Spherical shells buckling to the sound of music

NASA Astrophysics Data System (ADS)

Lee, Anna; Marthelot, Joel; Reis, Pedro

We study how the critical buckling load of spherical elastic shells can be modified by a fluctuating external pressure field. In our experiments, we employ thin elastomeric shells of nearly uniform thickness fabricated by the coating of a hemispherical mold with a polymer solution, which upon curing yields elastic structures. A shell is submerged in a water bath and loaded quasi-statically until buckling occurs by reducing its inner volume with a syringe pump. Simultaneously, a plunger connected to an electromagnetic shaker is placed above the shell and driven sinusoidally to create a fluctuating external pressure field that can excite dynamic vibration modes of the shell. These dynamic modes induce effective compressive stresses, in addition to those from the inner pressure loading, which can modify the critical conditions for the onset of buckling. We systematically quantify how the frequency and amplitude of the external driving affects the buckling strength of our shells. In specific regions of the parameter space, we find that pressure fluctuations can result in large reductions of the critical buckling pressure. This is analogous to the classic knock-down effect in shells due to intrinsic geometric imperfections, albeit now in a way that can be controlled externally.

Defect Implosion Experiments (DIME) at OMEGA

NASA Astrophysics Data System (ADS)

Cobble, J. A.; Schmitt, M. J.; Tregillis, I. L.; Obrey, K. D.; Magelssen, G. R.; Wilke, M. D.; Glebov, V.; Marshall, F. J.; Kim, Y. H.; Bradley, P. A.; Batha, S. H.

2010-11-01

The Los Alamos DIME campaign involves perturbed spherical implosions, driven by 60 OMEGA beams with uniform, symmetrical illumination. D-T-filled CH-shell targets with equatorial-plane defects are designed to produce a non-spherical neutron burn region. The objectives of the DIME series are to observe the non-spherical burn with the neutron imaging system (NIS) and to simulate the physics of the neutron and x-ray production. We have demonstrated adequate neutron yield for NIS imaging with targets of diameter 860 μm. All targets are filled with 5 atm of DT. We used two separate shell thicknesses: 8 μm and 15 μm, thus testing both exploding pusher and ablative designs. Defect channel depth ranges from 0 -- 8 μm. Width is 20 -- 40 μm. Perfect targets have no defect. Numerical simulations predict enhanced x-ray emission, that is suggested by experiment. Results from a recent DIME campaign will be discussed.

Invisible magnetic sensors

NASA Astrophysics Data System (ADS)

Mach-Batlle, Rosa; Navau, Carles; Sanchez, Alvaro

2018-04-01

Sensing magnetic fields is essential in many applications in biomedicine, transportation, or smart cities. The distortion magnetic sensors create in response to the field they are detecting may hinder their use, for example, in applications requiring dense packaging of sensors or accurately shaped field distributions. For sensing electromagnetic waves, cloaking shells that reduce the scattering of sensors have been introduced. However, the problem of making a magnetic sensor undetectable remains unsolved. Here, we present a general strategy on how to make a sensor magnetically invisible while keeping its ability to sense. The sensor is rendered undetectable by surrounding it with a spherical shell having a tailored magnetic permeability. Our method can be applied to arbitrary shaped magnetic sensors in arbitrary magnetic fields. The invisibility can be made exact when the sensor is spherical and the probed field is uniform. A metasurface composed of superconducting pieces is presented as a practical realization of the ideal invisibility shell.

The jump-off velocity of an impulsively loaded spherical shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chabaud, Brandon M.; Brock, Jerry S.

2012-04-13

We consider a constant temperature spherical shell of isotropic, homogeneous, linearly elastic material with density {rho} and Lame coefficients {lambda} and {mu}. The inner and outer radii of the shell are r{sub i} and r{sub o}, respectively. We assume that the inside of the shell is a void. On the outside of the shell, we apply a uniform, time-varying pressure p(t). We also assume that the shell is initially at rest. We want to compute the jump-off time and velocity of the pressure wave, which are the first time after t = 0 at which the pressure wave from themore » outer surface reaches the inner surface. This analysis computes the jump-off velocity and time for both compressible and incompressible materials. This differs substantially from [3], where only incompressible materials are considered. We will consider the behavior of an impulsively loaded, exponentially decaying pressure wave p(t) = P{sub 0{sup e}}{sup -{alpha}t}, where {alpha} {ge} 0. We notice that a constant pressure wave P(t) = P{sub 0} is a special case ({alpha} = 0) of a decaying pressure wave. Both of these boundary conditions are considered in [3].« less

Cracking the chocolate egg problem: polymeric films coated on curved substrates

NASA Astrophysics Data System (ADS)

Brun, Pierre-Thomas; Lee, Anna; Marthelot, Joel; Balestra, Gioele; Gallaire, François; Reis, Pedro

2015-11-01

Inspired by the traditional chocolate egg recipe, we show that pouring a polymeric solution onto spherical molds yields a simple and robust path of fabrication of thin elastic curved shells. The drainage dynamics naturally leads to uniform coatings frozen in time as the polymer cures, which are subsequently peeled off their mold. We show how the polymer curing affects the drainage dynamics and eventually selects the shell thickness and sets its uniformity. To this end, we perform coating experiments using silicon based elastomers, Vinylpolysiloxane (VPS) and Polydimethylsiloxane (PDMS). These results are rationalized combining numerical simulations of the lubrication flow field to a theoretical model of the dynamics yielding an analytical prediction of the formed shell characteristics. In particular, the robustness of the coating technique and its flexibility, two critical features for providing a generic framework for future studies, are shown to be an inherent consequence of the flow field (memory loss). The shell structure is both independent of initial conditions and tailorable by changing a single experimental parameter.

Tearing of thin spherical shells adhered to equally curved rigid substrates

NASA Astrophysics Data System (ADS)

McMahan, Connor; Lee, Anna; Marthelot, Joel; Reis, Pedro

Lasik (Laser-Assisted in Situ Keratomileusis) eye surgery involves the tearing of the corneal epithelium to remodel the corneal stroma for corrections such as myopia, hyperopia and astigmatism. One issue with this procedure is that during the tearing of the corneal epithelium, if the two propagating cracks coalesce, a flap detaches which could cause significant complications in the recovery of the patient. We seek to gain a predictive physical understanding of this process by performing precision desktop experiments on an analogue model system. First, thin spherical shells of nearly uniform thickness are fabricated by the coating of hemispherical molds with a polymer solution, which upon curing yields an elastic and brittle structure. We then create two notches near the equator of the shell and tear a flap by pulling tangentially to the spherical substrate, towards its pole. The resulting fracture paths are characterized by high-resolution 3D digital scanning. Our primary focus is on establishing how the positive Gaussian curvature of the system affects the path of the crack tip. Our results are directly contrasted against previous studies on systems with zero Gaussian curvature, where films were torn from planar and cylindrical substrates.

Design of efficient stiffened shells of revolution

NASA Technical Reports Server (NTRS)

Majumder, D. K.; Thornton, W. A.

1976-01-01

A method to produce efficient piecewise uniform stiffened shells of revolution is presented. The approach uses a first order differential equation formulation for the shell prebuckling and buckling analyses and the necessary conditions for an optimum design are derived by a variational approach. A variety of local yielding and buckling constraints and the general buckling constraint are included in the design process. The local constraints are treated by means of an interior penalty function and the general buckling load is treated by means of an exterior penalty function. This allows the general buckling constraint to be included in the design process only when it is violated. The self-adjoint nature of the prebuckling and buckling formulations is used to reduce the computational effort. Results for four conical shells and one spherical shell are given.

Synthesis, characterization and evaluation of uniformly sized core-shell imprinted microspheres for the separation trans-resveratrol from giant knotweed

NASA Astrophysics Data System (ADS)

Zhang, Zhaohui; Liu, Li; Li, Hui; Yao, Shouzhuo

2009-09-01

A novel core-shell molecularly imprinting microspheres (MIMs) with trans-resveratrol as the template molecule; acrylamide (AA) as functional monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker, was prepared based on SiO 2 microspheres with surface imprinting technique. These core-shell trans-resveratrol imprinted microspheres were characterized by infrared spectra (IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and high performance liquid chromatography (HPLC). The results showed that these core-shell imprinted microspheres, which take on perfect spherical shape with average shell thickness of 150 nm, exhibit especially selective recognition for trans-resveratrol. These imprinted microspheres were applied as solid-phase extraction materials for selective extraction of trans-resveratrol from giant knotweed extracting solution successfully.

Fluidized bed calciner apparatus

DOEpatents

Owen, Thomas J.; Klem, Jr., Michael J.; Cash, Robert J.

1988-01-01

An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

Core-shell monodisperse spherical mSiO2/Gd2O3:Eu3+@mSiO2 particles as potential multifunctional theranostic agents

NASA Astrophysics Data System (ADS)

Eurov, Daniil A.; Kurdyukov, Dmitry A.; Kirilenko, Demid A.; Kukushkina, Julia A.; Nashchekin, Alexei V.; Smirnov, Alexander N.; Golubev, Valery G.

2015-02-01

Core-shell nanoparticles with diameters in the range 100-500 nm have been synthesized as monodisperse spherical mesoporous (pore diameter 3 nm) silica particles with size deviation of less than 4 %, filled with gadolinium and europium oxides and coated with a mesoporous silica shell. It is shown that the melt technique developed for filling with gadolinium and europium oxides provides a nearly maximum filling of mesopores in a single-run impregnation, with gadolinium and europium uniformly distributed within the particles and forming no bulk oxides on their surface. The coating with a shell does not impair the monodispersity and causes no coagulation. The coating technique enables controlled variation of the shell thickness within the range 5-100 % relative to the core diameter. The thus produced nanoparticles are easily dispersed in water, have large specific surface area (300 m2 g-1) and pore volume (0.3 cm3 g-1), and are bright solid phosphor with superior stability in aqueous media. The core-shell structured particles can be potentially used for cancer treatment as a therapeutic agent (gadolinium neutron-capture therapy and drug delivery system) and, simultaneously, as a multimodal diagnostic tool (fluorescence and magnetic resonance imaging), thereby serving as a multifunctional theranostic agent.

Penetration of steady fluid motions into an outer stable layer excited by MHD thermal convection in rotating spherical shells

NASA Astrophysics Data System (ADS)

Takehiro, Shin-ichi; Sasaki, Youhei

2018-03-01

Penetration of steady magneto-hydrodynamic (MHD) disturbances into an upper strongly stratified stable layer excited by MHD thermal convection in rotating spherical shells is investigated. The theoretical model proposed by Takehiro (2015) is reexamined in the case of steady fluid motion below the bottom boundary. Steady disturbances penetrate into a density stratified MHD fluid existing in the semi-infinite region in the vertical direction. The axis of rotation of the system is tilted with respect to the vertical. The basic magnetic field is uniform and may be tilted with respect to the vertical and the rotation axis. Linear dispersion relation shows that the penetration distance with zero frequency depends on the amplitude of Alfvén wave speed. When Alfvén wave speed is small, viscous diffusion becomes dominant and penetration distance is similar to the horizontal scale of the disturbance at the lower boundary. In contrast, when Alfvén wave speed becomes larger, disturbance can penetrate deeper, and penetration distance becomes proportional to the Alfvén wave speed and inversely proportional to the geometric average of viscous and magnetic diffusion coefficients and to the total horizontal wavenumber. The analytic expression of penetration distance is in good agreement with the extent of penetration of mean zonal flow induced by finite amplitude convection in a rotating spherical shell with an upper stably stratified layer embedded in an axially uniform basic magnetic field. The theory expects that the stable layer suggested in the upper part of the outer core of the earth could be penetrated completely by mean zonal flows excited by thermal/compositional convection developing below the stable layer.

Computer Simulation of Magnetic Nova Shell Expantion

NASA Astrophysics Data System (ADS)

Dudnikova, Galina; Nikitin, Sergei; Snytnikov, Valeri; Vshivkov, Vitali

2000-10-01

An asymmetrical character of the shell expantion observed at many Nova may be associated with infuence of an inherent star magnetic field. Magneto-dipole energy of a Nova is much less than a kinetic energy of an exploding envelope. By this reason the conventional hydrodynamic models of point-like explosion with a spherical outward-directed shock wave do not consider effect of star magnetic field on the plasma movement. We used the numerical model based on the system of equations of the hybrid type( MHD approximation for electrons and Vlasov kinetic equations for ions). PIC-method for solving Vlasov equations was used. It gives an opportunaty to consider a complicated multi-flow motion of particles in plasma at super-Alfven velocity. At the beginning there is an immobile (cold) background plasma of a homogeneous concentration in a cylindrical region with a dipole magnetic field. Into the central spherical region of radius R, where the magnetic field remains uniform and constant , the external plasma does not penetrate with elastic reflections of ions at the spherical core surface. This boundary is spaced at r<

Effects of radial distribution of entropy diffusivity on critical modes of anelastic thermal convection in rotating spherical shells

NASA Astrophysics Data System (ADS)

Sasaki, Youhei; Takehiro, Shin-ichi; Ishiwatari, Masaki; Yamada, Michio

2018-03-01

Linear stability analysis of anelastic thermal convection in a rotating spherical shell with entropy diffusivities varying in the radial direction is performed. The structures of critical convection are obtained in the cases of four different radial distributions of entropy diffusivity; (1) κ is constant, (2) κT0 is constant, (3) κρ0 is constant, and (4) κρ0T0 is constant, where κ is the entropy diffusivity, T0 is the temperature of basic state, and ρ0 is the density of basic state, respectively. The ratio of inner and outer radii, the Prandtl number, the polytropic index, and the density ratio are 0.35, 1, 2, and 5, respectively. The value of the Ekman number is 10-3 or 10-5 . In the case of (1), where the setup is same as that of the anelastic dynamo benchmark (Jones et al., 2011), the structure of critical convection is concentrated near the outer boundary of the spherical shell around the equator. However, in the cases of (2), (3) and (4), the convection columns attach the inner boundary of the spherical shell. A rapidly rotating annulus model for anelastic systems is developed by assuming that convection structure is uniform in the axial direction taking into account the strong effect of Coriolis force. The annulus model well explains the characteristics of critical convection obtained numerically, such as critical azimuthal wavenumber, frequency, Rayleigh number, and the cylindrically radial location of convection columns. The radial distribution of entropy diffusivity, or more generally, diffusion properties in the entropy equation, is important for convection structure, because it determines the distribution of radial basic entropy gradient which is crucial for location of convection columns.

Imperfection sensitivity of pressured buckling of biopolymer spherical shells

NASA Astrophysics Data System (ADS)

Zhang, Lei; Ru, C. Q.

2016-06-01

Imperfection sensitivity is essential for mechanical behavior of biopolymer shells [such as ultrasound contrast agents (UCAs) and spherical viruses] characterized by high geometric heterogeneity. In this work, an imperfection sensitivity analysis is conducted based on a refined shell model recently developed for spherical biopolymer shells of high structural heterogeneity and thickness nonuniformity. The influence of related parameters (including the ratio of radius to average shell thickness, the ratio of transverse shear modulus to in-plane shear modulus, and the ratio of effective bending thickness to average shell thickness) on imperfection sensitivity is examined for pressured buckling. Our results show that the ratio of effective bending thickness to average shell thickness has a major effect on the imperfection sensitivity, while the effect of the ratio of transverse shear modulus to in-plane shear modulus is usually negligible. For example, with physically realistic parameters for typical imperfect spherical biopolymer shells, the present model predicts that actual maximum external pressure could be reduced to as low as 60% of that of a perfect UCA spherical shell or 55%-65% of that of a perfect spherical virus shell, respectively. The moderate imperfection sensitivity of spherical biopolymer shells with physically realistic imperfection is largely attributed to the fact that biopolymer shells are relatively thicker (defined by smaller radius-to-thickness ratio) and therefore practically realistic imperfection amplitude normalized by thickness is very small as compared to that of classical elastic thin shells which have much larger radius-to-thickness ratio.

Isochoric Implosions for Fast Ignition

NASA Astrophysics Data System (ADS)

Clark, Daniel; Tabak, Max

2006-10-01

Various gain models have shown the potentially great advantages of Fast Ignition (FI) Inertial Confinement Fusion (ICF) over its conventional hotspot ignition counterpart. These gain models, however, all assume nearly uniform-density fuel assemblies. By contrast, typical ICF implosions yield hollowed fuel assemblies with a high-density shell of fuel surrounding a low-density, high-pressure hotspot. To realize fully the advantages of FI, then, an alternative implosion design must be found which yields nearly isochoric fuel assemblies without substantial hotspots. Here, it is shown that a self-similar spherical implosion of the type originally studied by Guderley [Luftfahrtforschung 19, 302 (1942)] may be employed to yield precisely such quasi-isochoric imploded states. The difficulty remains, however, of accessing these self-similarly imploding configurations from initial conditions representing an actual ICF target, namely a uniform, solid-density shell at rest. Furthermore, these specialized implosions must be realized for practicable drive parameters, i.e., accessible peak pressures, shell aspect ratios, etc. An implosion scheme is presented which meets all of these requirements, suggesting the possibility of genuinely isochoric implosions for FI.

Quantifying the Impact of Nanoparticle Coatings and Non-uniformities on XPS Analysis: Gold/silver Core-shell Nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Yung-Chen Andrew; Engelhard, Mark H.; Baer, Donald R.

2016-03-07

Abstract or short description: Spectral modeling of photoelectrons can serve as a valuable tool when combined with X-ray photoelectron spectroscopy (XPS) analysis. Herein, a new version of the NIST Simulation of Electron Spectra for Surface Analysis (SESSA 2.0) software, capable of directly simulating spherical multilayer NPs, was applied to model citrate stabilized Au/Ag-core/shell nanoparticles (NPs). The NPs were characterized using XPS and scanning transmission electron microscopy (STEM) to determine the composition and morphology of the NPs. The Au/Ag-core/shell NPs were observed to be polydispersed in size, non-circular, and contain off-centered Au-cores. Using the average NP dimensions determined from STEM analysis,more » SESSA spectral modeling indicated that washed Au/Ag-core shell NPs were stabilized with a 0.8 nm l« less

Electromagnetic δ -function sphere

NASA Astrophysics Data System (ADS)

Parashar, Prachi; Milton, Kimball A.; Shajesh, K. V.; Brevik, Iver

2017-10-01

We develop a formalism to extend our previous work on the electromagnetic δ -function plates to a spherical surface. The electric (λe) and magnetic (λg) couplings to the surface are through δ -function potentials defining the dielectric permittivity and the diamagnetic permeability, with two anisotropic coupling tensors. The formalism incorporates dispersion. The electromagnetic Green's dyadic breaks up into transverse electric and transverse magnetic parts. We derive the Casimir interaction energy between two concentric δ -function spheres in this formalism and show that it has the correct asymptotic flat-plate limit. We systematically derive expressions for the Casimir self-energy and the total stress on a spherical shell using a δ -function potential, properly regulated by temporal and spatial point splitting, which are different from the conventional temporal point splitting. In the strong-coupling limit, we recover the usual result for the perfectly conducting spherical shell but in addition there is an integrated curvature-squared divergent contribution. For finite coupling, there are additional divergent contributions; in particular, there is a familiar logarithmic divergence occurring in the third order of the uniform asymptotic expansion that renders it impossible to extract a unique finite energy except in the case of an isorefractive sphere, which translates into λg=-λe.

Tunable dielectric properties of mesoporous carbon hollow microspheres via textural properties.

PubMed

Xu, Hailong; Yin, Xiaowei; Li, Zhaochen; Liu, Chenglong; Wang, Zeyu; Li, Minghang; Zhang, Litong; Cheng, Laifei

2018-05-04

In this study, mesoporous carbon hollow microspheres (PCHMs) with tunable textural properties have been prepared through a facile hard template etching method. The PCHMs were characterized by scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Raman spectra, and nitrogen adsorption and desorption systems. Uniform PCHMs with shell thickness ranging from 23 nm to 55 nm are realized. PCHMs with different textural properties can regulate dielectric and electromagnetic (EM) wave absorption effectively. The composite of paraffin wax mixed with 10 wt% PCHMs (the shell thickness of PCHMs is 35 nm) exhibits a minimum coefficient value of -53.8 dB at 8.8 GHz, with a thickness of 3.4 mm. Besides, it is remarkable that the effective absorption bandwidth covers all the X band with as low as a 10 wt% filler ratio, compared with other spherical EM wave absorbers. The excellent EM wave absorption capability of PCHMs can be ascribed to the better impendence matching and strong EM wave attenuation constant based on tunable textural properties. Our results provide a facile strategy to tune dielectric properties of spherical carbon absorbers based on textural properties, and can be extended to other spherical absorbers.

Tunable dielectric properties of mesoporous carbon hollow microspheres via textural properties

NASA Astrophysics Data System (ADS)

Xu, Hailong; Yin, Xiaowei; Li, Zhaochen; Liu, Chenglong; Wang, Zeyu; Li, Minghang; Zhang, Litong; Cheng, Laifei

2018-05-01

In this study, mesoporous carbon hollow microspheres (PCHMs) with tunable textural properties have been prepared through a facile hard template etching method. The PCHMs were characterized by scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Raman spectra, and nitrogen adsorption and desorption systems. Uniform PCHMs with shell thickness ranging from 23 nm to 55 nm are realized. PCHMs with different textural properties can regulate dielectric and electromagnetic (EM) wave absorption effectively. The composite of paraffin wax mixed with 10 wt% PCHMs (the shell thickness of PCHMs is 35 nm) exhibits a minimum coefficient value of -53.8 dB at 8.8 GHz, with a thickness of 3.4 mm. Besides, it is remarkable that the effective absorption bandwidth covers all the X band with as low as a 10 wt% filler ratio, compared with other spherical EM wave absorbers. The excellent EM wave absorption capability of PCHMs can be ascribed to the better impendence matching and strong EM wave attenuation constant based on tunable textural properties. Our results provide a facile strategy to tune dielectric properties of spherical carbon absorbers based on textural properties, and can be extended to other spherical absorbers.

Resource Letter NSM-1: New insights into the nuclear shell model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dean, David Jarvis; Hamilton, J. H.

2011-01-01

This Resource Letter provides a guide to the literature on the spherical shell model as applied to nuclei. The nuclear shell model describes the structure of nuclei starting with a nuclear core developed by the classical neutron and proton magic numbers N,Z=2,8,20,28,50,82, 126, where gaps occur in the single-particle energies as a shell is filled, and the interactions of valence nucleons that reside beyond that core. Various modern extensions of this model for spherical nuclei are likewise described. Significant extensions of the nuclear shell model include new magic numbers for spherical nuclei and now for deformed nuclei as well. Whenmore » both protons and neutrons have shell gaps at the same spherical or deformed shapes, they can reinforce each other to give added stability to that shape and lead to new magic numbers. The vanishings of the classical spherical shell model energy gaps and magic numbers in new neutron-rich nuclei are described. Spherical and deformed shell gaps are seen to be critical for the existence of elements with Z > 100.« less

Efficient color mixing through étendue conservation using freeform optics

NASA Astrophysics Data System (ADS)

Sorgato, Simone; Mohedano, Rubén.; Chaves, Julio; Cvetkovic, Aleksandra; Hernández, Maikel; Benitez, Pablo; Miñano, Juan C.; Thienpont, Hugo; Duerr, Fabian

2015-08-01

Today's SSL illumination market shows a clear trend to high flux packages with higher efficiency and higher CRI, realized by means of multiple color chips and phosphors. Such light sources require the optics to provide both near- and far-field color mixing. This design problem is particularly challenging for collimated luminaries, since traditional diffusers cannot be employed without enlarging the exit aperture and reducing brightness. Furthermore, diffusers compromise the light output ratio (efficiency) of the lamps to which they are applied. A solution, based on Köhler integration, consisting of a spherical cap comprising spherical microlenses on both its interior and exterior sides was presented in 2012. The diameter of this so-called Shell-Mixer was 3 times that of the chip array footprint. A new version of the Shell-Mixer, based on the Edge Ray Principle and conservation of etendue, where neither the outer shape of the cap nor the surfaces of the lenses are constrained to spheres or 2D Cartesian ovals will be shown in this work. The new shell is freeform, only twice as large as the original chip-array and equals the original model in terms of color uniformity, brightness and efficiency.

Time-resolved compression of a capsule with a cone to high density for fast-ignition laser fusion

DOE PAGES

Theobald, W.; Solodov, A. A.; Stoeckl, C.; ...

2014-12-12

The advent of high-intensity lasers enables us to recreate and study the behaviour of matter under the extreme densities and pressures that exist in many astrophysical objects. It may also enable us to develop a power source based on laser-driven nuclear fusion. Achieving such conditions usually requires a target that is highly uniform and spherically symmetric. Here we show that it is possible to generate high densities in a so-called fast-ignition target that consists of a thin shell whose spherical symmetry is interrupted by the inclusion of a metal cone. Using picosecond-time-resolved X-ray radiography, we show that we can achievemore » areal densities in excess of 300 mg cm -2 with a nanosecond-duration compression pulse -- the highest areal density ever reported for a cone-in-shell target. Such densities are high enough to stop MeV electrons, which is necessary for igniting the fuel with a subsequent picosecond pulse focused into the resulting plasma.« less

Time-resolved compression of a capsule with a cone to high density for fast-ignition laser fusion.

PubMed

Theobald, W; Solodov, A A; Stoeckl, C; Anderson, K S; Beg, F N; Epstein, R; Fiksel, G; Giraldez, E M; Glebov, V Yu; Habara, H; Ivancic, S; Jarrott, L C; Marshall, F J; McKiernan, G; McLean, H S; Mileham, C; Nilson, P M; Patel, P K; Pérez, F; Sangster, T C; Santos, J J; Sawada, H; Shvydky, A; Stephens, R B; Wei, M S

2014-12-12

The advent of high-intensity lasers enables us to recreate and study the behaviour of matter under the extreme densities and pressures that exist in many astrophysical objects. It may also enable us to develop a power source based on laser-driven nuclear fusion. Achieving such conditions usually requires a target that is highly uniform and spherically symmetric. Here we show that it is possible to generate high densities in a so-called fast-ignition target that consists of a thin shell whose spherical symmetry is interrupted by the inclusion of a metal cone. Using picosecond-time-resolved X-ray radiography, we show that we can achieve areal densities in excess of 300 mg cm(-2) with a nanosecond-duration compression pulse--the highest areal density ever reported for a cone-in-shell target. Such densities are high enough to stop MeV electrons, which is necessary for igniting the fuel with a subsequent picosecond pulse focused into the resulting plasma.

Global Curvature Buckling and Snapping of Spherical Shells.

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Steranka, Mark; Bade, Abdikhalaq; Trejo, Miguel; Holmes, Douglas

A spherical shell under external pressure will eventually buckle locally through the development of a dimple. However, when a free spherical shell is subject to variations in natural curvature, it will either buckle globally or snap towards a buckled configuration. We study the similarities and differences between pressure and curvature instabilities in spherical shells. We show how the critical buckling natural curvature is largely independent of the thinness and half-angle of the shell, while the critical snapping natural curvature grows linearly with the half-angle. As a result, we demonstrate how a critical half-angle, depending only on the thinness of the shell, sets the threshold between two different kinds of snapping: as a rule of thumb, shallow shells snap into everted shells, while deep shells snap into buckled shells. As the developed models are purely geometrical, the results are applicable to a large variety of stimuli and scales. NSF CAREER CMMI-1454153.

Fabrication of bifunctional core-shell Fe3O4 particles coated with ultrathin phosphor layer

PubMed Central

2013-01-01

Bifunctional monodispersed Fe3O4 particles coated with an ultrathin Y2O3:Tb3+ shell layer were fabricated using a facile urea-based homogeneous precipitation method. The obtained composite particles were characterized by powder X-ray diffraction, transmission electron microscopy (TEM), quantum design vibrating sample magnetometry, and photoluminescence (PL) spectroscopy. TEM revealed uniform spherical core-shell-structured composites ranging in size from 306 to 330 nm with a shell thickness of approximately 25 nm. PL spectroscopy confirmed that the synthesized composites displayed a strong eye-visible green light emission. Magnetic measurements indicated that the composite particles obtained also exhibited strong superparamagnetic behavior at room temperature. Therefore, the inner Fe3O4 core and outer Y2O3:Tb3+ shell layer endow the composites with both robust magnetic properties and strong eye-visible luminescent properties. These composite materials have potential use in magnetic targeting and bioseparation, simultaneously coupled with luminescent imaging. PMID:23962025

Fabrication of bifunctional core-shell Fe3O4 particles coated with ultrathin phosphor layer

NASA Astrophysics Data System (ADS)

Atabaev, Timur Sh; Kim, Hyung-Kook; Hwang, Yoon-Hwae

2013-08-01

Bifunctional monodispersed Fe3O4 particles coated with an ultrathin Y2O3:Tb3+ shell layer were fabricated using a facile urea-based homogeneous precipitation method. The obtained composite particles were characterized by powder X-ray diffraction, transmission electron microscopy (TEM), quantum design vibrating sample magnetometry, and photoluminescence (PL) spectroscopy. TEM revealed uniform spherical core-shell-structured composites ranging in size from 306 to 330 nm with a shell thickness of approximately 25 nm. PL spectroscopy confirmed that the synthesized composites displayed a strong eye-visible green light emission. Magnetic measurements indicated that the composite particles obtained also exhibited strong superparamagnetic behavior at room temperature. Therefore, the inner Fe3O4 core and outer Y2O3:Tb3+ shell layer endow the composites with both robust magnetic properties and strong eye-visible luminescent properties. These composite materials have potential use in magnetic targeting and bioseparation, simultaneously coupled with luminescent imaging.

Whispering gallery modes in a spherical microcavity with a photoluminescent shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grudinkin, S. A., E-mail: grudink@gvg.ioffe.ru; Dontsov, A. A.; Feoktistov, N. A.

2015-10-15

Whispering-gallery mode spectra in optical microcavities based on spherical silica particles coated with a thin photoluminescent shell of hydrogenated amorphous silicon carbide are studied. The spectral positions of the whispering-gallery modes for spherical microcavities with a shell are calculated. The dependence of the spectral distance between the TE and TM modes on the shell thickness is examined.

Post-buckling of a pressured biopolymer spherical shell with the mode interaction

NASA Astrophysics Data System (ADS)

Zhang, Lei; Ru, C. Q.

2018-03-01

Imperfection sensitivity is essential for mechanical behaviour of biopolymer shells characterized by high geometric heterogeneity. The present work studies initial post-buckling and imperfection sensitivity of a pressured biopolymer spherical shell based on non-axisymmetric buckling modes and associated mode interaction. Our results indicate that for biopolymer spherical shells with moderate radius-to-thickness ratio (say, less than 30) and smaller effective bending thickness (say, less than 0.2 times average shell thickness), the imperfection sensitivity predicted based on the axisymmetric mode without the mode interaction is close to the present results based on non-axisymmetric modes with the mode interaction with a small (typically, less than 10%) relative errors. However, for biopolymer spherical shells with larger effective bending thickness, the maximum load an imperfect shell can sustain predicted by the present non-axisymmetric analysis can be significantly (typically, around 30%) lower than those predicted based on the axisymmetric mode without the mode interaction. In such cases, a more accurate non-axisymmetric analysis with the mode interaction, as given in the present work, is required for imperfection sensitivity of pressured buckling of biopolymer spherical shells. Finally, the implications of the present study to two specific types of biopolymer spherical shells (viral capsids and ultrasound contrast agents) are discussed.

Design and Synthesis of Spherical Multicomponent Aggregates Composed of Core-Shell, Yolk-Shell, and Hollow Nanospheres and Their Lithium-Ion Storage Performances.

PubMed

Park, Gi Dae; Kang, Yun Chan

2018-03-01

Micrometer-sized spherical aggregates of Sn and Co components containing core-shell, yolk-shell, hollow nanospheres are synthesized by applying nanoscale Kirkendall diffusion in the large-scale spray drying process. The Sn 2 Co 3 -Co 3 SnC 0.7 -C composite microspheres uniformly dispersed with Sn 2 Co 3 -Co 3 SnC 0.7 mixed nanocrystals are formed by the first-step reduction of spray-dried precursor powders at 900 °C. The second-step oxidation process transforms the Sn 2 Co 3 -Co 3 SnC 0.7 -C composite into the porous microsphere composed of Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 core-shell, Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 yolk-shell, and CoSnO 3 -Co 3 O 4 hollow nanospheres at 300, 400, and 500 °C, respectively. The discharge capacity of the microspheres with Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 core-shell, Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 yolk-shell, and CoSnO 3 -Co 3 O 4 hollow nanospheres for the 200 th cycle at a current density of 1 A g -1 is 1265, 987, and 569 mA h g -1 , respectively. The ultrafine primary nanoparticles with a core-shell structure improve the structural stability of the porous-structured microspheres during repeated lithium insertion and desertion processes. The porous Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 microspheres with core-shell primary nanoparticles show excellent cycling and rate performances as anode materials for lithium-ion batteries. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Resolving complex fibre architecture by means of sparse spherical deconvolution in the presence of isotropic diffusion

NASA Astrophysics Data System (ADS)

Zhou, Q.; Michailovich, O.; Rathi, Y.

2014-03-01

High angular resolution diffusion imaging (HARDI) improves upon more traditional diffusion tensor imaging (DTI) in its ability to resolve the orientations of crossing and branching neural fibre tracts. The HARDI signals are measured over a spherical shell in q-space, and are usually used as an input to q-ball imaging (QBI) which allows estimation of the diffusion orientation distribution functions (ODFs) associated with a given region-of interest. Unfortunately, the partial nature of single-shell sampling imposes limits on the estimation accuracy. As a result, the recovered ODFs may not possess sufficient resolution to reveal the orientations of fibre tracts which cross each other at acute angles. A possible solution to the problem of limited resolution of QBI is provided by means of spherical deconvolution, a particular instance of which is sparse deconvolution. However, while capable of yielding high-resolution reconstructions over spacial locations corresponding to white matter, such methods tend to become unstable when applied to anatomical regions with a substantial content of isotropic diffusion. To resolve this problem, a new deconvolution approach is proposed in this paper. Apart from being uniformly stable across the whole brain, the proposed method allows one to quantify the isotropic component of cerebral diffusion, which is known to be a useful diagnostic measure by itself.

Hierarchical nanostructured hollow spherical carbon with mesoporous shell as a unique cathode catalyst support in proton exchange membrane fuel cell.

PubMed

Fang, Baizeng; Kim, Jung Ho; Kim, Minsik; Kim, Minwoo; Yu, Jong-Sung

2009-03-07

Hierarchical nanostructured spherical carbon with hollow macroporous core in combination with mesoporous shell has been explored to support Pt cathode catalyst with high metal loading in proton exchange membrane fuel cell (PEMFC). The hollow core-mesoporous shell carbon (HCMSC) has unique structural characteristics such as large specific surface area and mesoporous volume, ensuring uniform dispersion of the supported high loading (60 wt%) Pt nanoparticles with small particle size, and well-developed three-dimensionally interconnected hierarchical porosity network, facilitating fast mass transport. The HCMSC-supported Pt(60 wt%) cathode catalyst has demonstrated markedly enhanced catalytic activity toward oxygen reduction and greatly improved PEMFC polarization performance compared with carbon black Vulcan XC-72 (VC)-supported ones. Furthermore, the HCMSC-supported Pt(40 wt%) or Pt(60 wt%) outperforms the HCMSC-supported Pt(20 wt%) even at a low catalyst loading of 0.2 mg Pt cm(-2) in the cathode, which is completely different from the VC-supported Pt catalysts. The capability of supporting high loading Pt is supposed to accelerate the commercialization of PEMFC due to the anticipated significant reduction in the amount of catalyst support required, diffusion layer thickness and fabricating cost of the supported Pt catalyst electrode.

Synthesis of suitable SiO2 nano particles as the core in core-shell nanostructured materials.

PubMed

Ghahari, Mehdi; Aghababazadeh, Roya; Ebadzadeh, Touradj; Mirhabibi, Alireza; Brydson, Rik; Fabbri, Paola; Najafi, Farhod

2011-06-01

The effect of surfactant on the luminescent intensity of SiO2 @Y2O3:Eu3+ particles with a core shell structure is described. Core-shell particles are used in phosphor materials and employing spherical particles with a narrow size distribution is vital for the enhancement of luminescent properties. Three kinds of different surfactants were used to synthesis SiO2 nano particles via a sol gel process. The results demonstrated that comb polycarboxylic acid surfactant had a significant influence on the morphology and particle size distribution. Somehow, particles with 100 nm size and narrow size distribution were produced. These particles had relatively uniform packing, unlike particles produced with other surfactants or without surfactant which had irregular assembly. The photoluminescence intensity of SiO2 @Y2O3:Eu3+ particles that was synthesized by comb polycarboxylic acid surfactant was higher than those which were produced without surfactant.

Optical design of soft multifocal contact lens with uniform optical power in center-distance zone with optimized NURBS.

PubMed

Vu, Lien T; Chen, Chao-Chang A; Yu, Chia-Wei

2018-02-05

This study aims to develop a new optical design method of soft multifocal contact lens (CLs) to obtain uniform optical power in large center-distance zone with optimized Non-Uniform Rational B-spline (NURBS). For the anterior surface profiles of CLs, the NURBS design curves are optimized to match given optical power distributions. Then, the NURBS in the center-distance zones are fitted in the corresponding spherical/aspheric curves for both data points and their centers of curvature to achieve the uniform power. Four cases of soft CLs have been manufactured by casting in shell molds by injection molding and then measured to verify the design specifications. Results of power profiles of these CLs are concord with the given clinical requirements of uniform powers in larger center-distance zone. The developed optical design method has been verified for multifocal CLs design and can be further applied for production of soft multifocal CLs.

Acoustic manipulation: Bessel beams and active carriers

NASA Astrophysics Data System (ADS)

Rajabi, Majid; Mojahed, Alireza

2017-10-01

In this paper, we address the interaction of zero-order acoustic Bessel beams as an acoustic manipulation tool, with an active spherical shell, as a carrier in drug, agent, or material delivery systems, in order to investigate the controllability of exerted acoustic radiation force as the driver. The active body is comprised of a spherical elastic shell stimulated in its monopole mode of vibrations with the same frequency as the incident wave field via an internally bonded and spatially uniformly excited piezoelectric actuator. The main aim of this work is to examine the performance of a nondiffracting and self-reconstructing zero-order Bessel beam to obtain the full manipulability condition of active carriers in comparison with the case of a plane wave field. The results unveil some unique potentials of the Bessel beams in the company of active carriers, with emphasis on the consumed power of the actuation system. This paper will widen the path toward the single-beam robust acoustic manipulation techniques and may lead to the prospect of combined tweezers and fields, with applications in delivery systems, microswimmers, and trapper designs.

Probing Shells Against Buckling: A Nondestructive Technique for Laboratory Testing

NASA Astrophysics Data System (ADS)

Thompson, J. Michael T.; Hutchinson, John W.; Sieber, Jan

2017-12-01

This paper addresses testing of compressed structures, such as shells, that exhibit catastrophic buckling and notorious imperfection sensitivity. The central concept is the probing of a loaded structural specimen by a controlled lateral displacement to gain quantitative insight into its buckling behavior and to measure the energy barrier against buckling. This can provide design information about a structure’s stiffness and robustness against buckling in terms of energy and force landscapes. Developments in this area are relatively new but have proceeded rapidly with encouraging progress. Recent experimental tests on uniformly compressed spherical shells, and axially loaded cylinders, show excellent agreement with theoretical solutions. The probing technique could be a valuable experimental procedure for testing prototype structures, but before it can be used a range of potential problems must be examined and solved. The probing response is highly nonlinear and a variety of complications can occur. Here, we make a careful assessment of unexpected limit points and bifurcations, that could accompany probing, causing complications and possibly even collapse of a test specimen. First, a limit point in the probe displacement (associated with a cusp instability and fold) can result in dynamic buckling as probing progresses, as demonstrated in the buckling of a spherical shell under volume control. Second, various types of bifurcations which can occur on the probing path which result in the probing response becoming unstable are also discussed. To overcome these problems, we outline the extra controls over the entire structure that may be needed to stabilize the response.

Final report SI 08-SI-004: Fusion application targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biener, J; Kucheyev, S O; Wang, M Y

2010-12-03

Complex target structures are necessary to take full advantage of the unique laboratory environment created by inertial confinement fusion experiments. For example, uses-of-ignition targets that contain a thin layer of a low density nanoporous material inside a spherical ablator shell allow placing dopants in direct contact with the DT fuel. The ideal foam for this application is a low-density hydrocarbon foam that is strong enough to survive wetting with cryogenic hydrogen, and low enough in density (density less than {approx}30 mg/cc) to not reduce the yield of the target. Here, we discuss the fabrication foam-lined uses-of-ignition targets, and the developmentmore » of low-density foams that can be used for this application. Much effort has been directed over the last 20 years toward the development of spherical foam targets for direct-drive and fast-ignition experiments. In these targets, the spherical foam shell is used to define the shape of the cryogenic DT fuel layer, or acts as a surrogate to simulate the cryogenic fuel layer. These targets are fabricated from relatively high-density aerogels (>100 mg/cc) and coated with a few micron thick permeation barrier. With exception of the above mentioned fast ignition targets, the wall of these targets is typically larger than 100 microns. In contrast, the fusion application targets for indirect-drive experiments on NIF will require a much thinner foam shell surrounded by a much thicker ablator shell. The design requirements for both types of targets are compared in Table 1. The foam shell targets for direct-drive experiments can be made in large quantities and with reasonably high yields using an encapsulation technique pioneered by Takagi et al. in the early 90's. In this approach, targets are made by first generating unsupported foam shells using a triple-orifice droplet generator, followed by coating the dried foam shells with a thin permeation barrier. However, this approach is difficult, if not impossible, to transfer to the lower density and thinner wall foam shells required for indirect-drive uses-of-ignition targets for NIF that then would have to be coated with an at least hundred-micron-thick ablator film. So far, the thinnest shells that have been fabricated using the triple-orifice-droplet generator technique had a wall thickness of {approx}20 microns, but despite of being made from a higher-density foam formulation, the shells were mechanically very sensitive, difficult to dry, and showed large deviations from roundness. We thus decided to explore a different approach based on using prefabricated thick-walled spherical ablator shells as templates for the thin-walled foam shell. As in the case of the above mentioned encapsulation technique, the foam is made by sol-gel chemistry. However, our approach removes much the requirements on the mechanical stability of the foam shell as the foam shell is never handled in its free-standing form, and promises superior ablator uniformity and surface roughness. As discussed below, the success of this approach depends strongly on the availability of suitable aerogel chemistries (ideally pure hydrocarbon (CH)-based systems) with suitable rheological properties (high viscosity and high modulus near the gel point) that produce low-density and mechanically strong foams.« less

Non-Negative Spherical Deconvolution (NNSD) for estimation of fiber Orientation Distribution Function in single-/multi-shell diffusion MRI.

PubMed

Cheng, Jian; Deriche, Rachid; Jiang, Tianzi; Shen, Dinggang; Yap, Pew-Thian

2014-11-01

Spherical Deconvolution (SD) is commonly used for estimating fiber Orientation Distribution Functions (fODFs) from diffusion-weighted signals. Existing SD methods can be classified into two categories: 1) Continuous Representation based SD (CR-SD), where typically Spherical Harmonic (SH) representation is used for convenient analytical solutions, and 2) Discrete Representation based SD (DR-SD), where the signal profile is represented by a discrete set of basis functions uniformly oriented on the unit sphere. A feasible fODF should be non-negative and should integrate to unity throughout the unit sphere S(2). However, to our knowledge, most existing SH-based SD methods enforce non-negativity only on discretized points and not the whole continuum of S(2). Maximum Entropy SD (MESD) and Cartesian Tensor Fiber Orientation Distributions (CT-FOD) are the only SD methods that ensure non-negativity throughout the unit sphere. They are however computational intensive and are susceptible to errors caused by numerical spherical integration. Existing SD methods are also known to overestimate the number of fiber directions, especially in regions with low anisotropy. DR-SD introduces additional error in peak detection owing to the angular discretization of the unit sphere. This paper proposes a SD framework, called Non-Negative SD (NNSD), to overcome all the limitations above. NNSD is significantly less susceptible to the false-positive peaks, uses SH representation for efficient analytical spherical deconvolution, and allows accurate peak detection throughout the whole unit sphere. We further show that NNSD and most existing SD methods can be extended to work on multi-shell data by introducing a three-dimensional fiber response function. We evaluated NNSD in comparison with Constrained SD (CSD), a quadratic programming variant of CSD, MESD, and an L1-norm regularized non-negative least-squares DR-SD. Experiments on synthetic and real single-/multi-shell data indicate that NNSD improves estimation performance in terms of mean difference of angles, peak detection consistency, and anisotropy contrast between isotropic and anisotropic regions. Copyright © 2014 Elsevier Inc. All rights reserved.

Normalization and Implementation of Three Gravitational Acceleration Models

NASA Technical Reports Server (NTRS)

Eckman, Randy A.; Brown, Aaron J.; Adamo, Daniel R.; Gottlieb, Robert G.

2016-01-01

Unlike the uniform density spherical shell approximations of Newton, the consequence of spaceflight in the real universe is that gravitational fields are sensitive to the asphericity of their generating central bodies. The gravitational potential of an aspherical central body is typically resolved using spherical harmonic approximations. However, attempting to directly calculate the spherical harmonic approximations results in at least two singularities that must be removed to generalize the method and solve for any possible orbit, including polar orbits. Samuel Pines, Bill Lear, and Robert Gottlieb developed three unique algorithms to eliminate these singularities. This paper documents the methodical normalization of two of the three known formulations for singularity-free gravitational acceleration (namely, the Lear and Gottlieb algorithms) and formulates a general method for defining normalization parameters used to generate normalized Legendre polynomials and Associated Legendre Functions (ALFs) for any algorithm. A treatment of the conventional formulation of the gravitational potential and acceleration is also provided, in addition to a brief overview of the philosophical differences between the three known singularity-free algorithms.

Geometry induced phase transitions in magnetic spherical shell

NASA Astrophysics Data System (ADS)

Sloika, Mykola I.; Sheka, Denis D.; Kravchuk, Volodymyr P.; Pylypovskyi, Oleksandr V.; Gaididei, Yuri

2017-12-01

Equilibrium magnetization states in spherical shells of a magnetically soft ferromagnet form two out-of-surface vortices with codirectionally magnetized vortex cores at the sphere poles: (i) a whirligig state with the in-surface magnetization oriented along parallels is typical for thick shells; (ii) a three dimensional onion state with the in-surface meridional direction of the magnetization is realized in thin shells. The geometry of spherical shell prohibits an existence of spatially homogeneous magnetization distribution, even in the case of small sample radii. By varying geometrical parameters a continuous phase transition between the whirligig and onion states takes place. The detailed analytical description of the phase diagram is well confirmed by micromagnetic simulations.

Ascorbic-acid-assisted growth of high quality M@ZnO: a growth mechanism and kinetics study.

PubMed

Yang, Yun; Han, Shuhua; Zhou, Guangju; Zhang, Lijie; Li, Xingliang; Zou, Chao; Huang, Shaoming

2013-12-07

We present a general route for synthesizing M@ZnO nanoparticles (NPs) by using ascorbic acid (AA) to induce deposition of ZnO on various shaped and structured cationic-surfactant-capped NP surfaces (noble, magnetic, semiconductor, rod-like, spherical, cubic, dendrite, alloy, core@shell). The results show that the complexing (AA and Zn(2+)) and cooperative effects (AA and CTAB) play important roles in the formation of polycrystalline ZnO shells. Besides, the growth kinetics of M@ZnO was systematically studied. It was found that the slow growth rate favors the successful formation of uniform core@ZnO NPs with relatively loose shells. An appropriate growth rate allows achieving high quality M@ZnO NPs with dense shells. However, very fast growth causes significant additional nucleation and the formation of pure ZnO NPs. This general method is suitable for preparing M@ZnO using seed NPs prepared in both water and organic phases. It might be an alternative route for functionalizing NPs for bioapplications (ZnO is biocompatible), modulating material properties as designed, or synthesizing template materials for building other nanostructures.

Spherical-shell boundaries for two-dimensional compressible convection in a star

NASA Astrophysics Data System (ADS)

Pratt, J.; Baraffe, I.; Goffrey, T.; Geroux, C.; Viallet, M.; Folini, D.; Constantino, T.; Popov, M.; Walder, R.

2016-10-01

Context. Studies of stellar convection typically use a spherical-shell geometry. The radial extent of the shell and the boundary conditions applied are based on the model of the star investigated. We study the impact of different two-dimensional spherical shells on compressible convection. Realistic profiles for density and temperature from an established one-dimensional stellar evolution code are used to produce a model of a large stellar convection zone representative of a young low-mass star, like our sun at 106 years of age. Aims: We analyze how the radial extent of the spherical shell changes the convective dynamics that result in the deep interior of the young sun model, far from the surface. In the near-surface layers, simple small-scale convection develops from the profiles of temperature and density. A central radiative zone below the convection zone provides a lower boundary on the convection zone. The inclusion of either of these physically distinct layers in the spherical shell can potentially affect the characteristics of deep convection. Methods: We perform hydrodynamic implicit large eddy simulations of compressible convection using the MUltidimensional Stellar Implicit Code (MUSIC). Because MUSIC has been designed to use realistic stellar models produced from one-dimensional stellar evolution calculations, MUSIC simulations are capable of seamlessly modeling a whole star. Simulations in two-dimensional spherical shells that have different radial extents are performed over tens or even hundreds of convective turnover times, permitting the collection of well-converged statistics. Results: To measure the impact of the spherical-shell geometry and our treatment of boundaries, we evaluate basic statistics of the convective turnover time, the convective velocity, and the overshooting layer. These quantities are selected for their relevance to one-dimensional stellar evolution calculations, so that our results are focused toward studies exploiting the so-called 321D link. We find that the inclusion in the spherical shell of the boundary between the radiative and convection zones decreases the amplitude of convective velocities in the convection zone. The inclusion of near-surface layers in the spherical shell can increase the amplitude of convective velocities, although the radial structure of the velocity profile established by deep convection is unchanged. The impact of including the near-surface layers depends on the speed and structure of small-scale convection in the near-surface layers. Larger convective velocities in the convection zone result in a commensurate increase in the overshooting layer width and a decrease in the convective turnover time. These results provide support for non-local aspects of convection.

Thin Shell Model for NIF capsule stagnation studies

NASA Astrophysics Data System (ADS)

Hammer, J. H.; Buchoff, M.; Brandon, S.; Field, J. E.; Gaffney, J.; Kritcher, A.; Nora, R. C.; Peterson, J. L.; Spears, B.; Springer, P. T.

2015-11-01

We adapt the thin shell model of Ott et al. to asymmetric ICF capsule implosions on NIF. Through much of an implosion, the shell aspect ratio is large so the thin shell approximation is well satisfied. Asymmetric pressure drive is applied using an analytic form for ablation pressure as a function of the x-ray flux, as well as time-dependent 3D drive asymmetry from hohlraum calculations. Since deviations from a sphere are small through peak velocity, we linearize the equations, decompose them by spherical harmonics and solve ODE's for the coefficients. The model gives the shell position, velocity and areal mass variations at the time of peak velocity, near 250 microns radius. The variables are used to initialize 3D rad-hydro calculations with the HYDRA and ARES codes. At link time the cold fuel shell and ablator are each characterized by a density, adiabat and mass. The thickness, position and velocity of each point are taken from the thin shell model. The interior of the shell is filled with a uniform gas density and temperature consistent with the 3/2PV energy found from 1D rad-hydro calculations. 3D linked simulations compare favorably with integrated simulations of the entire implosion. Through generating synthetic diagnostic data, the model offers a method for quickly testing hypothetical sources of asymmetry and comparing with experiment. Prepared by LLNL under Contract DE-AC52-07NA27344.

The classical D-type expansion of spherical H II regions

NASA Astrophysics Data System (ADS)

Williams, Robin J. R.; Bibas, Thomas G.; Haworth, Thomas J.; Mackey, Jonathan

2018-06-01

Recent numerical and analytic work has highlighted some shortcomings in our understanding of the dynamics of H II region expansion, especially at late times, when the H II region approaches pressure equilibrium with the ambient medium. Here we reconsider the idealized case of a constant radiation source in a uniform and spherically symmetric ambient medium, with an isothermal equation of state. A thick-shell solution is developed which captures the stalling of the ionization front and the decay of the leading shock to a weak compression wave as it escapes to large radii. An acoustic approximation is introduced to capture the late-time damped oscillations of the H II region about the stagnation radius. Putting these together, a matched asymptotic equation is derived for the radius of the ionization front which accounts for both the inertia of the expanding shell and the finite temperature of the ambient medium. The solution to this equation is shown to agree very well with the numerical solution at all times, and is superior to all previously published solutions. The matched asymptotic solution can also accurately model the variation of H II region radius for a time-varying radiation source.

Supramolecular core-shell nanoparticles for photoconductive device applications

NASA Astrophysics Data System (ADS)

Cheng, Chih-Chia; Chen, Jem-Kun; Shieh, Yeong-Tarng; Lee, Duu-Jong

2016-08-01

We report a breakthrough discovery involving supramolecular-based strategies to construct novel core-shell heterojunction nanoparticles with hydrophilic adenine-functionalized polythiophene (PAT) as the core and hydrophobic phenyl-C61-butyric acid methyl ester (PCBM) as the shell, which enables the conception of new functional supramolecular assemblies for constructing functional nanomaterials for applications in optoelectronic devices. The generated nanoparticles exhibit uniform spherical shape, well-controlled tuning of particle size with narrow size distributions, and excellent electrochemical stability in solution and the solid state owing to highly efficient energy transfer from PAT to PCBM. When the PAT/PCBM nanoparticles were fabricated into a photoconducting layer in an electronic device, the resulting device showed excellent electric conduction characteristics, including an electrically-tunable voltage-controlled switch, and high short-circuit current and open-circuit voltage. These observations demonstrate how the self-assembly of PAT/PCBM into specific nanostructures may help to promote efficient charge generation and transport processes, suggesting potential for a wide variety of applications as a promising candidate material for bulk heterojunction polymer devices.

Multi-shell spherical GaAs /AlxGa1-x As quantum dot shells-size distribution as a mechanism to generate intermediate band energy levels

NASA Astrophysics Data System (ADS)

Rodríguez-Magdaleno, K. A.; Pérez-Álvarez, R.; Martínez-Orozco, J. C.; Pernas-Salomón, R.

2017-04-01

In this work the generation of an intermediate band of energy levels from multi-shell spherical GaAs /AlxGa1-x As quantum dot shells-size distribution is reported. Within the effective mass approximation the electronic structure of a GaAs spherical quantum-dot surrounded by one, two and three shells is studied in detail using a numerically stable transfer matrix method. We found that a shells-size distribution characterized by continuously wider GaAs domains is a suitable mechanism to generate the intermediate band whose width is also dependent on the Aluminium concentration x. Our results suggest that this effective mechanism can be used for the design of wider intermediate band than reported in other quantum systems with possible solar cells enhanced performance.

Spherical silicon-shell photonic band gap structures fabricated by laser-assisted chemical vapor deposition

NASA Astrophysics Data System (ADS)

Wang, H.; Yang, Z. Y.; Lu, Y. F.

2007-02-01

Laser-assisted chemical vapor deposition was applied in fabricating three-dimensional (3D) spherical-shell photonic band gap (PBG) structures by depositing silicon shells covering silica particles, which had been self-assembled into 3D colloidal crystals. The colloidal crystals of self-assembled silica particles were formed on silicon substrates using the isothermal heating evaporation approach. A continuous wave Nd:YAG laser (1064nm wavelength) was used to deposit silicon shells by thermally decomposing disilane gas. Periodic silicon-shell/silica-particle PBG structures were obtained. By removing the silica particles enclosed in the silicon shells using hydrofluoric acid, hollow spherical silicon-shell arrays were produced. This technique is capable of fabricating structures with complete photonic band gaps, which is predicted by simulations with the plane wave method. The techniques developed in this study have the potential to flexibly engineer the positions of the PBGs by varying both the silica particle size and the silicon-shell thickness. Ellipsometry was used to investigate the specific photonic band gaps for both structures.

Repeated crossing of two concentric spherical thin-shells with charge

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

Interaction/collision of two concentric spherical thin-shells of linear fluid resulting in collapse has been considered recently. We show that addition of finely tuned electric charges on the shells apart from the cosmological constant serves to delay the collapse indefinitely, yielding an ever colliding system of two concentric fluid shells. Given the finely tuned charges, this provides an example of a perpetual two-body motion in general relativity.

VLTI monitoring of the dust formation event of the Nova V1280 Scorpii

NASA Astrophysics Data System (ADS)

Chesneau, O.; Banerjee, D. P. K.; Millour, F.; Nardetto, N.; Sacuto, S.; Spang, A.; Wittkowski, M.; Ashok, N. M.; Das, R. K.; Hummel, C.; Kraus, S.; Lagadec, E.; Morel, S.; Petr-Gotzens, M.; Rantakyro, F.; Schöller, M.

2008-08-01

Context: We present the first high spatial-resolution monitoring of the dust-forming nova V1280 Sco, performed with the Very Large Telescope Interferometer (VLTI). Aims: These observations promise to improve the distance determination of such events and constrain the mechanisms leading to very efficient dust formation under the harsh physical conditions encountered in novae ejecta. Methods: Spectra and visibilities were regularly acquired between the onset of dust formation, 23 days after discovery (or 11 days after maximum), and day 145, using the beam-combiner instruments AMBER (near-IR) and MIDI (mid-IR). These interferometric observations were complemented by near-infrared data from the 1.2 m Mt. Abu Infrared Observatory, India. The observations are initially interpreted in terms of simple uniform models; however more complex models, probably involving a second shell, are required to explain data acquired following t=110 d after outburst. This behavior is in accordance with the light curve of V1280 Sco, which exhibits a secondary peak at about t=106 d, followed by a new, steep decline, suggesting a new dust-forming event. Spherical dust shell models generated with the DUSTY code are used to investigate the parameters of the main dust shell. Results: Using uniform disk models, these observations allow us to determine an apparent linear expansion rate for the dust shell of 0.35 ± 0.03 mas day-1 and the approximate ejection time of the matter in which dust formed of t_ejec = 10.5 ± 7 d, i.e. close to the maximum brightness. This information, combined with the expansion velocity of 500 ± 100 km s-1, implies a distance estimate of 1.6 ± 0.4 kpc. The sparse uv coverage does not enable deviations from spherical symmetry to be clearly discerned. The dust envelope parameters were determined. The dust mass generated was typically 2-8 × 10-9 M_⊙ day-1, with a probable peak in production at about 20 days after the detection of dust and another peak shortly after t=110 d, when the amount of dust in the shell was estimated as 2.2 × 10-7 M_⊙. Considering that the dust-forming event lasted at least 200-250 d, the mass of the ejected material is likely to have exceeded 10-4 M_⊙. The conditions for the formation of multiple shells of dust are also discussed. Based on observations made with the Very Large Telescope Interferometer at Paranal Observatory under programs 278.D-5053, 279.D-5014 and 079.D-0415.

Localized tidal deformations and dissipation in Enceladus

NASA Astrophysics Data System (ADS)

Beuthe, M.

2017-12-01

The geologic activity at Enceladus's south pole remains unexplained, though tidal deformations are probably the ultimate cause. Recent gravity and libration data indicate that Enceladus's icy crust floats on a global ocean, is rather thin, and has a strongly non-uniform thickness. Tidal effects are enhanced by crustal thinning at the south pole, so that realistic models of tidal tectonics and dissipation should include lateral variations of shell structure. I solve this problem with a new theory of non-uniform viscoelastic thin shells, allowing for large lateral variations of crustal thickness as well as large 3D variations of crustal rheology. The coupling to tidal forcing takes into account self-gravity, density stratification below the shell, core viscoelasticity, and crustal compressibility. The resulting tidal thin shell equations are two partial differential equations defined on the spherical surface, which can be solved numerically much faster than 3D Finite Element Methods. The error on tidal displacements is less than 5% if the thickness is less than 10% of the radius while the error on the deviatoric stress varies between 0 and 10%. If Enceladus's shell is conductive with isostatic thickness variations, crustal thinning increases surface stresses by 60% at the north pole and by a factor of more than 3 at the south pole. Similarly, the surface flux resulting from crustal dissipation increases by a factor of 3 at the south pole. If dissipation is an order of magnitude higher than predicted by the Maxwell model (as suggested by recent experimental data), the power dissipated in the crust could reach 50% of the total power required to maintain the crust in thermal equilibrium, and most of the surface flux variation could be explained by latitudinal variations of crustal dissipation. In all cases, a large part of the heat budget must be generated below the crust.

Modeling mantle convection in the spherical annulus

NASA Astrophysics Data System (ADS)

Hernlund, John W.; Tackley, Paul J.

2008-12-01

Most methods for modeling mantle convection in a two-dimensional (2D) circular annular domain suffer from innate shortcomings in their ability to capture several characteristics of the spherical shell geometry of planetary mantles. While methods such as rescaling the inner and outer radius to reduce anomalous effects in a 2D polar cylindrical coordinate system have been introduced and widely implemented, such fixes may have other drawbacks that adversely affect the outcome of some kinds of mantle convection studies. Here we propose a new approach that we term the "spherical annulus," which is a 2D slice that bisects the spherical shell and is quantitatively formulated at the equator of a spherical polar coordinate system after neglecting terms in the governing equations related to variations in latitude. Spherical scaling is retained in this approximation since the Jacobian function remains proportional to the square of the radius. We present example calculations to show that the behavior of convection in the spherical annulus compares favorably against calculations performed in other 2D annular domains when measured relative to those in a fully three-dimensional (3D) spherical shell.

Freeform étendue-preserving optics for light and color mixing

NASA Astrophysics Data System (ADS)

Sorgato, Simone; Mohedano, Rubén.; Chaves, Julio; Cvetkovic, Aleksandra; Hernández, Maikel; Benítez, Pablo; Miñano, Juan C.; Thienpont, Hugo; Duerr, Fabian

2015-09-01

Today's SSL illumination market shows a clear trend towards high flux packages with higher efficiency and higher CRI, realized by means of multiple color chips and phosphors. Such light sources require the optics to provide both near- and far-field color mixing. This design problem is particularly challenging for collimated luminaries, since traditional diffusers cannot be employed without enlarging the exit aperture and reducing brightness (so increasing étendue). Furthermore, diffusers compromise the light output ratio (efficiency) of the lamps to which they are applied. A solution, based on Köhler integration, consisting of a spherical cap comprising spherical microlenses on both its interior and exterior sides was presented in 2012. When placed on top of an inhomogeneous multichip Lambertian LED, this so-called Shell-Mixer creates a homogeneous (both spatially and angularly) virtual source, also Lambertian, where the images of the chips merge. The virtual source is located at the same position with essentially the same size of the original source. The diameter of this optics was 3 times that of the chip-array footprint. In this work, we present a new version of the Shell-Mixer, based on the Edge Ray Principle, where neither the overall shape of the cap nor the surfaces of the lenses are constrained to spheres or rotational Cartesian ovals. This new Shell- Mixer is freeform, only twice as large as the original chip-array and equals the original model in terms of brightness, color uniformity and efficiency.

The two-stage origin of bright rings in extended radio lobes

NASA Astrophysics Data System (ADS)

Morrison, P.; Sadun, A.

