Comparison of in-situ measurements and satellite-derived surface emissivity over Italian volcanic areas

NASA Astrophysics Data System (ADS)

Silvestri, Malvina; Musacchio, Massimo; Cammarano, Diego; Fabrizia Buongiorno, Maria; Amici, Stefania; Piscini, Alessandro

2016-04-01

In this work we compare ground measurements of emissivity collected during dedicated fields campaign on Mt. Etna and Solfatara of Pozzuoli volcanoes and acquired by means of Micro-FTIR (Fourier Thermal Infrared spectrometer) instrument with the emissivity obtained by using single ASTER data (Advanced Spaceborne Thermal Emission and Reflection Radiometer, ASTER 05) and the ASTER emissivity map extract from ASTER Global Emissivity Database (GED), released by LP DAAC on April 2, 2014. The database was developed by the National Aeronautics and Space Administration's (NASA) Jet Propulsion Laboratory (JPL), California Institute of Technology. The database includes land surface emissivity derived from ASTER data acquired over the contiguous United States, Africa, Arabian Peninsula, Australia, Europe, and China. Through this analysis we want to investigate the differences existing between the ASTER-GED dataset (average from 2000 to 2008 seasoning independent) and fall in-situ emissivity measurement. Moreover the role of different spatial resolution characterizing ASTER and MODIS, 90mt and 1km respectively, by comparing them with in situ measurements, is analyzed. Possible differences can be due also to the different algorithms used for the emissivity estimation, Temperature and Emissivity Separation algorithm for ASTER TIR band( Gillespie et al, 1998) and the classification-based emissivity method (Snyder and al, 1998) for MODIS. Finally land surface temperature products generated using ASTER-GED and ASTER 05 emissivity are also analyzed. Gillespie, A. R., Matsunaga, T., Rokugawa, S., & Hook, S. J. (1998). Temperature and emissivity separation from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images. IEEE Transactions on Geoscience and Remote Sensing, 36, 1113-1125. Snyder, W.C., Wan, Z., Zhang, Y., & Feng, Y.-Z. (1998). Classification-based emissivity for land surface temperature measurement from space. International Journal of Remote Sensing, 19, 2753-2574.

Elevated Ozone in the Troposphere over the Atlantic and Pacific Oceans in the Northern Hemisphere

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Tie, Xuexi

2003-01-01

Tropospheric column ozone (TCO) is derived from differential measurements of total column ozone from Nimus-7 and Earth Probe TOMS, and stratospheric column ozone from the Microwave Limb Sounder instrument on the Upper Atmospheric Research Satellite. It is shown that TCO during summer months over the Atlantic and Pacific Oceans at northern mid-latitudes is about the same (50-60 Dobson Units) as over the continents of North America, Europe and Asia, where surface emissions of nitrogen oxides from industrial sources, biomass and biofuel burning and biogenic emissions are significantly larger. This nearly uniform zonal variation in TCO is modulated by surface topography of the Rocky and Himalayan mountains and Tibetan Plateau where TCO is reduced by 20-30 Dobson Units. The zonal characteristics of TCO derived from satellite measurements are well simulated by a global chemical transport model called MOZART-2 (Model of Ozone and Related Chemical Tracers, version 2). The model results are analyzed to delineate the relative importance of various processes contributing to observed zonal characteristics of TCO, and they are shown that the surface emission of NOx contributes about 50% of the TCO at northern mid-latitudes, especially over the continents of North America, Europe and Asia. The result of TCO derived from TOMS and the analysis from MOZART-2 indicate that TCO is a very useful tool to study tropospheric O3 pollution resulting from surface emissions of pollutants.

Spatial relationships of sector-specific fossil fuel CO2 emissions in the United States

NASA Astrophysics Data System (ADS)

Zhou, Yuyu; Gurney, Kevin Robert

2011-09-01

Quantification of the spatial distribution of sector-specific fossil fuel CO2 emissions provides strategic information to public and private decision makers on climate change mitigation options and can provide critical constraints to carbon budget studies being performed at the national to urban scales. This study analyzes the spatial distribution and spatial drivers of total and sectoral fossil fuel CO2 emissions at the state and county levels in the United States. The spatial patterns of absolute versus per capita fossil fuel CO2 emissions differ substantially and these differences are sector-specific. Area-based sources such as those in the residential and commercial sectors are driven by a combination of population and surface temperature with per capita emissions largest in the northern latitudes and continental interior. Emission sources associated with large individual manufacturing or electricity producing facilities are heterogeneously distributed in both absolute and per capita metrics. The relationship between surface temperature and sectoral emissions suggests that the increased electricity consumption due to space cooling requirements under a warmer climate may outweigh the savings generated by lessened space heating. Spatial cluster analysis of fossil fuel CO2 emissions confirms that counties with high (low) CO2 emissions tend to be clustered close to other counties with high (low) CO2 emissions and some of the spatial clustering extends to multistate spatial domains. This is particularly true for the residential and transportation sectors, suggesting that emissions mitigation policy might best be approached from the regional or multistate perspective. Our findings underscore the potential for geographically focused, sector-specific emissions mitigation strategies and the importance of accurate spatial distribution of emitting sources when combined with atmospheric monitoring via aircraft, satellite and in situ measurements.

Interannual Variability of Ammonia Concentrations over the United States: Sources and Implications for Inorganic Particulate Matter

NASA Astrophysics Data System (ADS)

Schiferl, L. D.; Heald, C. L.; Van Damme, M.; Pierre-Francois, C.; Clerbaux, C.

2015-12-01

Modern agricultural practices have greatly increased the emission of ammonia (NH3) to the atmosphere. Recent controls to reduce the emissions of sulfur and nitrogen oxides (SOX and NOX) have increased the importance of understanding the role ammonia plays in the formation of surface fine inorganic particulate matter (PM2.5) in the United States. In this study, we identify the interannual variability in ammonia concentration, explore the sources of this variability and determine their contribution to the variability in surface PM2.5 concentration. Over the summers of 2008-2012, measurements from the Ammonia Monitoring Network (AMoN) and the Infrared Atmospheric Sounding Interferometer (IASI) satellite instrument show considerable variability in both surface and column ammonia concentrations (+/- 29% and 28% of the mean), respectively. This observed variability is larger than that simulated by the GEOS-Chem chemical transport model, where meteorology dominates the variability in ammonia and PM2.5 concentrations compared to the changes caused by SOX and NOX reductions. Our initial simulation does not include year-to-year changes in ammonia agricultural emissions. We use county-wide information on fertilizer sales and livestock populations, as well as meteorological variations to account for the interannual variability in agricultural activity and ammonia volatilization. These sources of ammonia emission variability are important for replicating observed variations in ammonia and PM2.5, highlighting how accurate ammonia emissions characterization is central to PM air quality prediction.

Martian Surface Compositions and Spectral Unit Mapping From the Thermal Emission Imaging System

NASA Astrophysics Data System (ADS)

Bandfield, J. L.; Christensen, P. R.; Rogers, D.

2005-12-01

The Thermal Emission Imaging System (THEMIS) on board the Mars Odyssey spacecraft observes Mars at nine spectral intervals between 6 and 15 microns and at 100 meter spatial sampling. This spectral and spatial resolution allows for mapping of local spectral units and coarse compositional determination of a variety of rock-forming materials such as carbonates, sulfates, and silicates. A number of data processing and atmospheric correction techniques have been developed to ease and speed the interpretation of multispectral THEMIS infrared images. These products and techniques are in the process of being made publicly available via the THEMIS website and were used to produce the results presented here. Spectral variability at kilometer scales in THEMIS data is more common in the southern highlands than in the northern lowlands. Many of the spectral units are associated with a mobile surface layer such as dune fields and mantled dust. However, a number of spectral units appear to be directly tied to the local geologic rock units. These spectral units are commonly associated with crater walls, floors, and ejecta blankets. Other surface compositions are correlated with layered volcanic materials and knobby remnant terrains. Most of the spectral variability observed to date appears to be tied to a variation in silicate mineralogy. Olivine rich units that have been previously reported in Nili Fossae, Ares Valles, and the Valles Marineris region appear to be sparse but common in a number of regions in the southern highlands. Variations in silica content consistent with previously reported global surface units also appear to be present in THEMIS images, allowing for an examination of their local geologic context. Previously reported quartz and feldspar rich exposures in northern Syrtis Major appear more extensive in the region than previously reported. A coherent global and local picture of the mineralogy of the Martian surface is emerging from THEMIS measurements along with other orbital thermal and near infrared spectroscopy measurements from the Mars Express and Mars Global Surveyor spacecraft.

Surface Ozone Background in the United States: Canadian and Mexican Pollution Influences

EPA Science Inventory

We use a global chemical transport model (GEOS-Chem) with 1° x 1° horizontal resolution to quantify the effects of anthropogenic emissions from Canada, Mexico, and outside North America on daily maximum 8-h average ozone concentrations in U.S.surface air.

SO2 Emissions and Lifetimes: Estimates from Inverse Modeling Using In Situ and Global, Space-Based (SCIAMACHY and OMI) Observations

NASA Technical Reports Server (NTRS)

Lee, Chulkyu; Martin Randall V.; vanDonkelaar, Aaron; Lee, Hanlim; Dickerson, RUssell R.; Hains, Jennifer C.; Krotkov, Nickolay; Richter, Andreas; Vinnikov, Konstantine; Schwab, James J.

2011-01-01

Top-down constraints on global sulfur dioxide (SO2) emissions are inferred through inverse modeling using SO2 column observations from two satellite instruments (SCIAMACHY and OMI). We first evaluated the S02 column observations with surface SO2 measurements by applying local scaling factors from a global chemical transport model (GEOS-Chem) to SO2 columns retrieved from the satellite instruments. The resulting annual mean surface SO2 mixing ratios for 2006 exhibit a significant spatial correlation (r=0.86, slope=0.91 for SCIAMACHY and r=0.80, slope = 0.79 for OMI) with coincident in situ measurements from monitoring networks throughout the United States and Canada. We evaluate the GEOS-Chem simulation of the SO2 lifetime with that inferred from in situ measurements to verity the applicability of GEOS-Chem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS-Chem model over the eastern United States is 13 h in summer and 48 h in winter, compared to lifetimes inferred from in situ measurements of 19 +/- 7 h in summer and 58 +/- 20 h in winter. We apply SO2 columns from SCIAMACHY and OMI to derive a top-down anthropogenic SO2 emission inventory over land by using the local GEOS-Chem relationship between SO2 columns and emissions. There is little seasonal variation in the top-down emissions (<15%) over most major industrial regions providing some confidence in the method. Our global estimate for annual land surface anthropogenic SO2 emissions (52.4 Tg S/yr from SCIAMACHY and 49.9 Tg S / yr from OMI) closely agrees with the bottom-up emissions (54.6 Tg S/yr) in the GEOS-Chem model and exhibits consistency in global distributions with the bottom-up emissions (r = 0.78 for SCIAMACHY, and r = 0.77 for OMI). However, there are significant regional differences.

China's international trade and air pollution in the United States.

PubMed

Lin, Jintai; Pan, Da; Davis, Steven J; Zhang, Qiang; He, Kebin; Wang, Can; Streets, David G; Wuebbles, Donald J; Guan, Dabo

2014-02-04

China is the world's largest emitter of anthropogenic air pollutants, and measurable amounts of Chinese pollution are transported via the atmosphere to other countries, including the United States. However, a large fraction of Chinese emissions is due to manufacture of goods for foreign consumption. Here, we analyze the impacts of trade-related Chinese air pollutant emissions on the global atmospheric environment, linking an economic-emission analysis and atmospheric chemical transport modeling. We find that in 2006, 36% of anthropogenic sulfur dioxide, 27% of nitrogen oxides, 22% of carbon monoxide, and 17% of black carbon emitted in China were associated with production of goods for export. For each of these pollutants, about 21% of export-related Chinese emissions were attributed to China-to-US export. Atmospheric modeling shows that transport of the export-related Chinese pollution contributed 3-10% of annual mean surface sulfate concentrations and 0.5-1.5% of ozone over the western United States in 2006. This Chinese pollution also resulted in one extra day or more of noncompliance with the US ozone standard in 2006 over the Los Angeles area and many regions in the eastern United States. On a daily basis, the export-related Chinese pollution contributed, at a maximum, 12-24% of sulfate concentrations over the western United States. As the United States outsourced manufacturing to China, sulfate pollution in 2006 increased in the western United States but decreased in the eastern United States, reflecting the competing effect between enhanced transport of Chinese pollution and reduced US emissions. Our findings are relevant to international efforts to reduce transboundary air pollution.

National housing and impervious surface scenarios for integrated climate impact assessments

PubMed Central

Bierwagen, Britta G.; Theobald, David M.; Pyke, Christopher R.; Choate, Anne; Groth, Philip; Thomas, John V.; Morefield, Philip

2010-01-01

Understanding the impacts of climate change on people and the environment requires an understanding of the dynamics of both climate and land use/land cover changes. A range of future climate scenarios is available for the conterminous United States that have been developed based on widely used international greenhouse gas emissions storylines. Climate scenarios derived from these emissions storylines have not been matched with logically consistent land use/cover maps for the United States. This gap is a critical barrier to conducting effective integrated assessments. This study develops novel national scenarios of housing density and impervious surface cover that are logically consistent with emissions storylines. Analysis of these scenarios suggests that combinations of climate and land use/cover can be important in determining environmental conditions regulated under the Clean Air and Clean Water Acts. We found significant differences in patterns of habitat loss and the distribution of potentially impaired watersheds among scenarios, indicating that compact development patterns can reduce habitat loss and the number of impaired watersheds. These scenarios are also associated with lower global greenhouse gas emissions and, consequently, the potential to reduce both the drivers of anthropogenic climate change and the impacts of changing conditions. The residential housing and impervious surface datasets provide a substantial first step toward comprehensive national land use/land cover scenarios, which have broad applicability for integrated assessments as these data and tools are publicly available. PMID:21078956

Evolution of anthropogenic emissions at the global and regional scale during the past three decades

NASA Astrophysics Data System (ADS)

Granier, C.; Bessagnet, B. B.; Bond, T. C.; D'Angiola, A.; Denier van der Gon, H.; Frost, G. J.; Heil, A.; Kaiser, J.; Kinne, S. A.; Klimont, Z.; Kloster, S.; Lamarque, J.; Liousse, C.; Masui, T.; Meleux, F.; Mieville, A.; Ohara, T.; Raut, J.; Riahi, K.; Schultz, M. G.; Smith, S.; Thomson, A. M.; van Aardenne, J.; van der Werf, G.; van Vuuren, D.

2010-12-01

The knowledge of the distributions of surface emissions of gases and aerosols is essential for an accurate modeling and analysis of the distribution and evolution of the concentration of gaseous and particulate chemical species. The quantification of surface fluxes by source of origin is furthermore central to the assessment of effects and the development of control measures. Over the past few years, different ranges of emission fluxes have been proposed by several studies, which have provided emissions at different spatial and temporal scales. We have compared the emissions of several chemical compounds, i.e. carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon, as provided by global and regional emissions inventories in different regions of the world for the past thirty years. The presentation will focus on the United States, Europe and China. Significant differences between the datasets providing emissions in these regions have been identified, reaching for example 60% and 35% for anthropogenic emissions of carbon monoxide and nitrogen oxides in both regions, respectively. We will assess the current uncertainties on surface emissions and their recent trends. This analysis is often hindered because of differences in base years and in species considered in the different datasets. Current work aiming at compiling comparable metrics for such species for the analysis of regional and global emission datasets will be discussed.

Effect of temperature and humidity on formaldehyde emissions in temporary housing units.

PubMed

Parthasarathy, Srinandini; Maddalena, Randy L; Russell, Marion L; Apte, Michael G

2011-06-01

The effect of temperature and humidity on formaldehyde emissions from samples collected from temporary housing units (THUs) was studied. The THUs were supplied by the U.S. Federal Emergency Management Administration (FEMA) to families that lost their homes in Louisiana and Mississippi during the Hurricane Katrina and Rita disasters. On the basis of a previous study, four of the composite wood surface materials that dominated contributions to indoor formaldehyde were selected to analyze the effects of temperature and humidity on the emission factors. Humidity equilibration experiments were carried out on two of the samples to determine how long the samples take to equilibrate with the surrounding environmental conditions. Small chamber experiments were then conducted to measure emission factors for the four surface materials at various temperature and humidity conditions. The samples were analyzed for formaldehyde via high-performance liquid chromatography. The experiments showed that increases in temperature or humidity contributed to an increase in emission factors. A linear regression model was built using the natural log of the percent relative humidity (RH) and inverse of temperature (in K) as independent variables and the natural log of emission factors as the dependent variable. The coefficients for the inverse of temperature and log RH with log emission factor were found to be statistically significant for all of the samples at the 95% confidence level. This study should assist in retrospectively estimating indoor formaldehyde exposure of occupants of THUs.

Top-down estimates of biomass burning emissions of black carbon in the western United States

Treesearch

Y. H. Mao; Q. B. Li; D. Chen; L. Zhang; W. -M. Hao; K.-N. Liou

2014-01-01

We estimate biomass burning and anthropogenic emissions of black carbon (BC) in the western US for May-October 2006 by inverting surface BC concentrations from the Interagency Monitoring of PROtected Visual Environment (IMPROVE) network using a global chemical transport model. We first use active fire counts from the Moderate Resolution Imaging Spectroradiometer (MODIS...

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

A test program to collect and analyze size-fractionated stack gas particulate samples for selected inorganic hazardous air pollutants (HAPs) was conducted . Specific goals of the program are (1) the collection of one-gram quantities of size-fractionated stack gas particulate matter for bulk (total) and surface chemical characterization, and (2) the determination of the relationship between particle size, bulk and surface (leachable) composition, and unit load. The information obtained from this program identifies the effects of unit load, particle size, and wet FGD system operation on the relative toxicological effects of exposure to particulate emissions. Field testing was conducted in twomore » phases. The Phase I field program was performed over the period of August 24 through September 20, 1992, at the Tennessee Valley Authority Widows Creek Unit 8 Power Station, located near Stevenson (Jackson County), Alabama, on the Tennessee River. Sampling activities for Phase II were conducted from September 11 through October 14, 1993. Widows Creek Unit 8 is a 575-megawatt plant that uses bituminous coal averaging 3.7% sulfur and 13% ash. Downstream of the boiler, a venture wet scrubbing system is used for control of both sulfur dioxide and particulate emissions. There is no electrostatic precipitator (ESP) in this system. This system is atypical and represents only about 5% of the US utility industry. However, this site was chosen for this study because of the lack of information available for this particulate emission control system.« less

Erodibility of and dust emissions from bare soil surfaces in the North American Southwest

USDA-ARS?s Scientific Manuscript database

Native plant communities throughout the Southwestern United States are subject to increased abiotic stress due to climate change. As native grass cover is replaced by shrubs, more bare soil surface is susceptible to erosion by wind. The dust record for the last 20 years indicates that wind erosion...

Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Yuyu; Gurney, Kevin R.

2011-07-01

Quantification of the spatial distribution of sector-specific fossil fuel CO2 emissions provides strategic information to public and private decision-makers on climate change mitigation options and can provide critical constraints to carbon budget studies being performed at the national to urban scales. This study analyzes the spatial distribution and spatial drivers of total and sectoral fossil fuel CO2 emissions at the state and county levels in the United States. The spatial patterns of absolute versus per capita fossil fuel CO2 emissions differ substantially and these differences are sector-specific. Area-based sources such as those in the residential and commercial sectors are drivenmore » by a combination of population and surface temperature with per capita emissions largest in the northern latitudes and continental interior. Emission sources associated with large individual manufacturing or electricity producing facilities are heterogeneously distributed in both absolute and per capita metrics. The relationship between surface temperature and sectoral emissions suggests that the increased electricity consumption due to space cooling requirements under a warmer climate may outweigh the savings generated by lessened space heating. Spatial cluster analysis of fossil fuel CO2 emissions confirms that counties with high (low) CO2 emissions tend to be clustered close to other counties with high (low) CO2 emissions and some of the spatial clustering extends to multi-state spatial domains. This is particularly true for the residential and transportation sectors, suggesting that emissions mitigation policy might best be approached from the regional or multi-state perspective. Our findings underscore the potential for geographically focused, sector-specific emissions mitigation strategies and the importance of accurate spatial distribution of emitting sources when combined with atmospheric monitoring via aircraft, satellite and in situ measurements. Keywords: Fossil-fuel; Carbon dioxide emissions; Sectoral; Spatial cluster; Emissions mitigation policy« less

Impacts of prescribed fires on air quality over the Southeastern United States in spring based on modeling and ground/satellite measurements.

PubMed

Zeng, Tao; Wang, Yuhang; Yoshida, Yasuko; Tian, Di; Russell, Amistead G; Barnard, William R

2008-11-15

Prescribed burning is a large aerosol source in the southeastern United States. Its air quality impact is investigated using 3-D model simulations and analysis of ground and satellite observations. Fire emissions for 2002 are calculated based on a recently developed VISTAS emission inventory. March was selected for the investigation because it is the most active prescribed fire month. Inclusion of fire emissions significantly improved model performance. Model results show that prescribed fire emissions lead to approximately 50% enhancements of mean OC and EC concentrations in the Southeast and a daily increase of PM2.5 up to 25 microg m(-3), indicating that fire emissions can lead to PM2.5 nonattainment in affected regions. Surface enhancements of CO up to 200 ppbv are found. Fire count measurements from the moderate resolution imaging spectroradiometer (MODIS) onboard the NASA Terra satellite show large springtime burning in most states, which is consistent with the emission inventory. These measurements also indicate that the inventory may underestimate fire emissions in the summer.

Causes and consequences of decreasing atmospheric organic aerosol in the United States.

PubMed

Ridley, D A; Heald, C L; Ridley, K J; Kroll, J H

2018-01-09

Exposure to atmospheric particulate matter (PM) exacerbates respiratory and cardiovascular conditions and is a leading source of premature mortality globally. Organic aerosol contributes a significant fraction of PM in the United States. Here, using surface observations between 1990 and 2012, we show that organic carbon has declined dramatically across the entire United States by 25-50%; accounting for more than 30% of the US-wide decline in PM. The decline is in contrast with the increasing organic aerosol due to wildfires and no clear trend in biogenic emissions. By developing a carbonaceous emissions database for the United States, we show that at least two-thirds of the decline in organic aerosol can be explained by changes in anthropogenic emissions, primarily from vehicle emissions and residential fuel burning. We estimate that the decrease in anthropogenic organic aerosol is responsible for averting 180,000 (117,000-389,000) premature deaths between 1990 and 2012. The unexpected decrease in organic aerosol, likely a consequence of the implementation of Clean Air Act Amendments, results in 84,000 (30,000-164,000) more lives saved than anticipated by the EPA between 2000 and 2010.

Causes and consequences of decreasing atmospheric organic aerosol in the United States

NASA Astrophysics Data System (ADS)

Ridley, D. A.; Heald, C. L.; Ridley, K. J.; Kroll, J. H.

2018-01-01

Exposure to atmospheric particulate matter (PM) exacerbates respiratory and cardiovascular conditions and is a leading source of premature mortality globally. Organic aerosol contributes a significant fraction of PM in the United States. Here, using surface observations between 1990 and 2012, we show that organic carbon has declined dramatically across the entire United States by 25–50%; accounting for more than 30% of the US-wide decline in PM. The decline is in contrast with the increasing organic aerosol due to wildfires and no clear trend in biogenic emissions. By developing a carbonaceous emissions database for the United States, we show that at least two-thirds of the decline in organic aerosol can be explained by changes in anthropogenic emissions, primarily from vehicle emissions and residential fuel burning. We estimate that the decrease in anthropogenic organic aerosol is responsible for averting 180,000 (117,000–389,000) premature deaths between 1990 and 2012. The unexpected decrease in organic aerosol, likely a consequence of the implementation of Clean Air Act Amendments, results in 84,000 (30,000–164,000) more lives saved than anticipated by the EPA between 2000 and 2010.

China’s international trade and air pollution in the United States

PubMed Central

Lin, Jintai; Pan, Da; Davis, Steven J.; Zhang, Qiang; He, Kebin; Wang, Can; Streets, David G.; Wuebbles, Donald J.; Guan, Dabo

2014-01-01

China is the world’s largest emitter of anthropogenic air pollutants, and measurable amounts of Chinese pollution are transported via the atmosphere to other countries, including the United States. However, a large fraction of Chinese emissions is due to manufacture of goods for foreign consumption. Here, we analyze the impacts of trade-related Chinese air pollutant emissions on the global atmospheric environment, linking an economic-emission analysis and atmospheric chemical transport modeling. We find that in 2006, 36% of anthropogenic sulfur dioxide, 27% of nitrogen oxides, 22% of carbon monoxide, and 17% of black carbon emitted in China were associated with production of goods for export. For each of these pollutants, about 21% of export-related Chinese emissions were attributed to China-to-US export. Atmospheric modeling shows that transport of the export-related Chinese pollution contributed 3–10% of annual mean surface sulfate concentrations and 0.5–1.5% of ozone over the western United States in 2006. This Chinese pollution also resulted in one extra day or more of noncompliance with the US ozone standard in 2006 over the Los Angeles area and many regions in the eastern United States. On a daily basis, the export-related Chinese pollution contributed, at a maximum, 12–24% of sulfate concentrations over the western United States. As the United States outsourced manufacturing to China, sulfate pollution in 2006 increased in the western United States but decreased in the eastern United States, reflecting the competing effect between enhanced transport of Chinese pollution and reduced US emissions. Our findings are relevant to international efforts to reduce transboundary air pollution. PMID:24449863

Agricultural pesticide emissions associated with common crops in the United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benjey, W.G.

Annual emissions for the year 1987 from the application of agricultural pesticides have been estimated by crop type by county for the United States using a geographic information system. The emissions estimates are based upon computed volatilization rates accounting for the properties of each pesticide, evaporation rates, mode of application (surface or soil incorporation) and percent of interception by leaves. Key pesticide properties include the Henry's Law constant, half-life in soil and the organic carbon partitioning coefficient. The volatilization rates are multiplied by the amount of pesticide applied by crop acreage in each county as determined from agricultural census andmore » pesticide sales data. The geographic distribution of the dominant emissions, such as atrazine and diazinon, etc. are presented by crop type and state. For a given pesticide, the geographic variability is controlled principally by amount applied and water availability as reflected in evaporation rates.« less

Evaluating the Regional Impact of Aircraft Emissions on Climate

NASA Astrophysics Data System (ADS)

Zhang, J.; Wuebbles, D. J.; Khodayari, A.

2017-12-01

Unlike other transportation sectors where pollutant emissions usually occur only near the Earth's surface, aviation emissions happen primarily at altitudes of 8-12 km above the surface, impacting the upper troposphere and the lower stratosphere (UTLS). At these altitudes, the pollutants can contribute significantly to greenhouse gas (GHGs) concentration and to the formation of secondary aerosols, which can have an impact on climate change. This study examines the regional effects on climate forcing resulting from aviation emissions. Most previous studies have focused on aviation effects on climate using globally-averaged metric values, which do not give information about the spatial variability of the effects. While aviation emissions have significant spatial variability in the sign and magnitude of response, the strength of regional effects is hidden due to the global averaging of climate change effects. In this study, the chemistry-climate Community Atmosphere Model (CAM-chem5) is used in analyses to examine the regional climate effects based on 4 different latitude bands (90oS-28oS, 28oS-28oN, 28oN-60oN, 60oN-90oN) and 3 regions (contiguous United States, Europe and East Asia). The most regionally important aviation emissions are short-lived species, such as black carbon (BC) and sulfates, emitted from aircraft directly, and O3-short induced by NOx emission indirectly. The regionality of these short-lived impacts are explored and compared to the globally-averaged effects. The results indicate that BC and sulfates have more regionality than O3. The radiative forcings for short-lived agents over the United States, Europe and East Asia are around 2-4 times of their corresponding global values. The results also suggest that the climate forcings will be the most underestimated over the United States when using globally-averaged values without considering regional heterogeneity.

Multispectral thermal infrared mapping of the 1 October 1988 Kupaianaha flow field, Kilauea volcano, Hawaii

USGS Publications Warehouse

Realmuto, V.J.; Hon, K.; Kahle, A.B.; Abbott, E.A.; Pieri, D.C.

1992-01-01

Multispectral thermal infrared radiance measurements of the Kupaianaha flow field were acquired with the NASA airborne Thermal Infrared Multispectral Scanner (TIMS) on the morning of 1 October 1988. The TIMS data were used to map both the temperature and emissivity of the surface of the flow field. The temperature map depicted the underground storage and transport of lava. The presence of molten lava in a tube or tumulus resulted in surface temperatures that were at least 10?? C above ambient. The temperature map also clearly defined the boundaries of hydrothermal plumes which resulted from the entry of lava into the ocean. The emissivity map revealed the boundaries between individual flow units within the Kupaianaha field. In general, the emissivity of the flows varied systematically with age but the relationship between age and emissivity was not unique. Distinct spectral anomalies, indicative of silica-rich surface materials, were mapped near fumaroles and ocean entry sites. This apparent enrichment in silica may have resulted from an acid-induced leaching of cations from the surfaces of glassy flows. Such incipient alteration may have been the cause for virtually all of the emissivity variations observed on the flow field, the spectral anomalies representing areas where the acid attack was most intense. ?? 1992 Springer-Verlag.

Why do Models Overestimate Surface Ozone in the Southeastern United States?

NASA Astrophysics Data System (ADS)

Travis, K.; Jacob, D.; Fisher, J. A.; Kim, S.; Marais, E. A.; Zhu, L.; Yu, K.; Miller, C. E.; Yantosca, R.; Payer Sulprizio, M.; Thompson, A. M.; Wennberg, P. O.; Crounse, J.; St Clair, J. M.; Cohen, R. C.; Laughner, J.; Dibb, J. E.; Hall, S. R.; Ullmann, K.; Wolfe, G.; Pollack, I. B.; Peischl, J.; Neuman, J. A.; Zhou, X.

2016-12-01

Ozone pollution in the Southeast US involves complex chemistry driven by emissions of anthropogenic nitrogen oxide radicals (NOx = NO + NO2) and biogenic isoprene. Model estimates of surface ozone concentrations tend to be biased high in the region and this is of concern for designing effective emission control strategies to meet air quality standards. We use detailed chemical observations from the SEAC4RS aircraft campaign in August and September 2013, interpreted with the GEOS-Chem chemical transport model at 0.25°×0.3125° horizontal resolution, to better understand the factors controlling surface ozone in the Southeast US. We find that the National Emission Inventory (NEI) for NO­x from the US Environmental Protection Agency (EPA) is too high in the Southeast and nationally by a factor of 2. This finding is based on SEAC4RS observations of NOx and its oxidation products, surface network observations of nitrate wet deposition fluxes, and OMI satellite observations of tropospheric NO2 columns. Upper tropospheric NO2 from lightning makes a large contribution to the satellite observations that must be accounted for when using these data to estimate surface NOx emissions. We find that only half of isoprene oxidation proceeds by the high-NOx pathway to produce ozone; this fraction is only moderately sensitive to changes in NOx emissions because isoprene and NOx emissions are spatially segregated. GEOS-Chem with reduced NOx emissions provides an unbiased simulation of ozone observations from the aircraft, and reproduces the observed ozone production efficiency in the boundary layer as derived from a regression of ozone and NOx oxidation products. However, the model is still biased high by 8±13 ppb relative to observed surface ozone in the Southeast US. Ozonesondes launched during midday hours show a 7 ppb ozone decrease from 1.5 km to the surface that GEOS-Chem does not capture. This may be caused by excessively dry conditions in the model, representing another factor important in the simulation of surface ozone.

Elevated Tropospheric Ozone over the Atlantic

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Tie, X.

2003-01-01

Tropospheric column ozone (TCO) is derived from differential measurements of TOMS total column ozone and Microwave Limb Sounder stratospheric column ozone. It is shown that TCO during summer months over the Atlantic and Pacific Oceans in northern midlatitudes is about the same (50 to 60 Dobson Units) as over the continents of North America, Europe, and Asia, where surface emissions of nitrogen oxides from industrial sources, biomass and biofuel burning and biogenic emissions are significantly larger. This nearly uniform zonal variation in TCO is modulated by surface topography of the Rocky and Himalayan mountains, and Tibetan plateau where TCO is reduced by 20 to 30 Dobson Units. The zonal variation in TCO is well simulated by a global chemical transport model called MOZART-2 (Model of Ozone and Related Chemical Tracers, version 2). The model results are analyzed to delineate the relative importance of various processes contributing to observed zonal characteristics of TCO.

Impacts of volcanic gases on climate, the environment, and people

USGS Publications Warehouse

McGee, Kenneth A.; Doukas, Michael P.; Kessler, Richard; Gerlach, Terrence M.

1997-01-01

Gases from volcanoes give rise to numerous impacts on climate, the environment, and people. U.S. Geological Survey (USGS) scientists are inventorying gas emissions at many of the almost 70 active volcanoes in the United States. This effort helps build a better understanding of the dynamic processes at work on the Earth's surface and is contributing important new information on how volcanic emissions affect global change.

Aerosols from fires: an examination of the effects on ozone photochemistry in the Western United States.

PubMed

Jiang, Xiaoyan; Wiedinmyer, Christine; Carlton, Annmarie G

2012-11-06

This study presents a first attempt to investigate the roles of fire aerosols in ozone (O(3)) photochemistry using an online coupled meteorology-chemistry model, the Weather Research and Foresting model with Chemistry (WRF-Chem). Four 1-month WRF-Chem simulations for August 2007, with and without fire emissions, were carried out to assess the sensitivity of O(3) predictions to the emissions and subsequent radiative feedbacks associated with large-scale fires in the Western United States (U.S.). Results show that decreases in planetary boundary layer height (PBLH) resulting from the radiative effects of fire aerosols and increases in emissions of nitrogen oxides (NO(x)) and volatile organic compounds (VOCs) from the fires tend to increase modeled O(3) concentrations near the source. Reductions in downward shortwave radiation reaching the surface and surface temperature due to fire aerosols cause decreases in biogenic isoprene emissions and J(NO(2)) photolysis rates, resulting in reductions in O(3) concentrations by as much as 15%. Thus, the results presented in this study imply that considering the radiative effects of fire aerosols may reduce O(3) overestimation by traditional photochemical models that do not consider fire-induced changes in meteorology; implementation of coupled meteorology-chemistry models are required to simulate the atmospheric chemistry impacted by large-scale fires.

Can dust emission mechanisms be determined from field measurements?

NASA Astrophysics Data System (ADS)

Klose, Martina; Webb, Nicholas; Gill, Thomas E.; Van Pelt, Scott; Okin, Gregory

2017-04-01

Field observations are needed to develop and test theories on dust emission for use in dust modeling systems. The dust emission mechanism (aerodynamic entrainment, saltation bombardment, aggregate disintegration) as well as the amount and particle-size distribution of emitted dust may vary under sediment supply- and transport-limited conditions. This variability, which is caused by heterogeneity of the surface and the atmosphere, cannot be fully captured in either field measurements or models. However, uncertainty in dust emission modeling can be reduced through more detailed observational data on the dust emission mechanism itself. To date, most measurements do not provide enough information to allow for a determination of the mechanisms leading to dust emission and often focus on a small variety of soil and atmospheric settings. Additionally, data sets are often not directly comparable due to different measurement setups. As a consequence, the calibration of dust emission schemes has so far relied on a selective set of observations, which leads to an idealization of the emission process in models and thus affects dust budget estimates. Here, we will present results of a study which aims to decipher the dust emission mechanism from field measurements as an input for future model development. Detailed field measurements are conducted, which allow for a comparison of dust emission for different surface and atmospheric conditions. Measurements include monitoring of the surface, loose erodible material, transported sediment, and meteorological data, and are conducted in different environmental settings in the southwestern United States. Based on the field measurements, a method is developed to differentiate between the different dust emission mechanisms.

Molecular modeling of field-driven ion emission from ionic liquids

NASA Astrophysics Data System (ADS)

Zhang, Fei; He, Yadong; Qiao, Rui

2017-11-01

Traditionally, operating electrosprays in the purely ionic mode is challenging, but recent experiments confirmed that such operation can be achieved using room-temperature ionic liquids as working electrolytes. Such electrosprays have shown promise in applications including chemical analysis, nanomanufacturing, and space propulsion. The mechanistic and quantitative understanding of such electrosprays at the molecular level, however, remain limited at present. In this work, we simulated ion emission from EMIM-PF6 ionic liquid films using the molecular dynamics method. We show that, when the surface electric field is smaller than 1.5V/nm, the ion emission current predicted using coarse-grained ionic liquid model observes the classical scaling law by J. V. Iribarne and B. A. Thomson, i.e., ln(Je/ σ) En1/2. These simulations, however, cannot capture the co-emission of cations and anions from ionic liquid surface observed in some experiments. Such co-emission was successfully captured when united-atom models were adopted for the ionic liquids. By examining the co-emission events with picosecond, sub-angstrom resolution, we clarified the origins of the co-emission phenomenon and delineate the molecular events leading to ion emission.

Why do Models Overestimate Surface Ozone in the Southeastern United States?

NASA Technical Reports Server (NTRS)

Travis, Katherine R.; Jacob, Daniel J.; Fisher, Jenny A.; Kim, Patrick S.; Marais, Eloise A.; Zhu, Lei; Yu, Karen; Miller, Christopher C.; Yantosca, Robert M.; Sulprizio, Melissa P.;

Why do models overestimate surface ozone in the Southeast United States?

NASA Astrophysics Data System (ADS)

Travis, Katherine R.; Jacob, Daniel J.; Fisher, Jenny A.; Kim, Patrick S.; Marais, Eloise A.; Zhu, Lei; Yu, Karen; Miller, Christopher C.; Yantosca, Robert M.; Sulprizio, Melissa P.; Thompson, Anne M.; Wennberg, Paul O.; Crounse, John D.; St. Clair, Jason M.; Cohen, Ronald C.; Laughner, Joshua L.; Dibb, Jack E.; Hall, Samuel R.; Ullmann, Kirk; Wolfe, Glenn M.; Pollack, Illana B.; Peischl, Jeff; Neuman, Jonathan A.; Zhou, Xianliang

2016-11-01

Ozone pollution in the Southeast US involves complex chemistry driven by emissions of anthropogenic nitrogen oxide radicals (NOx ≡ NO + NO2) and biogenic isoprene. Model estimates of surface ozone concentrations tend to be biased high in the region and this is of concern for designing effective emission control strategies to meet air quality standards. We use detailed chemical observations from the SEAC4RS aircraft campaign in August and September 2013, interpreted with the GEOS-Chem chemical transport model at 0.25° × 0.3125° horizontal resolution, to better understand the factors controlling surface ozone in the Southeast US. We find that the National Emission Inventory (NEI) for NOx from the US Environmental Protection Agency (EPA) is too high. This finding is based on SEAC4RS observations of NOx and its oxidation products, surface network observations of nitrate wet deposition fluxes, and OMI satellite observations of tropospheric NO2 columns. Our results indicate that NEI NOx emissions from mobile and industrial sources must be reduced by 30-60 %, dependent on the assumption of the contribution by soil NOx emissions. Upper-tropospheric NO2 from lightning makes a large contribution to satellite observations of tropospheric NO2 that must be accounted for when using these data to estimate surface NOx emissions. We find that only half of isoprene oxidation proceeds by the high-NOx pathway to produce ozone; this fraction is only moderately sensitive to changes in NOx emissions because isoprene and NOx emissions are spatially segregated. GEOS-Chem with reduced NOx emissions provides an unbiased simulation of ozone observations from the aircraft and reproduces the observed ozone production efficiency in the boundary layer as derived from a regression of ozone and NOx oxidation products. However, the model is still biased high by 6 ± 14 ppb relative to observed surface ozone in the Southeast US. Ozonesondes launched during midday hours show a 7 ppb ozone decrease from 1.5 km to the surface that GEOS-Chem does not capture. This bias may reflect a combination of excessive vertical mixing and net ozone production in the model boundary layer.

Why do Models Overestimate Surface Ozone in the Southeastern United States?

PubMed

Travis, Katherine R; Jacob, Daniel J; Fisher, Jenny A; Kim, Patrick S; Marais, Eloise A; Zhu, Lei; Yu, Karen; Miller, Christopher C; Yantosca, Robert M; Sulprizio, Melissa P; Thompson, Anne M; Wennberg, Paul O; Crounse, John D; St Clair, Jason M; Cohen, Ronald C; Laughner, Joshua L; Dibb, Jack E; Hall, Samuel R; Ullmann, Kirk; Wolfe, Glenn M; Pollack, Illana B; Peischl, Jeff; Neuman, Jonathan A; Zhou, Xianliang

2016-01-01

Ozone pollution in the Southeast US involves complex chemistry driven by emissions of anthropogenic nitrogen oxide radicals (NO x ≡ NO + NO 2 ) and biogenic isoprene. Model estimates of surface ozone concentrations tend to be biased high in the region and this is of concern for designing effective emission control strategies to meet air quality standards. We use detailed chemical observations from the SEAC 4 RS aircraft campaign in August and September 2013, interpreted with the GEOS-Chem chemical transport model at 0.25°×0.3125° horizontal resolution, to better understand the factors controlling surface ozone in the Southeast US. We find that the National Emission Inventory (NEI) for NO x from the US Environmental Protection Agency (EPA) is too high. This finding is based on SEAC 4 RS observations of NO x and its oxidation products, surface network observations of nitrate wet deposition fluxes, and OMI satellite observations of tropospheric NO 2 columns. Our results indicate that NEI NO x emissions from mobile and industrial sources must be reduced by 30-60%, dependent on the assumption of the contribution by soil NO x emissions. Upper tropospheric NO 2 from lightning makes a large contribution to satellite observations of tropospheric NO 2 that must be accounted for when using these data to estimate surface NO x emissions. We find that only half of isoprene oxidation proceeds by the high-NO x pathway to produce ozone; this fraction is only moderately sensitive to changes in NO x emissions because isoprene and NO x emissions are spatially segregated. GEOS-Chem with reduced NO x emissions provides an unbiased simulation of ozone observations from the aircraft, and reproduces the observed ozone production efficiency in the boundary layer as derived from a regression of ozone and NO x oxidation products. However, the model is still biased high by 8±13 ppb relative to observed surface ozone in the Southeast US. Ozonesondes launched during midday hours show a 7 ppb ozone decrease from 1.5 km to the surface that GEOS-Chem does not capture. This bias may reflect a combination of excessive vertical mixing and net ozone production in the model boundary layer.

Why do Models Overestimate Surface Ozone in the Southeastern United States?

PubMed Central

Travis, Katherine R.; Jacob, Daniel J.; Fisher, Jenny A.; Kim, Patrick S.; Marais, Eloise A.; Zhu, Lei; Yu, Karen; Miller, Christopher C.; Yantosca, Robert M.; Sulprizio, Melissa P.; Thompson, Anne M.; Wennberg, Paul O.; Crounse, John D.; St Clair, Jason M.; Cohen, Ronald C.; Laughner, Joshua L.; Dibb, Jack E.; Hall, Samuel R.; Ullmann, Kirk; Wolfe, Glenn M.; Pollack, Illana B.; Peischl, Jeff; Neuman, Jonathan A.; Zhou, Xianliang

2018-01-01

Ozone pollution in the Southeast US involves complex chemistry driven by emissions of anthropogenic nitrogen oxide radicals (NOx ≡ NO + NO2) and biogenic isoprene. Model estimates of surface ozone concentrations tend to be biased high in the region and this is of concern for designing effective emission control strategies to meet air quality standards. We use detailed chemical observations from the SEAC4RS aircraft campaign in August and September 2013, interpreted with the GEOS-Chem chemical transport model at 0.25°×0.3125° horizontal resolution, to better understand the factors controlling surface ozone in the Southeast US. We find that the National Emission Inventory (NEI) for NOx from the US Environmental Protection Agency (EPA) is too high. This finding is based on SEAC4RS observations of NOx and its oxidation products, surface network observations of nitrate wet deposition fluxes, and OMI satellite observations of tropospheric NO2 columns. Our results indicate that NEI NOx emissions from mobile and industrial sources must be reduced by 30–60%, dependent on the assumption of the contribution by soil NOx emissions. Upper tropospheric NO2 from lightning makes a large contribution to satellite observations of tropospheric NO2 that must be accounted for when using these data to estimate surface NOx emissions. We find that only half of isoprene oxidation proceeds by the high-NOx pathway to produce ozone; this fraction is only moderately sensitive to changes in NOx emissions because isoprene and NOx emissions are spatially segregated. GEOS-Chem with reduced NOx emissions provides an unbiased simulation of ozone observations from the aircraft, and reproduces the observed ozone production efficiency in the boundary layer as derived from a regression of ozone and NOx oxidation products. However, the model is still biased high by 8±13 ppb relative to observed surface ozone in the Southeast US. Ozonesondes launched during midday hours show a 7 ppb ozone decrease from 1.5 km to the surface that GEOS-Chem does not capture. This bias may reflect a combination of excessive vertical mixing and net ozone production in the model boundary layer. PMID:29619045

Venus Monitoring Camera (VMC/VEx) 1 micron emissivity and Magellan microwave properties of crater-related radar-dark parabolas and other terrains

NASA Astrophysics Data System (ADS)

Basilevsky, A. T.; Shalygina, O. S.; Bondarenko, N. V.; Shalygin, E. V.; Markiewicz, W. J.

2017-09-01

The aim of this work is a comparative study of several typical radar-dark parabolas, the neighboring plains and some other geologic units seen in the study areas which include craters Adivar, Bassi, Bathsheba, du Chatelet and Sitwell, at two depths scales: the upper several meters of the study object available through the Magellan-based microwave (at 12.6 cm wavelength) properties (microwave emissivity, Fresnel reflectivity, large-scale surface roughness, and radar cross-section), and the upper hundreds microns of the object characterized by the 1 micron emissivity resulted from the analysis of the near infra-red (NIR) irradiation of the night-side of the Venusian surface measured by the Venus Monitoring Camera (VMC) on-board of Venus Express (VEx).

[Characteristics of fugitive dust emission from paved road near construction activities].

PubMed

Tian, Gang; Fan, Shou-Bin; Li, Gang; Qin, Jian-Ping

2007-11-01

Because of the mud/dirt carryout from construction activities, the silt loading of paved road nearby is higher and the fugitive dust emission is stronger. By sampling and laboratory analysis of the road surface dust samples, we obtain the silt loading (mass of material equal to or less than 75 micromaters in physical diameter per unit area of travel surface) of paved roads near construction activities. The result show that silt loading of road near construction activities is higher than "normal road", and silt loading is negatively correlated with length from construction's door. According to AP-42 emission factor model of fugitive dust from roads, the emission factor of influenced road is 2 - 10 times bigger than "normal road", and the amount of fugitive dust emission influenced by one construction activity is "equivalent" to an additional road length of approximately 422 - 3 800 m with the baseline silt loading. Based on the spatial and temporal distribution of construction activities, in 2002 the amount of PM10 emission influenced by construction activities in Beijing city areas account of for 59% of fugitive dust from roads.

Estimating NOx emissions and surface concentrations at high spatial resolution using OMI

NASA Astrophysics Data System (ADS)

Goldberg, D. L.; Lamsal, L. N.; Loughner, C.; Swartz, W. H.; Saide, P. E.; Carmichael, G. R.; Henze, D. K.; Lu, Z.; Streets, D. G.

2017-12-01

In many instances, NOx emissions are not measured at the source. In these cases, remote sensing techniques are extremely useful in quantifying NOx emissions. Using an exponential modified Gaussian (EMG) fitting of oversampled Ozone Monitoring Instrument (OMI) NO2 data, we estimate NOx emissions and lifetimes in regions where these emissions are uncertain. This work also presents a new high-resolution OMI NO2 dataset derived from the NASA retrieval that can be used to estimate surface level concentrations in the eastern United States and South Korea. To better estimate vertical profile shape factors, we use high-resolution model simulations (Community Multi-scale Air Quality (CMAQ) and WRF-Chem) constrained by in situ aircraft observations to re-calculate tropospheric air mass factors and tropospheric NO2 vertical columns during summertime. The correlation between our satellite product and ground NO2 monitors in urban areas has improved dramatically: r2 = 0.60 in new product, r2 = 0.39 in operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to re-calculate vertical column data in areas with large spatial heterogeneities in NOx emissions. The methodologies developed in this work can be applied to other world regions and other satellite data sets to produce high-quality region-specific emissions estimates.

Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph

Emissions of CO 2 and CH 4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO 2 and CH 4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m -2 day -1 for CO 2 and 0 to 0.95 mg m -2 day -1 for CH 4. Next, we developed statisticalmore » models using spatial and physicochemical variables to predict surface diffusions of CO 2 and CH 4. Models explained 22.7 and 20.9% of the variation in CO 2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.« less

Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

DOE PAGES

Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph; ...

2015-10-29

Emissions of CO 2 and CH 4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO 2 and CH 4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m -2 day -1 for CO 2 and 0 to 0.95 mg m -2 day -1 for CH 4. Next, we developed statisticalmore » models using spatial and physicochemical variables to predict surface diffusions of CO 2 and CH 4. Models explained 22.7 and 20.9% of the variation in CO 2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.« less

Voyager IRIS Measurements of Triton's Thermal Emission: Impllications for Pluto?

NASA Astrophysics Data System (ADS)

Stansberry, John A.; Spencer, John; Linscott, Ivan

2015-11-01

The New Horizons Pluto encounter data set includes unique observations obtained using the Radio Science experiment to measure the night-side thermal emission at centimeter wavelengths, well beyond the emission peak (in the 70 to 100 micron range). 26 years ago the Voyager 2 Infrared Interferometer Spectrometer (IRIS) obtained spectra in the 30 - 50 micron wavelength range to try and detect thermal emission from Pluto's sibling, Triton. Conrath etal. (1989) analyzed 16 of the IRIS spectra of Triton's dayside and derived a weak limit of 36 K - 41 K. We have analysed those, and an additional 75 spectra, to refine the limits on the temperature of Triton's surface, and to explore diurnal differences in the thermal emission. Triton results from other Voyager instruments provide important constraints on our interpretation of the IRIS data, as do Spitzer measurements of Pluto's thermal emission.For unit-emissivity, average temperature is 34 K, inconsistent with the pressure of Triton's atmosphere (13 - 19 microbar), the presence of beta-phase nitrogen ice on the surface, and the likely presence ofwarm regions on the surface. The atmospheric pressure requires nitrogen ice temperatures of 37.4 K - 38.1 K, which in turn requires emissivity of 0.31--0.53. Such a low emissivity in this spectral region might be expected if the surface is dominated by nitrogen or methane ice. Averages of data subsets show evidence for brightness temperature variations across Triton's surface. Surprisingly, the data seem to indicate that Triton's nightside equatorial region was warmer than on the dayside.These Voyager results for Triton provide a useful context for interpreting New Horizons and ALMA observations of emission from Pluto in the sub-millimeter and centimeter region. JWST will be capable of detecting Triton's and Pluto's 10 - 28 micron thermal emission, although scattered light from Neptune may be an issue for the Triton. Combined with new capabilities of ALMA to measure the sub-millimeter emission (and even resolve the disks of Pluto and Triton), it seems possible that we may gain significant new insights into the thermal properties of these bodies in the coming decade.

Detection of CN emission from (2060) Chiron

NASA Technical Reports Server (NTRS)

Bus, Schelte J.; Schleicher, David G.; Bowell, Edward; A'Hearn, Michael F.

1991-01-01

The detection of CN emission the spectrum of (2060) Chiron not only underscores its cometary nature, but represents, at a heliocentric distance in excess of 11 AU, the most distantly detected instance of a cometary gas species. These observations are noted to be consistent with a driving of Chiron's outgassing by isolated outbursts of CO2 from a small fraction of Chiron's surface. If dusty particles or icy grains are dragged out by the gas with unit dust-to-gas mass ratio, outbursts need occur only once every several months. Such small-surface outgassings appear to characterize comets which have made many passages close to the sun.

RLS Instrument Radiometric Model: Instrument performance theoretical evaluation and experimental checks

NASA Astrophysics Data System (ADS)

Quintana, César; Ramos, Gonzalo; Moral, Andoni; Rodriguez, Jose Antonio; Pérez, Carlos; Hutchinson, Ian; INGLEY, Richard; Rull, Fernando

2016-10-01

Raman Laser Spectrometer (RLS) is one of the Pasteur payload instruments located at the Rover of the ExoMars mission and within the ESA's Aurora Exploration Programme. RLS will explore the Mars surface composition through the Raman spectroscopy technique. The instrument is divided into several units: a laser for Raman emission stimulation, an internal optical head (iOH) for sample excitation and for Raman emission recovering, a spectrometer with a CCD located at its output (SPU), the optical harness (OH) for the units connection, from the laser to the excitation path of the iOH and from the iOH reception path to the spectrometer, and the corresponding electronics for the CCD operation.Due to the variability of the samples to be analyzed on Mars, a radiometry prediction for the instrument performance results to be of the critical importance. In such a framework, and taking into account the SNR (signal to noise ratio) required for the achievement of successful results from the scientific point of view (a proper information about the Mars surface composition), a radiometric model has been developed to provide the requirements for the different units, i.e. the laser irradiance, the iOH, OH, and SPU throughputs, and the samples that will be possible to be analyzed in terms of its Raman emission and the relationship of the Raman signal with respect to fluorescence emission, among others.The radiometric model fundamentals (calculations and approximations), as well as the first results obtained during the bread board characterization campaign are here reported on.

NOx Emissions from Large Point Sources: Variability in Ozone Production, Resulting Health Damages and Economic Costs

NASA Astrophysics Data System (ADS)

Mauzerall, D. L.; Sultan, B.; Kim, N.; Bradford, D.

2004-12-01

We present a proof-of-concept analysis of the measurement of the health damage of ozone (O3) produced from nitrogen oxides (NOx = NO + NO2) emitted by individual large point sources in the eastern United States. We use a regional atmospheric model of the eastern United States, the Comprehensive Air Quality Model with Extensions (CAMx), to quantify the variable impact that a fixed quantity of NOx emitted from individual sources can have on the downwind concentration of surface O3, depending on temperature and local biogenic hydrocarbon emissions. We also examine the dependence of resulting ozone-related health damages on the size of the exposed population. The investigation is relevant to the increasingly widely used "cap and trade" approach to NOx regulation, which presumes that shifts of emissions over time and space, holding the total fixed over the course of the summer O3 season, will have minimal effect on the environmental outcome. By contrast, we show that a shift of a unit of NOx emissions from one place or time to another could result in large changes in the health effects due to ozone formation and exposure. We indicate how the type of modeling carried out here might be used to attach externality-correcting prices to emissions. Charging emitters fees that are commensurate with the damage caused by their NOx emissions would create an incentive for emitters to reduce emissions at times and in locations where they cause the largest damage.

Emissions of organophosphate and brominated flame retardants from selected consumer products and building materials

NASA Astrophysics Data System (ADS)

Kemmlein, Sabine; Hahn, Oliver; Jann, Oliver

The emissions of selected flame retardants were measured in 1- and 0.02-m 3 emission test chambers and 0.001-m 3 emission test cells. Four product groups were of interest: insulating materials, assembly foam, upholstery/mattresses, and electronics equipment. The experiments were performed under constant environmental conditions (23°C, 50% RH) using a fixed sample surface area and controlled air flow rates. Tris (2-chloro-isopropyl)phosphate (TCPP) was observed to be one of the most commonly emitted organophosphate flame retardants in polyurethane foam applications. Depending on the sample type, area-specific emission rates (SER a) of TCPP varied between 20 ng m -2 h -1 and 140 μg m -2 h -1. The emissions from electronic devices were measured at 60°C to simulate operating conditions. Under these conditions, unit specific emission rates (SER u) of organophosphates were determined to be 10-85 ng unit -1 h -1. Increasing the temperature increased the emission of several flame retardants by up to a factor of 500. The results presented in this paper indicate that emissions of several brominated and organophosphate flame retardants are measurable. Polybrominated diphenylethers exhibited an SER a of between 0.2 and 6.6 ng m -2 h -1 and an SER u of between 0.6 and 14.2 ng unit -1 h -1. Because of sink effects, i.e., sorption to chamber components, the emission test chambers and cells used in this study have limited utility for substances low vapour pressures, especially the highly brominated compounds; hexabromocyclododecane had an SER a of between 0.1 and 29 ng m -2 h -1 and decabromodiphenylether was not detectable at all.

Secondary organic aerosol from sesquiterpene and monoterpene emissions in the United States.

