Particle simulation of electromagnetic emissions from electrostatic instability driven by an electron ring beam on the density gradient

NASA Astrophysics Data System (ADS)

Horký, Miroslav; Omura, Yoshiharu; Santolík, Ondřej

2018-04-01

This paper presents the wave mode conversion between electrostatic and electromagnetic waves on the plasma density gradient. We use 2-D electromagnetic code KEMPO2 implemented with the generation of density gradient to simulate such a conversion process. In the dense region, we use ring beam instability to generate electron Bernstein waves and we study the temporal evolution of wave spectra, velocity distributions, Poynting flux, and electric and magnetic energies to observe the wave mode conversion. Such a conversion process can be a source of electromagnetic emissions which are routinely measured by spacecraft on the plasmapause density gradient.

Multicolor up conversion emission and color tunability in Yb 3+/Tm 3+/Ho 3+ triply doped heavy metal oxide glasses

NASA Astrophysics Data System (ADS)

Ledemi, Yannick; Manzani, Danilo; Ribeiro, Sidney J. L.; Messaddeq, Younes

2011-10-01

Multicolor and white light emissions have been achieved in Yb 3+, Tm 3+ and Ho 3+ triply doped heavy metal oxide glasses upon laser excitation at 980 nm. The red (660 nm), green (547 nm) and blue (478 nm) up conversion emissions of the rare earth (RE) ions triply doped TeO 2-GeO 2-Bi 2O 3-K 2O glass (TGBK) have been investigated as a function of the RE concentration and excitation power of the 980 nm laser diode. The most appropriate combination of RE in the TGBK glass host (1.6 wt% Yb 2O 3, 0.6 wt% Tm 2O 3 and 0.1 wt% Ho 2O 3) has been determined with the purpose to tune the primary colors (RGB) respective emissions and generate white light emission by varying the pump power. The involved infrared to visible up conversion mechanisms mainly consist in a three-photon blue up conversion of Tm 3+ ions and a two-photon green and red up conversions of Ho 3+ ions. The resulting multicolor emissions have been described according to the CIE-1931 standards.

Complex study on photoluminescence properties of YAG:Ce,Gd phosphors

NASA Astrophysics Data System (ADS)

Lisitsyn, V. M.; Ju, Yangyang; Stepanov, S. A.; Soschin, N. M.

2017-05-01

Luminescence characteristics of gadolinium co-doped yttrium aluminium garnet doped with cerium phosphors were studied. In this work, powder X-ray diffraction (XRD) spectra, elemental composition analyses, excitation and emission spectra, conversion efficiency of emission phosphor, corresponding (CIE) chromaticity colour coordinates and pulsed photoluminescence decay kinetic curves were investigated, all the measurements were performed at room temperature. The properties of the phosphors were studied by comparing the composition of the phosphors and their luminescent properties.

Excited-state absorption and fluorescence dynamics of Er3+:KY3F10

NASA Astrophysics Data System (ADS)

Labbé, C.; Doualan, J. L.; Moncorgé, R.; Braud, A.; Camy, P.

2018-05-01

We report here on a complete investigation of the excited-state absorption and fluorescence dynamics of Er3+ doped KY3F10 single crystals versus dopant concentrations and optical excitation conditions. Radiative and effective (including non-radiative relaxations) emission lifetimes and branching ratios are determined from a Judd-Ofelt analysis of the absorption spectra and via specific fluorescence experiments using wavelength selective laser excitations. Excited-state absorption and emission spectra are registered within seven spectral domains, i.e. 560 nm, 650 nm, 710 nm, 810 nm, 970 nm, 1550 nm and 2750 nm. A maximum gain cross-section of 0.93 × 10-21 cm2 is determined at the potential laser wavelength of 2.801 μm for a population ratio of 0.48. Saturation of fluorescence intensities and variations of population ratios versus pumping rates are registered and confronted with a rate equation model to derive the rates of the most important up-conversion and cross-relaxation energy transfers occurring at high dopant concentrations.

White light generation via up-conversion and blue tone in Er3+/Tm3+/Yb3+-doped zinc-tellurite glasses

NASA Astrophysics Data System (ADS)

Rivera, V. A. G.; Ferri, F. A.; Nunes, L. A. O.; Marega, E.

2017-05-01

Yb3+, Er3+ and Tm3+ triply doped zinc-tellurite glass have been prepared containing up to 3.23 wt% of rare-earth ion oxides, were characterized by absorption spectroscopy, excitation, emission and up-conversion spectra. Transparent and homogeneous glasses have been produced, managing the red, green and blue emission bands, in order to generate white light considering the human eye perception. The energy transfer (resonant or non-resonant) between those rare-earth ions provides a color balancing mechanism that maintains the operating point in the white region, generating warm white light, cool white light and artificial daylight through the increase of the 976/980 nm diode laser excitation power from 4 to 470 mW. A light source at 4000 K is obtained under the excitation at 980 nm with 15 mW, providing a white light environment that is comfortable to the human eye vision. The spectroscopic study presented in this work describes the white light generation by the triply-doped zinc-tellurite glass, ranging from blue, green and red, by controlling the laser excitation power and wavelength at 976/980 nm. Such white tuning provokes healthy effects on human health throughout the day, especially the circadian system.

Conversion electron spectrometry of Pu isotopes with a silicon drift detector.

PubMed

Pommé, S; Paepen, J; Peräjärvi, K; Turunen, J; Pöllänen, R

2016-03-01

An electron spectrometry set-up was built at IRMM consisting of a vacuum chamber with a moveable source holder and windowless Peltier-cooled silicon drift detector (SDD). The SDD is well suited for measuring low-energy x rays and electrons emitted from thin radioactive sources with low self-absorption. The attainable energy resolution is better than 0.5keV for electrons of 30keV. It has been used to measure the conversion electron spectra of three plutonium isotopes, i.e. (238)Pu, (239)Pu, (240)Pu, as well as (241)Am (being a decay product of (241)Pu). The obtained mixed x-ray and electron spectra are compared with spectra obtained with a close-geometry set-up using another SDD in STUK and spectra measured with a Si(Li) detector at IRMM. The potential of conversion electron spectrometry for isotopic analysis of mixed plutonium samples is investigated. With respect to the (240)Pu/(239)Pu isotopic ratio, the conversion electron peaks of both isotopes are more clearly separated than their largely overlapping peaks in alpha spectra. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Impact of Nd3+ ions on physical and optical properties of Lithium Magnesium Borate glass

NASA Astrophysics Data System (ADS)

Mhareb, M. H. A.; Hashim, S.; Ghoshal, S. K.; Alajerami, Y. S. M.; Saleh, M. A.; Dawaud, R. S.; Razak, N. A. B.; Azizan, S. A. B.

2014-11-01

Enhancing the up-conversion efficiency of borate glass via optimized doping of rare earth ions is an ever-ending quest in lasing glass. Neodymium (Nd3+) doped Lithium Magnesium Borate (LMB) glasses are prepared using the melt-quenching method. X-ray diffraction (XRD), Fourier transformed infrared (FTIR), UV-Vis-NIR absorption and Photoluminescence (PL) spectroscopic characterizations are made to examine the influence of Nd3+ concentration on physical properties and optical properties. Nd3+ contents dependent density, molar volume, refractive index, ion concentration, Polaron radius, inter nuclear distance, field strength, energy band gap and oscillator strength are calculated. XRD patterns confirm the amorphous nature of all glasses and the FTIR spectra reveal the presence of BO3 and BO4 functional groups. UV-Vis-IR spectra exhibit ten prominent bands centered at 871, 799, 741, 677, 625, 580, 522, 468, 426, 349 nm corresponding to the transitions from the ground state to 4F3/2, (4F5/2 + 2H9/2), (4F7/2 + 4S3/2), 4F9/2, 2H11/2, (4G5/2 + 2G7/2), (2K13/2 + 4G7/2 + 4G9/2), (2G9/2 + 2D3/2 + 2P3/2), (2P1/2 + 2D5/2), (4D3/2 + 4D5/2) excited states, respectively. A hyper-sensitive transition related to (4G5/2 + 2G7/2) level is evidenced at 580 nm. The room temperature up-conversion emission spectra at 800 nm excitation displays three peaks centered at 660, 610 and 540 nm. Glass with 0.5 mol% of Nd3+ showing an emission enhancement by a factor to two is attributed to the energy transfer between Mg2+ and Nd3+ ions. Our results suggest that these glasses can be nominated for solid state lasers and other photonic devices.

Structural and optical characterization of NaGdF{sub 4}: Ho{sup 3+}/Yb{sup 3+} UC nano-particles for lateral finger mark detections

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, A., E-mail: ak.phy87@gmail.com; Tiwari, S. P.; Krishna, K. M.

2016-05-23

Ho{sup 3+}/Yb{sup 3+} co-doped NaGdF{sub 4} up-conversion (UC) nano-particles were synthesized by thermal decomposition method. X-ray diffraction and FE-SEM image analysis were done to confirm the structure, morphology and determination of particle size. The UC emission spectra for as prepared as well as 100°C, 200°C, 300°C, 400°C, 800°C, 1000°C and 1200°C heated for 3h samples were recorded and there emission intensities were compared at a constant pump power of excitations 98.1 W/cm{sup 2}. The effect of emission intensity on decay time was also studied through focused and unfocused excitations. The synthesized material was successfully utilized in lateral finger mark detections onmore » the glass substrate through powder dusting method.« less

Photoluminescence Characteristics of Yag:Ce, Gd Based Phosphors with Different Prehistories

NASA Astrophysics Data System (ADS)

Lisitsyn, V. M.; Soshchin, N. P.; Yang yang, Yu; Stepanov, S. A.; Lisitsyna, L. A.; Tulegenova, A. T.; Abdullin, Kh. A.

2017-09-01

Luminescence characteristics of yttrium-aluminum garnet based phosphor samples differed by their elemental composition and prehistory of synthesis are studied. The morphology, structure, and elemental composition of phosphor samples, their excitation and emission spectra, efficiency of phosphor conversion of chip emission, and kinetics of luminescence decay are measured. The emission characteristics of phosphors are compared with their structural properties and elemental composition.

Bright up-conversion white light emission from Er3+ doped lithium fluoro zinc borate glasses for photonic applications

NASA Astrophysics Data System (ADS)

Vijayalakshmi, L.; Naveen Kumar, K.; Rao, K. Srinivasa; Hwang, Pyung

2018-03-01

Various concentrations of Er3+ (0.3, 0.5, 1.0 and 1.5 mol %) doped lithium fluoro zinc borate glasses were synthesized by a traditional melt quenching method. XRD, FTIR and FESEM have been employed to analyze the structural, compositional and morphological analysis respectively. Judd-Ofelt theory has been employed to analyze the intensity parameters (Ωλ, λ = 2, 4 and 6) which can be used to estimate the radiative properties of fluorescent levels of Er3+. We have been observed a strong NIR emission peak at 1.53 μm (4I13/2 → 4I15/2) under the excitation of 980 nm from Er3+: LBZ glasses. Nevertheless, the NIR emission is remarkably enhanced by increasing the Er3+ ions concentration until the optimized concentration of 0.5 mol%. The lifetime of the excited level of 4I13/2 in the NIR emission transition is evaluated and it is found to be1.22 ms from the decay analysis of 0.5 mol% Er3+: LBZ glass. Apart from the NIR emission, a bright up-conversion green emission is observed at 544 nm (4S3/2 → 4I15/2) along with an intense red emission at 659 nm (4F9/2 → 4I15/2) and a weak blue emission (2H9/2 → 4I15/2) under the excitation of 980 nm. Up-conversion emission features were significantly enhanced with increasing the Er3+ concentration up to 1.0 mol%. The combination of the obtained up-conversion emission colors of green, red and blue could generate white light emission. The cool white-light emission from the optimized glass sample has been confirmed from the Commission International de I'Echairage (CIE) 1931 chromaticity diagram analysis and their correlated color temperature (CCT) values. Based on the NIR and up-conversion emission features, Er3+: LBZ glasses could be suggested as promising candidates for optical amplifiers, optical telecommunication windows and white light photonic applications.

Picosecond flash spectroscopic studies on ultraviolet stabilizers and stabilized polymers

NASA Technical Reports Server (NTRS)

Scott, G. W.

1982-01-01

Spectroscopic and excited state decay kinetics are reported for monomeric and polymeric forms of ultraviolet stabilizers in the 2-(2'-hydroxyphenyl)-benzotriazole and 2-hydroxybenzophenone classes. For some of these molecules in various solvents at room temperature, (1) ground state absorption spectra, (2) emission spectra, (3) picosecond time-resolved transient absorption spectra, (4) ground state absorption recovery kinetics, (5) emission kinetics, and (6) transient absorption kinetics are reported. In the solid state at low temperatures, emission spectra and their temperature dependent kinetics up to approximately 200K as well as, in one case, the 12K excitation spectra of the observed dual emission are also reported.

Alpha and conversion electron spectroscopy of 238,239Pu and 241Am and alpha-conversion electron coincidence measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dion, Michael P.; Miller, Brian W.; Warren, Glen A.

2016-09-01

A technique to determine the isotopics of a mixed actinide sample has been proposed by measuring the coincidence of the alpha particle during radioactive decay with the conversion electron (or Auger) emitted during the relaxation of the daughter isotope. This presents a unique signature to allow the deconvolution of isotopes that possess overlapping alpha particle energy. The work presented here are results of conversion electron spectroscopy of 241Am, 238Pu and 239Pu using a dual-stage peltier-cooled 25 mm2 silicon drift detector. A passivated ion implanted planar silicon detector provided measurements of alpha spectroscopy. The conversion electron spectra were evaluated from 20–55more » keV based on fits to the dominant conversion electron emissions, which allowed the relative conversion electron emission intensities to be determined. These measurements provide crucial singles spectral information to aid in the coincident measurement approach.« less

Prism-coupled light emission from tunnel junctions

NASA Technical Reports Server (NTRS)

Ushioda, S.; Rutledge, J. E.; Pierce, R. M.

1985-01-01

Completely p-polarized light emission has been observed from smooth Al-AlO(x)-Au tunnel junctions placed on a prism coupler. The angle and polarization dependence demonstrate unambiguously that the emitted light is radiated by the fast-mode surface plasmon polariton. The emission spectra suggest that the dominant process for the excitation of the fast mode is through conversion of the slow mode to the fast mode mediated by residual roughness on the junction surface.

Strong emission in Yb3+/Er3+ co-doped phosphate glass ceramics

NASA Astrophysics Data System (ADS)

Liu, Yanling; Song, Feng; Jia, Guozhi; Zhang, Yanbang; Tang, Yi

Yb3+/Er3+ co-doped phosphate glass and glass ceramics were prepared by high-temperature melting method. The X-ray diffraction, transmission electron micrographs, up-conversion and infrared emissions, photothermal conversion properties of the samples have been measured. The results showed the annealing time had a great impact on the microstructure and luminous performance of the phosphate glass. At the beginning of annealing, the metaphosphate crystals were firstly dissolved out. The metaphosphate crystals gradually turned into the orthophosphate with the increasing of annealing time. The emission intensity of the sample was obviously improved after the precursor glass was annealed. The up-conversion and infrared emissions of the sample annealed at 600 °C for 24 h, reached the maximum intensity. Compared with the photothermal properties of glass, the lower photothermal conversion efficiency of the glass ceramics testified the strong emission.

High field terahertz pulse generation from plasma wakefield driven by tailored laser pulses

NASA Astrophysics Data System (ADS)

Chen, Zi-Yu

2013-06-01

A scheme to generate high field terahertz (THz) pulses by using tailored laser pulses interaction with a gas target is proposed. The laser wakefield based THz source is emitted from the asymmetric laser shape induced plasma transverse transient net currents. Particle-in-cell simulations show that THz emission with electric filed strength over 1 GV/cm can be obtained with incident laser at 1×1019 W/cm2 level, and the corresponding energy conversion efficiency is more than 10-4. The intensity scaling holds up to high field strengths. Such a source also has a broad tunability range in amplitude, frequency spectra, and temporal shape.

Methods for locating ground faults and insulation degradation condition in energy conversion systems

DOEpatents

Agamy, Mohamed; Elasser, Ahmed; Galbraith, Anthony William; Harfman Todorovic, Maja

2015-08-11

Methods for determining a ground fault or insulation degradation condition within energy conversion systems are described. A method for determining a ground fault within an energy conversion system may include, in part, a comparison of baseline waveform of differential current to a waveform of differential current during operation for a plurality of DC current carrying conductors in an energy conversion system. A method for determining insulation degradation within an energy conversion system may include, in part, a comparison of baseline frequency spectra of differential current to a frequency spectra of differential current transient at start-up for a plurality of DC current carrying conductors in an energy conversion system. In one embodiment, the energy conversion system may be a photovoltaic system.

Synthesis and up-conversion luminescence of Er{sup 3+} and Y b{sup 3+} codoped nanocrystalline tetra- (KLaP{sub 4}O{sub 12}) and pentaphosphates (LaP{sub 5}O{sub 14})

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marciniak, L., E-mail: l.marciniak@int.pan.wroc.pl; Stefanski, M.; Tomala, R.

2015-09-07

The up-converting nanocrystals of KLa{sub 0.95}Er{sub 0.05}Y b{sub x}P{sub 4}O{sub 12} and La{sub 0.95−x}Er{sub 0.05}Y b{sub x}P{sub 5}O{sub 14} were prepared using co-precipitation method. The spectroscopic properties of these materials were investigated in a function of Y b{sup 3+} concentration. The up-conversion emission, power dependence of emission intensities, and the luminescence decay times were investigated. It was found that the green to red and {sup 2}H{sub 11/2} → {sup 4}I{sub 15/2} to {sup 4}S{sub 3/2} → {sup 4}I{sub 15/2} emission intensity ratio were strongly affected by the Y b{sup 3+} concentration. Moreover, the order of up-conversion emission and threshold powermore » rises up with Y b{sup 3+} concentration for {sup 4}S{sub 3/2} → {sup 4}I{sub 15/2} transition. The luminescence decay time of the {sup 4}S{sub 3/2} → {sup 4}I{sub 15/2} emission increases with Y b{sup 3+} concentration while the {sup 4}F{sub 9/2} → {sup 4}I{sub 15/2} emission is independent of dopant concentration. The influence of the Y b{sup 3+} concentration on the up-conversion emission intensities was discussed in terms of concentration dependent hetero looped photon avalanche process. A comparison of the up-conversion properties of KLa{sub 0.95}Er{sub 0.05}Y b{sub x}P{sub 4}O{sub 12} and La{sub 0.95−x}Er{sub 0.05}Y b{sub x}P{sub 5}O{sub 14} nanocrystals was presented.« less

Up-conversion green emission of Yb3+/Er3+ ions doped YVO4 nanocrystals obtained via modified Pechini's method

NASA Astrophysics Data System (ADS)

Szczeszak, Agata; Runowski, Marcin; Wiglusz, Rafal J.; Grzyb, Tomasz; Lis, Stefan

2017-12-01

A series of lanthanide doped yttrium vanadates were prepared by Pechini's method (sol-gel process). The as-prepared precursors, in the presence of citric acid, were calcined in the temperature range of 600-900 °C. The obtained products were composed of small nanoparticles, in the size range of 20-50 nm, depending on the annealing temperature, exhibiting a bright green up-conversion emission, under NIR laser irradiation, and emission lifetimes in the range of 4.7-18.3 μs. Their structural, morphological and spectroscopic properties were investigated in detail by XRD, HR-TEM including FFT analysis, EDX and spectroscopic techniques (emission, power dependence and emission kinetics). The luminescence quenching phenomenon, manifested in a decrease of up-conversion intensity and shortening of emission lifetime, was observed with increasing of the Yb3+ ion concentration and decreasing the particle size. The optimal concentration of the Yb3+ ions was found to be 15 mol% (YVO4: Yb3+ 15 mol%, Er3+ 2 mol%).

[Luminescence properties of white LED blue light conversion materials].

PubMed

Hao, Hai-tao; Zhou, He-feng; Liang, Jian; Liu, Xu-guang; Xu, Bing-she

2007-02-01

Using rare earth oxides as raw materials, yttrium aluminum garnets activated by cerium and gadolinium ions were prepared by high energy ball milling and solid-state reaction at 1300 degrees C. The crystal structures of the products were studied by XRD, and the luminescence characteristics of Ce ion and the influence of Gd ion were studied by emission and excitation spectra. The results indicated that the products were yttrium aluminum garnet crystals of cubic system, and they were excited by blue light chips effectively. The emission peak of phosphors could change among 530-560 nm by adjusting the mole density of doping ions. The red shift of emission spectra could be interpreted with the configuration coordination figure. White LEDs were fabricated by phosphor conversion. When electric current is 20 mA, and the working voltage is 3.5 V, the white light LED chromaticity coordinates are x=0.310 and y=0.323, the lumen efficiency is 26.131 m x W(-1), the color rendering index is 81.8, and the color temperature is 6605 K.

Intense infrared emission of Er(3+) in Ca(8)Mg(SiO(4))(4)Cl(2) phosphor from energy transfer of Eu(2+) by broadband down-conversion.

PubMed

Zhou, Jiajia; Teng, Yu; Liu, Xiaofeng; Ye, Song; Xu, Xiaoqiu; Ma, Zhijun; Qiu, Jianrong

2010-10-11

We report on conversion of near-ultraviolet and visible radiation ranging from 250 to 500 nm into near-infrared emission by a Ca(8)Mg(SiO(4))(4)Cl(2): Eu(2+), Er(3+) phosphor. Efficient 1530-1560 nm Er(3+) emission ((4)I(13/2)-->(4)I(15/2)) was detected under the excitation of Eu(2+) (4f?5d) absorption band as a result of energy transfer from Eu(2+) to Er(3+), which is confirmed by both steady state and time-resolved emission spectra. The laser power dependent emission intensity changes were investigated to analysis the energy transfer mechanism. Energy transfer from Eu(2+) to Er(3+) followed by a multi-photon quantum cutting of Er(3+) is proposed. The result indicates that the phosphor has potential application in enhancement of conversion efficient of germanium solar cells because the energy difference of Er(3+): (4)I(13/2)-->(4)I(15/2) transition matches well with the bandgap of Ge (Eg~0.785 eV).

Kα X-Ray Emission Spectra and K X-Ray Absorption-Edge Structures of Fluorine in 3d Transition-Metal Difluorides

NASA Astrophysics Data System (ADS)

Sugiura, Chikara

1991-08-01

The fluorine Kα emission spectra in fluorescence from a series of 3d transition-metal difluorides MF2 (M=Mn, Fe, Co, Ni, Cu and Zn) have been measured with a high-resolution two-crystal vacuum spectrometer. It is shown that the observed FWHM of the Kα1,2 emission band is closely related to the difference in the electronegativity between the metal and fluorine atoms. The measured emission spectra are presented along with the UPS or XPS spectra of the valence bands and the fluorine K absorption spectra of the metal difluorides, reported previously. The structures at the fluorine K absorption edges are interpreted in terms of a molecular orbital (MO) model.

Observation of ionization shifts in K-shell emission from short-pulse laser irradiated micro-dot targets

NASA Astrophysics Data System (ADS)

Neumayer, Paul; Kritcher, Andrea; Landen, Otto; Lee, Haeja; Offerman, Dustin; Shipton, Eric; Glenzer, Siegfried

2006-10-01

X-ray Thomson scattering using short pulse laser generated intense line radiation has a great potential as a time-resolved temperature and density diagnostic for high-energy density states of matter. We present recent results characterizing Chlorine K-alpha and K-beta line emission obtained by irradiating Saran foil with 50 Terawatt laser pulses from the Callisto laser (Jupiter Laser Facility, Lawrence Livermore National Laboratory). Spectra from front and rear side emission are recorded simultaneously with high resolution HOPG spectrometers employing imaging plate detectors. Conversion efficiencies of laser pulse energy into x-ray line emission of several 10-5 are achieved and are maintained throughout up to 7 J of laser energy, thus constituting a short pulsed narrow band x-ray source of more than 10^11 photons. When the target size is reduced to 50 micrometer (``micro-dot'') a significant blue-shift of up to 5 eV is clearly observed. This can be attributed to higher ionization states of the target atoms indicating achievement of a high-temperature solid density state. This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under Contract No. W-7405-ENG-48 and LDRD 05-ERI-003.

Continuum radiation in planetary magnetospheres

NASA Technical Reports Server (NTRS)

Kurth, W. S.

1991-01-01

With the completion of the Voyager tour of the outer planets, radio and plasma wave instruments have executed the first survey of the wave spectra of Earth, Jupiter, Saturn, Uranus, and Neptune. One of the most notable conclusions of this survey is that there is a great deal of qualitative similarity in both the plasma wave and radio wave spectra from one magnetosphere to the next. In particular, in spite of detailed differences, most of the radio emissions at each of the planets have been tentatively classified into two primary categories. First, the most intense emissions are generally associated with the cyclotron maser instability. Second, a class of weaker emissions can be found at each of the magnetospheres which appears to be the result of conversion from intense electrostatic emissions at the upper hybrid resonance frequency into (primarily) ordinary mode radio emission. It is this second category, often referred to as nonthermal continuum radiation, which we will discuss in this review. We review the characteristics of the continuum spectrum at each of the planets, discuss the source region and direct observations of the generation of the emissions where available, and briefly describe the theories for the generation of the emissions. Over the past few years evidence has increased that the linear mode conversion of electrostatic waves into the ordinary mode can account for at least some of the continuum radiation observed. There is no definitive evidence which precludes the possibility that a nonlinear mechanism may also be important.

Photon-enhanced thermionic emission from p-GaAs with nonequilibrium Cs overlayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhuravlev, A. G.; Romanov, A. S.; Alperovich, V. L., E-mail: alper@isp.nsc.ru

2014-12-22

Photon-enhanced thermionic emission (PETE), which is promising for increasing the efficiency of solar energy conversion, is studied during cesium deposition on the As- and Ga-rich p-GaAs(001) surfaces and subsequent relaxation in the nonequilibrium Cs overlayer by means of photoemission quantum yield spectroscopy adapted for systems with time-variable parameters. Along with direct photoemission of “hot” electrons excited by light above the vacuum level, the spectra contain PETE contribution of “thermalized” electrons, which are excited below the vacuum level and emit in vacuum due to thermalization up in energy by phonon absorption. Comparing the measured and calculated spectra, the effective electron affinitymore » and escape probabilities of hot and thermalized electrons are obtained as functions of submonolayer Cs coverage. The minima in the affinity and pronounced peaks in the escape probabilities are observed for Cs deposition on both the As- and Ga-rich surfaces. Possible reasons for the low mean values of the electron escape probabilities and for the observed enhancement of the probabilities at certain Cs coverages are discussed, along with the implications for the PETE device realization.« less

Up-conversion multiwave (White) luminescence in the visible spectral range under excitation by IR laser diodes in the active BaY2F8:Yb3+,Pr3+ medium

NASA Astrophysics Data System (ADS)

Pushkar', A. A.; Uvarova, T. V.; Kiiko, V. V.

2011-08-01

The possibilities of occupying high-lying 4 f states of Pr3+ ions in the active BaY2F8:Yb3+,Pr3+ medium according to the photon avalanche and step-by-step sensitization mechanisms are compared. It is shown that the photon avalanche is unlikely to occur in the BaY2F8:Yb3+,Pr3+ crystal. The multiband luminescence spectra in the visible spectral range (white emission) under single- and multiwave pumping of BaY2F8:Yb3+,Pr3+ crystal by IR laser diodes are reported.

Novel Na(+) doped Alq3 hybrid materials for organic light-emitting diode (OLED) devices and flat panel displays.

PubMed

Bhagat, S A; Borghate, S V; Kalyani, N Thejo; Dhoble, S J

2015-05-01

Pure and Na(+) -doped Alq3 complexes were synthesized by a simple precipitation method at room temperature, maintaining a stoichiometric ratio. These complexes were characterized by X-ray diffraction, Fourier transform infrared (FTIR), UV/Vis absorption and photoluminescence (PL) spectra. The X-ray diffractogram exhibits well-resolved peaks, revealing the crystalline nature of the synthesized complexes, FTIR confirms the molecular structure and the completion of quinoline ring formation in the metal complex. UV/Vis absorption and PL spectra of sodium-doped Alq3 complexes exhibit high emission intensity in comparison with Alq3 phosphor, proving that when doped in Alq3 , Na(+) enhances PL emission intensity. The excitation spectra of the synthesized complexes lie in the range 242-457 nm when weak shoulders are also considered. Because the sharp excitation peak falls in the blue region of visible radiation, the complexes can be employed for blue chip excitation. The emission wavelength of all the synthesized complexes lies in the bluish green/green region ranging between 485 and 531 nm. The intensity of the emission wavelength was found to be elevated when Na(+) is doped into Alq3 . Because both the excitation and emission wavelengths fall in the visible region of electromagnetic radiation, these phosphors can also be employed to improve the power conversion efficiency of photovoltaic cells by using the solar spectral conversion principle. Thus, the synthesized phosphors can be used as bluish green/green light-emitting phosphors for organic light-emitting diodes, flat panel displays, solid-state lighting technology - a step towards the desire to reduce energy consumption and generate pollution free light. Copyright © 2014 John Wiley & Sons, Ltd.

[Two-photon up-conversion fluorescence of a neodymium organic framework Nd(BTC)].

PubMed

Xu, Hui; Jin, Run-zhi; Wu, Chun-yang; Yang, Yu; Qian, Guo-dong

2008-08-01

In the present work, a neodymium organic framework Nd(BTC) was synthesized by the solvothermal reaction of Nd(NO3)3 x 5H2O and H3BTC (BTC = 1,3,5-benzenetricarboxylate) in mixed solvents of DMF, ethanol and water, and was identified by elemental analysis. This MOF complex was characterized using X-ray diffraction (XRD), thermogravimetry-differential scanning calorimetry (TGA-DSC) analysis, UV-visible absorption spectra and fluorescence spectra. This polycrystalline powder lost DMF and H2O when heated to 120 degrees C, then remained stable till the temperature reached 500 degrees C. Near infrared fluorescence at 1064 nm due to the 4 F3/2--> 4 I11/2 transition of Nd3+ ions was exhibited when excited by 808 nm laser beam. It was also been found that up-conversion fluorescence of Nd(BTC) peaked at about 450 nm due to 2 D5/2 -->4 I11/2 transition of Nd3+ ions can be observed under the excitation of a 580 nm laser line. The mechanism of the up-conversion fluorescence of Nd(BTC) at around 450 nm under the excitation of 580 nm laser can be ascribed to both excited-state absorption and energy transfer up-conversion. This result indicated that such MOF can be employed as an up-conversion luminescence material in many potential application areas such as bio-labeling and fluorescence image.

NIR-to-NIR Deep Penetrating Nanoplatforms Y2O3:Nd3+/Yb3+@SiO2@Cu2S toward Highly Efficient Photothermal Ablation.

PubMed

Zhang, Zhiyu; Suo, Hao; Zhao, Xiaoqi; Sun, Dan; Fan, Li; Guo, Chongfeng

2018-05-02

A difunctional nano-photothermal therapy (PTT) platform with near-infrared excitation to near-infrared emission (NIR-to-NIR) was constructed through core-shell structures Y 2 O 3 :Nd 3+ /Yb 3+ @SiO 2 @Cu 2 S (YRSC), in which the core Y 2 O 3 :Nd 3+ /Yb 3+ and shell Cu 2 S play the role of bioimaging and photothermal conversion function, respectively. The structure and composition of the present PTT agents (PTAs) were characterized by powder X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectra. The NIR emissions of samples in the biological window area were measured by photoluminescence spectra under the excitation of 808 nm laser; further, the penetration depth of NIR emission at different wavelengths in biological tissue was also demonstrated by comparing with visible (vis) emission from Y 2 O 3 :Yb 3+ /Er 3+ @SiO 2 @Cu 2 S and NIR emission from YRSC through different injection depths in pork muscle tissues. The photo-thermal conversion effects were achieved through the outer ultrasmall Cu 2 S nanoparticles simultaneously absorb NIR light emission from the core Y 2 O 3 :Nd 3+/ Yb 3+ and the 808 nm excitation source to generate heat. Further, the heating effect of YRSC nanoparticles was confirmed by thermal imaging and ablation of YRSC to Escherichia coli and human hepatoma (HepG-2) cells. Results indicate that the YRSC has potential applications in PTT and NIR imaging in biological tissue.

Color-tunable up-conversion emission in Y2O3:Yb3+, Er3+ nanoparticles prepared by polymer complex solution method

PubMed Central

2013-01-01

Abstract Powders of Y2O3 co-doped with Yb3+ and Er3+ composed of well-crystallized nanoparticles (30 to 50 nm in diameter) with no adsorbed ligand species on their surface are prepared by polymer complex solution method. These powders exhibit up-conversion emission upon 978-nm excitation with a color that can be tuned from green to red by changing the Yb3+/Er3+ concentration ratio. The mechanism underlying up-conversion color changes is presented along with material structural and optical properties. PACS 42.70.-a, 78.55.Hx, 78.60.-b PMID:23522083

Dual functional NaYF4:Yb3+, Er3+@NaYF4:Yb3+, Nd3+ core-shell nanoparticles for cell temperature sensing and imaging

NASA Astrophysics Data System (ADS)

Shi, Zengliang; Duan, Yue; Zhu, Xingjun; Wang, Qiwei; Li, DongDong; Hu, Ke; Feng, Wei; Li, Fuyou; Xu, Chunxiang

2018-03-01

Lanthanide-doped up-conversion nanoparticles (UCNPs) provide a remote temperature sensing approach to monitoring biological microenvironments. In this research, the UCNPs of NaYF4:Yb3+, Er3+@NaYF4:Yb3+, Nd3+ with hexagonal (β)-phase were synthesized and applied in cell temperature sensing as well as imaging after surface modification with meso-2, 3-dimercaptosuccinic acid. In the core-shell UCNPs, Yb3+ ions were introduced as energy transfer media between sensitizers of Nd3+ and activators of Er3+ to improve Er3+emission and prevent their quenching behavior due to multiple energy levels of Nd3+. Under the excitations of 808 nm and 980 nm lasers, the NaYF4:Yb3+, Er3+@NaYF4:Yb3+, Nd3+ nanoparticles exhibited an efficient green band with two emission peaks at 525 nm and 545 nm, respectively, which originated from the transitions of 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 for Er3+ ions. We demonstrate that an occurrence of good logarithmic linearity exists between the intensity ratio of these two emission peaks and the reciprocal of the inside or outside temperature of NIH-3T3 cells. A better thermal stability is proved through temperature-dependent spectra with a heating-cooling cycle. The obtained viability of NIH-3T3 cells is greater than 90% after incubations of about 12 and 24 (h), and they possess a lower cytotoxicity of UCNPs. This work provides a method for monitoring the cell temperature and its living state from multiple dimensions including temperature response, cell images and visual up-conversion fluorescent color.

Results and Outlook of The Aluminum Capture Experiment (AlCap)

NASA Astrophysics Data System (ADS)

Quirk, John R.; Miller, James; ALCap Collaboration Collaboration

2016-03-01

Observation of neutrinoless muon-to-electron conversion in the presence of a nucleus would be unambiguous evidence of physics Beyond the Standard Model. Two experiments, COMET at J-PARC and Mu2e at Fermilab, will search for this process in the coming decade. Barring discovery, these experiments will provide upper-limits on this branching ratio up to 10,000 times better than previously published. COMET/Mu2e developed a joint venture, the AlCap Experiment, to measure particle emission spectra from muonic interactions in a number of materials. As a major source of background hits in COMET/Mu2e detectors, AlCap sought to measure the charged particle and neutron spectra following nuclear capture on the candidate target materials aluminum and titanium. Additionally, COMET/Mu2e are exploring normalization schemes via AlCap's measurement of the photon spectra following both atomic and nuclear capture. Over the course of 2013 and 2015, AlCap performed three runs at the Paul Scherrer Institut in Switzerland. The first acquired preliminary data for all spectra, the second run collected only neutron and photon data, and the third primarily charged particle data. Preliminary analyses of the first two runs, already impactful for COMET/Mu2e, is presented along with a summary of the third.

Enhanced electrical properties, color-tunable up-conversion luminescence, and temperature sensing behaviour in Er-doped Bi3Ti1.5W0.5O9 multifunctional ferroelectric ceramics

NASA Astrophysics Data System (ADS)

Zhang, Ying; Li, Jun; Chai, Xiaona; Wang, Xusheng; Li, Yongxiang; Yao, Xi

2017-03-01

Er-doped Bi3Ti1.5W0.5O9 (BTW-x) ferroelectric ceramics were prepared by a conventional solid-state reaction synthesis method, and their structure, electrical properties, up-conversion (UC) luminescence, and temperature sensing behaviour were investigated. A high piezoelectric coefficient d33 (9.6 pC/N), a large remnant polarization Pr (12.75 μC/cm2), a high Curie temperature Tc (730.2 °C), and the optimal luminescent intensity are obtained for the samples at x = 0.05. By changing the Er doped concentration, the BTW-x ceramics are capable of generating various UC spectra and the color could be tunable from green to yellow. According to the fluorescence intensity ratio of green emissions at 532.6 nm and 549.2 nm in the temperature range from 83 K to 423 K, optical temperature sensing properties are investigated and the maximum sensing sensitivity is found to be 0.00314 K-1 at 423 K. The results conclude that BTW-x would be a candidate in high temperature sensor, fluorescence thermometry, and opto-electronic integration applications.

Self-oscillations in field emission nanowire mechanical resonators: a nanometric dc-ac conversion.

PubMed

Ayari, Anthony; Vincent, Pascal; Perisanu, Sorin; Choueib, May; Gouttenoire, Vincent; Bechelany, Mikhael; Cornu, David; Purcell, Stephen T

2007-08-01

We report the observation of self-oscillations in a bottom-up nanoelectromechanical system (NEMS) during field emission driven by a constant applied voltage. An electromechanical model is explored that explains the phenomenon and that can be directly used to develop integrated devices. In this first study, we have already achieved approximately 50% dc/ac (direct to alternating current) conversion. Electrical self-oscillations in NEMS open up a new path for the development of high-speed, autonomous nanoresonators and signal generators and show that field emission (FE) is a powerful tool for building new nanocomponents.

Searching for the optimal synthesis parameters of InP/CdxZn1-xSe quantum dots when combined with a broad band phosphor to optimize color rendering and efficacy of a hybrid remote phosphor white LED

NASA Astrophysics Data System (ADS)

Ryckaert, Jana; Correia, António; Smet, Kevin; Tessier, Mickael D.; Dupont, Dorian; Hens, Zeger; Hanselaer, Peter; Meuret, Youri

2017-09-01

Combining traditional phosphors with a broad emission spectrum and non-scattering quantum dots with a narrow emission spectrum can have multiple advantages for white LEDs. It allows to reduce the amount of scattering in the wavelength conversion element, increasing the efficiency of the complete system. Furthermore, the unique possibility to tune the emission spectrum of quantum dots allows to optimize the resulting LED spectrum in order to achieve optimal color rendering properties for the light source. However, finding the optimal quantum dot properties to achieve optimal efficacy and color rendering is a non-trivial task. Instead of simply summing up the emission spectra of the blue LED, phosphor and quantum dots, we propose a complete simulation tool that allows an accurate analysis of the final performance for a range of different quantum dot synthesis parameters. The recycling of the reflected light from the wavelength conversion element by the LED package is taken into account, as well as the re-absorption and the associated red-shift. This simulation tool is used to vary two synthesis parameters (core size and cadmium fraction) of InP/CdxZn1-xSe quantum dots. We find general trends for the ideal quantum dot that should be combined with a specific YAG:Ce broad band phosphor to obtain optimal efficiency and color rendering for a white LED with a specific pumping LED and recycling cavity, with a desired CCT of 3500K.

Intense blue up-conversion luminescence in Tm 3+/Yb 3+ codoped oxyfluoride glass-ceramics containing β-PbF 2 nanocrystals

NASA Astrophysics Data System (ADS)

Zhang, Junjie; Duan, Zhongchao; He, Dongbing; Dai, Shixun; Zhang, Liyan; Hu, Lili

2005-12-01

Up-conversion luminescence properties of a Tm 3+/Yb 3+ codoped oxyfluoride glass-ceramics under 980 nm excitation are investigated. Intense blue emission centered at 476 nm, corresponding to 1G 4 → 3H 6 transitions of Tm 3+ was simultaneously observed in the transparent oxyfluoride glass ceramics at room temperature. The intensity of the blue up-conversion luminescence in a 1 mol% YbF 3-containing glass-ceramic was found to be about 40 times stronger than that in the precursor oxyfluoride glass. The reason for the intense Tm 3+ up-conversion luminescence in the oxyfluoride glass-ceramics is discussed. The dependence of up-conversion intensities on excitation power and possible up-conversion mechanism are also evaluated.

Intense blue up-conversion luminescence in Tm3+/Yb3+ codoped oxyfluoride glass-ceramics containing beta-PbF2 nanocrystals.

PubMed

Zhang, Junjie; Duan, Zhongchao; He, Dongbing; Dai, Shixun; Zhang, Liyan; Hu, Lili

2005-12-01

Up-conversion luminescence properties of a Tm3+/Yb3+ codoped oxyfluoride glass-ceramics under 980 nm excitation are investigated. Intense blue emission centered at 476 nm, corresponding to 1G4-->3H6 transitions of Tm3+ was simultaneously observed in the transparent oxyfluoride glass ceramics at room temperature. The intensity of the blue up-conversion luminescence in a 1 mol% YbF3-containing glass-ceramic was found to be about 40 times stronger than that in the precursor oxyfluoride glass. The reason for the intense Tm3+ up-conversion luminescence in the oxyfluoride glass-ceramics is discussed. The dependence of up-conversion intensities on excitation power and possible up-conversion mechanism are also evaluated.

Note: Enhancement of the extreme ultraviolet emission from a potassium plasma by dual laser irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Higashiguchi, Takeshi, E-mail: higashi@cc.utsunomiya-u.ac.jp; Yamaguchi, Mami; Otsuka, Takamitsu

2014-09-15

Emission spectra from multiply charged potassium ions ranging from K{sup 3+} to K{sup 5+} have been obtained in the extreme ultraviolet (EUV) spectral region. A strong emission feature peaking around 38 nm, corresponding to a photon energy of 32.6 eV, is the dominant spectral feature at time-averaged electron temperatures in the range of 8−12 eV. The variation of this emission with laser intensity and the effects of pre-pulses on the relative conversion efficiency (CE) have been explored experimentally and indicate that an enhancement of about 30% in EUV CE is readily attainable.

The Supercritical Pile Model: Prompt Emission Across the Electromagnetic Spectrum

NASA Technical Reports Server (NTRS)

Kazanas, Demos; Mastichiadis, A.

2008-01-01

The "Supercritical Pile" GRB model is an economical model that provides the dissipation necessary to convert explosively the energy stored in relativistic protons in the blast wave of a GRB into radiation; at the same time it produces spectra whose luminosity peaks at 1 MeV in the lab frame, the result of the kinematics of the proton-photon - pair production reaction that effects the conversion of proton energy to radiation. We outline the fundamental notions behind the "Supercritical Pile" model and discuss the resulting spectra of the prompt emission from optical to gamma-ray energies of order Gamma^2 m_ec^2, (Gamma is the Lorentz factor of the blast wave) present even in the absence of an accelerated particle distribution and compare our results to bursts that cover this entire energy range. Particular emphasis is given on the emission at the GLAST energy range both in the prompt and the afterglow stages of the burst.

Towards terahertz detection and calibration through spontaneous parametric down-conversion in the terahertz idler-frequency range generated by a 795 nm diode laser system

NASA Astrophysics Data System (ADS)

Kornienko, Vladimir V.; Kitaeva, Galiya Kh.; Sedlmeir, Florian; Leuchs, Gerd; Schwefel, Harald G. L.

2018-05-01

We study a calibration scheme for terahertz wave nonlinear-optical detectors based on spontaneous parametric down-conversion. Contrary to the usual low wavelength pump in the green, we report here on the observation of spontaneous parametric down-conversion originating from an in-growth poled lithium niobate crystal pumped with a continuous wave 50 mW, 795 nm diode laser system, phase-matched to a terahertz frequency idler wave. Such a system is more compact and allows for longer poling periods as well as lower losses in the crystal. Filtering the pump radiation by a rubidium-87 vapor cell allowed the frequency-angular spectra to be obtained down to ˜0.5 THz or ˜1 nm shift from the pump radiation line. The presence of an amplified spontaneous emission "pedestal" in the diode laser radiation spectrum significantly hampers the observation of spontaneous parametric down-conversion spectra, in contrast to conventional narrowband gas lasers. Benefits of switching to longer pump wavelengths are pointed out, such as collinear optical-terahertz phase-matching in bulk crystals.

FT-IR spectroscopic studies of polycyclic aromatic hydrocarbons

NASA Technical Reports Server (NTRS)

Salisbury, D. W.; Allen, J. E., Jr.; Donn, B.; Moore, W. J.; Khanna, R. K.

1990-01-01

Proper assessment of the hypothesis which correlates polycyclic aromatic hydrocarbons (PAHs) with the unidentified infrared emission bands requires additional experimental laboratory data. In order to address this need, thermal infrared emission studies were performed on a subset of PAHs suggested to be of astrophysical importance. It was proposed that infrared emission from interstellar PAHs occurs following absorption of an ultraviolet photon. Since energy transfer to the ground electronic state can be rapid for a species in which intersystem crossing is negligible, the emission spectrum may be viewed as resulting from an equilibrium vibrational temperature (Leger and d'Hendecourt, 1987). This has been the basis for using infrared absorption spectra to calculate the corresponding emission spectra at various temperatures. These calculations were made using room temperature infrared absorption coefficients instead of those at the temperature of interest because of the latter's unavailability. The present studies are designed to address the differences between the calculated and experimental thermal emission spectra and to provide information which will be useful in future ultraviolet induced infrared fluorescence studies. The emission spectra have been obtained for temperatures up to 825K using an emission cell designed to mount against an external port of an FT-IR spectrometer. These spectra provide information concerning relative band intensities and peak positions which is unavailable from previous calculations.

Paradigms and challenges for bioapplication of rare earth upconversion luminescent nanoparticles: small size and tunable emission/excitation spectra.

PubMed

Sun, Ling-Dong; Wang, Ye-Fu; Yan, Chun-Hua

2014-04-15

Rare earth (RE) materials, which are excited in the ultraviolet and emit in the visible light spectrum, are widely used as phosphors for lamps and displays. In the 1960's, researchers reported an abnormal emission phenomenon where photons emitted from a RE element carried more energy than those absorbed, owing to the sequential energy transfer between two RE ions--Yb(3+)-sensitized Er(3+) or Tm(3+)--in the solid state. After further study, researchers named this abnormal emission phenomenon upconversion (UC) emission. More recent approaches take advantage of solution-based synthesis, which allows creation of homogenous RE nanoparticles (NPs) with controlled size and structure that are capable of UC emission. Such nanoparticles are useful for many applications, especially in biology. For these applications, researchers seek small NPs with high upconversion emission intensity. These UCNPs have the potential to have multicolor and tunable emissions via various activators. A vast potential for future development remains by developing molecular antennas and energy transfer within RE ions. We expect UCNPs with optimized spectra behavior to meet the increasing demand of potential applications in bioimaging, biological detection, and light conversion. This Account focuses on efforts to control the size and modulate the spectra of UCNPs. We first review efforts in size control. One method is careful control of the synthesis conditions to manipulate particle nucleation and growth, but more recently researchers have learned that the doping conditions can affect the size of UCNPs. In addition, constructing homogeneous core/shell structures can control nanoparticle size by adjusting the shell thickness. After reviewing size control, we consider how diverse applications impose different requirements on excitation and/or emission photons and review recent developments on tuning of UC spectral profiles, especially the extension of excitation/emission wavelengths and the adjustment and purification of emission colors. We describe strategies that employ various dopants and others that build rationally designed nanostructures and nanocomposites to meet these goals. As the understanding of the energy transfer in the UC process has improved, core/shell structures have been proved useful for simultaneous tuning of excitation and emission wavelengths. Finally, we present a number of typical examples to highlight the upconverted emission in various applications, including imaging, detection, and sensing. We believe that with deeper understanding of emission phenomena and the ability to tune spectral profiles, UCNPs could play an important role in light conversion studies and applications.

Explanation of the cw operation of the Er3+ 3-μm crystal laser

NASA Astrophysics Data System (ADS)

Pollnau, M.; Graf, Th.; Balmer, J. E.; Lüthy, W.; Weber, H. P.

1994-05-01

A computer simulation of the Er3+ 3-μm crystal laser considering the full rate-equation scheme up to the 4F7/2 level has been performed. The influence of the important system parameters on lasing and the interaction of these parameters has been clarified with multiple-parameter variations. Stimulated emission is fed mainly by up-conversion from the lower laser level and in many cases is reduced by the quenching of the lifetime of this level. However, also without up-conversion a set of parameters can be found that allows lasing. Up-conversion from the upper laser level is detrimental to stimulated emission but may be compensated by cross relaxation from the 4S3/2 level. For a typical experimental situation we started with the parameters of Er3+:LiYF4. In addition, the host materials Y3Al5O12 (YAG), YAlO3, Y3Sc2Al3O12 (YSGG), and BaY2F8, as well as the possibilities of codoping, are discussed. In view of the consideration of all excited levels up to 4F7/2, all lifetimes and branching ratios, ground-state depletion, excited-state absorption, three up-conversion processes as well as their inverse processes, stimulated emission, and a realistic resonator design, this is, to our knowledge, the most detailed investigation of the Er3+ 3-μm crystal laser performed so far.

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX₃, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut.

PubMed

Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I; Krieg, Franziska; Caputo, Riccarda; Hendon, Christopher H; Yang, Ruo Xi; Walsh, Aron; Kovalenko, Maksym V

2015-06-10

Metal halides perovskites, such as hybrid organic-inorganic CH3NH3PbI3, are newcomer optoelectronic materials that have attracted enormous attention as solution-deposited absorbing layers in solar cells with power conversion efficiencies reaching 20%. Herein we demonstrate a new avenue for halide perovskites by designing highly luminescent perovskite-based colloidal quantum dot materials. We have synthesized monodisperse colloidal nanocubes (4-15 nm edge lengths) of fully inorganic cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I or mixed halide systems Cl/Br and Br/I) using inexpensive commercial precursors. Through compositional modulations and quantum size-effects, the bandgap energies and emission spectra are readily tunable over the entire visible spectral region of 410-700 nm. The photoluminescence of CsPbX3 nanocrystals is characterized by narrow emission line-widths of 12-42 nm, wide color gamut covering up to 140% of the NTSC color standard, high quantum yields of up to 90%, and radiative lifetimes in the range of 1-29 ns. The compelling combination of enhanced optical properties and chemical robustness makes CsPbX3 nanocrystals appealing for optoelectronic applications, particularly for blue and green spectral regions (410-530 nm), where typical metal chalcogenide-based quantum dots suffer from photodegradation.

White up-conversion emission in Ho3+/Tm3+/Yb3+ tri-doped glass ceramics embedding BaF2 nanocrystals

NASA Astrophysics Data System (ADS)

Li, Chenxia; Xu, Shiqing; Ye, Rengguang; Deng, Degang; Hua, Youjie; Zhao, Shilong; Zhuang, Songlin

2011-04-01

Ho3+/Tm3+/Yb3+ tri-doped glass ceramics with white light emitting have been developed and demonstrated. Pumped by 980 nm laser diode (LD), intensive red, green and blue up-conversions (UC) were obtained. The green emission is assigned to Ho3+ ion and the blue emission is assigned to Tm3+ ion, whereas the red emission is the combination contribution of the Ho3+ and Tm3+ ions. The RGB intensities could be adjusted by tuning the rare-earth ion concentration and pump power intensity. Thus, multicolor of the luminescence, including perfect white light with CIE-X=0.329 and CIE-Y=0.342 in the 1931 CIE chromaticity diagram can be obtained in 0.15 Ho3+/0.2Tm3+/3Yb3+ tri-doped glass ceramics embedding BaF2 nanocrystals pumped by a single infrared laser diode source of 980 nm at 500 mW. The up-conversion luminescence mechanism of Yb3+ sensitize Ho3+ and Tm3+ ions and the energy transfer from Ho3+ to Tm3+ in oxy-fluoride silicate glass ceramics were analyzed.

Plasmon-photon conversion to near-infrared emission from Yb(3+): (Au/Ag-nanoparticles) in tungsten-tellurite glasses.

PubMed

Rivera, V A G; Ledemi, Yannick; Pereira-da-Silva, Marcelo A; Messaddeq, Younes; Marega, Euclydes

2016-01-04

This manuscript reports on the interaction between (2)F5/2→(2)F7/2 radiative transition from Yb(3+) ions and localized surface plasmon resonance (from gold/silver nanoparticles) in a tungsten-tellurite glass. Such an interaction, similar to the down-conversion process, results in the Yb(3+) emission in the near-infrared region via resonant and non-resonant energy transfers. We associated such effects with the dynamic coupling described by the variations generated by the Hamiltonian HDC in either the oscillator strength, or the local crystal field, i.e. the line shape changes in the emission band. Here, the Yb(3+) ions emission is achieved through plasmon-photon coupling, observable as an enhancement or quenching in the luminescence spectra. Metallic nanoparticles have light-collecting capability in the visible spectrum and can accumulate almost all the photon energy on a nanoscale, which enable the excitation and emission of the Yb(3+) ions in the near-infrared region. This plasmon-photon conversion was evaluated from the cavity's quality factor (Q) and the coupling (g) between the nanoparticles and the Yb(3+) ions. We have found samples of low-quality cavities and strong coupling between the nanoparticles and the Yb(3+) ions. Our research can be extended towards the understanding of new plasmon-photon converters obtained from interactions between rare-earth ions and localized surface plasmon resonance.

Plasmon-photon conversion to near-infrared emission from Yb3+: (Au/Ag-nanoparticles) in tungsten-tellurite glasses

PubMed Central

Rivera, V. A. G.; Ledemi, Yannick; Pereira-da-Silva, Marcelo A.; Messaddeq, Younes; Marega Jr, Euclydes

2016-01-01

This manuscript reports on the interaction between 2F5/2→2F7/2 radiative transition from Yb3+ ions and localized surface plasmon resonance (from gold/silver nanoparticles) in a tungsten-tellurite glass. Such an interaction, similar to the down-conversion process, results in the Yb3+ emission in the near-infrared region via resonant and non-resonant energy transfers. We associated such effects with the dynamic coupling described by the variations generated by the Hamiltonian HDC in either the oscillator strength, or the local crystal field, i.e. the line shape changes in the emission band. Here, the Yb3+ ions emission is achieved through plasmon-photon coupling, observable as an enhancement or quenching in the luminescence spectra. Metallic nanoparticles have light-collecting capability in the visible spectrum and can accumulate almost all the photon energy on a nanoscale, which enable the excitation and emission of the Yb3+ ions in the near-infrared region. This plasmon-photon conversion was evaluated from the cavity’s quality factor (Q) and the coupling (g) between the nanoparticles and the Yb3+ ions. We have found samples of low-quality cavities and strong coupling between the nanoparticles and the Yb3+ ions. Our research can be extended towards the understanding of new plasmon-photon converters obtained from interactions between rare-earth ions and localized surface plasmon resonance. PMID:26725938

Prompt fission neutron multiplicity and spectrum model for 30-80 MeV neutrons incident on 238U

NASA Astrophysics Data System (ADS)

Tudora, Anabella; Vladuca, G.; Morillon, B.

2004-08-01

The improved Los Alamos model is developed for the first time in order to provide prompt fission neutron multiplicity, prompt fission neutron spectra and other quantities at high incident neutron energies where the fission of secondary compound nuclei formed by charged particle emission occurs. In this model (exemplified by the n+ 238U reaction up to 80 MeV incident energy) the fission of the secondary nuclei formed by proton emission, neutron evaporation from the nuclei formed by proton emission, deuteron emission, alpha emission and neutron evaporation from the nuclei formed by alpha emission is taken into account. Input model parameters and related excitation energy dependences are determined using available experimental information and systematics as well as total and partial neutron induced fission cross-sections and their ratios obtained separately from a recent evaluation performed up to medium energies. Our present model predictions are in good agreement with the measured prompt neutron spectra and multiplicities.

Impact of two different types of grassland-to-cropland-conversion on dynamics of soil organic matter mineralization and N2O emission

NASA Astrophysics Data System (ADS)

Roth, G.; Flessa, H.; Helfrich, M.; Well, R.

2012-04-01

Conversion of grassland to arable land often causes a decrease of soil organic matter stocks and it increases nitrate leaching and the emission of the greenhouse gases CO2 and N2O. Conversion methods which minimize the mechanical impact on the surface soil may reduce mineralization rates and greenhouse gas emissions. We determined the effect of two different types of grassland to maize conversion (a) plowing of the sward followed by seeding of maize and (b) chemical killing of the sward by glyphosate followed by direct seed of maize) on the mineralization of grassland derived organic matter, the release of nitrate and the emission of N2O. The field experiment was carried out at the research station Kleve which is located in North Rhine-Westphalia, Germany. A four times replicated plot experiment with the following treatments was set up in April 2010: (i) mechanical conversion of grassland to maize (ii) chemical conversion grassland to maize and (iii) continuous grassland as reference. Nitrogen fertilization was 137 kg N ha-1 for maize and 250 kg N ha-1 for grassland. Soil respiration and emission of N2O were measured weekly for one year using manual closed chambers and gas chromatography. Emission of CO2 from mineralization of grassland-derived organic matter was determined from the δ13C signature of soil respiration. Soil respiration was mainly fueled by mineralization of grassland-derived organic carbon. There was no effect of the type of grassland conversion on total mineralization of organic matter originating from grassland. Both grassland to maize conversion treatments exhibited very high soil nitrate concentrations one year after grassland conversion (about 250 kg NO3-N in 0 - 90 cm). Total N2O emission decreased in the order chemical conversion of grassland (25.5) > mechanical conversion of grassland (20.1) > permanent grassland (10.8). Emissions were highest after harvest of maize when soil moisture increased. The results show that both types of grassland-to-maize conversion resulted in a large surplus of soil nitrate which promotes nitrate leaching to the groundwater and indirect N2O emissions. In addition, it caused high direct N2O emissions. We found no evidence that grassland conversion without mechanical plowing is an option to reduce groundwater contamination and greenhouse gas emission to the atmosphere.

