USSR and Eastern Europe Scientific Abstracts Physics and Mathematics No. 35

DTIC Science & Technology

1977-06-15

depends on the film thickness, on the conditions of demagnetization , and on the constant of uniaxial magnetic anisotropy. The distribution of...Acoustics 2 Crystals and Semiconductors.. .*. 16 Electricity and Magnetism 51 Fluid Dynamics 64 Lasers and Masers 88 Magnetohydrodynamics 110...Molecular Physics 132 Nuclear Physics 133 Optics and Spectroscopy 158 Stress, Strain and Deformation 165 Superconductivity 170 Theoretical

Magnetization switching behavior with competing anisotropies in epitaxial Co3FeN /MnN exchange-coupled bilayers

NASA Astrophysics Data System (ADS)

Hajiri, T.; Yoshida, T.; Jaiswal, S.; Filianina, M.; Borie, B.; Ando, H.; Asano, H.; Zabel, H.; Kläui, M.

2016-11-01

We report unusual magnetization switching processes and angular-dependent exchange bias effects in fully epitaxial Co3FeN /MnN bilayers, where magnetocrystalline anisotropy and exchange coupling compete, probed by longitudinal and transverse magneto-optic Kerr effect (MOKE) magnetometry. The MOKE loops show multistep jumps corresponding to the nucleation and propagation of 90∘ domain walls in as-grown bilayers. By inducing exchange coupling, we confirm changes of the magnetization switching process due to the unidirectional anisotropy field of the exchange coupling. Taking into account the experimentally obtained values of the fourfold magnetocrystalline anisotropy, the unidirectional anisotropy field, the exchange-coupling constant, and the uniaxial anisotropy including its direction, the calculated angular-dependent exchange bias reproduces the experimental results. These results demonstrate the essential role of the competition between magnetocrystalline anisotropy and exchange coupling for understanding and tailoring exchange-coupling phenomena usable for engineering switching in fully epitaxial bilayers made of tailored materials.

Magnetic microstructure and magnetic properties of uniaxial itinerant ferromagnet Fe 3GeTe 2

DOE PAGES

León-Brito, Neliza; Bauer, Eric Dietzgen; Ronning, Filip; ...

2016-08-28

Here, magnetic force microscopy was used to observe the magnetic microstructure of Fe 3GeTe 2 at 4 K on the (001) surface. The surface magnetic structure consists of a two-phase domain branching pattern that is characteristic for highly uniaxial magnets in the plane perpendicular to the magnetic easy axis. The average surface magnetic domain width D s = 1.3 μm determined from this pattern, in combination with intrinsic properties calculated from bulk magnetization data (the saturation magnetization M s = 376 emu/cm 3 and the uniaxial magnetocrystalline anisotropy constant K u = 1.46 × 10 7 erg/cm 3), was usedmore » to determine the following micromagnetic parameters for Fe 3GeTe 2 from phenomenological models: the domain wall energy γ w = 4.7 erg/cm 2, the domain wall thickness δ w = 2.5 nm, the exchange stiffness constant A ex = 0.95 × 10 –7 erg/cm, the exchange length l ex = 2.3 nm, and the critical single domain particle diameter d c = 470 nm.« less

Fabrication of flexible oriented magnetic thin films with large in-plane uniaxial anisotropy by roll-to-roll nanoimprint lithography

NASA Astrophysics Data System (ADS)

Thantirige, Rukshan M.; John, Jacob; Pradhan, Nihar R.; Carter, Kenneth R.; Tuominen, Mark T.

2016-06-01

Here, we report wafer scale fabrication of densely packed Fe nanostripe-based magnetic thin films on a flexible substrate and their magnetic anisotropy properties. We find that Fe nanostripes exhibit large in-plane uniaxial anisotropy and nearly square hysteresis loops with energy products (BHmax) exceeding 3 MGOe at room temperature. High density Fe nanostripes were fabricated on 70 nm flexible polyethylene terephthalate (PET) gratings, which were made by a roll-to-roll (R2R) UV nanoimprint lithography technique. We observed large in-plane uniaxial anisotropies along the long dimension of nanostripes that can be attributed to the shape. Temperature dependent hysteresis measurements confirm that the magnetization reversal is driven by non-coherent rotation reversal processes.

A magneto-optic technique for studying magnetization reversal processes and anisotropies applied to Co/Cu/Co trilayer structures

NASA Astrophysics Data System (ADS)

Daboo, C.; Bland, J. A. C.; Hicken, R. J.; Ives, A. J. R.; Baird, M. J.; Walker, M. J.

1993-05-01

We report the magnetization reversal and magnetic anisotropy behavior of ultrathin Co/Cu(111)/Co (dCu=20 and 27 Å) trilayer structures prepared by MBE on a 500-Å Ge/GaAs(110) epilayer. We describe an arrangement in which the magnetization components parallel and perpendicular to the applied field are both determined from longitudinal MOKE measurements. For the samples examined, coherent rotation of the magnetization vector is observed when the magnetic field is applied along the hard in-plane anisotropy axis, with the magnitude of the magnetization vector constant and close to its bulk value. Results of micromagnetic calculations closely reproduce the observed parallel and perpendicular magnetization loops, and yield strong uniaxial magnetic anisotropies in both layers while the interlayer coupling appears to be absent or negligible in comparison with the anisotropy strengths. An absence of antiferromagnetic (AF) coupling has been observed previously [W. F. Egelhoff, Jr. and M. T. Kief, Phys. Rev. B 45, 7795 (1992)] in contrast to recent results, indicating that AF coupling [M. T. Johnson et al., Phys. Rev. Lett. 69, 969 (1992)] and GMR [D. Grieg et al., J. Magn. Magn. Mater. 110, L239 (1992)] can occur in Co/Cu(111)/Co structures grown by MBE, but these properties are sensitively dependent on growth conditions. The absence of coupling in our samples is attributed to the presence of a significant interface roughness induced by the Ge epilayer. The uniaxial anisotropies are assumed to arise from strain or defects induced in the film.

Controllable strain-induced uniaxial anisotropy of Fe{sub 81}Ga{sub 19} films deposited on flexible bowed-substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Guohong; Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201; School of Science, Nanchang University, Nanchang 330031

2013-11-07

We propose a convenient method to induce a uniaxial anisotropy in magnetostrictive Fe{sub 81}Ga{sub 19} films grown on flexible polyethylene terephthalate (PET) substrates by bending the substrate prior to deposition. A tensile/compressive stress is induced in the Fe{sub 81}Ga{sub 19} films when PET substrates are shaped from concave/convex to flat after deposition. The stressed Fe{sub 81}Ga{sub 19} films exhibit a significant uniaxial magnetic anisotropy due to the internal stress arising from changes in shape of PET substrates. The easy axis is along the tensile stress direction and the coercive field along easy axis is increased with increasing the internal tensilemore » stress. The remanence of hard axis is decreased with increasing the compressive stress, while the coercive field is almost unchanged. A modified Stoner-Wohlfarth model with considering the distribution of easy axes in polycrystalline films is used to account for the magnetic properties tuned by the strain-controlled magnetoelastic anisotropy in flexible Fe{sub 81}Ga{sub 19} films. Our investigations provide a convenient way to induce uniaxial magnetic anisotropy, which is particularly important for fabricating flexible magnetoelectronic devices.« less

Heterojunction-induced magnetic anisotropy and magnetization reversal of Ni wires on LiNbO3 substrate

NASA Astrophysics Data System (ADS)

Yamaguchi, Akinobu; Ohkochi, Takuo; Yasui, Akira; Kinoshita, Toyohiko; Yamada, Keisuke

2018-05-01

We report magnetic domain formation control within micro-scale polycrystalline Ni wires on a single-crystal Y-cut 128° LiNbO3 substrate. X-ray magnetic circular dichroism photoemission electron microscopy (XCDM-PEEM), micromagnetic simulations, and magnetoresistance (MR) measurements allowed us to estimate the uniaxial magnetic anisotropy induced by the magnetoelastic effect that originated at the interface between each Ni layer and the LiNbO3 substrate. Comparison of the XMCD-PEEM and MR measurement results shows that the competition between the shape magnetic anisotropy and the uniaxial magnetic anisotropy parallel to the orientation flat (OF) direction of the substrate leads to variations in both the magnetization order and the magnetization reversal process. The uniaxial magnetic anisotropy is estimated to be approximately 3.3 kJ/m3. This heterojunction structure composed of ferromagnetic and ferroelectric layers thus offers alternative ways to produce artificial functional multiferroic materials and devices.

Growth-induced anisotropy in bismuth - Rare-earth iron garnets

NASA Technical Reports Server (NTRS)

Fratello, V. J.; Slusky, S. E. G.; Brandle, C. D.; Norelli, M. P.

1986-01-01

The bismuth-doped rare-earth iron garnets, (R3-x-yBixPby)Fe5O12 (Bi:RIG, R = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y), were prepared under constant growth conditions to investigate the influence of ionic species on the bismuth-based growth-induced uniaxial anisotropy K(u) exp g. The effect of ionic species on growth-induced anisotropy in Bi:RIG was not consistent with the ionic size model of site ordering. In particular, Bi:SmIG, Bi:EuIG, and Bi:TbIG displayed high growth-induced anisotropies, up to 331,000 erg/cu cm at room temperature for x of about 0.5. The temperature dependence of these K(u) exp gs was somewhat higher than that of the well studied Bi:YIG. The site ordering of Bi can be modeled by assuming that small, low-oxygen-coordination BiOw exp +3-2 w melt complexes have a strong site selectivity for small, high-oxygen coordination sites at the growth interface.

Temperature-dependent magnetic anisotropy in the layered magnetic semiconductors Cr I3 and CrB r3

NASA Astrophysics Data System (ADS)

Richter, Nils; Weber, Daniel; Martin, Franziska; Singh, Nirpendra; Schwingenschlögl, Udo; Lotsch, Bettina V.; Kläui, Mathias

2018-02-01

Chromium trihalides are layered and exfoliable semiconductors and exhibit unusual magnetic properties with a surprising temperature dependence of the magnetization. By analyzing the evolution of the magnetocrystalline anisotropy with temperature in chromium iodide Cr I3 , we find it strongly changes from Ku=300 ±50 kJ / m3 at 5 K to Ku=43 ±7 kJ / m3 at 60 K , close to the Curie temperature. We draw a direct comparison to CrB r3 , which serves as a reference, and where we find results consistent with literature. In particular, we show that the anisotropy change in the iodide compound is more than 3 times larger than in the bromide. We analyze this temperature dependence using a classical model, showing that the anisotropy constant scales with the magnetization at any given temperature below the Curie temperature, indicating that the temperature dependence can be explained by a dominant uniaxial anisotropy where this scaling results from local spin clusters having thermally induced magnetization directions that deviate from the overall magnetization.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerhard, F.; Schumacher, C.; Gould, C.

NiMnSb is a ferromagnetic half-metal which, because of its rich anisotropy and very low Gilbert damping, is a promising candidate for applications in information technologies. We have investigated the in-plane anisotropy properties of thin, molecular beam epitaxy-grown NiMnSb films as a function of their Mn concentration. Using ferromagnetic resonance to determine the uniaxial and four-fold anisotropy fields, (2K{sub U})/(M{sub s}) and (2K{sub 1})/(M{sub s}) , we find that a variation in composition can change the strength of the four-fold anisotropy by more than an order of magnitude and cause a complete 90° rotation of the uniaxial anisotropy. This provides valuablemore » flexibility in designing new device geometries.« less

Epitaxial growth and magnetic properties of Fe4-xMnxN thin films grown on MgO(0 0 1) substrates by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Anzai, Akihito; Takata, Fumiya; Gushi, Toshiki; Toko, Kaoru; Suemasu, Takashi

2018-05-01

Epitaxial Fe4-xMnxN (x = 0, 1, 2, 3, and 4) thin films were successfully grown on MgO(0 0 1) single-crystal substrates by molecular beam epitaxy, and their crystalline qualities and magnetic properties were investigated. It was found that the lattice constants of Fe4-xMnxN obtained from X-ray diffraction measurement increased with the Mn content. The ratio of the perpendicular lattice constant c to the in-plane lattice constant a of Fe4-xMnxN was found to be about 0.99 at x ⩾ 2. The magnetic properties evaluated using a vibrating sample magnetometer at room temperature revealed that all of the Fe4-xMnxN films exhibited ferromagnetic behavior regardless of the value of x. In addition, the saturation magnetization decreased non-linearly as the Mn content increased. Finally, FeMn3N and Mn4N exhibited perpendicular anisotropy and their uniaxial magnetic anisotropy energies were 2.2 × 105 and 7.5 × 105 erg/cm3, respectively.

Effect of pre-straining on the evolution of material anisotropy in rolled magnesium alloy AZ31 sheet

NASA Astrophysics Data System (ADS)

Qiao, H.; Guo, X. Q.; Wu, P. D.

2013-12-01

The large strain Elastic Visco-Plastic Self-Consistent (EVPSC) model and the recently developed Twinning and De-Twinning (TDT) model are applied to study the mechanical behavior of rolled magnesium alloy AZ31 sheet. Three different specimen orientations with tilt angles of 0°, 45° and 90° between the rolling direction and longitudinal specimen axis are used to study the mechanical anisotropy under both uniaxial tension and compression. The effect of pre-strain in uniaxial compression along the rolling direction on subsequent uniaxial tension/compression along the three directions is also investigated. It is demonstrated that the twinning during pre-strain in compression and the detwinning in the subsequent deformation have a significant influence on the mechanical anisotropy. Numerical results are in good agreement with the experimental observations found in the literature.

Magnetic characteristics and nanostructures of FePt granular films with GeO2 segregant

NASA Astrophysics Data System (ADS)

Ono, Takuya; Moriya, Tomohiro; Hatayama, Masatoshi; Tsumura, Kaoru; Kikuchi, Nobuaki; Okamoto, Satoshi; Kitakami, Osamu; Shimatsu, Takehito

2017-01-01

To realize a granular film composed of L10-FePt grains with high uniaxial magnetic anisotropy energy, Ku, and segregants for energy-assisted magnetic recording, a FePt-GeO2/FePt-C stacked film was investigated in the engineering process. The FePt-GeO2/FePt-C stacked film fabricated at a substrate temperature of 450 °C realized uniaxial magnetic anisotropy, Kugrain , of about 2.5 × 107 erg/cm3, which is normalized by the volume fraction of FePt grains, and a granular structure with an averaged grain size of 7.7 nm. As the thickness of the FePt-GeO2 upper layer was increased to 9 nm, the Ku values were almost constant. That result differs absolutely from the thickness dependences of the other oxide segregant materials such as SiO2 and TiO2. Such differences on the oxide segregant are attributed to their chemical bond. The strong covalent bond of GeO2 is expected to result in high Ku of the FePt-GeO2/FePt-C stacked films.

Effect of the strong coupling on the exchange bias field in IrMn/Py/Ru/Co spin valves

NASA Astrophysics Data System (ADS)

Tarazona, H. S.; Alayo, W.; Landauro, C. V.; Quispe-Marcatoma, J.

2018-01-01

The IrMn/Py/Ru/Co (Py = Ni81Fe19) spin valves have been produced by sputtering deposition and analyzed by magnetization measurements and a theoretical modelling of their exchange interactions, based on the macro-spin model. The Ru thickness was grown between 6 and 22 Å, which is small enough to promote strong indirect coupling between Py and Co. Results of measurements showed a large and gradual change in the shape of hysteresis loops when the Ru thickness was varied. The theoretical analysis, using numerical calculations based on the gradient conjugate method, provides the exchange coupling constants (bilinear and biquadratic), the exchange anisotropy fields and the magnetic anisotropy fields (uniaxial and rotatable). The exchange bias fields of spin valves were compared to that of a IrMn/Py bilayer. We found that the difference between these fields oscillates with Ru thickness in the same manner as the bilinear coupling constants.

Magnetoresistive sensitivity and uniaxial anisotropy of spin-valve microstrips with a synthetic antiferromagnet

NASA Astrophysics Data System (ADS)

Chernyshova, T. A.; Milyaev, M. A.; Naumova, L. I.; Proglyado, V. V.; Bannikova, N. S.; Maksimova, I. K.; Petrov, I. A.; Ustinov, V. V.

2017-05-01

Microobjects (strips) were formed by contact photolithography using Ta/Ni80Fe20/Co90Fe10/Cu/Co90Fe10/Ru/Co90Fe10/Fe50Mn50/Ta spin-valves prepared by magnetron sputtering. A mutually perpendicular arrangement of uniaxial and unidirectional anisotropy axes in microobjects has been formed using two different thermomagnetic treatment regimes. The magnetoresistive sensitivity of spin valve and spin-valve-based microobject has been found to depend on the mutual arrangement of the easy magnetization axis and direction of magnetic field applied upon thermomagnetic treatment. The obtained data have been interpreted taking into account changes in the induced anisotropy and anisotropy due to the shape of the microobject.

Piezostrain tuning exchange bias mediated by electric field in composite heterostructure

NASA Astrophysics Data System (ADS)

Li, Pingping; Zhou, Cai; Wang, Wenqiang; Cao, Cuimei; Yao, Jinli; Jiang, Changjun

2017-12-01

The change of unidirectional anisotropy and uniaxial anisotropy field turned by piezostrain in an IrMn/Co/Ta/Pb(Mg1/3Nb2/3)O3-PbTiO3 heterostructure with an exchange bias was investigated by ferromagnetic resonance at room temperature. The curve of the magnetic resonance field versus the electric fields showed an asymmetric butterfly-like behavior, which was consistent with the result of strain versus electric field curves. This butterfly-like behavior can be attributed to the piezostrain effect. Specifically, the non-volatile uniaxial anisotropy field and unidirectional anisotropy field behavior under different electric fields induced by piezostrain effect were obtained. Our result is crucial for further application of future multiferroic devices.

Origin of magnetic anisotropy in doped Ce 2 Co 17 alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ke, Liqin; Kukusta, D. A.; Johnson, Duane D.

2016-10-21

Magnetocrystalline anisotropy (MCA) in doped Ce 2Co 17 and other competing structures was investigated using density functional theory. We confirmed that the MCA contribution from dumbbell Co sites is very negative. Replacing Co dumbbell atoms with a pair of Fe or Mn atoms greatly enhance the uniaxial anisotropy, which agrees quantitatively with experiment, and this enhancement arises from electronic-structure features near the Fermi level, mostly associated with dumbbell sites. With Co dumbbell atoms replaced by other elements, the variation of anisotropy is generally a collective effect and contributions from other sublattices may change significantly. Furthermore, we found that Zr dopingmore » promotes the formation of 1-5 structure that exhibits a large uniaxial anisotropy, such that Zr is the most effective element to enhance MCA in this system.« less

Longitudinal Relaxation of Ferromagnetic Grains

NASA Astrophysics Data System (ADS)

Würger, Alois

1998-07-01

We study the activated longitudinal dynamics of a small single-domain magnet with uniaxial anisotropy, coupled to quantum noise. The smallest finite eigenvalue λ1 = γ0e-EB/kBT of the relaxation matrix is evaluated in a controlled approximation. For white noise we find γ0~T-1 at moderate temperatures and γ0 = const at very low T. Coupling to elastic waves leads to a prefactor that is linear in T or constant, depending on temperature. At very low T, the discreteness of the energy spectrum is crucial.

Giant perpendicular exchange bias with antiferromagnetic MnN

NASA Astrophysics Data System (ADS)

Zilske, P.; Graulich, D.; Dunz, M.; Meinert, M.

2017-05-01

We investigated an out-of-plane exchange bias system that is based on the antiferromagnet MnN. Polycrystalline, highly textured film stacks of Ta/MnN/CoFeB/MgO/Ta were grown on SiOx by (reactive) magnetron sputtering and studied by x-ray diffraction and Kerr magnetometry. Nontrivial modifications of the exchange bias and the perpendicular magnetic anisotropy were observed as functions of both film thicknesses and field cooling temperatures. In optimized film stacks, a giant perpendicular exchange bias of 3600 Oe and a coercive field of 350 Oe were observed at room temperature. The effective interfacial exchange energy is estimated to be Jeff = 0.24 mJ/m2 and the effective uniaxial anisotropy constant of the antiferromagnet is Keff = 24 kJ/m3. The maximum effective perpendicular anisotropy field of the CoFeB layer is Hani = 3400 Oe. These values are larger than any previously reported values. These results possibly open a route to magnetically stable, exchange biased perpendicularly magnetized spin valves.

Field dependent magnetic anisotropy of Ga0.2Fe0.8 thin films

NASA Astrophysics Data System (ADS)

Resnick, Damon A.; McClure, A.; Kuster, C. M.; Rugheimer, P.; Idzerda, Y. U.

2011-04-01

Using longitudinal MOKE in combination with a variable strength rotating magnetic field, called the rotational MOKE (ROTMOKE) method, we show that the magnetic anisotropy for a Ga0.2Fe0.8 single crystal film with a thickness of 17 nm, grown on GaAs (001) with a thick ZnSe buffer layer, depends linearly on the strength of the applied magnetic field. The torque moment curves generated using ROTMOKE are well fit with a model that accounts for the uniaxial, cubic, or fourfold anisotropy, as well as additional terms with a linear dependence on the applied magnetic field. The uniaxial and cubic anisotropy fields, taken from both the hard and the easy axis scans, are seen to remain field independent. The field dependent terms are evidence of a large affect of the magnetostriction and its contribution to the effective magnetic anisotropy in GaxFe1-x thin films.

Electric-field-driven magnetization reversal in square-shaped nanomagnet-based multiferroic heterostructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peng, Ren-Ci; Nan, Ce-Wen, E-mail: jzw12@psu.edu, E-mail: cwnan@tsinghua.edu.cn; Wang, J. J., E-mail: jzw12@psu.edu, E-mail: cwnan@tsinghua.edu.cn

Based on phase field modeling and thermodynamic analysis, purely electric-field-driven magnetization reversal was shown to be possible in a multiferroic heterostructure of a square-shaped amorphous Co{sub 40}Fe{sub 40}B{sub 20} nanomagnet on top of a ferroelectric layer through electrostrain. The reversal is made possible by engineering the mutual interactions among the built-in uniaxial magnetic anisotropy, the geometry-dependent magnetic configuration anisotropy, and the magnetoelastic anisotropy. Particularly, the incorporation of the built-in uniaxial anisotropy made it possible to reverse magnetization with one single unipolar electrostrain pulse, which is simpler than previous designs involving the use of bipolar electrostrains and may alleviate ferroelectric fatigue.more » Critical conditions for triggering the magnetization reversal are identified.« less

Self-assembly of heterogeneous supramolecular structures with uniaxial anisotropy.

PubMed

Ruiz-Osés, M; Gonzalez-Lakunza, N; Silanes, I; Gourdon, A; Arnau, A; Ortega, J E

2006-12-28

Uniaxial anisotropy in two-dimensional self-assembled supramolecular structures is achieved by the coadsorption of two different linear molecules with complementary amine and imide functionalization. The two-dimensional monolayer is defined by a one-dimensional stack of binary chains, which can be forced to line up along steps in vicinal surfaces. The competing driving forces in the self-organization process are discussed in light of the structures observed during single molecule adsorption and coadsorption on flat and vicinal surfaces and the corresponding theoretical calculations.

Strain-Induced Anisotropic Fermi Contour of 2D Holes and Composite Fermions

NASA Astrophysics Data System (ADS)

Jo, Insun; Rosales, K. A. V.; Mueed, M. A.; Padmanabhan, M.; Pfeiffer, L. N.; West, K. W.; Baldwin, K. W.; Winkler, R.; Shayegan, M.

We present experimental and theoretical results demonstrating strain-induced Fermi contour anisotropy of two-dimensional (2D) holes and composite fermions (CFs) confined to a (001) GaAs quantum well. We apply a tunable uniaxial strain to a thinned (001) GaAs wafer, glued to a piezoelectric actuator. When the 2D holes are subjected to an in-plane uniaxial strain, their band structure and Fermi contour become anisotropic by about 30% even for a minute amount of strain, on the order of 10-4. Via measurements of commensurability oscillations, we determine the Fermi contour anisotropy for holes near zero magnetic field, and for CFs at high magnetic fields, as a function of uniaxial strain. The measured Fermi contour anisotropy of holes is consistent with the calculation results. The observed CF Fermi contour anisotropy also shows a strong dependence on the applied strain, which we compare quantitatively to that of the low-field holes. Supported by the NSF(Grants DMR-1305691, ECCS-1508925, and MRSEC DMR-1420541), the DOE Basic Energy Sciences (DE-FG02-00-ER45841), the Gordon and Betty Moore Foundation (GBMF4420), and the Keck Foundation. R. W. is supported by the NSF (DMR-1310199).

Precessional Switching of Thin Nanomagnets with Uniaxial Anisotropy

NASA Astrophysics Data System (ADS)

Devolder, Thibaut; Schumacher, Hans Werner; Chappert, Claude

This review describes the evolution of the magnetization of uniaxial thin magnets when subjected to fast-rising magnetic-field pulses. We report detailed "all-electrical" experimental investigations of precessional switching on soft uniaxial micrometer-sized thin magnets, and we discuss them using a comprehensive, mostly analytical framework. General criteria are derived for the analytical assessment of the switching ability of any arbitrary set of experimental parameters. For this, we start from the Landau-Lifshitz equation and first consider the precessional switching in a much idealized macrospin, easy-plane loss-free system. We then test the main outputs of this model with time-resolved experiments on advanced Magnetic Random Access Memories (MRAM) cells. Using applied fields above the anisotropy field H k , we prove the quasiperiodic nature of the magnetization trajectory and we demonstrate experimental conditions ensuring a sub-200 ps ballistic magnetization reversal. We then upgrade our model accuracy by taking into account the uniaxial anisotropy and the behavior in hard-axis fields of the order of H k . We derive a simple though reliable estimate of the switching speed; its limiting factors highlight the experimental poor switching reproducibility when close to the minimal hard-axis reversal field H k /2. The latter field does not correspond to the minimal energy cost of the reversal, whose prospective evolution in the future generations of MRAM is predicted. Small departures from the macrospin state are discussed. The effect of damping is modeled using perturbation theory. Finite damping alters the precessional motion periodicity and puts some constraints on the field rise time. A special focus is dedicated to the relaxation-dominated precessional switching: the minimal hard-axis field triggering the switching is shown to be above H k /2 by an extra field cost linked to the damping constant times the square root of M S H k . Finally, the selective addressing and the direct-write of a magnetic cell with combined easy-axis and hard-axis fields are studied. We introduce the concept of bounce and revisit the dynamical astroid to derive the related characteristic reversal durations and their margins. We propose a field timing that is immune to the delay jitter between the combined addressing fields. We finish by investigating briefly the challenges and the promises of the "precessional" strategy for future MRAM generations.

Measurement of electron paramagnetic resonance using terahertz time-domain spectroscopy.

PubMed

Kozuki, Kohei; Nagashima, Takeshi; Hangyo, Masanori

2011-12-05

We present a frequency-domain electron spin resonance (ESR) measurement system using terahertz time-domain spectroscopy. A crossed polarizer technique is utilized to increase the sensitivity in detecting weak ESR signals of paramagnets caused by magnetic dipole transitions between magnetic sublevels. We demonstrate the measurements of ESR signal of paramagnetic copper(II) sulfate pentahydrate with uniaxial anisotropy of the g-factor under magnetic fields up to 10 T. The lineshape of the obtained ESR signals agrees well with the theoretical predictions for a powder sample with the uniaxial anisotropy.

Antiferromagnetic layer thickness dependence of noncollinear uniaxial and unidirectional anisotropies in NiFe/FeMn/CoFe trilayers

NASA Astrophysics Data System (ADS)

Choi, Hyeok-Cheol; You, Chun-Yeol; Kim, Ki-Yeon; Lee, Jeong-Soo; Shim, Je-Ho; Kim, Dong-Hyun

2010-06-01

We have investigated the dependence of magnetic anisotropies of the exchange-biased NiFe/FeMn/CoFe trilayers on the antiferromagnetic (AF) layer thickness (tAF) by measuring in-plane angular-dependent ferromagnetic resonance fields. The resonance fields of NiFe and CoFe sublayers are shifted to lower and higher values compared to those of single unbiased ferromagnetic (F) layers, respectively, due to the interfacial exchange coupling when tAF≥2nm . In-plane angular dependence of resonance field reveals that uniaxial and unidirectional anisotropies coexist in the film plane, however, they are not collinear with each other. It is found that these peculiar noncollinear anisotropies significantly depend on tAF . The angle of misalignment displays a maximum around tAF=5nm and converges to zero when tAF is thicker than 10 nm. Contributions from thickness-dependent AF anisotropy and spin frustrations at both F/AF interfaces due to the structural imperfections should be accounted in order to understand the AF-layer thickness dependence of noncollinear magnetic anisotropies.

On the limits of uniaxial magnetic anisotropy tuning by a ripple surface pattern

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arranz, Miguel A.; Colino, Jose M., E-mail: josemiguel.colino@uclm.es; Palomares, Francisco J.

Ion beam patterning of a nanoscale ripple surface has emerged as a versatile method of imprinting uniaxial magnetic anisotropy (UMA) on a desired in-plane direction in magnetic films. In the case of ripple patterned thick films, dipolar interactions around the top and/or bottom interfaces are generally assumed to drive this effect following Schlömann's calculations for demagnetizing fields of an ideally sinusoidal surface [E. Schlömann, J. Appl. Phys. 41, 1617 (1970)]. We have explored the validity of his predictions and the limits of ion beam sputtering to induce UMA in a ferromagnetic system where other relevant sources of magnetic anisotropy aremore » neglected: ripple films not displaying any evidence of volume uniaxial anisotropy and where magnetocrystalline contributions average out in a fine grain polycrystal structure. To this purpose, the surface of 100 nm cobalt films grown on flat substrates has been irradiated at fixed ion energy, fixed ion fluency but different ion densities to make the ripple pattern at the top surface with wavelength Λ and selected, large amplitudes (ω) up to 20 nm so that stray dipolar fields are enhanced, while the residual film thickness t = 35–50 nm is sufficiently large to preserve the continuous morphology in most cases. The film-substrate interface has been studied with X-ray photoemission spectroscopy depth profiles and is found that there is a graded silicon-rich cobalt silicide, presumably formed during the film growth. This graded interface is of uncertain small thickness but the range of compositions clearly makes it a magnetically dead layer. On the other hand, the ripple surface rules both the magnetic coercivity and the uniaxial anisotropy as these are found to correlate with the pattern dimensions. Remarkably, the saturation fields in the hard axis of uniaxial continuous films are measured up to values as high as 0.80 kG and obey a linear dependence on the parameter ω{sup 2}/Λ/t in quantitative agreement with Schlömann's prediction for a surface anisotropy entirely ruled by dipolar interaction. The limits of UMA tuning by a ripple pattern are discussed in terms of the surface local angle with respect to the mean surface and of the onset of ripple detachment.« less

Magnetic properties of epitaxial bismuth ferrite-garnet mono- and bilayers

NASA Astrophysics Data System (ADS)

Semuk, E. Yu.; Berzhansky, V. N.; Prokopov, A. R.; Shaposhnikov, A. N.; Karavainikov, A. V.; Salyuk, O. Yu.; Golub, V. O.

2015-11-01

Magnetic properties of Bi1.5Gd1.5Fe4.5Al0.5O12 (84 nm) and Bi2.8Y0.2Fe5O12 (180 nm) films epitaxially grown on gallium-gadolinium garnet (GGG) single crystal (111) substrate as well as Bi1.5Gd1.5Fe4.5Al0.5O12/Bi2.8Y0.2Fe5O12 bilayer were investigated using ferromagnetic resonance technique. The mismatch of the lattice parameters of substrate and magnetic layers leads to formation of adaptive layers which affect on the high order anisotropy constant of the films but practically do not affect on uniaxial perpendicular magnetic anisotropy The magnetic properties of the bilayer film were explained in supposition of strong exchange coupling between magnetic layers taking into account film-film and film-substrate elastic interaction.

Visualization of Dynamic Vortex Structures in Magnetic Films with Uniaxial Anisotropy (Micromagnetic Simulation)

NASA Astrophysics Data System (ADS)

Zverev, V. V.; Izmozherov, I. M.; Filippov, B. N.

2018-02-01

Three-dimensional computer simulation of dynamic processes in a moving domain boundary separating domains in a soft magnetic uniaxial film with planar anisotropy is performed by numerical solution of Landau-Lifshitz-Gilbert equations. The developed visualization methods are used to establish the connection between the motion of surface vortices and antivortices, singular (Bloch) points, and core lines of intrafilm vortex structures. A relation between the character of magnetization dynamics and the film thickness is found. The analytical models of spatial vortex structures for imitation of topological properties of the structures observed in micromagnetic simulation are constructed.

A phenomenological approach to study the effect of uniaxial anisotropy on the magnetization of ferromagnetic nanoparticles

NASA Astrophysics Data System (ADS)

Sánchez-Marín, N.; Cuchillo, A.; Knobel, M.; Vargas, P.

2018-04-01

We study the effect of the uniaxial anisotropy in a system of ideal, noninteracting ferromagnetic nanoparticles by means of a thermodynamical model. We show that the effect of the anisotropy can be easily assimilated in a temperature shift Ta∗, in analogy to what was proposed by Allia et al. (2001) in the case of interacting nanomagnets. The phenomenological anisotropic Ta∗ parameter can be negative, indicating an antiferromagnetic-like behavior, or positive, indicating a ferromagnetic-like character as seen in the inverse susceptibility behavior as a function of temperature. The study is done considering an easy axis distribution to take into account the anisotropy axis dispersion in real samples (texture). In the case of a volumetric uniform distribution of anisotropy axes, the net effect makes Ta∗ to vanish, and the magnetic susceptibility behaves like a conventional superparamagnetic system, whereas in the others a finite value is obtained for Ta∗ . When magnetic moment distribution is considered, the effect is to enhance the Ta∗ parameter, when the dispersion of the magnetic moments becomes wider.

Comment on 'Detecting uniaxial single domain grains with a modified IRM technique' by R. Mitra, L. Tauxe and J. S. Gee

NASA Astrophysics Data System (ADS)

Fabian, K.

2012-10-01

In a recent article, Mitra et al. (2011) propose a modified IRM technique to identify the symmetry of magnetic anisotropy in single domain particle ensembles. They apply this technique to support an earlier suggestion that single domain grains in young mid-ocean ridge basalts (MORB) exhibit multiaxial anisotropy. Here it is shown that the design of their measurement is flawed, in that they do not take into account that the outcome essentially depends on the initial demagnetization state of the sample before the experiment, and on the coercivity distribution of the sample. Because all MORB specimens measured by Mitra et al. (2011) carried their original NRM, which closely resembles a thermally demagnetized state, their measurements first of all reflect the coercivity distributions and domain states of the samples, and contain little or no information about the symmetry of the magnetic anisotropy. All arguments previously put forward in favour of a dominant uniaxial anisotropy in MORB are therefore still valid.

Vectorial magnetometry with the magneto-optic Kerr effect applied to Co/Cu/Co trilayer structures

NASA Astrophysics Data System (ADS)

Daboo, C.; Bland, J. A. C.; Hicken, R. J.; Ives, A. J. R.; Baird, M. J.; Walker, M. J.

1993-05-01

We describe an arrangement in which the magnetization components parallel and perpendicular to the applied field are both determined from longitudinal magneto-optic Kerr effect measurements. This arrangement differs from the usual procedures in that the same optical geometry is used but the magnet geometry altered. This leads to two magneto-optic signals which are directly comparable in magnitude thereby giving the in-plane magnetization vector directly. We show that it is of great value to study both in-plane magnetization vector components when studying coupled structures where significant anisotropies are also present. We discuss simulations which show that it is possible to accurately determine the coupling strength in such structures by examining the behavior of the component of magnetization perpendicular to the applied field in the vicinity of the hard in-plane anisotropy axis. We illustrate this technique by examining the magnetization and magnetic anisotropy behavior of ultrathin Co/Cu(111)/Co (dCu=20 Å and 27 Å) trilayer structures prepared by molecular beam epitaxy, in which coherent rotation of the magnetization vector is observed when the magnetic field B is applied along the hard in-plane anisotropy axis, with the magnitude of the magnetization vector constant and close to its bulk value. Results of micromagnetic calculations closely reproduce the observed parallel and perpendicular magnetization loops, and yield strong uniaxial magnetic anisotropies in both layers, while the interlayer coupling appears to be absent or negligible in comparison with the anisotropy strengths.

Magnetic small-angle neutron scattering of bulk ferromagnets.

PubMed

Michels, Andreas

2014-09-24

We summarize recent theoretical and experimental work in the field of magnetic small-angle neutron scattering (SANS) of bulk ferromagnets. The response of the magnetization to spatially inhomogeneous magnetic anisotropy and magnetostatic stray fields is computed using linearized micromagnetic theory, and the ensuing spin-misalignment SANS is deduced. Analysis of experimental magnetic-field-dependent SANS data of various nanocrystalline ferromagnets corroborates the usefulness of the approach, which provides important quantitative information on the magnetic-interaction parameters such as the exchange-stiffness constant, the mean magnetic anisotropy field, and the mean magnetostatic field due to jumps ΔM of the magnetization at internal interfaces. Besides the value of the applied magnetic field, it turns out to be the ratio of the magnetic anisotropy field Hp to ΔM, which determines the properties of the magnetic SANS cross-section of bulk ferromagnets; specifically, the angular anisotropy on a two-dimensional detector, the asymptotic power-law exponent, and the characteristic decay length of spin-misalignment fluctuations. For the two most often employed scattering geometries where the externally applied magnetic field H0 is either perpendicular or parallel to the wave vector k0 of the incoming neutron beam, we provide a compilation of the various unpolarized, half-polarized (SANSPOL), and uniaxial fully-polarized (POLARIS) SANS cross-sections of magnetic materials.

Complex degree of mutual anisotropy in diagnostics of biological tissues physiological changes

NASA Astrophysics Data System (ADS)

Ushenko, Yu. A.; Dubolazov, O. V.; Karachevtcev, A. O.; Zabolotna, N. I.

2011-05-01

To characterize the degree of consistency of parameters of the optically uniaxial birefringent protein nets of blood plasma a new parameter - complex degree of mutual anisotropy is suggested. The technique of polarization measuring the coordinate distributions of the complex degree of mutual anisotropy of blood plasma is developed. It is shown that statistic approach to the analysis of complex degree of mutual anisotropy distributions of blood plasma is effective in the diagnosis and differentiation of acute inflammation - acute and gangrenous appendicitis.

Complex degree of mutual anisotropy in diagnostics of biological tissues physiological changes

NASA Astrophysics Data System (ADS)

Ushenko, Yu. A.; Dubolazov, A. V.; Karachevtcev, A. O.; Zabolotna, N. I.

2011-09-01

To characterize the degree of consistency of parameters of the optically uniaxial birefringent protein nets of blood plasma a new parameter - complex degree of mutual anisotropy is suggested. The technique of polarization measuring the coordinate distributions of the complex degree of mutual anisotropy of blood plasma is developed. It is shown that statistic approach to the analysis of complex degree of mutual anisotropy distributions of blood plasma is effective in the diagnosis and differentiation of acute inflammation - acute and gangrenous appendicitis.

Elastic properties of uniaxial-fiber reinforced composites - General features

NASA Astrophysics Data System (ADS)

Datta, Subhendu; Ledbetter, Hassel; Lei, Ming

The salient features of the elastic properties of uniaxial-fiber-reinforced composites are examined by considering the complete set of elastic constants of composites comprising isotropic uniaxial fibers in an isotropic matrix. Such materials exhibit transverse-isotropic symmetry and five independent elastic constants in Voigt notation: C(11), C(33), C(44), C(66), and C(13). These C(ij) constants are calculated over the entire fiber-volume-fraction range 0.0-1.0, using a scattered-plane-wave ensemple-average model. Some practical elastic constants such as the principal Young moduli and the principal Poisson ratios are considered, and the behavior of these constants is discussed. Also presented are the results for the four principal sound velocities used to study uniaxial-fiber-reinforced composites: v(11), v(33), v(12), and v(13).

Influence of dipolar interactions on the superparamagnetic relaxation time of γ-Fe2O3

NASA Astrophysics Data System (ADS)

Labzour, A.; Housni, A.; Limame, K.; Essahlaoui, A.; Sayouri, S.

2017-03-01

Influence of dipolar interactions on the Néel superparamagnetic relaxation time, τ , of an assembly of ultrafine ferromagnetic particles (γ-Fe2O3 ) with uniaxial anisotropy and of different sizes has been widely studied using Mössbauer technique. These studies, based on different analytical approaches, have shown that τ decreases with increasing interactions between particles. To interpret these results, we propose a model where interaction effects are considered as being due to a constant and external randomly oriented magnetic field B(Ψ, ϕ). The model is based on the resolution of the Fokker-Planck equation (FPE), generalizes previous calculations and gives satisfactory interpretation of the relaxation phenomenon in such systems.

A general perspective on the magnetization reversal in cylindrical soft magnetic nanowires with dominant shape anisotropy

NASA Astrophysics Data System (ADS)

Kuncser, A.; Antohe, S.; Kuncser, V.

2017-02-01

Peculiarities of the magnetization reversal process in cylindrical Ni-Cu soft magnetic nanowires with dominant shape anisotropy are analyzed via both static and time dependent micromagnetic simulations. A reversible process involving a coherent-like spin rotation is always observed for magnetic fields applied perpendicularly to the easy axis whereas nucleation of domain walls is introduced for fields applied along the easy axis. Simple criteria for making distinction between a Stoner-Wohlfarth type rotation and a nucleation mechanism in systems with uniaxial magnetic anisotropy are discussed. Superposed reversal mechanisms can be in action for magnetic fields applied at arbitrary angles with respect to the easy axis within the condition of an enough strong axial component required by the nucleation. The dynamics of the domain wall, involving two different stages (nucleation and propagation), is discussed with respect to initial computing conditions and orientations of the magnetic field. A nucleation time of about 3 ns and corkscrew domain walls propagating with a constant velocity of about 150 m/s are obtained in case of Ni-Cu alloy (Ni rich side) NWs with diameters of 40 nm and high aspect ratio.

Electronic and optical properties of GaN/AlN quantum dots on Si(111) subject to in-plane uniaxial stresses and variable excitation

NASA Astrophysics Data System (ADS)

Moshe, O.; Rich, D. H.; Birner, S.; Povolotskyi, M.; Damilano, B.; Massies, J.

2010-10-01

We have studied the excitation- and polarization-dependent optical properties of GaN/AlN self-assembled quantum dots (QDs) grown on Si(111) substrates. Ensembles of QDs were subject to various external stress configurations that resulted from the thermal expansion coefficient mismatch between the GaN/AlN layers and the Si(111) substrate and ranged from in-plane uniaxial stress, primarily along the ⟨112¯0⟩ directions, to in-plane biaxial stress, having magnitudes ranging from 20-30 kbar. Limited regions of uniaxial stress were obtained by exploiting naturally occurring microcracks that form during the postgrowth cooling. These microcracks act as stressors in order to create the highly localized regions of uniaxial stress. The local strain tensors for such QDs, which are subject to an interfacial stress perturbation, have been determined by modeling the dependence of the QD excitonic transition energy on the interfacial stress. Cathodoluminescence (CL) measurements of the excitonic transitions exhibit an in-plane linear polarization anisotropy in close proximity to microcracks. The polarization anisotropy is strongly dependent on the sample temperature and the electron beam excitation conditions used to excite the QD ensemble. Localized CL spectroscopy of the QDs exhibits emissions from both the ground and excited states, whose relative contributions depend on the level of excitation and temperature. Experimental results indicate that the polarization anisotropy vanishes at high temperatures (˜300 K) with an increasing excitation of the QDs, while the anisotropy decreases more slowly with excitation at low temperatures (˜60 K). A theoretical modeling of the effect of carrier filling on the polarization anisotropy and the excitonic transition energy was performed, as based on three-dimensional self-consistent solutions of the Schrödinger and Poisson equations using the 6×6 kṡp and effective mass methods for calculations of the e-h wave functions and electron and hole quasi-Fermi levels for varying levels of state filling. We attribute carrier filling and a thermal excitation of holes into higher energy QD hole states during excitation to account for the observed gradual decrease in the polarization anisotropy with an increasing electron-hole pair excitation density at T =300 K.

Skyrmion robustness in noncentrosymmetric magnets with axial symmetry: The role of anisotropy and tilted magnetic fields

NASA Astrophysics Data System (ADS)

Leonov, A. O.; Kézsmárki, I.

2017-12-01

We investigate the stability of Néel skyrmions against tilted magnetic fields in polar magnets with uniaxial anisotropy ranging from easy-plane to easy-axis type. We construct the corresponding phase diagrams and investigate the internal structure of skewed skyrmions with displaced cores. We find that moderate easy-plane anisotropy increases the stability range of Néel skyrmions for fields along the symmetry axis, while moderate easy-axis anisotropy enhances their robustness against tilted magnetic fields. We stress that the direction along which the skyrmion cores are shifted depends on the symmetry of the underlying crystal lattice. The cores of Néel skyrmions, realized in polar magnets with Cn v symmetry, are displaced either along or opposite to the off-axis (in-plane) component of the magnetic field depending on the rotation sense of the magnetization, dictated by the sign of the Dzyaloshinskii constant. The core shift of antiskyrmions, present in noncentrosymmetric magnets with D2 d symmetry, depends on the in-plane orientation of the magnetic field and can be parallel, antiparallel, or perpendicular to it. We argue that the role of anisotropy in magnets with axially symmetric crystal structure is different from that in cubic helimagnets. Our results can be applied to address recent experiments on polar magnets with C3 v symmetry, GaV4S8 and GaV4Se8 , and Mn1.4Pt0.9Pd0.1Sn with D2 d symmetry.

Negative refraction in molybdenum disulfide.

PubMed

Wang, Wenhui; Cui, Xudong; Yang, Erchan; Fan, Quanping; Xiang, Bin

2015-08-24

Recently, negative refractions have been demonstrated in uniaxial crystals with no necessary of negative permittivity and permeability. However, the small anisotropy parameterγin the uniaxial crystals limits the negative refraction occurrence only in a small range of the incident light angle, retarding its practical applications. In this paper, we report negative refraction induced by a pronounced anisotropic behavior in the bulk MoS(2). Using the first-principles, the dielectric function and refractive index calculations confirm a uniaxial trait of MoS(2) with a calculated anisotropy parameterγlarger than 2.5 in the entire range of visible wavelength. The critical incident angle to trigger a negative refraction in the bulk MoS(2) is calculated up to 90°. The finite-difference time-domain simulations prove that the incident light with a density of 59.5% can be negatively refracted in a MoS(2) slab with a thickness of 0.1 µm. Our results open up a new pathway for MoS(2)-like materials to a novel field of optical integration.

Nonlinear modeling of crystal system transition of black phosphorus using continuum-DFT model.

PubMed

Setoodeh, A R; Farahmand, H

2018-01-24

In this paper, the nonlinear behavior of black phosphorus crystals is investigated in tandem with dispersion-corrected density functional theory (DFT-D) analysis under uniaxial loadings. From the identified anisotropic behavior of black phosphorus due to its morphological anisotropy, a hyperelastic anisotropic (HA) model named continuum-DFT is established to predict the nonlinear behavior of the material. In this respect, uniaxial Cauchy stresses are employed on both the DFT-D and HA models along the zig-zag and armchair directions. Simultaneously, the transition of the crystal system is recognized at about 4.5 GPa of the applied uniaxial tensile stress along the zig-zag direction on the DFT-D simulation in the nonlinear region. In order to develop the nonlinear continuum model, unknown constants are surveyed with the optimized least square technique. In this regard, the continuum model is obtained to reproduce the Cauchy stress-stretch and density of strain-stretch results of the DFT-D simulation. Consequently, the modified HA model is introduced to characterize the nonlinear behavior of black phosphorus along the zig-zag direction. More importantly, the specific transition of the crystal system is successfully predicted in the new modified continuum-DFT model. The results reveal that the multiscale continuum-DFT model is well defined to replicate the nonlinear behavior of black phosphorus along the zig-zag and armchair directions.

Compensation for Phase Anisotropy of a Metal Reflector

NASA Technical Reports Server (NTRS)

Hong, John

2007-01-01

A method of compensation for the polarization- dependent phase anisotropy of a metal reflector has been proposed. The essence of the method is to coat the reflector with multiple thin alternating layers of two dielectrics that have different indices of refraction, so as to introduce an opposing polarization-dependent phase anisotropy. The anisotropy in question is a phenomenon that occurs in reflection of light at other than normal incidence: For a given plane wave having components polarized parallel (p) and perpendicular (s) to the plane of incidence, the phase of s-polarized reflected light differs from the phase p-polarized light by an amount that depends on the angle of incidence and the complex index of refraction of the metal. The magnitude of the phase difference is zero at zero angle of incidence (normal incidence) and increases with the angle of incidence. This anisotropy is analogous to a phase anisotropy that occurs in propagation of light through a uniaxial dielectric crystal. In such a case, another uniaxial crystal that has the same orientation but opposite birefringence can be used to cancel the phase anisotropy. Although it would be difficult to prepare a birefringent material in a form suitable for application to the curved surface of a typical metal reflector in an optical instrument, it should be possible to effect the desired cancellation of phase anisotropy by exploiting the form birefringence of multiple thin dielectric layers. (The term "form birefringence" can be defined loosely as birefringence arising, in part, from a regular array of alternating subwavelength regions having different indices of refraction.)

Investigation of the growth of garnet films by liquid phase epitaxy

NASA Technical Reports Server (NTRS)

Moody, J. W.; Shaw, R. W.; Sandfort, R. M.

1974-01-01

Liquid phase expitaxy was investigated to determine its applicability to fabricating magnetic rare earth garnet films for spacecraft data recording systems. Two mixed garnet systems were investigated in detail: (1) Gd-Y and (2) Eu-Yb-Y. All films were deposited on Gd3Ga5012 substrates. The uniaxial anisotropy of the Gd-Y garnets is primarily stress-induced. These garnets are characterized by high-domain wall mobility, low coercivity and modest anisotropy. Characteristic length was found to be relatively sensitive to temperature. The Eu-Yb-Y garnets exhibit acceptable mobilities, good temperature stability and reasonable quality factors. The uniaxial anisotropy of these garnets is primarily growth-induced. The system is well suited for compositional "tailoring" to optimize specific desirable properties. Liquid phase epitaxy can be used to deposit Gd3Ga5012 spacing layers on magnetic garnet films and this arrangement possesses certain advantages over more conventional magnetic filmspacing layer combinations. However, it cannot be used if the magnetic film is to be ion implanted.

Scaling of the Stress and Temperature Dependence of the Optical Anisotropy in Ba(Fe 1-x Co x ) 2As 2

DOE PAGES

Mirri, C.; Dusza, A.; Bastelberger, S.; ...

2016-09-15

We revisit our recent investigations of the optical properties in the underdoped regime of the title compounds with respect to their anisotropic behavior as a function of both temperature and uniaxial stress across the ferro-elastic tetragonal-to-orthorhombic transition. By exploiting a dedicated pressure device, we can tune and control uniaxial stress in situ thus changing the degree of detwinning of the samples in the orthorhombic SDW state as well as pressure-inducing an orthorhombicity in the paramagnetic tetragonal phase. Here we discover a hysteretic behavior of the optical anisotropy; its stress versus temperature dependence across the structural transition bears testimony to themore » analogy with the magnetic-field versus temperature dependence of the magnetization in a ferromagnet when crossing the Curie temperature. In this context, we find furthermore an intriguing scaling of the stress and temperature dependence of the optical anisotropy in Ba(Fe 1-xCo x) 2As 2.« less

Electronic, magnetic, and magnetocrystalline anisotropy properties of light lanthanides

DOE PAGES

Hackett, Timothy A.; Baldwin, D. J.; Paudyal, Durga

2017-05-17

Theoretical understanding of interactions between localized and mobile electrons and the crystal environment in light lanthanides is important because of their key role in much needed magnetic anisotropy in permanent magnet materials that have a great impact in automobile and wind turbine applications. We report electronic, magnetic, and magnetocrystalline properties of these basic light lanthanide elements studied from advanced density functional theory (DFT) calculations. We find that the inclusion of onsite 4f electron correlation and spin orbit coupling within the full-potential band structure is needed to understand the unique magnetocrystalline properties of these light lanthanides. The onsite electron correlation, spinmore » orbit coupling, and full potential for the asphericity of charge densities must be taken into account for the proper treatment of 4f states. We find the variation of total energy as a function of lattice constants that indicate multiple structural phases in Ce contrasting to a single stable structure obtained in other light lanthanides. The 4f orbital magnetic moments are partially quenched as a result of crystalline electric field splitting that leads to magnetocrystalline anisotropy. The charge density plots have similar asphericity and environment in Pr and Nd indicating similar magnetic anisotropy. However, Ce and Sm show completely different asphericity and environment as both orbital moments are significantly quenched. In addition, the Fermi surface structures exemplified in Nd indicate structural stability and unravel a cause of anisotropy. The calculated magnetocrystalline anisotropy energy (MAE) reveals competing c-axis and in-plane anisotropies, and also predicts possibilities of unusual structural deformations in light lanthanides. The uniaxial magnetic anisotropy is obtained in the double hexagonal closed pack structures of the most of the light lanthanides, however, the anisotropy is reduced or turned to planar in the low symmetry structures. As a result, through crystal field calculations we also illustrate the crystal field ground state 4f multiplets of light lanthanides.« less

Electronic, magnetic, and magnetocrystalline anisotropy properties of light lanthanides

NASA Astrophysics Data System (ADS)

Hackett, Timothy A.; Baldwin, D. J.; Paudyal, D.

2017-11-01

Theoretical understanding of interactions between localized and mobile electrons and the crystal environment in light lanthanides is important because of their key role in much needed magnetic anisotropy in permanent magnet materials that have a great impact in automobile and wind turbine applications. We report electronic, magnetic, and magnetocrystalline properties of these basic light lanthanide elements studied from advanced density functional theory (DFT) calculations. We find that the inclusion of onsite 4f electron correlation and spin orbit coupling within the full-potential band structure is needed to understand the unique magnetocrystalline properties of these light lanthanides. The onsite electron correlation, spin orbit coupling, and full potential for the asphericity of charge densities must be taken into account for the proper treatment of 4f states. We find the variation of total energy as a function of lattice constants that indicate multiple structural phases in Ce contrasting to a single stable structure obtained in other light lanthanides. The 4f orbital magnetic moments are partially quenched as a result of crystalline electric field splitting that leads to magnetocrystalline anisotropy. The charge density plots have similar asphericity and environment in Pr and Nd indicating similar magnetic anisotropy. However, Ce and Sm show completely different asphericity and environment as both orbital moments are significantly quenched. In addition, the Fermi surface structures exemplified in Nd indicate structural stability and unravel a cause of anisotropy. The calculated magnetocrystalline anisotropy energy (MAE) reveals competing c-axis and in-plane anisotropies, and also predicts possibilities of unusual structural deformations in light lanthanides. The uniaxial magnetic anisotropy is obtained in the double hexagonal closed pack structures of the most of the light lanthanides, however, the anisotropy is reduced or turned to planar in the low symmetry structures. Through crystal field calculations we also illustrate the crystal field ground state 4f multiplets of light lanthanides.

Electronic, magnetic, and magnetocrystalline anisotropy properties of light lanthanides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hackett, Timothy A.; Baldwin, D. J.; Paudyal, Durga

Theoretical understanding of interactions between localized and mobile electrons and the crystal environment in light lanthanides is important because of their key role in much needed magnetic anisotropy in permanent magnet materials that have a great impact in automobile and wind turbine applications. We report electronic, magnetic, and magnetocrystalline properties of these basic light lanthanide elements studied from advanced density functional theory (DFT) calculations. We find that the inclusion of onsite 4f electron correlation and spin orbit coupling within the full-potential band structure is needed to understand the unique magnetocrystalline properties of these light lanthanides. The onsite electron correlation, spinmore » orbit coupling, and full potential for the asphericity of charge densities must be taken into account for the proper treatment of 4f states. We find the variation of total energy as a function of lattice constants that indicate multiple structural phases in Ce contrasting to a single stable structure obtained in other light lanthanides. The 4f orbital magnetic moments are partially quenched as a result of crystalline electric field splitting that leads to magnetocrystalline anisotropy. The charge density plots have similar asphericity and environment in Pr and Nd indicating similar magnetic anisotropy. However, Ce and Sm show completely different asphericity and environment as both orbital moments are significantly quenched. In addition, the Fermi surface structures exemplified in Nd indicate structural stability and unravel a cause of anisotropy. The calculated magnetocrystalline anisotropy energy (MAE) reveals competing c-axis and in-plane anisotropies, and also predicts possibilities of unusual structural deformations in light lanthanides. The uniaxial magnetic anisotropy is obtained in the double hexagonal closed pack structures of the most of the light lanthanides, however, the anisotropy is reduced or turned to planar in the low symmetry structures. As a result, through crystal field calculations we also illustrate the crystal field ground state 4f multiplets of light lanthanides.« less

Control of magnetic anisotropy in (Ga,Mn)as by lithography-induced strain relaxation.

PubMed

Wenisch, J; Gould, C; Ebel, L; Storz, J; Pappert, K; Schmidt, M J; Kumpf, C; Schmidt, G; Brunner, K; Molenkamp, L W

2007-08-17

We report control of magnetic anisotropy in epitaxial (Ga,Mn)As by anisotropic strain relaxation in patterned structures. The strain in the structures is characterized using reciprocal space mapping by x-ray techniques. The magnetic anisotropy before patterning of the layer, which shows biaxial easy axes along [100] and [010], is replaced by a hard axis in the direction of large elastic strain relaxation and a uniaxial easy axis in the direction where pseudomorphic conditions are retained.

Magnetocrystalline anisotropy in UMn 2 Ge 2 and related Mn-based actinide ferromagnets

DOE PAGES

Parker, David S.; Ghimire, Nirmal; Singleton, John; ...

2015-05-04

We presenmore » t magnetization isotherms in pulsed magnetic fields up to 62 Tesla, supported by first principles calculations, demonstrating a huge uniaxial magnetocrystalline anisotropy energy - approximately 20 MJ/m 3 - in UMn 2 Ge 2 . This large anisotropy results from the extremely strong spin-orbit coupling affecting the uranium 5 f electrons, which in the calculations exhibit a substantial orbital moment exceeding 2 μ B. Finally, we also find from theoretical calculations that a number of isostructural Mn-actinide compounds are expected to have similarly large anisotropy.« less

The degree of mutual anisotropy of biological liquids polycrystalline nets as a parameter in diagnostics and differentiations of hominal inflammatory processes

NASA Astrophysics Data System (ADS)

Angelsky, O. V.; Ushenko, Yu. A.; Balanetska, V. O.

2011-09-01

To characterize the degree of consistency of parameters of the optically uniaxial birefringent protein nets of blood plasma a new parameter - complex degree of mutual anisotropy is suggested. The technique of polarization measuring the coordinate distributions of the complex degree of mutual anisotropy of blood plasma is developed. It is shown that statistic approach to the analysis of the complex degree of mutual anisotropy distributions of blood plasma is effective during the diagnostics and differentiation of an acute inflammatory processes as well as acute and gangrenous appendicitis.

Phase Diagram of a Three-Dimensional Antiferromagnet with Random Magnetic Anisotropy

DOE PAGES

Perez, Felio A.; Borisov, Pavel; Johnson, Trent A.; ...

2015-03-04

Three-dimensional (3D) antiferromagnets with random magnetic anisotropy (RMA) that were experimentally studied to date have competing two-dimensional and three-dimensional exchange interactions which can obscure the authentic effects of RMA. The magnetic phase diagram of Fe xNi 1-xF 2 epitaxial thin films with true random single-ion anisotropy was deduced from magnetometry and neutron scattering measurements and analyzed using mean field theory. Regions with uniaxial, oblique and easy plane anisotropies were identified. A RMA-induced glass region was discovered where a Griffiths-like breakdown of long-range spin order occurs.

Solid-solution stability and preferential site-occupancy in (R-R′){sub 2}Fe{sub 14}B compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Colin, C. V.; Dempsey, N. M.; Univ. Grenoble Alpes, Inst NEEL, F-38000 Grenoble

The rare-earth (R) uniaxial anisotropy of R{sub 2}Fe{sub 14}B compounds with magnetic R atoms (e.g., Nd or Pr) is at the origin of the exceptional hard magnetic properties achieved in magnets based on these compounds. The uniaxial anisotropy found in Ce{sub 2}Fe{sub 14}B is attributed mainly to the magnetism of Fe. Ce is the most abundant R element and there has been much recent effort to fabricate magnets in which Ce is partially substituted for Nd. In the present neutron study of (R{sub 1−x}Ce{sub x}){sub 2}Fe{sub 14}B (R = La or Nd), Ce is found to enter the R{sub 2}Fe{submore » 14}B phase over the entire composition range. The crystallographic parameters decrease with increasing Ce content and the Ce atoms preferentially occupy the smaller 4f sites. It is concluded that Ce in these (RR′){sub 2}Fe{sub 14}B compounds essentially maintains the intermediate valence character found in Ce{sub 2}Fe{sub 14}B. It is proposed that, in this intermediate valence state, Ce weakly contributes to uniaxial anisotropy, thus making a link with the fact that significant coercivity is preserved in Ce-substituted NdFeB magnets.« less

Evidence for Spin Singlet Pairing with Strong Uniaxial Anisotropy in URu2Si2 Using Nuclear Magnetic Resonance

NASA Astrophysics Data System (ADS)

Hattori, T.; Sakai, H.; Tokunaga, Y.; Kambe, S.; Matsuda, T. D.; Haga, Y.

2018-01-01

In order to identify the spin contribution to superconducting pairing compatible with the so-called "hidden order", Si 29 nuclear magnetic resonance measurements have been performed using a high-quality single crystal of URu2 Si2 . A clear reduction of the Si 29 Knight shift in the superconducting state has been observed under a magnetic field applied along the crystalline c axis, corresponding to the magnetic easy axis. These results provide direct evidence for the formation of spin-singlet Cooper pairs. Consequently, results indicating a very tiny change of the in-plane Knight shift reported previously demonstrate extreme uniaxial anisotropy for the spin susceptibility in the hidden order state.

Spin-valve giant magneto-resistance film with magnetostrictive FeSiB amorphous layer and its application to strain sensors

NASA Astrophysics Data System (ADS)

Hashimoto, Y.; Yamamoto, N.; Kato, T.; Oshima, D.; Iwata, S.

2018-03-01

Giant magneto-resistance (GMR) spin-valve films with an FeSiB/CoFeB free layer were fabricated to detect applied strain in a GMR device. The magnetostriction constant of FeSiB was experimentally determined to have 32 ppm, which was one order of magnitude larger than that of CoFeB. In order to detect the strain sensitively and robustly against magnetic field fluctuation, the magnetic field modulation technique was applied to the GMR device. It was confirmed that the output voltage of the GMR device depends on the strain, and the gauge factor K = 46 was obtained by adjusting the applied DC field intensity and direction. We carried out the simulation based on a macro-spin model assuming uniaxial anisotropy, interlayer coupling between the free and pin layers, strain-induced anisotropy, and Zeeman energy, and succeeded in reproducing the experimental results. The simulation predicts that improving the magnetic properties of GMR films, especially reducing interlayer coupling, will be effective for increasing the output, i.e., the gauge factor, of the GMR strain sensors.

Highly anisotropic exchange interactions of j eff = 1 2 iridium moments on the fcc lattice in La 2 B IrO 6   ( B = Mg , Zn )

DOE PAGES

Aczel, A. A.; Cook, A. M.; Williams, T. J.; ...

2016-06-20

Here we have performed inelastic neutron scattering (INS) experiments to investigate the magnetic excitations in the weakly distorted face-centered-cubic (fcc) iridate double perovskites Lamore » $$_2$$ZnIrO$$_6$$ and La$$_2$$MgIrO$$_6$$, which are characterized by A-type antiferromagnetic ground states. The powder inelastic neutron scattering data on these geometrically frustrated $$j_{\\rm eff}=1/2$$ Mott insulators provide clear evidence for gapped spin wave excitations with very weak dispersion. The INS results and thermodynamic data on these materials can be reproduced by conventional Heisenberg-Ising models with significant uniaxial Ising anisotropy and sizeable second-neighbor ferromagnetic interactions. Such a uniaxial Ising exchange interaction is symmetry-forbidden on the ideal fcc lattice, so that it can only arise from the weak crystal distortions away from the ideal fcc limit. This may suggest that even weak distortions in $$j_{\\rm eff}=1/2$$ Mott insulators might lead to strong exchange anisotropies. More tantalizingly, however, we find an alternative viable explanation of the INS results in terms of spin models with a dominant Kitaev interaction. In contrast to the uniaxial Ising exchange, the highly-directional Kitaev interaction is a type of exchange anisotropy which is symmetry-allowed even on the ideal fcc lattice. The Kitaev model has a magnon gap induced by quantum order-by-disorder, while weak anisotropies of the Kitaev couplings generated by the symmetry-lowering due to lattice distortions can pin the order and enhance the magnon gap. In conclusion, our findings highlight how even conventional magnetic orders in heavy transition metal oxides may be driven by highly-directional exchange interactions rooted in strong spin-orbit coupling.« less

Strong anisotropy of electric field effects on uniaxial relaxor ferroelectric Sr0.75Ba0.25Nb2O6 crystals proved by acoustic emission

NASA Astrophysics Data System (ADS)

Dul'kin, E.; Kojima, S.; Roth, M.

2018-01-01

[001] oriented Sr0.75Ba0.25Nb2O6 uniaxial relaxor ferroelectric crystals have been studied by acoustic emission in the temperature range of 20÷200 °C and under an external electric field up to 1 kV/cm. Under the application of an electric field the temperature of a dielectric maximum exhibits a nontrivial behavior: it remains constant at first, secondly steep decreases down to some threshold field, and thirdly starts to increase as a field enhances, whereas the same temperature of a dielectric maximum under a bias electric field to [100] oriented Sr0.75Ba0.25Nb2O6 crystals exhibits a smoothed minimum before the start to increase as a field enhances (E. Dul'kin et al., J. Appl. Phys. 110, 044106 (2011)). Such a difference of electric field effects in c- and a-cut crystals is discussed from the viewpoint of random-bond-random-field model of relaxor ferroelectrics. By the comparison between experimental and theoretical data, a dipole moment of the PNR was estimated to be 0.1 (C cm).

Growth of biaxially textured template layers using ion beam assisted deposition

NASA Astrophysics Data System (ADS)

Park, Seh-Jin

A two-step IBAD (ion beam assisted deposition) method is investigated, and compared to the conventional IBAD methods. The two step method uses surface energy anisotropy to achieve uniaxial texture and ion beam irradiation for biaxial texture. The biaxial texture was achieved by selective surface etching and enhanced by grain overgrowth. In this method, biaxial texture alignment is performed on a (001) uniaxially textured buffer layer. The material selected for achieving uniaxial texture, YBCO (YBa2Cu3O7-x), has strong surface energy anisotropy. YBCO is chemically susceptible to the reaction with the adjacent layer. Yttria stabilized zirconia (YSZ) was used to prevent the reaction between YBCO and the substrates (polycrystalline Ni alloy [Hastelloy] and amorphous SiNx/Si). A SrTiO3 layer was deposited on the uniaxially textured YBCO layer to retard stoichiometry change with subsequent processing. STO is well lattice matched with YBCO. A top layer of Ni was then deposited. The Ni layer was used for studying the effect of grain overgrowth. The obtained uniaxial Ni films were used for subsequent ion beam processing. Ar ion beam irradiation onto the uniaxially textured Ni film was used to study the effect of selective grain etching in achieving in-plane aligned Ni grains. Additional Ni deposition induces the overgrowth of the in-plane aligned Ni grains and, finally, the overall in-plane alignment. The in-plane alignment is examined with XRD phi scan. The effect of surface polarity of insulating oxide substrates on the epitaxial growth behavior was investigated. The lattice strain energy was the most important factor for determining the orientation of Ni films on a non-polar surface. However, for a polar surface, the surface energy plays an important role in determining the final orientation of the Ni films based on the experimental and theoretical results. Y2O3 growth behavior was also studied. The lattice strain energy is the most important factor for Y2O3 growth on single crystalline substrates. The surface energy anisotropy is the most important factor for the growth on amorphous substrates. The XRD phi scan study shows that Ar ion beam irradiation with favorable angle of incidence enhances the in-plane alignment of Y2O3 films grown on randomly oriented substrates due to the ion channeling.

NMR properties of 3He-A in biaxially anisotropic aerogel

NASA Astrophysics Data System (ADS)

Dmitriev, V. V.; Krasnikhin, D. A.; Senin, A. A.; Yudin, A. N.

2012-12-01

Theoretical model of G.E. Volovik for A-like phase of 3He in aerogel suggests formation of Larkin-Imry-Ma state of Anderson-Brinkmann-Morel order parameter. Most of results of NMR studies of A-like phase are in a good agreement with this model in assumption of uniaxial anisotropy, except for some of experiments in weakly anisotropic aerogel samples. We demonstrate that these results can be described in frames of the same model in assumption of biaxial anisotropy. Parameters of anisotropy in these experiments can be determined from the NMR data.

Anisotropy in layered half-metallic Heusler alloy superlattices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Azadani, Javad G.; Munira, Kamaram; Sivakumar, Chockalingam

2016-01-28

We show that when two Heusler alloys are layered in the [001], [110], or [111] directions for various thicknesses to form a superlattice, the Slater-Pauling rule may still be satisfied and the resulting superlattice is often half-metallic with gaps comparable to or larger than those of its constituents. In addition, uniaxial magnetocrystalline anisotropy is induced because of the differences in the electronic structure of the two Heuslers in the superlattice. Various full-full, full-half, and half-half Heusler superlattices are studied, and potential half-metallic superlattices with perpendicular magnetocrystalline anisotropy are identified.

Chiral phases of superfluid 3He in an anisotropic medium

NASA Astrophysics Data System (ADS)

Sauls, J. A.

2013-12-01

Recent advances in the fabrication and characterization of anisotropic silica aerogels with exceptional homogeneity provide new insight into the nature of unconventional pairing in disordered anisotropic media. I report theoretical analysis and predictions for the equilibrium phases of superfluid 3He infused into a low-density, homogeneous uniaxial aerogel. Ginzburg-Landau (GL) theory for a class of equal-spin-pairing (ESP) states in a medium with uniaxial anisotropy is developed and used to analyze recent experiments on uniaxially strained aerogels. For 3He in an axially “stretched” aerogel, GL theory predicts a transition from normal liquid into a chiral Anderson-Morel phase at Tc1 in which the chirality axis l̂ is aligned along the strain axis. This orbitally aligned state is protected from random fluctuations in the anisotropy direction, has a positive nuclear magnetic resonance (NMR) frequency shift, a sharp NMR resonance line, and is identified with the high-temperature ESP-1 phase of superfluid 3He in axially stretched aerogel. A second transition into a biaxial phase is predicted to onset at a slightly lower temperature Tc2

Domain engineering of the metastable domains in the 4f-uniaxial-ferromagnet CeRu2Ga2B

NASA Astrophysics Data System (ADS)

Wulferding, D.; Kim, H.; Yang, I.; Jeong, J.; Barros, K.; Kato, Y.; Martin, I.; Ayala-Valenzuela, O. E.; Lee, M.; Choi, H. C.; Ronning, F.; Civale, L.; Baumbach, R. E.; Bauer, E. D.; Thompson, J. D.; Movshovich, R.; Kim, Jeehoon

2017-04-01

In search of novel, improved materials for magnetic data storage and spintronic devices, compounds that allow a tailoring of magnetic domain shapes and sizes are essential. Good candidates are materials with intrinsic anisotropies or competing interactions, as they are prone to host various domain phases that can be easily and precisely selected by external tuning parameters such as temperature and magnetic field. Here, we utilize vector magnetic fields to visualize directly the magnetic anisotropy in the uniaxial ferromagnet CeRu2Ga2B. We demonstrate a feasible control both globally and locally of domain shapes and sizes by the external field as well as a smooth transition from single stripe to bubble domains, which opens the door to future applications based on magnetic domain tailoring.

Domain engineering of the metastable domains in the 4f-uniaxial-ferromagnet CeRu 2Ga 2B

DOE PAGES

Wulferding, Dirk; Kim, Hoon; Yang, Ilkyu; ...

2017-04-10

In search of novel, improved materials for magnetic data storage and spintronic devices, compounds that allow a tailoring of magnetic domain shapes and sizes are essential. Good candidates are materials with intrinsic anisotropies or competing interactions, as they are prone to host various domain phases that can be easily and precisely selected by external tuning parameters such as temperature and magnetic field. Here, we utilize vector magnetic fields to visualize directly the magnetic anisotropy in the uniaxial ferromagnet CeRu 2Ga 2B. We demonstrate a feasible control both globally and locally of domain shapes and sizes by the external field asmore » well as a smooth transition from single stripe to bubble domains, which opens the door to future applications based on magnetic domain tailoring.« less

Thickness dependence of voltage-driven magnetization switching in FeCo/PI/piezoelectric actuator heterostructures

NASA Astrophysics Data System (ADS)

Cui, B. S.; Guo, X. B.; Wu, K.; Li, D.; Zuo, Y. L.; Xi, L.

2016-03-01

Strain mediated magnetization switching of ferromagnetic/substrate/piezoelectric actuator heterostructures has become a hot issue due to the advantage of low-power consumption. In this work, Fe65Co35 thin films were deposited on a flexible polyamides (PI) substrate, which has quite low Young’s module (~4 GPa for PI as compared to ~180 GPa for Si) and benefits from complete transfer of the strain from the piezoelectric actuator to magnetic thin films. A complete 90° transition of the magnetic easy axis was realized in 50 nm thick FeCo films under the voltage of 70 V, while a less than 90° rotation angle of the magnetic easy axis direction was observed in other samples, which was ascribed to the distribution of the anisotropy field and/or the orthogonal misalignment between stress induced anisotropy and original uniaxial anisotropy. A model considering two uniaxial anisotropies with orthogonal arrangement was used to quantitatively understand the observed results and the linear-like voltage dependent anisotropy field, especially for 10 nm FeCo films, in which the switching mechanism along the easy axis direction can be explained by the domain wall depinning model. It indicates that the magnetic domain-wall movement velocity may be controlled by strain through tuning the energy barrier of the pinning in heterostructures. Moreover, voltage-driven 90° magnetization switching with low-power consumption was achieved in this work.