1996-01-01

A few strong radio sources show unusual large-intensity features (up to 100- or 200-kpc scale) within their extended lobes. These appear in the plane of the sky as nearly circular rings, but physically they are actually spherical shells. Two such sources, HerA (3C348) and 3C310, are analysed in terms of their similarly uniform kinematics. Such objects do not easily fit into the Fanaroff-Riley scheme for jet and lobe sources. We model these sources by a two-stage account of their dynamics. Long ago, acoustic waves (or weak shocks) were excited again and again to form sphere after sphere in the pre-existing thermal galactic wind. They all arose at one spot along the jet axis at the edge of the galaxy, to drift with the wind, expanding uniformly at the speed of sound in the near-isothermal gas. The wind flows out supersonically at about Mach 5. In a much later second stage, a new and much faster flow of relativistic plasma is energized by the active nucleus deep within the galaxy. That plasma jet swiftly forms the radio lobe and infuses it with radio electrons. The new plasma fills in locally the low-pressure portions of each drifting acoustic shell. The shells then appear as a procession of radio rings, with modest intensity contrast and an understandable polarization. Both of these radio ring sources appear to have optically double active nuclei. Perhaps periodic tidal forces determine the density modulations during the older outflow that gave rise to the several drifting shells.

Spherical neutron generator

DOEpatents

Leung, Ka-Ngo

2006-11-21

A spherical neutron generator is formed with a small spherical target and a spherical shell RF-driven plasma ion source surrounding the target. A deuterium (or deuterium and tritium) ion plasma is produced by RF excitation in the plasma ion source using an RF antenna. The plasma generation region is a spherical shell between an outer chamber and an inner extraction electrode. A spherical neutron generating target is at the center of the chamber and is biased negatively with respect to the extraction electrode which contains many holes. Ions passing through the holes in the extraction electrode are focused onto the target which produces neutrons by D-D or D-T reactions.

Method for preparing spherical thermoplastic particles of uniform size

DOEpatents

Day, J.R.

1975-11-17

Spherical particles of thermoplastic material of virtually uniform roundness and diameter are prepared by cutting monofilaments of a selected diameter into rod-like segments of a selected uniform length which are then heated in a viscous liquid to effect the formation of the spherical particles.

Core-shell hydrogel beads with extracellular matrix for tumor spheroid formation.

PubMed

Yu, L; Grist, S M; Nasseri, S S; Cheng, E; Hwang, Y-C E; Ni, C; Cheung, K C

2015-03-01

Creating multicellular tumor spheroids is critical for characterizing anticancer treatments since they may provide a better model of the tumor than conventional monolayer culture. Moreover, tumor cell interaction with the extracellular matrix can determine cell organization and behavior. In this work, a microfluidic system was used to form cell-laden core-shell beads which incorporate elements of the extracellular matrix and support the formation of multicellular spheroids. The bead core (comprising a mixture of alginate, collagen, and reconstituted basement membrane, with gelation by temperature control) and shell (comprising alginate hydrogel, with gelation by ionic crosslinking) were simultaneously formed through flow focusing using a cooled flow path into the microfluidic chip. During droplet gelation, the alginate acts as a fast-gelling shell which aids in preventing droplet coalescence and in maintaining spherical droplet geometry during the slower gelation of the collagen and reconstituted basement membrane components as the beads warm up. After droplet gelation, the encapsulated MCF-7 cells proliferated to form uniform spheroids when the beads contained all three components: alginate, collagen, and reconstituted basement membrane. The dose-dependent response of the MCF-7 cell tumor spheroids to two anticancer drugs, docetaxel and tamoxifen, was compared to conventional monolayer culture.

Normalization of Gravitational Acceleration Models

NASA Technical Reports Server (NTRS)

Eckman, Randy A.; Brown, Aaron J.; Adamo, Daniel R.

2011-01-01

Unlike the uniform density spherical shell approximations of Newton, the con- sequence of spaceflight in the real universe is that gravitational fields are sensitive to the nonsphericity of their generating central bodies. The gravitational potential of a nonspherical central body is typically resolved using spherical harmonic approximations. However, attempting to directly calculate the spherical harmonic approximations results in at least two singularities which must be removed in order to generalize the method and solve for any possible orbit, including polar orbits. Three unique algorithms have been developed to eliminate these singularities by Samuel Pines [1], Bill Lear [2], and Robert Gottlieb [3]. This paper documents the methodical normalization of two1 of the three known formulations for singularity-free gravitational acceleration (namely, the Lear [2] and Gottlieb [3] algorithms) and formulates a general method for defining normalization parameters used to generate normalized Legendre Polynomials and ALFs for any algorithm. A treatment of the conventional formulation of the gravitational potential and acceleration is also provided, in addition to a brief overview of the philosophical differences between the three known singularity-free algorithms.

Scattering theory derivation of a 3D acoustic cloaking shell.

PubMed

Cummer, Steven A; Popa, Bogdan-Ioan; Schurig, David; Smith, David R; Pendry, John; Rahm, Marco; Starr, Anthony

2008-01-18

Through acoustic scattering theory we derive the mass density and bulk modulus of a spherical shell that can eliminate scattering from an arbitrary object in the interior of the shell--in other words, a 3D acoustic cloaking shell. Calculations confirm that the pressure and velocity fields are smoothly bent and excluded from the central region as for previously reported electromagnetic cloaking shells. The shell requires an anisotropic mass density with principal axes in the spherical coordinate directions and a radially dependent bulk modulus. The existence of this 3D cloaking shell indicates that such reflectionless solutions may also exist for other wave systems that are not isomorphic with electromagnetics.

Preparation and characterization of polymer-coated core-shell structured magnetic microbeads

NASA Astrophysics Data System (ADS)

Liu, Z. L.; Ding, Z. H.; Yao, K. L.; Tao, J.; Du, G. H.; Lu, Q. H.; Wang, X.; Gong, F. L.; Chen, X.

2003-09-01

Composite microbeads consisting of polymer-coated iron oxide nanoparticles are prepared by the microemulsion polymerization of styrene, divinyl benzene and methacrylic acid in the presence of emulsifiers. Fourier transform infrared spectrometer analysis indicates the presence of -COOH groups and Fe 3O 4 of the microbeads. The amount of -COOH groups localized on the surface, which is about 0.15 mmol/g, is determined by conductometric titration. Transmission electron microscope picture reveals that the microbeads have a core-shell structure. The dissolving experiments of microbeads in hydrochloric acid and toluene further identify the core-shell structure. Optical microscope indicates that the magnetic microbeads have uniform and spherical forms with the size of 1-5 μm. Magnetic sensitivity measurement indicates that the microbeads can be used conveniently. Magnetic property measurement shows very little residual magnetization and coercivity, which are below 0.5 emu/g and around 15 Oe, respectively. The magnetic properties are greatly related to the particle sizes. The thermal gravity analysis result shows the improvement of thermal stability. The experiment of immobilized antibody indicates that the functional groups on the surface are appropriate.

On the generation of a bubbly universe - A quantitative assessment of the CfA slice

NASA Technical Reports Server (NTRS)

Ostriker, J. P.; Strassler, M. J.

1989-01-01

A first attempt is made to calculate the properties of the matter distribution in a universe filled with overlapping bubbles produced by multiple explosions. Each spherical shell follows the cosmological Sedov-Taylor solution until it encounters another shell. Thereafter, mergers are allowed to occur in pairs on the basis of N-body results. At the final epoch, the matrix of overlapping shells is populated with 'galaxies' and the properties of slices through the numerically constructed cube compare well with CfA survey results for specified initial conditions. A statistic is found which measures the distance distribution from uniformly distributed points to the nearest galaxies on the projected plane which appears to provide a good measure of the bubbly character of the galaxy distribution. In a quantitative analysis of the CfA 'slice of the universe', a very good match is found between simulation and the real data for final average bubble radii of (13.5 + or - 1.5)/h Mpc with formal filling factor 1.0-1.5 or actual filling factor of 65-80 percent.

Viscoelastic damped response of cross-ply laminated shallow spherical shells subjected to various impulsive loads

NASA Astrophysics Data System (ADS)

Şahan, Mehmet Fatih

2017-11-01

In this paper, the viscoelastic damped response of cross-ply laminated shallow spherical shells is investigated numerically in a transformed Laplace space. In the proposed approach, the governing differential equations of cross-ply laminated shallow spherical shell are derived using the dynamic version of the principle of virtual displacements. Following this, the Laplace transform is employed in the transient analysis of viscoelastic laminated shell problem. Also, damping can be incorporated with ease in the transformed domain. The transformed time-independent equations in spatial coordinate are solved numerically by Gauss elimination. Numerical inverse transformation of the results into the real domain are operated by the modified Durbin transform method. Verification of the presented method is carried out by comparing the results with those obtained by the Newmark method and ANSYS finite element software. Furthermore, the developed solution approach is applied to problems with several impulsive loads. The novelty of the present study lies in the fact that a combination of the Navier method and Laplace transform is employed in the analysis of cross-ply laminated shallow spherical viscoelastic shells. The numerical sample results have proved that the presented method constitutes a highly accurate and efficient solution, which can be easily applied to the laminated viscoelastic shell problems.

Dynamic equations for an isotropic spherical shell using the power series method and surface differential operators

NASA Astrophysics Data System (ADS)

Okhovat, Reza; Boström, Anders

2017-04-01

Dynamic equations for an isotropic spherical shell are derived by using a series expansion technique. The displacement field is split into a scalar (radial) part and a vector (tangential) part. Surface differential operators are introduced to decrease the length of all equations. The starting point is a power series expansion of the displacement components in the thickness coordinate relative to the mid-surface of the shell. By using the expansions of the displacement components, the three-dimensional elastodynamic equations yield a set of recursion relations among the expansion functions that can be used to eliminate all but the four of lowest order and to express higher order expansion functions in terms of those of lowest orders. Applying the boundary conditions on the surfaces of the spherical shell and eliminating all but the four lowest order expansion functions give the shell equations as a power series in the shell thickness. After lengthy manipulations, the final four shell equations are obtained in a relatively compact form which are given to second order in shell thickness explicitly. The eigenfrequencies are compared to exact three-dimensional theory with excellent agreement and to membrane theory.

Effects of compressibility on the temperature jump at the interface of layered, spherical-shell convection

NASA Technical Reports Server (NTRS)

Yen, David A.; Zhang, Shuxia; Langenberger, Sherri E.

1988-01-01

Large temperature jumps at the interface of layered convection are important to the argument used against the likelihood of separate circulations in the upper and lower mantles. This problem was studied within the framework of a compressible, constant viscosity spherical-shell model. Both mechanical and thermal coupling configurations are considered. Although the temperature jumps are reduced by compressibility, their magnitudes remain quite large, in the case of mechanical coupling. For thermal coupling, the temperature jumps become smaller but still are substantial, between 500 to 1000 C. In layered spherical-shell convection, flows in the lower mantle are several times greater than the surface velocities.

Shape evolution of a core-shell spherical particle under hydrostatic pressure.

PubMed

Colin, Jérôme

2012-03-01

The morphological evolution by surface diffusion of a core-shell spherical particle has been investigated theoretically under hydrostatic pressure when the shear modulii of the core and shell are different. A linear stability analysis has demonstrated that depending on the pressure, shear modulii, and radii of both phases, the free surface of the composite particle may be unstable with respect to a shape perturbation. A stability diagram finally emphasizes that the roughness development is favored in the case of a hard shell with a soft core.

The theory of spherically symmetric thin shells in conformal gravity

NASA Astrophysics Data System (ADS)

Berezin, Victor; Dokuchaev, Vyacheslav; Eroshenko, Yury

The spherically symmetric thin shells are the nearest generalizations of the point-like particles. Moreover, they serve as the simple sources of the gravitational fields both in General Relativity and much more complex quadratic gravity theories. We are interested in the special and physically important case when all the quadratic in curvature tensor (Riemann tensor) and its contractions (Ricci tensor and scalar curvature) terms are present in the form of the square of Weyl tensor. By definition, the energy-momentum tensor of the thin shell is proportional to Diracs delta-function. We constructed the theory of the spherically symmetric thin shells for three types of gravitational theories with the shell: (1) General Relativity; (2) Pure conformal (Weyl) gravity where the gravitational part of the total Lagrangian is just the square of the Weyl tensor; (3) Weyl-Einstein gravity. The results are compared with these in General Relativity (Israel equations). We considered in detail the shells immersed in the vacuum. Some peculiar properties of such shells are found. In particular, for the traceless ( = massless) shell, it is shown that their dynamics cannot be derived from the matching conditions and, thus, is completely arbitrary. On the contrary, in the case of the Weyl-Einstein gravity, the trajectory of the same type of shell is completely restored even without knowledge of the outside solution.

Calculation of Thermally-Induced Displacements in Spherically Domed Ion Engine Grids

NASA Technical Reports Server (NTRS)

Soulas, George C.

2006-01-01

An analytical method for predicting the thermally-induced normal and tangential displacements of spherically domed ion optics grids under an axisymmetric thermal loading is presented. A fixed edge support that could be thermally expanded is used for this analysis. Equations for the displacements both normal and tangential to the surface of the spherical shell are derived. A simplified equation for the displacement at the center of the spherical dome is also derived. The effects of plate perforation on displacements and stresses are determined by modeling the perforated plate as an equivalent solid plate with modified, or effective, material properties. Analytical model results are compared to the results from a finite element model. For the solid shell, comparisons showed that the analytical model produces results that closely match the finite element model results. The simplified equation for the normal displacement of the spherical dome center is also found to accurately predict this displacement. For the perforated shells, the analytical solution and simplified equation produce accurate results for materials with low thermal expansion coefficients.

Calculation of the acoustic radiation force on coated spherical shells in progressive and standing plane waves.

PubMed

Mitri, F G

2006-07-01

In this paper, analytical equations are derived for the time-averaged radiation force induced by progressive and standing acoustic waves incident on elastic spherical shells covered with a layer of viscoelastic and sound-absorbing material. The fluid surrounding the shells is considered compressible and nonviscous. The incident field is assumed to be moderate so that the scattered field from the shells is taken to linear approximation. The analytical results are illustrated by means of a numerical example in which the radiation force function curves are displayed, with particular emphasis on the coating thickness and the content of the hollow region of the shells. The fluid-loading on the radiation force function curves is analysed as well. This study attempts to generalize the various treatments of radiation force due to both progressive and standing waves on spherically-shaped structures immersed in ideal fluids. The results show that various ways can be effectively used for damping resonance peaks, such as by changing the fluid in the interior hollow region of the shells or by changing the coating thickness.

Moment equations for chromatography using superficially porous spherical particles.

PubMed

Miyabe, Kanji

2011-01-01

New moment equations were developed for chromatography using superficially porous (shell-type) spherical particles, which have recently attracted much attention as one of separation media for fast separation with high efficiency. At first, the moment equations of the first absolute and second central moments in the real time domain were derived from the analytical solution in the Laplace domain of a set of basic equations of the general rate model of chromatography, which represent the mass balance, mass-transfer rate, and reaction kinetics in the column packed with shell-type particles. Then, the moment equations were used for analyzing the experimental data of chromatography of kallidin in a Halo column, which were published in a previous paper written by other researchers. It was tried to predict the chromatographic behavior of shell-type particles having different shell thicknesses. The new moment equations are useful for a detailed analysis of the chromatographic behavior of shell-type spherical particles. It is also concluded that they can be used for the preliminarily optimization of their structural characteristics.

Electrostatics-driven shape transitions in soft shells.

PubMed

Jadhao, Vikram; Thomas, Creighton K; Olvera de la Cruz, Monica

2014-09-02

Manipulating the shape of nanoscale objects in a controllable fashion is at the heart of designing materials that act as building blocks for self-assembly or serve as targeted drug delivery carriers. Inducing shape deformations by controlling external parameters is also an important way of designing biomimetic membranes. In this paper, we demonstrate that electrostatics can be used as a tool to manipulate the shape of soft, closed membranes by tuning environmental conditions such as the electrolyte concentration in the medium. Using a molecular dynamics-based simulated annealing procedure, we investigate charged elastic shells that do not exchange material with their environment, such as elastic membranes formed in emulsions or synthetic nanocontainers. We find that by decreasing the salt concentration or increasing the total charge on the shell's surface, the spherical symmetry is broken, leading to the formation of ellipsoids, discs, and bowls. Shape changes are accompanied by a significant lowering of the electrostatic energy and a rise in the surface area of the shell. To substantiate our simulation findings, we show analytically that a uniformly charged disc has a lower Coulomb energy than a sphere of the same volume. Further, we test the robustness of our results by including the effects of charge renormalization in the analysis of the shape transitions and find the latter to be feasible for a wide range of shell volume fractions.

Nuclear Structure of 186Re

DTIC Science & Technology

2016-12-24

D population-depopulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 AME Atomic Mass Evaluation...this mass region are important for validating models of nuclear structure and reactions. The ENSDF feeds a specific data library relevant to nuclear...spherically asymmetric. Spherical asymmetry is common for nuclei between shell closures, such as those in the mid-shell 150  A  190 mass range of interest

Vibration of Shells

NASA Technical Reports Server (NTRS)

Leissa, A. W.

1973-01-01

The vibrational characteristics and mechanical properties of shell structures are discussed. The subjects presented are: (1) fundamental equations of thin shell theory, (2) characteristics of thin circular cylindrical shells, (3) complicating effects in circular cylindrical shells, (4) noncircular cylindrical shell properties, (5) characteristics of spherical shells, and (6) solution of three-dimensional equations of motion for cylinders.

Liquid Crystal Mediated Nano-assembled Gold Micro-shells

NASA Astrophysics Data System (ADS)

Quint, Makiko; Sarang, Som; Quint, David; Huang, Kerwyn; Gopinathan, Ajay; Hirst, Linda; Ghosh, Sayantani

We have created 3D nano-assenbled micro-shell by using thermotropic liquid crystal (LC), 4-Cyano-4'-pentylbiphenyl (5CB), doped with mesogen-functionalized gold nanoparticles (AuNPs). The assembly process is driven by the isotropic-nematic phase transition dynamics. We uniformly disperse the functionalized AuNPs into isotropic liquid crystal matrix and the mixture is cooled from the isotropic to the nematic phase. During the phase transition, the separation of LC-AuNP rich isotropic and ordered 5CB rich domains cause the functionalized AuNPs to move into the shrinking isotropic regions. The mesogenic ligands are locally crystalized during this process, which leads to the formation of a spherical shell with a densely packed wall of AuNPs. These micro-shells are capable of encapsulating fluorescence dye without visible leakages for several months. Additionally, they demonstrate strong localized surface plasmon resonance, which leads to localized heating on optical excitation. This photothermal effect disrupts the structure, releasing contents within seconds. Our results exhibiting the capture and optically regulated release of encapsulated substances is a novel platform that combines drug-delivery and photothermal therapy in one versatile and multifunctional unit. This work is supported by the NSF Grants No. DMR-1056860, ECC-1227034, and a University of California Merced Faculty Mentor Fellowship.

Self consistent field theory of virus assembly

NASA Astrophysics Data System (ADS)

Li, Siyu; Orland, Henri; Zandi, Roya

2018-04-01

The ground state dominance approximation (GSDA) has been extensively used to study the assembly of viral shells. In this work we employ the self-consistent field theory (SCFT) to investigate the adsorption of RNA onto positively charged spherical viral shells and examine the conditions when GSDA does not apply and SCFT has to be used to obtain a reliable solution. We find that there are two regimes in which GSDA does work. First, when the genomic RNA length is long enough compared to the capsid radius, and second, when the interaction between the genome and capsid is so strong that the genome is basically localized next to the wall. We find that for the case in which RNA is more or less distributed uniformly in the shell, regardless of the length of RNA, GSDA is not a good approximation. We observe that as the polymer-shell interaction becomes stronger, the energy gap between the ground state and first excited state increases and thus GSDA becomes a better approximation. We also present our results corresponding to the genome persistence length obtained through the tangent-tangent correlation length and show that it is zero in case of GSDA but is equal to the inverse of the energy gap when using SCFT.

Smoothed particle hydrodynamic simulations of expanding HII regions

NASA Astrophysics Data System (ADS)

Bisbas, Thomas G.

2009-09-01

This thesis deals with numerical simulations of expanding ionized regions, known as HII regions. We implement a new three dimensional algorithm in Smoothed Particle Hydrodynamics for including the dynamical effects of the interaction between ionizing radiation and the interstellar medium. This interaction plays a crucial role in star formation at all epochs. We study the influence of ionizing radiation in spherically symmetric clouds. In particular, we study the spherically symmetric expansion of an HII region inside a uniform-density, non-self-gravitating cloud. We examine the ability of our algorithm to reproduce the known theoretical solution and we find that the agreement is very good. We also study the spherically symmetric expansion inside a uniform-density, self-gravitating cloud. We propose a new differential equation of motion for the expanding shell that includes the effects of gravity. Comparing its numerical solution with the simulations, we find that the equation predicts the position of the shell accurately. We also study the expansion of an off-centre HII region inside a uniform-density, non- self-gravitating cloud. This results in an evolution known as the rocket effect, where the ionizing radiation pushes and accelerates the cloud away from the exciting star leading to its dispersal. During this evolution, cometary knots appear as a result of Rayleigh-Taylor and Vishniac instabilities. The knots are composed of a dense head with a conic tail behind them, a structure that points towards the ionizing source. Our simulations show that these knots are very reminiscent of the observed structures in planetary nebula, such as in the Helix nebula. The last part of this thesis is dedicated to the study of cores ionized by an exciting source which is placed outside and far away from them. The evolution of these cores is known as radiation driven compression (or implosion). We perform simulations and compare our findings with results of other workers and we find that they agree very well. Using stable Bonnor-Ebert spheres, we extend our study to modelling triggered star formation within these cores as they are overrun and compressed by the incident ionizing flux. We construct a parameter space diagram and we map regions where star formation is expected to be observed. All the above results indicate that the algorithm presented in this thesis works well for treating the propagation of ionizing radiation. This new algorithm provides the means to explore and evaluate the role of ionizing radiation in regulating the efficiency and statistics of star formation.

Exciton in a spherical core/shell nanostructure: Influence of surface ligand

NASA Astrophysics Data System (ADS)

Anitha, B.; Nithiananthi, P.

2018-04-01

Studies on exciton in an inverted type I spherical GaAs/Al0.3Ga0.7As core/shell nanostructure (CSN) are made using variational method. Dielectric constant and effective mass mismatches of the core and shell materials are considered. The effect of core and the shell dimensions on the exciton binding energy (BE) are analyzed for different shell (Rs) and core radii (Rc). It is observed that with the core and the shell inducement, significant change in BE can be achieved. In addition, the influence of ligand enclosureon the BE as a function of shell thickness (ST) is reviewed. The result exhibits that the presence of ligand considerably affects the BE. Further the transmission probability of exciton for various Rc and Rs are reported. The notable changes are compared and examined with and without ligand inclusion.

Fabrication of Nitrogen-Doped Hollow Mesoporous Spherical Carbon Capsules for Supercapacitors.

PubMed

Chen, Aibing; Xia, Kechan; Zhang, Linsong; Yu, Yifeng; Li, Yuetong; Sun, Hexu; Wang, Yuying; Li, Yunqian; Li, Shuhui

2016-09-06

A novel "dissolution-capture" method for the fabrication of nitrogen-doped hollow mesoporous spherical carbon capsules (N-HMSCCs) with high capability for supercapacitor is developed. The fabrication process is performed by depositing mesoporous silica on the surface of the polyacrylonitrile nanospheres, followed by a dissolution-capture process occurring in the polyacrylonitrile core and silica shell. The polyacrylonitrile core is dissolved by dimethylformamide treatment to form a hollow cavity. Then, the polyacrylonitrile is captured into the mesochannel of silica. After carbonization and etching of silica, N-HMSCCs with uniform mesopore size are produced. The N-HMSCCs show a high specific capacitance of 206.0 F g(-1) at a current density of 1 A g(-1) in 6.0 M KOH due to its unique hollow nanostructure, high surface area, and nitrogen content. In addition, 92.3% of the capacitance of N-HMSCCs still remains after 3000 cycles at 5 A g(-1). The "dissolution-capture" method should give a useful enlightenment for the design of electrode materials for supercapacitor.

Synthesis of carbon-coated Na2MnPO4F hollow spheres as a potential cathode material for Na-ion batteries

NASA Astrophysics Data System (ADS)

Wu, Ling; Hu, Yong; Zhang, Xiaoping; Liu, Jiequn; Zhu, Xing; Zhong, Shengkui

2018-01-01

Hollow sphere structure Na2MnPO4F/C composite is synthesized through spray drying, following in-situ pyrolytic carbon coating process. XRD results indicate that the well crystallized composite can be successfully synthesized, and no other impurity phases are detected. SEM and TEM results reveal that the Na2MnPO4F/C samples show intact hollow spherical architecture, and the hollow spherical shells with an average thickness of 150 nm-250 nm are composed of nanosized primary particles. Furthermore, the amorphous carbon layer is uniformly coated on the surface of the hollow sphere, and the nanosized Na2MnPO4F particles are well embedded in the carbon networks. Consequently, the hollow sphere structure Na2MnPO4F/C shows enhanced electrochemical performance. Especially, it is the first time that the obvious potential platforms (∼3.6 V) are observed during the charge and discharge process at room temperature.

Fundamental solutions to the bioheat equation and their application to magnetic fluid hyperthermia.

PubMed

Giordano, Mauricio A; Gutierrez, Gustavo; Rinaldi, Carlos

2010-01-01

Methods of predicting temperature profiles during local hyperthermia treatment are very important to avoid damage to healthy tissue. With this aim, fundamental solutions of Pennes' bioheat equation are derived in rectangular, cylindrical, and spherical coordinates. The medium is idealised as isotropic with effective thermal properties. Temperature distributions due to space- and time-dependent heat sources are obtained by the solution method presented. Applications of the fundamental solutions are addressed with emphasis on a particular problem of Magnetic Fluid Hyperthermia (MFH) consisting of a thin shell of magnetic nanoparticles in the outer surface of a spherical solid tumour. It is observed from the solution of this particular problem that the temperature profiles are strongly dependent on the distribution of the magnetic nanoparticles within the tissue. An almost uniform temperature profile is obtained inside the tumour with little penetration of therapeutic temperatures to the outer region of healthy tissue. The fundamental solutions obtained can be used to develop boundary element methods to predict temperature profiles with more complicated geometries.

Planck intermediate results: XXXIV. The magnetic field structure in the Rosette Nebula

DOE PAGES

Aghanim, N.; Alves, M. I. R.; Arnaud, M.; ...

2016-02-09

Planck has mapped the polarized dust emission over the whole sky, making it possible to trace the Galactic magnetic field structure that pervades the interstellar medium (ISM). In this paper, we combine polarization data from Planck with rotation measure (RM) observations towards a massive star-forming region, the Rosette Nebula in the Monoceros molecular cloud, to study its magnetic field structure and the impact of an expanding H ii region on the morphology of the field. We derive an analytical solution for the magnetic field, assumed to evolve from an initially uniform configuration following the expansion of ionized gas and themore » formation of a shell of swept-up ISM. From the RM data we estimate a mean value of the line-of-sight component of the magnetic field of about 3 μG (towards the observer) in the Rosette Nebula, for a uniform electron density of about 12 cm -3. The dust shell that surrounds the Rosette H ii region is clearly observed in the Planck intensity map at 353 GHz, with a polarization signal significantly different from that of the local background when considered asa whole. The Planck observations constrain the plane-of-the-sky orientation of the magnetic field in the Rosette’s parent molecular cloud to be mostly aligned with the large-scale field along the Galactic plane. The Planck data are compared with the analytical model, which predicts the mean polarization properties of a spherical and uniform dust shell for a given orientation of the field. This comparison leads to an upper limit of about 45° on the angle between the line of sight and the magnetic field in the Rosette complex, for an assumed intrinsic dust polarization fraction of 4%. This field direction can reproduce the RM values detected in the ionized region if the magnetic field strength in the Monoceros molecular cloud is in the range 6.5–9 μG. Finally, the present analytical model is able to reproduce the RM distribution across the ionized nebula, as well as the mean dust polarization properties of the swept-up shell, and can be directly applied to other similar objects.« less

Planck intermediate results: XXXIV. The magnetic field structure in the Rosette Nebula

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aghanim, N.; Alves, M. I. R.; Arnaud, M.

Planck has mapped the polarized dust emission over the whole sky, making it possible to trace the Galactic magnetic field structure that pervades the interstellar medium (ISM). In this paper, we combine polarization data from Planck with rotation measure (RM) observations towards a massive star-forming region, the Rosette Nebula in the Monoceros molecular cloud, to study its magnetic field structure and the impact of an expanding H ii region on the morphology of the field. We derive an analytical solution for the magnetic field, assumed to evolve from an initially uniform configuration following the expansion of ionized gas and themore » formation of a shell of swept-up ISM. From the RM data we estimate a mean value of the line-of-sight component of the magnetic field of about 3 μG (towards the observer) in the Rosette Nebula, for a uniform electron density of about 12 cm -3. The dust shell that surrounds the Rosette H ii region is clearly observed in the Planck intensity map at 353 GHz, with a polarization signal significantly different from that of the local background when considered asa whole. The Planck observations constrain the plane-of-the-sky orientation of the magnetic field in the Rosette’s parent molecular cloud to be mostly aligned with the large-scale field along the Galactic plane. The Planck data are compared with the analytical model, which predicts the mean polarization properties of a spherical and uniform dust shell for a given orientation of the field. This comparison leads to an upper limit of about 45° on the angle between the line of sight and the magnetic field in the Rosette complex, for an assumed intrinsic dust polarization fraction of 4%. This field direction can reproduce the RM values detected in the ionized region if the magnetic field strength in the Monoceros molecular cloud is in the range 6.5–9 μG. Finally, the present analytical model is able to reproduce the RM distribution across the ionized nebula, as well as the mean dust polarization properties of the swept-up shell, and can be directly applied to other similar objects.« less

Cooperative effects in spherical spasers: Ab initio analytical model

NASA Astrophysics Data System (ADS)

Bordo, V. G.

2017-06-01

A fully analytical semiclassical theory of cooperative optical processes which occur in an ensemble of molecules embedded in a spherical core-shell nanoparticle is developed from first principles. Both the plasmonic Dicke effect and spaser generation are investigated for the designs in which a shell/core contains an arbitrarily large number of active molecules in the vicinity of a metallic core/shell. An essential aspect of the theory is an ab initio account of the feedback from the core/shell boundaries which significantly modifies the molecular dynamics. The theory provides rigorous, albeit simple and physically transparent, criteria for both plasmonic superradiance and surface plasmon generation.

Metal shell technology based upon hollow jet instability. [for inertial confinement fusion

NASA Technical Reports Server (NTRS)

Kendall, J. M.; Lee, M. C.; Wang, T. G.

1982-01-01

Spherical shells of submillimeter size are sought as ICF targets. Such shells must be dimensionally precise, smooth, of high strength, and composed of a high atomic number material. A technology for the production of shells based upon the hydrodynamic instability of an annular jet of molten metal is described. Shells in the 0.7-2.0 mm size range have been produced using tin as a test material. Specimens exhibit good sphericity, fair concentricity, and excellent finish over most of the surface. Work involving a gold-lead-antimony alloy is in progress. Droplets of this are amorphous and possess superior surface finish. The flow of tin models that of the alloy well; experiments on both metals show that the technique holds considerable promise.

On the shape and orientation control of an orbiting shallow spherical shell structure

NASA Technical Reports Server (NTRS)

Bainum, P. M.; Reddy, A. S. S. R.

1982-01-01

The dynamics of orbiting shallow flexible spherical shell structures under the influence of control actuators was studied. Control laws are developed to provide both attitude and shape control of the structure. The elastic modal frequencies for the fundamental and lower modes are closely grouped due to the effect of the shell curvature. The shell is gravity stabilized by a spring loaded dumbbell type damper attached at its apex. Control laws are developed based on the pole clustering techniques. Savings in fuel consumption can be realized by using the hybrid shell dumbbell system together with point actuators. It is indicated that instability may result by not including the orbital and first order gravity gradient effects in the plant prior to control law design.

A Numeric Study of the Dependence of the Surface Temperature of Beta-Layered Regions on Absolute Thickness

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ebey, Peter S.; Asaki, Thomas J.; Hoffer, James K.

2000-01-15

Beta-layering of deuterium-tritium (D-T) ice in spherical shell geometries is numerically and analytically considered to investigate the relationship between temperature differences that arise because of inner-surface perturbations and the absolute shell thickness. The calculations use dimensions based on a proposed design of an inertial confinement fusion target for use at the National Ignition Facility. The temperature differences are calculated within D-T ice shells of varying total thicknesses, and the temperature differences calculated in three dimensions are compared both to the one-dimensional results and to the expected limits in three dimensions for long- and short-wavelength surface perturbations. The three-dimensional numeric resultsmore » agree well with both the long- and short-wavelength limits; the region of crossover from short- to long-wavelength behavior is mapped out. Temperature differences due to surface perturbations are proportional to D-T layer thickness in one-dimensional systems but not in three-dimensional spherical shells. In spherical shells, surface perturbations of long wavelength give rise to temperature perturbations that are approximately proportional to the total shell thickness, while for short-wavelength perturbations, the temperature differences are inversely related to total shell thickness. In contrast to the one-dimensional result, we find that in three dimensions there is not a general relationship between shell thickness and surface temperature differences.« less

Direct solution for thermal stresses in a nose cap under an arbitrary axisymmetric temperature distribution

NASA Technical Reports Server (NTRS)

Davis, Randall C.

1988-01-01

The design of a nose cap for a hypersonic vehicle is an iterative process requiring a rapid, easy to use and accurate stress analysis. The objective of this paper is to develop such a stress analysis technique from a direct solution of the thermal stress equations for a spherical shell. The nose cap structure is treated as a thin spherical shell with an axisymmetric temperature distribution. The governing differential equations are solved by expressing the stress solution to the thermoelastic equations in terms of a series of derivatives of the Legendre polynomials. The process of finding the coefficients for the series solution in terms of the temperature distribution is generalized by expressing the temperature along the shell and through the thickness as a polynomial in the spherical angle coordinate. Under this generalization the orthogonality property of the Legendre polynomials leads to a sequence of integrals involving powers of the spherical shell coordinate times the derivative of the Legendre polynomials. The coefficients of the temperature polynomial appear outside of these integrals. Thus, the integrals are evaluated only once and their values tabulated for use with any arbitrary polynomial temperature distribution.

Time-frequency analysis of the bistatic acoustic scattering from a spherical elastic shell.

PubMed

Anderson, Shaun D; Sabra, Karim G; Zakharia, Manell E; Sessarego, Jean-Pierre

2012-01-01

The development of low-frequency sonar systems, using, for instance, a network of autonomous systems in unmanned vehicles, provides a practical means for bistatic measurements (i.e., when the source and receiver are widely separated) allowing for multiple viewpoints of the target of interest. Time-frequency analysis, in particular, Wigner-Ville analysis, takes advantage of the evolution time dependent aspect of the echo spectrum to differentiate a man-made target, such as an elastic spherical shell, from a natural object of the similar shape. A key energetic feature of fluid-loaded and thin spherical shell is the coincidence pattern, also referred to as the mid-frequency enhancement (MFE), that results from antisymmetric Lamb-waves propagating around the circumference of the shell. This article investigates numerically the bistatic variations of the MFE with respect to the monostatic configuration using the Wigner-Ville analysis. The observed time-frequency shifts of the MFE are modeled using a previously derived quantitative ray theory by Zhang et al. [J. Acoust. Soc. Am. 91, 1862-1874 (1993)] for spherical shell's scattering. Additionally, the advantage of an optimal array beamformer, based on joint time delays and frequency shifts is illustrated for enhancing the detection of the MFE recorded across a bistatic receiver array when compared to a conventional time-delay beamformer. © 2012 Acoustical Society of America.

Synthesis of stiffened shells of revolution

NASA Technical Reports Server (NTRS)

Thornton, W. A.

1974-01-01

Computer programs for the synthesis of shells of various configurations were developed. The conditions considered are: (1) uniform shells (mainly cones) using a membrane buckling analysis, (2) completely uniform shells (cones, spheres, toroidal segments) using linear bending prebuckling analysis, and (3) revision of second design process to reduce the number of design variables to about 30 by considering piecewise uniform designs. A perturbation formula was derived and this allows exact derivatives of the general buckling load to be computed with little additional computer time.

Interplay of spherical closed shells and N /Z asymmetry in quasifission dynamics

NASA Astrophysics Data System (ADS)

Mohanto, G.; Hinde, D. J.; Banerjee, K.; Dasgupta, M.; Jeung, D. Y.; Simenel, C.; Simpson, E. C.; Wakhle, A.; Williams, E.; Carter, I. P.; Cook, K. J.; Luong, D. H.; Palshetkar, C. S.; Rafferty, D. C.

2018-05-01

Background: Quasifission (QF) has gained tremendous importance in heavy-ion nuclear physics research because of its strong influence on superheavy-element synthesis. Collisions involving closed-shell nuclei in the entrance channel are found to affect the QF reaction mechanism. Hence, it is important to improve the understanding of their effect on QF. Apart from that, some recent studies show that the difference in N /Z of reaction partners influences the reaction dynamics. Since heavier doubly magic nuclei have different N /Z than lighter doubly magic nuclei, it is important to understand the effect of N /Z mismatch as well as the effect of shell closures. Purpose: To investigate the effect of entrance-channel shell closures and N /Z asymmetry on QF. The reactions were chosen to decouple these effects from the contributions of other entrance-channel parameters. Method: Fission fragment mass-angle distributions were measured using the CUBE fission spectrometer, consisting of two large area position-sensitive multi-wire proportional counters (MWPCs), for five reactions, namely, 50Cr+208Pb , 52Cr+Pb,208206 , 54Cr+Pb,208204 . Result: Two components were observed in the measured fragment mass angle distribution, a fast mass-asymmetric quasifission and a slow mass-symmetric component having a less significant mass-angle correlation. The ratio of these components was found to depend on spherical closed shells in the entrance channel nuclei and the magnitude of the N /Z mismatch between the two reaction partners, as well as the beam energy. Conclusions: Entrance-channel spherical closed shells can enhance compound nucleus formation provided the N /Z asymmetry is small. Increase in the N /Z asymmetry is expected to destroy the effect of entrance-channel spherical closed shells, through nucleon transfer reactions.

Asymmetric Flasklike Hollow Carbonaceous Nanoparticles Fabricated by the Synergistic Interaction between Soft Template and Biomass.

PubMed

Chen, Chunhong; Wang, Haiyan; Han, Chuanlong; Deng, Jiang; Wang, Jing; Li, Mingming; Tang, Minghui; Jin, Haiyan; Wang, Yong

2017-02-22

The soft template method is broadly applied to the fabrication of hollow-structured nanomaterials. However, due to the instability and the typical spherical shape of these soft templates, the resultant particles have a spherical morphology with a wide size distribution. Herein, we developed a sustainable route to fabricate asymmetric flasklike hollow carbonaceous structures with a highly uniform morphology and a narrow size distribution using the soft template method. A dynamic growth mechanism induced by the synergetic interactions between template and biomass is proposed. The precursors (ribose) provide an acidic environment for sodium oleate during the hydrothermal process in which oleic acid nanoemulsions are initially formed and serve as both template and benign solvent for the amphiphilic derivatives of the precursor. Simultaneously, the cosurfactant P123 facilitates the uniform dispersion of the nanoemulsion and is believed to cause the carbonaceous shells to rupture, providing openings through which the intermediates can enter. These subtle interactions facilitate the formation of the flasklike, asymmetric, hollow, carbonaceous nanoparticles. Furthermore, this unique structure contributes to the high surface area (2335 m 2 g -1 ) of the flasklike carbon particles, which enhances the performance of supercapacitors. These findings may open up an exciting field for exploring anisotropic carbonaceous nanomaterials and for understanding the related mechanisms to provide guidance for the design of increasingly complex carbonaceous materials.

OWL: A code for the two-center shell model with spherical Woods-Saxon potentials

NASA Astrophysics Data System (ADS)

Diaz-Torres, Alexis

2018-03-01

A Fortran-90 code for solving the two-center nuclear shell model problem is presented. The model is based on two spherical Woods-Saxon potentials and the potential separable expansion method. It describes the single-particle motion in low-energy nuclear collisions, and is useful for characterizing a broad range of phenomena from fusion to nuclear molecular structures.

Optical absorption of carbon-gold core-shell nanoparticles

NASA Astrophysics Data System (ADS)

Wang, Zhaolong; Quan, Xiaojun; Zhang, Zhuomin; Cheng, Ping

2018-01-01

In order to enhance the solar thermal energy conversion efficiency, we propose to use carbon-gold core-shell nanoparticles dispersed in liquid water. This work demonstrates theoretically that an absorbing carbon (C) core enclosed in a plasmonic gold (Au) nanoshell can enhance the absorption peak while broadening the absorption band; giving rise to a much higher solar absorption than most previously studied core-shell combinations. The exact Mie solution is used to evaluate the absorption efficiency factor of spherical nanoparticles in the wavelength region from 300 nm to 1100 nm as well as the electric field and power dissipation profiles inside the nanoparticles at specified wavelengths (mostly at the localized surface plasmon resonance wavelength). The field enhancement by the localized plasmons at the gold surfaces boosts the absorption of the carbon particle, resulting in a redshift of the absorption peak with increased peak height and bandwidth. In addition to spherical nanoparticles, we use the finite-difference time-domain method to calculate the absorption of cubic core-shell nanoparticles. Even stronger enhancement can be achieved with cubic C-Au core-shell structures due to the localized plasmonic resonances at the sharp edges of the Au shell. The solar absorption efficiency factor can exceed 1.5 in the spherical case and reach 2.3 in the cubic case with a shell thickness of 10 nm. Such broadband absorption enhancement is in great demand for solar thermal applications including steam generation.

Calcium hydroxide coating on highly reactive nanoscale zero-valent iron for in situ remediation application.

PubMed

Wei, Cai-Jie; Xie, Yue-Feng; Wang, Xiao-Mao; Li, Xiao-Yan

2018-05-23

Nano scale zero-valent iron (nZVI), a promising engineering technology for in situ remediation, has been greatly limited by quick self-corrosion and low mobility in porous media. Highly reactive nZVI particles produced from the borohydride reduction method were enclosed in a releasable Ca(OH) 2 layer by the chemical deposition method. The amount of Ca(OH) 2 coated on nZVI surface were well controlled by the precursor dosage. At moderate Ca(OH) 2 dosage (R Ca/TFe  = 0.25) condition, the increment of Fe 0 content for the obtained nZVI/Ca-0.25 sample was observed. The interfacial reactions between the iron oxide shell and the Ca(OH) 2 saturated environment were delicately elucidated by the X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) spectrum. And the coverage of Ca(OH) 2 shell on spherical nZVI surface was found more complete and uniform for the nZVI/Ca sample obtained from the moderate precursor dosage condition (R Ca/TFe  = 0.25). The Ca(OH) 2 shell before dissolution was demonstrated owning the anti-corrosion capability to slow down the oxidation of Fe 0 core in air, during ethanol storage and in aqueous environment. The mechanism of anti-corrosion capability for nZVI/Ca-0.25 particle was interestingly found to be attributed to the Ca(OH) 2 shell isolation and also be potentially due to the iron oxide shell phase transformation mediated by the outer Ca(OH) 2 shell. An improved trichloroethylene reduction performance was observed for nZVI/Ca-0.25 than bare nZVI. The mobility of nZVI/Ca particles in water-saturated porous media was moderately improved before shell dissolution. Copyright © 2018 Elsevier Ltd. All rights reserved.

Structural analysis of Fe–Mn–O nanoparticles in glass ceramics by small angle scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raghuwanshi, Vikram Singh, E-mail: vikram.raghuwanshi@helmholtz-berlin.de; Harizanova, Ruzha; Tatchev, Dragomir

2015-02-15

Magnetic nanocrystals containing Fe and Mn were obtained by annealing of silicate glasses with the composition 13.6Na{sub 2}O–62.9SiO{sub 2}–8.5MnO–15.0Fe{sub 2}O{sub 3−x} (mol%) at 580 °C for different periods of time. Here, we present Small Angle Neutron Scattering using Polarized neutrons (SANSPOL) and Anomalous Small Angle X-ray Scattering (ASAXS) investigation on these glass ceramic samples. Analysis of scattering data from both methods reveals the formation of spherical core–shell type of nanoparticles with mean sizes between 10 nm and 100 nm. ASAXS investigation shows the particles have higher concentration of iron atoms and the shell like region surrounding the particles is enrichedmore » in SiO{sub 2}. SANSPOL investigation shows the particles are found to be magnetic and are surrounded by a non-magnetic shell-like region. - Graphical abstract: Magnetic spherical core–shell nanoparticles in glass ceramics: SANSPOL and ASAXS investigations. - Highlights: • Formation and growth mechanisms of magnetic nanoparticles in silicate glass. • SANSPOL and ASAXS methods employed to evaluate quantitative information. • Analyses showed formation of nanoparticles with spherical core–shell structures. • Core of the particle is magnetic and surrounded by weak magnetic shell like region.« less

Polaronic effects on the off-center donor impurity in AlAs/GaAs/SiO2 spherical core/shell quantum dots

NASA Astrophysics Data System (ADS)

El Haouari, M.; Feddi, E.; Dujardin, F.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.

2017-11-01

The ground state of a conduction electron coupled to an off-center impurity donor in a AlAS/GaAs spherical core/shell quantum dot is investigated theoretically. The image-charge effect and the influence of the electron-polar-LO-phonon interaction are considered. The electron-impurity binding energy is calculated via a variational procedure and is reported both as a function of the shell width and of the radial position of the donor atom. The polaronic effects on this quantity are particularly discussed.

Family of spherical models with special gravitational properties

NASA Astrophysics Data System (ADS)

Kondratyev, B. P.

2015-03-01

A new method for studying the structural and gravitational properties of spherical systems based on an analysis of the ratio of the potentials for their subsystems and shells has been developed. It has been proven for the first time that the gravitational virial Z( r) of the subsystem without allowance for the influence of the outer shell is equal to twice the work done to disperce the subsystem's matter to infinity. A new class of spherical models has been constructed in which: (1) the ratio of the contribution to the potential at point r from the spherical subsystem to the contribution from the outer shell does not depend on radius and is equal to a constant γ; (2) the ratio of the gravitational energy W( r) to Z( r) for the spherical subsystem does not depend on r; and (3) the models are described by a power law of the density ρ = cr - κ and potential . Expressions for the gravitational energy W( r) and virial Z( r) have been found for the subsystem. The limiting case of ρ( r) ∝ r -5/2, where the subsystem's potential at any sampling point is exactly equal to the potential from the outer shell and Z( r) is equivalent to its gravitational energy W( r), is considered in detail. The results supplement the classical potential theory. The question about the application of the models to the superdense nuclear star cluster in the center of the Milky Way is discussed.

Early post-mortem formation of carbonate concretions around tusk-shells over week-month timescales

NASA Astrophysics Data System (ADS)

Yoshida, Hidekazu; Ujihara, Atsushi; Minami, Masayo; Asahara, Yoshihiro; Katsuta, Nagayoshi; Yamamoto, Koshi; Sirono, Sin-Iti; Maruyama, Ippei; Nishimoto, Shoji; Metcalfe, Richard

2015-09-01

Carbonate concretions occur in sedimentary rocks of widely varying geological ages throughout the world. Many of these concretions are isolated spheres, centered on fossils. The formation of such concretions has been variously explained by diffusion of inorganic carbon and organic matter in buried marine sediments. However, details of the syn-depositional chemical processes by which the isolated spherical shape developed and the associated carbon sources are little known. Here we present evidence that spherical carbonate concretions (diameters φ : 14 ~ 37 mm) around tusk-shells (Fissidentalium spp.) were formed within weeks or months following death of the organism by the seepage of fatty acid from decaying soft body tissues. Characteristic concentrations of carbonate around the mouth of a tusk-shell reveal very rapid formation during the decay of organic matter from the tusk-shell. Available observations and geochemical evidence have enabled us to construct a ‘Diffusion-growth rate cross-plot’ that can be used to estimate the growth rate of all kinds of isolated spherical carbonate concretions identified in marine formations. Results shown here suggest that isolated spherical concretions that are not associated with fossils might also be formed from carbon sourced in the decaying soft body tissues of non-skeletal organisms with otherwise low preservation potential.

Analysis of two colliding fractionally damped spherical shells in modelling blunt human head impacts

NASA Astrophysics Data System (ADS)

Rossikhin, Yury A.; Shitikova, Marina V.

2013-06-01

The collision of two elastic or viscoelastic spherical shells is investigated as a model for the dynamic response of a human head impacted by another head or by some spherical object. Determination of the impact force that is actually being transmitted to bone will require the model for the shock interaction of the impactor and human head. This model is indended to be used in simulating crash scenarios in frontal impacts, and provide an effective tool to estimate the severity of effect on the human head and to estimate brain injury risks. The model developed here suggests that after the moment of impact quasi-longitudinal and quasi-transverse shock waves are generated, which then propagate along the spherical shells. The solution behind the wave fronts is constructed with the help of the theory of discontinuities. It is assumed that the viscoelastic features of the shells are exhibited only in the contact domain, while the remaining parts retain their elastic properties. In this case, the contact spot is assumed to be a plane disk with constant radius, and the viscoelastic features of the shells are described by the fractional derivative standard linear solid model. In the case under consideration, the governing differential equations are solved analytically by the Laplace transform technique. It is shown that the fractional parameter of the fractional derivative model plays very important role, since its variation allows one to take into account the age-related changes in the mechanical properties of bone.

Nuclear mass formula with the shell energies obtained by a new method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koura, H.; Tachibana, T.; Yamada, M.

1998-12-21

Nuclear shapes and masses are estimated by a new method. The main feature of this method lies in estimating shell energies of deformed nuclei from spherical shell energies by mixing them with appropriate weights. The spherical shell energies are calculated from single-particle potentials, and, till now, two mass formulas have been constructed from two different sets of potential parameters. The standard deviation of the calculated masses from all the experimental masses of the 1995 Mass Evaluation is about 760 keV. Contrary to the mass formula by Tachibana, Uno, Yamada and Yamada in the 1987-1988 Atomic Mass Predictions, the present formulasmore » can give nuclear shapes and predict on super-heavy elements.« less

Faraday Wave Turbulence on a Spherical Liquid Shell

NASA Technical Reports Server (NTRS)

Holt, R. Glynn; Trinh, Eugene H.

1996-01-01

Millimeter-radius liquid shells are acoustically levitated in an ultrasonic field. Capillary waves are observed on the shells. At low energies (minimal acoustic amplitude, thick shell) a resonance is observed between the symmetric and antisymmetric thin film oscillation modes. At high energies (high acoustic pressure, thin shell) the shell becomes fully covered with high-amplitude waves. Temporal spectra of scattered light from the shell in this regime exhibit a power-law decay indicative of turbulence.

Ion beam inertial confinement target

DOEpatents

Bangerter, Roger O.; Meeker, Donald J.

1985-01-01

A target for implosion by ion beams composed of a spherical shell of frozen DT surrounded by a low-density, low-Z pusher shell seeded with high-Z material, and a high-density tamper shell. The target has various applications in the inertial confinement technology. For certain applications, if desired, a low-density absorber shell may be positioned intermediate the pusher and tamper shells.

Synthesis of nanostructured/macroscopic low-density copper foams based on metal-coated polymer core–shell particles [Templated synthesis of nanowalled low-density copper foams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Sung Ho; Bazin, Nick; Shaw, Jessica I.

A robust, millimeter-sized low-density Cu foam with ~90% (v/v) porosity, ~30 nm thick walls, and ~1 μm diameter spherical pores is prepared by the slip-casting of metal-coated polymer core–shell particles followed by a thermal removal of the polymer. In this paper, we report our key findings that enable the development of the low-density Cu foams. First, we need to synthesize polystyrene (PS) particles coated with a very thin Cu layer (in the range of tens of nanometers). A simple reduction in the amount of Cu deposited onto the PS was not sufficient to form such a low-density Cu foams duemore » to issues related to foam collapse and densification upon the subsequent polymer removal step. Precise control over the morphology of the Cu coating on the particles is essential for the synthesis of a lower density of foams. Second, improving the dispersion of PS–Cu particles in a suspension used for the casting as well as careful optimization of a baking condition minimize the formation of irregular large voids, leading to Cu foams with a more uniform packing and a better connectivity of neighboring Cu hollow shells. Finally, we analyzed mechanical properties of the Cu foams with a depth-sensing indentation test. The uniform Cu foams show a significant improvement in mechanical properties (~1.5× modulus and ~3× hardness) compared to those of uncontrolled foam samples with a similar foam density but irregular large voids. As a result, higher surface areas and a good electric conductivity of the Cu foams present a great potential to future applications.« less

Synthesis of nanostructured/macroscopic low-density copper foams based on metal-coated polymer core–shell particles [Templated synthesis of nanowalled low-density copper foams

DOE PAGES

Kim, Sung Ho; Bazin, Nick; Shaw, Jessica I.; ...

2016-12-06

A robust, millimeter-sized low-density Cu foam with ~90% (v/v) porosity, ~30 nm thick walls, and ~1 μm diameter spherical pores is prepared by the slip-casting of metal-coated polymer core–shell particles followed by a thermal removal of the polymer. In this paper, we report our key findings that enable the development of the low-density Cu foams. First, we need to synthesize polystyrene (PS) particles coated with a very thin Cu layer (in the range of tens of nanometers). A simple reduction in the amount of Cu deposited onto the PS was not sufficient to form such a low-density Cu foams duemore » to issues related to foam collapse and densification upon the subsequent polymer removal step. Precise control over the morphology of the Cu coating on the particles is essential for the synthesis of a lower density of foams. Second, improving the dispersion of PS–Cu particles in a suspension used for the casting as well as careful optimization of a baking condition minimize the formation of irregular large voids, leading to Cu foams with a more uniform packing and a better connectivity of neighboring Cu hollow shells. Finally, we analyzed mechanical properties of the Cu foams with a depth-sensing indentation test. The uniform Cu foams show a significant improvement in mechanical properties (~1.5× modulus and ~3× hardness) compared to those of uncontrolled foam samples with a similar foam density but irregular large voids. As a result, higher surface areas and a good electric conductivity of the Cu foams present a great potential to future applications.« less

Light-weight spherical submergence vessel

NASA Technical Reports Server (NTRS)

Baker, I.

1974-01-01

Design vessel with very low thickness-to-radius ratio to obtain low weight, and fabricate it with aid of precision tracer-lathe to limit and control imperfections in spherical shape. Vessel is thin-walled, spherical, monocoque shell constructed from hemispheres joined with sealed and bolted meridional flange.

Confinement dynamics of a semiflexible chain inside nano-spheres

NASA Astrophysics Data System (ADS)

Fathizadeh, A.; Heidari, Maziar; Eslami-Mossallam, B.; Ejtehadi, M. R.

2013-07-01

We study the conformations of a semiflexible chain, confined in nano-scaled spherical cavities, under two distinct processes of confinement. Radial contraction and packaging are employed as two confining procedures. The former method is performed by gradually decreasing the diameter of a spherical shell which envelopes a confined chain. The latter procedure is carried out by injecting the chain inside a spherical shell through a hole on the shell surface. The chain is modeled with a rigid body molecular dynamics simulation and its parameters are adjusted to DNA base-pair elasticity. Directional order parameter is employed to analyze and compare the confined chain and the conformations of the chain for two different sizes of the spheres are studied in both procedures. It is shown that for the confined chains in the sphere sizes of our study, they appear in spiral or tennis-ball structures, and the tennis-ball structure is more likely to be observed in more compact confinements. Our results also show that the dynamical procedure of confinement and the rate of the confinement are influential parameters of the structure of the chain inside spherical cavities.

Search for the Exotic Wobbling Mode in Rhenium-171

DTIC Science & Technology

2011-05-13

USB hard drive. The decay sequences mentioned above release all of their γ rays within a nanosecond (ns). Data will be recorded when multiple ...events in which multiple detectors measured γ rays within a 120 ns window. An event in which three detectors fired within the coincidence window is...spherical nuclei; however, if the nucleus is axially deformed (non-spherical), the shell model cannot accurately describe its features . The shell model

Symmetry tuning of a near one-dimensional 2-shock platform for code validation at the National Ignition Facility

DOE PAGES

Khan, S. F.; MacLaren, S. A.; Salmonson, J. D.; ...

2016-04-27

Here, we introduce a new quasi 1-D implosion experimental platform at the National Ignition Facility designed to validate physics models as well as to study various Inertial Confinement Fusion aspects such as implosion symmetry, convergence, hydrodynamic instabilities, and shock timing. The platform has been developed to maintain shell sphericity throughout the compression phase and produce a round hot core at stagnation. This platform utilizes a 2-shock 1 MJ pulse with 340 TW peak power in a near-vacuum AuHohlraum and a CH ablator capsule uniformly doped with 1% Si. We also performed several inflight radiography, symmetry capsule, and shock timing experimentsmore » in order to tune the symmetry of the capsule to near round throughout several epochs of the implosion. Finally, adjusting the relative powers of the inner and outer cones of beams has allowed us to control the drive at the poles and equator of the capsule, thus providing the mechanism to achieve a spherical capsule convergence. Details and results of the tuning experiments are described.« less

Shape Engineering of Biomass-Derived Nanoparticles from Hollow Spheres to Bowls via Solvent-Induced Buckling.

PubMed

Chen, Chunhong; Li, Xuefeng; Jiang, Deng; Wang, Zhe; Wang, Yong

2018-06-19

To realize the asymmetry for the hollow carbonaceous nanostructures remains to be a great challenge, especially when biomass is chosen as the carbon resource via hydrothermal carbonization (HTC). Herein, a simple and straightforward solvent induced buckling strategy is demonstrated for the synthesis of asymmetric spherical and bowllike carbonaceous nanomaterials. The formation of the bowllike morphology was attributed to the buckling of the spherical shells induced by the dissolution of the oligomers. The bowllike particles made by this solvent-driven approach demonstrated a well-controlled morphology and a uniform particle size of ~360 nm. The obtained nanospheres and nanobowls can be loaded with CoS2 nanoparticles to act as novel heterogeneous catalysts for the selective hydrogenation of aromatic nitro compounds. With the bowllike structure in hand, as expected, the CoS2/nanobowls catalyst showed good tolerance to a wide scope of reducible groups and afforded both high activity and selectivity in almost all the tested substrates (14). © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Averaged ratio between complementary profiles for evaluating shape distortions of map projections and spherical hierarchical tessellations

NASA Astrophysics Data System (ADS)

Yan, Jin; Song, Xiao; Gong, Guanghong

2016-02-01

We describe a metric named averaged ratio between complementary profiles to represent the distortion of map projections, and the shape regularity of spherical cells derived from map projections or non-map-projection methods. The properties and statistical characteristics of our metric are investigated. Our metric (1) is a variable of numerical equivalence to both scale component and angular deformation component of Tissot indicatrix, and avoids the invalidation when using Tissot indicatrix and derived differential calculus for evaluating non-map-projection based tessellations where mathematical formulae do not exist (e.g., direct spherical subdivisions), (2) exhibits simplicity (neither differential nor integral calculus) and uniformity in the form of calculations, (3) requires low computational cost, while maintaining high correlation with the results of differential calculus, (4) is a quasi-invariant under rotations, and (5) reflects the distortions of map projections, distortion of spherical cells, and the associated distortions of texels. As an indicator of quantitative evaluation, we investigated typical spherical tessellation methods, some variants of tessellation methods, and map projections. The tessellation methods we evaluated are based on map projections or direct spherical subdivisions. The evaluation involves commonly used Platonic polyhedrons, Catalan polyhedrons, etc. Quantitative analyses based on our metric of shape regularity and an essential metric of area uniformity implied that (1) Uniform Spherical Grids and its variant show good qualities in both area uniformity and shape regularity, and (2) Crusta, Unicube map, and a variant of Unicube map exhibit fairly acceptable degrees of area uniformity and shape regularity.

MagIC: Fluid dynamics in a spherical shell simulator

NASA Astrophysics Data System (ADS)

Wicht, J.; Gastine, T.; Barik, A.; Putigny, B.; Yadav, R.; Duarte, L.; Dintrans, B.

2017-09-01

MagIC simulates fluid dynamics in a spherical shell. It solves for the Navier-Stokes equation including Coriolis force, optionally coupled with an induction equation for Magneto-Hydro Dynamics (MHD), a temperature (or entropy) equation and an equation for chemical composition under both the anelastic and the Boussinesq approximations. MagIC uses either Chebyshev polynomials or finite differences in the radial direction and spherical harmonic decomposition in the azimuthal and latitudinal directions. The time-stepping scheme relies on a semi-implicit Crank-Nicolson for the linear terms of the MHD equations and a Adams-Bashforth scheme for the non-linear terms and the Coriolis force.

Spherically-symmetric solutions in general relativity using a tetrad-based approach

NASA Astrophysics Data System (ADS)

Kim, Do Young; Lasenby, Anthony N.; Hobson, Michael P.

2018-03-01

We present a tetrad-based method for solving the Einstein field equations for spherically-symmetric systems and compare it with the widely-used Lemaître-Tolman-Bondi (LTB) model. In particular, we focus on the issues of gauge ambiguity and the use of comoving versus `physical' coordinate systems. We also clarify the correspondences between the two approaches, and illustrate their differences by applying them to the classic examples of the Schwarzschild and Friedmann-Lemaître-Robertson-Walker spacetimes. We demonstrate that the tetrad-based method does not suffer from the gauge freedoms inherent to the LTB model, naturally accommodates non-uniform pressure and has a more transparent physical interpretation. We further apply our tetrad-based method to a generalised form of `Swiss cheese' model, which consists of an interior spherical region surrounded by a spherical shell of vacuum that is embedded in an exterior background universe. In general, we allow the fluid in the interior and exterior regions to support pressure, and do not demand that the interior region be compensated. We pay particular attention to the form of the solution in the intervening vacuum region and illustrate the validity of Birkhoff's theorem at both the metric and tetrad level. We then reconsider critically the original theoretical arguments underlying the so-called Rh = ct cosmological model, which has recently received considerable attention. These considerations in turn illustrate the interesting behaviour of a number of `horizons' in general cosmological models.

Double-shell CuS nanocages as advanced supercapacitor electrode materials

NASA Astrophysics Data System (ADS)

Guo, Jinxue; Zhang, Xinqun; Sun, Yanfang; Zhang, Xiaohong; Tang, Lin; Zhang, Xiao

2017-07-01

Metal sulfides hollow structures are advanced materials for energy storage applications of lithium-ion batteries and supercapacitors. However, constructing hollow metal sulfides with specific features, such as multi-shell and non-spherical shape, still remains great challenge. In this work, we firstly demonstrate the synthesis of CuS double-shell hollow nanocages using Cu2O nanocubes as precursors. The synthesis processes involve the repeated anion exchange reaction with Na2S and the controllable etching using hydrochloric acid. The whole synthesis processes are well revealed and the obtained double-shell CuS is tested as pseudocapacitive electrode material for supercapacitors. As expected, the CuS double-shell hollow nanocages deliver high specific capacitance, good rate performance and excellent cycling stability due to their unique nano-architecture. The present work contributes greatly to the exploration of hollow metal sulfides with complex architecture and non-spherical shape, as well as their promising application in high-performance electrochemical supercapacitors.