Local H i emissivity measured with FERMI-LAT and implications for Cosmic-ray spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Casandjian, Jean -Marc

Cosmic-ray (CR) electrons and nuclei interact with the Galactic interstellar gas and produce high-energy γ-rays. The γ-ray emission rate per hydrogen atom, called emissivity, provides a unique indirect probe of the CR flux. We present the measurement and the interpretation of the emissivity in the solar neighborhood for γ-ray energy from 50 MeV to 50 GeV. We analyzed a subset of 4 yr of observations from the Large Area Telescope (LAT) aboard the Fermi Gamma-ray Space Telescope ( Fermi) restricted to absolute latitudesmore » $$10^\\circ \\lt | b| \\lt 70^\\circ $$. From a fit to the LAT data including atomic, molecular, and ionized hydrogen column density templates, as well as a dust optical depth map, we derived the emissivities, the molecular hydrogen–to–CO conversion factor $${X}_{\\mathrm{CO}}=(0.902\\pm 0.007)\\times {10}^{20}$$ cm–2 (K km s–1)–1, and the dust-to-gas ratio $${X}_{\\mathrm{DUST}}=(41.4\\pm 0.3)\\times {10}^{20}$$ cm–2 mag–1. Moreover, we detected for the first time γ-ray emission from ionized hydrogen. We compared the extracted emissivities to those calculated from γ-ray production cross sections and to CR spectra measured in the heliosphere. We observed that the experimental emissivities are reproduced only if the solar modulation is accounted for. This provides a direct detection of solar modulation observed previously through the anticorrelation between CR fluxes and solar activity. Lastly, we fitted a parameterized spectral form to the heliospheric CR observations and to the Fermi-LAT emissivity and obtained compatible local interstellar spectra for proton and helium kinetic energy per nucleon between between 1 and 100 GeV and for electron–positrons between 0.1 and 100 GeV.« less

Local H i emissivity measured with FERMI-LAT and implications for Cosmic-ray spectra

DOE PAGES

Casandjian, Jean -Marc

2015-06-20

Cosmic-ray (CR) electrons and nuclei interact with the Galactic interstellar gas and produce high-energy γ-rays. The γ-ray emission rate per hydrogen atom, called emissivity, provides a unique indirect probe of the CR flux. We present the measurement and the interpretation of the emissivity in the solar neighborhood for γ-ray energy from 50 MeV to 50 GeV. We analyzed a subset of 4 yr of observations from the Large Area Telescope (LAT) aboard the Fermi Gamma-ray Space Telescope ( Fermi) restricted to absolute latitudesmore » $$10^\\circ \\lt | b| \\lt 70^\\circ $$. From a fit to the LAT data including atomic, molecular, and ionized hydrogen column density templates, as well as a dust optical depth map, we derived the emissivities, the molecular hydrogen–to–CO conversion factor $${X}_{\\mathrm{CO}}=(0.902\\pm 0.007)\\times {10}^{20}$$ cm–2 (K km s–1)–1, and the dust-to-gas ratio $${X}_{\\mathrm{DUST}}=(41.4\\pm 0.3)\\times {10}^{20}$$ cm–2 mag–1. Moreover, we detected for the first time γ-ray emission from ionized hydrogen. We compared the extracted emissivities to those calculated from γ-ray production cross sections and to CR spectra measured in the heliosphere. We observed that the experimental emissivities are reproduced only if the solar modulation is accounted for. This provides a direct detection of solar modulation observed previously through the anticorrelation between CR fluxes and solar activity. Lastly, we fitted a parameterized spectral form to the heliospheric CR observations and to the Fermi-LAT emissivity and obtained compatible local interstellar spectra for proton and helium kinetic energy per nucleon between between 1 and 100 GeV and for electron–positrons between 0.1 and 100 GeV.« less

Fluorine Kα X-Ray Emission Spectra of MgF2, CaF2, SrF2 and BaF2

NASA Astrophysics Data System (ADS)

Sugiura, Chikara; Konishi, Wataru; Shoji, Shizuko; Kojima, Shinjiro

1990-11-01

The fluorine Kα emission spectra in fluorescence from a series of alkaline-earth fluorides MF2 (M=Mg, Ca, Sr and Ba) are measured with a high-resolution two-crystal vacuum spectrometer. An anomalously low intensity of the K1L1 satellite peak arising from 1s-1(2s2p)-1 initial states is observed for SrF2. The measured emission spectra are presented along with the UPS spectra of the F- 2p valence bands obtained by Poole et al. and the fluorine K absorption-edge spectra by Oizumi et al. By using these spectra, the first peak or shoulder in the fluorine K absorption-edge spectra is identified as being due to a core exciton which is formed below the bottom of the conduction band. The binding energy of the exciton is estimated to be 1.3(± 0.3), 1.1(± 0.2), 1.0(± 0.2) and 1.7(± 0.2) eV for MgF2, CaF2, SrF2 and BaF2, respectively.

An investigation of down-conversion luminescence properties of rare earth doped CaMoO4 phosphors for solar cell application

NASA Astrophysics Data System (ADS)

Verma, Akta; Sharma, S. K.

2018-05-01

In the present work, we have synthesized a CaMoO4:(1%)Er3+,(1%)Yb3+ down-converting phosphor by hydrothermal method. The primary goal of studying down-conversion is to enhance the conversion efficiency of Si-solar cell by converting one high energy (UV) photon into two low energy (NIR) photons. The various characterization such as XRD, FESEM and Photoluminescence (PL) were carried out. The X-ray diffraction (XRD) pattern exhibit tetragonal crystal structure and has a space group of I41a (88). The FESEM microphotograph shows surface morphology having a abundance of particles in spherical shape. The PL emission spectra were recorded both in Visible and NIR regions. There is hypertensive emission peak at 555 nm in the visible region due to 4S3/2 → 4I15/2 transition of Er3+ ions and an emission at 980 nm (2F5/2 → 2F7/2) due to Yb3+ ions. The result shows a demand of this down-converting material in the field of solar energy to improve the efficiency of Si-solar-cell.

Zirconia nanocrystals as submicron level biological label

NASA Astrophysics Data System (ADS)

Smits, K.; Liepins, J.; Gavare, M.; Patmalnieks, A.; Gruduls, A.; Jankovica, D.

2012-08-01

Inorganic nanocrystals are of increasing interest for their usage in biology and pharmacology research. Our interest was to justify ZrO2 nanocrystal usage as submicron level biological label in baker's yeast Saccharomyces cerevisia culture. For the first time (to our knowledge) images with sub micro up-conversion luminescent particles in biologic media were made. A set of undoped as well as Er and Yb doped ZrO2 samples at different concentrations were prepared by sol-gel method. The up-conversion luminescence for free standing and for nanocrystals with baker's yeast cells was studied and the differences in up-conversion luminescence spectra were analyzed. In vivo toxic effects of ZrO2 nanocrystals were tested by co-cultivation with baker's yeast.

Additives and solvents-induced phase and morphology modification of NaYF{sub 4} for improving up-conversion emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhuang, Jianle, E-mail: zhuangjianle@126.com; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275; Yang, Xianfeng

Both cubic and hexagonal NaYF{sub 4} were synthesized in different reaction systems via hydro/solvo-thermal route. The effects of reaction temperature, solvents, and additives on the synthesis of NaYF{sub 4} have been studied in detail. It has been shown that phase transformation from cubic NaYF{sub 4} to hexagonal NaYF{sub 4} always occurred. The sequence of the ability for inducing the phase transformation was ethanol>H{sub 2}O>acetic acid. It is found that ethanol can not only facilitate the formation of hexagonal NaYF{sub 4} but also control the growth of the crystal. This is quite unusual for the growth of H-NaYF{sub 4}. The up-conversionmore » emission properties of Yb/Er co-doped NaYF{sub 4} have also been investigated and the results demonstrated some general principles for improving up-conversion emission. - Graphical abstract: Additives and solvents can induce the phase transformation of NaYF{sub 4}, typically the use of organic sodium salt and ethanol. - Highlights: • The effect of additives and solvents on the synthesis of NaYF{sub 4} was studied in detail. • Ethanol can facilitate the formation of H-NaYF{sub 4} while acetic acid restrain it. • Three general principles for improving up-conversion emission were summarized.« less

Designing lanthanide-doped nanocrystals with both up- and down-conversion luminescence for anti-counterfeiting

NASA Astrophysics Data System (ADS)

Liu, Yanlan; Ai, Kelong; Lu, Lehui

2011-11-01

The widespread forgery in all kinds of paper documents and certificates has become a real threat to society. Traditional fluorescent anti-counterfeiting materials generally exhibit unicolor display and suffer greatly from substitution, thus leading to a poor anti-counterfeiting effect. In this work, unseen but significant enhanced blue down-conversion emission from oleic acid-stabilized lanthanide-doped fluoride nanocrystals is first present and the mechanism is proposed and validated. This not only endows these nanocrystals with dual-mode fluorescence, but also offers a simplified synthesis approach for dual-mode fluorescent nanocrystals involving no further complicated assembly or coating procedures, unlike the traditional methods. Furthermore, by changing the host/dopant combination or the content of dopant, these nanocrystals can exhibit simultaneously multicolor up-conversion emission under excitation at near-infrared light and unalterable blue down-conversion emission under ultraviolet light. A preliminary investigation of their anti-counterfeiting performance has been made, and the results indicate that this color tuning capability and high concealment makes these nanocrystals behave in a similar way to chameleons and can provide a strengthened and more reliable anti-counterfeiting effect.The widespread forgery in all kinds of paper documents and certificates has become a real threat to society. Traditional fluorescent anti-counterfeiting materials generally exhibit unicolor display and suffer greatly from substitution, thus leading to a poor anti-counterfeiting effect. In this work, unseen but significant enhanced blue down-conversion emission from oleic acid-stabilized lanthanide-doped fluoride nanocrystals is first present and the mechanism is proposed and validated. This not only endows these nanocrystals with dual-mode fluorescence, but also offers a simplified synthesis approach for dual-mode fluorescent nanocrystals involving no further complicated assembly or coating procedures, unlike the traditional methods. Furthermore, by changing the host/dopant combination or the content of dopant, these nanocrystals can exhibit simultaneously multicolor up-conversion emission under excitation at near-infrared light and unalterable blue down-conversion emission under ultraviolet light. A preliminary investigation of their anti-counterfeiting performance has been made, and the results indicate that this color tuning capability and high concealment makes these nanocrystals behave in a similar way to chameleons and can provide a strengthened and more reliable anti-counterfeiting effect. Electronic supplementary information (ESI) available: Fig. S1-S6, Table S. See DOI: 10.1039/c1nr10752f

Poly(vinylpyrrolidone) supported copper nanoclusters: glutathione enhanced blue photoluminescence for application in phosphor converted light emitting devices

NASA Astrophysics Data System (ADS)

Wang, Zhenguang; Susha, Andrei S.; Chen, Bingkun; Reckmeier, Claas; Tomanec, Ondrej; Zboril, Radek; Zhong, Haizheng; Rogach, Andrey L.

2016-03-01

Poly(vinylpyrrolidone) supported Cu nanoclusters were synthesized by reduction of Cu(ii) ions with ascorbic acid in water, and initially showed blue photoluminescence with a quantum yield of 8%. An enhancement of the emission quantum yield has been achieved by treatment of Cu clusters with different electron-rich ligands, with the most pronounced effect (photoluminescence quantum yield of 27%) achieved with glutathione. The bright blue emission of glutathione treated Cu NCs is fully preserved in the solid state powder, which has been combined with commercial green and red phosphors to fabricate down-conversion white light emitting diodes with a high colour rendering index of 92.Poly(vinylpyrrolidone) supported Cu nanoclusters were synthesized by reduction of Cu(ii) ions with ascorbic acid in water, and initially showed blue photoluminescence with a quantum yield of 8%. An enhancement of the emission quantum yield has been achieved by treatment of Cu clusters with different electron-rich ligands, with the most pronounced effect (photoluminescence quantum yield of 27%) achieved with glutathione. The bright blue emission of glutathione treated Cu NCs is fully preserved in the solid state powder, which has been combined with commercial green and red phosphors to fabricate down-conversion white light emitting diodes with a high colour rendering index of 92. Electronic supplementary information (ESI) available: The optical spectra of control experiments for Cu NC synthesis, optimization of the reaction conditions, and spectra for LEDs chips and blue LEDs. See DOI: 10.1039/c6nr00806b

Application of Ce3+ single-doped complexes as solar spectral downshifters for enhancing photoelectric conversion efficiencies of a-Si-based solar cells

NASA Astrophysics Data System (ADS)

Song, Pei; Jiang, Chun

2013-05-01

The effect on photoelectric conversion efficiency of an a-Si-based solar cell by applying a solar spectral downshifter of rare earth ion Ce3+ single-doped complexes including yttrium aluminum garnet Y3Al5O12 single crystals, nanostructured ceramics, microstructured ceramics and B2O3-SiO2-Gd2O3-BaO glass is studied. The photoluminescence excitation spectra in the region 360-460 nm convert effectively into photoluminescence emission spectra in the region 450-550 nm where a-Si-based solar cells exhibit a higher spectral response. When these Ce3+ single-doped complexes are placed on the top of an a-Si-based solar cell as precursors for solar spectral downshifting, theoretical relative photoelectric conversion efficiencies of nc-Si:H and a-Si:H solar cells approach 1.09-1.13 and 1.04-1.07, respectively, by means of AMPS-1D numerical modeling, potentially benefiting an a-Si-based solar cell with a photoelectric efficiency improvement.

Photoinduced intramolecular charge transfer in a cross-conjugated push-pull enediyne: implications toward photoreaction.

PubMed

Singh, Anuja; Pati, Avik Kumar; Mishra, Ashok Kumar

2018-05-30

Push-pull organic fluorophores are important owing to their interesting optoelectronical properties. Here we report the photophysics of a new cross-conjugated push-pull enediynyl dye which belongs to an unexplored class of π-conjugated donor-acceptor systems. Two N,N-dimethylaniline moieties serve as donors and one pyrene ring functions as an acceptor via a common Y-shaped 'enediyne' bridge which facilitates the cross-electronic communication. The dye exhibits dual emission from locally excited (LE) and intramolecular charge transfer (ICT) states. While the LE emission is dominant in non-polar solvents, the ICT emission predominates in polar solvents. Time-resolved fluorescence decay experiments reveal a relatively shorter lifetime component (∼0.5-0.9 ns) belonging to an ICT state and a relatively longer lifetime species (∼1.6-2.8 ns) corresponding to the LE state. The strong ICT behavior of the dye is manifested through the huge red-shift (4166 cm-1) of the emission spectra from non-polar cyclohexane to polar N,N-dimethylformamide. In contrast to many small push-pull organic dyes, the LE and ICT states of the push-pull enediynyl dye follow the same excitation pathway. The dominant red-shifted ICT emission (∼550 nm) intensity of the dye in polar solvent decreases with a concomitant appearance of the blue-shifted LE emission (∼385 nm) upon prolonged exposure to photons. This opens up a new photophysical strategy of achieving high contrast two fluorescence color conversion from yellow to blue.

Ultrafast hydrogen bond dynamics and partial electron transfer after photoexcitation of diethyl ester of 7-(diethylamino)-coumarin-3-phosphonic acid and its benzoxaphosphorin analog.

PubMed

Wagner, M S; Ilieva, E D; Petkov, P St; Nikolova, R D; Kienberger, R; Iglev, H

2015-04-21

The solvation dynamics after optical excitation of two phosphono-substituted coumarin derivatives dissolved in various solutions are studied by fluorescence up-conversion spectroscopy and quantum chemical simulations. The Kamlet-Taft analysis of the conventional absorption and emission spectra suggests weakening of the solvent-solute H-bonds upon optical excitation, which is in contrast to the results gained by the quantum simulations and earlier studies reported for coumarin derivatives without phosphono groups. The simulations give evidence that the solvent reorganisation around the excited fluorophore leads to partial electron transfer to the first solvation shell. The process occurs on a timescale between 1 and 10 ps depending on the solvent polarity and leads to a fast decay of the time-resolved emission signal. Using the ultrafast spectral shift of the time-dependent fluorescence we estimated the relaxation time of the H-bonds in the electronically excited state to be about 0.6 ps in water, 1.5 ps in ethanol and 2.8 ps in formamide.

Active media for up-conversion diode-pumped lasers

NASA Astrophysics Data System (ADS)

Tkachuk, Alexandra M.

1996-03-01

In this work, we consider the different methods of populating the initial and final working levels of laser transitions in TR-doped crystals under the selective 'up-conversion' and 'avalanche' diode laser pumping. On the basis of estimates of the probabilities of competing non-radiative energy-transfer processes rates obtained from the experimental data and theoretical calculations, we estimated the efficiency of the up-conversion pumping and selfquenching of the upper TR3+ states excited by laser-diode emission. The effect of the host composition, dopant concentration, and temperature on the output characteristics and up-conversion processes in YLF:Er; BaY2F8:Er; BaY2F8:Er,Yb and BaY2F8:Yb,Ho are determined.

DNA-mediated excitonic upconversion FRET switching

DOE PAGES

Kellis, Donald L.; Rehn, Sarah M.; Cannon, Brittany L.; ...

2015-11-17

Excitonics is a rapidly expanding field of nanophotonics in which the harvesting of photons, ensuing creation and transport of excitons via Förster resonant energy transfer (FRET), and subsequent charge separation or photon emission has led to the demonstration of excitonic wires, switches, Boolean logic and light harvesting antennas for many applications. FRET funnels excitons down an energy gradient resulting in energy loss with each step along the pathway. Conversely, excitonic energy up conversion via up conversion nanoparticles (UCNPs), although currently inefficient, serves as an energy ratchet to boost the exciton energy. Although FRET-based up conversion has been demonstrated, it suffersmore » from low FRET efficiency and lacks the ability to modulate the FRET. We have engineered an up conversion FRET-based switch by combining lanthanide-doped UCNPs and fluorophores that demonstrates excitonic energy up conversion by nearly a factor of 2, an excited state donor to acceptor FRET efficiency of nearly 25%, and an acceptor fluorophore quantum efficiency that is close to unity. These findings offer a promising path for energy up conversion in nanophotonic applications including artificial light harvesting, excitonic circuits, photovoltaics, nanomedicine, and optoelectronics.« less

Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics tuneable up-conversion phosphor

NASA Astrophysics Data System (ADS)

Méndez-Ramos, J.; Rodriguez, V. D.; Tikhomirov, V. K.; Del-Castillo, J.; Yanes, A. C.

2008-08-01

Transparent Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics have been prepared, 32(SiO{2}) 9(AlO{1.5}) 31.5(CdF{2}) 18.5(PbF{2}) 5.5(ZnF{2}): 3.5(Yb-Er-TmF{3}) mol%, where the co-dopants partition mostly to the fluoride PbF{2}-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm3+ and Er3+ can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2- and 3-photon up-conversion processes with pump power.

Internal combustion engine controls for reduced exhausts contaminants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matthews, D.R. Jr.

1974-06-04

An electrochemical control system for achieving optimum efficiency in the catalytic conversion of hydrocarbon and carbon monoxide emissions from internal combustion engines is described. The system automatically maintains catalyst temperature at a point for maximum pollutant conversion by adjusting ignition timing and fuel/air ratio during warm-up and subsequent operation. Ignition timing is retarded during engine warm-up to bring the catalytic converter to an efficient operating temperature within a minimum period of time. After the converter reaches a predetermined minimum temperature, the spark is advanced to within its normal operating range. A needle-valve adjustment during warm-up is employed to enrich themore » fuel/air mixture by approximately 10 percent. Following warm-up and attainment of a predetermined catalyst temperature, the needle valve is moved automatically to its normal position (e.g., a fuel/air ratio of 16:1). Although the normal lean mixture causes increased amounts of nitrogen oxide emissions, present NO/sub x/ converters appear capable of handling the increased emissions under normal operating conditions.« less

Quantitative analysis of Al-Si alloy using calibration free laser induced breakdown spectroscopy (CF-LIBS)

NASA Astrophysics Data System (ADS)

Shakeel, Hira; Haq, S. U.; Aisha, Ghulam; Nadeem, Ali

2017-06-01

The quantitative analysis of the standard aluminum-silicon alloy has been performed using calibration free laser induced breakdown spectroscopy (CF-LIBS). The plasma was produced using the fundamental harmonic (1064 nm) of the Nd: YAG laser and the emission spectra were recorded at 3.5 μs detector gate delay. The qualitative analysis of the emission spectra confirms the presence of Mg, Al, Si, Ti, Mn, Fe, Ni, Cu, Zn, Sn, and Pb in the alloy. The background subtracted and self-absorption corrected emission spectra were used for the estimation of plasma temperature as 10 100 ± 300 K. The plasma temperature and self-absorption corrected emission lines of each element have been used for the determination of concentration of each species present in the alloy. The use of corrected emission intensities and accurate evaluation of plasma temperature yield reliable quantitative analysis up to a maximum 2.2% deviation from reference sample concentration.

Cysteine optical sensing with an up-conversion host and two chemosensors derived from rhodamine: Construction, characterization and performance

NASA Astrophysics Data System (ADS)

Lin, Chen; Zhigang, Fang

2017-03-01

This paper focused on two rhodamine chemosensors for cysteine optical sensing. To minimize their photobleaching caused by excitation light, up-conversion NaYF4:Yb3 +/Er3 + nanocrystals were prepared and used as excitation host. Photophysical measurement on this host and the two chemosensors suggested that chemosensor absorption matched well with host emission. An efficient energy transfer between them was discussed and confirmed by their spectral analysis and emission lifetime comparison. Job's plot suggested that our chemosensors followed a simple recognition mechanism towards cysteine with binding stoichiometry of 1:1. Both chemosensors showed emission "off-on" effect triggered by cysteine and good photostability. Linear working curves with maximum sensitivity of 2.61 were obtained. S substituent was positive to improve selectivity.

High-order nonlinear optical processes in ablated carbon-containing materials: Recent approaches in development of the nonlinear spectroscopy using harmonic generation in the extreme ultraviolet range

NASA Astrophysics Data System (ADS)

Ganeev, R. A.

2017-08-01

The nonlinear spectroscopy using harmonic generation in the extreme ultraviolet range became a versatile tool for the analysis of the optical, structural and morphological properties of matter. The carbon-contained materials have shown the advanced properties among other studied species, which allowed both the definition of the role of structural properties on the nonlinear optical response and the analysis of the fundamental features of carbon as the attractive material for generation of coherent short-wavelength radiation. We review the studies of the high-order harmonic generation by focusing ultrashort pulses into the plasmas produced during laser ablation of various organic compounds. We discuss the role of ionic transitions of ablated carbon-containing molecules on the harmonic yield. We also show the similarities and distinctions of the harmonic and plasma spectra of organic compounds and graphite. We discuss the studies of the generation of harmonics up to the 27th order (λ = 29.9 nm) of 806 nm radiation in the boron carbide plasma and analyze the advantages and disadvantages of this target compared with the ingredients comprising B4C (solid boron and graphite) by comparing plasma emission and harmonic spectra from three species. We also show that the coincidence of harmonic and plasma emission wavelengths in most cases does not cause the enhancement or decrease of the conversion efficiency of this harmonic.

Multi-azimuthal-angle effects in self-induced supernova neutrino flavor conversions without axial symmetry

NASA Astrophysics Data System (ADS)

Mirizzi, Alessandro

2013-10-01

The flavor evolution of neutrinos emitted by a supernova (SN) core is strongly affected by the refractive effects associated with the neutrino-neutrino interactions in the deepest stellar regions. Till now, all numerical studies have assumed the axial symmetry for the “multi-angle effects” associated with the neutrino-neutrino interactions. Recently, it has been pointed out in Raffelt, Sarikas, and Seixas [Phys. Rev. Lett. 111, 091101 (2013)] that if this assumption is removed, a new multi-azimuthal-angle (MAA) instability emerges in the flavor evolution of the dense SN neutrino gas, in addition to the one caused by multi-zenith-angle effects. Inspired by this result, for the first time we numerically solve the nonlinear neutrino propagation equations in SN, introducing the azimuthal angle as an angular variable in addition to the usual zenith angle. We consider simple energy spectra with an excess of νe over ν¯e. We find that even starting with a complete axial symmetric neutrino emission, the MAA effects would lead to significant flavor conversions in normal mass hierarchy, in cases otherwise stable under the only multi-zenith-angle effects. The final outcome of the flavor conversions, triggered by the MAA instability, depends on the initial asymmetry between νe and ν¯e spectra. If it is sufficiently large, final spectra would show an ordered behavior with spectral swaps and splits. Conversely, for small flavor asymmetries flavor decoherence among angular modes develops, also affecting the flavor evolution in the inverted mass hierarchy.

Luminescence of Er 3+-doped nanostructured SiO 2-LaF 3 glass-ceramics prepared by the sol-gel method

NASA Astrophysics Data System (ADS)

Rodríguez, V. D.; Del Castillo, J.; Yanes, A. C.; Méndez-Ramos, J.; Torres, M.; Peraza, J.

2007-07-01

Transparent glass ceramics with composition of 95SiO2-5LaF3 doped with 0.1 mol% of Er3+ were synthesized by thermal treatment of precursor sol-gel glasses. Segregated LaF3 nanocrystals in the glass were confirmed from a structural analysis performed by X-ray diffraction. Blue, green and red efficient up-conversion emissions were observed under 980 nm excitation at room temperature. Under this excitation near infrared down-conversion at 1.55 μm is also observed. These results could be attributed to the precipitation of LaF3 nanocrystals and the incorporation of most Er3+ ions in these nanocrystals. The mechanisms involved in the up-conversion emissions could be ascribed to two and three photon processes.

A {sup 13}CO Detection in a Brightest Cluster Galaxy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vantyghem, A. N.; McNamara, B. R.; Hogan, M. T.

We present ALMA Cycle 4 observations of CO(1-0), CO(3-2), and {sup 13}CO(3-2) line emission in the brightest cluster galaxy (BCG) of RXJ0821+0752. This is one of the first detections of {sup 13}CO line emission in a galaxy cluster. Half of the CO(3-2) line emission originates from two clumps of molecular gas that are spatially offset from the galactic center. These clumps are surrounded by diffuse emission that extends 8 kpc in length. The detected {sup 13}CO emission is confined entirely to the two bright clumps, with any emission outside of this region lying below our detection threshold. Two distinct velocitymore » components with similar integrated fluxes are detected in the {sup 12}CO spectra. The narrower component (60 km s{sup −1} FWHM) is consistent in both velocity centroid and linewidth with {sup 13}CO(3-2) emission, while the broader (130–160 km s{sup −1}), slightly blueshifted wing has no associated {sup 13}CO(3-2) emission. A simple local thermodynamic model indicates that the {sup 13}CO emission traces 2.1 × 10{sup 9} M {sub ⊙} of molecular gas. Isolating the {sup 12}CO velocity component that accompanies the {sup 13}CO emission yields a CO-to-H{sub 2} conversion factor of α {sub CO} = 2.3 M {sub ⊙} (K km s{sup −1}){sup −1}, which is a factor of two lower than the Galactic value. Adopting the Galactic CO-to-H{sub 2} conversion factor in BCGs may therefore overestimate their molecular gas masses by a factor of two. This is within the object-to-object scatter from extragalactic sources, so calibrations in a larger sample of clusters are necessary in order to confirm a sub-Galactic conversion factor.« less

Modeling of radiative properties of Sn plasmas for extreme-ultraviolet source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sasaki, Akira; Sunahara, Atsushi; Furukawa, Hiroyuki

Atomic processes in Sn plasmas are investigated for application to extreme-ultraviolet (EUV) light sources used in microlithography. We develop a full collisional radiative (CR) model of Sn plasmas based on calculated atomic data using Hebrew University Lawrence Livermore Atomic Code (HULLAC). Resonance and satellite lines from singly and multiply excited states of Sn ions, which contribute significantly to the EUV emission, are identified and included in the model through a systematic investigation of their effect on the emission spectra. The wavelengths of the 4d-4f+4p-4d transitions of Sn{sup 5+} to Sn{sup 13+} are investigated, because of their importance for determining themore » conversion efficiency of the EUV source, in conjunction with the effect of configuration interaction in the calculation of atomic structure. Calculated emission spectra are compared with those of charge exchange spectroscopy and of laser produced plasma EUV sources. The comparison is also carried out for the opacity of a radiatively heated Sn sample. A reasonable agreement is obtained between calculated and experimental EUV emission spectra observed under the typical condition of EUV sources with the ion density and ionization temperature of the plasma around 10{sup 18} cm{sup -3} and 20 eV, respectively, by applying a wavelength correction to the resonance and satellite lines. Finally, the spectral emissivity and opacity of Sn plasmas are calculated as a function of electron temperature and ion density. The results are useful for radiation hydrodynamics simulations for the optimization of EUV sources.« less

High pressure luminescence spectra of CaMoO4:Ln3+ (Ln = Pr, Tb)

NASA Astrophysics Data System (ADS)

Mahlik, S.; Behrendt, M.; Grinberg, M.; Cavalli, E.; Bettinelli, M.

2013-03-01

Photoluminescence spectra and luminescence kinetics of pure CaMoO4 and CaMoO4 doped with Ln3+ (Ln = Pr or Tb) are presented. The spectra were obtained at high hydrostatic pressure up to 240 kbar applied in a diamond anvil cell. At ambient pressure undoped and doped samples exhibit a broad band emission extending between 380 and 700 nm with a maximum at 520 nm attributed to the {{MoO}}_{4}^{2-} luminescence. CaMoO4 doped with Pr3+ or Tb3+ additionally yields narrow emission lines related to f-f transitions. The undoped CaMoO4 crystal was characterized by a strong MoO{}_{4}^{2-} emission up to 240 kbar. In the cases of CaMoO4:Pr3+ and CaMoO4:Tb3+, high hydrostatic pressure caused quenching of Pr3+ and Tb3+ emission, and this effect was accompanied by a strong shortening of the luminescence lifetime. In doped samples, CaMoO4:Pr3+ and CaMoO4:Tb3+, quenching of the emission band attributed to {{MoO}}_{4}^{2-} was also observed, and at pressure above 130 kbar this luminescence was totally quenched. The effects mentioned above were related to the influence of the praseodymium (terbium) trapped exciton PTE (ITE—impurity trapped exciton) on the efficiency of the Pr3+ (Tb3+) and {{MoO}}_{4}^{2-} emissions.

Enhanced Power Conversion Efficiency of Perovskite Solar Cells with an Up-Conversion Material of Er3+-Yb3+-Li+ Tri-doped TiO2

NASA Astrophysics Data System (ADS)

Zhang, Zhenlong; Qin, Jianqiang; Shi, Wenjia; Liu, Yanyan; Zhang, Yan; Liu, Yuefeng; Gao, Huiping; Mao, Yanli

2018-05-01

In this paper, Er3+-Yb3+-Li+ tri-doped TiO2 (UC-TiO2) was prepared by an addition of Li+ to Er3+-Yb3+ co-doped TiO2. The UC-TiO2 presented an enhanced up-conversion emission compared with Er3+-Yb3+ co-doped TiO2. The UC-TiO2 was applied to the perovskite solar cells. The power conversion efficiency (PCE) of the solar cells without UC-TiO2 was 14.0%, while the PCE of the solar cells with UC-TiO2 was increased to 16.5%, which presented an increase of 19%. The results suggested that UC-TiO2 is an effective up-conversion material. And this study provided a route to expand the spectral absorption of perovskite solar cells from visible light to near-infrared using up-conversion materials.

Enhanced Power Conversion Efficiency of Perovskite Solar Cells with an Up-Conversion Material of Er3+-Yb3+-Li+ Tri-doped TiO2.

PubMed

Zhang, Zhenlong; Qin, Jianqiang; Shi, Wenjia; Liu, Yanyan; Zhang, Yan; Liu, Yuefeng; Gao, Huiping; Mao, Yanli

2018-05-11

In this paper, Er 3+ -Yb 3+ -Li + tri-doped TiO 2 (UC-TiO 2 ) was prepared by an addition of Li + to Er 3+ -Yb 3+ co-doped TiO 2 . The UC-TiO 2 presented an enhanced up-conversion emission compared with Er 3+ -Yb 3+ co-doped TiO 2 . The UC-TiO 2 was applied to the perovskite solar cells. The power conversion efficiency (PCE) of the solar cells without UC-TiO 2 was 14.0%, while the PCE of the solar cells with UC-TiO 2 was increased to 16.5%, which presented an increase of 19%. The results suggested that UC-TiO 2 is an effective up-conversion material. And this study provided a route to expand the spectral absorption of perovskite solar cells from visible light to near-infrared using up-conversion materials.

Iterative retrieval of surface emissivity and temperature for a hyperspectral sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borel, C.C.

1997-11-01

The central problem of temperature-emissivity separation is that we obtain N spectral measurements of radiance and need to find N + 1 unknowns (N emissivities and one temperature). To solve this problem in the presence of the atmosphere we need to find even more unknowns: N spectral transmissions {tau}{sub atmo}({lambda}) up-welling path radiances L{sub path}{up_arrow}({lambda}) and N down-welling path radiances L{sub path}{down_arrow}({lambda}). Fortunately there are radiative transfer codes such as MODTRAN 3 and FASCODE available to get good estimates of {tau}{sub atmo}({lambda}), L{sub path}{up_arrow}({lambda}) and L{sub path}{down_arrow}({lambda}) in the order of a few percent. With the growing use of hyperspectralmore » imagers, e.g. AVIRIS in the visible and short-wave infrared there is hope of using such instruments in the mid-wave and thermal IR (TIR) some day. We believe that this will enable us to get around using the present temperature - emissivity separation (TES) algorithms using methods which take advantage of the many channels available in hyperspectral imagers. The first idea we had is to take advantage of the simple fact that a typical surface emissivity spectrum is rather smooth compared to spectral features introduced by the atmosphere. Thus iterative solution techniques can be devised which retrieve emissivity spectra {epsilon} based on spectral smoothness. To make the emissivities realistic, atmospheric parameters are varied using approximations, look-up tables derived from a radiative transfer code and spectral libraries. By varying the surface temperature over a small range a series of emissivity spectra are calculated. The one with the smoothest characteristic is chosen. The algorithm was tested on synthetic data using MODTRAN and the Salisbury emissivity database.« less

2D Layered Materials of Rare-Earth Er-Doped MoS2 with NIR-to-NIR Down- and Up-Conversion Photoluminescence.

PubMed

Bai, Gongxun; Yuan, Shuoguo; Zhao, Yuda; Yang, Zhibin; Choi, Sin Yuk; Chai, Yang; Yu, Siu Fung; Lau, Shu Ping; Hao, Jianhua

2016-09-01

A 2D system of Er-doped MoS2 layered nanosheets is developed. Structural studies indicate that the Er atoms can be substitutionally introduced into MoS2 to form stable doping. Density functional theory calculation implies that the system remains stable. Both NIR-to-NIR up-conversion and down-conversion light-emissions are observed in 2D transition metal dichalcogenides, ascribed to the energy transition from Er(3+) dopants. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A double-stream Xe:He jet plasma emission in the vicinity of 6.7 nm

NASA Astrophysics Data System (ADS)

Chkhalo, N. I.; Garakhin, S. A.; Golubev, S. V.; Lopatin, A. Ya.; Nechay, A. N.; Pestov, A. E.; Salashchenko, N. N.; Toropov, M. N.; Tsybin, N. N.; Vodopyanov, A. V.; Yulin, S.

2018-05-01

We present the results of investigations of extreme ultraviolet (EUV) light emission in the range from 5 to 10 nm. The light source was a pulsed "double-stream" Xe:He gas jet target irradiated by a laser beam with a power density of ˜1011 W/cm2. The radiation spectra were measured with a Czerny-Turner monochromator with a plane diffraction grating. The conversion efficiency of the laser energy into EUV radiation caused by Xe+14…+16 ion emission in the range of 6-8 nm was measured using a calibrated power meter. The conversion efficiency of the laser radiation into EUV in the vicinity of 6.7 nm was (2.17 ± 0.13)% in a 1 nm spectral band. In the spectral band of the real optical system (0.7% for La/B multilayer mirrors) emitted into the half-space, it was (0.1 ± 0.006)%. The results of this study provide an impetus for further research on laser plasma sources for maskless EUV lithography at a wavelength of 6.7 nm.

Surface emissivity and temperature retrieval for a hyperspectral sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borel, C.C.

1998-12-01

With the growing use of hyper-spectral imagers, e.g., AVIRIS in the visible and short-wave infrared there is hope of using such instruments in the mid-wave and thermal IR (TIR) some day. The author believes that this will enable him to get around using the present temperature-emissivity separation algorithms using methods which take advantage of the many channels available in hyper-spectral imagers. A simple fact used in coming up with a novel algorithm is that a typical surface emissivity spectrum are rather smooth compared to spectral features introduced by the atmosphere. Thus, a iterative solution technique can be devised which retrievesmore » emissivity spectra based on spectral smoothness. To make the emissivities realistic, atmospheric parameters are varied using approximations, look-up tables derived from a radiative transfer code and spectral libraries. One such iterative algorithm solves the radiative transfer equation for the radiance at the sensor for the unknown emissivity and uses the blackbody temperature computed in an atmospheric window to get a guess for the unknown surface temperature. By varying the surface temperature over a small range a series of emissivity spectra are calculated. The one with the smoothest characteristic is chosen. The algorithm was tested on synthetic data using MODTRAN and the Salisbury emissivity database.« less

Control of Terahertz Emission by Ultrafast Spin-Charge Current Conversion at Rashba Interfaces

NASA Astrophysics Data System (ADS)

Jungfleisch, Matthias B.; Zhang, Qi; Zhang, Wei; Pearson, John E.; Schaller, Richard D.; Wen, Haidan; Hoffmann, Axel

2018-05-01

We show that a femtosecond spin-current pulse can generate terahertz (THz) transients at Rashba interfaces between two nonmagnetic materials. Our results unambiguously demonstrate the importance of the interface in this conversion process that we interpret in terms of the inverse Rashba Edelstein effect, in contrast to the THz emission in the bulk conversion process via the inverse spin-Hall effect. Furthermore, we show that at Rashba interfaces the THz-field amplitude can be controlled by the helicity of the light. The optical generation of electric photocurrents by these interfacial effects in the femtosecond regime will open up new opportunities in ultrafast spintronics.

Control of Terahertz Emission by Ultrafast Spin-Charge Current Conversion at Rashba Interfaces.

PubMed

Jungfleisch, Matthias B; Zhang, Qi; Zhang, Wei; Pearson, John E; Schaller, Richard D; Wen, Haidan; Hoffmann, Axel

2018-05-18

We show that a femtosecond spin-current pulse can generate terahertz (THz) transients at Rashba interfaces between two nonmagnetic materials. Our results unambiguously demonstrate the importance of the interface in this conversion process that we interpret in terms of the inverse Rashba Edelstein effect, in contrast to the THz emission in the bulk conversion process via the inverse spin-Hall effect. Furthermore, we show that at Rashba interfaces the THz-field amplitude can be controlled by the helicity of the light. The optical generation of electric photocurrents by these interfacial effects in the femtosecond regime will open up new opportunities in ultrafast spintronics.

Luminescence properties of Tm3+ ions single-doped YF3 materials in an unconventional excitation region.

PubMed

Chen, Yuan; Liu, Qing; Lin, Han; Yan, Xiaohong

2018-05-01

According to the spectral distribution of solar radiation at the earth's surface, under the excitation region of 1150 to 1350 nm, the up-conversion luminescence of Tm 3+ ions was investigated. The emission bands were matched well with the spectral response region of silicon solar cells, achieved by Tm 3+ ions single-doped yttrium fluoride (YF 3 ) phosphor, which was different from the conventional Tm 3+ /Yb 3+ ion couple co-doped materials. Additionally, the similar emission bands of Tm 3+ ions were achieved under excitation in the ultraviolet region. It is expected that via up-conversion and down-conversion routes, Tm 3+ -sensitized materials could convert photons to the desired wavelengths in order to reduce the energy loss of silicon solar cells, thereby enhancing the photovoltaic efficiency. Copyright © 2018 John Wiley & Sons, Ltd.

Spectrophotometric Study of the Region of the Sky Around the Galaxies Markarian 261 and 262

NASA Astrophysics Data System (ADS)

Khachikian, E. Ye.; Sargsyan, L. A.

2005-10-01

Results are presented from a detailed spectrophotometric study of a unique system of physically coupled galaxies whose spectra contain identical emission lines. This system consists of four galaxies, three of which have a double or multiple structure in their central portions and are, by definition, galaxies with two or multiple nuclei. Two of these objects are the galaxies with an ultraviolet excess (UVE), Mark 261 and Mark 262, while one is a galaxy made up of two identical starlike nuclei that are referred to as the “twin objects.” In the DSS2 charts, the latter show up as two adjacent stars without any surroundings. However, there are two condensations between these starlike nuclei. The fourth object has a triplet structure. It is shown here that all these objects have the same emission (line) spectra and red shifts. All the physical characteristics that can be determined from the spectra are determined: red shifts, relative intensities of emission lines, their equivalent widths, distances to the galaxies, etc. It is concluded that the members of this system have a common origin, more or less consistent with Ambartsumyan's idea of the fragmentation of an isolated, high density body.

Flare activity and photospheric analysis of Proxima Centauri

NASA Astrophysics Data System (ADS)

Pavlenko, Y.; Suárez Mascareño, A.; Rebolo, R.; Lodieu, N.; Béjar, V. J. S.; González Hernández, J. I.

2017-10-01

Context. We present the analysis of emission lines in high-resolution optical spectra of the planet-host star Proxima Centauri (Proxima) classified as a M5.5V. Aims: We carry out a detailed analysis of the observed spectra to get a better understanding of the physical conditions of the atmosphere of this star. Methods: We identify the emission lines in a series of 147 high-resolution optical spectra of the star at different levels of activity and compare them with the synthetic spectra computed over a wide spectral range. Results: Our synthetic spectra computed with the PHOENIX 2900/5.0/0.0 model atmosphere fits the observed spectral energy distribution from optical to near-infrared quite well. However, modelling strong atomic lines in the blue spectrum (3900-4200 Å) requires implementing additional opacity. We show that high-temperature layers in Proxima Centauri consist of at least three emitting parts: a) a stellar chromosphere where numerous emission lines form; we suggest that some emission cores of strong absorption lines of metals form there; b) flare regions above the chromosphere, where hydrogen Balmer lines up to high transition levels (10-2) form; and c) a stellar wind component with Vr = -30 km s-1 seen in some Balmer lines as blueshifted emission lines. We believe that the observed He line at 4026 Å in emission can be formed in that very hot region. Conclusions: We show that the real structure of the atmosphere of Proxima is rather complicated. The photosphere of the star is best fit by a normal M5 dwarf spectrum. On the other hand, emission lines form in the chromosphere, flare regions, and extended hot envelope. The movies are available at http://www.aanda.org

Characterization and cysteine sensing performance of nanocomposites based on up-conversion excitation host and rhodamine-derived probes

NASA Astrophysics Data System (ADS)

Yuqing, Zhao; Yi, Xing; Lihua, Li; Juanjuan, Ma

2018-02-01

Optical sensing for cysteine (Cys) recognition is an interesting topic due to Cys biological participation. In this paper, two rhodamine-based chemosensors were designed for Cys optical sensing. For chemosensor photostability improvement, up-conversion nanocrystals were synthesized and used as excitation host. These nanocrystals were modified with a phase transfer reagent α-cyclodextrin (α-CD) to improve their compatibility with chemosensors. An efficient energy transfer from these nanocrystals to chemosensors under 980 nm radiation was observed and confirmed by spectral match analysis, energy transfer radius calculation and emission decay lifetime comparison. A direct bonding mechanism between Cys and chemosensors with bonding stoichiometry of 1:1 was established by Job's plot experiment. Given the presence of Cys, chemosensor emission was increased, showing emission turn on effect. These two chemosensors showed good selectivity, improved photostability and linear sensing response towards Cys.

Up-conversion of MMW radiation to visual band using glow discharge detector and silicon detector

NASA Astrophysics Data System (ADS)

Aharon Akram, Avihai; Rozban, Daniel; Abramovich, Amir; Yitzhaky, Yitzhak; Kopeika, Natan S.

2016-10-01

In this work we describe and demonstrate a method for up-conversion of millimeter wave (MMW) radiation to the visual band using a very inexpensive miniature Glow Discharge Detector (GDD), and a silicon detector (photodetector). Here we present 100 GHz up-conversion images based on measuring the visual light emitting from the GDD rather than its electrical current. The results showed better response time of 480 ns and better sensitivity compared to the electronic detection that was performed in our previous work. In this work we performed MMW imaging based on this method using a GDD lamp, and a photodetector to measure GDD light emission.

Control of Terahertz Emission by Ultrafast Spin-Charge Current Conversion at Rashba Interfaces

DOE PAGES

Jungfleisch, Matthias B.; Zhang, Qi; Zhang, Wei; ...

2018-05-18

Here, we show that a femtosecond spin-current pulse can generate terahertz (THz) transients at Rashba interfaces between two nonmagnetic materials. Our results unambiguously demonstrate the importance of the interface in this conversion process that we interpret in terms of the inverse Rashba Edelstein effect, in contrast to the THz emission in the bulk conversion process via the inverse spin-Hall effect. Furthermore, we show that at Rashba interfaces the THz-field amplitude can be controlled by the helicity of the light. The optical generation of electric photocurrents by these interfacial effects in the femtosecond regime will open up new opportunities in ultrafastmore » spintronics.« less

Control of Terahertz Emission by Ultrafast Spin-Charge Current Conversion at Rashba Interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jungfleisch, Matthias B.; Zhang, Qi; Zhang, Wei

Here, we show that a femtosecond spin-current pulse can generate terahertz (THz) transients at Rashba interfaces between two nonmagnetic materials. Our results unambiguously demonstrate the importance of the interface in this conversion process that we interpret in terms of the inverse Rashba Edelstein effect, in contrast to the THz emission in the bulk conversion process via the inverse spin-Hall effect. Furthermore, we show that at Rashba interfaces the THz-field amplitude can be controlled by the helicity of the light. The optical generation of electric photocurrents by these interfacial effects in the femtosecond regime will open up new opportunities in ultrafastmore » spintronics.« less

Simultaneous NuSTAR/Chandra Observations of the Bursting Pulsar GRO J1744-28 During its Third Reactivation

NASA Technical Reports Server (NTRS)

Younes, G.; Kouveliotou, C.; Grefenstette, B. W.; Tomsick, J. A.; Tennant, A.; Finger, M. H.; Furst, F.; Pottschmidt, K.; Bhalerao, V.; Boggs, S. E.;

Highly efficient up-conversion and bright white light in RE co-doped KYF4 nanocrystals in sol-gel silica matrix

NASA Astrophysics Data System (ADS)

Méndez-Ramos, J.; Yanes, A. C.; Santana-Alonso, A.; del-Castillo, J.

2013-01-01

Transparent nano-glass-ceramics comprising Yb3+, Er3+ and Tm3+ co-doped KYF4 nanocrystals have been developed from sol-gel method. A structural analysis by means of X-ray diffraction confirmed the precipitation of cubic KYF4 nanocrystals into a silica matrix. Visible luminescence has been analyzed as function of treatment temperature of precursor sol-gel glasses. Highly efficient up-conversion emissions have been obtained under 980 nm excitation and studied by varying the doping level, processing temperature and pump power. Color tuneability has been quantified in terms of CIE diagram and in particular, a white-balanced overall emission has been achieved for a certain doping level and thermal treatment.

Effects of X-ray irradiation on the Eu3+ → Eu2+ conversion in CaAl2O4 phosphors

NASA Astrophysics Data System (ADS)

Gomes, Manassés A.; Carvalho, Jéssica C.; Andrade, Adriano B.; Rezende, Marcos V.; Macedo, Zélia S.; Valerio, Mário E. G.

2018-01-01

This paper reports structural and luminescence properties of Eu-doped CaAl2O4 produced by an alternative sol-gel method using coconut water. Results of differential thermal analysis (DTA), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) allowed us to identify the best synthesis conditions for sample preparation. Simultaneous measurements of X-ray absorption spectroscopy (XAS) and X-ray excited optical luminescence (XEOL) were also performed in the X-ray energy range of the Eu LIII edge. Results from photoluminescence (PL) showed only the characteristic Eu3+ emission. However, radioluminescence emission spectra from Eu-doped CaAl2O4 shows a process of conversion of Eu3+ to Eu2+, which is induced by X-ray irradiation and is dependent on the radiation dose energy. X-ray absorption near edge structure (XANES) measurements corroborate Eu reduction due to irradiation, showing that only the Eu3+ ion is present in stable form in the CaAl2O4.

Novel THz radiation from relativistic laser-plasmas

NASA Astrophysics Data System (ADS)

Sheng, Z. M.; Wu, H. C.; Wang, W. M.; Dong, X. G.; Chen, M.; Zhang, J.

2009-05-01

The interaction of ultrashort intense laser pulses with plasma can produce electromagnetic radiation of ultra-broad spectra ranging from terahertz (THz) radiation to keV x-rays and beyond. Here we present a review of our recent theoretical and numerical investigation on high power THz generation from tenuous plasma or gas targets irradiated by ultrashort intense laser pulses. Three mechanisms of THz emission are addressed, which include the linear mode conversion from laser wakefields in inhomogeneous plasma, transient current emission at the plasma-vacuum boundaries, and the emission from residual transverse currents produced by temporally-asymmetric laser pulses passing through gas or plasma targets. Since there is no breakdown limit for plasma under the irradiation of high power lasers, in principle, all these mechanisms can lead to terahertz pulse emission at the power of beyond megawatt with the field strength of MV/cm, suitable for the study of high THz field physics and other applications.

Franck-Condon Simulations including Anharmonicity of the Ã(1)A''-X̃(1)A' Absorption and Single Vibronic Level Emission Spectra of HSiCl and DSiCl.

PubMed

Mok, Daniel W K; Lee, Edmond P F; Chau, Foo-Tim; Dyke, John M

2009-03-10

RCCSD(T) and/or CASSCF/MRCI calculations have been carried out on the X̃(1)A' and Ã(1)A'' states of HSiCl employing basis sets of up to the aug-cc-pV5Z quality. Contributions from core correlation and extrapolation to the complete basis set limit were included in determining the computed equilibrium geometrical parameters and relative electronic energy of these two states of HSiCl. Franck-Condon factors which include allowance for anharmonicity and Duschinsky rotation between these two states of HSiCl and DSiCl were calculated employing RCCSD(T) and CASSCF/MRCI potential energy functions, and were used to simulate the Ã(1)A'' ← X̃(1)A' absorption and Ã(1)A'' → X̃(1)A' single vibronic level (SVL) emission spectra of HSiCl and DSiCl. Simulated absorption and experimental LIF spectra, and simulated and observed Ã(1)A''(0,0,0) → X̃(1)A' SVL emission spectra, of HSiCl and DSiCl are in very good agreement. However, agreement between simulated and observed Ã(1)A''(0,1,0) → X̃(1)A' and Ã(1)A''(0,2,1) → X̃(1)A' SVL emission spectra of DSiCl is not as good. Preliminary calculations on low-lying excited states of HSiCl suggest that vibronic interaction between low-lying vibrational levels of the Ã(1)A'' state and highly excited vibrational levels of the ã(3)A'' is possible. Such vibronic interaction may change the character of the low-lying vibrational levels of the Ã(1)A'' state, which would lead to perturbation in the SVL emission spectra from these vibrational levels.

Formation of definite GaN p-n junction by Mg-ion implantation to n--GaN epitaxial layers grown on a high-quality free-standing GaN substrate

NASA Astrophysics Data System (ADS)

Oikawa, Takuya; Saijo, Yusuke; Kato, Shigeki; Mishima, Tomoyoshi; Nakamura, Tohru

2015-12-01

P-type conversion of n--GaN by Mg-ion implantation was successfully performed using high quality GaN epitaxial layers grown on free-standing low-dislocation-density GaN substrates. These samples showed low-temperature PL spectra quite similar to those observed from Mg-doped MOVPE-grown p-type GaN, consisting of Mg related donor-acceptor pair (DAP) and acceptor bound exciton (ABE) emission. P-n diodes fabricated by the Mg-ion implantation showed clear rectifying I-V characteristics and UV and blue light emissions were observed at forward biased conditions for the first time.

Discovery of pulsed OH maser emission stimulated by a pulsar.

PubMed

Weisberg, Joel M; Johnston, Simon; Koribalski, Bärbel; Stanimirovic, Snezana

2005-07-01

Stimulated emission of radiation has not been directly observed in astrophysical situations up to this time. Here we demonstrate that photons from pulsar B1641-45 stimulate pulses of excess 1720-megahertz line emission in an interstellar hydroxyl (OH) cloud. As this stimulated emission is driven by the pulsar, it varies on a few-millisecond time scale, which is orders of magnitude shorter than the quickest OH maser variations previously detected. Our 1612-megahertz spectra are inverted copies of the 1720-megahertz spectra. This "conjugate line" phenomenon enables us to constrain the properties of the interstellar OH line-producing gas. We also show that pulsar signals undergo significantly deeper OH absorption than do other background sources, which confirms earlier tentative findings that OH clouds are clumpier on small scales than are neutral hydrogen clouds.

Electrical, thermal, catalytic and magnetic properties of nano-structured materials and their applications

NASA Astrophysics Data System (ADS)

Liu, Zuwei

Nanotechnology is a subject that studies the fabrication, properties, and applications of materials on the nanometer-scale. Top-down and bottom-up approaches are commonly used in nano-structure fabrication. The top-down approach is used to fabricate nano-structures from bulk materials by lithography, etching, and polishing etc. It is commonly used in mechanical, electronic, and photonic devices. Bottom-up approaches fabricate nano-structures from atoms or molecules by chemical synthesis, self-assembly, and deposition, such as sol-gel processing, molecular beam epitaxy (MBE), focused ion beam (FIB) milling/deposition, chemical vapor deposition (CVD), and electro-deposition etc. Nano-structures can have several different dimensionalities, including zero-dimensional nano-structures, such as fullerenes, nano-particles, quantum dots, nano-sized clusters; one-dimensional nano-structures, such as carbon nanotubes, metallic and semiconducting nanowires; two-dimensional nano-structures, such as graphene, super lattice, thin films; and three-dimensional nano-structures, such as photonic structures, anodic aluminum oxide, and molecular sieves. These nano-structured materials exhibit unique electrical, thermal, optical, mechanical, chemical, and magnetic properties in the quantum mechanical regime. Various techniques can be used to study these properties, such as scanning probe microscopy (SPM), scanning/transmission electron microscopy (SEM/TEM), micro Raman spectroscopy, etc. These unique properties have important applications in modern technologies, such as random access memories, display, solar energy conversion, chemical sensing, and bio-medical devices. This thesis includes four main topics in the broad area of nanoscience: magnetic properties of ferro-magnetic cobalt nanowires, plasmonic properties of metallic nano-particles, photocatalytic properties of titanium dioxide nanotubes, and electro-thermal-optical properties of carbon nanotubes. These materials and their properties are briefly reviewed in Chapter One, including the concepts of ferro-magnetism, plasmonics, photocatalysis, thermal emission, and Raman spectra of carbon nanotubes. In Chapter Two, we focus on the magnetic properties of ferro-magnetic cobalt nanowires with high crystalline quality synthesized via a low voltage electro-deposition method. The crystal structure of these Co nanowires is characterized by high resolution transmission electron microscopy and X-ray diffraction. The magnetic properties of individual nanowires and nanowire arrays are investigated by magnetic force microscope (MFM) and superconducting quantum interference device (SQUID) measurements. A theoretical model is developed to explain these experimental observations. In Chapter Three, we exploit the strong plasmon resonance of gold nanoparticles. We also demonstrate a new method for patterning SERS (surface enhanced Raman spectroscopy) aggregates of gold nanoparticles by using a focused laser beam to optically trap the nanoparticles in a water suspension. Raman spectroscopy is used to estimate the temperature in the laser spot during the in-situ aggregation, by measuring the Raman peak of the hydroxyl bond of water. In Chapter Four, we demonstrate plasmonic enhancement of photocatalytic water splitting under visible illumination by integrating strongly plasmonic Au nanoparticles with strongly catalytic TiO2. Electromagnetic simulations indicate that the near-field optical enhancement increases the electron-hole pair generation rate at the surface of the TiO2, thus increasing the amount of photo-generated charge contributing to catalysis. Our results suggest that enhancement factors many times larger than this are possible if this mechanism can be optimized. In Chapter Five, we study the Raman spectra and thermal emission spectra of individual suspended carbon nanotubes induced by electrical heating. Semiconducting and metallic devices exhibit different spectra, based on their distinctive band structures. Raman spectra and the blackbody emission background are used to fit the device temperature. In addition to the blackbody emission background, polarized peaks along the nanotube direction are observed in different ranges of the thermal emission spectra for metallic and semiconducting devices. These peaks are attributed to the transitions between Van Hove singularities that are thermally driven under these high applied bias voltages. A theoretical model is developed to calculate the thermal emission spectra based on this conclusion. In Chapter Six, we present some data of single crystal zinc oxide (ZnO) nanowires synthesized by the CVD method, including magneto-resistance measurements, optical-resistance measurements, and scanning-gate measurements. In Chapter Seven, we discuss some future work related to photocatalysis and carbon nanotubes.

The Equilibrium and Pre-equilibrium Triton Emission Spectra of Some Target Nuclei for ( n, xt) Reactions up to 45 MeV Energy

NASA Astrophysics Data System (ADS)

Tel, E.; Kaplan, A.; Aydın, A.; Özkorucuklu, S.; Büyükuslu, H.; Yıldırım, G.

2010-08-01

Although there have been significant research and development studies on the inertial and magnetic fusion reactor technology, there is still a long way to go to penetrate commercial fusion reactors to the energy market. Tritium self-sufficiency must be maintained for a commercial power plant. For self-sustaining (D-T) fusion driver tritium breeding ratio should be greater than 1.05. So, working out the systematics of ( n,t) reaction cross sections and triton emission differential data are important for the given reaction taking place on various nuclei at different energies. In this study, ( n,xt) reactions for some target nuclei as 16O, 27Al, 59Co and 209Bi have been investigated up to 45 MeV incident neutron energy. In the calculations of the triton emission spectra, the pre-equilibrium and equilibrium effects have been used. The calculated results have been compared with the experimental data taken from the literature.

Photoluminescence properties of Mn2+/Yb3+ co-doped oxyfluoride glasses for solar cells application

NASA Astrophysics Data System (ADS)

Yan, Ying; Chen, Zeng; Jia, Xiyang; Li, Shengjun

2018-01-01

Mn2+/Yb3+ co-doped oxyfluoride glasses were facilely synthesized in the SiO2-Al2O3-Na2O-CaF2 system. Partial crystallization processed during the preparation of the glasses, by which small amounts of CaF2 nano-crystals were formed. Under ultraviolet and blue (370-500 nm) light excitation, an efficient down-conversion involving the emission of near-infrared is realized in the Mn2+/Yb3+ co-doped oxyfluoride glasses. The near-infrared emission peaks mainly at 976 nm and secondarily at 1020 nm, which is a comfortable match with the band gap of c-Si. The variation in visible and near-infrared spectra and the decay curves of Mn2+:4T1 → 6A1 emission have been investigated to verify the possible energy transfer from Mn2+ ions to Yb3+ ions. On analyzing the energy transfer processes theoretically and experimentally, we propose that quantum cutting and down-shifting processes may occur simultaneously in the samples. We suggest that the Mn2+-Yb3+ co-doped materials can provide a novel direction to realize UV-Vis to NIR down-conversion for Si solar cells.

An ultrafast spectroscopic and quantum mechanical investigation of multiple emissions in push-pull pyridinium derivatives bearing different electron donors.

PubMed

Carlotti, B; Benassi, E; Cesaretti, A; Fortuna, C G; Spalletti, A; Barone, V; Elisei, F

2015-08-28

A joint experimental and theoretical approach, involving state-of-the-art femtosecond fluorescence up-conversion measurements and quantum mechanical computations including vibronic effects, was employed to get a deep insight into the excited state dynamics of two cationic dipolar chromophores (Donor-π-Acceptor(+)) where the electron deficient portion is a N-methyl pyridinium and the electron donor a trimethoxyphenyl or a pyrene, respectively. The ultrafast spectroscopic investigation, and the time resolved area normalised emission spectra in particular, revealed a peculiar multiple emissive behaviour and allowed the distinct emitting states to be remarkably distinguished from solvation dynamics, occurring in water in a similar timescale. The two and three emissions experimentally detected for the trimethoxyphenyl and pyrene derivatives, respectively, were associated with specific local emissive minima in the potential energy surface of S1 on the ground of quantum-mechanical calculations. A low polar and planar Locally Excited (LE) state together with a highly polar and Twisted Intramolecular Charge Transfer (TICT) state is identified to be responsible for the dual emission of the trimethoxyphenyl compound. Interestingly, the more complex photobehaviour of the pyrenyl derivative was explained considering the contribution to the fluorescence coming not only from the LE and TICT states but also from a nearly Planar Intramolecular Charge Transfer (PICT) state, with both the TICT and the PICT generated from LE by progressive torsion around the quasi-single bond between the methylpyridinium and the ethene bridge. These findings point to an interconversion between rotamers for the pyrene compound taking place in its excited state against the Non-equilibrated Excited Rotamers (NEER) principle.