PubMed

Sakulyanontvittaya, Tanarit; Guenther, Alex; Helmig, Detlev; Milford, Jana; Wiedinmyer, Christine

2008-12-01

Emissions of volatile organic compounds (VOC) from vegetation are believed to be a major source of secondary organic aerosol (SOA), which in turn comprises a large fraction of fine particulate matter in many areas. Sesquiterpenes are a class of biogenic VOC with high chemical reactivity and SOA yields. Sesquiterpenes have only recently been quantified in emissions from a wide variety of plants. In this study, a new sesquiterpene emission inventory is used to provide input to the Models-3 Community Multiscale Air Quality (CMAQ) model. CMAQ is used to estimate the contribution of sesquiterpenes and monoterpenes to SOA concentrations over the contiguous United States. The gas-particle partitioning module of CMAQ was modified to include condensable products of sesquiterpene oxidation and to update values of the enthalpy of vaporization. The resulting model predicts July monthly average surface concentrations of total SOA in the eastern U.S. ranging from about 0.2-0.8 microg m(-3). This is roughly double the amount of SOA produced in this region when sesquiterpenes are not included. Even with sesquiterpenes included, however, the model significantly underpredicts surface concentrations of particle-phase organic matter compared to observed values. Treating all SOA as capable of undergoing polymerization increases predicted monthly average surface concentrations in July to 0.4-1.2 microg m(-3), in closer agreement with observations. Using the original enthalpy of vaporization value in CMAQ in place of the values estimated from the recent literature results in predicted SOA concentrations of about 0.3-1.3 microg m(-3).

CO 2 is dominant greenhouse gas emitted from six hydropower reservoirs in southeastern United States during peak summer emissions

DOE PAGES

Bevelhimer, Mark S.; Stewart, Aurthur J.; Fortner, Allison M.; ...

2016-01-06

During August-September 2012, we sampled six hydropower reservoirs in southeastern United States. for CO 2 and CH 4 emissions via three pathways: diffusive emissions from water surface; ebullition in the water column; and losses from dam tailwaters during power generation. Average total emission rates of CO 2 for the six reservoirs ranged from 1,127 to 2,051 mg m -2 d -1, which is low to moderate compared to CO 2 emissions rates reported for tropical hydropower reservoirs and boreal ponds and lakes, and similar to rates reported for other temperate reservoirs. Similar average rates for CH 4 were also relativelymore » low, ranging from 5 to 83 mg m -2 d -1. On a whole-reservoir basis, total emissions of CO 2 ranged nearly 10-fold, from ~51,000 kg per day for Fontana to ~486,000 kg per day for Guntersville, and total emissions of CH 4 ranged nearly 20-fold, from ~5 kg per day for Fontana to ~83 kg per day for Allatoona. Emissions through the tailwater pathway varied among reservoirs, comprising from 20 to 50% of total CO 2 emissions and 0 to 90% of CH 4 emissions, depending on the reservoir. Furthermore, several explanatory factors related to reservoir morphology and water quality were considered for observed differences among reservoirs.« less

Emergence of new hydrologic regimes of surface water resources in the conterminous United States under future warming

DOE PAGES

Leng, Guoyong; Huang, Maoyi; Voisin, Nathalie; ...

2016-10-25

Emergence of significant changes in surface water PDF is detected across CONUS. Such emergence can be derived using global temperature increments at the national scale independent of emission scenarios but the relationship does not hold at sub-basin scale. The emergence of significant changes are due to changes in interannual variability rather than seasonal mean.

Modeling study of natural emissions, source apportionment, and emission control of atmospheric mercury

NASA Astrophysics Data System (ADS)

Shetty, Suraj K.

Mercury (Hg) is a toxic pollutant and is important to understand its cycling in the environment. In this dissertation, a number of modeling investigations were conducted to better understand the emission from natural surfaces, the source-receptor relationship of the emissions, and emission reduction of atmospheric mercury. The first part of this work estimates mercury emissions from vegetation, soil and water surfaces using a number of natural emission processors and detailed (LAI) Leaf Area Index data from GIS (Geographic Information System) satellite products. East Asian domain was chosen as it contributes nearly 50% of the global anthropogenic mercury emissions into the atmosphere. The estimated annual natural mercury emissions (gaseous elemental mercury) in the domain are 834 Mg yr-1 with 462 Mg yr-1 contributing from China. Compared to anthropogenic sources, natural sources show greater seasonal variability (highest in simmer). The emissions are significant, sometimes dominant, contributors to total mercury emission in the regions. The estimates provide possible explanation for the gaps between the anthropogenic emission estimates based on activity data and the emission inferred from field observations in the regions. To understand the contribution of domestic emissions to mercury deposition in the United States, the second part of the work applies the mercury model of Community Multi-scale Air Quality Modeling system (CMAQ-Hg v4.6) to apportion the various emission sources attributing to the mercury wet and dry deposition in the 6 United States receptor regions. Contributions to mercury deposition from electric generating units (EGU), iron and steel industry (IRST), industrial point sources excluding EGU and IRST (OIPM), the remaining anthropogenic sources (RA), natural processes (NAT), and out-of-boundary transport (BC) in domain was estimated. The model results for 2005 compared reasonably well to field observations made by MDN (Mercury Deposition Network) and CAMNet (Canadian Atmospheric Mercury Measurement Network). The model estimated a total deposition of 474 Mg yr-1 to the CONUS (Contiguous United States) domain, with two-thirds being dry deposited. Reactive gaseous mercury contributed the most to 60% of deposition. Emission speciation distribution is a key factor for local deposition as contribution from large point sources can be as high as 75% near (< 100 km) the emission sources, indicating that emission reduction may result in direct deposition decrease near the source locations. Among the sources, BC contributes to about 68% to 91% of total deposition. Excluding the BC's contribution, EGU contributes to nearly 50% of deposition caused by CONUS emissions in the Northeast, Southeast and East Central regions, while emissions from natural processes are more important in the Pacific and West Central regions (contributing up to 40% of deposition). The modeling results implies that implementation of the new emission standards proposed by USEPA (United States Environmental Protection Agency) would significantly benefit regions that have larger contributions from EGU sources. Control of mercury emissions from coal combustion processes has attracted great attention due to its toxicity and the emission-control regulations and has lead to advancement in state-of-the-art control technologies that alleviate the impact of mercury on ecosystem and human health. This part of the work applies a sorption model to simulate adsorption of mercury in flue gases, onto a confined-bed of activated carbon. The model's performances were studied at various flue gas flow rates, inlet mercury concentrations and adsorption bed temperatures. The process simulated a flue gas, with inlet mercury concentration of 300 ppb, entering at a velocity of 0.3 m s-1 from the bottom into a fixed bed (inside bed diameter of 1 m and 3 m bed height; bed temperature of 25 °C) of activated carbon (particle size of 0.004 m with density of 0.5 g cm-3 and surface area of 90.25 cm2 g -1). The model result demonstrated that a batch of activated carbon bed was capable of controlling mercury emission for approximately 275 days after which further mercury uptake starts to decrease till it reaches about 500 days when additional control ceases. An increase in bed temperature significantly reduces mercury sorption capacity of the activated carbon. Increase in flue gas flow rate may result in faster consumption of sorption capacity initially but at a later stage, the sorption rate decreases due to reduced sorption capacity. Thus, overall sorption rate remains unaffected. The activated carbon's effective life (time to reach saturation) is not affected by inlet mercury concentration, implying that the designing and operation of a mercury sorption process can be done independently. The results provide quantitative indication for designing efficient confined-bed process to remove mercury from flue gases.

Vehicle Traffic as a Source of Particulate Polycyclic Aromatic Hydrocarbon Exposure in the Mexico City Metropolitan Area

PubMed Central

MARR, LINSEY C.; GROGAN, LISA A.; WÖHRNSCHIMMEL, HENRY; MOLINA, LUISAT.; MOLINA, MARIO J.; SMITH, THOMAS J.; GARSHICK, ERIC

2005-01-01

Surface properties of aerosols in the Mexico City metropolitan area have been measured in a variety of exposure scenarios related to vehicle emissions in 2002, using continuous, real-time instruments. The objective of these experiments is to describe ambient and occupational particulate polycyclic aromatic hydrocarbon (PAH) concentrations associated with vehicular traffic and facilities using diesel vehicles. Median total particulate PAH concentrations along Mexico City’s roadways range from 60 to 910 ng m−3, averaged over a minimum of 1 h. These levels are approximately 5 times higher than concentrations measured in the United States and among the highest measured ambient values reported in the literature. The ratio of particulate PAH concentration to aerosol active surface area is much higher along roadways and in other areas of fresh vehicle emissions, compared to ratios measured at sites influenced more by aged emissions or noncombustion sources. For particles freshly emitted by vehicles, PAH and elemental carbon (EC) concentrations are correlated because they both originate during the combustion process. Comparison of PAH versus EC and active surface area concentrations at different locations suggests that surface PAH concentrations may diminish with particle aging. These results indicate that exposure to vehicle-related PAH emissions on Mexico City’s roadways may present an important public health risk. PMID:15180054

40 CFR 63.681 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... drain system, a gravity-operated conveyor (such as a chute), and a mechanically-powered conveyor (such... features permanently integrated into the design of the unit. Emission point means an individual tank, surface impoundment, container, oil-water or organic-water separator, transfer system, process vent, or...

40 CFR 63.681 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... drain system, a gravity-operated conveyor (such as a chute), and a mechanically-powered conveyor (such... features permanently integrated into the design of the unit. Emission point means an individual tank, surface impoundment, container, oil-water or organic-water separator, transfer system, process vent, or...

40 CFR 63.681 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... drain system, a gravity-operated conveyor (such as a chute), and a mechanically-powered conveyor (such... features permanently integrated into the design of the unit. Emission point means an individual tank, surface impoundment, container, oil-water or organic-water separator, transfer system, process vent, or...

A Framework for Evaluating Energy and Emissions of Connected and Automated Vehicles through Traffic Microsimulations

DOT National Transportation Integrated Search

2018-01-07

Connected and automated vehicles (CAV) are poised to transform surface transportation systems in the United States. Near-term CAV technologies like cooperative adaptive cruise control (CACC) have the potential to deliver energy efficiency and air qua...

Foreign and Domestic Contributions to Springtime Ozone Pollution over China

NASA Astrophysics Data System (ADS)

Ni, R.; Lin, J.; Yan, Y.; Lin, W.; Chen, H.

2017-12-01

Ozone is a critical air pollutant that damages human health and vegetation. Previous studies for the United States and Europe have shown large influences of foreign emissions on domestic ozone levels, whereas the relative contributions of foreign versus domestic emissions are much less clear for China. Here, we use a global-regional two-way coupled model system based on GEOS-Chem to quantify the contributions to springtime ozone over China from anthropogenic emissions in major source regions across the globe. Our results indicate considerable influences of foreign anthropogenic pollution on China's ozone pollution. Together, foreign anthropogenic emissions enhance springtime surface ozone over China by 3 12 ppb. Of all ozone over China produced by global anthropogenic emissions, foreign emissions contribute 40% near the surface, and the contribution increases with altitude until a value of 80% in the upper troposphere. Impact from Japan and Korea is 1 2 ppb over east coastal regions, and negligible in inland. Anthropogenic emissions of South and South-East Asia increase ozone over Tibet and the Yunnan-Guizhou Plateau by up to 5 ppb, and their contribution increases with height due to strong vertical transport. Pollution from North America and Europe mainly accompanies strong westerly winds and frequent cyclonic activities that are favorable to long-range transport. European anthropogenic pollution enhances surface ozone by 1 3 ppb over West and North China. Despite a much longer transport distance, the contribution from North America is greater than European contribution due to the nearly doubled amount of anthropogenic NMVOC emissions. The high percentage contribution of foreign anthropogenic emissions to China's ozone pollution can be partly explained by excessive domestic NOx emissions that suppress ozone production efficiency and even destroy ozone. Our study is relevant to Chinese ozone pollution control and global environmental protection collaboration.

Diverse policy implications for future ozone and surface UV in a changing climate

NASA Astrophysics Data System (ADS)

Butler, A. H.; Daniel, J. S.; Portmann, R. W.; Ravishankara, A. R.; Young, P. J.; Fahey, D. W.; Rosenlof, K. H.

2016-06-01

Due to the success of the Montreal Protocol in limiting emissions of ozone-depleting substances, concentrations of atmospheric carbon dioxide, nitrous oxide, and methane will control the evolution of total column and stratospheric ozone by the latter half of the 21st century. As the world proceeds down the path of reducing climate forcing set forth by the 2015 Conference of the Parties to the United Nations Framework Convention on Climate Change (COP 21), a broad range of ozone changes are possible depending on future policies enacted. While decreases in tropical stratospheric ozone will likely persist regardless of the future emissions scenario, extratropical ozone could either remain weakly depleted or even increase well above historical levels, with diverse implication for ultraviolet (UV) radiation. The ozone layer’s dependence on future emissions of these gases creates a complex policy decision space for protecting humans and ecosystems, which includes unexpected options such as accepting nitrous oxide emissions in order to maintain historical column ozone and surface UV levels.

Physics based calculation of the fine structure constant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lestone, John Paul

2009-01-01

We assume that the coupling between particles and photons is defined by a surface area and a temperature, and that the square of the temperature is the inverse of the surface area ({Dirac_h}=c= 1). By making assumptions regarding stimulated emission and effects associated with the finite length of a string that forms the particle surface, the fine structure constant is calculated to be {approx}1/137.04. The corresponding calculated fundamental unit of charge is 1.6021 x 10{sup -19} C.

Specific storage volumes: A useful tool for CO2 storage capacity assessment

USGS Publications Warehouse

Brennan, S.T.; Burruss, R.C.

2006-01-01

Subsurface geologic strata have the potential to store billions of tons of anthropogenic CO2; therefore, geologic carbon sequestration can be an effective mitigation tool used to slow the rate at which levels of atmospheric CO2 are increasing. Oil and gas reservoirs, coal beds, and saline reservoirs can be used for CO2 storage; however, it is difficult to assess and compare the relative storage capacities of these different settings. Typically, CO2 emissions are reported in units of mass, which are not directly applicable to comparing the CO2 storage capacities of the various storage targets. However, if the emission values are recalculated to volumes per unit mass (specific volume) then the volumes of geologic reservoirs necessary to store CO2 emissions from large point sources can be estimated. The factors necessary to convert the mass of CO2 emissions to geologic storage volume (referred to here as Specific Storage Volume or 'SSV') can be reported in units of cubic meters, cubic feet, and petroleum barrels. The SSVs can be used to estimate the reservoir volume needed to store CO2 produced over the lifetime of an individual point source, and to identify CO2 storage targets of sufficient size to meet the demand from that given point source. These storage volumes also can then be projected onto the land surface to outline a representative "footprint," which marks the areal extent of storage. This footprint can be compared with the terrestrial carbon sequestration capacity of the same land area. The overall utility of this application is that the total storage capacity of any given parcel of land (from surface to basement) can be determined, and may assist in making land management decisions. ?? Springer Science+Business Media, LLC 2006.

NO x emissions from large point sources: variability in ozone production, resulting health damages and economic costs

NASA Astrophysics Data System (ADS)

Mauzerall, Denise L.; Sultan, Babar; Kim, Namsoug; Bradford, David F.

We present a proof-of-concept analysis of the measurement of the health damage of ozone (O 3) produced from nitrogen oxides (NO=NO+NO) emitted by individual large point sources in the eastern United States. We use a regional atmospheric model of the eastern United States, the Comprehensive Air quality Model with Extensions (CAMx), to quantify the variable impact that a fixed quantity of NO x emitted from individual sources can have on the downwind concentration of surface O 3, depending on temperature and local biogenic hydrocarbon emissions. We also examine the dependence of resulting O 3-related health damages on the size of the exposed population. The investigation is relevant to the increasingly widely used "cap and trade" approach to NO x regulation, which presumes that shifts of emissions over time and space, holding the total fixed over the course of the summer O 3 season, will have minimal effect on the environmental outcome. By contrast, we show that a shift of a unit of NO x emissions from one place or time to another could result in large changes in resulting health effects due to O 3 formation and exposure. We indicate how the type of modeling carried out here might be used to attach externality-correcting prices to emissions. Charging emitters fees that are commensurate with the damage caused by their NO x emissions would create an incentive for emitters to reduce emissions at times and in locations where they cause the largest damage.

Preliminary evaluation of a liquid belt radiator for space applications

NASA Technical Reports Server (NTRS)

Teagan, W. P.; Fitzgerald, K.

1984-01-01

The liquid belt radiator (LBR) is discussed. The LBR system operates either in the sensible heat mode or in the latent heat mode. Parametric analysis shows that the LBR may reduce the mass of heat pipe radiators by 70 to 90% when the LBR surface has a total emissivity in excess of 0.3. It is indicated that the diffusion pump oils easily meet this criteria with emissivities greater than 0.8. Measurements on gallium indicate that its emissivity is probably in excess of 0.3 in the solid state when small amounts of impurities are on the surface. The point design exhibits a characteristic mass of 3.1 kg/kW of power dissipation, a mass per unit prime radiating area of approximately 0.9 kg/sq ms and a total package volume of approximately 2.50 cubic m. This compares favorably with conventional technologies which have weights on the order of 4 kg/sq m.

Venus Surface Composition Constrained by Observation and Experiment

NASA Astrophysics Data System (ADS)

Gilmore, Martha; Treiman, Allan; Helbert, Jörn; Smrekar, Suzanne

2017-11-01

New observations from the Venus Express spacecraft as well as theoretical and experimental investigation of Venus analogue materials have advanced our understanding of the petrology of Venus melts and the mineralogy of rocks on the surface. The VIRTIS instrument aboard Venus Express provided a map of the southern hemisphere of Venus at ˜1 μm allowing, for the first time, the definition of surface units in terms of their 1 μm emissivity and derived mineralogy. Tessera terrain has lower emissivity than the presumably basaltic plains, consistent with a more silica-rich or felsic mineralogy. Thermodynamic modeling and experimental production of melts with Venera and Vega starting compositions predict derivative melts that range from mafic to felsic. Large volumes of felsic melts require water and may link the formation of tesserae to the presence of a Venus ocean. Low emissivity rocks may also be produced by atmosphere-surface weathering reactions unlike those seen presently. High 1 μm emissivity values correlate to stratigraphically recent flows and have been used with theoretical and experimental predictions of basalt weathering to identify regions of recent volcanism. The timescale of this volcanism is currently constrained by the weathering of magnetite (higher emissivity) in fresh basalts to hematite (lower emissivity) in Venus' oxidizing environment. Recent volcanism is corroborated by transient thermal anomalies identified by the VMC instrument aboard Venus Express. The interpretation of all emissivity data depends critically on understanding the composition of surface materials, kinetics of rock weathering and their measurement under Venus conditions. Extended theoretical studies, continued analysis of earlier spacecraft results, new atmospheric data, and measurements of mineral stability under Venus conditions have improved our understanding atmosphere-surface interactions. The calcite-wollastonite CO2 buffer has been discounted due, among other things, to the rarity of wollastonite and instability of carbonate at the Venus surface. Sulfur in the Venus atmosphere has been shown experimentally to react with Ca in surface minerals to produce anhydrite. The extent of this SO2 buffer is constrained by the Ca content of surface rocks and sulfur content of the atmosphere, both of which are likely variable, perhaps due to active volcanism. Experimental work on a range of semiconductor and ferroelectric minerals is placing constraints on the cause(s) of Venus' anomalously radar bright highlands.

Characterization of Formaldehyde Emissions from Tire Crumb Rubber in Small Environmental Chambers - 2

EPA Science Inventory

Concerns have been raised about the safety of recycled rubber tire crumbs used in synthetic turf fields and playgrounds in the United States. To support federal efforts to better characterize recycled tire-derived surface materials, dynamic small chamber tests were conducted at...

Locally Resolved Electron Emission Area and Unified View of Field Emission from Ultrananocrystalline Diamond Films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chubenko, Oksana; Baturin, Stanislav S.; Kovi, Kiran K.

One of the common problems in case of field emission from polycrystalline diamond films, which typically have uniform surface morphology, is uncertainty in determining exact location of electron emission sites across the surface. Although several studies have suggested that grain boundaries are the main electron emission source, it is not particularly clear what makes some sites emit more than the others. It is also practically unclear how one could quantify the actual electron emission area and therefore field emission current per unit area. In this paper we study the effect of actual, locally resolved, field emission (FE) area on electronmore » emission characteristics of uniform planar highly conductive nitrogen-incorporated ultrananocrystalline diamond ((N)UNCD) field emitters. It was routinely found that field emission from as-grown planar (N)UNCD films is always confined to a counted number of discrete emitting centers across the surface which varied in size and electron emissivity. It was established that the actual FE area critically depends on the applied electric field, as well as that the actual FE area and the overall electron emissivity improve with sp2 fraction present in the film irrespectively of the original substrate roughness and morphology. To quantify the actual FE area and its dependence on the applied electric field, imaging experiments were carried out in a vacuum system in a parallel-plate configuration with a specialty anode phosphor screen. Electron emission micrographs were taken concurrently with I-V characteristics measurements. In addition, a novel automated image processing algorithm was developed to process extensive imaging datasets and calculate emission area per image. By doing so, it was determined that the emitting area was always significantly smaller than the FE cathode surface area. Namely, the actual FE area would change from 5×10-3 % to 1.5 % of the total cathode area with the applied electric field increased. Finally and most importantly, it was shown that when I-E curves as measured in the experiment were normalized by the field-dependent emission area, the resulting j-E curves demonstrated a strong kink and significant deviation from Fowler-Nordheim (FN) law, and eventually saturated at a current density of ~100 mA/cm2 . This value was nearly identical for all (N)UNCD films measured in this study, regardless of the substrate.« less

Operational prediction of air quality for the United States: applications of satellite observations

NASA Astrophysics Data System (ADS)

Stajner, Ivanka; Lee, Pius; Tong, Daniel; Pan, Li; McQueen, Jeff; Huang, Jianping; Huang, Ho-Chun; Draxler, Roland; Kondragunta, Shobha; Upadhayay, Sikchya

2015-04-01

Operational predictions of ozone and wildfire smoke over United States (U.S.) and predictions of airborne dust over the contiguous 48 states are provided by NOAA at http://airquality.weather.gov/. North American Mesoscale (NAM) weather predictions with inventory based emissions estimates from the U.S. Environmental Protection Agency (EPA) and chemical processes within the Community Multiscale Air Quality (CMAQ) model are combined together to produce ozone predictions. Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model is used to predict wildfire smoke and dust storm predictions. Routine verification of ozone predictions relies on AIRNow compilation of observations from surface monitors. Retrievals of smoke column integrals from GOES satellites and dust column integrals from MODIS satellite instruments are used for verification of smoke and dust predictions. Recent updates of NOAA's operational air quality predictions have focused on mobile emissions using the projections of mobile sources for 2012. Since emission inventories are complex and take years to assemble and evaluate causing a lag of information, we recently began combing inventory information with projections of mobile sources. In order to evaluate this emission update, these changes in projected NOx emissions from 2005-2012 were compared with observed changes in Ozone Monitoring Instrument (OMI) NO2 observations and NOx measured by surface monitors over large U.S. cities over the same period. Comparisons indicate that projected decreases in NOx emissions from 2005 to 2012 are similar, but not as strong as the decreases in the observed NOx concentrations and in OMI NO2 retrievals. Nevertheless, the use of projected mobile NOx emissions in the predictions reduced biases in predicted NOx concentrations, with the largest improvement in the urban areas. Ozone biases are reduced as well, with the largest improvement seen in rural areas. Recent testing of PM2.5 predictions is relying on emissions inventories augmented by real time sources from wildfires and dust storms. The evaluation of these test predictions relies on surface monitor data, but efforts are in progress to include comparisons with satellite observed aerosol optical depth (AOD) products. Testing of PM2.5 predictions continues to exhibit seasonal biases: overprediction in the winter and underprediction in the summer. The current efforts focus on bias correction and development of linkages with global atmospheric composition predictions.

Emergence of new hydrologic regimes of surface water resources in the conterminous United States under future warming

NASA Astrophysics Data System (ADS)

Leng, Guoyong; Huang, Maoyi; Voisin, Nathalie; Zhang, Xuesong; Asrar, Ghassem R.; Leung, L. Ruby

2016-11-01

Despite the importance of surface water to people and ecosystems, few studies have explored detectable changes in surface water supply in a changing climate, given its large natural variability. Here we analyze runoff projections from the Variable Infiltration Capacity hydrological model driven by 97 downscaled and bias-corrected Coupled Model Intercomparison Project Phase 5 climate projections over the conterminous United States (CONUS). Our results show that more than 40% of the CONUS land area will experience significant changes in the probability distribution functions (i.e. PDFs) of summer and winter runoff by the end of the 21st century, which may pose great challenges to future surface water supply. Sub-basin mean runoff PDFs are projected to change significantly after 2040s depending on the emission scenarios, with earliest occurrence in the Pacific Northwest and northern California regions. When examining the response as a function of changes in the global mean temperature (ΔGMT), a linear relationship is revealed at the 95% confidence level. Generally, 1 °C increase of GMT leads to 11% and 17% more lands experiencing changes in summer and winter runoff PDFs, respectively. Such changes in land fraction scale with ΔGMT at the country scale independent of emission scenarios, but the same relationship does not necessarily hold at sub-basin scales, due to the larger role of atmospheric circulation changes and their uncertainties on regional precipitation. Further analyses show that the emergence of significant changes in sub-basin runoff PDFs is indicative of the emergence of new hydrology regimes and it is dominated by the changes in variability rather than shift in the mean, regardless of the emission scenarios.

Comparison of ASTER Global Emissivity Database (ASTER-GED) With In-Situ Measurement In Italian Vulcanic Areas

NASA Astrophysics Data System (ADS)

Silvestri, M.; Musacchio, M.; Buongiorno, M. F.; Amici, S.; Piscini, A.

2015-12-01

LP DAAC released the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Global Emissivity Database (GED) datasets on April 2, 2014. The database was developed by the National Aeronautics and Space Administration's (NASA) Jet Propulsion Laboratory (JPL), California Institute of Technology. The database includes land surface emissivities derived from ASTER data acquired over the contiguous United States, Africa, Arabian Peninsula, Australia, Europe, and China. In this work we compare ground measurements of emissivity acquired by means of Micro-FTIR (Fourier Thermal Infrared spectrometer) instrument with the ASTER emissivity map extract from ASTER-GED and the emissivity obtained by using single ASTER data. Through this analysis we want to investigate differences existing between the ASTER-GED dataset (average from 2000 to 2008 seasoning independent) and fall in-situ emissivity measurement. Moreover the role of different spatial resolution characterizing ASTER and MODIS, 90mt and 1km respectively, by comparing them with in situ measurements. Possible differences can be due also to the different algorithms used for the emissivity estimation, Temperature and Emissivity Separation algorithm for ASTER TIR band( Gillespie et al, 1998) and the classification-based emissivity method (Snyder and al, 1998) for MODIS. In-situ emissivity measurements have been collected during dedicated fields campaign on Mt. Etna vulcano and Solfatara of Pozzuoli. Gillespie, A. R., Matsunaga, T., Rokugawa, S., & Hook, S. J. (1998). Temperature and emissivity separation from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images. IEEE Transactions on Geoscience and Remote Sensing, 36, 1113-1125. Snyder, W.C., Wan, Z., Zhang, Y., & Feng, Y.-Z. (1998). Classification-based emissivity for land surface temperature measurement from space. International Journal of Remote Sensing, 19, 2753-2574.

A multi-model assessment of pollution transport to the Arctic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shindell, D T; Chin, M; Dentener, F

2008-03-13

We examine the response of Arctic gas and aerosol concentrations to perturbations in pollutant emissions from Europe, East and South Asia, and North America using results from a coordinated model intercomparison. These sensitivities to regional emissions (mixing ratio change per unit emission) vary widely across models and species. Intermodel differences are systematic, however, so that the relative importance of different regions is robust. North America contributes the most to Arctic ozone pollution. For aerosols and CO, European emissions dominate at the Arctic surface but East Asian emissions become progressively more important with altitude, and are dominant in the upper troposphere.more » Sensitivities show strong seasonality: surface sensitivities typically maximize during boreal winter for European and during spring for East Asian and North American emissions. Mid-tropospheric sensitivities, however, nearly always maximize during spring or summer for all regions. Deposition of black carbon (BC) onto Greenland is most sensitive to North American emissions. North America and Europe each contribute {approx}40% of total BC deposition to Greenland, with {approx}20% from East Asia. Elsewhere in the Arctic, both sensitivity and total BC deposition are dominated by European emissions. Model diversity for aerosols is especially large, resulting primarily from differences in aerosol physical and chemical processing (including removal). Comparison of modeled aerosol concentrations with observations indicates problems in the models, and perhaps, interpretation of the measurements. For gas phase pollutants such as CO and O{sub 3}, which are relatively well-simulated, the processes contributing most to uncertainties depend on the source region and altitude examined. Uncertainties in the Arctic surface CO response to emissions perturbations are dominated by emissions for East Asian sources, while uncertainties in transport, emissions, and oxidation are comparable for European and North American sources. At higher levels, model-to-model variations in transport and oxidation are most important. Differences in photochemistry appear to play the largest role in the intermodel variations in Arctic ozone sensitivity, though transport also contributes substantially in the mid-troposphere.« less

Temperature Dependence of Factors Controlling Isoprene Emissions

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; Damon, Megan R.; Douglass, Anne R.; Witte, Jacquelyn C.

2009-01-01

We investigated the relationship of variability in the formaldehyde (HCHO) columns measured by the Aura Ozone Monitoring Instrument (OMI) to isoprene emissions in the southeastern United States for 2005-2007. The data show that the inferred, regional-average isoprene emissions varied by about 22% during summer and are well correlated with temperature, which is known to influence emissions. Part of the correlation with temperature is likely associated with other causal factors that are temperature-dependent. We show that the variations in HCHO are convolved with the temperature dependence of surface ozone, which influences isoprene emissions, and the dependence of the HCHO column to mixed layer height as OMI's sensitivity to HCHO increases with altitude. Furthermore, we show that while there is an association of drought with the variation in HCHO, drought in the southeastern U.S. is convolved with temperature.

Discrete space charge affected field emission: Flat and hemisphere emitters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jensen, Kevin L., E-mail: kevin.jensen@nrl.navy.mil; Shiffler, Donald A.; Tang, Wilkin

Models of space-charge affected thermal-field emission from protrusions, able to incorporate the effects of both surface roughness and elongated field emitter structures in beam optics codes, are desirable but difficult. The models proposed here treat the meso-scale diode region separate from the micro-scale regions characteristic of the emission sites. The consequences of discrete emission events are given for both one-dimensional (sheets of charge) and three dimensional (rings of charge) models: in the former, results converge to steady state conditions found by theory (e.g., Rokhlenko et al. [J. Appl. Phys. 107, 014904 (2010)]) but show oscillatory structure as they do. Surfacemore » roughness or geometric features are handled using a ring of charge model, from which the image charges are found and used to modify the apex field and emitted current. The roughness model is shown to have additional constraints related to the discrete nature of electron charge. The ability of a unit cell model to treat field emitter structures and incorporate surface roughness effects inside a beam optics code is assessed.« less

Multispectral thermal infrared mapping of the 1 October 1988 Kupaianaha flow field, Kilauea volcano, Hawaii

NASA Technical Reports Server (NTRS)

Realmuto, Vincent J.; Hon, Ken; Kahle, Anne B.; Abbott, Elsa A.; Pieri, David C.

1992-01-01

Multispectral thermal infrared radiance measurements of the Kupaianaha flow field were acquired with the NASA airborne Thermal Infrared Multispectral Scanner (TIMS) on the morning of 1 October 1988. The TIMS data were used to map both the temperature and emissivity of the surface of the flow field. The temperature map depicted the underground storage and transport of lava. The presence of molten lava in a tube or tumulus resulted in surface temperatures that were at least 10 C above ambient. The temperature map also clearly defined the boundaries of hydrothermal plumes which resulted from the entry of lava into the ocean. The emissivity map revealed the boundaries between individual flow units within the Kupaianaha field. Distinct spectral anomalies, indicative of silica-rich surface materials, were mapped near fumaroles and ocean entry sites. This apparent enrichment in silica may have resulted from an acid-induced leaching of cations from the surfaces of glassy flows.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Under contract with the US Department of Energy (DE-AC22-92PCO0367), Pittsburgh Energy Technology Center, Radian Corporation has conducted a test program to collect and analyze size-fractionated stack gas particulate samples for selected inorganic hazardous air pollutants (HAPS). Specific goals of the program are (1) the collection of one-gram quantities of size-fractionated stack gas particulate matter for bulk (total) and surface chemical charactization, and (2) the determination of the relationship between particle size, bulk and surface (leachable) composition, and unit load. The information obtained from this program identifies the effects of unit load, particle size, and wet FGD system operation on themore » relative toxicological effects of exposure to particulate emissions.« less

Quantifying the Seasonal and Interannual Variability of North American Isoprene Emissions Using Satellite Observations of the Formaldehyde Column

NASA Technical Reports Server (NTRS)

Palmer, Paul I.; Abbot, Dorian S.; Fu, Tzung-May; Jacob, Daniel J.; Chance, Kelly; Kurosu, Thomas P.; Guenther, Alex; Wiedinmyer, Christine; Stanton, Jenny C.; Pilling, Michael J.;

Climate effects of reducing black carbon emissions: Dependence on location of emission

NASA Astrophysics Data System (ADS)

Fuglestvedt, J.; Berntsen, T.; Myhre, G.; Rive, N. A.; Rypdal, K.; Gerland, S.; Pedersen, C.; Strøm, J.

2006-12-01

The role played by emissions of black carbon aerosols (BC) on the Earth's climate is diverse and the overall effect is still quite uncertain: Black carbon not only absorbs sunlight (direct effect), but it also has a semi- direct effect on clouds, and when deposited on snow and ice it changes the reflectivity (albedo) of the ground surface. These mechanisms generally have a warming effect on the climate. This poster presents a Norwegian project that focus on the net effect of current BC emissions and future possible reductions in emissions of BC aerosols, taking into account scientific, economic, and political perspectives on the inclusion of BC in climate policies. Thus, the scope of the project is interdisciplinary and includes observations in the Arctic, model simulations of dispersion of BC aerosols, its radiative forcing and climate effects. Some initial results from measurements of BC content in snow from the Norwegian Arctic and corresponding measurements for surface reflectance will be presented. The radiative forcing of BC emissions from different geographical regions differs due to differences in the removal processes (i.e. the lifetime) and the amount of solar radiation available for absorption (depends on latitude, clouds, and surface albedo). The atmospheric burdens and RF (of the direct effect) of regional BC emissions from fossil fuel sources have been calculated by the global chemical transport model Oslo-CTM2 and a radiative transfer model, and first results of time-integrated RF per unit of emission (equivalent to absolute GWPs) are presented. Future plans including i) analysis of cost effective emission reduction strategies, taking into account regional differences the forcing efficiencies, but also cost estimates for BC reductions in the different regions, and ii) an evaluation of the climate effects of the emission reductions through model simulations, including climatic, economic and political perspectives exploring obstacles and opportunities will also be presented.

Use of aluminum sulfate (alum) to decrease ammonia emissions from beef cattle bedded manure packs

USDA-ARS?s Scientific Manuscript database

Confined cattle facilities are an increasingly common housing system in the Northern Great Plains of the United States. Ammonia volatilization from the surface of the floor and bedding in these confined facilities depends on several variables including pH, temperature, and moisture content. When pH ...

Decreased atmospheric sulfur deposition across the southeastern U.S.: When will watersheds release stored sulfate?

Treesearch

Karen C. Rice; Todd M. Scanlon; Jason A. Lynch; Bernard J. Cosby

2014-01-01

Emissions of sulfur dioxide (SO2) to the atmosphere lead to atmospheric deposition of sulfate (SO42-), which is the dominant strong acid anion causing acidification of surface waters and soils in the eastern United States. Since passage of the Clean Air Act and its Amendments, atmospheric deposition...

Linking Global to Regional Models to Assess Future Climate Impacts on Surface Ozone Concentrations in the United States

EPA Science Inventory

The UCD sectional aerosol model has been coupled to the CMAQ air quality model and used to simulate air quality in Tampa, Florida. Sea salt emissions are parameterized as a function of modeled wind speed and relative humidity. Modeled aerosol sulfate, nitrate, ammonium, sodium,...

Site-specific diel mercury emission fluxes in landfill: Combined effects of vegetation and meteorological factors.

PubMed

Liu, Yang; Wu, Boran; Hao, Yongxia; Zhu, Wei; Li, Zhonggen; Chai, Xiaoli

2017-01-01

Mercury emission fluxes (MEFs) under different surface coverage conditions in a landfill were investigated in this study. The results show similar diel patterns of Hg emission flux under different coverage conditions, with peak fluxes occurring at midday and decreasing during night. We examined the effects of environmental factors on MEFs, such as the physiological characteristics of vegetation and meteorological conditions. The results suggest that growth of vegetation in the daytime facilitates the release of Hg in the anaerobic unit, while in the semi-aerobic unit, where vegetation had been removed, the higher mercury content of the cover soil prompted the photo-reduction pathway to become the main path of mercury release and increased MEFs. MEFs are positively correlated with solar radiation and air temperature, but negatively correlated with relative humidity. The correlation coefficients for MEFs with different environmental parameters indicate that in the anaerobic unit, solar radiation was the main influence on MEFs in September, while air temperature became the main determining factor in December. These observations suggest that the effects of meteorological conditions on the mercury release mechanism varies depending on the vegetation and soil pathways. Copyright © 2016. Published by Elsevier Ltd.

Unexpected slowdown of US pollutant emission reduction in the past decade

PubMed Central

McDonald, Brian C.; Worden, Helen; Worden, John R.; Miyazaki, Kazuyuki; Qu, Zhen; Henze, Daven K.; Jones, Dylan B. A.; Fischer, Emily V.; Zhu, Liye; Boersma, K. Folkert

2018-01-01

Ground and satellite observations show that air pollution regulations in the United States (US) have resulted in substantial reductions in emissions and corresponding improvements in air quality over the last several decades. However, large uncertainties remain in evaluating how recent regulations affect different emission sectors and pollutant trends. Here we show a significant slowdown in decreasing US emissions of nitrogen oxides (NOx) and carbon monoxide (CO) for 2011–2015 using satellite and surface measurements. This observed slowdown in emission reductions is significantly different from the trend expected using US Environmental Protection Agency (EPA) bottom-up inventories and impedes compliance with local and federal agency air-quality goals. We find that the difference between observations and EPA’s NOx emission estimates could be explained by: (i) growing relative contributions of industrial, area, and off-road sources, (ii) decreasing relative contributions of on-road gasoline, and (iii) slower than expected decreases in on-road diesel emissions. PMID:29712822

N2O emissions from a nitrogen-enriched river

USGS Publications Warehouse

McMahon, P.B.; Dennehy, K.F.

1999-01-01

Nitrous oxide (N2O) emissions from the South Platte River in Colorado were measured using closed chambers in the fall, winter, and summer of 1994- 1995. The South Platte River was enriched in inorganic N (9-800 ??M) derived from municipal wastewater effluent and groundwater return flows from irrigated agricultural fields. River water was as much as 2500% supersaturated with N2O, and median N2O emission rates from the river surface ranged from less than 90 to 32 600 ??g-N m-2 d-1. Seventy-nine percent of the variance in N2O emission rates was explained by concentrations of total inorganic N in river water and by water temperature. The estimated total annual N2O emissions from the South Platte River were 2 x 1013-6 x 1013 ??g-N yr-1. This amount of annual N2O emissions was similar to the estimated annual N2O emissions from all primary municipal wastewater treatment processes in the United States (1). Results from this study indicate that N-enriched rivers could be important anthropogenic sources of N2O to the atmosphere. However, N2O emission measurements from other N-enriched rivers are needed to better quantify this source.Nitrous oxide (N2O) emissions from the South Platte River in Colorado were measured using closed chambers in the fall, winter, and summer of 1994-1995. The South Platte River was enriched in inorganic N (9-800 ??M) derived from municipal wastewater effluent and groundwater return flows from irrigated agricultural fields. River water was as much as 2500% supersaturated with N2O, and median N2O emission rates from the river surface ranged from less than 90 to 32 600 ??g-N m-2 d-1. Seventy-nine percent of the variance in N2O emission rates was explained by concentrations of total inorganic N in river water and by water temperature. The estimated total annual N2O emissions from the South Platte River were 2??1013-6??1013 ??g-N yr-1. This amount of annual N2O emissions was similar to the estimated annual N2O emissions from all primary municipal wastewater treatment processes in the United States. Results from this study indicate that N-enriched rivers could be important anthropogenic sources of N2O to the atmosphere. However, N2O emission measurements from other N-enriched rivers are needed to better quantify this source.

Zonally averaged thermal balance and stability models for nitrogen polar caps on Triton

NASA Technical Reports Server (NTRS)

Stansberry, John A.; Lunine, J. I.; Porco, C. C.; Mcewen, A. S.

1990-01-01

Voyager four-color imaging data of Triton are analyzed to calculate the bolometric hemispheric albedo as a function of latitude and longitude. Zonal averages of these data have been incorporated into a thermal balance model involving insolation, reradiation, and latent heat of sublimation of N2 ice for the surface. The current average bolometric albedo of Triton's polar caps is 0.8, implying an effective temperature of 34.2 K and a surface pressure of N2 of 1.6 microbar for unit emissivity. This pressure is an order of magnitude lower than the surface pressure of 18 microbar inferred from Voyager data (Broadfoot et al., 1989; Conrath et al., 1989), a discrepancy that can be reconciled if the emissivity of the N2 on Triton's surface is 0.66. The model predicts that Triton's surface north of 15 deg N latitude is experiencing deposition of N2 frosts, as are the bright portions of the south polar cap near the equator. This result explains why the south cap covers nearly the entire southern hemisphere of Triton.

Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States

NASA Astrophysics Data System (ADS)

Li, Jingyi; Mao, Jingqiu; Fiore, Arlene M.; Cohen, Ronald C.; Crounse, John D.; Teng, Alex P.; Wennberg, Paul O.; Lee, Ben H.; Lopez-Hilfiker, Felipe D.; Thornton, Joel A.; Peischl, Jeff; Pollack, Ilana B.; Ryerson, Thomas B.; Veres, Patrick; Roberts, James M.; Neuman, J. Andrew; Nowak, John B.; Wolfe, Glenn M.; Hanisco, Thomas F.; Fried, Alan; Singh, Hanwant B.; Dibb, Jack; Paulot, Fabien; Horowitz, Larry W.

2018-02-01

Widespread efforts to abate ozone (O3) smog have significantly reduced emissions of nitrogen oxides (NOx) over the past 2 decades in the Southeast US, a place heavily influenced by both anthropogenic and biogenic emissions. How reactive nitrogen speciation responds to the reduction in NOx emissions in this region remains to be elucidated. Here we exploit aircraft measurements from ICARTT (July-August 2004), SENEX (June-July 2013), and SEAC4RS (August-September 2013) and long-term ground measurement networks alongside a global chemistry-climate model to examine decadal changes in summertime reactive oxidized nitrogen (RON) and ozone over the Southeast US. We show that our model can reproduce the mean vertical profiles of major RON species and the total (NOy) in both 2004 and 2013. Among the major RON species, nitric acid (HNO3) is dominant (˜ 42-45 %), followed by NOx (31 %), total peroxy nitrates (ΣPNs; 14 %), and total alkyl nitrates (ΣANs; 9-12 %) on a regional scale. We find that most RON species, including NOx, ΣPNs, and HNO3, decline proportionally with decreasing NOx emissions in this region, leading to a similar decline in NOy. This linear response might be in part due to the nearly constant summertime supply of biogenic VOC emissions in this region. Our model captures the observed relative change in RON and surface ozone from 2004 to 2013. Model sensitivity tests indicate that further reductions of NOx emissions will lead to a continued decline in surface ozone and less frequent high-ozone events.

An Investigation of the Effects of Black Carbon on Precipitation in the Western United States

NASA Astrophysics Data System (ADS)

Tseng, Hsien-Liang Rose

Black carbon (BC), the byproduct of incomplete combustion, is considered to be the second most important anthropogenic climate forcing agent after carbon dioxide. BC warms the atmosphere by absorbing solar radiation (direct effect), alters cloud and precipitation formation by acting as cloud condensation nuclei (indirect effect), and modifies cloud distribution via cloud burn-off (semi-direct effect). Currently, there are large discrepancies in general circulation model estimates of the influence of BC on precipitation. Even less known is how BC changes precipitation on regional scales. In the drought-stricken western United States (WUS), where BC emissions are known to affect the hydrological cycle, an investigation on how BC influences precipitation is warranted. In this study, we employ the Weather Research and Forecasting-Chemistry (WRF Chem) model (version 3.6.0) with the newly chemistry- and microphysics-coupled Fu-Liou-Gu radiation scheme to study how black carbon affects precipitation by separating BC-related effects into direct and semi-direct, and indirect effects. In this three-part study, we use a recent wet year (2005) to investigate black carbon effects. We first examine BC effects during a heavy wintertime heavy precipitation event (7-11 January 2005), a heavy summertime precipitation week for comparison to the wintertime event (20-24 July 2005), and finally, examine these same effects for the months of January to June 2005 to investigate month-long trends. We find that BC suppresses precipitation, predominantly through its direct and semi-direct effects. The direct and semi-direct effects warm the air aloft, and cool the lower levels of the atmosphere (surface dimming) through the reduction of downward shortwave radiation flux at the surface. These changes in vertical temperature increase the stability of the atmosphere and reduce convective precipitation. Convective precipitation reduction accounts for approximately 60 75% of the total precipitation reduction. Additionally, cooling in the lower levels reduces evaporation from the surface, which reduces the moisture needed for non-convective precipitation. Subsequently, reduced moisture in the atmosphere suppresses non-convective precipitation by approximately 10-40%. The indirect effects also reduce precipitation, but to a much smaller extent of 5-20%. Although we use an atypical BC emission dataset is used in this study, the resulting reduction of the different types of precipitation sheds light on the physical mechanisms of BC-cloud-radiation interactions by which the reductions follow. In particular, our results highlight the importance of the cumulus and surface layer parameterizations that house the triggering mechanism and surface moisture flux parameterizations in future studies. In this research we find the NEI 2005 emissions did not significantly change precipitation. This is likely due to the aggressive emission regulations that exist for the United States. Emission regulations, however, do not exist or are enforced equally across the globe. In the developing countries that rely on inefficient cook stoves and heating systems, the populations suffer the most due to black carbon emission. Along with respiratory and cardiovascular impacts from black carbon, they may suffer from reduced water resources from suppressed precipitation, as well. In a larger sense, findings from this research serve as a platform for understanding the wider-reaching effects of black carbon on regional precipitation and drought. In particular, in areas where there are no black carbon emission regulations, this would highlight health and potentially significant environmental benefits that could be achieved from a black carbon cap and trade.

Quantification of methane sources in the Athabasca Oil Sands Region of Alberta by aircraft mass balance

NASA Astrophysics Data System (ADS)

Baray, Sabour; Darlington, Andrea; Gordon, Mark; Hayden, Katherine L.; Leithead, Amy; Li, Shao-Meng; Liu, Peter S. K.; Mittermeier, Richard L.; Moussa, Samar G.; O'Brien, Jason; Staebler, Ralph; Wolde, Mengistu; Worthy, Doug; McLaren, Robert

2018-05-01

Aircraft-based measurements of methane (CH4) and other air pollutants in the Athabasca Oil Sands Region (AOSR) were made during a summer intensive field campaign between 13 August and 7 September 2013 in support of the Joint Canada-Alberta Implementation Plan for Oil Sands Monitoring. Chemical signatures were used to identify CH4 sources from tailings ponds (BTEX VOCs), open pit surface mines (NOy and rBC) and elevated plumes from bitumen upgrading facilities (SO2 and NOy). Emission rates of CH4 were determined for the five primary surface mining facilities in the region using two mass-balance methods. Emission rates from source categories within each facility were estimated when plumes from the sources were spatially separable. Tailings ponds accounted for 45 % of total CH4 emissions measured from the major surface mining facilities in the region, while emissions from operations in the open pit mines accounted for ˜ 50 %. The average open pit surface mining emission rates ranged from 1.2 to 2.8 t of CH4 h-1 for different facilities in the AOSR. Amongst the 19 tailings ponds, Mildred Lake Settling Basin, the oldest pond in the region, was found to be responsible for the majority of tailings ponds emissions of CH4 ( > 70 %). The sum of measured emission rates of CH4 from the five major facilities, 19.2 ± 1.1 t CH4 h-1, was similar to a single mass-balance determination of CH4 from all major sources in the AOSR determined from a single flight downwind of the facilities, 23.7 ± 3.7 t CH4 h-1. The measured hourly CH4 emission rate from all facilities in the AOSR is 48 ± 8 % higher than that extracted for 2013 from the Canadian Greenhouse Gas Reporting Program, a legislated facility-reported emissions inventory, converted to hourly units. The measured emissions correspond to an emissions rate of 0.17 ± 0.01 Tg CH4 yr-1 if the emissions are assumed as temporally constant, which is an uncertain assumption. The emission rates reported here are relevant for the summer season. In the future, effort should be devoted to measurements in different seasons to further our understanding of the seasonal parameters impacting fugitive emissions of CH4 and to allow for better estimates of annual emissions and year-to-year variability.

Guiding U.S. Afforestation Policy through Terrestrial Carbon Cycle Modeling

NASA Astrophysics Data System (ADS)

Mykleby, P.; Snyder, P. K.; Twine, T. E.

2015-12-01

Afforestation has been proposed as a practical and viable solution for curtailing the ever-increasing levels of carbon dioxide in Earth's atmosphere. Individual states and multi-region cooperatives have established initiatives to offset carbon emissions using a variety of strategies, afforestation being one of them. While afforestation provides a positive benefit of increased carbon sequestration, this land cover change also produces a lower surface albedo, which can lead to local warming. Given these competing effects, carbon balance and surface energy budget analyses were performed for the northern United States and southern Canada, to determine where and for how long forest plantations should be planted to provide a positive benefit to the climate system. We use a dynamic vegetation model to analyze the competing effects of increased carbon sequestration versus increased net radiation at the surface from afforestation. In addition to determining where carbon sequestration (biogeochemical) would outweigh albedo (biophysical) effects, we calculate the amount of emissions offset for a variety of land use scenarios. As an example, in the state of Minnesota state officials have mandated that carbon emissions be reduced 80% from 2005 to 2050. While only taking into consideration land that is currently forested by mature forests and grasslands, the state would only offset about 11% of 2005 emissions annually by reforesting this land with younger, more productive forests. This example suggests that a significant amount of agricultural land would need to be converted into forest to make any sizeable offset to statewide greenhouse gas emissions.

An analysis of the impacts of global climate and emissions changes on regional tropospheric ozone

NASA Technical Reports Server (NTRS)

John, Kuruvilla; Crist, Kevin C.; Carmichael, Gregory R.

1994-01-01

Many of the synergistic impacts resulting from future changes in emissions as well as changes in ambient temperature, moisture, and UV flux have not been quantified. A three-dimensional regional-scale photo-chemical model (STEM-2) is used in this study to evaluate these perturbations to trace gas cycles over the eastern half of the United States of America. The model was successfully used to simulate a regional-scale ozone episode (base case - June 1984) and four perturbations scenarios - viz., perturbed emissions, temperature, water vapor column, and incoming UV flux cases, and a future scenario (for the year 2034). The impact of these perturbation scenarios on the distribution of ozone and other major pollutants such as SO2 and sulfates were analyzed in detail. The spatial distribution and the concentration of ozone at the surface increased by about 5-15 percent for most cases except for the perturbed water vapor case. The regional scale surface ozone concentration distribution for the year 2034 (future scenario) showed an increase of non-attainment areas. The rural areas of Pennsylvania, West Virginia, and Georgia showed the largest change in the surface ozone field for the futuristic scenario when compared to the base case.

Modeling climate change effects on runoff and soil erosion in southeastern Arizona rangelands and implications for mitigation with rangeland conservation practices

USDA-ARS?s Scientific Manuscript database

Climate change is expected to impact runoff and soil erosion on rangelands in the southwestern United States. This study was done to evaluate the potential impacts of precipitation changes on soil erosion and surface runoff in southeastern Arizona using seven GCM models with three emission scenarios...

Direct measurements of sample heating by a laser-induced air plasma in pre-ablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS).

PubMed

Register, Janna; Scaffidi, Jonathan; Angel, S Michael

2012-08-01

Direct measurements of temperature changes were made using small thermocouples (TC), placed near a laser-induced air plasma. Temperature changes up to ~500 °C were observed. From the measured temperature changes, estimates were made of the amount of heat absorbed per unit area. This allowed calculations to be made of the surface temperature, as a function of time, of a sample heated by the air plasma that is generated during orthogonal pre-ablation spark dual-pulse (DP) LIBS measurements. In separate experiments, single-pulse (SP) LIBS emission and sample ablation rate measurements were performed on nickel at sample temperatures ranging from room temperature to the maximum surface temperature that was calculated using the TC measurement results (500 °C). A small, but real sample temperature-dependent increase in both SP LIBS emission and the rate of sample ablation was found for nickel samples heated up to 500 °C. Comparison of DP LIBS emission enhancement values for bulk nickel samples at room temperature versus the enhanced SP LIBS emission and sample ablation rates observed as a function of increasing sample temperature suggests that sample heating by the laser-induced air plasma plays only a minor role in DP LIBS emission enhancement.

Compositional Variations of Titan's Impact Craters Indicates Active Surface Erosion

NASA Astrophysics Data System (ADS)

Werynski, Alyssa; Neish, Catherine; Le Gall, Alice; Janssen, Michael A.

2017-10-01

Titan’s crust is assumed to be mostly water-ice. However, the surface composition is not well constrained due to its thick atmosphere. Based on infrared and radiometry data, the surface appears enriched in organics, with only few areas showing evidence of exposed water-ice. Regions of water-ice enrichment include the rims and ejecta blankets of impact craters. This study utilizes these geologic features to examine compositional variations across Titan’s surface, and their subsequent modification due to erosional processes.Sixteen craters and their ejecta blankets were mapped on a Cassini RADAR mosaic. These features were selected because they are some of the best preserved craters on Titan. Composition was inferred from Cassini’s Visual and Infrared Mapping Spectrometer (VIMS) and 2-cm emissivity data from the Cassini radiometer. With VIMS, different compositional units were inferred from their reflectivity at specific wavelengths. With the emissivity data, high values suggest more organic-rich material, while lower values indicate strong volume scattering. Areas with low emissivity have been interpreted to be water-ice rich, as water-ice is a favorable medium for volume scattering.Results show fresher, well-preserved craters in the dunes regions have a low emissivity indicative of water-ice, and a VIMS spectrum consistent with an unknown material, possibly a mixture of water-ice and organics. As these craters erode over time, the VIMS spectra remain the same but the emissivity increases. Well-preserved craters in the mid-latitude plains show VIMS spectra and emissivity values consistent with water-ice. As these plain craters degrade, the VIMS spectra remain the same, but the emissivity increases. The differing VIMS signatures suggest more mixing with organics during the cratering event in the organic-rich dunes than the plains. The changes in emissivity over time are consistent with organic infilling of subsurface fractures in both regions, with limited surficial alteration. These results support the idea that compositional variations in Titan’s impact craters are related primarily to erosion and infilling, and to a lesser extent, local variations in the overlying organic material of the pre-impact substrate.

Design and evaluation of a low nitrogen oxides natural gas-fired conical wire-mesh duct burner for a micro-cogeneration unit

NASA Astrophysics Data System (ADS)

Ramadan, Omar Barka Ab

A novel low NOx conical wire-mesh duct burner was designed, built and tested in the present research. This thesis documents the design process and the in-depth evaluation of this novel duct burner for the development of a more efficient micro-cogeneration unit. This duct burner provides the thermal energy necessary to raise the microturbine exhaust gases temperature to increase the heat recovery capability. The duct burner implements both lean-premixed and surface combustion techniques to achieve low NOx and CO emissions. The design of the duct burner was supported by a qualitative flow visualization study for the duct burner premixer to provide insight into the premixer flow field (mixing process). Different premixer geometries were used to control the homogeneity of the fuel-oxidant mixture at the exit of the duct burner premixer. Laser sheet illumination (LSI) technique was used to capture images of the mixing process, for each configuration studied. A quasi-quantitative analysis technique was developed to rank the different premixer geometries in terms of mixing effectiveness. The premixer geometries that provided better mixing were selected and used for the combustion tests. The full-scale gas-fired duct burner was installed in the exhaust duct of a micro-cogeneration unit for the evaluation. Three wire-mesh burners with different pressure drops were used. Each burner has a conical shape made from FeCrAL alloy mat and was designed based on a heat release per unit area of 2500 kW/m2 and a total heat release of 240kW at 100 percent excess air. The local momentum of the gaseous mixture introduced through the wire-mesh was adjusted so that the flame stabilized outside the burner mesh (surface combustion). Cold flow tests (i.e., the duct burner was off, but the microturbine was running) were conducted to measure the effect of different duct burner geometrical parameters on flow split between the combustion zone and the bypass channel, and on pressure drop across the duct burner. A considerable amount of detailed parametric experimental data was collected to investigate the performance characteristics of the duct burner. The variables studied (firing rate, mass flow ratio, conical burner pressure drop, blockage ratio, conical burner shield length, premixer geometry and inlet conditions) were all found to play an important role on emissions (NOx and CO), overall duct burner pressure drop and flame stability. The range of firing rates at which surface combustion was maintained for the duct burner was defined by direct observation of the burner surface and monitoring of the temperature in the combustion zone. Flame images were captured for qualitative assessment. The combustion tests results presented in this thesis proved that the design procedures that were implemented to design this novel microturbine conical wire-mesh duct burner were successful. During the course of the combustion tests, the duct burner displayed stable, low emissions operation throughout the surface firing rate range of 148 kW to 328 kW (1574 kW/m 2 to 3489 kW/m2). Emissions of less than 5 ppm (corrected to 15 percent 02) for NOx and CO emissions were recorded, while the duct burner successfully raised the microturbine exhaust gases temperature from about 227°C to as high as 700°C. The overall duct burner pressure drop throughout was consistently below the design limit of 249 Pa.