Nuclear tetrahedral symmetry: possibly present throughout the periodic table.

PubMed

Dudek, J; Goźdź, A; Schunck, N; Miśkiewicz, M

2002-06-24

More than half a century after the fundamental, spherical shell structure in nuclei had been established, theoretical predictions indicated that the shell gaps comparable or even stronger than those at spherical shapes may exist. Group-theoretical analysis supported by realistic mean-field calculations indicate that the corresponding nuclei are characterized by the TD(d) ("double-tetrahedral") symmetry group. Strong shell-gap structure is enhanced by the existence of the four-dimensional irreducible representations of TD(d); it can be seen as a geometrical effect that does not depend on a particular realization of the mean field. Possibilities of discovering the TD(d) symmetry in experiment are discussed.

Colloidal Spherical Quantum Wells with Near-Unity Photoluminescence Quantum Yield and Suppressed Blinking.

PubMed

Jeong, Byeong Guk; Park, Young-Shin; Chang, Jun Hyuk; Cho, Ikjun; Kim, Jai Kyeong; Kim, Heesuk; Char, Kookheon; Cho, Jinhan; Klimov, Victor I; Park, Philip; Lee, Doh C; Bae, Wan Ki

2016-10-02

Thick inorganic shell endows colloidal nanocrystals (NCs) with enhanced photochemical stability and suppression of photoluminescence intermittency (also known as blinking). However, the progress of using thick-shell heterostructure NCs in applications has been limited, due to low photoluminescence quantum yield (PL QY  60%) at room temperature. Here, we demonstrate thick-shell NCs with CdS/CdSe/CdS seed/spherical quantum well/shell (SQW) geometry that exhibit near-unity PL QY at room temperature and suppression of blinking. In SQW NCs, the lattice mismatch is diminished between the emissive CdSe layer and the surrounding CdS layers as a result of coherent strain, which suppresses the formation of misfit defects and consequently permits ~ 100% PL QY for SQW NCs with thick CdS shell (≥ 5 nm). High PL QY of thick-shell SQW NCs are preserved even in concentrated dispersion and in film under thermal stress, which makes them promising candidates for applications in solid-state lightings and luminescent solar concentrators.

The Case of the Disappearing Magnetic Dipole

ERIC Educational Resources Information Center

Gough, W.

2008-01-01

The problem of an oscillating magnetic dipole at the centre of a lossless dielectric spherical shell is considered. For simplicity, the free-space wavelength is taken to be much greater than the shell radii, but the relative permittivity [epsilon][subscript r] of the shell is taken as much greater than unity, so the wavelength in the shell could…

Excimers from stable and persistent supramolecular radical-pairs in red/NIR-emitting organic nanoparticles and polymeric films.

PubMed

Blasi, Davide; Nikolaidou, Domna M; Terenziani, Francesca; Ratera, Imma; Veciana, Jaume

2017-03-29

In this work, the luminescence properties of new materials based on open-shell molecular systems are studied. In particular, we prepared polymeric films and organic nanoparticles (ONPs) doped with triphenylmethyl radical molecules. ONPs exhibit a uniform size distribution, spherical morphology and high colloidal stability. The emission spectrum of low-doped ONP suspensions and low-doped films is very similar to the emission spectrum of TTM in solution, while the luminescence lifetime and the luminescence quantum yield (LQY) are highly increased. Increasing the radical doping leads to a progressive decrease of the LQY and the appearance of a new broad excimeric band at longer wavelengths, both for ONPs and films. Thus, not only the luminescence properties were improved, but also the formation of excimers from stable and persistent supramolecular radical-pairs was observed for the first time. The good stability and luminescence properties with emission in the red-NIR region (650-800 nm), together with the open-shell nature of the emitter, make these free-radical excimer-forming materials promising candidates for optoelectronic and bioimaging applications.

Soft particles at fluid interfaces: wetting, structure, and rheology

NASA Astrophysics Data System (ADS)

Isa, Lucio

Most of our current knowledge concerning the behavior of colloidal particles at fluid interfaces is limited to model spherical, hard and uniform objects. Introducing additional complexity, in terms of shape, composition or surface chemistry or by introducing particle softness, opens up a vast range of possibilities to address new fundamental and applied questions in soft matter systems at fluid interfaces. In this talk I will focus on the role of particle softness, taking the case of core-shell microgels as a paradigmatic example. Microgels are highly swollen and cross-linked hydrogel particles that, in parallel with their practical applications, e.g. for emulsion stabilization and surface patterning, are increasingly used as model systems to capture fundamental properties of bulk materials. Most microgel particles develop a core-shell morphology during synthesis, with a more cross-linked core surrounded by a corona of loosely linked and dangling polymer chains. I will first discuss the difference between the wetting of a hard spherical colloid and a core-shell microgel at an oil-water interface, pinpointing the interplay between adsorption at the interface and particle deformation. I will then move on to discuss the interplay between particle morphology and the microstructure and rheological properties of the interface. In particular, I will demonstrate that synchronizing the compression of a core-shell microgel-laden fluid interface with the deposition of the interfacial monolayer makes it possible to transfer the 2D phase diagram of the particles onto a solid substrate, where different positions correspond to different values of the surface pressure and the specific area. Using atomic force microscopy, we analyzed the microstructure of the monolayer and discovered a phase transition between two crystalline phases with the same hexagonal symmetry, but with two different lattice constants. The two phases correspond to shell-shell or core-core inter-particle contacts, respectively, where with increasing surface pressure the former mechanically fail enabling the particle cores to come into contact. In the phase-transition region, clusters of particles in core-core contacts nucleate, melting the surrounding shell-shell crystal, until the whole monolayer moves into the second phase. We furthermore extended our analysis to measure the interfacial rheology of the monolayers as a function of the surface pressure using an interfacial microdisk rheometer; the interfaces always show a strong elastic response, with a dip in the elastic modulus in correspondence of the melting of the shell-shell phase, followed by a steep increase upon formation of a percolating network of the core-core contacts. The presented results highlight the complex interplay between the wetting and deformation of individual soft particles at fluid interfaces and the overall interface microstructure and mechanics. They show strong connections to fundamental studies on phase transitions in two-dimensional systems and pave the way for novel nanoscale surface patterning routes. The author acknowledges financial support from the Swiss National Science Foundation Grant PP00P2-144646/1.

How Spherical Is a Cube (Gravitationally)?

ERIC Educational Resources Information Center

Sanny, Jeff; Smith, David

2015-01-01

An important concept that is presented in the discussion of Newton's law of universal gravitation is that the gravitational effect external to a spherically symmetric mass distribution is the same as if all of the mass of the distribution were concentrated at the center. By integrating over ring elements of a spherical shell, we show that the…

Reconstruction of spherically symmetric objects from slit-imaged emission: limitations due to finite slit width

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mueller, M.M.

1979-11-01

A simple method for reconstructing spherically symmetric objects from slit-imaged emission was recently described by Vest and Steel. Although this method is valid for infinitesimal slit widths and practically noise-free irradiance data, it is shown here that its validity does not extend to slits of practical width in the laser-fusion program. However, a method is given for reducing the Vest--Steel plots with practical apertures to obtain information on core diameter, shell diameter, and shell thickness.

Spherical thin-shell wormholes and modified Chaplygin gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharif, M.; Azam, M., E-mail: msharif.math@pu.edu.pk, E-mail: azammath@gmail.com

2013-05-01

The purpose of this paper is to construct spherical thin-shell wormhole solutions through cut and paste technique and investigate the stability of these solutions in the vicinity of modified Chaplygin gas. The Darmois-Israel formalism is used to formulate the stresses of the surface concentrating the exotic matter. We explore the stability of the wormhole solutions by using the standard potential method. We conclude that there exist more stable as well as unstable solutions than the previous study with generalized Chaplygin gas [19].

Recombination energy for negatively charged excitons inside type-II core/shell spherical quantum dots

NASA Astrophysics Data System (ADS)

Chafai, A.; Essaoudi, I.; Ainane, A.; Dujardin, F.; Ahuja, R.

2018-07-01

The recombination energy of isolated neutral exciton and that of isolated negatively charged exciton inside a type-II core/shell spherical quantum dot are studied. Our investigation considers the charge-carriers effective mass discontinuity at the surface contact between the core and shell materials. Although our model omits the effect of the surface polarization, the dielectric-constant mismatch at the nanodot boundaries was taken into account. In order to achieve the exciton and negative trion energies, we proceed by a variational calculation in the framework of the envelope approximation. Our results reveal a strong correlation between the nanodot morphology and the energy spectrum of the neutral and negatively charged exciton.

Placental Volumetry by 2-D Sonography with a New Mathematical Formula: Prospective Study on the Shell of a Spherical Sector Model.

PubMed

Kozinszky, Zoltan; Surányi, Andrea; Péics, Hajnalka; Molnár, András; Pál, Attila

2015-08-01

The aim of this study was to determine the utility of a new mathematical model in volumetric assessment of the placenta using 2-D ultrasound. Placental volumetry was performed in a prospective cross-sectional survey by virtual organ computer-aided analysis (VOCAL) with the help of a shell-off method in 346 uncomplicated pregnancies according to STROBE (Strengthening the Reporting of Observational Studies in Epidemiology) guidelines. Furthermore, placental thickness, length and height were measured with the 2-D technique to estimate placental volume based on the mathematical formula for the volume of "the shell of the spherical sector." Fetal size was also assessed by 2-D sonography. The placental volumes measured by 2-D and 3-D techniques had a correlation of 0.86. In the first trimester, the correlation was 0.82, and later during pregnancy, it was 0.86. Placental volumetry using "the circle-shaped shell of the spherical sector" mathematical model with 2-D ultrasound technique may be introduced into everyday practice to screen for placental volume deviations associated with adverse pregnancy outcome. Copyright © 2015 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

Quasi-spherical accretion in High Mass X-ray Binaries

NASA Astrophysics Data System (ADS)

Postnov, Konstantin

2016-07-01

Quasi-spherical accreion onto magnetized neutron stars from stellar winds in high-mass X-ray binaries is discussed. Depending on the X-ray luminosity of the neutron star, the accretion can proceed in two regimes (modes): at L_x ≳ 4× 10^{36} erg/s, Compton cooling of accreting matter near magnetosphere leads to a supersonic (Bondi) accretion, while at smaller X-ray luminosity the Compton cooling is ineffective, and subsonic settling accretion regime sets in. In this regime, a hot convective shell is formed around the magnetosphere, and the plasma entry rate into magnetosphere is controlled by less effective radiative plasma cooling. The shell mediates the angular momentum transfer from/to the neutron star magnetosphere. Observational evidences for the different accretion regimes in slowly rotating X-ray pulsars with moderate and low X-ray luminosity, as well as possible manifestations of non-stationary quasi-spherical settling accretion due to the magnetospheric shell instability in Supergiant Fast X-ray Transients will be presented.

Synthesis characterisation series of newly fabricated type II CdSe CdSe/CdTe nanocrystals and their optical properties

NASA Astrophysics Data System (ADS)

Ahmed, A. S.; Christopher, W.

2018-03-01

Nanocrystalline semiconductors exhibit different properties due to two basic factors. They possess high surface to volume ratio and the actual size of particle can determine the electronic and physical properties of the material. The small size results in an observable quantum confinement effect, defined by the increasing bandgap accompanied by the quantization of the energy levels to discrete values. In present work we have synthesized the series of cadmium selenide/cadmium telluride (CdSe/CdTe) core/shell and CdSe/CdTe/CdS core/shell/shell to investigate the biexciton energy through transient absorption measurements. These structures are type II nanocrystals are with a hole in the shell and the electron confined to the core. We specifically investigate the effect of nanoparticle shape on the electronic structure and ultrafast electronic dynamics in the band-edge exciton states of CdSe quantum dots, nanorods, and nanoplatelets. Particle size was chosen to enable straightforward comparisons of the effects of particle shape on the spectra and dynamics without retuning the laser source. In our results the Uv-vis showed only a mild redshift in the first excitonic an elongated tail with increasing shell thickness. High resolution Transmission Electron Microscopy (HRTEM) shows the slight agglomeration of the nanocrystals but still the size distribution was calculate able. Spherical small crystals ranging from 5.9 nm to 10 nm are observed. CdTe/CdSe structures were quasi spherical with a rough diameter 6 nm with some little agglomerated structure. . The spherical nanocrystals could be peanut shaped oriented along the c axis or the spherical only, which could explain the two peak emission. p-XRD results indicate the predominant wurtzite structure throughout.

Collapsing shells and black holes: a quantum analysis

NASA Astrophysics Data System (ADS)

Leal, P.; Bernardini, A. E.; Bertolami, O.

2018-06-01

The quantization of a spherically symmetric null shells is performed and extended to the framework of phase-space noncommutative (NC) quantum mechanics. This shell is considered to be inside a black hole event horizon. The encountered properties are investigated making use of the Israel junction conditions on the shell, considering that it is the boundary between two spherically symmetric spacetimes. Using this method, and considering two different Kantowski–Sachs spacetimes as a representation for the Schwarzschild spacetime, the relevant quantities on the shell are computed, such as its stress-energy tensor and the action for the whole spacetime. From the obtained action, the Wheeler–deWitt equation is deduced in order to provide the quantum framework for the system. Solutions for the wave function of the system are found on both the commutative and NC scenarios. It is shown that, on the commutative version, the wave function has a purely oscillatory behavior in the interior of the shell. In the NC setting, it is shown that the wave function vanishes at the singularity, as well as, at the event horizon of the black hole.

Role of membrane stresses in the support of planetary topography

NASA Technical Reports Server (NTRS)

Turcotte, D. L.; Willemann, R. J.; Haxby, W. F.; Norberry, J.

1981-01-01

The role of membrane stresses and bending stresses in supporting topographic loads on planetary elastic lithospheres is examined. A dimensionless parameter is introduced in order to determine the ability of a spherical shell to support loads through membrane stresses. It is determined that when this parameter is large, membrane stresses can fully support topographic loads with flexure, and when it is small the influence of the membrane stresses can be neglected. Equations governing the behavior of a spherical shell are solved for a topographic load expressed in terms of spherical harmonics, and spherical harmonic expansions of the measured gravity and topography for Mars and the moon are compared with the theory. It is concluded that membrane stresses play an important role in the support of topographic loads on the moon and Mars. The correlation of observed gravitational potential anomalies with the topography on Mars is explained by membrane stresses in the elastic lithosphere.

Axisymmetric inertial modes in a spherical shell at low Ekman numbers

NASA Astrophysics Data System (ADS)

Rieutord, M.; Valdettaro, L.

2018-06-01

We investigate the asymptotic properties of axisymmetric inertial modes propagating in a spherical shell when viscosity tends to zero. We identify three kinds of eigenmodes whose eigenvalues follow very different laws as the Ekman number $E$ becomes very small. First are modes associated with attractors of characteristics that are made of thin shear layers closely following the periodic orbit traced by the characteristic attractor. Second are modes made of shear layers that connect the critical latitude singularities of the two hemispheres of the inner boundary of the spherical shell. Third are quasi-regular modes associated with the frequency of neutral periodic orbits of characteristics. We thoroughly analyse a subset of attractor modes for which numerical solutions point to an asymptotic law governing the eigenvalues. We show that three length scales proportional to $E^{1/6}$, $E^{1/4}$ and $E^{1/3}$ control the shape of the shear layers that are associated with these modes. These scales point out the key role of the small parameter $E^{1/12}$ in these oscillatory flows. With a simplified model of the viscous Poincar\\'e equation, we can give an approximate analytical formula that reproduces the velocity field in such shear layers. Finally, we also present an analysis of the quasi-regular modes whose frequencies are close to $\\sin(\\pi/4)$ and explain why a fluid inside a spherical shell cannot respond to any periodic forcing at this frequency when viscosity vanishes.

Method of forming cavitated objects of controlled dimension

DOEpatents

Anderson, Paul R.; Miller, Wayne J.

1982-01-01

A method of controllably varying the dimensions of cavitated objects such as hollow spherical shells wherein a precursor shell is heated to a temperature above the shell softening temperature in an ambient atmosphere wherein the ratio of gases which are permeable through the shell wall at that temperature to gases which are impermeable through the shell wall is substantially greater than the corresponding ratio for gases contained within the precursor shell. As the shell expands, the partial pressures of permeable gases internally and externally of the shell approach and achieve equilibrium, so that the final shell size depends solely upon the difference in impermeable gas partial pressures and shell surface tension.

Experiments on Thermal Convection in Rotating Spherical Shells With Radial Gravity: The Geophysical Fluid Flow Cell

NASA Technical Reports Server (NTRS)

Hart, John E.

1996-01-01

Experiments designed to study the fluid dynamics of buoyancy driven circulations in rotating spherical shells were conducted on the United States Microgravity Laboratory 2 spacelab mission. These experiments address several aspects of prototypical global convection relevant to large scale motions on the Sun, Earth, and on the giant planets. The key feature is the consistent modeling of radially directed gravity in spherical geometry by using dielectric polarization forces. Imagery of the planforms of thermally driven flows for rapidly-rotating regimes shows an initial separation and eventual merger of equatorial and polar convection as the heating (i.e. the Rayleigh number) is increased. At low rotation rates, multiple-states of motion for the same external parameters were observed.

Accurate image-charge method by the use of the residue theorem for core-shell dielectric sphere

NASA Astrophysics Data System (ADS)

Fu, Jing; Xu, Zhenli

2018-02-01

An accurate image-charge method (ICM) is developed for ionic interactions outside a core-shell structured dielectric sphere. Core-shell particles have wide applications for which the theoretical investigation requires efficient methods for the Green's function used to calculate pairwise interactions of ions. The ICM is based on an inverse Mellin transform from the coefficients of spherical harmonic series of the Green's function such that the polarization charge due to dielectric boundaries is represented by a series of image point charges and an image line charge. The residue theorem is used to accurately calculate the density of the line charge. Numerical results show that the ICM is promising in fast evaluation of the Green's function, and thus it is useful for theoretical investigations of core-shell particles. This routine can also be applicable for solving other problems with spherical dielectric interfaces such as multilayered media and Debye-Hückel equations.

Curvature-driven morphing of non-Euclidean shells

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Jiang, Xin; Holmes, D. P.

2017-05-01

We investigate how thin structures change their shape in response to non-mechanical stimuli that can be interpreted as variations in the structure's natural curvature. Starting from the theory of non-Euclidean plates and shells, we derive an effective model that reduces a three-dimensional stimulus to the natural fundamental forms of the mid-surface of the structure, incorporating expansion, or growth, in the thickness. Then, we apply the model to a variety of thin bodies, from flat plates to spherical shells, obtaining excellent agreement between theory and numerics. We show how cylinders and cones can either bend more or unroll, and eventually snap and rotate. We also study the nearly isometric deformations of a spherical shell and describe how this shape change is ruled by the geometry of a spindle. As the derived results stem from a purely geometrical model, they are general and scalable.

Orthogonal fast spherical Bessel transform on uniform grid

NASA Astrophysics Data System (ADS)

Serov, Vladislav V.

2017-07-01

We propose an algorithm for the orthogonal fast discrete spherical Bessel transform on a uniform grid. Our approach is based upon the spherical Bessel transform factorization into the two subsequent orthogonal transforms, namely the fast Fourier transform and the orthogonal transform founded on the derivatives of the discrete Legendre orthogonal polynomials. The method utility is illustrated by its implementation for the problem of a two-atomic molecule in a time-dependent external field simulating the one utilized in the attosecond streaking technique.

A facile electrochemical route to the preparation of uniform and monoatomic copper shells for gold nanoparticles.

PubMed

Gründer, Y; Ramasse, Q M; Dryfe, R A W

2015-02-28

Copper on gold forms a monolayer deposit via underpotential deposition. For gold particles adsorbed at a liquid-liquid interface this results in a uniform one monolayer thick shell. This approach offers a new route for the uniform functionalisation of nanoparticles and presents a way to probe fundamental processes that underlie nanoparticle synthesis.

Structural and Optical Analysis of the Bio-mineralized Photonic Structures in the Shell of the Blue- Rayed Limpet Ansates Pellucida

NASA Astrophysics Data System (ADS)

Kolle, Mathias; Li, Ling; Kolle, Stefan; Weaver, James; Ortiz, Christine; Aizenberg, Joanna

2013-03-01

Many terrestrial biological organisms have evolved a variety of micro- and nanostructures that provide unique optical signatures including distinctive, dynamic coloration, high reflectivity or superior whiteness. Recently, photonic structures have also been found in the shells or spines of marine animals. Life under water imposes very distinct constraints on organisms relying on visual communication and on the designs and the materials involved in aquatic photonic structures. Here, we present a bio-mineralized calcium carbonate - based crystalline photonic system buried in the shell of the blue-rayed limpet Ansates pellucida. The structure consists of a layered stack of calcite lamellae with uniform thickness and inter-lamella spacing. This arrangement lies at the origin of the blue-green iridescence of the organism's characteristic stripes, which is caused by multilayer interference. The multilayer is supported by a disordered array of spherical particles with an average diameter of 300nm, likely serving to enhance the contrast of the blue stripes. We present a full structural and optical characterization of this bio-mineralised marine photonic system, supported by optical FDTD modeling. The authors gratefully acknowledge financial support by the Air Force Office of Scientific Research under Award No. FA9550-09-1-0669-DOD35CAP. M. Kolle is grateful for support from the Alexander von Humboldt - Foundation.

Effects of zonal flows on correlation between energy balance and energy conservation associated with nonlinear nonviscous atmospheric dynamics in a thin rotating spherical shell

NASA Astrophysics Data System (ADS)

Ibragimov, Ranis N.

2018-03-01

The nonlinear Euler equations are used to model two-dimensional atmosphere dynamics in a thin rotating spherical shell. The energy balance is deduced on the basis of two classes of functorially independent invariant solutions associated with the model. It it shown that the energy balance is exactly the conservation law for one class of the solutions whereas the second class of invariant solutions provides and asymptotic convergence of the energy balance to the conservation law.

Effect of multiple spin species on spherical shell neutron transmission analysis

NASA Technical Reports Server (NTRS)

Semler, T. T.

1972-01-01

A series of Monte Carlo calculations were performed in order to evaluate the effect of separated against merged spin statistics on the analysis of spherical shell neutron transmission experiments for gold. It is shown that the use of separated spin statistics results in larger average capture cross sections of gold at 24 KeV. This effect is explained by stronger windows in the total cross section caused by the interference between potential and J(+) resonances and by J(+) and J(-) resonance overlap allowed by the use of separated spin statistics.

A vectorized Poisson solver over a spherical shell and its application to the quasi-geostrophic omega-equation

NASA Technical Reports Server (NTRS)

Mullenmeister, Paul

1988-01-01

The quasi-geostrophic omega-equation in flux form is developed as an example of a Poisson problem over a spherical shell. Solutions of this equation are obtained by applying a two-parameter Chebyshev solver in vector layout for CDC 200 series computers. The performance of this vectorized algorithm greatly exceeds the performance of its scalar analog. The algorithm generates solutions of the omega-equation which are compared with the omega fields calculated with the aid of the mass continuity equation.

Multidimensional Analysis of Direct-Drive Plastic-Shell Implosions on OMEGA

NASA Astrophysics Data System (ADS)

Radha, P. B.

2004-11-01

Direct-drive implosions of plastic shells with the OMEGA laser are used as energy-scaled warm surrogates for ignition cryogenic targets designed for use on the National Ignition Facility. Plastic targets involve varying shell thickness (15 to 33 μm), fill pressures (3 to 15 atm), and shell adiabats. The multidimensional hydrodynamics code DRACO is used to evaluate the effects of capsule-surface roughness and illumination nonuniformities on target performance. These simulations indicate that shell stability during the acceleration phase plays a critical role in determining fusion yields. For shells that are thick enough to survive the Rayleigh--Taylor growth, target yields are significantly reduced by growth of the long (ℓ < 10) and intermediate modes (20 < ℓ < 50) occurring from single-beam laser nonuniformities. The neutron production rate for these thick shells truncates relative to one-dimensional (1-D) predictions. The neutron-rate curves for the thinner shells, however, have significantly lower amplitudes and widths closer to 1-D results, indicating shell breakup during the acceleration phase. The simulation results are consistent with experimental observations. Previously, the stability of plastic-shell implosions had been correlated to a static ``mix-width'' at the boundary of the gas and plastic pusher estimated using a variety of experimental observables and an assumption of spherical symmetry. Results of these 2-D simulations provide a comprehensive understanding of warm-target implosion dynamics without assumptions of spherical symmetry and serve to answer the question of the hydrodynamic surrogacy between these plastic-shell implosions and the cryogenic ignition designs.

Waltzing route toward double-helix formation in cholesteric shells

NASA Astrophysics Data System (ADS)

Darmon, Alexandre; Benzaquen, Michael; Seč, David; Čopar, Simon; Dauchot, Olivier; Lopez-Leon, Teresa

2016-08-01

Liquid crystals, when confined to a spherical shell, offer fascinating possibilities for producing artificial mesoscopic atoms, which could then self-assemble into materials structured at a nanoscale, such as photonic crystals or metamaterials. The spherical curvature of the shell imposes topological constraints in the molecular ordering of the liquid crystal, resulting in the formation of defects. Controlling the number of defects, that is, the shell valency, and their positions, is a key success factor for the realization of those materials. Liquid crystals with helical cholesteric order offer a promising, yet unexplored way of controlling the shell defect configuration. In this paper, we study cholesteric shells with monovalent and bivalent defect configurations. By bringing together experiments and numerical simulations, we show that the defects appearing in these two configurations have a complex inner structure, as recently reported for simulated droplets. Bivalent shells possess two highly structured defects, which are composed of a number of smaller defect rings that pile up through the shell. Monovalent shells have a single radial defect, which is composed of two nonsingular defect lines that wind around each other in a double-helix structure. The stability of the bivalent configuration against the monovalent one is controlled by c = h/p, where h is the shell thickness and p the cholesteric helical pitch. By playing with the shell geometry, we can trigger the transition between the two configurations. This transition involves a fascinating waltz dynamics, where the two defects come closer while turning around each other.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, F. J.; Radha, P. B.; Bonino, M. J.

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. As a result, fusion yields were increased by more than a factor of ~2 without increasing the energy of the laser by the use of contoured shells.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, F. J.; Radha, P. B.; Bonino, M. J.

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. Fusion yields were increased by more than a factor of ∼2 without increasing the energy of the laser by the use of contoured shells.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE PAGES

Marshall, F. J.; Radha, P. B.; Bonino, M. J.; ...

2016-01-28

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. As a result, fusion yields were increased by more than a factor of ~2 without increasing the energy of the laser by the use of contoured shells.

A Nonlinear Theory of Bending and Buckling of Thin Elastic Shallow Spherical Shells

NASA Technical Reports Server (NTRS)

Kaplan, A; Fung, Y C

1954-01-01

The problem of the finite displacement and buckling, of a shallow spherical dome is investigated both theoretically and experimentally. Experimental results seem to indicate that the classical criterion of buckling is applicable to very shallow spherical domes for which the theoretical calculation was made. A transition to energy criterion for higher domes is also indicated.

Dynamics of Inhomogeneous Shell Systems Under Non-Stationary Loading (Survey)

NASA Astrophysics Data System (ADS)

Lugovoi, P. Z.; Meish, V. F.

2017-09-01

Experimental works on the determination of dynamics of smooth and stiffened cylindrical shells contacting with a soil medium under various non-stationary loading are reviewed. The results of studying three-layer shells of revolution whose motion equations are obtained within the framework of the hypotheses of the Timoshenko geometrically nonlinear theory are stated. The numerical results for shells with a piecewise or discrete filler enable the analysis of estimation of the influence of geometrical and physical-mechanical parameters of structures on their dynamics and reveal new mechanical effects. Basing on the classical theory of shells and rods, the effect of the discrete arrangement of ribs and coefficients of the Winkler or Pasternak elastic foundation on the normal frequencies and modes of rectangular planar cylindrical and spherical shells is studied. The number and shape of dispersion curves for longitudinal harmonic waves in a stiffened cylindrical shell are determined. The equations of vibrations of ribbed shells of revolution on Winkler or Pasternak elastic foundation are obtained using the geometrically nonlinear theory and the Timoshenko hypotheses. On applying the integral-interpolational method, numerical algorithms are developed and the corresponding non-stationary problems are solved. The special attention is paid to the statement and solution of coupled problems on the dynamical interaction of cylindrical or spherical shells with the soil water-saturated medium of different structure.

One-dimensional MHD simulations of MTF systems with compact toroid targets and spherical liners

NASA Astrophysics Data System (ADS)

Khalzov, Ivan; Zindler, Ryan; Barsky, Sandra; Delage, Michael; Laberge, Michel

2017-10-01

One-dimensional (1D) MHD code is developed in General Fusion (GF) for coupled plasma-liner simulations in magnetized target fusion (MTF) systems. The main goal of these simulations is to search for optimal parameters of MTF reactor, in which spherical liquid metal liner compresses compact toroid plasma. The code uses Lagrangian description for both liner and plasma. The liner is represented as a set of spherical shells with fixed masses while plasma is discretized as a set of nested tori with circular cross sections and fixed number of particles between them. All physical fields are 1D functions of either spherical (liner) or small toroidal (plasma) radius. Motion of liner and plasma shells is calculated self-consistently based on applied forces and equations of state. Magnetic field is determined by 1D profiles of poloidal and toroidal fluxes - they are advected with shells and diffuse according to local resistivity, this also accounts for flux leakage into the liner. Different plasma transport models are implemented, this allows for comparison with ongoing GF experiments. Fusion power calculation is included into the code. We performed a series of parameter scans in order to establish the underlying dependencies of the MTF system and find the optimal reactor design point.

One-pot synthesis of biocompatible Te@phenol formaldehyde resin core-shell nanowires with uniform size and unique fluorescent properties by a synergized soft-hard template process.

PubMed

Qian, Haisheng; Zhu, Enbo; Zheng, Shunji; Li, Zhengquan; Hu, Yong; Guo, Changfa; Yang, Xingyun; Li, Liangchao; Tong, Guoxiu; Guo, Huichen

2010-12-10

One-pot hydrothermal process has been developed to synthesize uniform Te@phenol formaldehyde resin core-shell nanowires with unique fluorescent properties. A synergistic soft-hard template mechanism has been proposed to explain the formation of the core-shell nanowires. The Te@phenol formaldehyde resin core-shell nanowires display unique fluorescent properties, which give strong luminescent emission in the blue-violet and green regions with excitation wavelengths of 270 nm and 402 nm, respectively.

Apparatus for forming a continuous lightweight multicell material

NASA Technical Reports Server (NTRS)

Wang, Taylor G. (Inventor); Elleman, Daniel D. (Inventor); Kendall, James M., Jr. (Inventor)

1984-01-01

An apparatus is described for producing a lightweight structural material (12), by forming gas-filled shells (38) of molten material from a matrix of nozzles (22) that form shells of very uniform size at very uniform rates. The matrix of molten shells coalesce into a multi-cell material of controlled cellular structure. The shells can be of two different sizes (38, 44) that are interspersed, to form a multicell material that has a regular cell pattern but which avoids planes of weakness and localized voids. The gas (50) in the shells can be under a high pressure, and can be a fire extinguishing gas.

Optimum designs for superpressure balloons

NASA Astrophysics Data System (ADS)

Smith, M. S.; Rainwater, E. L.

2004-01-01

The elastica shape is now well known to be the best basic shape for superpressure balloon design. This shape, also known as the pumpkin, or natural shape for balloons, has been well understood since the early 1900s when it was applied to the determination of the shape of descending parachutes. The elastica shape was also investigated in the 1950s when high strength films were used to produce superpressure cylinder balloons. The need for uniform stress distribution in shells of early superpressure balloons led to a long period of the development of spherical superpressure balloons. Not until the late 1970s was the elastica shape revisited for the purpose of the producing superpressure balloons. This paper will review various development efforts in the field of superpressure design and will elaborate on the current state-of-the-art with suggestions for future developments.

Progress on CBET Platform at the Nike Laser

NASA Astrophysics Data System (ADS)

Weaver, J. L.; McKenty, P.; Oh, J.; Kehne, D.; Schmitt, A. J.; Obenschain, S.; Serlin, V.; Lehmberg, R.; Tsung, F.

2015-11-01

Cross-beam energy transport (CBET) studies are underway at the Nike krypton-fluoride (KrF) laser at NRL. This facility has unique characteristics that provide an excellent platform for CBET work - including short wavelength (248 nm), large bandwidth (1-3 THz), beam smoothing by induced spatial incoherence (ISI), and full aperture focal spot zooming. Nike's two beam arrays are widely separated (135° in azimuth) which facilitates CBET studies in a nearly opposing geometry, relevant to Polar Direct Drive implosions. Various target types are planned: planar slabs, cylindrical and spherical shells, and low-density targets. The solid targets will be used to examine gradient geometries and the latter will access larger volume, more uniform plasmas. The initial campaign is exploring changes observed by scattered light diagnostics for both beam arrays as the probe laser spectrum is modified. Work supported by DoE/NNSA.

Heat transport system, method and material

DOEpatents

Musinski, Donald L.

1987-01-01

A heat transport system, method and composite material in which a plurality of hollow spherical shells or microspheres having an outside diameter of less than or equal to 500 microns are encapsulated or embedded within a bulk material. Each shell has captured therein a volatile working fluid, such that each shell operates as a microsized heat pipe for conducting heat through the composite structure.

Core-shell structured SiO2@YVO4:Dy3+/Sm3+ phosphor particles: sol-gel preparation and characterization.

PubMed

Wang, H; Yu, M; Lin, C K; Lin, J

2006-08-01

Spherical SiO(2) particles have been coated with YVO(4):Dy(3+)/Sm(3+) phosphor layers by a Pechini sol-gel process, leading to the formation of core-shell structured SiO(2)@YVO(4):Dy(3+)/Sm(3+) particles. X-ray diffraction (XRD), Fourier-transform IR spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting SiO(2)@YVO(4):Dy(3+)/Sm(3+) core-shell phosphors. The obtained core-shell phosphors have perfect spherical shape with narrow size distribution (average size ca. 300 nm), smooth surface and non-agglomeration. The thickness of shells could be easily controlled by changing the number of deposition cycles (20 nm for one deposition cycle). The core-shell particles show strong characteristic emission from Dy(3+) for SiO(2)@YVO(4):Dy(3+) and from Sm(3+) for SiO(2)@YVO(4):Sm(3+) due to an efficient energy transfer from YVO(4) host to them. The PL intensity of Dy(3+) and Sm(3+) increases with raising the annealing temperature and the number of coating cycles.

Synthesis and thermal stability of W/WS{sub 2} inorganic fullerene-like nanoparticles with core-shell structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang Lianxia; Yang Haibin; Fu Wuyou

W/WS{sub 2} inorganic fullerene-like (IF) nanoparticles with core-shell structure are synthesized by the reaction of tungsten nanospheres and sulfur at relatively low temperatures (380-600 deg. C) under hydrogen atmosphere, in which tungsten nanospheres were prepared by wire electrical explosion method. Images of transmission electron microscopy and high-resolution transmission electron microscopy show that the composite particles are of core-shell structure with spherical shape and the shell thickness is about 10 nm. X-ray powder diffraction results indicate that the interlayer spacing of IF-WS{sub 2} shell decreases and approaches that of 2H-WS{sub 2} with increasing annealing temperatures, representing an expansion of 3.3-1.6%. Amore » mechanism of IF-WS{sub 2} formation via sulfur diffusion into fullerene nanoparticles is discussed. Thermal analysis shows that the nanoparticles obtained at different temperatures exhibit similar thermal stability and the onset temperature of oxidization is about 410 deg. C. Encapsulating hard tungsten core into IF-WS{sub 2} and the spherical shape of the core-shell structures may enhance their performance in tribological applications.« less

Spherical collapse in chameleon models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brax, Ph.; Rosenfeld, R.; Steer, D.A., E-mail: brax@spht.saclay.cea.fr, E-mail: rosenfel@ift.unesp.br, E-mail: daniele.steer@apc.univ-paris7.fr

2010-08-01

We study the gravitational collapse of an overdensity of nonrelativistic matter under the action of gravity and a chameleon scalar field. We show that the spherical collapse model is modified by the presence of a chameleon field. In particular, we find that even though the chameleon effects can be potentially large at small scales, for a large enough initial size of the inhomogeneity the collapsing region possesses a thin shell that shields the modification of gravity induced by the chameleon field, recovering the standard gravity results. We analyse the behaviour of a collapsing shell in a cosmological setting in themore » presence of a thin shell and find that, in contrast to the usual case, the critical density for collapse in principle depends on the initial comoving size of the inhomogeneity.« less

Acoustic radiation force acting on elastic and viscoelastic spherical shells placed in a plane standing wave field.

PubMed

Mitri, F G

2005-08-01

The theory of the acoustic radiation force acting on elastic spherical shells suspended in a plane standing wave field is developed in relation to their thickness and the content of their hollow regions. The theory is modified to include the effect of a hysteresis type of absorption of compressional and shear waves in the material. The fluid-loading effect on the acoustic radiation force function Y(st) is analyzed as well. Results of numerical calculations are presented for a number of elastic and viscoelastic materials, with the hollow region filled with water or air. These results show how the damping due to absorption, the change of the interior fluid inside the shells' hollow regions, and the exterior fluid surrounding their structures, affect the acoustic radiation force.

Magnetization processes in core/shell exchange-spring structures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, J. S.

2015-03-27

The magnetization reversal processes in cylindrical and spherical soft core/hard shell exchange-spring structures are investigated via the analytical nucleation theory, and are verified with numerical micromagnetic simulations. At small core sizes, the nucleation of magnetic reversal proceeds via the modified bulging mode, where the transverse component of the magnetization is only semi-coherent in direction and the nucleation field contains a contribution from self-demagnetization. For large core sizes, the modified curling mode, where the magnetization configuration is vortex-like, is favored at nucleation. The preference for the modified curling mode is beneficial in that the fluxclosure allows cylindrical and spherical core/shell exchange-springmore » elements to be densely packed into bulk permanent magnets without affecting the nucleation field, thereby offering the potential for high energy product.« less

SOME ENGINEERING PROPERTIES OF SHELLED AND KERNEL TEA (Camellia sinensis) SEEDS.

PubMed

Altuntas, Ebubekir; Yildiz, Merve

2017-01-01

Camellia sinensis is the source of tea leaves and it is an economic crop now grown around the World. Tea seed oil has been used for cooking in China and other Asian countries for more than a thousand years. Tea is the most widely consumed beverages after water in the world. It is mainly produced in Asia, central Africa, and exported throughout the World. Some engineering properties (size dimensions, sphericity, volume, bulk and true densities, friction coefficient, colour characteristics and mechanical behaviour as rupture force of shelled and kernel tea ( Camellia sinensis ) seeds were determined in this study. This research was carried out for shelled and kernel tea seeds. The shelled tea seeds used in this study were obtained from East-Black Sea Tea Cooperative Institution in Rize city of Turkey. Shelled and kernel tea seeds were characterized as large and small sizes. The average geometric mean diameter and seed mass of the shelled tea seeds were 15.8 mm, 10.7 mm (large size); 1.47 g, 0.49 g (small size); while the average geometric mean diameter and seed mass of the kernel tea seeds were 11.8 mm, 8 mm for large size; 0.97 g, 0.31 g for small size, respectively. The sphericity, surface area and volume values were found to be higher in a larger size than small size for the shelled and kernel tea samples. The shelled tea seed's colour intensity (Chroma) were found between 59.31 and 64.22 for large size, while the kernel tea seed's chroma values were found between 56.04 68.34 for large size, respectively. The rupture force values of kernel tea seeds were higher than shelled tea seeds for the large size along X axis; whereas, the rupture force values of along X axis were higher than Y axis for large size of shelled tea seeds. The static coefficients of friction of shelled and kernel tea seeds for the large and small sizes higher values for rubber than the other friction surfaces. Some engineering properties, such as geometric mean diameter, sphericity, volume, bulk and true densities, the coefficient of friction, L*, a*, b* colour characteristics and rupture force of shelled and kernel tea ( Camellia sinensis ) seeds will serve to design the equipment used in postharvest treatments.

The Morphology and Uniformity of Circumstellar OH/H2O Masers around OH/IR Stars

NASA Astrophysics Data System (ADS)

Felli, Derek Sean

Even though low mass stars ( 8 solar masses), the more massive stars drive the chemical evolution of galaxies from which the next generation of stars and planets can form. Understanding mass loss of asymptotic giant branch stars contributes to our understanding of the chemical evolution of the galaxy, stellar populations, and star formation history. Stars with mass 8 solar masses go supernova. In both cases, these stars enrich their environments with elements heavier than simple hydrogen and helium molecules. While some general info about how stars die and form planetary nebulae are known, specific details are missing due to a lack of high-resolution observations and analysis of the intermediate stages. For example, we know that mass loss in stars creates morphologically diverse planetary nebulae, but we do not know the uniformity of these processes, and therefore lack detailed models to better predict how spherically symmetric stars form asymmetric nebulae. We have selected a specific group of late-stage stars and observed them at different scales to reveal the uniformity of mass loss through different layers close to the star. This includes observing nearby masers that trace the molecular shell structure around these stars. This study revealed detailed structure that was analyzed for uniformity to place constraints on how the mass loss processes behave in models. These results will feed into our ability to create more detailed models to better predict the chemical evolution of the next generation of stars and planets.

Problems in understanding the structure and assembly of viruses

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, J.

1997-12-01

Though viruses infect the cells of all groups of animals, plants, and microorganisms, their structures follow a limited number of general themes; spherical or cylindrical shells built of hundreds of repeated protein subunits enclosing a nucleic acid - DNA or RNA - genome. Since the 1960s it has been known that the protein shells of spherical viruses in fact conform to icosahedral symmetry or to subtle deviations from icosahedral symmetry. The construction of the shell lattices and the transformations they go through in the different stages of the viral life cycle are not fully understood. The shells contain the nucleicmore » in a highly condensed state, of unknown coiling/organization. Features of the well studied bacterial viruses will be reviewed, with examples from adenoviruses, herpesviruses, poliovirus, and HIV. The emergence of new viral disease has led to increased interest in the development of agents which interfere with virus reproduction at the level of the assembly or function of the organized particle. Recently computational approaches to the problem of virus assembly have made important contributions to clarifying shell assembly processes. 1 ref.« less

Amplitude-modulated acoustic radiation force experienced by elastic and viscoelastic spherical shells in progressive waves.

PubMed

Mitri, F G; Fellah, Z E A

2006-07-01

The dynamic acoustic radiation force resulting from a dual-frequency beam incident on spherical shells immersed in an inviscid fluid is examined theoretically in relation to their thickness and the contents of their interior hollow regions. The theory is modified to include a hysteresis type of absorption inside the shells' material. The results of numerical calculations are presented for stainless steel and absorbing lucite (PolyMethyMethacrylAte) shells with the hollow region filled with water or air. Significant differences occur when the interior fluid inside the hollow region is changed from water to air. It is shown that the dynamic radiation force function Yd deviates from the static radiation force function Yp when the modulation size parameter deltax = mid R:x2 - x1mid R: (x1 = k1a, x2 = k2a, k1 and k2 are the wave vectors of the incident ultrasound waves, and a is the outer radius of the shell) starts to exceed the width of the resonance peaks in the Yp curves.

Models of Interacting Stellar Winds

NASA Astrophysics Data System (ADS)

Wilkin, Francis Patrick

Stars drive supersonic winds which interact violently with their surroundings. Analytic and numerical models of hypersonic, interacting circumstellar flows are presented for several important astrophysical problems. A new solution method for steady-state, axisymmetric, wind collision problems is applied to radiative bow shocks from moving stars and to the collision of two spherical winds in a binary star system. The solutions obtained describe the shape of the geometrically thin, shocked shell of matter, as well as its mass surface density and the tangential velocity within it. Analytic solutions are also obtained for non-axisymmetric bow shocks, where the asymmetry arises due to either a transverse gradient in the ambient medium, or a misaligned, axisymmetric stellar wind. While the solutions are all easily scaled in terms of their relevant dimensional parameters, the important assumption of radiative shocks implies that the models are most applicable towards systems with dense environments and low preshock velocities. The bow shock model has previously been applied to cometary, ultracompact HII regions by Van Buren et al. (1990), who discussed extensively the applicability of the thin shell approximation. I next model the collision between a protostellar wind and supersonic infall from a rotating cloud, employing a quasi-steady, thin-shell formulation. The spherical wind is initially crushed to the protostellar surface by nearly spherical infall. The centrifugal distortion of infalling matter eventually permits a wind-supported, trapped bubble to slowly expand on an evolutionary (~ 105 yr) time. The shell becomes progressively more extended along the rotational axis, due to the asymmetry of the infall. When the quasi-steady assumption breaks down, the shell has become a needle-like, bipolar configuration that may represent a precursor to protostellar jets. I stress, however, the likelihood of instability for the shell, and the possibility of oscillatory behavior in a fully time-dependent model.

Global Dynamic Modeling of Space-Geodetic Data

NASA Technical Reports Server (NTRS)

Bird, Peter

1995-01-01

The proposal had outlined a year for program conversion, a year for testing and debugging, and two years for numerical experiments. We kept to that schedule. In first (partial) year, author designed a finite element for isostatic thin-shell deformation on a sphere, derived all of its algebraic and stiffness properties, and embedded it in a new finite element code which derives its basic solution strategy (and some critical subroutines) from earlier flat-Earth codes. Also designed and programmed a new fault element to represent faults along plate boundaries. Wrote a preliminary version of a spherical graphics program for the display of output. Tested this new code for accuracy on individual model plates. Made estimates of the computer-time/cost efficiency of the code for whole-earth grids, which were reasonable. Finally, converted an interactive graphical grid-designer program from Cartesian to spherical geometry to permit the beginning of serious modeling. For reasons of cost efficiency, models are isostatic, and do not consider the local effects of unsupported loads or bending stresses. The requirements are: (1) ability to represent rigid rotation on a sphere; (2) ability to represent a spatially uniform strain-rate tensor in the limit of small elements; and (3) continuity of velocity across all element boundaries. Author designed a 3-node triangle shell element which has two different sets of basis functions to represent (vector) velocity and all other (scalar) variables. Such elements can be shown to converge to the formulas for plane triangles in the limit of small size, but can also applied to cover any area smaller than a hemisphere. The difficult volume integrals involved in computing the stiffness of such elements are performed numerically using 7 Gauss integration points on the surface of the sphere, beneath each of which a vertical integral is performed using about 100 points.

Thermal invisibility based on scattering cancellation and mantle cloaking

PubMed Central

Farhat, M.; Chen, P.-Y.; Bagci, H.; Amra, C.; Guenneau, S.; Alù, A.

2015-01-01

We theoretically and numerically analyze thermal invisibility based on the concept of scattering cancellation and mantle cloaking. We show that a small object can be made completely invisible to heat diffusion waves, by tailoring the heat conductivity of the spherical shell enclosing the object. This means that the thermal scattering from the object is suppressed, and the heat flow outside the object and the cloak made of these spherical shells behaves as if the object is not present. Thermal invisibility may open new vistas in hiding hot spots in infrared thermography, military furtivity, and electronics heating reduction. PMID:25928664

-dimensional thin shell wormhole with deformed throat can be supported by normal matter

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

2015-06-01

From the physics standpoint the exotic matter problem is a major difficulty in thin shell wormholes (TSWs) with spherical/cylindrical throat topologies. We aim to circumvent this handicap by considering angle dependent throats in dimensions. By considering the throat of the TSW to be deformed spherical, i.e., a function of and , we present general conditions which are to be satisfied by the shape of the throat in order to have the wormhole supported by matter with positive density in the static reference frame. We provide particular solutions/examples to the constraint conditions.

A Study of the Nearfield of an Excited Spherical Shell.

DTIC Science & Technology

1980-03-17

8217 tte exact wave harmonic series and the approximate Geometrical Theory of Diffraction (GTD) were used to predict the acoustic near field of an elastic...rr) )1/3 n 4 n14 XV e i+ (424 (ka) (2h (ka) nn an1 % Tte SkaI/ rA’ (k)2 nn in Ap ndi B]. =Q (ikc)~ (4.25)h(1 (a n Tn whee i adeayftore fo acosi prpaa3o...Approach to Scattering from Elastic Spherical Shells," NUC TP425, September 1974, Naval Undersea Center, San Diego, California. 36. Pathak, P. H. and

Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide.

PubMed

Müller, Achim; Krickemeyer, Erich; Bögge, Hartmut; Schmidtmann, Marc; Peters, Frank

1998-12-31

Plato and Kepler would have been pleased. Despite the large number of atoms present the cluster anion 1 resembles an icosahedral-type structure. This represents definitively an unprecedented event in chemistry! The structure is made up of 12 {Mo 11 } fragments such that the fivefold symmetry axes are retained in the resulting spherical object. As an inscribed icosahedron can be recognized in the spherical shell of 1 (see picture), similarities with Kepler's famous shell model of the cosmos can be seen. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

A Variational Formulation for the Finite Element Analysis of Sound Wave Propagation in a Spherical Shell

NASA Technical Reports Server (NTRS)

Lebiedzik, Catherine

1995-01-01

Development of design tools to furnish optimal acoustic environments for lightweight aircraft demands the ability to simulate the acoustic system on a workstation. In order to form an effective mathematical model of the phenomena at hand, we have begun by studying the propagation of acoustic waves inside closed spherical shells. Using a fully-coupled fluid-structure interaction model based upon variational principles, we have written a finite element analysis program and are in the process of examining several test cases. Future investigations are planned to increase model accuracy by incorporating non-linear and viscous effects.

Method and apparatus for determining diameter and wall thickness of minute hollow spherical shells

DOEpatents

Steinman, D.A.

1980-05-30

Method and apparatus for determining diameter and wall thickness of hollow microspheres or shells wherein terminal velocities of shells traveling in fluid-filled conduits of differing diameters are measured. A wall-effect factor is determined as a ratio of the terminal velocities, and shell outside diameter may then be ascertained as a predetermined empirical function of wall-effect factor. For shells of known outside diameter, wall thickness may then be ascertained as a predetermined empirical function of terminal velocity in either conduit.

Method and apparatus for determining diameter and wall thickness of minute hollow spherical shells

DOEpatents

Steinman, David A.

1982-01-01

Method and apparatus for determining diameter and wall thickness of hollow microspheres or shells wherein terminal velocities of shells traveling in fluid-filled conduits of differing diameters are measured. A wall-effect factor is determined as a ratio of the terminal velocities, and shell outside diameter may then be ascertained as a predetermined empirical function of wall-effect factor. For shells of known outside diameter, wall thickness may then be ascertained as a predetermined empirical function of terminal velocity in either conduit.

Evolution of a superbubble blastwave in a magnetized medium

NASA Technical Reports Server (NTRS)

Ferriere, Katia M.; Zweibel, Ellen G.; Maclow, Mordecai-Mark

1990-01-01

Researchers investigate the effects of interstellar magnetic fields on the evolution and structure of interstellar superbubbles, using both analytic and numerical magnetohydrodynamic (MHD) calculations. These cavities of hot gas, surrounded by shells of cold dense material preceded by a shock wave result from the combined action of stellar winds and supernova explosions in OB associations. If the medium in which a superbubble goes off is homogeneous and unmagnetized, the blast wave expands isotropically. As the interstellar gas flows through the shock, it cools significantly and gets strongly compressed such that thermal pressure remains approximately equal to ram pressure. Hence, the swept up material is confined to a very thin shell. However, if the ambient medium is permeated by a uniform magnetic field B sub o approx. 3 mu G (typical value for the interstellar matter (ISM)), the configuration loses its spherical symmetry, and, due to magnetic pressure, the shell of swept up material does not remain thin. Researchers found the following qualitative differences: (1) Except in the immediate vicinity of the magnetic poles, the shell is supported by magnetic pressure. (2) The refraction of field lines at the shock and the thermal pressure gradient along the shell both contribute to accelerating the gas toward the equator. The resulting mass flux considerably decreases the column density at the magnetic poles. (3) Away from the poles, magnetic tension in the shell causes the field lines (particularly the inner boundary) to elongate in the direction of B sub o. In contrast, the shock wave radius increases with increasing theta. (4) The reduced inertia of a parcel in the polar neighborhood makes it easier to decelerate, and accounts for the dimple which appears at the poles in numerical simulations. This dimple also results from the necessity to call on intermediate shocks in order to insure a smooth transition between a purely thermal shock at the poles and a magnetic shock in the rest of the shell. (5) The shock wave propagates faster than in the absence of magnetic field, except near the poles where the reduced mass of the shell allows it to be more efficiently decelerated.

Type II shell evolution in A = 70 isobars from the N ≥ 40 island of inversion

NASA Astrophysics Data System (ADS)

Morales, A. I.; Benzoni, G.; Watanabe, H.; Tsunoda, Y.; Otsuka, T.; Nishimura, S.; Browne, F.; Daido, R.; Doornenbal, P.; Fang, Y.; Lorusso, G.; Patel, Z.; Rice, S.; Sinclair, L.; Söderström, P.-A.; Sumikama, T.; Wu, J.; Xu, Z. Y.; Yagi, A.; Yokoyama, R.; Baba, H.; Avigo, R.; Bello Garrote, F. L.; Blasi, N.; Bracco, A.; Camera, F.; Ceruti, S.; Crespi, F. C. L.; de Angelis, G.; Delattre, M.-C.; Dombradi, Zs.; Gottardo, A.; Isobe, T.; Kojouharov, I.; Kurz, N.; Kuti, I.; Matsui, K.; Melon, B.; Mengoni, D.; Miyazaki, T.; Modamio-Hoybjor, V.; Momiyama, S.; Napoli, D. R.; Niikura, M.; Orlandi, R.; Sakurai, H.; Sahin, E.; Sohler, D.; Schaffner, H.; Taniuchi, R.; Taprogge, J.; Vajta, Zs.; Valiente-Dobón, J. J.; Wieland, O.; Yalcinkaya, M.

2017-02-01

The level structures of 70Co and 70Ni, populated from the β decay of 70Fe, have been investigated using β-delayed γ-ray spectroscopy following in-flight fission of a 238U beam. The experimental results are compared to Monte-Carlo Shell-Model calculations including the pf +g9/2 +d5/2 orbitals. The strong population of a (1+) state at 274 keV in 70Co is at variance with the expected excitation energy of ∼1 MeV from near spherical single-particle estimates. This observation indicates a dominance of prolate-deformed intruder configurations in the low-lying levels, which coexist with the normal near spherical states. It is shown that the β decay of the neutron-rich A = 70 isobars from the new island of inversion to the Z = 28 closed-shell regime progresses in accordance with a newly reported type of shell evolution, the so-called Type II, which involves many particle-hole excitations across energy gaps.

Tank measurements of scattering from a resin-filled fiberglass spherical shell with internal flaws.

PubMed

Tesei, Alessandra; Guerrini, Piero; Zampolli, Mario

2008-08-01

This paper presents results of acoustic inversion and structural health monitoring achieved by means of low to midfrequency elastic scattering analysis of simple, curved objects, insonified in a water tank. Acoustic elastic scattering measurements were conducted between 15 and 100 kHz on a 60-mm-radius fiberglass spherical shell, filled with a low-shear-speed epoxy resin. Preliminary measurements were conducted also on the void shell before filling, and on a solid sphere of the same material as the filler. These data were used to estimate the constituent material parameters via acoustic inversion. The objects were measured in the backscatter direction, suspended at midwater, and insonified by a broadband directional transducer. From the inspection of the response of the solid-filled shell it was possible to detect and characterize significant inhomogeneities of the interior (air pockets), the presence of which were later confirmed by x-ray CT scan and ultrasound measurements. Elastic wave analysis and a model-data comparison study support the physical interpretation of the measurements.

Greenhouse Effect: Temperature of a Metal Sphere Surrounded by a Glass Shell and Heated by Sunlight

ERIC Educational Resources Information Center

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the "z"-axis. This development is a generalization of the simple treatment of the…

Heat transport system, method and material

DOEpatents

Musinski, D.L.

1987-04-28

A heat transport system, method and composite material are disclosed in which a plurality of hollow spherical shells or microspheres having an outside diameter of less than or equal to 500 microns are encapsulated or embedded within a bulk material. Each shell has captured therein a volatile working fluid, such that each shell operates as a microsized heat pipe for conducting heat through the composite structure. 1 fig.

Carbon and nitrogen co-doped bowl-like Au/TiO2 nanostructures with tunable size for enhanced visible-light-driven photocatalysis

NASA Astrophysics Data System (ADS)

Li, Yayuan; Cao, Shubo; Zhang, Ang; Zhang, Chen; Qu, Ting; Zhao, Yongbin; Chen, Aihua

2018-07-01

It is of great importance to extend the UV response of anatase TiO2 into the visible light range for the practical applications. Here, a facile rout to carbon and nitrogen co-doped, Au loaded bowl-like TiO2 nanostructures with tunable size are proposed by using self-assembled polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) block copolymer (BCP) spherical micelles as templates. Amphiphilic PS-b-P4VP self-assembles to form PS@P4VP core-shell spherical micelles with P4VP as the out layer in an evaporable mixed solvents of ethanol/tetrahydrofuran (THF). The size of uniform PS@P4VP spherical micelles can be precisely tuned in the range of a few nm to several hundred nm by controlling the molecular composition of the BCPs. Bowl-like TiO2 nanostructures with a replicate size loaded with highly dispersed Au nanoparticles (NPs) of ∼5 nm in diameter are fabricated from these spherical micelles because of strong complex ability of pyridine groups. PS-b-P4VP provides carbon and nitrogen sources to dope the resulting samples simultaneously. The special carbon and nitrogen co-doped bowl-like Au/TiO2 nanostructures exhibit much higher photocatalytic activity in the photodegradation of rhodamine B (RhB) compared to Au/P25 under visible light irradiation. Furthermore, the photocatalytic activity is significantly influenced by the BCP molecular composition due to different surface area and loading capacity of the resulting samples. This study provides a facile way to synthesize multi-element doped hollow or bowl-like nanoparticles with tunable size in the nanometer range which have potential application at photocatalysis, oxygen reduction reaction, etc.

Spherical and tubule nanocarriers for sustained drug release

PubMed Central

Shutava, T.; Fakhrullin, R.; Lvov, Y.

2014-01-01

We discuss new trends in Layer-by-Layer (LbL) encapsulation of spherical and tubular cores of 50–150 nm diameter and loaded with drugs. This core size decrease (from few micrometers to a hundred of nanometers) for LbL encapsulation required development of sonication assistant non-washing technique and shell PEGylation to reach high colloidal stability of drug nanocarriers at 2–3 mg/mL concentration in isotonic buffers and serum. For 120–170 nm spherical LbL nanocapsules of low soluble anticancer drugs, polyelectrolyte shell thickness controls drug dissolution. As for nanotube carriers, we concentrated on natural halloysite clay nanotubes as cores for LbL encapsulation that allows high drug loading and sustains its release over tens and hundreds hours. Further drug release prolongation was reached with formation of the tube-end stoppers. PMID:25450068

Interacting shells in AdS spacetime and chaos

NASA Astrophysics Data System (ADS)

Brito, Richard; Cardoso, Vitor; Rocha, Jorge V.

2016-07-01

We study the simplest two-body problem in asymptotically anti-de Sitter spacetime: two, infinitely thin, concentric spherical shells of matter. We include only gravitational interaction between the two shells, but we show that the dynamics of this system is highly nontrivial. We observe prompt collapse to a black hole, delayed collapse and even perpetual oscillatory motion, depending on the initial location of the shells (or their energy content). The system exhibits critical behavior, and we show strong hints that it is also chaotic.

Stability of thin shell wormholes with a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory

NASA Astrophysics Data System (ADS)

Eid, A.

2017-11-01

In the framework of Darmois-Israel formalism, the dynamics of motion equations of spherically symmetric thin shell wormholes that are supported by a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory are constructed. The stability analysis of a thin shell wormhole is also discussed using a linearized radial perturbation around static solutions at the wormhole throat. The existence of stable static solutions depends on the value of some parameters of dynamical shell.

Synthesis of SiO2-Coated Core-Shell ZnO Composites for Preparing High-Voltage Varistors

NASA Astrophysics Data System (ADS)

Qu, Xiao; Yao, Da-Chuan; Liu, Jin-Ran; Wang, Mao-Hua; Zhang, Han-Ping

2018-01-01

Monodispersed ZnO composite microspheres were successfully prepared by a facile ultrasound irradiation method. Then, the uniform core-shell structured composites were synthesized through the hydrolysis of tetraethyl orthosilicate on the surface of the ZnO composite microspheres. Microstructural studies of the as-obtained powders were carried out using the techniques of the x-ray powder diffraction, field emission scanning electron microscopy and transmission electron microscopy with energy dispersive x-ray spectroscopy. The results show that the pink ZnO composite powders as the core were spherical structures with the size of approximately 100 nm, and the SiO2 shell was fully coated on the surface of the core. On the basis of these results, the effect of SiO2 content on the thickness of the synthesized composites and microstructure, as well as the electrical properties of the ZnO varistors sintered in air at 1150°C for 2 h, were fully studied. In particular, the ZnO varistor prepared with the appropriate amount of the SiO2 coating (˜40 nm) leads to a superior electrical performance with the high breakdown voltage of 418 V mm-1 and an excellent nonlinear coefficient of 70.7, compared with the varistors obtained without the SiO2 coating. The high performance is attributed to the smaller and more homogeneous ZnO grains obtained via the SiO2 coating.

Central depression in nuclear density and its consequences for the shell structure of superheavy nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Afanasjev, A.V.; Laboratory of Radiation Physics, Institute of Solid State Physics, University of Latvia, LV 2169 Salaspils, Miera str. 31; Frauendorf, S.

The influence of the central depression in the density distribution of spherical superheavy nuclei on the shell structure is studied within the relativistic mean-field theory. A large depression leads to the shell gaps at the proton Z=120 and neutron N=172 numbers, whereas a flatter density distribution favors N=184 and leads to the appearance of a Z=126 shell gap and to the decrease of the size of the Z=120 shell gap. The correlations between the magic shell gaps and the magnitude of the central depression are discussed for relativistic and nonrelativistic mean field theories.

Method of fabricating nested shells and resulting product

DOEpatents

Henderson, Timothy M.; Kool, Lawrence B.

1982-01-01

A multiple shell structure and a method of manufacturing such structure wherein a hollow glass microsphere is surface treated in an organosilane solution so as to render the shell outer surface hydrophobic. The surface treated glass shell is then suspended in the oil phase of an oil-aqueous phase dispersion. The oil phase includes an organic film-forming monomer, a polymerization initiator and a blowing agent. A polymeric film forms at each phase boundary of the dispersion and is then expanded in a blowing operation so as to form an outer homogeneously integral monocellular substantially spherical thermoplastic shell encapsulating an inner glass shell of lesser diameter.

A general low frequency acoustic radiation capability for NASTRAN

NASA Technical Reports Server (NTRS)

Everstine, G. C.; Henderson, F. M.; Schroeder, E. A.; Lipman, R. R.