Exceeding the solar cell Shockley-Queisser limit via thermal up-conversion of low-energy photons

NASA Astrophysics Data System (ADS)

Boriskina, Svetlana V.; Chen, Gang

2014-03-01

Maximum efficiency of ideal single-junction photovoltaic (PV) cells is limited to 33% (for 1 sun illumination) by intrinsic losses such as band edge thermalization, radiative recombination, and inability to absorb below-bandgap photons. This intrinsic thermodynamic limit, named after Shockley and Queisser (S-Q), can be exceeded by utilizing low-energy photons either via their electronic up-conversion or via the thermophotovoltaic (TPV) conversion process. However, electronic up-conversion systems have extremely low efficiencies, and practical temperature considerations limit the operation of TPV converters to the narrow-gap PV cells. Here we develop a conceptual design of a hybrid TPV platform, which exploits thermal up-conversion of low-energy photons and is compatible with conventional silicon PV cells by using spectral and directional selectivity of the up-converter. The hybrid platform offers sunlight-to-electricity conversion efficiency exceeding that imposed by the S-Q limit on the corresponding PV cells across a broad range of bandgap energies, under low optical concentration (1-300 suns), operating temperatures in the range 900-1700 K, and in simple flat panel designs. We demonstrate maximum conversion efficiency of 73% under illumination by non-concentrated sunlight. A detailed analysis of non-ideal hybrid platforms that allows for up to 15% of absorption/re-emission losses yields limiting efficiency value of 45% for Si PV cells.

High efficient photocatalytic selective oxidation of benzyl alcohol to benzaldehyde by solvothermal-synthesized ZnIn2S4 microspheres under visible light irradiation

NASA Astrophysics Data System (ADS)

Chen, Zhixin; Xu, Jingjing; Ren, Zhuyun; He, Yunhui; Xiao, Guangcan

2013-09-01

Hexagonal ZnIn2S4 samples have been synthesized by a solvothermal method. Their properties have been determined by X-ray diffraction, ultraviolet-visible-light diffuse reflectance spectra, field emission scanning electron microscopy, nitrogen adsorption-desorption and X-ray photoelectron spectra. These results demonstrate that ethanol solvent has significant influence on the morphology, optical and electronic nature for such marigold-like ZnIn2S4 microspheres. The visible light photocatalytic activities of the ZnIn2S4 have been evaluated by selective oxidation of benzyl alcohol to benzaldehyde using molecular oxygen as oxidant. The results show that 100% conversion along with >99% selectivity are reached over ZnIn2S4 prepared in ethanol solvent under visible light irradiation (λ>420 nm) of 2 h, but only 58% conversion and 57% yield are reached over ZnIn2S4 prepared in aqueous solvent. A possible mechanism of the high photocatalytic activity for selective oxidation of benzyl alcohol over ZnIn2S4 is proposed and discussed.

Measurement of CIB power spectra over large sky areas from Planck HFI maps

NASA Astrophysics Data System (ADS)

Mak, Daisy Suet Ying; Challinor, Anthony; Efstathiou, George; Lagache, Guilaine

2017-04-01

We present new measurements of the power spectra of the cosmic infrared background (CIB) anisotropies using the Planck 2015 full-mission High frequency instrument data at 353, 545 and 857 GHz over 20 000 deg2. We use techniques similar to those applied for the cosmological analysis of Planck, subtracting dust emission at the power spectrum level. Our analysis gives stable solutions for the CIB power spectra with increasing sky coverage up to about 50 per cent of the sky. These spectra agree well with H I-cleaned spectra from Planck measured on much smaller areas of sky with low Galactic dust emission. At 545 and 857 GHz, our CIB spectra agree well with those measured from Herschel data. We find that the CIB spectra at ℓ ≳ 500 are well fitted by a power-law model for the clustered CIB, with a shallow index γcib = 0.53 ± 0.02. This is consistent with the CIB results at 217 GHz from the cosmological parameter analysis of Planck. We show that a linear combination of the 545 and 857 GHz Planck maps is dominated by the CIB fluctuations at multipoles ℓ ≳ 300.

Water soluble (Ln3+) doped nanoparticle: Retention of strong luminescence

NASA Astrophysics Data System (ADS)

Attar, Tarannum Vahid; Khandpekar, Mahendra M.

2018-04-01

This paper deals with the synthesis of hexagonal nanoparticles of LaF3: Nd, Ho (LFNH) in the presence of LaCl3.7H2O and NH4F by precipitation method using deionized water as solvent. The nanoparticles have a nearly hexagonal shape with cell parameters, a = b = 7.0980 AU and c = 7.2300 AU and confirms with the JCPDS standard card (32-0483) of pure LaF3 crystals. The TEM results show that the average sizes of these nanoparticles are 15nm which is consistent with the sizes obtained from XRD measurements. The SEM image shows uniform size distribution of the nanoparticles. Detection of Second harmonic generation (SHG) signal together with the presence of wide transparency window (UV studies) makes LFNH suitable for optoelectronic applications. The Photoluminescence of the nanocrystals has been observed by excitation and emission spectra. The peak at 629nm indicates red up conversion fluorescence useful in applications like bioimaging and biolabelling.

Structural, optical and photovoltaic properties of co-doped CdTe QDs for quantum dots sensitized solar cells

NASA Astrophysics Data System (ADS)

Ayyaswamy, Arivarasan; Ganapathy, Sasikala; Alsalme, Ali; Alghamdi, Abdulaziz; Ramasamy, Jayavel

2015-12-01

Zinc and sulfur alloyed CdTe quantum dots (QDs) sensitized TiO2 photoelectrodes have been fabricated for quantum dots sensitized solar cells. Alloyed CdTe QDs were prepared in aqueous phase using mercaptosuccinic acid (MSA) as a capping agent. The influence of co-doping on the structural property of CdTe QDs was studied by XRD analysis. The enhanced optical absorption of alloyed CdTe QDs was studied using UV-vis absorption and fluorescence emission spectra. The capping of MSA molecules over CdTe QDs was confirmed by the FTIR and XPS analyses. Thermogravimetric analysis confirms that the prepared QDs were thermally stable up to 600 °C. The photovoltaic performance of alloyed CdTe QDs sensitized TiO2 photoelectrodes were studied using J-V characteristics under the illumination of light with 1 Sun intensity. These results show the highest photo conversion efficiency of η = 1.21%-5% Zn & S alloyed CdTe QDs.

Carbon stars with alpha-C:H emission

NASA Technical Reports Server (NTRS)

Gerbault, Florence; Goebel, John H.

1989-01-01

Many carbon stars in the IRS low resolution spectra (LRS) catalog were found which display emission spectra that compare favorable with the absorption spectrum of alpha-C:H. These stars have largely been classified as 4X in the LRS which has led to their interpretation by others in terms of displaying a mixture of the UIRF's 8.6 micron band and SiC at 11.5 microns. It was also found that many of these stars have a spectral upturn at 20+ microns which resembles the MgS band seen in carbon stars and planetary nebulae. It was concluded that this group of carbon stars will evolve into planetary nebulae like NGC 7027 and IC 418. In the presence of hard ultraviolet radiation the UIRF's will light up and be displayed as narrow emission bands on top of the broad alpha-C:H emission bands.

Rare-earth doped transparent nano-glass-ceramics: a new generation of photonic integrated devices

NASA Astrophysics Data System (ADS)

Rodríguez-Armas, Vicente Daniel; Tikhomirov, Victor K.; Méndez-Ramos, Jorge; Yanes, Angel C.; Del-Castillo, Javier; Furniss, David; Seddon, Angela B.

2007-05-01

We report on optical properties and prospect applications on rare-earth doped oxyfluoride precursor glass and ensuing nano-glass-ceramics. We find out the spectral optical gain of the nano-glass-ceramics and show that its flatness and breadth are advantageous as compared to contemporary used erbium doped optical amplifiers. We present the possibility of flat gain cross-section erbium doped waveguide amplifiers as short 'chip', all-optical, devices capable of dense wavelength division multiplexing, including the potential for direct writing of these devices inside bulk glasses for three-dimensional photonic integration. We carried out a comparative study of the up-conversion luminescence in Er 3+-doped and Yb 3+-Er 3+-Tm 3+ co-doped samples, which indicates that these materials can be used as green/red tuneable up-conversion phosphors and white light simulation respectively. Observed changes in the spectra of the up-conversion luminescence provide a tool for tuning the colour opening the way for producing 3-dimensional optical recording.

Spectroscopic studies of Nd3+ doped lead tungsten tellurite glasses for the NIR emission at 1062 nm

NASA Astrophysics Data System (ADS)

Venkateswarlu, M.; Mahamuda, Sk.; Swapna, K.; Prasad, M. V. V. K. S.; Srinivasa Rao, A.; Mohan Babu, A.; Shakya, Suman; Vijaya Prakash, G.

2015-01-01

Lead Tungsten Tellurite (LTT) glasses doped with different concentrations of Nd3+ ions were prepared by using the melt quenching technique to study the absorption, emission and decay spectral profiles with an aim to understand the lasing potentialities of these glasses. From the absorption spectra, the Judd-Ofelt (J-O) parameters are evaluated and in turn used to calculate the transition probability (AR), total transition probability (AT), radiative lifetime (τR) and branching ratios (βR) for prominent emission levels of Nd3+. The emission spectra recorded for LTT glasses gives three emission transitions 4F3/2 → 4I9/2, 4F3/2 → 4I11/2 and 4F3/2 → 4I13/2 for which effective band widths (ΔλP) and stimulated emission cross-sections (σse) are evaluated. Branching ratios (βR) measured for all the LTT glasses show that 4F3/2 → 4I11/2 transition is quite suitable for lasing applications. The intensity of emission spectra increases with increase in the concentrations of Nd3+ up to 1.0 mol% and beyond concentration quenching is observed. Relatively higher emission cross-sections and branching ratios observed for the present LTT glasses over the reported glasses suggests the feasibility of using LTT glasses for infrared laser applications. From the absorption, emission and decay spectral measurements, it was found that 1.0 mol% of Nd3+ ion concentration is aptly suitable for LTT glasses to give a strong NIR laser emission at 1062 nm.

On the effect of emergence angle on emissivity spectra: application to small bodies

NASA Astrophysics Data System (ADS)

Maturilli, Alessandro; Helbert, Jörn; Ferrari, Sabrina; D'Amore, Mario

2016-05-01

Dependence of laboratory-measured emissivity spectra from the emergence angle is a subject that still needs a lot of investigations to be fully understood. Most of the previous work is based on reflectance measurements in the VIS-NIR spectral region and on emissivity measurements of flat, solid surfaces (mainly metals), which are not directly applicable to the analysis of remote sensing data. Small bodies in particular (c.f. asteroids Itokawa and 1999JU3, the respective targets of JAXA Hayabusa and Hayabusa 2 missions) have a very irregular surface; hence, the spectra from those rough surfaces are difficult to compare with laboratory spectra, where the observing geometry is always close to "nadir." At the Planetary Emissivity Laboratory of the German Aerospace Center (DLR), we have set up a series of spectral measurements to investigate this problem in the 1- to 16-µm spectral region. We measured the emissivity for two asteroid analogue materials (meteorite Millbillillie and a synthetic enstatite) in vacuum and under purged air, at surface temperature of 100 °C, for emergence angles of 0°, 5°, 10°, 20°, 30°, 40°, 50°, and 60°. Emissivity of a serpentinite slab, already used as calibration target for the MARA instrument on Hayabusa 2 MASCOT lander and for the thermal infrared imager spectrometer on Hayabusa 2 orbiter, was measured under the same conditions. Additionally, a second basalt slab was measured. Both slabs were not measured at 5° inclination. Complementary reflectance measurements of the four samples were taken. For all the samples measured, we found that for calibrated emissivity, significant variations from values obtained at nadir (0° emergence angle) appear only for emergence angles ≥40°. Reflectance measurements confirmed this finding, showing the same trend of variations.

The accuracy of seminumerical reionization models in comparison with radiative transfer simulations

NASA Astrophysics Data System (ADS)

Hutter, Anne

2018-06-01

We have developed a modular seminumerical code that computes the time and spatially dependent ionization of neutral hydrogen (H I), neutral (He I), and single-ionized helium (He II) in the intergalactic medium (IGM). The model accounts for recombinations and provides different descriptions for the photoionization rate that are used to calculate the residual H I fraction in ionized regions. We compare different seminumerical reionization schemes to a radiative transfer (RT) simulation. We use the RT simulation as a benchmark, and find that the seminumerical approaches produce similar H II and He II morphologies and power spectra of the H I 21 cm signal throughout reionization. As we do not track partial ionization of He II, the extent of the double-ionized helium (He III) regions is consistently smaller. In contrast to previous comparison projects, the ionizing emissivity in our seminumerical scheme is not adjusted to reproduce the redshift evolution of the RT simulation, but directly derived from the RT simulation spectra. Among schemes that identify the ionized regions by the ratio of the number of ionization and absorption events on different spatial smoothing scales, we find those that mark the entire sphere as ionized when the ionization criterion is fulfilled to result in significantly accelerated reionization compared to the RT simulation. Conversely, those that flag only the central cell as ionized yield very similar but slightly delayed redshift evolution of reionization, with up to 20 per cent ionizing photons lost. Despite the overall agreement with the RT simulation, our results suggest that constraining ionizing emissivity-sensitive parameters from seminumerical galaxy formation-reionization models are subject to photon nonconservation.

The accuracy of semi-numerical reionization models in comparison with radiative transfer simulations

NASA Astrophysics Data System (ADS)

Hutter, Anne

2018-03-01

We have developed a modular semi-numerical code that computes the time and spatially dependent ionization of neutral hydrogen (H I), neutral (He I) and singly ionized helium (He II) in the intergalactic medium (IGM). The model accounts for recombinations and provides different descriptions for the photoionization rate that are used to calculate the residual H I fraction in ionized regions. We compare different semi-numerical reionization schemes to a radiative transfer (RT) simulation. We use the RT simulation as a benchmark, and find that the semi-numerical approaches produce similar H II and He II morphologies and power spectra of the H I 21cm signal throughout reionization. As we do not track partial ionization of He II, the extent of the double ionized helium (He III) regions is consistently smaller. In contrast to previous comparison projects, the ionizing emissivity in our semi-numerical scheme is not adjusted to reproduce the redshift evolution of the RT simulation, but directly derived from the RT simulation spectra. Among schemes that identify the ionized regions by the ratio of the number of ionization and absorption events on different spatial smoothing scales, we find those that mark the entire sphere as ionized when the ionization criterion is fulfilled to result in significantly accelerated reionization compared to the RT simulation. Conversely, those that flag only the central cell as ionized yield very similar but slightly delayed redshift evolution of reionization, with up to 20% ionizing photons lost. Despite the overall agreement with the RT simulation, our results suggests that constraining ionizing emissivity sensitive parameters from semi-numerical galaxy formation-reionization models are subject to photon nonconservation.

Investigating Supermassive Black Hole Spin at Different Redshift

NASA Astrophysics Data System (ADS)

Sinanan-Singh, Jasmine

2018-01-01

Supermassive black hole (SMBH) spin encodes vital information about the history of SMBH growth. High spins indicate a history of growth through large mass accretion events, which spin-up the black hole; Intermediate spins indicate a history of galactic mergers, which don't tend to systemcatically spin-up or spin-down black holes; low spins are attributed to successive, small accretion events with random orientations. Examining spin over different redshifts will help us understand the relative growth of SMBHs by mergers or accretion over cosmic time, an important part of understanding how SMBHs and their host galaxies co-evolved over time. To study spin, we compute the Fe K alpha emission line from the X-ray spectra of AGN sources in the Chandra-COSMOS Legacy Survey. We stack rest frame AGN spectra to improve the signal-to-noise ratio since the photon counts are low for individual spectra, and then average the spectra using an unwieghted mean. Our method is derived from Corral et al. (2008). We test our method on the two brightest sources in the COSMOS Survey and compute the rest frame average Fe K alpha emission line for different redshift bins. The SAO REU program is funded by the National Science Foundation REU and Department of Defense ASSURE programs under NSF Grant AST-1659473, and by the Smithsonian Institution.

Energy conversion of X-ray, ultraviolet and infrared radiation in Gd2O3 crystals doped with Er3+ ions

NASA Astrophysics Data System (ADS)

Trofimova, E. S.; Pustovarov, V. A.; Kuznetsova, Yu. A.; Zatsepin, A. F.

2017-09-01

Spectra of photoluminescence (PL) and X-ray excited luminescence (XRL) in region of 1.5-5.0 eV, PL excitation spectra (2.8-5.8 eV), PL decay kinetics were measured in Gd2O3 crystals doped both with Er3+ and Zn2+ ions. Synchrotron radiation (VEPP-3 storage ring, Novosibirsk, Russia) were used for XRL measurements. PL spectra were studied at room temperature and T= 88 K under excitation with energy Eexc: a) in fundamental absorption region (Eexc≥Eg); b) in intracenter excitation region (Eexc

Synthesis, Structural Characterization and Up-Conversion Luminescence Properties of NaYF4:Er3+,Yb3+@MOFs Nanocomposites

NASA Astrophysics Data System (ADS)

Giang, Lam Thi Kieu; Marciniak, Lukasz; Huy, Tran Quang; Vu, Nguyen; Le, Ngo Thi Hong; Binh, Nguyen Thanh; Lam, Tran Dai; Minh, Le Quoc

2017-10-01

This paper describes a facile synthesis of NaYF4:Er3+,Yb3+ nanoparticles embraced in metal-organic frameworks (MOFs), known as NaYF4:Er3+, Yb3+@MOFs core/shell nanostructures, by using iron(III) carboxylate (MIL-100) and zeolitic imidazolate frameworks (ZIF-8). Morphological, structural and optical characterization of these nanostructures were investigated by field emission-scanning electron microscopy, Fourier transform infrared spectroscopy, x-ray diffraction, and up-conversion luminescence measurements. Results showed that spherical-shaped NaYF4:Er3+,Yb3+@MIL-100 nanocomposites with diameters of 150-250 nm, and rod-shaped NaYF4:Er3+,Yb3+@ZIF-8 nanocomposites with lengths of 300-550 nm, were successfully synthesized. Under a 980-nm laser excitation at room temperature, the NaYF4:Er3+,Yb3+@MOFs nanocomposites exhibited strong up-conversion luminescence with two emission bands in the green part of spectrum at 520 nm and 540 nm corresponding to the 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 transitions of Er3+ ions, respectively, and a red emission band at 655 nm corresponding to the 4F9/2 → 4I15/2 transition of Er3+ ions. The above properties of NaYF4:Er3+,Yb3+@MOFs make them promising candidates for applications in biotechnology.

Measurement and Simulation of First-Orbit Fast-Ion D-Alpha Emission and the Application to Fast-Ion Loss Detection in the DIII-D Tokamak

NASA Astrophysics Data System (ADS)

Bolte, Nathan; Heidbrink, W. W.; Pace, D. C.; van Zeeland, M. A.; Chen, X.

2015-11-01

A new fast-ion diagnostic method uses passive emission of D-alpha radiation to determine fast-ion losses quantitatively. The passive fast-ion D-alpha simulation (P-FIDAsim) forward models the Doppler-shifted spectra of first-orbit fast ions that charge exchange with edge neutrals. Simulated spectra are up to 80 % correlated with experimental spectra. Calibrated spectra are used to estimate the 2D neutral density profile by inverting simulated spectra. The inferred neutral density shows the expected increase toward each x-point and an average value of 8 × 10 9 cm-3 at the plasma boundary and 1 × 10 11 cm-3 near the wall. Measuring and simulating first-orbit spectra effectively ``calibrates'' the system, allowing for the quantification of more general fast-ion losses. Sawtooth crashes are estimated to eject 1.2 % of the fast-ion inventory, in good agreement with a 1.7 % loss estimate made by TRANSP. Sightlines sensitive to passing ions observe larger sawtooth losses than sightlines sensitive to trapped ions. Supported by US DOE under SC-G903402, DE-FC02-04ER54698.

NaLa(MoO{sub 4}){sub 2}: RE{sup 3+} (RE{sup 3+} = Eu{sup 3+}, Sm{sup 3+}, Er{sup 3+}/Yb{sup 3+}) microspheres: the synthesis and optical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Zhiyi; Wang, Zhiying; Fu, Linlin

The strong green upconversion (UC) emission were observed in various Er{sup 3+}, Yb{sup 3+} co-doped NaLa(MoO{sub 4}){sub 2} samples synthesized via a hydrothermal route. The UC intensity depends on the dopant concentration, and the optimal UC emission was obtained in NaLa(MoO{sub 4}){sub 2}: 0.02Er{sup 3+}/0.10 Yb{sup 3+}. - Highlights: • The NaLa(MoO{sub 4}){sub 2} microspheres doped with Eu{sup 3+}, Sm{sup 3+} and Er{sup 3+}/Yb{sup 3+} were synthesized by a hydrothermal method. • The effects of the EDTA in the initial solution crystal phase and morphology were studied. • The down-conversion luminescence properties of NaLa(MoO{sub 4}){sub 2}: RE{sup 3+} (RE{sup 3+}more » = Eu{sup 3+}, Sm{sup 3+}) were investigated. • The UC luminescence properties and mechanism of Er{sup 3+}/Yb{sup 3+} co-doped NaLa(MoO{sub 4}){sub 2} was discussed. - Abstract: NaLa(MoO{sub 4}){sub 2}: RE{sup 3+} (RE{sup 3+} = Eu{sup 3+}, Sm{sup 3+}) microspheres have been synthesized at 180 °C via a facile EDTA-mediated hydrothermal route. X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), photoluminescence (PL) spectra were employed to characterize the samples. It was found that the amount of EDTA in the initial solution was responsible for crystal phase and shape determination. The effect of Eu{sup 3+} and Sm{sup 3+} doping concentrations on the luminescent intensity was also investigated in details. Furthermore, the up-conversion (UC) emissions have been observed in a series of Er{sup 3+}/Yb{sup 3+} co-doped NaLa(MoO{sub 4}){sub 2} samples. Concentration dependent studies revealed that the optimal composition was realized for a 2% Er{sup 3+} and 10% Yb{sup 3+}-doping concentration.« less

Emission Testing Results of Thermally Stable, Metamaterial, Selective-Emitters for Thermophotovoltaics

NASA Astrophysics Data System (ADS)

Levinson, Katherine; Naka, Norihito; Pfiester, Nicole; Licht, Abigail; Vandervelde, Tom

2015-03-01

In thermophotovoltaics, the energy from a heated emitter is converted to electricity by a photovoltaic diode. A selective emitter can be used to emit a narrow band of wavelengths tailored to the bandgap of the photovoltaic diode. This spectral shaping improves the conversion efficiency of the diode and reduces undesirable diode heating. In our research, we study selective emitters based on metamaterials composed of repeating nanoscale structures. The emission characteristics of these materials vary based on the compositional structure, allowing the emitted spectrum to be tunable. Simulations were performed with CST Microwave Studio to design emitters with peak wavelengths ranging from 1-10 microns. The structures were then fabricated using physical vapor deposition and electron beam lithography on a sapphire substrate. Emitter materials studied include gold, platinum, and iridium. Here we report on the emission spectra of the selective emitters and the post-heating structural integrity.

Double-Resonance Facilitated Decomposion of Emission Spectra

NASA Astrophysics Data System (ADS)

Kato, Ryota; Ishikawa, Haruki

2016-06-01

Emission spectra provide us with rich information about the excited-state processes such as proton-transfer, charge-transfer and so on. In the cases that more than one excited states are involved, emission spectra from different excited states sometimes overlap and a decomposition of the overlapped spectra is desired. One of the methods to perform a decomposition is a time-resolved fluorescence technique. It uses a difference in time evolutions of components involved. However, in the gas-phase, a concentration of the sample is frequently too small to carry out this method. On the other hand, double-resonance technique is a very powerful tool to discriminate or identify a common species in the spectra in the gas-phase. Thus, in the present study, we applied the double-resonance technique to resolve the overlapped emission spectra. When transient IR absorption spectra of the excited state are available, we can label the population of the certain species by the IR excitation with a proper selection of the IR wavenumbers. Thus, we can obtain the emission spectra of labeled species by subtracting the emission spectra with IR labeling from that without IR. In the present study, we chose the charge-transfer emission spectra of cyanophenyldisilane (CPDS) as a test system. One of us reported that two charge-transfer (CT) states are involved in the intramolecular charge-transfer (ICT) process of CPDS-water cluster and recorded the transient IR spectra. As expected, we have succeeded in resolving the CT emission spectra of CPDS-water cluster by the double resonance facilitated decomposion technique. In the present paper, we will report the details of the experimental scheme and the results of the decomposition of the emission spectra. H. Ishikawa, et al., Chem. Phys. Phys. Chem., 9, 117 (2007).

Fabrication and Luminescence Characterization of a Silica Nanomatrix Embedded with NaYF4:Yb:Er:Tm@NaGdF4/Fe3O4 Nanoparticles

NASA Astrophysics Data System (ADS)

Thangaraju, Dheivasigamani; Santhana, Vedi; Matsuda, Satoshi; Hayakawa, Yasuhiro

2018-05-01

Hexagonal NaYF4:Yb:Er:Tm@NaGdF4 core-shell nanocrystals were synthesized using a seed mediated hot injection method, and monodispersed Fe3O4 (4 nm) nanoparticles were prepared from iron(II) actylacetonate by a precursor thermal decomposition method. Structural and morphology verified NaYF4:Yb:Er:Tm@NaGdF4 and Fe3O4 nanoparticles were utilized for the preparation of NaYF4:Yb:Er:Tm@NaGdF4/Fe3O4@SiO2 nanocomposite using a micro-emulsion method. Existence of Fe3O4 in NaYF4:Yb:Er:Tm@NaGdF4 in SiO2 nano-spheres were confirmed with transmission electron microscopy. Luminescence measurement revealed that NaYF4:Yb:Er:Tm@NaGdF4 exhibited strong emissions at green and red regions, in addition to a weak blue emission also observed under 980 nm excitation. Up-conversion emission of the nanoparticle-embedded silica nanocomposite showed that the up-conversion emission was not affected by Fe3O4 nanoparticles.

A broadening temperature sensitivity range with a core-shell YbEr@YbNd double ratiometric optical nanothermometer

NASA Astrophysics Data System (ADS)

Marciniak, L.; Prorok, K.; Francés-Soriano, L.; Pérez-Prieto, J.; Bednarkiewicz, A.

2016-02-01

The chemical architecture of lanthanide doped core-shell up-converting nanoparticles can be engineered to purposely design the properties of luminescent nanomaterials, which are typically inaccessible to their homogeneous counterparts. Such an approach allowed to shift the up-conversion excitation wavelength from ~980 to the more relevant ~808 nm or enable Tb or Eu up-conversion emission, which was previously impossible to obtain or inefficient. Here, we address the issue of limited temperature sensitivity range of optical lanthanide based nano-thermometers. By covering Yb-Er co-doped core nanoparticles with the Yb-Nd co-doped shell, we have intentionally combined temperature dependent Er up-conversion together with temperature dependent Nd --> Yb energy transfer, and thus have expanded the temperature response range ΔT of a single nanoparticle based optical nano-thermometer under single ~808 nm wavelength photo-excitation from around ΔT = 150 K to over ΔT = 300 K (150-450 K). Such engineered nanocrystals are suitable for remote optical temperature measurements in technology and biotechnology at the sub-micron scale.The chemical architecture of lanthanide doped core-shell up-converting nanoparticles can be engineered to purposely design the properties of luminescent nanomaterials, which are typically inaccessible to their homogeneous counterparts. Such an approach allowed to shift the up-conversion excitation wavelength from ~980 to the more relevant ~808 nm or enable Tb or Eu up-conversion emission, which was previously impossible to obtain or inefficient. Here, we address the issue of limited temperature sensitivity range of optical lanthanide based nano-thermometers. By covering Yb-Er co-doped core nanoparticles with the Yb-Nd co-doped shell, we have intentionally combined temperature dependent Er up-conversion together with temperature dependent Nd --> Yb energy transfer, and thus have expanded the temperature response range ΔT of a single nanoparticle based optical nano-thermometer under single ~808 nm wavelength photo-excitation from around ΔT = 150 K to over ΔT = 300 K (150-450 K). Such engineered nanocrystals are suitable for remote optical temperature measurements in technology and biotechnology at the sub-micron scale. Electronic supplementary information (ESI) available: Characterization, structural and morphological characterization of nanocrystals, the measurement setup. See DOI: 10.1039/c5nr08223d

Reduction of Greenhouse Gas and Criteria Pollutant Emissions by Direct Conversion of Associated Flare Gas to Synthetic Fuels at Oil Wellheads

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tan, Eric C; Zhang, Yi Min; Schuetzle, Dennis

This study describes the results of a 'well-to-wheel' life cycle assessment (LCA) carried out to determine the potential greenhouse gas and criteria pollutant emission reductions that could be achieved by converting associated flare gas directly to synthetic fuels at oil wellheads in the US and globally. A Greyrock Flare Gas-to-Fuels(TM) conversion process at an Ohio oil well was used as the base case for this LCA. The liquid fuel produced directly from associated gas is comprised primarily of premium synthetic diesel with a small amount of synthetic gasoline. In this LCA scenario, the synthetic diesel and synthetic gasoline are blendedmore » at 20 and 10 vol% with petroleum diesel and gasoline, respectively. While the synthetic diesel fuel can be used as is (100%), the 20 vol% synthetic diesel blend (with petroleum diesel) was found to significantly improve engine performance, increase fuel economy, and reduce emissions. The direct conversion of associated gas to synthetic diesel fuels globally could reduce emissions of CO2 and CH4 by up to 356 and 5.96 million metric tons/year, respectively, resulting in the reduction of greenhouse gases (GHGs) by about 113.3 and 92.2% (20 year global warming potential) and 73.8 and 50.7% (100 year global warming potential) for synthetic diesel and gasoline fuels when compared to petroleum-derived gasoline fuels, respectively. Likewise, diesel criteria emissions could be reduced globally by up to 23.3, 0.374, 42.4, and 61.3 million metric tons/year globally for CO, particulates, NOx, and hydrocarbons, respectively. The potential economic benefit of this approach is that up to 5.30 and 71.1 billion liters of synthetic fuels could be produced each year in the US and globally from associated gas, respectively.« less

Optical properties of Mg2+, Yb3+, and Ho3+ tri-doped LiNbO3 crystals

NASA Astrophysics Data System (ADS)

Dai, Li; Liu, Chun-Rui; Tan, Chao; Yan, Zhe-Hua; Xu, Yu-Heng

2017-04-01

A series of LiNbO3 crystals tri-doped with Mg{}2+, Yb{}3+, and Ho{}3+ are grown by the conventional Czochraski technique. The concentrations of Mg{}2+, Yb{}3+, and Ho{}3+ ions in Mg:Yb:Ho:LiNbO3 crystals are measured by using an inductively coupled plasma atomic emission spectrometry. The x-ray diffraction is proposed to determine the lattice constant and analyze the internal structure of the crystal. The light-induced scattering of Mg:Yb:Ho:LiNbO3 crystal is quantitatively described via the threshold effect of incident exposure energy flux. The exposure energy ({E}{{r}}) is calculated to discuss the optical damage resistance ability. The exposure energy of Mg(7 mol):Yb:Ho:LiNbO3 crystal is 709.17 J/cm2, approximately 425 times higher than that of the Mg(1 mol):Yb:Ho:LiNbO3 crystal in magnitude. The blue, red, and very intense green bands of Mg:Yb:Ho:LiNbO3 crystal are observed under the 980-nm laser excitation to evaluate the up-conversion emission properties. The dependence of the emission intensity on pumping power indicates that the up-conversion emission is a two-photon process. The up-conversion emission mechanism is discussed in detail. This study indicates that Mg:Yb:Ho:LiNbO3 crystal can be applied to the fabrication of new multifunctional photoluminescence devices. Project supported by the National Natural Science Foundation of China (Grant No. 51301055), the Youth Science Fund of Heilongjiang Province, China (Grant No. QC2015061), the Special Funds of Harbin Innovation Talents in Science and Technology Research, China (Grant No. 2015RQQXJ045 ), and the Science Funds for the Young Innovative Talents of Harbin University of Science and Technology, China (Grant No. 201501).

Survey and research on up-conversion emission character and energy transition of Yb3+/Er3+/Tm3+ co-doped phosphate glass and glass ceramic

NASA Astrophysics Data System (ADS)

Yu, Yin; Song, Feng; Ming, Chengguo; Liu, Jiadong; Li, Wei; Liu, Yanling; Zhao, Hongyan

2012-11-01

By conventional high-temperature melting method, Yb3+/Er3+/Tm3+ co-doped phosphate glass was synthesized. After annealing the precursor glass, the phosphate glass ceramic (GC) was obtained. By measuring the X-ray diffraction (XRD) spectrum, it is proved that the LiYbP4O12 and Li6P6O18 nano-crystals have existed in the phosphate GC. The up-conversion (UC) emission intensity of the GC is obvious stronger compared to that of the glass. The reason is that the shorter distance between rare earth ions in the glass ceramic increases the energy transitions from the sensitized ions (Yb3+) to the luminous ions (Er3+ and Tm3+). By studying the dependence of UC emissions on the pump power, the 523 and 546 nm green emissions of Er3+ ions in the glass are two-photon processes. But in the glass ceramic, they are two/three-photon processes. The phenomenon implies that a three-photon process has participated in the population of the two green emissions. Using Dexter theory, we discuss the energy transitions of Er3+ and Tm3+. The results indicate the energy transition of Tm3+ to Er3+ is very strong in the GC, which changes the population mechanism of UC emissions of Er3+.

Energy transfer and up-conversion in rare-earth doped dielectric crystals

NASA Astrophysics Data System (ADS)

Tkachuk, Alexandra M.

1996-01-01

In this work, we consider the prospects of development of the visible, and IR laser-diode pumped lasers based on TR3+-doped double-fluoride crystals. On the basis of estimates of the probabilities of competing non-radiative energy-transfer processes obtained from the experiments and theoretical calculations, the conclusions are drawn on the efficiency of up-conversion pumping and selfquenching of the upper TR3+ states excited by laser-diode emission. The effect of the host composition, dopant concentration, and temperature on the efficiency of up-conversion processes is demonstrated on the example of the YLF:Nd, YLF:Er, BaY2F8:Er, and BaY2F8:Er,Yb crystals. The transfer microparameters for most important cross-relaxation transitions are determined and the conclusions about interaction mechanisms are drawn.

FERMI observations of high-energy gamma-ray emission from GRB 090217A

DOE PAGES

Ackermann, M.; Ajello, M.; Baldini, L.; ...

2010-06-22

The Fermi observatory is advancing our knowledge of gamma-ray bursts (GRBs) through pioneering observations at high energies, covering more than seven decades in energy with the two on-board detectors, the Large Area Telescope (LAT) and the Gamma-ray Burst Monitor (GBM). Here, we report on the observation of the long GRB 090217A which triggered the GBM and has been detected by the LAT with a significance greater than 9σ. We present the GBM and LAT observations and on-ground analyses, including the time-resolved spectra and the study of the temporal profile from 8 keV up to ~1 GeV. All spectra are wellmore » reproduced by a Band model. We compare these observations to the first two LAT-detected, long bursts GRB 080825C and GRB 080916C. These bursts were found to have time-dependent spectra and exhibited a delayed onset of the high-energy emission, which are not observed in the case of GRB 090217A. We discuss some theoretical implications for the high-energy emission of GRBs.« less

Optical properties of Nd3+ doped barium lithium fluoroborate glasses for near-infrared (NIR) emission

NASA Astrophysics Data System (ADS)

Mariselvam, K.; Arun Kumar, R.; Suresh, K.

2018-04-01

The neodymium doped barium lithium fluoroborate (Nd3+: BLFB) glasses with the chemical composition (70-x) H3BO3 - 10 Li2CO3 - 10 BaCO3- 5 CaF2-5 ZnO - x Nd2O3 (where x = 0.05, 0.1, 0.25, 0.5, 1, 2 in wt %) have been prepared by the conventional melt quenching technique and characterised through optical absorption, near infrared emission and decay-time measurements. The x-ray diffraction studies confirm the amorphous nature of the prepared glasses. The optical absorption spectra and emission spectra were recorded in the wavelength ranges of 190-1100 nm. The optical band gap (Eg) and Urbach energy (ΔE) values were calculated from the absorption spectra. The Judd-Ofelt intensity parameters were determined from the systematic analysis of the absorption spectrum of neodymium ions in the prepared glasses. The emission spectra exhibited three prominent peaks at 874, 1057, 1331 nm corresponding to the 4F3/2 → 4I9/2, 11/2, 13/2 transitions levels respectively in the near infrared region. The emission intensity of the 4F3/2 → 4I11/2 transition increases with the increase in neodymium concentration up to 0.5 wt% and the concentration quenching mechanism was observed for 1 wt% and 2 wt% concentrations. The lifetime of the 4F3/2 level was found to decrease with increasing Nd3+ ion concentration. The nature of energy transfer process was a single exponential curve which was studied for all the glasses and analysed.

Identification of S VIII through S XIV emission lines between 17.5 and 50 nm in a magnetically confined plasma

NASA Astrophysics Data System (ADS)

McCarthy, K. J.; Tamura, N.; Combs, S. K.; García, R.; Hernández Sánchez, J.; Navarro, M.; Panadero, N.; Pastor, I.; Soleto, A.; the TJ-II Team

2018-03-01

43 spectral emission lines from F-like to Li-like sulphur ions have been identified in the wavelength range from 17.5 to 50 nm in spectra obtained following tracer injection into plasmas created in a magnetically confined plasma device, the stellarator TJ-II. Plasmas created and maintained in this heliac device with electron cyclotron resonance heating achieve central electron temperatures and densities up to 1.5 keV and 8 × 1018 m-3, respectively. Tracer injections were performed with ≤6 × 1016 atoms of sulphur contained within ˜300 μm diameter polystyrene capsules, termed tracer encapsulated solid pellets, using a gas propulsion system to achieve velocities between 250 and 450 m s-1. Once ablation of the exterior polystyrene shell by plasma particles is completed, the sulphur is deposited in the plasma core where it is ionized up to S+13 and transported about the plasma. In order to aid line identification, which is made using a number of atomic line emission databases, spectra are collected before and after injection using a 1 m focal length normal incidence spectrometer equipped with a CCD camera. This work is motivated by the need to clearly identify sulphur emission lines in the vacuum ultraviolet range of magnetically confined plasmas, as sulphur x-ray emission lines are regularly observed in both tokamak and stellarator plasmas.

Orientation hydrogen-bonding effect on vibronic spectra of isoquinoline in water solvent: Franck-Condon simulation and interpretation

NASA Astrophysics Data System (ADS)

Liu, Yu-Hui; Wang, Shi-Ming; Wang, Chen-Wen; Zhu, Chaoyuan; Han, Ke-Li; Lin, Sheng-Hsien

2016-10-01

The excited-state orientation hydrogen-bonding dynamics, and vibronic spectra of isoquinoline (IQ) and its cationic form IQc in water have been investigated at the time-dependent density functional theory quantum chemistry level plus Franck-Condon simulation and interpretation. The excited-state orientation hydrogen bond strengthening has been found in IQ:H2O complex due to the charge redistribution upon excitation; this is interpreted by simulated 1:1 mixed absorption spectra of free IQ and IQ:H2O complex having best agreement with experimental results. Conversely, the orientation hydrogen bond in IQc:H2O complex would be strongly weakening in the S1 state and this is interpreted by simulated absorption spectra of free IQc having best agreement with experimental results. By performing Franck-Condon simulation, it reveals that several important vibrational normal modes with frequencies about 1250 cm-1 involving the wagging motion of the hydrogen atoms are very sensitive to the formation of the orientation hydrogen bond for the IQ/IQc:H2O complex and this is confirmed by damped Franck-Condon simulation with free IQ/IQc in water. However, the emission spectra of the IQ and IQc in water have been found differently. Upon the excitation, the simulated fluorescence of IQ in water is dominated by the IQ:H2O complex; thus hydrogen bond between IQ and H2O is much easier to form in the S1 state. While the weakened hydrogen bond in IQc:H2O complex is probably cleaved upon the laser pulse because the simulated emission spectrum of the free IQc is in better agreement with the experimental results.

Atomic emission lines in the near ultraviolet; hydrogen through krypton, section 1

NASA Technical Reports Server (NTRS)

Kelly, R. L.

1979-01-01

A compilation of spectra from the first 36 elements was prepared from published literature available through October 1977. In most cases, only those lines which were actually observed in emission or absorption are listed. The wavelengths included range from 2000 Angstroms to 3200 Angstroms with some additional lines up to 3500 Angstroms. Only lines of stripped atoms are reported; no molecular bands are included.

Atomic emission lines in the near ultraviolet; hydrogen through krypton, section 2

NASA Technical Reports Server (NTRS)

Kelly, R. L.

1979-01-01

A compilation of spectra from the first 36 elements was prepared from published literature available through October 1977. In most cases, only those lines which were actually observed in emission or absorption are listed. The wavelengths included range from 2000 Angstroms to 3200 Angstroms with some additional lines up to 3500 Angstroms. Only lines of stripped atoms are reported; no molecular bands are included.

Algorithms for classification of astronomical object spectra

NASA Astrophysics Data System (ADS)

Wasiewicz, P.; Szuppe, J.; Hryniewicz, K.

2015-09-01

Obtaining interesting celestial objects from tens of thousands or even millions of recorded optical-ultraviolet spectra depends not only on the data quality but also on the accuracy of spectra decomposition. Additionally rapidly growing data volumes demands higher computing power and/or more efficient algorithms implementations. In this paper we speed up the process of substracting iron transitions and fitting Gaussian functions to emission peaks utilising C++ and OpenCL methods together with the NOSQL database. In this paper we implemented typical astronomical methods of detecting peaks in comparison to our previous hybrid methods implemented with CUDA.

A user-friendly, menu-driven, language-free laser characteristics curves graphing program for desk-top IBM PC compatible computers

NASA Technical Reports Server (NTRS)

Klutz, Glenn

1989-01-01

A facility was established that uses collected data and feeds it into mathematical models that generate improved data arrays by correcting for various losses, base line drift, and conversion to unity scaling. These developed data arrays have headers and other identifying information affixed and are subsequently stored in a Laser Materials and Characteristics data base which is accessible to various users. The two part data base: absorption - emission spectra and tabulated data, is developed around twelve laser models. The tabulated section of the data base is divided into several parts: crystalline, optical, mechanical, and thermal properties; aborption and emission spectra information; chemical name and formulas; and miscellaneous. A menu-driven, language-free graphing program will reduce and/or remove the requirement that users become competent FORTRAN programmers and the concomitant requirement that they also spend several days to a few weeks becoming conversant with the GEOGRAF library and sequence of calls and the continual refreshers of both. The work included becoming thoroughly conversant with or at least very familiar with GEOGRAF by GEOCOMP Corp. The development of the graphing program involved trial runs of the various callable library routines on dummy data in order to become familiar with actual implementation and sequencing. This was followed by trial runs with actual data base files and some additional data from current research that was not in the data base but currently needed graphs. After successful runs, with dummy and real data, using actual FORTRAN instructions steps were undertaken to develop the menu-driven language-free implementation of a program which would require the user only know how to use microcomputers. The user would simply be responding to items displayed on the video screen. To assist the user in arriving at the optimum values needed for a specific graph, a paper, and pencil check list was made available to use on the trial runs.

Thermal-infrared spectral observations of geologic materials in emission

NASA Technical Reports Server (NTRS)

Christensen, Philip R.; Luth, Sharon J.

1987-01-01

The thermal-infrared spectra of geologic materials in emission were studied using the prototype Thermal Emission Spectrometer (TES). A variety of of processes and surface modifications that may influence or alter the spectra of primary rock materials were studied. It was confirmed that thermal emission spectra contain the same absorption features as those observed in transmission and reflection spectra. It was confirmed that the TES instrument can be used to obtain relevant spectra for analysis of rock and mineral composition.

Fluorine and Lithium at the Kimberley Outcrop, Gale Crater

NASA Technical Reports Server (NTRS)

Forni, O.; Vaniman, D. T.; Le Deit, L.; Clegg, S. M.; Lanza, N. L.; Lasue, J.; Bish, D. L.; Mangold, N.; Wiens, R. C.; Meslin, P.-Y.;

Time delay and excitation mode induced tunable red/near-infrared to green emission ratio of Er doped BiOCl

NASA Astrophysics Data System (ADS)

Avram, Daniel; Florea, Mihaela; Tiseanu, Ion; Tiseanu, Carmen

2015-09-01

Herein, we report on the emission color tunability of Er doped BiOCl measured under up—conversion as well as x-ray excitation modes. The dependence of red (670 nm) to green emission (543 nm) ratio on Er concentration (1 and 5%), excitation wavelength into different (656.4, 802 and 976 nm) or across single Er absorption levels (965 ÷ 990 nm) and delay after the laser pulse (0.001 ÷ 1 ms) is discussed in terms of ground state absorption/excited state absorption and energy transfer up-conversion mechanisms. A first example of extended Er x-ray emission measured in the range of 500 to 1700 nm shows comparable emission intensities corresponding to 543 nm and 1500 nm based transitions. The present results together with our earlier report on the upconversion emission of Er doped BiOCl excited at 1500 nm, suggest that Er doped BiOCl may be considered an attractive system for optical and x-ray imaging applications.

Structural, optical absorption and photoluminescence spectral studies of Sm3+ ions in Alkaline-Earth Boro Tellurite glasses

NASA Astrophysics Data System (ADS)

Siva Rama Krishna Reddy, K.; Swapna, K.; Mahamuda, Sk.; Venkateswarlu, M.; Srinivas Prasad, M. V. V. K.; Rao, A. S.; Prakash, G. Vijaya

2018-05-01

Sm3+ ions doped Alkaline-Earth Boro Tellurite (AEBT) glasses were prepared by using conventional melt quenching technique and characterized using the spectroscopic techniques such as FT-IR, optical absorption, emission and decay spectral measurements to understand their utility in optoelectronic devices. From absorption spectra, the bonding parameters, nephelauxetic ratios were determined to know the nature of bonding between Sm3+ ions and its surrounding ligands. From the measured oscillator strengths, the Judd-Ofelt (J-O) intensity parameters were evaluated and in turn used to estimate various radiative parameters for the fluorescent levels of Sm3+ ions in AEBT glasses. The PL spectra of Sm3+ ions exhibit three emission bands corresponding to the transitions 4G5/2 → 6H5/2, 6H7/2 and 6H9/2 in the visible region for which the emission cross-sections and branching ratios were evaluated. The decay spectral profiles measured for 4G5/2 → 6H7/2 transition showed single exponential for lower concentration and non-exponential for higher concentration of doped rare earth ion in the as prepared glasses. Conversion of decay spectral profiles from single to non-exponential have been analyzed using Inokuti-Hirayama (I-H) model to understand the energy transfer mechanism involved in the decay process. CIE Chromaticity coordinates were measured using emission spectral data to identify the exact region of emission from the as-prepared glasses. From the evaluated radiative parameters, emission cross-sections and quantum efficiencies, it was observed that AEBT glass with 1 mol% of Sm3+ ions is more suitable for designing optoelectronic devices.

The behavior of exciplex decay processes and interplay of radiationless transition and preliminary reorganization mechanisms of electron transfer in loose and tight pairs of reactants.

PubMed

Kuzmin, Michael G; Soboleva, Irina V; Dolotova, Elena V

2007-01-18

Exciplex emission spectra and rate constants of their decay via internal conversion and intersystem crossing are studied and discussed in terms of conventional radiationless transition approach. Exciplexes of 9-cyanophenanthrene with 1,2,3-trimethoxybenzene and 1,3,5-trimethoxybenzene were studied in heptane, toluene, butyl acetate, dichloromethane, butyronitrile, and acetonitrile. A better description of spectra and rate constants is obtained using 0-0 transition energy and Gauss broadening of vibrational bands rather than the free energy of electron transfer and reorganization energy. The coincidence of parameters describing exciplex emission spectra and dependence of exciplex decay rate constants on energy gap gives the evidence of radiationless quantum transition mechanism rather than thermally activated medium reorganization mechanism of charge recombination in exciplexes and excited charge transfer complexes (contact radical ion pairs) as well as in solvent separated radical ion pairs. Radiationless quantum transition mechanism is shown to provide an appropriate description also for the main features of exergonic excited-state charge separation reactions if fast mutual transformations of loose and tight pairs of reactants are considered. In particular, very fast electron transfer (ET) in tight pairs of reactants with strong electronic coupling of locally excited and charge transfer states can prevent the observation of an inverted region in bimolecular excited-state charge separation even for highly exergonic reactions.

Thermal Infrared Spectra of a Suite of Forsterite Samples and Ab-initio Modelling of theirs Spectra

NASA Astrophysics Data System (ADS)

Maturilli, A.; Stangarone, C.; Helbert, J.; Tribaudino, M.; Prencipe, M.

2017-12-01

Forsterite is the dominating component in olivine, a major constituent in ultrafemic rocks, as well as planetary bodies. Messenger X-ray spectrometer has shown that Mg-rich silicate minerals, such as enstatite and forsterite, dominate Mercury's surface (Weider et al 2012). A careful and detailed acquaintance with the forsterite spectral features and their dependence wrt environmental conditions on Mercury is needed to interpret the remote sensing data from previous and forthcoming missions. We propose an experimental vs calculation approach to reproduce and describe the spectral features of forsterite. TIR emissivity measurements are performed by the Planetary Spectroscopy Laboratory (PSL) of DLR. PSL offers the unique capability to measure the emissivity of samples at temperature up to 1000K under vacuum conditions. TIR emissivity and reflectance measurements are performed on 11 olivine samples having a different composition within the forsterite-fayalite series. When available, the sample has been measured in 2 different grain sizes (<25µm and 125-250µm ranges). Emissivity measurements are taken for temperatures from 300K to 900K step 100K in the 1-100µm spectral range. Modelling is based on ab initio calculation techniques, which allow reproducing properties of crystals, at any P/T condition, with the least possible amount of a priori empirical information. Spectra are calculated evaluating vibrational frequencies at different volume cell, here 0K, 300K and 1000K (extreme situations), taking into account zero point effects. The aim of this work is to study experimentally the effects of temperature, composition and grain sizes on emissivity band minima shifts. The outcomes will benefit the modelling of emissivity spectra with ab initio methods, already successfully enabling to foresee the bands shift due to temperature and composition, but not taking into account band shape due to grain size variations. Considering the chameleon-like effects of Mercury surface already observed (Helbert et al. 2013), this study wants to point out the main spectral features due to the composition and temperature. Our results are used to create a theoretical background to interpret the high temperature infrared emissivity spectra from MERTIS onboard the ESA BepiColombo mission to Mercury (Helbert et al. 2010).

Herschel Far Infrared Spectra of Dusty Star-Forming Galaxies

NASA Astrophysics Data System (ADS)

Wilson, Derek; Cooray, Asantha R.; Nayyeri, Hooshang

2017-01-01

We stack archival spectra from the Herschel Space Observatory's SPIRE Spectrometer in three redshift bins from low redshifts (z < 0.2), through intermediate redshifts (0.2 < z < 1), and up to high redshifts (z > 1) in order to determine the average properties of the gas and dust in dusty, star-forming galaxies and (U)LIRGs. In the lower-redshift stack, we detect a host of water and carbon monoxide rotational transition lines, as well as some fine structure lines such as [NII]. At intermediate redshifts, only a [CII] line appears. The high-redshift stack displays strong [CII] emission, as well as faint emission from [OI] and [OIII]. The observed emission lines are used to model the average number density and radiation field strength in the photodissociation regions of our high-redshift sample, and the spectral line energy distributions of CO rotational transitions from the low-redshift stack are presented.

Laser-induced emission spectroscopy of matrix-isolated carbon molecules: Experimental setup and new results on C3

NASA Astrophysics Data System (ADS)

Čermák, Ivo; Förderer, Markus; Čermáková, Iva; Kalhofer, Stefan; Stopka-Ebeler, Helmut; Monninger, Gerold; Krätschmer, Wolfgang

1998-06-01

We have studied small carbon molecules using a matrix-isolation technique. Our experimental setup is described in detail. The carbon clusters were produced by evaporating graphite and trapping the carbon-vapor molecules in solid argon, where molecular growth could be induced by controlled matrix annealing. To identify the produced molecules, absorption spectroscopy in the ultraviolet (UV)-visible and infrared (IR) spectral ranges was applied. Additional characterization of the excited and ground states of the molecules was obtained from emission and excitation spectra. The molecules were excited by a pulsed dye laser system and the emission spectra were recorded with a high-sensitivity photodiode-array spectrometer. We present our measurements on linear C3. The à 1Πu excited state of linear C3 was populated by the electronic transition à 1Πu←X˜ 1Σg+, and the corresponding excitation spectra of the C3 fluorescence (à 1Πu→X˜ 1Σg+) and phosphorescence (ã 3Πu→X˜ 1Σg+) were studied. Comparison of excitation and absorption spectra yielded information on site effects due to the matrix environment. Emission bands in the fluorescence and phosphorescence spectra up to vibrational energies of 8500 cm-1 could be observed. The radiation lifetime of the à 1Πu excited state of C3 in solid argon was found to be shorter than 10 ns. The phosphorescence transition ã 3Πu→X˜ 1Σg+ decays in about 10 ms and its rise indicates fast vibrational relaxation within the triplet system. Our data support a linear ground state geometry for C3 also in solid argon.

Near-IR, blue, and UV generation by frequency conversion of a Tm:YAP laser

NASA Astrophysics Data System (ADS)

Cole, Brian; Goldberg, Lew; Chinn, Steve

2018-02-01

We describe generation of near-infrared (944nm, 970nm), blue (472nm, 485nm), and UV (236 nm) light by frequency up-conversion of 2 μm output of a compact and efficient passively Q-switched Tm:YAP laser. The Tm:YAP laser source was near diffraction limited with maximum Q-switched pulse peak power of 190 kW. For second harmonic generation (SHG) of NIR, both periodically poled lithium niobate (PPLN) and lithium tri-borate (LBO) were evaluated, with 58% conversion efficiency and 3.1 W of 970 nm power achieved with PPLN. The PPLN 970nm emission was frequency doubled in 20mm long type I LBO, generating 1.1 W at 485nm with a conversion efficiency of 34%. With LBO used for frequency doubling of 2.3 W of 1888 nm Tm:YAP output to 944nm, 860mW was generated, with 37% conversion efficiency. Using a second LBO crystal to generate the 4th harmonic, 545mW of 472nm power was generated, corresponding to 64% conversion efficiency. To generate the 8th harmonic of Tm:YAP laser emission, the 472nm output of the second LBO was frequency doubled in a 7mm long BBO crystal, generating 110 mW at 236nm, corresponding to 21% conversion efficiency.

Local symmetric distortion boosted photon up-conversion and thermometric sensitivity in lanthanum oxide nanospheres.

PubMed

Suo, Hao; Zhao, Xiaoqi; Zhang, Zhiyu; Shi, Rui; Wu, Yanfang; Xiang, Jinmeng; Guo, Chongfeng

2018-05-17

It is essential to simultaneously boost the luminescence intensity and thermometric sensitivity of up-converted optical thermometers towards potential biomedical sensing applications. Herein, the effects of local site symmetry on the up-conversion (UC) emission and thermal sensing ability in trigonal-phased La2O3:Er3+/Yb3+ nanospheres were qualitatively explored using cubic-phased Lu2O3 and Y2O3 with a similar shape and phonon energy as contrasts. Under 980 nm light excitation, much stronger UC emissions were detected in La2O3 samples than that in cubic Lu2O3 and Y2O3 samples, and the possible mechanisms were elaborately proposed using Eu3+ as a luminescent probe. Thermo-responsive emission intensity from 2H11/2/4S3/2 levels was monitored to evaluate the absolute sensitivity of three samples, which strongly depends on the dopant-induced local site symmetric distortions according to the Judd-Ofelt theory. The potentiality of La2O3:Er3+/Yb3+ for sub-tissue thermometry was also validated by ex vivo experiments. Results open a promising avenue for realizing highly sensitive thermometry with a large signal-to-noise ratio in sub-tissues via finely tailoring the local site symmetry.

The origin of fast molecular outflows in quasars: molecule formation in AGN-driven galactic winds

NASA Astrophysics Data System (ADS)

Richings, Alexander J.; Faucher-Giguère, Claude-André

2018-03-01

We explore the origin of fast molecular outflows that have been observed in active galactic nuclei (AGNs). Previous numerical studies have shown that it is difficult to create such an outflow by accelerating existing molecular clouds in the host galaxy, as the clouds will be destroyed before they can reach the high velocities that are observed. In this work, we consider an alternative scenario where molecules form in situ within the AGN outflow. We present a series of hydro-chemical simulations of an isotropic AGN wind interacting with a uniform medium. We follow the time-dependent chemistry of 157 species, including 20 molecules, to determine whether molecules can form rapidly enough to produce the observed molecular outflows. We find H2 outflow rates up to 140 M_{⊙} yr^{-1}, which is sensitive to density, AGN luminosity, and metallicity. We compute emission and absorption lines of CO, OH, and warm (a few hundred K) H2 from the simulations in post-processing. The CO-derived outflow rates and OH absorption strengths at solar metallicity agree with observations, although the maximum line-of-sight velocities from the model CO spectra are a factor ≈2 lower than is observed. We derive a CO (1-0) to H2 conversion factor of α _{CO (1-0)} = 0.13 M_{⊙} (K km s^{-1} pc2)^{-1}, 6 times lower than is commonly assumed in observations of such systems. We find strong emission from the mid-infrared lines of H2. The mass of H2 traced by this infrared emission is within a few per cent of the total H2 mass. This H2 emission may be observable by James Webb Space Telescope.

Temperature dependence of the ratio of intensities of up-conversion fluorescence bands of YVO4 and YGdVO4 crystals and lead fluoride nano glass ceramics activated with erbium ions

NASA Astrophysics Data System (ADS)

Varaksa, Yu. A.; Sinitsyn, G. V.; Khodasevich, M. A.; Aseev, V. A.; Kolobkova, E. V.; Yasyukevich, A. S.

2015-01-01

Up-conversion fluorescence spectra of YVO4 and YGdVO4 crystals and lead fluoride nano glass ceramics coactivated with erbium and ytterbium ions have been studied in the wavelength range of 520-560 nm under 967-nm pumping. The ratio of intensities of fluorescence bands in the ranges of 520-530 and 540-550 nm has been measured in the temperature range of from room temperature to 150°C. It is shown that the considered materials can be used for preparing a sensing element of optical fluorescent temperature sensors; the sensitivity of measuring the temperature of nano glass-ceramics can be close to that of crystal samples.

Ca2 Al2 SiO7 :Ce3+ phosphors for mechanoluminescence dosimetry.

PubMed

Tiwari, Geetanjali; Brahme, Nameeta; Sharma, Ravi; Bisen, D P; Sao, Sanjay Kumar; Sahu, Ishwar Prasad

2016-12-01

A series of Ce 3+ ion single-doped Ca 2 Al 2 SiO 7 phosphors was synthesized by a combustion-assisted method at an initiating temperature of 600 °C. The samples were annealed at 1100 °C for 3 h and their X-ray diffraction patterns confirmed a tetragonal structure. The phase structure, particle size, surface morphology and elemental analysis were analyzed using X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy techniques. Thermoluminescence (TL) intensity increased with increase in ultraviolet (UV) light exposure time up to 15 min. With further increase in the UV irradiation time the TL intensity decreases. The increase in TL intensity indicates that trap concentration increased with UV exposure time. A broad peak at 121 °C suggested the existence of a trapping level. The peak of mechanoluminescence (ML) intensity versus time curve increased linearly with increasing impact velocity of the moving piston. Mechanoluminescence intensity increased with increase in UV irradiation time up to 15 min. Under UV-irradiation excitation, the TL and ML emission spectra of Ca 2 Al 2 SiO 7 :Ce 3+ phosphor showed the characteristic emission of Ce 3+ peaking at 400 nm (UV-violet) and originating from the Ce 3+ transitions of 5d-4f ( 2 F 5/2 and 2 F 7/2 ). The photoluminescence (PL) emission spectra for Ca 2 Al 2 SiO 7 :Ce 3+ were similar to the ML/TL emission spectra. The mechanism of ML excitation and the suitability of the Ca 2 Al 2 SiO 7 :Ce 3+ phosphor for radiation dosimetry are discussed. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Synergistic plasmonic and photonic crystal light-trapping: architectures for optical up-conversion in thin-film solar cells.

