixing of the bulk explosive material underground. (b) Storage...

  17. 30 CFR 57.6960 - Mixing of explosive material.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Mixing of explosive material. 57.6960 Section... General Requirements-Underground Only § 57.6960 Mixing of explosive material. (a) The mixing of... to the hazards associated with the mixing of the bulk explosive material underground. (b) Storage...

  18. 30 CFR 57.6960 - Mixing of explosive material.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Mixing of explosive material. 57.6960 Section... General Requirements-Underground Only § 57.6960 Mixing of explosive material. (a) The mixing of... to the hazards associated with the mixing of the bulk explosive material underground. (b) Storage...

  19. Method and apparatus for the in situ decontamination of underground water with the aid of solar energy

    DOEpatents

    Bench, Thomas R.; McCann, Larry D.

    1989-01-01

    A method for the in situ decontamination of underground water containing -volatile contaminants comprising continuously contacting in situ underground water containing non-volatile contaminants with a liquid-absorbent material possessing high capillary activity, allowing the non-volatile contaminants to deposit in the material while the water moves upwardly through the material by capillary action, allowing substantially decontaminated water to be volatilized by impinging solar radiation, and then allowing the volatilized water to escape from the material into the atmosphere. An apparatus for the in situ decontamination of underground water containing non-volatile contaminants comprising at least one water-impermeable elongated conduit having an upper portion and first and second open ends and containing a homogeneous liquid-absorbent material possessing high capillary activity, means for supporting said conduit, and means for accelerating the escape of the volatilized decontamined water from the material, said means being detachably connected to the second end of the elongated conduit; wherein when underground water contaminated with non-volatile contaminants is continuously contacted in situ with the material contained in the first end of the conduit and the second end of the conduit is placed in contact with atmospheric air, non-volatile contaminants deposit in said material as the water moves upwardly through the material by capillary action, is then volatilized by impinging solar energy and escapes to the atmosphere.

  20. Love Canal: environmental and toxicological studies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kim, C.S.

    The New York State Department of Health has been involved at the Love Canal since 1978. The State has carried out numerous environmental and toxicological studies. The major purposes for these studies were to define how Love Canal contaminants might be escaping into the environment at large, what paths contaminant migration might take, and what toxicological effects Love Canal chemicals might have individually and together. Although underground contaminant migration was hypothesized along swales and underground utility bedding, these mechanisms have been proven not to be operative except for some migration along the utility bedding under Frontier Avenue. In general nomore » underground migration has occurred outside the confines of the three city blocks that contain the Love Canal referred to as the ''first ring''. Studies have been confused by apparent burial of waste materials in areas proximate but not directly connected to the Love Canal. Migration of Love Canal leachate has occurred through storm sewers. Love Canal contaminants have reached creeks to the north and the Niagara River to the south through storm sewer transport. In spite of finding 2, 3, 7, 8 tetrachlorodibenzoparadioxin (TCDD), toxicological studies in situ and through exposure to volatile components in Love Canal soils do not indicate unusual toxicity. Animal studies continue in an attempt to determine the teratogenic and fetotoxic potential of Love Canal chemicals under different routes of exposure.« less

  1. Underground waste barrier structure

    DOEpatents

    Saha, Anuj J.; Grant, David C.

    1988-01-01

    Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

  2. A Shallow Underground Laboratory for Low-Background Radiation Measurements and Materials Development

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aalseth, Craig E.; Bonicalzi, Ricco; Cantaloub, Michael G.

    Abstract: Pacific Northwest National Laboratory recently commissioned a new shallow underground laboratory, located at a depth of approximately 30 meters water-equivalent. This new addition to the small class of radiation measurement laboratories located at modest underground depths worldwide houses the latest generation of custom-made, high-efficiency, low-background gamma-ray spectrometers and gas proportional counters. This manuscript describes the unique capabilities present in the shallow underground laboratory; these include large-scale ultra-pure materials production and a suite of radiation detection systems. Reported data characterize the degree of background reduction achieved through a combination of underground location, graded shielding, and rejection of cosmic-ray events. Wemore » conclude by presenting measurement targets and future opportunities.« less

  3. Underground barrier construction apparatus with soil-retaining shield

    DOEpatents

    Gardner, Bradley M.; Smith, Ann Marie; Hanson, Richard W.; Hodges, Richard T.

    1998-01-01

    An apparatus for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment.

  4. Underground barrier construction apparatus with soil-retaining shield

    DOEpatents

    Gardner, B.M.; Smith, A.M.; Hanson, R.W.; Hodges, R.T.

    1998-08-04

    An apparatus is described for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment. 17 figs.

  5. Effect of type of explosives and physical-mechanical properties of explosive rock on formation of toxic gases in atmosphere of shafts

    NASA Technical Reports Server (NTRS)

    Mindeli, E. O.; Khudyakov, M. Y.

    1981-01-01

    The quality of toxic gases formed during explosive work in underground shafts depends upon the type of explosives and the conditions of explosion. Several types of explosives and rocks were examined. All remaining conditions were maintained the same (sandy-argillaceous stemming, electrical method of explosions, diameter of blast holes, and the direct triggering of charges).

  6. 30 CFR 57.6102 - Explosive material storage practices.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

  7. 30 CFR 57.6102 - Explosive material storage practices.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

  8. 30 CFR 57.6102 - Explosive material storage practices.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

  9. Ecotoxicity of waste water from industrial fires fighting

    NASA Astrophysics Data System (ADS)

    Dobes, P.; Danihelka, P.; Janickova, S.; Marek, J.; Bernatikova, S.; Suchankova, J.; Baudisova, B.; Sikorova, L.; Soldan, P.

    2012-04-01

    As shown at several case studies, waste waters from extinguishing of industrial fires involving hazardous chemicals could be serious threat primary for surrounding environmental compartments (e.g. surface water, underground water, soil) and secondary for human beings, animals and plants. The negative impacts of the fire waters on the environment attracted public attention since the chemical accident in the Sandoz (Schweizerhalle) in November 1986 and this process continues. Last October, special Seminary on this topic has been organized by UNECE in Bonn. Mode of interaction of fire waters with the environment and potential transport mechanisms are still discussed. However, in many cases waste water polluted by extinguishing foam (always with high COD values), flammable or toxic dangerous substances as heavy metals, pesticides or POPs, are released to surface water or soil without proper decontamination, which can lead to environmental accident. For better understanding of this type of hazard and better coordination of firemen brigades and other responders, the ecotoxicity of such type of waste water should be evaluated in both laboratory tests and in water samples collected during real cases of industrial fires. Case studies, theoretical analysis of problem and toxicity tests on laboratory model samples (e.g. on bacteria, mustard seeds, daphnia and fishes) will provide additional necessary information. Preliminary analysis of waters from industrial fires (polymer material storage and galvanic plating facility) in the Czech Republic has already confirmed high toxicity. In first case the toxicity may be attributed to decomposition of burned material and extinguishing foams, in the latter case it can be related to cyanides in original electroplating baths. On the beginning of the year 2012, two years R&D project focused on reduction of extinguish waste water risk for the environment, was approved by Technology Agency of the Czech Republic.

  10. 30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

  11. 30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

  12. 30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

  13. 30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

  14. Chemical and toxicological evaluation of underground coal gasification (UCG) effluents. The coal rank effect.

    PubMed

    Kapusta, Krzysztof; Stańczyk, Krzysztof

    2015-02-01

    The effect of coal rank on the composition and toxicity of water effluents resulting from two underground coal gasification experiments with distinct coal samples (lignite and hard coal) was investigated. A broad range of organic and inorganic parameters was determined in the sampled condensates. The physicochemical tests were supplemented by toxicity bioassays based on the luminescent bacteria Vibrio fischeri as the test organism. The principal component analysis and Pearson correlation analysis were adopted to assist in the interpretation of the raw experimental data, and the multiple regression statistical method was subsequently employed to enable predictions of the toxicity based on the values of the selected parameters. Significant differences in the qualitative and quantitative description of the contamination profiles were identified for both types of coal under study. Independent of the coal rank, the most characteristic organic components of the studied condensates were phenols, naphthalene and benzene. In the inorganic array, ammonia, sulphates and selected heavy metals and metalloids were identified as the dominant constituents. Except for benzene with its alkyl homologues (BTEX), selected polycyclic aromatic hydrocarbons (PAHs), zinc and selenium, the values of the remaining parameters were considerably greater for the hard coal condensates. The studies revealed that all of the tested UCG condensates were extremely toxic to V. fischeri; however, the average toxicity level for the hard coal condensates was approximately 56% higher than that obtained for the lignite. The statistical analysis provided results supporting that the toxicity of the condensates was most positively correlated with the concentrations of free ammonia, phenols and certain heavy metals. Copyright © 2014 Elsevier Inc. All rights reserved.

  15. Underground structures increasing the intrinsic vulnerability of urban groundwater: Sensitivity analysis and development of an empirical law based on a groundwater age modelling approach

    NASA Astrophysics Data System (ADS)

    Attard, Guillaume; Rossier, Yvan; Eisenlohr, Laurent

    2017-09-01

    In a previous paper published in Journal of Hydrology, it was shown that underground structures are responsible for a mixing process between shallow and deep groundwater that can favour the spreading of urban contamination. In this paper, the impact of underground structures on the intrinsic vulnerability of urban aquifers was investigated. A sensitivity analysis was performed using a 2D deterministic modelling approach based on the reservoir theory generalized to hydrodispersive systems to better understand this mixing phenomenon and the mixing affected zone (MAZ) caused by underground structures. It was shown that the maximal extent of the MAZ caused by an underground structure is reached approximately 20 years after construction. Consequently, underground structures represent a long-term threat for deep aquifer reservoirs. Regarding the construction process, draining operations have a major impact and favour large-scale mixing between shallow and deep groundwater. Consequently, dewatering should be reduced and enclosed as much as possible. The role played by underground structures' dimensions was assessed. The obstruction of the first aquifer layer caused by construction has the greatest influence on the MAZ. The cumulative impact of several underground structures was assessed. It was shown that the total MAZ area increases linearly with underground structures' density. The role played by materials' properties and hydraulic gradient were assessed. Hydraulic conductivity, anisotropy and porosity have the strongest influence on the development of MAZ. Finally, an empirical law was derived to estimate the MAZ caused by an underground structure in a bi-layered aquifer under unconfined conditions. This empirical law, based on the results of the sensitivity analysis developed in this paper, allows for the estimation of MAZ dimensions under known material properties and underground structure dimensions. This empirical law can help urban planners assess the area of influence of underground structures and protect urban strategic reservoirs.

  16. Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kerry L. Nisson

    2012-10-01

    This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, “Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.”

  17. Get on Board the Underground Railroad: A Sample Unit for Fifth-Grade History Students.

    ERIC Educational Resources Information Center

    Ferguson, Phyllis M.; Young, Terrell A.

    1996-01-01

    Reviews the materials and procedures used in a fifth-grade history unit on the Underground Railroad. The unit integrated a variety of teaching methods and materials making extensive use of historical literature, K-W-L (what we Know, what we Want to find out, what we Learned) charts, and activities aimed at different learning styles. (MJP)

  18. Device and method for producing a containment barrier underneath and around in-situ buried waste

    DOEpatents

    Gardner, Bradley M.; Smith, Ann M.; Hanson, Richard W.; Hodges, Richard T.

    1998-01-01

    An apparatus for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably on which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment.

  19. Some relevant parameters for assessing fire hazards of combustible mine materials using laboratory scale experiments

    PubMed Central

    Litton, Charles D.; Perera, Inoka E.; Harteis, Samuel P.; Teacoach, Kara A.; DeRosa, Maria I.; Thomas, Richard A.; Smith, Alex C.

    2018-01-01

    When combustible materials ignite and burn, the potential for fire growth and flame spread represents an obvious hazard, but during these processes of ignition and flaming, other life hazards present themselves and should be included to ensure an effective overall analysis of the relevant fire hazards. In particular, the gases and smoke produced both during the smoldering stages of fires leading to ignition and during the advanced flaming stages of a developing fire serve to contaminate the surrounding atmosphere, potentially producing elevated levels of toxicity and high levels of smoke obscuration that render the environment untenable. In underground mines, these hazards may be exacerbated by the existing forced ventilation that can carry the gases and smoke to locations far-removed from the fire location. Clearly, materials that require high temperatures (above 1400 K) and that exhibit low mass loss during thermal decomposition, or that require high heat fluxes or heat transfer rates to ignite represent less of a hazard than materials that decompose at low temperatures or ignite at low levels of heat flux. In order to define and quantify some possible parameters that can be used to assess these hazards, small-scale laboratory experiments were conducted in a number of configurations to measure: 1) the toxic gases and smoke produced both during non-flaming and flaming combustion; 2) mass loss rates as a function of temperature to determine ease of thermal decomposition; and 3) mass loss rates and times to ignition as a function of incident heat flux. This paper describes the experiments that were conducted, their results, and the development of a set of parameters that could possibly be used to assess the overall fire hazard of combustible materials using small scale laboratory experiments. PMID:29599565

  20. Some relevant parameters for assessing fire hazards of combustible mine materials using laboratory scale experiments.

    PubMed

    Litton, Charles D; Perera, Inoka E; Harteis, Samuel P; Teacoach, Kara A; DeRosa, Maria I; Thomas, Richard A; Smith, Alex C

    2018-04-15

    When combustible materials ignite and burn, the potential for fire growth and flame spread represents an obvious hazard, but during these processes of ignition and flaming, other life hazards present themselves and should be included to ensure an effective overall analysis of the relevant fire hazards. In particular, the gases and smoke produced both during the smoldering stages of fires leading to ignition and during the advanced flaming stages of a developing fire serve to contaminate the surrounding atmosphere, potentially producing elevated levels of toxicity and high levels of smoke obscuration that render the environment untenable. In underground mines, these hazards may be exacerbated by the existing forced ventilation that can carry the gases and smoke to locations far-removed from the fire location. Clearly, materials that require high temperatures (above 1400 K) and that exhibit low mass loss during thermal decomposition, or that require high heat fluxes or heat transfer rates to ignite represent less of a hazard than materials that decompose at low temperatures or ignite at low levels of heat flux. In order to define and quantify some possible parameters that can be used to assess these hazards, small-scale laboratory experiments were conducted in a number of configurations to measure: 1) the toxic gases and smoke produced both during non-flaming and flaming combustion; 2) mass loss rates as a function of temperature to determine ease of thermal decomposition; and 3) mass loss rates and times to ignition as a function of incident heat flux. This paper describes the experiments that were conducted, their results, and the development of a set of parameters that could possibly be used to assess the overall fire hazard of combustible materials using small scale laboratory experiments.

  1. IN VITRO CYTOTOXICITY OF BTEX METABOLITES IN HELA CELL LINES

    EPA Science Inventory

    Fuel leakage from underground storage tanks is a major source of groundwater contamination. Although the toxicity of regulated compounds such as benzene, toluene, ethylbenzene, and xylene (BTEX) are well recognized, the cytotoxicity of their metabolites has not been studied exte...

  2. Preparation of Gd Loaded Liquid Scintillator for Daya Bay Neutrino Experiment

    NASA Astrophysics Data System (ADS)

    Ya-yun, Ding; Zhi-yong, Zhang

    2010-05-01

    Gadolinium loaded liquid scintillator (Gd-LS) is an excellent target material for reactor antineutrino experiments. Ideal Gd-LS should have long attenuation length, high light yield, long term stability, low toxicity, and should be compatible with the material used to build the detector. We have developed a new Gd-LS recipe in which carboxylic acid 3,5,5-trimethylhexanoic acid is used as the complexing ligand to gadolinium, 2,5-diphenyloxazole (PPO) and 1,4-bis[2-methylstyryl]benzene (bis-MSB) are used as primary fluor and wavelength shifter, respectively. The scintillator base is linear alkyl benzene (LAB). Eight hundred liters of Gd-LS has been synthesized and tested in a prototype detector. Results show that the Gd-LS has high quality and is suitable for underground experiments in large quantity. Large scale production facility has been built. A full batch production of 4 t Gd-LS has been produced and monitored for several months. The production of 180 t Gd-LS will be carried out in the near future.

  3. Going Deep...Putting the Undergound Dimension to Use

    ScienceCinema

    Laughton, Chris

    2017-12-09

    Underground construction can offer durable and environmentally-sound solutions to many of societies more pressing needs. The talk will identify some common uses for underground space and discuss current construction techniques used to mine in soils and rock. Examples of successful underground construction projects will demonstrate the advantages that the underground site can offer. In addition, insight will be provided into the nature of the risks run when working with a construction material (the ground) that cannot be made to order, nor precisely defined by the investigative processes currently at our disposal.

  4. Environmental Remediation and Application of Nanoscale Zero-Valent Iron and Its Composites for the Removal of Heavy Metal Ions: A Review.

    PubMed

    Zou, Yidong; Wang, Xiangxue; Khan, Ayub; Wang, Pengyi; Liu, Yunhai; Alsaedi, Ahmed; Hayat, Tasawar; Wang, Xiangke

    2016-07-19

    The presence of heavy metals in the industrial effluents has recently been a challenging issue for human health. Efficient removal of heavy metal ions from environment is one of the most important issues from biological and environmental point of view, and many studies have been devoted to investigate the environmental behavior of nanoscale zerovalent iron (NZVI) for the removal of toxic heavy metal ions, present both in the surface and underground wastewater. The aim of this review is to show the excellent removal capacity and environmental remediation of NZVI-based materials for various heavy metal ions. A new look on NZVI-based materials (e.g., modified or matrix-supported NZVI materials) and possible interaction mechanism (e.g., adsorption, reduction and oxidation) and the latest environmental application. The effects of various environmental conditions (e.g., pH, temperature, coexisting oxy-anions and cations) and potential problems for the removal of heavy metal ions on NZVI-based materials with the DFT theoretical calculations and EXAFS technology are discussed. Research shows that NZVI-based materials have satisfactory removal capacities for heavy metal ions and play an important role in the environmental pollution cleanup. Possible improvement of NZVI-based materials and potential areas for future applications in environment remediation are also proposed.

  5. Device and method for producing a containment barrier underneath and around in-situ buried waste

    DOEpatents

    Gardner, B.M.; Smith, A.M.; Hanson, R.W.; Hodges, R.T.

    1998-08-11

    An apparatus is described for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably on which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment. 15 figs.

  6. 30 CFR 57.4160 - Underground electric substations and liquid storage facilities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Prohibitions/precautions/housekeeping § 57.4160... noncombustible materials with equivalent fire protection characteristics. ...

  7. Development of minimum standards for hardwoods used in producing underground coal mine timbers

    Treesearch

    Floyd G. Timson

    1978-01-01

    This note presents minimum standards for raw material used in the production of sawn, split, and round timbers for the underground mining industry. The standards are based on a summary of information gathered from many mine-timber producers.

  8. 30 CFR 57.4505 - Fuel lines to underground areas.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Section 57.4505 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire... shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire protection...

  9. 30 CFR 75.1702 - Smoking; prohibition.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Smoking; prohibition. 75.1702 Section 75.1702... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1702 Smoking; prohibition. [Statutory Provisions] No person shall smoke, carry smoking materials, matches, or lighters underground, or smoke in or...

  10. 30 CFR 75.1702 - Smoking; prohibition.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Smoking; prohibition. 75.1702 Section 75.1702... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1702 Smoking; prohibition. [Statutory Provisions] No person shall smoke, carry smoking materials, matches, or lighters underground, or smoke in or...

  11. 30 CFR 75.1702 - Smoking; prohibition.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Smoking; prohibition. 75.1702 Section 75.1702... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1702 Smoking; prohibition. [Statutory Provisions] No person shall smoke, carry smoking materials, matches, or lighters underground, or smoke in or...

  12. 30 CFR 75.1702 - Smoking; prohibition.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Smoking; prohibition. 75.1702 Section 75.1702... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1702 Smoking; prohibition. [Statutory Provisions] No person shall smoke, carry smoking materials, matches, or lighters underground, or smoke in or...

  13. 30 CFR 75.1702 - Smoking; prohibition.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Smoking; prohibition. 75.1702 Section 75.1702... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1702 Smoking; prohibition. [Statutory Provisions] No person shall smoke, carry smoking materials, matches, or lighters underground, or smoke in or...

  14. 76 FR 9375 - Proposed Extension of Existing Information Collection; Sealing of Abandoned Areas

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-17

    ... prevent potentially explosive or toxic gases from migrating into the active working areas of underground... behind the seal must be monitored to prevent methane from reaching the explosive range. Miners rely on... used; Enhance the quality, utility, and clarity of the information to be collected; and Minimize the...

  15. 30 CFR 75.1106-3 - Storage of liquefied and nonliquefied compressed gas cylinders; requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...; requirements. (a) Liquefied and nonliquefied compressed gas cylinders stored in an underground coal mine shall... falling material, contact with power lines and energized electrical equipment, heat from welding, cutting...

  16. Application of Paste Backfill in Underground Coal Fires

    NASA Astrophysics Data System (ADS)

    Masniyom, M.; Drebenstedt, C.

    2009-04-01

    Coal fires are known from different coalfields worldwide. China, India, USA, Australia, Indonesia and South Africa are the main countries affected by coal fires. The fires is thermally intensive and cause numerous sinkholes, large-scale subsidence, air pollution, global warming, loss of mining productivity and increasing safety risk. The Wuda Inner Mongolia coalfield has been selected as a possible test area for paste backfill. The traditional methods, executed by fire fighting teams, by covering the coalfire areas with soil, blasting burning coal outcrops and injecting water in the subsurface fire pockets are continuously improved and extended. Initiatives to introduce modern techniques, such as backfill placement at fracture and borehole, to cool down the burning coal and cut off the air supply. This study is to investigate backfill materials and techniques suited for underground coal fires. Laboratory tests were carried out on physical, chemical and mechanical properties of different backfill materials and mixtures thereof. Special attention was paid to materials generated as by-products and other cheaply available materials e.g. fly ash from power plants. There is a good chance that one of the different material mixtures investigated can be used as a technically and economically viable backfill for underground coal fires.

  17. 30 CFR 75.400 - Accumulation of combustible materials.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock... rock-dusted surfaces, loose coal, and other combustible materials, shall be cleaned up and not be...

  18. 30 CFR 75.400 - Accumulation of combustible materials.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock... rock-dusted surfaces, loose coal, and other combustible materials, shall be cleaned up and not be...

  19. 30 CFR 75.400 - Accumulation of combustible materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock... rock-dusted surfaces, loose coal, and other combustible materials, shall be cleaned up and not be...

  20. 30 CFR 75.400 - Accumulation of combustible materials.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock... rock-dusted surfaces, loose coal, and other combustible materials, shall be cleaned up and not be...

  1. 30 CFR 75.400 - Accumulation of combustible materials.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock... rock-dusted surfaces, loose coal, and other combustible materials, shall be cleaned up and not be...

  2. Preparation of Gd Loaded Liquid Scintillator for Daya Bay Neutrino Experiment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ding Yayun; Zhang Zhiyong

    2010-05-12

    Gadolinium loaded liquid scintillator (Gd-LS) is an excellent target material for reactor antineutrino experiments. Ideal Gd-LS should have long attenuation length, high light yield, long term stability, low toxicity, and should be compatible with the material used to build the detector. We have developed a new Gd-LS recipe in which carboxylic acid 3,5,5-trimethylhexanoic acid is used as the complexing ligand to gadolinium, 2,5-diphenyloxazole (PPO) and 1,4-bis[2-methylstyryl]benzene (bis-MSB) are used as primary fluor and wavelength shifter, respectively. The scintillator base is linear alkyl benzene (LAB). Eight hundred liters of Gd-LS has been synthesized and tested in a prototype detector. Results showmore » that the Gd-LS has high quality and is suitable for underground experiments in large quantity. Large scale production facility has been built. A full batch production of 4 t Gd-LS has been produced and monitored for several months. The production of 180 t Gd-LS will be carried out in the near future.« less

  3. 78 FR 64022 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Program To...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-25

    ... for OMB Review; Comment Request; Program To Prevent Smoking in Hazardous Areas of Underground Coal... Administration (MSHA) sponsored information collection request (ICR) titled, ``Program to Prevent Smoking in... prohibits a person from smoking or carrying smoking materials underground or in places where there is a fire...

  4. 78 FR 13747 - Railroad Safety: Advisory Notice Related to Railroad Accidents in Vicinity of Underground Pipelines

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-28

    ... underground natural gas transmission pipeline operated by Nicor Gas. The pipeline well exceeded Federal... had the gas pipeline been installed at the railroad crossing with only the minimum level of ground... resumption of service.'' On July 31, 2012, the Pipeline and Hazardous Materials Safety Administration (PHMSA...

  5. Iron speciation of airborne subway particles by the combined use of energy dispersive electron probe X-ray microanalysis and Raman microspectrometry.

    PubMed

    Eom, Hyo-Jin; Jung, Hae-Jin; Sobanska, Sophie; Chung, Sang-Gwi; Son, Youn-Suk; Kim, Jo-Chun; Sunwoo, Young; Ro, Chul-Un

    2013-11-05

    Quantitative energy-dispersive electron probe X-ray microanalysis (ED-EPMA), known as low-Z particle EPMA, and Raman microspectrometry (RMS) were applied in combination for an analysis of the iron species in airborne PM10 particles collected in underground subway tunnels. Iron species have been reported to be a major chemical species in underground subway particles generated mainly from mechanical wear and friction processes. In particular, iron-containing particles in subway tunnels are expected to be generated with minimal outdoor influence on the particle composition. Because iron-containing particles have different toxicity and magnetic properties depending on their oxidation states, it is important to determine the iron species of underground subway particles in the context of both indoor public health and control measures. A recently developed analytical methodology, i.e., the combined use of low-Z particle EPMA and RMS, was used to identify the chemical species of the same individual subway particles on a single particle basis, and the bulk iron compositions of airborne subway particles were also analyzed by X-ray diffraction. The majority of airborne subway particles collected in the underground tunnels were found to be magnetite, hematite, and iron metal. All the particles collected in the tunnels of underground subway stations were attracted to permanent magnets due mainly to the almost ubiquitous ferrimagnetic magnetite, indicating that airborne subway particles can be removed using magnets as a control measure.

  6. Correlation of the Rock Mass Rating (RMR) System with the Unified Soil Classification System (USCS): Introduction of the Weak Rock Mass Rating System (W-RMR)

    NASA Astrophysics Data System (ADS)

    Warren, Sean N.; Kallu, Raj R.; Barnard, Chase K.

    2016-11-01

    Underground gold mines in Nevada are exploiting increasingly deeper ore bodies comprised of weak to very weak rock masses. The Rock Mass Rating (RMR) classification system is widely used at underground gold mines in Nevada and is applicable in fair to good-quality rock masses, but is difficult to apply and loses reliability in very weak rock mass to soil-like material. Because very weak rock masses are transition materials that border engineering rock mass and soil classification systems, soil classification may sometimes be easier and more appropriate to provide insight into material behavior and properties. The Unified Soil Classification System (USCS) is the most likely choice for the classification of very weak rock mass to soil-like material because of its accepted use in tunnel engineering projects and its ability to predict soil-like material behavior underground. A correlation between the RMR and USCS systems was developed by comparing underground geotechnical RMR mapping to laboratory testing of bulk samples from the same locations, thereby assigning a numeric RMR value to the USCS classification that can be used in spreadsheet calculations and geostatistical analyses. The geotechnical classification system presented in this paper including a USCS-RMR correlation, RMR rating equations, and the Geo-Pick Strike Index is collectively introduced as the Weak Rock Mass Rating System (W-RMR). It is the authors' hope that this system will aid in the classification of weak rock masses and more usable design tools based on the RMR system. More broadly, the RMR-USCS correlation and the W-RMR system help define the transition between engineering soil and rock mass classification systems and may provide insight for geotechnical design in very weak rock masses.

  7. 77 FR 74879 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Explosive...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-18

    ... Underground Gassy Mines ACTION: Notice. SUMMARY: The Department of Labor (DOL) is submitting the Mine Safety... Materials and Blasting Units in Metal and Nonmetal Underground Gassy Mines,'' to the Office of Management... blasting capacity for some metal and nonmetal gassy mines, 30 CFR 57.22606(a) outlines the procedures for a...

  8. 78 FR 35054 - Proposed Collection; Comment Request; Program to Prevent Smoking in Hazardous Areas (Pertains to...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-11

    ...; Program to Prevent Smoking in Hazardous Areas (Pertains to Underground Coal Mines) AGENCY: Mine Safety and... Act), 30 U.S.C. 877(c), and 30 CFR 75.1702 prohibits persons from smoking or carrying smoking... carrying smoking materials, matches, or lighters underground and to prevent smoking in hazardous areas...

  9. The Use of Modified Bentonite for Removal of Aromatic Organics from Contaminated Soil.

    PubMed

    Gitipour; Bowers; Bodocsi

    1997-12-15

    This study investigates the clay-aromatic interactions with a view to the use of bentonite clay for binding benzene, toluene, ethylbenzene, and o-xylene (BTEX compounds) in contaminated soils. BTEX compounds are the most toxic aromatic constituents of gasoline present in many underground storage tanks. Modified (organophilic) and ordinary bentonites are used to remove these organics. The organophilic bentonites are prepared by replacing the exchangeable inorganic cations present in bentonite particles with a quaternary ammonium salt. Various clay-to-soil ratios were applied to determine the efficiency of the modified bentonite in enhancing the cement-based solidification/stabilization (S/S) of BTEX contaminated soils. Toxicity characteristics leaching procedure (TCLP) tests were performed on soil samples to evaluate the leaching of the organics. In addition, X-ray diffraction analyses were conducted to assess the changes in the basal spacing of the clays as a result of their interaction with BTEX compounds. The findings of this study reveal that organophilic bentonite can act as a successful adsorbent for removing the aromatic organics from contaminated soil. Thus, this material is viable for enhancing the performance of cement-based S/S processes, as an adsorbent for petroleum spills, and for landfill liners and slurry walls. Copyright 1997 Academic Press.

  10. Shotcrete for Expedient Structural Repair

    DTIC Science & Technology

    1991-12-01

    pp. 29-44. Selmer - Olsen , R., "Examples of the Behavior of Shotcrete Linings Underground," Proceedings, Shotcrete for Ground Support, The Engineering... Selmer - Olsen , R. PAPER TITLE: Examples of the Behavior of Shotcrete Linings Underground DESCRIPTIVE TITLE NOTE: -0- BOOK/REPORT TITLE: Proceedings...prestressed tanks, thin overlays over structural materials, repair of concrete deteriorated by fire or earthquake, rock slope stabilization, and

  11. The relationship between environmental parameters of saline and underground karst - patients with different diseases in the course of speleotherapy - anthropogenic effect - keeping intact the underground environment and curative properties.

    NASA Astrophysics Data System (ADS)

    Simionca, Iu.; Hoteteu, M.; Chonka, Ia.; Slavik, P.; Kubas, J.; Grudnicki, N.

    2009-04-01

    One of the non-pharmacological therapy in patients with bronchial asthma (AB) and other BPOC is speleotherapy (ST), recognized as a complementary therapy. The curative effect of ST depends on geophysic structure of massive salt or karst, of mine or cave cavities, lack of noxes and toxic gas, also on the lack of the plant and microbial allergen, on the microclimatic parameters, sanitary and other parameters of the underground environment, on the mechanism of curative factors in these specific environments, on the medical particularities and disease specific speleotherapeutic methodology. An essential role they have environmental studies of underground cavities that own speleotherapeutic properties and use in medical and balneoclimatic tourism purposes. Among these studies are: - Air temperature, soil and salt layer; - Atmospheric pressure and the difference from the outside; - Relative humidity of the air underground; - Velocity of air currents; - Concentration of positive and negative air ions; - Particle size and concentration of saline aerosol; - Concentration of microorganisms, including pathogens, conditioning-pathogenic and saprophytic in air, soil saline and salt walls in rooms designed for speleotherapy; - Concentration of allergens; - Concentration of oxygen and carbon dioxide, the presence and concentration of ozone, the gaseous pollutants (NO2, SO2, hydrocarbons and derivatives of ozone); - Radioactivity (type, value), the presence and concentration of radon. Taking into consideration the possibility of anthropogenic effect on the underground salt or karst environment produced by patients with chronic inflammatory diseases, respiratory or skin allergic diseases is needed to assess the underground environmental sanitary parameters in various main locations (the entrance in the underground, the artificial or natural air flow; the sanatory area " - the location where patients or tourists are keeped for a period of 1-3 or more hours, bathroom) and the mechanism for keeping them intact. The data collected indicate the status of the underground salt or karst environment, allows the composition and aplication of the time period and speleotherapeutic procedures for patients with different pathologies in order to obtain speleotherapeutic positive effect or their use to balneoclimatic tourism, and also allow to assess anthropyc pollution and necessary measures for keeping intact of curative properties or their regeneration.

  12. 30 CFR 57.6102 - Explosive material storage practices.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Explosive material storage practices. 57.6102... Storage-Surface and Underground § 57.6102 Explosive material storage practices. (a) Explosive material... instructions and the date-plant-shift code are maintained with the product. Storage—Surface Only ...

  13. 30 CFR 57.6102 - Explosive material storage practices.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Explosive material storage practices. 57.6102... Storage-Surface and Underground § 57.6102 Explosive material storage practices. (a) Explosive material... instructions and the date-plant-shift code are maintained with the product. Storage—Surface Only ...

  14. 30 CFR 57.15001 - First aid materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false First aid materials. 57.15001 Section 57.15001 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE... Surface and Underground § 57.15001 First aid materials. Adequate first-aid materials, including stretchers...

  15. 30 CFR 57.6903 - Burning explosive material.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Burning explosive material. 57.6903 Section 57... General Requirements-Surface and Underground § 57.6903 Burning explosive material. If explosive material is suspected of burning at the blast site, persons shall be evacuated from the endangered area and...

  16. 30 CFR 57.6903 - Burning explosive material.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Burning explosive material. 57.6903 Section 57... General Requirements-Surface and Underground § 57.6903 Burning explosive material. If explosive material is suspected of burning at the blast site, persons shall be evacuated from the endangered area and...

  17. 30 CFR 57.6903 - Burning explosive material.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Burning explosive material. 57.6903 Section 57... General Requirements-Surface and Underground § 57.6903 Burning explosive material. If explosive material is suspected of burning at the blast site, persons shall be evacuated from the endangered area and...

  18. 30 CFR 57.6903 - Burning explosive material.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Burning explosive material. 57.6903 Section 57... General Requirements-Surface and Underground § 57.6903 Burning explosive material. If explosive material is suspected of burning at the blast site, persons shall be evacuated from the endangered area and...

  19. 30 CFR 57.6903 - Burning explosive material.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Burning explosive material. 57.6903 Section 57... General Requirements-Surface and Underground § 57.6903 Burning explosive material. If explosive material is suspected of burning at the blast site, persons shall be evacuated from the endangered area and...

  20. 30 CFR 57.6201 - Separation of transported explosive material.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Separation of transported explosive material... MINES Explosives Transportation-Surface and Underground § 57.6201 Separation of transported explosive material. Detonators shall not be transported on the same vehicle or conveyance with other explosives...

  1. 30 CFR 57.6201 - Separation of transported explosive material.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Separation of transported explosive material... MINES Explosives Transportation-Surface and Underground § 57.6201 Separation of transported explosive material. Detonators shall not be transported on the same vehicle or conveyance with other explosives...

  2. Effects of groundwater on radionuclides buried at the Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Martinez, B.A.; Maestas, S.; Thompson, J.L.

    A large fraction of the radioactive source from a nuclear test is confined to the cavity created by the event. A {open_quotes}melt glass{close_quotes} accumulates at the bottom of the cavity where the highest concentrations of refractory radionuclides (e.g., Zr-95, Eu-155, Pu-239) are found. Most of the movement of radionuclides underground at the Nevada Test Site occurs through the agency of moving groundwater. Results from samples that were taken from the cavity formed in 1981 by the underground test named Baseball indicate that radioactive materials have remained where they were deposited during the formation of the cavity and chimney. There maymore » not be a mechanism for radionuclides to migrate at this location due to small hydraulic gradients and a low hydraulic conductivity. The study done at this site offers further evidence that extensive migration of radioactive materials away from underground nuclear test sites does not occur in the absence of appreciable groundwater movement.« less

  3. UST/LUST Program Information

    EPA Pesticide Factsheets

    This asset includes an inventory of programmatic information, including policies and guidance, training course materials and Leaking Underground Storage Tanks (LUST) Trust Fund information. This documentation is used by states, territories, tribes and private parties to implement the Underground Storage Tank (UST) program. It also includes analysis of the laws and regulations that govern USTs, and policies and guidance for implementing the UST program developed by EPA in consultation with state and territorial UST programs.

  4. Transmutation studies at CEA in frame of the SPIN program objectives, results and future trends

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Salvatores, M.; Prunier, C.; Guerin, Y.

    1995-10-01

    In order to respond to the public concern about wastes and in particular the long-lived high level ones, a French law issued on December 30, 1991 identified the major objectives of research for the next fifteen years, before a new debate and possibly a decision on final wastes disposal in Parliament. These objectives are: (1) improvement of the wastes conditioning; (2) extraction and transmutation of the long-lived wastes in order to minimize their long term toxicity; (3) research performed in underground laboratories in order to characterize the capacity of geological structures to confine radioactive wastes (two sites have to bemore » selected for these underground laboratories, in concertation with the local population); (4) last, the study of conditioning and prolonged surface storage of wastes.« less

  5. 30 CFR 57.16017 - Hoisting heavy equipment or material.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Hoisting heavy equipment or material. 57.16017 Section 57.16017 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  6. 30 CFR 57.16017 - Hoisting heavy equipment or material.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Hoisting heavy equipment or material. 57.16017 Section 57.16017 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  7. 30 CFR 57.16017 - Hoisting heavy equipment or material.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Hoisting heavy equipment or material. 57.16017 Section 57.16017 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  8. 30 CFR 57.16017 - Hoisting heavy equipment or material.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Hoisting heavy equipment or material. 57.16017 Section 57.16017 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  9. 30 CFR 72.620 - Drill dust control at surface mines and surface areas of underground mines.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... collared and drilled wet, or other effective dust control measures shall be used, when drilling non-water-soluble material. Effective dust control measures shall be used when drilling water-soluble material. ...

  10. 30 CFR 72.620 - Drill dust control at surface mines and surface areas of underground mines.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... collared and drilled wet, or other effective dust control measures shall be used, when drilling non-water-soluble material. Effective dust control measures shall be used when drilling water-soluble material. ...

  11. 30 CFR 72.620 - Drill dust control at surface mines and surface areas of underground mines.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... collared and drilled wet, or other effective dust control measures shall be used, when drilling non-water-soluble material. Effective dust control measures shall be used when drilling water-soluble material. ...

  12. 30 CFR 72.620 - Drill dust control at surface mines and surface areas of underground mines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... collared and drilled wet, or other effective dust control measures shall be used, when drilling non-water-soluble material. Effective dust control measures shall be used when drilling water-soluble material. ...

  13. 30 CFR 72.620 - Drill dust control at surface mines and surface areas of underground mines.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... collared and drilled wet, or other effective dust control measures shall be used, when drilling non-water-soluble material. Effective dust control measures shall be used when drilling water-soluble material. ...

  14. A Fiber Bragg Grating-Based Monitoring System for Roof Safety Control in Underground Coal Mining

    PubMed Central

    Zhao, Yiming; Zhang, Nong; Si, Guangyao

    2016-01-01

    Monitoring of roof activity is a primary measure adopted in the prevention of roof collapse accidents and functions to optimize and support the design of roadways in underground coalmines. However, traditional monitoring measures, such as using mechanical extensometers or electronic gauges, either require arduous underground labor or cannot function properly in the harsh underground environment. Therefore, in this paper, in order to break through this technological barrier, a novel monitoring system for roof safety control in underground coal mining, using fiber Bragg grating (FBG) material as a perceived element and transmission medium, has been developed. Compared with traditional monitoring equipment, the developed, novel monitoring system has the advantages of providing accurate, reliable, and continuous online monitoring of roof activities in underground coal mining. This is expected to further enable the prevention of catastrophic roof collapse accidents. The system has been successfully implemented at a deep hazardous roadway in Zhuji Coal Mine, China. Monitoring results from the study site have demonstrated the advantages of FBG-based sensors over traditional monitoring approaches. The dynamic impacts of progressive face advance on roof displacement and stress have been accurately captured by the novel roadway roof activity and safety monitoring system, which provided essential references for roadway support and design of the mine. PMID:27775657

  15. Biological effect of Acidithiobacillus thiooxidans on some potentially toxic elements during alteration of SON 68 nuclear glass

    NASA Astrophysics Data System (ADS)

    Bachelet, M.; Crovisier, J. L.; Stille, P.; Vuilleumier, S.; Geoffroy, V.