1986-01-01

A new capability called NASHUA is described for calculating the radiated acoustic sound pressure field exterior to a harmonically-excited arbitrary submerged 3-D elastic structure. The surface fluid pressures and velocities are first calculated by coupling a NASTRAN finite element model of the structure with a discretized form of the Helmholtz surface integral equation for the exterior fluid. After the fluid impedance is calculated, most of the required matrix operations are performed using the general matrix manipulation package (DMAP) available in NASTRAN. Far field radiated pressures are then calculated from the surface solution using the Helmholtz exterior integral equation. Other output quantities include the maximum sound pressure levels in each of the three coordinate planes, the rms and average surface pressures and normal velocities, the total radiated power and the radiation efficiency. The overall approach is illustrated and validated using known analytic solutions for submerged spherical shells subjected to both uniform and nonuniform applied loads.

CLASSICAL AREAS OF PHENOMENOLOGY: Material parameter equation for rotating elliptical spherical cloaks

NASA Astrophysics Data System (ADS)

Ma, Hua; Qu, Shao-Bo; Xu, Zhuo; Zhang, Jie-Qiu; Wang, Jia-Fu

2009-01-01

By using the coordinate transformation method, we have deduced the material parameter equation for rotating elliptical spherical cloaks and carried out simulation as well. The results indicate that the rotating elliptical spherical cloaking shell, which is made of meta-materials whose permittivity and permeability are governed by the equation deduced in this paper, can achieve perfect invisibility by excluding electromagnetic fields from the internal region without disturbing any external field.

Composite Materials for Maxillofacial Prostheses.

DTIC Science & Technology

1981-08-01

necessary and Identify byv block number) MAXILLOFACIAL PROSTHESES; PROSTHETIC MATERIALS: MICROCAPSULES : SOFT FILLERS; ELASTOMER COMPOSITES 2,. ABSTRACT...used as fillers in the fabrication of maxillofacial prostheses. The projected systems are elastomeric-shelled, liquid-filled microcapsules . Improvements...elastomeric-shelled, liquid-filled microcapsules . Experiments continued on the interfacial polymerization process, with spherical, sealed, capsules

A versatile cooperative template-directed coating method to construct uniform microporous carbon shells for multifunctional core-shell nanocomposites.

PubMed

Guan, Buyuan; Wang, Xue; Xiao, Yu; Liu, Yunling; Huo, Qisheng

2013-03-21

A very simple cooperative template-directed coating method is developed for the preparation of core-shell, hollow, and yolk-shell microporous carbon nanocomposites. Particularly, the cationic surfactant C16TMA(+)·Br(-) used in the coating procedure improves the core dispersion in the reaction media and serves as the soft template for mesostructured resorcinol-formaldehyde resin formation, which results in the uniform polymer and microporous carbon shell coating on most functional cores with different surface properties. The core diameter and the shell thickness of the nanocomposites can be precisely tailored. This approach is highly reproducible and scalable. Several grams of polymer and carbon nanocomposites can be easily prepared by a facile one-pot reaction. The Au@hydrophobic microporous carbon yolk-shell catalyst favors the reduction of more hydrophobic nitrobenzene than hydrophilic 4-nitrophenol by sodium borohydride, which makes this type of catalyst@carbon yolk-shell composites promising nanomaterials as selective catalysts for hydrophobic reactants.

Radiative transfer in spherical shell atmospheres. I - Rayleigh scattering

NASA Technical Reports Server (NTRS)

Adams, C. N.; Kattawar, G. W.

1978-01-01

The plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere are compared and are applied to the study of a planet the size of the earth with a homogeneous conservative Rayleigh scattering atmosphere extending to a height of 100 km. Inadequacies of the approximations are considered. Radiance versus height distributions for both single and multiple scattering are presented, as are results for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. The data can be used for remote sensing applications and planetary spectroscopy.

Local-area simulations of rotating compressible convection and associated mean flows

NASA Technical Reports Server (NTRS)

Hurlburt, Neal E.; Brummell, N. H.; Toomre, Juri

1995-01-01

The dynamics of compressible convection within a curved local segment of a rotating spherical shell are considered in relation to the turbulent redistribution of angular momentum within the solar convection zone. Current supercomputers permit fully turbulent flows to be considered within the restricted geometry of local area models. By considering motions in a curvilinear geometry in which the Coriolos parameters vary with latitude, Rossby waves which couple with the turbulent convection are thought of as being possible. Simulations of rotating convection are presented in such a curved local segment of a spherical shell using a newly developed, sixth-order accurate code based on compact finite differences.

Coulomb matrix elements in multi-orbital Hubbard models.

PubMed

Bünemann, Jörg; Gebhard, Florian

2017-04-26

Coulomb matrix elements are needed in all studies in solid-state theory that are based on Hubbard-type multi-orbital models. Due to symmetries, the matrix elements are not independent. We determine a set of independent Coulomb parameters for a d-shell and an f-shell and all point groups with up to 16 elements (O h , O, T d , T h , D 6h , and D 4h ). Furthermore, we express all other matrix elements as a function of the independent Coulomb parameters. Apart from the solution of the general point-group problem we investigate in detail the spherical approximation and first-order corrections to the spherical approximation.

Nonlinear generation of large-scale magnetic fields in forced spherical shell dynamos

DOE Office of Scientific and Technical Information (OSTI.GOV)

Livermore, P. W.; Hughes, D. W.; Tobias, S. M.

2010-03-15

In an earlier paper [P. W. Livermore, D. W. Hughes, and S. M. Tobias, ''The role of helicity and stretching in forced kinematic dynamos in a spherical shell'', Phys. Fluids 19, 057101 (2007)], we considered the kinematic dynamo action resulting from a forced helical flow in a spherical shell. Although mean field electrodynamics suggests that the resulting magnetic field should have a significant mean (axisymmetric) component, we found no evidence for this; the dynamo action was distinctly small scale. Here we extend our investigation into the nonlinear regime in which the magnetic field reacts back on the velocity via themore » Lorentz force. Our main result is somewhat surprising, namely, that nonlinear effects lead to a considerable change in the structure of the magnetic field, its final state having a significant mean component. By investigating the dominant flow-field interactions, we isolate the dynamo mechanism and show schematically how the generation process differs between the kinematic and nonlinear regimes. In addition, we are able to calculate some components of the transport coefficient {alpha} and thus discuss our results within the context of mean field electrodynamics.« less

ShellFit: Reconstruction in the MiniCLEAN Detector

NASA Astrophysics Data System (ADS)

Seibert, Stanley

2010-02-01

The MiniCLEAN dark matter experiment is an ultra-low background liquid cryogen detector with a fiducial volume of approximately 150 kg. Dark matter candidate events produce ultraviolet scintillation light in argon at 128 nm and in neon at 80 nm. In order to detect this scintillation light, the target volume is enclosed by acrylic plates forming a spherical shell upon which an organic fluor, tetraphenyl butadiene (TPB), has been applied. TPB absorbs UV light and reemits visible light isotropically which can be detected by photomultiplier tubes. Two significant sources of background events in MiniCLEAN are decays of radon daughters embedded in the acrylic surface and external sources of neutrons, such as the photomultiplier tubes themselves. Both of these backgrounds can be mitigated by reconstructing the origin of the scintillation light and cutting events beyond a particular radius. The scrambling of photon trajectories at the TPB surface makes this task very challenging. The ``ShellFit'' algorithm for reconstructing event position and energy in a detector with a spherical wavelength-shifting shell will be described. The performance of ShellFit will be demonstrated using Monte Carlo simulation of several event types in the MiniCLEAN detector. )

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE PAGES

Velikovich, A. L.; Schmit, P. F.

2015-12-28

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-12-01

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining the "instantaneous growth rate" are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].

The influence of ozone and aerosols on the brightness and color of the twilight zone

NASA Technical Reports Server (NTRS)

Adams, C. N.; Plass, G. N.; Kattawar, G. W.

1973-01-01

The radiance and color of the twilight sky are calculated for single scattered radiation with the use of spherically symmetric models of the earth's atmosphere. Spherical geometry is used throughout the calculations with no plane parallel approximations. Refraction effects are taken into account through fine subdivision of the atmosphere into spherical shells of fixed index of refraction. Shell's law of refraction is used to calculate a direction of travel each time that a photon traverses the interface between layers. Five different models of the atmosphere were used: a pure molecular scattering atmosphere; molecular atmosphere plus ozone absorption; and three models with aerosol concentrations of 1, 3, and 10 times normal together with molecular scattering and ozone absorption. The results of the calculations are shown for various observation positions and local viewing angles in the solar plane for wavelengths in the range of 0.40 microns to 0.75 microns.

Acoustical scattering by multilayer spherical elastic scatterer containing electrorheological layer.

PubMed

Cai, Liang-Wu; Dacol, Dacio K; Orris, Gregory J; Calvo, David C; Nicholas, Michael

2011-01-01

A computational procedure for analyzing acoustical scattering by multilayer concentric spherical scatterers having an arbitrary mixture of acoustic and elastic materials is proposed. The procedure is then used to analyze the scattering by a spherical scatterer consisting of a solid shell and a solid core encasing an electrorheological (ER) fluid layer, and the tunability in the scattering characteristics afforded by the ER layer is explored numerically. Tunable scatterers with two different ER fluids are analyzed. One, corn starch in peanut oil, shows that a significant increase in scattering cross-section is possible in moderate frequencies. Another, fine poly-methyl methacrylate (PMMA) beads in dodecane, shows only slight change in scattering cross-sections overall. But, when the shell is thin, a noticeable local resonance peak can appear near ka=1, and this resonance can be turned on or off by the external electric field.

Gravitational potential energy of the earth: A spherical harmonic approach

NASA Technical Reports Server (NTRS)

Rubincam, D. P.

1977-01-01

A spherical harmonic equation for the gravitational potential energy of the earth is derived for an arbitrary density distribution by conceptually bringing in mass-elements from infinity and building up the earth shell upon spherical shell. The zeroth degree term in the spherical harmonic equation agrees with the usual expression for the energy of a radial density distribution. The second degree terms give a maximum nonhydrostatic energy in the mantle and crust of -2.77 x 10 to the twenty-ninth power ergs, an order of magnitude. If the earth is assumed to be a homogeneous viscous oblate spheroid relaxing to an equilibrium shape, then a lower limit to the mantle viscosity of 1.3 x 10 to the twentieth power poises is found by assuming the total geothermal flux is due to viscous dissipation. If the nonequilibrium figure is dynamically maintained by the earth acting as a heat engine at one per cent efficiency, then the viscosity is ten to the twenty second power poises, a number preferred by some as the viscosity of the mantle.

Acoustically excited surface waves on empty or fluid-filled cylindrical and spherical shells

NASA Astrophysics Data System (ADS)

Ahyi, A. Claude; Cao, H.; Raju, P. K.; Werby, M. F.; Bao, X. L.; Überall, H.

2002-05-01

A comparative study is presented of the acoustical excitation of circumferential (surface) waves on fluid-immersed cylindrical or spherical metal shells, which may be either evacuated, or filled with the same or a different fluid. The excited surface waves can manifest themselves by the resonances apparent in the sound scattering amplitude, which they cause upon phase matching following repeated circumnavigations of the target object, or by their re-radiation into the external fluid in the manner of head waves. We plot dispersion curves versus frequency of the surface waves, which for evacuated shells have a generally rising character, while the fluid filling adds an additional set of circumferential waves that descend with frequency. The resonances of these latter waves may also be interpreted as being due to phase matching, but they may alternately be interpreted as constituting the eigenfrequencies of the internal fluid contained in an elastic enclosure.

X-ray and Neutron Scattering Study of the Formation of Core–Shell-Type Polyoxometalates

DOE PAGES

Yin, Panchao; Wu, Bin; Mamontov, Eugene; ...

2016-02-05

A typical type of core-shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small angle X-ray scattering is used to study the structural features and stability of the core-shell structures in aqueous solutions. Time-resolved small angle X-ray scattering is applied to monitor the synthetic reactions and a three-stage formation mechanism is proposed to describe the synthesis of the core-shell polyoxometalates based on the monitoring results. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core-shell structures and two different types ofmore » water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures. A typical type of core shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small-angle X-ray scattering is used to study the structural features and stability of the core shell structures in aqueous solutions. Time-resolved small-angle X-ray scattering is applied to monitor the synthetic reactions, and a three-stage formation mechanism is proposed to describe the synthesis of the core shell polyoxometalates based on the monitoring results. New protocols have been developed by fitting the X-ray data with custom physical models, which provide more convincing, objective, and completed data interpretation. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core shell structures, and two different types of water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures.« less

Synthesis and Manipulation of Biofunctional Magnetic Particles

DTIC Science & Technology

2007-06-18

G. M., J Am. Chem. Soc., 2003, 125, 12704-12705. 6. "Asymmetric Dimers Can be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces of...Be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces of Spherical Silica Colloids", Lu, Y., Xiong, H. Jing, X., Xia, Y., Prentiss, M

Composite Materials for Maxillofacial Prostheses.

DTIC Science & Technology

1980-08-01

projected composite systems are elastomeric-shelled, liquid-filled * microcapsules . Experiments continued on the interfacial polymerization process with...filled microcapsules . Experiments continued on the interfacial polymerization process, with spherical, sealed, capsules achieved. Needs identified are...consists of liquid-filled, elastomeric-shelled microcapsules held together to form a deformable mass; this is to simulate the semi-liquid cellular structure

Mid-Infrared Interferometry on Spectral Lines. II. Continuum (Dust) Emission Around IRC +10216 and VY Canis Majoris

NASA Astrophysics Data System (ADS)

Monnier, J. D.; Danchi, W. C.; Hale, D. S.; Lipman, E. A.; Tuthill, P. G.; Townes, C. H.

2000-11-01

The University of California Berkeley Infrared Spatial Interferometer has measured the mid-infrared visibilities of the carbon star IRC +10216 and the red supergiant VY CMa. The dust shells around these sources have been previously shown to be time variable, and these new data are used to probe the evolution of the dust shells on a decade timescale, complementing contemporaneous studies at other wavelengths. Self-consistent, spherically symmetric models at maximum and minimum light both show the inner radius of the IRC +10216 dust shell to be much larger (150 mas) than expected from the dust-condensation temperature, implying that dust production has slowed or stopped in recent years. Apparently, dust does not form every pulsational cycle (638 days), and these mid-infrared results are consistent with recent near-infrared imaging, which indicates little or no new dust production in the last 3 yr. Spherically symmetric models failed to fit recent VY CMa data, implying that emission from the inner dust shell is highly asymmetric and/or time variable.

Morphology conserving aminopropyl functionalization of hollow silica nanospheres in toluene

NASA Astrophysics Data System (ADS)

Dobó, Dorina G.; Berkesi, Dániel; Kukovecz, Ákos

2017-07-01

Inorganic nanostructures containing cavities of monodisperse diameter distribution find applications in e.g. catalysis, adsorption and drug delivery. One of their possible synthesis routes is the template assisted core-shell synthesis. We synthesized hollow silica spheres around polystyrene cores by the sol-gel method. The polystyrene template was removed by heat treatment leaving behind a hollow spherical shell structure. The surface of the spheres was then modified by adding aminopropyl groups. Here we present the first experimental evidence that toluene is a suitable alternative functionalization medium for the resulting thin shells, and report the comprehensive characterization of the amino-functionalized hollow silica spheres based on scanning electron microscopy, transmission electron microscopy, N2 adsorption, FT-IR spectroscopy, Raman spectroscopy and electrokinetic potential measurement. Both the presence of the amino groups and the preservation of the hollow spherical morphology were unambiguously proven. The introduction of the amine functionality adds amphoteric character to the shell as shown by the zeta potential vs. pH function. Unlike pristine silica particles, amino-functionalized nanosphere aqueous sols can be stable at both acidic and basic conditions.

First fossil gravid turtle provides insight into the evolution of reproductive traits in turtles.

PubMed

Zelenitsky, Darla K; Therrien, Franc Ois; Joyce, Walter G; Brinkman, Donald B

2008-12-23

Here we report on the first discovery of shelled eggs inside the body cavity of a fossil turtle and on an isolated egg clutch, both referable to the Cretaceous turtle Adocus. These discoveries provide a unique opportunity to gain insight into the reproductive traits of an extinct turtle and to understand the evolution of such traits among living turtles. The gravid adult and egg clutch indicate that Adocus laid large clutches of rigid-shelled spherical eggs and established their nests near rivers, traits that are shared by its closest living relatives, the soft-shelled turtles. Adocus eggshell, however, was probably more rigid than that of living turtles, based on its great thickness and structure, features that may represent unique adaptations to intense predation or to arid nest environments. In light of the reproductive traits observed in Adocus, the distribution of reproductive traits among turtles reveals that large clutches of rigid-shelled eggs are primitive for hidden-necked turtles (cryptodirans) and that spherical eggs may have evolved independently within this group.

The electric field of a uniformly charged cubic shell

NASA Astrophysics Data System (ADS)

McCreery, Kaitlin; Greenside, Henry

2018-01-01

As an integrative and insightful example for undergraduates learning about electrostatics, we discuss how to use symmetry, Coulomb's law, superposition, Gauss's law, and visualization to understand the electric field E (x ,y ,z ) produced by a uniformly charged cubic shell. We first discuss how to deduce qualitatively, using freshman-level physics, the perhaps surprising fact that the interior electric field is nonzero and has a complex structure, pointing inwards from the middle of each face of the shell and pointing outwards towards each edge and corner. We then discuss how to understand the quantitative features of the electric field by plotting an analytical expression for E along symmetry lines and on symmetry surfaces of the shell.

Inertial modes and their transition to turbulence in a differentially rotating spherical gap flow

NASA Astrophysics Data System (ADS)

Hoff, Michael; Harlander, Uwe; Andrés Triana, Santiago; Egbers, Christoph

2016-04-01

We present a study of inertial modes in a spherical shell experiment. Inertial modes are Coriolis-restored linear wave modes, often arise in rapidly-rotating fluids (e.g. in the Earth's liquid outer core [1]). Recent experimental works showed that inertial modes exist in differentially rotating spherical shells. A set of particular inertial modes, characterized by (l,m,ˆω), where l, m is the polar and azimuthal wavenumber and ˆω = ω/Ωout the dimensionless frequency [2], has been found. It is known that they arise due to eruptions in the Ekman boundary layer of the outer shell. But it is an open issue why only a few modes develop and how they get enhanced. Kelley et al. 2010 [3] showed that some modes draw their energy from detached shear layers (e.g. Stewartson layers) via over-reflection. Additionally, Rieutord et al. (2012) [4] found critical layers within the shear layers below which most of the modes cannot exist. In contrast to other spherical shell experiments, we have a full optical access to the flow. Therefore, we present an experimental study of inertial modes, based on Particle-Image-Velocimetry (PIV) data, in a differentially rotating spherical gap flow where the inner sphere is subrotating or counter-rotating at Ωin with respect to the outer spherical shell at Ωout, characterized by the Rossby number Ro = (Ωin - Ωout)/Ωout. The radius ratio of η = 1/3, with rin = 40mm and rout = 120mm, is close to that of the Earth's core. Our apparatus is running at Ekman numbers (E ≈ 10-5, with E = ν/(Ωoutrout2), two orders of magnitude higher than most of the other experiments. Based on a frequency-Rossby number spectrogram, we can partly confirm previous considerations with respect to the onset of inertial modes. In contrast, the behavior of the modes in the counter-rotation regime is different. We found a triad interaction between three dominant inertial modes, where one is a slow axisymmetric Rossby mode [5]. We show that the amplitude of the most dominant mode (l,m,ˆω) = (3,2,˜ 0.71) is increasing with increasing |Ro| until a critical Rossby number Rocrit. Accompanying with this is an increase of the zonal mean flow outside the tangent cylinder, leading to enhanced angular momentum transport. At the particular Rocrit, the wave mode, and the entire flow, breaks up into smaller-scale turbulence [6], together with a strong increase of the zonal mean flow inside the tangent cylinder. We found that the critical Rossby number scales approximately with E1/5. References [1] Aldridge, K. D.; Lumb, L. I. (1987): Inertial waves identified in the Earth's fluid outer core. Nature 325 (6103), S. 421-423. DOI: 10.1038/325421a0. [2] Greenspan, H. P. (1968): The theory of rotating fluids. London: Cambridge U.P. (Cambridge monographs on mechanics and applied mathematics). [3] Kelley, D. H.; Triana, S. A.; Zimmerman, D. S.; Lathrop, D. P. (2010): Selection of inertial modes in spherical Couette flow. Phys. Rev. E 81 (2), 26311. DOI: 10.1103/PhysRevE.81.026311. [4] Rieutord, M.; Triana, S. A.; Zimmerman, D. S.; Lathrop, D. P. (2012): Excitation of inertial modes in an experimental spherical Couette flow. Phys. Rev. E 86 (2), 026304. DOI: 10.1103/PhysRevE.86.026304. [5] Hoff, M., Harlander, U., Egbers, C. (2016): Experimental survey of linear and nonlinear inertial waves and wave instabilities in a spherical shell. J. Fluid Mech., (in print) [6] Kerswell, R. R. (1999): Secondary instabilities in rapidly rotating fluids: inertial wave breakdown. Journal of Fluid Mechanics 382, S. 283-306. DOI: 10.1017/S0022112098003954.

A circumferential crack in a cylindrical shell under tension.

NASA Technical Reports Server (NTRS)

Duncan-Fama, M. E.; Sanders, J. L., Jr.

1972-01-01

A closed cylindrical shell under uniform internal pressure has a slit around a portion of its circumference. Linear shallow shell theory predicts inverse square-root-type singularities in certain of the stresses at the crack tips. This paper reports the computed strength of these singularities for different values of a dimensionless parameter based on crack length, shell radius and shell thickness.

Enhanced direct-drive implosions with thin high-Z ablation layers.

PubMed

Mostovych, Andrew N; Colombant, Denis G; Karasik, Max; Knauer, James P; Schmitt, Andrew J; Weaver, James L

2008-02-22

New direct-drive spherical implosion experiments with deuterium filled plastic shells have demonstrated significant and absolute (2x) improvements in neutron yield when the shells are coated with a very thin layer ( approximately 200-400 A) of high-Z material such as palladium. This improvement is interpreted as resulting from increased stability of the imploding shell. These results provide for a possible path to control laser imprint and stability in laser-fusion-energy target designs.

Radially Symmetric Motions of Nonlinearly Viscoelastic Bodies Under Live Loads

NASA Astrophysics Data System (ADS)

Stepanov, Alexey B.; Antman, Stuart S.

2017-12-01

This paper treats radially symmetric motions of nonlinearly viscoelastic circular-cylindrical and spherical shells subjected to the live loads of centrifugal force and (time-dependent) hydrostatic pressures. The governing equations are exact versions of those for 3-dimensional continuum mechanics (so shell does not connote an approximate via some shell theory). These motions are governed by quasilinear third-order parabolic-hyperbolic equations having but one independent spatial variable. The principal part of such a partial differential equation is determined by a general family of nonlinear constitutive equations. The presence of strains in two orthogonal directions requires a careful treatment of constitutive restrictions that are physically natural and support the analysis. The interaction of geometrically exact formulations, the compatible use of general constitutive equations for material response, and the presence of live loads show how these factors play crucial roles in the behavior of solutions. In particular, for different kinds of live loads there are thresholds separating materials that produce qualitatively different dynamical behavior. The analysis (using classical methods) covers infinite-time blowup for cylindrical shells subject to centrifugal forces, infinite-time blowup for cylindrical shells subject to steady and time-dependent hydrostatic pressures, finite-time blowup for spherical shells subject to steady and time-dependent hydrostatic pressures, and the preclusion of total compression. This paper concludes with a sketch (using some modern methods) of the existence of regular solutions until the time of blowup.

Casimir self-entropy of a spherical electromagnetic δ -function shell

NASA Astrophysics Data System (ADS)

Milton, Kimball A.; Kalauni, Pushpa; Parashar, Prachi; Li, Yang

2017-10-01

In this paper we continue our program of computing Casimir self-entropies of idealized electrical bodies. Here we consider an electromagnetic δ -function sphere ("semitransparent sphere") whose electric susceptibility has a transverse polarization with arbitrary strength. Dispersion is incorporated by a plasma-like model. In the strong-coupling limit, a perfectly conducting spherical shell is realized. We compute the entropy for both low and high temperatures. The transverse electric self-entropy is negative as expected, but the transverse magnetic self-entropy requires ultraviolet and infrared renormalization (subtraction), and, surprisingly, is only positive for sufficiently strong coupling. Results are robust under different regularization schemes. These rather surprising findings require further investigation.

Monostatic lidar/radar invisibility using coated spheres.

PubMed

Zhai, Peng-Wang; You, Yu; Kattawar, George W; Yang, Ping

2008-02-04

The Lorenz-Mie theory is revisited to explicitly include materials whose permeability is different from unity. The expansion coefficients of the scattered field are given for light scattering by both homogeneous and coated spheres. It is shown that the backscatter is exactly zero if the impedance of the spherical particles is equal to the intrinsic impedance of the surrounding medium. If spherical particles are sufficiently large, the zero backscatter can be explained as impedance matching using the asymptotic expression for the radar backscattering cross section. In the case of a coated sphere, the shell can be regarded as a cloak if the product of the thickness and the imaginary part of the refractive index of the outer shell is large.

Synergetic Effect of Yolk-Shell Structure and Uniform Mixing of SnS-MoS₂ Nanocrystals for Improved Na-Ion Storage Capabilities.

PubMed

Choi, Seung Ho; Kang, Yun Chan

2015-11-11

Mixed metal sulfide composite microspheres with a yolk-shell structure for sodium-ion batteries are studied. Tin-molybdenum oxide yolk-shell microspheres prepared by a one-pot spray pyrolysis process transform into yolk-shell SnS-MoS2 composite microspheres. The discharge capacities of the yolk-shell and dense-structured SnS-MoS2 composite microspheres for the 100th cycle are 396 and 207 mA h g(-1), and their capacity retentions measured from the second cycle are 89 and 47%, respectively. The yolk-shell SnS-MoS2 composite microspheres with high structural stability during repeated sodium insertion and desertion processes have low charge-transfer resistance even after long-term cycling. The synergetic effect of the yolk-shell structure and uniform mixing of the SnS and MoS2 nanocrystals result in the excellent sodium-ion storage properties of the yolk-shell SnS-MoS2 composite microspheres by improving their structural stability during cycling.

7 CFR 51.2085 - Fairly uniform color.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 7 Agriculture 2 2013-01-01 2013-01-01 false Fairly uniform color. 51.2085 Section 51.2085... Definitions § 51.2085 Fairly uniform color. Fairly uniform color means that the shells do not show excessive variation in color, whether bleached or natural. ...

7 CFR 51.2085 - Fairly uniform color.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 7 Agriculture 2 2014-01-01 2014-01-01 false Fairly uniform color. 51.2085 Section 51.2085... Definitions § 51.2085 Fairly uniform color. Fairly uniform color means that the shells do not show excessive variation in color, whether bleached or natural. ...

G7 BiSpherical Acetabular Shell PMCF Study

ClinicalTrials.gov

2017-11-22

Rheumatoid Arthritis; Osteoarthritis; Noninflammatory Degenerative Joint Disease; Avascular Necrosis; Correction of Functional Deformity; Non-Union Fracture; Femoral Neck Fractures; Trochanteric Fractures

Polarization effects on spectra of spherical core/shell nanostructures: Perturbation theory against finite difference approach

NASA Astrophysics Data System (ADS)

Ibral, Asmaa; Zouitine, Asmaa; Assaid, El Mahdi; El Achouby, Hicham; Feddi, El Mustapha; Dujardin, Francis

2015-02-01

Poisson equation is solved analytically in the case of a point charge placed anywhere in a spherical core/shell nanostructure, immersed in aqueous or organic solution or embedded in semiconducting or insulating matrix. Conduction and valence band-edge alignments between core and shell are described by finite height barriers. Influence of polarization charges induced at the surfaces where two adjacent materials meet is taken into account. Original expressions of electrostatic potential created everywhere in the space by a source point charge are derived. Expressions of self-polarization potential describing the interaction of a point charge with its own image-charge are deduced. Contributions of double dielectric constant mismatch to electron and hole ground state energies as well as nanostructure effective gap are calculated via first order perturbation theory and also by finite difference approach. Dependencies of electron, hole and gap energies against core to shell radii ratio are determined in the case of ZnS/CdSe core/shell nanostructure immersed in water or in toluene. It appears that finite difference approach is more efficient than first order perturbation method and that the effect of polarization charge may in no case be neglected as its contribution can reach a significant proportion of the value of nanostructure gap.

Chemical complexity in the winds of the oxygen-rich supergiant star VY Canis Majoris

NASA Astrophysics Data System (ADS)

Ziurys, L. M.; Milam, S. N.; Apponi, A. J.; Woolf, N. J.

2007-06-01

The interstellar medium is enriched primarily by matter ejected from old, evolved stars. The outflows from these stars create spherical envelopes, which foster gas-phase chemistry. The chemical complexity in circumstellar shells was originally thought to be dominated by the elemental carbon to oxygen ratio. Observations have suggested that envelopes with more carbon than oxygen have a significantly greater abundance of molecules than their oxygen-rich analogues. Here we report observations of molecules in the oxygen-rich shell of the red supergiant star VY Canis Majoris (VY CMa). A variety of unexpected chemical compounds have been identified, including NaCl, PN, HNC and HCO+. From the spectral line profiles, the molecules can be distinguished as arising from three distinct kinematic regions: a spherical outflow, a tightly collimated, blue-shifted expansion, and a directed, red-shifted flow. Certain species (SiO, PN and NaCl) exclusively trace the spherical flow, whereas HNC and sulphur-bearing molecules (amongst others) are selectively created in the two expansions, perhaps arising from shock waves. CO, HCN, CS and HCO+ exist in all three components. Despite the oxygen-rich environment, HCN seems to be as abundant as CO. These results suggest that oxygen-rich shells may be as chemically diverse as their carbon counterparts.

Chemical complexity in the winds of the oxygen-rich supergiant star VY Canis Majoris.

PubMed

Ziurys, L M; Milam, S N; Apponi, A J; Woolf, N J

2007-06-28

The interstellar medium is enriched primarily by matter ejected from old, evolved stars. The outflows from these stars create spherical envelopes, which foster gas-phase chemistry. The chemical complexity in circumstellar shells was originally thought to be dominated by the elemental carbon to oxygen ratio. Observations have suggested that envelopes with more carbon than oxygen have a significantly greater abundance of molecules than their oxygen-rich analogues. Here we report observations of molecules in the oxygen-rich shell of the red supergiant star VY Canis Majoris (VY CMa). A variety of unexpected chemical compounds have been identified, including NaCl, PN, HNC and HCO+. From the spectral line profiles, the molecules can be distinguished as arising from three distinct kinematic regions: a spherical outflow, a tightly collimated, blue-shifted expansion, and a directed, red-shifted flow. Certain species (SiO, PN and NaCl) exclusively trace the spherical flow, whereas HNC and sulphur-bearing molecules (amongst others) are selectively created in the two expansions, perhaps arising from shock waves. CO, HCN, CS and HCO+ exist in all three components. Despite the oxygen-rich environment, HCN seems to be as abundant as CO. These results suggest that oxygen-rich shells may be as chemically diverse as their carbon counterparts.

Interior of black holes and information recovery

NASA Astrophysics Data System (ADS)

Kawai, Hikaru; Yokokura, Yuki

2016-02-01

We analyze time evolution of a spherically symmetric collapsing matter from a point of view that black holes evaporate by nature. We first consider a spherical thin shell that falls in the metric of an evaporating Schwarzschild black hole of which the radius a (t ) decreases in time. The important point is that the shell can never reach a (t ) but it approaches a (t )-a (t )d/a (t ) d t . This situation holds at any radius because the motion of a shell in a spherically symmetric system is not affected by the outside. In this way, we find that the collapsing matter evaporates without forming a horizon. Nevertheless, a Hawking-like radiation is created in the metric, and the object looks the same as a conventional black hole from the outside. We then discuss how the information of the matter is recovered. We also consider a black hole that is adiabatically grown in the heat bath and obtain the interior metric. We show that it is the self-consistent solution of Gμ ν=8 π G ⟨Tμ ν⟩ and that the four-dimensional Weyl anomaly induces the radiation and a strong angular pressure. Finally, we analyze the internal structures of the charged and the slowly rotating black holes.

Quasi-static axisymmetric eversion hemispherical domes made of elastomers

NASA Astrophysics Data System (ADS)

Kabrits, Sergey A.; Kolpak, Eugeny P.

2016-06-01

The paper considers numerical solution for the problem of quasi-static axisymmetric eversion of a spherical shell (hemisphere) under action of external pressure. Results based on the general nonlinear theory of shells made of elastomers, proposed by K. F. Chernykh. It is used two models of shells based on the hypotheses of the Kirchhoff and Timoshenko, modified K.F. Chernykh for the case of hyperelastic rubber-like material. The article presents diagrams of equilibrium states of eversion hemispheres for both models as well as the shape of the shell at different points in the diagram.

Core-Shell-Corona Micelles with a Responsive Shell.

PubMed

Gohy, Jean-François; Willet, Nicolas; Varshney, Sunil; Zhang, Jian-Xin; Jérôme, Robert

2001-09-03

A reactor for the synthesis of gold nanoparticles is one of the uses of a poly(styrene)-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) triblock copolymer (PS-b-P2VP-b-PEO) which forms core-shell-corona micelles in water. Very low polydispersity spherical micelles are observed that consist of a PS core surrounded by a pH-sensitive P2VP shell and a corona of PEO chains end-capped by a hydroxyl group. The corona can act as a site for attaching responsive or sensing molecules. © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Review of high convergence implosion experiments with single and double shell targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delamater, N. D.; Watt, R. G.; Varnum, W. S.

2002-01-01

Experiments have been been performed in recent years at the Omega laser studying double shell capsules as an a1 teinative, 11011 cryogenic, path towards ignition at NTF. Double shell capsules designed to mitigate the Au M-band radiation asymmetries, were experimentally found to perform well in both spherical and cylindrical hohlraums, achieving near 1-D (-90 %) clean calculated yield at convergence comparable to that required for NIF ignition. Near-term plans include directly driven double shell experiments at Omega, which eliminates Au M-band radiation as a yield degradation m ec h an i s in.

Addendum to ''Thin-shell wormholes supported by ordinary matter in Einstein-Gauss-Bonnet gravity''

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simeone, Claudio

2011-04-15

Thin-shell wormholes are constructed starting from the exotic branch of the Wiltshire spherically symmetric solution of Einstein-Gauss-Bonnet gravity. The energy-momentum tensor of the shell is studied, and it is shown that configurations supported by matter satisfying the energy conditions exist for certain values of the parameters. Differing from the previous result associated with the normal branch of the Wiltshire solution, this is achieved for small positive values of the Gauss-Bonnet parameter and for vanishing charge.

Synthesis of poly(methyl methacrylate) core/chitosan-mixed-polyethyleneimine shell nanoparticles and their antibacterial property.

PubMed

Inphonlek, Supharat; Pimpha, Nuttaporn; Sunintaboon, Panya

2010-06-01

The core-shell nanoparticles possessing poly(methyl methacrylate) (PMMA) core coated with chitosan (CS), polyethyleneimine (PEI), and chitosan-mixed-polyethyleneimine (CS/PEI) shells were synthesized in this work. The emulsifier-free emulsion polymerization triggered by a redox initiating system from t-butylhydroperoxide (TBHP) and amine groups on CS and/or PEI was used as a synthetic method. In the CS/PEI systems, the amount of CS was kept constant (0.5g), while the amount of PEI was varied from 0.1 to 0.5g. The surface and physico-chemical properties of prepared nanoparticles were then examined. FTIR spectra indicated the presence of grafted PMMA on CS and/or PEI, and the weight fraction of incorporated PEI in the CS/PEI nanoparticles. All nanoparticles were spherical in shape with uniform size distribution illustrated by scanning electron microscopy (SEM). The introduction of PEI to CS nanoparticles yielded the higher monomer conversion, grafting efficiency, and grafting percentage compared with the CS nanoparticles. The size of CS/PEI nanoparticles was smaller than the original CS and PEI nanoparticles, and tended to decrease with increasing amount of PEI introduced. The introduction of PEI also brought the higher colloidal stability to the nanoparticles as indicated by zeta-potential measurement and isoelectric point analysis. The nanoparticles exhibited a promising antibacterial activity against Staphylococcus aureus and Escherichia coli. The nanoparticle-bacteria interaction was studied via SEM. The results suggested that they would be useful as effective antibacterial agents. Copyright 2010 Elsevier B.V. All rights reserved.

Electromagnetic Fields of a Uniform Sphere in a Uniform Conducting Medium with Application to Dipole Sources

DTIC Science & Technology

1991-09-01

12b. DISTRIBUTION CODE Approved for public release; distribution is unlimited. 13. ABSTRACT (Maximum 200 words) Vector spherical harmonic expansions are...electric and magnetic field vectors from E rand B - r alone. Genural expressions are given relating the scattered field expansion coefficients to the source...Prescnbed by ANSI Std. Z39-18 29W-102 NCSC TR 426-90 CONTENTS Pag o INTRODUCTION 1 BACKGROUND 1 ANGULAR MOMENTUM OPERATOR AND VECTOR SPHERICAL

METHOD OF MAKING SPHERICAL ACTINIDE CARBIDE

DOEpatents

White, G.D.; O'Rourke, D.C.

1962-12-25

This patent describes a method of making uniform, spherical, nonpyrophoric UC. UO/sub 2/ and carbon are mixed in stoichiometric proportions and passed through a plasma flame of inert gas at 10,000 to 13,000 deg C. (AEC)

Insight into the electrical properties and chain conformation of spherical polyelectrolyte brushes by dielectric spectroscopy

NASA Astrophysics Data System (ADS)

Guo, Xiaoxia; Zhao, Kongshuang

2017-02-01

We report here a dielectric study on three kinds of anionic spherical polyelectrolyte brush (SPBs, consisting of a polystyrene (PS) core and three different poly (acrylic acid) chains grafted onto the core) suspensions over a frequency ranging from 40 Hz to 110 MHz. The relaxation behavior of the SPB suspensions shows significant changes in the brush-layer properties when the mass fraction of SPBs and the pH of the suspensions change. Two definite relaxations related to the interfacial polarization are observed around 100 kHz and 10 MHz. A single-layer spherical-shell model is applied to describe the SPB suspensions wherein the suspended SPB is modeled as a spherical-shell composite particle in which an insulated PS sphere is surrounded by a conducting ion-permeable shell (the polyelectrolyte chain layer). We developed the curve-fitting procedure to analyze the dielectric spectrum in order to obtain the dielectric properties of the components of the SPBs, especially the properties of the polyelectrolyte brush. Based on this method and model, the permittivity and conductivity of the brush layer, ζ potential, etc are calculated. The ordered orientation of the water molecules in the layer leads to an additional electrical dipole moment; increasing pH causes the brush layer to swell. In addition, the repulsive force between the SPB particles are evaluated using the brush-layer thickness, which is obtained by fitting dielectric spectra, combined with relative theoretical formulas. Increasing PH values or SPB concentration would improve the stability of the SPBs dispersion.

Zonal Flow Velocimetry in Spherical Couette Flow using Acoustic Modes

NASA Astrophysics Data System (ADS)

Adams, Matthew M.; Mautino, Anthony R.; Stone, Douglas R.; Triana, Santiago A.; Lekic, Vedran; Lathrop, Daniel P.

2015-11-01

We present studies of spherical Couette flows using the technique of acoustic mode Doppler velocimetry. This technique uses rotational splittings of acoustic modes to infer the azimuthal velocity profile of a rotating flow, and is of special interest in experiments where direct flow visualization is impractical. The primary experimental system consists of a 60 cm diameter outer spherical shell concentric with a 20 cm diameter sphere, with air or nitrogen gas serving as the working fluid. The geometry of the system approximates that of the Earth's core, making these studies geophysically relevant. A turbulent shear flow is established in the system by rotating the inner sphere and outer shell at different rates. Acoustic modes of the fluid volume are excited using a speaker and measured via microphones, allowingdetermination of rotational splittings. Preliminary results comparing observed splittings with those predicted by theory are presented. While the majority of these studies were performed in the 60 cm diameter device using nitrogen gas, some work has also been done looking at acoustic modes in the 3 m diameter liquid sodium spherical Couette experiment. Prospects for measuring zonal velocity profiles in a wide variety of experiments are discussed.

Ariel 6 measurements of ultra-heavy cosmic ray fluxes in the region 34 or = Z or = 48

NASA Technical Reports Server (NTRS)

Fowler, P. H.; Masheder, M. R. W.; Moses, R. T.; Walker, R. N. F.; Worley, A.; Gay, A. M.

1985-01-01

The Ariel VI satellite was launched by NASA on a Scout rocket on 3rd June 1979 from Wallops Island, Virginia, USA, into a near circular 625 km orbit inclined at 55 deg. It carried a spherical cosmic ray detector designed by a group from Bristol University. A spherical aluminum vessel of diameter 75 cm contains a gas scintillation mixture and a thin spherical shell of Pilot 425 plastic, and forms a single optical cavity viewed by 16 photomultipliers. Particle tracks through the detector may be characterized by their impact parameter p and by whether or not they pass through the cup of plastic scintillator placed between the sphere and the spacecraft body (referred to below as the Anti-Coincidence Detector or ACD). Individual particle charges are determined by separately measuring the gas scintillation and the Cerenkov emission from the plastic shell. This is possible because of the quite different distribution in time of these emissions.

Novel Architecture for a Long-Life, Lightweight Venus Lander

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bugby, D.; Seghi, S.; Kroliczek, E.

2009-03-16

This paper describes a novel concept for an extended lifetime, lightweight Venus lander. Historically, to operate in the 480 deg. C, 90 atm, corrosive, mostly CO{sub 2} Venus surface environment, previous landers have relied on thick Ti spherical outer shells and thick layers of internal insulation. But even the most resilient of these landers operated for only about 2 hours before succumbing to the environment. The goal on this project is to develop an architecture that extends lander lifetime to 20-25 hours and also reduces mass compared to the Pioneer Venus mission architecture. The idea for reducing mass is to:more » (a) contain the science instruments within a spherical high strength lightweight polymer matrix composite (PMC) tank; (b) surround the PMC tank with an annular shell of high performance insulation pre-pressurized to a level that (after landing) will exceed the external Venus surface pressure; and (c) surround the insulation with a thin Ti outer shell that contains only a net internal pressure, eliminating buckling overdesign mass. The combination of the PMC inner tank and thin Ti outer shell is lighter than a single thick Ti outer shell. The idea for extending lifetime is to add the following three features: (i) an expendable water supply that is placed within the insulation or is contained in an additional vessel within the PMC tank; (ii) a thin spherical evaporator shell placed within the insulation a short radial distance from the outer shell; and (iii) a thin heat-intercepting liquid cooled shield placed inboard of the evaporator shell. These features lower the temperature of the insulation below what it would have been with the insulation alone, reducing the internal heat leak and lengthening lifetime. The use of phase change materials (PCMs) inside the PMC tank is also analyzed as a lifetime-extending design option. The paper describes: (1) analytical modeling to demonstrate reduced mass and extended life; (2) thermal conductivity testing of high performance insulation as a function of temperature and pressure; (3) a bench-top ambient pressure thermal test of the evaporation system; and (4) a higher fidelity test, to be conducted in a high pressure, high temperature inert gas test chamber, of a small-scale Venus lander prototype (made from two hemispherical interconnecting halves) that includes all of the aforesaid features.22 CFR 125.4(b)(13) applicable.« less

Facile, general and template-free construction of monodisperse yolk-shell metal@carbon nanospheres.

PubMed

Xu, Fei; Lu, Yuheng; Ma, Junhao; Huang, Zhike; Su, Quanfei; Fu, Ruowen; Wu, Dingcai

2017-11-07

Herein, we report a general and template-free protocol to construct novel yolk-shell metal@carbon nanospheres based on confined interfacial copolymerization, which greatly simplifies the synthetic route, yields uniform nanospheres with controllable diameters, and results in highly porous carbon shells. The yolk-shell Au@carbon shows improved adsorption capacity and high catalytic ability due to the synergistic effect of Au and the porous carbon shell.

Sheet-like assemblies of spherical particles with point-symmetrical patches.

PubMed

Mani, Ethayaraja; Sanz, Eduardo; Roy, Soumyajit; Dijkstra, Marjolein; Groenewold, Jan; Kegel, Willem K

2012-04-14

We report a computational study on the spontaneous self-assembly of spherical particles into two-dimensional crystals. The experimental observation of such structures stabilized by spherical objects appeared paradoxical so far. We implement patchy interactions with the patches point-symmetrically (icosahedral and cubic) arranged on the surface of the particle. In these conditions, preference for self-assembly into sheet-like structures is observed. We explain our findings in terms of the inherent symmetry of the patches and the competition between binding energy and vibrational entropy. The simulation results explain why hollow spherical shells observed in some Keplerate-type polyoxometalates (POM) appear. Our results also provide an explanation for the experimentally observed layer-by-layer growth of apoferritin--a quasi-spherical protein.

Nano-structured silica coated mesoporous carbon micro-granules for potential application in water filtration

NASA Astrophysics Data System (ADS)

Das, Avik; Sen, D.; Mazumder, S.; Ghosh, A. K.

2017-05-01

A novel nano-composite spherical micro-granule has been synthesized using a facile technique of solvent evaporation induced assembly of nanoparticles for potential application in water filtration. The spherical micro-granule is comprised of nano-structured shell of hydrophilic silica encapsulating a hydrophobic mesoporous carbon at the core. Hierarchical structure of such core-shell micro-granules has been rigorously characterized using small-angle neutron and X-ray scattering techniques and complemented with scanning electron microscopy. The hydrophilic silica envelope around the carbon core helps in incorporation of such granules into the hydrophilic polymeric ultra-filtration membrane. The interstitial micro-pores present in the silica shell can serve as water transport channels and the mesoporus carbon core enhances the separation performance due its well adsorption characteristics. It has been found that the incorporation of such granules inside the ultra-filtration membrane indeed enhances the water permeability as well as the separation performance in a significant way.

Investigation on the effects of temperature dependency of material parameters on a thermoelastic loading problem

NASA Astrophysics Data System (ADS)

Kumar, Anil; Mukhopadhyay, Santwana

2017-08-01

The present work is concerned with the investigation of thermoelastic interactions inside a spherical shell with temperature-dependent material parameters. We employ the heat conduction model with a single delay term. The problem is studied by considering three different kinds of time-dependent temperature and stress distributions applied at the inner and outer surfaces of the shell. The problem is formulated by considering that the thermal properties vary as linear function of temperature that yield nonlinear governing equations. The problem is solved by applying Kirchhoff transformation along with integral transform technique. The numerical results of the field variables are shown in the different graphs to study the influence of temperature-dependent thermal parameters in various cases. It has been shown that the temperature-dependent effect is more prominent in case of stress distribution as compared to other fields and also the effect is significant in case of thermal shock applied at the two boundary surfaces of the spherical shell.

Structural investigation of spherical hollow excipient Mannit Q by X-ray microtomography.

PubMed

Kajihara, Ryusuke; Noguchi, Shuji; Iwao, Yasunori; Yasuda, Yuki; Segawa, Megumi; Itai, Shigeru

2015-11-10

The structure of Mannit Q particles, an excipient made by spray-drying a d-mannitol solution, and Mannit Q tablets were investigated by synchrotron X-ray microtomography. The Mannit Q particles had a spherical shape with a hollow core. The shells of the particles consisted of fine needle-shaped crystals, and columnar crystals were present in the hollows. These structural features suggested the following formation mechanism for the hollow particles:during the spray-drying process, the solvent rapidly evaporated from the droplet surface, resulting in the formation of shells made of fine needle-shaped crystals.Solvent remaining inside the shells then evaporated slowly and larger columnar crystals grew as the hollows formed. Although most of the Mannit Q particles were crushed on tableting, some of the particles retained their hollow structures, probably because the columnar crystals inside the hollows functioned as props. This demonstrated that the tablets with porous void spaces may be readily manufactured using Mannit Q. Copyright © 2015 Elsevier B.V. All rights reserved.

Coulomb excitations for a short linear chain of metallic shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhemchuzhna, Liubov, E-mail: lzhemchuzhna@unm.edu; Center for High Technology Materials, University of New Mexico, Albuquerque, New Mexico 87106; Gumbs, Godfrey

2015-03-15

A self-consistent-field theory is given for the electronic collective modes of a chain containing a finite number, N, of Coulomb-coupled spherical two-dimensional electron gases arranged with their centers along a straight line, for simulating electromagnetic response of a narrow-ribbon of metallic shells. The separation between nearest-neighbor shells is arbitrary and because of the quantization of the electron energy levels due to their confinement to the spherical surface, all angular momenta L of the Coulomb excitations, as well as their projections M on the quantization axis, are coupled. However, for incoming light with a given polarization, only one angular momentum quantummore » number is usually required. Therefore, the electromagnetic response of the narrow-ribbon of metallic shells is expected to be controlled externally by selecting different polarizations for incident light. We show that, when N = 3, the next-nearest-neighbor Coulomb coupling is larger than its value if they are located at opposite ends of a right-angle triangle forming the triad. Additionally, the frequencies of the plasma excitations are found to depend on the orientation of the line joining them with respect to the axis of quantization since the magnetic field generated from the induced oscillating electric dipole moment on one sphere can couple to the induced magnetic dipole moment on another. Although the transverse inter-shell electromagnetic coupling can be modeled by an effective dynamic medium, the longitudinal inter-shell Coulomb coupling, on the other hand, can still significantly modify the electromagnetic property of this effective medium between shells.« less

Benchmark solution of the dynamic response of a spherical shell at finite strain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Versino, Daniele; Brock, Jerry S.

2016-09-28

Our paper describes the development of high fidelity solutions for the study of homogeneous (elastic and inelastic) spherical shells subject to dynamic loading and undergoing finite deformations. The goal of the activity is to provide high accuracy results that can be used as benchmark solutions for the verification of computational physics codes. Furthermore, the equilibrium equations for the geometrically non-linear problem are solved through mode expansion of the displacement field and the boundary conditions are enforced in a strong form. Time integration is performed through high-order implicit Runge–Kutta schemes. Finally, we evaluate accuracy and convergence of the proposed method bymore » means of numerical examples with finite deformations and material non-linearities and inelasticity.« less

Mirror mount

DOEpatents

Humpal, H.H.

1987-11-10

A mirror mount is provided that allows free pitch, yaw and roll motion of the mirror while keeping the location of a point on the surface of the mirror fixed in the rest frame of reference of the mount. Yaw movement is provided by two yaw cylinders that are bearing mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell that is air bearing mounted to move between a clamp and an upper pedestal bearing. The centers of curvature of the spherical surfaces of the shell lie upon the point. Pitch motion and roll motion are separately and independently imparted to mirror by a pair of pitch paddles and a pair of roll paddles that are independently and separately moved by control rods driven by motors. 5 figs.

Mirror mount

DOEpatents

Humpal, H.H.

1986-03-21

A mirror mount is provided that allows free pitch, yaw and roll motion of the mirror while keeping the location of a point on the surface of the mirror fixed in the rest frame of reference of the mount. Yaw movement is provided by two yaw cylinders that are bearing mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell that is air bearing mounted to move between a clamp and an upper pedestal bearing. The centers of curvature of the spherical surfaces of the shell lie upon the point. Pitch motion and roll motion are separately and independently imparted to mirror by a pair of pitch paddles and a pair of roll paddles that are independently and separately moved by control rods driven by motors.

HEAT TRANSFER MEANS

DOEpatents

Fraas, A.P.; Wislicenus, G.F.

1961-07-11

A heat exchanger is adapted to unifomly cool a spherical surface. Equations for the design of a spherical heat exchanger hav~g tubes with a uniform center-to-center spining are given. The heat exchanger is illustrated in connection with a liquid-fueled reactor.

Calculation of the Transition Matrix for the Scattering of Acoustic Waves from a Thin Elastic Spherical Shell Using the ATILA Finite Element Code

DTIC Science & Technology

1994-03-01

products of radial Hankel functions and spherical harmonics. The chosen driving frequency was 474 Hz, corresponding to a value of ka 1, where k is the...spherical harmonics. The chosen driving frequency was 474 Hz, corresponding to a value of ka = 1, where k is the wavenumber of sound in water and a is...wife Adriana for her support, understanding, and for her help in typing this thesis. vi I. INTRODUCTION The utilization of sonar systems in

Strongly localized image states of spherical graphitic particles.

PubMed

Gumbs, Godfrey; Balassis, Antonios; Iurov, Andrii; Fekete, Paula

2014-01-01

We investigate the localization of charged particles by the image potential of spherical shells, such as fullerene buckyballs. These spherical image states exist within surface potentials formed by the competition between the attractive image potential and the repulsive centripetal force arising from the angular motion. The image potential has a power law rather than a logarithmic behavior. This leads to fundamental differences in the nature of the effective potential for the two geometries. Our calculations have shown that the captured charge is more strongly localized closest to the surface for fullerenes than for cylindrical nanotube.

THREE-DIMENSIONAL MODELING OF THE DYNAMICS OF THERAPEUTIC ULTRASOUND CONTRAST AGENTS

PubMed Central

Hsiao, Chao-Tsung; Lu, Xiaozhen; Chahine, Georges

2010-01-01

A 3-D thick-shell contrast agent dynamics model was developed by coupling a finite volume Navier-Stokes solver and a potential boundary element method flow solver to simulate the dynamics of thick-shelled contrast agents subjected to pressure waves. The 3-D model was validated using a spherical thick-shell model validated by experimental observations. We then used this model to study shell break-up during nonspherical deformations resulting from multiple contrast agent interaction or the presence of a nearby solid wall. Our simulations indicate that the thick viscous shell resists the contrast agent from forming a re-entrant jet, as normally observed for an air bubble oscillating near a solid wall. Instead, the shell thickness varies significantly from location to location during the dynamics, and this could lead to shell break-up caused by local shell thinning and stretching. PMID:20950929

Expanding relativistic shells and gamma-ray burst temporal structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fenimore, E.E.; Madras, C.D.; Nayakshin, S.

1996-12-01

Many models of gamma-ray bursts (GRBs) involve a shell expanding at extreme relativistic speeds. The shell of material expands in a photon-quiet phase for a period {ital t}{sub 0} and then becomes gamma-ray active, perhaps due to inhomogeneities in the interstellar medium or the generation of shocks. Based on kinematics, we relate the envelope of the emission of the event to the characteristics of the photon-quiet and photon-active phases. We initially assume local spherical symmetry wherein, on average, the same conditions prevail over the shell`s surface within angles the order of {Gamma}{sup {minus}1}, where {Gamma} is the Lorentz factor formore » the bulk motion. The contribution of the curvature to the temporal structure is comparable to the contribution from the overall expansion. As a result, GRB time histories from a shell should have an envelope similar to {open_quotes}FRED{close_quotes} (fast rise, exponential decay) events in which the rise time is related to the duration of the photon-active phase and the fall time is related to the duration of the photon-quiet phase. This result depends only on local spherical symmetry and, since most GRBs do not have such envelopes, we introduce the {open_quotes}shell symmetry{close_quotes} problem: the observed time history envelopes of most GRBs do not agree with that expected for a relativistic expanding shell. Although FREDs have the signature of a relativistic shell, they may not be due to a single shell, as required by some cosmological models. Some FREDs have precursors in which the peaks are separated by more than the expansion time required to explain FRED shape. Such a burst is most likely explained by a central engine; that is, the separation of the multiple peaks occurs because the central site produced multiple releases of energy on timescales comparable to the duration of the event. (Abstract Truncated)« less

Hydrodynamic stability and Ti-tracer distribution in low-adiabat OMEGA direct-drive implosions

NASA Astrophysics Data System (ADS)

Joshi, Tirtha R.

We discuss the hydrodynamic stability of low-adiabat OMEGA direct-drive implosions based on results obtained from simultaneous emission and absorption spectroscopy of a titanium tracer added to the target. The targets were deuterium filled, warm plastic shells of varying thicknesses and filling gas pressures with a submicron Ti-doped tracer layer initially located on the inner surface of the shell. The spectral features from the titanium tracer are observed during the deceleration and stagnation phases of the implosion, and recorded with a time integrated spectrometer (XRS1), streaked crystal spectrometer (SSCA) and three gated, multi-monochromatic X-ray imager (MMI) instruments fielded along quasi-orthogonal lines-of-sight. The time-integrated, streaked and gated data show simultaneous emission and absorption spectral features associated with titanium K-shell line transitions but only the MMI data provides spatially resolved information. The arrays of gated spectrally resolved images recorded with MMI were processed to obtain spatially resolved spectra characteristic of annular contour regions on the image. A multi-zone spectroscopic analysis of the annular spatially resolved spectra permits the extraction of plasma conditions in the core as well as the spatial distribution of tracer atoms. In turn, the titanium atom distribution provides direct evidence of tracer penetration into the core and thus of the hydrodynamic stability of the shell. The observations, timing and analysis indicate that during fuel burning the titanium atoms have migrated deep into the core and thus shell material mixing is likely to impact the rate of nuclear fusion reactions, i.e. burning rate, and the neutron yield of the implosion. We have found that the Ti atom number density decreases towards the center in early deceleration phase, but later in time the trend is just opposite, i.e., it increases towards the center of the implosion core. This is in part a consequence of the convergent effect of spherical geometry. The spatial profiles of Ti areal densities in the implosion core are extracted from space-resolved spectra and also evaluated using 1D spherical scaling. The trends are similar to the Ti number density spatial profiles. The areal densities extracted from data and 1D spherical scaling are very comparable in the outer spherical zones of the implosion core but significantly deviate in the innermost zone. We have observed that approximately 85% of the Ti atoms migrate into the hot core, while 15% of the atoms are still on the shell-fuel interface and contributing to the absorption. In addition, a method to extract the hot spot size based on the formation of the absorption feature in a sequence of annular spectra will be discussed. Results and trends are discussed as a function of target shell thickness and filling pressure, and laser pulse shape.

Liquid crystals in micron-scale droplets, shells and fibers

NASA Astrophysics Data System (ADS)

Urbanski, Martin; Reyes, Catherine G.; Noh, JungHyun; Sharma, Anshul; Geng, Yong; Subba Rao Jampani, Venkata; Lagerwall, Jan P. F.

2017-04-01

The extraordinary responsiveness and large diversity of self-assembled structures of liquid crystals are well documented and they have been extensively used in devices like displays. For long, this application route strongly influenced academic research, which frequently focused on the performance of liquid crystals in display-like geometries, typically between flat, rigid substrates of glass or similar solids. Today a new trend is clearly visible, where liquid crystals confined within curved, often soft and flexible, interfaces are in focus. Innovation in microfluidic technology has opened for high-throughput production of liquid crystal droplets or shells with exquisite monodispersity, and modern characterization methods allow detailed analysis of complex director arrangements. The introduction of electrospinning in liquid crystal research has enabled encapsulation in optically transparent polymeric cylinders with very small radius, allowing studies of confinement effects that were not easily accessible before. It also opened the prospect of functionalizing textile fibers with liquid crystals in the core, triggering activities that target wearable devices with true textile form factor for seamless integration in clothing. Together, these developments have brought issues center stage that might previously have been considered esoteric, like the interaction of topological defects on spherical surfaces, saddle-splay curvature-induced spontaneous chiral symmetry breaking, or the non-trivial shape changes of curved liquid crystal elastomers with non-uniform director fields that undergo a phase transition to an isotropic state. The new research thrusts are motivated equally by the intriguing soft matter physics showcased by liquid crystals in these unconventional geometries, and by the many novel application opportunities that arise when we can reproducibly manufacture these systems on a commercial scale. This review attempts to summarize the current understanding of liquid crystals in spherical and cylindrical geometry, the state of the art of producing such samples, as well as the perspectives for innovative applications that have been put forward.

Foam shell cryogenic ICF target

DOEpatents

Darling, Dale H.

1987-01-01

A uniform cryogenic layer of DT fuel is maintained in a fusion target having a low density, small pore size, low Z rigid foam shell saturated with liquid DT fuel. Capillary action prevents gravitational slumping of the fuel layer. The saturated shell may be cooled to produce a solid fuel layer.

Cloaks for suppression or enhancement of scattering of diffuse photon density waves

NASA Astrophysics Data System (ADS)

Renthlei, Lalruatfela; Ramakrishna, S. Anantha; Wanare, Harshawardhan

2018-07-01

Enhancement of wave-like characteristics of heavily damped diffuse photon density waves in a random medium by amplification can induce strongly localised resonances. These resonances can be used to either suppress or enhance scattering from an inhomogeneity in the random medium by cloaking the inhomogeneous region by a shell of random medium with the correct levels of absorption or amplification. A spherical core-shell structure consisting of a shell of a random amplifying medium is shown to enhance or suppress specific resonant modes. A shell with an absorbing random medium is also shown to suppress scattering which can also be used for cloaking the core region.

Synthesis and Characterization of SiO2@Y2MoO6:Eu3+ Core-Shell Structured Spherical Phosphors by Sol-Gel Process.

PubMed

Li, G Z; Liu, F H; Chu, Z S; Wu, D M; Yang, L B; Li, J L; Wang, M N; Wang, Z L

2016-04-01

SiO2@Y2MoO6:Eu3+ core-shell phosphors were prepared by the sol-gel process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDS), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as kinetic decays were used to characterize the resulting SiO2@Y2MoO6:Eu3+ core-shell phosphors. The XRD results demonstrated that the Y2MoO6:Eu3+ layers on the SiO2 spheres crystallized after being annealed at 700 °C and the crystallinity increased with raising the annealing temperature. The obtained core-shell phosphors have spherical shape with narrow size distribution (average size ca. 640 nm), non-agglomeration, and smooth surface. The thickness of the Y2MoO6:Eu3+ shells on the SiO2 cores could be easily tailored by varying the number of deposition cycles (70 nm for four deposition cycles). The Eul+ shows a strong PL emission (dominated by 5D0-7F2 red emission at 614 nm) under the excitation of 347 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the number of coating cycles.

Watermarking on 3D mesh based on spherical wavelet transform.

PubMed

Jin, Jian-Qiu; Dai, Min-Ya; Bao, Hu-Jun; Peng, Qun-Sheng

2004-03-01

In this paper we propose a robust watermarking algorithm for 3D mesh. The algorithm is based on spherical wavelet transform. Our basic idea is to decompose the original mesh into a series of details at different scales by using spherical wavelet transform; the watermark is then embedded into the different levels of details. The embedding process includes: global sphere parameterization, spherical uniform sampling, spherical wavelet forward transform, embedding watermark, spherical wavelet inverse transform, and at last resampling the mesh watermarked to recover the topological connectivity of the original model. Experiments showed that our algorithm can improve the capacity of the watermark and the robustness of watermarking against attacks.

The synthesis, self-assembling, and biocompatibility of a novel O-carboxymethyl chitosan cholate decorated with glycyrrhetinic acid.

PubMed

Du, Hongliang; Yang, Xiaoye; Pang, Xin; Zhai, Guangxi

2014-10-13

O-carboxymethyl chitosan (OCMC) was firstly decorated with cholic acid (CA) to acquire an amphiphilic polymer under alkaline condition. Then glycyrrhetinic acid (GA) was conjugated to the polymer via a succinate linker and finally treated with NaCO3 solution to obtain new conjugates for potential liver targeted delivery. These conjugates formed uniform aggregates with low critical aggregation concentrations (0.028-0.079 mg/mL) in PBS. The average diameter of cholic acid modified carboxymethyl chitosan (CMCA) aggregates (110-257 nm) decreased with the increase of CA substitution degree and became slightly larger after GA modification. Negative zeta potential (-15 mV) of GA decorated CMCA (GA-CMCA) revealed that the formation of negatively charged shells and spherical morphology was observed under transmission electron microscopy. Furthermore, hemolysis test, in vitro cytotoxicity assay and cellular uptake study all demonstrated the safety and feasibility of these conjugates as a promising carrier for liver targeted drug delivery. Copyright © 2014 Elsevier Ltd. All rights reserved.