PubMed

Le, Khai Q; John, Sajeev

2014-01-13

We demonstrate, numerically, that with a 60 nanometer layer of optical up-conversion material, embedded with plasmonic core-shell nano-rings and placed below a sub-micron silicon conical-pore photonic crystal it is possible to absorb sunlight well above the Lambertian limit in the 300-1100 nm range. With as little as 500 nm, equivalent bulk thickness of silicon, the maximum achievable photo-current density (MAPD) is about 36 mA/cm2, using above-bandgap sunlight. This MAPD increases to about 38 mA/cm2 for one micron of silicon. Our architecture also provides solar intensity enhancement by a factor of at least 1400 at the sub-bandgap wavelength of 1500 nm, due to plasmonic and photonic crystal resonances, enabling a further boost of photo-current density from up-conversion of sub-bandgap sunlight. With an external solar concentrator, providing 100 suns, light intensities sufficient for significant nonlinear up-conversion can be realized. Two-photon absorption of sub-bandgap sunlight is further enhanced by the large electromagnetic density of states in the photonic crystal at the re-emission wavelength near 750 nm. It is suggested that this synergy of plasmonic and photonic crystal resonances can lead to unprecedented power conversion efficiency in ultra-thin-film silicon solar cells.

Constraining the Accretion Mode in LINER 1.9s

NASA Astrophysics Data System (ADS)

Sabra, Bassem; Der Sahaguian, Elias; Badr, Elie

2016-01-01

The accretion mode and the dominant power source in low-ionization nuclear emission-line regions (LINERs), a class of active galactic nuclei (AGN), are still elusive. We focus on a sample of 22 LINER 1.9s (Ho et al. 1997), a subclass of LINERs that show broad Halpha lines, a signature of blackhole-powered accretion, to test the hypothesis that the ionizing continuum emitted by a radiatively inefficient accretion flow (RIAF) could lead to the LINER ultraviolet (UV) emission-line ratios. Optical line-ratio diagrams are a weak diagnostic tool in distinguishing between possible power sources (Sabra et al. 2003). We search the Mikulski Archive for Space Telescopes (MAST) for UV spectra of the objects in the above sample and also perform photoionization simulations using CLOUDY (Ferland et al. 2013). Unfortunately, only one object (NGC 1052; Gabel et al. 2000) of the 22 LINER 1.9s has UV spectra that cover many emission lines; the rest of the objects either do not have any UV spectra, the spectral coverage is in-adequate, or the spectra have very low signal-to-noise ratios. Our photoionization simulations set up two identical grids of clouds with a range of densities and ionization parameters. We illuminate one grid with radiation emitted by a thin accretion disk (AD) and we illuminate the other grid with radiation from a RIAF. We overplot the UV emission-line ratio predictions for AD and RIAF illumination, together with the available line ratios for NGC 1052. Initial results show that UV lines could be used as diagnostics for the accretion mode in AGN. More UV spectral coverage of LINER 1.9s is needed in order to more fully utilize the diagnostic powers of UV emission line ratios.

Inference of the electron temperature in ICF implosions from the hard X-ray spectral continuum

NASA Astrophysics Data System (ADS)

Kagan, Grigory; Landen, O. L.; Svyatsky, D.; Sio, H.; Kabadi, N. V.; Simpson, R. A.; Gatu Johnson, M.; Frenje, J. A.; Petrasso, R. D.; Shah, R. C.; Joshi, T. R.; Hakel, P.; Weber, T. E.; Rinderknecht, H. G.; Thorn, D.; Schneider, M.; Bradley, D.; Kilkenny, J.

2017-10-01

The NIF Continuum Spectrometer, scheduled to be first deployed in Fall of 2017, will infer the imploded core electron temperature from the free-free continuum self-emission spectra of photons with energies of 20 to 30 keV. However, this hard X-ray radiation is emitted by the tail of the electron distribution, which likely deviates from Maxwellian and thus obscures interpretation of the data. We investigate resulting modifications to the X-ray spectra. The logarithmic slope of the spectrum from the more realistic, non-thermal tail of the electron distribution is found to decrease more rapidly at higher photon energies, as compared to the perfectly Maxwellian case. Interpreting the spectrum with assumption of Maxwellian electrons enforced is shown to give an electron temperature that is lower than the actual one. Conversely, due to its connection with the non-thermal features in the electron distribution, hard X-ray emission can provide unprecedented information about kinetic processes in the hot DT core. This work was performed under the auspices of the U.S. Dept. of Energy by the Los Alamos National Security, LLC, Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396.

The binuclear nickel center in the A-cluster of acetyl-CoA synthase (ACS) and two biomimetic dinickel complexes studied by X-ray absorption and emission spectroscopy

NASA Astrophysics Data System (ADS)

Schrapers, P.; Mebs, S.; Ilina, Y.; Warner, D. S.; Wörmann, C.; Schuth, N.; Kositzki, R.; Dau, H.; Limberg, C.; Dobbek, H.; Haumann, M.

2016-05-01

Acetyl-CoA synthase (ACS) is involved in the bacterial carbon oxide conversion pathway. The binuclear nickel sites in ACS enzyme and two biomimetic synthetic compounds containing a Ni(II)Ni(II) unit (1 and 2) were compared using XAS/XES. EXAFS analysis of ACS proteins revealed similar Ni-N/O/S bond lengths and Ni-Ni/Fe distances as in the crystal structure in oxidized ACS, but elongated Ni-ligand bonds in reduced ACS, suggesting more reduced nickel species. The XANES spectra of ACS and the dinickel complexes showed overall similar shapes, but less resolved pre-edge and edge features in ACS, attributed to more distorted square-planar nickel sites in particular in reduced ACS. DFT calculation of pre-edge absorption and Kβ2,5 emission features reproduced the experimental spectra of the synthetic complexes, was sensitive even to the small geometry differences in 1 and 2, and indicated low-spin Ni(II) sites. Comparison of nickel sites in proteins and biomimetic compounds is valuable for deducing structural and electronic differences in response to ligation and redox changes.

Forecasting the Contribution of Polarized Extragalactic Radio Sources in CMB Observations

NASA Astrophysics Data System (ADS)

Puglisi, G.; Galluzzi, V.; Bonavera, L.; Gonzalez-Nuevo, J.; Lapi, A.; Massardi, M.; Perrotta, F.; Baccigalupi, C.; Celotti, A.; Danese, L.

2018-05-01

We combine the latest data sets obtained with different surveys to study the frequency dependence of polarized emission coming from extragalactic radio sources (ERS). We consider data over a very wide frequency range starting from 1.4 GHz up to 217 GHz. This range is particularly interesting since it overlaps the frequencies of the current and forthcoming cosmic microwave background (CMB) experiments. Current data suggest that at high radio frequencies (ν ≥ 20 GHz) the fractional polarization of ERS does not depend on the total flux density. Conversely, recent data sets indicate a moderate increase of polarization fraction as a function of frequency, physically motivated by the fact that Faraday depolarization is expected to be less relevant at high radio frequencies. We compute ERS number counts using updated models based on recent data, and we forecast the contribution of unresolved ERS in CMB polarization spectra. Given the expected sensitivities and the observational patch sizes of forthcoming CMB experiments, about ∼200 (up to ∼2000) polarized ERS are expected to be detected. Finally, we assess that polarized ERS can contaminate the cosmological B-mode polarization if the tensor-to-scalar ratio is <0.05 and they have to be robustly controlled to de-lens CMB B-modes at the arcminute angular scales.

Temperature and baric dependence of nuclear quadruple resonance spectra in indium and gallium monoselenides

NASA Astrophysics Data System (ADS)

Khandozhko, Victor; Raranskii, Nikolai; Balazjuk, Vitaly; Samila, Andriy; Kovalyuk, Zahar

2013-12-01

Pulsed radiospectroscopy method has been used to study nuclear quadruple resonance (NQR) spectra of 69Ga and 115In isotopes in the layered semiconductors GaSe and InSe. It has been found that in GaSe and InSe there is a considerable temperature dependence of NQR frequency which in the temperature range of 250 to 390 K is practically linear with conversion slope 1.54 kHz/degree for 69Ga and 2.35 kHz/degree for 115In. In the same crystals the effect of uniaxial pressure on NQR spectra applied along the optical axis с up to the values of 500 kg/сm2 has been studied. A strong attenuation of NQR spectra intensity with increase in pressure on layered crystal package has been established. The unvaried multiplicity of resonance spectra indicates the absence of structural transformations in these layered crystals over the investigated range of temperatures and pressures.

X-ray spectroscopic study of amorphous and polycrystalline PbO films, α-PbO, and β-PbO for direct conversion imaging.

PubMed

Qamar, A; LeBlanc, K; Semeniuk, O; Reznik, A; Lin, J; Pan, Y; Moewes, A

2017-10-13

We investigated the electronic structure of Lead Oxide (PbO) - one of the most promising photoconductor materials for direct conversion x-ray imaging detectors, using soft x-ray emission and absorption spectroscopy. Two structural configurations of thin PbO layers, namely the polycrystalline and the amorphous phase, were studied, and compared to the properties of powdered α-PbO and β-PbO samples. In addition, we performed calculations within the framework of density functional theory and found an excellent agreement between the calculated and the measured absorption and emission spectra, which indicates high accuracy of our structural models. Our work provides strong evidence that the electronic structure of PbO layers, specifically the width of the band gap and the presence of additional interband and intraband states in both conduction and valence band, depend on the deposition conditions. We tested several model structures using DFT simulations to understand what the origin of these states is. The presence of O vacancies is the most plausible explanation for these additional electronic states. Several other plausible models were ruled out including interstitial O, dislocated O and the presence of significant lattice stress in PbO.

Excitonic nature of optical transitions in electroabsorption spectra of perovskite solar cells

NASA Astrophysics Data System (ADS)

Ruf, Fabian; Magin, Alice; Schultes, Moritz; Ahlswede, Erik; Kalt, Heinz; Hetterich, Michael

2018-02-01

We investigate the electronic structure of solution-processed perovskite solar cells using temperature-dependent electroabsorption (EA) spectroscopy. Simultaneous measurements of absorption and electromodulated spectra of semitransparent methylammonium lead iodide solar cells facilitate a direct comparison of the specific features. The EA spectra can be transformed to peak-like line shapes utilizing an approach based on the Kramers-Kronig relations. The resulting peak positions correspond well to the discrete excitonic—rather than the continuum—contribution of the absorption spectra derived from generalized Elliott fits. This indicates the excitonic nature of the observed EA resonance and is found to be consistent over the whole temperature range investigated (from T = 10 K up to room temperature). To further confirm these findings, a line shape analysis of the measured EA spectra was performed. The best agreement was achieved using a first-derivative-like functional form which is expected for excitonic systems and supports the conclusion of an excitonic optical transition. Exciton binding energies EB are estimated for the orthorhombic and tetragonal phases as 26 meV and 19 meV, respectively. Nevertheless, power-conversion efficiencies η up to 13% (11.5% stabilized) demonstrate good charge-carrier separation in the devices due to sufficient thermal dissociation and Sommerfeld-enhanced absorption.

Folic acid-functionalized up-conversion nanoparticles: toxicity studies in vivo and in vitro and targeted imaging applications

NASA Astrophysics Data System (ADS)

Sun, Lining; Wei, Zuwu; Chen, Haige; Liu, Jinliang; Guo, Jianjian; Cao, Ming; Wen, Tieqiao; Shi, Liyi

2014-07-01

Folate receptors (FRs) are overexpressed on a variety of human cancer cells and tissues, including cancers of the breast, ovaries, endometrium, and brain. This over-expression of FRs can be used to target folate-linked imaging specifically to FR-expressing tumors. Fluorescence is emerging as a powerful new modality for molecular imaging in both the diagnosis and treatment of disease. Combining innovative molecular biology and chemistry, we prepared three kinds of folate-targeted up-conversion nanoparticles as imaging agents (UCNC-FA: UCNC-Er-FA, UCNC-Tm-FA, and UCNC-Er,Tm-FA). In vivo and in vitro toxicity studies showed that these nanoparticles have both good biocompatibility and low toxicity. Moreover, the up-conversion luminescence imaging indicated that they have good targeting to HeLa cells and can therefore serve as potential fluorescent contrast agents.Folate receptors (FRs) are overexpressed on a variety of human cancer cells and tissues, including cancers of the breast, ovaries, endometrium, and brain. This over-expression of FRs can be used to target folate-linked imaging specifically to FR-expressing tumors. Fluorescence is emerging as a powerful new modality for molecular imaging in both the diagnosis and treatment of disease. Combining innovative molecular biology and chemistry, we prepared three kinds of folate-targeted up-conversion nanoparticles as imaging agents (UCNC-FA: UCNC-Er-FA, UCNC-Tm-FA, and UCNC-Er,Tm-FA). In vivo and in vitro toxicity studies showed that these nanoparticles have both good biocompatibility and low toxicity. Moreover, the up-conversion luminescence imaging indicated that they have good targeting to HeLa cells and can therefore serve as potential fluorescent contrast agents. Electronic supplementary information (ESI) available: Up-conversion luminescence spectra of UCNC-Er and UCNC-Er-FA, UCNC-Tm and UCNC-Tm-FA. Confocal luminescence imaging data collected as a series along the Z optical axis. See DOI: 10.1039/c4nr02312a

Spectral optimization simulation of white light based on the photopic eye-sensitivity curve

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Qi, E-mail: qidai@tongji.edu.cn; Institute for Advanced Study, Tongji University, 1239 Siping Road, Shanghai 200092; Key Laboratory of Ecology and Energy-saving Study of Dense Habitat

Spectral optimization simulation of white light is studied to boost maximum attainable luminous efficacy of radiation at high color-rendering index (CRI) and various color temperatures. The photopic eye-sensitivity curve V(λ) is utilized as the dominant portion of white light spectra. Emission spectra of a blue InGaN light-emitting diode (LED) and a red AlInGaP LED are added to the spectrum of V(λ) to match white color coordinates. It is demonstrated that at the condition of color temperature from 2500 K to 6500 K and CRI above 90, such white sources can achieve spectral efficacy of 330–390 lm/W, which is higher than the previously reportedmore » theoretical maximum values. We show that this eye-sensitivity-based approach also has advantages on component energy conversion efficiency compared with previously reported optimization solutions.« less

Spectroscopic identification of individual fluorophores using photoluminescence excitation spectra.

PubMed

Czerski, J; Colomb, W; Cannataro, F; Sarkar, S K

2018-01-25

The identity of a fluorophore can be ambiguous if other fluorophores or nonspecific fluorescent impurities have overlapping emission spectra. The presence of overlapping spectra makes it difficult to differentiate fluorescent species using discrete detection channels and unmixing of spectra. The unique absorption and emission signatures of fluorophores provide an opportunity for spectroscopic identification. However, absorption spectroscopy may be affected by scattering, whereas fluorescence emission spectroscopy suffers from signal loss by gratings or other dispersive optics. Photoluminescence excitation spectra, where excitation is varied and emission is detected at a fixed wavelength, allows hyperspectral imaging with a single emission filter for high signal-to-background ratio without any moving optics on the emission side. We report a high throughput method for measuring the photoluminescence excitation spectra of individual fluorophores using a tunable supercontinuum laser and prism-type total internal reflection fluorescence microscope. We used the system to measure and sort the photoluminescence excitation spectra of individual Alexa dyes, fluorescent nanodiamonds (FNDs), and fluorescent polystyrene beads. We used a Gaussian mixture model with maximum likelihood estimation to objectively separate the spectra. Finally, we spectroscopically identified different species of fluorescent nanodiamonds with overlapping spectra and characterized the heterogeneity of fluorescent nanodiamonds of varying size. © 2018 The Authors Journal of Microscopy © 2018 Royal Microscopical Society.

Use of borated polyethylene to improve low energy response of a prompt gamma based neutron dosimeter

NASA Astrophysics Data System (ADS)

Priyada, P.; Ashwini, U.; Sarkar, P. K.

2016-05-01

The feasibility of using a combined sample of borated polyethylene and normal polyethylene to estimate neutron ambient dose equivalent from measured prompt gamma emissions is investigated theoretically to demonstrate improvements in low energy neutron dose response compared to only polyethylene. Monte Carlo simulations have been carried out using the FLUKA code to calculate the response of boron, hydrogen and carbon prompt gamma emissions to mono energetic neutrons. The weighted least square method is employed to arrive at the best linear combination of these responses that approximates the ICRP fluence to dose conversion coefficients well in the energy range of 10-8 MeV to 14 MeV. The configuration of the combined system is optimized through FLUKA simulations. The proposed method is validated theoretically with five different workplace neutron spectra with satisfactory outcome.

The effect of MgO on the optical properties of lithium sodium borate doped with Cu+ ions

NASA Astrophysics Data System (ADS)

Alajerami, Yasser Saleh Mustafa; Hashim, Suhairul; Hassan, Wan Muhamad Saridan Wan; Ramli, Ahmad Termizi; Saleh, Muneer Aziz

2013-04-01

The current work presented the photoluminescence (PL) properties of a new glass system, which are reported for the first time. Based on the attractive properties of borate glass, a mixture of boric acid (70-x mol %) modified with lithium (20 mol %) and sodium carbonate (10 mol %) was prepared. The current study illustrated the effect of dopant and co-dopant techniques on the lithium sodium borate (LNB). Firstly, 0.1 mol % of copper ions doped with LNB was excited at 610 nm. The emission spectrum showed two prominent peaks in the violet region (403 and 440 nm). Then, we remarked the effect of adding different concentration of MgO on the optical properties of LNB. The results showed the great effect of magnesium oxide on the PL intensities (enhanced more than two times). Moreover, an obvious shifting has been defined toward the blue region (440 → 475 nm). The up-conversion optical properties were observed in all emission spectra. This enhancement is contributed to the energy transfer from MgO ions to monovalent Cu+ ion. It is well known that magnesium oxide alone generates weak emission intensity, but during this increment the MgO act as an activator (co-doped) for Cu+ ions. Finally, energy band gap, density, ion concentration, molar volume, Polaron radius and inter-nuclear distance all were measured for the current samples. The current samples were subjected to XRD for amorphous confirmation and IR for glass characterization before and after dopants addition. Finally, some of significant physical and optical parameters were also calculated.

A top-down method to fabricate SrAl2O4:Eu2+,Dy3+ nanosheets from commercial blocky phosphors

NASA Astrophysics Data System (ADS)

Zhang, Haoran; Xue, Zhiping; Lei, Bingfu; Dong, Hanwu; Zhang, Haiming; Deng, Suqing; Zheng, Mingtao; Liu, Yingliang; Xiao, Yong

2014-09-01

By using commercial SrAl2O4:Eu2+,Dy3+ phosphor as raw material, we have developed a novel and simple top-down method to fabricate SrAl2O4:Eu2+,Dy3+ nanosheets that are useful for potential practical applications, especially as fluorescent labels for biomolecules and mechano-optical nano-devices. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX) results demonstrate that the treated samples are still pure-phase of SrAl2O4:Eu2+,Dy3+. The field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) results indicate that the treated SrAl2O4:Eu2+,Dy3+ phosphors are built up by nanosheets bundles. Excitation and emission spectra, afterglow emission spectra and decay curves are used to analyze the luminescence properties of SrAl2O4:Eu2+,Dy3+ nanosheets, and the results show that, compared with commercial samples, the treated samples show similar spectra characteristic including the spectra shapes and the band position. Furthermore, the fluorescence and afterglow intensity of SrAl2O4:Eu2+,Dy3+ nanosheets can be tuned linearly by changing the circumstance temperatures, which further indicates its potential applications in fiber-optical thermometer materials.

Line Emission and X-ray Line Polarization of Multiply Ionized Mo Ions

NASA Astrophysics Data System (ADS)

Petkov, E. E.; Safronova, A. S.; Kantsyrev, V. L.; Shlyaptseva, V. V.; Stafford, A.; Safronova, U. I.; Shrestha, I. K.; Schultz, K. A.; Childers, R.; Cooper, M. C.; Beiersdorfer, P.; Hell, N.; Brown, G. V.

2016-10-01

We present a comprehensive experimental and theoretical study of the line emission from multiply ionized Mo ions produced by two different sets of experiments: at LLNL EBIT and the pulsed power generator Zebra at UNR. Mo line emission and polarization measurements were accomplished at EBIT for the first time. In particular, benchmarking experiments at the LLNL EBIT with Mo ions produced at electron beam energies from 2.75 keV up to 15 keV allowed us to break down these very complicated spectra into spectra with only few ionization stages and to select processes that influence them as well as to measure line polarization. The EBIT data were recorded using the EBIT Calorimeter Spectrometer and a crystal spectrometer with a Ge crystal. X-ray Mo spectra and pinhole images were collected from Z-pinch plasmas produced from various wire loads. Non-LTE modeling, high-precision relativistic atomic and polarization data were used to analyze L-shell Mo spectra. The influence of different plasma processes including electron beams on Mo line radiation is summarized. This work was supported by NNSA under DOE Grant DE-NA0002954. Experiments at the NTF/UNR were funded in part by DE-NA0002075. Work at LLNL was performed under the auspices of the U.S. DOE under contract DE-AC52-07NA27344.

Waste wood as bioenergy feedstock. Climate change impacts and related emission uncertainties from waste wood based energy systems in the UK.

PubMed

Röder, Mirjam; Thornley, Patricia

2018-04-01

Considering the urgent need to shift to low carbon energy carriers, waste wood resources could provide an alternative energy feedstock and at the same time reduce emissions from landfill. This research examines the climate change impacts and related emission uncertainties of waste wood based energy. For this, different grades of waste wood and energy application have been investigated using lifecycle assessment. Sensitivity analysis has then been applied for supply chain processes and feedstock properties for the main emission contributing categories: transport, processing, pelletizing, urea resin fraction and related N 2 O formation. The results show, depending on the waste wood grade, the conversion option, scale and the related reference case, that emission reductions of up to 91% are possible for non-treated wood waste. Compared to this, energy from treated wood waste with low contamination can achieve up to 83% emission savings, similar to untreated waste wood pellets, but in some cases emissions from waste wood based energy can exceed the ones of the fossil fuel reference - in the worst case by 126%. Emission reductions from highly contaminated feedstocks are largest when replacing electricity from large-scale coal and landfill. The highest emission uncertainties are related to the wood's resin fraction and N 2 O formation during combustion and, pelletizing. Comparing wood processing with diesel and electricity powered equipment also generated high variations in the results, while emission variations related to transport are relatively small. Using treated waste wood as a bioenergy feedstock can be a valid option to reduce emissions from energy production but this is only realisable if coal and landfill gas are replaced. To achieve meaningful emission reduction in line with national and international climate change targets, pre-treatment of waste wood would be required to reduce components that form N 2 O during the energy conversion. Copyright © 2017 Elsevier Ltd. All rights reserved.

Simulation of the A-X and B-X transition emission spectra of the InBr molecule for diagnostics in low-pressure plasmas

NASA Astrophysics Data System (ADS)

Briefi, S.; Fantz, U.

2011-04-01

Inductively coupled low-pressure discharges containing InBr have been investigated spectroscopically. In order to obtain plasma parameters such as the vibrational and rotational temperature of the InBr molecule, the emission spectra of the A\\,^3\\!\\Pi_{0^+}\\rightarrow X\\,^1\\!\\Sigma_{0}^+ and the B\\,^3\\! \\Pi_{1}\\rightarrow X\\,^1\\!\\Sigma_{0}^+ transitions have been simulated. The program is based on the molecular constants and takes into account vibrational states up to v = 24. The required Franck-Condon factors and vibrationally resolved transition probabilities have been computed solving the Schrödinger equation using the Born-Oppenheimer approximation. The ground state density of the InBr molecule in the plasma has been determined from absorption spectra using effective transition probabilities for the A-X and B-X transition according to the vibrational population. The obtained densities agree well with densities derived from an Arrhenius type vapour pressure equation.

Directional emissivity and reflectance: dependence on emergence angle

NASA Astrophysics Data System (ADS)

Maturilli, Alessandro; Helbert, Jörn

2017-04-01

Dependence of laboratory measured emissivity spectra from the emergence angle is a subject that still needs a lot of investigations to be fully understood. Most of the previous work is based on reflectance measurements in the VIS-NIR spectral region and on emissivity measurements of flat, solid surfaces (mainly metals), which are not directly applicable to the analysis of remote sensing data. Small bodies in particular (c.f. asteroids Itokawa and 1999JU3, the respective targets of JAXA Hayabusa and Hayabusa 2 missions) have a very irregular surface; hence the spectra from those rough surfaces are difficult to compare with laboratory spectra, where the observing geometry is always close to "nadir". At the Planetary Emissivity Laboratory (PEL) of the German Aerospace Center (DLR) we have set-up a series of spectral measurements to investigate this problem in the 1 - 16 µm spectral region. We measured the emissivity for two asteroid analog materials (meteorite Millbillillie and a synthetic enstatite) in vacuum and under purged air, at surface temperature of 100°C, for emergence angles of 0°, 5°, 10°, 20°, 30°, 40°, 50°, and 60°. Emissivity of a serpentinite slab, already used as calibration target for the MARA instrument on Hayabusa 2 MASCOT lander, and for the Thermal Infrared Imager (TIR) spectrometer on Hayabusa 2 orbiter was measured under the same conditions. Additionally a second basalt slab was measured. Both slabs were not measured at 5° inclination. Complementary reflectance measurements of the four samples were taken. For all the samples measured, we found that for calibrated emissivity, significant variations from values obtained at nadir (0° emergence angle) appear only for emergence angles ≥ 40°. Reflectance measurements confirmed this finding, showing the same trend of variations.

Detection of iron atoms by emission spectroscopy and laser-induced fluorescence in solid propellant flames.

PubMed

Vilmart, G; Dorval, N; Orain, M; Lambert, D; Devillers, R; Fabignon, Y; Attal-Tretout, B; Bresson, A

2018-05-10

Planar laser-induced fluorescence on atomic iron is investigated in this paper, and a measurement strategy is proposed to monitor the fluorescence of iron atoms with good sensitivity. A model is proposed to fit the experimental fluorescence spectra, and good agreement is found between simulated and experimental spectra. Emission and laser-induced fluorescence measurements are performed in the flames of ammonium perchlorate composite propellants containing iron-based catalysts. A fluorescence signal from iron atoms after excitation at 248 nm is observed for the first time in propellant flames. Images of the spatial distribution of iron atoms are recorded in the flame in which turbulent structures are generated. Iron fluorescence is detected up to 1.0 MPa, which opens the way to application in propellant combustion.

Design and spectrum calculation of 4H-SiC thermal neutron detectors using FLUKA and TCAD

NASA Astrophysics Data System (ADS)

Huang, Haili; Tang, Xiaoyan; Guo, Hui; Zhang, Yimen; Zhang, Yimeng; Zhang, Yuming

2016-10-01

SiC is a promising material for neutron detection in a harsh environment due to its wide band gap, high displacement threshold energy and high thermal conductivity. To increase the detection efficiency of SiC, a converter such as 6LiF or 10B is introduced. In this paper, pulse-height spectra of a PIN diode with a 6LiF conversion layer exposed to thermal neutrons (0.026 eV) are calculated using TCAD and Monte Carlo simulations. First, the conversion efficiency of a thermal neutron with respect to the thickness of 6LiF was calculated by using a FLUKA code, and a maximal efficiency of approximately 5% was achieved. Next, the energy distributions of both 3H and α induced by the 6LiF reaction according to different ranges of emission angle are analyzed. Subsequently, transient pulses generated by the bombardment of single 3H or α-particles are calculated. Finally, pulse height spectra are obtained with a detector efficiency of 4.53%. Comparisons of the simulated result with the experimental data are also presented, and the calculated spectrum shows an acceptable similarity to the experimental data. This work would be useful for radiation-sensing applications, especially for SiC detector design.

40 CFR Appendix B to Part 72 - Methodology for Conversion of Emissions Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Methodology for Conversion of... Conversion of Emissions Limits For the purposes of the Acid Rain Program, all emissions limits must be... conditions. Generic conversions for these limits are based on the assumed average energy contents listed in...

40 CFR Appendix B to Part 72 - Methodology for Conversion of Emissions Limits

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Methodology for Conversion of... Conversion of Emissions Limits For the purposes of the Acid Rain Program, all emissions limits must be... conditions. Generic conversions for these limits are based on the assumed average energy contents listed in...

Laser-induced down-conversion and infrared phosphorescence emissivity of novel ligand-free perovskite nanomaterials

NASA Astrophysics Data System (ADS)

Ahmed, M. A.; Khafagy, Rasha M.; El-sayed, O.

2014-03-01

For the first time, standalone and ligand-free series of novel rare-earth-based perovskite nanomaterials are used as near infrared (NIR) and mid infrared (MIR) emitters. Nano-sized La0.7Sr0.3M0.1Fe0.9O3; where M = 0, Mn2+, Co2+ or Ni2+ were synthesized using the flash auto-combustion method and characterized using FTIR, FT-Raman, SEM and EDX. Photoluminescence spectra were spontaneously recorded during pumping the samples with 0.5 mW of green laser emitting continuously at 532 nm. La0.7Sr0.3FeO3 (where M = 0) did not result in any infrared emissivity, while intense near and mid infrared down-converted phosphorescence was released from the M-doped samples. The released phosphorescence greatly shifted among the infrared spectral region with changing the doping cation. Ni2+-doped perovskite emitted at the short-wavelength near-infrared region, while Mn2+ and Co2+-doped perovskites emitted at the mid-wavelength infrared region. The detected laser-induced spontaneous parametric down-conversion phosphorescence (SPDC) occurred through a two-photon process by emitting two NIR or MIR photons among a cooperative energy transfer between the La3+ cations and the M2+ cations. Combining SrFeO3 ceramic with both a rare earth cation (RE3+) and a transition metal cation (Mn2+, Co2+ or Ni2+), rather than introducing merely RE3+ cations, greatly improved and controlled the infrared emissivity properties of synthesized perovskites through destroying their crystal symmetry and giving rise to asymmetrical lattice vibration and the nonlinear optical character. The existence of SPDC in the M2+-doped samples verifies their nonlinear character after the absence of this character in La0.7Sr0.3FeO3. Obtained results verify that, for the first time, perovskite nanomaterials are considered as nonlinear optical crystals with intense infrared emissivity at low pumping power of visible wavelengths, which nominates them for photonic applications and requires further studies regarding their lasing ability as laser active components. Such a single infrared-emitting-perovskite nanomaterial replaced, for the first time, the need for a polymeric ligand, which was a routine approach in such an application. Also, it avoided the complicated synthesis of organic-inorganic hybrids, prevented wide spectral-range emissions usually produced by polymers, facilitated obtaining near-infrared emission spectra within certain limits of wavelengths, and is considered as a new approach for fabricating a standalone perovskite nanomaterial for phosphorescent optoelectronic components and military uses.

On the response of Y 3Al 5O 12: Ce (YAG: Ce) powder scintillating screens to medical imaging X-rays

NASA Astrophysics Data System (ADS)

Kandarakis, I.; Cavouras, D.; Sianoudis, I.; Nikolopoulos, D.; Episkopakis, A.; Linardatos, D.; Margetis, D.; Nirgianaki, E.; Roussou, M.; Melissaropoulos, P.; Kalivas, N.; Kalatzis, I.; Kourkoutas, K.; Dimitropoulos, N.; Louizi, A.; Nomicos, C.; Panayiotakis, G.

2005-02-01

The aim of this study was to examine Y 3Al 5O 12:Ce (also known as YAG:Ce) powder scintillator under X-ray imaging conditions. This material shows a very fast scintillation decay time and it has never been used in X-ray medical imaging. In the present study various scintillator layers (screens) with coating thickness ranging from 13 to 166 mg/cm 2 were prepared in our laboratory by sedimentation of Y 3Al 5O 12: Ce powder. Optical emission spectra and light emission efficiency (spectrum area over X-ray exposure) of the layers were measured under X-ray excitation using X-ray tube voltages (80-120 kVp) often employed in general medical radiography and fluoroscopy. Spectral compatibility with various optical photon detectors (photodiodes, photocathodes, charge coupled devices, films) and intrinsic conversion efficiency values were determined using emission spectrum data. In addition, parameters related to X-ray detection, energy absorption efficiency and K-fluorescence characteristic emission were calculated. A theoretical model describing radiation and light transfer through scattering media was used to fit experimental data. Intrinsic conversion efficiency (η≈0.03-0.05) and light attenuation coefficients (σ≈26.5 cm/g) were derived through this fitting. Y 3Al 5O 12:Ce showed peak emission in the wavelength range 530-550 nm. The light emission efficiency was found to be maximum for the 107 mg/cm 2 layer. Due to its "green" emission spectrum, Y 3Al 5O 12:Ce showed excellent compatibility (of the order of 0.9) with the sensitivity of many currently used photodetectors. Taking into account its very fast response Y 3Al 5O 12:Ce could be considered for application in X-ray imaging especially in various digital detectors.

Infrared reflectance spectra (4-12 micron) of lunar samples

NASA Technical Reports Server (NTRS)

Nash, Douglas B.

1991-01-01

Presented here are infrared reflectance spectra of a typical set of Apollo samples to illustrate spectral character in the mid-infrared (4 to 12 microns) of lunar materials and how the spectra varies among three main forms: soil, breccia, and igneous rocks. Reflectance data, to a close approximation, are the inverse of emission spectra; thus, for a given material the spectral reflectance (R) at any given wavelength is related to emission (E) by 1 - R equals E. Therefore, one can use reflectance spectra of lunar samples to predict how emission spectra of material on the lunar surface will appear to spectrometers on orbiting spacecraft or earthbound telescopes. Spectra were measured in the lab in dry air using a Fourier Transform Infrared spectrometer. Shown here is only the key portion (4 to 12 microns) of each spectrum relating to the principal spectral emission region for sunlit lunar materials and to where the most diagnostic spectral features occur.

Stability study of PbSe semiconductor nanocrystals over concentration, size, atmosphere, and light exposure.

PubMed

Dai, Quanqin; Wang, Yingnan; Zhang, Yu; Li, Xinbi; Li, Ruowang; Zou, Bo; Seo, JaeTae; Wang, Yiding; Liu, Manhong; Yu, William W

2009-10-20

Infrared-emitting PbSe nanocrystals are of increasing interest in both fundamental research and technical application. However, the practical applications are greatly limited by their poor stability. In this work, absorption and photoluminescence spectra of PbSe nanocrystals were utilized to observe the stability of PbSe nanocrystals over several conventional factors, that is, particle concentration, particle size, temperature, light exposure, contacting atmosphere, and storage forms (solution or solid powder). Both absorption and luminescence spectra of PbSe nanocrystals exposed to air showed dependence on particle concentration, size, and light exposure, which caused large and quick blue-shifts in the optical spectra. This air-contacted instability arising from the destructive oxidation and subsequent collision-induced decomposition was kinetically dominated and differed from the traditional thought that smaller particles with lower concentrations shrank fast. The photoluminescence emission intensity of the PbSe nanocrystal solution under ultraviolet (UV) exposure in air increased first and then decreased slowly; without UV irradiation, the emission intensity monotonously decreased over time. However, if stored under nitrogen, no obvious changes in absorption and photoluminescence spectra of the PbSe nanocrystals were observed even under UV exposure or upon being heated up to 100 degrees C.

PHOTOSPHERE EMISSION FROM A HYBRID RELATIVISTIC OUTFLOW WITH ARBITRARY DIMENSIONLESS ENTROPY AND MAGNETIZATION IN GRBs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, He; Zhang, Bing, E-mail: gaohe@physics.unlv.edu, E-mail: zhang@physics.unlv.edu, E-mail: hug18@psu.edu

2015-03-10

In view of the recent Fermi observations of gamma-ray burst (GRB) prompt emission spectra, we develop a theory of photosphere emission of a hybrid relativistic outflow with a hot fireball component (defined by dimensionless entropy η) and a cold Poynting-flux component (defined by magnetization σ{sub 0} at the central engine). We consider the scenarios both without and with sub-photospheric magnetic dissipations. Based on a simplified toy model of jet dynamics, we develop two approaches: a 'bottom-up' approach to predict the temperature (for a non-dissipative photosphere) and luminosity of the photosphere emission and its relative brightness for a given pair ofmore » (η, σ{sub 0}); and a 'top-down' approach to diagnose central engine parameters (η and σ{sub 0}) based on the observed quasi-thermal photosphere emission properties. We show that a variety of observed GRB prompt emission spectra with different degrees of photosphere thermal emission can be reproduced by varying η and σ{sub 0} within the non-dissipative photosphere scenario. In order to reproduce the observed spectra, the outflows of most GRBs need to have a significant σ, both at the central engine and at the photosphere. The σ value at 10{sup 15} cm from the central engine (a possible non-thermal emission site) is usually also greater than unity, so that internal-collision-induced magnetic reconnection and turbulence (ICMART) may be the mechanism to power the non-thermal emission. We apply our top-down approach to GRB 110721A and find that the temporal evolution behavior of its blackbody component can be well interpreted with a time-varying (η, σ{sub 0}) at the central engine, instead of invoking a varying engine base size r {sub 0} as proposed by previous authors.« less

Spectra of clinical CT scanners using a portable Compton spectrometer.

PubMed

Duisterwinkel, H A; van Abbema, J K; van Goethem, M J; Kawachimaru, R; Paganini, L; van der Graaf, E R; Brandenburg, S

2015-04-01

Spectral information of the output of x-ray tubes in (dual source) computer tomography (CT) scanners can be used to improve the conversion of CT numbers to proton stopping power and can be used to advantage in CT scanner quality assurance. The purpose of this study is to design, validate, and apply a compact portable Compton spectrometer that was constructed to accurately measure x-ray spectra of CT scanners. In the design of the Compton spectrometer, the shielding materials were carefully chosen and positioned to reduce background by x-ray fluorescence from the materials used. The spectrum of Compton scattered x-rays alters from the original source spectrum due to various physical processes. Reconstruction of the original x-ray spectrum from the Compton scattered spectrum is based on Monte Carlo simulations of the processes involved. This reconstruction is validated by comparing directly and indirectly measured spectra of a mobile x-ray tube. The Compton spectrometer is assessed in a clinical setting by measuring x-ray spectra at various tube voltages of three different medical CT scanner x-ray tubes. The directly and indirectly measured spectra are in good agreement (their ratio being 0.99) thereby validating the reconstruction method. The measured spectra of the medical CT scanners are consistent with theoretical spectra and spectra obtained from the x-ray tube manufacturer. A Compton spectrometer has been successfully designed, constructed, validated, and applied in the measurement of x-ray spectra of CT scanners. These measurements show that our compact Compton spectrometer can be rapidly set-up using the alignment lasers of the CT scanner, thereby enabling its use in commissioning, troubleshooting, and, e.g., annual performance check-ups of CT scanners.

Surface chemistry and density distribution influence on visible luminescence of silicon quantum dots: an experimental and theoretical approach.

PubMed

Dutt, Ateet; Matsumoto, Yasuhiro; Santana-Rodríguez, G; Ramos, Estrella; Monroy, B Marel; Santoyo Salazar, J

2017-01-04

The impact of the surface reconstruction of the density distribution and photoluminescence of silicon quantum dots (QDs) embedded in a silicon oxide matrix (SiO x ) has been studied. Annealing treatments carried out on the as-deposited samples provoked the effusion of hydrogen species. Moreover, depending on the surrounding density and coalescence of QDs, they resulted in a change in the average size of the particles depending on the initial local environment. The shift in the luminescence spectra all over the visible region (blue, green and red) shows a strong dependence on the resultant change in the size and/or the passivation environment of QDs. Density functional theoretical (DFT) calculations support this fact and explain the possible electronic transitions (HOMO-LUMO gap) involved. Passivation in the presence of oxygen species lowers the band gap of Si 29 and Si 35 nanoclusters up to 1.7 eV, whereas, surface passivation in the environment of hydrogen species increases the band gap up to 4.4 eV. These results show a good agreement with the quantum confinement model described in this work and explain the shift in the luminescence all over the visible region. The results reported here offer vital insight into the mechanism of emission from silicon quantum dots which has been one of the most debated topics in the last two decades. QDs with multiple size distribution in different local environments (band gap) observed in this work could be used for the fabrication of light emission diodes (LEDs) or shift-conversion thin films in third generation efficient tandem solar cells for the maximum absorption of the solar spectrum in different wavelength regions.

PM2.5 ORGANIC COMPOSITION FROM SEVERAL SITES IN THE UNITED STATES

EPA Science Inventory

Organic constituents make up an important component of fine particulate matter (PM2.5) in ambient environments. While part of the composition of organic aerosol results from emissions of primary sources, an additional component appears to come from gas-to-particle conversion o...

Spectra- and temperature-dependent dynamics of directly end-pumped holmium lasers

NASA Astrophysics Data System (ADS)

Ji, Encai; Shen, Yijie; Nie, Mingming; Fu, Xing; Liu, Qiang

2017-04-01

We develop a theoretical model with high accuracy for directly end-pumped Ho3+ laser system considering the influences of ground-state depletion, energy transfer up-conversion, temperature-dependent cross sections, and pump spectra shift. The heat generation in our model is precisely evaluated by calculating the transition rates of non-radiation relaxation processes among manifolds and in-band relaxation processes based on a detailed analysis of energy levels structure of holmium ions. A spatial dynamic thermal iteration method, just developed by our group, is applied to describe the coupled influences between spatial thermal effects and pump spectra. This model is verified to both adapt to the narrow-band good beam-quality pumped case and the broad-band bad beam-quality pumped case, which is in accordance with our previous reported experimental results.

Spitzer Observations of Dust Destruction in the Puppis A Supernova Remnant

NASA Technical Reports Server (NTRS)

Arendt, Richard G.; Dwek, Eli,; Blair, William P.; Ghavamian, Parviz; Long, Knox S.

2010-01-01

Imaging and spectral observations of the Puppis A supernova remnant (SNR) with the Spitzer Space Telescope confirm that its IR emission is dominated by the thermal continuum emission of swept-up interstellar dust which is collisionally heated by the X-ray emitting gas of the SNR. Line emission is too weak to affect the fluxes measured in broadband observations, and is poorly correlated with the IR or X-ray emission. Modeling of spectra from regions both in the SNR and in the associated ISM show that the ubiquitous polycyclic aromatic hydrocarbons (PAHs) of the ISM are destroyed within the SNR, along with nearly 25% of the mass of graphite and silicate dust grains.

BRIEF COMMUNICATION: Calculation of a magnetic field effect on emission spectra of light diatomic molecules for diagnostic application to fusion edge plasmas

NASA Astrophysics Data System (ADS)

Shikama, T.; Fujii, K.; Mizushiri, K.; Hasuo, M.; Kado, S.; Zushi, H.

2009-12-01

A scheme for computation of emission spectra of light diatomic molecules under external magnetic and electric fields is presented. As model species in fusion edge plasmas, the scheme is applied to polarization-resolved emission spectra of H2, CH, C2, BH and BeH molecules. The possibility of performing spatially resolved measurements of these spectra is examined.

Optical properties of Nd3+ doped bismuth zinc borate glasses

NASA Astrophysics Data System (ADS)

Shanmugavelu, B.; Venkatramu, V.; Ravi Kanth Kumar, V. V.

2014-03-01

Glasses with compositions of (100-x) (Bi2ZnOB2O6) - x Nd2O3 (where x = 0.1, 0.3, 0.5, 1 and 2 mol%) were prepared by melt quenching method and characterized through optical absorption, emission and decay curve measurements. Optical absorption spectra have been analyzed using Judd-Ofelt theory. The emission spectra exhibit three peaks at 919, 1063 and 1337 nm corresponding to 4F3/2 to 4I9/2, 4I11/2 and 4I13/2 transitions in the near infrared region. The emission intensity of the 4F3/2 to 4I11/2 transition increases with increase of Nd3+ concentration up to 1 mol% and then concentration quenching is observed for 2 mol% of Nd3+ concentration. The lifetimes for the 4F3/2 level are found to decrease with increase in Nd2O3 concentration in the glasses. The decay curves of the glass up to 0.3 mol% of Nd3+ exhibit single exponential nature and thereafter the curves become nonexponential nature (0.5, 1 and 2 mol%). The nonexponential curve has been fitted to the Inokuti-Hirayama model to understand the nature of energy transfer process.

Optical properties of Nd3+ doped bismuth zinc borate glasses.

PubMed

Shanmugavelu, B; Venkatramu, V; Ravi Kanth Kumar, V V

2014-03-25

Glasses with compositions of (100-x) (Bi2ZnOB2O6) -x Nd2O3 (where x=0.1, 0.3, 0.5, 1 and 2 mol%) were prepared by melt quenching method and characterized through optical absorption, emission and decay curve measurements. Optical absorption spectra have been analyzed using Judd-Ofelt theory. The emission spectra exhibit three peaks at 919, 1063 and 1337 nm corresponding to (4)F3/2 to (4)I9/2, (4)I11/2 and (4)I13/2 transitions in the near infrared region. The emission intensity of the (4)F3/2 to (4)I11/2 transition increases with increase of Nd(3+) concentration up to 1 mol% and then concentration quenching is observed for 2 mol% of Nd(3+) concentration. The lifetimes for the (4)F3/2 level are found to decrease with increase in Nd2O3 concentration in the glasses. The decay curves of the glass up to 0.3 mol% of Nd(3+) exhibit single exponential nature and thereafter the curves become nonexponential nature (0.5, 1 and 2 mol%). The nonexponential curve has been fitted to the Inokuti-Hirayama model to understand the nature of energy transfer process. Copyright © 2013 Elsevier B.V. All rights reserved.

Host sensitized near-infrared emission in Nd3+ doped different alkaline-sodium-phosphate phosphors

NASA Astrophysics Data System (ADS)

Balakrishna, A.; Swart, H. C.; Kroon, R. E.; Ntwaeaborwa, O. M.

2018-04-01

Near-infrared (NIR) emitting phosphors of different alkaline based sodium-phosphate (MNa[PO4], where M = Mg, Ca, Sr and Ba were prepared by a conventional solution combustion method with fixed doping concentration of Nd3+ (1.0 mol%). The phosphors were characterized by powder X-ray diffraction, field emission scanning electron microscope, Fourier transform infrared spectroscopy, UV-vis spectroscopy and fluorescent spectrophotometry. The optical properties including reflectance, excitation and emission were investigated. The excitation spectra of the phosphors were characterized by a broadband extending from 450 to 900 nm. Upon excitation with a wavelength of 580 nm, the phosphor emits intensely infrared region at 872 nm, 1060 nm and 1325 nm which correspond to the 4F3/2 → 4I9/2, 4F3/2 → 4I11/2 and 4F3/2 → 4I13/2 transitions of Nd3+ ions and were found to vary for the different hosts. The strongest emission wavelength reaches 1060 nm. The most intense emission of Nd3+ was observed from Ca2+ incorporated host. The down conversion emissions of the material fall in the NIR region suggesting that the prepared phosphors have potential application in the development of photonic devices emitting in the NIR.

A comparative evaluation on the emission characteristics of ceramic and metallic catalytic converter in internal combustion engine

NASA Astrophysics Data System (ADS)

Leman, A. M.; Jajuli, Afiqah; Rahman, Fakhrurrazi; Feriyanto, Dafit; Zakaria, Supaat

2017-09-01

Enforcement of a stricter regulation on exhaust emission by many countries has led to utilization of catalytic converter to reduce the harmful pollutant emission. Ceramic and metallic catalytic converters are the most common type of catalytic converter used. The purpose of this study is to evaluate the performance of the ceramic and metallic catalytic converter on its conversion efficiency using experimental measurement. Both catalysts were placed on a modified exhaust system equipped with a Mitshubishi 4G93 single cylinder petrol engine that was tested on an eddy current dynamometer under steady state conditions for several engine speeds. The experimental results show that the metallic catalytic converter reduced a higher percentage of CO up to 98.6% reduction emissions while ceramic catalytic converter had a better reduction efficiency of HC up to 85.4% and 87.2% reduction of NOx.

Injection-insensitive lateral divergence in broad-area diode lasers achieved by spatial current modulation

NASA Astrophysics Data System (ADS)

Wang, Tao; Tong, Cunzhu; Wang, Lijie; Zeng, Yugang; Tian, Sicong; Shu, Shili; Zhang, Jian; Wang, Lijun

2016-11-01

High-power broad-area (BA) diode lasers often suffer from low beam quality, broad linewidth, and a widened slow-axis far field with increasing current. In this paper, a two-dimensional current-modulated structure is proposed and it is demonstrated that it can reduce not only the far-field sensitivity to the injection current but also the linewidth of the lasing spectra. Injection-insensitive lateral divergence was realized, and the beam parameter product (BPP) was improved by 36.5%. At the same time, the linewidth was decreased by about 45% without significant degradations of emission power and conversion efficiency.

Emission and reflection spectra from AlxGa1-xN/GaN single heterostructures

NASA Astrophysics Data System (ADS)

Reynolds, D. C.; Hoelscher, J.; Litton, C. W.; Collins, T. C.; Fitch, R.; Via, G. D.; Gillespie, J.; Crespo, A.; Jenkins, T. J.; Saxler, A.

2003-10-01

Emission and reflection spectra from AlGaN/GaN single heterostructures grown on SiC substrates were investigated. Two-dimensional electron gas (2DEG) transitions were observed in both emission and reflection. The transitions are sharp, associated with the excited state of the 2DEG, reflect the conservation of the K-selection rule, and are excitonlike. The transitions are also associated with both the A- and B-valence bands. To verify the origin of the reflection and emission spectra, the top AlGaN layer was removed by reactive ion etching. After etching, only the excitonic reflection and emission spectra associated with GaN were observed.

Evolution of synchrotron-radiation-based Mössbauer absorption spectroscopy for various isotopes

NASA Astrophysics Data System (ADS)

Seto, Makoto; Masuda, Ryo; Kobayashi, Yasuhiro; Kitao, Shinji; Kurokuzu, Masayuki; Saito, Makina; Hosokawa, Shuuich; Ishibashi, Hiroki; Mitsui, Takaya; Yoda, Yoshitaka; Mibu, Ko

2017-11-01

Synchrotron-radiation-based Mössbauer spectroscopy that yields absorption type Mössbauer spectra has been applied to various isotopes. This method enables the advanced measurement by using the excellent features of synchrotron radiation, such as Mössbauer spectroscopic measurement under high-pressures. Furthermore, energy selectivity of synchrotron radiation allows us to measure 40K Mössbauer spectra, of which observation is impossible by using ordinary radioactive sources because the first excited state of 40K is not populated by any radioactive parent nuclides. Moreover, this method has flexibility of the experimental setup that the measured sample can be used as a transmitter or a scatterer, depending on the sample conditions. To enhance the measurement efficiency of the spectroscopy, we developed a detection system in which a windowless avalanche photodiode (APD) detector is combined with a vacuum cryostat to detect internal conversion electrons adding to X-rays accompanied by nuclear de-excitation. In particular, by selecting the emission from the scatterer sample, depth selective synchrotron-radiation-based Mössbauer spectroscopy is possible. Furthermore, limitation of the time window in the delayed components enables us to obtain narrow linewidth in Mössbauer spectra. Measurement system that records velocity dependent time spectra and energy information simultaneously realizes the depth selective and narrow linewidth measurement.

Fluorescence of sanguinarine: fundamental characteristics and analysis of interconversion between various forms.

PubMed

Janovská, Marika; Kubala, Martin; Simánek, Vilím; Ulrichová, Jitka

2009-09-01

The quaternary isoquinoline alkaloid, sanguinarine (SG) plays an important role in both traditional and modern medicine, exhibiting a wide range of biological activities. Under physiological conditions, there is an equilibrium between the quaternary cation (SG+) and a pseudobase (SGOH) forms of SG. In the gastrointestinal tract, SG is converted to dihydrosanguinarine (DHSG). All forms exhibit bright fluorescence. However, their spectra overlap, which limited the use of powerful techniques based on fluorescence spectroscopy/microscopy. Our experiments using a combination of steady-state and time-resolved techniques enabled the separation of individual components. The results revealed that (a) the equilibrium constant between SG+ and SGOH is pKa = 8.06, while fluorescence of DHSG exhibited no changes in the pH range 5-12, (b) the SGOH has excitation/emission spectra with maxima at 327/418 nm and excited-state lifetime 3.2 ns, the spectra of the SG+ have maxima at 475/590 nm and excited-state lifetime 2.4 ns. The DHSG spectra have maxima at 327/446 nm and 2-exponential decay with components 4.2 and 2.0 ns, (c) NADH is able to convert SG to DHSG, while there is no apparent interaction between NADH and DHSG. These techniques are applicable for monitoring the SG to DHSG conversion in hepatocytes.

Single component Mn-doped perovskite-related CsPb2ClxBr5-x nanoplatelets with a record white light quantum yield of 49%: a new single layer color conversion material for light-emitting diodes.

PubMed

Wu, Hao; Xu, Shuhong; Shao, Haibao; Li, Lang; Cui, Yiping; Wang, Chunlei

2017-11-09

Single component nanocrystals (NCs) with white fluorescence are promising single layer color conversion media for white light-emitting diodes (LED) because the undesirable changes of chromaticity coordinates for the mixture of blue, green and red emitting NCs can be avoided. However, their practical applications have been hindered by the relative low photoluminescence (PL) quantum yield (QY) for traditional semiconductor NCs. Though Mn-doped perovskite nanocube is a potential candidate, it has been unable to realize a white-light emission to date. In this work, the synthesis of Mn-doped 2D perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets with a pure white emission from a single component is reported. Unlike Mn-doped perovskite nanocubes with insufficient energy transfer efficiency, the current reported Mn-doped 2D perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets show a 10 times higher energy transfer efficiency from perovskite to Mn impurities at the required emission wavelengths (about 450 nm for perovskite emission and 580 nm for Mn emission). As a result, the Mn/perovskite dual emission intensity ratio surprisingly elevates from less than 0.25 in case of Mn-doped nanocubes to 0.99 in the current Mn-doped CsPb 2 Cl x Br 5-x nanoplatelets, giving rise to a pure white light emission with Commission Internationale de l'Eclairage (CIE) color coordinates of (0.35, 0.32). More importantly, the highest PL QY for Mn-doped perovskite-related CsPb 2 Cl x Br 5-x nanoplatelets is up to 49%, which is a new record for white-emitting nanocrystals with single component. These highly luminescent nanoplatelets can be blended with polystyrene (PS) without changing the white light emission but dramatically improving perovskite stability. The perovskite-PS composites are available not only as a good solution processable coating material for assembling LED, but also as a superior conversion material for achieving white light LED with a single conversion layer.

Up-conversion luminescence properties and energy transfer of Tm{sup 3+}/Yb{sup 3+} co-doped BaLa{sub 2}ZnO{sub 5}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xie, Jing; Mei, Lefu, E-mail: mlf@cugb.edu.cn; Deng, Junru

2015-11-15

Tm{sup 3+}/Yb{sup 3+} co-doped BaLa{sub 2}ZnO{sub 5} up-conversion (UC) phosphors were successfully synthesized by high temperature solid-state reaction method. The X-ray diffraction (XRD) results show that synthesized phosphor co-doped with 0.75% Tm/10% Yb has the optimum pure phase of BaLa{sub 2}ZnO{sub 5} among different co-doping concentrations. The structure of BaLa{sub 2}ZnO{sub 5}:0.75% Tm/10% Yb phosphor was refined by the Rietveld method and results show the decreased unit cell parameters and cell volume after doping Tm{sup 3+}/Yb{sup 3+}, indicating that Tm{sup 3+}/Yb{sup 3+} have successfully replaced La{sup 3+}. Under excitation at 980 nm, Tm{sup 3+}/Yb{sup 3+} co-doped BaLa{sub 2}ZnO{sub 5} phosphorsmore » present bright blue emission near 478 nm generated by the {sup 1}G{sub 4}→{sup 3}H{sub 6} transition and weak red emissions around 653 nm and 692 nm generated by the {sup 1}G{sub 4}→{sup 3}F{sub 4} and {sup 3}F{sub 3}→{sup 3}H{sub 6} transitions of Tm{sup 3+}, respectively. The UC luminescence properties of BaLa{sub 2}ZnO{sub 5} phosphors co-doped with different Tm{sup 3+}/Yb{sup 3+} concentrations were investigated, and the related UC mechanisms of Tm{sup 3+}/Yb{sup 3+} co-doped BaLa{sub 2}ZnO{sub 5} depending on pump power were studied in detail. - Graphical abstract: Up-conversion luminescence of BaLa{sub 2}ZnO{sub 5}:Tm{sup 3+}/Yb{sup 3+} and its crystal structure and up-conversion mechanisms. - Highlights: • Up-conversion phosphors BaLa{sub 2}ZnO{sub 5} co-doped with Tm{sup 3+}/Yb{sup 3+} were synthesized by high temperature solid-state reaction method. • The crystal structure of BaLa{sub 2}ZnO{sub 5} and the changes of cell parameters and volume of BaLa{sub 2}ZnO{sub 5} after doping Tm{sup 3+} and Yb{sup 3+} have been discussed. • Up-conversion luminescence properties and energy transfer between Tm{sup 3+} and Yb{sup 3+} in BaLa{sub 2}ZnO{sub 5} have been discussed in detail.« less

Control of Wigner localization and electron cavity effects in near-field emission spectra of In(Ga)P/GaInP quantum-dot structures

NASA Astrophysics Data System (ADS)

Mintairov, A. M.; Kapaldo, J.; Merz, J. L.; Rouvimov, S.; Lebedev, D. V.; Kalyuzhnyy, N. A.; Mintairov, S. A.; Belyaev, K. G.; Rakhlin, M. V.; Toropov, A. A.; Brunkov, P. N.; Vlasov, A. S.; Zadiranov, Yu. M.; Blundell, S. A.; Mozharov, A. M.; Mukhin, I.; Yakimov, M.; Oktyabrsky, S.; Shelaev, A. V.; Bykov, V. A.

2018-05-01

Structural and emission properties of few-electron In(Ga)P/GaInP quantum dots (QDs) representing natural Wigner molecules (WM) and whispering gallery mode (WGM) electron (e ) cavities have been investigated. QD structures were grown using self-organized metal-organic vapor phase epitaxy and deposition from ˜3 to 7 monolayers of InP at 700 °C. Using atomic force microscopy, transmission electron microscopy, near-field scanning optical microscopy (NSOM), and μ -photoluminescence (μ -PL) spectra we obtained In(Ga)P/GaInP QDs having lateral size 80-180 nm, height 5-30 nm, Ga content 0.0-0.4, density 2 -10 μm-2 , and electron population up to 20 and demonstrated control of their density and size distribution. Using high-spatial-resolution low-temperature PL spectra, NSOM imaging, and calculations of charge density distributions we observed Wigner localization and e -cavity effects for a series of dots having quantum confinement ℏ ω0=0.5 -6 meV . We used these data together with time-resolved PL measurements to clarify the effect of Coulomb interaction and WM formation on emission spectra of few-electron QDs. We present direct observation of 2 e , 6 e , and 9 e WMs; 2 e and 4 e WGMs; and Fabry-Perot e modes and establish conditions of e -WGM-cavity formation in these QDs.

Effect of inlet temperature on the performance of a catalytic reactor. [air pollution control

NASA Technical Reports Server (NTRS)

Anderson, D. N.

