Aquifer wise seasonal variations and spatial distribution of major ions with focus on fluoride contamination-Pandharkawada block, Yavatmal district, Maharashtra, India.

PubMed

Pandith, Madhnure; Malpe, D B; Rao, A D; Rao, P N

2016-02-01

Seasonal variations in groundwater reveal lesser concentrations of major ions except NO3(-) during post-monsoon seasons in shallow aquifers as compared to deeper aquifers. The F(-) concentration from deeper aquifers is high in both seasons and shows a moderate positive relationship with weathering depth and is >5 mg/L in compound lava flow. Groundwater is mainly a Ca-HCO3 type in shallow aquifers and mixed type in deeper aquifers. Fluoride shows a positive correlation with pH, Na(+), HCO3(-) in shallow aquifers and an inverse correlation with Ca(2+) and HCO3(-) from deeper aquifers in both seasons. Approximately 45% of the samples are not suitable for drinking from both aquifers but suitable for irrigation purposes. Rock-water interaction, moderate alkalinity, sluggish movement, and higher residence time are the main causes for high F(-) in deeper aquifers as compared to shallow aquifers. As recommendations, drinking water requirement may be met from shallow aquifers/surface water and fluoride rich groundwater for other purposes. Most effective defluoridation techniques like ion exchange and reverse osmosis may be adopted along with integrated fluorosis mitigation measures and rooftop rainwater harvesting. Supplementary calcium and phosphorous rich food should be provided to children and creating awareness about safe drinking water habits, side effects of high F(-), and NO3(-) rich groundwater, improving oral hygiene conditions are other measures.

RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) biodegradation in aquifer sediments under manganese-reducing conditions

USGS Publications Warehouse

Bradley, Paul M.; Dinicola, Richard S.

2005-01-01

A shallow, RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine)–contaminated aquifer at Naval Submarine Base Bangor has been characterized as predominantly manganese-reducing, anoxic with local pockets of oxic conditions. The potential contribution of microbial RDX degradation to localized decreases observed in aquifer RDX concentrations was assessed in sediment microcosms amended with [U-14C] RDX. Greater than 85% mineralization of 14C-RDX to 14CO2 was observed in aquifer sediment microcosms under native, manganese-reducing, anoxic conditions. Significant increases in the mineralization of 14C-RDX to 14CO2 were observed in anoxic microcosms under NO3-amended or Mn(IV)-amended conditions. No evidence of 14C-RDX biodegradation was observed under oxic conditions. These results indicate that microbial degradation of RDX may contribute to natural attenuation of RDX in manganese-reducing aquifer systems.

RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) biodegradation in aquifer sediments under manganese-reducing conditions

USGS Publications Warehouse

Bradley, Paul M.; Dinicola, Richard S.

2005-01-01

A shallow, RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine)–contaminated aquifer at Naval Submarine Base Bangor has been characterized as predominantly manganese-reducing, anoxic with local pockets of oxic conditions. The potential contribution of microbial RDX degradation to localized decreases observed in aquifer RDX concentrations was assessed in sediment microcosms amended with [U-14C] RDX. Greater than 85% mineralization of14C-RDX to 14CO2 was observed in aquifer sediment microcosms under native, manganese-reducing, anoxic conditions. Significant increases in the mineralization of 14C-RDX to 14CO2 were observed in anoxic microcosms under NO3-amended or Mn(IV)-amended conditions. No evidence of 14C-RDX biodegradation was observed under oxic conditions. These results indicate that microbial degradation of RDX may contribute to natural attenuation of RDX in manganese-reducing aquifer systems.

Assessment of intrinsic bioremediation of jet fuel contamination in a shallow aquifer, Beaufort, South Carolina

USGS Publications Warehouse

Chapelle, Frank; Landmeyer, J.E.; Bradley, P.M.

1995-01-01

Field and laboratory studies show that microorganisms indigenous to the ground-water system underlying Tank Farm C, Marine Corps Air Station Beaufort, S.C., degrade petroleum hydrocarbons under aerobic and anaerobic conditions. Under aerobic conditions, sediments from the shallow aquifer underlying the site mineralized radiolabeled (14C) toluene to 14CO2 with first-order rate constants of about -0.29 per day. Sediments incubated under anaerobic conditions mineralized radiolabeled toluene more slowly, with first-order rate constants of -0.001 per day. Although anaerobic rates of biodegradation are low, they are significant in the hydrologic and geochemical context of the site. Because of low hydraulic conductivities (1.9-9.1 feet per day) and low hydraulic gradients (about 0.004 feet per feet), ground water flows slowly (approximately 20 feet per year) at this site. Furthermore, aquifer sediments contain organic-rich peat that has a high sorptive capacity. Under these conditions, hydrocarbon contaminants have moved no further than 10 feet downgradient of the jet fuel free product. Digital solute-transport simulations, using the range of model parameters measured at the site, show that dissolved contaminants will be completely degraded before they are discharged from the aquifer into adjacent surface-water bodies. These results show that natural attenuation processes are containing the migration of soluble hydrocarbons, and that intrinsic bioremediation is a potentially effective remedial strategy at this site.

The hydrogeochemical and isotopic investigations of the two-layered Shiraz aquifer in the northwest of Maharlou saline lake, south of Iran

NASA Astrophysics Data System (ADS)

Tajabadi, Mehdi; Zare, Mohammad; Chitsazan, Manouchehr

2018-03-01

Maharlou saline lake is the outlet of Shiraz closed basin in southern Iran, surrounded by several disconnected alluvial fresh water aquifers. These aquifers in the west and northwest of the lake are recharged by karstic anticlines such as Kaftarak in the north and Barmshour in the south. Here groundwater salinity varies along the depth so that better quality water is located below brackish or saline waters. The aim of this study is to investigate the reason for the salinity anomaly and the origin of the fresher groundwater in lower depth. Hence, the change in groundwater salinity along depth has been investigated by means of a set of geoelectrical, hydrogeological, hydrogeochemical, and environmental isotopes data. The interpretation of geoelectrical profiles and hydrogeological data indicates that the aquifer in the southeast of Shiraz plain is a two-layer aquifer separated by a fine-grained (silt and clay) layer with an approximate thickness of 40 m at the depth of about 100-120 m. Hydrgeochemistry showed that the shallow aquifer is recharged by Kaftarak karstic anticline and is affected by the saline lake water. The lake water fraction varies in different parts from zero for shallow aquifer close to the karstic anticlines to ∼70 percent in the margin of the lake. The deep aquifer is protected from the intrusion of saline lake water due to the presence of the above-mentioned confining layer with lake water fraction of zero. The stable isotopes signatures also indicate that the 'fresh' groundwater belonging to the deep aquifer is not subject to severe evaporation or mixing which is typical of the karstic water of the area. It is concluded that the characteristics of the deep aquifer are similar to those of the karstic carbonate aquifer. This karstic aquifer is most probably the Barmshour carbonated anticline buried under the shallow aquifer in the southern part. It may also be the extension of the Kaftarak anticline in the northern part.

Assessment of hydrochemical processes and groundwater hydrodynamics in a multilayer aquifer system under long-term irrigation condition: A case study of Nefzaoua basin, southern Tunisia.

PubMed

Tarki, M; Ben Hammadi, M; El Mejri, H; Dassi, L

2016-04-01

The hydrochemical and isotopic investigation of the Nefzaoua aquifer system demonstrates that groundwater mineralization in is controlled by natural and anthropogenic processes including water-rock interaction and irrigation return flow. It identifies all of the water bodies that flow within the aquifer system and their circulation patterns. The isotopically depleted paleowaters, identified within the deep and intermediate aquifers, undergo significant enrichment by evaporation during irrigation and recharged the shallow aquifer by return flow. Subsequently, they infiltrate to the intermediate aquifer which receives also rainfall modern recharge. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geology, hydrogeology, and potential of intrinsic bioremediation at the National Park Service Dockside II site and adjacent areas, Charleston, South Carolina, 1993-94

USGS Publications Warehouse

Campbell, B.G.; Petkewich, M.D.; Landmeyer, J.E.; Chapelle, F.H.

1996-01-01

A long history of industrial and commercial use of the National Park Service property and adjacent properties located in downtown Charleston, South Carolina, has caused extensive contamination of the shallow subsurface soils and water-table aquifer. The National Park Service property is located adjacent to a former manufactured-gas plant site, which is the major source of the contamination. Contamination of this shallow water-table aquifer is of concern because shallow ground water discharges to the Cooper River and contains contaminants, which may affect adjacent wildlife or human populations. The geology of the National Park Service property above the Ashley Formation of the Cooper Group consists of two Quaternary lithostratigraphic marine units, the Wando Formation and Holocene deposits, overlain by artificial fill. The Wando Formation overlies the Ashley Formation, a sandy calcareous clay, and consists of soft, organic clay overlain by gray sand. The Holocene deposits are composed of clayey to silty sand and soft organic-rich clay. The artificial fill, which was placed at the site to create dry land where salt marsh existed previously, is composed of sand, silt, and various scrap materials. The shallow hydrogeology of the National Park Service property overlying the Ashley Formation can be subdivided into two sandy aquifers separated by a leaky, black, organic-rich clay. The unconfined upper surficial aquifer is primarily artificial fill. The lower surficial aquifer consists of the Wando sand unit and is confined by the leaky organic-rich clay. Aquifer tests performed on the wells screened in these aquifers resulted in hydraulic conductivities from 0.1 to 10 feet per day for the upper surficial aquifer, and 16 feet per day for the lower surficial aquifer. Vertical hydraulic gradients at the site are typically low. A downward gradient from the upper surficial aquifer to the lower surficial aquifer occurs throughout most of the year. A brick-lined storm-water-drainage archway located in the study area is a conduit for the overflow of seawater into the surficial aquifer during exceptionally high tides. The efficiency of intrinsic bioremediation to reduce contaminant migration in the upper surficial aquifer at the National Park Service site was assessed to determine if, and at what concentrations, contaminants are being transported to the Cooper River. This assessment required incorporating hydrologic, geochemical, microbiologic, and demographic information into a predictive solute-transport model to determine rates of contaminant transport to the Cooper River. The transport of toluene and naphthalene was modeled as a surrogate for the transport of aromatic and other hydrocarbon compounds at the study area. Laboratory estimates of the adsorption coefficients for sediments of the upper surficial aquifer suggest preferential adsorption of naphthalene over toluene. The adsorption coefficient of naphthalene is at least two orders of magnitude greater than that determined for toluene. Laboratory microbial-biodegradation experiments indicate that microorganisms present in the shallow aquifer have the potential to degrade toluene under anaerobic and aerobic conditions, and naphthalene primarily under aerobic conditions. Rates of microbial biodegradation are similar for both compounds under aerobic conditions. Flow-model calibration to the January 1994 water-table surface of the upper surficial aquifer was achieved by specifying appropriate hydrogeologic boundary conditions and using hydraulic conductivity values determined in the field. The brick-lined storm-water drainage archway located in the study area was modeled to account for ground-water discharge through this drain. An exploratory modeling approach was used to evaluate the range of possible solutions that approximate the transport of contaminants to the observed distributions. Approximate toluene solute-transport conditions for January 1994 were estimated using velocity dist

Pollutant sources in an arsenic-affected multilayer aquifer in the Po Plain of Italy: Implications for drinking-water supply.

PubMed

Rotiroti, Marco; McArthur, John; Fumagalli, Letizia; Stefania, Gennaro A; Sacchi, Elisa; Bonomi, Tullia

2017-02-01

In aquifers 160 to 260m deep that used for public water-supply in an area ~150km 2 around the town of Cremona, in the Po Plain of Northern Italy, concentrations of arsenic (As) are increasing with time in some wells. The increase is due to drawdown of As-polluted groundwater (As ≤144μg/L) from overlying aquifers at depths 65 to 150m deep in response to large-scale abstraction for public supply. The increase in As threatens drinking-water quality locally, and by inference does so across the entire Po Plain, where natural As-pollution of groundwater (As >10μg/L) is a basin-wide problem. Using new and legacy data for Cl/Br, δ 18 O/δ 2 H and other hydrochemical parameters with groundwater from 32 wells, 9 surface waters, a sewage outfall and rainwater, we show that the deep aquifer (160-260m below ground level), which is tapped widely for public water-supply, is partly recharged by seepage from overlying aquifers (65-150m below ground level). Groundwater quality in deep aquifers appears free of anthropogenic influences and typically <10μg/L of As. In contrast, shallow groundwater and surface water in some, not all, areas are affected by anthropogenic contamination and natural As-pollution (As >10μg/L). Outfalls from sewage-treatment plants and black water from septic tanks firstly affect surface waters, which then locally infiltrate shallow aquifers under high channel-stages. Wastewater permeating shallow aquifers carries with it NO 3 and SO 4 which suppress reduction of iron oxyhydroxides in the aquifer sediments and so suppress the natural release of As to groundwater. Copyright © 2016 Elsevier B.V. All rights reserved.

Continuous seismic-reflection survey defining shallow sedimentary layers in the Charlotte Harbor and Venice areas, southwest Florida

USGS Publications Warehouse

Wolansky, R.M.; Haeni, F.P.; Sylvester, R.E.

1983-01-01

A continuous marine seismic-reflection survey system was used to define the configuration of shallow sedimentary layers underlying the Charlotte Harbor and Venice areas, southwest Florida. Seismic profiling was conducted over a distance of about 57 miles of Charlotte Harbor, the Peace and Myakka Rivers, and the Intracoastal Waterway near Venice using a high resolution energy source capable of penetrating 200 feet of sediments with a resolution of 1 to 3 feet. Five stratigraphic units defined from the seismic records includes sediments to Holocene to early Miocene age. All seismic-profile records are presented, along with geologic sections constructed from the records. Seismic reflection amplitude, frequency, continuity, configuration, external form, and areal association were utilized to interpret facies and depositional environments of the stratigraphic units. The despositional framework of the units ranges from shallow shelf to prograded slope. The stratigraphic units are correlated with the surficial aquifer and intermediate artesian aquifers, and permeable zones of the aquifers are related to the seismic records. (USGS)

Hydrogeology and potential effects of changes in water use, Carson Desert agricultural area, Churchill County, Nevada

USGS Publications Warehouse

Maurer, Douglas K.; Johnson, Ann K.; Welch, Alan H.

1994-01-01

Operating Criteria and Procedures established in 1988 for delivery of water for irrigation in the Newlands Project area include regulations and methods to increase Project efficiency. Public Law 101-618 of 1990 includes a target of 75-percent Project efficiency and a program of water-rights acquisition for wetlands maintenance. The directives could result in large reductions in water used for irrigation in the Carson Desert, potentially affecting ground-water supplies. Previous studies of the area have been evaluated to determine the current understanding of how aquifers are recharged, what controls the flow and quality of ground water, potential effects of changes in water use, and what additional information would be needed to quantify further changes in water use.Inflow of surface water to the basin from Lahontan Reservoir averaged about 370,000 acre-ft/yr (acre-feet per year) from 1975 to 1992, supplying water for irrigation of more than 50,000 acres. More than half of the water released from the reservoir is lost to seepage, operational spills, and evaporation before delivery of about 170,000 acre-ft/yr to farm headgates. The volume of water delivered to farms that does not contribute to crop consumptive use (on-farm loss) is poorly known but could be as much as 60,000 acre-ft/yr. Consumptive use on irrigated land may be about 180,000 acre-ft/yr, of which 50,000 acre-ft/yr may be derived from the shallow aquifer. Outflow from irrigated land is a mixture of operational spill, runoff from irrigated fields, and ground-water seepage to drains. Total outflow averages about 170,000 to 190,000 acre-ft/yr. This water flows to wetlands at Carson Lake, Stillwater Wildlife Management Area, and Carson Sink. Three sedimentary aquifers were previously defined in the basin: a shallow aquifer having highly variable lithology and water quality, an intermediate aquifer containing principally fresh water, and a deep aquifer having water of poor quality. The deep aquifer could possibly be divided into sedimentary and volcanic zones. In addition, a near-surface zone may exist near the top of the shallow aquifer where vertical flow is inhibited by underlying clay beds. A basalt aquifer near the center of the basin is the source of public supply and is recharged by the shallow, intermediate, and deep aquifers. Water levels in the basalt aquifer have declined about 10 feet from pre-pumping levels, and chloride and arsenic concentrations in the water have increased. The average depth to ground water has decreased beneath large areas of the Carson Desert since 1904 as a result of recharge of surface water used for irrigation. Ground water generally flows from west to east, and dissolvedsolids concentrations increase greatly near areas of ground-water discharge, where State of Nevada drinking-water standards commonly are exceeded. Uncertainties in the rates of recharge to and discharge from the basin cause an imbalance in the calculated water budget. Estimates for total recharge range from 400,000 to 420,000 acreft/yr, whereas estimates for discharge range from 630,000 to 680,000 acre-ft/yr. Estimates of inflow to and outflow from aquifers of the study area are as follows: shallow aquifer, more than 120,000 acre-ft/yr; intermediate aquifer, possibly more than 25,000 acre-ft/yr; deep aquifer, unknown; and basalt aquifer, about 4,000 acre-ft/yr. Estimates for flow volumes to and from the shallow and intermediate aquifers are based on assumed aquifer properties and could be in error by an order of magnitude or more. Conceptual models of the basin show that ground-water flow is downward from the shallow aquifer to the intermediate aquifer in the western part and near the center of the basin, and is upward in the eastern part of the basin. Little is known about flow in the deep aquifer. Nearsurface clay beds inhibit vertical flow near the center and eastern part of the basin except where breached by relict sand-filled channels of the Carson River. Conceptual models of the basin show that changes in water use in the western part of the basin probably would affect recharge to the sedimentary and basalt aquifers. Near the center of the basin, water-use changes could affect the shallow and basalt aquifers but might have less effect on the intermediate aquifer. In the eastern part of the basin, changes could affect the shallow aquifer, but would probably not affect the intermediate or basalt aquifers. If seepage is decreased by lining canals, and land is removed from production, water-level declines in the shallow aquifer could be greater than 10 feet as far as 2 miles from the lined canals. Depending upon the distribution of specific yield, decreasing recharge by 25,000 to 50,000 acre-ft/yr beneath 30,000 acres could cause water levels to decline from 4 to 17 feet. Where ground water supplements crop consumptive use, water levels could temporarily rise when land is removed from production. Where water is pumped from a near-surface zone of the shallow aquifer, water-level declines might not greatly affect pumped wells where the nearsurface zone is thickest, but could cause wells to go dry where the zone is thin. The understanding of surface-water and ground-water relations, recharge and discharge of ground water, ground-water movement, and the potential effects of changes in water use in the Carson Desert can be refined by studying (1) the extent of potable water in the intermediate and basalt aquifers, (2) lithology and specific yield of aquifer materials, (3) data on ground-water levels and quality, and (4) data on surface-water flow and quality, as well as monitoring the effects of changes in water use as they take place.

Delineating depth to bedrock beneath shallow unconfined aquifers: a gravity transect across the Palmer River Basin.

PubMed

Bohidar, R N; Sullivan, J P; Hermance, J F

2001-01-01

In view of the increasing demand on ground water supplies in the northeastern United States, it is imperative to develop appropriate methods to geophysically characterize the most widely used sources of ground water in the region: shallow unconfined aquifers consisting of well-sorted, stratified glacial deposits laid down in bedrock valleys and channels. The gravity method, despite its proven value in delineating buried bedrock valleys elsewhere, is seldom used by geophysical contractors in this region. To demonstrate the method's effectiveness for evaluating such aquifers, a pilot study was undertaken in the Palmer River Basin in southeastern Massachusetts. Because bedrock is so shallow beneath this aquifer (maximum depth is 30 m), the depth-integrated mass deficiency of the overlying unconsolidated material was small, so that the observed gravity anomaly was on the order of 1 milligal (mGal) or less. Thus data uncertainties were significant. Moreover, unlike previous gravity studies elsewhere, we had no a priori information on the density of the sediment. Under such circumstances, it is essential to include model constraints and weighted least-squares in the inversion procedure. Among the model constraints were water table configuration, bedrock outcrops, and depth to bedrock from five water wells. Our procedure allowed us to delineate depth to bedrock along a 3.5 km profile with a confidence interval of 1.8 m at a nominal depth of 17 m. Moreover, we obtained a porosity estimate in the range of 39% to 44%. Thus the gravity method, with appropriate refinements, is an effective tool for the reconnaissance of shallow unconfined aquifers.

Characterization of shallow unconsolidated aquifers in West Africa using different hydrogeological data sources as a contribution to the promotion of manual drilling and low cost techniques for groundwater exploration

NASA Astrophysics Data System (ADS)

Fussi, Fabio; Fumagalli, Letizia; Bonomi, Tullia; Kane, Cheikh H.; Fava, Francesco; Di Mauro, Biagio; Hamidou, Barry; Niang, Magatte; Wade, Souleye; Colombo, Roberto

2016-04-01

Manual drilling refers to several drilling methods that rely on human energy to construct a borehole and complete a water supply (Danert, 2015). It can be an effective strategy to increase access to groundwater in low income countries , but manual drilling can be applied only where shallow geological layers are relatively soft and water table is not too deep. It is important therefore to identify those zones where shallow hydrogeological conditions are suitable, investigating the characteristics of shallow porous aquifers. Existing hydrogeological studies are generally focused in the characterization of deep fractures aquifers, more productive and able to ensure water supply for large settlements. Information concerning shallow porous aquifers are limited. This research has been carried out in two different study areas in West Africa (North-Western Senegal and Eastern Guinea). Aim of the research is the characterization of shallow aquifer using different methods and the identification of hydrogeological condition suitable for manual drilling implementation. Three different methods to estimate geometry and hydraulic properties of shallow unconsolidated aquifers have been used: The first method is based on the analysis of stratigraphic data obtained from borehole logs of the national water point database in both countries. The following steps have been implemented on the original information using the software TANGAFRIC, specifically designed for this study: a) identification of most frequent terms used for hydrogeological description in Senegal and Guinea database; b) definition of standard categories and manual codification of data; c) automatic extraction of average distribution of textural classes at different depth intervals in the unconsolidated aquifer; d) estimation of hydraulic parameters using conversion tables between texture and hydraulic conductivity available in the literature. . The second method is based on the interpretation of pump and recovery test in large diameter wells. K values obtained from these tests provide direct information on hydraulic parameters of shallow porous aquifers (while pump tests data obtained from deep mechanized boreholes, exploiting fractured aquifers, cannot be considered representative for the target shallow aquifer of manual drilling). The third method is based on the interpretation of stratigraphic logs and simplified pump test from manual drilled wells carried out since 2012 in Guinea. In this country a standard and systematic procedure to collect hydrogeological data from these wells (therefore indicating properties of shallow aquifer) has been put in place in 2011; it is considered one of the best example worldwide about technical data collection and systematization from manual drilling activities, but its development has been stopped because of the outbreak of Ebola in this country. The integration of these 3 methods allow to estimate geometry and hydraulic behavior of shallow unconsolidated aquifer, identifying those areas where manual drilling is feasible and estimating potential yield that can be extracted. In the mean time this research provides relevant indications concerning the use of data obtained from low cost open hand dug or manually drilled wells (rarely used in hydrogeological research) for groundwater exploration of shallow aquifers.

Surface-Water and Groundwater Interactions along the Withlacoochee River, West-Central Florida

USGS Publications Warehouse

Trommer, J.T.; Yobbi, D.K.; McBride, W.S.

2009-01-01

A study of the Withlacoochee River watershed in west-central Florida was conducted from October 2003 to March 2007 to gain a better understanding of the hydrology and surface-water and groundwater interactions along the river. The Withlacoochee River originates in the Green Swamp area in north-central Polk County and flows northerly through seven counties, emptying into the Gulf of Mexico. This study includes only the part of the watershed located between the headwaters in the Green Swamp and the U.S. Geological Survey gaging station near Holder, Florida. The Withlacoochee River within the study area is about 108 miles long and drains about 1,820 square miles. The Withlacoochee River watershed is underlain by thick sequences of carbonate rock that are covered by thin surficial deposits of unconsolidated sand and sandy clay. The clay layer is breached in many places because of the karst nature of the underlying limestone, and the degree of confinement between the Upper Florida aquifer and the surficial aquifer is highly variable throughout the watershed. The potential for movement of water from the surface or shallow deposits to deeper deposits, or from deeper deposits to the shallow deposits, exists throughout the Withlacoochee River watershed. Water levels were higher in deeper Upper Floridan aquifer wells than in shallow Upper Floridan aquifer wells or surficial aquifer wells at 11 of 19 paired or nested well sites, indicating potential for discharge to the surface-water system. Water levels were higher in shallow Upper Floridan aquifer or surficial aquifer wells than in deeper Upper Floridan aquifer wells at five other sites, indicating potential for recharge to the deeper Upper Floridan aquifer. Water levels in the surficial aquifer and Upper Floridan aquifer wells at the remaining three sites were virtually the same, indicating little or no confinement at the sites. Potentiometric-surface maps of the Upper Floridan aquifer indicate the pattern of groundwater flow in the aquifer did not vary greatly from season to season during the study. Potentiometric contours indicate groundwater discharge to the river in the vicinity of Dade City and Lake Panasoffkee. During dry periods, groundwater from the underlying Upper Floridan aquifer contributed to the flow in the river. During wet periods, streamflow had additional contributions from runoff and input from tributaries. Groundwater has a greater effect on streamflow downstream from the Dade City station than upstream from the Dade City station because confinement between surficial deposits and the Upper Floridan aquifer is greater in the Green Swamp area than in downstream areas. Estimates of streamflow gains and losses were made along the Withlacoochee River during base-flow conditions in May 2004, April 2005, and April 2006. Base flow was higher in April 2005 than in May 2004 and April 2006. Consistent net seepage gains were identified in 16 of 20 subreaches analyzed during all seepage runs. The direction of exchange was variable in the remaining four subreaches. Low specific conductance, pH, and calcium concentrations in water from the Withlacoochee River near the headwater area indicated a surface-water system not directly connected to the Upper Floridan aquifer. Downstream from the Dade City station, higher specific conductance, pH, and calcium concentrations in the river water indicated an increasing influence of groundwater, and were similar to groundwater during low-flow conditions. Strontium isotope ratios indicate groundwater originates from shallow parts of the Upper Floridan aquifer in the upper reaches of the river, and from increasingly deeper parts of the aquifer in the downstream direction. Mean annual base-flow estimates also indicate increasing groundwater discharge to the river in the downstream direction. Mean annual base flow estimated using standard hydrograph separation method assumptions ranged from about 4.7 to 5.1 inches per year

Comparison of ground-water quality in samples from selected shallow and deep wells in the central Oklahoma aquifer, 2003-2005

USGS Publications Warehouse

Becker, Carol J.

2006-01-01

The aquifer units of the Central Oklahoma aquifer underlie about 2,890 square miles of central Oklahoma and are used extensively to supply water for municipal, domestic, industrial, and agricultural needs. The Central Oklahoma aquifer also is commonly referred to as the Garber-Wellington aquifer because the Garber Sandstone and Wellington Formation yield the greatest quantities of usable water for domestic and high-capacity wells. The major water-quality concerns for the Central Oklahoma aquifer described by the U.S. Geological Survey National Water Quality Assessment Program (1987 to 1992) were elevated concentrations of nitrate nitrogen in shallow water and the occurrence of arsenic, chromium, and selenium in parts of the aquifer. The quality of water from deep public-water supply wells in the Central Oklahoma aquifer is monitored by the State of Oklahoma. The chemical quality of water from shallow domestic wells is not monitored, and, therefore, there is a concern that well owners may be unknowingly ingesting water with nitrate nitrogen, arsenic, chromium, selenium, and other chemical constituents at concentrations that are considered harmful. As a result of this concern, the Oklahoma Department of Environmental Quality and the U.S. Geological Survey collaborated on a study to sample water during June 2003 through August 2005 from 23 shallow wells (less than 200 feet in depth) and 28 deep wells (200 feet or greater in depth) completed in the bedrock aquifer units of the Central Oklahoma aquifer. The objectives of the study were to describe the chemical quality of water from shallow and deep wells and to determine if the differences in constituent concentrations are statistically significant. Water from shallow wells had significantly higher concentrations of calcium, magnesium, bicarbonate, sulfate, chloride, and nitrate nitrogen than water from deep wells. There were no significant differences between concentrations of dissolved solids, sodium, and fluoride in water from shallow and deep wells. Water from 9 shallow wells had nitrate nitrogen concentrations greater than 2 milligrams per liter, suggesting nitrogen sources at land surface have had an effect on water from these wells. Water from three shallow wells (13 percent) exceeded the nitrate nitrogen maximum contaminant level of 10 milligrams per liter in drinking water. Water from shallow wells had significantly lower concentrations of arsenic, chromium, iron, and selenium than water from deep wells, whereas, concentrations of barium, copper, manganese, and zinc were similar. Water-quality data indicate that arsenic frequently occurs in shallow ground water from the Central Oklahoma aquifer, but at low concentrations (<10 micrograms per liter). The occurrence of chromium and selenium in water from shallow wells was infrequent and at low concentrations in this study. It does not appear that the quality of water from a shallow well can be predicted based on the quality of water from a nearby deep well. The results show that in general terms, shallow ground water has significantly higher concentrations of most major ions and significantly lower concentrations of arsenic, chromium, and selenium than water from deep wells.

Status of shallow-aquifer mapping in the Northern Front Range Area, Colorado

USGS Publications Warehouse

Robson, Stanley G.

2001-01-01

Mapping of shallow aquifers in the northern Front Range area of Colorado has been completed as part of the U.S. Geological Survey Front Range Infrastructure Resources Project. The aquifer mapping was undertaken as part of a comprehensive effort to better define the mineral, energy, cartographic, biological, and water resources that are critical to the support and development of the area's infrastructure, such as streets. highways, airports, and buildings. The aquifer mapping was undertaken in cooperation with the Colorado Division of Water Resources and the Colorado Water Conservation Board. The shallow aquifers have been mapped in a 2,450-square-mile area extending as an approximately 30-mile-wide band from north of Fort Collins to the Arapahoe-Douglas County line south of Denver (fig. I). The shallow aquifer mapping in the Denver metropolitan area was published in 1996 as Hydrologic Investigations Atlas HA-736 (Robson. 1996). Shallow aquifer mapping in the Greeley-Nunn area was published as HA-746A (Robson, Arnold, and Heiny, 2000a); mapping in the Fort Collins-Loveland area was published as HA-746B (Robson, Arnold, and Heiny, 2000b); mapping in the Fort Lupton-Gilcrest area was published as HA-746C (Robson, Heiny, and Arnold, 2000c); and mapping in the Boulder-Longmont area was published as HA-746D (Robson, Heiny, and Arnold, 2000d). Each of the five atlases contains five map sheets at 1:50,000 scale showing: 1. The thickness and extent of the unconsolidated sediments (loose gravel. sand. silt, and clay) that overlie the bedrock formations in the area (fig. 2). 2. The altitude and configuration of the bedrock surface. 3. The altitude of the water table and direction of ground-water movement. 4. The saturated thickness of the shallow aquifers. 5. The depth to the water table in the shallow aquifers.

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

USGS Publications Warehouse

Musgrove, MaryLynn; Beck, Jennifer A.; Paschke, Suzanne; Bauch, Nancy J.; Mashburn, Shana L.

2014-01-01

Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Hydrogeology and water quality of the shallow aquifer system at the Explosive Experimental Area, Naval Surface Warfare Center, Dahlgren Site, Dahlgren, Virginia

USGS Publications Warehouse

Bell, C.F.

1996-01-01

In October 1993, the U.S. Geological Survey began a study to characterize the hydrogeology of the shallow aquifer system at the Explosive Experimental Area, Naval Surface Warfare Center, Dahlgren Site, Dahlgren, Virginia, which is located on the Potomac River in the Coastal Plain Physiographic Province. The study provides a description of the hydrogeologic units, directions of ground-water flow, and back-ground water quality in the study area to a depth of about 100 feet. Lithologic, geophysical, and hydrologic data were collected from 28 wells drilled for this study, from 3 existing wells, and from outcrops. The shallow aquifer system at the Explosive Experimental Area consists of two fining-upward sequences of Pleistocene fluvial-estuarine deposits that overlie Paleocene-Eocene marine deposits of the Nanjemoy-Marlboro confining unit. The surficial hydrogeologic unit is the Columbia aquifer. Horizontal linear flow of water in this aquifer generally responds to the surface topography, discharging to tidal creeks, marshes, and the Potomac River, and rates of flow in this aquifer range from 0.003 to 0.70 foot per day. The Columbia aquifer unconformably overlies the upper confining unit 12-an organic-rich clay that is 0 to 55 feet thick. The upper confining unit conformably overlies the upper confined aquifer, a 0- to 35-feet thick unit that consists of interbedded fine-grained to medium-grained sands and clay. The upper confined aquifer probably receives most of its recharge from the adjacent and underlying Nanjemoy-Marlboro confining unit. Water in the upper confined aquifer generally flows eastward, northward, and northeastward at about 0.03 foot per day toward the Potomac River and Machodoc Creek. The Nanjemoy-Marlboro confining unit consists of glauconitic, fossiliferous silty fine-grained sands of the Nanjemoy Formation. Where the upper confined system is absent, the Nanjemoy-Marlboro confining unit is directly overlain by the Columbia aquifer. In some parts of the Explosive Experimental Area, horizontal hydraulic conductivities of the Nanjemoy-Marlboro confining unit and the Columbia aquifer are similar (from 10-4 to 10-2 foot per day), and these units effectively combine to form a thick (greater than 50 feet) aquifer. The background water quality of the shallow aquifer system is characteristic of ground waters in the Virginia Coastal Plain Physiographic Province. Water in the Columbia aquifer is a mixed ionic type, has a median pH of 5.9, and a median total dissolved solids of 106 milligrams per liter. Water in the upper confined aquifer and Nanjemoy-Marlboro confining unit is a sodium- calcium-bicarbonate type, and generally has higher pH, dissolved solids, and alkalinity than water in the Columbia aquifer. Water in the upper confined aquifer and some parts of the Columbia aquifer is anoxic, and it has high concentrations of dissolved iron, manganese, and sulfide.

Three-dimensional numerical simulations of methane gas migration from decommissioned hydrocarbon production wells into shallow aquifers

NASA Astrophysics Data System (ADS)

Roy, N.; Molson, J.; Lemieux, J.-M.; Van Stempvoort, D.; Nowamooz, A.

2016-07-01

Three-dimensional numerical simulations are used to provide insight into the behavior of methane as it migrates from a leaky decommissioned hydrocarbon well into a shallow aquifer. The conceptual model includes gas-phase migration from a leaky well, dissolution into groundwater, advective-dispersive transport and biodegradation of the dissolved methane plume. Gas-phase migration is simulated using the DuMux multiphase simulator, while transport and fate of the dissolved phase is simulated using the BIONAPL/3D reactive transport model. Methane behavior is simulated for two conceptual models: first in a shallow confined aquifer containing a decommissioned leaky well based on a monitored field site near Lindbergh, Alberta, Canada, and secondly on a representative unconfined aquifer based loosely on the Borden, Ontario, field site. The simulations show that the Lindbergh site confined aquifer data are generally consistent with a 2 year methane leak of 2-20 m3/d, assuming anaerobic (sulfate-reducing) methane oxidation and with maximum oxidation rates of 1 × 10-5 to 1 × 10-3 kg/m3/d. Under the highest oxidation rate, dissolved methane decreased from solubility (110 mg/L) to the threshold concentration of 10 mg/L within 5 years. In the unconfined case with the same leakage rate, including both aerobic and anaerobic methane oxidation, the methane plume was less extensive compared to the confined aquifer scenarios. Unconfined aquifers may therefore be less vulnerable to impacts from methane leaks along decommissioned wells. At other potential leakage sites, site-specific data on the natural background geochemistry would be necessary to make reliable predictions on the fate of methane in groundwater.

Field Verification of Stable Perched Groundwater in Layered Bedrock Uplands

USGS Publications Warehouse

Carter, J.T.; Gotkowitz, M.B.; Anderson, M.P.

2011-01-01

Data substantiating perched conditions in layered bedrock uplands are rare and have not been widely reported. Field observations in layered sedimentary bedrock in southwestern Wisconsin, USA, provide evidence of a stable, laterally extensive perched aquifer. Data from a densely instrumented field site show a perched aquifer in shallow dolomite, underlain by a shale-and-dolomite aquitard approximately 25 m thick, which is in turn underlain by sandstone containing a 30-m-thick unsaturated zone above a regional aquifer. Heads in water supply wells indicate that perched conditions extend at least several kilometers into hillsides, which is consistent with published modeling studies. Observations of unsaturated conditions in the sandstone over a 4-year period, historical development of the perched aquifer, and perennial flow from upland springs emanating from the shallow dolomite suggest that perched groundwater is a stable hydrogeologic feature under current climate conditions. Water-table hydrographs exhibit apparent differences in the amount and timing of recharge to the perched and regional flow systems; steep hydraulic gradients and tritium and chloride concentrations suggest there is limited hydraulic connection between the two. Recognition and characterization of perched flow systems have practical importance because their groundwater flow and transport pathways may differ significantly from those in underlying flow systems. Construction of multi-aquifer wells and groundwater withdrawal in perched systems can further alter such pathways. ?? 2010 The Author(s). Journal compilation ?? 2010 National Ground Water Association.

Sulphur and oxygen isotopic characters of dissolved sulphate in groundwater from the Pleistocene aquifer in the southern Jordan Valley (Jericho area, Palestine).

PubMed

Khayat, Saed; Hötzl, Heinz; Geyer, Stefan; Ali, Wasim; Knöller, Kay; Strauch, Gerhard

2006-09-01

Sulphate and chloride concentrations in the shallow Pleistocene aquifer systems in the lower Jordan valley area indicate a general trend of increasing salinity eastward and southward. This study was conducted in one of the important sub-basins feeding the Pleo-Pleistocene aquifer in the Jericho area in the southern part of the valley using S and O isotopes of dissolved sulphate. The results show that sulphate has mainly two contributions to the groundwater. One is the surface seepage, which is present as a salty leachate form with the positive delta34Ssulphate values of primary gypsum in Lisan and Samara formations, and the second is the upwelling saline water which was in contact with a deep secondary gypsum, aragonites and salty rocks and rose up under heavy abstraction with depleted 34S in sulphate and relatively high sulphate and chloride content. The latest was clearly shown in the Arab Project wells to the east that is undergoing a continuous heavy abstraction. The isotopic signatures of S and O in these wells to the east show that this depleted 34S and highly concentrated sulphate might also indicate a dissolved sulphate originating from pyrite oxidation that results from the interaction with a pyrite-rich aquifer, which can well up with salty water under heavy abstraction and is oxidised in the upper aerobic shallow aquifer.

Shallow ground-water quality beneath cropland in the Red River of the North Basin, Minnesota and North Dakota, 1993-95

USGS Publications Warehouse

Cowdery, Timothy K.

1997-01-01

Land-use factors that increased nitrate and herbicide concentrations were greater tilled area, chemical application, irrigation, and cropland contiguity. Hydrogeological factors that increased these concentrations were a deeper watertable (higher oxygen concentration and less organic carbon), larger grain-size and degree of sorting of aquifer material (shorter time in the soil zone and aquifer), and fewer sulfur-containing minerals (lignite and pyrite) composing the aquifer. High rainfall, just before sampling of the Sheyenne Delta aquifer, contributed to the relatively low nitrate and pesticide concentrations in the shallow ground water of this aquifer by raising the water table higher into the soil zone, increasing ponded water (increasing biodegradation), preventing some chemical application (flooded fields), and leaching and then displacing nitrate-rich water downward, beneath new recharge. The shallow ground-water quality measured beneath cropland in these land-use study areas covers a large range. The land-use, hydrogeological, and rainfall factors controlling this quality also control shallow ground-water quality in other surficial aquifers in the Red River of the North Basin. Although not used for drinking water, 43% of the shallow ground water from the Otter Tail outwash aquifer was above the U.S. Environmental Protection Agency's nitrate maximum contaminant level of 10 mg/L-N, reducing its potential uses. These high nitrate concentrations do not threaten the Otter Tail outwash aquifer's surface-water bodies with eutrophication however, because significant denitrification occurs beneath riparian wetlands before ground water discharges to surface waters.

Conceptual hydrogeologic framework of the shallow aquifer system at Virginia Beach, Virginia

USGS Publications Warehouse

Smith, Barry S.; Harlow, George E.

2002-01-01

The hydrogeologic framework of the shallow aquifer system at Virginia Beach was revised to provide a better understanding of the distribution of fresh ground water, its potential use, and its susceptibility to contamination. The revised conceptual framework is based primarily on analyses of continuous cores and downhole geophysical logs collected at 7 sites to depths of approximately 200 ft.The shallow aquifer system at Virginia Beach is composed of the Columbia aquifer, the Yorktown confining unit, and the Yorktown-East-over aquifer. The shallow aquifer system is separated from deeper units by the continuous St. Marys confining unit.The Columbia aquifer is defined as the predominantly sandy surficial deposits above the Yorktown confining unit. The Yorktown confining unit is composed of a series of very fine sandy to silty clay units of various colors at or near the top of the Yorktown Formation. The Yorktown confining unit varies in thickness and in composition, but on a regional scale is a leaky confining unit. The Yorktown-Eastover aquifer is defined as the predominantly sandy deposits of the Yorktown Formation and the upper part of the Eastover Formation above the confining clays of the St. Marys Formation. The limited areal extent of highly permeable deposits containing freshwater in the Yorktown-Eastover aquifer precludes the installation of highly productive freshwater wells over most of the city. Some deposits of biofragmental sand or shell hashes in the Yorktown-Eastover aquifer can support high-capacity wells.A water sample was collected from each of 10 wells installed at 5 of the 7 core sites to determine the basic chemistry of the aquifer system. One shallow well and one deep well was installed at each site. Concentrations of chloride were higher in the water from the deeper well at each site. Concentrations of dissolved iron in all of the water samples were higher than the U.S. Environmental Protection Agency Secondary Drinking Water Regulations. Concentrations of manganese and chloride were higher than the Secondary Drinking Water Regulations in samples from some wells.In the humid climate of Virginia Beach, the periodic recharge of freshwater through the sand units of the shallow aquifer system occurs often enough to create a dynamic equilibrium whereby freshwater flows continually down and away from the center of the ridges to mix with and sweep brackish water and saltwater back toward the tidal rivers, bays, salt marshes, and the Atlantic Ocean.The aquifers and confining units of the shallow aquifer system at Virginia Beach are heterogeneous, discontinuous, and without exact marker beds, which makes correlations in the study area difficult. Investigations using well cuttings, spot cores, or split-spoon samples with geophysical logs are not as definitive as continuous cores for determining or correlating hydrogeologic units. Future investigations of the shallow aquifer system would benefit by collecting continuous cores.

Vertical movement of ground water under the Merrill Field landfill, Anchorage, Alaska

USGS Publications Warehouse

Nelson, Gordon L.; Dearborn, L.L.

1982-01-01

Shallow groundwater under the Merrill Field sanitary landfill at Anchorage is polluted by leachate. Wells, including three Municipal-supply wells, obtain water from two confined aquifers 100-300 feet beneath the landfill area. Aquifer-test data and information on subsurface geology, ground-water levels, and properties of materials were used to estimate vertical gradients and vertical permeabilities under the landfill. The authors ' best estimates ' of vertical permeabilities of two confining units are 1 x 10 super -2 foot per day and 2 x 10 super -4 foot per day. Theoretical travel-time calculations indicate that minor amounts of pollutants may reach the upper confined aquifer after many tens of years, but that water of the composition of the leachate probably would not reach the aquifer for more than three centuries. The range of error in the theoretical travel-time calculations is likely to be plus or minus a factor of two or three. (USGS)

Shallow bedrock limits groundwater seepage-based headwater climate refugia

USGS Publications Warehouse

Briggs, Martin A.; Lane, John W.; Snyder, Craig D.; White, Eric A.; Johnson, Zachary; Nelms, David L.; Hitt, Nathaniel P.

2018-01-01

Groundwater/surface-water exchanges in streams are inexorably linked to adjacent aquifer dynamics. As surface-water temperatures continue to increase with climate warming, refugia created by groundwater connectivity is expected to enable cold water fish species to survive. The shallow alluvial aquifers that source groundwater seepage to headwater streams, however, may also be sensitive to seasonal and long-term air temperature dynamics. Depth to bedrock can directly influence shallow aquifer flow and thermal sensitivity, but is typically ill-defined along the stream corridor in steep mountain catchments. We employ rapid, cost-effective passive seismic measurements to evaluate the variable thickness of the shallow colluvial and alluvial aquifer sediments along a headwater stream supporting cold water-dependent brook trout (Salvelinus fontinalis) in Shenandoah National Park, VA, USA. Using a mean depth to bedrock of 2.6 m, numerical models predicted strong sensitivity of shallow aquifer temperature to the downward propagation of surface heat. The annual temperature dynamics (annual signal amplitude attenuation and phase shift) of potential seepage sourced from the shallow modeled aquifer were compared to several years of paired observed stream and air temperature records. Annual stream water temperature patterns were found to lag local air temperature by ∼8–19 d along the stream corridor, indicating that thermal exchange between the stream and shallow groundwater is spatially variable. Locations with greater annual signal phase lag were also associated with locally increased amplitude attenuation, further suggestion of year-round buffering of channel water temperature by groundwater seepage. Numerical models of shallow groundwater temperature that incorporate regional expected climate warming trends indicate that the summer cooling capacity of this groundwater seepage will be reduced over time, and lower-elevation stream sections may no longer serve as larger-scale climate refugia for cold water fish species, even with strong groundwater discharge.

Radon in the fluvial aquifers of the White River Basin, Indiana, 1995

USGS Publications Warehouse

Fenelon, Joseph M.; Moore, Rhett C.

1996-01-01

Water samples collected in 1995 from 57 monitoring wells (48 shallow and 9 deep) in the fluvial aquifers of the White River Basin were analyzed for radon. Radon concentrations in the shallow wells ranged from 140 to 1,600 pCi/L (picocuries per liter); the median concentration was 420 pCi/L. In comparison, analyses of the samples from the nine deep wells indicate that radon concentrations decrease with depth within the fluvial aquifers; the median concentration was 210 pCi/L. No areal trends in radon concentrations are evident in the water of the shallow fluvial aquifers of the basin

Potential impacts of leakage from deep CO2 geosequestration on overlying freshwater aquifers.

PubMed

Little, Mark G; Jackson, Robert B

2010-12-01

Carbon Capture and Storage may use deep saline aquifers for CO(2) sequestration, but small CO(2) leakage could pose a risk to overlying fresh groundwater. We performed laboratory incubations of CO(2) infiltration under oxidizing conditions for >300 days on samples from four freshwater aquifers to 1) understand how CO(2) leakage affects freshwater quality; 2) develop selection criteria for deep sequestration sites based on inorganic metal contamination caused by CO(2) leaks to shallow aquifers; and 3) identify geochemical signatures for early detection criteria. After exposure to CO(2), water pH declines of 1-2 units were apparent in all aquifer samples. CO(2) caused concentrations of the alkali and alkaline earths and manganese, cobalt, nickel, and iron to increase by more than 2 orders of magnitude. Potentially dangerous uranium and barium increased throughout the entire experiment in some samples. Solid-phase metal mobility, carbonate buffering capacity, and redox state in the shallow overlying aquifers influence the impact of CO(2) leakage and should be considered when selecting deep geosequestration sites. Manganese, iron, calcium, and pH could be used as geochemical markers of a CO(2) leak, as their concentrations increase within 2 weeks of exposure to CO(2).

Distribution of aquifers, liquid-waste impoundments, and municipal water-supply sources, Massachusetts

USGS Publications Warehouse

Delaney, David F.; Maevsky, Anthony

1980-01-01

Impoundments of liquid waste are potential sources of ground-water contamination in Massachusetts. The map report, at a scale of 1 inch equals 4 miles, shows the idstribution of aquifers and the locations of municipal water-supply sources and known liquid-waste impoundments. Ground water, an important source of municipal water supply, is produced from shallow sand and gravel aquifers that are generally unconfined, less than 200 feet thick, and yield less than 2,000 gallons per minute to individual wells. These aquifers commonly occupy lowlands and stream valleys and are most extensive in eastern Massachusetts. Surface impoundments of liquid waste are commonly located over these aquifers. These impoundments may leak and allow waste to infiltrate underlying aquifers and alter their water quality. (USGS)

Estimating spatiotemporal variability and sustainability of shallow groundwater in a well-irrigated plain of the Haihe River basin using SWAT model

NASA Astrophysics Data System (ADS)

Zhang, Xueliang; Ren, Li; Kong, Xiangbin

2016-10-01

Quantitatively estimating the spatiotemporal variability and sustainability of shallow groundwater with a distributed hydrological model could provide an important basis for proper groundwater management, especially in well-irrigated areas. In this study, the Soil and Water Assessment Tool (SWAT) model was modified and applied to a well-irrigated plain of the Haihe River basin. First, appropriate initial values of the parameters in the groundwater module were determined based on abundant hydrogeological investigations and assessment. Then, the model was satisfactorily calibrated and validated using shallow groundwater table data from 16 national wells monitored monthly from 1993 to 2010 and 148 wells investigated yearly from 2006 to 2012. To further demonstrate the model's rationality, the multi-objective validation was conducted by comparing the simulated groundwater balance components, actual evapotranspiration, and crop yields to multiple sources data. Finally, the established SWAT was used to estimate both shallow groundwater table fluctuation and shallow aquifer water storage change in time and space. Results showed that the average shallow groundwater table declined at a rate of 0.69-1.56 m a-1, which depleted almost 350 × 108 m3 of shallow aquifer water storage in the cropland during the period of 1993-2012. Because of the heterogeneity of the underlying surface and precipitation, these variations were spatiotemporally different. Generally, the shallow groundwater table declined 1.43-1.88 m during the winter wheat (Triticum aestivum L.) growing season, while it recovered 0.28-0.57 m during the summer maize (Zea mays L.) growing season except when precipitation was exceptionally scarce. According to the simulated depletion rate, the shallow aquifer in the study area may face a depletion crisis within the next 80 years. This study identified the regions where prohibitions or restrictions on shallow groundwater exploitation should be urgently carried out.

Ground-water resources of the Clifton Park area, Saratoga County, New York

USGS Publications Warehouse

Heisig, Paul M.

2002-01-01

Ground water is the sole source of public water supply for Clifton Park, a growing suburban community north of Albany, New York. Increasing water demand, coupled with concerns over ground-water quantity and quality, led the Clifton Park Water Authority in 1995 to initiate a cooperative study with the U.S. Geological Survey to update and refine the understanding of ground-water resources in the area.Ground-water resources are largely associated with three aquifers in the eastern half of the area. These aquifers overlie or encompass the Colonie Channel, a north-south-oriented bedrock channel that is filled primarily with lacustrine glacial deposits. The three aquifers are: (1) an unconfined lacustrine sand aquifer, (2) the Colonie Channel aquifer, which is confined within the deepest parts of the channel and variably confined and unconfined within the shallower, peripheral channel areas, and (3) an unconfined alluvial aquifer beneath the Mohawk River flood plain, which represents the southern limit of the study area. The lacustrine sand aquifer has little potential for large-scale withdrawals because it is predominantly fine grained and is susceptible to contamination from human activities at land surface. Water from this aquifer can, however, recharge the underlying peripheral parts of the Colonie Channel aquifer where hydraulic connections are present. The Colonie Channel aquifer consists of thin sand and gravel and (or) shallow, fractured bedrock over much of the channel area; discontinuous deposits of thicker (more than 20 feet) sand and gravel are common in the peripheral channel areas. The deepest, or central, channel area of this aquifer is isolated from the overlying lacustrine sand aquifer by a continuous lacustrine silt and clay unit, which is the primary channel-fill deposit. The most productive areas of the Colonie Channel aquifer are typically the shallow peripheral areas, where conditions range from unconfined to confined. The most productive aquifer within the area is the alluvial aquifer, which is sustained to an unknown extent by induced infiltration of Mohawk River water.The chemical composition of ground water within the Clifton Park area varies widely in response to hydrogeologic setting, pumpage, and contamination from human activities. These chemical differences can be used to deduce ground-water flow paths within and between the unconfined and confined areas of the aquifer system. Six water types are defined; three are naturally occurring and three are the result of human activities.Precipitation that infiltrates the land surface is the sole source of recharge to the lacustrine sand aquifer; precipitation also recharges the alluvial aquifer and unconfined parts of the Colonie Channel aquifer. Ground-water withdrawals from confined or unconfined peripheral areas of the Colonie Channel aquifer induce flow from recharge areas, from the underlying bedrock, or from other confined aquifer areas.The rate of recharge to the confined central area of the Colonie Channel aquifer appears to be low. Potentiometric levels as much as 100 feet below water-table levels in the overlying lacustrine sand aquifer indicate two large depressions in the potentiometric surface; these depressions indicate that withdrawals from this aquifer have cumulatively exceeded the recharge rates. Localized recharge of the central channel area apparently occurs from two peripheral channel areas that are characterized by zones of elevated water levels and (or) by water chemistry that differs from those within the central channel area. Recharge from, or hydraulic connection with, adjoining segments of the Colonie Channel aquifer to the north and south is likely, but the potential for significant recharge is low because the aquifer is thin and poorly permeable.

Application of groundwater residence time tracers and broad screening for micro-organic contaminants in the Indo-Gangetic aquifer system

NASA Astrophysics Data System (ADS)

Lapworth, Dan; Das, Prerona; Mukherjee, Abhijit; Petersen, Jade; Gooddy, Daren; Krishan, Gopal

2017-04-01

Groundwater abstracted from aquifers underlying urban centres across India provide a vital source of domestic water. Abstraction from municipal and private supplies is considerable and growing rapidly with ever increasing demand for water from expanding urban populations. This trend is set to continue. The vulnerability of deeper aquifers (typically >100 m below ground) used for domestic water to contamination migration from often heavily contaminated shallow aquifer systems has not been studies in detail in India. This paper focusses on the occurrence of micro-organic contaminants within sedimentary aquifers beneath urban centres which are intensively pumped for drinking water and domestic use. New preliminary results from a detailed case study undertaken across Varanasi, a city with an estimated population of ca. 1.5 million in Uttar Pradesh. Micro -organic groundwater quality status and evolution with depth is investigated through selection of paired shallow and deep sites across the city. These results are considered within the context of paired groundwater residence time tracers within the top 150m within the sedimentary aquifer system. Groundwater emerging contaminant results are compared with surface water quality from the Ganges which is also used for drinking water supply. Broad screening for >800 micro-organic compounds was undertaken. Age dating tools were employed to constrain and inform a conceptual model of groundwater recharge and contaminant evolution within the sedimentary aquifer system.

Uncertainty Quantification and Risk Mitigation of CO2 Leakage in Groundwater Aquifers

NASA Astrophysics Data System (ADS)

Sun, Y.; Tong, C.; Mansoor, K.; Carroll, S.

2013-12-01

The risk of CO2 leakage into shallow aquifers through various pathways such as faults and abandoned wells is a concern of CO2 geological sequestration. If a leak is detected in an aquifer system, a contingency plan is required to manage the CO2 storage and to protect the groundwater source. Among many remediation and mitigation strategies, the simplest is to stop CO2 leakage at a wellbore. Therefore, it is necessary to address whether and when the CO2 leaks should be sealed, and how much risk can be mitigated. In the presence of various uncertainties, including geological-structure uncertainty and parametric uncertainty, the risk of CO2 leakage into an aquifer needs to be assessed with probabilistic distributions of uncertain parameters. In this study, we developed an integrated model to simulate multiphase flow of CO2 and brine in a deep storage reservoir, through a leaky well at an uncertain location, and subsequently multicomponent reactive transport in a shallow aquifer. Each sub-model covers its domain-specific physics. Uncertainties of geological structure and parameters are considered together with decision variables (CO2 injection rate and mitigation time) for risk assessment of leakage-impacted aquifer volume. High-resolution and less-expensive reduced-order models (ROMs) of risk profiles are approximated as polynomial functions of decision variables and all uncertain parameters. These reduced-order models are then used in the place of computationally-expensive numerical models for future decision-making on if and when the leaky well is sealed. The tradeoff between CO2 storage capacity in the reservoir and the leakage-induced risk in the aquifer is evaluated. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

Aquifers in coastal reclaimed lands - real world assessments

NASA Astrophysics Data System (ADS)

Saha, A.; Bironne, A.; Vonhögen-Peeters, L.; Lee, W. K.; Babovic, V. M.; Vermeulen, P.; van Baaren, E.; Karaoulis, M.; Blanchais, F.; Nguyen, M.; Pauw, P.; Doornenbal, P.

2017-12-01

Climate change and population growth are significant concerns in coastal regions around the world, where more than 30% of the world's population reside. The numbers continue to rise as coastal areas are increasingly urbanized. Urbanization creates land shortages along the coasts, which has spurred coastal reclamation activities as a viable solution. In this study, we focus on these reclamation areas; reclaimed areas in Singapore, and in the Netherlands, and investigate the potential of these reclaimed bodies as artificial aquifers that could attenuate water shortage problems in addition to their original purpose. We compare how the reclamation methods determine the hydrogeological characteristics of these manmade aquifers. We highlight similarities in freshwater lens development in the artificial shallow aquifers under natural recharge under diverse conditions, i.e. tropical and temperate zones, using numerical models. The characteristics and responses of these aquifers with dynamic freshwater-saltwater interface are contrasted against naturally occurring coastal aquifers where equilibrium was disturbed by anthropogenic activities. Finally, we assess the risks associated with subsidence and saltwater intrusion, combining measurements and numerical models, in case these aquifers are planned for Aquifer Storage and Recovery (ASR) or Managed Aquifer Recharge (MAR) strategies. Relative performances of some ASR schemes are simulated and compared in the reclaimed lands.

Monitoring a pilot CO2 injection experiment in a shallow aquifer using 3D cross-well electrical resistance tomography

NASA Astrophysics Data System (ADS)

Yang, X.; Lassen, R. N.; Looms, M. C.; Jensen, K. H.

2014-12-01

Three dimensional electrical resistance tomography (ERT) was used to monitor a pilot CO2 injection experiment at Vrøgum, Denmark. The purpose was to evaluate the effectiveness of the ERT method for monitoring the two opposing effects from gas-phase and dissolved CO2 in a shallow unconfined siliciclastic aquifer. Dissolved CO2 increases water electrical conductivity (EC) while gas phase CO2 reduce EC. We injected 45kg of CO2 into a shallow aquifer for 48 hours. ERT data were collected for 50 hours following CO2 injection. Four ERT monitoring boreholes were installed on a 5m by 5m square grid and each borehole had 24 electrodes at 0.5 m electrode spacing at depths from 1.5 m to 13 m. ERT data were inverted using a difference inversion algorithm for bulk EC. 3D ERT successfully detected the CO2 plume distribution and growth in the shallow aquifer. We found that the changes of bulk EC were dominantly positive following CO2 injection, indicating that the effect of dissolved CO2 overwhelmed that of gas phase CO2. The pre-injection baseline resistivity model clearly showed a three-layer structure of the site. The electrically more conductive glacial sand layer in the northeast region are likely more permeable than the overburden and underburden and CO2 plumes were actually confined in this layer. Temporal bulk EC increase from ERT agreed well with water EC and cross-borehole ground penetrating radar data. ERT monitoring offers a competitive advantage over water sampling and GPR methods because it provides 3D high-resolution temporal tomographic images of CO2 distribution and it can also be automated for unattended operation. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344. Lawrence Livermore National Security, LLC. LLNL IM release#: LLNL-PROC-657944.

An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

USGS Publications Warehouse

Carmichael, J.K.

1989-01-01

Alluvial soils of the flood plain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with mercury and other metals, organic compounds, and radio-nuclides originating from the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy 's Oak Ridge Reservation. Observation wells were installed in the shallow aquifer of the flood plain, and water quality samples were collected to determine if contaminants are present in the shallow groundwater. Groundwater in the shallow aquifer occurs under water-table conditions. Recharge is primarily from precipitation and discharge is to East Fork Poplar Creek. Groundwater levels fluctuate seasonally in response to variations in recharge and evapotranspiration. During extremely dry periods, the water table drops below the base of the shallow aquifer in some flood-plain areas. Contaminants found in water samples from several of the wells in concentrations which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, phenols, and strontium-90. Total and dissolved uranium concentrations exceeded the analytical detection limit in nearly 70% of the wells in the flood plain. The results of water quality determinations demonstrate that elevated concentrations of most trace metals (and possibly organic compounds and radionuclides) were caused by contaminated sediments in the samples. The presence of contaminated sediment in samples is suspected to be the result of borehole contamination during well installation. (USGS)

Hydrostratigraphy of a Sand Aquifer from Combined ERT and GPR

NASA Astrophysics Data System (ADS)

Papadimitrios, K. S.; Ferris, G.; Bank, C.

2015-12-01

Overlapping resistivity and ground-penetrating radar transects were collected on a shallow sand aquifer. The study area covers about 150 by 150 m, and the water table depth in that area ranges from as shallow as 30 cm to over 2m. Electric resistivity tomography shows layers of resistances which we relate to the vadose zone (above 1200 Ohm.m), the saturated zone (approx. 300 Ohm.m), and underlying aquitard (above 1200 Ohm.m, made of glacial till). The resistivity sections fail to capture the topography of the sand-till boundary seen in collected radargrams (e.g., from 80 to 120 ns over a 30 m horizontal distance). Converting radar travel times to thickness of the aquifer requires knowledge of water table depth as well as radar velocity in both the saturated and unsaturated sands. Water table depth can be taken from resistivity pseudosections as well as local piezometers. Radar velocities can be estimated based on the properties of the local sand and assuming 100% saturation. In merging the results from the two datasets we are able to map local hydrostratigraphy and aquifer geometry.

First-order shallow aquifer characteristics across Europe: The International Hydrogeological Map of Europe at scale 1:1.5 Million (IHME1500)

NASA Astrophysics Data System (ADS)

Günther, Andreas; Duscher, Klaus; Broda, Stefan; Clos, Patrick; Reichling, Jörg

2017-04-01

Since the mid of the last century, pan-European hydrogeological overview-mapping is conducted at the scale 1 : 1.5 Million following common standards and guidelines to interpret suitable geologic mapping units in terms of potential uppermost aquifer (or non-aquifer) characteristics. These comprises potential aquifer productivities and general hydrogeological aquifer conditions (fissured vs. porous). The printed IHME1500 dataset successively elaborated and published from 1970 - 2013 consists of 25 individual map sheets. Besides the potential aquifer characterization grouped in six classes, IHME1500 offers a complete coverage of lithological material properties of potential shallow aquifer assemblages, and tracelines of major fault structures. Regional information on groundwater surfaces, aquifer thicknesses and depths, locations and characteristics of groundwater springs and other punctual information related to European groundwater resources is present for some areas in selected map sheets, however not digitally available. Synoptic IHME1500 vector data consists of a topographically corrected, seamless and harmonized polygon layer with attribute information on potential aquifer productivity and lithology. While the standardized aquifer-classification is relatively easy to harmonize across the entire mapped area, the lithological information of IHME1500 is presented using sheet-specific legend information resulting in more than 1000 aquifer lithology classes. An attempt was made to harmonize this information utilizing a specifically developed taxonomic scheme, treating consolidated, partly consolidated and unconsolidated materials separately. The translation of the original lithological information into this scheme allows for a hierarchical grouping of the mapping units into five generalization levels, where the highest aggregation level displays a ternary map showing the distribution of consolidated, partially consolidated and unconsolidated aquifer materials. The harmonized and hierarchically structured IHME1500 information based on the published map sheet data also allows for the extension of the mapped area in regions where only incomplete, unpublished IHME1500 draft information is available. IHME1500 now covers the entire European continent up to the Urals, the Caucasus region, and parts of the Middle East (Turkey, Cyprus, parts of Syria and Iraq). IHME1500 represents the only digitally available coherent overview information on potential groundwater resources and shallow aquifer characteristics across Europe. The data is therefore of great use for European policy support in terms of e.g. transboundary aquifer identification and characterization, the harmonization of regional European groundwater bodies, and the delineation of hot spot regions for aquifer systems under potential environmental stress with respect to climate change, natural hazards or migratory flows. Additionally, the lithological information of IHME1500 represents the only harmonized pan-European dataset on shallow subsurface geologic materials available and can used for the spatial delineation of soil parent materials and as a spatial predictor for the evaluation of geomorphological hazards at overview scales. IHME1500 GIS data can be downloaded through BGŔs product centre (http://produktcenter.bgr.de).

Hydrogeology and simulation of ground-water flow at Arnold Air Force Base, Coffee and Franklin counties, Tennessee

USGS Publications Warehouse

Haugh, C.J.; Mahoney, E.N.

1994-01-01

The U.S. Air Force at Arnold Air Force Base (AAFB), in Coffee and Franklin Counties, Tennessee, is investigating ground-water contamination in selected areas of the base. This report documents the results of a comprehensive investigation of the regional hydrogeology of the AAFB area. Three aquifers within the Highland Rim aquifer system, the shallow aquifer, the Manchester aquifer, and the Fort Payne aquifer, have been identified in the study area. Of these, the Manchester aquifer is the primary source of water for domestic use. Drilling and water- quality data indicate that the Chattanooga Shale is an effective confining unit, isolating the Highland Rim aquifer system from the deeper, upper Central Basin aquifer system. A regional ground-water divide, approximately coinciding with the Duck River-Elk River drainage divide, underlies AAFB and runs from southwest to northeast. The general direction of most ground-water flow is to the north- west or to the northwest or to the southeast from the divide towards tributary streams that drain the area. Recharge estimates range from 4 to 11 inches per year. Digital computer modeling was used to simulate and provide a better understanding of the ground-water flow system. The model indicates that most of the ground-water flow occurs in the shallow and Manchester aquifers. The model was most sensitive to increases in hydraulic conductivity and changes in recharge rates. Particle-tracking analysis from selected sites of ground-water contamination indicates a potential for contami- nants to be transported beyond the boundary of AAFB.

Superfund Record of Decision (EPA Region 6): Cimarron Mining Corporation site, Operable Unit 1, Lincoln County, Carrizozo, NM. (First remedial action), September 1990

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-09-21

The 10.6-acre Cimarron Mining site, Lincoln County, New Mexico, is an inactive milling facility used to recover iron from ores transported to the site. A shallow aquifer, which is not a potential drinking water source, and a deeper primary drinking water aquifer lie beneath the site. Cyanide was used until 1982 to recover precious metals. The operation of the mill resulted in the discharge of contaminated liquids onsite. The sources of environmental cyanide contamination at the site are the processed waste materials, including tailings piles and cinder block trench sediment piles, the cyanide solution and tailings spillage areas, and themore » cyanide solution recycling and disposal areas, including cinder block trenches and an unlined discharge pit. The major sources of ground water contamination by cyanide are the cinder block trenches and the discharge pit. These areas of prolonged contact between cyanide solution and underlying soil led to cyanide contamination in the shallow aquifer. The ROD addresses contaminated shallow ground water at the Cimarron Mining mill area as Operable Unit 1 (OU1). The primary contaminants of concern affecting the ground water are inorganics including cyanide.« less

Geochemical Evidence for Possible Natural Migration of Marcellus Formation Brine to Shallow Aquifers in Pennsylvania

NASA Astrophysics Data System (ADS)

Warner, N. R.; Darrah, T. H.; Jackson, R. B.; Osborn, S.; Down, A.; Vengosh, A.

2012-12-01

The acceleration in production of natural gas from shale formations through horizontal drilling and hydraulic fracturing has altered the landscape of domestic energy production in the USA. Yet shale gas exploration has generated an increased awareness of risks to drinking water quality amid concerns for the possible migration of stray gas or hydraulic fracturing fluid and/or flowback brine to shallow drinking water aquifers. The degree to which shallow drinking water is at risk from hydraulic fracturing could depend upon the hydraulic connectivity between the shale gas formations and the surface. In this study, we analyzed the geochemistry of over 400 water samples located across six counties of northeastern Pennsylvania in the three principle aquifers, two Upper Devonian Age bedrock aquifers (Catskill and Lock Haven) and one Quaternary Age (Alluvium) that overlie the Marcellus Formation. Based on a detailed analysis of major (Br, Cl, Na, Mg, Ba, and Sr) and trace (Li) element geochemistry, coupled with utilization of a specific spectrum of isotopic tracers (87Sr/86Sr, 228Ra/ 226Ra, 2H/H, 18O/16O), we identify a salinized (Cl> 20 mg/L) shallow groundwater type which suggests conservative mixing relationships between fresh shallow groundwater and an underlying brine. Identification of the brine source is complicated as many of the brines in the northern Appalachian Basin likely share a common origin as the expelled remnants of the formation of the Silurian Salina evaporate deposits. To determine the ultimate source of the diluted brine we compared the observed geochemistry to over 80 brines produced from northern Appalachian Basin formations. The shallow salinized groundwater most closely resembles diluted produced water from the Middle Devonian Marcellus Formation. The 18O/16O and 2H/H of the salinized groundwater indicate that the brine is likely diluted with post-glacial (<10,000 ybp) meteoric water. Combined, these data indicate that hydraulic connections allowed cross formational migration of brine from deeper formations (1-2 kilometers below ground surface) and subsequent dilution. The occurrence of the saline water does not appear to be correlated with the location of shale-gas wells. Also, salinized groundwater with similar major element chemistry was reported prior to the most recent shale-gas development in the region. The source of the salinized water is likely not the recent drilling and hydraulic fracturing; instead brine migrated into the shallow aquifers and was recently diluted through natural pathways and processes. However, the presence of natural hydraulic connections to deeper formations suggests specific structural and hydrodynamic regimes in northeastern Pennsylvania where shallow drinking water resources are at greater risk of contamination, particularly with fugitive gases, during drilling and hydraulic fracturing of shale gas. The severity of the risk could depend upon the presence of pathways that allow the migration of fluids into the shallow aquifers on human time scales.

Inter-relationship between shallow and deep aquifers under the influence of deep groundwater exploitation in the North China Plain

NASA Astrophysics Data System (ADS)

Han, Dongmei; Cao, Guoliang; Love, Andrew J.

2017-04-01

In the North China Plain (NCP), the interaction between shallow and deep groundwater flow systems enhanced by groundwater extraction has been investigated using multi-isotopic and chemical tracers for understanding the mechanism of salt water transport, which has long been one of the major regional environmental hydrogeological problems in NCP. Information about the problem will be determined using multiple lines of evidence, including field surveys of drilling and water sampling, as well as laboratory experiments and physical and numerical simulations. A conceptual model of groundwater flow system along WE cross-section from piedmont area to coastal region (Shijiazhuang-Hengshui-Cangzhou) has been developed and verified by geochemical modeling. A combined hydrogeochemical and isotopic investigation using ion relationships such as Cl/Br ratios, and environment isotopes (δ 18O, δ 2H, δ 34SSO4-δ 18OSO4, δ 15NNO_3-δ 18ONO_3, δ 13C and 87Sr/86Sr) was reviewed and carried for determining the sources of aquifer recharge, the origin of solutes and the mixing processes in groundwater flow system under the anthropogenic pumping and pollution. Results indicate that hydrochemistry of groundwater is characterized by mixing between end-members coming directly from Piedmont recharge areas, saline groundwater formed during geohistorical transgression in the shallow aquifers of central plain, and to groundwater circulating in a deeply buried Quaternary sediments. We also reviewed the groundwater age (tritium contents, 14C ages, 3H-3He ages, basin-scale flow modeling ages of groundwater) to recognize the local distributed recharge in this strongly exploited aquifer system. Finally, combined with the 1-D Cl transport modeling for the pore water of clay-rich aquitard, we reveal that salt transport in the aquitard is primarily controlled by vertical diffusion on million years' time scale, and the observed the salinized groundwater in deep aquifer may be caused by passing through ``windows'' or preferential flow path, rather than vertical flow through the aquitard.

Water resources of Lincoln and Union counties, South Dakota

USGS Publications Warehouse

Niehus, C.A.

1994-01-01

Water resources of Lincoln and Union Counties occur as surface water in streams and lakes and ground water in ten major glacial and one major bedrock aquifers. The major surface-water sources are the Missouri and Big Sioux Rivers. Glacial aquifers contain about 4 million acre-feet of water in storage; 1.5 million acre-feet are contained in the Missouri aquifer. The Wall Lake, Shindler, and Upper Vemillion-Missouri aquifers are deeply buried, confined aquifers with average thicknesses ranging from 31 to 41 feet. The Harrisburg and Big Sioux aquifers are shallow, water-table aquifers with average thicknesses of 26 and 28 feet, respectively. The Parker-Centerville, Newton Hills, and Brule Creek aquifers are buried, confined aquifers with average thicknesses ranging from 33 to 36 feet. The Lower Vermillion-Missouri aquifer is a buried, confined aquifer with an average thickness of 99 feet. The Missouri aquifer is confined in the northeastern portion of the aquifer and is a shallow, water-table aquifer elsewhere with average cumulative thickness of 84 feet.

Potential effects of surface coal mining on the hydrology of the Circle West coal tracts, McCone County, eastern Montana

USGS Publications Warehouse

Cannon, M.R.

1984-01-01

The Circle West coal tracts in McCone County, Montana, contain about 460 million tons of recoverable coal reserves. Estimates of coal reserves for the tract are based predominantly on the S coal bed, which averages about 16 ft in thickness. About 175 million tons, or 38%, of the recoverable coal is Federally owned and has been identified for potential lease sale. A hydrologic study has been conducted in the potential lease area to describe existing hydrologic systems and to assess potential effects of surface coal mining on local water resources. Geohydrologic data collected from wells and drill holes indicate that shallow aquifers exist in sandstone and coal beds of the Tongue River Member of the Fort Union Formation (Paleocene age). These shallow aquifers generally have small values of hydraulic conductivity (0.1 to 380 ft/day) and typically yield from 2 to 20 gal/min to stock and domestic wells. Where coal is extremely fractured or the thickness of saturated sandstone is large, some wells can yield in excess of 70 gal/min. Chemical analyses indicate that most shallow aquifers contain a sodium sulfate bicarbonate type water. Surface water resources of the area consist of intermittent streamflow in parts of the Nelson and Timber Creek basins plus a large network of reservoirs. The reservoirs provide a large part of the water supply for area livestock and irrigation. Water quality data for Nelson and Timber Creeks indicate that the water generally is a sodium sulfate type and has a large concentration (181 to 6,960 mg/L) of dissolved solids. Mining of the S coal bed in the Circle West coal tracts would permanently remove shallow coal and sandstone aquifers, resulting in the loss of shallow stock wells. Mining would destroy livestock reservoirs, alter runoff characteristics of Nelson Creek, and temporarily lower water levels in shallow aquifers near the mine. Leaching of soluble constituents from mine spoils may cause a long-term degradation of the quality of water in shallow aquifers in and near the coal tracts. Some of the effects on local water supplies could be mitigated by development of alternative water resources in deeper aquifers such as the Tullock aquifer of Paleocene age and the Fox Hills-lower Hell Creek aquifer of Late Cretaceous age. (Author 's abstract)

Assessment of groundwater contamination by gypsum dissolution in San Luis Potosí (México) using geoelectrical characterization

NASA Astrophysics Data System (ADS)

Arango-Galvan, C.; Ramos-Leal, J. A.; Yáñez-Rodríguez, M. A.; Corbo-Camargo, F.

2017-12-01

The Cerritos and Río Verde aquifers in San Luis Potosí (central México) make up a very complex aquifer system that is seriously affected by the overexploitation and the high concentration of sulphates. Currently, it is partially closed for extraction causing a substantial decrease in per capita drinking water availability affecting to more than 50,000 inhabitants in the region. Therefore, a very comprehensive study has been proposed in order to evaluate not only the groundwater contamination distribution but also to better know the aquifer configuration and its main hydrogeological characteristics as well. These studies include a detailed geological reconnaissance, hydrogeochemical analyses and a geoelectrical characterization. The main goal is to assess the aquifer geometry and to identify the gypsum horizons causing the presence of higher concentrations of sulphates in drinking water. A total of 26 audiomagnetotelluric soundings were measured and modelled along profiles following a perpendicular direction to the NW regional trending. Two-dimensional resistivity models suggest the presence of a shallow conductive layer (C1) with resistivity values ranging from 10 to 20 Ohm.m. It is related to the upper aquifer with a very low exploitation potential. A less conductive horizon (C2; 50 Ohm.m) underlying the shallow aquifer could be related to a very fractured limestone horizon forming a confined aquifer in the middle of the valley. A very resistive layer (R1) is observed underlying C1 and C2 units. This strata shows higher resistivity values (>100 Ohm.m) and could be associated with a reefal limestone identified as El Abra Formation. Finally, a conductive layer (<100 Ohm.m) observed beneath this horizon could be related to the oldest stratigraphic unit outcropping on the region, the Guaxcamá Formation, a gypsum-enriched unit, that contributes to the presence of sulphates in the upper aquifers by dissolution processes.

Impact of urbanization coupled with drought situations on groundwater quality in shallow (basalt) and deeper (granite) aquifers with special reference to fluoride in Nanded-Waghala Municipal Corporation, Nanded District, Maharashtra (India).

PubMed

Pandith, Madhnure; Kaplay, R D; Potdar, S S; Sangnor, H; Rao, A D

2017-09-01

Rapid expansion in urbanization and industrialization coupled with recent drought conditions has triggered unplanned groundwater development leading to severe stress on groundwater resources in many urban cities of India, particularly cities like Nanded, Maharashtra. In the quest of tapping drinking water requirement, due to recent drought conditions, people from the city are piercing through entire thickness of shallow basalt aquifers to reach productive deeper granite aquifers. Earlier reports from Nanded and surrounding districts suggest that deeper granite aquifer is contaminated with fluoride (geogenic). The study aimed to find out variations in fluoride concentration in shallow basalt (10-167 m) and deeper granite aquifers (below 167 m) and to find out the relationship between fluoride and other ions. Study suggests that concentration of fluoride in shallow basalt aquifer is within maximum permissible limits of Bureau of Indian Standards and deeper granite aquifer contains as high as 4.9 mg/l of fluoride and all samples from granite aquifers are unfit for human consumption. The groundwater from basalt aquifer is mainly Ca-HCO 3- Cl type, and from granite aquifer, it is Ca-Na-Cl type. The correlation plot between F - vs. pH, Na + and HCO 3 - shows a positive correlation and an inverse relationship with Ca 2+ in both aquifers. As recommendations, it is suggested that granite aquifers should not be tapped for drinking purposes; however, in drought situations, water from this aquifer should be blended with treated surface water before supplying for drinking purposes. Efforts may be made to utilize 1.35 MCM of rainwater from available rooftop, which is sufficient to cater for the needs of ~40,800 people annually. Most effective defluoridation techniques like electrolytic de-fluoridation (EDF), ion exchange and reverse osmosis may be adopted along with integrated fluorosis mitigation measures.

Recovery of energetically overexploited urban aquifers using surface water

NASA Astrophysics Data System (ADS)

García-Gil, Alejandro; Vázquez-Suñé, Enric; Sánchez-Navarro, José Ángel; Mateo Lázaro, Jesús

2015-12-01

Shallow aquifers have an important role in reducing greenhouse gases through helping manage the temperature of urban environments. Nevertheless, the uncontrolled rapid use of shallow groundwater resources to heat or cool urban environments can cause thermal pollution that will limit the long term sustainability of the resource. Therefore, there is a need for appropriate mitigation/remediation strategies capable of recovering energetically overexploited aquifers. In this work, a novel remediation strategy based on surface water recharge into aquifers is presented. To evaluate the capabilities of such measures for effective remediation, this strategy is optimized for a management problem raised in the overheated "Urban Alluvial Aquifer of Zaragoza" (Spain). The application of a transient groundwater flow and heat transport model under 512 different mitigation scenarios has enabled to quantify and discuss the magnitude of the remediation effect as a respond to injection rates of surface water, seasonal schedule of the injection and location of injection. The quantification of the relationship between these variables together with the evaluation of the amount of surface water injected per year in each scenario proposed have provided a better understanding of the system processes and an optimal management alternative. This work also makes awareness of the magnitude of the remediation procedure which is in an order of magnitude of tenths of years.

Herbicides and degradates in shallow aquifers of Illinois: Spatial and temporal trends

USGS Publications Warehouse

Mills, P.C.; Kolpin, D.W.; Scribner, E.A.; Thurman, E.M.

2005-01-01

During the fall of 2000, the occurrence was examined of 16 herbicides and 13 herbicide degradates in samples from 55 wells in shallow aquifers underlying grain producing regions of Illinois. Herbicide compounds with concentrations above 0.05 ??g/L were detected in 56 percent of the samples. No concentrations exceeded regulatory drinking water standards. The six most frequently detected compounds were degradates. Water age was an important factor in determining vulnerability of ground water to transport of herbicide compounds. Unconsolidated aquifers, which were indicated to generally contain younger ground water than bedrock aquifers, had a higher occurrence of herbicides (73 percent of samples) than bedrock aquifers (22 percent). Temporal analysis to determine if changes in concentrations of selected herbicides and degradates could be observed over a near decadal period indicated a decrease in detection frequency (25 to 18 percent) between samplings in 1991 and 2000. Over this period, significant differences in concentrations were observed for atrazine (decrease) and total acetochlor (increase). The increase in acetochlor compound concentrations corresponds to an increase in acetochlor use during the study period, while the decrease in atrazine concentrations corresponds to relatively consistent use of atrazine. Changes in frequency of herbicide detection and concentration do not appear related to changes in land use near sampled wells.

Groundwater Dynamics in Fossil Fractured Carbonate Aquifers in Eastern Arabian Peninsula

NASA Astrophysics Data System (ADS)

Farag, A. Z. A.; Heggy, E.; Helal, M.; Thirunavukkarasu, D.; Scabbia, G.; Palmer, E. M.

2017-12-01

The Eastern Arabian Peninsula, notably the Qatar Peninsula, represents one of the highest natural groundwater discharge areas for the Arabian platform fossil aquifer system. Groundwater flow dynamics in these aquifers trace the paleoclimatic conditions that have prevailed the Arabian Peninsula during the Quaternary. In such settings, connections between aquifers strongly affect the flow dynamics, water quality and availability as well as karst formation and landscape evolution. Geological structures such as folds, faults and fractures are central to aquifer connectivity, yet their role on groundwater flow is poorly understood. Herein, we performed a detailed mapping of exposed and buried structural features in Qatar using Landsat, Sentinel and ALOS-PalSAR scenes, correlated with field and laboratory measurements to understand their role in aquifer connectivity and groundwater dynamics. Our results suggest that E-W oriented fold-related faults act as vertical conduits along which artesian upward leakages from the deep aquifers (e.g. Aruma and Umm er Radhuma) take place into the shallower aquifers (e.g. Rus and Dammam). Evidence includes: (1) the high potentiometric surfaces of deep aquifers (6 to 25 m amsl) compare to the shallower aquifers (2-3 m amsl for the same region); (2) anomalous elevation of groundwater levels and steeper hydraulic gradients in densely faulted regions; (3) mixed isotopic composition in shallow aquifers (δ18O: -5 to -2 ‰, δ2H: -40 to -10 ‰) between reported deep fossil waters (δ18O: -6.3 ‰, δ2H: -55 ‰) and modern meteoric waters (weighted average: δ18O: -0.6 ‰, δ2H: 4 ‰); (4) abundant meso-crystalline fibrous gypsum veins along fault zones in the Dammam Formation (up to 28 m amsl) in southern Qatar where the anhydritic member of the Rus Formation predominates the subsurface leading to gypsum oversaturation of groundwater. The similarity of crystal morphology (platy crystals under SEM), mineralogical compositions from XRD analysis and geologic setting suggest a common genesis from elevated groundwater along faults during wet climatic periods. The present study suggests that ascending gaseous-rich deep waters along faults in Qatar is degrading the water quality and causing dissolution of carbonates and evaporites leading to strong karstification with abundant collapse features.

Chemical character of ground water in the shallow water-table aquifer at selected localities in the Memphis area, Tennessee

USGS Publications Warehouse

Parks, William Scott; Graham, D.D.; Lowery, J.F.

1981-01-01

Eight deep wells are being monitored in the Memphis, Tenn., area to detect any changes in the chemical character of water moving through the Memphis Sand towards major pumping centers. These wells are strategically located so as to intercept groundwater enroute through the Memphis Sand from the outcrop-recharge area. Although water quality analyses are available for many wells in the shallow water-table aquifer, no specific investigation has been made to characterize the quality of the water in this aquifer from which the Memphis Sand also receives part of its recharge. This investigation is to determine the chemical character of groundwater in the shallow water-table aquifer at selected localities in the Memphis area. Methods used to install eight shallow wells at abandoned dump sites containing chemical and/or industrial waste are described. Water samples from the eight shallow wells and two deep wells in the Memphis Sand were collected and analyzed. Results of the analysis are presented and the locations of the wells and dumps are shown on maps. (USGS)

Water Footprint and Water Consumption for the Main Crops and Biofuels Produced in Brazil

NASA Astrophysics Data System (ADS)

Sun, Y.; Tong, C.; Mansoor, K.; Carroll, S.

2011-12-01

The risk of CO2 leakage into shallow aquifers through various pathways such as faults and abandoned wells is a concern of CO2 geological sequestration. If a leak is detected in an aquifer system, a contingency plan is required to manage the CO2 storage and to protect the groundwater source. Among many remediation and mitigation strategies, the simplest is to stop CO2 leakage at a wellbore. Therefore, it is necessary to address whether and when the CO2 leaks should be sealed, and how much risk can be mitigated. In the presence of various uncertainties, including geological-structure uncertainty and parametric uncertainty, the risk of CO2 leakage into an aquifer needs to be assessed with probabilistic distributions of uncertain parameters. In this study, we developed an integrated model to simulate multiphase flow of CO2 and brine in a deep storage reservoir, through a leaky well at an uncertain location, and subsequently multicomponent reactive transport in a shallow aquifer. Each sub-model covers its domain-specific physics. Uncertainties of geological structure and parameters are considered together with decision variables (CO2 injection rate and mitigation time) for risk assessment of leakage-impacted aquifer volume. High-resolution and less-expensive reduced-order models (ROMs) of risk profiles are approximated as polynomial functions of decision variables and all uncertain parameters. These reduced-order models are then used in the place of computationally-expensive numerical models for future decision-making on if and when the leaky well is sealed. The tradeoff between CO2 storage capacity in the reservoir and the leakage-induced risk in the aquifer is evaluated. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

Geohydrology of the valley-fill aquifer in the Bath area, Lower Cohocton River, Steuben County, New York

USGS Publications Warehouse

Pagano, Timothy S.; Terry, D.B.; Shaw, M.L.; Ingram, A.W.

1984-01-01

The Bath valley-fill aquifer, southern New York, composed of outwash, ice-contact, and ice-disintegration sand and gravel, is highly productive and is in many areas in hydraulic contact with the Cohocton River. Potential well yields range 50 to more than 1,000 gallons per minute. Most of the aquifer is under shallow water-table conditions and vulnerable to surface contamination. Thickness ranges from 20 to 40 feet. Buried aquifers are present locally. The aquifer system underlies an area containing only a few small communities and therefore is not heavily pumped. Geohydrologic data are compiled on six maps at 1:24,000 scale and on a sheet of geologic sections. The maps depict surficial geology, soil-infiltration capacity, potentiometric surface, aquifer thickness, well yields, and land use. This map report set is one in a series of four that depict selected aquifers in Wester New York. It supplements a series that is being done by the U.S. Geological Survey in cooperation with State agencies. The maps are based largely on published reports, data filled in several State agencies, and some additional field data collection. (USGS)

Characterization of mechanisms and processes of groundwater salinization in irrigated coastal area using statistics, GIS, and hydrogeochemical investigations.

PubMed

Bouzourra, Hazar; Bouhlila, Rachida; Elango, L; Slama, Fairouz; Ouslati, Naceur

2015-02-01

Coastal aquifers are at threat of salinization in most parts of the world. This study was carried out in coastal shallow aquifers of Aousja-Ghar El Melh and Kalâat el Andalous, northeastern of Tunisia with an objective to identify sources and processes of groundwater salinization. Groundwater samples were collected from 42 shallow dug wells during July and September 2007. Chemical parameters such as Na(+), Ca(2+), Mg(2+), K(+), Cl(-), SO4 (2-), HCO3 (-), NO3 (-), Br(-), and F(-) were analyzed. The combination of hydrogeochemical, statistical, and GIS approaches was used to understand and to identify the main sources of salinization and contamination of these shallow coastal aquifers as follows: (i) water-rock interaction, (ii) evapotranspiration, (iii) saltwater is started to intrude before 1972 and it is still intruding continuously, (iv) irrigation return flow, (v) sea aerosol spray, and finally, (vi) agricultural fertilizers. During 2005/2006, the overexploitation of the renewable water resources of aquifers caused saline water intrusion. In 2007, the freshening of a brackish-saline groundwater occurred under natural recharge conditions by Ca-HCO3 meteoric freshwater. The cationic exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. The sulfate reduction process and the neo-formation of clays minerals characterize the hypersaline coastal Sebkha environments. Evaporation tends to increase the concentrations of solutes in groundwater from the recharge areas to the discharge areas and leads to precipitate carbonate and sulfate minerals.

Comparison between agricultural and urban ground-water quality in the Mobile River Basin

USGS Publications Warehouse

Robinson, James L.

2003-01-01

The Black Warrior River aquifer is a major source of public water supply in the Mobile River Basin. The aquifer outcrop trends northwest - southeast across Mississippi and Alabama. A relatively thin shallow aquifer overlies and recharges the Black Warrior River aquifer in the flood plains and terraces of the Alabama, Coosa, Black Warrior, and Tallapoosa Rivers. Ground water in the shallow aquifer and the Black Warrior River aquifer is susceptible to contamination due to the effects of land use. Ground-water quality in the shallow aquifer and the shallow subcrop of the Black Warrior River aquifer, underlying an agricultural and an urban area, is described and compared. The agricultural and urban areas are located in central Alabama in Autauga, Elmore, Lowndes, Macon, Montgomery, and Tuscaloosa Counties. Row cropping in the Mobile River Basin is concentrated within the flood plains of major rivers and their tributaries, and has been practiced in some of the fields for nearly 100 years. Major crops are cotton, corn, and beans. Crop rotation and no-till planting are practiced, and a variety of crops are grown on about one-third of the farms. Row cropping is interspersed with pasture and forested areas. In 1997, the average farm size in the agricultural area ranged from 196 to 524 acres. The urban area is located in eastern Montgomery, Alabama, where residential and commercial development overlies the shallow aquifer and subcrop of the Black Warrior River aquifer. Development of the urban area began about 1965 and continued in some areas through 1995. The average home is built on a 1/8 - to 1/4 - acre lot. Ground-water samples were collected from 29 wells in the agricultural area, 30 wells in the urban area, and a reference well located in a predominately forested area. The median depth to the screens of the agricultural and urban wells was 22.5 and 29 feet, respectively. Ground-water samples were analyzed for physical properties, major ions, nutrients, and pesticides. Samples from 8 of the agricultural wells and all 30 urban wells were age dated using analyses of chlorofluorocarbon, sulfur hexafluoride, and dissolved gases. Ground water sampled from the agricultural wells ranged in age from about 14 to 34 years, with a median age of about 18.5 years. Ground water sampled from the urban wells ranged in age from about 1 to 45 years, with a median age of about 12 years. The ages estimated for the ground water are consistent with the geology and hydrology of the study area and the design of the wells. All of the agricultural and urban wells sampled for this study produce water from the shallow aquifer that overlies and recharges the Black Warrior River aquifer, or from the uppermost unit of the Black Warrior River aquifer. The wells are located in the same physiographic setting, have similar depths, and the water collected from the wells had a similar range in age. Statistically significant differences in ground-water quality beneath the agricultural and urban areas can reasonably be attributed to the effects of land use. Ground water from the agricultural wells typically had acidic pH values and low specific conductance and alkalinity values. The water contained few dissolved solids, and typically had small concentrations of ions. Some of the agricultural ground-water contained concentrations of ammonia, nitrite plus nitrate, phosphorus, orthophosphate, and dissolved organic carbon in concentrations that exceeded those typically found in ground water. Pesticides were detected in ground water collected from 25 of the 29 agricultural wells. Nineteen different pesticide compounds were detected a total of 83 times. Herbicides were the most frequently detected class of pesticides. The greatest concentration of any pesticide was an estimated value of 1.4 microgram per liter of fluometuron. The Wilcoxan rank sum test was used to determine statistically significant differences in water quality between the agricultural and urba

Modeling of Methane Migration in Shallow Aquifers from Shale Gas Well Drilling.

PubMed

Zhang, Liwei; Soeder, Daniel J

2016-05-01

The vertical portion of a shale gas well, known as the "tophole" is often drilled using an air-hammer bit that may introduce pressures as high as 2400 kPa (350 psi) into groundwater while penetrating shallow aquifers. A 3-D TOUGH2 model was used to simulate the flow of groundwater under the high hydraulic heads that may be imposed by such trapped compressed air, based on an observed case in West Virginia (USA) in 2012. The model realizations show that high-pressure air trapped in aquifers may cause groundwater to surge away from the drill site at observable velocities. If dissolved methane is present within the aquifer, the methane can be entrained and transported to a maximum distance of 10.6 m per day. Results from this study suggest that one cause of the reported increase in methane concentrations in groundwater near shale gas production wells may be the transport of pre-existing methane via groundwater surges induced by air drilling, not necessarily direct natural gas leakage from the unconventional gas reservoir. The primary transport mechanisms are advective transport of dissolved methane with water flow, and diffusive transport of dissolved methane. © 2015, National Ground Water Association.

Shallow aquifer storage and recovery (SASR): Initial findings from the Willamette Basin, Oregon

NASA Astrophysics Data System (ADS)

Neumann, P.; Haggerty, R.

2012-12-01

A novel mode of shallow aquifer management could increase the volumetric potential and distribution of groundwater storage. We refer to this mode as shallow aquifer storage and recovery (SASR) and gauge its potential as a freshwater storage tool. By this mode, water is stored in hydraulically connected aquifers with minimal impact to surface water resources. Basin-scale numerical modeling provides a linkage between storage efficiency and hydrogeological parameters, which in turn guides rulemaking for how and where water can be stored. Increased understanding of regional groundwater-surface water interactions is vital to effective SASR implementation. In this study we (1) use a calibrated model of the central Willamette Basin (CWB), Oregon to quantify SASR storage efficiency at 30 locations; (2) estimate SASR volumetric storage potential throughout the CWB based on these results and pertinent hydrogeological parameters; and (3) introduce a methodology for management of SASR by such parameters. Of 3 shallow, sedimentary aquifers in the CWB, we find the moderately conductive, semi-confined, middle sedimentary unit (MSU) to be most efficient for SASR. We estimate that users overlying 80% of the area in this aquifer could store injected water with greater than 80% efficiency, and find efficiencies of up to 95%. As a function of local production well yields, we estimate a maximum annual volumetric storage potential of 30 million m3 using SASR in the MSU. This volume constitutes roughly 9% of the current estimated summer pumpage in the Willamette basin at large. The dimensionless quantity lag #—calculated using modeled specific capacity, distance to nearest in-layer stream boundary, and injection duration—exhibits relatively high correlation to SASR storage efficiency at potential locations in the CWB. This correlation suggests that basic field measurements could guide SASR as an efficient shallow aquifer storage tool.

Thermodynamic and hydrochemical controls on CH4 in a coal seam gas and overlying alluvial aquifer: new insights into CH4 origins

PubMed Central

Owen, D. Des. R.; Shouakar-Stash, O.; Morgenstern, U.; Aravena, R.

2016-01-01

Using a comprehensive data set (dissolved CH4, δ13C-CH4, δ2H-CH4, δ13C-DIC, δ37Cl, δ2H-H2O, δ18O-H2O, Na, K, Ca, Mg, HCO3, Cl, Br, SO4, NO3 and DO), in combination with a novel application of isometric log ratios, this study describes hydrochemical and thermodynamic controls on dissolved CH4 from a coal seam gas reservoir and an alluvial aquifer in the Condamine catchment, eastern Surat/north-western Clarence-Moreton basins, Australia. δ13C-CH4 data in the gas reservoir (−58‰ to −49‰) and shallow coal measures underlying the alluvium (−80‰ to −65‰) are distinct. CO2 reduction is the dominant methanogenic pathway in all aquifers, and it is controlled by SO4 concentrations and competition for reactants such as H2. At isolated, brackish sites in the shallow coal measures and alluvium, highly depleted δ2H-CH4 (<310‰) indicate acetoclastic methanogenesis where SO4 concentrations inhibit CO2 reduction. Evidence of CH4 migration from the deep gas reservoir (200–500 m) to the shallow coal measures (<200 m) or the alluvium was not observed. The study demonstrates the importance of understanding CH4 at different depth profiles within and between aquifers. Further research, including culturing studies of microbial consortia, will improve our understanding of the occurrence of CH4 within and between aquifers in these basins. PMID:27578542

Defining the natural fracture network in a shale gas play and its cover succession: The case of the Utica Shale in eastern Canada

NASA Astrophysics Data System (ADS)

Ladevèze, P.; Séjourné, S.; Rivard, C.; Lavoie, D.; Lefebvre, R.; Rouleau, A.

2018-03-01

In the St. Lawrence sedimentary platform (eastern Canada), very little data are available between shallow fresh water aquifers and deep geological hydrocarbon reservoir units (here referred to as the intermediate zone). Characterization of this intermediate zone is crucial, as the latter controls aquifer vulnerability to operations carried out at depth. In this paper, the natural fracture networks in shallow aquifers and in the Utica shale gas reservoir are documented in an attempt to indirectly characterize the intermediate zone. This study used structural data from outcrops, shallow observation well logs and deep shale gas well logs to propose a conceptual model of the natural fracture network. Shallow and deep fractures were categorized into three sets of steeply-dipping fractures and into a set of bedding-parallel fractures. Some lithological and structural controls on fracture distribution were identified. The regional geologic history and similarities between the shallow and deep fracture datasets allowed the extrapolation of the fracture network characterization to the intermediate zone. This study thus highlights the benefits of using both datasets simultaneously, while they are generally interpreted separately. Recommendations are also proposed for future environmental assessment studies in which the existence of preferential flow pathways and potential upward fluid migration toward shallow aquifers need to be identified.

Contributions to a shallow aquifer study by reprocessed seismic sections from petroleum exploration surveys, eastern Abu Dhabi, United Arab Emirates

USGS Publications Warehouse

Woodward, D.

1994-01-01

The US Geological Survey, in cooperation with the National Drilling Company of Abu Dhabi, is conducting a 4-year study of the fresh and slightly saline groundwater resources of the eastern Abu Dhabi Emirate. Most of this water occurs in a shallow aquifer, generally less than 150 m deep, in the Al Ain area. A critical part of the Al Ain area coincides with a former petroleum concession area where about 2780 km of vibroseis data were collected along 94 seismic lines during 1981-1983. Field methods, acquistion parameters, and section processing were originally designed to enhance reflections expected at depths ranging from 5000 to 6000 m, and subsurface features directly associated with the shallow aquifer system were deleted from the original seismic sections. The original field tapes from the vibroseis survey were reprocessed in an attempt to extract shallow subsurface information (depths less than 550 m) for investigating the shallow aquifer. A unique sequence of reproccessing parameters was established after reviewing the results from many experimental tests. Many enhancements to the resolution of shallow seismic reflections resulted from: (1) application of a 20-Hz, low-cut filter; (2) recomputation of static corrections to a datum nearer the land surface; (3) intensive velocity analyses; and (4) near-trace muting analyses. The number, resolution, and lateral continuity of shallow reflections were greatly enhanced on the reprocessed sections, as was the delineation of shallow, major faults. Reflections on a synthetic seismogram, created from a borehole drilled to a depth of 786 m on seismic line IQS-11, matcheddprecisely with shallow reflections on the reprocessed section. The 33 reprocessed sections were instrumental in preparing a map showing the major structural features that affect the shallow aquifer system. Analysis of the map provides a better understanding of the effect of these shallow features on the regional occurrence, movement, and quality of groundwater in the concession area. Results from this study demonstrate that original seismic field tapes collected for deep petroleum exploration can be reprocessed to explore for groundwater. ?? 1994.