Preparation of CMC-modified melamine resin spherical nano-phase change energy storage materials.

PubMed

Hu, Xiaofeng; Huang, Zhanhua; Zhang, Yanhua

2014-01-30

A novel carboxymethyl cellulose (CMC)-modified melamine-formaldehyde (MF) phase change capsule with excellent encapsulation was prepared by in situ polymerization. Effects of CMC on the properties of the capsules were studied by Fourier transformation infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), scanning electronic microscopy (SEM), X-ray diffractometry (XRD), and thermogravimetric analysis (TGA). The results showed that the CMC-modified capsules had an average diameter of about 50nm and good uniformity. The phase change enthalpy of the capsules was increased and the cracking ratio decreased by incorporating a suitable amount of CMC. The optimum phase change enthalpy of the nanocapsules was 83.46J/g, and their paraffin content was 63.1%. The heat resistance of the capsule shells decreased after CMC modification. In addition, the nanocapsule cracking ratio of the nanocapsules was 11.0%, which is highly attractive for their application as nano phase change materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

7 CFR 51.1407 - Fairly uniform in color.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 7 Agriculture 2 2014-01-01 2014-01-01 false Fairly uniform in color. 51.1407 Section 51.1407... Definitions § 51.1407 Fairly uniform in color. Fairly uniform in color means that the shells do not show sufficient variation in color to materially detract from the general appearance of the lot. ...

7 CFR 51.1407 - Fairly uniform in color.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 7 Agriculture 2 2013-01-01 2013-01-01 false Fairly uniform in color. 51.1407 Section 51.1407... Definitions § 51.1407 Fairly uniform in color. Fairly uniform in color means that the shells do not show sufficient variation in color to materially detract from the general appearance of the lot. ...

Gravastars in f (R ,T ) gravity

NASA Astrophysics Data System (ADS)

Das, Amit; Ghosh, Shounak; Guha, B. K.; Das, Swapan; Rahaman, Farook; Ray, Saibal

2017-06-01

We propose a unique stellar model under the f (R ,T ) gravity by using the conjecture of Mazur-Mottola [P. Mazur and E. Mottola, Report No. LA-UR-01-5067, P. Mazur and E. Mottola, Proc. Natl. Acad. Sci. USA 101, 9545 (2004), 10.1073/pnas.0402717101] which is known as gravastar and a viable alternative to the black hole as available in literature. This gravastar is described by the three different regions, viz., (I) Interior core region, (II) Intermediate thin shell, and (III) Exterior spherical region. The pressure within the interior region is equal to the constant negative matter density which provides a repulsive force over the thin spherical shell. This thin shell is assumed to be formed by a fluid of ultrarelativistic plasma and the pressure, which is directly proportional to the matter-energy density according to Zel'dovich's conjecture of stiff fluid [Y. B. Zel'dovich, Mon. Not. R. Astron. Soc. 160, 1 (1972), 10.1093/mnras/160.1.1P], does counterbalance the repulsive force exerted by the interior core region. The exterior spherical region is completely vacuum and assumed to be de Sitter spacetime which can be described by the Schwarzschild solution. Under this specification we find out a set of exact and singularity-free solution of the gravastar which presents several other physically valid features within the framework of alternative gravity.

ECCENTRIC ROLLING OF POWDER AND BONDING AGENT INTO SPHERICAL PELLETS

DOEpatents

Patton, G. Jr.; Zirinsky, S.

1961-06-01

A machine is described for pelletizing powder and bonding agent into spherical pellets of high density and uniform size. In this device, the material to be compacted is added to a flat circular pan which is moved in a circular orbit in a horizontal plane about an axis displaced from that of the pan's central axis without rotating the pan about its central axis. This movement causes the material contained therein to roll around the outside wall of the container and build up pellets of uniform shape, size, and density.

Low temperature grown ZnO@TiO{sub 2} core shell nanorod arrays for dye sensitized solar cell application

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goh, Gregory Kia Liang; Le, Hong Quang, E-mail: lehq@imre.a-star.edu.sg; Huang, Tang Jiao

High aspect ratio ZnO nanorod arrays were synthesized on fluorine-doped tin oxide glasses via a low temperature solution method. By adjusting the growth condition and adding polyethylenimine, ZnO nanorod arrays with tunable length were successfully achieved. The ZnO@TiO{sub 2} core shells structures were realized by a fast growth method of immersion into a (NH{sub 4}){sub 2}·TiF{sub 6} solution. Transmission electron microscopy, X-ray Diffraction and energy dispersive X-ray measurements all confirmed the existence of a titania shell uniformly covering the ZnO nanorod's surface. Results of solar cell testing showed that addition of a TiO{sub 2} shell to the ZnO nanorod significantlymore » increased short circuit current (from 4.2 to 5.2 mA/cm{sup 2}), open circuit voltage (from 0.6 V to 0.8 V) and fill factor (from 42.8% to 73.02%). The overall cell efficiency jumped from 1.1% for bare ZnO nanorod to 3.03% for a ZnO@TiO{sub 2} core shell structured solar cell with a 18–22 nm shell thickness, a nearly threefold increase. - Graphical abstract: The synthesis process of coating TiO{sub 2} shell onto ZnO nanorod core is shown schematically. A thin, uniform, and conformal shell had been grown on the surface of the ZnO core after immersing in the (NH{sub 4}){sub 2}·TiF{sub 6} solution for 5–15 min. - Highlights: • ZnO@TiO{sub 2} core shell nanorod has been grown on FTO substrate using low temperature solution method. • TEM, XRD, EDX results confirmed the existing of titana shell, uniformly covered rod's surface. • TiO{sub 2} shell suppressed recombination, demonstrated significant enhancement in cell's efficiency. • Core shell DSSC's efficiency achieved as high as 3.03%, 3 times higher than that of ZnO nanorods.« less

Cauchy horizon stability in a collapsing spherical dust cloud: II. Energy bounds for test fields and odd-parity gravitational perturbations

NASA Astrophysics Data System (ADS)

Ortiz, Néstor; Sarbach, Olivier

2018-01-01

We analyze the stability of the Cauchy horizon associated with a globally naked, shell-focussing singularity arising from the complete gravitational collapse of a spherical dust cloud. In a previous work, we have studied the dynamics of spherical test scalar fields on such a background. In particular, we proved that such fields cannot develop any divergences which propagate along the Cauchy horizon. In the present work, we extend our analysis to the more general case of test fields without symmetries and to linearized gravitational perturbations with odd parity. To this purpose, we first consider test fields possessing a divergence-free stress-energy tensor satisfying the dominant energy condition, and we prove that a suitable energy norm is uniformly bounded in the domain of dependence of the initial slice. In particular, this result implies that free-falling observers co-moving with the dust particles measure a finite energy of the field, even as they cross the Cauchy horizon at points lying arbitrarily close to the central singularity. Next, for the case of Klein–Gordon fields, we derive point-wise bounds from our energy estimates which imply that the scalar field cannot diverge at the Cauchy horizon, except possibly at the central singular point. Finally, we analyze the behaviour of odd-parity, linear gravitational and dust perturbations of the collapsing spacetime. Similarly to the scalar field case, we prove that the relevant gauge-invariant combinations of the metric perturbations stay bounded away from the central singularity, implying that no divergences can propagate in the vacuum region. Our results are in accordance with previous numerical studies and analytic work in the self-similar case.

Energy ejection in the collapse of a cold spherical self-gravitating cloud

NASA Astrophysics Data System (ADS)

Joyce, M.; Marcos, B.; Sylos Labini, F.

2009-08-01

When an open system of classical point particles interacting by Newtonian gravity collapses and relaxes violently, an arbitrary amount of energy may, in principle, be carried away by particles which escape to infinity. We investigate here, using numerical simulations, how this released energy and other related quantities (notably the binding energy and size of the virialized structure) depend on the initial conditions, for the one-parameter family of starting configurations given by randomly distributing N cold particles in a spherical volume. Previous studies have established that the minimal size reached by the system scales approximately as N1/3, a behaviour which follows trivially when the growth of perturbations (which regularize the singularity of the cold collapse in the N -> ∞ limit) is assumed to be unaffected by the boundaries. Our study shows that the energy ejected grows approximately in proportion to N1/3, while the fraction of the initial mass ejected grows only very slowly with N, approximately logarithmically, in the range of N simulated. We examine in detail the mechanism of this mass and energy ejection, showing explicitly that it arises from the interplay of the growth of perturbations with the finite size of the system. A net lag of particles compared to their uniform spherical collapse trajectories develops first at the boundaries and then propagates into the volume during the collapse. Particles in the outer shells are then ejected as they scatter through the time-dependent potential of an already re-expanding central core. Using modified initial configurations, we explore the importance of fluctuations at different scales and discreteness (i.e. non-Vlasov) effects in the dynamics.

Absolute Hugoniot measurements from a spherically convergent shock using x-ray radiography

NASA Astrophysics Data System (ADS)

Swift, Damian C.; Kritcher, Andrea L.; Hawreliak, James A.; Lazicki, Amy; MacPhee, Andrew; Bachmann, Benjamin; Döppner, Tilo; Nilsen, Joseph; Collins, Gilbert W.; Glenzer, Siegfried; Rothman, Stephen D.; Kraus, Dominik; Falcone, Roger W.

2018-05-01

The canonical high pressure equation of state measurement is to induce a shock wave in the sample material and measure two mechanical properties of the shocked material or shock wave. For accurate measurements, the experiment is normally designed to generate a planar shock which is as steady as possible in space and time, and a single state is measured. A converging shock strengthens as it propagates, so a range of shock pressures is induced in a single experiment. However, equation of state measurements must then account for spatial and temporal gradients. We have used x-ray radiography of spherically converging shocks to determine states along the shock Hugoniot. The radius-time history of the shock, and thus its speed, was measured by radiographing the position of the shock front as a function of time using an x-ray streak camera. The density profile of the shock was then inferred from the x-ray transmission at each instant of time. Simultaneous measurement of the density at the shock front and the shock speed determines an absolute mechanical Hugoniot state. The density profile was reconstructed using the known, unshocked density which strongly constrains the density jump at the shock front. The radiographic configuration and streak camera behavior were treated in detail to reduce systematic errors. Measurements were performed on the Omega and National Ignition Facility lasers, using a hohlraum to induce a spatially uniform drive over the outside of a solid, spherical sample and a laser-heated thermal plasma as an x-ray source for radiography. Absolute shock Hugoniot measurements were demonstrated for carbon-containing samples of different composition and initial density, up to temperatures at which K-shell ionization reduced the opacity behind the shock. Here we present the experimental method using measurements of polystyrene as an example.

Process for manufacture of inertial confinement fusion targets and resulting product

DOEpatents

Masnari, Nino A.; Rensel, Walter B.; Robinson, Merrill G.; Solomon, David E.; Wise, Kensall D.; Wuttke, Gilbert H.

1982-01-01

An ICF target comprising a spherical pellet of fusion fuel surrounded by a concentric shell; and a process for manufacturing the same which includes the steps of forming hemispheric shells of a silicon or other substrate material, adhering the shell segments to each other with a fuel pellet contained concentrically therein, then separating the individual targets from the parent substrate. Formation of hemispheric cavities by deposition or coating of a mold substrate is also described. Coatings or membranes may also be applied to the interior of the hemispheric segments prior to joining.

Octreotide-functionalized and resveratrol-loaded unimolecular micelles for targeted neuroendocrine cancer therapy

NASA Astrophysics Data System (ADS)

Xu, Wenjin; Burke, Jocelyn F.; Pilla, Srikanth; Chen, Herbert; Jaskula-Sztul, Renata; Gong, Shaoqin

2013-09-01

Medullary thyroid cancer (MTC) is a neuroendocrine tumor (NET) that is often resistant to standard therapies. Resveratrol suppresses MTC growth in vitro, but it has low bioavailability in vivo due to its poor water solubility and rapid metabolic breakdown, as well as lack of tumor-targeting ability. A novel unimolecular micelle based on a hyperbranched amphiphilic block copolymer was designed, synthesized, and characterized for NET-targeted delivery. The hyperbranched amphiphilic block copolymer consisted of a dendritic Boltorn® H40 core, a hydrophobic poly(l-lactide) (PLA) inner shell, and a hydrophilic poly(ethylene glycol) (PEG) outer shell. Octreotide (OCT), a peptide that shows strong binding affinity to somatostatin receptors, which are overexpressed on NET cells, was used as the targeting ligand. Resveratrol was physically encapsulated by the micelle with a drug loading content of 12.1%. The unimolecular micelles exhibited a uniform size distribution and spherical morphology, which were determined by both transmission electron microscopy (TEM) and dynamic light scattering (DLS). Cellular uptake, cellular proliferation, and Western blot analyses demonstrated that the resveratrol-loaded OCT-targeted micelles suppressed growth more effectively than non-targeted micelles. Moreover, resveratrol-loaded NET-targeted micelles affected MTC cells similarly to free resveratrol in vitro, with equal growth suppression and reduction in NET marker production. These results suggest that the H40-based unimolecular micelle may offer a promising approach for targeted NET therapy.

Small bending and stretching of sandwich-type shells

NASA Technical Reports Server (NTRS)

Reissner, Eric

1950-01-01

A theory has been developed for small bending and stretching of sandwich-type shells. This theory is an extension of the known theory of homogeneous thin elastic shells. It was found that two effects are important in the present problem, which are not normally of importance in the theory of curved shells: (1) the effect of transverse shear deformation and (2) the effect of transverse normal stress deformation. The first of these two effects has been known to be of importance in the theory of plates and beams. The second effect was found to occur in a manner which is typical for shells and has no counterpart in flat-plate theory. The general results of this report have been applied to the solution of problems concerning flat plates, circular rings, circular cylindrical shells, and spherical shells. In each case numerical examples have been given, illustrating the magnitude of the effects of transverse shear and normal stress deformation.

Tailoring sphere density for high pressure physical property measurements on liquids

NASA Astrophysics Data System (ADS)

Secco, R. A.; Tucker, R. F.; Balog, S. P.; Rutter, M. D.

2001-04-01

We present a new method of tailoring the density of a sphere for use as a probe in high pressure-temperature physical property experiments on liquids. The method consists of a composite sphere made of an inner, high density, metallic, spherical core and an exterior, low density, refractory, spherical shell or mantle. Micromechanical techniques are used to fabricate the composite sphere. We describe a relatively simple mechanical device that can grind hemispherical recesses as small as 200 μm in diameter in sapphire and as small as 500 μm in diameter in ruby hemispheres. Examples of composite spheres made with a Pt or WC core and Al2O3 shell used in metallic liquids pressurized to 16 GPa and 1900 K are shown.

Nonsymmetric dynamical thin-shell wormhole in Robinson-Trautman class

NASA Astrophysics Data System (ADS)

Svítek, O.; Tahamtan, T.

2018-02-01

The thin-shell wormhole created using the Darmois-Israel formalism applied to Robinson-Trautman family of spacetimes is presented. The stress energy tensor created on the throat is interpreted in terms of two dust streams and it is shown that asymptotically this wormhole settles to the Schwarzschild wormhole with a throat located at the position of the horizon. This behavior shows a nonlinear stability (within the Robinson-Trautman class) of this spherically symmetric wormhole. The gravitational radiation emitted by the Robinson-Trautman wormhole during the transition to spherical symmetry is indistinguishable from that of the corresponding black hole Robinson-Trautman spacetime. Subsequently, we show that the higher-dimensional generalization of Robinson-Trautman geometry offers a possibility of constructing wormholes without the need to violate the energy conditions for matter induced on the throat.

7 CFR 51.2085 - Fairly uniform color.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 7 Agriculture 2 2012-01-01 2012-01-01 false Fairly uniform color. 51.2085 Section 51.2085 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... color. Fairly uniform color means that the shells do not show excessive variation in color, whether...

7 CFR 51.2085 - Fairly uniform color.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 2 2011-01-01 2011-01-01 false Fairly uniform color. 51.2085 Section 51.2085 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... color. Fairly uniform color means that the shells do not show excessive variation in color, whether...

7 CFR 51.2085 - Fairly uniform color.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Fairly uniform color. 51.2085 Section 51.2085 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... color. Fairly uniform color means that the shells do not show excessive variation in color, whether...

Image reconstruction in cone-beam CT with a spherical detector using the BPF algorithm

NASA Astrophysics Data System (ADS)

Zuo, Nianming; Zou, Yu; Jiang, Tianzi; Pan, Xiaochuan

2006-03-01

Both flat-panel detectors and cylindrical detectors have been used in CT systems for data acquisition. The cylindrical detector generally offers a sampling of a transverse image plane more uniformly than does a flat-panel detector. However, in the longitudinal dimension, the cylindrical and flat-panel detectors offer similar sampling of the image space. In this work, we investigate a detector of spherical shape, which can yield uniform sampling of the 3D image space because the solid angle subtended by each individual detector bin remains unchanged. We have extended the backprojection-filtration (BPF) algorithm, which we have developed previously for cone-beam CT, to reconstruct images in cone-beam CT with a spherical detector. We also conduct computer-simulation studies to validate the extended BPF algorithm. Quantitative results in these numerical studies indicate that accurate images can be obtained from data acquired with a spherical detector by use of our extended BPF cone-beam algorithms.

Luminosity distance in ``Swiss cheese'' cosmology with randomized voids. II. Magnification probability distributions

NASA Astrophysics Data System (ADS)

Flanagan, Éanna É.; Kumar, Naresh; Wasserman, Ira; Vanderveld, R. Ali

2012-01-01

We study the fluctuations in luminosity distances due to gravitational lensing by large scale (≳35Mpc) structures, specifically voids and sheets. We use a simplified “Swiss cheese” model consisting of a ΛCDM Friedman-Robertson-Walker background in which a number of randomly distributed nonoverlapping spherical regions are replaced by mass-compensating comoving voids, each with a uniform density interior and a thin shell of matter on the surface. We compute the distribution of magnitude shifts using a variant of the method of Holz and Wald , which includes the effect of lensing shear. The standard deviation of this distribution is ˜0.027 magnitudes and the mean is ˜0.003 magnitudes for voids of radius 35 Mpc, sources at redshift zs=1.0, with the voids chosen so that 90% of the mass is on the shell today. The standard deviation varies from 0.005 to 0.06 magnitudes as we vary the void size, source redshift, and fraction of mass on the shells today. If the shell walls are given a finite thickness of ˜1Mpc, the standard deviation is reduced to ˜0.013 magnitudes. This standard deviation due to voids is a factor ˜3 smaller than that due to galaxy scale structures. We summarize our results in terms of a fitting formula that is accurate to ˜20%, and also build a simplified analytic model that reproduces our results to within ˜30%. Our model also allows us to explore the domain of validity of weak-lensing theory for voids. We find that for 35 Mpc voids, corrections to the dispersion due to lens-lens coupling are of order ˜4%, and corrections due to shear are ˜3%. Finally, we estimate the bias due to source-lens clustering in our model to be negligible.

Influence of corneal thickness on the intraocular pressure readings for Maklakoff's tonometer of different weight

NASA Astrophysics Data System (ADS)

Franus, D. V.

2018-05-01

Research is conducted into variation in the stress-strain state of the corneoscleral shell of the human eye under loading by a flat base stamp of varying weight. A three-dimensional finite-element model of the contact problem of loading of the corneoscleral shell in the ANSYS program package is presented. Cornea and sclera are modeled as conjugated transversely isotropic spherical shells. The cornea is modeled as a multilayer shell with variable thickness in which all modeled layers have their own individual elastic properties. The research deals with the numerical calculation of the diameter of the contact zone between the shell and the stamp. Values of correction coefficients for intraocular pressure are obtained depending on the thickness of the corneal shell in its center, allowing the true intraocular pressure to be determined more accurately.

Method and apparatus for generating microshells of refractory materials

NASA Technical Reports Server (NTRS)

Lee, Mark C. (Inventor); Schilling, Christopher (Inventor); Ladner, Jr., George O. (Inventor); Wang, Taylor G. (Inventor)

1987-01-01

A system is described for forming accurately spherical and centered fluid-filled shells, especially of high melting temperature material. Material which is to form the shells is placed in a solid form in a container, and the material is rapidly heated to a molten temperature to avoid recrystallization and the possible generation of unwanted microbubbles in the melt. Immediately after the molten shells are formed, they drop through a drop tower whose upper end is heated along a distance of at least one foot to provide time for dissipation of surface waves on the shells while they cool to a highly viscous, or just above melting temperature so that the bubble within the shell will not rise and become off centered. The rest of the tower is cryogenically cooled to cool the shell to a solid state.

Structural Basis for Near Unity Quantum Yield Core/Shell Nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

McBride, James; Treadway, Joe; Pennycook, Stephen J

2006-01-01

Aberration-corrected Z-contrast scanning transmission electron microscopy of core/shell nanocrystals shows clear correlations between structure and quantum efficiency. Uniform shell coverage is obtained only for a graded CdS/ZnS shell material and is found to be critical to achieving near 100% quantum yield. The sublattice sensitivity of the images confirms that preferential growth takes place on the anion-terminated surfaces. This explains the three-dimensional "nanobullet" shape observed in the case of core/shell nanorods.

Three-dimensional spherical models of convection in the earth's mantle

NASA Technical Reports Server (NTRS)

Bercovici, Dave; Schubert, Gerald; Glatzmaier, Gary A.

1989-01-01

Three-dimensional spherical models of mantle convection in the earth reveal that upwelling cylindrical plumes and downwelling planar sheets are the primary features of mantle circulation. Thus subduction zones and descending sheetlike slabs in the mantle are fundamental characteristics of thermal convection in a spherical shell and are not merely the consequences of the rigidity of the slabs, which are cooler than the surrounding mantle. Cylindrical mantle plumes that cause hot spots such as Hawaii are probably the only form of active upwelling and are therefore not just secondary convective currents separate from the large-scale mantle circulation.

Radiative shocks produced from spherical cryogenic implosions at the National Ignition Facility

DOE PAGES

Pak, A.; Divol, L.; Gregori, G.; ...

2013-05-20

Spherically expanding radiative shock waves have been observed from inertially confined implosion experiments at the National Ignition Facility. In these experiments, a spherical fusion target, initially 2 mm in diameter, is compressed via the pressure induced from the ablation of the outer target surface. At the peak compression of the capsule, x-ray and nuclear diagnostics indicate the formation of a central core, with a radius and ion temperature of ~20 μm and ~ 2 keV, respectively. This central core is surrounded by a cooler compressed shell of deuterium-tritium fuel that has an outer radius of ~40 μm and a densitymore » of >500 g/cm 3. Using inputs from multiple diagnostics, the peak pressure of the compressed core has been inferred to be of order 100 Gbar for the implosions discussed here. Furthermore, the shock front, initially located at the interface between the high pressure compressed fuel shell and surrounding in-falling low pressure ablator plasma, begins to propagate outwards after peak compression has been reached.« less

Interfacial effect on physical properties of composite media: Interfacial volume fraction with non-spherical hard-core-soft-shell-structured particles.

PubMed

Xu, Wenxiang; Duan, Qinglin; Ma, Huaifa; Chen, Wen; Chen, Huisu

2015-11-02

Interfaces are known to be crucial in a variety of fields and the interfacial volume fraction dramatically affects physical properties of composite media. However, it is an open problem with great significance how to determine the interfacial property in composite media with inclusions of complex geometry. By the stereological theory and the nearest-surface distribution functions, we first propose a theoretical framework to symmetrically present the interfacial volume fraction. In order to verify the interesting generalization, we simulate three-phase composite media by employing hard-core-soft-shell structures composed of hard mono-/polydisperse non-spherical particles, soft interfaces, and matrix. We numerically derive the interfacial volume fraction by a Monte Carlo integration scheme. With the theoretical and numerical results, we find that the interfacial volume fraction is strongly dependent on the so-called geometric size factor and sphericity characterizing the geometric shape in spite of anisotropic particle types. As a significant interfacial property, the present theoretical contribution can be further drawn into predicting the effective transport properties of composite materials.

Interfacial effect on physical properties of composite media: Interfacial volume fraction with non-spherical hard-core-soft-shell-structured particles

PubMed Central

Xu, Wenxiang; Duan, Qinglin; Ma, Huaifa; Chen, Wen; Chen, Huisu

2015-01-01

Interfaces are known to be crucial in a variety of fields and the interfacial volume fraction dramatically affects physical properties of composite media. However, it is an open problem with great significance how to determine the interfacial property in composite media with inclusions of complex geometry. By the stereological theory and the nearest-surface distribution functions, we first propose a theoretical framework to symmetrically present the interfacial volume fraction. In order to verify the interesting generalization, we simulate three-phase composite media by employing hard-core-soft-shell structures composed of hard mono-/polydisperse non-spherical particles, soft interfaces, and matrix. We numerically derive the interfacial volume fraction by a Monte Carlo integration scheme. With the theoretical and numerical results, we find that the interfacial volume fraction is strongly dependent on the so-called geometric size factor and sphericity characterizing the geometric shape in spite of anisotropic particle types. As a significant interfacial property, the present theoretical contribution can be further drawn into predicting the effective transport properties of composite materials. PMID:26522701

Self-consistent description of the SHFB equations for 112Sn

NASA Astrophysics Data System (ADS)

Ghafouri, M.; Sadeghi, H.; Torkiha, M.

2018-03-01

The Hartree-Fock (HF) method is an excellent approximation of the closed shell magic nuclei. Pair correlation is essential for the description of open shell nuclei and has been derived for even-even, odd-odd and even-odd nuclei. These effects are reported by Hartree-Fock with BCS (HFBCS) or Hartree-Fock-Bogolyubov (HFB). These issues have been investigated, especially in the nuclear charts, and such studies have been compared with the observed information. We compute observations such as total binding energy, charge radius, densities, separation energies, pairing gaps and potential energy surfaces for neutrons and protons, and compare them with experimental data and the result of the spherical codes. In spherical even-even neutron-rich nuclei are considered in the Skyrme-Hartree-Fock-Bogolyubov (SHFB) method with density-dependent pairing interaction. Zero-range density-dependent interactions is used in the pairing channel. We solve SHF or SHFB equations in the spatial coordinates with spherical symmetry for tin isotopes such as 112Sn. The numerical accuracy of solving equations in the coordinate space is much greater than the fundamental extensions, which yields almost precise results.

Compact Transducers and Arrays

DTIC Science & Technology

2005-05-01

Batra A, Priya S, Uchino K, Markley D, Newnham RE, Hofmann HF, "Energy harvesting using a piezoelectric "cymbal" transducer in dynamic environment...transducers, the flexural vibration of the metal shell causes an extensional vibration of the piezoelectric ceramic, or vice versa. Cymbal elements are...34On Axi-Symmetrical Vibrations of Shallow Spherical Shells," Quart. Appl. Math, 13 279 (1950). 19.R.S. Woollett, "Theory of the Piezoelectric Flexural

Resonant Vibrations and Vibrational Heating of Physically Nonlinear Viscoelastic Shells and Their Damping Using Piezoelectric Sensor and Actuator

NASA Astrophysics Data System (ADS)

Kirichok, I. F.

2017-09-01

Forced axisymmetric resonant vibrations and vibrational heating of viscoelastic, physically nonlinear, closed, spherical, and infinitely long cylindrical shells and ring with piezoelectric sensor and actuator are considered. The effect of physical nonlinearity of passive material on the vibration amplitude and vibrational heating temperature is studied. The possibility of active damping of vibrations by piezoelectric sensors and actuators is demonstrated.

Sound wave generation by a spherically symmetric outburst and AGN feedback in galaxy clusters II: impact of thermal conduction.

NASA Astrophysics Data System (ADS)

Tang, Xiaping; Churazov, Eugene

2018-04-01

We analyze the impact of thermal conduction on the appearance of a shock-heated gas shell which is produced when a spherically symmetric outburst of a supermassive black hole inflates bubbles of relativistic plasma at the center of a galaxy cluster. The presence of the hot and low-density shell can be used as an ancillary indicator for a high rate of energy release during the outburst, which is required to drive strong shocks into the gas. Here we show that conduction can effectively erase such shell, unless the diffusion of electrons is heavily suppressed. We conclude that a more robust proxy to the energy release rate is the ratio between the shock radius and bubble radius. We also revisited the issue of sound waves dissipation induced by thermal conduction in a scenario, where characteristic wavelength of the sound wave is set by the total energy of the outburst. For a fiducial short outburst model, the dissipation length does not exceed the cooling radius in a typical cluster, provided that the conduction is suppressed by a factor not larger than ˜100. For quasi-continuous energy injection neither the shock-heated shell nor the outgoing sound wave are important and the role of conduction is subdominant.

Superclustering in the explosion scenario. II - Prolate spheroidal shells from superconducting cosmic strings

NASA Technical Reports Server (NTRS)

Borden, David; Ostriker, Jeremiah P.; Weinberg, David H.

1989-01-01

If galaxies form on shells, then clusters of galaxies should form at the vertices where three shells intersect. Weinberg, Ostriker, and Dekel (WOD, 1989) studied this picture quantitatively and found that an intersecting spherical shell model reproduces many of the properties of the observed distribution of galaxy clusters, but that too much superclustering is produced. In this paper, the WOD analysis is repeated with prolate spheroids that could be created by superconducting cosmic strings. It is found that most of the attractive features of the WOD model are maintained in the more general case and there is slight improvement in some aspects, but that the overall problem of excessive superclustering is not really alleviated.

Fabrication of diamond shells

DOEpatents

Hamza, Alex V.; Biener, Juergen; Wild, Christoph; Woerner, Eckhard

2016-11-01

A novel method for fabricating diamond shells is introduced. The fabrication of such shells is a multi-step process, which involves diamond chemical vapor deposition on predetermined mandrels followed by polishing, microfabrication of holes, and removal of the mandrel by an etch process. The resultant shells of the present invention can be configured with a surface roughness at the nanometer level (e.g., on the order of down to about 10 nm RMS) on a mm length scale, and exhibit excellent hardness/strength, and good transparency in the both the infra-red and visible. Specifically, a novel process is disclosed herein, which allows coating of spherical substrates with optical-quality diamond films or nanocrystalline diamond films.

Thermodynamic Theory of Spherically Trapped Coulomb Clusters

NASA Astrophysics Data System (ADS)

Wrighton, Jeffrey; Dufty, James; Bonitz, Michael; K"{A}Hlert, Hanno

2009-11-01

The radial density profile of a finite number of identical charged particles confined in a harmonic trap is computed over a wide ranges of temperatures (Coulomb coupling) and particle numbers. At low temperatures these systems form a Coulomb crystal with spherical shell structure which has been observed in ultracold trapped ions and in dusty plasmas. The shell structure is readily reproduced in simulations. However, analytical theories which used a mean field approachfootnotetext[1]C. Henning et al., Phys. Rev. E 74, 056403 (2006) or a local density approximationfootnotetext[2]C. Henning et al., Phys. Rev. E 76, 036404 (2007) have, so far, only been able to reproduce the average density profile. Here we present an approach to Coulomb correlations based on the hypernetted chain approximation with additional bridge diagrams. It is demonstrated that this model reproduces the correct shell structure within a few percent and provides the basis for a thermodynamic theory of Coulomb clusters in the strongly coupled fluid state.footnotetext[3]J. Wrighton, J.W. Dufty, H. K"ahlert and M. Bonitz, J. Phys. A 42, 214052 (2009) and Phys. Rev. E (2009) (to be submitted)

Conserved charges of black holes in Weyl and Einstein-Gauss-Bonnet gravities

NASA Astrophysics Data System (ADS)

Peng, Jun-Jin

2014-11-01

An off-shell generalization of the Abbott-Deser-Tekin (ADT) conserved charge was recently proposed by Kim et al. They achieved this by introducing off-shell Noether currents and potentials. In this paper, we construct the crucial off-shell Noether current by the variation of the Bianchi identity for the expression of EOM, with the help of the property of Killing vector. Our Noether current, which contains an additional term that is just one half of the Lie derivative of a surface term with respect to the Killing vector, takes a different form in comparison with the one in their work. Then we employ the generalized formulation to calculate the quasi-local conserved charges for the most general charged spherically symmetric and the dyonic rotating black holes with AdS asymptotics in four-dimensional conformal Weyl gravity, as well as the charged spherically symmetric black holes in arbitrary dimensional Einstein-Gauss-Bonnet gravity coupled to Maxwell or nonlinear electrodynamics in AdS spacetime. Our results confirm those obtained through other methods in the literature.

Spherical loudspeaker array for local active control of sound.

PubMed

Rafaely, Boaz

2009-05-01

Active control of sound has been employed to reduce noise levels around listeners' head using destructive interference from noise-canceling sound sources. Recently, spherical loudspeaker arrays have been studied as multiple-channel sound sources, capable of generating sound fields with high complexity. In this paper, the potential use of a spherical loudspeaker array for local active control of sound is investigated. A theoretical analysis of the primary and secondary sound fields around a spherical sound source reveals that the natural quiet zones for the spherical source have a shell-shape. Using numerical optimization, quiet zones with other shapes are designed, showing potential for quiet zones with extents that are significantly larger than the well-known limit of a tenth of a wavelength for monopole sources. The paper presents several simulation examples showing quiet zones in various configurations.

Alternating current dielectrophoresis of core-shell nanoparticles: Experiments and comparison with theory

NASA Astrophysics Data System (ADS)

Yang, Chungja

Nanoparticles are fascinating where physical and optical properties are related to size. Highly controllable synthesis methods and nanoparticle assembly are essential for highly innovative technological applications. Well-defined shaped and sized nanoparticles enable comparisons between experiments, theory and subsequent new models to explain experimentally observed phenomena. Among nanoparticles, nonhomogeneous core-shell nanoparticles (CSnp) have new properties that arise when varying the relative dimensions of the core and the shell. This CSnp structure enables various optical resonances, and engineered energy barriers, in addition to the high charge to surface ratio. Assembly of homogeneous nanoparticles into functional structures has become ubiquitous in biosensors (i.e. optical labeling), nanocoatings, and electrical circuits. Limited nonhomogenous nanoparticle assembly has only been explored. Many conventional nanoparticle assembly methods exist, but this work explores dielectrophoresis (DEP) as a new method. DEP is particle polarization via non-uniform electric fields while suspended in conductive fluids. Most prior DEP efforts involve microscale particles. Prior work on core-shell nanoparticle assemblies and separately, nanoparticle characterizations with dielectrophoresis and electrorotation, did not systematically explore particle size, dielectric properties (permittivity and electrical conductivity), shell thickness, particle concentration, medium conductivity, and frequency. This work is the first, to the best of our knowledge, to systematically examine these dielectrophoretic properties for core-shell nanoparticles. Further, we conduct a parametric fitting to traditional core-shell models. These biocompatible core-shell nanoparticles were studied to fill a knowledge gap in the DEP field. Experimental results (chapter 5) first examine medium conductivity, size and shell material dependencies of dielectrophoretic behaviors of spherical CSnp into 2D and 3D particle-assemblies. Chitosan (amino sugar) and poly-L-lysine (amino acid, PLL) CSnp shell materials were custom synthesized around a hollow (gas) core by utilizing a phospholipid micelle around a volatile fluid templating for the shell material; this approach proves to be novel and distinct from conventional core-shell models wherein a conductive core is coated with an insulative shell. Experiments were conducted within a 100 nl chamber housing 100 um wide Ti/Au quadrapole electrodes spaced 25 um apart. Frequencies from 100kHz to 80MHz at fixed local field of 5Vpp were tested with 10-5 and 10-3 S/m medium conductivities for 25 seconds. Dielectrophoretic responses of ~220 and 340(or ~400) nm chitosan or PLL CSnp were compiled as a function of medium conductivity, size and shell material. Experiments further examined shell thickness and particle concentration (chapter 6) dependencies on ~530 nm CSnp dielectrophoretic and electrorotational responses with ~30nm and ~80 nm shell thicknesses and at particle concentration count rates of 5000 +/- 500, 10000 +/- 500, and 15000 +/- 500 counts per second. Using similar experimental conditions, both dielectrophoretic and electrorotational CSnp responses were compiled versus frequency, shell thickness, and particle concentration. Knowledge gained from this study includes a unique resonance-like dielectrophoretic and electrorotational spectrum, which is significantly distinct from other cells and particles. CSnp dielectric properties were then calculated by parametrically fitting parameters to an existing core-shell model. The optimum conductivity and relative permittivity for the core and the shell are 1E-15 S/m, 1, 0.6 S/m, and 90, respectively. These properties can be exploited to rapidly assemble these unique core-shell particles for future structural color production in fabrics, vehicle, and wall painting.

7 CFR 51.1407 - Fairly uniform in color.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 2 2011-01-01 2011-01-01 false Fairly uniform in color. 51.1407 Section 51.1407 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... in color. Fairly uniform in color means that the shells do not show sufficient variation in color to...

7 CFR 51.1407 - Fairly uniform in color.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 7 Agriculture 2 2012-01-01 2012-01-01 false Fairly uniform in color. 51.1407 Section 51.1407 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... in color. Fairly uniform in color means that the shells do not show sufficient variation in color to...

7 CFR 51.1407 - Fairly uniform in color.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Fairly uniform in color. 51.1407 Section 51.1407 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards... in color. Fairly uniform in color means that the shells do not show sufficient variation in color to...

Stress Analysis of Composite Cylindrical Shells with an Elliptical Cutout

NASA Technical Reports Server (NTRS)

Oterkus, E.; Madenci, E.; Nemeth, M. P.

2007-01-01

A special-purpose, semi-analytical solution method for determining the stress and deformation fields in a thin laminated-composite cylindrical shell with an elliptical cutout is presented. The analysis includes the effects of cutout size, shape, and orientation; non-uniform wall thickness; oval-cross-section eccentricity; and loading conditions. The loading conditions include uniform tension, uniform torsion, and pure bending. The analysis approach is based on the principle of stationary potential energy and uses Lagrange multipliers to relax the kinematic admissibility requirements on the displacement representations through the use of idealized elastic edge restraints. Specifying appropriate stiffness values for the elastic extensional and rotational edge restraints (springs) allows the imposition of the kinematic boundary conditions in an indirect manner, which enables the use of a broader set of functions for representing the displacement fields. Selected results of parametric studies are presented for several geometric parameters that demonstrate that analysis approach is a powerful means for developing design criteria for laminated-composite shells.

Formation mechanism of monodispersed spherical core-shell ceria/polymer hybrid nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Izu, Noriya, E-mail: n-izu@aist.go.jp; Uchida, Toshio; Matsubara, Ichiro

2011-08-15

Graphical abstract: The formation mechanism for core-shell nanoparticles is considered to be as follows: nucleation and particle growth occur simultaneously (left square); very slow particle growth occurs (middle square). Highlights: {yields} The size of the resultant nanoparticles was strongly and complicatedly dependent on the set temperature used during reflux heating and the PVP molecular weight. {yields} The size of the nanoparticles increased by a 2-step process as the reflux heating time increased. {yields} The IR spectral changes with increasing reflux time indicated the increase in the number of cross-linked polymers in the shell. -- Abstract: Very unique core-shell ceria (ceriummore » oxide)/polymer hybrid nanoparticles that have monodispersed spherical structures and are easily dispersed in water or alcohol without the need for a dispersant were reported recently. The formation mechanism of the unique nanoparticles, however, was not clear. In order to clarify the formation mechanism, these nanoparticles were prepared using a polyol method (reflux heating) under varied conditions of temperature, time, and concentration and molecular weight of added polymer (poly(vinylpyrrolidone)). The size of the resultant nanoparticles was strongly and complicatedly dependent on the set temperature used during reflux heating and the poly(vinylpyrrolidone) molecular weight. Furthermore, the size of the nanoparticles increased by a 2-step process as the reflux heating time increased. The IR spectral changes with increasing reflux time indicated the increase in the number of cross-linked polymers in the shell. From these results, the formation mechanism was discussed and proposed.« less

Far Field Boundary Conditions for Underwater Explosions

DTIC Science & Technology

1994-12-22

NSWCDDfTR-94/20 CHAPTER 1 INTRODUCTION A factor controlling the computational resources required to model an underwater explo- sion is the extent of...NSWCDD/TRI-94/20 SPHERICAL SHOCKS The explosion of a spherical TNT charge in a uniform water environment is modeled in spherical coordinates. The TNT is...described using a JWL equation of state while the water is modeled using a modified Tait equation of state.6 The TNT is assumed to combust

Nuclear shapes: Quest for triaxiality in 86Ge and the shape of 98Zr

NASA Astrophysics Data System (ADS)

Werner, V.; Lettmann, M.; Lizarazo, C.; Witt, W.; Cline, D.; Carpenter, M.; Doornenbal, P.; Obertelli, A.; Pietralla, N.; Savard, G.; Söderström, P.-A.; Wu, C.-Y.; Zhu, S.

2018-05-01

The region of neutron-rich nuclei above the N = 50 magic neutron shell closure encompasses a rich variety of nuclear structure, especially shapeevolutionary phenomena. This can be attributed to the complexity of sub-shell closures, their appearance and disappearance in the region, such as the N = 56 sub shell or Z = 40 for protons. Structural effects reach from a shape phase transition in the Zr isotopes, over shape coexistence between spherical, prolate, and oblate shapes, to possibly rigid triaxial deformation. Recent experiments in this region and their main physics viewpoints are summarized.

Apparatus for irradiating a continuously flowing stream of fluid. [For neutron activation analysis

DOEpatents

Speir, L.G.; Adams, E.L.

1982-05-13

An apparatus for irradiating a continuously flowing stream of fluid is disclosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4..pi.. radiation geometry. The irradiation source, for example a /sup 252/Cf neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

Apparatus for irradiating a continuously flowing stream of fluid

DOEpatents

Speir, Leslie G.; Adams, Edwin L.

1984-01-01

An apparatus for irradiating a continuously flowing stream of fluid is diosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4.pi. radiation geometry. The irradiation source, for example a .sup.252 CF neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

Reversible patterning of spherical shells through constrained buckling

NASA Astrophysics Data System (ADS)

Marthelot, J.; Brun, P.-T.; Jiménez, F. López; Reis, P. M.

2017-07-01

Recent advances in active soft structures envision the large deformations resulting from mechanical instabilities as routes for functional shape morphing. Numerous such examples exist for filamentary and plate systems. However, examples with double-curved shells are rarer, with progress hampered by challenges in fabrication and the complexities involved in analyzing their underlying geometrical nonlinearities. We show that on-demand patterning of hemispherical shells can be achieved through constrained buckling. Their postbuckling response is stabilized by an inner rigid mandrel. Through a combination of experiments, simulations, and scaling analyses, our investigation focuses on the nucleation and evolution of the buckling patterns into a reticulated network of sharp ridges. The geometry of the system, namely, the shell radius and the gap between the shell and the mandrel, is found to be the primary ingredient to set the surface morphology. This prominence of geometry suggests a robust, scalable, and tunable mechanism for reversible shape morphing of elastic shells.

High-value utilization of egg shell to synthesize Silver and Gold-Silver core shell nanoparticles and their application for the degradation of hazardous dyes from aqueous phase-A green approach.

PubMed

Sinha, Tanur; Ahmaruzzaman, M

2015-09-01

The common household material, egg shell of Anas platyrhynchos is utilized for the synthesis of Silver and Gold-Silver core shell nanoparticles using greener, environment friendly and economic way. The egg shell extracts were acting as a stabilizing and reducing agents. This method avoids the use of external reducing and stabilizing agents, templates and solvents. The effects of various reaction parameters, such as reaction temperature, concentration in the formation of nanoparticles have also been investigated. The compositional abundance of gelatin may be envisaged for the effective reductive as well as stabilizing potency. The mechanisms for the formation of NPs have also been presented. The synthesized Ag NPs formed were predominantly spherical in nature with an average size of particles in the range of 6-26 nm. While, Au-Ag core shell nanoparticles formed were spherical and oval shaped, within a narrow size spectrum of 9-18 nm. Both the Ag NPs Au-and Ag core shell nanoparticles showed characteristic Bragg's reflection planes of fcc structure and surface plasmon resonance at 430 nm and 365 nm, respectively. The NPs were utilized for the removal of toxic and hazardous dyes, such as Rose Bengal, Methyl Violet 6 B and Methylene Blue from aqueous phase. Approximately 98.2%, 98.4% and 97% degradations of Rose Bengal, Methyl Violet 6 B, and Methylene Blue were observed with Ag NPs, while the percentage degradation of these dyes was 97.3%, 97.6% and 96% with Au-Ag NPs, respectively. Therefore, the present study has opened up an innovative way for synthesizing Ag NPs and Au-Ag bimetallic nanostructures of different morphologies and sizes involving the utilization of egg shell extract. The high efficiency of the NPs as photocatalysts has opened a promising application for the removal of hazardous dyes from the industrial effluents. Copyright © 2015 Elsevier Inc. All rights reserved.

General route to multifunctional uniform yolk/mesoporous silica shell nanocapsules: a platform for simultaneous cancer-targeted imaging and magnetically guided drug delivery.

PubMed

Zhang, Lingyu; Wang, Tingting; Yang, Lei; Liu, Cong; Wang, Chungang; Liu, Haiyan; Wang, Y Andrew; Su, Zhongmin

2012-09-24

Hollow mesoporous SiO(2) (mSiO(2)) nanostructures with movable nanoparticles (NPs) as cores, so-called yolk-shell nanocapsules (NCs), have attracted great research interest. However, a highly efficient, simple and general way to produce yolk-mSiO(2) shell NCs with tunable functional cores and shell compositions is still a great challenge. A facile, general and reproducible strategy has been developed for fabricating discrete, monodisperse and highly uniform yolk-shell NCs under mild conditions, composed of mSiO(2) shells and diverse functional NP cores with different compositions and shapes. These NPs can be Fe(3)O(4) NPs, gold nanorods (GNRs), and rare-earth upconversion NRs, endowing the yolk-mSiO(2) shell NCs with magnetic, plasmonic, and upconversion fluorescent properties. In addition, multifunctional yolk-shell NCs with tunable interior hollow spaces and mSiO(2) shell thickness can be precisely controlled. More importantly, fluorescent-magnetic-biotargeting multifunctional polyethyleneimine (PEI)-modified fluorescent Fe(3)O(4)@mSiO(2) yolk-shell nanobioprobes as an example for simultaneous targeted fluorescence imaging and magnetically guided drug delivery to liver cancer cells is also demonstrated. This synthetic approach can be easily extended to the fabrication of multifunctional yolk@mSiO(2) shell nanostructures that encapsulate various functional movable NP cores, which construct a potential platform for the simultaneous targeted delivery of drug/gene/DNA/siRNA and bio-imaging. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Modifying the size and uniformity of upconversion Yb/Er:NaGdF4 nanocrystals through alkaline-earth doping.

PubMed

Lei, Lei; Chen, Daqin; Huang, Ping; Xu, Ju; Zhang, Rui; Wang, Yuansheng

2013-11-21

NaGdF4 is regarded as an ideal upconversion (UC) host material for lanthanide (Ln(3+)) activators because of its unique crystal structure, high Ln(3+) solubility, low phonon energy and high photochemical stability, and Ln(3+)-doped NaGdF4 UC nanocrystals (NCs) have been widely investigated as bio-imaging and magnetic resonance imaging agents recently. To realize their practical applications, controlling the size and uniformity of the monodisperse Ln(3+)-doped NaGdF4 UC NCs is highly desired. Unlike the routine routes by finely adjusting the multiple experimental parameters, herein we provide a facile and straightforward strategy to modify the size and uniformity of NaGdF4 NCs via alkaline-earth doping for the first time. With the increase of alkaline-earth doping content, the size of NaGdF4 NCs increases gradually, while the size-uniformity is still retained. We attribute this "focusing" of size distribution to the diffusion controlled growth of NaGdF4 NCs induced by alkaline-earth doping. Importantly, adopting the Ca(2+)-doped Yb/Er:NaGdF4 NCs as cores, the complete Ca/Yb/Er:NaGdF4@NaYF4 core-shell particles with excellent size-uniformity can be easily achieved. However, when taking the Yb/Er:NaGdF4 NCs without Ca(2+) doping as cores, they could not be perfectly covered by NaYF4 shells, and the obtained products are non-uniform in size. As a result, the UC emission intensity of the complete core-shell NCs increases by about 30 times in comparison with that of the cores, owing to the effective surface passivation of the Ca(2+)-doped cores and therefore protection of Er(3+) in the cores from the non-radiative decay caused by surface defects, whereas the UC intensity of the incomplete core-shell NCs is enhanced by only 3 times.

Multi-parameter actuation of a neutrally stable shell: a flexible gear-less motor.

PubMed

Hamouche, W; Maurini, C; Vidoli, S; Vincenti, A

2017-08-01

We have designed and tested experimentally a morphing structure consisting of a neutrally stable thin cylindrical shell driven by a multi-parameter piezoelectric actuation. The shell is obtained by plastically deforming an initially flat copper disc, so as to induce large isotropic and almost uniform inelastic curvatures. Following the plastic deformation, in a perfectly isotropic system, the shell is theoretically neutrally stable, having a continuous set of stable cylindrical shapes corresponding to the rotation of the axis of maximal curvature. Small imperfections render the actual structure bistable, giving preferred orientations. A three-parameter piezoelectric actuation, exerted through micro-fibre-composite actuators, allows us to add a small perturbation to the plastic inelastic curvature and to control the direction of maximal curvature. This actuation law is designed through a geometrical analogy based on a fully nonlinear inextensible uniform-curvature shell model. We report on the fabrication, identification and experimental testing of a prototype and demonstrate the effectiveness of the piezoelectric actuators in controlling its shape. The resulting motion is an apparent rotation of the shell, controlled by the voltages as in a 'gear-less motor', which is, in reality, a precession of the axis of principal curvature.

Multi-parameter actuation of a neutrally stable shell: a flexible gear-less motor

NASA Astrophysics Data System (ADS)

Hamouche, W.; Maurini, C.; Vidoli, S.; Vincenti, A.

2017-08-01

We have designed and tested experimentally a morphing structure consisting of a neutrally stable thin cylindrical shell driven by a multi-parameter piezoelectric actuation. The shell is obtained by plastically deforming an initially flat copper disc, so as to induce large isotropic and almost uniform inelastic curvatures. Following the plastic deformation, in a perfectly isotropic system, the shell is theoretically neutrally stable, having a continuous set of stable cylindrical shapes corresponding to the rotation of the axis of maximal curvature. Small imperfections render the actual structure bistable, giving preferred orientations. A three-parameter piezoelectric actuation, exerted through micro-fibre-composite actuators, allows us to add a small perturbation to the plastic inelastic curvature and to control the direction of maximal curvature. This actuation law is designed through a geometrical analogy based on a fully nonlinear inextensible uniform-curvature shell model. We report on the fabrication, identification and experimental testing of a prototype and demonstrate the effectiveness of the piezoelectric actuators in controlling its shape. The resulting motion is an apparent rotation of the shell, controlled by the voltages as in a `gear-less motor', which is, in reality, a precession of the axis of principal curvature.

Interfacial effect on the structural and optical properties of pure SnO2 and dual shells (ZnO; SiO2) coated SnO2 core-shell nanospheres for optoelectronic applications

NASA Astrophysics Data System (ADS)

Selvi, N.; Sankar, S.; Dinakaran, K.

2014-12-01

Nanocrystallites of SnO2 core and dual shells (ZnO, SiO2) coated SnO2 core-shell nanospheres were successfully synthesized by co-precipitation method. The as prepared and annealed samples were characterized by X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), High resolution transmission electron microscopy (HRTEM) and UV-Vis analysis. XRD pattern confirms the obtained SnO2 core with tetragonal rutile crystalline structure and the shell ZnO with hexagonal structure. FTIR result shows the functional groups present in the samples. The spherical morphology and the formation of the core-shell structures have been confirmed by HRTEM measurements. The UV-Vis showed that band gap is red shifted for as-prepared and the shells coated core-shell samples. From this investigation it can be concluded that the surface modification with different metal and insulating oxides strongly influences the optical properties of the core-shell materials which enhance their potential applications towards optical devices fabrication.

Eosin-Y sensitized core-shell TiO2-ZnO nano-structured photoanodes for dye-sensitized solar cell applications.

PubMed

Manikandan, V S; Palai, Akshaya K; Mohanty, Smita; Nayak, Sanjay K

2018-06-01

In the current investigation, TiO 2 and TiO 2 -ZnO (core-shell) spherical nanoparticles were synthesized by simple combined hydrolysis and refluxing method. A TiO 2 core nanomaterial on the shell material of ZnO was synthesized by utilizing variable ratios of ZnO. The structural characterization of TiO 2 -ZnO core/shell nanoparticles were done by XRD analysis. The spherical structured morphology of the TiO 2 -ZnO has been confirmed through field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) studies. The UV-visible spectra of TiO 2 -ZnO nanostructures were also compared with the pristine TiO 2 to investigate the shift of wavelength. The TiO 2 -ZnO core/shell nanoparticles at the interface efficiently collect the photogenarated electrons from ZnO and also ZnO act a barrier for reduced charge recombination of electrolyte and dye-nanoparticles interface. This combination improved the light absorption which induced the charge transfer ability and dye loading capacity of core-shell nanoparticles. An enhancement in the short circuit current (J sc ) from 1.67 mA/cm 2 to 2.1 mA/cm 2 has been observed for TiO 2 -ZnObased photoanode (with platinum free counter electrode), promises an improvement in the energy conversion efficiency by 57% in comparison with that of the DSSCs based on the pristine TiO 2 . Henceforth, TiO 2 -ZnO photoelectrode in ZnO will effectively act as barrier at the interface of TiO 2 -ZnO and TiO 2 , ensuring the potential for DSSC application. Copyright © 2018 Elsevier B.V. All rights reserved.

Gridless particle technique for the Vlasov-Poisson system in problems with high degree of symmetry

NASA Astrophysics Data System (ADS)

Boella, E.; Coppa, G.; D'Angola, A.; Peiretti Paradisi, B.

2018-03-01

In the paper, gridless particle techniques are presented in order to solve problems involving electrostatic, collisionless plasmas. The method makes use of computational particles having the shape of spherical shells or of rings, and can be used to study cases in which the plasma has spherical or axial symmetry, respectively. As a computational grid is absent, the technique is particularly suitable when the plasma occupies a rapidly changing space region.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shang Yazhuo; Hu Jun; Liu Honglai, E-mail: yazhuoshang@ecust.edu.c

Novel large-scale hollow ZnO spherical shells were synthesized by ionic liquids assisted hydrothermal oxidization of pure zinc powder without any catalyst at a relatively low temperature of 160 deg. C. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM) patterns show that the shells are composed of ZnO and the structure of the shells is very unique. Textured flower-like ZnO consisting of ZnO rods is grown on the outer surfaces of shells forming a triple assembly. Room-temperature photoluminescence spectra of the oxidized material show a sharp peak at 379 nm and a wider broad peak centeredmore » at 498 nm. The possible growth mechanism of the triple assembly of ZnO is discussed in detail. - Graphical abstract: A proposed growth mechanism of large scale hollow ZnO. Bubbles provide the aggregation center for ionic liquids that leads to the formation of hollow Zn particle-dotted shells, buoyancy promotes shells to go upward, the breach occurs when shells are subjected to overpressure.« less

Amplified Photon Upconversion by Photonic Shell of Cholesteric Liquid Crystals.

PubMed

Kang, Ji-Hwan; Kim, Shin-Hyun; Fernandez-Nieves, Alberto; Reichmanis, Elsa

2017-04-26

As an effective platform to exploit triplet-triplet-annihilation-based photon upconversion (TTA-UC), microcapsules composed of a fluidic UC core and photonic shell are microfluidically prepared using a triple emulsion as the template. The photonic shell consists of cholesteric liquid crystals (CLCs) with a periodic helical structure, exhibiting a photonic band gap. Combined with planar anchoring at the boundaries, the shell serves as a resonance cavity for TTA-UC emission and enables spectral tuning of the UC under low-power-density excitation. The CLC shell can be stabilized by introducing a polymerizable mesogen in the LC host. Because of the microcapsule spherical symmetry, spontaneous emission of the delayed fluorescence is omnidirectionally amplified at the edge of the stop band. These results demonstrate the range of opportunities provided by TTA-UC systems for the future design of low-threshold photonic devices.

Forming Uniform Deuterium-Ice Layers in Cryogenic Targets: Experiences Using the OMEGA Cryogenic Target Handling System

NASA Astrophysics Data System (ADS)

Harding, D. R.; Wittman, M. D.; Elasky, L.; Iwan, L. S.; Lund, L.

2001-10-01

The OMEGA Cryogenic Target Handling System (OCTHS) allows variable-thickness ice layers (nominal 100-μm) to be formed inside OMEGA-size (1-mm-diam., 3-μm-wall) plastic shells. The OCTHS design provides the most straightforward thermal environment for layering targets: permeation filled spherical targets are in a spherical isothermal environment. The layered target can be rotated 360^o to acquire multiple views of the ice layer. However, the capability of providing cryogenic targets for implosion experiments imposes constraints that do not exist in test systems dedicated to ice-layering studies. Most affected is the ability to characterize the target: space constraints and the need for multiple sets of windows limit the viewing access to f/5 optics, which affects the image quality. With these features, the OCTS provides the most relevant test system, to date, for layering targets and quantifying the overall ice roughness. No single layering protocol provides repeatable ice smoothness. All techniques require extensive operator interaction, and the layering process is lengthy. Typical ice rms smoothness varied from 5 to 10 μm for all targets studied. Characterizing the ice layer from different views shows a ~30% variation in the ice rms smoothness and a greater difference in the power spectra, depending on the view axis. This work was supported by the U.S. DOE Office of Inertial Confinement Fusion under Cooperative Agreement No. DE-FC03-92SF19460.

Effect of Particle Morphology on the Reactivity of Explosively Dispersed Titanium Particles

NASA Astrophysics Data System (ADS)

Frost, David L.; Cairns, Malcolm; Goroshin, Samuel; Zhang, Fan

2009-12-01

The effect of particle morphology on the reaction of titanium (Ti) particles explosively dispersed during the detonation of either cylindrical or spherical charges has been investigated experimentally. The explosive charges consisted of packed beds of Ti particles saturated with nitromethane. The reaction behaviour of irregularly-shaped Ti particles in three size ranges is compared with tests with spherical Ti particles. The particle reaction is strongly dependent on particle morphology, e.g., 95 μm spherical Ti particles failed to ignite (in cylinders up to 49 mm in dia), whereas similarly sized irregular Ti particles readily ignited. For irregular particles, the uniformity of ignition on the particle cloud surface was almost independent of particle size, but depended on charge diameter. As the charge diameter was reduced, ignition in the conically expanding particle cloud occurred only at isolated spots or bands. For spherical charges, whereas large irregular Ti particles ignited promptly and uniformly throughout the particle cloud, the smallest particles dispersed nonuniformly and ignition occurred at isolated locations after a delay. Hence the charge geometry, as well as particle morphology, influences the reaction behaviour of the particles.

Diagnostics for PLX-alpha

NASA Astrophysics Data System (ADS)

Gilmore, Mark; Hsu, Scott

2015-11-01

The goal of the Plasma Liner eXperiment PLX-alpha at Los Alamos National Laboratory is to establish the viability of creating a spherically imploding plasma liner for MIF and HED applications, using a spherical array of supersonic plasma jets launched by innovative contoured-gap coaxial plasma guns. PLX- α experiments will focus in particular on establishing the ram pressure and uniformity scalings of partial and fully spherical plasma liners. In order to characterize these parameters experimentally, a suite of diagnostics is planned, including multi-camera fast imaging, a 16-channel visible interferometer (upgraded from 8 channels) with reconfigurable, fiber-coupled front end, and visible and VUV high-resolution and survey spectroscopy. Tomographic reconstruction and data fusion techniques will be used in conjunction with interferometry, imaging, and synthetic diagnostics from modeling to characterize liner uniformity in 3D. Diagnostic and data analysis design, implementation, and status will be presented. Supported by the Advanced Research Projects Agency - Energy - U.S. Department of Energy.

Surfactant mediated hydrothermal synthesis, characterization and luminescent properties of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} core shell nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khajuria, Heena; Ladol, Jigmet; Khajuria, Sonika

Highlights: • Core shell nanorods were synthesised by surfactant assisted hydrothermal method. • Morphology of core shell nanorods resembles those of core nanorods indicating coating of shell on cores. • More uniform and non-aggregated core shell nanorods were prepared in presence of surfactants. • Surfactant assisted prepared core shell nanorods show intense emission as compared to uncoated core nanorods. - Abstract: Core shell GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} nanorods were synthesized via hydrothermal route in the presence of different surfactants [cetyltrimethyl ammonium bromide (CTAB) and Sodium dodecyl sulphate (SDS)]. The nanorods were characterized by powder X-ray diffractionmore » (PXRD), fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and photoluminescence (PL) studies. The X-ray diffraction results indicate good crystallinity and effective doping in core and core shell nanorods. SEM and TEM micrographs show that all of the as prepared gadolinium phosphate products have rod like shape. The compositional analysis of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} core was done by EDS. The emission intensity of the GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} @ GdPO{sub 4} core shell increased significantly with respect to those of GdPO{sub 4}: Ce{sup 3+}/Tb{sup 3+} core nanorods. The effect of surfactant on the uniformity, thickness and luminescence of the core shell nanorods was investigated.« less

Numerical modeling of the 3D dynamics of ultrasound contrast agent microbubbles using the boundary integral method

NASA Astrophysics Data System (ADS)

Wang, Qianxi; Manmi, Kawa; Calvisi, Michael L.

2015-02-01

Ultrasound contrast agents (UCAs) are microbubbles stabilized with a shell typically of lipid, polymer, or protein and are emerging as a unique tool for noninvasive therapies ranging from gene delivery to tumor ablation. While various models have been developed to describe the spherical oscillations of contrast agents, the treatment of nonspherical behavior has received less attention. However, the nonspherical dynamics of contrast agents are thought to play an important role in therapeutic applications, for example, enhancing the uptake of therapeutic agents across cell membranes and tissue interfaces, and causing tissue ablation. In this paper, a model for nonspherical contrast agent dynamics based on the boundary integral method is described. The effects of the encapsulating shell are approximated by adapting Hoff's model for thin-shell, spherical contrast agents. A high-quality mesh of the bubble surface is maintained by implementing a hybrid approach of the Lagrangian method and elastic mesh technique. The numerical model agrees well with a modified Rayleigh-Plesset equation for encapsulated spherical bubbles. Numerical analyses of the dynamics of UCAs in an infinite liquid and near a rigid wall are performed in parameter regimes of clinical relevance. The oscillation amplitude and period decrease significantly due to the coating. A bubble jet forms when the amplitude of ultrasound is sufficiently large, as occurs for bubbles without a coating; however, the threshold amplitude required to incite jetting increases due to the coating. When a UCA is near a rigid boundary subject to acoustic forcing, the jet is directed towards the wall if the acoustic wave propagates perpendicular to the boundary. When the acoustic wave propagates parallel to the rigid boundary, the jet direction has components both along the wave direction and towards the boundary that depend mainly on the dimensionless standoff distance of the bubble from the boundary. In all cases, the jet directions for the coated and uncoated bubble are similar but the jet width and jet velocity are smaller for a coated bubble. The effects of shell thickness and shell viscosity are analyzed and determined to affect the bubble dynamics, including jet development.