40 CFR 49.153 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... this section). (C) Step 3. If any of the emissions units affected by your proposed modification result... not subject to this program. (2) Increase in an emissions unit's annual allowable emissions limit. If... emissions unit's allowable emissions of a regulated NSR pollutant above its existing annual allowable...

40 CFR 49.153 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... this section). (C) Step 3. If any of the emissions units affected by your proposed modification result... not subject to this program. (2) Increase in an emissions unit's annual allowable emissions limit. If... emissions unit's allowable emissions of a regulated NSR pollutant above its existing annual allowable...

40 CFR 49.153 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... this section). (C) Step 3. If any of the emissions units affected by your proposed modification result... not subject to this program. (2) Increase in an emissions unit's annual allowable emissions limit. If... emissions unit's allowable emissions of a regulated NSR pollutant above its existing annual allowable...

Expected ozone benefits of reducing nitrogen oxide (NOx) emissions from coal-fired electricity generating units in the eastern United States.

PubMed

Vinciguerra, Timothy; Bull, Emily; Canty, Timothy; He, Hao; Zalewsky, Eric; Woodman, Michael; Aburn, George; Ehrman, Sheryl; Dickerson, Russell R

2017-03-01

On hot summer days in the eastern United States, electricity demand rises, mainly because of increased use of air conditioning. Power plants must provide this additional energy, emitting additional pollutants when meteorological conditions are primed for poor air quality. To evaluate the impact of summertime NO x emissions from coal-fired electricity generating units (EGUs) on surface ozone formation, we performed a series of sensitivity modeling forecast scenarios utilizing EPA 2018 version 6.0 emissions (2011 base year) and CMAQ v5.0.2. Coal-fired EGU NO x emissions were adjusted to match the lowest NO x rates observed during the ozone seasons (April 1-October 31) of 2005-2012 (Scenario A), where ozone decreased by 3-4 ppb in affected areas. When compared to the highest emissions rates during the same time period (Scenario B), ozone increased ∼4-7 ppb. NO x emission rates adjusted to match the observed rates from 2011 (Scenario C) increased ozone by ∼4-5 ppb. Finally in Scenario D, the impact of additional NO x reductions was determined by assuming installation of selective catalytic reduction (SCR) controls on all units lacking postcombustion controls; this decreased ozone by an additional 2-4 ppb relative to Scenario A. Following the announcement of a stricter 8-hour ozone standard, this analysis outlines a strategy that would help bring coastal areas in the mid-Atlantic region closer to attainment, and would also provide profound benefits for upwind states where most of the regional EGU NO x originates, even if additional capital investments are not made (Scenario A). With the 8-hr maximum ozone National Ambient Air Quality Standard (NAAQS) decreasing from 75 to 70 ppb, modeling results indicate that use of postcombustion controls on coal-fired power plants in 2018 could help keep regions in attainment. By operating already existing nitrogen oxide (NO x ) removal devices to their full potential, ozone could be significantly curtailed, achieving ozone reductions by up to 5 ppb in areas around the source of emission and immediately downwind. Ozone improvements are also significant (1-2 ppb) for areas affected by cross-state transport, especially Mid-Atlantic coast regions that had struggled to meet the 75 ppb standard.

Improved estimates of biomass burning emissions in the southeast United States

NASA Astrophysics Data System (ADS)

Nowell, H.; Holmes, C.; Elsner, J.; Hiers, J. K.; Robertson, K.

2017-12-01

Biomass burning is a major source of gas and particle emissions that affects air quality, human health, and climate. Prescribed burns in the southeastern United States consume more biomass and cover a larger area than fires in the rest of the United States combined. Although fires can be detected remotely from thermal infrared emission and changes to surface reflectance, there are multiple issues that make satellite detections difficult in the eastern United States. These include small fire sizes, short duration, low intensity, canopy coverage, and rapid vegetation regrowth. Some attempts have been made to compensate for this bias, for example the small fire product in the Global Fire Emission Database (GFED4.1s) product. The accuracy of GFED and other remotely sensed global fire emission inventories are largely unknown, outside of a few field studies, mainly because there are few independent datasets of fire extent. The Florida Forest Service (FFS) has extensive records on fire type, size, location, and time for both prescribed and wild fires, which have not previously been used to evaluate fire area and emissions. For our study period of 2004 to 2016, we compared FFS burn authorization data against GFED4.1s burned area. When averaged across the state of Florida, there is 4 times more land burned than detected from satellite sensors. When comparing FFS data against high quality records from Apalachicola National Forest, Avon Park Air Force Range, Eglin Air Force Base, Tall Timbers Research Station, and Tyndall Air Force base, the areal discrepancy between these records and FFS reports are +/- 15%, well below the 4 times detection discrepancy between satellites and FFS reports. We have developed a method to statistically correct this satellite bias in fire detections. Treating the FFS burn authorizations as accurate, we have found this bias ratio can be predicted from fire size, land cover type, leaf area, and month. The regression model incorporating these factors can predict greater than 80% of variance in bias ratio across Florida during the summer months with correlations around 0.6 on average. This improved estimate of burned area in Florida will be used in global circulation models to determine the true contribution of prescribed wild fires in the southeast United States to gas and particle emissions.

High-Resolution Thermal Inertia Mapping from the Mars Global Surveyor Thermal Emission Spectrometer

USGS Publications Warehouse

Mellon, M.T.; Jakosky, B.M.; Kieffer, H.H.; Christensen, P.R.

2000-01-01

High-resolution thermal inertia mapping results are presented, derived from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) observations of the surface temperature of Mars obtained during the early portion of the MGS mapping mission. Thermal inertia is the key property controlling the diurnal surface temperature variations, and is dependent on the physical character of the top few centimeters of the surface. It represents a complex combination of particle size, rock abundance, exposures of bedrock, and degree of induration. In this work we describe the derivation of thermal inertia from TES data, present global scale analysis, and place these results into context with earlier work. A global map of nighttime thermal-bolometer-based thermal inertia is presented at 14?? per pixel resolution, with approximately 63% coverage between 50??S and 70??N latitude. Global analysis shows a similar pattern of high and low thermal inertia as seen in previous Viking low-resolution mapping. Significantly more detail is present in the high-resolution TES thermal inertia. This detail represents horizontal small-scale variability in the nature of the surface. Correlation with albedo indicates the presence of a previously undiscovered surface unit of moderate-to-high thermal inertia and intermediate albedo. This new unit has a modal peak thermal inertia of 180-250 J m-2 K-1 s-12 and a narrow range of albedo near 0.24. The unit, covering a significant fraction of the surface, typically surrounds the low thermal inertia regions and may comprise a deposit of indurated fine material. Local 3-km-resolution maps are also presented as examples of eolian, fluvial, and volcanic geology. Some impact crater rims and intracrater dunes show higher thermal inertias than the surrounding terrain; thermal inertia of aeolian deposits such as intracrater dunes may be related to average particle size. Outflow channels and valleys consistently show higher thermal inertias than the surrounding terrain. Generally, correlations between spatial variations in thermal inertia and geologic features suggest a relationship between the hundred-meter-scale morphology and the centimeter-scale surface layer. ?? 2000 Academic Press.

40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (or group of identical units) equipped with SCR (or SNCR) and uses dry low-NOX technology to control... with add-on NOX emission controls, and for units that use dry low-NOX technology, the owner or operator... mass emissions unit that uses dry low-NOX premix technology to control NOX emissions, proper operation...

Hydrochloric acid: an overlooked driver of environmental change.

PubMed

Evans, Chris D; Monteith, Don T; Fowler, David; Cape, J Neil; Brayshaw, Susan

2011-03-01

Research on the ecosystem impacts of acidifying pollutants, and measures to control them, has focused almost exclusively on sulfur (S) and nitrogen (N) compounds. Hydrochloric acid (HCl), although emitted by coal burning, has been overlooked as a driver of ecosystem change because most of it was considered to redeposit close to emission sources rather than in remote natural ecosystems. Despite receiving little regulatory attention, measures to reduce S emissions, and changes in energy supply, have led to a 95% reduction in United Kingdom HCl emissions within 20 years. Long-term precipitation, surface water, and soil solution data suggest that the near-disappearance of HCl from deposition could account for 30-40% of chemical recovery from acidification during this time, affecting both near-source and remote areas. Because HCl is highly mobile in reducing environments, it is a more potent acidifier of wetlands than S or N, and HCl may have been the major driver of past peatland acidification. Reduced HCl loadings could therefore have affected the peatland carbon cycle, contributing to increases in dissolved organic carbon leaching to surface waters. With many regions increasingly reliant on coal for power generation, HCl should be recognized as a potentially significant constituent of resulting emissions, with distinctive ecosystem impacts.

Evaluating commercial marine emissions and their role in air quality policy using observations and the CMAQ model

NASA Astrophysics Data System (ADS)

Ring, Allison M.; Canty, Timothy P.; Anderson, Daniel C.; Vinciguerra, Timothy P.; He, Hao; Goldberg, Daniel L.; Ehrman, Sheryl H.; Dickerson, Russell R.; Salawitch, Ross J.

2018-01-01

We investigate the representation of emissions from the largest (Class 3) commercial marine vessels (c3 Marine) within the Community Multiscale Air Quality (CMAQ) model. In present emissions inventories developed by the United States Environmental Protection Agency (EPA), c3 Marine emissions are divided into off-shore and near-shore files. Off-shore c3 Marine emissions are vertically distributed within the atmospheric column, reflecting stack-height and plume rise. Near-shore c3 Marine emissions, located close to the US shoreline, are erroneously assumed to occur only at the surface. We adjust the near-shore c3 Marine emissions inventory by vertically distributing these emissions to be consistent with the off-shore c3 Marine inventory. Additionally, we remove near-shore c3 Marine emissions that overlap with off-shore c3 Marine emissions within the EPA files. The CMAQ model generally overestimates surface ozone (O3) compared to Air Quality System (AQS) site observations, with the largest discrepancies occurring near coastal waterways. We compare modeled O3 from two CMAQ simulations for June, July, and August (JJA) 2011 to surface O3 observations from AQS sites to examine the efficacy of the c3 Marine emissions improvements. Model results at AQS sites show average maximum 8-hr surface O3 decreases up to ∼6.5 ppb along the Chesapeake Bay, and increases ∼3-4 ppb around Long Island Sound, when the adjusted c3 Marine emissions are used. Along with the c3 Marine emissions adjustments, we reduce on-road mobile NOX emissions by 50%, motivated by work from Anderson et al. 2014, and reduce the lifetime of the alkyl nitrate species group from ∼10 days to ∼1 day based on work by Canty et al. 2015, to develop the ;c3 Science; model scenario. Simulations with these adjustments further improve model representation of the atmosphere. We calculate the ratio of column formaldehyde (HCHO) and tropospheric column nitrogen dioxide (NO2) using observations from the Ozone Monitoring Instrument and CMAQ model output to investigate the photochemical O3 production regime (VOC or NOX-limited) of the observed and modeled atmosphere. Compared to the baseline, the c3 Science model scenario more closely simulates the HCHO/NO2 ratio calculated from OMI data. Model simulations for JJA 2018 using the c3 Science scenario show a reduction of surface O3 by as much as ∼13 ppb for areas around the Chesapeake Bay and ∼2-3 ppb at locations in NY and CT downwind of New York City. These reductions are larger in 2018 than in 2011 due to a change in the photochemical O3 production regime in the Long Island Sound region and the projected decline of other (non-c3 Marine) sources of O3 precursors, highlighting the importance of proper representation of c3 Marine emissions in future modeling scenarios.

On the angular variation of thermal infrared emissivity of inorganic soils

NASA Astrophysics Data System (ADS)

GarcíA-Santos, Vicente; Valor, Enric; Caselles, Vicente; ÁNgeles Burgos, M.; Coll, CéSar

2012-10-01

Land surface temperature (LST), a key parameter for many environmental studies, can be most readily estimated by using thermal infrared (TIR) sensors onboard satellites. Accurate LST are contingent upon simultaneously accurate estimates of land surface emissivity (ɛ), which depend on sensor viewing angle and the anisotropy of optical and structural properties of surfaces. In the case of inorganic bare soils (IBS), there are still few data that quantify emissivity angular effects. The present work deals with the angular variation of TIR emissivity for twelve IBS types, representative of nine of the twelve soil textures found on Earth according to United States Department of Agriculture classification. Emissivity was measured with a maximum error of ±0.01, in several spectral ranges within the atmospheric window 7.7-14.3 μm, at different zenithal (θ) and azimuthal (φ) angles. Results showed that ɛ of all IBS studied is almost azimuthally isotropic, and also zenithally up to θ = 40°, from which ɛ values decrease with the increase of θ. This decrease is most pronounced in sandy IBS which is rich in quartz reaching a maximum difference from nadir of +0.101 at θ = 70°. On the other hand, clayey IBS did not show a significant decrease of ɛ up to θ= 60°. A parameterization of the relative-to-nadir emissivity in terms ofθ and sand and clay percentage was established. Finally, the impact of ignoring ɛangular effects on the retrievals of LST, using split-window-type algorithms, and of outgoing longwave radiation, was analyzed. Results showed systematic errors ranging between ±0.4 K to ±1.3 K for atmospheres with water vapor values lower than 4 cm in the case of LST, and errors between 2%-8%, in the estimation of different terms of the surface energy balance.

Methane production and emissions from four reclaimed and pristine wetlands of Southeastern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schipper, L.A.; Reddy, K.R.

Wetlands are significant contributors to global CH[sub 4] emission. We measured CH[sub 4] emissions at two pristine wetlands [Okefenokee swamp and the Everglades (Water Conservation Area 2A)] and two reclaimed wetlands (Sunny Hill Farm and Apopka Marsh) in Southeastern USA, and we attempted to relate emissions to CH[sub 4] production rates of the soil and the soil's biological and chemical properties. Methane emissions through cattail [Typha sp.] and waterilly [Nymphaea ordorata (L.)] ranged from 0.09 to 1.7 g CH[sub 4] m[sup [minus]2] d[sup [minus]1] and exhibited high spatial and temporal variability. Diffusive flux of CH[sub 4] was calculated using dissolvedmore » CH[sub 4] profiles in the soil pore water and accounted for <5% of the plant-mediated emissions. Potential CH[sub 4] production rates were measured as a function of depth using soil samples obtained at 2-cm increments. Methane production rates were the same order of magnitude at all sites (<1-70 ng CH[sub 4]-C g[sup [minus]1] soil C d[sup [minus]1]) and were highest in the surface soils (0-6 cm) at three of the wetland sites, indicating that the predominant source of C available to methanogens was in the surface soils. Methane production rates in the top 24 cm ranged from 0.3 to 1.1 g CH[sub 4] m[sup [minus]2] d[sup [minus]1] and annual C losses due to anaerobic decomposition accounted for between 0.68 and 3.7% of the total C in the surface 24-cm soil depth. 36 refs., 3 figs., 3 tabs.« less

Quantifying the climate impacts of albedo changes due to biofuel production: a comparison with biogeochemical effects

NASA Astrophysics Data System (ADS)

Caiazzo, Fabio; Malina, Robert; Staples, Mark D.; Wolfe, Philip J.; Yim, Steve H. L.; Barrett, Steven R. H.

2014-01-01

Lifecycle analysis is a tool widely used to evaluate the climate impact of greenhouse gas emissions attributable to the production and use of biofuels. In this paper we employ an augmented lifecycle framework that includes climate impacts from changes in surface albedo due to land use change. We consider eleven land-use change scenarios for the cultivation of biomass for middle distillate fuel production, and compare our results to previous estimates of lifecycle greenhouse gas emissions for the same set of land-use change scenarios in terms of CO2e per unit of fuel energy. We find that two of the land-use change scenarios considered demonstrate a warming effect due to changes in surface albedo, compared to conventional fuel, the largest of which is for replacement of desert land with salicornia cultivation. This corresponds to 222 gCO2e/MJ, equivalent to 3890% and 247% of the lifecycle GHG emissions of fuels derived from salicornia and crude oil, respectively. Nine of the land-use change scenarios considered demonstrate a cooling effect, the largest of which is for the replacement of tropical rainforests with soybean cultivation. This corresponds to - 161 gCO2e/MJ, or - 28% and - 178% of the lifecycle greenhouse gas emissions of fuels derived from soybean and crude oil, respectively. These results indicate that changes in surface albedo have the potential to dominate the climate impact of biofuels, and we conclude that accounting for changes in surface albedo is necessary for a complete assessment of the aggregate climate impacts of biofuel production and use.

21st century United States emissions mitigation could increase water stress more than the climate change it is mitigating.

PubMed

Hejazi, Mohamad I; Voisin, Nathalie; Liu, Lu; Bramer, Lisa M; Fortin, Daniel C; Hathaway, John E; Huang, Maoyi; Kyle, Page; Leung, L Ruby; Li, Hong-Yi; Liu, Ying; Patel, Pralit L; Pulsipher, Trenton C; Rice, Jennie S; Tesfa, Teklu K; Vernon, Chris R; Zhou, Yuyu

2015-08-25

There is evidence that warming leads to greater evapotranspiration and surface drying, thus contributing to increasing intensity and duration of drought and implying that mitigation would reduce water stresses. However, understanding the overall impact of climate change mitigation on water resources requires accounting for the second part of the equation, i.e., the impact of mitigation-induced changes in water demands from human activities. By using integrated, high-resolution models of human and natural system processes to understand potential synergies and/or constraints within the climate-energy-water nexus, we show that in the United States, over the course of the 21st century and under one set of consistent socioeconomics, the reductions in water stress from slower rates of climate change resulting from emission mitigation are overwhelmed by the increased water stress from the emissions mitigation itself. The finding that the human dimension outpaces the benefits from mitigating climate change is contradictory to the general perception that climate change mitigation improves water conditions. This research shows the potential for unintended and negative consequences of climate change mitigation.

Lightning Nitrogen Oxides (LNOx) Vertical Profile Quantification and 10 Year Trend Analysis using Ozone Monitoring Instrument (OMI) Satellite Measurements, Air Quality Station (AQS) Surface Measurements, The National Lightning Detection Network (NLDN), and Simulated by Cloud Resolving Chemical Transport Model (REAM Cloud)

NASA Astrophysics Data System (ADS)

Smeltzer, C. D.; Wang, Y.; Koshak, W. J.

2014-12-01

Vertical profiles and emission lifetimes of lightning nitrogen oxides (LNOx) are derived using the Ozone Monitoring Instrument (OMI). Approximately 200 million flashes, over a 10 year climate period, from the United States National Lighting Detection Network (NLDN), are aggregated with OMI cloud top height to determine the vertical LNOx structure. LNOx lifetime is determined as function of LNOx signal in a 36 kilometer vertical column from the time of the last known flash to depletion of the LNOx signal. Environmental Protection Agency (EPA) Air Quality Station (AQS) surface data further support these results by demonstrating as much as a 200% increase in surface level NO2 during strong thunderstorm events and a lag as long as 5 to 8 hours from the lightning event to the peak surface event, indicating a evolutional process. Analysis of cloud resolving chemical transport model (REAM Cloud) demonstrates that C-shaped LNOx profiles, which agree with OMI vertical profile observations, evolve due to micro-scale convective meteorology given inverted C-shaped LNOx emission profiles as determined from lightning radio telemetry. It is shown, both in simulations and in observations, that the extent to which the LNOx vertical distribution is C-shaped and the lifetime of LNOx is proportional to the shear-strength of the thunderstorm. Micro-scale convective meteorology is not adequately parameterized in global scale and regional scale chemical transport models (CTM). Therefore, these larger scale CTMs ought to use a C-shape emissions profile to best reproduce observations until convective parameterizations are updated. These findings are used to simulate decadal LNOx and lightning ozone climatology over the Continental United States (CONUS) from 2004-2014.

Evaluation of High Resolution Rapid Refresh-Smoke (HRRR-Smoke) model products for a case study using surface PM2.5 observations

NASA Astrophysics Data System (ADS)

Deanes, L. N.; Ahmadov, R.; McKeen, S. A.; Manross, K.; Grell, G. A.; James, E.

2016-12-01

Wildfires are increasing in number and size in the western United States as climate change contributes to warmer and drier conditions in this region. These fires lead to poor air quality and diminished visibility. The High Resolution Rapid Refresh-Smoke modeling system (HRRR-Smoke) is designed to simulate fire emissions and smoke transport with high resolution. The model is based on the Weather Research and Forecasting model, coupled with chemistry (WRF-Chem) and uses fire detection data from the Visible Infrared and Imaging Radiometer Suite (VIIRS) satellite instrument to simulate wildfire emissions and their plume rise. HRRR-Smoke is used in both real-time applications and case studies. In this study, we evaluate the HRRR-Smoke for August 2015, during one of the worst wildfire seasons on record in the United States, by focusing on wildfires that occurred in the northwestern US. We compare HRRR-Smoke simulations with hourly fine particulate matter (PM2.5) observations from the Air Quality System (https://www.epa.gov/aqs) from multiple air quality monitoring sites in Washington state. PM2.5 data includes measurements from urban, suburban and remote sites in the state. We discuss the model performance in capturing large PM2.5 enhancements detected at surface sites due to wildfires. We present various statistical parameters to demonstrate HRRR-Smoke's performance in simulating surface PM2.5 levels.

A new physically-based windblown dust emission ...

EPA Pesticide Factsheets

Dust has significant impacts on weather and climate, air quality and visibility, and human health; therefore, it is important to include a windblown dust emission module in atmospheric and air quality models. In this presentation, we summarize our efforts in development of a physics-based windblown dust emission scheme and its implementation in the CMAQ modeling system. The new model incorporates the effect of the surface wind speed, soil texture, soil moisture, and surface roughness in a physically sound manner. Specifically, a newly developed dynamic relation for the surface roughness length in this model is believed to adequately represent the physics of the surface processes involved in the dust generation. Furthermore, careful attention is paid in integrating the new windblown dust module within the CMAQ to ensure that the required input parameters are correctly configured. The new model is evaluated for the case studies including the continental United States and the Northern hemisphere, and is shown to be able to capture the occurrence of the dust outbreak and the level of the soil concentration. We discuss the uncertainties and limitations of the model and briefly describe our path forward for further improvements. The National Exposure Research Laboratory (NERL) Computational Exposure Division (CED) develops and evaluates data, decision-support tools, and models to be applied to media-specific or receptor-specific problem areas. CED uses modeling-based

Factor analysis of submicron particle size distributions near a major United States-Canada trade bridge.

PubMed

Ogulei, David; Hopke, Philip K; Ferro, Andrea R; Jaques, Peter A

2007-02-01

A factor analytic model has been applied to resolve and apportion particles based on submicron particle size distributions downwind of a United States-Canada bridge in Buffalo, NY. The sites chosen for this study were located at gradually increasing distances downwind of the bridge complex. Seven independent factors were resolved, including four factors that were common to all of the five sites considered. The common factors were generally characterized by the existence of two or more number and surface area modes. The seven factors resolved were identified as follows: fresh tail-pipe diesel exhaust, local/street diesel traffic, aged/evolved diesel particles, spark-ignition gasoline emissions, background urban emissions, heavy-duty diesel agglomerates, and secondary/transported material. Submicron (<0.5 microm) and ultrafine (<0.1 microm) particle emissions downwind of the bridge were dominated by commercial diesel truck emissions. Thus, this study obtained size distinction between fresh versus aged vehicle exhaust and spark-ignition versus diesel emissions based on the measured high time-resolution particle number concentrations. Because this study mainly used particles <300 nm in diameter, some sources that would usually exhibit number modes >100 nm were not resolved. Also, the resolved profiles suggested that the major number mode for fresh tailpipe diesel exhaust might exist below the detection limit of the spectrometer used. The average particle number contributions from the resolved factors were highest closest to the bridge.

Evaluation of Space-Based Constraints on Global Nitrogen Oxide Emissions with Regional Aircraft Measurements over and Downwind of Eastern North America

NASA Technical Reports Server (NTRS)

Martin, Randall V.; Sioris, Christopher E.; Chance, Kelly; Ryerson, Thomas B.; Flocke, Frank M.; Bertram, Timothy H.; Wooldridge, Paul J.; Cohen, Ronald C.; Neuman, J. Andy; Swanson, Aaron

2006-01-01

We retrieve tropospheric nitrogen dioxide (NO 2) columns for May 2004 to April 2005 from the SCIAMACHY satellite instrument to derive top-down emissions of nitrogen oxides (NO(x) = NO + NO2) via inverse modeling with a global chemical transport model (GEOS-Chem). Simulated NO 2 vertical profiles used in the retrieval are evaluated with airborne measurements over and downwind of North America (ICARTT); a northern midlatitude lightning source of 1.6 Tg N/yr minimizes bias in the retrieval. Retrieved NO2 columns are validated (r2 = 0.60, slope = 0.82) with coincident airborne in situ measurements. The top-down emissions are combined with a priori information from a bottom-up emission inventory with error weighting to achieve an improved a posteriori estimate of the global distribution of surface NOx emissions. Our a posteriori NOx emission inventory for land surface NOx emissions (46.1 Tg N/yr) is 22% larger than the GEIA-based a priori bottom-up inventory for 1998, a difference that reflects rising anthropogenic emissions, especially from East Asia A posteriori NOx emissions for East Asia (9.8 Tg N/yr) exceed those from other continents. The a posteriori inventory improves the GEOS-Chem simulation of NOx, peroxyacetylnitrate, and nitric acid with respect to airborne in situ measurements over and downwind of New York City. The a posteriori is 7% larger than the EDGAR 3.2FT2000 global inventory, 3% larger than the NEI99 inventory for the United States, and 68% larger than a regional inventory for 2000 for eastern Asia. SCIAMACHY NO2 columns over the North Atlantic show a weak plume from lightning NO(x).

Impacts of global, regional, and sectoral black carbon emission reductions on surface air quality and human mortality

NASA Astrophysics Data System (ADS)

Anenberg, S. C.; Talgo, K.; Arunachalam, S.; Dolwick, P.; Jang, C.; West, J. J.

2011-04-01

As a component of fine particulate matter (PM2.5), black carbon (BC) is associated with premature human mortality. BC also affects climate by absorbing solar radiation and reducing planetary albedo. Several studies have examined the climate impacts of BC emissions, but the associated health impacts have been studied less extensively. Here, we examine the surface PM2.5 and premature mortality impacts of halving anthropogenic BC emissions globally, from eight world regions, and from three major economic sectors. We use a global chemical transport model, MOZART-4, to simulate PM2.5 concentrations and a health impact function to calculate premature cardiopulmonary and lung cancer deaths. We estimate that halving global anthropogenic BC emissions reduces outdoor population-weighted average PM2.5 by 542 ng m-3 (1.8%) and avoids 157 000 (95% confidence interval, 120 000-194 000) annual premature deaths globally, with the vast majority occurring within the source region. While most of these avoided deaths can be achieved by halving East Asian emissions (54%), followed by South Asian emissions (31%), South Asian emissions have 50% greater mortality impacts per unit BC emitted than East Asian emissions. Globally, the contribution of residential, industrial, and transportation BC emissions to PM2.5-related mortality is 1.3, 1.2, and 0.6 times each sector's contribution to anthropogenic BC emissions, owing to the degree of co-location with population. Impacts of residential BC emissions are underestimated since indoor PM2.5 exposure is excluded. We estimate ~8 times more avoided deaths when BC and organic carbon (OC) emissions are halved together, suggesting that these results greatly underestimate the full air pollution-related mortality benefits of BC mitigation strategies which generally decrease both BC and OC. Confidence in our results would be strengthened by reducing uncertainties in emissions, model parameterization of aerosol processes, grid resolution, and PM2.5 concentration-mortality relationships globally.

Estimating Emissions of Ammonia and Methane from an Anaerobic Livestock Lagoon Using Micrometeorological Methods and Inverse Modeling

NASA Astrophysics Data System (ADS)

Shonkwiler, K. B.; Ham, J. M.; Williams, C.

2012-12-01

Evaluating the impact of increased carbon and nitrogen emissions on local air quality and regional bionetworks due to animal agricultural activity is of great interest to the public, political, economic and ecological welfare of areas within the scope of these practices. Globally, livestock operations account for 64% of annual anthropogenic emissions of ammonia (NH3) [1]. Concerning methane (CH4), anaerobic lagoons from commercial dairy operations contribute the second largest share of CH4 emissions from manure in the United States[1], and additionally are a local source of NH3 as well. Anaerobic lagoons are commonly used in commercial animal agriculture and as significant local sources of greenhouse gases (GHG), there is a strong need to quantify GHG emissions from these systems. In 2012 at a commercial dairy operation in Northern Colorado, USA, measurements of CH4 were made using eddy covariance (EC), while NH3 was estimated using a combination of real-time monitoring (cavity ring-down spectroscopy as well as time-integrated passive samplers). Methane emissions have been measured at this lagoon using EC since 2011, with fluxes ranging from 0.5 mg m-2 s-1 in early summer to >2 mg m-2 s-1 in late summer and early fall. Concentration data of both CH4 and NH3 were used to estimate emissions using a 2-dimensional inverse model based on solving the advection-diffusion equation[2]. In the case of the CH4-EC data, results from the inverse model were compared with the EC-derived flux estimates for enhanced parameterization of surface geometry within the lagoon environment. The model was then applied using measured NH3 concentrations to achieve emissions estimates. While NH3 fluxes from the lagoon tend to be much lower than those of CH4 by comparison, modeling emissions of NH3 from the simple geometry of a lagoon will assist in applying the model to more complex surfaces. [1] FAO, 2006. Livestock's long shadow: Environmental issues and options. Livestock, Environment, and Development Initiative. Food and Agriculture Organization of the United Nations, Rome, Italy. [2] Loubet, B., Génermont, S., Ferrara, R., Bedos, C., Decuq, C., Personne, E., Fanucci, O., Durand, B., Rana, G., Cellier, P., 2010. An inverse model to estimate ammonia emissions from fields. Eur. J. Soil Sci. 61: 793-805. Panorama of a weather station (left) utilizing micrometeorological methods to aid in estimating emissions of methane and ammonia from an anaerobic livestock lagoon (center) at a commercial dairy in Northern Colorado, USA.

Evidence of the Atlantic Multidecadal Oscillation driving multi-decadal variability of summertime surface air quality in the eastern United States: Implications for air quality management in the coming decades

NASA Astrophysics Data System (ADS)

Shen, L.; Mickley, L. J.

2016-12-01

Atlantic sea surface temperatures have a significant influence on the summertime meteorology and air quality in the eastern United States. In this study, we investigate the effect of the Atlantic Multidecadal Oscillation (AMO) on two key air pollutants, surface ozone and PM2.5, over the eastern United States. The shift of AMO from cold to warm phase increases surface air temperatures by 0.5 K across the East and reduces precipitation, resulting in a warmer and drier summer. By applying observed, present-day relationships between these pollutants and meteorological variables to a variety of observations and historical reanalysis datasets, we calculate the impacts of AMO on U.S. air quality. Our study reveals a multidecadal variability in mean summertime (JJA) maximum daily 8-hour (MDA8) ozone and surface PM2.5 concentrations in the eastern United States. In one-half cycle ( 30 years) of the AMO from negative to positive phase with constant anthropogenic emissions, JJA MDA8 ozone concentrations increase by 1-3 ppbv in the Northeast and 2-5 ppbv in the Great Plains; JJA PM2.5 concentrations increase by 0.8-1.2 μg m-3 in the Northeast and Southeast. The resulting impact on mortality rates is 4000 excess deaths per half cycle of AMO. We suggest that a complete picture of air quality management in coming decades requires consideration of the AMO influence.

Regional aerosol emissions and temperature response: Local and remote climate impacts of regional aerosol forcing

NASA Astrophysics Data System (ADS)

Lewinschal, Anna; Ekman, Annica; Hansson, Hans-Christen

2017-04-01

Emissions of anthropogenic aerosols vary substantially over the globe and the short atmospheric residence time of aerosols leads to a highly uneven radiative forcing distribution, both spatially and temporally. Regional aerosol radiative forcing can, nevertheless, exert a large influence on the temperature field away from the forcing region through changes in heat transport or the atmospheric or ocean circulation. Moreover, the global temperature response distribution to aerosol forcing may vary depending on the geographical location of the forcing. In other words, the climate sensitivity in one region can vary depending on the location of the forcing. The surface temperature distribution response to changes in sulphate aerosol forcing caused by sulphur dioxide (SO2) emission perturbations in four different regions is investigated using the Norwegian Earth System Model (NorESM). The four regions, Europe, North America, East and South Asia, are all regions with historically high aerosol emissions and are relevant from both an air-quality and climate policy perspective. All emission perturbations are defined relative to the year 2000 emissions provided for the Coupled Model Intercomparison Project phase 5. The global mean temperature change per unit SO2 emission change is similar for all four regions for similar magnitudes of emissions changes. However, the global temperature change per unit SO2 emission in simulations where regional SO2 emission were removed is substantially higher than that obtained in simulations where regional SO2 emissions were increased. Thus, the climate sensitivity to regional SO2 emissions perturbations depends on the magnitude of the emission perturbation in NorESM. On regional scale, on the other hand, the emission perturbations in different geographical locations lead to different regional temperature responses, both locally and in remote regions. The results from the model simulations are used to construct regional temperature potential (RTP) coefficients, which directly link regional aerosol or aerosol precursor emissions to the temperature response in different regions. These RTP coefficients can provide a simplified way to perform an initial evaluation of climate impacts of e.g. different emission policy pathways and pollution abatement strategies.

Application of OMI Observations to a Space-Based Indicator of NOx and VOC Controls on Surface Ozone Formation

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; Olson, Jennifer R.; Sillman, Sanford; Martin, Randall V.; Lamsal, Lok; Hu, Yongtao; Pickering, Kenneth E.; Retscher, Christian; Allen, Dale J.;

Low power arcjet system spacecraft impacts

NASA Technical Reports Server (NTRS)

Pencil, Eric J.; Sarmiento, Charles J.; Lichtin, D. A.; Palchefsky, J. W.; Bogorad, A. L.

1993-01-01

Application of electrothermal arcjets on communications satellites requires assessment of integration concerns identified by the user community. Perceived risks include plume contamination of spacecraft materials, induced arcing or electrostatic discharges between differentially charged spacecraft surfaces, and conducted and radiated electromagnetic interference (EMI) for both steady state and transient conditions. A Space Act agreement between Martin Marietta Astro Space, the Rocket Research Company, and NASA's Lewis Research Center was established to experimentally examine these issues. Spacecraft materials were exposed to an arcjet plume for 40 hours, representing 40 weeks of actual spacecraft life, and contamination was characterized by changes in surface properties. With the exception of the change in emittance of one sample, all measurable changes in surface properties resulted in acceptable end of life characteristics. Charged spacecraft samples were benignly and consistently reduced to ground potential during exposure to the powered arcjet plume, suggesting that the arcjet could act as a charge control device on spacecraft. Steady state EMI signatures obtained using two different power processing units were similar to emissions measured in a previous test. Emissions measured in UHF, S, C, Ku and Ka bands obtained a null result which verified previous work in the UHF, S, and C bands. Characteristics of conducted and radiated transient emissions appear within standard spacecraft susceptibility criteria.

WETCHIMP-WSL: Intercomparison of wetland methane emissions models over West Siberia

DOE PAGES

Bohn, T. J.; Melton, J. R.; Ito, A.; ...

2015-06-03

Wetlands are the world's largest natural source of methane, a powerful greenhouse gas. The strong sensitivity of methane emissions to environmental factors such as soil temperature and moisture has led to concerns about potential positive feedbacks to climate change. This risk is particularly relevant at high latitudes, which have experienced pronounced warming and where thawing permafrost could potentially liberate large amounts of labile carbon over the next 100 years. However, global models disagree as to the magnitude and spatial distribution of emissions, due to uncertainties in wetland area and emissions per unit area and a scarcity of in situ observations.more » Recent intensive field campaigns across the West Siberian Lowland (WSL) make this an ideal region over which to assess the performance of large-scale process-based wetland models in a high-latitude environment. Here we present the results of a follow-up to the Wetland and Wetland CH 4 Intercomparison of Models Project (WETCHIMP), focused on the West Siberian Lowland (WETCHIMP-WSL). We assessed 21 models and 5 inversions over this domain in terms of total CH 4 emissions, simulated wetland areas, and CH 4 fluxes per unit wetland area and compared these results to an intensive in situ CH 4 flux data set, several wetland maps, and two satellite surface water products. We found that (a) despite the large scatter of individual estimates, 12-year mean estimates of annual total emissions over the WSL from forward models (5.34 ± 0.54 Tg CH 4 yr⁻¹), inversions (6.06 ± 1.22 Tg CH 4 yr⁻¹), and in situ observations (3.91 ± 1.29 Tg CH 4 yr⁻¹) largely agreed; (b) forward models using surface water products alone to estimate wetland areas suffered from severe biases in CH 4 emissions; (c) the interannual time series of models that lacked either soil thermal physics appropriate to the high latitudes or realistic emissions from unsaturated peatlands tended to be dominated by a single environmental driver (inundation or air temperature), unlike those of inversions and more sophisticated forward models; (d) differences in biogeochemical schemes across models had relatively smaller influence over performance; and (e) multiyear or multidecade observational records are crucial for evaluating models' responses to long-term climate change.« less

77 FR 26476 - Standards of Performance for Greenhouse Gas Emissions for New Stationary Sources: Electric...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-04

... Performance for Greenhouse Gas Emissions for New Stationary Sources: Electric Utility Generating Units AGENCY... Greenhouse Gas Emissions for New Stationary Sources: Electric Utility Generating Units.'' The EPA is making... for Greenhouse Gas Emissions for New Stationary Sources: Electric Utility Generating Units, and...

TESTING CMAQ CHEMISTRY SENSITIVITIES IN BASE CHASE AND EMISSION CONTROL RUNS AT SEARCH AND SOS 99 SURFACE SITES IN THE SOUTHEASTERN UNITED STATES

EPA Science Inventory

CMAQ was run to simulate urban conditions in the southeastern U.S. in July 1999 at 32, 8, and 2 km grid spacings. Runs were made with two older mechanisms, Carbon Bond IV (CB4) and the Regional Acid Deposition Model, version 2 (RADM2), and with the more recent California Statewid...

Improving Simulations of Fine Dust Surface Concentrations over the Western United States by Optimizing the Particle Size Distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Li; Kok, Jasper F.; Henze, Daven

2013-06-28

To improve estimates of remote contributions of dust to fine particulate matter (PM2.5) in the western United States, new dust particle size distributions (PSDs) based upon scale-invariant fragmentation theory (Kok_PSD) with constraints from in situ measurements (IMP_PSD) are implemented in a chemical transport model (GEOS-Chem). Compared to initial simulations, this leads to reductions in the mass of emitted dust particles with radii <1.8 mm by 40%-60%. Consequently, the root-mean-square error in simulated fine dust concentrations compared to springtime surface observations in the western United States is reduced by 67%-81%. The ratio of simulated fine to coarse PM mass is alsomore » improved, which is not achievable by reductions in total dust emissions. The IMP_PSD best represents the PSD of dust transported from remote sources and reduces modeled PM2.5 concentrations up to 5 mg/m3 over the western United States, which is important when considering sources contributing to nonattainment of air quality standards. Citation: Zhang, L., J. F. Kok, D. K. Henze, Q. Li, and C. Zhao (2013), Improving simulations of fine dust surface concentrations over the western United States by optimizing the particle size distribution, Geophys. Res. Lett., 40, 3270-3275, doi:10.1002/grl.50591.« less

Analysis of very-high-resolution Galileo images of Europa: Implications for small-scale structure and surface evolution

NASA Astrophysics Data System (ADS)

Leonard, E. J.; Pappalardo, R. T.; Yin, A.; Prockter, L. M.; Patthoff, D. A.

2014-12-01

The Galileo Solid State Imager (SSI) recorded nine very high-resolution frames (8 at 12 m/pixel and 1 at 6 m/pixel) during the E12 flyby of Europa in Dec. 1997. To understand the implications for the small-scale structure and evolution of Europa, we mosaicked these frames (observations 12ESMOTTLE01 and 02, incidence ≈18°, emission ≈77°) into their regional context (part of observation 11ESREGMAP01, 220 m/pixel, incidence ≈74°, emission ≈23°), despite their very different viewing and lighting conditions. We created a map of geological units based on morphology, structure, and albedo along with stereoscopic images where the frames overlapped. The highly diverse units range from: high albedo sub-parallel ridge and grooved terrain; to variegated-albedo hummocky terrain; to low albedo and relatively smooth terrain. We classified and analyzed the diverse units solely based on the high-resolution image mosaic, prior to comparison to the context image, to obtain an in-depth look at possible surface evolution and underlying formational processes. We infer that some of these units represent different stages and forms of resurfacing, including cryovolcanic and tectonic resurfacing. However, significant morphological variation among units in the region indicates that there are different degrees of resurfacing at work. We have created candidate morphological sequences that provide insight into the conversion of ridged plains to chaotic terrain—generally, a process of subduing formerly sharp features through tectonic modification and/or cryovolcanism. When the map of the high-resolution area is compared to the regional context, features that appear to be one unit at regional resolution are comprised of several distinct units at high resolution, and features that appear to be smooth in the context image are found to show distinct textures. Moreover, in the context image, transitions from ridged units to disrupted units appear to be gradual; however the high-resolution image reveals them to be abrupt, suggesting tectonic control of these boundaries. These discrepancies could have important implications for a future landed exploration.

Surface Emissivity Maps for Use in Satellite Retrievals of Longwave Radiation

NASA Technical Reports Server (NTRS)

Wilber, Anne C.; Kratz, David P.; Gupta, Shashi K.

1999-01-01

Accurate accounting of surface emissivity is essential for the retrievals of surface temperature from remote sensing measurements, and for the computations of longwave (LW) radiation budget of the Earth?s surface. Past studies of the above topics assumed that emissivity for all surface types, and across the entire LW spectrum is equal to unity. There is strong evidence, however, that emissivity of many surface materials is significantly lower than unity, and varies considerably across the LW spectrum. We have developed global maps of surface emissivity for the broadband LW region, the thermal infrared window region (8-12 micron), and 12 narrow LW spectral bands. The 17 surface types defined by the International Geosphere Biosphere Programme (IGBP) were adopted as such, and an additional (18th) surface type was introduced to represent tundra-like surfaces. Laboratory measurements of spectral reflectances of 10 different surface materials were converted to corresponding emissivities. The 10 surface materials were then associated with 18 surface types. Emissivities for the 18 surface types were first computed for each of the 12 narrow spectral bands. Emissivities for the broadband and the window region were then constituted from the spectral band values by weighting them with Planck function energy distribution.

Estimating the impact of the 2004 Alaskan forest fires on episodic particulate matter pollution over the eastern United States through assimilation of satellite-derived aerosol optical depths in a regional air quality model

NASA Astrophysics Data System (ADS)

Mathur, Rohit

2008-09-01

During the summer of 2004, extensive wildfires burned in Alaska and western Canada; the fires were the largest on record for Alaska. Smoke from these fires was observed over the continental United States in satellite images, and a variety of chemical tracers associated with the fires were sampled by aircrafts deployed during the International Consortium for Atmospheric Research on Transport and Transformation field experiment. Several recent studies have quantified the impacts of the long-range transport of pollution associated with these fires on tropospheric CO and O3 levels over the eastern United States. This study quantifies the episodic impact of this pollution transport event on surface-level fine particulate matter (PM2.5) concentrations over the eastern United States during mid-July 2004, through the complementary use of remotely sensed, aloft, and surface measurements, in conjunction with a comprehensive regional atmospheric chemistry-transport model. A methodology is developed to assimilate MODIS aerosol optical depths in the model to represent the impacts of the fires. The resultant model predictions of CO and PM2.5 distributions are compared extensively with corresponding surface and aloft measurements. On the basis of the model calculations, a 0.12Tg enhancement in tropospheric PM2.5 mass loading over the eastern United States is estimated on 19 July 2004 due to the fires. This amount is significantly larger (approximately a factor of 8) than the total daily anthropogenic fine particulate matter emissions for the continental United States. Analysis of measured and modeled PM2.5 surface-level concentrations suggests that the transport of particulate matter pollution associated with the fires resulted in a 24-42 % enhancement in median surface-level PM2.5 concentrations across the eastern United States during 19-23 July 2004.

the Underestimation of Isorene in Houston during the Texas 2013 DISCOVER-AQ Campaign

NASA Astrophysics Data System (ADS)

Choi, Y.; Diao, L.; Czader, B.; Li, X.; Estes, M. J.

2014-12-01

This study applies principal component analysis to aircraft data from the Texas 2013 DISCOVER-AQ (Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality) field campaign to characterize isoprene sources over Houston during September 2013. The biogenic isoprene signature appears in the third principal component and anthropogenic signals in the following two. Evaluations of the Community Multiscale Air Quality (CMAQ) model simulations of isoprene with airborne measurements are more accurate for suburban areas than for industrial areas. This study also compares model outputs to eight surface automated gas chromatograph (Auto-GC) measurements near the Houston ship channel industrial area during the nighttime and shows that modeled anthropogenic isoprene is underestimated by a factor of 10.60. This study employs a new simulation with a modified anthropogenic emissions inventory (constraining using the ratios of observed values versus simulated ones) that yields closer isoprene predictions at night with a reduction in the mean bias by 56.93%, implying that model-estimated isoprene emissions from the 2008 National Emission Inventory are underestimated in the city of Houston and that other climate models or chemistry and transport models using the same emissions inventory might also be underestimated in other Houston-like areas in the United States.

40 CFR 75.73 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.73 Recordkeeping and reporting... for units using the low mass emissions unit provisions of § 75.19). (3) For each hour when the unit is operating, NOX mass emissions, calculated in accordance with section 8.1 of appendix F to this part. (4...

40 CFR 63.1568 - What are my requirements for HAP emissions from sulfur recovery units?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true What are my requirements for HAP emissions from sulfur recovery units? 63.1568 Section 63.1568 Protection of Environment ENVIRONMENTAL... requirements for HAP emissions from sulfur recovery units? (a) What emission limitations and work practice...

Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data.

PubMed

Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

2015-01-01

Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program's (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales.

Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data

PubMed Central

Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

2015-01-01

Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program’s (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales. PMID:26390037

Surface Emissivity Effects on Thermodynamic Retrieval of IR Spectral Radiance

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Smith, William L.; Liu, Xu

2006-01-01

The surface emissivity effect on the thermodynamic parameters (e.g., the surface skin temperature, atmospheric temperature, and moisture) retrieved from satellite infrared (IR) spectral radiance is studied. Simulation analysis demonstrates that surface emissivity plays an important role in retrieval of surface skin temperature and terrestrial boundary layer (TBL) moisture. NAST-I ultraspectral data collected during the CLAMS field campaign are used to retrieve thermodynamic properties of the atmosphere and surface. The retrievals are then validated by coincident in-situ measurements, such as sea surface temperature, radiosonde temperature and moisture profiles. Retrieved surface emissivity is also validated by that computed from the observed radiance and calculated emissions based on the retrievals of surface temperature and atmospheric profiles. In addition, retrieved surface skin temperature and emissivity are validated together by radiance comparison between the observation and retrieval-based calculation in the window region where atmospheric contribution is minimized. Both simulation and validation results have lead to the conclusion that variable surface emissivity in the inversion process is needed to obtain accurate retrievals from satellite IR spectral radiance measurements. Retrieval examples are presented to reveal that surface emissivity plays a significant role in retrieving accurate surface skin temperature and TBL thermodynamic parameters.

Acidic deposition in the northeastern United States: Sources and inputs, ecosystem effects, and management strategies

USGS Publications Warehouse

Driscoll, C.T.; Lawrence, G.B.; Bulger, A.J.; Butler, T.J.; Cronan, C.S.; Eagar, C.; Lambert, K.F.; Likens, G.E.; Stoddard, J.L.; Weathers, K.C.

2001-01-01

North America and Europe are in the midst of a large-scale experiment. Sulfuric and nitric acids have acidified soils, lakes, and streams, thereby stressing or killing terrestrial and aquatic biota. It is therefore critical to measure and to understand the recovery of complex ecosystems in response to decreases in acidic deposition. Fortunately, the NADP, CASTNet, and AIRMoN-dry networks are in place to measure anticipated improvements in air quality and in atmospheric deposition. Unfortunately, networks to measure changes in water quality are sparse, and networks to monitor soil, vegetation, and fish responses are even more limited. There is an acute need to assess the response of these resources to decreases in acid loading. It would be particularly valuable to assess the recovery of aquatic biota - which respond directly to acid stress - to changes in surface water chemistry (Gunn and Mills 1998). We used long-term research from the HBEF and other sites across the northeastern United States to synthesize data on the effects of acidic deposition and to assess ecosystem responses to reductions in emissions. On the basis of existing data, it is clear that in the northeastern United States ??? reductions of SO2 emissions since 1970 have resulted in statistically significant decreases in SO42- in wet and bulk deposition and in surface waters ??? emissions of NOX and concentrations of NO3- in wet and bulk deposition and in surface waters have shown no increase or decrease since the 1980s ??? estimates of NH3 emissions are uncertain, although atmospheric deposition of NH4+ remains important for forest management and stream NO3- loss ??? acidic deposition has accelerated the leaching of base cations from soils, thus delaying the recovery of ANC in lakes and streams from decreased emissions of SO2 (at the HBEF the available soil Ca pool appears to have declined 50% over the past 50 years) ???sulfur and N from atmospheric deposition have accumulated in forest soils across the region, and the slow release of these stored elements from soil has delayed the recovery of lakes and streams after emissions have been reduced ??? acidic deposition has increased the concentration of toxic forms of Al in soil waters, lakes, and streams ??? acidic deposition has leached cellular Ca from red spruce foliage, which has made trees susceptible to freezing injury and led to more than 50% mortality of canopy trees in some areas of the Northeast ??? deficiencies of Ca2+ and Mg2+ have caused extensive mortality of sugar maple in Pennsylvania, and acidic deposition contributed to the depletion of these cations from soil ??? forty-one percent of lakes in the Adirondack Mountains and 15% of lakes in New England have exhibited chronic or episodic acidification or both; 83% of the affected lakes are acidic because of atmospheric deposition ??? the ANC of surface waters in New England has increased only modestly, and the Adirondack and Catskill regions have experienced no significant improvement, after decreases in atmospheric S deposition in recent decades ??? acidification of surface waters has resulted in a decrease in the survival, size, and density of fish and in the loss of fish and other aquatic biota from lakes and streams ??? emissions of air pollutants have important linkages to other large-scale environmental problems, including coastal eutrophication, mercury contamination, visibility impairment, climate change, and tropospheric ozone Moreover, we anticipate that recovery from acidic deposition will be a complex, two-phase process in which chemical recovery precedes biological recovery. The time for biological recovery is better defined for aquatic than for terrestrial ecosystems. For acid-affected aquatic ecosystems, we expect that stream populations of macroinvertebrates and lake populations of zooplankton will recover 3-10 years after favorable chemical conditions are reestablished; recovery of fish populations would follow. For terrestrial ecos

A scheme for computing surface layer turbulent fluxes from mean flow surface observations

NASA Technical Reports Server (NTRS)

Hoffert, M. I.; Storch, J.

1978-01-01

A physical model and computational scheme are developed for generating turbulent surface stress, sensible heat flux and humidity flux from mean velocity, temperature and humidity at some fixed height in the atmospheric surface layer, where conditions at this reference level are presumed known from observations or the evolving state of a numerical atmospheric circulation model. The method is based on coupling the Monin-Obukov surface layer similarity profiles which include buoyant stability effects on mean velocity, temperature and humidity to a force-restore formulation for the evolution of surface soil temperature to yield the local values of shear stress, heat flux and surface temperature. A self-contained formulation is presented including parameterizations for solar and infrared radiant fluxes at the surface. Additional parameters needed to implement the scheme are the thermal heat capacity of the soil per unit surface area, surface aerodynamic roughness, latitude, solar declination, surface albedo, surface emissivity and atmospheric transmissivity to solar radiation.

Using Ozone Lidar to Investigate Sources of High Ozone Concentrations in the Western United States

NASA Astrophysics Data System (ADS)

Senff, C. J.; Langford, A. O.; Alvarez, R. J.; Brewer, Wm. A.; Banta, R. M.; Marchbanks, R. D.; Sandberg, S. P.; Weickmann, A. M.; Holloway, J. S.; Williams, E. J.

2016-06-01

We have used NOAA's Tunable Optical Profiler for Aerosol and oZone (TOPAZ) ozone lidar to investigate the sources of high surface ozone concentrations in two different regions of the western United States (US): the Uintah Basin in northeast Utah and Clark County in southern Nevada, which includes the city of Las Vegas. The Uintah Basin is a booming oil and gas producing region that often suffers from very high wintertime ozone concentrations. Clark County experiences violations of the US ozone standard primarily in spring and early summer despite a lack of any major local pollution sources. TOPAZ lidar observations, in conjunction with surface in situ measurements and model results, provided strong evidence that the high wintertime ozone concentrations in the Uintah Basin are primarily driven by local emissions associated with oil and gas exploration, whereas the Clark County ozone exceedances are often caused by ozone-rich air that is transported from the lower stratosphere all the way down to the earth's surface.

Reduction and prediction of N2O emission from an Anoxic/Oxic wastewater treatment plant upon DO control and model simulation.

PubMed

Sun, Shichang; Bao, Zhiyuan; Li, Ruoyu; Sun, Dezhi; Geng, Haihong; Huang, Xiaofei; Lin, Junhao; Zhang, Peixin; Ma, Rui; Fang, Lin; Zhang, Xianghua; Zhao, Xuxin

2017-11-01

In order to make a better understanding of the characteristics of N 2 O emission in A/O wastewater treatment plant, full-scale and pilot-scale experiments were carried out and a back propagation artificial neural network model based on the experimental data was constructed to make a precise prediction of N 2 O emission. Results showed that, N 2 O flux from different units followed a descending order: aerated grit tank>oxic zone≫anoxic zone>final clarifier>primary clarifier, but 99.4% of the total emission of N 2 O (1.60% of N-load) was monitored from the oxic zone due to its big surface area. A proper DO control could reduce N 2 O emission down to 0.21% of N-load in A/O process, and a two-hidden-layers back propagation model with an optimized structure of 4:3:9:1 could achieve a good simulation of N 2 O emission, which provided a new method for the prediction of N 2 O emission during wastewater treatment. Copyright © 2017. Published by Elsevier Ltd.

40 CFR 63.9634 - How do I demonstrate continuous compliance with the emission limitations that apply to me?

Code of Federal Regulations, 2012 CFR

2012-07-01

... selected for initial performance testing and defined within a group of similar emission units in accordance... similar air pollution control device applied to each similar emission unit within a defined group using... emission units within group “k”; Pi = Daily average parametric monitoring parameter value corresponding to...

40 CFR 63.9634 - How do I demonstrate continuous compliance with the emission limitations that apply to me?

Code of Federal Regulations, 2014 CFR

2014-07-01

... selected for initial performance testing and defined within a group of similar emission units in accordance... similar air pollution control device applied to each similar emission unit within a defined group using... emission units within group “k”; Pi = Daily average parametric monitoring parameter value corresponding to...

Mountain Plains Learning Experience Guide: Automotive Repair. Course: Emission Systems.