Arsenic and selenium in soils and shallow ground water in the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas of the Garrison Diversion Unit, North Dakota

USGS Publications Warehouse

Berkas, W.R.; Komor, S.C.

1996-01-01

The Garrison Diversion Unit project was authorized as part of the Pick-Sloan Missouri River Basin program to divert water from Lake Sakakawea to irrigation areas in North Dakota. A special Garrison Commission was created to evaluate an environmental concern that return flow from the irrigation areas might contain metals in toxic concentrations. This report summarizes the results of detailed investigations of the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas. A total of 223 soil samples were collected from the irrigation areas and analyzed for elemental composition. Water extractions were done on 40 of the 223 soil samples using a 1:5 soil-to-water extraction method, and the solution from the extraction was analyzed for elemental composition. A total of 52 ground-water samples were collected and analyzed for inorganic constituents and organic carbon.Average arsenic concentrations in the entire soil column ranged from 1.0 milligram per kilogram in the Harvey Pumping irrigation area to 70 milligrams per kilogram in the New Rockford irrigation area. Average selenium concentrations ranged from less than 0.1 milligram per kilogram in the Turtle Lake, New Rockford, Harvey Pumping, and Lincoln Valley irrigation areas to 6.0 milligrams per kilogram in the Turtle Lake irrigation area. In the Turtle Lake irrigation area, average arsenic and selenium concentrations generally increased with depth through the topsoil, oxidized soil, and transition soil but decreased in the reduced soil at the bottom of the sampled horizons. Average arsenic concentrations in the New Rockford irrigation area follow the same pattern as in the Turtle Lake irrigation area, but selenium concentrations do not show a clear pattern of variation with depth. In the Harvey Pumping and Lincoln Valley irrigation areas, arsenic and selenium concentrations do not appear to vary systematically with depth. No correlation is shown between the concentrations in soils and soil extracts, indicating that, based on conditions of laboratory soil-water extraction experiments, trace-element concentrations in soils are not good predictors of trace-element concentrations in irrigation return flow. Arsenic concentrations in the aquifers ranged from less than 1 microgram per liter to 27 micrograms per liter. Arsenic concentrations generally were larger in the deep part of the aquifers underlying the Turtle Lake and New Rockford irrigation areas than in the shallow part of the aquifers. In the shallow part of the aquifers, where oxidizing conditions prevail, arsenic is strongly adsorbed to soil particles. In the deep part of the aquifers, where reducing conditions prevail, arsenic is more mobile.Selenium concentrations in the aquifers ranged from less than 1 microgram per liter to 4 micrograms per liter. Little difference existed between the selenium concentrations in the shallow part of the aquifers underlying the irrigation areas and the concentrations in the deep part of the aquifers.

Revised shallow and deep water-level and storage-volume changes in the Equus Beds Aquifer near Wichita, Kansas, predevelopment to 1993

USGS Publications Warehouse

Hansen, Cristi V.; Lanning-Rush, Jennifer L.; Ziegler, Andrew C.

2013-01-01

Beginning in the 1940s, the Wichita well field was developed in the Equus Beds aquifer in southwestern Harvey County and northwestern Sedgwick County to supply water to the city of Wichita. The decline of water levels in the aquifer was noted soon after the development of the Wichita well field began. Development of irrigation wells began in the 1960s. City and agricultural withdrawals led to substantial water-level declines. Water-level declines enhanced movement of brines from past oil and gas activities near Burrton, Kansas and enhanced movement of natural saline water from the Arkansas River into the well field area. Large chloride concentrations may limit use or require the treatment of water from the well field for irrigation or public supply. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program (ILWSP) to ensure an adequate water supply for the city through 2050 and as part of its effort to effectively manage the part of the Equus Beds aquifer it uses. ILWSP uses several strategies to do this including the Equus Beds Aquifer Storage and Recovery (ASR) project. The purpose of the ASR project is to store water in the aquifer for later recovery and to help protect the aquifer from encroachment of a known oilfield brine plume near Burrton and saline water from the Arkansas River. As part of Wichita’s ASR permits, Wichita is prohibited from artificially recharging water into the aquifer in a Basin Storage area (BSA) grid cell if water levels in that cell are above the January 1940 water levels or are less than 10 feet below land surface. The map previously used for this purpose did not provide an accurate representation of the shallow water table. The revised predevelopment water-level altitude map of the shallow part of the aquifer is presented in this report. The city of Wichita’s ASR permits specify that the January 1993 water-level altitudes will be used as a lower baseline for regulating the withdrawal of artificial rechage credits from the Equus Beds aquifer by the city of Wichita. The 1993 water levels correspond to the lowest recorded levels and largest storage declines since 1940. Revised and new water-level maps of shallow and deep layers were developed to better represent the general condition of the aquifer. Only static water levels were used to better represent the general condition of the aquifer and comply with Wichita’s ASR permits. To ensure adequate data density, the January 1993 period was expanded to October 1992 through February 1993. Static 1993 water levels from the deep aquifer layer of the Equus Beds aquifer possibly could be used as the lower baseline for regulatory purposes. Previously, maps of water-level changes used to estimate the storage-volume changes included a combination of static (unaffected by pumping or nearby pumping) and stressed (affected by pumping or nearby pumping) water levels from wells. Some of these wells were open to the shallow aquifer layer and some were open to the deep aquifer layer of the Equus Beds aquifer. In this report, only static water levels in the shallow aquifer layer were used to determine storage-volume changes. The effects on average water-level and storage-volume change from the use of mixed, stressed water levels and a specific yield of 0.20 were compared to the use of static water levels in the shallow aquifer and a specific yield of 0.15. This comparison indicates that the change in specific yield causes storage-volume changes to decrease about 25 percent, whereas the use of static water levels in the shallow aquifer layer causes an increase of less than 4 percent. Use of a specific yield of 0.15 will result in substantial decreases in the amount of storage-volume change compared to those reported previously that were calculated using a specific yield of 0.20. Based on these revised water-level maps and computations, the overall decline and change in storage from predevelopment to 1993 represented a loss in storage of about 6 percent (-202,000 acre-feet) of the overall storage volume within the newly defined study area.

Shallow Aquifer Vulnerability From Subsurface Fluid Injection at a Proposed Shale Gas Hydraulic Fracturing Site

NASA Astrophysics Data System (ADS)

Wilson, M. P.; Worrall, F.; Davies, R. J.; Hart, A.

2017-11-01

Groundwater flow resulting from a proposed hydraulic fracturing (fracking) operation was numerically modeled using 91 scenarios. Scenarios were chosen to be a combination of hydrogeological factors that a priori would control the long-term migration of fracking fluids to the shallow subsurface. These factors were induced fracture extent, cross-basin groundwater flow, deep low hydraulic conductivity strata, deep high hydraulic conductivity strata, fault hydraulic conductivity, and overpressure. The study considered the Bowland Basin, northwest England, with fracking of the Bowland Shale at ˜2,000 m depth and the shallow aquifer being the Sherwood Sandstone at ˜300-500 m depth. Of the 91 scenarios, 73 scenarios resulted in tracked particles not reaching the shallow aquifer within 10,000 years and 18 resulted in travel times less than 10,000 years. Four factors proved to have a statistically significant impact on reducing travel time to the aquifer: increased induced fracture extent, absence of deep high hydraulic conductivity strata, relatively low fault hydraulic conductivity, and magnitude of overpressure. Modeling suggests that high hydraulic conductivity formations can be more effective barriers to vertical flow than low hydraulic conductivity formations. Furthermore, low hydraulic conductivity faults can result in subsurface pressure compartmentalization, reducing horizontal groundwater flow, and encouraging vertical fluid migration. The modeled worst-case scenario, using unlikely geology and induced fracture lengths, maximum values for strata hydraulic conductivity and with conservative tracer behavior had a particle travel time of 130 years to the base of the shallow aquifer. This study has identified hydrogeological factors which lead to aquifer vulnerability from shale exploitation.

Advection of surface-derived organic carbon fuels microbial reduction in Bangladesh groundwater

PubMed Central

Mailloux, Brian J.; Trembath-Reichert, Elizabeth; Cheung, Jennifer; Watson, Marlena; Stute, Martin; Freyer, Greg A.; Ferguson, Andrew S.; Ahmed, Kazi Matin; Alam, Md. Jahangir; Buchholz, Bruce A.; Thomas, James; Layton, Alice C.; Zheng, Yan; Bostick, Benjamin C.; van Geen, Alexander

2013-01-01

Chronic exposure to arsenic (As) by drinking shallow groundwater causes widespread disease in Bangladesh and neighboring countries. The release of As naturally present in sediment to groundwater has been linked to the reductive dissolution of iron oxides coupled to the microbial respiration of organic carbon (OC). The source of OC driving this microbial reduction—carbon deposited with the sediments or exogenous carbon transported by groundwater—is still debated despite its importance in regulating aquifer redox status and groundwater As levels. Here, we used the radiocarbon (14C) signature of microbial DNA isolated from groundwater samples to determine the relative importance of surface and sediment-derived OC. Three DNA samples collected from the shallow, high-As aquifer and one sample from the underlying, low-As aquifer were consistently younger than the total sediment carbon, by as much as several thousand years. This difference and the dominance of heterotrophic microorganisms implies that younger, surface-derived OC is advected within the aquifer, albeit more slowly than groundwater, and represents a critical pool of OC for aquifer microbial communities. The vertical profile shows that downward transport of dissolved OC is occurring on anthropogenic timescales, but bomb 14C-labeled dissolved OC has not yet accumulated in DNA and is not fueling reduction. These results indicate that advected OC controls aquifer redox status and confirm that As release is a natural process that predates human perturbations to groundwater flow. Anthropogenic perturbations, however, could affect groundwater redox conditions and As levels in the future. PMID:23487743

Field demonstration of CO2 leakage detection and potential impacts on groundwater quality at Brackenridge Field Laboratory

NASA Astrophysics Data System (ADS)

Zou, Y.; Yang, C.; Guzman, N.; Delgado, J.; Mickler, P. J.; Horvoka, S.; Trevino, R.

2015-12-01

One concern related to GCS is possible risk of unintended CO2 leakage from the storage formations into overlying potable aquifers on underground sources of drinking water (USDW). Here we present a series of field tests conducted in an alluvial aquifer which is on a river terrace at The University of Texas Brackenridge Field Laboratory. Several shallow groundwater wells were completed to the limestone bedrock at a depth of 6 m and screened in the lower 3 m. Core sediments recovered from the shallow aquifer show that the sediments vary in grain size from clay-rich layers to coarse sandy gravels. Two main types of field tests were conducted at the BFL: single- (or double-) well push-pull test and pulse-like CO2 release test. A single- (or double-) well push-pull test includes three phases: the injection phase, the resting phase and pulling phase. During the injection phase, groundwater pumped from the shallow aquifer was stored in a tank, equilibrated with CO2 gasand then injected into the shallow aquifer to mimic CO2 leakage. During the resting phase, the groundwater charged with CO2 reacted with minerals in the aquifer sediments. During the pulling phase, groundwater was pumped from the injection well and groundwater samples were collected continuously for groundwater chemistry analysis. In such tests, large volume of groundwater which was charged with CO2 can be injected into the shallow aquifer and thus maximize contact of groundwater charged with CO2. Different than a single- (or double-) well push-pull test, a pulse-like CO2 release test for validating chemical sensors for CO2 leakage detection involves a CO2 release phase that CO2 gas was directly bubbled into the testing well and a post monitoring phase that groundwater chemistry was continuously monitored through sensors and/or grounder sampling. Results of the single- (or double-) well push-pull tests conducted in the shallow aquifer shows that the unintended CO2 leakage could lead to dissolution of carbonates and some silicates and mobilization of heavy metals from the aquifer sediments to groundwater, however, such mobilization posed no risks on groundwater quality at this site. The pulse-like tests have demonstrated it is plausible to use chemical sensors for CO2 leakage detection in groundwater.

Hydrogeology of a Biosolids-Application Site Near Deer Trail, Colorado, 1993-99

USGS Publications Warehouse

Yager, Tracy J.B.; Arnold, L. Rick

2003-01-01

This report presents hydrogeology data and interpretations resulting from two studies related to biosolids applications at the Metro Wastewater Reclamation District property near Deer Trail, Colorado, done by the U.S. Geological Survey in cooperation with the Metro Wastewater Reclamation District: (1) a 1993-99 study of hydrology and water quality for the Metro Wastewater Reclamation District central property and (2) a 1999 study of regional bedrock-aquifer structure and local ground-water recharge. Biosolids were applied as a fertilizer during late 1993 through 1999. The 1993 Metro Wastewater Reclamation District property boundary constitutes the study area, but hydrogeologic structure maps for a much larger area are included in the report. The study area is located on the eastern margin of the Denver Basin, a bowl-shaped sequence of sedimentary rocks. The uppermost bedrock formations in the vicinity of the study area consist of the Pierre Shale, the Fox Hills Sandstone, and the Laramie Formation, parts of which comprise the Laramie-Fox Hills hydrostratigraphic unit and thus, where saturated, the Laramie-Fox Hills aquifer. In the vicinity of the study area, the Laramie-Fox Hills hydrostratigraphic unit dips gently to the northwest, crops out, and is partially eroded. The Laramie-Fox Hills aquifer is either absent or not fully saturated within the Metro Wastewater Reclamation District properties, although this aquifer is the principal aquifer used for domestic supply in the vicinity of the study area. Yield was small from two deep monitoring wells in the Laramie-Fox Hills aquifer within the study area. Depth to water in these wells was about 110 and 150 feet below land surface, and monthly water levels fluctuated 0.5 foot or less. Alluvial aquifers also are present in the unconsolidated sand and loess deposits in the valleys of the study area. Interactions of the deeper parts of the Laramie-Fox Hills aquifer with shallow ground water in the study area include a general close hydraulic connection between alluvial and bedrock aquifers, recharge of the Cottonwood Creek and much of the Muddy Creek alluvial aquifers by the bedrock aquifer, and possible recharge of the bedrock aquifer by a Rattlesnake Creek tributary. Some areas of shallow ground water were recharged by infiltration from rain or ponds, but other areas likely were recharged by other ground water. Data for shallow ground water indicate that ground-water recharge takes less than a day at some sites to about 40 years at another site. Depth to shallow ground water in the study area ranged from about 2 feet to about 37 feet below land surface. Shallow ground-water levels likely were affected by evapotranspiration. Ground water is present in shallow parts of the bedrock aquifer or in alluvial aquifers in four drainage basins: Badger Creek, Cottonwood Creek, Muddy Creek, and Rattlesnake Creek. These drainage basins generally contained only ephemeral streams, which flow only after intense rain.

ENVIRONMENTAL FACTORS INFLUENCING METHANOGENESIS IN A SHALLOW ANOXIC AQUIFER: A FIELD AND LABORATORY STUDY

EPA Science Inventory

The environmental factors influencing methanogenesis in a shallow anoxic aquifer were probed in a combined field and laboratory study. Field data collected over a year revealed that in situ rates of methane production were depressed in winter and elevated in summer. Over the same...

Effective detection of CO 2 leakage: a comparison of groundwater sampling and pressure monitoring

DOE PAGES

Keating, Elizabeth; Dai, Zhenxue; Dempsey, David; ...

2014-12-31

Shallow aquifer monitoring is likely to be a required aspect to any geologic CO 2 sequestration operation. Collecting groundwater samples and analyzing for geochemical parameters such as pH, alkalinity, total dissolved carbon, and trace metals has been suggested by a number of authors as a possible strategy to detect CO 2 leakage. The effectiveness of this approach, however, will depend on the hydrodynamics of the leak-induced CO 2 plume and the spatial distribution of the monitoring wells relative to the origin of the leak. To our knowledge, the expected effectiveness of groundwater sampling to detect CO 2 leakage has notmore » yet been quantitatively assessed. In this study we query hundreds of simulations developed for the National Risk Assessment Project (US DOE) to estimate risks to drinking water resources associated with CO 2 leaks. The ensemble of simulations represent transient, 3-D multi-phase reactive transport of CO 2 and brine leaked from a sequestration reservoir, via a leaky wellbore, into an unconfined aquifer. Key characteristics of the aquifer, including thickness, mean permeability, background hydraulic gradient, and geostatistical measures of aquifer heterogeneity, were all considered uncertain parameters. Complex temporally-varying CO 2 and brine leak rate scenarios were simulated using a heuristic scheme with ten uncertain parameters. The simulations collectively predict the spatial and temporal evolution of CO 2 and brine plumes over 200 years in a shallow aquifer under a wide range of leakage scenarios and aquifer characteristics. Using spatial data from an existing network of shallow drinking water wells in the Edwards Aquifer, TX, as one illustrative example, we calculated the likelihood of leakage detection by groundwater sampling. In this monitoring example, there are 128 wells available for sampling, with a density of about 2.6 wells per square kilometer. If the location of the leak is unknown a priori, a reasonable assumption in many cases, we found that the leak would be detected in at least one of the monitoring wells in less than 10% of the scenarios considered. This is because plume sizes are relatively small, and so the probability of detection decreases rapidly with distance from the leakage point. For example, 400m away from the leakage point there is less than 20% chance of detection. We then compared the effectiveness of groundwater quality sampling to shallow aquifer and/or reservoir pressure monitoring. For the Edwards Aquifer example, pressure monitoring in the same monitoring well network was found to be even less effective that groundwater quality monitoring. This is presumably due to the unconfined conditions and relatively high permeability, so pressure perturbations quickly dissipate. Although specific results may differ from site to site, this type of analysis should be useful to site operators and regulators when selecting leak detection strategies. Given the spatial characteristics of a proposed monitoring well network, probabilities of leakage detection can be rapidly calculated using this methodology. Although conditions such as these may not be favorable for leakage detection in shallow aquifers, leakage detection could be much more successful in the injection reservoir. We demonstrate proof-of-concept for this hypothesis, presenting a simulation where there is measurable pressure change at the injection well due to overpressurization, fault rupture, and consequent leakage up the fault into intermediate and shallow aquifers. The size of the detectible pressure change footprint is much larger in the reservoir than in either of the overlying aquifers. Further exploration of the range of conditions for which this technique would be successful is the topic of current study.« less

Hydrologic conditions at the Idaho National Engineering Laboratory, Idaho, emphasis; 1974-1978

USGS Publications Warehouse

Barraclough, Jack T.; Lewis, Barney D.; Jensen, Rodger G.

1981-01-01

Aqueous chemical and radioactive wastes have been discharged to shallow ponds and to shallow or deep wells on the Idaho National Engineering Laboratory (INEL) since 1952 and has affected the quality of the ground water in the underlying Snake River Plain aquifer. Ongoing studies conducted from 1974 through 1978 have shown the perpetuation of a perched ground-water zone in the basalt underlying the waste disposal ponds at the INEL 's Test Reactor Area and of several waste plumes in the regional aquifer created by deep well disposal at the Idaho Chemical Processing Plant (ICPP). The perched zone contains tritium, chromium-51, cobalt-60, strontium-90, and several nonradioactive chemicals. Tritium has formed the largest waste plume south of the ICPP, and accounts for 95 percent of the total radioacticity disposed of through the ICPP disposal well. Waste plumes with similar configurations and flowpaths contain sodium, chloride, and nitrate. Strontium-90, iodine-129, and cesium-137 are also discharged through the well but they are sorbed from solution as they move through the aquifer or are discharged in very small quantities. Strontium-90 and iodine-129 have formed small waste plumes and cesium-137 is not detectable in ground-water samples. Radionuclide plume size and concentrations therein are controlled by aquifer flow conditions, the quantity discharged, radioactive decay, sorption, dilution by dispersion, and perhaps other chemical reactions. Chemical wastes are subject to the same processes except for radioactive decay. (USGS)

Simulation of an urban ground-water-flow system in the Menomonee Valley, Milwaukee, Wisconsin using analytic element modeling

USGS Publications Warehouse

Dunning, C.P.; Feinstein, D.T.

2004-01-01

A single-layer, steady-state analytic element model was constructed to simulate shallow ground-water flow in the Menomonee Valley, an old industrial center southwest of downtown Milwaukee, Wisconsin. Project objectives were to develop an understanding of the shallow ground-water flow system and identify primary receptors of recharge to the valley. The analytic element model simulates flow in a 18.3 m (60 ft) thick layer of estuarine and alluvial sediments and man-made fill that comprises the shallow aquifer across the valley. The thin, laterally extensive nature of the shallow aquifer suggests horizontal-flow predominates, thus the system can appropriately be modeled with the Dupuit-Forchheimer approximation in an analytic element model. The model was calibrated to the measured baseflow increase between two USGS gages on the Menomonee River, 90 head measurements taken in and around the valley during December 1999, and vertical gradients measured at five locations under the river and estuary in the valley. Recent construction of the Milwaukee Metropolitan Sewer District Inline Storage System (ISS) in the Silurian dolomite under the Menomonee Valley has locally lowered heads in the dolomite appreciably, below levels caused by historic pumping. The ISS is a regional hydraulic sink which removes water from the bedrock even during dry weather. The potential effect on flow directions in the shallow aquifer of dry-weather infiltration to the ISS was evaluated by adjusting the resistance of the line-sink strings representing the ISS in the model to allow infiltration from 0 to 100% of the reported 9,500 m3/d. The best fit to calibration targets was found between 60% (5,700 m3/d) and 80% (7,600 m3/d) of the reported dry-weather infiltration. At 60% infiltration, 65% of the recharge falling on the valley terminates at the ISS and 35% at the Menomonee River and estuary. At 80% infiltration, 73% of the recharge terminates at the ISS, and 27% at the river and estuary. Model simulations suggest that the ISS has an greater influence on the shallow ground-water flow in the eastern half of valley as compared to the western half. Preliminary three-dimensional simulations using the numerical MODFLOW code show good agreement with the single-layer simulation and supports its use in evaluating the shallow system. Copyright ASCE 2004.

Ground-water flow and saline water in the shallow aquifer system of the southern watersheds of Virginia Beach, Virginia

USGS Publications Warehouse

Smith, Barry S.

2003-01-01

Population and tourism continues to grow in Virginia Beach, Virginia, but the supply of freshwater is limited. A pipeline from Lake Gaston supplies water for northern Virginia Beach, but ground water is widely used to water lawns in the north, and most southern areas of the city rely solely on ground water. Water from depths greater than 60 meters generally is too saline to drink. Concentrations of chloride, iron, and manganese exceed drinking-water standards in some areas. The U.S. Geological Survey, in cooperation with the city of Virginia Beach, Department of Public Utilities, investigated the shallow aquifer system of the southern watersheds to determine the distribution of fresh ground water, its potential uses, and its susceptibility to contamination. Aquifers and confining units of the southern watersheds were delineated and chloride concentrations in the aquifers and confining units were contoured. A ground-water-flow and solute-transport model of the shallow aquifer system reached steady state with regard to measured chloride concentrations after 31,550 years of freshwater recharge. Model simulations indicate that if freshwater is found in permeable sediments of the Yorktown-Eastover aquifer, such a well field could supply freshwater, possibly for decades, but eventually the water would become more saline. The rate of saline-water intrusion toward the well field would depend on the rate of pumping, aquifer properties, and on the proximity of the well field to saline water sources. The steady-state, ground-water-flow model also was used to simulate drawdowns around two hypothetical well fields and drawdowns around two hypothetical open-pit mines. The chloride concentrations simulated in the model did not approximate the measured concentrations for some wells, indicating sites where local hydrogeologic units or unit properties do not conform to the simple hydrogeology of the model. The Columbia aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer compose the hydrogeologic units of the shallow aquifer system of Virginia Beach. The Columbia and Yorktown-Eastover aquifers are poorly confined throughout most of the southern watersheds of Virginia Beach. The freshwater-to-saline-water distribution probably is in a dynamic equilibrium throughout most of the shallow aquifer system. Freshwater flows continually down and away from the center of the higher altitudes to mix with saline water from the tidal rivers, bays, salt marshes, and the Atlantic Ocean. Fresh ground water from the Columbia aquifer also leaks down through the Yorktown confining unit into the upper half of the Yorktown-Eastover aquifer and flows within the Yorktown-Eastover above saline water in the lower half of the aquifer. Ground-water recharge is minimal in much of the southern watersheds because the land surface generally is low and flat.

Isotope investigation on groundwater recharge and dynamics in shallow and deep alluvial aquifers of southwest Punjab.

PubMed

Keesari, Tirumalesh; Sharma, Diana A; Rishi, Madhuri S; Pant, Diksha; Mohokar, Hemant V; Jaryal, Ajay Kumar; Sinha, U K

2017-11-01

Groundwater samples collected from the alluvial aquifers of southwest Punjab, both shallow and deep zones were measured for environmental tritium ( 3 H) and stable isotopes ( 2 H and 18 O) to evaluate the source of recharge and aquifer dynamics. The shallow groundwater shows wide variation in isotopic signature (δ 18 O: -11.3 to -5.0‰) reflecting multiple sources of recharge. The average isotopic signature of shallow groundwaters (δ 18 O: -6.73 ± 1.03‰) is similar to that of local precipitation (-6.98 ± 1.66‰) indicating local precipitation contributes to a large extent compared to other sources. Other sources have isotopically distinct signatures due to either high altitude recharge (canal sources) or evaporative enrichment (irrigation return flow). Deep groundwater shows relatively depleted isotopic signature (δ 18 O: -8.6‰) and doesn't show any evaporation effect as compared to shallow zone indicating recharge from precipitation occurring at relatively higher altitudes. Environmental tritium indicates that both shallow ( 3 H: 5 - 10 T.U.) and deeper zone ( 3 H: 1.5 - 2.5 T.U.) groundwaters are modern. In general the inter-aquifer connections seem to be unlikely except a few places. Environmental isotope data suggests that shallow groundwater is dynamic, local and prone to changes in land use patterns while deep zone water is derived from distant sources, less dynamic and not impacted by surface manifestations. A conceptual groundwater flow diagram is presented. Copyright © 2017 Elsevier Ltd. All rights reserved.

Impacts of CO2 Leakage on a Shallow Aquifer System: Laboratory Column Experiments and Reactive Transport Modeling

NASA Astrophysics Data System (ADS)

Ha, Jong Heon; Jeen, Sung-Wook

2017-04-01

Groundwater quality change due to the leakage of CO2 in a shallow aquifer system is an important aspect of environmental impact assessment in a carbon dioxide capture and storage (CCS) site. This study evaluated geochemical changes in a shallow aquifer system resulting from leakage of CO2 through laboratory column experiments and reactive transport modeling. In the column experiments, two columns were set up and filled with the sediment from the Environmental Impact Test (EIT) facility of the Korea CO2 Storage Environmental Management (K-COSEM) Research Center. Groundwater, also collected form the EIT site, was purged with CO2 or Ar gases, and was pumped into the columns with the pumping rates of 200-1000 mL day-1 (0.124-0.62 m day-1). Profile and time-series effluent samplings were conducted to evaluate the spatial and temporal geochemical changes in the aquifer materials upon contact with CO2. The experimental results showed that after injecting CO2-purged groundwater, the pH was decreased, and alkalinity, electrical conductivity (EC) and concentrations of major cations were increased. The spatial and temporal geochemical changes from the column experiments indicate that dissolution of aquifer materials in contact with dissolved CO2 is the major contributor to the changes in groundwater geochemistry. The reactive transport modeling has been conducted to reproduce these geochemical changes in the aquifer system by incorporating dissolution of the dominant aluminosilicate minerals in the aquifer such as microcline, anorthite, albite, and biotite. This study suggests that pH, alkalinity, EC and concentrations of major cations are important monitoring parameters for detecting CO2 leakage in a shallow groundwater aquifer system.

Contaminant attenuation by shallow aquifer systems under steady flow

NASA Astrophysics Data System (ADS)

Soltani, S. S.; Cvetkovic, V.

2017-10-01

We present a framework for analyzing advection-dominated solute transport and transformation in aquifer systems of boreal catchments that are typically shallow and rest on crystalline bedrock. A methodology is presented for estimating tracer discharge based on particle trajectories from recharge to discharge locations and computing their first passage times assuming that the flow pattern is approximately steady-state. Transformation processes can be included by solving one-dimensional reactive transport with randomized water travel time as the independent variable; the distribution of the travel times incorporates morphological dispersion (due to catchment geometry/topography) as well as macro-dispersion (due to heterogeneity of underlying hydraulic properties). The implementation of the framework is illustrated for the well characterized coastal catchment of Forsmark (Sweden). We find that macro-dispersion has a notable effect on attenuation even though the morphological dispersion is significantly larger. Preferential flow on the catchment scale is found to be considerable with only 5% of the Eulerian velocities contributing to transport over the simulation period of 375 years. Natural attenuation is illustrated as a simple (linear decay) transformation process. Simulated natural attenuation can be estimated analytically reasonably well by using basic hydrological and structural information, the latter being the pathway length distribution and average aquifer depth to the bedrock.

GEOCHEMICAL MODELING OF ARSENIC SPECIATION AND MOBILIZATION: IMPLICATIONS FOR BIOREMEDIATION

EPA Science Inventory

Geochemical modeling techniques were used to examine the biogeochemical linkages between Fe, S, and As in shallow alluvial aquifers. We modeled: 1) the adsorption and desorption of As on the surface of hydrous ferric oxides (HFO’s) in stream beds under aerobic conditions; 2) red...

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, 1996-2006

USGS Publications Warehouse

Musgrove, MaryLynn; Fahlquist, Lynne; Houston, Natalie A.; Lindgren, Richard J.; Ging, Patricia B.

2010-01-01

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Potential for intrinsic bioremediation of a DNT-contaminated aquifer

USGS Publications Warehouse

Bradley, P.M.; Chapelle, F.H.; Landmeyer, J.E.; Schumacher, J.G.

1997-01-01

Microorganisms indigenous to a shallow aquifer, which underlies an explosives-contaminated site, mineralized 28% of [U-ring-14C] 2,4–dinitrotoluene to 14CO2 within 28 days under aerobic conditions. Approximately 20% of added 2,4–dinitrotoluene remained undegraded at the end of the incubation while approximately 22% and 6% were transformed to 4–amino-2–nitrotoluene and 2–amino-4–nitrotoluene, respectively. In aquifer microcosms containing 2,6–dinitrotoluene, approximately 67% of the substrate remained undegraded and approximately 14% was transformed to 2–amino-6–nitrotoluene. The radiolabeled study indicated that about 8% of the 2,6–dinotrotoluene was mineralized to CO2. The demonstrated degradation and subsequent mineralization of dinitrotoluene compounds by aquifer microorganisms are consistent with the decline in dissolved dinitrotoluene concentrations observed along the general ground-water flowpath at the site. The results indicate that intrinsic bioremediation may be a viable alternative for remediating contaminated ground water at this site.

Seasonal changes in ground-water levels in the shallow aquifer near Hagerman and the Pecos River, Chaves County, New Mexico

USGS Publications Warehouse

Garn, H.S.

1988-01-01

The Pecos River near Hagerman in Chaves County, New Mexico, historically has been a gaining stream. In 1938, the slope of the water table in the shallow alluvial aquifer near Hagerman was toward the Pecos River. By 1950, a large water-table depression had formed in the alluvial aquifer southwest of Hagerman. Continued enlargement of this depression could reverse the direction of groundwater flow to the Pecos River. Water levels were measured during 1981-85 in wells along a section extending from the Pecos River to a point within the depression. Although the water-table depression has not caused a perennial change in direction of groundwater flow, it has caused a seasonal reversal in the slope of the water table between the river and the depression during the growing season when pumpage from the shallow aquifer is the greatest. (USGS)

Hydrogeologic framework, hydrology, and water quality in the Pearce Creek Dredge Material Containment Area and vicinity, Cecil County, Maryland, 2010-11

USGS Publications Warehouse

Dieter, Cheryl A.; Koterba, Michael T.; Zapecza, Otto S.; Walker, Charles W.; Rice, Donald E.

2013-01-01

In 2009, to support an evaluation of the feasibility of reopening the Pearce Creek Dredge Material Containment Area (DMCA) in Cecil County, Maryland, for dredge-spoil disposal, the U.S. Geological Survey (USGS) began to implement a comprehensive study designed to improve the understanding of the hydrogeologic framework, hydrology, and water quality of shallow aquifers underlying the DMCA and adjacent communities, to determine whether or not the DMCA affected groundwater quality, and to assess whether or not groundwater samples contained chemical constituents at levels greater than maximum allowable or recommended levels established by the U.S. Environmental Protection Agency Safe Drinking Water Act. The study, conducted in 2010-11 by USGS in cooperation with the U.S. Army Corps of Engineers, included installation of observation wells in areas where data gaps led earlier studies to be inconclusive. The data from new wells and existing monitoring locations were interpreted and show the DMCA influences the groundwater flow and quality. Groundwater flow in the two primary aquifers used for local supplies-the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone)-is radially outward from the DMCA toward discharge areas, including West View Shores, the Elk River, and Pearce Creek Lake. In addition to horizontal flow outward from the DMCA, vertical gradients primarily are downward in most of the study area, and upward near the Elk River on the north side of the DMCA property, and the western part of West View Shores. Integrating groundwater geochemistry data in the analysis, the influence of the DMCA is not only a source of elevated concentrations of dissolved solids but also a geochemical driver of redox processes that enhances the mobilization and transport of redox-sensitive metals and nutrients. Groundwater affected by the DMCA is in the Magothy aquifer and upper Patapsco aquifer (shallow water-bearing zone). Based on minimal data, the water quality in the upper Patapsco aquifer deep water-bearing zone does not seem to have been impacted by the DMCA.

VULNERABILITY OF LOW-ARSENIC AQUIFERS TO MUNICIPAL PUMPING IN BANGLADESH

PubMed Central

Knappett, P. S. K.; Mailloux, B. J.; Choudhury, I.; Khan, M. R.; Michael, H. A.; Barua, S.; Mondal, D. R.; Steckler, M. S.; Akhter, S. H.; Ahmed, K. M.; Bostick, B.; Harvey, C. F.; Shamsudduha, M.; Shuai, P.; Mihajlov, I.; Mozumder, R.; van Geen, A.

2017-01-01

Sandy aquifers deposited >12,000 years ago, some as shallow as 30 m, have provided a reliable supply of low-arsenic (As) drinking water in rural Bangladesh. This study concerns the potential risk of contaminating these aquifers in areas surrounding the city of Dhaka where hydraulic heads in aquifers >150 m deep have dropped by 70 m in a few decades due to municipal pumping. Water levels measured continuously from 2012 to 2014 in 12 deep (>150m), 3 intermediate (90–150 m) and 6 shallow (<90 m) community wells, 1 shallow private well, and 1 river piezometer show that the resulting drawdown cone extends 15–35 km east of Dhaka. Water levels in 4 low-As community wells within the 62–147 m depth range closest to Dhaka were inaccessible by suction for up to a third of the year. Lateral hydraulic gradients in the deep aquifer system ranged from 1.7×10−4 to 3.7×10−4 indicating flow towards Dhaka throughout 2012–2014. Vertical recharge on the edge of the drawdown cone was estimated at 0.21±0.06 m/yr. The data suggest that continued municipal pumping in Dhaka could eventually contaminate some relatively shallow community wells. PMID:28966395

Appraisal of salinity and fluoride in a semi-arid region of India using statistical and multivariate techniques.

PubMed

Mor, Suman; Singh, Surender; Yadav, Poonam; Rani, Versha; Rani, Pushpa; Sheoran, Monika; Singh, Gurmeet; Ravindra, Khaiwal

2009-12-01

Various physico-chemical parameters, including fluoride (F(-)), were analyzed to understand the hydro-geochemistry of an aquifer in a semi-arid region of India. Furthermore, the quality of the shallow and deep aquifer (using tube well and hand pumps) was also investigated for their best ecological use including drinking, domestic, agricultural and other activities. Different multivariate techniques were applied to understand the groundwater chemistry of the aquifer. Findings of the correlation matrix were strengthened by the factor analysis, and this shows that salinity is mainly caused by magnesium salts as compared to calcium salts in the aquifer. The problem of salinization seems mainly compounded by the contamination of the shallow aquifers by the recharging water. High factor loading of total alkalinity and bicarbonates indicates that total alkalinity was mainly due to carbonates and bicarbonates of sodium. The concentration of F(-) was found more in the deep aquifer than the shallow aquifer. Further, only a few groundwater samples lie below the permissible limit of F(-), and this indicates a risk of dental caries in the populace of the study area. The present study indicates that regular monitoring of groundwater is an important step to avoid human health risks and to assess its quality for various ecological purposes.

Could arsenic mitigation lead to increased diarrheal disease in Bangladesh?

NASA Astrophysics Data System (ADS)

van Geen, A.; Ahmed, K.; Akita, Y.; Alam, M.; Culligan, P.; Feighery, J.; Ferguson, A. S.; Emch, M.; Escamilla, V.; Knappett, P.; Layton, A.; Mailloux, B. J.; McKay, L. D.; Mey, J. L.; Serre, M. L.; Streatfield, P. K.; Wu, J.; Yunus, M.

2010-12-01

Could arsenic mitigation lead to increased diarrheal disease in Bangladesh? The health risks of As exposure caused by the installation of millions of shallow tubewells in the Bengal Basin are widely known but fecal contamination of groundwater in this densely populated region with poor sanitation has rarely been studied systematically. In order to examine the degree of microbial contamination of groundwater and, specifically, determine whether arsenic mitigation by switching between shallow wells might affect exposure to microbial pathogens, 125 tubewells ranging between 20 and 120 ft in depth and spanning a wide range of As concentrations were monitored monthly for the fecal indicator E. coli across 7 villages of Matlab and Araihazar, Bangladesh. Overall, the fraction of shallow wells with detectable E. coli ranged from 20% during the dry season to 70% during the monsoon. The linear relation observed between the frequency of E. coli detection in well water during the monsoon and population residing within 25 m of a well (p<0.05) indicates a link between aquifer contamination and population density that might be explained by variations in overlying fecal source strength, coupled with rapid infiltration of surface contaminants into the aquifer. Neither well depth within the 20-120 ft range nor the presence of a concrete platform at the surface had a detectable impact on E. coli levels in well water. PCR analysis of groundwater from 50 wells where E. coli was detected (i.e. >1 CFU/100 mL) indicates that 40% of the wells contained a known pathogen such as Shigella, rotavirus or pathogenic E. coli. Detection of E. coli was on average higher by two-thirds in shallow wells with up to 10 ug/L As compared to shallow wells with >50 ug/L As. This raises the possibility that the most widely applied form of As mitigation, switching to a neighboring household’s low-As well, could result in increased exposure to microbial pathogens. The inverse relation between E. coli detection frequency and groundwater As may reflect the shorter hydraulic travel time to shallow low-As aquifers compared to high-As aquifers that has been reported previously. The relevance to human health of microbial contaminants contained in groundwater in South Asia is supported by significantly higher rates of diarrheal disease in children under 5 recorded in 2000-06 in Matlab for households using a shallow low-As well compared to households using a shallow high-As well, controlling for the effects of population density, socio-economic status, and flood control.

Hydrogeology and geochemistry of aquifers underlying the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California

USGS Publications Warehouse

Izbicki, John A.; Borchers, James W.; Leighton, David A.; Kulongoski, Justin T.; Fields, Latoya; Galloway, Devin L.; Michel, Robert L.

2003-01-01

The East Bay Plain, on the densely populated eastern shore of San Francisco Bay, contains an upper aquifer system to depths of 250 feet below land surface and an underlying lower aquifer system to depths of more than 650 feet. Injection and recovery of imported water has been proposed for deep aquifers at two sites within the lower aquifer system. Successful operation requires that the injected water be isolated from surface sources of poor-quality water during storage and recovery. Hydraulic, geochemical, and isotopic data were used to evaluate the isolation of deeper aquifers. Ground-water responses to tidal changes in the Bay suggest that thick clay layers present within these deposits effectively isolate the deeper aquifers in the northern part of the study area from overlying surficial deposits. These data also suggest that the areal extent of the shallow and deep aquifers beneath the Bay may be limited in the northern part of the study area. Despite its apparent hydraulic isolation, the lower aquifer system may be connected to the overlying upper aquifer system through the corroded and failed casings of abandoned wells. Water-level measurements in observation wells and downward flow measured in selected wells during nonpumped conditions suggest that water may flow through wells from the upper aquifer system into the lower aquifer system during nonpumped conditions. The chemistry of water from wells in the East Bay Plain ranges from fresh to saline; salinity is greater than seawater in shallow estuarine deposits near the Bay. Water from wells completed in the lower aquifer system has higher pH, higher sodium, chloride, and manganese concentrations, and lower calcium concentrations and alkalinity than does water from wells completed in the overlying upper aquifer system. Ground-water recharge temperatures derived from noble-gas data indicate that highly focused recharge processes from infiltration of winter streamflow and more diffuse recharge processes from infiltration of precipitation occur within the study area. However, recharge of imported water from leaking water-supply pipes, believed by previous investigators to be a large source of ground-water recharge, was not supported on the basis of oxygen-18 and deuterium data collected as part of this study. Based on tritium/helium-3 ages, most water in the upper aquifer system is relatively young and was recharged after 1952; however, water in the lower aquifer system is older and does not contain detectable tritium. Carbon-14 ages interpreted for water from wells in the lower aquifer system and underlying partly consolidated rocks range from 500 to more than 20,000 years before present. The greatest ages were in water from wells completed in the partly consolidated deposits that underlie the northern part of the study area. Ground water from wells in the lower aquifer system near the proposed Bayside injection/recovery site was recharged about 9,400 years before present and appears to be isolated from surface sources of recharge and ground-water contamination.

Redox controls on methane formation, migration and fate in shallow aquifers

NASA Astrophysics Data System (ADS)

Humez, Pauline; Mayer, Bernhard; Nightingale, Michael; Becker, Veith; Kingston, Andrew; Taylor, Stephen; Bayegnak, Guy; Millot, Romain; Kloppmann, Wolfram

2016-07-01

Development of unconventional energy resources such as shale gas and coalbed methane has generated some public concern with regard to the protection of groundwater and surface water resources from leakage of stray gas from the deep subsurface. In terms of environmental impact to and risk assessment of shallow groundwater resources, the ultimate challenge is to distinguish (a) natural in situ production of biogenic methane, (b) biogenic or thermogenic methane migration into shallow aquifers due to natural causes, and (c) thermogenic methane migration from deep sources due to human activities associated with the exploitation of conventional or unconventional oil and gas resources. This study combines aqueous and gas (dissolved and free) geochemical and isotope data from 372 groundwater samples obtained from 186 monitoring wells of the provincial Groundwater Observation Well Network (GOWN) in Alberta (Canada), a province with a long record of conventional and unconventional hydrocarbon exploration. We investigated whether methane occurring in shallow groundwater formed in situ, or whether it migrated into the shallow aquifers from elsewhere in the stratigraphic column. It was found that methane is ubiquitous in groundwater in Alberta and is predominantly of biogenic origin. The highest concentrations of biogenic methane (> 0.01 mM or > 0.2 mgL-1), characterized by δ13CCH4 values < -55 ‰, occurred in anoxic Na-Cl, Na-HCO3, and Na-HCO3-Cl type groundwaters with negligible concentrations of nitrate and sulfate suggesting that methane was formed in situ under methanogenic conditions for 39.1 % of the samples. In only a few cases (3.7 %) was methane of biogenic origin found in more oxidizing shallow aquifer portions suggesting limited upward migration from deeper methanogenic aquifers. Of the samples, 14.1 % contained methane with δ13CCH4 values > -54 ‰, potentially suggesting a thermogenic origin, but aqueous and isotope geochemistry data revealed that the elevated δ13CCH4 values were caused by microbial oxidation of biogenic methane or post-sampling degradation of low CH4 content samples rather than migration of deep thermogenic gas. A significant number of samples (39.2 %) contained methane with predominantly biogenic C isotope ratios (δ13CCH4 < -55 ‰) accompanied by elevated concentrations of ethane and sometimes trace concentrations of propane. These gases, observed in 28.1 % of the samples, bearing both biogenic (δ13C) and thermogenic (presence of C3) characteristics, are most likely derived from shallow coal seams that are prevalent in the Cretaceous Horseshoe Canyon and neighboring formations in which some of the groundwater wells are completed. The remaining 3.7 % of samples were not assigned because of conflicting parameters in the data sets or between replicates samples. Hence, despite quite variable gas concentrations and a wide range of δ13CCH4 values in baseline groundwater samples, we found no conclusive evidence for deep thermogenic gas migration into shallow aquifers either naturally or via anthropogenically induced pathways in this baseline groundwater survey. This study shows that the combined interpretation of aqueous geochemistry data in concert with chemical and isotopic compositions of dissolved and/or free gas can yield unprecedented insights into formation and potential migration of methane in shallow groundwater. This enables the assessment of cross-formational methane migration and provides an understanding of alkane gas sources and pathways necessary for a stringent baseline definition in the context of current and future unconventional hydrocarbon exploration and exploitation.

Hydrogeology of shallow basin-fill deposits in areas of Salt Lake Valley, Salt Lake County, Utah

USGS Publications Warehouse

Thiros, Susan A.

2003-01-01

A study of recently developed residential/commercial areas of Salt Lake Valley, Utah, was done from 1999 to 2001 in areas in which shallow ground water has the potential to move to a deeper aquifer that is used for public supply. Thirty monitoring wells were drilled and sampled in 1999 as part of the study. The ground water was either under unconfined or confined conditions, depending on depth to water and the presence or absence of fine-grained deposits. The wells were completed in the shallowest water-bearing zone capable of supplying water. Monitoring-well depths range from 23 to 154 feet. Lithologic, geophysical, hydraulic-conductivity, transmissivity, water-level, and water-temperature data were obtained for or collected from the wells.Silt and clay layers noted on lithologic logs correlate with increases in electrical conductivity and natural gamma radiation shown on many of the electromagnetic-induction and natural gamma logs. Relatively large increases in electrical conductivity, determined from the electromagnetic-induction logs, with no major changes in natural gamma radiation are likely caused by increased dissolved-solids content in the ground water. Some intervals with high electrical conductivity correspond to areas in which water was present during drilling.Unconfined conditions were present at 7 of 20 monitoring wells on the west side and at 2 of 10 wells on the east side of Salt Lake Valley. Fine-grained deposits confine the ground water. Anthropogenic compounds were detected in water sampled from most of the wells, indicating a connection with the land surface. Data were collected from 20 of the monitoring wells to estimate the hydraulic conductivity and transmissivity of the shallow ground-water system. Hydraulic-conductivity values of the shallow aquifer ranged from 30 to 540 feet per day. Transmissivity values of the shallow aquifer ranged from 3 to 1,070 feet squared per day. There is a close linear relation between transmissivity determined from slug-test analysis and transmissivity estimated from specific capacity.Water-level fluctuations were measured in the 30 monitoring wells from 1999 to July 2001. Generally, water-level changes measured in wells on the west side of the valley followed a seasonal trend and wells on the east side showed less fluctuation or a gradual decline during the 2-year period. This may indicate that a larger percentage of recharge to the shallow ground-water system on the west side is from somewhat consistent seasonal sources, such as canals and unconsumed irrigation water, as compared to sources on the east side. Water levels measured in monitoring wells completed in the shallow ground-water system near large-capacity public-supply wells varied in response to ground-water withdrawals from the deeper confined aquifer. Water temperature was monitored in 23 wells. Generally, little or no change in water temperature was measured in monitoring wells with a depth to water greater than about 40 feet. The shallower the water level in the well, the greater the water-temperature change measured during the study.Comparison of water levels measured in the monitoring wells and deeper wells in the same area indicate a downward gradient on the east side of the valley. Water levels in the shallow and deeper aquifers in the secondary recharge area on the west side of the valley were similar to those on the east side. Water levels measured in the monitoring wells and nearby wells completed in the deeper aquifer indicate that the vertical gradient can change with time and stresses on the system.

Laboratory simulation of the effects of overburden stress on the specific storage of shallow artesian aquifers

USGS Publications Warehouse

Sepúlveda, Nicasio; Zack, A.L.; Krishna, J.H.; Quinones-Aponte, Vicente; Gomez-Gomez, Fernando; Morris, G.L.

1990-01-01

A laboratory experiment to measure the specific storage of an aquifer material was conducted. A known dead load, simulating an overburden load, was applied to a sample of completely saturated aquifer material contained inside a cylinder. After the dead load was applied, water was withdrawn from the sample, causing the hydrostatic pressure to decrease and the effective stress to increase. The resulting compression of the sample and the amount of water withdrawn were measured after equilibrium was reached. The procedure was repeated by increasing the dead load and the hydrostatic pressure followed by withdrawing water to determine new values of effective stress and compaction. The simulated dead loads are typical of those experienced by shallow artesian aquifers. The void ratio and the effective stress of the aquifer sample, as simulated by different dead loads, determine the pore volume compressibility which, in turn, determines the values of specific storage. An analytical algorithm was used to independently determine the stress dependent profile of specific storage. These values are found to be in close agreement with laboratory results. Implications for shallow artesian aquifers, with relatively small overburden stress, are also addressed.

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

USGS Publications Warehouse

Harden, Stephen L.; Fine, Jason M.; Spruill, Timothy B.

2003-01-01

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers.All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County.In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system.The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean.Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers.Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards.Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

Temporal Variability of Groundwater Chemistry in Shallow and Deep Aquifers of Araihazar, Bangladesh

PubMed Central

Dhar, R. K.; Zheng, Y.; Stute, M.; van Geen, A.; Cheng, Z.; Shanewaz, M.; Shamsudduha, M.; Hoque, M. A.; Rahman, M. W.; Ahmed, K. M.

2008-01-01

Samples were collected every 2–4 weeks from a set of 37 monitoring wells over a period of 2–3 years in Araihazar, Bangladesh, to evaluate the temporal variability of groundwater composition for As and other constituents. The monitoring wells are grouped in 6 nests and span the 5–91 m depth range. Concentrations of As, Ca, Fe, K, Mg, Mn, Na, P, and S were measured by high-resolution ICPMS with a precision of 5% or better; concentrations of Cl were measured by ion chromatography. In shallow wells <30 m deep, As and P concentrations generally varied by <30%, whereas concentrations of the major ions (Na, K, Mg, Ca and Cl) and the redox-sensitive elements (Fe, Mn, and S) varied over time by up to ± 90%. In wells tapping the deeper aquifers > 30 m often below clay layers concentrations of groundwater As were much lower and varied by <10%. The concentrations of major cations also varied by <10% in these deep aquifers. In contrast, the concentration of redox-sensitive constituents Fe, S, and Mn in deep aquifers varied by up to 97% over time. Thus, strong decoupling between variations in As and Fe concentrations is evident in groundwaters from shallow and deep aquifers. Comparison of the time series data with groundwater ages determined by 3H/3He and 14C dating shows that large seasonal or inter-annual variations in major cation and chloride concentrations are restricted to shallow aquifers and groundwater recharged < 5 years ago. There is no corresponding change in As concentrations despite having significant variations of redox sensitive constituents in these very young waters. This is attributed to chemical buffering due to rapid equilibrium between solute and solid As. At two sites where the As content of groundwater in existing shallow wells averages 102 µg/L (range: < 5 to 648 µg/L; n=118) and 272 µg/L (range: 10 to 485 µg/L; n=65), respectively, a systematic long-term decline in As concentrations lends support to the notion that flushing may slowly deplete an aquifer of As. Shallow aquifer water with > 5 yr 3H/3He age show a constant As:P molar ratio of 9.6 over time, suggesting common mechanism of mobilization. PMID:18467001

California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project--shallow aquifer assessment

USGS Publications Warehouse

,

2013-01-01

The California State Water Resources Control Board’s (SWRCB) GAMA Program is a comprehensive assessment of statewide groundwater quality in California. From 2004 to 2012, the GAMA Program’s Priority Basin Project focused on assessing groundwater resources used for public drinking-water supplies. More than 2,000 public-supply wells were sampled by U.S. Geological Survey (USGS) for this effort. Starting in 2012, the GAMA Priority Basin Project began an assessment of water resources in shallow aquifers in California. These shallow aquifers provide water for domestic and small community-supply wells, which are often drilled to shallower depths in the groundwater system than public-supply wells. Shallow aquifers are of interest because shallow groundwater may respond more quickly and be more susceptible to contamination from human activities at the land surface, than the deeper aquifers. The SWRCB’s GAMA Program was developed in response to the Groundwater Quality Monitoring Act of 2001 (Water Code sections 10780-10782.3): a public mandate to assess and monitor the quality of groundwater resources used for drinking-water supplies, and to increase the availability of information about groundwater quality to the public. The U.S. Geological Survey is the technical lead of the Priority Basin Project. Stewardship of California’s groundwater resources is a responsibility shared between well owners, communities, and the State. Participants and collaborators in the GAMA Program include Regional Water Quality Control Boards, Department of Water Resources, Department of Public Health, local and regional groundwater management entities, county and local water agencies, community groups, and private citizens. Well-owner participation in the GAMA Program is entirely voluntary.

Abiotic Removal of TCE and cis-DCE by Magnetite under Aerobic Conditions in Ground Water (Maryland)

EPA Science Inventory

The former Twin Cities Army Ammunition Plant (TCAAP) is located just north of St. Paul, Minnesota. Disposal of chlorinated solvents at the Building102 site on the TCAAP contaminated groundwater in the shallow, unconsolidated sand aquifer with TCE and cis-DCE. Concentrations of ...

Understanding the fate of sanitation-related nutrients in a shallow sandy aquifer below an urban slum area

NASA Astrophysics Data System (ADS)

Nyenje, P. M.; Havik, J. C. N.; Foppen, J. W.; Muwanga, A.; Kulabako, R.

2014-08-01

We hypothesized that wastewater leaching from on-site sanitation systems to alluvial aquifers underlying informal settlements (or slums) may end up contributing to high nutrient loads to surface water upon groundwater exfiltration. Hence, we conducted a hydro-geochemical study in a shallow sandy aquifer in Bwaise III parish, an urban slum area in Kampala, Uganda, to assess the geochemical processes controlling the transport and fate of dissolved nutrients (NO3, NH4 and PO4) released from on-site sanitation systems to groundwater. Groundwater was collected from 26 observation wells. The samples were analyzed for major ions (Ca, Mg, Na, Mg, Fe, Mn, Cl and SO4) and nutrients (o-PO4, NO3 and NH4). Data was also collected on soil characteristics, aquifer conductivity and hydraulic heads. Geochemical modeling using PHREEQC was used to determine the level of o-PO4 control by mineral solubility and sorption. Groundwater below the slum area was anoxic and had near neutral pH values, high values of EC (average of 1619 μS/cm) and high concentrations of Cl (3.2 mmol/L), HCO3 (11 mmol/L) and nutrients indicating the influence from wastewater leachates especially from pit latrines. Nutrients were predominantly present as NH4 (1-3 mmol/L; average of 2.23 mmol/L). The concentrations of NO3 and o-PO4 were, however, low: average of 0.2 mmol/L and 6 μmol/L respectively. We observed a contaminant plume along the direction of groundwater flow (NE-SW) characterized by decreasing values of EC and Cl, and distinct redox zones. The redox zones transited from NO3-reducing in upper flow areas to Fe-reducing in the lower flow areas. Consequently, the concentrations of NO3 decreased downgradient of the flow path due to denitrification. Ammonium leached directly into the alluvial aquifer was also partially removed because the measured concentrations were less than the potential input from pit latrines (3.2 mmol/L). We attributed this removal (about 30%) to anaerobic ammonium oxidation (anammox) given that the cation exchange capacity of the aquifer was low (< 6 meq/100 g) to effectively adsorb NH4. Phosphate transport was, on the other hand, greatly retarded and our results showed that this was due to the adsorption of P to calcite and the co-precipitation of P with calcite and rhodochrosite. Our findings suggest that shallow alluvial sandy aquifers underlying urban slum areas are an important sink of excessive nutrients leaching from on-site sanitation systems.

THE ANAEROBIC BIODEGRADATION OF O-,M- AND P-CRESOL BY SULFATE-REDUCING BACTERIAL ENRICHMENT CULTURES OBTAINED FROM A SHALLOW ANOXIC AQUIFER

EPA Science Inventory

Sulfate-reducing bacterial enrichments were obtained from a shallow anoxic aquifer for their ability to metabolize either o-, m-, orp-cresol. GC/MS and simultaneous adaptation experiments suggested that the anaerobic decomposition of p-cresol proceeds ...

Stimulated anoxic biodegradation of aromatic hydrocarbons using Fe(III) ligands

USGS Publications Warehouse

Lovley, D.R.; Woodward, J.C.; Chapelle, F.H.

1994-01-01

Contamination of ground waters with water-soluble aromatic hydrocarbons, common components of petroleum pollution, often produces anoxic conditions under which microbial degradation of the aromatics is slow. Oxygen is often added to contaminated ground water to stimulate biodegradation, but this can be technically difficult and expensive. Insoluble Fe(III) oxides, which are generally abundant in shallow aquifers, are alternative potential oxidants, but are difficult for microorganisms to access. Here we report that adding organic ligands that bind to Fe(III) dramatically increases its bioavailability, and that in the presence of these ligands, rates of degradation of aromatic hydrocarbons in anoxic aquifer sediments are comparable to those in oxic sediments. We find that even benzene, which is notoriously refractory in the absence of oxygen, can be rapidly degraded. Our results suggest that increasing the bioavailability of Fe(III) by adding suitable ligands provides a potential alternative to oxygen addition for the bioremediation of petroleum-contaminated aquifers.Contamination of ground waters with water-soluble aromatic hydrocarbons, common components of petroleum pollution, often produces anoxic conditions under which microbial degradation of the aromatics is slow. Oxygen is often added to contaminated ground water to stimulate biodegradation, but this can be technically difficult and expensive. Insoluble Fe(III) oxides, which are generally abundant in shallow aquifers, are alternative potential oxidants, but are difficult for microorganisms to access. Here we report that adding organic ligands that bind to Fe(III) dramatically increases its bioavailability, and that in the presence of these ligands, rates of degradation of aromatic hydrocarbons in anoxic aquifer sediments are comparable to those in oxic sediments. We find that even benzene, which is notoriously refractory in the absence of oxygen, can be rapidly degraded. Our results suggest that increasing the bioavailability of Fe(III) by adding suitable ligands provides a potential alternative to oxygen addition for the bioremediation of petroleum-contamined aquifers.

Arsenic pollution of groundwater in Vietnam exacerbated by deep aquifer exploitation for more than a century

PubMed Central

Winkel, Lenny H. E.; Trang, Pham Thi Kim; Lan, Vi Mai; Stengel, Caroline; Amini, Manouchehr; Ha, Nguyen Thi; Viet, Pham Hung; Berg, Michael

2011-01-01

Arsenic contamination of shallow groundwater is among the biggest health threats in the developing world. Targeting uncontaminated deep aquifers is a popular mitigation option although its long-term impact remains unknown. Here we present the alarming results of a large-scale groundwater survey covering the entire Red River Delta and a unique probability model based on three-dimensional Quaternary geology. Our unprecedented dataset reveals that ∼7 million delta inhabitants use groundwater contaminated with toxic elements, including manganese, selenium, and barium. Depth-resolved probabilities and arsenic concentrations indicate drawdown of arsenic-enriched waters from Holocene aquifers to naturally uncontaminated Pleistocene aquifers as a result of > 100 years of groundwater abstraction. Vertical arsenic migration induced by large-scale pumping from deep aquifers has been discussed to occur elsewhere, but has never been shown to occur at the scale seen here. The present situation in the Red River Delta is a warning for other As-affected regions where groundwater is extensively pumped from uncontaminated aquifers underlying high arsenic aquifers or zones. PMID:21245347

Dissolved noble gases and stable isotopes as tracers of preferential fluid flow along faults in the Lower Rhine Embayment, Germany

NASA Astrophysics Data System (ADS)

Gumm, L. P.; Bense, V. F.; Dennis, P. F.; Hiscock, K. M.; Cremer, N.; Simon, S.

2016-02-01

Groundwater in shallow unconsolidated sedimentary aquifers close to the Bornheim fault in the Lower Rhine Embayment (LRE), Germany, has relatively low δ2H and δ18O values in comparison to regional modern groundwater recharge, and 4He concentrations up to 1.7 × 10-4 cm3 (STP) g-1 ± 2.2 % which is approximately four orders of magnitude higher than expected due to solubility equilibrium with the atmosphere. Groundwater age dating based on estimated in situ production and terrigenic flux of helium provides a groundwater residence time of ˜107 years. Although fluid exchange between the deep basal aquifer system and the upper aquifer layers is generally impeded by confining clay layers and lignite, this study's geochemical data suggest, for the first time, that deep circulating fluids penetrate shallow aquifers in the locality of fault zones, implying that sub-vertical fluid flow occurs along faults in the LRE. However, large hydraulic-head gradients observed across many faults suggest that they act as barriers to lateral groundwater flow. Therefore, the geochemical data reported here also substantiate a conduit-barrier model of fault-zone hydrogeology in unconsolidated sedimentary deposits, as well as corroborating the concept that faults in unconsolidated aquifer systems can act as loci for hydraulic connectivity between deep and shallow aquifers. The implications of fluid flow along faults in sedimentary basins worldwide are far reaching and of particular concern for carbon capture and storage (CCS) programmes, impacts of deep shale gas recovery for shallow groundwater aquifers, and nuclear waste storage sites where fault zones could act as potential leakage pathways for hazardous fluids.

Groundwater Ecosystems Vary with Land Use across a Mixed Agricultural Landscape.

PubMed

Korbel, K L; Hancock, P J; Serov, P; Lim, R P; Hose, G C

2013-01-01

Changes in surface land use may threaten groundwater quality and ecosystem integrity, particularly in shallow aquifers where links between groundwater and surface activities are most intimate. In this study we examine the response of groundwater ecosystem to agricultural land uses in the shallow alluvial aquifer of the Gwydir River valley, New South Wales, Australia. We compared groundwater quality and microbial and stygofauna assemblages among sites under irrigated cropping, non-irrigated cropping and grazing land uses. Stygofauna abundance and richness was greatest at irrigated sites, with the composition of the assemblage suggestive of disturbance. Microbial assemblages and water quality also varied with land use. Our study demonstrates significant differences in the composition of groundwater ecosystems in areas with different surface land use, and highlights the utility of groundwater biota for biomonitoring, particularly in agricultural landscapes. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

The effect of heterogeneity identifying the leakage of carbon dioxide in a shallow aquifer: an experimental study

NASA Astrophysics Data System (ADS)

Ha, S. W.; Lee, S. H.; Jeon, W. T.; Joo, Y. J.; Lee, K. K.

2014-12-01

Carbon dioxide (CO2) leakage into the shallow aquifer is one of the main concerns at a CO2 sequestration site. Various hydrogeochemical parameters have been suggested to determine the leakage (i.e., pH, EC, Alkalinity, Ca and δ13C). For the practical point of view, direct and continuous measurement of the dissolved CO2 concentration at the proper location can be the most useful strategy for the CO2 leakage detection in a shallow aquifer. In order to enhance possibility of identifying leaked CO2, monitoring location should be determined with regard to the shallow aquifer heterogeneity. In this study, a series of experiments were conducted to investigate the effects of heterogeneity on the dissolved CO2 concentrations. A 2-D sand tank of homogeneous medium sands including a single heterogeneity layer was designed. Two NDIR CO2 sensors, modified for continuous measuring in aquatic system, were installed above and below the single heterogeneous layer (clay, fine and medium sand lenses). Also, temperature and water contents were measured continuously at a same position. Bromocresol purple which is one of the acid-base indicator was used to visualize CO2 migration. During the gas phase CO2 injection at the bottom of the sand tank, dissolved CO2 in the water is continuously measured. In the results, significant differences of concentrations were observed due to the presence of heterogeneity layer, even the locations were close. These results suggested that monitoring location should be determined considering vertical heterogeneity of shallow aquifer at a CO2 leakage site.

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

NASA Astrophysics Data System (ADS)

Danczak, Robert; Yabusaki, Steven; Williams, Kenneth; Fang, Yilin; Hobson, Chad; Wilkins, Michael

2016-05-01

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Water-quality assessment of the Trinity River basin, Texas : ground-water quality of the Trinity, Carrizo-Wilcox, and Gulf Coast aquifers, February-August 1994

USGS Publications Warehouse

Reutter, David C.; Dunn, David D.

2000-01-01

Ground-water samples were collected from wells in the outcrops of the Trinity, Carrizo-Wilcox, and Gulf Coast aquifers during February-August 1994 to determine the quality of ground water in the three major aquifers in the Trinity River Basin study unit, Texas. These samples were collected and analyzed for selected properties, nutrients, major inorganic constituents, trace elements, pesticides, dissolved organic carbon, total phenols, methylene blue active substances, and volatile organic compounds as part of the U.S. Geological Survey National Water-Quality Assessment Program. Quality-control practices included the collection and analysis of blank, duplicate, and spiked samples. Samples were collected from 12 shallow wells (150 feet or less) and from 12 deep wells (greater than 150 feet) in the Trinity aquifer, 11 shallow wells and 12 deep wells in the Carrizo-Wilcox aquifer, and 14 shallow wells and 10 deep wells in the Gulf Coast aquifer. The three aquifers had similar water chemistries-calcium was the dominant cation and bicarbonate the dominant anion. Statistical tests relating well depths to concentrations of nutrients and major inorganic constituents indicated correlations between well depth and concentrations of ammonia nitrogen, nitrite plus nitrate nitrogen, bicarbonate, sodium, and dissolved solids in the Carrizo-Wilcox aquifer and between well depth and concentrations of sulfate in the Gulf Coast aquifer. The tests indicated no significant correlations for the Trinity aquifer. Concentrations of dissolved solids were larger than the secondary maximum contaminant level of 500 milligrams per liter established for drinking water by the U.S. Environmental Protection Agency in 12 wells in the Trinity aquifer, 4 wells in the Carrizo-Wilcox aquifer, and 6 wells in the Gulf Coast aquifer. Iron concentrations were larger than the secondary maximum contaminant level of 300 micrograms per liter in at least 3 samples from each aquifer, and manganese concentrations were larger than the secondary maximum contaminant level of 50 micrograms per liter in at least 2 samples from each aquifer. The pesticides atrazine, deethylatrazine, and pp'-DDE were detected in at least one sample from each aquifer. Diazinon was detected in 11 Trinity aquifer samples and 4 Carrizo-Wilcox aquifer samples. Each aquifer had one detection of a volatile organic compound-benzene in the Trinity aquifer, trichlorofluoromethane in the Carrizo-Wilcox aquifer, and trichloromethane in the Gulf Coast aquifer.

Dissolved methane occurrences in aquifers in the footprint of Texas shale plays and their controls

NASA Astrophysics Data System (ADS)

Nicot, J. P.; Mickler, P. J.; Larson, T.; Darvari, R.; Smyth, R. C.

2015-12-01

Many constituents typically associated with oil and gas production, such as methane and higher-order hydrocarbons, exist naturally in shallow groundwater. Recent studies of aquifers in the footprint of several gas plays across the US have showed that (1) dissolved thermogenic methane may or may not be present in the shallow subsurface and (2) shallow thermogenic methane could be naturally occurring and emplaced through mostly vertical migration over geologic time and is not necessarily a consequence of gas production from a gas play. A total of 800+ water wells have been sampled across the state of Texas to characterize shallow methane in fresh-water aquifers overlying shale plays and other tight formations (Barnett, Eagle Ford, Haynesville shale areas as well as in the Delaware Basin of West Texas). Analytical results suggest that dissolved methane is not widespread in shallow groundwater and that, when present at concentration greater than 10 mg/L, is often of natural but thermogenic or mixed origin according to the isotopic signature and to the presence of other light hydrocarbons.

Hydro-geochemical modeling of subalpine urbanized area: geochemical characterization of the shallow and deep aquifers of the urban district of Como (first results).

NASA Astrophysics Data System (ADS)

Terrana, Silvia; Brunamonte, Fabio; Frascoli, Francesca; Ferrario, Maria Francesca; Michetti, Alessandro Maria; Pozzi, Andrea; Gambillara, Roberto; Binda, Gilberto

2016-04-01

One of the greatest environmental and social-economics threats is climate change. This topic, in the next few years, will have a significant impact on the availability of water resources of many regions. This is compounded by the strong anthropization of water systems that shows an intensification of conflicts for water resource exploitation. Therefore, it is necessary a sustainable manage of natural resources thorough knowledge of the hosting territories. The development of investigation and data processing methods are essential to reduce costs for the suitable use and protection of resources. Identify a sample area for testing the best approach is crucial. This research aims to find a valid methodology for the characterization, modeling and management of subalpine urban aquifers, and the urban district of Como appears perfect. The city of Como is located at the southern end of the western sector of Lake Como (N Italy). It is a coastal town, placed on a small alluvial plain, therefore in close communication with the lake. The plain is drained by two streams, which are presently artificially buried, and have an underground flow path in the urban section till the mouth. This city area, so, is suitable for this project as it is intensely urbanized, its dimensions is not too extensive and it is characterized by two aquifers very important and little known. These are a shallow aquifer and a deep aquifer, which are important not only for any water supply, but also for the stability of the ground subsidence in the city. This research is also the opportunity to work in a particular well-known area with high scientific significance; however, there is complete absence of information regarding the deep aquifer. Great importance has also the chosen and used of the more powerful open source software for this type of area, such as PHREEQC, EnvironInsite, PHREEQE etc., used for geological and geochemical data processing. The main goal of this preliminary work is the characterization of both aquifers and the comprehension of the interaction between the shallow one and deep one. The first results of geochemical and hydrological analyses in nine piezometer, seven in the shallow aquifer and two in the deep one, permit to identify a general characterization of groundwater: the waters of both the aquifers are calcium bicarbonate, with discontinuous enrichment in sulphate and silicate. The conductibility values are higher in the shallow aquifer then in the deep aquifer, this is an indication of the high flow rate of the deep one and of the higher level of vulnerability of the shallow water respect the urban pollutant. Particular is also the relatively high temperature for the deep water (15.5°C to 16.1°C). The next steps of work are an increase of geochemical analysis, with trace element, and the correlation with hydro-chemical surface water.

ANALYTICAL ELEMENT MODELING OF COASTAL AQUIFERS

EPA Science Inventory

Four topics were studied concerning the modeling of groundwater flow in coastal aquifers with analytic elements: (1) practical experience was obtained by constructing a groundwater model of the shallow aquifers below the Delmarva Peninsula USA using the commercial program MVAEM; ...

Laboratory evidence of MTBE biodegradation in Borden aquifer material

NASA Astrophysics Data System (ADS)

Schirmer, Mario; Butler, Barbara J.; Church, Clinton D.; Barker, James F.; Nadarajah, Nalina

2003-02-01

Mainly due to intrinsic biodegradation, monitored natural attenuation can be an effective and inexpensive remediation strategy at petroleum release sites. However, gasoline additives such as methyl tert-butyl ether (MTBE) can jeopardize this strategy because these compounds often degrade, if at all, at a slower rate than the collectively benzene, toluene, ethylbenzene and the xylene (BTEX) compounds. Investigation of whether a compound degrades under certain conditions, and at what rate, is therefore important to the assessment of the intrinsic remediation potential of aquifers. A natural gradient experiment with dissolved MTBE-containing gasoline in the shallow, aerobic sand aquifer at Canadian Forces Base (CFB) Borden (Ontario, Canada) from 1988 to 1996 suggested that biodegradation was the main cause of attenuation for MTBE within the aquifer. This laboratory study demonstrates biologically catalyzed MTBE degradation in Borden aquifer-like environments, and so supports the idea that attenuation due to biodegradation may have occurred in the natural gradient experiment. In an experiment with batch microcosms of aquifer material, three of the microcosms ultimately degraded MTBE to below detection, although this required more than 189 days (or >300 days in one case). Failure to detect the daughter product tert-butyl alcohol (TBA) in the field and the batch experiments could be because TBA was more readily degradable than MTBE under Borden conditions.

Quantifying Nitrogen Transport from Riparian Groundwater Seeps to a Headwater Stream in an Agricultural Watershed

NASA Astrophysics Data System (ADS)

Redder, B.; Buda, A. R.; Kennedy, C. D.; Folmar, G.; DeWalle, D. R.; Boyer, E. W.

2017-12-01

Headwater streams in the Northeast region of the United States typically receive more than 50% of their base flow from groundwater, either by diffuse discharge through the streambed or by localized discharge through riparian seeps. It is very difficult to separate the individual contributions of these two groundwater fluxes to streamflow. Furthermore, riparian seeps show significant variability in discharge and nutrient concentration, adding uncertainty to estimates of groundwater-based nitrogen inputs to streams. In this study, we combined stream measurements at two different scales to quantify groundwater discharge by matrix flow through the streambed and by macropore flow through the riparian zone. The study site was a 175-m stream reach located in a heavily cultivated 45-hectare watershed in east-central Pennsylvania. Differential streamflow gauging and streambed measurements of hydraulic head gradient, hydraulic conductivity, and groundwater chemistry were used to solve for the riparian groundwater flux in a reach mass balance equation. Adopting a mass balance approach, riparian groundwater fluxes ranged from 115-205 m3 d-1, transporting 2-4 kg N d-1 of nitrate from the fractured bedrock aquifer to the stream. Air-water manometer readings from short-screened piezometers installed in the shallow streambed (30 cm) indicated slightly losing head gradients between the stream and groundwater, despite substantial (36-66%) increases in stream flow along the stream reach. Preliminary chemical data for the stream, streambed, and shallow ground water suggest that the stream is partially disconnected from the underlying aquifer and that riparian groundwater seeps supply essentially all water and nitrogen to the system. These results, along with the comparison of shallow and deep aquifer water with seep chemistry, provide insight into sources of water to riparian groundwater seeps and allow us to determine the transport and fate of nitrogen in a fractured aquifer system. The use of water isotopes and hydrometric data will be used to further test the hypothesis that this is a perched system disconnected from the aquifer below.

Pharmaceuticals in on-site sewage effluent and ground water, Western Montana

USGS Publications Warehouse

Godfrey, E.; Woessner, W.W.; Benotti, M.J.

2007-01-01

Human use of pharmaceuticals results in the excretion and disposal of compounds that become part of municipal and domestic waste streams. On-site waste water disposal and leaking city sewer systems can provide avenues for the migration of effluent to the underlying aquifers. This research assessed the occurrence and persistence of 22 target pharmaceuticals in septic tank effluent and two shallow, coarse-grained aquifers in western Montana. Twelve compounds (acetaminophen, caffeine, codeine, carbamazepine, cotinine, erythromycin-18, nicotine, paraxanthine, ranitidine, sulfamethoxazole, trimethoprim, and warfarin) were detected in a high school septic tank effluent. Three of the 12 compounds, carbamazepine, sulfamethoxazole, and nicotine, were detected in the underlying sand and gravel aquifer after effluent percolation through a 2.0-m thick sand vadose zone. Sampling of a second sand, gravel, and cobble dominated unconfined aquifer, partially overlain by septic systems and a city sewer system, revealed the presence of caffeine, carbamazepine, cotinine, nicotine, and trimethoprim. The presence of carbamazepine and sulfamethoxazole in these aquifers appears to correlate with local usage based on a reported monthly prescription volume. This work highlights the need for expanding geochemical investigations of sewage waste impacted ground water systems to include sampling for selected pharmaceuticals. ?? 2007 National Ground Water Association.

Pharmaceuticals in on-site sewage effluent and ground water, Western Montana.

PubMed

Godfrey, Emily; Woessner, William W; Benotti, Mark J

2007-01-01

Human use of pharmaceuticals results in the excretion and disposal of compounds that become part of municipal and domestic waste streams. On-site waste water disposal and leaking city sewer systems can provide avenues for the migration of effluent to the underlying aquifers. This research assessed the occurrence and persistence of 22 target pharmaceuticals in septic tank effluent and two shallow, coarse-grained aquifers in western Montana. Twelve compounds (acetaminophen, caffeine, codeine, carbamazepine, cotinine, erythromycin-18, nicotine, paraxanthine, ranitidine, sulfamethoxazole, trimethoprim, and warfarin) were detected in a high school septic tank effluent. Three of the 12 compounds, carbamazepine, sulfamethoxazole, and nicotine, were detected in the underlying sand and gravel aquifer after effluent percolation through a 2.0-m thick sand vadose zone. Sampling of a second sand, gravel, and cobble dominated unconfined aquifer, partially overlain by septic systems and a city sewer system, revealed the presence of caffeine, carbamazepine, cotinine, nicotine, and trimethoprim. The presence of carbamazepine and sulfamethoxazole in these aquifers appears to correlate with local usage based on a reported monthly prescription volume. This work highlights the need for expanding geochemical investigations of sewage waste impacted ground water systems to include sampling for selected pharmaceuticals.

DIAGNOSTIC MONITORING OF BIOGEOCHEMICAL INTERACTIONS OF A SHALLOW AQUIFER IN RESPONSE TO A CO2 LEAK

EPA Science Inventory

Results from these coupled laboratory and field experiments will greatly improve our understanding of the geochemical and microbiological reactions under low pH - high CO2 stress. We anticipate that this research will: (1) provide criteria for site selection for geological CO2...

Preliminary Study Contamination of Organochlorine Pesticide (Heptachlor) and Heavy Metal (Arsenic) in Shallow Groundwater Aquifer of Semarang Coastal Areas

NASA Astrophysics Data System (ADS)

Rochaddi, Baskoro; Adhi Suryono, Chrisna; Atmodjo, Warsito; Satriadi, Alfi

2018-02-01

The present study was conducted to assess the level of pesticide and heavy metal contamination in shallow aquifer of Semarang coastal areas. Results indicated that Heptachlor and Arsenic were detected in the water samples in the range 0.023-0.055 μg L-1 and 0,03-1,63 μg L-1, respectively. Compared to the standard limits of the organochlorine contents in the water sample by World Health Organization (WHO) limits and Indonesian Drinking and Domestic Water Quality Standard for Ground Water (IWQS), groundwater of Semarang Coastal Areas was contaminated with pesticide and heavy metal. This study has proven the presence of organochlorine and heavy metal contamination of some shallow aquifer supplies in the coastal areas of Semarang.

Modeling contamination of shallow unconfined aquifers through infiltration beds

USGS Publications Warehouse

Ostendorf, D.W.

1986-01-01

We model the transport of a simply reactive contaminant through an infiltration bed and underlying shallow, one-dimensional, unconfined aquifer with a plane, steeply sloping bottom in the assumed absence of dispersion and downgradient dilution. The effluent discharge and ambient groundwater flow under the infiltration beds are presumed to form a vertically mixed plume marked by an appreciable radial velocity component in the near field flow region. The near field analysis routes effluent contamination as a single linear reservoir whose output forms a source plane for the one-dimensional, far field flow region downgradient of the facility; the location and width of the source plane reflect the relative strengths of ambient flow and effluent discharge. We model far field contaminant transport, using an existing method of characteristics solution with frame speeds modified by recharge, bottom slope, and linear adsorption, and concentrations reflecting first-order reaction kinetics. The near and far field models simulate transport of synthetic detergents, chloride, total nitrogen, and boron in a contaminant plume at the Otis Air Force Base sewage treatment plant in Barnstable County, Massachusetts, with reasonable accuracy.

Hydrogeologic framework of the shallow ground-water system in the Cox Hall Creek basin, Cape May County, New Jersey

USGS Publications Warehouse

Lacombe, Pierre J.; Zapecza, Otto S.

2006-01-01

Cape May County is investigating the feasibility of restoring the lowermost reach of Cox Hall Creek to its former state as a tidal saltwater wetland; however, the potential for contamination of the shallow ground-water system, which provides water to hundreds of nearby privately owned domestic wells, with saltwater from the restored wetland is of particular concern. To evaluate the potential effectiveness and risks of restoring the saltwater wetlands, the County needs information about the hydrogeologic framework in the area, and about the potential vulnerability of the domestic wells to contamination. The shallow ground-water system in the Cox Hall Creek area consists of unconsolidated Holocene and Pleistocene deposits. The Holly Beach water-bearing zone, the unconfined (water-table) aquifer, is about 35 feet thick and contains a 2- to 4-foot-thick clay lens about 10 feet below land surface; a lower, more discontinuous clay lens about 30 to 35 feet below land surface ranges up to 5 feet in thickness. A 75-foot-thick confining unit separates the Holly Beach water-bearing zone from the underlying estuarine sand aquifer. The clay lenses in the Holly Beach water-bearing zone likely retard the movement of contaminants from septic tanks, lawns, and other surficial sources, protecting wells that tap the lower, sandy part of the aquifer. The clay lenses also may protect these wells from salty surface water if withdrawals from the Holly Beach water-bearing zone are not increased substantially. Deeper wells that tap the estuarine sand aquifer are more effectively protected from saltwater from surface sources because of the presence of the overlying confining unit.

Areal studies aid protection of ground-water quality in Illinois, Indiana, and Wisconsin

USGS Publications Warehouse

Mills, Patrick C.; Kay, Robert T.; Brown, Timothy A.; Yeskis, Douglas J.

1999-01-01

In 1991, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, initiated studies designed to characterize the ground-water quality and hydrogeology in northern Illinois, and southern and eastern Wisconsin (with a focus on the north-central Illinois cities of Belvidere and Rockford, and the Calumet region of northeastern Illinois and northwestern Indiana). These areas are considered especially susceptible to ground-water contamination because of the high density of industrial and waste-disposal sites and the shallow depth to the unconsolidated sand and gravel aquifers and the fractured, carbonate bedrock aquifers that underlie the areas. The data and conceptual models of ground-water flow and contaminant distribution and movement developed as part of the studies have allowed Federal, State, and local agencies to better manage, protect, and restore the water supplies of the areas. Water-quality, hydrologic, geologic, and geophysical data collected as part of these areal studies indicate that industrial contaminants are present locally in the aquifers underlying the areas. Most of the contaminants, particularly those at concentrations that exceeded regulatory water-quality levels, were detected in the sand and gravel aquifers near industrial or waste-disposal sites. In water from water-supply wells, the contaminants that were present generally were at concentrations below regulatory levels. The organic compounds detected most frequently at concentrations near or above regulatory levels varied by area. Trichloroethene, tetrachloroethene, and 1,1,1-trichloroethane (volatile chlorinated compounds) were most prevalent in north-central Illinois; benzene (a petroleum-related compound) was most prevalent in the Calumet region. Differences in the type of organic compounds that were detected in each area likely reflect differences in the types of industrial sites that predominate in the areas. Nickel and aluminum were the trace metals detected most frequently at concentrations above regulatory levels in both areas. Contaminants in the shallow sand and gravel aquifers and carbonate aquifers appear to have moved with ground water discharging to local lakes, streams, and wetlands. Ground-water flow and possibly contaminant movement is concentrated in the weathered surface zones and in deeper fractures of the carbonate aquifers underlying both areas.

Study of quaternary aquifers in Ganga Plain, India: focus on groundwater salinity, fluoride and fluorosis.

PubMed

Misra, Anil Kumar; Mishra, Ajai

2007-06-01

In marginal and central alluvial plains (Ganga Plain) of India, the inland salinity is continuously increasing, canal network and arid to semi-arid climatic conditions that led to excessive evapotranspiration concentrates the salt in soil and thereby escalating the groundwater salinity. In Mat Tahsil, Mathura district (Ganga Plain) study on shallow and deep aquifer salinity and fluoride was carried out in August 2001 and 2004. Groundwater salinity in some parts is more then 4000 microOmega(-1)/cm. This region is severely affected by endemic fluorosis due to consumption of fluoride-contaminated water. Analysis of F(-), Na(+), K(+), Cl(-) and HCO(3)(-) was carried out at 30 sites of dugwells and borewells. Result shows that there is a variation and continuous escalation in the groundwater salinity and fluoride concentration in deep and shallow aquifers on the basis of analysis. Classification of salinity levels was carried out in 2001 and 2004. The deep aquifers (borewells) are found more saline as compare to the shallow aquifers (dugwells) while F(-), Na(+), K(+), Cl(-) and HCO(3)(-) shows high concentration in shallow aquifers. The fluoride concentration in the groundwater of these villages showed values from 0.1 to 2.5mg/l, severe enough to cause dental and skeletal fluorosis among the inhabitants, especially children of these villages. One of the major effects of inland salinity in this region is from saline groundwater, which is reaching the land surface and causing soil salinisations and water logging in the NE and SE parts of Mat block.

Potentiometric surfaces of the Arnold Engineering Development Complex Area, Arnold Air Force Base, Tennessee, May and September 2011

USGS Publications Warehouse

Haugh, Connor J.; Robinson, John A.

2016-01-29

During May 2011, when water levels were near seasonal highs, water-level data were collected from 374 monitoring wells; and during September 2011, when water levels were near seasonal lows, water-level data were collected from 376 monitoring wells. Potentiometric surfaces were mapped by contouring altitudes of water levels measured in wells completed in the shallow aquifer, the upper and lower parts of the Manchester aquifer, and the Fort Payne aquifer. Water levels are generally 2 to 14 feet lower in September compared to May. The potentiometric-surface maps for all aquifers indicate a groundwater depression at the J4 test cell. Similar groundwater depressions in the shallow and upper parts of the Manchester aquifer are within the main testing area at the Arnold Engineering Development Complex at dewatering facilities.

Project Summary. ANALYTICAL ELEMENT MODELING OF COASTAL AQUIFERS

EPA Science Inventory

Four topics were studied concerning the modeling of groundwater flow in coastal aquifers with analytic elements: (1) practical experience was obtained by constructing a groundwater model of the shallow aquifers below the Delmarva Peninsula USA using the commercial program MVAEM; ...

The quality of our Nation's waters: water quality in the Denver Basin aquifer system, Colorado, 2003-05

USGS Publications Warehouse

Bauch, Nancy J.; Musgrove, MaryLynn; Mahler, Barbara J.; Paschke, Suzanne

2015-01-01

Availability and sustainability of groundwater in the Denver Basin aquifer system depend on water quantity and water quality. The Denver Basin aquifer system underlies about 7,000 square miles of the Great Plains in eastern Colorado and is the primary or sole source of water for domestic and public supply in many areas of the basin. Use of groundwater from the Denver Basin sandstone aquifers has been instrumental for development of the south Denver metropolitan area and other areas, but has resulted in a decline in water levels in some parts of the system. Human activities in many areas have adversely affected the quality of water in the aquifer system, especially the shallow parts. Groundwater in deeper parts of the system used for drinking water, once considered isolated from the effects of overlying land use, is increasingly vulnerable to contamination from human activities and geologic materials. Availability and sustainability of high-quality groundwater are vital to the economic health of the Denver Basin area.

Controlled CO2 injection into a shallow aquifer and leakage detection monitoring practices at the K-COSEM site, Korea

NASA Astrophysics Data System (ADS)

Lee, S. S.; Joun, W.; Ju, Y. J.; Ha, S. W.; Jun, S. C.; Lee, K. K.

2017-12-01

Artificial carbon dioxide injection into a shallow aquifer system was performed with two injection types imitating short- and long-term CO2 leakage events into a shallow aquifer. One is pulse type leakage of CO2 (6 hours) under a natural hydraulic gradient (0.02) and the other is long-term continuous injection (30 days) under a forced hydraulic gradient (0.2). Injection and monitoring tests were performed at the K-COSEM site in Eumseong, Korea where a specially designed well field had been installed for artificial CO2 release tests. CO2-infused and tracer gases dissolved groundwater was injected through a well below groundwater table and monitoring were conducted in both saturated and unsaturated zones. Real-time monitoring data on CO2 concentration and hydrochemical parameters, and periodical measurements of several gas tracers (He, Ar, Kr, SF6) were obtained. The pulse type short-term injection test was carried out prior to the long-term injection test. Results of the short-term injection test, under natural hydraulic gradient, showed that CO2 plume migrated along the preferential pathway identified through hydraulic interference tests. On the other hand, results of the long-term injection test indicated the CO2 plume migration path was aligned to the forced hydraulic gradient. Compared to the short-term test, the long-term injection formed detectable CO2 concentration change in unsaturated wellbores. Recovery data of tracer gases made breakthrough curves compatible to numerical simulation results. The monitoring results indicated that detection of CO2 leakage into groundwater was more effectively performed by using a pumping and monitoring method in order to capture by-passing plume. With this concept, an effective real-time monitoring method was proposed. Acknowledgement: Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2storage" from the KEITI (Project number : 2014001810003)

Integrated Assessment to Evaluate the Artificial Recharge in a Small Portion of the Aquifer of Puebla, Mexico

NASA Astrophysics Data System (ADS)

Arango-Galván, C.; Flores-Marquez, L. E.; Martínez-Serrano, R.

2009-12-01

New policies on the use of water resources in Mexico have led to implement some alternative measures to optimize water management. In particular, water regulation entities have recommended some tools to preserve and protect the groundwater supplies. One of these tools is the artificial recharge by injecting water directly into the aquifer. The main goal of this study is to assess if it is suitable to inject rainwater and surface water in a small portion of the aquifer of the city of Puebla, in central Mexico. Artificial aquifer recharging was evaluated using a numeric model, which simulated the physical properties of the system. The model setup was inferred from an integrated study taking into account hydraulic, geological and geophysical data. The geoelectrical model was computed using electric resistivity tomography (ERT) and time domain electromagnetic data (TDEM). The aquifer geological structure inferred from geophysics depicts the presence of a shallower layer composed of sand and clay deposits with low saturation and permeability. This layer contains silt lenses that can be controlling the persistence of small water bodies on surface. Some water surficial bodies seem to be isolated from the main aquifer system. The intermediate layer shows lower electrical resistivity and higher permeability. Underlying this horizon, it is a deeper layer that reaches 200 m depth, according to information obtained from borehole in the zone. This layer shows an electrical resistivity even lower than intermediate layer but low permeability, caused by the higher content of silts. Both of these layers are the shallower aquifer exploited in the area. Once the numeric model was built we proceeded to simulate scenarios that include the continued extraction and recharge of water in wells located in strategic areas of the study zone. The results suggest that the effect of infiltration is beneficial on aquifer recharge and reduces the cone of depression caused by the extraction. However, this remedial action will only have a positive effect if the extraction rate is adequate.

Geohydrologic framework of the Roswell ground-water basin, Chaves and Eddy Counties, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Welder, G.E.

This report describes the geohydrology of the Roswell ground-water basin and shows the long-term hydrostatic-head changes in the aquifers. The Roswell ground-water basin consists of a carbonate artesian aquifer overlain by a leaky confining bed, which, in turn is overlain by an alluvial water-table aquifer. The water-table aquifer is hydraulically connected to the Pecos River. Ground-water pumpage from about 1500 wells in the basin was about 378,000 acre-feet in 1978. Irrigation use on about 122,000 acres accounted for 95% of that pumpage. Permeable zones in the artesian aquifer are generally controlled by lithologic changes in the Permian San Andres Limestonemore » and Grayburg Formation and by fractures in the carbonate rock. The thickness of the artesian aquifer in the more heavily pumped part of the basin ranges from 260 to 460 feet. The confining bed is composed of slightly to moderately permeable rocks of the Permian Grayburg, Queen, and Seven Rivers Formations. The shallow aquifer is composed of permeable beds of sand and gravel in the valley-fill alluvium, which is Pliocene, Pleistocene, and Holocene in age. In 1975, the maximum saturated thickness of the valley fill was about 250 feet in depressions northeast of Roswell, south of Dexter, and at Artesia. Hydrostatic heads in the artesian aquifer declined 230 feet in the south part of the basin from 1905 to 1975. The maximum decline in the head of the shallow aquifer from 1938 to 1975 was 120 feet. The chloride concentration of ground-water samples collected in 1978 ranged from 15 to 7000 milligrams per liter for the artesian aquifer and from 20 to 3700 milligrams per liter for the shallow aquifer. The chloride content has gradually increased through the years in the eastern parts of both aquifers. 31 refs., 28 figs., 1 tab.« less

Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer and intermediate aquifer system in southwest Florida

USGS Publications Warehouse

Sacks, Laura A.; Tihansky, Ann B.

1996-01-01

In southwest Florida, sulfate concentrations in water from the Upper Floridan aquifer and overlying intermediate aquifer system are commonly above 250 milligrams per liter (the drinking water standard), particularly in coastal areas. Possible sources of sulfate include dissolution of gypsum from the deeper part of the Upper Floridan aquifer or the middle confining unit, saltwater in the aquifer, and saline waters from the middle confining unit and Lower Floridan aquifer. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated for the Peace and Myakka River Basins and adjacent coastal areas of southwest Florida. Samples were collected from 63 wells and a saline spring, including wells finished at different depth intervals of the Upper Floridan aquifer and intermediate aquifer system at about 25 locations. Sampling focused along three ground-water flow paths (selected based on a predevelopment potentiometric-surface map). Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (delta deuterium, oxygen-18, carbon-13 of inorganic carbon, and sulfur-34 of sulfate and sulfide); the ratio of strontium-87 to strontium-86 was analyzed for waters along one of the flow paths. Chemical and isotopic data indicate that dedolomitization reactions (gypsum and dolomite dissolution and calcite precipitation) control the chemical composition of water in the Upper Floridan aquifer in inland areas. This is confirmed by mass-balance modeling between wells in the shallowest interval in the aquifer along the flow paths. However, gypsum occurs deeper in the aquifer than these wells. Upwelling of sulfate-rich water that previously dissolved gypsum in deeper parts of the aquifer is a more likely source of sulfate than gypsum dissolution in shallow parts of the aquifer. This deep ground water moves to shallower zones in the aquifer discharge area. Saltwater from the Upper Floridan aquifer has not dissolved significant amounts of gypsum compared to fresher water in the aquifer. This is consistent with a shallow seawater source for the saltwater, rather than a deeper source from the underlying middle confining unit or Lower Floridan aquifer, which would have elevated sulfate concentrations. Ion exchange and dolomitization may be important reactions for saltwater in the aquifer. According to geochemical modeling, the freshwater end member for water in the saltwater mixing zone in the southwestern part of the study area is not upgradient water from the Upper Floridan aquifer that dissolved gypsum. Instead, this water appears to be isolated from the regional freshwater flow system and may be part of a more localized flow system. The chemical and isotopic composition of water in the intermediate aquifer system is controlled by differences in extent of reactions with aquifer minerals, upward leakage from the Upper Floridan aquifer, and saltwater mixing. In inland areas, water generally is characterized by relatively low sulfate concentrations (less than 250 milligrams per liter) and differences in extent of carbonate mineral dissolution. Some inland waters have elevated chloride concentrations, which may be related to evaporation prior to recharge. In coastal Sarasota County and in isolated inland areas, water from the intermediate aquifer system has high sulfate concentrations characteristic of dedolomitization waters from the Upper Floridan aquifer. The chemical and isotopic composition of these waters is controlled by upward leakage from the Upper Floridan aquifer, which naturally occurs in the discharge area but may be locally enhanced by pumping or interconnection of wells open to both aquifer systems. In western Charlotte County, the waters are dominated by sodium and chloride, and their compositions are consistent with mixing between saltwater and inland intermediate aquifer system water that has not been influenced by discharge from the

Groundwater monitoring program plan and conceptual site model for the Al-Tuwaitha Nuclear Research Center in Iraq.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Copland, John Robin; Cochran, John Russell

2013-07-01

The Radiation Protection Center of the Iraqi Ministry of Environment is developing a groundwater monitoring program (GMP) for the Al-Tuwaitha Nuclear Research Center located near Baghdad, Iraq. The Al-Tuwaitha Nuclear Research Center was established in about 1960 and is currently being cleaned-up and decommissioned by Iraqs Ministry of Science and Technology. This Groundwater Monitoring Program Plan (GMPP) and Conceptual Site Model (CSM) support the Radiation Protection Center by providing: A CSM describing the hydrogeologic regime and contaminant issues, recommendations for future groundwater characterization activities, and descriptions of the organizational elements of a groundwater monitoring program. The Conceptual Site Model identifiesmore » a number of potential sources of groundwater contamination at Al-Tuwaitha. The model also identifies two water-bearing zones (a shallow groundwater zone and a regional aquifer). The depth to the shallow groundwater zone varies from approximately 7 to 10 meters (m) across the facility. The shallow groundwater zone is composed of a layer of silty sand and fine sand that does not extend laterally across the entire facility. An approximately 4-m thick layer of clay underlies the shallow groundwater zone. The depth to the regional aquifer varies from approximately 14 to 17 m across the facility. The regional aquifer is composed of interfingering layers of silty sand, fine-grained sand, and medium-grained sand. Based on the limited analyses described in this report, there is no severe contamination of the groundwater at Al-Tuwaitha with radioactive constituents. However, significant data gaps exist and this plan recommends the installation of additional groundwater monitoring wells and conducting additional types of radiological and chemical analyses.« less

Characterization of geochemical constituents and bacterial populations associated with As mobilization in deep and shallow tube wells in Bangladesh.

PubMed

Sutton, Nora B; van der Kraan, Geert M; van Loosdrecht, Mark C M; Muyzer, Gerard; Bruining, Johannes; Schotting, Ruud J

2009-04-01

While millions of people drink arsenic-contaminated tube well water across Bangladesh, there is no recent scientific explanation which is able to either comprehensively explain arsenic mobilization or to predict the spatial distribution of affected wells. Rather, mitigation strategies have focused on the sinking of deep tube wells into the currently arsenic-free Pleistocene aquifer. In this study, Bangladesh shallow tube wells identified as contaminated and uncontaminated, as well as deep tube wells, were analyzed for geochemical and in situ microbiological composition. Whereas arsenic was detected in all Holocene aquifer wells, no arsenic was found in wells accessing the Pleistocene aquifer. Bacterial genera, including Comamonadaceae, Acidovorax, Acinetobacter, and Hydrogenophaga, associated with tolerance of high arsenic concentrations, rather than dissimilatory Fe(III) or As(V) reduction, were identified in shallow tube wells, indicating that mobilization may not occur at depth, but is rather due to drawdown of surface contaminated water. Deep tube wells contained microbes indicative of aerobic conditions, including the genera Aquabacterium, Limnobacter, and Roseomonas. It is concluded that through drawdown of arsenic or organic matter, further utilization of the Pleistocene aquifer could result in contamination similar to that observed in the Holocene aquifer.

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

USGS Publications Warehouse

Landon, Matthew K.; Clark, Brian R.; McMahon, Peter B.; McGuire, Virginia L.; Turco, Michael J.

2008-01-01

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Evaluation of a predictive ground-water solute-transport model at the Idaho National Engineering Laboratory, Idaho

USGS Publications Warehouse

Lewis, Barney D.; Goldstein, Flora J.

1982-01-01

Aqueous chemical and radioactive wastes discharged to shallow ponds and to shallow or deep wells on the Idaho National Engineering Laboratory (INEL) since 1952 have affected the quality of the ground water in the underlying Snake River Plain aquifer. The aqueous wastes have created large and laterally dispersed concentration plumes within the aquifer. The waste plumes with the largest areal distribution are those of chloride , tritium, and with high specific conductance values. The data from eight wells drilled near the southern INEL boundary during the summer of 1980 were used to evaluate the accuracy of a predictive modeling study completed in 1973, and to simulate 1980 positions of chloride and tritium plumes. Data interpretation from the drilling program indicates that the hydrogeologic characteristics of the subsurface rocks have marked effects on the regional ground-water flow regimen and, therefore, the movement of aqueous wastes. As expected, the waste plumes projected by the computer model for 1980, extended somewhat further downgradient than indicated by well data due to conservative worst-case assumptions in the model input and inacurate approximations of subsequent waste discharge and aquifer recharge conditions. (USGS)

Urban land-use study plan for the National Water-Quality Assessment Program

USGS Publications Warehouse

Squillace, P.J.; Price, C.V.