Micro-macro correlations and anisotropy in granular assemblies under uniaxial loading and unloading.

PubMed

Imole, Olukayode I; Wojtkowski, Mateusz; Magnanimo, Vanessa; Luding, Stefan

2014-04-01

The influence of contact friction on the behavior of dense, polydisperse granular assemblies under uniaxial (oedometric) loading and unloading deformation is studied using discrete element simulations. Even though the uniaxial deformation protocol is one of the "simplest" element tests possible, the evolution of the structural anisotropy necessitates its careful analysis and understanding, since it is the source of interesting and unexpected observations. On the macroscopic, homogenized, continuum scale, the deviatoric stress ratio and the deviatoric fabric, i.e., the microstructure behave in a different fashion during uniaxial loading and unloading. The maximal stress ratio and strain increase with increasing contact friction. In contrast, the deviatoric fabric reaches its maximum at a unique strain level independent of friction, with the maximal value decreasing with friction. For unloading, both stress and fabric respond to unloading strain with a friction-dependent delay but at different strains. On the micro-level, a friction-dependent non-symmetry of the proportion of weak (strong) and sliding (sticking) contacts with respect to the total contacts during loading and unloading is observed. Coupled to this, from the directional probability distribution, the "memory" and history-dependent behavior of granular systems is confirmed. Surprisingly, while a rank-2 tensor is sufficient to describe the evolution of the normal force directions, a sixth order harmonic approximation is necessary to describe the probability distribution of contacts, tangential force, and mobilized friction. We conclude that the simple uniaxial deformation activates microscopic phenomena not only in the active Cartesian directions, but also at intermediate orientations, with the tilt angle being dependent on friction, so that this microstructural features cause the interesting, nontrivial macroscopic behavior.

Evidence for gap anisotropy in SmB6

NASA Astrophysics Data System (ADS)

Derr, J.; Knebel, G.; Lapertot, G.; Salce, B.; Kunii, S.; Flouquet, J.

2007-03-01

Resistivity measurements under uniaxial stress have been performed on the intermediate valence compound SmB6 for various directions of the crystal. The experimental technique allows us to explore a limited pressure area (basically 0-3 kbar). Nevertheless, the results clearly show an anisotropy; indeed, the effect of the stress in the decrease of the residual resistivity is much higher in the <1 1 1> direction than in the <1 0 0> and the <1 1 0> orientations. This change is witness to the gap anisotropy which must be linked to the theory of excitonic semiconductors.

Magnetic anisotropy engineering: Single-crystalline Fe films on ion eroded ripple surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liedke, M. O.; Koerner, M.; Lenz, K.

We present a method to preselect the direction of an induced in-plane uniaxial magnetic anisotropy (UMA) in thin single-crystalline Fe films on MgO(001). Ion beam irradiation is used to modulate the MgO(001) surface with periodic ripples on the nanoscale. The ripple direction determines the orientation of the UMA, whereas the intrinsic cubic anisotropy of the Fe film is not affected. Thus, it is possible to superimpose an in-plane UMA with a precision of a few degrees - a level of control not reported so far that can be relevant for example in spintronics.

The finite scaling for S = 1 XXZ chains with uniaxial single-ion-type anisotropy

NASA Astrophysics Data System (ADS)

Wang, Honglei; Xiong, Xingliang

2014-03-01

The scaling behavior of criticality for spin-1 XXZ chains with uniaxial single-ion-type anisotropy is investigated by employing the infinite matrix product state representation with the infinite time evolving block decimation method. At criticality, the accuracy of the ground state of a system is limited by the truncation dimension χ of the local Hilbert space. We present four evidences for the scaling of the entanglement entropy, the largest eigenvalue of the Schmidt decomposition, the correlation length, and the connection between the actual correlation length ξ and the energy. The result shows that the finite scalings are governed by the central charge of the critical system. Also, it demonstrates that the infinite time evolving block decimation algorithm by the infinite matrix product state representation can be a quite accurate method to simulate the critical properties at criticality.

Review of the role of dielectric anisotropy in Dyakonov surface-wave propagation

NASA Astrophysics Data System (ADS)

Nelatury, Sudarshan R., II; Polo, John A., Jr.; Lakhtakia, Akhlesh

2008-08-01

Surface waves (SWs) are localized waves that travel along the planar interface between two different mediums when certain dispersion relations are satisfied. If both mediums have purely dielectric constitutive properties, the characteristics of SW propagation are determined by the anisotropy of both mediums. Surface waves are then called Dyakonov SWs (DSWs), after Dyakonov who theoretically established the possibility of SW propagation at the planar interface of an isotropic dielectric and a positive uniaxial dielectric. Since then, DSW propagation guided by interfaces between a variety of dielectrics has been studied. With an isotropic dielectric on one side, the dielectric on the other side of the interface can be not only positive uniaxial but also biaxial. DSW propagation can also occur along an interface between two uniaxial or biaxial dielectrics that are twisted about a common axis with respect to each other but are otherwise identical. Recently, DSW propagation has been studied taking (i) uniaxial dielectrics such as calomel and dioptase crystals; (ii) biaxial dielectrics such as hemimorphite, crocoite, tellurite, witherite, and cerussite; and (iii) electro-optic materials such as potassium niobate. With materials that are significantly anisotropic, the angular regime of directions for DSW propagation turns out to be narrow. In the case of naturally occurring crystals, one has to accept the narrow angular existence domain (AED). However, exploiting the Pockels effect not only facilitates dynamic electrical control of DSW propagation, but also widens the AED for DSW propagation.

Forces generated during stretch in the heart of the lobster Homarus americanus are anisotropic and are altered by neuromodulators

PubMed Central

Dickinson, E. S.; Johnson, A. S.; Ellers, O.; Dickinson, P. S.

2016-01-01

ABSTRACT Mechanical and neurophysiological anisotropies mediate three-dimensional responses of the heart of Homarus americanus. Although hearts in vivo are loaded multi-axially by pressure, studies of invertebrate cardiac function typically use uniaxial tests. To generate whole-heart length–tension curves, stretch pyramids at constant lengthening and shortening rates were imposed uniaxially and biaxially along longitudinal and transverse axes of the beating whole heart. To determine whether neuropeptides that are known to modulate cardiac activity in H. americanus affect the active or passive components of these length–tension curves, we also performed these tests in the presence of SGRNFLRFamide (SGRN) and GYSNRNYLRFamide (GYS). In uniaxial and biaxial tests, both passive and active forces increased with stretch along both measurement axes. The increase in passive forces was anisotropic, with greater increases along the longitudinal axis. Passive forces showed hysteresis and active forces were higher during lengthening than shortening phases of the stretch pyramid. Active forces at a given length were increased by both neuropeptides. To exert these effects, neuropeptides might have acted indirectly on the muscle via their effects on the cardiac ganglion, directly on the neuromuscular junction, or directly on the muscles. Because increases in response to stretch were also seen in stimulated motor nerve-muscle preparations, at least some of the effects of the peptides are likely peripheral. Taken together, these findings suggest that flexibility in rhythmic cardiac contractions results from the amplified effects of neuropeptides interacting with the length–tension characteristics of the heart. PMID:26896540

Biaxial Normal Strength Behavior in the Axial-Transverse Plane for Human Trabecular Bone—Effects of Bone Volume Fraction, Microarchitecture, and Anisotropy

PubMed Central

Sanyal, Arnav; Keaveny, Tony M.

2013-01-01

The biaxial failure behavior of the human trabecular bone, which has potential relevance both for fall and gait loading conditions, is not well understood, particularly for low-density bone, which can display considerable mechanical anisotropy. Addressing this issue, we investigated the biaxial normal strength behavior and the underlying failure mechanisms for human trabecular bone displaying a wide range of bone volume fraction (0.06–0.34) and elastic anisotropy. Micro-computer tomography (CT)-based nonlinear finite element analysis was used to simulate biaxial failure in 15 specimens (5 mm cubes), spanning the complete biaxial normal stress failure space in the axial-transverse plane. The specimens, treated as approximately transversely isotropic, were loaded in the principal material orientation. We found that the biaxial stress yield surface was well characterized by the superposition of two ellipses—one each for yield failure in the longitudinal and transverse loading directions—and the size, shape, and orientation of which depended on bone volume fraction and elastic anisotropy. However, when normalized by the uniaxial tensile and compressive strengths in the longitudinal and transverse directions, all of which depended on bone volume fraction, microarchitecture, and mechanical anisotropy, the resulting normalized biaxial strength behavior was well described by a single pair of (longitudinal and transverse) ellipses, with little interspecimen variation. Taken together, these results indicate that the role of bone volume fraction, microarchitecture, and mechanical anisotropy is mostly accounted for in determining the uniaxial strength behavior and the effect of these parameters on the axial-transverse biaxial normal strength behavior per se is minor. PMID:24121715

GaN microcavities: Giant Rabi splitting and optical anisotropy

NASA Astrophysics Data System (ADS)

Kavokin, Alexey; Gil, Bernard

1998-06-01

Numerical simulation of light reflection from a λ/2 GaN microcavity with Ga0.8Al0.2N/Ga0.5Al0.5N Bragg mirrors grown on the A surface of Al2O3 revealed a Rabi splitting of the order of 50 meV and remarkable optical anisotropy. These effects are originated from the giant exciton oscillator strength in GaN and a pronounced uniaxial strain in the structure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiogai, J.; Institute of Materials Research, Tohoku University, Sendai 980-8577, Miyagi; Ciorga, M., E-mail: mariusz.ciorga@ur.de

We investigate the angular dependence of the tunneling anisotropic magnetoresistance in (Ga,Mn)As/n-GaAs spin Esaki diodes in the regime where the tunneling process is dominated by the excess current through midgap states in (Ga,Mn)As. We compare it to similar measurements performed in the regime of band-to-band tunneling. Whereas the latter show biaxial symmetry typical for magnetic anisotropy observed in (Ga,Mn)As samples, the former is dominated by uniaxial anisotropy along the 〈110〉 axes.

Mechanical characterization of a short fiber-reinforced polymer at room temperature: experimental setups evaluated by an optical measurement system

NASA Astrophysics Data System (ADS)

Röhrig, C.; Scheffer, T.; Diebels, S.

2017-09-01

Composite materials are of great interest for industrial applications because of their outstanding properties. Each composite material has its own characteristics due to the large number of possible combinations of matrix and filler. As a result of their compounding, composites usually show a complex material behavior. This work is focused on the experimental testing of a short fiber-reinforced thermoplastic composite at room temperature. The characteristic behavior of this material class is often based on a superposition of typical material effects. The predicted characteristic material properties such as elasto-plasticity, damage and anisotropy of the investigated material are obtained from results of cyclic uniaxial tensile tests at constant strain rate. Concerning the manufacturing process as well as industrial applications, the experimental investigations are extended to multiaxial loading situations. Therefore, the composite material is examined with a setup close to a deep-drawing process, the Nakajima test (Nakazima et al. in Study on the formability of steel sheets. Yawate Technical Report No. 264, pp 8517-8530, 1968). The evaluation of the experimental investigations is provided by an optical analysis system using a digital image correlation software. Finally, based on the results of the uniaxial tensile tests, a one-dimensional macroscopic model is introduced and first results of the simulation are provided.

Three-dimensional spin mapping of antiferromagnetic nanopyramids having spatially alternating surface anisotropy at room temperature.

PubMed

Wang, Kangkang; Smith, Arthur R

2012-11-14

Antiferromagnets play a key role in modern spintronic devices owing to their ability to modify the switching behavior of adjacent ferromagnets via the exchange bias effect. Consequently, detailed measurements of the spin structure at antiferromagnetic interfaces and surfaces are highly desirable, not only for advancing technologies but also for enabling new insights into the underlying physics. Here using spin-polarized scanning tunneling microscopy at room-temperature, we reveal in three-dimensions an orthogonal spin structure on antiferromagnetic compound nanopyramids. Contrary to expected uniaxial anisotropy based on bulk properties, the atomic terraces are found to have alternating in-plane and out-of-plane magnetic anisotropies. The observed layer-wise alternation in anisotropy could have strong influences on future nanoscale spintronic applications.

Correlation between swift effects and tension-compression asymmetry in various polycrystalline materials

NASA Astrophysics Data System (ADS)

Revil-Baudard, Benoit; Chandola, Nitin; Cazacu, Oana; Barlat, Frédéric

2014-10-01

The Swift phenomenon, which refers to the occurrence of permanent axial deformation during monotonic free-end torsion, has been known for a very long time. While plastic anisotropy is considered to be its main cause, there is no explanation as to why in certain materials irreversible elongation occurs while in others permanent shortening is observed. In this paper, a correlation between Swift effects and the stress-strain behavior in uniaxial tension and compression is established. It is based on an elastic-plastic model that accounts for the combined influence of anisotropy and tension-compression asymmetry. It is shown that, if for a given orientation the uniaxial yield stress in tension is larger than that in compression, the specimen will shorten when twisted about that direction; however, if the yield stress in uniaxial compression is larger than that in uniaxial tension, axial elongation will occur. Furthermore, it is shown that on the basis of a few simple mechanical tests it is possible to predict the particularities of the plastic response in torsion for both isotropic and initially anisotropic materials. Unlike other previous interpretations of the Swift effects, which were mainly based on crystal plasticity and/or texture evolution, it is explained the occurrence of Swift effects at small to moderate plastic strains. In particular, the very good quantitative agreement between model and data for a strongly anisotropic AZ31-Mg alloy confirm the correlation established in this work between tension-compression asymmetry and Swift effects. Furthermore, it is explained why the sign of the axial plastic strains that develop depends on the twisting direction.

Effects of uniaxial pressure on the quantum tunneling of magnetization in a high-symmetry Mn12 single-molecule magnet

NASA Astrophysics Data System (ADS)

Atkinson, James H.; Fournet, Adeline D.; Bhaskaran, Lakshmi; Myasoedov, Yuri; Zeldov, Eli; del Barco, Enrique; Hill, Stephen; Christou, George; Friedman, Jonathan R.

2017-05-01

The symmetry of single-molecule magnets dictates their spin quantum dynamics, influencing how such systems relax via quantum tunneling of magnetization (QTM). By reducing a system's symmetry, through the application of a magnetic field or uniaxial pressure, these dynamics can be modified. We report measurements of the magnetization dynamics of a crystalline sample of the high-symmetry [M n12O12(O2CMe) 16(Me OH ) 4].M e OH single-molecule magnet as a function of uniaxial pressure applied either parallel or perpendicular to the sample's "easy" magnetization axis. At temperatures between 1.8 and 3.3 K, magnetic hysteresis loops exhibit the characteristic steplike features that signal the occurrence of QTM. After applying uniaxial pressure to the sample in situ, both the magnitude and field position of the QTM steps changed. The step magnitudes were observed to grow as a function of pressure in both arrangements of pressure, while pressure applied along (perpendicular to) the sample's easy axis caused the resonant-tunneling fields to increase (decrease). These observations were compared with simulations in which the system's Hamiltonian parameters were changed. From these comparisons, we determined that parallel pressure induces changes to the second-order axial anisotropy parameter as well as either the fourth-order axial or fourth-order transverse parameter, or to both. In addition, we find that pressure applied perpendicular to the easy axis induces a rhombic anisotropy E ≈D /2000 per kbar that can be understood as deriving from a symmetry-breaking distortion of the molecule.

Magnetic anisotropy of rare-earth magnets calculated by SIC and OEP

NASA Astrophysics Data System (ADS)

Akai, Hisazumi; Ogura, Masako

We have pointed out in our previous study that the chemical bonding between N and Sm plays an important role in the magnetic anisotropy change of Sm2Fe17 from in-plane to uniaxial ones caused by the introducing of N. This effect of N insertion was discussed in terms of change in the electronic structure calculated in the framework of LDA+SIC. The main issue here is whether the 4f states are dealt with properly in SIC. In the present study, we examine the applicability of SIC for the evaluation of the magnetic anisotropy of rare-earth (RE) magnets by comparing the results with various methods, in particular, the optimized effective potential (OEP) method. In this study, OEP is applied only on the RE sites. Admittedly, this is a drawback from the viewpoint of the consistent treatment of uncertainly inherent in the so-called KLI (Krieger-Li-Iafrate) constants. Putting this aside for the moment, we have calculated the electronic structure of RE magnets R2Fe17Nx and RCo5 (R=light RE), by OEP with exact-exchange (EXX) combined with Colle-Salvetti correlation. Our preliminary results have shown considerable differences between the SIC and OEP calculations. We will discuss the meaning of this discrepancy. This work was supported by the Elements Strategy Initiative Center for Magnetic Materials under the outsourcing project of MEXT and by a Grant-in-Aid for Scientific Research (No. 26400330) from MEXT.

Ab initio elastic properties and tensile strength of crystalline hydroxyapatite.

PubMed

Ching, W Y; Rulis, Paul; Misra, A

2009-10-01

We report elastic constant calculation and a "theoretical" tensile experiment on stoichiometric hydroxyapatite (HAP) crystal using an ab initio technique. These results compare favorably with a variety of measured data. Theoretical tensile experiments are performed on the orthorhombic cell of HAP for both uniaxial and biaxial loading. The results show considerable anisotropy in the stress-strain behavior. It is shown that the failure behavior of the perfect HAP crystal is brittle for tension along the z-axis with a maximum stress of 9.6 GPa at 10% strain. Biaxial failure envelopes from six "theoretical" loading tests show a highly anisotropic pattern. Structural analysis of the crystal under various stages of tensile strain reveals that the deformation behavior manifests itself mainly in the rotation of the PO(4) tetrahedron with concomitant movements of both the columnar and axial Ca ions. These results are discussed in the context of mechanical properties of bioceramic composites relevant to mineralized tissues.

Magnetic properties of ultrathin tetragonal Heusler D022-Mn3Ge perpendicular-magnetized films

NASA Astrophysics Data System (ADS)

Sugihara, A.; Suzuki, K. Z.; Miyazaki, T.; Mizukami, S.

2015-05-01

We investigated the crystal structure and magnetic properties of Manganese-germanium (Mn3Ge) films having the tetragonal D022 structure, with varied thicknesses (5-130 nm) prepared on chromium (Cr)-buffered single crystal MgO(001) substrates. A crystal lattice elongation in the in-plane direction, induced by the lattice mismatch between the D022-Mn3Ge and the Cr buffer layer, increased with decreasing thickness of the D022-Mn3Ge layer. The films exhibited clear magnetic hysteresis loops with a squareness ratio close to unity, and a step-like magnetization reversal even at a 5-nm thickness under an external field perpendicular to the film's plane. The uniaxial magnetic anisotropy constant of the films showed a reduction to less than 10 Merg/cm3 in the small thickness range (≤20 nm), likely due to the crystal lattice elongation in the in-plane direction.

Tensile behavior and flow stress anisotropy of accumulative roll bonded Cu-Nb nanolaminates

DOE PAGES

Nizolek, Thomas; Beyerlein, Irene J.; Mara, Nathan A.; ...

2016-02-01

The flow stress, ductility, and in-plane anisotropy are evaluated for bulk accumulative roll bonded copper-niobium nanolaminates with layer thicknesses ranging from 1.8 μm to 15 nm. Uniaxial tensile tests conducted parallel to the rolling direction and transverse direction demonstrate that ductility generally decreases with decreasing layer thickness; however, at 30 nm, both high strengths (1200 MPa) and significant ductility (8%) are achieved. The yield strength increases monotonically with decreasing layer thickness, consistent with the Hall-Petch relationship, and significant in-plane flow stress anisotropy is observed. As a result, Taylor polycrystal modeling is used to demonstrate that crystallographic texture is responsible formore » the in-plane anisotropy and that the effects of texture dominate even at nanoscale layer thicknesses.« less

Magnetic anisotropy, damping, and interfacial spin transport in Pt/LSMO bilayers

DOE PAGES

Lee, H. K.; Barsukov, I.; Swartz, A. G.; ...

2016-05-16

In this paper, we report ferromagnetic resonance measurements of magnetic anisotropy and damping in epitaxial La 0.7Sr 0.3MnO 3 (LSMO) and Pt capped LSMO thin films on SrTiO 3 (001) substrates. The measurements reveal large negative perpendicular magnetic anisotropy and a weaker uniaxial in-plane anisotropy that are unaffected by the Pt cap. The Gilbert damping of the bare LSMO films is found to be low α = 1.9(1) × 10 -3, and two-magnon scattering is determined to be significant and strongly anisotropic. The Pt cap increases the damping by 50% due to spin pumping, which is also directly detected viamore » inverse spin Hall effect in Pt. Our research demonstrates efficient spin transport across the Pt/LSMO interface.« less

Nanoscale magnetic ratchets based on shape anisotropy

NASA Astrophysics Data System (ADS)

Cui, Jizhai; Keller, Scott M.; Liang, Cheng-Yen; Carman, Gregory P.; Lynch, Christopher S.

2017-02-01

Controlling magnetization using piezoelectric strain through the magnetoelectric effect offers several orders of magnitude reduction in energy consumption for spintronic applications. However strain is a uniaxial effect and, unlike directional magnetic field or spin-polarized current, cannot induce a full 180° reorientation of the magnetization vector when acting alone. We have engineered novel ‘peanut’ and ‘cat-eye’ shaped nanomagnets on piezoelectric substrates that undergo repeated deterministic 180° magnetization rotations in response to individual electric-field-induced strain pulses by breaking the uniaxial symmetry using shape anisotropy. This behavior can be likened to a magnetic ratchet, advancing magnetization clockwise with each piezostrain trigger. The results were validated using micromagnetics implemented in a multiphysics finite elements code to simulate the engineered spatial and temporal magnetic behavior. The engineering principles start from a target device function and proceed to the identification of shapes that produce the desired function. This approach opens a broad design space for next generation magnetoelectric spintronic devices.

Anisotropic planar Heisenberg model of the quantum heterobimetallic zigzag chains with bridged ReIV-CuII magnetic complexes

NASA Astrophysics Data System (ADS)

Sobczak, P.; Barasiński, A.; Kamieniarz, G.; Drzewiński, A.

2011-12-01

An anisotropic quantum planar Heisenberg model is proposed and thoroughly analyzed within the numerical density-matrix renormalization group approach. The model takes into account the site-dependent alternating directions of the local coordination system for the ReIV ions and both the axial and the rhombic single-ion anisotropy terms. Thermodynamic properties of a simpler collinear model without the rhombic term and its Ising counterpart as well as some previous approximations for ReIV-ion-containing compounds are discussed to point out the importance of quantum effects and deficiencies of classical approaches. For the noncollinear model with the alternating uniaxial local z axis tilted by the angle θ from the global chain axis formed by copper ions, some symmetries for the single-crystal susceptibilities are found. In the strong-anisotropy limit some striking maxima in the corresponding single-crystal χT products are revealed and their relation to the experimental determination of the anisotropy parameters is emphasized. Some cases to which the collinear model for zigzag chains is fully applicable are indicated. Finally, fitting the reference experimental data for a powder sample of given chloro- and cyanobridged zigzag chains, the weaker magnetic coupling and the uniaxial single-ion anisotropy term parameters have been found. The corrected value of the ferromagnetic interaction parameter implies that for the cyanobridge compound the record of the highest superexchange through cyanide has not been beaten.

Electrical resistivity of the UAs 1- xSex solid solutions

NASA Astrophysics Data System (ADS)

Breandon, C.; Bartholin, H.; Tchapoutian, R.; Therond, P. G.; Schoenes, J.; Vogt, O.

1987-01-01

The electrical resistivity ϱ of UAs 1- xSex solid solutions has been measured between 13 K and room temperature. The magnetic phase diagram has been deduced. Effects of uniaxial stress on ϱ allow to understand some results and to reveal anisotropy of ϱ.

Acoustic anisotropy in uniaxial tungsten bronze ferroelectric single crystals studied by Brillouin light scattering

NASA Astrophysics Data System (ADS)

Ko, Jae-Hyeon; Lushnikov, S. G.; Kim, Do Han; Kojima, Seiji; Jun, Byeong-Eog; Hwang, Yoon Hwae

2008-11-01

Acoustic properties were investigated for four tungsten bronze (TB) uniaxial ferroelectric crystals, i.e., (Sr0.61Ba0.39)5Nb10O30 (SBN61), Cu-doped (K0.5Na0.5)1.0(Sr0.75Ba0.25)4.5Nb10O30 (KNSBN:Cu), K5.80Li3.82Nb10.12O30, and K4.74Li3.07Nb10.44O30 of which the spontaneous polarization is directed along the polar c axis. Large acoustic anisotropy between the two elastic constants C11 and C33 have been observed from all samples. C33 exhibits a significant softening on approaching the diffuse phase transition temperature from high-temperature side while C11 does not show any substantial change in the same temperature range. This softening is accompanied by substantial growth of hypersonic damping, appearance and growth of central peak (CP), and slowing down of the relevant dynamics of CP represented by the reducing half width. All these results indicate that the lattice motions along the c axis couple strongly to the one-component order parameter of the polar nanoregions (PNRs) or precursor polar clusters which form and grow below a certain temperature in the paraelectric phase. The inverse dielectric constant measured along the c axis of SBN61 and KNSBN:Cu can be described by two linear regions divided by a crossover temperature at which the change in the magnitude of dipole moments and the strength of the dipole couplings are expected due to the formation of PNRs. C33 of SBN61 becomes continuously softened upon cooling even when the temperature crosses the Burns temperature TB at which PNRs begin to appear. It may suggest that additional relaxation process other than that of PNRs may exist at high temperatures above TB and couple to the longitudinal acoustic waves propagating along the polar axis. Recent observation of a single-particle relaxation at high temperatures and its transformation into a collective relaxation of PNRs by dielectric spectroscopy [Belous et al., J. Appl. Phys. 102, 014111 (2007)] might be related to the anomalous acoustic behavior of SBN61 observed above TB.

Simulations of magnetic hysteresis loops at high temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Plumer, M. L.; Whitehead, J. P.; Fal, T. J.

2014-09-28

The kinetic Monte-Carlo algorithm as well as standard micromagnetics are used to simulate MH loops of high anisotropy magnetic recording media at both short and long time scales over a wide range of temperatures relevant to heat-assisted magnetic recording. Microscopic parameters, common to both methods, were determined by fitting to experimental data on single-layer FePt-based media that uses the Magneto-Optic Kerr effect with a slow sweep rate of 700 Oe/s. Saturation moment, uniaxial anisotropy, and exchange constants are given an intrinsic temperature dependence based on published atomistic simulations of FePt grains with an effective Curie temperature of 680 K. Ourmore » results show good agreement between micromagnetics and kinetic Monte Carlo results over a wide range of sweep rates. Loops at the slow experimental sweep rates are found to become more square-shaped, with an increasing slope, as temperature increases from 300 K. These effects also occur at higher sweep rates, typical of recording speeds, but are much less pronounced. These results demonstrate the need for accurate determination of intrinsic thermal properties of future recording media as input to micromagnetic models as well as the sensitivity of the switching behavior of thin magnetic films to applied field sweep rates at higher temperatures.« less

A numerical study on the influence of the Portevin Le Chatelier effect on necking in an aluminium alloy

NASA Astrophysics Data System (ADS)

Hopperstad, O. S.; Børvik, T.; Berstad, T.; Lademo, O.-G.; Benallal, A.

2007-10-01

The constitutive relation proposed by McCormick (1988 Acta Metall. 36 3061-7) for materials exhibiting negative steady-state strain-rate sensitivity and the Portevin-Le Chatelier (PLC) effect is incorporated into an elastic-viscoplastic model for metals with plastic anisotropy. The constitutive model is implemented in LS-DYNA for corotational shell elements. Plastic anisotropy is taken into account by use of the yield criterion Yld2000/Yld2003 proposed by Barlat et al (2003 J. Plast. 19 1297-319) and Aretz (2004 Modelling Simul. Mater. Sci. Eng. 12 491-509). The parameters of the constitutive equations are determined for a rolled aluminium alloy (AA5083-H116) exhibiting negative steady-state strain-rate sensitivity and serrated yielding. The parameter identification is based on existing experimental data. A numerical investigation is conducted to determine the influence of the PLC effect on the onset of necking in uniaxial and biaxial tension for different overall strain rates. The numerical simulations show that the PLC effect leads to significant reductions in the strain to necking for both uniaxial and biaxial stress states. Increased surface roughness with plastic deformation is predicted for strain rates giving serrated yielding in uniaxial tension. It is likely that this is an important reason for the reduced critical strains. The characteristics of the deformation bands (orientation, width, velocity and strain rate) are also studied.

Effect of uniaxial stress on the polarization of light emitted from GaN/AlN quantum dots grown on Si(111)

NASA Astrophysics Data System (ADS)

Moshe, O.; Rich, D. H.; Damilano, B.; Massies, J.

2008-04-01

Cathodoluminescence (CL) measurements of the ground-state excitonic transition of vertically stacked GaN/AlN quantum dots (QDs) exhibited an in-plane linear polarization anisotropy in close proximity to microcracks. Microcracks form as a result of a mismatch of the thermal expansion coefficient between the GaN/AlN layers and the Si(111) substrate. In close proximity to the cracks, the layers are found to be under uniaxial tensile stress, whereas the film is under biaxial tensile stress for distances greater than ˜3μm from the cracks. The microcracks serve as an excellent stressor through which the strain tensor of the GaN/AlN QDs can be reproducibly modified for studies of strain-induced changes in the optical and electronic properties by using a spatially resolved probe, such as with CL. Changes in the optical properties of the QDs are attributed to stress-dependent variations of the band edges and the electric field along [0001], which is caused by charge polarization. Such changes in the field will subsequently affect the oscillator strength between electrons and holes. Three-dimensional 6×6 kṡp calculations of the QD electron and hole wave functions and eigenstates were performed to examine the influence of biaxial and uniaxial tensile stresses on the polarization-dependent momentum matrix element in varying proximity to the microcracks. The model reveals that a change from biaxial to uniaxial stress alters the admixture of px and py characters of the band edges and the ground-state hole wave function, changes the shape and direction of elongation of the hole isosurfaces, and accounts well for the subsequent anisotropy in the polarization dependent optical transitions.

Damage tolerance of pressurized graphite/epoxy tape cylinders under uniaxial and biaxial loading. M.S. Thesis

NASA Technical Reports Server (NTRS)

Priest, Stacy Marie

1993-01-01

The damage tolerance behavior of internally pressurized, axially slit, graphite/epoxy tape cylinders was investigated. Specifically, the effects of axial stress, structural anisotropy, and subcritical damage were considered. In addition, the limitations of a methodology which uses coupon fracture data to predict cylinder failure were explored. This predictive methodology was previously shown to be valid for quasi-isotropic fabric and tape cylinders but invalid for structurally anisotropic (+/-45/90)(sub s) and (+/-45/0)(sub s) cylinders. The effects of axial stress and structural anisotropy were assessed by testing tape cylinders with (90/0/+/-45)(sub s), (+/-45/90)(sub s), and (+/-45/0)(sub s) layups in a uniaxial test apparatus, specially designed and built for this work, and comparing the results to previous tests conducted in biaxial loading. Structural anisotropy effects were also investigated by testing cylinders with the quasi-isotropic (0/+/-45/90)(sub s) layup which is a stacking sequence variation of the previously tested (90/0/+/-45)(sub s) layup with higher D(sub 16) and D(sub 26) terms but comparable D(sub 16) and D(sub 26) to D(sub 11) ratios. All cylinders tested and used for comparison are made from AS4/3501-6 graphite/epoxy tape and have a diameter of 305 mm. Cylinder slit lengths range from 12.7 to 50.8 mm. Failure pressures are lower for the uniaxially loaded cylinders in all cases. The smallest percent failure pressure decreases are observed for the (+/-45/90)(sub s) cylinders, while the greatest such decreases are observed for the (+/-45/0)(sub s) cylinders. The relative effects of the axial stress on the cylinder failure pressures do not correlate with the degree of structural coupling. The predictive methodology is not applicable for uniaxially loaded (+/-45/90)(sub s) and (+/-45/0)(sub s) cylinders, may be applicable for uniaxially loaded (90/0/+/-45)(sub s) cylinders, and is applicable for the biaxially loaded (90/0/+/-45)(sub s) and (0/+/-45/90)(sub s) cylinders. This indicates that the ratios of D(sub 16) and D(sub 26) to D(sub 11), as opposed to the absolute magnitudes of D(sub 16) and D(sub 26), may be important in the failure of these cylinders and in the applicability of the methodology. Discontinuities observed in the slit tip hoop strains for all the cylinders tested indicate that subcritical damage can play an important role in the failure of tape cylinders. This role varies with layup and loading condition and is likely coupled to the effects of structural anisotropy. Biaxial failure pressures may exceed the uniaxial values because the axial stress contributes to the formation of 0 deg ply splitting (accompanied by delamination) or similar stress-mitigating subcritical damage. The failure behavior of similar cylinders can also vary as a result of differences in the role of subcritical damage as observed for the case of a biaxially loaded (90/0/+/-45)(sub s) cylinder with a 12.7 mm slit. For this case, the methodology is valid when the initial coupon and cylinder fracture modes agree. However, the methodology underpredicts the failure pressure of the cylinder when a circumferential fracture path, suggestive of a 0 deg ply split, occurs at one slit tip. Thus, the failure behavior of some tape cylinders may be highly sensitive to the initial subcritical damage mechanism. Finite element analyses are recommended to determine how structural anisotropy and axial stress modify the slit tip stress states in cylinders from those found in flat plates since similarity of these stress states is a fundamental assumption of the current predictive methodology.

Magnetic and resonance properties of ferrihydrite nanoparticles doped with cobalt

NASA Astrophysics Data System (ADS)

Stolyar, S. V.; Yaroslavtsev, R. N.; Iskhakov, R. S.; Bayukov, O. A.; Balaev, D. A.; Dubrovskii, A. A.; Krasikov, A. A.; Ladygina, V. P.; Vorotynov, A. M.; Volochaev, M. N.

2017-03-01

Powders of undoped ferrihydrite nanoparticles and ferrihydrite nanoparticles doped with cobalt in the ratio of 5: 1 have been prepared by hydrolysis of 3 d-metal salts. It has been shown using Mössbauer spectroscopy that cobalt is uniformly distributed over characteristic crystal-chemical positions of iron ions. The blocking temperatures of ferrihydrite nanoparticles have been determined. The nanoparticle sizes, magnetizations, surface anisotropy constants, and bulk anisotropy constants have been estimated. The doping of ferrihydrite nanoparticles with cobalt leads to a significant increase in the anisotropy constant of a nanoparticle and to the formation of surface rotational anisotropy with the surface anisotropy constant K u = 1.6 × 10-3 erg/cm2.

Magneto-ionic effect in CoFeB thin films with in-plane and perpendicular-to-plane magnetic anisotropy

NASA Astrophysics Data System (ADS)

Baldrati, L.; Tan, A. J.; Mann, M.; Bertacco, R.; Beach, G. S. D.

2017-01-01

The magneto-ionic effect is a promising method to control the magnetic properties electrically. Charged mobile oxygen ions can easily be driven by an electric field to modify the magnetic anisotropy of a ferromagnetic layer in contact with an ionic conductor in a solid-state device. In this paper, we report on the room temperature magneto-ionic modulation of the magnetic anisotropy of ultrathin CoFeB films in contact with a GdOx layer, as probed by polar micro-Magneto Optical Kerr Effect during the application of a voltage across patterned capacitors. Both Pt/CoFeB/GdOx films with perpendicular magnetic anisotropy and Ta/CoFeB/GdOx films with uniaxial in-plane magnetic anisotropy in the as-grown state exhibit a sizable dependence of the magnetic anisotropy on the voltage (amplitude, polarity, and time) applied across the oxide. In Pt/CoFeB/GdOx multilayers, it is possible to reorient the magnetic anisotropy from perpendicular-to-plane to in-plane, with a variation of the magnetic anisotropy energy greater than 0.2 mJ m-2. As for Ta/CoFeB/GdOx multilayers, magneto-ionic effects still lead to a sizable variation of the in-plane magnetic anisotropy, but the anisotropy axis remains in-plane.

Synthesis, characterization and magneto optical properties of BaBixLaxYxFe12-3xO19 (0.0≤x≤0.33) hexaferrites

NASA Astrophysics Data System (ADS)

Güner, S.; Auwal, I. A.; Baykal, A.; Sözeri, H.

2016-10-01

BaBixLaxYxFe12-3xO19 (0.0≤x≤0.33) hexaferrites were synthesized by sol-gel autocombustion method and the effects of Bi, La, Y substitutions on structural, magneto-optical properties of barium hexaferrite were investigated. X-ray diffraction (XRD), Scanning electron microscopy (SEM), Vibrating sample magnetometer (VSM), and Percent diffuse reflectance spectroscopy (DR %), were used to study the physical properties. XRD peaks showed pure single phase of hexagonal ferrites and the average crystallite size varies in a range of 42.35-49.90 nm. Room temperature (RT) specific magnetization (σ-H) data revealed the strong ferromagnetic nature of hexaferrite with remanant specific magnetization (σr) in the range of 29.9-34.6 Am2/kg and extrapolated specific saturation magnetization (σs) in the range 53.69-67.42 Am2/kg. The maximum coercive field (Hc) of 3.812×105 A/m (belongs to BaFe12O19) decreases to minimum 2.177×105 A/m with increasing ion substitution. Magnetic anisotropy was confirmed as uniaxial and effective anisotropy constant (Keff) takes values between 2.532×105 J/m3 and 3.105×105 J/m3. The anisotropy field (Ha) around 1.6 T revealed that all samples are magnetically hard materials. The Tauc graphs were plotted to estimate the direct optical energy band gap (Eg) of hexaferrite. The Eg values decreased from 1.88 eV to 1.69 eV with increasing Bi, La, Y compositions.

Correlation between physical structure and magnetic anisotropy of a magnetic nanoparticle colloid.

PubMed

Dennis, C L; Jackson, A J; Borchers, J A; Gruettner, C; Ivkov, R

2018-05-25

We show the effects of a time-invariant magnetic field on the physical structure and magnetic properties of a colloid comprising 44 nm diameter magnetite magnetic nanoparticles, with a 24 nm dextran shell, in water. Structural ordering in this colloid parallel to the magnetic field occurs simultaneously with the onset of a colloidal uniaxial anisotropy. Further increases in the applied magnetic field cause the nanoparticles to order perpendicular to the field, producing unexpected colloidal unidirectional and trigonal anisotropies. This magnetic behavior is distinct from the cubic magnetocrystalline anisotropy of the magnetite and has its origins in the magnetic interactions among the mobile nanoparticles within the colloid. Specifically, these field-induced anisotropies and colloidal rearrangements result from the delicate balance between the magnetostatic and steric forces between magnetic nanoparticles. These magnetic and structural rearrangements are anticipated to influence applications that rely upon time-dependent relaxation of the magnetic colloids and fluid viscosity, such as magnetic hyperthermia and shock absorption.

Correlation between physical structure and magnetic anisotropy of a magnetic nanoparticle colloid

NASA Astrophysics Data System (ADS)

Dennis, C. L.; Jackson, A. J.; Borchers, J. A.; Gruettner, C.; Ivkov, R.

2018-05-01

We show the effects of a time-invariant magnetic field on the physical structure and magnetic properties of a colloid comprising 44 nm diameter magnetite magnetic nanoparticles, with a 24 nm dextran shell, in water. Structural ordering in this colloid parallel to the magnetic field occurs simultaneously with the onset of a colloidal uniaxial anisotropy. Further increases in the applied magnetic field cause the nanoparticles to order perpendicular to the field, producing unexpected colloidal unidirectional and trigonal anisotropies. This magnetic behavior is distinct from the cubic magnetocrystalline anisotropy of the magnetite and has its origins in the magnetic interactions among the mobile nanoparticles within the colloid. Specifically, these field-induced anisotropies and colloidal rearrangements result from the delicate balance between the magnetostatic and steric forces between magnetic nanoparticles. These magnetic and structural rearrangements are anticipated to influence applications that rely upon time-dependent relaxation of the magnetic colloids and fluid viscosity, such as magnetic hyperthermia and shock absorption.

Dynamics of the magnetization of single domain particles having triaxial anisotropy subjected to a uniform dc magnetic field

NASA Astrophysics Data System (ADS)

Ouari, Bachir; Kalmykov, Yury P.

2006-12-01

Thermally induced relaxation of the magnetization of single domain ferromagnetic particles with triaxial (orthorhombic) anisotropy in the presence of a uniform external magnetic field H0 is considered in the context of Brown's continuous diffusion model. Simple analytic equations, which allow one to describe qualitatively the field effects in the relaxation behavior of the system for wide ranges of the field strength and damping parameters are derived. It is shown that these formulas are in complete agreement with the exact matrix continued fraction solution of the infinite hierarchy of linear differential-recurrence equations for the statistical moments, which governs the magnetization dynamics of an individual particle (this hierarchy is derived by averaging the underlying stochastic Landau-Lifshitz-Gilbert equation over its realizations). It is also demonstrated that in strong fields the longitudinal relaxation of the magnetization is essentially modified by the contribution of the high-frequency "intrawell" modes to the relaxation process. This effect discovered for uniaxial particles by Coffey et al. [Phys. Rev. B 51, 15947 (1995)] is the natural consequence of the depletion of population of the shallow potential well. However, in contrast to uniaxial anisotropy, for orthorhombic crystals there is an inherent geometric dependence of the complex magnetic susceptibility and the relaxation time on the damping parameter α arising from the coupling of longitudinal and transverse relaxation modes.

Resonant x-ray diffraction revealing chemical disorder in sputtered L10 FeNi on Si(0 0 1)

NASA Astrophysics Data System (ADS)

Frisk, Andreas; Lindgren, Bengt; Pappas, Spiridon D.; Johansson, Erik; Andersson, Gabriella

2016-10-01

In the search for new rare earth free permanent magnetic materials, FeNi with a L10 structure is a possible candidate. We have synthesized the phase in the thin film form by sputtering onto HF-etched Si(0 0 1) substrates. Monatomic layers of Fe and Ni were alternately deposited on a Cu buffer layer, all of which grew epitaxially on the Si substrates. A good crystal structure and epitaxial relationship was confirmed by in-house x-ray diffraction (XRD). The chemical order, which to some part is the origin of an uniaxial magnetic anisotropy, was measured by resonant XRD. The 0 0 1 superlattice reflection was split in two symmetrically spaced peaks due to a composition modulation of the Fe and Ni layers. Furthermore the influence of roughness induced chemical anti-phase domains on the RXRD pattern is exemplified. A smaller than expected magnetic uniaxial anisotropy energy was obtained, which is partly due to the composition modulations, but the major reason is concluded to be the Cu buffer surface roughness.

Resonant x-ray diffraction revealing chemical disorder in sputtered L10 FeNi on Si(0 0 1).

PubMed

Frisk, Andreas; Lindgren, Bengt; Pappas, Spiridon D; Johansson, Erik; Andersson, Gabriella

2016-10-12

In the search for new rare earth free permanent magnetic materials, FeNi with a L10 structure is a possible candidate. We have synthesized the phase in the thin film form by sputtering onto HF-etched Si(0 0 1) substrates. Monatomic layers of Fe and Ni were alternately deposited on a Cu buffer layer, all of which grew epitaxially on the Si substrates. A good crystal structure and epitaxial relationship was confirmed by in-house x-ray diffraction (XRD). The chemical order, which to some part is the origin of an uniaxial magnetic anisotropy, was measured by resonant XRD. The 0 0 1 superlattice reflection was split in two symmetrically spaced peaks due to a composition modulation of the Fe and Ni layers. Furthermore the influence of roughness induced chemical anti-phase domains on the RXRD pattern is exemplified. A smaller than expected magnetic uniaxial anisotropy energy was obtained, which is partly due to the composition modulations, but the major reason is concluded to be the Cu buffer surface roughness.

Cu substituted CeCo 5 : New optimal permanent magnetic material with reduced criticality

DOE PAGES

Chouhan, Rajiv K.; Paudyal, D.

2017-06-26

A comprehensive theoretical prediction using a mechanism of site substitution confirms the crucial role of Cu in enhancing the capabilities of CeCo 5 as a competitive magnet with its known high coercivity. A remarkable enhancement of magnetic anisotropy energy (MAE) of 3.09 meV/f.u. and 2.94 meV/f.u. without significant decrease of magnetic moment is found for 10% and 5% Cu substitution at 2c sites of the hexagonal lattice. Our calculations predict the increment of coercivity and magnetocrystalline anisotropy (1.6 times) compared to pristine CeCo 5. Furthermore, the exceptional enhancement in MAE is due to the formation of asymmetric charge hybridization amongmore » the Cu (2c) and Co (both 2c and 3g) sites along the uniaxial direction. Because of this asymmetric charge distribution environment, the intrinsic behavior of Ce adjacent to Cu changes abruptly making them more uniaxial and magnetically enhanced creating mixed valence states. For our calculations, we have employed the full-potential augmented plane wave method in conjunction with spin orbit coupling.« less

The evolution of in-plane magnetic anisotropy in CoFeB/GaAs(001) films annealed at different temperatures

NASA Astrophysics Data System (ADS)

Tu, Hongqing; Wang, Ji; Wei, Lujun; Yuan, Yuan; Zhang, W.; You, Biao; Du, Jun

2018-05-01

A considerable in-plane uniaxial magnetic anisotropy (UMA) field (Hu ˜ 300 Oe) could be achieved when the amorphous CoFeB film was deposited on the GaAs(001) wafer by magnetron-sputtering after proper etch-annealed procedure. In order to get deep insights into the mechanism of the UMA, the film was annealed at different temperatures and the evolution of the in-plane magnetic anisotropy was investigated carefully. With increasing the annealing temperature (TA), the UMA could be maintained well when TA reached 250°C, but became very weak at 300°C. However, when TA was elevated to 400°C, another UMA (Hu ˜ 130 Oe) was built accompanied with a fourfold magnetic anisotropy with its strength of about 50 Oe. In terms of the magnetic anisotropy evolution along with TA, the anelastic strain, which is thought to be resulted from the interfacial interaction between CoFeB and GaAs, may play a dominant role in producing the enhanced UMA based on the `bond-orientational' anisotropy (BOA) model.

Influence of ambient moisture on the compaction behavior of microcrystalline cellulose powder undergoing uni-axial compression and roller-compaction: a comparative study using near-infrared spectroscopy.

PubMed

Gupta, Abhay; Peck, Garnet E; Miller, Ronald W; Morris, Kenneth R

2005-10-01

This study evaluates the effect of variation in the ambient moisture on the compaction behavior of microcrystalline cellulose (MCC) powder. The study was conducted by comparing the physico-mechanical properties of, and the near infrared (NIR) spectra collected on, compacts prepared by roller compaction with those collected on simulated ribbons, that is, compacts prepared under uni-axial compression. Relative density, moisture content, tensile strength (TS), and Young modulus were used as key sample attributes for comparison. Samples prepared at constant roller compactor settings and feed mass showed constant density and a decrease in TS with increasing moisture content. Compacts prepared under uni-axial compression at constant pressure and compact mass showed the opposite effect, that is, density increased while TS remained almost constant with increasing moisture content. This suggests difference in the influence of moisture on the material under roller compaction, in which the roll gap (i.e., thickness and therefore density) remains almost constant, vs. under uni-axial compression, in which the thickness is free to change in response to the applied pressure. Key sample attributes were also related to the NIR spectra using multivariate data analysis by the partial least squares projection to latent structures (PLS). Good agreement was observed between the measured and the NIR-PLS predicted values for all key attributes for both, the roller compacted samples as well as the simulated ribbons. Copyright (c) 2005 Wiley-Liss, Inc. and the American Pharmacists Association

Tailoring Magnetic Skyrmions by Geometric Confinement of Magnetic Structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Steven S.-L.; Phatak, C.; Petford-Long, A K

Nanoscale magnetic skyrmions have interesting static and transport properties that make them candidates for future spintronic devices. Control and manipulation of the size and behavior of skyrmions is thus of crucial importance. Here, using a Ginzburg-Landau approach, we show theoretically that skyrmions and skyrmion lattices can be stabilized by a spatial modulation of the uniaxial magnetic anisotropy in a thin film of a centro-symmetric ferromagnet. Remarkably, the skyrmion size is determined by the ratio of the exchange length and the period of the spatial modulation of the anisotropy, at variance with conventional skyrmions stabilized by dipolar and Dzyaloshinskii–Moriya interactions.

Tailoring Magnetic Skyrmions by Geometric Confinement of Magnetic Structures

DOE PAGES

Zhang, Steven S.-L.; Phatak, C.; Petford-Long, A K; ...

2017-12-12

Nanoscale magnetic skyrmions have interesting static and transport properties that make them candidates for future spintronic devices. Control and manipulation of the size and behavior of skyrmions is thus of crucial importance. Here, using a Ginzburg-Landau approach, we show theoretically that skyrmions and skyrmion lattices can be stabilized by a spatial modulation of the uniaxial magnetic anisotropy in a thin film of a centro-symmetric ferromagnet. Remarkably, the skyrmion size is determined by the ratio of the exchange length and the period of the spatial modulation of the anisotropy, at variance with conventional skyrmions stabilized by dipolar and Dzyaloshinskii–Moriya interactions.

Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory

NASA Astrophysics Data System (ADS)

Johnston, David C.

2017-03-01

The influence of uniaxial single-ion anisotropy -D Sz2 on the magnetic and thermal properties of Heisenberg antiferromagnets (AFMs) is investigated. The uniaxial anisotropy is treated exactly and the Heisenberg interactions are treated within unified molecular field theory (MFT) [Phys. Rev. B 91, 064427 (2015), 10.1103/PhysRevB.91.064427], where thermodynamic variables are expressed in terms of directly measurable parameters. The properties of collinear AFMs with ordering along the z axis (D >0 ) in applied field Hz=0 are calculated versus D and temperature T , including the ordered moment μ , the Néel temperature TN, the magnetic entropy, internal energy, heat capacity, and the anisotropic magnetic susceptibilities χ∥ and χ⊥ in the paramagnetic (PM) and AFM states. The high-field average magnetization per spin μz(Hz,D ,T ) is found, and the critical field Hc(D ,T ) is derived at which the second-order AFM to PM phase transition occurs. The magnetic properties of the spin-flop (SF) phase are calculated, including the zero-field properties TN(D ) and μ (D ,T ) . The high-field μz(Hz,D ,T ) is determined, together with the associated spin-flop field HSF(D ,T ) at which a second-order SF to PM phase transition occurs. The free energies of the AFM, SF, and PM phases are derived from which Hz-T phase diagrams are constructed. For fJ=-1 and -0.75 , where fJ=θp J/TN J and θp J and TN J are the Weiss temperature in the Curie-Weiss law and the Néel temperature due to exchange interactions alone, respectively, phase diagrams in the Hz-T plane similar to previous results are obtained. However, for fJ=0 we find a topologically different phase diagram where a spin-flop bubble with PM and AFM boundaries occurs at finite Hz and T . Also calculated are properties arising from a perpendicular magnetic field, including the perpendicular susceptibility χ⊥(D ,T ) , the associated effective torque at low fields arising from the -D Sz2 term in the Hamiltonian, the high-field perpendicular magnetization μ⊥, and the perpendicular critical field Hc ⊥ at which the second-order AFM to PM phase transition occurs. In addition to the above results for D >0 , the TN(D ) and ordered moment μ (T ,D ) for collinear AFM ordering along the x axis with D <0 are determined. In order to compare the properties of the above spin systems with those of noninteracting systems with -D Sz2 uniaxial anisotropy with either sign of D , Supplemental Material is provided in which results for the thermal and magnetic properties of such noninteracting spin systems are given.

Electrical Conductivity of Partially Molten Peridotite Analogue Under Shear: Supporting Evidence to the Partial Melting Hypothesis for the Oceanic Plate Motion

NASA Astrophysics Data System (ADS)

Manthilake, G.; Matsuzaki, T.; Yoshino, T.; Yamazaki, D.; Yoneda, A.; Ito, E.; Katsura, T.

2008-12-01

So far, two hypotheses have been proposed to explain softening of the oceanic asthenosphere allowing smooth motion of the oceanic lithosphere. One is partial melting, and the other is hydraulitic weakening. Although the hydraulitic weakening hypothesis is popular recently, Yoshino et al. [2006] suggested that this hypothesis cannot explain the high and anisotropic conductivity at the top of the asthenosphere near East Pacific Rise observed by Evans et al. [2005]. In order to explain the conductivity anisotropy over one order of magnitude by the partial melting hypothesis, we measured conductivity of partially molten peridotite analogue under shear conditions. The measured samples were mixtures of forsterite and chemically simplified basalt. The samples were pre- synthesized using a piston-cylinder apparatus at 1600 K and 2 GPa to obtain textural equilibrium. The pre- synthesized samples were formed to a disk with 3 mm in diameter and 1 mm in thickness. Conductivity measurement was carried out also at 1600 K and 2 GPa in a cubic-anvil apparatus with an additional uniaxial piston. The sample was sandwiched by two alumina pistons whose top was cut to 45 degree slope to generate shear. The shear strain rates of the sample were calibrated using a Mo strain marker in separate runs. The lower alumina piston was pushed by a tungsten carbide piston embedded in a bottom anvil with a constant speed. Conductivity was measured in the directions normal and parallel to the shear direction simultaneously. We mainly studied the sample with 1.6 volume percent of basaltic component. The shear strain rates were 0, 1.2x10(-6) and 5.2x10(-6) /s. The sample without shear did not show conductivity anisotropy. In contrast, the samples with shear showed one order of magnitude higher conductivity in the direction parallel to the shear than that normal to the shear. After the total strains reached 0.3, the magnitude of anisotropy became almost constant for both of the strain rates. The magnitude is thus independent of the strain rate. This study demonstrates that the anisotropy at the top of the asthenosphere can be explained based on the partially molten asthenosphere sheared by the plate motion.

Effects of local field and inherent strain in reflectance anisotropy spectra of A{sup III}B{sup V} semiconductors with naturally oxidized surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berkovits, V. L.; Kosobukin, V. A.; Gordeeva, A. B.

2015-12-28

Reflectance anisotropy (RA) spectra of naturally oxidized (001) surfaces of GaAs and InAs crystals are measured for photon energies from 1.5 up to 5.5 eV. The differential high-accuracy RA spectra reveal features substantially different from those caused by either a reconstruction of clean surface or a built-in near-surface electric field. Models of atomic structure with anisotropic transition layers of excess arsenic atoms specific for GaAs(001)/oxide and InAs(001)/oxide interfaces are proposed. In conformity with these models, a general theory of reflectance anisotropy is developed for semiconductor/oxide interfaces within the Green's function technique. The theory takes into account the combined effect of localmore » field due to interface dipoles and of intrinsic near-surface strain of the crystal. Measured RA spectra are analyzed in the model of valence-bond dipoles occupying a rectangular lattice in a multilayer medium. Comparing the measured and calculated spectra, we conclude that RA spectra of oxidized GaAs(001) and InAs(001) surfaces are simultaneously influenced by interface and near-surface anisotropies. The former is responsible for the broad-band spectral features which are associated with polarizability of the valence bonds attached to As atoms at the crystal/oxide interface. The near-surface anisotropy is due to inherent uniaxial straining the near-surface region of crystal. The effect of strain on RA spectra is experimentally and theoretically substantiated for GaAs crystal wafers undergone a uniaxial applied stress. Basically, this work results in the following. It establishes the physical nature of different levels of RA spectra observed in a majority of papers, but never analyzed. It demonstrates how the studied features of RA spectra could be applied for optical characterization of strained interfaces and atomic layers.« less

Effects of local field and inherent strain in reflectance anisotropy spectra of AIIIBV semiconductors with naturally oxidized surfaces

NASA Astrophysics Data System (ADS)

Berkovits, V. L.; Kosobukin, V. A.; Gordeeva, A. B.

2015-12-01

Reflectance anisotropy (RA) spectra of naturally oxidized (001) surfaces of GaAs and InAs crystals are measured for photon energies from 1.5 up to 5.5 eV. The differential high-accuracy RA spectra reveal features substantially different from those caused by either a reconstruction of clean surface or a built-in near-surface electric field. Models of atomic structure with anisotropic transition layers of excess arsenic atoms specific for GaAs(001)/oxide and InAs(001)/oxide interfaces are proposed. In conformity with these models, a general theory of reflectance anisotropy is developed for semiconductor/oxide interfaces within the Green's function technique. The theory takes into account the combined effect of local field due to interface dipoles and of intrinsic near-surface strain of the crystal. Measured RA spectra are analyzed in the model of valence-bond dipoles occupying a rectangular lattice in a multilayer medium. Comparing the measured and calculated spectra, we conclude that RA spectra of oxidized GaAs(001) and InAs(001) surfaces are simultaneously influenced by interface and near-surface anisotropies. The former is responsible for the broad-band spectral features which are associated with polarizability of the valence bonds attached to As atoms at the crystal/oxide interface. The near-surface anisotropy is due to inherent uniaxial straining the near-surface region of crystal. The effect of strain on RA spectra is experimentally and theoretically substantiated for GaAs crystal wafers undergone a uniaxial applied stress. Basically, this work results in the following. It establishes the physical nature of different levels of RA spectra observed in a majority of papers, but never analyzed. It demonstrates how the studied features of RA spectra could be applied for optical characterization of strained interfaces and atomic layers.

Thermoelastic-plastic flow equations in general coordinates

DOE PAGES

Blaschke, Daniel N.; Preston, Dean L.

2018-03-28

The equations governing the thermoelastic-plastic flow of isotropic solids in the Prandtl- Reuss and small anisotropy approximations in Cartesian coordinates are generalized to arbitrary coordinate systems. In applications the choice of coordinates is dictated by the symmetry of the solid flow. The generally invariant equations are evaluated in spherical, cylindrical (including uniaxial), and both prolate and oblate spheroidal coordinates.

Thermoelastic-plastic flow equations in general coordinates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blaschke, Daniel N.; Preston, Dean L.

The equations governing the thermoelastic-plastic flow of isotropic solids in the Prandtl- Reuss and small anisotropy approximations in Cartesian coordinates are generalized to arbitrary coordinate systems. In applications the choice of coordinates is dictated by the symmetry of the solid flow. The generally invariant equations are evaluated in spherical, cylindrical (including uniaxial), and both prolate and oblate spheroidal coordinates.

Nonminimal Einstein-Yang-Mills-Higgs theory: Associated, color, and color-acoustic metrics for the Wu-Yang monopole model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balakin, A. B.; Zayats, A. E.; Dehnen, H.

2007-12-15

We discuss a nonminimal Einstein-Yang-Mills-Higgs model with uniaxial anisotropy in the group space associated with the Higgs field. We apply this theory to the problem of propagation of color and color-acoustic waves in the gravitational background related to the nonminimal regular Wu-Yang monopole.

Effect of a quartic anisotropy energy on the ''spiral magnetic'' coexistence state of superconductivity and ferromagnetism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rose, G.H.; Hu, C.

1988-02-01

The effect of three types of ''quartic'' anisotropy energy (i.e., in the M/sup 4/ term of the magnetic Ginzburg-Landau free energy) on the polarization of the ''spiral magnetic'' state of Blount and Varma is studied near the onset temperature. For a quartic anisotropy with uniaxial symmetry, we find continuous polarization transitions from circular to elliptical and then to linear as the strength of a uni-easy-axis anisotropy is increased. (No transition is found for the uni-hard-axis case.) If the quartic anisotropy has cubic symmetry, we find a discontinuous transition directly between circular and linear, without going through an elliptic stage, whenmore » the sign of the anisotropy energy is to favor the cubic axes. (The polarization stays circular at all strengths of the anisotropy energy if the sign of the latter is to favor the body diagonals.) Finally, we model the anisotropy in primitive tetragonal ErRh/sub 4/B/sub 4/ with a quadratic anisotropy giving a hard c axis, plus a quartic anisotropy in the basal plane with a square symmetry. A first-order polarization transition directly between circular and linear is also obtained for this case, when the quartic anisotropy favors the principal axes in the basal plane. This last case studied provides a plausible explanation for the linear polarization observed in the coexistence state of ErRh/sub 4/B/sub 4/. .AE« less

Intrinsic magnetic properties of L10 FeNi obtained from meteorite NWA 6259

NASA Astrophysics Data System (ADS)

Poirier, Eric; Pinkerton, Frederick E.; Kubic, Robert; Mishra, Raja K.; Bordeaux, Nina; Mubarok, Arif; Lewis, Laura H.; Goldstein, Joseph I.; Skomski, Ralph; Barmak, Katayun

2015-05-01

FeNi having the tetragonal L10 crystal structure is a promising new rare-earth-free permanent magnet material. Laboratory synthesis is challenging, however, tetragonal L10 FeNi—the mineral "tetrataenite"—has been characterized using specimens found in nickel-iron meteorites. Most notably, the meteorite NWA 6259 recovered from Northwest Africa is 95 vol. % tetrataenite with a composition of 43 at. % Ni. Hysteresis loops were measured as a function of sample orientation on a specimen cut from NWA 6259 in order to rigorously deduce the intrinsic hard magnetic properties of its L10 phase. Electron backscatter diffraction showed that NWA 6259 is strongly textured, containing L10 grains oriented along any one of the three equivalent cubic directions of the parent fcc structure. The magnetic structure was modeled as a superposition of the three orthonormal uniaxial variants. By simultaneously fitting first-quadrant magnetization data for 13 different orientations of the sample with respect to the applied field direction, the intrinsic magnetic properties were estimated to be saturation magnetization 4πMs = 14.7 kG and anisotropy field Ha = 14.4 kOe. The anisotropy constant K = 0.84 MJ/m3 is somewhat smaller than the value K = 1.3 MJ/m3 obtained by earlier researchers from nominally equiatomic FeNi prepared by neutron irradiation accompanied by annealing in a magnetic field, suggesting that higher Ni content (fewer Fe antisite defects) may improve the anisotropy. The fit also indicated that NWA 6259 contains one dominant variant (62% by volume), the remainder of the sample being a second variant, and the third variant being absent altogether.

Intrinsic magnetic properties of L1(0) FeNi obtained from meteorite NWA 6259

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poirier, E; Pinkerton, FE; Kubic, R

2015-05-07

FeNi having the tetragonal L1(0) crystal structure is a promising new rare-earth-free permanent magnet material. Laboratory synthesis is challenging, however, tetragonal L1(0) FeNi-the mineral "tetrataenite"-has been characterized using specimens found in nickel-iron meteorites. Most notably, the meteorite NWA 6259 recovered from Northwest Africa is 95 vol.% tetrataenite with a composition of 43 at.% Ni. Hysteresis loops were measured as a function of sample orientation on a specimen cut from NWA 6259 in order to rigorously deduce the intrinsic hard magnetic properties of its L1(0) phase. Electron backscatter diffraction showed that NWA 6259 is strongly textured, containing L1(0) grains oriented alongmore » any one of the three equivalent cubic directions of the parent fcc structure. The magnetic structure was modeled as a superposition of the three orthonormal uniaxial variants. By simultaneously fitting first-quadrant magnetization data for 13 different orientations of the sample with respect to the applied field direction, the intrinsic magnetic properties were estimated to be saturation magnetization 4 pi M-s = 14.7 kG and anisotropy field H-a = 14.4 kOe. The anisotropy constant K = 0.84 MJ/m(3) is somewhat smaller than the value K = 1.3 MJ/m(3) obtained by earlier researchers from nominally equiatomic FeNi prepared by neutron irradiation accompanied by annealing in a magnetic field, suggesting that higher Ni content (fewer Fe antisite defects) may improve the anisotropy. The fit also indicated that NWA 6259 contains one dominant variant (62% by volume), the remainder of the sample being a second variant, and the third variant being absent altogether. (C) 2015 AIP Publishing LLC.« less

Generalized Reliability Methodology Applied to Brittle Anisotropic Single Crystals. Degree awarded by Washington Univ., 1999

NASA Technical Reports Server (NTRS)

Salem, Jonathan A.

2002-01-01

A generalized reliability model was developed for use in the design of structural components made from brittle, homogeneous anisotropic materials such as single crystals. The model is based on the Weibull distribution and incorporates a variable strength distribution and any equivalent stress failure criteria. In addition to the reliability model, an energy based failure criterion for elastically anisotropic materials was formulated. The model is different from typical Weibull-based models in that it accounts for strength anisotropy arising from fracture toughness anisotropy and thereby allows for strength and reliability predictions of brittle, anisotropic single crystals subjected to multiaxial stresses. The model is also applicable to elastically isotropic materials exhibiting strength anisotropy due to an anisotropic distribution of flaws. In order to develop and experimentally verify the model, the uniaxial and biaxial strengths of a single crystal nickel aluminide were measured. The uniaxial strengths of the <100> and <110> crystal directions were measured in three and four-point flexure. The biaxial strength was measured by subjecting <100> plates to a uniform pressure in a test apparatus that was developed and experimentally verified. The biaxial strengths of the single crystal plates were estimated by extending and verifying the displacement solution for a circular, anisotropic plate to the case of a variable radius and thickness. The best correlation between the experimental strength data and the model predictions occurred when an anisotropic stress analysis was combined with the normal stress criterion and the strength parameters associated with the <110> crystal direction.

Pentacoordinate and Hexacoordinate Mn(III) Complexes of Tetradentate Schiff-Base Ligands Containing Tetracyanidoplatinate(II) Bridges and Revealing Uniaxial Magnetic Anisotropy.

PubMed

Nemec, Ivan; Herchel, Radovan; Trávníček, Zdeněk

2016-12-08

Crystal structures and magnetic properties of polymeric and trinuclear heterobimetallic Mn III ···Pt II ···Mn III coordination compounds, prepared from the Ba[Pt(CN)₄] and [Mn(L4A/B)(Cl)] ( 1a / b ) precursor complexes, are reported. The polymeric complex [{Mn(L4A)}₂{μ⁴-Pt(CN)₄}] n ( 2a ), where H₂L4A = N , N '-ethylene-bis(salicylideneiminate), comprises the {Mn(L4A)} moieties covalently connected through the [Pt(CN)₄] 2- bridges, thus forming a square-grid polymeric structure with the hexacoordinate Mn III atoms. The trinuclear complex [{Mn(L4B)}₂{μ-Pt(CN)₄}] ( 2b ), where H₂L4B = N , N '-benzene-bis(4-aminodiethylene-salicylideneiminate), consists of two [{Mn(L4B)} moieties, involving pentacoordinate Mn III atoms, bridged through the tetracyanidoplatinate (II) bridges to which they are coordinated in a trans fashion. Both complexes possess uniaxial type of magnetic anisotropy, with D (the axial parameter of zero-field splitting) = -3.7(1) in 2a and -2.2(1) cm -1 in 2b . Furthermore, the parameters of magnetic anisotropy 2a and 2b were also thoroughly studied by theoretical complete active space self-consistent field (CASSCF) methods, which revealed that the former is much more sensitive to the ligand field strength of the axial ligands.

Magnetic properties and structure of low temperature phase MnBi with island structure

NASA Astrophysics Data System (ADS)

Ito, Masashi; Tanaka, Yoshitomo; Satoh, Takuya; Mankey, Gary; Schad, Rainer; Suzuki, Takao

2017-05-01

The magnetic properties of the low temperature phase (LTP) MnBi thin films of islands structure are discussed. The LTP MnBi islands are formed onto silica substrates after the multilayers Bi(3.2nm)/Mn(2nm)x N are deposited and then annealed at 450C for 0.5hr, where N is the number of the repetition of a pair of Mn and Bi layer. Those islands are found to be of the LTP MnBi, with the c-axis orientation along the normal to the sample plane for N=10 ˜ 40. Their size vary from place to place, but are averagely of about a few hundred nm in height and a few μm in width for N from 10 to 40. For N=200, the elongated islands are formed densely, with the length of about a few tens of μm. The coverage of those islands increases with N. The temperature dependence of saturation magnetization Ms is qualitatively similar to that for bulk, though the absolute values for Ms are smaller by 20%. The magnetic anisotropy constants of Ku1 and Ku2 are evaluated for the samples with N=10 ˜ 40, where Ku1 and Ku2 are the magnetic anisotropy constants corresponding to the second and fourth power term in the uniaxial magnetic anisotropy energy expression. It is found that the Ku1 increases with T monotonously, reaching to about 1x107 erg/cc at 400K. On the other hand, the Ku2 remains nearly zero for temperatures below 300K, and then becomes negative, reaching to about 7 x 106 erg/cc at 400K. This is the first to report of the temperature dependence of Ku1 and Ku2 in the LTP MnBi of an island structure. It is also noted that the decrease of Ku for a temperature range beyond around 450 K is possibly due to the decrease of the Ku2 component, as demonstrated in the present study.

Effect of Evolutionary Anisotropy on Earing Prediction in Cylindrical Cup Drawing

NASA Astrophysics Data System (ADS)

Choi, H. J.; Lee, K. J.; Choi, Y.; Bae, G.; Ahn, D.-C.; Lee, M.-G.

2017-05-01

The formability of sheet metals is associated with their planar anisotropy, and finite element simulations have been applied to the sheet metal-forming process by describing the anisotropic behaviors using yield functions and hardening models. In this study, the evaluation of anisotropic constitutive models was performed based on the non-uniform height profile or earing in circular cylindrical cup drawing. Two yield functions, a quadratic Hill1948 and a non-quadratic Yld2000-2d model, were used under non-associated and associated flow rules, respectively, to simultaneously capture directional differences in yield stress and r value. The effect of the evolution of anisotropy on the earing prediction was also investigated by employing simplified equivalent plastic strain rate-dependent anisotropic coefficients. The computational results were in good agreement with experiments when the proper choice of the yield function and flow rule, which predicts the planar anisotropy, was made. Moreover, the accuracy of the earing profile could be significantly enhanced if the evolution of anisotropy between uniaxial and biaxial stress states was additionally considered.

Dual-mode ferromagnetic resonance in an FeCoB/Ru/FeCoB synthetic antiferromagnet with uniaxial anisotropy

NASA Astrophysics Data System (ADS)

Wang, Cuiling; Zhang, Shouheng; Qiao, Shizhu; Du, Honglei; Liu, Xiaomin; Sun, Ruicong; Chu, Xian-Ming; Miao, Guo-Xing; Dai, Youyong; Kang, Shishou; Yan, Shishen; Li, Shandong

2018-05-01

Dual-mode ferromagnetic resonance is observed in FeCoB/Ru/FeCoB trilayer synthetic antiferromagnets with uniaxial in-plane magnetic anisotropy. The optical mode is present in the (0-108 Oe) magnetic field range, where the top and bottom layer magnetizations are aligned in opposite directions. The strong acoustic mode appears, when the magnetic field exceeds the 300 Oe value, which corresponds to the flop transition in the trilayer. Magnetic field and angular dependences of resonant frequencies are studied for both optical (low-field) and acoustic (high field) modes. The low-field mode is found to be anisotropic but insensitive to the magnetic field value. In contrast, the high field mode is quasi-isotropic, but its resonant frequency is tunable by the value of the magnetic field. The coexistence of two modes of ferromagnetic resonance as well as switching between them with the increase in the magnetic field originates from the difference in the sign of interlayer coupling energy at the parallel and antiparallel configurations of the synthetic antiferromagnet. The dual-mode resonance in the studied trilayer structures provides greater flexibility in the design and functionalization of micro-inductors in monolithic microwave integrated circuits.

Ultra-high resistive and anisotropic CoPd-CaF2 nanogranular soft magnetic films prepared by tandem-sputtering deposition

NASA Astrophysics Data System (ADS)

Naoe, Masayuki; Kobayashi, Nobukiyo; Ohnuma, Shigehiro; Iwasa, Tadayoshi; Arai, Ken-Ichi; Masumoto, Hiroshi

2015-10-01

Ultra-high resistive and anisotropic soft magnetic films for gigahertz applications are desirable to demonstrate the really practical films. Here we present a study of novel nanogranular films fabricated by tandem-sputtering deposition. Their electromagnetic properties and nanostructure have also been discussed. These films consisted of nanocrystallized CoPd alloy-granules and CaF2 matrix, and a specimen having a composition of (Co0.69Pd0.31)52-(Ca0.31F0.69)48 exhibited distinct in-plane uniaxial anisotropy after uniaxial field annealing with granule growth. Its complex permeability spectra have a ferromagnetic resonance frequency extending to the Super-High-Frequency band due to its higher anisotropy field, and its frequency response was quite well reproduced by a numerical calculation based on the Landau-Lifshitz-Gilbert equation. Furthermore, it was clarified that the CaF2-based nanogranular film exhibits a hundredfold higher electrical resistivity than conventional oxide or nitride-based films. Higher resistivity enables the film thickness to achieve a margin exceeding threefold against eddy current loss. The greater resistivity of nanogranular films is attributed to the wide energy bandgap and superior crystallinity of CaF2 matrix.

Effect of equatorial line nodes on the upper critical field and London penetration depth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kogan, V G; Prozorov, R

2014-09-01

The upper critical field Hc2 and its anisotropy are calculated for order parameters with line nodes at the equators, kz=0, of the Fermi surface of uniaxial superconductors. It is shown that characteristic features found in Fe-based materials (a nearly linear Hc2(T) in a broad T domain, a low and increasing on warming anisotropy γH=Hc2,ab/Hc2,c) can be caused by competing effects of the equatorial nodes and of the Fermi surface anisotropy. For certain material parameters, γH(T)-1 may change sign upon warming, in agreement with the recorded behavior of FeTeS systems. It is also shown that the anisotropy of the penetration depthmore » γλ=λc/λab decreases upon warming to reach γH at Tc, in agreement with data available. For some materials γλ(T) may change upon warming, from γλ>1 at low Ts to γλ<1 at high Ts.« less

Thickness dependence of the magnetic anisotropy and dynamic magnetic response of ferromagnetic NiFe films

NASA Astrophysics Data System (ADS)

Silva, E. F.; Corrêa, M. A.; Della Pace, R. D.; Plá Cid, C. C.; Kern, P. R.; Carara, M.; Chesman, C.; Alves Santos, O.; Rodríguez-Suárez, R. L.; Azevedo, A.; Rezende, S. M.; Bohn, F.