ERIC Educational Resources Information Center

Schramm, C.; Osland, Walt

One of twelve individualized courses included in an automotive repair curriculum, this course covers the theory, testing, and servicing of automotive emission control systems. The course is comprised of one unit, Fundamentals of Emission Systems. The unit begins with a Unit Learning Experience Guide that gives directions for unit completion. The…

Opportunities for Saving Energy and Improving Air Quality in Urban Heat Islands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akbari, Hashem

2007-07-01

World energy use is the main contributor to atmospheric CO2. In 2002, about 7.0 giga metric tons of carbon (GtC) were emitted internationally by combustion of gas, liquid, and solid fuels (CDIAC, 2006), 2 to 5 times the amount contributed by deforestation (Brown et al., 1988). The share of atmospheric carbon emissions for the United States from fossil fuel combustion was 1.6 GtC. Increasing use of fossil fuel and deforestation together have raised atmospheric CO{sub 2} concentration some 25% over the last 150 years. According to global climate models and preliminary measurements, these changes in the composition of the atmospheremore » have already begun raising the Earth's average temperature. If current energy trends continue, these changes could drastically alter the Earth's temperature, with unknown but potentially catastrophic physical and political consequences. During the last three decades, increased energy awareness has led to conservation efforts and leveling of energy consumption in the industrialized countries. An important byproduct of this reduced energy use is the lowering of CO{sub 2} emissions. Of all electricity generated in the United States, about one-sixth is used to air-condition buildings. The air-conditioning use is about 400 tera-watt-hours (TWh), equivalent to about 80 million metric tons of carbon (MtC) emissions, and translating to about $40 billion (B) per year. Of this $40 B/year, about half is used in cities that have pronounced 'heat islands'. The contribution of the urban heat island to the air-conditioning demand has increased over the last 40 years and it is currently at about 10%. Metropolitan areas in the United States (e.g., Los Angeles, Phoenix, Houston, Atlanta, and New York City) have typically pronounced heat islands that warrant special attention by anyone concerned with broad-scale energy efficiency (HIG, 2006). The ambient air is primarily heated through three processes: direct absorption of solar radiation, convection of heat from hot surfaces, and man-made heat (exhaust from cars, buildings, etc.). Air is fairly transparent to light--the direct absorption of solar radiation in atmospheric air only raises the air temperature by a small amount. Typically about 90% of solar radiation reaches the Earth's surface and then is either absorbed or reflected. The absorbed radiation on the surface increases the surface temperature. And in turn the hot surfaces heat the air. This convective heating is responsible for the majority of the diurnal temperature range. The contribution of man-made heat (e.g., air conditioning, cars) is very small, compared to the heating of air by hot surfaces, except for the downtown high-rise areas.« less

Natural and Anthropogenic Aerosol Trends from Satellite and Surface Observations and Model Simulations over the North Atlantic Ocean from 2002 to 2012

NASA Technical Reports Server (NTRS)

Jongeward, Andrew R.; Li, Zhanqing; He, Hao; Xiong, Xiaoxiong

2016-01-01

Aerosols contribute to Earths radiative budget both directly and indirectly, and large uncertainties remain in quantifying aerosol effects on climate. Variability in aerosol distribution and properties, as might result from changing emissions and transport processes, must be characterized. In this study, variations in aerosol loading across the eastern seaboard of theUnited States and theNorthAtlanticOcean during 2002 to 2012 are analyzed to examine the impacts of anthropogenic emission control measures using monthly mean data from MODIS, AERONET, and IMPROVE observations and Goddard Chemistry Aerosol Radiation and Transport (GOCART) model simulation.MODIS observes a statistically significant negative trend in aerosol optical depth (AOD) over the midlatitudes (-0.030 decade(sup-1)). Correlation analyses with surface AOD from AERONET sites in the upwind region combined with trend analysis from GOCART component AOD confirm that the observed decrease in the midlatitudes is chiefly associated with anthropogenic aerosols that exhibit significant negative trends from the eastern U.S. coast extending over the western North Atlantic. Additional analysis of IMPROVE surface PM(sub 2.5) observations demonstrates statistically significant negative trends in the anthropogenic components with decreasing mass concentrations over the eastern United States. Finally, a seasonal analysis of observational datasets is performed. The negative trend seen by MODIS is strongest during spring (MAM) and summer (JJA) months. This is supported by AERONET seasonal trends and is identified from IMPROVE seasonal trends as resulting from ammonium sulfate decreases during these seasons.

Physical Retrieval of Surface Emissivity Spectrum from Hyperspectral Infrared Radiances

NASA Technical Reports Server (NTRS)

Li, Jun; Weisz, Elisabeth; Zhou, Daniel K.

2007-01-01

Retrieval of temperature, moisture profiles and surface skin temperature from hyperspectral infrared (IR) radiances requires spectral information about the surface emissivity. Using constant or inaccurate surface emissivities typically results in large retrieval errors, particularly over semi-arid or arid areas where the variation in emissivity spectrum is large both spectrally and spatially. In this study, a physically based algorithm has been developed to retrieve a hyperspectral IR emissivity spectrum simultaneously with the temperature and moisture profiles, as well as the surface skin temperature. To make the solution stable and efficient, the hyperspectral emissivity spectrum is represented by eigenvectors, derived from the laboratory measured hyperspectral emissivity database, in the retrieval process. Experience with AIRS (Atmospheric InfraRed Sounder) radiances shows that a simultaneous retrieval of the emissivity spectrum and the sounding improves the surface skin temperature as well as temperature and moisture profiles, particularly in the near surface layer.

“Feathered” fractal surfaces to minimize secondary electron emission for a wide range of incident angles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swanson, Charles; Kaganovich, Igor D.

Complex structures on a material surface can significantly reduce the total secondary electron emission from that surface. The reduction occurs due to the capture of low-energy, true secondary electrons emitted at one point of the structure and intersecting another. We performed Monte Carlo calculations to demonstrate that fractal surfaces can reduce net secondary electron emission produced by the surface as compared to the flat surface. Specifically, we describe one surface, a “feathered” surface, which reduces the secondary electron emission yield more effectively than other previously considered configurations. Specifically, feathers grown onto a surface suppress secondary electron emission from shallow anglesmore » of incidence more effectively than velvet. Here, we find that, for the surface simulated, secondary electron emission yield remains below 20% of its un-suppressed value, even for shallow incident angles, where the velvet-only surface gives reduction factor of only 50%.« less

“Feathered” fractal surfaces to minimize secondary electron emission for a wide range of incident angles

DOE PAGES

Swanson, Charles; Kaganovich, Igor D.

2017-07-24

Complex structures on a material surface can significantly reduce the total secondary electron emission from that surface. The reduction occurs due to the capture of low-energy, true secondary electrons emitted at one point of the structure and intersecting another. We performed Monte Carlo calculations to demonstrate that fractal surfaces can reduce net secondary electron emission produced by the surface as compared to the flat surface. Specifically, we describe one surface, a “feathered” surface, which reduces the secondary electron emission yield more effectively than other previously considered configurations. Specifically, feathers grown onto a surface suppress secondary electron emission from shallow anglesmore » of incidence more effectively than velvet. Here, we find that, for the surface simulated, secondary electron emission yield remains below 20% of its un-suppressed value, even for shallow incident angles, where the velvet-only surface gives reduction factor of only 50%.« less

"Feathered" fractal surfaces to minimize secondary electron emission for a wide range of incident angles

NASA Astrophysics Data System (ADS)

Swanson, Charles; Kaganovich, Igor D.

2017-07-01

Complex structures on a material surface can significantly reduce the total secondary electron emission from that surface. The reduction occurs due to the capture of low-energy, true secondary electrons emitted at one point of the structure and intersecting another. We performed Monte Carlo calculations to demonstrate that fractal surfaces can reduce net secondary electron emission produced by the surface as compared to the flat surface. Specifically, we describe one surface, a "feathered" surface, which reduces the secondary electron emission yield more effectively than other previously considered configurations. Specifically, feathers grown onto a surface suppress secondary electron emission from shallow angles of incidence more effectively than velvet. We find that, for the surface simulated, secondary electron emission yield remains below 20% of its un-suppressed value, even for shallow incident angles, where the velvet-only surface gives reduction factor of only 50%.

Cure width potential for MOD resin composite molar restorations.

PubMed

Palin, William M; Senyilmaz, Dilek P; Marquis, Peter M; Shortall, Adrian C

2008-08-01

To investigate the capability of modern light-curing units exhibiting differences in emission spectra and light source exit window dimensions, for "one-shot" full-width curing of extensive (molar MOD) resin composite restorations. Specimens of Tetric (TT), Tetric Ceram HB (TC), Tetric Evoceram (TE) and Tetric Ceram Bleach (TB) resin composites containing varying ratios of Lucirin (TPO) and/or camphorquinone (CQ) photoinitiators were packed into a bar-shaped mould (12 mm length x 2 mm width x 2 mm thickness). Each product was irradiated using a halogen (Optilux 401; QTH), a conventional LED (LEDemetron; LED) and two so-called "third generation" oval-footprint LED light-curing units (LCUs) of the same model. The latter featured bimodal emission spectra (blue and ultraviolet diodes) with either high (unmodified output) and approximately 50% (modified output) blue light intensity (UltraLume-5; ULs, ULm, respectively). Vickers hardness number was obtained across the lateral extent of the bar at 1mm increments from the centre point on both upper and lower surfaces of the specimens. Significant linear relationships (R(2)=0.71-0.98) for each distance from the central position of all LCUs were identified between measured light intensity and corresponding upper and lower surface hardness values for each product (P<0.05). No significant differences (P>0.05) were recorded in total upper surface hardness of TC or TE cured with LED (68.7+/-3.2 and 70.5+/-2.5) or ULm (56.8+/-2.0 and 57.7+/-2.0). However, upper surface hardness of TT (CQ only) cured with ULm was significantly decreased (P<0.05) compared with other LCUs. When the ratio of hardness at the edge to central positions of the bar-shaped specimens for either surface was calculated, no significant difference (P>0.05) was identified for TB (containing TPO and decreased CQ) cured with either ULs or ULm (P>0.05) and was significantly increased (P<0.05) when cured with ULs compared with LED and QTH. Variability in light intensity across the curing-tip face, spectral output of dental light-curing units and differences in product photoinitiator chemistry all influence curing efficiency significantly across the width of extensive resin composite geometries.

New and Revised Emissions Factors for Flares and New Emissions Factors for Certain Refinery Process Units and Determination for No Changes to VOC Emissions Factors for Tanks and Wastewater Treatment Systems

EPA Pesticide Factsheets

New and Revised Emission Factors for Flares and New Emission Factors for Certain Refinery Process Units and Determination for No Changes to VOC Emission Factors for Tanks and Wastewater Treatment Systems

Projections of Ocean Acidification Under the U.N. Framework Convention of Climate Change Using a Reduced-Form Climate Carbon-Cycle Model

NASA Astrophysics Data System (ADS)

Hartin, C.

2016-02-01

Ocean chemistry is quickly changing in response to continued anthropogenic emissions of carbon to the atmosphere. Mean surface ocean pH has already decreased by 0.1 units relative to the preindustrial era. We use an open-source, simple climate and carbon cycle model ("Hector") to investigate future changes in ocean acidification (pH and calcium carbonate saturations) under the climate agreement from the United Nations Convention on Climate Change Conference (UNFCCC) of Parties in Paris 2015 (COP 21). Hector is a reduced-form, very fast-executing model that can emulate the global mean climate of the CMIP5 models, as well as the inorganic carbon cycle in the upper ocean, allowing us to investigate future changes in ocean acidification. We ran Hector under three different emissions trajectories, using a sensitivity analysis approach to quantify model uncertainty and capture a range of possible ocean acidification changes. The first trajectory is a business-as-usual scenario comparable to a Representative Concentration Pathway (RCP) 8.5, the second a scenario with the COP 21 commitments enacted, and the third an idealized scenario keeping global temperature change to 2°C, comparable to a RCP 2.6. Preliminary results suggest that under the COP 21 agreements ocean pH at 2100 will decrease by 0.2 units and surface saturations of aragonite (calcite) will decrease by 0.9 (1.4) units relative to 1850. Under the COP 21 agreement the world's oceans will be committed to a degree of ocean acidification, however, these changes may be within the range of natural variability evident in some paleo records.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bohn, T. J.; Melton, J. R.; Ito, A.

Wetlands are the world's largest natural source of methane, a powerful greenhouse gas. The strong sensitivity of methane emissions to environmental factors such as soil temperature and moisture has led to concerns about potential positive feedbacks to climate change. This risk is particularly relevant at high latitudes, which have experienced pronounced warming and where thawing permafrost could potentially liberate large amounts of labile carbon over the next 100 years. However, global models disagree as to the magnitude and spatial distribution of emissions, due to uncertainties in wetland area and emissions per unit area and a scarcity of in situ observations.more » Recent intensive field campaigns across the West Siberian Lowland (WSL) make this an ideal region over which to assess the performance of large-scale process-based wetland models in a high-latitude environment. Here we present the results of a follow-up to the Wetland and Wetland CH 4 Intercomparison of Models Project (WETCHIMP), focused on the West Siberian Lowland (WETCHIMP-WSL). We assessed 21 models and 5 inversions over this domain in terms of total CH 4 emissions, simulated wetland areas, and CH 4 fluxes per unit wetland area and compared these results to an intensive in situ CH 4 flux data set, several wetland maps, and two satellite surface water products. We found that (a) despite the large scatter of individual estimates, 12-year mean estimates of annual total emissions over the WSL from forward models (5.34 ± 0.54 Tg CH 4 yr⁻¹), inversions (6.06 ± 1.22 Tg CH 4 yr⁻¹), and in situ observations (3.91 ± 1.29 Tg CH 4 yr⁻¹) largely agreed; (b) forward models using surface water products alone to estimate wetland areas suffered from severe biases in CH 4 emissions; (c) the interannual time series of models that lacked either soil thermal physics appropriate to the high latitudes or realistic emissions from unsaturated peatlands tended to be dominated by a single environmental driver (inundation or air temperature), unlike those of inversions and more sophisticated forward models; (d) differences in biogeochemical schemes across models had relatively smaller influence over performance; and (e) multiyear or multidecade observational records are crucial for evaluating models' responses to long-term climate change.« less

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units E Appendix E to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION...

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units E Appendix E to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION...

Thermal insulated glazing unit

DOEpatents

Selkowitz, Stephen E.; Arasteh, Dariush K.; Hartmann, John L.

1991-01-01

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

Towards graphane field emitters

PubMed Central

Ding, Shuyi; Li, Chi; Zhou, Yanhuai; Collins, Clare M.; Kang, Moon H.; Parmee, Richard J.; Zhang, Xiaobing; Milne, William I.; Wang, Baoping

2015-01-01

We report on the improved field emission performance of graphene foam (GF) following transient exposure to hydrogen plasma. The enhanced field emission mechanism associated with hydrogenation has been investigated using Fourier transform infrared spectroscopy, plasma spectrophotometry, Raman spectroscopy, and scanning electron microscopy. The observed enhanced electron emissionhas been attributed to an increase in the areal density of lattice defects and the formation of a partially hydrogenated, graphane-like material. The treated GF emitter demonstrated a much reduced macroscopic turn-on field (2.5 V μm–1), with an increased maximum current density from 0.21 mA cm–2 (pristine) to 8.27 mA cm–2 (treated). The treated GFs vertically orientated protrusions, after plasma etching, effectively increased the local electric field resulting in a 2.2-fold reduction in the turn-on electric field. The observed enhancement is further attributed to hydrogenation and the subsequent formation of a partially hydrogenated structured 2D material, which advantageously shifts the emitter work function. Alongside augmentation of the nominal crystallite size of the graphitic superstructure, surface bound species are believed to play a key role in the enhanced emission. The hydrogen plasma treatment was also noted to increase the emission spatial uniformity, with an approximate four times reduction in the per unit area variation in emission current density. Our findings suggest that plasma treatments, and particularly hydrogen and hydrogen-containing precursors, may provide an efficient, simple, and low cost means of realizing enhanced nanocarbon-based field emission devices via the engineered degradation of the nascent lattice, and adjustment of the surface work function. PMID:28066543

40 CFR 75.19 - Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Optional SO 2, NO X, and CO 2... Provisions § 75.19 Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units. (a...) Determination of SO 2, NO X, and CO 2 emission rates. (i) If the unit combusts only natural gas and/or fuel oil...

40 CFR 75.19 - Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional SO 2, NO X, and CO 2... Provisions § 75.19 Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units. (a...) Determination of SO 2, NO X, and CO 2 emission rates. (i) If the unit combusts only natural gas and/or fuel oil...

40 CFR 63.1568 - What are my requirements for HAP emissions from sulfur recovery units?

Code of Federal Regulations, 2012 CFR

2012-07-01

... emissions from sulfur recovery units? 63.1568 Section 63.1568 Protection of Environment ENVIRONMENTAL... Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Catalytic Cracking Units, Catalytic Reforming Units, Sulfur Recovery Units, and Bypass Lines § 63.1568 What...

Radiative effects due to North American anthropogenic and lightning emissions: Global and regional modeling

NASA Astrophysics Data System (ADS)

Martini, Matus Novak

We analyze the contribution of North American (NA) lightning and anthropogenic emissions to summertime ozone concentrations, radiative forcing, and exports from North America using the global University of Maryland chemistry transport model (UMD-CTM) and the regional scale Weather Research and Forecasting model with chemistry (WRF-Chem). Lightning NO contributes by 15--20 ppbv to upper tropospheric ozone concentrations over the United States with the effects of NA lightning on ozone seen as far east as North Africa and Europe. Using the UMD-CTM, we compare changes in surface and column ozone amounts due to the NOx State Implementation Plan (SIP) Call with the natural variability in ozone due to changes in meteorology and lightning. Comparing early summer 2004 with 2002, surface ozone decreased by up to 5 ppbv due to the NO x SIP Call while changes in meteorology and lightning resulted in a 0.3--1.4 ppbv increase in surface ozone. Ozone column variability was driven primarily by changes in lightning NO emissions, especially over the North Atlantic. As part of our WRF-Chem analysis, we modify the radiation schemes to use model-calculated ozone (interactive ozone) instead of climatological ozone profiles and conduct multiple 4-day simulations of July 2007. We found that interactive ozone increased the outgoing longwave radiation (OLR) by 3 W m-2 decreasing the bias with respect to remotely sensed OLR. The improvement is due to a high bias in the climatological ozone profiles. The interactive ozone had a small impact on mean upper troposphere temperature (-0.15°C). The UMD-CTM simulations indicate that NA anthropogenic emissions are responsible for more ozone export but less ozone radiative forcing than lightning NO emissions. Over the North Atlantic, NA anthropogenic emissions contributed 0.15--0.30 W m-2 to the net downward radiative flux at the tropopause while NA lightning contributed 0.30--0.50 W m-2. The ozone export from anthropogenic emissions was almost twice as large as that from lightning emissions. The WRF-Chem simulations show that the export of reactive nitrogen was 23%--28% of the boundary layer emissions and 26%--38% of the total emissions including lightning NO.

High-resolution inventory of technologies, activities, and emissions of coal-fired power plants in China from 1990 to 2010

NASA Astrophysics Data System (ADS)

Liu, F.; Zhang, Q.; Tong, D.; Zheng, B.; Li, M.; Huo, H.; He, K. B.

2015-07-01

This paper, which focuses on emissions from China's coal-fired power plants during 1990-2010, is the second in a series of papers that aims to develop high-resolution emission inventory for China. This is the first time that emissions from China's coal-fired power plants were estimated at unit level for a 20 year period. This inventory is constructed from a unit-based database compiled in this study, named the China coal-fired Power plant Emissions Database (CPED), which includes detailed information on the technologies, activity data, operation situation, emission factors, and locations of individual units and supplements with aggregated data where unit-based information is not available. Between 1990 and 2010, compared to a 479 % growth in coal consumption, emissions from China's coal-fired power plants increased by 56, 335 and 442 % for SO2, NOx and CO2, respectively, and decreased by 23 % for PM2.5. Driven by the accelerated economy growth, large power plants were constructed throughout the country after 2000, resulting in dramatic growth in emissions. Growth trend of emissions has been effective curbed since 2005 due to strengthened emission control measures including the installation of flue-gas desulfurization (FGD) systems and the optimization of the generation fleet mix by promoting large units and decommissioning small ones. Compared to previous emission inventories, CPED significantly improved the spatial resolution and temporal profile of power plant emission inventory in China by extensive use of underlying data at unit level. The new inventory developed in this study will enable a close examination for temporal and spatial variations of power plant emissions in China and will help to improve the performances of chemical transport models by providing more accurate emission data.

40 CFR 60.31d - Emissions guidelines.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emissions guidelines. 60.31d Section 60...) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Emissions Guidelines and Compliance Times for Sulfuric Acid Production Units § 60.31d Emissions guidelines. Sulfuric acid production units. The emission...

Land Surface Microwave Emissivity Dynamics: Observations, Analysis and Modeling

NASA Technical Reports Server (NTRS)

Tian, Yudong; Peters-Lidard, Christa D.; Harrison, Kenneth W.; Kumar, Sujay; Ringerud, Sarah

2014-01-01

Land surface microwave emissivity affects remote sensing of both the atmosphere and the land surface. The dynamical behavior of microwave emissivity over a very diverse sample of land surface types is studied. With seven years of satellite measurements from AMSR-E, we identified various dynamical regimes of the land surface emission. In addition, we used two radiative transfer models (RTMs), the Community Radiative Transfer Model (CRTM) and the Community Microwave Emission Modeling Platform (CMEM), to simulate land surface emissivity dynamics. With both CRTM and CMEM coupled to NASA's Land Information System, global-scale land surface microwave emissivities were simulated for five years, and evaluated against AMSR-E observations. It is found that both models have successes and failures over various types of land surfaces. Among them, the desert shows the most consistent underestimates (by approx. 70-80%), due to limitations of the physical models used, and requires a revision in both systems. Other snow-free surface types exhibit various degrees of success and it is expected that parameter tuning can improve their performances.

Improved Satellite-based Photosysnthetically Active Radiation (PAR) for Air Quality Studies

NASA Astrophysics Data System (ADS)

Pour Biazar, A.; McNider, R. T.; Cohan, D. S.; White, A.; Zhang, R.; Dornblaser, B.; Doty, K.; Wu, Y.; Estes, M. J.

2015-12-01

One of the challenges in understanding the air quality over forested regions has been the uncertainties in estimating the biogenic hydrocarbon emissions. Biogenic volatile organic compounds, BVOCs, play a critical role in atmospheric chemistry, particularly in ozone and particulate matter (PM) formation. In southeastern United States, BVOCs (mostly as isoprene) are the dominant summertime source of reactive hydrocarbon. Despite significant efforts in improving BVOC estimates, the errors in emission inventories remain a concern. Since BVOC emissions are particularly sensitive to the available photosynthetically active radiation (PAR), model errors in PAR result in large errors in emission estimates. Thus, utilization of satellite observations to estimate PAR can help in reducing emission uncertainties. Satellite-based PAR estimates rely on the technique used to derive insolation from satellite visible brightness measurements. In this study we evaluate several insolation products against surface pyranometer observations and offer a bias correction to generate a more accurate PAR product. The improved PAR product is then used in biogenic emission estimates. The improved biogenic emission estimates are compared to the emission inventories over Texas and used in air quality simulation over the period of August-September 2013 (NASA's Discover-AQ field campaign). A series of sensitivity simulations will be performed and evaluated against Discover-AQ observations to test the impact of satellite-derived PAR on air quality simulations.

Hydrocarbons Emissions Due to Wellbore and other Subsurface Leakage in the Uintah Basin, Utah

NASA Astrophysics Data System (ADS)

Watkins, C.; Lyman, S. N.

2015-12-01

The explosive growth of oil and gas production in the United States has focused public and regulatory attention on environmental impacts of hydrocarbon extraction, including air quality and climate impacts. One potentially important emissions source is subsurface leakage of natural gas. Better understanding of wellbore and other subsurface leaks are important in providing ways to decrease pollution while increasing the efficiency of oil and gas production. Soil gas measurements carried out by USGS over the last several years in Utah's oil and gas fields have shown that, while concentrations of methane in soils near wells are typically low, soil gas near some wells can contain more than 50% methane. In the summers of 2013-2015 we carried out campaigns to measure the emission rate of methane and other hydrocarbons from soils near wells in the Uintah Basin, Utah. We also measured emissions at several locations on individual well pads and determined that concentrations of hydrocarbons tend to decrease with distance from the well head. Soil emissions were also measured at non-well sites in the same area to determine background emission rates. Emissions from exposed coal, oil shale, gilsonite, and fault zone surfaces were also measured. Relationships of emissions with soil gas concentrations, meteorological conditions, and soil properties were also investigated.

Archiving, processing, and disseminating ASTER products at the USGS EROS Data Center

USGS Publications Warehouse

Jones, B.; Tolk, B.; ,

2002-01-01

The U.S. Geological Survey EROS Data Center archives, processes, and disseminates Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data products. The ASTER instrument is one of five sensors onboard the Earth Observing System's Terra satellite launched December 18, 1999. ASTER collects broad spectral coverage with high spatial resolution at near infrared, shortwave infrared, and thermal infrared wavelengths with ground resolutions of 15, 30, and 90 meters, respectively. The ASTER data are used in many ways to understand local and regional earth-surface processes. Applications include land-surface climatology, volcanology, hazards monitoring, geology, agronomy, land cover change, and hydrology. The ASTER data are available for purchase from the ASTER Ground Data System in Japan and from the Land Processes Distributed Active Archive Center in the United States, which receives level 1A and level 1B data from Japan on a routine basis. These products are archived and made available to the public within 48 hours of receipt. The level 1A and level 1B data are used to generate higher level products that include routine and on-demand decorrelation stretch, brightness temperature at the sensor, emissivity, surface reflectance, surface kinetic temperature, surface radiance, polar surface and cloud classification, and digital elevation models. This paper describes the processes and procedures used to archive, process, and disseminate standard and on-demand higher level ASTER products at the Land Processes Distributed Active Archive Center.

40 CFR 76.10 - Alternative emission limitations.

Code of Federal Regulations, 2013 CFR

2013-07-01

...; and (ii) The installed NOX emission control system has been designed to meet the applicable emission... that the unit and NOX emission control system were operated in accordance with the bid and design specifications on which the design of the NOX emission control system was based; and (C) Unit operating data as...

40 CFR 76.10 - Alternative emission limitations.

Code of Federal Regulations, 2010 CFR

2010-07-01

...; and (ii) The installed NOX emission control system has been designed to meet the applicable emission... that the unit and NOX emission control system were operated in accordance with the bid and design specifications on which the design of the NOX emission control system was based; and (C) Unit operating data as...

Radio detection of extensive air showers at the Pierre Auger Observatory

NASA Astrophysics Data System (ADS)

Berat, C.

2013-08-01

The Pierre Auger Observatory explores the potential of radio-detection techniques to measure extensive air showers (EAS) induced by ultra-high energy cosmic rays. To study in detail the mechanisms responsible for radio emission in the MHz range, the Auger Engineering Radio Array has been installed at the Observatory. Presently consisting of 24 radio-detection stations, this number will grow to 150 units covering an area of almost 20 km2. Novel detection techniques based on the GHz emission from the EAS are currently being studied. AMBER (Air-shower Microwave Bremsstrahlung Experimental Radiometer) and MIDAS (Microwave Detection of Air Showers) are prototypes for a large imaging dish antenna. In EASIER (Extensive Air Shower Identification using Electron Radiometer), the microwave emission is detected by antenna horns located on each surface detector. MIDAS is a self-triggering system while AMBER and EASIER use the trigger from the Auger detectors to record the emission. The status of these radio-detection R&D efforts at the Pierre Auger Observatory will be reported.

Impact of Future Emissions and Climate Change on Surface Ozone over China

NASA Astrophysics Data System (ADS)

Ma, C. T.; Westervelt, D. M.; Fiore, A. M.; Rieder, H. E.; Kinney, P.; Wang, S.; Correa, G. J. P.

2017-12-01

China's immense ambient air pollution problem and world-leading greenhouse gas emissions place it at the forefront of global efforts to address these related environmental concerns. Here, we analyze the impact of ECLIPSE (Evaluating the Climate and Air Quality Impacts of Short-Lived Pollutants) future emissions scenarios representative of current legislation (CLE) and maximum technically feasible emissions reductions (MFR) on surface ozone (O3) concentrations over China in the 2030s and 2050s, in the context of a changing climate. We use a suite of simulations performed with the NOAA Geophysical Fluid Dynamics Laboratory's AM3 global chemistry-climate model. To estimate the impact of climate change in isolation on Chinese air quality, we hold emissions of air pollutants including O3 precursors fixed at 2015 levels but allow climate (global sea surface temperatures and sea ice cover) to change according to decadal averages for the years 2026-2035 and 2046-2055 from a three-member ensemble of GFDL-CM3 simulations under the RCP8.5 high warming scenario. Evaluation of the present-day simulation (2015 CLE) with observations from 1497 chiefly urban air quality monitoring stations shows that simulated surface O3 is positively biased by 26 ppb on average over the domain of China. Previous studies, however, have shown that the modeled ozone response to changes in NOx emissions over the Eastern United States mirrors the magnitude and structure of observed changes in maximum daily average 8-hour (MDA8) O3 distributions. Therefore, we use the model's simulated changes for the 2030s and 2050s to project changes in policy-relevant MDA8 O3 concentrations. We find an overall increase in MDA8 O3 for CLE scenarios in which emissions of NOx precursors are projected to increase, and under MFR scenarios, an overall decrease, with the highest changes occurring in summertime for both 2030 and 2050 MFR. Under climate change alone, the model simulates a mean summertime decrease of 1.3 ppb and wintertime increase of 3.3 ppb by 2050. Adjustment of the observed site-level MDA8 O3 distribution to reflect regionally interpolated projected changes from AM3 allows us to examine changes in the number of days in exceedance of MDA8 O3 Level I (50 ppb) and Level II (80 ppb) Chinese national ambient air quality standards.

Use of Air Quality Observations by the National Air Quality Forecast Capability

NASA Astrophysics Data System (ADS)

Stajner, I.; McQueen, J.; Lee, P.; Stein, A. F.; Kondragunta, S.; Ruminski, M.; Tong, D.; Pan, L.; Huang, J. P.; Shafran, P.; Huang, H. C.; Dickerson, P.; Upadhayay, S.

2015-12-01

The National Air Quality Forecast Capability (NAQFC) operational predictions of ozone and wildfire smoke for the United States (U.S.) and predictions of airborne dust for continental U.S. are available at http://airquality.weather.gov/. NOAA National Centers for Environmental Prediction (NCEP) operational North American Mesoscale (NAM) weather predictions are combined with the Community Multiscale Air Quality (CMAQ) model to produce the ozone predictions and test fine particulate matter (PM2.5) predictions. The Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model provides smoke and dust predictions. Air quality observations constrain emissions used by NAQFC predictions. NAQFC NOx emissions from mobile sources were updated using National Emissions Inventory (NEI) projections for year 2012. These updates were evaluated over large U.S. cities by comparing observed changes in OMI NO2 observations and NOx measured by surface monitors. The rate of decrease in NOx emission projections from year 2005 to year 2012 is in good agreement with the observed changes over the same period. Smoke emissions rely on the fire locations detected from satellite observations obtained from NESDIS Hazard Mapping System (HMS). Dust emissions rely on a climatology of areas with a potential for dust emissions based on MODIS Deep Blue aerosol retrievals. Verification of NAQFC predictions uses AIRNow compilation of surface measurements for ozone and PM2.5. Retrievals of smoke from GOES satellites are used for verification of smoke predictions. Retrievals of dust from MODIS are used for verification of dust predictions. In summary, observations are the basis for the emissions inputs for NAQFC, they are critical for evaluation of performance of NAQFC predictions, and furthermore they are used in real-time testing of bias correction of PM2.5 predictions, as we continue to work on improving modeling and emissions important for representation of PM2.5.

State Budgets, Unit Allocations, and Unit Emissions Rates

EPA Pesticide Factsheets

This Technical Support Document (TSD) provides information that supports EPA’s determination of state emissions budgets, unit-level allocations, direct control rate limits, and new unit set-asides for the Transport Rule proposal.

Improving land surface emissivty parameter for land surface models using portable FTIR and remote sensing observation in Taklimakan Desert

NASA Astrophysics Data System (ADS)

Liu, Yongqiang; Mamtimin, Ali; He, Qing

2014-05-01

Because land surface emissivity (ɛ) has not been reliably measured, global climate model (GCM) land surface schemes conventionally set this parameter as simply assumption, for example, 1 as in the National Oceanic and Atmospheric Administration (NOAA) National Centers for Environmental Prediction (NCEP) model, 0.96 for soil and wetland in the Global and Regional Assimilation and Prediction System (GRAPES) Common Land Model (CoLM). This is the so-called emissivity assumption. Accurate broadband emissivity data are needed as model inputs to better simulate the land surface climate. It is demonstrated in this paper that the assumption of the emissivity induces errors in modeling the surface energy budget over Taklimakan Desert where ɛ is far smaller than original value. One feasible solution to this problem is to apply the accurate broadband emissivity into land surface models. The Moderate Resolution Imaging Spectroradiometer (MODIS) instrument has routinely measured spectral emissivities in six thermal infrared bands. The empirical regression equations have been developed in this study to convert these spectral emissivities to broadband emissivity required by land surface models. In order to calibrate the regression equations, using a portable Fourier Transform infrared (FTIR) spectrometer instrument, crossing Taklimakan Desert along with highway from north to south, to measure the accurate broadband emissivity. The observed emissivity data show broadband ɛ around 0.89-0.92. To examine the impact of improved ɛ to radiative energy redistribution, simulation studies were conducted using offline CoLM. The results illustrate that large impacts of surface ɛ occur over desert, with changes up in surface skin temperature, as well as evident changes in sensible heat fluxes. Keywords: Taklimakan Desert, surface broadband emissivity, Fourier Transform infrared spectrometer, MODIS, CoLM

Effect of organic materials used in the synthesis on the emission from CdSe quantum dots

NASA Astrophysics Data System (ADS)

Lee, Jae-Won; Yang, Ho-Soon; Hong, K. S.; Kim, S. M.

2013-12-01

Quantum-dot nanocrystals have particular optical properties due to the quantum confinement effect and the surface effect. This study focuses on the effect of surface conditions on the emission from quantum dots. The quantum dots prepared with 1-hexadecylamine (HDA) in the synthesis show strong emission while the quantum dots prepared without HDA show weak emission, as well as emission from surface energy traps. The comparison of the X-ray patterns of these two sets of quantum dots reveals that HDA forms a layer on the surface of quantum dot during the synthesis. This surface passivation with a layer of HDA reduces surface energy traps, therefore the emission from surface trap levels is suppressed in the quantum dots synthesized with HDA.

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

40 CFR 63.1282 - Test methods, compliance procedures, and compliance demonstrations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... compliance demonstrations. (a) Determination of glycol dehydration unit flowrate, benzene emissions, or BTEX... dehydration unit natural gas flowrate, benzene emissions, or BTEX emissions. (1) The determination of actual flowrate of natural gas to a glycol dehydration unit shall be made using the procedures of either paragraph...

40 CFR 63.1282 - Test methods, compliance procedures, and compliance demonstrations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... compliance demonstrations. (a) Determination of glycol dehydration unit flowrate, benzene emissions, or BTEX... dehydration unit natural gas flowrate, benzene emissions, or BTEX emissions. (1) The determination of actual flowrate of natural gas to a glycol dehydration unit shall be made using the procedures of either paragraph...

40 CFR 63.1016 - Alternative means of emission limitation: Enclosed-vented process units.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Alternative means of emission limitation: Enclosed-vented process units. 63.1016 Section 63.1016 Protection of Environment ENVIRONMENTAL... § 63.1016 Alternative means of emission limitation: Enclosed-vented process units. (a) Use of closed...

40 CFR 63.1016 - Alternative means of emission limitation: Enclosed-vented process units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 10 2011-07-01 2011-07-01 false Alternative means of emission limitation: Enclosed-vented process units. 63.1016 Section 63.1016 Protection of Environment ENVIRONMENTAL... § 63.1016 Alternative means of emission limitation: Enclosed-vented process units. (a) Use of closed...

40 CFR 96.74 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... unit subject to an Acid Rain Emission limitation who signed and certified any submission that is made.... (b) Monitoring plans. (1) The owner or operator of a unit subject to an Acid Rain emissions... operator of a unit that is not subject to an Acid Rain emissions limitation shall comply with requirements...

40 CFR 96.74 - Recordkeeping and reporting.

Code of Federal Regulations, 2012 CFR

2012-07-01

... unit subject to an Acid Rain Emission limitation who signed and certified any submission that is made.... (b) Monitoring plans. (1) The owner or operator of a unit subject to an Acid Rain emissions... operator of a unit that is not subject to an Acid Rain emissions limitation shall comply with requirements...

40 CFR 96.375 - Petitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is not subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions...

40 CFR 96.375 - Petitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is not subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions...

40 CFR 96.74 - Recordkeeping and reporting.

Code of Federal Regulations, 2013 CFR

2013-07-01

... unit subject to an Acid Rain Emission limitation who signed and certified any submission that is made.... (b) Monitoring plans. (1) The owner or operator of a unit subject to an Acid Rain emissions... operator of a unit that is not subject to an Acid Rain emissions limitation shall comply with requirements...

40 CFR 96.74 - Recordkeeping and reporting.

Code of Federal Regulations, 2011 CFR

2011-07-01

... unit subject to an Acid Rain Emission limitation who signed and certified any submission that is made.... (b) Monitoring plans. (1) The owner or operator of a unit subject to an Acid Rain emissions... operator of a unit that is not subject to an Acid Rain emissions limitation shall comply with requirements...

40 CFR 96.375 - Petitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is not subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions...

40 CFR 96.74 - Recordkeeping and reporting.

Code of Federal Regulations, 2014 CFR

2014-07-01

... unit subject to an Acid Rain Emission limitation who signed and certified any submission that is made.... (b) Monitoring plans. (1) The owner or operator of a unit subject to an Acid Rain emissions... operator of a unit that is not subject to an Acid Rain emissions limitation shall comply with requirements...

40 CFR 96.375 - Petitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is not subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions...

40 CFR 96.375 - Petitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is not subject to an Acid Rain emissions... designated representative of a CAIR NOX Ozone Season unit that is subject to an Acid Rain emissions...

The effect of atmospheric sulfate reductions on diffuse radiation and photosynthesis in the eastern United States

NASA Astrophysics Data System (ADS)

Keppel-Aleks, G.; Washenfelder, R. A.

2016-12-01

Aerosol optical depth (AOD) has been shown to influence ecosystem carbon uptake by increasing the fraction of diffuse light, which increases photosynthesis over a greater fraction of the vegetated canopy. Several modeling studies have hypothesized that this effect may be a significant driver of the historical terrestrial carbon sink, and may therefore be an important climate feedback associated with changing air quality. In this study, we quantify the impact of anthropogenic aerosols on gross primary production (GPP) in the eastern United States. We focus on the eastern U.S. because 1) rapid decreases in SO2 emissions over the past two decades create an opportunity to examine the effects of reduced SO4 mass and aerosol optical depth; 2) SO2 emissions in the United States have been well quantified; 3) carbon fluxes within temperate ecosystems in the eastern United States have been well observed. We use accurate SO2 emission data for 1995-2013 in the Community Earth System Model (CESM) to determine trends in AOD, surface radiation, and photosynthesis. Between 1995 and 2013, U.S. SO2 emissions declined by over 70%, coinciding with observed AOD reductions of 3.0 ± 0.6% y-1 over the eastern U.S. In the Community Earth System Model (CESM), these trends cause diffuse light to decrease regionally by almost 0.6% y-1, leading to declines GPP of 0.07% y-1. Integrated over the analysis period and domain, this represents 0.5 PgC of omitted GPP. A separate upscaling calculation that used published relationships between GPP and diffuse light agreed with the CESM model results within 20%. The agreement between simulated and data-constrained upscaling results strongly suggests that anthropogenic sulfate trends have a small impact on carbon uptake in temperate forests due to scattered light.

40 CFR 63.9620 - On which units and by what date must I conduct performance tests or other initial compliance...

Code of Federal Regulations, 2013 CFR

2013-07-01

... section. (1) All emission units within a group must be of the same process type (e.g., primary crushers... emission units from different process types together for the purposes of this section. (2) All emission units within a group must also have the same type of air pollution control device (e.g., wet scrubbers...

40 CFR 63.9620 - On which units and by what date must I conduct performance tests or other initial compliance...

Code of Federal Regulations, 2014 CFR

2014-07-01

... section. (1) All emission units within a group must be of the same process type (e.g., primary crushers... emission units from different process types together for the purposes of this section. (2) All emission units within a group must also have the same type of air pollution control device (e.g., wet scrubbers...

40 CFR 63.9620 - On which units and by what date must I conduct performance tests or other initial compliance...

Code of Federal Regulations, 2012 CFR

2012-07-01

... section. (1) All emission units within a group must be of the same process type (e.g., primary crushers... emission units from different process types together for the purposes of this section. (2) All emission units within a group must also have the same type of air pollution control device (e.g., wet scrubbers...

40 CFR 63.9620 - On which units and by what date must I conduct performance tests or other initial compliance...

Code of Federal Regulations, 2010 CFR

2010-07-01

... section. (1) All emission units within a group must be of the same process type (e.g., primary crushers... emission units from different process types together for the purposes of this section. (2) All emission units within a group must also have the same type of air pollution control device (e.g., wet scrubbers...

40 CFR 63.9620 - On which units and by what date must I conduct performance tests or other initial compliance...

Code of Federal Regulations, 2011 CFR

2011-07-01

... section. (1) All emission units within a group must be of the same process type (e.g., primary crushers... emission units from different process types together for the purposes of this section. (2) All emission units within a group must also have the same type of air pollution control device (e.g., wet scrubbers...

Hyperspectrally-Resolved Surface Emissivity Derived Under Optically Thin Clouds

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu; Smith, William L.; Strow, L. Larrabee; Yang, Ping

2010-01-01

Surface spectral emissivity derived from current and future satellites can and will reveal critical information about the Earth s ecosystem and land surface type properties, which can be utilized as a means of long-term monitoring of global environment and climate change. Hyperspectrally-resolved surface emissivities are derived with an algorithm utilizes a combined fast radiative transfer model (RTM) with a molecular RTM and a cloud RTM accounting for both atmospheric absorption and cloud absorption/scattering. Clouds are automatically detected and cloud microphysical parameters are retrieved; and emissivity is retrieved under clear and optically thin cloud conditions. This technique separates surface emissivity from skin temperature by representing the emissivity spectrum with eigenvectors derived from a laboratory measured emissivity database; in other words, using the constraint as a means for the emissivity to vary smoothly across atmospheric absorption lines. Here we present the emissivity derived under optically thin clouds in comparison with that under clear conditions.

Estimating population exposure to ambient polycyclic aromatic hydrocarbon in the United States - Part I: Model development and evaluation.

PubMed

Zhang, Jie; Li, Jingyi; Wang, Peng; Chen, Gang; Mendola, Pauline; Sherman, Seth; Ying, Qi

2017-02-01

PAHs (polycyclic aromatic hydrocarbons) in the environment are of significant concern due to their negative impact on human health. PAH measurements at the air toxics monitoring network stations alone are not sufficient to provide a complete picture of ambient PAH levels or to allow accurate assessment of public exposure in the United States. In this study, speciation profiles for PAHs were prepared using data assembled from existing emission profile data bases, and the Sparse Matrix Operator Kernel Emissions (SMOKE) model was used to generate the gridded national emissions of 16 priority PAHs in the US. The estimated emissions were applied to simulate ambient concentration of PAHs for January, April, July and October 2011, using a modified Community Multiscale Air Quality (CMAQ) model (v5.0.1) that treats the gas and particle phase partitioning of PAHs and their reactions in the gas phase and on particle surface. Predicted daily PAH concentrations at 61 air toxics monitoring sites generally agreed with observations, and averaging the predictions over a month reduced the overall error. The best model performance was obtained at rural sites, with an average mean fractional bias (MFB) of -0.03 and mean fractional error (MFE) of 0.70. Concentrations at suburban and urban sites were underestimated with overall MFB=-0.57 and MFE=0.89. Predicted PAH concentrations were highest in January with better model performance (MFB=0.12, MFE=0.69; including all sites), and lowest in July with worse model performance (MFB=-0.90, MFE=1.08). Including heterogeneous reactions of several PAHs with O 3 on particle surface reduced the over-prediction bias in winter, although significant uncertainties were expected due to relative simple treatment of the heterogeneous reactions in the current model. Copyright © 2016 Elsevier Ltd. All rights reserved.

Soils as a Record of Anthropogenic Metal Inputs: From Susquehanna Shale Hills Critical Zone Observatory to Marietta, Ohio

NASA Astrophysics Data System (ADS)

Carter, M.; Herndon, E.; Brantley, S. L.

2012-12-01

Atmospheric deposition of metals emitted by anthropogenic activities has been a significant source of metal loading into soils in the United States for more than 200 years. Based on research at the Susquehanna Shale Hills CZO, we began investigating Mn inputs to soils in the northeastern U.S.A. from widespread atmospheric Mn emissions from steel manufacturers and coal-burning power plants. Total Mn inputs to Shale Hills soils at ridgetops are calculated to be 42 mg Mn/cm2. In order to more directly evaluate the link between Mn emissions and Mn enrichment in soils, we are now investigating soils around a ferromanganese refinery in Marietta, Ohio that is currently the largest emission source of manganese (Mn) into the atmosphere in the U.S.A. Particulate emissions during production are up to 31-34% percent manganese oxide (MnO) by weight. These particles range in diameter from 0.05 to 0.4 μm, making them both highly mobile and respirable. In order to assess the role of soils in Marietta as sinks for atmospherically-derived Mn, a series of soil cores have been collected from a range of distances (0.5 - 35 km) from the refinery. Mn is enriched at the soil surface up to 8 times above parent material composition sampled at 1 m depth near the source and decreases as a function of distance. Total mass of Mn added to soils per unit land area integrated over the soil depth core was calculated to be 50 mg Mn/cm2¬¬ near the refinery. In contrast, 10 mg Mn/cm2 was lost from the soil profile at a distance of 35 km from the facility. Enrichment of chromium (Cr) up to 3 times was also found in surface soils near the refinery, consistent with the production of ferrochromium at the Marietta plant. Further trace element analyses are being used to fingerprint atmospheric inputs from the refinery into the soil. Models of Mn addition to soils are also being developed and compared to known rates of emission.

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... subject to section 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

Impacts of fine particulate matter on premature mortality under future climate change

NASA Astrophysics Data System (ADS)

Park, S.; Allen, R.; Lim, C. H.

2016-12-01

Climate change modulates concentration of fine particulate matter (PM2.5) via modifying atmospheric circulation and the hydrological cycle. Furthermore, surface PM2.5 is significantly associated with respiratory diseases and premature mortality. In this study, we assess the response of PM2.5 concentration to climate change in the future (end of 21st century) and its effects on year of life lost (YLL) and premature mortality. We use outputs from five models participating in the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) to evaluate climate change effects on PM2.5: for present climate with current aerosol emissions and greenhouse gas concentrations, and for future climate, also with present-day aerosol emissions, but with end-of-the century greenhouse gas concentrations, sea surface temperatures and sea-ice. The results show that climate change is associated with an increase in PM2.5 concentration. Combined with global future population data from the United Nation (UN), we also find an increase in premature mortality and YLL.

Nitrogen Dioxide Trend over the United States: the View from the Ground, the View from Space

NASA Technical Reports Server (NTRS)

Lamsal, Lok N.; Duncan, Bryan N.; Yoshida, Yasuko; Krotkov, Nickolay A.

2014-01-01

Emissions of nitrogen oxides (NOx) are decreasing over the US due to environmental policies and technological change. We use observations of tropospheric nitrogen dioxide (NO2) columns from the Ozone Monitoring Instrument (OMI) satellite instrument and surface NO2 in-situ measurements from the air quality system (AQS) to quantify the trends, and to establish the relationship between the trends in tropospheric column and surface concentration. Both observations show substantial downward trends from 2005 to 2013, with an average reduction of 35 percent according to OMI and 38 percent according to AQS. The annual reduction rates are largest in 2005-2009: -6.2 percent per year and -7 percent per year observed by OMI and AQS, respectively. We examine various factors affecting the estimated trend in OMI NO2 columns and in-situ NO2 observations. An improved understanding of trend offers valuable insights about effectiveness of emission reduction regulations on state and federal level.

The Next-generation Berkeley High Resolution NO2 (BEHR NO2) Retrieval: Design and Preliminary Emissions Constraints

NASA Astrophysics Data System (ADS)

Laughner, J.; Cohen, R. C.

2017-12-01

Recent work has identified a number of assumptions made in NO2 retrievals that lead to biases in the retrieved NO2 column density. These include the treatment of the surface as an isotropic reflector, the absence of lightning NO2 in high resolution a priori profiles, and the use of monthly averaged a priori profiles. We present a new release of the Berkeley High Resolution (BEHR) OMI NO2 retrieval based on the new NASA Standard Product (version 3) that addresses these assumptions by: accounting for surface anisotropy by using a BRDF albedo product, using an updated method of regridding NO2 data, and revised NO2 a priori profiles that better account for lightning NO2 and daily variation in the profile shape. We quantify the effect these changes have on the retrieved NO2 column densities and the resultant impact these updates have on constraints of urban NOx emissions for select cities throughout the United States.

40 CFR 96.175 - Petitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... designated representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit... representative of a CAIR NOX unit that is not subject to an Acid Rain emissions limitation may submit a petition... representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit a petition...

40 CFR 96.175 - Petitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... designated representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit... representative of a CAIR NOX unit that is not subject to an Acid Rain emissions limitation may submit a petition... representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit a petition...

40 CFR 96.175 - Petitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... designated representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit... representative of a CAIR NOX unit that is not subject to an Acid Rain emissions limitation may submit a petition... representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit a petition...

40 CFR 96.175 - Petitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... designated representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit... representative of a CAIR NOX unit that is not subject to an Acid Rain emissions limitation may submit a petition... representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit a petition...

40 CFR 96.175 - Petitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... designated representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit... representative of a CAIR NOX unit that is not subject to an Acid Rain emissions limitation may submit a petition... representative of a CAIR NOX unit that is subject to an Acid Rain emissions limitation may submit a petition...

Characteristics of NOx emission from Chinese coal-fired power plants equipped with new technologies

NASA Astrophysics Data System (ADS)

Ma, Zizhen; Deng, Jianguo; Li, Zhen; Li, Qing; Zhao, Ping; Wang, Liguo; Sun, Yezhu; Zheng, Hongxian; Pan, Li; Zhao, Shun; Jiang, Jingkun; Wang, Shuxiao; Duan, Lei

2016-04-01

Coal combustion in coal-fired power plants is one of the important anthropogenic NOx sources, especially in China. Many policies and methods aiming at reducing pollutants, such as increasing installed capacity and installing air pollution control devices (APCDs), especially selective catalytic reduction (SCR) units, could alter NOx emission characteristics (NOx concentration, NO2/NOx ratio, and NOx emission factor). This study reported the NOx characteristics of eight new coal-fired power-generating units with different boiler patterns, installed capacities, operating loads, and coal types. The results showed that larger units produced less NOx, and anthracite combustion generated more NOx than bitumite and lignite combustion. During formation, the NOx emission factors varied from 1.81 to 6.14 g/kg, much lower than those of older units at similar scales. This implies that NOx emissions of current and future units could be overestimated if they are based on outdated emission factors. In addition, APCDs, especially SCR, greatly decreased NOx emissions, but increased NO2/NOx ratios. Regardless, the NO2/NOx ratios were lower than 5%, in accordance with the guidelines and supporting the current method for calculating NOx emissions from coal-fired power plants that ignore NO2.

Assessing the Gap Between Top-down and Bottom-up Measured Methane Emissions in Indianapolis, IN.

NASA Astrophysics Data System (ADS)

Prasad, K.; Lamb, B. K.; Cambaliza, M. O. L.; Shepson, P. B.; Stirm, B. H.; Salmon, O. E.; Lavoie, T. N.; Lauvaux, T.; Ferrara, T.; Howard, T.; Edburg, S. L.; Whetstone, J. R.

2014-12-01

Releases of methane (CH4) from the natural gas supply chain in the United States account for approximately 30% of the total US CH4 emissions. However, there continues to be large questions regarding the accuracy of current emission inventories for methane emissions from natural gas usage. In this paper, we describe results from top-down and bottom-up measurements of methane emissions from the large isolated city of Indianapolis. The top-down results are based on aircraft mass balance and tower based inverse modeling methods, while the bottom-up results are based on direct component sampling at metering and regulating stations, surface enclosure measurements of surveyed pipeline leaks, and tracer/modeling methods for other urban sources. Mobile mapping of methane urban concentrations was also used to identify significant sources and to show an urban-wide low level enhancement of methane levels. The residual difference between top-down and bottom-up measured emissions is large and cannot be fully explained in terms of the uncertainties in top-down and bottom-up emission measurements and estimates. Thus, the residual appears to be, at least partly, attributed to a significant wide-spread diffusive source. Analyses are included to estimate the size and nature of this diffusive source.

High-resolution inventory of technologies, activities, and emissions of coal-fired power plants in China from 1990 to 2010

NASA Astrophysics Data System (ADS)

Liu, F.; Zhang, Q.; Tong, D.; Zheng, B.; Li, M.; Huo, H.; He, K. B.

2015-12-01

This paper, which focuses on emissions from China's coal-fired power plants during 1990-2010, is the second in a series of papers that aims to develop a high-resolution emission inventory for China. This is the first time that emissions from China's coal-fired power plants were estimated at unit level for a 20-year period. This inventory is constructed from a unit-based database compiled in this study, named the China coal-fired Power plant Emissions Database (CPED), which includes detailed information on the technologies, activity data, operation situation, emission factors, and locations of individual units and supplements with aggregated data where unit-based information is not available. Between 1990 and 2010, compared to a 479 % growth in coal consumption, emissions from China's coal-fired power plants increased by 56, 335, and 442 % for SO2, NOx, and CO2, respectively, and decreased by 23 and 27 % for PM2.5 and PM10 respectively. Driven by the accelerated economic growth, large power plants were constructed throughout the country after 2000, resulting in a dramatic growth in emissions. The growth trend of emissions has been effectively curbed since 2005 due to strengthened emission control measures including the installation of flue gas desulfurization (FGD) systems and the optimization of the generation fleet mix by promoting large units and decommissioning small ones. Compared to previous emission inventories, CPED significantly improved the spatial resolution and temporal profile of the power plant emission inventory in China by extensive use of underlying data at unit level. The new inventory developed in this study will enable a close examination of temporal and spatial variations of power plant emissions in China and will help to improve the performances of chemical transport models by providing more accurate emission data.

Influence of nuclear power unit on decreasing emissions of greenhouse gases

NASA Astrophysics Data System (ADS)

Stanek, Wojciech; Szargut, Jan; Kolenda, Zygmunt; Czarnowska, Lucyna

2015-03-01

The paper presents a comparison of selected power technologies from the point of view of emissions of greenhouse gases. Such evaluation is most often based only on analysis of direct emissions from combustion. However, the direct analysis does not show full picture of the problem as significant emissions of GHG appear also in the process of mining and transportation of fuel. It is demonstrated in the paper that comparison of power technologies from the GHG point of view has to be done using the cumulative calculus covering the whole cycle of fuel mining, processing, transportation and end-use. From this point of view coal technologies are in comparable level as gas technologies while nuclear power units are characterised with lowest GHG emissions. Mentioned technologies are compared from the point of view of GHG emissions in full cycle. Specific GHG cumulative emission factors per unit of generated electricity are determined. These factors have been applied to simulation of the influence of introduction of nuclear power units on decrease of GHG emissions in domestic scale. Within the presented simulations the prognosis of domestic power sector development according to the Polish energy policy till 2030 has been taken into account. The profitability of introduction of nuclear power units from the point of view of decreasing GHG emissions has been proved.

Bridging the Global Precipitation and Soil Moisture Active Passive Missions: Variability of Microwave Surface Emissivity from In situ and Remote Sensing Perspectives

NASA Astrophysics Data System (ADS)

Zheng, Y.; Kirstetter, P.; Hong, Y.; Turk, J.

2016-12-01

The overland precipitation retrievals from satellite passive microwave (PMW) sensors such as the Global Precipitation Mission (GPM) microwave imager (GMI) are impacted by the land surface emissivity. The estimation of PMW emissivity faces challenges because it is highly variable under the influence of surface properties such as soil moisture, surface roughness and vegetation. This study proposes an improved quantitative understanding of the relationship between the emissivity and surface parameters. Surface parameter information is obtained through (i) in-situ measurements from the International Soil Moisture Network and (ii) satellite measurements from the Soil Moisture Active and Passive mission (SMAP) which provides global scale soil moisture estimates. The variation of emissivity is quantified with soil moisture, surface temperature and vegetation at various frequencies/polarization and over different types of land surfaces to sheds light into the processes governing the emission of the land. This analysis is used to estimate the emissivity under rainy conditions. The framework built with in-situ measurements serves as a benchmark for satellite-based analyses, which paves a way toward global scale emissivity estimates using SMAP.