1996-01-01

This study plan is for Urban Land-Use Studies initiated as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. There are two Urban Land-Use Study objectives: (1) Define the water quality in recharge areas of shallow aquifers underlying areas of new residential and commercial land use in large metropolitan areas, and (2) determine which natural and human factors most strongly affect the occurrence of contaminants in these shallow aquifers. To meet objective 1, each NAWQA Study Unit will install and collect water samples from at least 30 randomly located monitoring wells in a metropolitan area. To meet objective 2, aquifer characteristics and land-use information will be documented. This includes particle-size analysis of each major lithologic unit both in the unsaturated zone and in the aquifer near the water table. The percentage of organic carbon also will be determined for each lithologic unit. Geographic information system coverages will be created that document existing land use around the wells. These data will aid NAWQA personnel in relating natural and human factors to the occurrence of contaminants. Water samples for age dating also will be collected from all monitoring wells, but the samples will be stored until the occurrence of contaminants has been determined. Age-date analysis will be done only on those samples that have no detectable concentrations of anthropogenic contaminants.

Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

USGS Publications Warehouse

Katz, B.G.; Eberts, S.M.; Kauffman, L.J.

2011-01-01

A detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride-bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (0.5. mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5. mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells.The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from shallow wells (<20 m) with the range of 400-1100. The use of this ratio would be enhanced with information on other chloride sources, temporal variability of chloride and bromide concentrations in shallow groundwater, knowledge of septic-system age and maintenance, and the use of multiple tracers (combination of additional chemical and microbiological indicators). ?? 2010.

Hydrogeologic and hydraulic characterization of aquifer and nonaquifer layers in a lateritic terrain (West Bengal, India)

NASA Astrophysics Data System (ADS)

Biswal, Sabinaya; Jha, Madan K.; Sharma, Shashi P.

2018-02-01

The hydrogeologic and hydraulic characteristics of a lateritic terrain in West Bengal, India, were investigated. Test drilling was conducted at ten sites and grain-size distribution curves (GSDCs) were prepared for 275 geologic samples. Performance evaluation of eight grain-size-analysis (GSA) methods was carried out to estimate the hydraulic conductivity (K) of subsurface formations. Finally, the GSA results were validated against pumping-test data. The GSDCs indicated that shallow aquifer layers are coarser than the deeper aquifer layers (uniformity coefficient 0.19-11.4). Stratigraphy analysis revealed that both shallow and deep aquifers of varying thickness exist at depths 9-40 and 40-79 m, respectively. The mean K estimates by the GSA methods are 3.62-292.86 m/day for shallow aquifer layers and 0.97-209.93 m/day for the deeper aquifer layers, suggesting significant aquifer heterogeneity. Pumping-test data indicated that the deeper aquifers are leaky confined with transmissivity 122.69-693.79 m2/day, storage coefficient 1.01 × 10-7-2.13 × 10-4 and leakance 2.01 × 10-7-34.56 × 10-2 day-1. Although the K values yielded by the GSA methods are generally larger than those obtained from the pumping tests, the Slichter, Harleman and US Bureau Reclamation (USBR) GSA methods yielded reasonable values at most of the sites (1-3 times higher than K estimates by the pumping-test method). In conclusion, more reliable aquifers exist at deeper depths that can be tapped for dependable water supply. GSA methods such as Slichter, Harleman and USBR can be used for the preliminary assessment of K in lateritic terrains in the absence of reliable field methods.

Geoelectrical contribution for delineation the groundwater potential and subsurface structures on Tushka Area, Egypt

NASA Astrophysics Data System (ADS)

Abd El-Gawad, A. M. S.; Kotb, Adel D. M.; Hussien, Galal H. G.

2017-12-01

Tushka area represents the South East Western Desert, Egypt. its contain many drilled wells which have many problems during use, so the present study aims at identify the aquifer conditions and its relation with surface water and subsurface structure in addition to determine the aquifer thickness by using the basement relief from previous work, then assess the current situation of the drilled water wells. Geoelectrical data were measured, processed and interpreted in one, two and three dimensions using special Equipments and software. The interpretation results demonstrated that two types of groundwater aquifers (confined and unconfined) are present in the study area. The confined aquifer is located at the south of Khor Tushka and the unconfined aquifer is found in the north of Khor Tushka, where the last one is charged from Lake Nasser and Khor Tushka. The groundwater aquifers thicknesses are up to 440 m and the area is affected by normal faults of NW-SE and NE-SW trends. The study showed that there is no connection between the confined aquifer and the shallow overlaying aquifer. The confined aquifer is charged partially from the lake Nasser and Khor Tushka through specific areas under the capping layers of Nubian sandstone filled with hydrothermal solution and shale.

Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

DOE PAGES

Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.; ...

2016-05-11

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a 6-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species inmore » reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Thus, reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.« less

Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a 6-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species inmore » reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Thus, reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.« less

Hydrology and surface morphology of the Bonneville Salt Flats and Pilot Valley Playa, Utah

USGS Publications Warehouse

Lines, Gregory C.

1979-01-01

The Bonneville Salt Flats and Pilot Valley are in the western part of the Great Salt Lake Desert in northwest Utah. The areas are separate, though similar, hydrologic basins, and both contain a salt crust. The Bonneville salt crust covered about 40 square miles in the fall of 1976, and the salt crust in Pilot Valley covered 7 square miles. Both areas lack any noticeable surface relief (in 1976, 1.3 feet on the Bonneville salt crust and 0.3 foot on the Pilot Valley salt crust).The salt crust on the Salt Flats has been used for many years for automobile racing, and brines from shallow lacustrine deposits have been used for the production of potash. In recent years, there has been an apparent conflict between these two major uses of the area as the salt crust has diminished in both thickness and extent. Much of the Bonneville Racetrack has become rougher, and there has also been an increase in the amount of sediment on the south end of the racetrack. The Pilot Valley salt crust and surrounding playa have been largely unused.Evaporite minerals on the Salt Flats and the Pilot Valley playa are concentrated in three zones: (1) a carbonate zone composed mainly of authigenic clay-size carbonate minerals, (2) a sulfate zone composed mainly of authigenic gypsum, and (3) a chloride zone composed of crystalline halite (the salt crust). Five major types of salt crust were recognized on the Salt Flats, but only one type was observed in Pilot Valley. Geomorphic differences in the salt crust are caused by differences in their hydrologic environments. The salt crusts are dynamic features that are subject to change because of climatic factors and man's activities.Ground water occurs in three distinct aquifers in much of the western Great Salt Lake Desert: (1) the basin-fill aquifer, which yields water from conglomerate in the lower part of the basin fill, (2) the alluvial-fan aquifer, which yields water from sand and gravel along the western margins of both playas, and (3) the shallow-brine aquifer, which yields water from near-surface carbonate muds and crystalline halite and gypsum. The shallow-brine aquifer is the main source of brine used for the production of potash on the Salt Flats.Recharge to that part of the shallow-brine aquifer north of Interstate Highway 80 on the Salt Flats is mainly by infiltration of precipitation and wind-driven floods of surface brine. Discharge was mainly by evaporation at the playa surface and withdrawals from brine-collection ditches. Some water was transpired by phreatophytes, and some leaked into the alluvial fan along the western edge of the playa.Salt-scraping studies indicate that the amount of halite on the Salt Flats is directly related to the amount of recharge through the surface (which causes re-solution of halite) and the amount of evaporation at the surface (which causes crystallization of halite). Evaporation rates through sediment-covered salt crust and the gypsum surface were estimated at between 3x10-4 and 4x10-3 inches per day during the summer and fall of 1976. Evaporation rates through the surface of thick perennial salt crust were much higher.The concentration of dissolved solids in brine in the shallow-brine aquifer varies, but it generally increases from the edges of the playas toward areas of salt crust. Dissolved-solids concentration in the shallow brine ranges from less than 100,000 to more than 300,000 milligrams per liter on both playas. The increase in salinity toward areas of salt crust reflects the natural direction of brine movement through the aquifer toward the natural discharge area.On the Salt Flats, the percentages of dissolved potassium chloride and magnesium chloride in the shallow-brine aquifer generally increase from the edge of the playa to- ward the salt crust. The relative enrichment in potassium and magnesium reflects the many years of subsurface drainage toward the main discharge area (the salt crust) prior to man's withdrawal of brine. By artificially extracting brines from the carbonate muds, the percentages of potassium and magnesium have decreased while brine salinity has been maintained by re-solution of the salt crust.The configuration of the density-corrected potentiometric surface in the fall of 1976 indicates that brine in the shallow-brine aquifer under the Bonneville Racetrack was draining toward brine-collection ditches or a well field to the west. Ground-water divides have no effect on the movement of dissolved salt across the surface in wind-driven floods, and salt in surface brine was carried from the racetrack into the area of influence of the ditches by such surface movement. During 1976 on the Salt Flats, some brine was moving through the shallow-brine aquifer across lease and property boundaries.An evaluation of suggested remedial measures indicates that none will completely eliminate the conflict between uses or transform the Bonneville Salt Flats to its original state prior to man's activities in the area.

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

USGS Publications Warehouse

Burton, Carmen; Wright, Michael

2018-05-30

Groundwater quality in the approximately 7,820-square-kilometer (km2) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory.The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km2), Pajaro Valley (360 km2), Salinas Valley (2,000 km2), and Highlands (5,250 km2).This study had two primary components: the status assessment and the understanding assessment. The first primary component of this study—the status assessment—assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system.Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low.Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids.Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA (N-nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit.Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions.Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems.Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater.The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater.The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater.Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater.The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however.Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture.Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

Understanding the fate of sanitation-related nutrients in a shallow sandy aquifer below an urban slum area.

PubMed

Nyenje, P M; Havik, J C N; Foppen, J W; Muwanga, A; Kulabako, R

2014-08-01

We hypothesized that wastewater leaching from on-site sanitation systems to alluvial aquifers underlying informal settlements (or slums) may end up contributing to high nutrient loads to surface water upon groundwater exfiltration. Hence, we conducted a hydro-geochemical study in a shallow sandy aquifer in Bwaise III parish, an urban slum area in Kampala, Uganda, to assess the geochemical processes controlling the transport and fate of dissolved nutrients (NO3, NH4 and PO4) released from on-site sanitation systems to groundwater. Groundwater was collected from 26 observation wells. The samples were analyzed for major ions (Ca, Mg, Na, Mg, Fe, Mn, Cl and SO4) and nutrients (o-PO4, NO3 and NH4). Data was also collected on soil characteristics, aquifer conductivity and hydraulic heads. Geochemical modeling using PHREEQC was used to determine the level of o-PO4 control by mineral solubility and sorption. Groundwater below the slum area was anoxic and had near neutral pH values, high values of EC (average of 1619μS/cm) and high concentrations of Cl (3.2mmol/L), HCO3 (11mmol/L) and nutrients indicating the influence from wastewater leachates especially from pit latrines. Nutrients were predominantly present as NH4 (1-3mmol/L; average of 2.23mmol/L). The concentrations of NO3 and o-PO4 were, however, low: average of 0.2mmol/L and 6μmol/L respectively. We observed a contaminant plume along the direction of groundwater flow (NE-SW) characterized by decreasing values of EC and Cl, and distinct redox zones. The redox zones transited from NO3-reducing in upper flow areas to Fe-reducing in the lower flow areas. Consequently, the concentrations of NO3 decreased downgradient of the flow path due to denitrification. Ammonium leached directly into the alluvial aquifer was also partially removed because the measured concentrations were less than the potential input from pit latrines (3.2mmol/L). We attributed this removal (about 30%) to anaerobic ammonium oxidation (anammox) given that the cation exchange capacity of the aquifer was low (<6meq/100g) to effectively adsorb NH4. Phosphate transport was, on the other hand, greatly retarded and our results showed that this was due to the adsorption of P to calcite and the co-precipitation of P with calcite and rhodochrosite. Our findings suggest that shallow alluvial sandy aquifers underlying urban slum areas are an important sink of excessive nutrients leaching from on-site sanitation systems. Copyright © 2014 Elsevier B.V. All rights reserved.

Shallow, non-pumped wells: a low-energy alternative for cleaning polluted groundwater.

PubMed

Hudak, Paul F

2013-07-01

This modeling study evaluated the capability of non-pumped wells with filter media for preventing contaminant plumes from migrating offsite. Linear configurations of non-pumped wells were compared to permeable reactive barriers in simulated shallow homogeneous and heterogeneous aquifers. While permeable reactive barriers enabled faster contaminant removal and shorter distances of contaminant travel, non-pumped wells also prevented offsite contaminant migration. Overall, results of this study suggest that discontinuous, linear configurations of non-pumped wells may be a viable alternative to much more costly permeable reactive barriers for preventing offsite contaminant travel in some shallow aquifers.

Development of composting plant rock surrounding pollution. Case study - Točna in Příbor, The Czech Republic

NASA Astrophysics Data System (ADS)

Ondrasikova, I.; Stancl, L.

2017-10-01

Composting plant Točna utilize and modifies biologically biodegradable waste by aerobic fermentation method. After emergency leakage of leachate water in 2010 the quality of rock surrounding is being regularly monitored in the range of indicators: pH, conductivity, COD (chemical oxygen demand, Cr), HCO3 -, Cl-, N-NH4 +, N-NO3 -, N-NO2 - and humic substances. Technical adjustments of the interest area has been also made to prevent leakage of contaminated water. Locality monitoring system is ensured separately for shallow backfill aquifer and deeper quaternary aquifer. Protective hydraulic barrier is running at the same time to prevent effluent of shallow water to groundwater. Nitrogenous substances (above all ammonium ions) and humic substances belongs among main groundwater contaminants of the interest area. Peak concentration level of this substances is connected with shallow backfill aquifer, near south-east and east edge of the locality, not in general quaternary water direction. From long-term monitoring results follows that concentration of monitored substances is gradually decreasing, especially in water connected with backfill layer. Drier weather of last year helps to this development. Quality of quaternary aquifer is not influenced significantly, only locally in spots, in the places of both aquifers connection where increase of ammonium ions occurs as result of humic substance decomposition. In effect, monitored substances are not disseminated in quaternary aquifer.

Geologic Maps and Cross Sections of the Tuba City Open Dump Site and Vicinity, With Implications for the Occurrence and Flow of Ground Water

USGS Publications Warehouse

Otton, James K.; Johnson, Ray H.; Horton, Robert J.

2008-01-01

This report is designed to make available to interested parties geologic and limited hydrologic and geochemical information about the Tuba City Open Dump (TCOD) site. This information has been gathered during studies of the site from January to September 2008. Mapping by the authors and construction of cross sections show that a section of gently northeast-dipping Jurassic sedimentary rocks underlies the TCOD and vicinity. Low mesas in the area are capped by variably cemented gravels and siliceous limestones. Surficial sediments are composed of eolian sand and fluvially reworked eolian sand that overlie bedrock underneath the TCOD. Nearby Pasture Canyon is underlain by fluvial and floodplain sediment consisting of sand and silt. Shallow ground water of the water-table aquifer at the TCOD moves westward through the surficial sediment and the underlying weathered bedrock to Pasture Canyon then southward along the canyon. A fracture zone extends up the wash that passes just to the north of the TCOD and brings deeper ground water of the N-aquifer to the water-table aquifer. Bedrock consists of the Jurassic Navajo Sandstone composed of thick sections of eolian crossbedded sandstone with lesser laterally discontinuous layers of silty sandstone, siltstone, and limestone. Below the Navajo Sandstone is a section informally known as the Kayenta Formation-Navajo Sandstone transition zone. It is composed of calcareous sandstone, silty sandstone, siltstone, and limestone beds that intertongue with crossbedded sandstone. The finer grained rocks in both major bedrock units form aquitards that limit downward movement of ground water. The water-table aquifer is perched on these aquitards, which locally occurs beneath the two open dumps that form the TCOD site. A monocline occupies the position of Pasture Canyon west of the TCOD. Fractures likely related to the monocline are exposed in several localities. Deep ground waters consist of dilute calcium-bicarbonate waters low in all trace elements. Shallow ground water is variably affected by near-surface processes, which add varying amounts of sodium, chloride, sulfate, and trace elements. Locally, human influences, such as the TCOD, affect shallow ground-water chemistry.

First step to understand the importance of new deep aquifer pumping regime in groundwater system in a developing country, Kwale, Kenya.

NASA Astrophysics Data System (ADS)

Ferrer, Nuria; Folch, Albert; Lane, Mike; Thomas, Mike; Sasaka, Willie; Wara, Calvince; Banje, Said; Olago, Dan; Katuva, Jacob; Thomson, Patrick; Hope, Rob

2016-04-01

The population growth in the world carries on the one hand, an increased demand of fresh water and on the other hand, a decrease of quality and quantity of this resource. To avoid this deterioration it is essential doing a good management of surface water and groundwater, specially the second one, which has become the major source of water supply for domestic, industrial and agricultural sectors of many countries (UNEP 1999). This groundwater management starts with an accurate hydrogeological characterization of aquifer systems, mainly in that aquifer systems in which is changing the abstraction regime. In this context of population growth and new abstraction regimes on aquifer system is where the project "Gro for Good: Groundwater Risk for Growth and Development" is founded by UPGro. This interdisciplinary project has the main goal to design, test and transfer to the society an innovative Groundwater Risk Management Tool to improve and get by new governance transformations the balance between economic growth, groundwater sustainability (in terms of quality and quantity) and human development (http://upgro.org/consortium/gro-for-good/). The study area is located on the south eastern coast of Kenya, in Kwale County. The Kwale coastal groundwater system formed by a shallow and deep aquifer systems has long served urban water demands and an established tourism industry but now faces unprecedented ground and surface water resource demands especially from KISCOL's (5,500 hectares of irrigated sugarcane) and the country's largest mining operation (Base Titanium Ltd.). Despite both companies have drilled deep boreholes around the study area (416 km2) to extract groundwater from deep aquifer; no major pumping activity has started yet, allowing baseline evaluation. Scattered around the study are 440 handpumps providing drinking water to over 90,000 people. The relationship between the shallow and deep aquifers remains uncertain and so, the future influence on groundwater level and its quality either. So, in order to define the system and start to understand the different complex interactions, we present the initial results of the first complete water sampling field campaign (September 2015). Water isotope data and major ions were analyzed from 78 shallow and deep wells and surface water spread around study area. This field survey has been useful to understand the recharge, discharge areas and groundwater quality of deep aquifer system and which will have an important role for sustainable water management in the of Kwale area. Acknowledgements The research is primarily supported under the NERC/ESRC/DFID Unlocking the Potential of Groundwater for the Poor (UPGro) as a Catalyst Grant (NE/L001950/1) with work extending until 2019 as a Consortium Grant (NE/M008894/1), see http://www.upgro.org. Data for the paper will be publicly posted on the National Geoscience Data Centre and the UK Data Archive under the terms of the UPGro data management agreement.

Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia.

PubMed

Guo, Huaming; Zhang, Bo; Li, Yuan; Berner, Zsolt; Tang, Xiaohui; Norra, Stefan; Stüben, Doris

2011-04-01

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO₄²⁻ concentrations and δ³⁴S values indicates that bacterial reduction of SO₄²⁻ occurs in reducing aquifers. Due to high concentrations of Fe (> 0.5 mg L⁻¹), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. Copyright © 2011 Elsevier Ltd. All rights reserved.

Assessment of groundwater contamination by landfill leachate: a case in México.

PubMed

Reyes-López, Jaime A; Ramírez-Hernández, Jorge; Lázaro-Mancilla, Octavio; Carreón-Diazconti, Concepción; Garrido, Miguel Martín-Loeches

2008-01-01

In México, uncontrolled landfills or open-dumps are regularly used as "sanitary landfills". Interactions between landfills/open-dumps and shallow unconfined aquifers have been widely documented. Therefore, evidence showing the occurrence of aquifer contamination may encourage Mexican decision makers to enforce environmental regulations. Traditional methods such as chemical analysis of groundwater, hydrological descriptions, and geophysical studies including vertical electrical sounding (VES) and ground penetrating radar (GPR) were used for the identification and delineation of a contaminant plume in a shallow aquifer. The Guadalupe Victoria landfill located in Mexicali is used as a model study site. This landfill has a shallow aquifer of approximately 1m deep and constituted by silty sandy soil that may favor the transport of landfill leachate. Geophysical studies show a landfill leachate contaminant plume that extends for 20 and 40 m from the SE and NW edges of the landfill, respectively. However, the zone of the leachate's influence stretches for approximately 80 m on both sides of the landfill. Geochemical data corroborates the effects of landfill leachate on groundwater.

Detection of Potential Shallow Aquifer Using Electrical Resistivity Imaging (ERI) at UTHM Campus, Johor Malaysia

NASA Astrophysics Data System (ADS)

Izzaty Riwayat, Akhtar; Nazri, Mohd Ariff Ahmad; Hazreek Zainal Abidin, Mohd

2018-04-01

In recent years, Electrical Resistivity Imaging (ERI) has become part of important method in preliminary stage as to gain more information in indicate the hidden water in underground layers. The problem faces by engineers is to determine the exact location of groundwater zone in subsurface layers. ERI seen as the most suitable tools in exploration of groundwater as this method have been applied in geotechnical and geo-environment investigation. This study was conducted using resistivity at UTHM campus to interpret the potential shallow aquifer and potential location for borehole as observation well. A Schlumberger array was setup during data acquisition as this array is capable in imaging deeper profile data and suitable for areas with homogeneous layer. The raw data was processed using RES2DINV software for 2D subsurface image. The result obtained indicate that the thickness of shallow aquifer for both spread line varies between 7.5 m to 15 m. The analysis of rest raw data using IP showed that the chargeability parameter is equal to 0 which strongly indicated the presence of groundwater aquifer in the study area.

Ground-water levels in aquifers used for residential supply, Campton Township, Kane County, Illinois

USGS Publications Warehouse

Kay, Robert T.; Kraske, Kurt A.

1996-01-01

The U.S. Geological Survey, in cooperation with the Campton Township Board of Trustees, measured water levels in the aquifers used for residential supply in Campton Township, Kane County, Illinois. Aquifers used for residential supply are the shallow and deep aquifers in the glacial drift, composed of unconsolidated sand and gravels; the Alexandrian-Maquoketa aquifer, composed of dolomite and shale of the Alexandrian Series and the Maquoketa Group; the Galena-Platteville aquifer, composed of dolomite of the Platteville and Galena Groups; and the Ancell aquifer, composed of sandstones of the Glenwood Formation and the St. Peter Sanstone. Water-level altitudes in the shallow drift aquifers generally follow surface topography. Analysis of water-level data does not clearly indicate overutilization of these aquifers. Water-level altitudes in the deep drift aquifers decrease from west to east. Comparison of historical depth to water measurements with current (1995) measurements indicates large decreases in water levels in some areas. The deep drift aquifers may be overutilized at these locations. Water-level altitudes in the Alexandrian-Maquoketa aquifer generally decrease from west to east. The potentiometric surface of the aquifer follows the bedrock-surface topography in some locations. Localized low water-level altitudes and large decreases in water levels indicate the Alexandrian-Maquoketa aquifer is overutilized in several areas. Water-level altitudes in the wells finished in the Galena- Platteville aquifer vary by more than 300 feet. Large decreases in water levels in wells finished in the Galena-Platteville aquifer indicate the Galena-Platteville and Alexandrian-Maquoketa aquifers are overutilized in the northern part of the township. Water-level altitudes in the wells finished in the Ancell aquifer are also highly variable. There is no indication that the Ancell aquifer is overutilized.

Assessment of water resources in lead-zinc mined areas in Cherokee County, Kansas, and adjacent areas

USGS Publications Warehouse

Spruill, Timothy B.

1987-01-01

A study was conducted to evaluate water-resources problems related to abandoned lead and zinc mines in Cherokee County, Kansas, and adjacent areas in Missouri and Oklahoma. Past mining activities have caused changes in the hydrogeology of the area. Lead and zinc mining has caused discontinuities and perforations in the confining shale west of the Pennsylvanian-Mississippian geologic contact (referred to as the western area), which have created artificial ground-water recharge and discharge areas. Recharge to the shallow aquifer (rocks of Mississippian age) through collapses, shafts, and drill holes in the shale has caused the formation of a ground-water 'mound' in the vicinity of the Picher Field in Kansas and Oklahoma. Discharge of mine-contaminated ground water to Tar Creek occurs in Oklahoma from drill holes and shafts where the potentiometric surface of the shallow aquifer is above the land surface. Mining of ore in the shallow aquifer has resulted in extensive fracturing and removal of material, which has created highly transmissive zones and voids and increased ground-water storage properties of the aquifer. In the area east of the Pennsylvanian-Mississippian geologic contact (referred to as the eastern area), fractured rock and tailings on the land surface increased the amount of water available for infiltration to the shallow aquifer; in the western area, tailings on the impermeable shale created artificial, perched aquifer systems that slowly drain to surface streams. Pumping of the deep aquifer (rocks of Cambrian and Ordovician age) by towns and industries, which developed as a result of the mining industry, has resulted in a potential for downward movement of water from the shallow aquifer. The potential is greatest in Ottawa County, Oklahoma. Because of the large volume of water that may be transported from the shallow to the deep aquifer, open drill holes or casings present the greatest contamination hazard to water supplies in the deep aquifer. Mining allowed oxidation of ore deposits which, on saturation with water, resulted in poor-quality water that generally contains large concentrations of sulfate and trace metals. Water from mines in the eastern area contained dissolved-solids concentrations of less than 500 mg/L (milligrams per liter), a median pH of 3.9, sulfate concentrations that ranged between 98 and 290 mg/L, and median concentrations for zinc of 37,600 micrograms/L (micrograms per liter), for lead of 240 micrograms/L, for cadmium of 180 micrograms/L, for iron of 70 micrograms/L, for manganese of 240 micrograms/L, and for silica of 15 mg/L. Water from mines in the western area contained dissolved-solids concentrations of generally more than 500 mg/L, a median pH of 6.8, sulfate concentrations that ranged between 170 and 2,150 mg/L, and median concentrations for zinc of 3,200 micrograms/L, for lead of 0 micrograms/L (minimum detection limit is 10 micrograms/L), for cadmium of 6 micrograms/L, for iron of 840 micrograms/L, for manganese of 440 micrograms/L, and for silica of 11 mg/L. No conclusive evidence of lateral migration of water from the mines into domestic well-water supplies in the shallow aquifer was found in the study area in Kansas. Analyses of water from public-supply wells tapping the deep aquifer did not indicate contamination with trace metals, although chemical analyses from four of six wells exhibited increasing trends through time in sulfate concentrations. These increases probably reflect localized leakage of water from the shallow aquifer along corroded or leaky well casings. Effects of abandoned lead and zinc mines on tributaries of the Spring River in the eastern area are most severe in Short Creek. Compared with water samples from three other major streams in the eastern area, a sample collected from Short Creek, 2 miles west of Galena, Kansas, during August 1981, contained the largest concentrations of dissolved sulfate (240 mg/L), zinc (25,000 micrograms/L), ca

Early warning of freshwater salinization due to upward brine displacement by species transport simulations combined with a hydrochemical genesis model

NASA Astrophysics Data System (ADS)

Langer, Maria; Kühn, Michael

2016-04-01

Shallow groundwater resources could be possibly affected by intruding brines, which are displaced along hydraulically conductive faults as result of subsurface activities like CO2 injection. To avoid salinization of potable freshwater aquifers an early detection of intruding saline water is necessary, especially in regions where an initial geogenic salinization already exists. Our study is based on work of Tillner et al. [1] and Langer et al. [2] who investigated the influence of permeable fault systems on brine displacement for the prospective storage site Beeskow-Birkholz in the Northeast German Basin. With a 3D regional scale model considering the deep groundwater system, they demonstrated that the existence of hydraulically conductive faults is not necessarily an exclusion criterion for potential injection sites, because salinization of shallower aquifers strongly depends on the effective damage zone volume, the initial salinity distribution and overlying reservoirs [2], while permeability of fault zones does not influence salinization of shallower aquifers significantly [1]. Here we extracted a 2D cross section regarding the upper 220 m of the study area mainly represented by shallow freshwater aquifers, but also considering an initial geogenic salinization [3]. We took flow rates of the intruding brines from the previous studies [2] and implemented species transport simulations with the program code SHEMAT [4]. Results are investigated and interpreted with the hydrochemical genesis model GEBAH [5] which has been already applied as early warning of saltwater intrusions into freshwater aquifers and surface water [6]. GEBAH allows a categorization of groundwater by the ion ratios of the dissolved components and offers a first indicative determination for an existence and the intensity of saline water intrusion in shallow groundwater aquifer, independent of the concentration of the solution. With our model we investigated the migration of saline water through a fault or an erosional channel which both allows an exchange between the shallow freshwater and the deeper saline water complex. The salinization potential of a drinking water well in vicinity to the brine source was determined for different scenarios. [1] Tillner E., Kempka T., Nakaten B., Kühn M. (2013) Brine migration through fault zones: 3D numerical simulations for a prospective CO2 storage site in Northeast Germany. International Journal of Greenhouse Gas Control 19, 689-703. doi: 10.1016/ j.ijggc.2013.03.012 [2] Langer M., Tillner E., Kempka T., Kühn M. (2015) Effective damage zone volume of fault zones and initial salinity distribution determine intensity of shallow aquifer salinization in geological underground utilization. Hydrology and Earth System Sciences Discussion, 12, 5703-5748. doi: 10.5194/hessd-12-5703-2015 [3] Hotzan, G., and Voss, T. (2013): Complex hydrogeochemic-genetic mapping for evaluation of the endangerment of pleistocene and tertiary aquifers by saline waters in the region Storkow-Frankfurt (Oder)-Eisenhüttenstadt. Brandenburgische Geowissenschaftliche Beiträge, 20 (1/2), 62-82. (in German) [4] Clauser C. (2003) SHEMAT and Processing SHEMAT - Numerical simulation of reactive flow in hot aquifers, Springer Publishers, Heidelberg [5] Rechlin, B., Hoffknecht, A., Scholz, H., Helms, A. (2010): Genetic evaluation of analyses from the hydrosphere. Software GEBAH Vers. 1.1 LBGR/GCI, Cottbus, Königs Wusterhausen (in German) [6] Rechlin, B. (2008): A method for a concentration free early detection of saltwater intrusions into freshwater aquifers and surface water. Brandenburgische Geowissenschaftliche Beiträge, 15 (1/2), 57-68. (in German)

Deformation-induced changes in hydraulic head during ground-water withdrawal

USGS Publications Warehouse

Hsieh, Paul A.

1996-01-01

Ground-water withdrawal from a confined or semiconfined aquifer causes three-dimensional deformation in the pumped aquifer and in adjacent layers (overlying and underlying aquifers and aquitards). In response to the deformation, hydraulic head in the adjacent layers could rise or fall almost immediately after the start of pumping. This deformation-induced effect suggest that an adjacent layer undergoes horizontal compression and vertical extension when pumping begins. Hydraulic head initially drops in a region near the well and close to the pumped aquifer, but rises outside this region. Magnitude of head change varies from a few centimeters to more than 10 centimeters. Factors that influence the development of deformation-induced effects includes matrix rigidity (shear modulus), the arrangement of aquifer and aquitards, their thicknesses, and proximity to land surface. Induced rise in hydraulic head is prominent in an aquitard that extends from land surface to a shallow pumped aquifer. Induced drop in hydraulic head is likely observed close to the well in an aquifer that is separated from the pumped aquifer by a relatively thin aquitard. Induced effects might last for hours in an aquifer, but could persist for many days in an aquitard. Induced effects are eventually dissipated by fluid flow from regions of higher head to regions of lower head, and by propagation of drawdown from the pumped aquifer into adjacent layers.

Effects of Hurricane Katrina’s storm surge on the quality of shallow aquifers near the northern shoreline of Lake Pontchartrain, southeastern Louisiana: Chapter 7D in Science and the storms-the USGS response to the hurricanes of 2005

USGS Publications Warehouse

Tomaszewski, Dan J.; Lovelace, John K.

2007-01-01

The U.S. Geological Survey (USGS) sampled 13 wells on the northern shoreline of Lake Pontchartrain to determine the effect of Hurricane Katrina-induced storm surge water on the shallow groundwater resources. Surge water entering damaged wells did not contaminate the entire aquifer; however, contamination did occur locally at well sites. Because the storm surge from Katrina lasted only a few hours, surge water entering the aquifer will probably have only a short-term effect.

Entrainment of viruses from septic tank leach fields through a shallow, sandy soil aquifer.

PubMed

Vaughn, J M; Landry, E F; Thomas, M Z

1983-05-01

A study was conducted which focused on movement of naturally occurring human enteroviruses from a subsurface wastewater disposal system through a shallow aquifer. The potential for significant entrainment of virus particles was evidenced by their recovery at down-gradient distances of 67.05 m and from aquifer depths of 18 m. A significant negative correlation was observed between virus occurrence and the distance from the "septage" (leaching pool) source. Virus occurrence could not be statistically correlated with either total or fecal coliforms, indicating the limitations of current microbial water quality indicators for predicting the virological quality of groundwater.

Chlorate origin and fate in shallow groundwater below agricultural landscapes.

PubMed

Mastrocicco, Micòl; Di Giuseppe, Dario; Vincenzi, Fabio; Colombani, Nicolò; Castaldelli, Giuseppe

2017-12-01

In agricultural lowland landscapes, intensive agricultural is accompanied by a wide use of agrochemical application, like pesticides and fertilizers. The latter often causes serious environmental threats such as N compounds leaching and surface water eutrophication; additionally, since perchlorate can be present as impurities in many fertilizers, the potential presence of perchlorates and their by-products like chlorates and chlorites in shallow groundwater could be a reason of concern. In this light, the present manuscript reports the first temporal and spatial variation of chlorates, chlorites and major anions concentrations in the shallow unconfined aquifer belonging to Ferrara province (in the Po River plain). The study was made in 56 different locations to obtain insight on groundwater chemical composition and its sediment matrix interactions. During the monitoring period from 2010 to 2011, in June 2011 a nonpoint pollution of chlorates was found in the shallow unconfined aquifer belonging to Ferrara province. Detected chlorates concentrations ranged between 0.01 and 38 mg/l with an average value of 2.9 mg/l. Chlorates were found in 49 wells out of 56 and in all types of lithology constituting the shallow aquifer. Chlorates concentrations appeared to be linked to NO 3 - , volatile fatty acids (VFA) and oxygen reduction potential (ORP) variations. Chlorates behaviour was related to the biodegradation of perchlorates, since perchlorates are favourable electron acceptors for the oxidation of labile dissolved organic carbon (DOC) in groundwater. Further studies must take into consideration to monitor ClO 4 - in pore waters and groundwater to better elucidate the mass flux of ClO 4 - in shallow aquifers belonging to agricultural landscapes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Map showing the altitude and configuration of the water level in the shallow aquifer, January 1975, Roswell Basin, Chaves and Eddy counties, New Mexico

USGS Publications Warehouse

Welder, G.E.

1977-01-01

The altitude and gradient of the water table in the ' shallow aquifer ' of the Roswell basin in Chaves and Eddy Counties, New Mexico, for January 1975 is shown on a map, scale of 1/2-inch per mile. The map was prepared by the U.S. Geological Survey in cooperation with the New Mexico State Engineer Office. (Woodard-USGS)

Map showing the altitude and configuration of the water level in the shallow aquifer, January 1964, Roswell Basin, Chaves and Eddy counties, New Mexico

USGS Publications Warehouse

Welder, G.E.

1977-01-01

The altitude and gradient of the water table in the ' shallow aquifer ' of the Roswell basin in Chaves and Eddy Counties, New Mexico, for January 1964 is shown on a map, scale of 1/2-inch per mile. The map was prepared by the U.S. Geological Survey in cooperation with the New Mexico State Engineer Office. (Woodard-USGS)

Groundwater quality in the North San Francisco Bay shallow aquifer, California

USGS Publications Warehouse

Bennett, George L.; Fram, Miranda S.

2018-02-23

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The North San Francisco Bay Shallow Aquifer constitutes one of the study units being evaluated.

Remediating Contaminant Plumes in Groundwater with Shallow Excavations Containing Coarse Reactive Media.

PubMed

Hudak, Paul F

2018-02-01

A groundwater flow and mass transport model tested the capability of shallow excavations filled with coarse, reactive media to remediate a hypothetical unconfined aquifer with a maximum saturated thickness of 5 m. Modeled as contaminant sinks, the rectangular excavations were 10 m downgradient of an initial contaminant plume originating from a source at the top of the aquifer. The initial plume was approximately 259 m long, 23 m wide, and 5 m thick, with a downgradient tip located approximately 100 m upgradient of the site boundary. The smallest trench capable of preventing offsite migration was 11 m long (measured perpendicular to groundwater flow), 4 m wide (measured parallel to groundwater flow), and 3 m deep. Results of this study suggest that shallow trenches filled with coarse filter media that partially penetrate unconfined aquifers may be a viable alternative for remediating contaminated groundwater at some sites.

Groundwater movement, recharge, and perchlorate occurrence in a faulted alluvial aquifer in California (USA)

USGS Publications Warehouse

Izbicki, John A.; Teague, Nicholas F.; Hatzinger, Paul B.; Böhlke, John Karl; Sturchio, Neil C.

2015-01-01

Perchlorate from military, industrial, and legacy agricultural sources is present within an alluvial aquifer in the Rialto-Colton groundwater subbasin, 80 km east of Los Angeles, California (USA). The area is extensively faulted, with water-level differences exceeding 60 m across parts of the Rialto-Colton Fault separating the Rialto-Colton and Chino groundwater subbasins. Coupled well-bore flow and depth-dependent water-quality data show decreases in well yield and changes in water chemistry and isotopic composition, reflecting changing aquifer properties and groundwater recharge sources with depth. Perchlorate movement through some wells under unpumped conditions from shallower to deeper layers underlying mapped plumes was as high as 13 kg/year. Water-level maps suggest potential groundwater movement across the Rialto-Colton Fault through an overlying perched aquifer. Upward flow through a well in the Chino subbasin near the Rialto-Colton Fault suggests potential groundwater movement across the fault through permeable layers within partly consolidated deposits at depth. Although potentially important locally, movement of groundwater from the Rialto-Colton subbasin has not resulted in widespread occurrence of perchlorate within the Chino subbasin. Nitrate and perchlorate concentrations at the water table, associated with legacy agricultural fertilizer use, may be underestimated by data from long-screened wells that mix water from different depths within the aquifer.

Reductive dissolution and reactive solute transport in a sewage-contaminated glacial outwash aquifer

USGS Publications Warehouse

Lee, R.W.; Bennett, P.C.

1998-01-01

Contamination of shallow ground water by sewage effluent typically contains reduced chemical species that consume dissolved oxygen, developing either a low oxygen geochemical environment or an anaerobic geochemical environment. Based on the load of reduced chemical species discharged to shallow ground water and the amounts of reactants in the aquifer matrix, it should be possible to determine chemical processes in the aquifer and compare observed results to predicted ones. At the Otis Air Base research site (Cape Cod, Massachusetts) where sewage effluent has infiltrated the shallow aquifer since 1936, bacterially mediated processes such as nitrification, denitrification, manganese reduction, and iron reduction have been observed in the contaminant plume. In specific areas of the plume, dissolved manganese and iron have increased significantly where local geochemical conditions are favorable for reduction and transport of these constituents from the aquifer matrix. Dissolved manganese and iron concentrations ranged from 0.02 to 7.3 mg/L, and 0.001 to 13.0 mg/L, respectively, for 21 samples collected from 1988 to 1989. Reduction of manganese and iron is linked to microbial oxidation of sewage carbon, producing bicarbonate and the dissolved metal ions as by-products. Calculated production and flux of CO2 through the unsaturated zone from manganese reduction in the aquifer was 0.035 g/m2/d (12% of measured CO2 flux during winter). Manganese is limited in the aquifer, however. A one-dimensional, reaction-coupled transport model developed for the mildly reducing conditions in the sewage plume nearest the source beds showed that reduction, transport, and removal of manganese from the aquifer sediments should result in iron reduction where manganese has been depleted.

Quality of Shallow Groundwater and Drinking Water in the Mississippi Embayment-Texas Coastal Uplands Aquifer System and the Mississippi River Valley Alluvial Aquifer, South-Central United States, 1994-2004

USGS Publications Warehouse

Welch, Heather L.; Kingsbury, James A.; Tollett, Roland W.; Seanor, Ronald C.

2009-01-01

The Mississippi embayment-Texas coastal uplands aquifer system is an important source of drinking water, providing about 724 million gallons per day to about 8.9 million people in Texas, Louisiana, Mississippi, Arkansas, Missouri, Tennessee, Kentucky, Illinois, and Alabama. The Mississippi River Valley alluvial aquifer ranks third in the Nation for total withdrawals of which more than 98 percent is used for irrigation. From 1994 through 2004, water-quality samples were collected from 169 domestic, monitoring, irrigation, and public-supply wells in the Mississippi embayment-Texas coastal uplands aquifer system and the Mississippi River Valley alluvial aquifer in various land-use settings and of varying well capacities as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Groundwater samples were analyzed for physical properties and about 200 water-quality constituents, including total dissolved solids, major inorganic ions, trace elements, radon, nutrients, dissolved organic carbon, pesticides, pesticide degradates, and volatile organic compounds. The occurrence of nutrients and pesticides differed among four groups of the 114 shallow wells (less than or equal to 200 feet deep) in the study area. Tritium concentrations in samples from the Holocene alluvium, Pleistocene valley trains, and shallow Tertiary wells indicated a smaller component of recent groundwater than samples from the Pleistocene terrace deposits. Although the amount of agricultural land overlying the Mississippi River Valley alluvial aquifer was considerably greater than areas overlying parts of the shallow Tertiary and Pleistocene terrace deposits wells, nitrate was rarely detected and the number of pesticides detected was lower than other shallow wells. Nearly all samples from the Holocene alluvium and Pleistocene valley trains were anoxic, and the reducing conditions in these aquifers likely result in denitrification of nitrate. In contrast, most samples from the Pleistocene terrace deposits in Memphis, Tennessee, were oxic, and the maximum nitrate concentration measured was 6.2 milligrams per liter. Additionally, soils overlying the Holocene alluvium and Pleistocene valley trains, generally in areas near the wells, had lower infiltration rates and higher percentages of clay than soils overlying the shallow Tertiary and Pleistocene terrace deposits wells. Differences in these soil properties were associated with differences in the occurrence of pesticides. Pesticides were most commonly detected in samples from wells in the Pleistocene terrace deposits, which generally had the highest infiltration rates and lowest clay content. Median dissolved phosphorus concentrations were 0.07, 0.11, and 0.65 milligram per liter in samples from the shallow Tertiary, Pleistocene valley trains, and Holocene alluvium, respectively. The widespread occurrence of dissolved phosphorus at concentrations greater than 0.02 milligram per liter suggests either a natural source in the soils or aquifer sediments, or nonpoint sources such as fertilizer and animal waste or a combination of natural and human sources. Although phosphorus concentrations in samples from the Holocene alluvium were weakly correlated to concentrations of several inorganic constituents, elevated concentrations of phosphorus could not be attributed to a specific source. Phosphorus concentrations generally were highest where samples indicated anoxic and reducing conditions in the aquifers. Elevated dissolved phosphorus concentrations in base-flow samples from two streams in the study area suggest that transport of phosphorus with groundwater is a potential source contributing to high yields of phosphorus in the lower Mississippi River basin. Water from 55 deep wells (greater than 200 feet deep) completed in regional aquifers of Tertiary age represent a sample of the principal aquifers used for drinking-water supply in the study area. The wells were screened in both confined and

Hydrogeology and water quality of the shallow aquifer system at the Mainside, Naval Surface Warfare Center, Dahlgren Site, Dahlgren, Virginia

USGS Publications Warehouse

Harlow, G.E.; Bell, C.F.

1996-01-01

Lithologic and geophysical logs of boreholes at 29 sites show that the hydrogeologic framework of the Mainside of the Naval Surface Warfare Center, Dahlgren Site at Dahlgren, Virginia, consists of un-consolidated sedimentary deposits of gravel, sand, silt, and clay. The upper 220 feet of these sediments are divided into five hydrogeologic units, including the (1) Columbia (water-table) aquifer, (2) upper confining unit, (3) upper confined aquifer, (4) Nanjemoy-Marlboro confining unit, and (5) Aquia aquifer. The Columbia aquifer in the study area is a local system that is not affected by regional pumping. Ground-water recharge occurs at topographic highs in the northern part of the Mainside, and ground-water discharge occurs at topographic lows associated with adjacent surface-water bodies. Regionally, the direction of ground-water flow in the upper confined and Aquia aquifers is toward the southwest and southeast, respectively. A downward hydraulic gradient exists between the aquifers in the shallow system, and stresses on the Aquia aquifer are indicated by heads that range between 2 and 12 feet below sea level. The ratio of median horizontal hydraulic conductivity of the Columbia aquifer to median vertical hydraulic con-ductivity of the upper confining unit, however, is approximately 2,600:1; therefore, under natural- flow conditions, most water in the Columbia aquifer probably discharges to adjacent surface- water bodies. The composition and distribution of major ions vary in the Columbia aquifer. In general, water samples from wells located along the inland perimeter roads of the study area have chloride or a combination of chloride and sulfate as the dominant anions, and water samples from wells located in the interior of the study area have bicarbonate or a combination of bicarbonate and sulfate as the dominant anions. Sodium and calcium were the dominant cations in most samples. Dissolved solids and four inorganic constituents are present in water from the Columbia aquifer at concentrations that exceed the secondary maximum contaminant levels (SMCL's) for drinking water established by the U.S. Environmental Protection Agency. Concentration of dissolved solids exceed the SMCL of 500 milligrams per liter in 3 of 29 samples from the Columbia aquifer. An elevated concentration of sodium is present in one water sample, and elevated concentrations of chloride are present in two water samples. Concentrations of dissolved iron and manga-nese exceed the SMCL in 10 and 17 of 29 water samples, respectively, and are the most extensive water-quality problem with regard to inorganic constituents in the Columbia aquifer.

Ground-water resources of Riverton irrigation project area, Wyoming

USGS Publications Warehouse

Morris, Donald Arthur; Hackett, O.M.; Vanlier, K.E.; Moulder, E.A.; Durum, W.H.

1959-01-01

The Riverton irrigation project area is in the northwestern part of the Wind River basin in west-central Wyoming. Because the annual precipitation is only about 9 inches, agriculture, which is the principal occupation in the area, is dependent upon irrigation. Irrigation by surface-water diversion was begum is 1906; water is now supplied to 77,716 acres and irrigation has been proposed for an additional 31,344 acres. This study of the geology and ground-water resources of the Riverton irrigation project, of adjacent irrigated land, and of nearby land proposed for irrigation was begun during the summer of 1948 and was completed in 1951. The purpose of the investigation was to evaluate the ground-water resources of the area and to study the factors that should be considered in the solution of drainage and erosional problems within the area. The Riverton irrigation project area is characterized by flat to gently sloping stream terraces, which are flanked by a combination of badlands, pediment slopes, and broad valleys. These features were formed by long-continued erosion in an arid climate of the essentially horizontal, poorly consolidated beds of the Wind River formation. The principal streams of the area flow south-eastward. Wind River and Fivemile Creek are perennial streams and the others are intermittent. Ground-water discharge and irrigation return flow have created a major problem in erosion control along Fivemile Creek. Similar conditions might develop along Muddy and lower Cottonwood Creeks when land in their drainage basins is irrigated. The bedrock exposed in the area ranges in age from Late Cretaceous to early Tertiary (middle Eocene). The Wind River formation of early and middle Eocene age forms the uppermost bedrock formation in the greater part of the area. Unconsolidated deposits of Quaternary age, which consist of terrace gravel, colluvium, eolian sand and silt. and alluvium, mantle the Wind River formation in much of the area. In the irrigated parts of the project, water from domestic use is obtained chiefly from the sandstone beds of the Wind River formation although some is obtained from the alluvium underlying the bottom land and from the unconsolidated deposits underlying the lower terraces along the Wind River. Although adequate quantities if water for domestic use are available from the Wind River formation, there quantities are not considered to be large enough to warrant pumping of ground water for irrigation. Only a few wells are in the nonirrigated part of the area. When this new land is irrigated, a body of ground water will gradually form in the terrace deposits and the alluvial and colluvial-alluvial deposits. Eventually, the terrace deposits may yield adequate quantities of water for domestic and stock use, but only locally are the alluvial and colluvial-alluvial deposits likely to become suitable aquifers. In the Riverton irrigation project area, ground water occurs under water-table conditions near the surface and under artesian conditions in certain strata at both shallow and greater depths. Irrigation is the principal source of recharge to the shallow aquifers; the water level in wells that tap these aquifers fluctuates with irrigation. The depth to water in the shallow wells ranges from less than 1 foot to about 30 feet below the land surface, depending on the season of the year and on the length of time the land has been irrigated. The water level in the wells that tap the deep confined aquifers , which receive recharge indirectly from surface sources, fluctuates only slightly because the recharge and discharge are more constant. In most places the depth to water in wells penetrating the deep confined aquifers is mush greater than that in shallow wells. but in certain low areas water from the deep aquifers flows at the surface from wells. Ground water moves from the area of recharge in the direction of the hydraulic gradient and is discharges either by evapotranspiration; by inflow into streams, drains, or lakes; by pumping or flow of wells; or by flow of springs. Waterlogging and the associated development of saline soils are common in parts of the Riverton irrigation project and adjacent irrigated land. The waterlogging is in part the result of the infiltration of irrigation water in excess of the capacity of the aquifers to store and transmit this added recharge. The solution of the drainage problems involves the consideration of a number of factors, some of which are inadequately known in some parts of the area and require further investigation before fully effective drainage measures can be designed. The results of an aquifer test to determine the hydrologic characteristics of the Wind River formation at Riverton indicate a transmissibility of 10,000 gallons per day per foot (10,000 gpd per ft) and a storage coefficient of 2 x 10-4. The results of the test provide a part of the necessary foundation for the solution of present and future water-supply problems at Riverton and throughout the project area. Water from shallow aquifers in irrigated tracts in the Riverton irrigation project area generally contains large amounts of dissolved solids that were leached from the soil and rocks by infiltrating irrigation water. However, wells tapping beds that receive considerable recharge from influent canal and drain seepage yield water of relatively low mineralizatoin. Dilute water is obtained also from some shallow wells in the alluvial bottom lands and on low stream terraces that border the Wind Rover. Water from deep aquifers generally is more dilute than that from shallow aquifers. However, ground water from the deep aquifers, unmixed with irrigation water, generally has a percent sodium greater than 80. Analyses of salt crusts on the ground surface in low areas that are affected by effluent seepage and a high water table show predominance of sodium sulfate salinity, and from determinations of the water-soluble and acid-soluble substances in several samples of soil and shale it is apparent that harmful concentrations of salts are being deposited in poorly drained area. Although most of the soul in the Midvale irrigation district is of the normal arid type, analyses of soil samples show that saline, nonsaline alkaline, and saline alkaline types also are present.

Characterizing the spatiotemporal variability of groundwater levels of alluvial aquifers in different settings using drought indices

NASA Astrophysics Data System (ADS)

Haas, Johannes Christoph; Birk, Steffen

2017-05-01

To improve the understanding of how aquifers in different alluvial settings respond to extreme events in a changing environment, we analyze standardized time series of groundwater levels (Standardized Groundwater level Index - SGI), precipitation (Standardized Precipitation Index - SPI), and river stages of three subregions within the catchment of the river Mur (Austria). Using correlation matrices, differences and similarities between the subregions, ranging from the Alpine upstream part of the catchment to its shallow foreland basin, are identified and visualized. Generally, river stages exhibit the highest correlations with groundwater levels, frequently affecting not only the wells closest to the river, but also more distant parts of the alluvial aquifer. As a result, human impacts on the river are transferred to the aquifer, thus affecting the behavior of groundwater levels. Hence, to avoid misinterpretation of groundwater levels in this type of setting, it is important to account for the river and human impacts on it. While the river is a controlling factor in all of the subregions, an influence of precipitation is evident too. Except for deep wells found in an upstream Alpine basin, groundwater levels show the highest correlation with a precipitation accumulation period of 6 months (SPI6). The correlation in the foreland is generally higher than that in the Alpine subregions, thus corresponding to a trend from deeper wells in the Alpine parts of the catchment towards more shallow wells in the foreland. Extreme events are found to affect the aquifer in different ways. As shown with the well-known European 2003 drought and the local 2009 floods, correlations are reduced under flood conditions, but increased under drought. Thus, precipitation, groundwater levels and river stages tend to exhibit uniform behavior under drought conditions, whereas they may show irregular behavior during floods. Similarly, correlations are found to be weaker in years with little snow as compared with those with much snow. This is in agreement with typical aquifer response times over 1 month, suggesting that short events such as floods will not affect much of the aquifer, whereas a long-term event such as a drought or snow-rich winter will. Splitting the time series into periods of 12 years reveals a tendency towards higher correlations in the most recent time period from 1999 to 2010. This time period also shows the highest number of events with SPI values below -2. The SGI values behave in a similar way only in the foreland aquifer, whereas the investigated Alpine aquifers exhibit a contrasting behavior with the highest number of low SGI events in the time before 1986. This is a result of overlying trends and suggests that the groundwater levels within these subregions are more strongly influenced by direct human impacts, e.g., on the river, than by changes in precipitation. Thus, direct human impacts must not be ignored when assessing climate change impacts on alluvial aquifers situated in populated valleys.

Temporal and vertical variation of hydraulic head in aquifers in the Edgewood area, Aberdeen Proving Ground, Maryland

USGS Publications Warehouse

Donnelly, Colleen A.; Tenbus, Fredrick J.

1998-01-01

Water-level data and interpretations from previous hydrogeological studies conducted by the U.S. Geological Survey in the Edgewood Area of Aberdeen Proving Ground (APG), Maryland, were compared to determine similarities and differences among the aquifers. Because the sediments that comprise the shallow aquifers are discontinuous, the shallow ground-water-flow systems are local rather than extensive across the Edgewood Area. Hydrogeologic cross sections, hydrographs of water levels, and vertical gradients calculated from previous studies in the Canal Creek area, Graces Quarters, the O-Field area, Carroll Island, and the J-Field area, over periods of record ranging from 1 to 10 years during 1986-97, were used to determine recharge and discharge areas, connections between aquifers, and hydrologic responses of aquifers to natural and anthropogenic stress. Each of the aquifers in the study areas exhibited variation of hydraulic head that was attributed to seasonal changes in recharge. Upward hydraulic gradients and seasonal reversals of vertical hydraulic gradients between aquifers indicate the potential for local ground-water discharge from most of the aquifers that were studied in the Edgewood Area. Hydraulic head in individual aquifers in Graces Quarters and Carroll Island responded to offsite pumping during part of the period of record. Hydraulic head in most of the confined aquifers responded to tidal loading effects from nearby estuaries.

Using 3D geological modelling and geochemical mixing models to characterise alluvial aquifer recharge sources in the upper Condamine River catchment, Queensland, Australia.

PubMed

Martinez, Jorge L; Raiber, Matthias; Cendón, Dioni I

2017-01-01

The influence of mountain front recharge on the water balance of alluvial valley aquifers located in upland catchments of the Condamine River basin in Queensland, Australia, is investigated through the development of an integrated hydrogeological framework. A combination of three-dimensional (3D) geological modelling, hydraulic gradient maps, multivariate statistical analyses and hydrochemical mixing calculations is proposed for the identification of hydrochemical end-members and quantification of the relative contributions of each end-member to alluvial aquifer recharge. The recognised end-members correspond to diffuse recharge and lateral groundwater inflows from three hydrostratigraphic units directly connected to the alluvial aquifer. This approach allows mapping zones of potential inter-aquifer connectivity and areas of groundwater mixing between underlying units and the alluvium. Mixing calculations using samples collected under baseflow conditions reveal that lateral contribution from a regional volcanic aquifer system represents the majority (41%) of inflows to the alluvial aquifer. Diffuse recharge contribution (35%) and inflow from two sedimentary bedrock hydrostratigraphic units (collectively 24%) comprise the remainder of major recharge sources. A detailed geochemical assessment of alluvial groundwater evolution along a selected flowpath of a representative subcatchment of the Condamine River basin confirms mixing as a key process responsible for observed spatial variations in hydrochemistry. Dissolution of basalt-related minerals and dolomite, CO 2 uptake, ion-exchange, precipitation of clay minerals, and evapotranspiration further contribute to the hydrochemical evolution of groundwater in the upland alluvial aquifer. This study highlights the benefits of undertaking an integrated approach that combines multiple independent lines of evidence. The proposed methods can be applied to investigate processes associated with inter-aquifer mixing, including groundwater contamination resulting from depressurisation of underlying geological units hydraulically connected to the shallower water reservoirs. Copyright © 2016 Elsevier B.V. All rights reserved.

Preliminary evaluation of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

USGS Publications Warehouse

Hult, Marc F.; Schoenberg, Michael

1981-01-01

Operation of a coal-tar distillation and wood preserving plant for 1918-72 in St. Louis Park, Minnesota, resulted in ground-water contamination. This report presents the results of the first year (1979) of an ongoing study. By 1932, water in the Prairie du Chien-Jordan aquifer, the region 's major source of ground water, was contaminated 3,500 feet from the plant. The hydraulic characteristics of the Prairie du Chien-Jordan aquifer , its long contamination history, and fluctuating pumpage combine to creat a complex distribution of coal-tar derivatives observed in the aquifer. The Prairie du Chien-Jordan aquifer underlies the area at depths of 250 to 500 feet and is overlain by two bedrock aquifers (Platteville and St. Peter), two confining beds (Glenwood and basal part of St. Peter), and 70 to 100 feet of glacial drift. Multiaquifer wells in the area have permitted contaminated water from near-surface aquifers to flow downward into the Prairie du Chien-Jordan aquifer. Flow rates of 20 to 150 gallons per minute from the shallower aquifers into the Prairie du Chien-Jordan aquifer were observed in five wells. In the drift, a hydrocarbon fluid phase is moving vertically downward relative to the aqueous phase. Dissolved constituents in the drift and Platteville aquifer, the uppermost bedrock unit over most of the area, have moved at least 4,000 feet. Low-molecular-weight compounds are moving preferentially through the drift and Platteville aquifer system. (USGS)

Retardation of arsenic transport through a Pleistocene aquifer

PubMed Central

van Geen, Alexander; Bostick, Benjamín C.; Trang, Pham Thi Kim; Lan, Vi Mai; Mai, Nguyen-Ngoc; Manh, Phu Dao; Viet, Pham Hung; Radloff, Kathleen; Aziz, Zahid; Mey, Jacob L.; Stahl, Mason O.; Harvey, Charles F.; Oates, Peter; Weinman, Beth; Stengel, Caroline; Frei, Felix; Kipfer, Rolf; Berg, Michael

2013-01-01

Groundwater drawn daily from shallow alluvial sands by millions of wells over large areas of South and Southeast Asia exposes an estimated population of over 100 million to toxic levels of arsenic (1). Holocene aquifers are the source of widespread arsenic poisoning across the region (2, 3). In contrast, Pleistocene sands deposited in this region more than ~12,000 years ago mostly do not host groundwater with high levels of arsenic. Pleistocene aquifers are increasingly used as a safe source of drinking water (4) and it is therefore important to understand under what conditions low levels of arsenic can be maintained. Here we reconstruct the initial phase of contamination of a Pleistocene aquifer near Hanoi, Vietnam. We demonstrate that changes in groundwater flow conditions and the redox state of the aquifer sands induced by groundwater pumping caused the lateral intrusion of arsenic contamination over 120 m from Holocene aquifer into a previously uncontaminated Pleistocene aquifer. We also find that arsenic adsorbs onto the aquifer sands and that there is a 16–20 fold retardation in the extent of the contamination relative to the reconstructed lateral movement of groundwater over the same period. Our findings suggest that arsenic contamination of Pleistocene aquifers in South and Southeast Asia as a consequence of increasing levels of groundwater pumping have been delayed by the retardation of arsenic transport. PMID:24025840

Environmental Assessment, East Coast Basing of C-17 Aircraft. Volume 1

DTIC Science & Technology

2005-09-01

hydrogeologic units have been identified in the McGuire AFB area, particularly three shallow units and one deep unit (the Potomac-Raritan- Magothy System...McGuire AFB 2003c). The depth to groundwater is relatively shallow (less than five feet in some areas). The Potomac-Raritan- Magothy aquifer is...the primary source of potable water in the McGuire AFB area. The Base obtains water from four deep wells in the Potomac-Raritan- Magothy aquifer at

Environmental Assessment East Coast Basing of C-17 Aircraft. Volume 1

DTIC Science & Technology

2005-09-01

hydrogeologic units have been identified in the McGuire AFB area, particularly three shallow units and one deep unit (the Potomac-Raritan- Magothy System...McGuire AFB 2003c). The depth to groundwater is relatively shallow (less than five feet in some areas). The Potomac-Raritan- Magothy aquifer is...the primary source of potable water in the McGuire AFB area. The Base obtains water from four deep wells in the Potomac-Raritan- Magothy aquifer at

Hydrogeology of a hazardous-waste disposal site near Brentwood, Williamson County, Tennessee

USGS Publications Warehouse

Tucci, Patrick; Hanchar, D.W.; Lee, R.W.

1990-01-01

Approximately 44,000 gal of industrial solvent wastes were disposed in pits on a farm near Brentwood, Tennessee, in 1978, and contaminants were reported in the soil and shallow groundwater on the site in 1985. In order for the State to evaluate possible remedial-action alternatives, an 18-month study was conducted to define the hydrogeologic setting of the site and surrounding area. The area is underlain by four hydrogeologic units: (1) an upper aquifer consisting of saturated regolith, Bigby-Cannon Limestone, and weathered Hermitage Formation; (2) the Hermitage confining unit; (3) a lower aquifer consisting of the Carters Limestone; and (4) the Lebanon confining unit. Wells generally are low yielding less than 1 gal/min ), although locally the aquifers may yield as much as 80 gal/minute. This lower aquifer is anisotropic, and transmissivity of this aquifer is greatest in a northwest-southeast direction. Recharge to the groundwater system is primarily from precipitation, and estimates of average annual recharge rates range from 6 to 15 inches/year. Discharge from the groundwater system is primarily to the Little Harpeth River and its tributaries. Groundwater flow at the disposal site is mainly to a small topographic depression that drains the site. Geochemical data indicate four distinct water types. These types represent (1) shallow, rapidly circulating groundwater; (2) deeper (> than 100 ft), rapidly circulating groundwater; (3) shallow, slow moving groundwater; and (4) deeper, slow moving groundwater. Results of the numerical model indicate that most flow is in the upper aquifer. (USGS)

Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer in parts of Marion, Sumter, and Citrus counties, Florida

USGS Publications Warehouse

Sacks, Laura A.

1996-01-01

In inland areas of northwest central Florida, sulfate concentrations in the Upper Floridan aquifer are extremely variable and sometimes exceed drinking water standards (250 milligrams per liter). This is unusual because the aquifer is unconfined and near the surface, allowing for active recharge. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated in this area. Water was sampled from thirty-three wells in parts of Marion, Sumter, and Citrus Counties, within the Southwest Florida Water Management District; these included at least a shallow and a deep well at fifteen separate locations. Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (sulfur-34 of sulfate and sulfide, carbon-13 of inorganic carbon, deuterium, and oxygen-18). Sulfate concentrations ranged from less than 0.2 to 1,400 milligrams per liter, with higher sulfate concentrations usually in water from deeper wells. The samples can be categorized into a low sulfate group (less than 30 milligrams per liter) and a high sulfate group (greater than 30 milligrams per liter). For the high sulfate water, concentrations of calcium and magnesium increased concurrently with sulfate. Chemical and isotopic data and mass-balance modeling indicate that the composition of high sulfate waters is controlled by dedolomitization reactions (dolomite dissolution and calcite precipitation, driven by dissolution of gypsum). Gypsum occurs deeper in the aquifer than open intervals of sampled wells. Upward flow has been documented in deeper parts of the aquifer in the study area, which may be driven by localized discharge areas or rapid flow in shallow parts of the aquifer. Mixing between shallow ground water and sulfate-rich water that dissolved gypsum at the base of the aquifer is probably responsible for the range of concentrations observed in the study area. Other solutes that increased with sulfate apparently originate from the gypsum itself, from other mineral assemblages found deeper in the aquifer in association with gypsum, and from residual seawater from less- flushed, deeper parts of the aquifer. These ions are subsequently transported with sulfate to shallower parts of the aquifer where gypsum is not present. The composition of low sulfate ground water is controlled by differences in the extent of microbially mediated reactions, which produce carbon dioxide. This, in turn, influences the extent of calcite dissolution. Ground waters which underwent limited microbial reactions contained dissolved oxygen and were usually in ridge areas where recharge typically is rapid. Anaerobic waters were in lower lying areas of Sumter County, where soils are poorly drained and aquifer recharge is slow. Anaerobic waters had higher concentrations of calcium, bicarbonate, sulfide, dissolved organic carbon, iron, manganese, and silica, and had lower concentrations of nitrate than aerobic ground waters. For low sulfate waters, sulfate generally originates from meteoric sources (atmospheric precipitation), with variable amounts of oxidation of reduced sulfur and sulfate reduction. Sulfide is sometimes removed from solution, probably by precipitation of a sulfide minerals such as pyrite. In areas where deep ground water has low sulfate concentrations, the shallow flow system is apparently deeper than where high sulfate concentrations occur, and upwelling sulfate-rich water is negligible. The range of sulfate concentrations observed in the study areas and differences in sulfate concentrations with depth indicate a complex interaction between shallow and deep ground-water flow systems.

CO2 Leakage-Induced Shallow Aquifer Contaminations and Associated Health Risk Assessment.

NASA Astrophysics Data System (ADS)

Kim, C. Y.; Han, W. S.; Park, E.; Choung, S.; Piao, J.; Han, G.; Tianfu, X.

2016-12-01

Leakage of stored CO2 from designated deep formation could degrade portable groundwater quality in overlaying shallow aquifers. Dissolution of leaked CO2 causes to reduction of pH and alters dominant geochemical reactions, which ultimately enhances mobility of toxic heavy metals in shallow aquifer. In this study, among various toxic heavy metals, mobilization of As and U were focused because these metals are considered to be cancer potency factor when human being continuously exposes for long period. For this reason, it is critical to evaluate relationship between the amount of leaked CO2 into shallow aquifer and a degree of mobility in As and U. In the end, cancer risk to human body were quantified with probabilistic approach after accounting for shallow groundwater velocity, pumping rate from residential well, geologic heterogeneity. For this study, two-dimensional reactive transport models were developed. Geologic heterogeneity was accounted with three interbedded rock types, which consisted of sandstone, As and U bearing shale, and carbonate rocks, respectively. Within these three-rock types, variability includes changes in permeability, porosity, a type of minerals, and its volume fraction, accounting for both physical and chemical heterogeneities Finally, human health risk is calculated through multiplying cancer potency factor by average daily dose, which is obtained after acquiring for both As and U concentrations profile at residential well through reactive transport modeling. As per variability, a series of human health risks were calculated. Quantification of risk in conjunction with sensitivity analysis aids to evaluate a list of geologic parameters enhancing human health risk.

Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

NASA Astrophysics Data System (ADS)

Katz, Brian G.; Eberts, Sandra M.; Kauffman, Leon J.

2011-02-01

SummaryA detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride-bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (<20 m depth below land surface) had a significantly ( p < 0.05) higher median percentage of houses with septic tanks (1990 census data) than non-targeted wells. Higher ( p = 0.08) median nitrate-N concentration (3.1 mg/L) in oxic (dissolved oxygen concentrations >0.5 mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5 mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells. The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from shallow wells (<20 m) with the range of 400-1100. The use of this ratio would be enhanced with information on other chloride sources, temporal variability of chloride and bromide concentrations in shallow groundwater, knowledge of septic-system age and maintenance, and the use of multiple tracers (combination of additional chemical and microbiological indicators).

Cosmogenic, radiogenic, and stable isotopic constraints on groundwater residence time in the nubian aquifer, western desert of egypt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patterson, Leslie J.; Sturchio, Neil C.; Kennedy, B.Mack

2004-06-01

Measurements of radiochlorine ({sup 36}Cl), radiogenic noble gases ({sup 4}He and {sup 40}Ar), and stable chlorine isotope ratios were obtained to assess the residence time of groundwater in the Nubian Aquifer of the Western Desert of Egypt. Measured {sup 36}Cl/Cl ratios yield apparent residence times from {approx}0.2 to 1.2 x 10{sup 6} years in the deep (600-1200 m) groundwater (assuming constant Cl) and {le} 0.16 x 10{sup 6} years in the shallow (<600 m) groundwater. Values of {delta}{sup 37}Cl in the groundwater strengthen the application of the {sup 36}Cl dating method by constraining Cl sources and identifying groundwater mixing. Dissolvedmore » gases were measured in some of the deep groundwater samples. Measured {sup 4}He concentrations indicate accumulation of radiogenic {sup 4}He that is qualitatively consistent with the age progression indicated by the {sup 36}Cl/Cl ratios, but the flux of external {sup 4}He from the underlying crust has not been quantified and is not constant throughout the aquifer. Concentrations of {sup 40}Ar range from 3.3 to 6.7 x 10{sup -4} ccSTP/g and indicate excess air incorporation at recharge. Measured {sup 40}Ar/{sup 36}Ar ratios do not exceed the atmospheric ratio. A two-dimensional numerical hydrodynamic transect of the aquifer was modeled from the area of the Uweinat Uplift to the northern Bahariya Oasis. Predicted groundwater velocities in the deep portion of the aquifer are 0.5-3.5 m/yr with groundwater residence times up to 9 x 10{sup 5} years; residence times up to 1.3 x 10{sup 6} years are predicted in the confining shale. Aquifer properties are estimated by using the model to fit the measured {sup 36}Cl/Cl ratios. Under these conditions, hydrodynamic residence times are within about 30 percent of those calculated from {sup 36}Cl when mixing of Cl{sup -} is accounted for in the highest-Cl{sup -} deep groundwaters. By mutually calibrating multiple methods (hydrodynamic, {sup 36}Cl, and {sup 4}He), a consistent picture of the Nubian Aquifer has emerged in which lateral flow from a southern recharge area dominates the deep horizons, while shallow horizons contain younger, autochthonous recharge.« less

Long-Term Changes In The Shallow Water Table In A Mining Area: The Lubin-Glogow Copper Region, Southwestern Poland

NASA Astrophysics Data System (ADS)

Bochenska, T.; Limisiewicz, P.; Loprawski, L.

1995-03-01

In regions of intense mining, shortages of water are common. Increased water demand is normally associated with industry in mining areas, and mine unwatering has negative effects on the natural groundwater balance. The study area occupies 3,300 square kilometers within the copper mining region of Lubin-Glogow, southwestern Poland. Pumping of groundwater to drain mines has created a cone of depression that underlies 2,500 square kilometers. The lowering of potentiometric surfaces has occurred in deep aquifers, which are isolated from the surface by thick confining units (loams and clays). Changes of hydraulic head in the shallow aquifer have not previously been observed. In this study, the authors analyzed the water-table changes in the shallow aquifer. The statistical analysis of the water table was based on two sets of water-level measurements in about 1,200 farm wells during dry seasons. The first set was done in the fall of 1986, the second in the fall of 1991. In addition to these measurements, multi-seasonal observations were made by the mining survey in several tens of wells. During five years, the head declined an average of 0.4 meter. Locally, the lowering was as great as five meters. The regional decline of head resulted in a loss of water resources about 2×108 cubic meters. Regionally, this loss is not directly related to the dewatering of copper mines. Locally, however, mining activity strongly influences the water table. The general trend of the decline is probably an effect of decreasing precipitation.

Influence of lateral groundwater flow in a shallow aquifer on eco-hydrological process in a shrub-grass coexistence semiarid area

NASA Astrophysics Data System (ADS)

Wang, Siru; Sun, Jinhua; Lei, Huimin; Zhu, Qiande; Jiang, Sanyuan

2017-04-01

Topography has a considerable influence on eco-hydrological processes resulting from the patterns of solar radiation distribution and lateral water flow. However, not much quantitative information on the contribution of lateral groundwater flow on ecological processes such as vegetation growth and evapo-transpiration is available. To fill this gap, we used a simple eco-hydrological model based on water balance with a 3D groundwater module that uses Darcy's law. This model was applied to a non-contributing area of 50km2 dominated by grassland and shrubland with an underlying shallow aquifer. It was calibrated using manually and remotely sensed vegetation data and water flux data observed by eddy covariance system of two flux towers as well as water table data obtained from HOBO recorders of 40 wells. The results demonstrate that the maximum hydraulic gradient and the maximum flux of lateral groundwater flow reached to 0.156m m-1 and 0.093m3 s-1 respectively. The average annual maximum LAI in grassland, predominantly in low-lying areas, improved by about 5.9% while that in shrubland, predominantly in high-lying areas, remained the same when lateral groundwater flow is considered adequately compared to the case without considering lateral groundwater flow. They also show that LAI is positively and nonlinearly related to evapotranspiration, and that the greater the magnitude of evapotranspiration, the smaller the rate of increase of LAI. The results suggest that lateral groundwater flow should not be neglected when simulating eco-hydrological process in areas with a shallow aquifer.

Ground water in Dale Valley, New York

USGS Publications Warehouse

Randall, Allan D.

1979-01-01

Dale Valley is a broad valley segment, enlarged by glacial erosion, at the headwaters of Little Tonawanda Creek near Warsaw , New York. A thin, shallow alluvial aquifer immediately underlies the valley floor but is little used. A deeper gravel aquifer, buried beneath many feet of lake deposits, is tapped by several industrial wells. A finite-difference digital model treated the deep aquifer as two-dimensional with recharge and discharge through a confining layer. It was calibrated by simulating (1) natural conditions, (2) an 18-day aquifer test, and (3) 91 days of well-field operation. Streamflow records and model simulations suggest that in moderately wet years such as 1974, a demand of 750 gallons per minute could be met by withdrawal from the creek and from the aquifer without excessive drawdown at production wells or existing domestic wells. With reasonable but unverified model adjustments to simulate an unusually dry year, the model predicts that a demand of 600 gallons per minute could be met from the same sources. Water high in chloride has migrated from bedrock into parts of the deep aquifer. Industrial pumpage, faults in the bedrock, and the natural flow system may be responsible. (Woodard-USGS)

Implications of Fecal Bacteria Input from Latrine-Polluted Ponds for Wells in Sandy Aquifers

PubMed Central

Knappett, Peter S. K.; McKay, Larry D.; Layton, Alice; Williams, Daniel E.; Alam, Md. J.; Huq, Md. R.; Mey, Jacob; Feighery, John E.; Culligan, Patricia J.; Mailloux, Brian J.; Zhuang, Jie; Escamilla, Veronica; Emch, Michael; Perfect, Edmund; Sayler, Gary S.; Ahmed, Kazi M.; van Geen, Alexander

2012-01-01

Ponds receiving latrine effluents may serve as sources of fecal contamination to shallow aquifers tapped by millions of tube-wells in Bangladesh. To test this hypothesis, transects of monitoring wells radiating away from four ponds were installed in a shallow sandy aquifer underlying a densely populated village and monitored for 14 months. Two of the ponds extended to medium sand. Another pond was sited within silty sand and the last in silt. The fecal indicator bacterium E. coli was rarely detected along the transects during the dry season and was only detected near the ponds extending to medium sand up to 7 m away during the monsoon. A log-linear decline in E. coli and Bacteroidales concentrations with distance along the transects in the early monsoon indicates that ponds excavated in medium sand were the likely source of contamination. Spatial removal rates ranged from 0.5-1.3 log10/m. After the ponds were artificially filled with groundwater to simulate the impact of a rain storm, E. coli levels increased near a pond recently excavated in medium sand, but no others. These observations show that adjacent sediment grain-size and how recently a pond was excavated influence how much fecal contamination ponds receiving latrine effluents contribute to neighboring groundwater. PMID:22191430

Heterogeneity-enhanced gas phase formation in shallow aquifers during leakage of CO2-saturated water from geologic sequestration sites

NASA Astrophysics Data System (ADS)

Plampin, Michael R.; Lassen, Rune N.; Sakaki, Toshihiro; Porter, Mark L.; Pawar, Rajesh J.; Jensen, Karsten H.; Illangasekare, Tissa H.

2014-12-01

A primary concern for geologic carbon storage is the potential for leakage of stored carbon dioxide (CO2) into the shallow subsurface where it could degrade the quality of groundwater and surface water. In order to predict and mitigate the potentially negative impacts of CO2 leakage, it is important to understand the physical processes that CO2 will undergo as it moves through naturally heterogeneous porous media formations. Previous studies have shown that heterogeneity can enhance the evolution of gas phase CO2 in some cases, but the conditions under which this occurs have not yet been quantitatively defined, nor tested through laboratory experiments. This study quantitatively investigates the effects of geologic heterogeneity on the process of gas phase CO2 evolution in shallow aquifers through an extensive set of experiments conducted in a column that was packed with layers of various test sands. Soil moisture sensors were utilized to observe the formation of gas phase near the porous media interfaces. Results indicate that the conditions under which heterogeneity controls gas phase evolution can be successfully predicted through analysis of simple parameters, including the dissolved CO2 concentration in the flowing water, the distance between the heterogeneity and the leakage location, and some fundamental properties of the porous media. Results also show that interfaces where a less permeable material overlies a more permeable material affect gas phase evolution more significantly than interfaces with the opposite layering.

Factors Affecting Spatial and Temporal Variability in Nutrient and Pesticide Concentrations in the Surficial Aquifer on the Delmarva Peninsula

USGS Publications Warehouse

Debrewer, Linda M.; Ator, Scott W.; Denver, Judith M.

2007-01-01

Water quality in the unconfined, unconsolidated surficial aquifer on the Delmarva Peninsula is influenced by the availability of soluble ions from natural and human sources, and by geochemical factors that affect the mobility and fate of these ions within the aquifer. Ground-water samples were collected from 60 wells completed in the surficial aquifer of the peninsula in 2001 and analyzed for major ions, nutrients, and selected pesticides and degradation products. Analytical results were compared to similar data from a subset of sampled wells in 1988, as well as to land use, soils, geology, depth, and other potential explanatory variables to demonstrate the effects of natural and human factors on water quality in the unconfined surficial aquifer. This study was conducted as part of the National Water-Quality Assessment Program of the U.S. Geological Survey, which is designed (in part) to describe the status and trends in ground-water quality and to provide an understanding of natural and human factors that affect ground-water chemistry in different parts of the United States. Results of this study may be useful for water-resources managers tasked with addressing water-quality issues of local and regional importance because the surficial aquifer on the Delmarva Peninsula is a major source of water for domestic and public supply and provides the majority of flow in local streams. Human impacts are apparent in ground-water quality throughout the surficial aquifer. The surficial aquifer on the Delmarva Peninsula is generally sandy and very permeable with well-oxygenated ground water. Dissolved constituents found throughout various depths of the unconfined aquifer are likely derived from the predominantly agricultural practices on the peninsula, although effects of road salt, mineral dissolution, and other natural and human influences are also apparent in some areas. Nitrate occurred at concentrations exceeding natural levels in many areas, and commonly exceeded 10 milligrams per liter (as nitrogen). In addition to land use in the aquifer recharge area, concentrations of nitrate in ground water are related to regional patterns in soil drainage that affect underlying aquifer redox conditions. Over the peninsula, nitrate concentrations are not related to recharge date of the water, but are positively correlated with depth in shallow wells screened beneath agricultural areas. Nitrate concentrations increased in oxic areas (dissolved oxygen greater than 1 milligram per liter) of the deeper part of the surficial aquifer used for domestic supply by an average of about 2 milligrams per liter between 1988 and 2001, although no changes were apparent in shallower parts of the aquifer over that same period. Water in the surficial aquifer generally flows from land-surface recharge to surface-water discharge areas in less than 30 years. As a result, the entire flow system in the surficial aquifer has likely been affected by human activities on and near the land surface over the past several decades. Pesticide compounds occurred widely at low levels throughout the surficial aquifer. The most commonly used herbicides (metolachlor, alachlor, and atrazine) were the most commonly detected. These pesticides primarily occurred in ground water in the form of degradation products. The widespread occurrence of these and other pesticide compounds reflects their abundant use as well as chemical properties and aquifer characteristics that allow their movement into ground water. Mixtures of pesticides are common. Most samples contained at least 3 different compounds; several samples contained as many as 11. Pesticide concentrations in the surficial aquifer are relatively high beneath recharge areas with well-drained soils in the shallow part of the aquifer and in oxic environments throughout the surficial aquifer. Concentrations are generally below existing drinking-water standards, although standards are not available for all of the pesticide compound

Dating groundwater with dissolved silica and CFC concentrations in crystalline aquifers.

PubMed

Marçais, Jean; Gauvain, Alexandre; Labasque, Thierry; Abbott, Benjamin W; Pinay, Gilles; Aquilina, Luc; Chabaux, François; Viville, Daniel; de Dreuzy, Jean-Raynald

2018-09-15

Estimating intermediate water residence times (a few years to a century) in shallow aquifers is critical to quantifying groundwater vulnerability to nutrient loading and estimating realistic recovery timelines. While intermediate groundwater residence times are currently determined with atmospheric tracers such as chlorofluorocarbons (CFCs), these analyses are costly and would benefit from other tracer approaches to compensate for the decreasing resolution of CFC methods in the 5-20 years range. In this context, we developed a framework to assess the capacity of dissolved silica (DSi) to inform residence times in shallow aquifers. We calibrated silicate weathering rates with CFCs from multiple wells in five crystalline aquifers in Brittany and in the Vosges Mountains (France). DSi and CFCs were complementary in determining apparent weathering reactions and residence time distributions (RTDs) in shallow aquifers. Silicate weathering rates were surprisingly similar among Brittany aquifers, varying from 0.20 to 0.23 mg L -1  yr -1 with a coefficient of variation of 7%, except for the aquifer where significant groundwater abstraction occurred, where we observed a weathering rate of 0.31 mg L -1  yr -1 . The silicate weathering rate was lower for the aquifer in the Vosges Mountains (0.12 mg L -1  yr -1 ), potentially due to differences in climate and anthropogenic solute loading. Overall, these optimized silicate weathering rates are consistent with previously published studies with similar apparent ages range. The consistency in silicate weathering rates suggests that DSi could be a robust and cheap proxy of mean residence times for recent groundwater (5-100 years) at the regional scale. This methodology could allow quantification of seasonal groundwater contributions to streams, estimation of residence times in the unsaturated zone and improve assessment of aquifer vulnerability to anthropogenic pollution. Copyright © 2018 Elsevier B.V. All rights reserved.

Nitrate in aquifers beneath agricultural systems

USGS Publications Warehouse

Burkart, M.R.; Stoner, J.D.; ,

2007-01-01

Research from several regions of the world provides spatially anecdotal evidence to hypothesize which hydrologic and agricultural factors contribute to groundwater vulnerability to nitrate contamination. Analysis of nationally consistent measurements from the U.S. Geological Survey's NAWQA program confirms these hypotheses for a substantial range of agricultural systems. Shallow unconfined aquifers are most susceptible to nitrate contamination associated with agricultural systems. Alluvial and other unconsolidated aquifers are the most vulnerable and also shallow carbonate aquifers that provide a substantial but smaller contamination risk. Where any of these aquifers are overlain by permeable soils the risk of contamination is larger. Irrigated systems can compound this vulnerability by increasing leaching facilitated by additional recharge and additional nutrient applications. The system of corn, soybean, and hogs produced significantly larger concentrations of groundwater nitrate than all other agricultural systems because this system imports the largest amount of N-fertilizer per unit production area. Mean nitrate under dairy, poultry, horticulture, and cattle and grains systems were similar. If trends in the relation between increased fertilizer use and groundwater nitrate in the United States are repeated in other regions of the world, Asia may experience increasing problems because of recent increases in fertilizer use. Groundwater monitoring in Western and Eastern Europe as well as Russia over the next decade may provide data to determine if the trend in increased nitrate contamination can be reversed. If the concentrated livestock trend in the United States is global, it may be accompanied by increasing nitrogen contamination in groundwater. Concentrated livestock provide both point sources in the confinement area and intense non-point sources as fields close to facilities are used for manure disposal. Regions where irrigated cropland is expanding, such as in Asia, may experience the greatest impact of this practice on groundwater nitrate. ?? USDA 2007.

Efficient infiltration of water in the subsurface by using point-wells: A field study

NASA Astrophysics Data System (ADS)

Lopik, J. V.; Schotting, R.; Raoof, A.

2017-12-01

The ability to infiltrate large volumes of water in the subsurface would have great value for battling flooding in urban regions. Moreover, efficient water infiltration is key to optimize underground aquifer storage and recovery (ASR), aquifer thermal energy storage (ATES), as well as construction dewatering systems. Usually, variable infiltration rates of large water quantities could have a huge hydrogeological impact in the upper part of (phreatic) aquifer systems. In urban regions, minimizing excessive groundwater table fluctuations are necessary. A newly developed method, Fast, High Volume Infiltration (FHVI), by Dutch dewatering companies can be used to enable fast injection into the shallow subsurface. Conventional infiltration methods are using injection wells that screen large parts of the aquifer depth, whereas FHVI uses a specific infiltration point (1-m well screen) in the aquifer. These infiltration points are generally thin, high permeable layers in the aquifer of approximately 0.5-2 meter thick, and are embedded by less permeable layers. Currently, much higher infiltration pressures in shallow aquifers can be achieved with FHVI (up to 1 bar) compared to conventional infiltration methods ( 0.2 bar). Despite the high infiltration pressures and high discharge rate near the FHVI-filter, the stresses on shallow groundwater levels are significantly reduced with FHVI. In order to investigate the mechanisms that enable FHVI, a field experiment is conducted in a sandy aquifer to obtain insight in the 3-D hydraulic pressure distribution and flow patterns around a FHVI-filter during infiltration. A detailed characterization of the soil profile is obtained by using soil samples and cone pressure tests with a specific hydraulic profiling tool to track the vertical variation in aquifer permeability. A tracer test with bromide and heat is conducted to investigate preferential flow paths. The experimental data show that tracking small heterogeneities in aquifers and analysing the permeability difference ratio between the aimed infiltration layer and the surrounding layers in the aquifer are key to optimize the configuration of the FHVI-well. The results show that the use of point wells in thin, high permeable layers could drastically improve the efficiency of the infiltration system.

A conceptual model for groundwater - surface water interactions in the Darling River Floodplain, N.S.W., Australia

NASA Astrophysics Data System (ADS)

Brodie, R. S.; Lawrie, K.; Somerville, P.; Hostetler, S.; Magee, J.; Tan, K. P.; Clarke, J.

2013-12-01

Multiple lines of evidence were used to develop a conceptual model for interaction between the Darling River and associated floodplain aquifers in western New South Wales, Australia. Hydrostratigraphy and groundwater salinities were mapped using airborne electromagnetics (AEM), validated by sonic-core drilling. The AEM was highly effective in mapping groundwater freshening due to river leakage in discrete zones along the river corridor. These fresh resources occurred in both the unconfined Quaternary aquifers and the underlying, largely semi-confined Pliocene aquifers. The AEM was also fundamental to mapping the Blanchetown Clay aquitard which separates these two aquifer systems. Major-ion chemistry highlighted a mixing signature between river waters and groundwaters in both the Quaternary and Pliocene aquifers. Stable isotope data indicates that recharge to the key Pliocene aquifers is episodic and linked to high-flow flood events rather than river leakage being continuous. This was also evident when groundwater chemistry was compared with river chemistry under different flow conditions. Mapping of borehole levels showed groundwater mounding near the river, emphasising the regional significance of losing river conditions for both aquifer systems. Critically, rapid and significant groundwater level responses were measured during large flood events. In the Pliocene aquifers, continuation of rising trends after the flood peak receded confirms that this is an actual recharge response rather than hydraulic loading. The flow dependency of river leakage can be explained by the presence of mud veneers and mineral precipitates along the Darling River channel bank when river flows are low. During low flow conditions these act as impediments to river leakage. During floods, high flow velocities scour these deposits, revealing lateral-accretion surfaces in the shallow scroll plain sediments. This scouring allows lateral bank recharge to the shallow aquifer. During flood recession, mud veneers are re-deposited while transient return flows from bank storage results in carbonate precipitation in river banks. Active recharge of the Pliocene aquifers requires leakage pathways through the overlying Blanchetown Clay. Neogene-to-Present tectonic modification of the alluvial sequence, including discrete fault offsets in the Blanchetown Clay, was identified in the AEM data. Mapped faults are coincident with structures mapped in LiDAR, airborne magnetics, regional gravity, and seismic data.The study highlighted the utility of AEM in mapping the critical geological controls on groundwater-surface interaction, including the previously unrecognised tectonic influences on the largely unconsolidated alluvial sequence. Flow-dependent recharge due to changing river bed conductance has implications for groundwater assessment and management. An analysis of historic river flows suggests that active recharge would only occur for about 17% of the time when flow exceeds about 9,000 ML/d. Recharge would be negligible with groundwater extraction during low-flow conditions.

Ground-water flow in the shallow aquifer system at the Naval Weapons Station Yorktown, Virginia

USGS Publications Warehouse

Smith, Barry S.

2001-01-01

The Environmental Directorate of the Naval Weapons Station Yorktown, Virginia, is concerned about possible contamination of ground water at the Station. Ground water at the Station flows through a shallow system of layered aquifers and leaky confining units. The units of the shallow aquifer system are the Columbia aquifer, the Cornwallis Cave confining unit, the Cornwallis Cave aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer. The Eastover-Calvert confining unit separates the shallow aquifer system from deeper confined aquifers beneath the Station. A three-dimensional, finite-difference, ground-water flow model was used to simulate steady-state ground-water flow of the shallow aquifer system in and around the Station. The model simulated ground-water flow from the peninsular drainage divide that runs across the Lackey Plain near the southern end of the Station north to King Creek and the York River and south to Skiffes Creek and the James River. The model was calibrated by minimizing the root mean square error between 4 7 measured and corresponding simulated water levels. The calibrated model was used to determine the ground-water budget and general directions of ground-water flow. A particle-tracking routine was used with the calibrated model to estimate groundwater flow paths, flow rates, and traveltimes from selected sites at the Station. Simulated ground-water flow velocities of the Station-area model were small beneath the interstream areas of the Lackey Plain and Croaker Flat, but increased outward toward the streams and rivers where the hydraulic gradients are larger. If contaminants from the land surface entered the water table at or near the interstream areas of the Station, where hydraulic gradients are smaller, they would migrate more slowly than if they entered closer to the streams or the shores of the rivers where gradients commonly are larger. The ground-water flow simulations indicate that some ground water leaks downward from the water table to the Yorktown confining unit and, where the confining unit is absent, to the Yorktown-Eastover aquifer. The velocities of advective-driven contaminants would decrease considerably when entering the Yorktown confining unit because the hydraulic conductivity of the confining unit is small compared to that of the aquifers. Any contaminants that moved with advective ground-water flow near the groundwater divide of the Lackey Plain would move relatively slowly because the hydraulic gradients are small there. The direction in which the contaminants would move, however, would be determined by precisely where the contaminants entered the water table. The model was not designed to accurately simulate ground-water flow paths through local karst features. Beneath Croaker Flat, ground water flows downward through the Columbia aquifer and the Yorktown confining unit into the Yorktown-Eastover aquifer. Analyses of the movement of simulated particles from two adjacent sites at Croaker Flat indicated that ground-water flow paths were similar at first but diverged and discharged to different tributaries of Indian Field Creek or to the York River. These simulations indicate that complex and possibly divergent flow paths and traveltimes are possible at the Station. Although the Station-area model is not detailed enough to simulate ground-water flow at the scales commonly used to track and remediate contaminants at specific sites, general concepts about possible contaminant migration at the Station can be inferred from the simulations.

Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species inmore » reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments. Frontiers in Earth Science Journal Impact & Description - ResearchGate - Impact Rankings ( 2015 and 2016 ). Available from: https://www.researchgate.net/journal/2296-6463_Frontiers_in_Earth_Science [accessed Jul 25, 2016].« less

Determinants of Shallow Groundwater As Variability in Bangladesh

NASA Astrophysics Data System (ADS)

Radloff, K. A.; Zheng, Y.; Stute, M.; Rahman, M.; Mihajlov, I.; Siu, H.; Huq, M.; Choudhury, I.; Ahmed, K.; van Geen, A.

2010-12-01

Manually operated tube wells that tap into shallow aquifers remain a critical source of untreated drinking water in south Asia and an estimated 37 million people are still exposed to elevated levels of As in Bangladesh(1). This field effort sought to address two questions. What mechanisms control the partitioning of As between groundwater and sediment? How does groundwater transport affect the spatial variability of dissolved As? Understanding the source of groundwater variability is essential for understanding how [As] will change with time, especially as Bangladesh and its water demands develop. Arsenic mobility and transport within the shallow aquifer was investigated at a 0.5 km2 site where [As] increases from <5 to 600 μg/L over 300 m as the aquifer becomes increasingly reducing. Aquifer recharge occurs in the raised, sandy village, where low [As] and elevated [SO4] are found. Until a few years ago, the net groundwater flow extended from the village, beneath a thickening silty layer covered by agricultural fields, towards a small stream. The sediments, however, were a homogenous, highly reduced sand throughout the site. Arsenic adsorption along this transect was investigated by two different approaches. Despite the geochemical gradients along the transect, adsorption of As under anaerobic conditions measured by spiking freshly collected sediment was remarkably uniform: Kd = 1.5 ± 0.5 L/kg, at 14 of 15 locations. Push- pull tests were used to alter groundwater [As] surrounding a well, without disturbing the sediment. The aquifer responded to the imposed dis-equilibrium by either adsorbing or desorbing As within a few days. These results provide further evidence that groundwater [As] is controlled by As sorption reactions with the sediment that reach equilibrium rapidly compared to the time scale of groundwater flow. A simple reactive-transport model for the site based on the measured partitioning coefficient, Kd, however, supports the notion that the [As] gradient observed reflects the gradual removal of As by groundwater flow over hundreds to thousands of years. The onset of irrigation and industrial pumping at this site has induced a reversal in flow, consequently groundwater now moves from high [As] into low [As] areas. This change could result in rising [As] to levels >50 μg/L in the village within the next few decades. The rapid economic development of Bangladesh could induce similar changes in groundwater flow, and thus As concentrations, elsewhere. This suggests that periodic monitoring of shallow wells low in As within regions of where the As content of groundwater is variable is particularly important. The size of the pool of As adsorbed on the sediment also indicates that current attempts to flush Bangladeshi aquifers “clean” through increased pumping will likely be ineffective. 1. BBS/UNICEF. Bangladesh: Multiple Indicator Cluster Survey, 2009. (Dhaka, Bangladesh, 2009).

Investigation of the influence of groundwater advection on energy extraction rates for sustainable borehole heat exchanger operation

NASA Astrophysics Data System (ADS)

Schelenz, Sophie; Dietrich, Peter; Vienken, Thomas

2016-04-01

A sustainable thermal exploitation of the shallow subsurface requires a precise understanding of all relevant heat transport processes. Currently, planning practice of shallow geothermal systems (especially for systems < 30 kW) focuses on conductive heat transport as the main energy source while the impact of groundwater flow as the driver for advective heat transport is neglected or strongly simplified. The presented study proves that those simplifications of complex geological and hydrogeological subsurface characteristics are insufficient for a precise evaluation of site-specific energy extraction rates. Based on synthetic model scenarios with varying subsurface conditions (groundwater flow velocity and aquifer thickness) the impact of advection on induced long term temperature changes in 5 and 10 m distance of the borehole heat exchanger is presented. Extending known investigations, this study enhances the evaluation of shallow geothermal energy extraction rates by considering conductive and advective heat transport under varying aquifer thicknesses. Further, it evaluates the impact of advection on installation lengths of the borehole heat exchanger to optimize the initial financial investment. Finally, an evaluation approach is presented that classifies relevant heat transport processes according to their Péclet number to enable a first quantitative assessment of the subsurface energy regime and recommend further investigation and planning procedures.

Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin, environmental setting and study design

USGS Publications Warehouse

Stark, J.R.; Andrews, W.J.; Fallon, J.D.; Fong, A.L.; Goldstein, R.M.; Hanson, P.E.; Kroening, S.E.; Lee, K.E.

1996-01-01

Environmental stratification consists of dividing the study unit into subareas with homogeneous characteristics to assess natural and anthropogenic factors affecting water quality. The assessment of water quality in streams and in aquifers is based on the sampling design that compares water quality within homogeneous subareas defined by subbasins or aquifer boundaries. The study unit is stratified at four levels for the surface-water component: glacial deposit composition, surficial geology, general land use and land cover, and secondary land use. Ground-water studies emphasize shallow ground water where quality is most likely influenced by overlying land use and land cover. Stratification for ground-water sampling is superimposed on the distribution of shallow aquifers. For each aquifer and surface-water basin this stratification forms the basis for the proposed sampling design used in the Upper Mississippi River Basin National Water-Quality Assessment.

Coastal ground water at risk - Saltwater contamination at Brunswick, Georgia and Hilton Head Island, South Carolina

USGS Publications Warehouse

Krause, Richard E.; Clarke, John S.

2001-01-01

IntroductionSaltwater contamination is restricting the development of ground-water supply in coastal Georgia and adjacent parts of South Carolina and Florida. The principal source of water in the coastal area is the Upper Floridan aquifer—an extremely permeable and high-yielding aquifer—which was first developed in the late 1800s. Pumping from the aquifer has resulted in substantial ground-water-level decline and subsequent saltwater intrusion of the aquifer from underlying strata containing highly saline water at Brunswick, Georgia, and with encroachment of sea-water into the aquifer at the northern end of Hilton Head Island, South Carolina. The saltwater contamination at these locations has constrained further development of the Upper Floridan aquifer in the coastal area and has created competing demands for the limited supply of freshwater. The Georgia Department of Natural Resources, Georgia Environmental Protection Division (GaEPD) has restricted permitted withdrawal of water from the Upper Floridan aquifer in parts of the coastal area (including the Savannah and Brunswick areas) to 1997 rates, and also has restricted additional permitted pumpage in all 24 coastal area counties to 36 million gallons per day above 1997 rates. These actions have prompted interest in alternative management of the aquifer and in the development of supplemental sources of water supply including those from the shallower surficial and upper and lower Brunswick aquifers and from the deeper Lower Floridan aquifer.

Regional-scale brine migration along vertical pathways due to CO2 injection - Part 2: A simulated case study in the North German Basin

NASA Astrophysics Data System (ADS)

Kissinger, Alexander; Noack, Vera; Knopf, Stefan; Konrad, Wilfried; Scheer, Dirk; Class, Holger

2017-06-01

Saltwater intrusion into potential drinking water aquifers due to the injection of CO2 into deep saline aquifers is one of the hazards associated with the geological storage of CO2. Thus, in a site-specific risk assessment, models for predicting the fate of the displaced brine are required. Practical simulation of brine displacement involves decisions regarding the complexity of the model. The choice of an appropriate level of model complexity depends on multiple criteria: the target variable of interest, the relevant physical processes, the computational demand, the availability of data, and the data uncertainty. In this study, we set up a regional-scale geological model for a realistic (but not real) onshore site in the North German Basin with characteristic geological features for that region. A major aim of this work is to identify the relevant parameters controlling saltwater intrusion in a complex structural setting and to test the applicability of different model simplifications. The model that is used to identify relevant parameters fully couples flow in shallow freshwater aquifers and deep saline aquifers. This model also includes variable-density transport of salt and realistically incorporates surface boundary conditions with groundwater recharge. The complexity of this model is then reduced in several steps, by neglecting physical processes (two-phase flow near the injection well, variable-density flow) and by simplifying the complex geometry of the geological model. The results indicate that the initial salt distribution prior to the injection of CO2 is one of the key parameters controlling shallow aquifer salinization. However, determining the initial salt distribution involves large uncertainties in the regional-scale hydrogeological parameterization and requires complex and computationally demanding models (regional-scale variable-density salt transport). In order to evaluate strategies for minimizing leakage into shallow aquifers, other target variables can be considered, such as the volumetric leakage rate into shallow aquifers or the pressure buildup in the injection horizon. Our results show that simplified models, which neglect variable-density salt transport, can reach an acceptable agreement with more complex models.

Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

DOE PAGES

Dai, Zhenxue; Keating, Elizabeth; Bacon, Diana H.; ...

2014-03-07

Carbon sequestration in geologic reservoirs is an important approach for mitigating greenhouse gases emissions to the atmosphere. This study first develops an integrated Monte Carlo method for simulating CO 2 and brine leakage from carbon sequestration and subsequent geochemical interactions in shallow aquifers. Then, we estimate probability distributions of five risk proxies related to the likelihood and volume of changes in pH, total dissolved solids, and trace concentrations of lead, arsenic, and cadmium for two possible consequence thresholds. The results indicate that shallow groundwater resources may degrade locally around leakage points by reduced pH and increased total dissolved solids (TDS).more » The volumes of pH and TDS plumes are most sensitive to aquifer porosity, permeability, and CO 2 and brine leakage rates. The estimated plume size of pH change is the largest, while that of cadmium is the smallest among the risk proxies. Plume volume distributions of arsenic and lead are similar to those of TDS. The scientific results from this study provide substantial insight for understanding risks of deep fluids leaking into shallow aquifers, determining the area of review, and designing monitoring networks at carbon sequestration sites.« less

Sea-level rise and coastal groundwater inundation and shoaling at select sites in California, USA

USGS Publications Warehouse

Hoover, Daniel J.; Odigie, Kingsley; Swarzenski, Peter W.; Barnard, Patrick

2017-01-01

Study regionThe study region spans coastal California, USA, and focuses on three primary sites: Arcata, Stinson Beach, and Malibu Lagoon.Study focus1 m and 2 m sea-level rise (SLR) projections were used to assess vulnerability to SLR-driven groundwater emergence and shoaling at select low-lying, coastal sites in California. Separate and combined inundation scenarios for SLR and groundwater emergence were developed using digital elevation models of study site topography and groundwater surfaces constructed from well data or published groundwater level contours.New hydrological insights for the regionSLR impacts are a serious concern in coastal California which has a long (∼1800 km) and populous coastline. Information on the possible importance of SLR-driven groundwater inundation in California is limited. In this study, the potential for SLR-driven groundwater inundation at three sites (Arcata, Stinson Beach, and Malibu Lagoon) was investigated under 1 m and 2 m SLR scenarios. These sites provide insight into the vulnerability of Northern California coastal plains, coastal developments built on beach sand or sand spits, and developed areas around coastal lagoons associated with seasonal streams and berms. Northern California coastal plains with abundant shallow groundwater likely will see significant and widespread groundwater emergence, while impacts along the much drier central and southern California coast may be less severe due to the absence of shallow groundwater in many areas. Vulnerability analysis is hampered by the lack of data on shallow coastal aquifers, which commonly are not studied because they are not suitable for domestic or agricultural use. Shallow saline aquifers may be present in many areas along coastal California, which would dramatically increase vulnerability to SLR-driven groundwater emergence and shoaling. Improved understanding of the extent and response of California coastal aquifers to SLR will help in preparing for mitigation and adaptation.

Occurrence of Pharmaceuticals in Shallow Ground-Water of Suffolk County, New York, 2002-05

USGS Publications Warehouse

Benotti, Mark J.; Fisher, Shawn; Terracciano, Stephen

2006-01-01

Seventy (70) water samples were collected from 61 wells in the upper glacial and Magothy aquifers (9 wells were sampled twice) during 2002-05 and analyzed for 24 pharmaceuticals. Wells were selected for their proximity to known wastewater-treatment facilities that discharge to the shallow upper glacial aquifer. Pharmaceuticals were detected in 28 of the 70 samples, 19 of which contained one compound, and 9 of which contained two or more compounds. Concentrations of detected compounds were extremely low; most ranged from 0.001 to 0.1 microgram per liter (part per billion). The two most commonly detected compounds were carbamazepine (an antiepileptic drug) and sulfamethoxazole (an antibiotic). Occurrence of pharmaceutical compounds in Suffolk County ground-water is less prevalent than in susceptible streams of the United States that were tested in 1998-2000, but the similarity of median concentrations of the detected compounds of the two data sets indicates that current wastewater practices can serve to introduce pharmaceuticals to this shallow aquifer.

Ground-water resources of Camas Prairie, Camas and Elmore Counties, Idaho

USGS Publications Warehouse

Walton, William Clarence

1962-01-01

Camas Prairie is an eastward-trending intermontane basin along the north flank of the Snake River Plain in southern Idaho. The basin is about 40 miles long and averages about 8 miles wide. It was formed as a structural depression in which a considerable thickness of alluvial and lake deposits accumulated behind basalt flows, which at times blocked the outlet to the east. Intrusive and extrusive rocks of Cretaceous to Quarternary age enclose the basin on the north, west, and east. The enclosing rocks yield small amounts of water to springs and wells from the weathered mantle and fractures. The principal aquifers are sand and gravel in the alluvial fill, and basalt. Water in the shallow deposits is not confined, and the water table generally is less than 10 feet below the surface at most places. Ground water in the deeper deposits occurs chiefly in two horizons that comprise the upper and lower artesian aquifers. Throughout much of the prairie, the pressure is sufficient that water will flow from wells in these aquifers. Recharge to the basin is from direct precipitation and percolation of stream runoff from the bordering mountains. Ground water moves from the higher areas at the base of the encircling mountains toward the center of the basin and the eastern outlet. The artesian aquifers leak by upward percolation through the imperfectly confining beds and help maintain the shallow water table. Basalt, which interfingers with the alluvial deposits, is an important aquifer near the southeast margin of the prairie and at the east end. Annual recharge to the artesian aquifers is estimated to be about 40,000 acre-feet. Discharge from the artesian aquifers is about equally divided between upward leakage to the shallow aquifers and underflow out of the prairie. Most of the underflow discharges into Camas Creek or Magic Reservoir east of the prairie; little of the underflow reaches the Snake River Plain. Wells drilled for irrigation generally yield 500 to 1,200 gallons per minute from the artesian aquifers. Better construction and development methods would result in considerably better yields. Wells drilled in the basalt will yield 2,000 to 3,000 gallons per minute with moderate drawdowns. Computations made using aquifer coefficients, estimated on the basis of data collected during the investigation, suggest that 12,000 acre-feet of ground water might be withdrawn annually. However, the aquifers are limited in areal extent, and productivity of the alluvial aquifers is not great. Consequently heavy development would result in large drawdowns in wells, and there would be much interference between wells. The postulated large withdrawals from wells on the prairie would be supplied in part by a reduction in underflow from the prairie and in part by a decrease in leakage from the artesian aquifers, which in turn would cause a decline in the shallow water table.

Hydrogeology, water quality, and potential for transport of organochlorine pesticides in ground water at the North Hollywood Dump, Memphis, Tennessee

USGS Publications Warehouse

Broshears, R.E.; Bradley, M.W.

1992-01-01

Geologic, hydrologic, and water-quality data indicate that ground-water contamination is confined to shallow horizons within the unconfined aquifer underlying the North Hollywood Dump in Memphis, Tennessee. The dump is a closed municipal-industrial landfill that has been ranked as Tennessee's potentially most dangerous hazardous-waste site. Toxic constituents of concern at the dump include residues from the manufacture of organochlorine pesticides. The dump overlies an unconfined aquifer of unconsolidated sands, silts, and clays. During average hydrologic conditions, ground waterflows beneath the dump at a mean velocity of approximately 3 feet per day and discharges to the Wolf River. Leachate from the dump mixes with underlying ground water, resulting in increased concentrations of dissolved solids and organic carbon downgradient from the dump. The mobility of chlordane, a representative organochlorine pesticide, is limited by its low solubility and its strong affinity for sand, silt, and clays of the aquifer. Degradation of chlordane may occur slowly, if at all, in the aquifer. Based on estimates of mean ground-water velocity and retardation of the pesticide due to sorption, mean travel times for chlordane migrating from the dump to the ground-water discharge zone are of the order of 50 to 500 years. Simulations of chlordane concentration resulting from the discharge of contaminated ground water and complete mixing in the Wolf River are sensitive to assumptions about chlordane persistence in the unconfined aquifer. If the half life of chlordane in the aquifer is assumed to be 30 years or less, the simulated concentration of chlordane in the Wolf River under average flow conditions is less than the most stringent water-quality criterion.

Hydrogeologic Heterogeneity Enhances the Transfer of Salt Toward the High-Quality Deep Aquifers of the Western San Joaquin Valley (CA, USA)

NASA Astrophysics Data System (ADS)

Henri, C. V.; Harter, T.; Zhang, H.

2016-12-01

Increasing anthropogenic and drought stresses lead salinity to be of serious concern within regard to with the sustainability of regional groundwater quality. Agricultural basins of the Central Valley, CA (USA) are, and will continue to be, impacted by salinity issues in the coming future decades and or centuries. The aquifer system below the Western San Joaquin Valley is characterized by a shallow unconfined aquifer with high salinity overlying high quality semi-confined and deeper confined aquifers. A key challenge in the area is to predict if, when and how water traveling from the the low-quality shallow groundwater will reach and degrade the deeper semi-confined and confined aquifers. Previous studies, accounting for a simplified description of the aquifer hydraulic properties in their flow model, concluded that saline shallow groundwater would need 200-400 years to reach the semi-confined aquifer and 250-600 years to impact the deeper confined aquifer. However, well known heterogeneities in aquifer hydraulic properties significantly impact contaminant transport due to preferential flow paths and increased dispersion. Our study aims to (1) better understand the impact of heterogeneous hydraulic properties on the distribution of travel times from non-point source contamination, and (2) reassess the temporal scale of salt transfer into the deeper aquifers of the Western San Joaquin Valley. A detailed non-stationary geostatistical model was developed to describe the spatial variability of hydrofacies in great detail at the basin scale. The hydraulic properties corresponding to each hydrofacies are then calibrated in order to reproduce water fluxes previously modeled and calibrated. Subsequently, we use the random-walk particle tracking method to simulate the advective-dispersive transport of salt throughout the study area from a non-point source zone represented by the entire top layer of the model. The flux concentrations of solute crossing a series of monitoring wells and the bottom edge of the system are recorded over a period of 2000 years. The travel-time analysis from these breakthrough curves indicates that a significant portion of injected salt is very likely to reach the deeper confined aquifer within the next 50 to 100 years in zones with high aquifer connectivity.

Groundwater-quality data in the Monterey–Salinas shallow aquifer study unit, 2013: Results from the California GAMA Program

USGS Publications Warehouse

Goldrath, Dara A.; Kulongoski, Justin T.; Davis, Tracy A.

2016-09-01

Groundwater quality in the 3,016-square-mile Monterey–Salinas Shallow Aquifer study unit was investigated by the U.S. Geological Survey (USGS) from October 2012 to May 2013 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project. The GAMA Monterey–Salinas Shallow Aquifer study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the shallow-aquifer systems in parts of Monterey and San Luis Obispo Counties and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The shallow-aquifer system in the Monterey–Salinas Shallow Aquifer study unit was defined as those parts of the aquifer system shallower than the perforated depth intervals of public-supply wells, which generally corresponds to the part of the aquifer system used by domestic wells. Groundwater quality in the shallow aquifers can differ from the quality in the deeper water-bearing zones; shallow groundwater can be more vulnerable to surficial contamination.Samples were collected from 170 sites that were selected by using a spatially distributed, randomized grid-based method. The study unit was divided into 4 study areas, each study area was divided into grid cells, and 1 well was sampled in each of the 100 grid cells (grid wells). The grid wells were domestic wells or wells with screen depths similar to those in nearby domestic wells. A greater spatial density of data was achieved in 2 of the study areas by dividing grid cells in those study areas into subcells, and in 70 subcells, samples were collected from exterior faucets at sites where there were domestic wells or wells with screen depths similar to those in nearby domestic wells (shallow-well tap sites).Field water-quality indicators (dissolved oxygen, water temperature, pH, and specific conductance) were measured, and samples for analysis of inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids, and alkalinity) were collected at all 170 sites. In addition to these constituents, the samples from grid wells were analyzed for organic constituents (volatile organic compounds, pesticides and pesticide degradates), constituents of special interest (perchlorate and N-nitrosodimethylamine, or NDMA), radioactive constituents (radon-222 and gross-alpha and gross-beta radioactivity), and geochemical and age-dating tracers (stable isotopes of carbon in dissolved inorganic carbon, carbon-14 abundances, stable isotopes of hydrogen and oxygen in water, and tritium activities).Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 11 percent of the wells in the Monterey–Salinas Shallow Aquifer study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. With the exception of trace elements, blanks rarely contained detectable concentrations of any constituent, indicating that contamination from sample-collection procedures was not a significant source of bias in the data for the groundwater samples. Low concentrations of some trace elements were detected in blanks; therefore, the data were re-censored at higher reporting levels. Replicate samples generally were within the limits of acceptable analytical reproducibility. The median values of matrix-spike recoveries were within the acceptable range (70 to 130 percent) for the volatile organic compounds (VOCs) and N-nitrosodimethylamine (NDMA), but were only approximately 64 percent for pesticides and pesticide degradates.The sample-collection protocols used in this study were designed to obtain representative samples of groundwater. The quality of groundwater can differ from the quality of drinking water because water chemistry can change as a result of contact with plumbing systems or the atmosphere; because of treatment, disinfection, or blending with water from other sources; or some combination of these. Water quality in domestic wells is not regulated in California, however, to provide context for the water-quality data presented in this report, results were compared to benchmarks established for drinking-water quality. The primary comparison benchmarks were maximum contaminant levels established by the U.S. Environmental Protection Agency and the State of California (MCL-US and MCL-CA, respectively). Non-regulatory benchmarks were used for constituents without maximum contaminant levels (MCLs), including Health Based Screening Levels (HBSLs) developed by the USGS and State of California secondary maximum contaminant levels (SMCL-CA) and notification levels. Most constituents detected in samples from the Monterey–Salinas Shallow Aquifer study unit had concentrations less than their respective benchmarks.Of the 148 organic constituents analyzed in the 100 grid-well samples, 38 were detected, and all concentrations were less than the benchmarks. Volatile organic compounds were detected in 26 of the grid wells, and pesticides and pesticide degradates were detected in 28 grid wells. The special-interest constituent NDMA was detected above the HBSL in three samples, one of which also had a perchlorate concentration greater than the MCL-CA.Of the inorganic constituents, 6 were detected at concentrations above their respective MCL benchmarks in grid-well samples: arsenic (5 grid wells above the MCL of 10 micrograms per liter, μg/L), selenium (3 grid wells, MCL of 50 μg/L), uranium (4 grid wells, MCL of 30 μg/L), nitrate (16 grid wells, MCL of 10 milligrams per liter, mg/L), adjusted gross alpha particle activity (10 grid wells, MCL of 15 picocuries per liter, pCi/L), and gross beta particle activity (1 grid well, MCL of 50 pCi/L). An additional 4 inorganic constituents were detected at concentrations above their respective HBSL benchmarks in grid-well samples: boron (1 grid well above the HBSL of 6,000 μg/L), manganese (8 grid wells, HBSL of 300 μg/L), molybdenum (6 grid wells, HBSL of 40 μg/L), and strontium (6 grid wells, HBSL of 4,000 μg/L). Of the inorganic constituents, 4 were detected at concentrations above their non-health based SMCL benchmarks in grid-well samples: iron (9 grid wells above the SMCL of 300 μg/L), chloride (7 grid wells, SMCL of 500 mg/L), sulfate (14 grid wells, SMCL of 500 mg/L), and total dissolved solids (27 grid wells, SMCL of 1,000 mg/L).Of the inorganic constituents analyzed in the 70 shallow-well tap sites, 10 were detected at concentrations above the benchmarks. Of the inorganic constituents, 3 were detected at concentrations above their respective MCL benchmarks in shallow-well tap sites: arsenic (2 shallow-well tap sites above the MCL of 10 μg/L), uranium (2 shallow-well tap sites, MCL of 30 μg/L), and nitrate (24 shallow-well tap sites, MCL of 10 mg/L). An additional 3 inorganic constituents were detected above their respective HBSL benchmarks in shallow-well tap sites: manganese (4 shallow-well tap sites above the HBSL of 300 μg/L), molybdenum (4 shallow-well tap sites, HBSL of 40 μg/L), and zinc (2 shallow-well tap sites, HBSL of 2,000 μg/L). Of the inorganic constituents, 4 were detected at concentrations above their non-health based SMCL benchmarks in shallow-well tap sites: iron (6 shallow-well tap sites above the SMCL of 300 μg/L), chloride (1 shallow-well tap site, SMCL of 500 mg/L), sulfate (9 shallow-well tap sites, SMCL of 500 mg/L), and total dissolved solids (15 shallow-well tap sites, SMCL of 1,000 mg/L).

Morphometric analysis with open source software to explore shallow hydrogeological features in Senegal and Guinea

NASA Astrophysics Data System (ADS)

Fussi, Fabio; Di Leo, Margherita; Bonomi, Tullia; Di Mauro, Biagio; Fava, Francesco; Fumagalli, Letizia; Hamidou Kane, Cheikh; Faye, Gayane; Niang, Magatte; Wade, Souleye; Hamidou, Barry; Colombo, Roberto

2015-04-01

Water represents a vital resource for everyone on this Planet, but, for some populations, the access to potable water is not given for granted. Recently, the interest in low cost technical solutions to improve access to ground water in developing countries, especially for people located in remote areas, has increased. Manual drilling (techniques to drill boreholes for water using human or animal power) is well known and practiced for centuries in many countries and represents a valid alternative to increase water access. Lately, this practice has raised the attention of national governments and international organizations. This technique is applicable only where hydrogeological conditions are suitable, namely in presence of thick layers of unconsolidated sediments and a shallow water table Aim of this study is exploring the potential of morphometric analysis to improve the methodology to identify areas with suitable hydrogeological conditions for manual drilling, supporting the implementation of water supply programs that can have great impact on living condition of the population. The characteristics of shallow geological layers are strongly dependent from geomorphological processes and are usually reflected in the morphological characteristics of landforms. Under these hypotheses, we have been investigating the geo-statistical correlation between several morphometric variables and a set of hydrogeological variables used in the estimation of suitability for manual drilling: thickness of unconsolidated sediments, texture, hydraulic conductivity of shallow aquifer, depth of water table. The morphology of two study areas with different landscape characteristics in Guinea and Senegal has been investigated coupling the Free and Open Source Software GRASS GIS and R. Several morphometric parameters have been extracted from ASTER GDEM digital elevation model, and have been compared with a set of hydrogeological characteristics obtained from semi-automatic analysis of stratigraphic logs from water boreholes. We observed the relationships between the spatial distribution of hydrogeological features and the morphology, applying multivariate statistical analysis. The ultimate goal of this study is to infer hydrogeological information of shallow aquifers, exploiting morphometric parameters (together with other layers of information from existing thematic maps and remote sensing) and to reconstruct the geometry and the characteristic of shallow porous aquifer. This research is part of a larger project financed by NERC (National Environment Research Council, UK) in the framework of the program UPGRO (Unlocking the Potential of Groundwater for the Poors), with the collaboration of different partners from Italy, Senegal and Guinea

The origin of high hydrocarbon groundwater in shallow Triassic aquifer in Northwest Guizhou, China.

PubMed

Liu, Shan; Qi, Shihua; Luo, Zhaohui; Liu, Fangzhi; Ding, Yang; Huang, Huanfang; Chen, Zhihua; Cheng, Shenggao

2018-02-01

Original high hydrocarbon groundwater represents a kind of groundwater in which hydrocarbon concentration exceeds 0.05 mg/L. The original high hydrocarbon will significantly reduce the environment capacity of hydrocarbon and lead environmental problems. For the past 5 years, we have carried out for a long-term monitoring of groundwater in shallow Triassic aquifer in Northwest Guizhou, China. We found the concentration of petroleum hydrocarbon was always above 0.05 mg/L. The low-level anthropogenic contamination cannot produce high hydrocarbon groundwater in the area. By using hydrocarbon potential, geochemistry and biomarker characteristic in rocks and shallow groundwater, we carried out a comprehensive study in Dalongjing (DLJ) groundwater system to determine the hydrocarbon source. We found a simplex hydrogeology setting, high-level water-rock-hydrocarbon interaction and obviously original hydrocarbon groundwater in DLJ system. The concentration of petroleum hydrocarbon in shallow aquifer was found to increase with the strong water-rock interaction. Higher hydrocarbon potential was found in the upper of Guanling formation (T 2 g 3 ) and upper of Yongningzhen formation (T 1 yn 4 ). Heavily saturated carbon was observed from shallow groundwater, which presented similar distribution to those from rocks, especially from the deeper groundwater. These results indicated that the high concentrations of original hydrocarbon in groundwater could be due to the hydrocarbon release from corrosion and extraction out of strata over time.

Fate and origin of 1,2 - dichloropropane in an unconfined shallow aquifer

USGS Publications Warehouse

Tesoriero, Anthony J.; Loffler, F.E.; Liebscher, Hugh

2001-01-01

A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.

Reconnaissance of the ground-water, surface-water system in the Zekiah Swamp Run basin, Charles and Prince Georges Counties, Maryland

USGS Publications Warehouse

Hopkins, H.T.; Fisher, G.T.; McGreevy, L.J.

1986-01-01

The water table in the alluvium of the Zekiah Swamp Run valley in southern Maryland is above stream level during most of the year and the alluvial aquifer contributes water to the stream. During the summer, however, high evapotranspiration sometimes lowers the water table below the stream level. Water then moves from the stream to the alluvium and, at times, reaches of the stream become dry. Pumping from the confined aquifers has caused water levels to decline several tens of ft, which has increased the downward gradient between the water-table aquifer and the underlying confined aquifers. Three synoptic surveys of base flow show areal and temporal variations in stream discharge, pH, specific conductance, dissolved oxygen, and temperature. April 1984 base flows were high (141 cu ft/sec, at the Route 6 gage) because of high precipitation during March. July 1983 base flows were low (2.35 cu ft/sec at the Route 6 gage) and showed significant loss of streamflow because of high antecedent evapotranspiration. Estimates of inflow and outflow of the Zekiah Swamp Run basin above Route 6 during the 1984 water year include: Precipitation, 50.21 in; stream outflow, 20.10 in; shallow groundwater underflow, 0.1 in; stream outflow, 20.10 in; shallow groundwater underflow, 0.1 in; and evapotranspiration, 33 in. A streamflow budget of a 5.1 mi area of the valley of Zekiah Swamp Run between Routes 5 and 6, during the April 1984 survey and a loss of almost 5 cu ft during the July 1983 survey. (Author 's abstract)

Redox potential of shallow groundwater by 1-month continuous in situ potentiometric measurements

NASA Astrophysics Data System (ADS)

Ioka, Seiichiro; Muraoka, Hirofumi; Suzuki, Yota

2017-10-01

One-month continuous in situ potentiometric measurements of redox potential (Eh) were used to investigate the dominant redox processes in the shallow groundwater (i.e., <10 m) of a Holocene aquifer, Aomori City, northern Japan. The Eh values, which were determined using a platinum electrode, were -163, -169 and -173 mV, respectively, for three monitoring campaigns. The temperatures and pH values of shallow groundwater during all three periods were approximately 12 °C and 6.6, respectively. Dissolved oxygen and sulfide ion concentrations were not detected. Chemical analyses showed that the shallow groundwater is Na-Fe-HCO3 type, and contains over 40 mg/L of Fe (the dominant cation) and over 200 mg/L of HCO3 - (the dominant anion). A good fit was found between measured Eh values and Eh values calculated using thermodynamic data of fine-grained goethite. This suggests that Fe redox system is related to the Eh values of shallow groundwater in the Aomori City aquifer.

Numerical simulation of seasonal heat storage in a contaminated shallow aquifer - Temperature influence on flow, transport and reaction processes

NASA Astrophysics Data System (ADS)

Popp, Steffi; Beyer, Christof; Dahmke, Andreas; Bauer, Sebastian

2015-04-01

The energy market in Germany currently faces a rapid transition from nuclear power and fossil fuels towards an increased production of energy from renewable resources like wind or solar power. In this context, seasonal heat storage in the shallow subsurface is becoming more and more important, particularly in urban regions with high population densities and thus high energy and heat demand. Besides the effects of increased or decreased groundwater and sediment temperatures on local and large-scale groundwater flow, transport, geochemistry and microbiology, an influence on subsurface contaminations, which may be present in the urban surbsurface, can be expected. Currently, concerns about negative impacts of temperature changes on groundwater quality are the main barrier for the approval of heat storage at or close to contaminated sites. The possible impacts of heat storage on subsurface contamination, however, have not been investigated in detail yet. Therefore, this work investigates the effects of a shallow seasonal heat storage on subsurface groundwater flow, transport and reaction processes in the presence of an organic contamination using numerical scenario simulations. A shallow groundwater aquifer is assumed, which consists of Pleistoscene sandy sediments typical for Northern Germany. The seasonal heat storage in these scenarios is performed through arrays of borehole heat exchangers (BHE), where different setups with 6 and 72 BHE, and temperatures during storage between 2°C and 70°C are analyzed. The developing heat plume in the aquifer interacts with a residual phase of a trichloroethene (TCE) contamination. The plume of dissolved TCE emitted from this source zone is degraded by reductive dechlorination through microbes present in the aquifer, which degrade TCE under anaerobic redox conditions to the degradation products dichloroethene, vinyl chloride and ethene. The temperature dependence of the microbial degradation activity of each degradation step is taken into account for the numerical simulations. Hence, the simulations are performed with the code OpenGeoSys, which is especially suited for simulating coupled thermal, hydraulic and geochemical processes. The scenario simulations show an increase in the source zone emission of TCE at higher temperatures, which is primarily due to the focusing of the groundwater flow in the area of higher temperatures within the source zone and to a lesser part to an increase in TCE solubility. On the other hand, a widening of the contaminant plume and enlargement of the area for TCE biodegradation is induced, which leads to an increase in biodegradation of the chlorinated hydrocarbons. In combination almost no change in the overall ratio of degraded to emitted TCE is found, which shows that the seasonal heat storage is not negatively influencing the present TCE contamination under these assumptions. The results of this work serve to support the risk assessment for the interaction between heat storage and contaminations in the shallow subsurface and show positive interactions as well as possible conflicts.

Distribution and formation of high-fluorine groundwater in China

NASA Astrophysics Data System (ADS)

Fuhong, Ren; Shuqin, Jiao

1988-08-01

In China, high-fluorine groundwater, which contains more than 1.0 mg/l fluorine, is mainly distributed in shallow aquifers of unconsolidated deposits in some arid and semiarid areas, deep aquifers of unconsolidated deposits in semiarid areas, as well as in hot springs of bed rock mountainous area and aquifers of fluorite-mine area. Its formation is controlled by regional climate factors, seepage conditions of groundwater, as well as the hydrogeochemical environment. The physicochemical properties of soil mass of the aeration zone play an important role in fluorine concentration in shallow groundwater. In the coastal plain areas, where groundwater is mainly recharged and discharged vertically, and its regime type belongs to the type of infiltration—evaporation, the grain size of soil mass of aeration zone directly influences the amount of fluorine transferred from solid medium into water; and the chemical constituents of the soil mass of aeration zone controls the chemical characteristics of the shallow groundwater, consequently influencing the concentration condition of fluorine in water. Fluorine ion in groundwater continuously migrates and concentrates under the comprehensive influence of many factors. High-fluorine groundwater exceeding the sanitary standard (1.0 mg/l) has an obvious zonality in regional distribution in China. Based on current statistics, there are roughly 50 million people (Zheng Qifu 1986) who have consumed water which exceeds standards in China. In highfluorine groundwater areas, endemic fluorine-poisoning often arises to different extents, affecting human health seriously. At the end of 1983, over 20 million patients were suffering from fluorine-poisoning diseases in China (Xu Guozhang, unpublished data). Therefore, research of the distribution feature and formation mechanism of fluorine ion in groundwater has become an important task.

Aquifer geochemistry and effects of pumping on ground-water quality at the Green Belt Parkway Well Field, Holbrook, Long Island, New York

USGS Publications Warehouse

Brown, Craig J.; Colabufo, Steven; Coates, John D.

2002-01-01

Geochemistry, microbiology, and water quality of the Magothy aquifer at a new supply well in Holbrook were studied to help identify factors that contribute to iron-related biofouling of public-supply wells. The organic carbon content of borehole sediments from the screen zone, and the dominant terminal electron-accepting processes (TEAPs), varied by depth. TEAP assays of core sediments indicated that iron reduction, sulfate reduction, and undetermined (possibly oxic) reactions and microbial activity are correlated with organic carbon (lignite) content. The quality of water from this well, therefore, reflects the wide range of aquifer microenvironments at this site.High concentrations of dissolved iron (3.6 to 6.4 micromoles per liter) in water samples from this well indicate that some water is derived from Fe(III)-reducing sediments within the aquifer, but traces of dissolved oxygen indicate inflow of shallow, oxygenated water from shallow units that overlie the local confining units. Water-quality monitoring before and during a 2-day pumping test indicates that continuous pumping from the Magothy aquifer at this site can induce downward flow of shallow, oxygenated water despite the locally confined conditions. Average concentrations of dissolved oxygen are high (5.2 milligrams per liter, or mg/L) in the overlying upper glacial aquifer and at the top of the Magothy aquifer (4.3 mg/L), and low ( < 0.1 mg/L) in the deeper, anaerobic part of the Magothy; average concentrations of phosphate are high (0.4 mg/L) in the upper glacial aquifer and lower (0.008 mg/L) at the top of the Magothy aquifer and in the deeper part of the Magothy (0.013 mg/L). Concentrations of both constituents increased during the 2 days of pumping. The δ34S of sulfate in shallow ground water from observation wells (3.8 to 6.4 per mil) was much heavier than that in the supplywell water (-0.1 per mil) and was used to help identify sources of water entering the supply well. The δ34S of sulfate in a deep observation well adjacent to the supply well increased from 2.4 per mil before pumping to 3.3 per mil after pumping; this confirms that the pumping induced downward migration of water. The lighter δ34S value in the pumped water than in the adjacent observation well probably indicates FeS2 oxidation (which releases light δ34S in adjacent sediments) by the downward flow of oxygenated water.

Groundwater quality in the shallow aquifers of the Monterey Bay, Salinas Valley, and adjacent highland areas, California

USGS Publications Warehouse

Burton, Carmen

2018-05-30

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The shallow aquifers of the groundwater basins around Monterey Bay, the Salinas Valley, and the highlands adjacent to the Salinas Valley constitute one of the study units.

Geohydrology, simulation of ground-water flow, and ground-water quality at two landfills, Marion County, Indiana

USGS Publications Warehouse

Duwelius, R.F.; Greeman, T.K.

1989-01-01

Concentrations of dissolved inorganic substances in ground-water samples indicate that leachate from both landfills is reaching the shallow aquifers. The effect on deeper aquifers is small because of the predominance of horizontal ground-water flow and discharge to the streams. Increases in almost all dissolved constituents were observed in shallow wells that are screened beneath and downgradient from the landfills. Several analyses, especially those for bromide, dissolved solids, and ammonia, were useful in delineating the plume of leachate at both landfills.

Reinterpreting the importance of oxygen-based biodegradation in chloroethene-contaminated groundwater

USGS Publications Warehouse

Bradley, Paul M.

2011-01-01

Chlororespiration is common in shallow aquifer systems under conditions nominally identified as anoxic. Consequently, chlororespiration is a key component of remediation at many chloroethene-contaminated sites. In some instances, limited accumulation of reductive dechlorination daughter products is interpreted as evidence that natural attenuation is not adequate for site remediation. This conclusion is justified when evidence for parent compound (tetrachloroethene, PCE, or trichloroethene, TCE) degradation is lacking. For many chloroethene-contaminated shallow aquifer systems, however, nonconservative losses of the parent compounds are clear but the mass balance between parent compound attenuation and accumulation of reductive dechlorination daughter products is incomplete. Incomplete mass balance indicates a failure to account for important contaminant attenuation mechanisms and is consistent with contaminant degradation to nondiagnostic mineralization products like CO2. While anoxic mineralization of chloroethene compounds has been proposed previously, recent results suggest that oxygen-based mineralization of chloroethenes also can be significant at dissolved oxygen concentrations below the currently accepted field standard for nominally anoxic conditions. Thus, reassessment of the role and potential importance of low concentrations of oxygen in chloroethene biodegradation are needed, because mischaracterization of operant biodegradation processes can lead to expensive and ineffective remedial actions. A modified interpretive framework is provided for assessing the potential for chloroethene biodegradation under different redox conditions and the probable role of oxygen in chloroethene biodegradation.

Hydrogeology of the Olean area, Cattaraugus County, New York

USGS Publications Warehouse

Zarriello, Phillip J.; Reynolds, Richard J.

1987-01-01

Most principal aquifers in upstate New York are unconsolidated glacial and alluvial deposits within bedrock valleys. Groundwater in these aquifers can be under either water table (unconfined) or artesian (confined) conditions. Farms, industries, or towns and cities have been built upon many of these aquifers because they form level areas suitable for development and generally provide an ample groundwater supply. This development, coupled with the generally high permeability of these deposits and the typically shallow depth to the water table, makes groundwater in these aquifers susceptible to contamination from point sources such as landfills, road salt stockpiles, hydrocarbon fuel storage, and industrial facilities with a potential for contaminant leakage, in addition to urban and agricultural runoff, septic tank leachate, and other nonpoint sources. The report summarizes the geohydrology of the aquifer system in the Olean area. The large amount of geohydrologic data collected in the Olean area during previous and current investigations enabled the construction of nine maps: location and wells and test holes (plate 1), surficial geology (plate 2), geologic sections (plate 3), generalized bedrock topography (plate 4), potentiometric surface (plate 5), saturated thickness of the outwash aquifer (plate 6), generalized soil permeability (plate 7), land use (plate 8), and estimated well yields (plate 9). (Lantz-PTT)

Fast ground-water mixing and basal recharge in an unconfined, alluvial aquifer, Konza LTER Site, Northeastern Kansas

USGS Publications Warehouse

Macpherson, G.L.; Sophocleous, M.

2004-01-01

Ground-water chemistry and water levels at three levels in a well nest were monitored biweekly for two and a half years in a shallow unconfined floodplain aquifer in order to study the dynamics of such shallow aquifers. The aquifer, in northeastern Kansas, consists of high porosity, low hydraulic conductivity fine-grained sediments dominated by silt and bounded by fractured limestone and shale bedrock. Results show that the aquifer underwent chemical stratification followed by homogenization three times during the study period. The length of time between maximum stratification and complete homogenization was 3-5 months. The chemical parameters most useful for demonstrating the mixing trends were dissolved nitrate and sulfate. Higher nitrate concentrations were typical of unsaturated zone water and were sourced from fertilizer applied to the cultivated fields on the floodplain. Variations in sulfate concentrations are attributed to dissolution of rare gypsum in limestone bedrock and variable evapoconcentration in the unsaturated zone. The mixing of three chemically different waters (entrained, unsaturated-zone water; water entering the base of the floodplain aquifer; and water in residence before each mixing event) was simulated. The resident water component for each mixing event was a fixed composition based on measured water chemistry in the intermediate part of the aquifer. The entrained water composition was calculated using a measured composition of the shallow part of the aquifer and measurements of soil-water content in the unsaturated zone. The incoming basal water composition and the fractions of each mixing component were fitted to match the measured chemistry at the three levels in the aquifer. A conceptual model for this site explains: (1) rapid water-level rises, (2) water-chemistry changes at all levels in the aquifer coincident with the water-level rises, (3) low measured hydraulic conductivity of the valley fill and apparent lack of preferential flow pathways, (4) minuscule amounts of unsaturated-zone recharge, and (5) dissolved oxygen peaks in the saturated zone lagging water-level peaks. We postulate that rainfall enters fractures in bedrock adjacent to the floodplain. This recharge water moves rapidly through the fractured bedrock into the base of the floodplain aquifer. The recharge event through the bedrock causes a rapid rise in water level in the floodplain aquifer, and the chemistry of the deepest water in the floodplain aquifer changes at that time. The rising water also entrains slow-moving, nitrate-rich, unsaturated-zone water, altering the chemistry of water in the shallow part of the aquifer. Vertical chemical stratification in the aquifer is thus created by the change in water chemistry in the upper and lower parts of the saturated zone. As the water level begins to decline, the aquifer undergoes mixing that eventually results in homogeneous water chemistry. The rise in water level from the recharge event also displaces gas from the unsaturated zone that is then replaced as the water level declines following the recharge event. This new, oxygen-rich vadose-zone air equilibrates rapidly with saturated-zone water, resulting in a dissolved oxygen pulse in the ground water that peaks one-half to 2 months after the water-level peak. This oxygen pulse subsequently declines over a period of 2-6 months. ?? 2003 Elsevier B.V. All rights reserved.

Fate of microbial metabolites of hydrocarbons in a coastal plain aquifer: The role of electron acceptors

USGS Publications Warehouse

Cozzarelli, I.M.; Herman, J.S.; Baedecker, M. Jo

1995-01-01

A combined field and laboratory study was undertaken to understand the distribution and geochemical conditions that influence the prevalence of low molecular weight organic acids in groundwater of a shallow aquifer contaminated with gasoline. Aromatic hydrocarbons from gasoline were degraded by microbially mediated oxidation-reduction reactions, including reduction of nitrate, sulfate, and Fe(III). The biogeochemical reactions changed overtime in response to changes in the hydrogeochemical conditions in the aquifer. Aliphatic and aromatic organic acids were associated with hydrocarbon degradation in anoxic zones of the aquifer. Laboratory microcosms demonstrated that the biogeochemical fate of specific organic acids observed in groundwater varied with the structure of the acid and the availability of electron acceptors. Benzoic and phenylacetic acid were degraded by indigenous aquifer microorganisms when nitrate was supplied as an electron acceptor. Aromatic acids with two or more methyl substituants on the benzene ring persisted under nitrate-reducing conditions. Although iron reduction and sulfate reduction were important processes in situ and occurred in the microcosms, these reactions were not coupled to the biological oxidation of aromatic organic acids that were added to the microcosms as electron donors. ?? 1995 American Chemical Society.

Groundwater geochemistry in shallow aquifers above longwall mines in Illinois, USA

NASA Astrophysics Data System (ADS)

Booth, C. J.; Bertsch, L. P.

1999-12-01

Aquifers above high-extraction underground coal mines are not affected by mine drainage, but they may still exhibit changes in groundwater chemistry due to alterations in groundwater flow induced by mine subsidence. At two active longwall mine sites in Illinois, USA, glacial-drift aquifers were largely unaffected by mining, but the geochemistry of the bedrock aquifers changed during the post-mining water-level recovery. At the Jefferson site, brackish, high-sulfate water present in the upper bedrock shale briefly had lower values of total dissolved solids (TDS) after mining due to increased recharge from the overlying drift, whereas TDS and sulfate increased in the sodium-bicarbonate water present in the underlying sandstone due to downward leakage from the shale and lateral inflow of water through the sandstone. At the Saline site, sandstones contained water ranging from brackish sodium-chloride to fresh sodium-bicarbonate type. Post-mining recovery of the potentiometric levels was minimal, and the water had minor quality changes. Longwall mining affects geochemistry due to subsidence-related fracturing, which increases downward leakage from overlying units, and due to the temporary potentiometric depression and subsequent recovery, whereby water from surrounding areas of the aquifer recharges the affected zone above and adjacent to the mine.

Geothermal implications of a refined composition-age geologic map for the volcanic terrains of southeast Oregon, northeast California, and southwest Idaho, USA

USGS Publications Warehouse

Burns, Erick; Gannett, Marshall W.; Sherrod, David R.; Keith, Mackenzie K.; Curtis, Jennifer A.; Bartolino, James R.; Engott, John A.; Scandella, Benjamin P.; Stern, Michelle A.; Flint, Alan L.

2017-01-01

Sufficient temperatures to generate steam likely exist under most of the dominantly volcanic terrains of southeast Oregon, northeast California, and southeast Idaho, USA, but finding sufficient permeability to allow efficient advective heat exchange is an outstanding challenge. A new thematic interpretation of existing state-level geologic maps provides an updated and refined distribution of the composition and age of geologic units for the purposes of assessing the implications for measurement and development of geothermal resources. This interpretation has been developed to better understand geothermal and hydrologic resources of the region. Comparison of the new geologic categories with available hydrologic data shows that younger volcanogenic terrains tend to have higher primary permeability than older terrains. Decrease in primary permeability with age is attributable to weathering and hydrothermal alteration of volcanogenic deposits to pore-filling clays and deposition of secondary deposits (e.g., zeolites). Spring density as a function of geology and precipitation can be used to infer groundwater flow path length within the upper aquifers. Beneath the upper aquifers, we postulate that, due to accelerated hydrothermal alteration at temperatures ~>30 °C, primary permeability at depths of geothermal interest will be limited, and that secondary permeability is a more viable target for hydrothermal fluid withdrawal. Because open fractures resulting from tensile stresses will affect all geologic layers, regions with a significant amount of groundwater flow through shallow, structurally controlled secondary permeability may overlay zones of deep secondary permeability. Regardless of whether the shallow permeability is connected with the deep permeability, shallow groundwater flow can mask the presence of deep hydrothermal flow, resulting in blind geothermal systems. Ideally, hydraulic connectivity between shallow and deep secondary permeability is limited, so that shallow groundwater does not cool potential geothermal reservoirs.

Underground structures increasing the intrinsic vulnerability of urban groundwater: Sensitivity analysis and development of an empirical law based on a groundwater age modelling approach

NASA Astrophysics Data System (ADS)

Attard, Guillaume; Rossier, Yvan; Eisenlohr, Laurent

2017-09-01

In a previous paper published in Journal of Hydrology, it was shown that underground structures are responsible for a mixing process between shallow and deep groundwater that can favour the spreading of urban contamination. In this paper, the impact of underground structures on the intrinsic vulnerability of urban aquifers was investigated. A sensitivity analysis was performed using a 2D deterministic modelling approach based on the reservoir theory generalized to hydrodispersive systems to better understand this mixing phenomenon and the mixing affected zone (MAZ) caused by underground structures. It was shown that the maximal extent of the MAZ caused by an underground structure is reached approximately 20 years after construction. Consequently, underground structures represent a long-term threat for deep aquifer reservoirs. Regarding the construction process, draining operations have a major impact and favour large-scale mixing between shallow and deep groundwater. Consequently, dewatering should be reduced and enclosed as much as possible. The role played by underground structures' dimensions was assessed. The obstruction of the first aquifer layer caused by construction has the greatest influence on the MAZ. The cumulative impact of several underground structures was assessed. It was shown that the total MAZ area increases linearly with underground structures' density. The role played by materials' properties and hydraulic gradient were assessed. Hydraulic conductivity, anisotropy and porosity have the strongest influence on the development of MAZ. Finally, an empirical law was derived to estimate the MAZ caused by an underground structure in a bi-layered aquifer under unconfined conditions. This empirical law, based on the results of the sensitivity analysis developed in this paper, allows for the estimation of MAZ dimensions under known material properties and underground structure dimensions. This empirical law can help urban planners assess the area of influence of underground structures and protect urban strategic reservoirs.

Applicability of 87Sr/86Sr in examining return flow of irrigation water in highly agricultural watersheds in Japan

NASA Astrophysics Data System (ADS)

Yoshida, T.; Nakano, T.; Shin, K. C.; Tsuchihara, T.; Miyazu, S.; Kubota, T.

2017-12-01

Water flows in watersheds containing extensive areas of irrigated paddies are complex because of the substantial volumes involved and the repeated cycles of water diversion from, and return to, streams. For better management of low-flow conditions, numerous studies have attempted to quantify the return flow using the stable isotopes of water; however, the temporal variation in these isotopic compositions due to fractionation during evaporation from water surfaces hinders their application to watersheds with extensive irrigated paddies. In this study, we tested the applicability of the strontium isotopes (87Sr/86Sr, hereafter Sr ratio) for studying hydrological processes in a typical agricultural watershed located on the alluvial fan of the Kinu River, namely the Gogyo River, in central Japan. The Sr ratio of water changes only because of interactions with the porous media it flows through, or because of mixing with water that has different Sr ratios. We sampled water both at a single rice paddy, and on the watershed scale in the irrigated and non-irrigated periods. The soil water under the paddy decreased as sampling depth increased, and the soil water at a depth of 1.5 m showed a similar Sr ratio to the spring. The water sampled in the drainage channel with a concrete lined bottom showed a similar Sr ratio to the irrigation water, whereas that with a soil bottom was plotted between the plots of the irrigation water and shallow aquifer. These results suggest the Sr ratio decreases as it mixes with the soil water through percolation; whereas the Sr ratio will be less likely to change when water drains from paddies via surface pathways. The streamflow samples were plotted linearly on the Sr ratio and 1/Sr plot, indicating that the streamflow was composed of two end-members; the irrigation water and the shallow aquifer. The continuous decline in the Sr ratio along the stream suggests an exfiltration of water from the shallow aquifers. The stream water during the non-irrigated period were lower in Sr ratios and higher in Sr concentrations, suggesting an increase in contributions of the water from the shallow aquifers. Understanding the return flow of irrigation water in highly agricultural watersheds is vital for measuring any temporal changes in flow to the lower parts of the watershed, and allows for improved water management.

Sustainable yields from large diameter wells in shallow weathered aquifers

NASA Astrophysics Data System (ADS)

Rushton, K. R.; de Silva, C. S.

2016-08-01

Large diameter wells in shallow weathered aquifers provide a valuable source of water for domestic and agricultural purposes in many locations including the Indian subcontinent. However, when used for irrigation, these wells often fail towards the end of the dry season. By considering two case studies in the dry and intermediate rainfall zones of Sri Lanka, reasons for the limited yield of these wells are identified. The first case study is concerned with a sloping catchment; a significant proportion of the precipitation during the rainy season either becomes runoff or passes down-gradient through the aquifer and is discharged at the ground surface. Furthermore, during the dry season, groundwater discharge continues. In the second case study the topography is generally flat but, even though the aquifer fills most years during the rainy season, there is often only sufficient water to irrigate about half of each farmer's holding. These investigations are based on field information and the development of conceptual and computational models. Of critical importance in assessing the long term yield of a well is the formation of a seepage face on the side of the well, with the water table a significant distance above the pumping water level. Consequently the water table may only be lowered to about half the depth of the well. The paper concludes with recommendations for the exploitation of groundwater from shallow weathered aquifers to minimise the risk of failure during the dry season.

Geostatistical analysis of effective vertical hydraulic conductivity and presence of confining layers in the Shallow Glacial Drift Aquifer, Oakland County, Michigan

USGS Publications Warehouse

Bissell, E.G.; Aichele, Stephen S.

2004-01-01

About 400,000 residents of Oakland County, Mich., rely on ground water for their primary drinking-water supply. More than 90 percent of these residents draw ground water from the shallow glacial drift aquifer. Understanding the vertical hydraulic conductivity of the shallow glacial drift aquifer is important both in identifying areas of ground-water recharge and in evaluating susceptibility to contamination. The geologic environment throughout much of the county, however, is poorly understood and heterogeneous, making conventional aquifer mapping techniques difficult. Geostatistical procedures are therefore used to describe the effective vertical hydraulic conductivity of the top 50 ft of the glacial deposits and to predict the probability of finding a potentially protective confining layer at a given location. The results presented synthesize the available well-log data; however, only about 40 percent of the explainable variation in the dataset is accounted for, making the results more qualitative than quantitative. Most of the variation in the effective vertical hydraulic conductivity cannot be explained with the well-log data currently available (as of 2004). Although the geologic environment is heterogeneous, the quality-assurance process indicated that more than half of the wells in the county’s Wellkey database (statewide database for monitoring drinking-water wells) had inconsistent identifications of lithology.

Evaluation of effects of groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant, Shelby County, Tennessee

USGS Publications Warehouse

Haugh, Connor J.

2016-08-10

The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects of future groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant in Shelby County, Tennessee. The scenario used in the simulation consisted of a 30-year average withdrawal period followed by a 30-day maximum withdrawal period. Effects of withdrawals at the Allen plant site on the Mississippi embayment aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the 30-year average withdrawal period and at the end of the scenario to a base case without the Allen combined-cycle combustion turbine plant withdrawals. Simulated potentiometric surface declines in the Memphis aquifer at the Allen plant site were about 7 feet at the end of the 30-year average withdrawal period and 11 feet at the end of the scenario. The affected area of the Memphis aquifer at the Allen plant site as delineated by the 4-foot potentiometric surface-decline contour was 2,590 acres at the end of the 30-year average withdrawal period and 11,380 acres at the end of the scenario. Simulated declines in the underlying Fort Pillow aquifer and overlying shallow aquifer were both less than 1 foot at the end of the 30-year average withdrawal period and the end of the scenario.

The distribution of methane in groundwater in Alberta (Canada) and associated aqueous geochemistry conditions

NASA Astrophysics Data System (ADS)

Humez, Pauline; Mayer, Bernhard; Nightingale, Michael; Becker, Veith; Kingston, Andrew; Taylor, Stephen; Millot, Romain; Kloppmann, Wolfram

2016-04-01

Development of unconventional energy resources such as shale gas and coalbed methane has generated some public concern with regard to the protection of groundwater and surface water resources from leakage of stray gas from the deep subsurface. In terms of environmental impact to and risk assessment of shallow groundwater resources, the ultimate challenge is to distinguish: (a) natural in-situ production of biogenic methane, (b) biogenic or thermogenic methane migration into shallow aquifers due to natural causes, and (c) thermogenic methane migration from deep sources due to human activities associated with the exploitation of conventional or unconventional oil and gas resources. We have conducted a NSERC-ANR co-funded baseline study investigating the occurrence of methane in shallow groundwater of Alberta (Canada), a province with a long record of conventional and unconventional hydrocarbon exploration. Our objective was to assess the occurrence and sources of methane in shallow groundwaters and to also characterize the hydrochemical environment in which the methane was formed or transformed through redox processes. Ultimately our aim was to determine whether methane was formed in-situ or whether it migrated from deeper formations into shallow aquifers. Combining hydrochemical and dissolved and free geochemical gas data from 372 groundwater samples obtained from 186 monitoring wells of the provincial groundwater observation well network (GOWN) in Alberta, it was found that methane is ubiquitous in groundwater in Alberta and is predominantly of biogenic origin. The highest concentrations of dissolved biogenic methane (> 0.01 mM or > 0.2 mg/L), characterized by δ13CCH4 values < -55‰, occurred in anoxic Na-Cl, Na-HCO3 and Na-HCO3-Cl type groundwater with negligible concentrations of nitrate and sulfate suggesting that methane was formed in-situ under methanogenic conditions consistent with the redox ladder concept. Despite quite variable gas concentrations and a wide range of δ13CCH4 values in baseline groundwater samples, no conclusive evidence was found for deep thermogenic gas that had migrated in significant amounts into shallow aquifers either naturally or via anthropogenically induced pathways. This study shows that the combined interpretation of aqueous geochemistry data in concert with the chemical and isotopic composition of dissolved and/or free gas can yield unprecedented insights into formation or migration of methane in shallow groundwater. This enables the assessment of cross-formational methane migration and provides an understanding of alkane gas sources and pathways necessary for a stringent baseline definition in the context of current and future unconventional hydrocarbon exploration and exploitation.

Fate and origin of 1,2-dichloropropane in an unconfined shallow aquifer

USGS Publications Warehouse

Tesoriero, A.J.; Loffler, F.E.; Liebscher, H.

2001-01-01

A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.

Assessment of water resources in lead-zinc mined areas in Cherokee County, Kansas, and adjacent areas

USGS Publications Warehouse

Spruill, Timothy B.

1984-01-01

A study was conducted to evaluate water-resources problems related to abandoned lead and zinc mines in Cherokee County, Kansas, and adjacent areas in Missouri and Oklahoma. Past mining activities have caused changes in the hydrogeology of the area. Lead and zinc mining has caused discontinuities and perforations in the confining shale west of the Pennsylvanian-Mississippian geologic contact (referred to as the western area), which have created artificial ground-water recharge and discharge areas. Recharge to the shallow aquifer (rocks of Mississippian age) through collapses, shafts, and drill holes in the shale has caused the formation of a groundwater "mound" in the vicinity of the Picher Field in Kansas and Oklahoma. Discharge of mine-contaminated ground water to Tar Creek occurs in'Oklahoma from drill holes and shafts where the potentiometric surface of the shallow aquifer is above the land surface. Mining of ore in the shallow aquifer has resulted in extensive fracturing and removal of material, which has created highly transmissive zones and voids and increased ground-water storage properties of the aquifer. In the area east of the Pennsylvanian-Mississippian geologic contact (referred to as the eastern area), fractured rock and tailings on the land surface increased the amount of water available for infiltration to the shallow aquifer; in the western area, tailings on the impermeable shale created artificial, perched aquifer systems that slowly drain to surface streams.Pumping of the deep aquifer (rocks of Cambrian and Ordovician age) by towns and industries, which developed as a result of the mining industry, has resulted in a potential for downward movement of water from the shallow aquifer. The potential is greatest in Ottawa County, Oklahoma. Because of the large volume of water that may be transported from the shallow to the deep aquifer, open drill holes or casings present the greatest contamination hazard to water supplies in the deep aquifer.Mining allowed oxidation of ore deposits which, on saturation with water, resulted in poor-quality water that generally contains large concentrations of sulfate and trace metals. Water from mines in the eastern area contained dissolved-solids concentrations of less than 500 mg/L (milligrams per liter), a median pH of 3.9, sulfate concentrations that ranged between 98 and 290 mg/L, and median concentrations for zinc of 37,600 pg/L (micrograms per liter), for lead of 240 pg/L, for cadmium of 180 ug/L, for iron of 70 pg/L, for manganese of 240 pg/L, and for silica of 15 mg/L. Water from mines in the western area contained dissolved-solids concentrations of generally more than 500 mg/L, a median pH of 6.8, sulfate concentrations that ranged between 170 and 2,150 mg/L, and median concentrations for zinc of 3,200 pg/L, for lead of 0 pg/L (minimum detection limit is 10 pg/L), for cadmium of 6 pg/L, for iron of 840 pg/L, for manganese of 440 ug/L, and for silica of 11 mg/L.No conclusive evidence of lateral migration of water from the mines into domestic well-water supplies in the shallow aquifer was found in the study area in Kansas. Analyses of water from public-supply wells tapping the deep aquifer did not indicate contamination with trace metals, although chemical analyses from four of six wells exhibited increasing trends through time in sulfate concentrations. These increases probably reflect localized leakage of water from the shallow aquifer along corroded or leaky well casings.Effects of abandoned lead and zinc mines on tributaries of the Spring River in the eastern area are most severe in Short Creek. Compared with water samples from three other major streams in the eastern area, a sample collected from Short Creek, 2 miles west of Galena, Kansas, during August 1981, contained the largest concentrations of dissolved sulfate (240 mg/L), zinc (25,000 pg/L), cadmium (170 pg/L), manganese (1,700 ug/L), and the lowest pH (6.0). Concentrations of these constituents are due primarily to inflow of ground water from the breccia, mines, and to seepage from chat piles in the Short Creek basin. The largest concentrations of zinc and manganese in the Spring River during August 1981, were observed in analyses of samples collected below Short Creek. In the western area, drainage from tailings, which act as perched aquifers on the impervious Pennsylvanian shales, appeared to have little effect on water quality in Willow Creek during low-flow conditions but caused larger concentrations of dissolved zinc just after a wet period during June 1981. Drainage from tailings cause large concentrations of sulfate, zinc, and cadmium in Tar Creek in Kansas. Compared with four other major streams in the western area in Kansas, Tar Creek contained the largest low-flow concentrations of sulfate (910 mg/L), zinc (5,800 pg/L), and cadmium (40ug/L).

OBSERVATIONS FROM CONTAMINANT PLUMES ON LONG ISLAND

EPA Science Inventory

The aquifers of Long Island serve as a sole source drinking water supply for the entire
local population of about three million people. Where the shallow Upper Glacial Aquifer has been contaminated with petroleum hydrocarbons and methyl tert-butyl ether (MTBE), intensive site ...

Screening for suitable areas for Aquifer Thermal Energy Storage within the Brussels Capital Region, Belgium using coupled groundwater flow and heat transport modelling tools

NASA Astrophysics Data System (ADS)

Anibas, Christian; Kukral, Janik; Touhidul Mustafa, Syed Md; Huysmans, Marijke

2017-04-01

Urban areas have a great potential for shallow geothermal systems. Their energy demand is high, but currently they have only a limited potential to cover their own energy demand. The transition towards a low-carbon energy regime offers alternative sources of energy an increasing potential. Urban areas however pose special challenges for the successful exploitation of shallow geothermal energy. High building densities limit the available space for drillings and underground investigations. Urban heat island effects and underground structures influence the thermal field, groundwater pollution and competing water uses limit the available subsurface. To tackle these challenges in the Brussels Capital Region, Belgium two projects 'BruGeo' and the recently finished 'Prospective Research of Brussels project 2015-PRFB-228' address the investigation in urban geothermal systems. They aim to identify the key factors of the underground with respect to Aquifer Thermal Energy Storage (ATES) installations like thermal properties, aquifer thicknesses, groundwater flow velocities and their heterogeneity. Combined numerical groundwater and heat transport models are applied for the assessment of both open and closed loop shallow geothermal systems. The Brussels Capital Region comprises of the Belgian Capital, the City of Brussels and 18 other municipalities covering 161 km2 with almost 1.2 million inhabitants. Beside the high population density the Brussels Capital Region has a pronounced topography and a relative complex geology. This is both a challenge and an opportunity for the exploitation of shallow geothermal energy. The most important shallow hydrogeological formation in the Brussels-Capital Region are the Brussels Sands with the Brussels Sands Aquifer. Scenarios where developed using criteria for the hydrogeological feasibility of ATES installations such as saturated aquifer thickness, groundwater flow velocity and the groundwater head below surface. The Brussels Sands Formation is covering almost 8000 ha, roughly the half of the Brussels Capital Region. In an optimistic scenario (i.e. all criteria show acceptable or favorable conditions) around 80% of the 8000 ha is suitable for ATES. This is an indication for the considerable potential for ATES installations in the Brussels Capital Region. Results of the research will lead to quantitative spatial output about the potential of shallow geothermal energy use in the Region.

Ground-water quality and geochemistry, Carson Desert, western Nevada

USGS Publications Warehouse

Lico, Michael S.; Seiler, R.L.

1994-01-01

Aquifers in the Carson Desert are the primary source of drinking water, which is highly variable in chemical composition. In the shallow basin-fill aquifers, water chemistyr varies from a dilute calcium bicarbonate-dominated water beneath the irrigated areas to a saline sodium chloride- dominated water beneath unirrigated areas. Water samples from the shallow aquifers commonly have dissolved solids, chloride, magnesium, sulfate, arsenic, and manganese concentrations that exceed State of Nevada drinking-water standards. Water in the intermediante basin-fill aquifers is a dilute sodium bicarbonate type in the Fallon area and a distinctly more saline sodium chloride type in the Soda Lake-Upsal Hogback area. Dissolved solids, chloride, arsenic, fluoride, and manganese concen- trations commonly exceed drinking-water standards. The basalt aquifer contains a dilute sodium bicarbonate chloride water. Arsenic concentrations exceed standards in all sampled wells. The concen- trations of major constituents in ground water beneath the southern Carson Desert are the result of evapotranspiration and natural geochemical reactions with minerals derived mostly from igneous rocks. Water with higher concentrations of iron and manganese is near thermodynamic equilibrium with siderite and rhodochrosite and indicates that these elements may be limited by the solubility of their respective carbonate minerals. Naturally occurring radionuclides (uranium and radon-222) are present in ground water from the Carson Desert in concen- tratons higher than proposed drinking-water standards. High uranium concentrations in the shallow aquifers may be caused by evaporative concentration and the release of uranium during dissolution of iron and manganese oxides or the oxidation of sedimentary organic matter that typically has elevated uranium concentrations. Ground water in the Carson Desert does not appear to have be contaminated by synthetic organic chemicals.

Global Sampling for Integrating Physics-Specific Subsystems and Quantifying Uncertainties of CO 2 Geological Sequestration

DOE PAGES

Sun, Y.; Tong, C.; Trainor-Guitten, W. J.; ...

2012-12-20

The risk of CO 2 leakage from a deep storage reservoir into a shallow aquifer through a fault is assessed and studied using physics-specific computer models. The hypothetical CO 2 geological sequestration system is composed of three subsystems: a deep storage reservoir, a fault in caprock, and a shallow aquifer, which are modeled respectively by considering sub-domain-specific physics. Supercritical CO 2 is injected into the reservoir subsystem with uncertain permeabilities of reservoir, caprock, and aquifer, uncertain fault location, and injection rate (as a decision variable). The simulated pressure and CO 2/brine saturation are connected to the fault-leakage model as amore » boundary condition. CO 2 and brine fluxes from the fault-leakage model at the fault outlet are then imposed in the aquifer model as a source term. Moreover, uncertainties are propagated from the deep reservoir model, to the fault-leakage model, and eventually to the geochemical model in the shallow aquifer, thus contributing to risk profiles. To quantify the uncertainties and assess leakage-relevant risk, we propose a global sampling-based method to allocate sub-dimensions of uncertain parameters to sub-models. The risk profiles are defined and related to CO 2 plume development for pH value and total dissolved solids (TDS) below the EPA's Maximum Contaminant Levels (MCL) for drinking water quality. A global sensitivity analysis is conducted to select the most sensitive parameters to the risk profiles. The resulting uncertainty of pH- and TDS-defined aquifer volume, which is impacted by CO 2 and brine leakage, mainly results from the uncertainty of fault permeability. Subsequently, high-resolution, reduced-order models of risk profiles are developed as functions of all the decision variables and uncertain parameters in all three subsystems.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Y.; Tong, C.; Trainor-Guitten, W. J.

The risk of CO 2 leakage from a deep storage reservoir into a shallow aquifer through a fault is assessed and studied using physics-specific computer models. The hypothetical CO 2 geological sequestration system is composed of three subsystems: a deep storage reservoir, a fault in caprock, and a shallow aquifer, which are modeled respectively by considering sub-domain-specific physics. Supercritical CO 2 is injected into the reservoir subsystem with uncertain permeabilities of reservoir, caprock, and aquifer, uncertain fault location, and injection rate (as a decision variable). The simulated pressure and CO 2/brine saturation are connected to the fault-leakage model as amore » boundary condition. CO 2 and brine fluxes from the fault-leakage model at the fault outlet are then imposed in the aquifer model as a source term. Moreover, uncertainties are propagated from the deep reservoir model, to the fault-leakage model, and eventually to the geochemical model in the shallow aquifer, thus contributing to risk profiles. To quantify the uncertainties and assess leakage-relevant risk, we propose a global sampling-based method to allocate sub-dimensions of uncertain parameters to sub-models. The risk profiles are defined and related to CO 2 plume development for pH value and total dissolved solids (TDS) below the EPA's Maximum Contaminant Levels (MCL) for drinking water quality. A global sensitivity analysis is conducted to select the most sensitive parameters to the risk profiles. The resulting uncertainty of pH- and TDS-defined aquifer volume, which is impacted by CO 2 and brine leakage, mainly results from the uncertainty of fault permeability. Subsequently, high-resolution, reduced-order models of risk profiles are developed as functions of all the decision variables and uncertain parameters in all three subsystems.« less

Strong seepage of shallow groundwater shifts the timing of the annual thermal signals in stream water

NASA Astrophysics Data System (ADS)

Briggs, M. A.; Johnson, Z. C.; Snyder, C.; Hitt, N. P.; White, E. A.; Lane, J. W., Jr.; Nelms, D. L.

2016-12-01

Conventional wisdom indicates that while short-term (e.g. diurnal) thermal variance in streams may be attenuated by groundwater seepage, annual temperature swings will essentially track the local air temperature signal. However, the temperature of shallow (less than 5 m depth) groundwater from seepage zones may not be constant and near the local mean air temperature, but instead will fluctuate seasonally, and show a pronounced phase lag from the annual air signal. The degree of phase lag will be dependent on the rate of vertical fluid and heat exchange through shallow aquifer sediments. Gaining headwater streams might be expected to adopt similar phase lags to local seepage zones. We explore these dynamics through 9 mountain watersheds in Shenandoah National Park, VA, USA that harbor critical habitat for cold-water brook trout (Salvelinus fontinalis). Daily paired air and stream water temperature records were collected for up to 5 years at several stream locations along each watershed. Sinusoids fit to multiple-year data from more than 100 total locations indicate an average phase shift from air to surface water of approximately 10 d; this may primarily be due to strong conductive exchange with the rocky alluvial aquifer in generally incised and shaded channels. A subset of these transects (n=4) showed phase-lags greater than 20 d, coinciding with locations of particularly pronounced diurnal variance attenuation, indicating strong groundwater influence. Shallow bedrock, evaluated throughout the watersheds with passive seismic methods, restricts downward infiltration of precipitation in the mountain bedrock aquifers. Numerical 1D vertical aquifer models indicate similar phase lags in shallow groundwater at the bedrock contact to that observed in stream seepage zones. Therefore, contrary to conventional wisdom, shaded mountain streams with strong groundwater influence may adopt the annual thermal signature of the adjacent aquifer, shifting the stream thermal maxima timing from that predicted by air temperature. This research illustrates the utility of long-term paired air/stream thermal records, which further refine the evaluation of apparent groundwater influence to aquatic habitat.

Hydrogeology, ground-water use, and ground-water levels in the Mill Creek Valley near Evendale, Ohio

USGS Publications Warehouse

Schalk, Charles; Schumann, Thomas

2002-01-01

Withdrawals of ground water in the central Mill Creek Valley near Evendale, Ohio, caused water-level declines of more than 100 feet by the 1950s. Since the 1950s, management practices have changed to reduce the withdrawals of ground water, and recovery of water levels in long-term monitoring wells in the valley has been documented. Changing conditions such as these prompted a survey of water use, streamflow conditions, and water levels in several aquifers in the central Mill Creek Valley, Hamilton and Butler Counties, Ohio. Geohydrologic information, water use, and water levels were compiled from historical records and collected during the regional survey. Data collected during the survey are presented in terms of updated geohydrologic information, water use in the study area, water levels in the aquifers, and interactions between ground water and surface water. Some of the data are concentrated at former Air Force Plant 36 (AFP36), which is collocated with the General Electric Aircraft Engines (GEAE) plant, and these data are used to describe geohydrology and water levels on a more local scale at and near the plant. A comparison of past and current ground-water use and levels indicates that the demand for ground water is decreasing and water levels are rising. Before 1955, most of the major industrial ground-water users had their own wells, ground water was mined from a confined surficial (lower) aquifer, and water levels were more than 100 feet below their predevelopment level. Since 1955, however, these users have been purchasing their water from the city of Cincinnati or a private water purveyor. The cities of Reading and Lockland, both producers of municipal ground-water supplies in the area, shut down their well fields within their city limits. Because the demand for ground-water supplies in the valley has lessened greatly since the 1950s, withdrawals have decreased, and, consequently, water levels in the lower aquifer are 65 to 105 feet higher than they were in 1955. During the time of the water-level survey (November 2000), ground water was being pumped from four locations in the lower aquifer, including three municipalities and one remediation site. Effects of pumping in those four areas were evident from the regional water-level data. Overall, the direction of ground-water flow in the lower aquifer is from northeast to southwest along the primary orientation of the Mill Creek Valley in the study area. Water levels in shallower surficial aquifers were mapped at local scales centered on GEAE. Examination of well logs indicated that these aquifers (called shallow and water-table) are discontinuous and, on a regional scale, few wells were completed in these aquifers. Water levels in the shallow aquifer indicated that flow was from northeast to southwest except in areas where pumping in the lower aquifer or the proximity of Mill Creek may have been affecting water levels in the shallow aquifer. Water levels in the water-table aquifer indicated flow toward Mill Creek from GEAE.

Indicators of the sources and distribution of nitrate in water from shallow domestic wells in agricultural areas of the New Jersey Coastal Plain

USGS Publications Warehouse

Vowinkel, Eric F.; Tapper, Robert J.

1995-01-01

Previously collected and new water-quality data from shallow wells (screened interval less than 30 meters below the land surface) in predominantly agricultural areas of the New Jersey Coastal Plain were used to determine the relation of nitrate concentrations in shallow ground water to various hydrogeologic and land-use factors in the study area. Information on land use, well construction, hydrogeology, and water quality were used to predict the conditions under which concentrations of nitrate as nitrogen in water from domestic wells in predominantly agricultural areas are most likely to be equal to or larger than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 10 milligrams per liter. Results of the analyses of water-quality samples collected during 1980-89 from 230 shallow wells in the outcrop areas of the Kirkwood-Cohansey and Potomac-Raritan-Magothy aquifer systems were used to evaluate the regional effects of land use on shallow-ground-water quality. Results of statistical analysis indicate that concentrations of nitrate in shallow ground water are significantly different (p= 0.001) in agricultural areas than in undeveloped areas in both aquifer systems. Concentrations of nitrate nitrogen exceeded the MCL in water from more than 33 percent of the 60 shallow wells in agricultural areas. Concentrations of hitrate in water from shallow wells in agricultural areas increased as the percentage of agricultural land within an 800-meter-radius buffer zone of the wellhead increased (r= 0.81). Concentrations ofhitrate in water from domestic wells in agricultural areas were similar (p= 0.23) to those concentrations in water from irrigation wells. These results indicate that most of the nitrate in water from domestic wells in agricultural areas results from agricultural practices rather than other sources, such as septic systems. Water-quality samples collected from 12 shallow domestic wells in agricultural areas screened in the outcrop areas of the Kirkwood-Cohansey and Potomac-Raritan-Magothy aquifer systems were used to evaluate the local effects of hydrogeologic conditions and land-use activities on shallow-ground-water quality. Concentrations of water-quality constituents in these wells were similar among four sampling events over a l-year span. The concentration of hitrate in water from 6 of the 12 wells exceeded the MCL. Concentrations of nitrate greater than the MCL are associated with: values of specific conductance greater than 200 microsiemens per centimeter at 25 degrees Celsius, a screened interval whose top is less than 20 meters below land surface, concentrations of dissolved oxygen greater than 6 milligrams per liter, presence of pesticides in the ground water, a distance of less than 250 meters between the wellhead and the surfacewater divide, and presence of livestock near the wellhead. Ratios of stable isotopes of nitrogen in the water samples indicate that the source of hitrate in the ground water was predominantly chemical fertilizers rather than livestock wastes or effluent from septic systems.

MICROBIAL COMMUNITY STRUCTURE IN A SHALLOW HYDROCARBON-CONTAMINATED AQUIFER ASSOCIATED WITH HIGH ELECTRICAL CONDUCTIVITY

EPA Science Inventory

Little is known about the complex interactions between microbial communities and electrical properties in contaminated aquifers. In order to investigate possible connections between these parameters a study was undertaken to investigate the hypothesis that the degradation of hydr...

ENHANCED REMEDIATION DEMONSTRATIONS AT HILL AFB: INTRODUCTION

EPA Science Inventory

Nine enhanced aquifer remediation technologies were demonstrated side-by-side at a Hill Air Force Base Chemical Disposal Pit/Fire Training Area site. The demonstrations were performed inside 3 x 5 m cells isolated from the surrounding shallow aquifer by steel piling. The site w...

Temporal changes in VOC discharge to surface water from a fractured rock aquifer during well installation and operation, Greenville, South Carolina

USGS Publications Warehouse

Vroblesky, D.A.; Robertson, J.F.

1996-01-01

Analysis of the vapor in passive vapor samplers retrieved from a streambed in fractured rock terrain implied that volatile organic carbon (VOC) discharge from ground water to surface water substantially increased following installation of a contaminant recovery well using air rotary drilling. The air rotary technique forced air into the aquifer near the stream. The injection produced an upward hydraulic gradient that appears to have transported water and contaminants from deeper parts of the aquifer through fractures into shallow parts of the aquifer. Once in the shallow flow regime, the contamination was transported to the stream, where it discharged during the next several weeks following well installation. After the recovery well was activated and began continuously pumping contaminated ground water to a treatment facility, the VOC concentrations in the stream bottom passive vapor samplers decreased to below detectable concentrations, suggesting that the withdrawal had captured the contaminated ground water that previously had discharged to the stream.

Interactions between deep bedrock aquifers and surface water in function of recharge and topography: a numerical study

NASA Astrophysics Data System (ADS)

Goderniaux, P.; Davy, P.; Le Borgne, T.; Bresciani, E.; Jimenez-Martinez, J.

2011-12-01

In crystalline rock regions, such as Brittany (France), important reserves of groundwater into deep fractured aquifers are increasingly used and provide high quality water compared to shallow aquifers which can be subject to agricultural contamination. However, recharge processes of these deep aquifers and interactions with surface water are not yet fully understood. In some areas, intensive pumping is carried out without guarantee of the resource quantity and quality. Understanding these processes is crucial for sustainable management of the resource. In this study, we study how deep groundwater fluxes, pathways, ages, and river-aquifer interactions vary according to recharge. We assume that water flowing from the ground surface is distributed between shallow more permeable layers and deep layers. This repartition mostly depends on recharge rates. With high recharge, groundwater levels are high and subsurface streamlines are relatively short between recharge areas and existing draining rivers, which constitutes a very dense network. Therefore, most of the groundwater fluxes occur through the more permeable shallow layers. With low recharge, groundwater levels are lower, and river and shallow permeable levels are partly disconnected from each other. This induces a general increase of the groundwater streamlines length from the recharge areas to more sporadic discharge areas, and more fluxes occur through the deep layers. Recharge conditions and river-aquifer interactions have changed over the last thousands of years, due to change in precipitation, temperatures, existence of permafrost, etc. They have strongly influenced deep groundwater fluxes and can explain current groundwater age and flux distribution. To study these interactions, a regional-scale finite difference flow model was implemented. The model covers an area of 1400 km 2 , a depth of 1 km, and the topography is characteristic of Brittany. As rivers are mainly fed by groundwater drainage, seepages faces are used on the whole modelled area, so that the river network is not prescribed but dependent on simulated groundwater conditions. Different recharge conditions were tested (from 20 to 500 mm/yr). Results show that streamline lengths and groundwater ages have exponential distributions with characteristic lengths increasing with decreasing recharge. The total area of discharge zones decreases with recharge. Groundwater age is quite variable and increases with depth, but the variability is much more important in discharge areas than recharge areas. The proportion of groundwater discharge into the sea (compared to total recharge) increases when total recharge decreases. The model was also used to test the influence of heterogeneity or hydraulic conductivity contrast between shallow and deep layers on deep groundwater fluxes. In a completely homogeneous model, deep fluxes are correlated with recharge fluxes. Correlation decreases while contrast increases. If the permeability of the shallow weather zone is now 3 orders of magnitude larger than of deep aquifer, we observed that simulated deep groundwater fluxes increase locally, despite total recharge at the level of the ground surface decreases.

Overview of environmental and hydrogeologic conditions at Fort Yukon, Alaska

USGS Publications Warehouse

Nakanishi, Allan S.; Dorava, Joseph M.

1994-01-01

The village of Fort Yukon along the Yukon River in east-central Alaska has long cold winters and short summers. The Federal Aviation Administration operates and supports some airport facilities in Fort Yukon and is evaluating the severity of environmental contamination and options for remediation of such contamination at their facilites. Fort Yukon is located on the flood plain of the Yukon River and obtains its drinking water from a shallow aquifer located in the thick alluvium underlying the village. Surface spills and disposal of hazardous materials combined with annual flooding of the Yukon River may affect the quality of the ground water. Alternative drinking-water sources are available from local surface-water bodies or from presently unidentified confined aquifers.

Flushing History as a Hydrogeological Control on the Regional Distribution of Arsenic in Shallow Groundwater of the Bengal Basin

PubMed Central

2008-01-01

Whereas serious health consequences of widespread consumption of groundwater elevated in As have been documented in several South Asian countries, the mechanisms responsible for As mobilization in reducing aquifers remain poorly understood. We document here a previously unrecognized and consistent relationship between dissolved As concentrations in reducing groundwater and the phosphate-mobilizable As content of aquifer sediment for a set of precisely depth-matched samples from across Bangladesh. The relationship holds across nearly 3 orders of magnitude in As concentrations and suggests that regional as well as local patterns of dissolved As in shallow groundwater are set by the solid phase according to a remarkably constant ratio of ∼250 μg/L dissolved As per 1 mg/kg P-mobilizable As. We use this relationship in a simple model of groundwater recharge to propose that the distribution of groundwater As in shallow aquifers of the Bengal Basin could primarily reflect the different flushing histories of sand formations deposited in the region over the past several thousand years. PMID:18504954

Geochemical Characterization of Shallow and Deep Aquifer Mixing in the East Newport Mesa Area, Orange County, CA

NASA Astrophysics Data System (ADS)

Neel, B.; Hagedorn, B.; Xu, X.; Walker, J. C.

2016-12-01

Groundwater flow in the East Newport Mesa has not been extensively studied due to the lack of sufficiently deep production or monitoring wells in the area. In this study, a conceptual hydrogeologic model of the area is developed to characterize lateral and vertical flow patterns between the shallow-most semi-perched, semi-confined aquifer and the underlying regional, potable, confined aquifer. Groundwaters from 12 newly constructed monitoring wells throughout the region, screened at depths ranging from 6.5 to 110 meters below ground surface were sampled and analyzed once for 222Rn, 14C, 13C, 18O, and 2H, and one year quarterly for major ion composition. Additionally, water levels in each well were monitored weekly and adjacent surface waters were analyzed once for 222Rn activity. Geochemical analysis and groundwater level trends were used to test against a model developed based on correlation of downhole logs and known regional geologic structure from basin-wide reports. Major ion analysis revealed endmember groundwaters of NaHCO3, CaHCO3, and NaCl character, and others that fall along endmember mixing lines, while time-series data show that groundwaters in the shallow eastern-most portion of the mesa varied up to 20% in Ca:Na ratio throughout the year. 13C values range from -26.3 to -12.4‰, while 14C age dates range from 485 to 10,280 years before present, and in some cases show an age-inversion, where waters of younger apparent age lie below those of older. Groundwaters sampled throughout the mesa showed 222Rn values ranging from 8 to 1,501 pCi/L. A primary feature of the preliminary conceptual model is the presence of an aquifer mergence zone, i.e., an angular or erosional unconformity in which the intervening aquitard between the two zones is eroded away, thus hydraulically joining the two aquifers. Mixing patterns inferred by major ion data and asymptotic decay of 14C support the existence of a mergence zone and also highlight a potential seasonal intrusion of seawater from the Upper Newport Back Bay into the mesa. This conceptual model will potentially serve as the foundation for a numerical flow model, and related contaminant transport model, with implications for managing and protecting drinking water production wells in the Orange County Groundwater Basin.

Sources of low-arsenic groundwater in the Bengal Basin: investigating the influence of the last glacial maximum palaeosol using a 115-km traverse across Bangladesh

NASA Astrophysics Data System (ADS)

Hoque, M. A.; McArthur, J. M.; Sikdar, P. K.

2014-05-01

Pollution of groundwater in the Bengal Basin (Bangladesh and West Bengal, India) by arsenic (As) puts at risk the health of more than 100 million consumers. Using 1,580 borehole lithological logs and published hydrochemistry on 2,387 wells, it was predicted that low-As (<10 μg/L) groundwater exists, in palaeo-interfluvial aquifers of brown sand capped by a protective palaeosol, beneath at least 45,000 km2 of the Bengal Basin. The aquifers were predicted to be at a depth of as little as 25 m below ground level (mbgl), and typically no more than 50 mbgl. The predictions were confirmed along an east-west traverse 115 km in length (i.e. across half of Bangladesh) by drilling 28 new boreholes to 91-m depth to reveal subsurface sedimentology, and by mapping As distribution in groundwater. The aquifers identified occur at typically <40 mbgl and so are accessible with local drilling methods. A protective palaeosol that caps the palaeo-interfluvial aquifers prevents downward movement into them of As-polluted groundwater present in shallower palaeo-channel aquifers and ensures that the palaeo-interfluvial aquifers will yield low-As groundwater for the foreseeable future. Their use, in place of the shallower As-polluted palaeo-channel aquifers, would rapidly mitigate the health risks from consumption of As-polluted groundwater.

Descriptions and characterizations of water-level data and groundwater flow for the Brewster Boulevard and Castle Hayne Aquifer Systems and the Tarawa Terrace Aquifer

USGS Publications Warehouse

Faye, Robert E.; Jones, L. Elliott; Suárez-Soto, René J.

2013-01-01

This supplement of Chapter A (Supplement 3) summarizes results of analyses of groundwater-level data and describes corresponding elements of groundwater flow such as vertical hydraulic gradients useful for groundwater-flow model calibration. Field data as well as theoretical concepts indicate that potentiometric surfaces within the study area are shown to resemble to a large degree a subdued replica of surface topography. Consequently, precipitation that infiltrates to the water table flows laterally from highland to lowland areas and eventually discharges to streams such as Northeast and Wallace Creeks and New River. Vertically downward hydraulic gradients occur in highland areas resulting in the transfer of groundwater from shallow relatively unconfined aquifers to underlying confined or semi-confined aquifers. Conversely, in the vicinity of large streams such as Wallace and Frenchs Creeks, diffuse upward leakage occurs from underlying confined or semi-confined aquifers. Point water-level data indicating water-table altitudes, water-table altitudes estimated using a regression equation, and estimates of stream levels determined from a digital elevation model (DEM) and topographic maps were used to estimate a predevelopment water-table surface in the study area. Approximate flow lines along hydraulic gradients are shown on a predevelopment potentiometric surface map and extend from highland areas where potentiometric levels are greatest toward streams such as Wallace Creek and Northeast Creek. The distribution of potentiometric levels and corresponding groundwater-flow directions conform closely to related descriptions of the conceptual model.

GROUND-WATER SAMPLING BIAS OBSERVED IN SHALLOW, CONVENTIONAL WELLS

EPA Science Inventory

A previous field demonstration project on nitrate-based bioremediation of a fuel-contaminated aquifer used short-screened clustered well points in addition to shallow (10 foot), conventional monitoring wells to monitor the progress of remediation during surface application of rec...

Understanding wetland sub-surface hydrology using geologic and isotopic signatures

NASA Astrophysics Data System (ADS)

Sikdar, P. K.; Sahu, P.

2009-07-01

This paper attempts to utilize hydrogeology and isotope composition of groundwater to understand the present hydrological processes prevalent in a freshwater wetland, source of wetland groundwater, surface water/groundwater interaction and mixing of groundwater of various depth zones in the aquifer. This study considers East Calcutta Wetlands (ECW) - a freshwater peri-urban inland wetland ecosystem located at the lower part of the deltaic alluvial plain of South Bengal Basin and east of Kolkata city. This wetland is well known over the world for its resource recovery systems, developed by local people through ages, using wastewater of the city. Geological investigations reveal that the sub-surface geology is completely blanketed by the Quaternary sediments comprising a succession of silty clay, sand of various grades and sand mixed with occasional gravels and thin intercalations of silty clay. At few places the top silty clay layer is absent due to scouring action of past channels. In these areas sand is present throughout the geological column and the areas are vulnerable to groundwater pollution. Groundwater mainly flows from east to west and is being over-extracted to the tune of 65×103 m3/day. δ18O and δD values of shallow and deep groundwater are similar indicating resemblance in hydrostratigraphy and climate of the recharge areas. Groundwater originates mainly from monsoonal rain with some evaporation prior to or during infiltration and partly from bottom of ponds, canals and infiltration of groundwater withdrawn for irrigation. Relatively high tritium content of the shallow groundwater indicates local recharge, while the deep groundwater with very low tritium is recharged mainly from distant areas. At places the deep aquifer has relatively high tritium, indicating mixing of groundwater of shallow and deep aquifers. Metals such as copper, lead, arsenic, cadmium, aluminium, nickel and chromium are also present in groundwater of various depths. Therefore, aquifers of wetland and surrounding urban areas which are heavily dependent on groundwater are vulnerable to pollution. In the area south of ECW isotope data indicates no interaction between shallow and deep aquifer and hence this area may be a better location to treat sewage water than within ECW. To reduce the threat of pollution in ECW's aquifer, surface water-groundwater interaction should be minimized by regulating tubewell operation time, introducing treated surface water supply system and artificial recharging of the aquifer.

Regional-Scale Controls on Arsenic Contamination in the Multi-Aquifer System of the Mekong Delta, Vietnam

NASA Astrophysics Data System (ADS)

Erban, L.; Gorelick, S.; Fendorf, S. E.

2014-12-01

Geogenic groundwater arsenic poses a considerable health threat to a large, largely agrarian population in the Mekong Delta, Vietnam. Demand for groundwater continues to rise despite limited information about where arsenic contamination occurs and how it may be affected by excessive pumping. We investigate arsenic measurements from over >40,000 wells found throughout the Delta's seven major exploited aquifers, relating trends in contamination to ancillary physico-chemical datasets. Logistic regression modeling shows that among wells in the most shallow aquifers, arsenic occurrence above the WHO standard (10 µg/L) is best described by a well's distance to 1) the Mekong River network and 2) delta front, its depth and location within fault-bounded areas of the delta. The shallow model is inadequate to capture contaminant occurrence in deeper aquifers (generally 200-500m) where wells are rarely contaminated except in near-river areas undergoing heavy pumping. Our results are the first to quantify how the probability of arsenic contamination varies in 3D throughout the complex aquifer system in relation to both natural and anthropogenically-mediated factors, and suggest that excessive extraction may be degrading the quality of deep aquifers. Findings may serve as a baseline for managing groundwater use for optimal human welfare and assessing any future changes in arsenic occurrence.

Determining shallow aquifer vulnerability by the DRASTIC model and hydrochemistry in granitic terrain, southern India

NASA Astrophysics Data System (ADS)

Mondal, N. C.; Adike, S.; Singh, V. S.; Ahmed, S.; Jayakumar, K. V.

2017-08-01

Shallow aquifer vulnerability has been assessed using GIS-based DRASTIC model by incorporating the major geological and hydrogeological factors that affect and control the groundwater contamination in a granitic terrain. It provides a relative indication of aquifer vulnerability to the contamination. Further, it has been cross-verified with hydrochemical signatures such as total dissolved solids (TDS), Cl-, HCO3-, SO4^{2-} and Cl-/HCO3- molar ratios. The results show four zones of aquifer vulnerability (i.e., negligible, low, moderate and high) based on the variation of DRASTIC Vulnerability Index (DVI) between 39 and 132. About 57% area in the central part is found moderately and highly contaminated due to the 80 functional tannery disposals and is more prone to groundwater aquifer vulnerability. The high range values of TDS (2304-39,100 mg/l); Na+(239- 6,046 mg/l) and Cl- (532-13,652 mg/l) are well correlated with the observed high vulnerable zones. The values of Cl-/HCO3- (molar ratios: 1.4-106.8) in the high vulnerable zone obviously indicate deterioration of the aquifer due to contamination. Further cumulative probability distributions of these parameters indicate several threshold values which are able to demarcate the diverse vulnerability zones in granitic terrain.

Hydrologic, lithologic, and chemical data for sediment in the shallow alluvial aquifer at two sites near Fallon, Churchill County, Nevada, 1984-85

USGS Publications Warehouse

Lico, M.S.; Welch, A.H.; Hughes, J.L.

1986-01-01

The U.S. Geological Survey collected an extensive amount of hydrogeologic data from the shallow alluvial aquifer at two study sites near Fallon, Nevada, from 1984 though 1985. These data were collected as part of a study to determine the geochemical controls on the mobility of arsenic and other trace elements in shallow groundwater systems. The main study area is approximately 7 miles south of Fallon. A subsidiary study area is about 8 miles east of Fallon. The data collected include lithologic logs and water level altitudes for the augered sampling wells and piezometers, and determinations of arsenic and selenium content, grain size, porosity, hydraulic conductivity, and mineralogy for sediment samples from cores. (USGS)

Regional groundwater-flow model of the Lake Michigan Basin in support of Great Lakes Basin water availability and use studies

USGS Publications Warehouse

Feinstein, D.T.; Hunt, R.J.; Reeves, H.W.

2010-01-01

A regional groundwater-flow model of the Lake Michigan Basin and surrounding areas has been developed in support of the Great Lakes Basin Pilot project under the U.S. Geological Survey's National Water Availability and Use Program. The transient 2-million-cell model incorporates multiple aquifers and pumping centers that create water-level drawdown that extends into deep saline waters. The 20-layer model simulates the exchange between a dense surface-water network and heterogeneous glacial deposits overlying stratified bedrock of the Wisconsin/Kankakee Arches and Michigan Basin in the Lower and Upper Peninsulas of Michigan; eastern Wisconsin; northern Indiana; and northeastern Illinois. The model is used to quantify changes in the groundwater system in response to pumping and variations in recharge from 1864 to 2005. Model results quantify the sources of water to major pumping centers, illustrate the dynamics of the groundwater system, and yield measures of water availability useful for water-resources management in the region. This report is a complete description of the methods and datasets used to develop the regional model, the underlying conceptual model, and model inputs, including specified values of material properties and the assignment of external and internal boundary conditions. The report also documents the application of the SEAWAT-2000 program for variable-density flow; it details the approach, advanced methods, and results associated with calibration through nonlinear regression using the PEST program; presents the water-level, drawdown, and groundwater flows for various geographic subregions and aquifer systems; and provides analyses of the effects of pumping from shallow and deep wells on sources of water to wells, the migration of groundwater divides, and direct and indirect groundwater discharge to Lake Michigan. The report considers the role of unconfined conditions at the regional scale as well as the influence of salinity on groundwater flow. Lastly, it describes several categories of limitations and discusses ways of extending the regional model to address issues at the local scale. Results of the simulations portray a regional groundwater-flow system that, over time, has largely maintained its natural predevelopment configuration but that locally has been strongly affected by well withdrawals. The quantity of rainfall in the Lake Michigan Basin and adjacent areas supports a dense surface-water network and recharge rates consistent with generally shallow water tables and predominantly shallow groundwater flow. At the regional scale, pumping has not caused major modifications of the shallow flow system, but it has resulted in decreases in base flow to streams and in direct discharge to Lake Michigan (about 2 percent of the groundwater discharged and about 0.5 cubic foot per second per mile of shoreline). On the other hand, well withdrawals have caused major reversals in regional flow patterns around pumping centers in deep, confined aquifers - most noticeably in the Cambrian-Ordovician aquifer system on the west side of Lake Michigan near the cities of Green Bay and Milwaukee in eastern Wisconsin, and around Chicago in northeastern Illinois, as well as in some shallow bedrock aquifers (for example, in the Marshall aquifer near Lansing, Mich.). The reversals in flow have been accompanied by large drawdowns with consequent local decrease in storage. On the west side of Lake Michigan, groundwater withdrawals have caused appreciable migration of the deep groundwater divides. Before the advent of pumping, the deep Lake Michigan groundwater-basin boundaries extended west of the Lake Michigan surface-water basin boundary, in some places by tens of miles. Over time, the pumping centers have replaced Lake Michigan as the regional sink for the deep flow system. The regional model is intended to support the framework pilot study of water availability and use for the Great Lakes Basin (Reeves, in press).

Hydrochemical evaluation and identification of geochemical processes in the shallow and deep wells in the Ramganga Sub-Basin, India.

PubMed

Rajmohan, Natarajan; Patel, Neelam; Singh, Gaurav; Amarasinghe, Upali A

2017-09-01

Groundwater samples were collected from 44 wells in the Ramganga Sub-Basin (RSB), India, and analysed for major ions, nutrients and trace metals. The primary goal of this study is to evaluate the hydrochemistry and to identify the geochemical processes that govern the water chemistry in the shallow and deep tube wells in the study area using geochemical methods. The knowledge of changes in hydrochemistry of the aquifers is important for both groundwater recharge and use in the region. This study found that there are substantial differences of water chemistry between shallow and deep wells. In the shallow wells, the average concentrations of total dissolved solid (TDS), Na, K, Ca, Mg, HCO 3 , Cl, SO 4 , NO 3 , PO 4 , F, Cu, Mn, Fe and Cr are twofold higher than the deep wells. The concentrations of dissolved silica in the groundwater do not vary with the depth, which implies that the variation in the water chemistry is not due to mineral dissolution alone. Major ion ratios and saturation indices suggest that the water chemistry is predominantly controlled by dissolution of carbonate minerals, silicate weathering and ion exchange reactions. Thermodynamic evaluation (ion activity ratios and stability filed diagrams) indicates that the kaolinite and gibbsite controlled the water chemistry in the both shallow and deep wells. In addition, the groundwater chemistry in the shallow wells is affected by the vertical infiltration of contaminated water from surface contamination sources and nitrification process. In the deep wells, absence of NO 3 and low concentrations of Cl, SO 4 , PO 4 and F imply the role of regional flow and denitrification in the groundwater. Results concluded that proper management plan is necessary to protect the shallow aquifer in the RSB since shallow aquifer pumping is less expensive than the deeper one.

A BENCH SCALE STUDY ON BIODEGRADATION AND VOLATILIZATION OF ETHYLBENZOATE IN AQUIFERS. (R825549C039)

EPA Science Inventory

Experiments were conducted to investigate the fate of ethylbenzoate and soil microorganisms in shallow aquifers. Biodegradation and volatilization have been identified as the major mechanisms in attenuating ethylbenzoate in contaminated soils. The rate of volatilization was ex...

Groundwater quality in the shallow aquifers of the Monterey Bay, Salinas Valley, and adjacent highland areas, Southern Coast Ranges, California

USGS Publications Warehouse

Burton, Carmen

2018-05-30

The Monterey-Salinas Shallow Aquifer study unit covers approximately 7,820 square kilometers (km2) in Santa Cruz, Monterey, and San Luis Obispo Counties in the Central Coast Hydrologic Region of California. The study unit was divided into four study areas—Santa Cruz, Pajaro Valley, Salinas Valley, and Highlands. More than 75 percent of the water used for drinking-water supply in the Central Coast Hydrologic Region of California is groundwater, and there are more than 8,000 well driller’s logs for domestic wells (California Department of Water Resources, 2013).

Groundwater Quality in the Shallow Aquifers of the Monterey Bay, Salinas Valley, and Adjacent Highland Areas, Southern Coast Ranges, California

USGS Publications Warehouse

Burton, Carmen

2018-05-30

The Monterey-Salinas Shallow Aquifer study unit covers approximately 7,820 square kilometers (km2) in Santa Cruz, Monterey, and San Luis Obispo Counties in the Central Coast Hydrologic Region of California. The study unit was divided into four study areas—Santa Cruz, Pajaro Valley, Salinas Valley, and Highlands. More than 75 percent of the water used for drinking-water supply in the Central Coast Hydrologic Region of California is groundwater, and there are more than 8,000 well driller’s logs for domestic wells (California Department of Water Resources, 2013).

Groundwater quality in the shallow aquifers of the Tulare, Kaweah, and Tule Groundwater Basins and adjacent highlands areas, Southern San Joaquin Valley, California

USGS Publications Warehouse

Fram, Miranda S.

2017-01-18

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The shallow aquifers of the Tulare, Kaweah, and Tule groundwater basins and adjacent highlands areas of the southern San Joaquin Valley constitute one of the study units being evaluated.

Bicarbonate Impact on U(VI) Bioreduction in a Shallow Alluvial Aquifer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Long, Philip E.; Williams, Kenneth H.; Davis, James A.

Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al. 2003, Williams et al. 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al. 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggestedmore » the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, that the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ~3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in aquifers.« less

Bicarbonate impact on U(VI) bioreduction in a shallow alluvial aquifer

NASA Astrophysics Data System (ADS)

Long, Philip E.; Williams, Kenneth H.; Davis, James A.; Fox, Patricia M.; Wilkins, Michael J.; Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.; Berman, Elena S. F.; Gupta, Manish; Chandler, Darrell P.; Murray, Chris; Peacock, Aaron D.; Giloteaux, Ludovic; Handley, Kim M.; Lovley, Derek R.; Banfield, Jillian F.

2015-02-01

Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al., 2003; Williams et al., 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al., 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggested the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer sediments desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ∼3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction in the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in aquifers.

Decoupling of As and Fe release to Bangladesh groundwater under reducing conditions. Part I: Evidence from sediment profiles

NASA Astrophysics Data System (ADS)

Horneman, A.; van Geen, A.; Kent, D. V.; Mathe, P. E.; Zheng, Y.; Dhar, R. K.; O'Connell, S.; Hoque, M. A.; Aziz, Z.; Shamsudduha, M.; Seddique, A. A.; Ahmed, K. M.

2004-09-01

This study reexamines the notion that extensive As mobilization in anoxic groundwater of Bangladesh is intimately linked to the dissolution of Fe oxyhydroxides on the basis of analyses performed on a suite of freshly collected samples of aquifer material. Detailed sediment profiles extending to 40 to 70 m depth below the surface were obtained at six sites where local groundwater As concentrations were known to span a wide range. The sediment properties that were measured include (1) the proportion of Fe(II) in the Fe fraction leached in hot 1.2 N HCl, (2) diffuse spectral reflectance, and (3) magnetic susceptibility. In parallel with local concentrations of dissolved As ranging from <5 to 600 μg/L, Fe(II)/Fe ratios in shallow (gray) Holocene sands tended to gradually increase with depth from values of 0.3 to 0.5 to up to 0.9. In deeper (orange) aquifers of presumed Pleistocene age that were separated from shallow sands by a clay layer and contained <5 μg/L dissolved As, leachable Fe(II)/Fe ratios averaged ˜0.2. There was no consistent relation between sediment Fe(II)/Fe and dissolved Fe concentrations in groundwater in nearby wells. The reflectance measurements indicate a systematic linear relation (R 2 of 0.66; n = 151) between the first derivative transform of the reflectance at 520 nm and Fe(II)/Fe. The magnetic susceptibility of the shallow aquifer sands ranged from 200 to 3600 (x 10 -9 m 3/kg SI) and was linearly related (R 2 of 0.75; n = 29) to the concentrations of minerals that could be magnetically separated (0.03 to 0.79% dry weight). No systematic depth trends in magnetic susceptibility were observed within the shallow sands, although the susceptibility of deeper low-As aquifers was low (up to ˜200 × 10 -9 m 3/kg SI). This set of observations, complemented by incubation results described in a companion paper by van Geen et al. (this volume), suggests that the release of As is linked to the transformation of predominantly Fe (III) oxyhydroxide coatings on sand particles to Fe(II) or mixed Fe(II/III) solid phases with a flatter reflectance spectrum such as siderite, vivianite, or magnetite, without necessarily resulting in the release of Fe to groundwater. The very low As/Fe ratio of magnetically separated minerals compared to the As/Fe of bulk acid leachate (2 vs. 40 10 -6, respectively) suggests that such a transformation could be accompanied by a significant redistribution of As to a mobilizable phase on the surface of aquifer particles.

Temporal changes in the configuration of the water table in the vicinity of the management systems evaluation area site, central Nebraska

USGS Publications Warehouse

Kilpatrick, John M.

1996-01-01

To improve understanding of the hydrologic characteristics of the shallow aquifer in the vicinity of the Management Systems Evaluation Area site near Shelton, Nebraska, water levels were measured in approximately 130 observation wells in both June and September 1991. Two water-table maps and a water-level-change map were drawn on the basis of these measurements. In addition, historical data from U.S. Geological Survey computer files and published reports were used to determine the approximate configuration of the water table in 1931 and to draw one short-term and two-long term water- level hydrographs. Comparison of the three water- table maps indicates general similarities. The average horizontal hydraulic gradient in the shallow aquifer is about 7.5 feet per mile, and the flow direction is to the east-northeast. The water table declined 2 to 10 feet between June and September 1991, with the greatest decline occurring in a wedge-shaped area south of the Wood River and north of the Platte River. The 1991 water-table configurations appear to indicate that the aquifer either was discharging to the Platte River in this reach or there was little flow between the river and the aquifer. Comparison of the 1931 and 1991 water-table maps indicates that, except for short-term variations, the water-table configuration changed little during this 61-year period. Two long-term water-level hydrographs confirm this conclusion, indicating that the shallow aquifer in this area has been in long-term, dynamic equilibrium.