    2009-04-01

    Although underground nuclear waste repositories are not expected to be favourable places for microbial activity, one should not exclude localized action of extremophilic bacteria on some materials involved in the storage concept. Among endogenous or accidentally introduced acidophiles, some are susceptible to lead to a locally drastic decreased in pH, with potential consequences on materials corrosion. Experiments were performed with Acidithiobacillus thiooxidans on 100-125 m french reference nuclear glass SON68 grains in a mineral medium under static conditions during 60 days at 25degC. Growth medium was periodically renewed and analyzed by ICP-AES and ICP-MS spectrometry for both major, trace and ultra-trace elements. Biofilm formation was evidenced by confocal laser microscopy, staining DNA with ethidium bromide and exopolysaccharides with calcofluor white. Biofilm thickness around material grains exceeded 20 m under the chosen experimental conditions. It can be noticed that while numerous studies on biofilm formation upon interaction between Acidithiobacillus ferrooxidans and materials are found in the literature, evidence for biofilm formation is still scarce for the case of the acidophilic bacterium A. thiooxidans. Presence of biofilm is a key parameter for material alteration at the solid/solution interface in biotic systems. Indeed, various constitutive elements of materials trapped in the polyanionic polymer of biofilm may also influence the alteration process. In particular, biofilm may reduce the alteration rate of materials by forming a protective barrier at their surface (Aouad et al., 2008). In this study, glass alteration rates, determined using strontium as tracer, showed that the progressive formation of a biofilm on the surface of glass has a protective effect against its alteration. Uranium and rare earth elements (REE) are efficiently trapped in the biogenic compartment of the system (exopolysaccharides + bacterial cells). Besides, the ratio biotic/abiotic concentrations of REE and U in the leachant decreases with increasing time which seems to indicate a good capacity of EPS for long term trapping of potentially toxic elements. Aouad G., Crovisier J.-L., Damidot D., Stille P., Hutchens E., Mutterer J., Meyer J.-M., and Geoffroy V. A. (2008) Interactions between municipal solid waste incinerator bottom ash and bacteria (Pseudomonas aeruginosa). Science of The Total Environment 393((2-3)), 385-393.

  16. Iron-nickel alloys as canister material for radioactive waste disposal in underground repositories

    NASA Astrophysics Data System (ADS)

    Apps, J. A.

    1982-09-01

    Canisters containing high-level radioactive waste must retain their integrity in an underground waste repository for at least one thousand years after burial (Nuclear Regulatory Commission, 1981). Since no direct means of verifying canister integrity is plausible over such a long period, indirect methods must be chosen. A persuasive approach is to examine the natural environment and find a suitable material which is thermodynamically compatible with the host rock under the environmental conditions with the host rock under the environmental conditions expected in a waste repository. Several candidates have been proposed, among them being iron-nickel alloys that are known to occur naturally in altered ultramafic rocks. The following review of stability relations among iron-nickel alloys below 3500 C is the initial phase of a more detailed evaluation of these alloys as suitable canister materials.

  17. Preparation of construction specifications, contract documents, field testing, educational materials, and course offerings for trenchless construction

    DOT National Transportation Integrated Search

    2005-10-01

    Trenchless technology offers methods by which underground utilities may be installed without damage to overlying pavement, if proper precautions are observed. In the past ten years, repeated improvements in technology, materials, and methods have adv...

  18. Safety management of an underground-based gravitational wave telescope: KAGRA

    NASA Astrophysics Data System (ADS)

    Ohishi, Naoko; Miyoki, Shinji; Uchiyama, Takashi; Miyakawa, Osamu; Ohashi, Masatake

    2014-08-01

    KAGRA is a unique gravitational wave telescope with its location underground and use of cryogenic mirrors. Safety management plays an important role for secure development and operation of such a unique and large facility. Based on relevant law in Japan, Labor Standard Act and Industrial Safety and Health Law, various countermeasures are mandated to avoid foreseeable accidents and diseases. In addition to the usual safety management of hazardous materials, such as cranes, organic solvents, lasers, there are specific safety issues in the tunnel. Prevention of collapse, flood, and fire accidents are the most critical issues for the underground facility. Ventilation is also important for prevention of air pollution by carbon monoxide, carbon dioxide, organic solvents and radon. Oxygen deficiency should also be prevented.

  19. Mining Security Pipe(TSM)with Underground GPS Global(RSPG)Escape Security Device in Underground Mining

    NASA Astrophysics Data System (ADS)

    Giménez, Rafael Barrionuevo

    2016-06-01

    TSM is escape pipe in case of collapse of terrain. The TSM is a passive security tool placed underground to connect the work area with secure area (mining gallery mainly). TSM is light and hand able pipe made with aramid (Kevlar), carbon fibre, or other kind of new material. The TSM will be placed as a pipe line network with many in/out entrances/exits to rich and connect problem work areas with another parts in a safe mode. Different levels of instrumentation could be added inside such as micro-led escape way suggested, temperature, humidity, level of oxygen, etc.). The open hardware and software like Arduino will be the heart of control and automation system.

  20. Reducing drinking water supply chemical contamination: risks from underground storage tanks.

    PubMed

    Enander, Richard T; Hanumara, R Choudary; Kobayashi, Hisanori; Gagnon, Ronald N; Park, Eugene; Vallot, Christopher; Genovesi, Richard

    2012-12-01

    Drinking water supplies are at risk of contamination from a variety of physical, chemical, and biological sources. Ranked among these threats are hazardous material releases from leaking or improperly managed underground storage tanks located at municipal, commercial, and industrial facilities. To reduce human health and environmental risks associated with the subsurface storage of hazardous materials, government agencies have taken a variety of legislative and regulatory actions--which date back more than 25 years and include the establishment of rigorous equipment/technology/operational requirements and facility-by-facility inspection and enforcement programs. Given a history of more than 470,000 underground storage tank releases nationwide, the U.S. Environmental Protection Agency continues to report that 7,300 new leaks were found in federal fiscal year 2008, while nearly 103,000 old leaks remain to be cleaned up. In this article, we report on an alternate evidence-based intervention approach for reducing potential releases from the storage of petroleum products (gasoline, diesel, kerosene, heating/fuel oil, and waste oil) in underground tanks at commercial facilities located in Rhode Island. The objective of this study was to evaluate whether a new regulatory model can be used as a cost-effective alternative to traditional facility-by-facility inspection and enforcement programs for underground storage tanks. We conclude that the alternative model, using an emphasis on technical assistance tools, can produce measurable improvements in compliance performance, is a cost-effective adjunct to traditional facility-by-facility inspection and enforcement programs, and has the potential to allow regulatory agencies to decrease their frequency of inspections among low risk facilities without sacrificing compliance performance or increasing public health risks. © 2012 Society for Risk Analysis.

  1. Effect of test conditions on relative toxicity rankings of fifteen materials

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Cumming, H. J.

    1977-01-01

    Fifteen materials were evaluated for relative toxicity of pyrolysis effluents, using different test conditions in the USF methodology. Wool fabrics were consistently among the most toxic materials, and polystyrene and polychloroprene flexible foam were consistently among the least toxic materials.

  2. Life cycle assessment of overhead and underground primary power distribution.

    PubMed

    Bumby, Sarah; Druzhinina, Ekaterina; Feraldi, Rebe; Werthmann, Danae; Geyer, Roland; Sahl, Jack

    2010-07-15

    Electrical power can be distributed in overhead or underground systems, both of which generate a variety of environmental impacts at all stages of their life cycles. While there is considerable literature discussing the trade-offs between both systems in terms of aesthetics, safety, cost, and reliability, environmental assessments are relatively rare and limited to power cable production and end-of-life management. This paper assesses environmental impacts from overhead and underground medium voltage power distribution systems as they are currently built and managed by Southern California Edison (SCE). It uses process-based life cycle assessment (LCA) according to ISO 14044 (2006) and SCE-specific primary data to the extent possible. Potential environmental impacts have been calculated using a wide range of midpoint indicators, and robustness of the results has been investigated through sensitivity analysis of the most uncertain and potentially significant parameters. The studied underground system has higher environmental impacts in all indicators and for all parameter values, mostly due to its higher material intensity. For both systems and all indicators the majority of impact occurs during cable production. Promising strategies for impact reduction are thus cable failure rate reduction for overhead and cable lifetime extension for underground systems.

  3. Relative toxicity of pyrolysis products of some materials used in home furnishings

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Furst, A.

    1976-01-01

    Seventy samples of cushioning and upholstery materials used in home furnishings were evaluated for relative toxicity by means of the USF/NASA toxicity screening test. The materials were variably toxic under pyrolysis conditions, and this test appeared suitable for discriminating among them on the bases of time to incapacitation and time to death. The addition of fire retardants to these materials to comply with flammability regulations either had no significant effect on toxicity, or resulted in a reduction in relative toxicity. The modification of materials to comply with California upholstered furniture flammability regulations appears to have resulted in desirable limitations on toxicity. Fifty percent of the 70 materials tested caused incapacitation earlier than did the materials in compliance, and 30 percent caused death earlier.

  4. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOEpatents

    Taylor, Robert T.; Jackson, Kenneth J.; Duba, Alfred G.; Chen, Ching-I

    1998-01-01

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

  5. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOEpatents

    Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

    1998-05-19

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

  6. Thermal surface characteristics of coal fires 1 results of in-situ measurements

    NASA Astrophysics Data System (ADS)

    Zhang, Jianzhong; Kuenzer, Claudia

    2007-12-01

    Natural underground coal fires are fires in coal seams occurring subsurface. The fires are ignited through a process named spontaneous combustion, which occurs based on a natural reaction but is usually triggered through human interaction. Coal mining activities expose coal to the air. This leads to the exothermal oxidation of the carbon in the coal with the air's oxygen to CO 2 and - under certain circumstances - to spontaneous combustion. Coal fires occur in many countries world wide - however, currently the Chinese coal mining industry faces the biggest problems with coal fires. Coal fires destroy the valuable resource coal and furthermore lead to many environmental degradation phenomena such as the deterioration of surrounding vegetation, land subsidence and the emission of toxic gasses (CO, N 2O). They additionally contribute to the emission of green house relevant gasses such as CO 2 and CH 4 to the atmosphere. In this paper we present thermal characteristics of coal fires as measured in-situ during a field campaign to the Wuda coal fire area in south-central Inner Mongolia, China. Thermal characteristics include temperature anomaly measurements at the surface, spatial surface temperature profiles of fire areas and unaffected background areas, diurnal temperature profiles, and temperature measurements inside of coal fire induced cracks in the overlying bedrock. For all the measurements the effects of uneven solar heating through influences of slope and aspect are considered. Our findings show that coal fires result in strong or subtle thermal surface anomalies. Especially the latter can easily be influenced by heating of the surrounding background material through solar influences. Temperature variation of background rocks with different albedo, slope, aspect or vegetation cover can substantially influence the detectability of thermal anomalies. In the worst case coal fire related thermal anomalies can be completely masked by solar patterns during the daytime. Thus, night-time analysis is the most suitable for thermal anomaly mapping of underground coal fires, although this is not always feasible. The heat of underground coal fires only progresses very slowly through conduction in the rock material. Anomalies of coal fires completely covered by solid unfractured bedrock are very weak and were only measured during the night. The thermal pattern of underground coal fires manifested on the surface during the daytime is thus the pattern of cracks and vents, which occur due to the volume loss underground and which support radiation and convective energy transport of hot gasses. Inside coal fire temperatures can hardly be measured and can only be recorded if the glowing coal is exposed through a wider crack in the overlaying bedrock. Direct coal fire temperatures measured ranged between 233 °C and 854 °C. The results presented can substantially support the planning of thermal mapping campaigns, analyses of coal fire thermal anomalies in remotely sensed data, and can provide initial and boundary conditions for coal fire related numerical modeling. In a second paper named "Thermal Characteristics of Coal Fires 2: results of measurements on simulated coal fires" [ Zhang J., Kuenzer C., Tetzlaff A., Oettl D., Zhukov B., Wagner W., 2007. Thermal Characteristics of Coal Fires 2: Result of measurements on simulated coal fires. Accepted for publication at Journal of Applied Geophysics. doi:10.1016/j.jappgeo.2007.08.003] we report about thermal characteristics of simulated coal fires simulated under simplified conditions. The simulated set up allowed us to measure even more parameters under undisturbed conditions — especially inside fire temperatures. Furthermore we could demonstrate the differences between open surface coal fires and covered underground coal fires. Thermal signals of coal fires in near range thermal remotely sensed imagery from an observing tower and from an airplane are presented and discussed.

  7. Development of an underground HPGe array facility for ultra low radioactivity measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sala, E.; Kang, W. G.; Kim, Y. D.

    Low Level Counting techniques using low background facilities are continuously under development to increase the possible sensitivity needed for rare physics events experiments. The CUP (Center for Underground Physics) group of IBS is developing, in collaboration with Canberra, a ultra low background instrument composed of two arrays facing each other with 7 HPGe detectors each. The low radioactive background of each detector has been evaluated and improved by the material selection of the detector components. Samples of all the building materials have been provided by the manufacturer and the contaminations had been measured using an optimized low background 100% HPGemore » with a dedicated shielding. The evaluation of the intrinsic background has been performed using MonteCarlo simulations and considering the contribution of each material with the measured contamination. To further reduce the background, the instrument will be placed in the new underground laboratory at YangYang exploiting the 700m mountain coverage and radon-free air supplying system. The array has been designed to perform various Ultra Low background measurements; the sensitivity we are expecting will allow not only low level measurements of Ra and Th contaminations in Copper or other usually pure materials, but also the search for rare decays. In particular some possible candidates and configurations to detect the 0νECEC (for example {sup 106}Cd and {sup 156}Dy) and rare β decays ({sup 96}Zr, {sup 180m}Ta , etc ) are under study.« less

  8. 30 CFR 57.6202 - Vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Vehicles. 57.6202 Section 57.6202 Mineral... and Underground § 57.6202 Vehicles. (a) Vehicles containing explosive material shall be— (1... operation. (b) Vehicles containing explosives shall have— (1) No sparking material exposed in the cargo...

  9. 30 CFR 57.6202 - Vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Vehicles. 57.6202 Section 57.6202 Mineral... and Underground § 57.6202 Vehicles. (a) Vehicles containing explosive material shall be— (1... operation. (b) Vehicles containing explosives shall have— (1) No sparking material exposed in the cargo...

  10. 30 CFR 57.6202 - Vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Vehicles. 57.6202 Section 57.6202 Mineral... and Underground § 57.6202 Vehicles. (a) Vehicles containing explosive material shall be— (1... operation. (b) Vehicles containing explosives shall have— (1) No sparking material exposed in the cargo...

  11. 30 CFR 57.6202 - Vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Vehicles. 57.6202 Section 57.6202 Mineral... and Underground § 57.6202 Vehicles. (a) Vehicles containing explosive material shall be— (1... operation. (b) Vehicles containing explosives shall have— (1) No sparking material exposed in the cargo...

  12. 30 CFR 57.6202 - Vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Vehicles. 57.6202 Section 57.6202 Mineral... and Underground § 57.6202 Vehicles. (a) Vehicles containing explosive material shall be— (1... operation. (b) Vehicles containing explosives shall have— (1) No sparking material exposed in the cargo...

  13. 30 CFR 75.1322 - Stemming boreholes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Stemming boreholes. 75.1322 Section 75.1322... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Explosives and Blasting § 75.1322 Stemming boreholes. (a) Only noncombustible material shall be used for stemming boreholes. (b) Stemming materials other than...

  14. 30 CFR 75.1322 - Stemming boreholes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Stemming boreholes. 75.1322 Section 75.1322... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Explosives and Blasting § 75.1322 Stemming boreholes. (a) Only noncombustible material shall be used for stemming boreholes. (b) Stemming materials other than...

  15. 30 CFR 75.1322 - Stemming boreholes

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Stemming boreholes 75.1322 Section 75.1322... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Explosives and Blasting § 75.1322 Stemming boreholes (a) Only noncombustible material shall be used for stemming boreholes. (b) Stemming materials other than...

  16. 30 CFR 75.1322 - Stemming boreholes

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Stemming boreholes 75.1322 Section 75.1322... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Explosives and Blasting § 75.1322 Stemming boreholes (a) Only noncombustible material shall be used for stemming boreholes. (b) Stemming materials other than...

  17. Accident Prevention and Diagnostics of Underground Pipeline Systems

    NASA Astrophysics Data System (ADS)

    Trokhimchuk, M.; Bakhracheva, Y.

    2017-11-01

    Up to forty thousand accidents occur annually with underground pipelines due to corrosion. The comparison of the methods for assessing the quality of anti-corrosion coating is provided. It is proposed to use the device to be tied-in to existing pipeline which has a higher functionality in comparison with other types of the devices due to the possibility of tie-in to the pipelines with different diameters. The existing technologies and applied materials allow us to organize industrial production of the proposed device.

  18. Quantum cryptography over underground optical fibers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hughes, R.J.; Luther, G.G.; Morgan, G.L.

    1996-05-01

    Quantum cryptography is an emerging technology in which two parties may simultaneously generated shared, secret cryptographic key material using the transmission of quantum states of light whose security is based on the inviolability of the laws of quantum mechanics. An adversary can neither successfully tap the key transmissions, nor evade detection, owing to Heisenberg`s uncertainty principle. In this paper the authors describe the theory of quantum cryptography, and the most recent results from their experimental system with which they are generating key material over 14-km of underground optical fiber. These results show that optical-fiber based quantum cryptography could allow secure,more » real-time key generation over ``open`` multi-km node-to-node optical fiber communications links between secure ``islands.``« less

  19. The Soil Is Alive!

    ERIC Educational Resources Information Center

    Science and Children, 1989

    1989-01-01

    Describes activities which demonstrate the abundance of organisms living underground. Provides outlined directions, lists of materials, and a soil ecosystem transparency for delving into the properties of soil. (RT)

  20. Simulation studies of muon-produced background events deep underground and consequences for double beta decay experiments

    NASA Astrophysics Data System (ADS)

    Massarczyk, Ralph; Majorana Collaboration

    2015-10-01

    Cosmic radiation creates a significant background for low count rate experiments. The Majorana demonstrator experiment is located at the Sanford Underground Research Facility at a depth of 4850ft below the surface but it can still be penetrated by cosmic muons with initial energies above the TeV range. The interaction of muons with the rock, the shielding material in the lab and the detector itself can produce showers of secondary particles, like fast neutrons, which are able to travel through shielding material and can produce high-energy γ-rays via capture or inelastic scattering. The energy deposition of these γ rays in the detector can overlap with energy region of interest for the neutrino-less double beta decay. Recent studies for cosmic muons penetrating the Majorana demonstrator are made with the Geant4 code. The results of these simulations will be presented in this talk and an overview of the interaction of the shower particles with the detector, shielding and veto system will be given. This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Nuclear Physics, the Particle Astrophysics Program of the National Science Foundation, and the Sanford Underground Research Facility. Supported by U.S. Department of Energy through the LANL/LDRD Program.

  1. 77 FR 20700 - Examinations of Work Areas in Underground Coal Mines for Violations of Mandatory Health or Safety...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-06

    ... safety standards related to ventilation, methane, roof control, combustible materials, rock dust, other... standards related to ventilation, methane, roof control, combustible materials, rock dust, other safeguards... and unsafe conditions, such as methane accumulations, water accumulations, and adverse roof conditions...

  2. 48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 2012) (a) Definitions. As used in...

  3. 48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 1993) (a) Definitions. As used in...

  4. 48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 2012) (a) Definitions. As used in...

  5. 48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 1993) (a) Definitions. As used in...

  6. New cosmic rays experiments in the underground laboratory of IFIN-HH from Slanic Prahova, Romania

    NASA Astrophysics Data System (ADS)

    Mitrica, Bogdan; Stanca, Denis; Brancus, Iliana; Margineanu, Romul; Blebea-Apostu, Ana-Maria; Gomoiu, Claudia; Saftoiu, Alexandra; Toma, Gabriel; Rebel, Heinigerd; Haungs, Andreas; Sima, Octavian; Gherghel-Lascu, Alexandru; Niculescu-Oglinzanu, Mihai

    2015-02-01

    Since 2006 a modern laboratory has been developed by IFIN-HH in the underground of Slanic Prahova salt ore. This work presents a short review of previous scientific activities performed in the underground laboratory, in parallel with some plans for the future. A mobile detector for cosmic muon flux measurements has been set up at IFIN-HH, Romania. The device is used to measure the muon flux on different locations at the surface and underground and it consists of two detection layers, each one including four large scintillator plates. A new rotatable detector for measurements of the directional variation of the muon flux has been designed and it is presently under preliminary tests. Built from four layers of sensitive material and using for collecting the signals and directing them to the micro PMTs a new technique, through optical fibers instead wave length shifters, it allows an easy discrimination of the moun flux on the arrival directions of muons. Combining the possibility to rotate and the directionality properties, the underground muon detector is acting like a muon tomography device, being able to scan, using cosmic muons, the rock material above the detector. In parallel new detection system based on SiPM will be also installed in the following weeks. It should be composed by four layers, each layer consisting in 4 scintillator plates what we consider in the following as a module of detection. For this purpose, first two scintillator layers, with the optical fibers positioned on perpendicular directions are put in coincidence with other two layers, 1 m distance from the first two, with similar optical fiber arrangement, thus allowing reconstructing muon trajectory. It is intended also to design and construct an experimental device for the investigation of such radio antennas and the behavior of the signal in rock salt at the Slanic salt mine in Romania. Another method to detect high energy neutrinos is based on the detection of secondary particles resulting from the interaction with the salt massive. We intent to design and construct a 3D array in the underground of Slanic Prahova salt ore.

  7. Assessment and quantification of plastics waste generation in major 60 cities of India.

    PubMed

    Nalini, R; Srinivasulu, B; Shit, Subhas C; Nigam, Suneel Kumar; Akolkar, A B; Dwivedfi, R K

    2013-04-01

    Polymers or plastics materials registered rapid growth in 1970s, 1980s and 1990s at the rate of 2-2.5 times the GDP growth in India. The demand for plastic raw material got more than doubled from 3.3 Million Metric Ton to 6.8 Million Metric Tons in 2010 attributed mainly to rapid urbanization, spread of retail chains, plastics based packaging from grocery to food and vegetable products to cosmetics and consumer items. Plastics packages have its merits over many of conventional materials in the related sector but unless they are collected back effectively after their use to go into recycling process, they become an eyesore in the stream of Municipal Solid Waste (MSW) due to high visibility. As the synthetic and conventional plastics are non-biodegradable in nature, these remain in the dump yards/ landfills for several years, if not collected properly. Due to non- biodegradability, plastics waste remains in the environment for several years, if not collected and disposing plastics wastes at landfills are unsafe since toxic chemicals leach out into the soil and as they contaminate soil and underground water quality. The municipal solid waste also increasing day-by-day due to the inefficient source collection, segregation and transmission of plastics waste for recycling and reusing. In order to find out the realistic plastics waste generation, a study on assessment and quantification of plastics waste has been carried out by CPCB in collaboration with CIPET on selected 60 major cities of India.

  8. [CHROMATOSPECTROPHOTOMETRIC METHOD OF QUANTITATIVE ANALYSIS OF LAPPACONITINE IN THE UNDERGROUND PARTS OF ACONITUM ORIENTALE MILL, GROWING IN GEORGIA].

    PubMed

    Kintsurashvili, L

    2016-05-01

    Aconitum orientale Mill (family Helleboraceae) is a perennial herb. It is spread in forests of the west and the east Georgia and in the subalpine zone. The research objects were underground parts of Aconitum orientale Mill, which were picked in the phase of fruiting in Borjomi in 2014. We had received alkaloids sum from the air-dry underground parts (1.5 kg) with chloroform extract which was alkalined by 5% sodium carbonate. We received the alkaloids sum of 16.5 g and determined that predominant is pharmacologically active diterpenic alkaloid - Lappaconitine, which is an acting initial part of the antiarrhythmic drug "Allapinin". The chromatospectrophotometrical method of quantitative analysis of Lappaconitine is elaborated for the detection of productivity of the underground parts of Aconitum orientale Mill. It was determined that maximal absorption wave length in ultra-violet spectrum (λmax) is 308 nm; It is established that relative error is norm (4%) from statical processing of quantitative analysis results. We determined that the content of Lappaconitine in the underground parts of Aconitum orientale Mill is 0.11-0.13% in the phase of fruiting. In consequence of experimental data Aconitum orientale Mill is approved as the raw material to receive pharmacologically active Lappaconitine.

  9. Multisensor system for toxic gases detection generated on indoor environments

    NASA Astrophysics Data System (ADS)

    Durán, C. M.; Monsalve, P. A. G.; Mosquera, C. J.

    2016-11-01

    This work describes a wireless multisensory system for different toxic gases detection generated on indoor environments (i.e., Underground coal mines, etc.). The artificial multisensory system proposed in this study was developed through a set of six chemical gas sensors (MQ) of low cost with overlapping sensitivities to detect hazardous gases in the air. A statistical parameter was implemented to the data set and two pattern recognition methods such as Principal Component Analysis (PCA) and Discriminant Function Analysis (DFA) were used for feature selection. The toxic gases categories were classified with a Probabilistic Neural Network (PNN) in order to validate the results previously obtained. The tests were carried out to verify feasibility of the application through a wireless communication model which allowed to monitor and store the information of the sensor signals for the appropriate analysis. The success rate in the measures discrimination was 100%, using an artificial neural network where leave-one-out was used as cross validation method.

  10. Clean Power Generation from the Intractable Natural Coalfield Fires: Turn Harm into Benefit.

    PubMed

    Shi, Bobo; Su, Hetao; Li, Jinshi; Qi, Haining; Zhou, Fubao; Torero, José L; Chen, Zhongwei

    2017-07-13

    The coal fires, a global catastrophe for hundreds of years, have been proved extremely difficult to control, and hit almost every coal-bearing area globally. Meanwhile, underground coal fires contain tremendous reservoir of geothermal energy. Approximately one billion tons of coal burns underground annually in the world, which could generate ~1000 GW per annum. A game-changing approach, environmentally sound thermal energy extraction from the intractable natural coalfield fires, is being developed by utilizing the waste energy and reducing the temperature of coalfield fires at the same time. Based on the Seebeck effect of thermoelectric materials, the temperature difference between the heat medium and cooling medium was employed to directly convert thermal energy into clean electrical energy. By the time of December 2016, the power generation from a single borehole at Daquan Lake fire district in Xinjiang has been exceeded 174.6 W. The field trial demonstrates that it is possible to exploit and utilize the waste heat resources in the treated coal fire areas. It promises a significant impact on the structure of global energy generation and can also promote progress in thermoelectric conversion materials, geothermal exploration, underground coal fires control and other energy related areas.

  11. 30 CFR 75.2 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... of gas mask approved by MSHA and NIOSH under 42 CFR part 84 for escape only from underground mines.... Pulverized limestone, dolomite, gypsum, anhydrite, shale, adobe, or other inert material, preferably light...

  12. 30 CFR 75.2 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... of gas mask approved by MSHA and NIOSH under 42 CFR part 84 for escape only from underground mines.... Pulverized limestone, dolomite, gypsum, anhydrite, shale, adobe, or other inert material, preferably light...

  13. 30 CFR 75.2 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... of gas mask approved by MSHA and NIOSH under 42 CFR part 84 for escape only from underground mines.... Pulverized limestone, dolomite, gypsum, anhydrite, shale, adobe, or other inert material, preferably light...

  14. Explosion and/or fire risk assessment methodology: a common approach, structured for underground coalmine environments / Metoda szacowania ryzyka wybuchu i pożarów: podejście ogólne, dostosowane do środowiska kopalni podziemnej

    NASA Astrophysics Data System (ADS)

    Cioca, Ionel-Lucian; Moraru, Roland Iosif

    2012-10-01

    In order to meet statutory requirements concerning the workers health and safety, it is necessary for mine managers within Valea Jiului coal basin in Romania to address the potential for underground fires and explosions and their impact on the workforce and the mine ventilation systems. Highlighting the need for a unified and systematic approach of the specific risks, the authors are developing a general framework for fire/explosion risk assessment in gassy mines, based on the quantification of the likelihood of occurrence and gravity of the consequences of such undesired events and employing Root-Cause analysis method. It is emphasized that even a small fire should be regarded as being a major hazard from the point of view of explosion initiation, should a combustible atmosphere arise. The developed methodology, for the assessment of underground fire and explosion risks, is based on the known underground explosion hazards, fire engineering principles and fire test criteria for potentially combustible materials employed in mines.

  15. Application and Prospects of High-strength Lightweight Materials used in Coal mine

    NASA Astrophysics Data System (ADS)

    He, Pan

    2017-09-01

    This paper describes some high-strength lightweight materials used in coal mine, and if their performance can meet the requirements of underground safety for explosion-proof, anti-static, friction sparks mine; and reviewed the species, characteristic, preparation process of high-strength lightweight materials for having inspired lightweight high-strength performance by modifying or changing the synthesis mode used in coal mine equipment.

  16. 75 FR 36120 - Proposed Information Collection Request Submitted for Public Comment and Recommendations; Program...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-24

    ... Submitted for Public Comment and Recommendations; Program To Prevent Smoking Underground and in Hazardous... Act), 30 U.S.C. 877(c), and 30 CFR 75.1702 prohibit persons from smoking or carrying smoking materials... mine operators are required to develop programs to prevent persons from carrying smoking materials...

  17. How to Tell What's Underground.

    ERIC Educational Resources Information Center

    Bartholomew, Rolland B.

    Presented is a suggested instructional lesson based on important clues that lead to a better understanding of the kinds of materials that lie under and within the earth's crust. Comparing density of earth rocks to density of the whole earth, and accounting for the discrepancy, leads to awareness of the difference of materials of the earth's…

  18. Shape and Reinforcement Optimization of Underground Tunnels

    NASA Astrophysics Data System (ADS)

    Ghabraie, Kazem; Xie, Yi Min; Huang, Xiaodong; Ren, Gang

    Design of support system and selecting an optimum shape for the opening are two important steps in designing excavations in rock masses. Currently selecting the shape and support design are mainly based on designer's judgment and experience. Both of these problems can be viewed as material distribution problems where one needs to find the optimum distribution of a material in a domain. Topology optimization techniques have proved to be useful in solving these kinds of problems in structural design. Recently the application of topology optimization techniques in reinforcement design around underground excavations has been studied by some researchers. In this paper a three-phase material model will be introduced changing between normal rock, reinforced rock, and void. Using such a material model both problems of shape and reinforcement design can be solved together. A well-known topology optimization technique used in structural design is bi-directional evolutionary structural optimization (BESO). In this paper the BESO technique has been extended to simultaneously optimize the shape of the opening and the distribution of reinforcements. Validity and capability of the proposed approach have been investigated through some examples.

  19. Effect of Variable Compression Ratio on Performance of a Diesel Engine Fueled with Karanja Biodiesel and its Blends

    NASA Astrophysics Data System (ADS)

    Mishra, Rahul Kumar; soota, Tarun, Dr.; singh, Ranjeet

    2017-08-01

    Rapid exploration and lavish consumption of underground petroleum resources have led to the scarcity of underground fossil fuels moreover the toxic emissions from such fuels are pernicious which have increased the health hazards around the world. So the aim was to find an alternative fuel which would meet the requirements of petroleum or fossil fuels. Biodiesel is a clean, renewable and bio-degradable fuel having several advantages, one of the most important of which is being its eco-friendly and better knocking characteristics than diesel fuel. In this work the performance of Karanja oil was analyzed on a four stroke, single cylinder, water cooled, variable compression ratio diesel engine. The fuel used was 5% - 25% karanja oil methyl ester by volume in diesel. The results such obtained are compared with standard diesel fuel. Several properties i.e. Brake Thermal Efficiency, Brake Specific Fuel Consumptions, Exhaust Gas Temperature are determined at all operating conditions & at variable compression ratio 17 and 17.5.

  20. THE TOXICITY OF RUBBERS AND PLASTICS USED IN TRANSFUSION-GIVING SETS

    PubMed Central

    Cruickshank, C. N. D.; Hooper, Caroline; Lewis, H. B. M.; MacDougall, J. D. B.

    1960-01-01

    The toxicity of different rubbers and plastics used in transfusion-giving sets has been investigated by examining their effects on (a) cultures of chick embryo tissues, (b) the oxygen uptake of guinea-pig skin tissue cultures, and (c) the growth of Str. pyogenes. The results of the laboratory tests have been compared with the incidence of thrombophlebitis after prolonged transfusions through the various materials. It was found that where the materials inhibited the growth of Str. pyogenes they were also toxic to tissue cultures, but that some materials which were toxic to tissue cultures did not inhibit bacterial growth. The assessments of the relative toxicity of the materials tested by the two tissue culture methods were in agreement. The skin respiration studies, however, gave more information on the early effects of the toxic materials. The relative toxicity of the materials as revealed by these tests could be correlated with the differences in the incidence of thrombophlebitis following intravenous infusions administered through giving-sets assembled with the materials tested. It is suggested therefore that the toxicity revealed by these tests is of clinical importance, and that tissue culture toxicity tests will prove to be of value in selecting rubbers and plastics for clinical purposes. Images PMID:13813084

  1. Experiments Developed to Study Microgravity Smoldering Combustion

    NASA Technical Reports Server (NTRS)

    Vergilii, Franklin

    2001-01-01

    The overall objective of the Microgravity Smoldering Combustion (MSC) research program is to understand and predict smoldering combustion under normal and microgravity (near-zero-gravity) conditions to help prevent and control smolder-originated fires, in both environments. Smoldering is defined as a nonflaming, self-sustaining, propagating, exothermic surface reaction. If a material is sufficiently permeable, smoldering is not confined to its outer surface, but can propagate as a reaction wave through the interior of the material. The MSC program will accomplish its goals by conducting smolder experiments on the ground and in a space-based laboratory, and developing theoretical models of the process. Space-based experiments are necessary because smoldering is a very slow process and, consequently, its study in a microgravity environment requires extended periods of time that can only be achieved in space. Smoldering can occur in a variety of processes ranging from the smolder of porous insulating materials to underground coal combustion. Many materials can sustain smoldering, including wood, cloth, foams, tobacco, other dry organic materials, and charcoal. The ignition, propagation, transition to flaming, and extinction of the smolder reaction are controlled by complex, thermochemical mechanisms that are not well understood. As with many forms of combustion, gravity affects the availability of the oxidizer and the transport of heat, and therefore, the rate of combustion. The smoldering combustion of porous materials has been studied both experimentally and theoretically, usually in the context of fire safety. Smoldering encompasses a number of fundamental processes, including heat and mass transfer in a porous media; endothermic pyrolysis of combustible material; ignition, propagation, and extinction of heterogeneous exothermic reactions at the solid-gas pore interface; and the onset of gas phase reactions (flaming) from existing surface reactions. Smoldering presents a serious fire risk because the combustion can propagate slowly in a material's interior and go undetected for long periods of time. It typically yields a substantially higher conversion of fuel to toxic compounds than does flaming (though more slowly), and may undergo a sudden transition to flaming.

  2. A geological and geotechnical investigation of the settlement area of Zümrüt Building (Konya, Turkey) which caused 92 fatalities due to its collapse

    NASA Astrophysics Data System (ADS)

    Özdemir, Adnan

    2008-02-01

    This study examines the local geological conditions and soil structure as possible causes of the collapse of the Zümrüt Building 2 February 2004. This catastrophe resulted in 92 fatalities and 35 injuries. This study also examines other views which claim weak soil structure, elastic and consolidation settlement of soil and excessive groundwater extraction as well as subsidence resulting from the underground silt erosion as possible factors. Zümrüt Building was constructed on normally consolidated, low plasticity clay. The underground water table was 30 m in depth. The internal friction angle of soil was 8°-30°, its cohesion was between 34 and 127 kN/m2 and standard penetration test numbers varied between 11 and 50. The underground water level beneath Zümrüt Building had risen 4.5 m since its construction. Therefore the claim that subsidence resulting from the decrease of underground water level contributed to the collapse is incorrect. Secondly the settlement, resulting from the filling up of the pores created by the silt receding with the underground water, was 4.4 mm in total, and attributing this as the primary cause of the collapse is also incorrect. Soil properties, in situ and laboratory test results showed that the existing and/or expected settlement and the differential ground settlement in the Zümrüt building vicinity had the potential to cause structural damage. The tensile stresses caused by differential settlements recorded here are thought to be an indicator, but not the main cause contributing to the collapse of the building. The Zümrüt Building collapse was due to several compounding mistakes during the construction phase. These were geotechnical and other project faults and the use of low quality construction materials. The resulting catastrophe caused 92 fatalities, 35 injuries and a material loss of approximately US7 million.

  3. 43 CFR 3436.2-1 - Qualified exchange proponents.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... interrupt farming or materially damage the quantity and quality of the water in surface or underground water... Control and Reclamation Act. (b) Exchange proponents bear the burden of establishing their qualifications...

  4. 43 CFR 3436.2-1 - Qualified exchange proponents.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... interrupt farming or materially damage the quantity and quality of the water in surface or underground water... Control and Reclamation Act. (b) Exchange proponents bear the burden of establishing their qualifications...

  5. 30 CFR 57.4504 - Fan installations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... for main and booster fans, and air ducts connecting main fans to underground openings shall be constructed of noncombustible materials. (b) Areas within 25 feet of main fans or booster fans shall be free...

  6. 30 CFR 57.4504 - Fan installations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... for main and booster fans, and air ducts connecting main fans to underground openings shall be constructed of noncombustible materials. (b) Areas within 25 feet of main fans or booster fans shall be free...

  7. 30 CFR 57.4504 - Fan installations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... for main and booster fans, and air ducts connecting main fans to underground openings shall be constructed of noncombustible materials. (b) Areas within 25 feet of main fans or booster fans shall be free...

  8. 30 CFR 57.4504 - Fan installations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... for main and booster fans, and air ducts connecting main fans to underground openings shall be constructed of noncombustible materials. (b) Areas within 25 feet of main fans or booster fans shall be free...

  9. Low Background Assay Results for LZ

    NASA Astrophysics Data System (ADS)

    Oliver-Mallory, Kelsey; Thomas, Keenan; Lux-Zeplin Collaboration; Berkeley Low Background Facility Team

    2016-03-01

    The next generation dark matter experiment LUX-ZEPLIN (LZ) requires careful control of intrinsic radioactivity in all critical detector components in order to reach its unprecedented target sensitivity to Weakly Interacting Massive Particles (WIMPs): 2 ×10-48 cm2 at 50 GeV/c2. Appropriate material selection is essential to meeting this goal, and an extensive campaign of low background screening is currently being carried out using assay devices at the Sanford Underground Research Facility and the Boulby Underground Laboratory. We will present results from this work, including measurements for the Ti cryostat, PMT bases, PMT raw materials, PTFE, and other components. This work was partially supported by the U.S. Department of Energy (DOE) under Award Number DE-AC02-05CH11231, and is based upon work supported by the National Science Foundation Graduate Research Fellowship under Grant No. 1106400.

  10. System for fracturing an underground geologic formation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mace, Jonathan L.; Tappan, Bryce C.; Seitz, Gerald J.