Design of a hybrid emissivity domestic electric oven

NASA Astrophysics Data System (ADS)

Isik, Ozgur; Onbasioglu, Seyhan Uygur

2017-10-01

In this study, the radiative properties of the surfaces of an electric oven were investigated. Using experimental data related to an oven-like enclosure, a novel combination of surface properties was developed. Three different surface emissivity combinations were analysed experimentally: low-emissivity, high emissivity (black-coated), and hybrid emissivity. The term "hybrid emissivity design" here corresponds to an enclosure with some high emissive and some low-emissive surfaces. The experiments were carried out according to the EN 50304 standard. When a brick (load) was placed in the enclosure, the view factors between its surfaces were calculated with the Monte Carlo method. These and the measured surface temperatures were then used to calculate the radiative heat fluxes on the surfaces of the load. The three different models were compared with respect to energy consumption and baking time. The hybrid model performed best, with the highest radiative heat transfer between the surfaces of the enclosure and the load and minimum heat loss from the cavity. Thus, it was the most efficient model with the lowest energy consumption and the shortest baking time. The recent European Union regulation regarding the energy labelling of domestic ovens was used.

Active radiometer for self-calibrated furnace temperature measurements

DOEpatents

Woskov, Paul P.; Cohn, Daniel R.; Titus, Charles H.; Wittle, J. Kenneth; Surma, Jeffrey E.

1996-01-01

Radiometer with a probe beam superimposed on its field-of-view for furnace temperature measurements. The radiometer includes a heterodyne millimeter/submillimeter-wave receiver including a millimeter/submillimeter-wave source for probing. The receiver is adapted to receive radiation from a surface whose temperature is to be measured. The radiation includes a surface emission portion and a surface reflection portion which includes the probe beam energy reflected from the surface. The surface emission portion is related to the surface temperature and the surface reflection portion is related to the emissivity of the surface. The simultaneous measurement of surface emissivity serves as a real time calibration of the temperature measurement.

40 CFR 98.73 - Calculating GHG emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

40 CFR 98.73 - Calculating GHG emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

40 CFR 98.73 - Calculating GHG emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

40 CFR 98.73 - Calculating GHG emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

40 CFR 98.73 - Calculating GHG emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

Thermal insulated glazing unit

DOEpatents

Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

1988-04-05

An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

Assessment and economic valuation of air pollution impacts on human health over Europe and the United States as calculated by a multi-model ensemble in the framework of AQMEII3

NASA Astrophysics Data System (ADS)

Im, Ulas; Brandt, Jørgen; Geels, Camilla; Mantzius Hansen, Kaj; Heile Christensen, Jesper; Skou Andersen, Mikael; Solazzo, Efisio; Kioutsioukis, Ioannis; Alyuz, Ummugulsum; Balzarini, Alessandra; Baro, Rocio; Bellasio, Roberto; Bianconi, Roberto; Bieser, Johannes; Colette, Augustin; Curci, Gabriele; Farrow, Aidan; Flemming, Johannes; Fraser, Andrea; Jimenez-Guerrero, Pedro; Kitwiroon, Nutthida; Liang, Ciao-Kai; Nopmongcol, Uarporn; Pirovano, Guido; Pozzoli, Luca; Prank, Marje; Rose, Rebecca; Sokhi, Ranjeet; Tuccella, Paolo; Unal, Alper; Garcia Vivanco, Marta; West, Jason; Yarwood, Greg; Hogrefe, Christian; Galmarini, Stefano

2018-04-01

The impact of air pollution on human health and the associated external costs in Europe and the United States (US) for the year 2010 are modeled by a multi-model ensemble of regional models in the frame of the third phase of the Air Quality Modelling Evaluation International Initiative (AQMEII3). The modeled surface concentrations of O3, CO, SO2 and PM2.5 are used as input to the Economic Valuation of Air Pollution (EVA) system to calculate the resulting health impacts and the associated external costs from each individual model. Along with a base case simulation, additional runs were performed introducing 20 % anthropogenic emission reductions both globally and regionally in Europe, North America and east Asia, as defined by the second phase of the Task Force on Hemispheric Transport of Air Pollution (TF-HTAP2). Health impacts estimated by using concentration inputs from different chemistry-transport models (CTMs) to the EVA system can vary up to a factor of 3 in Europe (12 models) and the United States (3 models). In Europe, the multi-model mean total number of premature deaths (acute and chronic) is calculated to be 414 000, while in the US, it is estimated to be 160 000, in agreement with previous global and regional studies. The economic valuation of these health impacts is calculated to be EUR 300 billion and 145 billion in Europe and the US, respectively. A subset of models that produce the smallest error compared to the surface observations at each time step against an all-model mean ensemble results in increase of health impacts by up to 30 % in Europe, while in the US, the optimal ensemble mean led to a decrease in the calculated health impacts by ˜ 11 %. A total of 54 000 and 27 500 premature deaths can be avoided by a 20 % reduction of global anthropogenic emissions in Europe and the US, respectively. A 20 % reduction of North American anthropogenic emissions avoids a total of ˜ 1000 premature deaths in Europe and 25 000 total premature deaths in the US. A 20 % decrease of anthropogenic emissions within the European source region avoids a total of 47 000 premature deaths in Europe. Reducing the east Asian anthropogenic emissions by 20 % avoids ˜ 2000 total premature deaths in the US. These results show that the domestic anthropogenic emissions make the largest impacts on premature deaths on a continental scale, while foreign sources make a minor contribution to adverse impacts of air pollution.

Temperature dependence of low-energy positron-induced Auger-electron emission: Evidence for high surface sensitivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayer, R.; Schwab, A.; Weiss, A.

1990-08-01

We report the experimental observation of the temperature dependence of the intensity of low-energy positron-annihilation-induced Auger-electron emission spectroscopy (PAES) from Cu(100). These studies show that the mechanism for stimulating Auger electrons is found to compete with positronium (Ps) emission from a surface. The positrons that induce Auger-electron emission therefore originate from the same surface state from which Ps is thermally desorbed. Hence, PAES should have higher surface sensitivity ({approximately}1 A) relative to conventional methods for generating Auger-electron emission from surfaces ({approximately}5--10 A).

Study of the normal emissivity of molybdenum during thermal oxidation process

NASA Astrophysics Data System (ADS)

Xu, Yihan; Li, Longfei; Yu, Kun; Liu, Yufang

2018-04-01

The infrared normal spectral emissivity of the oxidized molybdenum was measured during thermal oxidation process, and the integral emissivity was calculated from the data of spectral emissivity. It is found that the surface oxidation has a remarkable effect on the spectral emissivity of molybdenum, and the spectral emissivity curves become more fluctuant with the increase in oxidation time. The integral emissivity grows exponentially with the oxidation time at 773 K, remains almost constant at 823 K, and fluctuates at 873 and 923 K. The X-ray fluorescence spectrometer, the X-ray diffraction, and the scanning electron microscopy were employed to analyze the changes in surface composition and surface morphology. The results show that the most probable reason for the variation of integral emissivity is the change in surface roughness caused by the variation in the size and shape of oxide particle on specimen surface.

Frequency and Angular Variations of Land Surface Microwave Emissivities: Can we Estimate SSM/T and AMSU Emissivities from SSM/I Emissivities?

NASA Technical Reports Server (NTRS)

Prigent, Catherine; Wigneron, Jean-Pierre; Rossow, William B.; Pardo-Carrion, Juan R.

1999-01-01

To retrieve temperature and humidity profiles from SSM/T and AMSU, it is important to quantify the contribution of the Earth surface emission. So far, no global estimates of the land surface emissivities are available at SSM/T and AMSU frequencies and scanning conditions. The land surface emissivities have been previously calculated for the globe from the SSM/I conical scanner between 19 and 85 GHz. To analyze the feasibility of deriving SSM/T and AMSU land surface emissivities from SSM/I emissivities, the spectral and angular variations of the emissivities are studied, with the help of ground-based measurements, models and satellite estimates. Up to 100 GHz, for snow and ice free areas, the SSM/T and AMSU emissivities can be derived with useful accuracy from the SSM/I emissivities- The emissivities can be linearly interpolated in frequency. Based on ground-based emissivity measurements of various surface types, a simple model is proposed to estimate SSM/T and AMSU emissivities for all zenith angles knowing only the emissivities for the vertical and horizontal polarizations at 53 deg zenith angle. The method is tested on the SSM/T-2 91.655 GHz channels. The mean difference between the SSM/T-2 and SSM/I-derived emissivities is less than or equal to 0.01 for all zenith angles with an r.m.s. difference of approx. = 0.02. Above 100 GHz, preliminary results are presented at 150 GHz, based on SSM/T-2 observations and are compared with the very few estimations available in the literature.

The Effect of Central American Smoke Aerosols on the Air Quality and Climate over the Southeastern United States: First Results from RAMS-AROMA

NASA Astrophysics Data System (ADS)

Wang, J.; Christopher, S. A.; Nair, U. S.; Reid, J.; Prins, E. M.; Szykman, J.

2004-12-01

Observation shows that smoke aerosols from biomass burning activities in Central America can be transported to the Southeastern United States (SEUS). In this study, the Regional Atmospheric Modeling System - Assimilation and Radiation Online Modeling of Aerosols (RAMS-AROMA) is used to investigate the effect of transported smoke aerosols on climate and air quality over the SEUS. AROMA is an aerosol transport model with capabilities of online integration of aerosol radiation effects and online assimilation of satellite-derived aerosol and emission products. It is assembled within the RAMS, so two-way interactions between aerosol fields and other meteorology fields are achieved simultaneously during each model time step. RAMS-AROMA is a unique tool that can be used to examine the aerosol radiative impacts on the surface energy budget and atmospheric heating rate and to investigate how atmospheric thermal and dynamical processes respond to such impacts and consequently affect the aerosol distribution (so called feedbacks). First results regarding air quality effects and radiative forcing of transported smoke aerosols will be presented from RAMS-AROMA based on assimilation of smoke emission products from the Fire Locating and Modeling of Burning Emissions (FLAMBE) project and aerosol optical thickness data derived from the MODIS instrument on the Terra and Aqua satellites. Comparisons with PM2.5 data collected from the EPA observation network and the aerosol optical thickness data from the DOE Atmosphere Radiation Measurements in the Southern Great Plains (ARM SGP) showed that RAMS-AROMA can predict the timing and spatial distribution of smoke events very well, with an accuracy useful for air quality forecasts. The smoke radiative effects on the surface temperature and atmospheric heating rate as well as their feedbacks will also be discussed.

Sea-based Infrared Radiance Measurements of Ocean and Atmosphere from the ACAPEX/CalWater2 Campaign

NASA Astrophysics Data System (ADS)

Gero, P. J.; Knuteson, R.; Hackel, D.; Phillips, C.; Westphall, M.

2015-12-01

The ARM Cloud Aerosol Precipitation Experiment (ACAPEX) / CalWater2 was a joint DOE/NOAA field campaign in early 2015 to study atmospheric rivers in the Pacific Ocean and their impacts on the western United States. The campaign goals were to improve understanding and modeling of large-scale dynamics and cloud and precipitation processes associated with atmospheric rivers and aerosol-cloud interactions that influence precipitation variability and extremes in the western United States. Coordinated measurements were made from ground-, aircraft- and sea-based platforms. The second ARM mobile facility (AMF-2) was deployed on board the NOAA Ship Ronald H. Brown for this campaign, which included a new Marine Atmospheric Emitted Radiance Interferometer (M-AERI) to measure the atmospheric downwelling and reflected infrared radiance spectrum at the Earth's surface with high absolute accuracy. The M-AERI measures spectral infrared radiance between 520-3020 cm-1 (3.3-19 μm) at a resolution of 0.5 cm-1. The M-AERI can selectively view the atmospheric scene at zenith, and ocean/atmospheric scenes over a range of ±45° from the horizon. The AERI uses two high-emissivity blackbodies for radiometric calibration, which in conjunction with the instrument design and a suite of rigorous laboratory diagnostics, ensures the radiometric accuracy to be better than 1% (3σ) of the ambient radiance. The M-AERI radiance spectra can be used to retrieve profiles of temperature and water vapor in the troposphere, as well as measurements of trace gases, cloud properties, surface emissivity and ocean skin temperature. We present preliminary results on measurements of ocean skin temperature, ocean emissivity properties as a function of view angle and wind speed, as well as comparisons with radiosondes and satellite observations.

40 CFR 96.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... entire year and shall report the NOX mass emissions data and heat input data for such unit, in an... monitoring of NOX mass emissions) for such unit for the entire year and report the NOX mass emissions data and heat input data for such unit in accordance with paragraph (d)(1) of this section; or (ii) Meet...

Mercury and halogens in coal--Their role in determining mercury emissions from coal combustion

USGS Publications Warehouse

Kolker, Allan; Quick, Jeffrey C.; Senior, Connie L.; Belkin, Harvey E.

2012-01-01

Mercury is a toxic pollutant. In its elemental form, gaseous mercury has a long residence time in the atmosphere, up to a year, allowing it to be transported long distances from emission sources. Mercury can be emitted from natural sources such as volcanoes, or from anthropogenic sources, such as coal-fired powerplants. In addition, all sources of mercury on the Earth's surface can re-emit it from land and sea back to the atmosphere, from which it is then redeposited. Mercury in the atmosphere is present in such low concentrations that it is not considered harmful. Once mercury enters the aquatic environment, however, it can undergo a series of biochemical transformations that convert a portion of the mercury originally present to methylmercury, a highly toxic organic form of mercury that accumulates in fish and birds. Many factors contribute to creation of methylmercury in aquatic ecosystems, including mercury availability, sediment and nutrient load, bacterial influence, and chemical conditions. In the United States, consumption of fish with high levels of methylmercury is the most common pathway for human exposure to mercury, leading the U.S. Environmental Protection Agency (EPA) to issue fish consumption advisories in every State. The EPA estimates that 50 percent of the mercury entering the atmosphere in the United States is emitted from coal-burning utility powerplants. An EPA rule, known as MATS (for Mercury and Air Toxics Standards), to reduce emissions of mercury and other toxic pollutants from powerplants, was signed in December 2011. The rule, which is currently under review, specifies limits for mercury and other toxic elements, such as arsenic, chromium, and nickel. MATS also places limits on emission of harmful acid gases, such as hydrochloric acid and hydrofluoric acid. These standards are the result of a 2010 detailed nationwide program by the EPA to sample stack emissions and thousands of shipments of coal to coal-burning powerplants. The United States is the only nation to have collected such detailed information for mercury in both its coal and its utility emissions.

Two Surface Temperature Retrieval Methods Compared Over Agricultural Lands

NASA Technical Reports Server (NTRS)

French, Andrew N.; Schmugge, Thomas J.; Jacob, Frederic; Ogawa, Kenta; Houser, Paul R. (Technical Monitor)

2002-01-01

Accurate, spatially distributed surface temperatures are required for modeling evapotranspiration (ET) over agricultural fields under wide ranging conditions, including stressed and unstressed vegetation. Modeling approaches that use surface temperature observations, however, have the burden of estimating surface emissivities. Emissivity estimation, the subject of much recent research, is facilitated by observations in multiple thermal infrared bands. But it is nevertheless a difficult task. Using observations from a multiband thermal sensor, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), estimated surface emissivities and temperatures are retrieved in two different ways: the temperature emissivity separation approach (TES) and the normalized emissivity approach (NEM). Both rely upon empirical relationships, but the assumed relationships are different. TES relies upon a relationship between the minimum spectral emissivity and the range of observed emissivities. NEM relies upon an assumption that at least one thermal band has a pre-determined emissivity (close to 1.0). The benefits and consequences of each approach will be demonstrated for two different landscapes: one in central Oklahoma, USA and another in southern New Mexico.

Multiple Emission Angle Surface-Atmosphere Separations of MGS Thermal Emission Spectrometer Data

NASA Technical Reports Server (NTRS)

Bandfield, J. L.; Smith, M. D.

2001-01-01

Multiple emission angle observations taken by MGS-TES have been used to derive atmospheric opacities and surface temperatures and emissivities with increased accuracy and wavelength coverage. Martian high albedo region surface spectra have now been isolated. Additional information is contained in the original extended abstract.

On the relationship between land surface infrared emissivity and soil moisture

NASA Astrophysics Data System (ADS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu

2018-01-01

The relationship between surface infrared (IR) emissivity and soil moisture content has been investigated based on satellite measurements. Surface soil moisture content can be estimated by IR remote sensing, namely using the surface parameters of IR emissivity, temperature, vegetation coverage, and soil texture. It is possible to separate IR emissivity from other parameters affecting surface soil moisture estimation. The main objective of this paper is to examine the correlation between land surface IR emissivity and soil moisture. To this end, we have developed a simple yet effective scheme to estimate volumetric soil moisture (VSM) using IR land surface emissivity retrieved from satellite IR spectral radiance measurements, assuming those other parameters impacting the radiative transfer (e.g., temperature, vegetation coverage, and surface roughness) are known for an acceptable time and space reference location. This scheme is applied to a decade of global IR emissivity data retrieved from MetOp-A infrared atmospheric sounding interferometer measurements. The VSM estimated from these IR emissivity data (denoted as IR-VSM) is used to demonstrate its measurement-to-measurement variations. Representative 0.25-deg spatially-gridded monthly-mean IR-VSM global datasets are then assembled to compare with those routinely provided from satellite microwave (MW) multisensor measurements (denoted as MW-VSM), demonstrating VSM spatial variations as well as seasonal-cycles and interannual variability. Initial positive agreement is shown to exist between IR- and MW-VSM (i.e., R2 = 0.85). IR land surface emissivity contains surface water content information. So, when IR measurements are used to estimate soil moisture, this correlation produces results that correspond with those customarily achievable from MW measurements. A decade-long monthly-gridded emissivity atlas is used to estimate IR-VSM, to demonstrate its seasonal-cycle and interannual variation, which is spatially coherent and consistent with that from MW measurements, and, moreover, to achieve our objective of investigating the relationship between land surface IR emissivity and soil moisture.

Unitized Regenerative Fuel Cell System Gas Storage/Radiator Development

NASA Technical Reports Server (NTRS)

Jakupca, Ian; Burke, Kenneth A.

2003-01-01

The ancillary components for Unitized Regenerative Fuel Cell (URFC) Energy Storage System are being developed at the NASA Glenn Research Center. This URFC system is unique in that it uses the surface area of the hydrogen and oxygen storage tanks as radiating heat surfaces for overall thermal control of the system. The waste heat generated by the URFC stack during charging and discharging is transferred from the cell stack to the surface of each tank by loop heat pipes. The heat pipes are coiled around each tank and covered with a thin layer of thermally conductive layer of carbon composite. The thin layer of carbon composite acts as a fin structure that spreads the heat away from the heat pipe and across the entire tank surface. Two different sized commercial grade composite tanks were constructed with integral heat pipes and tested in a thermal vacuum chamber to examine the feasibility of using the storage tanks as system radiators. The storage radiators were subjected to different steady-state heat loads and varying heat load profiles. The surface emissivity and specific heat capacity of each tank were calculated. The results were incorporated into a model that simulates the performance of similar radiators using lightweight, space rated carbon composite tanks.

Guide to Magellan image interpretation

NASA Technical Reports Server (NTRS)

Ford, John P.; Plaut, Jeffrey J.; Weitz, Catherine M.; Farr, Tom G.; Senske, David A.; Stofan, Ellen R.; Michaels, Gregory; Parker, Timothy J.; Fulton, D. (Editor)

1993-01-01

An overview of Magellan Mission requirements, radar system characteristics, and methods of data collection is followed by a description of the image data, mosaic formats, areal coverage, resolution, and pixel DN-to-dB conversion. The availability and sources of image data are outlined. Applications of the altimeter data to estimate relief, Fresnel reflectivity, and surface slope, and the radiometer data to derive microwave emissivity are summarized and illustrated in conjunction with corresponding SAR image data. Same-side and opposite-side stereo images provide examples of parallax differences from which to measure relief with a lateral resolution many times greater than that of the altimeter. Basic radar interactions with geologic surfaces are discussed with respect to radar-imaging geometry, surface roughness, backscatter modeling, and dielectric constant. Techniques are described for interpreting the geomorphology and surface properties of surficial features, impact craters, tectonically deformed terrain, and volcanic landforms. The morphologic characteristics that distinguish impact craters from volcanic craters are defined. Criteria for discriminating extensional and compressional origins of tectonic features are discussed. Volcanic edifices, constructs, and lava channels are readily identified from their radar outlines in images. Geologic map units are identified on the basis of surface texture, image brightness, pattern, and morphology. Superposition, cross-cutting relations, and areal distribution of the units serve to elucidate the geologic history.

Estimation of carbon dioxide emissions per urban center link unit using data collected by the Advanced Traffic Information System in Daejeon, Korea

NASA Astrophysics Data System (ADS)

Ryu, B. Y.; Jung, H. J.; Bae, S. H.; Choi, C. U.

2013-12-01

CO2 emissions on roads in urban centers substantially affect global warming. It is important to quantify CO2 emissions in terms of the link unit in order to reduce these emissions on the roads. Therefore, in this study, we utilized real-time traffic data and attempted to develop a methodology for estimating CO2 emissions per link unit. Because of the recent development of the vehicle-to-infrastructure (V2I) communication technology, data from probe vehicles (PVs) can be collected and speed per link unit can be calculated. Among the existing emission calculation methodologies, mesoscale modeling, which is a representative modeling measurement technique, requires speed and traffic data per link unit. As it is not feasible to install fixed detectors at every link for traffic data collection, in this study, we developed a model for traffic volume estimation by utilizing the number of PVs that can be additionally collected when the PV data are collected. Multiple linear regression and an artificial neural network (ANN) were used for estimating the traffic volume. The independent variables and input data for each model are the number of PVs, travel time index (TTI), the number of lanes, and time slots. The result from the traffic volume estimate model shows that the mean absolute percentage error (MAPE) of the ANN is 18.67%, thus proving that it is more effective. The ANN-based traffic volume estimation served as the basis for the calculation of emissions per link unit. The daily average emissions for Daejeon, where this study was based, were 2210.19 ton/day. By vehicle type, passenger cars accounted for 71.28% of the total emissions. By road, Gyeryongro emitted 125.48 ton/day, accounting for 5.68% of the total emission, the highest percentage of all roads. In terms of emissions per kilometer, Hanbatdaero had the highest emission volume, with 7.26 ton/day/km on average. This study proves that real-time traffic data allow an emissions estimate in terms of the link unit. Furthermore, an analysis of CO2 emissions can support traffic management to make decisions related to the reduction of carbon emissions.

Active radiometer for self-calibrated furnace temperature measurements

DOEpatents

Woskov, P.P.; Cohn, D.R.; Titus, C.H.; Wittle, J.K.; Surma, J.E.

1996-11-12

A radiometer is described with a probe beam superimposed on its field-of-view for furnace temperature measurements. The radiometer includes a heterodyne millimeter/submillimeter-wave receiver including a millimeter/submillimeter-wave source for probing. The receiver is adapted to receive radiation from a surface whose temperature is to be measured. The radiation includes a surface emission portion and a surface reflection portion which includes the probe beam energy reflected from the surface. The surface emission portion is related to the surface temperature and the surface reflection portion is related to the emissivity of the surface. The simultaneous measurement of surface emissivity serves as a real time calibration of the temperature measurement. 5 figs.

Impacts of global, regional, and sectoral black carbon emission reductions on surface air quality and human mortality

NASA Astrophysics Data System (ADS)

Anenberg, S. C.; Talgo, K.; Arunachalam, S.; Dolwick, P.; Jang, C.; West, J. J.

2011-07-01

As a component of fine particulate matter (PM2.5), black carbon (BC) is associated with premature human mortality. BC also affects climate by absorbing solar radiation and reducing planetary albedo. Several studies have examined the climate impacts of BC emissions, but the associated health impacts have been studied less extensively. Here, we examine the surface PM2.5 and premature mortality impacts of halving anthropogenic BC emissions globally and individually from eight world regions and three major economic sectors. We use a global chemical transport model, MOZART-4, to simulate PM2.5 concentrations and a health impact function to calculate premature cardiopulmonary and lung cancer deaths. We estimate that halving global anthropogenic BC emissions reduces outdoor population-weighted average PM2.5 by 542 ng m-3 (1.8 %) and avoids 157 000 (95 % confidence interval, 120 000-194 000) annual premature deaths globally, with the vast majority occurring within the source region. Most of these avoided deaths can be achieved by halving emissions in East Asia (China; 54 %), followed by South Asia (India; 31 %), however South Asian emissions have 50 % greater mortality impacts per unit BC emitted than East Asian emissions. Globally, halving residential, industrial, and transportation emissions contributes 47 %, 35 %, and 15 % to the avoided deaths from halving all anthropogenic BC emissions. These contributions are 1.2, 1.2, and 0.6 times each sector's portion of global BC emissions, owing to the degree of co-location with population globally. We find that reducing BC emissions increases regional SO4 concentrations by up to 28 % of the magnitude of the regional BC concentration reductions, due to reduced absorption of radiation that drives photochemistry. Impacts of residential BC emissions are likely underestimated since indoor PM2.5 exposure is excluded. We estimate ∼8 times more avoided deaths when BC and organic carbon (OC) emissions are halved together, suggesting that these results greatly underestimate the full air pollution-related mortality benefits of BC mitigation strategies which generally decrease both BC and OC. The choice of concentration-response factor and health effect thresholds affects estimated global avoided deaths by as much as 56 % but does not strongly affect the regional distribution. Confidence in our results would be strengthened by reducing uncertainties in emissions, model parameterization of aerosol processes, grid resolution, and PM2.5 concentration-mortality relationships globally.

40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

Code of Federal Regulations, 2011 CFR

2011-07-01

... for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). 60.105a Section 60.105a... and operations for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). (a) FCCU and... Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units...

40 CFR 60.105a - Monitoring of emissions and operations for fluid catalytic cracking units (FCCU) and fluid coking...

Code of Federal Regulations, 2010 CFR

2010-07-01

... for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). 60.105a Section 60.105a... and operations for fluid catalytic cracking units (FCCU) and fluid coking units (FCU). (a) FCCU and... Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units...

40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... Recovery Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in...

40 CFR Table 22 to Subpart Uuu of... - Inorganic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Catalytic Reforming Units 22 Table 22 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 22 Table 22 to Subpart UUU of Part 63—Inorganic HAP Emission Limits for Catalytic Reforming Units...

40 CFR Table 22 to Subpart Uuu of... - Inorganic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Catalytic Reforming Units 22 Table 22 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 22 Table 22 to Subpart UUU of Part 63—Inorganic HAP Emission Limits for Catalytic Reforming Units...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... Recovery Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

40 CFR 63.1588 - What inspections must I conduct?

Code of Federal Regulations, 2013 CFR

2013-07-01

... treatment units as of October 26, 1999. The method you use to determine your HAP emissions, such as modeling... emission modeling, for each HAP, determine annual emissions (Mg/year) from all wastewater units up to, but...

40 CFR 63.1588 - What inspections must I conduct?

Code of Federal Regulations, 2012 CFR

2012-07-01

... treatment units as of October 26, 1999. The method you use to determine your HAP emissions, such as modeling... emission modeling, for each HAP, determine annual emissions (Mg/year) from all wastewater units up to, but...

Global Thermal Power Plants Database: Unit-Based CO2, SO2, NOX and PM2.5 Emissions in 2010

NASA Astrophysics Data System (ADS)

Tong, D.; Qiang, Z.; Davis, S. J.

2016-12-01

There are more than 30,000 thermal power plants now operating worldwide, reflecting a tremendously diverse infrastructure that includes units burning oil, natural gas, coal and biomass and ranging in capacity from <1MW to >1GW. Although the electricity generated by this infrastructure is vital to economic activities across the world, it also produces more CO2 and air pollution emissions than any other industry sector. Here we present a new database of global thermal power-generating units and their emissions as of 2010, GPED (Global Power Emissions Database), including the detailed unit information of installed capacity, operation year, geographic location, fuel type and control measures for more than 70000 units. In this study, we have compiled, combined, and harmonized the available underlying data related to thermal power-generating units (e.g. eGRID of USA, CPED of China and published Indian power plants database), and then analyzed the generating capacity, capacity factor, fuel type, age, location, and installed pollution-control technology in order to determine those units with disproportionately high levels of emissions. In total, this work is of great importance for improving spatial distribution of global thermal power plants emissions and exploring their environmental impacts at global scale.

An old disk still capable of forming a planetary system.

PubMed

Bergin, Edwin A; Cleeves, L Ilsedore; Gorti, Uma; Zhang, Ke; Blake, Geoffrey A; Green, Joel D; Andrews, Sean M; Evans, Neal J; Henning, Thomas; Oberg, Karin; Pontoppidan, Klaus; Qi, Chunhua; Salyk, Colette; van Dishoeck, Ewine F

2013-01-31

From the masses of the planets orbiting the Sun, and the abundance of elements relative to hydrogen, it is estimated that when the Solar System formed, the circumstellar disk must have had a minimum mass of around 0.01 solar masses within about 100 astronomical units of the star. (One astronomical unit is the Earth-Sun distance.) The main constituent of the disk, gaseous molecular hydrogen, does not efficiently emit radiation from the disk mass reservoir, and so the most common measure of the disk mass is dust thermal emission and lines of gaseous carbon monoxide. Carbon monoxide emission generally indicates properties of the disk surface, and the conversion from dust emission to gas mass requires knowledge of the grain properties and the gas-to-dust mass ratio, which probably differ from their interstellar values. As a result, mass estimates vary by orders of magnitude, as exemplified by the relatively old (3-10 million years) star TW Hydrae, for which the range is 0.0005-0.06 solar masses. Here we report the detection of the fundamental rotational transition of hydrogen deuteride from the direction of TW Hydrae. Hydrogen deuteride is a good tracer of disk gas because it follows the distribution of molecular hydrogen and its emission is sensitive to the total mass. The detection of hydrogen deuteride, combined with existing observations and detailed models, implies a disk mass of more than 0.05 solar masses, which is enough to form a planetary system like our own.

40 CFR 97.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... section, the NOX emission rate and NOX concentration values substituted for missing data under subpart D... report the NOX mass emissions data and heat input data for such unit, in an electronic quarterly report... emissions) for such unit for the entire year and report the NOX mass emissions data and heat input data for...

40 CFR 97.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2012 CFR

2012-07-01

...: (1) If the CAIR NOX Ozone Season unit is subject to an Acid Rain emissions limitation or a CAIR NOX... Acid Rain emissions limitation or a CAIR NOX emissions limitation, then the CAIR designated...) of this chapter. (4) For CAIR NOX Ozone Season units that are also subject to an Acid Rain emissions...

40 CFR 97.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2014 CFR

2014-07-01

...: (1) If the CAIR NOX Ozone Season unit is subject to an Acid Rain emissions limitation or a CAIR NOX... Acid Rain emissions limitation or a CAIR NOX emissions limitation, then the CAIR designated...) of this chapter. (4) For CAIR NOX Ozone Season units that are also subject to an Acid Rain emissions...

40 CFR 97.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2013 CFR

2013-07-01

...: (1) If the CAIR NOX Ozone Season unit is subject to an Acid Rain emissions limitation or a CAIR NOX... Acid Rain emissions limitation or a CAIR NOX emissions limitation, then the CAIR designated...) of this chapter. (4) For CAIR NOX Ozone Season units that are also subject to an Acid Rain emissions...

40 CFR 97.374 - Recordkeeping and reporting.

Code of Federal Regulations, 2011 CFR

2011-07-01

...: (1) If the CAIR NOX Ozone Season unit is subject to an Acid Rain emissions limitation or a CAIR NOX... Acid Rain emissions limitation or a CAIR NOX emissions limitation, then the CAIR designated...) of this chapter. (4) For CAIR NOX Ozone Season units that are also subject to an Acid Rain emissions...

Modeling potential climate change impacts on the trees of the northeastern United States

Treesearch

Louis Iverson; Anantha Prasad; Stephen Matthews

2008-01-01

We evaluated 134 tree species from the eastern United States for potential response to several scenarios of climate change, and summarized those responses for nine northeastern United States. We modeled and mapped each species individually and show current and potential future distributions for two emission scenarios (A1fi [higher emission] and B1 [lower emission]) and...

40 CFR 61.67 - Emission tests.

Code of Federal Regulations, 2011 CFR

2011-07-01

... = Conversion factor from ppmw to units of emission standard, 0.001 (metric units) = 0.002 (English units) PPVC...(a), or § 61.64(a)(1), (b), (c), or (d), or from any control system to which reactor emissions are... conversion factor, 1,000 g/kg (1 lb/lb). 10−6 = Conversion factor for ppm. Z = Production rate, kg/hr (lb/hr...

40 CFR 61.67 - Emission tests.

Code of Federal Regulations, 2012 CFR

2012-07-01

... = Conversion factor from ppmw to units of emission standard, 0.001 (metric units) = 0.002 (English units) PPVC...(a), or § 61.64(a)(1), (b), (c), or (d), or from any control system to which reactor emissions are... conversion factor, 1,000 g/kg (1 lb/lb). 10−6 = Conversion factor for ppm. Z = Production rate, kg/hr (lb/hr...

40 CFR Table 4 to Subpart Bbbb of... - Model Rule-Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a

Code of Federal Regulations, 2011 CFR

2011-07-01

... Existing Small Municipal Waste Combustion Unit a 4 Table 4 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a For...

40 CFR Table 2 to Subpart Bbbb of... - Model Rule-Class I Emission Limits for Existing Small Municipal Waste Combustion Units a

Code of Federal Regulations, 2014 CFR

2014-07-01

... Existing Small Municipal Waste Combustion Units a 2 Table 2 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class I Emission Limits for Existing Small Municipal Waste Combustion Units a For...

40 CFR Table 4 to Subpart Bbbb of... - Model Rule-Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a

Code of Federal Regulations, 2014 CFR

2014-07-01

... Existing Small Municipal Waste Combustion Unit a 4 Table 4 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a For...

40 CFR Table 4 to Subpart Bbbb of... - Model Rule-Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a

Code of Federal Regulations, 2010 CFR

2010-07-01

... Existing Small Municipal Waste Combustion Unit a 4 Table 4 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a For...

40 CFR Table 2 to Subpart Bbbb of... - Model Rule-Class I Emission Limits for Existing Small Municipal Waste Combustion Units a

Code of Federal Regulations, 2012 CFR

2012-07-01

... Existing Small Municipal Waste Combustion Units a 2 Table 2 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class I Emission Limits for Existing Small Municipal Waste Combustion Units a For...

40 CFR Table 2 to Subpart Bbbb of... - Model Rule-Class I Emission Limits for Existing Small Municipal Waste Combustion Units a

Code of Federal Regulations, 2013 CFR

2013-07-01

... Existing Small Municipal Waste Combustion Units a 2 Table 2 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class I Emission Limits for Existing Small Municipal Waste Combustion Units a For...

40 CFR Table 2 to Subpart Bbbb of... - Model Rule-Class I Emission Limits for Existing Small Municipal Waste Combustion Units a

Code of Federal Regulations, 2010 CFR

2010-07-01

... Existing Small Municipal Waste Combustion Units a 2 Table 2 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class I Emission Limits for Existing Small Municipal Waste Combustion Units a For...

40 CFR Table 2 to Subpart Bbbb of... - Model Rule-Class I Emission Limits for Existing Small Municipal Waste Combustion Units a

Code of Federal Regulations, 2011 CFR

2011-07-01

... Existing Small Municipal Waste Combustion Units a 2 Table 2 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class I Emission Limits for Existing Small Municipal Waste Combustion Units a For...

40 CFR Table 4 to Subpart Bbbb of... - Model Rule-Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a

Code of Federal Regulations, 2012 CFR

2012-07-01

... Existing Small Municipal Waste Combustion Unit a 4 Table 4 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a For...

40 CFR Table 4 to Subpart Bbbb of... - Model Rule-Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a

Code of Federal Regulations, 2013 CFR

2013-07-01

... Existing Small Municipal Waste Combustion Unit a 4 Table 4 to Subpart BBBB of Part 60 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... Part 60—Model Rule—Class II Emission Limits for Existing Small Municipal Waste Combustion Unit a For...

40 CFR 97.71 - Initial certification and recertification procedures.

Code of Federal Regulations, 2013 CFR

2013-07-01

... operator of a NOX Budget unit that is subject to an Acid Rain emissions limitation shall comply with the... section. (b) The owner or operator of a NOX Budget unit that is not subject to an Acid Rain emissions...) of this section. The owner or operator of a NOX Budget unit that is subject to an Acid Rain emissions...

40 CFR 97.71 - Initial certification and recertification procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

... operator of a NOX Budget unit that is subject to an Acid Rain emissions limitation shall comply with the... section. (b) The owner or operator of a NOX Budget unit that is not subject to an Acid Rain emissions...) of this section. The owner or operator of a NOX Budget unit that is subject to an Acid Rain emissions...

40 CFR 97.71 - Initial certification and recertification procedures.

Code of Federal Regulations, 2012 CFR

2012-07-01

... operator of a NOX Budget unit that is subject to an Acid Rain emissions limitation shall comply with the... section. (b) The owner or operator of a NOX Budget unit that is not subject to an Acid Rain emissions...) of this section. The owner or operator of a NOX Budget unit that is subject to an Acid Rain emissions...

Engine Tune-up Service. Unit 6: Emission Control Systems. Student Guide. Automotive Mechanics Curriculum.

ERIC Educational Resources Information Center

Bacon, E. Miles

This student guide is for Unit 6, Emission Control Systems, in the Engine Tune-Up Service portion of the Automotive Mechanics Curriculum. It deals with inspecting, testing, and servicing an emission control system. A companion review exercise book and posttests are available separately as CE 031 221-222. An introduction tells how this unit fits…

40 CFR Table 30 to Subpart Uuu of... - Operating Limits for HAP Emissions From Sulfur Recovery Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Operating Limits for HAP Emissions From Sulfur Recovery Units 30 Table 30 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 30 Table 30 to Subpart UUU of Part 63—Operating Limits for HAP Emissions...

40 CFR Table 36 to Subpart Uuu of... - Work Practice Standards for HAP Emissions From Bypass Lines

Code of Federal Regulations, 2011 CFR

2011-07-01

... Emissions From Bypass Lines 36 Table 36 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 36 Table 36 to Subpart UUU of Part 63—Work Practice Standards for HAP Emissions From Bypass Lines...

40 CFR Table 30 to Subpart Uuu of... - Operating Limits for HAP Emissions From Sulfur Recovery Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Operating Limits for HAP Emissions From Sulfur Recovery Units 30 Table 30 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 30 Table 30 to Subpart UUU of Part 63—Operating Limits for HAP Emissions...

40 CFR Table 36 to Subpart Uuu of... - Work Practice Standards for HAP Emissions From Bypass Lines

Code of Federal Regulations, 2010 CFR

2010-07-01

... Emissions From Bypass Lines 36 Table 36 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 36 Table 36 to Subpart UUU of Part 63—Work Practice Standards for HAP Emissions From Bypass Lines...

Correlation of CVD Diamond Electron Emission with Film Properties

NASA Astrophysics Data System (ADS)

Bozeman, S. P.; Baumann, P. K.; Ward, B. L.; Nemanich, R. J.; Dreifus, D. L.

1996-03-01

Electron field emission from metals is affected by surface morphology and the properties of any dielectric coating. Recent results have demonstrated low field electron emission from p-type diamond, and photoemission measurements have identified surface treatments that result in a negative electron affinity (NEA). In this study, the field emission from diamond is correlated with surface treatment, surface roughness, and film properties (doping and defects). Electron emission measurements are reported on diamond films synthesized by plasma CVD. Ultraviolet photoemission spectroscopy indicates that the CVD films exhibit a NEA after exposure to hydrogen plasma. Field emission current-voltage measurements indicate "threshold voltages" ranging from approximately 20 to 100 V/micron.

Greenhouse gas emissions from home composting of organic household waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andersen, J.K., E-mail: jka@env.dtu.d; Boldrin, A.; Christensen, T.H.

2010-12-15

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week{sup -1} and the temperature inside the composting units was in all cases only a few degrees (2-10 {sup o}C) higher than the ambient temperature.more » The emissions of methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) were quantified as 0.4-4.2 kg CH{sub 4} Mg{sup -1} input wet waste (ww) and 0.30-0.55 kg N{sub 2}O Mg{sup -1} ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH{sub 4} and N{sub 2}O emissions) of 100-239 kg CO{sub 2}-eq. Mg{sup -1} ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH{sub 4} during mixing which was estimated to 8-12% of the total CH{sub 4} emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg{sup -1} ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO{sub 2}-eq. Mg{sup -1} ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.« less

Greenhouse gas emissions from home composting of organic household waste.

PubMed

Andersen, J K; Boldrin, A; Christensen, T H; Scheutz, C

2010-12-01

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week(-1) and the temperature inside the composting units was in all cases only a few degrees (2-10 °C) higher than the ambient temperature. The emissions of methane (CH(4)) and nitrous oxide (N(2)O) were quantified as 0.4-4.2 kg CH(4)Mg(-1) input wet waste (ww) and 0.30-0.55 kg N(2)OMg(-1)ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH(4) and N(2)O emissions) of 100-239 kg CO(2)-eq.Mg(-1)ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH(4) during mixing which was estimated to 8-12% of the total CH(4) emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg(-1)ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO(2)-eq.Mg(-1)ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants. Copyright © 2010 Elsevier Ltd. All rights reserved.

Estimating State-Specific Contributions to PM2.5- and O3-Related Health Burden from Residential Combustion and Electricity Generating Unit Emissions in the United States.

PubMed

Penn, Stefani L; Arunachalam, Saravanan; Woody, Matthew; Heiger-Bernays, Wendy; Tripodis, Yorghos; Levy, Jonathan I

2017-03-01

Residential combustion (RC) and electricity generating unit (EGU) emissions adversely impact air quality and human health by increasing ambient concentrations of fine particulate matter (PM 2.5 ) and ozone (O 3 ). Studies to date have not isolated contributing emissions by state of origin (source-state), which is necessary for policy makers to determine efficient strategies to decrease health impacts. In this study, we aimed to estimate health impacts (premature mortalities) attributable to PM 2.5 and O 3 from RC and EGU emissions by precursor species, source sector, and source-state in the continental United States for 2005. We used the Community Multiscale Air Quality model employing the decoupled direct method to quantify changes in air quality and epidemiological evidence to determine concentration-response functions to calculate associated health impacts. We estimated 21,000 premature mortalities per year from EGU emissions, driven by sulfur dioxide emissions forming PM 2.5 . More than half of EGU health impacts are attributable to emissions from eight states with significant coal combustion and large downwind populations. We estimate 10,000 premature mortalities per year from RC emissions, driven by primary PM 2.5 emissions. States with large populations and significant residential wood combustion dominate RC health impacts. Annual mortality risk per thousand tons of precursor emissions (health damage functions) varied significantly across source-states for both source sectors and all precursor pollutants. Our findings reinforce the importance of pollutant-specific, location-specific, and source-specific models of health impacts in design of health-risk minimizing emissions control policies. Citation: Penn SL, Arunachalam S, Woody M, Heiger-Bernays W, Tripodis Y, Levy JI. 2017. Estimating state-specific contributions to PM 2.5 - and O 3 -related health burden from residential combustion and electricity generating unit emissions in the United States. Environ Health Perspect 125:324-332; http://dx.doi.org/10.1289/EHP550.

Dust emissions created by low-level rotary-winged aircraft flight over desert surfaces

NASA Astrophysics Data System (ADS)

Gillies, J. A.; Etyemezian, V.; Kuhns, H.; McAlpine, J. D.; King, J.; Uppapalli, S.; Nikolich, G.; Engelbrecht, J.

2010-03-01

There is a dearth of information on dust emissions from sources that are unique to U.S. Department of Defense testing and training activities. Dust emissions of PM 10 and PM 2.5 from low-level rotary-winged aircraft travelling (rotor-blade ≈7 m above ground level) over two types of desert surfaces (i.e., relatively undisturbed desert pavement and disturbed desert soil surface) were characterized at the Yuma Proving Ground (Yuma, AZ) in May 2007. Fugitive emissions are created by the shear stress of the outflow of high speed air created by the rotor-blade. The strength of the emissions was observed to scale primarily as a function of forward travel speed of the aircraft. Speed affects dust emissions in two ways: 1) as speed increases, peak shear stress at the soil surface was observed to decline proportionally, and 2) as the helicopter's forward speed increases its residence time over any location on the surface diminishes, so the time the downward rotor-generated flow is acting upon that surface must also decrease. The state of the surface over which the travel occurs also affects the scale of the emissions. The disturbed desert test surface produced approximately an order of magnitude greater emission than the undisturbed surface. Based on the measured emission rates for the test aircraft and the established scaling relationships, a rotary-winged aircraft similar to the test aircraft traveling 30 km h -1 over the disturbed surface would need to travel 4 km to produce emissions equivalent to one kilometer of travel by a light wheeled military vehicle also traveling at 30 km h -1 on an unpaved road. As rotary-winged aircraft activity is substantially less than that of off-road vehicle military testing and training activities it is likely that this source is small compared to emissions created by ground-based vehicle movements.

Secondary electron emission characteristics of ion-textured copper and high-purity isotropic graphite surfaces

NASA Technical Reports Server (NTRS)

Curren, A. N.; Jensen, K. A.

1984-01-01

Experimentally determined values of true secondary electron emission and relative values of reflected primary electron yield for untreated and ion textured oxygen free high conductivity copper and untreated and ion textured high purity isotropic graphite surfaces are presented for a range of primary electron beam energies and beam impingement angles. This investigation was conducted to provide information that would improve the efficiency of multistage depressed collectors (MDC's) for microwave amplifier traveling wave tubes in space communications and aircraft applications. For high efficiency, MDC electrode surfaces must have low secondary electron emission characteristics. Although copper is a commonly used material for MDC electrodes, it exhibits relatively high levels of secondary electron emission if its surface is not treated for emission control. Recent studies demonstrated that high purity isotropic graphite is a promising material for MDC electrodes, particularly with ion textured surfaces. The materials were tested at primary electron beam energies of 200 to 2000 eV and at direct (0 deg) to near grazing (85 deg) beam impingement angles. True secondary electron emission and relative reflected primary electron yield characteristics of the ion textured surfaces were compared with each other and with those of untreated surfaces of the same materials. Both the untreated and ion textured graphite surfaces and the ion treated copper surface exhibited sharply reduced secondary electron emission characteristics relative to those of untreated copper. The ion treated graphite surface yielded the lowest emission levels.

A Population of Faint Extended Line Emitters and the Host Galaxies of Optically Thick QSO Absorption Systems

NASA Astrophysics Data System (ADS)

Rauch, Michael; Haehnelt, Martin; Bunker, Andrew; Becker, George; Marleau, Francine; Graham, James; Cristiani, Stefano; Jarvis, Matt; Lacey, Cedric; Morris, Simon; Peroux, Celine; Röttgering, Huub; Theuns, Tom

2008-07-01

We have conducted a long-slit search for low surface brightness Lyα emitters at redshift 2.67 < z < 3.75. A 92 hr long exposure with the ESO VLT FORS2 instrument down to a 1 σ surface brightness detection limit of 8 × 10-20 erg cm-2 s-1 arcsec-2 per arcsec2 aperture yielded a sample of 27 single line emitters with fluxes of a few × 10-18 erg s-1 cm-2. We present arguments that most objects are indeed Lyα. The large comoving number density, 3 × 10-2 h370 Mpc-3, the large covering factor, dN/dz ~ 0.2-1, and the often extended Lyα emission suggest that the emitters can be identified with the elusive host population of damped Lyα systems (DLAS) and high column density Lyman limit systems (LLS). A small inferred star formation rate, perhaps supplemented by cooling radiation, appears to energetically dominate the Lyα emission, and is consistent with the low metallicity, low dust content, and theoretically inferred low masses of DLAS, and with the relative lack of success of earlier searches for their optical counterparts. Some of the line profiles show evidence for radiative transfer in galactic outflows. Stacking surface brightness profiles, we find emission out to at least 4''. The centrally concentrated emission of most objects appears to light up the outskirts of the emitters (where LLS arise) down to a column density where the conversion from UV to Lyα photon becomes inefficient. DLAS, high column density LLS, and the emitter population discovered in this survey appear to be different observational manifestations of the same low-mass, protogalactic building blocks of present-day L* galaxies. Based partly on observations made with ESO Telescopes at the Paranal Observatories under Program ID LP173.A-0440, and partly on observations obtained at the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under a cooperative agreement with the NSF on behalf of the Gemini partnership: the National Science Foundation (United States), the Science and Technology Facilities Council (United Kingdom), the National Research Council (Canada), CONICYT (Chile), the Australian Research Council (Australia), CNPq (Brazil) and CONICET (Argentina).

2002 Monthly Carbon Dioxide Emissions from Mexico at a 10x10k Spatial Resolution

NASA Astrophysics Data System (ADS)

Mendoza, D. L.; Gurney, K. R.; Geethakumar, S.; Zhou, Y.; Sahni, N.

2009-12-01

The contribution of fossil fuel CO2 emissions to the total measured amount of CO2 in the Earth’s atmosphere remains an important component of carbon cycle science, particularly as efforts to understand the net exchange of carbon at the surface move to smaller scales. In order to reduce the uncertainty of this flux, researchers led by Purdue University have built a high-resolution fossil fuel CO2 flux inventory for the United States, called “Vulcan”. The Vulcan inventory quantifies emissions for the United States at 10km resolution every hour for the year 2002 and can be seen as a key component of a national assessment and verification system for greenhouse gas emissions and emissions mitigation. As part of the North American Carbon Project, the 2002 carbon dioxide emissions from Mexico are presented at the monthly temporal and municipality spatial scale. Mexico is of particular importance because of the scientific integration under the North American Carbon Program. Furthermore, Mexico has seen a notable growth in its population as well as migration toward urban centers and increasing energy requirements due in part to industrial intensification. The native resolution of the emissions is geolocated (lat/lon) for point sources, such as power plants, airports, and large industry. The emissions are estimated at the municipality level for residential and commercial sources, and allocated to roads for the mobile transport sector. Data sources include the National Emissions Inventory (NEI), Commission for Environmental Cooperation (CEC), and Carbon Monitoring for Action (CARMA). CO2 emissions are calculated from the 1999 NEI data by converting CO emissions using sector and process-dependent emission factors, and is scaled up to 2002 using statistics obtained from the Carbon Dioxide Information Analysis Center CDIAC. CEC and CARMA data, which encompass power plant emissions, are already in units of CO2. Emissions are regridded to 10x10k and 0.1x0.1 deg grids to enable atmospheric CO2 transport modeling. All economic sectors are analyzed, including power plants, commercial, residential, industrial, on-road, and non-road. Municipality and regional scale analysis is presented to explore the differences in economic and industrial development and need. Specific centers of high emissions are highlighted and analyzed in order to put into context the development and growth of certain economic sectors. The annualized emissions are compared to estimates by the International Energy Agency and found to be very similar although some discrepancies are expected due to the different methods of obtaining results. Vulcan reports process-based emissions while IEA reports fuel sales. The Vulcan output is also disaggregated by fuel type and comparisons with IEA are presented across economic sectors. A monthly product based on monthly sales is also presented. Sales by major fuel types (oil, natural gas, coal) are obtained from EIA data and those results shape the monthly cycle. These results are compared to a similar national studies, and similarities and differences are analyzed and discussed.

Effect of a fuel activation device (FAD) on particulate matter and black carbon emissions from a diesel locomotive engine.

PubMed

Park, Duckshin; Lee, Taejeong; Lee, Yongil; Jeong, Wonseog; Kwon, Soon-Bark; Kim, Dongsool; Lee, Kiyoung

2017-01-01

Emission reduction is one of the most efficient control measures in fuel-powered locomotives. The purpose of this study was to determine the reduction in particulate matter (PM) and black carbon (BC) emissions following the installation of a fuel activation device (FAD). The FAD was developed to enhance fuel combustion by atomizing fuel and to increase the surface area per unit volume of injected fuel. Emission reduction by the FAD was evaluated by installing a FAD in an operating diesel locomotive in Mongolia. The test was conducted on a train operating on a round-trip 238-km route between Ulaanbaatar and Choir stations in Mongolia. The fuel consumption rate was slightly reduced following the FAD installation. The FAD installation decreased PM and BC emissions in the diesel locomotive, especially coarse PM. The PM 10 reductions achieved after FAD installation were 58.0, 69.7, and 34.2% for the constant velocity, stopping, and acceleration stages of the train's operation, respectively. The BC reduction rates were 29.5, 52.8, and 27.4% for the constant velocity, stopping, and acceleration stages, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568...

40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568(a)(1...

40 CFR Table 29 to Subpart Uuu of... - HAP Emission Limits for Sulfur Recovery Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Units 29 Table 29 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 29 Table 29 to Subpart UUU of Part 63—HAP Emission Limits for Sulfur Recovery Units As stated in § 63.1568(a)(1...

Exoelectron emission from a clean, annealed magnesium single crystal during oxygen adsorption

NASA Technical Reports Server (NTRS)

Ferrante, J.

1976-01-01

Exoelectron emission was observed from a clean, annealed Mg (0001) surface during oxygen and chlorine adsorption at pressures of 6.5x10 0.00001- N/sq m and lower. the studies were performed in an ultrahigh vacuum system. The crystals were cleaned by argon ion bombardment and annealed at 300 C. Auger electron spectroscopy was used to verify surface cleanliness, and low energy electron diffraction was used to verify that the surface was annealed. The emission was found to be oxygen arrival rate dependent. Two peaks were observed in the electron emission with exposure. Evidence is presented that the formation of the second peak corresponds to oxidation of the Mg surface. No emission was observed from clean aluminum during adsorption. Results verify that electron emission occurs from a strain free surface simply upon adsorption of oxygen. A qualitative explanation for the mechanisms of emission in terms of chemical effects is presented.

Estimation of Phosphorus Emissions in the Upper Iguazu Basin (brazil) Using GIS and the More Model

NASA Astrophysics Data System (ADS)

Acosta Porras, E. A.; Kishi, R. T.; Fuchs, S.; Hilgert, S.

2016-06-01

Pollution emissions into the drainage basin have direct impact on surface water quality. These emissions result from human activities that turn into pollution loads when they reach the water bodies, as point or diffuse sources. Their pollution potential depends on the characteristics and quantity of the transported materials. The estimation of pollution loads can assist decision-making in basin management. Knowledge about the potential pollution sources allows for a prioritization of pollution control policies to achieve the desired water quality. Consequently, it helps avoiding problems such as eutrophication of water bodies. The focus of the research described in this study is related to phosphorus emissions into river basins. The study area is the upper Iguazu basin that lies in the northeast region of the State of Paraná, Brazil, covering about 2,965 km2 and around 4 million inhabitants live concentrated on just 16% of its area. The MoRE (Modeling of Regionalized Emissions) model was used to estimate phosphorus emissions. MoRE is a model that uses empirical approaches to model processes in analytical units, capable of using spatially distributed parameters, covering both, emissions from point sources as well as non-point sources. In order to model the processes, the basin was divided into 152 analytical units with an average size of 20 km2. Available data was organized in a GIS environment. Using e.g. layers of precipitation, the Digital Terrain Model from a 1:10000 scale map as well as soils and land cover, which were derived from remote sensing imagery. Further data is used, such as point pollution discharges and statistical socio-economic data. The model shows that one of the main pollution sources in the upper Iguazu basin is the domestic sewage that enters the river as point source (effluents of treatment stations) and/or as diffuse pollution, caused by failures of sanitary sewer systems or clandestine sewer discharges, accounting for about 56% of the emissions. Second significant shares of emissions come from direct runoff or groundwater, being responsible for 32% of the total emissions. Finally, agricultural erosion and industry pathways represent 12% of emissions. This study shows that MoRE is capable of producing valid emission calculation on a relatively reduced input data basis.

The surface emissions trap: a new approach in indoor air purification.

PubMed

Markowicz, Pawel; Larsson, Lennart

2012-11-01

A new device for stopping or reducing potentially irritating or harmful emissions from surfaces indoors is described. The device is a surface emissions trap prototype and consists of an adsorbent sheet with a semipermeable barrier surrounded by two thin nonwoven layers. The trap may be applied directly at the source of the emissions e.g. at moisture-affected floors and walls, surfaces contaminated by chemical spills etc. This results in an immediate stop or reduction of the emitting pollutants. The trap has a very low water vapor resistance thus allowing drying of wet surfaces. In laboratory experiments typically 98% reduction of air concentrations of volatile organic compounds and a virtually total reduction of mold particle-associated mycotoxins was observed. The surface emissions trap may represent a convenient and efficient way of restoring indoor environments polluted by microbial and other moisture-associated emissions. Copyright © 2012 Elsevier B.V. All rights reserved.

Urban density and the metabolic reach of metropolitan areas: A panel analysis of per capita transportation emissions at the county-level.