2017-05-01

We investigate the thickness dependence of the magnetic anisotropy and dynamic magnetic response of ferromagnetic NiFe films. We go beyond quasi-static measurements and focus on the dynamic magnetic response by considering three complementary techniques: the ferromagnetic resonance, magnetoimpedance and magnetic permeability measurements. We verify remarkable modifications in the magnetic anisotropy, i.e. the well-known behavior of in-plane uniaxial magnetic anisotropy systems gives place to a complex magnetic behavior as the thickness increases, and splits the films in two groups according to the magnetic properties. We identify magnetoimpedance and magnetic permeability curves with multiple resonance peaks, as well as the evolution of the ferromagnetic resonance absorption spectra, as fingerprints of strong changes of the magnetic properties associated to the vanishing of the in-plane magnetic anisotropy and to the emergence of non-homogeneous magnetization configuration, local anisotropies and out-of-plane anisotropy contribution arisen as a consequence of the non-uniformities of the stress stored in the film as the thickness is increased and/or to the columnar growth of the film. We interpret the experimental results in terms of the structural and morphological properties, quasi-static magnetic behavior, magnetic domain structure and different mechanisms governing the magnetization dynamics at distinct frequency ranges.

Anisotropy and applied-field effects on the spiral magnetic coexistence state of ferromagnetic superconductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rose, G.H.

1988-01-01

The effect of three types of quartic anisotropy energy on the polarization of the spiral-magnetic state of Blount and Varma is studied near the onset temperature. A quartic anisotropy with uniaxial symmetry and a quartic anisotropy with cubic symmetry are studied, and the anisotropy in primitive tetragonal ErRh{sub 4}B{sub 4} is modeled with a quadratic anisotropy giving a hard c-axis, plus a quartic anisotropy in the basal plane with a square symmetry. Details of the magnetizations, wave vectors, and polarizations are presented. Further, using a variational approach, the author investigates the effects, in a slab geometry, of an infinitesimal andmore » finite magnetic field applied parallel to the slab on the spiral magnetic state. By additionally calculating the effects on the normal ferroparamagnetic state and the uniform superconducting state, he studies applied field vs. temperature phase diagrams. Due to the large experimental uncertainty in the material parameters, an extended range of values is studied, producing a number of interesting and physically unique phase diagrams. A categorization of the types of phase diagrams over the selected range of the material parameters is presented. Finally, the effective superconducting penetration depth in the presence of the spiral magnetic state is calculated.« less

Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory

DOE PAGES

Johnston, David C.

2017-03-17

Here, the influence of uniaxial single-ion anisotropy –DS 2 z on the magnetic and thermal properties of Heisenberg antiferromagnets (AFMs) is investigated. The uniaxial anisotropy is treated exactly and the Heisenberg interactions are treated within unified molecular field theory (MFT), where thermodynamic variables are expressed in terms of directly measurable parameters. The properties of collinear AFMs with ordering along the z axis (D>0) in applied field H z = 0 are calculated versus D and temperature T, including the ordered moment μ, the Néel temperature T N, the magnetic entropy, internal energy, heat capacity, and the anisotropic magnetic susceptibilities χmore » ∥ and χ ⊥ in the paramagnetic (PM) and AFM states. The high-field average magnetization per spin μ z(H z,D,T) is found, and the critical field H c(D,T) is derived at which the second-order AFM to PM phase transition occurs. The magnetic properties of the spin-flop (SF) phase are calculated, including the zero-field properties T N(D) and μ(D,T). The high-field μ z(H z,D,T) is determined, together with the associated spin-flop field H SF(D,T) at which a second-order SF to PM phase transition occurs. The free energies of the AFM, SF, and PM phases are derived from which H z–T phase diagrams are constructed. For f J =–1 and –0.75, where f J = θ pJ/T NJ and θ pJ and T NJ are the Weiss temperature in the Curie-Weiss law and the Néel temperature due to exchange interactions alone, respectively, phase diagrams in the H z–T plane similar to previous results are obtained. However, for f J = 0 we find a topologically different phase diagram where a spin-flop bubble with PM and AFM boundaries occurs at finite H z and T. Also calculated are properties arising from a perpendicular magnetic field, including the perpendicular susceptibility χ ⊥(D,T), the associated effective torque at low fields arising from the –DS 2 z term in the Hamiltonian, the high-field perpendicular magnetization μ ⊥, and the perpendicular critical field H c⊥ at which the second-order AFM to PM phase transition occurs. In addition to the above results for D > 0, the T N(D) and ordered moment μ(T,D) for collinear AFM ordering along the x axis with D < 0 are determined. In order to compare the properties of the above spin systems with those of noninteracting systems with –DS 2 z uniaxial anisotropy with either sign of D, Supplemental Material is provided in which results for the thermal and magnetic properties of such noninteracting spin systems are given.« less

Some Recent Developments in the Endochronic Theory with Application to Cyclic Histories

NASA Technical Reports Server (NTRS)

Valanis, K. C.; Lee, C. F.

1983-01-01

Constitutive equations with only two easily determined material constants predict the stress (strain) response of normalized mild steel to a variety of general strain (stress) histories, without a need for special unloading-reloading rules. The equations are derived from the endochronic theory of plasticity of isotropic materials with an intrinsic time scale defined in the plastic strain space. Agreement between theoretical predictions and experiments are are excellent quantitatively in cases of various uniaxial constant amplitude histories, variable uniaxial strain amplitude histories and cyclic relaxation. The cyclic ratcheting phenomenon is predicted by the present theory.

On the Kolmogorov constant in stochastic turbulence models

NASA Astrophysics Data System (ADS)

Heinz, Stefan

2002-11-01

The Kolmogorov constant is fundamental in stochastic models of turbulence. To explain the reasons for observed variations of this quantity, it is calculated for two flows by various methods and data. Velocity fluctuations are considered as the sum of contributions due to anisotropy, acceleration fluctuations and stochastic forcing that is controlled by the Kolmogorov constant. It is shown that the effects of anisotropy and acceleration fluctuations are responsible for significant variations of the Kolmogorov constant. It is found near 2 for flows where anisotropy and acceleration fluctuations contribute to the energy budget, and near 6 if such contributions disappear.

High-Performance Digital Imaging System for Development and Characterization of Novel Materials and Processes

DTIC Science & Technology

2006-08-08

taking into account the effects of polycrystalline microstructures, elastic anisotropy of the crystals, and material damages due to microplasticity and...anisotropic crystal elasticity, intragranular microplasticity and intergranular microfracture have been developed and implemented into the ABAQUS codes...Zhang, K. S., Wu, M. S., and Feng, R. (2005). Simulation of microplasticity -induced deformation in uniaxially strained ceramics by 3-D Voronoi

Thermal stability of bubble domains in ferromagnetic discs

NASA Astrophysics Data System (ADS)

Hrkac, G.; Bance, S.; Goncharov, A.; Schrefl, T.; Suess, D.

2007-05-01

The transition and thermal stability of disc-shaped ferromagnetic particles at the temperature of T = 300 K with a uniaxial anisotropy along the symmetry axis from a bi-domain to a single domain state has been studied. The nudge elastic band method was used to map the energy landscape and to calculate the energy barrier between the transition states. For single FePt disc-shaped particles with perpendicular anisotropy three transition configurations have been found: single domain, stripe- and stable bubble domains at zero applied field. The single domain configuration along the positive anisotropy axis is reached by an annihilation process of the domain wall and the all-down state by a complex domain expansion process. Magnetization configurations in two interacting discs show an increase in thermal stability compared with single disc systems, which is attributed to the interacting magnetostatic energy between the two particles.

Luminescent hyperbolic metasurfaces

NASA Astrophysics Data System (ADS)

Smalley, J. S. T.; Vallini, F.; Montoya, S. A.; Ferrari, L.; Shahin, S.; Riley, C. T.; Kanté, B.; Fullerton, E. E.; Liu, Z.; Fainman, Y.

2017-01-01

When engineered on scales much smaller than the operating wavelength, metal-semiconductor nanostructures exhibit properties unobtainable in nature. Namely, a uniaxial optical metamaterial described by a hyperbolic dispersion relation can simultaneously behave as a reflective metal and an absorptive or emissive semiconductor for electromagnetic waves with orthogonal linear polarization states. Using an unconventional multilayer architecture, we demonstrate luminescent hyperbolic metasurfaces, wherein distributed semiconducting quantum wells display extreme absorption and emission polarization anisotropy. Through normally incident micro-photoluminescence measurements, we observe absorption anisotropies greater than a factor of 10 and degree-of-linear polarization of emission >0.9. We observe the modification of emission spectra and, by incorporating wavelength-scale gratings, show a controlled reduction of polarization anisotropy. We verify hyperbolic dispersion with numerical simulations that model the metasurface as a composite nanoscale structure and according to the effective medium approximation. Finally, we experimentally demonstrate >350% emission intensity enhancement relative to the bare semiconducting quantum wells.

In-plane magnetic anisotropy and coercive field dependence upon thickness of CoFeB

NASA Astrophysics Data System (ADS)

Kipgen, Lalminthang; Fulara, Himanshu; Raju, M.; Chaudhary, Sujeet

2012-09-01

The structural and magnetic properties of as-grown 5-50 nm thin ion-beam sputter deposited transition metal-metalloid Co20Fe60B20 (CFB) films are reported in this communication. A broad peak observed at 2θ∼45° in the glancing angle X-ray diffraction pattern revealed the formation of very fine nano-sized grains embedded in majority amorphous CFB matrix. Although no magnetic field is applied during deposition, the longitudinal magneto-optic Kerr effect measurements performed at 300 K in these as-grown films clearly established the presence of in-plane uniaxial magnetic anisotropy (Ku). It is argued that this observed anisotropy is strain-induced. This is supported by the observed dependence of direction of Ku on the angle between applied magnetic field and crystallographic orientation of the underlying Si(100) substrate, and increase in the coercivity with the increase of the film thickness.

Magnetic Anisotropy and Chemical Order of Artificially Synthesized L10-Ordered FeNi Films on Au-Cu-Ni Buffer Layers

NASA Astrophysics Data System (ADS)

Kojima, Takayuki; Mizuguchi, Masaki; Koganezawa, Tomoyuki; Osaka, Keiichi; Kotsugi, Masato; Takanashi, Koki

2012-01-01

L10-FeNi films were grown by alternate monatomic layer deposition on Au-Cu-Ni buffer layers at several substrate temperatures (Ts), and the relation between the uniaxial magnetic anisotropy energy (Ku) and the long-range chemical order parameter (S) was investigated. A large Ku of (7.0 ±0.2) ×106 erg/cm3 and S of 0.48 ±0.05 were obtained. The value of Ku was larger than those reported previously for artificially synthesized FeNi films. It was first found that both Ku and S increased with Ts, and Ku was roughly proportional to S.

Nonlinear susceptibility and dynamic hysteresis loops of magnetic nanoparticles with biaxial anisotropy

NASA Astrophysics Data System (ADS)

Ouari, Bachir; Titov, Serguey V.; El Mrabti, Halim; Kalmykov, Yuri P.

2013-02-01

The nonlinear ac susceptibility and dynamic magnetic hysteresis (DMH) of a single domain ferromagnetic particle with biaxial anisotropy subjected to both external ac and dc fields of arbitrary strength and orientation are treated via Brown's continuous diffusions model [W. F. Brown, Jr., Phys. Rev. 130, 1677 (1963)] of magnetization orientations. The DMH loops and nonlinear ac susceptibility strongly depend on the dc and ac field strengths, the polar angle between the easy axis of the particle, the external field vectors, temperature, and damping. In contrast to uniaxial particles, the nonlinear ac stationary response and DMH strongly depend on the azimuthal direction of the ac field and the biaxiality parameter Δ.

Measurements of Hk and Ms in thin magnetic films by the angular dependence of the planar Hall effect

NASA Astrophysics Data System (ADS)

Vatskicheva, M.; Vatskichev, L.

1987-11-01

It is shown that the angular dependences of the planar Hall effect measured with infinite magnetic field and with magnetic field H⩾ Hk have an intersection point and this fact is enough for measuring the anisotropy field Hk applying the method presented by Pastor, Ferreiro and Torres in J. Magn. Magn. Mat. 53 (1986) 349, 62 (1986) 101. The scaling of the Hall tension U proportional to M2s in mV/Am -1 gives a possibility for calculating the Ms-values of the films. These assumptions are verified for NiFe- and NiFeGe films with a uniaxial magnetic anisotropy.

Buckling of Fiber Reinforced Composite Plates with Nanofiber Reinforced Matrices

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Murthy, Pappu L. N.

2010-01-01

Anisotropic composite plates were evaluated with nanofiber reinforced matrices (NFRM). The nanofiber reinforcement volumes ratio in the matrix was 0.01. The plate dimensions were 20 by 10 by 1.0 in. (508 by 254 by 25.4 mm). Seven different loading condition cases were evaluated: three for uniaxial loading, three for pairs of combined loading, and one with three combined loadings. The anisotropy arose from the unidirectional plates having been at 30 from the structural axis. The anisotropy had a full 6 by 6 rigidities matrix which were satisfied and solved by a Galerkin buckling algorithm. The buckling results showed that the NFRM plates buckled at about twice those with conventional matrix.

Structural phase transition of gold under uniaxial, tensile, and triaxial stresses: An ab initio study

NASA Astrophysics Data System (ADS)

Durandurdu, Murat

2007-07-01

The behavior of gold crystal under uniaxial, tensile, and three different triaxial stresses is studied using an ab initio constant pressure technique within a generalized gradient approximation. Gold undergoes a phase transformation from the face-centered-cubic structure (fcc) to a body-centered-tetragonal (bct) structure having the space group of I4/mmm with the application of uniaxial stress, while it transforms to a face-centered-tetragonal (fct) phase within I4/mmm symmetry under uniaxial tensile loading. Further uniaxial compression of the bct phase results in a symmetry change from I4/mmm to P1 at high stresses and ultimately structural failure around 200.0GPa . For the case of triaxial stresses, gold also converts into a bct state. The critical stress for the fcc-to-bct transformation increases as the ratio of the triaxial stress increases. Both fct and bct phases are elastically unstable.

Numerical analysis and experimental verification of elastomer bending process with different material models

NASA Astrophysics Data System (ADS)

Kut, Stanislaw; Ryzinska, Grazyna; Niedzialek, Bernadetta

2016-01-01

The article presents the results of tests in order to verifying the effectiveness of the nine selected elastomeric material models (Neo-Hookean, Mooney with two and three constants, Signorini, Yeoh, Ogden, Arruda-Boyce, Gent and Marlow), which the material constants were determined in one material test - the uniaxial tension testing. The convergence assessment of nine analyzed models were made on the basis of their performance from an experimental bending test of the elastomer samples from the results of numerical calculations FEM for each material models. To calculate the material constants for the analyzed materials, a model has been generated by the stressstrain characteristics created as a result of experimental uniaxial tensile test with elastomeric dumbbell samples, taking into account the parameters received in its 18th cycle. Using such a calculated material constants numerical simulation of the bending process of a elastomeric, parallelepipedic sampleswere carried out using MARC / Mentat program.

Fabric controls on the brittle failure of folded gneiss and schist

NASA Astrophysics Data System (ADS)

Agliardi, Federico; Zanchetta, Stefano; Crosta, Giovanni B.

2014-12-01

We experimentally studied the brittle failure behaviour of folded gneiss and schist. Rock fabric and petrography were characterised by meso-structural analyses, optical microscopy, X-ray diffraction, and SEM imaging. Uniaxial compression, triaxial compression and indirect tension laboratory tests were performed to characterise their strength and stress-strain behaviour. Fracture patterns generated in compression were resolved in 3D through X-ray computed tomography at different resolutions (30 to 625 μm). Uniaxial compression tests revealed relatively low and scattered values of unconfined compressive strength (UCS) and Young's modulus, with no obvious relationships with the orientation of foliation. Samples systematically failed in four brittle modes, involving different combinations of shear fractures along foliation or parallel to fold axial planes, or the development of cm-scale shear zones. Fracture quantification and microstructural analysis show that different failure modes occur depending on the mutual geometrical arrangement and degree of involvement of two distinct physical anisotropies, i.e. the foliation and the fold axial planes. The Axial Plane Anisotropy (APA) is related to micro-scale grain size reduction and shape preferred orientation within quartz-rich domains, and to mechanical rotation or initial crenulation cleavage within phyllosilicate-rich domains at fold hinge zones. In quartz-rich rocks (gneiss), fracture propagation through quartz aggregates forming the APA corresponds to higher fracture energy and strength than found for fracture through phyllosilicate-rich domains. This results in a strong dependence of strength on the failure mode. Conversely, in phyllosilicate-rich rocks (schist), all the failure modes are dominated by the strength of phyllosilicates, resulting in a sharp reduction of strength anisotropy.

Empirical Measurements of Biomechanical Anisotropy of the Human Vocal Fold Lamina Propria

PubMed Central

Kelleher, Jordan E.; Siegmund, Thomas; Du, Mindy; Naseri, Elhum; Chan, Roger W.

2013-01-01

The vocal folds are known to be mechanically anisotropic due to the microstructural arrangement of fibrous proteins such as collagen and elastin in the lamina propria. Even though this has been known for many years, the biomechanical anisotropic properties have rarely been experimentally studied. We propose that an indentation procedure can be used with uniaxial tension in order to obtain an estimate of the biomechanical anisotropy within a single specimen. Experiments were performed on the lamina propria of three male and three female human vocal folds dissected from excised larynges. Two experiments were conducted: each specimen was subjected to cyclic uniaxial tensile loading in the longitudinal (i.e. anterior-posterior) direction, and then to cyclic indentation loading in the transverse (i.e. medial-lateral) direction. The indentation experiment was modeled as contact on a transversely isotropic half-space using the Barnett-Lothe tensors. The longitudinal elastic modulus EL was computed from the tensile test, and the transverse elastic modulus ET and longitudinal shear modulus GL were obtained by inverse analysis of the indentation force-displacement response. It was discovered that the average of EL/ET was 14 for the vocal ligament and 39 for the vocal fold cover specimens. Also, the average of EL/GL, a parameter important for models of phonation, was 28 for the vocal ligament and 54 for the vocal fold cover specimens. These measurements of anisotropy could contribute to more accurate models of fundamental frequency regulation and provide potentially better insights into the mechanics of vocal fold vibration. PMID:22886592

Unexpected Magnetic Domain Behavior in LTP-MnBi

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nguyen, PK; Jin, S; Berkowitz, AE

2013-07-01

Low-temperature-phase MnBi (LTP-MnBi) has attracted much interest as a potential rare-earth-free permanent magnet material because of its high uniaxial magnetocrystalline anisotropy at room temperature, K approximate to 10(7) ergs/cc, and the unusual increase of anisotropy with increasing temperature, with an accompanying increasing coercive force (H-C) with temperature. However, due to the complex Mn-Bi phase diagram, bulk samples of LTP-MnBi with the optimum saturation moment, similar to 75-76 emu/g have been achieved only with zone-refined single crystals. We have prepared polycrystalline samples of LTP-MnBi by induction melting and annealing at 300 degrees C. The moment in 70 kOe is 73.5 emu/g,more » but H-C is only 50 Oe. This is quite surprising-the high saturation moment indicates the dominating presence of LTP-MnBi. Therefore, an H-C c of some significant fraction of 2K/M-S approximate to 30 kOe would seem reasonable in this polycrystalline sample. By examining "Bitter" patterns, we show that the sample is composed of similar to 50 - 100 mu m crystallites. The randomly oriented crystallites exhibit the variety of magnetic domain structures and orientations expected from the hexagonal-structured MnBi with its strong uniaxial anisotropy. Clearly, the reversal of magnetization in the sample proceeds by the low-field nucleation of reversed magnetization in each crystallite, rather than by a wall-pinning mechanism. When the annealed sample was milled into fine particles, H-C increased by several orders of magnitude, as expected.« less

Random anisotropy model approach on ion beam sputtered Co 20Cu 80 granular alloy

NASA Astrophysics Data System (ADS)

Errahmani, H.; Hassanaı̈n, N.; Berrada, A.; Abid, M.; Lassri, H.; Schmerber, G.; Dinia, A.

2002-03-01

The Co 20Cu 80 granular film has been elaborated using ion beam sputtering technique. The magnetic properties of the sample were studied in the temperature range 5-300 K at H⩽50 kOe. From the thermomagnetisation curve, which is found to obey to the Bloch law, we have extracted the spin wave stiffness constant D and the exchange constant A. The magnetic experimental results have been interpreted in the framework of random anisotropy model. We have determined the local anisotropy constant KL and the local correlation length of anisotropy axis Ra, which is compared to the experimental grains size obtained by transmission electronic microscopy.

Structural characterization and magnetic properties of L10-MnAl films grown on different underlayers by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Takata, Fumiya; Gushi, Toshiki; Anzai, Akihito; Toko, Kaoru; Suemasu, Takashi

2018-03-01

We grow MnAl films on different underlayers by molecular beam epitaxy (MBE), and investigate their structural and magnetic properties. L10-ordered MnAl films were successfully grown both on an MgO(0 0 1) single-crystalline substrate and on an Mn4N(0 0 1) buffer layer formed on MgO(0 0 1) and SrTiO3(0 0 1) substrates. For the MgO substrate, post rapid thermal annealing (RTA) drastically improved the crystalline quality and the degree of L10-ordering, whereas no improvement in the crystallinity was achieved by altering the substrate temperature (TS) during MBE growth. However, high-quality L10-MnAl films were formed on the Mn4N buffer layer by simply varying TS. Structural analysis using X-ray diffraction showed MnAl on an MgO substrate had a cubic structure whereas MnAl on the Mn4N buffer had a tetragonal structure. This difference in crystal structure affected the magnetic properties of the MnAl films. The uniaxial magnetic anisotropy constant (Ku) was drastically improved by inserting an Mn4N buffer layer. We achieved a perpendicular magnetic anisotropy of Ku = 5.0 ± 0.7 Merg/cm3 for MnAl/Mn4N film on MgO and 6.0 ± 0.2 Merg/cm3 on STO. These results suggest that Mn4N has potential as an underlayer for L10-MnAl.

Effects of magnetic field and pressure in magnetoelastic stress reconfigurable thin film resonators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Staruch, M.; Bussmann, K.; Finkel, P.

2015-07-20

Free-standing CoFe thin-film doubly clamped stress reconfigurable resonators were investigated as a function of magnetic field and pressure. A large uniaxial anisotropy resulting from residual uniaxial tensile stress, as revealed from magnetic hysteresis loops, leads to an easy magnetization axis aligned along the length of the beams. The quality factor of the driven resonator beams under vacuum is increased by 30 times, leading to an enhanced signal-to-noise ratio and a predicted reduction in the intrinsic magnetic noise by a factor of 6, potentially reaching as low as ∼25 pT/√Hz at 1 Torr. Stress reconfigurable sensors operating under vacuum could thus furthermore » improve the limit of detection and advance development of magnetic field sensing technology.« less

Nematic-driven anisotropic electronic properties of underdoped detwinned Ba(Fe1-xCox)2As2 revealed by optical spectroscopy

NASA Astrophysics Data System (ADS)

Degiorgi, L.

2015-03-01

We collect optical reflectivity data as a function of temperature across the structural tetragonal-to-orthorhombic phase transition at Ts on Ba(Fe1-xCox)2As2 for x = 0, 2.5% and 4.5%, with uniaxial and in-situ tunable applied pressure in order to detwin the sample and to exert on it an external symmetry breaking field. At T =Ts . Moreover, the optical anisotropy gets progressively depleted with increasing Co-content in the underdoped regime, consistent with the doping dependence of the orthorhombicity but contrary to the non-monotonic behavior observed for the dc anisotropy. Our findings bear testimony for an important anisotropy of the electronic structure and thus underscore an electronic polarization upon (pressure) inducing and entering the nematic phase. Work in collaboration with: A. Dusza, C. Mirri, S. Bastelberger, A. Lucarelli (ETH Zurich) and J.H. Chu, H.H. Kuo, I.R. Fisher (Stanford University).

Ultra High Strain Rate Nanoindentation Testing.

PubMed

Sudharshan Phani, Pardhasaradhi; Oliver, Warren Carl

2017-06-17

Strain rate dependence of indentation hardness has been widely used to study time-dependent plasticity. However, the currently available techniques limit the range of strain rates that can be achieved during indentation testing. Recent advances in electronics have enabled nanomechanical measurements with very low noise levels (sub nanometer) at fast time constants (20 µs) and high data acquisition rates (100 KHz). These capabilities open the doors for a wide range of ultra-fast nanomechanical testing, for instance, indentation testing at very high strain rates. With an accurate dynamic model and an instrument with fast time constants, step load tests can be performed which enable access to indentation strain rates approaching ballistic levels (i.e., 4000 1/s). A novel indentation based testing technique involving a combination of step load and constant load and hold tests that enables measurement of strain rate dependence of hardness spanning over seven orders of magnitude in strain rate is presented. A simple analysis is used to calculate the equivalent uniaxial response from indentation data and compared to the conventional uniaxial data for commercial purity aluminum. Excellent agreement is found between the indentation and uniaxial data over several orders of magnitude of strain rate.

Light propagation in two-dimensional photonic crystals based on uniaxial polar materials: results on polaritonic spectrum

NASA Astrophysics Data System (ADS)

Gómez-Urrea, H. A.; Duque, C. A.; Pérez-Quintana, I. V.; Mora-Ramos, M. E.

2017-03-01

The dispersion relations of two-dimensional photonic crystals made of uniaxial polaritonic cylinders arranged in triangular lattice are calculated. The particular case of the transverse magnetic polarization is taken into account. Three different uniaxial materials showing transverse phonon-polariton excitations are considered: aluminum nitride, gallium nitride, and indium nitride. The study is carried out by means of the finite-difference time-domain technique for the solution of Maxwell equations, together with the method of the auxiliary differential equation. It is shown that changing the filling fraction can result in the modification of both the photonic and polaritonic bandgaps in the optical dispersion relations. Wider gaps appear for smaller filling fraction values, whereas a larger number of photonic bandgaps will occur within the frequency range considered when a larger filling fraction is used. The effect of including the distinct wurtzite III-V nitride semiconductors as core materials in the cylinders embedded in the air on the photonic properties is discussed as well, highlighting the effect of the dielectric anisotropy on the properties of the polaritonic part of the photonic spectrum.

Advanced Microwave Ferrite Research (AMFeR): Phase Four

DTIC Science & Technology

2009-10-15

epitaxial but the easy uniaxial anisotropy axis likely shows some dispersion. Due to inhomogeneity line broadening and two magnon scattering losses, the...below FMR field, there are degenerate spin waves (or magnon ) with the uniform mode (that always exists due to a finite FMR linewidth in reality...wave dispersion curves. developed two magnon scattering processes. On the other hand, below the FMR frequency or above the FMR field, there are no

Creep Laboratory manual

NASA Astrophysics Data System (ADS)

Osgerby, S.; Loveday, M. S.

1992-06-01

A manual for the NPL Creep Laboratory, a collective name given to two testing laboratories, the Uniaxial Creep Laboratory and the Advanced High Temperature Mechanical Testing Laboratory, is presented. The first laboratory is devoted to uniaxial creep testing and houses approximately 50 high sensitivity creep machines including 10 constant stress cam lever machines. The second laboratory houses a low cycle fatigue testing machine of 100 kN capacity driven by a servo-electric actuator, five machines for uniaxial tensile creep testing of engineering ceramics at temperatures up to 1600C, and an electronic creep machine. Details of the operational procedures for carrying out uniaxial creep testing are given. Calibration procedures to be followed in order to comply with the specifications laid down by British standards, and to provide traceability back to the primary standards are described.

Measurement of the magnetic anisotropy energy constants for magneto-optical recording media

NASA Technical Reports Server (NTRS)

Hajjar, R. A.; Wu, T. H.; Mansuripur, M.

1992-01-01

Measurement of the magneto-optical polar Kerr effect is performed on rare earth-transition metal (RE-TM) amorphous films using in-plane fields. From this measurement and the measurement of the saturation magnetization using a vibrating sample magnetometer (VSM), the magnetic anisotropy constants are determined. The temperature dependence is presented of the magnetic anisotropy in the range of -175 to 175 C. The results show a dip in the anisotropy near magnetic compensation. This anomaly is explained based on the finite exchange coupling between the rare earth and transition metal subnetworks.

Effect of uniaxial stress on the electrochemical properties of graphene with point defects

NASA Astrophysics Data System (ADS)

Szroeder, Paweł; Sagalianov, Igor Yu.; Radchenko, Taras M.; Tatarenko, Valentyn A.; Prylutskyy, Yuriy I.; Strupiński, Włodzimierz

2018-06-01

We report a calculational study of electron states and the resulting electrochemical properties of uniaxially strained graphene with point defects. For this study the reduction of ferricyanide to ferrocyanide serves as a benchmark electrochemical reaction. We find that the heterogeneous electron transfer activity of the perfect graphene electrode rises under uniaxial strain. However, evolution of the cathodic reaction rate depends on the direction of strain. For moderate lattice deformations, the zigzag strain improves electrochemical performance better than the armchair strain. Standard rate constant increases by 50% at the zigzag strain of 10%. Vacancies, covalently bonded moieties, charged adatoms and substitutional impurities in the zigzag strained graphene induce changes in the shape of the curve of the cathodic reaction rate. However, this changes do not translate into the electrocatalytic activity. Vacancies and covalently bonded moieties at concentration of 0.1% do not affect the electrochemical performance. Charged adatoms and substitutional impurities give a slight increase in the standard rate constant by, respectively, 2.2% and 3.4%.

Ising-like spin anisotropy and competing antiferromagnetic-ferromagnetic orders in GdBaCo2O5.5 single crystals.

PubMed

Taskin, A A; Lavrov, A N; Ando, Yoichi

2003-06-06

In RBaCo2O5+x compounds (R is rare earth), a ferromagnetic-antiferromagnetic competition is accompanied by a giant magnetoresistance. We study the magnetization of detwinned GdBaCo2O5.5 single crystals and find a remarkable uniaxial anisotropy of Co3+ spins which is tightly linked with the chain oxygen ordering in GdO0.5 planes. Reflecting the underlying oxygen order, CoO2 planes also develop a spin-state order consisting of Co3+ ions in alternating rows of S=1 and S=0 states. The magnetic structure appears to be composed of weakly coupled ferromagnetic ladders with Ising-like moments, which gives a simple picture for magnetotransport phenomena.

Evidence for equivalence of diffusion processes of passive scalar and magnetic fields in anisotropic Navier-Stokes turbulence.

PubMed

Jurčišinová, E; Jurčišin, M

2017-05-01

The influence of the uniaxial small-scale anisotropy on the kinematic magnetohydrodynamic turbulence is investigated by using the field theoretic renormalization group technique in the one-loop approximation of a perturbation theory. The infrared stable fixed point of the renormalization group equations, which drives the scaling properties of the model in the inertial range, is investigated as the function of the anisotropy parameters and it is shown that, at least at the one-loop level of approximation, the diffusion processes of the weak passive magnetic field in the anisotropically driven kinematic magnetohydrodynamic turbulence are completely equivalent to the corresponding diffusion processes of passively advected scalar fields in the anisotropic Navier-Stokes turbulent environments.

Ising versus XY anisotropy in frustrated R(2)Ti(2)O(7) compounds as "Seen" by Polarized Neutrons.

PubMed

Cao, H; Gukasov, A; Mirebeau, I; Bonville, P; Decorse, C; Dhalenne, G

2009-07-31

We studied the field induced magnetic order in R(2)Ti(2)O(7) pyrochlore compounds with either uniaxial (R=Ho, Tb) or planar (R=Er, Yb) anisotropy, by polarized neutron diffraction. The determination of the local susceptibility tensor {chi(parallel to),chi(perpendicular)} provides a universal description of the field induced structures in the paramagnetic phase (2-270 K), whatever the field value (1-7 T) and direction. Comparison of the thermal variations of chi(parallel to) and chi(perpendicular) with calculations using the rare earth crystal field shows that exchange and dipolar interactions must be taken into account. We determine the molecular field tensor in each case and show that it can be strongly anisotropic.

Numerical simulation of a relaxation test designed to fit a quasi-linear viscoelastic model for temporomandibular joint discs.

PubMed

Commisso, Maria S; Martínez-Reina, Javier; Mayo, Juana; Domínguez, Jaime

2013-02-01

The main objectives of this work are: (a) to introduce an algorithm for adjusting the quasi-linear viscoelastic model to fit a material using a stress relaxation test and (b) to validate a protocol for performing such tests in temporomandibular joint discs. This algorithm is intended for fitting the Prony series coefficients and the hyperelastic constants of the quasi-linear viscoelastic model by considering that the relaxation test is performed with an initial ramp loading at a certain rate. This algorithm was validated before being applied to achieve the second objective. Generally, the complete three-dimensional formulation of the quasi-linear viscoelastic model is very complex. Therefore, it is necessary to design an experimental test to ensure a simple stress state, such as uniaxial compression to facilitate obtaining the viscoelastic properties. This work provides some recommendations about the experimental setup, which are important to follow, as an inadequate setup could produce a stress state far from uniaxial, thus, distorting the material constants determined from the experiment. The test considered is a stress relaxation test using unconfined compression performed in cylindrical specimens extracted from temporomandibular joint discs. To validate the experimental protocol, the test was numerically simulated using finite-element modelling. The disc was arbitrarily assigned a set of quasi-linear viscoelastic constants (c1) in the finite-element model. Another set of constants (c2) was obtained by fitting the results of the simulated test with the proposed algorithm. The deviation of constants c2 from constants c1 measures how far the stresses are from the uniaxial state. The effects of the following features of the experimental setup on this deviation have been analysed: (a) the friction coefficient between the compression plates and the specimen (which should be as low as possible); (b) the portion of the specimen glued to the compression plates (smaller areas glued are better); and (c) the variation in the thickness of the specimen. The specimen's faces should be parallel to ensure a uniaxial stress state. However, this is not possible in real specimens, and a criterion must be defined to accept the specimen in terms of the specimen's thickness variation and the deviation of the fitted constants arising from such a variation.

Mechanical responses, texture evolution, and yield loci of extruded AZ31 magnesium alloy under various loading conditions: Experiment and modeling

NASA Astrophysics Data System (ADS)

Kabirian, Farhoud

Mechanical responses and texture evolution of extruded AZ31 Mg are measured under uniaxial (tension-compression) and multiaxial (free-end torsion) loadings. Compression loading is carried out in three different directions at temperature and strain rate ranges of 77-423 K and 10-4 -3000 s -1, respectively. Texture evolution at different intermediate strains reveals that crystal reorientation is exhausted at smaller strains with increase in strain rate while increase in temperature retards twinning. In addition to the well-known tension-compression yield asymmetry, a strong anisotropy in strain hardening response is observed. Strain hardening during the compression experiment is intensified with decreasing and increasing temperature and strain rate, respectively. This complex behavior is explained through understanding the roles of deformation mechanisms using the Visco-Plastic Self Consistent (VPSC) model. In order to calibrate the VPSC model's constants as accurate as possible, a vast number of mechanical responses including stress-strain curves in tension, compression in three directions, and free-end torsion, texture evolution at different strains, lateral strains of compression samples, twin volume fraction, and axial strain during the torsion experiment. Modeling results show that depending on the number of measurements used for calibration, roles of different mechanisms in plastic deformation change significantly. In addition, a precise definition of yield is established for the extruded AZ31magnesium alloy after it is subjected to different loading conditions (uniaxial to multiaxial) at four different plastic strains. The yield response is measured in ?-? space. Several yield criteria are studied to predict yield response of extruded AZ31. This study proposes an asymmetrical fourth-order polynomial yield function. Material constants in this model can be directly calculated using mechanical measurements. Convexity of the proposed model is discussed, and domains of constants where convexity holds are determined. Effects of grain refinement induced by Equal Channel Angular Pressing, ECAP, on mechanical responses and texture evolution are investigated. Yield strength in compression increases after ECAP, however, strain-hardening rate drops with number of ECAP passes while failure strain increases. Texture measurements reveal the higher propensity to twinning in the extruded material compared with ECAPed magnesium. Calculated Schmid factor maps are utilized to connect the observed mechanical responses to the texture.

The temperature dependence of the anisotropy constants for nickel

NASA Astrophysics Data System (ADS)

Szpunar, B.

1984-04-01

A universal function is suggested for the description of the temperature dependence of the anisotropy constants for Ni. The function has been obtained from the extended Stevens operators for J→ {1}/{2}. The prediction is in good agreement with experimental data.

Cross-bedding related anisotropy and its interplay with various boundary conditions in the formation and orientation of joints in an aeolian sandstone

NASA Astrophysics Data System (ADS)

Deng, Shang; Cilona, Antonino; Morrow, Carolyn; Mapeli, Cesar; Liu, Chun; Lockner, David; Prasad, Manika; Aydin, Atilla

2015-08-01

Previous research revealed that the cross-bedding related anisotropy in Jurassic aeolian Aztec Sandstone cropping out in the Valley of Fire State Park, Nevada, affects the orientation of compaction bands, also known as anti-cracks or closing mode structures. We hypothesize that cross-bedding should have a similar influence on the orientation of the opening mode joints within the same rock at the same location. To test this hypothesis, we investigated the relationship between the orientation of cross-beds and the orientation of different categories of joint sets including cross-bed package confined joints and joint zones in the Aztec Sandstone. The field data show that the cross-bed package confined joints occur at high-angle to bedding and trend roughly parallel to the dip direction of the cross-beds. In comparison, the roughly N-S trending joint zones appear not to be influenced by the cross-beds in any significant way but frequently truncate against the dune boundaries. To characterize the anisotropy due to cross-bedding in the Aztec Sandstone, we measured the P-wave velocities parallel and perpendicular to bedding from 11 samples and determined an average P-wave anisotropy to be slightly larger than 13%. From these results, a model based on the generalized Hooke's law for anisotropic materials is used to analyze deformation of cross-bedded sandstone as a transversely isotropic material. In the analysis, the dip angle of cross-beds is assumed to be constant and the strike orientation varying from 0° to 359° in the east (x), north (y), and up (z) coordinate system. We find qualitative agreement between most of the model results and the observed field relations between cross-beds and the corresponding joint sets. The results also suggest that uniaxial extension (εzz > εxx = εyy = 0) and axisymmetric extension (εxx = εyy < εzz and εxx = εyy > εzz) would amplify the influence of cross-bedding associated anisotropy on the joint orientation whereas a triaxial extension (εxx > εyy > εzz) would mitigate this influence. We suggest that the potential implication of different categories of joint sets (i.e., cross-bed package confined joints and joint zones) forming in response to the variation of the boundary conditions (axisymmetric extension and triaxial extension, respectively) and the interplay with the rock anisotropy is significant. These results have important implications for fluid flow through aeolian sandstones in reservoirs and aquifers.

Ferromagnetic resonance of a YIG film in the low frequency regime

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Seongjae; Grudichak, Scott; Sklenar, Joseph

2016-07-21

An improved method for characterizing the magnetic anisotropy of films with cubic symmetry is described and is applied to an yttrium iron garnet (111) film. Analysis of the ferromagnetic resonance (FMR) spectra performed both in-plane and out-of-plane from 0.7 to 8 GHz yielded the magnetic anisotropy constants as well as the saturation magnetization. The field at which FMR is observed turns out to be quite sensitive to anisotropy constants (by more than a factor ten) in the low frequency (<2 GHz) regime, and when the orientation of the magnetic field is nearly normal to the sample plane; the restoring force onmore » the magnetization arising from the magnetocrystalline anisotropy fields is then comparable to that from the external field, thereby allowing the anisotropy constants to be determined with greater accuracy. In this region, unusual dynamical behaviors are observed such as multiple resonances and a switching of FMR resonance with only a 1° change in field orientation at 0.7 GHz.« less

Pressure-induced spin reorientation transition in layered ferromagnetic insulator Cr2Ge2Te6

NASA Astrophysics Data System (ADS)

Lin, Zhisheng; Lohmann, Mark; Ali, Zulfikhar A.; Tang, Chi; Li, Junxue; Xing, Wenyu; Zhong, Jiangnan; Jia, Shuang; Han, Wei; Coh, Sinisa; Beyermann, Ward; Shi, Jing

2018-05-01

The anisotropic magnetoresistance (AMR) of Cr2Ge2Te6 (CGT), a layered ferromagnetic insulator, is investigated under an applied hydrostatic pressure up to 2 GPa. The easy-axis direction of the magnetization is inferred from the AMR saturation feature in the presence and absence of an applied pressure. At zero applied pressure, the easy axis is along the c direction or perpendicular to the layer. Upon application of a hydrostatic pressure > 1 GPa, the uniaxial anisotropy switches to easy-plane anisotropy which drives the equilibrium magnetization from the c axis to the a b plane at zero magnetic field, which amounts to a giant magnetic anisotropy energy change (> 100%). As the temperature is increased across the Curie temperature, the characteristic AMR effect gradually decreases and disappears. Our first-principles calculations confirm the giant magnetic anisotropy energy change with moderate pressure and assign its origin to the increased off-site spin-orbit interaction of Te atoms due to a shorter Cr-Te distance. Such a pressure-induced spin reorientation transition is very rare in three-dimensional ferromagnets, but it may be common to other layered ferromagnets with similar crystal structures to CGT, and therefore offers a unique way to control magnetic anisotropy.

Thermoelectric anisotropy in the iron-based superconductor Ba (Fe1-xCox) 2As2

NASA Astrophysics Data System (ADS)

Matusiak, Marcin; Rogacki, Krzysztof; Wolf, Thomas

2018-06-01

We report on the in-plane anisotropy of the Seebeck and Nernst coefficients as well as of the electrical resistivity determined for a series of strain-detwinned single crystals of Ba (Fe1-xC ox) 2A s2 . Two underdoped samples (x =0.024 , 0.045) exhibiting a transition from the tetragonal paramagnetic phase to the orthorhombic spin density wave (SDW) phase (at Ttr=100 and 60 K, respectively) show an onset of Nernst anisotropy at temperatures above 200 K, which is significantly higher than Ttr. In the optimally doped sample (x =0.06 ) the transport properties also appear to be in-plane anisotropic below T ≈120 K, despite the fact that this particular composition does not show any evidence of long-range magnetic order. However, the anisotropy observed in the optimally doped crystal is rather small, and for the Seebeck and Nernst coefficients the difference between values measured along and across the uniaxial strain has an opposite sign to those observed for underdoped crystals with x =0.024 and 0.045. For these two samples, the insensitivity of the Nernst anisotropy to the SDW transition suggests that the origin of nematicity might be something other than magnetic.

Uniaxial strain control of spin-polarization in multicomponent nematic order of BaFe 2As 2

DOE PAGES

Kissikov, T.; Sarkar, R.; Lawson, M.; ...

2018-03-13

The iron-based high temperature superconductors exhibit a rich phase diagram reflecting a complex interplay between spin, lattice, and orbital degrees of freedom. The nematic state observed in these compounds epitomizes this complexity, by entangling a real-space anisotropy in the spin fluctuation spectrum with ferro-orbital order and an orthorhombic lattice distortion. A subtle and less-explored facet of the interplay between these degrees of freedom arises from the sizable spin-orbit coupling present in these systems, which translates anisotropies in real space into anisotropies in spin space. We present nuclear magnetic resonance studies, which reveal that the magnetic fluctuation spectrum in the paramagneticmore » phase of BaFe 2As 2 acquires an anisotropic response in spin-space upon application of a tetragonal symmetry-breaking strain field. Lastly, our results unveil an internal spin structure of the nematic order parameter, indicating that electronic nematic materials may offer a route to magneto-mechanical control.« less

Anisotropy of diamagnetic susceptibility in Thassos marble: A comparison between measured and modeled data

NASA Astrophysics Data System (ADS)

de Wall, Helga; Bestmann, Michel; Ullemeyer, Klaus

2000-11-01

A study of shear zones within the calcite marble complex of the island of Thassos (Greece) shows that the low field anisotropy of magnetic susceptibility (AMS)-technique can be successfully applied to diamagnetic rocks for characterizing rock fabrics. The strain path involves both an early pure shear stage and a simple shear overprint that is documented by a transition from triaxial (neutral) to uniaxial (prolate) shapes of AMS ellipsoids. The maximum susceptibility is oriented perpendicular to the rock foliation, reflecting the preferred orientation of calcite c-axes in the protolith as well as in the mylonites. For three samples that represent different types of calcite fabrics, the AMS was recalculated from neutron and electron backscatter diffraction textural data. A comparison of the measured and modeled data shows a good coincidence for the orientation of the principal AMS axes and for the recalculated anisotropy data. Both measured and modeled data sets reflect the change from neutral to distinct prolate ellipsoids during progressive deformation.

Topological spin-hedgehog crystals of a chiral magnet as engineered with magnetic anisotropy

NASA Astrophysics Data System (ADS)

Kanazawa, N.; White, J. S.; Rønnow, H. M.; Dewhurst, C. D.; Morikawa, D.; Shibata, K.; Arima, T.; Kagawa, F.; Tsukazaki, A.; Kozuka, Y.; Ichikawa, M.; Kawasaki, M.; Tokura, Y.

2017-12-01

We report the engineering of spin-hedgehog crystals in thin films of the chiral magnet MnGe by tailoring the magnetic anisotropy. As evidenced by neutron scattering on films with different thicknesses and by varying a magnetic field, we can realize continuously deformable spin-hedgehog crystals, each of which is described as a superposition state of a different set of three spin spirals (a triple-q state). The directions of the three propagation vectors q vary systematically, gathering from the three orthogonal 〈100 〉 directions towards the film normal as the strength of the uniaxial magnetic anisotropy and/or the magnetic field applied along the film normal increase. The formation of triple-q states coincides with the onset of topological Hall signals, that are ascribed to skew scattering by an emergent magnetic field originating in the nontrivial topology of spin hedgehogs. These findings highlight how nanoengineering of chiral magnets makes possible the rational design of unique topological spin textures.

Nanosecond electric modification of order parameters

NASA Astrophysics Data System (ADS)

Borshch, Volodymyr

In this Dissertation, we study a nanosecond electro-optic response of a nematic liquid crystal in a geometry where an applied electric field E modifies the tensor order parameter but does not change the orientation of the optic axis (director N̂). We use nematics with negative dielectric anisotropy with the electric field applied perpendicularly to N̂. The field changes the dielectric tensor at optical frequencies (optic tensor), due to the following mechanisms: (a) nanosecond creation of biaxial orientational order; (b) uniaxial modification of the orientational order that occurs over the timescales of tens of nanoseconds, and (c) quenching of director fluctuations with a wide range of characteristic times up to milliseconds. We develop a model to describe the dynamics of all three mechanisms. We design the experimental conditions to selectively suppress the contributions from the quenching of director fluctuations (c) and from the biaxial order effect (a) and thus, separate the contributions of the three mechanisms in the electro-optic response. As a result, the experimental data can be well fitted with the model parameters. The analysis provides a rather detailed physical picture of how the liquid crystal responds to a strong electric field, E ˜ 108 V/m, on a timescale of nanoseconds. This work provides a useful guide in the current search of the biaxial nematic phase. Namely, the temperature dependence of the biaxial susceptibility allows one to estimate the temperature of the potential uniaxial-to-biaxial phase transition. An analysis of the quenching of director fluctuations indicates that on a timescale of nanoseconds, the classic model with constant viscoelastic material parameters might reach its limit of validity. The effect of nanosecond electric modification of the order parameter (NEMOP) can be used in applications in which one needs to achieve ultrafast (nanosecond) changes of optical characteristics, such as birefringence.

Investigation of Three-Dimensional Stress Fields and Slip Systems for FCC Single Crystal Superalloy Notched Specimens

NASA Technical Reports Server (NTRS)

Arakere, Nagaraj K.; Magnan, Shannon; Ebrahimi, Fereshteh; Ferroro, Luis

2004-01-01

Metals and their alloys, except for a few intermetallics, are inherently ductile, i.e. plastic deformation precedes fracture in these materials. Therefore, resistance to fracture is directly related to the development of the plastic zone at the crack tip. Recent studies indicate that the fracture toughness of single crystals depends on the crystallographic orientation of the notch as well as the loading direction. In general, the dependence of crack propagation resistance on crystallographic orientation arises from the anisotropy of (i) elastic constants, (ii) plastic deformation (or slip), and (iii) the weakest fracture planes (e.g. cleavage planes). Because of the triaxial stress state at the notch tips, many slip systems that otherwise would not be activated during uniaxial testing, become operational. The plastic zone formation in single crystals has been tackled theoretically by Rice and his co-workers and only limited experimental work has been conducted in this area. The study of the stresses and strains in the vicinity of a FCC single crystal notch tip is of relatively recent origin. We present experimental and numerical investigation of 3D stress fields and evolution of slip sector boundaries near notches in FCC single crystal tension test specimens, and demonstrate that a 3D linear elastic finite element model that includes the effect of material anisotropy is shown to predict active slip planes and sectors accurately. The slip sector boundaries are shown to have complex curved shapes with several slip systems active simultaneously near the notch. Results are presented for surface and mid-plane of the specimens. The results demonstrate that accounting for 3D elastic anisotropy is very important for accurate prediction of slip activation near FCC single crystal notches loaded in tension. Results from the study will help establish guidelines for fatigue damage near single crystal notches.

Intrinsic magnetic properties of L1{sub 0} FeNi obtained from meteorite NWA 6259

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poirier, Eric; Pinkerton, Frederick E., E-mail: frederick.e.pinkerton@gm.com; Kubic, Robert

2015-05-07

FeNi having the tetragonal L1{sub 0} crystal structure is a promising new rare-earth-free permanent magnet material. Laboratory synthesis is challenging, however, tetragonal L1{sub 0} FeNi—the mineral “tetrataenite”—has been characterized using specimens found in nickel-iron meteorites. Most notably, the meteorite NWA 6259 recovered from Northwest Africa is 95 vol. % tetrataenite with a composition of 43 at. % Ni. Hysteresis loops were measured as a function of sample orientation on a specimen cut from NWA 6259 in order to rigorously deduce the intrinsic hard magnetic properties of its L1{sub 0} phase. Electron backscatter diffraction showed that NWA 6259 is strongly textured, containing L1{submore » 0} grains oriented along any one of the three equivalent cubic directions of the parent fcc structure. The magnetic structure was modeled as a superposition of the three orthonormal uniaxial variants. By simultaneously fitting first-quadrant magnetization data for 13 different orientations of the sample with respect to the applied field direction, the intrinsic magnetic properties were estimated to be saturation magnetization 4πM{sub s} = 14.7 kG and anisotropy field H{sub a} = 14.4 kOe. The anisotropy constant K = 0.84 MJ/m{sup 3} is somewhat smaller than the value K = 1.3 MJ/m{sup 3} obtained by earlier researchers from nominally equiatomic FeNi prepared by neutron irradiation accompanied by annealing in a magnetic field, suggesting that higher Ni content (fewer Fe antisite defects) may improve the anisotropy. The fit also indicated that NWA 6259 contains one dominant variant (62% by volume), the remainder of the sample being a second variant, and the third variant being absent altogether.« less

Compositional modulated atomic layer stacking and uniaxial magnetocrystalline anisotropy of CoPt alloy sputtered films with close-packed plane orientation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saito, Shin, E-mail: ssaito@ecei.tohoku.ac.jp; Nozawa, Naoki; Hinata, Shintaro

An atomic layer stacking structure in hexagonal close packed (hcp) Co{sub 100−x}Pt{sub x} alloy films with c-plane sheet texture was directly observed by a high-angle annular dark-field imaging scanning transmission electron microscopy. The analysis of sequential and/or compositional atomic layer stacking structure and uniaxial magnetocrystalline anisotropy (K{sub u} = K{sub u1} + K{sub u2}) revealed that (1) integrated intensity of the superlattice diffraction takes the maximum at x = 20 at. % and shows broadening feature against x for the film fabricated under the substrate temperature (T{sub sub}) of 400 °C. (2) Compositional separation structure in atomic layers is formed for the films fabricated under T{sub sub} = 400 °C.more » A sequential alternative stacking of atomic layers with different compositions is hardly formed in the film with x = 50 at. %, whereas easily formed in the film with x = 20 at. %. This peculiar atomic layer stacking structure consists of in-plane-disordered Pt-rich and Pt-poor layers, which is completely different from the so-called atomic site ordered structure. (3) A face centered cubic atomic layer stacking as faults appeared in the host hcp atomic layer stacking exists in accompanies with irregularities for the periodicity of the compositional modulation atomic layers. (4) K{sub u1} takes the maximum of 1.4 × 10{sup 7 }erg/cm{sup 3} at around x = 20 at. %, whereas K{sub u2} takes the maximum of 0.7 × 10{sup 7 }erg/cm{sup 3} at around x = 40 at. %, which results in the maximum of 1.8 × 10{sup 7 }erg/cm{sup 3} of K{sub u} at x = 30 at. % and a shoulder in compositional dependence of K{sub u} in the range of x = 30–60 at. %. Not only compositional separation of atomic layers but also sequential alternative stacking of different compositional layers is quite important to improve essential uniaxial magnetocrystalline anisotropy.« less

Dynamic compressive strength of epoxy composites

NASA Astrophysics Data System (ADS)

Plastinin, A. V.; Sil'vestrov, V. V.

1996-11-01

The strength of laminated and unidirectionally reinforced composite materials was investigated in conditions of dynamic uniaxial compression with a strain rate of 50-1000 sec-1 using the split Hopkinson pressure bar method. It was shown that in conditions of dynamic compression, glass/epoxy, aramid/epoxy, and carbon/epoxy composites exhibit elastic-brittle behavior with anisotropy of the strength and elastic properties. The effect of the strain rate on the strength characteristics of fiberglass-reinforced plastics was demonstrated.

A Program of Research on Microfabrication Techniques for VLSI Magnetic Devices.

DTIC Science & Technology

1982-10-01

contribution to the implantation- induced uniaxial anisotropy field change. BACKGROUND Magnetic garnet films are grown by liquid phase epitaxy ( LPE ) on non...a single crystal, non-magnetic garnet substrate by the liquid phase epitaxy ( LPE ) method. These thin films , usually one to three microns in thickness...microscopy. Experimental Procedures Films of (SmYGdTm)3Ca0a.Fe4.6012 garnet were grown by liquid phase epitaxy ( LPE ) on gadolinium-gallium garnet (GGG

Modelling compensated antiferromagnetic interfaces with MuMax3

NASA Astrophysics Data System (ADS)

De Clercq, Jonas; Leliaert, Jonathan; Van Waeyenberge, Bartel

2017-10-01

We show how compensated antiferromagnetic interfaces can be implemented in the micromagnetic simulation program MuMax3. We demonstrate that we can model spin flop coupling as a uniaxial anisotropy for small canting angles and how we can take into account the exact energy terms for strong coupling between a ferromagnet and a compensated antiferromagnet. We also investigate athermal training in biaxial antiferromagnets and reproduce the training effect in a polycrystalline IrMn/CoFe bilayer.

Structural and magnetic properties of ultra-thin Fe films on metal-organic chemical vapour deposited GaN(0001)

NASA Astrophysics Data System (ADS)

Kim, Jun-Young; Ionescu, Adrian; Mansell, Rhodri; Farrer, Ian; Oehler, Fabrice; Kinane, Christy J.; Cooper, Joshaniel F. K.; Steinke, Nina-Juliane; Langridge, Sean; Stankiewicz, Romuald; Humphreys, Colin J.; Cowburn, Russell P.; Holmes, Stuart N.; Barnes, Crispin H. W.

2017-01-01

Structural and magnetic properties of 1-10 nm thick Fe films deposited on GaN(0001) were investigated. In-situ reflecting high energy electron diffraction images indicated a α-Fe(110)/GaN(0001) growth of the 3D Volmer-Weber type. The α-Fe(110) X-ray diffraction peak showed a 1° full-width at half-maximum, indicating ≈20 nm grain sizes. A significant reduction in Fe atomic moment from its bulk value was observed for films thinner than 4 nm. Both GaN/Fe interface roughness and Fe film coercivity increased with Fe thickness, indicating a possible deterioration of Fe crystalline quality. Magnetic anisotropy was mainly uniaxial for all films while hexagonal anisotropies appeared for thicknesses higher than 3.7 nm.

Spin reorientations in Tb-Fe films grown on polyimide substrates

NASA Astrophysics Data System (ADS)

Maneesh, K. Sai; Arout Chelvane, J.; Talapatra, A.; Basumatary, Himalay; Mohanty, J.; Kamat, S. V.

2018-02-01

This paper reports the effect of film thickness and rapid thermal annealing on the spin reorientations in Tb-Fe films grown on flexible polyimide substrates. Magnetization studies indicated that the spins reorient from in-plane to out-of-plane direction with increase in film thicknesses. This was confirmed by magnetic force microscopy studies which showed weak featureless contrast for films deposited with lower thickness and a strong out-of-plane contrast for films grown with higher thicknesses. On subsequent rapid thermal annealing all the Tb-Fe films exhibited in-plane magnetic anisotropy. The results were explained based on competition between uniaxial and shape anisotropies, nature of residual stresses as well as nucleation of crystalline Fe phase in an amorphous Tb-Fe matrix on rapid thermal annealing.

Hydrophilic Channel Alignment of Perfluoronated Sulfonic-Acid Ionomers for Vanadium Redox Flow Batteries.

PubMed

So, Soonyong; Cha, Min Suc; Jo, Sang-Woo; Kim, Tae-Ho; Lee, Jang Yong; Hong, Young Taik

2018-06-13

It is known that uniaxially drawn perfluoronated sulfonic-acid ionomers (PFSAs) show diffusion anisotropy because of the aligned water channels along the deformation direction. We apply the uniaxially stretched membranes to vanadium redox flow batteries (VRFBs) to suppress the permeation of active species, vanadium ions through the transverse directions. The aligned water channels render much lower vanadium permeability, resulting in higher Coulombic efficiency (>98%) and longer self-discharge time (>250 h). Similar to vanadium ions, proton conduction through the membranes also decreases as the stretching ratio increases, but the thinned membranes show the enhanced voltage and energy efficiencies over the range of current density, 50-100 mA/cm 2 . Hydrophilic channel alignment of PFSAs is also beneficial for long-term cycling of VRFBs in terms of capacity retention and cell performances. This simple pretreatment of membranes offers an effective and facile way to overcome high vanadium permeability of PFSAs for VRFBs.

Structural and magnetic properties of new uniaxial nanocrystalline Pr5Co19 compound

NASA Astrophysics Data System (ADS)

Bouzidi, W.; Mliki, N.; Bessais, L.

2017-11-01

Highly-coercive nanocrystalline Pr5Co19 powders have been synthesized by mechanical milling for the first time. The structural properties are studied by X-ray diffraction and refined with Rietveld method. This analysis revealed that whatever annealing temperature, samples crystallize in the rhombohedral (3R) of Ce5Co19-type structure (space group R 3 bar m). The magnetization curve as a function of temperature shows a magnetic transition state at the Curie temperature TC = 690 K. The optimum hard magnetic properties have been obtained for Pr5Co19 milled for 5 h and annealed at 1048 K for 30 min. These alloys exhibit a coercivity of 15 kOe at room temperature. This high coercivity is attributed to the high uniaxial magnetocrystalline anisotropy, nanoscale grain size, and to the homogeneous nanostructure developed by mechanical milling process and subsequent annealing.

Orthotropic Laminated Open-cell Frameworks Retaining Strong Auxeticity under Large Uniaxial Loading

NASA Astrophysics Data System (ADS)

Tanaka, Hiro; Suga, Kaito; Iwata, Naoki; Shibutani, Yoji

2017-01-01

Anisotropic materials form inside living tissue and are widely applied in engineered structures, where sophisticated structural and functional design principles are essential to employing these materials. This paper presents a candidate laminated open-cell framework, which is an anisotropic material that shows remarkable mechanical performance. Using additive manufacturing, artificial frameworks are fabricated by lamination of in-plane orthotropic microstructures made of elbowed beam and column members; this fabricated structure features orthogonal anisotropy in three-dimensional space. Uniaxial loading tests reveal strong auxeticity (high negative Poisson’s ratios) in the out-of-plane direction, which is retained reproducibly up to the nonlinear elastic region, and is equal under tensile and compressive loading. Finite element simulations support the observed auxetic behaviors for a unit cell in the periodic framework, which preserve the theoretical elastic properties of an orthogonal solid. These findings open the possibility of conceptual materials design based on geometry.

A Computational Scheme To Evaluate Hamaker Constants of Molecules with Practical Size and Anisotropy.

PubMed

Hongo, Kenta; Maezono, Ryo

2017-11-14

We propose a computational scheme to evaluate Hamaker constants, A, of molecules with practical sizes and anisotropies. Upon the increasing feasibility of diffusion Monte Carlo (DMC) methods to evaluate binding curves for such molecules to extract the constants, we discussed how to treat the averaging over anisotropy and how to correct the bias due to the nonadditivity. We have developed a computational procedure for dealing with the anisotropy and reducing statistical errors and biases in DMC evaluations, based on possible validations on predicted A. We applied the scheme to cyclohexasilane molecule, Si 6 H 12 , used in "printed electronics" fabrications, getting A ≈ 105 ± 2 zJ, being in plausible range supported even by other possible extrapolations. The scheme provided here would open a way to use handy ab initio evaluations to predict wettabilities as in the form of materials informatics over broader molecules.

The observation of AE events under uniaxial compression and the quantitative relationship between the anisotropy index and the main failure plane

NASA Astrophysics Data System (ADS)

Zhang, Zhibo; Wang, Enyuan; Chen, Dong; Li, Xuelong; Li, Nan

2016-11-01

In this paper, the P-wave velocities in different directions of sandstone samples under uniaxial compression are measured. The results indicate that the changes in the P-wave velocity in different directions are almost the same. In the initial stage of loading, the P-wave velocity exhibits a rising trend due to compaction and closure of preexisting fissures. As the stress increase, preexisting fissures are closed but induced fractures are not yet generated. The sandstone samples become denser and more uniform. The P-wave velocity remains in a steady state at a high level. In the late stage of loading, the P-wave velocity drops significantly due to the expansion and breakthrough of induced fractures. The P-wave velocity anisotropy index ε is analyzed during the process of loading. It can be observed that the change in the degree of wave velocity anisotropy can be divided into three stages: the AB stage, the BC stage and the CD stage, with a changing trend from decline to incline. In the initial stage of loading, the preexisting fissures have a randomized distribution, and the change is large-scale and uniform. The difference in each spatial point decreases gradually, and synchronization increases gradually. Thus, the P-wave velocity anisotropy declines. As the stress increases gradually, with the expansion and breakthrough of induced fractures, the difference in each spatial point increases. Before failure of rock samples, the violent change region of the rock samples' internal structure is focused on a narrow two-dimensional zone, and the rock samples' structural change is obviously local. Therefore, the degree of velocity anisotropy rises after declining, and it also has good corresponding relation among the AE count, the location of AE events and the degree of wave velocity anisotropy. The projection plane of the main fracture plane on the axis plane is recorded as M plane. Based on the AFF equation, for the CD stage, we analyze the quantitative relationship between the velocity anisotropy index ε and angle θ, which is the difference between the angle of the M plane and the X plane and the angle of the M plane and the Y plane from the theoretical point. The results indicate that 1/ε and cotθ/2 have good negative linear relationship that can be expressed as cotθ/2 = a ∗1/ε + b. According to experimental data, the linear fit of 1/ε and cotθ/2 is found, obtaining cotθ/2 = - 0.04721/ε + 0.03, with a linear fit index of 0.908. From an experimental point of view, the linear relationship between 1/ε and cotθ/2 is verified. Through this research, we propose a new method for quantitatively predicting the main fracture occurrence position by P-wave velocity anisotropy. This work has an important significance for understanding buckling failure of rocks.

Magnetic anisotropies and rotational hysteresis in Ni81Fe19/Fe50Mn50 films: A study by torque magnetometry and anisotropic magnetoresistance

NASA Astrophysics Data System (ADS)

da Silva, O. E.; de Siqueira, J. V.; Kern, P. R.; Garcia, W. J. S.; Beck, F.; Rigue, J. N.; Carara, M.

2018-04-01

Exchange bias properties of NiFe/FeMn thin films have been investigated through X-ray diffraction, hysteresis loops, angular measurements of anisotropic magnetoresistance (AMR) and magnetic torque. As first predicted by Meiklejohn and Bean we found a decrease on the bias field as the NiFe layer thickness increases. However such reduction is not as strong as expected and it was attributed to the increase on the number of uncompensed antiferromagnetic spins resulting from the increase on the number of FeMn grains at the interface as the thickness of the NiFe layer is increased. The angular evolution of AMR and the magnetic torque were calculated and compared to the experimental ones using the minimization of the free magnetic energy and finding the magnetization equilibrium angle. The free energy, for each grain of the polycrystalline sample, is composed by the following terms: Zeeman, uniaxial, unidirectional and the rotatable energies. While from the AMR curves we obtain stable anisotropy fields independently on the measuring fields, from the torque curves we obtain increasing values of the uniaxial and rotatable fields, as the measuring field is increased. These results were attributed to the physical origin and sensitivity of the two different techniques. Magnetoresistance is mainly sensitive to the inner portion of the ferromagnetic layer, and the torque brings out information of the whole ferromagnetic layer including the interface of the layers. In this way, we believe that the increase in the uniaxial and rotatable values were due to an increase on the volume of the ferromagnetic layer, near the interfaces, which is made to rotate with the measuring field. Studying the rotational hysteresis by both techniques allows to separately obtain the contributions coming from the inner portion of ferromagnetic layer and from the interface.

Correlations Between Structural and Magnetic Properties of Co2 FeSi Heusler-Alloy Thin Films

NASA Astrophysics Data System (ADS)

Zhu, Weihua; Wu, Di; Zhao, Bingcheng; Zhu, Zhendong; Yang, Xiaodi; Zhang, Zongzhi; Jin, Q. Y.

2017-09-01

The structural and magnetic properties are the most important parameters for practical applications of Co-based Heusler alloys. The correlations between the crystallization degree, chemical order, magnetic coercivity, saturation magnetization (MS ), and in-plane magnetic anisotropies are systematically investigated for Co2FeSi (CFS) films fabricated at different temperatures (TS ). XRD shows that the CFS layer changes progressively from a disordered crystal structure into a chemically disordered A 2 structure and further into a chemically ordered B 2 and even L 21 structures when increasing TS up to 480 °C . Meanwhile, the static angular remanence magnetization curves show a clear transition of magnetic anisotropy from twofold to fourfold symmetry, due to the competition effect between the uniaxial anisotropy field HU and biaxial anisotropy field HB . The HU value is found to be weakly dependent on TS , while HB shows a continuous enhancement at TS>300 °C , implying that the enhancement of the L 21 ordering degree would not weaken the biaxial anisotropy. The varying trend of HB is similar to MS , which can be respectively attributed to the improved crystal structure and chemical order. The anisotropic fields and their variation behaviors determined by a vibrating sample magnetometer are highly consistent with the results by a time-resolved magneto-optical Kerr effect study. Our findings provide a better understanding of the structural ordering and magnetic anisotropy, which will be helpful for designing advanced spintronic devices.

Influence of anisotropy on anomalous scaling of a passive scalar advected by the Navier-Stokes velocity field.

PubMed

Jurcisinová, E; Jurcisin, M; Remecký, R

2009-10-01

The influence of weak uniaxial small-scale anisotropy on the stability of the scaling regime and on the anomalous scaling of the single-time structure functions of a passive scalar advected by the velocity field governed by the stochastic Navier-Stokes equation is investigated by the field theoretic renormalization group and operator-product expansion within one-loop approximation of a perturbation theory. The explicit analytical expressions for coordinates of the corresponding fixed point of the renormalization-group equations as functions of anisotropy parameters are found, the stability of the three-dimensional Kolmogorov-like scaling regime is demonstrated, and the dependence of the borderline dimension d(c) is an element of (2,3] between stable and unstable scaling regimes is found as a function of the anisotropy parameters. The dependence of the turbulent Prandtl number on the anisotropy parameters is also briefly discussed. The influence of weak small-scale anisotropy on the anomalous scaling of the structure functions of a passive scalar field is studied by the operator-product expansion and their explicit dependence on the anisotropy parameters is present. It is shown that the anomalous dimensions of the structure functions, which are the same (universal) for the Kraichnan model, for the model with finite time correlations of the velocity field, and for the model with the advection by the velocity field driven by the stochastic Navier-Stokes equation in the isotropic case, can be distinguished by the assumption of the presence of the small-scale anisotropy in the systems even within one-loop approximation. The corresponding comparison of the anisotropic anomalous dimensions for the present model with that obtained within the Kraichnan rapid-change model is done.

Induced Anisotropy in FeCo-Based Nanocrystalline Ferromagnetic Alloys (HITPERM) by Very High Field Annealing

NASA Technical Reports Server (NTRS)

Johnson, F.; Garmestani, H.; Chu, S.-Y.; McHenry, M. E.; Laughlin, D. E.

2004-01-01

Very high magnetic field annealing is shown to affect the magnetic anisotropy in FeCo-base nanocrystalline soft ferromagnetic alloys. Alloys of composition Fe(44.5)Co(44.5)Zr(7)B(4) were prepared by melt spinning into amorphous ribbons, then wound to form toroidal bobbin cores. One set of cores was crystallized in a zero field at 600 deg. C for 1 h, then, field annealed at 17 tesla (T) at 480 deg. C for 1 h. Another set was crystallized in a 17-T field at 480 deg. C for 1 h. Field orientation was transverse to the magnetic path of the toroidal cores. An induced anisotropy is indicated by a sheared hysteresis loop. Sensitive torque magnetometry measurements with a Si cantilever sensor indicated a strong, uniaxial, longitudinal easy axis in the zero-field-crystallized sample. The source is most likely magnetoelastic anisotropy, caused by the residual stress from nanocrystallization and the nonzero magnetostriction coefficient for this material. The magnetostrictive coefficient lambda(5) is measured to be 36 ppm by a strain gage technique. Field annealing reduces the magnitude of the induced anisotropy. Core loss measurements were made in the zero-field-crystallized, zero-field-crystallized- than-field-annealed, and field-crystallized states. Core loss is reduced 30%-50% (depending on frequency) by field annealing. X-ray diffraction reveals no evidence of crystalline texture or orientation that would cause the induced anisotropy. Diffusional pair ordering is thought to be the cause of the induced anisotropy. However, reannealing the samples in the absence of a magnetic field at 480 deg. C does not completely remove the induced anisotropy.

Thickness Dependence of the Dzyaloshinskii-Moriya Interaction in Co2 FeAl Ultrathin Films: Effects of Annealing Temperature and Heavy-Metal Material

NASA Astrophysics Data System (ADS)

Belmeguenai, M.; Roussigné, Y.; Bouloussa, H.; Chérif, S. M.; Stashkevich, A.; Nasui, M.; Gabor, M. S.; Mora-Hernández, A.; Nicholson, B.; Inyang, O.-O.; Hindmarch, A. T.; Bouchenoire, L.

2018-04-01

The interfacial Dzyaloshinskii-Moriya interaction (IDMI) is investigated in Co2FeAl (CFA) ultrathin films of various thicknesses (0.8 nm ≤tCFA≤2 nm ) grown by sputtering on Si substrates, using Pt, W, Ir, and MgO buffer or/and capping layers. Vibrating sample magnetometry reveals that the magnetization at saturation (Ms ) for the Pt- and Ir-buffered films is higher than the usual Ms of CFA due to the proximity-induced magnetization (PIM) in Ir and Pt estimated to be 19% and 27%, respectively. The presence of PIM in these materials is confirmed using x-ray resonant magnetic reflectivity. Moreover, while no PIM is induced in W, higher PIM is obtained with Pt when it is used as a buffer layer rather than a capping layer. Brillouin light scattering in the Damon-Eshbach geometry is used to investigate the thickness dependences of the IDMI constants from the spin-wave nonreciprocity and the perpendicular anisotropy field versus the annealing temperature. The IDMI sign is found to be negative for Pt /CFA and Ir /CFA , while it is positive for W /CFA . The thickness dependence of the effective IDMI constant for stacks involving Pt and W shows the existence of two regimes similar to that of the perpendicular anisotropy constant due to the degradation of the interfaces as the CFA thickness approaches a critical thickness. The surface IDMI and anisotropy constants of each stack are determined for the thickest samples where a linear thickness dependence of the effective IDMI constant and the effective magnetization are observed. The interface anisotropy and IDMI constants investigated for the Pt /CFA /MgO system show different trends with the annealing temperature. The decrease of the IDMI constant with increasing annealing temperature is probably due to the electronic structure changes at the interfaces, while the increase of the interface anisotropy constant is coherent with the interface quality and disorder enhancement.

Spin Waves and Transport Properties in Ferromagnetic Co-Al-O and Fe-Al-O Granular Films: A Brillouin Scattering Study

NASA Astrophysics Data System (ADS)

Yoshihara, Akira; Ohnuma, Shigehiro; Fujimori, Hiroyasu; Nakamura, Shintaro; Nojima, Tsutomu

2008-09-01

A systematic Brillouin light scattering (BLS) study on long-wavelength spin waves (SWs) in ferromagnetic TM-Al-O (TM=Co, Fe) nano-granular films with thickness of >1 μm was performed under magnetic fields of up to 4 kOe at room temperature. BLS spectra consist of a pair of bulk SW peaks on both frequency sides and a surface localized SW peak only on the positive frequency side in this study. These SW frequencies as a function of the magnetic field can be fully reproduced by the magnetostatic frequency formula developed for a semi-infinite uniform ferromagnetic medium with an exchange coupling and an in-plane uniaxial magnetic anisotropy. We determined a set of the magnetic constants including the exchange field HE for each film. Combining the exchange field HE with the electrical resistivity ρ for each film at room temperature, we found an inverse-square law given by ρ=a(HE)-2 for both the Co and Fe granular films with aFe=30.3 μΩ\\cdotcm\\cdot(kOe)2 and aCo=22.1 μΩ\\cdotcm\\cdot(kOe)2, respectively.

Modelling magnetic anisotropy of single-chain magnets in |d/J| ≥ 1 regime

NASA Astrophysics Data System (ADS)

Haldar, Sumit; Raghunathan, Rajamani; Sutter, Jean-Pascal; Ramasesha, S.