    2017-03-14

    An explosive system for fracturing an underground geologic formation adjacent to a wellbore can comprise a plurality of explosive units comprising an explosive material contained within the casing, and detonation control modules electrically coupled to the plurality of explosive units and configured to cause a power pulse to be transmitted to at least one detonator of at least one of the plurality of explosive units for detonation of the explosive material. The explosive units are configured to be positioned within a wellbore in spaced apart positions relative to one another along a string with the detonation control modules positioned adjacentmore » to the plurality of explosive units in the wellbore, such that the axial positions of the explosive units relative to the wellbore are at least partially based on geologic properties of the geologic formation adjacent the wellbore.« less

  11. Multi-layer waste containment barrier

    DOEpatents

    Smith, Ann Marie; Gardner, Bradley M.; Nickelson, David F.

    1999-01-01

    An apparatus for constructing an underground containment barrier for containing an in-situ portion of earth. The apparatus includes an excavating device for simultaneously (i) excavating earthen material from beside the in-situ portion of earth without removing the in-situ portion and thereby forming an open side trench defined by opposing earthen sidewalls, and (ii) excavating earthen material from beneath the in-situ portion of earth without removing the in-situ portion and thereby forming a generally horizontal underground trench beneath the in-situ portion defined by opposing earthen sidewalls. The apparatus further includes a barrier-forming device attached to the excavating device for simultaneously forming a side barrier within the open trench and a generally horizontal, multi-layer barrier within the generally horizontal trench. The multi-layer barrier includes at least a first layer and a second layer.

  12. Early distinction system of mine fire in underground by using a neural-network system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ohga, Kotaro; Higuchi, Kiyoshi

    1996-12-31

    In our laboratory, a new detection system using smell detectors was developed to detect the spontaneous combustion of coal and the combustion of other materials used underground. The results of experiments clearly the combustion of materials can be detected earlier by this detection system than by conventional detectors for gas and smoke, and there were significant differences between output data from each smell detector for coal, rubber, oil and wood. In order to discern the source of combustion gases, we have been developing a distinction system using a neural-network system. It has shown successful results in laboratory tests. This papermore » describes our detection system using smell detectors and our distinction system which uses a neural-network system, and presents results of experiments using both systems.« less

  13. Early detection of mine fire in underground by using smell detectors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ohga, Kotaro; Higuchi, Kiyoshi

    1995-12-31

    In our laboratory, a new detection system using smell detectors was developed to detect the spontaneous combustion of coal and the combustion of other materials used underground. Laboratory experiments were carried out on several kinds of coals, including South African coals, and machine oil, wood and rubber used in belt conveyers. The following results were obtained: (1) Spontaneous combustion of coal can be detected earlier by smell detectors than by conventional CO detection methods. (2) There were no differences in the results using different kinds of coal. (3) Combustion d other materials can also be detected earlier by this systemmore » than by conventional detectors for gas and smoke. (4) Use of this detection system enables one to discern the source of the combustion gases, whether it be coal, wood, oil or rubber.« less

  14. RIFM fragrance ingredient safety assessment, 2-ethyl-1-hexanol, CAS registry number 104-76-7.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic. Data from the suitable read across analog 2-butyloctan-1-ol (CAS # 3913-02-8) show that this material does not have skin sensitization potential. The reproductive and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (0.03 and 1.4 mg/day, respectively). The developmental and repeat dose toxicity endpoints were completed data on the target material which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. 48 CFR 252.223-7006 - Prohibition on Storage, Treatment, and Disposal of Toxic or Hazardous Materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ..., Treatment, and Disposal of Toxic or Hazardous Materials. 252.223-7006 Section 252.223-7006 Federal..., Treatment, and Disposal of Toxic or Hazardous Materials. As prescribed in 223.7106, use the basic clause or..., TREATMENT, AND DISPOSAL OF TOXIC OR HAZARDOUS MATERIALS—BASIC (SEP 2014) (a) Definitions. As used in this...

  16. Seeding materials: Health and safety considerations

    NASA Technical Reports Server (NTRS)

    Brown, R. D.

    1985-01-01

    The choice of a proper seeding material for laser velocimeters must include health and safety considerations. Failure to do so can lead to catastrophic results. All materials are toxic, and laser velocimeter seeding materials are no exception. Toxicity may be considered an inherent property of a given material. The manifestation of that property or the physiological response to the material is dependent on dose and exposure conditions. An approximate physiological classification of toxicity is given in tablular form. Toxicity in some situations is not necessarily the most restrictive factor in selection of materials. It is also very important to consider how the material is used so that actual exposure to the material in a damaging form can result. For example, nickel and cadmium are both extremely toxic as systemic poisons and in the case of nickel as a carcinogen. Seeding materials are dispersed in air under conditions that favor personnel exposure. Dispersal equipment is frequently if not normally manned, and personnel are often required to make frequent adjustments to assure proper operations.

  17. 43 CFR 3436.1-1 - Qualified lease proponents.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... farming or materially damage the quantity and quality of the water in surface or underground water systems... exchange bear the burden of establishing that they are qualified pursuant to paragraph (a) of this section...

  18. 43 CFR 3436.1-1 - Qualified lease proponents.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... farming or materially damage the quantity and quality of the water in surface or underground water systems... exchange bear the burden of establishing that they are qualified pursuant to paragraph (a) of this section...

  19. Environmental statutes, 1985 edition

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1985-01-01

    All major environmental laws are incorporated into a single book. The complete text of each statute as currently amended is included with a detailed Table of Contents for your quick referral. Contents: Clean Air Act; Federal Water Pollution Control Act; National Environmental Policy Act; Noise Control Act; FIFRA; Marines Sanctuaries Act; Occupational Safety and Health Act; Resource Conservation and Recovery Act including the new Hazardous and Solid Waste Amendments of 1984 with the new Leaking Underground Storage Tank law; Safe Drinking Water Act; Toxic Substances Control Act; CERCLA/Superfund; and the Used Oil Recycling Act.

  20. Technologies for the management of MSW incineration ashes from gas cleaning: New perspectives on recovery of secondary raw materials and circular economy.

    PubMed

    Quina, Margarida J; Bontempi, Elza; Bogush, Anna; Schlumberger, Stefan; Weibel, Gisela; Braga, Roberto; Funari, Valerio; Hyks, Jiri; Rasmussen, Erik; Lederer, Jakob

    2018-09-01

    Environmental policies in the European Union focus on the prevention of hazardous waste and aim to mitigate its impact on human health and ecosystems. However, progress is promoting a shift in perspective from environmental impacts to resource recovery. Municipal solid waste incineration (MSWI) has been increasing in developed countries, thus the amount of air pollution control residues (APCr) and fly ashes (FA) have followed the same upward trend. APCr from MSWI is classified as hazardous waste in the List of Waste (LoW) and as an absolute entry (19 01 07*), but FA may be classified as a mirror entry (19 0 13*/19 01 14). These properties arise mainly from their content in soluble salts, potentially toxic metals, trace organic pollutants and high pH in contact with water. Since these residues have been mostly disposed of in underground and landfills, other possibilities must be investigated to recover secondary raw materials and products. According to the literature, four additional routes of recovery have been found: detoxification (e.g. washing), product manufacturing (e.g. ceramic products and cement), practical applications (e.g. CO 2 sequestration) and recovery of materials (e.g. Zn and salts). This work aims to identify the best available technologies for material recovery in order to avoid landfill solutions. Within this scope, six case studies are presented and discussed: recycling in lightweight aggregates, glass-ceramics, cement, recovery of zinc, rare metals and salts. Finally, future perspectives are provided to advance understanding of this anthropogenic waste as a source of resources, yet tied to safeguards for the environment. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

  1. Chlorhexidine hexametaphosphate as a wound care material coating: antimicrobial efficacy, toxicity and effect on healing.

    PubMed

    Barbour, Michele E; Maddocks, Sarah E; Grady, Helena J; Roper, James A; Bass, Mark D; Collins, Andrew M; Dommett, Rachel M; Saunders, Margaret

    2016-08-01

    In this study, chlorhexidine hexametaphosphate (CHX-HMP) is investigated as a persistent antimicrobial coating for wound care materials. CHX-HMP was used as a wound care material coating and compared with chlorhexidine digluconate materials with respect to antimicrobial efficacy, toxicity and wound closure. Antimicrobial efficacy at day 1, 3 and 7 was observed with experimental and commercial materials. CHX-HMP coated materials had less toxic effect on human placental cells than commercial chlorhexidine dressings. CHX-HMP in pluronic gel did not delay healing but reduced wound colonization by E. faecalis. CHX-HMP could become a useful component of wound care materials with sustained antimicrobial efficacy, lower toxicity than chlorhexidine digluconate materials, and reduction in wound colonization without affecting closure.

  2. Toxicity of Uranium Adsorbent Materials using the Microtox Toxicity Test

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Park, Jiyeon; Jeters, Robert T.; Gill, Gary A.

    2015-10-01

    The Marine Sciences Laboratory at the Pacific Northwest National Laboratory evaluated the toxicity of a diverse range of natural and synthetic materials used to extract uranium from seawater. The uranium adsorbent materials are being developed as part of the U. S. Department of Energy, Office of Nuclear Energy, Fuel Resources Program. The goal of this effort was to identify whether deployment of a farm of these materials into the marine environment would have any toxic effects on marine organisms.

  3. Opportunities for Multidisciplinary Research in Partnership with Rock Engineers at the Deep Underground Science and Engineering Laboratory

    NASA Astrophysics Data System (ADS)

    Laughton, C.

    2008-12-01

    For the last half century the physics community has increasingly turned to the use of underground space to conduct basic research. The community is currently planning to conduct a new generation of underground experiments at the Deep Underground Science and Engineering Laboratory (DUSEL). DUSEL will be constructed within the footprint of the defunct Homestake Gold Mine, located in Lead, South Dakota. Physics proposals call for the construction of new caverns in which to conduct major new experiments. Some of the proposed laboratory facilities will be significantly larger and deeper than any previously constructed. The talk will highlight possible opportunities for integrating multi-disciplinary research in to the cavern construction program, and will stress the need to work closely with design and construction contractors to ensure that research goals can be achieve with minimal impact on project work. The constructors of large caverns should be particularly receptive to, and encouraging of geoscience research that could improve the engineering characterization of the rock mass. An improved understanding of the rock mass, as the host construction material, would result in a more reliable cavern design and construction process, and a reduced construction risk to the Project.

  4. Choosing the function of mechanical properties of grounds and rock formations due to their heterogeneity

    NASA Astrophysics Data System (ADS)

    Frolova, Irina; Agakhanov, Murad

    2018-03-01

    The development of computing techniques to analyze underground structures, buildings in high-rise construction that would fully take account of the conditions of their design and operation, as well as the real material properties, is one of the important trends in structural mechanics. For the territory in high-rise construction it is necessary to monitor the deformations of the soil surface. When high-rise construction is recommended to take into account the rheological properties and temperature deformations of the soil, the effect of temperature on the mechanical characteristics of the surrounding massif. Similar tasks also arise in the creation and operation of underground parts of high-rise construction, which are used for various purposes. These parts of the structures are surrounded by rock massifs of various materials. The actual mechanical characteristics of such materials must be taken into account. The objective property of nearly all materials is their non-homogeneity, both natural and technological. The work addresses the matters of building nonhomogeneous media initial models based on the experimental evidence. This made it possible to approximate real dependencies and obtain the appropriate functions in a simple and convenient way.

  5. Photocatalytic Pre-Oxidation of Arsenic (III) in Groundwater by a Visible-Light-Driven System with Magnetic Separating Characteristic

    NASA Astrophysics Data System (ADS)

    Cui, Y.; Liu, Y.; Peng, L.; Qin, Y.

    2017-12-01

    Arsenic was a typical toxic metalloid element and its contamination in groundwater was widely recognized as a global health problem, especially in north China, where people depended on groundwater as water resource. Arsenic was existed as As(III) in underground water, and has low affinity to the surface of various minerals and more toxic and more difficultly to be removed compared with As(V), so a pre-oxidation technology by transforming As (III) to As (V) is highly desirable. Electrochemical and oxidizing agents were traditional technology, which usually causes secondary pollution. A novel methodology is presented here, using prepared magnetic visible-light-driven nanomaterials as recyclable media to investigate As(III) pre-oxidation processing. Ag@AgCl core-shell nanowires were first synthesized by oxidation of Ag nanowires with moderate FeCl3, and exhibited excellent photocatalytic activity to As(III) with visible-light. The ratio of chloridization was proved to act as key effect on photocatalytic oxidation efficiency. Testing with simulated groundwater condition proved that pH, ionic strength and concentration of humic acid have obvious effects on Ag@AgCl photocatalytic ability. h+ and ·O2- were confirmed to be the main active species during the visible-light driven photocatalytic oxidation process for As(III) by trapping experiments with radical scavengers. Then Fe0 was introduced to prepare Fe-Ag nanowire and chloridized into Fe-Ag@AgCl to provide magnetic characteristic. The magnetic recycling and re-chloride experiments validated this visible-light-driven material has excellent stable and high reused ability as photocatalyst under visible light irradiation.

  6. Remediation of coal mining wastewaters using chitosan microspheres.

    PubMed

    Geremias, R; Pedrosa, R C; Benassi, J C; Fávere, V T; Stolberg, J; Menezes, C T B; Laranjeira, M C M

    2003-12-01

    This study aimed to evaluate the potential use of chitosan and chitosan/poly(vinylalcohol) microspheres incorporating with tetrasulphonated copper (II) phthalocyanine (CTS/PVA/TCP) in the remediation of coal mining wastewaters. The process was monitored by toxicity tests both before and after adsorption treatments with chitosan and microspheres. Physicochemical parameters, including pH and trace-metal concentration, as well as bioindicators of water pollution were used to that end. Wastewater samples colleted from drainage of underground coal mines, decantation pools, and contaminated rivers were scrutinized. Acute toxicity tests were performed using the Brine Shrimp Test (BST) in order to evaluate the remediation efficiency of different treatments. The results showed that the pH of treated wastewater samples were improved to values close to neutrality. Chitosan treatments were also effective in removing trace-metals. Pre-treatment with chitosan followed by microsphere treatment (CTS/PVA/TCP) was more effective in decreasing toxicity than the treatment using only chitosan. This was probably due to the elimination of pollutants other than trace-metals. Thus, the use of chitosan and microspheres is an adequate alternative towards remediation of water pollution from coal mining.

  7. Dredged Material Analysis Tools; Performance of Acute and Chronic Sediment Toxicity Methods

    DTIC Science & Technology

    2008-04-01

    Chronic Sediment Toxicity Methods Jeffery Steevens, Alan Kennedy, Daniel Farrar, Cory McNemar, Mark R. Reiss, Roy K. Kropp, Jon Doi, and Todd Bridges...Research Program ERDC/EL TR-08-16 April 2008 Dredged Material Analysis Tools Performance of Acute and Chronic Sediment Toxicity Methods Jeffery...potential advan- tages and disadvantages of using chronic sediment toxicity tests with relevant benthic macroinvertebrates as part of dredged material

  8. An analysis of roof bolter fatalities and injuries in U.S. mining

    PubMed Central

    Sammarco, J.J.; Podlesny, A.; Rubinstein, E.N.; Demich, B.

    2017-01-01

    Roof bolting typically follows the extraction of a commodity to help keep the roof from collapsing. During 2004 to 2013, roof bolter operators had the highest number of machinery-related injuries, accounting for 64.7 percent, at underground coal mines. This paper analyzes U.S. roof bolter fatal and nonfatal lost-time injury data at underground work locations for all commodities from 2004 through 2013 and determines risk indices for six roof bolting tasks. For fatal and nonfatal incidences combined, the roof bolting tasks in order of the highest to lowest risk index were bolting, handling of materials, setting the temporary roof support (TRS), drilling, tramming, and traversing. For fatalities, the roof bolting tasks in order of the highest to lowest risk index were handling of materials, setting the TRS, bolting, drilling, traversing, and tramming. Age was found to be a significant factor. Severity of injury, indicated by days lost, was found to increase with increasing age as well as with increasing experience, largely due to the confounding of age and experience. The operation of the roof bolting machine used in underground mining should be a research priority given the high frequency and severity of incidents. The results also suggest that temporal factors may exist, so additional research is warranted to better understand these factors and potentially develop interventions. This research provides a data-driven foundation from which future research can be conducted for safety interventions to reduce the frequency and severity of incidences involving the roof bolter activities of bolting, handling of materials, and setting the TRS. PMID:28845099

  9. 24 CFR 581.6 - Suitability criteria.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ..., the property will not be determined unsuitable on this basis. (2) Property containing flammable or... handling flammable or explosive material (excluding underground storage) will be determined unsuitable..., friable asbestos, PCB's, or natural hazardous substances such as radon, periodic flooding, sinkholes or...

  10. Remediating MGP brownfields

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Larsen, B.R.

    Before natural gas pipelines became widespread in this country, gas fuel was produced locally in more than 5,000 manufactured gas plants (MGPs). The toxic wastes from these processes often were disposed onsite and have since seeped into the surrounding soil and groundwater. Although the MGPs--commonly called gas plants, gas-works or town gas plants--have closed and most have been demolished, they have left a legacy of environmental contamination. At many MGP sites, underground storage tanks were constructed of wood or brick, with process piping and equipment which frequently leaked. Waste materials often were disposed onsite. Releases of coal tars, oils andmore » condensates produced within the plants contributed to a wide range of contamination from polycyclic aromatic hydrocarbons, phenols, benzene and cyanide. Remediation of selected MGP sites has been sporadic. Unless the site has been identified as a Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) Superfund site, the regulatory initiative to remediate often remains with the state in which the MGP is located. A number of factors are working to change that picture and to create a renewed interest in MGP site remediation. The recent Brownfield Initiative by the US Environmental Protection Agency (EPA) is such an example.« less

  11. Development of an Integrated Toxicity Assessment System for use in Operational Deployment and Materials Development

    DTIC Science & Technology

    2006-05-01

    In addition to NBC concerns, there are issues in many current military settings for exposures to toxic industrial chemicals or materials (TICs or TIMs...Significant health issues caused by use of legacy chemicals have emphasized the need for more effective predication of chemical toxicity . This paper...current military settings for exposures to toxic industrial chemicals or materials (TICs or TIMs). Significant health issues caused by use of legacy

  12. Preliminary Toxicological Analysis of the Effect of Coal Slurry Impoundment Water on Human Liver Cells

    USGS Publications Warehouse

    Bunnell, Joseph E.

    2008-01-01

    Coal is usually 'washed' with water and a variety of chemicals to reduce its content of sulfur and mineral matter. The 'washings' or 'coal slurry' derived from this process is a viscous black liquid containing fine particles of coal, mineral matter, and other dissolved and particulate substances. Coal slurry may be stored in impoundments or in abandoned underground mines. Human health and environmental effects potentially resulting from leakage of chemical substances from coal slurry into drinking water supplies or aquatic ecosystems have not been systematically examined. Impoundments are semipermeable, presenting the possibility that inorganic and organic substances, some of which may be toxic, may contaminate ground or surface water. The Agency for Toxic Substances and Disease Registry, part of the Centers for Disease Control and Prevention, has concluded that well water in Mingo County, West Virginia, constitutes a public health hazard.

  13. In vitro toxicity analysis of nanoscale aluminum: Particle size and shape effects

    NASA Astrophysics Data System (ADS)

    Palazuelos Jorganes, Maria

    2007-12-01

    Nanostructured materials promise to revolutionize many key areas of science and technology. As our ability to manipulate matter at the nanoscale increases, there is a need to assess the effects of these materials on human health and the environment. Materials at the nanoscale are interesting and useful because they possess properties that are different from the equivalent bulk or molecular scale. These same properties can make toxicological profiles very different from those of the same materials on a different scale. There is a rising consensus that toxicity analysis of nanomaterials should start from a thorough physicochemical characterization of the materials under investigation in order to be able to establish a proper correlation between the nanoparticles characteristics and their effects and behavior in physiological environments. This research is a clear example of the necessity of comprehensive studies when investigating the toxicity of nanomaterials. Aluminum nanoparticles are being extensively used for their very unique energetic properties. These materials offer a very promising market that is fostering many startup companies which are expected to consolidate on strong technological positions. Aluminum is generally recognized as a non-toxic material to humans and it is widely used for applications which imply direct human contact. The effect of aluminum nanoparticles in human health is still an unknown. My research consisted of an in vitro toxicity screening of aluminum materials from nano to micron size, including spherical irregularly shaped particles. Several issues relating to size, shape, detection and characterization of nanoparticles in the different environments relevant to in vitro toxicity analysis were addressed and suitable protocols were developed. Lung human epithelial cells were exposed to different concentrations of these materials and the effects were analyzed by means of various toxicity tests. Some of the materials investigated caused elevated in vitro toxicity. Cells endocytosed the particles and a clear correlation between the particle size, shape and the effects observed was established. The hypothesized toxicity mechanism was explored using different analytical techniques. The detected toxicity of aluminum nanoparticles was demonstrated to be a direct effect of their reactivity inside the cells.

  14. The effect of inclined soil layers on surface vibration from underground railways using a semi-analytical approach

    NASA Astrophysics Data System (ADS)

    Jones, S.; Hunt, H.

    2009-08-01

    Ground vibration due to underground railways is a significant source of disturbance for people living or working near the subways. The numerical models used to predict vibration levels have inherent uncertainty which must be understood to give confidence in the predictions. A semi-analytical approach is developed herein to investigate the effect of soil layering on the surface vibration of a halfspace where both soil properties and layer inclination angles are varied. The study suggests that both material properties and inclination angle of the layers have significant effect (± 10dB) on the surface vibration response.

  15. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mitrica, Bogdan; Stanca, Denis; Brancus, Iliana

    Since 2006 a modern laboratory has been developed by IFIN-HH in the underground of Slanic Prahova salt ore. This work presents a short review of previous scientific activities performed in the underground laboratory, in parallel with some plans for the future. A mobile detector for cosmic muon flux measurements has been set up at IFIN-HH, Romania. The device is used to measure the muon flux on different locations at the surface and underground and it consists of two detection layers, each one including four large scintillator plates. A new rotatable detector for measurements of the directional variation of the muonmore » flux has been designed and it is presently under preliminary tests. Built from four layers of sensitive material and using for collecting the signals and directing them to the micro PMTs a new technique, through optical fibers instead wave length shifters, it allows an easy discrimination of the moun flux on the arrival directions of muons. Combining the possibility to rotate and the directionality properties, the underground muon detector is acting like a muon tomography device, being able to scan, using cosmic muons, the rock material above the detector. In parallel new detection system based on SiPM will be also installed in the following weeks. It should be composed by four layers, each layer consisting in 4 scintillator plates what we consider in the following as a module of detection. For this purpose, first two scintillator layers, with the optical fibers positioned on perpendicular directions are put in coincidence with other two layers, 1 m distance from the first two, with similar optical fiber arrangement, thus allowing reconstructing muon trajectory. It is intended also to design and construct an experimental device for the investigation of such radio antennas and the behavior of the signal in rock salt at the Slanic salt mine in Romania. Another method to detect high energy neutrinos is based on the detection of secondary particles resulting from the interaction with the salt massive. We intent to design and construct a 3D array in the underground of Slanic Prahova salt ore.« less

  16. Toxics Use Reduction to Achieve Enhanced Pollution Prevention Success

    EPA Pesticide Factsheets

    Training material from the Massachusetts Toxics Use Reduction Institute, University of Massachusetts Lowell. This training explains toxic use reduction, process mapping and materials accounting. Helps identify TUR opportunities and TUR options evaluation

  17. The toxicity of X material

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ferry, J.L.

    1943-12-31

    This report addresses toxicity (largely chemical) of Manhattan Project materials from the point of worker protection. Known chemical toxicities of X material (uranium), nitrous fumes, fluorine, vanadium, magnesium, and lime are described followed by safe exposure levels, symptoms of exposure, and treatment recommendations. The report closes with an overview of general policy in a question and answer format.

  18. [Genotoxicity and toxicity assay of water sampled from the underground nuclear explosion site in the north of the Perm region (Russia)].

    PubMed

    Evseeva, T I; Geras'kin, S A; Shuktomova, I I; Taskaev, A I

    2004-01-01

    The results of our study revealed a local biologically relevant surface water contamination in the radionuclide anomaly in the north of Russia (Perm region) by means of Allium shoenoprasum L. the anaphase-telophase chromosome aberration assay. This radionuclide anomaly was formed in 1971 as a result of an underground nuclear explosion with soil excavation. Specific activities of main dose-forming radionuclides in all examined reservoirs are below intervention levels officially adopted in Russia for drinking water. We found that 90Sr significantly contribute to induction of cytogenetic disturbances. Our previous and described here data suggest that metal ions and radionuclides combined exposure on the various biota species (with the dose below permissible exposure limits for human) may cause substantial biological effects in part be due to synergic response. The findings described here indicated that development of a new concept of radiation protection for humans and biota should be based on the clear understanding of biological effects of low doses of radiation in chronic exposure to multi-pollutant mixtures.

  19. RIFM fragrance ingredient safety assessment, linalyl cinnamate, CAS Registry Number 78-37-5.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic nor does it have skin sensitization potential. The reproductive and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (0.03 and 1.4 mg/day, respectively). The developmental toxicity endpoint was completed using linalool (CAS # 78-70-6), dehydrolinalool (CAS # 29171-20-8) and cinnamic acid (CAS # 621-82-9) as suitable read across analogs, which provided a MOE > 100. The repeated dose toxicity endpoint was completed using data on the target material which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. 30 CFR 57.4500 - Heat sources.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control... shall be separated from combustible materials if a fire hazard could be created. ...

  1. Determining the relative toxicity and smoke obscuration of combustion products of mine combustibles. Report of Investigations/1990

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    De Rosa, M.I.; Litton, C.D.

    1990-01-01

    Combustible materials, when burned, produce toxic gases and smoke, which may vary dramatically from one material to another, with resultant different total toxicity and smoke obscuration levels. The U.S. Bureau of Mines report presents smoke property data acquired for a variety of mine combustibles and shows that there exists a correlation between the smoke properties, the relative toxicity, and the smoke obscuration levels of those combustibles tested. These correlations can be used to devise simple, standard tests for determining the toxic and smoke obscuration hazards of mine materials during fire.

  2. Two Sources of Nonisotropic Radiation From Underground Explosions in Granite

    DOE PAGES

    Vorobiev, O. Yu.

    2017-10-23

    Significant tangential ground motion observed during underground explosions makes it difficult to distinguish them from natural earthquakes. Such motion can be generated by the source geometry and emplacement conditions, by the heterogeneous nature of the rock mass (mechanical properties may vary in space due to the presence of cracks, joints, faults, and various geologic layers) and also by the nonuniform in situ stress state. The last mechanism is increasingly important with depth when the difference in main principal stresses becomes significant. This paper is focused on the role of material strength of the rock mass in generation of nonradial motionmore » during explosions in prestressed media. Numerical modeling of underground chemical explosions in granite at various depths has been conducted to compare two possible mechanisms of shear wave generation. The first, caused by rock mass anisotropy, is important at shallow depth. The second is related to elastic-plastic relaxation around the cavity created by the explosion. As a result, tangential motions for these two mechanisms have different signatures.« less

  3. The Mile Deep Muon Detector at Sanford Underground Laboratory

    NASA Astrophysics Data System (ADS)

    McMahan, Margaret; Gabriel, Steve

    2012-03-01

    For educating students and teachers about basic nuclear and particle physics, you can't go wrong with cosmic rays muons as a cheap and reliable source of data. A simple and relatively inexpensive detector gives a myriad of possibilities to cover core material in physical science, chemistry, physics, and statistics and gives students opportunities to design their own investigations. At Sanford Underground Laboratory at Homestake, in Lead, SD, cosmic ray muon detectors are being used to answer the first question always asked by any visitor to the facility, ``Why are you building the lab a mile underground'' A conventional Quarknet-style detector is available in the education facility on the surface, with a much larger companion detector, the Mile Deep Muon Detector, set up 4850 feet below the surface. Using the Quarknet data acquisition board, the data will be made available to students and teachers through the Cosmic Ray E-lab website. The detector was tested and installed as part of a summer program for students beginning their first or second year of college.

  4. Two Sources of Nonisotropic Radiation From Underground Explosions in Granite

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vorobiev, O. Yu.

    Significant tangential ground motion observed during underground explosions makes it difficult to distinguish them from natural earthquakes. Such motion can be generated by the source geometry and emplacement conditions, by the heterogeneous nature of the rock mass (mechanical properties may vary in space due to the presence of cracks, joints, faults, and various geologic layers) and also by the nonuniform in situ stress state. The last mechanism is increasingly important with depth when the difference in main principal stresses becomes significant. This paper is focused on the role of material strength of the rock mass in generation of nonradial motionmore » during explosions in prestressed media. Numerical modeling of underground chemical explosions in granite at various depths has been conducted to compare two possible mechanisms of shear wave generation. The first, caused by rock mass anisotropy, is important at shallow depth. The second is related to elastic-plastic relaxation around the cavity created by the explosion. As a result, tangential motions for these two mechanisms have different signatures.« less

  5. Environmental radionuclides as contaminants of HPGe gamma-ray spectrometers: Monte Carlo simulations for Modane underground laboratory.

    PubMed

    Breier, R; Brudanin, V B; Loaiza, P; Piquemal, F; Povinec, P P; Rukhadze, E; Rukhadze, N; Štekl, I

    2018-05-21

    The main limitation in the high-sensitive HPGe gamma-ray spectrometry has been the detector background, even for detectors placed deep underground. Environmental radionuclides such as 40 K and decay products in the 238 U and 232 Th chains have been identified as the most important radioactive contaminants of construction parts of HPGe gamma-ray spectrometers. Monte Carlo simulations have shown that the massive inner and outer lead shields have been the main contributors to the HPGe-detector background, followed by aluminum cryostat, copper cold finger, detector holder and the lead ring with FET. The Monte Carlo simulated cosmic-ray background gamma-ray spectrum has been by about three orders of magnitude lower than the experimental spectrum measured in the Modane underground laboratory (4800 m w.e.), underlying the importance of using radiopure materials for the construction of ultra-low-level HPGe gamma-ray spectrometers. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Low Background Counting at LBNL

    DOE PAGES

    Smith, A. R.; Thomas, K. J.; Norman, E. B.; ...

    2015-03-24

    The Low Background Facility (LBF) at Lawrence Berkeley National Laboratory in Berkeley, California provides low background gamma spectroscopy services to a wide array of experiments and projects. The analysis of samples takes place within two unique facilities; locally within a carefully-constructed, low background cave and remotely at an underground location that historically has operated underground in Oroville, CA, but has recently been relocated to the Sanford Underground Research Facility (SURF) in Lead, SD. These facilities provide a variety of gamma spectroscopy services to low background experiments primarily in the form of passive material screening for primordial radioisotopes (U, Th, K)more » or common cosmogenic/anthropogenic products, as well as active screening via Neutron Activation Analysis for specific applications. The LBF also provides hosting services for general R&D testing in low background environments on the surface or underground for background testing of detector systems or similar prototyping. A general overview of the facilities, services, and sensitivities is presented. Recent activities and upgrades will also be presented, such as the completion of a 3π anticoincidence shield at the surface station and environmental monitoring of Fukushima fallout. The LBF is open to any users for counting services or collaboration on a wide variety of experiments and projects.« less

  7. Toxic Substances Registry System: Index of Material Safety Data Sheets. Revised

    NASA Technical Reports Server (NTRS)

    1998-01-01

    The January 1998 revision of the Index of Materials Safety Data Sheets (MSDS) for the Kennedy Space Center (KSC) Toxic Substances Registry System (TSRS) is presented. The MSDS lists toxic substances by manufacturer, trade name, stock number, and distributor. The index provides information on hazards, use, and chemical composition of materials stored at KSC.

  8. Toxic Substances Registry System: Index of Material Safety Data Sheets. Volume 1; Manufacturer

    NASA Technical Reports Server (NTRS)

    1998-01-01

    The April 1998 revision of the Index of Materials Safety Data Sheets (MSDS) for the Kennedy Space Center (KSC) Toxic Substances Registry System (TSRS) is presented. The MSDS lists toxic substances by manufacturer, trade name, stock number, and distributor. The index provides information on hazards, use, and chemical composition of materials stored at KSC.

  9. Toxic Substances Registry System Index of Material Safety Data Sheets

    NASA Technical Reports Server (NTRS)

    1997-01-01

    The July 1997 revision of the Index of Material Safety Data Sheets (MSDS) for the Kennedy Space Center (KSC) Toxic Substances Registry System (TSRS) is presented. The MSDS lists toxic substances by manufacturer, trade name, stock number, and distributor. The index provides information on hazards, use, and chemical composition of materials stored at KSC.

  10. Operational Plan for Underground Storage Tank 322 R2U2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Griffin, D.

    2017-06-07

    This Operational Plan provides the operator of the tank system with guidelines relating to the safe and compliant operation and maintenance of the tank system. The tank system schematic and list of emergency contacts shall be posted near the tank so they are visible to tank personnel. This Operational Plan shall be kept on file by the Facility Supervisor. It should be understood when managing this tank system that it is used to store hazardous waste temporarily for 90 calendar days or less. The rinsewater handled in the tank system is considered hazardous and may exhibit the characteristic of toxicity.

  11. Microcomputer keeps watch at Emerald Mine

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1987-04-01

    This paper reviews the computerized mine monitoring system set up at the Emerald Mine, SW Pennsylvania, USA. This coal mine has pioneered the automation of many production and safety features and this article covers their work in fire detection and conveyor belt monitoring. A central computer control room can safely watch over the whole underground mining operation using one 25 inch colour monitor. These new data-acquisition systems will lead the way, in the future, to safer move efficient coal mining. Multi-point monitoring of carbon monoxide, heat anomalies, toxic gases and the procedures in conveyor belt operation from start-up to closedown.

  12. Greening coal: breakthroughs and challenges in carbon capture and storage.

    PubMed

    Stauffer, Philip H; Keating, Gordon N; Middleton, Richard S; Viswanathan, Hari S; Berchtold, Kathryn A; Singh, Rajinder P; Pawar, Rajesh J; Mancino, Anthony

    2011-10-15

    Like it or not, coal is here to stay, for the next few decades at least. Continued use of coal in this age of growing greenhouse gas controls will require removing carbon dioxide from the coal waste stream. We already remove toxicants such as sulfur dioxide and mercury, and the removal of CO₂ is the next step in reducing the environmental impacts of using coal as an energy source (i.e., greening coal). This paper outlines some of the complexities encountered in capturing CO₂ from coal, transporting it large distances through pipelines, and storing it safely underground.

  13. Ecological evaluation of proposed dredged material from St. Andrew Bay, Florida

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mayhew, H.L.; Word, J.Q.; Kohn, N.P.

    1993-10-01

    The US Army Corps of Engineers (USACE), Mobile District, requested that the Battelle/Marine Sciences Laboratory (MSL) conduct field sampling and chemical and biological testing to determine the suitability of potential dredged material for open ocean disposal. Sediment from St. Andrew Bay was chemically characterized and evaluated for biological toxicity and bioaccumulation of contaminants. The Tier III guidance for ocean disposal testing requires tests of water column effects (following dredged material disposal), deposited sediment toxicity, and bioaccumulation of contaminants from deposited sediment (dredged material). To meet these requirements, the MSL conducted suspended-particulate-phase (SPP) toxicity tests, solid-phase toxicity tests, and bioaccumulation testingmore » on sediment representing potential dredged material from Panama City Harbor. Physical and chemical characterization of sediment to support toxicity and bioaccumulation results was also conducted on both the test and reference sediments. The MSL collected sediment samples from five sites in St. Andrew Bay and one reference site near Lands End Peninsula. The five test sediments and the reference sediment were analyzed for physical and chemical sediment characteristics, SPP chemical contaminants, solid-phase toxicity, SPP toxicity, and bioaccumulation of contaminants.« less

  14. 36 CFR 292.16 - Standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., improvement and use of the property will not materially detract from the scenic, natural, historic, pastoral... underground. (5) No structures or other improvements will be constructed in or encroaching upon streambeds..., roads, and similar facilities or improvements. Any such necessary encroachment will avoid impeding water...

  15. Making It Underground: Comparative Material on the Informal Sector in Western Market Economies.

    ERIC Educational Resources Information Center

    Portes, Alejandro; Sassen-Koob, Saskia

    1987-01-01

    This paper examines the informal economy and its relationship to commonly held theories of industrial development. Evidence is presented which contradicts the prevailing assumption that informal economies will disappear with the advance of modern industrial growth. (Author/JDH)

  16. Sinkhole development induced by underground quarrying, and the related hazard

    NASA Astrophysics Data System (ADS)

    Parise, M.; Delle Rose, M.

    2009-04-01

    Sinkholes are extremely widespread in Apulia, a very flat and carbonate region, that acted as the foreland during the phases of building up of the Southern Apenninic Chain in Miocene time. This is due to the presence of soluble rocks throughout the region, that highly predispose the area to this very subtle natural hazard. In addition to the natural setting, which favours their development, sinkholes may also be induced by anthropogenic activities. In the latter sense, underground quarrying represents one of the most dangerous activities in karst areas. Apulia has a long history of quarrying. Since the roman time, the local rocks, from the Cretaceous micritic limestones to the Quaternary calcarenites, have been intensely quarried and used as building and ornamental materials. In several settings of the region, the rocks with the best petrographic characteristics are located at depths ranging from a few to some tens of meters. This caused the opening of many underground quarries, and the development of a complex network of subterranean galleries. Underground quarrying had a great impulse at the turn between the XIX and the XX century, when a large number of quarries was opened. Later on, after the Second World War, most of the quarries were progressively abandoned, even because of the first signs of instability, both underground and at the ground surface. With time, the memory of the presence and development of the underground quarries was progressively lost, with severe repercussions on the safety of the land above the excavated areas. Lack of knowledge of the subterranean pattern of galleries, combined with the expansion of the built-up areas at the surface, resulted in increasing significantly the vulnerability of exposed elements at risk. Events such as the 29 March, 2007, at Gallipoli only by chance did not result in any casualties, when a 15-mt wide and 5-mt deep sinkhole opened in a few hours at a road crossing, above the site of an old underground quarry. Within the framework of research programs devoted to recognition of sinkholes in Apulia, and addressed to the evaluation of the sinkhole hazard, this paper examines in detail the distribution of sinkholes related to underground quarrying in Salento, the southern part of Apulia, where the presence of subterranean quarries is particularly high. Through description of some case studies, the main problems related to underground quarries, and the development of sinkholes are discussed, even taking into account civil protection issues, that is in terms of the effects these phenomena may have on the local communities.

  17. Toxicity of the pyrolysis products of spacecraft materials

    NASA Technical Reports Server (NTRS)

    Lawrence, W. H.

    1974-01-01

    A number of spacecraft construction materials are evaluated for the toxic effects of their thermodegradation products on rats. Pyrolysis toxicity testing of pyrolysate fumes establish carbon monoxide, carbon dioxide and hydrogen cyanide as the most common intoxicating agents. Generally, COHb levels of animals expiring in the test chamber suggest higher concentrations of CO are produced with larger samples of most materials.

  18. Toxic Substances Registry System: Index of Material Safety Data Sheets. Revised

    NASA Technical Reports Server (NTRS)

    1997-01-01

    The October 1997 revision of the Index of Material Safety Data Sheets (MSDS) for the Kennedy Space Center (KSC) Toxic Substances Registry System (TSRS) is presented. The MSDS lists toxic substances by manufacturer, trade name, stock number, and distributor. The index provides information on the hazards, use, and chemical composition of materials stored and used at KSC.

  19. Simulation of Underground Muon Flux with Application to Muon Tomography

    NASA Astrophysics Data System (ADS)

    Yamaoka, J. A. K.; Bonneville, A.; Flygare, J.; Lintereur, A.; Kouzes, R.