PubMed

Ergas, Christina; Clement, Matthew; McGee, Julius

2016-07-01

We engage a tension in the urban environment literature that positions cities as both drivers of environmental destruction and loci of environmental protection. We argue that the traditional binary view of cities as either harmful or beneficial is too simplistic; we advance a more nuanced understanding of cities to study their internal and external metabolic effects in terms of carbon emissions from on-road transportation at the county-level across the continental United States between 2002 and 2007. First, utilizing satellite imagery from the National Land Cover Database, we create a novel measure of population density by quantifying the number of people per square mile of impervious surface area. Second, we develop a measure of metropolitan adjacency from the rural classifications datasets published by the USDA. In spatial regression models, we find that while higher density reduces emissions, counties that are geographically isolated from metropolitan areas actually have lower per capita emissions, all else equal. We elaborate on the conceptual, methodological, and practical implications of our study in the conclusion. Copyright © 2016 Elsevier Inc. All rights reserved.

Emissivity of Candidate Materials for VHTR Applicationbs: Role of Oxidation and Surface Modification Treatments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sridharan, Kumar; Allen, Todd; Anderson, Mark

The Generation IV (GEN IV) Nuclear Energy Systems Initiative was instituted by the Department of Energy (DOE) with the goal of researching and developing technologies and materials necessary for various types of future reactors. These GEN IV reactors will employ advanced fuel cycles, passive safety systems, and other innovative systems, leading to significant differences between these future reactors and current water-cooled reactors. The leading candidate for the Next Generation Nuclear Plant (NGNP) to be built at Idaho National Lab (INL) in the United States is the Very High Temperature Reactor (VHTR). Due to the high operating temperatures of the VHTR,more » the Reactor Pressure Vessel (RPV) will partially rely on heat transfer by radiation for cooling. Heat expulsion by radiation will become all the more important during high temperature excursions during off-normal accident scenarios. Radiant power is dictated by emissivity, a material property. The NGNP Materials Research and Development Program Plan [1] has identified emissivity and the effects of high temperature oxide formation on emissivity as an area of research towards the development of the VHTR.« less

Effects of temperature-dependent NOx emissions on continental ozone production

NASA Astrophysics Data System (ADS)

Romer, Paul S.; Duffey, Kaitlin C.; Wooldridge, Paul J.; Edgerton, Eric; Baumann, Karsten; Feiner, Philip A.; Miller, David O.; Brune, William H.; Koss, Abigail R.; de Gouw, Joost A.; Misztal, Pawel K.; Goldstein, Allen H.; Cohen, Ronald C.

2018-02-01

Surface ozone concentrations are observed to increase with rising temperatures, but the mechanisms responsible for this effect in rural and remote continental regions remain uncertain. Better understanding of the effects of temperature on ozone is crucial to understanding global air quality and how it may be affected by climate change. We combine measurements from a focused ground campaign in summer 2013 with a long-term record from a forested site in the rural southeastern United States, to examine how daily average temperature affects ozone production. We find that changes to local chemistry are key drivers of increased ozone concentrations on hotter days, with integrated daily ozone production increasing by 2.3 ppb °C-1. Nearly half of this increase is attributable to temperature-driven increases in emissions of nitrogen oxides (NOx), most likely by soil microbes. The increase of soil NOx emissions with temperature suggests that ozone will continue to increase with temperature in the future, even as direct anthropogenic NOx emissions decrease dramatically. The links between temperature, soil NOx, and ozone form a positive climate feedback.

Thermal effects of λ = 808 nm GaAlAs diode laser irradiation on different titanium surfaces.

PubMed

Giannelli, Marco; Lasagni, Massimo; Bani, Daniele

2015-12-01

Diode lasers are widely used in dental laser treatment, but little is known about their thermal effects on different titanium implant surfaces. This is a key issue because already a 10 °C increase over the normal body temperature can induce bone injury and compromise osseo-integration. The present study aimed at evaluating the temperature changes and surface alterations experienced by different titanium surfaces upon irradiation with a λ = 808 nm diode laser with different settings and modalities. Titanium discs with surfaces mimicking different dental implant surfaces including TiUnite and anodized, machined surfaces were laser-irradiated in contact and non-contact mode, and with and without airflow cooling. Settings were 0.5-2.0 W for the continuous wave mode and 10-45 μJ, 20 kHz, 5-20 μs for the pulsed wave mode. The results show that the surface characteristics have a marked influence on temperature changes in response to irradiation. The TiUnite surface, corresponding to the osseous interface of dental implants, was the most susceptible to thermal rise, while the machined surfaces, corresponding to the implant collar, were less affected. In non-contact mode and upon continuous wave emission, the temperature rose above the 50 °C tissue damage threshold. Scanning electron microscopy investigation of surface alterations revealed that laser treatment in contact mode resulted in surface scratches even when no irradiation was performed. These findings indicate that the effects of diode laser irradiation on implant surfaces depend on physical features of the titanium coating and that in order to avoid thermal or physical damage to implant surface the irradiation treatment has to be carefully selected.

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2010 CFR

2010-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2013 CFR

2013-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2011 CFR

2011-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2012 CFR

2012-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

40 CFR 270.27 - Specific Part B information requirements for air emission controls for tanks, surface...

Code of Federal Regulations, 2014 CFR

2014-07-01

... requirements for air emission controls for tanks, surface impoundments, and containers. 270.27 Section 270.27... information requirements for air emission controls for tanks, surface impoundments, and containers. (a) Except... containers that use air emission controls in accordance with the requirements of 40 CFR part 264, subpart CC...

Effects of soot-induced snow albedo change on snowpack and hydrological cycle in western United States based on Weather Research and Forecasting chemistry and regional climate simulations

NASA Astrophysics Data System (ADS)

Qian, Yun; Gustafson, William I.; Leung, L. Ruby; Ghan, Steven J.

2009-02-01

Radiative forcing induced by soot on snow is an important anthropogenic forcing affecting the global climate. In this study we simulated the deposition of soot aerosol on snow and the resulting impact on snowpack and the hydrological cycle in the western United States. A year-long simulation was performed using the chemistry version of the Weather Research and Forecasting model (WRF-Chem) to determine the soot deposition, followed by three simulations using WRF in meteorology-only mode, with and without the soot-induced snow albedo perturbations. The chemistry simulation shows large spatial variability in soot deposition that reflects the localized emissions and the influence of the complex terrain. The soot-induced snow albedo perturbations increase the surface net solar radiation flux during late winter to early spring, increase the surface air temperature, and reduce the snow accumulation and spring snowmelt. These effects are stronger over the central Rockies and southern Alberta, where soot deposition and snowpack overlap the most. The indirect forcing of soot accelerates snowmelt and alters stream flows, including a trend toward earlier melt dates in the western United States. The soot-induced albedo reduction initiates a positive feedback process whereby dirty snow absorbs more solar radiation, heating the surface and warming the air. This warming causes reduced snow depth and fraction, which further reduces the regional surface albedo for the snow-covered regions. For a doubled snow albedo perturbation, the change to surface energy and temperature is around 50-80%; however, snowpack reduction is nonlinearly accelerated.

2010-2015 methane trends over Canada, the United States, and Mexico observed by the GOSAT satellite: contributions from different source sectors

NASA Astrophysics Data System (ADS)

Sheng, J. X.; Jacob, D.; Turner, A. J.; Maasakkers, J. D.; Benmergui, J. S.; Bloom, A. A.; Arndt, C.; Gautam, R.; Zavala Araiza, D.; Hamburg, S.; Boesch, H.; Parker, R.

2017-12-01

We use six years (2010-2015) of methane column data from the GOSAT satellite to examine trends in atmospheric methane over North America and infer trends in emissions. Local methane enhancements above background are diagnosed in the GOSAT data on a 0.5°x0.5° grid by estimating the local background as the low (10th-25th) quantile of the deseasonalized frequency distributions of the data for individual years. Trends in methane enhancements on the 0.5°x0.5° grid are then aggregated nationally and for individual source sectors, using information from state-of-science bottom-up inventories, to increase statistical power. We infer that US methane emissions increased by 1.9% a-1 over the six-year period, with contributions from both oil/gas systems (possibly unconventional gas production) and from livestock in the Midwest (possibly swine production). Mexican emissions show a decrease that can be attributed to a decreasing cattle population. Canadian emissions show interannual variability driven by wetlands emissions and correlated with wetland areal extent. The US emission trends inferred from the GOSAT data are within the constraint provided by surface observations from the North American Carbon Program network.

40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2010 CFR

2010-07-01

...), manufacturer and model, and must have the same history of modifications (e.g., have the same controls installed... (or group of identical units) equipped with SCR (or SNCR) and uses dry low-NOX technology to control... with add-on NOX emission controls, and for units that use dry low-NOX technology, the owner or operator...

Allocating emissions to 4 km and 1 km horizontal spatial resolutions and its impact on simulated NOx and O3 in Houston, TX

NASA Astrophysics Data System (ADS)

Pan, Shuai; Choi, Yunsoo; Roy, Anirban; Jeon, Wonbae

2017-09-01

A WRF-SMOKE-CMAQ air quality modeling system was used to investigate the impact of horizontal spatial resolution on simulated nitrogen oxides (NOx) and ozone (O3) in the Greater Houston area (a non-attainment area for O3). We employed an approach recommended by the United States Environmental Protection Agency to allocate county-based emissions to model grid cells in 1 km and 4 km horizontal grid resolutions. The CMAQ Integrated Process Rate analyses showed a substantial difference in emissions contributions between 1 and 4 km grids but similar NOx and O3 concentrations over urban and industrial locations. For example, the peak NOx emissions at an industrial and urban site differed by a factor of 20 for the 1 km and 8 for the 4 km grid, but simulated NOx concentrations changed only by a factor of 1.2 in both cases. Hence, due to the interplay of the atmospheric processes, we cannot expect a similar level of reduction of the gas-phase air pollutants as the reduction of emissions. Both simulations reproduced the variability of NASA P-3B aircraft measurements of NOy and O3 in the lower atmosphere (from 90 m to 4.5 km). Both simulations provided similar reasonable predictions at surface, while 1 km case depicted more detailed features of emissions and concentrations in heavily polluted areas, such as highways, airports, and industrial regions, which are useful in understanding the major causes of O3 pollution in such regions, and to quantify transport of O3 to populated communities in urban areas. The Integrated Reaction Rate analyses indicated a distinctive difference of chemistry processes between the model surface layer and upper layers, implying that correcting the meteorological conditions at the surface may not help to enhance the O3 predictions. The model-observation O3 bias in our studies (e.g., large over-prediction during the nighttime or along Gulf of Mexico coastline), were due to uncertainties in meteorology, chemistry or other processes. Horizontal grid resolution is unlikely the major contributor to these biases.

40 CFR Table 30 to Subpart Uuu of... - Operating Limits for HAP Emissions From Sulfur Recovery Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Sulfur Recovery Units 30 Table 30 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 30 Table 30 to Subpart UUU of Part 63—Operating Limits for HAP Emissions From Sulfur Recovery...

The Impact of Dielectric Constant Model and Surface Reference on Differences Between SMOS and Aquarius Sea Surface Salinity

NASA Technical Reports Server (NTRS)

Dinnat, E. P.; Boutin, J.; Yin, X.; LeVine, D. M.

2014-01-01

Two ongoing space missions share the scientific objective of mapping the global Sea Surface Salinity (SSS), yet their observations show significant discrepancies. ESA's Soil Moisture and Ocean Salinity (SMOS) and NASA's Aquarius use L-band (1.4 GHz) radiometers to measure emission from the sea surface and retrieve SSS. Significant differences in SSS retrieved by both sensors are observed, with SMOS SSS being generally lower than Aquarius SSS, except for very cold waters where SMOS SSS is the highest overall. Figure 1 is an example of the difference between the SSS retrieved by SMOS and Aquarius averaged over one month and 1 degree in longitude and latitude. Differences are mostly between -1 psu and +1 psu (psu, practical salinity unit), with a significant regional and latitudinal dependence. We investigate the impact of the vicarious calibration and retrieval algorithm used by both mission on these differences.

Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

NASA Technical Reports Server (NTRS)

Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

2000-01-01

We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

Enhanced practical photosynthetic CO2 mitigation

DOEpatents

Bayless, David J.; Vis-Chiasson, Morgan L.; Kremer, Gregory G.

2003-12-23

This process is unique in photosynthetic carbon sequestration. An on-site biological sequestration system directly decreases the concentration of carbon-containing compounds in the emissions of fossil generation units. In this process, photosynthetic microbes are attached to a growth surface arranged in a containment chamber that is lit by solar photons. A harvesting system ensures maximum organism growth and rate of CO.sub.2 uptake. Soluble carbon and nitrogen concentrations delivered to the cyanobacteria are enhanced, further increasing growth rate and carbon utilization.

Monitoring Oilfield Operations and GHG Emissions Sources Using Object-based Image Analysis of High Resolution Spatial Imagery

NASA Astrophysics Data System (ADS)

Englander, J. G.; Brodrick, P. G.; Brandt, A. R.

2015-12-01

Fugitive emissions from oil and gas extraction have become a greater concern with the recent increases in development of shale hydrocarbon resources. There are significant gaps in the tools and research used to estimate fugitive emissions from oil and gas extraction. Two approaches exist for quantifying these emissions: atmospheric (or 'top down') studies, which measure methane fluxes remotely, or inventory-based ('bottom up') studies, which aggregate leakage rates on an equipment-specific basis. Bottom-up studies require counting or estimating how many devices might be leaking (called an 'activity count'), as well as how much each device might leak on average (an 'emissions factor'). In a real-world inventory, there is uncertainty in both activity counts and emissions factors. Even at the well level there are significant disagreements in data reporting. For example, some prior studies noted a ~5x difference in the number of reported well completions in the United States between EPA and private data sources. The purpose of this work is to address activity count uncertainty by using machine learning algorithms to classify oilfield surface facilities using high-resolution spatial imagery. This method can help estimate venting and fugitive emissions sources from regions where reporting of oilfield equipment is incomplete or non-existent. This work will utilize high resolution satellite imagery to count well pads in the Bakken oil field of North Dakota. This initial study examines an area of ~2,000 km2 with ~1000 well pads. We compare different machine learning classification techniques, and explore the impact of training set size, input variables, and image segmentation settings to develop efficient and robust techniques identifying well pads. We discuss the tradeoffs inherent to different classification algorithms, and determine the optimal algorithms for oilfield feature detection. In the future, the results of this work will be leveraged to be provide activity counts of oilfield surface equipment including tanks, pumpjacks, and holding ponds.

Model Estimate of Pan-Arctic Lakes and Wetlands Methane Emissions and Their Future Climate Response

NASA Astrophysics Data System (ADS)

Chen, X.; Bohn, T. J.; Maksyutov, S. S.; Lettenmaier, D. P.

2013-12-01

Lakes and wetlands are important sources of the greenhouse gas CH4, whose emission rate is sensitive to climate. The northern high latitudes, which are especially susceptible to climate change, contain about 50% of the world's lakes and wetlands. Given predicted changes in the climate of this region over the next century (IPCC AR5 scenarios), there is concern about a possible positive feedback resulting from methane emissions from the region's wetlands and lakes. To study the climate response of emissions from northern high latitude lakes and wetlands, we employed a large-scale hydrology and carbon cycling model (Variable Infiltration Capacity model; VIC) over the Pan-Arctic domain, which was linked to an atmospheric model (Japan's National Institute of Environmental Studies transport model; NIES TM). In particular, the VIC model simulates the land surface hydrology and carbon cycling across a dynamic lake-wetland continuum, while NIES TM models the atmospheric mixing and 3-dimension transport of methane emitted. The VIC model includes a distributed wetland water table scheme, which accounts for microtopography around the lakes and simulates variations in inundated area that are calibrated to match a passive microwave based inundation product. Per-unit-area carbon uptake and methane emissions at the land surface have been calibrated using extensive in situ observations at West Siberia. Also, the atmospheric methane concentration from this linked model run was verified for the recent 5 years with satellite observations from Aqua's Atmospheric Infrared Sounder (AIRS) and Envisat's Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) instruments. Using RCP4.5 and RCP8.5 future climate scenarios, we examine CH4 emissions from high latitude lakes and wetlands, as well as their net greenhouse warming potential, over the next 3 centuries across the Pan-Arctic domain. We also assess relative uncertainties in emissions from each of the sources.

Third Stokes parameter emission from a periodic water surface

NASA Technical Reports Server (NTRS)

Johnson, J. T.; Kong, J. A.; Shin, R. T.; Staelin, D. H.; Oneill, K.; Lohanick, A.

1991-01-01

An experiment in which the third Stokes parameter thermal emission from a periodic water surface was measured is documented. This parameter is shown to be related to the direction of periodicity of the periodic surface and to approach brightnesses of up to 30 K at X band for the surface used in the experiment. The surface actually analyzed was a 'two-layer' periodic surface; the theory of thermal emission from such a surface is derived and the theoretical results are found to be in good agreement with the experimental measurements. These results further the idea of using the third Stokes parameter emission as an indicator of wind direction over the ocean.

Climate change impact of livestock CH4 emission in India: Global temperature change potential (GTP) and surface temperature response.

PubMed

Kumari, Shilpi; Hiloidhari, Moonmoon; Kumari, Nisha; Naik, S N; Dahiya, R P

2018-01-01

Two climate metrics, Global surface Temperature Change Potential (GTP) and the Absolute GTP (AGTP) are used for studying the global surface temperature impact of CH 4 emission from livestock in India. The impact on global surface temperature is estimated for 20 and 100 year time frames due to CH 4 emission. The results show that the CH 4 emission from livestock, worked out to 15.3 Tg in 2012. In terms of climate metrics GTP of livestock-related CH 4 emission in India in 2012 were 1030 Tg CO 2 e (GTP 20 ) and 62 Tg CO 2 e (GTP 100 ) at the 20 and 100 year time horizon, respectively. The study also illustrates that livestock-related CH 4 emissions in India can cause a surface temperature increase of up to 0.7mK and 0.036mK over the 20 and 100 year time periods, respectively. The surface temperature response to a year of Indian livestock emission peaks at 0.9mK in the year 2021 (9 years after the time of emission). The AGTP gives important information in terms of temperature change due to annual CH 4 emissions, which is useful when comparing policies that address multiple gases. Copyright © 2017 Elsevier Inc. All rights reserved.

Inventory of methane emissions from U.S. cattle

NASA Astrophysics Data System (ADS)

Westberg, H.; Lamb, B.; Johnson, K. A.; Huyler, M.

2001-01-01

Many countries, including the United States, are in the process of inventorying greenhouse gas emissions as a prerequisite for designing control strategies. We have developed a measurement-based inventory of methane emissions from cattle in the United States. Methane emission factors were established for the major livestock groups using an internal tracer method. The groups studied included cows, replacement heifers, slaughter cattle, calves, and bulls in the beef sector and cows plus replacement heifers in the dairy industry. Since methane emission is dependent on the quality and quantity of feed, diets were chosen that are representative of the feed regimes utilized by producers in the United States. Regional cattle populations, obtained from U.S. Department of Agriculture statistics, were combined with the methane emission factors to yield regional emission estimates. The methane totals from the five regions were then summed to give a U.S. inventory of cattle emissions for 1990, 1992, 1994, 1996, and 1998. Annual releases ranged from 6.50 Tg in 1990 to a high of 6.98 Tg in 1996. On a regional scale the North Central region of the United States had the largest methane emissions from livestock followed by the South Central and the West. The beef cow group released the most methane (˜2.5 Tg yr-1) followed by slaughter cattle (˜1.7 Tg yr-1) and dairy cows at about 1.5 Tg yr-1. Methane released by cattle in the United States contributes about 11% of the global cattle source.

Generation of single attosecond pulse within one atomic unit by using multi-cycle inhomogeneous polarization gating technology in bowtie-shaped nanostructure

NASA Astrophysics Data System (ADS)

Feng, Liqiang; Liu, Hang

2018-04-01

The generations of high-order harmonic spectra and single attosecond pulses (SAPs) driven by the multi-cycle inhomogeneous polarization gating (PG) technology in the bowtie-shaped nanostructure have been theoretically investigated. It is found that by setting the bowtie-shaped nanostructure along the driven laser polarization direction, not only the extension of the harmonic cutoff can be achieved, caused by the surface plasmon polaritons, but also the modulations of the harmonics can be decreased, caused by the PG technology and the inhomogeneous effect. As a result, the contribution of the harmonic plateau is only from one harmonic emission peak with the dominant short quantum path. Further, by properly adding a half-cycle pulse into the driven laser field, the harmonic emission process can be precisely controlled in the half-cycle duration and a supercontinuum with the bandwidth of 263 eV can be obtained. Finally, by directly superposing the harmonics from this supercontinuum, a SAP with the full width at half maximum of 23 as can be obtained, which is shorter than one atomic unit.

Derived Land Surface Emissivity From Suomi NPP CrIS

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu

2012-01-01

Presented here is the land surface IR spectral emissivity retrieved from the Cross-track Infrared Sounder (CrIS) measurements. The CrIS is aboard the Suomi National Polar-orbiting Partnership (NPP) satellite launched on October 28, 2011. We describe the retrieval algorithm, demonstrate the surface emissivity retrieved with CrIS measurements, and inter-comparison with the Infrared Atmospheric Sounding Interferometer (IASI) emissivity. We also demonstrate that surface emissivity from satellite measurements can be used in assistance of monitoring global surface climate change, as a long-term measurement of IASI and CrIS will be provided by the series of EUMETSAT MetOp and US Joint Polar Satellite System (JPSS) satellites. Monthly mean surface properties are produced using last 5-year IASI measurements. A temporal variation indicates seasonal diversity and El Nino/La Nina effects not only shown on the water but also on the land. Surface spectral emissivity and skin temperature from current and future operational satellites can be utilized as a means of long-term monitoring of the Earth's environment. CrIS spectral emissivity are retrieved and compared with IASI. The difference is small and could be within expected retrieval error; however it is under investigation.

Quantitative Surface Emissivity and Temperature Measurements of a Burning Solid Fuel Accompanied by Soot Formation

NASA Technical Reports Server (NTRS)

Piltch, Nancy D.; Pettegrew, Richard D.; Ferkul, Paul; Sacksteder, K. (Technical Monitor)

2001-01-01

Surface radiometry is an established technique for noncontact temperature measurement of solids. We adapt this technique to the study of solid surface combustion where the solid fuel undergoes physical and chemical changes as pyrolysis proceeds, and additionally may produce soot. The physical and chemical changes alter the fuel surface emissivity, and soot contributes to the infrared signature in the same spectral band as the signal of interest. We have developed a measurement that isolates the fuel's surface emissions in the presence of soot, and determine the surface emissivity as a function of temperature. A commercially available infrared camera images the two-dimensional surface of ashless filter paper burning in concurrent flow. The camera is sensitive in the 2 to 5 gm band, but spectrally filtered to reduce the interference from hot gas phase combustion products. Results show a strong functional dependence of emissivity on temperature, attributed to the combined effects of thermal and oxidative processes. Using the measured emissivity, radiance measurements from several burning samples were corrected for the presence of soot and for changes in emissivity, to yield quantitative surface temperature measurements. Ultimately the results will be used to develop a full-field, non-contact temperature measurement that will be used in spacebased combustion investigations.

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... the boiler at a normal or conservatively high excess oxygen level in conjunction with these tests....2Substitute 1.25 times the highest NOX emission rate from the baseline correlation tests for the fuel (or fuel... potential NOX emission rate (MER) (as defined in § 72.2 of this chapter) for each unit operating hour...

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... the boiler at a normal or conservatively high excess oxygen level in conjunction with these tests....2Substitute 1.25 times the highest NOX emission rate from the baseline correlation tests for the fuel (or fuel... potential NOX emission rate (MER) (as defined in § 72.2 of this chapter) for each unit operating hour...

Factors influencing CO2 and CH4 emissions from coastal wetlands in the Liaohe Delta, Northeast China

NASA Astrophysics Data System (ADS)

Olsson, L.; Ye, S.; Yu, X.; Wei, M.; Krauss, K. W.; Brix, H.

2015-08-01

Many factors are known to influence greenhouse gas emissions from coastal wetlands, but it is still unclear which factors are most important under field conditions when they are all acting simultaneously. The objective of this study was to assess the effects of water table, salinity, soil temperature and vegetation on CH4 emissions and ecosystem respiration (Reco) from five coastal wetlands in the Liaohe Delta, Northeast China: two Phragmites australis (common reed) wetlands, two Suaeda salsa (sea blite) marshes and a rice (Oryza sativa) paddy. Throughout the growing season, the Suaeda wetlands were net CH4 sinks whereas the Phragmites wetlands and the rice paddy were net CH4 sources emitting 1.2-6.1 g CH4 m-2 yr-1. The Phragmites wetlands emitted the most CH4 per unit area and the most CH4 relative to CO2. The main controlling factors for the CH4 emissions were water table, temperature, soil organic carbon and salinity. The CH4 emission was accelerated at high and constant (or managed) water tables and decreased at water tables below the soil surface. High temperatures enhanced CH4 emissions, and emission rates were consistently low (< 1 mg CH4 m-2 h-1) at soil temperatures < 18 °C. At salinity levels > 18 ppt, the CH4 emission rates were always low (< 1 mg CH4 m-2 h-1) probably because methanogens were out-competed by sulphate-reducing bacteria. Saline Phragmites wetlands can, however, emit significant amounts of CH4 as CH4 produced in deep soil layers are transported through the air-space tissue of the plants to the atmosphere. The CH4 emission from coastal wetlands can be reduced by creating fluctuating water tables, including water tables below the soil surface, as well as by occasional flooding by high-salinity water. The effects of water management schemes on the biological communities in the wetlands must, however, be carefully studied prior to the management in order to avoid undesirable effects on the wetland communities.

Factors influencing CO2 and CH4 emissions from coastal wetlands in the Liaohe Delta, Northeast China

NASA Astrophysics Data System (ADS)

Olsson, L.; Ye, S.; Yu, X.; Wei, M.; Krauss, K. W.; Brix, H.

2015-02-01

Many factors are known to influence greenhouse gas emissions from coastal wetlands, but it is still unclear which factors are most important under field conditions when they are all acting simultaneously. The objective of this study was to assess the effects of water table, salinity, soil temperature and vegetation on CH4 emissions and ecosystem respiration (Reco) from five coastal wetlands in the Liaohe Delta, northeast China: two Phragmites australis (common reed) wetlands, two Suaeda salsa (sea blite) marshes and a rice (Oryza sativa) paddy. Throughout the growing season, the Suaeda wetlands were net CH4 sinks whereas the Phragmites wetlands and the rice paddy were net CH4 sources emitting 1.2-6.1 g CH4 m-2 y-1. The Phragmites wetlands emitted the most CH4 per unit area and the most CH4 relative to CO2. The main controlling factors for the CH4 emissions were water table, temperature and salinity. The CH4 emission was accelerated at high and constant (or managed) water tables and decreased at water tables below the soil surface. High temperatures enhanced CH4 emissions, and emission rates were consistently low (< 1 mg CH4 m-2 h) at soil temperatures <18 °C. At salinity levels > 18 ppt, the CH4 emission rates were always low (< 1 mg CH4 m-2 h-1) probably because methanogens were outcompeted by sulphate reducing bacteria. Saline Phragmites wetlands can, however, emit significant amounts of CH4 as CH4 produced in deep soil layers are transported through the air-space tissue of the plants to the atmosphere. The CH4 emission from coastal wetlands can be reduced by creating fluctuating water tables, including water tables below the soil surface, as well as by occasional flooding by high-salinity water. The effects of water management schemes on the biological communities in the wetlands must, however, be carefully studied prior to the management in order to avoid undesirable effects on the wetland communities.

Mercury emission estimates from fires: an initial inventory for the United States.

PubMed

Wiedinmyer, Christine; Friedli, Hans

2007-12-01

Recent studies have shown that emissions of mercury (Hg), a hazardous air pollutant, from fires can be significant. However, to date, these emissions have not been well-quantified for the entire United States. Daily emissions of Hg from fires in the lower 48 states of the United States (LOWER48) and in Alaska were estimated for 2002-2006 using a simple fire emissions model. Emission factors of Hg from fires in different ecosystems were compiled from published plume studies and from soil-based assessments. Annual averaged emissions of Hg from fires in the LOWER48 and Alaska were 44 (20-65) metric tons yr(-1), equivalent to approximately 30% of the U.S. EPA 2002 National Emissions Inventory for Hg. Alaska had the highest averaged monthly emissions of all states; however, the emissions have a high temporal variability. Emissions from forests dominate the inventory, suggesting that Hg emissions from agricultural fires are not significant on an annual basis. The uncertainty in the Hg emission factors due to limited data leads to an uncertainty in the emission estimates on the order of +/-50%. Research is still needed to better constrain Hg emission factors from fires, particularly in the eastern U.S. and for ecosystems other than forests.

40 CFR 265.1035 - Recordkeeping requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... waste management units in one recordkeeping system if the system identifies each record by each... data supporting determinations of vent emissions and emission reductions achieved by add-on control... that result in maximum organic emissions, such as when the waste management unit is operating at the...

Compression and ablation of the photo-irradiated molecular cloud the Orion Bar.

PubMed

Goicoechea, Javier R; Pety, Jérôme; Cuadrado, Sara; Cernicharo, José; Chapillon, Edwige; Fuente, Asunción; Gerin, Maryvonne; Joblin, Christine; Marcelino, Nuria; Pilleri, Paolo

2016-09-08

The Orion Bar is the archetypal edge-on molecular cloud surface illuminated by strong ultraviolet radiation from nearby massive stars. Our relative closeness to the Orion nebula (about 1,350 light years away from Earth) means that we can study the effects of stellar feedback on the parental cloud in detail. Visible-light observations of the Orion Bar show that the transition between the hot ionized gas and the warm neutral atomic gas (the ionization front) is spatially well separated from the transition between atomic and molecular gas (the dissociation front), by about 15 arcseconds or 6,200 astronomical units (one astronomical unit is the Earth-Sun distance). Static equilibrium models used to interpret previous far-infrared and radio observations of the neutral gas in the Orion Bar (typically at 10-20 arcsecond resolution) predict an inhomogeneous cloud structure comprised of dense clumps embedded in a lower-density extended gas component. Here we report one-arcsecond-resolution millimetre-wave images that allow us to resolve the molecular cloud surface. In contrast to stationary model predictions, there is no appreciable offset between the peak of the H 2 vibrational emission (delineating the H/H 2 transition) and the edge of the observed CO and HCO + emission. This implies that the H/H 2 and C + /C/CO transition zones are very close. We find a fragmented ridge of high-density substructures, photoablative gas flows and instabilities at the molecular cloud surface. The results suggest that the cloud edge has been compressed by a high-pressure wave that is moving into the molecular cloud, demonstrating that dynamical and non-equilibrium effects are important for the cloud evolution.

Compression and ablation of the photo-irradiated molecular cloud the Orion Bar

NASA Astrophysics Data System (ADS)

Goicoechea, Javier R.; Pety, Jérôme; Cuadrado, Sara; Cernicharo, José; Chapillon, Edwige; Fuente, Asunción; Gerin, Maryvonne; Joblin, Christine; Marcelino, Nuria; Pilleri, Paolo

2016-09-01

The Orion Bar is the archetypal edge-on molecular cloud surface illuminated by strong ultraviolet radiation from nearby massive stars. Our relative closeness to the Orion nebula (about 1,350 light years away from Earth) means that we can study the effects of stellar feedback on the parental cloud in detail. Visible-light observations of the Orion Bar show that the transition between the hot ionized gas and the warm neutral atomic gas (the ionization front) is spatially well separated from the transition between atomic and molecular gas (the dissociation front), by about 15 arcseconds or 6,200 astronomical units (one astronomical unit is the Earth-Sun distance). Static equilibrium models used to interpret previous far-infrared and radio observations of the neutral gas in the Orion Bar (typically at 10-20 arcsecond resolution) predict an inhomogeneous cloud structure comprised of dense clumps embedded in a lower-density extended gas component. Here we report one-arcsecond-resolution millimetre-wave images that allow us to resolve the molecular cloud surface. In contrast to stationary model predictions, there is no appreciable offset between the peak of the H2 vibrational emission (delineating the H/H2 transition) and the edge of the observed CO and HCO+ emission. This implies that the H/H2 and C+/C/CO transition zones are very close. We find a fragmented ridge of high-density substructures, photoablative gas flows and instabilities at the molecular cloud surface. The results suggest that the cloud edge has been compressed by a high-pressure wave that is moving into the molecular cloud, demonstrating that dynamical and non-equilibrium effects are important for the cloud evolution.

Emissions implications of downscaled electricity generation scenarios for the western United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nsanzineza, Rene; O’Connell, Matthew; Brinkman, Gregory

This study explores how emissions from electricity generation in the Western Interconnection region of the U.S. might respond in circa 2030 to contrasting scenarios for fuel prices and greenhouse gas (GHG) emissions fees. We examine spatial and temporal variations in generation mix across the region and year using the PLEXOS unit commitment and dispatch model with a production cost model database adapted from the Western Electricity Coordinating Council. Emissions estimates are computed by combining the dispatch model results with unit-specific, emissions-load relationships. Wind energy displaces natural gas and coal in scenarios with relatively expensive natural gas or with GHG fees.more » Correspondingly, annual emissions of NOx, SO2, and CO2 are reduced by 20-40% in these cases. NOx emissions, which are a concern as a precursor of ground-level ozone, are relatively high and consistent across scenarios during summer, when peak electricity loads occur and wind resources in the region are comparatively weak. Accounting for the difference in start-up versus stabilized NOx emissions rates for natural gas plants had little impact on region-wide emissions estimates due to the dominant contribution from coal-fired plants, but would be more important in the vicinity of the natural gas units.« less

Detection of CN Emission from (2060) Chiron.

PubMed

Bus, S J; A'hearn, M F; Schleicher, D G; Bowell, E

1991-02-15

In the past decade there has been a gradual, but substantial change in our understanding of the physical nature of (2060) Chiron. Once thought to be the first known member of a population of asteroids orbiting between Saturn and Uranus, Chiron is now generally regarded as the largest known comet. The detection of CN emission in the spectrum of Chiron is reported. Not only do these observations underscore the cometary nature of Chiron, but, at a heliocentric distance exceeding 11 astronomical units, represent the most distant detection yet of a neutral gas species common in comets. These results are consistent with the outgassing from Chiron being primarily driven by isolated outbursts of CO(2) from a very small fraction of Chiron's surface. These may be indicative of primordial inhomogeneities.

Year-round CH4 and CO2 flux dynamics in two contrasting freshwater ecosystems of the subarctic

NASA Astrophysics Data System (ADS)

Jammet, Mathilde; Dengel, Sigrid; Kettner, Ernesto; Parmentier, Frans-Jan W.; Wik, Martin; Crill, Patrick; Friborg, Thomas

2017-11-01

Lakes and wetlands, common ecosystems of the high northern latitudes, exchange large amounts of the climate-forcing gases methane (CH4) and carbon dioxide (CO2) with the atmosphere. The magnitudes of these fluxes and the processes driving them are still uncertain, particularly for subarctic and Arctic lakes where direct measurements of CH4 and CO2 emissions are often of low temporal resolution and are rarely sustained throughout the entire year. Using the eddy covariance method, we measured surface-atmosphere exchange of CH4 and CO2 during 2.5 years in a thawed fen and a shallow lake of a subarctic peatland complex. Gas exchange at the fen exhibited the expected seasonality of a subarctic wetland with maximum CH4 emissions and CO2 uptake in summer, as well as low but continuous emissions of CH4 and CO2 throughout the snow-covered winter. The seasonality of lake fluxes differed, with maximum CO2 and CH4 flux rates recorded at spring thaw. During the ice-free seasons, we could identify surface CH4 emissions as mostly ebullition events with a seasonal trend in the magnitude of the release, while a net CO2 flux indicated photosynthetic activity. We found correlations between surface CH4 emissions and surface sediment temperature, as well as between diel CO2 uptake and diel solar input. During spring, the breakdown of thermal stratification following ice thaw triggered the degassing of both CH4 and CO2. This spring burst was observed in 2 consecutive years for both gases, with a large inter-annual variability in the magnitude of the CH4 degassing. On the annual scale, spring emissions converted the lake from a small CO2 sink to a CO2 source: 80 % of total annual carbon emissions from the lake were emitted as CO2. The annual total carbon exchange per unit area was highest at the fen, which was an annual sink of carbon with respect to the atmosphere. Continuous respiration during the winter partly counteracted the fen summer sink by accounting for, as both CH4 and CO2, 33 % of annual carbon exchange. Our study shows (1) the importance of overturn periods (spring or fall) for the annual CH4 and CO2 emissions of northern lakes, (2) the significance of lakes as atmospheric carbon sources in subarctic landscapes while fens can be a strong carbon sink, and (3) the potential for ecosystem-scale eddy covariance measurements to improve the understanding of short-term processes driving lake-atmosphere exchange of CH4 and CO2.

40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

Impacts of seasonal and regional variability in biogenic VOC emissions on surface ozone in the Pearl River Delta region, China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Situ, S.; Guenther, Alex B.; Wang, X. J.

In this study, the BVOC emissions in November 2010 over the Pearl River Delta (PRD) region in southern China have been estimated by the latest version of a Biogenic Volatile Organic Compound (BVOC) emission model (MEGAN v2.1). The evaluation of MEGAN performance at a representative forest site within this region indicates MEGAN can estimate BVOC emissions reasonably well in this region except overestimating isoprene emission in autumn for reasons that are discussed in this manuscript. Along with the output from MEGAN, the Weather Research and Forecasting model with chemistry (WRF-Chem) is used to estimate the impacts of BVOC emissions onmore » surface ozone in the PRD region. The results show BVOC emissions increase the daytime ozone peak by *3 ppb on average, and the max hourly impacts of BVOC emissions on the daytime ozone peak is 24.8 ppb. Surface ozone mixing ratios in the central area of Guangzhou- Foshan and the western Jiangmen are most sensitive to BVOC emissions BVOCs from outside and central PRD influence the central area of Guangzhou-Foshan and the western Jiangmen significantly while BVOCs from rural PRD mainly influence the western Jiangmen. The impacts of BVOC emissions on surface ozone differ in different PRD cities, and the impact varies in different seasons. Foshan and Jiangmen being most affected in autumn, result in 6.0 ppb and 5.5 ppb increases in surface ozone concentrations, while Guangzhou and Huizhou become more affected in summer. Three additional experiments concerning the sensitivity of surface ozone to MEGAN input variables show that surface ozone is more sensitive to landcover change, followed by emission factors and meteorology.« less

Quantification of surface emissions: An historical perspective from GEIA

NASA Astrophysics Data System (ADS)

Granier, C.; Denier Van Der Gon, H.; Doumbia, E. H. T.; Frost, G. J.; Guenther, A. B.; Hassler, B.; Janssens-Maenhout, G. G. A.; Lasslop, G.; Melamed, M. L.; Middleton, P.; Sindelarova, K.; Tarrason, L.; van Marle, M.; W Kaiser, J.; van der Werf, G.

2015-12-01

Assessments of the composition of the atmosphere and its evolution require accurate knowledge of the surface emissions of atmospheric compounds. The first community development of global surface emissions started in 1990, when GEIA was established as a component of the International Global Atmospheric Chemistry (IGAC) project. At that time, GEIA meant "Global Emissions Inventory Activity". Since its inception, GEIA has brought together people to understand emissions from anthropogenic, biomass burning and natural sources. The first goal of GEIA was to establish a "best" inventory for the base year 1985 at 1x1 degree resolution. Since then many inventories have been developed by various groups at the global and regional scale at different temporal and spatial resolutions. GEIA, which now means the "Global Emissions Initiative", has evolved into assessing, harmonizing and distributing emissions datasets. We will review the main achievements of GEIA, and show how the development and evaluation of surface emissions has evolved during the last 25 years. We will discuss the use of surface, in-situ and remote sensing observations to evaluate and improve the quantification of emissions. We will highlight the main uncertainties currently limiting emissions datasets, such as the spatial and temporal evolution of emissions at different resolutions, the quantification of emerging emission sources (such as oil/gas extraction and distribution, biofuels, etc.), the speciation of the emissions of volatile organic compounds and of particulate matter, the capacity building necessary for organizing the development of regional emissions across the world, emissions from shipping, etc. We will present the ECCAD (Emissions of Atmospheric Compounds and Compilation of Ancillary Data) database, developed as part of GEIA to facilitate the access and evaluation of emission inventories.

Ecological controls on N2O emission in surface litter and near-surface soil of a managed grassland: modelling and measurements

NASA Astrophysics Data System (ADS)

Grant, Robert F.; Neftel, Albrecht; Calanca, Pierluigi

2016-06-01

Large variability in N2O emissions from managed grasslands may occur because most emissions originate in surface litter or near-surface soil where variability in soil water content (θ) and temperature (Ts) is greatest. To determine whether temporal variability in θ and Ts of surface litter and near-surface soil could explain this in N2O emissions, a simulation experiment was conducted with ecosys, a comprehensive mathematical model of terrestrial ecosystems in which processes governing N2O emissions were represented at high temporal and spatial resolution. Model performance was verified by comparing N2O emissions, CO2 and energy exchange, and θ and Ts modelled by ecosys with those measured by automated chambers, eddy covariance (EC) and soil sensors on an hourly timescale during several emission events from 2004 to 2009 in an intensively managed pasture at Oensingen, Switzerland. Both modelled and measured events were induced by precipitation following harvesting and subsequent fertilizing or manuring. These events were brief (2-5 days) with maximum N2O effluxes that varied from < 1 mgNm-2h-1 in early spring and autumn to > 3 mgNm-2h-1 in summer. Only very small emissions were modelled or measured outside these events. In the model, emissions were generated almost entirely in surface litter or near-surface (0-2 cm) soil, at rates driven by N availability with fertilization vs. N uptake with grassland regrowth and by O2 supply controlled by litter and soil wetting relative to O2 demand from microbial respiration. In the model, NOx availability relative to O2 limitation governed both the reduction of more oxidized electron acceptors to N2O and the reduction of N2O to N2, so that the magnitude of N2O emissions was not simply related to surface and near-surface θ and Ts. Modelled N2O emissions were found to be sensitive to defoliation intensity and timing which controlled plant N uptake and soil θ and Ts prior to and during emission events. Reducing leaf area index (LAI) remaining after defoliation to half that under current practice and delaying harvesting by 5 days raised modelled N2O emissions by as much as 80 % during subsequent events and by an average of 43 % annually. Modelled N2O emissions were also found to be sensitive to surface soil properties. Increasing near-surface bulk density by 10 % raised N2O emissions by as much as 100 % during emission events and by an average of 23 % annually. Relatively small spatial variation in management practices and soil surface properties could therefore cause the large spatial variation in N2O emissions commonly found in field studies. The global warming potential from annual N2O emissions in this intensively managed grassland largely offset those from net C uptake in both modelled and field experiments. However, model results indicated that this offset could be adversely affected by suboptimal land management and soil properties.

Multiwavelength pyrometer for gray and non-gray surfaces in the presence of interfering radiation

NASA Technical Reports Server (NTRS)

Ng, Daniel L. P. (Inventor)

1994-01-01

A method and apparatus for detecting the temperature of gray and non-gray bodies in the presence of interfering radiation are presented. A gray body has a constant emissivity less than 1 and a non-gray body has an emissivity which varies with wavelength. The emissivity and reflectivity of the surface is determined over a range of wavelengths. Spectra are also measured of the extraneous interference radiation source and the surface of the object to be measured in the presence of the extraneous interference radiation source. An auxiliary radiation source is used to determine the reflectivity of the surface and also the emissivity. The measured spectrum of the surfaces in the presence of the extraneous interference radiation source is set equal to the emissivity of the surface multiplied by a Planck function containing a temperature term T plus the surface reflectivity multiplied by the spectrum of the extraneous interference radiation source. The equation is then solved for T to determine the temperature of the surface.

Control of formaldehyde and TVOC emission from wood-based flooring composites at various manufacturing processes by surface finishing.

PubMed

Kim, Sumin

2010-04-15

This paper assesses the reproducibility of testing formaldehyde and TVOC emission behavior from wood flooring composites bonded by urea-formaldehyde resin at various manufacturing steps for surface finishing materials. The surface adhesion step of laminate flooring for this research was divided into two steps; HDF only and HDF with LPMs. In the case of engineered flooring, the manufacturing steps were divided into three steps; plywood only, fancy veneer bonded on plywood and UV coated on fancy veneer with plywood. Formaldehyde and VOCs emission decreased at the process of final surface finishing materials; LPMs were applied on the surface of HDF for laminate flooring. Although emissions increased when fancy veneer was bonded onto plywood in the case of engineered flooring, emission was dramatically reduced up to similar level with plywood only when final surface finishing; UV-curable coating was applied on fancy veneer. This study suggests that formaldehyde and VOCs emission from floorings can be controlled at manufacturing steps for surface finishing. 2009 Elsevier B.V. All rights reserved.

An assessment of the land surface emissivity in the 8 - 12 micrometer window determined from ASTER and MODIS data

NASA Astrophysics Data System (ADS)

Schmugge, T.; Hulley, G.; Hook, S.

2009-04-01

The land surface emissivity is often overlooked when considering surface properties that effect the energy balance. However, knowledge of the emissivity in the window region is important for determining the longwave radiation balance and its subsequent effect on surface temperature. The net longwave radiation (NLR) is strongly affected by the difference between the temperature of the emitting surface and the sky brightness temperature, this difference will be the greatest in the window region. Outside the window region any changes in the emitted radiation by emissivity variability are mostly compensated for by changes in the reflected sky brightness. The emissivity variability is typically greatest in arid regions where the exposed soil and rock surfaces display the widest range of emissivity. For example, the dune regions of North Africa have emissivities of 0.7 or less in the 8 to 9 micrometer wavelength band due to the quartz sands of the region, which can produce changes in NLR of more than 10 w/m*m compared to assuming a constant emissivity. The errors in retrievals of atmospheric temperature and moisture profiles from hyperspectral infrared radiances, such as those from the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite result from using constant or inaccurate surface emissivities, particularly over arid and semi-arid regions here the variation in emissivity is large, both spatially and spectrally. The multispectral thermal infrared data obtained from the Advanced Spaceborne Thermal Emission and Reflection (ASTER) radiometer and MODerate resolution Imaging Spectrometer (MODIS) sensors on NASA's Terra satellite have been shown to be of good quality and provide a unique new tool for studying the emissivity of the land surface. ASTER has 5 channels in the 8 to 12 micrometer waveband with 90 m spatial resolution, when the data are combined with the Temperature Emissivity Separation (TES) algorithm the surface emissivity over this wavelength region can be determined. The TES algorithm has been validated with field measurements using a multi-spectral radiometer having similar bands to ASTER. The ASTER data have now been used to produce a seasonal gridded database of the emissivity for North America and the results compared to laboratory measured emissivities of in-situ rock/sand samples collected at ten validation sites in the Western USA during 2008. The directional hemispherical reflectance of the in-situ samples are measured in the laboratory using a Nicolet Fourier Transform Interferometer (FTIR), converted to emissivity using Kirchoff's law, and convolving to the appropriate sensor spectral response functions. This ASTER database, termed the North American ASTER Land Surface Emissivity Database (NAALSED), was validated using the laboratory results from these ten sites to within 0.015 (1.5%) in emissivity. MODIS has 3 channels in this waveband with 1km spatial resolution and almost daily global coverage. The MODIS data are composited to 5 km resolution and day night pairs of observations are used to derive the emissivities. These results have been validated using the ASTER emissivities over selected test areas.

Directional emissivity from two-dimensional infrared waveguide arrays

NASA Astrophysics Data System (ADS)

Burckel, D. Bruce; Davids, Paul S.; Finnegan, Patrick S.; Figueiredo, Pedro N.; Ginn, James C.

2015-09-01

Fabrication and optical characterization of surfaces covered with open-ended metallic waveguides are presented along with numerical modeling of these structures. Both modeling and measurement of the structures indicate that the 2-D array of 3D metallic waveguides modify both the direction and spectral content of the emissivity, resulting in directionality normal to the surface due to the optical axis of the waveguides and spectrally narrow emissivity due to the lateral dimensions of the waveguides. Furthermore, the optical behavior of these structures is placed in the broader context of other structured emission/absorption surfaces such as organ pipe modes, surface plasmon modes, and coherent thermal emission from gratings.

Electron reflection and secondary emission characteristics of sputter-textured pyrolytic graphite surfaces

NASA Technical Reports Server (NTRS)

Wintucky, E. G.; Curren, A. N.; Sovey, J. S.

1981-01-01

Low secondary and reflected primary electron emission from the collector electrode surfaces is important for optimum collector efficiency and hence for high overall efficiency of microwave amplifier tubes used in communication satellites and in military systems. Ion sputter texturing of the surface effectively suppresses electron emission from pyrolytic graphite, which is a promising collector electrode material. Secondary and reflected primary electron emission characteristics of sputter textured pyrolytic graphite surfaces with microstructures of various sizes and densities are presented. The microstructure with the lowest electron emission levels, less than those of soot, consists of a dense array of tall, thin spires.

MODULATING EMISSIONS FROM ELECTRIC GENERATING UNITS AS A FUNCTION OF METEOROLOGICAL VARIABLES

EPA Science Inventory

Electric Generating Units (EGUs) are an important source of emissions of nitrogen oxides (NOx), which react with volatile organic compounds (VOCs) in the presence of sunlight to form ozone. Emissions from EGUs are believed to vary depending on short-term demands for electricity;...

LINKING REGIONAL AEROSOL EMISSION CHANGES WITH MULTIPLE IMPACT MEASURES THROUGH DIRECT AND CLOUD-RELATED FORCING ESTIMATES

EPA Science Inventory

Outputs expected from this project include improved confidence in direct radiative forcing and cloud radiative forcing, particularly over the United States and with regard to United States emissions publicly available, documented data sets including emission inventories of siz...

Aerosol direct, indirect, semidirect, and surface albedo effects from sector contributions based on the IPCC AR5 emissions for preindustrial and present-day conditions

NASA Astrophysics Data System (ADS)

Bauer, Susanne E.; Menon, Surabi

2012-01-01

The anthropogenic increase in aerosol concentrations since preindustrial times and its net cooling effect on the atmosphere is thought to mask some of the greenhouse gas-induced warming. Although the overall effect of aerosols on solar radiation and clouds is most certainly negative, some individual forcing agents and feedbacks have positive forcing effects. Recent studies have tried to identify some of those positive forcing agents and their individual emission sectors, with the hope that mitigation policies could be developed to target those emitters. Understanding the net effect of multisource emitting sectors and the involved cloud feedbacks is very challenging, and this paper will clarify forcing and feedback effects by separating direct, indirect, semidirect and surface albedo effects due to aerosols. To this end, we apply the Goddard Institute for Space Studies climate model including detailed aerosol microphysics to examine aerosol impacts on climate by isolating single emission sector contributions as given by the Coupled Model Intercomparison Project Phase 5 (CMIP5) emission data sets developed for Intergovernmental Panel on Climate Change (IPCC) AR5. For the modeled past 150 years, using the climate model and emissions from preindustrial times to present-day, the total global annual mean aerosol radiative forcing is -0.6 W/m2, with the largest contribution from the direct effect (-0.5 W/m2). Aerosol-induced changes on cloud cover often depends on cloud type and geographical region. The indirect (includes only the cloud albedo effect with -0.17 W/m2) and semidirect effects (-0.10 W/m2) can be isolated on a regional scale, and they often have opposing forcing effects, leading to overall small forcing effects on a global scale. Although the surface albedo effects from aerosols are small (0.016 W/m2), triggered feedbacks on top of the atmosphere (TOA) radiative forcing can be 10 times larger. Our results point out that each emission sector has varying impacts by geographical region. For example, the single sector most responsible for a net positive radiative forcing is the transportation sector in the United States, agricultural burning and transportation in Europe, and the domestic emission sector in Asia. These sectors are attractive mitigation targets.

Aerosol Direct, Indirect, Semidirect, and Surface Albedo Effects from Sector Contributions Based on the IPCC AR5 Emissions for Preindustrial and Present-day Conditions

NASA Technical Reports Server (NTRS)

Bauer, Susanne E.; Menon, Surabi

2012-01-01

The anthropogenic increase in aerosol concentrations since preindustrial times and its net cooling effect on the atmosphere is thought to mask some of the greenhouse gas-induced warming. Although the overall effect of aerosols on solar radiation and clouds is most certainly negative, some individual forcing agents and feedbacks have positive forcing effects. Recent studies have tried to identify some of those positive forcing agents and their individual emission sectors, with the hope that mitigation policies could be developed to target those emitters. Understanding the net effect of multisource emitting sectors and the involved cloud feedbacks is very challenging, and this paper will clarify forcing and feedback effects by separating direct, indirect, semidirect and surface albedo effects due to aerosols. To this end, we apply the Goddard Institute for Space Studies climate model including detailed aerosol microphysics to examine aerosol impacts on climate by isolating single emission sector contributions as given by the Coupled Model Intercomparison Project Phase 5 (CMIP5) emission data sets developed for Intergovernmental Panel on Climate Change (IPCC) AR5. For the modeled past 150 years, using the climate model and emissions from preindustrial times to present-day, the total global annual mean aerosol radiative forcing is -0.6 W/m(exp 2), with the largest contribution from the direct effect (-0.5 W/m(exp 2)). Aerosol-induced changes on cloud cover often depends on cloud type and geographical region. The indirect (includes only the cloud albedo effect with -0.17 W/m(exp 2)) and semidirect effects (-0.10 W/m(exp 2)) can be isolated on a regional scale, and they often have opposing forcing effects, leading to overall small forcing effects on a global scale. Although the surface albedo effects from aerosols are small (0.016 W/m(exp 2)), triggered feedbacks on top of the atmosphere (TOA) radiative forcing can be 10 times larger. Our results point out that each emission sector has varying impacts by geographical region. For example, the single sector most responsible for a net positive radiative forcing is the transportation sector in the United States, agricultural burning and transportation in Europe, and the domestic emission sector in Asia. These sectors are attractive mitigation targets.

Wexler's Great Smoke Pall: a chemistry-climate model analysis of a singularly large emissions pulse

NASA Astrophysics Data System (ADS)

Field, R. D.; Voulgarakis, A.

2011-12-01

We model the effects of the smoke plume from what was arguably the largest forest fire in recorded history. The Chinchaga fire burned continuously during the summer of 1950 in northwestern Canada during a very dry fire season. On September 22nd, the fire made a major advance, burning an area of approximately 1400 km2. Ground and aircraft observations showed that from September 22 to 28, the smoke plume from the emissions pulse travelled over northern Canada, southward over the Great Lakes region and eastern US, across the Atlantic, and to Western Europe. Over the Great Lakes region, the plume remained thick enough to create twilight conditions in the mid-afternoon, and was estimated to have caused a 4 oC cooling at the surface. While many instances of long-range transport of wildfire emissions have been detected over the past decade, we know of no other wildfire which created such an acute effect on downward shortwave radiation at such a long distance. As a result, the fire was an important analogue event used in estimating the effects of a nuclear winter. Simulations with the nudged version of the GISS chemistry-climate model accurately capture the long-range transport pattern of the smoke emissions in the free-troposphere. The timing and location of aircraft observations of the plume over the eastern US, North Atlantic and the United Kingdom were well-matched to modeled anomalies of CO and aerosol optical depth. Further work will examine the model's ability to create twilight conditions during the day, and to provide an estimate of the consequent cooling effects at the surface from this remarkable emissions pulse.

Estimating Western U.S. Oil & Gas Emissions with OMI NO2 Data

NASA Astrophysics Data System (ADS)

Clifton, O. E.; Holloway, T.; Oberman, J.

2012-12-01

In the last ten years, there has been a steep increase in the number natural gas and oil extraction facilities in the United States due to hydraulic fracturing ("fracking"). Each facility requires a large range of equipment, such as drilling rigs, compressor engines, heaters, and pneumatic devices. These activities can lead to elevated nitrogen dioxide (NO2) emissions in rural areas, often in regions without routine NO2 surface monitoring. Furthermore, permitting rules vary from state to state, and many new extraction facilities are unpermitted and exact emissions unknown. On April 18, 2012, the EPA announced air pollution standards for volatile organic compounds (VOCs) emissions from the oil and gas industry. Until 2015, when these standards must be in effect, NOx (NO2 + NO) will continue to react with VOCs to form unhealthy levels of tropospheric ozone in regions with heavy use of hydraulic fracturing. In order to identify areas of elevated NO2 emissions and constrain associated on-road and off-road sources in areas with prominent shale basins and known drilling, we employ remote sensing estimates of column NO2 from the Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite. OMI NO2 is sensitive to the planetary boundary layer and to surface air pollution and thus has high temporal and spatial variation. These Level-2 satellite data are processed with the Wisconsin Horizontal Interpolation Program for Satellites (WHIPS), developed at the University of Wisconsin-Madison. We interpolate the data to allow further ease in mapping change in NO2 associated with drilling, and the quantification of pollution trends attributable to hydraulic-fracturing in the Western U.S. from 2004 to the present.