1978-01-01

A 12 cm diameter by 15 cm long catalytic reactor was tested with No. 2 diesel fuel in a combustion test rig at inlet temperatures of 700, 800, 900, and 1000 K. Other test conditions included pressures of 3 and 6 x 10 to the 5th power Pa, reference velocities of 10, 15, and 20 m/s, and adiabatic combustion temperatures in the range 1100 to 1400 K. The combustion efficiency was calculated from measurements of carbon monoxide and unburned hydrocarbon emissions. Nitrogen oxide emissions and reactor pressure drop were also measured. At a reference velocity of 10 m/s, the CO and unburned hydrocarbons emissions, and, therefore, the combustion efficiency, were independent of inlet temperature. At an inlet temperature of 1000 K, they were independent of reference velocity. Nitrogen oxides emissions resulted from conversion of the small amount (135 ppm) of fuel-bound nitrogen in the fuel. Up to 90 percent conversion was observed with no apparent effect of any of the test variables. For typical gas turbine operating conditions, all three pollutants were below levels which would permit the most stringent proposed automotive emissions standards to be met.

On-the-fly ab initio semiclassical dynamics: Emission spectra of oligothiophenes

NASA Astrophysics Data System (ADS)

Wehrle, Marius; Sulc, Miroslav; Vanicek, Jiri

2014-03-01

We employ the thawed Gaussian approximation (TGA) [E. J. Heller, J. Chem. Phys. 62, 1544 (1975)] within an on-the-fly ab initio (OTF-AI) scheme to calculate the vibrationally resolved emission spectra of oligothiophenes up to five rings. OTF-AI-TGA is efficient enough to treat all vibrational degrees of freedom on an equal footing even in case of 5-oligothiophene (105 vibrational degrees of freedom), thus obviating the need for the crude global harmonic approximation, popular for large system. The experimental emission spectra have been almost perfectly reproduced. In order to provide a deeper insight into the associated physical and chemical processes, we present a systematic approach to assess the importance and to analyze the mutual coupling of individual vibrational degrees of freedom during the dynamics. This allows us to explain the changes in the vibrational line shapes of the oligothiophenes with increasing number of rings. Furthermore, we observe the dynamical interplay between quinoid and aromatic characters of individual rings in the oligothiophene chain during the dynamics and confirm that the quinoid character prevails in the center of the chain. This research was supported by the Swiss NSF Grant No. 200021_124936/1 and NCCR Molecular Ultrafast Science & Technology (MUST), and by the EPFL.

Compton scattering of self-absorbed synchrotron emission

NASA Astrophysics Data System (ADS)

Gao, He; Lei, Wei-Hua; Wu, Xue-Feng; Zhang, Bing

2013-11-01

Synchrotron self-Compton (SSC) scattering is an important emission mechanism in many astronomical sources, such as gamma-ray bursts (GRBs) and active galactic nuclei. We give a complete presentation of the analytical approximations for the Compton scattering of synchrotron emission with both weak and strong synchrotron self-absorption. All possible orders of the characteristic synchrotron spectral breaks (νa, νm and νc) are studied. In the weak self-absorption regime, i.e. νa < νc, the electron energy distribution is not modified by the self-absorption process. The shape of the SSC component broadly resembles that of synchrotron, but with the following features: The SSC flux increases linearly with frequency up to the SSC break frequency corresponding to the self-absorption frequency νa; and the presence of a logarithmic term in the high-frequency range of the SSC spectra makes it harder than the power-law approximation. In the strong absorption regime, i.e. νa > νc, heating of low-energy electrons due to synchrotron absorption leads to pile-up of electrons, and form a thermal component besides the broken power-law component. This leads to two-component (thermal + non-thermal) spectra for both the synchrotron and SSC spectral components. For νc < νa < νm, the spectrum is thermal (non-thermal) dominated if ν _a > √{ν _m ν _c} (ν _a < √{ν _m ν _c}). Similar to the weak-absorption regime, the SSC spectral component is broader than the simple broken power-law approximation. We derive the critical condition for strong absorption (electron pile-up), and discuss a case of GRB reverse shock emission in a wind medium, which invokes νa > max(νm, νc).

Thermochemical conversion of biomass storage covers to reduce ammonia emissions from dairy manure Thermochemical conversion of biomass storage covers to reduce ammonia emissions from dairy manure

USDA-ARS?s Scientific Manuscript database

Manure storages, and in particular those storing digested manure, are a source of ammonia (NH3) emissions. Permeable manure storage covers can reduce NH3 emissions, however performance can decline as they degrade. Thermochemical conversion of biomass through pyrolysis and steam treatment could incre...

Modeling of the EUV and X-Ray Emission Spectra Induced by the Solar Winds Ions in the Heliosphere

NASA Technical Reports Server (NTRS)

Kharchenko, Vasili

2005-01-01

We have carried out investigation of the EUV and X-ray emission spectra induced in interaction between the Solar Wind (SW) and interstellar neutral gas. The spectra of most important SW ions have been computed for the charge-exchange mechanism of X-ray emission using new accurate spectroscopic data from recent laboratory measurements and theoretical calculations. Total spectra have been constructed as a sum of spectra induced in the charge-exchange collisions by individual O(exp q+), C(exp q+), N(exp q+), Ne(exp q+), Mg (exp q+) and Fe(exp q+) ions. Calculations have been performed for X-ray emission from the heliospheric hydrogen and helium gas. X-ray maps of the heliosphere have been computed. The power density of X-ray sources in the heliospheric ecliptic plane is shown for the H gas and for the He gas. Distances from the Sun (0,0) are given in AU. The helium cone is clear seen in the X-ray map of the charge-exchange emission induced by the solar wind. X-ray emission spectra detected by the Chandra X-ray telescope from the "dark" side of Moon has been identified as a X-ray background emission induced by the solar wind from the geocorona. Spectra and intensities of this charge-exchange X-rays have been compared with the heliospheric component of the X-ray background. Observations and modeling of the SW spectra induced from the geocorona indicate a strong presence of emission lines of highly charged oxygen ions. Anisotropy in distribution of heliospheric X-rays has been predicted and calculated for the regions of the fast and slow solar winds.

Study of atomic and molecular emission spectra of Sr by laser induced breakdown spectroscopy (LIBS).

PubMed

Bhatt, Chet R; Alfarraj, Bader; Ayyalasomayajula, Krishna K; Ghany, Charles; Yueh, Fang Y; Singh, Jagdish P

2015-12-01

Laser Induced Breakdown Spectroscopy (LIBS) is an ideal analytical technique for in situ analysis of elemental composition. We have performed a comparative study of the quantitative and qualitative analysis of atomic and molecular emission from LIBS spectra. In our experiments, a mixture of SrCl2 and Al2O3 in powder form was used as a sample. The atomic emission from Sr and molecular emission from SrCl and SrO observed in LIBS spectra were analyzed. The optimum laser energies, gate delays, and gate widths for selected atomic lines and molecular bands were determined from spectra recorded at various experimental parameters. These optimum experimental conditions were used to collect calibration data, and the calibration curves were used to predict the Sr concentration. Limits of detection (LODs) for selected atomic and molecular emission spectra were determined.

Coherent manipulation of spontaneous emission spectra in coupled semiconductor quantum well structures.

PubMed

Chen, Aixi

2014-11-03

In triple coupled semiconductor quantum well structures (SQWs) interacting with a coherent driving filed, a coherent coupling field and a weak probe field, spontaneous emission spectra are investigated. Our studies show emission spectra can easily be manipulated through changing the intensity of the driving and coupling field, detuning of the driving field. Some interesting physical phenomena such as spectral-line enhancement/suppression, spectral-line narrowing and spontaneous emission quenching may be obtained in our system. The theoretical studies of spontaneous emission spectra in SQWS have potential application in high-precision spectroscopy. Our studies are based on the real physical system [Appl. Phys. Lett.86(20), 201112 (2005)], and this scheme might be realizable with presently available techniques.

Method to generate high efficient devices which emit high quality light for illumination

DOEpatents

Krummacher, Benjamin C.; Mathai, Mathew; Choong, Vi-En; Choulis, Stelios A.

2009-06-30

An electroluminescent apparatus includes an OLED device emitting light in the blue and green spectrums, and at least one down conversion layer. The down conversion layer absorbs at least part of the green spectrum light and emits light in at least one of the orange spectra and red spectra.

Thermal Emission Spectroscopy of 1 Ceres: Evidence for Olivine

NASA Technical Reports Server (NTRS)

Witteborn, Fred. C.; Roush, Ted L.; Cohen, Martin

1999-01-01

Thermal emission spectra of the largest asteroid, 1 Ceres, obtained from the Kuiper Airborne Observatory display features that may provide information about its surface mineralogy. The emissivity, obtained by dividing the spectra by a standard thermal model, is compared with emissivity spectra of olivines and phyllosilicates deduced via Kirchoff's law from reflectivity measurements. The spectra provide a fairly good match to fine grained olivines (0 to 5 micrometer size range). The smoothness of the spectrum beyond 18 micrometers is an indication of particles smaller than 50 micrometers. While the abrupt rise in emissivity near 8 micrometers matches many silicates, the distinct emissivity minimum centered near 12.8 micrometers is consistant with iron-poor olivines, but not with phyllosilicates. It suggests the presence of opaques and does not exclude a mixture with organics and fine-grained phyllosilicates.

Dynamical and Radiative Properties of X-Ray Pulsar Accretion Columns: Phase-averaged Spectra

NASA Astrophysics Data System (ADS)

West, Brent F.; Wolfram, Kenneth D.; Becker, Peter A.

2017-02-01

The availability of the unprecedented spectral resolution provided by modern X-ray observatories is opening up new areas for study involving the coupled formation of the continuum emission and the cyclotron absorption features in accretion-powered X-ray pulsar spectra. Previous research focusing on the dynamics and the associated formation of the observed spectra has largely been confined to the single-fluid model, in which the super-Eddington luminosity inside the column decelerates the flow to rest at the stellar surface, while the dynamical effect of gas pressure is ignored. In a companion paper, we have presented a detailed analysis of the hydrodynamic and thermodynamic structure of the accretion column obtained using a new self-consistent model that includes the effects of both gas and radiation pressures. In this paper, we explore the formation of the associated X-ray spectra using a rigorous photon transport equation that is consistent with the hydrodynamic and thermodynamic structure of the column. We use the new model to obtain phase-averaged spectra and partially occulted spectra for Her X-1, Cen X-3, and LMC X-4. We also use the new model to constrain the emission geometry, and compare the resulting parameters with those obtained using previously published models. Our model sheds new light on the structure of the column, the relationship between the ionized gas and the photons, the competition between diffusive and advective transport, and the magnitude of the energy-averaged cyclotron scattering cross-section.

Dynamical and Radiative Properties of X-Ray Pulsar Accretion Columns: Phase-averaged Spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, Brent F.; Wolfram, Kenneth D.; Becker, Peter A., E-mail: bwest@usna.edu, E-mail: kswolfram@gmail.com, E-mail: pbecker@gmu.edu

The availability of the unprecedented spectral resolution provided by modern X-ray observatories is opening up new areas for study involving the coupled formation of the continuum emission and the cyclotron absorption features in accretion-powered X-ray pulsar spectra. Previous research focusing on the dynamics and the associated formation of the observed spectra has largely been confined to the single-fluid model, in which the super-Eddington luminosity inside the column decelerates the flow to rest at the stellar surface, while the dynamical effect of gas pressure is ignored. In a companion paper, we have presented a detailed analysis of the hydrodynamic and thermodynamicmore » structure of the accretion column obtained using a new self-consistent model that includes the effects of both gas and radiation pressures. In this paper, we explore the formation of the associated X-ray spectra using a rigorous photon transport equation that is consistent with the hydrodynamic and thermodynamic structure of the column. We use the new model to obtain phase-averaged spectra and partially occulted spectra for Her X-1, Cen X-3, and LMC X-4. We also use the new model to constrain the emission geometry, and compare the resulting parameters with those obtained using previously published models. Our model sheds new light on the structure of the column, the relationship between the ionized gas and the photons, the competition between diffusive and advective transport, and the magnitude of the energy-averaged cyclotron scattering cross-section.« less

Soil emissivity and reflectance spectra measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sobrino, Jose A.; Mattar, Cristian; Pardo, Pablo

We present an analysis of the laboratory reflectance and emissivity spectra of 11 soil samples collected on different field campaigns carried out over a diverse suite of test sites in Europe, North Africa, and South America from 2002 to 2008. Hemispherical reflectance spectra were measured from 2.0 to 14 {mu}m with a Fourier transform infrared spectrometer, and x-ray diffraction analysis (XRD) was used to determine the mineralogical phases of the soil samples. Emissivity spectra were obtained from the hemispherical reflectance measurements using Kirchhoff's law and compared with in situ radiance measurements obtained with a CIMEL Electronique CE312-2 thermal radiometer andmore » converted to emissivity using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) temperature and emissivity separation algorithm. The CIMEL has five narrow bands at approximately the same positions as the ASTER. Results show a root mean square error typically below 0.015 between laboratory emissivity measurements and emissivity measurements derived from the field radiometer.« less

Optical, colloidal and biological properties of up-converting nanoparticles embedded in polyester nanocarriers

NASA Astrophysics Data System (ADS)

Wawrzyńczyk, Dominika; Kulbacka, Julita; Bazylińska, Urszula

2017-08-01

We have investigated the change in optical properties and biocompatibility of up-converting NaYF4 nanoparticles (NPs) upon encapsulation inside the polyester nanocarriers (NCs) stabilized by Crempophor RH40 (CRH40), poly(D,L-lactide) (PLA), Pluronic P123 (P123). NaYF4:Er3+,Yb3+ NPs showed intense green and red emission, and upon encapsulation the increase of red band in respect to green one was observed, with no luminescence lifetime shortening. Obtained NCs showed prolonged colloidal stability and protective effect of the polymer shell simultaneously preserving the high emission efficiency of nanoparticles embedded within the silicon oil (SO) core. Based on emission spectra, kinetic measurements and cytotoxicity studies upon human malignant melanoma Me45 cell line we have shown the advantages of using polyester NCs as containers for the up-converting NPs. Due to the possibility of co-encapsulation of photosensitizers the obtained nanocarriers showed potential for application in theranostics.

Preliminary panoramic study of river calm muscle using neodymium:yttrium-aluminum-garnet (Nd: YAG) laser-induced breakdown spectroscopy (LIBS)

NASA Astrophysics Data System (ADS)

Idris, N.; Lahna, K.; Usmawanda, T. N.; Herman; Ramli, M.; Hedwig, R.; Marpaung, A. M.; Kurniawan, K. H.

2018-04-01

A wide coverage spectral investigation on the muscle of river calm sample has been carried out using laser-induced breakdown spectroscopy for examining the overall profile of the emission spectra from the produced plasma. The basic apparatus of LIBS system used is a Nd-YAG laser and wide coverage optical multichannel analyzer (OMA) system. The river clam samples used is collected from Panga River in Aceh Jaya Regency, Aceh, Indonesia up streaming in a mountain of Gunong Ujeun, which is used as a location of the intensive traditional mining activity. Assuming that heavy metal accumulated in the clam muscle, LIBS experiments were carried out on the muscle of the calm. The sample used was fresh muscle sliced and attached to a copper plate. Plasma was generated by focusing the laser beam on the sample surface under air surrounding gas at 1 atmosphere. It is found that there are only major elements of host organic, namely C, H, O, N and the minor element of salts can be detected from fresh the clam sample when using a high pulse laser energy under air surrounding at high pressure of 1 atmosphere. There is no emission lines from any metal can be detected. Several experimental parameters were explored to study the panoramic dynamic of the emission spectra. It is found that the lower energy and the lower pressure is better for obtaining better emission spectra showing the possibility for determination of the analyte.

Theory and Simulation of Exoplanetary Atmospheric Haze: Giant Spectral Line Broadening

NASA Astrophysics Data System (ADS)

Sadeghpour, Hossein; Felfeli, Zineb; Kharchenko, Vasili; Babb, James; Vrinceanu, Daniel

2018-01-01

Prominent spectral features in observed transmission spectra of exoplanets are obscured. Atmospheric haze is the leading candidate for the flattening of spectral transmission of expolanetray occultation, but also for solar system planets, Earth and cometary atmospheres. Such spectra which carry information about how the planetary atmospheres become opaque to stellar light in transit, show broad absorption where strong absorption lines from sodium or potassium and water are predicted to exist. In this work, we develop a detailed atomistic theoretical model, taking into account interaction between an atomic or molecular radiator with dust and haze particulates. Our model considers a realistic structure of haze particulates from small seed particles up to sub-micron irregularly shaped aggregates. This theory of interaction between haze and radiator particles allows to consider nearly all realistic structure, size and chemical composition of haze particulates. The computed shift and broadening of emission spectra will include both quasi-static (mean field) and collisional (pressure) shift and broadening. Our spectral calculations will be verified with available laboratory experimental data on spectra of alkali atoms in liquid droplet, solid ice, dust and dense gaseous environments. The simplicity, elegance and generality of the proposed model makes it amenable to a broad community of users in astrophysics and chemistry. The verified models can be used for analysis of emission and absorption spectra of alkali atoms from exoplanets, solar system planets, satellites and comets.

Shell- and subshell-resolved projectile excitation of hydrogenlike Au{sup 78+} ions in relativistic ion-atom collisions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gumberidze, A.; Frankfurt Institute for Advanced Studies FIAS, D-60438 Frankfurt am Main; Fritzsche, S.

2010-11-15

The projectile excitation of high-Z ions has been investigated in relativistic ion-atoms collisions by observing the subsequent x-ray emission. The x-ray spectra from the projectile excitation have been separated from the x-ray emission following electron capture into the excited states using a novel anticoincidence technique. For the particular case of hydrogenlike Au{sup 78+} ions colliding with Ar atoms, Coulomb excitation from the ground state into the fine-structure-resolved n=2 levels as well as into levels with principal quantum number n{>=}3 has been measured with excellent statistics. The observed spectra agree well with simulated spectra that are based on Dirac's relativistic equationmore » and the proper inclusion of the magnetic interaction into the amplitudes for projectile excitation. It is shown that a coherent inclusion of the magnetic part of the Lienard-Wiechert potential leads to the lowering of the excitation cross section by up to 35%. This effect is more pronounced for excitation into states with high angular momentum and is confirmed by our experimental data.« less

Development of SnS (FTO/CdS/SnS) thin films by nebulizer spray pyrolysis (NSP) for solar cell applications

NASA Astrophysics Data System (ADS)

Arulanantham, A. M. S.; Valanarasu, S.; Jeyadheepan, K.; Ganesh, V.; Shkir, Mohd

2018-01-01

Herein we report a well-organized analysis on various key-properties of SnS thin films for solar cell fabricated by nebulizer spray pyrolysis technique. X-ray diffraction study reveals the polycrystalline nature of deposited films with orthorhombic crystal structure. The crystallite size was calculated and observed to be in the range of 8-28 nm with increasing molarity of precursor solution. The stoichiometry composition of SnS was confirmed by EDX study. SEM/AFM studies divulge the well-covered deposited surface with spherical grains and the size of grains is increasing with concentration and so the roughness. A remarkable decrease in band gap from 2.6 eV to 1.6 eV was noticed by raising the molar concentration from 0.025 M up to 0.075 M. A single strong emission peak at about 825 nm is observed in PL spectra with enhanced intensity which may be attributed to near band edge emission. From the Hall effect measurement, it was found that the SnS thin film exhibits p-type conductivity. The calculated values of resistivity and carrier concentration are 0.729 Ω cm and 3.67 × 1018/cm3 respectively. Furthermore, to study the photovoltaic properties of SnS thin films a heterojunction solar cell, FTO/n-CdS/p-SnS was produced and the conversion efficiency was recorded about 0.01%.

Controlling the emission profile of an H2 discharge lamp to simulate interstellar radiation fields

NASA Astrophysics Data System (ADS)

Ligterink, N. F. W.; Paardekooper, D. M.; Chuang, K.-J.; Both, M. L.; Cruz-Diaz, G. A.; van Helden, J. H.; Linnartz, H.

2015-12-01

Context. Microwave discharge hydrogen-flow lamps have been used for more than half a century to simulate interstellar ultraviolet radiation fields in the laboratory. Recent discrepancies between identical measurements in different laboratories, as well as clear wavelength dependent results obtained in monochromatic (synchrotron) experiments, hint at a more elaborate dependence on the exact discharge settings than assumed so far. Aims: We have investigated systematically two lamp geometries in full dependence of a large number of different running conditions and the spectral emission patterns are characterized for the first time with fully calibrated absolute flux numbers. Methods: A sophisticated plasma lamp calibration set-up has been used to record the vacuum-ultraviolet emission spectra with a spectral resolution of 0.5 nm and bandwidth of 1.6 nm in the 116-220 nm region. Spectra are compared with the output of a calibrated D2-lamp which allows a derivation of absolute radiance values. Results: The general findings of over 200 individual measurements are presented, illustrating how the lamp emission pattern depends on i) microwave power; ii) gas and gas mixing ratios; iii) discharge lamp geometry; iv) cavity positioning; and v) gas pressure.

Electrode Build-Up of Reducible Metal Composites toward Achievable Electrochemical Conversion of Carbon Dioxide.

PubMed

Lee, Seunghwa; Lee, Jaeyoung

2016-02-19

At the beginning of the 21st century, our world is faced with a global-warming problem due to the continuous increase in carbon dioxide emission, and thus, the development of novel experimental techniques is needed. The electrochemical conversion of carbon dioxide into high-value organic compounds could be of vital importance to solve this issue. The biggest challenge has always been to develop an electrocatalyst that is chemically active and structurally stable. Herein, previous studies, recent approaches, and current points of view on the electrode structure of metal oxide composites for the advanced electrochemical conversion of carbon dioxide are reviewed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High temperature growth of Pt on the Rh(111) surface

NASA Astrophysics Data System (ADS)

Duisberg, M.; Dräger, M.; Wandelt, K.; Gruber, E. L. D.; Schmid, M.; Varga, P.

1999-08-01

The epitaxial growth of Pt on the Rh(111) surface at 700 K was studied with AES, UPS, ISS and STM. From AES and ISS measurements a 2D growth mode is concluded at this substrate temperature. The morphology of the surface is studied by photoemission spectra of adsorbed Xe (PAX) and STM. A disperse distribution of the Pt atoms is suggested by PAX and is consistent with an incorporation of these atoms into the first substrate layer. Atomically and chemically resolved STM measurements confirm these conclusions. The interaction of CO with the surface alloy is investigated by UPS. The CO-induced features in UP spectra show significant differences in the peak positions and shape between the clean substrate and the surface precovered with different amounts of Pt. The CO induced emissions are, thus, used for a quantitative titration of Pt on the Rh surface.

Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

NASA Technical Reports Server (NTRS)

Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

2000-01-01

We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

Versatile ruthenium(II) dye towards blue-light emitter and dye-sensitizer for solar cells

NASA Astrophysics Data System (ADS)

Zanoni, Kassio P. S.; Amaral, Ronaldo C.; Murakami Iha, Neyde Y.; Abreu, Felipe D.; de Carvalho, Idalina M. M.

2018-06-01

A versatile Ru(II) complex bearing an anthracene moiety was synthesized in our search for suitable compounds towards efficient molecular devices. The new engineered dye, cis‑[Ru(dcbH2)(NCS)2(mbpy‑anth)] (dcbH2 = 2,2‧‑bipyridyl‑4,4‧‑dicarboxylic acid, mbpy‑anth = 4‑[N‑(2‑anthryl)carbamoyl]‑4‧‑methyl‑2,2‧‑bipyridine), exhibits a blueish emission in a vibronically structured spectrum ascribed to the fluorescence of a 1LCAnth (ligand centered) excited state in the anthracene and has a potential to be exploited in the fields of smart lighting and displays. This complex was also employed in dye-sensitized solar cells with fairly efficient solar energy conversion with the use of self-assembled TiO2 compact layers beneath the TiO2 mesoporous film to prevent meso‑TiO2/dye back reactions. Further photoelectrochemical investigations through incident photon-to-current efficiency and electrochemical impedance spectra showed that the all-nano-TiO2 compact layer acts as contact layers that increase the electron harvesting in the external circuit, enhancing efficiencies up to 50%.

Versatile ruthenium(II) dye towards blue-light emitter and dye-sensitizer for solar cells.

PubMed

Zanoni, Kassio P S; Amaral, Ronaldo C; Murakami Iha, Neyde Y; Abreu, Felipe D; de Carvalho, Idalina M M

2018-06-05

A versatile Ru(II) complex bearing an anthracene moiety was synthesized in our search for suitable compounds towards efficient molecular devices. The new engineered dye, cis‑[Ru(dcbH 2 )(NCS) 2 (mbpy‑anth)] (dcbH 2 =2,2'‑bipyridyl‑4,4'‑dicarboxylic acid, mbpy‑anth=4‑[N‑(2‑anthryl)carbamoyl]‑4'‑methyl‑2,2'‑bipyridine), exhibits a blueish emission in a vibronically structured spectrum ascribed to the fluorescence of a 1 LC Anth (ligand centered) excited state in the anthracene and has a potential to be exploited in the fields of smart lighting and displays. This complex was also employed in dye-sensitized solar cells with fairly efficient solar energy conversion with the use of self-assembled TiO 2 compact layers beneath the TiO 2 mesoporous film to prevent meso‑TiO 2 /dye back reactions. Further photoelectrochemical investigations through incident photon-to-current efficiency and electrochemical impedance spectra showed that the all-nano-TiO 2 compact layer acts as contact layers that increase the electron harvesting in the external circuit, enhancing efficiencies up to 50%. Copyright © 2018 Elsevier B.V. All rights reserved.

Angle-resolved photoluminescence spectrum of a uniform phosphor layer

NASA Astrophysics Data System (ADS)

Fujieda, Ichiro; Ohta, Masamichi

2017-10-01

A photoluminescence spectrum depends on an emission angle due to self-absorption in a phosphor material. Assuming isotropic initial emission and Lambert-Beer's law, we have derived simple expressions for the angle-resolved spectra emerging from the top and bottom surfaces of a uniform phosphor layer. The transmittance of an excitation light through the phosphor layer can be regarded as a design parameter. For a strongly-absorbing phosphor layer, the forward flux is less intense and more red-shifted than the backward flux. The red-shift is enhanced as the emission direction deviates away from the plane normal. When we increase the transmittance, the backward flux decreases monotonically. The forward flux peaks at a certain transmittance value. The two fluxes become similar to each other for a weakly-absorbing phosphor layer. We have observed these behaviors in experiment. In a practical application, self-absorption decreases the efficiency of conversion and results in angle-dependent variations in chromaticity coordinates. A patterned phosphor layer with a secondary optical element such as a remote reflector alleviates these problems.

The down-conversion and up-conversion photoluminescence properties of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}:Yb{sup 3+}/Pr{sup 3+} ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Yinpeng; Luo, Laihui, E-mail: luolaihui@nbu.edu.cn; Wang, Jia

2015-07-28

Na{sub 0.5}Bi{sub 0.5−x−y}Yb{sub x}Pr{sub y}TiO{sub 3} (NBT:xYb/yPr) ceramics with different Yb and Pr contents are prepared. Both the down-conversion (DC) and up-conversion (UC) photoluminescence (PL) of the ceramics via 453 and 980 nm excitation, respectively, are investigated. The effect of Yb{sup 3+} and Pr{sup 3+} doping contents on the DC and UC PL is significantly different from each other. Furthermore, the UC PL of the ceramics as a function of temperatures is measured to investigate the UC process in detail. Based on energy level diagram of Pr{sup 3+} and Yb{sup 3+} ions and the DC and UC PL spectra, the DCmore » and UC PL mechanisms of Pr{sup 3+} and Yb{sup 3+} ions are discussed. Especially, the UC PL mechanism is clarified, which is different from the previously reported literature. Also, the temperature sensing properties of the ceramics are studied based on the photoluminescence ratio technique, using the thermal coupling energy levels of Pr{sup 3+}.« less

Efficient near-infrared up-conversion photoluminescence in carbon nanotubes

PubMed Central

Akizuki, Naoto; Aota, Shun; Mouri, Shinichiro; Matsuda, Kazunari; Miyauchi, Yuhei

2015-01-01

Photoluminescence phenomena normally obey Stokes' law of luminescence according to which the emitted photon energy is typically lower than its excitation counterparts. Here we show that carbon nanotubes break this rule under one-photon excitation conditions. We found that the carbon nanotubes exhibit efficient near-infrared photoluminescence upon photoexcitation even at an energy lying >100–200 meV below that of the emission at room temperature. This apparently anomalous phenomenon is attributed to efficient one-phonon-assisted up-conversion processes resulting from unique excited-state dynamics emerging in an individual carbon nanotube with accidentally or intentionally embedded localized states. These findings may open new doors for energy harvesting, optoelectronics and deep-tissue photoluminescence imaging in the near-infrared optical range. PMID:26568250

Infrared emission from the supernova remnant Puppis A: Dust and gas parameters

NASA Technical Reports Server (NTRS)

Arendt, Richard G.; Dwek, Eli; Petre, R

1989-01-01

The infrared (IR) spectra of collisionally heated dust at several regions across the supernova remnant (SNR) Puppis A were modelled. Through the comparison of the actual and model spectra, the possible range of gas density and temperature within these areas was narrowed down. From the models, information on the minimum and maximum dust grain sizes and the amount of sputtering which has occurred was found. Finally the mass of gas and dust, the IR luminosity, the effective thickness, and the length of time since the dust was swept up by the SNR were derived for these regions.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kerby, Leslie Marie

Emission of light fragments (LF) from nuclear reactions is an open question. Different reaction mechanisms contribute to their production; the relative roles of each, and how they change with incident energy, mass number of the target, and the type and emission energy of the fragments is not completely understood. None of the available models are able to accurately predict emission of LF from arbitrary reactions. However, the ability to describe production of LF (especially at energies ≳ 30 MeV) from many reactions is important for different applications, such as cosmic-ray-induced Single Event Upsets (SEUs), radiation protection, and cancer therapy withmore » proton and heavy-ion beams, to name just a few. The Cascade-Exciton Model (CEM) version 03.03 and the Los Alamos version of the Quark-Gluon String Model (LAQGSM) version 03.03 event generators in Monte Carlo N-Particle Transport Code version 6 (MCNP6) describe quite well the spectra of fragments with sizes up to ⁴He across a broad range of target masses and incident energies (up to ~ 5 GeV for CEM and up to ~ 1 TeV/A for LAQGSM). However, they do not predict the high energy tails of LF spectra heavier than ⁴He well. Most LF with energies above several tens of MeV are emitted during the precompound stage of a reaction. The current versions of the CEM and LAQGSM event generators do not account for precompound emission of LF larger than ⁴He. The aim of our work is to extend the precompound model in them to include such processes, leading to an increase of predictive power of LF-production in MCNP6. This entails upgrading the Modified Exciton Model currently used at the preequilibrium stage in CEM and LAQGSM. It also includes expansion and examination of the coalescence and Fermi break-up models used in the precompound stages of spallation reactions within CEM and LAQGSM. Extending our models to include emission of fragments heavier than ⁴He at the precompound stage has indeed provided results that have much better agreement with experimental data.« less

Unravelling thermal emissivity spectra of the main minerals on Mercury's surface by comparison with ab initio calculated IR-HT vibrational frequencies

NASA Astrophysics Data System (ADS)

Stangarone, C.; Helbert, J.; Tribaudino, M.; Maturilli, A.; D'Amore, M.; Ferrari, S.; Prencipe, M.

2015-12-01

Spectral signatures of minerals are intimately related to the crystal structure; therefore they may represent a remote sensing model to determine surface composition of planetary bodies, by analysing their spectral reflectance and emission. However, one of the most critical point is data interpretation considering planetary surfaces, as Mercury, where the changes in spectral characteristics are induced by the high temperatures conditions (Helbert et al., 2013). The aim of this work is to interpret the experimental thermal emissivity spectra with an innovative approach: simulating IR spectra of the main mineral families that compose the surface of Mercury, focusing on pyroxenes (Sprague et al., 2002), both at room and high temperature, exploiting the accuracy of ab initio quantum mechanical calculations, by means of CRYSTAL14 code (Dovesi et al., 2014). The simulations will be compared with experimental emissivity measurements of planetary analogue samples at temperature up to 1000K, performed at Planetary Emissivity Laboratory (PEL) by Institute of Planetary Research (DLR, Berlin). Results will be useful to create a theoretical background to interpret HT-IR emissivity spectra that will be collected by the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS), a spectrometer developed by DLR that will be on board of the ESA BepiColombo Mercury Planetary Orbiter (MPO) scheduled for 2017. The goal is to point out the most interesting spectral features for a geological mapping of Mercury and other rocky bodies, simulating the environmental conditions of the inner planets of Solar System. Dovesi R., Saunders V. R., Roetti C., Orlando R., Zicovich-Wilson C. M., Pascale F., Civalleri B., Doll K., Harrison N. M., Bush I. J., D'Arco P., Llunell M., Causà M. & Noël Y. 2014. CRYSTAL14 User's Manual, University of Torino. Sprague, A. L., Emery, J. P., Donaldson, K. L., Russell, R. W., Lynch, D. K., & Mazuk, A. L. (2002). Mercury: Mid-infrared (3-13.5 μm) observations show heterogeneous composition, presence of intermediate and basic soil types, and pyroxene. Meteoritics & Planetary Science, 37(9), 1255-1268.

VizieR Online Data Catalog: Broad Hβ emission line in 102 Seyfert galaxies (Runco+, 2016)

NASA Astrophysics Data System (ADS)

Runco, J. N.; Cosens, M.; Bennert, V. N.; Scott, B.; Komossa, S.; Malkan, M. A.; Lazarova, M. S.; Auger, M. W.; Treu, T.; Park, D.

2018-02-01

A sample of 102 local (0.02=

A single-photon fluorescence and multi-photon spectroscopic study of atherosclerotic lesions

NASA Astrophysics Data System (ADS)

Smith, Michael S. D.; Ko, Alex C. T.; Ridsdale, Andrew; Schattka, Bernie; Pegoraro, Adrian; Hewko, Mark D.; Shiomi, Masashi; Stolow, Albert; Sowa, Michael G.

2009-06-01

In this study we compare the single-photon autofluorescence and multi-photon emission spectra obtained from the luminal surface of healthy segments of artery with segments where there are early atherosclerotic lesions. Arterial tissue was harvested from atherosclerosis-prone WHHL-MI rabbits (Watanabe heritable hyperlipidemic rabbit-myocardial infarction), an animal model which mimics spontaneous myocardial infarction in humans. Single photon fluorescence emission spectra of samples were acquired using a simple spectrofluorometer set-up with 400 nm excitation. Samples were also investigated using a home built multi-photon microscope based on a Ti:sapphire femto-second oscillator. The excitation wavelength was set at 800 nm with a ~100 femto-second pulse width. Epi-multi-photon spectroscopic signals were collected through a fibre-optics coupled spectrometer. While the single-photon fluorescence spectra of atherosclerotic lesions show minimal spectroscopic difference from those of healthy arterial tissue, the multi-photon spectra collected from atherosclerotic lesions show marked changes in the relative intensity of two-photon excited fluorescence (TPEF) and second-harmonic generation (SHG) signals when compared with those from healthy arterial tissue. The observed sharp increase of the relative SHG signal intensity in a plaque is in agreement with the known pathology of early lesions which have increased collagen content.

High excitation rovibrational molecular analysis in warm environments

NASA Astrophysics Data System (ADS)

Zhang, Ziwei; Stancil, Phillip C.; Cumbee, Renata; Ferland, Gary J.

2017-06-01

Inspired by advances in infrared observation (e.g., Spitzer, Herschel and ALMA), we investigate rovibrational emission CO and SiO in warm astrophysical environments. With recent innovation in collisional rate coefficients and rescaling methods, we are able to construct more comprehensive collisional data with high rovibrational states (vibration up to v=5 and rotation up to J=40) and multiple colliders (H2, H and He). These comprehensive data sets are used in spectral simulations with the radiative transfer codes RADEX and Cloudy. We obtained line ratio diagnostic plots and line spectra for both near- and far-infrared emission lines over a broad range of density and temperature for the case of a uniform medium. Considering the importance of both molecules in probing conditions and activities of UV-irradiated interstellar gas, we model rovibrational emission in photodissociation region (PDR) and AGB star envelopes (such as VY Canis Majoris, IK Tau and IRC +10216) with Cloudy. Rotational diagrams, energy distribution diagrams, and spectra are produced to examine relative state abundances, line emission intensity, and other properties. With these diverse models, we expect to have a better understanding of PDRs and expand our scope in the chemical architecture and evolution of AGB stars and other UV-irradiated regions. The soon to be launched James Webb Space Telescope (JWST) will provide high resolution observations at near- to mid-infrared wavelengths, which opens a new window to study molecular vibrational emission calling for more detailed chemical modeling and comprehensive laboratory astrophysics data on more molecules. This work was partially supported by NASA grants NNX12AF42G and NNX15AI61G. We thank Benhui Yang, Kyle Walker, Robert Forrey, and N. Balakrishnan for collaborating on the collisional data adopted in the current work.

Dynamics of ultra-broadband terahertz quantum cascade lasers for comb operation.

PubMed

Li, Hua; Laffaille, Pierre; Gacemi, Djamal; Apfel, Marc; Sirtori, Carlo; Leonardon, Jeremie; Santarelli, Giorgio; Rösch, Markus; Scalari, Giacomo; Beck, Mattias; Faist, Jerome; Hänsel, Wolfgang; Holzwarth, Ronald; Barbieri, Stefano

2015-12-28

We present an experimental investigation of the multimode dynamics and the coherence of terahertz quantum cascade lasers emitting over a spectral bandwidth of ~1THz. The devices are studied in free-running and under direct RF modulation. Depending on the pump current we observe different regimes of operation, where RF spectra displaying single and multiple narrow beat-note signals alternate with spectra showing a single beat-note characterized by an intense phase-noise, extending over a bandwidth up to a few GHz. We investigate the relation between this phase-noise and the dynamics of the THz modes through the electro-optic sampling of the laser emission. We find that when the phase-noise is large, the laser operates in an unstable regime where the lasing modes are incoherent. Under RF modulation of the laser current such instability can be suppressed and the modes coherence recovered, while, simultaneously, generating a strong broadening of the THz emission spectrum.

Sanduleak's Star (LMC Anonymous) - Its similarity in the far-ultraviolet with the luminous object Eta Carinae and SN 1987A

NASA Technical Reports Server (NTRS)

Michalitsianos, A. G.; Kafatos, M.; Shore, S. N.

1989-01-01

Low-resolution IUE SWP spectra of the peculiar object LMC Anonymous (Sanduleak's Star) indicates strong evidence for CNO-processed nebula in the vicinity of the star. The far-UV spectrum of LMC Anonymous closely resembles that of the S Condensation of Eta Carinae. The similarity between LMC Anonymous and the S Condensation is apparent from the absolute intensity of the N V, semiforbidden N IV, and semiforbidden N III emission lines compared with the reduced strength of C IV or semiforbidden C III emission. IUE spectra of the S Condensation and SN 1987A may provide important clues concerning the nature of LMC Anonymous, which indicates departures from normal cosmic abundances of nitrogen relative to carbon that are extreme. This may suggest that carbon envelope burning and dredge-up occurred simultaneously during the helium-burning stage.

Sanduleak's Star (LMC Anonymous) - Its similarity in the far-ultraviolet with the luminous object Eta Carinae and SN 1987A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michalitsianos, A.G.; Kafatos, M.; Shore, S.N.

1989-06-01

Low-resolution IUE SWP spectra of the peculiar object LMC Anonymous (Sanduleak's Star) indicates strong evidence for CNO-processed nebula in the vicinity of the star. The far-UV spectrum of LMC Anonymous closely resembles that of the S Condensation of Eta Carinae. The similarity between LMC Anonymous and the S Condensation is apparent from the absolute intensity of the N V, semiforbidden N IV, and semiforbidden N III emission lines compared with the reduced strength of C IV or semiforbidden C III emission. IUE spectra of the S Condensation and SN 1987A may provide important clues concerning the nature of LMC Anonymous,more » which indicates departures from normal cosmic abundances of nitrogen relative to carbon that are extreme. This may suggest that carbon envelope burning and dredge-up occurred simultaneously during the helium-burning stage. 25 refs.« less

Spectroscopy and energy transfer in lead borate glasses doubly doped with Dy(3)(+)-Tb(3+) and Tb(3)(+)-Eu(3+) ions.

PubMed

Pisarska, Joanna; Kos, Agnieszka; Pisarski, Wojciech A

2014-08-14

Lead borate glasses doubly doped with Dy(3)(+)-Tb(3+) and Tb(3+)-Eu(3+) were investigated using optical spectroscopy. Luminescence spectra of rare earths were detected under various excitation wavelengths. The main green emission band due to (5)D4→(7)F5 transition of Tb(3+) is observed under excitation of Dy(3+), whereas the main red emission band related to (5)D0→(7)F2 transition of Eu(3+) is successfully observed under direct excitation of Tb(3+). In both cases, the energy transfer processes from Dy(3+) to Tb(3+) and from Tb(3+) to Eu(3+) in lead borate glasses occur through a nonradiative processes with efficiencies up to 16% and 18%, respectively. The presence of energy transfer process was also confirmed by excitation spectra measurements. Copyright © 2014 Elsevier B.V. All rights reserved.

Dual color emitting Eu doped strontium orthosilicate phosphors synthesized by bio-template assisted ultrasound for solid state lightning and display applications.

PubMed

Venkataravanappa, M; Nagabhushana, H; Daruka Prasad, B; Darshan, G P; Basavaraj, R B; Vijayakumar, G R

2017-01-01

A novel Sr 2 SiO 4 :Eu (1-5mol %) superstructures (SS) were synthesized using bio-sacrificial A.V. gel assisted ultrasound method. Powder X-ray diffraction patterns confirmed the presence of both α and β phase formation. It was evident that the morphological growth was highly reliant on A.V. gel concentration, sonication time, pH and sonication power. The formation mechanisms for different hierarchical SS were proposed. From diffuse reflectance spectra, the energy band gap was estimated and found to be ∼4.70-5.11eV. The photoluminescence emission spectra for the excitation at 392nm, shows characteristic emission peaks at 593, 613, 654 and 702nm which were attributed to 5 D 0 → 7 F 0 , 7 F 1, 7 F 2 and 7 F 3 transitions of Eu 3+ ions respectively. Conversely, when the samples were subjected to the heat treatment at 850°C for 3h under argon atmosphere, display an intense broad emission peak with two de-convoluted peaks at 490 and 550nm due to 4f 6 5d 1 →4f 1 ( 8 S 7/2 ) transitions of Eu 2+ ions. The concentration quenching phenomenon was discussed which attributes to energy transfer, electron-phonon coupling and ion-ion interaction. The Judd-Ofelt intensity parameters and other radiative properties were estimated by using emission spectra. The CIE chromaticity coordinate values of Sr 2 SiO 4 :Eu 2+ and Eu 3+ nanophosphors were located in green and red regions respectively. The calculated CCT and CRI values specify that the present phosphor can be fairly useful for both green and red components of white LED's. Luminescence decay and quantum yield suggest the suitability of this phosphor as an efficient luminescent medium for light emitting diodes. Overall, the results elucidated a rapid, environmentally benign, cost-effective and convenient method for Sr 2 SiO 4 :Eu 3+ synthesis and for the possible applications such as solid state lighting and display devices. Copyright © 2016 Elsevier B.V. All rights reserved.

Förster resonance energy transfer, absorption and emission spectra in multichromophoric systems. III. Exact stochastic path integral evaluation.

PubMed

Moix, Jeremy M; Ma, Jian; Cao, Jianshu

2015-03-07

A numerically exact path integral treatment of the absorption and emission spectra of open quantum systems is presented that requires only the straightforward solution of a stochastic differential equation. The approach converges rapidly enabling the calculation of spectra of large excitonic systems across the complete range of system parameters and for arbitrary bath spectral densities. With the numerically exact absorption and emission operators, one can also immediately compute energy transfer rates using the multi-chromophoric Förster resonant energy transfer formalism. Benchmark calculations on the emission spectra of two level systems are presented demonstrating the efficacy of the stochastic approach. This is followed by calculations of the energy transfer rates between two weakly coupled dimer systems as a function of temperature and system-bath coupling strength. It is shown that the recently developed hybrid cumulant expansion (see Paper II) is the only perturbative method capable of generating uniformly reliable energy transfer rates and emission spectra across a broad range of system parameters.

Life-cycle assessment of transportation biofuels from hydrothermal liquefaction of forest residues in British Columbia.

PubMed

Nie, Yuhao; Bi, Xiaotao

2018-01-01

Biofuels from hydrothermal liquefaction (HTL) of abundantly available forest residues in British Columbia (BC) can potentially make great contributions to reduce the greenhouse gas (GHG) emissions from the transportation sector. A life-cycle assessment was conducted to quantify the GHG emissions of a hypothetic 100 million liters per year HTL biofuel system in the Coast Region of BC. Three scenarios were defined and investigated, namely, supply of bulky forest residues for conversion in a central integrated refinery (Fr-CIR), HTL of forest residues to bio-oil in distributed biorefineries and subsequent upgrading in a central oil refinery (Bo-DBR), and densification of forest residues in distributed pellet plants and conversion in a central integrated refinery (Wp-CIR). The life-cycle GHG emissions of HTL biofuels is 20.5, 17.0, and 19.5 g CO 2 -eq/MJ for Fr-CIR, Bo-DBR, and Wp-CIR scenarios, respectively, corresponding to 78-82% reduction compared with petroleum fuels. The conversion stage dominates the total GHG emissions, making up more than 50%. The process emitting most GHGs over the life cycle of HTL biofuels is HTL buffer production. Transportation emission, accounting for 25% of Fr-CIR, can be lowered by 83% if forest residues are converted to bio-oil before transportation. When the credit from biochar applied for soil amendment is considered, a further reduction of 6.8 g CO 2 -eq/MJ can be achieved. Converting forest residues to bio-oil and wood pellets before transportation can significantly lower the transportation emission and contribute to a considerable reduction of the life-cycle GHG emissions. Process performance parameters (e.g., HTL energy requirement and biofuel yield) and the location specific parameter (e.g., electricity mix) have significant influence on the GHG emissions of HTL biofuels. Besides, the recycling of the HTL buffer needs to be investigated to further improve the environmental performance of HTL biofuels.

NOAA's Van-Based Mobile Atmospheric Emissions Measurement Laboratory

NASA Astrophysics Data System (ADS)

Dube, W. P.; Peischl, J.; Neuman, J. A.; Eilerman, S. J.; Holloway, M.; Roberts, O.; Aikin, K. C.; Ryerson, T. B.

2015-12-01

The Chemical Science Division (CSD) mobile atmospheric emissions measurement laboratory is the second and latest of two mobile measurement vans outfitted for atmospheric sampling by the NOAA Earth System Research Laboratory. In this presentation we will describe the modifications made to this vehicle to provide a versatile and relatively inexpensive instrument platform including: the 2 kW 120 volt instrument power system; battery back-up system; data acquisition system; real-time display; meteorological, directional, and position sensor package; and the typical atmospheric emissions instrument package. The van conversion uses commercially available, off-the-shelf components from the marine and RV industries, thus keeping the costs quite modest.

Nano-optomechanical transducer

DOEpatents

Rakich, Peter T; El-Kady, Ihab F; Olsson, Roy H; Su, Mehmet Fatih; Reinke, Charles; Camacho, Ryan; Wang, Zheng; Davids, Paul

2013-12-03

A nano-optomechanical transducer provides ultrabroadband coherent optomechanical transduction based on Mach-wave emission that uses enhanced photon-phonon coupling efficiencies by low impedance effective phononic medium, both electrostriction and radiation pressure to boost and tailor optomechanical forces, and highly dispersive electromagnetic modes that amplify both electrostriction and radiation pressure. The optomechanical transducer provides a large operating bandwidth and high efficiency while simultaneously having a small size and minimal power consumption, enabling a host of transformative phonon and signal processing capabilities. These capabilities include optomechanical transduction via pulsed phonon emission and up-conversion, broadband stimulated phonon emission and amplification, picosecond pulsed phonon lasers, broadband phononic modulators, and ultrahigh bandwidth true time delay and signal processing technologies.

Emission from water vapor and absorption from other gases at 5-7.5 μm in Spitzer-IRS Spectra Of Protoplanetary Disks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sargent, B. A.; Forrest, W.; Watson, Dan M.

We present spectra of 13 T Tauri stars in the Taurus-Auriga star-forming region showing emission in Spitzer Space Telescope Infrared Spectrograph 5-7.5 μm spectra from water vapor and absorption from other gases in these stars' protoplanetary disks. Seven stars' spectra show an emission feature at 6.6 μm due to the ν{sub 2} = 1-0 bending mode of water vapor, with the shape of the spectrum suggesting water vapor temperatures >500 K, though some of these spectra also show indications of an absorption band, likely from another molecule. This water vapor emission contrasts with the absorption from warm water vapor seenmore » in the spectrum of the FU Orionis star V1057 Cyg. The other 6 of the 13 stars have spectra showing a strong absorption band, peaking in strength at 5.6-5.7 μm, which for some is consistent with gaseous formaldehyde (H{sub 2}CO) and for others is consistent with gaseous formic acid (HCOOH). There are indications that some of these six stars may also have weak water vapor emission. Modeling of these stars' spectra suggests these gases are present in the inner few AU of their host disks, consistent with recent studies of infrared spectra showing gas in protoplanetary disks.« less

The role of ultraviolet-A reflectance and ultraviolet-A induced fluorescence in the appearance of budgerigar plumage: insights from spectrofluorometry and reflectance spectrophotometry.

PubMed Central

Pearn, Sophie M; Bennett, Andrew T D; Cuthill, Innes C

2003-01-01

Fluorescence has so far been found in 52 parrot species when illuminated with ultraviolet-A (UVA) 'black' lamps, and two attempts have been made to determine whether such fluorescence plays any role in sexual signalling. However, the contribution of the reflectance versus fluorescence to the total radiance from feathers, even in the most studied species to date (budgerigars), is unclear. Nor has the plumage of this study species been systematically assessed to determine the distribution of fluorescent patches. We therefore used spectrofluorometry to determine which areas of budgerigars fluoresce and the excitation and emission spectra involved; this is the first time that such a technique has been applied to avian plumage. We found that both the yellow crown and (normally hidden) white downy chest feathers exhibit strong UVA-induced fluorescence, with peak emissions at 527 nm and 436 nm, respectively. Conversely, the bright-green chest and dark-blue tail feathers do not fluoresce. When comparing reflectance spectra (400-700 nm) from the yellow crown using illuminants with a proportion of UVA comparable to daylight, and illuminants with all UVA removed, no measurable difference resulting from fluorescence was found. This suggests that under normal daylight the contribution of fluorescence to radiance is probably trivial. Furthermore, these spectra revealed that males had fluorescent crowns with substantially higher reflectance than those of females, in both the UV waveband and at longer wavelengths. Reflectance spectrophotometry was also performed on a number of live wild-type male budgerigars to investigate the chromatic contrast between the different plumage areas. This showed that many plumage regions are highly UV-reflective. Overall our results suggest that rapid surveys using UVA black lamps may overestimate the contribution of fluorescence to plumage coloration, and that any signalling role of fluorescence emissions, at least from the yellow crown of budgerigars, may not be as important as previously thought. PMID:12737665

Properties and Spatial Distribution of Dust Emission in the Crab Nebula

NASA Technical Reports Server (NTRS)

Sonneborn, G.; Temim, T.; Dwek, E.; Arendt, R.; Gehrz, R.; Slane, P.

2011-01-01

The nature and quantity of dust produced in supernovae (SNe) is still poorly understood. Recent IR observations of freshly-formed dust in supernova remnants (SNRs) have yielded significantly lower dust masses than predicted by theoretical models and observations high-redshift galaxies. The Crab Nebula's pulsar wind is thought to be sweeping up freshly-formed SN dust along with the SN ejecta. The evidence for this dust was found in the form of an IR bump in the integrated spectrum of the Crab and in extinction against the synchrotron nebula that revealed the presence of dust in the filament cores. We present the first spatially-resolved emission spectra of dust in the Crab Nebula acquired with the Spitzer Space Telescope. The IR spectra are dominated by synchrotron emission and show forbidden line emission from both sides of the expanding nebula, including emission from [S III], [Si II], [Ne II], [Ne III], [Ne V], [Ar III], [Ar V], [Fe II], and [Ni II]. We extrapolated a synchrotron spectral data cube from the Spitzer 3.6 and 4.5 micron images, and subtracted this contribution from our 15-40 micron spectral data to produce a map of the residual continuum emission from dust. The emission appears to be concentrated along the ejecta filaments and is well described by astronomical silicates at an average temperature of 65 K. The estimated mass of dust in the Crab Nebula is 0.008 solar masses.

Concentration dependence of luminescence efficiency of Dy3+ ions in strontium zinc phosphate glasses mixed with Pb3 O4.

PubMed

Kumar, Valluri Ravi; Giridhar, G; Veeraiah, N

2017-02-01

In this work we synthesized SrO-ZnO-P 2 O 5 glasses mixed with Pb 3 O 4 (heavy metal oxide) and doped with different amounts of Dy 2 O 3 (0.1 to 1.0 mol%). Subsequently their emission and decay characteristics were investigated as a function of Dy 2 O 3 concentration. The emission spectra exhibited three principal emission bands in the visible region corresponding to 4 F 9 /2  →  6 H 15 /2 (482 nm), 6 H 13 /2 (574 nm) and 6 H 11 /2 (663 nm) transitions. With increase in the concentration of Dy 2 O 3 (upto 0.8 mol%) a considerable increase in the intensity of these bands was observed and, for further increase, quenching of photoluminescence (PL) output was observed. Using emission spectra, various radiative parameters were evaluated and all these parameters were found to increase with increase in Dy 2 O 3 concentration. The Y/B integral emission intensity ratio of Dy 3 + ions evaluated from these spectra exhibited a decreasing trend with increase in the Dy 2 O 3 concentration up to 0.8 mol%. Quenching of luminescence observed in the case of the glasses doped with 1.0 mol% is attributed to clustering of Dy 3 + ions. The quantitative analysis of these results together with infra-red (IR) spectral studies indicated that 0.8 mol% is the optimum concentration of Dy 3 + ions needed to achieve maximum luminescence efficiency. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Up-conversion in an Er-containing nanocomposite and microlasers based on it

NASA Astrophysics Data System (ADS)

Sobeshchuk, N. O.; Denisyuk, I. Yu.

2017-06-01

The results of an investigation of three-dimensional polymer microcavities doped with inorganic luminescent particles are presented. Microlasers in the form of rectangular parallelepipeds were fabricated based on the SU8 2025 photoresist by means of compact UV lithography. Luminescent particles containing erbium oxide were obtained by low-temperature synthesis of the corresponding chlorides in a nonaqueous medium. The obtained spectra confirm the presence of a narrowband laser radiation exhibiting a Stokes shift.

SLUG - stochastically lighting up galaxies - III. A suite of tools for simulated photometry, spectroscopy, and Bayesian inference with stochastic stellar populations

NASA Astrophysics Data System (ADS)

Krumholz, Mark R.; Fumagalli, Michele; da Silva, Robert L.; Rendahl, Theodore; Parra, Jonathan

2015-09-01

Stellar population synthesis techniques for predicting the observable light emitted by a stellar population have extensive applications in numerous areas of astronomy. However, accurate predictions for small populations of young stars, such as those found in individual star clusters, star-forming dwarf galaxies, and small segments of spiral galaxies, require that the population be treated stochastically. Conversely, accurate deductions of the properties of such objects also require consideration of stochasticity. Here we describe a comprehensive suite of modular, open-source software tools for tackling these related problems. These include the following: a greatly-enhanced version of the SLUG code introduced by da Silva et al., which computes spectra and photometry for stochastically or deterministically sampled stellar populations with nearly arbitrary star formation histories, clustering properties, and initial mass functions; CLOUDY_SLUG, a tool that automatically couples SLUG-computed spectra with the CLOUDY radiative transfer code in order to predict stochastic nebular emission; BAYESPHOT, a general-purpose tool for performing Bayesian inference on the physical properties of stellar systems based on unresolved photometry; and CLUSTER_SLUG and SFR_SLUG, a pair of tools that use BAYESPHOT on a library of SLUG models to compute the mass, age, and extinction of mono-age star clusters, and the star formation rate of galaxies, respectively. The latter two tools make use of an extensive library of pre-computed stellar population models, which are included in the software. The complete package is available at http://www.slugsps.com.

On the X-ray spectra of luminous, inhomogeneous accretion flows

NASA Astrophysics Data System (ADS)

Merloni, A.; Malzac, J.; Fabian, A. C.; Ross, R. R.

2006-08-01

We discuss the expected X-ray spectral and variability properties of black hole accretion discs at high luminosity, under the hypothesis that radiation-pressure-dominated discs are subject to violent clumping instabilities and, as a result, have a highly inhomogeneous two-phase structure. After deriving the full accretion disc solutions explicitly in terms of the parameters of the model, we study their radiative properties both with a simple two-zone model, treatable analytically, and with radiative transfer simulations which account simultaneously for energy balance and Comptonization in the hot phase, together with reflection, reprocessing, ionization and thermal balance in the cold phase. We show that, if not only the density, but also the heating rate within these flows is inhomogeneous, then complex reflection-dominated spectra can be obtained for a high enough covering fraction of the cold phase. In general, large reflection components in the observed X-ray spectra should be associated with strong soft excesses, resulting from the combined emission of ionized atomic emission lines. The variability properties of such systems are such that, even when contributing to a large fraction of the hard X-ray spectrum, the reflection component is less variable than the power-law-like emission originating from the hot Comptonizing phase, in agreement with what is observed in many Narrow Line Seyfert 1 galaxies and bright Seyfert 1. Our model falls within the family of those trying to explain the complex X-ray spectra of bright AGN with ionized reflection, but presents an alternative, specific, physically motivated, geometrical set-up for the complex multiphase structure of the inner regions of near-Eddington accretion flows.

TD-M06-2X insights into the absorption and emission spectra of dichlorvos and its molecularly imprinted recognition by methacrylic acid.

PubMed

Cheng, Xueli

2016-11-01

The absorption and emission spectra of dichlorvos and the dichlorvos-MAA complex in methanol, water, and chloroform in the molecularly imprinted recognition were investigated systematically. The M06-2X results revealed that: 1) the hydroxyl groups in polar solvents such as methanol and water may markedly influence the weak interactions, and then alter the adsorption and emission spectra; 2) the electronic excitation in absorption spectra of dichlorvos is dominated by the configuration HOMO → LUMO, but in the most stable dichlorvos-MAA it becomes the ππ* excitation of HOMO → LUMO + 1; 3) Mulliken charges reveal that dichlorvos almost dissociates to Cl - and a cation in its S 1 excitation state; 4) the phosphorescence spectra of dichlorvos-MAA are relatively weak. Graphical Abstract The absorption and emission spectra of dichlorvos and the dichlorvos-MAA complex in the molecularly imprinted recognition of dichlorvos were investigated systematically in methanol, water, and chloroform as solvents.

Studies of the DOM aqueous extracts from coastal marine sediments

NASA Astrophysics Data System (ADS)

Sakellariadou, F.