2017-11-01

Single-molecule magnets (SMMs) with single-ion anisotropies comparable to exchange interactions J between spins have recently been synthesised. Here, we provide theoretical insights into the magnetism of such systems. We study spin chains with site-spins, s = 1, 3/2 and 2 and strength of on-site anisotropy comparable to the exchange constants between the spins. We find that large on-site anisotropies lead to crossing of the states with different MS values in the same spin manifold to which they belong in the absence of anisotropy. When on-site anisotropy is increased further, we also find that the MS states of the higher energy spin states descend below the MS states of the ground spin manifold. Giant spin in this limit is no longer conserved and describing the axial and rhombic anisotropies of the molecule, DM and EM, respectively, is not possible. However, the giant spin of the low-lying large MS states is very nearly an integer and, using this spin value, it is possible to construct an effective spin-Hamiltonian and compute the molecular magnetic anisotropy constants DM and EM. We report effect of finite sizes, rotations of site anisotropies and chain dimerisation on the effective anisotropy of the spin chains.

Tailoring perpendicular magnetic coupling by XMCD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Idzerda, Y. U.; Snow, R.; Bhatkar, H.

2017-01-10

The elemental perpendicular magnetic anisotropy constants of both elements of a 20 nm bcc Co 88Mn 12 alloy film grown on MgO(001) and capped with Al, have been determined. By fitting a Stoner-Wohlfarth astroid model to the measured Co and Mn L 3 XMCD peak intensities as a function of incidence photon angle with the magnetic field applied co-axially with the photon propagation direction, the elemental perpendicular anisotropy constants were found to be –6.46 x 10 5 J/m 3 and –6.68 x 10 5 J/m 3, respectively. The modeling of the Co and Mn data both result in nearly themore » same anisotropy constant as expected for a single alloy film.« less

Multiple resonance peaks of FeCo thin films with NiFe underlayer

NASA Astrophysics Data System (ADS)

Zhong, Xiaoxi; Soh, Wee Tee; Phuoc, Nguyen N.; Liu, Ying; Ong, C. K.

2015-01-01

Under zero external magnetic fields, single-layer FeCo thin films exhibit no ferromagnetic resonance (FMR) peaks, while multiple FMR peaks were obtained by growing FeCo thin films on NiFe underlayers with various thicknesses up to 50 nm. Comprehensive investigations of the dynamic magnetic properties and origin of the peaks were conducted through measurements of microwave permeability via a shorted microstrip perturbation technique. Through fitted values of saturation magnetization Ms, uniaxial anisotropy HKsta, and rotatable anisotropy HKrot extracted from the FMR experiments, it was found that two of the three resonance peaks originate from FeCo, and the third from NiFe. The two magnetic phases of FeCo grains are found to have different values of HKrot and explained by the exchange interaction between FeCo and NiFe grains.

Buckling and Vibration of Fiber Reinforced Composite Plates With Nanofiber Reinforced Matrices

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Murthy, Pappu L. N.

2011-01-01

Anisotropic composite plates were evaluated with nanofiber reinforced matrices (NFRM). The nanofiber reinforcement volumes ratio in the matrix was 0.01. The plate dimensions were 20 by 10 by 1.0 in. (508 by 254 by 25.4 mm). Seven different loading condition cases were evaluated for buckling: three for uniaxial loading, three for pairs of combined loading, and one with three combined loadings. The anisotropy arose from the unidirectional plates having been at 30 from the structural axis. The anisotropy had a full 6 by 6 rigidities matrix which were satisfied and solved by a Galerkin buckling algorithm. For vibration the same conditions were used with the applied cods about a small fraction of the buckling loads. The buckling and vibration results showed that the NFRM plates buckled at about twice those with conventional matrix.

Three dielectric constants and orientation order parameters in nematic mesophases

NASA Astrophysics Data System (ADS)

Yoon, Hyung Guen; Jeong, Seung Yeon; Kumar, Satyendra; Park, Min Sang; Park, Jung Ok; Srinivasarao, M.; Shin, Sung Tae

2011-03-01

Temperature dependence of the three components ɛ1 , ɛ2 , and ɛ3 of dielectric constant and orientation order parameters in the nematic phase of mesogens with rod, banana, and zero-order dendritic shape were measured using the in-plane and vertical switching geometries, and micro-Raman technique. Results on the well-known uniaxial (Nu) nematogens, E7 and 5CB, revealed two components ɛ1 = ~ɛ| | and ɛ2 = ~ɛ3 = ~ɛ⊥ , as expected. The three dielectric constants were different for two azo substituted (A131 and A103) and an oxadiazole based (ODBP-Ph-C12) bent core mesogens, and a Ge core tetrapode. In some cases, two of the components became the same indicating a loss of biaxiality at temperatures coinciding with the previously reported Nu to biaxial nematic transition. This interpretation is substantiated by micro-Raman measurements of the uniaxial and biaxial nematic order parameters. Supported by the US Department of Energy, Basic Energy Sciences grant ER46572 and by Samsung Electronics Corporation.

A two-fluid approximation for calculating the cosmic microwave background anisotropies

NASA Technical Reports Server (NTRS)

Seljak, Uros

1994-01-01

We present a simplified treatment for calculating the cosmic microwave background anisotropy power spectrum in adiabatic models. It consists of solving for the evolution of a two-fluid model until the epoch of recombination and then integrating over the sources to obtain the cosmic microwave background (CMB) anisotropy power spectrum. The approximation is useful both for a physical understanding of CMB anisotropies as well as for a quantitative analysis of cosmological models. Comparison with exact calculations shows that the accuracy is typically 10%-20% over a large range of angles and cosmological models, including those with curvature and cosmological constant. Using this approximation we investigate the dependence of the CMB anisotropy on the cosmological parameters. We identify six dimensionless parameters that uniquely determine the anisotropy power spectrum within our approximation. CMB experiments on different angular scales could in principle provide information on all these parameters. In particular, mapping of the Doppler peaks would allow an independent determination of baryon mass density, matter mass density, and the Hubble constant.

Impact of tensile strain on the thermal transport of zigzag hexagonal boron nitride nanoribbon: An equilibrium molecular dynamics study

NASA Astrophysics Data System (ADS)

Navid, Ishtiaque Ahmed; Intisar Khan, Asir; Subrina, Samia

2018-02-01

The thermal conductivity of single layer strained hexagonal boron nitride nanoribbon (h-BNNR) has been computed using the Green—Kubo formulation of Equilibrium Molecular Dynamics (EMD) simulation. We have investigated the impact of strain on thermal transport of h-BNNR by varying the applied tensile strain from 1% upto 5% through uniaxial loading. The thermal conductivity of h-BNNR decreases monotonically with the increase of uniaxial tensile strain keeping the sample size and temperature constant. The thermal conductivity can be reduced upto 86% for an applied uniaxial tensile strain of 5%. The impact of temperature and width variation on the thermal conductivity of h-BNNR has also been studied under different uniaxial tensile strain conditions. With the increase in temperature, the thermal conductivity of strained h-BNNR exhibits a decaying characteristics whereas it shows an opposite pattern with the increasing width. Such study would provide a good insight on the strain tunable thermal transport for the potential device application of boron nitride nanostructures.

Manipulating the magnetic anisotropy and magnetization dynamics by stress: Numerical calculation and experiment

NASA Astrophysics Data System (ADS)

Correa, M. A.; Bohn, F.

2018-05-01

We perform a theoretical and experimental investigation of the magnetic properties and magnetization dynamics of a ferromagnetic magnetostrictive multilayer grown onto a flexible substrate and submitted to external stress. We calculate the magnetic behavior and magnetoimpedance effect for a trilayered system from an approach that considers a magnetic permeability model for planar geometry and a magnetic free energy density which takes into account induced uniaxial and magnetoelastic anisotropy contributions. We verify remarkable modifications of the magnetic anisotropy with external stress, as well as we show that the dynamic magnetic response is strongly affected by these changes. We discuss the magnetic features that lead to modifications of the frequency limits where distinct mechanisms are responsible by the magnetoimpedance variations, enabling us to manipulate the resonance fields. To test the robustness of the approach, we directly compare theoretical results with experimental data. Thus, we provide experimental evidence to confirm the validity of the theoretical approach, as well as to manipulate the resonance fields to tune the MI response according to real applications in devices.

Tailoring magnetic domains in Gd-Fe thin films

NASA Astrophysics Data System (ADS)

Talapatra, A.; Chelvane, J. Arout; Mohanty, J.

2018-05-01

This paper presents the global modification of magnetic domains and magnetic properties in amorphous Gd19Fe81 thin films with rapid thermal processing at two distinct temperatures (250oC and 450oC), and with different time intervals viz., 2, 5, 10 and 20 minutes. 100 nm thick as-prepared films display nano-scale meandering stripe domains with high magnetic phase contrast which is the signature of perpendicular magnetic anisotropy. The films processed at 250oC for various time intervals show successive reduction in magnetic phase contrast and domain size. The domain pattern completely disappeared, and topography dominated mixed magnetic phase has been obtained for the films processed at 450oC for time intervals greater than 2 minutes. The magnetization measurements indicate the reduction in perpendicular magnetic anisotropy with increase in saturation magnetization for all the rapid thermal processed films. The experimental outputs have been used to simulate the domain pattern. Reduction in uniaxial anisotropy along with the increase in saturation magnetization successfully explain the experimental trend of decrease in domain size and magnetic contrast.

Research Update: Focused ion beam direct writing of magnetic patterns with controlled structural and magnetic properties

NASA Astrophysics Data System (ADS)

Urbánek, Michal; Flajšman, Lukáš; Křižáková, Viola; Gloss, Jonáš; Horký, Michal; Schmid, Michael; Varga, Peter

2018-06-01

Focused ion beam irradiation of metastable Fe78Ni22 thin films grown on Cu(100) substrates is used to create ferromagnetic, body-centered cubic patterns embedded into paramagnetic, face-centered-cubic surrounding. The structural and magnetic phase transformation can be controlled by varying parameters of the transforming gallium ion beam. The focused ion beam parameters such as the ion dose, number of scans, and scanning direction can be used not only to control a degree of transformation but also to change the otherwise four-fold in-plane magnetic anisotropy into the uniaxial anisotropy along a specific crystallographic direction. This change is associated with a preferred growth of specific crystallographic domains. The possibility to create magnetic patterns with continuous magnetization transitions and at the same time to create patterns with periodical changes in magnetic anisotropy makes this system an ideal candidate for rapid prototyping of a large variety of nanostructured samples. Namely, spin-wave waveguides and magnonic crystals can be easily combined into complex devices in a single fabrication step.

Tuning magnetic properties of magnetoelectric BiFeO 3-NiFe 2O 4 nanostructures

NASA Astrophysics Data System (ADS)

Crane, S. P.; Bihler, C.; Brandt, M. S.; Goennenwein, S. T. B.; Gajek, M.; Ramesh, R.

2009-02-01

Multifunctional thin film nanostructures containing soft magnetic materials such as nickel ferrite are interesting for potential applications in microwave signal processing because of the possibility to shrink the size of device architecture and limit device power consumption. An essential prerequisite to future applications of such a system is a firm understanding of its magnetic properties. We show that nanostructures composed of ferrimagnetic NiFe 2O 4 pillars in a multiferroic BiFeO 3 matrix can be tuned magnetically by altering the aspect ratio of the pillars by depositing films of varying thickness. Magnetic anisotropy is studied using ferromagnetic resonance, which shows that the uniaxial magnetic anisotropy in the growth direction changes sign upon increasing the film thickness. The magnitude of this anisotropy contribution can be explained via a combination of shape and magnetostatic effects, using the object-oriented micromagnetic framework (OOMMF). The key factors determining the magnetic properties of the films are shown to be the aspect ratio of individual pillars and magnetostatic interactions between neighboring pillars.

Electronic structure and magnetic anisotropy of Sm2Fe17Nx

NASA Astrophysics Data System (ADS)

Akai, Hisazumi; Ogura, Masako

2014-03-01

Electronic structure and magnetic properties of Sm2Fe17Nx are studies on the basis of the first-principles electronic structure calculation in the framework of the density functional theory within the local density and coherent potential approximations. The magnetic anisotropy of the system as a function of nitrogen concentration x is discussed by taking account not only of the crystal field effects but also of the effects of the f-electron transfer from Sm to the neighboring sites. Also discussed is the magnetic transition temperature that is estimated by mapping the system into a Heisenberg model. The results show the crystalline magnetic anisotropy changes its direction from in-plane to uniaxial ones as x increases. It takes the maximum value near x ~ 2 . 8 and then decreases slightly towards x = 3 . The mechanism for these behaviors is discussed in the light of the results of detailed calculations on the bonding properties between Sm and its neighboring N. This work was partly supported by Elements Strategy Initiative Center for Magnetic Materials Project, the Ministry of Education, Culture, Sports, Science and Technology, Japan.

Strain induced parametric pumping of a domain wall and its depinning from a notch

NASA Astrophysics Data System (ADS)

Nepal, Rabindra; Gungordu, Utkan; Kovalev, Alexey

Using Thiele's method and detailed micromagnetic simulations, we study resonant oscillation of a domain wall in a notch of a ferromagnetic nanowire due to the modulation of magnetic anisotropy by external AC strain. Such resonant oscillation results from the parametric pumping of domain wall by AC strain at frequency about double the free domain wall oscillation frequency, which is mainly determined by the perpendicular anisotropy and notch geometry. This effect leads to a substantial reduction in depinning field or current required to depin a domain wall from the notch, and offers a mechanism for efficient domain wall motion in a notched nanowire. Our theoretical model accounts for the pinning potential due to a notch by explicitly calculating ferromagnetic energy as a function of notch geometry parameters. We also find similar resonant domain wall oscillations and reduction in the domain wall depinning field or current due to surface acoustic wave in soft ferromagnetic nanowire without uniaxial anisotropy that energetically favors an in-plane domain wall. DOE Early Career Award DE-SC0014189 and DMR- 1420645.

Effect of Aerogel Anisotropy in Superfluid 3He-A

NASA Astrophysics Data System (ADS)

Zimmerman, A. M.; Li, J. I. A.; Pollanen, J.; Collett, C. A.; Gannon, W. J.; Halperin, W. P.

2014-03-01

Two theories have been advanced to describe the effects of anisotropic impurity introduced by stretched silica aerogel on the orientation of the orbital angular momentum l& circ; in superfluid 3He-A. These theories disagree on whether the anisotropy will orient l& circ; perpendicular[2] or parallel[3] to the strain axis. In order to examine this question we have produced and characterized a homogeneous aerogel sample with uniaxial anisotropy introduced during growth, corresponding to stretching of the aerogel. These samples have been shown to stabilize two new chiral states;[4] the higher temperature state being the subject of the present study. Using pulsed NMR we have performed experiments on 3He-A imbibed in this sample in two orientations: strain parallel and perpendicular to the applied magnetic field. From the NMR frequency shifts as a function of tip angle and temperature, we find that the angular momentum l& circ; is oriented along the strain axis, providing evidence for the theory advanced by Sauls. This work was supported by the National Science Foundation, DMR-1103625.

Anisotropy influence on the failure of Ti6Al4V sheets deformed at room and elevated temperature

NASA Astrophysics Data System (ADS)

Wang, Q. L.; Ghiotti, A.; Bruschi, S.

2018-05-01

Ti6Al4V sheets are usually difficult-to-form at room temperature as a consequence of their strong basal texture and hcp crystal lattice. The heating of the alloy below the beta transus temperature is recognized to enhance its formability, reducing the flow stress and increasing the ductility. However, the influence of the sheet anisotropy on the material failure hasn't been studied yet. To this aim, the paper presents the anisotropy influence on the failure characteristics of Ti6Al4V titanium alloy sheets making use of tensile tests carried out at room temperature and 600°C on smooth, notched and shear samples in order to have various stress states. The fracture strain is measured and the effect of the sample orientation and stress state is identified. To determine the actual stress state for each sample geometry, a numerical model is set up and calibrated using elasto-plastic data from uni-axial tensile tests on smooth samples. Finally, the fracture surfaces are observed through SEM analysis to explain the failure characteristics.

Dipole moment and polarizability of impurity doped quantum dots under anisotropy, spatially-varying effective mass and dielectric screening function: Interplay with noise

NASA Astrophysics Data System (ADS)

Ghosh, Anuja; Ghosh, Manas

2018-01-01

Present work explores the profiles of polarizability (αp) and electric dipole moment (μ) of impurity doped GaAs quantum dot (QD) under the aegis of spatially-varying effective mass, spatially-varying dielectric constant and anisotropy of the system. Presence of noise has also been invoked to examine how its intervention further tunes αp and μ. Noise term maintains a Gaussian white feature and it has been incorporated to the system through two different roadways; additive and multiplicative. The various facets of influence of spatially-varying effective mass, spatially-varying dielectric constant and anisotropy on αp and μ depend quite delicately on presence/absence of noise and also on the mode through which noise has been administered. The outcomes of the study manifest viable routes to harness the dipole moment and polarizability of doped QD system through the interplay between noise, anisotropy and variable effective mass and dielectric constant of the system.

Model for temperature-dependent magnetization of nanocrystalline materials

NASA Astrophysics Data System (ADS)

Bian, Q.; Niewczas, M.

2015-01-01

A magnetization model of nanocrystalline materials incorporating intragrain anisotropies, intergrain interactions, and texture effects has been extended to include the thermal fluctuations. The method relies on the stochastic Landau-Lifshitz-Gilbert theory of magnetization dynamics and permits to study the magnetic properties of nanocrystalline materials at arbitrary temperature below the Currie temperature. The model has been used to determine the intergrain exchange constant and grain boundary anisotropy constant of nanocrystalline Ni at 100 K and 298 K. It is found that the thermal fluctuations suppress the strength of the intergrain exchange coupling and also reduce the grain boundary anisotropy. In comparison with its value at 2 K, the interparticle exchange constant decreases by 16% and 42% and the grain boundary anisotropy constant decreases by 28% and 40% at 100 K and 298 K, respectively. An application of the model to study the grain size-dependent magnetization indicates that when the thermal activation energy is comparable to the free energy of grains, the decrease in the grain size leads to the decrease in the magnetic permeability and saturation magnetization. The mechanism by which the grain size influences the magnetic properties of nc-Ni is discussed.

Experimental investigation on the fracture behaviour of black shale by acoustic emission monitoring and CT image analysis during uniaxial compression

NASA Astrophysics Data System (ADS)

Wang, Y.; Li, C. H.; Hu, Y. Z.

2018-04-01

Plenty of mechanical experiments have been done to investigate the deformation and failure characteristics of shale; however, the anisotropic failure mechanism has not been well studied. Here, laboratory Uniaxial Compressive Strength tests on cylindrical shale samples obtained by drilling at different inclinations to bedding plane were performed. The failure behaviours of the shale samples were studied by real-time acoustic emission (AE) monitoring and post-test X-ray computer tomography (CT) analysis. The experimental results suggest that the pronounced bedding planes of shale have a great influence on the mechanical properties and AE patterns. The AE counts and AE cumulative energy release curves clearly demonstrate different morphology, and the `U'-shaped curve relationship between the AE counts, AE cumulative energy release and bedding inclination was first documented. The post-test CT image analysis shows the crack patterns via 2-D image reconstructions, an index of stimulated fracture density is defined to represent the anisotropic failure mode of shale. What is more, the most striking finding is that the AE monitoring results are in good agreement with the CT analysis. The structural difference in the shale sample is the controlling factor resulting in the anisotropy of AE patterns. The pronounced bedding structure in the shale formation results in an anisotropy of elasticity, strength and AE information from which the changes in strength dominate the entire failure pattern of the shale samples.

Strain Rate Effect on Tensile Flow Behavior and Anisotropy of a Medium-Manganese TRIP Steel

NASA Astrophysics Data System (ADS)

Alturk, Rakan; Hector, Louis G.; Matthew Enloe, C.; Abu-Farha, Fadi; Brown, Tyson W.

2018-06-01

The dependence of the plastic anisotropy on the nominal strain rate for a medium-manganese (10 wt.% Mn) transformation-induced plasticity (TRIP) steel with initial austenite volume fraction of 66% (balance ferrite) has been investigated. The material exhibited yield point elongation, propagative instabilities during hardening, and austenite transformation to α'-martensite either directly or through ɛ-martensite. Uniaxial strain rates within the range of 0.005-500 s-1 along the 0°, 45°, and 90° orientations were selected based upon their relevance to automotive applications. The plastic anisotropy ( r) and normal anisotropy ( r n) indices corresponding to each direction and strain rate were determined using strain fields obtained from stereo digital image correlation systems that enabled both quasistatic and dynamic measurements. The results provide evidence of significant, orientation-dependent strain rate effects on both the flow stress and the evolution of r and r n with strain. This has implications not only for material performance during forming but also for the development of future strain-rate-dependent anisotropic yield criteria. Since tensile data alone for the subject medium-manganese TRIP steel do not satisfactorily determine the microstructural mechanisms responsible for the macroscopic-scale behavior observed on tensile testing, additional tests that must supplement the mechanical test results presented herein are discussed.

Influences of vanadium on magnetocrystalline anisotropy and magnetic properties of Gd2Co17-xVx

NASA Astrophysics Data System (ADS)

Chu, W. G.; Rao, G. H.; Liu, G. Y.; Yang, H. F.; Liu, W. F.; Ouyang, Z. W.; Feng, X. M.; Liang, J. K.

2002-12-01

Single-phase Gd2Co17-xVx compounds (x=0.0-1.5) crystallizing in the rhombohedral Th2Zn17 structure have been synthesized. The lattice parameters a and c of the compounds increase linearly with increasing V content, and the rate of increase of c is about 2.5 times as large as that of a. Substitution of a small amount of V atoms (x=0.3) for Co atoms leads to the occurrence of uniaxial magnetocrystalline anisotropy of Gd2Co17-xVx. The anisotropy field HA increases drastically with increasing V content. The variations of both the lattice parameters and the magnetocrystalline anisotropy with V content suggest a preferential occupation of the V atoms at the 6c dumbbell site. The Curie temperature TC, saturation moment MS, and average Co moment <μCo> of the compounds decrease greatly as the V content increases. The rapid decrease of TC is essentially attributed to a serious weakening of the Co-Co interactions due to the preferential occupation of the V atoms at the 6c site. The effect of a strong hybridization between the V and Co atoms is plausibly responsible for the decreases of the MS and <μCo>.

Strain Rate Effect on Tensile Flow Behavior and Anisotropy of a Medium-Manganese TRIP Steel

NASA Astrophysics Data System (ADS)

Alturk, Rakan; Hector, Louis G.; Matthew Enloe, C.; Abu-Farha, Fadi; Brown, Tyson W.

2018-04-01

The dependence of the plastic anisotropy on the nominal strain rate for a medium-manganese (10 wt.% Mn) transformation-induced plasticity (TRIP) steel with initial austenite volume fraction of 66% (balance ferrite) has been investigated. The material exhibited yield point elongation, propagative instabilities during hardening, and austenite transformation to α'-martensite either directly or through ɛ-martensite. Uniaxial strain rates within the range of 0.005-500 s-1 along the 0°, 45°, and 90° orientations were selected based upon their relevance to automotive applications. The plastic anisotropy (r) and normal anisotropy (r n) indices corresponding to each direction and strain rate were determined using strain fields obtained from stereo digital image correlation systems that enabled both quasistatic and dynamic measurements. The results provide evidence of significant, orientation-dependent strain rate effects on both the flow stress and the evolution of r and r n with strain. This has implications not only for material performance during forming but also for the development of future strain-rate-dependent anisotropic yield criteria. Since tensile data alone for the subject medium-manganese TRIP steel do not satisfactorily determine the microstructural mechanisms responsible for the macroscopic-scale behavior observed on tensile testing, additional tests that must supplement the mechanical test results presented herein are discussed.

Temperature dependence of electron magnetic resonance spectra of iron oxide nanoparticles mineralized in Listeria innocua protein cages

NASA Astrophysics Data System (ADS)

Usselman, Robert J.; Russek, Stephen E.; Klem, Michael T.; Allen, Mark A.; Douglas, Trevor; Young, Mark; Idzerda, Yves U.; Singel, David J.

2012-10-01

Electron magnetic resonance (EMR) spectroscopy was used to determine the magnetic properties of maghemite (γ-Fe2O3) nanoparticles formed within size-constraining Listeria innocua (LDps)-(DNA-binding protein from starved cells) protein cages that have an inner diameter of 5 nm. Variable-temperature X-band EMR spectra exhibited broad asymmetric resonances with a superimposed narrow peak at a gyromagnetic factor of g ≈ 2. The resonance structure, which depends on both superparamagnetic fluctuations and inhomogeneous broadening, changes dramatically as a function of temperature, and the overall linewidth becomes narrower with increasing temperature. Here, we compare two different models to simulate temperature-dependent lineshape trends. The temperature dependence for both models is derived from a Langevin behavior of the linewidth resulting from "anisotropy melting." The first uses either a truncated log-normal distribution of particle sizes or a bi-modal distribution and then a Landau-Liftshitz lineshape to describe the nanoparticle resonances. The essential feature of this model is that small particles have narrow linewidths and account for the g ≈ 2 feature with a constant resonance field, whereas larger particles have broad linewidths and undergo a shift in resonance field. The second model assumes uniform particles with a diameter around 4 nm and a random distribution of uniaxial anisotropy axes. This model uses a more precise calculation of the linewidth due to superparamagnetic fluctuations and a random distribution of anisotropies. Sharp features in the spectrum near g ≈ 2 are qualitatively predicted at high temperatures. Both models can account for many features of the observed spectra, although each has deficiencies. The first model leads to a nonphysical increase in magnetic moment as the temperature is increased if a log normal distribution of particles sizes is used. Introducing a bi-modal distribution of particle sizes resolves the unphysical increase in moment with temperature. The second model predicts low-temperature spectra that differ significantly from the observed spectra. The anisotropy energy density K1, determined by fitting the temperature-dependent linewidths, was ˜50 kJ/m3, which is considerably larger than that of bulk maghemite. The work presented here indicates that the magnetic properties of these size-constrained nanoparticles and more generally metal oxide nanoparticles with diameters d < 5 nm are complex and that currently existing models are not sufficient for determining their magnetic resonance signatures.

Apparatus for measurement of acoustic wave propagation under uniaxial loading with application to measurement of third-order elastic constants of piezoelectric single crystals.

PubMed

Zhang, Haifeng; Kosinski, J A; Karim, Md Afzalul

2013-05-01

We describe an apparatus for the measurement of acoustic wave propagation under uniaxial loading featuring a special mechanism designed to assure a uniform mechanical load on a cube-shaped sample of piezoelectric material. We demonstrate the utility of the apparatus by determining the effects of stresses on acoustic wave speed, which forms a foundation for the final determination of the third-order elastic constants of langasite and langatate single crystals. The transit time method is used to determine changes in acoustic wave velocity as the loading is varied. In order to minimize error and improve the accuracy of the wave speed measurements, the cross correlation method is used to determine the small changes in the time of flight. Typical experimental results are presented and discussed.

Anisotropic Constitutive Relationships in Energetic Materials: Nitromethane and Rdx

NASA Astrophysics Data System (ADS)

Oleynik, I. I.; Conroy, M.; White, C. T.

2007-12-01

The anisotropic constitutive relationships in solid nitromethane (NM) and α-RDX were studied using first-principles density functional theory (DFT). In addition to hydrostatic compressions, we performed uniaxial compressions in the [100], [010], [001], [110], [101], [011], and [111] directions up to the compression ratio V/V0 = 0.70. Equilibrium properties, including lattice parameters and elastic constants, as well as hydrostatic EOS, are in good agreement with available experimental data. The shear stresses of uniaxially compressed NM and α-RDX were used to predict the relative shock sensitivity between different crystallographic directions.

Effect of Stress Triaxiality on the Flow and Fracture of Mg Alloy AZ31

NASA Astrophysics Data System (ADS)

Kondori, Babak; Benzerga, A. Amine

2014-07-01

The microscopic damage mechanisms operating in a hot-rolled magnesium alloy AZ31B are investigated under both uniaxial and controlled triaxial loadings. Their connection to macroscopic fracture strains and fracture mode (normal vs shear) is elucidated using postmortem fractography, interrupted tests, and microscopic analysis. The fracture locus (strain-to-failure vs stress triaxiality) exhibits a maximum at moderate triaxiality, and the strain-to-failure is found to be greater in notched specimens than in initially smooth ones. A transition from twinning-induced fracture under uniaxial loading to microvoid coalescence fracture under triaxial loading is evidenced. It is argued that this transition accounts in part for the observed greater ductility in notched bars. The evolution of plastic anisotropy with stress triaxiality is also investigated. It is inferred that anisotropic plasticity at a macroscopic scale suffices to account for the observed transition in the fracture mode from flat (triaxial loading) to shear-like (uniaxial loading). Damage is found to initiate at second-phase particles and deformation twins. Fracture surfaces of broken specimens exhibit granular morphology, coarse splits, twin-sized crack traces, as well as shallow and deep dimples, in proportions that depend on the overall stress triaxiality and fracture mode. An important finding is that AZ31B has a greater tolerance to ductile damage accumulation than has been believed thus far, based on the fracture behavior in uniaxial specimens. Another finding, common to both tension and compression, is the increase in volumetric strain, the microscopic origins of which remain to be elucidated.

Uniaxial magnetic anisotropy energy of Fe wires embedded in carbon nanotubes.

PubMed

Muñoz, Francisco; Mejía-López, Jose; Pérez-Acle, Tomas; Romero, Aldo H

2010-05-25

In this work, we analyze the magnetic anisotropy energy (MAE) of Fe cylinders embedded within zigzag carbon nanotubes, by means of ab initio calculations. To see the influence of the confinement, we fix the Fe cylinder diameter and we follow the changes of the MAE as a function of the diameter of the nanotube, which contains the Fe cylinder. We find that the easy axis changes from parallel to perpendicular, with respect to the cylinder axis. The orientation change depends quite strongly on the confinement, which indicates a nontrivial dependence of the magnetization direction as function of the nanotube diameter. We also find that the MAE is affected by where the Fe cylinder sits with respect to the carbon nanotube, and the coupling between these two structures could also dominate the magnetic response. We analyze the thermal stability of the magnetization orientation of the Fe cylinder close to room temperature.

New structures of Fe3S for rare-earth-free permanent magnets

NASA Astrophysics Data System (ADS)

Yu, Shu; Zhao, Xin; Wu, Shunqing; Nguyen, Manh Cuong; Zhu, Zi-zhong; Wang, Cai-Zhuang; Ho, Kai-Ming

2018-02-01

We applied an adaptive genetic algorithm (AGA) to search for low-energy crystal structures of Fe3S. A number of structures with energies lower than that of the experimentally reported Pnma and I-4 structures have been obtained from our AGA searches. These low-energy structures can be classified as layer-motif and column-motif structures. In the column-motif structures, Fe atoms self-assemble into rods with a bcc type of underlying lattice, which are separated by the holes terminated by S atoms. In the layer-motif structures, the bulk Fe is broken into slabs of several layers passivated by S atoms. Magnetic property calculations showed that the column-motif structures exhibit reasonably high uniaxial magnetic anisotropy. In addition, we examined the effect of Co doping to Fe3S and found that magnetic anisotropy can be enhanced through Co doping.

Effect of spacer layer on the magnetization dynamics of permalloy/rare-earth/permalloy trilayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luo, Chen, E-mail: ronanluochen@gmail.com; Yin, Yuli; Zhang, Dong

2015-05-07

The permalloy/rare-earth/permalloy trilayers with different types (Gd and Nd) and thicknesses of spacer layer are investigated using frequency dependence of ferromagnetic resonance (FMR) measurements at room temperature, which shows different behaviors with different rare earth spacer layers. By fitting the frequency dependence of the FMR resonance field and linewidth, we find that the in-plane uniaxial anisotropy retains its value for all samples, the perpendicular anisotropy remains almost unchanged for different thickness of Gd layer but the values are tailored by different thicknesses of Nd layer. The Gilbert damping is almost unchanged with different thicknesses of Gd; however, the Gilbert dampingmore » is significantly enhanced from 8.4×10{sup −3} to 20.1×10{sup −3} with 6 nm of Nd and then flatten out when the Nd thickness rises above 6 nm.« less

New structures of Fe3S for rare-earth-free permanent magnets

DOE PAGES

Yu, Shu; Zhao, Xin; Wu, Shunqing; ...

2018-02-25

We applied adaptive genetic algorithm (AGA) to search for low-energy crystal structures of Fe 3S. A number of structures with energies lower than that of the experimentally reported Pnma and I-4 structures have been obtained from our AGA searches. These low-energy structures can be classified as layer-motif and column-motif structures. In the column-motif structures, Fe atoms self-assemble into rods with bcc type of underlying lattice, which are separated by the holes terminated by S atoms. In the layer-motif structures, the bulk Fe is broken into slabs of several layers passivated by S atoms. Magnetic properties calculations showed that the column-motifmore » structures exhibit reasonably high uniaxial magnetic anisotropy. In addition, we examined the effect of Co doping to Fe 3S and found magnetic anisotropy can be enhanced through Co doping.« less

Brownian motion and entropic torque driven motion of domain walls in antiferromagnets

NASA Astrophysics Data System (ADS)

Yan, Zhengren; Chen, Zhiyuan; Qin, Minghui; Lu, Xubing; Gao, Xingsen; Liu, Junming

2018-02-01

We study the spin dynamics in antiferromagnetic nanowire under an applied temperature gradient using micromagnetic simulations on a classical spin model with a uniaxial anisotropy. The entropic torque driven domain-wall motion and the Brownian motion are discussed in detail, and their competition determines the antiferromagnetic wall motion towards the hotter or colder region. Furthermore, the spin dynamics in an antiferromagnet can be well tuned by the anisotropy and the temperature gradient. Thus, this paper not only strengthens the main conclusions obtained in earlier works [Kim et al., Phys. Rev. B 92, 020402(R) (2015), 10.1103/PhysRevB.92.020402; Selzer et al., Phys. Rev. Lett. 117, 107201 (2016), 10.1103/PhysRevLett.117.107201], but more importantly gives the concrete conditions under which these conclusions apply, respectively. Our results may provide useful information on the antiferromagnetic spintronics for future experiments and storage device design.

Electrical Transport on the Shastry-Sutherland Lattice in Ising-type Rare Earth Tetraborides

NASA Astrophysics Data System (ADS)

Ye, Linda; Suzuki, Takehito; Checkelsky, Joseph. G.

In the presence of a magnetic field, frustrated spin systems may exhibit plateaus at fractional values of their saturation magnetization. Study of the magnetic ordering and excitations at such plateaus are key to understanding the nature of the underlying ground states in these systems. Here we study the magnetization plateaus in metallic rare earth tetraborides RB4 with Ising-type anisotropy (R = Er, Tm) in which R resides on a Shastry-Sutherland lattice. We focus on electrical transport and find that the response reflects scattering of charge carriers with the static and dynamic plateau structure. Modeling of these results is consistent with the expected strong uniaxial anisotropy and provides a framework for the study of plateau states in metallic frustrated systems. We thank NSF Grant No. DMR-1231319, Tsinghua Education Foundation, Moore foundation Grant No. GBMF3848 for support.

Linear stability analysis of a levitated nanomagnet in a static magnetic field: Quantum spin stabilized magnetic levitation

NASA Astrophysics Data System (ADS)

Rusconi, C. C.; Pöchhacker, V.; Cirac, J. I.; Romero-Isart, O.

2017-10-01

We theoretically study the levitation of a single magnetic domain nanosphere in an external static magnetic field. We show that, apart from the stability provided by the mechanical rotation of the nanomagnet (as in the classical Levitron), the quantum spin origin of its magnetization provides two additional mechanisms to stably levitate the system. Despite the Earnshaw theorem, such stable phases are present even in the absence of mechanical rotation. For large magnetic fields, the Larmor precession of the quantum magnetic moment stabilizes the system in full analogy with magnetic trapping of a neutral atom. For low magnetic fields, the magnetic anisotropy stabilizes the system via the Einstein-de Haas effect. These results are obtained with a linear stability analysis of a single magnetic domain rigid nanosphere with uniaxial anisotropy in a Ioffe-Pritchard magnetic field.

Effects of external magnetic field and magnetic anisotropy on chiral spin structures of square nanodisks investigated with a quantum simulation approach

NASA Astrophysics Data System (ADS)

Liu, Zhaosen; Ian, Hou

2016-04-01

We employed a quantum simulation approach to investigate the magnetic properties of monolayer square nanodisks with Dzyaloshinsky-Moriya (DM) interaction. The computational program converged very quickly, and generated chiral spin structures on the disk planes with good symmetry. When the DM interaction is sufficiently strong, multi-domain structures appears, their sizes or average distance between each pair of domains can be approximately described by a modified grid theory. We further found that the external magnetic field and uniaxial magnetic anisotropy both normal to the disk plane lead to reductions of the total free energy and total energy of the nanosystems, thus are able to stabilize and/or induce the vortical structures, however, the chirality of the vortex is still determined by the sign of the DM interaction parameter. Moreover, the geometric shape of the nanodisk affects the spin configuration on the disk plane as well.

Effects of Dzyaloshinsky-Moriya interaction on magnetism in nanodisks from a self-consistent approach

NASA Astrophysics Data System (ADS)

Liu, Zhaosen; Ian, Hou

2016-01-01

We give a theoretical study on the magnetic properties of monolayer nanodisks with both Heisenberg exchange and Dzyaloshinsky-Moriya (DM) interactions. In particular, we survey the magnetic effects caused by anisotropy, external magnetic field, and disk size when DM interaction is present by means of a new quantum simulation method facilitated by a self-consistent algorithm based on mean field theory. This computational approach finds that uniaxial anisotropy and transversal magnetic field enhance the net magnetization as well as increase the transition temperature of the vortical phase while preserving the chiralities of the swirly magnetic structures, whereas when the strength of DM interaction is sufficiently strong for a given disk size, magnetic domains appear within the circularly bounded region, which vanish and give in to a single vortex when a transversal magnetic field is applied. The latter confirms the magnetic skyrmions induced by the magnetic field as observed in the experiments.

Prediction of hole expansion ratio for various steel sheets based on uniaxial tensile properties

NASA Astrophysics Data System (ADS)

Kim, Jae Hyung; Kwon, Young Jin; Lee, Taekyung; Lee, Kee-Ahn; Kim, Hyoung Seop; Lee, Chong Soo

2018-01-01

Stretch-flangeability is one of important formability parameters of thin steel sheets used in the automotive industry. There have been many attempts to predict hole expansion ratio (HER), a typical term to evaluate stretch-flangeability, using uniaxial tensile properties for convenience. This paper suggests a new approach that uses total elongation and average normal anisotropy to predict HER of thin steel sheets. The method provides a good linear relationship between HER of the machined hole and the predictive variables in a variety of materials with different microstructures obtained using different processing methods. The HER of the punched hole was also well predicted using the similar approach, which reflected only the portion of post uniform elongation. The physical meaning drawn by our approach successfully explained the poor HER of austenitic steels despite their considerable elongation. The proposed method to predict HER is simple and cost-effective, so it will be useful in industry. In addition, the model provides a physical explanation of HER, so it will be useful in academia.

Exploration of Fermi-Pasta-Ulam Behavior in a Magnetic System

NASA Astrophysics Data System (ADS)

Lewis, Jeramy; Camley, Robert E.; Anderson, Nicholas R.

2018-04-01

We study nonlinear spin motion in one-dimensional magnetic chains. We find significant differences from the classic Fermi-Pasta-Ulam (FPU) problem examining nonlinear elastic motion in a chain. We find that FPU behavior, the transfer of energy among low order eigenmodes, does not occur in magnetic systems with only exchange and external fields, but does exist if a uniaxial anisotropy is also present. The FPU behavior may be altered or turned off through the magnitude and orientation of an external magnetic field. A realistic micromagnetic model shows such behavior could be measurable.

Structure and elasticity of phlogopite under compression: Geophysical implications

NASA Astrophysics Data System (ADS)

Chheda, Tanvi D.; Mookherjee, Mainak; Mainprice, David; dos Santos, Antonio M.; Molaison, Jamie J.; Chantel, Julien; Manthilake, Geeth; Bassett, William A.

2014-08-01

We investigated the response of the crystal structure, lattice parameters, and unit-cell volume of hydrous layered silicate phlogopite at conditions relevant to subduction zone settings. We have used first principles simulation based on density functional theory to calculate the equation of state and full elastic constant tensor. Based on the generalized gradient approximation, the full single crystal elastic constant tensor with monoclinic symmetry shows significant anisotropy with the compressional elastic constants: c11 = 181 GPa, c22 = 185 GPa, c33 = 62 GPa, the shear elastic constants c44 = 14 GPa, c55 = 20 GPa, c66 = 68 Ga, and c46 = -6 GPa; the off diagonal elastic constants c12 = 48 GPa, c13 = 12 GPa, c23 = 12 GPa, c15 = -16 GPa, c25 = -5 GPa and c35 = -1 GPa at zero pressure. The elastic anisotropy of phlogopite is larger than most of the layered hydrous phases relevant in the subduction zone conditions. The shear anisotropy, AVS for phlogopite is ∼77% at zero pressure condition and although it decreases upon compression it remains relatively high compared to other hydrous phases relevant in the subduction zone settings. We also note that the shear elastic constants for phlogopite are relatively low. Phlogopite also has a high isotropic bulk VP/VS ratio ∼2.0. However, the VP/VS ratio also exhibits significant anisotropy with values as low as 1.49. Thus, phlogopite bearing metasomatized mantle could readily explain unusual VP/VS ratio as observed from seismological studies from the mantle wedge regions of the subduction zone.

Spin-Orbit Torque-Assisted Switching in Magnetic Insulator Thin Films with Perpendicular Magnetic Anisotropy

NASA Astrophysics Data System (ADS)

Wu, Mingzhong

As an in-plane charge current flows in a heavy metal film with spin-orbit coupling, it produces a torque that can induce magnetization switching in a neighboring ferromagnetic metal film. Such spin-orbit torque (SOT)-induced switching has been studied extensively in recent years and has shown higher efficiency than switching using conventional spin-transfer torque. This presentation reports the SOT-assisted switching in heavy metal/magnetic insulator systems.1 The experiments made use of Pt/BaFe12O19 bi-layered structures. Thanks to its strong spin-orbit coupling, Pt has been widely used to produce pure spin currents in previous studies. BaFe12O19 is an M-type barium hexagonal ferrite and is often referred as BaM. It is one of the few magnetic insulators with strong magneto-crystalline anisotropy and shows an effective uniaxial anisotropy field of about 17 kOe. It's found that the switching response in the BaM film strongly depends on the charge current applied to the Pt film. When a constant magnetic field is applied in the film plane, the charge current in the Pt film can switch the normal component of the magnetization (M⊥) in the BaM film between the up and down states. The current also dictates the up and down states of the remnant magnetization when the in-plane field is reduced to zero. When M⊥ is measured by sweeping an in-plane field, the response manifests itself as a hysteresis loop, which evolves in a completely opposite manner if the sign of the charge current is flipped. When the coercivity is measured by sweeping an out-of-plane field, its value can be reduced or increased by as much as about 500 Oe if an appropriate charge current is applied. 1. P. Li, T. Liu, H. Chang, A. Kalitsov, W. Zhang, G. Csaba, W. Li, D. Richardson, A. Demann, G. Rimal, H. Dey, J. S. Jiang, W. Porod, S. Field, J. Tang, M. C. Marconi, A. Hoffmann, O. Mryasov, and M. Wu, Nature Commun. 7:12688 doi: 10.1038/ncomms12688 (2016).

Mathematical Model Relating Uniaxial Compressive Behavior of Manufactured Sand Mortar to MIP-Derived Pore Structure Parameters

PubMed Central

Tian, Zhenghong; Bu, Jingwu

2014-01-01

The uniaxial compression response of manufactured sand mortars proportioned using different water-cement ratio and sand-cement ratio is examined. Pore structure parameters such as porosity, threshold diameter, mean diameter, and total amounts of macropores, as well as shape and size of micropores are quantified by using mercury intrusion porosimetry (MIP) technique. Test results indicate that strains at peak stress and compressive strength decreased with the increasing sand-cement ratio due to insufficient binders to wrap up entire sand. A compression stress-strain model of normal concrete extending to predict the stress-strain relationships of manufactured sand mortar is verified and agreed well with experimental data. Furthermore, the stress-strain model constant is found to be influenced by threshold diameter, mean diameter, shape, and size of micropores. A mathematical model relating stress-strain model constants to the relevant pore structure parameters of manufactured sand mortar is developed. PMID:25133257

Mathematical model relating uniaxial compressive behavior of manufactured sand mortar to MIP-derived pore structure parameters.

PubMed

Tian, Zhenghong; Bu, Jingwu

2014-01-01

The uniaxial compression response of manufactured sand mortars proportioned using different water-cement ratio and sand-cement ratio is examined. Pore structure parameters such as porosity, threshold diameter, mean diameter, and total amounts of macropores, as well as shape and size of micropores are quantified by using mercury intrusion porosimetry (MIP) technique. Test results indicate that strains at peak stress and compressive strength decreased with the increasing sand-cement ratio due to insufficient binders to wrap up entire sand. A compression stress-strain model of normal concrete extending to predict the stress-strain relationships of manufactured sand mortar is verified and agreed well with experimental data. Furthermore, the stress-strain model constant is found to be influenced by threshold diameter, mean diameter, shape, and size of micropores. A mathematical model relating stress-strain model constants to the relevant pore structure parameters of manufactured sand mortar is developed.

Shock-induced transformations in crystalline RDX: a uniaxial constant-stress Hugoniostat molecular dynamics simulation study.

PubMed

Bedrov, Dmitry; Hooper, Justin B; Smith, Grant D; Sewell, Thomas D

2009-07-21

Molecular dynamics (MD) simulations of uniaxial shock compression along the [100] and [001] directions in the alpha polymorph of hexahydro-1,3,5-trinitro-1,3,5-triazine (alpha-RDX) have been conducted over a wide range of shock pressures using the uniaxial constant stress Hugoniostat method [Ravelo et al., Phys. Rev. B 70, 014103 (2004)]. We demonstrate that the Hugoniostat method is suitable for studying shock compression in atomic-scale models of energetic materials without the necessity to consider the extremely large simulation cells required for an explicit shock wave simulation. Specifically, direct comparison of results obtained using the Hugoniostat approach to those reported by Thompson and co-workers [Phys. Rev. B 78, 014107 (2008)] based on large-scale MD simulations of shocks using the shock front absorbing boundary condition (SFABC) approach indicates that Hugoniostat simulations of systems containing several thousand molecules reproduced the salient features observed in the SFABC simulations involving roughly a quarter-million molecules, namely, nucleation and growth of nanoscale shear bands for shocks propagating along the [100] direction and the polymorphic alpha-gamma phase transition for shocks directed along the [001] direction. The Hugoniostat simulations yielded predictions of the Hugoniot elastic limit for the [100] shock direction consistent with SFABC simulation results.

Modeling the electrical resistance of gold film conductors on uniaxially stretched elastomeric substrates

NASA Astrophysics Data System (ADS)

Cao, Wenzhe; Görrn, Patrick; Wagner, Sigurd

2011-05-01

The electrical resistance of gold film conductors on polydimethyl siloxane substrates at stages of uniaxial stretching is measured and modeled. The surface area of a gold conductor is assumed constant during stretching so that the exposed substrate takes up all strain. Sheet resistances are calculated from frames of scanning electron micrographs by numerically solving for the electrical potentials of all pixels in a frame. These sheet resistances agree sufficiently well with values measured on the same conductors to give credence to the model of a stretchable network of gold links defined by microcracks.

Evolution of plastic anisotropy for high-strain-rate computations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schiferl, S.K.; Maudlin, P.J.

1994-12-01

A model for anisotropic material strength, and for changes in the anisotropy due to plastic strain, is described. This model has been developed for use in high-rate, explicit, Lagrangian multidimensional continuum-mechanics codes. The model handles anisotropies in single-phase materials, in particular the anisotropies due to crystallographic texture--preferred orientations of the single-crystal grains. Textural anisotropies, and the changes in these anisotropies, depend overwhelmingly no the crystal structure of the material and on the deformation history. The changes, particularly for a complex deformations, are not amenable to simple analytical forms. To handle this problem, the material model described here includes a texturemore » code, or micromechanical calculation, coupled to a continuum code. The texture code updates grain orientations as a function of tensor plastic strain, and calculates the yield strength in different directions. A yield function is fitted to these yield points. For each computational cell in the continuum simulation, the texture code tracks a particular set of grain orientations. The orientations will change due to the tensor strain history, and the yield function will change accordingly. Hence, the continuum code supplies a tensor strain to the texture code, and the texture code supplies an updated yield function to the continuum code. Since significant texture changes require relatively large strains--typically, a few percent or more--the texture code is not called very often, and the increase in computer time is not excessive. The model was implemented, using a finite-element continuum code and a texture code specialized for hexagonal-close-packed crystal structures. The results for several uniaxial stress problems and an explosive-forming problem are shown.« less

Magnetic domain interactions of Fe3O4 nanoparticles embedded in a SiO2 matrix.

PubMed

Fuentes-García, J A; Diaz-Cano, A I; Guillen-Cervantes, A; Santoyo-Salazar, J

2018-03-23

Currently, superparamagnetic functionalized systems of magnetite (Fe 3 O 4 ) nanoparticles (NPs) are promising options for applications in hyperthermia therapy, drug delivery and diagnosis. Fe 3 O 4 NPs below 20 nm have stable single domains (SSD), which can be oriented by magnetic field application. Dispersion of Fe 3 O 4 NPs in silicon dioxide (SiO 2 ) matrix allows local SSD response with uniaxial anisotropy and orientation to easy axis, 90° <001> or 180° <111>. A successful, easy methodology to produce Fe 3 O 4 NPs (6-17 nm) has been used with the Stöber modification. NPs were embedded in amorphous and biocompatible SiO 2 matrix by mechanical stirring in citrate and tetraethyl orthosilicate (TEOS). Fe 3 O 4 NPs dispersion was sampled in the range of 2-12 h to observe the SiO 2 matrix formation as time function. TEM characterization identified optimal conditions at 4 h stirring for separation of SSD Fe 3 O 4 in SiO 2 matrix. Low magnetization (M s ) of 0.001 emu and a coercivity (H c ) of 24.75 Oe indicate that the embedded SSD Fe 3 O 4 in amorphous SiO 2 reduces the M s by a diamagnetic barrier. Magnetic force microscopy (MFM) showed SSD Fe 3 O 4 of 1.2 nm on average embedded in SiO 2 matrix with uniaxial anisotropy response according to Fe 3+ and Fe 2+ electron spin coupling and rotation by intrinsic Neél contribution.

Ferroelectric materials for applications in sensor protection

NASA Astrophysics Data System (ADS)

Bhalla, Amar S.; Cross, L. Eric

1995-07-01

The focus of this program has been upon producing and characterizing new functional materials whose properties can be fine tuned to provide eye sensor protection against laser threats and to suit a range of optoelectronic device applications. Material systems that maximize orientational anisotropy (for use in scattering mode systems) and systems that minimize orientational anisotropy (for use in high field modulators and field induced photorefractive applications) were both approached. Relaxor ferroelectric tungsten bronze single crystals (Sr,Ba)Nb2O6 and (Pb,Ba)Nb2O6 solid solution families and relaxor ferroelectric perovskite (1-x)Pb(Mg(1/3)Nb(2/3))O(3-x)PbTiO3 (PMN-PT) families, were studied extensively. The unique capabilities of a laser heated pedestal growth (LHPG) system were utilized for growth of new materials in single crystal fiber form that produces crystals of long interaction length for optical wave in the crystal and high crystal perfection with maximized properties along chosen directions. Hot uniaxial pressing, hot forging, or appropriate solid state reaction processing methods were used to produce transparent polycrystalline ceramics to provide low scattering, high anisotropy ceramics or high scattering, high anisotropy ceramics. This final report summarizes significant results produced from this program through combination of experimental and crystal chemistry approaches in this field, delineates conclusions drawn from the research, and provides recommendations for future research.

Quantum phase transitions driven by rhombic-type single-ion anisotropy in the S =1 Haldane chain

NASA Astrophysics Data System (ADS)

Tzeng, Yu-Chin; Onishi, Hiroaki; Okubo, Tsuyoshi; Kao, Ying-Jer

2017-08-01

The spin-1 Haldane chain is an example of the symmetry-protected-topological (SPT) phase in one dimension. Experimental realization of the spin chain materials usually involves both the uniaxial-type, D (Sz)2 , and the rhombic-type, E [(Sx)2-(Sy)2] , single-ion anisotropies. Here, we provide a precise ground-state phase diagram for a spin-1 Haldane chain with these single-ion anisotropies. Using quantum numbers, we find that the Z2 symmetry breaking phase can be characterized by double degeneracy in the entanglement spectrum. Topological quantum phase transitions take place on particular paths in the phase diagram, from the Haldane phase to the large-Ex, large-Ey, or large-D phases. The topological critical points are determined by the level spectroscopy method with a newly developed parity technique in the density matrix renormalization group [Phys. Rev. B 86, 024403 (2012), 10.1103/PhysRevB.86.024403], and the Haldane-large-D critical point is obtained with an unprecedented precision, (D/J ) c=0.9684713 (1 ) . Close to this critical point, a small rhombic single-ion anisotropy |E |/J ≪1 can destroy the Haldane phase and bring the system into a y -Néel phase. We propose that the compound [Ni (HF2) (3-Clpy ) 4] BF4 is a candidate system to search for the y -Néel phase.

Strong anisotropy and magnetostriction in the two-dimensional Stoner ferromagnet Fe 3 GeTe 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhuang, Houlong L.; Kent, P. R. C.; Hennig, Richard G.

Comore » mputationally characterizing magnetic properies of novel two-dimensional (2D) materials serves as an important first step of exploring possible applications. Using density-functional theory, we show that single-layer Fe 3 GeTe 2 is a potential 2D material with sufficiently low formation energy to be synthesized by mechanical exfoliation from the bulk phase with a van der Waals layered structure. In addition, we calculated the phonon dispersion demonstrating that single-layer Fe 3 GeTe 2 is dynamically stable. Furthermore, we find that similar to the bulk phase, 2D Fe 3 GeTe 2 exhibits amagnetic moment that originates from a Stoner instability. In contrast to other 2D materials, we find that single-layer Fe 3 GeTe 2 exhibits a significant uniaxial magnetocrystalline anisotropy energy of 920μ eV per Fe atom originating from spin-orbit coupling. In conclusion, we show that applying biaxial tensile strains enhances the anisotropy energy, which reveals strong magnetostriction in single-layer Fe 3 GeTe 2 with a sizable magneostrictive coefficient. Our results indicate that single-layer Fe 3 GeTe 2 is potentially useful for magnetic storage applications.« less

Strong anisotropy and magnetostriction in the two-dimensional Stoner ferromagnet Fe 3 GeTe 2

DOE PAGES

Zhuang, Houlong L.; Kent, P. R. C.; Hennig, Richard G.

2016-04-06

Comore » mputationally characterizing magnetic properies of novel two-dimensional (2D) materials serves as an important first step of exploring possible applications. Using density-functional theory, we show that single-layer Fe 3 GeTe 2 is a potential 2D material with sufficiently low formation energy to be synthesized by mechanical exfoliation from the bulk phase with a van der Waals layered structure. In addition, we calculated the phonon dispersion demonstrating that single-layer Fe 3 GeTe 2 is dynamically stable. Furthermore, we find that similar to the bulk phase, 2D Fe 3 GeTe 2 exhibits amagnetic moment that originates from a Stoner instability. In contrast to other 2D materials, we find that single-layer Fe 3 GeTe 2 exhibits a significant uniaxial magnetocrystalline anisotropy energy of 920μ eV per Fe atom originating from spin-orbit coupling. In conclusion, we show that applying biaxial tensile strains enhances the anisotropy energy, which reveals strong magnetostriction in single-layer Fe 3 GeTe 2 with a sizable magneostrictive coefficient. Our results indicate that single-layer Fe 3 GeTe 2 is potentially useful for magnetic storage applications.« less

Annealing and thickness effects on magnetic properties of Co2FeAl alloy films

NASA Astrophysics Data System (ADS)

Wang, Ke; Xu, Zhan; Ling, Fujin; Wang, Yahong; Dong, Shuo

2018-03-01

Co2FeAl (CFA) films in a wide thickness range between 2 and 100 nm are sputtered at room temperature. Perpendicular magnetic anisotropy (PMA) is achieved in the annealed structure of Pd/CFA/MgO with CFA thickness ranging between 2.3 and 4.9 nm. PMA as high as 2 × 106 erg/cm3 is demonstrated in the structures annealed in the temperature range between 300 and 350 °C. Positive contributions to the PMA made by the interfaces of Pd/CFA and CFA/MgO are identified. For the as-deposited structure of MgO/CFA/Ta with thick CFA alloy up to 5 nm or above a high effective saturation magnetization of 983.9 ± 30.1 emu/cc is derived from the fitting and an in-plane uniaxial magnetic anisotropy of 104 erg/cm3 in magnitude is revealed by angular dependent magnetic measurements. In addition to the increase in saturation magnetization, a fourfold cubic magnetic anisotropy is found to develop with annealing, in line with the improvement of the crystalline structure confirmed by X-ray diffraction measurements. Out results provide some useful information for the design of the CFA-based magnetoelectronic devices.

Failure of the Porcine Ascending Aorta: Multidirectional Experiments and a Unifying Microstructural Model

PubMed Central

Witzenburg, Colleen M.; Dhume, Rohit Y.; Shah, Sachin B.; Korenczuk, Christopher E.; Wagner, Hallie P.; Alford, Patrick W.; Barocas, Victor H.

2017-01-01

The ascending thoracic aorta is poorly understood mechanically, especially its risk of dissection. To make better predictions of dissection risk, more information about the multidimensional failure behavior of the tissue is needed, and this information must be incorporated into an appropriate theoretical/computational model. Toward the creation of such a model, uniaxial, equibiaxial, peel, and shear lap tests were performed on healthy porcine ascending aorta samples. Uniaxial and equibiaxial tests showed anisotropy with greater stiffness and strength in the circumferential direction. Shear lap tests showed catastrophic failure at shear stresses (150–200 kPa) much lower than uniaxial tests (750–2500 kPa), consistent with the low peel tension (∼60 mN/mm). A novel multiscale computational model, including both prefailure and failure mechanics of the aorta, was developed. The microstructural part of the model included contributions from a collagen-reinforced elastin sheet and interlamellar connections representing fibrillin and smooth muscle. Components were represented as nonlinear fibers that failed at a critical stretch. Multiscale simulations of the different experiments were performed, and the model, appropriately specified, agreed well with all experimental data, representing a uniquely complete structure-based description of aorta mechanics. In addition, our experiments and model demonstrate the very low strength of the aorta in radial shear, suggesting an important possible mechanism for aortic dissection. PMID:27893044

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnston, David C.

Here, the influence of uniaxial single-ion anisotropy –DS 2 z on the magnetic and thermal properties of Heisenberg antiferromagnets (AFMs) is investigated. The uniaxial anisotropy is treated exactly and the Heisenberg interactions are treated within unified molecular field theory (MFT), where thermodynamic variables are expressed in terms of directly measurable parameters. The properties of collinear AFMs with ordering along the z axis (D>0) in applied field H z = 0 are calculated versus D and temperature T, including the ordered moment μ, the Néel temperature T N, the magnetic entropy, internal energy, heat capacity, and the anisotropic magnetic susceptibilities χmore » ∥ and χ ⊥ in the paramagnetic (PM) and AFM states. The high-field average magnetization per spin μ z(H z,D,T) is found, and the critical field H c(D,T) is derived at which the second-order AFM to PM phase transition occurs. The magnetic properties of the spin-flop (SF) phase are calculated, including the zero-field properties T N(D) and μ(D,T). The high-field μ z(H z,D,T) is determined, together with the associated spin-flop field H SF(D,T) at which a second-order SF to PM phase transition occurs. The free energies of the AFM, SF, and PM phases are derived from which H z–T phase diagrams are constructed. For f J =–1 and –0.75, where f J = θ pJ/T NJ and θ pJ and T NJ are the Weiss temperature in the Curie-Weiss law and the Néel temperature due to exchange interactions alone, respectively, phase diagrams in the H z–T plane similar to previous results are obtained. However, for f J = 0 we find a topologically different phase diagram where a spin-flop bubble with PM and AFM boundaries occurs at finite H z and T. Also calculated are properties arising from a perpendicular magnetic field, including the perpendicular susceptibility χ ⊥(D,T), the associated effective torque at low fields arising from the –DS 2 z term in the Hamiltonian, the high-field perpendicular magnetization μ ⊥, and the perpendicular critical field H c⊥ at which the second-order AFM to PM phase transition occurs. In addition to the above results for D > 0, the T N(D) and ordered moment μ(T,D) for collinear AFM ordering along the x axis with D < 0 are determined. In order to compare the properties of the above spin systems with those of noninteracting systems with –DS 2 z uniaxial anisotropy with either sign of D, Supplemental Material is provided in which results for the thermal and magnetic properties of such noninteracting spin systems are given.« less

Elasticity, slowness, thermal conductivity and the anisotropies in the Mn3Cu1-xGexN compounds

NASA Astrophysics Data System (ADS)

Li, Guan-Nan; Chen, Zhi-Qian; Lu, Yu-Ming; Hu, Meng; Jiao, Li-Na; Zhao, Hao-Ting

2018-03-01

We perform the first-principles to systematically investigate the elastic properties, minimum thermal conductivity and anisotropy of the negative thermal expansion compounds Mn3Cu1-xGexN. The elastic constant, bulk modulus, shear modulus, Young’s modulus and Poisson ratio are calculated for all the compounds. The results of the elastic constant indicate that all the compounds are mechanically stable and the doped Ge can adjust the ductile character of the compounds. According to the values of the percent ratio of the elastic anisotropy AB, AE and AG, shear anisotropic factors A1, A2 and A3, all the Mn3Cu1-xGexN compounds are elastic anisotropy. The three-dimensional diagrams of elastic moduli in space also show that all the compounds are elastic anisotropy. In addition, the acoustic wave speed, slowness, minimum thermal conductivity and Debye temperature are also calculated. When the ratio of content for Cu and Ge arrived to 1:1, the compound has the lowest thermal conductivity and the highest Debye temperature.

The phonon-polariton spectrum of one-dimensional Rudin-Shapiro photonic superlattices with uniaxial polar materials

NASA Astrophysics Data System (ADS)

Gómez-Urrea, H. A.; Duque, C. A.; Mora-Ramos, M. E.

2015-11-01

The properties of the optical-phonon-associated polaritonic modes that appear under oblique light incidence in 1D superlattices made of photonic materials are studied. The investigated systems result from the periodic repetition of quasiregular Rudin-Shapiro (RS) multilayer units. It is assume that the structure consists of both passive non-dispersive layers of constant refraction index and active layers of uniaxial polar materials. In particular, we consider III-V wurtzite nitrides. The optical axis of these polaritonic materials is taken along the growth direction. Maxwell equations are solved using the transfer matrix technique for all admissible values of the incidence angle.

Structure of vortices in superfluid 3He A-like phase in uniaxially stretched aerogel

NASA Astrophysics Data System (ADS)

Aoyama, Kazushi; Ikeda, Ryusuke

2009-02-01

Possible vortex-core transitions in A-like phase of superfluid 3He in uniaxially stretched aerogel are investigated. Since the global anisotropy in this system induces the polar pairing state in a narrow range close to the superfluid transition in addition to the A-like and B-like phases, the polar state may occur in the core of a vortex in the A-like phase identified with the ABM pairing state, like in the case of the bulk B phase where a core including the ABM state is realized at higher pressures. We examine the core structure of a single vortex under the boundary condition compatible with the Mermin-Ho vortex in the presence of the dipole interaction. Following Salomaa and Volovik's approach, we numerically solve the Ginzburg-Landau equation for an axially symmetric vortex and, by examining its stability against nonaxisymmetric perturbations, discuss possible vortex core states. It is found that a first order transition on core states may occur on warming from an axisymmetric vortex with a nonunitary core to a singular vortex with the polar core.

Electrical resistivity of CeNiSn under uniaxial and hydrostatic pressures

NASA Astrophysics Data System (ADS)

Echizen, Y.; Umeo, K.; Igaue, T.; Takabatake, T.

2002-05-01

We present measurements of the electrical resistivity ρ(T) on high-quality single-crystalline CeNiSn under both hydrostatic pressure up to 1 GPa and uniaxial pressure up to 0.25 GPa. At ambient pressure, ρ(T) along the orthorhombic a-axis (b-axis) shows two maxima at TL = 12 K (14 K) and TH = 74 K (40 K), respectively, which arise from the Kondo scattering of conduction electrons by the crystal-field ground state and excited states. With increasing hydrostatic pressure, both TL and TH increase linearly, and for P≥0.8 GPa, the anisotropy in ρ(T) for I∥a and I∥b almost vanishes as a result of increased hybridization between the 4f electrons and the conduction electrons. Under P∥a, both TL and TH in ρ(I∥b) increase similarly to under hydrostatic pressure. Under P∥c, however, the depression of TL in ρ(I∥a) and ρ(I∥b) suggests that the c-f hybridization in the crystal-field ground state is weakened in the a-b plane of CeNiSn.

Determination of the out-of-plane anisotropy contributions (first and second anisotropy terms) in amorphous Nd-Co thin films by micromagnetic numerical simulations

NASA Astrophysics Data System (ADS)

Alvarez-Prado, L. M.; Cid, R.; Morales, R.; Diaz, J.; Vélez, M.; Rubio, H.; Hierro-Rodriguez, A.; Alameda, J. M.

2018-06-01

Amorphous Nd-Co thin films exhibit stripe shaped periodic magnetic domains with local out-of-plane magnetization components due to their perpendicular magnetic anisotropy. This anisotropy has been quantified in a fairly simple way by reproducing the experimental magnetization curves by means of micromagnetic numerical simulations. The simulations show that the first (K1) and second (K2) anisotropy constants must be used to properly describe the variation of the stripe domains with the in plane applied magnetic field. A strong temperature dependence of both K1 and K2 has been obtained between 10 K and room temperature. This anisotropy behavior is characteristic of two magnetically coupled 3d-4f sublattices with competing anisotropies.

Spin-wave resonances and surface spin pinning in Ga1-xMnxAs thin films

NASA Astrophysics Data System (ADS)

Bihler, C.; Schoch, W.; Limmer, W.; Goennenwein, S. T. B.; Brandt, M. S.

2009-01-01

We investigate the dependence of the spin-wave resonance (SWR) spectra of Ga0.95Mn0.05As thin films on the sample treatment. We find that for the external magnetic field perpendicular to the film plane, the SWR spectrum of the as-grown thin films and the changes upon etching and short-term hydrogenation can be quantitatively explained via a linear gradient in the uniaxial magnetic anisotropy field in growth direction. The model also qualitatively explains the SWR spectra observed for the in-plane easy-axis orientation of the external magnetic field. Furthermore, we observe a change in the effective surface spin pinning of the partially hydrogenated sample, which results from the tail in the hydrogen-diffusion profile. The latter leads to a rapidly changing hole concentration/magnetic anisotropy profile acting as a barrier for the spin-wave excitations. Therefore, short-term hydrogenation constitutes a simple method to efficiently manipulate the surface spin pinning.

Anisotropy of the ferromagnetic L10 phase in the Mn-Al-C alloys induced by high-pressure spark plasma sintering

NASA Astrophysics Data System (ADS)

Tyrman, Muriel; Ahmim, Smail; Pasko, Alexandre; Etgens, Victor; Mazaleyrat, Frédéric; Quetel-Weben, Simon; Perrière, Loïc; Guillot, Ivan

2018-05-01

The metastable τ-phase of MnAl equi-atomic compound belongs to a family of ferromagnetic alloys with L10 crystal structure. Stabilization of the phase by adding 2 at. % using manganese carbide (Mn23C6) enhances the magnetization in relation with the increase in lattice volume. It is thus a promising candidate for rare-earth-free permanent magnets. Coercivity of Mn-Al-C alloys being still weak, there is an interest to see to which extend sintering/transformation of the ɛ-phase by Spark Plasma Sintering (SPS) can increase the coercivity and the anisotropy. The structural and the magnetic properties were studied for samples sintered at 550 °C under uniaxial pressure of 100, 200, 300 and 400 MPa. Coercivity, remanence and anistotropy appears with the sintering pressure. The high pressure applied while sintering produces preferential orientation of the flake-shaped grains which influences the remanence.

Temperature dependence of the anisotropy field of L10 FePt near the Curie temperature

NASA Astrophysics Data System (ADS)

Richter, H. J.; Parker, G. J.

2017-06-01

Near the Curie temperature, the anisotropy field of magnetically uniaxial L10 FePt is expected to follow the scaling law (1 - T/Tc)β, where T is the temperature and Tc is the Curie temperature. In the literature, β values between 0.36 and 0.65 have been reported. Based on recording measurements and micromagnetic analysis, we show that only the values of β near the low end of the reported range are compatible with the data. We also conclude that thermally activated magnetization reversal at temperatures near Tc cannot be ignored, even at time scales smaller than 1 ns. We demonstrate that thermally activated magnetization reversal at temperatures close to Tc is well described by conventional theory with a frequency factor f0 of the order of 1012 Hz. It is reasoned that the unusually high value for f0 is a consequence of the temperature-induced reduction of the degree of alignment of the micro-spins within the grains.

Tuning the ground state of the Kondo lattice in UT Bi2 (T = Ag, Au) single crystals

NASA Astrophysics Data System (ADS)

Rosa, Priscila; Luo, Yongkang; Pagliuso, Pascoal; Bauer, Eric; Thompson, Joe; Fisk, Zachary

2015-03-01

Motivated by the interesting magnetic anisotropy found in the Ce-based heavy fermion family Ce TX2 (T = transition metal, X = pnictogen), here we study the novel U-based parent compounds U TBi2 (T = Ag, Au) by combining magnetization, electrical resistivity, and heat-capacity measurements. The single crystals, synthesized by the self-flux method, also crystallize in the tetragonal HfCuSi2-type structure (space group P4/nmm). Interestingly, although UAgBi2 is a low- γ antiferromagnet below TN = 181 K, UAuBi2 is a moderately heavy uniaxial ferromagnet below Tc = 22 K. Nevertheless, both compounds display the easy-magnetization direction along the c-axis and a large magnetocrystalline anisotropy. Our results point out to an incoherent Kondo behaviour in the paramagnetic state and an intricate competition between crystal field effects and two anisotropic exchange interactions, which lead to the remarkable difference in the observed ground states.

Load partitioning between the bcc-iron matrix and NiAl-type precipitates in a ferritic alloy on multiple length scales

PubMed Central

Sun, Zhiqian; Song, Gian; Sisneros, Thomas A.; Clausen, Bjørn; Pu, Chao; Li, Lin; Gao, Yanfei; Liaw, Peter K.

2016-01-01

An understanding of load sharing among constituent phases aids in designing mechanical properties of multiphase materials. Here we investigate load partitioning between the body-centered-cubic iron matrix and NiAl-type precipitates in a ferritic alloy during uniaxial tensile tests at 364 and 506 °C on multiple length scales by in situ neutron diffraction and crystal plasticity finite element modeling. Our findings show that the macroscopic load-transfer efficiency is not as high as that predicted by the Eshelby model; moreover, it depends on the matrix strain-hardening behavior. We explain the grain-level anisotropic load-partitioning behavior by considering the plastic anisotropy of the matrix and elastic anisotropy of precipitates. We further demonstrate that the partitioned load on NiAl-type precipitates relaxes at 506 °C, most likely through thermally-activated dislocation rearrangement on the microscopic scale. The study contributes to further understanding of load-partitioning characteristics in multiphase materials. PMID:26979660

Load partitioning between the bcc-iron matrix and NiAl-type precipitates in a ferritic alloy on multiple length scales

DOE PAGES

Sun, Zhiqian; Song, Gian; Sisneros, Thomas A.; ...

2016-03-16

An understanding of load sharing among constituent phases aids in designing mechanical properties of multiphase materials. Here we investigate load partitioning between the body-centered-cubic iron matrix and NiAl-type precipitates in a ferritic alloy during uniaxial tensile tests at 364 and 506 C on multiple length scales by in situ neutron diffraction and crystal plasticity finite element modeling. Our findings show that the macroscopic load-transfer efficiency is not as high as that predicted by the Eshelby model; moreover, it depends on the matrix strain-hardening behavior. We explain the grain-level anisotropic load-partitioning behavior by considering the plastic anisotropy of the matrix andmore » elastic anisotropy of precipitates. We further demonstrate that the partitioned load on NiAl-type precipitates relaxes at 506 C, most likely through thermally-activated dislocation rearrangement on the microscopic scale. Furthermore, the study contributes to further understanding of load-partitioning characteristics in multiphase materials.« less

Critical current density and microstructure of screen-printed (Bi,Pb)2Sr2Ca2Cu3O(x) thick film sandwiched between Ag substrates

NASA Astrophysics Data System (ADS)

Oota, A.; Matsui, H.; Funakura, M.; Iwaya, J.; Maeda, J.

1993-07-01

A process of combined rolling and uniaxial pressing with intermediate sintering steps for fabrication of screen-printed (Bi,Pb)2Sr2Ca2Cu3O(x) thick films sandwiched between Ag substrates yields c-axis-oriented microstructures with a high critical current density (Jc) of 1.5 x 10 exp 4 A/sq cm (77 K, 0 T) and 9.0 x 10 exp 4 A/sq cm (23 K, 0 T). The measured Jc anisotropy at 77 K, as a function of the angle Theta between B and c axis, is pronounced. An increase in B sharpens a peak at Theta = 90 deg in the Jc vs Theta curve, together with enhancement of the anisotropy ratio. In high fields above 0.5 T, the half-height angular width of the peak approaches an average misalignment angle between the grains with increasing B.

Observation of longitudinal spin-Seebeck effect in cobalt-ferrite epitaxial thin films

NASA Astrophysics Data System (ADS)

Niizeki, Tomohiko; Kikkawa, Takashi; Uchida, Ken-ichi; Oka, Mineto; Suzuki, Kazuya Z.; Yanagihara, Hideto; Kita, Eiji; Saitoh, Eiji

2015-05-01

The longitudinal spin-Seebeck effect (LSSE) has been investigated in cobalt ferrite (CFO), an exceptionally hard magnetic spinel ferrite. A bilayer of a polycrystalline Pt and an epitaxially-strained CFO(110) exhibiting an in-plane uniaxial anisotropy was prepared by reactive rf sputtering technique. Thermally generated spin voltage in the CFO layer was measured via the inverse spin-Hall effect in the Pt layer. External-magnetic-field (H) dependence of the LSSE voltage (VLSSE) in the Pt/CFO(110) sample with H ∥ [001] was found to exhibit a hysteresis loop with a high squareness ratio and high coercivity, while that with H ∥ [ 1 1 ¯ 0 ] shows a nearly closed loop, reflecting the different anisotropies induced by the epitaxial strain. The magnitude of VLSSE has a linear relationship with the temperature difference (ΔT), giving the relatively large VLSSE /ΔT of about 3 μV/K for CFO(110) which was kept even at zero external field.