An Analysis of the Effect of Surface Heat Exchange on the Thermal Behavior of an Idealized Aquifer Thermal Energy Storage System

NASA Astrophysics Data System (ADS)

Güven, O.; Melville, J. G.; Molz, F. J.

1983-06-01

Analytical expressions are derived for the temperature distribution and the mean temperature of an idealized aquifer thermal energy storage (ATES) system, taking into account the heat exchange at the ground surface and the finite thickness of the overlying layer above the storage aquifer. The analytical expressions for the mean temperature may be used to obtain rough estimates of first-cycle recovery factors for preliminary evaluations of shallow confined or unconfined ATES systems. The results, which are presented in nondimensional plots, indicate that surface heat exchange may have a significant influence on the thermal behavior of shallow ATES systems. Thus it is suggested that the effects of surface heat exchange should be considered carefully and included in the detailed analyses of such ATES systems.

Connecting Soil Water to Groundwater to Streams: Understanding Controls of Nitrate Losses from a Dryland Agricultural Landscape in the Upper Missouri River Watershed

NASA Astrophysics Data System (ADS)

Sigler, W. A.; Ewing, S. A.; Payn, R. A.; Jones, C. A.; Brookshire, J.; Klassen, J. K.; Jackson-Smith, D.; Weissmann, G. S.

2016-12-01

Shallow aquifers impaired by nitrate from agriculture are widespread and remediation or prevention of this problem requires understanding of N leaching rates at a variety of spatial scales. Characterization of the drivers of nitrate leaching at an intermediate scale (103 to 105 ha) is needed to bridge from field scale observations to the landscape-scale context, allowing informed water resource management decisions. Here we explore patterns in nitrate leaching rates across a depositional landform with a predominant land use of non-irrigated small grain production in the Northern Great Plains within the Upper Missouri Basin. The shallow Moccasin terrace (260,000 ha) aquifer is bounded in vertical extent by underlying shale and is isolated from mountain front stream recharge, such that aquifer recharge is dominated by infiltration of precipitation through agricultural soils. We leverage this simplified landform scale water balance to estimate leaching rates using groundwater nitrate concentrations and surface water discharge, and quantify uncertainty using a Monte Carlo approach based on spatial variation in groundwater nitrate concentrations. Landform-scale nitrate-N leaching rates ranged between 10 and 24 kg ha-1 yr-1 during 2012-2014 across two terrace catchments. These rates represent 11 to 27% of fertilizer application rates but are likely derived from a combination of soil organic N mineralization and direct fertilizer loss. While groundwater apparent age is relatively young (0-5 y) based on tritium-helium analysis, whole-aquifer turnover time calculations are an order of magnitude longer (20-23 y), suggesting aquifer heterogeneity and thus a longer potential response time to management changes than suggested by tracer-based aging. We collaborated with local producers to undertake this work, and discussed our results with community members throughout the study. Based on a follow-up survey, producers are now more likely to consider nitrate leaching when making management decisions, suggesting that location-specific producer engagement can facilitate practical solutions to non-point source water quality issues.

Selected hydrologic data from the Cedar Rapids area, Linn County, Iowa, April 1996 through March 1999

USGS Publications Warehouse

Boyd, R.A.; Kuzniar, R.L.; Schulmeyer, P.M.

1999-01-01

The City of Cedar Rapids, Iowa obtains its municipal water supply from four well fields along the Cedar River. The wells are completed at depths of about 60 to 80 feet in a shallow alluvial aquifer adjacent to the Cedar River. The City of Cedar Rapids and the U.S. Geological Survey have conducted a cooperative study of the groundwater flow system and water quality near the well fields since 1992. The purpose of this report is to document selected hydrologic data collected from April 1996 through March 1999. Data include the results of water-quality analyses, ground-waterlevels continuously measured with pressure transducers and data recorders, and physical properties continuously monitored using multiprobe instruments. Water-quality samples were collected from selected wells and the Cedar River to conduct periodic monitoring, to evaluate ground-water geochemistry, to assess the occurrence of pesticides and herbicide degradates in the alluvial aquifer, and to characterize water quality in shallow ground water near a wetland area in the Seminole Well Field. Types of water-quality analyses included common ions (calcium, chloride, iron, magnesium, manganese, potassium, silica, sodium, and sulfate), trace elements (boron, bromide, and fluoride), nutrients (ammonia as nitrogen, nitrite as nitrogen, nitrite plus nitrate as nitrogen, and orthophosphate as phosphorus), dissolved organic carbon, and selected pesticides and herbicide degradates. Ground-water levels in selected observation wells were continuously measured to assess temporal trends in groundwater levels in the alluvial aquifer and bedrock aquifer, to help calibrate a ground-water flow model being constructed to simulate local groundwater flow under transient conditions near the well fields, and to assess hydrologic conditions near a wetland area in the Seminole Well Field. Physical properties (specific conductance, pH, dissolved oxygen, and water temperature) were continuously monitored to assess temporal variation and to help evaluate the interaction between the Cedar River and ground water in the alluvial aquifer.

Characterization of an alluvial aquifer with thermal tracer tomography

NASA Astrophysics Data System (ADS)

Somogyvári, Márk; Bayer, Peter

2017-04-01

In the summer of 2015, a series of thermal tracer tests was performed at the Widen field site in northeast Switzerland. At this site numerous hydraulic, tracer, geophysical and hydrogeophysical field tests have been conducted in the past to investigate a shallow alluvial aquifer. The goals of the campaign in 2015 were to design a cost-effective thermal tracer tomography setup and to validate the concept of travel time-based thermal tracer tomography under field conditions. Thermal tracer tomography uses repeated thermal tracer injections with different injection depths and distributed temperature measurements to map the hydraulic conductivity distribution of a heterogeneous aquifer. The tracer application was designed with minimal experimental time and cost. Water was heated in inflatable swimming pools using direct sunlight of the warm summer days, and it was injected as low temperature pulses in a well. Because of the small amount of injected heat, no long recovery times were required between the repeated heat tracer injections and every test started from natural thermal conditions. At Widen, four thermal tracer tests were performed during a period of three days. Temperatures were measured in one downgradient well using a distributed temperature measurement system installed at seven depth points. Totally 12 temperature breakthrough curves were collected. Travel time based tomographic inversion assumes that thermal transport is dominated by advection and the travel time of the thermal tracer can be related to the hydraulic conductivities of the aquifer. This assumption is valid in many shallow porous aquifers where the groundwater flow is fast. In our application, the travel time problem was treated by a tomographic solver, analogous to seismic tomography, to derive the hydraulic conductivity distribution. At the test site, a two-dimensional cross-well hydraulic conductivity profile was reconstructed with the travel time based inversion. The reconstructed profile corresponds well with the findings of the earlier hydraulic and geophysical experiments at the site.

Modelling an induced thermal plume with data from electrical resistivity tomography and distributed temperature sensing: a case study in northeast Italy

NASA Astrophysics Data System (ADS)

Cultrera, Matteo; Boaga, Jacopo; Di Sipio, Eloisa; Dalla Santa, Giorgia; De Seta, Massimiliano; Galgaro, Antonio

2018-05-01

Groundwater tracer tests are often used to improve aquifer characterization, but they present several disadvantages, such as the need to pour solutions or dyes into the aquifer system and alteration of the water's chemical properties. Thus, tracers can affect the groundwater flow mechanics and data interpretation becomes more complex, hindering effective study of ground heat pumps for low enthalpy geothermal systems. This paper presents a preliminary methodology based on a multidisciplinary application of heat as a tracer for defining the main parameters of shallow aquifers. The field monitoring techniques electrical resistivity tomography (ERT) and distributed temperature sensing (DTS) are noninvasive and were applied to a shallow-aquifer test site in northeast Italy. The combination of these measurement techniques supports the definition of the main aquifer parameters and therefore the construction of a reliable conceptual model, which is then described through the numerical code FEFLOW. This model is calibrated with DTS and validated by ERT outcomes. The reliability of the numerical model in terms of fate and transport is thereby enhanced, leading to the potential for better environmental management and protection of groundwater resources through more cost-effective solutions.

Hydrogeochemical alteration of groundwater due to a CO2 injection test into a shallow aquifer in Northeast Germany

NASA Astrophysics Data System (ADS)

Dethlefsen, Frank; Peter, Anita; Hornbruch, Götz; Lamert, Hendrik; Garbe-Schönberg, Dieter; Beyer, Matthias; Dietrich, Peter; Dahmke, Andreas

2014-05-01

The accidental release of CO2 into potable aquifers, for instance as a consequence of a leakage out of a CO2 store site, can endanger drinking water resources due to the induced geochemical processes. A 10-day CO2 injection experiment into a shallow aquifer was carried out in Wittstock (Northeast Germany) in order to investigate the geochemical impact of a CO2 influx into such an aquifer and to test different monitoring methods. Information regarding the site investigation, the injection procedure monitoring setup, and first geochemical monitoring results are described in [1]. Apart from the utilization of the test results to evaluate monitoring approaches [2], further findings are presented on the evaluation of the geophysical monitoring [3], and the monitoring of stable carbon isotopes [4]. This part of the study focuses of the hydrogeochemical alteration of groundwater due to the CO2 injection test. As a consequence of the CO2 injection, major cations were released, i.e. concentrations increased, whereas major anion concentrations - beside bicarbonate - decreased, probably due to increased anion sorption capacity at variably charged exchange sites of minerals. Trace element concentrations increased as well significantly, whereas the relative concentration increase was far larger than the relative concentration increase of major cations. Furthermore, geochemical reactions show significant spatial heterogeneity, i.e. some elements such as Cr, Cu, Pb either increased in concentration or remained at stable concentrations with increasing TIC at different wells. Statistical analyses of regression coefficients confirm the different spatial reaction patterns at different wells. Concentration time series at single wells give evidence, that the trace element release is pH dependent, i.e. trace elements such as Zn, Ni, Co are released at pH of around 6.2-6.6, whereas other trace elements like As, Cd, Cu are released at pH of 5.6-6.4. [1] Peter, A., et al., Investigation of the geochemical impact of CO2; on shallow groundwater: design and implementation of a CO2; injection test in Northeast Germany. Environmental Earth Sciences, 2012. 67(2): p. 335-349. [2] Dethlefsen, F., et al., Monitoring approaches for detecting and evaluating CO2 and formation water leakages into near-surface aquifers. Energy Procedia, 2013. 37(0): p. 4886-4893. [3] Lamert, H., et al., Feasibility of geoelectrical monitoring and multiphase modeling for process understanding of gaseous CO2; injection into a shallow aquifer. Environmental Earth Sciences, 2012. 67(2): p. 447-462. [4] Schulz, A., et al., Monitoring of a simulated CO2 leakage in a shallow aquifer using stable carbon isotopes. Environmental Science & Technology, 2012. 46(20): p. 11243-11250.

An overview of nitrate sources and operating processes in arid and semiarid aquifer systems.

PubMed

Gutiérrez, Mélida; Biagioni, Richard N; Alarcón-Herrera, Maria Teresa; Rivas-Lucero, Bertha A

2018-05-15

Nitrate concentration in most aquifers in arid and semi-arid areas has increased in the past several decades as a result of human activities. Under the predominantly oxic conditions of these aquifers, denitrification is inhibited, allowing nitrate, a soluble and stable form of nitrogen (N), to accumulate. Because of its close association with municipal and agricultural wastes, nitrate is commonly used as an indicator of anthropogenic contamination. Aquifers affected by agricultural waste may contain salts from irrigation returns and herbicides in addition to nitrates. Preventing leakage from soil to deeper parts of the aquifer is thus a priority in the sustainable management of aquifers in arid and semiarid areas. Studies report a wide range of nitrate concentrations distributed non-uniformly within the aquifer, with roughly 40% and 20% of sampled wells exceeding 50mg/L nitrate in shallow and deep parts of the aquifer respectively. In aquifers at risk of becoming contaminated, nitrate isotopes (δ 15 N, δ 18 O, Δ 17 O) can be used to identify the source of nitrogen as mineral or organic fertilizer, sewage, or atmospheric deposition. A variety of mathematical models (crop, hydrological, geochemical, or a combination of them) have been successful in identifying best practices that minimize N leakage without negatively affecting crop yield. In addition, field research in crop management, e.g., conservation agriculture, has yielded promising results in determining the adequate dosage and time of application of fertilizers to reduce N losses. Examples of key dryland aquifers impacted by nitrate are discussed, and some of the most pressing challenges to achieve sustainability are presented. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of organic contamination in urban groundwater surrounding a municipal landfill, Zhoukou, China.

PubMed

Han, D M; Tong, X X; Jin, M G; Hepburn, Emily; Tong, C S; Song, X F

2013-04-01

This paper investigates the organic pollution status of shallow aquifer sediments and groundwater around Zhoukou landfill. Chlorinated aliphatic hydrocarbons, monocylic aromatic hydrocarbons, halogenated aromatic hydrocarbons, organochlorine pesticides and other pesticides, and polycyclic aromatic hydrocarbons (PAHs) have been detected in some water samples. Among the detected eleven PAHs, phenanthrene, fluorine, and fluoranthene are the three dominant in most of the groundwater samples. Analysis of groundwater samples around the landfill revealed concentrations of PAHs ranging from not detected to 2.19 μg/L. The results show that sediments below the waste dump were low in pollution, and the shallow aquifer, at a depth of 18-30 m, was heavily contaminated, particularly during the wet season. An oval-shaped pollution halo has formed, spanning 3 km from west to east and 2 km from south to north, and mainly occurs in groundwater depths of 2-4 m. For PAH source identification, both diagnostic ratios of selected PAHs and principal component analysis were studied, suggesting mixed sources of pyro- and petrogenic derived PAHs in the Zhoukou landfill. Groundwater table fluctuations play an important role in the distribution of organic pollutants within the shallow aquifer. A conceptual model of leachate migration in the Quaternary aquifers surrounding the Zhoukou landfill has been developed to describe the contamination processes based on the major contaminant (PAHs). The groundwater zone contaminated by leachate has been identified surrounding the landfill.

Stewardship of water and fertilizer in irrigated cotton

USDA-ARS?s Scientific Manuscript database

Agriculture is a vital part of the southeast Missouri economy and it is essential that we maintain our precious soil and water resources. While we have shallow, high quality groundwater for irrigation, it is important to realize that our aquifer, the Mississippi River Valley Alluvial Aquifer, also p...

TRANSPORT OF INORGANIC COLLOIDS THROUGH NATURAL AQUIFER MATERIAL: IMPLICATIONS FOR CONTAMINANT TRANSPORT

EPA Science Inventory

The stability and transport of radiolabeled Fe₂O₃ particles were studied using laboratory batch and column techniques. Core material collected from a shallow sand and gravel aquifer was used as the immobile column matrix material. Variables in the study incl...

MOLECULAR ANALYSIS OF MICROBIAL COMMUNITY STRUCTURES IN PRISTINE AND CONTAMINATED AQUIFERS: FIELD AND LABORATORY MICROCOSM EXPERIMENTS

EPA Science Inventory

This study used phylogenetic probes in hybridization analysis to (i) determine in situ microbial community structures in regions of a shallow sand aquifer that were oxygen depleted and fuel contaminated (FC) or aerobic and noncontaminted (NC) and (ii) examine alterations in micro...

Hydrologic connections and dynamics of water movement in the classical Karst (Kras) Aquifer: evidence from frequent chemical and stable isotope sampling

USGS Publications Warehouse

Doctor, Daniel H.

2008-01-01

A review of past research on the hydrogeology of the Classical Karst (Kras) region and new information obtained from a two- year study using environmental tracers are presented in this paper. The main problems addressed are 1) the sources of water to the Kras aquifer resurgence zone-including the famous Timavo springs-under changing flow regimes; 2) a quantification of the storage volumes of the karst massif corresponding to flow regimes defined by hydrograph recessions of the Timavo springs; and 3) changing dynamics between deep phreatic conduit flow and shallow phreatic and epiphreatic storage within the aquifer resurgence zone as determined through changes in chemical and isotopic composition at springs and wells. Particular focus was placed on addressing the long-standing question of the influence of the Soca River on the ground waters of the aquifer resurgence zone. The results indicate that the alluvial aquifer supplied by the sinking of the Soca River on the northwestern edge of the massif contributes approximately 75% of the mean annual outflow to the smaller springs of the aquifer resurgence zone, and as much as 53% to the mean annual outflow of the Timavo springs. As a whole, the Soca River is estimated to contribute 56% of the average outflow of the Kras aquifer resurgence. The proportions of Soca River water increase under drier conditions, and decrease under wetter conditions. Time series analysis of oxygen stable isotope records indicate that the transit time of Soca River water to the Timavo springs, Sardos spring, and well B-4 is on the order of 1-2 months, depending on hydrological conditions. The total baseflow storage of the Timavo springs is estimated to be 518 million m3, and represents 88.5% of the storage capacity estimated for all flow regimes of the springs. The ratio of baseflow storage volume to the average annual volume discharged at the Timavo springs is 0.54. The Reka River sinking in Slovenia supplies substantial allogenic recharge to the aquifer; however, its influence on the northwest resurgence zone is limited to the Timavo springs, and is only a significant component of the spring discharge under flood conditions for relatively brief periods (several days to weeks). Sustainability of the trans-boundary aquifer of the Kras will benefit from maintaining high water quality in the Soca River, as well as focused water tracing experiments within the epiphreatic zone of the aquifer to better delineate the recharge zone and to identify sources of potential contamination to the Brestovica water supply well.

Reversible adsorption and flushing of arsenic in a shallow, Holocene aquifer of Bangladesh

PubMed Central

Radloff, Kathleen A.; Zheng, Yan; Stute, Martin; Weinman, Beth; Bostick, Benjamin; Mihajlov, Ivan; Bounds, Margaret; Rahman, M. Moshiur; Huq, M. Rezaul; Ahmed, Kazi M.; Schlosser, Peter; van Geen, Alexander

2015-01-01

The spatial heterogeneity of dissolved arsenic (As) concentrations in shallow groundwater of the Bengal Basin has been attributed to transport of As (and reactive carbon) from external sources or to the release of As from within grey sand formations. We explore the latter scenario in this detailed hydrological and geochemical study along a 300 m transect of a shallow aquifer extending from a groundwater recharge area within a sandy channel bar to its discharge into a nearby stream. Within the 10–20 m depth range, groundwater ages along the transect determined by the 3H–3He method increase from <10 yr in the recharge area to a maximum of 40 yr towards the stream. Concentrations of groundwater As within the same grey sands increase from 10 to 100 to ∼500 µg/L along this transect. Evidence of reversible adsorption of As between the groundwater and sediment was obtained from a series of push–pull experiments, traditional batch adsorption experiments, and the accidental flooding of a shallow monitoring well. Assuming reversible adsorption and a distribution coefficient, Kd, of 0.15–1.5 L/kg inferred from these observations, a simple flushing model shows that the increase in As concentrations with depth and groundwater age at this site, and at other sites in the Bengal and Red River Basins, can be attributed to the evolution of the aquifer over 100–1000 years as aquifer sands are gradually flushed of their initial As content. A wide range of As concentrations can thus be maintained in groundwater with increases with depth governed by the history of flushing and local recharge rates, without external inputs of reactive carbon or As from other sources. PMID:28458447

Suspended sediment in selected streams of southeastern Montana

USGS Publications Warehouse

Litke, D.W.

1982-01-01

The relatively flat Badger Road area near Fairbanks occupies part of the alluvial plain of the Chena and Tanana Rivers and is underlain by scattered areas of permafrost. The water table of the high-transmissivity aquifer that underlies the area is generally shallower than 15 feet, fluctuates seasonally about 2 feet, and slopes northwesterly, the direction of ground-water flow. Private domestic-supply wells obtain water from the upper part of the aquifer. Septic systems used to dispose of waste water are installed at or only slightly above the water table in the same aquifer. Analyses of samples from 16 observation wells in undeveloped parts of the study area and from 33 domestic wells indicated that water quality has not been significantly degraded by on-site waste disposal. Three samples had detectable but minor contamination by fecal coliform bacteria. Anomalous values of chloride and ammonia in one third of the domestic wells may indicate incipient degradation of ground-water quality by septic-tank effluent. (USGS)

High-resolution seismic reflection profiling for mapping shallow aquifers in Lee County, Florida

USGS Publications Warehouse

Missimer, T.M.; Gardner, Richard Alfred

1976-01-01

High-resolution continuous seismic reflection profiling equipment was utilized to define the configuration of sedimentary layers underlying part of Lee County, Florida. About 45 miles (72 kilometers) of profile were made on the Caloosahatchee River Estuary and San Carlos Bay. Two different acoustic energy sources, a high resolution boomer and a 45-electrode high resolution sparker, both having a power input of 300 joules, were used to obtain both adequate penetration and good resolution. The seismic profiles show that much of the strata of middle Miocene to Holocene age apparently are extensively folded but not faulted. Initial interpretations indicate that: (1) the top of the Hawthorn Formation (which contains the upper Hawthorn aquifer) has much relief due chiefly to apparent folding; (2) the limestone, sandstone, and unconsolidated sand and phosphorite, which together compose the sandstone aquifer, appear to be discontinuous; (3) the green clay unit of the Tamiami Formation contains large scale angular beds dipping eastward; and (4) numerous deeply cut alluvium-filled paleochannels underlie the Caloosahatchee River. (Woodard-USGS)

Quality of ground water in the Biscayne Aquifer in Miami-Dade, Broward, and Palm Beach counties, Florida, 1996-1998, with emphasis on contaminants

USGS Publications Warehouse

Bradner, Anne; McPherson, Benjamin F.; Miller, Ronald L.; Kish, George; Bernard, Bruce

2005-01-01

The high permeability of the sand and limestone sediments and shallow water table of the Biscayne aquifer make ground water vulnerable to contamination by human activities. To assess potential contamination in the aquifer, untreated ground water was sampled from 30 public-supply wells (40-165 feet deep) in Broward, Miami-Dade, and Palm Beach Counties, 32 shallow wells (10-50 feet deep) in a recently urbanized (residential and light commercial) part of Broward County, and 3 shallow reference wells in Broward County. Results from sample analyses indicate that major ions, pH, dissolved oxygen, nutrients, and trace element concentrations were generally within the range indicative of background concentrations, except for: (1) substantially higher bromide concentrations in water from public-supply wells in southern Miami-Dade County; (2) a few relatively high (greater than 2 milligrams per liter) concentrations of nitrate in water from public-supply wells near agricultural lands in Miami-Dade and southern Broward Counties; and (3) a few relatively high concentrations of arsenic (greater than 10 micrograms per liter) in water from some shallow urban wells near golf courses. Pesticides were detected in every public-supply well, in most of the shallow, urban monitoring wells (78 percent), and in one reference well; however, no pesticide concentration exceeded any drinking-water standard. Fifteen different pesticides or their degradation products were detected. The most frequently detected pesticides were atrazine and tebuthiuron; less frequently detected were the herbicides diuron, fenuron, prometon, metolachlor, simazine, and 2,6-diethylaniline. Volatile organic compounds (VOCs) were detected in most of the public-supply wells (77 percent) and shallow, urban wells (91 percent) and in two of the three reference wells. Thirty-two different VOCs were detected in ground water in the Biscayne aquifer, with cis-1,2-dichloroethene the most frequently detected VOC in the public-supply wells, followed by methyl tert-butyl ether (MTBE), 1,4-dichlorobenzene, and chloroform. Toluene, p-isopropyltoluene, and 1,2,4-trimethylbenzene were the most frequently detected VOCs in the shallow, urban wells. Concentrations of all VOCs were less than the maximum contaminant level (MCL) for public drinking water, except in two samples from public-supply wells near industrialized areas that had vinyl chloride concentrations (3 and 5 micrograms per liter) above the MCL of 1 microgram per liter.

Geohydrology of the cross-Florida barge canal area, with special reference to the Ocala vicinity

USGS Publications Warehouse

Faulkner, Glen L.

1973-01-01

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene age and younger, which overlies limestone of the Floridan aquifer. Westward from Ocala, most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with the limited exchange of water between the pools and the aquifers. The water levels in the Summit Pools will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be controlled partly by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Summit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene Miocene age, including from older to younger, the Lake City, Avon Park, and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, in thickness from a few feet to 300 feet. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate western limit of a continuous blanket of materials of Miocene-Pliocene(?) age covering the rocks of the Floridan aquifer. East of the line, much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley, direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remain. Lack of the cover is a result of erosion on the crest and flank of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Floridan aquifer. The fractures and faults are important controls for orientation of solution channels and, therefore, for development of ground-water circulation patterns. When the system surface streams, which once drained the Barge Canal area, eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal streams remain, such as the Oklawaha and Withlacoochee Rivers and a few short tributaries, while one of the most highly developed subsurface drainage systems in the world has evolved in cavernous limestone of the Floridan aquifer. Two of the larger freshwater springs in the world now

Geohydrology of the Cross-Florida Barge Canal area, with special reference to the Ocala vicinity

USGS Publications Warehouse

Faulkner, Glen L.

1970-01-01

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene and younger age, which overlies limestone of the Floridan aquifer. Westward from Ocala most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with limited exchange of water between the pools and the aquifers. The water levels in the Summit Pool will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be partially controlled by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Sun, nit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene to Miocene age, including, from older to younger the Lake City, Avon Park and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar Limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, ranging from a few feet to two or three hundred feet thick. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate westward limit of a continuous blanket of Miocene-Pliocene(?) age materials covering the rocks of the Floridan aquifer. East of the line much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remains. Lack of the cover is a result of erosion on the crest and flanks of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined, and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Florida Aquifer. The fractures and faults are important controls for orientation of solution channels, and, therefore, for development of ground-water circulation patterns. When the system of surface streams which once drained the Barge Canal area eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal rivers, such as the Oklawaha and Withlacoochee Rivers, and a few short tributaries remain, while one of the most highly developed subsurface drainage systems in the world has evolved in the cavernous limestones of the Floridan aquifer. Two of the larger fresh water spr

The Virginia Coastal Plain Hydrogeologic Framework

USGS Publications Warehouse

McFarland, Randolph E.; Scott, Bruce T.

2006-01-01

A refined descriptive hydrogeologic framework of the Coastal Plain of eastern Virginia provides a new perspective on the regional ground-water system by incorporating recent understanding gained by discovery of the Chesapeake Bay impact crater and determination of other geological relations. The seaward-thickening wedge of extensive, eastward-dipping strata of largely unconsolidated sediments is classified into a series of 19 hydrogeologic units, based on interpretations of geophysical logs and allied descriptions and analyses from a regional network of 403 boreholes. Potomac aquifer sediments of Early Cretaceous age form the primary ground-water supply resource. The Potomac aquifer is designated as a single aquifer because the fine-grained interbeds, which are spatially highly variable and inherently discontinuous, are not sufficiently dense across a continuous expanse to act as regional barriers to ground-water flow. Part of the Potomac aquifer in the outer part of the Chesapeake Bay impact crater consists of megablock beds, which are relatively undeformed internally but are bounded by widely separated faults. The Potomac aquifer is entirely truncated across the inner part of the crater. The Potomac confining zone approximates a transition from the Potomac aquifer to overlying hydrogeologic units. New or revised designations of sediments of Late Cretaceous age that are present only south of the James River include the upper Cenomanian confining unit, the Virginia Beach aquifer and confining zone, and the Peedee aquifer and confining zone. The Virginia Beach aquifer is a locally important ground-water supply resource. Sediments of late Paleocene to early Eocene age that compose the Aquia aquifer and overlying Nanjemoy-Marlboro confining unit are truncated along the margin of the Chesapeake Bay impact crater. Sediments of late Eocene age compose three newly designated confining units within the crater, which are from bottom to top, the impact-generated Exmore clast and Exmore matrix confining units, and the Chickahominy confining unit. Piney Point aquifer sediments of early Eocene to middle Miocene age overlie most of the Chesapeake Bay impact crater and beyond, but are a locally significant ground-water supply resource only outside of the crater across the middle reaches of the Northern Neck, Middle, and York-James Peninsulas. Sediments of middle Miocene to late Miocene age that compose the Calvert confining unit and overlying Saint Marys confining unit effectively separate the underlying Piney Point aquifer and deeper aquifers from overlying shallow aquifers. Saint Marys aquifer sediments of late Miocene age separate the Calvert and Saint Marys confining units across two limited areas only. Sediments of the Yorktown-Eastover aquifer of late Miocene to late Pliocene age form the second most heavily used ground-water supply resource. The Yorktown confining zone approximates a transition to the overlying late Pliocene to Holocene sediments of the surficial aquifer, which extends across the entire land surface in the Virginia Coastal Plain and is a moderately used supply. The Yorktown-Eastover aquifer and the eastern part of the surficial aquifer are closely associated across complex and extensive hydraulic connections and jointly compose a shallow, generally semiconfined ground-water system that is hydraulically separated from the deeper system. Vertical faults extend from the basement upward through most of the hydrogeologic units but may be more widespread and ubiquitous than recognized herein, because areas of sparse boreholes do not provide adequate spatial control. Hydraulic conductivity probably is decreased locally by disruption of depositional intergranular structure by fault movement in the generally incompetent sediments. Localized fluid flow in open fractures may be unique in the Chickahominy confining unit. Some hydrogeologic units are partly to wholly truncated where displacements are large rela

Numerical modeling of experimental observations on gas formation and multi-phase flow of carbon dioxide in subsurface formations

NASA Astrophysics Data System (ADS)

Pawar, R.; Dash, Z.; Sakaki, T.; Plampin, M. R.; Lassen, R. N.; Illangasekare, T. H.; Zyvoloski, G.

2011-12-01

One of the concerns related to geologic CO2 sequestration is potential leakage of CO2 and its subsequent migration to shallow groundwater resources leading to geochemical impacts. Developing approaches to monitor CO2 migration in shallow aquifer and mitigate leakage impacts will require improving our understanding of gas phase formation and multi-phase flow subsequent to CO2 leakage in shallow aquifers. We are utilizing an integrated approach combining laboratory experiments and numerical simulations to characterize the multi-phase flow of CO2 in shallow aquifers. The laboratory experiments involve a series of highly controlled experiments in which CO2 dissolved water is injected in homogeneous and heterogeneous soil columns and tanks. The experimental results are used to study the effects of soil properties, temperature, pressure gradients and heterogeneities on gas formation and migration. We utilize the Finite Element Heat and Mass (FEHM) simulator (Zyvoloski et al, 2010) to numerically model the experimental results. The numerical models capture the physics of CO2 exsolution, multi-phase fluid flow as well as sand heterogeneity. Experimental observations of pressure, temperature and gas saturations are used to develop and constrain conceptual models for CO2 gas-phase formation and multi-phase CO2 flow in porous media. This talk will provide details of development of conceptual models based on experimental observation, development of numerical models for laboratory experiments and modelling results.

Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

NASA Astrophysics Data System (ADS)

Toth, David J.; Katz, Brian G.

2006-06-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.

Impact of diffuse nitrate pollution sources on groundwater quality--some examples from Czechoslovakia.

PubMed Central

Benes, V; Pĕkný, V; Skorepa, J; Vrba, J

1989-01-01

In several regions of Czechoslovakia with intensive agricultural production, the correlation between the amount of nitrogen fertilizer applied and the nitrate content in groundwater has been recognized. Nitrate pollution of groundwater is considered to be the most serious source of nonpoint pollution in Czechoslovakia. A program of research into the effects of farming activities on groundwater quality in Czechoslovakia is under way on experimental fields (20 to 30 hectares) and, simultaneously, in regions in which shallow, vulnerable aquifers occur. The importance of the soil organic matter's stability for maintaining the groundwater quality is emphasized. Research based on nitrogen and organic carbon balance has shown that the restoration of a soil-groundwater system is a complicated process that usually requires changes in the extent and intensity of agricultural activities and consistent attention to the effects produced by natural conditions. Regional investigation of the impact of farming on shallow aquifers in the fluvial deposits of the Elbe River in Bohemia has proved the hydrochemical instability and vertical hydrochemical heterogeneity of these aquifers. The WASTEN deterministic model was used for modeling the transport and transformation of various types of inorganic fertilizers. The input data is based on laboratory and field measurements. Special topics are the verification of model calculations and the time and spatial variability of input data with respect to the unsaturated zone. The research results are being used for making regional and national agro-groundwater managerial schemes more precise, as well as for decision-making. PMID:2559844

Farm water budgets for semiarid irrigated floodplains of northern New Mexico: characterizing the surface water-groundwater interactions

NASA Astrophysics Data System (ADS)

Gutierrez, K. Y.; Fernald, A.; Ochoa, C. G.; Guldan, S. J.

2013-12-01

KEY WORDS - Hydrology, Water budget, Deep percolation, Surface water-Groundwater interactions. With the recent projections for water scarcity, water balances have become an indispensable water management tool. In irrigated floodplains, deep percolation from irrigation can represent one of the main aquifer recharge sources. A better understanding of surface water and groundwater interactions in irrigated valleys is needed for properly assessing the water balances in these systems and estimating potential aquifer recharge. We conducted a study to quantify the parameters and calculate the water budgets in three flood irrigated hay fields with relatively low, intermediate and, high water availability in northern New Mexico. We monitored different hydrologic parameters including total amount of water applied, change in soil moisture, drainage below the effective root zone, and shallow water level fluctuations in response to irrigation. Evapotranspiration was calculated from weather station data collected in-situ using the Samani-Hargreaves. Previous studies in the region have estimated deep percolation as a residual parameter of the water balance equation. In this study, we used both, the water balance method and actual measurements of deep percolation using passive lysimeters. Preliminary analyses for the three fields show a relatively rapid movement of water through the upper 50 cm of the vadose zone and a quick response of the shallow aquifer under flood irrigation. Further results from this study will provide a better understanding of surface water-groundwater interactions in flood irrigated valleys in northern New Mexico.

Shallow geothermal investigations into the existence of the Valles Caldera outflow plume near Ponderosa and Jemez Pueblo, north-central, New Mexico

NASA Astrophysics Data System (ADS)

Salaz, Robert Ezekiel

Geothermal research within the Jemez Mountains spans several decades and is documented in many papers. This study serves to extend the research boundary to the south and east outside of Valles caldera and Canon de San Diego, where the main occurrences of geothermal activity are located. The focus of this investigation is to test for a deep ~900 m, stratigraphically-bound thermal aquifer within the Madera Limestone along the western margin of the Santo Domingo basin transition zone near Ponderosa and Jemez Pueblo, in north-central New Mexico. Numerous springs were sampled for aqueous geochemistry to identify leakage of a deeper geothermal aquifer into shallow aquifers. Wells were sampled for temperature anomalies. In addition, two travertine deposits were analyzed for stable isotope composition and one deposit was dated using U-Series techniques to assess the timing and origin of deposition. This study is important because researchers in other extensional basins have identified reasonably good geothermal reservoirs in deep carbonate aquifers that are similar in geologic setting to the Madera Limestone aquifer of this study. The existence of a deep geothermal aquifer near Ponderosa and Jemez Pueblo, New Mexico could prove to be another prospect for geothermal exploration in the Jemez Mountains. Aqueous geochemistry of springs are plotted on ternary Piper diagrams to help classify similar geochemical trends and group these trends into recognizable patterns. These data indicate calcium carbonate rich waters in the north that may gradationally change to alkaline type waters as they flow south through the study area. Contrasting this data, SiO2 and TDS concentrations show two separate systems that may indicate separate confined aquifers. Two distinct TDS regions are observed, one with higher concentrations (>1000 ppm) shows a decrease from N-S and one with lower concentrations (<600 ppm) shows an increase from N-S. The data indicate that the waters can be classified as shallow meteoric waters within the Jemez Mountains. The geochemical complexity of the data point towards separate systems with distinct geochemical characteristics, i.e. confined aquifers, but the complexity and sparseness of data make further interpretations difficult. No evidence of geothermal mixing was observed in any of the samples. Temperature data taken from shallow water wells that penetrate Tertiary Zia Sandstone and Triassic Chinle Group sediments (less than 200 m) show higher than expected geothermal gradients, up to 93 °C/km. Transient temperature models of an aquifer with warm water flowing laterally may explain how an expected background temperature gradient in the Rio Grande rift of 30 °C/km could be heated to 80 °C/km. The aquifer is the Madera Limestone, with a projected depth of 900 meters, which lies below the Abo Formation and the Chinle Group aquitards. The models point toward a period of advective heat transport of a deep stratigraphically-bound, laterally flowing geothermal aquifer and subsequent conductive heating of the strata above the aquifer. Travertine data show elevated delta13C values from 1.31‰ -- 5.18‰ PDB, indicating a possible magmatic source. delta18O paleotemperature results indicate spring temperatures of approximately 33 °C. U-series dates yield an age for one travertine mound, ~150 meters above the active stream channel, of approximately 450 ka +/-17 ka. These data are also consistent with published data from Soda Dam. Although the data show mixed indications of a potential geothermal resource at depth, it is evident that there is no leakage of this resource into the shallow groundwater within the study area. However, higher-than-normal geothermal gradients may indicate a thermal source at depth. Travertine data are sparse, but support the existence of thermal activity related to geothermal events from the Valles caldera in the past. (Abstract shortened by ProQuest.).

Unconfined aquifer response to infiltration basins and shallow pump tests

NASA Astrophysics Data System (ADS)

Ostendorf, David W.; DeGroot, Don J.; Hinlein, Erich S.

2007-05-01

SummaryWe measure and model the unsteady, axisymmetric response of an unconfined aquifer to delayed, arbitrary recharge. Water table drainage follows the initial elastic aquifer response, as modeled for uniform, instantaneous recharge by Zlotnik and Ledder [Zlotnik, V., Ledder, G., 1992. Groundwater flow in a compressible unconfined aquifer with uniform circular recharge. Water Resources Research 28(6), 1619-1630] and delayed drainage by Moench [Moench, A.F., 1995. Combining the Neuman and Boulton models for flow to a well in an unconfined aquifer. Ground Water 33(3), 378-384]. We extend their analyses with a convolution integral that models the delayed response of an aquifer to infiltration from a circular infiltration basin. The basin routes the hydrograph to the water table with a decay constant dependent on a Brooks and Corey [Brooks, R.H., Corey, A.T., 1966. Properties of porous media affecting fluid flow. Journal of the Irrigation and Drainage Division ASCE 92(2), 61-88] unsaturated permeability exponent. The resulting closed form model approaches Neuman's [Neuman, S.P., 1972. Theory of flow in unconfined aquifers considering delayed response of the water table. Water Resources Research 8(4), 1031-1045] partially penetrating pump test equation for a small source radius, instantaneous, uniform drainage and a shallow screen section. Irrigation pump data at a well characterized part of the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate the small source model, while infiltration data from the closed drainage system of State Route 25 calibrate the infiltration basin model. The calibrated permeability, elasticity, specific yield, and permeability exponent are plausible and consistent for the pump and infiltration data sets.

Impact of lateral flow on the transition from connected to disconnected stream-aquifer systems

NASA Astrophysics Data System (ADS)

Xian, Yang; Jin, Menggui; Liu, Yanfeng; Si, Aonan

2017-05-01

Understanding the mechanisms by which stream water infiltrates through streambeds to recharge groundwater systems is essential to sustainable management of scarce water resources in arid and semi-arid areas. An inverted water table (IWT) can develop under a stream in response to the desaturation between the stream and underlying aquifer as the system changes from a connected to disconnected status. However, previous studies have suggested that the IWT can only occur at the bottom of a low permeability streambed in which only the vertical flow between the stream and groundwater during disconnection was assumed. In the present study, numerical simulations revealed that the lateral flow induced by capillarity or heterogeneity also plays an essential role on interactions between streams and aquifers. Three pathways were identified for the transition from connection to disconnection in homogenous systems; notably, the lowest point of an IWT can develop not only at the bottom of the streambed but also within the streambed or the aquifer in response to the initial desaturation at, above, or below the interface between the streambed and aquifer (IBSA), respectively. A sensitivity analysis indicated that in wide streams, the lowest point of an IWT only occurs at the bottom of the streambed; however, for a stream half width of 1 m above a 6 m thick sandy loam streambed, the lowest point occurs in the streambed as stream depth is less than 0.5 m. This critical stream depth increases with streambed thickness and decreases with stream width. Thus, in narrow streams the lowest point can also develop in a thick streambed under a shallow stream. In narrow streams, the lowest point also forms in the aquifer if the ratio of the hydraulic conductivity of the streambed to that of the aquifer is greater than the ratio of the streambed thickness to the sum of the stream depth and the streambed thickness; correspondingly, the streambed is thin but relatively permeable and the stream is deep. Furthermore, in heterogeneous streambed systems, two or three pathways can simultaneously occur and various parts of the IWT occur at distinct positions relative to the IBSA. This challenges the commonly held assumption that streambed under a disconnected stream is always fully saturated, and limits the methods which introduce a negative or atmospheric pressure value at the IBSA to calculate seepage rate or assess stream-aquifer connectivity.

Impacts of Soil-aquifer Heat and Water Fluxes on Simulated Global Climate

NASA Technical Reports Server (NTRS)

Krakauer, N.Y.; Puma, Michael J.; Cook, B. I.

2013-01-01

Climate models have traditionally only represented heat and water fluxes within relatively shallow soil layers, but there is increasing interest in the possible role of heat and water exchanges with the deeper subsurface. Here, we integrate an idealized 50m deep aquifer into the land surface module of the GISS ModelE general circulation model to test the influence of aquifer-soil moisture and heat exchanges on climate variables. We evaluate the impact on the modeled climate of aquifer-soil heat and water fluxes separately, as well as in combination. The addition of the aquifer to ModelE has limited impact on annual-mean climate, with little change in global mean land temperature, precipitation, or evaporation. The seasonal amplitude of deep soil temperature is strongly damped by the soil-aquifer heat flux. This not only improves the model representation of permafrost area but propagates to the surface, resulting in an increase in the seasonal amplitude of surface air temperature of >1K in the Arctic. The soil-aquifer water and heat fluxes both slightly decrease interannual variability in soil moisture and in landsurface temperature, and decrease the soil moisture memory of the land surface on seasonal to annual timescales. The results of this experiment suggest that deepening the modeled land surface, compared to modeling only a shallower soil column with a no-flux bottom boundary condition, has limited impact on mean climate but does affect seasonality and interannual persistence.

A geochemical approach to determine sources and movement of saline groundwater in a coastal aquifer

USGS Publications Warehouse

Anders, Robert; Mendez, Gregory O.; Futa, Kiyoto; Danskin, Wesley R.

2014-01-01

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major-ions, the chemical composition is classified as Na-Ca-Cl-SO4, Na-Cl, or Na-Ca-Cl type water. δ2H and δ18O values range from −47.7‰ to −12.8‰ and from −7.0‰ to −1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. 87Sr/86Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. 3H and 14C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher-elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest-to-southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers.

A geochemical approach to determine sources and movement of saline groundwater in a coastal aquifer.

PubMed

Anders, Robert; Mendez, Gregory O; Futa, Kiyoto; Danskin, Wesley R

2014-01-01

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major-ions, the chemical composition is classified as Na-Ca-Cl-SO4, Na-Cl, or Na-Ca-Cl type water. δ(2)H and δ(18)O values range from -47.7‰ to -12.8‰ and from -7.0‰ to -1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. (87)Sr/(86)Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. (3)H and (14)C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher-elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest-to-southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers. © 2013, National Ground Water Association.

Groundwater and surface water exchange and resulting Nitrate dynamics in the Bogue Phalia Basin in northwestern Mississippi

USGS Publications Warehouse

Barlow, Jeannie R.; Coupe, Richard H.

2012-01-01

During April 2007 through September 2008, the USGS collected hydrogeologic and water-quality data from a site on the Bogue Phalia to evaluate the role of groundwater and surface-water interaction on the transport of nitrate to the shallow sand and gravel aquifer underlying the Mississippi Alluvial Plain in northwestern Mississippi. A two-dimensional groundwater/surface-water exchange model was developed using temperature and head data and VS2DH, a variably saturated flow and energy transport model. Results from this model showed that groundwater/surface-water exchange at the site occurred regularly and recharge was laterally extensive into the alluvial aquifer. Nitrate was consistently reported in surface-water samples (n = 52, median concentration = 39.8 μmol/L) although never detected in samples collected from in-stream piezometers or shallow monitoring wells adjacent to the stream (n = 46). These two facts, consistent detections of nitrate in surface water and no detections of nitrate in groundwater, coupled with model results that indicate large amounts of surface water moving through an anoxic streambed, support the case for denitrification and nitrate loss through the streambed.

CO 2 Leakage Into Shallow Aquifers: Modeling CO 2 Gas Evolution and Accumulation at Interfaces of Heterogeneity

DOE PAGES

Porter, Mark L.; Plampin, Michael; Pawar, Rajesh; ...

2014-12-31

The physicochemical processes associated with CO 2 leakage into shallow aquifer systems are complex and span multiple spatial and time scales. Continuum-scale numerical models that faithfully represent the underlying pore-scale physics are required to predict the long-term behavior and aid in risk analysis regarding regulatory and management decisions. This study focuses on benchmarking the numerical simulator, FEHM, with intermediate-scale column experiments of CO 2 gas evolution in homogeneous and heterogeneous sand configurations. Inverse modeling was conducted to calibrate model parameters and determine model sensitivity to the observed steady-state saturation profiles. It is shown that FEHM is a powerful tool thatmore » is capable of capturing the experimentally observed out ow rates and saturation profiles. Moreover, FEHM captures the transition from single- to multi-phase flow and CO 2 gas accumulation at interfaces separating sands. We also derive a simple expression, based on Darcy's law, for the pressure at which CO 2 free phase gas is observed and show that it reliably predicts the location at which single-phase flow transitions to multi-phase flow.« less

Interim Report: 100-NR-2 Apatite Treatability Test: Low Concentration Calcium Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, Mark D.; Fritz, Brad G.; Mendoza, Donaldo P.

2008-07-11

Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100-NR-2 hydrogeologic conditions, U.S. Department of Energy, Fluor Hanford, Inc., Pacific Northwest National Laboratory, and the Washington Department of Ecology agreed that the long-term strategy for groundwater remediation at 100-N Area will include apatite sequestration as the primary treatment, followed by a secondary treatment if necessary (most likely phytoremediation). Since then, the agencies have worked together to agree on which apatite sequestration technology has the greatest chance of reducing Sr-90 flux to the river at a reasonable cost. In July 2005, aqueous injection, (i.e., the introduction of apatite-formingmore » chemicals into the subsurface) was endorsed as the interim remedy and selected for field testing. Studies are in progress to assess the efficacy of in situ apatite formation by aqueous solution injection to address both the vadose zone and the shallow aquifer along the 300 ft of shoreline where Sr-90 concentrations are highest. This report describes the field testing of the shallow aquifer treatment.« less

Hydrologic characteristics and possible effects of surface mining in the northwestern part of West Branch Antelope Creek basin, Mercer County, North Dakota

USGS Publications Warehouse

Crawley, Mark E.; Emerson, Douglas G.

1981-01-01

Lignite beds and abundant discontinuous sandstone beds of the Paleocene Sentinel Butte Member of the Fort Union Formation and sand and gravel beds in the Quarternary glaciofluvial deposits (Antelope Creek aquifer) are the most important aquifers for domestic and livestock water supplies in the West Branch Antelope Creek basin. In the Beulah-Zap lignite, ground water moves from highland area in the west toward the Antelope Creek aquifer. Water levels in the basal Sentinel Butte sandstone appear to be controlled by the level of Lake Sakakawea. In the glaciofluvial deposits of the Antelope Creek aquifer water moves from a ground-water divide northwestward to Lake Sakakawea and southeastward toward the Knife River. Large water-level declines in wells completed in the lignite and shallower aquifers could be expected with mining. The effects probably would be limited to within 1 to 2 miles of an active mine. Surface-runoff duration could be altered by increased infiltration and retention in the reclaimed are and possible temporal extension of base flow could occur. Shallow ground water beneath mine sites would be expected to increase in dissolved solids and locally to contain large sodium and sulfate concentrations. In some locations movement of poor quality water toward the Antelope Creek aquifer would be expected. (USGS)

Depth of the base of the Jackson aquifer, based on geophysical exploration, southern Jackson Hole, Wyoming, USA

USGS Publications Warehouse

Nolan, B.T.; Campbell, D.L.; Senterfit, R.M.

1998-01-01

A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100-600 ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming.

Arsenic mobilization in the aquifers of three physiographic settings of West Bengal, India: understanding geogenic and anthropogenic influences.

PubMed

Bhowmick, Subhamoy; Nath, Bibhash; Halder, Dipti; Biswas, Ashis; Majumder, Santanu; Mondal, Priyanka; Chakraborty, Sudipta; Nriagu, Jerome; Bhattacharya, Prosun; Iglesias, Monica; Roman-Ross, Gabriela; Guha Mazumder, Debendranath; Bundschuh, Jochen; Chatterjee, Debashis

2013-11-15

A comparative hydrogeochemical study was carried out in West Bengal, India covering three physiographic regions, Debagram and Chakdaha located in the Bhagirathi-Hooghly alluvial plain and Baruipur in the delta front, to demonstrate the control of geogenic and anthropogenic influences on groundwater arsenic (As) mobilization. Groundwater samples (n = 90) from tube wells were analyzed for different physico-chemical parameters. The low redox potential (Eh = -185 to -86 mV) and dominant As(III) and Fe(II) concentrations are indicative of anoxic nature of the aquifer. The shallow (<100 m) and deeper (>100 m) aquifers of Bhagirathi-Hooghly alluvial plains as well as shallow aquifers of delta front are characterized by Ca(2+)HCO3(-) type water, whereas Na(+) and Cl(-) enrichment is found in the deeper aquifer of delta front. The equilibrium of groundwater with respect to carbonate minerals and their precipitation/dissolution seems to be controlling the overall groundwater chemistry. The low SO4(2-) and high DOC, PO4(3-) and HCO3(-) concentrations in groundwater signify ongoing microbial mediated redox processes favoring As mobilization in the aquifer. The As release is influenced by both geogenic (i.e. geomorphology) and anthropogenic (i.e. unsewered sanitation) processes. Multiple geochemical processes, e.g., Fe-oxyhydroxides reduction and carbonate dissolution, are responsible for high As occurrence in groundwaters. Copyright © 2012 Elsevier B.V. All rights reserved.

STABLE CARBON ISOTOPE BIOGEOCHEMISTRY OF A SHALLOW SAND AQUIFER CONTAMINATED WITH FUEL HYDROCARBONS

EPA Science Inventory

Ground-water chemistry and the stable C isotope composition ( 13CDIC) of dissolved C (DIC) were measured in a sand aquifer contaminated with JP-4 fuel hydrocarbons. Results show that ground water in the upgradient zone was characterized by DIC content of 14-20 mg C/L and 13CDIC...

LABORATORY STUDIES ON THE STABILITY AND TRANSPORT OF INORGANIC COLLOIDS THROUGH NATURAL AQUIFER MATERIAL

EPA Science Inventory

The stability and transport of radio-labeled Fe2O3 particles were studied using laboratory batch and column techniques. Core material collected from shallow sand and gravel aquifer was used as the immobile column matrix material. Variables in the study included flow rate, pH, i...

Summary of extensometric measurements in El Paso, Texas

USGS Publications Warehouse

Heywood, Charles E.

2003-01-01

Two counter-weighted-pipe borehole extensometers were installed on the left bank of the Rio Grande between El Paso, Texas, and Ciudad Juarez, Chihuahua, Mexico, in 1992. A shallow extensometer measures vertical compaction in the 6- to 100-meter aquifer-system depth interval. A deep extensometer measures vertical compaction in the 6- to 305-meter aquifer-system depth interval. Both extensometers are referenced to the same surface datum, which allows time-series differencing to determine vertical compaction in the depth interval between 100 and 305 meters. From April 2, 1993, through June 13, 2002, 1.6 centimeters of compaction occurred in the 6-to 305-m depth interval. Until February 1999, most aquifer-system compaction occurred in the deeper aquifer-system interval between 100 and 305 meters, from which ground water was extracted. After that time, compaction in the shallow interval from 6 to 100 meters was predominant and attained a maximum of 7.6 millimeters by June 13, 2002. Minor residual compaction is expected to continue; continued maintenance of the El Paso extensometers would document this process.

Disposal of saltwater during well construction--Problems and solutions

USGS Publications Warehouse

Pitt, William A.; Meyer, Frederick W.; Hull, John E.

1977-01-01

The recent interest in the disposal of treated sewage effluent by deep-well injection into salt-water-filled aquifers has increased the need for proper disposal of salt water as more wells are drilled and tested each year.The effects on an unconfined aquifer of the improper disposal of salt water associated with the construction of three wells in southeastern Florida emphasize this need. In two of the wells provisions to prevent and detect salt-water contamination of the unconfined aquifer were practically nonexistent, and in one well extensive provisions were made. Of the three drilling sites the one with proper provision for detection presented no serious problem, as the ground water contaminated by the salt water was easily located and removed. The provisions consisted of drilling a brine-injection well to dispose of salt water discharged in drilling and testing operations, using a closed drilling circulation system to reduce spillage, installing shallow observation wells to map the extent and depth of any salt-water contamination of the shallow aquifer, and installing a dewatering system to remove contaminated ground water.

Modeling Three-Dimensional Flow in Confined Aquifers by Superposition of Both Two- and Three-Dimensional Analytic Functions

NASA Astrophysics Data System (ADS)

Haitjema, Henk M.

1985-10-01

A technique is presented to incorporate three-dimensional flow in a Dupuit-Forchheimer model. The method is based on superposition of approximate analytic solutions to both two- and three-dimensional flow features in a confined aquifer of infinite extent. Three-dimensional solutions are used in the domain of interest, while farfield conditions are represented by two-dimensional solutions. Approximate three- dimensional solutions have been derived for a partially penetrating well and a shallow creek. Each of these solutions satisfies the condition that no flow occurs across the confining layers of the aquifer. Because of this condition, the flow at some distance of a three-dimensional feature becomes nearly horizontal. Consequently, remotely from a three-dimensional feature, its three-dimensional solution is replaced by a corresponding two-dimensional one. The latter solution is trivial as compared to its three-dimensional counterpart, and its use greatly enhances the computational efficiency of the model. As an example, the flow is modeled between a partially penetrating well and a shallow creek that occur in a regional aquifer system.

Water-quality observations of the San Antonio segment of the Edwards aquifer, Texas, with an emphasis on processes influencing nutrient and pesticide geochemistry and factors affecting aquifer vulnerability, 2010–16

USGS Publications Warehouse

Opsahl, Stephen P.; Musgrove, MaryLynn; Mahler, Barbara J.; Lambert, Rebecca B.

2018-06-07

As questions regarding the influence of increasing urbanization on water quality in the Edwards aquifer are raised, a better understanding of the sources, fate, and transport of compounds of concern in the aquifer—in particular, nutrients and pesticides—is needed to improve water management decision-making capabilities. The U.S. Geological Survey, in cooperation with the San Antonio Water System, performed a study from 2010 to 2016 to better understand how water quality changes under a range of hydrologic conditions and in contrasting land-cover settings (rural and urban) in the Edwards aquifer. The study design included continuous hydrologic monitoring, continuous water-quality monitoring, and discrete sample collection for a detailed characterization of water quality at a network of sites throughout the aquifer system. The sites were selected to encompass a “source-to-sink” (that is, from aquifer recharge to aquifer discharge) approach. Network sites were selected to characterize rainfall, recharging surface water, and groundwater; groundwater sites included wells in the unconfined part of the aquifer (unconfined wells) and in the confined part of the aquifer (confined wells) and a major discharging spring. Storm-related samples—including rainfall samples, stormwater-runoff (surface-water) samples, and groundwater samples—were collected to characterize the aquifer response to recharge.Elevated nitrate concentrations relative to national background values and the widespread detection of pesticides indicate that the Edwards aquifer is vulnerable to contamination and that vulnerability is affected by factors such as land cover, aquifer hydrogeology, and changes in hydrologic conditions. Greater vulnerability of groundwater in urban areas relative to rural areas was evident from results for urban groundwater sites, which generally had higher nitrate concentrations, elevated δ15N-nitrate values, a greater diversity of pesticides, and higher pesticide concentrations. The continuum of water quality from unconfined rural groundwater sites (least affected by anthropogenic contamination) to unconfined urban groundwater sites (most affected by anthropogenic contamination) demonstrates enhanced vulnerability of urban versus rural land cover. Differences in contaminant occurrences and concentration among unconfined urban wells indicate that the urban parts of the aquifer are not uniformly vulnerable, but rather are affected by spatial differences in the sources of nutrients and pesticides. In urban areas, the shallow, unconfined groundwater sites showed greater temporal variability in both nutrient and pesticide concentrations, as well as a greater degree of contamination, than did deeper, confined groundwater sites. In comparison to that of the shallow, unconfined groundwater sites, the water quality of the deeper, confined groundwater sites was relatively invariant during this multiyear study. Although aquifer hydrogeology is an important factor related to aquifer vulnerability, land cover likely has a greater influence on pesticide contamination of groundwater. Temporal variability in hydrologic conditions for the Edwards aquifer is apparent in data for surface water as a source of groundwater recharge, water-level altitude in wells, spring discharge, and groundwater quality. This temporal variability affects recharge sources, recharge amounts, groundwater traveltimes, flow routing, water-rock interaction processes, dilution, mixing, and, in turn, water quality. Relations of land cover, aquifer hydrogeology, and changing hydrologic conditions to water quality are complex but provide insight into the vulnerability of Edwards aquifer groundwater—a vital drinking-water resource.

Hydrogeology, Water Chemistry, and Factors Affecting the Transport of Contaminants in the Zone of Contribution of a Public-Supply Well in Modesto, Eastern San Joaquin Valley, California

USGS Publications Warehouse

Jurgens, Bryant C.; Burow, Karen R.; Dalgish, Barbara A.; Shelton, Jennifer L.

2008-01-01

Ground-water chemistry in the zone of contribution of a public-supply well in Modesto, California, was studied by the U.S. Geological Survey National Water Quality Assessment (NAWQA) Program's topical team for Transport of Anthropogenic and Natural Contaminants (TANC) to supply wells. Twenty-three monitoring wells were installed in Modesto to record baseline hydraulic information and to collect water-quality samples. The monitoring wells were divided into four categories that represent the chemistry of different depths and volumes of the aquifer: (1) water-table wells were screened between 8.5 and 11.7 m (meter) (28 and 38.5 ft [foot]) below land surface (bls) and were within 5 m (16 ft) of the water table; (2) shallow wells were screened between 29 and 35 m (95 and 115 ft) bls; (3) intermediate wells were screened between 50.6 and 65.5 m (166 and 215 ft) bls; and (4) deep wells are screened between 100 to 106 m (328 and 348 ft) bls. Inorganic, organic, isotope, and age-dating tracers were used to characterize the geochemical conditions in the aquifer and understand the mechanisms of mobilization and movement of selected constituents from source areas to a public-supply well. The ground-water system within the study area has been significantly altered by human activities. Water levels in monitoring wells indicated that horizontal movement of ground water was generally from the agricultural areas in the northeast towards a regional water-level depression within the city in the southwest. However, intensive pumping and irrigation recharge in the study area has caused large quantities of ground water to move vertically downward within the regional and local flow systems. Analysis of age tracers indicated that ground-water age varied from recent recharge at the water table to more than 1,000 years in the deep part of the aquifer. The mean age of shallow ground water was determined to be between 30 and 40 years. Intermediate ground water was determined to be a mixture of modern (Post-1950) and old (Pre-1950) ground water. As a result, concentrations of age tracers were detectable but diluted by older ground water. Deep ground water generally represented water that was recharged under natural conditions and therefore had much older ages. Ground water reaching the public-supply well was a mixture of older intermediate and deep ground water and young shallow ground water that has been anthropogenically-influenced to a greater extent than intermediate ground water. Uranium and nitrate pose the most significant threat to the quality of water discharged from the public-supply well. Although pesticides and VOCs were present in ground water from the public-supply well and monitoring wells, currently concentrations of these contaminants are generally less than one-hundredth the concentration of drinking water standards. In contrast, both uranium and nitrate were above half the concentration of drinking water standards for public-supply well samples, and were above drinking water standards for several water-table and shallow monitoring wells. Shallow ground water contributes roughly 20 percent of the total flow to the public-supply well and was the entry point of most contaminants reaching the public-supply well. Naturally-occurring uranium, which is commonly adsorbed to aquifer sediments, was mobilized by oxygen-rich, high-alkalinity water, causing concentrations in some monitoring wells to be above the drinking-water standard of 30 ug/L (microgram per liter). Adsorption experiments, sediment extractions, and uranium isotopes indicated uranium in water-table and shallow ground water was leached from aquifer sediments. Uranium is strongly correlated to bicarbonate concentrations (as measured by alkalinity) in ground water. Bicarbonate can effectively limit uranium adsorption to sediments. As a result, continued downward movement of high-alkalinity, oxygen-rich ground water will likely lead to larger portions of the aquifer having

Two Reactive Zones within Riverbank Aquifers Impact the Accumulation of Arsenic within Permeable Natural Reactive Barrier

NASA Astrophysics Data System (ADS)

Knappett, P.; Myers, K.; Jewell, K.; Berube, M.; Datta, S.; Hossain, A.; Hosain, A.; Lipsi, M.; Ahmed, K. M.

2017-12-01

River stage fluctuations drives river water, rich oxidants, into riverbanks aquifers. When these aquifers are rich in dissolved iron (Fe), iron oxides (FeOOH) precipitate, creating a reactive surface upon which toxic elements such as arsenic (As) may sorb. These Permeable Natural Reactive Barriers (PNRBs) have been studied on the Meghna River. The lack of understanding of what controls their formation and fate could result in dangerous consequences. Pumping of riverbank aquifers for irrigation could re-mobilize toxic concentrations of As into drinking water aquifers. It is important to understand the hydrological, geochemical and biological processes controlling the properties of PNRBs. To this end, monitoring wells and drive-point piezometers were installed orthogonal to the Meghna River in Bangladesh. The dimensions of the shallow aquifer was mapped with Electrical Resistivity Tomography (ERT). The monitoring wells and a river gage were instrumented with pressure transducers to record water level fluctuations. Groundwater flows towards the river for most of the year but reverses under the influence of local irrigation pumping in the late dry season and rapidly rising river stage in the early monsoon. Semi-diurnal tides in the dry season have an amplitude of 80 cm. Declining concentrations of conservative dissolved ions towards the river indicated a zone of dilution from river water extending up to 50 m from the river's dry season edge. Dissolved As was produced as groundwater passed through this dilution zone until the final 20 m where As was abruptly removed from solution. This location coincided with a PNRB with enriched solid-phase Fe and Mn within the upper 3 m of sediment. 16S bacterial community DNA was sequenced from the wells and drive-point piezometers to map the distribution of Fe and As reducers and oxidizers. The richest overall biodiversity was found within the PNRB zone. It contained the most oxidizing and reducing species. This evidence suggests that transient river levels drive mixing between oxidizing and reducing agents in Hyporheic Zones (HZs). When the shallow aquifers are rich in dissolved concentrations of Fe and As, this mixing results in the accumulation of solid-phase Fe and As. This is likely a general process affecting other oxide-forming metals and toxic elements they bind.

Assessment of intrinsic bioremediation of gasoline contamination in the shallow aquifer, Laurel Bay Exchange, Marine Corps Air Station Beaufort, South Carolina

USGS Publications Warehouse

Landmeyer, J.E.; Chapelle, Francis; Bradley, P.M.

1996-01-01

Laboratory, field, and digital solute-transport- modeling studies demonstrate that microorganisms indigenous to the shallow ground-water system at Laurel Bay Exchange, Marine Corps Air Station Beaufort, South Carolina, can degrade petroleum hydrocarbons in gasoline released at the site. Microorganisms in aquifer sediments incubated in the laboratory under aerobic and anaerobic conditions mineralized radiolabeled carbon 14-toluene to 14C-carbon dioxide with first-order rate constants of Kbio = -0.640 per day and Kbio = -0.003 per day, respectively. Digital solute- transport modeling using the numerical code SUTRA revealed that anaerobic biodegradation of benzene occurs with a first-order rate constant near Kbio = -0.00025 per day. Sandy aquifer material beneath Laurel Bay Exchange is characterized by relatively high hydraulic conductivities (Kaq = 8.9 to 17.3 feet per day), average ground-water flow rate of about 60 feet per year, and a relatively uniform hydraulic gradient of 0.004 feet per foot. The sandy aquifer material also has low adsorptive potentials for toluene and benzene (both about Kad = 2.0 x 10-9 cubic feet per milligram), because of the lack of natural organic matter in the aquifer. The combination of this ground-water-flow rate and absence of significant adsorptive capacity in the aquifer permits toluene and benzene concentrations to be detected downgradient from the source area in monitoring wells, even though biodegradation of these compounds has been demonstrated. Solute-transport simulations, however, indicate that toluene and benzene will not reach the Broad River, the nearest point of contact with wildlife or human populations, about 3,600 feet west of the site boundary. These simulations also show that contamination will not be transported to the nearest Marine Corps property line about 2,400 feet south of the site. This is primarily because the source of contaminants has essentially been removed, and the low adsorptive capacity of the aquifer sediments has prevented the occurrence of an adsorbed, continuous source of petroleum hydrocarbons. Therefore, digital simulations of toluene and benzene transport at Laurel Bay Exchange indicate that intrinsic bioremediation could be a successful remediation alternative for prohibiting transport of dissolved toluene and benzene to the Broad River.

Well installation, single-well testing, and particle-size analysis for selected sites in and near the Lost Creek Designated Ground Water Basin, north-central Colorado, 2003-2004

USGS Publications Warehouse

Beck, Jennifer A.; Paschke, Suzanne S.; Arnold, L. Rick

2011-01-01

This report describes results from a groundwater data-collection program completed in 2003-2004 by the U.S. Geological Survey in support of the South Platte Decision Support System and in cooperation with the Colorado Water Conservation Board. Two monitoring wells were installed adjacent to existing water-table monitoring wells. These wells were installed as well pairs with existing wells to characterize the hydraulic properties of the alluvial aquifer and shallow Denver Formation sandstone aquifer in and near the Lost Creek Designated Ground Water Basin. Single-well tests were performed in the 2 newly installed wells and 12 selected existing monitoring wells. Sediment particle size was analyzed for samples collected from the screened interval depths of each of the 14 wells. Hydraulic-conductivity and transmissivity values were calculated after the completion of single-well tests on each of the selected wells. Recovering water-level data from the single-well tests were analyzed using the Bouwer and Rice method because test data most closely resembled those obtained from traditional slug tests. Results from the single-well test analyses for the alluvial aquifer indicate a median hydraulic-conductivity value of 3.8 x 10-5 feet per second and geometric mean hydraulic-conductivity value of 3.4 x 10-5 feet per second. Median and geometric mean transmissivity values in the alluvial aquifer were 8.6 x 10-4 feet squared per second and 4.9 x 10-4 feet squared per second, respectively. Single-well test results for the shallow Denver Formation sandstone aquifer indicate a median hydraulic-conductivity value of 5.4 x 10-6 feet per second and geometric mean value of 4.9 x 10-6 feet per second. Median and geometric mean transmissivity values for the shallow Denver Formation sandstone aquifer were 4.0 x 10-5 feet squared per second and 5.9 x 10-5 feet squared per second, respectively. Hydraulic-conductivity values for the alluvial aquifer in and near the Lost Creek Designated Ground Water Basin generally were greater than hydraulic-conductivity values for the Denver Formation sandstone aquifer and less than hydraulic-conductivity values for the alluvial aquifer along the main stem of the South Platte River Basin reported by previous studies. Particle sizes were analyzed for a total of 14 samples of material representative of the screened interval in each of the 14 wells tested in this study. Of the 14 samples collected, 8 samples represent the alluvial aquifer and 6 samples represent the Denver Formation sandstone aquifer in and near the Lost Creek Designated Ground Water Basin. The sampled alluvial aquifer material generally contained a greater percentage of large particles (larger than 0.5 mm) than the sampled sandstone aquifer material. Alternatively, the sampled sandstone aquifer material generally contained a greater percentage of fine particles (smaller than 0.5 mm) than the sampled alluvial aquifer material consistent with the finding that the alluvial aquifer is more conductive than the sandstone aquifer in the vicinity of the Lost Creek Designated Ground Water Basin.

Cenomanian-Turonian aquifer of central Israel, its development and possible use as a storage reservoir

USGS Publications Warehouse

Schneider, Robert

1964-01-01

The Cenomanian-Turonian formations constitute a highly permeable dolomite and limestone aquifer in central Israel. The aquifer is on the west limb of an anticlinorium that trends north-northeast. In places it may be as much as 800 meters thick, but in the report area, largely the foothills of the Judean-Ephraim Mountains where the water development is most intensive, its thickness is generally considerably less. In some places the aquifer occurs at or near the land surface, or it is covered by sandy and gravelly coastal-plain deposits. However, in a large part of the area, it is overlain by as much as 400 meters of relatively impermeable strata, and it is probably underlain by less permeable Lower Cretaceous strata. In general the aquifer water is under artesian pressure. The porosity of the aquifer is characterized mainly by solution channels and cavities produced by jointing and faulting. In addition to the generally high permeability of the aquifer, some regions, which probably coincide with ancient drainage patterns and (or) fault zones, have exceptionally high permeabilities. The source of most of the water in the aquifer is believed to be rain that falls on the foothills area. The westward movement of ground water from the mountainous outcrop areas appears to be impeded by a zone of low permeability which is related to structural and stratigraphic conditions along the western side of the mountains. Gradients of the piezometric surface are small, and the net direction of water movement is westward and northwestward under natural conditions. Locally, however, the flow pattern may be in other directions owing to spatial variations in permeability in the aquifer, the location of natural discharge outlets, and the relation of the aquifer to adjacent geologic formations. There probably is also a large vertical component of flow. Pumping has modified the flow pattern by producing several irregularly shaped shallow depressions in the piezometric surface although, to date, no unwatering of the aquifer has occurred. In the central part of the area, pumping has induced some infiltration from overlying coastal-plain formations. Injecting and storing surplus water seasonally in the aquifer should be feasible at almost any place. However, the movement and recovery of the injected water probably could be controlled most easily if the water were injected where depressions have been formed in the piezometric surface.

Effects of human-induced alteration of groundwater flow on concentrations of naturally-occurring trace elements at water-supply wells

USGS Publications Warehouse

Ayotte, J.D.; Szabo, Z.; Focazio, M.J.; Eberts, S.M.

2011-01-01

The effects of human-induced alteration of groundwater flow patterns on concentrations of naturally-occurring trace elements were examined in five hydrologically distinct aquifer systems in the USA. Although naturally occurring, these trace elements can exceed concentrations that are considered harmful to human health. The results show that pumping-induced hydraulic gradient changes and artificial connection of aquifers by well screens can mix chemically distinct groundwater. Chemical reactions between these mixed groundwaters and solid aquifer materials can result in the mobilization of trace elements such as U, As and Ra, with subsequent transport to water-supply wells. For example, in the High Plains aquifer near York, Nebraska, mixing of shallow, oxygenated, lower-pH water from an unconfined aquifer with deeper, confined, anoxic, higher-pH water is facilitated by wells screened across both aquifers. The resulting higher-O2, lower-pH mixed groundwater facilitated the mobilization of U from solid aquifer materials, and dissolved U concentrations were observed to increase significantly in nearby supply wells. Similar instances of trace element mobilization due to human-induced mixing of groundwaters were documented in: (1) the Floridan aquifer system near Tampa, Florida (As and U), (2) Paleozoic sedimentary aquifers in eastern Wisconsin (As), (3) the basin-fill aquifer underlying the California Central Valley near Modesto (U), and (4) Coastal Plain aquifers of New Jersey (Ra). Adverse water-quality impacts attributed to human activities are commonly assumed to be related solely to the release of the various anthropogenic contaminants to the environment. The results show that human activities including various land uses, well drilling, and pumping rates and volumes can adversely impact the quality of water in supply wells, when associated with naturally-occurring trace elements in aquifer materials. This occurs by causing subtle but significant changes in geochemistry and associated trace element mobilization as well as enhancing advective transport processes.

On the origins of hypersaline groundwater in the Nile Delta aquifer

NASA Astrophysics Data System (ADS)

van Engelen, Joeri; Oude Essink, Gualbert H. P.; Kooi, Henk; Bierkens, Marc F. P.

2018-05-01

The Nile Delta is essential to Egypt's agro- and socio-economy. Although surface water is the traditional source for Egypt's irrigation, the shallow fresh groundwater resources underlying the delta are increasingly burdened by groundwater pumping, which increases interest in the status of the groundwater resources. Groundwater up to three times more saline than sea water was found at 600 m depth. The occurrence of this hypersaline groundwater raises doubts on the often-made assumption in the literature that seawater is the only source of salt in the Nile Delta aquifer and makes further investigation necessary. Knowledge on the origin of this hypersaline groundwater is key in assessing the possibility of deep fresh groundwater pockets. In this paper we conducted computational analyses to assess possible origins using both analytical solutions and numerical models. It is concluded that the hypersaline groundwater can either originate from Quaternary free convection systems, or from compaction-induced upward salt transport of hypersaline groundwater that formed during the Messinian salinity crisis. Our results also indicate that with groundwater dating it is possible to discriminate between these two hypotheses. Furthermore, it is deduced that the hydrological connection between aquifer and sea is crucial to the hydrogeological functioning of the Nile Delta Aquifer.

Hydrogeologic implications of increased septic-tank-soil-absorption system density, Ogden Valley, Weber County, Utah

USGS Publications Warehouse

Lowe, Mike; Miner, Michael L.; ,

1990-01-01

Ground water in Ogden Valley occurs in perched, confined, and unconfined aquifers in the valley fill to depths of 600 feet and more. The confined aquifer, which underlies only the western portion of the valley, is overlain by cleyey silt lacustrine sediments probably deposited during the Bonneville Basin's Little Valley lake cycle sometime between 90,000 and 150,000 years ago. The top of this cleyey silt confining layer is generally 25 to 60 feet below the ground surface. Unconfined conditions occur above and beyond the outer margin of the confining layer. The sediments overlying the confining layer are primarily Lake Bonneville deposits. Water samples from springs, streams, and wells around Pineview Reservoir, and from the reservoir itself, were collected and analyzed. These samples indicate that water quality in Ogden Valley is presently good. Average nitrate concentrations in the shallow unconfined aquifer increase toward the center of Ogden Valley. This trend was not observed in the confined aquifer. There is no evidence, however, of significant water-quality deterioration, even in the vicinity of Huntsville, a town that has been densely developed using septic-tank-soil-absorption systems for much of the time since it was founded in 1860.

Simulation of groundwater flow in the shallow aquifer system of the Delmarva Peninsula, Maryland and Delaware

USGS Publications Warehouse

Sanford, Ward E.; Pope, Jason P.; Selnick, David L.; Stumvoll, Ryan F.

2012-01-01

Estimating future loadings of nitrogen to the Chesapeake Bay requires knowledge about the groundwater flow system and the traveltime of water and chemicals between recharge at the water table and the discharge to streams and directly to the bay. The Delmarva Peninsula has a relatively large proportion of its land devoted to agriculture and a large associated nitrogen load in groundwater that has the potential to enter the bay in discharging groundwater. To better understand the shallow aquifer system with respect to this loading and the traveltime to the bay, the U.S. Geological Survey constructed a steady-state groundwater flow model for the region. The model is based on estimates of recharge calculated using recently developed regression equations for evapotranspiration and surface runoff. The hydrogeologic framework incorporated into the model includes unconfined surficial aquifer sediments, as well as subcropping confined aquifers and confining beds down to 300 feet below land surface. The model was calibrated using 48 water-level measurements and 24 tracer-based ages from wells located across the peninsula. The resulting steady-state flow solution was used to estimate ages of water in the shallow aquifer system through the peninsula and the distribution and magnitude of groundwater traveltime from recharge at the water table to discharge in surface-water bodies (referred to as return time). Return times vary but are typically less than 10 years near local streams and greater than 100 years near the stream divides. The model can be used to calculate nitrate transport parameters in various local watersheds and predict future trends in nitrate loadings to Chesapeake Bay for different future nitrogen application scenarios.

Geologic controls on the chemical behaviour of nitrate in riverside alluvial aquifers, Korea

NASA Astrophysics Data System (ADS)

Min, Joong-Hyuk; Yun, Seong-Taek; Kim, Kangjoo; Kim, Hyoung-Soo; Kim, Dong-Ju

2003-04-01

To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land-use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers.About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l-1 NO3-), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l-1 NO3-). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4 15N) applied to farmland, and animal manure and sewage (15-20 15N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland-recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the 15N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent.

Deep challenges for China's war on water pollution.

PubMed

Han, Dongmei; Currell, Matthew J; Cao, Guoliang

2016-11-01

China's Central government has released an ambitious plan to tackle the nation's water pollution crisis. However, this is inhibited by a lack of data, particularly for groundwater. We compiled and analyzed water quality classification data from publicly available government sources, further revealing the scale and extent of the crisis. We also compiled nitrate data in shallow and deep groundwater from a range of literature sources, covering 52 of China's groundwater systems; the most comprehensive national-scale assessment yet. Nitrate pollution at levels exceeding the US EPA's maximum contaminant level (10 mg/L NO 3 N) occurs at the 90th percentile in 25 of 36 shallow aquifers and 10 out of 37 deep or karst aquifers. Isotopic compositions of groundwater nitrate (δ 15 N and δ 18 O NO3 values ranging from -14.9‰ to 35.5‰ and -8.1‰ to 51.0‰, respectively) indicate many nitrate sources including soil nitrogen, agricultural fertilizers, untreated wastewater and/or manure, and locally show evidence of de-nitrification. From these data, it is clear that contaminated groundwater is ubiquitous in deep aquifers as well as shallow groundwater (and surface water). Deep aquifers contain water recharged tens of thousands of years before present, long before widespread anthropogenic nitrate contamination. This groundwater has therefore likely been contaminated due to rapid bypass flow along wells or other conduits. Addressing the issue of well condition is urgently needed to stop further pollution of China's deep aquifers, which are some of China's most important drinking water sources. China's new 10-point Water Pollution Plan addresses previous shortcomings, however, control and remediation of deep groundwater pollution will take decades of sustained effort. Copyright © 2016. Published by Elsevier Ltd.

Water quality in the vicinity of Mosquito Creek Lake, Trumbull County, Ohio, in relation to the chemistry of locally occurring oil, natural gas, and brine

USGS Publications Warehouse

Barton, G.J.; Burruss, R.C.; Ryder, R.T.

1998-01-01

Environmental samples collected in the Mosquito Creek Lake area were used to characterize water quality in relation to the chemistry of locally occurring oil, natural gas, and brine and to establish baseline water quality. Mosquito Creek Lake (a manmade reservoir) and the shallow bedrock aquifers near the lake are major sources of potable water in central Trumbull County. The city of Warren relies on the lake as a sole source of potable water. Some of the lake bottom may be in direct hydraulic connection with the underlying aquifers. The city of Cortland, along the southeastern shore of the lake, relies on the Cussewago Sandstone aquifer as a sole source of potable water. This aquifer subcrops beneath the glacio-fluvial sediments that underlie the lake. Nearly all residential homes around the lake, with the exception of homes in the city of Cortland, rely on domestic supply wells as a source of potable water.Oil and natural gas exploration and production have been ongoing in the Mosquito Creek Lakearea since the discovery of the historic Mecca Oil Pool in the Mississippian Berea and Cussewago Sandstones in 1860. Since the late 1970' s, the major drilling objective and zone of production is the Lower Silurian Clinton sandstone. The oil and natural gas resources of the Mosquito Creek Lake area, including reservoir pressure, production history, and engineering and abandonment practices are described in this report.The chemical and isotopic characteristics of the historic Mecca oil and natural gas are very different than those of the Clinton sandstone oil and natural gas. Gas chromatograms show that Mecca oil samples are extensively altered by biodegradation, whereas Clinton sandstone oils are not. Extensive alteration of Mecca oil is consistent with their occurrence at very shallow depths (less than 100 ft below land surface) where microbial activity can affect their composition. Also, the carbon-isotope composition of dissolved methane gas from Berea and Cussewago Sandstone water samples indicates that the gas is microbially generated, whereas the Clinton sandstone gases are thermogenically generated.Methane gas, in addition to crude oil, occurs naturally in the shallow Berea and Cussewago Sandstone aquifers in the Mosquito Creek Lake area and concentrations of dissolved methane are significant in the city of Cortland public-supply wells and in the domestic-supply wells near the southern shore of the lake. Water associated with oil and gas in the Clinton sandstone is a brine with high concentrations of chloride. Water from the Berea and Cussewago Sandstones, however, is fresh and potable. The contrasting geochemical characteristics are important for addressing water-quality issues that relate to oil and natural gas development in the Mosquito Creek area.A reexamination of the geologic framework and results of a subsurface-gas survey show that crude oil in the historic Mecca Oil Pool probably does not seep into Mosquito Creek Lake. Environmental samples show no evidence of any measurable release of oil, gas, or brine from the deeper Clinton sandstone oil and gas wells to the shallow aquifers, the lake, or lake tributaries. Brine is not associated with the hydrocarbons in the shallow Berea-Cussewago aquifer system and therefore cannot be a source of brine contamination. A mixing diagram constructed for dissolved bromide and chloride in surface water and water-supply wells shows no demonstrable mixing of these water resources with brine from the Clinton sandstone. There is some notable salinity in surface waters; however, the water is bromide poor, and a mixing diagram indicates that some local ground waters are influenced by halite solutions, presumably derived from leaching of road salt or from septic effluent.

Carbon isotopes of dissolved inorganic carbon reflect utilization of different carbon sources by microbial communities in two limestone aquifer assemblages

NASA Astrophysics Data System (ADS)

Nowak, Martin E.; Schwab, Valérie F.; Lazar, Cassandre S.; Behrendt, Thomas; Kohlhepp, Bernd; Totsche, Kai Uwe; Küsel, Kirsten; Trumbore, Susan E.

2017-08-01

Isotopes of dissolved inorganic carbon (DIC) are used to indicate both transit times and biogeochemical evolution of groundwaters. These signals can be complicated in carbonate aquifers, as both abiotic (i.e., carbonate equilibria) and biotic factors influence the δ13C and 14C of DIC. We applied a novel graphical method for tracking changes in the δ13C and 14C of DIC in two distinct aquifer complexes identified in the Hainich Critical Zone Exploratory (CZE), a platform to study how water transport links surface and shallow groundwaters in limestone and marlstone rocks in central Germany. For more quantitative estimates of contributions of different biotic and abiotic carbon sources to the DIC pool, we used the NETPATH geochemical modeling program, which accounts for changes in dissolved ions in addition to C isotopes. Although water residence times in the Hainich CZE aquifers based on hydrogeology are relatively short (years or less), DIC isotopes in the shallow, mostly anoxic, aquifer assemblage (HTU) were depleted in 14C compared to a deeper, oxic, aquifer complex (HTL). Carbon isotopes and chemical changes in the deeper HTL wells could be explained by interaction of recharge waters equilibrated with post-bomb 14C sources with carbonates. However, oxygen depletion and δ13C and 14C values of DIC below those expected from the processes of carbonate equilibrium alone indicate considerably different biogeochemical evolution of waters in the upper aquifer assemblage (HTU wells). Changes in 14C and 13C in the upper aquifer complexes result from a number of biotic and abiotic processes, including oxidation of 14C-depleted OM derived from recycled microbial carbon and sedimentary organic matter as well as water-rock interactions. The microbial pathways inferred from DIC isotope shifts and changes in water chemistry in the HTU wells were supported by comparison with in situ microbial community structure based on 16S rRNA analyses. Our findings demonstrate the large variation in the importance of biotic as well as abiotic controls on 13C and 14C of DIC in closely related aquifer assemblages. Further, they support the importance of subsurface-derived carbon sources like DIC for chemolithoautotrophic microorganisms as well as rock-derived organic matter for supporting heterotrophic groundwater microbial communities and indicate that even shallow aquifers have microbial communities that use a variety of subsurface-derived carbon sources.

Delineation of brine contamination in and near the East Poplar oil field, Fort Peck Indian Reservation, northeastern Montana, 2004-09

USGS Publications Warehouse

Thamke, Joanna N.; Smith, Bruce D.

2014-01-01

The extent of brine contamination in the shallow aquifers in and near the East Poplar oil field is as much as 17.9 square miles and appears to be present throughout the entire saturated zone in contaminated areas. The brine contamination affects 15–37 billion gallons of groundwater. Brine contamination in the shallow aquifers east of the Poplar River generally moves to the southwest toward the river and then southward in the Poplar River valley. The likely source of brine contamination in the shallow aquifers is brine that is produced with crude oil in the East Poplar oil field study area. Brine contamination has not only affected the water quality from privately owned wells in and near the East Poplar oil field, but also the city of Poplar’s public water-supply wells. Three water-quality types characterize water in the shallow aquifers; a fourth water-quality type in the study area characterizes the brine. Type 1 is uncontaminated water that is suitable for most domestic purposes and typically contains sodium bicarbonate and sodium/magnesium sulfate as the dominant ions. Type 2 is moderately contaminated water that is suitable for some domestic purposes, but not used for drinking water, and typically contains sodium and chloride as the dominant ions. Type 3 is considerably contaminated water that is unsuitable for any domestic purpose and always contains sodium and chloride as the dominant ions. Type 3 quality of water in the shallow aquifers is similar to Type 4, which is the brine that is produced with crude oil. Electromagnetic apparent conductivity data were collected in the 106 square-mile area and used to determine extent of brine contamination. These data were collected and interpreted in conjunction with water-quality data collected through 2009 to delineate brine plumes in the shallow aquifers. Monitoring wells subsequently were drilled in some areas without existing water wells to confirm most of the delineated brine plumes; however, several possible plumes do not contain either existing water wells or monitoring wells. Analysis of groundwater samples from wells confirms the presence of 12.1 square miles of contamination, as much as 1.7 square miles of which is considerably contaminated (Type 3). Electromagnetic apparent conductivity data in areas with no wells delineate an additional 5.8 square miles of possible contamination, 2.1 square miles of which might be considerably contaminated (Type 3). Storage-tank facilities, oil wells, brine-injection wells, pipelines, and pits are likely sources of brine in the study area. It is not possible to identify discrete oil-related features as likely sources of brine plumes because several features commonly are co-located. During the latter half of the twentieth century, many brine plumes migrated beyond the immediate source area and likely mix together in modern and ancestral Poplar River valley subareas.

Geochemistry of shallow ground water in coastal plain environments in the southeastern United States: Implications for aquifer susceptibility

USGS Publications Warehouse

Tesoriero, A.J.; Spruill, T.B.; Eimers, J.L.

2004-01-01

Ground-water chemistry data from coastal plain environments have been examined to determine the geochemical conditions and processes that occur in these areas and assess their implications for aquifer susceptibility. Two distinct geochemical environments were studied to represent a range of conditions: an inner coastal plain setting having more well-drained soils and lower organic carbon (C) content and an outer coastal plain environment that has more poorly drained soils and high organic C content. Higher concentrations of most major ions and dissolved inorganic and organic C in the outer coastal plain setting indicate a greater degree of mineral dissolution and organic matter oxidation. Accordingly, outer coastal plain waters are more reducing than inner coastal plain waters. Low dissolved oxygen (O2) and nitrate (NO 3-) concentrations and high iron (Fe) concentrations indicate that ferric iron (Fe (III)) is an important electron acceptor in this setting, while dissolved O2 is the most common terminal electron acceptor in the inner coastal plain setting. The presence of a wide range of redox conditions in the shallow aquifer system examined here underscores the importance of providing a detailed geochemical characterization of ground water when assessing the intrinsic susceptibility of coastal plain settings. The greater prevalence of aerobic conditions in the inner coastal plain setting makes this region more susceptible to contamination by constituents that are more stable under these conditions and is consistent with the significantly (p<0.05) higher concentrations of NO3- found in this setting. Herbicides and their transformation products were frequently detected (36% of wells sampled), however concentrations were typically low (<0.1 ??g/L). Shallow water table depths often found in coastal plain settings may result in an increased risk of the detection of pesticides (e.g., alachlor) that degrade rapidly in the unsaturated zone.

Hydrogeology and hydrochemistry of a shallow alluvial aquifer, western Saudi Arabia

NASA Astrophysics Data System (ADS)

Al-Shaibani, Abdulaziz M.

2008-02-01

A hydrogeological and hydrochemical study was conducted on a shallow alluvial aquifer, Wadi Wajj, in western Saudi Arabia to assess the influence of protection measures on groundwater quality. The hydrochemistry was assessed up-gradient and down-gradient from potential contamination sources in the main city in dry and wet seasons prior to and after the installation of major drainage and wastewater facilities. Wadi Wajj is an unconfined aquifer where water is stored and transmitted through fractured and weathered bedrock and the overlying alluvial sediments. Natural recharge to the aquifer is about 5% of rainfall-runoff. Hydrochemistry of the aquifer shows temporal and seasonal changes as influenced by protection measures and rainfall runoff. Both groundwater and runoff showed similar chemical signature, which is mostly of chloride-sulfate-bicarbonate and sodium-calcium type. Groundwater downstream of the city, though of poorer quality than upstream, showed significant improvement after the installation of a concrete runoff tunnel and a wastewater treatment plant. Concentrations of many of the groundwater quality indicators (e.g., TDS, coliform bacteria, and nitrate) exceed US Environmental Protection Agency drinking-water standards. Heavy metal content is, however, within allowable limits by local and international standards. The chemical analyses also suggest the strong influence of stream runoff and sewage water on the groundwater quality.

Near-surface mapping using SH-wave and P-wave seismic land-streamer data acquisition in Illinois, U.S

USGS Publications Warehouse

Pugin, Andre J.M.; Larson, T.H.; Sargent, S.L.; McBride, J.H.; Bexfield, C.E.

2004-01-01

SH-wave and P-wave high-resolution seismic reflection combined with land-streamer technology provide 3D regional maps of geologic formations that can be associated with aquifers and aquitards. Examples for three study areas are considered to demonstrate this. In these areas, reflection profiling detected near-surface faulting and mapped a buried glacial valley and its aquifers in two settings. The resulting seismic data can be used directly to constrain hydrogeologic modeling of shallow aquifers.

Ground-water availability in part of the Borough of Carroll Valley, Adams County, Pennsylvania, and the establishment of a drought-monitor well

USGS Publications Warehouse

Low, Dennis J.; Conger, Randall W.

2002-01-01

Continued population growth in the Borough of Carroll Valley (Borough) coupled with the drought of 2001 have increased the demand for ground water in the Borough. This demand has led Borough officials to undertake an effort to evaluate the capability of the crystalline-bedrock aquifers to meet future, projected growth and to establish a drought-monitor well within and for the use of the Borough. As part of this effort, this report summarizes ground-water data available from selected sections within the Borough and provides geohydrologic information needed to evaluate ground-water availability and recharge sources within part of the Borough. The availability of ground water in the Borough is limited by the physical characteristics of the underlying bedrock, and its upland topographic setting. The crystalline rocks (metabasalt, metarhyolite, greenstone schist) that underlie most of the study area are among the lowest yielding aquifers in the Commonwealth. More than 25 percent of the wells drilled in the metabasalt, the largest bedrock aquifer in the study area, have driller reported yields less than 1.25 gallons per minute. Driller reports indicate also that water-producing zones are shallow and few in number. In general, 50 percent of the water-producing zones reported by drillers are penetrated at depths of 200 feet or less and 90 percent at depths of 370 feet or less. Borehole geophysical data indicate that most of the water-producing zones are at lithologic contacts, but such contacts are penetrated infrequently and commonly do not intersect areas of ground-water recharge. Single-well aquifer tests and slug tests indicate that the bedrock aquifers also do not readily transmit large amounts of water. The median hydraulic conductivity and transmissivity of the bedrock aquifers are 0.01 foot per dayand 2.75 feet squared per day, respectively. The crystalline and siliciclastic (Weverton and Loudoun Formations) bedrock aquifers are moderately to highly resistant to weathering, resulting in topographic highs coupled with steep, narrow valleys. This rugged topography results in extensive surface runoff, which limits infiltration and hence recharge to the shallow and deep ground-water systems. Streams that flow through the study area generally are small and ephemeral. Where perennial, the streams represent areas of ground-water discharge. Thickness of the overlying mantle (regolith or depth to bedrock) varies from 0 to more than 65 feet over short distances. In general, a thick regolith will store and transmit large quantities of water to the underlying bedrock aquifers. In the study area, however, there is no correlation between thick regolith and greater reported yields. Thus, it appears that the hydraulic connection between water-bearing fractures at depth and ground water stored in the regolith is poor, which further limits ground-water availability. Recharge to the bedrock aquifers from the approximately 46 inches of annual precipitation aver-ages about 13 inches per year, or 975 gallons per day per acre. During drought years, however, this recharge rate may average only 9 inches per year [675 gallons per day per acre]. Decreased recharge to the bedrock aquifers results in declining water levels and possibly dry wells, as well as reduced flows to streams and other surface-water bodies. Although the consumptive use of ground water by homeowners is minor (about 14 percent), the pumping of a well will change the natural flow paths of ground water and reduce the amount of water stored (at least temporarily) in the bedrock aquifers.

Major-ion and selected trace-metal chemistry of the Biscayne Aquifer, Southeast Florida

USGS Publications Warehouse

Radell, M.J.; Katz, B.G.

1991-01-01

The major-ion and selected trace-metal chemistry of the Biscayne aquifer was characterized as part of the Florida Ground-Water Quality Monitoring Network Program, a multiagency cooperative effort concerned with delineating baseline water quality for major aquifer systems in the State. The Biscayne aquifer is unconfined and serves as the sole source of drinking water for more than 3 million people in southeast Florida. The Biscayne aquifer consists of highly permeable interbedded limestone and sandstone of Pleistocene and Pliocene age underlying most of Dade and Broward Counties and parts of Palm Beach and Monroe Counties. The high permeability is largely caused by extensive carbonate dissolution. Water sampled from 189 wells tapping the Biscayne aquifer was predominantly a calcium bicarbonate type with some mixed types occurring in coastal areas and near major canals. Major - ion is areally uniform throughout the aquifer. According to nonparametric statistical tests of major ions and dissolved solids, the concentrations of calcium, sodium, bicarbonate, and dissolved solids increased significantly with well depth ( 0.05 significance level ), probably a result of less circulation at depth. Potassium and nitrate concentrations decreased significantly with depth. Although the source of recharge to the aquifer varies seasonally, there was no statistical difference in the concentration of major ions in pared water samples from 27 shallow wells collected during wet and dry seasons. Median concentrations for barium, chromium, copper, lead, and manganese were below maximum or secondary maximum contaminant levels set by the US Environmental Protection Agency. The median iron concentration only slightly exceeded the secondary maximum contaminant level. The concentration of barium was significantly related (0.05 significance level) to calcium and bicarbonate concentration. No distinct areal pattern or vertical distribution of the selected trace metals was evident in water from the Biscayne aquifer. Sources for trace metals found in water from the Biscayne aquifer may include local contamination, well-construction techniques, canal - aquifer interactions, and natural occurrence in area soils and rock.

Putting aquifers into atmospheric simulation models: An example from the Mill Creek Watershed, Northeastern Kansas

USGS Publications Warehouse

York, J.P.; Person, M.; Gutowski, W.J.; Winter, T.C.

2002-01-01

Aquifer-atmosphere interactions can be important in regions where the water table is shallow (<2 m). A shallow water table provides moisture for the soil and vegetation and thus acts as a source term for evapotranspiration to the atmosphere. A coupled aquifer-land surface-atmosphere model has been developed to study aquifer-atmosphere interactions in watersheds, on decadal timescales. A single column vertically discretized atmospheric model is linked to a distributed soil-vegetation-aquifer model. This physically based model was able to reproduce monthly and yearly trends in precipitation, stream discharge, and evapotranspiration, for a catchment in northeastern Kansas. However, the calculated soil moisture tended to drop to levels lower than were observed in drier years. The evapotranspiration varies spatially and seasonally and was highest in cells situated in topographic depressions where the water table is in the root zone. Annually, simulation results indicate that from 5-20% of groundwater supported evapotranspiration is drawn from the aquifer. The groundwater supported fraction of evapotranspiration is higher in drier years, when evapotranspiration exceeds precipitation. A long-term (40 year) simulation of extended drought conditions indicated that water table position is a function of groundwater hydrodynamics and cannot be predicted solely on the basis of topography. The response time of the aquifer to drought conditions was on the order of 200 years indicating that feedbacks between these two water reservoirs act on disparate time scales. With recent advances in the computational power of massively parallel supercomputers, it may soon become possible to incorporate physically based representations of aquifer hydrodynamics into general circulation models (GCM) land surface parameterization schemes. ?? 2002 Elsevier Science Ltd. All rights reserved.

A Microbiological Water Quality Evaluation of Ganges River Deltaic Aquifers

NASA Astrophysics Data System (ADS)

Yerby, C. J.; Gragg, S. E.; Page, J.; Leavens, J.; Bhattacharya, P.; Harrington, J.; Datta, S.

2014-12-01

Substantial natural contamination from trace elements (like arsenic) and pathogens make Ganges Deltaic aquifers an area of utmost concern. Following millions of cases of chronic arsenic poisoning from the groundwaters of the region, numerous residents are still knowingly ingesting water from shallow to intermediate accessible depth drinking water wells. Added to the calamity of arsenic is the prevalence of pathogenic bacteria in these waters. The increasing frequency of gastroenteritis signifies the need to quantify the magnitude and extensiveness of health degrading agents--bacterial pathogens (i.e. Salmonella) and non-pathogens (i.e. Enterobacteriaceae) --within the water supply in accessible Gangetic aquifers. To assess the dissolved microbiological quality in the region, present study sampling locations are along defined piezometer nests in an area in SE Asia (Bangladesh). Every nest contains samples from wells at varying depths covering shallow to deep aquifers. To date, 17 of the 76 water samples were analyzed for Salmonella, generic Escherichia coli (E. coli) and coliforms. Briefly, samples were plated in duplicate onto E. coli/Coliform petrifilm and incubated at 370C for 48 hours. Next, each sample was enriched in buffered peptone water and incubated at 370C for 18 hours. Bacterial DNA was extracted and amplified using a qPCR machine. Amplification plots were analyzed to determine presence/absence of microorganisms. All water samples (n=~76) are analyzed for Salmonella, Escherichia coli O157:H7, Listeria spp. and Shigella. Pathogen populations of PCR-positive water samples are enumerated using the agar direct plate method. Non-pathogenic bacterial indicator organisms (i.e. Enterobacteriaceae) will also be enumerated. Over the course of the experiment, we hypothesize that shallower wells will 1)have a higher pathogen prevalence and 2)harbor pathogens and nonpathogens at higher concentrations. While the 17 samples analyzed to date were negative for Salmonella, and E. coli, we anticipate subsequent sample analyses may reveal, E. coli or pathogenic (i.e. Salmonella) contamination due to livestock and anthropogenic wastes in the area. With farmers using shallow depth aquifers to irrigate crops, there is a very real threat of foodborne illness and the risk to public health is great.

Impacts of physical and chemical aquifer heterogeneity on basin-scale solute transport: Vulnerability of deep groundwater to arsenic contamination in Bangladesh

NASA Astrophysics Data System (ADS)

Michael, Holly A.; Khan, Mahfuzur R.