2012-04-01

Dissolved organic matter (DOM) represents a major exchangeable organic pool playing an outstanding role in the ocean carbon cycle. It has a complex chemical structure made up of a wide range of organic molecules. The composition of DOM depends on the sources proximity and the exposure to any sort of degradation mechanism. The coloured (or chromophoric) dissolved organic matter (CDOM), representing the optically active fraction of DOM, consists of aromatic rings able to absorb light in the visible and UV regions (Kirk, 1994) and fluorophoric molecules that emit light. The main fluorophoric moieties of CDOM are humic material with a blue fluorescence and protein material with an ultraviolet (UV) fluorescence (Mopper and Schultz, 1993). Dissolved organic matter interacts with pollutants either by enhancing their bioavailability or by influencing their transportation to the soluble phase. In addition, DOM affects the remineralisation of carbon and its preservation in marine sediments. Referring to its origin, it can be terrestrial, freshwater or marine one. Fluorescence spectroscopy is a technique widely applied for the identification and characterization of organic matter, being fast, simple, non-destructive and sensitive. In addition, the fluorescence analysis for the physico-chemical characterization of organic matter requires a small amount of aqueous sample at a low concentration, in comparison with the large sample volumes needed for conventional techniques. At the present study coastal sediment samples were collected from Messiniakos gulf in the south western Peloponnese in South Greece. Messiniakos gulf has a seabed dominated by very abrupt inclinations reaching depths of more than 1000m. All samples, according to their grain size, are classified as fine clayey silt. Dissolved organic matter was extracted under gentle extraction conditions (4 mM CaCl2 solution). The various classes of organic components present at the DOM aqueous extracts were characterised by fluorescence spectroscopy technique as DOM fluorescence is a property furnishing valuable information for its composition and biogeochemical cycling. Fluorescence spectra were recorded using a Perkin-Elmer LS 55 luminescence spectrophotometer equipped with the WinLab 4.00.02 software for data processing. Conventional mono-dimensional emission, excitation and synchronous-scan excitation spectra were recorded. Mono dimensional emission spectra were recorded over the range 380-600 nm at a constant excitation wavelength of 360 nm. Excitation spectra were recorded over the range 300-500 nm at a fixed emission wavelength of 520 nm. Synchronous-scan excitation spectra were measured by scanning simultaneously both the excitation and the emission wavelengths (from 300 to 550 nm), while maintaining a constant, optimised wavelength difference Δλ (λem - λexc) = 18 nm. (Senesi et al., 1991). Total Luminescence Spectra (3D fluorescence spectra) were obtained in the form of excitation/emission matrix spectra (or contour maps) by scanning the wavelength emission over the range 300 to 600 nm, while the excitation wavelength was increased sequentially by 5-nm steps from 250 to 500 nm. In comparison with the limited provided information from the conventional fluorescence spectroscopy, EEM analysis seems to be sufficiently sensitive to distinguish between the various types of marine gelbstoff as well as to help estimating the contribution of each of them. Humification indices according to Ohno (2002) and Zsolnay (1999) were calculated. The Humification index (HIX) according to Ohno is calculated by dividing the emission intensity in the 435 to 480 nm region by the emission intensity in the 300 to 345 nm region; HIX quantifies the red shift of the emission spectra toward longer wavelengths with increasing humification. The HI index according to Zsolnay is defined as the area in the upper quarter (Σ435-480nm) of the usable emission peak divided by the area in the lower usable quarter (Σ300-445nm). All fluorescence spectra were thoroughly evaluated for the classification of chromophoric units present. Variations were observed according to the sampling site and more precisely its proximity to the coastline and the corresponding water column's depth; the oceanographic characteristics allowing or obstructing sea water circulation; as well as the proximity of each sample to the seabed, in other words the characterization of each sediment sample as surface of subsurface one.

Nuclear Neutrino Spectra in Late Stellar Evolution

NASA Astrophysics Data System (ADS)

Misch, G. Wendell; Sun, Yang; Fuller, George

2018-05-01

Neutrinos are the principle carriers of energy in massive stars, beginning from core carbon burning and continuing through core collapse and after the core bounce. In fact, it may be possible to detect neutrinos from nearby pre-supernova stars. Therefore, it is of great interest to understand the neutrino energy spectra from these stars. Leading up to core collapse, beginning around core silicon burning, nuclei become dominant producers of neutrinos, particularly at high neutrino energy, so a systematic study of nuclear neutrino spectra is desirable. We have done such a study, and we present our sd-shell model calculations of nuclear neutrino energy spectra for nuclei in the mass number range A = 21 - 35. Our study includes neutrinos produced by charged lepton capture, charged lepton emission, and neutral current nuclear deexcitation. Previous authors have tabulated the rates of charged current nuclear weak interactions in astrophysical conditions, but the present work expands on this not only by providing neutrino energy spectra, but also by including the heretofore untabulated neutral current de-excitation neutrino pairs.

Planck 2013 results. IX. HFI spectral response

NASA Astrophysics Data System (ADS)

Planck Collaboration; Ade, P. A. R.; Aghanim, N.; Armitage-Caplan, C.; Arnaud, M.; Ashdown, M.; Atrio-Barandela, F.; Aumont, J.; Baccigalupi, C.; Banday, A. J.; Barreiro, R. B.; Battaner, E.; Benabed, K.; Benoît, A.; Benoit-Lévy, A.; Bernard, J.-P.; Bersanelli, M.; Bielewicz, P.; Bobin, J.; Bock, J. J.; Bond, J. R.; Borrill, J.; Bouchet, F. R.; Boulanger, F.; Bridges, M.; Bucher, M.; Burigana, C.; Cardoso, J.-F.; Catalano, A.; Challinor, A.; Chamballu, A.; Chary, R.-R.; Chen, X.; Chiang, H. C.; Chiang, L.-Y.; Christensen, P. R.; Church, S.; Clements, D. L.; Colombi, S.; Colombo, L. P. L.; Combet, C.; Comis, B.; Couchot, F.; Coulais, A.; Crill, B. P.; Curto, A.; Cuttaia, F.; Danese, L.; Davies, R. D.; de Bernardis, P.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Delouis, J.-M.; Désert, F.-X.; Dickinson, C.; Diego, J. M.; Dole, H.; Donzelli, S.; Doré, O.; Douspis, M.; Dupac, X.; Efstathiou, G.; Enßlin, T. A.; Eriksen, H. K.; Falgarone, E.; Finelli, F.; Forni, O.; Frailis, M.; Franceschi, E.; Galeotta, S.; Ganga, K.; Giard, M.; Giraud-Héraud, Y.; González-Nuevo, J.; Górski, K. M.; Gratton, S.; Gregorio, A.; Gruppuso, A.; Hansen, F. K.; Hanson, D.; Harrison, D.; Henrot-Versillé, S.; Hernández-Monteagudo, C.; Herranz, D.; Hildebrandt, S. R.; Hivon, E.; Hobson, M.; Holmes, W. A.; Hornstrup, A.; Hovest, W.; Huffenberger, K. M.; Hurier, G.; Jaffe, A. H.; Jaffe, T. R.; Jones, W. C.; Juvela, M.; Keihänen, E.; Keskitalo, R.; Kisner, T. S.; Kneissl, R.; Knoche, J.; Knox, L.; Kunz, M.; Kurki-Suonio, H.; Lagache, G.; Lamarre, J.-M.; Lasenby, A.; Laureijs, R. J.; Lawrence, C. R.; Leahy, J. P.; Leonardi, R.; Leroy, C.; Lesgourgues, J.; Liguori, M.; Lilje, P. B.; Linden-Vørnle, M.; López-Caniego, M.; Lubin, P. M.; Macías-Pérez, J. F.; Maffei, B.; Mandolesi, N.; Maris, M.; Marshall, D. J.; Martin, P. G.; Martínez-González, E.; Masi, S.; Massardi, M.; Matarrese, S.; Matthai, F.; Mazzotta, P.; McGehee, P.; Melchiorri, A.; Mendes, L.; Mennella, A.; Migliaccio, M.; Mitra, S.; Miville-Deschênes, M.-A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Munshi, D.; Murphy, J. A.; Naselsky, P.; Nati, F.; Natoli, P.; Netterfield, C. B.; Nørgaard-Nielsen, H. U.; North, C.; Noviello, F.; Novikov, D.; Novikov, I.; Osborne, S.; Oxborrow, C. A.; Paci, F.; Pagano, L.; Pajot, F.; Paoletti, D.; Pasian, F.; Patanchon, G.; Perdereau, O.; Perotto, L.; Perrotta, F.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Pietrobon, D.; Plaszczynski, S.; Pointecouteau, E.; Polenta, G.; Ponthieu, N.; Popa, L.; Poutanen, T.; Pratt, G. W.; Prézeau, G.; Prunet, S.; Puget, J.-L.; Rachen, J. P.; Reinecke, M.; Remazeilles, M.; Renault, C.; Ricciardi, S.; Riller, T.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Roudier, G.; Rusholme, B.; Santos, D.; Savini, G.; Scott, D.; Shellard, E. P. S.; Spencer, L. D.; Starck, J.-L.; Stolyarov, V.; Stompor, R.; Sudiwala, R.; Sureau, F.; Sutton, D.; Suur-Uski, A.-S.; Sygnet, J.-F.; Tauber, J. A.; Tavagnacco, D.; Terenzi, L.; Tomasi, M.; Tristram, M.; Tucci, M.; Umana, G.; Valenziano, L.; Valiviita, J.; Van Tent, B.; Vielva, P.; Villa, F.; Vittorio, N.; Wade, L. A.; Wandelt, B. D.; Yvon, D.; Zacchei, A.; Zonca, A.

2014-11-01

The Planck High Frequency Instrument (HFI) spectral response was determined through a series of ground based tests conducted with the HFI focal plane in a cryogenic environment prior to launch. The main goal of the spectral transmission tests was to measure the relative spectral response (includingthe level of out-of-band signal rejection) of all HFI detectors to a known source of electromagnetic radiation individually. This was determined by measuring the interferometric output of a continuously scanned Fourier transform spectrometer with all HFI detectors. As there is no on-board spectrometer within HFI, the ground-based spectral response experiments provide the definitive data set for the relative spectral calibration of the HFI. Knowledge of the relative variations in the spectral response between HFI detectors allows for a more thorough analysis of the HFI data. The spectral response of the HFI is used in Planck data analysis and component separation, this includes extraction of CO emission observed within Planck bands, dust emission, Sunyaev-Zeldovich sources, and intensity to polarization leakage. The HFI spectral response data have also been used to provide unit conversion and colour correction analysis tools. While previous papers describe the pre-flight experiments conducted on the Planck HFI, this paper focusses on the analysis of the pre-flight spectral response measurements and the derivation of data products, e.g. band-average spectra, unit conversion coefficients, and colour correction coefficients, all with related uncertainties. Verifications of the HFI spectral response data are provided through comparisons with photometric HFI flight data. This validation includes use of HFI zodiacal emission observations to demonstrate out-of-band spectral signal rejection better than 108. The accuracy of the HFI relative spectral response data is verified through comparison with complementary flight-data based unit conversion coefficients and colour correction coefficients. These coefficients include those based upon HFI observations of CO, dust, and Sunyaev-Zeldovich emission. General agreement is observed between the ground-based spectral characterization of HFI and corresponding in-flight observations, within the quoted uncertainty of each; explanations are provided for any discrepancies.

Terahertz injection lasers based on PbSnSe alloy with an emission wavelength up to 46.5 μm

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maremyanin, K. V., E-mail: kirillm@ipmras.ru; Rumyantsev, V. V.; Ikonnikov, A. V.

2016-12-15

Diffusion injection lasers based on Pb{sub 1} {sub –} {sub x}Sn{sub x}Se alloy, emitting in a wide spectral range of 10–46.5 μm depending on the composition and temperatures are fabricated. A technology for growing high-quality single crystals from the vapor phase under conditions of free growth is developed. The dependences of the total emission intensity on the pump current and the emission spectra of injection lasers based on Pb{sub 1–x}Sn{sub x}Se are studied. In these samples, lasing of long-wavelength radiation to a record wavelength of 46.5 μm is achieved.

The Zone of Avoidance as an X-ray absorber - the role of the galactic foreground modelling Swift XRT spectra

NASA Astrophysics Data System (ADS)

Racz, I. I.; Bagoly, Z.; Tóth, L. V.; Balázs, L. G.; Horvath, I.; Zahorecz, S.

2018-05-01

Gamma-ray bursts (GRBs) are the most powerful explosive events in the Universe. The prompt gamma emission is followed by an X-ray afterglow that is also detected for over nine hundred GRBs by the Swift BAT and XRT detectors. The X-ray afterglow spectrum bears essential information about the burst, and the surrounding interstellar medium (ISM). Since the radiation travels through the line of sight intergalactic medium and the ISM in the Milky Way, the observed emission is influenced by extragalactic and galactic components. The column density of the Galactic foreground ranges several orders of magnitudes, due to both the large scale distribution of ISM and its small scale structures. We examined the effect of local HI column density on the penetrating X-ray emission, as the first step towards a precise modeling of the measured X-ray spectra. We fitted the X-ray spectra using the Xspec software, and checked how the shape of the initially power low spectrum changes with varying input Galactic HI column density. The total absorbing HI column is a sum of the intrinsic and Galactic component. We also investigated the model results for the intrinsic component varying the Galactic foreground. We found that such variations may alter the intrinsic hydrogen column density up to twenty-five percent. We will briefly discuss its consequences.

Measurements and parameterization of neutron energy spectra from targets bombarded with 120 GeV protons

NASA Astrophysics Data System (ADS)

Kajimoto, T.; Shigyo, N.; Sanami, T.; Iwamoto, Y.; Hagiwara, M.; Lee, H. S.; Soha, A.; Ramberg, E.; Coleman, R.; Jensen, D.; Leveling, A.; Mokhov, N. V.; Boehnlein, D.; Vaziri, K.; Sakamoto, Y.; Ishibashi, K.; Nakashima, H.

2014-10-01

The energy spectra of neutrons were measured by a time-of-flight method for 120 GeV protons on thick graphite, aluminum, copper, and tungsten targets with an NE213 scintillator at the Fermilab Test Beam Facility. Neutron energy spectra were obtained between 25 and 3000 MeV at emission angles of 30°, 45°, 120°, and 150°. The spectra were parameterized as neutron emissions from three moving sources and then compared with theoretical spectra calculated by PHITS and FLUKA codes. The yields of the theoretical spectra were substantially underestimated compared with the yields of measured spectra. The integrated neutron yields from 25 to 3000 MeV calculated with PHITS code were 16-36% of the experimental yields and those calculated with FLUKA code were 26-57% of the experimental yields for all targets and emission angles.

Broadband high-frequency waves and intermittent energy conversion at dipolarization fronts

NASA Astrophysics Data System (ADS)

Yang, J.; Cao, J.; Fu, H.; Wang, T.; Liu, W.; Yao, Z., Sr.

2017-12-01

Dipolarization front (DF) is a sharp boundary most probably separating the reconnection jet from the background plasma sheet. So far at this boundary, the observed waves are mainly in low-frequency range (e.g., magnetosonic waves and lower hybrid waves). Few high-frequency waves are observed in this region. In this paper, we report the broadband high-frequency wave emissions at the DF. These waves, having frequencies extending from the electron cyclotron frequency fce, up to the electron plasma frequency fpe, could contribute 10% to the in situ measurement of intermittent energy conversion at the DF layer. Their generation may be attributed to electron beams, which are simultaneously observed at the DF as well. Furthermore, we find intermittent energy conversion is primarily to the broadband fluctuations in the lower hybrid frequency range although the net energy conversion is small.

Extreme ultraviolet emission spectra of Gd and Tb ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kilbane, D.; O'Sullivan, G.

2010-11-15

Theoretical extreme ultraviolet emission spectra of gadolinium and terbium ions calculated with the Cowan suite of codes and the flexible atomic code (FAC) relativistic code are presented. 4d-4f and 4p-4d transitions give rise to unresolved transition arrays in a range of ions. The effects of configuration interaction are investigated for transitions between singly excited configurations. Optimization of emission at 6.775 nm and 6.515 nm is achieved for Gd and Tb ions, respectively, by consideration of plasma effects. The resulting synthetic spectra are compared with experimental spectra recorded using the laser produced plasma technique.

40 CFR 61.67 - Emission tests.

Code of Federal Regulations, 2011 CFR

2011-07-01

... = Conversion factor from ppmw to units of emission standard, 0.001 (metric units) = 0.002 (English units) PPVC...(a), or § 61.64(a)(1), (b), (c), or (d), or from any control system to which reactor emissions are... conversion factor, 1,000 g/kg (1 lb/lb). 10−6 = Conversion factor for ppm. Z = Production rate, kg/hr (lb/hr...

40 CFR 61.67 - Emission tests.

Code of Federal Regulations, 2012 CFR

2012-07-01

... = Conversion factor from ppmw to units of emission standard, 0.001 (metric units) = 0.002 (English units) PPVC...(a), or § 61.64(a)(1), (b), (c), or (d), or from any control system to which reactor emissions are... conversion factor, 1,000 g/kg (1 lb/lb). 10−6 = Conversion factor for ppm. Z = Production rate, kg/hr (lb/hr...

The 8-13 micron spectra of comets and the composition of silicate grains

NASA Technical Reports Server (NTRS)

Hanner, Martha S.; Lynch, David K.; Russell, Ray W.

1994-01-01

We have analyzed the existing spectra of seven comets which show an emission feature at 7.8-13 micrometers. Most have been converted to a common calibration, taking into account the SiO feature in late-type standard stars. The spectra are compared with spectra of the Trapezium, interplanetary dust particles (IDPs), laboratory mineral samples, and small particle emission models. The emission spectra show a variety of shapes; there is no unique 'cometary silicate'. A peak at 11.20-11.25 micrometers, indicative of small crystalline olivine particles, is seen in only three comets of this sample, P/Halley, Bradfield 1987 XXIX, and Levy 1990 XX. The widths of the emission features range from 2.6 to 4.1 micrometers (FWHM). To explain the differing widths and the broad 9.8 micrometers maximum, glassy silicate particles, including both pyroxene and olivine compositions, are the most plausible candidates. Calculations of emission models confirm that small grains of glassy silicate well mixed with carbonaceous material are plausible cometary constituents. No single class of chondritic aggregate IDPs exhibits spectra closely matching the comet spectra. A mixture of IDP spectra, particularly the glass-rich aggregates, approximately matches the spectra of comets P/Halley, Levy, and Bradfield 1987 XXIX. Yet, if comets are simply a mix of IDP types, it is puzzling that the classes of IDPs are so distinct. None of the comet spectra match the spectrum of the Trapezium. Thus, the mineralogy of the cometary silicates is not the same as that of the interstellar medium. The presence of a component of crystalline silicates in comets may be evidence of mixing between high- and low-temperature regions in the solar nebula.

New Constraints on the Geometry and Kinematics of Matter Surrounding the Accretion Flow in X-Ray Binaries from Chandra High-Energy Transmission Grating X-Ray Spectroscopy

NASA Technical Reports Server (NTRS)

Tzanavaris, P.; Yaqoob, T.

2018-01-01

The narrow, neutral Fe Ka fluorescence emission line in X-ray binaries (XRBs) is a powerful probe of the geometry, kinematics, and Fe abundance of matter around the accretion flow. In a recent study it has been claimed, using Chandra High-Energy Transmission Grating (HETG) spectra for a sample of XRBs, that the circumnuclear material is consistent with a solar-abundance, uniform, spherical distribution. It was also claimed that the Fe Ka line was unresolved in all cases by the HETG. However, these conclusions were based on ad hoc models that did not attempt to relate the global column density to the Fe Ka line emission. We revisit the sample and test a self-consistent model of a uniform, spherical X-ray reprocessor against HETG spectra from 56 observations of 14 Galactic XRBs. We find that the model is ruled out in 13/14 sources because a variable Fe abundance is required. In two sources a spherical distribution is viable, but with nonsolar Fe abundance. We also applied a solar-abundance Compton-thick reflection model, which can account for the spectra that are inconsistent with a spherical model, but spectra with a broader bandpass are required to better constrain model parameters. We also robustly measured the velocity width of the Fe Ka line and found FWHM values of up to approx. 5000 km/s. Only in some spectra was the Fe Ka line unresolved by the HETG.

Dissecting Reactor Antineutrino Flux Calculations

NASA Astrophysics Data System (ADS)

Sonzogni, A. A.; McCutchan, E. A.; Hayes, A. C.

2017-09-01

Current predictions for the antineutrino yield and spectra from a nuclear reactor rely on the experimental electron spectra from 235U, 239Pu, 241Pu and a numerical method to convert these aggregate electron spectra into their corresponding antineutrino ones. In the present work we investigate quantitatively some of the basic assumptions and approximations used in the conversion method, studying first the compatibility between two recent approaches for calculating electron and antineutrino spectra. We then explore different possibilities for the disagreement between the measured Daya Bay and the Huber-Mueller antineutrino spectra, including the 238U contribution as well as the effective charge and the allowed shape assumption used in the conversion method. We observe that including a shape correction of about +6 % MeV-1 in conversion calculations can better describe the Daya Bay spectrum. Because of a lack of experimental data, this correction cannot be ruled out, concluding that in order to confirm the existence of the reactor neutrino anomaly, or even quantify it, precisely measured electron spectra for about 50 relevant fission products are needed. With the advent of new rare ion facilities, the measurement of shape factors for these nuclides, for many of which precise beta intensity data from TAGS experiments already exist, would be highly desirable.

Dissecting Reactor Antineutrino Flux Calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sonzogni, A. A.; McCutchan, E. A.; Hayes, A. C.

2017-09-15

Current predictions for the antineutrino yield and spectra from a nuclear reactor rely on the experimental electron spectra from 235 U , 239 Pu , 241 Pu and a numerical method to convert these aggregate electron spectra into their corresponding antineutrino ones. In our present work we investigate quantitatively some of the basic assumptions and approximations used in the conversion method, studying first the compatibility between two recent approaches for calculating electron and antineutrino spectra. We then explore different possibilities for the disagreement between the measured Daya Bay and the Huber-Mueller antineutrino spectra, including the 238 U contribution as wellmore » as the effective charge and the allowed shape assumption used in the conversion method. Here, we observe that including a shape correction of about + 6 % MeV - 1 in conversion calculations can better describe the Daya Bay spectrum. Because of a lack of experimental data, this correction cannot be ruled out, concluding that in order to confirm the existence of the reactor neutrino anomaly, or even quantify it, precisely measured electron spectra for about 50 relevant fission products are needed. With the advent of new rare ion facilities, the measurement of shape factors for these nuclides, for many of which precise beta intensity data from TAGS experiments already exist, would be highly desirable.« less

The Ca II infrared triplet's performance as an activity indicator compared to Ca II H and K. Empirical relations to convert Ca II infrared triplet measurements to common activity indices

NASA Astrophysics Data System (ADS)

Martin, J.; Fuhrmeister, B.; Mittag, M.; Schmidt, T. O. B.; Hempelmann, A.; González-Pérez, J. N.; Schmitt, J. H. M. M.

2017-09-01

Aims: A large number of Calcium infrared triplet (IRT) spectra are expected from the Gaia and CARMENES missions. Conversion of these spectra into known activity indicators will allow analysis of their temporal evolution to a better degree. We set out to find such a conversion formula and to determine its robustness. Methods: We have compared 2274 Ca II IRT spectra of active main-sequence F to K stars taken by the TIGRE telescope with those of inactive stars of the same spectral type. After normalizing and applying rotational broadening, we subtracted the comparison spectra to find the chromospheric excess flux caused by activity. We obtained the total excess flux, and compared it to established activity indices derived from the Ca II H and K lines, the spectra of which were obtained simultaneously to the infrared spectra. Results: The excess flux in the Ca II IRT is found to correlate well with R'HK and R+HK, as well as SMWO, if the B - V-dependency is taken into account. We find an empirical conversion formula to calculate the corresponding value of one activity indicator from the measurement of another, by comparing groups of datapoints of stars with similar B - V.

High-resolution 18 CM spectra of OH/IR stars

NASA Astrophysics Data System (ADS)

Fix, John D.

1987-02-01

High-velocity-resolution, high-signal-to-noise spectra have been obtained for the 18 cm maser emission lines from a number of optically visible OH/IR stars. The spectra have been interpreted in terms of a recent model by Alcock and Ross (1986), in which OH/IR stars lose mass in discrete elements rather than by a continuous wind. Comparison of the observed spectra with synthetic spectra shows that the lines are the composite emission from thousands or tens of thousands of individual elements.

Retrieval of constituent mixing ratios from limb thermal emission spectra

NASA Technical Reports Server (NTRS)

Shaffer, William A.; Kunde, Virgil G.; Conrath, Barney J.

1988-01-01

An onion-peeling iterative, least-squares relaxation method to retrieve mixing ratio profiles from limb thermal emission spectra is presented. The method has been tested on synthetic data, containing various amounts of added random noise for O3, HNO3, and N2O. The retrieval method is used to obtain O3 and HNO3 mixing ratio profiles from high-resolution thermal emission spectra. Results of the retrievals compare favorably with those obtained previously.

High-level ab initio calculations on HGeCl and the equilibrium geometry of the A1A'' state derived from Franck-Condon analysis of the single-vibronic-level emission spectra of HGeCl and DGeCl.

PubMed

Mok, Daniel K W; Chau, Foo-Tim; Lee, Edmond P F; Dyke, John M

2010-02-01

CCSD(T) and/or CASSCF/MRCI calculations have been carried out on the X(1)A' and A(1)A'' states of HGeCl. The fully relativistic effective core potential, ECP10MDF, and associated standard valence basis sets of up to the aug-cc-pV5Z quality were employed for Ge. Contributions from core correlation and extrapolation to the complete basis set limit were included in determining the computed equilibrium geometrical parameters and relative electronic energy of these two states of HGeCl. Based on the currently, most systematic CCSD(T) calculations performed in this study, the best theoretical geometrical parameters of the X(1)A' state are r(e)(HGe) = 1.580 +/- 0.001 A, theta(e) = 93.88 +/- 0.01 degrees and r(e)(GeCl) = 2.170 +/- 0.001 A. In addition, Franck-Condon factors including allowance for anharmonicity and Duschinsky rotation between these two states of HGeCl and DGeCl were calculated employing CCSD(T) and CASSCF/MRCI potential energy functions, and were used to simulate A(1)A'' --> X(1)A' SVL emission spectra of HGeCl and DGeCl. The iterative Franck-Condon analysis (IFCA) procedure was carried out to determine the equilibrium geometrical parameters of the A(1)A'' state of HGeCl by matching the simulated, and available experimental SVL emission spectra of HGeCl and DGeCl of Tackett et al., J Chem Phys 2006, 124, 124320, using the available, estimated experimental equilibrium (r(e)(z)) structure for the X(1)A' state, while varying the equilibrium geometrical parameters of the A(1)A'' state systematically. Employing the derived IFCA geometry of r(e)(HGe) = 1.590 A, r(e)(GeCl) = 2.155 A and theta(e)(HGeCl) = 112.7 degrees for the A(1)A'' state of HGeCl in the spectral simulation, the simulated absorption and SVL emission spectra of HGeCl and DGeCl agree very well with the available experimental LIF and SVL emission spectra, respectively. Copyright 2009 Wiley Periodicals, Inc.

Purely organic electroluminescent material realizing 100% conversion from electricity to light

PubMed Central

Kaji, Hironori; Suzuki, Hajime; Fukushima, Tatsuya; Shizu, Katsuyuki; Suzuki, Katsuaki; Kubo, Shosei; Komino, Takeshi; Oiwa, Hajime; Suzuki, Furitsu; Wakamiya, Atsushi; Murata, Yasujiro; Adachi, Chihaya

2015-01-01

Efficient organic light-emitting diodes have been developed using emitters containing rare metals, such as platinum and iridium complexes. However, there is an urgent need to develop emitters composed of more abundant materials. Here we show a thermally activated delayed fluorescence material for organic light-emitting diodes, which realizes both approximately 100% photoluminescence quantum yield and approximately 100% up-conversion of the triplet to singlet excited state. The material contains electron-donating diphenylaminocarbazole and electron-accepting triphenyltriazine moieties. The typical trade-off between effective emission and triplet-to-singlet up-conversion is overcome by fine-tuning the highest occupied molecular orbital and lowest unoccupied molecular orbital distributions. The nearly zero singlet–triplet energy gap, smaller than the thermal energy at room temperature, results in an organic light-emitting diode with external quantum efficiency of 29.6%. An external quantum efficiency of 41.5% is obtained when using an out-coupling sheet. The external quantum efficiency is 30.7% even at a high luminance of 3,000 cd m−2. PMID:26477390

Probing the spatial dependence of the emission spectrum of single human retinal lipofuscin granules using near-field scanning optical microscopy.

PubMed

Haralampus-Grynaviski, N M; Lamb, L E; Simon, J D; Krogmeier, J R; Dunn, R C; Pawlak, A; Rózanowska, M; Sarna, T; Burke, J M

2001-08-01

The emission spectra of single lipofuscin granules are examined using spectrally resolved confocal microscopy and near-field scanning optical microscopy (NSOM). The emission spectrum varies among the granules examined revealing that individual granules are characterized by different distributions of fluorophores. The range of spectra observed is consistent with in vivo spectra of human retinal pigment epithelium cells. NSOM measurements reveal that the shape of the spectrum does not vary with position within the emissive regions of single lipofuscin granules. These results suggest that the relative distribution of fluorophores within the emissive regions of an individual granule is homogeneous on the spatial scale approximately 150 nm.

The dust mass in Cassiopeia A

NASA Astrophysics Data System (ADS)

De Looze, Ilse; Barlow, Mike; Marcowith, Alexandre; Tatischef, Vincent

2016-06-01

Theoretical models predict that core-collapse supernovae (CCSNe) can be efficient dust producers (0.1-1 Msun) and potentially responsible for most of the dust production in the early Universe. Observational evidence for this dust production efficiency has remained limited. Herschel observations from 70-500 microns of the 335-year old Cassiopeia A have indicated the presence of ˜0.1 Msun of cool (T˜35 K) dust interior to the reverse shock (Barlow et al. 2010), while Dunne et al. (2009) have claimed a detection of ˜1 Msun of cold (˜20 K) dust, based on SCUBA 850-micron polarimetric data. At sub-millimeter wavelengths, the supernova dust emission is heavily contaminated by interstellar dust emission and by the synchrotron radiation from the SNR. We present the first spatially resolved analysis of the infrared and submillimeter emission of Cas, A at better than 1 parsec resolution, based on our Herschel PACS and SPIRE 70-500um images. We used our PACS IFU and SPIRE FTS spectra to remove the contaminating emission from bright lines (e.g. [OIII]88, [CII]158). We updated the spectral index of the synchrotron emission based on recent Planck data, and extrapolated this synchrotron spectrum from a 3.7 mm VLA image to infrared/submillimeter wavelengths. We modeled the interstellar dust emission using a Galactic dust emission template from Jones et al. (2013), while the ISM dust mass is scaled to reproduce the continuum emission in the SPIRE FTS spectra at wavelengths > 650 micron (after subtraction of synchrotron emission). The UV radiation field that illuminates the ISM dust was constrained through PDR modelling of the [CI] 1-0, 2-1 and CO 4-3 lines observed in the SPIRE FTS spectra, and was found to range between 0.3 G0 and 1.0 G0 in units of the Draine IS radiation field. Within the uncertainties of the radiation field that illuminates the ISM material and the observational errors, we detect a dust mass of up to 0.8 Msun in Cas, A, with an average temperature of 30 K, in the region interior to the reverse shock. Our SN dust mass map has a rather smooth appearance, which suggests that dust formed uniformly throughout the ejecta. A Cas A dust mass of up to 0.8 Msun is in the same range as the ˜0.7 Msun of dust found in SN 1987A (Matsuura et al. 2015) and the ˜0.2 Msun of dust found in the Crab Nebula (Gomez et al. 2012; Owen & Barlow 2015). With these dust masses core-collapse supernovae can potentially account for the very large large masses of dust that have been observed in some high redshift galaxies.

Measurements of thermal infrared spectral reflectance of frost, snow, and ice

NASA Technical Reports Server (NTRS)

Salisbury, John W.; D'Aria, Dana M.; Wald, Andrew

1994-01-01

Because much of Earth's surface is covered by frost, snow, and ice, the spectral emissivities of these materials are a significant input to radiation balance calculations in global atmospheric circulation and climate change models. Until now, however, spectral emissivities of frost and snow have been calculated from the optical constants of ice. We have measured directional hemispherical reflectance spectra of frost, snow, and ice from which emissivities can be predicted using Kirchhoff's law (e = 1-R). These measured spectra show that contrary to conclusions about the emissivity of snow drawn from previously calculated spectra, snow emissivity departs significantly from blackbody behavior in the 8-14 micrometer region of the spectrum; snow emissivity decreases with both increasing particle size and increasing density due to packing or grain welding; while snow emissivity increases due to the presence of meltwater.

New Gener. High-Energy Spectra of the Blazar 3C 279 with XMM-Newton and GLAST

NASA Astrophysics Data System (ADS)

Collmar, Werner

2007-10-01

We propose two 20 ksec XMM-Newton observations of the X-ray bright gamma-ray blazar 3C~279 simultaneous with GLAST/LAT. The main goal is to measure its X-ray properties (spectrum, variability) in order to (1) improve our knowledge on the X-ray emission of the blazar, and (2) to supplement and correlate them to simultaneous GLAST/LAT Gamma-ray observations (30 MeV-300 GeV). Simultaneous GLAST observations of 3C 279 are guaranteed (assuming proper operation then). The high-energy data will be supplemented by ground-based measurements, adding finally up to multifrequency spectra which have unprecedented accuracy and will extend up to high-energy gamma-rays. Such high-quality SEDs will provide severe constraints on their modeling and have the potential to discriminate among models.

A Comparative Cathodoluminescence Emission Study of Feldspathic Glasses in SNC Meteorites and Quenched Melts of These Glasses

NASA Astrophysics Data System (ADS)

Kubny, A.; Jagoutz, E.

2001-12-01

In this study the cathodoluminescence (electron-excited luminescence) emission spectra were measured in the range 200 to 900 nm of individual feldspathic glass grains in the SNC meteorites Shergotty 101, Shergotty 232, ALHA 84001, EETA 79001-47, EETA 79001-276, and Dar al Gani 476 and those of quenched melts of the feldspathic glass grains. The quenching experiments of the original feldspathic glasses were conducted at 1500° C and atmospheric pressure. The aim of this CL emission study was the characterization of feldspathic glasses of SNC meteorites by comparison of the diagnostic spectral features of the feldspathic glasses of SNC meteorites with those of their quenched melts. In the CL emission spectra of the studied feldspathic glasses generally broad bands in the blue (ca. 460 nm), green (ca. 560 nm), and red (ca. 700 nm) can appear. These emission bands are assigned to structural defects (Al-O--Al centers), and the structural incorporation of Mn2+ and Fe3+ , respectively. The blue emission band at about 460 nm attributed to Al-O--Al centers is observed in the spectra of the original feldspathic glasses whereas it is not present (or only in low relative intensity) in the spectra of the quenched melts. The green emission band at 550 to 575 nm assigned to electronic transitions of Mn2+ in M sites is observed in the spectra of the original feldspathic glasses. It is shifted to longer wavelengths of 590 to 605 nm in the spectra of the quenched melts. The occurrence of the red emission band at about 700 nm attributed to electronic transition of Fe3+ in the spectra of the quenched melts of the feldspathic glasses indicates the presence of structural units which allow the occupancy of Fe3+ on tetrahedral sites. The results obtained by CL emission spectroscopy confirm results of Raman spectroscopic studies that the stuctures of feldspathic glasses of the studied SNC meteorites are modified by melting and quenching at atmospheric pressure. Additionally, comparison with published work on CL emission of shocked oligoclases shows that the feldspathic glasses of the studied SNC meteorites are not diaplectic but melt glasses.

High-Resolution X-Ray Spectra of the Symbiotic Star SS73 17

NASA Technical Reports Server (NTRS)

Eze, R. N. C.; Luna, G. J. M.; Smith, R. K.

2010-01-01

SS73 17 was an innocuous Mira-type symbiotic star until the International Gamma-Ray Astrophysics Laboratory and Swift discovered its bright hard X-ray emission, adding it to the small class of "hard X-ray emitting symbiotics." Suzaku observations in 2006 then showed it emits three bright iron lines as well, with little to no emission in the 0.3-2.0 keV bandpass. We present here follow-up observations with the Chandra High Energy Transmission Grating and Suzaku that confirm the earlier detection of strong emission lines of Fe K(alpha) fluorescence, Fe XXV and Fe XXVI but also show significantly more soft X-ray emission. The high-resolution spectrum also shows emission lines of other highly ionized ions as Si xiv and possibly S XVI. In addition, a re-analysis of the 2006 Suzaku data using the latest calibration shows that the hard (15-50 keV) X-ray emission is brighter than previously thought and remains constant in both the 2006 and 2008 data. The G ratio calculated from the Fe xxv lines shows that these lines are thermal, not photoionized, in origin.With the exception of the hard X-ray emission, the spectra from both epochs can be fit using thermal radiation assuming a differential emission measure based on a cooling-flow model combined with a full and partial absorber. We show that acceptable fits can be obtained for all the data in the 1-10 keV band varying only the partial absorber. Based on the temperature and accretion rate, the thermal emission appears to be arising from the boundary layer between the accreting white dwarf and the accretion disk.

Two-Color Coherent Control of Femtosecond Above-Threshold Photoemission from a Tungsten Nanotip.

PubMed

Förster, Michael; Paschen, Timo; Krüger, Michael; Lemell, Christoph; Wachter, Georg; Libisch, Florian; Madlener, Thomas; Burgdörfer, Joachim; Hommelhoff, Peter

2016-11-18

We demonstrate coherent control of multiphoton and above-threshold photoemission from a single solid-state nanoemitter driven by a fundamental and a weak second harmonic laser pulse. Depending on the relative phase of the two pulses, electron emission is modulated with a contrast of the oscillating current signal of up to 94%. Electron spectra reveal that all observed photon orders are affected simultaneously and similarly. We confirm that photoemission takes place within 10 fs. Accompanying simulations indicate that the current modulation with its large contrast results from two interfering quantum pathways leading to electron emission.

Laser-initiated explosive electron emission from flat germanium crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porshyn, V., E-mail: porshyn@uni-wuppertal.de; Mingels, S.; Lützenkirchen-Hecht, D.

2016-07-28

Flat Sb-doped germanium (100) crystals were investigated in the triode configuration under pulsed tunable laser illumination (pulse duration t{sub laser} = 3.5 ns and photon energy hν = 0.54–5.90 eV) and under DC voltages <10{sup 4} V. Large bunch charges up to ∼1 μC were extracted from the cathodes for laser pulses >1 MW/cm{sup 2} corresponding to a high quantum efficiency up to 3.3% and cathode currents up to 417 A. This laser-induced explosive electron emission (EEE) from Ge was characterized by its voltage-, laser power- and hν-sensitivity. The analysis of the macroscopic surface damage caused by the EEE is included as well. Moreover, we have carried out firstmore » direct measurements of electron energy distributions produced during the EEE from the Ge samples. The measured electron spectra hint for electron excitations to the vacuum level of the bulk and emission from the plasma plume with an average kinetic energy of ∼0.8 eV.« less

A large-area diffuse air discharge plasma excited by nanosecond pulse under a double hexagon needle-array electrode.

PubMed

Liu, Zhi-Jie; Wang, Wen-Chun; Yang, De-Zheng; Wang, Sen; Zhang, Shuai; Tang, Kai; Jiang, Peng-Chao

2014-01-01

A large-area diffuse air discharge plasma excited by bipolar nanosecond pulse is generated under a double hexagon needle-array electrode at atmospheric pressure. The images of the diffuse discharge, electric characteristics, and the optical emission spectra emitted from the diffuse air discharge plasma are obtained. Based on the waveforms of pulse voltage and current, the power consumption, and the power density of the diffuse air discharge plasma are investigated under different pulse peak voltages. The electron density and the electron temperature of the diffuse plasma are estimated to be approximately 1.42×10(11) cm(-3) and 4.4 eV, respectively. The optical emission spectra are arranged to determine the rotational and vibrational temperatures by comparing experimental with simulated spectra. Meanwhile, the rotational and vibrational temperatures of the diffuse discharge plasma are also discussed under different pulse peak voltages and pulse repetition rates, respectively. In addition, the diffuse air discharge plasma can form an area of about 70×50 mm(2) on the surface of dielectric layer and can be scaled up to the required size. Crown Copyright © 2013. Published by Elsevier B.V. All rights reserved.

Preliminary study on preparation of BCNO phosphor particles using citric acid as carbon source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nuryadin, Bebeh W.; Pratiwi, Tripuspita; Faryuni, Irfana D.

A citric acid was used as a carbon source in the preparation of boron carbon oxy-nitride (BCNO) phosphor particles by a facile process. The preparation process was conducted at relatively low temperature 750 °C and at ambient pressure. The prepared BCNO phosphors showed a high photoluminescence (PL) performance at peak emission wavelength of 470 nm under excitation by a UV light 365 nm. The effects of carbon/boron and nitrogen/boron molar ratios on the PL properties were also investigated. The result showed that the emission spectra with a wavelength peak ranging from 444 nm to 496 nm can be obtained bymore » varying carbon/boron ratios from 0.1 to 0.9. In addition, the observations showed that the BCNO phosphor material has two excitation peaks located at the 365 nm (UV) and 420 nm (blue). Based on these observations, we believe that the citric acid derived BCNO phosphor particles can be a promising inexpensive material for phosphor conversion-based white LED.« less

Tandem luminescent solar concentrators based on engineered quantum dots

NASA Astrophysics Data System (ADS)

Wu, Kaifeng; Li, Hongbo; Klimov, Victor I.

2018-02-01

Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors for terrestrial and space-based photovoltaics. Due to their high emission efficiencies and readily tunable emission and absorption spectra, colloidal quantum dots have emerged as a new and promising type of LSC fluorophore. Spectral tunability of the quantum dots also facilitates the realization of stacked multilayered LSCs, where enhanced performance is obtained through spectral splitting of incident sunlight, as in multijunction photovoltaics. Here, we demonstrate a large-area (>230 cm2) tandem LSC based on two types of nearly reabsorption-free quantum dots spectrally tuned for optimal solar-spectrum splitting. This prototype device exhibits a high optical quantum efficiency of 6.4% for sunlight illumination and solar-to-electrical power conversion efficiency of 3.1%. The efficiency gains due to the tandem architecture over single-layer devices quickly increase with increasing LSC size and can reach more than 100% in structures with window sizes of more than 2,500 cm2.

IUE observations of the Jovian dayglow emission

NASA Technical Reports Server (NTRS)

Mcgrath, M. A.; Feldman, P. D.; Ballester, G. E.; Moos, H. W.

1989-01-01

IUE spectra of Jupiter are examined in light of recent models put forward to explain the anomalously bright ultraviolet emissions seen from the upper atmospheres of the outer planets. Chi-squared fits of the IUE spectra with model spectra produced by two proposed excitation mechanisms, electron impact and fluorescence of solar radiation, result in consistently higher chi-squared values for the solar fluorescence model. No conclusive evidence is found in the IUE data for the dominance of solar fluorescence over electron excitation in producing the Jovian dayglow emission.

Emission wavelength of AlGaAs-GaAs multiple quantum well lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blood, P.; Fletcher, E.D.; Hulyer, P.J.

1986-04-28

We have recorded spontaneous emission spectra from multiple quantum well lasers grown by molecular beam epitaxy with 25-A-wide GaAs wells by opening a window in the top contact stripe. These spectra have a low-energy tail and consequently the gain spectra derived from them show that laser emission occurs at a lower photon energy than the lowest energy confined particle transition. The observed laser wavelength and threshold current are consistent with the position of the peak in the gain spectrum.

40 CFR 60.73 - Emission monitoring.

Code of Federal Regulations, 2010 CFR

2010-07-01

... operator shall establish a conversion factor for the purpose of converting monitoring data into units of the applicable standard (kg/metric ton, lb/ton). The conversion factor shall be established by... represents emission measurements concurrent with the reference method test periods, the conversion factor...

Ultrafast Transient Absorption Spectroscopy Investigation of Photoinduced Dynamics in POLY(3-HEXYLTHIOPHENE)-BLOCK-OLIGO(ANTHRACENE-9,10-DIYL)

NASA Astrophysics Data System (ADS)

Strain, Jacob; Rathnayake, Hemali; Liu, Jinjun

2017-06-01

Semiconducting polymer nanostructures featuring bulk heterojunction (BHJ) architecture are promising light harvesters in photovoltaic (PV) devices because they allow control of individual domain sizes, internal structure and ordering, as well as well-defined contact between the electron donor and acceptor. Power conversion efficiency (PCE) of PV devices strongly depends on photoinduced dynamics. Understanding and optimizing photoinduced charge transfer processes in BHJ's hence help improve the performance of PV devices and increase their PCE in particular. We have investigated the photoinduced dynamics of a block polymer containing moieties of poly-3-hexylthiophene (P3HT) and polyanthracene (PANT) in solution and in solid state with femtosecond transient absorption (TA) spectroscopy. The dynamics of the polymer PANT alone are also studied as a control. The TA spectra of PANT includes a strong excited state absorption centered at 610 (nm) along with a stimulated emission signal stretching past the detection limit into the UV region which is absent in the monomer's spectra in the detection window. The block polymer's TA spectra strongly resembles that of P3HT but a noticeable positive pull on P3HT's stimulated emission signal residing at 575-620 (nm) is indicative of the excited state absorption of PANT in the adjacent spectral region. The doubling of the lifetime exciton delocalization on the block polymer versus P3HT alone have alluded that the lifetime of P3HT is extended by the covalent addition of PANT. The current spectroscopic investigation represents an interesting example of photoinduced processes in systems with complex energy level structure. Studies of dependence of change generation and separation on composition, dimension, and morphology of the heterojunctions are in process.

Very long baseline interferometric observations of the hydroxyl masers in VY Canis Majoris

NASA Technical Reports Server (NTRS)

Reid, M. J.; Muhleman, D. O.

1978-01-01

Results are presented for spectral-line VLBI observations of the OH emission from VY CMa. The main-line (1665 and 1667 MHz) emission was mapped with an angular resolution of 0.02 arcsec by analyzing interferometer phase data. The main-line emission comes from many maser components of apparent size less than 0.03 arcsec which are separated by up to 0.5 arcsec. New maser features near the center of the OH spectra were detected and found to lie within the region encompassed by the low-velocity OH emission. The 1612-MHz emission was mapped by Fourier inversion of the VLBI data from two baselines. All spatially isolated maser components appeared smaller than 0.15 arcsec; however, the maser emission is very complex at most velocities. Maser components within a velocity range of 1.3 km/s are often separated by more than 1 arcsec, while components more than 10 km/s apart in each emission complex are often coincident to 0.2 arcsec.

Dynamics of vapor emissions at wire explosion thresholda)

NASA Astrophysics Data System (ADS)

Belony, Paul A.; Kim, Yong W.

2010-10-01

X-pinch plasmas have been actively studied in the recent years. Numerical simulation of the ramp-up of metallic vapor emissions from wire specimens shows that under impulsive Ohmic heating the wire core invariably reaches a supercritical state before explosion. The heating rate depends sensitively on the local wire resistance, leading to highly variable vapor emission flux along the wire. To examine the vapor emission process, we have visualized nickel wire explosions by means of shock formation in air. In a single explosion as captured by shadowgraphy, there usually appear several shocks with spherical or cylindrical wave front originating from different parts of the wire. Growth of various shock fronts in time is well characterized by a power-law scaling in one form or another. Continuum emission spectra are obtained and calibrated to measure temperature near the explosion threshold. Shock front structures and vapor plume temperature are examined.

Possible Charge-Exchange X-Ray Emission in the Cygnus Loop Detected with Suzaku

NASA Technical Reports Server (NTRS)

Katsuda, Satoru; Tsunemi, Hiroshi; Mori, Koji; Uchida, Hiroyuki; Kosugi, Hiroko; Kimura, Masashi; Nakajima, Hiroshi; Takakura, Satoru; Petre, Robert; Hewitt. John W.;

Estimated Mid-Infrared (200-2000 cm-1) Optical Constants of Some Silica Polymorphs

NASA Astrophysics Data System (ADS)

Glotch, Timothy; Rossman, G. R.; Michalski, J. R.

2006-09-01

We use Lorentz-Lorenz dispersion analysis to model the mid-infrared (200-2000 cm-1) optical constants, of opal-A, opal-CT, and tridymite. These minerals, which are all polymorphs of silica (SiO2), are potentially important in the analysis of thermal emission spectra acquired by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) and Mars Exploration Rover Mini-TES instruments in orbit and on the surface of Mars as well as emission spectra acquired by telescopes of planetary disks and dust and debris clouds in young solar systems. Mineral samples were crushed, washed, and sieved and emissivity spectra of the >100; μm size fraction were acquired at Arizona State University's emissivity spectroscopy laboratory. Therefore, the spectra and optical constants are representative of all crystal orientations. Ideally, emissivity or reflectance measurements of single polished crystals or fine powders pressed to compact disks are used for the determination of mid-infrared optical constants. Measurements of these types of surfaces eliminate or minimize multiple reflections, providing a specular surface. Our measurements, however, likely produce a reasonable approximation of specular emissivity or reflectance, as the minimum particle size is greater than the maximum wavelength of light measured. Future work will include measurement of pressed disks of powdered samples in emission and reflection, and when possible, small single crystals under an IR reflectance microscope, which will allow us to assess the variability of spectra and optical constants under different sample preparation and measurement conditions.

Dynamics of the Shocked Gas in the Eta Carinae System as Seen by Chandra

NASA Technical Reports Server (NTRS)

Corcoran, M. F.; Hamaguchi, K.; Henley, D. B.; Ishibashi, K.; Gull, T.; Nielsen, K.; Pittard, J. M.

2006-01-01

We report on a series of X-ray spectra of the supermassive star Eta Carinae obtained by the High Energy Transmission Grating Spectrometer on the CHANDRA X-ray observatory before, during and after the star's X-ray minimum in the summer of 2003. The X-ray spectra show significant variations in emission measure and absorption, in the strength of the iron K edge and fluorescent iron emission, but show little change in the distribution of emission measure with temperature. The CHANDRA spectra also resolve emission from Si, S, Fe and other elements in H-like and He-like configurations. The HETGS spectra show that these lines change in centroid energy along with evidence of changes in the forbidden-to-intercombination ratios of the He-like triplets. These spectra offer strong support that the X-ray emission originates within a shock cone around an unseen, massive companion. The variations of the X-ray line spectrum provide a direct measure of the dynamics of the shocked gas in this cone and also evidence that the hottest region of the shock is not always in collisional ionization equilibrium. We discuss these results in light of the recent discovery of He II 4686 emission and the reported discovery of FUV emission from the companion star. This work was supported by SAO/Chandra grant GO3-4008A.

Reducing the negative human-health impacts of bioenergy crop emissions through region-specific crop selection

DOE PAGES

Porter, William C.; Rosenstiel, Todd N.; Guenther, Alex; ...

2015-05-06

An expected global increase in bioenergy-crop cultivation as an alternative to fossil fuels will have consequences on both global climate and local air quality through changes in biogenic emissions of volatile organic compounds (VOCs). While greenhouse gas emissions may be reduced through the substitution of next-generation bioenergy crops such as eucalyptus, giant reed, and switchgrass for fossil fuels, the choice of species has important ramifications for human health, potentially reducing the benefits of conversion due to increases in ozone (O₃) and fine particulate matter (PM₂̣₅) levels as a result of large changes in biogenic emissions. Using the Community Earth Systemmore » Model we simulate the conversion of marginal and underutilized croplands worldwide to bioenergy crops under varying future anthropogenic emissions scenarios. A conservative global replacement using high VOC-emitting crop profiles leads to modeled population-weighted O₃ increases of 5–27 ppb in India, 1–9 ppb in China, and 1–6 ppb in the United States, with peak PM₂̣₅ increases of up to 2 μgm⁻³. We present a metric for the regional evaluation of candidate bioenergy crops, as well as results for the application of this metric to four representative emissions profiles using four replacement scales (10–100% maximum estimated available land). Finally, we assess the total health and climate impacts of biogenic emissions, finding that the negative consequences of using high-emitting crops could exceed 50% of the positive benefits of reduced fossil fuel emissions in value.« less

Reducing the negative human-health impacts of bioenergy crop emissions through region-specific crop selection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Porter, William C.; Rosenstiel, Todd N.; Guenther, Alex

An expected global increase in bioenergy-crop cultivation as an alternative to fossil fuels will have consequences on both global climate and local air quality through changes in biogenic emissions of volatile organic compounds (VOCs). While greenhouse gas emissions may be reduced through the substitution of next-generation bioenergy crops such as eucalyptus, giant reed, and switchgrass for fossil fuels, the choice of species has important ramifications for human health, potentially reducing the benefits of conversion due to increases in ozone (O₃) and fine particulate matter (PM₂̣₅) levels as a result of large changes in biogenic emissions. Using the Community Earth Systemmore » Model we simulate the conversion of marginal and underutilized croplands worldwide to bioenergy crops under varying future anthropogenic emissions scenarios. A conservative global replacement using high VOC-emitting crop profiles leads to modeled population-weighted O₃ increases of 5–27 ppb in India, 1–9 ppb in China, and 1–6 ppb in the United States, with peak PM₂̣₅ increases of up to 2 μgm⁻³. We present a metric for the regional evaluation of candidate bioenergy crops, as well as results for the application of this metric to four representative emissions profiles using four replacement scales (10–100% maximum estimated available land). Finally, we assess the total health and climate impacts of biogenic emissions, finding that the negative consequences of using high-emitting crops could exceed 50% of the positive benefits of reduced fossil fuel emissions in value.« less

Reducing the negative human-health impacts of bioenergy crop emissions through region-specific crop selection

NASA Astrophysics Data System (ADS)

Porter, William C.; Rosenstiel, Todd N.; Guenther, Alex; Lamarque, Jean-Francois; Barsanti, Kelley

2015-05-01

An expected global increase in bioenergy-crop cultivation as an alternative to fossil fuels will have consequences on both global climate and local air quality through changes in biogenic emissions of volatile organic compounds (VOCs). While greenhouse gas emissions may be reduced through the substitution of next-generation bioenergy crops such as eucalyptus, giant reed, and switchgrass for fossil fuels, the choice of species has important ramifications for human health, potentially reducing the benefits of conversion due to increases in ozone (O3) and fine particulate matter (PM2.5) levels as a result of large changes in biogenic emissions. Using the Community Earth System Model we simulate the conversion of marginal and underutilized croplands worldwide to bioenergy crops under varying future anthropogenic emissions scenarios. A conservative global replacement using high VOC-emitting crop profiles leads to modeled population-weighted O3 increases of 5-27 ppb in India, 1-9 ppb in China, and 1-6 ppb in the United States, with peak PM2.5 increases of up to 2 μg m-3. We present a metric for the regional evaluation of candidate bioenergy crops, as well as results for the application of this metric to four representative emissions profiles using four replacement scales (10-100% maximum estimated available land). Finally, we assess the total health and climate impacts of biogenic emissions, finding that the negative consequences of using high-emitting crops could exceed 50% of the positive benefits of reduced fossil fuel emissions in value.

Prominent spectral features of Sm3+ ion in disordered zinc tellurite glass

NASA Astrophysics Data System (ADS)

Tanko, Y. A.; Sahar, M. R.; Ghoshal, S. K.

Trivalent rare earth doped glasses with modified spectroscopic features are essential for solid state lasers and diverse photonic applications. Glass composition optimisation may fulfil such demand. Stimulating the spectral properties of samarium (Sm3+) ions in tellurite glass host with desired enhancement is the key issue. Glasses with composition (80 - x)TeO2-20ZnO-(x)Sm2O3, where 0 ⩽ x ⩽ 1.5 mol% are prepared using melt quenching method. The role of varying Sm3+ contents to improving the absorption and emission properties of the prepared glasses are determined. XRD pattern verifies amorphous nature of synthesised glasses. FTIR spectroscopy has been used to observe the structural modification of (TeO4) trigonal bipyramid structural units. DTA traces display prominent transition peaks for glass transition, crystallisation and melting temperature. Samples are discerned to be stable with desired Hruby parameter and superior glass forming ability. The UV-Vis-NIR absorption spectra reveals nine peaks centred at 470, 548, 947, 1085, 1238, 1385, 1492, 1550 and 1589 nm. These bands arise due to 6H5/2 → 4I11/2, 4G5/2, 6F11/2, 6F9/2, 6F7/2, 6F5/2, 6F3/2, 6H15/2 and 6F1/2 transitions, respectively. The direct, indirect band gap and Urbach energy calculated from the absorption edge of UV-Vis-NIR spectra are found to appear within (2.75-3.18) eV, (3.22-3.40) eV, and (0.20-0.31) eV, respectively. The observed increase in refractive index from 2.45 to 2.47 is ascribed to the generation of non-bridging oxygen atoms via the conversion of TeO4 into TeO3 units. Conversely the decrease in refractive index to 2.39 is attributed to the lower ionic radii (1.079 Å) of Sm3+. PL spectra under the excitation of 452 nm display four emission bands centred at 563, 600, 644 and 705 nm corresponding to 4G5/2 → 6H5/2, 6H7/2, 6H9/2 and 6H11/2 transitions of samarium ions. Excellent features of the results nominate these compositions towards prospective applications.

Single-Molecule Spectroscopy Unmasks the Lowest Exciton State of the B850 Assembly in LH2 from Rps. acidophila

PubMed Central

Kunz, Ralf; Timpmann, Kõu; Southall, June; Cogdell, Richard J.; Freiberg, Arvi; Köhler, Jürgen

2014-01-01

We have recorded fluorescence-excitation and emission spectra from single LH2 complexes from Rhodopseudomonas (Rps.) acidophila. Both types of spectra show strong temporal spectral fluctuations that can be visualized as spectral diffusion plots. Comparison of the excitation and emission spectra reveals that for most of the complexes the lowest exciton transition is not observable in the excitation spectra due to the cutoff of the detection filter characteristics. However, from the spectral diffusion plots we have the full spectral and temporal information at hand and can select those complexes for which the excitation spectra are complete. Correlating the red most spectral feature of the excitation spectrum with the blue most spectral feature of the emission spectrum allows an unambiguous assignment of the lowest exciton state. Hence, application of fluorescence-excitation and emission spectroscopy on the same individual LH2 complex allows us to decipher spectral subtleties that are usually hidden in traditional ensemble spectroscopy. PMID:24806933

Advances in the RXTE Proportional Counter Array Calibration: Nearing the Statistical Limit

NASA Technical Reports Server (NTRS)

Shaposhnikov, Nikolai; Jahoda, Keith; Markwardt, Craig; Swank, Jean; Strohmayer, Tod

2012-01-01

During its 16 years of service Rossi X-ray Timing Explorer (RXTE) mission has provided an extensive archive of data, which will serve as a primary source of high cadence observation of variable X-ray sources for fast timing studies. It is, therefore, very important to have the most reliable calibration of RXTE instruments. The Proportional Counter Array (PCA) is the primary instrument on-board RXTE which provides data in 2-50 keY with higher than millisecond time resolution in up to 256 energy channels. In 2009 RXTE team revised the response residual minimization method used to derive the parameters of the PCA physical model. The procedure is now based on the residual minimization between the model spectrum for Crab nebula emission and a calibration data set consisting of a number of spectra from the Crab and the on-board Am241 calibration source, uniformly covering a whole RXTE span. The new method led to a much more effective model convergence and allowed for better understanding of the behavior of the PCA energy-to-channel relationship. It greatly improved the response matrix performance. We describe the new version of the RXTE/PCA response generator PCARMF vll.7 along with the corresponding energy-to-channel conversion table (version e05v04) and their difference from the previous releases of PCA calibration. The new PCA response adequately represents the spectrum of the calibration sources and successfully predicts the energy of the narrow iron emission line in Cas-A throughout the RXTE mission.