Self-consistent theory of nanodomain formation on non-polar surfaces of ferroelectrics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morozovska, Anna N.; Obukhovskii, Vyacheslav; Fomichov, Evhen

2016-04-28

We propose a self-consistent theoretical approach capable of describing the features of the anisotropic nanodomain formation induced by a strongly inhomogeneous electric field of a charged scanning probe microscopy tip on nonpolar cuts of ferroelectrics. We obtained that a threshold field, previously regarded as an isotropic parameter, is an anisotropic function that is specified from the polar properties and lattice pinning anisotropy of a given ferroelectric in a self-consistent way. The proposed method for the calculation of the anisotropic threshold field is not material specific, thus the field should be anisotropic in all ferroelectrics with the spontaneous polarization anisotropy alongmore » the main crystallographic directions. The most evident examples are uniaxial ferroelectrics, layered ferroelectric perovskites, and low-symmetry incommensurate ferroelectrics. Obtained results quantitatively describe the differences at several times in the nanodomain length experimentally observed on X and Y cuts of LiNbO3 and can give insight into the anisotropic dynamics of nanoscale polarization reversal in strongly inhomogeneous electric fields.« less

Magnetic behavior of the ferromagnetic quantum chain systems (C6H11NH3)CuCl3 (CHAC) and (C6H11NH3)CuBr3 (CHAB)

NASA Astrophysics Data System (ADS)

Kopinga, A.; Tinus, A. M. C.; de Jonge, W. J. M.

1982-04-01

Heat-capacity measurements on (C6H11NH3)CuBr3 (CHAB) in the region 0.45 < T<55 K are presented. Three-dimensional ordering is observed at Tc=1.50 K. The data are analyzed together with previously reported measurements on (C6H11NH3)CuCl3 (CHAC). Both compounds appear to be very good approximations of a ferromagnetic S=12 Heisenberg linearchain system with Jk~50 K. From the data it is inferred that the intrachain interaction of CHAC contains about 2% uniaxial anisotropy, whereas CHAB contains about 5% easy-plane anisotropy. The results are corroborated by magnetization measurements on CHAB below Tc, which also reveal a metamagnetic transition for H-->∥b (Hc=210Oe). From the value of Hc and the location of the tricitical point the interchain interactions in CHAB were found as zAFJAFk=-0.03 K, zFJFk~0.08 K.

Static properties of ferromagnetic quantum chains: Numerical results and experimental data on two S=1/2 systems (invited)

NASA Astrophysics Data System (ADS)

Kopinga, K.; Delica, T.; Leschke, H.

1990-05-01

New results of a variant of the numerically exact quantum transfer matrix method have been compared with experimental data on the static properties of [C6H11NH3]CuBr3(CHAB), a ferromagnetic system with about 5% easy-plane anisotropy. Above T=3.5 K, the available data on the zero-field heat capacity, the excess heat capacity ΔC=C(B)-C(B=0), and the magnetization are described with an accuracy comparable to the experimental error. Calculations of the spin-spin correlation functions reveal that the good description of the experimental correlation length in CHAB by a classical spin model is largely accidental. The zero-field susceptibility, which can be deduced from these correlation functions, is in fair agreement with the reported experimental data between 4 and 100 K. The method also seems to yield accurate results for the chlorine isomorph, CHAC, a system with about 2% uniaxial anisotropy.

CONSTRAINTS ON SPATIAL VARIATIONS IN THE FINE-STRUCTURE CONSTANT FROM PLANCK

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Bryan, Jon; Smidt, Joseph; De Bernardis, Francesco

2015-01-01

We use the cosmic microwave background (CMB) anisotropy data from Planck to constrain the spatial fluctuations of the fine-structure constant α at a redshift of 1100. We use a quadratic estimator to measure the four-point correlation function of the CMB temperature anisotropies and extract the angular power spectrum fine-structure constant spatial variations projected along the line of sight at the last scattering surface. At tens of degree angular scales and above, we constrain the fractional rms fluctuations of the fine-structure constant to be (δα/α){sub rms} < 3.4 × 10{sup –3} at the 68% confidence level. We find no evidence formore » a spatially varying α at a redshift of 10{sup 3}.« less

Superposition model analysis of the magnetocrystalline anisotropy of Ba-ferrite

NASA Astrophysics Data System (ADS)

Novák, Pavel

1994-06-01

Theoretical analysis of the first magnetocrystalline anisotropy constantK 1 of BaFe12O19 is performed. Two contributions toK 1 are considered — single ion anisotropy and dipolar anisotropy. ParameterD which determines the magnitude of the single ion contribution is calculated on the basis of the superposition model. It is argued that the disagreement between calculated and observed values ofK 1 is most likely connected with the contribution of Fe3+ ions on bipyramidal sites, for which the value ofD is uncertain.

Site-specific magnetic anisotropies in R2Fe14B systems

NASA Astrophysics Data System (ADS)

Yoshioka, T.; Tsuchiura, H.

2018-04-01

The local magnetic anisotropy of R ions in R2Fe14B (R = Dy, Ho) systems is studied based on a microscopic effective spin model constructed from the information obtained by using first-principles calculations. By taking into account up to 6-th order crystal electric field parameters, the model satisfactory describes the observed magnetization curves and the temperature dependence of anisotropy constants. We found that at low temperatures, the noncollinear structure appears in the Ho2Fe14B system reflecting the local magnetic anisotropy.

Annealing temperature and thickness dependencies of structural and magnetic properties of Co2FeAl thin films

NASA Astrophysics Data System (ADS)

Belmeguenai, M.; Gabor, M. S.; Zighem, F.; Roussigné, Y.; Faurie, D.; Tiusan, C.

2016-09-01

Co2FeAl (CFA) thin films, of various thicknesses (3 nm≤t ≤50 nm ), have been grown by sputtering on (001) MgO single-crystal substrates and annealed at different temperatures (RT≤Ta≤600 ∘C , where RT is the room temperature). The influence of the CFA thickness (t ), as well as ex situ annealing temperature (Ta), on the magnetic and structural properties has been investigated by x-ray diffraction (XRD), vibrating sample magnetometry, and broadband microstrip ferromagnetic resonance (MS-FMR). The XRD revealed an epitaxial growth of the films with the cubic [001] CFA axis normal to the substrate plane and that the chemical order varies from the B 2 phase to the A 2 phase when decreasing t or Ta. The deduced lattice parameters showed an in-plane tetragonal distortion and in-plane and out-plane strains that increase with Ta and 1 /t . For all Ta values, the variation of the effective magnetization, deduced from the fit of MS-FMR measurements, shows two different regimes separated by a critical thickness, which is Ta dependent. It decreases (increases) linearly with the inverse thickness (1 /t ) in the first (second) regime due to the contribution of the magnetoelastic anisotropy to surface (to volume) anisotropy. The observed behavior has been analyzed through a model allowing for the separation of the magnetocrystalline, magnetoelastic, and Néel-type interface anisotropy constants to the surface and the volume anisotropies. Similar behavior has been observed for the effective fourfold anisotropy field which governs the in-plane anisotropy present in all the samples. Finally, the MS-FMR data also allow one to conclude that the gyromagnetic factor remains constant and that the exchange stiffness constant increases with Ta.

High-resolution vector magnetometry: Piezo-spin-polarization effect and in-plane strain-induced dominating uniaxial magnetic anisotropy in a 200-nm-thick Ni thin film

NASA Astrophysics Data System (ADS)

Benito, L.

2018-04-01

Owing to its high-sensitivity, reliability, fast, versatile and cost-effective operation, vibrating sample magnetometers (VSM) are massively popular characterization instruments at Magnetism laboratories worldwide. Nevertheless, the inherent appearance of synchronous noise represents a major drawback, which critically limits the fine probing of nanometer-sized media. I here report on an innovative approach to eliminate synchronous noise in VSM. This consists of fitting engineered mechanical devices that absorbs vibration energy, dissipating that into heat. Complementarily, a novel transversal pick-up coil system is also presented and analyzed; this detection system has been engineered to enhance the noise-to-signal ratio and optimized for measuring small size thin film samples. The implementation of a combined mechanical and electromagnetic approach enables to notably enhance the VSM performance, achieving a sensitivity better than 1 ×10-6 emu and a resolution below 5 ×10-8 emu, so that the magnetization vector in nanostructured media can be accurately mapped out down to cryogenic temperatures. I lastly show precision magnetometry measurements carried out in an epitaxial (0 0 1)-oriented 200 nm-thick Ni thin film. The analysis reveals the arising of an in-plane dominating strain-induced uniaxial magnetic anisotropy, K2ef = - 6.455kJ m - 3 , and a stunning piezo-spin-polarization effect resulting in a remarkable 10% modulation of the magnetization vector, ∼ 27 emu/cm3, with respect to the cubic lattice axes. Both effects are attributed to the likely existence of an orthorhombic lattice distortion, i.e.εxx -εyy ≈ - 2 ×10-3 . This categorical link enables to assign the observed anisotropic spin-polarization in the Ni overlayer to a two-ion magnetoelastic coupling effect.

Effect of orientational ordering of magnetic nanoemulsions immobilized in agar gel on magnetic hyperthermia

NASA Astrophysics Data System (ADS)

Lahiri, B. B.; Ranoo, Surojit; Philip, John

2018-04-01

Magnetic nanoemulsions of droplet size ∼200 nm, loaded with single domain superparamagnetic nanoparticles (MNP), are potential candidates for multimodal hyperthermia due to availability of large loading volume and enhanced permeation and retention (EPR) in the cancerous tissues. In such nanoemulsions, radio frequency alternating magnetic field induced heating occur at two entirely different length scales, viz. Neel-Brown relaxation of the dispersed MNP and Brownian relaxation of emulsion droplets. Here we study the effects of orientation ordering or texturing of droplets, immobilized in a tissue mimicking agar matrix, on the field induced heating efficiency. A higher specific absorption rate (maximum ∼73 ± 2 W/gFe) is observed for droplets orientated parallel to the direction of the alternating magnetic field because of the enhancement of effective uniaxial anisotropy energy density and increased effective relaxation time. For identical and non-interacting MNP oriented parallel to the external DC magnetic field, a threefold increase in the effective uniaxial anisotropy energy density and ∼20-30% increased specific absorption rate are observed as compared to those oriented perpendicular to the magnetic field. Magnetic force microscopy images showed that the spherical morphology of the droplets remains intact even after orientational ordering and average topographic height of the droplets are found to be ∼220 (±17) nm, which is in good agreement with the most probable size obtained from dynamic light scattering. The residual volume magnetization of the emulsion droplets is found to be 1.1 × 10-6 emu/cc, indicating the superparamagnetic nature of the droplets in tissue equivalent environment. The observed increase in heating efficiency of the immobilized and oriented emulsion droplets shows promising applications in multimodal hyperthermia therapy because of the requirement of lower dose of MNP and shorter treatment time.

Anisotropy-governed competition of magnetic phases in the honeycomb quantum magnet Na3Ni2SbO6 studied by dilatometry and high-frequency ESR

NASA Astrophysics Data System (ADS)

Werner, J.; Hergett, W.; Gertig, M.; Park, J.; Koo, C.; Klingeler, R.

2017-06-01

Thermodynamic properties and low-energy magnon excitations of S =1 honeycomb-layered Na3Ni2SbO6 have been investigated by high-resolution dilatometry, static magnetization, and high-frequency electron spin resonance studies in magnetic fields up to 16 T. At TN = 16.5 K, there is a tricritical point separating two distinct antiferromagnetic phases, AF1 and AF2, from the paramagnetic regime. In addition, our data imply short-range antiferromagnetic correlations at least up to ˜5 TN . Well below TN, the magnetic field BC1≈9.5 T is needed to stabilize AF2 against AF1. The thermal expansion and magnetostriction anomalies at TN and BC 1 imply significant magnetoelastic coupling, both of which are associated with a sign change of ∂ L /∂ B . The transition at BC 1 is associated with softening of the antiferromagnetic resonance modes observed in the electron-spin-resonance spectra. The anisotropy gap Δ =360 GHz implies considerable uniaxial anisotropy. We deduce the crucial role of axial anisotropy favoring the AF1 spin structure over the AF2 one. While the magnetostriction data disprove a simple spin-flop scenario at BC 1, the nature of a second transition at BC 2 ≈ 13 T remains unclear. Both the sign of the magnetostriction and Grüneisen analysis suggest that the short-range correlations at high temperatures are of AF2 type.

Cubic anisotropy in (Ga,Mn)As layers: Experiment and theory

NASA Astrophysics Data System (ADS)

Sawicki, M.; Proselkov, O.; Sliwa, C.; Aleshkevych, P.; Domagala, J. Z.; Sadowski, J.; Dietl, T.

2018-05-01

Historically, comprehensive studies of dilute ferromagnetic semiconductors, e.g., p -type (Cd,Mn)Te and (Ga,Mn)As, paved the way for a quantitative theoretical description of effects associated with spin-orbit interactions in solids, such as crystalline magnetic anisotropy. In particular, the theory was successful in explaining uniaxial magnetic anisotropies associated with biaxial strain and nonrandom formation of magnetic dimers in epitaxial (Ga,Mn)As layers. However, the situation appears much less settled in the case of the cubic term: the theory predicts switchings of the easy axis between in-plane <100 > and <110 > directions as a function of the hole concentration, whereas only the <100 > orientation has been found experimentally. Here, we report on the observation of such switchings by magnetization and ferromagnetic resonance studies on a series of high-crystalline quality (Ga,Mn)As films. We describe our findings by the mean-field p -d Zener model augmented with three new ingredients. The first one is a scattering broadening of the hole density of states, which reduces significantly the amplitude of the alternating carrier-induced contribution. This opens the way for the two other ingredients, namely the so-far disregarded single-ion magnetic anisotropy and disorder-driven nonuniformities of the carrier density, both favoring the <100 > direction of the apparent easy axis. However, according to our results, when the disorder gets reduced, a switching to the <110 > orientation is possible in a certain temperature and hole concentration range.

BICEP2 / Keck Array IX: New bounds on anisotropies of CMB polarization rotation and implications for axionlike particles and primordial magnetic fields

NASA Astrophysics Data System (ADS)

BICEP2 Collaboration; Keck Array Collaboration; Ade, P. A. R.; Ahmed, Z.; Aikin, R. W.; Alexander, K. D.; Barkats, D.; Benton, S. J.; Bischoff, C. A.; Bock, J. J.; Bowens-Rubin, R.; Brevik, J. A.; Buder, I.; Bullock, E.; Buza, V.; Connors, J.; Crill, B. P.; Duband, L.; Dvorkin, C.; Filippini, J. P.; Fliescher, S.; Germaine, T. St.; Ghosh, T.; Grayson, J.; Harrison, S.; Hildebrandt, S. R.; Hilton, G. C.; Hui, H.; Irwin, K. D.; Kang, J.; Karkare, K. S.; Karpel, E.; Kaufman, J. P.; Keating, B. G.; Kefeli, S.; Kernasovskiy, S. A.; Kovac, J. M.; Kuo, C. L.; Larson, N.; Leitch, E. M.; Megerian, K. G.; Moncelsi, L.; Namikawa, T.; Netterfield, C. B.; Nguyen, H. T.; O'Brient, R.; Ogburn, R. W.; Pryke, C.; Richter, S.; Schillaci, A.; Schwarz, R.; Sheehy, C. D.; Staniszewski, Z. K.; Steinbach, B.; Sudiwala, R. V.; Teply, G. P.; Thompson, K. L.; Tolan, J. E.; Tucker, C.; Turner, A. D.; Vieregg, A. G.; Weber, A. C.; Wiebe, D. V.; Willmert, J.; Wong, C. L.; Wu, W. L. K.; Yoon, K. W.

2017-11-01

We present the strongest constraints to date on anisotropies of cosmic microwave background (CMB) polarization rotation derived from 150 GHz data taken by the BICEP2 & Keck Array CMB experiments up to and including the 2014 observing season (BK14). The definition of the polarization angle in BK14 maps has gone through self-calibration in which the overall angle is adjusted to minimize the observed T B and E B power spectra. After this procedure, the Q U maps lose sensitivity to a uniform polarization rotation but are still sensitive to anisotropies of polarization rotation. This analysis places constraints on the anisotropies of polarization rotation, which could be generated by CMB photons interacting with axionlike pseudoscalar fields or Faraday rotation induced by primordial magnetic fields. The sensitivity of BK14 maps (˜3 μ K -arc min ) makes it possible to reconstruct anisotropies of the polarization rotation angle and measure their angular power spectrum much more precisely than previous attempts. Our data are found to be consistent with no polarization rotation anisotropies, improving the upper bound on the amplitude of the rotation angle spectrum by roughly an order of magnitude compared to the previous best constraints. Our results lead to an order of magnitude better constraint on the coupling constant of the Chern-Simons electromagnetic term ga γ≤7.2 ×10-2/HI (95% confidence) than the constraint derived from the B -mode spectrum, where HI is the inflationary Hubble scale. This constraint leads to a limit on the decay constant of 10-6≲fa/Mpl at mass range of 10-33≤ma≤10-28 eV for r =0.01 , assuming ga γ˜α /(2 π fa) with α denoting the fine structure constant. The upper bound on the amplitude of the primordial magnetic fields is 30 nG (95% confidence) from the polarization rotation anisotropies.

Effects of Substrate Surface Topology on NiFe/Cu/Co Spin Valve Characteristics

NASA Astrophysics Data System (ADS)

Kim, Hyeong-Jun; Jeong, Won-Cheol; Cho, Kwon-Ku; Kim, Young-Keun; Joo, Seung-Ki

2000-08-01

In order to control the crystallinity of sputter-deposited NiFe/Cu/Co spin valve thin films, surface topology of 4°tilt-cut Si(111) substrates was modified in various ways prior to formation of the spin valves. In case of the mirror polished substrate, NiFe and Co showed fcc (110) preferred orientation with in-plane uniaxial magnetic anisotropy. The easy axes of these magnetic layers were aligned in 90° to each other and giant magnetoresistance (GMR) was measured to be 4.5% at room temperature. The spin valves formed on the amorphized substrate by Ar ion mass doping, however, did not show magnetic anisotropy due to the loss of crystallinity and no appreciable GMR could be observed. The spin valves deposited on the unpolished substrate, of which the average surface roughness was measured to be a few microns, turned out to show a sound multilayeredness as well as crystallinity, but GMR was reduced to 3.5%. Tailing in the magnetoresistance (R-H) curve occurred in the spin valves formed on the unpolished substrate, and it was thought to be attributed to the shape anisotropy related to the interface roughness of the films. Detailed discussion on the relationship between GMR and crystallinity of the magnetic layers has been made with the results of simple simulation.

Magnetism of new metastable cobalt-nitride compounds.

PubMed

Balasubramanian, Balamurugan; Zhao, Xin; Valloppilly, Shah R; Beniwal, Sumit; Skomski, Ralph; Sarella, Anandakumar; Jin, Yunlong; Li, Xingzhong; Xu, Xiaoshan; Cao, Huibo; Wang, Haohan; Enders, Axel; Wang, Cai-Zhuang; Ho, Kai-Ming; Sellmyer, David J

2018-06-06

The search for new magnetic materials with high magnetization and magnetocrystalline anisotropy is important for a wide range of applications including information and energy processing. There is only a limited number of naturally occurring magnetic compounds that are suitable. This situation stimulates an exploration of new phases that occur far from thermal-equilibrium conditions, but their stabilization is generally inhibited due to high positive formation energies. Here a nanocluster-deposition method has enabled the discovery of a set of new non-equilibrium Co-N intermetallic compounds. The experimental search was assisted by computational methods including adaptive-genetic-algorithm and electronic-structure calculations. Conventional wisdom is that the interstitial or substitutional solubility of N in Co is much lower than that in Fe and that N in Co in equilibrium alloys does not produce materials with significant magnetization and anisotropy. By contrast, our experiments identify new Co-N compounds with favorable magnetic properties including hexagonal Co3N nanoparticles with a high saturation magnetic polarization (Js = 1.28 T or 12.8 kG) and an appreciable uniaxial magnetocrystalline anisotropy (K1 = 1.01 MJ m-3 or 10.1 Mergs per cm3). This research provides a pathway for uncovering new magnetic compounds with computational efficiency beyond the existing materials database, which is significant for future technologies.

Effect of size and moisture on the mechanical behavior of SU-8 thin films

NASA Astrophysics Data System (ADS)

Robin, C. J.; Jonnalagadda, K. N.

2016-02-01

The mechanical properties of SU-8 were investigated in conjunction with size effect, mechanical anisotropy and moisture absorption. Uniaxial tensile experiments were conducted on SU-8 films of 500 nm and 2 μm thickness. A spin coating process was used to fabricate the films with one set from a single coat (single layer) and the others containing multiple coats (multilayer) with pre-baking in between. The stress versus strain response was obtained from in situ optical experiments and a digital image correlation method. Compared to single layer films, the multilayer films showed a significant increase in mechanical properties as well as in-plane anisotropy. This anisotropy was confirmed using Fourier transform infrared spectroscopy and attributed to the spin coating process, which resulted in higher crosslinking density in the film, and molecular orientation in the radial direction. Moisture absorption studies revealed that the mechanical properties were affected by water, which exists in both the free and bonded form in the polymer and acts as a plasticizer. The effect of moisture was similar in both the single and multilayer films, but was higher for the latter due to multiple processing steps as well as the existence of higher percentage of epoxy polar groups.

Cross-bedding Related Anisotropy and its Role in the Orientation of Joints in an Aeolian Sandstone

NASA Astrophysics Data System (ADS)

Deng, S.; Cilona, A.; Mapeli, C.; Panfilau, A.; Aydin, A.; Prasad, M.

2014-12-01

Previous research revealed that the cross-bedding related anisotropy in aeolian sandstones affects the orientation of compaction bands, also known as anticracks. We hypothesize that cross-bedding should a have similar influence on the orientation of the joints within the same rock at the same location. To test this hypothesis, we investigated the relationship between the cross-beds and the cross-bed package confined joints in the Jurassic aeolian Aztec Sandstone cropping out in the Valley of Fire State Park, Nevada. The field data demonstrates that the cross-bed package confined joints occur at high-angle to bedding and trend roughly parallel to the dip direction of the cross-beds. This shows that the cross-bed orientation and the associated anisotropy also exert a strong control on the formation and orientation of the joints. In order to characterize the anisotropy due to cross-bedding in the Aztec Sandstone, we measured the P-wave velocities parallel and perpendicular to bedding from 11 samples in the laboratory using a bench-top ultrasonic assembly. The measured P-wave anisotropy is about 13% on average. Based on these results, a numerical model based on the generalized Hooke's law for anisotropic materials is analyzed assuming the cross-bedded sandstone to be transversely isotropic. Using this model, we tested various cross-bed orientations as well as different strain boundary conditions (uniaxial, axisymmetric and triaxial). It is possible to define a boundary condition under which the modeled results roughly match with the observed relationship between cross-bed package confined joints and cross-beds. These results have important implications for fluid flow through aeolian sandstones in reservoirs and aquifers.

Anisotropy of the Mechanical Properties of TbF3 Crystals

NASA Astrophysics Data System (ADS)

Karimov, D. N.; Lisovenko, D. S.; Sizova, N. L.; Sobolev, B. P.

2018-01-01

TbF3 (sp. gr. Pnma) crystals up to 40 mm in diameter have been grown from melt by a Bridgman technique. The anisotropy of their mechanical properties is studied for the first time. the technical elasticity constants are calculated, and room-temperature values of Vickers microhardness for the (010) and (100) planes are measured. The shape of indentation impressions is found to correlate with Young's modulus anisotropy for TbF3 crystals.

Magneto-optical and catalytic properties of Fe3O4@HA@Ag magnetic nanocomposite

NASA Astrophysics Data System (ADS)

Amir, Md.; Güner, S.; Yıldız, A.; Baykal, A.

2017-01-01

Fe3O4@HA@Ag magnetic nanocomposites (MNCs) were successfully synthesized by the simple reflux method for the removal of azo dyes from the industrial aqueous media. Fe3O4@HA@AgMNCs exhibited high catalytic activity to reduce MB within 20 min from the waste water. The obtained materials were characterized by the means of different techniques. Powder X-ray diffraction (XRD) analysis confirmed the single-phase of Fe3O4 spinel structure. SEM and TEM analysis indicated that Fe3O4@HA@AgMNCs were nanoparticles like structure with small agglomeration. TG result showed that the products contained 9% of HA. The characteristic peaks of HA at 1601 cm-1 and 1703 cm-1 was observed by the means of FT-IR spectra of Fe3O4@HA@AgMNCs. The hysteresis (σ-H) curves revealed Fe3O4@HA@Ag MNCs exhibit a typical superparamagnetic characteristic with a saturation magnetization of 59.11 emu/g and measured magnetic moment is 2.45 μB. The average magnetic particle dimension (Dmag) is 13.25 nm. In accordance, the average crystallite and particle dimensions were obtained as 11.50 nm and 13.10 nm from XRD and TEM measurements, respectively. Magnetocrystalline anisotropy was offered as uniaxial and calculated effective anisotropy constant (Keff) is 2.96×105 Erg/g. The blocking temperature was estimated as 522 K. The size-dependent saturation magnetization suggests the existence of a magnetically dead layer as 0.793 nm for Fe3O4@HA@Ag MNCs. The UV-vis diffuse reflectance spectroscopy (DRS) and Kubelka-Munk theory were applied to determine the optical properties of powder samples. The direct optical energy band gap (Eg) values were estimated from Tauc plots between 1.62 eV and 2.12 eV.

Effects of anisotropy and irradiation on the deformation behavior of Zircaloy 2. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pelloux, R.M.; Ballinger, R.; Lucas, G.

1979-01-01

An experimental program investigated the effects of texture anisotropy and irradiation on the mechanical behavior of Zircaloy-2. Short time and time dependent mechanical behavior were considered. Irradiation effects were simulated through the use of 4.75 MeV protons. The temperature ranges investigated were 298/sup 0/K and 573 to 673/sup 0/K. Both cold worked-stress relieved and annealed material were used in this experimental program. Short time yield behavior of different crystallographic textures was determined by uniaxial and plane strain tests in the temperature range 298/sup 0/K and 573 to 673/sup 0/K. Monotonic flow loci were constructed for each texture. Yield behavior ismore » a strong function of the crystallographic texture number f at all temperatures investigated. The rotation of texture with increasing plastic strain was investigated as a function of initial texture at 298/sup 0/K and 623/sup 0/K. The rate of texture rotation df/epsilon/sub p/ was found to be a unique function of the initial texture for plastic strains less than 0.08. Time dependent mechanical behavior was investigated in the range 573 to 673/sup 0/K using constant load creep and stress relaxation tests. The tensile creep strength is proportional to the resolved fraction of basal poles in the test direction. In variable stress and temperature tests, the time-hardening rule was found to be inapplicable. The strain-hardening rule was applied with success to data obtained at temperatures less than or equal to 648/sup 0/K. Irradiation creep tests were conducted in vacuum at 598/sup 0/K and 102 to 241 MPa on 80..mu..m thick Zircaloy-2 foil specimens in both the recrystallized and cold worked-stress relieved condition. In the irradiation creep tests irradiation hardening and enhanced irradiation creep were observed. Radiation hardening effects were significant in annealed material but were attenuated in cold worked-stress relieved material.« less

Magneto-structural correlations in a family of Fe(II)Re(IV)(CN)2 single-chain magnets: density functional theory and ab initio calculations.

PubMed

Zhang, Yi-Quan; Luo, Cheng-Lin; Wu, Xin-Bao; Wang, Bing-Wu; Gao, Song

2014-04-07

Until now, the expressions of the anisotropic energy barriers Δξ and ΔA, using the uniaxial magnetic anisotropy D, the intrachain coupling strength J, and the high-spin ground state S for single-chain magnets (SCMs) in the intermediate region between the Ising and the Heisenberg limits, were unknown. To explore this relationship, we used density functional theory and ab initio methods to obtain expressions of Δξ and ΔA in terms of D, J, and S of six R4Fe(II)-Re(IV)Cl4(CN)2 (R = diethylformamide (1), dibutylformamide (2), dimethylformamide (3), dimethylbutyramide (4), dimethylpropionamide (5), and diethylacetamide (6)) SCMs in the intermediate region. The ΔA value for compounds 1-3 was very similar to the magnetic anisotropic energy of a single Fe(II), while the value of Δξ was predicted using the exchange interaction of Fe(II) with the neighboring Re(IV), which could be expressed as 2JSReSFe. Similar to compounds 1-3, the anisotropy energy barrier ΔA of compounds 4 and 5 was also equal to (Di - Ei)SFe(2), but the correlation energy Δξ was closely equal to 2JSReSFe(cos 98.4 - cos 180) due to the reversal of the spins on the opposite Fe(II). For compound 6, one unit cell of Re(IV)Fe(II) was regarded as a domain wall since it had two different Re(IV)-Fe(II) couplings. Thus, the Δξ of compound 6 was expressed as 4J″SRe1Fe1SRe2Fe2, where J″ was the coupling constant of the neighboring unit cells of Re1Fe1 and Re2Fe2, and ΔA was equal to the anisotropic energy barrier of one domain wall given by DRe1Fe1(S(2)Re1Fe1 - 1/4).

The relationship between magnetic anisotropy, rock-strength anisotropy and vein emplacement in gold-bearing metabasalts of Gadag (South India)

NASA Astrophysics Data System (ADS)

Vishnu, C. S.; Lahiri, Sivaji; Mamtani, Manish A.

2018-01-01

In this study the importance of rock strength and its anisotropy in controlling vein emplacement is evaluated by integrating anisotropy of magnetic susceptibility (AMS) with rock mechanics data from massive (visibly isotropic) metabasalts of Gadag region (Dharwar Craton, South India). Orientation of magnetic foliation (MF) is first recognized from AMS. Subsequently, rock mechanics tests viz. ultrasonic P-wave velocity (Vp), uniaxial compressive strength (UCS) and point load strength (Is(50)) are done in cores extracted parallel and perpendicular to MF. Vp is found to be higher in direction parallel to MF than perpendicular to it. In contrast rock strength (UCS and Is(50)) is greater in direction perpendicular to MF, than parallel to it. This proves that rocks from the gold mineralized belt of Gadag have rock strength anisotropy. Orientation of MF in Gadag region is NW-SE, which is also the mean orientation of quartz veins. Previous studies indicate that emplacement of veins in the region took place during regional D3 (NW-SE shortening). Based on the present study, it is concluded that vein emplacement took place in NW-SE orientation because the rocks have strength anisotropy and are weaker in this direction (orientation of MF), which dilated to accommodate fluid flow. In addition, vein intensities are measured along three traverses and found to be variable. It is argued that since mineralization is favoured when the system gets saturated with fluid, variation in fluid flow could not have been responsible for variation in vein intensities in the study area. Since the rock strength of the different blocks investigated here is not uniform, it is envisaged that variation in rock strength played an important role in controlling the vein intensities. It is concluded that rock strength variation controlled strain partitioning and channelized fluid flow thus influencing vein emplacement and mineralization and formation of lodes.

Exciton-phonon coupling in diindenoperylene thin films

NASA Astrophysics Data System (ADS)

Heinemeyer, U.; Scholz, R.; Gisslén, L.; Alonso, M. I.; Ossó, J. O.; Garriga, M.; Hinderhofer, A.; Kytka, M.; Kowarik, S.; Gerlach, A.; Schreiber, F.

2008-08-01

We investigate exciton-phonon coupling and exciton transfer in diindenoperylene (DIP) thin films on oxidized Si substrates by analyzing the dielectric function determined by variable-angle spectroscopic ellipsometry. Since the molecules in the thin-film phase form crystallites that are randomly oriented azimuthally and highly oriented along the surface normal, DIP films exhibit strongly anisotropic optical properties with uniaxial symmetry. This anisotropy can be determined by multiple sample analysis. The thin-film spectrum is compared with a monomer spectrum in solution, which reveals similar vibronic subbands and a Huang-Rhys parameter of S≈0.87 for an effective internal vibration at ℏωeff=0.17eV . However, employing these parameters the observed dielectric function of the DIP films cannot be described by a pure Frenkel exciton model, and the inclusion of charge-transfer (CT) states becomes mandatory. A model Hamiltonian is parametrized with density-functional theory calculations of single DIP molecules and molecule pairs in the stacking geometry of the thin-film phase, revealing the vibronic coupling constants of DIP in its excited and charged states together with electron and hole transfer integrals along the stack. From a fit of the model calculation to the observed dielectric tensor, we find the lowest CT transition E00CT at 0.26±0.05eV above the neutral molecular excitation energy E00F , which is an important parameter for device applications.

A novel model for smectic liquid crystals: Elastic anisotropy and response to a steady-state flow.

PubMed

Püschel-Schlotthauer, Sergej; Meiwes Turrión, Victor; Stieger, Tillmann; Grotjahn, Robin; Hall, Carol K; Mazza, Marco G; Schoen, Martin

2016-10-28

By means of a combination of equilibrium Monte Carlo and molecular dynamics simulations and nonequilibrium molecular dynamics we investigate the ordered, uniaxial phases (i.e., nematic and smectic A) of a model liquid crystal. We characterize equilibrium behavior through their diffusive behavior and elastic properties. As one approaches the equilibrium isotropic-nematic phase transition, diffusion becomes anisotropic in that self-diffusion D ⊥ in the direction orthogonal to a molecule's long axis is more hindered than self-diffusion D ∥ in the direction parallel to that axis. Close to nematic-smectic A phase transition the opposite is true, D ∥ < D ⊥ . The Frank elastic constants K 1 , K 2 , and K 3 for the respective splay, twist, and bend deformations of the director field n̂ are no longer equal and exhibit a temperature dependence observed experimentally for cyanobiphenyls. Under nonequilibrium conditions, a pressure gradient applied to the smectic A phase generates Poiseuille-like or plug flow depending on whether the convective velocity is parallel or orthogonal to the plane of smectic layers. We find that in Poiseuille-like flow the viscosity of the smectic A phase is higher than in plug flow. This can be rationalized via the velocity-field component in the direction of the flow. In a sufficiently strong flow these smectic layers are not destroyed but significantly bent.

Methyl fluoride-13C in nematic liquid crystals: Anisotropy of the indirect 13C-19F spin-spin coupling and of the 1H, 13C, and 19F chemical shieldings

NASA Astrophysics Data System (ADS)

Jokisaari, J.; Hiltunen, Y.; Lounila, J.

1986-09-01

The anisotropy of the indirect 13C-19F spin-spin coupling tensor of methyl fluoride-13C in the liquid crystals ZLI 1167, EBBA, their mixtures, phase IV, and phase 1221 was studied by applying 1H and 19F NMR spectroscopy. The relative anisotropy ΔJCF/JCF gets values between -4.3 (in ZLI 1167) and +30.7 (in EBBA) when determined in the conventional way from the experimental dipolar coupling constants taking into account only harmonic vibrational corrections. The inclusion of the deformational corrections in both the direct and indirect C-F coupling tensors leads to a constant, solvent independent relative anisotropy of -2.5±0.2. This result is also obtained when a mixture of the liquid crystals ZLI 1167 and EBBA is used which mixture gives an undistorted geometry for methyl fluoride. The chemical shielding anisotropies ΔσH, ΔσC, and ΔσF for methyl fluoride were determined by applying the method of mixing two thermotropic nematogens (ZLI 1167 and EBBA) with opposite anisotropies of diamagnetic susceptibility. The results ΔσH =+5.2±0.2 ppm, ΔσC =+87±4 ppm, and ΔσF =-90±4 ppm are in fair agreement with theoretical calculations.

Constitutive modeling of the human Anterior Cruciate Ligament (ACL) under uniaxial loading using viscoelastic prony series and hyperelastic five parameter Mooney-Rivlin model

NASA Astrophysics Data System (ADS)

Chakraborty, Souvik; Mondal, Debabrata; Motalab, Mohammad

2016-07-01

In this present study, the stress-strain behavior of the Human Anterior Cruciate Ligament (ACL) is studied under uniaxial loads applied with various strain rates. Tensile testing of the human ACL samples requires state of the art test facilities. Furthermore, difficulty in finding human ligament for testing purpose results in very limited archival data. Nominal Stress vs. deformation gradient plots for different strain rates, as found in literature, is used to model the material behavior either as a hyperelastic or as a viscoelastic material. The well-known five parameter Mooney-Rivlin constitutivemodel for hyperelastic material and the Prony Series model for viscoelastic material are used and the objective of the analyses comprises of determining the model constants and their variation-trend with strain rates for the Human Anterior Cruciate Ligament (ACL) material using the non-linear curve fitting tool. The relationship between the model constants and strain rate, using the Hyperelastic Mooney-Rivlin model, has been obtained. The variation of the values of each coefficient with strain rates, obtained using Hyperelastic Mooney-Rivlin model are then plotted and variation of the values with strain rates are obtained for all the model constants. These plots are again fitted using the software package MATLAB and a power law relationship between the model constants and strain rates is obtained for each constant. The obtained material model for Human Anterior Cruciate Ligament (ACL) material can be implemented in any commercial finite element software package for stress analysis.

Investigation of the use of uniaxial comb-shaped Galfenol patches for a guided wave-based magnetostrictive phased array sensor

NASA Astrophysics Data System (ADS)

Yoo, Byungseok; Pines, Darryll J.

2018-05-01

This paper investigates the use of uniaxial comb-shaped Fe-Ga alloy (Galfenol) patches in the development of a Magnetostrictive Phased Array Sensor (MPAS) for the Guided Wave (GW) damage inspection technique. The MPAS consists of six highly-textured Galfenol patches with a <100> preferred orientation and a Hexagonal Magnetic Circuit Device (HMCD). The Galfenol patches individually aligned to distinct azimuthal directions were permanently attached to a thin aluminum plate specimen. The detachable HMCD encloses a biasing magnet and six sensing coils with unique directional sensing preferences, equivalent to the specific orientation of the discrete Galfenol patches. The preliminary experimental tests validated that the GW sensing performance and directional sensitivity of the Galfenol-based sensor were significantly improved by the magnetic shape anisotropy effect on the fabrication of uniaxial comb fingers to a Galfenol disc patch. We employed a series of uniaxial comb-shaped Galfenol patches to form an MPAS with a hexagonal sensor configuration, uniformly arranged within a diameter of 1". The Galfenol MPAS was utilized to identify structural damage simulated by loosening joint bolts used to fasten the plate specimen to a frame structure. We compared the damage detection results of the MPAS with those of a PZT Phased Array Sensor (PPAS) collocated to the back surface of the plate. The directional filtering characteristic of the Galfenol MPAS led to acquiring less complicated GW signals than the PPAS using omnidirectional PZT discs. However, due to the detection limit of the standard hexagonal patterned array, the two array sensors apparently identified only the loosened bolts located along one of the preferred orientations of the array configuration. The use of the fixed number of the Galfenol patches for the MPAS construction constrained the capability of sensing point multiplication of the HMCD by altering its rotational orientation, resulting in such damage detection limitation of the MPAS.

Evolution of the interfacial perpendicular magnetic anisotropy constant of the Co2FeAl/MgO interface upon annealing

NASA Astrophysics Data System (ADS)

Conca, A.; Niesen, A.; Reiss, G.; Hillebrands, B.

2018-04-01

We investigate a series of films with different thickness of the Heusler alloy Co2FeAl in order to study the effect of annealing on the interface with a MgO layer and on the bulk magnetic properties. Our results reveal that while the perpendicular interface anisotropy constant K\\perpS is zero for the as-deposited samples, its value increases with annealing up to a value of 1.14 +/- 0.07 mJ m‑2 for the series annealed at 320 °C and of 2.01 +/- 0.7 mJ m‑2 for the 450 °C annealed series owing to a strong modification of the interface during the thermal treatment. This large value ensures a stabilization of a perpendicular magnetization orientation for an extrapolated thickness below 1.7 nm. The data additionally shows that the in-plane biaxial anisotropy constant has a different evolution with thickness in as-deposited and annealed systems. The Gilbert damping parameter α shows minima for all series for a thickness of 40 nm and an absolute minimum value of 2.8+/-0.1×10-3 . The thickness dependence is explained in terms of an inhomogeneous magnetization state generated by the interplay between the different anisotropies of the system and by the crystalline disorder.

Knitted Patterns as a Model for Anisotropy

ERIC Educational Resources Information Center

Cepic, Mojca

2012-01-01

Anisotropy is a difficult concept, although it is often met in everyday life. This paper describes a simple model--knitted patterns--having anisotropic elastic properties. The elastic constant is measured for the force applied in different directions with respect to the knitting direction. It is also shown that the deformation of the knitted…

Full magnetization process of 3d-4f hard magnetic materials in ultrahigh magnetic fields (an example: RFe11Ti)

NASA Astrophysics Data System (ADS)

Kuz'min, M. D.; Zvezdin, A. K.

1998-03-01

The prospects of using the free-powder high-field magnetization method for a quantitative study of inter-sublattice exchange interaction in 3d-4f hard magnetic materials are analyzed. Such analysis is stimulated by the availability of pulsed magnetic fields ˜103 T generated by implosion. Particular attention is paid to effects due to magnetic anisotropy, essential for these materials. The 3d-4f ferrimagnets where both sublattices contribute positively to the easy-axis anisotropy are shown to be suitable objects of study by the free-powder method, because (i) anomalies in their low-temperature magnetizatization curves are sharp and (ii) anisotropic effects can be allowed for without quantitative knowledge of the anisotropy constants. Moreover, these "good" hard magnetic materials can be brought into metamagnetic regime by diluting the rare earth sublattice with nonmagnetic yttrium; then, regardless of the anisotropy constants, the magnetization curve at low temperatures has just one steplike anomaly, the threshold field being equal exactly to the molecular field acting on the rare earth.

Magnetisation reversal in anisotropy graded Co/Pd multilayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barton, C. W., E-mail: craig.barton-2@postgrad.manchester.ac.uk; Thomson, T.

2015-08-14

We demonstrate high precision controllability of the magnetization reversal nucleation process in [Co/Pd]{sub 8} multilayer films consisting of two sets of bilayers with high and low perpendicular anisotropy, respectively. The anisotropy of the entire film is set by the degree of Co/Pd interfacial mixing during deposition which provides fine control of the anisotropy of an individual bilayer in the multilayer stack. The relative number of each type of bilayer is used to select the magnetisation reversal behavior such that changing one bilayer changes the properties of the entire multilayer through anisotropy averaging. A simple extension to the sputtering protocol wouldmore » provide multilayer films with fully graded anisotropy, while maintaining a constant saturation magnetization opening new possibilities for the creation of highly engineered multilayer structures for spin torque devices and future magnetic recording media.« less

Magnetization and anisotropy of cobalt ferrite thin films

NASA Astrophysics Data System (ADS)

Eskandari, F.; Porter, S. B.; Venkatesan, M.; Kameli, P.; Rode, K.; Coey, J. M. D.

2017-12-01

The magnetization of thin films of cobalt ferrite frequently falls far below the bulk value of 455 kA m-1 , which corresponds to an inverse cation distribution in the spinel structure with a significant orbital moment of about 0.6 μB that is associated with the octahedrally coordinated Co2+ ions. The orbital moment is responsible for the magnetostriction and magnetocrystalline anisotropy and its sensitivity to imposed strain. We have systematically investigated the structure and magnetism of films produced by pulsed-laser deposition on different substrates (Ti O2 , MgO, MgA l2O4 , SrTi O3 , LSAT, LaAl O3 ) and as a function of temperature (500 -700 °C) and oxygen pressure (10-4-10 Pa ) . Magnetization at room-temperature ranges from 60 to 440 kA m-1 , and uniaxial substrate-induced anisotropy ranges from +220 kJ m-3 for films on deposited on MgO (100) to -2100 kJ m-3 for films deposited on MgA l2O4 (100), where the room-temperature anisotropy field reaches 14 T. No rearrangement of high-spin Fe3+ and Co2+ cations on tetrahedral and octahedral sites can reduce the magnetization below the bulk value, but a switch from Fe3+ and Co2+ to Fe2+ and low-spin Co3+ on octahedral sites will reduce the low-temperature magnetization to 120 kA m-1 , and a consequent reduction of Curie temperature can bring the room-temperature value to near zero. Possible reasons for the appearance of low-spin cobalt in the thin films are discussed.

Magnetization reversal in epitaxial exchange-biased IrMn/FeGa bilayers with anisotropy geometries controlled by oblique deposition

NASA Astrophysics Data System (ADS)

Zhang, Yao; Zhan, Qingfeng; Zuo, Zhenghu; Yang, Huali; Zhang, Xiaoshan; Dai, Guohong; Liu, Yiwei; Yu, Ying; Wang, Jun; Wang, Baomin; Li, Run-Wei

2015-05-01

We fabricated epitaxial exchange biased (EB) IrMn/FeGa bilayers by oblique deposition and systematically investigated their magnetization reversal. Two different configurations with the uniaxial magnetic anisotropy Ku parallel and perpendicular to the unidirectional anisotropy Ke b were obtained by controlling the orientation of the incident FeGa beam during deposition. A large ratio of Ku/Ke b was obtained by obliquely depositing the FeGa layer to achieve a large Ku while reducing the IrMn thickness to obtain a small Ke b. Besides the previously reported square loops, conventional asymmetrically shaped loops, and one-sided and two-sided two-step loops, unusual asymmetrically shaped loops with a three-step magnetic transition for the descending branch and a two-step transition for the ascending branch and biased three-step loops were observed at various field orientations in the films of both IrMn (tIrMn=1.5 to 20 nm)/FeGa (10 nm) with Ku⊥ Ke b and IrMn (tIrMn≤2 nm)/FeGa (10 nm) with Ku|| Ke b . Considering the geometries of anisotropies, a model based on domain wall nucleation and propagation was employed to quantitatively describe the angular dependent behaviors of IrMn/FeGa bilayers. The biased three-step magnetic switching was predicted to take place when | Ku|> ɛ90°+Ke b , where ɛ90° is the 90° domain wall nucleation energy, and the EB leads to the appearance of the unusual asymmetrically shaped hysteresis loops.

Nonlinear elastic response of strong solids: First-principles calculations of the third-order elastic constants of diamond

DOE PAGES

Hmiel, A.; Winey, J. M.; Gupta, Y. M.; ...

2016-05-23

Accurate theoretical calculations of the nonlinear elastic response of strong solids (e.g., diamond) constitute a fundamental and important scientific need for understanding the response of such materials and for exploring the potential synthesis and design of novel solids. However, without corresponding experimental data, it is difficult to select between predictions from different theoretical methods. Recently the complete set of third-order elastic constants (TOECs) for diamond was determined experimentally, and the validity of various theoretical approaches to calculate the same may now be assessed. We report on the use of density functional theory (DFT) methods to calculate the six third-order elasticmore » constants of diamond. Two different approaches based on homogeneous deformations were used: (1) an energy-strain fitting approach using a prescribed set of deformations, and (2) a longitudinal stress-strain fitting approach using uniaxial compressive strains along the [100], [110], and [111] directions, together with calculated pressure derivatives of the second-order elastic constants. The latter approach provides a direct comparison to the experimental results. The TOECs calculated using the energy-strain approach differ significantly from the measured TOECs. In contrast, calculations using the longitudinal stress-uniaxial strain approach show good agreement with the measured TOECs and match the experimental values significantly better than the TOECs reported in previous theoretical studies. Lastly, our results on diamond have demonstrated that, with proper analysis procedures, first-principles calculations can indeed be used to accurately calculate the TOECs of strong solids.« less

Experiments on stress dependent borehole acoustic waves.

PubMed

Hsu, Chaur-Jian; Kane, Michael R; Winkler, Kenneth; Wang, Canyun; Johnson, David Linton

2011-10-01

In the laboratory setup, a borehole traverses a dry sandstone formation, which is subjected to a controlled uniaxial stress in the direction perpendicular to the borehole axis. Measurements are made in a single loading-unloading stress cycle from zero to 10 MPa and then back down to zero stress. The applied stress and the presence of the borehole induce anisotropy in the bulk of the material and stress concentration around the borehole, both azimuthally and radially. Acoustic waves are generated and detected in the water-filled borehole, including compressional and shear headwaves, as well as modes of monopole, dipole, quadrupole, and higher order azimuthal symmetries. The linear and non-linear elastic parameters of the formation material are independently quantified, and utilized in conjunction with elastic theories to predict the characteristics of various borehole waves at zero and finite stress conditions. For example, an analytic theory is developed which is successfully used to estimate the changes of monopole tube mode at low frequency resulted from uniaxial stress, utilizing the measured material third order elasticity parameters. Comparisons between various measurements as well as that between experiments and theories are also presented. © 2011 Acoustical Society of America

The origin of uniaxial negative thermal expansion in layered perovskites

NASA Astrophysics Data System (ADS)

Ablitt, Chris; Craddock, Sarah; Senn, Mark S.; Mostofi, Arash A.; Bristowe, Nicholas C.

2017-10-01

Why is it that ABO3 perovskites generally do not exhibit negative thermal expansion (NTE) over a wide temperature range, whereas layered perovskites of the same chemical family often do? It is generally accepted that there are two key ingredients that determine the extent of NTE: the presence of soft phonon modes that drive contraction (have negative Grüneisen parameters); and anisotropic elastic compliance that predisposes the material to the deformations required for NTE along a specific axis. This difference in thermal expansion properties is surprising since both ABO3 and layered perovskites often possess these ingredients in equal measure in their high-symmetry phases. Using first principles calculations and symmetry analysis, we show that in layered perovskites there is a significant enhancement of elastic anisotropy due to symmetry breaking that results from the combined effect of layering and condensed rotations of oxygen octahedra. This feature, unique to layered perovskites of certain symmetry, is what allows uniaxial NTE to persist over a large temperature range. This fundamental insight means that symmetry and the elastic tensor can be used as descriptors in high-throughput screening and to direct materials design.

BICEP2 / Keck Array IX: New bounds on anisotropies of CMB polarization rotation and implications for axionlike particles and primordial magnetic fields

DOE PAGES

Ade, P. A. R.; Ahmed, Z.; Aikin, R. W.; ...

2017-11-09

We present the strongest constraints to date on anisotropies of cosmic microwave background (CMB) polarization rotation derived from 150 GHz data taken by the BICEP2 & Keck Array CMB experiments up to and including the 2014 observing season (BK14). The definition of the polarization angle in BK14 maps has gone through self-calibration in which the overall angle is adjusted to minimize the observed TB and EB power spectra. After this procedure, the QU maps lose sensitivity to a uniform polarization rotation but are still sensitive to anisotropies of polarization rotation. This analysis places constraints on the anisotropies of polarization rotation,more » which could be generated by CMB photons interacting with axionlike pseudoscalar fields or Faraday rotation induced by primordial magnetic fields. The sensitivity of BK14 maps ( ~3 μK - arc min ) makes it possible to reconstruct anisotropies of the polarization rotation angle and measure their angular power spectrum much more precisely than previous attempts. Our data are found to be consistent with no polarization rotation anisotropies, improving the upper bound on the amplitude of the rotation angle spectrum by roughly an order of magnitude compared to the previous best constraints. Our results lead to an order of magnitude better constraint on the coupling constant of the Chern-Simons electromagnetic term g aγ ≤ 7.2 × 10 -2/H I (95% confidence) than the constraint derived from the B -mode spectrum, where H I is the inflationary Hubble scale. This constraint leads to a limit on the decay constant of 10 -6 ≲ f a / M pl at mass range of 10 -33 ≤ m a ≤ 10 -28eV for r = 0.01 , assuming g aγ ~ α/( 2πf a) with α denoting the fine structure constant. The upper bound on the amplitude of the primordial magnetic fields is 30 nG (95% confidence) from the polarization rotation anisotropies.« less

BICEP2 / Keck Array IX: New bounds on anisotropies of CMB polarization rotation and implications for axionlike particles and primordial magnetic fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ade, P. A. R.; Ahmed, Z.; Aikin, R. W.

We present the strongest constraints to date on anisotropies of cosmic microwave background (CMB) polarization rotation derived from 150 GHz data taken by the BICEP2 & Keck Array CMB experiments up to and including the 2014 observing season (BK14). The definition of the polarization angle in BK14 maps has gone through self-calibration in which the overall angle is adjusted to minimize the observed TB and EB power spectra. After this procedure, the QU maps lose sensitivity to a uniform polarization rotation but are still sensitive to anisotropies of polarization rotation. This analysis places constraints on the anisotropies of polarization rotation,more » which could be generated by CMB photons interacting with axionlike pseudoscalar fields or Faraday rotation induced by primordial magnetic fields. The sensitivity of BK14 maps ( ~3 μK - arc min ) makes it possible to reconstruct anisotropies of the polarization rotation angle and measure their angular power spectrum much more precisely than previous attempts. Our data are found to be consistent with no polarization rotation anisotropies, improving the upper bound on the amplitude of the rotation angle spectrum by roughly an order of magnitude compared to the previous best constraints. Our results lead to an order of magnitude better constraint on the coupling constant of the Chern-Simons electromagnetic term g aγ ≤ 7.2 × 10 -2/H I (95% confidence) than the constraint derived from the B -mode spectrum, where H I is the inflationary Hubble scale. This constraint leads to a limit on the decay constant of 10 -6 ≲ f a / M pl at mass range of 10 -33 ≤ m a ≤ 10 -28eV for r = 0.01 , assuming g aγ ~ α/( 2πf a) with α denoting the fine structure constant. The upper bound on the amplitude of the primordial magnetic fields is 30 nG (95% confidence) from the polarization rotation anisotropies.« less

Elastic properties of sulphur and selenium doped ternary PbTe alloys by first principles

NASA Astrophysics Data System (ADS)

Bali, Ashoka; Chetty, Raju; Mallik, Ramesh Chandra

2014-04-01

Lead telluride (PbTe) is an established thermoelectric material which can be alloyed with sulphur and selenium to further enhance the thermoelectric properties. Here, a first principles study of ternary alloys PbSxTe(1-x) and PbSexTe(1-x) (0≤x≤1) based on the Virtual Crystal Approximation (VCA) is presented for different ratios of the isoelectronic atoms in each series. Equilibrium lattice parameters and elastic constants have been calculated and compared with the reported data. Anisotropy parameter calculated from the stiffness constants showed a slight improvement in anisotropy of elastic properties of the alloys over undoped PbTe. Furthermore, the alloys satisfied the predicted stability criteria from the elastic constants, showing stable structures, which agreed with the previously reported experimental results.

Magnetic switching, relaxation, and domain structure of a Co/Si(111) film

NASA Astrophysics Data System (ADS)

Baird, M. J.; Bland, J. A. C.; Gu, E.; Ives, A. J. R.; Schumann, F. O.; Hughes, H. P.

1993-11-01

We have used scanning magneto-optic Kerr effect (MOKE) microscopy to investigate the magnetic relaxation of a polycrystalline hcp 125 Å Co/Si(111) film with planar uniaxial anisotropy, on time scales between 10 and 2400 s and with a spatial resolution of 15 μm. In a static magnetic field slightly less than the coercive field and applied along the easy axis direction, domains develop and the magnetization reversal proceeds via displacements of 180° domain walls. Microscopic images of this metastable state allow the 180° domains to be identified by calibration of the MOKE signal with respect to that for the saturated magnetization states. The 180° reversed domains are observed to grow in the direction of the field in the form of narrow fingers, extending via short Barkhausen jumps, randomly spaced in time over the entire time-scale range investigated, with typical distances between pinning sites of the order of microns. This reversal behavior is qualitatively similar to that reported for Au/Co perpendicular anisotropy films a few monolayers thick.

Unit-Sphere Anisotropic Multiaxial Stochastic-Strength Model Probability Density Distribution for the Orientation of Critical Flaws

NASA Technical Reports Server (NTRS)

Nemeth, Noel

2013-01-01

Models that predict the failure probability of monolithic glass and ceramic components under multiaxial loading have been developed by authors such as Batdorf, Evans, and Matsuo. These "unit-sphere" failure models assume that the strength-controlling flaws are randomly oriented, noninteracting planar microcracks of specified geometry but of variable size. This report develops a formulation to describe the probability density distribution of the orientation of critical strength-controlling flaws that results from an applied load. This distribution is a function of the multiaxial stress state, the shear sensitivity of the flaws, the Weibull modulus, and the strength anisotropy. Examples are provided showing the predicted response on the unit sphere for various stress states for isotropic and transversely isotropic (anisotropic) materials--including the most probable orientation of critical flaws for offset uniaxial loads with strength anisotropy. The author anticipates that this information could be used to determine anisotropic stiffness degradation or anisotropic damage evolution for individual brittle (or quasi-brittle) composite material constituents within finite element or micromechanics-based software

Anisotropic particles strengthen granular pillars under compression

NASA Astrophysics Data System (ADS)

Harrington, Matt; Durian, Douglas J.

2018-01-01

We probe the effects of particle shape on the global and local behavior of a two-dimensional granular pillar, acting as a proxy for a disordered solid, under uniaxial compression. This geometry allows for direct measurement of global material response, as well as tracking of all individual particle trajectories. In general, drawing connections between local structure and local dynamics can be challenging in amorphous materials due to lower precision of atomic positions, so this study aims to elucidate such connections. We vary local interactions by using three different particle shapes: discrete circular grains (monomers), pairs of grains bonded together (dimers), and groups of three bonded in a triangle (trimers). We find that dimers substantially strengthen the pillar and the degree of this effect is determined by orientational order in the initial condition. In addition, while the three particle shapes form void regions at distinct rates, we find that anisotropies in the local amorphous structure remain robust through the definition of a metric that quantifies packing anisotropy. Finally, we highlight connections between local deformation rates and local structure.

Characterizing full matrix constants of piezoelectric single crystals with strong anisotropy using two samples

NASA Astrophysics Data System (ADS)

Tang, Liguo; Zhang, Yang; Cao, Wenwu

2016-10-01

Although the self-consistency of the full matrix material constants of a piezoelectric sample obtained by the resonant ultrasonic spectroscopy technique can be guaranteed because all constants come from the same sample, it is a great challenge to determine the constants of a piezoelectric sample with strong anisotropy because it might not be possible to identify enough resonance modes from the resonance spectrum. To overcome this difficulty, we developed a strategy to use two samples of similar geometries to increase the number of easy identifiable modes. Unlike the IEEE resonance methods, sample-to-sample variation here is negligible because the two samples have almost the same dimensions, cut from the same specimen and poled under the same conditions. Using this method, we have measured the full matrix constants of a [011]c poled 0.71Pb(Mg1/3Nb2/3)O3-0.29PbTiO3 single crystal, which has 17 independent constants. The self-consistency of the obtained results is checked by comparing the calculated elastic stiffness constants c33 D , c44 D , and c55 D with those directly measured ones using the ultrasonic pulse-echo method.

Anisotropic Pressure Effects on Superconductivity in Fe1+yTe1-xSx

NASA Astrophysics Data System (ADS)

Yamamoto, Kazunori; Yamazaki, Teruo; Yamanaka, Takayoshi; Ueta, Daichi; Yoshizawa, Hideki; Yaguchi, Hiroshi

2018-05-01

We have investigated the uniaxial and hydrostatic pressure effects on superconductivity in Fe1.07Te0.88S0.12 through magnetic susceptibility measurements down to 1.8 K. The superconducting transition temperature Tc is enhanced by out-of-plane pressure (uniaxial pressure along the c-axis); the onset temperature of the superconductivity reaches 11.8 K at 0.4 GPa. In contrast, Tc is reduced by in-plane pressure (uniaxial pressure along the ab-plane) and hydrostatic pressure. Taking into account these results, it is inferred that the superconductivity of Fe1+yTe1-xSx is enhanced when the lattice constant c considerably decreases. This implies that the relationship between Tc and the anion height for Fe1+yTe1-xSx is similar to that for most iron-based superconductors. We consider the reduction of Tc by hydrostatic pressure to be due to the suppression of spin fluctuations because the system moves away from antiferromagnetic ordering, and the enhancement of Tc by out-of-plane pressure to be due to the anion height effect on Tc.

Fabric symmetry of low anisotropic rocks inferred from ultrasonic sounding: Implications for the geomechanical models

NASA Astrophysics Data System (ADS)

Přikryl, Richard; Lokajíček, Tomáš; Pros, Zdeněk; Klíma, Karel

2007-02-01

The geomechanical models were established based on the absence or presence of certain rock fabric elements — texture (crystallographic preferred orientation), microstructure (shape preferred orientation) and microcracks (flat voids). The proposed models include both (i) the ideal material showing random texture and structure but no microcracks, i.e. the material which is hardly to be found in nature, and (ii) the materials possessing various combinations of fabric elements that show different spatial arrangements. The mutual relationship between those parameters and seismic and geomechanical properties are discussed. Selected models were experimentally verified during laboratory experiments. These consist of measurement of P-wave velocities in 132 independent directions under several confining pressures in the range 0.1-400 MPa. From measured data 3D P-wave patterns can be constructed and the influence of microcracks and of texture and structure on the rock seismic anisotropy can be determined. The seismic anisotropy established at different levels of confining pressure can be used for the interpretation of rock fabric symmetry of rocks showing low anisotropy in macroscale and for the selection of directions in which the geomechanical test can be performed. The measured P-wave velocities were then mathematically processed by using a fitting function V=V+k·P-v·10 which reflects contribution of P-wave velocity in the mineral skeleton of an ideal sample without microcracks extrapolated to the atmospheric pressure level from high confining pressure interval (ca. 200-400 MPa) ( v0), linear compressibility of the samples ( kv), and confining pressure during which most of the cracks are closed ( P0). These parameters improve the understanding of the response of various rock fabric elements on increasing confinement and corresponding changes in elasticity. The observed seismic and geomechanical anisotropies reflect intensity of the fabric of rock-forming minerals and microcracks. The magnitude of seismic anisotropy measured at atmospheric pressure corresponds to the anisotropy of static elastic modulus and is governed by the spatial arrangement of microcracks. The magnitude of strength anisotropy (uniaxial compressive strength) correlates more likely to the seismic anisotropy determined at high confining pressure and is connected to the preferred orientations (either CPO or SPO or both) of rock-forming minerals.

Construction of an ultra low temperature cryostat and transverse acoustic spectroscopy in superfluid helium-3 in compressed aerogels

NASA Astrophysics Data System (ADS)

Bhupathi, Pradeep

An ultra low temperature cryostat is designed and implemented in this work to perform experiments at sub-millikelvin temperatures, specifically aimed at understanding the superfluid phases of 3He in various scenarios. The cryostat is a combination of a dilution refrigerator (Oxford Kelvinox 400) with a base temperature of 5.2 mK and a 48 mole copper block as the adiabatic nuclear demagnetization stage with a lowest temperature of ≈ 200 muK. With the various techniques implemented for limiting the ambient heat leak to the cryostat, we were able to stay below 1 mK for longer than 5 weeks. The details of design, construction and performance of the cryostat are presented. We measured high frequency shear acoustic impedance in superfluid 3He in 98% porosity aerogel at pressures of 29 bar and 32 bar in magnetic fields upto 3 kG with the aerogel cylinder compressed along the symmetry axis to generate global anisotropy. With 5% compression, there is an indication of a supercooled A-like to B-like transition in aerogel in a wider temperature width than the A phase in the bulk, while at 10% axial compression, the A-like to B-like transition is absent on cooling down to ≈ 300 muK in zero magnetic field and in magnetic fields up to 3 kG. This behavior is in contrast to that in 3He in uncompressed aerogels, in which the supercooled A-like to B-like transitions have been identified by various experimental techniques. Our result is consistent with theoretical predictions. To characterize the anisotropy in compressed aerogels, optical birefringence is measured in 98% porosity silica aerogel samples subjected to various degrees of uniaxial compression up to 15% strain, with wavelengths between 200 to 800 nm. Uncompressed aerogels exhibit no or a minimal degree of birefringence, indicating the isotropic nature of the material over the length scale of the wavelength. Uniaxial compression of aerogel introduces global anisotropy, which produces birefringence in the material. We observed a quasi-linear strain dependence in Deltan = ne -- no in compressed aerogels, where n e(o) is the index of refraction for the extraordinary (ordinary) ray of light that has its polarization parallel to the compression axis. Incidentally, this effect has potential applications for aerogels as tunable waveplates operating in a broad spectral range.

Antiferromagnetic exchange coupling measurements on single Co clusters

NASA Astrophysics Data System (ADS)

Wernsdorfer, W.; Leroy, D.; Portemont, C.; Brenac, A.; Morel, R.; Notin, L.; Mailly, D.

2009-03-01

We report on single-cluster measurements of the angular dependence of the low-temperature ferromagnetic core magnetization switching field in exchange-coupled Co/CoO core-shell clusters (4 nm) using a micro-bridge DC superconducting quantum interference device (μ-SQUID). It is observed that the coupling with the antiferromagnetic shell induces modification in the switching field for clusters with intrinsic uniaxial anisotropy depending on the direction of the magnetic field applied during the cooling. Using a modified Stoner-Wohlfarth model, it is shown that the core interacts with two weakly coupled and asymmetrical antiferromagnetic sublattices. Ref.: C. Portemont, R. Morel, W. Wernsdorfer, D. Mailly, A. Brenac, and L. Notin, Phys. Rev. B 78, 144415 (2008)

Magnetoresistance due to domain walls in an epitaxial microfabricated Fe wire

NASA Astrophysics Data System (ADS)

Rüdiger, U.; Yu, J.; Kent, A. D.; Parkin, S. S. P.

1998-08-01

The domain wall (DW) contribution to magnetoresistance has been investigated using an epitaxial microfabricated bcc (110) Fe wires of 2 μm linewidth. A strong in-plane uniaxial component to the magnetic anisotropy perpendicular to the wire axis causes a regular stripe domain pattern with closure domains. The stripe domain width in zero-applied magnetic field is strongly affected by the magnetic history and can be continuously varied from 0.45 to 1.8 μm. This enables a measurement of the resistivity as a function of DW density in a single wire. Clear evidence is presented that the resistivity is reduced in the presence of DWs at low temperatures.

Simulation of uniaxial deformation of hexagonal crystals (Mg, Be)

NASA Astrophysics Data System (ADS)

Vlasova, A. M.; Kesarev, A. G.

2017-12-01

Molecular dynamics (MD) simulations were performed for the nanocompression loading of nanocrystalline magnesium and beryllium modeled by an interatomic potential of the embedded atom method (EAM). It is shown that the main deformation modes are prismatic slip and twinning for magnesium, and only prismatic slip for beryllium. The formation of stable configurations of dislocation grids in magnesium and beryllium was observed. Dislocation networks are formed in the habit plane of the twin in a magnesium nanocrystall. Some dislocation reactions are suggested to explain the appearance of such networks. Shockley partial dislocations in a beryllium nanocrystall form grids in the slip plane. A strong anisotropy between slip systems was observed, which is in agreement with experimental data.

First-principles calculations for elastic properties of OsB 2 under pressure

NASA Astrophysics Data System (ADS)

Yang, Jun-Wei; Chen, Xiang-Rong; Luo, Fen; Ji, Guang-Fu

2009-11-01

The structure, elastic properties and elastic anisotropy of orthorhombic OsB 2 are investigated by density functional theory method with the ultrasoft pseudopotential scheme in the frame of the generalized gradient approximation (GGA) as well as local density approximation (LDA). The obtained structural parameters, elastic constants, elastic anisotropy and Debye temperature for OsB 2 under pressure are consistent with the available experimental data and other theoretical results. It is found that the elastic constants, bulk modulus and Debye temperature of OsB 2 tend to increase with increasing pressure. It is predicted that OsB 2 is not a superhard material from our calculations.

The influence of pore geometry and orientation on the strength and stiffness of porous rock

NASA Astrophysics Data System (ADS)

Griffiths, Luke; Heap, Michael J.; Xu, Tao; Chen, Chong-feng; Baud, Patrick

2017-03-01

The geometry of voids in porous rock falls between two end-members: very low aspect ratio (the ratio of the minor to the major axis) microcracks and perfectly spherical pores with an aspect ratio of unity. Although the effect of these end-member geometries on the mechanical behaviour of porous rock has received considerable attention, our understanding of the influence of voids with an intermediate aspect ratio is much less robust. Here we perform two-dimensional numerical simulations (Rock Failure Process Analysis, RFPA2D) to better understand the influence of pore aspect ratio (from 0.2 to 1.0) and the angle between the pore major axis and the applied stress (from 0 to 90°) on the mechanical behaviour of porous rock under uniaxial compression. Our numerical simulations show that, for a fixed aspect ratio (0.5) the uniaxial compressive strength and Young's modulus of porous rock can be reduced by a factor of ∼2.4 and ∼1.3, respectively, as the angle between the major axis of the elliptical pores and the applied stress is rotated from 0 to 90°. The influence of pore aspect ratio on strength and Young's modulus depends on the pore angle. At low angles (∼0-10°) an increase in aspect ratio reduces the strength and Young's modulus. At higher angles (∼40-90°), however, strength and Young's modulus increase as aspect ratio is increased. At intermediate angles (∼20-30°), strength and Young's modulus first increase and then decrease as pore aspect ratio approaches unity. These simulations also highlight that the influence of pore angle on compressive strength and Young's modulus decreases as the pore aspect ratio approaches unity. We find that the analytical solution for the stress concentration around a single elliptical pore, and its contribution to elasticity, are in excellent qualitative agreement with our numerical simulations. The results of our numerical modelling are also in agreement with recent experimental data for porous basalt, but fail to capture the strength anisotropy observed in experiments on sandstone. We conclude that the alignment of grains or platy minerals such as clays exerts a greater influence on strength anisotropy in porous sandstones than pore geometry. Finally, we show that the strength anisotropy that arises as a result of preferentially aligned elliptical pores is of a similar magnitude to that generated by bedding in porous sandstones and foliation in low-porosity metamorphic rocks. The modelling presented herein shows that porous rocks containing elliptical pores can display a strength and stiffness anisotropy, with implications for the preservation and destruction of porosity and permeability, as well as the distribution of stress and strain within the Earth's crust.

Stretch-Orientation of LaRC(TM) RP 50 Polyimide Film

NASA Technical Reports Server (NTRS)

Hawkins, Brian P.; Hinkley, Jeffrey A.; Pater, Ruth H.; Moore, Joanne

2006-01-01

An addition-curable poly(amic acid) film was subjected to various thermal pretreatments and then to uniaxial or biaxial drawing. Hot-stretching to 300% of the initial length produced better than twofold increases in tensile modulus and strength of partially-cured films. Most of the improvement was maintained upon completion of the curing at constant length.

Linking strain anisotropy and plasticity in copper metallization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murray, Conal E., E-mail: conal@us.ibm.com; Jordan-Sweet, Jean; Priyadarshini, Deepika

2015-05-04

The elastic anisotropy of copper leads to significant variation in the x-ray elastic constants (XEC), which link diffraction-based strain measurements to stress. An accurate depiction of the mechanical response in copper thin films requires a determination of an appropriate grain interaction model that lies between Voigt and Reuss limits. It is shown that the associated XEC weighting fraction, x*, between these limits provides a metric by which strain anisotropy can be quantified. Experimental values of x*, as determined by a linear regression scheme of diffraction data collected from multiple reflections, reveal the degree of strain anisotropy and its dependence onmore » plastic deformation induced during in-situ and ex-situ thermal treatments.« less

Elastic anisotropy effects on the electrical responses of a thin sample of nematic liquid crystal.

PubMed

Gomes, O A; Yednak, C A R; Ribeiro de Almeida, R R; Teixeira-Souza, R T; Evangelista, L R

2017-03-01

The electrical responses of a nematic liquid crystal cell are investigated by means of the elastic continuum theory. The nematic medium is considered as a parallel circuit of a resistance and a capacitance and the electric current profile across the sample is determined as a function of the elastic constants. In the reorientation process of the nematic director, the resistance and capacitance of the sample are determined by taking into account the elastic anisotropy. A nonmonotonic profile for the current is observed in which a minimum value of the current may be used to estimate the elastic constants values. This scenario suggests a theoretical method to determine the values of the bulk elastic constants in a single planar aligned cell just by changing the direction of applied electrical field and measuring the resulting electrical current.

Magnetic domain observation of FeCo thin films fabricated by alternate monoatomic layer deposition

NASA Astrophysics Data System (ADS)

Ohtsuki, T.; Kojima, T.; Kotsugi, M.; Ohkochi, T.; Mizuguchi, M.; Takanashi, K.

2014-01-01

FeCo thin films are fabricated by alternate monoatomic layer deposition method on a Cu3Au buffer layer, which in-plane lattice constant is very close to the predicted value to obtain a large magnetic anisotropy constant. The variation of the in-plane lattice constant during the deposition process is investigated by reflection high-energy electron diffraction. The magnetic domain images are also observed by a photoelectron emission microscope in order to microscopically understand the magnetic structure. As a result, element-specific magnetic domain images show that Fe and Co magnetic moments align parallel. A series of images obtained with various azimuth reveal that the FeCo thin films show fourfold in-plane magnetic anisotropy along ⟨110⟩ direction, and that the magnetic domain structure is composed only of 90∘ wall.

Cosmic microwave background anisotropies in cold dark matter models with cosmological constant: The intermediate versus large angular scales

NASA Technical Reports Server (NTRS)

Stompor, Radoslaw; Gorski, Krzysztof M.

1994-01-01

We obtain predictions for cosmic microwave background anisotropies at angular scales near 1 deg in the context of cold dark matter models with a nonzero cosmological constant, normalized to the Cosmic Background Explorer (COBE) Differential Microwave Radiometer (DMR) detection. The results are compared to those computed in the matter-dominated models. We show that the coherence length of the Cosmic Microwave Background (CMB) anisotropy is almost insensitive to cosmological parameters, and the rms amplitude of the anisotropy increases moderately with decreasing total matter density, while being most sensitive to the baryon abundance. We apply these results in the statistical analysis of the published data from the UCSB South Pole (SP) experiment (Gaier et al. 1992; Schuster et al. 1993). We reject most of the Cold Dark Matter (CDM)-Lambda models at the 95% confidence level when both SP scans are simulated together (although the combined data set renders less stringent limits than the Gaier et al. data alone). However, the Schuster et al. data considered alone as well as the results of some other recent experiments (MAX, MSAM, Saskatoon), suggest that typical temperature fluctuations on degree scales may be larger than is indicated by the Gaier et al. scan. If so, CDM-Lambda models may indeed provide, from a point of view of CMB anisotropies, an acceptable alternative to flat CDM models.