2016-12-01

Aquifer heterogeneity presents a primary challenge in predicting the movement of solutes in groundwater systems. The problem is particularly difficult on very large scales, across which permeability, chemical properties, and pumping rates may vary by many orders of magnitude and data are often sparse. An example is the fluvio-deltaic aquifer system of Bangladesh, where naturally-occurring arsenic (As) exists over tens of thousands of square kilometers in shallow groundwater. Millions of people in As-affected regions rely on deep (≥150 m) groundwater as a safe source of drinking water. The sustainability of this resource has been evaluated with models using effective properties appropriate for a basin-scale contamination problem, but the extent to which preferential flow affects the timescale of downward migration of As-contaminated shallow groundwater is unknown. Here we embed detailed, heterogeneous representations of hydraulic conductivity (K), pumping rates, and sorptive properties (Kd) within a basin-scale numerical groundwater flow and solute transport model to evaluate their effects on vulnerability and deviations from simulations with homogeneous representations in two areas with different flow systems. Advective particle tracking shows that heterogeneity in K does not affect average travel times from shallow zones to 150 m depth, but the travel times of the fastest 10% of particles decreases by a factor of ∼2. Pumping distributions do not strongly affect travel times if irrigation remains shallow, but increases in the deep pumping rate substantially reduce travel times. Simulation of advective-dispersive transport with sorption shows that deep groundwater is protected from contamination over a sustainable timeframe (>1000 y) if the spatial distribution of Kd is uniform. However, if only low-K sediments sorb As, 30% of the aquifer is not protected. Results indicate that sustainable management strategies in the Bengal Basin should consider impacts of both physical and chemical heterogeneity, as well as their correlation. These insights from Bangladesh show that preferential flow strongly influences breakthrough of both conservative and reactive solutes even at large spatial scales, with implications for predicting water supply vulnerability in contaminated heterogeneous aquifers worldwide.

Quaternary stratigraphy, sediment characteristics and geochemistry of arsenic-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in central Bangladesh.

PubMed

Shamsudduha, M; Uddin, A; Saunders, J A; Lee, M-K

2008-07-29

This study focuses on the Quaternary stratigraphy, sediment composition, mineralogy, and geochemistry of arsenic (As)-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in the central Bangladesh. Arsenic concentrations in 85 tubewells in Manikganj area, 70 km northwest of Dhaka City, range from 0.25 microg/L to 191 microg/L with a mean concentration of 33 microg/L. Groundwater is mainly Ca-HCO(3) type with high concentrations of dissolved As, Fe, and Mn, but low level of SO(4). The uppermost aquifer occurs between 10 m and 80 m below the surface that has a mean arsenic concentration of 35 microg/L. Deeper aquifer (>100 m depth) has a mean arsenic concentration of 18 microg/L. Sediments in the upper aquifer are mostly gray to dark-gray, whereas sediments in the deep aquifer are mostly yellowing-gray to brown. Quartz, feldspar, mica, hornblende, garnet, kyanite, tourmaline, magnetite, ilmenite are the major minerals in sediments from both aquifers. Biotite and potassium feldspar are dominant in shallow aquifer, although plagioclase feldspar and garnet are abundant in deep aquifer sediments. Sediment composition suggests a mixed provenance with sediment supplies from both orogenic belts and cratons. High arsenic concentrations in sediments are found within the upper 50 m in drilled core samples. Statistical analysis shows that As, Fe, Mn, Ca, and P are strongly correlated in sediments. Concentrations of Cd, Cu, Ni, Zn, and Bi also show strong correlations with arsenic in the Manikganj sediment cores. Authigenic goethite concretions, possibly formed by bacteria, are found in the shallow sediments, which contain arsenic of a concentration as high as 8.8 mg/kg. High arsenic concentrations in aquifers are associated with fine-grained sediments that were derived mostly from the recycled orogens and relatively rapidly deposited mainly by meandering channels during the Early to Middle Holocene rising sea-level conditions.

Chemical and microbiological monitoring of a sole-source aquifer intended for artificial recharge, Nassau County, New York

USGS Publications Warehouse

Katz, Brian G.; Mallard, Gail E.

1980-01-01

In late 1980, approximately 4 million gallons per day of highly treated wastewater will be used to recharge the groundwater reservoir in central Nassau County through a system of 10 recharge basins and 5 shallow injection wells. To evaluate the impact of large-scale recharge with reclaimed water on groundwater quality, the U.S. Geological Survey has collected hydrologic and water-quality data from a 1-square-mile area around the recharge site to provide a basis for future comparison. Extensive chemical and microbiological analyses are being made on samples from 48 wells screened in the upper glacial (water-table) aquifer and the upper part of the underlying Magothy (public-supply) aquifer. Preliminary results indicate that water from the upper glacial aquifer contains significant concentrations of nitrate and low-molecular-weight chlorinated hydrocarbons and detectable concentrations of organochlorine insecticides and polychlorinated biphenyls. At present, no fecal contamination is evident in either aquifer in the area studied. In the few samples containing fecal indicator bacteria, the numbers were low. Nonpoint sources provide significant loads of organic and inorganic compounds; major sources include cesspool and septic-tank effluent, cesspool and septic-tank cleaners and other over-the-counter domestic organic solvents, fertilizers, insecticides for termite and other pest control, and stormwater runoff to recharge basins. The water-table aquifer is composed mainly of stratified, well-sorted sand and gravel and, as a result, is highly permeable. In the 1-square-mile area studied, some contaminants seem to have traveled 200 feet downward to the bottom of the water-table aquifer and into the upper part of the public-supply aquifer. (USGS)

Occurrence of trihalomethanes in the nation's ground water and drinking-water supply wells, 1985-2002

USGS Publications Warehouse

Schaap, Bryan D.; Zogorski, John S.

2006-01-01

This report describes the occurrence of trihalomethanes (THMs) in the Nation's ground water and drinking-water supply wells based on analysis of 5,642 samples of untreated ground water and source water collected or compiled during 1985-2002 by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. THMs are a group of volatile organic compounds (VOCs) with natural and anthropogenic sources that are of interest because they are associated with acute and chronic health problems in humans. THMs occur in water primarily from chlorination and are classified as disinfection by-products. In this report, the four THMs are discussed in the order of chloroform, bromodichloromethane, dibromochloromethane, and then bromoform; this sequence corresponds to largest to smallest chlorine content and smallest to largest bromine content. Four trihalomethanes were detected in less than 20 percent of samples from studies of (1) aquifers, (2) shallow ground water in agricultural areas, (3) shallow ground water in urban areas, (4) domestic wells, and (5) public wells. Detection frequencies for individual THMs in the five studies ranged from zero for shallow ground water in agricultural areas to 19.5 percent for shallow ground water in urban areas. None of the samples from aquifer studies, domestic wells, or public wells had total THM concentrations (the sum of the concentrations of chloroform, bromodichloromethane, dibromochloromethane, and bromoform) greater than or equal to the U.S. Environmental Protection Agency Maximum Contaminant Level of 80 micrograms per liter (?g/L). Comparisons of results among studies of aquifers, shallow ground water in agricultural areas, and shallow ground water in urban areas were used to describe the occurrence of the four THMs in ground water for three different land-use settings-mixed, agricultural, and urban, respectively. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 7.9 percent of the samples from aquifer studies, 2.2 percent of the samples from shallow ground water in agricultural areas, and 19.5 percent of the samples from shallow ground water in urban areas. In general, detection frequencies and concentrations of the four THMs were greater in shallow ground water in urban areas compared to aquifer studies and to shallow ground water in agricultural areas. For all three of these studies, the most common two-THM mixture at the 0.2-?g/L assessment level was chloroform-bromodichloromethane, and this was the only two-THM mixture found in samples of shallow ground water in agricultural areas. Comparisons of results between studies of domestic wells and public wells were used to describe the occurrence of the four THMs in two different supplies of ground water used for drinking water. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 5.2 percent of the domestic well samples and in 14.7 percent of the public well samples. In general, detection frequencies and THM concentrations were greater in samples from public wells than from domestic wells. At the 0.2-?g/L assessment level, the six possible two-THM mixtures occurred about six times more frequently in samples from public wells than from domestic wells. One of the most common two-THM mixtures in samples from domestic and public wells was bromodichloromethane-dibromochloromethane. Detection frequency is associated with the chlorine content of the THM compound. In general, for each of the five studies, as the chlorine content of the THM compound decreased, the detection frequency at the 0.2-?g/L assessment level also decreased. The exception was the study of public wells in which the detection frequency of the THMs decreased in the following order: chloroform, bromoform, dibromochloromethane, and bromodichloromethane. At the 0.2-?g/L assessment level, the median concentration for one or more of the four THMs ranged from 0.3 ?g/L (shallow ground water in agricultural a

Investigation of the potential source area, contamination pathway, and probable release history of chlorinated-solvent-contaminated groundwater at the Capital City Plume Site, Montgomery, Alabama, 2008-2010

USGS Publications Warehouse

Landmeyer, James E.; Miller, Scott; Campbell, Bruce G.; Vroblesky, Don A.; Gill, Amy C.; Clark, Athena P.

2011-01-01

Detection of the organic solvent perchloroethylene (PCE) in a shallow public-supply well in 1991 and exposure of workers in 1993 to solvent vapors during excavation activities to depths near the water table provided evidence that the shallow aquifer beneath the capital city of Montgomery, Alabama, was contaminated. Investigations conducted from 1993 to 1999 by State and Federal agencies confirmed the detection of PCE in the shallow aquifer, as well as the detection of the organic solvent trichloroethylene (TCE) and various inorganic compounds, but the source of the groundwater contamination was not determined. In May 2000 the U.S. Environmental Protection Agency proposed that the site, called the Capital City Plume (CCP) Site, be a candidate for the National Priorities List. Between 2000 and 2007, numerous site-investigation activities also did not determine the source of the groundwater contamination. In 2008, additional assessments were conducted at the CCP Site to investigate the potential source area, contamination pathway, and the probable release history of the chlorinated-solvent-contaminated groundwater. The assessments included the collection of (1) pore water in 2008 from the hyporheic zone of a creek using passive-diffusion bag samplers; (2) tissue samples in 2008 and 2009 from trees growing in areas of downtown Montgomery characterized by groundwater contamination and from trees growing in riparian zones along the Alabama River and Cypress Creek; and (3) groundwater samples in 2009 and 2010. The data collected were used to investigate the potential source area of contaminants detected in groundwater, the pathway of groundwater contamination, and constraints on the probable contaminant-release history. The data collected between 2008 and 2010 indicate that the PCE and TCE contamination of the shallow aquifer beneath the CCP Site most likely resulted from the past use and disposal of industrial wastewater from printing operations containing chlorinated solvents into the sanitary sewer and (or) stormwater systems of Montgomery. Moreover, chlorinated-solvent use and disposal occurred at least between the 1940s and 1970s at several locations occupied by printing operations. The data also indicate that PCE and TCE contamination continues to occur in the shallow subsurface near potential release areas and that PCE and TCE have been transported to the intermediate part of the shallow aquifer.

Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface ground water: background, base cases, shallow reservoirs, short-term gas and water transport

EPA Pesticide Factsheets

Researchers examined gas and water transport between a deep tight shale gas reservoir and a shallow overlying aquifer in the two years following hydraulic fracturing, assuming a pre-existing connecting pathway.

Pre- and post-reservoir ground-water conditions and assessment of artificial recharge at Sand Hollow, Washington County, Utah, 1995-2005

USGS Publications Warehouse

Heilweil, Victor M.; Susong, David D.; Gardner, Philip M.; Watt, Dennis E.

2005-01-01

Sand Hollow, Utah, is the site of a surface-water reservoir completed in March 2002, which is being operated by the Washington County Water Conservancy District primarily as an aquifer storage and recovery project. The reservoir is an off-channel facility receiving water from the Virgin River, diverted near the town of Virgin, Utah. It is being operated conjunctively, providing both surface-water storage and artificial recharge to the underlying Navajo aquifer. The U.S. Geological Survey and the Bureau of Reclamation conducted a study to document baseline ground-water conditions at Sand Hollow prior to the operation of the reservoir and to evaluate changes in ground-water conditions caused by the reservoir.Pre-reservoir age dating using tritium/helium, chlorofluorocarbons, and carbon-14 shows that shallow ground water in the Navajo Sandstone in some areas of Sand Hollow entered the aquifer from 2 to 25 years before sample collection. Ground water in low-recharge areas and deeper within the aquifer may have entered the aquifer more than 8,000 years ago. Ground-water levels in the immediate vicinity of Sand Hollow Reservoir have risen by as much as 80 feet since initial filling began in March 2002. In 2005, ground water was moving laterally away from the reservoir in all directions, whereas the pre-reservoir direction of ground-water flow was predominantly toward the north.Tracers, or attributes, of artificial recharge include higher specific conductance, higher dissolved-solids concentrations, higher chloride-to-bromide ratios, more-depleted stable isotopes (2H and 18O), and higher total-dissolved gas pressures. These tracers have been detected at observation and production wells close to the reservoir. About 15,000 tons of naturally occurring salts that previously accumulated in the vadose zone beneath the reservoir are being flushed into the aquifer. Except for the shallowest parts of the aquifer, this is generally not affecting water quality, largely because of the large saturated thickness of the Navajo aquifer. Since the initial filling of Sand Hollow Reservoir, arsenic concentrations have risen to exceed U.S. Environmental Protection Agency standards only in some shallow observation wells. These increases in arsenic concentration are likely caused by increasing pH associated with artificial recharge beneath the reservoir, rather than flushing of previously accumulated salts in the vadose zone. There has been no trend of increasing arsenic concentration in deeper production wells.Estimated evaporation rates for Sand Hollow Reservoir, calculated by the Jensen-Haise method with data from the Sand Hollow weather station, range from about 55 to 61 inches per year and result in a total evaporative loss of about 6,000 acre-feet of water from March 2002 to September 2004. Rates of artificial recharge of ground water beneath Sand Hollow Reservoir have ranged from about 0.02 to 0.44 feet per day, with an average rate excluding the initial 3-month wetting period of about 0.06 feet per day. A total of about 28,000 acre-feet of recharge to the underlying Navajo aquifer occurred from March 2002 to September 2004.

Redox reaction rates in shallow aquifers: Implications for nitrate transport in groundwater and streams

USGS Publications Warehouse

Tesoriero, Anthony J.

2012-01-01

Groundwater age and water chemistry data along flow paths from recharge areas to streams were used to evaluate the trends and transformations of agricultural chemicals. Results from this analysis indicate that median nitrate recharge concentrations in these agricultural areas have increased markedly over the last 50 years from 4 mg N/L in samples collected prior to 1983 to 7.5 mg N/L in samples collected since 1983. The effect that nitrate accumulation in shallow aquifers will have on drinking water quality and stream ecosystems is dependent on the rate of redox reactions along flow paths and on the age distribution of nitrate discharging to supply wells and streams.

Occurrence and Distribution of Iron, Manganese, and Selected Trace Elements in Ground Water in the Glacial Aquifer System of the Northern United States

USGS Publications Warehouse

Groschen, George E.; Arnold, Terri L.; Morrow, William S.; Warner, Kelly L.

2009-01-01

Dissolved trace elements, including iron and manganese, are often an important factor in use of ground water for drinking-water supplies in the glacial aquifer system of the United States. The glacial aquifer system underlies most of New England, extends through the Midwest, and underlies portions of the Pacific Northwest and Alaska. Concentrations of dissolved trace elements in ground water can vary over several orders of magnitude across local well networks as well as across regions of the United States. Characterization of this variability is a step toward a regional screening-level assessment of potential human-health implications. Ground-water sampling, from 1991 through 2003, of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey determined trace element concentrations in water from 847 wells in the glacial aquifer system. Dissolved iron and manganese concentrations were analyzed in those well samples and in water from an additional 743 NAWQA land-use and major-aquifer survey wells. The samples are from monitoring and water-supply wells. Concentrations of antimony, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, selenium, strontium, thallium, uranium, and zinc vary as much within NAWQA study units (local scale; ranging in size from a few thousand to tens of thousands of square miles) as over the entire glacial aquifer system. Patterns of trace element concentrations in glacial aquifer system ground water were examined by using techniques suitable for a dataset with zero to 80 percent of analytical results reported as below detection. During the period of sampling, the analytical techniques changed, which generally improved the analytical sensitivity. Multiple reporting limits complicated the comparison of detections and concentrations. Regression on Order Statistics was used to model probability distributions and estimate the medians and other quantiles of the trace element concentrations. Strontium and barium were the most frequently detected and usually were present in the highest concentrations. Iron and manganese were the next most commonly detected and next highest in concentrations. Iron concentrations were the most variable with respect to the range of variations (both within local networks and aquifer-wide) and with respect to the disparity between magnitude of concentrations (detections) and the frequency of samples below reporting limits (nondetections). Antimony, beryllium, cadmium, silver, and thallium were detected too infrequently for substantial interpretation of their occurrence or distributions or potential human-health implications. For those elements that were more frequently detected, there are some geographic patterns in their occurrence that primarily reflect climate effects. The highest concentrations of several elements were found in the West-Central glacial framework area (High Plains and northern Plains areas). There are few important patterns for any element in relation to land use, well type, or network type. Shallow land-use (monitor) wells had iron concentrations generally lower than the glacial aquifer system wells overall and much lower than major-aquifer survey wells, which comprise mostly private- and public-supply wells. Unlike those for iron, concentration patterns for manganese were similar among shallow land-use wells and major-aquifer survey wells. An apparent relation between low pH and relatively low concentrations of many elements, except lead, may be more indicative of the relatively low dissolved-solids content in wells in the Northeastern United States that comprise the majority of low pH wells, than of a pH dependent pattern. Iron and manganese have higher concentrations and larger ranges of concentrations especially under more reducing conditions. Dissolved oxygen and well depth were related to iron and manganese concentrations. Redox conditions also affect several trace elements such

Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA

NASA Astrophysics Data System (ADS)

Harte, Philip T.; Smith, Thor E.; Williams, John H.; Degnan, James R.

2012-05-01

In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment.

Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA

USGS Publications Warehouse

Harte, Philip T.; Smith, Thor E.; Williams, John H.; Degnan, James R.

2012-01-01

In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment.

Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA.

PubMed

Harte, Philip T; Smith, Thor E; Williams, John H; Degnan, James R

2012-05-01

In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment. Published by Elsevier B.V.

Ground water hydrology of the Elizabethtown area, Kentucky

USGS Publications Warehouse

Mull, D.S.; Lyverse, M.A.

1984-01-01

The principal aquifer in a 52 square mile karst area in north central Kentucky is the St. Louis Limestone of Mississippian age. Unconsolidated residuum and surficial deposits of slumped material may store water and recharge the underlying limestone aquifer. Precipitation averages 49 inches annually; 6 inches recharges ground-water reservoirs. The shallow ground-water velocity ranged from 0.30 to 1.40 feet per second. Flow net analysis indicates that about 2 million gallons of water per day flows through a 1.8 mile wide section of the aquifer. A water-level contour map indicates that the hydraulic gradient averages 40 feet per mile and that the water levels near the city supply wells have not lowered in 10 years. The effects of three faults on the ground-water flow system is shown as ponding on the upthrown side of the faults. Caliper logs suggest that shallow ground-water flow occurs in sheet-like openings within 100 feet of land surface. The openings range in height from 1 inch or less to 6 feet. A test well penetrated 5 zones of horizontal openings. The specific capacity ranged from 11.5 to 12.1 gallons per minute per foot of drawdown after 12 and 72 hours of pumping at 280 to 510 gallons per minute. Water in 28 wells and springs meets most drinking water standards and generally is a very hard calcium bicarbonate type. Heavily pumped industrial and public-supply wells tend to yield water with high values of specific conductance and sulfate. Coliform bacteria varied widely in rural wells and the city springs. Seven wells had no coliform bacteria. (USGS)

Sources and fate of high levels of ammonium in surface water and shallow groundwater of the Jianghan Plain, Central China.

PubMed

Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

2017-02-22

High levels of ammonium from anthropogenic sources threaten the quality of surface waters and groundwaters in some areas worldwide, but elevated ammonium levels of natural sources also have been identified. High levels of ammonium have been detected in both surface water and shallow groundwater of the Jianghan Plain, an alluvial plain of the Yangtze River. This study used N isotopes coupled with ancillary chemistry to identify ammonium in this region. Ammonium in the Tongshun River (up to 10.25 mg L -1 ) showed a sharp accumulation in the upstream and gradual attenuation in the downstream. The δ 15 N values of ammonium in the TSR were high and ranged narrowly from +12.5 to +15.4‰, suggesting an anthropogenic source that was septic effluent from industrial waste discharge. Sorption and nitrification were likely to respectively serve as the principal processes contributing to ammonium attenuation in different reaches of the downstream TSR. In shallow groundwater, high levels of ammonium (up to 14.10 mg L -1 ) occurred in a reducing environment. The narrow δ 15 N variation with low values (+2.3 to +4.5‰) in the lower aquifer suggested a natural source that was organic N mineralization. The δ 15 N values in the shallow aquitard exhibited a wide range from -1.8 to +9.4‰, owing to various sources. Two types of water in the shallow aquitard could be identified: (1) type-1 water with relatively longer residence time was similar to those in the aquifer where ammonium was mainly sourced from organic N mineralization; (2) type-2 water with shorter residence time was jointly affected by surface input, chemical attenuation and mineralization of organic N. The aquitard prevents prompt ammonium exchange between the surface and aquifer, and the shallower part of the aquitard provides a sufficient reaction time and an active reaction rate for ammonium removal.

Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

USGS Publications Warehouse

Toth, D.J.; Katz, B.G.

2006-01-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data-chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6) - for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge. ?? Springer-Verlag 2006.

Erratum: Mixing of shallow and deep groundwater as indicated by the chemistry and age of karstic springs

NASA Astrophysics Data System (ADS)

Toth, David J.; Katz, Brian G.

2006-09-01

Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca-HCO3 (six), Na-Cl (four), and mixed (one). The evolution of water chemistry for Ca-HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na-Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4-53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca-HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na-Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.

Palaeosol control on groundwater flow and pollutant distribution: the example of arsenic.

PubMed

McArthur, John M; Nath, Bibhash; Banerjee, Dhiraj M; Purohit, R; Grassineau, N

2011-02-15

The consumption of groundwater polluted by arsenic (As) has a severe and adverse effect on human health, particularly where, as happens in parts of SE Asia, groundwater is supplied largely from fluvial/deltaic aquifers. The lateral distribution of the As-pollution in such aquifers is heterogeneous. The cause of the heterogeneity is obscure. The location and severity of the As-pollution is therefore difficult to predict, despite the importance of such predictions to the protection of consumer health, aquifer remediation, and aquifer development. To explain the heterogeneity, we mapped As-pollution in groundwater using 659 wells across 102 km(2) of West Bengal, and logged 43 boreholes, to reveal that the distribution of As-pollution is governed by subsurface sedimentology. Across 47 km(2) of contiguous palaeo-interfluve, we found that the shallow aquifer (<70 mbgl) is unpolluted by As (<10 μg/L) because it is capped by an impermeable palaeosol of red clay (the last glacial maximum palaeosol, or LGMP, of ref 1 ) at depths between 16 and 24 mbgl. The LGMP protects the aquifer from vertical recharge that might carry As-rich water or dissolved organic matter that might drive reduction of sedimentary iron oxides and so release As to groundwater. In 55 km(2) of flanking palaeo-channels, the palaeosol is absent, so invasion of the aquifer by As and dissolved organic matter can occur, so palaeo-channel groundwater is mostly polluted by As (>50 μg/L). The role of palaeosols and, in particular, the LGMP, has been overlooked as a control on groundwater flow and pollutant movement in deltaic and coastal aquifers worldwide. Models of pollutant infiltration in such environments must include the appreciation that, where the LGMP (or other palaeosols) are present, recharge moves downward in palaeo-channel regions that are separated by palaeo-interfluvial regions where vertical recharge to underlying aquifers cannot occur and where horizontal flow occurs above the LGMP and any aquifer it caps.

Impact of climate changes during the last 5 million years on groundwater in basement aquifers.

PubMed

Aquilina, Luc; Vergnaud-Ayraud, Virginie; Les Landes, Antoine Armandine; Pauwels, Hélène; Davy, Philippe; Pételet-Giraud, Emmanuelle; Labasque, Thierry; Roques, Clément; Chatton, Eliot; Bour, Olivier; Ben Maamar, Sarah; Dufresne, Alexis; Khaska, Mahmoud; Le Gal La Salle, Corinne; Barbecot, Florent

2015-09-22

Climate change is thought to have major effects on groundwater resources. There is however a limited knowledge of the impacts of past climate changes such as warm or glacial periods on groundwater although marine or glacial fluids may have circulated in basements during these periods. Geochemical investigations of groundwater at shallow depth (80-400 m) in the Armorican basement (western France) revealed three major phases of evolution: (1) Mio-Pliocene transgressions led to marine water introduction in the whole rock porosity through density and then diffusion processes, (2) intensive and rapid recharge after the glacial maximum down to several hundred meters depths, (3) a present-day regime of groundwater circulation limited to shallow depth. This work identifies important constraints regarding the mechanisms responsible for both marine and glacial fluid migrations and their preservation within a basement. It defines the first clear time scales of these processes and thus provides a unique case for understanding the effects of climate changes on hydrogeology in basements. It reveals that glacial water is supplied in significant amounts to deep aquifers even in permafrosted zones. It also emphasizes the vulnerability of modern groundwater hydrosystems to climate change as groundwater active aquifers is restricted to shallow depths.

Experiments in water spreading at Newark, Delaware

USGS Publications Warehouse

Boggess, Durward Haye; Rima, Donald Robert

1962-01-01

Two experiments in water spreading were made at Newark, Del., to evaluate the prospects of using excess storm runoff to recharge the shallow water-table aquifer which serves the community. Water was diverted from 1 of the city's 3 production wells and released into an infiltration ditch near the municipal well field. Although slightly more than 65,000 cubic feet of water (nearly 500,000 gallons ) was spread in the infiltration ditch and allowed to seep into the subsurface, there was no indication that any appreciable amount of water reached the producing aquifer. Instead, a perched zone of saturation was created by the presence of an impermeable or slightly permeable bed above the water table. So effective is this barrier to the downward movement of water that within a period of less than 1 day, the apex of the perched zone rose about 10 feet to the level of the bottom of the infiltration ditch. As more water was added, the mound of saturation spread laterally. On the basis of these experiments, it appears that the principal aquifer at Newark, Del., would not be benefited by spreading water in shallow infiltration ditches or basins. However, the absorptive capacity of the unsaturated materials which occur at a shallow depth, is sufficient to permit the disposal of large volumes of storm runoff.

Assessing the magnitude and timing of anthropogenic warming of a shallow aquifer: example from Virginia Beach, USA

USGS Publications Warehouse

Eggleston, John R.; McCoy, Kurt J.

2015-01-01

Groundwater temperature measurements in a shallow coastal aquifer in Virginia Beach, Virginia, USA, suggest groundwater warming of +4.1 °C relative to deeper geothermal gradients. Observed warming is related to timing and depth of influence of two potential thermal drivers—atmospheric temperature increases and urbanization. Results indicate that up to 30 % of groundwater warming at the water table can be attributed to atmospheric warming while up to 70 % of warming can be attributed to urbanization. Groundwater temperature readings to 30-m depth correlate positively with percentage of impervious cover and negatively with percentage of tree canopy cover; thus, these two land-use metrics explain up to 70 % of warming at the water table. Analytical and numerical modeling results indicate that an average vertical groundwater temperature profile for the study area, constructed from repeat measurement at 11 locations over 15 months, is consistent with the timing of land-use change over the past century in Virginia Beach. The magnitude of human-induced warming at the water table (+4.1 °C) is twice the current seasonal temperature variation, indicating the potential for ecological impacts on wetlands and estuaries receiving groundwater discharge from shallow aquifers.

IMPACT OF ETHANOL ON THE NATURAL ATTENUATION OF BENZENE, TOLUENE, AND O-XYLENE IN A NORMALLY SULFATE-REDUCING AQUIFER

EPA Science Inventory

Two side-by-side field experiments were conducted in a shallow sulfate-reducing aquifer at a former service station site at Vandenberg Air Force Base, CA. On one side, we injected site groundwater amended with 1-3 mg/L benzene, toluene, and o-xylene (B, T, and o-X). On the othe...

A Geology-Based Estimate of Connate Water Salinity Distribution

DTIC Science & Technology

2014-09-01

poses serious environmental concerns if connate water is mobilized into shallow aquifers or surface water systems. Estimating the distribution of...groundwater flow and salinity transport near the Herbert Hoover Dike (HHD) surrounding Lake Okeechobee in Florida . The simulations were conducted using the...on the geologic configuration at equilibrium, and the horizontal salinity distribution is strongly linked to aquifer connectivity because

Nutrients in groundwaters of the conterminous United States, 1992-1995

USGS Publications Warehouse

Nolan, B.T.; Stoner, J.D.

2000-01-01

Results of a national water quality assessment indicate that nitrate is detected in 71% of groundwater samples, more than 13 times as often as ammonia, nitrite, organic nitrogen, and orthophosphate, based on a common detection threshold of 0.2 mg/L. Shallow groundwater (typically 5 m deep or less) beneath agricultural land has the highest median nitrate concentration (3.4 mg/L), followed by shallow groundwater beneath urban land (1.6 mg/L) and deeper groundwater in major aquifers (0.48 mg/L). Nitrate exceeds the maximum contaminant level, 10 mg/L as nitrogen, in more than 15% of groundwater samples from 4 of 33 major aquifers commonly used as a source of drinking water. Nitrate concentration in groundwater is variable and depends on interactions among several factors, including nitrogen loading, soil type, aquifer permeability, recharge rate, and climate. For a given nitrogen loading, factors that generally increase nitrate concentration in groundwater include well-drained soils, fractured bedrock, and irrigation. Factors that mitigate nitrate contamination of groundwater include poorly drained soils, greater depth to groundwater, artificial drainage systems, intervening layers of unfractured bedrock, a low rate of groundwater recharge, and anaerobic conditions in aquifers.

Relationship of Shallow Groundwater Quality to Hydraulic Fracturing Activities in Antrim and Kalkaska Counties, MI

NASA Astrophysics Data System (ADS)

Stefansky, J. N.; Robertson, W. M.; Chappaz, A.; Babos, H.; Israel, S.; Groskreutz, L. M.

2015-12-01

Hydraulic fracturing (fracking) of oil and natural gas (O&G) wells is a widely applied technology that can increase yields from tight geologic formations. However, it is unclear how fracking may impact shallow groundwater; previous research into its effects has produced conflicting results. Much of the worry over potential impacts to water quality arises from concerns about the produced water. The water produced from O&G formations is often salty, contains toxic dissolved elements, and can be radioactive. If fracking activities cause or increase connectivity between O&G formations and overlying groundwater, there may be risks to aquifers. As one part of a groundwater quality study in Antrim and Kalkaska Counties, MI, samples were collected from the unconfined glacial aquifer (3-300 m thick) and produced water from the underlying Antrim formation, a shallow (180-670 m deep) natural gas producing black shale. Groundwater samples were collected between 200 to 10,000 m distance from producing Antrim gas wells and from a range of screened intervals (15-95 m). Samples were analyzed for major constituents (e.g., Br, Cl), pH, conductivity, and dissolved oxygen (DO). The specific conductance of groundwater samples ranged from 230-1020 μS/cm; DO ranged from 0.4-100% saturation. Preliminary results show a slight inverse correlation between specific conductance and proximity to producing Antrim wells. The observed range of DO saturation in glacial aquifer groundwater appears to be related to both screened depth of the water wells and proximity to Antrim wells. During sampling, some well owners expressed concerns about the effects of fracking on groundwater quality and reported odd smells and tastes in their water after O&G drilling occurred near their homes. The results of this study and reported observations provide evidence to suggest a potential hydrogeological connection between the Antrim formation and the overlying glacial aquifer in some locations; it also raises questions about water quality in Antrim and Kalkaska counties. Further investigation is needed to address questions raised in this study. As the controversy surrounding fracking is growing and the application of this technology spreads worldwide, it is important for the questions about fracking and groundwater quality to be well addressed.

Water development for phosphate mining in a karst setting in Florida—a complex environmental problem

NASA Astrophysics Data System (ADS)

Lamoreaux, P. E.

1989-09-01

The State of Florida, U.S.A., passed legislation in the early 1970s and developed regulations applied to large withdrawals of groundwater. These regulations require strict adherence to defining the impact on surface water, shallow Surficial Aquifers, and the deeper aquifers within the Floridan Aquifer System. These regulations require the development of a Regional Impact Statement and a Consumptive Use Permit. To meet these requirements it is necessary to perform surface- and groundwater studies, extensive pumping tests and the collection of detailed monitoring and water quality data. These permits fall under the jurisdiction of the Florida Department of Environmental Regulations and are administrated under Regional Water Management districts, such as the Southwest Florida Management District. These regional district offices have a regulatory hearing board, hold public hearings that are properly advertized, and have support staffs of geologists, engineers, chemists, and biologists. The Florida Code involved required that, “The water crop, in the absence of data to the contrary, is 1,000 gallons per day per acre.” A “5—3—1 Criteria” also applies that requires that a determination be made to show that there will not be more than a 5 foot average decline in water level in the Floridan Aquifer at the boundary of a property to be developed, not more than a 3-foot decline in the Surficial Aquifer at the boundary, and no more than a 1-foot decline in the nearest water body (pond, lake, etc.). In addition, surface-water flow in streams of the area must not be decreased more than 5 percent unless a variance to the rule is obtained. The hydrogeological work required to meet these regulations is described in the following report.

Water-Table and Potentiometric-Surface Altitudes in the Upper Glacial, Magothy, and Lloyd Aquifers beneath Long Island, New York, March-April 2006

USGS Publications Warehouse

Monti, Jack; Busciolano, Ronald J.

2009-01-01

The U.S. Geological Survey (USGS), in cooperation with State and local agencies, systematically collects ground-water data at varying measurement frequencies to monitor the hydrologic situation on Long Island, New York. Each year during March and April, the USGS conducts a synoptic survey of hydrologic conditions to define the spatial distribution of the water table and potentiometric surfaces within the three main water-bearing units underlying Long Island - the upper glacial, Magothy, and Lloyd aquifers. These data and the maps constructed from them are commonly used in studies of Long Island's hydrology, and by water managers and suppliers for aquifer management and planning purposes. Water-level measurements made in 502 wells across Long Island during March-April 2006, were used to prepare the maps in this report. Measurements were made by the wetted-tape method to the nearest hundredth of a foot. Water-table and potentiometric-surface altitudes in these aquifers were contoured using these measurements. The water-table contours were interpreted using water-level data collected from 341 wells screened in the upper glacial aquifer and (or) shallow Magothy aquifer; the Magothy aquifer's potentiometric-surface contours were interpreted from measurements at 102 wells screened in the middle to deep Magothy aquifer and (or) contiguous and hydraulically connected Jameco aquifer; and the Lloyd aquifer's potentiometric-surface contours were interpreted from measurements at 59 wells screened in the Lloyd aquifer or contiguous and hydraulically connected North Shore aquifer. Many of the supply wells are in continuous operation and, therefore, were turned off for a minimum of 24 hours before measurements were made so that the water levels in the wells could recover to the level of the potentiometric head in the surrounding aquifer. Full recovery time at some of these supply wells can exceed 24 hours; therefore, water levels measured at these wells are assumed to be less accurate than those measured at observation wells, which are not pumped. In this report, all water-level altitudes are referenced to the National Geodetic Vertical Datum of 1929 (NGVD 29).

Aquifer response to stream-stage and recharge variations. II. Convolution method and applications

NASA Astrophysics Data System (ADS)

Barlow, P. M.; DeSimone, L. A.; Moench, A. F.

2000-05-01

In this second of two papers, analytical step-response functions, developed in the companion paper for several cases of transient hydraulic interaction between a fully penetrating stream and a confined, leaky, or water-table aquifer, are used in the convolution integral to calculate aquifer heads, streambank seepage rates, and bank storage that occur in response to stream-stage fluctuations and basinwide recharge or evapotranspiration. Two computer programs developed on the basis of these step-response functions and the convolution integral are applied to the analysis of hydraulic interaction of two alluvial stream-aquifer systems in the northeastern and central United States. These applications demonstrate the utility of the analytical functions and computer programs for estimating aquifer and streambank hydraulic properties, recharge rates, streambank seepage rates, and bank storage. Analysis of the water-table aquifer adjacent to the Blackstone River in Massachusetts suggests that the very shallow depth of water table and associated thin unsaturated zone at the site cause the aquifer to behave like a confined aquifer (negligible specific yield). This finding is consistent with previous studies that have shown that the effective specific yield of an unconfined aquifer approaches zero when the capillary fringe, where sediment pores are saturated by tension, extends to land surface. Under this condition, the aquifer's response is determined by elastic storage only. Estimates of horizontal and vertical hydraulic conductivity, specific yield, specific storage, and recharge for a water-table aquifer adjacent to the Cedar River in eastern Iowa, determined by the use of analytical methods, are in close agreement with those estimated by use of a more complex, multilayer numerical model of the aquifer. Streambank leakance of the semipervious streambank materials also was estimated for the site. The streambank-leakance parameter may be considered to be a general (or lumped) parameter that accounts not only for the resistance of flow at the river-aquifer boundary, but also for the effects of partial penetration of the river and other near-stream flow phenomena not included in the theoretical development of the step-response functions.

Thermal Impact of Medium Deep Borehole Thermal Energy Storage on the Shallow Subsurface

NASA Astrophysics Data System (ADS)

Welsch, Bastian; Schulte, Daniel O.; Rühaak, Wolfram; Bär, Kristian; Sass, Ingo

2017-04-01

Borehole heat exchanger arrays are a well-suited and already widely applied method for exploiting the shallow subsurface as seasonal heat storage. However, in most of the populated regions the shallow subsurface also comprises an important aquifer system used for drinking water production. Thus, the operation of shallow geothermal heat storage systems leads to a significant increase in groundwater temperatures in the proximity of the borehole heat exchanger array. The magnitude of the impact on groundwater quality and microbiology associated with this temperature rise is controversially discussed. Nevertheless, the protection of shallow groundwater resources has priority. Accordingly, water authorities often follow restrictive permission policies for building such storage systems. An alternative approach to avoid this issue is the application of medium deep borehole heat exchanger arrays instead of shallow ones. The thermal impact on shallow aquifers can be significantly reduced as heat is stored at larger depth. Moreover, it can be further diminished by the installation of a thermally insulating materials in the upper section of the borehole heat exchangers. Based on a numerical simulation study, the advantageous effects of medium deep borehole thermal energy storage are demonstrated and quantified. A finite element software is used to model the heat transport in the subsurface in 3D, while the heat transport in the borehole heat exchangers is solved analytically in 1D. For this purpose, an extended analytical solution is implemented, which also allows for the consideration of a thermally insulating borehole section.

Regional assessment of groundwater quality for drinking purpose.

PubMed

Jang, Cheng-Shin

2012-05-01

Owing to limited surface water during a long-term drought, this work attempted to locate clean and safe groundwater in the Choushui River alluvial fan of Taiwan based on drinking-water quality standards. Because aquifers contained several pollutants, multivariate indicator kriging (MVIK) was adopted to integrate the multiple pollutants in groundwater based on drinking- and raw-water quality standards and to explore spatial uncertainty. According to probabilities estimated by MVIK, safe zones were determined under four treatment conditions--no treatment; ammonium-N and iron removal; manganese and arsenic removal; and ammonium-N, iron, manganese, and arsenic removal. The analyzed results reveal that groundwater in the study area is not appropriate for drinking use without any treatments because of high ammonium-N, iron, manganese, and/or arsenic concentrations. After ammonium-N, iron, manganese, and arsenic removed, about 81.9-94.9% of total areas can extract safe groundwater for drinking. The proximal-fan, central mid-fan, southern mid-fan, and northern regions are the excellent locations to pump safe groundwater for drinking after treatment. Deep aquifers of exceeding 200 m depth have wider regions to obtain excellent groundwater than shallow aquifers do.

Improving ASR Recovery Efficiency by Partially-penetrating Wells in Brackish Aquifers

NASA Astrophysics Data System (ADS)

Chen, Y.

2015-12-01

Aquifer storage and recovery (ASR) is a proven cost-effective powerful technology for environmental protection and water resources optimization. The recovery efficiency (RE) is regarded as the key criteria for evaluating the ASR performance. In this study, a particular ASR scheme with the fully-penetrating well (FPW) for injection and the partially-penetrating well (PPW) for recovery is proposed to improve the RE for ASR schemes implemented in brackish aquifers. This design appreciates the tilting shape of the interface with underlying heavier salt water. For the FPW, recovery has to be terminated as soon as the interface toe reaches the well, while the toe can be pulled up to the PPW for recovery termination, resulting in later breakthrough of salt water into the pumping well, more recoverable water extracted from the shallow layers, and a higher RE. Key hydrogeological and operational parameters affecting the RE were investigated by numerical simulations. Results demonstrated the effectiveness and efficiency of the new ASR scheme and provided practical guidance for designing such a scheme in various hydrogeological conditions.

Shallow aquifer response to climate change scenarios in a small catchment in the Guarani Aquifer outcrop zone.

PubMed

Melo, Davi C D; Wendland, Edson

2017-05-01

Water availability restrictions are already a reality in several countries. This issue is likely to worsen due to climate change, predicted for the upcoming decades. This study aims to estimate the impacts of climate change on groundwater system in the Guarani Aquifer outcrop zone. Global Climate Models (GCM) outputs were used as inputs to a water balance model, which produced recharge estimates for the groundwater model. Recharge was estimated across different land use types considering a control period from 2004 to 2014, and a future period from 2081 to 2099. Major changes in monthly rainfall means are expected to take place in dry seasons. Most of the analysed scenarios predict increase of more than 2 ºC in monthly mean temperatures. Comparing the control and future runs, our results showed a mean recharge change among scenarios that ranged from ~-80 to ~+60%, depending on the land use type. As a result of such decrease in recharge rates, the response given by the groundwater model indicates a lowering of the water table under most scenarios.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

This document summarizes the performance of the groundwater restoration systems installed by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) at the former CCC/USDA grain storage facility in Utica, Nebraska, during the sixth year of system operation, from December 1, 2009, until November 30, 2010. In the project at Utica, the CCC/USDA is cooperating with multiple state and federal agencies to remove carbon tetrachloride contamination from a shallow aquifer underlying the town and to provide supplemental treated groundwater for use in the restoration of a nearby wetlands area. Argonne National Laboratory has assisted the CCC/USDA by providingmore » technical oversight for the aquifer restoration effort and facilities during this review period. This document presents overviews of the aquifer restoration facilities (Section 2) and system operations (Section 3), then describes groundwater production results (Section 4), groundwater treatment results (Section 5), and associated groundwater monitoring, system modifications, and costs during the review period (Section 6). Section 7 summarizes the present year of operation. Performance prior to December 1, 2009, has been reviewed previously (Argonne 2005, 2006, 2008, 2009a, 2010).« less

Multiple isotopes (O, C, Li, Sr) as tracers of CO2 and brine leakage from CO2-enhanced oil recovery activities in Permian Basin, Texas, USA

NASA Astrophysics Data System (ADS)

Phan, T. T.; Sharma, S.; Gardiner, J. B.; Thomas, R. B.; Stuckman, M.; Spaulding, R.; Lopano, C. L.; Hakala, A.

2017-12-01

Potential CO2 and brine migration or leakage into shallow groundwater is a critical issue associated with CO2 injection at both enhanced oil recovery (EOR) and carbon sequestration sites. The effectiveness of multiple isotope systems (δ18OH2O, δ13C, δ7Li, 87Sr/86Sr) in monitoring CO2 and brine leakage at a CO2-EOR site located within the Permian basin (Seminole, Texas, USA) was studied. Water samples collected from an oil producing formation (San Andres), a deep groundwater formation (Santa Rosa), and a shallow groundwater aquifer (Ogallala) over a four-year period were analyzed for elemental and isotopic compositions. The absence of any change in δ18OH2O or δ13CDIC values of water in the overlying Ogallala aquifer after CO2 injection indicates that injected CO2 did not leak into this aquifer. The range of Ogallala water δ7Li (13-17‰) overlaps the San Andres water δ7Li (13-15‰) whereas 87Sr/86Sr of Ogallala (0.70792±0.00005) significantly differs from San Andres water (0.70865±0.00003). This observation demonstrates that Sr isotopes are much more sensitive than Li isotopes in tracking brine leakage into shallow groundwater at the studied site. In contrast, deep groundwater δ7Li (21-25‰) is isotopically distinct from San Andres produced water; thus, monitoring this intermitted formation water can provide an early indication of CO2 injection-induced brine migration from the underlying oil producing formation. During water alternating with gas (WAG) operations, a significant shift towards more positive δ13CDIC values was observed in the produced water from several of the San Andres formation wells. The carbon isotope trend suggests that the 13C enriched injected CO2 and formation carbonates became the primary sources of dissolved inorganic carbon in the area surrounding the injection wells. Moreover, one-way ANOVA statistical analysis shows that the differences in δ7Li (F(1,16) = 2.09, p = 0.17) and 87Sr/86Sr (F(1,18) = 4.47, p = 0.05) values of shallow groundwater collected before and during the WAG period are not statistically significant. The results to date suggest that the water chemistry of shallow groundwater has not been influenced by the CO2 injection activities. The efficacy of each isotope system as a monitoring tool will be evaluated and discussed using a Bayesian mixing model.

Biofilm development in a hotspot of mixing between shallow and deep groundwater in a fractured aquifer: field evidence from joint flow, chemical and microbiological characterization

NASA Astrophysics Data System (ADS)

Bochet, Olivier; Le Borgne, Tanguy; Pédrot, Mathieu; Labasque, Thierry; Lavenant, Nicolas; Petton, Christophe; Dufresne, Alexis; Ben Maamar, Sarah; Chatton, Eliot; De la Bernardie, Jérôme; Aquilina, Luc

2015-04-01

Biofilm development in a hotspot of mixing between shallow and deep groundwater in a fractured aquifer: field evidence from joint flow, chemical and microbiological characterization Olivier Bochet1, Tanguy Le Borgne1, Mathieu Pédrot1, Thierry Labasque1, Nicolas Lavenant1, Christophe Petton1, Alexis Dufresne2,Sarah Ben Maamar1-2, Eliot Chatton1, Jérôme de la Bernardie1, Luc Aquilina1 1: Géosciences Rennes, CNRS UMR 6118, Université de Rennes 1, Campus de Beaulieu bât 14B, Rennes, France 2: Ecobio, CNRS UMR 6553, Université de Rennes 1, Campus de Beaulieu, bât 14, Rennes, France Biofilms play a major role in controlling the fluxes and reactivity of chemical species transported in hydrological systems. Their development can have either positive impacts on groundwater quality (e.g. attenuation of contaminants under natural or stimulated conditions), or possible negative effects on subsurface operations (e.g. bio-clogging of geothermal dipoles or artificial recharge systems). Micro-organisms require both electron donors and electron acceptors for cellular growth, proliferation and maintenance of their metabolic functions. The mechanisms controlling these reactions derive from the interactions occurring at the micro-scale that depend on mineral compositions, the biota of subsurface environment, but also fluid mixing, which determines the local concentrations of nutriments, electron donors and electron acceptors. Hence, mixing zones between oxygen and nutriment rich shallow groundwater and mineralized deep groundwater are often considered as potential hotspots of microbial activity, although relatively few field data document flow distributions, transport properties, chemical gradients and micro-organisms distributions across these mixing interfaces. Here we investigate the origin of a localized biofilm development observed in the fractured granite aquifer at the Ploemeur observatory (H+ network hplus.ore.fr).This biofilm composed of ferro-oxidizing bacteria is observed in an 130m deep artesian well. Borehole video logs show an important colonization of the well by the biofilm in the shallower part (0 to 60m), while it is inexistent in the deeper part (60 to 130m). As flow is localized in a few deep and shallow fractures, we presume that the spatial distribution of biofilm is controlled by mixing between shallow and deep groundwater. To verify this hypothesis we conducted a field campaign with joint characterization of the flow and chemical composition of water flowing from the different fractures, as well as the microbiological composition of the biofilm at different depth, using pyrosequencing techniques. We will discuss in this presentation the results of this interdisciplinary dataset and their implications for the occurrence of hotspots of microbiological activity in the subsurface.

Effects of dissolved CO2 on Shallow Freshwater Microbial Communities simulating a CO2 Leakage Scenario

NASA Astrophysics Data System (ADS)

Gulliver, D. M.; Lowry, G. V.; Gregory, K.

2013-12-01

Geological carbon sequestration is likely to be part of a comprehensive strategy to minimize the atmospheric release of greenhouse gasses, establishing a concern of sequestered CO2 leakage into overlying potable aquifers. Leaking CO2 may affect existing biogeochemical processes and therefore water quality. There is a critical need to understand the evolution of CO2 exposed microbial communities that influence the biogeochemistry in these freshwater aquifers. The evolution of microbial ecology for different CO2 exposure concentrations was investigated using fluid-slurry samples obtained from a shallow freshwater aquifer (55 m depth, 0.5 MPa, 22 °C, Escatawpa, MS). The microbial community of well samples upstream and downstream of CO2 injection was characterized. In addition, batch vessel experiments were conducted with the upstream aquifer samples exposed to varying pCO2 from 0% to 100% under reservoir temperature and pressure for up to 56 days. The microbial community of the in situ experiment and the batch reactor experiment were analyzed with 16S rRNA clone libraries and qPCR. In both the in situ experiment and the batch reactor experiment, DNA concentration did not correlate with CO2 exposure. Both the in situ experiment and the batch reactors displayed a changing microbial community with increased CO2 exposure. The well water isolate, Curvibacter, appeared to be the most tolerant genus to high CO2 concentrations in the in situ experiments and to mid-CO2 concentrations in the batch reactors. In batch reactors with pCO2 concentrations higher than experienced in situ (pCO2 = 0.5 MPa), Pseudomonas appeared to be the most tolerant genus. Findings provide insight into a dynamic biogeochemical system that will alter with CO2 exposure. Adapted microbial populations will eventually give rise to the community that will impact the metal mobility and water quality. Knowledge of the surviving microbial populations will enable improved models for predicting the fate of CO2 following leakage and lead to better strategies for ensuring the quality of potable aquifer water.

Selective recharge and isotopic composition of shallow groundwater within temperate, epigenic carbonate aquifers

NASA Astrophysics Data System (ADS)

Florea, Lee J.

2013-05-01

This paper considers the variation of δ18O and δ2H (VSMOW) in precipitation and shallow groundwater from carbonate aquifers that lend insight into the source and timing of recharge within temperate, epigenic karst. The shallow groundwater collected during 2010 and 2011 at Stream Cave (SC) and Natural Bridge Caverns (NBC) represent one input to and the primary output from the Redmond Creek karst aquifer in the Cumberland Plateau of southeast Kentucky, respectively. These data are compared with the isotopic composition of concurrent samples of precipitation from the same watershed that covers some 1900 ha. Values of δ18O and δ2H at SC and NBC are statistically similar and cluster at the midpoint of the local meteoric water line. These values remain surprisingly constant despite seasonal changes in temperature regimens and discharge. Samples in 2012 from regional springs that include Redmond Creek are more depleted in the heavier isotope and similarly stable despite coming from aquifers of a range of sizes and physical characteristics. Applying a Priestly-Taylor model for daily values of potential evapotranspiration, only 43% of the 1.10 m of precipitation in the 2010-2011 dataset remains as potential recharge, primarily during cooler months with lower solar insolation. Weighting δ18O and δ2H values of precipitation by potential recharge creates a better match with the isotopic composition of shallow groundwater than by weighting by precipitation amount. The isotopic composition and deuterium excess of precipitation samples are directly and inversely proportional to temperature, respectively. Deuterium excess in this study and displays intra- and inter-annual variation that ranges from a minimum of +11.1‰ to a maximum of +29.5‰ that demonstrate the higher-than-average deuterium excess in greater Appalachia and the shifting latitude of moisture sources, including a significant winter component of re-evaporated, continental moisture.

Hydrological connectivity of perched aquifers and regional aquifers in semi-arid environments: a case study from Namibia

NASA Astrophysics Data System (ADS)

Hamutoko, J. T.; Wanke, H.

2017-12-01

Integrated isotopic and hydrological tracers along with standard hydrological data are used to understand complex dry land hydrological processes on different spatial and temporal scales. The objective of this study is to analyse the relationship between the perched aquifers and the regional aquifer using hydrochemical data and isotopic composition in the Cuvelai-Etosha Basin in Namibia. This relation between the aquifers will aid in understanding groundwater recharge processes and flow dynamics. Perched aquifers are discontinuous shallow aquifers with water level ranging from 0 to 30 meters below ground level. The regional aquifer occurs in semi-consolidated sandstone at depths between about 60 and 160 meters below ground level. Water samples were collected from both aquifers in 10 villages and were analysed for major ions and stable isotopes. The results show overlapping hydrochemistry and isotopic compositions of both aquifers in 8 villages which suggest the possibility of perched aquifer water infiltrating into the regional aquifer. In two villages the hydrochemistry and isotopic composition of the aquifers are totally different and this suggests that there is no interaction between this aquifers. Areas where perched aquifers are connected to regional aquifers maybe recharge zones. These finding have important implications for groundwater resource management.

Numerical Model of Hydraulic Fracturing Fluid Transport in the Subsurface with Pressure Transient, Density Effects, and Imbibition

NASA Astrophysics Data System (ADS)

Birdsell, D.; Rajaram, H.; Dempsey, D.; Viswanathan, H.

2014-12-01

Understanding the transport of hydraulic fracturing (HF) fluid that is injected into the deep subsurface for shale gas extraction is important to ensure that shallow drinking water aquifers are not contaminated from an environmental and public health perspective and to understand formation damage from an oil and gas production perspective. Upward pressure gradients, permeable pathways such as faults or improperly abandoned wellbores, and the density contrast of the HF fluid to the surrounding brine encourages upward HF fluid migration. In contrast, the very low shale permeability and the imbibition of water into partially-saturated shale may sequester much of the HF fluid. Using the Finite Element Heat and Mass Transfer Code (FEHM), single-phase flow and transport simulations are performed to quantify how much HF fluid is removed via the wellbore as flowback and produced water and how much reaches overlying aquifers; imbibition is calculated with a semi-analytical one-dimensional solution and treated as a sink term. The travel time for HF fluid to reach the shallow aquifers is highly dependent on the amount of water imbibed and the suction applied to the well. If imbibition rates and suction are small, the pressure transient due to injection and the density contrast allows rapid upward plume migration at early times. The density contrast diminishes considerably within tens to hundreds of years as mixing occurs. We present estimates of HF fluid migration to shallow aquifers during the first 1,000 years after hydraulic fracturing begins for ranges of subsurface properties.

Transport and fate of chloride from road salt within a mixed urban and agricultural watershed in Illinois (USA): assessing the influence of chloride application rates

NASA Astrophysics Data System (ADS)

Ludwikowski, Jessica J.; Peterson, Eric W.

2018-06-01

In a typical winter season, approximately 471,000 tons of road salt are deposited along roadways in Illinois, USA. An estimated 45% of the deposited road salt will infiltrate through the soils and into shallow aquifers. Transported through shallow aquifers, chloride associated with the road salts has the potential to reside within groundwater for years based on the pathway, the geologic material, and the recharge rate of the aquifer system. Utilizing MODFLOW and MT3D, simulations employing various road-salt application rates were conducted to assess the net accumulation of chloride and the residence times of chloride in an agriculture-dominated watershed that originates in an urban area. A positive-linear relationship was observed between the application rate of chloride and both the maximum chloride concentration and total mass accumulated within the watershed. Simulated annual recharge rates along impacted surfaces ranged from 1,000 to 10,000 mg/L. After 60 years of application, simulated chloride concentrations in groundwater ranged from 197 to 1,900 mg/L. For all application rates, chloride concentrations within the groundwater rose at an annual rate of >3 mg/L. While concentrations increase throughout the system, the majority of chloride accumulation occurs near the roads and the urban areas. Model simulations reveal a positive relationship between application rate and residence time of chloride (1,123-1,288 days based on application rate). The models indicate that continued accumulation of chloride in shallow aquifers can be expected, and methods that apply less chloride effectively need to be examined.

Transport and fate of chloride from road salt within a mixed urban and agricultural watershed in Illinois (USA): assessing the influence of chloride application rates

NASA Astrophysics Data System (ADS)

Ludwikowski, Jessica J.; Peterson, Eric W.

2018-01-01

In a typical winter season, approximately 471,000 tons of road salt are deposited along roadways in Illinois, USA. An estimated 45% of the deposited road salt will infiltrate through the soils and into shallow aquifers. Transported through shallow aquifers, chloride associated with the road salts has the potential to reside within groundwater for years based on the pathway, the geologic material, and the recharge rate of the aquifer system. Utilizing MODFLOW and MT3D, simulations employing various road-salt application rates were conducted to assess the net accumulation of chloride and the residence times of chloride in an agriculture-dominated watershed that originates in an urban area. A positive-linear relationship was observed between the application rate of chloride and both the maximum chloride concentration and total mass accumulated within the watershed. Simulated annual recharge rates along impacted surfaces ranged from 1,000 to 10,000 mg/L. After 60 years of application, simulated chloride concentrations in groundwater ranged from 197 to 1,900 mg/L. For all application rates, chloride concentrations within the groundwater rose at an annual rate of >3 mg/L. While concentrations increase throughout the system, the majority of chloride accumulation occurs near the roads and the urban areas. Model simulations reveal a positive relationship between application rate and residence time of chloride (1,123-1,288 days based on application rate). The models indicate that continued accumulation of chloride in shallow aquifers can be expected, and methods that apply less chloride effectively need to be examined.

Electrical Resistivity Imaging and the Saline Water Interface in High-Quality Coastal Aquifers

NASA Astrophysics Data System (ADS)

Costall, A.; Harris, B.; Pigois, J. P.

2018-05-01

Population growth and changing climate continue to impact on the availability of natural resources. Urbanization of vulnerable coastal margins can place serious demands on shallow groundwater. Here, groundwater management requires definition of coastal hydrogeology, particularly the seawater interface. Electrical resistivity imaging (ERI) appears to be ideally suited for this purpose. We investigate challenges and drivers for successful electrical resistivity imaging with field and synthetic experiments. Two decades of seawater intrusion monitoring provide a basis for creating a geo-electrical model suitable for demonstrating the significance of acquisition and inversion parameters on resistivity imaging outcomes. A key observation is that resistivity imaging with combinations of electrode arrays that include dipole-dipole quadrupoles can be configured to illuminate consequential elements of coastal hydrogeology. We extend our analysis of ERI to include a diverse set of hydrogeological settings along more than 100 km of the coastal margin passing the city of Perth, Western Australia. Of particular importance are settings with: (1) a classic seawater wedge in an unconfined aquifer, (2) a shallow unconfined aquifer over an impermeable substrate, and (3) a shallow multi-tiered aquifer system over a conductive impermeable substrate. We also demonstrate a systematic increase in the landward extent of the seawater wedge at sites located progressively closer to the highly urbanized center of Perth. Based on field and synthetic ERI experiments from a broad range of hydrogeological settings, we tabulate current challenges and future directions for this technology. Our research contributes to resolving the globally significant challenge of managing seawater intrusion at vulnerable coastal margins.

Electrical Resistivity Imaging and the Saline Water Interface in High-Quality Coastal Aquifers

NASA Astrophysics Data System (ADS)

Costall, A.; Harris, B.; Pigois, J. P.

2018-07-01

Population growth and changing climate continue to impact on the availability of natural resources. Urbanization of vulnerable coastal margins can place serious demands on shallow groundwater. Here, groundwater management requires definition of coastal hydrogeology, particularly the seawater interface. Electrical resistivity imaging (ERI) appears to be ideally suited for this purpose. We investigate challenges and drivers for successful electrical resistivity imaging with field and synthetic experiments. Two decades of seawater intrusion monitoring provide a basis for creating a geo-electrical model suitable for demonstrating the significance of acquisition and inversion parameters on resistivity imaging outcomes. A key observation is that resistivity imaging with combinations of electrode arrays that include dipole-dipole quadrupoles can be configured to illuminate consequential elements of coastal hydrogeology. We extend our analysis of ERI to include a diverse set of hydrogeological settings along more than 100 km of the coastal margin passing the city of Perth, Western Australia. Of particular importance are settings with: (1) a classic seawater wedge in an unconfined aquifer, (2) a shallow unconfined aquifer over an impermeable substrate, and (3) a shallow multi-tiered aquifer system over a conductive impermeable substrate. We also demonstrate a systematic increase in the landward extent of the seawater wedge at sites located progressively closer to the highly urbanized center of Perth. Based on field and synthetic ERI experiments from a broad range of hydrogeological settings, we tabulate current challenges and future directions for this technology. Our research contributes to resolving the globally significant challenge of managing seawater intrusion at vulnerable coastal margins.

A study on the influence of tides on the water table conditions of the shallow coastal aquifers

NASA Astrophysics Data System (ADS)

Singaraja, C.; Chidambaram, S.; Jacob, Noble

2018-03-01

Tidal variation and water level in aquifer is an important function in the coastal environment, this study attempts to find the relationship between water table fluctuation and tides in the shallow coastal aquifers. The study was conducted by selecting three coastal sites and by monitoring the water level for every 2-h interval in 24 h of observation. The study was done during two periods of full moon and new moon along the Cuddalore coastal region of southern part of Tamil Nadu, India. The study shows the relationship between tidal variation, water table fluctuations, dissolved oxygen, and electrical conductivity. An attempt has also been made in this study to approximate the rate of flow of water. Anyhow, the differences are site specific and the angle of inclination of the water table shows a significant relation to the mean sea level, with respect to the distance of the point of observation from the sea and elevation above mean sea level.

Geophysical survey for groundwater potential investigation in peat land area, Riau, Indonesia

NASA Astrophysics Data System (ADS)

Islami, N.; Irianti, M.; Azhar; Nor, M.; Fakhrudin

2018-04-01

Tropical forests, especially peat lands, are particularly vulnerable to forest fires. Fires are the most common disasters in peat lands in the dry season, especially in Riau Province, Indonesia. In the process of extinguishing the peat fire, several substantial problems arise to stop peat fires during this period. This study aims to determine the possibility of using ground water as a source of water to anticipate the early mitigation of peat land fires disaster. The geoelectrical resistivity surveys were used to predict the subsurface geological data including peat thickness and depth of aquifers. The geometry of peat lands was determined using geostatistics based on geoelectrical resistivity interpretation data. Peat Land thickness varies up to 4 m in the north and is thinner to the south. A shallower and deeper aquifer is available at a depth of 13 m to 18 m and 70 m to 90 m respectively. In general, the potential of groundwater in the shallow aquifer is predicted to be sufficient for peat land watering anytime.

Rapid transport from the surface to wells in fractured rock: a unique infiltration tracer experiment.

PubMed

Levison, Jana K; Novakowski, Kent S

2012-04-01

A unique infiltration tracer experiment was performed whereby a fluorescent dye was applied to the land surface in an agricultural field, near Perth, Ontario, Canada, to simulate the transport of solutes to two pumped monitoring wells drilled into the granitic gneiss aquifer. This experiment, interpreted using the discrete-fracture capability of the numerical model HydroGeoSphere, showed that solute transport from the surface through thin soil (less than 2m) to wells in fractured bedrock can be extremely rapid (on the order of hours). Also, it was demonstrated that maximum concentrations of contaminants originating from the ground surface will not necessarily be the highest in the shallow aquifer horizon. These are important considerations for both private and government-owned drinking water systems that draw water from shallow fractured bedrock aquifers. This research illustrates the extreme importance of protecting drinking water at the source. Copyright © 2012 Elsevier B.V. All rights reserved.

Variable Flow Pathways and Geochemical History of Seepage Under Mississippi River Levees: 2011, 2015, and 2016 Floods

NASA Astrophysics Data System (ADS)

Voll, K.; Davidson, G. R.; Borrok, D. M.; Corcoran, M. K.; Kelley, J.; Ma, L.

2017-12-01

Seepage beneath levees during flood stage is a concern when piping occurs, creating channels under the levee and forming sand boils where transported sediments discharge. The flow depth beneath a levee varies with surface geology, following deeper paths where the levee sits on channel fill deposits and shallower paths where it sits on sandbar deposits. Piping along shallow pathways poses an increased risk of levee failure. The Lower Mississippi River Valley alluvial aquifer is geochemically stratified, with reducing waters at greater depth, resulting in unique geochemical signatures for water passing beneath the Mississippi River levee along variable flow paths. Sampling from sand boils and flowing relief wells north of Vicksburg, MS, during the 2011, 2015, and 2016 flood events demonstrates the utility of using the geochemistry of discharge water to identify different flow pathways, and to provide greater insight on the variable water-rock interactions as a function of depth. Relief wells discharge water mainly from deeper zones, reflected by low redox potential, high Fe and As, and low 87Sr/86Sr ratios. High variability in As concentrations may result from varying degrees of reductive dissolution of Fe and Mn and release of co-precipitated As. At shallower depths the aquifer is mostly oxic, lower in Fe, As, and bicarbonate, and higher in sulfate concentrations and 87Sr/86Sr ratios. The geochemical signatures of sand-boil discharge varied between boils that were short distances apart. Water samples plotted on a Piper Diagram fell along two distinct trends starting with river water and diverging along pathways reflecting unique water-rock interaction at different depths. Strontium isotope ratios indicate differences in geochemistry are not just from variable redox reactions, but also reflect dissolution of primary minerals of unique composition or provenance. Oxygen and hydrogen isotopes of all subsurface samples reflect an unexpected level of evaporation of river water prior to recharge to the aquifer, attributed to the presence of numerous water-filled depressions between the river channel and levee system. Tritium levels from wells and boils ranged from 2.3 to 7.4 TU, with some high values coming from deeper zones indicating localized variation in the residence time of water at equal depths beneath levees.

Nitrate in ground water and spring water near four dairy farms in North Florida, 1990-93

USGS Publications Warehouse

Andrews, W.J.

1994-01-01

Concentrations of nitrate and other selected water- quality characteristics were analyzed periodically for two years in water from 51 monitoring wells installed at four farms and in water discharging from three nearby springs along the Suwannee River in Lafayette and Suwannee Counties to examine the quality of ground water at these farms and the transport of nutrients in ground water to the nearby spring-fed Suwannee River: Ground water from shallow wells, which were completed in the top ten feet of the saturated zone in a surficial sandy aquifer and in the karstic Upper Floridan aquifer generally had the highest concentrations of nitrate, ranging from <.02 to 130 mg/L as nitrogen. Nitrate concentrations commonly exceeded the primary drinking water standard of 10 mg/L for nitrate as nitrogen in water from shallow wells, which tapped the top ten feet of the uppermost aquifers near waste-disposal areas such as wastewater lagoons and defoliated, intensive-use areas near milking barns. Upgradient from waste-disposal areas, concentrations of nitrate in ground water were commonly less than 1 mg/L as nitrogen. Water samples from deep wells (screened 20 feet deeper than shallow wells in these aquifers) generally had lower concentrations of nitrate (ranging from <0.02 to 84 mg/L) than water from shallow wells. Water samples from the three monitored springs (Blue, Telford, and Convict Springs) had nitrate concentrations ranging from 1.5 to 6.5 mg/L as nitrogen, which were higher than those typically occurring in water from upgradient wells at the monitored dairy farms or from back- ground wells sampled in the region. Analyses of nitrogen isotope ratios in nitrate indicated that leachate from animal wastes was the principal source of nitrate in ground water adjacent to waste-disposal areas at the monitored and unmonitored dairy farms. Leachate from a combi- nation of fertilizers, soils, and animal wastes appeared to be the source of nitrate in ground- water downgradient from pastures and wastewater spray fields at dairy farms and in water discharging from three nearby springs. Although denitrifying bacteria were present in counts sometimes exceeding 240,000 colonies/100mL in water from dairy-farm monitoring wells, ground water in the uppermost aquifers in Lafayette and Suwannee Counties generally contained too much oxygen for denitrification to remove nitrate from shallow ground water. Denitrification was more likely to occur in deeper ground water, which typically has lower dissolved oxygen concentrations.

Installation and Sampling of Observation Wells and Analyses of Water From the Shallow Aquifer at Selected Waste-Disposal Sites in the Memphis Area, Tennessee

DTIC Science & Technology

1989-01-01

water-table aquifer. This aquifer is made up chiefly of the alluvium and fluvial (terrace) deposits of Quaternary age , but locally may include sand in...the uppermost part of the Jackson Formation and Claiborne Group of Tertiary age . Water samples were collected from these 10 wells and from two...been identified as having received unknown quantities and types of industrial wastes (Waste Age , 1979, p. 54, 56). These sites are the (1) Belleuue

Water Quality in the Equus Beds Aquifer and the Little Arkansas River Before Implementation of Large-Scale Artificial Recharge, South-Central Kansas, 1995-2005

USGS Publications Warehouse

Ziegler, Andrew C.; Hansen, Cristi V.; Finn, Daniel A.

2010-01-01

Artificial recharge of the Equus Beds aquifer using runoff from the Little Arkansas River in south-central Kansas was first proposed in 1956 and was one of many options considered by the city of Wichita to preserve its water supply. Declining aquifer water levels of as much as 50 feet exacerbated concerns about future water availability and enhanced migration of saltwater into the aquifer from past oil and gas activities near Burrton and from the Arkansas River. Because Wichita changed water-management strategies and decreased pumping from the Equus Beds aquifer in 1992, water storage in the aquifer recovered by about 50 percent. This recovery is the result of increased reliance on Cheney Reservoir for Wichita water supply, decreased aquifer pumping, and larger than normal precipitation. Accompanying the water-level recovery, the average water-level gradient in the aquifer decreased from about 12 feet per mile in 1992 to about 8 feet per mile in January 2006. An important component of artificial recharge is the water quality of the receiving aquifer and the water being recharged (source water). Water quality within the Little Arkansas River was defined using data from two real-time surface-water-quality sites and discrete samples. Water quality in the Equus Beds aquifer was defined using sample analyses collected at 38 index sites, each with a well completed in the shallow and deep parts of the Equus Beds aquifer. In addition, data were collected at diversion well sites, recharge sites, background wells, and prototype wells for the aquifer storage and recovery project. Samples were analyzed for major ions, nutrients, trace metals, radionuclides, organic compounds, and bacterial and viral indicators. Water-quality constituents of concern for artificial recharge are those constituents that frequently (more than 5 percent of samples) may exceed Federal [U.S. Environmental Protection Agency (USEPA)] and State drinking-water criteria in water samples from the receiving aquifer or in samples from the source water. Constituents of concern include major ions (sulfate and chloride), nutrients (nitrite plus nitrate), trace elements (arsenic, iron, and manganese), organic compounds (atrazine), and fecal bacterial indicators. This report describes the water quality in the Equus Beds aquifer and the Little Arkansas River from 1995 through 2005 before implementation of large-scale recharge activities. Sulfate concentrations in water samples from the Little Arkansas River rarely exceeded Federal secondary drinking water regulation (SDWR) of 250 milligrams per liter (mg/L). Sulfate concentrations in groundwater were exceeded in about 18 percent of the wells in the shallow (less than or equal to 80 feet deep) parts of the aquifer and in about 13 percent of the wells in the deep parts the aquifer. Larger sulfate concentrations were associated with parts of the aquifer with the largest water-level declines. Water-quality changes in the Equus Beds aquifer likely were caused by dewatering and oxidation of aquifer material that subsequently resulted in increased sulfate concentrations as water levels recovered. The primary sources of chloride to the Equus Beds aquifer are from past oil and gas activities near Burrton and from the Arkansas River. Computed chloride concentrations in the Little Arkansas River near Halstead exceeded the Federal SDWR of 250 mg/L about 27 percent of the time (primarily during low-flow conditions). Chloride concentrations in groundwater exceeded 250 mg/L in about 8 percent or less of the study area, primarily near Burrton and along the Arkansas River. Chloride in groundwater near Burrton has migrated downgradient about 3 miles during the past 40 to 45 years. The downward and horizontal migration of the chloride is controlled by the hydraulic gradient in the aquifer, dispersion of chloride, and discontinuous clay layers that can inhibit further downward migration. Chloride in the shallow parts of the Equus Beds

Transport of chromium and selenium in the suboxic zone of a shallow aquifer: Influence of redox and adsorption reactions

USGS Publications Warehouse

Kent, D.B.; Davis, J.A.; Anderson, L.C.D.; Rea, B.A.; Waite, T.D.

1994-01-01

Breakthrough of Cr(VI) (chromate), Se(VI) (selenate), and O2 (dissolved oxygen) was observed in tracer tests conducted in a shallow, sand and gravel aquifer with mildly reducing conditions. Loss of Cr, probably due to reduction of Cr(VI) to Cr(III) and irreversible sorption of Cr(III), occurred along with slight retardation of Cr(VI), owing to reversible sorption. Reduction of Se(VI) and O2 was thermodynamically feasible but did not occur, indicating conditions, were unfavorable to microbial reduction. Cr(VI) reduction by constituents of aquifer sediments did not achieve local equilibrium during transport. The reduction rate was probably limited by incomplete contact between Cr(VI) transported along predominant flow paths and reductants located in regions within aquifer sediments of comparatively low permeability. Scatter in the amount of Cr reduction calculated from individual breakthrough curves at identical distances downgradient probably resulted from heterogeneities in the distribution of reductants in the sediments. Predictive modeling of the transport and fate of redox-sensitive solutes cannot be based strictly on thermodynamic considerations; knowledge of reaction rates is critical. Potentially important mass transfer rate limitations between solutes and reactants in sediments as well as heterogeneities in the distribution of redox properties in aquifers complicate determination of limiting rates for use in predictive simulations of the transport of redox-sensitive contaminants in groundwater.

Variable exchange between a stream and an aquifer in the Rio Grande Project Area

NASA Astrophysics Data System (ADS)

Sheng, Z.; Abudu, S.; Michelsen, A.; King, P.

2016-12-01

Both surface water and groundwater in the Rio Grande Project area in southern New Mexico and Far West Texas have been stressed by natural conditions such as droughts and human activities, including urban development and agricultural irrigation. In some area pumping stress in the aquifer becomes so great that it depletes the river flow especially during the irrigation season, typically from March through October. Therefore understanding such relationship between surface water and groundwater becomes more important in regional water resources planning and management. In this area, stream flows are highly regulated by the upstream reservoirs during the irrigation season and greatly influenced by return flows during non-irrigation season. During a drought additional groundwater pumping to supplement surface water shortage further complicates the surface water and groundwater interaction. In this paper the authors will use observation data and results of numerical models (MODFLOW) to characterize and quantify hydrological exchange fluxes between groundwater in the aquifers and surface water as well as impacts of groundwater pumping. The interaction shows a very interesting seasonal variation (irrigation vs. non-irrigation) as well as impact of a drought. Groundwater has been pumped for both municipal supplies and agricultural irrigation, which has imposed stresses toward both stream flows and aquifer storage. The results clearly show that historic groundwater pumping has caused some reaches of the river change from gaining stream to losing stream. Beyond the exchange between surface water and groundwater in the shallow aquifer, groundwater pumping in a deep aquifer could also enhance the exchanges between different aquifers through leaky confining layers. In the earlier history of pumping, pumping from the shallow aquifer is compensated by simple depletion of surface water, while deep aquifer tends to use the aquifer storage. With continued pumping, the cumulative stresses from deeper aquifers migrate upward, resulting in additional depletion of surface water. Eventually such impacts turn some reaches of a gaining river into a losing stream. The research finding provides information needed for future regional water planning and conjunctive management of surface water and groundwater resources.

Geohydrology of the Island of Oahu, Hawaii

USGS Publications Warehouse

Hunt, Charles D.

1996-01-01

The island of Oahu, Hawaii, is the eroded remnant of two coalesced shield volcanoes, the Waianae Volcano and the Koolau Volcano. Shield-building lavas emanated mainly from the rift zones of the volcanoes. Subaerial eruptions of the Waianae Volcano occurred between 3.9 and 2.5 million years ago, and eruptions of the Koolau Volcano occurred between 2.6 and 1.8 million years ago. The volcanoes have subsided more then 6,000 feet, and erosion has destroyed all but the western rim of the Koolau Volcano and the eastern part of the Waianae Volcano, represented by the Koolau and Waianae Ranges, respectively. Hydraulic properties of the volcanic-rock aquifers are determined by the distinctive textures and geometry of individual lava flows. Individual lava flows are characterized by intergranular, fracture, and conduit-type porosity and commonly are highly permeable. The stratified nature of the lava flows imparts a layered heterogeneity. The flows are anisotropic in three dimensions, with the largest permeability in the longitudinal direction of the lava flow, an intermediate permeability in the direction transverse to the flow, and the smallest permeability normal to bedding. Averaged over several lava-flow thicknesses, lateral hydraulic conductivity of dike-free lava flows is about 500 to 5,000 feet per day, with smaller and larger values not uncommon. Systematic areal variations in lava-flow thickness or other properties may impart trends in the heterogeneity. The aquifers of Oahu contain two flow regimes: shallow freshwater and deep saltwater. The freshwater floats on underlying saltwater in a condition of buoyant displacement, although the relation is not necessarily a simple hydrostatic balance everywhere. Natural driving mechanisms for freshwater and saltwater flow differ. Freshwater moves mainly by simple gravity flow; meteoric water flows from inland recharge areas at higher altitudes to discharge areas at lower altitudes near the coast. Remnant volcanic heat also may drive geothermal convection of freshwater in the rift zones. Saltwater flow is driven by changes in freshwater volume and sea level and by dispersive and geothermal convection. Freshwater flow is much more active--velocity is higher and residence time is shorter--than saltwater flow. Hydrodynamic dispersion produces a transition zone of mixed water between the freshwater and the underlying saltwater. The Waianae aquifer in the Waianae Volcanics and the Koolau aquifer in the Koolau Basalt are the two principal volcanic-rock aquifers on Oahu. The sequences of coastal-plain and valley-fill deposits locally form aquifers, but these aquifers are of minor importance because of the small volume of water contained in them. The two principal volcanic-rock aquifers are composed mainly of thick sequences of permeable, thin-bedded lava flows. These aquifers combine to form a layered aquifer system throughout central Oahu where the Koolau aquifer overlies the Waianae aquifer. They are separated by a regional confining unit formed by weathering along the Waianae-Koolau unconformity, which marks the eroded and weathered surface of the Waianae Volcano buried by younger Koolau lava flows. The areal hydraulic continuity of the aquifers of Oahu is interrupted in many places by steeply dipping, stratigraphically unconformable, geohydrologic barriers. These low-permeability features include eruptive feeder dikes, sedimentary valley fills, and former erosional surfaces now buried by younger lava flows or sediments. The barriers impede and divert lateral ground-water flow and impound ground water to greater heights than would occur in the absence of the barriers, causing abrupt stepped discontinuities in the potentiometric surface. The largest discontinuities are associated with dense concentrations of dikes in the eruptive rift zones of each volcano. The dikes in these zones originate from great depths and impede flow both in shallow-freshwater and in deep-saltwater flow sy

Sanitary protection zoning based on time-dependent vulnerability assessment model - case examples at two different type of aquifers

NASA Astrophysics Data System (ADS)

Živanović, Vladimir; Jemcov, Igor; Dragišić, Veselin; Atanacković, Nebojša

2017-04-01

Delineation of sanitary protection zones of groundwater source is a comprehensive and multidisciplinary task. Uniform methodology for protection zoning for various type of aquifers is not established. Currently applied methods mostly rely on horizontal groundwater travel time toward the tapping structure. On the other hand, groundwater vulnerability assessment methods evaluate the protective function of unsaturated zone as an important part of groundwater source protection. In some particular cases surface flow might also be important, because of rapid transfer of contaminants toward the zones with intense infiltration. For delineation of sanitary protection zones three major components should be analysed: vertical travel time through unsaturated zone, horizontal travel time through saturated zone and surface water travel time toward intense infiltration zones. Integrating the aforementioned components into one time-dependent model represents a basis of presented method for delineation of groundwater source protection zones in rocks and sediments of different porosity. The proposed model comprises of travel time components of surface water, as well as groundwater (horizontal and vertical component). The results obtained using the model, represent the groundwater vulnerability as the sum of the surface and groundwater travel time and corresponds to the travel time of potential contaminants from the ground surface to the tapping structure. This vulnerability assessment approach do not consider contaminant properties (intrinsic vulnerability) although it can be easily improved for evaluating the specific groundwater vulnerability. This concept of the sanitary protection zones was applied at two different type of aquifers: karstic aquifer of catchment area of Blederija springs and "Beli Timok" source of intergranular shallow aquifer. The first one represents a typical karst hydrogeological system with part of the catchment with allogenic recharge, and the second one, the groundwater source within shallow intergranular alluvial aquifer, dominantly recharged by river bank filtration. For sanitary protection zones delineation, the applied method has shown the importance of introducing all travel time components equally. In the case of the karstic source, the importance of the surface flow toward ponor zones has been emphasized, as a consequence of rapid travel time of water in relation to diffuse infiltration from autogenic part. When it comes to the shallow intergranular aquifer, the character of the unsaturated zone gets more prominent role in the source protection, as important buffer of the vertical movement downward. The applicability of proposed method has been shown regardless of the type of the aquifer, and at the same time intelligible results of the delineated sanitary protection zones are possible to validate with various methods. Key words: groundwater protection zoning, time dependent model, karst aquifer, intergranular aquifer, groundwater source protection

Comparison of nitrate, pesticides, and volatile organic compounds in samples from monitoring and public-supply wells, Kirkwood-Cohansey aquifer system, southern New Jersey

USGS Publications Warehouse

Stackelberg, Paul E.; Kauffman, L.J.; Baehr, A.L.; Ayers, M.A.

2000-01-01

The number and total concentration of volatile organic compounds (VOCs) per sample were significantly greater in water from public-supply wells than in water from shallow and moderate-depth monitoring wells in the surficial Kirkwood-Cohansey aquifer system in the Glassboro area of southern New Jersey. In contrast, concentrations of nitrate (as nitrogen) and the number and total concentration of pesticides per sample were statistically similar in samples from shallow and moderate-depth monitoring wells and those from public-supply wells. VOCs in ground water typically are derived from point sources, which commonly exist in urban areas and which result in spatially variable contaminant concentrations near the water table. Because larger volumes of water are withdrawn from public-supply wells than from monitoring wells, their contributing areas are larger and, therefore, they are more likely to intercept water flowing from VOC point sources. Additionally, public-supply wells intercept flow paths that span a large temporal interval. Public-supply wells in the Glassboro study area withdraw water flowing along short paths, which contains VOCs that recently entered the aquifer system, and water flowing along relatively long paths, which contains VOCs that originated from the degradation of parent compounds or that are associated with past land uses. Because the volume of water withdrawn from monitoring wells is small and because shallow monitoring wells are screened near the water table, they generally intercept only relatively short flow paths. Therefore, samples from these wells represent relatively recent, discrete time intervals and contain both fewer VOCs and a lower total VOC concentration than samples from public-supply wells. Nitrate and pesticides in ground water typically are derived from nonpoint sources, which commonly are found in both agricultural and urban areas and typically result in lowlevel, relatively uniform concentrations near the water table. Because nonpoint sources are diffuse and because processes such as degradation or sorption/dispersion do not occur at rates sufficient to prevent detection of these constituents in parts of the aquifer used for domestic and public supply in the study area, concentrations of nitrate and pesticides and numbers of pesticide compounds are likely to be similar in samples from shallow monitoring wells and samples from public-supply wells. Results of a comparison of (1) the general characteristics of, and water-quality data from, public-supply wells in the Glassboro study area to available data from public-supply wells screened in the Kirkwood-Cohansey aquifer system outside the study area, and (2) land-use settings, soil characteristics, and aquifer properties in and outside the study area indicate that the findings of this study likely are applicable to the entire extent of the Kirkwood- Cohansey aquifer system in southern New Jersey.

Localized sulfate-reducing zones in a coastal plain aquifer

USGS Publications Warehouse

Brown, C.J.; Coates, J.D.; Schoonen, M.A.A.

1999-01-01

High concentrations of dissolved iron in ground water of coastal plain or alluvial aquifers contribute to the biofouling of public supply wells for which treatment and remediation is costly. Many of these aquifers, however, contain zones in which microbial sulfate reduction and the associated precipitation of iron-sulfide minerals decreases iron mobility. The principal water-bearing aquifer (Magothy Aquifer of Cretaceous age) in Suffolk County, New York, contains localized sulfate-reducing zones in and near lignite deposits, which generally are associated with clay lenses. Microbial analyses of core samples amended with [14C]-acetate indicate that microbial sulfate reduction is the predominant terminal-electron-accepting process (TEAP) in poorly permeable, lignite-rich sediments at shallow depths and near the ground water divide. The sulfate-reducing zones are characterized by abundant lignite and iron-sulfide minerals, low concentrations of Fe(III) oxyhydroxides, and by proximity to clay lenses that contain pore water with relatively high concentrations of sulfate and dissolved organic carbon. The low permeability of these zones and, hence, the long residence time of ground water within them, permit the preservation and (or) allow the formation of iron-sulfide minerals, including pyrite and marcasite. Both sulfate-reducing bacteria (SRB) and iron-reducing bacteria (IRB) are present beneath and beyond the shallow sulfate-reducing zones. A unique Fe(III)-reducing organism, MD-612, was found in core sediments from a depth of 187 m near the southern shore of Long Island. The distribution of poorly permeable, lignite-rich, sulfate-reducing zones with decreased iron concentration is varied within the principal aquifer and accounts for the observed distribution of dissolved sulfate, iron, and iron sulfides in the aquifer. Locating such zones for the placement of production wells would be difficult, however, because these zones are of limited aerial extent.

Hydrogeochemical contrast between brown and grey sand aquifers in shallow depth of Bengal Basin: consequences for sustainable drinking water supply.

PubMed

Biswas, Ashis; Nath, Bibhash; Bhattacharya, Prosun; Halder, Dipti; Kundu, Amit K; Mandal, Ujjal; Mukherjee, Abhijit; Chatterjee, Debashis; Mörth, Carl-Magnus; Jacks, Gunnar

2012-08-01

Delineation of safe aquifer(s) that can be targeted by cheap drilling technology for tubewell (TW) installation becomes highly imperative to ensure access to safe and sustainable drinking water sources for the arsenic (As) affected population in Bengal Basin. This study investigates the potentiality of brown sand aquifers (BSA) as a safe drinking water source by characterizing its hydrogeochemical contrast to grey sand aquifers (GSA) within shallow depth (<70 m) over an area of 100 km(2) in Chakdaha Block of Nadia district, West Bengal, India. The results indicate that despite close similarity in major ion composition, the redox condition is markedly different in groundwater of the two studied aquifers. The redox condition in the BSA is delineated to be Mn oxy-hydroxide reducing, not sufficiently lowered for As mobilization into groundwater. In contrast, the enrichments of NH(4)(+), PO(4)(3-), Fe and As along with lower Eh in groundwater of GSA reflect reductive dissolution of Fe oxy-hydroxide coupled to microbially mediated oxidation of organic matter as the prevailing redox process causing As mobilization into groundwater of this aquifer type. In some portions of GSA the redox status even has reached to the stage of SO(4)(2-) reduction, which to some extent might sequester dissolved As from groundwater by co-precipitation with authigenic pyrite. Despite having low concentration of As in groundwater of the BSA the concentration of Mn often exceeds the drinking water guidelines, which warrants rigorous assessment of attendant health risk for Mn prior to considering mass scale exploitation of the BSA for possible sustainable drinking water supply. Copyright © 2012 Elsevier B.V. All rights reserved.

Depth of the vadose zone controls aquifer biogeochemical conditions and extent of anthropogenic nitrogen removal

USGS Publications Warehouse

Szymczycha, Beata; Kroeger, Kevin D.; Crusius, John; Bratton, John F.

2017-01-01

We investigated biogeochemical conditions and watershed features controlling the extent of nitrate removal through microbial dinitrogen (N2) production within the surficial glacial aquifer located on the north and south shores of Long Island, NY, USA. The extent of N2 production differs within portions of the aquifer, with greatest N2 production observed at the south shore of Long Island where the vadose zone is thinnest, while limited N2production occurred under the thick vadose zones on the north shore. In areas with a shallow water table and thin vadose zone, low oxygen concentrations and sufficient DOC concentrations are conducive to N2production. Results support the hypothesis that in aquifers without a significant supply of sediment-bound reducing potential, vadose zone thickness exerts an important control of the extent of N2 production. Since quantification of excess N2 relies on knowledge of equilibrium N2concentration at recharge, calculated based on temperature at recharge, we further identify several features, such as land use and cover, seasonality of recharge, and climate change that should be considered to refine estimation of recharge temperature, its deviation from mean annual air temperature, and resulting deviation from expected equilibrium gas concentrations.

Changes of freshwater-lens thickness in basaltic island aquifers overlain by thick coastal sediments

USGS Publications Warehouse

Rotzoll, Kolja; Oki, Delwyn S.; El-Kadi, Aly I.

2010-01-01

Freshwater-lens thickness and long-term changes in freshwater volume in coastal aquifers are commonly assessed through repeated measurement of salinity profiles from monitor wells that penetrate into underlying salt water. In Hawaii, the thickest measured freshwater lens is currently 262 m in dike-free, volcanic-rock aquifers that are overlain by thick coastal sediments. The midpoint depth (depth where salinity is 50% salt water) between freshwater and salt water can serve as an indicator for freshwater thickness. Most measured midpoints have risen over the past 40 years, indicating a shrinking lens. The mean rate of rise of the midpoint from 1999–2009 varied locally, with faster rates in highly developed areas (1.0 m/year) and slower rates in less developed areas (0.5 m/year). The thinning of the freshwater lenses is the result of long-term groundwater withdrawal and reduced recharge. Freshwater/salt-water interface locations predicted from measured water levels and the Ghyben-Herzberg principle may be deeper than measured midpoints during some periods and shallower during other periods, although depths may differ up to 100 m in some cases. Moreover, changes in the midpoint are slower than changes in water level. Thus, water levels may not be a reliable indicator of the amount of freshwater in a coastal aquifer.

Determination of hydraulic properties in the vicinity of a landfill near Antioch, Illinois

USGS Publications Warehouse

Kay, Robert T.; Earle, John D.

1990-01-01

A hydrogeologic investigation was conducted in and around a landfill near Antioch, Illinois, in December 1987. The investigation consisted, in part, of an aquifer test that was designed to determine the hydraulic connection between the hydrogeologic units in the area. The hydrogeologic units consist of a shallow, unconfined, sand and gravel aquifer of variable thickness that overlies an intermediate confining unit of variable thickness composed predominantly of till. Underlying the till is a deep, confined, sand and gravel aquifer that serves as the water supply for the village of Antioch. The aquifer test was conducted in the confined aquifer. Aquifer-test data were analyzed using the Hantush and Jacob method for a leaky confined aquifer with no storage in the confining unit. Calculated transmissivity of the confined aquifer ranged from 1.96x10^4 to 2.52x10^4 foot squared per day and storativity ranged from 2.10x10^-4 to 8.71x10^-4. Leakage through the confining unit ranged from 1.29x10^-4 to 7.84x10^-4 foot per day per foot, and hydraulic conductivity of the confining unit ranged from 3.22x10^-3 to 1.96x10^-2 foot per day. The Hantush method for analysis of a leaky confined aquifer with storage in the confining unit also was used to estimate aquifer and confining-unit properties. Transmissivity and storativity values calculated using the Hantush method are in good agreement with the values calculated from the Hantush and Jacob method. Properties of the confining unit were estimated using the ratio method of Neuman and Witherspoon. The estimated diffusivity of the confining unit ranged from 50.36 to 68.13 feet squared per day, A value for the vertical hydraulic conductivity of the confining unit calculated from data obtained using both the Hantush and the Neuman and Witherspoon methods was within the range of values calculated by the Hantush and Jacob method. The aquifer-test data clearly showed that the confining unit is hydraulically connected to the confined aquifer. The aquifer-test data also indicated that the unconfined aquifer becomes hydraulically connected to the deep sand and gravel aquifer within 24 hours after the start of pumping in the confined aquifer.

Brine migration resulting from pressure increases in a layered subsurface system

NASA Astrophysics Data System (ADS)

Delfs, Jens-Olaf; Nordbeck, Johannes; Bauer, Sebastian

2016-04-01

Brine originating from the deep subsurface impairs parts of the freshwater resources in the North German Basin. Some of the deep porous formations (esp. Trias and Jurassic) exhibit considerable storage capacities for waste fluids (CO2, brine from oil production or cavern leaching), raising concerns among water providers that this type of deep subsurface utilization might impair drinking water supplies. On the one hand, overpressures induced by fluid injections and the geothermal gradient support brine migration from deep into shallow formations. On the other hand, the rising brine is denser than the surrounding less-saline formation waters and, therefore, tends to settle down. Aim of this work is to investigate the conditions under which pressurized formation brine from deep formations can reach shallow freshwater resources. Especially, the role of intermediate porous formations between the storage formation and the groundwater is studied. For this, complex thermohaline simulations using a coupled numerical process model are necessary and performed in this study, in which fluid density depends on fluid pressure, temperature and salt content and the governing partial differential equations are coupled. The model setup is 2D and contains a hypothetic series of aquifers and barriers, each with a thickness of 200 m. Formation pressure is increased at depths of about 2000 m in proximity to a salt wall and a permeable fault. The domain size reaches up to tens of kilometers horizontally to the salt wall. The fault connects the injection formation and the freshwater aquifer such that conditions can be considered as extremely favorable for induced brine migration (worst case scenarios). Brine, heat, and salt fluxes are quantified with reference to hydraulic permeabilities, storage capacities (in terms of domain size), initial salt and heat distribution, and operation pressures. The simulations reveal the development of a stagnation point in the fault region in each intermediate aquifer above the injection formation, where brine settles down and flows from the fault zone into the aquifer. This effect changes buoyancy so that lower density brine from the upper aquifers can rise higher and at larger fluxes compared to the case when no intermediary aquifers are present. In general, uplift of brine originating from the intermediary aquifers is mainly restricted to the next overlying two to three permeable aquifers (200m-1000m) or even only to the next aquifer if injection pressures are lower than about 10 bar. If injection induced over-pressures are high, brine from the injection reservoir can dominate inflow into the freshwater reservoir at late times (tens of years). An extensive parameter variation shows the effects of individual parameters. It is found, e.g., that no brine enters the freshwater aquifer if fault permeability is lower than about 10-14 m2. Acknowledgments: This work is part of the ANGUS+ project (www.angusplus.de) and funded by the German Federal Ministry of Education and Research (BMBF) as part of the energy storage initiative "Energiespeicher".

Nitrate Contamination of Deep Aquifers in the Salinas Valley, California

NASA Astrophysics Data System (ADS)

Moran, J. E.; Esser, B. K.; Hillegonds, D. J.; Holtz, M.; Roberts, S. K.; Singleton, M. J.; Visser, A.; Kulongoski, J. T.; Belitz, K.

2011-12-01

The Salinas Valley, known as 'the salad bowl of the world', has been an agricultural center for more than 100 years. Irrigated row crops such as lettuce and strawberries dominate both land use and water use. Groundwater is the exclusive supply for both irrigation and drinking water. Some irrigation wells and most public water supply wells in the Salinas Valley are constructed to draw water from deep portions of the aquifer system, where contamination by nitrate is less likely than in the shallow portions of the aquifer system. However, a number of wells with top perforations greater than 75 m deep, screened below confining or semi-confining units, have nitrate concentrations greater than the Maximum Contaminant Limit (MCL) of 45 mg/L as NO3-. This study uses nitrate concentrations from several hundred irrigation, drinking water, and monitoring wells (Monterey County Water Resources Agency, 1997), along with tritium-helium groundwater ages acquired at Lawrence Livermore National Laboratory through the State of California Groundwater Monitoring and Assessment (GAMA) program (reported in Kulongoski et al., 2007 and in Moran et al., in press), to identify nitrate 'hot spots' in the deep aquifer and to examine possible modes of nitrate transport to the deep aquifer. In addition, observed apparent groundwater ages are compared with the results of transport simulations that use particle tracking and a stochastic-geostatistical framework to incorporate aquifer heterogeneity to determine the distribution of travel times from the water table to each well (Fogg et al., 1999). The combined evidence from nitrate, tritium, tritiogenic 3He, and radiogenic 4He concentrations, reveals complex recharge and flow to the capture zone of the deep drinking water wells. Widespread groundwater pumping for irrigation accelerates vertical groundwater flow such that high nitrate groundwater reaches some deep drinking water wells. Deeper portions of the wells often draw in water that recharged before agricultural activity began in the valley, while some shallower intervals draw in recycled irrigation water which can have a low tritium concentration but high nitrate concentration. The irrigation return water may take a decade or more to reach the water table, given that the vadose zone in some affected areas is more than 30 m deep, but downward migration is likely enhanced by preferential flow paths, plowing, crop removal, and sprinkler irrigation in surrounding fields. This work was performed under the auspices of the U.S. DOE by LLNL under Contract DE-AC52-07NA27344. Fogg et al., 1999, in AGU Geophysical Monograph 108. Kulongoski et al., 2007. USGS Data Series Report 167 Monterey County Water Agency, 1997. Water Resources Data Report (Water Year 1994-1995) Moran et al., 2011. California GAMA Special Study: Nitrate Fate and Transport in the Salinas Valley. LLNL, in press.

Classifying zones of suitability for manual drilling using textural and hydraulic parameters of shallow aquifers: a case study in northwestern Senegal

NASA Astrophysics Data System (ADS)

Fussi, F. Fabio; Fumagalli, Letizia; Fava, Francesco; Di Mauro, Biagio; Kane, Cheik Hamidou; Niang, Magatte; Wade, Souleye; Hamidou, Barry; Colombo, Roberto; Bonomi, Tullia

2017-12-01

A method is proposed that uses analysis of borehole stratigraphic logs for the characterization of shallow aquifers and for the assessment of areas suitable for manual drilling. The model is based on available borehole-log parameters: depth to hard rock, depth to water, thickness of laterite and hydraulic transmissivity of the shallow aquifer. The model is applied to a study area in northwestern Senegal. A dataset of boreholes logs has been processed using a software package (TANGAFRIC) developed during the research. After a manual procedure to assign a standard category describing the lithological characteristics, the next step is the automated extraction of different textural parameters and the estimation of hydraulic conductivity using reference values available in the literature. The hydraulic conductivity values estimated from stratigraphic data have been partially validated, by comparing them with measured values from a series of pumping tests carried out in large-diameter wells. The results show that this method is able to produce a reliable interpretation of the shallow hydrogeological context using information generally available in the region. The research contributes to improving the identification of areas where conditions are suitable for manual drilling. This is achieved by applying the described method, based on a structured and semi-quantitative approach, to classify the zones of suitability for given manual drilling techniques using data available in most African countries. Ultimately, this work will support proposed international programs aimed at promoting low-cost water supply in Africa and enhancing access to safe drinking water for the population.

Internal Technical Report, 1981 Annual Report, An Analysis of the Response of the Raft River Geothermal Site Monitor Wells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thurow, T.L.; Large, R.M.; Allman, D.W.

1982-04-01

A groundwater monitoring program has been established on the Raft River Geothermal Site since 1978. The objective of this program is to document possible impacts that may be caused by geothermal production and injection on the shallow aquifers used for culinary and irrigation purposes. This annual progress report summarizes data from 12 monitor wells during 1981. These data are compared with long-term trends and are correlated with seasonal patterns, irrigation water use and geothermal production and testing. These results provide a basis for predicting long-term impacts of sustained geothermal production and testing. To date, there has been no effect onmore » the water quality of the shallow aquifers.« less

Use of Tritium and Helium to Define Groundwater Flow Conditions in a Coastal Aquifer Influenced by Seawater Intrusion: Everglades National Park

NASA Astrophysics Data System (ADS)

Price, R. M.; Top, Z.; Happell, J. D.; Swart, P. K.