    2015-12-01

    Muon tomography uses highly energetic muons, produced by cosmic rays interacting within the upper atmosphere, to image dense materials. Like x-rays, an image can be constructed from the negative of the absorbed (or scattered) muons. Unlike x-rays, these muons can penetrate thousands of meters of earth. Muon tomography has been shown to be useful across a wide range of applications (such as imaging of the interior of volcanoes and cargo containers). This work estimates the sensitivity of muon tomography for various underground applications. We use simulations to estimate the change in flux as well as the spatial resolution when imaging static objects, such as mine shafts, and dynamic objects, such as a CO2 reservoir filling over time. We present a framework where we import ground density data from other sources, such as wells, gravity and seismic data, to generate an expected muon flux distribution at specified underground locations. This information can further be fed into a detector simulation to estimate a final experimental sensitivity. There are many applications of this method. We explore its use to image underground nuclear test sites, both the deformation from the explosion as well as the supporting infrastructure (access tunnels and shafts). We also made estimates for imaging a CO2 sequestration site similar to Futuregen 2.0 in Illinois and for imaging magma chambers beneath the Cascade Range volcanoes. This work may also be useful to basic science, such as underground dark matter experiments, where increasing experimental sensitivity requires, amongst other factors, a precise knowledge of the muon background.

  20. Comparison and Tensorial Formulation of Inelastic Constitutive Models of Salt Rock Behaviour and Efficient Numerical Implementatio

    NASA Astrophysics Data System (ADS)

    Nagel, T.; Böttcher, N.; Görke, U. J.; Kolditz, O.

    2014-12-01

    The design process of geotechnical installations includes the application of numerical simulation tools for safety assessment, dimensioning and long term effectiveness estimations. Underground salt caverns can be used for the storage of natural gas, hydrogen, oil, waste or compressed air. For their design one has to take into account fluctuating internal pressures due to different levels of filling, the stresses imposed by the surrounding rock mass, irregular geometries and possibly heterogeneous material properties [3] in order to estimate long term cavern convergence as well as locally critical wall stresses. Constitutive models applied to rock salt are usually viscoplastic in nature and most often based on a Burgers-type rheological model extended by non-linear viscosity functions and/or plastic friction elements. Besides plastic dilatation, healing and damage are sometimes accounted for as well [2]. The scales of the geotechnical system to be simulated and the laboratory tests from which material parameters are determined are vastly different. The most common material testing modalities to determine material parameters in geoengineering are the uniaxial and the triaxial compression tests. Some constitutive formulations in widespread use are formulated based on equivalent rather than tensorial quantities valid under these specific test conditions and are subsequently applied to heterogeneous underground systems and complex 3D load cases. We show here that this procedure is inappropriate and can lead to erroneous results. We further propose alternative formulations of the constitutive models in question that restore their validity under arbitrary loading conditions. For an efficient numerical simulation, the discussed constitutive models are integrated locally with a Newton-Raphson algorithm that directly provides the algorithmically consistent tangent matrix for the global Newton iteration of the displacement based finite element formulation. Finally, the finite element implementations of the proposed constitutive formulations are employed to simulate an underground salt cavern used for compressed air energy storage with OpenGeoSys [1]. Transient convergence and stress fields are evaluated for typical fluctuating operation pressure regimes.

  1. 30 CFR 57.12004 - Electrical conductors.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Electrical conductors. 57.12004 Section 57... Surface and Underground § 57.12004 Electrical conductors. Electrical conductors shall be of a sufficient... operations will not damage the insulating materials. Electrical conductors exposed to mechanical damage shall...

  2. 30 CFR 77.1001 - Stripping; loose material.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....1001 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND COAL MINES... angle of repose, or barriers, baffle boards, screens, or other devices be provided that afford...

  3. Job Grading Standard for Electrician (High Voltage) WG-2810.

    ERIC Educational Resources Information Center

    Civil Service Commission, Washington, DC. Bureau of Policies and Standards.

    The standard covers nonsupervisory work involved in installation, test, repair, and maintenance of electric power plant and/or overhead and underground primary electrical distribution systems. These jobs require knowledge and application of electrical principles, procedures, materials, and safety standards governing work on electrical systems…

  4. 30 CFR 57.19096 - Familiarity with signal code.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 57.19096 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Personnel... signals for cages, skips, and mantrips when persons or materials are being transported shall be familiar...

  5. 30 CFR 57.12004 - Electrical conductors.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Electrical conductors. 57.12004 Section 57... Surface and Underground § 57.12004 Electrical conductors. Electrical conductors shall be of a sufficient... operations will not damage the insulating materials. Electrical conductors exposed to mechanical damage shall...

  6. 30 CFR 57.12004 - Electrical conductors.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Electrical conductors. 57.12004 Section 57... Surface and Underground § 57.12004 Electrical conductors. Electrical conductors shall be of a sufficient... operations will not damage the insulating materials. Electrical conductors exposed to mechanical damage shall...

  7. Biochar application to hardrock mine tailings: Soil quality, microbial activity, and toxic element sorption

    USGS Publications Warehouse

    Kelly, Charlene N.; Peltz, Christopher D.; Stanton, Mark R.; Rutherford, David W.; Rostad, Colleen E.

    2014-01-01

    Waste rock piles from historic mining activities remain unvegetated as a result of metal toxicity and high acidity. Biochar has been proposed as a low-cost remediation strategy to increase soil pH and reduce leaching of toxic elements, and improve plant establishment. In this laboratory column study, biochar made from beetle-killed pine wood was assessed for utility as a soil amendment by mixing soil material from two mine sites collected near Silverton, Colorado, USA with four application rates of biochar (0%, 10%, 20%, 30% vol:vol). Columns were leached seven times over 65 days and leachate pH and concentration of toxic elements and base cations were measured at each leaching. Nutrient availability and soil physical and biological parameters were determined following the incubation period. We investigated the hypotheses that biochar incorporation into acidic mine materials will (1) reduce toxic element concentrations in leaching solution, (2) improve soil parameters (i.e. increase nutrient and water holding capacity and pH, and decrease compaction), and (3) increase microbial populations and activity. Biochar directly increased soil pH (from 3.33 to 3.63 and from 4.07 to 4.77 in the two materials) and organic matter content, and decreased bulk density and extractable salt content in both mine materials, and increased nitrate availability in one material. No changes in microbial population or activity were detected in either mine material upon biochar application. In leachate solution, biochar increased base cations from both materials and reduced the concentrations of Al, Cd, Cu, Pb, and Zn in leachate solution from one material. However, in the material with greater toxic element content, biochar did not reduce concentrations of any measured dissolved toxic elements in leachate and resulted in a potentially detrimental release of Cd and Zn into solution at concentrations above that of the pure mine material. The length of time of effectiveness and specific sorption by biochar is variable by element and the toxic element concentration and acidity of the initial mine material.

  8. The Art Recipe Book, Volume One: 60 Non-toxic Art Materials from Readily Available Materials.

    ERIC Educational Resources Information Center

    Janeczko, Donna

    This collection of recipes is intended for art teachers to provide low-cost, non-toxic materials for classroom use. The materials needed are readily available and can be purchased in quantity to help the budget conscious teacher. Recipes included are for modeling materials, edible modeling materials, paints and inks, adhesives, fixatives, and…

  9. Toxicity of electronic waste leachates to Daphnia magna: screening and toxicity identification evaluation of different products, components, and materials.

    PubMed

    Lithner, Delilah; Halling, Maja; Dave, Göran

    2012-05-01

    Electronic waste has become one of the fastest growing waste problems in the world. It contains both toxic metals and toxic organics. The aim of this study was to (1) investigate to what extent toxicants can leach from different electronic products, components, and materials into water and (2) identify which group of toxicants (metals or hydrophobic organics) that is causing toxicity. Components from five discarded electronic products (cell phone, computer, phone modem, keyboard, and computer mouse) were leached in deionised water for 3 days at 23°C in concentrations of 25 g/l for metal components, 50 g/l for mixed-material components, and 100 g/l for plastic components. The water phase was tested for acute toxicity to Daphnia magna. Eighteen of 68 leachates showed toxicity (with immobility of D. magna ≥ 50% after 48 h) and came from metal or mixed-material components. The 8 most toxic leachates, with 48 h EC(50)s ranging from 0.4 to 20 g/l, came from 2 circuit sheets (key board), integrated drive electronics (IDE) cable clips (computer), metal studs (computer), a circuit board (computer mouse), a cord (phone modem), mixed parts (cell phone), and a circuit board (key board). All 5 electronic products were represented among them. Toxicity identification evaluations (with C18 and CM resins filtrations and ethylenediaminetetraacetic acid addition) indicated that metals caused the toxicity in the majority of the most toxic leachates. Overall, this study has shown that electronic waste can leach toxic compounds also during short-term leaching with pure water.

  10. Cosmogenic activation of materials

    NASA Astrophysics Data System (ADS)

    Cebrián, Susana

    2017-10-01

    Experiments looking for rare events like the direct detection of dark matter particles, neutrino interactions or the nuclear double beta decay are operated deep underground to suppress the effect of cosmic rays. But, the production of radioactive isotopes in materials due to previous exposure to cosmic rays is a hazard when ultra-low background conditions are required. In this context, the generation of long-lived products by cosmic nucleons has been studied for many detector media and for other materials commonly used. Here, the main results obtained on the quantification of activation yields on the Earth’s surface will be summarized, considering both measurements and calculations following different approaches. The isotope production cross-sections and the cosmic ray spectrum are the two main ingredients when calculating this cosmogenic activation; the different alternatives for implementing them will be discussed. Activation that can take place deep underground mainly due to cosmic muons will be briefly commented too. Presently, the experimental results for the cosmogenic production of radioisotopes are scarce and discrepancies between different calculations are important in many cases, but the increasing interest on this background source which is becoming more and more relevant can help to change this situation.

  11. Comparison of Thermal Stability of Dry High-strength Concrete and Wet High-strength Concrete

    NASA Astrophysics Data System (ADS)

    Musorina, Tatiana; Katcay, Aleksandr; Selezneva, Anna; Kamskov, Victor

    2018-03-01

    High-strength concrete is a modern material, which occupies it`s own niche on the construction material market. It is applicable in a large-scale high-rise construction, particularly an underground construction is a frequently used solution for a space saving. Usually underground structure is related to a wet usage environment. Though not all properties of the high-strength concrete are investigated to the full extent. Under adverse climatic conditions of the Russian Federation one of the most important properties for constructional materials is a thermal capacity. Therefore, the main purpose of the paper is to compare a thermal capacity of the high-strength concrete in humid conditions and a thermal capacity of the high-strength concrete in dry operational condition. During the study dependency between thermal capacity and design wall thickness and ambient humidity has to be proven with two experiments. As a result the theoretical relation between thermal capacity characteristic - thermal inertia and wall thickness and ambient humidity was confirmed by the experimental data. The thermal capacity of a building is in direct ratio to the construction thickness. It follows from the experiments and calculations that wet high-strength concrete has less thermal stability.

  12. Evaluation of detection and response times of fire sensors using an atmospheric monitoring system

    PubMed Central

    Rowland, J.H.; Litton, C.D.; Thomas, R.A.

    2017-01-01

    Atmospheric monitoring systems (AMS) are required when using air from conveyor belt entries to ventilate working sections in U.S. underground coal mines. AMS technology has the potential to increase fire safety mine-wide, but research is needed to determine the detection and response times for fires of a variety of combustible materials. To evaluate the potential of an AMS for fire detection in other areas of a coal mine, a series of full-scale fire experiments were conducted to determine detection and response times from fires of different combustible materials that are found in U.S. underground coal mines, including high- and low-volatility coals, conveyor belts, brattice materials, different types of wood, diesel fuel, and a foam sealant. These experiments were conducted in the Safety Research Coal Mine (SRCM) of the U.S. National Institute for Occupational Safety and Health (NIOSH) located in Pittsburgh, PA, using a commercially available AMS that is typical of current technology. The results showed that through proper selection of sensors and their locations, a mine-wide AMS can provide sufficient early fire warning times and improve the health and safety of miners. PMID:28529442

  13. Evaluation of detection and response times of fire sensors using an atmospheric monitoring system.

    PubMed

    Rowland, J H; Litton, C D; Thomas, R A

    2016-01-01

    Atmospheric monitoring systems (AMS) are required when using air from conveyor belt entries to ventilate working sections in U.S. underground coal mines. AMS technology has the potential to increase fire safety mine-wide, but research is needed to determine the detection and response times for fires of a variety of combustible materials. To evaluate the potential of an AMS for fire detection in other areas of a coal mine, a series of full-scale fire experiments were conducted to determine detection and response times from fires of different combustible materials that are found in U.S. underground coal mines, including high- and low-volatility coals, conveyor belts, brattice materials, different types of wood, diesel fuel, and a foam sealant. These experiments were conducted in the Safety Research Coal Mine (SRCM) of the U.S. National Institute for Occupational Safety and Health (NIOSH) located in Pittsburgh, PA, using a commercially available AMS that is typical of current technology. The results showed that through proper selection of sensors and their locations, a mine-wide AMS can provide sufficient early fire warning times and improve the health and safety of miners.

  14. Immobilized materials for removal of toxic metal ions from surface/groundwaters and aqueous waste streams.

    PubMed

    Zawierucha, Iwona; Kozlowski, Cezary; Malina, Grzegorz

    2016-04-01

    Heavy metals from industrial processes are of special concern because they produce chronic poisoning in the aquatic environment. More strict environmental regulations on the discharge of toxic metals require the development of various technologies for their removal from polluted streams (i.e. industrial wastewater, mine waters, landfill leachate, and groundwater). The separation of toxic metal ions using immobilized materials (novel sorbents and membranes with doped ligands), due to their high selectivity and removal efficiency, increased stability, and low energy requirements, is promising for improving the environmental quality. This critical review is aimed at studying immobilized materials as potential remediation agents for the elimination of numerous toxic metal (e.g. Pb, Cd, Hg, and As) ions from polluted streams. This study covers the general characteristics of immobilized materials and separation processes, understanding of the metal ion removal mechanisms, a review of the application of immobilized materials for the removal of toxic metal ions, as well as the impacts of various parameters on the removal efficiency. In addition, emerging trends and opportunities in the field of remediation technologies using these materials are addressed.

  15. Toxic substances alert program

    NASA Technical Reports Server (NTRS)

    Junod, T. L.

    1978-01-01

    A toxicity profile is provided, of 187 toxic substances procured by NASA Lewis Research Center during a 3 1/2 year period, including 27 known or suspected carcinogens. The goal of the program is to assure that the center's health and safety personnel are aware of the procurement and use of toxic substances and to alert and inform the users of these materials as to the toxic characteristics and the control measures needed to ensure their safe use. The program also provides a continuing record of the toxic substances procured, who procured them, what other toxic substances the user has obtained in the past, and where similar materials have been used elsewhere at the center.

  16. 30 CFR 57.16013 - Working with molten metal.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Working with molten metal. 57.16013 Section 57.16013 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  17. 30 CFR 57.16013 - Working with molten metal.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Working with molten metal. 57.16013 Section 57.16013 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  18. 30 CFR 57.6801 - Vehicle repair.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Vehicle repair. 57.6801 Section 57.6801 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... and Underground § 57.6801 Vehicle repair. Vehicles containing explosive material and oxidizers shall...

  19. 30 CFR 57.6801 - Vehicle repair.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Vehicle repair. 57.6801 Section 57.6801 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... and Underground § 57.6801 Vehicle repair. Vehicles containing explosive material and oxidizers shall...

  20. 30 CFR 57.6801 - Vehicle repair.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Vehicle repair. 57.6801 Section 57.6801 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... and Underground § 57.6801 Vehicle repair. Vehicles containing explosive material and oxidizers shall...

  1. 30 CFR 57.6801 - Vehicle repair.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Vehicle repair. 57.6801 Section 57.6801 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... and Underground § 57.6801 Vehicle repair. Vehicles containing explosive material and oxidizers shall...

  2. 30 CFR 57.6801 - Vehicle repair.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Vehicle repair. 57.6801 Section 57.6801 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... and Underground § 57.6801 Vehicle repair. Vehicles containing explosive material and oxidizers shall...

  3. 1. VIEW OF ONE OF THE INNER ROOMS WITHIN VAULT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW OF ONE OF THE INNER ROOMS WITHIN VAULT 996. THE UNDERGROUND VAULTS WERE USED TO STORE SPECIAL NUCLEAR MATERIAL AWAITING ON- AND OFF-SITE SHIPMENT. - Rocky Flats Plant, Storage Vault, Southeast corner of protected area, Northwest of Building 991, Golden, Jefferson County, CO

  4. 30 CFR 75.404 - Exemption of anthracite mines.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Exemption of anthracite mines. 75.404 Section 75.404 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  5. 30 CFR 75.404 - Exemption of anthracite mines.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Exemption of anthracite mines. 75.404 Section 75.404 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  6. 30 CFR 75.404 - Exemption of anthracite mines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Exemption of anthracite mines. 75.404 Section 75.404 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  7. 30 CFR 75.404 - Exemption of anthracite mines.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Exemption of anthracite mines. 75.404 Section 75.404 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  8. 30 CFR 75.404 - Exemption of anthracite mines.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exemption of anthracite mines. 75.404 Section 75.404 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  9. 30 CFR 77.1435 - Load end attachments.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND COAL MINES Personnel... where use of other materials is a design feature, zinc (spelter) shall be used for socketing wire ropes. Design feature means either the manufacturer's original design or a design approved by a registered...

  10. 30 CFR 715.19 - Use of explosives.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... wells, petroleum or gas-storage facilities, municipal water-storage facilities, fluid-transmission pipelines, gas or oil-collection lines, or water and sewage lines; and (C) 500 feet of an underground mine... explosive materials shall— (i) Have demonstrated a knowledge of, and a willingness to comply with, safety...

  11. 30 CFR 57.4533 - Mine opening vicinity.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and... materials; or (b) Constructed to meet a fire resistance rating of no less than one hour; or (c) Provided...

  12. 30 CFR 77.1104 - Accumulations of combustible materials.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., grease, lubricants, paints, or flammable liquids shall not be allowed to accumulate where they can create... Section 77.1104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND...

  13. 30 CFR 77.1104 - Accumulations of combustible materials.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., grease, lubricants, paints, or flammable liquids shall not be allowed to accumulate where they can create... Section 77.1104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND...

  14. 30 CFR 77.1104 - Accumulations of combustible materials.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., grease, lubricants, paints, or flammable liquids shall not be allowed to accumulate where they can create... Section 77.1104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND...

  15. 30 CFR 77.1104 - Accumulations of combustible materials.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., grease, lubricants, paints, or flammable liquids shall not be allowed to accumulate where they can create... Section 77.1104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND...

  16. 30 CFR 77.1104 - Accumulations of combustible materials.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., grease, lubricants, paints, or flammable liquids shall not be allowed to accumulate where they can create... Section 77.1104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND...

  17. 30 CFR 57.16012 - Storage of incompatible substances.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Section 57.16012 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials... concentrated acids and alkalies, shall be stored to prevent inadvertent contact with each other or with other...

  18. 30 CFR 57.16012 - Storage of incompatible substances.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Section 57.16012 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials... concentrated acids and alkalies, shall be stored to prevent inadvertent contact with each other or with other...

  19. Basic Books in the Mass Media.

    ERIC Educational Resources Information Center

    Blum, Eleanor

    References to information on the background, structure, function, contents, and effects of mass communications are provided in this annotated booklist. Material is included on theory, popular culture, the Black press, communications technology, the underground press and film, and mass media violence and the entries are arranged according to the…

  20. Inexpensive Device for Demonstrating Rock Slope Failure and Other Collapse Phenomena.

    ERIC Educational Resources Information Center

    Stimpson, B.

    1980-01-01

    Describes an inexpensive modeling technique for demonstrating large-scale displacement phenomena in rock masses, such as slope collapse and failure of underground openings. Excavation of the model material occurs through openings made in the polyurethane foam in the correct excavation sequence. (Author/SA)

  1. Low-background gamma spectroscopy at the Boulby Underground Laboratory

    NASA Astrophysics Data System (ADS)

    Scovell, P. R.; Meehan, E.; Araújo, H. M.; Dobson, J.; Ghag, C.; Kraus, H.; Kudryavtsev, V. A.; Liu, X.-. R.; Majewski, P.; Paling, S. M.; Preece, R. M.; Saakyan, R.; Tomás, A.; Toth, C.; Yeoman, L. M.

    2018-01-01

    The Boulby Underground Germanium Suite (BUGS) comprises three low-background, high-purity germanium detectors operating in the Boulby Underground Laboratory, located 1.1 km underground in the north-east of England, UK. BUGS utilises three types of detector to facilitate a high-sensitivity, high-throughput radio-assay programme to support the development of rare-event search experiments. A Broad Energy Germanium (BEGe) detector delivers sensitivity to low-energy gamma-rays such as those emitted by 210Pb and 234Th. A Small Anode Germanium (SAGe) well-type detector is employed for efficient screening of small samples. Finally, a standard p-type coaxial detector provides fast screening of standard samples. This paper presents the steps used to characterise the performance of these detectors for a variety of sample geometries, including the corrections applied to account for cascade summing effects. For low-density materials, BUGS is able to radio-assay to specific activities down to 3.6mBqkg-1 for 234Th and 6.6mBqkg-1 for 210Pb both of which have uncovered some significant equilibrium breaks in the 238U chain. In denser materials, where gamma-ray self-absorption increases, sensitivity is demonstrated to specific activities of 0.9mBqkg-1 for 226Ra, 1.1mBqkg-1 for 228Ra, 0.3mBqkg-1 for 224Ra, and 8.6mBqkg-1 for 40K with all upper limits at a 90% confidence level. These meet the requirements of most screening campaigns presently under way for rare-event search experiments, such as the LUX-ZEPLIN (LZ) dark matter experiment. We also highlight the ability of the BEGe detector to probe the X-ray fluorescence region which can be important to identify the presence of radioisotopes associated with neutron production; this is of particular relevance in experiments sensitive to nuclear recoils.

  2. RIFM fragrance ingredient safety assessment, 1-(1,2,3,4-tetrahydro-4,4-dimethyl-1-naphthyl)propan-1-one, CAS Registry Number 74499-60-8.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data from the target material and the suitable read across analog 6-acetyl-1,1,2,4,4,7-hexamethyltetraline (CAS # 21145-77-7) show that this material is not genotoxic. Data from the suitable read across analog 6-acetyl-1,1,2,4,4,7-hexamethyltetraline (CAS # 21145-77-7) provided a MOE > 100 for the repeat dose and developmental toxicity endpoints. The reproductive and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class II material (0.009 mg/kg/day and 0.47 mg/day, respectively). Data on the target material showed that this material is below the non-reactive DST for skin sensitization and did not have the potential for phototoxicity or photoallergenicity. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. A molecular study on bacterial resistance to arsenic-toxicity in surface and underground waters of Latium (Italy).

    PubMed

    Davolos, Domenico; Pietrangeli, Biancamaria

    2013-10-01

    Latium, a region in central Italy, is known for its extensive volcanic areas that make a significant contribution to the arsenic (As) contamination of freshwater environments, even though some degree of As water pollution may be caused by human activities. The information available on indigenous As-resistant prokaryotes in aquatic environments of Latium is, however, still limited. In this study, we describe new bacteria that are resistant to arsenic toxicity and were isolated from the surface waters of Lake Vico and the Sacco River, two groundwater systems in Latium, as well as from bottled natural mineral water from the same region. The 16S rRNA gene sequence analysis for the As-resistant strains in lake and river waters points to a prevalence of β- and γ-Proteobacteria, while α-Proteobacteria, Firmicutes and Bacteroidetes are represented to a lesser extent. By contrast, solely γ-Proteobacteria were isolated from groundwater samples. The presence of Actinobacteria was documented exclusively in bottled mineral water. In addition, we conducted a DNA sequence-based study on the gene codifying arsB, an As(III) efflux membrane protein pump related to arsenic resistance, for all the As-resistant bacterial isolates. A phylogenetic analysis was carried out on the newly sequenced 16S rRNA genes and arsB in the present study as well as on an additional 16S rRNA/arsB dataset we obtained previously from Lake Albano, from the Tiber and from a well in Bassano Romano located in Latium (Davolos and Pietrangeli, 2011). Overall, the phylogenetic diversity of As-resistant bacteria in underground water was very limited if compared with lentic and lotic waters. Lastly, our molecular data support the hypothesis that the horizontal gene transfer of ars in As-containing freshwater environments is not limited to closely-related genomes, but also occurs between bacteria that are distant from an evolutionary viewpoint, thereby indicating that such genetic events may be considered a source of microbial resistance to arsenic-toxicity. Copyright © 2013 Elsevier Inc. All rights reserved.

  4. Fossil energy program

    NASA Astrophysics Data System (ADS)

    McNeese, L. E.

    1981-12-01

    The progress made during the period from July 1 through September 30 for the Oak Ridge National Laboratory research and development projects in support of the increased utilization of coal and other fossil fuels as sources of clean energy is reported. The following topics are discussed: coal conversion development, chemical research and development, materials technology, fossil energy materials program, liquefaction projects, component development, process analysis, environmental control technology, atmospheric fluidized bed combustion, underground coal gasification, coal preparation and waste utilization.

  5. Decontamination of Subway Infrastructure Materials ...

    EPA Pesticide Factsheets

    Report This report provides the results of an assessment to determine the decontamination efficacy of methyl bromide (MB) fumigant in inactivating Bacillus anthracis (B.a.; causative agent for anthrax) spores on materials typically found in subway system infrastructure. To facilitate future decontaminations employing MB in a subway environment, this investigation focused on finding efficacious conditions when using MB at temperatures that may be encountered in an underground subway system (i.e., temperatures lower than used in previous studies).

  6. Low background screening capability in the UK

    NASA Astrophysics Data System (ADS)

    Ghag, Chamkaur

    2015-08-01

    Low background rare event searches in underground laboratories seeking observation of direct dark matter interactions or neutrino-less double beta decay have the potential to profoundly advance our understanding of the physical universe. Successful results from these experiments depend critically on construction from extremely radiologically clean materials and accurate knowledge of subsequent low levels of expected background. The experiments must conduct comprehensive screening campaigns to reduce radioactivity from detector components, and these measurements also inform detailed characterisation and quantification of background sources and their impact, necessary to assign statistical significance to any potential discovery. To provide requisite sensitivity for material screening and characterisation in the UK to support our rare event search activities, we have re-developed our infrastructure to add ultra-low background capability across a range of complementary techniques that collectively allow complete radioactivity measurements. Ultra-low background HPGe and BEGe detectors have been installed at the Boulby Underground Laboratory, itself undergoing substantial facility re-furbishment, to provide high sensitivity gamma spectroscopy in particular for measuring the uranium and thorium decay series products. Dedicated low-activity mass spectrometry instrumentation has been developed at UCL for part per trillion level contaminant identification to complement underground screening with direct U and Th measurements, and meet throughput demands. Finally, radon emanation screening at UCL measures radon background inaccessible to gamma or mass spectrometry techniques. With this new capability the UK is delivering half of the radioactivity screening for the LZ dark matter search experiment.

  7. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ghag, Chamkaur

    Low background rare event searches in underground laboratories seeking observation of direct dark matter interactions or neutrino-less double beta decay have the potential to profoundly advance our understanding of the physical universe. Successful results from these experiments depend critically on construction from extremely radiologically clean materials and accurate knowledge of subsequent low levels of expected background. The experiments must conduct comprehensive screening campaigns to reduce radioactivity from detector components, and these measurements also inform detailed characterisation and quantification of background sources and their impact, necessary to assign statistical significance to any potential discovery. To provide requisite sensitivity for material screeningmore » and characterisation in the UK to support our rare event search activities, we have re-developed our infrastructure to add ultra-low background capability across a range of complementary techniques that collectively allow complete radioactivity measurements. Ultra-low background HPGe and BEGe detectors have been installed at the Boulby Underground Laboratory, itself undergoing substantial facility re-furbishment, to provide high sensitivity gamma spectroscopy in particular for measuring the uranium and thorium decay series products. Dedicated low-activity mass spectrometry instrumentation has been developed at UCL for part per trillion level contaminant identification to complement underground screening with direct U and Th measurements, and meet throughput demands. Finally, radon emanation screening at UCL measures radon background inaccessible to gamma or mass spectrometry techniques. With this new capability the UK is delivering half of the radioactivity screening for the LZ dark matter search experiment.« less

  8. Selected chemical characteristics and acute toxicity of urban stormwater, streamflow, and bed material, Maricopa County, Arizona

    USGS Publications Warehouse

    Lopes, T.J.; Fossum, K.D.

    1995-01-01

    Statistical analyses indicated that urban stormwater could degrade the quality of streamflow because of oil and grease, pesticides, dissolved trace metals, and ammonia in stormwater. Ammonia, lead, cadmium, and zinc are released by urban activities and accumulate in bed material. Ammonia could be from fertilizers, fecal matter, and other sources. Lead is probably from vehicles that use leaded gasoline. Cadmium and zinc could be from particulate metal in oil, brake pads, and other sources. Samples of the initial runoff from urban drainage basins appeared to be more toxic than flow-weighted composite samples, and stormwater was more harmful to fathead minnows than to Ceriodaphnia dubia. Streamflow samples from the Salt River were not toxic to either species. The sensitivity of fathead minnows to urban stormwater from most urban drainage basins indicated that the toxicants were detrimental to fish and could be present in stormwater throughout Phoenix. Results of toxicity identification evaluations indicated the toxicity was mostly due to organic constituents. Mortality, however, did not correlate with organophosphate pesticide concentrations. Surfactants and (or) other constituents leached from asphalt could be toxic. The most toxic bed-material samples were collected from an undeveloped drainage basin. Within urban-drainage basins, bed-material samples collected where stormwater accumulates appeared to be more toxic than samples collected from areas unaffected by stormwater. Mortality rates correlated with recoverable concentrations of zinc, copper, and cadmium; however these rates correlated poorly with pesticide concentrations. The bioavailability of trace metals appeared to be controlled by the adsorption properties of bed material.

  9. Harvester ant bioassay for assessing hazardous chemical waste sites. [Pogonomyrmex owhyeei

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gano, K.A.; Carlile, D.W.; Rogers, L.E.

    1985-05-01

    A technique was developed for using harvester ants, Pogonomyrmex owhyeei, in terrestrial bioassays. Procedures were developed for maintaining stock populations, handling ants, and exposing ants to toxic materials. Relative toxicities were determined by exposing ants to 10 different materials. These materials included three insecticides, Endrin, Aldrin, and Dieldrin; one herbicide, 2,4-D; three complex industrial waste residuals, wood preservative sludge, drilling fluid, and slop oil; and three heavy metals, copper zinc, and cadium. Ants were exposed in petri dishes containing soil amended with a particular toxicant. Under these test conditions, ants showed no sensitivity to the metals or 2,4-D. Ants weremore » sensitive to the insecticides and oils in repeated tests, and relative toxicity remained consistent throughout. Aldrin was the most toxic material followed by Dieldrin, Endrin, wood preservative sludge, drilling fluid, and slop oil. 12 refs., 2 figs., 2 tabs.« less

  10. Harvester ant bioassay for assessing hazardous chemical waste sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gano, K.A.; Carlile, D.W.; Rogers, L.E.

    1984-12-01

    A technique was developed for using harvester ants, Pogonomyrmex owhyeei, in terrestrial bioassays. Procedures were developed for maintaining stock populations, handling ants, and exposing ants to toxic materials. Relative toxicities were determined by exposing ants to 10 different materials. These materials included three insecticides, Endrin, Aldrin, and Dieldrin; one herbicide, 2,4-D; three oil-like compounds, wood preservative, drilling fluid, and slop oil; and three heavy metals, copper, zinc, and cadmium. Ants were exposed in petri dishes containing soil amended with a particular toxicant. Under these test conditions, ants showed no sensitivity to the metals or 2,4-D. Ants were sensitive to themore » insecticides and oils in repeated tests, and relative toxicity remained consistent throughout. Aldrin was the most toxic material, followed by Dieldrin, Endrin, wood preservative, drilling fluid, and slop oil. 10 refs., 2 figs., 2 tabs.« less

  11. RIFM fragrance ingredient safety assessment, ethylene brassylate, CAS Registry Number 105-95-3.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    : The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic nor does it have skin sensitization potential. The local respiratory toxicity endpoint was completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (1.4 mg/day). The repeated dose toxicity endpoint was completed using ethylene dodecanedioate (CAS # 54982-83-1) as a suitable read across analog, which provided a MOE > 100. The developmental and reproductive toxicity endpoint was completed using oxacyclohexadec-12-en-2-one, (12E)- (CAS # 111879-80-2) as a suitable read across analog, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra along with data on the target material. The environmental endpoint was completed as described in the RIFM Framework along with data on the suitable read across analog oxacyclohexadec-12-en-2-one, (12E)- (CAS # 111879-80-2). Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Dredged Material Analysis Tools; Performance of Acute and Chronic Sediment Toxicity Methods

    DTIC Science & Technology

    2008-07-01

    Chronic Sediment Toxicity Methods Jeffery Steevens, Alan Kennedy, Daniel Farrar, Cory McNemar, Mark R. Reiss, Roy K. Kropp, Jon Doi, and Todd Bridges...Environmental Research Program ERDC/EL TR-08-16 July 2008 Revised Dredged Material Analysis Tools Performance of Acute and Chronic Sediment Toxicity ...insight into the potential advan- tages and disadvantages of using chronic sediment toxicity tests with relevant benthic macroinvertebrates as part of

  13. Early Combination of Material Characteristics and Toxicology Is Useful in the Design of Low Toxicity Carbon Nanofiber

    PubMed Central

    Jensen, Ellen K.; Larsen, Sten Y.; Nygaard, Unni C.; Marioara, Calin D.; Syversen, Tore

    2012-01-01

    This paper describes an approach for the early combination of material characterization and toxicology testing in order to design carbon nanofiber (CNF) with low toxicity. The aim was to investigate how the adjustment of production parameters and purification procedures can result in a CNF product with low toxicity. Different CNF batches from a pilot plant were characterized with respect to physical properties (chemical composition, specific surface area, morphology, surface chemistry) as well as toxicity by in vitro and in vivo tests. A description of a test battery for both material characterization and toxicity is given. The results illustrate how the adjustment of production parameters and purification, thermal treatment in particular, influence the material characterization as well as the outcome of the toxic tests. The combination of the tests early during product development is a useful and efficient approach when aiming at designing CNF with low toxicity. Early quality and safety characterization, preferably in an iterative process, is expected to be efficient and promising for this purpose. The toxicity tests applied are preliminary tests of low cost and rapid execution. For further studies, effects such as lung inflammation, fibrosis and respiratory cancer are recommended for the more in-depth studies of the mature CNF product.

  14. Ground-water situation in Oregon

    USGS Publications Warehouse

    Newcomb, R.C.

    1951-01-01

    The water that occurs beneath the land surface follows definite and well-known rules of hydraulics, the same as water on the surface. However, ground water must be studied by methods, some of which are unique to that type of water occurrence, in order to evaluate the part it plays in the over-all water scheme.Water that falls on the land surface as rain or snow and water that rests upon the surface may in places pass laterally or downward through the pores of the earth materials. There it may take one or more of a variety of paths before again flowing out on the surface or being expelled to the atmosphere by evaporation and by the transpiration of plants. Water so diverted underground is delayed or diverted from its course toward the sea and that digression results in many services of prime importance to mankind. Underground, the water generally exceeds in total quantity the water present on the land surface at any one time.The discussion of ground water can be clarified somewhat by a description of the major parts or phases of the normal path of water underground.

  15. An Effective Belt Conveyor for Underground Ore Transportation Systems

    NASA Astrophysics Data System (ADS)

    Krol, Robert; Kawalec, Witold; Gladysiewicz, Lech

    2017-12-01

    Raw material transportation generates a substantial share of costs in the mining industry. Mining companies are therefore determined to improve the effectiveness of their transportation system, focusing on solutions that increase both its energy efficiency and reliability while keeping maintenance costs low. In the underground copper ore operations in Poland’s KGHM mines vast and complex belt conveyor systems have been used for horizontal haulage of the run-of-mine ore from mining departments to shafts. Basing upon a long-time experience in the field of analysing, testing, designing and computing of belt conveyor equipment with regard to specific operational conditions, the improvements to the standard design of an underground belt conveyor for ore transportation have been proposed. As the key elements of a belt conveyor, the energy-efficient conveyor belt and optimised carrying idlers have been developed for the new generation of underground conveyors. The proposed solutions were tested individually on the specially constructed test stands in the laboratory and in the experimental belt conveyor that was built up with the use of prototype parts and commissioned for the regular ore haulage in a mining department in the KGHM underground mine “Lubin”. Its work was monitored and the recorded operational parameters (loadings, stresses and strains, energy dissipation, belt tracking) were compared with those previously collected on a reference (standard) conveyor. These in-situ measurements have proved that the proposed solutions will return with significant energy savings and lower maintenance costs. Calculations made on the basis of measurement results in the specialized belt conveyor designing software allow to estimate the possible savings if the modernized conveyors supersede the standard ones in a large belt conveying system.

  16. RIFM fragrance ingredient safety assessment, isobornyl isovalerate, CAS registry number 7779-73-9.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lapczynski, A; Liebler, D C; O'Brien, D; Parakhia, R; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2017-12-01

    This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization potential, as well as, environmental safety. Data from the suitable read across analog isobornyl acetate (CAS # 125-12-2) show that this material is not genotoxic, provided a MOE > 100 for the repeated dose, developmental and reproductive endpoints, and does not have skin sensitization potential. The local respiratory toxicity endpoint was completed using the TTC (threshold of Toxicological Concern) for a Cramer Class II material (0.47 mg/day). The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Flow Line, Durafill VS, and Dycal toxicity to dental pulp cells: effects of growth factors

    PubMed Central

    Furey, Alyssa; Hjelmhaug, Julie; Lobner, Doug

    2010-01-01

    Introduction The objective was to determine the effects of growth factor treatment on dental pulp cell sensitivity to toxicity of two composite restoration materials, Flow Line and Durafill VS, and a calcium hydroxide pulp capping material, Dycal. Methods Toxicity of the dental materials to cultures of primary dental pulp cells was determined by the MTT metabolism assay. The ability of six different growth factors to influence the toxicity was tested. Results A 24 hour exposure to either Flow Line or Durafill VS caused approximately 40% cell death, while Dycal exposure caused approximately 80% cell death. The toxicity of Flow Line and Durafill VS was mediated by oxidative stress. Four of the growth factors tested (BMP-2, BMP-7, EGF, and TGF-β) decreased the basal MTT values while making the cells resistant to Flow Line and Durafill VS toxicity, except BMP-2 which made the cells more sensitive to Flow Line. Treatment with FGF-2 caused no change in basal MTT metabolism, prevented the toxicity of Durafill VS, but increased the toxicity of Flow Line. Treatment with IGF-I increased basal MTT metabolism and made the cells resistant to Flow Line and Durafill VS toxicity. None of the growth factors made the cells resistant to Dycal toxicity. Conclusions The results indicate that growth factors can be used to alter the sensitivity of dental pulp cells to commonly used restoration materials. The growth factors BMP-7, EGF, TGF-β, and IGF-I provided the best profile of effects, making the cells resistant to both Flow Line and Durafill VS toxicity. PMID:20630288

  18. From Seat Belts to Safe Brakes, Here's the Latest School Bus News.

    ERIC Educational Resources Information Center

    Zakariya, Sally Banks

    1985-01-01

    Provides an update on emerging safety issues, new technological developments, and upcoming regulations that could affect school transportation programs. Two new sets of federal regulations to watch for will govern underground fuel storage tanks and hazardous materials, and restrict asbestos in vehicle brake linings. (MD)

  19. 30 CFR 57.9160 - Train movement during shift changes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Train movement during shift changes. 57.9160 Section 57.9160 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND..., the movement of underground trains carrying rock or material shall be limited to areas where the...

  20. 30 CFR 57.9160 - Train movement during shift changes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Train movement during shift changes. 57.9160 Section 57.9160 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND..., the movement of underground trains carrying rock or material shall be limited to areas where the...

  1. 30 CFR 57.9160 - Train movement during shift changes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Train movement during shift changes. 57.9160 Section 57.9160 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND..., the movement of underground trains carrying rock or material shall be limited to areas where the...

  2. 30 CFR 57.9160 - Train movement during shift changes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Train movement during shift changes. 57.9160 Section 57.9160 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND..., the movement of underground trains carrying rock or material shall be limited to areas where the...