A scatterometry based CD metrology solution for advanced nodes, including capability of handling birefringent layers with uniaxial anisotropy

NASA Astrophysics Data System (ADS)

Ke, Chih-Ming; Hu, Jimmy; Wang, Willie; Huang, Jacky; Chung, H. L.; Liang, C. R.; Shih, Victor; Liu, H. H.; Lee, H. J.; Lin, John; Fan, Y. D.; Yen, Tony; Wright, Noelle; Alvarez Sanchez, Ruben; Coene, Wim; Noot, Marc; Yuan, Kiwi; Wang, Vivien; Bhattacharyya, Kaustuve; van der Mast, Karel

2009-03-01

A brand new CD metrology technique that can address the need for accuracy, precision and speed in near future lithography is probably one of the most challenging items. CDSEMs have served this need for a long time, however, a change of or an addition to this traditional approach is inevitable as the increase in the need for better precision (tight CDU budget) and speed (driven by the demand for increase in sampling) continues to drive the need for advanced nodes. The success of CD measurement with scatterometry remains in the capability to model the resist grating, such as, CD and shape (side wall angle), as well as the under-lying layers (thickness and material property). Things are relatively easier for the cases with isotropic under-lying layers (that consists of single refractive or absorption indices). However, a real challenge to such a technique becomes evident when one or more of the under-lying layers are anisotropic. In this technical presentation the authors would like to evaluate such CD reconstruction technology, a new scatterometry based platform under development at ASML, which can handle bi-refringent non-patterned layers with uniaxial anisotropy in the underlying stack. In the RCWA code for the bi-refringent case, the elegant formalism of the enhanced transmittance matrix can still be used. In this paper, measurement methods and data will be discussed from several complex production stacks (layers). With inclusion of the bi-refringent modeling, the in-plane and perpendicular n and k values can be treated as floating parameters for the bi-refringent layer, so that very robust CD-reconstruction is achieved with low reconstruction residuals. As a function of position over the wafer, significant variations of the perpendicular n and k values are observed, with a typical radial fingerprint on the wafer, whereas the variations in the in-plane n and k values are seen to be considerably lower.

Mechanical and histological characterization of the abdominal muscle. A previous step to modelling hernia surgery.

PubMed

Hernández, B; Peña, E; Pascual, G; Rodríguez, M; Calvo, B; Doblaré, M; Bellón, J M

2011-04-01

The aims of this study are to experimentally characterize the passive elastic behaviour of the rabbit abdominal wall and to develop a mechanical constitutive law which accurately reproduces the obtained experimental results. For this purpose, tissue samples from New Zealand White rabbits 2150±50 (g) were mechanically tested in vitro. Mechanical tests, consisting of uniaxial loading on tissue samples oriented along the craneo-caudal and the perpendicular directions, respectively, revealed the anisotropic non-linear mechanical behaviour of the abdominal tissues. Experiments were performed considering the composite muscle (including external oblique-EO, internal oblique-IO and transverse abdominis-TA muscle layers), as well as separated muscle layers (i.e., external oblique, and the bilayer formed by internal oblique and transverse abdominis). Both the EO muscle layer and the IO-TA bilayer demonstrated a stiffer behaviour along the transversal direction to muscle fibres than along the longitudinal one. The fibre arrangement was measured by means of a histological study which confirmed that collagen fibres are mainly responsible for the passive mechanical strength and stiffness. Furthermore, the degree of anisotropy of the abdominal composite muscle turned out to be less pronounced than those obtained while studying the EO and IO-TA separately. Moreover, a phenomenological constitutive law was used to capture the measured experimental curves. A Levenberg-Marquardt optimization algorithm was used to fit the model constants to reproduce the experimental curves. Copyright © 2010 Elsevier Ltd. All rights reserved.

Small planar domains in amorphous thin films: Nucleation and equilibrium conditions (abstract)

NASA Astrophysics Data System (ADS)

Labrune, M.; Hamzaoui, S.; Puchalska, I. B.; Battarel, C.; Hubert, A.

1984-03-01

The purpose of this work is to investigate a new type of small flat domain in the shape of lozenges. Such domains may be used for high-density nonvolatile shift register memories [C. Battarel, R. Morille, and A. Caplain, IEEE Trans. Magn. July (1983)]. Experimental and theoretical results for nucleation and stability of small lozenge domains less than 10 μm in length in Co-Ni-P and CoTi [G. Suran, K. Ounadjela, and J. Sztern (this Proceedings)] amorphous thin films 1500 Å thick are presented. The films have a low coercivity (Hc ˜1 Oe) and a significant in-plane uniaxial anisotropy (HK ˜35 Oe). The domains were observed in an optical microscope by longitudinal Kerr effect using an experimental method described by Prutton. Domain nucleation is obtained by applying a local field higher than HK. It must be emphasized that to stabilize the domain two constant fields having opposite direction are required: H1 applied inside the domain and parallel to its magnetization; H2 parallel to the main magnetization of the film (H1>H2). Experimental results obtained for such configuration of magnetic fields will be presented and compared with numerical computations. The theoretical model will be discussed and the role played by the magnetostatic energy emphasized. The model takes into account the spreading of the magnetic charges which appear at the boundary of the domain. Finally, application to experimental devices as mentioned in the first reference above will be shown.

Uniaxial Stretching of Poly(keto-ether-imide) Films

NASA Technical Reports Server (NTRS)

Hinkley, Jeffrey A.; Dezern, James F.; Feuz, L.; Klinedinst, D.

1999-01-01

Fully-cured aromatic polyimides were prepared from various combinations of five dianhydrides and six diamines. When heated progressively under constant load, most of the films elongated rapidly near their glass transition temperatures. In about half of the nineteen materials, the strain was self-limiting - a possible indication of strain-induced crystallinity. The presence of crystallinity was established unambiguously for one material.

On the Use of Biaxial Properties in Modeling Annulus as a Holzapfel–Gasser–Ogden Material

PubMed Central

Momeni Shahraki, Narjes; Fatemi, Ali; Goel, Vijay K.; Agarwal, Anand

2015-01-01

Besides the biology, stresses and strains within the tissue greatly influence the location of damage initiation and mode of failure in an intervertebral disk. Finite element models of a functional spinal unit (FSU) that incorporate reasonably accurate geometry and appropriate material properties are suitable to investigate such issues. Different material models and techniques have been used to model the anisotropic annulus fibrosus, but the abilities of these models to predict damage initiation in the annulus and to explain clinically observed phenomena are unclear. In this study, a hyperelastic anisotropic material model for the annulus with two different sets of material constants, experimentally determined using uniaxial and biaxial loading conditions, were incorporated in a 3D finite element model of a ligamentous FSU. The purpose of the study was to highlight the biomechanical differences (e.g., intradiscal pressure, motion, forces, stresses, strains, etc.) due to the dissimilarity between the two sets of material properties (uniaxial and biaxial). Based on the analyses, the biaxial constants simulations resulted in better agreements with the in vitro and in vivo data, and thus are more suitable for future damage analysis and failure prediction of the annulus under complex multiaxial loading conditions. PMID:26090359

Optical properties of bismuth and gallium substituted thulium iron garnet films

NASA Astrophysics Data System (ADS)

Gerhardt, R.; Sure, S.; Dötsch, H.; Linkewitz, T.; Tolksdorf, W.

1993-09-01

Bismuth and gallium substituted films of thulium iron garnet, grown by liquid phase epitaxy on [111] oriented substrates of gadolinium gallium garnet, are investigated for optical isolator applications. At a wavelength of λ = 1.3 μm the optical damping, the refractive index, the optical anisotropy, and the Faraday rotation are measured as function of the substitution level. It turns out that the growth induced optical anisotropy is very small, similar to the magnetic anisotropy. The observed difference between forward and backward propagation constants of TM modes is in excellent agreement with calculations.

Magnetic domain observation of FeCo thin films fabricated by alternate monoatomic layer deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohtsuki, T., E-mail: ohtsuki@spring8.or.jp; Kotsugi, M.; Ohkochi, T.

2014-01-28

FeCo thin films are fabricated by alternate monoatomic layer deposition method on a Cu{sub 3}Au buffer layer, which in-plane lattice constant is very close to the predicted value to obtain a large magnetic anisotropy constant. The variation of the in-plane lattice constant during the deposition process is investigated by reflection high-energy electron diffraction. The magnetic domain images are also observed by a photoelectron emission microscope in order to microscopically understand the magnetic structure. As a result, element-specific magnetic domain images show that Fe and Co magnetic moments align parallel. A series of images obtained with various azimuth reveal that themore » FeCo thin films show fourfold in-plane magnetic anisotropy along 〈110〉 direction, and that the magnetic domain structure is composed only of 90∘ wall.« less

Elastic properties of sulphur and selenium doped ternary PbTe alloys by first principles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bali, Ashoka, E-mail: rcmallik@physics.iisc.ernet.in; Chetty, Raju, E-mail: rcmallik@physics.iisc.ernet.in; Mallik, Ramesh Chandra, E-mail: rcmallik@physics.iisc.ernet.in

2014-04-24

Lead telluride (PbTe) is an established thermoelectric material which can be alloyed with sulphur and selenium to further enhance the thermoelectric properties. Here, a first principles study of ternary alloys PbS{sub x}Te{sub (1−x)} and PbSe{sub x}Te{sub (1−x)} (0≤x≤1) based on the Virtual Crystal Approximation (VCA) is presented for different ratios of the isoelectronic atoms in each series. Equilibrium lattice parameters and elastic constants have been calculated and compared with the reported data. Anisotropy parameter calculated from the stiffness constants showed a slight improvement in anisotropy of elastic properties of the alloys over undoped PbTe. Furthermore, the alloys satisfied the predictedmore » stability criteria from the elastic constants, showing stable structures, which agreed with the previously reported experimental results.« less

The effect of dipole-dipole interactions on coercivity, anisotropy constant, and blocking temperature of MnFe2O4 nanoparticles

NASA Astrophysics Data System (ADS)

Aslibeiki, B.; Kameli, P.; Salamati, H.

2016-02-01

Superparamagnetic manganese ferrite nanoparticles with mean size of = 6.5(±1.5) nm were synthesized through a solvothermal method using Tri-ethylene glycol as a solvent. The peak temperature of zero field cooled measurements of magnetization and AC magnetic susceptibility curves shifted toward higher temperatures by applying different pressures from 0 to 1 kbar and increasing the powders compaction. The frequency dependence of AC susceptibility measurements indicated the presence of weak dipole-dipole interactions between nanoparticles. By increasing the powders compaction and interactions strength, the coercive field (Hc) increased and squareness (Mr/Ms) decreased. The obtained effective anisotropy constant (Keff), by susceptibility measurements, was from 1.72 × 106 to 2.36 × 106 ergs/cm3 for pressure of 0 to 1 kbar. These values are larger than those obtained from hysteresis loops at 5 K (0.14 × 106 to 0.34 × 106 erg/cm3). Also, the Keff was two orders of magnitude greater than that of bulk MnFe2O4. Size, surface effects, and total energy barrier between equilibrium states were reported as the main causes of large anisotropy. Below 75 K, a signature of weak surface spin glass was observed. However, memory effect experiment indicated that there is no collective superspin glass state in the samples. This study suggests the role of powders compaction on properties of a magnetic nanoparticles system. Furthermore, the coercivity, the anisotropy constant, and the blocking temperature are affected by changing nanoparticles compaction.

45° sign switching of effective exchange bias due to competing anisotropies in fully epitaxial Co3FeN/MnN bilayers.

PubMed

Hajiri, T; Yoshida, T; Filianina, M; Jaiswal, S; Borie, B; Asano, H; Zabel, H; Kläui, M

2017-12-05

We report an unusual angular-dependent exchange bias effect in ferromagnet/antiferromagnet bilayers, where both ferromagnet and antiferromagnet are epitaxially grown. Numerical model calculations predict an approximately 45° period for the sign switching of the exchange-bias field, depending on the ratio between magnetocrystalline anisotropy and exchange-coupling constant. The switching of the sign is indicative of a competition between a fourfold magnetocrystalline anisotropy of the ferromagnet and a unidirectional anisotropy field of the exchange coupling. This predicted unusual angular-dependent exchange bias and its magnetization switching process are confirmed by measurements on fully epitaxial Co 3 FeN/MnN bilayers by longitudinal and transverse magneto-optic Kerr effect magnetometry. These results provide a deeper understanding of the exchange coupling phenomena in fully epitaxial bilayers with tailored materials and open up a complex switching energy landscape engineering by anisotropies.

45° sign switching of effective exchange bias due to competing anisotropies in fully epitaxial Co3FeN/MnN bilayers

NASA Astrophysics Data System (ADS)

Hajiri, T.; Yoshida, T.; Filianina, M.; Jaiswal, S.; Borie, B.; Asano, H.; Zabel, H.; Kläui, M.

2018-01-01

We report an unusual angular-dependent exchange bias effect in ferromagnet/antiferromagnet bilayers, where both ferromagnet and antiferromagnet are epitaxially grown. Numerical model calculations predict an approximately 45° period for the sign switching of the exchange-bias field, depending on the ratio between magnetocrystalline anisotropy and exchange-coupling constant. The switching of the sign is indicative of a competition between a fourfold magnetocrystalline anisotropy of the ferromagnet and a unidirectional anisotropy field of the exchange coupling. This predicted unusual angular-dependent exchange bias and its magnetization switching process are confirmed by measurements on fully epitaxial Co3FeN/MnN bilayers by longitudinal and transverse magneto-optic Kerr effect magnetometry. These results provide a deeper understanding of the exchange coupling phenomena in fully epitaxial bilayers with tailored materials and open up a complex switching energy landscape engineering by anisotropies.

Detecting uniaxial single domain grains with a modified IRM technique

NASA Astrophysics Data System (ADS)

Mitra, R.; Tauxe, L.; Gee, J. S.

2011-12-01

Mid-ocean ridge basalt (MORB) specimens have often been found to have high ratios of saturation remanence to saturation magnetization (Mrs/Ms). This has been attributed either to dominant cubic anisotropy or to insufficient saturating field leading to overestimation of Mrs/Ms of a dominantly uniaxial single domain (USD) assemblage. To resolve this debate, we develop an independent technique to detect USD assemblages. The experimental protocol involves subjecting the specimen to bidirectional impulse fields at each step. The experiment is similar to the conventional isothermal remanent magnetization (IRM) acquisition experiment but the field is applied twice, in antiparallel directions. We define a new parameter, IRAT, as the ratio of the remanences at each field step and show it to have characteristic behaviour for the two assemblages; IRAT ˜1 at all field steps for USD and <1 with a strong field dependence for multi-axial single domain (MSD) grains. We verified the theoretical predictions experimentally with representative USD and MSD specimens. Experiments with MORBs gave low IRATs for specimens having high Mrs/Ms. This argues for a dominant MSD assemblage in the MORBs, possibly cubic in nature. Although undersaturation of the samples can indeed be a contributing factor to the exceptionally high Mrs/Ms, this study shows that the nature of the assemblage cannot be dominantly USD.

Physical property measurements on analog granites related to the joint verification experiment

NASA Astrophysics Data System (ADS)

Martin, Randolph J., III; Coyner, Karl B.; Haupt, Robert W.

1990-08-01

A key element in JVE (Joint Verification Experiment) conducted jointly between the United States and the USSR is the analysis of the geology and physical properties of the rocks in the respective test sites. A study was initiated to examine unclassified crystalline rock specimens obtained from areas near the Soviet site, Semipalatinsk and appropriate analog samples selected from Mt. Katadin, Maine. These rocks were also compared to Sierra White and Westerly Granite which have been studied in great detail. Measurements performed to characterize these rocks were: (1) Uniaxial strain with simultaneous compressional and shear wave velocities; (2) Hydrostatic compression to 150 MPa with simultaneous compressional and shear wave velocities; (3) Attenuation measurements as a function of frequency and strain amplitude for both dry and water saturated conditions. Elastic moduli determined from the hydrostatic compression and uniaxial strain test show that the rock matrix/mineral properties were comparable in magnitudes which vary within 25 percent from sample to sample. These properties appear to be approximately isotropic, especially at high pressures. However, anisotropy evident for certain samples at pressures below 35 MPa is attributed to dominant pre-existing microcrack populations and their alignments. Dependence of extensional attenuation and Young's modulus on strain amplitude were experimentally determined for intact Sierra White granite using the hysteresis loop technique.

Nonlinear effects on composite laminate thermal expansion

NASA Technical Reports Server (NTRS)

Hashin, Z.; Rosen, B. W.; Pipes, R. B.

1979-01-01

Analyses of Graphite/Polyimide laminates shown that the thermomechanical strains cannot be separated into mechanical strain and free thermal expansion strain. Elastic properties and thermal expansion coefficients of unidirectional Graphite/Polyimide specimens were measured as a function of temperature to provide inputs for the analysis. The + or - 45 degrees symmetric Graphite/Polyimide laminates were tested to obtain free thermal expansion coefficients and thermal expansion coefficients under various uniaxial loads. The experimental results demonstrated the effects predicted by the analysis, namely dependence of thermal expansion coefficients on load, and anisotropy of thermal expansion under load. The significance of time dependence on thermal expansion was demonstrated by comparison of measured laminate free expansion coefficients with and without 15 day delay at intermediate temperature.

An Improvement of the Anisotropy and Formability Predictions of Aluminum Alloy Sheets

NASA Astrophysics Data System (ADS)

Banabic, D.; Comsa, D. S.; Jurco, P.; Wagner, S.; Vos, M.

2004-06-01

The paper presents an yield criterion for orthotropic sheet metals and its implementation in a theoretical model in order to calculate the Forming Limit Curves. The proposed yield criterion has been validated for two aluminum alloys: AA3103-0 and AA5182-0, respectively. The biaxial tensile test of cross specimens has been used for the determination of the experimental yield locus. The new yield criterion has been implemented in the Marciniak-Kuczynski model for the calculus of limit strains. The calculated Forming Limit Curves have been compared with the experimental ones, determined by frictionless test: bulge test, plane strain test and uniaxial tensile test. The predicted Forming Limit Curves using the new yield criterion are in good agreement with the experimental ones.

Effect of stress on energy flux deviation of ultrasonic waves in GR/EP composites

NASA Technical Reports Server (NTRS)

Prosser, William H.; Kriz, R. D.; Fitting, Dale W.

1990-01-01

Ultrasonic waves suffer energy flux deviation in graphite/epoxy because of the large anisotropy. The angle of deviation is a function of the elastic coefficients. For nonlinear solids, these coefficients and thus the angle of deviation is a function of stress. Acoustoelastic theory was used to model the effect of stress on flux deviation for unidirectional T300/5208 using previously measured elastic coefficients. Computations were made for uniaxial stress along the x3 axis (fiber axis) and the x1 for waves propagating in the x1x3 plane. These results predict a shift as large as three degrees for the quasi-transverse wave. The shift in energy flux offers a new nondestructive technique of evaluating stress in composites.

Electric field control of magnetic properties in FeRh/PMN-PT heterostructures

NASA Astrophysics Data System (ADS)

Xie, Yali; Zhan, Qingfeng; Shang, Tian; Yang, Huali; Liu, Yiwei; Wang, Baomin; Li, Run-Wei

2018-05-01

We investigated electric control of magnetic properties in FeRh/PMN-PT heterostructures. An electric field of 1 kV/cm applied on the PMN-PT substrate could increase the coercivity of FeRh film from 60 to 161 Oe at 360 K where the FeRh antiferromagnetic to ferromagnetic phase transition occurs. The electric field dependent coercive field reveals a butterfly shape, indicating a strain-mediated magnetoelectric coupling across the FeRh/PMN-PT interface. However, the uniaxial magnetic anisotropy of FeRh is almost unchanged with the applied electric field on the PMN-PT substrate, which suggests the change of coercivity in FeRh films is mainly due to the shift of the magnetic transition temperature under the electric field.

First order transitions by conduction calorimetry: Application to deuterated potassium dihydrogen phosphate ferroelastic crystal under uniaxial pressure

NASA Astrophysics Data System (ADS)

Gallardo, M. C.; Jiménez, J.; Koralewski, M.; del Cerro, J.

1997-03-01

The specific heat c and the heat power W exchanged by a Deuterated Potassium Dihydrogen Phosphate ferroelectric-ferroelastic crystal have been measured simultaneously for both decreasing and increasing temperature at a low constant rate (0.06 K/h) between 175 and 240 K. The measurements were carried out under controlled uniaxial stresses of 0.3 and 4.5±0.1 bar applied to face (110). At Tt=207.9 K, a first order transition is produced with anomalous specific heat behavior in the interval where the transition heat appears. This anomalous behavior is explained in terms of the temperature variation of the heat power during the transition. During cooling, the transition occurs with coexistence of phases, while during heating it seems that metastable states are reached. Excluding data affected by the transition heat, the specific heat behavior agrees with the predictions of a 2-4-6 Landau potential in the range of 4-15 K below Tt while logarithmic behavior is obtained in the range from Tt to 1 K below Tt. Data obtained under 0.3 and 4.5 bar uniaxial stresses exhibit the same behavior.

Slow Crack Growth Behavior and Life/Reliability Analysis of 96 wt % Alumina at Ambient Temperature With Various Specimen/Loading Configurations

NASA Technical Reports Server (NTRS)

Choi, Sung R.; Powers, Lynn M.; Nemeth, Noel N.

2000-01-01

Extensive constant stress-rate testing for 96 wt % alumina was conducted in room-temperature distilled water using four different specimen/loading configurations: rectangular beam test specimens under four-point uniaxial flexure, square plate test specimens in ring-on-ring biaxial flexure, square plate test specimens in ball-on-ring biaxial flexure, and dog-boned tensile test specimens in pure tension. The slow crack growth (SCG) parameter n was almost independent of specimen/loading configurations, in either four-point uniaxial flexure, ring-on-ring biaxial flexure, ball-on-ring biaxial flexure, or pure tension, ranging from n = 35 to 47 with an average value of n = 41.1 +/- 4.5. The prediction of fatigue strength/reliability based on the four-point uniaxial flexure data by using the CARES/Life design code as well as a simple PIA model was in good agreement with both the ring-on-ring biaxial and the ball-on-ring biaxial flexure data. A poor prediction using the PIA model was observed for the dog-boned tensile test specimens, presumably due to different flaw population involved in the tensile test specimens.

Structure organization and magnetic properties of microscale ferrogels: The effect of particle magnetic anisotropy

NASA Astrophysics Data System (ADS)

Ryzhkov, Aleksandr V.; Melenev, Petr V.; Balasoiu, Maria; Raikher, Yuriy L.

2016-08-01

The equilibrium structure and magnetic properties of a ferrogel object of small size (microferrogel(MFG)) are investigated by coarse-grained molecular dynamics. As a generic model of a microferrogel (MFG), a sample with a lattice-like mesh is taken. The solid phase of the MFG consists of magnetic (e.g., ferrite) nanoparticles which are mechanically linked to the mesh making some part of its nodes. Unlike previous models, the finite uniaxial magnetic anisotropy of the particles, as it is the case for real ferrogels, is taken into account. For comparison, two types of MFGs are considered: MFG-1, which dwells in virtually non-aggregated state independently of the presence of an external magnetic field, and MFG-2, which displays aggregation yet under zero field. The structure states of the samples are analyzed with the aid of angle-resolved radial distribution functions and cluster counts. The results reveal the crucial role of the matrix elasticity on the structure organization as well as on magnetization of both MFGs. The particle anisotropy, which plays insignificant role in MFG-1 (moderate interparticle magnetodipole interaction), becomes an important factor in MFG-2 (strong interaction). There, the restrictions imposed on the particle angular freedom by the elastic matrix result in notable diminution of the particle chain lengths as well as the magnetization of the sample. The approach proposed enables one to investigate a large variety of MFGs, including those of capsule type and to purposefully choose the combination of their magnetoelastic parameters.

High piezoelectric performance of poly(lactic acid) film manufactured by solid-state extrusion

NASA Astrophysics Data System (ADS)

Yoshida, Mitsunobu; Onogi, Takayuki; Onishi, Katsuki; Inagaki, Takuma; Tajitsu, Yoshiro

2014-09-01

Recently, the application of uniaxially stretched poly(l-lactic acid) (PLLA) films to speakers, actuators, and pressure sensors has been attempted, taking advantage of their piezoelectric performance. However, the shear piezoelectric constant d14 of uniaxially stretched PLLA film is conventionally 6-10 pC N-1. To realize a high sensitivity of pressure sensors, compact speakers, and actuators, and a low driving voltage, further improvement of the piezoelectric performance is desired. In this study, we carried out solid-state extrusion (SSE) to stretch and orient poly(d-lactic acid) (PDLA) and verified its effects on piezoelectric performance. By SSE, we were able to improve the mechanical strength and elastic modulus of PDLA samples. Furthermore, the d14 of the samples was significantly increased to approximately 20 pC N-1.

Accelerated Gray and White Matter Deterioration With Age in Schizophrenia.

PubMed

Cropley, Vanessa L; Klauser, Paul; Lenroot, Rhoshel K; Bruggemann, Jason; Sundram, Suresh; Bousman, Chad; Pereira, Avril; Di Biase, Maria A; Weickert, Thomas W; Weickert, Cynthia Shannon; Pantelis, Christos; Zalesky, Andrew

2017-03-01

Although brain changes in schizophrenia have been proposed to mirror those found with advancing age, the trajectory of gray matter and white matter changes during the disease course remains unclear. The authors sought to measure whether these changes in individuals with schizophrenia remain stable, are accelerated, or are diminished with age. Gray matter volume and fractional anisotropy were mapped in 326 individuals diagnosed with schizophrenia or schizoaffective disorder and in 197 healthy comparison subjects aged 20-65 years. Polynomial regression was used to model the influence of age on gray matter volume and fractional anisotropy at a whole-brain and voxel level. Between-group differences in gray matter volume and fractional anisotropy were regionally localized across the lifespan using permutation testing and cluster-based inference. Significant loss of gray matter volume was evident in schizophrenia, progressively worsening with age to a maximal loss of 8% in the seventh decade of life. The inferred rate of gray matter volume loss was significantly accelerated in schizophrenia up to middle age and plateaued thereafter. In contrast, significant reductions in fractional anisotropy emerged in schizophrenia only after age 35, and the rate of fractional anisotropy deterioration with age was constant and best modeled with a straight line. The slope of this line was 60% steeper in schizophrenia relative to comparison subjects, indicating a significantly faster rate of white matter deterioration with age. The rates of reduction of gray matter volume and fractional anisotropy were significantly faster in males than in females, but an interaction between sex and diagnosis was not evident. The findings suggest that schizophrenia is characterized by an initial, rapid rate of gray matter loss that slows in middle life, followed by the emergence of a deficit in white matter that progressively worsens with age at a constant rate.

Magnetic characteristics of a high-layer-number NiFe/FeMn multilayer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paterson, G. W., E-mail: gary.paterson@glasgow.ac.uk; Gonçalves, F. J. T.; McFadzean, S.

2015-11-28

We report the static and dynamic magnetic characteristics of a high-layer-number NiFe/FeMn multilayer test structure with potential applications in broadband absorber and filter devices. To allow fine control over the absorption linewidths and to understand the mechanisms governing the resonances in a tailored structure similar to that expected to be used in real world applications, the multilayer was intentionally designed to have layer thickness and interface roughness variations. Magnetometry measurements show that the sample has complex hysteresis loops with features consistent with single ferromagnetic film reversals. Characterisation by transmission electron microscopy allows us to correlate the magnetic properties with structuralmore » features, including the film widths and interface roughnesses. Analysis of resonance frequencies from broadband ferromagnetic resonance measurements as a function of field magnitude and orientation provide values of the local exchange bias, rotatable anisotropy, and uniaxial anisotropy fields for specific layers in the stack and explain the observed mode softening. The linewidths of the multilayer are adjustable around the bias field, approaching twice that seen at larger fields, allowing control over the bandwidth of devices formed from the structure.« less

Magnetic avalanches in manganese-acetate, "magnetic deflagration"

NASA Astrophysics Data System (ADS)

Suzuki, Yoko

Mn12-acetate, first synthesized in 1980 by Lis, is one example of a class of many molecules called single molecule magnets (SMMs) or molecular nanomagnets. These molecules have several atomic spins strongly coupled together within each molecule. They exhibit interesting quantum mechanical phenomena at low temperatures such as quantum tunneling of magnetization, which was first found with Mn12-acetate in 1996 by Friedman, et al. , and Berry phase oscillations which were measured in Fe8 (another SMM) in 1999 by Wernsdorfer, et al. In addition to possible application as memory storage and qubits for quantum computers, these systems provide the means for studies of mesoscopic physics as well as the interactions of the molecules with their environment, such as phonon, photon, nuclear spin, intermolecular dipole, and exchange interactions. Mn12-acetate has twelve Mn ions magnetically coupled in the center of the molecule yielding a giant spin of S = 10 at low temperature. It also has a large uniaxial anisotropy of 65 K. Below 3 K, magnetization curves show strong hysteresis due to the anisotropy barrier. At thesis temperatures, the spin relaxes through the barrier by quantum tunneling of magnetization, which produces regularly-spaced multiple resonant steps in the hysteresis curve. Magnetic avalanches, first detected by Paulsen et al., also occur for some samples only at low temperature, leading to a very fast single-step reversal of the full magnetization, which clearly differs from relaxation by tunneling. In this thesis, I present the results of detailed experimental studies of two aspects of magnetic avalanche phenomenon: "conditions for the triggering of avalanches" and "propagation of the avalanche front". In the first study, we find the magnetic fields at which avalanches occur are stochastically distributed in a particular range of fields. For the second study, we conducted local time-resolved measurements. The results indicate the magnetization avalanches spread as a narrow interface that propagate through the crystal at a constant velocity which is roughly two orders of magnitude smaller than the speed of sound in solids. We argue this phenomenon is closely analogous to the propagation of a flame front(deflagration) through a flammable chemical substance.

Effect of molecular anisotropy on the intensity and degree of polarization of light scattered from model atmospheres

NASA Technical Reports Server (NTRS)

Bahethi, O. P.; Fraser, R. S.

1975-01-01

Computations of the intensity, flux, degree of polarization, and the positions of neutral points are presented for models of the terrestrial gaseous and hazy atmospheres by incorporating the molecular anisotropy due to air in the Rayleigh scattering optical thickness and phase matrix. Molecular anisotropy causes significant changes in the intensity, flux and the degree of polarization of the scattered light. The positions of neutral points do not change significantly. When the Rayleigh scattering optical thickness is kept constant and the molecular anisotropy factor is included only in the Rayleigh phase matrix, the flux does not change and the intensity and positions of neutron points change by a small amount. The changes in the degree of polarization are still significant.

Cyanoresin, cyanoresin/cellulose triacetate blends for thin film, dielectric capacitors

NASA Technical Reports Server (NTRS)

Yen, Shiao-Ping S. (Inventor); Lewis, Carol R. (Inventor); Cygan, Peter J. (Inventor); Jow, T. Richard (Inventor)

1996-01-01

Non brittle dielectric films are formed by blending a cyanoresin such as cyanoethyl, hydroxyethyl cellulose (CRE) with a compatible, more crystalline resin such as cellulose triacetate. The electrical breakdown strength of the blend is increased by orienting the films by uniaxial or biaxial stretching. Blends of high molecular weight CRE with high molecular weight cyanoethyl cellulose (CRC) provide films with high dielectric constants.

Cyanoresin, cyanoresin/cellulose triacetate blends for thin film, dielectric capacitors

NASA Technical Reports Server (NTRS)

Yen, Shiao-Ping (Inventor); Jow, T. Richard (Inventor)

1993-01-01

Non-brittle dielectric films are formed by blending a cyanoresin such as cyanoethyl, hydroxyethyl cellulose (CRE) with a compatible, more crystalline resin such as cellulose triacetate. The electrical breakdown strength of the blend is increased by orienting the films by uniaxial or biaxial stretching. Blends of high molecular weight CRE with high molecular weight cyanoethyl cellulose (CRC) provide films with high dielectric constants.

Prediction study of structural, elastic and electronic properties of FeMP (M = Ti, Zr, Hf) compounds

NASA Astrophysics Data System (ADS)

Tanto, A.; Chihi, T.; Ghebouli, M. A.; Reffas, M.; Fatmi, M.; Ghebouli, B.

2018-06-01

First principles calculations are applied in the study of FeMP (M = Ti, Zr, Hf) compounds. We investigate the structural, elastic, mechanical and electronic properties by combining first-principles calculations with the CASTEP approach. For ideal polycrystalline FeMP (M = Ti, Zr, Hf) the shear modulus, Young's modulus, Poisson's ratio, elastic anisotropy indexes, Pugh's criterion, elastic wave velocities and Debye temperature are also calculated from the single crystal elastic constants. The shear anisotropic factors and anisotropy are obtained from the single crystal elastic constants. The Debye temperature is calculated from the average elastic wave velocity obtained from shear and bulk modulus as well as the integration of elastic wave velocities in different directions of the single crystal.

Cold dark matter confronts the cosmic microwave background - Large-angular-scale anisotropies in Omega sub 0 + lambda 1 models

NASA Technical Reports Server (NTRS)

Gorski, Krzysztof M.; Silk, Joseph; Vittorio, Nicola

1992-01-01

A new technique is used to compute the correlation function for large-angle cosmic microwave background anisotropies resulting from both the space and time variations in the gravitational potential in flat, vacuum-dominated, cold dark matter cosmological models. Such models with Omega sub 0 of about 0.2, fit the excess power, relative to the standard cold dark matter model, observed in the large-scale galaxy distribution and allow a high value for the Hubble constant. The low order multipoles and quadrupole anisotropy that are potentially observable by COBE and other ongoing experiments should definitively test these models.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peng, Hua; College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024; Kioussis, Nicholas, E-mail: nick.kioussis@csun.edu

Using ab initio based calculations, we have calculated the intrinsic lattice thermal conductivity of chiral tellurium. We show that the interplay between the strong covalent intrachain and weak van der Waals interchain interactions gives rise to the phonon band gap between the lower and higher optical phonon branches. The underlying mechanism of the large anisotropy of the thermal conductivity is the anisotropy of the phonon group velocities and of the anharmonic interatomic force constants (IFCs), where large interchain anharmonic IFCs are associated with the lone electron pairs. We predict that tellurium has a large three-phonon scattering phase space that resultsmore » in low thermal conductivity. The thermal conductivity anisotropy decreases under applied hydrostatic pressure.« less

Highly anisotropic mobility in solution processed TIPS-pentacene film studied by independently driven four GaIn probes

NASA Astrophysics Data System (ADS)

Yoshimoto, Shinya; Takahashi, Kohtaro; Suzuki, Mitsuharu; Yamada, Hiroko; Miyahara, Ryosuke; Mukai, Kozo; Yoshinobu, Jun

2017-08-01

We have studied in-plane anisotropy in the field-effect mobility of solution-processed organic semiconductor 6,13-bis(triisopropylsilylethynyl)pentacene by using independently driven four gallium indium (Ga-In) probes. Liquid-metal Ga-In probes are highly effective for reproducible conductivity measurements of organic thin films. We demonstrated that a high mobility anisotropy of 44 was obtained by using a square four-probe method and a feedback circuit to keep the channel potential constant. The present method minimized the influences of the contact resistance and the insensitivity of anisotropy in a linear arrangement in two-dimensional field-effect transistors.

Investigation of anisotropic thermal transport in cross-linked polymers

NASA Astrophysics Data System (ADS)

Simavilla, David Nieto

Thermal transport in lightly cross-linked polyisoprene and polybutadine subjected to uniaxial elongation is investigated experimentally. We employ two experimental techniques to assess the effect that deformation has on this class of materials. The first technique, which is based on Forced Rayleigh Scattering (FRS), allows us to measure the two independent components of the thermal diffusivity tensor as a function of deformation. These measurements along with independent measurements of the tensile stress and birefringence are used to evaluate the stress-thermal and stress-optic rules. The stress-thermal rule is found to be valid for the entire range of elongations applied. In contrast, the stress-optic rule fails for moderate to large stretch ratios. This suggests that the degree of anisotropy in thermal conductivity depends on both orientation and tension in polymer chain segments. The second technique, which is based on infrared thermography (IRT), allows us to measure anisotropy in thermal conductivity and strain induced changes in heat capacity. We validate this method measurements of anisotropic thermal conductivity by comparing them with those obtained using FRS. We find excellent agreement between the two techniques. Uncertainty in the infrared thermography method measurements is estimated to be about 2-5 %. The accuracy of the method and its potential application to non-transparent materials makes it a good alternative to extend current research on anisotropic thermal transport in polymeric materials. A second IRT application allows us to investigate the dependence of heat capacity on deformation. We find that heat capacity increases with stretch ratio in polyisoprene specimens under uniaxial extension. The deviation from the equilibrium value of heat capacity is consistent with an independent set of experiments comparing anisotropy in thermal diffusivity and conductivity employing FRS and IRT techniques. We identify finite extensibility and strain-induced crystallization as the possible causes explaining our observations and evaluate their contribution making use of classical rubber elasticity results. Finally, we study of the role of evaporation-induced thermal effects in the well-know phenomena of the tears of wine. We develop a transport model and support its predictions by experimentally measuring the temperature gradient present in wine and cognac films using IRT. Our results demonstrate that the Marangoni flow responsible for wine tears results from both composition and temperature gradients, whose relative contribution strongly depends on the thermodynamic properties of ethanol-water mixtures. The methods developed here can be used to obtain a deeper understanding of Marangoni flows, which are ubiquitous in nature and modern technology.

The effect of dipole-dipole interactions on coercivity, anisotropy constant, and blocking temperature of MnFe{sub 2}O{sub 4} nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aslibeiki, B., E-mail: b.aslibeiki@tabrizu.ac.ir; Kameli, P.; Salamati, H.

2016-02-14

Superparamagnetic manganese ferrite nanoparticles with mean size of 〈D〉 = 6.5(±1.5) nm were synthesized through a solvothermal method using Tri-ethylene glycol as a solvent. The peak temperature of zero field cooled measurements of magnetization and AC magnetic susceptibility curves shifted toward higher temperatures by applying different pressures from 0 to 1 kbar and increasing the powders compaction. The frequency dependence of AC susceptibility measurements indicated the presence of weak dipole-dipole interactions between nanoparticles. By increasing the powders compaction and interactions strength, the coercive field (H{sub c}) increased and squareness (M{sub r}/M{sub s}) decreased. The obtained effective anisotropy constant (K{sub eff}), by susceptibilitymore » measurements, was from 1.72 × 10{sup 6} to 2.36 × 10{sup 6 }ergs/cm{sup 3} for pressure of 0 to 1 kbar. These values are larger than those obtained from hysteresis loops at 5 K (0.14 × 10{sup 6} to 0.34 × 10{sup 6 }erg/cm{sup 3}). Also, the K{sub eff} was two orders of magnitude greater than that of bulk MnFe{sub 2}O{sub 4}. Size, surface effects, and total energy barrier between equilibrium states were reported as the main causes of large anisotropy. Below 75 K, a signature of weak surface spin glass was observed. However, memory effect experiment indicated that there is no collective superspin glass state in the samples. This study suggests the role of powders compaction on properties of a magnetic nanoparticles system. Furthermore, the coercivity, the anisotropy constant, and the blocking temperature are affected by changing nanoparticles compaction.« less

Giant Perpendicular Magnetic Anisotropy of Graphene-Co Heterostructures

NASA Astrophysics Data System (ADS)

Yang, Hongxin; Hallal, Ali; Chshiev, Mairbek; Spintec theory Team

We report strongly enhanced perpendicular anisotropy (PMA) of Co films by graphene coating via ab-initio calculations. The results show that graphene coating can improve the surface anisotropy of Co film up to twice large of the bare Co case and keep the film effective anisotropy being out-of-plane till 25 Å of Co, in agreement with experiments. Our layer resolved analysis reveals that PMA of Co (Co/Gr) films mainly originates from the adjacent 3 Co layers close to surface (interface) and can be strongly influenced by graphene. Furthermore, orbital hybridization analysis uncovers the origin of the PMA enhancement which is due to graphene-Co bonding causing an inversion of Co 3dz 2 and 3dx 2 - y 2 Bloch states close to Fermi level. Finally, we propose to design Co-graphene heterostructures which possess a linearly increasing surface anisotropy and a constant effective anisotropy. These findings point towards a possible engineering graphene-Co junctions with giant anisotropy, which stands as a hallmark for future spintronic information processing. This work was supported by European Graphene Flagship, European Union-funded STREP project CONCEPT-GRAPHENE, French ANR Projects NANOSIM-GRAPHENE and NMGEM

Cap-Induced Magnetic Anisotropy in Ultra-thin Fe/MgO(001) Films

NASA Astrophysics Data System (ADS)

Brown-Heft, Tobias; Pendharkar, Mihir; Lee, Elizabeth; Palmstrom, Chris

Magnetic anisotropy plays an important role in the design of spintronic devices. Perpendicular magnetic anisotropy (PMA) is preferred for magnetic tunnel junctions because the resulting energy barrier between magnetization states can be very high and this allows enhanced device scalability suitable for magnetic random access memory applications. Interface induced anisotropy is often used to control magnetic easy axes. For example, the Fe/MgO(001) system has been predicted to exhibit PMA in the ultrathin Fe limit. We have used in-situ magneto optic Kerr effect and ex-situ SQUID to study the changes in anisotropy constants between bare Fe/MgO(001) films and those capped with MgO, Pt, and Ta. In some cases in-plane anisotropy terms reverse sign after capping. We also observe transitions from superparamagnetic to ferromagnetic behavior induced by capping layers. Perpendicular anisotropy is observed for Pt/Fe/MgO(001) films after annealing to 300°C. These effects are characterized and incorporated into a magnetic simulation that accurately reproduces the behavior of the films. This work was supported in part by the Semiconductor Research Corporation programs (1) MSR-Intel, and (2) C-SPIN.

Changes in reflectance anisotropy of wheat crop during different phenophases

NASA Astrophysics Data System (ADS)

Lunagaria, Manoj M.; Patel, Haridas R.

2017-04-01

The canopy structure of wheat changes significantly with growth stages and leads to changes in reflectance anisotropy. Bidirectional reflectance distribution function characterises the reflectance anisotropy of the targets, which can be approximated. Spectrodirectional reflectance measurements on wheat crop were acquired using a field goniometer system. The bidirectional reflectance spectra were acquired at 54 view angles to cover the hemispheric span up to 60° view zenith. The observations were made during early growth stages till maturity of the crop. The anisotropy was not constant for all wavelengths and anisotropic factors clearly revealed spectral dependence, which was more pronounced in near principal plane. In near infrared, wheat canopy expressed less reflectance anisotropy because of higher multiple scattering. The broad hotspot signature was noticeable in reflectance of canopy whenever view and solar angles were close. Distinct changes in bidirectional reflectance distribution function were observed during booting to flowering stages as the canopy achieves more uniformity, height and head emergence. The function clearly reveals bowl shape during heading to early milking growth stages of the crop. Late growth stages show less prominent gap and shadow effects. Anisotropy index revealed that wheat exhibits changes in reflectance anisotropy with phenological development and with spectral bands.

Spin-orbit-torque-induced magnetic domain wall motion in Ta/CoFe nanowires with sloped perpendicular magnetic anisotropy.

PubMed

Zhang, Yue; Luo, Shijiang; Yang, Xiaofei; Yang, Chang

2017-05-17

In materials with the gradient of magnetic anisotropy, spin-orbit-torque-induced magnetization behaviour has attracted attention because of its intriguing scientific principle and potential application. Most of the magnetization behaviours microscopically originate from magnetic domain wall motion, which can be precisely depicted using the standard cooperative coordinate method (CCM). However, the domain wall motion in materials with the gradient of magnetic anisotropy using the CCM remains lack of investigation. In this paper, by adopting CCM, we established a set of equations to quantitatively depict the spin-orbit-torque-induced motion of domain walls in a Ta/CoFe nanotrack with weak Dzyaloshinskii-Moriya interaction and magnetic anisotropy gradient. The equations were solved numerically, and the solutions are similar to those of a micromagnetic simulation. The results indicate that the enhanced anisotropy along the track acts as a barrier to inhibit the motion of the domain wall. In contrast, the domain wall can be pushed to move in a direction with reduced anisotropy, with the velocity being accelerated by more than twice compared with that for the constant anisotropy case. This substantial velocity manipulation by anisotropy engineering is important in designing novel magnetic information devices with high reading speeds.

Anisotropy estimation of compacted municipal solid waste using pressurized vertical well liquids injection.

PubMed

Singh, Karamjit; Kadambala, Ravi; Jain, Pradeep; Xu, Qiyong; Townsend, Timothy G

2014-06-01

Waste hydraulic conductivity and anisotropy represent two important parameters controlling fluid movement in landfills, and thus are the key inputs in design methods where predictions of moisture movement are necessary. Although municipal waste hydraulic conductivity has been estimated in multiple laboratory and field studies, measurements of anisotropy, particularly at full scale, are rare, even though landfilled municipal waste is generally understood to be anisotropic. Measurements from a buried liquids injection well surrounded by pressure transducers at a full-scale landfill in Florida were collected and examined to provide an estimate of in-situ waste anisotropy. Liquids injection was performed at a constant pressure and the resulting pore pressures in the surrounding waste were monitored. Numerical fluid flow modeling was employed to simulate the pore pressures expected to occur under the conditions operated. Nine different simulations were performed at three different lateral hydraulic conductivity values and three different anisotropy values. Measured flowrate and pore pressures collected from conditions of approximate steady state were compared with the simulation results to assess the range of anisotropies. The results support that compacted municipal waste in landfills is anisotropic, provide anisotropy estimates greater than previous measurements, and suggest that anisotropy decreases with landfill depth. © The Author(s) 2014.

Symmetry mismatch-driven perpendicular magnetic anisotropy for perovskite/brownmillerite heterostructures.

PubMed

Zhang, Jing; Zhong, Zhicheng; Guan, Xiangxiang; Shen, Xi; Zhang, Jine; Han, Furong; Zhang, Hui; Zhang, Hongrui; Yan, Xi; Zhang, Qinghua; Gu, Lin; Hu, Fengxia; Yu, Richeng; Shen, Baogen; Sun, Jirong

2018-05-15

Grouping different transition metal oxides together by interface engineering is an important route toward emergent phenomenon. While most of the previous works focused on the interface effects in perovskite/perovskite heterostructures, here we reported on a symmetry mismatch-driven spin reorientation toward perpendicular magnetic anisotropy in perovskite/brownmillerite heterostructures, which is scarcely seen in tensile perovskite/perovskite heterostructures. We show that alternately stacking perovskite La 2/3 Sr 1/3 MnO 3 and brownmillerite LaCoO 2.5 causes a strong interface reconstruction due to symmetry discontinuity at interface: neighboring MnO 6 octahedra and CoO 4 tetrahedra at the perovskite/brownmillerite interface cooperatively relax in a manner that is unavailable for perovskite/perovskite interface, leading to distinct orbital reconstructions and thus the perpendicular magnetic anisotropy. Moreover, the perpendicular magnetic anisotropy is robust, with an anisotropy constant two orders of magnitude greater than the in-plane anisotropy of the perovskite/perovskite interface. The present work demonstrates the great potential of symmetry engineering in designing artificial materials on demand.

Magnetic properties of ferritin and akaganeite nanoparticles in aqueous suspension

NASA Astrophysics Data System (ADS)

Koralewski, Marceli; Pochylski, Mikołaj; Gierszewski, Jacek

2013-09-01

We have studied the magnetically induced optical birefringence Δ n of horse spleen ferritin (HSF) and aqueous suspensions of several different-sized iron oxyhydroxide nanoparticles coated with different polysaccharides mimicking ferritin. The structure and dimensions of the akaganeite mineral core were characterized by XRD and TEM, respectively. The stability of the suspensions in the measurement temperature range from 278 to 358 K was confirmed by UV-Vis absorption spectroscopy. The values of optical polarizability anisotropy Δ α, magnetic susceptibility anisotropy Δ χ, and permanent magnetic dipole moment μ m of the akaganeite nanoparticles have been estimated on the basis of the temperature dependence of the Cotton-Mouton (C-M) constant. The magnetic birefringence of Fe-sucrose has been described tentatively by different types of Langevin function allowing another estimation of Δ χ and μ m. The obtained permanent magnetic dipole moment μ m of the studied akaganeite nanoparticles proves small and comparable to that of HSF. The value of μ m is found to increase with decreasing nanoparticle diameter. Observed in a range spanning more than five orders of magnitude, the linear relation between the C-M constant and the iron concentration provides a basis for possible analytical application of the C-M effect in biomedicine. The established relation between the C-M constant and the nanoparticle diameter confirms that the dominant contribution to the measured magnetic birefringence comes from the magnetic susceptibility anisotropy Δ χ. A comparison of the C-M constants of the studied akaganeite nanoparticles with the data obtained for HSF provides evidence that the ferritin core behaves as a non-Euclidian solid.

Magnetic and elastic wave anisotropy in partially molten rocks: insight from experimental melting of synthetic quartz-mica schist (Invited)

NASA Astrophysics Data System (ADS)

Almqvist, B.; Misra, S.; Biedermann, A. R.; Mainprice, D.

2013-12-01

We studied the magnetic and elastic wave speed anisotropy of a synthetically prepared quartz-mica schist, prior to, during and after experimental melting. The synthetic rock was manufactured from a mixture of powders with equal volumes of quartz and muscovite. The powders were initially compacted with 200 MPa uniaxial stress at room temperature and sealed in a stainless steel canister. Subsequently the sealed canister was isostatically pressed at 180 MPa and 580 °C for 24 hours. This produced a solid medium with ~25 % porosity. Mica developed a preferred grain-shape alignment due to the initial compaction with differential load, where mica flakes tend to orient perpendicular to the applied stress and hence define a synthetic foliation plane. In the last stage we used a Paterson gas-medium apparatus, to pressurize and heat the specimens up to 300 MPa and 750 °C for a six hour duration. This stage initially compacted the rock, followed by generation of melt, and finally crystallization of new minerals from the melt. Elastic wave speed measurements were performed in situ at pressure and temperature, with a transducer assembly mounted next to the sample. Magnetic measurements were performed before and after the partial melt experiments. Anisotropy was measured in low- and high-field, using a susceptibility bridge and torsion magnetometer, respectively. Additionally we performed measurements of hysteresis, isothermal remanent magnetization (IRM) and susceptibility as a function of temperature, to investigate the magnetic properties of the rock. The elastic wave speed, before the melting-stage of the experiment, exhibits a distinct anisotropy with velocities parallel to the foliation being about 15 % higher than normal to the foliation plane. Measurements of the magnetic anisotropy in the bulk sample show that anisotropy is originating from the preferred orientation of muscovite, with a prominent flattening fabric. In contrast, specimens that underwent partial melting display a weaker elastic and magnetic anisotropy, because muscovite preferentially melts due to dehydration melting at 750 °C. The decrease in anisotropy can be inferred from in situ observation of elastic wave anisotropy, but also from comparison of measurements of magnetic anisotropy prior to and subsequent to experiment. A distinct anisotropy is however identified after the experiments both in susceptibility and remanence, which appears to be controlled by the original foliation. As muscovite undergoes dehydration melting a small amount of Fe is released into the melt. Crystallization from the melt indicates that the Fe is bound in biotite and Fe-oxides. The bulk susceptibility and saturation remanence increase by more than one order of magnitude in samples after the melting experiment. The newly formed ferrimagnetic phase, identified through hysteresis, IRM and thermomagnetic measurements, have a tight grouping in the magnetite pseudo-single-domain field on a Day plot. Our experiments are pertinent to the study of partially molten rocks and provide an opportunity to help guide research in magnetic and elastic wave anisotropy of migmatite and granite. In particular the results from experiments apply to the understanding of generation and percolation of melt prior to, or coeval to, the onset of deformation.

Critical and compensation behavior of a mixed spin-3/2 and spin-5/2 Ising ferrimagnetic system in a graphene layer

NASA Astrophysics Data System (ADS)

Alzate-Cardona, J. D.; Sabogal-Suárez, D.; Restrepo-Parra, E.

2017-05-01

We have studied the magnetic properties of the mixed spin σ = ± 3/2, ± 1/2 and spin S = ± 5/2, ± 3/2, ± 1/2 Ising ferrimagnetic system in a graphene layer by means of Monte Carlo simulations. The effects of next-nearest neighbors exchange interactions and crystal field anisotropy on the critical and compensation behavior of the system have been investigated. The results show that, for a system with given values of the crystal field anisotropy and exchange interaction constants, a compensation point only exists if the values of the spins in the ground state are such that | S | > | σ | and Jσ is higher than a certain value Jσmin . It was shown that the relationship between Jσmin and JS is linear for a given value of the crystal field constant. The compensation and the critical temperature are very sensitive to the change of JS and Jσ, respectively, while the crystal field anisotropy affects both temperatures to a large extent.

Electric-field-control of magnetic anisotropy of Co0.6Fe0.2B0.2/oxide stacks using reduced voltage

NASA Astrophysics Data System (ADS)

Kita, Koji; Abraham, David W.; Gajek, Martin J.; Worledge, D. C.

2012-08-01

We have demonstrated purely electrical manipulation of the magnetic anisotropy of a Co0.6Fe0.2B0.2 film by applying only 8 V across the CoFeB/oxide stack. A clear transition from in-plane to perpendicular anisotropy was observed. The quantitative relationship between interface anisotropy energy and the applied electric-field was determined from the linear voltage dependence of the saturation field. By comparing the dielectric stacks of MgO/Al2O3 and MgO/HfO2/Al2O3, enhanced voltage control was also demonstrated, due to the higher dielectric constant of the HfO2. These results suggest the feasibility of purely electrical control of magnetization with small voltage bias for spintronics applications.

A Three-Parameter Model for Predicting Fatigue Life of Ductile Metals Under Constant Amplitude Multiaxial Loading

NASA Astrophysics Data System (ADS)

Liu, Jia; Li, Jing; Zhang, Zhong-ping

2013-04-01

In this article, a fatigue damage parameter is proposed to assess the multiaxial fatigue lives of ductile metals based on the critical plane concept: Fatigue crack initiation is controlled by the maximum shear strain, and the other important effect in the fatigue damage process is the normal strain and stress. This fatigue damage parameter introduces a stress-correlated factor, which describes the degree of the non-proportional cyclic hardening. Besides, a three-parameter multiaxial fatigue criterion is used to correlate the fatigue lifetime of metallic materials with the proposed damage parameter. Under the uniaxial loading, this three-parameter model reduces to the recently developed Zhang's model for predicting the uniaxial fatigue crack initiation life. The accuracy and reliability of this three-parameter model are checked against the experimental data found in literature through testing six different ductile metals under various strain paths with zero/non-zero mean stress.

Numerical considerations in the development and implementation of constitutive models

NASA Technical Reports Server (NTRS)

Haisler, W. E.; Imbrie, P. K.

1985-01-01

Several unified constitutive models were tested in uniaxial form by specifying input strain histories and comparing output stress histories. The purpose of the tests was to evaluate several time integration methods with regard to accuracy, stability, and computational economy. The sensitivity of the models to slight changes in input constants was also investigated. Results are presented for In100 at 1350 F and Hastelloy-X at 1800 F.

New insight in the nature of surface magnetic anisotropy in iron borate

NASA Astrophysics Data System (ADS)

Strugatsky, M.; Seleznyova, K.; Zubov, V.; Kliava, J.

2018-02-01

The theory of surface magnetism of iron borate, FeBO3, has been extended by taking into consideration a crystal field contribution to the surface magnetic anisotropy energy. For this purpose, a model of distortion of the six-fold oxygen environment of iron ions in the near-surface layer of iron borate has been put forward. The spin Hamiltonian parameters for isolated Fe3+ ions in the distorted environment of the near-surface layer have been calculated using the Newman's superposition model. The crystal field contribution to the surface magnetic anisotropy energy has been calculated in the framework of the perturbation theory. The model developed allows concluding that the distortions of the iron environment produce a significant crystal field contribution to the surface magnetic anisotropy constant. The results of experimental studies of the surface magnetic anisotropy in iron borate can be described assuming the existence of relative contractions in the near-surface layer of the order of 1 %.

45^○ sign switching of effective exchange bias due to competing anisotropies in fully epitaxial Co₃FeN/MnN bilayers.

PubMed

Hajiri, Tetsuya; Yoshida, Takuya; Filianina, Mariia; Jaiswal, Samridh; Borie, Benjamin; Asano, H; Zabel, Hartmut; Klaui, Mathias

2017-11-20

We report an unusual angular-dependent exchange bias effect in ferromagnet/antiferromagnet bilayers, where both ferromagnet and antiferromagnet are epitaxially grown. Numerical model calculations predict an approximately 45$^\\circ$ period for the sign switching of the exchange-bias field, depending on the ratio between magnetocrystalline anisotropy and exchange-coupling constant. The switching of the sign is indicative of a competition between a fourfold magnetocrystalline anisotropy of the ferromagnet and a unidirectional anisotropy field of the exchange coupling. This predicted unusual angular-dependent exchange bias and its magnetization switching process are confirmed by measurements on fully epitaxial Co$_3$FeN/MnN bilayers by longitudinal and transverse magneto-optic Kerr effect magnetometry. These results provide a deeper understanding of the exchange coupling phenomena in fully epitaxial bilayers with tailored materials and open up a complex switching energy landscape engineering by anisotropies. © 2017 IOP Publishing Ltd.

SU-F-19A-05: Experimental and Monte Carlo Characterization of the 1 Cm CivaString 103Pd Brachytherapy Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reed, J; Micka, J; Culberson, W

Purpose: To determine the in-air azimuthal anisotropy and in-water dose distribution for the 1 cm length of the CivaString {sup 103}Pd brachytherapy source through measurements and Monte Carlo (MC) simulations. American Association of Physicists in Medicine Task Group No. 43 (TG-43) dosimetry parameters were also determined for this source. Methods: The in-air azimuthal anisotropy of the source was measured with a NaI scintillation detector and simulated with the MCNP5 radiation transport code. Measured and simulated results were normalized to their respective mean values and compared. The TG-43 dose-rate constant, line-source radial dose function, and 2D anisotropy function for this sourcemore » were determined from LiF:Mg,Ti thermoluminescent dosimeter (TLD) measurements and MC simulations. The impact of {sup 103}Pd well-loading variability on the in-water dose distribution was investigated using MC simulations by comparing the dose distribution for a source model with four wells of equal strength to that for a source model with strengths increased by 1% for two of the four wells. Results: NaI scintillation detector measurements and MC simulations of the in-air azimuthal anisotropy showed that ≥95% of the normalized data were within 1.2% of the mean value. TLD measurements and MC simulations of the TG-43 dose-rate constant, line-source radial dose function, and 2D anisotropy function agreed to within the experimental TLD uncertainties (k=2). MC simulations showed that a 1% variability in {sup 103}Pd well-loading resulted in changes of <0.1%, <0.1%, and <0.3% in the TG-43 dose-rate constant, radial dose distribution, and polar dose distribution, respectively. Conclusion: The CivaString source has a high degree of azimuthal symmetry as indicated by the NaI scintillation detector measurements and MC simulations of the in-air azimuthal anisotropy. TG-43 dosimetry parameters for this source were determined from TLD measurements and MC simulations. {sup 103}Pd well-loading variability results in minimal variations in the in-water dose distribution according to MC simulations. This work was partially supported by CivaTech Oncology, Inc. through an educational grant for Joshua Reed, John Micka, Wesley Culberson, and Larry DeWerd and through research support for Mark Rivard.« less

Kinetic arrest of field-temperature induced first order phase transition in quasi-one dimensional spin system Ca{sub 3}Co{sub 2}O{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

De, Santanu, E-mail: santanujuphys91@gmail.com; Kumar, Kranti; Banerjee, A.

We have found that the geometrically frustrated spin chain compound Ca{sub 3}Co{sub 2}O{sub 6} belonging to Ising like universality class with uniaxial anisotropy shows kinetic arrest of first order intermediate phase (IP) to ferrimagnetic (FIM) transition. In this system, dc magnetization measurements followed by different protocols suggest the coexistence of high temperature IP with equilibrium FIM phase in low temperature. Formation of metastable state due to hindered first order transition has also been probed through cooling and heating in unequal field (CHUF) protocol. Kinetically arrested high temperature IP appears to persist down to almost the spin freezing temperature in thismore » system.« less

Influence of nitrogen on magnetic properties of indium oxide

NASA Astrophysics Data System (ADS)

Ashok, Vishal Dev; De, S. K.

2013-07-01

Magnetic properties of indium oxide (In2O3) prepared by the decomposition of indium nitrate/indium hydroxide in the presence of ammonium chloride (NH4Cl) has been investigated. Structural and optical characterizations confirm that nitrogen is incorporated into In2O3. Magnetization has been convoluted to individual diamagnetic paramagnetic and ferromagnetic contributions with varying concentration of NH4Cl. Spin wave with diverging thermal exponent dominates in both field cool and zero field cool magnetizations. Uniaxial anisotropy plays an important role in magnetization as a function of magnetic field at higher concentration of NH4Cl. Avrami analysis indicates the absence of pinning effect in the magnetization process. Ferromagnetism has been interpreted in terms of local moments induced by anion dopant and strong hybridization with host cation.

The formation of magnetic silicide Fe3Si clusters during ion implantation

NASA Astrophysics Data System (ADS)

Balakirev, N.; Zhikharev, V.; Gumarov, G.

2014-05-01

A simple two-dimensional model of the formation of magnetic silicide Fe3Si clusters during high-dose Fe ion implantation into silicon has been proposed and the cluster growth process has been computer simulated. The model takes into account the interaction between the cluster magnetization and magnetic moments of Fe atoms random walking in the implanted layer. If the clusters are formed in the presence of the external magnetic field parallel to the implanted layer, the model predicts the elongation of the growing cluster in the field direction. It has been proposed that the cluster elongation results in the uniaxial magnetic anisotropy in the plane of the implanted layer, which is observed in iron silicide films ion-beam synthesized in the external magnetic field.

Electronic transport on the Shastry-Sutherland lattice in Ising-type rare-earth tetraborides

NASA Astrophysics Data System (ADS)

Ye, Linda; Suzuki, Takehito; Checkelsky, Joseph G.

2017-05-01

In the presence of a magnetic field frustrated spin systems may exhibit plateaus at fractional values of saturation magnetization. Such plateau states are stabilized by classical and quantum mechanisms including order by disorder, triplon crystallization, and various competing order effects. In the case of electrically conducting systems, free electrons represent an incisive probe for the plateau states. Here we study the electrical transport of Ising-type rare-earth tetraborides R B4 (R =Er , Tm), a metallic Shastry-Sutherland lattice showing magnetization plateaus. We find that the longitudinal and transverse resistivities reflect scattering with both the static and the dynamic plateau structure. We model these results consistently with the expected strong uniaxial anisotropy on a quantitative level, providing a framework for the study of plateau states in metallic frustrated systems.

A geometric exploration of stress in deformed liquid foams

NASA Astrophysics Data System (ADS)

Evans, Myfanwy E.; Schröder-Turk, Gerd E.; Kraynik, Andrew M.

2017-03-01

We explore an alternate way of looking at the rheological response of a yield stress fluid: using discrete geometry to probe the heterogeneous distribution of stress in soap froth. We present quasi-static, uniaxial, isochoric compression and extension of three-dimensional random monodisperse soap froth in periodic boundary conditions and examine the stress and geometry that result. The stress and shape anisotropy of individual cells is quantified by Q, a scalar measure derived from the interface tensor that gauges each cell’s contribution to the global stress. Cumulatively, the spatial distribution of highly deformed cells allows us to examine how stress is internally distributed. The topology of highly deformed cells, how they arrange relative to one another in space, gives insight into the heterogeneous distribution of stress.

Magnetic properties of Ni nanoparticles dispersed in silica prepared by high-energy ball milling

NASA Astrophysics Data System (ADS)

González, E. M.; Montero, M. I.; Cebollada, F.; de Julián, C.; Vicent, J. L.; González, J. M.

1998-04-01

We analyze the magnetic properties of mechanically ground nanosized Ni particles dispersed in a SiO2 matrix. Our magnetic characterization of the as-milled samples show the occurrence of two blocking processes and that of non-monotonic milling time evolutions of the magnetic-order temperature, the high-field magnetization and the saturation coercivity. The measured coercivities exhibit giant values and a uniaxial-type temperature dependence. Thermal treatment carried out in the as-prepared samples result in a remarkable coercivity reduction and in an increase of the high-field magnetization. We conclude, on the basis of the consideration of a core (pure Ni) and shell (Ni-Si inhomogeneous alloy) particle structure, that the magnetoelastic anisotropy plays the dominant role in determining the magnetic properties of our particles.

Critical switching fluence of L10-FePt nanoparticles with practical size to ultrafast all-optical polarization switching

NASA Astrophysics Data System (ADS)

Huang, Tao; Wang, Haiwei; Cheng, Weiming; Zou, Yuhao; Xie, Changsheng

2017-06-01

The magnetic storage industry will be pushed into a new era by emerging magnetic materials and ingenious read/write techniques. Recently, L10-FePt nanoparticles with exceptionally high uniaxial anisotropy, combined with the technique of all-optical magnetic switching, have increasingly drawn the attention of researchers. Focusing on L10-FePt nanoparticles, we report the superparamagnetic size limits and three elaborate stages of magnetic orientation switching, which demonstrate that in terms of the opto-magnetic responses of L10-FePt nanoparticles with the size of 6 nm, the fluence of an ultrashort laser pulse should not be larger than the level of 40 mJ/cm2 in order to achieve the helicity-dependent all-optical switching.

Effect of Stress on Energy Flux Deviation of Ultrasonic Waves in Ultrasonic Waves in GR/EP Composites

NASA Technical Reports Server (NTRS)

Prosser, William H.; Kriz, R. D.; Fitting, Dale W.

1990-01-01

Ultrasonic waves suffer energy flux deviation in graphite/epoxy because of the large anisotropy. The angle of deviation is a function of the elastic coefficients. For nonlinear solids, these coefficients and thus the angle of deviation is a function of stress. Acoustoelastic theory was used to model the effect of stress on flux deviation for unidirectional T300/5208 using previously measured elastic coefficients. Computations were made for uniaxial stress along the x3 axis fiber axis) and the x1 axis for waves propagating in the x1x3 plane. These results predict a shift as large as three degrees for the quasi-transverse wave. The shift in energy flux offers new nondestructive technique of evaluating stress in composites.

Measurement and control of in-plane surface chemistry during the oxidation of H-terminated (111) Si

PubMed Central

Gokce, Bilal; Adles, Eric J.; Aspnes, David E.; Gundogdu, Kenan

2010-01-01

In-plane directional control of surface chemistry during interface formation can lead to new opportunities regarding device structures and applications. Control of this type requires techniques that can probe and hence provide feedback on the chemical reactivity of bonds not only in specific directions but also in real time. Here, we demonstrate both control and measurement of the oxidation of H-terminated (111) Si. Control is achieved by externally applying uniaxial strain, and measurement by second-harmonic generation (SHG) together with the anisotropic-bond model of nonlinear optics. In this system anisotropy results because bonds in the strain direction oxidize faster than those perpendicular to it, leading in addition to transient structural changes that can also be detected at the bond level by SHG. PMID:20876145

Computer simulation of single-phase nanocrystalline permanent magnets

NASA Astrophysics Data System (ADS)

Griffiths, M. K.; Bishop, J. E. L.; Tucker, J. W.; Davies, H. A.

1998-03-01

Demagnetizing curves have been calculated numerically for three-dimensional micromagnetic model assemblies of randomly oriented, magnetically hard, exchange coupled, uniaxial nanocrystals as typified by rapidly quenched Nd 2Fe 14B. The curves were obtained as a sequence of static equilibrium states in an incrementally changing applied field. The magnetization distribution in each state was obtained by minimizing the sum of the exchange, anisotropy and Zeeman energies of the assembly, using a modified LaBonte method, with computational elements as small as 1.11 nm (roughly {1}/{4} the domain wall thickness in Nd 2Fe 14B). For computational economy, internal dipolar interactions were ignored in the energy minimization. For a material with the magnetic constants of stoichiometric Nd 2Fe 14B, tests showed that these interactions contribute less than 3% to the energy. On increasing the model grain size from 4.4 to 36 nm, the reduced remanence fell from 76 to 54% and the reduced intrinsic coercivity μ0iHCMS/ KU increased from 0.16 to 0.46 (just under half the Stoner-Wohlfarth value); both sets of results are in reasonable agreement with experimental values. The energy product, evaluated for Nd 2Fe 14B, ranged from ˜224 kJ/m 3 for 10 nm grains to ˜128 kJ/m 3 for 36 nm grains. For grain sizes ⩾20 nm, spatial magnetization variation was confined to domain walls centred on the grain boundaries. For grain sizes decreasing below about twice the domain wall thickness, spatial magnetization variation extended to the interior of the grains and exhibited increasingly long-range correlations.

Significant manipulation of output performance of a bridge-structured spin valve magnetoresistance sensor via an electric field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yue; Yan, Baiqian; Ou-Yang, Jun

2016-01-28

Through principles of spin-valve giant magnetoresistance (SV-GMR) effect and its application in magnetic sensors, we have investigated electric-field control of the output performance of a bridge-structured Co/Cu/NiFe/IrMn SV-GMR sensor on a PZN-PT piezoelectric substrate using the micro-magnetic simulation. We centered on the influence of the variation of uniaxial magnetic anisotropy constant (K) of Co on the output of the bridge, and K was manipulated via the stress of Co, which is generated from the strain of a piezoelectric substrate under an electric field. The results indicate that when K varies between 2 × 10{sup 4 }J/m{sup 3} and 10 × 10{sup 4 }J/m{sup 3}, the outputmore » performance can be significantly manipulated: The linear range alters from between −330 Oe and 330 Oe to between −650 Oe and 650 Oe, and the sensitivity is tuned by almost 7 times, making it possible to measure magnetic fields with very different ranges. According to the converse piezoelectric effect, we have found that this variation of K can be realized by applying an electric field with the magnitude of about 2–20 kV/cm on a PZN-PT piezoelectric substrate, which is realistic in application. This result means that electric-control of SV-GMR effect has potential application in developing SV-GMR sensors with improved performance.« less

Molecular order and T1-relaxation, cross-relaxation in nitroxide spin labels

NASA Astrophysics Data System (ADS)

Marsh, Derek

2018-05-01

Interpretation of saturation-recovery EPR experiments on nitroxide spin labels whose angular rotation is restricted by the orienting potential of the environment (e.g., membranes) currently concentrates on the influence of rotational rates and not of molecular order. Here, I consider the dependence on molecular ordering of contributions to the rates of electron spin-lattice relaxation and cross relaxation from modulation of N-hyperfine and Zeeman anisotropies. These are determined by the averages and , where θ is the angle between the nitroxide z-axis and the static magnetic field, which in turn depends on the angles that these two directions make with the director of uniaxial ordering. For saturation-recovery EPR at 9 GHz, the recovery rate constant is predicted to decrease with increasing order for the magnetic field oriented parallel to the director, and to increase slightly for the perpendicular field orientation. The latter situation corresponds to the usual experimental protocol and is consistent with the dependence on chain-labelling position in lipid bilayer membranes. An altered dependence on order parameter is predicted for saturation-recovery EPR at high field (94 GHz) that is not entirely consistent with observation. Comparisons with experiment are complicated by contributions from slow-motional components, and an unexplained background recovery rate that most probably is independent of order parameter. In general, this analysis supports the interpretation that recovery rates are determined principally by rotational diffusion rates, but experiments at other spectral positions/field orientations could increase the sensitivity to order parameter.

Fluid Effects on Shear for Seismic Waves in Finely Layered Porous Media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berryman, J G

Although there are five effective shear moduli for any layered VTI medium, one and only one effective shear modulus of the layered system (namely the uniaxial shear) contains all the dependence of pore fluids on the elastic or poroelastic constants that can be observed in vertically polarized shear waves. Pore fluids can increase the magnitude the shear energy stored in this modulus by an amount that ranges from the smallest to the largest effective shear moduli of the VTI system. But, since there are five shear moduli in play, the overall increase in shear energy due to fluids is reducedmore » by a factor of about 5 in general. We can therefore give definite bounds on the maximum increase of overall shear modulus, being about 20% of the allowed range as liquid is fully substituted for gas. An attendant increase of density (depending on porosity and fluid density) by approximately 5 to 10% decreases the shear wave speed and, thereby, partially offsets the effect of this shear modulus increase. The final result is an increase of shear wave speed on the order of 5 to 10%. This increase is shown to be possible under most favorable circumstances - i.e. when the shear modulus fluctuations are large (resulting in strong anisotropy) and the medium behaves in an undrained fashion due to fluid trapping. At frequencies higher than seismic (such as sonic and ultrasonic waves for well-logging or laboratory experiments), resulting short response times also produce the requisite undrained behavior and, therefore, fluids also affect shear waves at high frequencies by increasing rigidity.« less

Spin canting in a Dy-based single-chain magnet with dominant next-nearest-neighbor antiferromagnetic interactions

NASA Astrophysics Data System (ADS)

Bernot, K.; Luzon, J.; Caneschi, A.; Gatteschi, D.; Sessoli, R.; Bogani, L.; Vindigni, A.; Rettori, A.; Pini, M. G.

2009-04-01

We investigate theoretically and experimentally the static magnetic properties of single crystals of the molecular-based single-chain magnet of formula [Dy(hfac)3NIT(C6H4OPh)]∞ comprising alternating Dy3+ and organic radicals. The magnetic molar susceptibility χM displays a strong angular variation for sample rotations around two directions perpendicular to the chain axis. A peculiar inversion between maxima and minima in the angular dependence of χM occurs on increasing temperature. Using information regarding the monomeric building block as well as an ab initio estimation of the magnetic anisotropy of the Dy3+ ion, this “anisotropy-inversion” phenomenon can be assigned to weak one-dimensional ferromagnetism along the chain axis. This indicates that antiferromagnetic next-nearest-neighbor interactions between Dy3+ ions dominate, despite the large Dy-Dy separation, over the nearest-neighbor interactions between the radicals and the Dy3+ ions. Measurements of the field dependence of the magnetization, both along and perpendicularly to the chain, and of the angular dependence of χM in a strong magnetic field confirm such an interpretation. Transfer-matrix simulations of the experimental measurements are performed using a classical one-dimensional spin model with antiferromagnetic Heisenberg exchange interaction and noncollinear uniaxial single-ion anisotropies favoring a canted antiferromagnetic spin arrangement, with a net magnetic moment along the chain axis. The fine agreement obtained with experimental data provides estimates of the Hamiltonian parameters, essential for further study of the dynamics of rare-earth-based molecular chains.