2002-05-01

The concentrations of tritium (3H) and helium isotopes (3He, 4He) were used as tracers of groundwater flow in Everglades National Park, South Florida (USA). Both fresh and brackish groundwaters were collected from 47 wells completed at depths ranging from 2 m to 73 m within the Surficial Aquifer System (SAS). Ages as determined by 3H/3He techniques indicate that groundwater within the upper 28 m originated after the nuclear era (within the last 42 yr) and below 28 m before then with evidence of some mixing at the interface. Inter-annual variation of the 3H/3He ages within the upper 28 m was significant throughout the three year investigation, suggesting varying hydrologic conditions. The age of the shallow groundwater in the southern regions of ENP (Rocky Glades and Taylor Slough) tended to be younger following times of high water level when the dominant direction of groundwater flow water was to the southeast. In the same region, significantly older groundwater was observed following times of low water levels and a shift in the groundwater flow direction toward the southwest. Near the canals, the reverse occurred with the ages of shallow groundwater tending to be younger following times of low water levels, suggesting a greater influence of recharge water from the canals to the surrounding aquifer. Although water levels and the direction of hydrologic gradients vary greatly within a 3-month time period, the average age of the shallow (<28 m) fresh groundwaters was 17 +/- 9 years. In the region of Taylor Slough Bridge, younger groundwater was consistently detected below older groundwater in the Biscayne Aquifer suggesting a preferential flow path to the deeper formation. An increase in 4He with depth suggests that radiogenic 4He produced in the underlying Hawthorn Group is dispersed into the SAS. Higher Δ 4He values in brackish groundwaters compared to fresh waters from similar depths indicate an enhanced vertical transport of 4He in the seawater mixing zone. Seawater intrudes at distances of 6 to 28 km at shallow depths (<28 m) in the SAS along the entire coastline of ENP and further inland at depths up to 68 m thereby preventing the direct discharge of fresh groundwater from the SAS into downgradient marine systems. Instead, brackish to saline groundwater is expected to discharge to the overlying surface water of the Everglades and possibly along the coastlines of Florida Bay and the Gulf of Mexico over an approximately 6 to 28 km wide strip that parallels the coastline.

Seawater intrusion in karstic, coastal aquifers: Current challenges and future scenarios in the Taranto area (southern Italy).

PubMed

De Filippis, Giovanna; Foglia, Laura; Giudici, Mauro; Mehl, Steffen; Margiotta, Stefano; Negri, Sergio Luigi

2016-12-15

Mediterranean areas are characterized by complex hydrogeological systems, where management of freshwater resources, mostly stored in karstic, coastal aquifers, is necessary and requires the application of numerical tools to detect and prevent deterioration of groundwater, mostly caused by overexploitation. In the Taranto area (southern Italy), the deep, karstic aquifer is the only source of freshwater and satisfies the main human activities. Preserving quantity and quality of this system through management policies is so necessary and such task can be addressed through modeling tools which take into account human impacts and the effects of climate changes. A variable-density flow model was developed with SEAWAT to depict the "current" status of the saltwater intrusion, namely the status simulated over an average hydrogeological year. Considering the goals of this analysis and the scale at which the model was built, the equivalent porous medium approach was adopted to represent the deep aquifer. The effects that different flow boundary conditions along the coast have on the transport model were assessed. Furthermore, salinity stratification occurs within a strip spreading between 4km and 7km from the coast in the deep aquifer. The model predicts a similar phenomenon for some submarine freshwater springs and modeling outcomes were positively compared with measurements found in the literature. Two scenarios were simulated to assess the effects of decreased rainfall and increased pumping on saline intrusion. Major differences in the concentration field with respect to the "current" status were found where the hydraulic conductivity of the deep aquifer is higher and such differences are higher when Dirichlet flow boundary conditions are assigned. Furthermore, the Dirichlet boundary condition along the coast for transport modeling influences the concentration field in different scenarios at shallow depths; as such, concentration values simulated under stressed conditions are lower than those simulated under undisturbed conditions. Copyright © 2016 Elsevier B.V. All rights reserved.

Hypoaigic influences on groundwater flux to a seasonally saline river

NASA Astrophysics Data System (ADS)

Trefry, M. G.; Svensson, T. J. A.; Davis, G. B.

2007-03-01

SummaryHypoaigic zones are aquifer volumes close to and beneath the shores of saline surface water bodies, and are characterized by the presence of time-dependent natural convection and chemical stratification. When transient and cyclic processes are involved there is significant potential for complex flow and reaction in the near-shore aquifer, presenting a unique challenge to pollutant risk assessment methodologies. This work considers the nature of some hypoaigic processes generated by the seasonally saline Canning River of Western Australia near a site contaminated by petroleum hydrocarbons. A dissolved hydrocarbon plume migrates within the shallow superficial aquifer to the nearby bank of the Canning River. Beneath the river bank a zone of complex fluid mixing is established by seasonal and tidal influences. Understanding this complexity and the subsequent ramifications for local biogeochemical conditions is critical to inferring the potential for degradation of advecting contaminants. A range of modelling approaches throws light on the overall topographic controls of discharge to the river, on the saline convection processes operating under the river bank, on the potential for fluid mixing, and on the various important time scales in the system. Saline distributions simulated within the aquifer hypoaigic zone are in at least qualitative agreement with previous field measurements at the site and are strongly affected by seasonal influences. Groundwater seepage velocities at the shoreline are found to be positively correlated with river salinity. Calculations of fluid age distributions throughout the system show sensitivity to dispersivity values; however, maximum fluid ages under the river appear to be diffusion limited to a few decades. The saline convection cell in the aquifer defines a zone of strong dispersive dilution of aged (many decades) deep aquifer fluids with relatively young (several months) riverine fluids. Seasonal recharge and river salinity cycles induce regular perturbations to the convection cell, yielding intra-annual variations of 50% in seepage velocity and almost 30% in wedge penetration distance at the plume location.

Uranium and radon in ground water in the lower Illinois River basin

USGS Publications Warehouse

Morrow, William S.

2001-01-01

Uranium and radon are present in ground water throughout the United States, along with other naturally occurring radionuclides. The occurrence and distribution of uranium and radon are of concern because these radionuclides are carcinogens that can be ingested through drinking water. As part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program, water samples were collected and analyzed for uranium and radon from 117 wells in four aquifers in the lower Illinois River Basin (LIRB) from 1996 to 1997. The aquifers were the shallow glacial drift deposits of the Bloomington Ridged Plain (BRP) not overlying a buried bedrock valley (BRP N/O BV), shallow glacial drift deposits of the BRP overlying the Mahomet Buried Bedrock Valley (BRP O/L MBBV), shallow glacial drift deposits of the Galesburg/Springfield Plain not overlying a buried bedrock valley (GSP N/O BV), and the deep glacial drift deposits of the Mahomet Buried Bedrock Valley (MBBV). Uranium was detected in water samples from all aquifers except the MBBV and ranged in concentration from less than 1 microgram per liter ( ? g/L) to 17 ? g/L. Uranium concentrations did not exceed 20 ? g/L, the proposed U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) at the time of sampling (1996?97). The current (2001) promulgated MCL is 30 ? g/L (U.S. Environmental Protection Agency, 2000). The highest median uranium concentration (2.0 ? g/L) among the four aquifers was in the BRP N/O BV. Uranium most often occurred in oxidizing and sulfate-rich water. Radon was detected in water samples from all aquifers in the LIRB. Radon concentrations in all aquifers ranged from less than 80 picocuries per liter (pCi/L) to 1,300 pCi/L. Of 117 samples, radon concentrations exceeded 300 pCi/L (the proposed USEPA MCL) in 34 percent of the samples. Radon concentrations exceeded 300 pCi/L in more than one-half of the samples from the GSP N/O BV and the BRP O/L MBBV. No sample exceeded the proposed Alternative Maximum Contaminant Level (AMCL) of 4,000 pCi/L. Concentrations of uranium and radon were not correlated.

Optimization of DRASTIC method by artificial neural network, nitrate vulnerability index, and composite DRASTIC models to assess groundwater vulnerability for unconfined aquifer of Shiraz Plain, Iran.

PubMed

Baghapour, Mohammad Ali; Fadaei Nobandegani, Amir; Talebbeydokhti, Nasser; Bagherzadeh, Somayeh; Nadiri, Ata Allah; Gharekhani, Maryam; Chitsazan, Nima

2016-01-01

Extensive human activities and unplanned land uses have put groundwater resources of Shiraz plain at a high risk of nitrate pollution, causing several environmental and human health issues. To address these issues, water resources managers utilize groundwater vulnerability assessment and determination of protection. This study aimed to prepare the vulnerability maps of Shiraz aquifer by using Composite DRASTIC index, Nitrate Vulnerability index, and artificial neural network and also to compare their efficiency. The parameters of the indexes that were employed in this study are: depth to water table, net recharge, aquifer media, soil media, topography, impact of the vadose zone, hydraulic conductivity, and land use. These parameters were rated, weighted, and integrated using GIS, and then, used to develop the risk maps of Shiraz aquifer. The results indicated that the southeastern part of the aquifer was at the highest potential risk. Given the distribution of groundwater nitrate concentrations from the wells in the underlying aquifer, the artificial neural network model offered greater accuracy compared to the other two indexes. The study concluded that the artificial neural network model is an effective model to improve the DRASTIC index and provides a confident estimate of the pollution risk. As intensive agricultural activities are the dominant land use and water table is shallow in the vulnerable zones, optimized irrigation techniques and a lower rate of fertilizers are suggested. The findings of our study could be used as a scientific basis in future for sustainable groundwater management in Shiraz plain.

Geoenvironmental and structural studies for developing new water resources in arid and semi-arid regions using remote sensing and GIS

NASA Astrophysics Data System (ADS)

Amer, Reda Mohammed

2011-12-01

Water crises are rising with increasing world population and decreasing of freshwater resources. This problem is magnified in the arid and semi-arid regions because surface water resources are very limited and highly unreliable and therefore groundwater is the primary source of water supply in these regions. This study presents an integrated approach for the identification of groundwater occurrences using remote sensing, geological, and geophysical data, and establishing sustainable paths to groundwater management. The Central Eastern Desert (CED) of Egypt was selected as a test site for this study because its climate is arid and there is an urgent need to identify potential areas for groundwater accumulations. Field investigations indicated that the CED has three types of aquifers; shallow alluvial (SA), and fracture zone (FZ) aquifers in the valley depressions, and deep aquifers in the sedimentary succession that range in age from Late Cretaceous to Recent in the marginal extensional sub-basins (ESB) along the Red Sea coast. I developed three models: (1) a Geographic Information System (GIS) model for groundwater potential in the SA and FZ shallow aquifers; (2) a kinematic model for the development of the ESB; and (3) a groundwater budget model for the ESB aquifers. The GIS model is based on the analysis of remote sensing data of the Phased Array L-band Synthetic Aperture Radar, the Landsat Enhanced Thematic Mapper Plus, and the Advanced Spaceborne Thermal Emission and Reflection Radiometer digital elevation model. The model was evaluated and proven successful against the existing shallow water wells, and by geophysical surveys using Ground Penetrating Radar and Geoelectric methods. The kinematic model indicated that the ESB were formed in the orthogonal rifting phase in the late Oligocene that is followed by oblique rifting phase during the early Miocene which resulted to the en-echelon pattern of the inland ESB and nucleation of the rift depression into segments separated by oblique-slip accommodation zones. The groundwater budget model shows that the ESB aquifers have considerable amounts of paleowater that can be purified and used for drinking. The renewable groundwater of SA and FZ aquifers can be used for herding, irrigation, and ore dressing in the mining zones.

Interaction of cold-water aquifers with exploited reservoirs of the Cerro Prieto geothermal system

USGS Publications Warehouse

Truesdell, Alfred; Lippmann, Marcelo

1990-01-01

Cerro Prieto geothermal reservoirs tend to exhibit good hydraulic communication with adjacent cool groundwater aquifers. Under natural state conditions the hot fluids mix with the surrounding colder waters along the margins of the geothermal system, or discharge to shallow levels by flowing up fault L. In response to exploitation reservoir pressures decrease, leading to changes in the fluid flow pattern in the system and to groundwater influx. The various Cerro Prieto reservoirs have responded differently to production, showing localized near-well or generalized boiling, depending on their access to cool-water recharge. Significant cooling by dilution with groundwater has only been observed in wells located near the edges of the field. In general, entry of cool water at Cerro Prieto is beneficial because it tends to maintain reservoir pressures, restrict boiling, and lengthen the life and productivity of wells.

NLEAP/GIS approach for identifying and mitigating regional nitrate-nitrogen leaching

USGS Publications Warehouse

Shaffer, M.J.; Hall, M.D.; Wylie, B.K.; Wagner, D.G.; Corwin, D.L.; Loague, K.

1996-01-01

Improved simulation-based methodology is needed to help identify broad geographical areas where potential NO3-N leaching may be occurring from agriculture and suggest management alternatives that minimize the problem. The Nitrate Leaching and Economic Analysis Package (NLEAP) model was applied to estimate regional NO3-N leaching in eastern Colorado. Results show that a combined NLEAP/GIS technology can be used to identify potential NO3-N hot spots in shallow alluvial aquifers under irrigated agriculture. The NLEAP NO3-N Leached (NL) index provided the most promising single index followed by NO3-N Available for Leaching (NAL). The same combined technology also shows promise in identifying Best Management Practice (BMP) methods that help minimize NO3-N leaching in vulnerable areas. Future plans call for linkage of the NLEAP/GIS procedures with groundwater modeling to establish a mechanistic analysis of agriculture-aquifer interactions at a regional scale.

The potential for convection and implications for geothermal energy in the Perth Basin, Western Australia

NASA Astrophysics Data System (ADS)

Sheldon, Heather A.; Florio, Brendan; Trefry, Michael G.; Reid, Lynn B.; Ricard, Ludovic P.; Ghori, K. Ameed R.

2012-11-01

Convection of groundwater in aquifers can create areas of anomalously high temperature at shallow depths which could be exploited for geothermal energy. Temperature measurements in the Perth Basin (Western Australia) reveal thermal patterns that are consistent with convection in the Yarragadee Aquifer. This observation is supported by Rayleigh number calculations, which show that convection is possible within the range of aquifer thickness, geothermal gradient, salinity gradient and permeability encountered in the Yarragadee Aquifer, assuming that the aquifer can be treated as a homogeneous anisotropic layer. Numerical simulations of convection in a simplified model of the Yarragadee Aquifer show that: (1) the spacing of convective upwellings can be predicted from aquifer thickness and permeability anisotropy; (2) convective upwellings may be circular or elongate in plan view; (3) convective upwellings create significant temperature enhancements relative to the conductive profile; (4) convective flow rates are similar to regional groundwater flow rates; and (5) convection homogenises salinity within the aquifer. Further work is required to constrain the average horizontal and vertical permeability of the Yarragadee Aquifer, to assess the validity of treating the aquifer as a homogeneous anisotropic layer, and to determine the impact of realistic aquifer geometry and advection on convection.

Fast formation of supergene Mn oxides/hydroxides under acidic conditions in the oxic/anoxic transition zone of a shallow aquifer.

PubMed

Schäffner, F; Merten, D; Pollok, K; Wagner, S; Knoblauch, S; Langenhorst, F; Büchel, G

2015-12-01

Extensive uranium mining in the former German Democratic Republic (GDR) in eastern Thuringia and Saxony took place during the period of 1946-1990. During mining activities, pelitic sediments rich in organic carbon and uranium were processed and exposed to oxygen. Subsequent pyrite oxidation and acidic leaching lead to partial contamination of the area with heavy metals and acid mine drainage (AMD) even few years after completion of remediation. One of those areas is the former heap Gessen (Ronneburg, Germany) were the residual contamination can be found 10 m under the base of the former heap containing partly permeable drainage channels. Actually, in such a system, a rapid but locally restricted mineralization of Mn oxides takes place under acidic conditions. This formation can be classified as a natural attenuation process as certain heavy metals, e.g., Cd (up to 6 μg/g), Ni (up to 311 μg/g), Co (up to 133 μg/g), and Zn (up to 104 μg/g) are bound to this phases. The secondary minerals occur as colored layers close to the shallow aquifer in glacial sediments and could be identified as birnessite and todorokite as Mn phase. The thermodynamic model shows that even small changes in the system are sufficient to shift either the pH or the Eh in the direction of stable Mn oxide phases in this acidic system. As a consequence of 9-15-year-long formation process (or even less), the supergene mineralization provides a cost-efficient contribution for remediation (natural attenuation) strategies of residual with heavy metals (e.g., Cd, Co, Ni, Zn) contaminated substrates.

Microbial Indicators, Pathogens, and Antibiotic Resistance in Groundwater Impacted by Animal Farming: Field Scale to Basin Scale

NASA Astrophysics Data System (ADS)

Harter, T.; Li, X.; Atwill, E. R.; Packman, A. I.

2015-12-01

Several surveys of microbial indicators and pathogens were conducted to determine the impact of confined animal farming operations (CAFOs) on shallow, local, and regional groundwater quality in the Central Valley aquifer system, California. The aquifer system consists of highly heterogeneous, alluvial, unconsolidated coarse- to fine-grained sediments and is among the largest aquifers in the U.S.. Overlying landuse includes 3 million ha of irrigated agriculture and 1.7 million mature dairy cows in nearly 1,500 CAFOs. A multi-scale survey of water-borne indicator pathogens (Enterococcus spp. and generic E. coli) and of three water-borne pathogens (Campylobacter, Salmonella, and E. coli O157:H7) was conducted at five different spatial scales, increasing with distance from animal sources of these enteric microbial organisms: moist surfaces within individual CAFO sub-systems (calf-hutches, heifer corrals, mature cow stalls, hospital barn etc.), first encountered (shallow) groundwater immediately below these sub-systems, production aquifer below CAFOs, production aquifer near CAFOs, and production aquifer away from CAFOs. Where found, indicator pathogens were tested for antibiotic resistance. Hundreds of samples were collected at each scale: continuously during irrigation events and seasonally over a multi-year period at the three smaller site-scales; and in a one-time survey at the two larger, regional scales. All three pathogens were frequently detected in moist surface samples across CAFO sub-systems, albeit at concentrations several orders of magnitude lower than enteric indicators. Two of the three pathogens (but not Campylobacter) were also detected in first encountered groundwater, at 3-9 m below ground surface, in 1% of samples. No pathogens were found at the production aquifer scales. Generic E. coli was detected in ¼ of first encountered groundwater samples, and in 4% of production aquifer samples, while Enterococcus spp. was ubiquitously present across the three site scales on CAFOs and in ¼ of production aquifer samples near and away from CAFOs. Two thirds of E. coli and five in six Enterococcus exhibited resistance to multiple (> 2) antibiotics. Field monitoring results are consistent with fate and transport modeling that accounts for heterogeneity in aquifer systems.

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

USGS Publications Warehouse

Bexfield, Laura M.; Jurgens, Bryant C.; Crilley, Dianna M.; Christenson, Scott C.

2012-01-01

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

Controls on Methane Occurrences in Aquifers Overlying the Eagle Ford Shale Play, South Texas.

PubMed

Nicot, Jean-Philippe; Larson, Toti; Darvari, Roxana; Mickler, Patrick; Uhlman, Kristine; Costley, Ruth

2017-07-01

Assessing natural vs. anthropogenic sources of methane in drinking water aquifers is a critical issue in areas of shale oil and gas production. The objective of this study was to determine controls on methane occurrences in aquifers in the Eagle Ford Shale play footprint. A total of 110 water wells were tested for dissolved light alkanes, isotopes of methane, and major ions, mostly in the eastern section of the play. Multiple aquifers were sampled with approximately 47 samples from the Carrizo-Wilcox Aquifer (250-1200 m depth range) and Queen City-Sparta Aquifer (150-900 m depth range) and 63 samples from other shallow aquifers but mostly from the Catahoula Formation (depth <150 m). Besides three shallow wells with unambiguously microbial methane, only deeper wells show significant dissolved methane (22 samples >1 mg/L, 10 samples >10 mg/L). No dissolved methane samples exhibit thermogenic characteristics that would link them unequivocally to oil and gas sourced from the Eagle Ford Shale. In particular, the well water samples contain very little or no ethane and propane (C1/C2+C3 molar ratio >453), unlike what would be expected in an oil province, but they also display relatively heavier δ 13 C methane (>-55‰) and δD methane (>-180‰). Samples from the deeper Carrizo and Queen City aquifers are consistent with microbial methane sourced from syndepositional organic matter mixed with thermogenic methane input, most likely originating from deeper oil reservoirs and migrating through fault zones. Active oxidation of methane pushes δ 13 C methane and δD methane toward heavier values, whereas the thermogenic gas component is enriched with methane owing to a long migration path resulting in a higher C1/C2+C3 ratio than in the local reservoirs. © 2017, National Ground Water Association.

Use of bromide:Chloride ratios to differentiate potential sources of chloride in a shallow, unconfined aquifer affected by brackish-water intrusion

USGS Publications Warehouse

Andreasen, D.C.; Fleck, W.B.

1997-01-01

Brackish water from Chesapeake Bay and its tributaries has entered the Aquia aquifer in east-central Anne Arundel County, Maryland, USA. This determination was made based on chloride analyses of water samples collected in wells screened in the Aquia aquifer between October 1988 and May 1989. The Aquia aquifer, which is composed of fine- to medium-grained sand, is a shallow, unconfined aquifer in this area. Land use is primarily urban, consisting of a mixture of residential and light commercial areas. Associated with the urban setting is the potential for chloride contamination to enter the Aquia aquifer from anthropogenic sources, such as residential septic-tank effluent, leaky public sewer lines, road-deicing salt, stormwater infiltration basins, and domestic water-conditioning recharge effluent. In order to map the distribution of bay-water intrusion in the Aquia aquifer, chloride derived from Chesapeake Bay was differentiated from chloride derived from anthropogenic sources by comparing the ratio of dissolved bromide to dissolved chloride (bromide:chloride) in groundwater to the distinctive ratio in Chesapeake Bay water. Two additional factors considered in determining the source of the chloride were nitrogen concentrations and well-screen positions of sampled wells in relation to the estimated depth of the fresh-water/brackish-water interface. Of 36 Aquia-aquifer water samples with chloride concentrations greater than 30 mg/L, 22 had bromide:chloride ratios similar to the ratio in Chesapeake Bay water, an indication that bay water is the primary source of the chloride. Of the other 14 samples with bromide:chloride ratios dissimilar to the ratio in Chesapeake Bay water, seven were from wells where screen positions were substantially above the estimated fresh-water/brackish-water interface. Three of these samples had nitrogen concentrations (as nitrite plus nitrate) greater than 3.0 mg/L, an indication that chloride in these groundwater samples comes from anthropogenic sources, at least in part.

Natural dissolved organic matter dynamics in karstic aquifer: O'Leno Sink-Rise system, Florida, USA

NASA Astrophysics Data System (ADS)

Jin, J.; Zimmerman, A. R.

2010-12-01

Natural dissolved organic matter (NDOM) dynamics in karstic aquifer remain poorly understood due to the inaccessibility and heterogeneity of the subsurface. Because the Santa Fe River sinks into the Floridan Aquifer and emerges 6 km down gradient, the O'Leno Sink-Rise system in Northern Florida provides an ideal setting to study NDOM transformation in groundwater. Water samples were collected at both high and low temporal resolutions over 3 years from the River Sink, Rise, and a series of shallow and deep wells. Analyses of dissolved organic and inorganic carbon, stable isotopic, and spectrophotometry (excitation-emission matrix or EEM) show that reversals of hydrologic head gradient in the conduit and matrix are closely related to the delivery of NDOM to the aquifer. In addition, the relative influence of biotic and abiotic processes varies along spatiotemporal gradients; regions of the aquifer with greatest connectivity to surface water (new NDOM and terminal electron acceptor supply) see the most microbial transformation of NDOM, while those with least connectivity see relatively greater abiotic transformation of NDOM. A source water mixing model was established for the Sink-Rise system using Mg2+ and SO42- concentrations from three end-members identified as allogenic recharge, upwelling deep water, and shallow groundwater of the Upper Floridan Aquifer. Biogeochemical processes were quantified after accounting for changes that occurred due to source water mixing, according to the model. In addition to NDOM remineralization by subsurface microbes which occurred mostly during wet periods, adsorption of NDOM onto aquifer materials as well as release of NDOM from aquifer materials was also observed. During wet periods when DOC-rich conduit water entered the matrix, progressive NDOM remineralization was found along the preferential flow paths from the conduits into the matrices. Both biotic and abiotic NDOM transformation processes were found to control channel dissolution and thus the subsurface geomorphology, all of which are linked to hydrology and climate patterns.

Response of the Rio Grande and shallow ground water in the Mesilla Bolson to irrigation, climate stress, and pumping

USGS Publications Warehouse

Walton, J.; Ohlmacher, G.; Utz, D.; Kutianawala, M.

1999-01-01

The El Paso-Ciudad Juarez metropolitan area obtains its water from the Rio Grande and intermontane-basin aquifers. Shallow ground water in this region is in close communications with the surface water system. A major problem with both systems is salinity. Upstream usage of the water in the Rio Grande for irrigation and municipalities has led to concentration of soluble salts to the point where the surface water commonly exceeds drinking water standards. Shallow ground water is recharged by surface water (primarily irrigation canals and agricultural fields) and discharges to surface water (agricultural drains) and deeper ground water. The source of water entering the Rio Grande varies seasonally. During the irrigation season, water is released from reservoirs and mixes with the return flow from irrigation drains. During the non-irrigation season (winter), flow is from irrigation drains and river water quality is indicative of shallow ground water. The annual cycle can be ascertained from the inverse correlation between ion concentrations and discharge in the river. Water-quality data indicate that the salinity of shallow ground water increases each year during a drought. Water-management strategies in the region can affect water quality. Increasing the pumping rate of water-supply wells will cause shallow ground water to flow into the deeper aquifers and degrade the water quality. Lining the canals in the irrigation system to stop water leakage will lead to water quality degradation in shallow ground water and, eventually, deep ground water by removing a major source of high quality recharge that currently lowers the salinity of the shallow ground water.

Strategies towards an optimized use of the shallow geothermal potential

NASA Astrophysics Data System (ADS)

Schelenz, S.; Firmbach, L.; Kalbacher, T.; Goerke, U.; Kolditz, O.; Dietrich, P.; Vienken, T.

2013-12-01

Thermal use of the shallow subsurface for heat generation, cooling and thermal energy storage is increasingly gaining importance in reconsideration of future energy supplies, e.g. in the course of German energy transition, with application shifting from isolated to intensive use. The planning and dimensioning of (geo-)thermal applications is strongly influenced by the availability of exploration data. Hence, reliable site-specific dimensioning of systems for the thermal use of the shallow subsurface will contribute to an increase in resource efficiency, cost reduction during installation and operation, as well as reduction of environmental impacts and prevention of resource over-exploitation. Despite large cumulative investments that are being made for the utilization of the shallow thermal potential, thermal energy is in many cases exploited without prior on-site exploration and investigation of the local geothermal potential, due to the lack of adequate and cost-efficient exploration techniques. We will present new strategies for an optimized utilization of urban thermal potential, showcased at a currently developed residential neighborhood with high demand for shallow geothermal applications, based on a) enhanced site characterization and b) simulation of different site specific application scenarios. For enhanced site characterization, surface geophysics and vertical high resolution direct push-profiling were combined for reliable determination of aquifer structure and aquifer parameterization. Based on the site characterization, different site specific geothermal application scenarios, including different system types and system configurations, were simulated using OpenGeoSys to guarantee an environmental and economic sustainable thermal use of the shallow subsurface.

Groundwater chemistry and occurrence of arsenic in the Meghna floodplain aquifer, southeastern Bangladesh

USGS Publications Warehouse

Zahid, A.; Hassan, M.Q.; Balke, K.-D.; Flegr, M.; Clark, D.W.

2008-01-01

Dissolved major ions and important heavy metals including total arsenic and iron were measured in groundwater from shallow (25-33 m) and deep (191-318 m) tube-wells in southeastern Bangladesh. These analyses are intended to help describe geochemical processes active in the aquifers and the source and release mechanism of arsenic in sediments for the Meghna Floodplain aquifer. The elevated Cl- and higher proportions of Na+ relative to Ca2+, Mg2+, and K+ in groundwater suggest the influence by a source of Na+ and Cl-. Use of chemical fertilizers may cause higher concentrations of NH 4+ and PO 43- in shallow well samples. In general, most ions are positively correlated with Cl-, with Na+ showing an especially strong correlation with Cl-, indicating that these ions are derived from the same source of saline waters. The relationship between Cl-/HCO 3- ratios and Cl- also shows mixing of fresh groundwater and seawater. Concentrations of dissolved HCO 3- reflect the degree of water-rock interaction in groundwater systems and integrated microbial degradation of organic matter. Mn and Fe-oxyhydroxides are prominent in the clayey subsurface sediment and well known to be strong adsorbents of heavy metals including arsenic. All five shallow well samples had high arsenic concentration that exceeded WHO recommended limit for drinking water. Very low concentrations of SO 42- and NO 3- and high concentrations of dissolved Fe and PO 43- and NH 4+ ions support the reducing condition of subsurface aquifer. Arsenic concentrations demonstrate negative co-relation with the concentrations of SO 42- and NO 3- but correlate weakly with Mo, Fe concentrations and positively with those of P, PO 43- and NH 4+ ions. ?? 2007 Springer-Verlag.

Integrated geophysical application to investigate groundwater potentiality of the shallow Nubian aquifer at northern Kharga, West

NASA Astrophysics Data System (ADS)

Younis, Abdellatif; Soliman, Mamdouh; Moussa, Salah; Massoud, Usama; ElNabi, Sami Abd; Attia, Magdy

2016-06-01

Continuous evaluation of groundwater aquifers in the basin of Kharga Oasis is very important. Groundwater in Kharga Oasis represents the major factor for the development plans of this area as it is the sole source for water supplies required for drinking and irrigation purposes. This study is concerned by analyzing the groundwater potentiality of the shallow aquifer at the northern part of Kharga basin by integrated application of Vertical Electrical Sounding (VES) and Time domain Electromagnetic (TEM) techniques. The VES data were measured at 28 points arranged along a north-south trending line by applying Schlumberger array with a maximum current-electrode spacing (AB) of 1000 m. The TEM data were measured at 167 points arranged along 11 east-west trending lines by using a single square loop with 50 m loop-side length. The VES and TEM data have been individually inverted, where the VES models were used as initial models for TEM data inversion. The final models were used for construction of 17 geoelectrical sections and 5 contour maps describing subsurface water-bearing layers at the investigated area. Correlation of the obtained models with geologic, hydrogeologic and borehole information indicates that the shallow aquifer comprises two zones (A-up) and (B-down) separated by a highly conductive shale layer. The upper zone (A) is composed of fine to medium sand with thin clay intercalations. It exhibits low to moderate resistivities. This zone was detected at depth values ranging from 10 to 70 m below ground surface (bgs) and shows a thickness of 25-90 m. The lower zone (B) exhibits moderate to high resistivity values with expected good water quality. The upper surface of zone B was detected at 60-165 m depth.

Temperature-induced impacts on groundwater quality and arsenic mobility in anoxic aquifer sediments used for both drinking water and shallow geothermal energy production.

PubMed

Bonte, Matthijs; van Breukelen, Boris M; Stuyfzand, Pieter J

2013-09-15

Aquifers used for the production of drinking water are increasingly being used for the generation of shallow geothermal energy. This causes temperature perturbations far beyond the natural variations in aquifers and the effects of these temperature variations on groundwater quality, in particular trace elements, have not been investigated. Here, we report the results of column experiments to assess the impacts of temperature variations (5°C, 11°C, 25°C and 60°C) on groundwater quality in anoxic reactive unconsolidated sandy sediments derived from an aquifer system widely used for drinking water production in the Netherlands. Our results showed that at 5 °C no effects on water quality were observed compared to the reference of 11°C (in situ temperature). At 25°C, As concentrations were significantly increased and at 60 °C, significant increases were observed pH and DOC, P, K, Si, As, Mo, V, B, and F concentrations. These elements should therefore be considered for water quality monitoring programs of shallow geothermal energy projects. No consistent temperature effects were observed on Na, Ca, Mg, Sr, Fe, Mn, Al, Ba, Co, Cu, Ni, Pb, Zn, Eu, Ho, Sb, Sc, Yb, Ga, La, and Th concentrations, all of which were present in the sediment. The temperature-induced chemical effects were probably caused by (incongruent) dissolution of silicate minerals (K and Si), desorption from, and potentially reductive dissolution of, iron oxides (As, B, Mo, V, and possibly P and DOC), and mineralisation of sedimentary organic matter (DOC and P). Copyright © 2013 Elsevier Ltd. All rights reserved.

Methane Occurrences in Aquifers Overlying the Barnett Shale Play with a Focus on Parker County, Texas.

PubMed

Nicot, Jean-Philippe; Mickler, Patrick; Larson, Toti; Clara Castro, M; Darvari, Roxana; Uhlman, Kristine; Costley, Ruth

2017-07-01

Clusters of elevated methane concentrations in aquifers overlying the Barnett Shale play have been the focus of recent national attention as they relate to impacts of hydraulic fracturing. The objective of this study was to assess the spatial extent of high dissolved methane previously observed on the western edge of the play (Parker County) and to evaluate its most likely source. A total of 509 well water samples from 12 counties (14,500 km 2 ) were analyzed for methane, major ions, and carbon isotopes. Most samples were collected from the regional Trinity Aquifer and show only low levels of dissolved methane (85% of 457 unique locations <0.1 mg/L). Methane, when present is primarily thermogenic (δ 13 C 10th and 90th percentiles of -57.54 and -39.00‰ and C1/C2+C3 ratio 10th, 50th, and 90th percentiles of 5, 15, and 42). High methane concentrations (>20 mg/L) are limited to a few spatial clusters. The Parker County cluster area includes historical vertical oil and gas wells producing from relatively shallow formations and recent horizontal wells producing from the Barnett Shale (depth of ∼1500 m). Lack of correlation with distance to Barnett Shale horizontal wells, with distance to conventional wells, and with well density suggests a natural origin of the dissolved methane. Known commercial very shallow gas accumulations (<200 m in places) and historical instances of water wells reaching gas pockets point to the underlying Strawn Group of Paleozoic age as the main natural source of the dissolved gas. © 2017, National Ground Water Association.

Availability and quality of water from drift aquifers in Marshall, Pennington, Polk, and Red Lake counties, northwestern Minnesota

USGS Publications Warehouse

Lindgren, R.J.

1996-01-01

Water samples analyzed for nitrate had nitrate concentrations below the reporting limit (0.05 milligrams per liter) in 10 out of 23 wells. Two samples had nitrate concentrations greater than 10 milligrams per liter. Pesticide concentrations in water samples from 17 wells screened in unconfined and shallow confined aquifers were below or only slightly above laboratory reporting limits.

La prospection geothermique de surface au Maroc: hydrodynamisme, anomalies thermiques et indices de surfaceGeothermal prospecting in Morocco: hydrodynamics, thermal anomalies and surface indices

NASA Astrophysics Data System (ADS)

Zarhloule, Y.; Lahrache, A.; Ben Abidate, L.; Khattach, D.; Bouri, S.; Boukdir, A.; Ben Dhia, H.

2001-05-01

Shallow geothermal prospecting ( < 700 m) has been performed in four zones in Morocco for which few deep data are available: northwestern basin, northeastern basin, Tadla Basin and Agadir Basin. These areas are different geologically and hydrogeologically. The temperature data from 250 wells at depths between 15 and 500 m have been analysed in order to estimate the natural geothermal gradient in these areas, to determine the principal thermal anomalies, to identify the main thermal indices and to characterise the recharge, discharge and potential mixing limits of the aquifers. The hydrostratigraphical study of each basin revealed several potential reservoir layers in which the Turonian carbonate aquifer (Tadal and Agadir Basins) and Liassic acquifer (Moroccan northwestern and northeastern basins) are the most important hot water reservoirs in Morocco. The recharge zones of each aquifer are characterised by high topography, high water potential, shallow cold water, low geothermal gradient and negative anomalies. The discharge zones are characterized by low topography, low piezometric level, high geothermal gradient, high temperature with hot springs and positive anomalies. The main thermal indices and the principal thermal anomalies that coincide with the artesian zones of the Turonian and Liassic aquifers have been identified.

Estimates of nitrogen loads entering Long Island Sound from ground water and streams on Long Island, New York, 1985–96

USGS Publications Warehouse

Scorca, Michael P.; Monti, Jack

2001-01-01

Fresh ground water that discharges from the northern part of Long Island's aquifer system to Long Island Sound contains elevated concentrations of nitrogen from agricultural fertilizer, domestic waste and fertilizer, and precipitation. The nitrogen contributes to algal blooms, which consume oxygen as the algae die and decompose. The resulting low dissolved oxygen concentrations (hypoxia) adversely affect plant and animal populations in Long Island Sound.The four major streams on the north shore of Long Island that have long-term discharge and water-quality records were selected for analysis of geographic, long-term, and seasonal trends in nitrogen concentration. Nitrogen concentrations generally decrease eastward among three Nassau County streams, then increase again at the easternmost stream, Nissequogue River in Suffolk County. A long-term (1970-96) increase in total nitrogen concentrations in the Nissequogue River also is evident. Seasonal fluctuations in nitrogen concentrations in all four streams reflect chemical reactions and microbial activity in the stream system, so total nitrogen concentrations in the three easternmost streams generally were lowest during summer and highest in winter, whereas those in the westernmost stream (Glen Cove Creek) were highest during summer and lowest in winter.The nitrogen loads discharged to Long Island Sound from each of the four streams for each year during 1985-96 were calculated from the annual mean total nitrogen concentration and the annual mean discharge. Nissequogue River's annual mean discharges were 3 to 6 times larger than those of Glen Cove and Mill Neck Creeks, and produced the largest annual loads of nitrogen--65 to 149 ton/yr (59,000 to 135,000 kg/yr). Cold Spring Brook had the lowest annual mean discharges and annual mean total nitrogen concentrations of the four streams; its annual mean nitrogen load ranged from 1.2 to 2.8 ton/yr (1,100 to 2,500 kg/yr).The nitrogen load carried to Long Island Sound by shallow ground water from the north shore of Long Island was calculated from simulated shallow-aquifer discharges from Nassau and Suffolk Counties (9,200 and 21,400 Mgal/yr or 34,800,000 and 81,100,000 m3/yr, respectively) and median total nitrogen concentrations at selected wells (2.2 and 4.3 milligrams per liter as N, respectively). The resultant nitrogen load was 84 ton/yr (76,500 kg/yr) for Nassau County and 384 ton/yr (349,000 kg/yr) for Suffolk County.The nitrogen load carried to Long Island Sound by deep ground water from the north shore was calculated from simulated deep-aquifer discharges from Nassau and Suffolk counties (13,200 and 47,300 Mgal/yr or 50,000,000 and 179,000,000 m3/yr, respectively). The median nitrogen concentrations of deep ground water for the two counties were 1.62 and 1.34 mg/L as N, respectively. The resultant nitrogen load from deep-aquifer discharge was 89 ton/yr (81,000 kg/yr) for Nassau County and 265 ton/yr (240,000 kg/yr) for Suffolk County.Nitrogen loads entering Long Island Sound from the shallow aquifer underlying three areas of differing land use along the north shore--a sewered residential area in Nassau County, an unsewered residential area in Suffolk County, and an agricultural area in Suffolk County--were evaluated. The agricultural area contains no major streams and, therefore, produces very little surface runoff to Long Island Sound and substantially greater shallow-aquifer discharge than in the sewered and unsewered areas. Ground water in the agricultural area also had the highest median nitrogen concentration (9.9 mg/L as N) of the three land-use areas and discharged the largest estimated nitrogen load to Long Island Sound--152 ton/yr (138,000 kg/yr), which represents about 40 percent of the estimated total nitrogen load from Suffolk County. Ground water in the sewered area had the lowest nitrogen concentration (1.9 mg/L as N) and discharged the smallest nitrogen load to Long Island Sound--7.28 ton/yr (6,600 kg/yr). The analysis indicates that land use on the north shore of Long Island can greatly affect the nitrogen concentration of water in the shallow aquifer and the resultant nitrogen load discharged to Long Island Sound from ground water.

Assessing the mechanisms controlling the mobilization of arsenic in the arsenic contaminated shallow alluvial aquifer in the blackfoot disease endemic area.

PubMed

Liao, Vivian Hsiu-Chuan; Chu, Yu-Ju; Su, Yu-Chen; Lin, Po-Cheng; Hwang, Yaw-Huei; Liu, Chen-Wuing; Liao, Chung-Min; Chang, Fi-John; Yu, Chan-Wei

2011-12-15

High levels of arsenic in groundwater and drinking water represent a major health problem worldwide. Drinking arsenic-contaminated groundwater is a likely cause of blackfoot disease (BFD) in Taiwan, but mechanisms controlling the mobilization of arsenic present at elevated concentrations within aquifers remain understudied. Microcosm experiments using sediments from arsenic contaminated shallow alluvial aquifers in the blackfoot disease endemic area showed simultaneous microbial reduction of Fe(III) and As(V). Significant soluble Fe(II) (0.23±0.03 mM) in pore waters and mobilization of As(III) (206.7±21.2 nM) occurred during the first week. Aqueous Fe(II) and As(III) respectively reached concentrations of 0.27±0.01 mM and 571.4±63.3 nM after 8 weeks. We also showed that the addition of acetate caused a further increase in aqueous Fe(II) but the dissolved arsenic did not increase. We further isolated an As(V)-reducing bacterium native to aquifer sediments which showed that the direct enzymatic reduction of As(V) to the potentially more-soluble As(III) in pore water is possible in this aquifer. Our results provide evidence that microorganisms can mediate the release of sedimentary arsenic to groundwater in this region and the capacity for arsenic release was not limited by the availability of electron donors in the sediments. Copyright © 2011 Elsevier B.V. All rights reserved.

Near-surface, marine seismic-reflection data defines potential hydrogeologic confinement bypass in a tertiary carbonate aquifer, southeastern Florida

USGS Publications Warehouse

Cunningham, Kevin J.; Walker, Cameron; Westcott, Richard L.

2012-01-01

Approximately 210 km of near-surface, high-frequency, marine seismic-reflection data were acquired on the southeastern part of the Florida Platform between 2007 and 2011. Many high-resolution, seismic-reflection profiles, interpretable to a depth of about 730 m, were collected on the shallow-marine shelf of southeastern Florida in water as shallow as 1 m. Landward of the present-day shelf-margin slope, these data image middle Eocene to Pleistocene strata and Paleocene to Pleistocene strata on the Miami Terrace. This high-resolution data set provides an opportunity to evaluate geologic structures that cut across confining units of the Paleocene to Oligocene-age carbonate rocks that form the Floridan aquifer system.Seismic profiles image two structural systems, tectonic faults and karst collapse structures, which breach confining beds in the Floridan aquifer system. Both structural systems may serve as pathways for vertical groundwater flow across relatively low-permeability carbonate strata that separate zones of regionally extensive high-permeability rocks in the Floridan aquifer system. The tectonic faults occur as normal and reverse faults, and collapse-related faults have normal throw. The most common fault occurrence delineated on the reflection profiles is associated with karst collapse structures. These high-frequency seismic data are providing high quality structural analogs to unprecedented depths on the southeastern Florida Platform. The analogs can be used for assessment of confinement of other carbonate aquifers and the sealing potential of deeper carbonate rocks associated with reservoirs around the world.

Scoping Alternatives for Negative Emission Technologies. FRACCC - Possible Routes to Biomass-Derived Carbon Injection in Shallow Aquifers?

NASA Astrophysics Data System (ADS)

Correa Silva, R.; Larter, S.

2016-12-01

Atmospheric CO2 capture into biomass is one of the capture options for negative emission technologies, although proposed sequestration systems such as the permanent burial of total fresh biomass, algal lipids or soil amendment with biochar are yet to be successfully demonstrated as effective at scale. In the context of carbon sequestration, shallow geological reservoirs have not been exhaustively explored, even though they pose, away from groundwater protection zones, potentially low implementation cost, and geographically abundant potential carbon storage reservoirs. Typical carbon storage vectors considered, such as CO2 and biochar, are not suitable for shallow aquifer disposal, due either to cap rock containment requirements, or shallow aquifer CO2 densities, or issues related to formation damage from solid particles. Thus, a cost-effective technology, aimed at converting biomass into a large-scale carbon vector fit-for-disposal in shallow formations could be significant, linking promising carbon capture and containment strategies. In this work, we discuss the development of unconventional carbon vectors for subsurface storage in the form of Functionalized, Refractory and Aqueous Compatible Carbon Compounds (FRACCC), as a potential alternative negative emission technology (Larter et al., 2010). The concept is based on CO2 capture into microbial and algal biomass, followed by the modification of biomass constituents through facile chemical reactions aimed at rendering the biomass efficiently into a stable, biologically refractory but water soluble form, similar in some regards, to dissolved organic matter in the oceans, then sequestering the material in geological settings. As the injected material is not buoyant, containment specifications are more modest than for CO2 injection and potentially, more reservoirs could be accessible! This work analyses the technological, economic and societal implications of such potential FRACCC technologies, and make an assessment of whether such routes are likely to be technically, economically and politically viable.

CO 2 leakage impacts on shallow groundwater. Field-scale reactive-transport simulations informed by observations at a natural analog site

DOE PAGES

Keating, Elizabeth H.; Hakala, J. Alexandra; Viswanathan, Hari; ...

2013-03-01

It is challenging to predict the degree to which shallow groundwater might be affected by leaks from a CO 2 sequestration reservoir, particularly over long time scales and large spatial scales. In this study observations at a CO 2 enriched shallow aquifer natural analog were used to develop a predictive model which is then used to simulate leakage scenarios. This natural analog provides the opportunity to make direct field observations of groundwater chemistry in the presence of elevated CO 2, to collect aquifer samples and expose them to CO 2 under controlled conditions in the laboratory, and to test themore » ability of multiphase reactive transport models to reproduce measured geochemical trends at the field-scale. The field observations suggest that brackish water entrained with the upwelling CO 2 are a more significant source of trace metals than in situ mobilization of metals due to exposure to CO 2. The study focuses on a single trace metal of concern at this site: U. Experimental results indicate that cation exchange/adsorption and dissolution/precipitation of calcite containing trace amounts of U are important reactions controlling U in groundwater at this site, and that the amount of U associated with calcite is fairly well constrained. Simulations incorporating these results into a 3-D multi-phase reactive transport model are able to reproduce the measured ranges and trends between pH, pCO 2, Ca, total C, U and Cl -at the field site. Although the true fluxes at the natural analog site are unknown, the cumulative CO 2 flux inferred from these simulations are approximately equivalent to 37.8E-3 MT, approximately corresponding to a .001% leak rate for injection at a large (750 MW) power plant. The leakage scenario simulations suggest that if the leak only persists for a short time the volume of aquifer contaminated by CO 2-induced mobilization of U will be relatively small, yet persistent over 100 a.« less

Effects of the West Desert Pumping Project on Near-Surface Brine Resources in the Newfoundland Basin, Tooele and Box Elder Counties, Utah

NASA Astrophysics Data System (ADS)

White, W. W.; Jones, B. F.; Kohler, J. F.

2006-12-01

The Bureau of Land Management and U.S. Geological Survey have identified changes in Newfoundland Basin shallow-brine aquifer chemistry that resulted from pumping Great Salt Lake brine into the Newfoundland Evaporation Basin during the West Desert pumping project. The pumping project was operated by the State of Utah from April 1987, to June 1989 in an attempt to lower the historically high level of Great Salt Lake (pond elevation was 4,211.85 feet in 1986). Effects of the pumping on the Newfoundland Basin included altering the chemical character of the shallow brine aquifer by mixing two chemically different brines, and depositing a halite salt crust where none was previously reported on the lacustrine sediments of the Newfoundland Basin playa. The halite salt crust resulted from evaporation of the brine pond generated by the pumping project. Changes in the shallow-brine aquifer chemistry were determined by comparing pre-pumping brine chemistry with that of post pumping brine, and examining variation with borehole depth and location (i.e., playa periphery vs central basin topographic low) of specific analyte concentration profiles and solid-phase mineral assemblages obtained from analyses of core sample pore water and mineralogy. Brine sample analyses from 72 exploratory boreholes drilled in the Newfoundland Basin by Reynolds Metals Company during the mid 1960's provided pre-pumping brine chemistry. Post pumping chemistry was obtained from analyses of brine samples from 24 boreholes hand-augured between 1998 and 2001 in the central and peripheral portions of the Newfoundland Basin. TEQUIL, a brine equilibrium model, was used to better understand how the Great Salt Lake brines introduced into the Newfoundland Basin may have interacted with fluids contained within the Basin's shallow-brine aquifer. TEQUIL identified the sequence of mineral precipitation from evaporation of pre and post-pumping Newfoundland Basin shallow-aquifer fluids and Great Salt Lake brine. The model was also used to simulate 50-50 mixing of Great Salt Lake brine with pre-pumping Newfoundland Basin shallow-aquifer. The resulting precipitated mineral suite from sequential evaporation of the simulated brine mix was nearly identical to that from TEQUIL simulation of the post-pumping Newfoundland Basin brine. This differed from the mineral suite precipitated from the pre-pumping Newfoundland Basin brine. Examination of pore water chemistry and solid-phase mineralogy from borehole core samples taken from the playa periphery to the basin topographic low illustrate the following chemical and mineralogical generalities. At peripheral sites, magnesium and potassium concentrations decreased to near constant values below 0.5% at depths greater than 5 feet below the surface. Sulfate at similar depth ranged from 0.5 to 2% in peripheral areas. However, near the topographic low, sulfate reached 4.5% below the thickest salt crust at depths of about 3 feet, and then, along with magnesium and potassium, decreased to less than 1+ or 2% near the surface. In contrast, sulfate concentration in intermediate areas with thin salt crust, peaked near the surface but, magnesium and potassium concentrations peaked at depth. This suggests that the most recent salts precipitated from re-solution brine (generated from dissolution of halite salt crust by rain) were depleted with respect to magnesium and potassium, as compared to the deeper groundwater residuals from ancient Lake Bonneville.

Decreased waterborne pathogenic bacteria in an urban aquifer related to intense shallow geothermal exploitation.

PubMed

García-Gil, Alejandro; Gasco-Cavero, Samanta; Garrido, Eduardo; Mejías, Miguel; Epting, Jannis; Navarro-Elipe, Mercedes; Alejandre, Carmen; Sevilla-Alcaine, Elena

2018-08-15

The implications of intensive use of shallow geothermal energy resources in shallow urban aquifers are still not known for waterborne pathogens relevant to human health. Firstly, we hypothesized that waterborne enteric pathogens would be relatively increased in heated groundwater plumes. To prove this, microbiological sampling of 31 piezometers covering the domain of an urban groundwater body affected by microbiological contamination and energetically exploited by 70 groundwater heat pump systems was performed. Mean differences of pathogenic bacteria contents between impacted and non-impacted monitoring points were assessed with a two-tailed independent Student's t-test or Mann-Whitney U and correlation coefficients were also calculated. Surprisingly, the results obtained revealed a significant and generalized decrease in waterborne pathogen contents in thermally impacted piezometers compared to that of non-impacted piezometers. This decrease is hypothesized to be caused by a heat shock to bacteria within the heat exchangers. The statistically significant negative correlations obtained between waterborne pathogen counts and temperature could be explained by the spatial distribution of the bacteria, finding that bacteria start to recover with increasing distance from the injection point. Also, different behavior groups fitting exponential regression models were found for the bacteria species studied, justified by the different presence and influence of several aquifer parameters and major, minor and trace elements studied, as well as the coexistence with other bacteria species. The results obtained from this work reinforce the concept of shallow geothermal resources as a clean energy source, as they could also provide the basis to control the pathogenic bacteria contents in groundwater bodies. Copyright © 2018 Elsevier B.V. All rights reserved.

Quantifying the contribution of groundwater on water consumption in arid crop land with shallow groundwater

NASA Astrophysics Data System (ADS)

Huo, Z.; Liu, Z.; Wang, X.; Qu, Z.

2016-12-01

Groundwater from the shallow aquifers can supply substantial water for evapotranspiration of crops. However, it is difficult to quantify to the contribution of groundwater on crop's water consumption. In present study, regional scale evapotranspiration and the groundwater contribution to evapotranspiration were estimated by the soil water balance equation in Hetao irrigation distric with shallow aquifers, China. Estimates used an 8-year (2006-2013) hydrological dataset including soil moisture, the depth to water table, irrigation amounts, rainfall data, and drainage water flow. The 8-year mean evapotranspiration was estimated to be 664 mm. The mean groundwater supported evapotranspiration (ETg) was estimated to be 228 mm, with variation from 145 mm to 412 mm during the crop growth period. Analysis of the positive correlation between evapotranspiration and the sum of irrigation and rainfall, and the analysis of the negative correlation between ETg/ET and the sum of irrigation and rainfall, reflect the need of groundwater to meet the evapotranspiration demand. Approximately 20% to 40% of the evapotranspiration is from the shallow aquifers in the study area. Furthermore, a new method estimating daily ETg during the crop growing season was developed. The effects of crop growth stage, climate condition, groundwater depth and soil moisture are considered in the model. The method was tested with controlled lysimeter experiments of winter wheat including five controlled water table depths and four soil profiles of different textures. The simulated ETg is a good agreement with the measured data for four soil profiles and different depths to groundwater table. These results could be useful for the government to understand the significant role of the groundwater and make reasonable water use policy in the semiarid agricultural regions.

Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport.

PubMed

Reagan, Matthew T; Moridis, George J; Keen, Noel D; Johnson, Jeffrey N

2015-04-01

Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on two general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes. Short-term leakage fractured reservoirs requires high-permeability pathways Production strategy affects the likelihood and magnitude of gas release Gas release is likely short-term, without additional driving forces.

Variability in Benthic Exchange Rate, Depth, and Residence Time Beneath a Shallow Coastal Estuary

NASA Astrophysics Data System (ADS)

Russoniello, Christopher J.; Heiss, James W.; Michael, Holly A.

2018-03-01

Hydrodynamically driven benthic exchange of water between the water column and shallow seabed aquifer is a significant and dynamic component of coastal and estuarine fluid budgets. Associated exchange of solutes promotes ecologically important chemical reactions, so quantifying benthic exchange rates, depths, and residence times constrains coastal chemical cycling estimates. We present the first combined field, numerical, and analytical modeling investigation of wave-induced exchange. Temporal variability of exchange was calculated with data collected by instruments deployed in a shallow estuary for 11 days. Differential pressure sensors recorded pressure gradients across the seabed, and up- and down-looking ADCPs recorded currents and pressures to determine wave parameters, surface-water currents, and water depth. Wave-induced exchange was calculated (1) directly from differential pressure measurements, and indirectly with an analytical model based on wave parameters from (2) ADCP and (3) wind data. Wave-induced exchange from pressure measurements and ADCP-measured wave parameters matched well, but both exceeded wind-based values. Exchange induced by tidal pumping and current-bed form interaction—the other primary drivers in shallow coastal waters were calculated from tidal stage variation and ADCP-measured currents. Exchange from waves (mean = 20.0 cm/d; range = 1.75-92.3 cm/d) greatly exceeded exchange due to tides (mean = 3.7 cm/d) and current-bed form interaction (mean = 6.5 × 10-2 cm/d). Groundwater flow models showed aquifer properties affect wave-driven benthic exchange: residence time and depth increased and exchange rates decreased with increasing hydraulic diffusivity (ratio of aquifer permeability to compressibility). This new understanding of benthic exchange will help managers assess its control over chemical fluxes to marine systems.

Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

DOE PAGES

Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; ...

2015-04-18

Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on twomore » general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.« less

Controls on groundwater flow in the Bengal Basin of India and Bangladesh: Regional modeling analysis

USGS Publications Warehouse

Michael, H.A.; Voss, C.I.

2009-01-01

Groundwater for domestic and irrigation purposes is produced primarily from shallow parts of the Bengal Basin aquifer system (India and Bangladesh), which contains high concentrations of dissolved arsenic (exceeding worldwide drinking water standards), though deeper groundwater is generally low in arsenic. An essential first step for determining sustainable management of the deep groundwater resource is identification of hydrogeologic controls on flow and quantification of basin-scale groundwater flow patterns. Results from groundwater modeling, in which the Bengal Basin aquifer system is represented as a single aquifer with higher horizontal than vertical hydraulic conductivity, indicate that this anisotropy is the primary hydrogeologic control on the natural flowpath lengths. Despite extremely low hydraulic gradients due to minimal topographic relief, anisotropy implies large-scale (tens to hundreds of kilometers) flow at depth. Other hydrogeologic factors, including lateral and vertical changes in hydraulic conductivity, have minor effects on overall flow patterns. However, because natural hydraulic gradients are low, the impact of pumping on groundwater flow is overwhelming; modeling indicates that pumping has substantially changed the shallow groundwater budget and flowpaths from predevelopment conditions. ?? Springer-Verlag 2009.

Hydrogeochemistry of high-fluoride groundwater at Yuncheng Basin, northern China.

PubMed

Li, Chengcheng; Gao, Xubo; Wang, Yanxin

2015-03-01

Hydrogeochemical and environmental isotope methods were integrated to delineate the spatial distribution and enrichment of fluoride in groundwater at Yuncheng Basin in northern China. One hundred groundwater samples and 10 Quaternary sediment samples were collected from the Basin. Over 69% of the shallow groundwater (with a F(-) concentration of up to 14.1mg/L), 44% of groundwater samples from the intermediate and 31% from the deep aquifers had F(-) concentrations above the WHO provisional drinking water guideline of 1.5mg/L. Groundwater with high F(-) concentrations displayed a distinctive major ion chemistry: Na-rich and Ca-poor with a high pH value and high HCO3(-) content. Hydrochemical diagrams and profiles and hydrogen and oxygen isotope compositions indicate that variations in the major ion chemistry and pH are controlled by mineral dissolution, cation exchange and evaporation in the aquifer systems, which are important for F(-) mobilization as well. Leakage of shallow groundwater and/or evaporite (gypsum and mirabilite) dissolution may be the major sources for F(-) in groundwater of the intermediate and deep aquifers. Copyright © 2014 Elsevier B.V. All rights reserved.

Controls on groundwater flow in the Bengal Basin of India and Bangladesh: regional modeling analysis

NASA Astrophysics Data System (ADS)

Michael, Holly A.; Voss, Clifford I.

2009-11-01

Groundwater for domestic and irrigation purposes is produced primarily from shallow parts of the Bengal Basin aquifer system (India and Bangladesh), which contains high concentrations of dissolved arsenic (exceeding worldwide drinking water standards), though deeper groundwater is generally low in arsenic. An essential first step for determining sustainable management of the deep groundwater resource is identification of hydrogeologic controls on flow and quantification of basin-scale groundwater flow patterns. Results from groundwater modeling, in which the Bengal Basin aquifer system is represented as a single aquifer with higher horizontal than vertical hydraulic conductivity, indicate that this anisotropy is the primary hydrogeologic control on the natural flowpath lengths. Despite extremely low hydraulic gradients due to minimal topographic relief, anisotropy implies large-scale (tens to hundreds of kilometers) flow at depth. Other hydrogeologic factors, including lateral and vertical changes in hydraulic conductivity, have minor effects on overall flow patterns. However, because natural hydraulic gradients are low, the impact of pumping on groundwater flow is overwhelming; modeling indicates that pumping has substantially changed the shallow groundwater budget and flowpaths from predevelopment conditions.

Hydrogeologic framework, hydrology, and refined conceptual model of groundwater flow for Coastal Plain aquifers at the Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2005-12

USGS Publications Warehouse

Brayton, Michael J.; Cruz, Roberto M.; Myers, Luke; Degnan, James R.; Raffensperger, Jeff P.

2015-01-01

The regional hydrogeologic framework indicates that the site is underlain by Coastal Plain sediments of the Columbia, Merchantville, and Potomac Formations. Two primary aquifers underlying the site, the Columbia and the upper Potomac, are separated by the Merchantville Formation confining unit. Local groundwater flow in the surficial (Columbia) aquifer is controlled by topography and generally flows northward and discharges to nearby surface water. Regional flow within the Potomac aquifer is towards the southeast, and is strongly influenced by major water withdrawals locally. Previous investigations at the site indicated that contaminants, primarily benzene and chlorinated benzene compounds, were present in the Columbia aquifer in most locations; however, there were only limited detections in the upper Potomac aquifer as of 2004. From 2005 through 2012, the USGS designed a monitoring network, assisted with exploratory drilling, collected data at monitoring wells, conducted geophysical surveys, evaluated water-level responses in wells during pumping of a production well, and evaluated major aquifer withdrawals. Data collected through these efforts were used to refine the local conceptual flow system. The refined conceptual flow system for the site includes: (a) identification of gaps in confining units in the study area, (b) identification and correlation of multiple water-bearing sand intervals within the upper Potomac Formation, (c) connections between groundwater and surface water, (d) connections between shallow and deeper groundwater, (e) new water-level (or potentiometric surface) maps and inferred flow directions, and (f) identification of major local pumping well influences. The implications of the revised conceptual flow system on the occurrence and movement of site contaminants are that the resulting detection of contaminants in the upper Potomac aquifer at specific well locations can be attributed primarily to either advective lateral transport, direct vertical contaminant transport, or a combination of vertical and lateral movement resulting from changes in water withdrawal rates over time.

Groundwater Quality and Quantity in a Coastal Aquifer Under High Human Pressure: Understand the Aquifer Functioning and the Social Perception of Water Use for a Better Water Management. Example of Recife (PE, Brazil)

NASA Astrophysics Data System (ADS)

Petelet-Giraud, E.; Cary, L.; Bertrand, G.; Alves, L. M.; Cary, P.; Giglio-Jacquemot, A.; Aquilina, L.; Hirata, R.; Montenegro, S.; Aurouet, A.; Franzen, M.; Chatton, E.

2015-12-01

The Recife Metropolitan Region is a typical "hot spot" illustrating the problems of southern countries on water issues inducing high pressures on water resources both on quantity and quality in the context of global social and environmental changes. This study is based on an interdisciplinary approach, coupling "hard" geosciences together with "soft" social sciences with the aim to study the human impact on coastal aquifers in a context of overexploitation to improve the existing water management tools. By revisiting the geological and hydrogeological conceptual models, field campaigns of groundwater and surface water sampling and analysis, and of interviews of different actors on the theme of water supply and management in Recife Metropolitan Region, the main results can be summarized as follows: (1) The recharge of the deep strategic confined aquifers is very limited resulting in water level decrease (up to -90m in 25y) due to overexploitation. (2) Groundwater residence time in these deep aquifers is over 10,000 years. (3) The natural upward flux of these confined aquifers is observed inland, but is reversed in the heavily populated areas along the coast leading to mixing with modern groundwater coming from the shallow aquifers. (4) Groundwater salinization is inherited from the Pleistocene marine transgression, only partly diluted by the recharge through the mangroves during the subsequent regression phase. Today, leakage from surficial aquifers induces local salinization. (5) Local climatic scenarios predict a reduction of rainfall volume of 20% together with an increase of sea level (18-59cm by 2100). (5) The Public authorities tend to deny the difficulties that people, especially those in precarious situation, are confronted with regarding water, especially in times of drought. The COQUEIRAL research project is financially supported by ANR (ANR-11-CEPL-012); FACEPE (APQ-0077-3.07/11); FAPESP (2011/50553-0

Microbial succession and stimulation following a test well injection simulating CO2 leakage into shallow Newark Basin aquifers

NASA Astrophysics Data System (ADS)

Dueker, M.; Clauson, K.; Yang, Q.; Umemoto, K.; Seltzer, A. M.; Zakharova, N. V.; Matter, J. M.; Stute, M.; Takahashi, T.; Goldberg, D.; O'Mullan, G. D.

2012-12-01

Despite growing appreciation for the importance of microbes in altering geochemical reactions in the subsurface, the microbial response to geological carbon sequestration injections and the role of microbes in altering metal mobilization following leakage scenarios in shallow aquifers remain poorly constrained. A Newark Basin test well was utilized in field experiments to investigate patterns of microbial succession following injection of CO2 saturated water into isolated aquifer intervals. Additionally, laboratory mesocosm experiments, including microbially-active and inactive (autoclave sterilized) treatments, were used to constrain the microbial role in mineral dissolution, trace metal release, and gas production (e.g. hydrogen and methane). Hydrogen production was detected in both sterilized and unsterilized laboratory mesocosm treatments, indicating abiotic hydrogen production may occur following CO2 leakage, and methane production was detected in unsterilized, microbially active mesocosms. In field experiments, a decrease in pH following injection of CO2 saturated aquifer water was accompanied by mobilization of trace elements (e.g. Fe and Mn), the production of hydrogen gas, and increased bacterial cell concentrations. 16S ribosomal RNA clone libraries, from samples collected before and after the test well injection, were compared in an attempt to link variability in geochemistry to changes in aquifer microbiology. Significant changes in microbial composition, compared to background conditions, were found following the test well injection, including a decrease in Proteobacteria, and an increased presence of Firmicutes, Verrucomicrobia, Acidobacteria and other microbes associated with iron reducing and syntrophic metabolism. The concurrence of increased microbial cell concentration, and rapid microbial community succession, with increased concentrations of hydrogen gas suggests that abiotically produced hydrogen may serve as an ecologically-relevant energy source stimulating changes in aquifer microbial communities immediately following CO2 leakage.

Compilation of regional ground water monitoring data to investigate 60 years of ground water dynamics in New England

NASA Astrophysics Data System (ADS)

Boutt, D. F.; Weider, K. M.

2010-12-01

Theory suggests that ground water systems at shallow depths are sensitive to climate system dynamics but respond at differing rates due to primarily hydrogeologic characteristics of the aquifer. These rates are presumably to a first order controlled by the transmissivity and hydrogeologic settings of aquifer systems. Regional scale modeling and understanding of the impact of this behavior is complicated by the fact that aquifer systems in glaciated regions of the North American continent often possess high degrees of heterogeneity as well as disparate hydraulic connections between aquifer systems. In order to investigate these relationships we present the results of a regional compilation of groundwater hydraulic head data across the New England states together with corresponding atmospheric (precipitation and temperature) and streamflow data for a 60 year period (1950-2010). Ground water trends are calculated as normalized anomalies, and analyzed with respect to regional compiled precipitation, temperature, and streamflow. Anomalies in ground water levels are analyzed together with hydrogeologic variables such as aquifer thickness, topographic setting, and distance from coast. The time-series display decadal patterns with ground water levels being highly variable and lagging that of precipitation and streamflow pointing to site specific and non-linear response to changes in climate. Sites with deeper water tables respond slower and with larger anomalies compared to shallow water table sites. Tills consistently respond quicker and have larger anomalies compared to outwash and stratified glacial deposits. The data set suggests that while regional patterns in ground water table response are internally consistent, the magnitude and timing of the response to wet or dry periods is extremely sensitive to hydrogeologic characteristics of the host aquifer.

Arsenic release from shallow aquifers of the Hetao basin, Inner Mongolia: evidence from bacterial community in aquifer sediments and groundwater.

PubMed

Li, Yuan; Guo, Huaming; Hao, Chunbo

2014-12-01

Indigenous microbes play crucial roles in arsenic mobilization in high arsenic groundwater systems. Databases concerning the presence and the activity of microbial communities are very useful in evaluating the potential of microbe-mediated arsenic mobilization in shallow aquifers hosting high arsenic groundwater. This study characterized microbial communities in groundwaters at different depths with different arsenic concentrations by DGGE and one sediment by 16S rRNA gene clone library, and evaluated arsenic mobilization in microcosm batches with the presence of indigenous bacteria. DGGE fingerprints revealed that the community structure changed substantially with depth at the same location. It indicated that a relatively higher bacterial diversity was present in the groundwater sample with lower arsenic concentration. Sequence analysis of 16S rRNA gene demonstrated that the sediment bacteria mainly belonged to Pseudomonas, Dietzia and Rhodococcus, which have been widely found in aquifer systems. Additionally, NO3(-)-reducing bacteria Pseudomonas sp. was the largest group, followed by Fe(III)-reducing, SO4(2-)-reducing and As(V)-reducing bacteria in the sediment sample. These anaerobic bacteria used the specific oxyanions as electron acceptor and played a significant role in reductive dissolution of Fe oxide minerals, reduction of As(V), and release of arsenic from sediments into groundwater. Microcosm experiments, using intact aquifer sediments, showed that arsenic release and Fe(III) reduction were microbially mediated in the presence of indigenous bacteria. High arsenic concentration was also observed in the batch without amendment of organic carbon, demonstrating that the natural organic matter in sediments was the potential electron donor for microbially mediated arsenic release from these aquifer sediments.

Characterising alluvial aquifers in a remote ephemeral catchment (Flinders River, Queensland) using a direct push tracer approach

NASA Astrophysics Data System (ADS)

Taylor, Andrew R.; Smith, Stanley D.; Lamontagne, Sébastien; Suckow, Axel

2018-01-01

The availability of reliable water supplies is a key factor limiting development in northern Australia. However, characterising groundwater resources in this remote part of Australia is challenging due to a lack of existing infrastructure and data. Here, direct push technology (DPT) was used to characterise shallow alluvial aquifers at two locations in the semiarid Flinders River catchment. DPT was used to evaluate the saturated thickness of the aquifer and estimate recharge rates by sampling for environmental tracers in groundwater (major ions, 2H, 18O, 3H and 14C). The alluvium at Fifteen Mile Reserve and Glendalough Station consisted of a mixture of permeable coarse sandy and gravely sediments and less permeable clays and silts. The alluvium was relatively thin (i.e. < 20 m) and, at the time of the investigation, was only partially saturated. Tritium (3H) concentrations in groundwater was ∼1 Tritium Unit (TU), corresponding to a mean residence time for groundwater of about 12 years. The lack of an evaporation signal for the 2H and 18O of groundwater suggests rapid localised recharge from overbank flood events as the primary recharge mechanism. Using the chloride mass balance technique (CMB) and lumped parameter models to interpret patterns in 3H in the aquifer, the mean annual recharge rate varied between 21 and 240 mm/yr. Whilst this recharge rate is relatively high for a semiarid climate, the alluvium is thin and heterogeneous hosting numerous alluvial aquifers with varied connectivity and limited storage capacity. Combining DPT and environmental tracers is a cost-effective strategy to characterise shallow groundwater resources in unconsolidated sedimentary aquifers in remote data sparse areas.

Geohydrology and quality of water in aquifers in Lucas, Sandusky, and Wood counties, northwestern Ohio

USGS Publications Warehouse

Breen, K.J.; Dumouchelle, D.H.

1991-01-01

The hydrology and quality of ground water were evaluated for the surficial sand and carbonate aquifers in northwestern Ohio. A locally important surficial sand aquifer in western Lucas County was evaluated on the basis of data from 10 wells completed in undeveloped and developed areas. The carbonate aquifer in Silurian and Devonian bedrock at its northernmost extent on the Ohio mainland was evaluated on the basis of data from previous studies and data from 466 wells and 11 springs. Most data are for the period 1985-88. The unconfined surficial sand aquifer is less than 50 ft. (feet) thick. Clay-rich drift, which restricts vertical movement of water, underlines the aquifer. Recharge is from precipitation, and discharge is by evapotranspiration and by flow to local streams and drainage ditches. Water levels are generally 2 to 8 ft. below land surface and fluctuate a total of about 3.5 ft. seasonally in a forested area. Concentrations of iron and manganese in ground water are excessive in some areas. Waters from shallow drive-point wells in residential areas contained larger concentrations of dissolved solids, hardness, sodium, and chloride than did waters from identical wells in undeveloped areas. The presence of nitrate nitrogen an other selected constituents in ground water in residential areas, and the absence of these constituents in ground water in undeveloped areas, indicate that the surficial sand aquifer has been affected by development. In carbonate aquifer, fractures, bedding-plane joints, and other secondary openings are the principal water-bearing zones. These zones can be areally and stratigraphically separated by low-permeability rock. Leaky artesian or semiconfined conditions predominate beneath most of the 1,400-mi? study area. The aquifer is confined by relatively impermeable underlying shale of Silurian age and overlying clay-rich drift of Quaternary age. Unproductive strata, including evaporites, within the sequence of carbonate rocks also confine some water-bearing zones. The carbonate aquifer is part of a regional ground-water-flow system; however, subsystems such as the eastern karst and central outcrops are locally important. The potentiometric surface indicates that recharge from areas south and west of the study area flows toward discharge areas along major rivers (Maumee, Portage, and Sandusky) , to a buried bedrock valley in central Sandusky County, and to springs and flowing wells. The potentiometric surface flattens markedly near the southern shore of Lake Erie, where ground-water levels approximate those of the lake, indicating a hydraulic connection between the lake and the aquifer. Hydrogeologic characteristics and water-quality data indicate that Lake Erie is not a major source of recharge to the aquifer. Ground-water ages inferred from tritium concentrations and potentiometric-surface maps indicate that recharge from precipitation enters the aquifer by subsurface drainage in karstified strata in eastern Sandusky County and by infiltration in shallow bedrock areas where drift is less than 20 ft. thick. The quality of water in the carbonate aquifer is described with reference to 52 properties and constituents that characterize chemical, radiochemical, bacteriologic, and physical conditions. Ground-water samples from 135 wells and 11 springs are used in the characterization. On the basis of these data, water from the aquifer is generally suitable for drinking and for most domestic purposes. The most areally widespread aesthtic factors limiting the use of ground water are hardness, concentrations of dissolved solids, sulfate and iron, and the presence of hydrogen sulfide. Selected bacteria are commonly present and may compromise the potability of water from the aquifer. Coliform bacteria from surface sources were found in 47 of 143 water samples. Analyses for total coliform bacteria indicate that 36 of the 125 samples from wells maintained for potable supply have bacteria counts of 4

Water-Resources Investigations in Tennessee: Programs and Activities of the U.S. Geological Survey, 1992-94

DTIC Science & Technology

1995-01-01

rainfall runoff model, DR&& to Bear Branch watershed, Murfreesboro, Tennessee .......... 37 Seepage and spring inventory reconnaissance and base-flow... bearing rocks in the Valley and Ridge, Blue Ridge, and Piedmont physiographic provinces, and covers parts of eight states from New Jersey to Alabama...100 feet in diameter and about 250 feet deep. It penetrates three water- bearing units of carbonate origin (the shallow aquifer, the Manchester aquifer

Connectivity to the surface determines diversity patterns in subsurface aquifers of the Fennoscandian shield.

PubMed

Hubalek, Valerie; Wu, Xiaofen; Eiler, Alexander; Buck, Moritz; Heim, Christine; Dopson, Mark; Bertilsson, Stefan; Ionescu, Danny

2016-10-01

Little research has been conducted on microbial diversity deep under the Earth's surface. In this study, the microbial communities of three deep terrestrial subsurface aquifers were investigated. Temporal community data over 6 years revealed that the phylogenetic structure and community dynamics were highly dependent on the degree of isolation from the earth surface biomes. The microbial community at the shallow site was the most dynamic and was dominated by the sulfur-oxidizing genera Sulfurovum or Sulfurimonas at all-time points. The microbial community in the meteoric water filled intermediate aquifer (water turnover approximately every 5 years) was less variable and was dominated by candidate phylum OD1. Metagenomic analysis of this water demonstrated the occurrence of key genes for nitrogen and carbon fixation, sulfate reduction, sulfide oxidation and fermentation. The deepest water mass (5000 year old waters) had the lowest taxon richness and surprisingly contained Cyanobacteria. The high relative abundance of phylogenetic groups associated with nitrogen and sulfur cycling, as well as fermentation implied that these processes were important in these systems. We conclude that the microbial community patterns appear to be shaped by the availability of energy and nutrient sources via connectivity to the surface or from deep geological processes.

A correction for Dupuit-Forchheimer interface flow models of seawater intrusion in unconfined coastal aquifers

NASA Astrophysics Data System (ADS)

Koussis, Antonis D.; Mazi, Katerina; Riou, Fabien; Destouni, Georgia

2015-06-01

Interface flow models that use the Dupuit-Forchheimer (DF) approximation for assessing the freshwater lens and the seawater intrusion in coastal aquifers lack representation of the gap through which fresh groundwater discharges to the sea. In these models, the interface outcrops unrealistically at the same point as the free surface, is too shallow and intersects the aquifer base too far inland, thus overestimating an intruding seawater front. To correct this shortcoming of DF-type interface solutions for unconfined aquifers, we here adapt the outflow gap estimate of an analytical 2-D interface solution for infinitely thick aquifers to fit the 50%-salinity contour of variable-density solutions for finite-depth aquifers. We further improve the accuracy of the interface toe location predicted with depth-integrated DF interface solutions by ∼20% (relative to the 50%-salinity contour of variable-density solutions) by combining the outflow-gap adjusted aquifer depth at the sea with a transverse-dispersion adjusted density ratio (Pool and Carrera, 2011), appropriately modified for unconfined flow. The effectiveness of the combined correction is exemplified for two regional Mediterranean aquifers, the Israel Coastal and Nile Delta aquifers.

Nitrogen contamination in groundwater in an agricultural region along the New Silk Road, northwest China: distribution and factors controlling its fate.

PubMed

Chen, Jie; Qian, Hui; Wu, Hao

2017-05-01

Nitrogen contamination is a global concern and has been a serious problem in agricultural areas. The present study was carried out in an intensively irrigated region of northwest China along the New Silk Road, Yinchuan Plain, where the residents depend on the groundwater as the primary source for drinking. To understand the nitrogen contamination in the aquifer system, the distribution of nitrate and ammonium and its controlling factors were studied based on hydrochemical, hydrogeological, and isotopic analyses. 11.37 and 40% of phreatic water samples are categorized as NO 3 -N and NH 4 -N pollution in accordance with the WHO standards. A total of 59.52% of confined water samples has high NH 4 -N values, exceeding the permissible limit for drinking purpose. The results indicate NO 3 -N predominates in the shallow water and NH 4 -N predominates in the deep water for the single phreatic aquifer. For the multilayer structure area, NO 3 -N predominates in the phreatic aquifer of the western and the southern parts of the plain; NH 4 -N predominates in the phreatic aquifer of the middle and the northern parts of the plain, and in the confined aquifers where groundwater pumping had been performed. The mixture of synthetic fertilizer and manure/sewage is primarily responsible for the phreatic water based on isotopic analysis. In the confined aquifers, higher NH 4 -N concentrations are mainly attributed to intensive pumping under higher pumping rates. The results of this study can be used as a scientific basis for the future research on nitrogen in the plain. They can also be used by scholars and decision makers who are interested in groundwater protection and sustainable development.

Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

DOE PAGES

Zheng, Liange; Carroll, Susan; Bianchi, Marco; ...

2014-12-31

A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

Effectiveness of pilot connector well in artificial recharge of the Floridan aquifer, western Orange County, Florida

USGS Publications Warehouse

Watkins, Frank A.

1977-01-01

A connector well pilot installation, in continuous operation in western Orange County since December 4, 1970, was transferring water from the lower of two shallow sand aquifers to the Floridan aquifer at a rate of 13 gallons per minute when measured on September 23, 1971. The recharge water is untreated and analyses show it to be chemically and physically compatible with the water in the Floridan aquifer. The temperatures of the recharging and receiving waters were identical, 23 deg C. The transfer of water from the lower sand aquifer to the Floridan aquifer caused only a small buildup of artesian pressure in the Floridan aquifer but it lowered the artesian head 4 feet in the lower sand aquifer near the well which supplied the recharge water. Water levels in the upper sand aquifer were not affected, probably because of the low permeability of an intervening hardpan layer. However, after six auger holes back-filled with sand connected the two sand aquifers on April 5, 1972, a rise of water levels in the lower sand aquifer was noted. The principal chemical and physical effects on the water in the Floridan aquifer were a general improvement in chemical quality and an increase in color. The color may decrease as more water moves through the sand aquifer and the material responsible for the high color is removed by flushing. (Woodard-USGS)

Assessment of managed aquifer recharge from Sand Hollow Reservoir, Washington County, Utah, updated to conditions in 2010

USGS Publications Warehouse

Heilweil, Victor M.; Marston, Thomas M.

2011-01-01

Sand Hollow Reservoir in Washington County, Utah, was completed in March 2002 and is operated primarily for managed aquifer recharge by the Washington County Water Conservancy District. From 2002 through 2009, total surface-water diversions of about 154,000 acre-feet to Sand Hollow Reservoir have allowed it to remain nearly full since 2006. Groundwater levels in monitoring wells near the reservoir rose through 2006 and have fluctuated more recently because of variations in reservoir water-level altitude and nearby pumping from production wells. Between 2004 and 2009, a total of about 13,000 acre-feet of groundwater has been withdrawn by these wells for municipal supply. In addition, a total of about 14,000 acre-feet of shallow seepage was captured by French drains adjacent to the North and West Dams and used for municipal supply, irrigation, or returned to the reservoir.From 2002 through 2009, about 86,000 acre-feet of water seeped beneath the reservoir to recharge the underlying Navajo Sandstone aquifer. Water-quality sampling was conducted at various monitoring wells in Sand Hollow to evaluate the timing and location of reservoir recharge moving through the aquifer. Tracers of reservoir recharge include major and minor dissolved inorganic ions, tritium, dissolved organic carbon, chlorofluorocarbons, sulfur hexafluoride, and noble gases. By 2010, this recharge arrived at monitoring wells within about 1,000 feet of the reservoir.

Assessment of managed aquifer recharge at Sand Hollow Reservoir, Washington County, Utah, updated to conditions through 2014

USGS Publications Warehouse

Marston, Thomas M.; Heilweil, Victor M.

2016-09-08

Sand Hollow Reservoir in Washington County, Utah, was completed in March 2002 and is operated primarily for managed aquifer recharge by the Washington County Water Conservancy District. From 2002 through 2014, diversions of about 216,000 acre-feet from the Virgin River to Sand Hollow Reservoir have allowed the reservoir to remain nearly full since 2006. Groundwater levels in monitoring wells near the reservoir rose through 2006 and have fluctuated more recently because of variations in reservoir stage and nearby pumping from production wells. Between 2004 and 2014, about 29,000 acre-feet of groundwater was withdrawn by these wells for municipal supply. In addition, about 31,000 acre-feet of shallow seepage was captured by French drains adjacent to the North and West Dams and used for municipal supply, irrigation, or returned to the reservoir. From 2002 through 2014, about 127,000 acre-feet of water seeped beneath the reservoir to recharge the underlying Navajo Sandstone aquifer.Water quality continued to be monitored at various wells in Sand Hollow during 2013–14 to evaluate the timing and location of reservoir recharge as it moved through the aquifer. Changing geochemical conditions at monitoring wells WD 4 and WD 12 indicate rising groundwater levels and mobilization of vadose-zone salts, which could be a precursor to the arrival of reservoir recharge.

Quantifying the Movement and Dissolution of Fugitive Methane in Shallow Aquifers: Visualization Experiments

NASA Astrophysics Data System (ADS)

Van De Ven, C. J. C.; Mumford, K. G.

2016-12-01

The environmental impact and potential human health implications, specifically from the contamination of groundwater sources, has sparked controversy around shale gas extraction in North America. It is clear that understanding the effects of hydraulic fracturing on shallow fresh water aquifers is of great importance, including the threat of stray gas (also referred to as fugitive methane) on groundwater quality. Faulty wells provide a preferential pathway for free gas phase (mostly methane) to migrate from deeper gas-bearing formations of natural gas to shallow aquifers, followed by its dissolution into the surrounding groundwater. An increased understanding of the fate of fugitive methane in shallow aquifers is required to assess the potential risks associated with current and future operations, as well as to better link gas migration, dissolution and the deterioration of groundwater quality. In this study, a series of laboratory experiments were performed using carbon dioxide (CO2) gas as a surrogate for methane to improve our understanding of gas dissolution in groundwater systems. Using CO2, a novel laboratory technique was developed that allows the measurement of dissolved CO2 concentrations using image analysis alongside visualization of free gas mobilization. The technique is based on the acidification of water during CO2 dissolution, which causes a colour change in an indicator dye. The colour change is recorded using a visual light transmission technique, in which digital images are used to track dissolved concentrations at high spatial (1 mm) and temporal (5 s) resolutions in a two-dimensional (25 × 25 × 1 cm3) flow cell. The experiments were completed in both homogeneous sand packs and sand packs containing layered heterogeneities to investigate the dissolution of both gas fingers and gas pools. The results demonstrate the potential of this novel technique for investigating gas dissolution, and showed significant tailing of dissolved CO2 and persistence of other gas phase components. This technique will aid in the development of conceptual models to link fugitive methane to groundwater contamination and provide detailed data required for the validation of numerical models that account for gas-water mass transfer; both of which are required for the development of sound monitoring techniques.

Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators

USGS Publications Warehouse

Panno, S.V.; Hackley, Keith C.; Hwang, H.-H.; Kelly, W.R.

2001-01-01

The sources of nitrate (NO-3) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO-3 concentrations in excess of the USEPA's drinking water standard of 10 mg N/1. Relative to background levels, the NO-3 concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO-3 to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and ??15N and ??18O of the NO-3 ions. The isotopic data were most definitive and suggested that the sources of NO-3 in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO-3 and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO-3 and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for ??15N and ??18O of the NO-3 ranged from 3.2??? to 19.1??? and from 7.2??? to 18.7???, respectively. The trend of ??15N and ??18O data for NO-3 also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. ?? 2001 Elsevier Science B.V. All rights reserved.

Pesticides in shallow groundwater in the Delmarva Peninsula

USGS Publications Warehouse

Koterba, M.T.; Banks, W.S.L.; Shedlock, R.J.

1993-01-01

A regional study of the areal and depth distribution of pesticides in shallow groundwater in the Delmarva Peninsula of Delaware, Maryland, and Virginia was done to (i) relate the pesticides detected to landscape and shallow subsurface features, and (ii) evaluate aquifer vulnerability and the potential contamination of drinking-water supplies. Water samples collected at 100 wells from 1988 to 1990 were analyzed for concentrations of 36 pesticides, four metabolites, and other constituents. The most commonly detected residues were atrazine, cyanazine, simazine, alachlor, metolachlor, and dicamba. Concentrations were low; few exceeded 3 ??g L-1. Most detections correlate with the intensive use of these herbicides in three widely distributed and commonly rotated crops-corn (Zea mays L.), soybean [Glycine max (L.) Merr.], and small grain-particularly if grown in well- drained soils. Most detections occurred in samples collected from shallow wells screened within 10 m of the overlying water table. The shallow depth distribution of most residues is consistent with their suspected history of use (ca. 20 yr), and patterns in shallow groundwater flow in the surficial aquifer in the study area. The areal and depth distributions of detectable residues in groundwater did not correlate with a vulnerability index, nor any of the component scores developed to estimate that index using the DRASTIC method. The shallow depth of most detections also indicates why few samples from water-supply wells in this study had measurable concentrations of pesticides; most supply wells are deeper than 10 m below the water table. The low number of contaminated samples from supply wells implies that deep groundwater currently (1992) used for drinking generally does not contain detectable pesticide residues.

Megacity pumping and preferential flow threaten groundwater quality

PubMed Central

Khan, Mahfuzur R.; Koneshloo, Mohammad; Knappett, Peter S. K.; Ahmed, Kazi M.; Bostick, Benjamin C.; Mailloux, Brian J.; Mozumder, Rajib H.; Zahid, Anwar; Harvey, Charles F.; van Geen, Alexander; Michael, Holly A.

2016-01-01

Many of the world's megacities depend on groundwater from geologically complex aquifers that are over-exploited and threatened by contamination. Here, using the example of Dhaka, Bangladesh, we illustrate how interactions between aquifer heterogeneity and groundwater exploitation jeopardize groundwater resources regionally. Groundwater pumping in Dhaka has caused large-scale drawdown that extends into outlying areas where arsenic-contaminated shallow groundwater is pervasive and has potential to migrate downward. We evaluate the vulnerability of deep, low-arsenic groundwater with groundwater models that incorporate geostatistical simulations of aquifer heterogeneity. Simulations show that preferential flow through stratigraphy typical of fluvio-deltaic aquifers could contaminate deep (>150 m) groundwater within a decade, nearly a century faster than predicted through homogeneous models calibrated to the same data. The most critical fast flowpaths cannot be predicted by simplified models or identified by standard measurements. Such complex vulnerability beyond city limits could become a limiting factor for megacity groundwater supplies in aquifers worldwide. PMID:27673729

Assessment of hydrogeologic conditions with emphasis on water quality and wastewater injection, southwest Sarasota and West Charlotte counties, Florida

USGS Publications Warehouse

Hutchinson, C.B.

1992-01-01

The 250-square-mile area of southwest Sarasota and west Charlotte Counties is underlain by a complex hydrogeologic system having diverse ground-water quality. The surficial and intermediate aquifer systems and the Upper Floridan aquifer of the Floridan aquifer system contain six separate aquifers, or permeable zones, and have a total thickness of about 2,000 feet. Water in the clastic surficial aquifer system is potable and is tapped by hundreds of shallow, low-yielding supply wells. Water in the mixed clastic and carbonate intermediate aquifer system is potable in the upper part, but in the lower part, because of increasing salinity, it is used primarily for reverse-osmosis desalinization feed water and irrigation. Within the Upper Floridan aquifer, limestone and dolomite of the Suwannee permeable zone are tapped by irrigation and reverse-osmosis supply wells. The underlying, less permeable limestone of the Suwannee-Ocala semiconfining unit generally encompasses the transition zone between freshwater and very saline water. Interbedded limestone and dolomite of the Ocala-Avon Park moderately permeable zone and Avon Park highly permeable zone compose the deep, very saline injection zone. Potential ground-water contamination problems include flooding by storm tides, upward movement of saline water toward pumping centers by natural and induced leakage or through improperly constructed and abandoned wells, and lateral and vertical movement of treated sewage and reverse-osmosis wastewater injected into deep zones. Effects of flooding are evident in coastal areas where vertical layering of fresh and saline waters is observed. Approximately 100 uncontrolled flowing artesian wells that have interaquifer flow rates as high as 350 gallons per minute have been located and scheduled for plugging by the Southwest Florida Water Management District--in an attempt to improve ground-water quality of the shallow aquifers. Because each aquifer or permeable zone has unique head and water-quality characteristics, construction of single-zone wells would eliminate cross-contamination and borehole interflow. Such a program, when combined with the plugging of shallow-cased wells having long open-hole intervals connecting multiple zones, would safeguard ground-water resources in the study area. The study area encompasses seven wastewater injection sites that have a projected capacity for injecting 29 million gallons per day into the zone 1,100 to 2,050 feet below land surface. There are six additional sites within 20 miles. The first well began injecting reverse-osmosis wastewater in 1984, and since then, other wells have been drilled and permitted for injection of treated sewage. A numerical model was used to evaluate injection-well design and potential for movement of injected wastewater within the hydrogeologic framework. The numerical model was used to simulate injection through a representative well at a rate of 1 million gallons per day for 10 years. In this simulation, a convection cell developed around the injection well with the buoyant fresh injectant rising to form a lens within the injection zone below the lower Suwannee-Ocala semiconfining unit. Around an ideal, fully penetrating well cased 50 feet into the injection zone and open from a depth of 1,150 feet to 2,050 feet, simulations show that the injectant moves upward to a depth of 940 feet, forms a lens about 600 feet thick, and spreads radially outward to a distance of about 2,300 feet after 10 years. Comparison simulations of injection through wells having open depth intervals of 1,150 to 1,400 feet and 1,450 to 2,050 feet demonstrate that such changes in well construction have little effect on the areal spread of the injectant lens or the rate of upward movement. Simulations also indicate that reverse-osmosis wastewater injected beneath a supply well field, where water levels above the semiconfining unit are lowered 20 feet by pumping, would move upward after 10 years to a de

Transport of fecal-derived microorganisms from latrine ponds to aquifers in Bangladesh

NASA Astrophysics Data System (ADS)

Knappett, P. S.; McKay, L. D.; Layton, A.; Alam, M.; Williams, D.; Huq, M. R.; Mailloux, B. J.; Ferguson, A.; Feighery, J. E.; Culligan, P. J.; Escamilla, V.; Emch, M.; Akita, Y.; Serre, M. L.; Perfect, E.; Gentry, R. W.; Ahmed, K. M.; van Geen, A.

2009-12-01

Groundwater has been the principal source of drinking water for over 100 million people in rural Bangladesh for the past twenty years. The shallow depths and simple construction of the private wells has raised concern that these wells may be receiving fecal contamination from the densely populated rural areas with poor sanitation, contributing to high rates of diarrheal disease. Ponds are ubiquitous in Bangladesh, serving multiple purposes, including receiving fecal effluent from latrines, and private wells are frequently located in close proximity to these potential groundwater contamination sources. After detecting E. coli in up to 70% of private and monitoring wells throughout a village in Araihazar, the numerous ponds throughout the village were hypothesized to be sources of this contamination. To test this hypothesis 9 lateral transects of 4 monitoring wells each, 7 m deep and placed 1 m apart, were installed radiating away from four ponds of contrasting ages and near surface geology. These transects were monitored throughout the year to look for evidence that the ponds were contributing E. coli to the groundwater system. During the dry season from September 2008 to May 2009 no E. coli was observed in the shallow monitoring wells. In contrast, when the rains began in June 2009 several of the transects showed increasing water levels and E. coli with proximity to the pond, providing evidence that some ponds were acting as a contamination point source. A major rainfall event was simulated in June 2009 in each of the four ponds, raising the water level by 20 to 30 cm while adjacent transects were monitored. In two recently dug, deep ponds E. coli travelled up to 6 m into the medium sand aquifer within 24 hours as a result of the simulated rainfall event. In the two older ponds, which had well developed silt layers on the bottom or were emplaced in silty aquifers little E. coli was detected in the adjacent monitoring wells under natural or forced gradient conditions. For the two ponds with sandy bottoms, the pulse of E. coli was attenuated exponentially with distance, but elevated levels of E. coli remained in the aquifer for more than 10 days after the initial flooding of the ponds. Thus, during the wet season, proximity to young, deep ponds cut into sandy aquifers is a risk factor for diarrheal disease in the adjacent households. The ponds alone, however, cannot explain the spatial and temporal distribution of E. coli throughout the village aquifer, and additional sources require investigation.

The evolution of Devonian hydrocarbon gases in shallow aquifers of the northern Appalachian Basin: Insights from integrating noble gas and hydrocarbon geochemistry

NASA Astrophysics Data System (ADS)

Darrah, Thomas H.; Jackson, Robert B.; Vengosh, Avner; Warner, Nathaniel R.; Whyte, Colin J.; Walsh, Talor B.; Kondash, Andrew J.; Poreda, Robert J.

2015-12-01

The last decade has seen a dramatic increase in domestic energy production from unconventional reservoirs. This energy boom has generated marked economic benefits, but simultaneously evoked significant concerns regarding the potential for drinking-water contamination in shallow aquifers. Presently, efforts to evaluate the environmental impacts of shale gas development in the northern Appalachian Basin (NAB), located in the northeastern US, are limited by: (1) a lack of comprehensive ;pre-drill; data for groundwater composition (water and gas); (2) uncertainty in the hydrogeological factors that control the occurrence of naturally present CH4 and brines in shallow Upper Devonian (UD) aquifers; and (3) limited geochemical techniques to quantify the sources and migration of crustal fluids (specifically methane) at various time scales. To address these questions, we analyzed the noble gas, dissolved ion, and hydrocarbon gas geochemistry of 72 drinking-water wells and one natural methane seep all located ≫1 km from shale gas drill sites in the NAB. In the present study, we consciously avoided groundwater wells from areas near active or recent drilling to ensure shale gas development would not bias the results. We also intentionally targeted areas with naturally occurring CH4 to characterize the geochemical signature and geological context of gas-phase hydrocarbons in shallow aquifers of the NAB. Our data display a positive relationship between elevated [CH4], [C2H6], [Cl], and [Ba] that co-occur with high [4He]. Although four groundwater samples show mantle contributions ranging from 1.2% to 11.6%, the majority of samples have [He] ranging from solubility levels (∼45 × 10-6 cm3 STP/L) with below-detectable [CH4] and minor amounts of tritiogenic 3He in low [Cl] and [Ba] waters, up to high [4He] = 0.4 cm3 STP/L with a purely crustal helium isotopic end-member (3He/4He = ∼0.02 times the atmospheric ratio (R/Ra)) in samples with CH4 near saturation for shallow groundwater (P(CH4) = ∼1 atmosphere) and elevated [Cl] and [Ba]. These data suggest that 4He is dominated by an exogenous (i.e., migrated) crustal source for these hydrocarbon gas- and salt-rich fluids. In combination with published inorganic geochemistry (e.g., 87Sr/86Sr, Sr/Ba, Br-/Cl-), new noble gas and hydrocarbon isotopic data (e.g., 20Ne/36Ar, C2+/C1, δ13C-CH4) suggest that a hydrocarbon-rich brine likely migrated from the Marcellus Formation (via primary hydrocarbon migration) as a dual-phase fluid (gas + liquid) and was fractionated by solubility partitioning during fluid migration and emplacement into conventional UD traps (via secondary hydrocarbon migration). Based on the highly fractionated 4He/CH4 data relative to Marcellus and UD production gases, we propose an additional phase of hydrocarbon gas migration where natural gas previously emplaced in UD hydrocarbon traps actively diffuses out into and equilibrates with modern shallow groundwater (via tertiary hydrocarbon migration) following uplift, denudation, and neotectonic fracturing. These data suggest that by integrating noble gas geochemistry with hydrocarbon and dissolved ion chemistry, one can better determine the source and migration processes of natural gas in the Earth's crust, which are two critical factors for understanding the presence of hydrocarbon gases in shallow aquifers.

Status of groundwater levels and storage volume in the Equus Beds aquifer near Wichita, Kansas, January 2016

USGS Publications Warehouse

Klager, Brian J.

2016-12-29

The Equus Beds aquifer in south-central Kansas, which is part of the High Plains aquifer, serves as a source of water for municipal and agricultural users in the area. The city of Wichita has used the Equus Beds aquifer as one of its primary water sources since the 1940s. The aquifer in and around Wichita’s well field reached historically low water levels in 1993, prompting the city to adopt new water-use and conservation strategies to ensure future water supply needs were met. Part of the plan was to initiate a managed aquifer recharge program called the Equus Beds Aquifer Storage and Recovery project. The goal of the managed aquifer recharge program is to artificially recharge the Equus Beds aquifer with treated water from the Little Arkansas River. As part of the Equus Beds Aquifer Storage and Recovery project, the city of Wichita and the U.S. Geological Survey have partnered in a long-term cooperative study to monitor and describe the quantity and quality of the water in the Equus Beds aquifer and the Little Arkansas River.The city of Wichita, the Equus Beds Groundwater Management District No. 2, the Kansas Department of Agriculture–Division of Water Resources, and the U.S. Geological Survey collected groundwater levels in numerous wells screened in the Equus Beds aquifer in the area in and around Wichita’s well field in January 2016. The measurements were used to interpolate potentiometric surfaces for shallow and deep parts of the aquifer in the study area. These potentiometric surfaces were compared with potentiometric surfaces from previous years to estimate changes in water levels and storage volume in the study area.Groundwater levels were generally higher in January 2016 than they were in January 2015. On average, in January 2016, groundwater levels in the shallow part of the aquifer were about 3.4 feet higher and groundwater levels in the deep part of the aquifer were about 3.8 feet higher than in January 2015. The volume of water stored in the study area decreased by about 74,000 acre-feet between predevelopment (the time period before substantial pumpage began in the 1940s) and January 2016; increased by about 121,000 acre-feet between the historic low in 1993 and January 2016; and increased by about 61,000 acre-feet between January 2015 and January 2016. About 62 percent of the storage volume lost between predevelopment and 1993 has been recovered. The increase in storage volume from January 2015 to January 2016 can probably be attributed to less pumping by the city of Wichita and irrigators, more recharge due to higher-than-average precipitation, and higher volumes of artificial recharge in 2015.

Geologic and hydrogeologic characteristics of the Ogallala Formation and White River Group, Belvoir Ranch near Cheyenne, Laramie County, Wyoming

USGS Publications Warehouse

Bartos, Timothy T.; Diehl, Sharon F.; Hallberg, Laura L.; Webster, Daniel M.