  3. 30 CFR 57.9160 - Train movement during shift changes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Train movement during shift changes. 57.9160 Section 57.9160 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND..., the movement of underground trains carrying rock or material shall be limited to areas where the...

  4. 76 FR 71707 - Revising Underground Storage Tank Regulations-Revisions to Existing Requirements and New...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-18

    ... Equipment C. Addressing Deferrals 1. Emergency Power Generator UST Systems 2. Airport Hydrant Fuel.... Maintain Deferral for USTs Containing Radioactive Material and Emergency Generator UST Systems at Nuclear... (air, water, 481, 483-486, 48811. truck, transit, pipeline, and airport operations). Communications and...

  5. 30 CFR 75.400-2 - Cleanup program.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

  6. 30 CFR 75.402-2 - Exceptions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Exceptions. 75.402-2 Section 75.402-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-2 Exceptions...

  7. 30 CFR 75.400-2 - Cleanup program.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

  8. 30 CFR 75.400-2 - Cleanup program.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

  9. 30 CFR 75.400-2 - Cleanup program.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

  10. 30 CFR 75.402-1 - Definition.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Definition. 75.402-1 Section 75.402-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-1 Definition. The...

  11. 30 CFR 75.402-1 - Definition.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Definition. 75.402-1 Section 75.402-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-1 Definition. The...

  12. 30 CFR 75.402-1 - Definition.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Definition. 75.402-1 Section 75.402-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-1 Definition. The...

  13. 30 CFR 75.402-1 - Definition.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Definition. 75.402-1 Section 75.402-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-1 Definition. The...

  14. 30 CFR 75.401-1 - Excessive amounts of dust.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Excessive amounts of dust. 75.401-1 Section 75.401-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  15. 30 CFR 75.402 - Rock dusting.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Rock dusting. 75.402 Section 75.402 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402 Rock dusting... or too high in incombustible content to propagate an explosion, shall be rock dusted to within 40...

  16. 30 CFR 75.401-1 - Excessive amounts of dust.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Excessive amounts of dust. 75.401-1 Section 75.401-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  17. 30 CFR 75.402-2 - Exceptions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Exceptions. 75.402-2 Section 75.402-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-2 Exceptions...

  18. 30 CFR 75.401-1 - Excessive amounts of dust.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Excessive amounts of dust. 75.401-1 Section 75.401-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  19. 30 CFR 75.402-2 - Exceptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exceptions. 75.402-2 Section 75.402-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-2 Exceptions...

  20. 30 CFR 75.401-1 - Excessive amounts of dust.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Excessive amounts of dust. 75.401-1 Section 75.401-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  1. 30 CFR 75.402-1 - Definition.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Definition. 75.402-1 Section 75.402-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-1 Definition. The...

  2. 30 CFR 75.400-1 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Definitions. 75.400-1 Section 75.400-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-1 Definitions. (a...

  3. 30 CFR 75.400-1 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Definitions. 75.400-1 Section 75.400-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-1 Definitions. (a...

  4. 30 CFR 75.402-2 - Exceptions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Exceptions. 75.402-2 Section 75.402-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-2 Exceptions...

  5. 30 CFR 75.400-1 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Definitions. 75.400-1 Section 75.400-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-1 Definitions. (a...

  6. 30 CFR 75.400-1 - Definitions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Definitions. 75.400-1 Section 75.400-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-1 Definitions. (a...

  7. 30 CFR 75.402 - Rock dusting.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Rock dusting. 75.402 Section 75.402 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402 Rock dusting... or too high in incombustible content to propagate an explosion, shall be rock dusted to within 40...

  8. 30 CFR 75.402 - Rock dusting.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Rock dusting. 75.402 Section 75.402 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402 Rock dusting... or too high in incombustible content to propagate an explosion, shall be rock dusted to within 40...

  9. 30 CFR 75.400-2 - Cleanup program.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Cleanup program. 75.400-2 Section 75.400-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-2 Cleanup...

  10. 30 CFR 75.402 - Rock dusting.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Rock dusting. 75.402 Section 75.402 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402 Rock dusting... or too high in incombustible content to propagate an explosion, shall be rock dusted to within 40...

  11. 30 CFR 75.402 - Rock dusting.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Rock dusting. 75.402 Section 75.402 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402 Rock dusting... or too high in incombustible content to propagate an explosion, shall be rock dusted to within 40...

  12. 30 CFR 75.402-2 - Exceptions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Exceptions. 75.402-2 Section 75.402-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.402-2 Exceptions...

  13. 30 CFR 75.400-1 - Definitions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Definitions. 75.400-1 Section 75.400-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.400-1 Definitions. (a...

  14. 30 CFR 75.401-1 - Excessive amounts of dust.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Excessive amounts of dust. 75.401-1 Section 75.401-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting...

  15. 18 CFR 157.215 - Underground storage testing and development.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 7 OF THE NATURAL GAS ACT Interstate Pipeline Blanket Certificates and Authorization Under Section 7..., construct and operate natural gas pipeline and compression facilities, including injection, withdrawal, and... the gas bubble. This map need not be filed if there is no material change from the map previously...

  16. 76 FR 80553 - Mandatory Reporting of Greenhouse Gases: Technical Revisions to the Petroleum and Natural Gas...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-23

    ... facilities 486210 Pipeline transportation of natural gas. Petroleum and Natural Gas Systems. 221210 Natural... and Budget PHMSA Pipeline and Hazardous Material Safety Administration QA/QC quality assurance/quality... distribution pipelines, but also into liquefied natural gas storage or into underground storage. We are...

  17. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Roof Support § 75... accessible location on each working section or within four crosscuts of each working section. (b) The...

  18. 30 CFR 822.12 - Protection of agricultural activities.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... alluvial valley floors; or (2) cause material damage to the quantity or quality of water in surface or underground water systems that supply alluvial valley floors. (b) Statutory exclusions. The prohibitions of... be of negligible impact on the farm's agricultural production; (3) To any surface coal mining and...

  19. 30 CFR 822.12 - Protection of agricultural activities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... alluvial valley floors; or (2) cause material damage to the quantity or quality of water in surface or underground water systems that supply alluvial valley floors. (b) Statutory exclusions. The prohibitions of... be of negligible impact on the farm's agricultural production; (3) To any surface coal mining and...

  20. 75 FR 17529 - High-Voltage Continuous Mining Machine Standard for Underground Coal Mines

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-06

    ..., requires manufacturers to provide safeguards against corona on all 4,160-volt circuits in explosion-proof enclosures. Corona is a luminous discharge that occurs around electric conductors that are subject to high electric stresses. Corona can cause premature breakdown of insulating materials in explosion-proof...

  1. 40 CFR 270.2 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...

  2. 40 CFR 270.2 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...

  3. 40 CFR 270.2 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...

  4. 36 CFR 292.18 - Mineral resources.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...; provided, that an operating plan is not required for— (1) Operations which only involve vehicular travel on... of more than 100 pounds of material for analysis and study, provided the Area Ranger has prior notice of such activities; or (4) The evaluation and study of existing underground mine workings not...

  5. 30 CFR 57.6307 - Drill stem loading.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Drill stem loading. 57.6307 Section 57.6307... Transportation-Surface and Underground § 57.6307 Drill stem loading. Explosive material shall not be loaded into blastholes with drill stem equipment or other devices that could be extracted while containing explosive...

  6. 30 CFR 57.6307 - Drill stem loading.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Drill stem loading. 57.6307 Section 57.6307... Transportation-Surface and Underground § 57.6307 Drill stem loading. Explosive material shall not be loaded into blastholes with drill stem equipment or other devices that could be extracted while containing explosive...

  7. 30 CFR 57.6307 - Drill stem loading.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Drill stem loading. 57.6307 Section 57.6307... Transportation-Surface and Underground § 57.6307 Drill stem loading. Explosive material shall not be loaded into blastholes with drill stem equipment or other devices that could be extracted while containing explosive...

  8. 30 CFR 57.6307 - Drill stem loading.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Drill stem loading. 57.6307 Section 57.6307... Transportation-Surface and Underground § 57.6307 Drill stem loading. Explosive material shall not be loaded into blastholes with drill stem equipment or other devices that could be extracted while containing explosive...

  9. 30 CFR 57.6307 - Drill stem loading.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Drill stem loading. 57.6307 Section 57.6307... Transportation-Surface and Underground § 57.6307 Drill stem loading. Explosive material shall not be loaded into blastholes with drill stem equipment or other devices that could be extracted while containing explosive...

  10. 30 CFR 57.6800 - Storage facilities.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Storage facilities. 57.6800 Section 57.6800...-Surface and Underground § 57.6800 Storage facilities. When repair work which could produce a spark or flame is to be performed on a storage facility— (a) The explosive material shall be moved to another...

  11. 30 CFR 57.6800 - Storage facilities.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Storage facilities. 57.6800 Section 57.6800...-Surface and Underground § 57.6800 Storage facilities. When repair work which could produce a spark or flame is to be performed on a storage facility— (a) The explosive material shall be moved to another...

  12. 30 CFR 57.6800 - Storage facilities.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Storage facilities. 57.6800 Section 57.6800...-Surface and Underground § 57.6800 Storage facilities. When repair work which could produce a spark or flame is to be performed on a storage facility— (a) The explosive material shall be moved to another...

  13. 30 CFR 57.6800 - Storage facilities.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Storage facilities. 57.6800 Section 57.6800...-Surface and Underground § 57.6800 Storage facilities. When repair work which could produce a spark or flame is to be performed on a storage facility— (a) The explosive material shall be moved to another...

  14. 30 CFR 57.6800 - Storage facilities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Storage facilities. 57.6800 Section 57.6800...-Surface and Underground § 57.6800 Storage facilities. When repair work which could produce a spark or flame is to be performed on a storage facility— (a) The explosive material shall be moved to another...

  15. 30 CFR 57.3201 - Location for performing scaling.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Location for performing scaling. 57.3201... Control Scaling and Support-Surface and Underground § 57.3201 Location for performing scaling. Scaling shall be performed from a location which will not expose persons to injury from falling material, or...

  16. 30 CFR 57.4462 - Storage of combustible liquids underground.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4462 Storage of...) Combustible liquids, including oil or grease, shall be stored in non-glass containers or storage tanks. The... one inch of shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire...

  17. 30 CFR 57.4462 - Storage of combustible liquids underground.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4462 Storage of...) Combustible liquids, including oil or grease, shall be stored in non-glass containers or storage tanks. The... one inch of shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire...

  18. 30 CFR 57.4462 - Storage of combustible liquids underground.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4462 Storage of...) Combustible liquids, including oil or grease, shall be stored in non-glass containers or storage tanks. The... one inch of shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire...

  19. 30 CFR 57.4462 - Storage of combustible liquids underground.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4462 Storage of...) Combustible liquids, including oil or grease, shall be stored in non-glass containers or storage tanks. The... one inch of shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire...

  20. 30 CFR 57.4462 - Storage of combustible liquids underground.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Fire Prevention and Control Flammable and Combustible Liquids and Gases § 57.4462 Storage of...) Combustible liquids, including oil or grease, shall be stored in non-glass containers or storage tanks. The... one inch of shotcrete, one-half inch of gunite, or other noncombustible material with equivalent fire...

  1. Detection of underground voids in Ohio by use of geophysical methods

    USGS Publications Warehouse

    Munk, Jens; Sheets, R.A.

    1997-01-01

    Geophysical methods are generally classified as electrical, potential field, and seismic methods. Each method type relies on contrasts of physical properties in the subsurface. Forward models based on the physical properties of air- and water-filled voids within common geologic materials indicate that several geophysical methods are technically feasible for detection of subsurface voids in Ohio, but ease of use and interpretation varies widely between the methods. Ground-penetrating radar is the most rapid and cost-effective method for collection of subsurface data in areas associated with voids under roadways. Electrical resistivity, gravity, or seismic reflection methods have applications for direct delineation of voids, but data-collection and analytical procedures are more time consuming. Electrical resistivity, electromagnetic, or magnetic methods may be useful in locating areas where conductive material, such as rail lines, are present in abandoned underground coal mines. Other electrical methods include spontaneous potential and very low frequency (VLF); these latter two methods are considered unlikely candidates for locating underground voids in Ohio. Results of ground-penetrating radar surveys at three highway sites indicate that subsurface penetration varies widely with geologic material type and amount of cultural interference. Two highway sites were chosen over abandoned underground coal mines in eastern Ohio. A third site in western Ohio was chosen in an area known to be underlain by naturally occurring voids in lime stone. Ground-penetrating radar surveys at Interstate 470, in Belmont County, Ohio, indicate subsurface penetration of less than 15 feet over a mined coal seam that was known to vary in depth from 0 to 40 feet. Although no direct observations of voids were made, anomalous areas that may be related to collapse structures above voids were indicated. Cultural interference dominated the radar records at Interstate 70, Guernsey County, Ohio, where coal was mined under the site at a depth of about 50 feet. Interference from overhead powerlines, the field vehicle, and guardrails complicated an interpretation of the radar records where the depth of penetration was estimated to be less than 5 feet. Along State Route 33, in Logan County, Ohio, bedding planes and structures possibly associated with dissolution of limestone were profiled with ground-penetrating radar. Depth of penetration was estimated to be greater than 50 feet.

  2. 40 CFR 227.32 - Liquid, suspended particulate, and solid phases of a material.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... interact with ocean water to form insoluble matter or new toxic compounds, or materials which may release toxic compounds upon deposition, the Administrator, Regional Administrator, or the District Engineer, as... the material be performed upon a mixture of the waste with ocean water rather than on the material...

  3. 40 CFR 227.32 - Liquid, suspended particulate, and solid phases of a material.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... interact with ocean water to form insoluble matter or new toxic compounds, or materials which may release toxic compounds upon deposition, the Administrator, Regional Administrator, or the District Engineer, as... the material be performed upon a mixture of the waste with ocean water rather than on the material...

  4. 40 CFR 227.32 - Liquid, suspended particulate, and solid phases of a material.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... interact with ocean water to form insoluble matter or new toxic compounds, or materials which may release toxic compounds upon deposition, the Administrator, Regional Administrator, or the District Engineer, as... the material be performed upon a mixture of the waste with ocean water rather than on the material...

  5. Reproducibility of polycarbonate reference material in toxicity evaluation

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Huttlinger, P. A.

    1981-01-01

    A specific lot of bisphenol A polycarbonate has been used for almost four years as the reference material for the NASA-USF-PSC toxicity screening test method. The reproducibility of the test results over this period of time indicate that certain plastics may be more suitable reference materials than the more traditional cellulosic materials.

  6. Compositions and methods for removal of toxic metals and radionuclides

    NASA Technical Reports Server (NTRS)

    McKay, David S. (Inventor); Cuero, Raul G. (Inventor)

    2007-01-01

    The present invention relates to compositions and methods for the removal of toxic metals or radionuclides from source materials. Toxic metals may be removed from source materials using a clay, such as attapulgite or highly cationic bentonite, and chitin or chitosan. Toxic metals may also be removed using volcanic ash alone or in combination with chitin or chitosan. Radionuclides may be removed using volcanic ash alone or in combination with chitin or chitosan.

  7. Contamination source review for Building E7995, Edgewood Area, Aberdeen Proving Ground, Maryland

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Booher, M.N.; Miller, G.A.; Draugelis, A.K.

    1995-09-01

    The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from the review may be used to assist the US Army in planning for the future use or disposition, of the buildings. The source contamination review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, investigation of potential hazardous materials facilities (HMFs), and review of available records regarding underground storage tanks. This reportmore » provides the results of the contamination source review for Building E7995. any of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances, the potential exists for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings, and associated structures or appurtenances, may contribute to environmental concerns at APG.« less

  8. Dietary Acrylamide and the Risks of Developing Cancer: Facts to Ponder.

    PubMed

    Kumar, Jaya; Das, Srijit; Teoh, Seong Lin

    2018-01-01

    Acrylamide (AA) is a water soluble white crystalline solid commonly used in industries. It was listed as an industrial chemical with potential carcinogenic properties. However to date, AA was used to produce polyacrylamide polymer, which was widely used as a coagulant in water treatment; additives during papermaking; grouting material for dams, tunnels, and other underground building constructions. AA in food could be formed during high-temperature cooking via several mechanisms, i.e., formation via acrylic acid which may be derived from the degradation of lipid, carbohydrates, or free amino acids; formation via the dehydration/decarboxylation of organic acids (malic acid, lactic acid, and citric acid); and direct formation from amino acids. The big debate is whether this compound is toxic to human beings or not. In the present review, we discuss the formation of AA in food products, its consumption, and possible link to the development of any cancers. We discuss the body enzymatic influence on AA and mechanism of action of AA on hormone, calcium signaling pathways, and cytoskeletal filaments. We also highlight the deleterious effects of AA on nervous system, reproductive system, immune system, and the liver. The present and future mitigation strategies are also discussed. The present review on AA may be beneficial for researchers, food industry, and also medical personnel.

  9. Dietary Acrylamide and the Risks of Developing Cancer: Facts to Ponder

    PubMed Central

    Kumar, Jaya; Das, Srijit; Teoh, Seong Lin

    2018-01-01

    Acrylamide (AA) is a water soluble white crystalline solid commonly used in industries. It was listed as an industrial chemical with potential carcinogenic properties. However to date, AA was used to produce polyacrylamide polymer, which was widely used as a coagulant in water treatment; additives during papermaking; grouting material for dams, tunnels, and other underground building constructions. AA in food could be formed during high-temperature cooking via several mechanisms, i.e., formation via acrylic acid which may be derived from the degradation of lipid, carbohydrates, or free amino acids; formation via the dehydration/decarboxylation of organic acids (malic acid, lactic acid, and citric acid); and direct formation from amino acids. The big debate is whether this compound is toxic to human beings or not. In the present review, we discuss the formation of AA in food products, its consumption, and possible link to the development of any cancers. We discuss the body enzymatic influence on AA and mechanism of action of AA on hormone, calcium signaling pathways, and cytoskeletal filaments. We also highlight the deleterious effects of AA on nervous system, reproductive system, immune system, and the liver. The present and future mitigation strategies are also discussed. The present review on AA may be beneficial for researchers, food industry, and also medical personnel. PMID:29541638

  10. Cyclododecane exposure in the field of conservation and restoration of art objects.

    PubMed

    Vernez, David; Wognin, Barthélémy; Tomicic, Catherine; Plateel, Gregory; Charrière, Nicole; Bruhin, Stefanie

    2011-04-01

    Recent work practices in the conservation and restoration involve the use of cyclododecane (CDD, CAS 294-62-2) to protect fragile artifacts during their handling or transportation. Little is known about its toxicity, and no previous exposure has been reported. A short field investigation was conducted to characterize the exposure conditions to both CDD vapors and aerosols. Measurements were conducted in the laboratory of conservation and restoration of the archeological service in Bern (Switzerland). Three indoor and four outdoor typical work situations, either during brush or spray gun applications, were investigated. Measurements were performed on charcoal adsorbent tube and analyzed by a gas chromatograph equipped with a flame ionization detector. Measurements have been conducted during both brush and spray gun applications. Indoor exposures were of 0.75-15.5 mg/m(3), while outdoors exposures were 19.5-53.9 mg/m(3). Exposures appear to be extremely localized due to both physicochemical properties and application methods of the CDD. Vapor exposure increases dramatically with the confinement of the workplace. Preventive measures should be undertaken to limit as much as possible these exposures. Field work in confined areas (ditches, underground) is of particular concern. CDD-coated artifacts or materials should be stored in ventilated areas to avoid delayed exposures.

  11. Toxicity of thermal degradation products of spacecraft materials

    NASA Technical Reports Server (NTRS)

    Lawrence, W. H.; Turner, J. E.; Sanford, C.; Foster, S.; Baldwin, E.; Oconnor, J.

    1982-01-01

    Three polymeric materials were evaluated for relative toxicity of their pyrolysis products to rats by inhalation: Y-7683 (LS 200), Y-7684 (Vonar 3 on Fiberglass), and Y-7685 (Vonar 3 on N W Polyester). Criteria employed for assessing relative toxicity were (1) lethality from in-chamber pyrolysis, (2) lethality from an outside-of-chamber pyrolysis MSTL Procedure, and (3) disruption of trained rats' shock-avoidance performance during sub-lethal exposures to in-chamber pyrolysis of the materials.

  12. RIFM fragrance ingredient safety assessment, α-Ionone, CAS Registry Number 127-41-3.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization potential, as well as, environmental safety. Repeated dose toxicity was determined to have the most conservative systemic exposure derived NO[A]EL of 10 mg/kg/day. A dietary 90-day subchronic toxicity study conducted in rats resulted in a MOE of 182 while assuming 100% absorption from skin contact and inhalation. A MOE of >100 is deemed acceptable. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. RIFM fragrance ingredient safety assessment, isoeugenol, CAS Registry Number 97-54-1.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization potential, as well as, environmental safety. Repeated dose toxicity was determined to have the most conservative systemic exposure derived NO[A]EL of 37.5 mg/kg/day. A gavage 13-week subchronic toxicity study conducted in mice resulted in a MOE of 5769 while considering 38.4% absorption from skin contact and 100% from inhalation. A MOE of >100 is deemed acceptable. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. RIFM fragrance ingredient safety assessment, p-Isopropylbenzyl acetate, CAS Registry Number 59230-57-8.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization, as well as environmental safety. Data from the suitable read across analog, benzyl acetate (CAS # 140-11-4), show that this material is not genotoxic nor does it have skin sensitization potential. The repeated dose, developmental and reproductive, and local respiratory toxicity endpoints were completed using benzyl acetate (CAS # 140-11-4) as a suitable read across analog, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. RIFM fragrance ingredient safety assessment, acetic acid, C7-9-branched alkyl esters, C8-rich, CAS Registry Number 108419-32-5.

    PubMed

    Api, A M; Belsito, D; Botelho, D; Browne, D; Bruze, M; Burton, G A; Buschmann, J; Calow, P; Dagli, M L; Date, M; Dekant, W; Deodhar, C; Fryer, A D; Joshi, K; La Cava, S; Lapczynski, A; Liebler, D C; O'Brien, D; Parakhia, R; Patel, A; Penning, T M; Ritacco, G; Romine, J; Salvito, D; Schultz, T W; Sipes, I G; Thakkar, Y; Tsang, S; Wahler, J

    2017-12-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic. Data from the suitable read across analog isoamyl acetate (CAS# 123-92-2) show that this material does not have skin sensitization potential. The reproductive and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (0.03 mg/kg/day and 1.4 mg/day, respectively). The repeated dose and developmental endpoint was completed using data on the target material, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. RIFM fragrance ingredient safety assessment, 2-ethyl-1-butanol, CAS Registry Number 97-95-0.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data from the suitable read across analog 2-ethylhexanol (CAS # 104-76-7) show that this material is not genotoxic. Data from the suitable read across analog isopropyl alcohol (CAS # 67-63-0) show that this material does not have skin sensitization potential. The local respiratory toxicity endpoint was completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (1.4 mg/day). The repeated dose toxicity endpoint was completed using 2-ethylhexanol (CAS # 104-76-7) and 1-heptanol, 2-propyl (CAS # 10042-59-8) as suitable read across analogs, which provided a MOE > 100. The developmental and reproductive toxicity endpoint was completed using 2-ethyl-hexanol (CAS # 104-76-7) and isobutyl alcohol (CAS # 78-83-1) as suitable read across analogs, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Source term estimation and the isotopic ratio of radioactive material released from the WIPP repository in New Mexico, USA.

    PubMed

    Thakur, P

    2016-01-01

    After almost 15 years of operations, the Waste Isolation Pilot Plant (WIPP) had one of its waste drums breach underground as a result of a runaway chemical reaction in the waste it contained. This incident occurred on February 14, 2014. Moderate levels of radioactivity were released into the underground air. A small portion of the contaminated underground air also escaped to the surface through the ventilation system and was detected approximately 1 km away from the facility. According to the source term estimation, the actual amount of radioactivity released from the WIPP site was less than 1.5 mCi. The highest activity detected on the surface was 115.2 μBq/m(3) for (241)Am and 10.2 μBq/m(3) for (239+240)Pu at a sampling station located 91 m away from the underground air exhaust point and 81.4 μBq/m(3) of (241)Am and 5.8 μBq/m(3) of (239+240)Pu at a monitoring station located approximately 1 km northwest of the WIPP facility. The dominant radionuclides released were americium and plutonium, in a ratio that matches the content of the breached drum. Air monitoring across the WIPP site intensified following the first reports of radiation detection underground to determine the extent of impact to WIPP personnel, the public, and the environment. In this paper, the early stage monitoring data collected by an independent monitoring program conducted by the Carlsbad Environmental Monitoring & Research Center (CEMRC) and an oversight monitoring program conducted by the WIPP's management and operating contractor, the Nuclear Waste Partnership (NWP) LLC were utilized to estimate the actual amount of radioactivity released from the WIPP underground. The Am and Pu isotope ratios were measured and used to support the hypothesis that the release came from one drum identified as having breached that represents a specific waste stream with this radionuclide ratio in its inventory. This failed drum underwent a heat and gas producing reaction that overpowered its vent and lifted its lid to allow release of waste into the underground air. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Manufactured caverns in carbonate rock

    DOEpatents

    Bruce, David A.; Falta, Ronald W.; Castle, James W.; Murdoch, Lawrence C.

    2007-01-02

    Disclosed is a process for manufacturing underground caverns suitable in one embodiment for storage of large volumes of gaseous or liquid materials. The method is an acid dissolution process that can be utilized to form caverns in carbonate rock formations. The caverns can be used to store large quantities of materials near transportation facilities or destination markets. The caverns can be used for storage of materials including fossil fuels, such as natural gas, refined products formed from fossil fuels, or waste materials, such as hazardous waste materials. The caverns can also be utilized for applications involving human access such as recreation or research. The method can also be utilized to form calcium chloride as a by-product of the cavern formation process.

  19. Relative toxicity of pyrolysis products of some synthetic polymers

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Slattengren, C. L.; Furst, A.; Kourtides, D. A.; Parker, J. A.

    1976-01-01

    Nineteen samples of synthetic polymers were evaluated for relative toxicity in the course of characterizing materials intended for aircraft interior applications. The generic polymers included ABS, chlorinated PVC, polycarbonate, polyphenylene oxide, polyphenylene sulfide, polysulfone, polyaryl sulfone, polyether sulfone, polybismaleimide, and polyvinyl fluoride. Test results are presented, and compared in relative rankings with similar results on cellulosic materials and other synthetic polymers. Under these test conditions, the samples of synthetic polymers were either comparable to or significantly less toxic than the samples of commercial cellulosic materials.

  20. Toxicity of the pyrolysis products of spacecraft materials

    NASA Technical Reports Server (NTRS)

    Lawrence, W. H.

    1976-01-01

    Data is presented which provides guides to (1) approximate temperature necessary to initiate thermodegradation of the polymeric materials tested, (2) the relative toxicity of thermodegradation products from the various materials, (3) the relative importance of carbon monoxide as the primary cause of death (as contrasted to cyanide or other toxic gases), and (4) whether or not the hazards of the fumes are confined to the time of exposure, or whether post-exposure death is likely. Two different experimental methods were employed.

  1. Validation of Microtox as a first screening tool for waste classification.

    PubMed

    Weltens, R; Deprez, K; Michiels, L

    2014-12-01

    The Waste Framework Directive (WFD; 2008/98/EG) describes how waste materials are to be classified as hazardous or not. For complex waste materials chemical analyses are often not conclusive and the WFD provides the possibility to assess the hazardous properties by testing on the waste materials directly. As a methodology WFD refers to the protocols described in the CLP regulation (regulation on Classification, Labeling and Packaging of chemicals) but the toxicity tests on mammals are not acceptable for waste materials. The DISCRISET project was initiated to investigate the suitability of alternative toxicity tests that are already in use in pharmaceutical applications, for the toxicological hazard assessment of complex waste materials. Results indicated that Microtox was a good candidate as a first screening test in a tiered approached hazard assessment. This is now further validated in the present study. The toxic responses measured in Microtox were compared to biological responses in other bioassays for both organic and inorganic fractions of the wastes. Both fractions contribute to the toxic load of waste samples. Results show that the Microtox test is indeed a good and practical screening tool for the organic fraction. A screening threshold (ST) of 5 geq/l as the EC50 value in Microtox is proposed as this ST allows to recognize highly toxic samples in the screening test. The data presented here show that the Microtox toxicity response at this ST is not only predictive for acute toxicity in other organisms but also for sub lethal toxic effects of the organic fraction. This limit value has to be further validated. For the inorganic fraction no specific biotest can be recommended as a screening test, but the use of direct toxicity assessment is also preferable for this fraction as metal speciation is an important issue to define the toxic load of elutriate fractions. A battery of 3 tests (Microtox, Daphnia and Algae) for direct toxicity assessment of this fraction is recommended in literature, but including tests for mechanistic toxicity might be useful. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Some possible reference materials for fire toxicity tests

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Solis, A. N.

    1977-01-01

    Suitable reference materials need to be selected in order to standardize any test method. The evaluation of cotton, polyethylene, polyether sulfone, polycarbonate, polystyrene, and polyurethane flexible and rigid foams as possible reference materials for the University of San Francisco/NASA toxicity screening test method is discussed.

  3. Origin of the Polygons and Underground Structures in Western Utopia Planitia on Mars

    NASA Technical Reports Server (NTRS)

    Yoshikawa, K.

    2002-01-01

    The area of lower albedo (Hvm) has a higher density of polygonal patterns. These patterns potentially suggest that 1) the polygonal pattern is caused primarily by ground heaving and collapsing, 2) lower albedo materials had higher tensile strength. Additional information is contained in the original extended abstract.

  4. 30 CFR 942.817 - Performance standards-Underground mining activities.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: (1) Channel lining shall be designed using standards engineering practices to pass safely the design... material not utilized in diversion channel geometry or regrading of the channel shall be disposed of in... lieu of the requirements of § 817.46(c)(1)(ii)(A) of this chapter, sedimentation ponds shall provide a...

  5. 30 CFR 942.817 - Performance standards-Underground mining activities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...: (1) Channel lining shall be designed using standards engineering practices to pass safely the design... material not utilized in diversion channel geometry or regrading of the channel shall be disposed of in... lieu of the requirements of § 817.46(c)(1)(ii)(A) of this chapter, sedimentation ponds shall provide a...

  6. 30 CFR 75.403-1 - Incombustible content.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Incombustible content. 75.403-1 Section 75.403-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.403-1 Incombustible content. Moisture contained...

  7. 30 CFR 75.403-1 - Incombustible content.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Incombustible content. 75.403-1 Section 75.403-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.403-1 Incombustible content. Moisture contained...

  8. 30 CFR 75.403-1 - Incombustible content.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Incombustible content. 75.403-1 Section 75.403-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.403-1 Incombustible content. Moisture contained...

  9. 30 CFR 75.403-1 - Incombustible content.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Incombustible content. 75.403-1 Section 75.403-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.403-1 Incombustible content. Moisture contained...

  10. 40 CFR 146.10 - Plugging and abandoning Class I, II, III, IV, and V wells.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) WATER PROGRAMS (CONTINUED) UNDERGROUND INJECTION CONTROL PROGRAM: CRITERIA AND STANDARDS General... of drinking water. The Director may allow Class III wells to use other plugging materials if the... sources of drinking water. (2) Placement of the cement plugs shall be accomplished by one of the following...

  11. Tropical Engineering. Design Manual-11.1.

    DTIC Science & Technology

    1980-03-01

    fication TS-15250 for cold piping below 35 degrees F. Cellular glass 11.1-75 insulation only shall be used. Flexible unicellular insulation shall not be...11.1-71 2. Materials .........o......................................11.1-71 a. Underground Water Piping ...11.1-71 b. Protective Coating for Copper Tubing .................11.1-71 c. Above-ground Piping ................................. 11.1

  12. 30 CFR 75.403-1 - Incombustible content.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Incombustible content. 75.403-1 Section 75.403-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.403-1 Incombustible content. Moisture contained...

  13. 30 CFR 57.22102 - Smoking (I-C mines).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Smoking (I-C mines). 57.22102 Section 57.22102... Methane in Metal and Nonmetal Mines Fire Prevention and Control § 57.22102 Smoking (I-C mines). (a) Persons shall not smoke or carry smoking materials, matches, or lighters underground or within 50 feet of...

  14. 30 CFR 57.22102 - Smoking (I-C mines).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Smoking (I-C mines). 57.22102 Section 57.22102... Methane in Metal and Nonmetal Mines Fire Prevention and Control § 57.22102 Smoking (I-C mines). (a) Persons shall not smoke or carry smoking materials, matches, or lighters underground or within 50 feet of...

  15. 30 CFR 57.22102 - Smoking (I-C mines).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Smoking (I-C mines). 57.22102 Section 57.22102... Methane in Metal and Nonmetal Mines Fire Prevention and Control § 57.22102 Smoking (I-C mines). (a) Persons shall not smoke or carry smoking materials, matches, or lighters underground or within 50 feet of...

  16. 30 CFR 57.22102 - Smoking (I-C mines).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Smoking (I-C mines). 57.22102 Section 57.22102... Methane in Metal and Nonmetal Mines Fire Prevention and Control § 57.22102 Smoking (I-C mines). (a) Persons shall not smoke or carry smoking materials, matches, or lighters underground or within 50 feet of...

  17. Study of the Microstructure Evolution of Low-pH Cements Based on Ordinary Portland Cement (OPC) by Mid- and Near-Infrared Spectroscopy, and Their Influence on Corrosion of Steel Reinforcement.

    PubMed

    García Calvo, José Luis; Sánchez Moreno, Mercedes; Alonso Alonso, María Cruz; Hidalgo López, Ana; García Olmo, Juan

    2013-06-18

    Low-pH cements are designed to be used in underground repositories for high level waste. When they are based on Ordinary Portland Cements (OPC), high mineral admixture contents must be used which significantly modify their microstructure properties and performance. This paper evaluates the microstructure evolution of low-pH cement pastes based on OPC plus silica fume and/or fly ashes, using Mid-Infrared and Near-Infrared spectroscopy to detect cement pastes mainly composed of high polymerized C-A-S-H gels with low C/S ratios. In addition, the lower pore solution pH of these special cementitious materials have been monitored with embedded metallic sensors. Besides, as the use of reinforced concrete can be required in underground repositories, the influence of low-pH cementitious materials on steel reinforcement corrosion was analysed. Due to their lower pore solution pH and their different pore solution chemical composition a clear influence on steel reinforcement corrosion was detected.

  18. Low-background Gamma Spectroscopy at Sanford Underground Laboratory

    NASA Astrophysics Data System (ADS)

    Chiller, Christopher; Alanson, Angela; Mei, Dongming

    2014-03-01

    Rare-event physics experiments require the use of material with unprecedented radio-purity. Low background counting assay capabilities and detectors are critical for determining the sensitivity of the planned ultra-low background experiments. A low-background counting, LBC, facility has been built at the 4850-Level Davis Campus of the Sanford Underground Research Facility to perform screening of material and detector parts. Like many rare event physics experiments, our LBC uses lead shielding to mitigate background radiation. Corrosion of lead brick shielding in subterranean installations creates radon plate-out potential as well as human risks of ingestible or respirable lead compounds. Our LBC facilities employ an exposed lead shield requiring clean smooth surfaces. A cleaning process of low-activity silica sand blasting and borated paraffin hot coating preservation was employed to guard against corrosion due to chemical and biological exposures. The resulting lead shield maintains low background contribution integrity while fully encapsulating the lead surface. We report the performance of the current LBC and a plan to develop a large germanium well detector for PMT screening. Support provided by Sd governors research center-CUBED, NSF PHY-0758120 and Sanford Lab.

  19. 30 CFR 75.343 - Underground shops.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Underground shops. 75.343 Section 75.343...-3 through § 75.1107-16, or be enclosed in a noncombustible structure or area. (b) Underground shops... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.343 Underground shops. (a) Underground...

  20. RIFM fragrance ingredient safety assessment, α-Methylbenzyl acetate, CAS Registry Number 93-92-5.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization potential, as well as, environmental safety. Developmental toxicity was determined to have the most conservative systemic exposure derived NO[A]EL of 100 mg/kg/day. A gavage developmental toxicity study conducted in rats on a suitable read across analog resulted in aMOE of 3571 while considering 78.7% absorption from skin contact and 100% from inhalation. A MOE of >100 is deemed acceptable. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Toxic-Waste Disposal by Combustion in Containers

    NASA Technical Reports Server (NTRS)

    Houseman, J.; Stephens, J. B.; Moynihan, P. I.; Compton, L. E.; Kalvinskas, J. J.

    1986-01-01

    Chemical wastes burned with minimal handling in storage containers. Technique for disposing of chemical munitions by burning them inside shells applies to disposal of toxic materials stored in drums. Fast, economical procedure overcomes heat-transfer limitations of conventional furnace designs by providing direct contact of oxygenrich combustion gases with toxic agent. No need to handle waste material, and container also decontaminated in process. Oxygen-rich torch flame cuts burster well and causes vaporization and combustion of toxic agent contained in shell.

  2. Toxicity evaluations of various carbon nanomaterials.

    PubMed

    Uo, Motohiro; Akasaka, Tsukasa; Watari, Fumio; Sato, Yoshinori; Tohji, Kazuyuki

    2011-01-01

    After the discovery of fullerene and carbon nanotubes, various carbon nanomaterials were discovered or synthesized. The carbon nanomaterials have remarkable properties, different from bulk materials with the same chemical composition, and are therefore useful for industrial applications. However, the toxicity of nanomaterials may also differ from that of the bulk materials; this difference poses a concern. The physical similarity of nanomaterials to asbestos has led to evaluations for toxicity by many researchers using various methods. In this review, we compile and compare the toxicity evaluations of each carbon nanomaterial.

  3. Inhalation toxicology. V., Evaluation of relative toxicity to rats of thermal decomposition products from two aircraft seat fire-blocking materials.

    DOT National Transportation Integrated Search

    1985-11-01

    Two fire-blocking layer (FBL) materials, designed to delay the thermal decomposition of polyurethane foam seat cushions during an aircraft cabin fire, were evaluated for the relative toxicity of their gaseous combustion products. Each materials was t...

  4. Renewed mining and reclamation: Imapacts on bats and potential mitigation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brown, P.E.; Berry, R.D.

    Historic mining created new roosting habitat for many bat species. Now the same industry has the potential to adversely impact bats. Contemporary mining operations usually occur in historic districts; consequently the old workings are destroyed by open pit operations. Occasionally, underground techniques are employed, resulting in the enlargement or destruction of the original workings. Even during exploratory operations, historic mine openings can be covered as drill roads are bulldozed, or drills can penetrate and collapse underground workings. Nearby blasting associated with mine construction and operation can disrupt roosting bats. Bats can also be disturbed by the entry of mine personnelmore » to collect ore samples or by recreational mine explorers, since the creation of roads often results in easier access. In addition to roost disturbance, other aspects of renewed mining can have adverse impacts on bat populations, and affect even those bats that do not live in mines. Open cyanide ponds, or other water in which toxic chemicals accumulate, can poison bats and other wildlife. The creation of the pits, roads and processing areas often destroys critical foraging habitat, or change drainage patterns. Finally, at the completion of mining, any historic mines still open may be sealed as part of closure and reclamation activities. The net result can be a loss of bats and bat habitat. Conversely, in some contemporary underground operations, future roosting habitat for bats can be fabricated. An experimental approach to the creation of new roosting habitat is to bury culverts or old tires beneath waste rock. Mining companies can mitigate for impacts to bats by surveying to identify bat-roosting habitat, removing bats prior to renewed mining or closure, protecting non-impacted roost sites with gates and fences, researching to identify habitat requirements and creating new artificial roosts.« less

  5. An investigation of the PM2.5 and NO2 concentrations and their human health impacts in the metro subway system of Suzhou, China.