Connecting Surface Emissions, Convective Uplifting, and Long-Range Transport of Carbon Monoxide in the Upper Troposphere: New Observations from the Aura Microwave Limb Sounder

NASA Technical Reports Server (NTRS)

Jiang, Jonathan H.; Livesey, Nathaniel J.; Su, Hui; Neary, Lori; McConnell, John C.; Richards, Nigel A. D.

2007-01-01

Two years of observations of upper tropospheric (UT) carbon monoxide (CO) from the Aura Microwave Limb Sounder are analyzed; in combination with the CO surface emission climatology and data from the NCEP analyses. It is shown that spatial distribution, temporal variation and long-range transport of UT CO are closely related to the surface emissions, deep-convection and horizontal winds. Over the Asian monsoon region, surface emission of CO peaks in boreal spring due to high biomass burning in addition to anthropogenic emission. However, the UT CO peaks in summer when convection is strongest and surface emission of CO is dominated by anthropogenic source. The long-range transport of CO from Southeast Asia across the Pacific to North America, which occurs most frequently during boreal summer, is thus a clear imprint of Asian anthropogenic pollution influencing global air quality.

Estimating State-Specific Contributions to PM2.5- and O3-Related Health Burden from Residential Combustion and Electricity Generating Unit Emissions in the United States

PubMed Central

Penn, Stefani L.; Arunachalam, Saravanan; Woody, Matthew; Heiger-Bernays, Wendy; Tripodis, Yorghos; Levy, Jonathan I.

2016-01-01

Background: Residential combustion (RC) and electricity generating unit (EGU) emissions adversely impact air quality and human health by increasing ambient concentrations of fine particulate matter (PM2.5) and ozone (O3). Studies to date have not isolated contributing emissions by state of origin (source-state), which is necessary for policy makers to determine efficient strategies to decrease health impacts. Objectives: In this study, we aimed to estimate health impacts (premature mortalities) attributable to PM2.5 and O3 from RC and EGU emissions by precursor species, source sector, and source-state in the continental United States for 2005. Methods: We used the Community Multiscale Air Quality model employing the decoupled direct method to quantify changes in air quality and epidemiological evidence to determine concentration–response functions to calculate associated health impacts. Results: We estimated 21,000 premature mortalities per year from EGU emissions, driven by sulfur dioxide emissions forming PM2.5. More than half of EGU health impacts are attributable to emissions from eight states with significant coal combustion and large downwind populations. We estimate 10,000 premature mortalities per year from RC emissions, driven by primary PM2.5 emissions. States with large populations and significant residential wood combustion dominate RC health impacts. Annual mortality risk per thousand tons of precursor emissions (health damage functions) varied significantly across source-states for both source sectors and all precursor pollutants. Conclusions: Our findings reinforce the importance of pollutant-specific, location-specific, and source-specific models of health impacts in design of health-risk minimizing emissions control policies. Citation: Penn SL, Arunachalam S, Woody M, Heiger-Bernays W, Tripodis Y, Levy JI. 2017. Estimating state-specific contributions to PM2.5- and O3-related health burden from residential combustion and electricity generating unit emissions in the United States. Environ Health Perspect 125:324–332; http://dx.doi.org/10.1289/EHP550 PMID:27586513

Spatial and Temporal Patterns in Carbon Emissions to the Atmosphere

NASA Astrophysics Data System (ADS)

Broniak, C. T.; Blasing, T. J.; Marland, G.

2003-12-01

Data on global fossil-fuel emissions of CO2 to the atmosphere for year 2000 show that the range of national average per capita emissions, in metric tons of carbon per person, includes values of 5.40 for the United States, 2.61 for Germany, 0.29 for India and 0.04 for Liberia. This range is more than two orders of magnitude. Similar data on national fossil-fuel emissions for the United States vary by more than an order of magnitude, from 34.18 metric tons of carbon per person for Wyoming to 2.70 for California. The state data also show differing patterns of change over time. The Kyoto Protocol would require ratifying developed countries to reduce greenhouse gas emissions to quantified negotiated targets. The concept of contraction and convergence (C&C) has been widely touted as a possible basis for ultimate, more strict limits on greenhouse gas emissions. The idea of C&C is that per-capita emissions of CO2 for all countries would converge toward some common value that is consistent with stabilization of global climate. The U.S., on the other hand, has proposed intensity-based emissions targets whereby goals would be defined in terms of emissions per unit of gross domestic product, or perhaps emissions per unit of output for specific activities. This paper describes the data set on U.S. CO2 emissions by state, and begins to explore the patterns between states and over time.

Unitized Regenerative Fuel Cell System Gas Storage-Radiator Development

NASA Technical Reports Server (NTRS)

Burke, Kenneth A.; Jakupta, Ian

2005-01-01

High-energy-density regenerative fuel cell systems that are used for energy storage require novel approaches to integrating components in order to preserve mass and volume. A lightweight unitized regenerative fuel cell (URFC) energy storage system concept is being developed at the NASA Glenn Research Center. This URFC system minimizes mass by using the surface area of the hydrogen and oxygen storage tanks as radiating heat surfaces for overall thermal control of the system. The waste heat generated by the URFC stack during charging and discharging is transferred from the cell stack to the surface of each tank by loop heat pipes, which are coiled around each tank and covered with a thin layer of thermally conductive carbon composite. The thin layer of carbon composite acts as a fin structure that spreads the heat away from the heat pipe and across the entire tank surface. Two different-sized commercial-grade composite tanks were constructed with integral heat pipes and tested in a thermal vacuum chamber to examine the feasibility of using the storage tanks as system radiators. The storage tank-radiators were subjected to different steady-state heat loads and varying heat load profiles. The surface emissivity and specific heat capacity of each tank were calculated. In the future, the results will be incorporated into a model that simulates the performance of similar radiators using lightweight, spacerated carbon composite tanks.

Sensitivity of thermal inertia calculations to variations in environmental factors. [in mapping of Earth's surface by remote sensing

NASA Technical Reports Server (NTRS)

Kahle, A. B.; Alley, R. E.; Schieldge, J. P.

1984-01-01

The sensitivity of thermal inertia (TI) calculations to errors in the measurement or parameterization of a number of environmental factors is considered here. The factors include effects of radiative transfer in the atmosphere, surface albedo and emissivity, variations in surface turbulent heat flux density, cloud cover, vegetative cover, and topography. The error analysis is based upon data from the Heat Capacity Mapping Mission (HCMM) satellite for July 1978 at three separate test sites in the deserts of the western United States. Results show that typical errors in atmospheric radiative transfer, cloud cover, and vegetative cover can individually cause root-mean-square (RMS) errors of about 10 percent (with atmospheric effects sometimes as large as 30-40 percent) in HCMM-derived thermal inertia images of 20,000-200,000 pixels.

Historical gaseous and primary aerosol emissions in the United States from 1990-2010

EPA Science Inventory

An accurate description of emissions is crucial for model simulations to reproduce and interpret observed phenomena over extended time periods. In this study, we used an approach based on activity data to develop a consistent series of spatially resolved emissions in the United S...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.84 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTINUOUS EMISSION MONITORING Hg Mass Emission Provisions § 75.84 Recordkeeping and reporting... Federal Hg mass emission reduction program”; (2) The information required in § 75.58(b)(3), for units with... or sorbent trap monitoring systems, for each hour when the unit is operating, record the Hg mass...

40 CFR 63.1567 - What are my requirements for inorganic HAP emissions from catalytic reforming units?

Code of Federal Regulations, 2013 CFR

2013-07-01

... different reactors in the catalytic reforming unit are regenerated in separate regeneration systems, then these emission limitations apply to each separate regeneration system. These emission limitations apply... catalyst rejuvenation operations during coke burn-off and catalyst regeneration. You can choose from the...

40 CFR 63.1567 - What are my requirements for inorganic HAP emissions from catalytic reforming units?

Code of Federal Regulations, 2012 CFR

2012-07-01

... different reactors in the catalytic reforming unit are regenerated in separate regeneration systems, then these emission limitations apply to each separate regeneration system. These emission limitations apply... catalyst rejuvenation operations during coke burn-off and catalyst regeneration. You can choose from the...

40 CFR 63.1567 - What are my requirements for inorganic HAP emissions from catalytic reforming units?

Code of Federal Regulations, 2014 CFR

2014-07-01

... different reactors in the catalytic reforming unit are regenerated in separate regeneration systems, then these emission limitations apply to each separate regeneration system. These emission limitations apply... catalyst rejuvenation operations during coke burn-off and catalyst regeneration. You can choose from the...

40 CFR 60.1885 - What must I include in my annual report?

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitoring system (§ 60.1850(a)(1)). (d) For municipal waste combustion units that use activated carbon for controlling dioxins/furans or mercury emissions, include four records: (1) The average carbon feed rates... municipal waste combustion units only, nitrogen oxides emissions. (3) Carbon monoxide emissions. (4) Load...

40 CFR 62.9970 - Identification of plan-negative declaration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Rhode Island Air Emissions from Existing Commercial and Industrial Solid Waste Incineration Units § 62... solid waste incineration units in the state subject to the emission guidelines under part 60, subpart DDDD of this chapter. [67 FR 17946, Apr. 12, 2002] Municipal Waste Combustor Emissions From Existing...

40 CFR 62.9970 - Identification of plan-negative declaration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Rhode Island Air Emissions from Existing Commercial and Industrial Solid Waste Incineration Units § 62... solid waste incineration units in the state subject to the emission guidelines under part 60, subpart DDDD of this chapter. [67 FR 17946, Apr. 12, 2002] Municipal Waste Combustor Emissions From Existing...

40 CFR 60.46c - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.46c Emission monitoring for sulfur dioxide... the inlet to the steam generating unit and analyzed for sulfur content and heat content according the...

40 CFR 60.46c - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.46c Emission monitoring for sulfur dioxide... the inlet to the steam generating unit and analyzed for sulfur content and heat content according the...

40 CFR 60.46c - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.46c Emission monitoring for sulfur dioxide... the inlet to the steam generating unit and analyzed for sulfur content and heat content according the...

40 CFR 60.46c - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.46c Emission monitoring for sulfur dioxide... the inlet to the steam generating unit and analyzed for sulfur content and heat content according the...

Current and future emissions of primary pollutants from coal-fired power plants in Shaanxi, China.

PubMed

Xu, Yong; Hu, Jianlin; Ying, Qi; Hao, Hongke; Wang, Dexiang; Zhang, Hongliang

2017-10-01

A high-resolution inventory of primary atmospheric pollutants from coal-fired power plants in Shaanxi in 2012 was built based on a detailed database compiled at unit level involving unit capacity, boiler size and type, commission time, corresponding control technologies, and average coal quality of 72 power plants. The pollutants included SO 2 , NO x , fine particulate matter (PM 2.5 ), inhalable particulate matter (PM 10 ), organic carbon (OC), elemental carbon (EC), carbon monoxide (CO) and non-methane volatile organic compounds (NMVOC). Emission factors for SO 2 , NO x , PM 2.5 and PM 10 were adopted from standardized official promulgation, supplemented by those from local studies. The estimated annual emissions of SO 2 , NO x , PM 2.5 , PM 10 , EC, OC, CO and NMVOC were 152.4, 314.8, 16.6, 26.4, 0.07, 0.27, 64.9 and 2.5kt, respectively. Small units (<100MW), which accounted for ~60% of total unit numbers, had less coal consumption but higher emission rates compared to medium (≥100MW and <300MW) and large units (≥300MW). Main factors affecting SO 2 , NO x , PM 2.5 and PM 10 emissions were decontamination efficiency, sulfur content and ash content of coal. Weinan and Xianyang were the two cities with the highest emissions, and Guanzhong Plain had the largest emission density. Despite the projected growth of coal consumption, emissions would decrease in 2030 due to improvement in emission control technologies and combustion efficiencies. SO 2 and NO x emissions would experience significant reduction by ~81% and ~84%, respectively. PM 2.5 , PM 10 , EC and OC would be decreased by ~43% and CO and NMVOC would be reduced by ~16%. Copyright © 2017 Elsevier B.V. All rights reserved.

Emission-dominated gas exchange of elemental mercury vapor over natural surfaces in China

NASA Astrophysics Data System (ADS)

Wang, Xun; Lin, Che-Jen; Yuan, Wei; Sommar, Jonas; Zhu, Wei; Feng, Xinbin

2016-09-01

Mercury (Hg) emission from natural surfaces plays an important role in global Hg cycling. The present estimate of global natural emission has large uncertainty and remains unverified against field data, particularly for terrestrial surfaces. In this study, a mechanistic model is developed for estimating the emission of elemental mercury vapor (Hg0) from natural surfaces in China. The development implements recent advancements in the understanding of air-soil and air-foliage exchange of Hg0 and redox chemistry in soil and on surfaces, incorporates the effects of soil characteristics and land use changes by agricultural activities, and is examined through a systematic set of sensitivity simulations. Using the model, the net exchange of Hg0 between the atmosphere and natural surfaces of mainland China is estimated to be 465.1 Mg yr-1, including 565.5 Mg yr-1 from soil surfaces, 9.0 Mg yr-1 from water bodies, and -100.4 Mg yr-1 from vegetation. The air-surface exchange is strongly dependent on the land use and meteorology, with 9 % of net emission from forest ecosystems; 50 % from shrubland, savanna, and grassland; 33 % from cropland; and 8 % from other land uses. Given the large agricultural land area in China, farming activities play an important role on the air-surface exchange over farmland. Particularly, rice field shift from a net sink (3.3 Mg uptake) during April-October (rice planting) to a net source when the farmland is not flooded (November-March). Summing up the emission from each land use, more than half of the total emission occurs in summer (51 %), followed by spring (28 %), autumn (13 %), and winter (8 %). Model verification is accomplished using observational data of air-soil/air-water fluxes and Hg deposition through litterfall for forest ecosystems in China and Monte Carlo simulations. In contrast to the earlier estimate by Shetty et al. (2008) that reported large emission from vegetative surfaces using an evapotranspiration approach, the estimate in this study shows natural emissions are primarily from grassland and dry cropland. Such an emission pattern may alter the current understanding of Hg emission outflow from China as reported by Lin et al. (2010b) because a substantial natural Hg emission occurs in West China.

Monitoring and assessment of ocean acidification in the Arctic Ocean-A scoping paper

USGS Publications Warehouse

Robbins, Lisa L.; Yates, Kimberly K.; Feely, Richard; Fabry, Victoria

2010-01-01

Carbon dioxide (CO2) in the atmosphere is absorbed at the ocean surface by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution. Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats. The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

40 CFR 63.3890 - What emission limits must I meet?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Hazardous Air Pollutants for Surface Coating of Miscellaneous Metal Parts and Products... surface coating operations meet the applicability criteria of more than one of the subcategory emission.... (1) If the general use or magnet wire surface coating operations subject to only one of the emission...

Secondary electron emission from textured surfaces

NASA Astrophysics Data System (ADS)

Huerta, C. E.; Patino, M. I.; Wirz, R. E.

2018-04-01

In this work, a Monte Carlo model is used to investigate electron induced secondary electron emission for varying effects of complex surfaces by using simple geometric constructs. Geometries used in the model include: vertical fibers for velvet-like surfaces, tapered pillars for carpet-like surfaces, and a cage-like configuration of interlaced horizontal and vertical fibers for nano-structured fuzz. The model accurately captures the secondary electron emission yield dependence on incidence angle. The model shows that unlike other structured surfaces previously studied, tungsten fuzz exhibits secondary electron emission yield that is independent of primary electron incidence angle, due to the prevalence of horizontally-oriented fibers in the fuzz geometry. This is confirmed with new data presented herein of the secondary electron emission yield of tungsten fuzz at incidence angles from 0-60°.

Environmental impact of minimally invasive surgery in the United States: an estimate of the carbon dioxide footprint.

PubMed

Power, Nicholas E; Silberstein, Jonathan L; Ghoneim, Tarek P; Guillonneau, Bertrand; Touijer, Karim A

2012-12-01

To attempt to quantitate the carbon footprint of minimally invasive surgery (MIS) through approximated scope 1 to 3 CO(2) emissions to identify its potential role in global warming. To estimate national usage, we determined the number of inpatient and outpatient MIS procedures using International Classification of Diseases, ninth revision-clinical modification codes for all MIS procedures in a 2009 sample collected in national databases. Need for surgery was considered essential, and therefore traditional open surgery was used as the comparator. Scope 1 (direct) CO(2) emissions resulting from CO(2) gas used for insufflation were based on both escaping procedural CO(2) and metabolic CO(2) eliminated via respiration. Scopes 2 and 3 (indirect) emissions related to capture, compression, and transportation of CO(2) to hospitals and the disposal of single-use equipment not used in open surgery were calculated. The total CO(2) emissions were calculated to be 355,924 tonnes/year. For perspective, if MIS in the United States was considered a country, it would rank 189 th on the United Nations 2008 list of countries' carbon emissions per year. Limitations include the inability to account for uncertainty using the various models and tools for approximating CO(2) emissions. CO(2) emission of MIS in the United States may have a significant environmental impact. This is the first attempt to quantify CO(2) emissions related to MIS in the United States. Strategies for reduction, while maintaining high quality medical care, should be considered.

Tire wear particles in the aquatic environment - A review on generation, analysis, occurrence, fate and effects.

PubMed

Wagner, Stephan; Hüffer, Thorsten; Klöckner, Philipp; Wehrhahn, Maren; Hofmann, Thilo; Reemtsma, Thorsten

2018-08-01

Tire wear particles (TWP), generated from tire material during use on roads have gained increasing attention as part of organic particulate contaminants, such as microplastic, in aquatic environments. The available information on properties and generation of TWP, analytical techniques to determine TWP, emissions, occurrence and behavior and ecotoxicological effects of TWP are reviewed with a focus on surface water as a potential receptor. TWP emissions are traffic related and contribute 5-30% to non-exhaust emissions from traffic. The mass of TWP generated is estimated at 1,327,000 t/a for the European Union, 1,120,000 t/a for the United States and 133,000 t/a for Germany. For Germany, this is equivalent to four times the amount of pesticides used. The mass of TWP ultimately entering the aquatic environment strongly depends on the extent of collection and treatment of road runoff, which is highly variable. For the German highways it is estimated that up to 11,000 t/a of TWP reach surface waters. Data on TWP concentrations in the environment, including surface waters are fragmentary, which is also due to the lack of suitable analytical methods for their determination. Information on TWP properties such as density and size distribution are missing; this hampers assessing the fate of TWP in the aquatic environment. Effects in the aquatic environment may stem from TWP itself or from compounds released from TWP. It is concluded that reliable knowledge on transport mechanism to surface waters, concentrations in surface waters and sediments, effects of aging, environmental half-lives of TWP as well as effects on aquatic organisms are missing. These aspects need to be addressed to allow for the assessment of risk of TWP in an aquatic environment. Copyright © 2018 Elsevier Ltd. All rights reserved.

Coherent and radiative couplings through two-dimensional structured environments

NASA Astrophysics Data System (ADS)

Galve, F.; Zambrini, R.

2018-03-01

We study coherent and radiative interactions induced among two or more quantum units by coupling them to two-dimensional (2D) lattices acting as structured environments. This model can be representative of atoms trapped near photonic crystal slabs, trapped ions in Coulomb crystals, or to surface acoustic waves on piezoelectric materials, cold atoms on state-dependent optical lattices, or even circuit QED architectures, to name a few. We compare coherent and radiative contributions for the isotropic and directional regimes of emission into the lattice, for infinite and finite lattices, highlighting their differences and existing pitfalls, e.g., related to long-time or large-lattice limits. We relate the phenomenon of directionality of emission with linear-shaped isofrequency manifolds in the dispersion relation, showing a simple way to disrupt it. For finite lattices, we study further details such as the scaling of resonant number of lattice modes for the isotropic and directional regimes, and relate this behavior with known van Hove singularities in the infinite lattice limit. Furthermore, we export the understanding of emission dynamics with the decay of entanglement for two quantum, atomic or bosonic, units coupled to the 2D lattice. We analyze in some detail completely subradiant configurations of more than two atoms, which can occur in the finite lattice scenario, in contrast with the infinite lattice case. Finally, we demonstrate that induced coherent interactions for dark states are zero for the finite lattice.

Identification of Dust Source Regions at High-Resolution and Dynamics of Dust Source Mask over Southwest United States Using Remote Sensing Data

NASA Astrophysics Data System (ADS)

Sprigg, W. A.; Sahoo, S.; Prasad, A. K.; Venkatesh, A. S.; Vukovic, A.; Nickovic, S.

2015-12-01

Identification and evaluation of sources of aeolian mineral dust is a critical task in the simulation of dust. Recently, time series of space based multi-sensor satellite images have been used to identify and monitor changes in the land surface characteristics. Modeling of windblown dust requires precise delineation of mineral dust source and its strength that varies over a region as well as seasonal and inter-annual variability due to changes in land use and land cover. Southwest USA is one of the major dust emission prone zone in North American continent where dust is generated from low lying dried-up areas with bare ground surface and they may be scattered or appear as point sources on high resolution satellite images. In the current research, various satellite derived variables have been integrated to produce a high-resolution dust source mask, at grid size of 250 m, using data such as digital elevation model, surface reflectance, vegetation cover, land cover class, and surface wetness. Previous dust source models have been adopted to produce a multi-parameter dust source mask using data from satellites such as Terra (Moderate Resolution Imaging Spectroradiometer - MODIS), and Landsat. The dust source mask model captures the topographically low regions with bare soil surface, dried-up river plains, and lakes which form important source of dust in southwest USA. The study region is also one of the hottest regions of USA where surface dryness, land use (agricultural use), and vegetation cover changes significantly leading to major changes in the areal coverage of potential dust source regions. A dynamic high resolution dust source mask have been produced to address intra-annual change in the aerial extent of bare dry surfaces. Time series of satellite derived data have been used to create dynamic dust source masks. A new dust source mask at 16 day interval allows enhanced detection of potential dust source regions that can be employed in the dust emission and transport pathways models for better estimation of emission of dust during dust storms, particulate air pollution, public health risk assessment tools and decision support systems.

Evaluation of ionic air purifiers for reducing aerosol exposure in confined indoor spaces.

PubMed

Grinshpun, S A; Mainelis, G; Trunov, M; Adhikari, A; Reponen, T; Willeke, K

2005-08-01

Numerous techniques have been developed over the years for reducing aerosol exposure in indoor air environments. Among indoor air purifiers of different types, ionic emitters have gained increasing attention and are presently used for removing dust particles, aeroallergens and airborne microorganisms from indoor air. In this study, five ionic air purifiers (two wearable and three stationary) that produce unipolar air ions were evaluated with respect to their ability to reduce aerosol exposure in confined indoor spaces. The concentration decay of respirable particles of different properties was monitored in real time inside the breathing zone of a human manikin, which was placed in a relatively small (2.6 m3) walk-in chamber during the operation of an ionic air purifier in calm air and under mixing air condition. The particle removal efficiency as a function of particle size was determined using the data collected with a size-selective optical particle counter. The removal efficiency of the more powerful of the two wearable ionic purifiers reached about 50% after 15 min and almost 100% after 1.5 h of continuous operation in the chamber under calm air conditions. In the absence of external ventilation, air mixing, especially vigorous one (900 CFM), enhanced the air cleaning effect. Similar results were obtained when the manikin was placed inside a partial enclosure that simulated an aircraft seating configuration. All three stationary ionic air purifiers tested in this study were found capable of reducing the aerosol concentration in a confined indoor space. The most powerful stationary unit demonstrated an extremely high particle removal efficiency that increased sharply to almost 90% within 5-6 min, reaching about 100% within 10-12 min for all particle sizes (0.3-3 microm) tested in the chamber. For the units of the same emission rate, the data suggest that the ion polarity per se (negative vs. positive) does not affect the performance but the ion emission rate does. The effects of particle size (within the tested range) and properties (NaCl, PSL, Pseudomonas fluorescens bacteria) as well as the effects of the manikin's body temperature and its breathing on the ionic purifier performance were either small or insignificant. The data suggest that the unipolar ionic air purifiers are particularly efficient in reducing aerosol exposure in the breathing zone when used inside confined spaces with a relatively high surface-to-volume ratio. Ionic air purifiers have become increasingly popular for removing dust particles, aeroallergens and airborne microorganisms from indoor air in various settings. While the indoor air cleaning effect, resulting from unipolar and bipolar ion emission, has been tested by several investigators, there are still controversial claims (favorable and unfavorable) about the performance of commercially available ionic air purifiers. Among the five tested ionic air purifiers (two wearable and three stationary) producing unipolar air ions, the units with a higher ion emission rate provided higher particle removal efficiency. The ion polarity (negative vs. positive), the particle size (0.3-3 microm) and properties (NaCl, PSL, Pseudomonas fluorescens bacteria), as well as the body temperature and breathing did not considerable affected the ionization-driven particle removal. The data suggest that the unipolar ionic air purifiers are particularly efficient in reducing aerosol exposure in the breathing zone when they are used inside confined spaces with a relatively high surface-to-volume ratio (such as automobile cabins, aircraft seating areas, bathrooms, cellular offices, small residential rooms, and animal confinements). Based on our experiments, we proposed that purifiers with a very high ion emission rate be operated in an intermittent mode if used indoors for extended time periods. As the particles migrate to and deposit on indoor surfaces during the operation of ionic air purifiers, some excessive surface contamination may occur, which introduces the need of periodic cleaning these surfaces.

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

NASA Astrophysics Data System (ADS)

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie; Stavitski, Eli; Sadowski, Jerzy T.; Vescovo, Elio; Walter, Andrew; Attenkofer, Klaus; Stacchiola, Darío J.; Liu, Mingzhao

2017-12-01

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices such as ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of the reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O 2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of themore » reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.« less

Near band edge photoluminescence of ZnO nanowires: Optimization via surface engineering

DOE PAGES

Yan, Danhua; Zhang, Wenrui; Cen, Jiajie; ...

2017-12-04

Zinc oxide (ZnO) nanowire arrays have potential applications for various devices including ultra-violet light emitting diodes and lasers, where photoluminescence of intense near band edge emission without defect emissions is usually desired. Here, we demonstrate, counter-intuitively, that the near band edge emission may become dominant by introducing certain surface defects to ZnO nanowires via surface engineering. Specifically, near band edge emission (NBE) is effectively enhanced after a low pressure O 2 plasma treatment that sputters off surface oxygen species to produce a reduced and oxygen vacancy-rich surface. The effect is attributed to the lowered surface valence band maximum of themore » reduced ZnO surface that creates an accumulative band bending, which screens the photo-generated minority carriers (holes) from reaching or being trapped by the surface defects.« less

A Theoretical and Experimental Study of Emission Spectroscopy of Planetary Surfaces

NASA Astrophysics Data System (ADS)

Henderson, Bradley Gray

1995-01-01

This thesis explores the spectral emissivity of particulate materials on planetary surfaces through theoretical modeling and supporting laboratory and field investigations. In the first part of the thesis, I develop a Monte Carlo ray tracing model to calculate the directional and spectral emissivity and the polarization state of the radiation emitted from a particulate, isothermal surface for emission angles 0^circ-90^ circ and wavelengths 7-16 mu m. The results show that roughness and scattering significantly affect the character of the emitted radiation field and should be taken into account when interpreting the physical properties of a planetary surface from IR spectrophotometry or spectropolarimetry. The remainder of the thesis focuses on understanding near-surface thermal gradients and their effects on emission spectra for different planetary environments. These gradients are formed by radiative cooling in the top few hundred microns of low conductivity particulate materials on planetary surfaces with little or no atmosphere. I model the heat transfer by conduction and radiation in the top few millimeters of a planetary regolith for scattering and non-scattering media. In conjunction with the modeling, I measure emission spectra of fine-grained quartz in an environment chamber designed to simulate the conditions on other planetary surfaces. The results show that significant thermal gradients will form in the near surface of materials on the surface of the Moon and Mercury. Their presence increases spectral contrast and creates emission maxima in the transparent regions of the spectrum. Thermal gradients are shown to be responsible for the observed wavelength shifts of the Christiansen emission peak with variations in thermal conductivity and grain size. The results are also used to analyze recent telescopic spectra of the Moon and Mercury and can explain certain features seen in those data. Thermal gradients are shown to be minor for the surface of Mars and negligible on Earth. I conclude that the spectral effects created by near-surface thermal gradients are predictable and might even provide an extra source of information about the physical nature of a planetary surface, and mid-IR emission spectroscopy should therefore prove to be useful for remote sensing of airless bodies.

Organic Light-Emitting Diodes with a Perylene Interlayer Between the Electrode-Organic Interface

NASA Astrophysics Data System (ADS)

Saikia, Dhrubajyoti; Sarma, Ranjit

2018-01-01

The performance of an organic light-emitting diode (OLED) with a vacuum-deposited perylene layer over a fluorine-doped tin oxide (FTO) surface is reported. To investigate the effect of the perylene layer on OLED performance, different thicknesses of perylene are deposited on the FTO surface and their current density-voltages (J-V), luminance-voltages (L-V) and device efficiency characteristics at their respective thickness are studied. Further analysis is carried out with an UV-visible light double-beam spectrophotometer unit, a four-probe resistivity unit and a field emission scanning electron microscope set up to study the optical transmittance, sheet resistance and surface morphology of the bilayer anode film. We used N,N'-bis(3-methyl phenyl)- N,N'(phenyl)-benzidine (TPD) as the hole transport layer, Tris(8-hydroxyquinolinato)aluminum (Alq3) as a light-emitting layer and lithium fluoride as an electron injection layer. The luminance efficiency of an OLED structure with a 9-nm-thick perylene interlayer is increased by 2.08 times that of the single-layer FTO anode OLED. The maximum value of current efficiency is found to be 5.25 cd/A.

40 CFR Appendix D to Part 75 - Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units D Appendix D to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Pt. 75, App. D Appendix D to Part 75—Optional SO2 Emissions Data...

Nitrogen emissions, deposition, and monitoring in the western United States

Treesearch

Mark E. Fenn; Richard Haeuber; Gail S. Tonnesen; Jill S. Baron; Susanne Grossman-Clarke; Diane Hope; Daniel A. Jaffe; Scott Copeland; Linda Geiser; Heather M. Rueth; James O. Sickman

2003-01-01

Nitrogen (N) deposition in the western United States ranges from 1 to 4 kilograms (kg) per hectare (ha) per year over much of the region to as high as 30 to 90 kg per ha per year downwind of major urban and agricultural areas. Primary N emissions sources are transportation, agriculture, and industry. Emissions of N as ammonia are about 50% as great as emissions of N as...

Estimation of VOC emissions from produced-water treatment ponds in Uintah Basin oil and gas field using modeling techniques

NASA Astrophysics Data System (ADS)

Tran, H.; Mansfield, M. L.; Lyman, S. N.; O'Neil, T.; Jones, C. P.

2015-12-01

Emissions from produced-water treatment ponds are poorly characterized sources in oil and gas emission inventories that play a critical role in studying elevated winter ozone events in the Uintah Basin, Utah, U.S. Information gaps include un-quantified amounts and compositions of gases emitted from these facilities. The emitted gases are often known as volatile organic compounds (VOCs) which, beside nitrogen oxides (NOX), are major precursors for ozone formation in the near-surface layer. Field measurement campaigns using the flux-chamber technique have been performed to measure VOC emissions from a limited number of produced water ponds in the Uintah Basin of eastern Utah. Although the flux chamber provides accurate measurements at the point of sampling, it covers just a limited area of the ponds and is prone to altering environmental conditions (e.g., temperature, pressure). This fact raises the need to validate flux chamber measurements. In this study, we apply an inverse-dispersion modeling technique with evacuated canister sampling to validate the flux-chamber measurements. This modeling technique applies an initial and arbitrary emission rate to estimate pollutant concentrations at pre-defined receptors, and adjusts the emission rate until the estimated pollutant concentrations approximates measured concentrations at the receptors. The derived emission rates are then compared with flux-chamber measurements and differences are analyzed. Additionally, we investigate the applicability of the WATER9 wastewater emission model for the estimation of VOC emissions from produced-water ponds in the Uintah Basin. WATER9 estimates the emission of each gas based on properties of the gas, its concentration in the waste water, and the characteristics of the influent and treatment units. Results of VOC emission estimations using inverse-dispersion and WATER9 modeling techniques will be reported.

Textured carbon on copper: A novel surface with extremely low secondary electron emission characteristics

NASA Technical Reports Server (NTRS)

Curren, A. N.; Jensen, K. A.

1985-01-01

Experimentally determined values of true secondary electron emission and relative values of reflected primary electron yield for a range of primary electron beam energies and beam impingement angles are presented for a series of novel textured carbon surfaces on copper substrates. (All copper surfaces used in this study were oxygen-free, high-conductivity grade). The purpose of this investigation is to provide information necessary to develop high-efficiency multistage depressed collectors (MDC's) for microwave amplifier traveling-wave tubes (TWT's) for communications and aircraft applications. To attain the highest TWT signal quality and overall efficiency, the MDC electrode surface must have low secondary electron emission characteristics. While copper is the material most commonly used for MDC electrodes, it exhibits relatively high levels of secondary electron emission unless its surface is treated for emission control. The textured carbon surface on copper substrate described in this report is a particularly promising candidate for the MDC electrode application. Samples of textured carbon surfaces on copper substrates typical of three different levels of treatment are prepared and tested for this study. The materials are tested at primary electron beam energies of 200 to 2000 eV and at direct (0 deg) to near-grazing (85 deg) beam impingement angles. True secondary electron emission and relative reflected primary electron yield characteristics of the textured surfaces are compared with each other and with those of untreated copper. All the textured carbon surfaces on copper substrate tested exhibited sharply lower secondary electron emission characteristics than those of an untreated copper surface.

Radiative decay engineering 3. Surface plasmon-coupled directional emission

PubMed Central

Lakowicz, Joseph R.

2009-01-01

A new method of fluorescence detection that promises to increase sensitivity by 20- to 1000-fold is described. This method will also decrease the contribution of sample autofluorescence to the detected signal. The method depends on the coupling of excited fluorophores with the surface plasmon resonance present in thin metal films, typically silver and gold. The phenomenon of surface plasmon-coupled emission (SPCE) occurs for fluorophores 20–250 nm from the metal surface, allowing detection of fluorophores over substantial distances beyond the metal–sample interface. SPCE depends on interactions of the excited fluorophore with the metal surface. This interaction is independent of the mode of excitation; that is, it does not require evanescent wave or surface-plasmon excitation. In a sense, SPCE is the inverse process of the surface plasmon resonance absorption of thin metal films. Importantly, SPCE occurs over a narrow angular distribution, converting normally isotropic emission into easily collected directional emission. Up to 50% of the emission from unoriented samples can be collected, much larger than typical fluorescence collection efficiencies near 1% or less. SPCE is due only to fluorophores near the metal surface and may be regarded as emission from the induced surface plasmons. Autofluorescence from more distal parts of the sample is decreased due to decreased coupling. SPCE is highly polarized and autofluorescence can be further decreased by collecting only the polarized component or only the light propagating with the appropriate angle. Examples showing how simple optical configurations can be used in diagnostics, sensing, or biotechnology applications are presented. Surface plasmon-coupled emission is likely to find widespread applications throughout the biosciences. PMID:14690679

A superior architecture of brightness enhancement for display backlighting

NASA Astrophysics Data System (ADS)

Dross, Oliver; Parkyn, William A.; Chaves, Julio; Falicoff, Waqidi; Miñano, Juan Carlos; Benitez, Pablo; Alvarez, Roberto

2006-08-01

Brightness enhancement of backlighting for displays is typically achieved via crossed micro prismatic films that are introduced between a backlight unit and a transmissive (LCD) display. Prismatic films let pass light only into a restricted angular range, while, in conjunction with other reflective elements below the backlight, all other light is recycled within the backlight unit, thereby increasing the backlight luminance. This design offers no free parameters to influence the resulting light distribution and suffers from insufficient stray light control. A novel strategy of light recycling is introduced, using a microlens array in conjunction with a hole array in a reflective surface, that can provide higher luminance, superior stray light control, and can be designed to meet almost any desired emission pattern. Similar strategies can be applied to mix light from different colored LEDs being mounted upside down to shine into a backlight unit.

Mesoscale modeling of Central American smoke transport to the United States: 1. ``Top-down'' assessment of emission strength and diurnal variation impacts

NASA Astrophysics Data System (ADS)

Wang, Jun; Christopher, Sundar A.; Nair, U. S.; Reid, Jeffrey S.; Prins, Elaine M.; Szykman, James; Hand, Jenny L.

2006-03-01

As is typical in the Northern Hemisphere spring, during 20 April to 21 May 2003, significant biomass burning smoke from Central America was transported to the southeastern United States (SEUS). A coupled aerosol, radiation, and meteorology model that is built upon the heritage of the Regional Atmospheric Modeling System (RAMS), having newly developed capabilities of Assimilation and Radiation Online Modeling of Aerosols (AROMA) algorithm, was used to simulate the smoke transport and quantify the smoke radiative impacts on surface energetics, boundary layer, and other atmospheric processes. This paper, the first of a two-part series, describes the model and examines the ability of RAMS-AROMA to simulate the smoke transport. Because biomass-burning fire activities have distinct diurnal variations, the FLAMBE hourly smoke emission inventory that is derived from the geostationary satellite (GOES) fire products was assimilated into the model. In the "top-down" analysis, ground-based observations were used to evaluate the model performance, and the comparisons with model-simulated results were used to estimate emission uncertainties. Qualitatively, a 30-day simulation of smoke spatial distribution as well as the timing and location of the smoke fronts are consistent with those identified from the PM2.5 observation network, local air quality reports, and the measurements of aerosol optical thickness (AOT) and aerosol vertical profiles from the Southern Great Plains (SGP) Atmospheric Radiation Measurements (ARM) site in Oklahoma. Quantitatively, the model-simulated daily mean near-surface dry smoke mass correlates well with PM2.5 mass at 34 locations in Texas and with the total carbon mass and nonsoil potassium mass (KNON) at three IMPROVE sites along the smoke pathway (with linear correlation coefficients R = 0.77, 0.74, and 0.69 at the significance level larger than 0.99, respectively). The top-down sensitivity analysis indicates that the total smoke particle emission during the study period is about 1.3 ± 0.2 Tg. The results further indicate that the simulation with a daily smoke emission inventory provides a slightly better correlation with measurements in the downwind region on daily scales but gives an unrealistic diurnal variation of AOT in the smoke source region. This study suggests that the assimilation of emission inventories from geostationary satellites is superior to that of polar orbiting satellites and has important implications for the modeling of air quality in areas influenced by fire-related pollutants from distant sources.

Finding Blackbody Temperature and Emissivity on a Sub-Pixel Scale

NASA Astrophysics Data System (ADS)

Bernstein, D. J.; Bausell, J.; Grigsby, S.; Kudela, R. M.

2015-12-01

Surface temperature and emissivity provide important insight into the ecosystem being remotely sensed. Dozier (1981) proposed a an algorithm to solve for percent coverage and temperatures of two different surface types (e.g. sea surface, cloud cover, etc.) within a given pixel, with a constant value for emissivity assumed. Here we build on Dozier (1981) by proposing an algorithm that solves for both temperature and emissivity of a water body within a satellite pixel by assuming known percent coverage of surface types within the pixel. Our algorithm generates thermal infrared (TIR) and emissivity end-member spectra for the two surface types. Our algorithm then superposes these end-member spectra on emissivity and TIR spectra emitted from four pixels with varying percent coverage of different surface types. The algorithm was tested preliminarily (48 iterations) using simulated pixels containing more than one surface type, with temperature and emissivity percent errors of ranging from 0 to 1.071% and 2.516 to 15.311% respectively[1]. We then tested the algorithm using a MASTER image from MASTER collected as part of the NASA Student Airborne Research Program (NASA SARP). Here the temperature of water was calculated to be within 0.22 K of in situ data. The algorithm calculated emissivity of water with an accuracy of 0.13 to 1.53% error for Salton Sea pixels collected with MASTER, also collected as part of NASA SARP. This method could improve retrievals for the HyspIRI sensor. [1] Percent error for emissivity was generated by averaging percent error across all selected bands widths.

Using surface water application to reduce 1,3-dichloropropene emission from soil fumigation.

PubMed

Gao, Suduan; Trout, Thomas J

2006-01-01

High emissions from soil fumigants increase the risk of detrimental impact on workers, bystanders, and the environment, and jeopardize future availability of fumigants. Efficient and cost-effective approaches to minimize emissions are needed. This study evaluated the potential of surface water application (or water seal) to reduce 1,3-dichloropropene (1,3-D) emissions from soil (Hanford sandy loam) columns. Treatments included dry soil (control), initial water application (8 mm of water just before fumigant application), initial plus a second water application (2.6 mm) at 12 h, initial plus two water applications (2.6 mm each time) at 12 and 24 h, standard high density polyethylene (HDPE) tarp, initial water application plus HDPE tarp, and virtually impermeable film (VIF) tarp. Emissions from the soil surface and distribution of 1,3-D in the soil-gas phase were monitored for 2 wk. Each water application abruptly reduced 1,3-D emission flux, which rebounded over a few hours. Peak emission rates were substantially reduced, but total emission reduction was small. Total fumigant emission was 51% of applied for the control, 46% for initial water application only, and 41% for the three intermittent water applications with the remaining water treatment intermediate. The HDPE tarp alone resulted in 45% emission, while initial water application plus HDPE tarp resulted in 38% emission. The most effective soil surface treatment was VIF tarp (10% emission). Surface water application can be as effective, and less expensive than, standard HDPE tarp. Frequent water application is required to substantially reduce emissions.

Memoris, A Wide Angle Camera For Bepicolombo

NASA Astrophysics Data System (ADS)

Cremonese, G.; Memoris Team

In order to answer to the Announcement of Opportunity of ESA for the BepiColombo payload, we are working on a wide angle camera concept named MEMORIS (MEr- cury MOderate Resolution Imaging System). MEMORIS will performe stereoscopic images of the whole Mercury surface using two different channels at +/- 20 degrees from the nadir point. It will achieve a spatial resolution of 50m per pixel at 400 km from the surface (peri-Herm), corresponding to a vertical resolution of about 75m with the stereo performances. The scientific objectives will be addressed by MEMORIS may be identified as follows: Estimate of surface age based on crater counting Crater morphology and degrada- tion Stratigraphic sequence of geological units Identification of volcanic features and related deposits Origin of plain units from morphological observations Distribution and type of the tectonic structures Determination of relative age among the structures based on cross-cutting relationships 3D Tectonics Global mineralogical mapping of main geological units Identification of weathering products The last two items will come from the multispectral capabilities of the camera utilizing 8 to 12 (TBD) broad band filters. MEMORIS will be equipped by a further channel devoted to the observations of the tenuous exosphere. It will look at the limb on a given arc of the BepiColombo orbit, in so doing it will observe the exosphere above a surface latitude range of 25-75 degrees in the northern emisphere. The exosphere images will be obtained above the surface just observed by the other two channels, trying to find possible relantionship, as ground-based observations suggest. The exospheric channel will have four narrow-band filters centered on the sodium and potassium emissions and the adjacent continua.

Transfer Printing Method to Obtain Polarized Light Emission in Organic Light-Emitting Device

NASA Astrophysics Data System (ADS)

Noh, Hee Yeon; Park, Chang-sub; Park, Ji-Sub; Kang, Shin-Won; Kim, Hak-Rin

2012-06-01

We demonstrate a transfer printing method to obtain polarized light emission in organic light-emitting devices (OLEDs). On a rubbed self-assembled monolayer (SAM), a spin-coated liquid crystalline light-emissive polymer is aligned along the rubbing direction because of the anisotropic interfacial intermolecular interaction. Owing to the low surface energy of the SAM surface, the light-emissive layer was easily transferred to a patterned poly(dimethylsiloxane) (PDMS) stamp surface without degrading the ordering. Finally, a polarized light-emissive OLED device was prepared by transferring the patterned light-emissive layer to the charge transport layer of the OLED structure.

Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005–2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Z.; Streets, D. G.; de Foy, B.

Satellite remote sensing of tropospheric nitrogen dioxide (NO 2) can provide valuable information for estimating surface nitrogen oxides (NO x) emissions. Using an exponentially modified Gaussian (EMG) method and taking into account the effect of wind on observed NO 2 distributions, we estimate 3-year moving-average emissions of summertime NO x from 35 US (United States) urban areas directly from NO 2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NO x emissions from each urban area by applyingmore » the EMG method to OMI data with wind speeds greater than 3–5 m s -1. Meanwhile, we find that OMI NO 2 observations under weak-wind conditions (i.e., < 3 m s −1) are qualitatively better correlated to the surface NO x source strength in comparison to all-wind OMI maps; therefore, we use them to calculate the satellite-observed NO 2 burdens of urban areas and compare with NO x emission estimates. The EMG results show that OMI-derived NO x emissions are highly correlated ( R > 0.93) with weak-wind OMI NO 2 burdens as well as with bottom-up NO x emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous EMG-obtained effective NO 2 lifetimes (~ 3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO 2 chemical lifetimes. In general, isolated urban areas with NO x emission intensities greater than ~ 2 Mg h -1 produce statistically significant weak-wind signals in 3-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NO x emissions over all selected US urban areas decreased by 49 %, consistent with reductions of 43, 47, 49, and 44 % in the total bottom-up NO x emissions, the sum of weak-wind OMI NO 2 columns, the total weak-wind OMI NO 2 burdens, and the averaged NO 2 concentrations, respectively, reflecting the success of NO x control programs for both mobile sources and power plants. The decrease rates of these NO x-related quantities are found to be faster (i.e., -6.8 to -9.3 % yr −1) before 2010 and slower (i.e., -3.4 to -4.9 % yr −1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NO x emissions, the weak-wind OMI NO 2 burdens, and ground-based NO 2 measurements, and high correlations are found for all urban areas (median R= 0.8), particularly large ones ( R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NO x emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.« less

40 CFR 62.1985 - Identification of plan-negative declaration.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Delaware Emissions from Existing Commercial/industrial Solid Waste Incineration Units § 62.1985... solid waste incineration units within the State of Delaware that are subject to 40 CFR part 60, subpart DDDD. [68 FR 49, Jan. 2, 2003] Emissions From Existing Other Solid Waste Combustion Units ...

40 CFR 62.1985 - Identification of plan-negative declaration.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Delaware Emissions from Existing Commercial/industrial Solid Waste Incineration Units § 62.1985... solid waste incineration units within the State of Delaware that are subject to 40 CFR part 60, subpart DDDD. [68 FR 49, Jan. 2, 2003] Emissions From Existing Other Solid Waste Combustion Units ...

Indirect estimation of emission factors for phosphate surface mining using air dispersion modeling.

PubMed

Tartakovsky, Dmitry; Stern, Eli; Broday, David M

2016-06-15

To date, phosphate surface mining suffers from lack of reliable emission factors. Due to complete absence of data to derive emissions factors, we developed a methodology for estimating them indirectly by studying a range of possible emission factors for surface phosphate mining operations and comparing AERMOD calculated concentrations to concentrations measured around the mine. We applied this approach for the Khneifiss phosphate mine, Syria, and the Al-Hassa and Al-Abyad phosphate mines, Jordan. The work accounts for numerous model unknowns and parameter uncertainties by applying prudent assumptions concerning the parameter values. Our results suggest that the net mining operations (bulldozing, grading and dragline) contribute rather little to ambient TSP concentrations in comparison to phosphate processing and transport. Based on our results, the common practice of deriving the emission rates for phosphate mining operations from the US EPA emission factors for surface coal mining or from the default emission factor of the EEA seems to be reasonable. Yet, since multiple factors affect dispersion from surface phosphate mines, a range of emission factors, rather than only a single value, was found to satisfy the model performance. Copyright © 2016 Elsevier B.V. All rights reserved.

Emissions from oil and gas operations in the United States and their air quality implications.

PubMed

Allen, David T

2016-06-01

The energy supply infrastructure in the United States has been changing dramatically over the past decade. Increased production of oil and natural gas, particularly from shale resources using horizontal drilling and hydraulic fracturing, made the United States the world's largest producer of oil and natural gas in 2014. This review examines air quality impacts, specifically, changes in greenhouse gas, criteria air pollutant, and air toxics emissions from oil and gas production activities that are a result of these changes in energy supplies and use. National emission inventories indicate that volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from oil and gas supply chains in the United States have been increasing significantly, whereas emission inventories for greenhouse gases have seen slight declines over the past decade. These emission inventories are based on counts of equipment and operational activities (activity factors), multiplied by average emission factors, and therefore are subject to uncertainties in these factors. Although uncertainties associated with activity data and missing emission source types can be significant, multiple recent measurement studies indicate that the greatest uncertainties are associated with emission factors. In many source categories, small groups of devices or sites, referred to as super-emitters, contribute a large fraction of emissions. When super-emitters are accounted for, multiple measurement approaches, at multiple scales, produce similar results for estimated emissions. Challenges moving forward include identifying super-emitters and reducing their emission magnitudes. Work done to date suggests that both equipment malfunction and operational practices can be important. Finally, although most of this review focuses on emissions from energy supply infrastructures, the regional air quality implications of some coupled energy production and use scenarios are examined. These case studies suggest that both energy production and use should be considered in assessing air quality implications of changes in energy infrastructures, and that impacts are likely to vary among regions. The energy supply infrastructure in the United States has been changing dramatically over the past decade, leading to changes in emissions from oil and natural gas supply chain sources. In many source categories along these supply chains, small groups of devices or sites, referred to as super-emitters, contribute a large fraction of emissions. Effective emission reductions will require technologies for both identifying super-emitters and reducing their emission magnitudes.

Anthropogenic emissions of methane in the United States

PubMed Central

Miller, Scot M.; Wofsy, Steven C.; Michalak, Anna M.; Kort, Eric A.; Andrews, Arlyn E.; Biraud, Sebastien C.; Dlugokencky, Edward J.; Eluszkiewicz, Janusz; Fischer, Marc L.; Janssens-Maenhout, Greet; Miller, Ben R.; Miller, John B.; Montzka, Stephen A.; Nehrkorn, Thomas; Sweeney, Colm

2013-01-01

This study quantitatively estimates the spatial distribution of anthropogenic methane sources in the United States by combining comprehensive atmospheric methane observations, extensive spatial datasets, and a high-resolution atmospheric transport model. Results show that current inventories from the US Environmental Protection Agency (EPA) and the Emissions Database for Global Atmospheric Research underestimate methane emissions nationally by a factor of ∼1.5 and ∼1.7, respectively. Our study indicates that emissions due to ruminants and manure are up to twice the magnitude of existing inventories. In addition, the discrepancy in methane source estimates is particularly pronounced in the south-central United States, where we find total emissions are ∼2.7 times greater than in most inventories and account for 24 ± 3% of national emissions. The spatial patterns of our emission fluxes and observed methane–propane correlations indicate that fossil fuel extraction and refining are major contributors (45 ± 13%) in the south-central United States. This result suggests that regional methane emissions due to fossil fuel extraction and processing could be 4.9 ± 2.6 times larger than in EDGAR, the most comprehensive global methane inventory. These results cast doubt on the US EPA’s recent decision to downscale its estimate of national natural gas emissions by 25–30%. Overall, we conclude that methane emissions associated with both the animal husbandry and fossil fuel industries have larger greenhouse gas impacts than indicated by existing inventories. PMID:24277804

GLYCOL DEHYDRATOR BTEX AND VOC EMISSIONS TESTING RESULTS AT TWO UNITS IN TEXAS AND LOUISIANA VOL. II: APPENDICES

EPA Science Inventory

The report gives results of the collection of emissions test data st two triethylene glycol units to provide data for the comparison to GRI-GLYCalc, a computer program developed to estimate emissions from glycol dehydrators. [NOTE: Glycol dehydrators are used in the natural gas i...

GLYCOL DEHYDRATOR BTEX AND VOC EMISSIONS TESTING RESULTS AT TWO UNITS IN TEXAS AND LOUISIANA VOL. I: TECHNICAL REPORT

EPA Science Inventory

The report gives results of the collection of emissions tests data at two triethylene glycol units to provide data for comparison to GRI-GLYCalc, a computer program developed to estimate emissions from glycol dehydrators. (NOTE: Glycol dehydrators are used in the natural gas indu...

40 CFR 98.162 - GHGs to report.

Code of Federal Regulations, 2010 CFR

2010-07-01

... GREENHOUSE GAS REPORTING Hydrogen Production § 98.162 GHGs to report. You must report: (a) CO2 process emissions from each hydrogen production process unit. (b) CO2, CH4 and N2O combustion emissions from each hydrogen production process unit. You must calculate and report these combustion emissions under subpart C...

40 CFR 63.1567 - What are my requirements for inorganic HAP emissions from catalytic reforming units?

Code of Federal Regulations, 2011 CFR

2011-07-01

... reactors in the catalytic reforming unit are regenerated in separate regeneration systems, then these emission limitations apply to each separate regeneration system. These emission limitations apply to... rejuvenation operations during coke burn-off and catalyst regeneration. You can choose from the two options in...

40 CFR 76.14 - Monitoring, recordkeeping, and reporting.

Code of Federal Regulations, 2011 CFR

2011-07-01

... NOX emission control system to the owner or operator showing that such system was designed to meet the... emission control system that were not included in the design specifications and performance guarantee, but... regard to the following types of Group 1, Phase I units: (i) Units employing no new NOX emission control...

40 CFR 76.14 - Monitoring, recordkeeping, and reporting.

Code of Federal Regulations, 2012 CFR

2012-07-01

... NOX emission control system to the owner or operator showing that such system was designed to meet the... emission control system that were not included in the design specifications and performance guarantee, but... regard to the following types of Group 1, Phase I units: (i) Units employing no new NOX emission control...

40 CFR 76.14 - Monitoring, recordkeeping, and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... NOX emission control system to the owner or operator showing that such system was designed to meet the... emission control system that were not included in the design specifications and performance guarantee, but... regard to the following types of Group 1, Phase I units: (i) Units employing no new NOX emission control...

Particulate matter and black carbon optical properties and emission factors from prescribed fires in the southeastern United States

EPA Science Inventory

The aerosol emissions from prescribed fires in the Southeastern United States were measured and compared to emissions from laboratory burns with fuels collected from the site. Fine particulate matter (PM2.5), black carbon, and aerosol light scattering and absorption were characte...

40 CFR 96.75 - Petitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... subject to an Acid Rain emissions limitation may submit a petition under § 75.66 of this chapter to the... account representative of a NOX Budget unit that is not subject to an Acid Rain emissions limitation may... account representative of a NOX Budget unit that is subject to an Acid Rain emissions limitation may...

40 CFR 96.75 - Petitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... subject to an Acid Rain emissions limitation may submit a petition under § 75.66 of this chapter to the... account representative of a NOX Budget unit that is not subject to an Acid Rain emissions limitation may... account representative of a NOX Budget unit that is subject to an Acid Rain emissions limitation may...

40 CFR 96.75 - Petitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... subject to an Acid Rain emissions limitation may submit a petition under § 75.66 of this chapter to the... account representative of a NOX Budget unit that is not subject to an Acid Rain emissions limitation may... account representative of a NOX Budget unit that is subject to an Acid Rain emissions limitation may...

40 CFR 96.75 - Petitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... subject to an Acid Rain emissions limitation may submit a petition under § 75.66 of this chapter to the... account representative of a NOX Budget unit that is not subject to an Acid Rain emissions limitation may... account representative of a NOX Budget unit that is subject to an Acid Rain emissions limitation may...

40 CFR 96.75 - Petitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... subject to an Acid Rain emissions limitation may submit a petition under § 75.66 of this chapter to the... account representative of a NOX Budget unit that is not subject to an Acid Rain emissions limitation may... account representative of a NOX Budget unit that is subject to an Acid Rain emissions limitation may...

40 CFR 60.47b - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.47b Emission monitoring for sulfur dioxide... generating unit and analyzing them for sulfur and heat content according to Method 19 of appendix A of this...

40 CFR 60.47b - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.47b Emission monitoring for sulfur dioxide... generating unit and analyzing them for sulfur and heat content according to Method 19 of appendix A of this...

40 CFR 60.47b - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.47b Emission monitoring for sulfur dioxide... generating unit and analyzing them for sulfur and heat content according to Method 19 of appendix A of this...

40 CFR 60.47b - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.47b Emission monitoring for sulfur dioxide... generating unit and analyzing them for sulfur and heat content according to Method 19 of appendix A of this...

40 CFR 60.47b - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Emission monitoring for sulfur dioxide... Industrial-Commercial-Institutional Steam Generating Units § 60.47b Emission monitoring for sulfur dioxide... generating unit and analyzing them for sulfur and heat content according to Method 19 of appendix A of this...

Unpolarized infrared emissivity with shadow from anisotropic rough sea surfaces with non-Gaussian statistics.