Roadmap on optical energy conversion

NASA Astrophysics Data System (ADS)

Boriskina, Svetlana V.; Green, Martin A.; Catchpole, Kylie; Yablonovitch, Eli; Beard, Matthew C.; Okada, Yoshitaka; Lany, Stephan; Gershon, Talia; Zakutayev, Andriy; Tahersima, Mohammad H.; Sorger, Volker J.; Naughton, Michael J.; Kempa, Krzysztof; Dagenais, Mario; Yao, Yuan; Xu, Lu; Sheng, Xing; Bronstein, Noah D.; Rogers, John A.; Alivisatos, A. Paul; Nuzzo, Ralph G.; Gordon, Jeffrey M.; Wu, Di M.; Wisser, Michael D.; Salleo, Alberto; Dionne, Jennifer; Bermel, Peter; Greffet, Jean-Jacques; Celanovic, Ivan; Soljacic, Marin; Manor, Assaf; Rotschild, Carmel; Raman, Aaswath; Zhu, Linxiao; Fan, Shanhui; Chen, Gang

2016-07-01

For decades, progress in the field of optical (including solar) energy conversion was dominated by advances in the conventional concentrating optics and materials design. In recent years, however, conceptual and technological breakthroughs in the fields of nanophotonics and plasmonics combined with a better understanding of the thermodynamics of the photon energy-conversion processes reshaped the landscape of energy-conversion schemes and devices. Nanostructured devices and materials that make use of size quantization effects to manipulate photon density of states offer a way to overcome the conventional light absorption limits. Novel optical spectrum splitting and photon-recycling schemes reduce the entropy production in the optical energy-conversion platforms and boost their efficiencies. Optical design concepts are rapidly expanding into the infrared energy band, offering new approaches to harvest waste heat, to reduce the thermal emission losses, and to achieve noncontact radiative cooling of solar cells as well as of optical and electronic circuitries. Light-matter interaction enabled by nanophotonics and plasmonics underlie the performance of the third- and fourth-generation energy-conversion devices, including up- and down-conversion of photon energy, near-field radiative energy transfer, and hot electron generation and harvesting. Finally, the increased market penetration of alternative solar energy-conversion technologies amplifies the role of cost-driven and environmental considerations. This roadmap on optical energy conversion provides a snapshot of the state of the art in optical energy conversion, remaining challenges, and most promising approaches to address these challenges. Leading experts authored 19 focused short sections of the roadmap where they share their vision on a specific aspect of this burgeoning research field. The roadmap opens up with a tutorial section, which introduces major concepts and terminology. It is our hope that the roadmap will serve as an important resource for the scientific community, new generations of researchers, funding agencies, industry experts, and investors.

NOVAC - Network for Observation of Volcanic and Atmospheric Change: Data archiving and management

NASA Astrophysics Data System (ADS)

Lehmann, T.; Kern, C.; Vogel, L.; Platt, U.; Johansson, M.; Galle, B.

2009-12-01

The potential for volcanic risk assessment using real-time gas emissions data and the recognized power of sharing data from multiple eruptive centers were the motivation for a European Union FP6 Research Program project entitled NOVAC: Network for Observation of Volcanic and Atmospheric Change. Starting in 2005, a worldwide network of permanent scanning Differential Optical Absorption Spectroscopy (DOAS) instruments was installed at 26 volcanoes around the world. These ground-based remote sensing instruments record the characteristic absorption of volcanic gas emissions (e.g. SO2, BrO) in the ultra-violet wavelength region. A real-time DOAS retrieval was implemented to evaluate the measured spectra, thus providing the respective observatories with gas emission data which can be used for volcanic risk assessment and hazard prediction. Observatory personnel at each partner institution were trained on technical and scientific aspects of the DOAS technique, and a central database was created to allow the exchange of data and ideas between all partners. A bilateral benefit for volcano observatories as well as scientific institutions (e.g. universities and research centers) resulted. Volcano observatories were provided with leading edge technology for measuring volcanic SO2 emission fluxes, and now use this technology for monitoring and risk assessment, while the involved universities and research centers are working on global studies and characterizing the atmospheric impact of the observed gas emissions. The NOVAC database takes into account that project members use the database in a variety of different ways. Therefore, the data is structured in layers, the top of which contains basic information about each instrument. The second layer contains evaluated emission data such as SO2 column densities, SO2 emission fluxes, and BrO/SO2 ratios. The lowest layer contains all spectra measured by the individual instruments. Online since the middle of 2006, the NOVAC database currently contains 26 volcanoes, 56 instruments and more than 50 million spectra. It is scalable for up to 200 or more volcanoes, as the NOVAC project is open to outside participation. The data is archived in a MySQL Database system, storing and querying is done with PHP functions. The web interface is dynamically created based on the existing dataset and offers approx. 150 different search, display, and sorting options. Each user has a separate account and can save his personal search configuration from session to session. Search results are displayed in table form and can also be downloaded. Both evaluated data files and measured spectra can be downloaded as single files or in packages. The spectra can be plotted directly from the database, as well as several measurement values and evaluated parameters over selectable timescales. Because of the large extent of the dataset, major emphasis was placed on performance optimization.

A study on emission characteristics of an EFI engine with ethanol blended gasoline fuels

NASA Astrophysics Data System (ADS)

He, Bang-Quan; Wang, Jian-Xin; Hao, Ji-Ming; Yan, Xiao-Guang; Xiao, Jian-Hua

The effect of ethanol blended gasoline fuels on emissions and catalyst conversion efficiencies was investigated in a spark ignition engine with an electronic fuel injection (EFI) system. The addition of ethanol to gasoline fuel enhances the octane number of the blended fuels and changes distillation temperature. Ethanol can decrease engine-out regulated emissions. The fuel containing 30% ethanol by volume can drastically reduce engine-out total hydrocarbon emissions (THC) at operating conditions and engine-out THC, CO and NO x emissions at idle speed, but unburned ethanol and acetaldehyde emissions increase. Pt/Rh based three-way catalysts are effective in reducing acetaldehyde emissions, but the conversion of unburned ethanol is low. Tailpipe emissions of THC, CO and NO x have close relation to engine-out emissions, catalyst conversion efficiency, engine's speed and load, air/fuel equivalence ratio. Moreover, the blended fuels can decrease brake specific energy consumption.

Technique for the comparison of light spectra from natural and laboratory generated lightning current arcs

NASA Astrophysics Data System (ADS)

Mitchard, D.; Clark, D.; Carr, D.; Haddad, A.

2016-08-01

A technique was developed for the comparison of observed emission spectra from lightning current arcs generated through self-breakdown in air and the use of two types of initiation wire, aluminum bronze and nichrome, against previously published spectra of natural lightning events. A spectrograph system was used in which the wavelength of light emitted by the lightning arc was analyzed to derive elemental interactions. A lightning impulse of up to 100 kA was applied to a two hemispherical tungsten electrode configuration which allowed the effect of the lightning current and lightning arc length to be investigated. A natural lightning reference spectrum was reconstructed from literature, and generated lightning spectra were obtained from self-breakdown across a 14.0 mm air gap and triggered along initiation wires of length up to 72.4 mm. A comparison of the spectra showed that the generated lightning arc induced via self-breakdown produced a very similar spectrum to that of natural lightning, with the addition of only a few lines from the tungsten electrodes. A comparison of the results from the aluminum bronze initiation wire showed several more lines, whereas results from the nichrome initiation wire differed greatly across large parts of the spectrum. This work highlights the potential use for spectrographic techniques in the study of lightning interactions with surrounding media and materials, and in natural phenomena such as recently observed ball lightning.

Spectrophotometry near the atmospheric cutoff of the strongest Bowen resonance fluorescence lines of O III in two planetary nebulae

NASA Technical Reports Server (NTRS)

O'Dell, C. R.; Opal, Chet B.

1989-01-01

Spectrophotometric results are presented for the stronger, well-resolved Bowen O III resonance fluorescence emission lines in the planetary nebulae 7027 and NGC 7662 down to and including the intrinsically strong line at 3133 A. These data are combined with results from the IUE atlas of spectra and similar results for the longer wavelength lines by Likkel and Aller (1986) to give the first full coverage of the Bowen lines. Good agreement is found with fluorescence theory for the primary cascade lines, except for the Likkel and Aller results. The efficiency of conversion of the exciting He II Ly-alpha into O III lines is determined, and values comparable to other planetary nebulae are found.

Observations of neutral iron emission in twilight spectra

NASA Technical Reports Server (NTRS)

Tepley, C. A.; Meriwether, J. W., Jr.; Walker, J. C. G.; Mathews, J. D.

1981-01-01

A method is presented for the analysis of twilight airglow spectra that may be contaminated by atmospheric continuum emission of unknown brightness. The necessity of correcting for this continuum emission when measuring weak airglow features in twilight is illustrated by application of the method to the neutral iron line at 3860 A.

The far-ultraviolet spectra and geometric albedos of Jupiter and Saturn

NASA Technical Reports Server (NTRS)

Clarke, J. T.; Moos, H. W.; Feldman, P. D.

1982-01-01

Spectra and geometric albedoes in the range 1200 to 1940 A are compiled for Jupiter and Saturn on the basis of IUE observations. The spectra of both planets are dominated by H Lyman-alpha emission line at 1216 A, although absorption bands of C2H2 are apparent at longer wavelengths, particularly in the spectrum of Saturn, and the C I line at 1657 A is also observed. Geometric albedoes show emission features corresponding to the weak H2 Lyman and Werner bands around 1230-1280 A, auroral Lyman band emission, C I emission, and C2H2 absorption from 1600 to 1900 A. A model of atmospheric absorption in homogeneously mixed atmospheres of H2 and trace molecular absorbers is then presented and fit to the Jupiter albedo, resulting in a predicted atmosphere containing C2H2 and an unidentified molecular or particulate absorber. Finally, north-south maps of Jupiter continuum emission show limb darkening, and a comparison of equatorial and polar spectra indicates a polar increase in C2H2 absorption and weaker polar H2 emissions than previously reported.

Improving the photovoltaic performance of perovskite solar cells with acetate

PubMed Central

Zhao, Qian; Li, G. R.; Song, Jian; Zhao, Yulong; Qiang, Yinghuai; Gao, X. P.

2016-01-01

In an all-solid-state perovskite solar cell, methylammonium lead halide film is in charge of generating photo-excited electrons, thus its quality can directly influence the final photovoltaic performance of the solar cell. This paper accentuates a very simple chemical approach to improving the quality of a perovskite film with a suitable amount of acetic acid. With introduction of acetate ions, a homogeneous, continual and hole-free perovskite film comprised of high-crystallinity grains is obtained. UV-visible spectra, steady-state and time-resolved photoluminescence (PL) spectra reveal that the obtained perovskite film under the optimized conditions shows a higher light absorption, more efficient electron transport, and faster electron extraction to the adjoining electron transport layer. The features result in the optimized perovskite film can provide an improved short-circuit current. The corresponding solar cells with a planar configuration achieves an improved power conversion efficiency of 13.80%, and the highest power conversion efficiency in the photovoltaic measurements is up to 14.71%. The results not only provide a simple approach to optimizing perovskite films but also present a novel angle of view on fabricating high-performance perovskite solar cells. PMID:27934924

Improving the photovoltaic performance of perovskite solar cells with acetate.

PubMed

Zhao, Qian; Li, G R; Song, Jian; Zhao, Yulong; Qiang, Yinghuai; Gao, X P

2016-12-09

In an all-solid-state perovskite solar cell, methylammonium lead halide film is in charge of generating photo-excited electrons, thus its quality can directly influence the final photovoltaic performance of the solar cell. This paper accentuates a very simple chemical approach to improving the quality of a perovskite film with a suitable amount of acetic acid. With introduction of acetate ions, a homogeneous, continual and hole-free perovskite film comprised of high-crystallinity grains is obtained. UV-visible spectra, steady-state and time-resolved photoluminescence (PL) spectra reveal that the obtained perovskite film under the optimized conditions shows a higher light absorption, more efficient electron transport, and faster electron extraction to the adjoining electron transport layer. The features result in the optimized perovskite film can provide an improved short-circuit current. The corresponding solar cells with a planar configuration achieves an improved power conversion efficiency of 13.80%, and the highest power conversion efficiency in the photovoltaic measurements is up to 14.71%. The results not only provide a simple approach to optimizing perovskite films but also present a novel angle of view on fabricating high-performance perovskite solar cells.

2D-COS of in situ μ-Raman and in situ IR spectra for structure evolution characterisation of NEP-deposited cobalt oxide catalyst during n-nonane combustion

NASA Astrophysics Data System (ADS)

Chlebda, Damian K.; Jodłowski, Przemysław J.; Jędrzejczyk, Roman J.; Łojewska, Joanna

2017-11-01

New catalytic systems are still in development to meet the challenge of regulations concerning the emission of volatile organic compounds (VOCs). This is because such compounds have a significant impact on air quality and some of them are toxic to the environment and human beings. The catalytic combustion process of VOCs over non-noble metal catalysts is of great interest to researchers. The high conversion parameters and cost effective preparation makes them a valuable alternative to monoliths and noble metal catalysts. In this study, the cobalt catalyst was prepared by non-equilibrium plasma deposition of organic precursor on calcined kanthal steel. Thus prepared, cobalt oxide based microstructural short-channel reactors were tested for n-nonane combustion and the catalyst surfaces were examined by in situ μ-Raman spectroscopy and in situ infrared spectroscopy. The spectra collected at various temperatures were used in generalised two-dimensional correlation analysis to establish the sequential order of spectral intensity changes and correlate the simultaneous changes in bands selectively coupled by different interaction mechanisms. The 2D synchronous and asynchronous contour maps were proved to be a valuable extension to the standard analysis of the temperature dependent 1D spectra.

In-use catalyst surface area and its relation to HC conversion efficiency and FTP emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donahue, K.S.; Sabourin, M.A.; Larson, R.E.

1986-01-01

Surface area data, steady-state hydrocarbon conversion efficiency data, and hydrocarbon emissions results have been determined for catalysts collected by the U.S. Environmental Protection Agency from properly maintained 1981 and 1982 model year vehicles. Catalysts covered in this study were limited to those with three-way-plus-oxidation monolith technologies. Catalyst surface areas were measured using the BET method, conversion efficiencies were measured on an exhaust gas generator, and emissions results were determined using the Urban Driving Schedule of the Federal Test Procedure. Results indicate that correlation of catalyst surface area data with hydrocarbon conversion efficiency data and hydrocarbon emissions results is significant formore » the sample studied.« less

The Galah Survey: Classification and Diagnostics with t-SNE Reduction of Spectral Information

NASA Astrophysics Data System (ADS)

Traven, G.; Matijevič, G.; Zwitter, T.; Žerjal, M.; Kos, J.; Asplund, M.; Bland-Hawthorn, J.; Casey, A. R.; De Silva, G.; Freeman, K.; Lin, J.; Martell, S. L.; Schlesinger, K. J.; Sharma, S.; Simpson, J. D.; Zucker, D. B.; Anguiano, B.; Da Costa, G.; Duong, L.; Horner, J.; Hyde, E. A.; Kafle, P. R.; Munari, U.; Nataf, D.; Navin, C. A.; Reid, W.; Ting, Y.-S.

2017-02-01

Galah is an ongoing high-resolution spectroscopic survey with the goal of disentangling the formation history of the Milky Way using the fossil remnants of disrupted star formation sites that are now dispersed around the Galaxy. It is targeting a randomly selected magnitude-limited (V ≤ 14) sample of stars, with the goal of observing one million objects. To date, 300,000 spectra have been obtained. Not all of them are correctly processed by parameter estimation pipelines, and we need to know about them. We present a semi-automated classification scheme that identifies different types of peculiar spectral morphologies in an effort to discover and flag potentially problematic spectra and thus help to preserve the integrity of the survey results. To this end, we employ the recently developed dimensionality reduction technique t-SNE (t-distributed stochastic neighbor embedding), which enables us to represent the complex spectral morphology in a two-dimensional projection map while still preserving the properties of the local neighborhoods of spectra. We find that the majority (178,483) of the 209,533 Galah spectra considered in this study represents normal single stars, whereas 31,050 peculiar and problematic spectra with very diverse spectral features pertaining to 28,579 stars are distributed into 10 classification categories: hot stars, cool metal-poor giants, molecular absorption bands, binary stars, Hα/Hβ emission, Hα/Hβ emission superimposed on absorption, Hα/Hβ P-Cygni, Hα/Hβ inverted P-Cygni, lithium absorption, and problematic. Classified spectra with supplementary information are presented in the catalog, indicating candidates for follow-up observations and population studies of the short-lived phases of stellar evolution.

The Galah Survey: Classification and Diagnostics with t-SNE Reduction of Spectral Information

DOE Office of Scientific and Technical Information (OSTI.GOV)

Traven, G.; Zwitter, T.; Žerjal, M.

Galah is an ongoing high-resolution spectroscopic survey with the goal of disentangling the formation history of the Milky Way using the fossil remnants of disrupted star formation sites that are now dispersed around the Galaxy. It is targeting a randomly selected magnitude-limited ( V ≤ 14) sample of stars, with the goal of observing one million objects. To date, 300,000 spectra have been obtained. Not all of them are correctly processed by parameter estimation pipelines, and we need to know about them. We present a semi-automated classification scheme that identifies different types of peculiar spectral morphologies in an effort tomore » discover and flag potentially problematic spectra and thus help to preserve the integrity of the survey results. To this end, we employ the recently developed dimensionality reduction technique t-SNE ( t -distributed stochastic neighbor embedding), which enables us to represent the complex spectral morphology in a two-dimensional projection map while still preserving the properties of the local neighborhoods of spectra. We find that the majority (178,483) of the 209,533 Galah spectra considered in this study represents normal single stars, whereas 31,050 peculiar and problematic spectra with very diverse spectral features pertaining to 28,579 stars are distributed into 10 classification categories: hot stars, cool metal-poor giants, molecular absorption bands, binary stars, H α /H β emission, H α /H β emission superimposed on absorption, H α /H β P-Cygni, H α /H β inverted P-Cygni, lithium absorption, and problematic. Classified spectra with supplementary information are presented in the catalog, indicating candidates for follow-up observations and population studies of the short-lived phases of stellar evolution.« less

Fuel Economy and Emissions of a Vehicle Equipped with an Aftermarket Flexible-Fuel Conversion Kit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas, John F; Huff, Shean P; West, Brian H

2012-04-01

The U.S. Environmental Protection Agency (EPA) grants Certificates of Conformity for alternative fuel conversion systems and also offers other forms of premarket registration of conversion kits for use in vehicles more than two model years old. Use of alternative fuels such as ethanol, natural gas, and propane are encouraged by the Energy Policy Act of 1992. Several original equipment manufacturers (OEMs) produce emissions-certified vehicles capable of using alternative fuels, and several alternative fuel conversion system manufacturers produce EPA-approved conversion systems for a variety of alternative fuels and vehicle types. To date, only one manufacturer (Flex Fuel U.S.) has received EPAmore » certifications for ethanol fuel (E85) conversion kits. This report details an independent evaluation of a vehicle with a legal installation of a Flex Fuel U.S. conversion kit. A 2006 Dodge Charger was baseline tested with ethanol-free certification gasoline (E0) and E20 (gasoline with 20 vol % ethanol), converted to flex-fuel operation via installation of a Flex Box Smart Kit from Flex Fuel U.S., and retested with E0, E20, E50, and E81. Test cycles included the Federal Test Procedure (FTP or city cycle), the highway fuel economy test (HFET), and the US06 test (aggressive driving test). Averaged test results show that the vehicle was emissions compliant on E0 in the OEM condition (before conversion) and compliant on all test fuels after conversion. Average nitrogen oxide (NOx) emissions exceeded the Tier 2/Bin 5 intermediate life NO{sub X} standard with E20 fuel in the OEM condition due to two of three test results exceeding this standard [note that E20 is not a legal fuel for non-flexible-fuel vehicles (non-FFVs)]. In addition, one E0 test result before conversion and one E20 test result after conversion exceeded the NOX standard, although the average result in these two cases was below the standard. Emissions of ethanol and acetaldehyde increased with increasing ethanol, while nonmethane organic gas and CO emissions remained relatively unchanged for all fuels and cycles. Higher fraction ethanol blends appeared to decrease NO{sub X} emissions on the FTP and HFET (after conversion). As expected, fuel economy (miles per gallon) decreased with increasing ethanol content in all cases.« less

Cometary kilometric radio waves and plasma waves correlated with ion pick-up effect at Comet Halley

NASA Technical Reports Server (NTRS)

Oya, H.; Morioka, A.; Miyake, W.; Smith, E. J.; Tsurutani, B. T.

1985-01-01

Bow-shock movements at Comet Halley are inferred from the discrete spectra of the cometary kilometric radiation (30-195 kHz); the observed emissions can be interpreted as being generated and propagating from the moving shock. The shock motion is possibly associated with the time variation of the solar wind and cometary outgassing. It is concluded that these plasma wave phenomena are manifestations of ion pick-up processes, which occur even in a remote region 7 million to 10 million km from the cometary nucleus.

On the Origin of the Flare Emission in IRIS ’ SJI 2832 Filter:Balmer Continuum or Spectral Lines?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kleint, Lucia; Krucker, Säm; Heinzel, Petr

Continuum (“white-light,” WL) emission dominates the energetics of flares. Filter-based observations, such as the IRIS SJI 2832 filter, show WL-like brightenings during flares, but it is unclear whether the emission arises from real continuum emission or enhanced spectral lines, possibly turning into emission. The difficulty in filter-based observations, contrary to spectral observations, is to determine which processes contribute to the observed brightening during flares. Here we determine the contribution of the Balmer continuum and the spectral line emission to IRIS ’ SJI 2832 emission by analyzing the appropriate passband in simultaneous IRIS NUV spectra. We find that spectral line emissionmore » can contribute up to 100% to the observed slitjaw images (SJI) emission, that the relative contributions usually temporally vary, and that the highest SJI enhancements that are observed are most likely because of the Balmer continuum. We conclude that care should be taken when calling SJI 2832 a continuum filter during flares, because the influence of the lines on the emission can be significant.« less

Thermometry properties of Er, Yb-Gd2O2S microparticles: dependence on the excitation mode (cw versus pulsed excitation) and excitation wavelength (980 nm versus 1500 nm)

NASA Astrophysics Data System (ADS)

Avram, Daniel; Tiseanu, Carmen

2018-04-01

Herein, we present a first report on the luminescence thermometry properties of Er, Yb doped Gd2O2S microparticles under near infrared up-conversion excitation at 980 and 1500 nm measured in the 280-800 K interval. The thermometry properties are assessed using both cw and ns pulsed excitation as well as tuning the excitation wavelength across Yb and Er absorption profiles. For low cw (300 mW cm-1) and pulsed ns (400 ÷ 550 mW cm-1) excitation modes, no thermal load is observed. At room-temperature (280 K), the maximum relative sensitivity values are comparable under pulsed excitation at 980 and 1500 nm, around ˜0.01 and ˜0.008% K-1, respectively. In addition, a relative intense up-conversion emission at 980 nm under excitation at 1500 nm is measured. Our findings evidence attractive up-conversion and thermometry properties Er, Yb doped Gd2O2S under near-infrared excitation and highlight the need to explore further these properties in the nanoparticulate regime.

Effects of temporal laser profile on the emission spectra for underwater laser-induced breakdown spectroscopy: Study by short-interval double pulses with different pulse durations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tamura, Ayaka, E-mail: tamura.ayaka.88m@st.kyoto-u.ac.jp; Matsumoto, Ayumu; Nishi, Naoya

We investigate the effects of temporal laser profile on the emission spectra of laser ablation plasma in water. We use short-interval (76 ns) double pulses with different pulse durations of the composing two pulses for the irradiation of underwater target. Narrow atomic spectral lines in emission spectra are obtained by the irradiation, where the two pulses are wide enough to be merged into a single-pulse-like temporal profile, while deformed spectra are obtained when the two pulses are fully separated. The behavior of the atomic spectral lines for the different pulse durations is consistent with that of the temporal profiles of themore » optical emission intensities of the plasma. All these results suggest that continuous excitation of the plasma during the laser irradiation for ∼100 ns is a key to obtain narrow emission spectral lines.« less

A comparative theoretical study on core-hole excitation spectra of azafullerene and its derivatives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng, Yunfeng; Department of Physics, Guizhou University, Guiyang 550025; Gao, Bin, E-mail: bin.gao@uit.no

2014-03-28

The core-hole excitation spectra—near-edge x-ray absorption spectroscopy (NEXAFS), x-ray emission spectroscopy (XES), and x-ray photoelectron spectroscopy (XPS) shake-up satellites have been simulated at the level of density functional theory for the azafullerene C{sub 59}N and its derivatives (C{sub 59}N){sup +}, C{sub 59}HN, (C{sub 59}N){sub 2}, and C{sub 59}N–C{sub 60}, in which the XPS shake-up satellites were simulated using our developed equivalent core hole Kohn-Sham (ECH-KS) density functional theory approach [B. Gao, Z. Wu, and Y. Luo, J. Chem. Phys. 128, 234704 (2008)] which aims for the study of XPS shake-up satellites of large-scale molecules. Our calculated spectra are generally inmore » good agreement with available experimental results that validates the use of the ECH-KS method in the present work. The nitrogen K-edge NEXAFS, XES, and XPS shake-up satellites spectra in general can be used as fingerprints to distinguish the azafullerene C{sub 59}N and its different derivatives. Meanwhile, different carbon K-edge spectra could also provide detailed information of (local) electronic structures of different molecules. In particular, a peak (at around 284.5 eV) in the carbon K-edge NEXAFS spectrum of the heterodimer C{sub 59}N–C{sub 60} is confirmed to be related to the electron transfer from the C{sub 59}N part to the C{sub 60} part in this charge-transfer complex.« less

Modeling the complexity of acoustic emission during intermittent plastic deformation: Power laws and multifractal spectra

NASA Astrophysics Data System (ADS)

Kumar, Jagadish; Ananthakrishna, G.

2018-01-01

Scale-invariant power-law distributions for acoustic emission signals are ubiquitous in several plastically deforming materials. However, power-law distributions for acoustic emission energies are reported in distinctly different plastically deforming situations such as hcp and fcc single and polycrystalline samples exhibiting smooth stress-strain curves and in dilute metallic alloys exhibiting discontinuous flow. This is surprising since the underlying dislocation mechanisms in these two types of deformations are very different. So far, there have been no models that predict the power-law statistics for discontinuous flow. Furthermore, the statistics of the acoustic emission signals in jerky flow is even more complex, requiring multifractal measures for a proper characterization. There has been no model that explains the complex statistics either. Here we address the problem of statistical characterization of the acoustic emission signals associated with the three types of the Portevin-Le Chatelier bands. Following our recently proposed general framework for calculating acoustic emission, we set up a wave equation for the elastic degrees of freedom with a plastic strain rate as a source term. The energy dissipated during acoustic emission is represented by the Rayleigh-dissipation function. Using the plastic strain rate obtained from the Ananthakrishna model for the Portevin-Le Chatelier effect, we compute the acoustic emission signals associated with the three Portevin-Le Chatelier bands and the Lüders-like band. The so-calculated acoustic emission signals are used for further statistical characterization. Our results show that the model predicts power-law statistics for all the acoustic emission signals associated with the three types of Portevin-Le Chatelier bands with the exponent values increasing with increasing strain rate. The calculated multifractal spectra corresponding to the acoustic emission signals associated with the three band types have a maximum spread for the type C bands and decreasing with types B and A. We further show that the acoustic emission signals associated with Lüders-like band also exhibit a power-law distribution and multifractality.

Modeling the complexity of acoustic emission during intermittent plastic deformation: Power laws and multifractal spectra.

PubMed

Kumar, Jagadish; Ananthakrishna, G

2018-01-01

Scale-invariant power-law distributions for acoustic emission signals are ubiquitous in several plastically deforming materials. However, power-law distributions for acoustic emission energies are reported in distinctly different plastically deforming situations such as hcp and fcc single and polycrystalline samples exhibiting smooth stress-strain curves and in dilute metallic alloys exhibiting discontinuous flow. This is surprising since the underlying dislocation mechanisms in these two types of deformations are very different. So far, there have been no models that predict the power-law statistics for discontinuous flow. Furthermore, the statistics of the acoustic emission signals in jerky flow is even more complex, requiring multifractal measures for a proper characterization. There has been no model that explains the complex statistics either. Here we address the problem of statistical characterization of the acoustic emission signals associated with the three types of the Portevin-Le Chatelier bands. Following our recently proposed general framework for calculating acoustic emission, we set up a wave equation for the elastic degrees of freedom with a plastic strain rate as a source term. The energy dissipated during acoustic emission is represented by the Rayleigh-dissipation function. Using the plastic strain rate obtained from the Ananthakrishna model for the Portevin-Le Chatelier effect, we compute the acoustic emission signals associated with the three Portevin-Le Chatelier bands and the Lüders-like band. The so-calculated acoustic emission signals are used for further statistical characterization. Our results show that the model predicts power-law statistics for all the acoustic emission signals associated with the three types of Portevin-Le Chatelier bands with the exponent values increasing with increasing strain rate. The calculated multifractal spectra corresponding to the acoustic emission signals associated with the three band types have a maximum spread for the type C bands and decreasing with types B and A. We further show that the acoustic emission signals associated with Lüders-like band also exhibit a power-law distribution and multifractality.

Optical Studies of CaS:Eu, Sm Infrared Stimulable Phosphors

NASA Astrophysics Data System (ADS)

Tamura, Yasuaki; Shibukawa, Atsushi

1993-07-01

The photoluminescence (PL) and infrared stimulated luminescence (ISL) spectra of CaS:Eu,Sm infrared stimulable phosphors (ISPs) are studied. In addition, the concentration dependence of ISL intensity is examined. Sm3+- and Eu2+-related structures are found in both the PL excitation and emission spectra. Two types of Sm3+ are found, one of which exhibits strong emission at around 650 nm and the other, weak emission compared to the other emissions at around 565 nm and 605 nm. These are assigned to an asymmetric and a symmetric site, respectively. ISL excitation spectra coincide with the Eu2+ 4f7 to 4f65d1 and 4f66s1 transitions and range from 220 to 650 nm. ISL emission spectra coincide with the Eu2+ 4f65d1 to 4f7 transition and range from 550 to 750 nm. ISL stimulation spectra range from 0.8 μm to 1.7 μm and are thought to indicate the Sm2+ ion transition from 4f6 to 4f55d1. The maximum ISL intensity is obtained from a sample with Eu and Sm concentrations of 500 and 130 ppm, respectively.

Synchrotron emission from nanowire array targets irradiated by ultraintense laser pulses

NASA Astrophysics Data System (ADS)

Martinez, B.; d’Humières, E.; Gremillet, L.

2018-07-01

We present a numerical study, based on two-dimensional particle-in-cell simulations, of the synchrotron emission induced during the interaction of femtosecond laser pulses of intensities I = 1021–1023 W cm‑2 with nanowire arrays. Through an extensive parametric scan on the target parameters, we identify and characterize several dominant radiation mechanisms, mainly depending on the transparency or opacity of the plasma produced by the wire expansion. At I = 1022 W m‑2, the emission of high-energy (>10 keV) photons attains a maximum conversion efficiency of ∼10% for 36–50 nm wire widths and 1 μm interspacing. This maximum radiation yield is found to be similar to that achieved in a uniform plasma of same average (sub-solid) density, but nanowire arrays provide efficient radiation sources over a broader parameter range. Moreover, we examine the variations of the photon spectra with the laser intensity and the wire material, and we demonstrate that the radiation efficiency can be further enhanced by adding a plasma mirror at the backside of the nanowire array. Finally, we briefly consider the influence of a finite laser focal spot and oblique incidence angle.

Effect of Annealing Time of YAG:Ce3+ Phosphor on White Light Chromaticity Values

NASA Astrophysics Data System (ADS)

Abd, Husnen R.; Hassan, Z.; Ahmed, Naser M.; Almessiere, Munirah Abdullah; Omar, A. F.; Alsultany, Forat H.; Sabah, Fayroz A.; Osman, Ummu Shuhada

2018-02-01

Yttrium and aluminium nitrate phosphors doped with cerium nitrate and mixed with urea (fuel) are prepared by using microwave-induced combustion synthesis according to the formula Y(3-0.06)Al5O12:0.06Ce3+ (YAG:Ce3+) to produce white light emitting diodes by conversion from blue indium gallium nitride-light emitting diode chips. The sintering time with fixed temperature (1050°C) for phosphor powder was optimized and found to be 5 h. The crystallinity, structure, chemical composition, luminescent properties with varying currents densities and chromaticity were characterized by x-ray diffraction, field emission-scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, photoluminescence emission, electroluminescence and standard CIE 1931 chromaticity diagram, respectively. The energy levels of Ce3+ in YAG were discussed based on its absorption and excitation spectra. The results show that the obtained YAG:Ce3+ phosphor sintered for 5 h has good crystallinity with pure phase, low agglomerate with spherical shaped particles and strong yellow emission, offering cool-white LED with tuneable correlated color temperature and a good color rendering index compared to those prepared by sintering for 2 h and as-prepared phosphor powders.

Luminescence and luminescence quenching of highly efficient Y2Mo4O15:Eu3+ phosphors and ceramics

PubMed Central

Janulevicius, Matas; Marmokas, Paulius; Misevicius, Martynas; Grigorjevaite, Julija; Mikoliunaite, Lina; Sakirzanovas, Simas; Katelnikovas, Arturas

2016-01-01

A good LED phosphor must possess strong enough absorption, high quantum yields, colour purity, and quenching temperatures. Our synthesized Y2Mo4O15:Eu3+ phosphors possess all of these properties. Excitation of these materials with near-UV or blue radiation yields bright red emission and the colour coordinates are relatively stable upon temperature increase. Furthermore, samples doped with 50% Eu3+ showed quantum yields up to 85%, what is suitable for commercial application. Temperature dependent emission spectra revealed that heavily Eu3+ doped phosphors possess stable emission up to 400 K and lose half of the efficiency only at 515 K. In addition, ceramic disks of Y2Mo4O15:75%Eu3+ phosphor with thickness of 0.71 and 0.98 mm were prepared and it turned out that they efficiently convert radiation of 375 and 400 nm LEDs to the red light, whereas combination with 455 nm LED yields purple colour. PMID:27180941

Luminescence and luminescence quenching of highly efficient Y2Mo4O15:Eu(3+) phosphors and ceramics.

PubMed

Janulevicius, Matas; Marmokas, Paulius; Misevicius, Martynas; Grigorjevaite, Julija; Mikoliunaite, Lina; Sakirzanovas, Simas; Katelnikovas, Arturas

2016-05-16

A good LED phosphor must possess strong enough absorption, high quantum yields, colour purity, and quenching temperatures. Our synthesized Y2Mo4O15:Eu(3+) phosphors possess all of these properties. Excitation of these materials with near-UV or blue radiation yields bright red emission and the colour coordinates are relatively stable upon temperature increase. Furthermore, samples doped with 50% Eu(3+) showed quantum yields up to 85%, what is suitable for commercial application. Temperature dependent emission spectra revealed that heavily Eu(3+) doped phosphors possess stable emission up to 400 K and lose half of the efficiency only at 515 K. In addition, ceramic disks of Y2Mo4O15:75%Eu(3+) phosphor with thickness of 0.71 and 0.98 mm were prepared and it turned out that they efficiently convert radiation of 375 and 400 nm LEDs to the red light, whereas combination with 455 nm LED yields purple colour.

Bottom-up photonic crystal cavities formed by patterned III-V nanopillars.

PubMed

Scofield, Adam C; Shapiro, Joshua N; Lin, Andrew; Williams, Alex D; Wong, Ping-Show; Liang, Baolai L; Huffaker, Diana L

2011-06-08

We report on the formation and optical properties of bottom-up photonic crystal (PC) cavities formed by III-V nanopillars (NPs) via catalyst-free selective-area metal-organic chemical vapor deposition on masked GaAs substrates. This method of NP synthesis allows for precise lithographic control of NP position and diameter enabling simultaneous formation of both the photonic band gap (PBG) region and active gain region. The PBG and cavity resonance are determined by independently tuning the NP radius r, pitch a, and height h in the respective masked areas. Near-infrared emission at 970 nm is achieved from axial GaAs/InGaAs heterostructures with in situ passivation by laterally grown InGaP shells. To achieve out-of-plane optical confinement, the PC cavities are embedded in polydimethylsiloxane (PDMS) and removed from the growth substrate. Spatially and spectrally resolved 77 K photoluminescence demonstrates a strong influence of the PBG resonance on device emission. Resonant peaks are observed in the emission spectra of PC cavities embedded in PDMS.

Characterizing the X-ray Emission in Small Magellanic Cloud Supernova Remnants

NASA Astrophysics Data System (ADS)

Man, Nicole; Auchettl, Katie; Lopez, Laura

2018-01-01

The Small Magellanic Cloud is a close, metal-poor galaxy with active star formation, and it has a diverse population of 24 supernova remnants (SNRs) that have been identified at several wavelengths. Past work has characterized the X-ray emission in these sources separately and aimed to constrain their explosive origins from observations with Chandra and XMM-Newton. Three SNRs have possible evidence for Type Ia explosions based on strong Fe-L emission in their X-ray spectra, although the environments and intermediate-mass element abundances are more consistent with those of core-collapse SNe. In this poster, we analyze the archival Chandra and XMM-Newton observations of the SMC SNR sample, and we model the sources' X-ray spectra in a systematic way to derive the plasma properties and to constrain the nature of the explosions. In one SNR, we note the presence of an X-ray binary near the source's geometric center, suggesting the compact object was produced in the SN explosion. As one of only three SNRs known in the Local Group to host a binary system, this source is worthy of follow-up investigations to probe explosions of massive stars in binary systems.

MIPAS middle atmosphere water vapor distributions

NASA Astrophysics Data System (ADS)

Garcia-Comas, Maya; Lopez-Puertas, Manuel; Funke, Bernd; Bermejo-Pantale, Diego; Stiller, Gabriele; Grabowski, Udo; von Clarmann, Thomas

Water vapor is a key constituent of the middle atmosphere. It is involved in the ozone chem-istry, it is the precursor of PSCs and PMCs, and it is an infrared cooler in the stratosphere. The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) onboard Envisat observes the H2O infrared emissions with high resolution up to the mesopause. We have derived water vapor abundance from MIPAS spectra using the IMK/IAA data processor, which includes the GRANADA non-LTE algorithm. That allows for accurate H2O retrievals in the atmospheric regions where its emissions are affected by non-LTE, i.e., above 50km and particularly in the polar summer. We describe the information gained from MIPAS spectra about the non-LTE processes affecting the H2O infrared emissions, discuss its uncertainties and present MIPAS pole-to-pole distributions of water vapor retrieved from the stratosphere to the upper meso-sphere. We pay special attention to its behavior in the polar summer mesosphere, where the presence of PMCs and particular dynamical events may perturb the H2O vertical distribution. We also compare our results with those from global circulation models and other independent measurements.

Carbon dioxide emissions and the overshoot ratio change resulting from the implementation of 2nd Energy Master Plan in South Korea

NASA Astrophysics Data System (ADS)

Yeo, M. J.; Kim, Y. P.

2015-12-01

The direction of the energy policies of the country is important in the projection of environmental impacts of the country. The greenhouse gases (GHGs) emission of the energy sector in South Korea is very huge, about 600 MtCO2e in 2011. Also the carbon footprint due to the energy consumption contributes to the ecological footprint is also large, more than 60%. Based on the official plans (the national greenhouse gases emission reduction target for 2030 (GHG target for 2030) and the 2nd Energy Master Plan (2nd EMP)), several scenarios were proposed and the sensitivity of the GHG emission amount and 'overshoot ratio' which is the ratio of ecological footprint to biocapacity were estimated. It was found that to meet the GHG target for 2030 the ratio of non-emission energy for power generation should be over 71% which would be very difficult. We also found that the overshoot ratio would increase from 5.9 in 2009 to 7.6 in 2035. Thus, additional efforts are required to reduce the environmental burdens in addition to optimize the power mix configuration. One example is the conversion efficiency in power generation. If the conversion efficiency in power generation rises up 50% from the current level, 40%, the energy demand and resultant carbon dioxide emissions would decrease about 10%. Also the influence on the environment through changes in consumption behavior, for example, the diet choice is expected to be meaningful.

Substantial N2O emission during the initial period of the wheat season due to the conversion of winter-flooded paddy to rice-wheat rotation

NASA Astrophysics Data System (ADS)

Zhou, Wei; Lin, Shan; Wu, Lei; Zhao, Jingsong; Wang, Milan; Zhu, Bo; Mo, Yongliang; Hu, Ronggui; Chadwick, Dave; Shaaban, Muhammad

2017-12-01

Winter-flooded paddy is a typical rice-based cropping system to conserve water for the next rice growing season. Conversion of winter-flooded paddy to rice-wheat rotation has been widely adopted with the development of the water conservation infrastructure and the government's encouragement of winter agriculture in China in recent decades. However, the effects of this conversion on N2O emission are still not clear. Three winter-flooded paddy fields were studied in a split-plot design. One-half of each field was converted to rice-wheat rotation (RW), and the other half remained winter-flooded as rice-fallow (RF). Each plot of RW and RF was further divided into four subplots: three subplots for conventional N fertilizer application (RW-NC and RF-NC) and one for unfertilized treatment (RW-N0 and RF-N0). Conversion of RF-NC to RW-NC increased the N2O emission up to 6.6-fold in the first year and 4.4-fold in the second year. Moreover, N2O emissions for the entire wheat season were 1.74-3.74 kg N ha-1 and 0.24-0.31 kg N ha-1 from RW-NC and RW-N0, respectively, and accounted for 78%-94% and 78%-97% of the total annual amount. N2O emitted during the first 11-21 days of the wheat season from RW-NC was 1.48-3.28 kg N ha-1 and that from RW-N0 was 0.14-0.17 kg N ha-1, which contributed to 66%-82% and 45%-71% of the total annual amount, respectively. High N2O fluxes occurred when the soil water-filled pore space (WFPS) was in the range of 68%-72% and the ratio of available carbon to nitrogen in the soil was <1.42. The contribution of WFPS and dissolved organic carbon (DOC) explained most of the variation of the N2O fluxes compared with the other measured environmental and soil factors. These findings suggest that the conversion of winter-flooded paddy to rice-wheat rotation increased N2O emissions that could be mitigated by controlling the soil moisture and ratio of available soil carbon to nitrogen.

Bovine Host Genetic Variation Influences Rumen Microbial Methane Production with Best Selection Criterion for Low Methane Emitting and Efficiently Feed Converting Hosts Based on Metagenomic Gene Abundance

PubMed Central

Roehe, Rainer; Dewhurst, Richard J.; Duthie, Carol-Anne; Rooke, John A.; McKain, Nest; Ross, Dave W.; Hyslop, Jimmy J.; Waterhouse, Anthony; Freeman, Tom C.

2016-01-01

Methane produced by methanogenic archaea in ruminants contributes significantly to anthropogenic greenhouse gas emissions. The host genetic link controlling microbial methane production is unknown and appropriate genetic selection strategies are not developed. We used sire progeny group differences to estimate the host genetic influence on rumen microbial methane production in a factorial experiment consisting of crossbred breed types and diets. Rumen metagenomic profiling was undertaken to investigate links between microbial genes and methane emissions or feed conversion efficiency. Sire progeny groups differed significantly in their methane emissions measured in respiration chambers. Ranking of the sire progeny groups based on methane emissions or relative archaeal abundance was consistent overall and within diet, suggesting that archaeal abundance in ruminal digesta is under host genetic control and can be used to genetically select animals without measuring methane directly. In the metagenomic analysis of rumen contents, we identified 3970 microbial genes of which 20 and 49 genes were significantly associated with methane emissions and feed conversion efficiency respectively. These explained 81% and 86% of the respective variation and were clustered in distinct functional gene networks. Methanogenesis genes (e.g. mcrA and fmdB) were associated with methane emissions, whilst host-microbiome cross talk genes (e.g. TSTA3 and FucI) were associated with feed conversion efficiency. These results strengthen the idea that the host animal controls its own microbiota to a significant extent and open up the implementation of effective breeding strategies using rumen microbial gene abundance as a predictor for difficult-to-measure traits on a large number of hosts. Generally, the results provide a proof of principle to use the relative abundance of microbial genes in the gastrointestinal tract of different species to predict their influence on traits e.g. human metabolism, health and behaviour, as well as to understand the genetic link between host and microbiome. PMID:26891056

Bovine Host Genetic Variation Influences Rumen Microbial Methane Production with Best Selection Criterion for Low Methane Emitting and Efficiently Feed Converting Hosts Based on Metagenomic Gene Abundance.

PubMed

Roehe, Rainer; Dewhurst, Richard J; Duthie, Carol-Anne; Rooke, John A; McKain, Nest; Ross, Dave W; Hyslop, Jimmy J; Waterhouse, Anthony; Freeman, Tom C; Watson, Mick; Wallace, R John

2016-02-01

Methane produced by methanogenic archaea in ruminants contributes significantly to anthropogenic greenhouse gas emissions. The host genetic link controlling microbial methane production is unknown and appropriate genetic selection strategies are not developed. We used sire progeny group differences to estimate the host genetic influence on rumen microbial methane production in a factorial experiment consisting of crossbred breed types and diets. Rumen metagenomic profiling was undertaken to investigate links between microbial genes and methane emissions or feed conversion efficiency. Sire progeny groups differed significantly in their methane emissions measured in respiration chambers. Ranking of the sire progeny groups based on methane emissions or relative archaeal abundance was consistent overall and within diet, suggesting that archaeal abundance in ruminal digesta is under host genetic control and can be used to genetically select animals without measuring methane directly. In the metagenomic analysis of rumen contents, we identified 3970 microbial genes of which 20 and 49 genes were significantly associated with methane emissions and feed conversion efficiency respectively. These explained 81% and 86% of the respective variation and were clustered in distinct functional gene networks. Methanogenesis genes (e.g. mcrA and fmdB) were associated with methane emissions, whilst host-microbiome cross talk genes (e.g. TSTA3 and FucI) were associated with feed conversion efficiency. These results strengthen the idea that the host animal controls its own microbiota to a significant extent and open up the implementation of effective breeding strategies using rumen microbial gene abundance as a predictor for difficult-to-measure traits on a large number of hosts. Generally, the results provide a proof of principle to use the relative abundance of microbial genes in the gastrointestinal tract of different species to predict their influence on traits e.g. human metabolism, health and behaviour, as well as to understand the genetic link between host and microbiome.

Parmeterization of spectra

NASA Technical Reports Server (NTRS)

Cornish, C. R.

1983-01-01

Following reception and analog to digital conversion (A/D) conversion, atmospheric radar backscatter echoes need to be processed so as to obtain desired information about atmospheric processes and to eliminate or minimize contaminating contributions from other sources. Various signal processing techniques have been implemented at mesosphere-stratosphere-troposphere (MST) radar facilities to estimate parameters of interest from received spectra. Such estimation techniques need to be both accurate and sufficiently efficient to be within the capabilities of the particular data-processing system. The various techniques used to parameterize the spectra of received signals are reviewed herein. Noise estimation, electromagnetic interference, data smoothing, correlation, and the Doppler effect are among the specific points addressed.

Using 3D dynamic models to reproduce X-ray properties of colliding wind binaries

NASA Astrophysics Data System (ADS)

Russell, Christopher Michael Post

Colliding wind binaries (CWBs) are unique laboratories for X-ray astrophysics. The two massive stars contained in these systems have powerful radiatively driven stellar winds, and the conversion of their kinetic energy to heat (up to 108 K) at the wind-wind collision region generates hard thermal X-rays (up to 10 keV). Rich data sets exist of several multi-year-period systems, as well as key observations of shorter period systems, and detailed models are required to disentangle the phase-locked emission and absorption processes in these systems. To interpret these X-ray light curves and spectra, this dissertation models the wind-wind interaction of CWBs using 3D smoothed particle hydrodynamics (SPH), and solves the 3D formal solution of radiative transfer to synthesize the model X-ray properties, allowing direct comparison with the colliding-wind X-ray spectra observed by, e.g., RXTE and XMM. The multi-year-period, highly eccentric CWBs we examine are eta Carinae and WR140. For the commonly inferred primary mass loss rate of ˜10 -3 Msun/yr, eta Carinae's 3D model reproduces quite well the 2-10 keV RXTE light curve, hardness ratio, and dynamic spectra in absolute units. This agreement includes the ˜3 month X-ray minimum associated with the 1998.0 and 2003.5 periastron passages, which we find to occur as the primary wind encroaches into the secondary wind's acceleration region. This modeling provides further evidence that the observer is mainly viewing the system through the secondary's shock cone, and suggests that periastron occurs ~1 month after the onset of the X-ray minimum. The model RXTE observables of WR140 match the data well in absolute units, although the decrease in model X-rays around periastron is less than observed. There is very good agreement between the observed XMM spectrum taken on the rise before periastron and the model. We also model two short-period CWBs, HD150136, which has a wind-star collision, and delta Orionis A, the closest eclipsing CWB. The asymmetry predicted in the unobserved portion of HD150136's orbit, and the line profile variations due to the cavity carved into the primary wind by the secondary in delta Orionis A, helped provide a basis for newly approved Chandra observations of both systems.

Preliminary Estimates of the Potential for Carbon Mitigation in European Soils Through No-Till Farming

DOE Data Explorer

Smith, P. [University of Aberdeen, Aberdeen, UK; Powlson, D. [University of Aberdeen, Aberdeen, UK; Glendining, M. [University of Aberdeen, Aberdeen, UK; Smith, J. [University of Aberdeen, Aberdeen, UK

2003-01-01

in this paper we estimate the European potential for carbon mitigation of no-till farming using results from European tillage experiments. Our calculations suggest some potential in terms of (a) reduced agricultural fossil fuel emissions, and (b) increased soil carbon sequestration. We estimate that 100% conversion to no-till farming would be likely to sequester about 23 Tg C y^–11 in the European Union or about 43 Tg C y^–1 in the wider Europe (excluding the former Soviet Union). In addition, up to 3.2 Tg C y^–1 could be saved in agricultural fossil fuel emissions. Compared to estimates of the potential for carbon sequestration of other carbon mitigation options, no-till agriculture shows nearly twice the potential of scenarios whereby soils are amended with organic materials. Our calculations suggest that 100% conversion to no-till agriculture in Europe could mitigate all fossil fuel-carbon emissions from agriculture in Europe. However, this is equivalent to only about 4.1% of total anthropogenic CO2-carbon produced annually in Europe (excluding the former Soviet Union) which in turn is equivalent to about 0.8% of global annual anthropogenic CO2-carbon emissions.

Ultrabroadband phased-array radio frequency (RF) receivers based on optical techniques

NASA Astrophysics Data System (ADS)

Overmiller, Brock M.; Schuetz, Christopher A.; Schneider, Garrett; Murakowski, Janusz; Prather, Dennis W.

2014-03-01

Military operations require the ability to locate and identify electronic emissions in the battlefield environment. However, recent developments in radio detection and ranging (RADAR) and communications technology are making it harder to effectively identify such emissions. Phased array systems aid in discriminating emitters in the scene by virtue of their relatively high-gain beam steering and nulling capabilities. For the purpose of locating emitters, we present an approach realize a broadband receiver based on optical processing techniques applied to the response of detectors in conformal antenna arrays. This approach utilizes photonic techniques that enable us to capture, route, and process the incoming signals. Optical modulators convert the incoming signals up to and exceeding 110 GHz with appreciable conversion efficiency and route these signals via fiber optics to a central processing location. This central processor consists of a closed loop phase control system which compensates for phase fluctuations induced on the fibers due to thermal or acoustic vibrations as well as an optical heterodyne approach for signal conversion down to baseband. Our optical heterodyne approach uses injection-locked paired optical sources to perform heterodyne downconversion/frequency identification of the detected emission. Preliminary geolocation and frequency identification testing of electronic emissions has been performed demonstrating the capabilities of our RF receiver.

Luminous and Variable Stars in M31 and M33. IV. Luminous Blue Variables, Candidate LBVs, B[e] Supergiants, and the Warm Hypergiants: How to Tell Them Apart

DOE Office of Scientific and Technical Information (OSTI.GOV)

Humphreys, Roberta M.; Gordon, Michael S.; Hahn, David

In this series of papers we have presented the results of a spectroscopic survey of luminous stars in the nearby spirals M31 and M33. Here, we present spectroscopy of 132 additional stars. Most have emission-line spectra, including luminous blue variables (LBVs) and candidate LBVs, Fe ii emission line stars, the B[e] supergiants, and the warm hypergiants. Many of these objects are spectroscopically similar and are often confused with each other. We examine their similarities and differences and propose the following guidelines that can be used to help distinguish these stars in future work. (1) The B[e] supergiants have emission linesmore » of [O i] and [Fe ii] in their spectra. Most of the spectroscopically confirmed sgB[e] stars also have warm circumstellar dust in their spectral energy distributions (SEDs). (2) Confirmed LBVs do not have the [O i] emission lines in their spectra. Some LBVs have [Fe ii] emission lines, but not all. Their SEDs show free–free emission in the near-infrared but no evidence for warm dust . Their most important and defining characteristic is the S Dor-type variability. (3) The warm hypergiants spectroscopically resemble the LBVs in their dense wind state and the B[e] supergiants. However, they are very dusty. Some have [Fe ii] and [O i] emission in their spectra like the sgB[e] stars, but are distinguished by their A- and F-type absorption-line spectra. In contrast, the B[e] supergiant spectra have strong continua and few if any apparent absorption lines. Candidate LBVs should share the spectral characteristics of the confirmed LBVs with low outflow velocities and the lack of warm circumstellar dust.« less

Investigating the Near-Infrared Properties of Planetary Nebulae II. Medium Resolution Spectra. 2; Medium Resolution Spectra

NASA Technical Reports Server (NTRS)

Hora, Joseph L.; Latter, William B.; Deutsch, Lynne K.

1998-01-01

We present medium-resolution (R approximately 700) near-infrared (lambda = 1 - 2.5 micrometers) spectra of a sample of planetary nebulae (PNe). A narrow slit was used which sampled discrete locations within the nebulae; observations were obtained at one or more positions in the 41 objects included in the survey. The PN spectra fall into one of four general categories: H1 emission line-dominated PNe, H1 and H2 emission line PNe, H2 emission line-dominated PNe, and continuum-dominated PNe. These categories correlate with morphological type, with the elliptical PNe falling into the first group, and the bipolar PNe primarily in the H2 and continuum emission groups. The categories also correlate with C/O ratio, with the O-rich objects falling into the first group and the C-rich objects in the groups. Other spectral features were observed in all catagories, such as continuum emission from the central star, and warm dust continuum emission towards the long wavelength end of the spectra. H2 was detected in four PNe in this survey for the first time. An analysis was performed using the H2 line ratios in all of the PN spectra in the survey where a sufficient number of lines were observed to determine the ortho-to-para ratio and the rotational and vibrational excitation temperatures of the H-2 in those objects. One unexpected result from this analysis is that the H-2 is excited by absorption of ultraviolet photons in most of the PNe, although there are several PNe in which collisional excitation plays an important role. The correlation between bipolar morphology and H2 emission has been strengthened with the new detections of H2 in this survey.

Light up-conversion from near-infrared to blue using a photoresponsive organic light-emitting device

NASA Astrophysics Data System (ADS)

Chikamatsu, Masayuki; Ichino, Yoshiro; Takada, Noriyuki; Yoshida, Manabu; Kamata, Toshihide; Yase, Kiyoshi

2002-07-01

A photoresponsive organic light-emitting device combining blue-emitting organic electroluminescent (EL) diode with titanyl phthalocyanine as a near-infrared (IR) sensitive layer was fabricated. By irradiating near-IR light to the device, blue emission occurred in the lower drive voltage (between 5 and 12 V). The result indicates that the device acts as a light switch and/or an up-converter from near-IR light (1.6 eV) to blue (2.6 eV). The EL response times of rise and decay using a near-IR light trigger were 260 and 330 mus, respectively. At a higher voltage (above 12 V), enhancement of blue emission was observed with near-IR light irradiation. The ON/OFF ratio reached a maximum of 103.

Aptamer-Mediated Up-conversion Core/MOF Shell Nanocomposites for Targeted Drug Delivery and Cell Imaging

PubMed Central

Deng, Kerong; Hou, Zhiyao; Li, Xuejiao; Li, Chunxia; Zhang, Yuanxin; Deng, Xiaoran; Cheng, Ziyong; Lin, Jun

2015-01-01

Multifunctional nanocarriers for targeted bioimaging and drug delivery have attracted much attention in early diagnosis and therapy of cancer. In this work, we develop a novel aptamer-guided nanocarrier based on the mesoporous metal-organic framework (MOF) shell and up-conversion luminescent NaYF4:Yb3+/Er3+ nanoparticles (UCNPs) core for the first time to achieve these goals. These UCNPs, chosen as optical labels in biological assays and medical imaging, could emit strong green emission under 980 nm laser. The MOF structure based on iron (III) carboxylate materials [MIL-100 (Fe)] possesses high porosity and non-toxicity, which is of great value as nanocarriers for drug storage/delivery. As a unique nanoplatform, the hybrid inorganic-organic drug delivery vehicles show great promising for simultaneous targeted labeling and therapy of cancer cells. PMID:25597762

Diffuse emission and pathological Seyfert spectra

NASA Technical Reports Server (NTRS)

Halpern, Jules P.

1995-01-01

In this annual ROSAT status report, the diffuse emission and spectra from Seyfert galaxies are examined. Three papers are presented and their contents include the soft x-ray properties and spectra of a binary millisecond pulsar, the PSPC and HRI observations of a Starburst/Seyfert 2 Galaxy, and an analysis of the possibility of x-ray luminous starbursts in the Einstein Medium Sensitivity Survey.

The effect of surface pre-conditioning treatments on the local composition of Zr-based conversion coatings formed on aluminium alloys

NASA Astrophysics Data System (ADS)

Cerezo, J.; Vandendael, I.; Posner, R.; de Wit, J. H. W.; Mol, J. M. C.; Terryn, H.

2016-03-01

This study investigates the effect of different alkaline, acidic and thermal pre-conditioning treatments applied to different Al alloy surfaces. The obtained results are compared to the characteristics of Zr-based conversion coatings that were subsequently generated on top of these substrates. Focus is laid on typical elemental distributions on the sample surfaces, in particular on the amount of precipitated functional additives such as Cu species that are present in the substrate matrix as well as in the conversion bath solutions. To this aim, Field Emission Auger Electron spectra, depth profiles and surface maps with superior local resolution were acquired and compared to scanning electron microscopy images of the sample. The results show how de-alloying processes, which occur at and around intermetallic particles in the Al matrix during typical industrial alkaline or acidic cleaning procedures, provide a significant source of crystallization cores for any following coating processes. This is in particular due for Cu-species, as the resulting local Cu structures on the surface strongly affect the film formation and compositions of state-of-the-art Zr-based films. The findings are highly relevant for industrial treatments of aluminium surfaces, especially for those that undergo corrosion protection and painting process steps prior to usage.

Numerical models for the diffuse ionized gas in galaxies. I. Synthetic spectra of thermally excited gas with turbulent magnetic reconnection as energy source

NASA Astrophysics Data System (ADS)

Hoffmann, T. L.; Lieb, S.; Pauldrach, A. W. A.; Lesch, H.; Hultzsch, P. J. N.; Birk, G. T.

2012-08-01

Aims: The aim of this work is to verify whether turbulent magnetic reconnection can provide the additional energy input required to explain the up to now only poorly understood ionization mechanism of the diffuse ionized gas (DIG) in galaxies and its observed emission line spectra. Methods: We use a detailed non-LTE radiative transfer code that does not make use of the usual restrictive gaseous nebula approximations to compute synthetic spectra for gas at low densities. Excitation of the gas is via an additional heating term in the energy balance as well as by photoionization. Numerical values for this heating term are derived from three-dimensional resistive magnetohydrodynamic two-fluid plasma-neutral-gas simulations to compute energy dissipation rates for the DIG under typical conditions. Results: Our simulations show that magnetic reconnection can liberate enough energy to by itself fully or partially ionize the gas. However, synthetic spectra from purely thermally excited gas are incompatible with the observed spectra; a photoionization source must additionally be present to establish the correct (observed) ionization balance in the gas.