    PubMed

    Cao, Shi-Jie; Kong, Xiang-Ri; Li, Linyan; Zhang, Weirong; Ye, Zi-Ping; Deng, Yelin

    2017-05-24

    This study measured the particle concentrations with an aerodynamic diameter smaller than 2.5 μm (PM 2.5 ), nitrogen dioxide (NO 2 ), and relative humidity (RH) at five metro subway stations in Suzhou's subway system (Lines 1 and 2). The real-time monitoring campaign was conducted from March 30 th to April 10 th and August 4 th to August 21 st , 2015. The monitoring practice was carried out during rush (7:00-9:00 AM and 17:00-19:00 PM) and regular hours (other times) at the ground and underground levels under different weather conditions with a purpose of obtaining representative data. The monitored results show that the concentrations of PM 2.5 in the train carriages were lower than the concentrations at the underground platforms during both spring and summer. The mean PM 2.5 concentrations at all the underground platforms in all the sub-stations monitored were significantly higher than those at the ground level. The human health impact was calculated to be 6300 annual DALYs (or 375 deaths) due to exposure to the subway system in Suzhou according to the UNEP-SETAC toxicity (USEtox) model. Linear regression models were applied to evaluate the relationships between the PM 2.5 , NO 2 concentrations, and RH. We found that a 10% increment in RH from the current average level of 50-60% can lead to a 9.8 μg m -3 concentration decrease in PM 2.5 . This further results in the total human health impact being reduced to 2451 DALYs (150-4753 DALYs), representing a 20% decrease (1.2-38%).

  6. Methods for Casting Subterranean Ant Nests

    PubMed Central

    Tschinkel, Walter R.

    2010-01-01

    The study of subterranean ant nests has been impeded by the difficulty of rendering their structures in visible form. Here, several different casting materials are shown to make perfect casts of the underground nests of ants. Each material (dental plaster, paraffin wax, aluminum, zinc) has advantages and limitations, which are discussed. Some of the materials allow the recovery of the ants entombed in the casts, allowing a census of the ants to be connected with features of their nest architecture. The necessary equipment and procedures are described in the hope that more researchers will study this very important aspect of ant natural history. PMID:20673073

  7. RIFM fragrance ingredient safety assessment, Isopulegol, CAS Registry Number 89-79-2.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic nor does it have skin sensitization potential. The repeated dose, developmental and reproductive, and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (0.03, 0.03 mg/kg/day and 1.4 mg/day, respectively). The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Physiological and lavage fluid cytological and biochemical endpoints of toxicity in the rat

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lehnert, B.E.

    1992-01-01

    Exposure of the respiratory tract to toxic materials can result in a variety of physiologic disturbances that can serve as endpoints of toxicity. In addition to a brief review of commonly assessed physiologic endpoints, attention is given in the first component of this report to the use of both nose breathing and mouth'' breathing rats in toxicity studies that involve measurements of ventilatory functional changes in response to test atmospheres. Additionally, the usefulness of maximum oxygen consumption, or VO[sub 2max], as a physiologic endpoint of toxicity that uses exercising rats after exposure to test atmospheres is described, along with anmore » introduction to post-exposure exercise as an important behavioral activity that can markedly impact on the severity of acute lung injury caused by pneumoedematogenic materials. The second component of this report focuses on bronchoalveolar lavage and cytological and biochemical endpoints that can be assessed in investigations of the toxicities of test materials. As will be shown herein, some of the biochemical endpoints of toxicity, especially, can sensitively detect subtle injury to the lower respiratory tract that may escape detection by changes in some other conventional endpoints of toxicity, including lung gravimetric increases and histopathological alterations.« less

  9. Physiological and lavage fluid cytological and biochemical endpoints of toxicity in the rat

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lehnert, B.E.

    1992-12-31

    Exposure of the respiratory tract to toxic materials can result in a variety of physiologic disturbances that can serve as endpoints of toxicity. In addition to a brief review of commonly assessed physiologic endpoints, attention is given in the first component of this report to the use of both nose breathing and ``mouth`` breathing rats in toxicity studies that involve measurements of ventilatory functional changes in response to test atmospheres. Additionally, the usefulness of maximum oxygen consumption, or VO{sub 2max}, as a physiologic endpoint of toxicity that uses exercising rats after exposure to test atmospheres is described, along with anmore » introduction to post-exposure exercise as an important behavioral activity that can markedly impact on the severity of acute lung injury caused by pneumoedematogenic materials. The second component of this report focuses on bronchoalveolar lavage and cytological and biochemical endpoints that can be assessed in investigations of the toxicities of test materials. As will be shown herein, some of the biochemical endpoints of toxicity, especially, can sensitively detect subtle injury to the lower respiratory tract that may escape detection by changes in some other conventional endpoints of toxicity, including lung gravimetric increases and histopathological alterations.« less

  10. 30 CFR 72.630 - Drill dust control at underground areas of underground mines.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Drill dust control at underground areas of underground mines. 72.630 Section 72.630 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT... dust control at underground areas of underground mines. (a) Dust resulting from drilling in rock shall...

  11. Active cooling-based surface confinement system for thermal soil treatment

    DOEpatents

    Aines, R.D.; Newmark, R.L.

    1997-10-28

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

  12. Active cooling-based surface confinement system for thermal soil treatment

    DOEpatents

    Aines, Roger D.; Newmark, Robin L.

    1997-01-01

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

  13. DarkSide search for dark matter

    NASA Astrophysics Data System (ADS)

    Alexander, T.; Alton, D.; Arisaka, K.; Back, H. O.; Beltrame, P.; Benziger, J.; Bonfini, G.; Brigatti, A.; Brodsky, J.; Bussino, S.; Cadonati, L.; Calaprice, F.; Candela, A.; Cao, H.; Cavalcante, P.; Chepurnov, A.; Chidzik, S.; Cocco, A. G.; Condon, C.; D'Angelo, D.; Davini, S.; De Vincenzi, M.; De Haas, E.; Derbin, A.; Di Pietro, G.; Dratchnev, I.; Durben, D.; Empl, A.; Etenko, A.; Fan, A.; Fiorillo, G.; Franco, D.; Fomenko, K.; Forster, G.; Gabriele, F.; Galbiati, C.; Gazzana, S.; Ghiano, C.; Goretti, A.; Grandi, L.; Gromov, M.; Guan, M.; Guo, C.; Guray, G.; Hungerford, E. V.; Ianni, Al; Ianni, An; Joliet, C.; Kayunov, A.; Keeter, K.; Kendziora, C.; Kidner, S.; Klemmer, R.; Kobychev, V.; Koh, G.; Komor, M.; Korablev, D.; Korga, G.; Li, P.; Loer, B.; Lombardi, P.; Love, C.; Ludhova, L.; Luitz, S.; Lukyanchenko, L.; Lund, A.; Lung, K.; Ma, Y.; Machulin, I.; Mari, S.; Maricic, J.; Martoff, C. J.; Meregaglia, A.; Meroni, E.; Meyers, P.; Mohayai, T.; Montanari, D.; Montuschi, M.; Monzani, M. E.; Mosteiro, P.; Mount, B.; Muratova, V.; Nelson, A.; Nemtzow, A.; Nurakhov, N.; Orsini, M.; Ortica, F.; Pallavicini, M.; Pantic, E.; Parmeggiano, S.; Parsells, R.; Pelliccia, N.; Perasso, L.; Perasso, S.; Perfetto, F.; Pinsky, L.; Pocar, A.; Pordes, S.; Randle, K.; Ranucci, G.; Razeto, A.; Romani, A.; Rossi, B.; Rossi, N.; Rountree, S. D.; Saggese, P.; Saldanha, R.; Salvo, C.; Sands, W.; Seigar, M.; Semenov, D.; Shields, E.; Skorokhvatov, M.; Smirnov, O.; Sotnikov, A.; Sukhotin, S.; Suvarov, Y.; Tartaglia, R.; Tatarowicz, J.; Testera, G.; Thompson, J.; Tonazzo, A.; Unzhakov, E.; Vogelaar, R. B.; Wang, H.; Westerdale, S.; Wojcik, M.; Wright, A.; Xu, J.; Yang, C.; Zavatarelli, S.; Zehfus, M.; Zhong, W.; Zuzel, G.

    2013-11-01

    The DarkSide staged program utilizes a two-phase time projection chamber (TPC) with liquid argon as the target material for the scattering of dark matter particles. Efficient background reduction is achieved using low radioactivity underground argon as well as several experimental handles such as pulse shape, ratio of ionization over scintillation signal, 3D event reconstruction, and active neutron and muon vetos. The DarkSide-10 prototype detector has proven high scintillation light yield, which is a particularly important parameter as it sets the energy threshold for the pulse shape discrimination technique. The DarkSide-50 detector system, currently in commissioning phase at the Gran Sasso Underground Laboratory, will reach a sensitivity to dark matter spin-independent scattering cross section of 10-45 cm2 within 3 years of operation.

  14. Modeling Elastic Wave Propagation from an Underground Chemical Explosion Using Higher Order Finite Difference Approximation: Theory, Validation and Application to SPE

    NASA Astrophysics Data System (ADS)

    Hirakawa, E. T.; Ezzedine, S. M.; Petersson, A.; Sjogreen, B.; Vorobiev, O.; Pitarka, A.; Antoun, T.; Walter, W. R.

    2016-12-01

    Motions from underground explosions are governed by non-linear hydrodynamic response of material. However, the numerical calculation of this non-linear constitutive behavior is computationally intensive in contrast to the elastic and acoustic linear wave propagation solvers. Here, we develop a hybrid modeling approach with one-way hydrodynamic-to-elastic coupling in three dimensions in order to propagate explosion generated ground motions from the non-linear near-source region to the far-field. Near source motions are computed using GEODYN-L, a Lagrangian hydrodynamics code for high-energy loading of earth materials. Motions on a dense grid of points sampled on two nested shells located beyond the non-linear damaged zone are saved, and then passed to SW4, an anelastic anisotropic fourth order finite difference code for seismic wave modeling. Our coupling strategy is based on the decomposition and uniqueness theorems where motions are introduced into SW4 as a boundary source and continue to propagate as elastic waves at a much lower computational cost than by using GEODYN-L to cover the entire near- and the far-field domain. The accuracy of the numerical calculations and the coupling strategy is demonstrated in cases with a purely elastic medium as well as non-linear medium. Our hybrid modeling approach is applied to SPE-4' and SPE-5 which are the most recent underground chemical explosions conducted at the Nevada National Security Site (NNSS) where the Source Physics Experiments (SPE) are performed. Our strategy by design is capable of incorporating complex non-linear effects near the source as well as volumetric and topographic material heterogeneity along the propagation path to receiver, and provides new prospects for modeling and understanding explosion generated seismic waveforms. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-698608.

  15. Potential of Live Spirulina platensis on Biosorption of Hexavalent Chromium and Its Conversion to Trivalent Chromium.

    PubMed

    Colla, Luciane Maria; Dal'Magro, Clinei; De Rossi, Andreia; Thomé, Antônio; Reinehr, Christian Oliveira; Bertolin, Telma Elita; Costa, Jorge Alberto Vieira

    2015-01-01

    Microalga biomass has been described worldwide according their capacity to realize biosorption of toxic metals. Chromium is one of the most toxic metals that could contaminate superficial and underground water. Considering the importance of Spirulina biomass in production of supplements for humans and for animal feed we assessed the biosorption of hexavalent chromium by living Spirulina platensis and its capacity to convert hexavalent chromium to trivalent chromium, less toxic, through its metabolism during growth. The active biomass was grown in Zarrouk medium diluted to 50% with distilled water, keeping the experiments under controlled conditions of aeration, temperature of 30°C and lighting of 1,800 lux. Hexavalent chromium was added using a potassium dichromate solution in fed-batch mode with the aim of evaluate the effect of several additions contaminant in the kinetic parameters of the culture. Cell growth was affected by the presence of chromium added at the beginning of cultures, and the best growth rates were obtained at lower metal concentrations in the medium. The biomass removed until 65.2% of hexavalent chromium added to the media, being 90.4% converted into trivalent chromium in the media and 9.6% retained in the biomass as trivalent chromium (0.931 mg.g(-1)).

  16. Prompt gamma neutron activation analysis of toxic elements in radioactive waste packages.

    PubMed

    Ma, J-L; Carasco, C; Perot, B; Mauerhofer, E; Kettler, J; Havenith, A

    2012-07-01

    The French Alternative Energies and Atomic Energy Commission (CEA) and National Radioactive Waste Management Agency (ANDRA) are conducting an R&D program to improve the characterization of long-lived and medium activity (LL-MA) radioactive waste packages. In particular, the amount of toxic elements present in radioactive waste packages must be assessed before they can be accepted in repository facilities in order to avoid pollution of underground water reserves. To this aim, the Nuclear Measurement Laboratory of CEA-Cadarache has started to study the performances of Prompt Gamma Neutron Activation Analysis (PGNAA) for elements showing large capture cross sections such as mercury, cadmium, boron, and chromium. This paper reports a comparison between Monte Carlo calculations performed with the MCNPX computer code using the ENDF/B-VII.0 library and experimental gamma rays measured in the REGAIN PGNAA cell with small samples of nickel, lead, cadmium, arsenic, antimony, chromium, magnesium, zinc, boron, and lithium to verify the validity of a numerical model and gamma-ray production data. The measurement of a ∼20kg test sample of concrete containing toxic elements has also been performed, in collaboration with Forschungszentrum Jülich, to validate the model in view of future performance studies for dense and large LL-MA waste packages. Copyright © 2012 Elsevier Ltd. All rights reserved.

  17. Materials safety data sheets the basis for control of toxic chemicals. Volume II

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bolton, N. E.; Ketchen, E. E.; Porter, W. E.

    For large industrial and research operations, maintaining reasonable control of all toxic materials used in their operations can be a formidable task. A system utilizing cards has been developed that serves a dual purpose, informing the user regarding hazards of a particular material and also facilitating appropriate workplace surveillance during its use. Selected data, including threshold limit values, routes of absorption, symptoms of exposure, chronic effects, and emergency first-aid procedures, are printed on the card. A portion of the card contains the label that the user detaches and affixes to the container. This label classifies the material according to flammability,more » toxicity, reactivity, and special properties on a 0 through 4 hazard rating system. This report describes the development and use of such cards, contains the associated Toxic Material Data Sheets that provide full backup data for the labels, and furnishes a glossary of biomedical terms used in the Data Sheets.« less

  18. 25 CFR 247.18 - What are the sanitation prohibitions?

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., bottle, sewage, waste water or material, either by removal from the site, or by depositing it into receptacles or at places provided for such purposes. (c) You may not bring refuse, debris, or toxic or hazardous materials to the sites for disposal. (d) All toxic or hazardous materials must be properly removed...

  19. 25 CFR 247.18 - What are the sanitation prohibitions?

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ..., bottle, sewage, waste water or material, either by removal from the site, or by depositing it into receptacles or at places provided for such purposes. (c) You may not bring refuse, debris, or toxic or hazardous materials to the sites for disposal. (d) All toxic or hazardous materials must be properly removed...

  20. 25 CFR 247.18 - What are the sanitation prohibitions?

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ..., bottle, sewage, waste water or material, either by removal from the site, or by depositing it into receptacles or at places provided for such purposes. (c) You may not bring refuse, debris, or toxic or hazardous materials to the sites for disposal. (d) All toxic or hazardous materials must be properly removed...

  1. Prediction of blast fragmentation of underground stopes for in situ leaching

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stagg, M.S.; Otterness, R.E.; Djahanguiri, F.

    1994-12-31

    The US Bureau of Mines (USBM) evaluated empirical equations that predict fragmentation from underground stope rounds. Controlled blasting is necessary for creating leaching stopes that maximize the recovery and minimize backbreak of the perimeter wall. This paper presents the fragmentation results from one of the three drop-raise blasts used to develop a reduced-scale cylindrical stope, 1.8 m in diameter and 6 m in height. The stope is located in the Colorado School of Mines Experimental Mine (Edgar Mine) in Idaho Springs, Colorado. This stope is part of a USBM research effort to determine the feasibility of incorporating in situ leachingmore » of rubblized stopes into active underground metal and nonmetal mines. All the material from the first blast, 14 mtons was sieved. The resulting distribution was compared to the distribution predicted from empirical equations. The best fit was found with a USBM equation developed from over 50 sieved, reduced-scale (1- to 2-m) high wall blasts. Modifications to the equations were made to account for the observed differences due to breakout angle, shot geometry, initiation timing, decoupling, rock fracture toughness and explosive energy.« less

  2. A new screening test for toxicity testing of dental materials.

    PubMed

    Pelka, M; Danzl, C; Distler, W; Petschelt, A

    2000-07-01

    The development of a micro plate assay for cytotoxicity testing of dental materials based on a bioassay using brine shrimp larvae (artemia salina) as sensitive organisms. Brine shrimp larvae are commonly used for cytotoxicity assays in pharmacology. These larvae are sensitive to toxic substances. The ratio between dead larvae (no motility) and living larvae (high motility) in comparison to a control without any toxic substances is used to estimate the toxicity of the test solutions. The test materials (Arabesk((R)), Solitaire((R)), Pertac((R)) II, Tetric((R)), Herculite((R)) and the compomer materials Dyract((R)), Hytac((R)), Compoglass((R))) were polymerized and consecutively milled. After incubation of 1g in 4ml distilled water at 37 degrees C for 48h, the solid materials were separated by centrifugation. The solutions were equibrilated with NaCl to a salt content of 25g/l. Aliquots of 200microl were distributed in eight micro wells and 50microl of a artemia salina containing (n=8-14) solution were added to each well. As controls eight wells with 250microl salt solution containing a comparable number of brine shrimp were used. At baseline, after 2, 5, 24 and 48h, the dead shrimp were counted using a stereo microscope. Finally all shrimps were sacrificed using Na-acid (5%) and counted to get the number of shrimps per well. All compomers and Solitaire caused 100% brine shrimp lethality after 24h and showed significantly (p<0.01, signed rank test) higher toxicities than the remaining composites. With the exception of Pertac II, all composites showed significantly higher toxic values than the control. Pertac II did not show any differences from the controls used. This new technique has some advantages for toxicity testing of restorative materials, because it can quickly be carried out at low costs. The disadvantage is the high quantity of material used and the low sensitivity.

  3. 40 CFR 280.220 - Ownership of an underground storage tank or underground storage tank system or facility or...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Ownership of an underground storage tank or underground storage tank system or facility or property on which an underground storage tank or underground storage tank system is located. 280.220 Section 280.220 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID...

  4. Toxicity testing of restorative dental materials using brine shrimp larvae (Artemia salina).

    PubMed

    Milhem, Manar M; Al-Hiyasat, Ahmad S; Darmani, Homa

    2008-01-01

    This study investigated the effect of extracts of different composites, glass ionomer cement (GIC)s and compomers on the viability of brine shrimp larvae. Ethanolic extracts of four dental composites (Z-100; Solitaire 2; Filtek P60 and Synergy), a conventional GIC (Ketac-Fil), a resin-modified glass ionomer cement (Vitremer), two compomers (F2000; Dyract AP), and a flowable compomer (Dyract Flow) were prepared from each material. Following evaporation of the ethanol, the extracts were resuspended in distilled water, which was then used to test the effects on the viability of brine shrimp larvae. For the composites, the extract of Synergy was the least toxic (88% viability) followed by the extracts of Solitaire 2, Z100 and P60 (75%, 67.5% and 50% viability, respectively). One-way ANOVA revealed highly significant differences between the resin composite materials (p<0.001). Follow-up comparison between the composite groups by Tukey's pairwise multiple-comparison test (alpha =0.05) showed that the extract of Synergy was significantly less toxic than the extracts of all the other materials except that of Solitaire 2. The compomers showed 100% lethality, while the percentage of viable larvae for the extracts of Ketac-Fil, and Vitremer were 32.3%, and 37.0%, respectively. One-way ANOVA revealed highly significant differences between the groups of materials (p<0.001). Follow-up comparison between the groups by Tukey's test (alpha = 0.05) showed that the toxic effect of the extracts of the compomers were significantly greater than that of Ketac-Fil, and Vitremer. The differences in the toxic effects of Vitremer and Ketac-Fil were not statistically significant. In conclusion, the toxicity of composite materials varied according to their chemical composition. Compomers were the most lethal materials to brine shrimp larvae followed by GICs and then composites.

  5. RIFM fragrance ingredient safety assessment, benzyl butyrate, CAS Registry Number 103-37-7.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data from the suitable read across analog benzyl acetate (CAS # 140-11-4) show that this material is not genotoxic nor does it have skin sensitization potential and also provided a MOE > 100 for the repeated dose, developmental and reproductive, and local respiratory toxicity endpoints. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Modeling aerosol emissions from the combustion of composite materials

    NASA Technical Reports Server (NTRS)

    Roop, J. A.; Caldwell, D. J.; Kuhlmann, K. J.

    1994-01-01

    The use of advanced composite materials (ACM) in the B-2 bomber, composite armored vehicle, and F-22 advanced tactical fighter has rekindled interest concerning the health risk of burned or burning ACM. The objective of this work was to determine smoke production from burning ACM and its toxicity. A commercial version of the UPITT II combustion toxicity method developed at the University of Pittsburgh, and subsequently refined through a US Army-funded basic research project, was used to established controlled combustion conditions which were selected to evaluate real-world exposure scenarios. Production and yield of toxic species varied with the combustion conditions. Previous work with this method showed that the combustion conditions directly influenced the toxicity of the decomposition products from a variety of materials.

  7. Toxic substances registry system: Index of material safety data sheets

    NASA Technical Reports Server (NTRS)

    1992-01-01

    The Jul. 1992 Revision of the KSC Toxic Substances Registry System (TSRS) Index of Material Safety Data Sheets (MSDS's) is presented. The listed MSDS's reflect product inventories and associated MSDS's which were submitted to the Toxic Substance Registry Data Base maintained by the Base Operations Contractors of the Biomedical Operations and Research Office of KSC. The purpose of the index is to provide a means of accessing information on the hazards associated with the toxic and otherwise hazardous chemicals stored and used at KSC. Indices are provided for manufacturers, trademarks, and stock numbers.

  8. 40 CFR 280.71 - Permanent closure and changes-in-service.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... UNDERGROUND STORAGE TANKS (UST) Out-of-Service UST Systems and Closure § 280.71 Permanent closure and changes... sludges. All tanks taken out of service permanently must also be either removed from the ground or filled with an inert solid material. (c) Continued use of an UST system to store a non-regulated substance is...

  9. 40 CFR 280.71 - Permanent closure and changes-in-service.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... UNDERGROUND STORAGE TANKS (UST) Out-of-Service UST Systems and Closure § 280.71 Permanent closure and changes... sludges. All tanks taken out of service permanently must also be either removed from the ground or filled with an inert solid material. (c) Continued use of an UST system to store a non-regulated substance is...

  10. 40 CFR 280.71 - Permanent closure and changes-in-service.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... UNDERGROUND STORAGE TANKS (UST) Out-of-Service UST Systems and Closure § 280.71 Permanent closure and changes... sludges. All tanks taken out of service permanently must also be either removed from the ground or filled with an inert solid material. (c) Continued use of an UST system to store a non-regulated substance is...

  11. 40 CFR 280.71 - Permanent closure and changes-in-service.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... UNDERGROUND STORAGE TANKS (UST) Out-of-Service UST Systems and Closure § 280.71 Permanent closure and changes... sludges. All tanks taken out of service permanently must also be either removed from the ground or filled with an inert solid material. (c) Continued use of an UST system to store a non-regulated substance is...

  12. Cost Effective, Ultra Sensitive Groundwater Monitoring for Site Remediation and Management

    DTIC Science & Technology

    2015-05-01

    feasibility studies. ................... 30  Table 5. Compounds screened in the laboratory for IS2 sampling...tank SVOC semivolatile organic compound TCE trichloroethene TPH total petroleum hydrocarbon USEPA U.S. Environmental Protection Agency UST...underground storage tank V volt VOA volatile organic analysis VOC volatile organic compound Technical material contained in this report has

  13. 30 CFR 57.4660 - Work in shafts, raises, or winzes and other activities involving hazard areas.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Welding/cutting/compressed Gases § 57.4660... noncombustible material. (3) Shield the activity so that hot metal and sparks cannot cause a fire. (4) Provide a...

  14. Removal of carbon monoxide. Physical adsorption on natural and synthetic zeolites

    NASA Technical Reports Server (NTRS)

    Alfani, F.; Greco, G., Jr.; Iroio, G.

    1982-01-01

    The utilization of natural zeolite materials in the elimination of polluting gases is investigated. Carbon monoxide pollution is emphasized because its concentration may reach dangerous levels in places such as vehicle tunnels, underground parking lots, etc. The elimination of carbon monoxide is also of interest in some industrial processes relating to the production of pure gases.

  15. Preparation and multi-properties determination of radium-containing rocklike material

    NASA Astrophysics Data System (ADS)

    Hong, Changshou; Li, Xiangyang; Zhao, Guoyan; Jiang, Fuliang; Li, Ming; Zhang, Shuai; Wang, Hong; Liu, Kaixuan

    2018-02-01

    The radium-containing rocklike material were fabricated using distilled water, ordinary Portland cement and additives mixed aggregates and admixtures according to certain proportion. The physico-mechanical properties as well as radioactive properties of the prepared rocklike material were measured. Moreover, the properties of typical granite sample were also investigated. It is found on one hand, similarities exist in physical and mechanical properties between the rocklike material and the granite sample, this confirms the validity of the proposed method; on the other hand, the rocklike material generally performs more remarkable radioactive properties compared with the granite sample, while radon diffusive properties in both materials are essentially matching. This study will provide a novel way to prepare reliable radium-containing samples for radon study of underground uranium mine.

  16. Toxic substances registry system: Index of material safety data sheets

    NASA Technical Reports Server (NTRS)

    1991-01-01

    The Material Safety Data Sheets (MSDSs) listed in this index reflect product inventories and associated MSDSs which have been submitted to the Toxic Substance Registry database maintained by the Base Operations Contractor at the Kennedy Space Center. The purpose of this index is to provide a means to access information on the hazards associated with the toxic and otherwise hazardous chemicals stored and used at the Kennedy Space Center.

  17. RIFM fragrance ingredient safety assessment, linalyl benzoate, CAS Registry Number 126-64-7.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dkant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data show that this material is not genotoxic. Data from the suitable read across analog linalyl phenylacetate (CAS # 7143-69-3) show that this material does not have skin sensitization potential. The repeated dose toxicity endpoint was completed using linalyl cinnamate (CAS # 78-37-5) as a suitable read across analog, which provided a MOE > 100. The developmental and reproductive toxicity endpoint was completed using linalool (CAS # 78-70-6), dehydrolinalool (CAS # 29171-20-8), benzoic acid (CAS # 65-85-0) and sodium benzoate (CAS # 532-32-1) as suitable read across analogs, which provided a MOE > 100. The local respiratory toxicity endpoint was completed using linalool (CAS # 78-70-6) and benzoic acid (CAS # 65-85-0) as suitable read across analogs, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework along with data from the suitable read across analog linalyl cinnamate (CAS # 78-375). Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Thermophysical parameters from laboratory measurements and tests in borehole heat exchangers

    NASA Astrophysics Data System (ADS)

    Pacetti, Chiara; Giuli, Gabriele; Invernizzi, Chiara; Chiozzi, Paolo; Verdoya, Massimo

    2017-04-01

    Besides the type of thermal regime, the performance of borehole heat exchangers relies on the overall thermal resistance of the borehole. This parameter strongly depends on the underground thermal conductivity, which accounts for most of the heat that can be extracted. The geometric configuration and the increase of thermal conductivity of the grout filling back the bore can yield a non-negligible enhancement in thermal performances. In this paper, we present a study on a pilot geothermal plant consisting of two borehole heat exchangers, 95 m deep and 9 m apart. Laboratory and in situ tests were carried out with the aim of investigating underground thermal properties, mechanisms of heat transfer and thermal characteristics of the filling grouts. Samples of grouting materials were analysed in the lab for assessing the thermal conductivity. An attempt to improve the thermal conductivity was made by doping grouts with alumina. Results showed that alumina large concentrations can increase the thermal conductivity by 25-30%. The in situ experiments included thermal logs under conditions of thermal equilibrium and thermal response tests (TRTs). The analysis of the temperature-depth profiles, based on the mass and energy balance in permeable horizons with uniform thermo-hydraulic and steady-state conditions, revealed that the underground thermal regime is dominated by conduction. TRTs were performed by injecting a constant heat rate per unit length into the boreholes for 60-90 hours. After TRTs, the temperature drop off (TDO) was recorded at 20-m-depth intervals for one week in both holes. The TRT time series were interpreted according to the classical model of the infinite line source (ILS), to infer the underground thermal conductivity. The TDO records allowed the inference of the underground thermal properties variation with depth. The results of thermal conductivity inferred with the ILS method are consistent with the values obtained from the TDO analysis.

  19. Development of a Portable Muon Witness System

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aguayo Navarrete, Estanislao; Kouzes, Richard T.; Orrell, John L.

    2011-01-01

    Since understanding and quantifying cosmic ray induced radioactive backgrounds in copper and germanium are important to the MAJORANA DEMONSTRATOR, methods are needed for monitoring the levels of such backgrounds produced in materials being transported and processed for the experiment. This report focuses on work conducted at Pacific Northwest National Laboratory to develop a muon witness system as a one way of monitoring induced activities. The operational goal of this apparatus is to characterize cosmic ray exposure of materials. The cosmic ray flux at the Earth’s surface is composed of several types of particles, including neutrons, muons, gamma rays and protons.more » These particles induce nuclear reactions, generating isotopes that contribute to the radiological background. Underground, the main mechanism of activation is by muon produced spallation neutrons since the hadron component of cosmic rays is removed at depths greater than a few tens of meters. This is a sub-dominant contributor above ground, but muons become predominant in underground experiments. For low-background experiments cosmogenic production of certain isotopes, such as 68Ge and 60Co, must be accounted for in the background budgets. Muons act as minimum ionizing particles, depositing a fixed amount of energy per unit length in a material, and have a very high penetrating power. Using muon flux measurements as a “witness” for the hadron flux, the cosmogenic induced activity can be quantified by correlating the measured muon flux and known hadronic production rates. A publicly available coincident muon cosmic ray detector design, the Berkeley Lab Cosmic Ray Detector (BLCRD), assembled by Juniata College, is evaluated in this work. The performance of the prototype is characterized by assessing its muon flux measurements. This evaluation is done by comparing data taken in identical scenarios with other cosmic ray telescopes. The prototype is made of two plastic scintillator paddles with associated electronics to measure energy depositions in coincidence in the two paddles. For this particular application of the prototype, the measurements performed concentrated on a broad investigation of the dependence of the muon flux on depth underground. These tests were conducted inside at Building 3420/1307 and underground at Building 3425 at the Pacific Northwest National Laboratory. The second half of this report analyzes modifications to the electronics of the BLCRD to make this detector portable. Among other modifications, a battery powered version of these electronics is proposed for the final Muon Witness design.« less

  20. 30 CFR 75.343 - Underground shops.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Underground shops. 75.343 Section 75.343... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.343 Underground shops. (a) Underground shops shall be equipped with an automatic fire suppression system meeting the requirements of § 75.1107...

  1. 30 CFR 75.343 - Underground shops.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground shops. 75.343 Section 75.343... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.343 Underground shops. (a) Underground shops shall be equipped with an automatic fire suppression system meeting the requirements of § 75.1107...

  2. 30 CFR 75.343 - Underground shops.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Underground shops. 75.343 Section 75.343... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.343 Underground shops. (a) Underground shops shall be equipped with an automatic fire suppression system meeting the requirements of § 75.1107...

  3. 30 CFR 75.343 - Underground shops.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Underground shops. 75.343 Section 75.343... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.343 Underground shops. (a) Underground shops shall be equipped with an automatic fire suppression system meeting the requirements of § 75.1107...

  4. RIFM fragrance ingredient safety assessment, Eugenol, CAS Registry Number 97-53-0.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current use conditions is supported by the existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity, skin sensitization potential, as well as, environmental safety. Reproductive toxicity was determined to have the most conservative systemic exposure derived NO[A]EL of 230 mg/kg/day. A gavage multigenerational continuous breeding study conducted in rats on a suitable read across analog resulted in a MOE of 12,105 while considering 22.6% absorption from skin contact and 100% from inhalation. A MOE of >100 is deemed acceptable. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. 30 CFR 57.8519 - Underground main fan controls.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground main fan controls. 57.8519 Section... Ventilation Surface and Underground § 57.8519 Underground main fan controls. All underground main fans shall have controls placed at a suitable protected location remote from the fan and preferably on the surface...

  6. RIFM fragrance ingredient safety assessment, 2-methylundecanol, CAS Registry Number 10522-26-6.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Penning, T M; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    This material was evaluated for genotoxicity, repeated dose toxicity, reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data from the suitable read across analogs 2-butyloctan-1-ol (CAS # 3913-02-8) and 2-ethyl-1-hexanol (CAS # 104-76-7) show that this material is not genotoxic nor does it have skin sensitization potential. The reproductive and local respiratory toxicity endpoints were completed using the TTC (Threshold of Toxicological Concern) for a Cramer Class I material (0.03 and 1.4 mg/day, respectively). The repeated dose toxicity endpoint was completed using 2-ethyl-1-hexanol (CAS # 104-76-7) and 1-heptanol, 2-propyl (CAS # 10042-59-8) as suitable read across analogs, which provided a MOE > 100. The developmental toxicity endpoint was completed using 2-ethyl-1-hexanol (CAS # 104-76-7) as a suitable read across analog, which provided a MOE > 100 The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Precise Heat Control: What Every Scientist Needs to Know About Pyrolytic Techniques to Solve Real Problems

    NASA Technical Reports Server (NTRS)

    Devivar, Rodrigo

    2014-01-01

    The performance of a material is greatly influenced by its thermal and chemical properties. Analytical pyrolysis, when coupled to a GC-MS system, is a powerful technique that can unlock the thermal and chemical properties of almost any substance and provide vital information. At NASA, we depend on precise thermal analysis instrumentation for understanding aerospace travel. Our analytical techniques allow us to test materials in the laboratory prior to an actual field test; whether the field test is miles up in the sky or miles underground, the properties of any involved material must be fully studied and understood in the laboratory.

  8. A three-dimensional back-analysis of the collapse of an underground cavity in soft rocks

    NASA Astrophysics Data System (ADS)

    Fazio, Nunzio Luciano; Lollino, Piernicola; Perrotti, Michele; Parise, Mario; Bonamini, Marco; Di Maggio, Cipriano; Madonia, Giuliana; Vattano, Marco

    2016-04-01

    Anthropogenic sinkholes have recently occurred in built-up areas of Sicily (southern Italy) and are generally associated with the presence of ancient underground quarries for the extraction of soft calcarenite rock, used as building material. These quarries were poorly excavated and then were abandoned in the following decades; urban expansion has recently enlarged to involve the areas affected by presence of the cavities, so that the likely collapse of the underground systems poses serious risks to people, buildings and infrastructures. The present work focuses on the case of the town of Marsala, where in 2003 a sinkhole opened at the outskirts of town, near peri-urban buildings. Field surveys, structural analysis of the joint networks in the rock mass and numerical modeling were carried out in order to investigate the most significant factors responsible of the instability processes of the underground quarry. In particular, a geotechnical three-dimensional model has been defined based on in-situ measurements and surveys. The FEM analyses have been performed with the code Plaxis-3D, by using initially the Mohr-Coulomb elasto-plastic model and then assessing the influence of the joint systems on the rock-mass stability with a jointed rock anisotropic model. Discrete planar bands have been also used to simulate the effect of specific joints, as an alternative to the jointed rock model. The results are in good agreement with the failure mechanism generated during the 2003 sinkhole event, and confirm that reliable analyses of these problems requires 3-D sophisticated tools.

  9. Development of spacecraft toxic gas removal agents

    NASA Technical Reports Server (NTRS)

    Moore, R. S.

    1974-01-01

    The development of agents suitable for removal of CO, NH3, NO2 SO2, and other spacecraft contaminants was approached. An extensive technology review was conducted, yielding a large number of potentially useful materials and/or concepts. Because the two toxic gases of greatest interest, CO and NH3, suggested the use of catalysis principles emphasis was placed on the intestigation of transition metals on various supports. Forty-three materials were prepared or obtained and 25 were tested. Gas chromatographic techniques were used to find seven candidates that effectively managed various combinations of the four toxic gases: none managed all. These candidates included six transition metal-containing preparations and a supported LiOH material. Three commercial charcoals showed some efficiency for the toxic gases and may constitute candidates for enhancement by doping with transition metals.

  10. Creep behaviour of a polymer-based underground support liner

    NASA Astrophysics Data System (ADS)

    Guner, Dogukan; Ozturk, Hasan

    2017-09-01

    All underground excavations (tunnels, mines, caverns, etc.) need a form of support to ensure that excavations remain safe and stable for the designed service lifetime. In the last decade, a new support material, thin spray-on liner (TSL) has started to take place of traditional underground surface supports of bolts and shotcrete. TSLs are generally cement, latex, polymer-based and also reactive or non-reactive, multi-component materials applied to the rock surface with a layer of few millimeter thickness. They have the advantages of low volume, logistics, rapid application and low operating cost. The majority of current TSLs are two-part products that are mixed on site before spraying onto excavation rock surfaces. Contrary to the traditional brittle supports, the high plastic behaviour of TSLs make them to distribute the loads on larger lining area. In literature, there is a very limited information exist on the creep behavior of TSLs. In this study, the creep behavior of a polymer-based TSL was investigated. For this purpose, 7-day cured dogbone TSL specimens were tested under room temperature and humidity conditions according to ASTM-D2990 creep testing standard. A range of dead weights (80, 60, 40, and 20 % of the tensile strength) were applied up to 1500 hours. As a result of this study, the time-dependent strain behavior of a TSL was presented for different constant load conditions. Moreover, a new equation was derived to estimate tensile failure time of the TSL for a given loading condition. If the tensile stress acting on the TSL is known, the effective permanent support time of the TSL can be estimated by the proposed relationship.

  11. Flame retardants in UK furniture increase smoke toxicity more than they reduce fire growth rate.

    PubMed

    McKenna, Sean T; Birtles, Robert; Dickens, Kathryn; Walker, Richard G; Spearpoint, Michael J; Stec, Anna A; Hull, T Richard

    2018-04-01

    This paper uses fire statistics to show the importance of fire toxicity on fire deaths and injuries, and the importance of upholstered furniture and bedding on fatalities from unwanted fires. The aim was to compare the fire hazards (fire growth and smoke toxicity) using different upholstery materials. Four compositions of sofa-bed were compared: three meeting UK Furniture Flammability Regulations (FFR), and one using materials without flame retardants intended for the mainland European market. Two of the UK sofa-beds relied on chemical flame retardants to meet the FFR, the third used natural materials and a technical weave in order to pass the test. Each composition was tested in the bench-scale cone calorimeter (ISO 5660) and burnt as a whole sofa-bed in a sofa configuration in a 3.4 × 2.25 × 2.4 m 3 test room. All of the sofas were ignited with a No. 7 wood crib; the temperatures and yields of toxic products are reported. The sofa-beds containing flame retardants burnt somewhat more slowly than the non-flame retarded EU sofa-bed, but in doing so produced significantly greater quantities of the main fire toxicants, carbon monoxide and hydrogen cyanide. Assessment of the effluents' potential to incapacitate and kill is provided showing the two UK flame retardant sofa-beds to be the most dangerous, followed by the sofa-bed made with European materials. The UK sofa-bed made only from natural materials (Cottonsafe ® ) burnt very slowly and produced very low concentrations of toxic gases. Including fire toxicity in the FFR would reduce the chemical flame retardants and improve fire safety. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

  12. A review on anthropogenic impact to the Micro Prespa lake and its damages

    NASA Astrophysics Data System (ADS)

    Frasheri, N.; Pano, N.; Frasheri, A.; Beqiraj, G.; Bushati, S.; Taska, E.