Core-shell-corona polymeric micelles as a versatile template for synthesis of inorganic hollow nanospheres.

PubMed

Sasidharan, Manickam; Nakashima, Kenichi

2014-01-21

Hollow, inorganic nanoscale capsules have many applications, from the delivery of encapsulated products for cosmetic and medicinal purposes to use as lightweight composite materials. Early methods for producing inorganic hollow nanospheres using hard templates suffered from low product yield and shell weakness upon template removal. In the past decade, researchers have turned to amphiphilic copolymers to synthesize hollow nanostructures and ordered mesoporous materials. Amphiphilic molecules self-assemble into well-defined nanostructures including spherical micelles. Micelles formed from simple, two-component AB diblock and ABA triblock copolymers, however, have been difficult to work with to construct inorganic hollow nanoparticles, because the corona of the micelle, which serves as the template for the shell, becomes unstable as it absorbs inorganic shell precursors, causing aggregates to form. Newly developed, three-component ABC triblock copolymers may solve this problem. They provide nanoassemblies with more diverse morphological and functional features than AB diblock and ABA triblock copolymers. Micelles formed from ABC triblock copolymers in selective solvents that dissolve only one or two of the blocks provide templates for these improved nanoassemblies. By manipulating individual polymer blocks, one can "encode" additional features at the molecular level. For instance, modifying the functional groups or substitution patterns of the blocks allows better morphological and size control. Insights into polymer self-assembly gained over years of work in our group have set the stage to systematically engineer inorganic spherical hollow nanoparticles using ABC triblock copolymers. In this Account, we report our recent progress in producing diverse, inorganic hollow spherical nanospheres from asymmetric triblock copolymeric micelles with core-shell-corona architecture as templates. We discuss three classes of polymeric micelles-with neutral, cationic, and anionic shell structures-that allow fabrication of a variety of hollow nanoparticles. Importantly, we synthesized all of these particles in water, avoiding use of hazardous organic solvents. We have designed the precursor of the inorganic material to be selectively sorbed into the shell domain, leaving the corona free from the inorganic precursors that would destabilize the micelle. The core, meanwhile, is the template for the formation of the hollow void. By rationally tailoring experimental parameters, we readily and selectively obtained a variety of hollow nanoparticles including silica, hybrid silicas, metal-oxides, metal-carbonates, metal-sulfates, metal-borates, and metal-phosphates. Finally, we highlight the state-of-the-art techniques we used to characterize these nanoparticles, and describe experiments that demonstrate the potential of these hollow particles in drug delivery, and as anode and cathode materials for lithium-ion batteries.

The NIF x-ray spectrometer calibration campaign at Omega.

PubMed

Pérez, F; Kemp, G E; Regan, S P; Barrios, M A; Pino, J; Scott, H; Ayers, S; Chen, H; Emig, J; Colvin, J D; Bedzyk, M; Shoup, M J; Agliata, A; Yaakobi, B; Marshall, F J; Hamilton, R A; Jaquez, J; Farrell, M; Nikroo, A; Fournier, K B

2014-11-01

The calibration campaign of the National Ignition Facility X-ray Spectrometer (NXS) was carried out at the Omega laser facility. Spherically symmetric, laser-driven, millimeter-scale x-ray sources of K-shell and L-shell emission from various mid-Z elements were designed for the 2-18 keV energy range of the NXS. The absolute spectral brightness was measured by two calibrated spectrometers. We compare the measured performance of the target design to radiation hydrodynamics simulations.

Application of Powder Diffraction Methods to the Analysis of the Atomic Structure of Nanocrystals: The Concept of the Apparent Lattice Parameter (ALP)

NASA Technical Reports Server (NTRS)

Palosz, B.; Grzanka, E.; Gierlotka, S.; Stelmakh, S.; Pielaszek, R.; Bismayer, U.; Weber, H.-P.; Palosz, W.; Curreri, Peter A. (Technical Monitor)

2002-01-01

The applicability of standard methods of elaboration of powder diffraction data for determination of the structure of nano-size crystallites is analysed. Based on our theoretical calculations of powder diffraction data we show, that the assumption of the infinite crystal lattice for nanocrystals smaller than 20 nm in size is not justified. Application of conventional tools developed for elaboration of powder diffraction data, like the Rietveld method, may lead to erroneous interpretation of the experimental results. An alternate evaluation of diffraction data of nanoparticles, based on the so-called 'apparent lattice parameter' (alp) is introduced. We assume a model of nanocrystal having a grain core with well-defined crystal structure, surrounded by a surface shell with the atomic structure similar to that of the core but being under a strain (compressive or tensile). The two structural components, the core and the shell, form essentially a composite crystal with interfering, inseparable diffraction properties. Because the structure of such a nanocrystal is not uniform, it defies the basic definitions of an unambiguous crystallographic phase. Consequently, a set of lattice parameters used for characterization of simple crystal phases is insufficient for a proper description of the complex structure of nanocrystals. We developed a method of evaluation of powder diffraction data of nanocrystals, which refers to a core-shell model and is based on the 'apparent lattice parameter' methodology. For a given diffraction pattem, the alp values are calculated for every individual Bragg reflection. For nanocrystals the alp values depend on the diffraction vector Q. By modeling different a0tomic structures of nanocrystals and calculating theoretically corresponding diffraction patterns using the Debye functions we showed, that alp-Q plots show characteristic shapes which can be used for evaluation of the atomic structure of the core-shell system. We show, that using a simple model of a nanocrystal with spherical shape and centro-symmetric strain at the surface shell we obtain theoretical alp-Q values which match very well the alp-Q plots determined experimentally for Sic, GaN, and diamond nanopowders. The theoretical models are defined by the lattice parameter of the grain core, thickness of the surface shell, and the magnitude and distribution of the strain field in the surface shell. According to our calculations, the part of the diffraction pattern measured at relatively low diffraction vectors Q (below 10/angstrom) provides information on the surface strain, whle determination of the lattice parameters in the grain core requires measurements at large Q-values (above 15 - 20/angstrom).

Wideband and multi-frequency infrared cloaking of spherical objects by using the graphene-based metasurface.

PubMed

Shokati, Elnaz; Granpayeh, Nosrat; Danaeifar, Mohammad

2017-04-10

The ultrathin graphene metasurface is proposed as a mantle cloak to achieve wideband tunable scattering reduction around the spherical (three-dimensional) objects. The cloaking shell over the metallic or dielectric sphere is structured by a periodic array of graphene nanodisks that operate at infrared frequencies. By using the polarizability of the graphene nanodisks and equivalent conductivity method, the metasurface reactance is obtained. To achieve the cloaking shell for both dielectric and conducting spheres, the metasurface reactance as a function of nanodisks dimensions, graphene's Fermi energy, and permittivity of the surrounding areas can be tuned from the inductive to capacitive situation. Inhomogeneous metasurfaces including graphene nanodisks with different radii provide wideband invisibility due to extra resonances. We could significantly increase the 3-dB bandwidth more than the homogenous case by simpler realistic designs compared to the multi-layer structures. The analytical results are confirmed with full-wave numerical simulations.

Quantification of Processing Effects on Filament Wound Pressure Vessels

NASA Technical Reports Server (NTRS)

Aiello, Robert A.; Chamis, Christos C.

1999-01-01

A computational simulation procedure is described which is designed specifically for the modeling and analysis of filament wound pressure vessels. Cylindrical vessels with spherical or elliptical end caps can be generated automatically. End caps other than spherical or elliptical may be modeled by varying circular sections along the x-axis according to the C C! end cap shape. The finite element model generated is composed of plate type quadrilateral shell elements on the entire vessel surface. This computational procedure can also be sued to generate grid, connectivity and material cards (bulk data) for component parts of a larger model. These bulk data are assigned to a user designated file for finite element structural/stress analysis of composite pressure vessels. The procedure accommodates filament would pressure vessels of all types of shells-of-revolution. It has provisions to readily evaluate initial stresses due to pretension in the winding filaments and residual stresses due to cure temperature.

Quantification of Processing Effects on Filament Wound Pressure Vessels. Revision

NASA Technical Reports Server (NTRS)

Aiello, Robert A.; Chamis, Christos C.

2002-01-01

A computational simulation procedure is described which is designed specifically for the modeling and analysis of filament wound pressure vessels. Cylindrical vessels with spherical or elliptical end caps can be generated automatically. End caps other than spherical or elliptical may be modeled by varying circular sections along the x-axis according to the end cap shape. The finite element model generated is composed of plate type quadrilateral shell elements on the entire vessel surface. This computational procedure can also be used to generate grid, connectivity and material cards (bulk data) for component parts of a larger model. These bulk data are assigned to a user designated file for finite element structural/stress analysis of composite pressure vessels. The procedure accommodates filament wound pressure vessels of all types of shells-of -revolution. It has provisions to readily evaluate initial stresses due to pretension in the winding filaments and residual stresses due to cure temperature.

Mirror mount

DOEpatents

Humpal, Harold H.

1987-01-01

A mirror mount (10) is provided that allows free pitch, yaw and roll motion of the mirror (28) while keeping the location of a point (56) on the surface of the mirror (28) fixed in the rest frame of reference of the mount (10). Yaw movement is provided by two yaw cylinders (30,32) that are bearing (52) mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell (42) that is air bearing (72,74) mounted to move between a clamp (60) and an upper pedestal bearing (44). The centers of curvature of the spherical surfaces of the shell (42) lie upon the point (56). Pitch motion and roll motion are separately and independently imparted to mirror (28) by a pair of pitch paddles (34) and a pair of roll paddles (36) that are independently and separately moved by control rods (76,80) driven by motors (78,82).

Primary and secondary particle contributions to the depth dose distribution in a phantom shielded from solar flare and Van Allen protons

NASA Technical Reports Server (NTRS)

Santoro, R. T.; Claiborne, H. C.; Alsmiller, R. G., Jr.

1972-01-01

Calculations have been made using the nucleon-meson transport code NMTC to estimate the absorbed dose and dose equivalent distributions in astronauts inside space vehicles bombarded by solar flare and Van Allen protons. A spherical shell shield of specific radius and thickness with a 30-cm-diam. tissue ball at the geometric center was used to simulate the spacecraft-astronaut configuration. The absorbed dose and the dose equivalent from primary protons, secondary protons, heavy nuclei, charged pions, muons, photons, and positrons and electrons are given as a function of depth in the tissue phantom. Results are given for solar flare protons with a characteristic rigidity of 100 MV and for Van Allen protons in a 240-nautical-mile circular orbit at 30 degree inclination angle incident on both 20-g/sq cm-thick aluminum and polyethylene spherical shell shields.

Fabrication, Characterization and Cytotoxicity of Spherical-Shaped Conjugated Gold-Cockle Shell Derived Calcium Carbonate Nanoparticles for Biomedical Applications

NASA Astrophysics Data System (ADS)

Kiranda, Hanan Karimah; Mahmud, Rozi; Abubakar, Danmaigoro; Zakaria, Zuki Abubakar

2018-01-01

The evolution of nanomaterial in science has brought about a growing increase in nanotechnology, biomedicine, and engineering fields. This study was aimed at fabrication and characterization of conjugated gold-cockle shell-derived calcium carbonate nanoparticles (Au-CSCaCO3NPs) for biomedical application. The synthetic technique employed used gold nanoparticle citrate reduction method and a simple precipitation method coupled with mechanical use of a Programmable roller-ball mill. The synthesized conjugated nanomaterial was characterized for its physicochemical properties using transmission electron microscope (TEM), field emission scanning electron microscope (FESEM) equipped with energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FTIR). However, the intricacy of cellular mechanisms can prove challenging for nanomaterial like Au-CSCaCO3NPs and thus, the need for cytotoxicity assessment. The obtained spherical-shaped nanoparticles (light-green purplish) have an average diameter size of 35 ± 16 nm, high carbon and oxygen composition. The conjugated nanomaterial, also possesses a unique spectra for aragonite polymorph and carboxylic bond significantly supporting interactions between conjugated nanoparticles. The negative surface charge and spectra absorbance highlighted their stability. The resultant spherical shaped conjugated Au-CSCaCO3NPs could be a great nanomaterial for biomedical applications.

Dynamos in asymptotic-giant-branch stars as the origin of magnetic fields shaping planetary nebulae.

PubMed

Blackman, E G; Frank, A; Markiel, J A; Thomas, J H; Van Horn, H M

2001-01-25

Planetary nebulae are thought to be formed when a slow wind from the progenitor giant star is overtaken by a subsequent fast wind generated as the star enters its white dwarf stage. A shock forms near the boundary between the winds, creating the relatively dense shell characteristic of a planetary nebula. A spherically symmetric wind will produce a spherically symmetric shell, yet over half of known planetary nebulae are not spherical; rather, they are elliptical or bipolar in shape. A magnetic field could launch and collimate a bipolar outflow, but the origin of such a field has hitherto been unclear, and some previous work has even suggested that a field could not be generated. Here we show that an asymptotic-giant-branch (AGB) star can indeed generate a strong magnetic field, having as its origin a dynamo at the interface between the rapidly rotating core and the more slowly rotating envelope of the star. The fields are strong enough to shape the bipolar outflows that produce the observed bipolar planetary nebulae. Magnetic braking of the stellar core during this process may also explain the puzzlingly slow rotation of most white dwarf stars.

Compact Q-balls and Q-shells in a scalar electrodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arodz, H.; Lis, J.

2009-02-15

We investigate spherically symmetric nontopological solitons in electrodynamics with a scalar field self-interaction U{approx}|{psi}| taken from the complex signum-Gordon model. We find Q-balls for small absolute values of the total electric charge Q, and Q-shells when |Q| is large enough. In both cases the charge density exactly vanishes outside certain compact regions in the three-dimensional space. The dependence of the total energy E of small Q-balls on the total electric charge has the form E{approx}|Q|{sup 5/6}, while in the case of very large Q-shells, E{approx}|Q|{sup 7/6}.

Greenhouse effect: temperature of a metal sphere surrounded by a glass shell and heated by sunlight

NASA Astrophysics Data System (ADS)

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the z-axis. This development is a generalization of the simple treatment of the greenhouse effect given by Kittel and Kroemer (1980 Thermal Physics (San Francisco: Freeman)) and can serve as a very simple model demonstrating the much more complex Earth greenhouse effect. Solution of the model problem provides an excellent pedagogical tool at the Junior/Senior undergraduate level.

Polystyrene Core-Silica Shell Particles with Defined Nanoarchitectures as a Versatile Platform for Suspension Array Technology.

PubMed

Sarma, Dominik; Gawlitza, Kornelia; Rurack, Knut

2016-04-19

The need for rapid and high-throughput screening in analytical laboratories has led to significant growth in interest in suspension array technologies (SATs), especially with regard to cytometric assays targeting a low to medium number of analytes. Such SAT or bead-based assays rely on spherical objects that constitute the analytical platform. Usually, functionalized polymer or silica (SiO2) microbeads are used which each have distinct advantages and drawbacks. In this paper, we present a straightforward synthetic route to highly monodisperse SiO2-coated polystyrene core-shell (CS) beads for SAT with controllable architectures from smooth to raspberry- and multilayer-like shells by varying the molecular weight of poly(vinylpyrrolidone) (PVP), which was used as the stabilizer of the cores. The combination of both organic polymer core and a structurally controlled inorganic SiO2 shell in one hybrid particle holds great promises for flexible next-generation design of the spherical platform. The particles were characterized by electron microscopy (SEM, T-SEM, and TEM), thermogravimetry, flow cytometry, and nitrogen adsorption/desorption, offering comprehensive information on the composition, size, structure, and surface area. All particles show ideal cytometric detection patterns and facile handling due to the hybrid structure. The beads are endowed with straightforward modification possibilities through the defined SiO2 shells. We successfully implemented the particles in fluorometric SAT model assays, illustrating the benefits of tailored surface area which is readily available for small-molecule anchoring. Very promising assay performance was shown for DNA hybridization assays with quantification limits down to 8 fmol.

STEAM STIRRED HOMOGENEOUS NUCLEAR REACTOR

DOEpatents

Busey, H.M.

1958-06-01

A homogeneous nuclear reactor utilizing a selfcirculating liquid fuel is described. The reactor vessel is in the form of a vertically disposed tubular member having the lower end closed by the tube walls and the upper end closed by a removal fianged assembly. A spherical reaction shell is located in the lower end of the vessel and spaced from the inside walls. The reaction shell is perforated on its lower surface and is provided with a bundle of small-diameter tubes extending vertically upward from its top central portion. The reactor vessel is surrounded in the region of the reaction shell by a neutron reflector. The liquid fuel, which may be a solution of enriched uranyl sulfate in ordinary or heavy water, is mainiained at a level within the reactor vessel of approximately the top of the tubes. The heat of the reaction which is created in the critical region within the spherical reaction shell forms steam bubbles which more upwardly through the tubes. The upward movement of these bubbles results in the forcing of the liquid fuel out of the top of these tubes, from where the fuel passes downwardly in the space between the tubes and the vessel wall where it is cooled by heat exchangers. The fuel then re-enters the critical region in the reaction shell through the perforations in the bottom. The upper portion of the reactor vessel is provided with baffles to prevent the liquid fuel from splashing into this region which is also provided with a recombiner apparatus for recombining the radiolytically dissociated moderator vapor and a control means.

Structural Assessment of Advanced Composite Tow-Steered Shells

NASA Technical Reports Server (NTRS)

Wu, K. Chauncey; Stanford, Bret K.; Hrinda, Glenn A.; Wang, Zhuosong; Martin, Robert a.; Kim, H. Alicia

2013-01-01

The structural performance of two advanced composite tow-steered shells, manufactured using a fiber placement system, is assessed using both experimental and analytical methods. The fiber orientation angles vary continuously around the shell circumference from 10 degrees on the shell crown and keel, to 45 degrees on the shell sides. The two shells differ in that one shell has the full 24-tow course applied during each pass of the fiber placement system, while the second shell uses the fiber placement system s tow drop/add capability to achieve a more uniform shell wall thickness. The shells are tested in axial compression, and estimates of their prebuckling axial stiffnesses and bifurcation buckling loads are predicted using linear finite element analyses. These preliminary predictions compare well with the test results, with an average agreement of approximately 10 percent.

Proton-neutron sdg boson model and spherical-deformed phase transition

NASA Astrophysics Data System (ADS)

Otsuka, Takaharu; Sugita, Michiaki

1988-12-01

The spherical-deformed phase transition in nuclei is described in terms of the proton-neutron sdg interacting boson model. The sdg hamiltonian is introduced to model the pairing+quadrupole interaction. The phase transition is reproduced in this framework as a function of the boson number in the Sm isotopes, while all parameters in the hamiltonian are kept constant at values reasonable from the shell-model point of view. The sd IBM is derived from this model through the renormalization of g-boson effects.

Two-component dark-bright solitons in three-dimensional atomic Bose-Einstein condensates.

PubMed

Wang, Wenlong; Kevrekidis, P G

2017-03-01

In the present work, we revisit two-component Bose-Einstein condensates in their fully three-dimensional (3D) form. Motivated by earlier studies of dark-bright solitons in the 1D case, we explore the stability of these structures in their fully 3D form in two variants. In one the dark soliton is planar and trapping a planar bright (disk) soliton. In the other case, a dark spherical shell soliton creates an effective potential in which a bright spherical shell of atoms is trapped in the second component. We identify these solutions as numerically exact states (up to a prescribed accuracy) and perform a Bogolyubov-de Gennes linearization analysis that illustrates that both structures can be dynamically stable in suitable intervals of sufficiently low chemical potentials. We corroborate this finding theoretically by analyzing the stability via degenerate perturbation theory near the linear limit of the system. When the solitary waves are found to be unstable, we explore their dynamical evolution via direct numerical simulations which, in turn, reveal wave forms that are more robust. Finally, using the SO(2) symmetry of the model, we produce multi-dark-bright planar or shell solitons involved in pairwise oscillatory motion.

Rotational Splittings of Acoustic Modes in an Experimental Model of a Planetary Core

NASA Astrophysics Data System (ADS)

Adams, M. M.; Stone, D.; Lathrop, D. P.

2014-12-01

Planetary zonal flows can be probed in principle using the tools of helioseismology. We explore this technique using laboratory experiments where the measurement of zonal flows is also of geophysical relevance. The experiments are carried out in a device with a geometry similar to that of Earth's core. It consists of a 60 cm diameter outer spherical shell concentric with a 20 cm diameter inner sphere. Air between the inner sphere and outer shell is used as the working fluid. A turbulent shear flow is driven in the air by independently rotating the inner sphere and outer shell. Acoustic modes are excited in the vessel with a speaker, and microphones are used to measure the rotational splittings of these modes. The radial profile of azimuthal velocities is inferred from these splittings, in an approach analogous to that used in helioseismology to determine solar velocity profiles. By varying the inner and outer rotation rates, different turbulent states can be investigated. Comparison is made to previous experimental investigations of turbulent spherical Couette flow. These experiments also serve as a test of this diagnostic, which may be used in the future in liquid sodium experiments, providing information on zonal flows in hydromagnetic experiments.

Shape-Controlled Synthesis of Magnetic Iron Oxide@SiO₂-Au@C Particles with Core-Shell Nanostructures.

PubMed

Li, Mo; Li, Xiangcun; Qi, Xinhong; Luo, Fan; He, Gaohong

2015-05-12

The preparation of nonspherical magnetic core-shell nanostructures with uniform sizes still remains a challenge. In this study, magnetic iron oxide@SiO2-Au@C particles with different shapes, such as pseduocube, ellipsoid, and peanut, were synthesized using hematite as templates and precursors of magnetic iron oxide. The as-obtained magnetic particles demonstrated uniform sizes, shapes, and well-designed core-shell nanostructures. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) analysis showed that the Au nanoparticles (AuNPs) of ∼6 nm were uniformly distributed between the silica and carbon layers. The embedding of the metal nanocrystals into the two different layers prevented the aggregation and reduced the loss of the metal nanocrystals during recycling. Catalytic performance of the peanut-like particles kept almost unchanged without a noticeable decrease in the reduction of 4-nitrophenol (4-NP) in 8 min even after 7 cycles, indicating excellent reusability of the particles. Moreover, the catalyst could be readily recycled magnetically after each reduction by an external magnetic field.

Comparisons of Buckling Capacity Curves of Pressurized Spheres with EDR Provisions and Experimental Results

NASA Astrophysics Data System (ADS)

Błażejewski, Paweł; Marcinowski, Jakub

2017-06-01

Existing provisions leading to the assessment of the buckling resistance of pressurised spherical shells were published in the European Design Recommendations (EDR) [1]. This book comprises rules which refer to the stability of steel shells of different shapes. In the first step of the general procedure they require calculation of two reference quantities: the elastic critical buckling reference pRcr and the plastic reference resistance pRpl. These quantities should be determined in the linear buckling analysis (LBA) and in the materially nonlinear analysis (MNA) respectively. Only in the case of spherical shells the existing procedure has exceptional character. It is based on the geometrically nonlinear analysis (GNA) and on the geometrically and materially nonlinear analysis (GMNA), respectively. From this reason, in this particular case there was a need to change the existing approach. The new procedure was presented in the work of Błażejewski & Marcinowski in 2016 (comp. [2]). All steps of the procedure leading to the assessment of buckling resistance of pressurized steel, spherical shells were presented in this work. The elaborated procedure is consistent with provisions of Eurocode EN1993-1-6 (comp. [3]) and with recommendations inserted in Europeans Design Recommendations [1]. The proposed capacity curves were compared with existing proposal published in [1] for three different fabrication quality classes predicted in [3]. In this work also comparisons of author's proposals with experimental results obtained by other authors were presented.

Atomic level characterization of cadmium selenide nanocrystal systems using atomic number contrast scanning transmission electron microscopy and Rutherford backscattering spectroscopy

NASA Astrophysics Data System (ADS)

McBride, James R.

This project involved the characterization of CdSe nanocrystals. Through the use of Atomic Number Contrast Scanning Transmission Electron Microscopy (Z-STEM) and Rutherford Backscattering Spectroscopy (RBS), atomic level structure and chemical information was obtained. Specifically, CdSe nanocrystals produced using a mixture of hexadecylamine (HDA) and trioctylphosphine oxide (TOPO) were determined to be spherical compared to nanocrystals produced in TOPO only, which had elongated (101) facets. Additionally, the first Z-STEM images of CdSe/ZnS core/shell nanocrystals were obtained. From these images, the growth mechanism of the ZnS shell was determined and the existence of non-fluorescent ZnS particles was confirmed. Through collaboration with Quantum Dot Corp., core/shell nanocrystals with near unity quantum yield were developed. These core/shell nanocrystals included a US intermediate layer to improve shell coverage.

Resistive switching of Sn-doped In2O3/HfO2 core-shell nanowire: geometry architecture engineering for nonvolatile memory.

PubMed

Huang, Chi-Hsin; Chang, Wen-Chih; Huang, Jian-Shiou; Lin, Shih-Ming; Chueh, Yu-Lun

2017-05-25

Core-shell NWs offer an innovative approach to achieve nanoscale metal-insulator-metal (MIM) heterostructures along the wire radial direction, realizing three-dimensional geometry architecture rather than planar type thin film devices. This work demonstrated the tunable resistive switching characteristics of ITO/HfO 2 core-shell nanowires with controllable shell thicknesses by the atomic layer deposition (ALD) process for the first time. Compared to planar HfO 2 thin film device configuration, ITO/HfO 2 core-shell nanowire shows a prominent resistive memory behavior, including lower power consumption with a smaller SET voltage of ∼0.6 V and better switching voltage uniformity with variations (standard deviation(σ)/mean value (μ)) of V SET and V RESET from 0.38 to 0.14 and from 0.33 to 0.05 for ITO/HfO 2 core-shell nanowire and planar HfO 2 thin film, respectively. In addition, endurance over 10 3 cycles resulting from the local electric field enhancement can be achieved, which is attributed to geometry architecture engineering. The concept of geometry architecture engineering provides a promising strategy to modify the electric-field distribution for solving the non-uniformity issue of future RRAM.

Linear and nonlinear magneto-optical properties of an off-center single dopant in a spherical core/shell quantum dot

NASA Astrophysics Data System (ADS)

Feddi, E.; Talbi, A.; Mora-Ramos, M. E.; El Haouari, M.; Dujardin, F.; Duque, C. A.

2017-11-01

Using the effective mass approximation and a variational procedure, we have investigated the nonlinear optical absorption coefficient and the relative refractive index changes associated to a single dopant confined in core/shell quantum dots considering the influences of the core/shell dimensions, externally applied magnetic field, and dielectric mismatch. The results show that the optical absorption coefficient and the coefficients of relative refractive index change depend strongly on the core/shell sizes and they are blue shifted when the spatial confinement increases so this effect is magnified by higher structural dimensions. Additionally, it is obtained that both studied optical properties are sensitive to the dielectric environment in such a way that their amplitudes are very affected by the local field corrections.

CVD graphene sheets electrochemically decorated with "core-shell" Co/CoO nanoparticles

NASA Astrophysics Data System (ADS)

Bayev, V. G.; Fedotova, J. A.; Kasiuk, J. V.; Vorobyova, S. A.; Sohor, A. A.; Komissarov, I. V.; Kovalchuk, N. G.; Prischepa, S. L.; Kargin, N. I.; Andrulevičius, M.; Przewoznik, J.; Kapusta, Cz.; Ivashkevich, O. A.; Tyutyunnikov, S. I.; Kolobylina, N. N.; Guryeva, P. V.

2018-05-01

The paper reports on the first successful fabrication of Co-graphene composites by electrochemical deposition of Co nanoparticles (NPs) on the sheets of twisted graphene. Characterization of the surface morphology and element mapping of twisted graphene decorated with Co NPs by transmission and scanning electron microscopy in combination with the energy-dispersive X-ray spectroscopy reveals the formation of isolated quasi-spherical oxidized Co NPs with the mean diameter 〈 d〉 ≈ 220 nm and core-shell structure. X-ray photoelectron spectroscopy indicates that the core of deposited NPs consists of metal Co while the shell is CoO. Composite Co-graphene samples containing core-shell NPs reveal an exchange bias field up to 160 Oe at 4 K as detected by vibrating sample magnetometry after the field cooling procedure.

Theoretical and experimental design studies for the Atmospheric General Circulation Experiment

NASA Technical Reports Server (NTRS)

Fowlis, W. W.; Hathaway, D. H.; Miller, T. L.; Roberts, G. O.; Kopecky, K. J.

1985-01-01

The major criterion for the Atmospheric General Circulation Experiment (AGCE) design is that it be possible to realize strong baroclinic instability in the spherical configuration chosen. A configuration was selected in which a hemispherical shell of fluid is subjected to latitudinal temperature gradients on its spherical boundaries and the latitudinal boundaries are insulators. Work in the laboratory with a cylindrical version of this configuration revealed more instabilities than baroclinic instability. Since researchers fully expect these additional instabilities to appear in the spherical configuration also, they decided to continue the laboratory cylindrical annulus studies. Four flow regimes were identified: an axisymmetric Hadley circulation, boundary layer convection, baroclinic waves and deep thermal convection. Regime diagrams were prepared.

Impact of a nonuniform charge distribution on virus assembly

NASA Astrophysics Data System (ADS)

Li, Siyu; Erdemci-Tandogan, Gonca; Wagner, Jef; van der Schoot, Paul; Zandi, Roya

2017-08-01

Many spherical viruses encapsulate their genomes in protein shells with icosahedral symmetry. This process is spontaneous and driven by electrostatic interactions between positive domains on the virus coat proteins and the negative genomes. We model the effect of the nonuniform icosahedral charge distribution from the protein shell instead using a mean-field theory. We find that this nonuniform charge distribution strongly affects the optimal genome length and that it can explain the experimentally observed phenomenon of overcharging of virus and viruslike particles.

The Union’s Naval War in Louisiana, 1861-1863

DTIC Science & Technology

2006-11-06

Navy,” 2 December 1861, in Appendix to the Congressional Globe , 37th Cong., 2d Sess., 1861, 18. In his report, Welles referred to the blockade as...were pouring into the Forts a perfect storm of shot, shell, grape , Cannister, and spherical can. The roar of the artillery was deafening; the rushing...sound of the descending bombs, the sharp, whizzing noise made by the jagged fragments of exploded shells, the whirring of grape shot and hissing of

Strain-Driven Stacking Faults in CdSe/CdS Core/Shell Nanorods.

PubMed

Demortière, Arnaud; Leonard, Donovan N; Petkov, Valeri; Chapman, Karena; Chattopadhyay, Soma; She, Chunxing; Cullen, David A; Shibata, Tomohiro; Pelton, Matthew; Shevchenko, Elena V

2018-04-19

Colloidal semiconductor nanocrystals are commonly grown with a shell of a second semiconductor material to obtain desired physical properties, such as increased photoluminescence quantum yield. However, the growth of a lattice-mismatched shell results in strain within the nanocrystal, and this strain has the potential to produce crystalline defects. Here, we study CdSe/CdS core/shell nanorods as a model system to investigate the influence of core size and shape on the formation of stacking faults in the nanocrystal. Using a combination of high-angle annular dark-field scanning transmission electron microscopy and pair-distribution-function analysis of synchrotron X-ray scattering, we show that growth of the CdS shell on smaller, spherical CdSe cores results in relatively small strain and few stacking faults. By contrast, growth of the shell on larger, prolate spheroidal cores leads to significant strain in the CdS lattice, resulting in a high density of stacking faults.

The Oscillations of Coronal Loops Including the Shell

NASA Astrophysics Data System (ADS)

Mikhalyaev, B. B.; Solov'ev, A. A.

2005-04-01

We investigate the MHD waves in a double magnetic flux tube embedded in a uniform external magnetic field. The tube consists of a dense hot cylindrical cord surrounded by a co-axial shell. The plasma and the magnetic field are taken to be uniform inside the cord and also inside the shell. Two slow and two fast magnetosonic modes can exist in the thin double tube. The first slow mode is trapped by the cord, the other is trapped by the shell. The oscillations of the second mode have opposite phases inside the cord and shell. The speeds of the slow modes propagating along the tube are close to the tube speeds inside the cord and the shell. The behavior of the fast modes depends on the magnitude of Alfvén speed inside the shell. If it is less than the Alfvén speed inside the cord and in the environment, then the fast mode is trapped by the shell and the other may be trapped under the certain conditions. In the opposite case when the Alfvén speed in the shell is greater than those inside the cord and in the environment, then the fast mode is radiated by the tube and the other may also be radiated under certain conditions. The oscillation of the cord and the shell with opposite phases is the distinctive feature of the process. The proposed model allows to explain the basic phenomena connected to the coronal oscillations: i) the damping of oscillations stipulated in the double tube model by the radiative loss, ii) the presence of two different modes of perturbations propagating along the loop with close speeds, iii) the opposite phases of oscillations of modulated radio emission, coming from the near coronal sources having sharply different densities.

Transverse shear effects on the stress-intensity factor for a circumferentially cracked, specially orthotropic cylindrical shell

NASA Technical Reports Server (NTRS)

Delale, F.; Erdogan, F.

1977-01-01

The problem of a cylindrical shell containing a circumferential through crack is considered by taking into account the effect of transverse shear deformations. The formulation is given for a specially orthotropic material within the confines of a linearized shallow shell theory. The particular theory used permits the consideration of all five boundary conditions regarding moment and stress resultants on the crack surface. Consequently, aside from multiplicative constants representing the stress intensity factors, the membrane and bending components of the asymptotic stress fields near the crack tip are found to be identical. The stress intensity factors are calculated separately for a cylinder under a uniform membrane load, and that under a uniform bending moment. Sample results showing the nature of the out-of-plane crack surface displacement and the effect of the Poisson's ratio are presented.

Comparison of Large eddy dynamo simulation using dynamic sub-grid scale (SGS) model with a fully resolved direct simulation in a rotating spherical shell

NASA Astrophysics Data System (ADS)

Matsui, H.; Buffett, B. A.

2017-12-01

The flow in the Earth's outer core is expected to have vast length scale from the geometry of the outer core to the thickness of the boundary layer. Because of the limitation of the spatial resolution in the numerical simulations, sub-grid scale (SGS) modeling is required to model the effects of the unresolved field on the large-scale fields. We model the effects of sub-grid scale flow and magnetic field using a dynamic scale similarity model. Four terms are introduced for the momentum flux, heat flux, Lorentz force and magnetic induction. The model was previously used in the convection-driven dynamo in a rotating plane layer and spherical shell using the Finite Element Methods. In the present study, we perform large eddy simulations (LES) using the dynamic scale similarity model. The scale similarity model is implement in Calypso, which is a numerical dynamo model using spherical harmonics expansion. To obtain the SGS terms, the spatial filtering in the horizontal directions is done by taking the convolution of a Gaussian filter expressed in terms of a spherical harmonic expansion, following Jekeli (1981). A Gaussian field is also applied in the radial direction. To verify the present model, we perform a fully resolved direct numerical simulation (DNS) with the truncation of the spherical harmonics L = 255 as a reference. And, we perform unresolved DNS and LES with SGS model on coarser resolution (L= 127, 84, and 63) using the same control parameter as the resolved DNS. We will discuss the verification results by comparison among these simulations and role of small scale fields to large scale fields through the role of the SGS terms in LES.

Application of the line-spring model to a cylindrical shell containing a circumferential or axial part-through crack

NASA Technical Reports Server (NTRS)

Delale, F.; Erdogan, F.

1981-01-01

An approximate solution was obtained for a cylindrical shell containing a part-through surface crack. It was assumed that the shell contains a circumferential or axial semi-elliptic internal or external surface crack and was subjected to a uniform membrane loading or a uniform bending moment away from the crack region. A Reissner type theory was used to account for the effects of the transverse shear deformations. The stress intensity factor at the deepest penetration point of the crack was tabulated for bending and membrane loading by varying three dimensionless length parameters of the problem formed from the shell radius, the shell thickness, the crack length, and the crack depth. The upper bounds of the stress intensity factors are provided by the results of the elasticity solution obtained from the axisymmetric crack problem for the circumferential crack, and that found from the plane strain problem for a circular ring having a radial crack for the axial crack. The line-spring model gives the expected results in comparison with the elasticity solutions. Results also compare well with the existing finite element solution of the pressurized cylinder containing an internal semi-elliptic surface crack.

Additively manufactured MEMS multiplexed coaxial electrospray sources for high-throughput, uniform generation of core-shell microparticles.

PubMed

Olvera-Trejo, D; Velásquez-García, L F

2016-10-18

This study reports the first MEMS multiplexed coaxial electrospray sources in the literature. Coaxial electrospraying is a microencapsulation technology based on electrohydrodynamic jetting of two immiscible liquids, which allows precise control with low size variation of the geometry of the core-shell particles it generates, which is of great importance in numerous biomedical and engineering applications, e.g., drug delivery and self-healing composites. By implementing monolithic planar arrays of miniaturized coaxial electrospray emitters that work uniformly in parallel, the throughput of the compound microdroplet source is greatly increased, making the microencapsulation technology compatible with low-cost commercial applications. Miniaturized core-shell particle generators with up to 25 coaxial electrospray emitters (25 emitters cm -2 ) were fabricated via stereolithography, which is an additive manufacturing process that can create complex microfluidic devices at a small fraction of the cost per device and fabrication time associated with silicon-based counterparts. The characterization of devices with the same emitter structure but different array sizes demonstrates uniform array operation. Moreover, the data demonstrate that the per-emitter current is approximately proportional to the square root of the flow rate of the driving liquid, and it is independent of the flow rate of the driven liquid, as predicted by the theory. The core/shell diameters and the size distribution of the generated compound microparticles can be modulated by controlling the flow rates fed to the emitters.

A generic double-curvature piezoelectric shell energy harvester: Linear/nonlinear theory and applications

NASA Astrophysics Data System (ADS)

Zhang, X. F.; Hu, S. D.; Tzou, H. S.

2014-12-01

Converting vibration energy to useful electric energy has attracted much attention in recent years. Based on the electromechanical coupling of piezoelectricity, distributed piezoelectric zero-curvature type (e.g., beams and plates) energy harvesters have been proposed and evaluated. The objective of this study is to develop a generic linear and nonlinear piezoelectric shell energy harvesting theory based on a double-curvature shell. The generic piezoelectric shell energy harvester consists of an elastic double-curvature shell and piezoelectric patches laminated on its surface(s). With a current model in the closed-circuit condition, output voltages and energies across a resistive load are evaluated when the shell is subjected to harmonic excitations. Steady-state voltage and power outputs across the resistive load are calculated at resonance for each shell mode. The piezoelectric shell energy harvesting mechanism can be simplified to shell (e.g., cylindrical, conical, spherical, paraboloidal, etc.) and non-shell (beam, plate, ring, arch, etc.) distributed harvesters using two Lamé parameters and two curvature radii of the selected harvester geometry. To demonstrate the utility and simplification procedures, the generic linear/nonlinear shell energy harvester mechanism is simplified to three specific structures, i.e., a cantilever beam case, a circular ring case and a conical shell case. Results show the versatility of the generic linear/nonlinear shell energy harvesting mechanism and the validity of the simplification procedures.

Method and apparatus for uniformly concentrating solar flux for photovoltaic applications

DOEpatents

Jorgensen, Gary J.; Carasso, Meir; Wendelin, Timothy J.; Lewandowski, Allan A.

1992-01-01

A dish reflector and method for concentrating moderate solar flux uniformly on a target plane on a solar cell array, the dish having a stepped reflective surface that is characterized by a plurality of ring-like segments arranged about a common axis, and each segment having a concave spherical configuration.

Wide scanning spherical antenna

NASA Technical Reports Server (NTRS)

Shen, Bing (Inventor); Stutzman, Warren L. (Inventor)

1995-01-01

A novel method for calculating the surface shapes for subreflectors in a suboptic assembly of a tri-reflector spherical antenna system is introduced, modeled from a generalization of Galindo-Israel's method of solving partial differential equations to correct for spherical aberration and provide uniform feed to aperture mapping. In a first embodiment, the suboptic assembly moves as a single unit to achieve scan while the main reflector remains stationary. A feed horn is tilted during scan to maintain the illuminated area on the main spherical reflector fixed throughout the scan thereby eliminating the need to oversize the main spherical reflector. In an alternate embodiment, both the main spherical reflector and the suboptic assembly are fixed. A flat mirror is used to create a virtual image of the suboptic assembly. Scan is achieved by rotating the mirror about the spherical center of the main reflector. The feed horn is tilted during scan to maintain the illuminated area on the main spherical reflector fixed throughout the scan.

Plasma oscillations in spherical Gaussian shaped ultracold neutral plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Tianxing; Lu, Ronghua, E-mail: lurh@siom.ac.cn; Guo, Li

2016-04-15

The collective plasma oscillations are investigated in ultracold neutral plasma with a non-uniform density profile. Instead of the plane configuration widely used, we derive the plasma oscillation equations with spherically symmetric distribution and Gaussian density profile. The damping of radial oscillation is found. The Tonks–Dattner resonances of the ultracold neutral plasma with an applied RF field are also calculated.

Effect of Particle Morphology on the Reactivity of Explosively Dispersed Titanium Particles

NASA Astrophysics Data System (ADS)

Frost, David; Cairns, Malcolm; Goroshin, Samuel; Zhang, Fan

2009-06-01

The effect of particle morphology on the reaction of titanium (Ti) particles explosively dispersed during the detonation of either cylindrical or spherical charges has been investigated experimentally. The explosive charges consisted of packed beds of Ti particles saturated with nitromethane. The reaction behavior of irregularly-shaped Ti particles in three size ranges is compared with tests with spherical Ti particles. The particle reaction is strongly dependent on particle morphology, e.g., 95 μm spherical Ti particles failed to ignite (in cylinders up to 49 mm in dia), whereas similarly sized irregular Ti particles readily ignited. For irregular particles, the uniformity of ignition on the particle cloud surface was almost independent of particle size, but depended on charge diameter. As the charge diameter was reduced, ignition in the conically expanding particle cloud occurred only at isolated spots or bands. For spherical charges, although large irregular Ti particles ignited promptly and uniformly throughout the particle cloud, the smallest particles dispersed nonuniformly and ignition occurred at isolated locations. In general, particle ignition is a competition between particle heating (which is influenced by particle morphology, size, number density and the local thermodynamic history) and expansion cooling of the products.

Designing of an artificial light energy converter in the form of short-chain dyad when combined with core-shell gold/silver nanocomposites.

PubMed

Dutta Pal, Gopa; Paul, Somnath; Bardhan, Munmun; De, Asish; Ganguly, Tapan

2017-06-05

UV-vis absorption, steady state and time resolved fluorescence and absorption spectroscopic investigations demonstrate that the short chain dyad MNTMA when combined with gold-silver core-shell (Au@Ag) nanocomposite , forms elongated conformers in the excited state whereas for the dyad - Ag (spherical) system the majority of dyads remains in a folded conformation. In the dyad-core-shell nanocomposite system, energy wasting charge recombination rate slows down primarily due to elongated conformation and thus it may be anticipated that this hybrid nanocomposite system may serve as a better light energy conversion device. Copyright © 2017 Elsevier B.V. All rights reserved.

A molecular dynamics study of the relaxation of an excited molecule in crystalline nitromethane

NASA Astrophysics Data System (ADS)

Rivera-Rivera, Luis A.; Siavosh-Haghighi, Ali; Sewell, Thomas D.; Thompson, Donald L.

2014-07-01

Classical molecular dynamics simulations were used to study the relaxation of an excited nitromethane molecule in perfect crystalline nitromethane at 250 K and 1 atm pressure. The molecule was instantaneously excited by statistically distributing energy E∗ between 25.0 kcal/mol and 125.0 kcal/mol among the 21 degrees of freedom of the molecule. The relaxation occurs exponentially with time constants between 11.58 ps and 13.57 ps. Energy transfer from the excited molecule to surrounding quasi-spherical shells of molecules occurs concurrently to both the nearest and next-nearest neighbor shells, but with more energy per molecule transferred more rapidly to the first shell.

Monodisperse core-shell particles composed of magnetite and dye-functionalized mesoporous silica

NASA Astrophysics Data System (ADS)

Eurov, D. A.; Kurdyukov, D. A.; Medvedev, A. V.; Kirilenko, D. A.; Yakovlev, D. R.; Golubev, V. G.

2017-08-01

Hybrid particles with a core-shell structure have been obtained in the form of monodisperse spherical mesoporous silica particles filled with magnetite and covered with a mesoporous silica shell functionalized with a luminescent dye. The particles have a small root-mean-square size deviation (at most 10%), possess a specific surface area and specific pore volume of up to 250 m2/g and 0.15 cm3/g, respectively, and exhibit visible luminescence peaked at a wavelength of 530 nm. The particles can be used in diagnostics of cancerous diseases, serving simultaneously for therapeutic (magnetic hyperthermia and targeted drug delivery) and diagnostic (contrast agent for magnetic-resonance tomography and luminescent marker) purposes.

An efficient shutter-less non-uniformity correction method for infrared focal plane arrays

NASA Astrophysics Data System (ADS)

Huang, Xiyan; Sui, Xiubao; Zhao, Yao

2017-02-01

The non-uniformity response in infrared focal plane array (IRFPA) detectors has a bad effect on images with fixed pattern noise. At present, it is common to use shutter to prevent from radiation of target and to update the parameters of non-uniformity correction in the infrared imaging system. The use of shutter causes "freezing" image. And inevitably, there exists the problems of the instability and reliability of system, power consumption, and concealment of infrared detection. In this paper, we present an efficient shutter-less non-uniformity correction (NUC) method for infrared focal plane arrays. The infrared imaging system can use the data gaining in thermostat to calculate the incident infrared radiation by shell real-timely. And the primary output of detector except the shell radiation can be corrected by the gain coefficient. This method has been tested in real infrared imaging system, reaching high correction level, reducing fixed pattern noise, adapting wide temperature range.

Spherical Macroporous Carbon Nanotube Particles with Ultrahigh Sulfur Loading for Lithium-Sulfur Battery Cathodes.

PubMed

Gueon, Donghee; Hwang, Jeong Tae; Yang, Seung Bo; Cho, Eunkyung; Sohn, Kwonnam; Yang, Doo-Kyung; Moon, Jun Hyuk

2018-01-23

A carbon host capable of effective and uniform sulfur loading is the key for lithium-sulfur batteries (LSBs). Despite the application of porous carbon materials of various morphologies, the carbon hosts capable of uniformly impregnating highly active sulfur is still challenging. To address this issue, we demonstrate a hierarchical pore-structured CNT particle host containing spherical macropores of several hundred nanometers. The macropore CNT particles (M-CNTPs) are prepared by drying the aerosol droplets in which CNTs and polymer particles are dispersed. The spherical macropore greatly improves the penetration of sulfur into the carbon host in the melt diffusion of sulfur. In addition, the formation of macropores greatly develops the volume of the micropore between CNT strands. As a result, we uniformly impregnate 70 wt % sulfur without sulfur residue. The S-M-CNTP cathode shows a highly reversible capacity of 1343 mA h g -1 at a current density of 0.2 C even at a high sulfur content of 70 wt %. Upon a 10-fold current density increase, a high capacity retention of 74% is observed. These cathodes have a higher sulfur content than those of conventional CNT hosts but nevertheless exhibit excellent performance. Our CNTPs and pore control technology will advance the commercialization of CNT hosts for LSBs.

Path planning and parameter optimization of uniform removal in active feed polishing

NASA Astrophysics Data System (ADS)

Liu, Jian; Wang, Shaozhi; Zhang, Chunlei; Zhang, Linghua; Chen, Huanan

2015-06-01

A high-quality ultrasmooth surface is demanded in short-wave optical systems. However, the existing polishing methods have difficulties meeting the requirement on spherical or aspheric surfaces. As a new kind of small tool polishing method, active feed polishing (AFP) could attain a surface roughness of less than 0.3 nm (RMS) on spherical elements, although AFP may magnify the residual figure error or mid-frequency error. The purpose of this work is to propose an effective algorithm to realize uniform removal of the surface in the processing. At first, the principle of the AFP and the mechanism of the polishing machine are introduced. In order to maintain the processed figure error, a variable pitch spiral path planning algorithm and the dwell time-solving model are proposed. For suppressing the possible mid-frequency error, the uniformity of the synthesis tool path, which is generated by an arbitrary point at the polishing tool bottom, is analyzed and evaluated, and the angular velocity ratio of the tool spinning motion to the revolution motion is optimized. Finally, an experiment is conducted on a convex spherical surface and an ultrasmooth surface is finally acquired. In conclusion, a high-quality ultrasmooth surface can be successfully obtained with little degradation of the figure and mid-frequency errors by the algorithm.

High-resolution speckle masking interferometry and radiative transfer modeling of the oxygen-rich AGB star AFGL 2290

NASA Astrophysics Data System (ADS)

Gauger, A.; Balega, Y. Y.; Irrgang, P.; Osterbart, R.; Weigelt, G.

1999-06-01

We present the first diffraction-limited speckle masking observations of the oxygen-rich AGB star AFGL 2290. The speckle interferograms were recorded with the Russian 6 m SAO telescope. At the wavelength 2.11 microns a resolution of 75 milli-arcsec (mas) was obtained. The reconstructed diffraction-limited image reveals that the circumstellar dust shell (CDS) of AFGL 2290 is at least slightly non-spherical. The visibility function shows that the stellar contribution to the total 2.11 microns flux is less than ~ 40%, indicating a rather large optical depth of the circumstellar dust shell. The 2-dimensional Gaussian visibility fit yields a diameter of AFGL 2290 at 2.11 microns of 43 masx51 mas, which corresponds to a diameter of 42 AUx50 AU for an adopted distance of 0.98 kpc. Our new observational results provide additional constraints on the CDS of AFGL 2290, which supplement the information from the spectral energy distribution (SED). To determine the structure and the properties of the CDS we have performed radiative transfer calculations for spherically symmetric dust shell models. The observed SED approximately at phase 0.2 can be well reproduced at all wavelengths by a model with T_eff=2000 K, a dust temperature of 800 K at the inner boundary r1, an optical depth tau_ {V}=100 and a radius for the single-sized grains of a_gr=0.1 microns . However, the 2.11 microns visibility of the model does not match the observation. Exploring the parameter space, we found that grain size is the key parameter in achieving a fit of the observed visibility while retaining the match of the SED, at least partially. Both the slope and the curvature of the visibility strongly constrain the possible grain radii. On the other hand, the SED at longer wavelengths, the silicate feature in particular, determines the dust mass loss rate and, thereby, restricts the possible optical depths of the model. With a larger grain size of 0.16 microns and a higher tau_ {V}=150, the observed visibility can be reproduced preserving the match of the SED at longer wavelengths. Nevertheless, the model shows a deficiency of flux at short wavelengths, which is attributed to the model assumption of a spherically symmetric dust distribution, whereas the actual structure of the CDS around AFGL 2290 is in fact non-spherical. Our study demonstrates the possible limitations of dust shell models which are constrained solely by the spectral energy distribution, and emphasizes the importance of high spatial resolution observations for the determination of the structure and the properties of circumstellar dust shells around evolved stars. Based on data collected at the 6~m telescope of the Special Astrophysical Observatory in Russia

Nonlinear elastic inclusions in isotropic solids.

PubMed

Yavari, Arash; Goriely, Alain

2013-12-08

We introduce a geometric framework to calculate the residual stress fields and deformations of nonlinear solids with inclusions and eigenstrains. Inclusions are regions in a body with different reference configurations from the body itself and can be described by distributed eigenstrains. Geometrically, the eigenstrains define a Riemannian 3-manifold in which the body is stress-free by construction. The problem of residual stress calculation is then reduced to finding a mapping from the Riemannian material manifold to the ambient Euclidean space. Using this construction, we find the residual stress fields of three model systems with spherical and cylindrical symmetries in both incompressible and compressible isotropic elastic solids. In particular, we consider a finite spherical ball with a spherical inclusion with uniform pure dilatational eigenstrain and we show that the stress in the inclusion is uniform and hydrostatic. We also show how singularities in the stress distribution emerge as a consequence of a mismatch between radial and circumferential eigenstrains at the centre of a sphere or the axis of a cylinder.

Nonlinear elastic inclusions in isotropic solids

PubMed Central

Yavari, Arash; Goriely, Alain

2013-01-01

We introduce a geometric framework to calculate the residual stress fields and deformations of nonlinear solids with inclusions and eigenstrains. Inclusions are regions in a body with different reference configurations from the body itself and can be described by distributed eigenstrains. Geometrically, the eigenstrains define a Riemannian 3-manifold in which the body is stress-free by construction. The problem of residual stress calculation is then reduced to finding a mapping from the Riemannian material manifold to the ambient Euclidean space. Using this construction, we find the residual stress fields of three model systems with spherical and cylindrical symmetries in both incompressible and compressible isotropic elastic solids. In particular, we consider a finite spherical ball with a spherical inclusion with uniform pure dilatational eigenstrain and we show that the stress in the inclusion is uniform and hydrostatic. We also show how singularities in the stress distribution emerge as a consequence of a mismatch between radial and circumferential eigenstrains at the centre of a sphere or the axis of a cylinder. PMID:24353470

A fully automatic, threshold-based segmentation method for the estimation of the Metabolic Tumor Volume from PET images: validation on 3D printed anthropomorphic oncological lesions

NASA Astrophysics Data System (ADS)

Gallivanone, F.; Interlenghi, M.; Canervari, C.; Castiglioni, I.

2016-01-01

18F-Fluorodeoxyglucose (18F-FDG) Positron Emission Tomography (PET) is a standard functional diagnostic technique to in vivo image cancer. Different quantitative paramters can be extracted from PET images and used as in vivo cancer biomarkers. Between PET biomarkers Metabolic Tumor Volume (MTV) has gained an important role in particular considering the development of patient-personalized radiotherapy treatment for non-homogeneous dose delivery. Different imaging processing methods have been developed to define MTV. The different proposed PET segmentation strategies were validated in ideal condition (e.g. in spherical objects with uniform radioactivity concentration), while the majority of cancer lesions doesn't fulfill these requirements. In this context, this work has a twofold objective: 1) to implement and optimize a fully automatic, threshold-based segmentation method for the estimation of MTV, feasible in clinical practice 2) to develop a strategy to obtain anthropomorphic phantoms, including non-spherical and non-uniform objects, miming realistic oncological patient conditions. The developed PET segmentation algorithm combines an automatic threshold-based algorithm for the definition of MTV and a k-means clustering algorithm for the estimation of the background. The method is based on parameters always available in clinical studies and was calibrated using NEMA IQ Phantom. Validation of the method was performed both in ideal (e.g. in spherical objects with uniform radioactivity concentration) and non-ideal (e.g. in non-spherical objects with a non-uniform radioactivity concentration) conditions. The strategy to obtain a phantom with synthetic realistic lesions (e.g. with irregular shape and a non-homogeneous uptake) consisted into the combined use of standard anthropomorphic phantoms commercially and irregular molds generated using 3D printer technology and filled with a radioactive chromatic alginate. The proposed segmentation algorithm was feasible in a clinical context and showed a good accuracy both in ideal and in realistic conditions.

Well-crystallized mesoporous TiO2 shells for enhanced photocatalytic activity: prepared by carbon coating and silica-protected calcination.

PubMed

Zhang, Zewu; Zhou, Yuming; Zhang, Yiwei; Zhou, Shijian; Shi, Junjun; Kong, Jie; Zhang, Sicheng

2013-04-14

Mesoporous anatase-phase TiO2 hollow shells were successfully fabricated by the solvothermal and calcination process. This method involves preparation of SiO2@TiO2 core-shell colloidal templates, sequential deposition of carbon and then silica layers through solvothermal and sol-gel processes, crystallization of TiO2 by calcination and finally removal of the inner and outer silica to produce hollow anatase TiO2 shells. The prepared samples were characterized by transmission electron microscopy, X-ray diffraction, N2 adsorption-desorption isotherms and UV-vis absorption spectroscopy. The results show that a uniform carbon layer is coated on the core-shell particles through the solvothermal process. The combustion of carbon offers the space for the TiO2 to further grow into large crystal grains, and the outer silica layer serves as a barrier against the excessive growth of anatase TiO2 nanocrystals. Furthermore, the initial crystallization of TiO2 generated in the carbon coating step and the heat generated by the combustion of the carbon layer allow the crystallization of TiO2 at a relatively low temperature without changing the uniform structure. When used as photocatalysts for the oxidation decomposition of Rhodamine B in aqueous solution under UV irradiation, the hollow TiO2 shells showed enhanced catalytic activity. Moreover, the TiO2 hollow shells prepared with optimal crystallinity by this method showed a higher performance than commercial P25 TiO2.

Optimization and design of pigments for heat-insulating coatings

NASA Astrophysics Data System (ADS)

Wang, Guang-Hai; Zhang, Yue

2010-12-01

This paper reports that heat insulating property of infrared reflective coatings is obtained through the use of pigments which diffuse near-infrared thermal radiation. Suitable structure and size distribution of pigments would attain maximum diffuse infrared radiation and reduce the pigment volume concentration required. The optimum structure and size range of pigments for reflective infrared coatings are studied by using Kubelka—Munk theory, Mie model and independent scattering approximation. Taking titania particle as the pigment embedded in an inorganic coating, the computational results show that core-shell particles present excellent scattering ability, more so than solid and hollow spherical particles. The optimum radius range of core-shell particles is around 0.3 ~ 1.6 μm. Furthermore, the influence of shell thickness on optical parameters of the coating is also obvious and the optimal thickness of shell is 100-300 nm.

Glass shell manufacturing in space. [residual gases in spherical shells made from metal-organic gels

NASA Technical Reports Server (NTRS)

Nolen, R. J.; Ebner, M. A.; Downs, R. L.

1980-01-01

Residual gases always found in glass shells are CO2, O2 and N2. In those cases where high water vapor pressure is maintained in the furnace, water is also found in the shells. Other evidence for the existence of water in shells is the presence of water-induced surface weathering of the interior shell surface. Water and CO2 are the predominant volatiles generated by the pyrolysis of both inorganic and hydrolyzed metal-organic gels. The pyrolysates of unhydrolyzed metal-organic gels also contain, in addition to water and CO2, significant levels of organic volatiles, such as ethanol and some hydrocarbons; on complete oxidation, these produce CO2 and water as well. Water is most likely the initial blowing agent, it is produced copiously during the initial stages of heating. In the later stages, CO2 becomes the dominant gas as H2O is lost at increasing rates. Water in the shell arises mainly from gel dehydration, CO2 by sodium bicarbonate/carbonate decomposition and carbon oxidation, and O2 and N2 by permeation of the ambient furnace air through the molten shell wall.

Radiative transfer in spherical shell atmospheres. 2: Asymmetric phase functions

NASA Technical Reports Server (NTRS)

Kattawar, G. W.; Adams, C. N.

1977-01-01

The effects are investigated of sphericity on the radiation reflected from a planet with a homogeneous, conservative scattering atmosphere of optical thicknesses of 0.25 and 1.0. A Henyey-Greenstein phase function with asymmetry factors of 0.5 and 0.7 is considered. Significant differences were found when these results were compared with the plane-parallel calculations. Also large violations of the reciprocity theorem, which is only true for plane-parallel calculations, were noted. Results are presented for the radiance versus height distributions as a function of planetary phase angle.

Cosmic dust-ion-acoustic waves, spherical modified Kadomtsev-Petviashvili model, and symbolic computation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao Yitian; Tian Bo; State Key Laboratory of Software Development Environment, Beijing University of Aeronautics and Astronautics, Beijing 100083

2006-11-15

The spherical modified Kadomtsev-Petviashvili (smKP) model is hereby derived with symbolic computation for the dust-ion-acoustic waves with zenith-angle perturbation in a cosmic dusty plasma. Formation and properties of both dark and bright smKP nebulons are obtained and discussed. The relevance of those smKP nebulons to the supernova shells and Saturn's F-ring is pointed out, and possibly observable nebulonic effects for the future cosmic plasma experiments are proposed. The difference of the smKP nebulons from other types of nebulons is also analyzed.

Black hole evaporation in conformal gravity

NASA Astrophysics Data System (ADS)

Bambi, Cosimo; Modesto, Leonardo; Porey, Shiladitya; Rachwał, Lesław

2017-09-01

We study the formation and the evaporation of a spherically symmetric black hole in conformal gravity. From the collapse of a spherically symmetric thin shell of radiation, we find a singularity-free non-rotating black hole. This black hole has the same Hawking temperature as a Schwarzschild black hole with the same mass, and it completely evaporates either in a finite or in an infinite time, depending on the ensemble. We consider the analysis both in the canonical and in the micro-canonical statistical ensembles. Last, we discuss the corresponding Penrose diagram of this physical process.

The AGCE related studies of baroclinic flows in spherical geometry

NASA Technical Reports Server (NTRS)

Hyun, J. M.

1983-01-01

Steady state, axisymmetric motions of a Boussineaq fluid continued in rotating spherical anmulus are considered. The motions are driven by latitudinally varying temperature gradient at the shells. Linearized formulations for a narrow gap are derived and the flow field is divided into the Ekman layers and the geostrophic interior. The Ekman layer flows are consistent with the known results for cylindrical geometries. Within the framework of rather restrictive assumptions, the interior flows are solved by a series of associated Legendre polynomials. The solutions show qualitative features valid at midlatitudes.

Black hole evaporation in conformal gravity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bambi, Cosimo; Rachwał, Lesław; Modesto, Leonardo

We study the formation and the evaporation of a spherically symmetric black hole in conformal gravity. From the collapse of a spherically symmetric thin shell of radiation, we find a singularity-free non-rotating black hole. This black hole has the same Hawking temperature as a Schwarzschild black hole with the same mass, and it completely evaporates either in a finite or in an infinite time, depending on the ensemble. We consider the analysis both in the canonical and in the micro-canonical statistical ensembles. Last, we discuss the corresponding Penrose diagram of this physical process.

Time-dependent response of filamentary composite spherical pressure vessels

NASA Technical Reports Server (NTRS)

Dozier, J. D.

1983-01-01

A filamentary composite spherical pressure vessel is modeled as a pseudoisotropic (or transversely isotropic) composite shell, with the effects of the liner and fill tubes omitted. Equations of elasticity, macromechanical and micromechanical formulations, and laminate properties are derived for the application of an internally pressured spherical composite vessel. Viscoelastic properties for the composite matrix are used to characterize time-dependent behavior. Using the maximum strain theory of failure, burst pressure and critical strain equations are formulated, solved in the Laplace domain with an associated elastic solution, and inverted back into the time domain using the method of collocation. Viscoelastic properties of HBFR-55 resin are experimentally determined and a Kevlar/HBFR-55 system is evaluated with a FORTRAN program. The computed reduction in burst pressure with respect to time indicates that the analysis employed may be used to predict the time-dependent response of a filamentary composite spherical pressure vessel.

Impact of spherical nanoparticles on nematic order parameters

NASA Astrophysics Data System (ADS)

Kyrou, C.; Kralj, S.; Panagopoulou, M.; Raptis, Y.; Nounesis, G.; Lelidis, I.