PubMed

Bourlier, Christophe

2005-07-10

The emissivity of two-dimensional anisotropic rough sea surfaces with non-Gaussian statistics is investigated. The emissivity derivation is of importance for retrieval of the sea-surface temperature or equivalent temperature of a rough sea surface by infrared thermal imaging. The well-known Cox-Munk slope probability-density function, considered non-Gaussian, is used for the emissivity derivation, in which the skewness and the kurtosis (related to the third- and fourth-order statistics, respectively) are included. The shadowing effect, which is significant for grazing angles, is also taken into account. The geometric optics approximation is assumed to be valid, which means that the rough surface is modeled as a collection of facets reflecting locally the light in the specular direction. In addition, multiple reflections are ignored. Numerical results of the emissivity are presented for Gaussian and non-Gaussian statistics, for moderate wind speeds, for near-infrared wavelengths, for emission angles ranging from 0 degrees (nadir) to 90 degrees (horizon), and according to the wind direction. In addition, the emissivity is compared with both measurements and a Monte Carlo ray-tracing method.

A novel methodology to quantify nitrous oxide emissions from full-scale wastewater treatment systems with surface aerators.

PubMed

Ye, Liu; Ni, Bing-Jie; Law, Yingyu; Byers, Craig; Yuan, Zhiguo

2014-01-01

The quantification of nitrous oxide (N2O) emissions from open-surface wastewater treatment systems with surface aerators is difficult as emissions from the surface aerator zone cannot be easily captured by floating hoods. In this study, we propose and demonstrate a novel methodology to estimate N2O emissions from such systems through determination of the N2O transfer coefficient (kLa) induced by surface aerators based on oxygen balance for the entire system. The methodology is demonstrated through its application to a full-scale open oxidation ditch wastewater treatment plant with surface aerators. The estimated kLa profile based on a month-long measurement campaign for oxygen balance, intensive monitoring of dissolved N2O profiles along the oxidation ditch over a period of four days, together with mathematical modelling, enabled to determine the N2O emission factor from this treatment plant (0.52 ± 0.16%). Majority of the N2O emission was found to occur in the surface aerator zone, which would be missed if the gas hood method was applied alone. Copyright © 2013 Elsevier Ltd. All rights reserved.

3D-CFD analysis of diffusion and emission of VOCs in a FLEC cavity.

PubMed

Zhu, Q; Kato, S; Murakami, S; Ito, K

2007-06-01

This study is performed as a part of research that examines the emission and diffusion characteristics of volatile organic compounds (VOCs) from indoor building materials. In this paper, the flow field and the emission field of VOCs from the surface of building materials in a Field and Laboratory Emission Cell (FLEC) cavity are examined by 3D Computational Fluid Dynamics (CFD) analysis. The flow field within the FLEC cavity is laminar. With a total flow of 250 ml/min, the air velocity near the test material surface ranges from 0.1 to 4.5 cm/s. Three types of emission from building materials are studied here: (i) emission phenomena controlled by internal diffusion, (ii) emission phenomena controlled by external diffusion, and (iii) emission phenomena controlled by mixed diffusion (internal + external diffusion). In the case of internal diffusion material, with respect to the concentration distribution in the cavity, the local VOC emission rate becomes uniform and the FLEC works well. However, in the case of evaporation type (external diffusion) material, or mixed type materials (internal + external diffusion) when the resistance to transporting VOCs in the material is small, the FLEC is not suitable for emission testing because of the thin FLEC cavity. In this case, the mean emission rate is restricted to a small value, since the VOC concentration in the cavity rises to the same value as the surface concentration through molecular diffusion within the thin cavity, and the concentration gradient normal to the surface becomes small. The diffusion field and emission rate depend on the cavity concentration and on the Loading Factor. That is, when the testing material surface in the cavity is partially sealed to decrease the Loading Factor, the emission rate become higher with the decrease in the exposed area of the testing material. The flow field and diffusion field within the FLEC cavity are investigated by CFD method. After presenting a summary of the velocity distributed over the surface of test material and the emission properties of different type materials in FLEC, the paper pointed out that there is a bias in the airflow inside the FLEC cavity but do not influence the result of test emission rate, and the FLEC method is unsuitable for evaporation type materials in which the mass transfer of the surface controls the emission rate.

40 CFR Table 5 to Subpart Jjj of... - Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... Existing Small Municipal Waste Combustion Units 5 Table 5 to Subpart JJJ of Part 62 Protection of... Combustion Units Constructed on or Before August 30, 1999 Pt. 62, Subpt. JJJ, Table 5 Table 5 to Subpart JJJ of Part 62—Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units...

40 CFR Table 5 to Subpart Jjj of... - Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Existing Small Municipal Waste Combustion Units 5 Table 5 to Subpart JJJ of Part 62 Protection of... Combustion Units Constructed on or Before August 30, 1999 Pt. 62, Subpt. JJJ, Table 5 Table 5 to Subpart JJJ of Part 62—Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units...

40 CFR Table 5 to Subpart Jjj of... - Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... Existing Small Municipal Waste Combustion Units 5 Table 5 to Subpart JJJ of Part 62 Protection of... Combustion Units Constructed on or Before August 30, 1999 Pt. 62, Subpt. JJJ, Table 5 Table 5 to Subpart JJJ of Part 62—Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units...

40 CFR Table 5 to Subpart Jjj of... - Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... Existing Small Municipal Waste Combustion Units 5 Table 5 to Subpart JJJ of Part 62 Protection of... Combustion Units Constructed on or Before August 30, 1999 Pt. 62, Subpt. JJJ, Table 5 Table 5 to Subpart JJJ of Part 62—Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units...

40 CFR Table 5 to Subpart Jjj of... - Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Existing Small Municipal Waste Combustion Units 5 Table 5 to Subpart JJJ of Part 62 Protection of... Combustion Units Constructed on or Before August 30, 1999 Pt. 62, Subpt. JJJ, Table 5 Table 5 to Subpart JJJ of Part 62—Carbon Monoxide Emission Limits for Existing Small Municipal Waste Combustion Units...

40 CFR 63.7522 - Can I use emissions averaging to comply with this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... section. You may not include new boilers or process heaters in an emissions average. (b) For a group of... subcategory of units designed to burn gas 2 (other) fuels. (iv) You may not average across the units designed to burn liquid, units designed to burn solid fuel, and units designed to burn gas 2 (other...

40 CFR Table 6 to Subpart Cccc of... - Emission Limitations for Energy Recovery Units That Commenced Construction After June 4, 2010, or...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Recovery Units That Commenced Construction After June 4, 2010, or That Commenced Reconstruction or... Standards of Performance for Commercial and Industrial Solid Waste Incineration Units Pt. 60, Subpt. CCCC, Table 6 Table 6 to Subpart CCCC of Part 60—Emission Limitations for Energy Recovery Units That Commenced...

Spatial and temporal patterns of dust emissions (2004-2012) in semi-arid landscapes, southeastern Utah, USA

USGS Publications Warehouse

Flagg, Cody B.; Neff, Jason C.; Reynolds, Richard L.; Belnap, Jayne

2013-01-01

Aeolian dust can influence nutrient availability, soil fertility, plant interactions, and water-holding capacity in both source and downwind environments. A network of 85 passive collectors for aeolian sediment spanning numerous plant communities, soil types, and land-use histories covering approximately 4000 square kilometers across southeastern Utah was used to sample horizontal emissions of aeolian sediment. The sample archive dates to 2004 and is currently the largest known record of field-scale dust emissions for the southwestern United States. Sediment flux peaked during the spring months in all plant communities (mean: 38.1 g m−2 d−1), related to higher, sustained wind speeds that begin in the early spring. Dust flux was lowest during the winter period (mean: 5 g m−2 d−1) when surface wind speeds are typically low. Sites dominated by blackbrush and sagebrush shrubs had higher sediment flux (mean: 19.4 g m−2 d−1) compared to grasslands (mean: 11.2 g m−2 d−1), saltbush shrublands (mean: 10.3 g m−2 d−1), and woodlands (mean: 8.1 g m−2 d−1). Contrary to other studies on dust emissions, antecedent precipitation during one, two, and three seasons prior to sample collection did not significantly influence emission rates. Physical site-scale factors controlling dust emissions were complex and varied from one vegetation type to another.

C-H Hot Bands in the Near-IR Emission Spectra of Leonids

NASA Technical Reports Server (NTRS)

Freund, F. T.; Scoville, J.; Holm, R.; Seelemann, R.; Freund, M. M.

2002-01-01

The reported infrared (IR) emission spectra from 1999 Leonid fireballs show a 3.4 micron C-H emission band and unidentified bands at longer wavelengths. Upon atmospheric entry, the Leonid meteorites were flash-heated to temperatures around 2400K, which would destroy any organics on the surface of the meteorite grains. We propose that the nu(sub )CH emission band in the Leonid emission spectra arises from matrix-embedded C(sub n)-H-O entities that are protected from instant pyrolysis. Our model is based on IR absorption nu(sub )CH bands, which we observed in laboratory-grown MgO and natural olivine single crystals, where they arise from C(sub n)-H-O units imbedded in the mineral matrix, indicative of aliphatic -CH2- and -CH3 organics. Instead of being pyrolyzed, the C(sub n)-H-O entities in the Leonid trails become vibrationally excited to higher levels n = 1, 2, 3 etc. During de-excitation they emit at 3.4 microns, due to the (0 => 1) transition, and at longer wavelengths, due to hot bands. As a first step toward verifying this hypothesis we measured the C-H vibrational manifold of hexane (C6H14). The calculated positions of the (2 => l ) , (3 => 2), and possibly (4 => 3) hot bands agree with the Leonid emission bands at 3.5, 3.8 and 4.l microns.

Radiative forcing associated with particulate carbon emissions resulting from the use of mercury control technology.

PubMed

Lin, Guangxing; Penner, Joyce E; Clack, Herek L

2014-09-02

Injection of powdered activated carbon (PAC) adsorbents into the flue gas of coal fired power plants with electrostatic precipitators (ESPs) is the most mature technology to control mercury emissions for coal combustion. However, the PAC itself can penetrate ESPs to emit into the atmosphere. These emitted PACs have similar size and optical properties to submicron black carbon (BC) and thus could increase BC radiative forcing unintentionally. The present paper estimates, for the first time, the potential emission of PAC together with their climate forcing. The global average maximum potential emissions of PAC is 98.4 Gg/yr for the year 2030, arising from the assumed adoption of the maximum potential PAC injection technology, the minimum collection efficiency, and the maximum PAC injection rate. These emissions cause a global warming of 2.10 mW m(-2) at the top of atmosphere and a cooling of -2.96 mW m(-2) at the surface. This warming represents about 2% of the warming that is caused by BC from direct fossil fuel burning and 0.86% of the warming associated with CO2 emissions from coal burning in power plants. Its warming is 8 times more efficient than the emitted CO2 as measured by the 20-year-integrated radiative forcing per unit of carbon input (the 20-year Global Warming Potential).

Directional Thermal Emission and Absorption from Surface Microstructures in Metalized Plastics

DTIC Science & Technology

2013-09-01

conductive surfaces for directional emission is presented. First, key accomplishments in exploiting surface plasmons for coherent thermal emission from...than as an absorbing coating . In the 2005 design proposed by Lee et al., thermally excited surface waves at a silicon carbide to photonic crystal stack...sufficiently to significantly effect the film durability and thermal conductivity , the profile of the cavity begins to change shape. Although a case

Springtime high surface ozone events over the western United States: Quantifying the role of stratospheric intrusions

NASA Astrophysics Data System (ADS)

Fiore, A. M.; Lin, M.; Cooper, O. R.; Horowitz, L. W.; Naik, V.; Levy, H.; Langford, A. O.; Johnson, B. J.; Oltmans, S. J.; Senff, C. J.

2011-12-01

As the National Ambient Air Quality (NAAQS) standard for ozone (O_{3}) is lowered, it pushes closer to policy-relevant background levels (O_{3} concentrations that would exist in the absence of North American anthropogenic emissions), making attainment more difficult with local controls. We quantify the Asian and stratospheric components of this North American background, with a primary focus on the western United States. Prior work has identified this region as a hotspot for deep stratospheric intrusions in spring. We conduct global simulations at 200 km and 50 km horizontal resolution with the GFDL AM3 model, including a stratospheric O_{3} tracer and two sensitivity simulations with anthropogenic emissions from Asia and North America turned off. The model is evaluated with a suite of in situ and satellite measurements during the NOAA CalNex campaign (May-June 2010). The model reproduces the principle features in the observed surface to near tropopause distribution of O_{3} along the California coast, including its latitudinal variation and the development of regional high-O_{3} episodes. Four deep tropopause folds are diagnosed and we find that the remnants of these stratospheric intrusions are transported to the surface of Southern California and Western U.S. Rocky Mountains, contributing 10-30 ppbv positive anomalies relative to the simulated campaign mean stratospheric component in the model surface layer. We further examine the contribution of North American background, including its stratospheric and Asian components, to the entire distribution of observed MDA8 O_{3} at 12 high-elevation CASTNet sites in the Mountain West. We find that the stratospheric O_{3} tracer constitutes 50% of the North American background, and can enhance surface maximum daily 8-hour average (MDA8) O_{3} by 20 ppb when observed surface O_{3} is in the range of 60-80 ppbv. Our analysis highlights the potential for natural sources such as deep stratospheric intrusions to contribute to high surface O_{3} episodes in the western U.S., representing a major challenge if the NAAQS were to be tightened. We further demonstrate the potential for using satellite (AIRS and OMI) measurements of total column O_{3} to develop space-based criteria to define these exceptional events in support of regional air quality management.

Global Emissions of Refrigerants HCFC-22 and HFC-134a: Unforeseen Seasonal Contributions

NASA Astrophysics Data System (ADS)

Xiang, B.; Patra, P. K.; Montzka, S. A.; Miller, S. M.; Elkins, J. W.; Moore, F.; Atlas, E. L.; Miller, B. R.; Prinn, R. G.; Wofsy, S. C.

2014-12-01

HCFC-22 (CHClF2) and HFC-134a (CH2FCF3) are two major gases currently used worldwide in domestic and commercial refrigeration and air conditioning. HCFC-22 contributes to stratospheric ozone depletion and both species are potent greenhouse gases, and their global emissions continue to rise at the present. In this work, we study aircraft based in-situ observations of HCFC-22 and HFC-134a over the Pacific Ocean in a three-year span (HIaper Pole-to-Pole Observation of carbon cycle and greenhouse gases study, HIPPO 2009-2011) and combine these data with long-term observations from global surface sites (NOAA and AGAGE networks). We find a steady increase in global annual emissions of HCFC-22 and HFC-134a for the past two decades (on average 3% and 4% per year, respectively). Emissions of HFC-134a since 2000 are consistently higher, with 60% more in recent years (2009-2011), compared to the United Nations Framework Convention on Climate Change (UNFCCC) inventory. Using both HIPPO and surface data, we quantify and verify enhanced summertime emissions of HFC-134a and HCFC-22 that are about three times those in the wintertime. This unforeseen large seasonal contribution indicates unaccounted mechanisms controlling refrigerant gas emissions, missing in the existing inventory estimates. Possible mechanisms for greater refrigerant leakages in the summer are: 1) higher vapor pressure in the sealed compartment of the system at summer high temperatures (saturated vapor pressure is ~ 3 times at 303 K compared to that at 273 K for both species), and 2) more frequent use of refrigeration and air conditioners in the summer (vapor pressure in the compressor line is higher when in use than not in use). Our results suggest that the engineering of the refrigeration and air conditioning systems can greatly influence the release of these two species to the atmosphere.

Will the California Current lose its nesting Tufted Puffins?

PubMed Central

Kelly, Ryan P.; Pearson, Scott F.

2018-01-01

Tufted Puffin (Fratercula cirrhata) populations have experienced dramatic declines since the mid-19th century along the southern portion of the species range, leading citizen groups to petition the United States Fish and Wildlife Service (USFWS) to list the species as endangered in the contiguous US. While there remains no consensus on the mechanisms driving these trends, population decreases in the California Current Large Marine Ecosystem suggest climate-related factors, and in particular the indirect influence of sea-surface temperature on puffin prey. Here, we use three species distribution models (SDMs) to evaluate projected shifts in habitat suitable for Tufted Puffin nesting for the year 2050 under two future Intergovernmental Panel on Climate Change (IPCC) emission scenarios. Ensemble model results indicate warming marine and terrestrial temperatures play a key role in the loss of suitable Tufted Puffin nesting conditions in the California Current under both business-as-usual (RCP 8.5) and moderated (RCP 4.5) carbon emission scenarios, and in particular, that mean summer sea-surface temperatures greater than 15 °C are likely to make habitat unsuitable for breeding. Under both emission scenarios, ensemble model results suggest that more than 92% of currently suitable nesting habitat in the California Current is likely to become unsuitable. Moreover, the models suggest a net loss of greater than 21% of suitable nesting sites throughout the entire North American range of the Tufted Puffin, regardless of emission-reduction strategies. These model results highlight continued Tufted Puffin declines—particularly among southern breeding colonies—and indicate a significant risk of near-term extirpation in the California Current Large Marine Ecosystem. PMID:29593940

Will the California Current lose its nesting Tufted Puffins?

PubMed

Hart, Christopher J; Kelly, Ryan P; Pearson, Scott F

2018-01-01

Tufted Puffin ( Fratercula cirrhata ) populations have experienced dramatic declines since the mid-19th century along the southern portion of the species range, leading citizen groups to petition the United States Fish and Wildlife Service (USFWS) to list the species as endangered in the contiguous US. While there remains no consensus on the mechanisms driving these trends, population decreases in the California Current Large Marine Ecosystem suggest climate-related factors, and in particular the indirect influence of sea-surface temperature on puffin prey. Here, we use three species distribution models (SDMs) to evaluate projected shifts in habitat suitable for Tufted Puffin nesting for the year 2050 under two future Intergovernmental Panel on Climate Change (IPCC) emission scenarios. Ensemble model results indicate warming marine and terrestrial temperatures play a key role in the loss of suitable Tufted Puffin nesting conditions in the California Current under both business-as-usual (RCP 8.5) and moderated (RCP 4.5) carbon emission scenarios, and in particular, that mean summer sea-surface temperatures greater than 15 °C are likely to make habitat unsuitable for breeding. Under both emission scenarios, ensemble model results suggest that more than 92% of currently suitable nesting habitat in the California Current is likely to become unsuitable. Moreover, the models suggest a net loss of greater than 21% of suitable nesting sites throughout the entire North American range of the Tufted Puffin, regardless of emission-reduction strategies. These model results highlight continued Tufted Puffin declines-particularly among southern breeding colonies-and indicate a significant risk of near-term extirpation in the California Current Large Marine Ecosystem.

Highly elevated atmospheric levels of volatile organic compounds in the Uintah Basin, Utah.

PubMed

Helmig, D; Thompson, C R; Evans, J; Boylan, P; Hueber, J; Park, J-H

2014-05-06

Oil and natural gas production in the Western United States has grown rapidly in recent years, and with this industrial expansion, growing environmental concerns have arisen regarding impacts on water supplies and air quality. Recent studies have revealed highly enhanced atmospheric levels of volatile organic compounds (VOCs) from primary emissions in regions of heavy oil and gas development and associated rapid photochemical production of ozone during winter. Here, we present surface and vertical profile observations of VOC from the Uintah Basin Winter Ozone Studies conducted in January-February of 2012 and 2013. These measurements identify highly elevated levels of atmospheric alkane hydrocarbons with enhanced rates of C2-C5 nonmethane hydrocarbon (NMHC) mean mole fractions during temperature inversion events in 2013 at 200-300 times above the regional and seasonal background. Elevated atmospheric NMHC mole fractions coincided with build-up of ambient 1-h ozone to levels exceeding 150 ppbv (parts per billion by volume). The total annual mass flux of C2-C7 VOC was estimated at 194 ± 56 × 10(6) kg yr(-1), equivalent to the annual VOC emissions of a fleet of ∼100 million automobiles. Total annual fugitive emission of the aromatic compounds benzene and toluene, considered air toxics, were estimated at 1.6 ± 0.4 × 10(6) and 2.0 ± 0.5 × 10(6) kg yr(-1), respectively. These observations reveal a strong causal link between oil and gas emissions, accumulation of air toxics, and significant production of ozone in the atmospheric surface layer.

Test Report Emission Test Program EPA Information Collection Request for Delayed Coking Units 736 Coker Unit

EPA Pesticide Factsheets

ARI Environmental, Inc. (ARI) was retained by Houston Refining LP (HRO) to conduct an emission test program at their refinery located in Houston, Texas. The testing was conducted on on the 736 Delayed Coking Unit (DCU) in response to EPA's ICR.

Mapping 1995 global anthropogenic emissions of mercury

NASA Astrophysics Data System (ADS)

Pacyna, Jozef M.; Pacyna, Elisabeth G.; Steenhuisen, Frits; Wilson, Simon

This paper presents maps of anthropogenic Hg emissions worldwide within a 1°×1° latitude/longitude grid system in 1995. As such, the paper is designed for modelers simulating the Hg transport within air masses and Hg deposition to aquatic and terrestrial ecosystems. Maps of total Hg emissions and its three main chemical species: elemental gaseous Hg, divalent gaseous Hg, and particle-associated Hg are presented. The main emissions occur in southeast Asia (particularly in China), South Africa, Central and Eastern Europe, and the Eastern United States. These are the regions where coal combustion is the main source of electricity and heat production. Waste incineration adds to these emissions in the Eastern United States. Emissions of total Hg and its three species are quite similar in terms of their (global) spatial distributions. They reflect the worldwide distribution of coal consumption in large power plants, industrial burners, and small combustion units, such as residential and commercial furnaces.

Odour and ammonia emissions from intensive poultry units in Ireland.

PubMed

Hayes, E T; Curran, T P; Dodd, V A

2006-05-01

Odour and ammonia emissions were measured from three broiler, two layer and two turkey houses in Ireland. The broiler units gave a large range of odour and ammonia emission rates depending on the age of the birds and the season. A considerable variation between the odour and ammonia emission rates was evident for the two layer units which may have been due to the different manure handling systems utilised in the houses. There was relatively little difference in the odour and ammonia emissions from the two turkey houses. As a precautionary principle, odour emission rates utilised in atmospheric dispersion models should use the maximum values for broilers and turkeys (1.22 and 10.5 ou(E) s(-1) bird(-1) respectively) and the mean value for the layers depending on the manure handling system used (0.47 or 1.35 ou(E) s(-1) bird(-1)).

Soil moisture, dielectric permittivity and emissivity of soil: effective depth of emission measured by the L-band radiometer ELBARA

NASA Astrophysics Data System (ADS)

Usowicz, Boguslaw; Lukowski, Mateusz; Marczewski, Wojciech; Usowicz, Jerzy; Lipiec, Jerzy; Rojek, Edyta; Slominska, Ewa; Slominski, Jan

2014-05-01

Due to the large variation of soil moisture in space and in time, obtaining soil water balance with an aid of data acquired from the surface is still a challenge. Microwave remote sensing is widely used to determine the water content in soil. It is based on the fact that the dielectric constant of the soil is strongly dependent on its water content. This method provides the data in both local and global scales. Very important issue that is still not solved, is the soil depth at which radiometer "sees" the incoming radiation and how this "depth of view" depends on water content and physical properties of soil. The microwave emission comes from its entire profile, but much of this energy is absorbed by the upper layers of soil. As a result, the contribution of each layer to radiation visible for radiometer decreases with depth. The thickness of the surface layer, which significantly contributes to the energy measured by the radiometer is defined as the "penetration depth". In order to improve the physical base of the methodology of soil moisture measurements using microwave remote sensing and to determine the effective emission depth seen by the radiometer, a new algorithm was developed. This algorithm determines the reflectance coefficient from Fresnel equations, and, what is new, the complex dielectric constant of the soil, calculated from the Usowicz's statistical-physical model (S-PM) of dielectric permittivity and conductivity of soil. The model is expressed in terms of electrical resistance and capacity. The unit volume of soil in the model consists of solid, water and air, and is treated as a system made up of spheres, filling volume by overlapping layers. It was assumed that connections between layers and spheres in the layer are represented by serial and parallel connections of "resistors" and "capacitors". The emissivity of the soil surface is calculated from the ratio between the brightness temperature measured by the ELBARA radiometer (GAMMA Remote Sensing AG) and the physical temperature of the soil surface measured by infrared sensor. As the input data for S-PM: volumes of soil components, mineralogical composition, organic matter content, specific surface area and bulk density of the soil were used. Water contents in the model are iteratively changed, until emissivities calculated from the S-PM reach the best agreement with emissivities measured by the radiometer. Final water content will correspond to the soil moisture measured by the radiometer. Then, the examined soil profile will be virtually divided into thin slices where moisture, temperature and thermal properties will be measured and simultaneously modelled via S-PM. In the next step, the slices will be "added" starting from top (soil surface), until the effective soil moisture will be equal to the soil moisture measured by ELBARA. The thickness of obtained stack will be equal to desired "penetration depth". Moreover, it will be verified further by measuring the moisture content using thermal inertia. The work was partially funded by the Government of Poland through an ESA Contract under the PECS ELBARA_PD project No. 4000107897/13/NL/KML.

Ecological Controls on N2O Emission in Surface Litter and Near-surface Soil of a Managed Grassland: Modelling and Measurements

NASA Astrophysics Data System (ADS)

Grant, Robert; Neftel, Albrecht; Calanca, Pierluigi

2016-04-01

Large variability in N2O emissions from managed grasslands may occur because most emissions originate in surface litter or near-surface soil where variability in soil water content (q) and temperature (Ts) is greatest. To determine whether temporal variability in q and Ts of surface litter and near-surface soil could explain that in N2O emissions, a simulation experiment was conducted with ecosys, a comprehensive mathematical model of terrestrial ecosystems in which processes governing N2O emissions were represented at high temporal and spatial resolution. Model performance was verified by comparing N2O emissions, CO2 and energy exchange, and q and Ts modelled by ecosys with those measured by automated chambers, eddy covariance (EC) and soil sensors at an hourly time-scale during several emission events from 2004 to 2009 in an intensively managed pasture at Oensingen, Switzerland. Both modelled and measured events were induced by precipitation following harvesting and subsequent fertilizing or manuring. These events were brief (2 - 5 days) with maximum N2O effluxes that varied from < 1 mg N m-2 h-1 in early spring and autumn to > 3 mg N m-2 h-1 in summer. Only very small emissions were modelled or measured outside these events. In the model, emissions were generated almost entirely in surface litter or near-surface (0 - 2 cm) soil, at rates driven by N availability with fertilization vs. N uptake with grassland regrowth, and by O2 limitation from wetting relative to O2 demand from respiration. In the model, NOx availability relative to O2 limitation governed both the reduction of more oxidized electron acceptors to N2O and the reduction of N2O to N2, so that the magnitude of N2O emissions was not simply related to surface and near-surface q and Ts. Modelled N2O emissions were found to be sensitive to defoliation intensity and timing (relative to that of fertilization) which controlled plant N uptake and soil q and Ts prior to and during emission events. In a model sensitivity study, reducing LAI remaining after defoliation to one-half that under current practice and delaying harvesting by 5 days raised N2O emissions by as much as 80% during subsequent events and by an average of 43% annually. The global warming potential from annual N2O emissions in this intensively managed grassland largely offset those from net C uptake in both modelled and field experiments. However model results indicated that this offset could be adversely affected by suboptimal harvest intensity and timing.

Exciplex-like emission from a closely-spaced, orthogonally-sited anthracenyl-boron dipyrromethene (Bodipy) molecular dyad.

PubMed

Benniston, Andrew C; Harriman, Anthony; Whittle, Victoria L; Zelzer, Mischa; Harrington, Ross W; Clegg, William

2010-07-30

A molecular dyad, , has been prepared that incorporates a boron dipyrromethene (Bodipy) group functionalized at the meso position with an anthracenyl unit. Emission from the dyad contains contributions from both localized fluorescence from the Bodipy unit and exciplex-like emission associated with an intramolecular charge-transfer state. The peak position, intensity and lifetime of this exciplex emission are solvent dependent and the shift in the emission maximum shows a linear relationship to the solvent polarity function (Deltaf). The calculated dipole moment for the exciplex is 22.5 +/- 2.2 D. The radiative rate constant (k(RAD)) for exciplex emission decreases progressively with increasing solvent polarity. In this latter case, k(RAD) shows an obvious dependence on the energy gap between the exciplex state and the first-excited singlet state resident on the Bodipy unit. The emission characteristics for dissolved in perfluorooctane are used to characterize the refractive index and dielectric constant of the solvent.

Field emission study of carbon nanostructures

NASA Astrophysics Data System (ADS)

Zhao, Xin

Recently, carbon nanosheets (CNS), a novel nanostructure, were developed in our laboratory as a field emission source for high emission current. To characterize, understand and improve the field emission properties of CNS, a ultra-high vacuum surface analysis system was customized to conduct relevant experimental research in four distinct areas. The system includes Auger electron spectroscopy (AES), field emission energy spectroscopy (FEES), field emission I-V testing, and thermal desorption spectroscopy (TDS). Firstly, commercial Mo single tips were studied to calibrate the customized system. AES and FEES experiments indicate that a pyramidal nanotip of Ca and O elements formed on the Mo tip surface by field induced surface diffusion. Secondly, field emission I-V testing on CNS indicates that the field emission properties of pristine nanosheets are impacted by adsorbates. For instance, in pristine samples, field emission sources can be built up instantaneously and be characterized by prominent noise levels and significant current variations. However, when CNS are processed via conditioning (run at high current), their emission properties are greatly improved and stabilized. Furthermore, only H2 desorbed from the conditioned CNS, which indicates that only H adsorbates affect emission. Thirdly, the TDS study on nanosheets revealed that the predominant locations of H residing in CNS are sp2 hybridized C on surface and bulk. Fourthly, a fabricating process was developed to coat low work function ZrC on nanosheets for field emission enhancement. The carbide triple-peak in the AES spectra indicated that Zr carbide formed, but oxygen was not completely removed. The Zr(CxOy) coating was dispersed as nanobeads on the CNS surface. Although the work function was reduced, the coated CNS emission properties were not improved due to an increased beta factor. Further analysis suggest that for low emission current (<1 uA), the H adsorbates affect emission by altering the work function. In high emission current (>10 uA), thermal, ionic or electronic transition effects may occur, which differently affect the field emission process.

Modeling electron emission and surface effects from diamond cathodes

NASA Astrophysics Data System (ADS)

Dimitrov, D. A.; Smithe, D.; Cary, J. R.; Ben-Zvi, I.; Rao, T.; Smedley, J.; Wang, E.

2015-02-01

We developed modeling capabilities, within the Vorpal particle-in-cell code, for three-dimensional simulations of surface effects and electron emission from semiconductor photocathodes. They include calculation of emission probabilities using general, piece-wise continuous, space-time dependent surface potentials, effective mass, and band bending field effects. We applied these models, in combination with previously implemented capabilities for modeling charge generation and transport in diamond, to investigate the emission dependence on applied electric field in the range from approximately 2 MV/m to 17 MV/m along the [100] direction. The simulation results were compared to experimental data. For the considered parameter regime, conservation of transverse electron momentum (in the plane of the emission surface) allows direct emission from only two (parallel to [100]) of the six equivalent lowest conduction band valleys. When the electron affinity χ is the only parameter varied in the simulations, the value χ = 0.31 eV leads to overall qualitative agreement with the probability of emission deduced from experiments. Including band bending in the simulations improves the agreement with the experimental data, particularly at low applied fields, but not significantly. Using surface potentials with different profiles further allows us to investigate the emission as a function of potential barrier height, width, and vacuum level position. However, adding surface patches with different levels of hydrogenation, modeled with position-dependent electron affinity, leads to the closest agreement with the experimental data.

Multi-wavelength emissivity measurement of stainless steel substrate

NASA Astrophysics Data System (ADS)

Zhang, Y. F. F.; Dai, J. M. M.; Zhang, L.; Pan, W. D. D.

2013-01-01

The emissivity is a key parameter to measure the surface temperature of materials in the radiation thermometry. In this paper, the surface emissivity of metallic substrates is measured by the multi-wavelength emissivity measurement apparatus developed by the Harbin Institute of Technology (HIT). The measuring principle of this apparatus is based on the energy comparison. Several radiation thermometers, whose emissivity coefficients corrected by the measured emissivity from this apparatus, are used to measure the surface temperature of stainless steel substrates. The temperature values measured by means of radiation thermometry are compared to those measured by means of contact thermometry. The relative error between the two means is less than 2% at temperatures from 700K to 1300K, it suggests that the emissivity of stainless steel substrate measured by the multi-wavelength emissivity measurement apparatus are accurate and reliable. Emissivity measurements performed with this apparatus present an uncertainty of 5.9% (cover factor=2).

Far-infrared surface emissivity and climate.

PubMed

Feldman, Daniel R; Collins, William D; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

2014-11-18

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8-2.0 W m(-2) difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m(-2), and 15%, respectively, after only 25 y of integration. Additionally, the calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

Far-infrared surface emissivity and climate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldman, Daniel R.; Collins, William D.; Pincus, Robert

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

Far-infrared surface emissivity and climate

PubMed Central

Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

2014-01-01

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m−2 difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m−2, and 15%, respectively, after only 25 y of integration. Additionally, the calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change. PMID:25368189

Far-infrared surface emissivity and climate

DOE PAGES

Feldman, Daniel R.; Collins, William D.; Pincus, Robert; ...

2014-11-03

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

Environmental Impact of Minimally Invasive Surgery in the United States: An Estimate of the Carbon Dioxide Footprint

PubMed Central

Power, Nicholas E.; Silberstein, Jonathan L.; Ghoneim, Tarek P.; Guillonneau, Bertrand

2012-01-01

Abstract Purpose To attempt to quantitate the carbon footprint of minimally invasive surgery (MIS) through approximated scope 1 to 3 CO2 emissions to identify its potential role in global warming. Patients and Methods To estimate national usage, we determined the number of inpatient and outpatient MIS procedures using International Classification of Diseases, ninth revision-clinical modification codes for all MIS procedures in a 2009 sample collected in national databases. Need for surgery was considered essential, and therefore traditional open surgery was used as the comparator. Scope 1 (direct) CO2 emissions resulting from CO2 gas used for insufflation were based on both escaping procedural CO2 and metabolic CO2 eliminated via respiration. Scopes 2 and 3 (indirect) emissions related to capture, compression, and transportation of CO2 to hospitals and the disposal of single-use equipment not used in open surgery were calculated. Results The total CO2 emissions were calculated to be 355,924 tonnes/year. For perspective, if MIS in the United States was considered a country, it would rank 189th on the United Nations 2008 list of countries' carbon emissions per year. Limitations include the inability to account for uncertainty using the various models and tools for approximating CO2 emissions. Conclusion CO2 emission of MIS in the United States may have a significant environmental impact. This is the first attempt to quantify CO2 emissions related to MIS in the United States. Strategies for reduction, while maintaining high quality medical care, should be considered. PMID:22845049

Evaluation of the effect of accounting method, IPCC v. LCA, on grass-based and confinement dairy systems' greenhouse gas emissions.

PubMed

O'Brien, D; Shalloo, L; Patton, J; Buckley, F; Grainger, C; Wallace, M

2012-09-01

Life cycle assessment (LCA) and the Intergovernmental Panel on Climate Change (IPCC) guideline methodology, which are the principal greenhouse gas (GHG) quantification methods, were evaluated in this study using a dairy farm GHG model. The model was applied to estimate GHG emissions from two contrasting dairy systems: a seasonal calving pasture-based dairy farm and a total confinement dairy system. Data used to quantify emissions from these systems originated from a research study carried out over a 1-year period in Ireland. The genetic merit of cows modelled was similar for both systems. Total mixed ration was fed in the Confinement system, whereas grazed grass was mainly fed in the grass-based system. GHG emissions from these systems were quantified per unit of product and area. The results of both methods showed that the dairy system that emitted the lowest GHG emissions per unit area did not necessarily emit the lowest GHG emissions possible for a given level of product. Consequently, a recommendation from this study is that GHG emissions be evaluated per unit of product given the growing affluent human population and increasing demand for dairy products. The IPCC and LCA methods ranked dairy systems' GHG emissions differently. For instance, the IPCC method quantified that the Confinement system reduced GHG emissions per unit of product by 8% compared with the grass-based system, but the LCA approach calculated that the Confinement system increased emissions by 16% when off-farm emissions associated with primary dairy production were included. Thus, GHG emissions should be quantified using approaches that quantify the total GHG emissions associated with the production system, so as to determine whether the dairy system was causing emissions displacement. The IPCC and LCA methods were also used in this study to simulate, through a dairy farm GHG model, what effect management changes within both production systems have on GHG emissions. The findings suggest that single changes have a small mitigating effect on GHG emissions (<5%), except for strategies used to control emissions from manure storage in the Confinement system (14% to 24%). However, when several management strategies were combined, GHG emissions per unit of product could be reduced significantly (15% to 30%). The LCA method was identified as the preferred approach to assess the effect of management changes on GHG emissions, but the analysis indicated that further standardisation of the approach is needed given the sensitivity of the approach to allocation decisions regarding milk and meat.

Thermal properties of Rhea's Poles: Evidence for a Meter-Deep Unconsolidated Subsurface Layer

NASA Technical Reports Server (NTRS)

Howett, C. J. A.; Spencer, J. R.; Hurford, T.; Verbiscer, A.; Segura, M.

2016-01-01

Cassini's Composite Infrared Spectrometer (CIRS) observed both of Rhea's polar regions during a close (2000 km) flyby on 9th March 2013 during orbit 183. Rhea's southern pole was again observed during a more distant (51,000 km) flyby on 10th February 2015 during orbit 212. The results show Rhea's southern winter pole is one of the coldest places directly observed in our Solar System: surface temperatures of 25.4 +/-7.4 K and 24.7 +/-6.8 K are inferred from orbit 183 and 212 data, respectively. The surface temperature of the northern summer pole inferred from orbit 183 data is warmer: 66.6 +/-0.6 K. Assuming the surface thermophysical properties of the two polar regions are comparable then these temperatures can be considered a summer and winter seasonal temperature constraint for the polar region. Orbit 183 will provide solar longitude ( LS ) coverage at 133 deg and 313 deg for the summer and winter poles respectively, while orbit 212 provides an additional winter temperature constraint at LS 337 deg. Seasonal models with bolometric albedo values between 0.70 and 0.74 and thermal inertia values between 1 and 46 J m( exp -2) K( exp -1) s (exp -1/2) (otherwise known as MKS units) can provide adequate fits to these temperature constraints (assuming the winter temperature is an upper limit). Both these albedo and thermal inertia values agree within the uncertainties with those previously observed on both Rhea's leading and trailing hemispheres. Investigating the seasonal temperature change of Rhea's surface is particularly important, as the seasonal wave is sensitive to deeper surface temperatures ( approximately tens of centimeters to meter depths) than the more commonly reported diurnal wave (typically less than a centimeter), the exact depth difference dependent upon the assumed surface properties. For example, if a surface porosity of 0.5 and thermal inertia of 25 MKS is assumed then the depth of the seasonal thermal wave is 76 cm, which is much deeper than the approximately 0.5 cm probed by diurnal studies of Rhea ( Howett et al., 2010 ). The low thermal inertia derived here implies that Rhea's polar surfaces are highly porous even at great depths. Analysis of a CIRS focal plane 1 (10-600 cm(exp -1 ) stare observation, taken during the orbit 183 encounter between 16:22:33 and 16:23:26 UT centered on 71.7 deg W, 58.7 deg S provides the first analysis of a thermal emissivity spectrum on Rhea. The results show a flat emissivity spectrum with negligible emissivity features. A few possible explanations exist for this flat emissivity spectrum, but the most likely for Rhea is that the surface is both highly porous and composed of small particles ( less than approximately 50 micrometers).

40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

Code of Federal Regulations, 2014 CFR

2014-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS... Pollutants: Site Remediation Surface Impoundments § 63.7905 What emissions limitations or work practice...

40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

Code of Federal Regulations, 2010 CFR

2010-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS... Pollutants: Site Remediation Surface Impoundments § 63.7905 What emissions limitations or work practice...

40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

Code of Federal Regulations, 2012 CFR

2012-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS... Pollutants: Site Remediation Surface Impoundments § 63.7905 What emissions limitations or work practice...

40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

Code of Federal Regulations, 2011 CFR

2011-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS... Pollutants: Site Remediation Surface Impoundments § 63.7905 What emissions limitations or work practice...

40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

Code of Federal Regulations, 2013 CFR

2013-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS... Pollutants: Site Remediation Surface Impoundments § 63.7905 What emissions limitations or work practice...

Pollutant emissions from vehicles with regenerating after-treatment systems in regulatory and real-world driving cycles.

PubMed

Alvarez, Robert; Weilenmann, Martin; Novak, Philippe

2008-07-15

Regenerating exhaust after-treatment systems are increasingly employed in passenger cars in order to comply with regulatory emission standards. These systems include pollutant storage units that occasionally have to be regenerated. The regeneration strategy applied, the resultant emission levels and their share of the emission level during normal operation mode are key issues in determining realistic overall emission factors for these cars. In order to investigate these topics, test series with four cars featuring different types of such after-treatment systems were carried out. The emission performance in legislative and real-world cycles was monitored as well as at constant speeds. The extra emissions determined during regeneration stages are presented together with the methodology applied to calculate their impact on overall emissions. It can be concluded that exhaust after-treatment systems with storage units cause substantial overall extra emissions during regeneration mode and can appreciably affect the emission factors of cars equipped with such systems, depending on the frequency of regenerations. Considering that the fleet appearance of vehicles equipped with such after-treatment systems will increase due to the evolution of statutory pollutant emission levels, extra emissions originating from regenerations of pollutant storage units consequently need to be taken into account for fleet emission inventories. Accurately quantifying these extra emissions is achieved by either conducting sufficient repetitions of emission measurements with an individual car or by considerably increasing the size of the sample of cars with comparable after-treatment systems.

A Solar Receiver-Reactor with Specularly Reflecting Walls for High-Temperature Thermoelectrochemical and Thermochemical Processes

DTIC Science & Technology

1987-10-27

on the radiosity concept1 2 - t and was simply and quickly formulated when we assumed that the power distribution across each surface was uniform. Our...power per unit area leaving A,, its radiosity B,, consists of two components. The direct emission is kIwT1 4 . The diffusely t reflected portion of the...leaving Am, the radiosity Ba, is the radiation power arriving at the aperture from the concentrator. It is given by B2 = P/A 2 = IAA4-/A 2 , (5) where

Engine Tune-up Service. Unit 6: Emission Control Systems. Posttests. Automotive Mechanics Curriculum.

ERIC Educational Resources Information Center

Morse, David T.; May, Theodore R.

This book of posttests is designed to accompany the Engine Tune-Up Service Student Guide for Unit 6, Emission Control Systems, available separately as CE 031 220. Focus of the posttests is inspecting, testing, and servicing emission control systems. One multiple choice posttest is provided that covers the seven performance objectives contained in…

Directional Emissivity Effects on Martian Surface Brightness Temperatures

NASA Astrophysics Data System (ADS)

Pitman, K. M.; Wolff, M. J.; Bandfield, J. L.; Clancy, R. T.; Clayton, G. C.

2001-11-01

The angular dependence of thermal emission from the surface of Mars has not been well characterized. Although nadir sequences constitute most of the MGS/TES Martian surface observations [1,2], a significant number scans of Martian surfaces at multiple emission angles (emission phase function (EPF) sequences) also exist. Such data can provide insight into surface structures, thermal inertias, and non-isotropic corrections to thermal emission measurements [3]. The availability of abundant EPF data as well as the added utility of such observations for atmospheric characterization provide the impetus for examining the phenomenon of directional emissivity. We present examples of directional emissivity effects on brightness temperature spectra for a variety of typical Martian surfaces. We examine the theoretical development by Hapke (1993, 1996) [4,5] and compare his algorithm to that of Mishchenko et al. (1999) [6]. These results are then compared to relevant TES EPF data. This work is supported through NASA grant NAGS-9820 (MJW) and JPL contract no. 961471 (RTC). [1] Smith et al. (1998), AAS-DPS meeting # 30, # 11.P07. [2] Kieffer, Mullins, & Titus (1998), EOS, 79, 533. [3] Jakosky, Finiol, & Henderson (1990), JGR, 17, 985--988. [4] Hapke, B. (1993), Theory of Reflectance & Emittance Spectroscopy, Cambridge Univ. Press, NY. [5] Hapke, B. (1996), JGR, 101, E7, 16817--16831. [6] Mishchenko et al. (1999), JQSRT, 63, 409--432.

40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION...: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From Sulfur...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

Code of Federal Regulations, 2010 CFR

2010-07-01

...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

40 CFR Table 32 to Subpart Uuu of... - Requirements for Performance Tests for HAP Emissions From Sulfur Recovery Units Not Subject to...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Sulfur Oxides 32 Table 32 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 32 Table 32 to Subpart UUU of Part 63—Requirements for Performance Tests for HAP Emissions From...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 7 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Metal HAP Emissions From Catalytic Cracking Units 7 Table 7 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 7 Table 7 to Subpart UUU of Part 63...

40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

Plasmon enhanced terahertz emission from single layer graphene.

PubMed

Bahk, Young-Mi; Ramakrishnan, Gopakumar; Choi, Jongho; Song, Hyelynn; Choi, Geunchang; Kim, Yong Hyup; Ahn, Kwang Jun; Kim, Dai-Sik; Planken, Paul C M

2014-09-23

We show that surface plasmons, excited with femtosecond laser pulses on continuous or discontinuous gold substrates, strongly enhance the generation and emission of ultrashort, broadband terahertz pulses from single layer graphene. Without surface plasmon excitation, for graphene on glass, 'nonresonant laser-pulse-induced photon drag currents' appear to be responsible for the relatively weak emission of both s- and p-polarized terahertz pulses. For graphene on a discontinuous layer of gold, only the emission of the p-polarized terahertz electric field is enhanced, whereas the s-polarized component remains largely unaffected, suggesting the presence of an additional terahertz generation mechanism. We argue that in the latter case, 'surface-plasmon-enhanced optical rectification', made possible by the lack of inversion symmetry at the graphene on gold surface, is responsible for the strongly enhanced emission. The enhancement occurs because the electric field of surface plasmons is localized and enhanced where the graphene is located: at the surface of the metal. We believe that our results point the way to small, thin, and more efficient terahertz photonic devices.

Mechanism of Prism-Coupled Scanning Tunneling Microscope Light Emission

NASA Astrophysics Data System (ADS)

Iida, Wataru; Ahamed, Jamal U.; Katano, Satoshi; Uehara, Yoichi

2011-09-01

We have investigated the mechanism of scanning tunneling microscope light emission (STM-LE) in a prism-coupled configuration using finite difference time domain analysis. In this configuration, the sample is a metallic thin film evaporated on the bottom surface of a hemispherical glass prism. STM light emitted into the prism (prism-side emission) through the metallic film is measured. Since both localized surface plasmons (LSP) and surface plasmon polaritons (SPP) contribute to prism-side emission, this emission is stronger than that in conventional STM-LE measured from the sample surface side, which is radiated by LSP alone. We show that the spatial resolution of prism-side emission is determined not by the propagation length of SPP, but by the lateral size of LSP, similarly to conventional (i.e., tip side) STM-LE. Thus, we conclude that, by using the prism-coupled configuration, the signal level of STM-LE improves without the loss of spatial resolution attained in tip side emission.

Retrieval of Methane Source Strengths in Europe Using a Simple Modeling Approach to Assess the Potential of Spaceborne Lidar Observations

NASA Technical Reports Server (NTRS)

Weaver, C.; Kiemle, C.; Kawa, S. R.; Aalto, T.; Necki, J.; Steinbacher, M.; Arduini, J.; Apadula, F.; Berkhout, H.; Hatakka, J.

2014-01-01

We investigate the sensitivity of future spaceborne lidar measurements to changes in surface methane emissions. We use surface methane observations from nine European ground stations and a Lagrangian transport model to infer surface methane emissions for 2010. Our inversion shows the strongest emissions from the Netherlands, the coal mines in Upper Silesia, Poland, and wetlands in southern Finland. The simulated methane surface concentrations capture at least half of the daily variability in the observations, suggesting that the transport model is correctly simulating the regional transport pathways over Europe. With this tool we can test whether proposed methane lidar instruments will be sensitive to changes in surface emissions. We show that future lidar instruments should be able to detect a 50% reduction in methane emissions from the Netherlands and Germany, at least during summer.

Radio emission of sea surface at centimeter wavelengths and is fluctuations

NASA Technical Reports Server (NTRS)

Tseytlin, N. M.; Shutko, A. M.; Zhislin, G. M.

1981-01-01

The eigen thermal radio emission of the sea was examined as well as the agitated surface of the sea when the reflection (scattering) is similar in nature to diffused scattering. The contribution of this emission to the total emission of the sea is practically constant in time, and the time fluctuations of the radio emissions of the sea are basically determined only by a change in the eigen emission of the sea, connected with the agitation.

Global Precipitation Measurement, Validation, and Applications Integrated Hydrologic Validation to Improve Physical Precipitation Retrievals for GPM

NASA Technical Reports Server (NTRS)

Peters-Lidar, Christa D.; Tian, Yudong; Kenneth, Tian; Harrison, Kenneth; Kumar, Sujay

2011-01-01

Land surface modeling and data assimilation can provide dynamic land surface state variables necessary to support physical precipitation retrieval algorithms over land. It is well-known that surface emission, particularly over the range of frequencies to be included in the Global Precipitation Measurement Mission (GPM), is sensitive to land surface states, including soil properties, vegetation type and greenness, soil moisture, surface temperature, and snow cover, density, and grain size. In order to investigate the robustness of both the land surface model states and the microwave emissivity and forward radiative transfer models, we have undertaken a multi-site investigation as part of the NASA Precipitation Measurement Missions (PMM) Land Surface Characterization Working Group. Specifically, we will demonstrate the performance of the Land Information System (LIS; http://lis.gsfc.nasa.gov; Peters-Lidard et aI., 2007; Kumar et al., 2006) coupled to the Joint Center for Satellite Data Assimilation (JCSDA's) Community Radiative Transfer Model (CRTM; Weng, 2007; van Deist, 2009). The land surface is characterized by complex physical/chemical constituents and creates temporally and spatially heterogeneous surface properties in response to microwave radiation scattering. The uncertainties in surface microwave emission (both surface radiative temperature and emissivity) and very low polarization ratio are linked to difficulties in rainfall detection using low-frequency passive microwave sensors (e.g.,Kummerow et al. 2001). Therefore, addressing these issues is of utmost importance for the GPM mission. There are many approaches to parameterizing land surface emission and radiative transfer, some of which have been customized for snow (e.g., the Helsinki University of Technology or HUT radiative transfer model;) and soil moisture (e.g., the Land Surface Microwave Emission Model or LSMEM).

Using the Hestia bottom-up FFCO2 emissions estimation to identify drivers and hotspots in urban areas

NASA Astrophysics Data System (ADS)

Rao, P.; Patarasuk, R.; Gurney, K. R.; o'Keefe, D.; Song, Y.; Huang, J.; Buchert, M.; Lin, J. C.; Mendoza, D. L.; Ehleringer, J. R.; Eldering, A.; Miller, C. E.; Duren, R. M.

2015-12-01

Urban areas occupy 3% of the earth's land surface and generate 75% of the fossil fuel carbon dioxide (FFCO2) emissions. We report on the application of the Hestia Project to the Salt Lake County (SLC) and Los Angeles (LA) domains. Hestia quantifies FFCO2 in fine space-time detail across urban domains using a scientific "bottom-up" approach. We explore the utility of the Hestia to inform both urbanization science and greenhouse gas (GHG) mitigation policy. We focus on the residential sector in SLC and the onroad sector in LA as these sectors are large emissions contributors in each locale, and local governments have some authority and policy levers to mitigate these emissions. Multiple regression using sociodemographic data across SLC census block-groups shows that per capita income exhibits a positive relationship with FFCO2 emissions while household size exhibits a negative relationship, after controlling for total population. Housing units per area (i.e., compact development) has little effect on FFCO2 emissions. Rising income in the high-income group has twice as much impact on the emissions as the low-income group. Household size for the low-income group has four times the impact on the emissions as the high-income group. In LA, onroad FFCO2 emissions account for 49% of total emissions, of which 41% is from arterials (intermediate road class). Arterials also have the largest carbon emissions intensity - FFCO2/vehicle distance travelled (VKT) - possibly from high traffic congestion and fleet composition. Non-interstate hotspot emissions (> 419 tC ln-km-1) are equally dominated by particular arterials and collectors (lowest road class) though collectors have a higher VKT. These hotspots occur largely in LA (67%) and Orange (18%) counties and provide targeted information for onroad emissions reduction. Using Hestia to identify FFCO2 emissions drivers and hotpots can aid state and local policy makers in planning the most effective GHG reductions.

Self-calibrated active pyrometer for furnace temperature measurements

DOEpatents

Woskov, Paul P.; Cohn, Daniel R.; Titus, Charles H.; Surma, Jeffrey E.

1998-01-01

Pyrometer with a probe beam superimposed on its field-of-view for furnace temperature measurements. The pyrometer includes a heterodyne millimeter/sub-millimeter-wave or microwave receiver including a millimeter/sub-millimeter-wave or microwave source for probing. The receiver is adapted to receive radiation from a surface whose temperature is to be measured. The radiation includes a surface emission portion and a surface reflection portion which includes the probe beam energy reflected from the surface. The surface emission portion is related to the surface temperature and the surface reflection portion is related to the emissivity of the surface. The simultaneous measurement of surface emissivity serves as a real time calibration of the temperature measurement. In an alternative embodiment, a translatable base plate and a visible laser beam allow slow mapping out of interference patterns and obtaining peak values therefor. The invention also includes a waveguide having a replaceable end portion, an insulating refractory sleeve and/or a source of inert gas flow. The pyrometer may be used in conjunction with a waveguide to form a system for temperature measurements in a furnace. The system may employ a chopper or alternatively, be constructed without a chopper. The system may also include an auxiliary reflector for surface emissivity measurements.

Comparison of SMOS and Aquarius Sea Surface Salinity and Analysis of Possible Causes for the Differences

NASA Technical Reports Server (NTRS)

Dinnat, E. P.; Boutin, J.; Yin, X.; Le Vine, D. M.; Waldteufel, P.; Vergely, J. -L.

2014-01-01

Two ongoing space missions share the scientific objective of mapping the global Sea Surface Salinity (SSS), yet their observations show significant discrepancies. ESA's Soil Moisture and Ocean Salinity (SMOS) and NASA's Aquarius use L-band (1.4 GHz) radiometers to measure emission from the sea surface and retrieve SSS. Significant differences in SSS retrieved by both sensors are observed, with SMOS SSS being generally lower than Aquarius SSS, except for very cold waters where SMOS SSS is the highest overall. Figure 1 is an example of the difference between the SSS retrieved by SMOS and Aquarius averaged over one month and 1 degree in longitude and latitude. Differences are mostly between -1 psu and +1 psu (psu, practical salinity unit), with a significant regional and latitudinal dependence. We investigate the impact of the vicarious calibration and some components of the retrieval algorithm used by both mission on these differences.

40 CFR 63.1563 - When do I have to comply with this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units... for an existing catalytic cracking unit allowing additional time to meet the emission limitations and work practice standards for catalytic cracking units in §§ 63.1564 and 63.1565 if you commit to...

40 CFR 63.1563 - When do I have to comply with this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units... for an existing catalytic cracking unit allowing additional time to meet the emission limitations and work practice standards for catalytic cracking units in §§ 63.1564 and 63.1565 if you commit to...

40 CFR 98.162 - GHGs to report.

Code of Federal Regulations, 2012 CFR

2012-07-01

... GREENHOUSE GAS REPORTING Hydrogen Production § 98.162 GHGs to report. You must report: (a) CO2 emissions from each hydrogen production process unit. (b) [Reserved] (c) CO2, CH4, and N2O emissions from each stationary combustion unit other than hydrogen production process units. You must calculate and report these...

40 CFR 98.162 - GHGs to report.

Code of Federal Regulations, 2011 CFR

2011-07-01

... GREENHOUSE GAS REPORTING Hydrogen Production § 98.162 GHGs to report. You must report: (a) CO2 emissions from each hydrogen production process unit. (b) [Reserved] (c) CO2, CH4, and N2O emissions from each stationary combustion unit other than hydrogen production process units. You must calculate and report these...

40 CFR 98.162 - GHGs to report.

Code of Federal Regulations, 2013 CFR

2013-07-01

... GREENHOUSE GAS REPORTING Hydrogen Production § 98.162 GHGs to report. You must report: (a) CO2 emissions from each hydrogen production process unit. (b) [Reserved] (c) CO2, CH4, and N2O emissions from each stationary combustion unit other than hydrogen production process units. You must calculate and report these...