    2012-04-01

    Paper presents the results of the integrated and multidisciplinary studies for investigation of the anthropogenic damages to Albanian part of the transborder Micro Prespa Lake. Remote sensing with Landsat images was used for identification of environmental changes in time for the period 1970 - 2010. Micro Prespa Lake is lake with international status, as Ramsar Convection, International Park and Special Protection Area-79/409/EEC. According to the studies, investigations and analyses, the following were concluded: Devolli River- Micro Prespa Lake irrigation system was not scientifically supported by environmental engineering, hydroeconomy and International Rights principles. It does work according to the projected parameters, and also, doesn't supply the agricultural needs. About of 10 % of the water volume, discharges by Devolli River in Micro Prespa Lake during the winter, is taken from this lake for the irrigation in summer. Great surface of Albanian part of Micro Prespa Lake is destroyed. The other part of the lake is atrophied and the habitat and biodiversity are damaged. Important and unique species of fish, birds and plants of national and international values are risked. The underground karstic connection ways for water circulation are blocked. There are ruining the historic values of the area, such the encient Treni cave from the Bronze Age. The Albanian part of the Micro Prespa Lake has been damaged by the human activities. A huge amount of 1,2 million cubic meters alluvium has been deposited on the lake bottom and lakeshore, which was transported by the Devolli River waters, since 1974. This river waters, rich in alluvium and organic coal material from outcropped geological formations, also absorbed free chemical toxic remains by the drainage of Devolli farm ground, which have changed the chemical features of the lake water and degrading it. Micro Prespa Lake communicates with Macro Prespa Lake, and together with Ohrid Lake. Blockage of underground karstic connection ways has diminished not only the components of the lake water balance, but also the decreasing yield of the underground springs, that supply the Ohrid lake and drinkable water springs. The Albanian part of the Micro Prespa Lake plays the role of a gigantic decanter. This is an unprecedented case, not only in Albanian but also in Balkan and World hydrography. Devolli river alluvium deposited in Micro Prespa Lake caused the otherwise of territory of Republic of Albania in this area. Albania will not have any part in this lake after some years. The social and public opinion in Albania, must be conscious for the otherwise of Albanian territory, which in the case of Micro Prespa Lake has a national and international negative effect on destructions of a transborder lake, defendey by Europian Convents.

  13. Release and Movement of Radionuclides in Soils Contaminated with Fallout Materials from an Underground Thermonuclear Detonation

    DTIC Science & Technology

    1962-07-06

    Studies The degree of dissolution of the fallout material in H2 0, HCl, DTPA, CDTA, and EDDHA solutions was investigated by the suspension method...days was: EDDHA >DTPA>CDTA>H 2 0. while after 65 days the order of effect was: CDTA> EDDHA >DTPA>H 20. Portions of gamma ray spectra of the 106 day...the same amounts of radionuclides as did H120. The most abundant radio- nuclide was radiotungsten for H120, DTPA, CDTA, and EDDHA supernatant liquids

  14. Assessing the Potential Environmental Consequences of a New Energetic Material: A Phased Approach, September 2005

    DTIC Science & Technology

    2007-12-01

    there are no reliable alternatives to animal testing in the determination of toxicity. QSARs are only as reliable as the corroborating toxicological ...2) QSAR approaches can also be used to estimate toxicological impact. Toxicity QSAR models can often predict many toxicity parameters without... Toxicology Study No. 87-XE-03N3-05, Assessing the Potential Environmental Consequences of a New Energetic Material: A Phased Approach, September 2005 1

  15. A Subject Reference: Benefit-Cost Analysis of Toxic Substances, Hazardous Materials and Solid Waste Control (1977)

    EPA Pesticide Factsheets

    Discussion of methodological issues for conducting benefit-cost analysis and provides guidance for selecting and applying the most appropriate and useful mechanisms in benefit-cost analysis of toxic substances, hazardous materials, and solid waste control

  16. 30 CFR 784.22 - Geologic information.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... occurring; (ii) Chemical analyses identifying those strata that may contain acid- or toxic-forming, or... that the analysis for alkalinity-producing material is unnecessary; and (iii) Chemical analysis of the...; (ii) Chemical analyses for acid- or toxic-forming or alkalinity-producing materials and their content...

  17. TOXICITY TESTING, RISK ASSESSMENT, AND OPTIONS FOR DREDGED MATERIAL MANAGEMENT

    EPA Science Inventory

    Programs for evaluating proposed discharges of dredged material into waters of the United States specify a tiered testing and evaluation protocol that includes performance of acute and chronic bioassays to assess toxicity of the dredged sediments. Although these evaluations refl...

  18. Ampoule Failure System

    NASA Technical Reports Server (NTRS)

    Watring, Dale A. (Inventor); Johnson, Martin L. (Inventor)

    1996-01-01

    An ampoule failure system for use in material processing furnaces comprising a containment cartridge and an ampoule failure sensor. The containment cartridge contains an ampoule of toxic material therein and is positioned within a furnace for processing. An ampoule failure probe is positioned in the containment cartridge adjacent the ampoule for detecting a potential harmful release of toxic material therefrom during processing. The failure probe is spaced a predetermined distance from the ampoule and is chemically chosen so as to undergo a timely chemical reaction with the toxic material upon the harmful release thereof. The ampoule failure system further comprises a data acquisition system which is positioned externally of the furnace and is electrically connected to the ampoule failure probe so as to form a communicating electrical circuit. The data acquisition system includes an automatic shutdown device for shutting down the furnace upon the harmful release of toxic material. It also includes a resistance measuring device for measuring the resistance of the failure probe during processing. The chemical reaction causes a step increase in resistance of the failure probe whereupon the automatic shutdown device will responsively shut down the furnace.

  19. Relative toxicity of products of pyrolysis and combustion of polymeric materials using various test conditions

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.

    1976-01-01

    Relative toxicity data for a large number of natural and synthetic polymeric materials are presented which were obtained by 11 pyrolysis and three flaming-combustion test methods. The materials tested include flexible and rigid polyurethane foams, different kinds of fabrics and woods, and a variety of commodity polymers such as polyethylene. Animal exposure chambers of different volumes containing mice, rats, or rabbits were used in the tests, which were performed over the temperature range from ambient to 800 C with and without air flow or recirculation. The test results are found to be sensitive to such variables as exposure mode, temperature, air flow and dilution, material concentration, and animal species, but relative toxicity rankings appear to be similar for many methods and materials. It is concluded that times to incapacitance and to death provide a more suitable basis for relative toxicity rankings than percent mortality alone, that temperature is the most important variable in the tests reported, and that variables such as chamber volume and animal species may not significantly affect the rankings.

  20. A new design concept of fully grouted rock bolts in underground construction

    NASA Astrophysics Data System (ADS)

    Phich Nguyen, Quang; Nguyen, Van Manh; Tuong Nguyen, Ke

    2018-04-01

    The main problem after excavating an underground excavation is to maintain the stability of the excavation for a certain period of time. Failure in meeting this demand is a threat to safety of men and equipment. Support and reinforcement are different instruments with different mechanisms. Among the common support systems in tunnelling and mining, rock bolts have been widely used to reinforce rock mass and also to reduce geological hazards. Furthermore rock bolts can be applied under varying different geological conditions with cost-effectiveness. Although different methods are developed for grouted rock bolts design until now, the interaction mechanism of the rock bolts and rock mass is still very complicated issue. The paper addresses an analytical model for the analysis and design of fully grouted rock bolts based on the reinforcement principle. According to this concept the jointed rock mass reinforced by grouted rock bolts is considered as composite material which includes rock mass, the grout material and the bolt shank. The mechanical properties of this composite material depend on the ratio of the components. The closed-form solution was developed based on the assumption that the rock mass arround a circular tunnel remained elastic after installing fully grouted rock bolts. The main parameters of the rock-bolt system (the diameter and length of bolt shank, the space between the bolts) are then easily estimated from the obtained solution.

  1. Relative toxicity of pyrolysis products of some foams and fabrics

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.

    1976-01-01

    A limited number of foams and fabrics was evaluated in the course of developing test procedures for determining the relative toxicity of materials. The principal variable studied, heating rate, did not affect the relative ranking of the materials tested. Two pyrolysis test procedures using the same basic approach but employing different sample weights, chamber volumes, laboratory animals, heating rates, and upper temperature limits, resulted in identical rankings of relative toxicity. The data obtained show that modification of conventional flexible polyurethane foams with flame retardants to comply with California upholstered furniture flammability regulations seems to consistently reduce toxicity under pyrolysis conditions.

  2. The sensitivity of relative toxicity rankings by the USF/NASA test method to some test variables

    NASA Technical Reports Server (NTRS)

    Hilado, C. J.; Labossiere, L. A.; Leon, H. A.; Kourtides, D. A.; Parker, J. A.; Hsu, M.-T. S.

    1976-01-01

    Pyrolysis temperature and the distance between the source and sensor of effluents are two important variables in tests for relative toxicity. Modifications of the USF/NASA toxicity screening test method to increase the upper temperature limit of pyrolysis, reduce the distance between the sample and the test animals, and increase the chamber volume available for animal occupancy, did not significantly alter rankings of relative toxicity of four representative materials. The changes rendered some differences no longer significant, but did not reverse any rankings. The materials studied were cotton, wool, aromatic polyamide, and polybenzimidazole.

  3. [Research progress of health effect of polybrominated diphenyl ethers].

    PubMed

    Zhai, J X; Tong, S L

    2016-06-01

    Polybrominated diphenyl ethers (PBDEs) was one of the most common brominated flame retardants, it has been widely used in products such as furnitures, polymer and plastical material, textiles, electronic products and building materials. PBDEs have potential effect such as neurodevelopmental toxicity, reproductive toxicity, thyroid toxicity, immunological toxicity, embryo toxicity, liver toxicity, teratogenicity and potential carcinogenicity. This paper was aimed to review the environmental exposure way, current level, neurotoxicity, neurodevelopmental toxicity and reproductive toxicity of PBDEs. In recent years, PBDEs has been detected in environment, wildlife animal and human body around the world, there were the significant differences of exposure levels of PBDEs. The most abundant congener were tetra-BDE or BDE-47, hexa-BDE or BDE-153, and deca-BDE or BDE-209. Prenatal exposure to PBDEs has great impact on the infants' neurodevelopmental function, induces changes in neuropsychological developmental behavior, decreases of congnition, motivation and attention. High levels of PBDEs have positive relationship with Luteinizing hormone levels, testis disfunction and children's cryptorchidism, and have negative relationship with sperm number and testis size.

  4. [The Research Advancement and Conception of the Deep-underground Medicine].

    PubMed

    Xie, He-Ping; Liu, Ji-Feng; Gao, Ming-Zhong; Wan, Xue-Hong; Liu, Shi-Xi; Zou, Jian; Wu, Jiang; Ma, Teng-Fei; Liu, Yi-Lin; Bu, Hong; Li, Wei-Min

    2018-03-01

    The 21th century is the century of exploring and utilizing the underground space. In the future, more and more people will spend more and more time living or/and working in the underground space. However,we know little about the effect on the health of human caused by the underground environment. Herein,we systematically put forward the strategic conception of the deep-underground medicine,in order to reveal relative effects and mechanism of the potential factors in the deep underground space on human's physiological and psychological healthy,and to work out the corresponding countermeasures. The original deep-underground medicine includes the following items. ①To model different depth of underground environment according to various parameters (such as temperature,radiation,air pressure, rock,microorganism), and to explore their quantitative character and effects on human health and mechanism. ② To study the psychological change, maintenance of homeostasis and biothythm of organism in the deep underground space. ③ To learn the association between psychological healthy of human and the depth, structure, physical environment and working time of underground space. ④ To investigate the effect of different terrane and lithology on healthy of human and to deliberate their contribution on organism growth. ⑤ To research the character and their mechanism of growth,metabolism,exchange of energy,response of growth, aging and adaptation of cells living in deep underground space. ⑥ To explore the physiological feature,growth of microbiome and it's interaction with host in the deep underground space. ⑦ To develop deep-underground simulation space, the biologically medical technology and equipments. As a research basis,a deep-underground medical lab under a rock thickness of about 1 470 m has been built,which aims to operate the research of the effect on living organism caused by different depth of underground environment. Copyright© by Editorial Board of Journal of Sichuan University (Medical Science Edition).

  5. Evaluation of dredged material proposed for ocean disposal from Arthur Kill Project Area, New York

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gruendell, B.D.; Barrows, E.S.; Borde, A.B.

    1997-01-01

    The objective of the bioassay reevaluation of Arthur Kill Federal Project was to reperform toxicity testing on proposed dredged material following current ammonia reduction protocols. Arthur Kill was one of four waterways sampled and evaluated for dredging and disposal in April 1993. Sediment samples were recollected from the Arthur Kill Project areas in August 1995. Tests and analyses were conducted according to the manual developed by the USACE and the U.S. Environmental Protection Agency (EPA), Evaluation of Dredged Material Proposed for Ocean Disposal (Testing Manual), commonly referred to as the {open_quotes}Green Book,{close_quotes} and the regional manual developed by the USACE-NYDmore » and EPA Region II, Guidance for Performing Tests on Dredged Material to be Disposed of in Ocean Waters. The reevaluation of proposed dredged material from the Arthur Kill project areas consisted of benthic acute toxicity tests. Thirty-three individual sediment core samples were collected from the Arthur Kill project area. Three composite sediments, representing each reach of the area proposed for dredging, was used in benthic acute toxicity testing. Benthic acute toxicity tests were performed with the amphipod Ampelisca abdita and the mysid Mysidopsis bahia. The amphipod and mysid benthic toxicity test procedures followed EPA guidance for reduction of total ammonia concentrations in test systems prior to test initiation. Statistically significant acute toxicity was found in all Arthur Kill composites in the static renewal tests with A. abdita, but not in the static tests with M. bahia. Statistically significant acute toxicity and a greater than 20% increase in mortality over the reference sediment was found in the static renewal tests with A. abdita. M. bahia did not show statistically significant acute toxicity or a greater than 10% increase in mortality over reference sediment in static tests. 5 refs., 2 figs., 2 tabs.« less

  6. Underground Coal Preparation System and Applications

    NASA Astrophysics Data System (ADS)

    Wei, Cao; DeYong, Shang; BaoNing, Zhang

    2018-03-01

    The underground coal preparation is a cutting-edge technology of the coal industry worldwide. This paper introduced the meaning of implementing the underground coal preparation, and the practical applications of underground mechanical moving screen jig, underground heavy medium shallow slot and underground air jigger. Through analyzing the main separation equipment and the advantages and disadvantages of three primary processes from aspects of process complexity, slime water treatment, raw coal preparation, etc., the difference among technology investment, construction scale, production cost and economic benefit is concluded.

  7. Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management

    DTIC Science & Technology

    2015-05-01

    Example anion concentrations in groundwater used for feasibility studies. ................... 30 Table 5. Compounds screened in the laboratory for IS2...phase extraction ST storage tank SVOC semivolatile organic compound TCE trichloroethene TPH total petroleum hydrocarbon USEPA U.S. Environmental...Protection Agency UST underground storage tank V volt VOA volatile organic analysis VOC volatile organic compound Technical material

  8. City Safaris. A Sierra Club Explorer's Guide to Urban Adventures for Grownups and Kids.

    ERIC Educational Resources Information Center

    Shaffer, Carolyn; Fielder, Erica

    Most people think of nature in the city as parks and zoos and dandelions pushing up through cracks in the sidewalk, but it is also asphalt streets, granite office buildings and mazes of underground pipes and cables. The materials of which the streets and buildings are constructed began as prehistoric jungles and ancient mountains. The systems that…

  9. 30 CFR 57.4660 - Work in shafts, raises, or winzes and other activities involving hazard areas.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Welding/cutting/compressed Gases § 57.4660... cutting with an electric arc or open flame More than 1 gallon of combustible liquid, unless in a closed... combustible plastics. Soldering or thawing with an open flame Within 10 feet of— Materials in a shaft, raise...

  10. 30 CFR 57.4660 - Work in shafts, raises, or winzes and other activities involving hazard areas.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Welding/cutting/compressed Gases § 57.4660... cutting with an electric arc or open flame More than 1 gallon of combustible liquid, unless in a closed... combustible plastics. Soldering or thawing with an open flame Within 10 feet of— Materials in a shaft, raise...

  11. 30 CFR 57.4660 - Work in shafts, raises, or winzes and other activities involving hazard areas.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Welding/cutting/compressed Gases § 57.4660... cutting with an electric arc or open flame More than 1 gallon of combustible liquid, unless in a closed... combustible plastics. Soldering or thawing with an open flame Within 10 feet of— Materials in a shaft, raise...

  12. 30 CFR 57.4660 - Work in shafts, raises, or winzes and other activities involving hazard areas.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...-UNDERGROUND METAL AND NONMETAL MINES Fire Prevention and Control Welding/cutting/compressed Gases § 57.4660... cutting with an electric arc or open flame More than 1 gallon of combustible liquid, unless in a closed... combustible plastics. Soldering or thawing with an open flame Within 10 feet of— Materials in a shaft, raise...

  13. Logging Residue Available for Mine-Timber Production

    Treesearch

    Floyd G. Timson

    1978-01-01

    Hardwood logging residue was examined as a source of raw material in the manufacture of sawn, split, and round timbers for use in underground coal mines. Forty-four percent of the total logging residue (residue !U 4 inches in diameter outside bark (dob), small end, and 4 feet long) from sawlog-only harvests was suitable for mine-timber production. Only 26 percent of...

  14. 30 CFR 75.401 - Abatement of dust; water or water with a wetting agent.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Abatement of dust; water or water with a wetting agent. 75.401 Section 75.401 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.401 Abatement of...

  15. 30 CFR 75.401 - Abatement of dust; water or water with a wetting agent.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Abatement of dust; water or water with a wetting agent. 75.401 Section 75.401 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.401 Abatement of...

  16. 30 CFR 75.401 - Abatement of dust; water or water with a wetting agent.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Abatement of dust; water or water with a wetting agent. 75.401 Section 75.401 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.401 Abatement of...

  17. 30 CFR 75.401 - Abatement of dust; water or water with a wetting agent.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Abatement of dust; water or water with a wetting agent. 75.401 Section 75.401 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.401 Abatement of...

  18. 30 CFR 75.401 - Abatement of dust; water or water with a wetting agent.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Abatement of dust; water or water with a wetting agent. 75.401 Section 75.401 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Combustible Materials and Rock Dusting § 75.401 Abatement of...

  19. Architecture Earth-Sheltered Buildings. Design Manual 1.4

    DTIC Science & Technology

    1984-03-01

    pavilions (as entrances), greenhouses (as skylights), and pitched or shed roofs (as clerestories). Exterior materials such as gliss, metal, and tile can...condensation could occur will be :"",.- essentially at the interior air temperature. Otherwise, provisions for occasional dehumidification can be... Dehumidification of Shelter Space, Office of Civil Defense, Battl.acreek, Michigan, 1961. THERMAL ENVIRONMENT OF UNDERGROUND SHELTERS "Achenbach, P.R

  20. Subterranean termites - their prevention and control in buildings

    Treesearch

    Chris Peterson; Terence L. Wagner; Joseph E. Mulrooney; Thomas G. Shelton

    2006-01-01

    Subterranean termites are the most important insect pest of wood in the United States. Living in large underground colonies, termites may attack any wood in contact with the soil and may even construct protective shelter tubes over nonwood materials to attack wood above ground. Most damage in the United States is caused by termites in the genus Reticulitermes, but an...

  1. Neutron induced radio-isotopes and background for Ge double beta decay experiments

    NASA Astrophysics Data System (ADS)

    Chu, Pinghan; Majorana Collaboration

    2015-10-01

    Environmental neutrons, mostly produced by muons in the cosmic rays, might contribute backgrounds to the search for neutrinoless double beta decays. These neutrons can interact with materials and generate radio-isotopes, which can decay and produce radioactive backgrounds. Some of these neutron-induced isotopes have a signature of a time-delayed coincidence, allowing us to study these infrequent events. For example, such isotopes can decay by beta decay to metastable states and then decay by gamma decay to the ground state. Considering the time-delayed coincidence of these two processes, we can determine candidates for these neutron-induced isotopes in the data and estimate the flux of neutrons in the deep underground environment. In this report, we will list possible neutron-induced isotopes and the methodology to detect them, especially those that can affect the search for neutrinoless double beta decays in 76Ge. This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Nuclear Physics, the Particle Astrophysics Program of the National Science Foundation, and the Sanford Underground Research Facility. We acknowledge the support of the U.S. Department of Energy through the LANL/LDRD Program.

  2. Organically modified low-grade kaolin as a secondary containment material for underground storage tanks.

    PubMed

    Moon, Chul-Hwan; Lee, Jai-Young; Oh, Byung-Taek; Choi, Sang-Il

    2007-08-01

    Batch scale reactions were conducted to evaluate the efficacy of modified low-grade kaolin for the treatment of petroleum contaminants. Low-grade kaolin, which has been unvalued as material in the mining process because of its low quality for commercial products, was modified with HDTMA (hexadecyl-trimethylammonium), and its efficiency was compared with that of HDTMA-modified bentonite, which is used as a secondary containment barrier for underground storage tanks. The sorption capacity and hydraulic conductivity of both the HDTMA-modified bentonite and low-grade kaolin were investigated and showed distribution coefficients in the sorption of benzene, toluene, ethylbenzene and xylene ranging between 45.7 and 583.7 and 57.0 and 525.1, respectively. The hydraulic conductivities were 2.53 x 10(-8) and 5.62 x 10(-8) cm/s for the HDTMA-modified bentonite and low-grade kaolin, respectively. These results suggest that HDTMA-modified low-grade kaolin could be used as a hydraulic barrier against advection migration of petroleum contaminants. Simulation of the one-dimensional transport of benzene through a liner made of either one of the compounds was also performed. These results also showed that HDTMA-modified kaolin more effectively retards the transport of benzene.

  3. Zonal disintegration of rocks around underground workings. Part II. Rock fracture simulated in equivalent materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shemyakin, E.I.; Fisenko, G.L.; Kurlenya, M.V.

    1987-05-01

    For a detailed testing of the effects discovered in situ, analysis of the patterns and origination conditions of fractured rock zones inside the bed around workings, and ways explosions affect the surrounding rocks, a program and a method of study on models of equivalent materials have been developed. The method of simulation on two- and three-dimensional models involved building in a solid or fissured medium a tunnel of a circular or arched cross section. The tests were done for elongate adit-type workings. At the first stage, three models were tested with different working support systems: anchor supports, concrete-spray supports andmore » no supports. Zone formation is shown and described. Tests were continued on two groups of three-dimensional models to bring the model closer to in situ conditions. The presence of gaping cracks and heavily fractured zones deep in the interior of the bed with a quasicylindrical symmetry indicates that the common views concerning the stressed-strained state of rocks around underground workings are at variance with the actual patterns of deformation and destruction of rocks near the workings in deep horizons.« less

  4. Impacts of chemical modification on the toxicity of diverse nanocellulose materials to developing zebrafish

    PubMed Central

    Harper, Bryan J.; Clendaniel, Alicea; Sinche, Federico; Way, Daniel; Hughes, Michael; Schardt, Jenna; Simonsen, John; Stefaniak, Aleksandr B.

    2016-01-01

    Cellulose is an abundant and renewable resource currently being investigated for utility in nanomaterial form for various promising applications ranging from medical and pharmaceutical uses to mechanical reinforcement and biofuels. The utility of nanocellulose and wide implementation ensures increasing exposure to humans and the environment as nanocellulose-based technologies advance. Here, we investigate how differences in aspect ratio and changes to surface chemistry, as well as synthesis methods, influence the biocompatibility of nanocellulose materials using the embryonic zebrafish. Investigations into the toxicity of neutral, cationic and anionic surface functionalities revealed that surface chemistry had a minimal influence on the overall toxicity of nanocellulose materials. Higher aspect ratio cellulose nanofibers produced by mechanical homogenization were, in some cases, more toxic than other cellulose-based nanofibers or nanocrystals produced by chemical synthesis methods. Using fluorescently labeled nanocellulose we were able to show that nanocellulose uptake did occur in embryonic zebrafish during development. We conclude that the benign nature of nanocellulose materials makes them an ideal platform to systematically investigate the inherent surface features driving nanomaterial toxicity in order to create safer design principles for engineered nanoparticles. PMID:27468180

  5. Toxic substances registry system: Index of material safety data sheets

    NASA Technical Reports Server (NTRS)

    1993-01-01

    The Material Safety Data Sheets (MSDS's) listed in this index reflect product inventories and associated MSDS's which were submitted to the Toxic Substances Registry database maintained by the Base Operations Contractor at the Kennedy Space Center. The purpose of this index is to provide KSC government, contractor, and tenant organizations a means to access information on the hazards associated with these chemicals. The Toxic Substance Registry Service (TSRS) was established to manage information dealing with the storage and use of toxic and otherwise hazardous materials at KSC. As a part of this service, the BOC Environmental Health Services maintains a central repository of MSDS's which were provided to TSRS. The data on the TSRS are obtained from NASA, contractor, and tenant organizations who use or store hazardous materials at KSC. It is the responsibility of these organizations to conduct inventories, obtain MSDS's, distribute Hazard Communication information to their employees, and otherwise implement compliance with appropriate Federal, State, and NASA Hazard Communication and Worker Right-to-Know regulations and policies.

  6. Environmental Assessment: Demolish CASS Switch Stations Buildings 644, 645, 646 at Grand Forks Air Force Base

    DTIC Science & Technology

    2006-06-01

    Per Year TSCA Toxic Substance Control Act TSI Thermal System Insulation UAV Unmanned Aerial Vehicle UHF Ultra High Frequency UPS Uninterruptible...Conservation and Recovery Act (RCRA) of 1976 [42 U.S.C. Sec. 6901, et seq.] • Toxic Substances Control Act (TSCA) of 1976 [15 U.S.C. Sec. 2601, et...Corporation (SAIC). Typical hazardous materials include reactive materials such as explosives, ignitables, toxics , and corrosives. Improper storage can

  7. A PEG-Based Hydrogel for Effective Wound Care Management

    PubMed Central

    Chen, Sen-Lu; Fu, Ru-Huei; Liao, Shih-Fei; Liu, Shih-Ping; Lin, Shinn-Zong; Wang, Yu-Chi

    2018-01-01

    It is extremely challenging to achieve strong adhesion in soft tissues while minimizing toxicity, tissue damage, and other side effects caused by wound sealing materials. In this study, flexible synthetic hydrogel sealants were prepared based on polyethylene glycol (PEG) materials. PEG is a synthetic material that is nontoxic and inert and, thus, suitable for use in medical products. We evaluated the in vitro biocompatibility tests of the dressings to assess cytotoxicity and irritation, sensitization, pyrogen toxicity, and systemic toxicity following the International Organization for Standardization 10993 standards and the in vivo effects of the hydrogel samples using Coloskin liquid bandages as control samples for potential in wound closure. PMID:29637814

  8. Lead-free solders: issues of toxicity, availability and impacts of extraction

    NASA Technical Reports Server (NTRS)

    Ku, A.; Shapiro, A. A.; Kua, A.; Ogunseitan, O.; Saphores, J. D.; Schoenung, J. M.

    2003-01-01

    This project set out to evaluate the critical issues of toxicity and public health effects, material availability, and the environmental impacts of raw material extraction and metal finishing, with the goal of using environmental impact as a factor in selecting feasible lead-free alloys.

  9. MODELING THE FATE OF TOXIC ORGANIC MATERIALS IN AQUATIC ENVIRONMENTS

    EPA Science Inventory

    Documentation is given for PEST, a dynamic simulation model for evaluating the fate of toxic organic materials (TOM) in freshwater environments. PEST represents the time-varying concentration (in ppm) of a given TOM in each of as many as 16 carrier compartments; it also computes ...

  10. TOXICITY TESTING OF RESTORATIVE DENTAL MATERIALS USING BRINE SHRIMP LARVAE (ARTEMIA SALINA)

    PubMed Central

    Milhem, Manar M.; Al-Hiyasat, Ahmad S.; Darmani, Homa

    2008-01-01

    This study investigated the effect of extracts of different composites, glass ionomer cement (GIC)s and compomers on the viability of brine shrimp larvae. Ethanolic extracts of four dental composites (Z-100; Solitaire 2; Filtek P60 and Synergy), a conventional GIC (Ketac-Fil), a resin-modified glass ionomer cement (Vitremer), two compomers (F2000; Dyract AP), and a flowable compomer (Dyract Flow) were prepared from each material. Following evaporation of the ethanol, the extracts were resuspended in distilled water, which was then used to test the effects on the viability of brine shrimp larvae. For the composites, the extract of Synergy was the least toxic (88% viability) followed by the extracts of Solitaire 2, Z100 and P60 (75%, 67.5% and 50% viability, respectively). One-way ANOVA revealed highly significant differences between the resin composite materials (p<0.001). Follow-up comparison between the composite groups by Tukey's pairwise multiple-comparison test (α =0.05) showed that the extract of Synergy was significantly less toxic than the extracts of all the other materials except that of Solitaire 2. The compomers showed 100% lethality, while the percentage of viable larvae for the extracts of Ketac-Fil, and Vitremer were 32.3%, and 37.0%, respectively. One-way ANOVA revealed highly significant differences between the groups of materials (p<0.001). Follow-up comparison between the groups by Tukey's test (α = 0.05) showed that the toxic effect of the extracts of the compomers were significantly greater than that of Ketac-Fil, and Vitremer. The differences in the toxic effects of Vitremer and Ketac-Fil were not statistically significant. In conclusion, the toxicity of composite materials varied according to their chemical composition. Compomers were the most lethal materials to brine shrimp larvae followed by GICs and then composites. PMID:19089264

  11. Geological problems in radioactive waste isolation - A world wide review

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Witherspoon, P.A.

    1991-06-01

    The problem of isolating radioactive wastes from the biosphere presents specialists in the earth sciences with some of the most complicated problems they have ever encountered. This is especially true for high-level waste (HLW), which must be isolated in the underground and away from the biosphere for thousands of years. The most widely accepted method of doing this is to seal the radioactive materials in metal canisters that are enclosed by a protective sheath and placed underground in a repository that has been carefully constructed in an appropriate rock formation. Much new technology is being developed to solve the problemsmore » that have been raised, and there is a continuing need to publish the results of new developments for the benefit of all concerned. Table 1 presents a summary of the various formations under investigation according to the reports submitted for this world wide review. It can be seen that in those countries that are searching for repository sites, granitic and metamorphic rocks are the prevalent rock type under investigation. Six countries have developed underground research facilities that are currently in use. All of these investigations are in saturated systems below the water table, except the United States project, which is in the unsaturated zone of a fractured tuff.« less

  12. Bioarchitecture - a new vision of energy sustainable cities

    NASA Astrophysics Data System (ADS)

    Krzemińska, Alicja; Zaręba, Anna; Dzikowska, Anna

    2017-11-01

    Transformation of the natural environment will press the humanity to search for the new look at the problems of architecture and urban design. Nowadays passive houses construction is a standard and green roofs are incorporated in the design of contemporary cities. That's why city cluster will be successively transformed into sustainable bionic systems, which allows to protect the nature and stop further degradation and exploitation of public green space. The good examples of contemporary trend of designing in harmony with nature are energy sustainable underground buildings of Malcolm Wells, who in 60s designed his first energy sufficient construction. The underground cities and rock houses were built from the early beginning of architecture, with significant examples of cities: Sanmenxia in China in Henan Province, Matmata (Tunisia), Cappadocia (Turkey), Uplisciche (Georgia) or Brlhovce (Slovakia) etc. The underground buildings and cities, blending in with the background of topography, have a positive influence on the landscape and are energy sustainable. Climate responsive design materials create effective insulation, which allows to maintain the stable temperature inside the buildings. Bioarchitecture improves the microclimate in the neighborhood through increasing oxygen concentration in atmosphere and limiting of CO2 emission. Bioarchitecture represents new direction in changing the design priorities towards being closer with nature and it's needs.

  13. [Dust and gas factors in extraction of polymetallic ore in Arctic conditions and their hygienic assessment].

    PubMed

    Borisenkova, R V; Lutsenko, L A; Skriabin, S Iu; Khristenko, P P

    1996-01-01

    Studies of drilling and blasting method of copper and nickel ores extraction at underground Transpolar mines proved that the highest concentrations of dust appeared during dry drilling of vertical blast holes, work of scraper windlass, fragmentation of out-size blocks, preparation of concrete mixture. Presence of aggressive metals, especially nickel, in the ore dust is a main base for planned thorough investigations of fibrogenic, toxic and carcinogenic effects of copper and nickel ore dust, for more precise assessment of its MAC in the air of workplace. Two-step purification of exhaust gases appearing due to mining diesel machines is not quite efficient, as the concentrations of nitrogen oxides (assessed through nitrogen dioxide) continually exceeded the MAC.

  14. Fire resistivity and toxicity studies of candidate aircraft passenger seat materials

    NASA Technical Reports Server (NTRS)

    Fewell, L. L.; Trabold, E. L.; Spieth, H.

    1978-01-01

    Fire resistivity studies were conducted on a wide range of candidate nonmetallic materials being considered for the construction of improved fire resistant aircraft passenger seats. These materials were evaluated on the basis of FAA airworthiness burn and smoke generation tests, colorfastness, limiting oxygen index, and animal toxicity tests. Physical, mechanical, and aesthetic properties were also assessed. Candidate seat materials that have significantly improved thermal response to various thermal loads corresponding to reasonable fire threats as they relate to in-flight fire situations, are identified.

  15. A Psychosocial Approach to Understanding Underground Spaces

    PubMed Central

    Lee, Eun H.; Christopoulos, George I.; Kwok, Kian W.; Roberts, Adam C.; Soh, Chee-Kiong

    2017-01-01

    With a growing need for usable land in urban areas, subterranean development has been gaining attention. While construction of large underground complexes is not a new concept, our understanding of various socio-cultural aspects of staying underground is still at a premature stage. With projected emergence of underground built environments, future populations may spend much more of their working, transit, and recreational time in underground spaces. Therefore, it is essential to understand the challenges and advantages that such environments have to improve the future welfare of users of underground spaces. The current paper discusses various psycho-social aspects of underground spaces, the impact they can have on the culture shared among the occupants, and possible solutions to overcome some of these challenges. PMID:28400744

  16. A Psychosocial Approach to Understanding Underground Spaces.

    PubMed

    Lee, Eun H; Christopoulos, George I; Kwok, Kian W; Roberts, Adam C; Soh, Chee-Kiong

    2017-01-01

    With a growing need for usable land in urban areas, subterranean development has been gaining attention. While construction of large underground complexes is not a new concept, our understanding of various socio-cultural aspects of staying underground is still at a premature stage. With projected emergence of underground built environments, future populations may spend much more of their working, transit, and recreational time in underground spaces. Therefore, it is essential to understand the challenges and advantages that such environments have to improve the future welfare of users of underground spaces. The current paper discusses various psycho-social aspects of underground spaces, the impact they can have on the culture shared among the occupants, and possible solutions to overcome some of these challenges.

  17. High-performance green flexible electronics based on biodegradable cellulose nanofibril paper

    PubMed Central

    Jung, Yei Hwan; Chang, Tzu-Hsuan; Zhang, Huilong; Yao, Chunhua; Zheng, Qifeng; Yang, Vina W.; Mi, Hongyi; Kim, Munho; Cho, Sang June; Park, Dong-Wook; Jiang, Hao; Lee, Juhwan; Qiu, Yijie; Zhou, Weidong; Cai, Zhiyong; Gong, Shaoqin; Ma, Zhenqiang

    2015-01-01

    Today's consumer electronics, such as cell phones, tablets and other portable electronic devices, are typically made of non-renewable, non-biodegradable, and sometimes potentially toxic (for example, gallium arsenide) materials. These consumer electronics are frequently upgraded or discarded, leading to serious environmental contamination. Thus, electronic systems consisting of renewable and biodegradable materials and minimal amount of potentially toxic materials are desirable. Here we report high-performance flexible microwave and digital electronics that consume the smallest amount of potentially toxic materials on biobased, biodegradable and flexible cellulose nanofibril papers. Furthermore, we demonstrate gallium arsenide microwave devices, the consumer wireless workhorse, in a transferrable thin-film form. Successful fabrication of key electrical components on the flexible cellulose nanofibril paper with comparable performance to their rigid counterparts and clear demonstration of fungal biodegradation of the cellulose-nanofibril-based electronics suggest that it is feasible to fabricate high-performance flexible electronics using ecofriendly materials. PMID:26006731

  18. High-performance green flexible electronics based on biodegradable cellulose nanofibril paper.

    PubMed

    Jung, Yei Hwan; Chang, Tzu-Hsuan; Zhang, Huilong; Yao, Chunhua; Zheng, Qifeng; Yang, Vina W; Mi, Hongyi; Kim, Munho; Cho, Sang June; Park, Dong-Wook; Jiang, Hao; Lee, Juhwan; Qiu, Yijie; Zhou, Weidong; Cai, Zhiyong; Gong, Shaoqin; Ma, Zhenqiang

    2015-05-26

    Today's consumer electronics, such as cell phones, tablets and other portable electronic devices, are typically made of non-renewable, non-biodegradable, and sometimes potentially toxic (for example, gallium arsenide) materials. These consumer electronics are frequently upgraded or discarded, leading to serious environmental contamination. Thus, electronic systems consisting of renewable and biodegradable materials and minimal amount of potentially toxic materials are desirable. Here we report high-performance flexible microwave and digital electronics that consume the smallest amount of potentially toxic materials on biobased, biodegradable and flexible cellulose nanofibril papers. Furthermore, we demonstrate gallium arsenide microwave devices, the consumer wireless workhorse, in a transferrable thin-film form. Successful fabrication of key electrical components on the flexible cellulose nanofibril paper with comparable performance to their rigid counterparts and clear demonstration of fungal biodegradation of the cellulose-nanofibril-based electronics suggest that it is feasible to fabricate high-performance flexible electronics using ecofriendly materials.

  19. High-performance green flexible electronics based on biodegradable cellulose nanofibril paper

    NASA Astrophysics Data System (ADS)

    Jung, Yei Hwan; Chang, Tzu-Hsuan; Zhang, Huilong; Yao, Chunhua; Zheng, Qifeng; Yang, Vina W.; Mi, Hongyi; Kim, Munho; Cho, Sang June; Park, Dong-Wook; Jiang, Hao; Lee, Juhwan; Qiu, Yijie; Zhou, Weidong; Cai, Zhiyong; Gong, Shaoqin; Ma, Zhenqiang

    2015-05-01

    Today's consumer electronics, such as cell phones, tablets and other portable electronic devices, are typically made of non-renewable, non-biodegradable, and sometimes potentially toxic (for example, gallium arsenide) materials. These consumer electronics are frequently upgraded or discarded, leading to serious environmental contamination. Thus, electronic systems consisting of renewable and biodegradable materials and minimal amount of potentially toxic materials are desirable. Here we report high-performance flexible microwave and digital electronics that consume the smallest amount of potentially toxic materials on biobased, biodegradable and flexible cellulose nanofibril papers. Furthermore, we demonstrate gallium arsenide microwave devices, the consumer wireless workhorse, in a transferrable thin-film form. Successful fabrication of key electrical components on the flexible cellulose nanofibril paper with comparable performance to their rigid counterparts and clear demonstration of fungal biodegradation of the cellulose-nanofibril-based electronics suggest that it is feasible to fabricate high-performance flexible electronics using ecofriendly materials.

  20. Particle Shape Effect on Macroscopic Behaviour of Underground Structures: Numerical and Experimental Study

    NASA Astrophysics Data System (ADS)

    Szarf, Krzysztof; Combe, Gael; Villard, Pascal

    2015-02-01

    The mechanical performance of underground flexible structures such as buried pipes or culverts made of plastics depend not only on the properties of the structure, but also on the material surrounding it. Flexible drains can deflect by 30% with the joints staying tight, or even invert. Large deformations of the structure are difficult to model in the framework of Finite Element Method, but straightforward in Discrete Element Methods. Moreover, Discrete Element approach is able to provide information about the grain-grain and grain-structure interactions at the microscale. This paper presents numerical and experimental investigations of flexible buried pipe behaviour with focus placed on load transfer above the buried structure. Numerical modeling was able to reproduce the experimental results. Load repartition was observed, being affected by a number of factors such as particle shape, pipe friction and pipe stiffness.