2014-01-01

The geologic and hydrogeologic characteristics of Tertiary lithostratigraphic units (Ogallala Formation and White River Group) that typically compose or underlie the High Plains aquifer system in southeastern Wyoming were described physically and chemically, and evaluated at a location on the Belvoir Ranch in Laramie County, Wyoming. On the basis of this characterization and evaluation, three Tertiary lithostratigraphic units were identified using physical and chemical characteristics determined during this study and previous studies, and these three units were determined to be correlative with three identified hydrogeologic units composing the groundwater system at the study site—a high-yielding aquifer composed of the entire saturated thickness of the heterogeneous and coarse-grained fluvial sediments assigned to the Ogallala Formation (Ogallala aquifer); an underlying confining unit composed primarily of very fine-grained volcaniclastic sediments and mudrocks assigned to the Brule Formation of the White River Group and some additional underlying sediments that belong to either the Brule or Chadron Formation, or both (Brule confining unit); and an underlying low-yielding aquifer composed primarily of poorly sorted fluvial sediments assigned to the Chadron Formation of the White River Group (Chadron aquifer). Despite widely varying sediment heterogeneity and consolidation, some limited hydraulic connection throughout the full vertical extent of the Ogallala aquifer was indicated but not conclusively proven by interpretation of similar chemical and isotopic characteristics, modern apparent groundwater ages, and similar hydraulic-head responses measured continuously in two Ogallala aquifer monitoring wells installed for this study at two different widely separated (83 feet) depth intervals. Additional work beyond the scope of this study, such as aquifer tests, would be required to conclusively determine hydraulic connection within the Ogallala aquifer. Groundwater levels (hydraulic heads) measured continuously using water-level recorders in both monitoring wells completed in the Ogallala aquifer showed a consistent strong upward vertical gradient in the Ogallala aquifer, indicating the potential for water to move from deeper to shallower parts of the aquifer, regardless of the time of year and the presumed effects of pumping of public-supply and industrial wells in the area. Continuous measurement of groundwater levels in the shallowest monitoring well, installed near the water table, and examination of subsequently constructed water-level hydrographs indicated substantial groundwater recharge is likely during the spring of 2009 and 2010 from the ephemeral stream (Lone Tree Creek) located adjacent to the study site that flows primarily in response to spring snowmelt from the adjacent Laramie Mountains and surface runoff from precipitation events. Using the water-table fluctuation method, groundwater recharge was estimated to be about 13 inches for the period beginning in early October 2009 and ending in late June 2010, and about 4 inches for the period beginning in March 2011 and ending in early July 2011. Comparison of previously measured groundwater levels (hydraulic heads) and groundwater-quality characteristics in nearby monitoring wells completed in the Chadron aquifer with those measured in the two monitoring wells installed for this study in the Ogallala aquifer, combined with detailed lithologic characterization, strongly indicated the Brule confining unit hydraulically confines and isolates the Chadron aquifer from the overlying Ogallala aquifer, thus likely limiting hydraulic connection between the two units. Consequently, because of the impermeable nature of the Brule confining unit and resulting hydraulic separation of the Ogallala and Chadron aquifers, and compared with local and regional hydrostratigraphic definitions of the High Plains aquifer system, the groundwater system in Tertiary lithostratigraphic units overlying the Upper Cretaceous Lance Formation at the location studied on the Belvoir Ranch was defined as being composed of, from shallowest to deepest, the High Plains aquifer system (high-yielding Ogallala aquifer only, composed of the saturated Ogallala Formation); the Brule confining unit composed of the Brule Formation of the White River Group and an underlying fine-grained depth interval with sediments that belong to either the Brule or Chadron Formation, or both; and the low-yielding Chadron aquifer (composed of poorly sorted coarse-grained sediments with substantial fine-grained matrix material assigned to the Chadron Formation of the White River Group).

Groundwater-quality data for the Madera/Chowchilla–Kings shallow aquifer study unit, 2013–14: Results from the California GAMA Program

USGS Publications Warehouse

Shelton, Jennifer L.; Fram, Miranda S.

2017-02-03

Groundwater quality in the 2,390-square-mile Madera/Chowchilla–Kings Shallow Aquifer study unit was investigated by the U.S. Geological Survey from August 2013 to April 2014 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program’s Priority Basin Project. The study was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality in the shallow aquifer systems of the Madera, Chowchilla, and Kings subbasins of the San Joaquin Valley groundwater basin. The shallow aquifer system corresponds to the part of the aquifer system generally used by domestic wells and is shallower than the part of the aquifer system generally used by public-supply wells. This report presents the data collected for the study and a brief preliminary description of the results.Groundwater samples were collected from 77 wells and were analyzed for organic constituents, inorganic constituents, selected isotopic and age-dating tracers, and microbial indicators. Most of the wells sampled for this study were private domestic wells. Unlike groundwater from public-supply wells, the groundwater from private domestic wells is not regulated for quality in California and is rarely analyzed for water-quality constituents. To provide context for the sampling results, however, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory benchmarks established for drinking-water quality by the U.S. Environmental Protection Agency, the State of California, and the U.S. Geological Survey.Of the 319 organic constituents assessed in this study (90 volatile organic compounds and 229 pesticides and pesticide degradates), 17 volatile organic compounds and 23 pesticides and pesticide degradates were detected in groundwater samples; concentrations of all but 2 were less than the respective benchmarks. The fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2-dibromoethane (EDB) were detected at concentrations above their respective regulatory benchmarks in samples from a total of four wells.Most detections of inorganic constituents were at concentrations or activities less than the respective benchmark levels. Five inorganic constituents were detected in groundwater samples from one or more wells at concentrations or activities greater than their respective regulatory, health-based benchmarks: arsenic, uranium, nitrate, adjusted gross alpha particle activity, and gross beta particle activity. Four inorganic constituents were detected in samples from one or more wells at concentrations or activities greater than their respective non-regulatory, health-based benchmarks: manganese, molybdenum, vanadium, and radon-222. Three inorganic constituents were detected in groundwater samples from one or more wells at concentrations greater than their respective non-regulatory, aesthetic-based benchmarks: iron, sulfate, and total dissolved solids.Microbial indicators (Escherichia coli, total coliform, and enterococci) were analyzed for presence or absence. The presence of Escherichia coli (E. coli) was not detected; the presence of total coliform was detected in samples from 10 of the 72 grid wells for which it was analyzed, and the presence of enterococci was detected in samples from 5 of the 73 grid wells analyzed.

Recharge of an Unconfined Pumice Aquifer: Winter Rainfall Versus Snow Pack, South-central Oregon

NASA Astrophysics Data System (ADS)

Cummings, M. L.; Weatherford, J. M.; Eibert, D.

2015-12-01

Walker Rim study area, an uplifted fault block east of the Cascade Range, south-central Oregon, exceeds 1580 m elevation and includes Round Meadow-Sellers Marsh closed basin, and headwaters of Upper Klamath Basin, Deschutes Basin, and Christmas Lake Valley in the Great Basin. The water-bearing unit is 2.8 to 3.0 m thick Plinian pumice fall from the Holocene eruption of Mount Mazama, Cascade Range. The perched pumice aquifer is underlain by low permeability regolith and bedrock. Disruption of the internal continuity of the Plinian pumice fall by fluvial and lacustrine processes resulted in hydrogeologic environments that include fens, wet meadows, and areas of shallow water table. Slopes are low and surface and groundwater pathways follow patterns inherited from the pre-eruption landscape. Discharge for streams and springs and depth to water table measured in open-ended piezometers slotted in the pumice aquifer have been measured between March and October, WY 2011 through WY2015. Yearly occupation on same date has been conducted for middle April, June 1st, and end of October. WY2011 and WY2012 received more precipitation than the 30 year average while WY2014 was the third driest year in 30 years of record. WY2014 and WY2015 provide an interesting contrast. Drought conditions dominated WY2014 while WY2015 was distinct in that the normal cold-season snow pack was replaced by rainfall. Cumulative precipitation exceeded the 30-year average between October and March. The pumice aquifer of wet meadows and areas of shallow water table experienced little recharge in WY2015. Persistence of widespread diffuse discharge from fens declined by middle summer as potentiometric surfaces lowered into confining peat layers or in some settings into the pumice aquifer. Recharge of the perched pumice aquifer in rain-dominated WY2015 was similar to or less than in the snow-dominated drought of WY2014. Rain falling on frozen ground drove runoff rather than aquifer recharge.

Hydrogeologic characteristics and water quality of a confined sand unit in the surficial aquifer system, Hunter Army Airfield, Chatham County, Georgia

USGS Publications Warehouse

Gonthier, Gerard

2012-01-01

An 80-foot-deep well (36Q397, U.S. Geological Survey site identification 320146081073701) was constructed at Hunter Army Airfield to assess the potential of using the surficial aquifer system as a water source to irrigate a ballfield complex. A 300-foot-deep test hole was drilled beneath the ballfield complex to characterize the lithology and water-bearing characteristics of sediments above the Upper Floridan aquifer. The test hole was then completed as well 36Q397 open to a 19-foot-thick shallow, confined sand unit contained within the surficial aquifer system. A single-well, 24-hour aquifer test was performed by pumping well 36Q397 at a rate of 50 gallons per minute during July 13-14, 2011, to characterize the hydrologic properties of the shallow, confined sand unit. Two pumping events prior to the aquifer test affected water levels. Drawdown during all three pumping events and residual drawdown during recovery periods were simulated using the Theis formula on multiple changes in discharge rate. Simulated drawdown and residual drawdown match well with measured drawdown and residual drawdown using values of horizontal hydraulic conductivity and specific storage, which are typical for a confined sand aquifer. Based on the hydrologic parameters used to match simulated drawdown and residual drawdown to measured drawdown and residual drawdown, the transmissivity of the sand was determined to be about 400 feet squared per day. The horizontal hydraulic conductivity of the sand was determined to be about 20 feet per day. Analysis of a water-quality sample indicated that the water is suitable for irrigation. Sample analysis indicated a calcium-carbonate type water having a total dissolved solids concentration of 39 milligrams per liter. Specific conductance and concentrations of all analyzed constituents were below those that would be a concern for irrigation, and were below primary and secondary water-quality criteria levels.

Interaction of coastal urban groundwater with infrastructure due to tidal variation

NASA Astrophysics Data System (ADS)

Su, X.; Prigiobbe, V.

2017-12-01

The urbanization of coastal areas has been increasing during the last century. For these areas, groundwater is one of major source of potable water for the population, the industry, and the agriculture, with an average demand of 30 m3/s [1,2]. Simultaneously, the rate of sea-level rise has been recorded to be approximately 40 mm/yr [3], with potential negative consequences on the coastal groundwater. As the sea-level rises, sea-water intrusion into potable aquifers may become more important [4] and the water table of the shallow aquifer underneath the coastal areas may rise [5]. Therefore, the water quality of the aquifer decreases and interaction between the shallow aquifer and infrastructure may occur. In particular, in the latter case, disruptive events may become more frequent, such as infiltration of groundwater into damaged sewer causing discharge of untreated sewage (combined sewer overflows, CSOs). Here, a study is presented on the modeling of urban groundwater in coastal areas to identify the cause of frequent CSOs in dry weather conditions, i.e., CSOs are not expected to occur. The evolution of the water table was described in response of tidal variation to quantify the interaction between the shallow aquifer and an aging sewer. The watershed of the city of Hoboken (NJ), at the estuary of Hudson river, was implemented in MODFLOW. The model was built using dataset from various sources. Geostatistic was applied to create the aquifer geology and measurements of the water table from monitoring wells within the urban area were used as boundary conditions and model validation. Preliminary results of the simulations are shown the figure, where the water table over a period of 7 months was calculated. The groundwater model with the sewer will help identifying the parts of the network that might be submerged by the groundwater and, therefore, subjected to infiltration. Combining groundwater and sewer modeling with the hydrograph separation method [6], the model prediction of infiltration will be validated. References [1] Pimentel et al. BioScience, 54, 909-918, 2004. [2] Owolabi Glob. Ini., 11, 69-87, 2017. [3] Milne Astro. Geophys., 49, 224-228, 2008 [4] Vzquez-Su et al. Hydro. J. 13, 522-533, 2005. [5] Gburek et al. Ground Water, 37,175-184, 1999. [6] Prigiobbe and Giulianelli. Water Sci.Tech. 60, 727-735, 2009.

Hydrochemical zonation of the western part of Göksu Delta aquifer system, Southern Turkey

NASA Astrophysics Data System (ADS)

Dokuz, U. E.; Çelik, M.; Arslan, Ş.; Engin, H.

2012-04-01

In general, coastal areas are preferred places for human settlement, especially at places where infrastructure routes benefit from rivers, streets, or harbours. As a result, these areas usually suffer from rising population and endure increasingly high demand on natural resources like water. Göksu Delta, located in southern Turkey, is one of the important wetland areas of Turkey at the Mediterranean coast. It is divided into two parts by Göksu River. The western part of the delta, which is the subject matter of this study, hosts fertile agricultural fields, touristic places and a Special Environmental Protection Area. These properties of the region lead to a water-dependent ecosystem where groundwater has widely been used for agricultural and domestic purposes. When the exploitation of groundwater peaked in the middle of 1990s, the groundwater levels dropped and seawater intruded. General Directorate of State Hydraulic Works tried to stop seawater intrusion by building irrigation channels connected to Göksu River and banned drilling of new wells for groundwater exploitation, although it is hard to control the drilling of wells without official permit. Geological studies show that the delta is composed of terrestrial sediments including clay to coarse sand deposited during Quaternary. The heterogeneous sediments of Göksu Delta cause hydrogeological features of the aquifer systems to be heterogeneous and anisotropic. Hydrogeological investigations, therefore, indicate mainly two different aquifers, shallow and deep, separated by an aquitard. The shallow aquifer is under unconfined to confined conditions from north to south while the deep aquifer is under confined conditions. This study focuses on hydrogeochemical zonation in terms of hydrochemical processes that affect the Göksu Delta aquifer systems. For this purpose, hydrogeochemical and isotopic studies are conducted to understand the salinisation and softening processes of groundwater. The physicochemical and hydrochemical features of the water (EC, TDS, HCO3-, SO4-2, Cl-, Na+, Ca+2, Mg+2, K+, Br-, B+3, Sr+2, NO3-, PO4-3) were evaluated and composition diagrams were plotted (e.g. ion vs Cl-, ion vs TDS, Na+ vs Ca+2, HCO3/Cl vs Cl-). Ratios of HCO3/Cl, Na/Cl, Ca/Cl, SO4/Cl, Br/Cl, B/Cl were calculated and isotope analyses (δ18O, δD and Tritium) were conducted. By these methods, it is possible to differentiate the effects of agricultural land use, seawater intrusion, ion exchange, and softening processes. Hydrochemical analyses indicate that the dominant anion is HCO3- and the dominant cation is Ca+2 for the northern part and Na+ for the southern part of the aquifers. Both EC values (417-2890 µS/cm), Cl- (16-320 mg/l) and Na+ (490,68-558,58 mg/l) concentrations of groundwater increase along the flow path from north to south for the aquifer system. Combined evaluations show that seawater intrusion is still dominant in the southern part of the study area while ion exchange and softening processes control the central part. Both NO3- (up to 19,6 mg/l) and PO4-3 (up to 11 mg/l) contents as well as Br/Cl ratios indicate agricultural pollution at some locations in the study area.

Using Geophysics to Define Hydrostratigraphic Units in the Edwards and Trinity Aquifers, Texas

NASA Astrophysics Data System (ADS)

Smith, B. D.; Blome, C. D.; Clark, A. K.; Kress, W.; Smith, D. V.

2007-05-01

Airborne and ground geophysical surveys conducted in Uvalde, Medina, and northern Bexar counties, Texas, can be used to define and characterize hydrostratigraphic units of the Edwards and Trinity aquifers. Airborne magnetic surveys have defined numerous Cretaceous intrusive stocks and laccoliths, mainly in Uvalde County, that influence local hydrology and perhaps regional ground-water flow paths. Depositional environments in the aquifers can be classified as shallow water platforms (San Marcos Platform, Edwards Group), shoal and reef facies (Devils River Trend, Devils River Formation), and deeper water basins (Maverick Basin, West Nueces, McKnight, and Salmon Peak Formations). Detailed airborne and ground electromagnetic surveys have been conducted over the Edwards aquifer catchment zone (exposed Trinity aquifer rocks), recharge zone (exposed Edwards aquifer rocks), and artesian zone (confined Edwards) in the Seco Creek area (northeast Uvalde and Medina Counties; Devils River Trend). These geophysical survey data have been used to divide the Edwards exposed within the Balcones fault zone into upper and lower hydrostratigraphic units. Although both units are high electrical resistivity, the upper unit has slightly lower resistivity than the lower unit. The Georgetown Formation, at the top of the Edwards Group has a moderate resistivity. The formations that comprise the upper confining units to the Edwards aquifer rocks have varying resistivities. The Eagleford and Del Rio Groups (mainly clays) have very low resistivities and are excellent electrical marker beds in the Seco Creek area. The Buda Limestone is characterized by high resistivities. Moderate resistivities characterize the Austin Group rocks (mainly chalk). The older Trinity aquifer, underlying the Edwards aquifer rocks, is characterized by less limestone (electrically resistive or low conductivity units) and greater quantities of mudstones (electrically conductive or low resistivity units). In the western area (Devils River Trend and Maverick Basin) of the Trinity aquifer system there are well-defined collapse units and features that are marked by moderate resistivities bracketed by resistive limestone and conductive mudstone of the Glen Rose Limestone. In the central part of the aquifer (San Marcos Platform) the Trinity's lithologies are divided into upper and lower units with further subdivisions into hydrostratigraphic units. These hydrostratigraphic units are well mapped by an airborne electromagnetic survey in Bexar County. Electrical properties of the Edwards aquifer also vary across the fresh-saline water interface where ground and borehole electrical surveys have been conducted. The saline- saturated Edwards is predictably more conductive than the fresh-water saturated rocks. Similar fresh-saline water interfaces exist within the upper confining units of the Edwards aquifer (Carrizo-Wilcox aquifer) and the Trinity aquifer rocks.

Quantification of anthropogenic impact on groundwater-dependent terrestrial ecosystem using geochemical and isotope tools combined with 3-D flow and transport modelling

NASA Astrophysics Data System (ADS)

Zurek, A. J.; Witczak, S.; Dulinski, M.; Wachniew, P.; Rozanski, K.; Kania, J.; Postawa, A.; Karczewski, J.; Moscicki, W. J.

2015-02-01

Groundwater-dependent ecosystems (GDEs) have important functions in all climatic zones as they contribute to biological and landscape diversity and provide important economic and social services. Steadily growing anthropogenic pressure on groundwater resources creates a conflict situation between nature and man which are competing for clean and safe sources of water. Such conflicts are particularly noticeable in GDEs located in densely populated regions. A dedicated study was launched in 2010 with the main aim to better understand the functioning of a groundwater-dependent terrestrial ecosystem (GDTE) located in southern Poland. The GDTE consists of a valuable forest stand (Niepolomice Forest) and associated wetland (Wielkie Błoto fen). It relies mostly on groundwater from the shallow Quaternary aquifer and possibly from the deeper Neogene (Bogucice Sands) aquifer. In July 2009 a cluster of new pumping wells abstracting water from the Neogene aquifer was set up 1 km to the northern border of the fen. A conceptual model of the Wielkie Błoto fen area for the natural, pre-exploitation state and for the envisaged future status resulting from intense abstraction of groundwater through the new well field was developed. The main aim of the reported study was to probe the validity of the conceptual model and to quantify the expected anthropogenic impact on the studied GDTE. A wide range of research tools was used. The results obtained through combined geologic, geophysical, geochemical, hydrometric and isotope investigations provide strong evidence for the existence of upward seepage of groundwater from the deeper Neogene aquifer to the shallow Quaternary aquifer supporting the studied GDTE. Simulations of the groundwater flow field in the study area with the aid of a 3-D flow and transport model developed for Bogucice Sands (Neogene) aquifer and calibrated using environmental tracer data and observations of hydraulic head in three different locations on the study area, allowed us to quantify the transient response of the aquifer to operation of the newly established Wola Batorska well field. The model runs reveal the presence of upward groundwater seepage to the shallow Quaternary aquifer of the order of 440 m3 d-1. By the end of the simulation period (2029), with continuous operation of the Wola Batorska well field at maximum permissible capacity (ca. 10 000 m3 d-1), the direction of groundwater seepage will change sign (total change of the order of 900 m3 d-1). The water table drawdown in the study area will reach ca. 30 cm. This may have significant adverse effects on functioning of the studied GDTE.

Hydrologic evaluation of salinity control and reclamation projects in the Indus Plain, Pakistan--A summary

USGS Publications Warehouse

Mundorff, Maurice John; Carrigan, P.H.; Steele, T.D.; Randall, A.D.

1976-01-01

This report summarizes the observations and findings of a team of four specialists from the U.S. Geological Survey assigned to Pakistan under the auspices of the U.S. Agency for International Development during May to August 1972 for a hydrologic evaluation of Salinity Control and Reclamation Projects in the Indus Plain Individual members of the team undertook comprehensive studies related to climatology, surface-water hydrology, and the canal system; streamflow and sediment yields of the rivers; computer applications to hydrologic data; aquifer characteristics; hydrologic evaluation of Salinity Control and Reclamation Projects (SCARPs); tubewell performance; hydrology of shallow versus deep tubewells; well and well-screen design in the Indus Plain; evaluation of observed and anticipated trends in both private and public tubewell development; evaluation of water-quality programs, data analysis, and records, and computer coding of special water-quality data; and evaluation of water-level data, well discharge and specific-capacity tests and aquifer tests. The reclamation program, by pumping from tubewells, has been notably successful in lowering the water table, in providing supplemental water for irrigation and for leaching of salinized soils, and in improving crop production. Some changes in water quality have been observed in SCARP-I and the Mona Scheme of SCARP-II, but these have not as yet (1972) significantly affected the utility of the water for irrigation. Problems associated with reclamation include control of deterioration in performance of tubewells and their rehabilitation, local brackish or saline-water encroachment, and maintenance of a favorable salt balance in the ground-water system. Rapid and as yet (1972) unregulated growth of shallow private tubewell development in the past decade has introduced complicating factors to the reclamation planning of the early 1960's which had emphasized public tubewell development through the SCARP program. In comparing shallow (0-200 feet) with deep (200-400 feet} tubewell development, it is concluded that long-term response of the water table is the same, whether many shallow wells of small capacity or fewer deeper wells of large capacity pump the same total volume of water in the same area. Moreover, it is concluded that there is no definite advantage for either type of pumping regime with respect to water quality. Utilization of the Punjab aquifer could be greatly enhanced by recharge of high-quality water diverted from the Chenab and Jhelum Rivers to the Ravi and Sutlej Rivers by way of the link and irrigation canals during periods of surplus flow. Recharge to the aquifer could also be improved by diversion of high-quality water from the Chenab and the Jhelum to natural nalas and other surface drainageways during periods of surplus flow. Such recharge would be of much better quality than water leaching downward from irrigated fields. Continued monitoring of the hydrologic system and research on problems engendered by reclamation are essential to the viability of the SCARP program and related water-resources development in the Indus River Basin.

Helicopter electromagnetic and magnetic survey maps and data, East Poplar Oil Field area, August 2004, Fort Peck Indian Reservation, northeastern Montana

USGS Publications Warehouse

Smith, Bruce D.; Thamke, Joanna N.; Cain, Michael J.; Tyrrell, Christa; Hill, Patricia L.

2006-01-01

This report is a data release for a helicopter electromagnetic and magnetic survey that was conducted during August 2004 in a 275-square-kilometer area that includes the East Poplar oil field on the Fort Peck Indian Reservation. The electromagnetic equipment consisted of six different coil-pair orientations that measured resistivity at separate frequencies from about 400 hertz to about 140,000 hertz. The electromagnetic resistivity data were converted to six electrical conductivity grids, each representing different approximate depths of investigation. The range of subsurface investigation is comparable to the depth of shallow aquifers. Areas of high conductivity in shallow aquifers in the East Poplar oil field area are being delineated by the U.S. Geological Survey, in cooperation with the Fort Peck Assiniboine and Sioux Tribes, in order to map areas of saline-water plumes. Ground electromagnetic methods were first used during the early 1990s to delineate more than 31 square kilometers of high conductivity saline-water plumes in a portion of the East Poplar oil field area. In the 10 years since the first delineation, the quality of water from some wells completed in the shallow aquifers in the East Poplar oil field changed markedly. The extent of saline-water plumes in 2004 likely differs from that delineated in the early 1990s. The geophysical and hydrologic information from U.S. Geological Survey studies is being used by resource managers to develop ground-water resource plans for the area.

3D modeling of groundwater heat transport in the shallow Westliches Leibnitzer Feld aquifer, Austria

NASA Astrophysics Data System (ADS)

Rock, Gerhard; Kupfersberger, Hans

2018-02-01

For the shallow Westliches Leibnitzer feld aquifer (45 km2) we applied the recently developed methodology by Kupfersberger et al. (2017a) to derive the thermal upper boundary for a 3D heat transport model from observed air temperatures. We distinguished between land uses of grass and agriculture, sealed surfaces, forest and water bodies. To represent the heat flux from heated buildings and the mixture between different land surfaces in urban areas we ran the 1D vertical heat conduction module SoilTemp which is coupled to the heat transport model (using FEFLOW) on a time step basis. Over a simulation period of 23 years the comparison between measured and observed groundwater temperatures yielded NSE values ranging from 0.41 to 0.92 including readings at different depths. The model results showed that the thermal input signals lead to distinctly different vertical groundwater temperature distributions. To overcome the influence of specific warm or cold years we introduced the computation of an annual averaged groundwater temperature profile. With respect to the use of groundwater cooling or heating facilities we evaluated the application of vertically averaged statistical groundwater temperature distributions compared to the use of temperature distributions at selected dates. We concluded that the heat transport model serves well as an aquifer scale management tool to optimize the use of the shallow subsurface for thermal purposes and to analyze the impacts of corresponding measures on groundwater temperatures.

Bryozoan fauna of the Upper Clays Ferry, Kope, and Lower Fairview formations (Edenian, Upper Ordovician) at Moffett Road, northern Kentucky

USGS Publications Warehouse

Karklins, Olgerts L.

1983-01-01

The geology, water movement, and sediment characteristics in the upstream part of the Spring River basin have been appraised, to assist the U.S. EPA in their study of dioxin contamination in the area. The U.S. Environmental Protection Agency has confirmed that the dioxin compound, TCDD (2,3,7 ,8-tetrachlorodibenzo-p-dioxin), is present in the soils, streambed sediments, and fish in the upstream part of the Spring River Basin. Although the solubility of dioxin is small, it may be moving through the hydrologic system, adsorbed on sediment particles. Water movement in the shallow aquifer generally follows the topography. In upland areas, precipitation recharges the shallow aquifer, then the shallow aquifer water discharges into larger streams. Sediment yields generally are small in the upstream part of the Spring River basin. Suspended sediment discharges for the Spring River at La Russell ranged from 3.0 tons/day at a flow of 79 cu ft/sec, 1.7 times the 7-day 2-yr low flow, to about 1240 tons/day at a flow of 1600 cu ft/sec, 6.7 times the long-term average. Suspended sediment particles in the Spring River and Honey Creek generally were silt and clay (smaller than 0.062 mm). Fine sediments with adsorbed dioxin may be transported out of the area by streamflow, or they may be deposited on flood plains or in downstream impoundments during periods of flooding. (Lantz-PTT)

Groundwater depth prediction in a shallow aquifer in north China by a quantile regression model

NASA Astrophysics Data System (ADS)

Li, Fawen; Wei, Wan; Zhao, Yong; Qiao, Jiale

2017-01-01

There is a close relationship between groundwater level in a shallow aquifer and the surface ecological environment; hence, it is important to accurately simulate and predict the groundwater level in eco-environmental construction projects. The multiple linear regression (MLR) model is one of the most useful methods to predict groundwater level (depth); however, the predicted values by this model only reflect the mean distribution of the observations and cannot effectively fit the extreme distribution data (outliers). The study reported here builds a prediction model of groundwater-depth dynamics in a shallow aquifer using the quantile regression (QR) method on the basis of the observed data of groundwater depth and related factors. The proposed approach was applied to five sites in Tianjin city, north China, and the groundwater depth was calculated in different quantiles, from which the optimal quantile was screened out according to the box plot method and compared to the values predicted by the MLR model. The results showed that the related factors in the five sites did not follow the standard normal distribution and that there were outliers in the precipitation and last-month (initial state) groundwater-depth factors because the basic assumptions of the MLR model could not be achieved, thereby causing errors. Nevertheless, these conditions had no effect on the QR model, as it could more effectively describe the distribution of original data and had a higher precision in fitting the outliers.

Modeling groundwater/surface-water interactions in an Alpine valley (the Aosta Plain, NW Italy): the effect of groundwater abstraction on surface-water resources

NASA Astrophysics Data System (ADS)

Stefania, Gennaro A.; Rotiroti, Marco; Fumagalli, Letizia; Simonetto, Fulvio; Capodaglio, Pietro; Zanotti, Chiara; Bonomi, Tullia

2018-02-01

A groundwater flow model of the Alpine valley aquifer in the Aosta Plain (NW Italy) showed that well pumping can induce river streamflow depletions as a function of well location. Analysis of the water budget showed that ˜80% of the water pumped during 2 years by a selected well in the downstream area comes from the baseflow of the main river discharge. Alluvial aquifers hosted in Alpine valleys fall within a particular hydrogeological context where groundwater/surface-water relationships change from upstream to downstream as well as seasonally. A transient groundwater model using MODFLOW2005 and the Streamflow-Routing (SFR2) Package is here presented, aimed at investigating water exchanges between the main regional river (Dora Baltea River, a left-hand tributary of the Po River), its tributaries and the underlying shallow aquifer, which is affected by seasonal oscillations. The three-dimensional distribution of the hydraulic conductivity of the aquifer was obtained by means of a specific coding system within the database TANGRAM. Both head and flux targets were used to perform the model calibration using PEST. Results showed that the fluctuations of the water table play an important role in groundwater/surface-water interconnections. In upstream areas, groundwater is recharged by water leaking through the riverbed and the well abstraction component of the water budget changes as a function of the hydraulic conditions of the aquifer. In downstream areas, groundwater is drained by the river and most of the water pumped by wells comes from the base flow component of the river discharge.

Linking a one-dimensional pesticide fate model to a three-dimensional groundwater model to simulate pollution risks of shallow and deep groundwater underlying fractured till.

PubMed

Stenemo, Fredrik; Jørgensen, Peter R; Jarvis, Nicholas

2005-09-01

The one-dimensional pesticide fate model MACRO was loose-linked to the three-dimensional discrete fracture/matrix diffusion model FRAC3DVS to describe transport of the pesticide mecoprop in a fractured moraine till and local sand aquifer (5-5.5 m depth) overlying a regional limestone aquifer (16 m depth) at Havdrup, Denmark. Alternative approaches to describe the upper boundary in the groundwater model were examined. Field-scale simulations were run to compare a uniform upper boundary condition with a spatially variable upper boundary derived from Monte-Carlo simulations with MACRO. Plot-scale simulations were run to investigate the influence of the temporal resolution of the upper boundary conditions for fluxes in the groundwater model and the effects of different assumptions concerning the macropore/fracture connectivity between the two models. The influence of within-field variability of leaching on simulated mecoprop concentrations in the local aquifer was relatively small. A fully transient simulation with FRAC3DVS gave 20 times larger leaching to the regional aquifer compared to the case with steady-state water flow, assuming full connectivity with respect to macropores/fractures across the boundary between the two models. For fully transient simulations 'disconnecting' the macropores/fractures at the interface between the two models reduced leaching by a factor 24. A fully connected, transient simulation with FRAC3DVS, with spatially uniform upper boundary fluxes derived from a MACRO simulation with 'effective' parameters is therefore recommended for assessing leaching risks to the regional aquifer, at this, and similar sites.

Simulation of the effects of seasonally varying pumping on intraborehole flow and the vulnerability of public-supply wells to contamination

USGS Publications Warehouse

Yager, Richard M.; Heywood, Charles E.

2014-01-01

Public-supply wells with long screens in alluvial aquifers can produce waters of differing quality from different depths. Seasonal changes in quality are linked to seasonal changes in pumping rates that influence the distribution of flow into the well screens under pumping conditions and the magnitude and direction of intraborehole flow within the wells under ambient conditions. Groundwater flow and transport simulations with MODFLOW and MT3DMS were developed to quantify the effects of changes in average seasonal pumping rates on intraborehole flow and water quality at two long-screened, public-supply wells, in Albuquerque, New Mexico and Modesto, California, where widespread pumping has altered groundwater flow patterns. Simulation results indicate that both wells produce water requiring additional treatment to maintain potable quality in winter when groundwater withdrawals are reduced because less water is derived from parts of the aquifer that contain water requiring less treatment. Simulation results indicate that the water quality at both wells could be improved by increasing average winter-pumping rates to induce more lateral flow from parts of the aquifer that contain better quality water. Arsenic-bearing water produced by the Albuquerque well could be reduced from 55% to 45% by doubling average winter-pumping rate, while nitrate- and uranium-bearing water produced by the Modesto well could be reduced from 95% to 65% by nearly tripling the average winter-pumping rate. Higher average winter-pumping rates would also reduce the volume of intraborehole flow within both wells and prevent the exchange of poor quality water between shallow and deep parts of both aquifers.

Mapping deep aquifer salinity trends in the southern San Joaquin Valley using borehole geophysical data constrained by chemical analyses

NASA Astrophysics Data System (ADS)

Gillespie, J.; Shimabukuro, D.; Stephens, M.; Chang, W. H.; Ball, L. B.; Everett, R.; Metzger, L.; Landon, M. K.

2016-12-01

The California State Water Resources Control Board and the California Division of Oil, Gas and Geothermal Resources are collaborating with the U.S. Geological Survey to map groundwater resources near oil fields and to assess potential interactions between oil and gas development and groundwater resources. Groundwater resources having salinity less than 10,000 mg/L total dissolved solids may be classified as Underground Sources of Drinking Water (USDW) and subject to protection under the federal Safe Drinking Water Act. In this study, we use information from oil well borehole geophysical logs, oilfield produced water and groundwater chemistry data, and three-dimensional geologic surfaces to map the spatial distribution of salinity in aquifers near oil fields. Salinity in the southern San Joaquin Valley is controlled primarily by depth and location. The base of protected waters occurs at very shallow depths, often < 300 meters, in the western part of the valley where aquifer recharge is low in the rain shadow of the Coast Ranges. The base of protected water is much deeper, often >1,500 meters, in the eastern part of the San Joaquin Valley where higher runoff from the western slopes of the Sierra Nevada provide relatively abundant aquifer recharge. Stratigraphy acts as a secondary control on salinity within these broader areas. Formations deposited in non-marine environments are generally fresher than marine deposits. Layers isolated vertically between confining beds and cut off from recharge sources may be more saline than underlying aquifers that outcrop in upland areas on the edge of the valley with more direct connection to regional recharge areas. The role of faulting is more ambiguous. In some areas, abrupt changes in salinity may be fault controlled but, more commonly, the faults serve as traps separating oil-bearing strata that are exempt from USDW regulations, from water-bearing strata that are not exempt.

Biochemical indicators for the bioavailability of organic carbon in ground water

USGS Publications Warehouse

Chapelle, F.H.; Bradley, P.M.; Goode, D.J.; Tiedeman, C.; Lacombe, P.J.; Kaiser, K.; Benner, R.

2009-01-01

The bioavailability of total organic carbon (TOC) was examined in ground water from two hydrologically distinct aquifers using biochemical indicators widely employed in chemical oceanography. Concentrations of total hydrolyzable neutral sugars (THNS), total hydrolyzable amino acids (THAA), and carbon-normalized percentages of TOC present as THNS and THAA (referred to as "yields") were assessed as indicators of bioavailability. A shallow coastal plain aquifer in Kings Bay, Georgia, was characterized by relatively high concentrations (425 to 1492 ??M; 5.1 to 17.9 mg/L) of TOC but relatively low THNS and THAA yields (???0.2%-1.0%). These low yields are consistent with the highly biodegraded nature of TOC mobilized from relatively ancient (Pleistocene) sediments overlying the aquifer. In contrast, a shallow fractured rock aquifer in West Trenton, New Jersey, exhibited lower TOC concentrations (47 to 325 ??M; 0.6 to 3.9 mg/L) but higher THNS and THAA yields (???1% to 4%). These higher yields were consistent with the younger, and thus more bioavailable, TOC being mobilized from modern soils overlying the aquifer. Consistent with these apparent differences in TOC bioavailability, no significant correlation between TOC and dissolved inorganic carbon (DIC), a product of organic carbon mineralization, was observed at Kings Bay, whereas a strong correlation was observed at West Trenton. In contrast to TOC, THNS and THAA concentrations were observed to correlate with DIC at the Kings Bay site. These observations suggest that biochemical indicators such as THNS and THAA may provide information concerning the bioavailability of organic carbon present in ground water that is not available from TOC measurements alone.

Evaluation of pollution susceptibility of Karst aquifers of Rewa Town (Madhya Pradesh) using "DRASTIC" approach.

PubMed

Dubey, D P; Tiwari, R N; Dwivedi, Umesh

2006-04-01

Pollution susceptibility of groundwater of Rewa town situated on karstified Bhander limestones of the Bhander group is discussed in this paper. Pollution potential of selected localities in the town has been determined using the DRASTIC INDEX methodology. Pollution potential for these localities varied between 162 to 217. Shallow aquifers in karstified limestones having direct access to surface water were found more susceptible to pollution. Accordingly, remedial measures were suggested for minimising pollution.

Integrated Framework for Assessing Impacts of CO₂ Leakage on Groundwater Quality and Monitoring-Network Efficiency: Case Study at a CO₂ Enhanced Oil Recovery Site.

PubMed

Yang, Changbing; Hovorka, Susan D; Treviño, Ramón H; Delgado-Alonso, Jesus

2015-07-21

This study presents a combined use of site characterization, laboratory experiments, single-well push-pull tests (PPTs), and reactive transport modeling to assess potential impacts of CO2 leakage on groundwater quality and leakage-detection ability of a groundwater monitoring network (GMN) in a potable aquifer at a CO2 enhanced oil recovery (CO2 EOR) site. Site characterization indicates that failures of plugged and abandoned wells are possible CO2 leakage pathways. Groundwater chemistry in the shallow aquifer is dominated mainly by silicate mineral weathering, and no CO2 leakage signals have been detected in the shallow aquifer. Results of the laboratory experiments and the field test show no obvious damage to groundwater chemistry should CO2 leakage occur and further were confirmed with a regional-scale reactive transport model (RSRTM) that was built upon the batch experiments and validated with the single-well PPT. Results of the RSRTM indicate that dissolved CO2 as an indicator for CO2 leakage detection works better than dissolved inorganic carbon, pH, and alkalinity at the CO2 EOR site. The detection ability of a GMN was assessed with monitoring efficiency, depending on various factors, including the natural hydraulic gradient, the leakage rate, the number of monitoring wells, the aquifer heterogeneity, and the time for a CO2 plume traveling to the monitoring well.

Tracing organic matter composition and distribution and its role on arsenic release in shallow Cambodian groundwaters

NASA Astrophysics Data System (ADS)

Lawson, Michael; Polya, David A.; Boyce, Adrian J.; Bryant, Charlotte; Ballentine, Christopher J.

2016-04-01

Biogeochemical processes that utilize dissolved organic carbon are widely thought to be responsible for the liberation of arsenic from sediments to shallow groundwater in south and southeast Asia. The accumulation of this known carcinogen to hazardously high concentrations has occurred in the primary source of drinking water in large parts of densely populated countries in this region. Both surface and sedimentary sources of organic matter have been suggested to contribute dissolved organic carbon in these aquifers. However, identification of the source of organic carbon responsible for driving arsenic release remains enigmatic and even controversial. Here, we provide the most extensive interrogation to date of the isotopic signature of ground and surface waters at a known arsenic hotspot in Cambodia. We present tritium and radiocarbon data that demonstrates that recharge through ponds and/or clay windows can transport young, surface derived organic matter into groundwater to depths of 44 m under natural flow conditions. Young organic matter dominates the dissolved organic carbon pool in groundwater that is in close proximity to these surface water sources and we suggest this is likely a regional relationship. In locations distal to surface water contact, dissolved organic carbon represents a mixture of both young surface and older sedimentary derived organic matter. Ground-surface water interaction therefore strongly influences the average dissolved organic carbon age and how this is distributed spatially across the field site. Arsenic mobilization rates appear to be controlled by the age of dissolved organic matter present in these groundwaters. Arsenic concentrations in shallow groundwaters (<20 m) increase by 1 μg/l for every year increase in dissolved organic carbon age compared to only 0.25 μg/l for every year increase in dissolved organic carbon age in deeper (>20 m) groundwaters. We suggest that, while the rate of arsenic release is greatest in shallow aquifer sediments, arsenic release also occurs in deeper aquifer sediments and as such remains an important process in controlling the spatial distribution of arsenic in the groundwaters of SE Asia. Our findings suggest that any anthropogenic activities that alter the source of groundwater recharge or the timescales over which recharge takes place may also drive changes in the natural composition of dissolved organic carbon in these groundwaters. Such changes have the potential to influence both the spatial and temporal evolution of the current groundwater arsenic hazard in this region.

Appraising options to reduce shallow groundwater tables and enhance flow conditions over regional scales in an irrigated alluvial aquifer system

USGS Publications Warehouse

Morway, Eric D.; Gates, Timothy K.; Niswonger, Richard G.

2013-01-01

Some of the world’s key agricultural production systems face big challenges to both water quantity and quality due to shallow groundwater that results from long-term intensive irrigation, namely waterlogging and salinity, water losses, and environmental problems. This paper focuses on water quantity issues, presenting finite-difference groundwater models developed to describe shallow water table levels, non-beneficial groundwater consumptive use, and return flows to streams across two regions within an irrigated alluvial river valley in southeastern Colorado, USA. The models are calibrated and applied to simulate current baseline conditions in the alluvial aquifer system and to examine actions for potentially improving these conditions. The models provide a detailed description of regional-scale subsurface unsaturated and saturated flow processes, thereby enabling detailed spatiotemporal description of groundwater levels, recharge to infiltration ratios, partitioning of ET originating from the unsaturated and saturated zones, and groundwater flows, among other variables. Hybrid automated and manual calibration of the models is achieved using extensive observations of groundwater hydraulic head, groundwater return flow to streams, aquifer stratigraphy, canal seepage, total evapotranspiration, the portion of evapotranspiration supplied by upflux from the shallow water table, and irrigation flows. Baseline results from the two regional-scale models are compared to model predictions under variations of four alternative management schemes: (1) reduced seepage from earthen canals, (2) reduced irrigation applications, (3) rotational lease fallowing (irrigation water leased to municipalities, resulting in temporary dry-up of fields), and (4) combinations of these. The potential for increasing the average water table depth by up to 1.1 and 0.7 m in the two respective modeled regions, thereby reducing the threat of waterlogging and lowering non-beneficial consumptive use from adjacent fallow and naturally-vegetated lands, is demonstrated for the alternative management intervention scenarios considered. Net annual average savings of up to about 9.9 million m3 (8000 ac ft) and 2.3 million m3 (1900 ac ft) of non-beneficial groundwater consumptive use is demonstrated for the study periods in each of the two respective study regions. Alternative water management interventions achieve varying degrees of benefits in each of the two regions, suggesting a need to adopt region-specific interventions and avoid a ‘one-size-fits-all’ approach. Impacts of the considered interventions on return flows to the river were predicted to be significant, highlighting the need for flow augmentation to comply with an interstate river compact and portending beneficial impacts on solute loading.

Groundwater Quality in the Central Eastside San Joaquin Valley, California

USGS Publications Warehouse

Belitz, Kenneth; Landon, Matthew K.

2010-01-01

The Central Eastside study unit is located in California's San Joaquin Valley. The 1,695 square mile study unit includes three groundwater subbasins: Modesto, Turlock, and Merced (California Department of Water Resources, 2003). The primary water-bearing units consist of discontinuous lenses of gravel, sand, silt, and clay, which are derived largely from the Sierra Nevada Mountains to the east. Public-supply wells provide most of the drinking water supply in the Central Eastside. Consequently, the primary aquifer in the Central Eastside study unit is defined as that part of the aquifer corresponding to the perforated interval of wells listed in the California Department of Public Health database. Public-supply wells are typically drilled to depths of 200 to 350 feet, consist of solid casing from the land surface to a depth of about 100 to 200 feet, and they are perforated below the solid casing. Water quality in the shallower and deeper parts of the aquifer system may differ from that in the primary aquifer. The Central Eastside study unit has hot and dry summers and cool, moist, winters. Average annual rainfall ranges from 11 to 15 inches. The Stanislaus, Tuolumne, and Merced Rivers, with headwaters in the Sierra Nevada Mountains, are the primary streams traversing the study unit. Land use in the study unit is approximately 59 percent (%) agricultural, 34% natural (primarily grassland), and 7% urban. The primary crops are almonds, walnuts, peaches, grapes, grain, corn, and alfalfa. The largest urban areas (2003 population in parentheses) are the cities of Modesto (206,872), Turlock (63,467), and Merced (69,512). Municipal water use accounts for about 5% of the total water use in the Central Eastside study unit, with the remainder used for irrigated agriculture. Groundwater accounts for about 75% of the municipal supply, and surface water accounts for about 25%. Recharge to the groundwater flow system is primarily from percolation of irrigation return, precipitation, seepage from reservoirs and rivers, and urban return (Burow and others, 2004; Phillips and others, 2007). The primary sources of discharge are pumping for irrigation and municipal supply, evaporation from areas with a shallow depth to water, and discharge to streams. Recharge at shallow depths and pumping from wells at greater depths causes downward movement of groundwater in the aquifer in the Central Eastside. This vertical movement of water has the potential to carry chemical constituents from shallow depths to the greater depths where supply wells commonly are perforated.

No-Impact Threshold Values for NRAP's Reduced Order Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Last, George V.; Murray, Christopher J.; Brown, Christopher F.

2013-02-01

The purpose of this study was to develop methodologies for establishing baseline datasets and statistical protocols for determining statistically significant changes between background concentrations and predicted concentrations that would be used to represent a contamination plume in the Gen II models being developed by NRAP’s Groundwater Protection team. The initial effort examined selected portions of two aquifer systems; the urban shallow-unconfined aquifer system of the Edwards-Trinity Aquifer System (being used to develop the ROM for carbon-rock aquifers, and the a portion of the High Plains Aquifer (an unconsolidated and semi-consolidated sand and gravel aquifer, being used to development the ROMmore » for sandstone aquifers). Threshold values were determined for Cd, Pb, As, pH, and TDS that could be used to identify contamination due to predicted impacts from carbon sequestration storage reservoirs, based on recommendations found in the EPA’s ''Unified Guidance for Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities'' (US Environmental Protection Agency 2009). Results from this effort can be used to inform a ''no change'' scenario with respect to groundwater impacts, rather than the use of an MCL that could be significantly higher than existing concentrations in the aquifer.« less

Surface-Water and Ground-Water Resources of Kendall County, Illinois

USGS Publications Warehouse

Kay, Robert T.; Mills, Patrick C.; Hogan, Jennifer L.; Arnold, Terri L.

2005-01-01

Water-supply needs in Kendall County, in northern Illinois, are met exclusively from ground water derived from glacial drift aquifers and bedrock aquifers open to Silurian, Ordovician, and Cambrian System units. As a result of population growth in Kendall County and the surrounding area, water use has increased from about 1.2 million gallons per day in 1957 to more than 5 million gallons per day in 2000. The purpose of this report is to characterize the surface-water and ground-water resources of Kendall County. The report presents a compilation of available information on geology, surface-water and ground-water hydrology, water quality, and water use. The Fox River is the primary surface-water body in Kendall County and is used for both wastewater disposal and as a drinking-water supply upstream of the county. Water from the Fox River requires pretreatment for use as drinking water, but the river is a potentially viable additional source of water for the county. Glacial drift aquifers capable of yielding sufficient water for municipal supply are expected to be present in northern Kendall County, along the Fox River, and in the Newark Valley and its tributaries. Glacial drift aquifers capable of yielding sufficient water for residential supply are present in most of the county, with the exception of the southeastern portion. Volatile organic compounds and select trace metals and pesticides have been detected at low concentrations in glacial drift aquifers near waste-disposal sites. Agricultural-related constituents have been detected infrequently in glacial drift aquifers near agricultural areas. However, on the basis of the available data, widespread, consistent problems with water quality are not apparent in these aquifers. These aquifers are a viable source for additional water supply, but would require further characterization prior to full development. The shallow bedrock aquifer is composed of the sandstone units of the Ancell Group, the Prairie du Chien Group, the Galena-Platteville dolomite, the Maquoketa Group, and the Silurian dolomite where these units are at the bedrock surface. The availability of water from the shallow bedrock aquifer depends primarily on the geologic unit utilized. The Silurian dolomite, Galena-Platteville dolomite, and Ancell Group can yield sufficient water for residential and municipal supply in at least some parts of the county. The Cambrian-Ordovician aquifer system is composed of the most widespread, productive aquifers in northern Illinois and is used for water supply by a number of municipalities and industrial facilities. Water levels in the aquifer system have declined by as much as 600 feet in Kendall County and the aquifer frequently contains concentrations of radium above established health guidelines.

Connections among soil, ground, and surface water chemistries characterize nitrogen loss from an agricultural landscape in the upper Missouri River Basin

NASA Astrophysics Data System (ADS)

Sigler, W. Adam; Ewing, Stephanie A.; Jones, Clain A.; Payn, Robert A.; Brookshire, E. N. Jack; Klassen, Jane K.; Jackson-Smith, Douglas; Weissmann, Gary S.

2018-01-01

Elevated nitrate in shallow aquifers is common in agricultural areas and remediation requires an understanding of nitrogen (N) leaching at a variety of spatial scales. Characterization of the drivers of nitrate leaching at the mesoscale level (102-103 km2) is needed to bridge from field-scale observations to the landscape-scale context, allowing informed water resource management decisions. Here we explore patterns in nitrate leaching rates across a depositional landform in the northern Great Plains within the Upper Missouri Basin, where the predominant land use is non-irrigated small grain production, and nitrate-N concentrations above 10 mg L-1 are common. The shallow Moccasin terrace (260 km2) aquifer is bounded in vertical extent by underlying shale and is isolated from mountain front stream recharge, such that aquifer recharge is dominated by infiltration of precipitation through agricultural soils. This configuration presents a simple landform-scale water balance that we leveraged to estimate leaching rates using groundwater nitrate concentrations and surface water discharge, and quantify uncertainty using a Monte Carlo approach based on spatial variation in observations of groundwater nitrate concentrations. A participatory research approach allowed local farmer knowledge of the landscape to be incorporated into the study design, improved selection of and access to sample sites, and enhanced prospects for addressing nitrate leaching through collaborative understanding of system hydrology. Mean landform-scale nitrate-N leaching rates were 11 and 18 kg ha-1 yr-1 during the 2012-2014 study for the two largest catchments draining the terrace. Over a standard three-year crop rotation, these leaching rates represent 19-31% of typical fertilizer N application rates; however, leaching losses are likely derived not only from fertilizer but also from soil organic N mineralization, and are apparently higher during the post-fallow phase of the crop rotation. Groundwater apparent age is relatively young (0-5 yr) based on tritium-helium analysis, but whole-aquifer turnover time calculations are an order of magnitude longer (20-23 yr), suggesting changes in groundwater may lag behind changes in land management by years to decades.

Geochemical and isotopic determination of deep groundwater contributions and salinity to the shallow groundwater and surface water systems, Mesilla Basin, New Mexico, Texas, and Mexico

NASA Astrophysics Data System (ADS)

Robertson, A.; Carroll, K. C.; Kubicki, C.; Purtshert, R.

2017-12-01

The Mesilla Basin/Conejos-Médanos aquifer system, extending from southern New Mexico to Chihuahua, Mexico, is a priority transboundary aquifer under the 2006 United States­-Mexico Transboundary Aquifer Assessment Act. Declining water levels, deteriorating water quality, and increasing groundwater use by municipal, industrial, and agricultural users on both sides of the international border raise concerns about long-term aquifer sustainability. Relative contributions of present-day and "paleo" recharge to sustainable fresh groundwater yields has not been determined and evidence suggests that a large source of salinity at the distal end of the Mesilla Basin is saline discharge from deep groundwater flow. The magnitude and distribution of those deep saline flow paths are not determined. The contribution of deep groundwater to discharge and salinity in the shallow groundwater and surface water of the Mesilla Basin will be determined by collecting discrete groundwater samples and analyzing for aqueous geochemical and isotopic tracers, as well as the radioisotopes of argon and krypton. Analytes include major ions, trace elements, the stable isotopes of water, strontium and boron isotopes, uranium isotopes, the carbon isotopes of dissolved inorganic carbon, noble gas concentrations and helium isotope ratios. Dissolved gases are extracted and captured from groundwater wells using membrane contactors in a process known as ultra-trace sampling. Gas samples are analyzed for radioisotope ratios of krypton by the ATTA method and argon by low-level counting. Effectiveness of the ultra-trace sampling device and method was evaluated by comparing results of tritium concentrations to the krypton-85 content. Good agreement between the analyses, especially in samples with undetectable tritium, indicates that the ultra-trace procedure is effective and confirms that introduction of atmospheric air has not occurred. The geochemistry data indicate a complex system of geochemical endmembers, and mixing between these endmembers. Ongoing work seeks to better constrain groundwater ages and mixing models through the coupled use of conventional aqueous geochemical and isotopic analysis and the ultra-trace constituents.

The Value of Information: Assessing the Ability of Electrical Resistivity to Detect CO2 Leakage in a Shallow Aquifer

NASA Astrophysics Data System (ADS)

Trainor Guitton, W. J.; Yang, X.; Mansoor, K.; Ramirez, A. L.; Sun, Y.; Carroll, S.

2012-12-01

This study demonstrates a methodology for evaluating the value of electrical resistivity data to detect CO2 leakage in a shallow groundwater aquifer. This methodology adopts the value of information (VOI) metric from the field of decision analysis. We consider a stakeholder's decision of whether or not to remediate the aquifer, given that they are uncertain whether or not a CO2 leak has occurred from a deep storage source through a well-bore into the shallow aquifer and what the impact of that leak would be. Two themes of uncertainty are needed for VOI studies. The first is related to the uncertain state of the subsurface, which is directly related to the outcome of the decision. In our example, it is uncertain whether or not the shallow groundwater has been impacted by CO2 leakage. The impact may be determined by the existence of depressed pH or elevated TDS (total dissolved solids) plume. We utilize results from a previous work that investigated uncertainty quantification of spatial heterogeneity and leakage rates (Mansoor et al, 2011). Therefore, we have a comprehensive suite of 713 simulations that represent our uncertainty regarding the existence and extent of a CO2 plume. Given certain TDS and pH thresholds, the simulations are categorized into two groups: impacted (a plume exists) or not impacted (no plume) at time=50 years. The second theme is related to the information's accuracy to inform us about the existence of a plume (e.g. the state of the subsurface directly relevant to the decision). The uncertainty of the information is measured by the data likelihood and is used to determine the value of imperfect information. For this demonstration, we consider how electrical resistivity data can detect the existence of pH plumes (due to the dissolution of CO2) and TDS (due to the accompanying brine leakage). The pH and TDS output from the 713 simulations are used to determine the electrical resistivity at time = 0 and time=50 years. An empirical method is used to compare the time=0 and time=50 resistivities: the geometric log mean ratio (GLMR) of the 2 data sets is calculated (Daily et al, 2004). This requires only the forward response be calculated at the 2 different times. The GLMR is used as a sensitivity measure, representing how much the electrical resistivity would change given the conditions of the aquifer. The likelihood of electrical resistivity to detect the presence of a plume is estimated by comparing the GLMR and the category (plume or no plume) for all the 713 simulations. Electrical resistivity forward models were calculated for two acquisition configurations: surface electrodes only and surface-to-borehole. For the surface acquisition, a GLMR >0.05 exclusively identifies impacted simulations. Whereas GLMR <0.05 give a more ambiguous message: both simulations that are impacted and not have GMLR<0.05. The degree of this ambiguity changes with different definitions of the plume (i.e. pH and TDS thresholds). Surface-to-borehole forward models were performed for a borehole located 200m from the leaky well. Results show that surface-to-borehole resistivity data is more reliable at distinguishing between impacted and non-impacted simulations, and therefore the VOI is higher than for surface electrodes alone. Prepared by LLNL under Contract No. DE-AC52-07NA27344.

Geochemical Effects of Induced Stream-Water and Artificial Recharge on the Equus Beds Aquifer, South-Central Kansas, 1995-2004

USGS Publications Warehouse

Schmidt, Heather C. Ross; Ziegler, Andrew C.; Parkhurst, David L.

2007-01-01

Artificial recharge of the Equus Beds aquifer is part of a strategy implemented by the city of Wichita, Kansas, to preserve future water supply and address declining water levels in the aquifer of as much as 30 feet caused by withdrawals for water supply and irrigation since the 1940s. Water-level declines represent a diminished water supply and also may accelerate migration of saltwater from the Burrton oil field to the northwest and the Arkansas River to the southwest into the freshwater of the Equus Beds aquifer. Artificial recharge, as a part of the Equus Beds Ground-Water Recharge Project, involves capturing flows larger than base flow from the Little Arkansas River and recharging the water to the Equus Beds aquifer by means of infiltration or injection. The geochemical effects on the Equus Beds aquifer of induced stream-water and artificial recharge at the Halstead and Sedgwick sites were determined through collection and analysis of hydrologic and water-quality data and the application of statistical, mixing, flow and solute-transport, and geochemical model simulations. Chloride and atrazine concentrations in the Little Arkansas River and arsenic concentrations in ground water at the Halstead recharge site frequently exceeded regulatory criteria. During 30 percent of the time from 1999 through 2004, continuous estimated chloride concentrations in the Little Arkansas River at Highway 50 near Halstead exceeded the Secondary Drinking-Water Regulation of 250 milligrams per liter established by the U.S. Environmental Protection Agency. Chloride concentrations in shallow monitoring wells located adjacent to the stream exceeded the drinking-water criterion five times from 1995 through 2004. Atrazine concentrations in water sampled from the Little Arkansas River had large variability and were at or near the drinking-water Maximum Contaminant Level of 3.0 micrograms per liter as an annual average established by the U.S. Environmental Protection Agency. Atrazine concentrations were much smaller than the drinking-water criterion and were detected at much smaller concentrations in shallow monitoring wells and diversion well water located adjacent to the stream probably because of sorption on aquifer sediment. Before and after artificial recharge, large, naturally occurring arsenic concentrations in the recharge water for the Halstead diversion well and recharge site exceeded the Maximum Contaminant Level of 10 micrograms per liter established by the U.S. Environmental Protection Agency for drinking water. Arsenic and iron concentrations decreased when water was recharged through recharge basins or a trench; however, chemical precipitation and potential biofouling eventually may decrease the artificial recharge efficiency through basins and trenches. At the Sedgwick site, chloride concentrations infrequently exceeded regulatory criteria. Large concentrations of atrazine were treated to decrease concentrations to less than regulatory criteria. Recharge of treated stream water through recharge basins avoids potentially large concentrations of arsenic and iron that exist at the Halstead diversion site. Results from a simple mixing model using chloride as a tracer indicated that the water chemistry in shallow monitoring well located adjacent to the Little Arkansas River was 80 percent of stream water, demonstrating effective recharge of the alluvial aquifer by the stream. Results also indicated that about 25 percent of the water chemistry of the diversion well water was from the shallow part of the aquifer. Additionally, diverting water through a diversion well located adjacent to the stream removed about 75 percent of the atrazine, probably through sorption to aquifer sediment, and decreased the need for additional water treatment to remove atrazine. A flow and solute-transport model was developed using water-level and chloride concentration data to simulate and better evaluate the quantity of stream-water flow to the p

Simulation of Variable-Density Ground-Water Flow and Saltwater Intrusion beneath Manhasset Neck, Nassau County, New York, 1905-2005

USGS Publications Warehouse

Monti, Jack; Misut, Paul E.; Busciolano, Ronald J.

2009-01-01

The coastal-aquifer system of Manhasset Neck, Nassau County, New York, has been stressed by pumping, which has led to saltwater intrusion and the abandonment of one public-supply well in 1944. Measurements of chloride concentrations and water levels in 2004 from the deep, confined aquifers indicate active saltwater intrusion in response to public-supply pumping. A numerical model capable of simulating three-dimensional variable-density ground-water flow and solute transport in heterogeneous, anisotropic aquifers was developed using the U.S. Geological Survey finite-element, variable-density, solute-transport simulator SUTRA, to investigate the extent of saltwater intrusion beneath Manhasset Neck. The model is composed of eight layers representing the hydrogeologic system beneath Manhasset Neck. Four modifications to the area?s previously described hydrogeologic framework were made in the model (1) the bedrock-surface altitude at well N12191 was corrected from a previously reported value, (2) part of the extent of the Raritan confining unit was shifted, (3) part of the extent of the North Shore confining unit was shifted, and (4) a clay layer in the upper glacial aquifer was added in the central and southern parts of the Manhasset Neck peninsula. Ground-water flow and the location of the freshwater-saltwater interface were simulated for three conditions (time periods) (1) a steady-state (predevelopment) simulation of no pumping prior to about 1905, (2) a 40-year transient simulation based on 1939 pumpage representing the 1905-1944 period of gradual saltwater intrusion, and (3) a 60-year transient simulation based on 1995 pumpage representing the 1945-2005 period of stabilized withdrawals. The 1939 pumpage rate (12.1 million gallons per day (Mgal/d)) applied to the 1905-1944 transient simulation caused modeled average water-level declines of 2 and 4 feet (ft) in the shallow and deep aquifer systems from predevelopment conditions, respectively, a net decrease of 5.2 Mgal/d in freshwater discharge to offshore areas and a net increase of 6.9 Mgal/d of freshwater entering the model from the eastern, western, and southern lateral boundaries. The 1995 pumpage rate (43.3 Mgal/d) applied to the 1945-2005 transient simulation caused modeled average water-level declines of 5 and 8 ft in the shallow and deep aquifer systems from predevelopment conditions, respectively, a net decrease of 13.2 Mgal/d in freshwater discharge to offshore areas and a net increase of 30.1 Mgal/d of freshwater entering the model from the eastern, western, and southern lateral boundaries. The simulated decrease in freshwater discharge to the offshore areas caused saltwater intrusion in two parts of the deep aquifer system under Manhasset Neck. Saline ground water simulated in a third part of the deep aquifer system under Manhasset Neck was due to the absence of the North Shore confining unit near Sands Point. Simulated chloride concentrations greater than 250 milligrams per liter (mg/L) were used to represent the freshwater-saltwater interface, and the movement of this concentration was evaluated for transient simulations. The decrease in the 1905-1944 simulated freshwater discharge to the offshore areas caused the freshwater-saltwater interface in the deep aquifer system to advance landward more than 1,700 ft from its steady-state position in the vicinity of Baxter Estates Village, Long Island, New York. The decrease in the 1945-2005 simulated freshwater discharge to the offshore areas caused a different area of the freshwater-saltwater interface in the deep aquifer system to advance more than 600 ft from its steady-state position approximately 1 mile south of the Baxter Estates Village. However, the 1945-2005 transient simulation underestimates the concentration and extent of saltwater intrusion determined from water-quality samples collected from wells N12508 and N12793, where measured chloride concentrations increased from 625 and 18 mg/L in 1997 t

The `Henry Problem' of `density-driven' groundwater flow versus Tothian `groundwater flow systems' with variable density: A review of the influential Biscayne aquifer data.

NASA Astrophysics Data System (ADS)

Weyer, K. U.

2017-12-01

Coastal groundwater flow investigations at the Biscayne Bay, south of Miami, Florida, gave rise to the concept of density-driven flow of seawater into coastal aquifers creating a saltwater wedge. Within that wedge, convection-driven return flow of seawater and a dispersion zone were assumed by Cooper et al. (1964) to be the cause of the Biscayne aquifer `sea water wedge'. This conclusion was based on the chloride distribution within the aquifer and on an analytical model concept assuming convection flow within a confined aquifer without taking non-chemical field data into consideration. This concept was later labelled the `Henry Problem', which any numerical variable density flow program must be able to simulate to be considered acceptable. Both, `density-driven flow' and Tothian `groundwater flow systems' (with or without variable density conditions) are driven by gravitation. The difference between the two are the boundary conditions. 'Density-driven flow' occurs under hydrostatic boundary conditions while Tothian `groundwater flow systems' occur under hydrodynamic boundary conditions. Revisiting the Cooper et al. (1964) publication with its record of piezometric field data (heads) showed that the so-called sea water wedge has been caused by discharging deep saline groundwater driven by gravitational flow and not by denser sea water. Density driven flow of seawater into the aquifer was not found reflected in the head measurements for low and high tide conditions which had been taken contemporaneously with the chloride measurements. These head measurements had not been included in the flow interpretation. The very same head measurements indicated a clear dividing line between shallow local fresh groundwater flow and saline deep groundwater flow without the existence of a dispersion zone or a convection cell. The Biscayne situation emphasizes the need for any chemical interpretation of flow pattern to be supported by head data as energy indicators of flow fields. At the Biscayne site density-driven flow of seawater did and does not exist. Instead this site and the Florida coast line in general are the end points of local fresh and regional saline groundwater flow systems driven by gravity forces and not by density differences.

Using hydrochemical data and modelling to enhance the knowledge of groundwater flow and quality in an alluvial aquifer of Zagreb, Croatia.

PubMed

Marković, Tamara; Brkić, Željka; Larva, Ozren

2013-08-01

The Zagreb alluvial aquifer system is located in the southwest of the Pannonian Basin in the Sava Valley in Croatia. It is composed of Quaternary unconsolidated deposits and is highly utilised, primarily as a water supply for the more than one million inhabitants of the capital city of Croatia. To determine the origin and dynamics of the groundwater and to enhance the knowledge of groundwater flow and the interactions between the groundwater and surface water, extensive hydrogeological and hydrochemical investigations have been completed. The groundwater levels monitored in nested observation wells and the lithological profile indicate that the aquifer is a single hydrogeologic unit, but the geochemical characteristics of the aquifer indicate stratification. The weathering of carbonate and silicate minerals has an important role in groundwater chemistry, especially in the area where old meanders of the Sava River existed. Groundwater quality was observed to be better in the deeper parts of the aquifer than in the shallower parts. Furthermore, deterioration of the groundwater quality was observed in the area under the influence of the landfill. The stable isotopic composition of all sampled waters indicates meteoric origin. NETPATH-WIN was used to calculate the mixing proportions between initial waters (water from the Sava River and groundwater from "regional" flow) in the final water (groundwater sampled from observation wells). According to the results, the mixing proportions of "regional" flow and the river water depend on hydrological conditions, the duration of certain hydrological conditions and the vicinity of the Sava River. Moreover, although the aquifer system behaves as a single hydrogeologic unit from a hydraulic point of view, it still clearly demonstrates geochemical stratification, which could be a decisive factor in future utilisation strategies for the aquifer system. Copyright © 2013 Elsevier B.V. All rights reserved.

3D coupled heat and mass transfer processes at the scale of sedimentary basisn

NASA Astrophysics Data System (ADS)

Cacace, M.; Scheck-Wenderoth, M.; Kaiser, B. O.

2014-12-01

We use coupled 3D simulations of fluid, heat, and transport based on a 3D structural model of a complex geological setting, the Northeast German Basin (NEGB). The geological structure of the NEGB is characterized by a relatively thick layer of Permian Zechstein salt, structured in differnet diapirs (up to 5000 m thick) and pillows locally reaching nearly the surface. Salt is thermally more conductive than other sediments, hydraulically impervious but highly solvable. Thus salt structures have first order influence on the temperature distribution, the deep flow regime and the salinity of groundawater bearing aquifers. In addition, the post-Permian sedimentary sequence is vertically subdivided into several aquifers and aquitards. The shallow Quaternary to late Tertiary freshwater aquifer is separated from the underlying Mesozoic saline aquifers by an embedded Tertiary clay enriched aquitard (Rupelian Aquitard). An important feature of this aquitard is that hydraulic connections between the upper and lower aquifers exist in areas where the Rupelian Aquitard is missing (hydrogeological windows). By means of 3D numerical simulations we explore the role of heat conduction, pressure, and density driven groundwater flow as well as fluid viscosity-related and salinity-dependent effects on the resulting flow and temperature fields. Our results suggest that the regional temperature distribution within the basin results from interactions between regional pressure forces and thermal diffusion locally enhanced by thermal conductivity contrasts between the different sedimentary rocks with the highly conductive salt. Buoyancy forces triggered by temperature-dependent fluid density variations affect only locally the internal thermal configuration. Locations, geometry, and wavelengths of convective thermal anomalies are mainly controlled by the permeability field and thickness values of the respective geological layers. Numerical results from 3D thermo-haline numerical simulations suggest that hydrogeological windows act as preferential domains of hydraulic interconnectivity between the different aquifers at depth, and enable vigorous heat and mass transport which causes a mixing of warm and saline groundwater with cold and less saline groundwater within both aquifers.

Ground-water levels, flow, and quality in northwestern Elkhart County, Indiana, 1980-89

USGS Publications Warehouse

Duwelius, R.F.; Silcox, C.A.

1991-01-01

The time of peak dissolved-bromide concentrations in water from shallow wells downgradient from the landfill was used to estimate a rate of horizontal flow of water in the unconfined aquifer. The average rate of flow between shallow wells downgradient from the landfill was estimated to be 1.2 feet per day. This rate is within the range of values for ground-water flow calculated according to Darcy's law.

Aquifer response to stream-stage and recharge variations. II. Convolution method and applications

USGS Publications Warehouse

Barlow, P.M.; DeSimone, L.A.; Moench, A.F.

2000-01-01

In this second of two papers, analytical step-response functions, developed in the companion paper for several cases of transient hydraulic interaction between a fully penetrating stream and a confined, leaky, or water-table aquifer, are used in the convolution integral to calculate aquifer heads, streambank seepage rates, and bank storage that occur in response to streamstage fluctuations and basinwide recharge or evapotranspiration. Two computer programs developed on the basis of these step-response functions and the convolution integral are applied to the analysis of hydraulic interaction of two alluvial stream-aquifer systems in the northeastern and central United States. These applications demonstrate the utility of the analytical functions and computer programs for estimating aquifer and streambank hydraulic properties, recharge rates, streambank seepage rates, and bank storage. Analysis of the water-table aquifer adjacent to the Blackstone River in Massachusetts suggests that the very shallow depth of water table and associated thin unsaturated zone at the site cause the aquifer to behave like a confined aquifer (negligible specific yield). This finding is consistent with previous studies that have shown that the effective specific yield of an unconfined aquifer approaches zero when the capillary fringe, where sediment pores are saturated by tension, extends to land surface. Under this condition, the aquifer's response is determined by elastic storage only. Estimates of horizontal and vertical hydraulic conductivity, specific yield, specific storage, and recharge for a water-table aquifer adjacent to the Cedar River in eastern Iowa, determined by the use of analytical methods, are in close agreement with those estimated by use of a more complex, multilayer numerical model of the aquifer. Streambank leakance of the semipervious streambank materials also was estimated for the site. The streambank-leakance parameter may be considered to be a general (or lumped) parameter that accounts not only for the resistance of flow at the river-aquifer boundary, but also for the effects of partial penetration of the river and other near-stream flow phenomena not included in the theoretical development of the step-response functions.Analytical step-response functions, developed for several cases of transient hydraulic interaction between a fully penetrating stream and a confined, leaky, or water-table aquifer, are used in the convolution integral to calculate aquifer heads, streambank seepage rates, and bank storage that occur in response to stream-stage fluctuations and basinwide recharge or evapotranspiration. Two computer programs developed on the basis of these step-response functions and the convolution integral are applied to the analysis of hydraulic interaction of two alluvial stream-aquifer systems. These applications demonstrate the utility of the analytical functions and computer programs for estimating aquifer and streambank seepage rates and bank storage.

Geohydrology of the Lloyd Aquifer, Long Island, New York

USGS Publications Warehouse

Garber, M.S.

1986-01-01

The Lloyd aquifer contains only about 9% of the water stored in Long Island 's groundwater system but is the only source of potable water for several communities near the north and south shores. The Lloyd aquifer is virtually untapped throughout most of central Long Island because current legal restrictions permit its use only in coastal areas. The upper surface of the Lloyd aquifer ranges in depth from 100 ft below land surface on the north shore to more than 1,500 ft on the south shore. Aquifer thickness increases southward from 50 ft to about 500 ft. Transmissivity ranges from 1,500 to 19,000 sq ft/day. All recharge (35 to 40 mil gal/day) and nearly all discharge is through the overlying confining unit. Nearly all of the pumpage (approximately 20 mil gal/day) is in Queens and along the north and south shores of Nassau County. Potable water can be obtained on most of Long Island in larger quantities and at shallower depths from other aquifers than from the Lloyd. Local contamination of these other aquifers, however, may require at least temporary withdrawals from the Lloyd in noncoastal areas. Significant withdrawals from the Lloyd aquifer may lower the potentiometric surface and thereby induce landward movement of sea water into the aquifer in coastal areas. (Author 's abstract)

A new hydrogeological model of charging shallow and deep aquifers in the Lake Neusiedl - Seewinkel region (Northern Burgenland, Austria)

NASA Astrophysics Data System (ADS)

Häusler, Hermann; Müllegger, Christian; Körner, Wilfried; Ottner, Franz; Prohaska, Thomas; Irrgeher, Johanna; Tchaikovsky, Anastassiya; Dober, Gregor; Gritzmann, Romana; Mykhaylyuk, Ivanna

2014-05-01

The hypothesis of ascending thermal groundwater in the Seewinkel was introduced by Tauber (1965), favoured by Schmid (1970), and followed up by Wurm (2000). The main idea of this hypothesis was up welling of saline waters from a deep aquifer along faults, which in the 1950s have been identified as such in seismic sections. An aquifer of marine deposits of Badenian to Sarmatian age was postulated as source, and hydrochemical composition of water should have changed during migration due to high contents of sodium carbonate and sulphate instead of potassium chloride in the shallow groundwater bodies of the Seewinkel. Häusler (2010) argued, however, that fault aquifers discharging saline waters nowhere have been identified in this region. Supposed that according to the ascendance hypothesis ion composition of up welling formation water could have undergone a change, the primary isotope signal of marine water should have not. In order to get a better insight to the groundwater cycle we compare results from geochemical analyses, clay mineralogical analyses, and leachates of source rocks of potential recharge areas with respective analyses of shallow and deep aquifers, and apply the method of stable hydroisotopes such as oxygen, deuterium, strontium and chloride for distinguishing origin of groundwaters. We evaluate the hypothesis of up welling connate waters, and eventually come up with a new conceptual hydrogeological model for the Neusiedl-Seewinkel region regarding composition, origin, flow direction and residence time of groundwater in shallow and deeper aquifers. The very low value of -12.26‰ for oxygen isotope ratio of thermal groundwater from the deepest aquifer drilled to a depth of about 1000 metres at Frauenkirchen in northern Seewinkel, which is not highly mineralised, excludes connate water as major source, which basically is characterized by high oxygen isotope ratio values. Taking into account that oxygen isotope ratio-values ranging from -12.0‰ to -10.5‰ in the catchment of Lake Neusiedl are characteristic for waters derived from the cooler period of the Pleistocene (Rank et al., 1982), we conclude that groundwater of the deepest aquifer of the Seewinkel is not of Badenian to Sarmatian age but only several tens of thousands of years old. The artesian wells of the Seewinkel region drilled down to several hundreds of metres yielded groundwater with oxygen isotope ratio-values ranging between -11.90‰ and -10.83‰, values fitting well to waters of Pleistocene age of that region. Since wells discharging the Leitha Mountains also revealed oxygen isotope ratio-values varying from -11.10‰ to -10.22‰, we conclude that the mountain chains surrounding Lake Neusiedl basically charged both shallow and deeper aquifers of the Seewinkel. From oxygen isotope ratios of these groundwater bodies we therefore conclude that first the majority of aquifers of the Lake Neusiedl region was charged from the surrounding mountain chains, and second that salinity of soils in the Seewinkel region cannot be derived from up welling connate water, as has been proofed for Lake Kelemenszék area south of Budapest (Simon et al., 2011). There is no doubt on the fact, however, that differing amounts of free carbon dioxide in several aquifers of the Seewinkel region originate from deep-seated post volcanic activity in this region. Häusler, H. (2010)(ed.): Geologische Karte der Republik Österreich 1:50.000, Erläuterungen zur Geologischen Karte 78 Rust.- 191 S., 65 Abb., 5 Tab., 2 Taf., (Geologische Bundesanstalt), Wien. Rank, D., Rajner, V., Staudner, F. and Papesch, W. (1982): Zur Altersdatierung der Grundwässer am Ostufer des Neusiedlersees.- BFB-Bericht, 43, 197-204, 2 Abb., (Biologisches Forschungsinstitut für Burgenland), Illmitz. Simon, S., Mádl-Szőnyi, J., Müller, I. and Pogácsás, G. (2011): Conceptual model for surface salinization in an overpressured and a superimposed gravity-flow field, Lake Kelemenszék area, Hungary.- Hydrogeology Journal, 19, 701-717. Tauber, A. F. (1965): Geologische Typologie und Genese der Mineralquellen und Mineralwässer im Neusiedlerseegebiet.- Wissenschaftliche Arbeiten aus dem Burgenland, 34, 259-304, 6 Tab., Eisenstadt. Wurm, M. (2000): Hydrogeochemische Methodik zur Klärung von Interaktionsprozessen von Formations-, Mineral-, Tiefengrund- und oberflächennahen Grundwässern im Einzugsgebiet des Neusiedlersees.- Unveröffentlichte Diplomarbeit, Institut für Geowissenschaften, Abteilung für Geologie und Lagerstättenlehre, Montanuniversität Leoben, 125 S., zahlr. Abb., Anhang (71 hydrochemische Analysen), Leoben.

Shallow Carbon Sequestration Demonstration Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pendergrass, Gary; Fraley, David; Alter, William

The potential for carbon sequestration at relatively shallow depths was investigated at four power plant sites in Missouri. Exploratory boreholes were cored through the Davis Shale confining layer into the St. Francois aquifer (Lamotte Sandstone and Bonneterre Formation). Precambrian basement contact ranged from 654.4 meters at the John Twitty Energy Center in Southwest Missouri to over 1100 meters near the Sioux Power Plant in St. Charles County. Investigations at the John Twitty Energy Center included 3D seismic reflection surveys, downhole geophysical logging and pressure testing, and laboratory analysis of rock core and water samples. Plans to perform injectivity tests atmore » the John Twitty Energy Center, using food grade CO{sub 2}, had to be abandoned when the isolated aquifer was found to have very low dissolved solids content. Investigations at the Sioux Plant and Thomas Hill Energy Center in Randolph County found suitably saline conditions in the St. Francois. A fourth borehole in Platte County was discontinued before reaching the aquifer. Laboratory analyses of rock core and water samples indicate that the St. Charles and Randolph County sites could have storage potentials worthy of further study. The report suggests additional Missouri areas for further investigation as well.« less

Pollution indicators in groundwater of two agricultural catchments in Lower Silesia (Poland)

NASA Astrophysics Data System (ADS)

Kasperczyk, Lidia; Modelska, Magdalena; Staśko, Stanisław

2016-12-01

The article discusses the content and source of mineral nitrogen compounds in groundwater, based on the data collected in two river catchments in two series (spring and autumn 2014). The study area comprises two catchments located in Lower Silesia, Poland - Cicha Woda and Sąsiecznica. Both catchments are characterised agricultural character of development. In the both researched areas, the points of State Environmental Monitoring (SEM) are located but only the Cicha Woda area is classified as nitrate vulnerable zone (NVZ). To analyse and compare the contamination of Quaternary and Neogene aquifers, the concentration of nitrates, nitrites, ammonium and potassium ions was measured primarily. Results showed the exceedance of nitrogen mineral forms of shallow groundwater Quaternary aquifer in both basins. The concentration of nitrates range from 0.08 to 142.12 mgNO3 -/dm3 (Cicha Woda) and from 2.6 to 137.65 mg NO3 -/dm3 (Sąsiecznica). The major source of pollution is probably the intensive agriculture activity. It causes a degradation of the shallow groundwater because of nitrate, nitrite, potassium, phosphates and ammonium contents. There was no observed contamination of anthropogenic origin in the deeper Neogene aquifer of Cicha Woda catchment.

Altitude of the water table in the alluvial and Wilcox aquifers in the vicinity of Richland and Tehuacana creeks and the Trinity River, Texas, December 1979

USGS Publications Warehouse

Garza, Sergio

1980-01-01

This map shows the altitude of the water table in the alluvial and Wilcox aquifers in the vicinity of Richland and Tehuacana Creeks and the Trinity River, Tex., in December 1979. The water-table contours were constructed on the basis of water-level control derived from an inventory of shallow wells in the area, topographic maps, and field locations of numerous small springs and seeps. (USGS)

Vertical distribution of hydraulic characteristics and water quality in three boreholes in the Galena-Platteville Aquifer at the Parson's Casket Hardware Superfund site, Belvidere, Illinois, 1990

USGS Publications Warehouse

Mills, P.C.

1993-01-01

The U.S. Geological Survey investigated contaminant migration in the Galena-Platteville aquifer at the Parson's Casket Hardware site in Belvidere, Ill. This report presents the results of the first phase of the investigation, from August through December 1990. A packer assembly was used to isolate various depth intervals in three 150-foot-deep boreholes in the dolomite aquifer. Aquifer-test data include vertical distributions of vertical hydraulic gradient, horizontal hydraulic conductivity (K), and response of water levels in observation wells to borehole pumping. Water-quality data include vertical distributions of field-measured properties and laboratory determinations of concentrations of volatile organic compounds (VOC's). vertical hydraulic gradients in the aquifer were downward. The downward gradients ranged from less than 0.01 to 0.37 foot/foot. The largest gradient was associated with an elevated-K interval at 115 to 125 feet below land surface. The hydraulic characteristics of strata within the aquifer seem to be generally consistent across the site. The strata can be subdivided into five hydraulic units with the following approximate depth ranges-and K's : (1) a 1- to 5-foot-thick weathered surface at about 35 feet below land surface, 1-200 ft/d (feet per day); (2) 35-80 feet, 0.05-0.5 ft/d; (3) 80-115 feet, 0.5 ft/d; (4) 115-125 feet, 0.5-10 ft/d; and (5) 125-150 feet, 0.5 ft/d. Water-level drawdowns were detected in one shallow bedrock observation well during pumping of some of the packed intervals in a nearby borehole, indicating that the degree of vertical connection between some intervals in the aquifer may be greater than that between others. During development pumping of one borehole, drawdowns were detected in a nearby well screened in the lower part of the overlying glacial-drift deposits, indicating hydraulic connection between the glacial drift aquifer and the bedrock aquifer. VOC's were detected throughout the upper half (about 150 feet ) of the bedrock aquifer beneath the site. The detected compounds were predominantly chlorinated ethenes and ethanes (maximum concentration was 570 ppb (parts per billion) of trichloroethylene. There was a positive correlation between concentrations of VOC's, specific conductance, and K. The distribution of VOC concentrations indicate that the low-K dolomite beds in the Galena-Platteville aquifer may impede the downward migration of the VOC's and that the high-K beds and fissures may provide pathways for the lateral migration of VOC's through the aquifer. Contaminant migration is possibly affected by ground-water flow through vertical fractures that connect shallow beds with deeper beds in the aquifer, thus explaining the detections of some VOC species at intermittent depths.

Water resources of the Prairie Island Indian Reservation, Minnesota, 1994-97

USGS Publications Warehouse

Cowdery, Timothy K.

1999-01-01

The only surface-water constituents exceeding U.S. Environmental Protection Agency drinking water standards was coliform or fecal streptococci bacteria, which was exceeded in all samples. Thirteen percent of ground-water samples exceeded the nitrate maximum contaminant level (MCL), but this is probably higher than the percentage of the aquifer exceeding the nitrate MCL because most of the wells sampled were shallow. Surface-water recharge to and ground-water discharge from the surficial aquifer influence the water quality in both the aquifer and the surrounding surface water. However, surface water probably influences ground-water quality more because of the greater amount of surface water flowing through the study area.

Application of carbonate cyclostratigraphy and borehole geophysics to delineate porosity and preferential flow in the karst limestone of the Biscayne aquifer, SE Florida

USGS Publications Warehouse

Cunningham, K.J.; Renken, R.A.; Wacker, M.A.; Zygnerski, M.R.; Robinson, E.; Shapiro, A.M.; Wingard, G.L.

2006-01-01

Combined analyses of cores, borehole geophysical logs, and cyclostratigraphy produced a new conceptual hydrogeologic framework for the triple-porosity (matrix, touching-vug, and conduit porosity) karst limestone of the Biscayne aquifer in a 0.65 km2 study area, SE Florida. Vertical lithofacies successions, which have recurrent stacking patterns, fit within high-frequency cycles. We define three ideal high-frequency cycles as: (1) upward-shallowing subtidal cycles, (2) upward-shallowing paralic cycles, and (3) aggradational subtidal cycles. Digital optical borehole images, tracers, and flow meters indicate that there is a predictable vertical pattern of porosity and permeability within the three ideal cycles, because the distribution of porosity and permeability is related to lithofacies. Stratiform zones of high permeability commonly occur just above flooding surfaces in the lower part of upward-shallowing subtidal and paralic cycles, forming preferential groundwater flow zones. Aggradational subtidal cycles are either mostly high-permeability zones or leaky, low-permeability units. In the study area, groundwater flow within stratiform high-permeability zones is through a secondary pore system of touching-vug porosity principally related to molds of burrows and pelecypods and to interburrow vugs. Movement of a dye-tracer pulse observed using a borehole fluid-temperature tool during a conservative tracer test indicates heterogeneous permeability. Advective movement of the tracer appears to be most concentrated within a thin stratiform flow zone contained within the lower part of a high-frequency cycle, indicating a distinctly high relative permeability for this zone. Borehole flow-meter measurements corroborate the relatively high permeability of the flow zone. Identification and mapping of such high-permeability flow zones is crucial to conceptualization of karst groundwater flow within a cyclostratigraphic framework. Many karst aquifers are included in cyclic platform carbonates. Clearly, a cyclostratigraphic approach that translates carbonate aquifer heterogeneity into a consistent framework of correlative units will improve simulation of karst groundwater flow. ?? 2006 Geological Society of America.

Recharge of low-arsenic aquifers tapped by community wells in Araihazar, Bangladesh, inferred from environmental isotopes.

PubMed

Mihajlov, I; Stute, M; Schlosser, P; Mailloux, B J; Zheng, Y; Choudhury, I; Ahmed, K M; van Geen, A

2016-05-01

More than 100,000 community wells have been installed in the 150-300 m depth range throughout Bangladesh over the past decade to provide low-arsenic drinking water (<10 μg/L As), but little is known about how aquifers tapped by these wells are recharged. Within a 25 km 2 area of Bangladesh east of Dhaka, groundwater from 65 low-As wells in the 35-240 m depth range was sampled for tritium ( 3 H), oxygen and hydrogen isotopes of water ( 18 O/ 16 O and 2 H/ 1 H), carbon isotope ratios in dissolved inorganic carbon (DIC, 14 C/ 12 C and 13 C/ 12 C), noble gases, and a suite of dissolved constituents, including major cations, anions, and trace elements. At shallow depths (<90 m), 24 out of 42 wells contain detectable 3 H of up to 6 TU, indicating the presence of groundwater recharged within 60 years. Radiocarbon ( 14 C) ages in DIC range from modern to 10 kyr. In the 90-240 m depth range, however, only 5 wells shallower than 150 m contain detectable 3 H (<0.3 TU) and 14 C ages of DIC cluster around 10 kyr. The radiogenic helium ( 4 He) content in groundwater increases linearly across the entire range of 14 C ages at a rate of 2.5×10 -12 ccSTP 4 He g -1 yr -1 . Within the samples from depths >90 m, systematic relationships between 18 O/ 16 O, 2 H/ 1 H, 13 C/ 12 C and 14 C/ 12 C, and variations in noble gas temperatures, suggest that changes in monsoon intensity and vegetation cover occurred at the onset of the Holocene, when the sampled water was recharged. Thus, the deeper low-As aquifers remain relatively isolated from the shallow, high-As aquifer.

Recharge of low-arsenic aquifers tapped by community wells in Araihazar, Bangladesh, inferred from environmental isotopes

PubMed Central

Mihajlov, I.; Stute, M.; Schlosser, P.; Mailloux, B. J.; Zheng, Y.; Choudhury, I.; Ahmed, K.M.; van Geen, A.

2017-01-01

More than 100,000 community wells have been installed in the 150–300 m depth range throughout Bangladesh over the past decade to provide low-arsenic drinking water (<10 μg/L As), but little is known about how aquifers tapped by these wells are recharged. Within a 25 km2 area of Bangladesh east of Dhaka, groundwater from 65 low-As wells in the 35–240 m depth range was sampled for tritium (3H), oxygen and hydrogen isotopes of water (18O/16O and 2H/1H), carbon isotope ratios in dissolved inorganic carbon (DIC, 14C/12C and 13C/12C), noble gases, and a suite of dissolved constituents, including major cations, anions, and trace elements. At shallow depths (<90 m), 24 out of 42 wells contain detectable 3H of up to 6 TU, indicating the presence of groundwater recharged within 60 years. Radiocarbon (14C) ages in DIC range from modern to 10 kyr. In the 90–240 m depth range, however, only 5 wells shallower than 150 m contain detectable 3H (<0.3 TU) and 14C ages of DIC cluster around 10 kyr. The radiogenic helium (4He) content in groundwater increases linearly across the entire range of 14C ages at a rate of 2.5×10−12 ccSTP 4He g−1 yr−1. Within the samples from depths >90 m, systematic relationships between 18O/16O, 2H/1H, 13C/12C and 14C/12C, and variations in noble gas temperatures, suggest that changes in monsoon intensity and vegetation cover occurred at the onset of the Holocene, when the sampled water was recharged. Thus, the deeper low-As aquifers remain relatively isolated from the shallow, high-As aquifer. PMID:28966406

Superfund Record of Decision (EPA Region 4): USMC Camp Lejeune Military Reservation, NC. (First remedial action), September 1992. Interim report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-09-23

The 500-acre Camp Lejeune Military Reservation is located 15 miles southeast of Jacksonville, in Onslow County, North Carolina. Within the site lies the Hadnot Point Industrial Area (HPIA), which was constructed in the late 1930's. It is composed of 75 buildings and facilities, which include gas stations, offices, storage yards, maintenance shops, and a dry cleaning plant. Several areas of the HPIA have been investigated for potential contamination attributed to Marine Corps activities and operations that resulted in a generation of potentially hazardous wastes. The ROD addresses an interim remedial action for the shallow aquifer at the HPIA to protectmore » human health from exposure to VOCs and metals. The primary contaminants of concern affecting the shallow ground water aquifer are VOCs, including benzene and TCE; and metals, including arsenic, chromium, and lead.« less

Identifying sources, formation pathways and geological controls of methane in shallow groundwater above unconventional natural gas plays in Alberta, Canada

NASA Astrophysics Data System (ADS)

Mayer, B.; Humez, P.; Nightingale, M.; Ing, J.; Kingston, A. W.; Clarkson, C.; Cahill, A.; Parker, B. L.; Cherry, J. A.; Millot, R.; Kloppmann, W.; Osadetz, K.; Lawton, D.

2015-12-01

With the advent of shale gas development facilitated by hydraulic fracturing it has become increasingly important to develop tracer tools to scientifically determine potential impacts of stray gases on shallow aquifers. To assess potential future impacts on shallow aquifers by leakage of natural gas from unconventional energy resource development, it is essential to establish a reliable baseline. Occurrence of methane in shallow groundwater in Alberta (Canada) between 2006 and 2014 was assessed and was ubiquitous in 186 sampled monitoring wells. Free and dissolved gas sampling and measurement approaches yielded comparable results with often low methane concentrations in shallow groundwater, but in 28 samples methane exceeded 10 mg/L in dissolved gas and 300,000 ppmv in free gas. Methane concentrations in free and dissolved gas samples were found to increase with well depth and were especially elevated in groundwater obtained from aquifers containing coal seams and shale units. Carbon isotope ratios of methane averaged -69.7 ± 11.1 ‰ in free gas and -65.6 ± 8.9 ‰ in dissolved gas. δ13C values were not found to vary with well depth or lithology indicating that the methane in Alberta groundwater was formed via a similar mechanism. The low δ13C values in concert with average δ2H values of -289 ± 44 ‰ suggest that most methane was of biogenic origin predominantly generated via CO2 reduction. This interpretation is confirmed by gas dryness parameters typically >500 due to only small amounts of ethane and a lack of propane in most samples. Novel approaches of in-situ concentration and isotope measurements for methane during drilling of a 530 m deep well yielded a mud-gas profile characterizing natural gas occurrences in the intermediate zone. Comparison with mudgas profile carbon isotope data revealed that methane in the investigated shallow groundwater in Alberta is isotopically similar to hydrocarbon gases found in 100-250 meter depths in the Western Canadian Sedimentary Basin and is currently not sourced from thermogenic hydrocarbon occurrences in deeper portions of the basin. The assembled data set provides evidence that potential stray gas contamination by isotopically distinct deeper thermogenic gases from the intermediate or from production zones can be effectively detected by suitable monitoring programs.

Evidence of Decoupling between Arsenic and Phosphate in Shallow Groundwater of Bangladesh and Potential Implications.

PubMed

Aziz, Z; Bostick, B C; Zheng, Y; Huq, M R; Rahman, M M; Ahmed, K M; van Geen, A

2017-02-01

Reductive dissolution of iron oxyhydroxides and reduction of arsenic are often invoked as leading causes of high dissolved As levels in shallow groundwater of Bangladesh. The second of these assumptions is questioned here by comparing the behavior As and phosphate (P), a structural analogue for As (V) which also adsorbs strongly to Fe oxyhydroxides but is not subject to reduction. The first line of evidence is provided by a detailed groundwater time-series spanning two years for three wells in the 6-9 m depth range showing removal of As(III) from shallow groundwater during the monsoon without of loss of P. The data indicate a loss of ~90% of the dissolved As from groundwater in the intermediate well relative to a level of 3 μmol/L As predicted by conservative mixing between groundwater sampled from the shallower and the deeper well. In contrast, P concentrations of ~30 μmol/L in the intermediate well closely match the prediction from conservative mixing. Reduction therefore appears to inhibit the release of As to groundwater at this site relative to P instead of enhancing it. A re-analysis of existing groundwater As and P data from across the country provides a broader context for this finding and confirms that, without reduction, elevated concentrations of As would probably be even more widespread in shallow aquifers of Bangladesh. Without providing definite proof, X-ray absorption spectroscopy of sediment from the time-series site and elsewhere suggests that the loss of As from groundwater may be coupled to precipitation of As sulfide. Further study is needed to assess the implications of these observations for shallow aquifers that have been subjected to increased withdrawals for irrigation in recent decades.

Evidence of Decoupling between Arsenic and Phosphate in Shallow Groundwater of Bangladesh and Potential Implications

PubMed Central

Aziz, Z.; Bostick, B.C.; Zheng, Y.; Huq, M.R.; Rahman, M.M.; Ahmed, K.M.; van Geen, A.

2016-01-01

Reductive dissolution of iron oxyhydroxides and reduction of arsenic are often invoked as leading causes of high dissolved As levels in shallow groundwater of Bangladesh. The second of these assumptions is questioned here by comparing the behavior As and phosphate (P), a structural analogue for As (V) which also adsorbs strongly to Fe oxyhydroxides but is not subject to reduction. The first line of evidence is provided by a detailed groundwater time-series spanning two years for three wells in the 6–9 m depth range showing removal of As(III) from shallow groundwater during the monsoon without of loss of P. The data indicate a loss of ~90% of the dissolved As from groundwater in the intermediate well relative to a level of 3 μmol/L As predicted by conservative mixing between groundwater sampled from the shallower and the deeper well. In contrast, P concentrations of ~30 μmol/L in the intermediate well closely match the prediction from conservative mixing. Reduction therefore appears to inhibit the release of As to groundwater at this site relative to P instead of enhancing it. A re-analysis of existing groundwater As and P data from across the country provides a broader context for this finding and confirms that, without reduction, elevated concentrations of As would probably be even more widespread in shallow aquifers of Bangladesh. Without providing definite proof, X-ray absorption spectroscopy of sediment from the time-series site and elsewhere suggests that the loss of As from groundwater may be coupled to precipitation of As sulfide. Further study is needed to assess the implications of these observations for shallow aquifers that have been subjected to increased withdrawals for irrigation in recent decades. PMID:28239232

Preliminary assessment of the occurrence and possible sources of MTBE in groundwater in the United States, 1993-1994

USGS Publications Warehouse

Squillace, P.J.; Zogorski, J.S.; Wilber, W.G.; Price, C.V.

1996-01-01

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concentrations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE) is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient groundwater from urban areas that were collected during 1993-1994 aspart of the U.S. Geological Survey's National Water-Quality Assessment program. Samples were collected from five drinking water wells, 12 springs, and 193 monitoring wells in urban areas. No MTBE was detected in drinking water wells. At a reporting level of 0.2 ??g/L, MTBE was detected most frequently in shallow groundwater from urban areas (27% of 210 wells and springs sampled in eight areas) as compared to shallow groundwater from agricultural areas (1.3% of 549 wells sampled in 21 areas) or deeper groundwater from major aquifers (1.0% of 412 wells sampled in nine areas). Only 3% of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ??g/L, which is the estimated lower limit of the United States Environmental Protection Agency draft drinking water health advisory. Because MTBE is persistent and mobile in groundwater, it can move from shallow to deeper aquifers with time. In shallow urban groundwater, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylene (BTEX) compounds, which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in groundwater include point sources, such as leaking storage tanks, and non-point sources, such as recharge of precipitation and stormwater runoff.

Metatranscriptomic evidence of pervasive and diverse chemolithoautotrophy relevant to C, S, N and Fe cycling in a shallow alluvial aquifer

PubMed Central

Jewell, Talia N M; Karaoz, Ulas; Brodie, Eoin L; Williams, Kenneth H; Beller, Harry R

2016-01-01

Groundwater ecosystems are conventionally thought to be fueled by surface-derived allochthonous organic matter and dominated by heterotrophic microbes living under often-oligotrophic conditions. However, in a 2-month study of nitrate amendment to a perennially suboxic aquifer in Rifle (CO), strain-resolved metatranscriptomic analysis revealed pervasive and diverse chemolithoautotrophic bacterial activity relevant to C, S, N and Fe cycling. Before nitrate injection, anaerobic ammonia-oxidizing (anammox) bacteria accounted for 16% of overall microbial community gene expression, whereas during the nitrate injection, two other groups of chemolithoautotrophic bacteria collectively accounted for 80% of the metatranscriptome: (1) members of the Fe(II)-oxidizing Gallionellaceae family and (2) strains of the S-oxidizing species, Sulfurimonas denitrificans. Notably, the proportion of the metatranscriptome accounted for by these three groups was considerably greater than the proportion of the metagenome coverage that they represented. Transcriptional analysis revealed some unexpected metabolic couplings, in particular, putative nitrate-dependent Fe(II) and S oxidation among nominally microaerophilic Gallionellaceae strains, including expression of periplasmic (NapAB) and membrane-bound (NarGHI) nitrate reductases. The three most active groups of chemolithoautotrophic bacteria in this study had overlapping metabolisms that allowed them to occupy different yet related metabolic niches throughout the study. Overall, these results highlight the important role that chemolithoautotrophy can have in aquifer biogeochemical cycling, a finding that has broad implications for understanding terrestrial carbon cycling and is supported by recent studies of geochemically diverse aquifers. PMID:26943628