Monitoring of the alignment in developing tissue-engineered constructs by elastic scattering spectroscopy

NASA Astrophysics Data System (ADS)

Kostyuk, Oksana P.; Brown, Robert A.

2004-07-01

Elastic light scattering spectroscopy was applied to monitor the development of alignment in fibroblast-populated collagen gels. Gels were seeded with human dermal fibroblasts in rectangular moulds so uniaxial tension was generated in the central zone of the gels due to cell contraction. There was a gradual transition from a disorganized matrix with round cells to highly organized cell/collagen matrix, aligned in the direction of the principal strain developed during gel contraction (observed with light microscopy under phase contrast). Spectra of the backscattered light (320 - 850 nm) were acquired via an optical probe with 2.75-mm source-detector separation, positioned perpendicularly to the gel surface, at 0, 17, 24, 41, 47, 65 and 72h. Spectra were registered for light propagating along, perpendicular and at intermediate angles relative to the cell/collagen matrix alignment, at 45° intervals. Backscatter was isotropic for non-contracted gels. However, as gels contracted, anisotropy of backscatter gradually increased. This was characterized by an 'anisotropy factor,' AF (500 nm), calculated as the ratio of backscatter intensities at 90° and 0° positions of the probe, at 500 nm. AF (500nm) increased from 1.2 +/- 0.1 at 0h up to 2.6 +/- 0.4 at 72h of contraction, with more backscatter detected perpendicular to the cell/collagen matrix alignment than in parallel direction. Thus, backscatter anisotropy allows determination of the direction of the preferential alignment and quantitative monitoring of its development during gel contraction. It is possible to use measurements of this type to quantify a proportion of oriented fibrils in the gel using modeling.

Elasticity of Pargasite Amphibole: A Hydrous Phase at Mid Lithospheric Discontinuity

NASA Astrophysics Data System (ADS)

Peng, Y.; Mookherjee, M.

2017-12-01

Mid Lithospheric Discontinuity (MLD) is characterized by a low shear wave velocity ( 3 to 10 %). In cratons, the depth of MLD varies between 80 and 100 km. The reduction of the shear wave velocity at MLD is similar to what is observed in the lithosphere-asthenosphere boundary (LAB). Such low velocity at MLD could be caused by partial melting, temperature induced grain boundary sliding, changes in the elastic anisotropy, and/or metasomatism which may lead to the formation of hydrous phases including mica and amphibole. Thus, it is clear that in order to assess the role of metasomatism at MLD, we need better constraints on the elasticity of hydrous phases. However, such elasticity data are scarce. In this study, we explore elasticity of pargasite amphibole [NaCa2(Mg4Al)(Si6Al2)O22(OH)2] using density functional theory (DFT) with local density approximation (LDA) and generalized gradient approximation (GGA). We find that the pressure-volume results can be adequately described by a finite strain equation with the bulk modulus, K0 being 102 and 85 GPa for LDA and GGA respectively. We also determined the full elastic constant tensor (Cij) using the finite difference method. The bulk modulus, K0 determined from the full elastic constant tensor is 104 GPa for LDA and 87 GPa for GGA. The shear modulus, G0 determined from the full elastic constant tensor is 64 GPa for LDA and 58 GPa for GGA. The bulk and shear moduli predicted with LDA are 5 and 1 % stiffer than the recent results [1]. In contrast, the bulk and shear moduli predicted with GGA are 12 and 10 % softer compared to the recent results [1]. The full elastic constant tensor for pargasite shows significant anisotropy. For instance, LDA predicts compressional (AVP) and shear (AVS) wave anisotropy of 22 and 20 % respectively. At higher pressure, elastic moduli stiffen. However, temperature is likely to have an opposite effect on the elasticity and this remains largely unknown for pargasite. Compared to the major mantle minerals, pargasite has softer elastic constants and significant anisotropy and may explain the reduction in shear wave velocity at MLD. Reference: [1] Brown, J. M., Abramson, E. H.,2016, Phys. Earth Planet. Int., 261, 161-171. Acknowledgement: This work is supported by US NSF award EAR 1639552.

Stress anisotropy and velocity anisotropy in low porosity shale

NASA Astrophysics Data System (ADS)

Kuila, U.; Dewhurst, D. N.; Siggins, A. F.; Raven, M. D.

2011-04-01

Shales are known for often marked intrinsic anisotropy of many of their properties, including strength, permeability and velocity for example. In addition, it is well known that anisotropic stress fields can also have a significant impact on anisotropy of velocity, even in an isotropic medium. This paper sets out to investigate the ultrasonic velocity response of well-characterised low porosity shales from the Officer Basin in Western Australia to both isotropic and anisotropic stress fields and to evaluate the velocity response to the changing stress field. During consolidated undrained multi-stage triaxial tests on core plugs cut normal to bedding, V pv increases monotonically with increasing effective stress and V s1 behaves similarly although with some scatter. V ph and V sh remain constant initially but then decrease within each stage of the multi-stage test, although velocity from stage to stage at any given differential stress increases. This has the impact of decreasing both P-wave (ɛ) and S-wave anisotropy (γ) through application of differential stress within each loading stage. However, increasing the magnitude of an isotropic stress field has little effect on the velocity anisotropies. The intrinsic anisotropy of the shale remains reasonably high at the highest confining pressures. The results indicate the magnitude and orientation of the stress anisotropy with respect to the shale microfabric has a significant impact on the velocity response to changing stress fields.

Freezing point and solid-liquid interfacial free energy of Stockmayer dipolar fluids: a molecular dynamics simulation study.

PubMed

Wang, Jun; Apte, Pankaj A; Morris, James R; Zeng, Xiao Cheng

2013-09-21

Stockmayer fluids are a prototype model system for dipolar fluids. We have computed the freezing temperatures of Stockmayer fluids at zero pressure using three different molecular-dynamics simulation methods, namely, the superheating-undercooling method, the constant-pressure and constant-temperature two-phase coexistence method, and the constant-pressure and constant-enthalpy two-phase coexistence method. The best estimate of the freezing temperature (in reduced unit) for the Stockmayer (SM) fluid with the dimensionless dipole moment μ*=1, √2, √3 is 0.656 ± 0.001, 0.726 ± 0.002, and 0.835 ± 0.005, respectively. The freezing temperature increases with the dipolar strength. Moreover, for the first time, the solid-liquid interfacial free energies γ of the fcc (111), (110), and (100) interfaces are computed using two independent methods, namely, the cleaving-wall method and the interfacial fluctuation method. Both methods predict that the interfacial free energy increases with the dipole moment. Although the interfacial fluctuation method suggests a weaker interfacial anisotropy, particularly for strongly dipolar SM fluids, both methods predicted the same trend of interfacial anisotropy, i.e., γ100 > γ110 > γ111.

Structure induced magnetic anisotropy behavior in Co/GaAs(001) films

NASA Astrophysics Data System (ADS)

Blundell, S. J.; Gester, M.; Bland, J. A. C.; Daboo, C.; Gu, E.; Baird, M. J.; Ives, A. J. R.

1993-05-01

Epitaxial Co has been grown on GaAs(001) and studied by both low-energy electron diffraction (LEED) and reflection high-energy electron diffraction (RHEED), and by the magneto-optic Kerr effect (MOKE) and polarized neutron reflection (PNR). Three samples were fabricated using different growth procedures: (1) ``interrupted'' growth (including an anneal); (2) and (3) continuous growth of similar thicknesses. For sample 1, RHEED patterns indicate an initial growth in the bcc phase followed by a relaxation into a distorted single phase at completion of growth, whereas samples 2 and 3 showed a multicrystalline structure after growth. LEED patterns were used to check the existence of the 2×4 reconstruction patterns before growth, but no LEED patterns could be obtained after more than 2 Å Co was deposited, in contrast to the RHEED patterns which remained visible throughout the growth. Structural analysis of the completed films indicates the formation of a ˜10 Å CoO layer on the Co/air interface, and gives thicknesses for magnetic material of (1) 30 Å and (2) 80 Å. Sample 1 showed a dominant fourfold magnetic anisotropy with the easy axis parallel to the (100) direction and with a strength 2K4/M of ˜0.5 kOe, smaller in magnitude than that reported for bcc films on GaAs(110) but along the same axis [G. A. Prinz et al., J. Appl. Phys. 57, 3672 (1985)]. However, samples 2 and 3 showed only a large uniaxial anisotropy along the (110) direction of strength 2K1/M of ˜1.5 kOe and ˜2.5 kOe, respectively, similar in magnitude to those previously observed [G. A. Prinz et al., J. Appl. Phys. 57, 3676 (1985)]. We attribute the origin of the contrasting magnetic anisotropy behavior observed to the differences in final structure.

CeCo5 thin films with perpendicular anisotropy grown by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Sharma, S.; Hildebrandt, E.; Major, M.; Komissinskiy, P.; Radulov, I.; Alff, L.

2018-04-01

Buffer-free, highly textured (0 0 1) oriented CeCo5 thin films showing perpendicular magnetic anisotropy were synthesized on (0 0 1) Al2O3 substrates by molecular beam epitaxy. Ce exists in a mixture of Ce3+ and Ce4+ valence states as shown by X-ray photoelectron spectroscopy. The first anisotropy constant, K1, as measured by torque magnetometry was 0.82 MJ/m3 (8.2 ×106erg /cm3) . A maximum coercivity of 5.16 kOe with a negative temperature coefficient of -0.304%K-1 and a magnetization of 527.30 emu/cm3 was measured perpendicular to the film plane at 5 K. In addition, a large anisotropy of the magnetic moment of 15.5% was observed. These magnetic parameters make CeCo5 a potential candidate material for spintronic and magnetic recording applications.

Micromechanisms of deformation in shales

NASA Astrophysics Data System (ADS)

Bonnelye, A.; Gharbi, H.; Hallais, S.; Dimanov, A.; Bornert, M.; Picard, D.; Mezni, M.; Conil, N.

2017-12-01

One of the envisaged solutions for nuclear wastes disposal is underground repository in shales. For this purpose, the Callovo Oxfordian (Cox) argillaceous formation is extensively studied. The hydro-mechanical behavior of the argillaceous rock is complex, like the multiphase and multi-scale structured material itself. The argilaceous matrix is composed of interstratified illite-smectite particles, it contains detritic quartz and calcite, accessory pyrite, and the rock porosity ranges from micrometre to nanometre scales. Besides the bedding anisotropy, structural variabilities exist at all scales, from the decametric-metric scales of the geological formation to the respectively millimetric and micrometric scales of the aggregates of particles and clay particles Our study aims at understanding the complex mechanisms which are activated at the micro-scale and are involved in the macroscopic inelastic deformation of such a complex material. Two sets of experiments were performed, at two scales on three bedding orientations (90°, 45° and 0°). The first set was dedicated to uniaxial deformation followed with an optical set-up with a pixel resolution of 0.55µm. These experiments allowed us to see the fracture propagation with different patterns depending on the bedding orientation. For the second set of experiments, an experimental protocol was developed in order to perform uniaxial deformation experiment at controlled displacement rate, inside an environmental scanning electron microscope (ESEM), under controlled relative humidity, in order to preserve as much as possible the natural state of saturation of shales. We aimed at characterizing the mechanical anisotropy and the mechanisms involved in the deformation, with an image resolution below the micormeter. The observed sample surfaces were polished by broad ion beam in order to reveal the fine microstructures of the argillaceous matrix. In both cases, digital images were acquired at different loading stages during the deformation process and Digital Image Correlation Technique (DIC) was applied in order to retrieve full strain fields at various scales from sample scale to microstructure scale. The analysis allows for identification of the active mechanisms, their relationships to the microstructure and their interactions.

The Homogenized Energy Model (HEM) for Characterizing Polarization and Strains in Hysteretic Ferroelectric Materials: Material Properties and Uniaxial Model Development

DTIC Science & Technology

2012-01-01

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Self-organization of the magnetization in ferromagnetic nanowires

NASA Astrophysics Data System (ADS)

Ivanov, A. A.; Orlov, V. A.

2017-10-01

In this work we demonstrate the occurrence of the characteristic spatial scale in the distribution of magnetization unrelated to the domain wall or crystallite size with using computer simulation of magnetization in a polycrystalline ferromagnetic nanowire. This is the stochastic domain size. We show that this length is included in the spectral density of the pinning force of domain wall on inhomogeneities of the crystallographic anisotropy. The constant and distribution of easy axes directions of the effective anisotropy of stochastic domain, are analytically calculated.

Exact anisotropic viscous fluid solutions of Einstein's equations

NASA Astrophysics Data System (ADS)

Goenner, H. F. M.; Kowalewski, F.

1989-05-01

A method for obtaining anisotropic, rotationless viscous fluid matter solutions of Bianchi type I and Segré type [1, 111] with the barotropic equation of state is presented. Solutions for which the anisotropy decreases exponentially or with a power law as well as solutions with average Hubble parameterH ˜t -1 are discussed. Also, a class of solutions with constant anisotropy and Bianchi type VIh is found. The dominant energy condition holds and the transport coefficients show the right sign.

Searching for a Cosmological Preferred Direction with 147 Rotationally Supported Galaxies

NASA Astrophysics Data System (ADS)

Zhou, Yong; Zhao, Zhi-Chao; Chang, Zhe

2017-10-01

It is well known that the Milgrom’s modified Newtonian dynamics (MOND) explains well the mass discrepancy problem in galaxy rotation curves. The MOND predicts a universal acceleration scale below which the Newtonian dynamics is still invalid. We get the universal acceleration scale of 1.02 × 10-10 m s-2 by using the Spitzer Photometry and Accurate Rotation Curves (SPARC) data set. Milgrom suggested that the acceleration scale may be a fingerprint of cosmology on local dynamics and related to the Hubble constant g † ˜ cH 0. In this paper, we use the hemisphere comparison method with the SPARC data set to investigate possible spatial anisotropy on the acceleration scale. It is found that the hemisphere of the maximum acceleration scale is in the direction (l,b)=(175\\buildrel{\\circ}\\over{.} {5}-{10^\\circ }+{6^\\circ }, -6\\buildrel{\\circ}\\over{.} {5}-{3^\\circ }+{9^\\circ }) with g †,max = 1.10 × 10-10 m s-2, while the hemisphere of the minimum acceleration scale is in the opposite direction (l,b)=(355\\buildrel{\\circ}\\over{.} {5}-{10^\\circ }+{6^\\circ }, 6\\buildrel{\\circ}\\over{.} {5}-{9^\\circ }+{3^\\circ }) with g †,min = 0.76 × 10-10 m s-2. The level of anisotropy reaches up to 0.37 ± 0.04. Robust tests show that such an anisotropy cannot be reproduced by a statistically isotropic data set. We also show that the spatial anisotropy on the acceleration scale is less correlated with the non-uniform distribution of the SPARC data points in the sky. In addition, we confirm that the anisotropy of the acceleration scale does not depend significantly on other physical parameters of the SPARC galaxies. It is interesting to note that the maximum anisotropy direction found in this paper is close with other cosmological preferred directions, particularly the direction of the “Australia dipole” for the fine structure constant.

Giant interfacial perpendicular magnetic anisotropy in Fe/CuIn 1 -xGaxSe2 beyond Fe/MgO

NASA Astrophysics Data System (ADS)

Masuda, Keisuke; Kasai, Shinya; Miura, Yoshio; Hono, Kazuhiro

2017-11-01

We study interfacial magnetocrystalline anisotropies in various Fe/semiconductor heterostructures by means of first-principles calculations. We find that many of those systems show perpendicular magnetic anisotropy (PMA) with a positive value of the interfacial anisotropy constant Ki. In particular, the Fe/CuInSe 2 interface has a large Ki of ˜2.3 mJ /m2 , which is about 1.6 times larger than that of Fe/MgO known as a typical system with relatively large PMA. We also find that the values of Ki in almost all the systems studied in this work follow the well-known Bruno's relation, which indicates that minority-spin states around the Fermi level provide dominant contributions to the interfacial magnetocrystalline anisotropies. Detailed analyses of the local density of states and wave-vector-resolved anisotropy energy clarify that the large Ki in Fe/CuInSe 2 is attributed to the preferable 3 d -orbital configurations around the Fermi level in the minority-spin states of the interfacial Fe atoms. Moreover, we have shown that the locations of interfacial Se atoms are the key for such orbital configurations of the interfacial Fe atoms.

Electronic and magnetic properties of Ni nanoparticles embedded in various organic semiconductor matrices.

PubMed

Bräuer, Björn; Vaynzof, Yana; Zhao, Wei; Kahn, Antoine; Li, Wen; Zahn, Dietrich R T; Fernández, César de Julián; Sangregorio, Claudio; Salvan, Georgeta

2009-04-09

Ni nanoparticles with a size distribution from 2 to 6 nm, embedded in various organic matrices, were fabricated in ultrahigh vacuum. For this purpose metal free and Ni phthalocyanine, fullerene C(60), and pentacene were coevaporated with Ni. When coevaporated, Ni and H(2)Pc react, leading to the formation of NiPc and Ni nanoparticles. The molecular structure of the matrix was found to have negligible effect on the size of the nanoparticles but to influence the magnetic anisotropy of the nanoparticles: Ni nanoparticles formed in the buckyball matrix have a cubic symmetry, while nanoparticles formed in matrices consisting of planar molecules exhibit a uniaxial symmetry. After exposure to atmosphere, photoelectron spectroscopy investigations demonstrate the presence of metallic Ni nanoparticles accompanied by Ni oxide and the existence of a charge transfer from the organic matrix to the particles in all investigated systems. The oxidized Ni nanoparticles exhibit a larger magnetic anisotropy compared to the freshly prepared particles which show superparamagnetic properties above 17 K. Moreover, photoelectron spectroscopy was used to probe the oxidation process of the Ni nanoparticles in different organic matrices. It could thus be shown that a matrix consisting of spherical molecules like C(60) prevent the particles much better from oxidation compared to matrices of flat molecules.

Multi-jump magnetic switching in ion-beam sputtered amorphous Co{sub 20}Fe{sub 60}B{sub 20} thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raju, M.; Chaudhary, Sujeet; Pandya, D. K.

2013-08-07

Unconventional multi-jump magnetization reversal and significant in-plane uniaxial magnetic anisotropy (UMA) in the ion-beam sputtered amorphous Co{sub 20}Fe{sub 60}B{sub 20}(5–75 nm) thin films grown on Si/amorphous SiO{sub 2} are reported. While such multi-jump behavior is observed in CoFeB(10 nm) film when the magnetic field is applied at 10°–20° away from the easy-axis, the same is observed in CoFeB(12.5 nm) film when the magnetic field is 45°–55° away from easy-axis. Unlike the previous reports of multi-jump switching in epitaxial films, their observance in the present case of amorphous CoFeB is remarkable. This multi-jump switching is found to disappear when the filmsmore » are crystallized by annealing at 420 °C. The deposition geometry and the energy of the sputtered species appear to intrinsically induce a kind of bond orientation anisotropy in the films, which leads to the UMA in the as-grown amorphous CoFeB films. Exploitation of such multi-jump switching in amorphous CoFeB thin films could be of technological significance because of their applications in spintronic devices.« less

Direct observation of temperature-driven magnetic symmetry transitions by vectorial resolved MOKE magnetometry

NASA Astrophysics Data System (ADS)

Cuñado, Jose Luis F.; Pedrosa, Javier; Ajejas, Fernando; Perna, Paolo; Miranda, Rodolfo; Camarero, Julio

2017-10-01

Angle- and temperature-dependent vectorial magnetometry measurements are necessary to disentangle the effective magnetic symmetry in magnetic nanostructures. Here we present a detailed study on an Fe(1 0 0) thin film system with competing collinear biaxial (four-fold symmetry) and uniaxial (two-fold) magnetic anisotropies, carried out with our recently developed full angular/broad temperature range/vectorial-resolved magneto-optical Kerr effect magnetometer, named TRISTAN. The data give direct views on the angular and temperature dependence of the magnetization reversal pathways, from which characteristic axes, remanences, critical fields, domain wall types, and effective magnetic symmetry are obtained. In particular, although the remanence shows four-fold angular symmetry for all investigated temperatures (15 K-400 K), the critical fields show strong temperature and angular dependencies and the reversal mechanism changes for specific angles at a given (angle-dependent) critical temperature, showing signatures of an additional collinear two-fold symmetry. This symmetry-breaking is more relevant as temperature increases to room temperature. It originates from the competition between two anisotropy contributions with different symmetry and temperature evolution. The results highlight the importance of combining temperature and angular studies, and the need to look at different magnetic parameters to unravel the underlying magnetic symmetries and temperature evolutions of the symmetry-breaking effects in magnetic nanostructures.

Thermally assisted interlayer magnetic coupling through Ba{sub 0.05}Sr{sub 0.95}TiO{sub 3} barriers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carreira, Santiago J.; Steren, Laura B.; Consejo Nacional de Investigaciones Científicas y Técnicas, Ciudad Autonoma de Buenos Aires C1425FQB

2016-08-08

We report on the interlayer exchange coupling across insulating barriers observed on Ni{sub 80}Fe{sub 20}/Ba{sub 0.05}Sr{sub 0.95}TiO{sub 3}/La{sub 0.66}Sr{sub 0.33}MnO{sub 3} (Py/BST{sub 0.05}/LSMO) trilayers. The coupling mechanism has been analyzed in terms of the barrier thickness, samples' substrate, and temperature. We examined the effect of MgO (MGO) and SrTiO{sub 3} (STO) (001) single-crystalline substrates on the magnetic coupling and also on the magnetic anisotropies of the samples in order to get a deeper understanding of the magnetism of the structures. We measured a weak coupling mediated by spin-dependent tunneling phenomena whose sign and strength depend on barrier thickness and substrate.more » An antiferromagnetic (AF) exchange prevails for most of the samples and smoothly increases with the barrier thicknesses as a consequence of the screening effects of the BST{sub 0.05}. The coupling monotonically increases with temperature in all the samples and this behavior is attributed to thermally assisted mechanisms. The magnetic anisotropy of both magnetic components has a cubic symmetry that in the case of permalloy is added to a small uniaxial component.« less

First observation of a negative elastic constant in intermediate valent TmSe

NASA Astrophysics Data System (ADS)

Boppart, H.; Treindl, A.; Wachter, P.; Roth, S.

1980-08-01

The sound velocities v L, v T 1 and v T 2 have been measured at 15 MHz on Tm 3+0.87Se and Tm 2.8+0.99Se between 300 K and 4.2 K and the elastic constants c ij have been derived. In intermediate valent Tm 2.8+0.99Se c 12 turned out to be negative. This sign is interpreted as being typical for intermediate valent compounds. Also for the first time experimental evidence is given for crystal field effects in Tm 3+0.87Se. Strong elastic nonlinearities are observed in intermediate valent Tm 2.8+0.99Se with uniaxial pressure.

Theory of third-order spectroscopic methods to extract detailed molecular orientational dynamics for planar surfaces and other uniaxial systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishida, Jun; Fayer, Michael D., E-mail: fayer@stanford.edu

Functionalized organic monolayers deposited on planar two-dimensional surfaces are important systems for studying ultrafast orientational motions and structures of interfacial molecules. Several studies have successfully observed the orientational relaxation of functionalized monolayers by fluorescence depolarization experiments and recently by polarization-resolved heterodyne detected vibrational transient grating (HDTG) experiments. In this article we provide a model-independent theory to extract orientational correlation functions unique to interfacial molecules and other uniaxial systems based on polarization-resolved resonant third-order spectroscopies, such as pump-probe spectroscopy, HDTG spectroscopy, and fluorescence depolarization experiment. It will be shown (in the small beam-crossing angle limit) that five measurements are necessary tomore » completely characterize the monolayer's motions: I{sub ∥}(t) and I{sub ⊥}(t) with the incident beams normal to the surface, I{sub ∥}(t) and I{sub ⊥}(t) with a non-zero incident angle, and a time averaged linear dichroism measurement. Once these measurements are performed, two orientational correlation functions corresponding to in-plane and out-of-plane motions are obtained. The procedure is applicable not only for monolayers on flat surfaces, but any samples with uniaxial symmetry such as uniaxial liquid crystals and aligned planar bilayers. The theory is valid regardless of the nature of the actual molecular motions on interface. We then apply the general results to wobbling-in-a-cone model, in which molecular motions are restricted to a limited range of angles. Within the context of the model, the cone angle, the tilt of the cone relative to the surface normal, and the orientational diffusion constant can be determined. The results are extended to describe analysis of experiments where the beams are not crossing in the small angle limit.« less

Experimental and numerical characterisation of the elasto-plastic properties of bovine trabecular bone and a trabecular bone analogue.

PubMed

Kelly, Nicola; McGarry, J Patrick

2012-05-01

The inelastic pressure dependent compressive behaviour of bovine trabecular bone is investigated through experimental and computational analysis. Two loading configurations are implemented, uniaxial and confined compression, providing two distinct loading paths in the von Mises-pressure stress plane. Experimental results reveal distinctive yielding followed by a constant nominal stress plateau for both uniaxial and confined compression. Computational simulation of the experimental tests using the Drucker-Prager and Mohr-Coulomb plasticity models fails to capture the confined compression behaviour of trabecular bone. The high pressure developed during confined compression does not result in plastic deformation using these formulations, and a near elastic response is computed. In contrast, the crushable foam plasticity models provide accurate simulation of the confined compression tests, with distinctive yield and plateau behaviour being predicted. The elliptical yield surfaces of the crushable foam formulations in the von Mises-pressure stress plane accurately characterise the plastic behaviour of trabecular bone. Results reveal that the hydrostatic yield stress is equal to the uniaxial yield stress for trabecular bone, demonstrating the importance of accurate characterisation and simulation of the pressure dependent plasticity. It is also demonstrated in this study that a commercially available trabecular bone analogue material, cellular rigid polyurethane foam, exhibits similar pressure dependent yield behaviour, despite having a lower stiffness and strength than trabecular bone. This study provides a novel insight into the pressure dependent yield behaviour of trabecular bone, demonstrating the inadequacy of uniaxial testing alone. For the first time, crushable foam plasticity formulations are implemented for trabecular bone. The enhanced understanding of the inelastic behaviour of trabecular bone established in this study will allow for more realistic simulation of orthopaedic device implantation and failure. Copyright © 2011 Elsevier Ltd. All rights reserved.

Laser-induced THz magnetization precession for a tetragonal Heusler-like nearly compensated ferrimagnet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mizukami, S., E-mail: mizukami@wpi-aimr.tohoku.ac.jp; Sugihara, A.; Suzuki, K. Z.

2016-01-04

Laser-induced magnetization precessional dynamics was investigated in epitaxial films of Mn{sub 3}Ge, which is a tetragonal Heusler-like nearly compensated ferrimagnet. The ferromagnetic resonance (FMR) mode was observed, the precession frequency for which exceeded 0.5 THz and originated from the large magnetic anisotropy field of approximately 200 kOe for this ferrimagnet. The effective damping constant was approximately 0.03. The corresponding effective Landau-Lifshitz constant is approximately 60 Mrad/s and is comparable with those of the similar Mn-Ga materials. The physical mechanisms for the Gilbert damping and for the laser-induced excitation of the FMR mode were also discussed in terms of the spin-orbit-induced damping and themore » laser-induced ultrafast modulation of the magnetic anisotropy, respectively.« less

Anisotropic k-essence cosmologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chimento, Luis P.; Forte, Monica

We investigate a Bianchi type-I cosmology with k-essence and find the set of models which dissipate the initial anisotropy. There are cosmological models with extended tachyon fields and k-essence having a constant barotropic index. We obtain the conditions leading to a regular bounce of the average geometry and the residual anisotropy on the bounce. For constant potential, we develop purely kinetic k-essence models which are dust dominated in their early stages, dissipate the initial anisotropy, and end in a stable de Sitter accelerated expansion scenario. We show that linear k-field and polynomial kinetic function models evolve asymptotically to Friedmann-Robertson-Walker cosmologies.more » The linear case is compatible with an asymptotic potential interpolating between V{sub l}{proportional_to}{phi}{sup -{gamma}{sub l}}, in the shear dominated regime, and V{sub l}{proportional_to}{phi}{sup -2} at late time. In the polynomial case, the general solution contains cosmological models with an oscillatory average geometry. For linear k-essence, we find the general solution in the Bianchi type-I cosmology when the k field is driven by an inverse square potential. This model shares the same geometry as a quintessence field driven by an exponential potential.« less

FIELD DEPENDENCE OF THE SPIN REORIENTATION TEMPERATURE IN MICRO AND NANOCRYSTALLINE FORMS OF Nd{sub 2}Fe{sub 14}B.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LEWIS,L.H.; HARLAND,C.L.

2002-08-18

Insight into the anisotropy behavior of Nd{sub 2}Fe{sub 14}B may be obtained by measurements of the spin reorientation temperature T{sub S} where the overall magnetocrystalline anisotropy changes to allow the magnetic moment to relax from an easy axis to an easy cone configuration. DC magnetization measurements made at various applied fields on sintered and nanocrystalline forms of Nd{sub 2}Fe{sub 14}B indicate a T{sub S} that remains constant for the sintered sample but is strongly field-dependent for the nanocrystalline forms of the material. Specifically, T{sub S} decreases with decreasing applied fields of strengths 5 T, 1 T and 0.01 T. Amore » simple model that minimizes the total energy of the system leads to the conclusion that the spin reorientation temperature is insensitive to applied field. Therefore it is concluded that the apparent decrease in the system's spin reorientation temperatures with decrease in measuring field can be attributed to the nanoscale structure of the system and a difference in the anisotropy constants compared to their bulk values.« less

Modulation of anisotropy in electrospun tissue-engineering scaffolds: Analysis of fiber alignment by the fast Fourier transform

PubMed Central

Ayres, Chantal; Bowlin, Gary L.; Henderson, Scott C.; Taylor, Leander; Shultz, Jackie; Alexander, John; Telemeco, Todd A.; Simpson, David G.

2010-01-01

We describe the use of the fast Fourier transform (FFT) in the measurement of anisotropy in electrospun scaffolds of gelatin as a function of the starting conditions. In electrospinning, fiber alignment and overall scaffold anisotropy can be manipulated by controlling the motion of the collecting mandrel with respect to the source electrospinning solution. By using FFT to assign relative alignment values to an electrospun matrix it is possible to systematically evaluate how different processing variables impact the structure and material properties of a scaffold. Gelatin was suspended at varying concentrations (80, 100, 130, 150 mg/ml) and electrospun from 2,2,2 trifluoroethanol onto rotating mandrels (200–7000 RPM). At each starting concentration, fiber diameter remained constant over a wide range of mandrel RPM. Scaffold anisotropy developed as a function of fiber diameter and mandrel RPM. The induction of varying degrees of anisotropy imparted distinctive material properties to the electrospun scaffolds. The FFT is a rapid method for evaluating fiber alignment in tissue-engineering materials. PMID:16859744

Strength of anisotropy in a granular material: Linear versus nonlinear contact model

NASA Astrophysics Data System (ADS)

La Ragione, Luigi; Gammariello, Marica; Recchia, Giuseppina

2016-12-01

In this paper, we deal with anisotropy in an idealized granular material made of a collection of frictional, elastic, contacting particles. We present a theoretical analysis for an aggregate of particles isotropically compressed and then sheared, in which two possible contacts laws between particles are considered: a linear contact law, where the contact stiffness is constant; and a nonlinear contact law, where the contact stiffness depends on the overlapping between particles. In the former case the anisotropy observed in the aggregate is associated with particle arrangement. In fact, although the aggregate is initially characterized by an isotropic network of contacts, during the loading, an anisotropic texture develops, which is measured by a fabric tensor. With a nonlinear contact law it is possible to develop anisotropy because contacting stiffnesses are different, depending on the orientation of the contact vectors with respect to the axis of the applied deformation. We find that before the peak load is reached, an aggregate made of particles with a linear contact law develops a much smaller anisotropy compared with that of an aggregate with a nonlinear law.

On the Ising character of the quantum-phase transition in LiHoF4

NASA Astrophysics Data System (ADS)

Skomski, R.

2016-05-01

It is investigated how a transverse magnetic field affects the quantum-mechanical character of LiHoF4, a system generally considered as a textbook example for an Ising-like quantum-phase transition. In small magnetic fields, the low-temperature behavior of the ions is Ising-like, involving the nearly degenerate low-lying Jz = ± 8 doublet. However, as the transverse field increases, there is a substantial admixture of states having |Jz| < 8. Near the quantum-phase-transition field, the system is distinctively non-Ising like, and all Jz eigenstates yield ground-state contributions of comparable magnitude. A classical analog to this mechanism is the micromagnetic single point in magnets with uniaxial anisotropy. Since Ho3+ has J = 8, the ion's behavior is reminiscent of the classical limit (J = ∞), but quantum corrections remain clearly visible.

Distinctive uniaxial magnetic anisotropy and positive magnetoresistance in (110)-oriented Fe3O4 films

NASA Astrophysics Data System (ADS)

Dho, Joonghoe; Kim, Byeong-geon; Ki, Sanghoon

2015-04-01

Magnetite (Fe3O4) films were synthesized on (110)-oriented MgO, MgAl2O4, and SrTiO3 substrates for comparative studies of the substrates' effects on magnetic and magnetoresistance properties of the films. For the [-110] direction, the hysteresis loops of the Fe3O4 film on MgAl2O4 exhibited a good squareness with the largest coercivity of ˜1090 Oe, and the ratio of remanent magnetization to saturation magnetization was ˜0.995. For the [001] direction, positive magnetoresistance in weak magnetic fields was most distinct for the (110) SrTiO3 substrate with the largest lattice mismatch. Positive magnetoresistance in the (110) Fe3O4 films was presumably affected by imperfect atomic arrangements at anti-phase boundaries.

A challenging hysteresis operator for the simulation of Goss-textured magnetic materials

NASA Astrophysics Data System (ADS)

Cardelli, Ermanno; Faba, Antonio; Laudani, Antonino; Pompei, Michele; Quondam Antonio, Simone; Fulginei, Francesco Riganti; Salvini, Alessandro

2017-06-01

A new hysteresis operator for the simulation of Goss-textured ferromagnets is here defined. The operator is derived from the classic Stoner-Wohlfarth model, where the anisotropy energy is assumed to be cubic instead of uniaxial, in order to reproduce the magnetic behavior of Goss textured ferromagnetic materials, such as grain-oriented Fe-Si alloys, Ni-Fe alloys, and Ni-Co alloys. A vector hysteresis model based on a single hysteresis operator is then implemented and used for the prediction of the rotational magnetizations that have been measured in a sample of grain-oriented electrical steel. This is especially promising for FEM based calculations, where the magnetization state in each point must be recalculated at each time step. Finally, the computed loops, as well as the magnetic losses, are compared to the measured data.

Room Temperature Ferromagnetic, Anisotropic, Germanium Rich FeGe(001) Alloys.

PubMed

Lungu, George A; Apostol, Nicoleta G; Stoflea, Laura E; Costescu, Ruxandra M; Popescu, Dana G; Teodorescu, Cristian M

2013-02-21

Ferromagnetic Fe x Ge 1- x with x = 2%-9% are obtained by Fe deposition onto Ge(001) at high temperatures (500 °C). Low energy electron diffraction (LEED) investigation evidenced the preservation of the (1 × 1) surface structure of Ge(001) with Fe deposition. X-ray photoelectron spectroscopy (XPS) at Ge 3d and Fe 2p core levels evidenced strong Fe diffusion into the Ge substrate and formation of Ge-rich compounds, from FeGe₃ to approximately FeGe₂, depending on the amount of Fe deposited. Room temperature magneto-optical Kerr effect (MOKE) evidenced ferromagnetic ordering at room temperature, with about 0.1 Bohr magnetons per Fe atom, and also a clear uniaxial magnetic anisotropy with the in-plane easy magnetization axis. This compound is a good candidate for promising applications in the field of semiconductor spintronics.

Tunable transmittance in anisotropic two-dimensional materials

NASA Astrophysics Data System (ADS)

Nualpijit, Phusit; Sinner, Andreas; Ziegler, Klaus

2018-06-01

A uniaxial strain applied to graphenelike materials moves the Dirac nodes along the boundary of the Brillouin zone. An extreme case is the merging of the Dirac node positions to a single degenerate spectral node, which gives rise to a new topological phase. Then isotropic Dirac nodes are replaced by a node with a linear behavior in one and a parabolic behavior in the other direction. This anisotropy influences substantially the optical properties. We propose a method to determine characteristic spectral and transport properties in black phosphorus layers, which were recently studied by several groups with angle-resolved photoemission spectroscopy, and discuss how the transmittance, the reflectance, and the optical absorption of this material can be tuned. In particular, we demonstrate that the transmittance of linearly polarized incident light varies from nearly 0% to almost 100% in the microwave and far-infrared regime.

Duality of two pairs of double-walled nanotubes consisting of S=1 and S=3/2 spins probed by means of a quantum simulation approach

NASA Astrophysics Data System (ADS)

Liu, Zhaosen; Ian, Hou

2017-01-01

Using a quantum simulation approach, we investigate in the present work the spontaneous magnetic properties of two pairs of double-walled cylindrical nanotubes consisting of different spins. Our simulated magnetic and thermodynamic properties for each pair of them are precisely identical, exhibiting a fascinating property of the nature world and demonstrating the correctness of our simulation approach. The second pair of nanotubes are frustrated, two magnetic phases of distinct spin configurations appear in the low temperature region, but only the inner layer consisting of small spins is frustrated evidently, its magnetization is considerably suppressed in the high temperature phase. Moreover, the nanosystems exhibit typical Ising-like behavior due to the uniaxial anisotropy along the z-direction, and evident finite-size effects as well.

Coupled and decoupled on-chip solenoid inductors with nanogranular magnetic cores

NASA Astrophysics Data System (ADS)

He, Yuhan; Wang, Luo; Wang, Yicheng; Zhang, Huaiwu; Peng, Dongliang; Bai, Feiming

2017-12-01

On-chip integrated solenoid inductors with multilayered nanogranular magnetic cores have been designed and fabricated on silicon wafers. Both decoupled and coupled inductors with multilayered magnetic cores were studied. For the decoupled inductor, an inductance of 14.2 nH or an equivalent inductance area density greater than 100 nH/mm2 was obtained, which is about 14 times of that of the air-core inductor, and the quality factor is 7.5 at 130 MHz. For the coupled inductor, an even higher peak quality factor of 17 was achieved at 300 MHz, however, the inductance area density decreased to 34 nH/mm2. The reason of the enhanced peak quality factor was attributed to less spike domains on the edge of the closure-loop shaped magnetic core, and therefore higher permeability and more uniform uniaxial anisotropy.

Effects of anisotropies in turbulent magnetic diffusion in mean-field solar dynamo models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pipin, V. V.; Kosovichev, A. G.

2014-04-10

We study how anisotropies of turbulent diffusion affect the evolution of large-scale magnetic fields and the dynamo process on the Sun. The effect of anisotropy is calculated in a mean-field magnetohydrodynamics framework assuming that triple correlations provide relaxation to the turbulent electromotive force (so-called the 'minimal τ-approximation'). We examine two types of mean-field dynamo models: the well-known benchmark flux-transport model and a distributed-dynamo model with a subsurface rotational shear layer. For both models, we investigate effects of the double- and triple-cell meridional circulation, recently suggested by helioseismology and numerical simulations. To characterize the anisotropy effects, we introduce a parameter ofmore » anisotropy as a ratio of the radial and horizontal intensities of turbulent mixing. It is found that the anisotropy affects the distribution of magnetic fields inside the convection zone. The concentration of the magnetic flux near the bottom and top boundaries of the convection zone is greater when the anisotropy is stronger. It is shown that the critical dynamo number and the dynamo period approach to constant values for large values of the anisotropy parameter. The anisotropy reduces the overlap of toroidal magnetic fields generated in subsequent dynamo cycles, in the time-latitude 'butterfly' diagram. If we assume that sunspots are formed in the vicinity of the subsurface shear layer, then the distributed dynamo model with the anisotropic diffusivity satisfies the observational constraints from helioseismology and is consistent with the value of effective turbulent diffusion estimated from the dynamics of surface magnetic fields.« less

Strain localization parameters of AlCu4MgSi processed by high-energy electron beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lunev, A. G., E-mail: agl@ispms.ru; Nadezhkin, M. V., E-mail: mvn@ispms.ru; National Research Tomsk Polytechnic University, Tomsk, 634050

2015-10-27

The influence of the electron beam surface treatment of AlCu4MgSi on the strain localization parameters and on the critical strain value of the Portevin–Le Chatelier effect has been considered. The strain localization parameters were measured using speckle imaging of the specimens subjected to the constant strain rate uniaxial tension at a room temperature. Impact of the surface treatment on the Portevin–Le Chatelier effect has been investigated.

Dislocation based controlling of kinematic hardening contribution to simulate primary and secondary stages of uniaxial ratcheting

NASA Astrophysics Data System (ADS)

Bhattacharjee, S.; Dhar, S.; Acharyya, S. K.

2017-07-01

The primary and secondary stages of the uniaxial ratcheting curve for the C-Mn steel SA333 have been investigated. Stress controlled uniaxial ratcheting experiments were conducted with different mean stresses and stress amplitudes to obtain curves showing the evolution of ratcheting strain with number of cycles. In stage-I of the ratcheting curve, a large accumulation of ratcheting strain occurs, but at a decreasing rate. In contrast, in stage-II a smaller accumulation of ratcheting strain is found and the ratcheting rate becomes almost constant. Transmission electron microscope observations reveal that no specific dislocation structures are developed during the early stages of ratcheting. Rather, compared with the case of low cycle fatigue, it is observed that sub-cell formation is delayed in the case of ratcheting. The increase in dislocation density as a result of the ratcheting strain is obtained using the Orowan equation. The ratcheting strain is obtained from the shift of the plastic strain memory surface. The dislocation rearrangement is incorporated in a functional form of dislocation density, which is used to calibrate the parameters of a kinematic hardening law. The observations are formulated in a material model, plugged into the ABAQUS finite element (FE) platform as a user material subroutine. Finally the FE-simulated ratcheting curves are compared with the experimental curves.

Evolution of structural and magnetic properties of amorphous CoFeB film with thermal annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gupta, Ranjeeta; Gupta, Ajay; Gupta, Mukul

2013-08-14

Evolution of structural and magnetic properties of amorphous Co{sub 68}Fe{sub 14}B{sub 18} thin film with thermal annealing has been studied. Initially, the film exhibits a structural relaxation as evidenced by annihilation of excess free volume and an increase in topological short range order. Annealing at 473 K results in precipitation of primary phase followed by formation of boride phase at a still higher temperature of 598 K. Iron preferentially precipitates out in the primary phase, resulting in the formation of bcc Co{sub 58}Fe{sub 41}. This suggests an affinity of Co towards B. Such affinity between Co and B is evidencedmore » even in the as-deposited film, using hard x-ray photoelectron spectroscopy (HAXPES) measurements. As-deposited film exhibits an in-plane uniaxial magnetic anisotropy which disappears at a temperature well beyond crystallization temperature, suggesting that the origin of anisotropy is mainly a chemical short range order in the system. Variation in the coercivity with thermal annealing can be understood in terms of random anisotropy model. Precise measurement of Fe self-diffusion using neutron reflectivity shows that diffusion length associated with annihilation of excess free volume in the film is about 0.5 nm. This agrees with the length scale of structural fluctuations in amorphous alloys. Secondary ion mass spectrometry measurements show that thermal annealing results in depletion of B in the region of the interface with the substrate, with associated faster Fe diffusion in this region. This faster diffusion of Fe may be a possible cause of preferential crystallization of the film in the interfacial region as seen in some earlier studies.« less

Change and anisotropy of elastic modulus in sheet metals due to plastic deformation

NASA Astrophysics Data System (ADS)

Ishitsuka, Yuki; Arikawa, Shuichi; Yoneyama, Satoru

2015-03-01

In this study, the effect of the plastic deformation on the microscopic structure and the anisotropy of the elastic modulus in the cold-rolled steel sheet (SPCC) is investigated. Various uniaxial plastic strains (0%, 2.5%, 5%, 7.5%, and 10%) are applied to the annealed SPCC plates, then, the specimens for the tensile tests are cut out from them. The elastic moduli in the longitudinal direction and the transverse direction to the direction that are pre-strained are measured by the tensile tests. Cyclic tests are performed to investigate the effects of the internal friction caused by the movable dislocations in the elastic deformation. Also, the movable dislocations are quantified by the boundary tracking for TEM micrographs. In addition, the behaviors of the change of the elastic modulus in the solutionized and thermal aged aluminum alloy (A5052) are measured to investigate the effect on the movable dislocations with the amount of the depositions. As a result in SPCC, the elastic moduli of the 0° and 90° directions decrease more than 10% as 10% prestrain applied. On the other hand, the elastic modulus shows the recovery behavior after the strain aging and the annealing. The movable dislocation and the internal friction show a tendency to increase as the plastic strain increases. The marked anisotropy is not observed in the elastic modulus and the internal friction. The elastic modulus in A5052 with many and few depositions decreases similarly by the plastic deformation. From the above, the movable dislocations affect the elastic modulus strongly without depending on the deposition amount. Moreover, the elastic modulus recovers after the plastic deformation by reducing the effects of them with the strain aging and the heat treatment.

Effects of B and Mo on the magnetic properties of NdFeTi-nitrides with ThMn[sub 12]-type structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Y.B.; Kim, H.T.; Kim, C.S.

1993-11-01

The alloys having nearly single phase of ThMn[sub 12]-type structure (1-12 phase) have been successfully synthesized in NdFe[sub 10.7]Ti[sub 1.3[minus]y]M[sub y] (M = B/Mo) alloy systems by substituting B or Mo up to 23% of Ti (y=0.3). After nitrification, the unit cell volume of 1--12 phase has increased by about 2--3% and a-Fe phase of 5--15 wt.% has been formed depending on the substitutional elements. The nitrides, NdFe[sub 10.7]TiB[sub 0.3]N[sub x] and Nd Fe[sub 10.7]TiMo[sub 0.3]N[sub x], were confirmed to have uniaxial anisotropy by X-ray diffractometry. The results of magnetic measurements for the nitrides have shown that B is verymore » effective for the increase of both Curie temperature and magnetization. On the other band, Mo is effective for the increase of anisotropy field, but it decreases the magnetization. The Curie temperature and magnetization of NdFe[sub 10.7]TiB[sub 0.3]N[sub x] are 560 C and 148 Am[sup 2] /kg, respectively, by about 20% and 15% higher than those of NdFe[sub 10.7]Ti[sub 1.3]N[sub x]. The anisotropy field of NdFe[sub 10.7]TiMo[sub 0.3]N[sub x] is about 7960 kA/m (100 kOe) which is about 25% higher than that of NdFe[sub 10.7]Ti[sub 1.3]N[sub x].« less

Uniaxial experimental study of the acoustic emission and deformation behavior of composite rock based on 3D digital image correlation (DIC)

NASA Astrophysics Data System (ADS)

Cheng, Jian-Long; Yang, Sheng-Qi; Chen, Kui; Ma, Dan; Li, Feng-Yuan; Wang, Li-Ming

2017-12-01

In this paper, uniaxial compression tests were carried out on a series of composite rock specimens with different dip angles, which were made from two types of rock-like material with different strength. The acoustic emission technique was used to monitor the acoustic signal characteristics of composite rock specimens during the entire loading process. At the same time, an optical non-contact 3D digital image correlation technique was used to study the evolution of axial strain field and the maximal strain field before and after the peak strength at different stress levels during the loading process. The effect of bedding plane inclination on the deformation and strength during uniaxial loading was analyzed. The methods of solving the elastic constants of hard and weak rock were described. The damage evolution process, deformation and failure mechanism, and failure mode during uniaxial loading were fully determined. The experimental results show that the θ = 0{°}-45{°} specimens had obvious plastic deformation during loading, and the brittleness of the θ = 60{°}-90{°} specimens gradually increased during the loading process. When the anisotropic angle θ increased from 0{°} to 90{°}, the peak strength, peak strain, and apparent elastic modulus all decreased initially and then increased. The failure mode of the composite rock specimen during uniaxial loading can be divided into three categories: tensile fracture across the discontinuities (θ = 0{°}-30{°}), sliding failure along the discontinuities (θ = 45{°}-75{°}), and tensile-split along the discontinuities (θ = 90{°}). The axial strain of the weak and hard rock layers in the composite rock specimen during the loading process was significantly different from that of the θ = 0{°}-45{°} specimens and was almost the same as that of the θ = 60{°}-90{°} specimens. As for the strain localization highlighted in the maximum principal strain field, the θ = 0{°}-30{°} specimens appeared in the rock matrix approximately parallel to the loading direction, while in the θ = 45{°}-90{°} specimens it appeared at the hard and weak rock layer interface.

Molecular Based Temperature and Strain Rate Dependent Yield Criterion for Anisotropic Elastomeric Thin Films

NASA Technical Reports Server (NTRS)

Bosi, F.; Pellegrino, S.

2017-01-01

A molecular formulation of the onset of plasticity is proposed to assess temperature and strain rate effects in anisotropic semi-crystalline rubbery films. The presented plane stress criterion is based on the strain rate-temperature superposition principle and the cooperative theory of yielding, where some parameters are assumed to be material constants, while others are considered to depend on specific modes of deformation. An orthotropic yield function is developed for a linear low density polyethylene thin film. Uniaxial and biaxial inflation experiments were carried out to determine the yield stress of the membrane via a strain recovery method. It is shown that the 3% offset method predicts the uniaxial elastoplastic transition with good accuracy. Both the tensile yield points along the two principal directions of the film and the biaxial yield stresses are found to obey the superposition principle. The proposed yield criterion is compared against experimental measurements, showing excellent agreement over a wide range of deformation rates and temperatures.

Bistatic scattering from a three-dimensional object above a two-dimensional randomly rough surface modeled with the parallel FDTD approach.

PubMed

Guo, L-X; Li, J; Zeng, H

2009-11-01

We present an investigation of the electromagnetic scattering from a three-dimensional (3-D) object above a two-dimensional (2-D) randomly rough surface. A Message Passing Interface-based parallel finite-difference time-domain (FDTD) approach is used, and the uniaxial perfectly matched layer (UPML) medium is adopted for truncation of the FDTD lattices, in which the finite-difference equations can be used for the total computation domain by properly choosing the uniaxial parameters. This makes the parallel FDTD algorithm easier to implement. The parallel performance with different number of processors is illustrated for one rough surface realization and shows that the computation time of our parallel FDTD algorithm is dramatically reduced relative to a single-processor implementation. Finally, the composite scattering coefficients versus scattered and azimuthal angle are presented and analyzed for different conditions, including the surface roughness, the dielectric constants, the polarization, and the size of the 3-D object.

Constitutive Modelling of Resins in the Compliance Domain

NASA Astrophysics Data System (ADS)

Klasztorny, M.

2004-07-01

A rheological HWKK/H model for resins is developed taking into consideration the up-to-date analyses of experimental results. Constitutive compliance equations of linear are formulated for this model in the shear/bulk form, which describes, among other things, the first-rank reversible isothermal creep. The shear (distorsional) deformations are simulated with three independent stress history functions of fractional and normal exponential types. The volume deformations are simulated as perfectly elastic. The model is described by two elastic and six viscoelastic constants, namely three long-term creep coefficients and three retardation times. The constitutive compliance equations of viscoealsticity for resins are also formulated in the coupled form. Formulae for converting the constants of shear/bulk (uncoupled) viscoelasticity into the constants of coupled viscoelasticity are given too. An algorithm for identifying the material constants, based on the creep of uniaxially tensioned bar samples, is formulated in a way that gives unique results. The material constants are fiund for Epidian 53 epoxy and Polimal 109 polyester resins. The creep processes, simulated based on the experimental data, are presented graphically for both the resins examined.

Constraints on universe models with cosmological constant from cosmic microwave background anisotropy

NASA Astrophysics Data System (ADS)

Sugiyama, Naoshi; Gouda, Naoteru; Sasaki, Misao

1990-12-01

Thorough numerical calculations of the fluctuations in the cosmic microwave background radiation using the gage-invariant formalism are carried out for various cosmological models with the cosmological constant. It is shown that a spatially flat cold dark matter-dominated universe of Omega(0) = 0.1 to about 0.4 and H(0) = 50 to about 100 km/s per Mpc with adiabatic perturbations has the possibility of giving the final answer to cosmological puzzles. It is also found that the introduction of the cosmological constant may revive pure baryonic universe models.

Flat-topped beam transmittance in anisotropic non-Kolmogorov turbulent marine atmosphere

NASA Astrophysics Data System (ADS)

Ata, Yalçın; Baykal, Yahya

2017-10-01

Turbulence affects optical propagation, and, as a result, the intensity is attenuated along the path of propagation. The attenuation becomes significant when the turbulence becomes stronger. Transmittance is a measure indicating how much power is collected at the receiver after the optical wave propagates in the turbulent medium. The on-axis transmittance is formulated when a flat-topped optical beam propagates in a marine atmosphere experiencing anisotropic non-Kolmogorov turbulence. Variations in the transmittance are evaluated versus the beam source size, beam number, link distance, power law exponent, anisotropy factor, and structure constant. It is found that larger beam source sizes and beam numbers yield higher transmittance values; however, as the link distance, power law exponent, anisotropy factor, or structure constant increase, transmittance values are lowered. Our results will help in the performance evaluations of optical wireless communication and optical imaging systems operating in a marine atmosphere.

Orbital measurements of the Earth's radiation budget during the first decade of the space program

NASA Technical Reports Server (NTRS)

Bandeen, W. R.

1982-01-01

The instrumentation and data analysis methods applied to data from the Explorer 7, TIROS 2, 3, 4, and 7, and Nimbus 2 and 3 experimental satellites are summarized. Problems encountered in analyzing these data included: determining the value of the solar constant, inaccuracies introduced by degradation of the sensors in orbit, the need to infer the total reflected and emitted radiation from filtered measurements, the development of corrections for anisotropy in order to determine the outgoing flux densities at the moment of measurement, and the development of corrections to account for diurnal variability. The corrections for long- and shortwave anisotropy and historical determinations of the solar constant and albedo are treated in detail. These early measurements indicated that the planetary albedo was lower, the emitted radiation higher, and the equator-to-pole gradient of net radiation greater than previously supposed.

Ultralow temperature terahertz magnetic thermodynamics of perovskite-like SmFeO3 ceramic

PubMed Central

Fu, Xiaojian; Zeng, Xinxi; Wang, Dongyang; Chi Zhang, Hao; Han, Jiaguang; Jun Cui, Tie

2015-01-01

The terahertz magnetic properties of perovskite-like SmFeO3 ceramic are investigated over a broad temperature range, especially at ultralow temperatures, using terahertz time-domain spectroscopy. It is shown that both resonant frequencies of quasi-ferromagnetic and quasi-antiferromagnetic modes have blue shifts with the decreasing temperature due to the enhancement of effective magnetic field. The temperature-dependent magnetic anisotropy constants are further estimated using the resonant frequencies, under the approximation of omitting the contribution of Sm3+ magnetic moments to the effective field. Specially, the effective anisotropy constants in the ca and cb planes at 3 K are 6.63 × 105 erg/g and 8.48 × 105 erg/g, respectively. This thoroughly reveals the terahertz magnetic thermodynamics of orthoferrites and will be beneficial to the application in terahertz magnetism. PMID:26424488

Magnetization dynamics in dilute Pd1-xFex thin films and patterned microstructures considered for superconducting electronics

NASA Astrophysics Data System (ADS)

Golovchanskiy, I. A.; Bolginov, V. V.; Abramov, N. N.; Stolyarov, V. S.; Ben Hamida, A.; Chichkov, V. I.; Roditchev, D.; Ryazanov, V. V.

2016-10-01

Motivated by recent burst of applications of ferromagnetic layers in superconducting digital and quantum elements, we study the magnetism of thin films and patterned microstructures of Pd0.99Fe0.01. In this diluted ferromagnetic system, a high-sensitivity ferromagnetic resonance (FMR) experiment reveals spectroscopic signatures of re-magnetization and enables the estimation of the saturation magnetization, the anisotropy field, and the Gilbert damping constant. The detailed analysis of FMR spectra links the observed unexpectedly high reduced anisotropy field (0.06-0.14) with the internal anisotropy, points towards a cluster nature of the ferromagnetism, and allows estimating characteristic time scale for magnetization dynamics in Pd-Fe based cryogenic memory elements to ( 3 - 5 ) × 10 - 9 s.

Analysis of flow near a dug well in an unconfined aquifer

NASA Astrophysics Data System (ADS)

Sridharan, K.; Sathyanarayana, D.; Reddy, A. Siva

1990-11-01

A numerical analysis of flow to a dug well in an unconfined aquifer is made, taking into account well storage, elastic storage release, gravity drainage, anisotropy, partial penetration, vertical flow and seepage surface at the well face, and treating the water table in the aquifer and water level in the well as unknown boundaries. The pumped discharge is maintained constant. The solution is obtained by a two-level iterative scheme. The effects of governing parameters on the drawdown, development of seepage surface and contribution from aquifer flow to the total discharge are discussed. The degree of anisotropy and partial penetration are found to be the parameters which affect the flow characteristics most significantly. The effect of anisotropy on the development of seepage surface is very pronounced.

Limits on cold dark matter cosmologies from new anisotropy bounds on the cosmic microwave background

NASA Technical Reports Server (NTRS)

Vittorio, Nicola; Meinhold, Peter; Lubin, Philip; Muciaccia, Pio Francesco; Silk, Joseph

1991-01-01

A self-consistent method is presented for comparing theoretical predictions of and observational upper limits on CMB anisotropy. New bounds on CDM cosmologies set by the UCSB South Pole experiment on the 1 deg angular scale are presented. An upper limit of 4.0 x 10 to the -5th is placed on the rms differential temperature anisotropy to a 95 percent confidence level and a power of the test beta = 55 percent. A lower limit of about 0.6/b is placed on the density parameter of cold dark matter universes with greater than about 3 percent baryon abundance and a Hubble constant of 50 km/s/Mpc, where b is the bias factor, equal to unity only if light traces mass.

Spatial distribution characteristics of magnetization in exchange-coupled bilayers with mutually orthogonal anisotropies

NASA Astrophysics Data System (ADS)

Xiang, Y.; Chen, C. W.

2017-05-01

The magnetization distribution of a bilayer exchange spring system with mutually orthogonal anisotropies was investigated by micromagnetic simulation. Results showed that the spatial change rate of the magnetization direction could be engineered by varying the material parameters, layer thicknesses, and magnetic field. When no magnetic field is applied, this angular change rate is determined by three parameter ratios: a ratio of the exchange energy and anisotropy constants of both layers and two thickness ratios of both layers. If these three ratios are kept invariant, the ratio of the angular change of the soft layer over the hard layer will remain the same. When a magnetic field is applied, two more ratios concerning the magnetic field should be added to determine the spatial angular change of the magnetization direction.

Exchange bias and perpendicular anisotropy study of ultrathin Pt-Co-Pt-IrMn multilayers sputtered on float glass

NASA Astrophysics Data System (ADS)

Laval, M.; Lüders, U.; Bobo, J. F.

2007-09-01

We have prepared ultrathin Pt-Co-Pt-IrMn polycrystalline multilayers on float-glass substrates by DC magnetron sputtering. We have determined the optimal set of thickness for both Pt layers, the Co layer and the IrMn biasing layer so that these samples exhibit at the same time out-of-plane magnetic anisotropy and exchange bias. Kerr microscopy domain structure imaging evidences an increase of nucleation rate accompanied with inhomogeneous magnetic behavior in the case of exchange-biased films compared to Pt-Co-Pt trilayers. Polar hysteresis loops are measured in obliquely applied magnetic field conditions, allowing us to determine both perpendicular anisotropy effective constant Keff and exchange-bias coupling JE, which are significantly different from the ones determined by standard switching field measurements.

Anomalous anisotropies of fission fragments in near- and sub-barrier fusion-fussion reactions

NASA Astrophysics Data System (ADS)

Huanqiao, Zhang; Zuhua, Liu; Jincheng, Xu; Jun, Lu; Ming, Ruan; Kan, Xu

1992-03-01

Fission cross sections and angular distributions have been measured for the reactions of 16O + 232Th and238U, and19F + 208Pb and232Th at near- and sub-barrier energies. The fission excitation functions are rather well reproduced on the basis of Wong model or coupled channels theory. However, the models which reproduce the sub-barrier fusion cross sections fail to account for the experimental anisotropies of fission fragments. It is found that the observed anisotropies are much larger than expected. For the first time it has been observed that the anisotropies as a function of the center-of-mass energy show a peak centered near 4.5 MeV below the fusion barrier for several reaction systems. The present approaches fail to explain these anomalies. For 19F + 208Pb systems, our results confirm the prediction of an approximately constant value for the mean square spin of the compound nucleus produced in far sub-barrier fusion reaction.

GaAs micromachining in the 1 H2SO4:1 H2O2:8 H2O system. From anisotropy to simulation

NASA Astrophysics Data System (ADS)

Tellier, C. R.

2011-02-01

The bulk micromachining on (010), (110) and (111)A GaAs substrates in the 1 H2SO4:1 H2O2:8 H2O system is investigated. Focus is placed on anisotropy of 3D etching shapes with a special emphasis on convex and concave undercuts which are of prime importance in the wet micromachining of mechanical structures. Etched structures exhibit curved contours and more and less rounded sidewalls showing that the anisotropy is of type 2. This anisotropy can be conveniently described by a kinematic and tensorial model. Hence, a database composed of dissolution constants is further determined from experiments. A self-elaborated simulator which works with the proposed database is used to derive theoretical 3D shapes. Simulated shapes agree well with observed shapes of microstructures. The successful simulations open up two important applications for MEMS: CAD of mask patterns and meshing of simulated shapes for FEM simulation tools.

Unitaxial constant velocity microactuator

DOEpatents

McIntyre, Timothy J.

1994-01-01

A uniaxial drive system or microactuator capable of operating in an ultra-high vacuum environment. The mechanism includes a flexible coupling having a bore therethrough, and two clamp/pusher assemblies mounted in axial ends of the coupling. The clamp/pusher assemblies are energized by voltage-operated piezoelectrics therewithin to operatively engage the shaft and coupling causing the shaft to move along its rotational axis through the bore. The microactuator is capable of repeatably positioning to sub-manometer accuracy while affording a scan range in excess of 5 centimeters. Moreover, the microactuator generates smooth, constant velocity motion profiles while producing a drive thrust of greater than 10 pounds. The system is remotely controlled and piezoelectrically driven, hence minimal thermal loading, vibrational excitation, or outgassing is introduced to the operating environment.

Effects of post-deposition magnetic field annealing on magnetic properties of NiO/Co90Fe10 bilayers

NASA Astrophysics Data System (ADS)

Zheng, Chao; Su, Shan; Chiu, Chun-Cheng; Skoropata, Elizabeth; Desautels, Ryan D.; van Lierop, Johan; Lin, Ko-Wei; Pong, Philip W. T.

2018-01-01

The ferromagnetic (FM)/antiferromagnetic (AF) bilayer structures have drawn intensive attention because of their wide applications in modern spintronic devices. While abundant published works have been reported on the interface effects of the FM/AF bilayers caused by the magnetic field annealing (MFA) process, the volume effects caused by the MFA treatment have been rarely considered. In this work, the microstructural and magnetic properties of the NiO/CoFe bilayers with various CoFe thicknesses were investigated under different annealing temperatures. At high annealing temperature, the interlayer mixing and exchange coupling between NiO and CoFe layers were promoted and consequently the interface effects were facilitated. The interfacial oxides acted as pinning centers and randomly pinned the FM domains, leading to an increase of coercivity and a considerable degradation of uniaxial anisotropy. The increase of coercivity was also contributed by the enhancement of the interfacial exchange coupling between the NiO and CoFe layers after MFA. As the CoFe thickness increased, the volume effects tended to dominate over the interface effects, resulting in the preservation the uniaxially anisotropic features of CoFe. These results indicate that both the coercivity and anisotropic features of the NiO/CoFe bilayers can be directly affected by the MFA process, opening up the possibility of modifying the magnetism in the NiO/CoFe bilayers and offering an effective way to improve the performance of modern spintronic devices.

Magnetization reversal of in-plane uniaxial Co films and its dependence on epitaxial alignment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Idigoras, O., E-mail: o.idigoras@nanogune.eu; Suszka, A. K.; Berger, A.

2014-02-28

This work studies the influence of crystallographic alignment onto magnetization reversal in partially epitaxial Co films. A reproducible growth sequence was devised that allows for the continuous tuning of grain orientation disorder in Co films with uniaxial in-plane anisotropy by the controlled partial suppression of epitaxy. While all stable or meta-stable magnetization states occurring during a magnetic field cycle exhibit a uniform magnetization for fully epitaxial samples, non-uniform states appear for samples with sufficiently high grain orientation disorder. Simultaneously with the occurrence of stable domain states during the magnetization reversal, we observe a qualitative change of the applied field anglemore » dependence of the coercive field. Upon increasing the grain orientation disorder, we observe a disappearance of transient domain wall propagation as the dominating reversal process, which is characterized by an increase of the coercive field for applied field angles away from the easy axis for well-ordered epitaxial samples. Upon reaching a certain disorder threshold level, we also find an anomalous magnetization reversal, which is characterized by a non-monotonic behavior of the remanent magnetization and coercive field as a function of the applied field angle in the vicinity of the nominal hard axis. This anomaly is a collective reversal mode that is caused by disorder-induced frustration and it can be qualitatively and even quantitatively explained by means of a two Stoner-Wohlfarth particle model. Its predictions are furthermore corroborated by Kerr microscopy and by Brillouin light scattering measurements.« less

Temperature-dependent elasticity of Pb [(Mg0.33Nb0.67 ) 1 -xT ix ] O3

NASA Astrophysics Data System (ADS)

Tennakoon, Sumudu; Gladden, Joseph; Mookherjee, Mainak; Besara, Tiglet; Siegrist, Theo

2017-10-01

Relaxor ferroelectric materials, such as Pb [(Mg0.33Nb0.67 ) 1 -xT ix ] O3 (PMN-PT) with generic stoichiometry, undergo a ferroelectric-to-paraelectric phase transition as a function of temperature. The exact transition characterized by Curie temperature (Tc) varies as a function of chemistry (x ), i.e., the concentration of Ti. In this study, we investigated the structural phase transition by exploring the temperature dependence of the single-crystal elastic properties of Pb [(Mg0.33Nb0.67 ) 0.7T i0.3 ] O3 , i.e., x ≈0.3 . We used resonant ultrasound spectroscopy to determine the elasticity at elevated temperatures, from which Tc=398 ±5 K for PMN-PT (x ≈0.3 ) was determined. We report the full elastic constant tensor (Ci j={ C11,C12,C44 }), acoustic attenuation (Q-1), longitudinal (VP) and shear (VS) sound velocities, and elastic anisotropy of PMN-PT as a function of temperature for 400 Tc the material first stiffens and reaches maxima in the vicinity of the Burns temperature (Tb˜673 K ), followed by a more typical gradual softening of the elastic constants. Similar temperature-dependent anomalies are also observed with anisotropy and Q-1, with minima in the vicinity of Tb. We used the temperature dependence of Ci j, Q-1, VP,VS , and anisotropy to infer the evolution of polar nanoregions as the material evolved from T >Tc .

Role of fluctuations in random compressible systems at marginal dimensionality

NASA Astrophysics Data System (ADS)

Meissner, G.; Sasvári, L.; Tadić, B.

1986-07-01

In a unified treatment we have studied the role of fluctuations in uniaxial random systems at marginal dimensionality d*=4 with the n=1 component order parameter being coupled to elastic degrees of freedom. Depending on the ratio of the nonuniversal parameters of quenched disorder Δ0 and of elastic fluctuations v~0, a first- or second-order phase transition is found to occur, separated by a tricritical point. A complete account of critical properties and of macroscopic as well as of microscopic elastic stability is given for temperatures T>Tc. Universal singularities of thermodynamic functions are determined for t=(T-Tc)/Tc-->0 including the tricritical point: for v~0/Δ0>-2, they are the same as in a rigid random system; for v~0/Δ0=-2, they are different due to lattice compressibility being related, however, to the former by Fisher renormalization. Fluctuation corrections in one-loop approximation have been evaluated in a nonuniversal critical temperature range, tx<

The effective elastic properties of human trabecular bone may be approximated using micro-finite element analyses of embedded volume elements.

PubMed

Daszkiewicz, Karol; Maquer, Ghislain; Zysset, Philippe K

2017-06-01

Boundary conditions (BCs) and sample size affect the measured elastic properties of cancellous bone. Samples too small to be representative appear stiffer under kinematic uniform BCs (KUBCs) than under periodicity-compatible mixed uniform BCs (PMUBCs). To avoid those effects, we propose to determine the effective properties of trabecular bone using an embedded configuration. Cubic samples of various sizes (2.63, 5.29, 7.96, 10.58 and 15.87 mm) were cropped from [Formula: see text] scans of femoral heads and vertebral bodies. They were converted into [Formula: see text] models and their stiffness tensor was established via six uniaxial and shear load cases. PMUBCs- and KUBCs-based tensors were determined for each sample. "In situ" stiffness tensors were also evaluated for the embedded configuration, i.e. when the loads were transmitted to the samples via a layer of trabecular bone. The Zysset-Curnier model accounting for bone volume fraction and fabric anisotropy was fitted to those stiffness tensors, and model parameters [Formula: see text] (Poisson's ratio) [Formula: see text] and [Formula: see text] (elastic and shear moduli) were compared between sizes. BCs and sample size had little impact on [Formula: see text]. However, KUBCs- and PMUBCs-based [Formula: see text] and [Formula: see text], respectively, decreased and increased with growing size, though convergence was not reached even for our largest samples. Both BCs produced upper and lower bounds for the in situ values that were almost constant across samples dimensions, thus appearing as an approximation of the effective properties. PMUBCs seem also appropriate for mimicking the trabecular core, but they still underestimate its elastic properties (especially in shear) even for nearly orthotropic samples.

Anisotropic inflation with a non-minimally coupled electromagnetic field to gravity

NASA Astrophysics Data System (ADS)

Adak, Muzaffer; Akarsu, Özgür; Dereli, Tekin; Sert, Özcan

2017-11-01

We consider the non-minimal model of gravity in Y(R) F2-form. We investigate a particular case of the model, for which the higher order derivatives are eliminated but the scalar curvature R is kept to be dynamical via the constraint YRFmnFmn =-2/κ2. The effective fluid obtained can be represented by interacting electromagnetic field and vacuum depending on Y(R), namely, the energy density of the vacuum tracks R while energy density of the conventional electromagnetic field is dynamically scaled with the factor Y(R)/2. We give exact solutions for anisotropic inflation by assuming the volume scale factor of the Universe exhibits a power-law expansion. The directional scale factors do not necessarily exhibit power-law expansion, which would give rise to a constant expansion anisotropy, but expand non-trivially and give rise to a non-monotonically evolving expansion anisotropy that eventually converges to a non-zero constant. Relying on this fact, we discuss the anisotropic e-fold during the inflation by considering observed scale invariance in CMB and demanding the Universe to undergo the same amount of e-folds in all directions. We calculate the residual expansion anisotropy at the end of inflation, though as a result of non-monotonic behaviour of expansion anisotropy all the axes of the Universe undergo the same of amount of e-folds by the end of inflation. We also discuss the generation of the modified electromagnetic field during the first few e-folds of the inflation and its persistence against to the vacuum till end of inflation.

Seismic anisotropy from crust to core: a mineral and rock physics perspective

NASA Astrophysics Data System (ADS)

Mainprice, David

2014-05-01

Since the early work of Hess and co-works for mantle in the 1960s and Poupinet et al. in 1980s for the inner core, we know that seismic anisotropy is a global phenomenon. Progress in seismology has led to a much more complete image of the Earth's interior in terms of heterogeneity and anisotropy. The interpretation of the seismic anisotropy requires a multidisciplinary effort to unravel the geodynamic scenario recorded in today's seismological snapshot. Progress in mineral physics on the experimental measurement of elastic properties at extreme conditions are now completed by ab initio atomic modelling for the full range of temperatures and pressures of the Earth's interior. The new data on the elastic constants of wider range minerals enables more realistic petrology for seismic anisotropy models. Experimental plastic deformation of polycrystalline samples at deep Earth conditions allows the direct study of crystal preferred orientation (CPO) and these studies are completed by ab initio atomic modelling of dislocations and other defects that control plasticity. Finally, polycrystalline plasticity codes allow the simulation of CPO reported by experimentalists and the modelling of more complex strain paths required for geodynamic models. The CPO of crustal and mantle rocks from the Earth's surface or recovered as xenoliths, provides a geological verification of the CPOs present in the Earth. The systematic use of CPO measured by U-stage for field studies all over the world for last 40 years has now been intensified in last 15 years by the use of electron back-scattered diffraction (EBSD) to study of CPO and the associated digital microstructure. It is an appropriate time to analysis CPO databases of olivine and other minerals, which represents the work of our group, both present and former members, as well as collaborating colleagues. It is also interesting to compare the natural record as illustrated by our databases in the light of recent experimental results. Information on CPO together with single crystal elastic constants and the equation of state allow the modelling of seismic anisotropy due to plasticity at any PT condition, and the connection with geodynamic processes related to large-scale flow in the deep Earth.

Thermodynamics of anisotropic antiferromagnetic Heisenberg chain in the presence of longitudinal magnetic field

NASA Astrophysics Data System (ADS)

Rezania, H.