  1. Blasting for abandoned-mine land reclamation (closure of individual subsidence features and erratic, undocumented underground coal-mine workings). Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Workman, J.L.; Thompson, J.

    1991-01-01

    The study has examined the feasibility of blasting for mitigating various abandoned mine land features on AML sites. The investigation included extensive field trial blasts at sites in North Dakota and Montana. A blasting technique was used that was based on spherical cratering concepts. At the Beulah, North Dakota site thirteen individual vertical openings (sinkholes) were blasted with the intent to fill the voids. The blasts were designed to displace material laterally into the void. Good success was had in filling the sinkholes. At the White site in Montana erratic underground rooms with no available documentation were collapsed. An aditmore » leading into the mine was also blasted. Both individual room blasting and area pattern blasting were studied. A total of eight blasts were fired on the one acre area. Exploration requirements and costs were found to be extensive.« less

  2. Peaceful Uses of Fusion

    DOE R&D Accomplishments Database

    Teller, E.

    1958-07-03

    Applications of thermonuclear energy for peaceful and constructive purposes are surveyed. Developments and problems in the release and control of fusion energy are reviewed. It is pointed out that the future of thermonuclear power reactors will depend upon the construction of a machine that produces more electric energy than it consumes. The fuel for thermonuclear reactors is cheap and practically inexhaustible. Thermonuclear reactors produce less dangerous radioactive materials than fission reactors and, when once brought under control, are not as likely to be subject to dangerous excursions. The interaction of the hot plasma with magnetic fields opens the way for the direct production of electricity. It is possible that explosive fusion energy released underground may be harnessed for the production of electricity before the same feat is accomplished in controlled fusion processes. Applications of underground detonations of fission devices in mining and for the enhancement of oil flow in large low-specific-yield formations are also suggested.

  3. Method and apparatus for constructing an underground barrier wall structure

    DOEpatents

    Dwyer, Brian P.; Stewart, Willis E.; Dwyer, Stephen F.

    2002-01-01

    A method and apparatus for constructing a underground barrier wall structure using a jet grout injector subassembly comprising a pair of primary nozzles and a plurality of secondary nozzles, the secondary nozzles having a smaller diameter than the primary nozzles, for injecting grout in directions other than the primary direction, which creates a barrier wall panel having a substantially uniform wall thickess. This invention addresses the problem of the weak "bow-tie" shape that is formed during conventional jet injection when using only a pair of primary nozzles. The improvement is accomplished by using at least four secondary nozzles, of smaller diameter, located on both sides of the primary nozzles. These additional secondary nozzles spray grout or permeable reactive materials in other directions optimized to fill in the thin regions of the bow-tie shape. The result is a panel with increased strength and substantially uniform wall thickness.

  4. Urban Underground Pipelines Mapping Using Ground Penetrating Radar

    NASA Astrophysics Data System (ADS)

    Jaw, S. W.; M, Hashim

    2014-02-01

    Underground spaces are now being given attention to exploit for transportation, utilities, and public usage. The underground has become a spider's web of utility networks. Mapping of underground utility pipelines has become a challenging and difficult task. As such, mapping of underground utility pipelines is a "hit-and-miss" affair, and results in many catastrophic damages, particularly in urban areas. Therefore, this study was conducted to extract locational information of the urban underground utility pipeline using trenchless measuring tool, namely ground penetrating radar (GPR). The focus of this study was to conduct underground utility pipeline mapping for retrieval of geometry properties of the pipelines, using GPR. In doing this, a series of tests were first conducted at the preferred test site and real-life experiment, followed by modeling of field-based model using Finite-Difference Time-Domain (FDTD). Results provide the locational information of underground utility pipelines associated with its mapping accuracy. Eventually, this locational information of the underground utility pipelines is beneficial to civil infrastructure management and maintenance which in the long term is time-saving and critically important for the development of metropolitan areas.

  5. Toxic Substances Registry System. Index of Material Safety Data Sheets

    NASA Technical Reports Server (NTRS)

    1994-01-01

    The October 1994 revision of the KSC Toxic Substances Registry System (TSRS) Material Safety Data Sheets (MSD's) is presented. The listed MSD's which were submitted to the TSRS are maintained by the Base Operations Contractors of the Biomedical Operations and Research Office of KSC. The purpose of the index is to provide a means of accessing information on the hazards associated with the toxic and otherwise hazardous chemicals stored and used at KSC. Indices are provided for manufacturers, trademarks, and stock numbers.

  6. Simultaneous gas-chromatographic determination of toxic gases in combustion atmospheres.

    DOT National Transportation Integrated Search

    1994-09-01

    Measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Since toxic effects of gases depend on both their concentrations and duration of exposures, frequent atmosphere sa...

  7. Reducing Environmental Toxicity of Silver Nanoparticles through Shape Control.

    PubMed

    Gorka, Danielle E; Osterberg, Joshua S; Gwin, Carley A; Colman, Benjamin P; Meyer, Joel N; Bernhardt, Emily S; Gunsch, Claudia K; DiGulio, Richard T; Liu, Jie

    2015-08-18

    The use of antibacterial silver nanomaterials in consumer products ranging from textiles to toys has given rise to concerns over their environmental toxicity. These materials, primarily nanoparticles, have been shown to be toxic to a wide range of organisms; thus methods and materials that reduce their environmental toxicity while retaining their useful antibacterial properties can potentially solve this problem. Here we demonstrate that silver nanocubes display a lower toxicity toward the model plant species Lolium multiflorum while showing similar toxicity toward other environmentally relevant and model organisms (Danio rerio and Caenorhabditis elegans) and bacterial species (Esherichia coli, Bacillus cereus, and Pseudomonas aeruginosa) compared to quasi-spherical silver nanoparticles and silver nanowires. More specifically, in the L. multiflorum experiments, the roots of silver nanocube treated plants were 5.3% shorter than the control, while silver nanoparticle treated plant roots were 39.6% shorter than the control. The findings here could assist in the future development of new antibacterial products that cause less environmental toxicity after their intended use.

  8. Geophysical aspects of underground fluid dynamics and mineral transformation process

    NASA Astrophysics Data System (ADS)

    Khramchenkov, Maxim; Khramchenkov, Eduard

    2014-05-01

    The description of processes of mass exchange between fluid and poly-minerals material in porous media from various kinds of rocks (primarily, sedimentary rocks) have been examined. It was shown that in some important cases there is a storage equation of non-linear diffusion equation type. In addition, process of filtration in un-swelling soils, swelling porous rocks and coupled process of consolidation and chemical interaction between fluid and particles material were considered. In the latter case equations of physical-chemical mechanics of conservation of mass for fluid and particles material were used. As it is well known, the mechanics of porous media is theoretical basis of such branches of science as rock mechanics, soil physics and so on. But at the same moment some complex processes in the geosystems lacks full theoretical description. The example of such processes is metamorphosis of rocks and correspondent variations of stress-strain state. In such processes chemical transformation of solid and fluid components, heat release and absorption, phase transitions, rock destruction occurs. Extensive usage of computational resources in limits of traditional models of the mechanics of porous media cannot guarantee full correctness of obtained models and results. The process of rocks consolidation which happens due to filtration of underground fluids is described from the position of rock mechanics. As an additional impact, let us consider the porous media consolidating under the weight of overlying rock with coupled complex geological processes, as a continuous porous medium of variable mass. Problems of obtaining of correct storage equations for coupled processes of consolidation and mass exchange between underground fluid and skeleton material are often met in catagenesi processes description. The example of such processes is metamorphosis of rocks and correspondent variations of stress-strain state. In such processes chemical transformation of solid and fluid components, heat release and absorption, phase transitions, rock destruction occurs. Extensive usage of computational resources in limits of traditional models of the mechanics of porous media cannot guarantee full correctness of obtained models and results. The present work is dedicated to the retrieval of new ways to formulate and construct such models. It was shown that in some important cases there is a governing equation of non-linear diffusion equation type (well-known Fisher equation). In addition, some geophysical aspects of filtration process in usual non-swelling soils, swelling porous rocks and coupled process of consolidation and chemical interaction between fluid and skeleton material, including earth quakes, are considered.

  9. A toxicologic and dermatologic assessment of cinnamyl phenylpropyl materials when used as fragrance ingredients.

    PubMed

    Belsito, D; Bickers, D; Bruze, M; Calow, P; Dagli, M; Fryer, A D; Greim, H; Miyachi, Y; Saurat, J H; Sipes, I G

    2011-12-01

    The cinnamyl phenylpropyl fragrance ingredients are a diverse group of chemical structures that have similar metabolic and toxicity profiles. A toxicological and dermatological review of these fragrance ingredients is presented. The common characteristic structural element of cinnamyl phenylpropyl materials is an aryl substituted primary alcohol/aldehyde/ester. For high end users, calculated maximum dermal exposures vary from 0.14% to 0.72%; systemic exposures vary from 0.0002 to 0.0280 mg/kg/day. Human dermatological studies show that these materials are not generally irritants or sensitizers at lower exposures from consumer products. Reactions (0.9%) in fragrance sensitive patients were observed with 3-phenyl-1-propanol at 5% in petrolatum. The cinnamyl phenylpropyl materials had low acute toxicity and no significant toxicity in repeat dose oral or dermal toxicity studies. No mutagenic or genotoxic activity in bacteria and mammalian cell line assays was observed. The cinnamyl phenylpropyl alcohol materials participate in the same beta oxidation pathways as their parent cinnamic acid derivatives, including common routes of absorption, distribution, and metabolic detoxification, and exhibit similar toxicological endpoints. Based on the review of available data, it is concluded that these materials would not present a safety concern at current levels of use as fragrance ingredients. Copyright © 2011 Elsevier Ltd. All rights reserved.

  10. Evidence of Human Health Impacts from Uncontrolled Coal Fires in Jharia, India

    NASA Astrophysics Data System (ADS)

    Dhar, U.; Balogun, A. H.; Finkelman, R.; Chakraborty, S.; Olanipekun, O.; Shaikh, W. A.

    2017-12-01

    Uncontrolled coal fires and burning coal waste piles have been reported from dozens of countries. These fires can be caused by spontaneous combustion, sparks from machinery, lightning strikes, grass or forest fires, or intentionally. Both underground and surface coal fires mobilize potentially toxic elements such as sulfur, arsenic, selenium, fluorine, lead, and mercury as well as dangerous organic compounds such as benzene, toluene, xylene, ethylbenzene and deadly gases such as CO2 and CO. Despite the serious health problems that can be caused by uncontrolled coal fires it is rather surprising that there has been so little research and documentation of their health impacts. Underground coal fires in the Jharia region of India where more than a million people reside, have been burning for 100 years. Numerous villages exist above the underground fires exposing the residents daily to dangerous emissions. Local residents near the fire affected areas do their daily chores without concern about the intensity of nearby fires. During winter children enjoy the heat of the coal fires oblivious to the potentially harmful emissions. To determine if these uncontrolled coal fires have caused health problems we developed a brief questionnaire on general health indices and administered it to residents of the Jharia region. Sixty responses were obtained from residents of two villages, one proximal to the coal fires and one about 5 miles away from the fires. The responses were statistically analyzed using SAS 9.4. It was observed that at a significance level of 5%, villagers who lived more than 5 miles away from the fires had a 98.3% decreased odds of having undesirable health outcomes. This brief survey indicates the risk posed by underground coal fires and how it contributes to the undesirable health impacts. What remains is to determine the specific health issues, what components of the emissions cause the health problems, and what can be done to minimize these problems. Collaboration between geoscientists and public health researchers are essential to assess complex geohealth issues such as those that may be caused by uncontrolled coal fires. This type of multidisciplinary collaboration must be maintained and expanded to include engineers, social scientists, and others to help minimize or avoid these problems.

  11. 77 FR 47668 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Underground...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-09

    ... extract oil from shale in underground metal and nonmetal I-A and I-B mines (those that operate in a... underground oil shale mines. The standard requires that, prior to ignition of underground retorts, mine...

  12. Research on joint parameter inversion for an integrated underground displacement 3D measuring sensor.

    PubMed

    Shentu, Nanying; Qiu, Guohua; Li, Qing; Tong, Renyuan; Shentu, Nankai; Wang, Yanjie

    2015-04-13

    Underground displacement monitoring is a key means to monitor and evaluate geological disasters and geotechnical projects. There exist few practical instruments able to monitor subsurface horizontal and vertical displacements simultaneously due to monitoring invisibility and complexity. A novel underground displacement 3D measuring sensor had been proposed in our previous studies, and great efforts have been taken in the basic theoretical research of underground displacement sensing and measuring characteristics by virtue of modeling, simulation and experiments. This paper presents an innovative underground displacement joint inversion method by mixing a specific forward modeling approach with an approximate optimization inversion procedure. It can realize a joint inversion of underground horizontal displacement and vertical displacement for the proposed 3D sensor. Comparative studies have been conducted between the measured and inversed parameters of underground horizontal and vertical displacements under a variety of experimental and inverse conditions. The results showed that when experimentally measured horizontal displacements and vertical displacements are both varied within 0~30 mm, horizontal displacement and vertical displacement inversion discrepancies are generally less than 3 mm and 1 mm, respectively, under three kinds of simulated underground displacement monitoring circumstances. This implies that our proposed underground displacement joint inversion method is robust and efficient to predict the measuring values of underground horizontal and vertical displacements for the proposed sensor.

  13. High altitude mine waste remediation -- Implementation of the Idarado remedial action plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hardy, A.J.; Redmond, J.V.; River, R.A.

    1999-07-01

    The Idarado Mine in Colorado's San Juan Mountains includes 11 tailing areas, numerous waste rock dumps, and a large number of underground openings connected by over 100 miles of raises and drifts. The tailings and mine wastes were generated from different mining and milling operations between 1975 and 1978. the Idarado Remedial Action Plan (RAP) was an innovative 5-year program developed for remediating the impacts of historic mining activities in the San Miguel River and Red Mountain Creek drainages. The challenges during implementation included seasonal access limitations due to the high altitude construction areas, high volumes of runoff during snowmore » melt, numerous abandoned underground openings and stopped-out veins, and high profile sites adjacent to busy jeep trails and a major ski resort town. Implementation of the RAP has included pioneering efforts in engineering design and construction of remedial measures. Innovative engineering designs included direct revegetation techniques for the stabilization of tailings piles, concrete cutoff walls and French drains to control subsurface flows, underground water controls that included pipelines, weeplines, and portal collection systems, and various underground structures to collect and divert subsurface flows often exceeding 2,000 gpm. Remote work locations have also required the use of innovative construction techniques such as heavy lift helicopters to move construction materials to mines above 10,000 feet. This paper describes the 5-year implementation program which has included over 1,000,000 cubic yards of tailing regrading, application of 5,000 tons of manure and 26,000 tons of limestone, and construction of over 10,000 feet of pipeline and approximately 45,000 feet of diversion channel.« less

  14. Lead isotopes and trace metals in dust at Yucca Mountain

    USGS Publications Warehouse

    Kwak, Loretta; Neymark, Leonid A.; Peterman, Zell E.

    2008-01-01

    Lead (Pb)-isotope compositions and trace-metal concentrations were determined for samples of dust collected from underground and surface locations at and near the proposed radioactive waste repository at Yucca Mountain, Nevada. Rare earth element concentrations in the dust samples from the underground tunnels are similar to those in wholerock samples of the repository host rocks (Miocene Tiva Canyon Tuff and Topopah Spring Tuff), supporting interpretation that the subsurface dust is mainly composed of rock comminuted during tunnel construction. Other trace metals (arsenic, cadmium, cobalt, chromium, copper, manganese, nickel, lead, antimony, thallium, and zinc) are variably enriched in the subsurface dust samples relative to the average concentrations in the host rocks. Average concentrations of arsenic and lead in dust samples, high concentrations of which can cause corrosion of waste canisters, have enrichment factors from 1.2 to 1.6 and are insignificant relative to the range of concentrations for these metals observed in the host rock samples. Most dust samples from surface sites also are enriched in many of these trace metals relative to average repository host rocks. At least some of these enrichments may be artifacts of sampling. Plotted on a 208Pb/206Pb-207Pb/206Pb graph, Pb-isotope compositions of dust samples from underground sites form a mixing line extending from host-rock Pb-isotope compositions towards compositions of many of the dust samples from surface sites; however, combined Pb concentration and isotope data indicate the presence of a Pbenriched component in the subsurface dust that is not derived from host rock or surface dust and may derive from anthropogenic materials introduced into the underground environment.

  15. Toxicity of combustion products from burning polymers: development and evaluation of methods

    PubMed Central

    Wright, P. L.; Adams, C. H.

    1976-01-01

    Laboratory and room-scale experiments were conducted with natural and synthetic polymers: cotton, paper, wood, wool, acetate, acrylic, nylon, and urethane. Smoke and off-gases from single materials were generated in a dual-compartment 110-liter exposure chamber. Multicomponent, composite fuel loads were burned within a 100 m3 facility subdivided into rooms. In chamber experiments, mortality depended on the amount of material burned, i.e., fuel consumption (FC). Conventional dose (FC)/mortality curves were obtained, and the amount of fuel required to produce 50% mortality (FC50) was calculated. With simple flame ignition, cotton was the only material that produced smoke concentrations lethal to rats; FC50 values for cotton ranged from 2 g to 9 g, depending on the configuration of the cotton sample burned. When supplemental conductive heat was added to flame ignition, the following FC50 values were obtained; nylon, 7 g; acrylic, 8 g; newsprint, 9 g; cotton, 10 g; and wood, 11 g. Mortality resulting from any given material depended upon the specific conditions employed for its thermal decomposition. Toxicity of off-gasses from pyrolysis of phosphorus-containing trimethylol propane—polyurethane foams was markedly decreased by addition of a flame ignition source. Further studies are needed to determine the possible relevance of single-material laboratory scale smoke toxicity experiments. Room-scale burns were conducted to assess the relative contributions of single materials to toxicity of smoke produced by a multicomponent self-perpetuating fire. Preliminary results suggest that this approach permits a realistic evaluation of the contribution of single materials to the toxicity of smoke from residential fires. ImagesFIGURE 2. PMID:1026420

  16. Surface modifications on InAs decrease indium and arsenic leaching under physiological conditions

    NASA Astrophysics Data System (ADS)

    Jewett, Scott A.; Yoder, Jeffrey A.; Ivanisevic, Albena

    2012-11-01

    Devices containing III-V semiconductors such as InAs are increasingly being used in the electronic industry for a variety of optoelectronic applications. Furthermore, the attractive chemical, material, electronic properties make such materials appealing for use in devices designed for biological applications, such as biosensors. However, in biological applications the leaching of toxic materials from these devices could cause harm to cells or tissue. Additionally, after disposal, toxic inorganic materials can leach from devices and buildup in the environment, causing long-term ecological harm. Therefore, the toxicity of these materials along with their stability in physiological conditions are important factors to consider. Surface modifications are one common method of stabilizing semiconductor materials in order to chemically and electronically passivate them. Such surface modifications could also prevent the leaching of toxic materials by preventing the regrowth of the unstable surface oxide layer and by creating an effective barrier between the semiconductor surface and the surrounding environment. In this study, various surface modifications on InAs are developed with the goal of decreasing the leaching of indium and arsenic. The leaching of indium and arsenic from modified substrates was assessed in physiological conditions using inductively coupled plasma mass spectrometry (ICP-MS). Substrates modified with 11-mercapto-1-undecanol (MU) and graft polymerized with poly(ethylene) glycol (PEG) were most effective at preventing indium and arsenic leaching. These surfaces were characterized using contact angle analysis, ellipsometry, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). Substrates modified with collagen and synthetic polyelectrolytes were least effective, due to the destructive nature of acidic environments on InAs. The toxicity of modified and unmodified InAs, along with raw indium, arsenic, and PEG components was assessed using zebrafish embryos.

  17. Conventional Expeditionary Forces: A 21st Century Triad for Strategic Deterrence

    DTIC Science & Technology

    2009-05-27

    testing and transfers of nuclear materials, the ability to effectively monitor and track all such activities 100% of the time does not exist at present nor...Limited Test Ban Treaty of 1963 sought to stabilize the arms race and reduce environmental damage by banning atmospheric, sea-based, and space-based...nuclear weapons tests , thereby limiting future testing to underground conditions, and was signed 139

  18. The effect of dilatancy on the unloading behavior of Mt. Helen tuff

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Attia, A.V.; Rubin, M.B.

    1993-11-01

    In order to understand the role of rock dilatancy in modeling the response of partially saturated rock formations to underground nuclear explosions, we have developed a thermodynamically consistent model for a porous material, partially saturated with fluid. This model gives good predictions of the unloading behavior of dry, partially saturated, and fully saturated Mt. Helen tuff, as measured by Heard.

  19. RIFM fragrance ingredient safety assessment, 3,7-dimethyl-1,6-nonadien-3-ol, CAS Registry Number 10339-55-6.

    PubMed

    Api, A M; Belsito, D; Bhatia, S; Bruze, M; Calow, P; Dagli, M L; Dekant, W; Fryer, A D; Kromidas, L; La Cava, S; Lalko, J F; Lapczynski, A; Liebler, D C; Miyachi, Y; Politano, V T; Ritacco, G; Salvito, D; Schultz, T W; Shen, J; Sipes, I G; Wall, B; Wilcox, D K

    2016-11-01

    The use of this material under current conditions is supported by existing information. This material was evaluated for genotoxicity, repeated dose toxicity, developmental and reproductive toxicity, local respiratory toxicity, phototoxicity/photoallergenicity, skin sensitization, as well as environmental safety. Data from the suitable read across analog linalool (CAS # 78-70-6) show that this material is not genotoxic nor does it have skin sensitization potential and also provided a MOE > 100 for the local respiratory endpoint. The repeated dose, developmental and reproductive toxicity endpoints were completed using nerolidol (isomer unspecified, CAS # 7212-44-4) as a suitable read across analog, which provided a MOE > 100. The phototoxicity/photoallergenicity endpoint was completed based on suitable UV spectra. The environmental endpoint was completed as described in the RIFM Framework. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. 78 FR 73471 - Refuge Alternatives for Underground Coal Mines

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-06

    ... Refuge Alternatives for Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor... Agency's Request for Information (RFI) on Refuge Alternatives for Underground Coal Mines. This extension...), MSHA published a Request for Information on Refuge Alternatives for Underground Coal Mines. The RFI...

  1. An Economic Comparison of Passively Conditioned Underground Houses.

    DTIC Science & Technology

    1981-05-01

    15 Heat Transfer ........ ..................... ... 34 Energy Balance and Human Thermal Comfort . ...... ... 41 Conclusion...114 29. Thermal Comfort --Passive Underground House ... ........... .. 117 30. Stable Soil Temperature Depths...121 31. Thermal Comfort --Deep Earth Underground House .. ......... .. 124 32. Life Cycle Cash Flow Diagram--Base Underground House

  2. Graphene oxide and reduced graphene oxide induced neural pheochromocytoma-derived PC12 cell lines apoptosis and cell cycle alterations via the ERK signaling pathways.

    PubMed

    Kang, Yiyuan; Liu, Jia; Wu, Junrong; Yin, Qian; Liang, Huimin; Chen, Aijie; Shao, Longquan

    2017-01-01

    Given the novel applications of graphene materials in biomedical and electronics industry, the health hazards of these particles have attracted extensive worldwide attention. Although many studies have been performed on graphene material-induced toxic effects, toxicological data for the effect of graphene materials on the nervous system are lacking. In this study, we focused on the biological effects of graphene oxide (GO) and reduced graphene oxide (rGO) materials on PC12 cells, a type of traditional neural cell line. We found that GO and rGO exerted significant toxic effects on PC12 cells in a dose- and time-dependent manner. Moreover, apoptosis appeared to be a response to toxicity. A potent increase in the number of PC12 cells at G0/G1 phase after GO and rGO exposure was detected by cell cycle analysis. We found that phosphorylation levels of ERK signaling molecules, which are related to cell cycle regulation and apoptosis, were significantly altered after GO and rGO exposure. In conclusion, our results show that GO has more potent toxic effects than rGO and that apoptosis and cell cycle arrest are the main toxicity responses to GO and rGO treatments, which are likely due to ERK pathway regulation.

  3. 30 CFR 75.1712-10 - Underground sanitary facilities; maintenance.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Underground sanitary facilities; maintenance... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1712-10 Underground sanitary facilities; maintenance. Sanitary toilets shall be regularly maintained in...

  4. 30 CFR 75.1712-10 - Underground sanitary facilities; maintenance.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Underground sanitary facilities; maintenance... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1712-10 Underground sanitary facilities; maintenance. Sanitary toilets shall be regularly maintained in...

  5. 30 CFR 75.1712-10 - Underground sanitary facilities; maintenance.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Underground sanitary facilities; maintenance... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1712-10 Underground sanitary facilities; maintenance. Sanitary toilets shall be regularly maintained in...

  6. 30 CFR 75.1712-10 - Underground sanitary facilities; maintenance.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground sanitary facilities; maintenance... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1712-10 Underground sanitary facilities; maintenance. Sanitary toilets shall be regularly maintained in...

  7. 30 CFR 75.1712-10 - Underground sanitary facilities; maintenance.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Underground sanitary facilities; maintenance... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Miscellaneous § 75.1712-10 Underground sanitary facilities; maintenance. Sanitary toilets shall be regularly maintained in...

  8. 30 CFR 57.4561 - Stationary diesel equipment underground.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Stationary diesel equipment underground. 57... Fire Prevention and Control Installation/construction/maintenance § 57.4561 Stationary diesel equipment underground. Stationary diesel equipment underground shall be— (a) Supported on a noncombustible base; and (b...

  9. 30 CFR 75.811 - High-voltage underground equipment; grounding.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...-voltage equipment supplying power to such equipment receiving power from resistance grounded systems shall... 30 Mineral Resources 1 2010-07-01 2010-07-01 false High-voltage underground equipment; grounding... COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Underground High-Voltage...

  10. Materials Safety Data Sheets: the basis for control of toxic chemicals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ketchen, E.E.; Porter, W.E.

    1979-09-01

    The Material Safety Data Sheets contained in this volume are the basis for the Toxic Chemical Control Program developed by the Industrial Hygiene Department, Health Division, ORNL. The three volumes are the update and expansion of ORNL/TM-5721 and ORNL/TM-5722 Material Safety Data Sheets: The Basis for Control of Toxic Chemicals, Volume I and Volume II. As such, they are a valuable adjunct to the data cards issued with specific chemicals. The chemicals are identified by name, stores catalog number where appropriate, and sequence numbers from the NIOSH Registry of Toxic Effects of Chemical Substances, 1977 Edition, if available. The datamore » sheets were developed and compiled to aid in apprising the employees of hazards peculiar to the handling and/or use of specific toxic chemicals. Space limitation necessitate the use of descriptive medical terms and toxicological abbreviations. A glossary and an abbreviation list were developed to define some of those sometimes unfamiliar terms and abbreviations. The page numbers are keyed to the catalog number in the chemical stores at ORNL.« less

  11. Materials Safety Data Sheets: the basis for control of toxic chemicals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ketchen, E.E.; Porter, W.E.

    The Material Safety Data Sheets contained in this volume are the basis for the Toxic Chemical Control Program developed by the Industrial Hygiene Department, Health Division, ORNL. The three volumes are the update and expansion of ORNL/TM-5721 and ORNL/TM-5722 Material Safety Data Sheets: The Basis for Control of Toxic Chemicals, Volume I and Volume II. As such, they are a valuable adjunct to the data cards issued with specific chemicals. The chemicals are identified by name, stores catalog number where appropriate, and sequence numbers from the NIOSH Registry of Toxic Effects of Chemical Substances, 1977 Edition, if available. The datamore » sheets were developed and compiled to aid in apprising the employees of hazards peculiar to the handling and/or use of specific toxic chemicals. Space limitation necessitate the use of descriptive medical terms and toxicological abbreviations. A glossary and an abbreviation list were developed to define some of those sometimes unfamiliar terms and abbreviations. The page numbers are keyed to the catalog number in the chemical stores at ORNL.« less

  12. Determination of the fire hazards of mine materials using a radiant panel.

    PubMed

    Harteis, S P; Litton, C D; Thomas, R A

    2016-01-01

    The objective of this study was to develop a laboratory-scale method to rank the ignition and fire hazards of commonly used underground mine materials and to eliminate the need for the expensive large-scale tests that are currently being used. A radiant-panel apparatus was used to determine the materials' relevant thermal characteristics: time to ignition, critical heat flux for ignition, heat of gasification, and mass-loss rate. Three thermal parameters, TRP , TP1 and TP4 , were derived from the data, then developed and subsequently used to rank the combined ignition and fire hazards of the combustible materials from low hazard to high hazard. The results compared favorably with the thermal and ignition hazards of similar materials reported in the literature and support this approach as a simpler one for quantifying these combustible hazards.

  13. Evaluation of dredged material proposed for ocean disposal from Hackensack River Project Area, New York

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gruendell, B.D.; Barrows, E.S.; Borde, A.B.

    1997-01-01

    The objective of the bioassay reevaluation of the Hackensack River Federal Project was to reperform toxicity testing on proposed dredged material with current ammonia reduction protocols. Hackensack River was one of four waterways sampled and evaluated for dredging and disposal in April 1993. Sediment samples were re-collected from the Hackensack River Project area in August 1995. Tests and analyses were conducted according to the manual developed by the USACE and the U.S. Environmental Protection Agency (EPA), Evaluation of Dredged Material Proposed for Ocean Disposal (Testing Manual), commonly referred to as the {open_quotes}Green Book,{close_quotes} and the regional manual developed by themore » USACE-NYD and EPA Region II, Guidance for Performing Tests on Dredged Material to be Disposed of in Ocean Waters. The reevaluation of proposed dredged material from the Hackensack River project area consisted of benthic acute toxicity tests. Thirty-three individual sediment core samples were collected from the Hackensack River project area. Three composite sediments, representing each reach of the area proposed for dredging, were used in benthic acute toxicity testing. Benthic acute toxicity tests were performed with the amphipod Ampelisca abdita and the mysid Mysidopsis bahia. The amphipod and mysid benthic toxicity test procedures followed EPA guidance for reduction of total ammonia concentrations in test systems prior to test initiation. Statistically significant acute toxicity was found in all three Hackensack River composites in the static renewal tests with A. abdita, but not in the static tests with M. bahia. Statistically significant acute toxicity and a greater than 20% increase in mortality over the reference sediment was found in the static renewal tests with A. abdita. Statistically significant mortality 10% over reference sediment was observed in the M. bahia static tests. 5 refs., 2 figs., 2 tabs.« less

  14. The mathematical model of radon-222 accumulation in underground mines

    NASA Astrophysics Data System (ADS)

    Klimshin, A.

    2012-04-01

    Necessity to control underground mine air radon level arises during building and operating mines as well as auto and railway tunnels including those for metros. Calculation of underground mine air radon level can be fulfilled for estimation of potential radon danger of area for underground structure building. In this work the new mathematical model of radon accumulation in underground mines has been suggested. It takes into consideration underground mine dimensions, air exchange factor and soils ability to emanate radon. The following assumptions have been taken for model development. It is assumed that underground mine is a cylinder of length L and of base area S. Due to ventilation atmosphere air of volume activity Catm, is coming in through one cylinder base and is going out of volume activity Cind from underground mine. Diffusion radon flux is coming in through side surfaces of underground mine. The sources of this flux are radium-226 atoms distributed evenly in rock. For simplification of the task it considered possible to disregard radon emanation by loosened rock and underground waters. As a result of solution of the radon diffusion equation the following expression for calculation of radon volume activity in underground space air has been got: 2·r0 ·λv ·Catm-·l·K0(r0/l)-+D-·K1(r0/l)·C0- Cind = 2·(λ+ λv)·r0 ·l·K0 (r0/l)+ D ·K1(r0/l) . The following designations are used in this expression: Kν(r) - the second genus modified Bessel's function, C0 - equilibrium radon volume activity in soil air, l - diffusion radon length in soil, D - radon diffusion factor, r0 - radius of underground tunnel, λv - factor of air exchange. Expression found may be used for calculation of the minimum factor of necessary air exchange for ensuring safe radon levels in underground spaces. With this worked out model expected levels of radon volume activity were calculated for air in the second metro line underground spaces in the city of Yekaterinburg, Russia.

  15. Teaching about Hazardous and Toxic Materials. Teaching Activities in Environmental Education Series.

    ERIC Educational Resources Information Center

    Disinger, John F.; Lisowski, Marylin

    Designed to assist practitioners of both formal and non-formal settings, this 18th volume of the ERIC Clearinghouse for Science, Mathematics, and Environmental Education's Teaching Activities in Environmental Education series specifically focuses on the theme of hazardous and toxic materials. Initially, basic environmental concepts that deal with…

  16. Radiation release at the nation's only operating deep geological repository--an independent monitoring perspective.

    PubMed

    Thakur, P; Ballard, S; Hardy, R

    2014-11-04

    Recent incidents at the nation's only operating deep geologic nuclear waste repository, the Waste Isolation Pilot Plant (WIPP), resulted in the release of americium and plutonium from one or more defense-related transuranic (TRU) waste containers into the environment. WIPP is a U.S. Department of Energy mined geologic repository that has been in operation since March, 1999. Over 85,000 m3 of waste in various vented payload containers have been emplaced in the repository. The primary radionuclides within the disposed waste are 239+240Pu and 241Am, which account for more than 99% of the total TRU radioactivity disposed and scheduled for disposal in the repository. For the first time in its 15 years of operation, there was an airborne radiation release from the WIPP at approximately 11:30 PM Mountain Standard Time (MST) on Friday, February 14, 2014. The radiation release was likely caused by a chemical reaction inside a TRU waste drum that contained nitrate salts and organic sorbent materials. In a recent news release, DOE announced that photos taken of the waste underground showed evidence of heat and gas pressure resulting in a deformed lid, in material expelled through that deformation, and in melted plastic and rubber and polyethylene in the vicinity of that drum. Recent entries into underground Panel 7 have confirmed that at least one waste drum containing a nitrate salt bearing waste stream from Los Alamos National Laboratory was breached underground and was the most likely source of the release. Further investigation is underway to determine if other containers contributed to the release. Air monitoring across the WIPP site intensified following the first reports of radiation detection underground to ascertain whether or not there were releases to the ground surface. Independent analytical results of air filters from sampling stations on and near the WIPP facility have been released by us at the Carlsbad Environmental Monitoring & Research Center and confirmed trace amounts of 241Am and 239+240Pu, at ratios reflecting the suspect waste stream. The highest activity detected offsite was 115.2 μBq/m3 for 241Am and 10.2 μBq/m3 for 239+240 Pu. These concentrations in air were very small, localized, and below any level of public health or environmental concern.

  17. Biological Interactions of Graphene-Family Nanomaterials – An Interdisciplinary Review

    PubMed Central

    Sanchez, Vanesa C.; Jachak, Ashish; Hurt, Robert H.; Kane, Agnes B.

    2011-01-01

    Graphene is a single-atom thick, two-dimensional sheet of hexagonally arranged carbon atoms isolated from its three-dimensional parent material, graphite. Related materials include few-layer-graphene (FLG), ultrathin graphite, graphene oxide (GO), reduced graphene oxide (rGO), and graphene nanosheets (GNS). This review proposes a systematic nomenclature for this set of “Graphene-Family Nanomaterials” (GFNs) and discusses specific materials properties relevant for biomolecular and cellular interactions. The article discusses several unique modes of interaction between GFNs and nucleic acids, lipid bilayers, and conjugated small molecule drugs and dyes. Some GFNs are produced as dry powders using thermal exfoliation, and in these cases inhalation is a likely route of human exposure. Some GFNs have aerodynamic sizes that can lead to inhalation and substantial deposition in the human respiratory tract, which may impair lung defense and clearance leading to formation of granulomas and lung fibrosis. The limited literature on in vitro toxicity suggests that GFNs can be either benign or toxic to cells, and it is hypothesized that the biological response will vary across the material family depending on layer number, lateral size, stiffness, hydrophobicity, surface functionalization, and dose. Generation of reactive oxygen species (ROS) in target cells is a potential mechanism for toxicity, although the extremely high hydrophobic surface area of some GFNs may also lead to significant interactions with membrane lipids leading to direct physical toxicity or adsorption of biological molecules leading to indirect toxicity. Limited in vivo studies demonstrate systemic biodistribution and biopersistence of GFNs following intravenous delivery. Similar to other smooth, continuous, biopersistent implants or foreign bodies, GFNs have the potential to induce foreign body tumors. Long-term adverse health impacts must be considered in design of GFNs for drug delivery, tissue engineering, and fluorescence-based biomolecular sensing. Future research is needed to explore fundamental biological responses to GFNs including systematic assessment of the physical and chemical materials properties related to toxicity. Complete materials characterization and mechanistic toxicity studies are essential for safer design and manufacturing of GFNs in order to optimize biological applications with minimal risks for environmental health and safety. PMID:21954945

  18. OSI Passive Seismic Experiment at the Former Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sweeney, J J; Harben, P

    On-site inspection (OSI) is one of the four verification provisions of the Comprehensive Nuclear Test Ban Treaty (CTBT). Under the provisions of the CTBT, once the Treaty has entered into force, any signatory party can request an on-site inspection, which can then be carried out after approval (by majority voting) of the Executive Council. Once an OSI is approved, a team of 40 inspectors will be assembled to carry out an inspection to ''clarify whether a nuclear weapon test explosion or any other nuclear explosion has been carried out in violation of Article I''. One challenging aspect of carrying outmore » an on-site inspection (OSI) in the case of a purported underground nuclear explosion is to detect and locate the underground effects of an explosion, which may include an explosion cavity, a zone of damaged rock, and/or a rubble zone associated with an underground collapsed cavity. The CTBT (Protocol, Section II part D, paragraph 69) prescribes several types of geophysical investigations that can be carried out for this purpose. One of the methods allowed by the CTBT for geophysical investigation is referred to in the Treaty Protocol as ''resonance seismometry''. This method, which was proposed and strongly promoted by Russia during the Treaty negotiations, is not described in the Treaty. Some clarification about the nature of the resonance method can be gained from OSI workshop presentations by Russian experts in the late 1990s. Our understanding is that resonance seismometry is a passive method that relies on seismic reverberations set up in an underground cavity by the passage of waves from regional and teleseismic sources. Only a few examples of the use of this method for detection of underground cavities have been presented, and those were done in cases where the existence and precise location of an underground cavity was known. As is the case with many of the geophysical methods allowed during an OSI under the Treaty, how resonance seismology really works and its effectiveness for OSI purposes has yet to be determined. For this experiment, we took a broad approach to the definition of ''resonance seismometry''; stretching it to include any means that employs passive seismic methods to infer the character of underground materials. In recent years there have been a number of advances in the use of correlation and noise analysis methods in seismology to obtain information about the subsurface. Our objective in this experiment was to use noise analysis and correlation analysis to evaluate these techniques for detecting and characterizing the underground damage zone from a nuclear explosion. The site that was chosen for the experiment was the Mackerel test in Area 4 of the former Nevada Test Site (now named the Nevada National Security Site, or NNSS). Mackerel was an underground nuclear test of less than 20 kT conducted in February of 1964 (DOENV-209-REV 15). The reason we chose this site is because there was a known apical cavity occurring at about 50 m depth above a rubble zone, and that the site had been investigated by the US Geological Survey with active seismic methods in 1965 (Watkins et al., 1967). Note that the time delay between detonation of the explosion (1964) and the time of the present survey (2010) is nearly 46 years - this would not be typical of an expected OSI under the CTBT.« less

  19. AN OVERVIEW OF TOXICANT IDENTIFICATION IN SEDIMENTS AND DREDGED MATERIALS

    EPA Science Inventory

    The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation?s waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. K...

  20. 78 FR 58264 - Refuge Alternatives for Underground Coal Mines

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-23

    ... Refuge Alternatives for Underground Coal Mines AGENCY: Mine Safety and Health Administration, Labor... Agency's Request for Information (RFI) on Refuge Alternatives for Underground Coal Mines. This extension... Alternatives for Underground Coal Mines. The RFI comment period had been scheduled to close on October 7, 2013...

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