2018-04-01

We study experimentally the impact of spherical nanoparticles on the orientational order parameters of a host nematic liquid crystal. We use spherical core-shell quantum dots that are surface functionalized to promote homeotropic anchoring on their interface with the liquid crystal host. We show experimentally that the orientational order may be strongly affected by the presence of spherical nanoparticles even at low concentrations. The orientational order of the composite system is probed by means of polarized micro-Raman spectroscopy and by optical birefringence measurements as function of temperature and concentration. Our data show that the orientational order depends on the concentration in a nonlinear way, and the existence of a crossover concentration χc≈0.004 pw . It separates two different regimes exhibiting pure-liquid crystal like (χ <χc ) and distorted-nematic ordering (χ >χc ), respectively. In the latter phase the degree of ordering is lower with respect to the pure-liquid crystal nematic phase.

Elastic properties of spherically anisotropic piezoelectric composites

NASA Astrophysics Data System (ADS)

Wei, En-Bo; Gu, Guo-Qing; Poon, Ying-Ming

2010-09-01

Effective elastic properties of spherically anisotropic piezoelectric composites, whose spherically anisotropic piezoelectric inclusions are embedded in an infinite non-piezoelectric matrix, are theoretically investigated. Analytical solutions for the elastic displacements and the electric potentials under a uniform external strain are derived exactly. Taking into account of the coupling effects of elasticity, permittivity and piezoelectricity, the formula is derived for estimating the effective elastic properties based on the average field theory in the dilute limit. An elastic response mechanism is revealed, in which the effective elastic properties increase as inclusion piezoelectric properties increase and inclusion dielectric properties decrease. Moreover, a piezoelectric response mechanism, of which the effective piezoelectric response vanishes due to the symmetry of spherically anisotropic composite, is also disclosed.

Scope of inextensible frame hypothesis in local action analysis of spherical reservoirs

NASA Astrophysics Data System (ADS)

Vinogradov, Yu. I.

2017-05-01

Spherical reservoirs, as objects perfect with respect to their weight, are used in spacecrafts, where thin-walled elements are joined by frames into multifunction structures. The junctions are local, which results in origination of stress concentration regions and the corresponding rigidity problems. The thin-walled elements are reinforced by frame to decrease the stresses in them. To simplify the analysis of the mathematical model of common deformation of the shell (which is a mathematical idealization of the reservoir) and the frame, the assumption that the frame axial line is inextensible is used widely (in particular, in the manual literature). The unjustified use of this assumption significantly distorts the concept of the stress-strain state. In this paper, an example of a lens-shaped structure formed as two spherical shell segments connected by a frame of square profile is used to carry out a numerical comparative analysis of the solutions with and without the inextensible frame hypothesis taken into account. The scope of the hypothesis is shown depending on the structure geometric parameters and the load location degree. The obtained results can be used to determine the stress-strain state of the thin-walled structure with an a priori prescribed error, for example, in research and experimental design of aerospace systems.

Low fuel convergence path to ignition on the NIF

NASA Astrophysics Data System (ADS)

Schmitt, M. J.; Molvig, Kim; Gianakon, T. A.; Woods, C. N.; Krasheninnikova, N. S.; Hsu, S. C.; Schmidt, D. W.; Dodd, E. S.; Zylstra, Alex; Scheiner, B.; McKenty, P.; Campbell, E. M.; Froula, D.; Betti, R.; Michel, T.

2017-10-01

A novel concept for achieving ignition on the NIF is proposed that obviates current issues plaguing single-shell high-convergence capsules. A large directly-driven Be shell is designed to robustly implode two nested internal shells by efficiently converting 1.7MJ of laser energy from a 6 ns, low intensity laser pulse, into a 1 ns dynamic pressure pulse to ignite and burn a central liquid DT core after a fuel convergence of only 9. The short, low intensity laser pulse mitigates LPI allowing more uniform laser drive of the target and eliminates hot e-, preheat and laser zooming issues. Preliminary rad-hydro simulations predict ignition initiation with 90% maximum inner shell velocity, before deceleration Rayleigh-Taylor growth can cause significant pusher shell mix into the compressed DT fuel. The gold inner pusher shell reduces pre-ignition radiation losses from the fuel allowing ignition to occur at 2.5keV. Further 2D simulations show that the short pulse design results in a spatially uniform kinetic drive that is tolerant to variations in laser cone power. A multi-pronged effort, in collaboration with LLE, is progressing to optimize this design for NIF's PDD laser configuration. Work performed under the auspices of the U.S. Dept. of Energy by the Los Alamos National Security, LLC, Los Alamos National Laboratory under contract DE-FG02-051ER54810.

Coaxial Electrospinning and Characterization of Core-Shell Structured Cellulose Nanocrystal Reinforced PMMA/PAN Composite Fibers

PubMed Central

Li, Chao; Li, Qingde; Ni, Xiaohui; Liu, Guoxiang; Cheng, Wanli; Han, Guangping

2017-01-01

A modified coaxial electrospinning process was used to prepare composite nanofibrous mats from a poly(methyl methacrylate) (PMMA) solution with the addition of different cellulose nanocrystals (CNCs) as the sheath fluid and polyacrylonitrile (PAN) solution as the core fluid. This study investigated the conductivity of the as-spun solutions that increased significantly with increasing CNCs addition, which favors forming uniform fibers. This study discussed the effect of different CNCs addition on the morphology, thermal behavior, and the multilevel structure of the coaxial electrospun PMMA + CNCs/PAN composite nanofibers. A morphology analysis of the nanofibrous mats clearly demonstrated that the CNCs facilitated the production of the composite nanofibers with a core-shell structure. The diameter of the composite nanofibers decreased and the uniformity increased with increasing CNCs concentrations in the shell fluid. The composite nanofibrous mats had the maximum thermal decomposition temperature that was substantially higher than electrospun pure PMMA, PAN, as well as the core-shell PMMA/PAN nanocomposite. The BET (Brunauer, Emmett and Teller) formula results showed that the specific surface area of the CNCs reinforced core-shell composite significantly increased with increasing CNCs content. The specific surface area of the composite with 20% CNCs loading rose to 9.62 m2/g from 3.76 m2/g for the control. A dense porous structure was formed on the surface of the electrospun core-shell fibers. PMID:28772933

Critical strain for Sn incorporation into spontaneously graded Ge/GeSn core/shell nanowires.

PubMed

Albani, Marco; Assali, Simone; Verheijen, Marcel A; Koelling, Sebastian; Bergamaschini, Roberto; Pezzoli, Fabio; Bakkers, Erik P A M; Miglio, Leo

2018-04-19

We address the role of non-uniform composition, as measured by energy-dispersive x-ray spectroscopy, in the elastic properties of core/shell nanowires for the Ge/GeSn system. In particular, by finite element method simulations and transmission electron diffraction measurements, we estimate the residual misfit strain when a radial gradient in Sn and a Ge segregation at the nanowire facet edges are present. An elastic stiffening of the structure with respect to the uniform one is concluded, particularly for the axial strain component. More importantly, refined predictions linking the strain and the Sn percentage at the nanowire facets enable us to quantitatively determine the maximum compressive strain value allowing for additional Sn incorporation into a GeSn alloy. The progressive incorporation with increasing shell thickness, under constant growth conditions, is specifically induced by the nanowire configuration, where a larger elastic relaxation of the misfit strain takes place.

IRC +10 216 in 3-D: morphology of a TP-AGB star envelope

PubMed Central

Guélin, M.; Patel, N.A.; Bremer, M.; Cernicharo, J.; Castro-Carrizo, A.; Pety, J.; Fonfría, J.P.; Agúndez, M.; Santander-García, M.; Quintana-Lacaci, G.; Velilla Prieto, L.; Blundell, R.; Thaddeus, P.

2017-01-01

During their late pulsating phase, AGB stars expel most of their mass in the form of massive dusty envelopes, an event that largely controls the composition of interstellar matter. The envelopes, however, are distant and opaque to visible and NIR radiation: their structure remains poorly known and the mass-loss process poorly understood. Millimeter-wave interferometry, which combines the advantages of longer wavelength, high angular resolution and very high spectral resolution is the optimal investigative tool for this purpose. Mm waves pass through dust with almost no attenuation. Their spectrum is rich in molecular lines and hosts the fundamental lines of the ubiquitous CO molecule, allowing a tomographic reconstruction of the envelope structure. The circumstellar envelope IRC +10 216 and its central star, the C-rich TP-AGB star closest to the Sun, are the best objects for such an investigation. Two years ago, we reported the first detailed study of the CO(2-1) line emission in that envelope, made with the IRAM 30-m telescope. It revealed a series of dense gas shells, expanding at a uniform radial velocity. The limited resolution of the telescope (HPBW 11″) did not allow us to resolve the shell structure. We now report much higher angular resolution observations of CO(2-1), CO(1-0), CN(2-1) and C4H(24-23) made with the SMA, PdB and ALMA interferometers (with synthesized half-power beamwidths of 3″, 1″ and 0.3″, respectively). Although the envelope appears much more intricate at high resolution than with an 11″ beam, its prevailing structure remains a pattern of thin, nearly concentric shells. The average separation between the brightest CO shells is 16″ in the outer envelope, where it appears remarkably constant. Closer to the star (< 40″), the shell pattern is denser and less regular, showing intermediary arcs. Outside the small (r < 0.3″) dust formation zone, the gas appears to expand radially at a constant velocity, 14.5 km s−1, with small turbulent motions. Based on that property, we have reconstructed the 3-D structure of the outer envelope and have derived the gas temperature and density radial profiles in the inner (r < 25″) envelope. The shell-intershell density contrast is found to be typically 3. The over-dense shells have spherical or slightly oblate shapes and typically extend over a few steradians, implying isotropic mass loss. The regular spacing of shells in the outer envelope supports the model of a binary star system with a period of 700 years and a near face-on elliptical orbit. The companion fly-by triggers enhanced episodes of mass loss near periastron. The densification of the shell pattern observed in the central part of the envelope suggests a more complex scenario for the last few thousand years. ⋆ PMID:29456257

Suppression of an acoustic mode by an elastic mode of a liquid-filled spherical shell resonator.

PubMed

Lonzaga, Joel B; Raymond, Jason L; Mobley, Joel; Gaitan, D Felipe

2011-02-01

The purpose of this paper is to report on the suppression of an approximately radial (radially symmetric) acoustic mode by an elastic mode of a water-filled, spherical shell resonator. The resonator, which has a 1-in. wall thickness and a 9.5-in. outer diameter, was externally driven by a small transducer bolted to the external wall. Experiments showed that for the range of drive frequencies (19.7-20.6 kHz) and sound speeds in water (1520-1570 m/s) considered in this paper, a nonradial (radially nonsymmetric) mode was also excited, in addition to the radial mode. Furthermore, as the sound speed in the liquid was changed, the resonance frequency of the nonradial mode crossed with that of the radial one and the amplitude of the latter was greatly reduced near the crossing point. The crossing of the eigenfrequency curves of these two modes was also predicted theoretically. Further calculations demonstrated that while the radial mode is an acoustic one associated with the interior fluid, the nonradial mode is an elastic one associated with the shell. Thus, the suppression of the radial acoustic mode is apparently caused by the overlapping with the nonradial elastic mode near the crossing point.

Solar-Light-Driven Renewable Butanol Separation by Core-Shell Ag@ZIF-8 Nanowires.

PubMed

Liu, Xu; He, Liangcan; Zheng, Jianzhong; Guo, Jun; Bi, Feng; Ma, Xiang; Zhao, Kun; Liu, Yaling; Song, Rui; Tang, Zhiyong

2015-06-03

Core-shell Ag@ZIF-8 nanowires, where single Ag nanowires are coated with uniform zeolitic-imidazolate-framework-8 (ZIF-8) shells, successfully realize renewable adsorptive separation of low concentrations of butanol from an aqueous medium under solar light irradiation by taking advantage of the exceptional adsorption capability of the ZIF-8 shells toward butanol and the unique plasmonic photothermal effect of the Ag nanowire cores. Impressively, the high separation efficiency is maintained as almost unchanged, even after 10 adsorption/desorption cycles. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spherical Pendulum Small Oscillations for Slewing Crane Motion

PubMed Central

Perig, Alexander V.; Stadnik, Alexander N.; Deriglazov, Alexander I.

2014-01-01

The present paper focuses on the Lagrange mechanics-based description of small oscillations of a spherical pendulum with a uniformly rotating suspension center. The analytical solution of the natural frequencies' problem has been derived for the case of uniform rotation of a crane boom. The payload paths have been found in the inertial reference frame fixed on earth and in the noninertial reference frame, which is connected with the rotating crane boom. The numerical amplitude-frequency characteristics of the relative payload motion have been found. The mechanical interpretation of the terms in Lagrange equations has been outlined. The analytical expression and numerical estimation for cable tension force have been proposed. The numerical computational results, which correlate very accurately with the experimental observations, have been shown. PMID:24526891

Detection of defects on apple using B-spline lighting correction method

NASA Astrophysics Data System (ADS)

Li, Jiangbo; Huang, Wenqian; Guo, Zhiming

To effectively extract defective areas in fruits, the uneven intensity distribution that was produced by the lighting system or by part of the vision system in the image must be corrected. A methodology was used to convert non-uniform intensity distribution on spherical objects into a uniform intensity distribution. A basically plane image with the defective area having a lower gray level than this plane was obtained by using proposed algorithms. Then, the defective areas can be easily extracted by a global threshold value. The experimental results with a 94.0% classification rate based on 100 apple images showed that the proposed algorithm was simple and effective. This proposed method can be applied to other spherical fruits.

A new treatment of the albedo radiation pressure in the case of a uniform albedo and of a spherical satellite

NASA Technical Reports Server (NTRS)

Borderies, Nicole; Longaretti, Pierre-Yves

1990-01-01

The purpose of this paper is to present a model for the radiation pressure acceleration of a spherical satellite, due to the radiation reflected by a planet with a uniform albedo. A particular choice of variables allows one to reduce the surface integrals over the lit portion of the planet visible to the satellite to one-dimensional integrals. Exact analytical expressions are found for the integrals corresponding to the case where the spacecraft does not 'see' the terminator. The other integrals can be computer either numerically, or analytical in an approximate form. The results are compared with those of Lochry (1966). The model is applied to Magellan, a spacecraft orbiting Venus.

Acoustic Characterization and Enhanced Ultrasound Imaging of Long-Circulating Lipid-Coated Microbubbles.

PubMed

Li, Hongbo; Yang, Yanye; Zhang, Meimei; Yin, Liping; Tu, Juan; Guo, Xiasheng; Zhang, Dong

2018-05-01

A long-circulating lipid-coated ultrasound (US) contrast agent was fabricated to achieve a longer wash-out time and gain more resistance against higher-mechanical index sonication. Systemic physical, acoustic, and in vivo imaging experiments were performed to better understand the underlying mechanism enabling the improvement of contrast agent performance by adjusting the physical and acoustic properties of contrast agent microbubbles. By simply altering the gas core, a kind of US contrast agent microbubble was synthesized with a similar lipid-coating shell as SonoVue microbubbles (Bracco SpA, Milan, Italy) to achieve a longer wash-out time and higher inertial cavitation threshold. To bridge the structure-performance relationship of the synthesized microbubbles, the imaging performance of the microbubbles was assessed in vivo with SonoVue as a control group. The size distribution and inertial cavitation threshold of the synthesized microbubbles were characterized, and the shell parameters of the microbubbles were determined by acoustic attenuation measurements. All of the measurements were compared with SonoVue microbubbles. The synthesized microbubbles had a spherical shape, a smooth, consistent membrane, and a uniform distribution, with an average diameter of 1.484 μm. According to the measured attenuation curve, the synthesized microbubbles resonated at around 2.8 MHz. Although the bubble's shell elasticity (0.2 ± 0.09 N/m) was comparable with SonoVue, it had relatively greater viscosity and inertial cavitation because of the different gas core. Imaging studies showed that the synthesized microbubbles had a longer circulation time and a better chance of fighting against rapid collapse than SonoVue. Nano/micrometer long-circulating lipid-coated microbubbles could be fabricated by simply altering the core composition of SonoVue microbubbles with a higher-molecular weight gas. The smaller diameter and higher inertial cavitation threshold of the synthesized microbubbles might make it easier to access deep-seated organs and give prolonged imaging enhancement in the liver. © 2017 by the American Institute of Ultrasound in Medicine.

Effect of shear stress on cell cultures and other reactor problems

NASA Technical Reports Server (NTRS)

Schleier, H.

1981-01-01

Anchorage dependent cell cultures in fluidized beds are tested. Feasibility calculations indicate the allowed parameters and estimate the shear stresses therein. In addition, the diffusion equation with first order reaction is solved for the spherical shell (double bubble) reactor with various constraints.

The Confinement and Breakout of Protostellar Winds: Time-Dependent Solution

NASA Technical Reports Server (NTRS)

Wilkin, F.; Stahler, S.

2000-01-01

Jets from embedded young stars may be collimated by the anisotropic infall of their cloud envelopes. To model this effect, we have followed numerically the motion of the shocked shell created by the impact of a spherical wind and a rotating, collapsing cloud.

The Ozone Mapping and Profiler Suite (OMPS) Limb Profiler (LP) Version 1 aerosol extinction retrieval algorithm: theoretical basis

NASA Astrophysics Data System (ADS)

Loughman, Robert; Bhartia, Pawan K.; Chen, Zhong; Xu, Philippe; Nyaku, Ernest; Taha, Ghassan

2018-05-01

The theoretical basis of the Ozone Mapping and Profiler Suite (OMPS) Limb Profiler (LP) Version 1 aerosol extinction retrieval algorithm is presented. The algorithm uses an assumed bimodal lognormal aerosol size distribution to retrieve aerosol extinction profiles at 675 nm from OMPS LP radiance measurements. A first-guess aerosol extinction profile is updated by iteration using the Chahine nonlinear relaxation method, based on comparisons between the measured radiance profile at 675 nm and the radiance profile calculated by the Gauss-Seidel limb-scattering (GSLS) radiative transfer model for a spherical-shell atmosphere. This algorithm is discussed in the context of previous limb-scattering aerosol extinction retrieval algorithms, and the most significant error sources are enumerated. The retrieval algorithm is limited primarily by uncertainty about the aerosol phase function. Horizontal variations in aerosol extinction, which violate the spherical-shell atmosphere assumed in the version 1 algorithm, may also limit the quality of the retrieved aerosol extinction profiles significantly.

Impacts of Modification of Alloying Method on Inclusion Evolution in RH Refining of Silicon Steel.

PubMed

Li, Fangjie; Li, Huigai; Zheng, Shaobo; You, Jinglin; Han, Ke; Zhai, Qijie

2017-10-19

This study explores the effect of introducing additional alloy elements not only in a different order but also at different stages of the Ruhrstahl-Heraeus (RH) process of low-carbon silicon steel production. A more economical method, described as "pre-alloying", has been introduced. The evolution of MnO-FeO inclusions produced by pre-alloying was investigated. Results show that spherical 3FeO·MnO inclusions form first, then shelled FeO·zMnO (z = 0.7-4) inclusions nucleate on the surface of pre-existing 3FeO·MnO. Spherical FeO·zMnO (z = 3-5) is further evolved from shelled 3FeO·MnO by diffusion. Because these MnO-FeO inclusions float up into the slag before degassing, the pre-alloying process does not affect the quality of the melt in the end. Both carbon content and inclusion size conform to industry standards.

Exact solution of mean-field plus an extended T = 1 nuclear pairing Hamiltonian in the seniority-zero symmetric subspace

NASA Astrophysics Data System (ADS)

Pan, Feng; Ding, Xiaoxue; Launey, Kristina D.; Dai, Lianrong; Draayer, Jerry P.

2018-05-01

An extended pairing Hamiltonian that describes multi-pair interactions among isospin T = 1 and angular momentum J = 0 neutron-neutron, proton-proton, and neutron-proton pairs in a spherical mean field, such as the spherical shell model, is proposed based on the standard T = 1 pairing formalism. The advantage of the model lies in the fact that numerical solutions within the seniority-zero symmetric subspace can be obtained more easily and with less computational time than those calculated from the mean-field plus standard T = 1 pairing model. Thus, large-scale calculations within the seniority-zero symmetric subspace of the model is feasible. As an example of the application, the average neutron-proton interaction in even-even N ∼ Z nuclei that can be suitably described in the f5 pg9 shell is estimated in the present model, with a focus on the role of np-pairing correlations.

Buckling Instability Causes Inertial Thrust for Spherical Swimmers at All Scales

NASA Astrophysics Data System (ADS)

Djellouli, Adel; Marmottant, Philippe; Djeridi, Henda; Quilliet, Catherine; Coupier, Gwennou

2017-12-01

Microswimmers, and among them aspirant microrobots, generally have to cope with flows where viscous forces are dominant, characterized by a low Reynolds number (Re). This implies constraints on the possible sequences of body motion, which have to be nonreciprocal. Furthermore, the presence of a strong drag limits the range of resulting velocities. Here, we propose a swimming mechanism which uses the buckling instability triggered by pressure waves to propel a spherical, hollow shell. With a macroscopic experimental model, we show that a net displacement is produced at all Re regimes. An optimal displacement caused by nontrivial history effects is reached at intermediate Re. We show that, due to the fast activation induced by the instability, this regime is reachable by microscopic shells. The rapid dynamics would also allow high-frequency excitation with standard traveling ultrasonic waves. Scale considerations predict a swimming velocity of order 1 cm /s for a remote-controlled microrobot, a suitable value for biological applications such as drug delivery.

Impacts of Modification of Alloying Method on Inclusion Evolution in RH Refining of Silicon Steel

PubMed Central

Li, Huigai; Zheng, Shaobo; You, Jinglin; Han, Ke; Zhai, Qijie

2017-01-01

This study explores the effect of introducing additional alloy elements not only in a different order but also at different stages of the Ruhrstahl-Heraeus (RH) process of low-carbon silicon steel production. A more economical method, described as “pre-alloying”, has been introduced. The evolution of MnO-FeO inclusions produced by pre-alloying was investigated. Results show that spherical 3FeO·MnO inclusions form first, then shelled FeO·zMnO (z = 0.7–4) inclusions nucleate on the surface of pre-existing 3FeO·MnO. Spherical FeO·zMnO (z = 3–5) is further evolved from shelled 3FeO·MnO by diffusion. Because these MnO-FeO inclusions float up into the slag before degassing, the pre-alloying process does not affect the quality of the melt in the end. Both carbon content and inclusion size conform to industry standards. PMID:29048379

Magnetic spherical cores partly coated with periodic mesoporous organosilica single crystals.

PubMed

Li, Jing; Wei, Yong; Li, Wei; Deng, Yonghui; Zhao, Dongyuan

2012-03-07

Core-shell structured materials are of special significance in various applications. Until now, most reported core-shell structures have polycrystalline or amorphous coatings as their shell layers, with popular morphologies of microspheres or quasi-spheres. However, the single crystals, either mesoscale or atomic ones, are still rarely reported as shell layers. If single crystals can be coated on core materials, it would result in a range of new type core-shell structures with various morphologies, and probably more potential applications. In this work, we demonstrate that periodic mesoporous organosilica (PMO) single crystals can partly grow on magnetic microspheres to form incomplete Fe(3)O(4)@nSiO(2)@PMO core-shell materials in aqueous solution, which indeed is the first illustration that mesoporous single-crystal materials can be used as shell layers for preparation of core-shell materials. The achieved materials have advantages of high specific surface areas, good magnetic responses, embedded functional groups and cubic mesopore channels, which might provide them with various application conveniences. We suppose the partial growth is largely decided by the competition between growing tendency of single crystals and the resistances to this tendency. In principle, other single crystals, including a range of atomic single crystals, such as zeolites, are able to be developed into such core-shell structures.

Surface-engineered core-shell nano-size ferrites and their antimicrobial activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baraliya, Jagdish D., E-mail: jdbaraliya@yahoo.co.in; Joshi, Hiren H., E-mail: jdbaraliya@yahoo.co.in

We report the results of biological study on core-shell structured MFe{sub 2}O{sub 4} (where M = Co, Mn, Ni) nanoparticles and influence of silica- DEG dual coating on their antimicrobial activity. Spherical MFe{sub 2}O{sub 4} nanoparticles were prepared via a Co-precipitation method. The microstructures and morphologies of these nanoparticles were studied by x-ray diffraction and FTIR. The antimicrobial activity study carried out in nutrient agar medium with addition of antimicrobial synthesis compound which is tested for its activity against different types of bacteria.

Viscous forces are predominant in the zona pellucida mechanical resistance

NASA Astrophysics Data System (ADS)

Papi, Massimiliano; Maiorana, Alessandro; Douet, Cécile; Maulucci, Giuseppe; Parasassi, Tiziana; Brunelli, Roberto; Goudet, Ghylène; De Spirito, Marco

2013-01-01

The zona pellucida (ZP) is a multilayer glycoprotein spherical shell surrounding mammalian eggs. The ZP's mechanical response plays a crucial role in mammalian fertilization and is a parameter commonly adopted in "in vitro fertilization" to characterize the oocytes quality. While it is assumed that ZP mechanical response is purely elastic, here we prove that dissipative forces cannot be neglected. Physiologically, this evidence implies that an increase in the spermatozoa motility can induce dramatic changes on the ZP reaction force turning ZP shell in an impenetrable barrier leading to fertility impairments.

Surface-engineered core-shell nano-size ferrites and their antimicrobial activity

NASA Astrophysics Data System (ADS)

Baraliya, Jagdish D.; Joshi, Hiren H.

2014-04-01

We report the results of biological study on core-shell structured MFe2O4 (where M = Co, Mn, Ni) nanoparticles and influence of silica- DEG dual coating on their antimicrobial activity. Spherical MFe2O4 nanoparticles were prepared via a Co-precipitation method. The microstructures and morphologies of these nanoparticles were studied by x-ray diffraction and FTIR. The antimicrobial activity study carried out in nutrient agar medium with addition of antimicrobial synthesis compound which is tested for its activity against different types of bacteria.

Deformable Hollow Periodic Mesoporous Organosilica Nanocapsules for Significantly Improved Cellular Uptake.

PubMed

Teng, Zhaogang; Wang, Chunyan; Tang, Yuxia; Li, Wei; Bao, Lei; Zhang, Xuehua; Su, Xiaodan; Zhang, Fan; Zhang, Junjie; Wang, Shouju; Zhao, Dongyuan; Lu, Guangming

2018-01-31

Mesoporous solids have been widely used in various biomedical areas such as drug delivery and tumor therapy. Although deformability has been recognized as a prime important characteristic influencing cellular uptake, the synthesis of deformable mesoporous solids is still a great challenge. Herein, deformable thioether-, benzene-, and ethane-bridged hollow periodic mesoporous organosilica (HPMO) nanocapsules have successfully been synthesized for the first time by a preferential etching approach. The prepared HPMO nanocapsules possess uniform diameters (240-310 nm), high surface areas (up to 878 m 2 ·g -1 ), well-defined mesopores (2.6-3.2 nm), and large pore volumes (0.33-0.75 m 3 ·g -1 ). Most importantly, the HPMO nanocapsules simultaneously have large hollow cavities (164-270 nm), thin shell thicknesses (20-38 nm), and abundant organic moiety in the shells, which endow a lower Young's modulus (E Y ) of 3.95 MPa than that of solid PMO nanoparticles (251 MPa). The HPMOs with low E Y are intrinsically flexible and deformable in the solution, which has been well-characterized by liquid cell electron microscopy. More interestingly, it is found that the deformable HPMOs can easily enter into human breast cancer MCF-7 cells via a spherical-to-oval morphology change, resulting in a 26-fold enhancement in cellular uptake (43.1% cells internalized with nanocapsules versus 1.65% cells with solid counterparts). The deformable HPMO nanocapsules were further loaded with anticancer drug doxorubicin (DOX), which shows high killing effects for MCF-7 cells, demonstrating the promise for biomedical applications.

Synthesis of raspberry-like monodisperse magnetic hollow hybrid nanospheres by coating polystyrene template with Fe(3)O(4)@SiO(2) particles.

PubMed

Wang, Chunlei; Yan, Juntao; Cui, Xuejun; Wang, Hongyan

2011-02-01

In this paper, we present a novel method for the preparation of raspberry-like monodisperse magnetic hollow hybrid nanospheres with γ-Fe(2)O(3)@SiO(2) particles as the outer shell. PS@Fe(3)O(4)@SiO(2) composite nanoparticles were successfully prepared on the principle of the electrostatic interaction between negatively charged silica and positively charged polystyrene, and then raspberry-like magnetic hollow hybrid nanospheres with large cavities were achieved by means of calcinations, simultaneously, the magnetite (Fe(3)O(4)) was transformed into maghemite (γ-Fe(2)O(3)). Transmission electron microscopy (TEM) demonstrated that the obtained magnetic hollow silica nanospheres with the perfect spherical profile were well monodisperse and uniform with the mean size of 253nm. The Fourier transform infrared (FTIR) spectrometry, energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) provided the sufficient evidences for the presence of Fe(3)O(4) in the silica shell. Moreover, the magnetic hollow silica nanospheres possessed a characteristic of superparamagnetic with saturation magnetization value of about 7.84emu/g by the magnetization curve measurement. In addition, the nitrogen adsorption-desorption measurement exhibited that the pore size, BET surface area, pore volume of magnetic hollow silica nanospheres were 3.5-5.5nm, 307m(2)g(-1) and 1.33cm(3)g(-1), respectively. Therefore, the magnetic hollow nanospheres possess a promising future in controlled drug delivery and targeted drug applications. Copyright © 2010 Elsevier Inc. All rights reserved.

Asymmetric-shell ignition capsule design to tune the low-mode asymmetry during the peak drive

NASA Astrophysics Data System (ADS)

Gu, Jianfa; Dai, Zhensheng; Song, Peng; Zou, Shiyang; Ye, Wenhua; Zheng, Wudi; Gu, Peijun; Wang, Jianguo; Zhu, Shaoping

2016-08-01

The low-mode radiation flux asymmetry in the hohlraum is a main source of performance degradation in the National Ignition Facility (NIF) implosion experiments. To counteract the deleterious effects of the large positive P2 flux asymmetry during the peak drive, this paper develops a new tuning method called asymmetric-shell ignition capsule design which adopts the intentionally asymmetric CH ablator layer or deuterium-tritium (DT) ice layer. A series of two-dimensional implosion simulations have been performed, and the results show that the intentionally asymmetric DT ice layer can significantly improve the fuel ρR symmetry, hot spot shape, hot spot internal energy, and the final neutron yield compared to the spherical capsule. This indicates that the DT asymmetric-shell capsule design is an effective tuning method, while the CH ablator asymmetric-shell capsule could not correct the fuel ρR asymmetry, and it is not as effective as the DT asymmetric-shell capsule design.

Asymmetric-shell ignition capsule design to tune the low-mode asymmetry during the peak drive

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gu, Jianfa, E-mail: gu-jianfa@iapcm.ac.cn; Dai, Zhensheng, E-mail: dai-zhensheng@iapcm.ac.cn; Song, Peng

2016-08-15

The low-mode radiation flux asymmetry in the hohlraum is a main source of performance degradation in the National Ignition Facility (NIF) implosion experiments. To counteract the deleterious effects of the large positive P2 flux asymmetry during the peak drive, this paper develops a new tuning method called asymmetric-shell ignition capsule design which adopts the intentionally asymmetric CH ablator layer or deuterium-tritium (DT) ice layer. A series of two-dimensional implosion simulations have been performed, and the results show that the intentionally asymmetric DT ice layer can significantly improve the fuel ρR symmetry, hot spot shape, hot spot internal energy, and themore » final neutron yield compared to the spherical capsule. This indicates that the DT asymmetric-shell capsule design is an effective tuning method, while the CH ablator asymmetric-shell capsule could not correct the fuel ρR asymmetry, and it is not as effective as the DT asymmetric-shell capsule design.« less

Core-shell biopolymer nanoparticle delivery systems: synthesis and characterization of curcumin fortified zein-pectin nanoparticles.

PubMed

Hu, Kun; Huang, Xiaoxia; Gao, Yongqing; Huang, Xulin; Xiao, Hang; McClements, David Julian

2015-09-01

Biopolymer core-shell nanoparticles were fabricated using a hydrophobic protein (zein) as the core and a hydrophilic polysaccharide (pectin) as the shell. Particles were prepared by coating cationic zein nanoparticles with anionic pectin molecules using electrostatic deposition (pH 4). The core-shell nanoparticles were fortified with curcumin (a hydrophobic bioactive molecule) at a high loading efficiency (>86%). The resulting nanoparticles were spherical, relatively small (diameter ≈ 250 nm), and had a narrow size distribution (polydispersity index ≈ 0.24). The encapsulated curcumin was in an amorphous (rather than crystalline form) as detected by differential scanning calorimetry (DSC). Fourier transform infrared (FTIR) and Raman spectra indicated that the encapsulated curcumin interacted with zein mainly through hydrophobic interactions. The nanoparticles were converted into a powdered form that had good water-dispersibility. These core-shell biopolymer nanoparticles could be useful for incorporating curcumin into functional foods and beverages, as well as dietary supplements and pharmaceutical products. Copyright © 2015 Elsevier Ltd. All rights reserved.

DNA nanoparticles with core-shell morphology.

PubMed

Chandran, Preethi L; Dimitriadis, Emilios K; Lisziewicz, Julianna; Speransky, Vlad; Horkay, Ferenc

2014-10-14

Mannobiose-modified polyethylenimines (PEI) are used in gene therapy to generate nanoparticles of DNA that can be targeted to the antigen-presenting cells of the immune system. We report that the sugar modification alters the DNA organization within the nanoparticles from homogenous to shell-like packing. The depth-dependent packing of DNA within the nanoparticles was probed using AFM nano-indentation. Unmodified PEI-DNA nanoparticles display linear elastic properties and depth-independent mechanics, characteristic of homogenous materials. Mannobiose-modified nanoparticles, however, showed distinct force regimes that were dependent on indentation depth, with 'buckling'-like response that is reproducible and not due to particle failure. By comparison with theoretical studies of spherical shell mechanics, the structure of mannobiosylated particles was deduced to be a thin shell with wall thickness in the order of few nanometers, and a fluid-filled core. The shell-core structure is also consistent with observations of nanoparticle denting in altered solution conditions, with measurements of nanoparticle water content from AFM images, and with images of DNA distribution in Transmission Electron Microscopy.

Analytical and experimental studies of natural vibrations modes of ring-stiffened truncated-cone shells with variable theoretical ring fixity

NASA Technical Reports Server (NTRS)

Naumann, E. C.; Catherines, D. S.; Walton, W. C., Jr.

1971-01-01

Experimental and analytical investigations of the vibratory behavior of ring-stiffened truncated-cone shells are described. Vibration tests were conducted on 60 deg conical shells having up to four ring stiffeners and for free-free and clamped-free edge constraints and 9 deg conical shells, for two thicknesses, each with two angle rings and for free-free, free-clamped, and clamped-clamped edge constraints. The analytical method is based on linear thin shell theory, employing the Rayleigh-Ritz method. Discrete rings are represented as composed of one or more segments, each of which is a short truncated-cone shell of uniform thickness. Equations of constraint are used to join a ring and shell along a circumferential line connection. Excellent agreement was obtained for comparisons of experimental and calculated frequencies.

Sound Transmission through a Cylindrical Sandwich Shell with Honeycomb Core

NASA Technical Reports Server (NTRS)

Tang, Yvette Y.; Robinson, Jay H.; Silcox, Richard J.

1996-01-01

Sound transmission through an infinite cylindrical sandwich shell is studied in the context of the transmission of airborne sound into aircraft interiors. The cylindrical shell is immersed in fluid media and excited by an oblique incident plane sound wave. The internal and external fluids are different and there is uniform airflow in the external fluid medium. An explicit expression of transmission loss is derived in terms of modal impedance of the fluids and the shell. The results show the effects of (a) the incident angles of the plane wave; (b) the flight conditions of Mach number and altitude of the aircraft; (c) the ratios between the core thickness and the total thickness of the shell; and (d) the structural loss factors on the transmission loss. Comparisons of the transmission loss are made among different shell constructions and different shell theories.

Simple and efficient synthesis of copper(II)-modified uniform magnetic Fe3O4@SiO2 core/shell microspheres for immobilization of cellulase

NASA Astrophysics Data System (ADS)

Li, Shi-Kuo; Hou, Xiao-Cheng; Huang, Fang-Zhi; Li, Chuan-Hao; Kang, Wen-Juan; Xie, An-Jian; Shen, Yu-Hua

2013-11-01

In this paper, we reported a simple and efficient protocol for preparation of Cu2+-modified magnetic Fe3O4@SiO2 core/shell microspheres for immobilization of cellulase. The uniform magnetic Fe3O4@SiO2 core/shell microspheres with a thin shell of 20 nm were synthesized through a solvothermal method followed by a sol-gel process. An amino-terminated silane coupling agent of (3-aminopropyl)triethoxysilane (APTS) was then grafted on them for capturing Cu2+ ions. The reaction process is very simple, efficient, and economical. Noticeably, the content of Cu2+ ions on the magnetic core/shell microspheres can reach 4.6 Wt%, endowing them possess as high immobilization capacity as 225.5 mg/g for cellulase. And the immobilized cellulase can be retained over 90 % on the magnetic microspheres after six cycles. Meanwhile, the magnetic microspheres decorated with Cu2+ ions show a superparamagnetic character with a high magnetic saturation of 58.5 emu/g at room temperature, suggesting conveniently and rapidly recycle the enzyme from solution. This facile, recyclable, high immobilization capacity and activity strategy may find potential applications in enzyme catalytic reactions with low cost.

Core-shell-structured nanothermites synthesized by atomic layer deposition

NASA Astrophysics Data System (ADS)

Qin, Lijun; Gong, Ting; Hao, Haixia; Wang, Keyong; Feng, Hao

2013-12-01

Thermite materials feature very exothermic solid-state redox reactions. However, the energy release rates of traditional thermite mixtures are limited by the reactant diffusion velocities. In this work, atomic layer deposition (ALD) is utilized to synthesize thermite materials with greatly enhanced reaction rates. By depositing certain types of metal oxides (oxidizers) onto a commercial Al nanopowder, core-shell-structured nanothermites can be produced. The average film deposition rate on the Al nanopowder is 0.17 nm/cycle for ZnO and 0.031 nm/cycle for SnO2. The thickness of the oxidizer layer can be precisely controlled by adjusting the ALD cycle number. The compositions, morphologies, and structures of the ALD nanothermites are characterized by X-ray photoelectron spectroscopy, scanning electron microscopy, and high-resolution transmission electron microscopy. The characterization results reveal nearly perfect coverage of the Al nanoparticles by uniform ALD oxidizer layers and confirm the formation of core-shell nanoparticles. Combustion properties of the nanothermites are probed by laser ignition technique. Reactions of the core-shell-structured nanothermites are several times faster than the mixture of nanopowders. The promoted reaction rate is mostly attributed to the uniform distribution of reactants on the nanometer scale. These core-shell-structured nanothermites provide a potential pathway to control and enhance thermite reactions.

The crack problem in a specially orthotropic shell with double curvature

NASA Technical Reports Server (NTRS)

Delale, F.; Erdogan, F.

1983-01-01

The crack problem of a shallow shell with two nonzero curvatures is considered. It is assumed that the crack lies in one of the principal planes of curvature and the shell is under Mode I loading condition. The material is assumed to be specially orthotropic. After giving the general formulation of the problem the asymptotic behavior of the stress state around the crack tip is examined. The analysis is based on Reissner's transverse shear theory. Thus, as in the bending of cracked plates, the asymptotic results are shown to be consistent with that obtained from the plane elasticity solution of crack problems. Rather extensive numerical results are obtained which show the effect of material orthotropy on the stress intensity factors in cylindrical and spherical shells and in shells with double curvature. Other results include the stress intensity factors in isotropic toroidal shells with positive or negative curvature ratio, the distribution of the membrane stress resultant outside the crack, and the influence of the material orthotropy on the angular distribution of the stresses around the crack tip. Previously announced in STAR as N83-16782

The crack problem in a specially orthotropic shell with double curvature

NASA Technical Reports Server (NTRS)

Delale, F.; Erdogan, F.

1982-01-01

The crack problem of a shallow shell with two nonzero curvatures is considered. It is assumed that the crack lies in one of the principal planes of curvature and the shell is under Mode I loading condition. The material is assumed to be specially orthotropic. After giving the general formulation of the problem the asymptotic behavior of the stress state around the crack tip is examined. The analysis is based on Reissner's transverse shear theory. Thus, as in the bending of cracked plates, the asymptotic results are shown to be consistent with that obtained from the plane elasticity solution of crack problems. Rather extensive numerical results are obtained which show the effect of material orthotropy on the stress intensity factors in cylindrical and spherical shells and in shells with double curvature. Other results include the stress intensity factors in isotropic toroidal shells with positive or negative curvature ratio, the distribution of the membrane stress resultant outside the crack, and the influence of the material orthotropy on the angular distribution of the stresses around the crack tip.

Elastic field of a spherical inclusion with non-uniform eigenfields in second strain gradient elasticity

NASA Astrophysics Data System (ADS)

Delfani, M. R.; Latifi Shahandashti, M.

2017-09-01

In this paper, within the complete form of Mindlin's second strain gradient theory, the elastic field of an isolated spherical inclusion embedded in an infinitely extended homogeneous isotropic medium due to a non-uniform distribution of eigenfields is determined. These eigenfields, in addition to eigenstrain, comprise eigen double and eigen triple strains. After the derivation of a closed-form expression for Green's function associated with the problem, two different cases of non-uniform distribution of the eigenfields are considered as follows: (i) radial distribution, i.e. the distributions of the eigenfields are functions of only the radial distance of points from the centre of inclusion, and (ii) polynomial distribution, i.e. the distributions of the eigenfields are polynomial functions in the Cartesian coordinates of points. While the obtained solution for the elastic field of the latter case takes the form of an infinite series, the solution to the former case is represented in a closed form. Moreover, Eshelby's tensors associated with the two mentioned cases are obtained.

Rectangular Shell Plating Under Uniformly Distributed Hydrostatic Pressure

NASA Technical Reports Server (NTRS)

Neubert, M; Sommer, A

1940-01-01

A check of the calculation methods used by Foppl and Henky for investigating the reliability of shell plating under hydrostatic pressure has proved that the formulas yield practical results within the elastic range of the material. Foppl's approximate calculation leaves one on the safe side. It further was found on the basis of the marked ductility of the shell plating under tensile stress that the strength is from 50 to 100 percent higher in the elastic range than expected by either method.

Fabrication and characterization of millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Haoting; Liao, Qilong, E-mail: liaoqilong@swust.edu.cn; Dai, Yunya

2016-04-15

Highlights: • Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} hollow spheres have been prepared. • The diameters of the prepared hollow spheres are 500–1300μm. • The degree of sphericity for the prepared hollow spheres is above 98%. • The mechanisms of transparency are discussed. - Abstract: Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres have been successfully prepared using the oil-in-water (paraffin-in-alumina sol) droplets as precursors made by self-made T-shape micro-emulsion device. The main crystalline phase of the obtained hollow sphere is alpha alumina. The prepared translucent La{sub 2}O{sub 3}-containing Al{sub 2}O{sub 3} ceramic hollow spheresmore » have diameters of 500–1300 μm, wall thickness of about 23 μm and the degree of sphericity of above 98%. With the increase of the La{sub 2}O{sub 3} content, grains and grain-boundaries of the alumina spherical shell for the prepared millimeter-scale hollow spheres become regular and clear gradually. When the La{sub 2}O{sub 3} content is 0.1 wt.%, the crystal surface of the obtained Al{sub 2}O{sub 3} spherical shell shows optimal grains and few pores, and its transmittance reaches 42% at 532 nm laser light. This method provides a promising technique of preparing millimeter-scale translucent ceramic hollow spheres for laser inertial confined fusion.« less

Plastic buckling. [post-bifurcation and imperfection sensitivity

NASA Technical Reports Server (NTRS)

Hutchinson, J. W.

1974-01-01

The present article is concerned mainly with the post-bifurcation and imperfection-sensitivity aspects of plastic buckling. A simple two-degree-of-freedom model is used to introduce post-bifurcation behavior and a second model illustrates features of the behavior of continuous solids and structures. Hill's bifurcation criterion for a class of three-dimensional solids is applied to the Donnell-Mushtari-Vlasov (DMV) theory of plates and shells. A general treatment of the initial post-bifurcation behavior of plates and shells is given within the context of the DMV theory. This is illustrated by problems involving columns and circular plates under radial compression. Numerical results are given for a column under axial compression, a circular plate under radial compression, and spherical and cylindrical shells.

A comparative photophysicochemical study of phthalocyanines encapsulated in core-shell silica nanoparticles.

PubMed

Fashina, Adedayo; Amuhaya, Edith; Nyokong, Tebello

2015-02-25

This work presents the synthesis and characterization of a new zinc phthalocyanine complex tetrasubstituted with 3-carboxyphenoxy in the peripheral position. The photophysical properties of the new complex are compared with those of phthalocyanines tetra substituted with 3-carboxyphenoxy or 4-carboxyphenoxy at non-peripheral positions. Three phthalocyanine complexes were encapsulated within silica matrix to form a core shell and the hybrid nanoparticles particles obtained were spherical and mono dispersed. When encapsulated within the silica shell nanoparticles, phthalocyanines showed improved triplet quantum yields and singlet oxygen quantum yields than surface grafted derivatives. The improvements observed could be attributed to the protection provided for the phthalocyanine complexes by the silica matrix. Copyright © 2014 Elsevier B.V. All rights reserved.

Hierarchically assembled theranostic nanostructures for siRNA delivery and imaging applications.

PubMed

Shrestha, Ritu; Elsabahy, Mahmoud; Luehmann, Hannah; Samarajeewa, Sandani; Florez-Malaver, Stephanie; Lee, Nam S; Welch, Michael J; Liu, Yongjian; Wooley, Karen L

2012-10-24

Dual functional hierarchically assembled nanostructures, with two unique functions of carrying therapeutic cargo electrostatically and maintaining radiolabeled imaging agents covalently within separate component building blocks, have been developed via the supramolecular assembly of several spherical cationic shell cross-linked nanoparticles clustered around a central anionic shell cross-linked cylinder. The shells of the cationic nanoparticles and the hydrophobic core domain of the anionic central cylindrical nanostructure of the assemblies were utilized to complex negatively charged nucleic acids (siRNA) and to undergo radiolabeling, respectively, for potential theranostic applications. The assemblies exhibited exceptional cell transfection and radiolabeling efficiencies, providing an overall advantage over the individual components, which could each facilitate only one or the other of the functions.

HI emission from the red giant Y CVn with the VLA and FAST

NASA Astrophysics Data System (ADS)

Hoai, Do T.; Nhung, Pham T.; Matthews, Lynn D.; Gérard, Eric; Le Bertre, Thibaut

2017-07-01

Imaging studies with the Very Large Array (VLA) have revealed HI emission associated with the extended circumstellar shells of red giants. We analyze the spectral map obtained on Y CVn, a J-type carbon star on the Asymptotic Giant Branch. The HI line profiles can be interpreted with a model of a detached shell resulting from the interaction of a stellar outflow with the local interstellar medium. We reproduce the spectral map by introducing a distortion along a direction corresponding to the star’s motion in space. We then use this fitting to simulate observations expected from the Five-hundred-meter Aperture Spherical radio Telescope (FAST), and discuss its potential for improving our description of the outer regions of circumstellar shells.

In-flight performance of the Faint Object Camera of the Hubble Space Telescope

NASA Technical Reports Server (NTRS)

Greenfield, P.; Paresce, F.; Baxter, D.; Hodge, P.; Hook, R.; Jakobsen, P.; Jedrzejewski, R.; Nota, A.; Sparks, W. B.; Towers, N.

1991-01-01

An overview of the Faint Object Camera and its performance to date is presented. In particular, the detector's efficiency, the spatial uniformity of response, distortion characteristics, detector and sky background, detector linearity, spectrography, and operation are discussed. The effect of the severe spherical aberration of the telescope's primary mirror on the camera's point spread function is reviewed, as well as the impact it has on the camera's general performance. The scientific implications of the performance and the spherical aberration are outlined, with emphasis on possible remedies for spherical aberration, hardware remedies, and stellar population studies.

Synthesis of fly ash based core-shell composites for use as functional pigment in paints

NASA Astrophysics Data System (ADS)

Sharma, Richa; Tiwari, Sangeeta

2016-04-01

Fly ash is a combustion residue, mainly composed of silica, alumina and iron oxides. It is produced by the power industries in very large amounts and usually disposed in landfills, which have represented an environmental problem in recent years1. The need to generate a market for fly ash consumption is the main reason why alternative applications have been studied. It has been applied as an additive in construction materials like cement and pavements2. The present work describes the synthesis of Flyash-Titania core-shell particles by precipitation technique using Titanium tetra isopropoxide (TTIP) which can be used for variety of applications such as NIR reflecting materials for cool coatings, Photocatalysis etc. In this work, Fly ash is used in core and Nano -TiO2 is coated as shell on it. Surfactants are used to improve the adhesion of Nano Titania shell on fly ash core. Effect on adhesion of TiO2 on Fly ash is studied by using different types of surfactant. The preparation of core shells was carried out in absence of surfactant as well as using anionic and non-ionic surfactants. The percentage of surfactant was varied to study the effect of amount of surfactant on the uniformity and size of particles in the shell using Kubelka-Munk transformed reflectance spectra. The morphology of core shell structures was studied using SEM technique. Use of anionic surfactant results in more uniform coating with reduced particle size of the shell material. The composite particles prepared by using anionic surfactant are having good pigment properties and also shows good reflectance in Near Infrared region and hence can be used as a pigment in cool coatings.

ZnO/ZnSxSe1-x core/shell nanowire arrays as photoelectrodes with efficient visible light absorption

NASA Astrophysics Data System (ADS)

Wang, Zhenxing; Zhan, Xueying; Wang, Yajun; Safdar, Muhammad; Niu, Mutong; Zhang, Jinping; Huang, Ying; He, Jun

2012-08-01

ZnO/ZnSxSe1-x core/shell nanowires have been synthesized on n+-type silicon substrate via a two-step chemical vapor deposition method. Transmission electron microscopy reveals that ZnSxSe1-x can be deposited on the entire surface of ZnO nanowire, forming coaxial heterojunction along ZnO nanowire with very smooth shell surface and high shell thickness uniformity. The photoelectrode after deposition of the ternary alloy shell significantly improves visible light absorption efficiency. Electrochemical impedance spectroscopy results explicitly indicate that the introduction of ZnSxSe1-x shell to ZnO nanowires effectively improves the photogenerated charge separation process. Our finding opens up an efficient means for achieving high efficient energy conversion devices.

IRAS observations of R Coronae Borealis - Detection and study of a fossil shell

NASA Technical Reports Server (NTRS)

Gillett, F. C.; Backman, D. E.; Beichman, C.; Neugebauer, G.

1986-01-01

IRAS observations of the extreme hydrogen-deficient supergiant R CrB are presented and discussed. The star is surrounded by an enormous cool dust cloud which is tentatively identified as a fossil remnant of the hydrogen-rich envelope of the star. The angular extent of the emission corresponds to a linear extent of 8 pc, 20 times larger than the largest previously known shell around a late-type star. The radiating material is distributed very symmetrically over a wide range of radial distances from the star. The dust temperature is nearly constant throughout the extended shell. The total mass in the shell is about 0.3 solar mass. The ejection process appears to have occurred in a spherically symmetric fashion with a nearly constant mass loss rate and expansion velocity over a period of about 150,000 yr, terminating about 26,000 yr ago.

Thermochromic microcapsules with highly transparent shells obtained through in-situ polymerization of urea formaldehyde around thermochromic cores for smart wood coatings.

PubMed

Zhu, Xiaodong; Liu, Yu; Li, Zhao; Wang, Weicong

2018-03-05

In this paper, thermochromic microcapsules were synthesized in situ polymerization with urea formaldehyde as shell material and thermochromic compounds as core material. The effects of emulsifying agent and conditions on surface morphology and particle size of microcapsules were studied. It was found that the size and surface morphology of microcapsules were strongly depending on stirring rate and the ratio of core to shell. The stable and small size spherical microcapsules with excellent transparency can be obtained at an emulsifying agent to core to shell ratio as 1:5:7.5 under mechanical stirring at 12 krpm for 15 min. Finally, the thermochromic property was discussed by loading microcapsules in wood and wood coatings. Results indicate that microcapsules can realize the thermochromic property while incorporated with wood and coatings, and could have high potential in smart material fabrication.

Nonlinear problems of the theory of heterogeneous slightly curved shells

NASA Technical Reports Server (NTRS)

Kantor, B. Y.

1973-01-01

An account if given of the variational method of the solution of physically and geometrically nonlinear problems of the theory of heterogeneous slightly curved shells. Examined are the bending and supercritical behavior of plates and conical and spherical cupolas of variable thickness in a temperature field, taking into account the dependence of the elastic parameters on temperature. The bending, stability in general and load-bearing capacity of flexible isotropic elastic-plastic shells with different criteria of plasticity, taking into account compressibility and hardening. The effect of the plastic heterogeneity caused by heat treatment, surface work hardening and irradiation by fast neutron flux is investigated. Some problems of the dynamic behavior of flexible shells are solved. Calculations are performed in high approximations. Considerable attention is given to the construction of a machine algorithm and to the checking of the convergence of iterative processes.

A platonic solid templating Archimedean solid: an unprecedented nanometre-sized Ag37 cluster

NASA Astrophysics Data System (ADS)

Li, Xiao-Yu; Su, Hai-Feng; Yu, Kai; Tan, Yuan-Zhi; Wang, Xing-Po; Zhao, Ya-Qin; Sun, Di; Zheng, Lan-Sun

2015-04-01

The spontaneous formation of discrete spherical nanosized molecules is prevalent in nature, but the authentic structural mimicry of such highly symmetric polyhedra from edge sharing of regular polygons has remained elusive. Here we present a novel ball-shaped {(HNEt3)[Ag37S4(SC6H4tBu)24(CF3COO)6(H2O)12]} cluster (1) that is assembled via a one-pot process from polymeric {(HNEt3)2[Ag10(SC6H4tBu)12]}n and CF3COOAg. Single crystal X-ray analysis confirmed that 1 is a Td symmetric spherical molecule with a [Ag36(SC6H4tBu)24] anion shell enwrapping a AgS4 tetrahedron. The shell topology of 1 belongs to one of 13 Archimedean solids, a truncated tetrahedron with four edge-shared hexagons and trigons, which are supported by a AgS4 Platonic solid in the core. Interestingly, the cluster emits green luminescence centered at 515 nm at room temperature. Our investigations have provided a promising synthetic protocol for a high-nuclearity silver cluster based on underlying geometrical principles.The spontaneous formation of discrete spherical nanosized molecules is prevalent in nature, but the authentic structural mimicry of such highly symmetric polyhedra from edge sharing of regular polygons has remained elusive. Here we present a novel ball-shaped {(HNEt3)[Ag37S4(SC6H4tBu)24(CF3COO)6(H2O)12]} cluster (1) that is assembled via a one-pot process from polymeric {(HNEt3)2[Ag10(SC6H4tBu)12]}n and CF3COOAg. Single crystal X-ray analysis confirmed that 1 is a Td symmetric spherical molecule with a [Ag36(SC6H4tBu)24] anion shell enwrapping a AgS4 tetrahedron. The shell topology of 1 belongs to one of 13 Archimedean solids, a truncated tetrahedron with four edge-shared hexagons and trigons, which are supported by a AgS4 Platonic solid in the core. Interestingly, the cluster emits green luminescence centered at 515 nm at room temperature. Our investigations have provided a promising synthetic protocol for a high-nuclearity silver cluster based on underlying geometrical principles. Electronic supplementary information (ESI) available: detailed synthesis procedure, tables, crystal data in CIF files, IR data, TGA results and powder X-ray diffractogram for 1. CCDC 1042228. See DOI: 10.1039/c5nr01222h

The Geophysical Fluid Flow Cell Experiment

NASA Technical Reports Server (NTRS)

Hart, J. E.; Ohlsen, D.; Kittleman, S.; Borhani, N.; Leslie, F.; Miller, T.

1999-01-01

The Geophysical Fluid Flow Cell (GFFC) experiment performed visualizations of thermal convection in a rotating differentially heated spherical shell of fluid. In these experiments dielectric polarization forces are used to generate a radially directed buoyancy force. This enables the laboratory simulation of a number of geophysically and astrophysically important situations in which sphericity and rotation both impose strong constraints on global scale fluid motions. During USML-2 a large set of experiments with spherically symmetric heating were carried out. These enabled the determination of critical points for the transition to various forms of nonaxisymmetric convection and, for highly turbulent flows, the transition latitudes separating the different modes of motion. This paper presents a first analysis of these experiments as well as data on the general performance of the instrument during the USML-2 flight.

Electrons on a spherical surface: Physical properties and hollow spherical clusters

NASA Astrophysics Data System (ADS)

Cricchio, Dario; Fiordilino, Emilio; Persico, Franco

2012-07-01

We discuss the physical properties of a noninteracting electron gas constrained to a spherical surface. In particular we consider its chemical potentials, its ionization potential, and its electric static polarizability. All these properties are discussed analytically as functions of the number N of electrons. The trends obtained with increasing N are compared with those of the corresponding properties experimentally measured or theoretically evaluated for quasispherical hollow atomic and molecular clusters. Most of the properties investigated display similar trends, characterized by a prominence of shell effects. This leads to the definition of a scale-invariant distribution of magic numbers which follows a power law with critical exponent -0.5. We conclude that our completely mechanistic and analytically tractable model can be useful for the analysis of self-assembling complex systems.

Novel nanometer-level uniform amorphous carbon coating for boron powders by direct pyrolysis of coronene without solvent.

PubMed

Ye, ShuJun; Song, MingHui; Kumakura, Hiroaki

2015-01-30

A 3 nm coronene coating and a 4 nm amorphous carbon coating with a uniform shell-core encapsulation structure for nanosized boron (B) powders are formed by a simple process in which coronene is directly mixed with boron particles without a solvent and heated at 520 °C for 1 h or at 630 °C for 3 h in a vacuum-sealed silica tube. Coronene has a melting point lower than its decomposition temperature, which enables liquid coronene to cover B particles by liquid diffusion and penetration without the need for a solvent. The diffusion and penetration of coronene can extend to the boundaries of particles and to inside the agglomerated nanoparticles to form a complete shell-core encapsulated structure. As the temperature is increased, thermal decomposition of coronene on the B particles results in the formation of a uniform amorphous carbon coating layer. This novel and simple nanometer-level uniform amorphous carbon coating method can possibly be applied to many other powders; thus, it has potential applications in many fields at low cost.

Dynamics of a suspension of interacting yolk-shell particles

DOE PAGES

Sánchez Díaz, L. E.; Cortes-Morales, E. C.; Li, X.; ...

2014-12-01

In this work we study the self-diusion properties of a liquid of hollow spherical particles (shells) bearing a smaller solid sphere in their interior (yolks). We model this system using purely repulsive hard-body interactions between all (shell and yolk) particles, but assume the presence of a background ideal solvent such that all the particles execute free Brownian motion between collisions, characterized by short-time self-diusion coecients D0 s for the shells and D0 y for the yolks. Using a softened version of these interparticle potentials we perform Brownian dynamics simulations to determine the mean squared displacement and intermediate scattering function ofmore » the yolk-shell complex. These results can be understood in terms of a set of eective Langevin equations for the N interacting shell particles, pre-averaged over the yolks' degrees of freedom, from which an approximate self-consistent description of the simulated self-diusion properties can be derived. Here we compare the theoretical and simulated results between them, and with the results for the same system in the absence of yolks. We nd that the yolks, which have no eect on the shell-shell static structure, in uence the dynamic properties in a predictable manner, fully captured by the theory.« less

Transformation of a Finite-Element Model of a Piezoelectric Spherical Shell Transducer from a Nodal to a Spherical Harmonic Function Representation

DTIC Science & Technology

1990-06-01

J) :(270, )..pTod( 301,j)s(331,j)- pcod (302.j) s(271,j)-prod(303,J)s(332,j ):prod(304,J) s(272,J) prod(305,i) s(333,j) prod(306,j) s(273,jJ.’ptod(307...j).prodf 335,J) sf348, j)-prod( 336.1) 9(288,j)-prod(337,J) of 349, j)- pcod ( 338,J) s(209, j)-prod(339,J) of 350,j)-prod( 340,J) s(290,jJ.. pCod (341,J

Apparatus for controlling molten core debris

DOEpatents

Golden, Martin P. [Trafford, PA; Tilbrook, Roger W. [Monroeville, PA; Heylmun, Neal F. [Pittsburgh, PA

1977-07-19

Apparatus for containing, cooling, diluting, dispersing and maintaining subcritical the molten core debris assumed to melt through the bottom of a nuclear reactor pressure vessel in the unlikely event of a core meltdown. The apparatus is basically a sacrificial bed system which includes an inverted conical funnel, a core debris receptacle including a spherical dome, a spherically layered bed of primarily magnesia bricks, a cooling system of zig-zag piping in graphite blocks about and below the bed and a cylindrical liner surrounding the graphite blocks including a steel shell surrounded by firebrick. Tantalum absorber rods are used in the receptacle and bed.

Regular and chaotic dynamics of non-spherical bodies. Zeldovich's pancakes and emission of very long gravitational waves

NASA Astrophysics Data System (ADS)

Bisnovatyi-Kogan, G. S.; Tsupko, O. Yu.

2015-10-01

> In this paper we review a recently developed approximate method for investigation of dynamics of compressible ellipsoidal figures. Collapse and subsequent behaviour are described by a system of ordinary differential equations for time evolution of semi-axes of a uniformly rotating, three-axis, uniform-density ellipsoid. First, we apply this approach to investigate dynamic stability of non-spherical bodies. We solve the equations that describe, in a simplified way, the Newtonian dynamics of a self-gravitating non-rotating spheroidal body. We find that, after loss of stability, a contraction to a singularity occurs only in a pure spherical collapse, and deviations from spherical symmetry prevent the contraction to the singularity through a stabilizing action of nonlinear non-spherical oscillations. The development of instability leads to the formation of a regularly or chaotically oscillating body, in which dynamical motion prevents the formation of the singularity. We find regions of chaotic and regular pulsations by constructing a Poincaré diagram. A real collapse occurs after damping of the oscillations because of energy losses, shock wave formation or viscosity. We use our approach to investigate approximately the first stages of collapse during the large scale structure formation. The theory of this process started from ideas of Ya. B. Zeldovich, concerning the formation of strongly non-spherical structures during nonlinear stages of the development of gravitational instability, known as `Zeldovich's pancakes'. In this paper the collapse of non-collisional dark matter and the formation of pancake structures are investigated approximately. Violent relaxation, mass and angular momentum losses are taken into account phenomenologically. We estimate an emission of very long gravitational waves during the collapse, and discuss the possibility of gravitational lensing and polarization of the cosmic microwave background by these waves.

On the Effective Thermal Conductivity of Porous Packed Beds with Uniform Spherical Particles

NASA Technical Reports Server (NTRS)

Kandula, Max

2010-01-01

Point contact models for the effective thermal conductivity of porous media with uniform spherical inclusions have been briefly reviewed. The model of Zehner and Schlunder (1970) has been further validated with recent experimental data over a broad range of conductivity ratio from 8 to 1200 and over a range of solids fraction up to about 0.8. The comparisons further confirm the validity of Zehner-Schlunder model, known to be applicable for conductivity ratios less than about 2000, above which area contact between the particles becomes significant. This validation of the Zehner-Schlunder model has implications for its use in the prediction of the effective thermal conductivity of water frost (with conductivity ratio around 100) which arises in many important areas of technology.

Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties.

PubMed

Siddiq, Abdur R; Kennedy, Andrew R

2015-02-01

Porous PEEK structures with approximately 85% open porosity have been made using PEEK-OPTIMA® powder and a particulate leaching technique using porous, near-spherical, sodium chloride beads. A novel manufacturing approach is presented and compared with a traditional dry mixing method. Irrespective of the method used, the use of near-spherical beads with a fairly narrow size range results in uniform pore structures. However the integration, by tapping, of fine PEEK into a pre-existing network salt beads, followed by compaction and "sintering", produces porous structures with excellent repeatability and homogeneity of density; more uniform pore and strut sizes; an improved and predictable level of connectivity via the formation of "windows" between the cells; faster salt removal rates and lower levels of residual salt. Although tapped samples show a compressive yield stress >1 MPa and stiffness >30 MPa for samples with 84% porosity, the presence of windows in the cell walls means that tapped structures show lower strengths and lower stiffnesses than equivalent structures made by mixing. Copyright © 2014 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Paviter; Kaur, Manpreet; Singh, Bikramjeet

Boron-carbon core shell structures have been synthesized by solvo-thermal synthesis route. The synthesized material is highly pure. X-ray diffraction analysis confirms the reduction of reactants in to boron and carbon. Scanning Electron Microscopy (SEM) analysis showed that the shell is uniform with average thickness of 340 nm. Photo luminescence studies showed that the material is blue light emitting with CIE color coordinates: x=0.16085, y=0.07554.

Precisely Size-Tunable Monodisperse Hairy Plasmonic Nanoparticles via Amphiphilic Star-Like Block Copolymers.

PubMed

Chen, Yihuang; Yoon, Young Jun; Pang, Xinchang; He, Yanjie; Jung, Jaehan; Feng, Chaowei; Zhang, Guangzhao; Lin, Zhiqun

2016-12-01

In situ precision synthesis of monodisperse hairy plasmonic nanoparticles with tailored dimensions and compositions by capitalizing on amphiphilic star-like diblock copolymers as nanoreactors are reported. Such hairy plasmonic nanoparticles comprise uniform noble metal nanoparticles intimately and perpetually capped by hydrophobic polymer chains (i.e., "hairs") with even length. Interestingly, amphiphilic star-like diblock copolymer nanoreactors retain the spherical shape under reaction conditions, and the diameter of the resulting plasmonic nanoparticles and the thickness of polymer chains situated on the surface of the nanoparticle can be readily and precisely tailored. These hairy nanoparticles can be regarded as hard/soft core/shell nanoparticles. Notably, the polymer "hairs" are directly and permanently tethered to the noble metal nanoparticle surface, thereby preventing the aggregation of nanoparticles and rendering their dissolution in nonpolar solvents and the homogeneous distribution in polymer matrices with long-term stability. This amphiphilic star-like block copolymer nanoreactor-based strategy is viable and robust and conceptually enables the design and synthesis of a rich variety of hairy functional nanoparticles with new horizons for fundamental research on self-assembly and technological applications in plasmonics, catalysis, energy conversion and storage, bioimaging, and biosensors. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Nanoformulation of Brain-Derived Neurotrophic Factor with Target Receptor-Triggered-Release in the Central Nervous System.

PubMed

Jiang, Yuhang; Fay, James M; Poon, Chi-Duen; Vinod, Natasha; Zhao, Yuling; Bullock, Kristin; Qin, Si; Manickam, Devika S; Yi, Xiang; Banks, William A; Kabanov, Alexander V

2018-02-07

Brain-derived neurotrophic factor (BDNF) is identified as a potent neuroprotective and neuroregenerative agent for many neurological diseases. Regrettably, its delivery to the brain is hampered by poor serum stability and rapid brain clearance. Here, a novel nanoformulation is reported composed of a bio-compatible polymer, poly(ethylene glycol)- b -poly(L-glutamic acid) (PEG-PLE), that hosts the BDNF molecule in a nanoscale complex, termed here Nano-BDNF. Upon simple mixture, Nano-BDNF spontaneously forms uniform spherical particles with a core-shell structure. Molecular dynamics simulations suggest that binding between BDNF and PEG-PLE is mediated through electrostatic coupling as well as transient hydrogen bonding. The formation of Nano-BDNF complex stabilizes BDNF and protects it from nonspecific binding with common proteins in the body fluid, while allowing it to associate with its receptors. Following intranasal administration, the nanoformulation improves BDNF delivery throughout the brain and displays a more preferable regional distribution pattern than the native protein. Furthermore, intranasally delivered Nano-BDNF results in superior neuroprotective effects in the mouse brain with lipopolysaccharides-induced inflammation, indicating promise for further evaluation of this agent for the therapy of neurologic diseases.

Polymerizable Molecular Silsesquioxane Cage Armored Hybrid Microcapsules with In Situ Shell Functionalization.

PubMed

Xing, Yuxiu; Peng, Jun; Xu, Kai; Lin, Weihong; Gao, Shuxi; Ren, Yuanyuan; Gui, Xuefeng; Liang, Shengyuan; Chen, Mingcai

2016-02-01

We prepared core-shell polymer-silsesquioxane hybrid microcapsules from cage-like methacryloxypropyl silsesquioxanes (CMSQs) and styrene (St). The presence of CMSQ can moderately reduce the interfacial tension between St and water and help to emulsify the monomer prior to polymerization. Dynamic light scattering (DLS) and TEM analysis demonstrated that uniform core-shell latex particles were achieved. The polymer latex particles were subsequently transformed into well-defined hollow nanospheres by removing the polystyrene (PS) core with 1:1 ethanol/cyclohexane. High-resolution TEM and nitrogen adsorption-desorption analysis showed that the final nanospheres possessed hollow cavities and had porous shells; the pore size was approximately 2-3 nm. The nanospheres exhibited large surface areas (up to 486 m 2  g -1 ) and preferential adsorption, and they demonstrated the highest reported methylene blue adsorption capacity (95.1 mg g -1 ). Moreover, the uniform distribution of the methacryloyl moiety on the hollow nanospheres endowed them with more potential properties. These results could provide a new benchmark for preparing hollow microspheres by a facile one-step template-free method for various applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Identification and onset of inertial modes in the wide-gap spherical Couette system

NASA Astrophysics Data System (ADS)

Barik, A.; Wicht, J.; Triana, S. A.; Hoff, M.

2016-12-01

The spherical Couette system consists of two concentric rotating spheres with a fluid filling the shell in between. The system has been studied for a long time by fluid dynamicists and is ideal for studying flow instabilities due to differential rotation and the interaction of the same with magnetic fields - important for understanding dynamics of planetary and stellar interiors. The system is also a basis for a new generation of dynamo experiments because of its closer geometrical resemblance to real astrophysical objects as compared to past experiments. We simulate this system using the two different pseudo-spectral codes MagIC and XSHELLS. We focus here on a very interesting and general instability in this system - inertial modes. A rotating body of fluid is known to sustain oscillatory waves due to the restoring action of the Coriolis force. In a bounded container, these form a discrete spectrum called inertial modes. These modes have been analytically known for a rotating full sphere for over a century now. In a spherical shell, they cannot be formulated analytically. However, many of these inertial modes are observed in spherical Couette experiments as well as in simulations. Past studies have tried to explain the onset of these modes invoking wave over-reflection or critical layer instabilities on the cylinder tangent to the inner sphere. In this study, we present the inertial modes found in our simulations and try to explain their onset as secondary instabilities due to the destabilization of the fundamental non-axisymmetric instability, forming a triadic resonance with the fundamental instability. We run various simulations varying the rotation rate of the inner sphere, while keeping the rotation rate of the outer sphere constant. We track velocities and induced magnetic field and produce spectrograms similar to those of the experiments. Our results match very well the experimental data from spherical Couette set-ups at BTU Cottbus and the University of Maryland.

Effects of particle packing on the sintered microstructure

NASA Astrophysics Data System (ADS)

Barringer, E. A.; Bowen, H. K.

1988-04-01

The sintering process is shown to be critically dependent on particle-packing density and porosity uniformity. Sintering experiments were conducted on compacts consisting of monodisperse, spherical TiO2 particles. Densification kinetics and microstructure evolution for two initial packing densities, 55% and 69% of theoretical, were investigated. The lower-density compacts sintered rapidly to theoretical density, yet improved particle-packing density and uniformity significantly enhanced densification.

The nuclear shell model toward the drip lines

NASA Astrophysics Data System (ADS)

Poves, A.; Caurier, E.; Nowacki, F.; Sieja, K.

2012-10-01

We describe the 'islands of inversion' that occur when approaching the neutron drip line around the magic numbers N=20, N=28 and N=40 in the framework of the interacting shell model in very large valence spaces. We explain these configuration inversions (and the associated shape transitions) as the result of the competition between the spherical mean field (monopole) that favors magicity and the correlations (multipole) that favor deformed intruder states. We also show that the N=20 and N=28 islands are in reality a single one, which for the magnesium isotopes is limited by N=18 and N=32.

Stability analysis of ultrasound thick-shell contrast agents

PubMed Central

Lu, Xiaozhen; Chahine, Georges L.; Hsiao, Chao-Tsung

2012-01-01

The stability of thick shell encapsulated bubbles is studied analytically. 3-D small perturbations are introduced to the spherical oscillations of a contrast agent bubble in response to a sinusoidal acoustic field with different amplitudes of excitation. The equations of the perturbation amplitudes are derived using asymptotic expansions and linear stability analysis is then applied to the resulting differential equations. The stability of the encapsulated microbubbles to nonspherical small perturbations is examined by solving an eigenvalue problem. The approach then identifies the fastest growing perturbations which could lead to the breakup of the encapsulated microbubble or contrast agent. PMID:22280568

The pick-up of cometary protons by the solar wind

NASA Technical Reports Server (NTRS)

Neugebauer, M.; Goldstein, B. E.; Goldstein, R.; Lazarus, A. J.; Altwegg, K.; Balsiger, H.

1987-01-01

The HERS detector of the Ion Mass Spectrometer on the Giotto spacecraft measured the 3-dimensional distribution of picked-up cometary protons over a distance of about 8 million km upstream of the bow shock of comet P/Hally. The protons were observed to be elastically scattered out of their original cycloidal trajectories such that they were nonuniformly distributed over a spherical shell in velocity space. The shell radius (relative to its expected radius) and thickness increased as the bow shock was approached. Down-stream of the shock, the cometary protons could not be distinguished from the heated solar wind protons.

On the control of a robot ball using two omniwheels

NASA Astrophysics Data System (ADS)

Ivanov, Alexander P.

2015-07-01

We discuss the dynamics of a balanced body of spherical shape on a rough plane, controlled by the movement of a built-in shell. These two shells are set in relative motion due to rotation of the two symmetrical omniwheels. It is shown that the ball can be moved to any point on the plane along a straight or (in the case of the initial degeneration) polygonal line. Moreover, any prescribed curvilinear trajectory of the ball center can be followed by an appropriate control strategy as far as the diameter connecting both wheels is nonvertical.

Special Features of Light Absorption by the Dimer of Bilayer Microparticles

NASA Astrophysics Data System (ADS)

Geints, Yu. É.; Panina, E. K.; Zemlyanov, A. A.

2018-05-01

Results of numerical simulation of light absorption by the dimer of bilayer spherical particles consisting of a water core and a polymer shell absorbing radiation are presented. The spatial distribution and the amplitude characteristics of the volume density of the absorbed power are investigated. It is shown that for a certain spatial dimer configuration, the maximal achievable density of the absorbed power is realized. It is also established that for closely spaced microcapsules with high shell absorption indices, the total power absorbed in the dimer volume can increase in comparison with the radiation absorption by two insulated microparticles.

Spectrophotometry at 10 microns of T Tauri stars

NASA Technical Reports Server (NTRS)

Cohen, M.; Witteborn, F. C.

1985-01-01

New 8-13 micron spectra of 32 T Tau, or related young, stars are presented. Silicate emission features are commonly seen. Absorptions occur less frequently but also match the properties of silicate materials. The shape of the emission feature suggests that a more crystalline grain is responsible in the T Tau stars than those of the Trapezium region. The evolution of the silicate component of the circumstellar shell around T Tau stars, and its dependence upon stellar wind activity, visual linear polarization, and extinction are investigated. Several correlations suggest that the shells are likely to be flattened, disklike structures rather than spherical.

Stress Analysis of Composite Cylindrical Shells With an Elliptical Cutout

NASA Technical Reports Server (NTRS)

Nemeth, M. P.; Oterkus, E.; Madenci, E.

2005-01-01

A special-purpose, semi-analytical solution method for determining the stress and deformation fields in a thin laminated-composite cylindrical shell with an elliptical cutout is presented. The analysis includes the effects of cutout size, shape, and orientation; nonuniform wall thickness; oval-cross-section eccentricity; and loading conditions. The loading conditions include uniform tension, uniform torsion, and pure bending. The analysis approach is based on the principle of stationary potential energy and uses Lagrange multipliers to relax the kinematic admissibility requirements on the displacement representations through the use of idealized elastic edge restraints. Specifying appropriate stiffness values for the elastic extensional and rotational edge restraints (springs) allows the imposition of the kinematic boundary conditions in an indirect manner, which enables the use of a broader set of functions for representing the displacement fields. Selected results of parametric studies are presented for several geometric parameters that demonstrate that analysis approach is a powerful means for developing design criteria for laminated-composite shells.

Expansion of a radially symmetric blast shell into a uniformly magnetized plasma

NASA Astrophysics Data System (ADS)

Dieckmann, M. E.; Moreno, Q.; Doria, D.; Romagnani, L.; Sarri, G.; Folini, D.; Walder, R.; Bret, A.; d'Humières, E.; Borghesi, M.

2018-05-01

The expansion of a thermal pressure-driven radial blast shell into a dilute ambient plasma is examined with two-dimensional PIC simulations. The purpose is to determine if laminar shocks form in a collisionless plasma which resemble their magnetohydrodynamic counterparts. The ambient plasma is composed of electrons with the temperature of 2 keV and cool fully ionized nitrogen ions. It is permeated by a spatially uniform magnetic field. A forward shock forms between the shocked ambient medium and the pristine ambient medium, which changes from an ion acoustic one through a slow magnetosonic one to a fast magnetosonic shock with increasing shock propagation angles relative to the magnetic field. The slow magnetosonic shock that propagates obliquely to the magnetic field changes into a tangential discontinuity for a perpendicular propagation direction, which is in line with the magnetohydrodynamic model. The expulsion of the magnetic field by the expanding blast shell triggers an electron-cyclotron drift instability.

Region Spherical Harmonic Magnetic Modeling from Near-Surface and Satellite-Altitude Anomlaies

NASA Technical Reports Server (NTRS)

Kim, Hyung Rae; von Frese, Ralph R. B.; Taylor, Patrick T.

2013-01-01

The compiled near-surface data and satellite crustal magnetic measured data are modeled with a regionally concentrated spherical harmonic presentation technique over Australia and Antarctica. Global crustal magnetic anomaly studies have used a spherical harmonic analysis to represent the Earth's magnetic crustal field. This global approach, however is best applied where the data are uniformly distributed over the entire Earth. Satellite observations generally meet this requirement, but unequally distributed data cannot be easily adapted in global modeling. Even for the satellite observations, due to the errors spread over the globe, data smoothing is inevitable in the global spherical harmonic presentations. In addition, global high-resolution modeling requires a great number of global spherical harmonic coefficients for the regional presentation of crustal magnetic anomalies, whereas a lesser number of localized spherical coefficients will satisfy. We compared methods in both global and regional approaches and for a case where the errors were propagated outside the region of interest. For observations from the upcoming Swarm constellation, the regional modeling will allow the production a lesser number of spherical coefficients that are relevant to the region of interest

Mn@Si14+: a singlet fullerene-like endohedrally doped silicon cluster.

PubMed

Ngan, Vu Thi; Pierloot, Kristine; Nguyen, Minh Tho

2013-04-21

The electronic structure of Mn@Si14(+) is determined using DFT and CASPT2/CASSCF(14,15) computations with large basis sets. The endohedrally Mn-doped Si cationic cluster has a D3h fullerene-like structure featuring a closed-shell singlet ground state with a singlet-triplet gap of ~1 eV. A strong stabilizing interaction occurs between the 3d(Mn) and the 2D-shell(Si14) orbitals, and a large amount of charge is transferred from the Si14 cage to the Mn dopant. The 3d(Mn) orbitals are filled by encapsulation, and the magnetic moment of Mn is completely quenched. Full occupation of [2S, 2P, 2D] shell orbitals by 18 delocalized electrons confers the doped Mn@Si14(+) cluster a spherically aromatic character.

Formation of superheavy elements in the capture of very heavy ions at high excitation energies

NASA Astrophysics Data System (ADS)

Royer, G.

2013-05-01

The potential barriers governing the reactions 58Fe+244Pu, 238U+64Ni, and 238U+72Ge have been determined from a liquid-drop model taking into account the proximity energy, shell energies, rotational energy, and deformation of the incoming nuclei in the quasimolecular shape valley. Double-humped potential barriers appear in these entrance channels. The external saddle-point corresponds to two touching ellipsoidal nuclei when the shell and pairing effects are taken into account, while the inner barrier is due to the shell effects at the vicinity of the spherical shape of the composite system. Between them, a large potential pocket exists and persists at very high angular momenta allowing the capture of very heavy ions at high excitation energies.

Transient analysis using conical shell elements

NASA Technical Reports Server (NTRS)

Yang, J. C. S.; Goeller, J. E.; Messick, W. T.

1973-01-01

The use of the NASTRAN conical shell element in static, eigenvalue, and direct transient analyses is demonstrated. The results of a NASTRAN static solution of an externally pressurized ring-stiffened cylinder agree well with a theoretical discontinuity analysis. Good agreement is also obtained between the NASTRAN direct transient response of a uniform cylinder to a dynamic end load and one-dimensional solutions obtained using a method of characteristics stress wave code and a standing wave solution. Finally, a NASTRAN eigenvalue analysis is performed on a hydroballistic model idealized with conical shell elements.

Sample-morphology effects on x-ray photoelectron peak intensities. III. Simulated spectra of model core–shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, Cedric J., E-mail: cedric.powell@nist.gov; Chudzicki, Maksymilian; Werner, Wolfgang S. M.

2015-09-15

The National Institute of Standards and Technology database for the simulation of electron spectra for surface analysis has been used to simulate Cu 2p photoelectron spectra for four types of spherical copper–gold nanoparticles (NPs). These simulations were made to extend the work of Tougaard [J. Vac. Sci. Technol. A 14, 1415 (1996)] and of Powell et al. [J. Vac. Sci. Technol. A 31, 021402 (2013)] who performed similar simulations for four types of planar copper–gold films. The Cu 2p spectra for the NPs were compared and contrasted with analogous results for the planar films and the effects of elastic scatteringmore » were investigated. The new simulations were made for a monolayer of three types of Cu/Au core–shell NPs on a Si substrate: (1) an Au shell of variable thickness on a Cu core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; (2) a Cu shell of variable thickness on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; and (3) an Au shell of variable thickness on a 1 nm Cu shell on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. For these three morphologies, the outer-shell thickness was varied until the Cu 2p{sub 3/2} peak intensity was the same (within 2%) as that found in our previous work with planar Cu/Au morphologies. The authors also performed similar simulations for a monolayer of spherical NPs consisting of a CuAu{sub x} alloy (also on a Si substrate) with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. In the latter simulations, the relative Au concentration (x) was varied to give the same Cu 2p{sub 3/2} peak intensity (within 2%) as that found previously. For each morphology, the authors performed simulations with elastic scattering switched on and off. The authors found that elastic-scattering effects were generally strong for the Cu-core/Au-shell and weak for the Au-core/Cu-shell NPs; intermediate elastic-scattering effects were found for the Au-core/Cu-shell/Au-shell NPs. The shell thicknesses required to give the selected Cu 2p{sub 3/2} peak intensity for the three types of core–shell NPs were less than the corresponding film thicknesses of planar samples since Cu 2p photoelectrons can be detected from the sides and, for the smaller NPs, bottoms of the NPs. Elastic-scattering effects were also observed on the Au atomic fractions found for the CuAu{sub x} NP alloys with different diameters.« less

Computation of Relative Magnetic Helicity in Spherical Coordinates

NASA Astrophysics Data System (ADS)

Moraitis, Kostas; Pariat, Étienne; Savcheva, Antonia; Valori, Gherardo

2018-06-01

Magnetic helicity is a quantity of great importance in solar studies because it is conserved in ideal magnetohydrodynamics. While many methods for computing magnetic helicity in Cartesian finite volumes exist, in spherical coordinates, the natural coordinate system for solar applications, helicity is only treated approximately. We present here a method for properly computing the relative magnetic helicity in spherical geometry. The volumes considered are finite, of shell or wedge shape, and the three-dimensional magnetic field is considered to be fully known throughout the studied domain. Testing of the method with well-known, semi-analytic, force-free magnetic-field models reveals that it has excellent accuracy. Further application to a set of nonlinear force-free reconstructions of the magnetic field of solar active regions and comparison with an approximate method used in the past indicates that the proposed method can be significantly more accurate, thus making our method a promising tool in helicity studies that employ spherical geometry. Additionally, we determine and discuss the applicability range of the approximate method.

Modeling and studying of white light emitting diodes based on CdS/ZnS spherical quantum dots

NASA Astrophysics Data System (ADS)

Hasanirokh, K.; Asgari, A.

2018-07-01

In this paper, we propose a quantum dot (QD) based white light emitting diode (WLED) structure to study theoretically the material gain and quantum efficiency of the system. We consider the spherical QDs with a II-VI semiconductor core (CdS) that covered with a wider band gap semiconductor acting as a shell (ZnS). In order to generate white light spectrum, we use layers with different dot size that can emit blue, green and red colors. The blue emission originating from CdS core combines to green/orange components originating from ZnS shell and creates an efficiency white light emission. To model this device, at first, we solve Schrödinger and Poisson equations self consistently and obtain eigen energies and wave functions. Then, we calculate the optical gain and internal quantum efficiency (IQE) of a CdS/ZnS LED sample. We investigate the structural parameter effects on the optical properties of the WLED. The numerical results show that the gain profile and IQE curves depend strongly on the structural parameters such as dot size, carrier density and volume scaling parameter. The gain profile becomes higher and wider with increasing the core radius while it becomes less and narrower with increasing the shell thickness. Furthermore, it is found that the volume scaling parameter can manage the system quantum efficiency.

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-11-01

Bell-Plesset effects accounting for the time dependence of the radius, velocity and acceleration of the Rayleigh-Taylor-unstable surface are ubiquitous in the instability of spherical laser targets and magnetically driven cylindrical liners. We present an analytical model that, for an ideal incompressible fluid and small perturbation amplitudes, exactly accounts for the Bell-Plesset effects in finite-thickness targets and liners through acceleration and deceleration phases. We derive the time-dependent dispersion equations determining the ``instantaneous growth rate'' and demonstrate that by integrating this growth rate over time (the WKB approximation) we accurately evaluate the number of perturbation e-foldings during the acceleration phase. In the limit of the small target/liner thickness, we obtain the exact thin-shell perturbation equations and approximate thin-shell dispersion relations, generalizing the earlier results of Harris (1962), Ott (1972) and Bud'ko et al. (1989). This research was supported by the US DOE/NNSA (A.L.V.), and in part by appointment to the Sandia National Laboratories Truman Fellowship in National Security Science and Engineering (P.F.S.), which is part of the Laboratory Directed Research and Development (LDRD) Program, Project No. 165746, and sponsored by Sandia Corporation (a wholly owned subsidiary of Lockheed Martin Corporation) as Operator of Sandia National Laboratories under its U.S. Department of Energy Contract No. DE-AC04-94AL85000.

The energy of a prolate spheroidal shell in a uniform magnetic field

NASA Astrophysics Data System (ADS)

Koksharov, Yu. A.

2017-04-01

The problem of the energy of a spheroidal magnetic shell, solved by methods of classical electrodynamics, arises, in particular, upon the study of thin-wall biocompatible microcapsules in connection with a pressing issue of targeted drug delivery. The drug inside a microcapsule should be released from the shell at a required instant of time by destroying the capsule's shell. The placement inside a shell of magnetic nanoparticles sensitive to an external magnetic field theoretically makes it possible to solve both problems: to transport a capsule to the required place and to destroy its shell. In particular, the shell can be destroyed under the action of internal stress when the shape of a capsule is changed. In this paper, the analysis of the model of a magnetic microcapsule in the form of a prolate spheroidal shell is performed and formulas for the magnetostatic and magnetic free energy when the magnetic field is directed along the major axis of the spheroid are derived.

Glass shell manufacturing in space

NASA Technical Reports Server (NTRS)

Downs, R. L.; Ebner, M. A.; Nolen, R. L., Jr.

1981-01-01

Highly-uniform, hollow glass spheres (shells), which are used for inertial confinement fusion targets, were formed from metal-organic gel powder feedstock in a vertical furnace. As a result of the rapid pyrolysis caused by the furnace, the gel is transformed to a shell in five distinct stages: (a) surface closure of the porous gel; (b) generation of a closed-cell foam structure in the gel; (c) spheridization of the gel and further expansion of the foam; (d) coalescence of the closed-cell foam to a single-void shell; and (e) fining of the glass shell. The heat transfer from the furnace to the falling gel particle was modeled to determine the effective heating rate of the gel. The model predicts the temperature history for a particle as a function of mass, dimensions, specific heat, and absorptance as well as furnace temperature profile and thermal conductivity of the furnace gas. A model was developed that predicts the gravity-induced degradation of shell concentricity in falling molten shells as a function of shell characteristics and time.

Visualization of Bacterial Microcompartment Facet Assembly Using High-Speed Atomic Force Microscopy

DOE PAGES

Sutter, Markus; Faulkner, Matthew; Aussignargues, Clément; ...

2015-11-30

Bacterial microcompartments (BMCs) are proteinaceous organelles widespread among bacterial phyla. They compartmentalize enzymes within a selectively permeable shell and play important roles in CO 2 fixation, pathogenesis, and microbial ecology. Here, we combine X-ray crystallography and high-speed atomic force microscopy to characterize, at molecular resolution, the structure and dynamics of BMC shell facet assembly. Our results show that preformed hexamers assemble into uniformly oriented shell layers, a single hexamer thick. We also observe the dynamic process of shell facet assembly. Shell hexamers can dissociate from and incorporate into assembled sheets, indicating a flexible intermolecular interaction. Furthermore, we demonstrate that themore » self-assembly and dynamics of shell proteins are governed by specific contacts at the interfaces of shell proteins. Our study provides novel insights into the formation, interactions, and dynamics of BMC shell facets, which are essential for the design and engineering of self-assembled biological nanoreactors and scaffolds based on BMC architectures.« less

One-pot synthesis of iniferter-bound polystyrene core nanoparticles for the controlled grafting of multilayer shells

NASA Astrophysics Data System (ADS)

Marchyk, Nataliya; Maximilien, Jacqueline; Beyazit, Selim; Haupt, Karsten; Sum Bui, Bernadette Tse

2014-02-01

A novel approach using one-pot synthesis for the production of uniform, iniferter-bound polystyrene core nanoparticles of size 30-40 nm is described. Conventional oil-in-water emulsion polymerisation of styrene and divinylbenzene, combining a hybrid initiation system (thermal and UV), triggered sequentially, was employed to form the surface-bound thiocarbamate iniferters in situ. The iniferter cores were then used as seeds for re-initiating further polymerisation by UV irradiation to produce water-compatible core-shell nanoparticles. Grafting of various shell-types is demonstrated: linear polymers of poly(N-isopropylacrylamide) brushes, crosslinked polymers bearing different surface charges and molecularly imprinted polymers. The shell thickness was readily tuned by varying the monomers' concentration and polymerisation time. Our method is straightforward and in addition, gives access to the preparation of fluorescent seeds and the possibility of grafting nanosized multiple shells. The core-shell nanoparticles were fully characterised by dynamic light scattering, transmission electron microscopy, Fourier transform infrared spectroscopy and microelemental analysis.A novel approach using one-pot synthesis for the production of uniform, iniferter-bound polystyrene core nanoparticles of size 30-40 nm is described. Conventional oil-in-water emulsion polymerisation of styrene and divinylbenzene, combining a hybrid initiation system (thermal and UV), triggered sequentially, was employed to form the surface-bound thiocarbamate iniferters in situ. The iniferter cores were then used as seeds for re-initiating further polymerisation by UV irradiation to produce water-compatible core-shell nanoparticles. Grafting of various shell-types is demonstrated: linear polymers of poly(N-isopropylacrylamide) brushes, crosslinked polymers bearing different surface charges and molecularly imprinted polymers. The shell thickness was readily tuned by varying the monomers' concentration and polymerisation time. Our method is straightforward and in addition, gives access to the preparation of fluorescent seeds and the possibility of grafting nanosized multiple shells. The core-shell nanoparticles were fully characterised by dynamic light scattering, transmission electron microscopy, Fourier transform infrared spectroscopy and microelemental analysis. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr05295h

About mechanisms of tetonic activity of the satellites

NASA Astrophysics Data System (ADS)

Barkin, Yu. V.

2003-04-01

ABOUT MECHANISMS OF TECTONIC ACTIVITY OF THE SATELLITES Yu.V. Barkin Sternberg Astronomical Institute, Moscow, Russia, barkin@sai.msu.ru Due to attraction of the central planet and others external bodies satellite is subjected by tidal and non-tidal deformations. Elastic energy is changed in dependence from mutual position and motion of celestial bodies and as result the tensional state of satellite and its tectonic (endogenous) activity also is changed. Satellites of the planets have the definite shell’s structure and due to own rotation these shells are characterized by different oblatenesses. Gravitational interaction of the satellite and its mother planet generates big additional mechanical forces (and moments) between the neighboring non-spherical shells of the satellite (mantle, core and crust). These forces and moments are cyclic functions of time, which are changed in the different time-scales. They generate corresponding cyclic perturbations of the tensional state of the shells, their deformations, small relative transnational displacements and slow rotation of the shells and others. In geological period of time it leads to a fundamental tectonic reconstruction of the body. Definite contribution to discussed phenomena are caused by classical tidal mechanism. of planet-satellite interaction. But in this report we discuss in first the new mechanisms of endogenous activity of celestial bodies. They are connected with differential gravitational attraction of non-spherical satellite shells by the external celestial bodies which leads: 1) to small relative rotation (nutations) of the shells; 2) to small relative translational motions of the shells (displacements of their center of mass); 3) to relative displacements and rotations of the shells due to eccentricity of their center of mass positions; 4) to viscous elastic deformations of the shells and oth. (Barkin, 2001). For higher evaluations of the power of satellite endogenous activities were obtained analytical formulae. Obtained theoretical evaluations of the force and power characteristics are in good agreement with observational date and in particular they explain some from the well known problems of planetology. The following phenomena obtain an explanation: 1. Higher endogenous activity of Io; 2. Europe crack systems; 3. high endogenous activity of Ganimede, Titan, Miranda, Enceladus, Ariel. Well known relations of tectonic activity between satellites: Ariel and Umbriel, Reiha and Diona, Titania and Oberon have been explained in terms of numerical values of force and energy characteristics. Conclusion about high endogenous activity of Titan also presents important interest. The work was accepted and financed by RFBR grant N 02-05-64176 and by grant SAB2000-0235 of Ministry of Education of Spain (Secretaria de Estado de Educacion y Universidades).

Shell microstructures of mussels (Bivalvia: Mytilidae: Bathymodiolinae) from deep-sea chemosynthetic sites: Do they have a phylogenetic significance?

NASA Astrophysics Data System (ADS)

Génio, Luciana; Kiel, Steffen; Cunha, Marina R.; Grahame, John; Little, Crispin T. S.

2012-06-01

The increasing number of bathymodiolin mussel species being described from deep-sea chemosynthetic environments worldwide has raised many questions about their evolutionary history, and their systematics is still being debated. Mussels are also abundant in fossil chemosynthetic assemblages, but their identification is problematic due to conservative shell morphology within the group and preservation issues. Potential resolution of bathymodiolin taxonomy requires new character sets, including morphological features that are likely to be preserved in fossil specimens. To investigate the phylogenetic significance of shell microstructural features, we studied the shell microstructure and mineralogy of 10 mussel species from hydrothermal vents and hydrocarbon seeps, and 15 taxa from sunken wood and bone habitats, and compared these observations with current molecular phylogenies of the sub-family Bathymodiolinae. In addition, we analyzed the shell microstructure in Adipicola chickubetsuensis from fossil whale carcasses, and in Bathymodiolus cf. willapaensis and “Modiola exbrocchii” from fossil cold seeps, and discussed the usefulness of these characters for identification of fossil chemosymbiotic mussels. Microstructural shell features are quite uniform among vent, seep, wood and bone mussel taxa, and therefore established bathymodiolin lineages cannot be discriminated, nor can the relations between fossil and modern species be determined with these characters. Nevertheless, the uniformity of shell microstructures observed among chemosymbiotic mussels and the similarity with its closest relative, Modiolus modiolus, does not challenge the monophyly of the group. Slight differences are found between the large vent and seep mussels and the small mytilids commonly found in habitats enriched in organic matter. Together with previous data, these results indicate that a repeated pattern of paedomorphism characterizes the evolutionary history of deep-sea mussels, and the occurrence of neotenous features should be considered in the taxonomic revision of this group.

Revisiting chameleon gravity: Thin-shell and no-shell fields with appropriate boundary conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tamaki, Takashi; Department of Physics, Rikkyo University, Toshima, Tokyo 171-8501; Tsujikawa, Shinji

2008-10-15

We derive analytic solutions of a chameleon scalar field {phi} that couples to a nonrelativistic matter in the weak gravitational background of a spherically symmetric body, paying particular attention to a field mass m{sub A} inside of the body. The standard thin-shell field profile is recovered by taking the limit m{sub A}r{sub c}{yields}{infinity}, where r{sub c} is a radius of the body. We show the existence of 'no-shell' solutions where the field is nearly frozen in the whole interior of the body, which does not necessarily correspond to the 'zero-shell' limit of thin-shell solutions. In the no-shell case, under themore » condition m{sub A}r{sub c}>>1, the effective coupling of {phi} with matter takes the same asymptotic form as that in the thin-shell case. We study experimental bounds coming from the violation of equivalence principle as well as solar-system tests for a number of models including f(R) gravity and find that the field is in either the thin-shell or the no-shell regime under such constraints, depending on the shape of scalar-field potentials. We also show that, for the consistency with local gravity constraints, the field at the center of the body needs to be extremely close to the value {phi}{sub A} at the extremum of an effective potential induced by the matter coupling.« less

Jammed elastic shells - a 3D experimental soft frictionless granular system

NASA Astrophysics Data System (ADS)

Jose, Jissy; Blab, Gerhard A.; van Blaaderen, Alfons; Imhof, Arnout

2015-03-01

We present a new experimental system of monodisperse, soft, frictionless, fluorescent labelled elastic shells for the characterization of structure, universal scaling laws and force networks in 3D jammed matter. The interesting fact about these elastic shells is that they can reversibly deform and therefore serve as sensors of local stress in jammed matter. Similar to other soft particles, like emulsion droplets and bubbles in foam, the shells can be packed to volume fractions close to unity, which allows us to characterize the contact force distribution and universal scaling laws as a function of volume fraction, and to compare them with theoretical predictions and numerical simulations. However, our shells, unlike other soft particles, deform rather differently at large stresses. They deform without conserving their inner volume, by forming dimples at contact regions. At each contact one of the shells buckled with a dimple and the other remained spherical, closely resembling overlapping spheres. We conducted 3D quantitative analysis using confocal microscopy and image analysis routines specially developed for these particles. In addition, we analysed the randomness of the process of dimpling, which was found to be volume fraction dependent.

Super-tough, ultra-stretchable and strongly compressive hydrogels with core-shell latex particles inducing efficient aggregation of hydrophobic chains.

PubMed

Ren, Xiuyan; Huang, Chang; Duan, Lijie; Liu, Baijun; Bu, Lvjun; Guan, Shuang; Hou, Jiliang; Zhang, Huixuan; Gao, Guanghui

2017-05-14

Toughness, strechability and compressibility for hydrogels were ordinarily balanced for their use as mechanically responsive materials. For example, macromolecular microsphere composite hydrogels with chemical crosslinking exhibited excellent compression strength and strechability, but poor tensile stress. Here, a novel strategy for the preparation of a super-tough, ultra-stretchable and strongly compressive hydrogel was proposed by introducing core-shell latex particles (LPs) as crosslinking centers for inducing efficient aggregation of hydrophobic chains. The core-shell LPs always maintained a spherical shape due to the presence of a hard core even by an external force and the soft shell could interact with hydrophobic chains due to hydrophobic interactions. As a result, the hydrogels reinforced by core-shell LPs exhibited not only a high tensile strength of 1.8 MPa and dramatic elongation of over 20 times, but also an excellent compressive performance of 13.5 MPa at a strain of 90%. The Mullins effect was verified for the validity of core-shell LP-reinforced hydrogels by inducing aggregation of hydrophobic chains. The novel strategy strives to provide a better avenue for designing and developing a new generation of hydrophobic association tough hydrogels with excellent mechanical properties.

Facile synthesis of multi-shell structured binary metal oxide powders with a Ni/Co mole ratio of 1:2 for Li-Ion batteries

NASA Astrophysics Data System (ADS)

Choi, Seung Ho; Park, Sun Kyu; Lee, Jung-Kul; Kang, Yun Chan

2015-06-01

Multi-shell structured binary transition metal oxide powders with a Ni/Co mole ratio of 1:2 are prepared by a simple spray drying process. Precursor powder particles prepared by spray drying from a spray solution of citric acid and ethylene glycol have completely spherical shape, fine size, and a narrow size distribution. The precursor powders turn into multi-shell powders after a post heat-treatment at temperatures between 250 and 800 °C. The multi-shell structured powders are formed by repeated combustion and contraction processes. The multi-shell powders have mixed crystal structures of Ni1-xCo2O4-x and NiO phases regardless of the post-treatment temperature. The reversible capacities of the powders post-treated at 250, 400, 600, and 800 °C after 100 cycles are 584, 913, 808, and 481 mA h g-1, respectively. The low charge transfer resistance and high lithium ion diffusion rate of the multi-shell powders post-treated at 400 °C with optimum grain size result in superior electrochemical properties even at high current densities.

Porogranular materials composed of elastic Helmholtz resonators for acoustic wave absorption.

PubMed

Griffiths, Stéphane; Nennig, Benoit; Job, Stéphane

2017-01-01

A theoretical and experimental study of the acoustic absorption of granular porous media made of non-cohesive piles of spherical shells is presented. These shells are either rigid or elastic, possibly drilled with a neck (Helmholtz resonators), and either porous or impervious. A description is given of acoustic propagation through these media using the effective medium models proposed by Johnson (rigid particles) and Boutin (rigid Helmholtz resonators), which are extended to the configurations studied in this work. A solution is given for the local equation of elasticity of a shell coupled to the viscous flow of air through the neck and the micropores. The models and the simulations are compared to absorption spectra measured in reflection in an impedance tube. The effective medium models and the measurements show excellent agreement for configurations made of rigid particles and rigid Helmholtz resonators that induce an additional peak of absorption at low frequency. A shift of the Helmholtz resonance toward low frequencies, due to the softness of the shells is revealed by the experiments for elastic shells made of soft elastomer and is well reproduced by the simulations. It is shown that microporous shells enhance and broaden acoustic absorption compared to stiff or elastic resonators.

Sound Source Localization Using Non-Conformal Surface Sound Field Transformation Based on Spherical Harmonic Wave Decomposition

PubMed Central

Zhang, Lanyue; Ding, Dandan; Yang, Desen; Wang, Jia; Shi, Jie

2017-01-01

Spherical microphone arrays have been paid increasing attention for their ability to locate a sound source with arbitrary incident angle in three-dimensional space. Low-frequency sound sources are usually located by using spherical near-field acoustic holography. The reconstruction surface and holography surface are conformal surfaces in the conventional sound field transformation based on generalized Fourier transform. When the sound source is on the cylindrical surface, it is difficult to locate by using spherical surface conformal transform. The non-conformal sound field transformation by making a transfer matrix based on spherical harmonic wave decomposition is proposed in this paper, which can achieve the transformation of a spherical surface into a cylindrical surface by using spherical array data. The theoretical expressions of the proposed method are deduced, and the performance of the method is simulated. Moreover, the experiment of sound source localization by using a spherical array with randomly and uniformly distributed elements is carried out. Results show that the non-conformal surface sound field transformation from a spherical surface to a cylindrical surface is realized by using the proposed method. The localization deviation is around 0.01 m, and the resolution is around 0.3 m. The application of the spherical array is extended, and the localization ability of the spherical array is improved. PMID:28489065

Solutions for the conductivity of multi-coated spheres and spherically symmetric inclusion problems

NASA Astrophysics Data System (ADS)

Pham, Duc Chinh

2018-02-01

Variational results on the macroscopic conductivity (thermal, electrical, etc.) of the multi-coated sphere assemblage have been used to derive the explicit expression of the respective field (thermal, electrical, etc.) within the spheres in d dimensions (d=2,3). A differential substitution approach has been developed to construct various explicit expressions or determining equations for the effective spherically symmetric inclusion problems, which include those with radially variable conductivity, different radially variable transverse and normal conductivities, and those involving imperfect interfaces, in d dimensions. When the volume proportion of the outermost spherical shell increases toward 1, one obtains the respective exact results for the most important specific cases: the dilute solutions for the compound inhomogeneities suspended in a major matrix phase. Those dilute solution results are also needed for other effective medium approximation schemes.

Manufacturing of glassy thin shell for adaptive optics: results achieved

NASA Astrophysics Data System (ADS)

Poutriquet, F.; Rinchet, A.; Carel, J.-L.; Leplan, H.; Ruch, E.; Geyl, R.; Marque, G.

2012-07-01

Glassy thin shells are key components for the development of adaptive optics and are part of future & innovative projects such as ELT. However, manufacturing thin shells is a real challenge. Even though optical requirements for the front face - or optical face - are relaxed compared to conventional passive mirrors, requirements concerning thickness uniformity are difficult to achieve. In addition, process has to be completely re-defined as thin mirror generates new manufacturing issues. In particular, scratches and digs requirement is more difficult as this could weaken the shell, handling is also an important issue due to the fragility of the mirror. Sagem, through REOSC program, has recently manufactured different types of thin shells in the frame of European projects: E-ELT M4 prototypes and VLT Deformable Secondary Mirror (VLT DSM).

Morphology-Controlled Synthesis of Au/Cu₂FeSnS₄ Core-Shell Nanostructures for Plasmon-Enhanced Photocatalytic Hydrogen Generation.

PubMed

Ha, Enna; Lee, Lawrence Yoon Suk; Man, Ho-Wing; Tsang, Shik Chi Edman; Wong, Kwok-Yin

2015-05-06

Copper-based chalcogenides of earth-abundant elements have recently arisen as an alternate material for solar energy conversion. Cu2FeSnS4 (CITS), a quaternary chalcogenide that has received relatively little attention, has the potential to be developed into a low-cost and environmentlly friendly material for photovoltaics and photocatalysis. Herein, we report, for the first time, the synthesis, characterization, and growth mechanism of novel Au/CITS core-shell nanostructures with controllable morphology. Precise manipulations in the core-shell dimensions are demonstrated to yield two distinct heterostructures with spherical and multipod gold nanoparticle (NP) cores (Au(sp)/CITS and Au(mp)/CITS). In photocatalytic hydrogen generation with as-synthesized Au/CITS NPs, the presence of Au cores inside the CITS shell resulted in higher hydrogen generation rates, which can be attributed to the surface plasmon resonance (SPR) effect. The Au(sp)/CITS and Au(mp)/CITS core-shell NPs enhanced the photocatalytic hydrogen generation by about 125% and 240%, respectively, compared to bare CITS NPs.

Equilibium and Stability of Spherical Vlasov Systems

NASA Astrophysics Data System (ADS)

Barnes, D. C.; Chacon, L.; Finn, J. M.

2002-04-01

Collisionless systems with inverse square interaction potentials and possible background confining potentials are considered for the case of spherical symmetry and in the Vlasov limit. The equilibrium is the most general, with single-particle distribution function dependence on both total energy E and total angular momentum L. A new formulation of the full integral-equation stability problem is developed. For a general spherical harmonic perturbation potential, the 3D stability problem is reduced to a 2D problem in an arbitrary central plane of motion, then to a small number of coupled 1D problems involving only the radius. Normal modes depend only on the total mode number l, as is shown directly by this new formulation, with all m degenerate. This method has been used for the Coulomb (repulsive) case.[1] An equilibrium family with uniform central (electron) density is found, and the low-frequency response computed to show that these solutions may provide stable confinement of a massive second (ion) species. These methods may be applied to a particle bunch in the beam frame, and some stability results appropriate to this case are presented. Application to the gravitational (attractive) case is also described, and some initial analytic results are presented. [1] D. C. Barnes, L. Chacón, J. M. Finn, “Equilibrium and Low-frequency Stability of a Uniform Density, Collisionless, Spherical Vlasov System,” submitted to Phys. of Plasmas (2002).

Calculations of the Sound Scattering of Hyperbolic Frequency Modulated Chirped Pulses from Fluid-filled Spherical Shell Sonar Targets

DTIC Science & Technology

2010-02-01

calculated the target strength of the most intense partial wave, a quantity termed the “effective target strength” by Kaduchak and Loeffler (1998...ed., United States Naval Institute, Annapolis, 417 pp. Kaduchak, G. and Loeffler , C.M. (1998). “Relationship between material parameters and

Plasma Liner Research for MTF at NASA Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Thio, Y. C. F.; Eskridge, R.; Lee, M.; Martin, A.; Smith, J.; Cassibry, J. T.; Wu, S. T.; Kirkpatrick, R. C.; Knapp, C. E.; Turchi, P. J.;

MTF Driven by Plasma Liner Dynamically Formed by the Merging of Plasma Jets: An Overview

NASA Technical Reports Server (NTRS)

Thio, Y. C. Francis; Eskridge, Richard; Martin, Adam; Smith, James; Lee, Michael; Rodgers, Stephen L. (Technical Monitor)

2001-01-01

One approach for standoff delivery of the momentum flux for compressing the target in MTF consists of using a spherical array of plasma jets to form a spherical plasma shell imploding towards the center of a magnetized plasma, a compact toroid (Figure 1). A 3-year experiment (PLX-1) to explore the physics of forming a 2-D plasma liner (shell) by merging plasma jets is described. An overview showing how this 3-year project (PLX-1) fits into the program plan at the national and international level for realizing MTF for energy and propulsion is discussed. Assuming that there will be a parallel program in demonstrating and establishing the underlying physics principles of MTF using whatever liner is appropriate (e.g. a solid liner) with a goal of demonstrating breakeven by 2010, the current research effort at NASA MSFC attempts to complement such a program by addressing the issues of practical embodiment of MTF for propulsion. Successful conclusion of PLX-1 will be followed by a Physics Feasibility Experiment (PLX-2) for the Plasma Liner Driven MTF.

Spherical crystals in dusty plasmas - Simulation and theory

NASA Astrophysics Data System (ADS)

Bonitz, M.; Henning, C.; Golubnychiy, V.; Baumgartner, H.; Ludwig, P.; Arp, O.; Block, D.; Piel, A.; Melzer, A.; Kraeft, W. D.

2006-10-01

Coulomb crystals in spherically symmetric traps have been found in trapped cold ions and, recently, in dusty plasmas at room temperature [1] allowing for precision measurements, including individual particle positions and trajectories. Thus, for the first time, strong correlation phenomena can be studied directly on the microscopic level which allows for detailed comparisons with theoretical results and computer simulations. We present molecular dynamics and Monte Carlo simulations of Coulomb crystals in the range from 10 to 10,000 particles which agree very well with the measurements [3]. The results include the ground state shell configurations and symmetry properties [2,3], the crystal stability and melting behavior. Finally, a thermodynamic theory is developed and compared to simpler models, such as shell models [4]. [1] O. Arp, D. Block, A. Piel, and A. Melzer, Phys. Rev. Lett. 93, 165004 (2004). [2] P. Ludwig, S. Kosse, and M. Bonitz, Phys. Rev. E 71, 046403 (2005). [3] M. Bonitz, D. Block, O. Arp, V. Golubnychiy, H. Baumgartner, P. Ludwig, A. Piel, and A. Filinov, Phys. Rev. Lett. 96, 075001 (2006). [4] C. Henning et al., submitted for publication.

De novo modeling of the F420-reducing [NiFe]-hydrogenase from a methanogenic archaeon by cryo-electron microscopy

PubMed Central

Mills, Deryck J; Vitt, Stella; Strauss, Mike; Shima, Seigo; Vonck, Janet

2013-01-01

Methanogenic archaea use a [NiFe]-hydrogenase, Frh, for oxidation/reduction of F420, an important hydride carrier in the methanogenesis pathway from H2 and CO2. Frh accounts for about 1% of the cytoplasmic protein and forms a huge complex consisting of FrhABG heterotrimers with each a [NiFe] center, four Fe-S clusters and an FAD. Here, we report the structure determined by near-atomic resolution cryo-EM of Frh with and without bound substrate F420. The polypeptide chains of FrhB, for which there was no homolog, was traced de novo from the EM map. The 1.2-MDa complex contains 12 copies of the heterotrimer, which unexpectedly form a spherical protein shell with a hollow core. The cryo-EM map reveals strong electron density of the chains of metal clusters running parallel to the protein shell, and the F420-binding site is located at the end of the chain near the outside of the spherical structure. DOI: http://dx.doi.org/10.7554/eLife.00218.001 PMID:23483797

Study of SHE at SHIP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hofmanna, Sigurd; Institut fuer Kernphysik, Goethe-Universitaet Frankfurt, Max von Laue-Strasse 1, 60438 Frankfurt am Main

2010-06-01

The nuclear shell model predicts that the next doubly magic shell-closure beyond {sup 208}Pb is at a proton number Z = 114, 120, or 126 and at a neutron number N = 184. The outstanding aim of experimental investigations is the exploration of this region of spherical 'SuperHeavy Elements'(SHEs). Experimental methods are described, which allowed for the identification of elements produced on a cross-section level of about 1 pb. Reactions used at SHIP are based on targets of lead and uranium. The decay data reveal that for the heaviest elements, the dominant decay mode is alpha emission, not fission. Decaymore » properties as well as reaction cross-sections are compared with results obtained at other laboratories and with results of theoretical investigations. Finally, plans are presented for the further development of the experimental set-up and the application of new techniques, as for instance the precise mass measurement of the produced nuclei using ion traps. At increased sensitivity, detailed exploration of the region of spherical SHEs will start, after first steps on the island of SHEs were made in recent years.« less

Studies of SHE at SHIP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hofmann, Sigurd; Institut fuer Kernphysik, Goethe-Universitaet Frankfurt, Max von Laue-Strasse 1, 60438 Frankfurt am Main

2010-04-30

The nuclear shell model predicts that the next doubly magic shell-closure beyond {sup 208}Pb is at a proton number Z = 114, 120, or 126 and at a neutron number N = 184. The outstanding aim of experimental investigations is the exploration of this region of spherical 'Super-Heavy Elements'(SHEs). Experimental methods are described, which allowed for the identification of elements produced on a cross-section level of about 1 pb. Reactions used at SHIP are based on targets of lead and uranium. The decay data reveal that for the heaviest elements, the dominant decay mode is alpha emission, not fission. Decaymore » properties as well as reaction cross-sections are compared with results obtained at other laboratories and with results of theoretical investigations. Finally, plans are presented for the further development of the experimental setup and the application of new techniques, as for instance the precise mass measurement of the produced nuclei using ion traps. At increased sensitivity, detailed exploration of the region of spherical SHEs will start, after first steps on the island of SHEs were made in recent years.« less

CONSISTENT SCALING LAWS IN ANELASTIC SPHERICAL SHELL DYNAMOS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yadav, Rakesh K.; Gastine, Thomas; Christensen, Ulrich R.

2013-09-01

Numerical dynamo models always employ parameter values that differ by orders of magnitude from the values expected in natural objects. However, such models have been successful in qualitatively reproducing properties of planetary and stellar dynamos. This qualitative agreement fuels the idea that both numerical models and astrophysical objects may operate in the same asymptotic regime of dynamics. This can be tested by exploring the scaling behavior of the models. For convection-driven incompressible spherical shell dynamos with constant material properties, scaling laws had been established previously that relate flow velocity and magnetic field strength to the available power. Here we analyzemore » 273 direct numerical simulations using the anelastic approximation, involving also cases with radius-dependent magnetic, thermal, and viscous diffusivities. These better represent conditions in gas giant planets and low-mass stars compared to Boussinesq models. Our study provides strong support for the hypothesis that both mean velocity and mean magnetic field strength scale as a function of the power generated by buoyancy forces in the same way for a wide range of conditions.« less

Analytical study of the acoustic field in a spherical resonator for single bubble sonoluminescence.

PubMed

Dellavale, Damián; Urteaga, Raúl; Bonetto, Fabián J

2010-01-01

The acoustic field in the liquid within a spherical solid shell is calculated. The proposed model takes into account Stoke's wave equation in the viscous fluid, the membrane theory to describe the solid shell motion and the energy loss through the external couplings of the system. A point source at the resonator center is included to reproduce the acoustic emission of a sonoluminescence bubble. Particular calculations of the resulting acoustic field are performed for viscous liquids of interest in single bubble sonoluminescence. The model reveals that in case of radially symmetric modes of low frequency, the quality factor is mainly determined by the acoustic energy flowing through the mechanical coupling of the resonator. Alternatively, for high frequency modes the quality factor is mainly determined by the viscous dissipation in the liquid. Furthermore, the interaction between the bubble acoustic emission and the resonator modes is analyzed. It was found that the bubble acoustic emission produces local maxima in the resonator response. The calculated amplitudes and relative phases of the harmonics constituting the bubble acoustic environment can be used to improve multi-frequency driving in sonoluminescence.

Sonochemical synthesis of silica particles and their size control

NASA Astrophysics Data System (ADS)

Kim, Hwa-Min; Lee, Chang-Hyun; Kim, Bonghwan

2016-09-01

Using an ultrasound-assisted sol-gel method, we successfully synthesized very uniformly shaped, monodisperse, and size-controlled spherical silica particles from a mixture of ethanol, water, and tetraethyl orthosilicate in the presence of ammonia as catalyst, at room temperature. The diameters of the silica particles were distributed in the range from 40 to 400 nm; their morphology was well characterized by scanning electron microscopy. The silica particle size could be adjusted by choosing suitable concentrations of ammonium hydroxide and water, which in turn determined the nucleation and growth rates of the particles during the reaction. This sonochemical-based silica synthesis offers an alternative way to produce spherical silica particles in a relatively short reaction time. Thus, we suggest that this simple, low-cost, and efficient method of preparing uniform silica particles of various sizes will have practical and wide-ranging industrial applicability.

Method for producing solid or hollow spherical particles of chosen chemical composition and of uniform size

DOEpatents

Hendricks, Charles D.

1988-01-01

A method is provided for producing commercially large quantities of high melting temperature solid or hollow spherical particles of a predetermined chemical composition and having a uniform and controlled size distribution. An end (18, 50, 90) of a solid or hollow rod (20, 48, 88) of the material is rendered molten by a laser beam (14, 44, 82). Because of this, there is no possibility of the molten rod material becoming contaminated with extraneous material. In various aspects of the invention, an electric field is applied to the molten rod end (18, 90), and/or the molten rod end (50, 90) is vibrated. In a further aspect of the invention, a high-frequency component is added to the electric field applied to the molten end of the rod (90). By controlling the internal pressure of the rod, the rate at which the rod is introduced into the laser beam, the environment of the process, the vibration amplitude and frequency of the molten rod end, the electric field intensity applied to the molten rod end, and the frequency and intensity of the component added to the electric field, the uniformity and size distribution of the solid or hollow spherical particles (122) produced by the inventive method is controlled. The polarity of the electric field applied to the molten rod end can be chosen to eliminate backstreaming electrons, which tend to produce run-away heating in the rod, from the process.

Elastic Solutions in a Semi-Infinite Solid with an Ellipsoidal Inclusion

DTIC Science & Technology

1990-01-25

the free surface has been solved for a spherical inclusion with pure dilatational eigenstrain ( stress free transformation strain ) ( Mindlin and Cheng...1950B ), an ellipsoidal inclusion with pure dilatational eigenstrains ( Seo and Mura, 1979 ) and a cuboidal inclusion with uniform eigenstrains ...solution of a half-space under normal surface traction on the full space solution due to a cuboidal inclusion and its image with the uniform eigenstrains

Fabrication of slender elastic shells by the coating of curved surfaces

NASA Astrophysics Data System (ADS)

Lee, A.; Brun, P.-T.; Marthelot, J.; Balestra, G.; Gallaire, F.; Reis, P. M.

2016-04-01

Various manufacturing techniques exist to produce double-curvature shells, including injection, rotational and blow molding, as well as dip coating. However, these industrial processes are typically geared for mass production and are not directly applicable to laboratory research settings, where adaptable, inexpensive and predictable prototyping tools are desirable. Here, we study the rapid fabrication of hemispherical elastic shells by coating a curved surface with a polymer solution that yields a nearly uniform shell, upon polymerization of the resulting thin film. We experimentally characterize how the curing of the polymer affects its drainage dynamics and eventually selects the shell thickness. The coating process is then rationalized through a theoretical analysis that predicts the final thickness, in quantitative agreement with experiments and numerical simulations of the lubrication flow field. This robust fabrication framework should be invaluable for future studies on the mechanics of thin elastic shells and their intrinsic geometric nonlinearities.

An experimental determination of the drag coefficient of a Mens 8+ racing shell.

PubMed

Buckmann, James G; Harris, Samuel D

2014-01-01

This study centered around an experimental analysis of a Mens Lightweight Eight racing shell and, specifically, determining an approximation for the drag coefficient. A testing procedure was employed that used a Global Positioning System (GPS) unit in order to determine the acceleration and drag force on the shell, and through calculations yield a drag coefficient. The testing was run over several days in numerous conditions, and a 95% confidence interval was established to capture the results. The results obtained, over these varying trials, maintained a successful level of consistency. The significance of this study transcends the determination an approximation for the drag coefficient of the racing shell; it defined a successful means of quantifying performance of the shell itself. The testing procedures outlined in the study represent a uniform means of evaluating the factors that influence drag on the shell, and thus influence speed.

Buckling analysis of Big Dee Vacuum Vessel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lightner, S.; Gallix, R.

1983-12-01

A simplified three-dimensional shell buckling analysis of the GA Technologies Inc., Big Dee Vacuum Vessel (V/V) was performed using the finite element program TRICO. A coarse-mesh linear elastic model, which accommodated the support boundary conditions, was used to determine the buckling mode shape under a uniform external pressure. Using this buckling mode shape, refined models were used to calculate the linear buckling load (P/sub crit/) more accurately. Several different designs of the Big Dee V/V were considered in this analysis. The supports for the V/V were equally-spaced radial pins at the outer diameter of the mid-plane. For all the casesmore » considered, the buckling mode was axisymmetric in the toroidal direction. Therefore, it was possible to use only a small angular sector of a toric shell for the refined analysis. P/sub crit/ for the Big Dee is about 60 atm for a uniform external pressure. Also investigated in this analysis were the effects of geometrical imperfections and non-uniform pressure distributions.« less

LDH nanocages synthesized with MOF templates and their high performance as supercapacitors

NASA Astrophysics Data System (ADS)

Jiang, Zhen; Li, Zhengping; Qin, Zhenhua; Sun, Haiyan; Jiao, Xiuling; Chen, Dairong

2013-11-01

Layered double hydroxides (LDHs) are currently attracting intense research interest for their various applications. Three LDH hollow nano-polyhedra are synthesized with zeolitic imidazolate framework-67 (ZIF-67) nanocrystals as the templates. The nanocages well inherit the rhombic dodecahedral shape of the ZIF-67 templates, and the shell is composed of nanosheets assembled with an edge-to-face stacking. This is the first synthesis of the LDH non-spherical structures. And the mechanism of utilizing metal-organic framework (MOF) nanocrystals as templates is explored. Control of the simultaneous reactions, the precipitation of the shells and the template etching, is extremely crucial to the preparation of the perfect nanocages. And the Ni-Co LDH nanocages exhibit superior pseudocapacitance property due to their novel hierarchical and submicroscopic structures.Layered double hydroxides (LDHs) are currently attracting intense research interest for their various applications. Three LDH hollow nano-polyhedra are synthesized with zeolitic imidazolate framework-67 (ZIF-67) nanocrystals as the templates. The nanocages well inherit the rhombic dodecahedral shape of the ZIF-67 templates, and the shell is composed of nanosheets assembled with an edge-to-face stacking. This is the first synthesis of the LDH non-spherical structures. And the mechanism of utilizing metal-organic framework (MOF) nanocrystals as templates is explored. Control of the simultaneous reactions, the precipitation of the shells and the template etching, is extremely crucial to the preparation of the perfect nanocages. And the Ni-Co LDH nanocages exhibit superior pseudocapacitance property due to their novel hierarchical and submicroscopic structures. Electronic supplementary information (ESI) available: Experimental details, XRD, TEM, SEM, and XPS images. See DOI: 10.1039/c3nr03829g

Determination of the structure and composition of Au-Ag bimetallic spherical nanoparticles using single particle ICP-MS measurements performed with normal and high temporal resolution.

PubMed

Kéri, Albert; Kálomista, Ildikó; Ungor, Ditta; Bélteki, Ádám; Csapó, Edit; Dékány, Imre; Prohaska, Thomas; Galbács, Gábor

2018-03-01

In this study, the information that can be obtained by combining normal and high resolution single particle ICP-MS (spICP-MS) measurements for spherical bimetallic nanoparticles (BNPs) was assessed. One commercial certified core-shell Au-Ag nanoparticle and three newly synthesized and fully characterized homogenous alloy Au-Ag nanoparticle batches of different composition were used in the experiments as BNP samples. By scrutinizing the high resolution spICP-MS signal time profiles, it was revealed that the width of the signal peak linearly correlates with the diameter of nanoparticles. It was also observed that the width of the peak for same-size nanoparticles is always significantly larger for Au than for Ag. It was also found that it can be reliably determined whether a BNP is of homogeneus alloy or core-shell structure and that, in the case of the latter, the core comprises of which element. We also assessed the performance of several ICP-MS based analytical methods in the analysis of the quantitative composition of bimetallic nanoparticles. Out of the three methods (normal resolution spICP-MS, direct NP nebulization with solution-mode ICP-MS, and solution-mode ICP-MS after the acid dissolution of the nanoparticles), the best accuracy and precision was achieved by spICP-MS. This method allows the determination of the composition with less than 10% relative inaccuracy and better than 3% precision. The analysis is fast and only requires the usual standard colloids for size calibration. Combining the results from both quantitative and structural analyses, the core diameter and shell thickness of core-shell particles can also be calculated. Copyright © 2017 Elsevier B.V. All rights reserved.