2018-07-01

We have addressed the specific heat and magnetization of one dimensional spin-1/2 anisotropic antiferromagnetic Heisenberg chain at finite magnetic field. We have investigated the thermodynamic properties by means of excitation spectrum in terms of a hard core Bosonic representation. The effect of in-plane anisotropy thermodynamic properties has also been studied via the Bosonic model by Green's function approach. This anisotropy is considered for exchange constants that couple spin components perpendicular to magnetic field direction. We have found the temperature dependence of the specific heat and longitudinal magnetization in the gapped field induced spin-polarized phase for various magnetic fields and anisotropy parameters. Furthermore we have studied the magnetic field dependence of specific heat and magnetization for various anisotropy parameters. Our results show temperature dependence of specific heat includes a peak so that its temperature position goes to higher temperature with increase of magnetic field. We have found the magnetic field dependence of specific heat shows a monotonic decreasing behavior for various magnetic fields due to increase of energy gap in the excitation spectrum. Also we have studied the temperature dependence of magnetization for different magnetic fields and various anisotropy parameters.

Anomalous thermal diffusivity in underdoped YBa2Cu3O6+x

PubMed Central

Levenson-Falk, Eli M.; Ramshaw, B. J.; Bonn, D. A.; Liang, Ruixing; Hardy, W. N.; Hartnoll, Sean A.; Kapitulnik, Aharon

2017-01-01

The thermal diffusivity in the ab plane of underdoped YBCO crystals is measured by means of a local optical technique in the temperature range of 25–300 K. The phase delay between a point heat source and a set of detection points around it allows for high-resolution measurement of the thermal diffusivity and its in-plane anisotropy. Although the magnitude of the diffusivity may suggest that it originates from phonons, its anisotropy is comparable with reported values of the electrical resistivity anisotropy. Furthermore, the anisotropy drops sharply below the charge order transition, again similar to the electrical resistivity anisotropy. Both of these observations suggest that the thermal diffusivity has pronounced electronic as well as phononic character. At the same time, the small electrical and thermal conductivities at high temperatures imply that neither well-defined electron nor phonon quasiparticles are present in this material. We interpret our results through a strongly interacting incoherent electron–phonon “soup” picture characterized by a diffusion constant D∼vB2τ, where vB is the soup velocity, and scattering of both electrons and phonons saturates a quantum thermal relaxation time τ∼ℏ/kBT. PMID:28484003

Size-dependent magnetic anisotropy of PEG coated Fe3O4 nanoparticles; comparing two magnetization methods

NASA Astrophysics Data System (ADS)

Nayek, C.; Manna, K.; Imam, A. A.; Alqasrawi, A. Y.; Obaidat, I. M.

2018-02-01

Understanding the size dependent magnetic anisotropy of iron oxide nanoparticles is essential for the successful application of these nanoparticles in several technological and medical fields. PEG-coated iron oxide (Fe3O4) nanoparticles with core diameters of 12 nm, 15 nm, and 16 nm were synthesized by the usual co-precipitation method. The morphology and structure of the nanoparticles were investigated using transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and X-ray diffraction (XRD). Magnetic measurements were conducted using a SQUID. The effective magnetic anisotropy was calculated using two methods from the magnetization measurements. In the first method the zero-field-cooled magnetization versus temperature measurements were used at several applied magnetic fields. In the second method we used the temperature-dependent coercivity curves obtained from the zero-field-cooled magnetization versus magnetic field hysteresis loops. The role of the applied magnetic field on the effective magnetic anisotropy, calculated form the zero-field-cooled magnetization versus temperature measurements, was revealed. The size dependence of the effective magnetic anisotropy constant Keff obtained by the two methods are compared and discussed.

Transition from itinerant metamagnetism to ferromagnetism in UCo1-xOsxAl solid solutions

NASA Astrophysics Data System (ADS)

Andreev, A. V.; Šebek, J.; Shirasaki, K.; Daniš, S.; Gorbunov, D. I.; Yamamura, T.; Vejpravová, J.; Havela, L.; de Boer, F. R.

2018-05-01

The influence of substitution of a small amount of Os (<2%) on the Co sublattice on the magnetism of the itinerant metamagnet UCoAl is studied on single-crystalline UCo1-xOsxAl compounds with x = 0.002, 0.005 and 0.01. For x = 0.002, the ground state is still paramagnetic, like in UCoAl. The metamagnetic-transition field is 0.37 T, twice lower than in UCoAl. The compound with x = 0.005 is at the border between the paramagnetic and the ferromagnetic ground state. At T = 2 K, it is ferromagnetic, at elevated temperatures a magnetic field is necessary to maintain the magnetic state. In zero field, the ferromagnetic state vanishes at T = 8 K. The compound with x = 0.01 is a ferromagnet with strong uniaxial magnetic anisotropy similar to the previously studied compounds with x = 0.02-0.20.

Strain-modulated anisotropy of quantum transport properties in single-layer silicene: Spin and valley filtering

NASA Astrophysics Data System (ADS)

Farokhnezhad, M.; Esmaeilzadeh, M.; Shakouri, Kh.

2017-11-01

Strained two-dimensional crystals often offer novel physical properties that are usable to improve their electronic performance. Here we show by the theory of elasticity combined with the tight-binding approximation that local strains in silicene can open up new prospects for generating fully polarized spin and valley currents. The trajectory of electrons flowing through locally strained regions obeys the same behavior as light waves propagating in uniaxial anisotropic materials. The refraction angle of electrons at local strain boundaries exhibits a strong dependence on the valley degree of freedom, allowing for valley filtering based on the strain direction. The ability to control the spin polarization direction additionally requires a perpendicular electric field to be involved in combination with the local strain. Further similarities of the problem with optics of anisotropic materials are elucidated and possible applications in spin- and valleytronic nanodevices are discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aldosary, Mohammed; Li, Junxue; Tang, Chi

30-80 nm thick yttrium iron garnet (YIG) films are grown by pulsed laser deposition on a 5 nm thick sputtered Pt atop gadolinium gallium garnet substrate (GGG) (110). Upon post-growth rapid thermal annealing, single crystal YIG(110) emerges as if it were epitaxially grown on GGG(110) despite the presence of the intermediate Pt film. The YIG surface shows atomic steps with the root-mean-square roughness of 0.12 nm on flat terraces. Both Pt/YIG and GGG/Pt interfaces are atomically sharp. The resulting YIG(110) films show clear in-plane uniaxial magnetic anisotropy with a well-defined easy axis along 〈001〉 and a peak-to-peak ferromagnetic resonance linewidth of 7.5 Oe atmore » 9.32 GHz, similar to YIG epitaxially grown on GGG. Both spin Hall magnetoresistance and longitudinal spin Seebeck effects in the inverted bilayers indicate excellent Pt/YIG interface quality.« less

The anisotropic effective damping of thickness-dependent epitaxial Co2FeAl films studied by spin rectification

NASA Astrophysics Data System (ADS)

Chen, Zhendong; Kong, Wenwen; Mi, Kui; Chen, Guilin; Zhang, Peng; Fan, Xiaolong; Gao, Cunxu; Xue, Desheng

2018-03-01

Epitaxial Co2FeAl films with the thickness varying from 26.4 nm to 4.6 nm were grown on MgO(001) substrates by molecular beam epitaxy. Spin rectification was adopted to study the dynamic magnetic properties of the Co2FeAl films, considering the reported advantages of this technique with high thickness-independent sensitivity on samples. At a fixed microwave frequency, the in-plane angular dependent resonance fields and their linewidths exhibit a superposition of a uniaxial and a fourfold anisotropy for all samples. The results reveal an anisotropic damping behavior of the films. Along in-plane different azimuths of the films, frequency-dependent resonance-field linewidths were investigated. The anisotropic effective damping of the films with the thickness varying from 26.4 nm to 4.6 nm was then analyzed, which is contributed from the two-magnon scattering.

Tuning of optical mode magnetic resonance in CoZr/Ru/CoZr synthetic antiferromagnetic trilayers by oblique sputtering

NASA Astrophysics Data System (ADS)

Wang, Wenqiang; Wang, Fenglong; Cao, Cuimei; Li, Pingping; Yao, Jinli; Jiang, Changjun

2018-04-01

CoZr/Ru/CoZr synthetic antiferromagnetic trilayers with strong antiferromagnetic interlayer coupling were fabricated by an oblique sputtering method that induced in-plane uniaxial magnetic anisotropy. A microstrip method using a vector network analyzer was applied to investigate the magnetic resonance modes of the trilayers, including the acoustic modes (AMs) and the optical modes (OMs). At zero magnetic field, the CoZr/Ru/CoZr trilayers showed OMs with resonance frequencies of up to 7.1 GHz. By increasing the applied external magnetic field, the magnetic resonance mode can be tuned to various OMs, mixed modes, and AMs. Additionally, the magnetic resonance mode showed an angular dependence between the magnetization and the microwave field, which showed similar switching of the magnetic modes with variation of the angle. Our results provide important information that will be helpful in the design of multifunctional microwave devices.

Noise suppression and crosstalk analysis of on-chip magnetic film-type noise suppressor

NASA Astrophysics Data System (ADS)

Ma, Jingyan; Muroga, Sho; Endo, Yasushi; Hashi, Shuichiro; Naoe, Masayuki; Yokoyama, Hiroo; Hayashi, Yoshiaki; Ishiyama, Kazushi

2018-05-01

This paper discusses near field, conduction and crosstalk noise suppression of magnetic films with uniaxial anisotropy on transmission lines for a film-type noise suppressor in the GHz frequency range. The electromagnetic noise suppressions of magnetic films with different permeability and resistivity were measured and simulated with simple microstrip lines. The experimental and simulated results of Co-Zr-Nb and CoPd-CaF2 films agreed with each other. The results indicate that the higher permeability leads to a better near field shielding, and in the frequency range of 2-7 GHz, a higher conduction noise suppression. It also suggests that the higher resistivity results in a better crosstalk suppression in the frequency range below 2 GHz. These results can support the design guidelines of the magnetic film-type noise suppressor used in the next generation IC chip.

Optical Anisotropy and Waveguiding in Thin Films of a Conjugated Polymer Which Exhibits Stimulated Emission.

NASA Astrophysics Data System (ADS)

Miller, E. Kirk; McGehee, Michael; Diaz-Garcia, Maria; Srikant, V.; Heeger, Alan J.

1998-03-01

We report variable angle spectroscopic ellipsometry (VASE) measurements on thin films of poly(2-butyl-5(2-ethyl-hexyl)-1,4- phenylenevinylene) (BuEH-PPV) in the spectral region below the electronic absorption edge. We find that the films are best described as uniaxially anisotropic, with the optical axis perpendicular to the plane of the film, consistent with the notion that the polymer chains lie preferentially in the plane of the film. Due to the anisotropic distribution of chromophores, the in-plane index of refraction is found to be significantly higher and more dispersive than the out-of- plane index, implying a higher effective index for transverse-electric (TE) waveguide modes than for the corresponding transverse- magnetic (TM) modes. The implications of these data for amplified spontaneous emission (ASE) experiments and in-plane laser structures are discussed.

Measured iron-gallium alloy tensile properties under magnetic fields

NASA Astrophysics Data System (ADS)

Yoo, Jin-Hyeong; Flatau, Alison B.

2004-07-01

Tension testing is used to identify Galfenol material properties under low level DC magnetic bias fields. Dog bone shaped specimens of single crystal Fe100-xGax, where 17<=x<=33, underwent tensile testing along two crystalographic axis orientations, [110] and [100]. The material properties being investigated and calculated from measured quantities are: Young's modulus and Poisson's ratio. Data are presented that demonstrate the dependence of these material properties on applied magnetic field levels and provide a preliminary assessment of the trends in material properties for performance under varied operating conditions. The elastic properties of Fe-Ga alloys were observed to be increasingly anisotropic with rising Ga content for the stoichiometries examined. The largest elastic anisotropies were manifested in [110] Poisson's ratios of as low as -0.63 in one specimen. This negative Poisson's ratio creates a significant in-plane auxetic behavior that could be exploited in applications that capitalize on unique area effects produced under uniaxial loading.

Shock fabrics in fine-grained micrometeorites

NASA Astrophysics Data System (ADS)

Suttle, M. D.; Genge, M. J.; Russell, S. S.

2017-10-01

The orientations of dehydration cracks and fracture networks in fine-grained, unmelted micrometeorites were analyzed using rose diagrams and entropy calculations. As cracks exploit pre-existing anisotropies, analysis of their orientation provides a mechanism with which to study the subtle petrofabrics preserved within fine-grained and amorphous materials. Both uniaxial and biaxial fabrics are discovered, often with a relatively wide spread in orientations (40°-60°). Brittle deformation cataclasis and rotated olivine grains are reported from a single micrometeorite. This paper provides the first evidence for impact-induced shock deformation in fine-grained micrometeorites. The presence of pervasive, low-grade shock features in CM chondrites and CM-like dust, anomalously low-density measurements for C-type asteroids, and impact experiments which suggest CM chondrites are highly prone to disruption all imply that CM parent bodies are unlikely to have remained intact and instead exist as a collection of loosely aggregated rubble-pile asteroids, composed of primitive shocked clasts.

Large Strain Behaviour of ZEK100 Magnesium Alloy at Various Strain Rates

NASA Astrophysics Data System (ADS)

Lévesque, Julie; Kurukuri, Srihari; Mishra, Raja; Worswick, Michael; Inal, Kaan

A constitutive framework based on a rate-dependent crystal plasticity theory is employed to simulate large strain deformation in hexagonal closed-packed metals that deform by slip and twinning. The model allows the twinned zones and the parent matrix to rotate independently. ZEK100 magnesium alloy sheets which significant texture weakening compared to AZ31 sheets are investigated using the model. There is considerable in-plane anisotropy and tension compression asymmetry in the flow behavior of ZEK100. Simulations of uniaxial tension in different directions at various strain rates and the accompanying texture evolution are performed and they are in very good agreement with experimental measurements. The effect of strain rate on the activation of the various slip systems and twinning show that differences in the strain rate dependence of yield stress and Rvalues in ZEK100 have their origin in the activation of different deformation mechanisms.

Static and high frequency magnetic properties of FeGa thin films deposited on convex flexible substrates

NASA Astrophysics Data System (ADS)

Yu, Ying; Zhan, Qingfeng; Wei, Jinwu; Wang, Jianbo; Dai, Guohong; Zuo, Zhenghu; Zhang, Xiaoshan; Liu, Yiwei; Yang, Huali; Zhang, Yao; Xie, Shuhong; Wang, Baomin; Li, Run-Wei

2015-04-01

Magnetostrictive FeGa thin films were deposited on the bowed flexible polyethylene terephthalate (PET) substrates, which were fixed on the convex mold. A compressive stress was induced in FeGa films when the PET substrates were shaped from convex to flat. Due to the effect of magnetostriction, FeGa films exhibit an obvious in-plane uniaxial magnetic anisotropy which could be enhanced by increasing the applied pre-strains on the substrates during growth. Consequently, the ferromagnetic resonance frequency of the films was significantly increased, but the corresponding initial permeability was decreased. Moreover, the films with pre-strains less than 0.78% exhibit a working bandwidth of microwave absorption about 2 GHz. Our investigations demonstrated a convenient method via the pre-strained substrates to tune the high frequency properties of magnetic thin films which could be applied in flexible microwave devices.

Intergrannular strain evolution in a zircaloy-4 alloy with Widmanstatten microstructure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clausen, Bjorn; Vogel, Sven C; Garlea, Eena

2009-01-01

A Zircaloy-4 alloy with Widmanstatten-Basketweave microstructure and random texture has been used to study the deformation systems responsible for the polycrystalline plasticity at the grain level. The evolution of internal strain and bulk texture is investigated using neutron diffraction and an elasto-plastic self-consistent (EPSC) modeling scheme. The macroscopic stress-strain behavior and intergranular (hkil-specific) strain development, parallel and perpendicular to the loading direction, were measured in-situ during uniaxial tensile loading. Then, the EPSC model was employed to simulate the experimental results. This modeling scheme accounts for the thermal anisotropy; elastic-plastic properties of the constituent grains; and activation, reorientation, and stress relaxationmore » associated with twinning. The agreement between the experiment and the model will be discussed as well as the critical resolved shear stresses (CRSS) and the hardening coefficients obtained from the model.« less

Simulation study of axial ultrasound transmission in heterogeneous cortical bone model

NASA Astrophysics Data System (ADS)

Takano, Koki; Nagatani, Yoshiki; Matsukawa, Mami

2017-07-01

Ultrasound propagation in a heterogeneous cortical bone was studied. Using a bovine radius, the longitudinal wave velocity distribution in the axial direction was experimentally measured in the MHz range. The bilinear interpolation and piecewise cubic Hermite interpolation methods were applied to create a three-dimensional (3D) precise velocity model of the bone using experimental data. By assuming the uniaxial anisotropy of the bone, the distributions of all elastic moduli of a 3D heterogeneous model were estimated. The elastic finite-difference time-domain method was used to simulate axial ultrasonic wave propagation. The wave propagation in the initial model was compared with that in the thinner model, where the inner part of the cortical bone model was removed. The wave front of the first arriving signal (FAS) slightly depended on the heterogeneity in each model. Owing to the decrease in bone thickness, the propagation behavior also changed and the FAS velocity clearly decreased.

Room Temperature Ferromagnetic, Anisotropic, Germanium Rich FeGe(001) Alloys

PubMed Central

Lungu, George A.; Apostol, Nicoleta G.; Stoflea, Laura E.; Costescu, Ruxandra M.; Popescu, Dana G.; Teodorescu, Cristian M.

2013-01-01

Ferromagnetic FexGe1−x with x = 2%–9% are obtained by Fe deposition onto Ge(001) at high temperatures (500 °C). Low energy electron diffraction (LEED) investigation evidenced the preservation of the (1 × 1) surface structure of Ge(001) with Fe deposition. X-ray photoelectron spectroscopy (XPS) at Ge 3d and Fe 2p core levels evidenced strong Fe diffusion into the Ge substrate and formation of Ge-rich compounds, from FeGe3 to approximately FeGe2, depending on the amount of Fe deposited. Room temperature magneto-optical Kerr effect (MOKE) evidenced ferromagnetic ordering at room temperature, with about 0.1 Bohr magnetons per Fe atom, and also a clear uniaxial magnetic anisotropy with the in-plane [110] easy magnetization axis. This compound is a good candidate for promising applications in the field of semiconductor spintronics. PMID:28809330

Non-volatile magnetic random access memory

NASA Technical Reports Server (NTRS)

Katti, Romney R. (Inventor); Stadler, Henry L. (Inventor); Wu, Jiin-Chuan (Inventor)

1994-01-01

Improvements are made in a non-volatile magnetic random access memory. Such a memory is comprised of an array of unit cells, each having a Hall-effect sensor and a thin-film magnetic element made of material having an in-plane, uniaxial anisotropy and in-plane, bipolar remanent magnetization states. The Hall-effect sensor is made more sensitive by using a 1 m thick molecular beam epitaxy grown InAs layer on a silicon substrate by employing a GaAs/AlGaAs/InAlAs superlattice buffering layer. One improvement avoids current shunting problems of matrix architecture. Another improvement reduces the required magnetizing current for the micromagnets. Another improvement relates to the use of GaAs technology wherein high electron-mobility GaAs MESFETs provide faster switching times. Still another improvement relates to a method for configuring the invention as a three-dimensional random access memory.

Broken rotational symmetry on the Fermi surface of a high-Tc superconductor

DOE PAGES

Ramshaw, B. J.; Harrison, N.; Sebastian, S. E.; ...

2017-02-13

Broken fourfold rotational (C 4) symmetry is observed in the experimental properties of several classes of unconventional superconductors. It has been proposed that this symmetry breaking is important for superconducting pairing in these materials, but in the high-T c cuprates this broken symmetry has never been observed on the Fermi surface. Here we report a pronounced anisotropy in the angle dependence of the interlayer magnetoresistance of the underdoped high transition temperature (high-T c) superconductor YBa 2Cu 3O 6.58, directly revealing broken C 4 symmetry on the Fermi surface. Moreover, we demonstrate that this Fermi surface has C 2 symmetry ofmore » the type produced by a uniaxial or anisotropic density-wave phase. This establishes the central role of C 4 symmetry breaking in the Fermi surface reconstruction of YBa 2Cu 3O 6+δ , and suggests a striking degree of universality among unconventional superconductors.« less

High Curie temperature drive layer materials for ion-implanted magnetic bubble devices

NASA Technical Reports Server (NTRS)

Fratello, V. J.; Wolfe, R.; Blank, S. L.; Nelson, T. J.

1984-01-01

Ion implantation of bubble garnets can lower the Curie temperature by 70 C or more, thus limiting high temperature operation of devices with ion-implanted propagation patterns. Therefore, double-layer materials were made with a conventional 2-micron bubble storage layer capped by an ion-implantable drive layer of high Curie temperature, high magnetostriction material. Contiguous disk test patterns were implanted with varying doses of a typical triple implant. Quality of propagation was judged by quasistatic tests on 8-micron period major and minor loops. Variations of magnetization, uniaxial anisotropy, implant dose, and magnetostriction were investigated to ensure optimum flux matching, good charged wall coupling, and wide operating margins. The most successful drive layer compositions were in the systems (SmDyLuCa)3(FeSi)5O12 and (BiGdTmCa)3(FeSi)5O12 and had Curie temperatures 25-44 C higher than the storage layers.

Changes in magnetic domain structure during twin boundary motion in single crystal Ni-Mn-Ga exhibiting magnetic shape memory effect

NASA Astrophysics Data System (ADS)

Kopecký, V.; Fekete, L.; Perevertov, O.; Heczko, O.

2016-05-01

The complexity of Ni-Mn-Ga single crystal originates from the interplay between ferromagnetic domain structure and ferroelastic twinned microstructure. Magnetic domain structure in the vicinity of single twin boundary was studied using magneto-optical indicator film and magnetic force microscopy technique. The single twin boundary of Type I was formed mechanically and an initial magnetization state in both variants were restored by local application of magnetic field (≈40 kA/m). The differently oriented variants exhibited either stripe or labyrinth magnetic domain pattern in agreement with the uniaxial magnetocrystalline anisotropy of the martensite. The twin boundary was then moved by compressive or tensile stress. The passage of the boundary resulted in the formation of granular or rake domains, respectively. Additionally, the specific magnetic domains pattern projected by twin boundary gradually vanished during twin boundary motion.

Angular tuning of the magnetic birefringence in rippled cobalt films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arranz, Miguel A., E-mail: MiguelAngel.Arranz@uclm.es; Colino, José M.

We report the measurement of magnetically induced birefringence in rippled Co films. For this purpose, the magneto-optical properties of ion beam eroded ferromagnetic films were studied using Kerr magnetometry and magnetic birefringence in the transmitted light intensity. Upon sufficient ion sculpting, these ripple surface nanostructures developed a defined uniaxial anisotropy in the in-plane magnetization, finely tuning the magnetic birefringence effect. We have studied its dependence on the relative orientation between the ripple direction and the magnetic field, and found this effect to be dramatically correlated with the capability to neatly distinguish the mechanisms for the in-plane magnetization reversal, i.e., rotationmore » and nucleation. This double refraction corresponds univocally to the two magnetization axes, parallel and perpendicular to the ripples direction. We have also observed that tuned birefringence in stack assemblies of rippled Co films, which enables us to technically manipulate the number and direction of refraction axes.« less

ANISOTROPY DETERMINATIONS IN EXCHANGE SPRING MAGNETS.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LEWIS,L.H.; HARLAND,C.L.

2002-08-18

Ferromagnetic nanocomposites, or ''exchange spring'' magnets, possess a nanoscaled microstructure that allows intergrain magnetic exchange forces to couple the constituent grains and alter the system's effective magnetic anisotropies. While the effects of the anisotropy alterations are clearly seen in macroscopic magnetic measurement, it is extremely difficult to determine the detailed effects of the system's exchange coupling, such as the interphase exchange length, the inherent domain wall widths or the effective anisotropies of the system. Clarification of these materials parameters may be obtained from the ''micromagnetic'' phenomenological model, where the assumption of magnetic reversal initiating in the magnetically-soft regions of themore » exchange-spring maqet is explicitly included. This approach differs from that typically applied by other researchers and allows a quantitative estimate of the effective anisotropies of an exchange spring system. Hysteresis loops measured on well-characterized nanocomposite alloys based on the composition Nd{sub 2}Fe{sub 14}B + {alpha}-Fe at temperatures above the spin reorientation temperature were analyzed within the framework of the micromagnetic phenomenological model. Preliminary results indicate that the effective anisotropy constant in the material is intermediate to that of bulk {alpha}-Fe and bulk Nd{sub 2}Fe{sub 14}B and increases with decreasing temperature. These results strongly support the idea that magnetic reversal in nanocomposite systems initiates in the lower-anisotropy regions of the system, and that the soft-phase regions become exchange-hardened by virtue of their proximity to the magnetically-hard regions.« less

Prediction of equibiaxial loading stress in collagen-based extracellular matrix using a three-dimensional unit cell model.

PubMed

Susilo, Monica E; Bell, Brett J; Roeder, Blayne A; Voytik-Harbin, Sherry L; Kokini, Klod; Nauman, Eric A

2013-03-01

Mechanical signals are important factors in determining cell fate. Therefore, insights as to how mechanical signals are transferred between the cell and its surrounding three-dimensional collagen fibril network will provide a basis for designing the optimum extracellular matrix (ECM) microenvironment for tissue regeneration. Previously we described a cellular solid model to predict fibril microstructure-mechanical relationships of reconstituted collagen matrices due to unidirectional loads (Acta Biomater 2010;6:1471-86). The model consisted of representative volume elements made up of an interconnected network of flexible struts. The present study extends this work by adapting the model to account for microstructural anisotropy of the collagen fibrils and a biaxial loading environment. The model was calibrated based on uniaxial tensile data and used to predict the equibiaxial tensile stress-stretch relationship. Modifications to the model significantly improved its predictive capacity for equibiaxial loading data. With a comparable fibril length (model 5.9-8μm, measured 7.5μm) and appropriate fibril anisotropy the anisotropic model provides a better representation of the collagen fibril microstructure. Such models are important tools for tissue engineering because they facilitate prediction of microstructure-mechanical relationships for collagen matrices over a wide range of microstructures and provide a framework for predicting cell-ECM interactions. Copyright © 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Spin-polarized Second Harmonic Generation from the Antiferromagnetic CaCoSO Single Crystal

NASA Astrophysics Data System (ADS)

Reshak, A. H.

2017-04-01

The spin-polarized second harmonic generation (SHG) of the recently synthesized CaCoSO single crystal is performed based on the calculated electronic band structure. The calculation reveals that the spin-up (↑) channel of CaCoSO possesses a direct energy gap (Γv-Γc) of about 2.187 eV, 1.187 eV (Kv-Kc) for the spin-down (↓) channel and an indirect gap (Γv-Kc) of about 0.4 eV for the spin-polarized CaCoSO single crystal. The linear optical properties obtained reveal that the recently synthesized crystal exhibits considerable anisotropy with negative uniaxial anisotropy and birefringence favor to enhance the SHG. We have calculated the three non-zero tensor components of the SHG and found the is the dominat component, one with a large SHG of about (d33 = 6.936 pm/V at λ = 1064 nm), the half value of KTiOPO4 (KTP). As the values of (↑) < (↓) < spin-polarized are related to the values of the energy gap of (↑) 2.187 eV> (↓) 1.187 eV> spin-polarized gap 0.4 eV therefore, a smaller energy gap gives better SHG performance. Furthermore, the microscopic first hyperpolarizability, βijk, is calculated.

Mechanical Properties of Austenitic Stainless Steel Made by Additive Manufacturing.

PubMed

Luecke, William E; Slotwinski, John A

2014-01-01

Using uniaxial tensile and hardness testing, we evaluated the variability and anisotropy of the mechanical properties of an austenitic stainless steel, UNS S17400, manufactured by an additive process, selective laser melting. Like wrought materials, the mechanical properties depend on the orientation introduced by the processing. The recommended stress-relief heat treatment increases the tensile strength, reduces the yield strength, and decreases the extent of the discontinuous yielding. The mechanical properties, assessed by hardness, are very uniform across the build plate, but the stress-relief heat treatment introduced a small non-uniformity that had no correlation to position on the build plate. Analysis of the mechanical property behavior resulted in four conclusions. (1) The within-build and build-to-build tensile properties of the UNS S17400 stainless steel are less repeatable than mature engineering structural alloys, but similar to other structural alloys made by additive manufacturing. (2) The anisotropy of the mechanical properties of the UNS S17400 material of this study is larger than that of mature structural alloys, but is similar to other structural alloys made by additive manufacturing. (3) The tensile mechanical properties of the UNS S17400 material fabricated by selective laser melting are very different from those of wrought, heat-treated 17-4PH stainless steel. (4) The large discontinuous yielding strain in all tests resulted from the formation and propagation of Lüders bands.

Effects on Magnetic Properties of GaMnAs Induced by Proximity of Topological Insulator Bi2Se3

NASA Astrophysics Data System (ADS)

Bac, Seul-Ki; Lee, Hakjoon; Lee, Sangyeop; Choi, Seonghoon; Lee, Sanghoon; Liu, X.; Dobrowolska, M.; Furdyna, J. K.

2018-04-01

Effects induced by a topological insulator Bi2Se3 on the magnetic properties of an adjacent GaMnAs film have been investigated using transport measurements. We observed three conspicuous effects in the GaMnAs layer induced by the proximity of the Bi2Se3 overlayer. First, our resistivity data as a function of temperature show that the GaMnAs layer adjacent to the Bi2Se3 displayed strongly metallic behavior, as compared with the GaMnAs control specimen. Second, the Curie temperature of the GaMnAs in the bilayer was observed to be higher than that of the control layer, in our case by nearly a factor of two. Finally, we observed significant changes in the in-plane magnetic anisotropy of the GaMnAs in the bilayer, in the form of much higher values of both cubic and uniaxial anisotropy parameters. This latter feature manifests itself in a rather spectacular increase of the coercive field observed in magnetization reversal across the in-plane hard axis. These results suggest that proximity of an adjacent Bi2Se3 layer represents an important tool for modifying and controlling the ferromagnetic properties of GaMnAs film, and could thus be used to optimize this and similar materials for applications in spintronic devices.

Sol–gel auto combustion synthesis of CoFe{sub 2}O{sub 4}/1-methyl-2-pyrrolidone nanocomposite with ethylene glycol: Its magnetic characterization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Topkaya, R., E-mail: rtopkaya@gyte.edu.tr; Kurtan, U.; Junejo, Y.

2013-09-01

Graphical abstract: - Highlights: • CoFe{sub 2}O{sub 4} was generated by sol–gel autocombustion using 1-methyl-2-pyrrolidone and ethylene glycol. • The presence of spin-disordered surface layer on magnetic core was established. • A linear dependence of the coercivity on temperature was fitted to Kneller's law. - Abstract: Magnetic nanoparticles were generated by sol–gel auto combustion synthesis of metal salts in the presence of 1-methyl-2-pyrrolidone, a functional solvent and ethylene glycol as usual solvent. The average crystallite size was obtained by using line profile fitting as 11 ± 5 nm. The saturation magnetization value decreases with usage of the ethylene glycol inmore » synthesis. The observed exchange bias effect further confirms the existence of the magnetically ordered core surrounded by spin-disordered surface layer and the ethylene glycol. Square-root temperature dependence of coercivity can be fitted to Kneller's law in the temperature range of 10–400 K. The reduced remanent magnetization values lower than the theoretical value of 0.5 for non-interacting single domain particles indicate the CoFe{sub 2}O{sub 4}-1-methyl-2-pyrrolidone nanocomposite to have uniaxial anisotropy instead of the expected cubic anisotropy according to the Stoner–Wohlfarth model.« less

Mechanical Properties of Austenitic Stainless Steel Made by Additive Manufacturing

PubMed Central

Luecke, William E; Slotwinski, John A

2014-01-01

Using uniaxial tensile and hardness testing, we evaluated the variability and anisotropy of the mechanical properties of an austenitic stainless steel, UNS S17400, manufactured by an additive process, selective laser melting. Like wrought materials, the mechanical properties depend on the orientation introduced by the processing. The recommended stress-relief heat treatment increases the tensile strength, reduces the yield strength, and decreases the extent of the discontinuous yielding. The mechanical properties, assessed by hardness, are very uniform across the build plate, but the stress-relief heat treatment introduced a small non-uniformity that had no correlation to position on the build plate. Analysis of the mechanical property behavior resulted in four conclusions. (1) The within-build and build-to-build tensile properties of the UNS S17400 stainless steel are less repeatable than mature engineering structural alloys, but similar to other structural alloys made by additive manufacturing. (2) The anisotropy of the mechanical properties of the UNS S17400 material of this study is larger than that of mature structural alloys, but is similar to other structural alloys made by additive manufacturing. (3) The tensile mechanical properties of the UNS S17400 material fabricated by selective laser melting are very different from those of wrought, heat-treated 17-4PH stainless steel. (4) The large discontinuous yielding strain in all tests resulted from the formation and propagation of Lüders bands. PMID:26601037

Driving ferromagnetic resonance frequency of FeCoB/PZN-PT multiferroic heterostructures to Ku-band via two-step climbing: composition gradient sputtering and magnetoelectric coupling

PubMed Central

Li, Shandong; Xue, Qian; Duh, Jenq-Gong; Du, Honglei; Xu, Jie; Wan, Yong; Li, Qiang; Lü, Yueguang

2014-01-01

RF/microwave soft magnetic films (SMFs) are key materials for miniaturization and multifunctionalization of monolithic microwave integrated circuits (MMICs) and their components, which demand that the SMFs should have higher self-bias ferromagnetic resonance frequency fFMR, and can be fabricated in an IC compatible process. However, self-biased metallic SMFs working at X-band or higher frequency were rarely reported, even though there are urgent demands. In this paper, we report an IC compatible process with two-step superposition to prepare SMFs, where the FeCoB SMFs were deposited on (011) lead zinc niobate–lead titanate substrates using a composition gradient sputtering method. As a result, a giant magnetic anisotropy field of 1498 Oe, 1–2 orders of magnitude larger than that by conventional magnetic annealing method, and an ultrahigh fFMR of up to 12.96 GHz reaching Ku-band, were obtained at zero magnetic bias field in the as-deposited films. These ultrahigh microwave performances can be attributed to the superposition of two effects: uniaxial stress induced by composition gradient and magnetoelectric coupling. This two-step superposition method paves a way for SMFs to surpass X-band by two-step or multi-step, where a variety of magnetic anisotropy field enhancing methods can be cumulated together to get higher ferromagnetic resonance frequency. PMID:25491374

Love-to-Rayleigh Conversions and Seismic Anisotropy in Cascadia

NASA Astrophysics Data System (ADS)

Rieger, Duayne Matthew

Seismic anisotropy is often attributed to the development of lattice-preferred orientation (LPO) of olivine crystals in peridotite, induced by the dislocation creep component of mantle deformation (Karato et al., 2008; Ribe, 1992). Mantle-flow-induced seismic anisotropy is often modeled in the simple form of hexagonal symmetry, where the anisotropic volume is uniaxially fast or slow. This relationship between seismic anisotropy and mantle deformation allows for the mapping of mantle dynamics using measurements of seismic anisotropy. Presently, methods of measuring seismic anisotropy in Earth's mantle include shear-wave splitting and surface-wave tomography. These methods are tuned to seismically fast axes laying in the horizontal or surface-tangent plane and are limited in discerning clipping seismic fast axes. This is a shortcoming. It is reasonable to suspect the presence of dipping seismic fast axes induced by mantle flow in several tectonic regimes such as subduction zones. The slab rollback model of the subduction zone system has been argued to exhibit trench-parallel subslab anisotropy due to the lateral evacuation of the subslab mantle material (Hall et al., 2000; Russo and Silver, 1994). This model has been emboldened by the dominance of trench-parallel shear-wave-splitting measurements in the subslab mantle of global subduction zones. This model has significant geodynamic implications, requiring viscous decoupling between the subslab mantle and the sub-ducting slab. The Cascadian subduction zone is of particular scientific interest. While experiencing slab rollback (Zandt and Humphreys, 2008), trench-perpendicular shear-wave-splitting measurements are observed in the subslab mantle of Cascadia (Currie et al., 2004; Eakin et al., 2010; Long and Silver, 2008; 2009). This suggests either viscous coupling resulting in slab-entrained flow or the presence of an alternate relationship between finite strain in the mantle and seismic anisotropy. The ability to discern a clipping anisotropic axis would help gain insight into the mantle dynamics of regions such as Cascadia. Lateral gradients of seismic anisotropy in Earth's upper mantle induce coupling among Earth's spheroidal and toroidal normal modes. This coupling can manifest as observable surface-wave polarization anomalies resulting from Love to Rayleigh wave conversions. These Love to Rayleigh conversions are known in the literature as Quasi-Love (QL) waves (Park and Yu, 1992) and are sensitive to both the strike and the dip of an anisotropic symmetry axis. In this dissertation I investigate the phenomenology of QL surface-wave scattering, including its sensitivity to the type and orientation of seismic anisotropy. I then apply my findings to observations of QL wave scattering in Cascada in order to further constrain subslab mantle anisotropy in the region. First, I make initial observations and confirm the presence of QL scattering in Cascada and the western U.S. using data recorded on USArray. I then move on to develop an algorithm to model efficiently QL wave scattering in the presence of 3-dimensional anisotropic structure. Using this forward-modeling algorithm, I investigate the dependence of QL wave scattering on the type and orientation of seismic Anisotropy. I find that P and S anisotropies exhibit independent effects on scattering. Scattering due to S anisotropy is stronger than that due to P anisotropy for all orientations and dominates in the observed scattering pattern. Both the phase and amplitude of the QL wave is dependent on the orientation (strike and dip) of the symmetry axis relative to the incident propagation azimuth of the source-receiver great-circle path. Due to this, the orientation of the anisotropic symmetry axis provides a distinct signature which is observable in the variation of QL wave scattering with wave-propagation azimuth. Finally, using data recorded on USArray, I observe the variation in QL wave scattering with propagation azimuth. I then attempt to forward-model the observed behavior using the algorithm developed earlier. The best-fitting model suggests coherent trench-perpendicular mantle anisotropy with an eastward dip in the sublsab mantle of the Cascadian subduction zone. The resulting anisotropic model adds confidence to the entrained subslab mantle-flow model for Cascadia and further refutes the 3-D return-flow model associated with slab rollback.

YCo5±x thin films with perpendicular anisotropy grown by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Sharma, S.; Hildebrandt, E.; Sharath, S. U.; Radulov, I.; Alff, L.

2017-06-01

The synthesis conditions of buffer-free (00l) oriented YCo5 and Y2Co17 thin films onto Al2O3 (0001) substrates have been explored by molecular beam epitaxy (MBE). The manipulation of the ratio of individual atomic beams of Yttrium, Y and Cobalt, Co, as well as growth rate variations allows establishing a thin film phase diagram. Highly textured YCo5±x thin films were stabilized with saturation magnetization of 517 emu/cm3 (0.517 MA/m), coercivity of 4 kOe (0.4 T), and anisotropy constant, K1, equal to 5.34 ×106 erg/cm3 (0.53 MJ/m3). These magnetic parameters and the perpendicular anisotropy obtained without additional underlayers make the material system interesting for application in magnetic recording devices.

On the generation of magnetosheath lion roars

NASA Technical Reports Server (NTRS)

Lee, L. C.; Wu, C. S.; Price, C. P.

1987-01-01

A theoretical model is proposed to discuss the electron dynamics associated with the mirror waves and their effects on the generation of the observed lion roars in the magnetosheath. It is pointed out that the usual double-adiabatic theory of hydromagnetics is not applicable to the electrons in mirror waves. Although the electron magnetic moment is conserved, the energy of each electron in the mirror waves is expected to be constant. Assuming an initial electron temperature anisotropy, it can be shown that in the low field region the electron temperature and thermal anisotropy are higher than the initial values, whereas in the high field region the electron temperature and anisotropy are lower. This point can lead to a theoretical explanation of the important features of the observed lion roars. Then present discussion complements the existing theories in the literature.

Interpretation of the cosmic microwave background radiation anisotropy detected by the COBE Differential Microwave Radiometer

NASA Technical Reports Server (NTRS)

Wright, E. L.; Meyer, S. S.; Bennett, C. L.; Boggess, N. W.; Cheng, E. S.; Hauser, M. G.; Kogut, A.; Lineweaver, C.; Mather, J. C.; Smoot, G. F.

1992-01-01

The large-scale cosmic background anisotropy detected by the COBE Differential Microwave Radiometer (DMR) instrument is compared to the sensitive previous measurements on various angular scales, and to the predictions of a wide variety of models of structure formation driven by gravitational instability. The observed anisotropy is consistent with all previously measured upper limits and with a number of dynamical models of structure formation. For example, the data agree with an unbiased cold dark matter (CDM) model with H0 = 50 km/s Mpc and Delta-M/M = 1 in a 16 Mpc radius sphere. Other models, such as CDM plus massive neutrinos (hot dark matter (HDM)), or CDM with a nonzero cosmological constant are also consistent with the COBE detection and can provide the extra power seen on 5-10,000 km/s scales.

Diffusion Monte Carlo method for evaluating Hamaker constants

NASA Astrophysics Data System (ADS)

Maezono, Ryo; Hongo, Kenta

We evaluated Hamaker's constants for Si6H12 (CHS) to investigate its wettability, which is industrially useful but no references available. The constant is fundamental for wettability, but not directly accessible by experiments. Ab initio estimations are therefore in demand, and surely give an impact for broader fields such as tribology where the wettability plays an important role. The evaluation of binding curves itself could be a big challenge if it is applied to a practical molecule such as CHS, because highly accurate descriptions of electron correlations in vdW bindings get tough for such larger sizes with anisotropy. We applied DMC to overcome this difficulty, showing a new direction for wettability issues. Since ab intio estimations rely on simple assumptions such as additivity (and hence we denote it as Aadd), it would include biases. Taking a benzene as a benchmark, we compared Aadd evaluated from several available binding curves with other reported AL (estimations based on Lifshitz theory). By the comparison, we get trends of biases in Aa dd due to non-additivity and anisotropy because AL is expected to capture these effects to some extent in macroscopic manner. The expected trends here surprisingly well explain the series of results for CHS.

Raman spectroscopic determination of the length, strength, compressibility, Debye temperature, elasticity, and force constant of the C-C bond in graphene.

PubMed

Yang, X X; Li, J W; Zhou, Z F; Wang, Y; Yang, L W; Zheng, W T; Sun, Chang Q

2012-01-21

From the perspective of bond relaxation and bond vibration, we have formulated the Raman phonon relaxation of graphene, under the stimuli of the number-of-layers, the uni-axial strain, the pressure, and the temperature, in terms of the response of the length and strength of the representative bond of the entire specimen to the applied stimuli. Theoretical unification of the measurements clarifies that: (i) the opposite trends of the Raman shifts, which are due to the number-of-layers reduction, of the G-peak shift and arises from the vibration of a pair of atoms, while the D- and the 2D-peak shifts involve the z-neighbor of a specific atom; (ii) the tensile strain-induced phonon softening and phonon-band splitting arise from the asymmetric response of the C(3v) bond geometry to the C(2v) uni-axial bond elongation; (iii) the thermal softening of the phonons originates from bond expansion and weakening; and (iv) the pressure stiffening of the phonons results from bond compression and work hardening. Reproduction of the measurements has led to quantitative information about the referential frequencies from which the Raman frequencies shift as well as the length, energy, force constant, Debye temperature, compressibility and elastic modulus of the C-C bond in graphene, which is of instrumental importance in the understanding of the unusual behavior of graphene.

Langmuir Films of Flexible Polymers Transferred to Aqueous/Liquid Crystal Interfaces Induce Uniform Azimuthal Alignment of the Liquid Crystal

PubMed Central

Kinsinger, Michael I.; Buck, Maren E.; Meli, Maria-Victoria; Abbott, Nicholas L.; Lynn, David M.

2009-01-01

We reported recently that amphiphilic polymers can be assembled at interfaces created between aqueous phases and thermotropic liquid crystals (LCs) in ways that (i) couple the organization of the polymer to the order of the LC and (ii) respond to changes in the properties of aqueous phases that can be characterized as changes in the optical appearance of the LC. This investigation sought to characterize the behavior of aqueous-LC interfaces decorated with uniaxially compressed thin films of polymers transferred by Langmuir-Schaefer (LS) transfer. Here, we report physicochemical characterization of interfaces created between aqueous phases and the thermotropic LC 4-cyano-4’-pentylbiphenyl (5CB) decorated with Langmuir films of a novel amphiphilic polymer (polymer 1), synthesized by the addition of hydrophobic and hydrophilic side chains to poly(2-vinyl-4,4’-dimethylazlactone). Initial characterization of this system resulted in the unexpected observation of uniform azimuthal alignment of 5CB after LS transfer of the polymer films to aqueous-5CB interfaces. This paper describes characterization of Langmuir films of polymer 1 hosted at aqueous-5CB interfaces as well as the results of our investigations into the origins of the uniform ordering of the LC observed upon LS transfer. Our results, when combined, support the conclusion that uniform azimuthal alignment of 5CB is the result of long-range ordering of polymer chains in the Langmuir films (in a preferred direction orthogonal to the direction of compression) that is generated during uniaxial compression of the films prior to LS transfer. Although past studies of Langmuir films of polymers at aqueous-air interfaces have demonstrated that in-plane alignment of polymer backbones can be induced by uniaxial compression, these past reports have generally made use of polymers with rigid backbones. One important outcome of this current study is thus the observation of anisotropy and long-range order in Langmuir films of a novel flexible polymer. A second important outcome is the observation that the existence, extent, and dynamics of this order can be identified and characterized optically by transfer of the Langmuir film to a thin film of LC. Additional characterization of Langmuir films of two other flexible polymers [poly(methyl methacrylate) and poly(vinyl stearate)] using this method also resulted in uniform azimuthal alignment of 5CB, suggesting that the generation of long-range order in uniaxially compressed Langmuir films of polymers may also occur more generally over a broader range of polymers with flexible backbones. PMID:19836025

AnisoVis: a MATLAB™ toolbox for the visualisation of elastic anisotropy

NASA Astrophysics Data System (ADS)

Healy, D.; Timms, N.; Pearce, M. A.

2016-12-01

The elastic properties of rocks and minerals vary with direction, and this has significant consequences for their physical response to acoustic waves and natural or imposed stresses. This anisotropy of elasticity is well described mathematically by 4th rank tensors of stiffness or compliance. These tensors are not easy to visualise in a single diagram or graphic, and visualising Poisson's ratio and shear modulus presents a further challenge in that their anisotropy depends on two principal directions. Students and researchers can easily underestimate the importance of elastic anisotropy. This presentation describes an open source toolbox of MATLAB scripts that aims to visualise elastic anisotropy in rocks and minerals. The code produces linked 2-D and 3-D representations of the standard elastic constants, such as Young's modulus, Poisson's ratio and shear modulus, all from a simple GUI. The 3-D plots can be manipulated by the user (rotated, panned, zoomed), to encourage investigation and a deeper understanding of directional variations in the fundamental properties. Examples are presented of common rock forming minerals, including those with negative Poisson's ratio (auxetic behaviour). We hope that an open source code base will encourage further enhancements from the rock physics and wider geoscience communities. Eventually, we hope to generate 3-D prints of these complex and beautiful natural surfaces to provide a tactile link to the underlying physics of elastic anisotropy.

Crystal preferred orientation of amphibole and implications for seismic anisotropy in the crust

NASA Astrophysics Data System (ADS)

Jung, Haemyeong

2016-04-01

Strong seismic anisotropy is often observed in the middle to lower crust and it has been considered to be originated from the crystal preferred orientation (CPO) of anisotropic minerals such as amphibole. Amphibolite is one of the dominant rocks in the middle to lower crust. In this study, crystal preferred orientations of hornblende in amphibolites at Yeoncheon and Chuncheon areas in South Korea were determined by using the electron backscattered diffraction (EBSD)/SEM with HKL Channel 5 software. In Yeoncheon area, hornblende showed two types of CPOs. Type-I CPO is characterized as (100) poles of hornblende aligned subnormal to foliation and [001] axes aligned subparallel to lineation. Type-II CPO is characterized as (100) poles of hornblende aligned subnormal to foliation and (010) poles aligned subparallel to lineation (refer to Ko and Jung, 2015, Nature Communications). In Chuncheon area, three types of CPOs of hornblende were observed. In addition to the type-I and -II CPOs described above, type-III CPO of hornblende was observed in Chuncheon area and it is characterized as (100) poles of hornblende aligned subnormal to foliation and both [001] axes and (010) poles aligned as a girdle subparallel to foliation. Using the observed CPO and the single crystal elastic constant of hornblende, seismic anisotropy of hornblende was calculated. Seismic anisotropy of P-wave was strong in the range of 10.2 - 13.5 %. Seismic anisotropy of S-wave was also strong in the range of 6.9 - 11.2 %. These results show that hornblende deformed in nature can produce a strong CPO, resulting in a strong seismic anisotropy in the middle to lower crust. Taking into account of the CPO of plagioclase in the rock, seismic anisotropies of whole rock turned out to be maximum P-wave anisotropy (Vp) of 9.8% and maximum S-wave anisotropy (Vs) of 8.2%. Therefore, strong seismic anisotropy found in the middle to lower crust in nature can be attributed to the CPO of hornblende in amphibolite.

Why do Hematite FORCs Look Weird?

NASA Astrophysics Data System (ADS)

Harrison, R. J.

2017-12-01

Although much progress has been made in the modelling of first-order reversal curve (FORC) diagrams for ensembles of interacting single domain (SD) magnetite particles with cubic and uniaxial anisotropy, a comprehensive understanding of FORC diagrams for magnetic minerals with other forms of anisotropy is currently lacking. For example, it has long been recognised that FORC diagrams for hematite display a range of unexplained features, including one or more of the following: 1) a kidney-shaped positive peak that is negatively offset from the horizontal axis; 2) a negative peak that sits below the offset positive peak; and 3) a negative-positive streak that extends at a steep negative angle to the horizontal axis. Here we demonstrate that many of the diagnostic features of hematite FORCs can be explained as an intrinsic consequence of hexagonal anisotropy operating within the basal plane. Simulations are performed for an ensemble of identical, randomly oriented, non-interacting SD particles, with easy axes located at 60° to each other within a basal plane. In the general case, there are six stable or metastable solutions for the magnetic state of a particle, with different critical fields for switching into and out of the corresponding hysteresis branch. Downward switching between branches at the reversal field is paired with either symmetrical or asymmetrical upward switching between branches at the measurement field. Paired switching events lead to both symmetrical (central ridge) and asymmetrical (negatively shifted) signals in the FORC diagram. A downward transition out of one branch means the corresponding upward transition from that branch is no longer accessible, leading to a negative contribution to the FORC distribution. At the same time, an upward transition from a different branch becomes newly accessible, leading to a paired positive contribution to the FORC distribution. Simulations of interacting SD particles with hexagonal anisotropy and a broad range of switching fields reproduce many of the features typically associated with hematite FORC diagrams, demonstrating that key features can largely be explained as an intrinsic effect caused by the availability of multiple hysteresis branches.

Correlations Between the Cosmic X-Ray and Microwave Backgrounds: Constraints on a Cosmological Constant

NASA Technical Reports Server (NTRS)

Boughn, S. P.; Crittenden, R. G.; Turok, N. G.

1998-01-01

In universes with significant curvature or cosmological constant, cosmic microwave background (CMB) anisotropies are created very recently via the Rees-Sciama or integrated Sachs-Wolfe effects. This causes the CMB anisotropies to become partially correlated with the local matter density (z less than 4). We examine the prospects of using the hard (2- 10 keV) X-ray background as a probe of the local density and the measured correlation between the HEAO1 A2 X-ray survey and the 4-year COBE-DMR map to obtain a constraint on the cosmological constant. The 95% confidence level upper limit on the cosmological constant is OMega(sub Lambda) less than or equal to 0.5, assuming that the observed fluctuations in the X-ray map result entirely from large scale structure. (This would also imply that the X-rays trace matter with a bias factor of b(sub x) approx. = 5.6 Omega(sub m, sup 0.53)). This bound is weakened considerably if a large portion of the X-ray fluctuations arise from Poisson noise from unresolved sources. For example, if one assumes that the X-ray bias is b(sub x) = 2, then the 95% confidence level upper limit is weaker, Omega(sub Lambda) less than or equal to 0.7. More stringent limits should be attainable with data from the next generation of CMB and X-ray background maps.

Bianchi Type-I Anisotropic Dark Energy Model with Constant Deceleration Parameter

NASA Astrophysics Data System (ADS)

Pradhan, Anirudh; Amirhashchi, H.; Saha, Bijan

2011-09-01

A new dark energy model in anisotropic Bianchi type-I (B-I) space-time with time dependent equation of state (EoS) parameter and constant deceleration parameter has been investigated in the present paper. The Einstein's field equations have been solved by applying a variation law for generalized Hubble's parameter (Berman in Il Nuovo Cimento B 74:182, 1983) which generates two types of solutions, one is of power-law type and other is of the exponential form. The existing range of the dark energy EoS parameter ω for derived model is found to be in good agreement with the three recent observations (i) SNe Ia data (Knop et al. in Astrophys. J. 598:102, 2003), (ii) SNe Ia data collaborated with CMBR anisotropy and galaxy clustering statistics (Tegmark et al. in Astrophys. J. 606:702, 2004) and (iii) a combination of cosmological datasets coming from CMB anisotropies, luminosity distances of high redshift type Ia supernovae and galaxy clustering (Hinshaw et al. in Astrophys. J. Suppl. Ser. 180:225, 2009 and Komatsu et al. in Astrophys. J. Suppl. Ser. 180:330, 2009). The cosmological constant Λ is found to be a decreasing function of time and it approaches a small positive value at the present epoch which is corroborated by results from recent supernovae Ia observations. It has also been suggested that the dark energy that explains the observed accelerating universe may arise due to the contribution to the vacuum energy of the EoS in a time dependent background. Geometric and kinematic properties of the model and the behaviour of the anisotropy of the dark energy have been carried out.

Dosimetric parameters of three new solid core I‐125 brachytherapy sources

PubMed Central

Solberg, Timothy D.; DeMarco, John J.; Hugo, Geoffrey; Wallace, Robert E.

2002-01-01

Monte Carlo calculations and TLD measurements have been performed for the purpose of characterizing dosimetric properties of new commercially available brachytherapy sources. All sources tested consisted of a solid core, upon which a thin layer of I125 has been adsorbed, encased within a titanium housing. The PharmaSeed BT‐125 source manufactured by Syncor is available in silver or palladium core configurations while the ADVANTAGE source from IsoAid has silver only. Dosimetric properties, including the dose rate constant, radial dose function, and anisotropy characteristics were determined according to the TG‐43 protocol. Additionally, the geometry function was calculated exactly using Monte Carlo and compared with both the point and line source approximations. The 1999 NIST standard was followed in determining air kerma strength. Dose rate constants were calculated to be 0.955±0.005,0.967±0.005, and 0.962±0.005 cGyh−1U−1 for the PharmaSeed BT‐125‐1, BT‐125‐2, and ADVANTAGE sources, respectively. TLD measurements were in excellent agreement with Monte Carlo calculations. Radial dose function, g(r), calculated to a distance of 10 cm, and anisotropy function F(r, θ), calculated for radii from 0.5 to 7.0 cm, were similar among all source configurations. Anisotropy constants, ϕ¯an, were calculated to be 0.941, 0.944, and 0.960 for the three sources, respectively. All dosimetric parameters were found to be in close agreement with previously published data for similar source configurations. The MCNP Monte Carlo code appears to be ideally suited to low energy dosimetry applications. PACS number(s): 87.53.–j PMID:11958652

Dielectric Anistropy, Elastic Constants, and Threshold Voltage Measurements of Gold-nanoparticle Colloids in Nematic 5CB

NASA Astrophysics Data System (ADS)

Visco, Angelo; Foust, Jon; Belobradich, Joseph; Mahmood, Rizwan; Zapien, Donald

We have explored electro-optical and thermal properties of gold nanoparticles (GNPs) colloids in 4-cyano- 4'-pentylbiphenyl (5CB) liquid crystals (LCs). GNP's do not readily disperse in a LC host and, so, have been treated with either, 1-Hexane-thiol, 1-Dodecane-thiol, or 1-Octadecyl-thiol. This treatment suppresses the aggregation of GNPs within the 5CB host to a threshold of approximately 0.7% GNP by weight. Our measurements on dodecanethiol and hexanethiol treated GNPs showed an unusual, steep trough in the dielectric anisotropy and elastic constants at a critical concentration of 0.0862 wt. % GNPs in 5CB. Due to the order parameter, we have observed a peak in the transition temperature at the same critical concentration. Above the critical concentration the transition temperatures, dielectric anisotropy, and elastic constants level off to within experimental uncertainty. Measurements of dodecanethiol treated GNPs in 5CB reveal distinctions in the rate of change in dielectric anisotropy as compared to hexanethiol treated GNPs in 5CB. This effect is possibly due to the increased carbon concentration in dodeccanethiol compared to hexanethiol. Attempts to mix the Smectic A (SmA), 8CB liquid crystal using our hexanethiol and dodecanethiol GNPs were unsuccessful for particle sizes of 100nm and 28nm. We suspect that this is due to an insufficient length of the carbon-chain and U.V. spectroscopy measurements may prove useful in characterizing the resulting aggregation. We hope the system will be helpful in modifying the properties of mesophases that may ultimately results in developing new electro-optical devices. Acknowledgements: The funding for the project was provided by Slippery Rock University (2015-2016).

Compositional dependence of magnetic anisotropy in chemically synthesized Co3- x Fe x O4 (0 ≤ x ≤ 2)

NASA Astrophysics Data System (ADS)

Hayashi, Kensuke; Yamada, Keisuke; Shima, Mutsuhiro

2018-01-01

Magnetic anisotropy of Co3- x Fe x O4 (CFO, 0 ≤ x ≤ 2) thin-film and powder samples prepared by a sol-gel method has been investigated as a function of Fe composition x. Structural analyses by X-ray diffraction show that CFO powder samples exhibit diffraction peaks associated with the spinel structure when x < 2, while CFO thin-film samples with thickness of 130-510 nm yield the peaks when 0 ≤ x ≤ 2. CFO thin-film samples are highly (111)-oriented with the Lotgering factor greater than 0.9 when 0.6 ≤ x ≤ 1.3. The magnetic anisotropy constant K 1 of CFO powder samples estimated from their room-temperature hysteresis loops yields a minimum when x = 0.9. Relatively large in-plane magnetic anisotropy (K eff = 5.7 × 105 erg/cm3) is observed for the CFO thin-film sample when x = 1.3. With increasing x, the magnetic easy axis of the spinel CFO changes from 〈111〉 to 〈100〉 when x = 0.9.

Nanofiber-structured hydrogel yarns with pH-response capacity and cardiomyocyte-drivability for bio-microactuator application.

PubMed

Wu, Shaohua; Duan, Bin; Qin, Xiaohong; Butcher, Jonathan T

2017-09-15

Polymeric hydrogels have great potential in soft biological micro-actuator applications. However, inappropriate micro-architecture, non-anisotropy, weak biomechanics, and inferior response behaviors limit their development. In this study, we designed and manufactured novel polyacrylonitrile (PAN)-based hydrogel yarns composed with uniaxially aligned nanofibers. The nanofibrous hydrogel yarns possessed anisotropic architecture and robust mechanical properties with flexibility, and could be assembled into defined scaffold structures by subsequent processes. The as-prepared hydrogel yarns showed excellent pH response behaviors, with around 100% maximum length and 900% maximum diameter changes, and the pH response was completed within several seconds. Moreover, the hydrogel yarns displayed unique cell-responsive abilities to promote the cell adhesion, proliferation, and smooth muscle differentiation of human adipose derived mesenchymal stem cells (HADMSC). Chicken cardiomyocytes were further seeded onto our nanofibrous hydrogel yarns to engineer living cell-based microactuators. Our results demonstrated that the uniaxially aligned nanofibrous networks within the hydrogel yarns were the key characteristics leading to the anisotropic organization of cardiac cells, and improved sarcomere organization, mimicking the cardiomyocyte bundles in the native myocardium. The construct is capable of sustaining spontaneous cardiomyocyte pumping behaviors for 7days. Our PAN-based nanofibrous hydrogel yarns are attractive for creating linear microactuators with pH-response capacity and biological microactuators with cardiomyocyte-drivability. A mechanically robust polyacrylonitrile-based nanofibrous hydrogel yarn is fabricated by using a modified electrospinning setup in combination with chemical modification processes. The as-prepared hydrogel yarn possesses a uniaxially aligned nanofiber microarchitecture and supports a rapid, pH-dependent expansion/contraction response within a few seconds. Embryonic cardiomyocytes-seeded hydrogel yarn improves the sarcomere organization and mimics the cardiomyocyte bundles in the native myocardium, which sustains spontaneous cardiomyocyte pumping behaviors. The nanofibrous hydrogel yarn has several advantages over traditional bulk hydrogel scaffolds in terms of robust biomechanics, anisotropic aligned architecture, and superior pH response behaviors. Our nanofibrous hydrogel yarn holds the potential to be developed into novel linear and biological microactuators for various biomedical applications. Copyright © 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Phonon dispersion evolution in uniaxially strained aluminum crystal

NASA Astrophysics Data System (ADS)

Parthasarathy, Ranganathan; Misra, Anil; Aryal, Sitaram; Ouyang, Lizhi

2018-04-01

The influence of loading upon the phonon dispersion of crystalline materials could be highly nonlinear with certain particular trends that depend upon the loading path. In this paper, we have calculated the influence of [100] uniaxial strain on the phonon dispersion and group velocities in fcc aluminum using second moments of position obtained from molecular dynamics (MD) simulation at 300 K. In contrast to nonlinear monotonic variation of both longitudinal and transverse phonon frequencies along the Δ , Λ and Σ lines of the first Brillouin zone under tension, transverse phonon branches along the Λ line show inflection at specific wavevectors when the compressive strain exceeds 5%. Further, the longitudinal group velocities along the high-symmetry Δ line vary non-monotonically with strain, reaching a minimum at 5% compressive strain. Throughout the strain range studied, the equilibrium positions of atoms displace in an affine manner preserving certain static structural symmetry. We attribute the anomalies in the phonon dispersion to the non-affine evolution of second moments of atomic position, and the associated plateauing of force constants under the applied strain path.

DOE Office of Scientific and Technical Information (OSTI.GOV)

El-Gendy, AA; Bertino, M; Clifford, D

Attainment of magnetic order in nanoparticles at room temperature is an issue of critical importance for many different technologies. For ordinary ferromagnetic materials, a reduction in size leads to decreased magnetic anisotropy and results in superparamagnetic relaxations. If, instead, anisotropy could be enhanced at reduced particle sizes, then it would be possible to attain stable magnetic order at room temperature. Herein, we provide experimental evidence substantiating the synthesis of a cobalt iron carbide phase (CoFe2C) of nanoparticles. Structural characterization of the CoFe2C carbide phase was performed by transmission electron microscopy, electron diffraction and energy electron spectroscopy. X-ray diffraction was alsomore » performed as a complimentary analysis. Magnetic characterization of the carbide phase revealed a blocking temperature, TB, of 790K for particles with a domain size as small as 5 +/- 1 nm. The particles have magnetocrystalline anisotropy of 4.662 +/- 10 6 J/m(3), which is ten times larger than that of Co nanoparticles. Such colossal anisotropy leads to thermally stable long range magnetic order. Moreover, the thermal stability constant is much larger than that of the commonly used FePt nanoparticles. With thermal stability and colossal anisotropy, the CoFe2C nanoparticles have huge potential for enhanced magnetic data storage devices. (C) 2015 AIP Publishing LLC.« less

Textures of eclogites and blueschists from Syros island, Greece: Inferences for elastic anisotropy of subducted oceanic crust

NASA Astrophysics Data System (ADS)

Keppler, Ruth; Behrmann, Jan H.; Stipp, Michael

2017-07-01

Many blueschists and eclogites are inferred to have formed from oceanic basalts in subducted slabs. Knowledge of their elastic behavior is essential for reconstructing the internal structure of subduction zones. The Cycladic blueschist unit, exposed on Syros Island (Greece), contains rocks belonging to an exhumed Tertiary subduction complex. They were possibly part of a subduction channel, a shear zone above the subducting slab in which exhumation is possible during subduction. Intense plastic deformation, forming crystallographic preferred orientations (CPO), accompanied blueschist and eclogite metamorphism. CPO of the constituent minerals in the collected samples was determined by time-of-flight neutron diffraction. Two samples are foliated fine-grained blueschists with strong CPO, rich in glaucophane, zoisite, and phengite. Two coarser-grained eclogite samples rich in omphacite and clinozoisite, or glaucophane, have weaker CPO. Vp and Vs anisotropies were computed from the orientation distribution function and single-crystal elastic constants. All samples show velocity maxima parallel to the mineral lineation, and minima normal to the foliation, providing important constraints on orientations of seismic anisotropy in subduction channels. Vp anisotropies are up to 3 times higher (6.5-12%) in the blueschists than in the eclogites (3-4%), pointing to a potentially important lithological control of elastic anisotropy in subducted oceanic crust.

Seismic anisotropy from compositional banding in granulites from the deep magmatic arc of Fiordland, New Zealand

NASA Astrophysics Data System (ADS)

Cyprych, Daria; Piazolo, Sandra; Almqvist, Bjarne S. G.

2017-11-01

We present calculated seismic velocities and anisotropies of mafic granulites and eclogites from the Cretaceous deep lower crust (∼40-65 km) of Fiordland, New Zealand. Both rock types show a distinct foliation defined by cm-scale compositional banding. Seismic properties are estimated using the Asymptotic Expansion Homogenisation - Finite Element (AEH-FE) method that, unlike the commonly used Voigt-Reuss-Hill homogenisation, incorporates the phase boundary network into calculations. The predicted mean P- and S-wave velocities are consistent with previously published data for similar lithologies from other locations (e.g., Kohistan Arc), although we find higher than expected anisotropies (AVP ∼ 5.0-8.0%, AVS ∼ 3.0-6.5%) and substantial S-wave splitting along foliation planes in granulites. This seismic signature of granulites results from a density and elasticity contrast between cm-scale pyroxene ± garnet stringers and plagioclase matrix rather than from crystallographic orientations alone. Banded eclogites do not show elevated anisotropies as the contrast in density and elastic constants of garnet and pyroxene is too small. The origin of compositional banding in Fiordland granulites is primarily magmatic and structures described here are expected to be typical for the base of present day magmatic arcs. Hence, we identify a new potential source of anisotropy within this geotectonic setting.

Seismic Anisotropy from Surface Refraction Measurements

NASA Astrophysics Data System (ADS)

Vilhelm, J.; Hrdá, J.; Klíma, K.; Lokajícek, T.; Pros, Z.

2003-04-01

The contribution deals with the methods of determining P and S wave velocities in the shallow refraction seismics. The comparison of a P-wave anisotropy from samples and field surface measurement is performed. The laboratory measurement of the P-wave velocity is realized as omni directional ultrasound measurement on oriented spherical samples (diameter 5 cm) under a hydrostatic pressure up to 400 MPa. The field measurement is based on the processing of at least one pair of reversed time-distance curves of refracted waves. Different velocity calculation techniques are involved including tomographic approach from the surface. It is shown that field seismic measurement can reflect internal rock fabric (lineation, mineral anisotropy) as well as effects connected with the fracturing and weathering. The elastic constants derived from laboratory measurements exhibit transversal isotropy. For the estimation of anisotropy influence we perform ray-tracing by the software package ANRAY (Consortium Seismic Waves in Complex 3-D Structures). The use of P and S wave anisotropy measurement to determine hard rock hydro-geological collector (water resource) is presented. In a relatively homogeneous lutaceous sedimentary medium we identified a transversally isotropic layer which exhibits increased value of permeability (transmisivity). The seismic measurement is realized by three component geophones with both vertical and shear seismic sources. VLF and resistivity profiling accompany the filed survey.

Will COBE challenge the inflationary paradigm - Cosmic microwave background anisotropies versus large-scale streaming motions revisited

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gorski, K.M.

1991-03-01

The relation between cosmic microwave background (CMB) anisotropies and large-scale galaxy streaming motions is examined within the framework of inflationary cosmology. The minimal Sachs and Wolfe (1967) CMB anisotropies at large angular scales in the models with initial Harrison-Zel'dovich spectrum of inhomogeneity normalized to the local large-scale bulk flow, which are independent of the Hubble constant and specific nature of dark matter, are found to be within the anticipated ultimate sensitivity limits of COBE's Differential Microwave Radiometer experiment. For example, the most likely value of the quadrupole coefficient is predicted to be a2 not less than 7 x 10 tomore » the -6th, where equality applies to the limiting minimal model. If (1) COBE's DMR instruments perform well throughout the two-year period; (2) the anisotropy data are not marred by the systematic errors; (3) the large-scale motions retain their present observational status; (4) there is no statistical conspiracy in a sense of the measured bulk flow being of untypically high and the large-scale anisotropy of untypically low amplitudes; and (5) the low-order multipoles in the all-sky primordial fireball temperature map are not detected, the inflationary paradigm will have to be questioned. 19 refs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weiser, Philip; Qin, Ying; Yin, Weikai

Uniaxial stress experiments performed for the 3306 cm -1 vibrational line assigned to the interstitial-hydrogen, shallow-donor center in In 2O 3 reveal its symmetry and transition- moment direction. The defect alignment that can be produced by a [001] stress applied at 165 K is due to a process that is also a hydrogen- diffusion jump, providing a microscopic determination of the diffusion constant for H in In 2O 3 and its mechanism. Lastly, our experimental results strongly complement theoretical predictions for the structure and diffusion of the interstitial hydrogen donor center in In 2O 3.

Effects of biaxial strains on electronic and elastic properties of hexagonal XSi2 (X = Cr, Mo, W) from first-principles

NASA Astrophysics Data System (ADS)

Zhu, Haiyan; Shi, Liwei; Li, Shuaiqi; Zhang, Shaobo; Xia, Wangsuo

2018-02-01

Structural, electronic properties and elastic anisotropy of hexagonal C40 XSi2 (X = Cr, Mo, W) under equibiaxial in-plane strains are systematically studied using first-principle calculations. The energy gaps show significant changes with biaxial strains, whereas they are always indirect band-gap materials for -6% <ɛxx < 6%. All elastic constants, bulk modulus, shear modulus, Young's modulus increase (decrease) almost linearly with increasing compressive (tensile) strains. The evolutions of BH /GH ratio and Poisson's ratio indicate that these compounds have a better (worse) ductile behaviour under compressive (tensile) strains. A set of 3D plots show a larger directional variability in the Young's modulus E and shear modulus G at different strains for the three compounds, which is consist with the values of anisotropy factors. Moreover, the evolution of Debye temperature and anisotropy of sound velocities with biaxial strains are discussed.

On the generation of magnetosheath lion roars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, L.C.; Wu, C.S.; Price, C.P.

1987-03-01

A theoretical model is proposed to discuss the electron dynamics associated with the mirror waves and their effects on the generation of the observed lion roars in the magnetosheath. It is pointed out that the usual double-adiabatic theory of hydromagnetics is not applicable to the electrons in mirror waves. Although the electron magnetic moment is conserved, the energy of each electron in the mirror waves is expected to be constant (because of the high electron speed along the magnetic field). Assuming an initial electron temperature anisotropy, the authors can show that in the low field region the electron temperature andmore » thermal anisotropy are higher than the initial values, whereas in the high field region the electron temperature and anisotropy are lower. This point can lead to a theoretical explanation of the important features of the observed lion roars. The present discussion complements the existing theories in the literature.« less

Optical anisotropy of the human cornea determined with a polarizing microscope.

PubMed

Bone, Richard A; Draper, Grenville

2007-12-01

We have investigated the optical anisotropy of the human cornea using a polarizing microscope normally used for optical mineralogy studies. The central part of the cornea was removed from 14 eyes (seven donors). With the sample placed on the microscope stage, we consistently observed hyperbolic isogyres characteristic of a negative biaxial material. The angle between the optic axes, generally similar in both eyes, ranged from 12 degrees to 40 degrees (mean+/-SD=31 degrees +/-8 degrees ). The optic axial plane always inclined downward in the nasal direction at 1 degrees -45 degrees below the horizontal (mean+/-SD=22+/-13 degrees ). The retardance produced by the corneas was estimated to be less than 200 nm. In conclusion, the human cornea possesses the anisotropy of a negative biaxial material. Both the angle between the optic axes and the retardance were fairly constant among the majority of samples, suggestive of uniformity in corneal structure.

Cosmic background radiation anisotropies in universes dominated by nonbaryonic dark matter

NASA Technical Reports Server (NTRS)

Bond, J. R.; Efstathiou, G.

1984-01-01

Detailed calculations of the temperature fluctuations in the cosmic background radiation for universes dominated by massive collisionless relics of the big bang are presented. An initially adiabatic constant curvature perturbation spectrum is assumed. In models with cold dark matter, the simplest hypothesis - that galaxies follow the mass distribution leads to small-scale anisotropies which exceed current observational limits if omega is less than 0.2 h to the -4/3. Since low values of omega are indicated by dynamical studies of galaxy clustering, cold particle models in which light traces mass are probably incorrect. Reheating of the pregalactic medium is unlikely to modify this conclusion. In cold particle or neutrino-dominated universes with omega = 1, presented predictions for small-scale and quadrupole anisotropies are below current limits. In all cases, the small-scale fluctuations are predicted to be about 10 percent linearly polarized.

Effects of iron deficiency on anisotropy and ferromagnetic resonance linewidth in Bi-doped LiZn ferrite

NASA Astrophysics Data System (ADS)

Jiang, Xiaona; Wang, Wei; Yu, Zhong; Sun, Ke; Lan, Zhongwen; Zhang, Xinran; Harris, Vincent G.

2017-05-01

Bi-doped LiZn ferrites with different iron deficiencies were fabricated by a conventional ceramic method. Anisotropy constant (K1) was calculated and ferromagnetic resonance (FMR) linewidth (ΔH) was investigated. Crystalline anisotropy broadening linewidth (ΔHa) and porosity broadening linewidth (ΔHp) were derived by an approximate calculation based on dipolar narrowing theory, which play a significant role in contributions to FMR linewidth and occupy more than 90 % of ΔH. Physical and static magnetic properties of LiZn ferrite with iron deficiency are presented, which supports a decline in linewidths with increasing iron deficiency. Iron deficiency makes K1, ΔHa and ΔHp reduce. The results also show that ΔHp is the majority of contributions to ΔH in Bi-doped LiZn ferrite and densification is an effective method to decrease ΔH.