IUE Spectra and photoionization models of the Seyfert 2 glaxies NGC 7674 and I Zw 92

NASA Technical Reports Server (NTRS)

Kraemer, Steven B.; Wu, Chi-Chao; Crenshaw, D. Michael; Harrington, J. Patrick

1994-01-01

The physical conditions in the narrow-line regions of two Seyfert 2 galaxies, NGC 7674 and I Zw 92, are examined using IUE spectra, published optical spectra and multifrequency observations, and photoionization models. For each Seyfert galaxy, the emission-line fluxes were dereddened using the He II lambda(1640)/lambda(4686) ratio. Photoionization models were calculated using a power-law index determined from the He II lambda(4686)/H-beta ratio; the index is very similar to that obtained from a fit to the observed multifrequency continuum from the infrared to the X-rays. The models were calculated in a way that minimized the number of assumptions, and given the uncertainties in the reddening corrections, the calculated ratios match nearly all of the dereddened ratios successfully. a multicomponent model (three components with different densities and ionization parameters) was required to fit the spectrum of I Zw 92, whereas a single component was sufficient for NGC 7674. The CNO abundances are close to solar, although a reduced abundance of up to one-third solar for one or more of the heavy elements is possible. In contrast to a previous study of Mrk 3, dust inside the narrow-line region (NLR) louds was not required to fit the spectra of these two Seyfert galaxies, although the emission lines experience considerable reddening from external dust. Higher signal-to-noise spectra in the UV are essential for placing further restrictions on the reddening and physical conditions in the narrow-line regions of Seyfert galaxies.

New Constraints on the Geometry and Kinematics of Matter Surrounding the Accretion Flow in X-Ray Binaries from Chandra High-energy Transmission Grating X-Ray Spectroscopy

NASA Astrophysics Data System (ADS)

Tzanavaris, P.; Yaqoob, T.

2018-03-01

The narrow, neutral Fe Kα fluorescence emission line in X-ray binaries (XRBs) is a powerful probe of the geometry, kinematics, and Fe abundance of matter around the accretion flow. In a recent study it has been claimed, using Chandra High-Energy Transmission Grating (HETG) spectra for a sample of XRBs, that the circumnuclear material is consistent with a solar-abundance, uniform, spherical distribution. It was also claimed that the Fe Kα line was unresolved in all cases by the HETG. However, these conclusions were based on ad hoc models that did not attempt to relate the global column density to the Fe Kα line emission. We revisit the sample and test a self-consistent model of a uniform, spherical X-ray reprocessor against HETG spectra from 56 observations of 14 Galactic XRBs. We find that the model is ruled out in 13/14 sources because a variable Fe abundance is required. In two sources a spherical distribution is viable, but with nonsolar Fe abundance. We also applied a solar-abundance Compton-thick reflection model, which can account for the spectra that are inconsistent with a spherical model, but spectra with a broader bandpass are required to better constrain model parameters. We also robustly measured the velocity width of the Fe Kα line and found FWHM values of up to ∼5000 km s‑1. Only in some spectra was the Fe Kα line unresolved by the HETG.

One step Pd(0)-catalyzed synthesis, X-ray analysis, and photophysical properties of cyclopent[hi]aceanthrylene: fullerene-like properties in a nonalternant cyclopentafused aromatic hydrocarbon.

PubMed

Dang, Hung; Levitus, Marcia; Garcia-Garibay, Miguel A

2002-01-09

A simple procedure for the synthesis of cyclopentafused polycyclic aromatic hydrocarbons (CP-PAH) with Pd(PPh(3))(2)Cl(2) catalyst has been applied to the one-pot palladium(0)-catalyzed coupling of 9,10-dibromoanthracene (1) with 2-methyl-3-butyn-2-ol. Reactions carried out in refluxing benzene in the presence of CuSO(4)/Al(2)O(3) yielded 9,10-dialkynylanthracene 2a, alkynyl aceanthrylene 2b, and 2,7-disubstituted cyclopent[hi]aceanthrylene 2c in 13%, 23%, and 19% purified yields, respectively, with total conversions of 80-90%. Sealed tube reactions without copper at 110 degrees C improved the yield of 2c up to >75%. Single-crystal X-ray analyses of 2a and 2c reveal a three-dimensional hydrogen bonding network, producing a unique crystal packing. The packing structure of 2b is dominated by pi-pi stacking interactions between two aceanthrylene molecules. CP-PAHs 2b and 2c have potentially interesting fullerene-like photophysics. While the UV-vis and fluorescence spectra of 2a (Phi(F) = 0.87) show the characteristic vibronic structure of anthracene, the UV-vis spectra of ruby-red aceanthrylene 2b and greenish-black cyclopent[hi]aceanthrylene 2c extend well into the visible range. Isomers 2b and 2c showed no detectable fluorescence emission. Unlike fullerenes, compounds 2b and 2c are poor singlet oxygen sensitizers with measured (1)O(2) quantum yields of 0.02 and 0.06, respectively. As expected from a simple Hückel analysis, 2c has relatively low two-electron reduction potentials as determined by cyclic voltammetry.

K β X-Ray Emission Spectra of Phosphorus Oxo Acids and Anions

NASA Astrophysics Data System (ADS)

Sugiura, Chikara

1995-03-01

With a high-resolution two-crystal vacuum spectrometer, the phosphorus Kβ emission spectra in fluorescence are measured for H3PO3 (= H2PHO3), H3PO4, Li3PO4, Na3PO4·12H2O, Na2HPO4, NaH2PO4, K3PO4·nH2O, K2HPO4, KH2PO4, Ca3(PO4)2, CaHPO4·2H2O, Ca(H2PO4)2·H2O, CaHPO3·H2O, Ca(H2PO2)2 and NH4H2PO4. In the phosphate compounds, a weak peak is observed on the high-energy side of the main peak Kβ1 and related to a molecular orbital of t2 symmetry in the PO43- ion. It is shown that the phosphorus Kβ emission spectra are influenced by ligand substitution and cations. The measured Kβ emission spectra of Li3PO4, Na3PO4·12H2O, K3PO4·nH2O and Ca3(PO4)2 are presented along with the previously reported P-K absorption spectra of these phosphate compounds. The emission and absorption spectra are interpreted in terms of available molecular orbitals of the PO43- ion.

A case study on the myth of emission from aliphatic amides

NASA Astrophysics Data System (ADS)

Singh, Avinash Kumar; Das, Sreyashi; Datta, Anindya

2016-12-01

For several decades, aliphatic amidic compounds have been believed to be emissive. We report that this contention is incorrect and that the anomalous emission from amides originates in fluorescent impurities generated during their synthesis. In order to make this point, we have synthesized fluorescent compounds and have compared the absorption spectra with excitation spectra.

Simple performance evaluation of pulsed spontaneous parametric down-conversion sources for quantum communications.

PubMed

Smirr, Jean-Loup; Guilbaud, Sylvain; Ghalbouni, Joe; Frey, Robert; Diamanti, Eleni; Alléaume, Romain; Zaquine, Isabelle

2011-01-17

Fast characterization of pulsed spontaneous parametric down conversion (SPDC) sources is important for applications in quantum information processing and communications. We propose a simple method to perform this task, which only requires measuring the counts on the two output channels and the coincidences between them, as well as modeling the filter used to reduce the source bandwidth. The proposed method is experimentally tested and used for a complete evaluation of SPDC sources (pair emission probability, total losses, and fidelity) of various bandwidths. This method can find applications in the setting up of SPDC sources and in the continuous verification of the quality of quantum communication links.

Modeling Fe II Emission and Revised Fe II (UV) Empirical Templates for the Seyfert 1 Galaxy I Zw 1

NASA Astrophysics Data System (ADS)

Bruhweiler, F.; Verner, E.

2008-03-01

We use the narrow-lined broad-line region (BLR) of the Seyfert 1 galaxy, I Zw 1, as a laboratory for modeling the ultraviolet (UV) Fe II 2100-3050 Å emission complex. We calculate a grid of Fe II emission spectra representative of BLR clouds and compare them with the observed I Zw 1 spectrum. Our predicted spectrum for log [nH/(cm -3) ] = 11.0, log [ΦH/(cm -2 s-1) ] = 20.5, and ξ/(1 km s-1) = 20, using Cloudy and an 830 level model atom for Fe II with energies up to 14.06 eV, gives a better fit to the UV Fe II emission than models with fewer levels. Our analysis indicates (1) the observed UV Fe II emission must be corrected for an underlying Fe II pseudocontinuum; (2) Fe II emission peaks can be misidentified as that of other ions in active galactic nuclei (AGNs) with narrow-lined BLRs possibly affecting deduced physical parameters; (3) the shape of 4200-4700 Å Fe II emission in I Zw 1 and other AGNs is a relative indicator of narrow-line region (NLR) and BLR Fe II emission; (4) predicted ratios of Lyα, C III], and Fe II emission relative to Mg II λ2800 agree with extinction corrected observed I Zw 1 fluxes, except for C IV λ1549 (5) the sensitivity of Fe II emission strength to microturbulence ξ casts doubt on existing relative Fe/Mg abundances derived from Fe II (UV)/Mg II flux ratios. Our calculated Fe II emission spectra, suitable for BLRs in AGNs, are available at http://iacs.cua.edu/people/verner/FeII. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 05-26555.

NIR dual luminescence from an extended porphyrin. Spectroscopy, photophysics and theory.

PubMed

Gourlaouen, Christophe; Daniel, Chantal; Durola, Fabien; Frey, Julien; Heitz, Valérie; Sauvage, Jean-Pierre; Ventura, Barbara; Flamigni, Lucia

2014-05-22

Spectroscopic and photophysical properties of an extended Zn porphyrin with fused bis(tetraazaanthracene) arms including a 2,9-diphenyl-1,10-phenanthroline incorporated in a polyether macrocycle are investigated in solvents of different polarity pointing to the presence of two emitting singlet excited states. The absorption and emission features are identified and ascribed, on the basis of solvent polarity dependence, to a π-π* and to a charge transfer (CT) state, respectively. Whereas the intraligand π-π* transition is assigned to the intense absorption observed at 442-455 nm, the CT states contribute to the bands at 521-525 nm and 472-481 nm. The theoretical analysis of the absorption spectrum confirms the presence of two strong bands centered at 536 and 437 nm corresponding to CT and π-π* states, respectively. Weak CT transitions are calculated at 657 and 486 nm. Two emission maxima are observed in toluene at 724 nm from a (1)π-π* state and at 800 nm from a (1)CT state, respectively. (1)CT bands shift bathochromically by increasing the solvent polarity whereas the energy of the (1)π-π band is less affected. Likewise, the emission yield and lifetime associated with the low energy (1)CT band are strongly affected by solvent polarity. This is rationalized by a (1)π-π* → (1)CT internal conversion driven by solvent polarity, this process being competitive with the (1)π-π* to ground state deactivation channel. Time resolved absorption spectra indicate the presence of two triplet states, a short-lived one (nanoseconds range) and a longer lived one (hundreds of microsecond range) ascribed to a (3)π-π* and a (3)CT, respectively. For them, a conversion mechanism similar to that of the singlet excited states is suggested.

Spectroscopic investigations of Nd3+ doped Lithium Lead Alumino Borate glasses for 1.06 μm laser applications

NASA Astrophysics Data System (ADS)

Deopa, Nisha; Rao, A. S.; Gupta, Mohini; Vijaya Prakash, G.

2018-01-01

Neodymium doped lithium lead alumino borate glasses were synthesized with the molar composition 10Li2Osbnd 10PbOsbnd (10-x) Al2O3sbnd 70B2O3sbnd x Nd2O3 (where, x = 0.1, 0.5, 1.0, 1.5, 2.0 and 2.5 mol %) via conventional melt quenching technique to understand their lasing potentialities using the absorption, emission and photoluminescence decay spectral measurements. The oscillator strengths measured from the absorption spectra were used to estimate the Judd-Ofelt intensity parameters using least square fitting procedure. The emission spectra recorded for the as-prepared glasses under investigation exhibit two emission transitions 4F3/2 → 4I11/2 (1063 nm) and 4F3/2 → 4I9/2 (1350 nm) for which radiative parameters have been evaluated. The emission intensity increases with increase in Nd3+ ion concentration up to 1 mol % and beyond concentration quenching took place. The decay profile shows single exponential nature for lower Nd3+ ion concentration and non-exponential for higher concentration. To elucidate the nature of energy transfer process, the non-exponential decay curves were well fitted to Inokuti-Hirayama model. The relatively higher values of emission cross-sections, branching ratios and quantum efficiency values obtained for 1.0 mol% of Nd3+ ions in LiPbAlB glass suggests it's aptness in generating lasing action at 1063 nm in NIR region.

78 FR 77120 - Proposed Information Collection Request; Comment Request; Motor Vehicle Emissions: Revisions to...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-12-20

... Alternative Fuels Conversions AGENCY: Environmental Protection Agency (EPA). ACTION: Notice. SUMMARY: The... Emissions: Revisions to Certification of Alternative Fuels Conversions'' (EPA ICR No. 0783.64, OMB Control... Vehicle and Engine Conversions Final Rule which was issued on April 8, 2011 (76 FR 19830). This includes a...

Observation of >400-eV precursor plasmas from low-wire-number copper arrays at the 1-MA zebra facility.

PubMed

Coverdale, C A; Safronova, A S; Kantsyrev, V L; Ouart, N D; Esaulov, A A; Deeney, C; Williamson, K M; Osborne, G C; Shrestha, I; Ampleford, D J; Jones, B

2009-04-17

Experiments with cylindrical copper wire arrays at the 1-MA Zebra facility show that high temperatures exist in the precursor plasmas formed when ablated wire array material accretes on the axis prior to the stagnation of a z pinch. In these experiments, the precursor radiated approximately 20% of the >1000 eV x-ray output, and time-resolved spectra show substantial emission from Cu L-shell lines. Modeling of the spectra shows an increase in temperature as the precursor forms, up to approximately 450 eV, after which the temperature decreases to approximately 220-320 eV until the main implosion.

Ce3+ luminescent centers of different symmetries in KMgF3 single crystals

NASA Astrophysics Data System (ADS)

Francini, R.; Grassano, U. M.; Landi, L.; Scacco, A.; D'elena, M.; Nikl, M.; Cechova, N.; Zema, N.

1997-12-01

Absorption, emission, and excitation spectra of KMgF3 doped with Ce3+ have been measured in the near ultraviolet up to 180 nm. In this fluoroperovskite lattice, absorption of the Ce3+ impurity is found at energies higher than 4.4 eV. Broad-band emissions are measured at 350 nm and 275 nm which are identified as the 5d-->4f radiative recombination at two different Ce3+ centers. The same substitutional site is proposed for both centers, with the unperturbed site rapidly saturating with an increasing concentration of Ce3+ in favor of a site perturbed by two K+-ion vacancies.

Fluorescent excitation of Fe 2, Mn 2, Ti 2, N 1 lines by V 4, N 5, O 6: Emission lines in the spectra of symbiotic stars and Seyfert galaxies

NASA Technical Reports Server (NTRS)

Gilra, D. P.

1984-01-01

Analysis of the published IUE and ground based high resolution spectra of symbiotic stars, particularly RR Tel, shows that the dominant excitation mechanism of Fe II, Mn II, Ti II, and N I lines is the selective fluorescent excitation of some levels by the strong C IV, N V, and O VI emission lines. The same mechanism should work for the excitation of Fe II lines in the spectra of Seyfert galaxies and Q60's whose emission spectra are quite similar to those of symbiotic stars. The similarities and differences between the fluroescent excitation mechanism reported herein and the Bowen's mechanism is analyzed.

X-Ray, UV and Optical Observations of Classical Cepheids: New Insights into Cepheid Evolution, and the Heating and Dynamics of Their Atmospheres

NASA Astrophysics Data System (ADS)

Engle, Scott G.; Guinan, Edward F.

2012-06-01

To broaden the understanding of classical Cepheid structure, evolution and atmospheres, we have extended our continuing secret lives of Cepheids program by obtaining XMM/Chandra X-ray observations, and Hubble space telescope (HST) / cosmic origins spectrograph (COS) FUV-UV spectra of the bright, nearby Cepheids Polaris, δ Cep and β Dor. Previous studies made with the international ultraviolet explorer (IUE) showed a limited number of UV emission lines in Cepheids. The well-known problem presented by scattered light contamination in IUE spectra for bright stars, along with the excellent sensitivity & resolution combination offered by HST/COS, motivated this study, and the spectra obtained were much more rich and complex than we had ever anticipated. Numerous emission lines, indicating 10^4 K up to ~3 x 10^5 K plasmas, have been observed, showing Cepheids to have complex, dynamic outer atmospheres that also vary with the photospheric pulsation period. The FUV line emissions peak in the phase range φ ∼ 0.8-1.0 and vary by factors as large as 10x. A more complete picture of Cepheid outer atmospheres is accomplished when the HST/COS results are combined with X-ray observations that we have obtained of the same stars with XMM-Newton & Chandra. The Cepheids detected to date have X-ray luminosities of log Lx ~ 28.5-29.1 ergs/sec, and plasma temperatures in the 2-8 x 10^6 K range. Given the phase-timing of the enhanced emissions, the most plausible explanation is the formation of a pulsation-induced shocks that excite (and heat) the atmospheric plasmas surrounding the photosphere. A pulsation-driven α^2 equivalent dynamo mechanism is also a viable and interesting alternative. However, the tight phase-space of enhanced emission (peaking near 0.8-1.0 φ) favor the shock heating mechanism hypothesis.

Suzaku Observations of Luminous Quasars: Revealing the Nature of High-Energy Blazar Emission in Low-level activity States

DOE PAGES

Abdo, A. A.; Ackermann, M.; Ajello, M.; ...

2010-05-21

We present the results from the Suzaku X-ray observations of five flat-spectrum radio quasars (FSRQs), namely PKS 0208–512, Q 0827+243, PKS 1127–145, PKS 1510–089, and 3C 454.3. Here, all these sources were additionally monitored simultaneously or quasi-simultaneously by the Fermi satellite in gamma rays and the Swift UVOT in the UV and optical bands, respectively. Here, we constructed their broadband spectra covering the frequency range from 10 14 Hz up to 10 25 Hz, and those reveal the nature of high-energy emission of luminous blazars in their low-activity states. The analyzed X-ray spectra are well fitted by a power-law modelmore » with photoelectric absorption. In the case of PKS 0208–512, PKS 1127–145, and 3C 454.3, the X-ray continuum showed indication of hardening at low energies. Moreover, when compared with the previous X-ray observations, we see a significantly increasing contribution of low-energy photons to the total X-ray fluxes when the sources are getting fainter. The same behavior can be noted in the Suzaku data alone. A likely explanation involves a variable, flat-spectrum component produced via inverse-Compton emission, plus an additional, possibly steady soft X-ray component prominent when the source gets fainter. This soft X-ray excess is represented either by a steep power-law (photon indices Γ ~ 3-5) or a blackbody-type emission with temperatures kT ~ 0.1-0.2 keV. We model the broadband spectra of the five observed FSRQs using synchrotron self-Compton and/or external-Compton radiation models. Lastly, our modeling suggests that the difference between the low- and high-activity states in luminous blazars is due to the different total kinetic power of the jet, most likely related to varying bulk Lorentz factor of the outflow within the blazar emission zone.« less

Single-molecule spectroscopy unmasks the lowest exciton state of the B850 assembly in LH2 from Rps. acidophila.

PubMed

Kunz, Ralf; Timpmann, Kõu; Southall, June; Cogdell, Richard J; Freiberg, Arvi; Köhler, Jürgen

2014-05-06

We have recorded fluorescence-excitation and emission spectra from single LH2 complexes from Rhodopseudomonas (Rps.) acidophila. Both types of spectra show strong temporal spectral fluctuations that can be visualized as spectral diffusion plots. Comparison of the excitation and emission spectra reveals that for most of the complexes the lowest exciton transition is not observable in the excitation spectra due to the cutoff of the detection filter characteristics. However, from the spectral diffusion plots we have the full spectral and temporal information at hand and can select those complexes for which the excitation spectra are complete. Correlating the red most spectral feature of the excitation spectrum with the blue most spectral feature of the emission spectrum allows an unambiguous assignment of the lowest exciton state. Hence, application of fluorescence-excitation and emission spectroscopy on the same individual LH2 complex allows us to decipher spectral subtleties that are usually hidden in traditional ensemble spectroscopy. Copyright © 2014 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Identifying Student and Teacher Difficulties in Interpreting Atomic Spectra Using a Quantum Model of Emission and Absorption of Radiation

ERIC Educational Resources Information Center

Savall-Alemany, Francisco; Domènech-Blanco, Josep Lluís; Guisasola, Jenaro; Martínez-Torregrosa, Joaquín

2016-01-01

Our study sets out to identify the difficulties that high school students, teachers, and university students encounter when trying to explain atomic spectra. To do so, we identify the key concepts that any quantum model for the emission and absorption of electromagnetic radiation must include to account for the gas spectra and we then design two…

Emission analysis of RE3+ (RE = Sm, Dy):B2O3-TeO2-Li2O-AlF3 glasses.

PubMed

Raju, C Nageswara; Sailaja, S; Kumari, S Pavan; Dhoble, S J; Kumar, V Ramesh; Ramanaiah, M V; Reddy, B Sudhakar

2013-01-01

This article reports on the optical properties of 0.5% mol of Sm(3+), Dy(3+) ion-doped B2O3-TeO2-Li2O-AlF3 (LiAlFBT) glasses. The glass samples were characterized by optical absorption and emission spectra. Judd-Ofelt theory was applied to analyze the optical absorption spectra and calculate the intensity parameters and radiative properties of the emission transitions. The emission spectra of Sm(3+) and Dy(3+):LiAlFBT glasses showed a bright reddish-orange emission at 598 nm ((4)G5/2 → (6)H7/2) and an intense yellow emission at 574 nm ((4)F9/2 → (6)H13/2), respectively. Full width at half maximum (FWHM), stimulated emission cross section, gain bandwidth and optical gain values were also calculated to extend the applications of the Sm(3+) and Dy(3+):LiAlFBT glasses. Copyright © 2012 John Wiley & Sons, Ltd.

Ejecta patterns of Meteor Crater, Arizona derived from the linear un-mixing of TIMS data and laboratory thermal emission spectra

NASA Technical Reports Server (NTRS)

Ramsey, Michael S.; Christensen, Philip R.

1992-01-01

Accurate interpretation of thermal infrared data depends upon the understanding and removal of complicating effects. These effects may include physical mixing of various mineralogies and particle sizes, atmospheric absorption and emission, surficial coatings, geometry effects, and differential surface temperatures. The focus is the examination of the linear spectral mixing of individual mineral or endmember spectra. Linear addition of spectra, for particles larger than the wavelength, allows for a straight-forward method of deconvolving the observed spectra, predicting a volume percent of each endmember. The 'forward analysis' of linear mixing (comparing the spectra of physical mixtures to numerical mixtures) has received much attention. The reverse approach of un-mixing thermal emission spectra was examined with remotely sensed data, but no laboratory verification exists. Understanding of the effects of spectral mixing on high resolution laboratory spectra allows for the extrapolation to lower resolution, and often more complicated, remotely gathered data. Thermal Infrared Multispectral Scanner (TIMS) data for Meteor Crater, Arizona were acquired in Sep. 1987. The spectral un-mixing of these data gives a unique test of the laboratory results. Meteor Crater (1.2 km in diameter and 180 m deep) is located in north-central Arizona, west of Canyon Diablo. The arid environment, paucity of vegetation, and low relief make the region ideal for remote data acquisition. Within the horizontal sedimentary sequence that forms the upper Colorado Plateau, the oldest unit sampled by the impact crater was the Permian Coconino Sandstone. A thin bed of the Toroweap Formation, also of Permian age, conformably overlays the Coconino. Above the Toroweap lies the Permian Kiabab Limestone which, in turn, is covered by a thin veneer of the Moenkopi Formation. The Moenkopi is Triassic in age and has two distinct sub-units in the vicinity of the crater. The lower Wupatki member is a fine-grained sandstone, while the upper Moqui member is a fissile siltstone. Ejecta from these units are preserved as inverted stratigraphy up to 2 crater radii from the rim. The mineralogical contrast between the units, relative lack of post-emplacement erosion and ejecta mixing provide a unique site to apply the un-mixing model. Selection of the aforementioned units as endmembers reveals distinct patterns in the ejecta of the crater.

Global analysis of the high temperature infrared emission spectrum of 12CH4 in the dyad (ν2/ν4) region

NASA Astrophysics Data System (ADS)

Amyay, Badr; Louviot, Maud; Pirali, Olivier; Georges, Robert; Vander Auwera, Jean; Boudon, Vincent

2016-01-01

We report new assignments of vibration-rotation line positions of methane (12CH4) in the so-called dyad (ν2/ν4) region (1100-1500 cm-1), and the resulting update of the vibration-rotation effective model of methane, previously reported by Nikitin et al. [Phys. Chem. Chem. Phys. 15, 10071 (2013)], up to and including the tetradecad. High resolution (0.01 cm-1) emission spectra of methane have been recorded up to about 1400 K using the high-enthalpy source developed at Institut de Physique de Rennes associated with the Fourier transform spectrometer of the SOLEIL synchrotron facility (AILES beamline). Analysis of these spectra allowed extending rotational assignments in the well-known cold band (dyad-ground state (GS)) and related hot bands in the pentad-dyad system (3000 cm-1) up to Jmax = 30 and 29, respectively. In addition, 8512 new transitions belonging to the octad-pentad (up to J = 28) and tetradecad-octad (up to J = 21) hot band systems were successfully identified. As a result, the MeCaSDa database of methane was significantly improved. The line positions assigned in this work, together with the information available in the literature, were fitted using 1096 effective parameters with a dimensionless standard deviation σ = 2.09. The root mean square deviations dRMS are 3.60 × 10-3 cm-1 for dyad-GS cold band, 4.47 ×10-3 cm-1 for the pentad-dyad, 5.43 × 10-3 cm-1 for the octad-pentad, and 4.70 × 10-3 cm-1 for the tetradecad-octad hot bands. The resulting new line list will contribute to improve opacity and radiative transfer models for hot atmospheres, such as those of hot-Jupiter type exoplanets.

Laboratory simulation of infrared astrophysical features. [Terrestrial silicate, meteoritic and lunar soil 10-micron spectral comparisons with comets Bennet and Kohoutek

NASA Technical Reports Server (NTRS)

Rose, L. A.

1979-01-01

Laboratory infrared emission and absorption spectra have been taken of terrestrial silicates, meteorites, and lunar soils in the form of micrometer and submicrometer grains. The emission spectra were taken in a way that imitates telescopic observations. The purpose was to see which materials best simulate the 10-micron astrophysical feature. The emission spectra of dunite, fayalite, and Allende give a good fit to the 10-micron broadband emission feature of comets Bennett and Kohoutek. A study of the effect of grain size on the presence of the 10-micron emission feature of dunite shows that for particles larger than 37 microns no feature is seen. The emission spectrum of the Murray meteorite, a Type 2 carbonaceous chrondrite, is quite similar to the intermediate-resolution spectrum of comet Kohoutek in the 10-micron region. Hydrous silicates or amorphous magnesium silicates in combination with high-temperature condensates, such as olivine or anorthite, would yield spectra that match the intermediate-resolution spectrum of comet Kohoutek in the 10-micron region. Glassy olivine and glassy anorthite in approximately equal proportions would also give a spectrum that is a good fit to the cometary 10-micron feature.

YAG:Er3+, CaF2:Er3+, and Er2O3 Emission Spectra Under Laser and Laser Thermal Excitation

NASA Astrophysics Data System (ADS)

Marchenko, V. M.

2018-05-01

Experimental luminescence and selective-emission (SE) spectra of YAG:Er3+ (10 at.%) and CaF2:Er3+ (1 at.%) single crystals and Er2O3 polycrystal under laser and laser thermal excitation of the Er3+-ion multiplets are compared. Luminescence spectra under resonant excitation are determined by multiplet population relaxation with the corresponding radiative and nonradiative probabilities. The form of the SE spectra is determined by the thermal population of the multiplets and the probabilities of only radiative transitions. The SE band at 800 nm (4I9/2 → 4I15/2) is an indicator of high-temperature thermal emission of Er3+ ions. The absence of this band in luminescence spectra is explained by the short lifetime of the τ(4I9/2) level of 53 ns at T = 300 K.

Measurements of constituents of interest in the photochemistry of the ozone layer using infrared techniques

NASA Technical Reports Server (NTRS)

Murcray, D. G.; Williams, J. W.; Barker, D. B.; Goldman, A.; Bradford, C.; Cook, G.

1978-01-01

Infrared solar spectra and infrared atmospheric emission spectra were obtained from the ground, from aircraft and from balloons. The initial detection of most stratospheric molecules was achieved by the solar spectral technique because better resolution helps remove interference from other molecules. Because the sun is an intense source of radiation, the resolution which can be obtained with good signal-to-noise, is greater than with atmospheric emission spectroscopy. Data are generally taken using a method that enhances the number of molecules in the optical path i.e. at large solar zenith angles for solar spectra and at low elevation angles for atmospheric emission spectra. The search for molecules which are predicted to be present but which, the detection of a molecule known to be present from other measurement techniques but observed for the first time in infrared solar spectra, and some further data on the variability of HNO3 are discussed.

Simulated infrared emission spectra of highly excited polyatomic molecules: a detailed model of the PAH-UIR hypothesis

NASA Technical Reports Server (NTRS)

Cook, D. J.; Saykally, R. J.

1998-01-01

A detailed description of the polycyclic aromatic hydrocarbon (PAH)/unidentified infrared band (UIR) mechanism is presented in which experimental spectral bandshape functions are used to simulate IR emission spectra for individual molecules. These spectra are additively superimposed to produce a conglomerate spectrum representative of a family of PAH molecules. Ab initio vibrational frequencies and intensities for nine PAHs (neutral and cationic) as large as ovalene are used in conjunction with measured bandshape and temperature-dependent redshift data to simulate the UIR bands. The calculated spectra of cations provide a closer match to the UIRs than do those of the neutrals. However, the PAH cations used in the simulations fail to reproduce the details of the UIR emission spectra. The discrepancies are potentially alleviated if both larger PAHs and a greater number of PAHs were included in the simulation.

State interference in resonance Auger and x-ray emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cesar, A.; Agren, H.

1992-03-01

Starting from a scattering-theory formulation, cross sections for Auger and x-ray decay from energetically shifted inner-shell states are derived. Two situations are studied: (i) when there are several close-lying intermediate core-hole states with no vibrational excitations, in which case a {ital state} {ital interference} effect is identified; and (ii) when there are several close-lying intermediate states with vibrational excitations, in which case a {ital vibronic} {ital interference} effect is identified. In the latter case, the present formalism is a many-state generalization of the {ital vibrational} {ital interference} {ital effects} derived from the same type of scattering formalism in our previousmore » paper (A. Cesar, H. Agren, and V. Carravetta, Phys. Rev. A 40, 187 (1989)). Applications are carried out for spectra of some few-state model systems. It is found that a conventional analysis in terms of discrete noninteracting (noninterfering) states, such as the one-center decomposition model, is only valid when the ratio ({ital R}) between energy shift and lifetime is sufficiently large. For states with small {ital R}, a more complete theoretical account must be undertaken, including, e.g., the calculation of phases of the respective transition moments. The presented formalism applies to resonance Auger or x-ray emission spectra, to Auger and x-ray emission from core-electron shake-up states, and also, under certain circumstances, to emission from chemically shifted core-hole states.« less

Li-Like CX

NASA Astrophysics Data System (ADS)

Dorsey, Zachary

2018-06-01

A fantastic discovery in 1996 caused an epiphany when it was realized that the charge exchange (CX) process was an important source of X-ray emission from comets. Over the last two decades, CX induced X-ray emission has been detected in a wide variety of solar and extra-solar sources. Recently, our group developed the Kronos database which contains CX cross sections and emission spectra for all H-like and most He-Like ions up to iron, based primarily on multichannel Landau-Zener calculations. Here we present preliminary results for extending Kronos to Li-like ions. Due to the incompleteness of highly-charged Li-like atomic structure data, we estimate missing energy levels and transition probabilities with a quantum defect approach and the package Autostructure.This work was support by NASA grants NNX13AF31G.

Mid-infrared, long wave infrared (4-12 μm) molecular emission signatures from pharmaceuticals using laser-induced breakdown spectroscopy (LIBS).

PubMed

Yang, Clayton S-C; Brown, Ei E; Kumi-Barimah, Eric; Hommerich, Uwe H; Jin, Feng; Trivedi, Sudhir B; Samuels, Alan C; Snyder, A Peter

2014-01-01

In an effort to augment the atomic emission spectra of conventional laser-induced breakdown spectroscopy (LIBS) and to provide an increase in selectivity, mid-wave to long-wave infrared (IR), LIBS studies were performed on several organic pharmaceuticals. Laser-induced breakdown spectroscopy signature molecular emissions of target organic compounds are observed for the first time in the IR fingerprint spectral region between 4-12 μm. The IR emission spectra of select organic pharmaceuticals closely correlate with their respective standard Fourier transform infrared spectra. Intact and/or fragment sample molecular species evidently survive the LIBS event. The combination of atomic emission signatures derived from conventional ultraviolet-visible-near-infrared LIBS with fingerprints of intact molecular entities determined from IR LIBS promises to be a powerful tool for chemical detection.

Graphene surface plasmons mediated thermal radiation

NASA Astrophysics Data System (ADS)

Li, Jiayu; Liu, Baoan; Shen, Sheng

2018-02-01

A graphene nanostructure can simultaneously serve as a plasmonic optical resonator and a thermal emitter when thermally heated up. The unique electronic and optical properties of graphene have rendered tremendous potential in the active manipulation of light and the microscopic energy transport in nanostructures. Here we show that the thermally pumped surface plasmonic modes along graphene nanoribbons could dramatically modulate their thermal emission spectra in both near- and far-fields. Based on the fluctuating surface current method implemented by the resistive boundary method, we directly calculate the thermal emission spectrum from single graphene ribbons and vertically paired graphene ribbons. Furthermore, we demonstrate that both the near- and far-field thermal emission from graphene nanostructures can be optimized by tuning the chemical potential of doped graphene. The general guideline to maximize the thermal emission is illustrated by the our recently developed theory on resonant thermal emitters modulated by quasi-normal modes.

SEMICONDUCTOR MATERIALS: White light photoluminescence from ZnS films on porous Si substrates

NASA Astrophysics Data System (ADS)

Caifeng, Wang; Qingshan, Li; Bo, Hu; Weibing, Li

2010-03-01

ZnS films were deposited on porous Si (PS) substrates using a pulsed laser deposition (PLD) technique. White light emission is observed in photoluminescence (PL) spectra, and the white light is the combination of blue and green emission from ZnS and red emission from PS. The white PL spectra are broad, intense in a visible band ranging from 450 to 700 nm. The effects of the excitation wavelength, growth temperature of ZnS films, PS porosity and annealing temperature on the PL spectra of ZnS/PS were also investigated.

Optical studies of CaS:Eu,Sm infrared stimulable phosphors

NASA Astrophysics Data System (ADS)

Tamura, Yasuaki; Shibukawa, Atsushi

1993-07-01

The photoluminescence (PL) and infrared stimulated luminescence (ISL) spectra of CaS:Eu,Sm infrared stimulable phosphors (ISPs) are studied. In addition, the concentration dependence of ISL intensity is examined. Sm(3+) and Eu(2+) related structures are found in both the PL excitation and emission spectra. Two types of Sm(3+) are found, one of which exhibits strong emission at around 650 nm and the other weak emission compared to the other emissions at around 565 nm and 605 nm. These are assigned to an asymmetric and a symmetric site, respectively. ISL excitation spectra coincide with the Eu(2+) 4f(sup 7) to 4f(sup 6)5d(sup 1) and 4f(sup 6)6s(sup 1) transitions and range from 220 to 650 nm. ISL emission spectra coincide with the Eu(2+) 4f(sup 6)5d(sup 1) to 4f(sup 7) transition and range from 550 to 750 nm. ISL stimulation spectra range from 0.8 micron to 1.7 micron and are thought to indicate the Sm(2+) ion transition from 4f(sup 6) to 4f(sup 5)5d(sup 1). The maximum ISL intensity is obtained from a sample with Eu and Sm concentrations of 500 and 130 ppm, respectively.

Emission spectra profiling of fluorescent proteins in living plant cells

PubMed Central

2013-01-01

Background Fluorescence imaging at high spectral resolution allows the simultaneous recording of multiple fluorophores without switching optical filters, which is especially useful for time-lapse analysis of living cells. The collected emission spectra can be used to distinguish fluorophores by a computation analysis called linear unmixing. The availability of accurate reference spectra for different fluorophores is crucial for this type of analysis. The reference spectra used by plant cell biologists are in most cases derived from the analysis of fluorescent proteins in solution or produced in animal cells, although these spectra are influenced by both the cellular environment and the components of the optical system. For instance, plant cells contain various autofluorescent compounds, such as cell wall polymers and chlorophyll, that affect the spectral detection of some fluorophores. Therefore, it is important to acquire both reference and experimental spectra under the same biological conditions and through the same imaging systems. Results Entry clones (pENTR) of fluorescent proteins (FPs) were constructed in order to create C- or N-terminal protein fusions with the MultiSite Gateway recombination technology. The emission spectra for eight FPs, fused C-terminally to the A- or B-type cyclin dependent kinases (CDKA;1 and CDKB1;1) and transiently expressed in epidermal cells of tobacco (Nicotiana benthamiana), were determined by using the Olympus FluoView™ FV1000 Confocal Laser Scanning Microscope. These experimental spectra were then used in unmixing experiments in order to separate the emission of fluorophores with overlapping spectral properties in living plant cells. Conclusions Spectral imaging and linear unmixing have a great potential for efficient multicolor detection in living plant cells. The emission spectra for eight of the most commonly used FPs were obtained in epidermal cells of tobacco leaves and used in unmixing experiments. The generated set of FP Gateway entry vectors represents a valuable resource for plant cell biologists. PMID:23552272

Tuning extreme ultraviolet emission for optimum coupling with multilayer mirrors for future lithography through control of ionic charge states

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohashi, Hayato, E-mail: ohashi@cc.utsunomiya-u.ac.jp; Higashiguchi, Takeshi, E-mail: higashi@cc.utsunomiya-u.ac.jp; Suzuki, Yuhei

2014-01-21

We report on the identification of the optimum plasma conditions for a laser-produced plasma source for efficient coupling with multilayer mirrors at 6.x nm for beyond extreme ultraviolet lithography. A small shift to lower energies of the peak emission for Nd:YAG laser-produced gadolinium plasmas was observed with increasing laser power density. Charge-defined emission spectra were observed in electron beam ion trap (EBIT) studies and the charge states responsible identified by use of the flexible atomic code (FAC). The EBIT spectra displayed a larger systematic shift of the peak wavelength of intense emission at 6.x nm to longer wavelengths with increasingmore » ionic charge. This combination of spectra enabled the key ion stage to be confirmed as Gd{sup 18+}, over a range of laser power densities, with contributions from Gd{sup 17+} and Gd{sup 19+} responsible for the slight shift to longer wavelengths in the laser-plasma spectra. The FAC calculation also identified the origin of observed out-of-band emission and the charge states responsible.« less

A New Probe of Dust Attenuation in Star-Forming Galaxies

NASA Astrophysics Data System (ADS)

Leitherer, Claus

2017-08-01

We propose to develop, calibrate and test a new technique to measure dust attenuation in star-forming galaxies. The technique utilizes the strong stellar-wind emission lines in Wolf-Rayet stars, which are routinely observed in galaxy spectra locally and up to redshift 3. The He II 1640 and 4686 features are recombination lines whose intrinsic ratio is almost exclusively determined by atomic physics. Therefore it can serve as a stellar dust probe in the same way as the nebular hydrogen-line ratio can be used to measure the reddening of the gas phase. Archival spectra of Wolf-Rayet stars will be analyzed to calibrate the method, and panchromatic FOS and STIS spectra of nearby star-forming galaxies will be used as a first application. The new technique allows us to study stellar and nebular attenuation in galaxies separately and to test its effects at different stellar age and mass regimes.

Fabrication and enhanced photoluminescence properties of Sm3+-doped ZnO-Al2O3-B2O3-SiO2 glass derived willemite glass-ceramic nanocomposites

NASA Astrophysics Data System (ADS)

Tarafder, Anal; Molla, Atiar Rahaman; Mukhopadhyay, Sunanda; Karmakar, Basudeb

2014-07-01

The transparent willemite, Zn2SiO4 (ZS) glass-ceramic nanocomposites were prepared from melt-quench derived ZnO-Al2O3-B2O3-SiO2 (ZABS) precursor glass by an isothermal heat-treatment process. The generation of willemite crystal phase, size and morphology with increase in heat-treatment time was examined by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) techniques. The average calculated crystallite size obtained from XRD is found to be in the range 80-120 nm. The decreased refractive index with increase in heat-treatment time attributed to partial replacement of ZnO4 units of willemite nanocrystals by AlO4 units and simultaneous generation of vacancies in the Zn-site. Fourier transform infrared (FTIR) reflection spectroscopy exhibits the structural evolution of willemite glass-ceramics. The photoluminescence spectra of Sm3+ ions exhibit emission transitions of 4G5/2 → 6HJ (J = 5/2, 7/2, 9/2, 11/2) and its excitation spectra shows an intense absorption band at 402 nm. These spectra reveal that the luminescence performance of the glass-ceramic nanocomposites is enhanced up to 14-fold with crystallization into willemite.

Dual modality instrument for simultaneous optical coherence tomography imaging and fluorescence spectroscopy.

PubMed

Barton, Jennifer Kehlet; Guzman, Francisco; Tumlinson, Alexandre

2004-01-01

We develop a dual-modality device that combines the anatomical imaging capabilities of optical coherence tomography (OCT) with the functional capabilities of laser-induced fluorescence (LIF) spectroscopy. OCT provides cross-sectional images of tissue structure to a depth of up to 2 mm with approximately 10-microm resolution. LIF spectroscopy provides histochemical information in the form of emission spectra from a given tissue location. The OCT subsystem utilizes a superluminescent diode with a center wavelength of 1300 nm, whereas a helium cadmium laser provides the LIF excitation source at wavelengths of 325 and 442 nm. Preliminary data are obtained on eight postmortem aorta samples, each 10 mm in length. OCT images and LIF spectra give complementary information from normal and atherosclerotic portions of aorta wall. OCT images show structures such as intima, media, internal elastic lamina, and fibrotic regions. Emission spectra ratios of 520/490 (325-nm excitation) and 595/635 (442-nm excitation) could be used to identify normal and plaque regions with 97 and 91% correct classification rates, respectively. With miniaturization of the delivery probe and improvements in system speed, this dual-modality device could provide a valuable tool for identification and characterization of atherosclerotic plaques. (c) 2004 Society of Photo-Optical Instrumentation Engineers.

Spectral characterization of surface emissivities in the thermal infrared

NASA Astrophysics Data System (ADS)

Niclòs, Raquel; Mira, Maria; Valor, Enric; Caselles, Diego; García-Santos, Vicente; Caselles, Vicente; Sánchez, Juan M.

2015-04-01

Thermal infrared (TIR) remote sensing trends to hyperspectral sensors on board satellites in the last decades, e.g., the current EOS-MODIS and EOS-ASTER and future missions like HyspIRI, ECOSTRESS, THIRSTY and MISTIGRI. This study aims to characterize spectrally the emissive properties of several surfaces, mostly soils. A spectrometer ranging from 2 to 16 μm, D&P Model 102, has been used to measure samples with singular spectral features, e.g. a sandy soil rich in gypsum sampled in White Sands (New Mexico, USA), salt samples, powdered quartz, and powdered calcite. These samples were chosen for their role in the assessment of thermal emissivity of soils, e.g., the calcite and quartz contents are key variables for modeling TIR emissivities of bare soils, along with soil moisture and organic matter. Additionally, the existence of large areas in the world with abundance of these materials, some of them used for calibration/validation activities of satellite sensors and products, makes the chosen samples interesting. White Sands is the world's largest gypsum dune field encompassing 400 km^2; the salt samples characterize the Salar of Uyuni (Bolivia), the largest salt flat in the world (up to 10,000 km^2), as well as the Jordanian and Israeli salt evaporation ponds at the south end of the Dead Sea, or the evaporation lagoons in Aigües-Mortes (France); and quartz is omnipresent in most of the arid regions of the world such as the Algodones Dunes or Kelso Dunes (California, USA), with areas around 700 km2 and 120 km^2, respectively. Measurements of target leaving radiance, hemispherical radiance reflected by a diffuse reflectance panel, and the radiance from a black body at different temperatures were taken to obtain thermal spectra with the D&P spectrometer. The good consistency observed between our measurements and laboratory spectra of similar samples (ASTER and MODIS spectral libraries) indicated the validity of the measurement protocol. Further, our study showed the high precision achieved by in situ spectra of real covers (instead of laboratory measurements over microscopic portions of samples). Several spectral features were observed: 1) the high spectral contrast of gypsum in the TIR, which emissivity decreases from 0.98 up to 0.70 around 8.6 μm, 2) the broad absorption band of salt in the infrared (low emissivity at wavelengths lower than 16.7 μm), 3) the weak absorption feature of the quartz Reststrahlen bands (low emissivity between 7.7 and 9.7 μm, and near 12.6 μm), and 4) the absorption features near 11.4 μm and 14.0 μm characteristics of calcite.

First XMM-Newton Observations of a Cataclysmic Variable II: Spectral Studies of OY Car

NASA Technical Reports Server (NTRS)

Ramsay, Gavin; Cordova, France; Cottam, Jean; Mason, Keith; Much, Rudu; Osborne, Julian; Pandel, Dirk; Poole, Tracey; Wheatley, Peter

2000-01-01

We present XMM-Newton X-ray spectra of the disc accreting cataclysmic variable OY Car, which were obtained during the performance verification phase of the mission. These data were taken 4 days after a short outburst. In the EPIC spectra we find strong Iron K(beta) emission with weaker Iron K(alpha) emission together with Silicon and Sulphur lines. The spectra are best fitted with a three temperature plasma model with a partial covering absorber. Multiple temperature emission is confirmed by the emission lines seen in the RGS spectrum and the H/He like intensity ratio for Iron and Sulphur which imply temperatures of approx. 7keV and approx. 3keV respectively.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prieto, J. L.; Knapp, G. R.; Rest, A.

We present follow-up optical imaging and spectroscopy of one of the light echoes of η Carinae's nineteenth century Great Eruption discovered by Rest et al. By obtaining images and spectra at the same light echo position between 2011 and 2014, we follow the evolution of the Great Eruption on a 3 yr timescale. We find remarkable changes in the photometric and spectroscopic evolution of the echo light. The i-band light curve shows a decline of ∼0.9 mag in ∼1 yr after the peak observed in early 2011 and a flattening at later times. The spectra show a pure-absorption early G-type stellar spectrummore » at peak, but a few months after peak the lines of the Ca II triplet develop strong P-Cygni profiles and we see the appearance of [Ca II] 7291, 7324 doublet in emission. These emission features and their evolution in time resemble those observed in the spectra of some Type IIn supernovae and supernova impostors. Most surprisingly, starting ∼300 days after peak brightness, the spectra show strong molecular transitions of CN at ≳ 6800 Å. The appearance of these CN features can be explained if the ejecta are strongly nitrogen enhanced, as is observed in modern spectroscopic studies of the bipolar Homunculus nebula. Given the spectroscopic evolution of the light echo, velocities of the main features, and detection of strong CN, we are likely seeing ejecta that contributes directly to the Homunculus nebula.« less

SpectraPlot.com: Integrated spectroscopic modeling of atomic and molecular gases

NASA Astrophysics Data System (ADS)

Goldenstein, Christopher S.; Miller, Victor A.; Mitchell Spearrin, R.; Strand, Christopher L.

2017-10-01

SpectraPlot is a web-based application for simulating spectra of atomic and molecular gases. At the time this manuscript was written, SpectraPlot consisted of four primary tools for calculating: (1) atomic and molecular absorption spectra, (2) atomic and molecular emission spectra, (3) transition linestrengths, and (4) blackbody emission spectra. These tools currently employ the NIST ASD, HITRAN2012, and HITEMP2010 databases to perform line-by-line simulations of spectra. SpectraPlot employs a modular, integrated architecture, enabling multiple simulations across multiple databases and/or thermodynamic conditions to be visualized in an interactive plot window. The primary objective of this paper is to describe the architecture and spectroscopic models employed by SpectraPlot in order to provide its users with the knowledge required to understand the capabilities and limitations of simulations performed using SpectraPlot. Further, this manuscript discusses the accuracy of several underlying approximations used to decrease computational time, in particular, the use of far-wing cutoff criteria.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harilal, Sivanandan S.; LaHaye, Nicole L.; Phillips, Mark C.

We use a two-dimensional laser-induced fluorescence spectroscopy technique to measure the coupled absorption and emission properties of atomic species in plasmas produced via laser ablation of solid aluminum targets at atmospheric pressure. Emission spectra from the Al I 394.4 nm and Al I 396.15 nm transitions are measured while a frequency-doubled, continuous-wave, Ti:Sapphire laser is tuned across the Al I 396.15 nm transition. The resulting two-dimensional spectra show the energy coupling between the two transitions via increased emission intensity for both transitions during resonant absorption of the continuous-wave laser at one transition. Time-delayed and gated detection of the emission spectrummore » is used to isolate the resonantly-excited fluorescence emission from the thermally-excited emission from the plasma. In addition, the tunable continuous-wave laser measures the absorption spectrum of the Al transition with ultra-high resolution after the plasma has cooled, resulting in narrower spectral linewidths than observed in emission spectra. Our results highlight that fluorescence spectroscopy employing continuous-wave laser re-excitation after pulsed laser ablation combines benefits of both traditional emission and absorption spectroscopic methods.« less

Utilization of methanol for polymer electrolyte fuel cells in mobile systems

NASA Astrophysics Data System (ADS)

Schmidt, V. M.; Brockerhoff, P.; Hohlein, B.; Menzer, R.; Stimming, U.

1994-04-01

The constantly growing volume of road traffic requires the introduction of new vehicle propulsion systems with higher efficiency and drastically reduced emission rates. As part of the fuel cell programme of the Research Centre Julich a vehicle propulsion system with methanol as secondary energy carrier and a polymer electrolyte membrane fuel cell (PEMFC) as the main component for energy conversion is developed. The fuel gas is produced by a heterogeneously catalyzed steam reforming reaction in which methanol is converted to H2, CO and CO2. The required energy is provided by the catalytic conversion of methanol for both heating up the system and reforming methanol. The high CO content of the fuel gas requires further processing of the gas or the development of new electrocatalysts for the anode. Various Pt-Ru alloys show promising behaviour as CO-tolerant anodes. The entire fuel cell system is discussed in terms of energy and emission balances. The development of important components is described and experimental results are discussed.

Calculation of conversion coefficients for clinical photon spectra using the MCNP code.

PubMed

Lima, M A F; Silva, A X; Crispim, V R

2004-01-01

In this work, the MCNP4B code has been employed to calculate conversion coefficients from air kerma to the ambient dose equivalent, H*(10)/Ka, for monoenergetic photon energies from 10 keV to 50 MeV, assuming the kerma approximation. Also estimated are the H*(10)/Ka for photon beams produced by linear accelerators, such as Clinac-4 and Clinac-2500, after transmission through primary barriers of radiotherapy treatment rooms. The results for the conversion coefficients for monoenergetic photon energies, with statistical uncertainty <2%, are compared with those in ICRP publication 74 and good agreements were obtained. The conversion coefficients calculated for real clinic spectra transmitted through walls of concrete of 1, 1.5 and 2 m thick, are in the range of 1.06-1.12 Sv Gy(-1).

Technique for the comparison of light spectra from natural and laboratory generated lightning current arcs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitchard, D., E-mail: mitcharddr@cardiff.ac.uk; Clark, D.; Carr, D.

A technique was developed for the comparison of observed emission spectra from lightning current arcs generated through self-breakdown in air and the use of two types of initiation wire, aluminum bronze and nichrome, against previously published spectra of natural lightning events. A spectrograph system was used in which the wavelength of light emitted by the lightning arc was analyzed to derive elemental interactions. A lightning impulse of up to 100 kA was applied to a two hemispherical tungsten electrode configuration which allowed the effect of the lightning current and lightning arc length to be investigated. A natural lightning reference spectrum wasmore » reconstructed from literature, and generated lightning spectra were obtained from self-breakdown across a 14.0 mm air gap and triggered along initiation wires of length up to 72.4 mm. A comparison of the spectra showed that the generated lightning arc induced via self-breakdown produced a very similar spectrum to that of natural lightning, with the addition of only a few lines from the tungsten electrodes. A comparison of the results from the aluminum bronze initiation wire showed several more lines, whereas results from the nichrome initiation wire differed greatly across large parts of the spectrum. This work highlights the potential use for spectrographic techniques in the study of lightning interactions with surrounding media and materials, and in natural phenomena such as recently observed ball lightning.« less

Near-field scanning magneto-optical spectroscopy of Wigner molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mintairov, A. M., E-mail: amintair@nd.edu; Rouvimov, S.; Ioffe Physical-Technical Institute of the Russian Academy of Sciences, Saint Petersburg, 194021

We study the emission spectra of single self-organized InP/GaInP QDs (size 100-220 nm) using high-spatial-resolution, low-temperature (5 K) near-field scanning optical microscope (NSOM) operating at magnetic field strength B=0-10 T. The dots contain up to twenty electrons and represent natural Wigner molecules (WM). We observed vibronic-type shake-up structure in single electron QDs manifesting formation of two electron (2e) WM in photo-excited state. We found that relative intensities of the shake-up components described well by vibronic Frank-Condon factors giving for dots having parabolic confinement energy ħω{sub 0}=1.2-4 meV molecule bond lengths 40-140 nm. We used measurements of magnetic-field-induced shifts to distinguishmore » emission of 2e-WM and singly charged exciton (trion). We also observed magnetic-field-induced molecular-droplet transition for two electron dot, emitting through doubly charge exciton (tetron) at zero magnetic field.« less

The impact of JP-4/JP-8 conversion on aircraft engine exhaust emissions. Interim technical report Jul 75--Feb 76

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blazowski, W.S.

1976-05-01

The proposed conversion of predominant Air Force fuel usage from JP-4 to JP-8 has created the need to examine the dependence of engine pollutant emission on fuel type. Available data concerning the effect of fuel type on emissions has been reviewed. T56 single combustor testing has been undertaken to determine JP-4/JP-8 emission variations over a wide range of simulated engine cycle operating conditions at idle. In addition, a J85-5 engine was tested using JP-4 and JP-8. Results of the previous and new data collectively led to the following conclusions regarding conversion to JP-8: (a) HC and CO emission changes willmore » depend upon individual combustor design features, (b) no change to NOx emission will occur, and (c) an increase in smoke/particulate emissions will result. It is recommended that these findings be incorporated into air quality analytical models to define the overall impact of the proposed conversion. Further, it is recommended that combustor analytical models be employed to attempt prediction of the results described herein. Should these models be successful, analytical prediction of JP-8 emissions from other Air Force engine models may be substituted for more combustor rig or engine testing. (auth)« less

Characterization of thin films on the nanometer scale by Auger electron spectroscopy and X-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Powell, C. J.; Jablonski, A.; Werner, W. S. M.; Smekal, W.

2005-01-01

We describe two NIST databases that can be used to characterize thin films from Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) measurements. First, the NIST Electron Effective-Attenuation-Length Database provides values of effective attenuation lengths (EALs) for user-specified materials and measurement conditions. The EALs differ from the corresponding inelastic mean free paths on account of elastic-scattering of the signal electrons. The database supplies "practical" EALs that can be used to determine overlayer-film thicknesses. Practical EALs are plotted as a function of film thickness, and an average value is shown for a user-selected thickness. The average practical EAL can be utilized as the "lambda parameter" to obtain film thicknesses from simple equations in which the effects of elastic-scattering are neglected. A single average practical EAL can generally be employed for a useful range of film thicknesses and for electron emission angles of up to about 60°. For larger emission angles, the practical EAL should be found for the particular conditions. Second, we describe a new NIST database for the Simulation of Electron Spectra for Surface Analysis (SESSA) to be released in 2004. This database provides data for many parameters needed in quantitative AES and XPS (e.g., excitation cross-sections, electron-scattering cross-sections, lineshapes, fluorescence yields, and backscattering factors). Relevant data for a user-specified experiment are automatically retrieved by a small expert system. In addition, Auger electron and photoelectron spectra can be simulated for layered samples. The simulated spectra, for layer compositions and thicknesses specified by the user, can be compared with measured spectra. The layer compositions and thicknesses can then be adjusted to find maximum consistency between simulated and measured spectra, and thus, provide more detailed characterizations of multilayer thin-film materials. SESSA can also provide practical EALs, and we compare values provided by the NIST EAL database and SESSA for hafnium dioxide. Differences of up to 10% were found for film thicknesses less than 20 Å due to the use of different physical models in each database.

Galaxy And Mass Assembly (GAMA): spectroscopic analysis

NASA Astrophysics Data System (ADS)

Hopkins, A. M.; Driver, S. P.; Brough, S.; Owers, M. S.; Bauer, A. E.; Gunawardhana, M. L. P.; Cluver, M. E.; Colless, M.; Foster, C.; Lara-López, M. A.; Roseboom, I.; Sharp, R.; Steele, O.; Thomas, D.; Baldry, I. K.; Brown, M. J. I.; Liske, J.; Norberg, P.; Robotham, A. S. G.; Bamford, S.; Bland-Hawthorn, J.; Drinkwater, M. J.; Loveday, J.; Meyer, M.; Peacock, J. A.; Tuffs, R.; Agius, N.; Alpaslan, M.; Andrae, E.; Cameron, E.; Cole, S.; Ching, J. H. Y.; Christodoulou, L.; Conselice, C.; Croom, S.; Cross, N. J. G.; De Propris, R.; Delhaize, J.; Dunne, L.; Eales, S.; Ellis, S.; Frenk, C. S.; Graham, Alister W.; Grootes, M. W.; Häußler, B.; Heymans, C.; Hill, D.; Hoyle, B.; Hudson, M.; Jarvis, M.; Johansson, J.; Jones, D. H.; van Kampen, E.; Kelvin, L.; Kuijken, K.; López-Sánchez, Á.; Maddox, S.; Madore, B.; Maraston, C.; McNaught-Roberts, T.; Nichol, R. C.; Oliver, S.; Parkinson, H.; Penny, S.; Phillipps, S.; Pimbblet, K. A.; Ponman, T.; Popescu, C. C.; Prescott, M.; Proctor, R.; Sadler, E. M.; Sansom, A. E.; Seibert, M.; Staveley-Smith, L.; Sutherland, W.; Taylor, E.; Van Waerbeke, L.; Vázquez-Mata, J. A.; Warren, S.; Wijesinghe, D. B.; Wild, V.; Wilkins, S.

2013-04-01

The Galaxy And Mass Assembly (GAMA) survey is a multiwavelength photometric and spectroscopic survey, using the AAOmega spectrograph on the Anglo-Australian Telescope to obtain spectra for up to ˜300 000 galaxies over 280 deg2, to a limiting magnitude of rpet < 19.8 mag. The target galaxies are distributed over 0 < z ≲ 0.5 with a median redshift of z ≈ 0.2, although the redshift distribution includes a small number of systems, primarily quasars, at higher redshifts, up to and beyond z = 1. The redshift accuracy ranges from σv ≈ 50 km s-1 to σv ≈ 100 km s-1 depending on the signal-to-noise ratio of the spectrum. Here we describe the GAMA spectroscopic reduction and analysis pipeline. We present the steps involved in taking the raw two-dimensional spectroscopic images through to flux-calibrated one-dimensional spectra. The resulting GAMA spectra cover an observed wavelength range of 3750 ≲ λ ≲ 8850 Å at a resolution of R ≈ 1300. The final flux calibration is typically accurate to 10-20 per cent, although the reliability is worse at the extreme wavelength ends, and poorer in the blue than the red. We present details of the measurement of emission and absorption features in the GAMA spectra. These measurements are characterized through a variety of quality control analyses detailing the robustness and reliability of the measurements. We illustrate the quality of the measurements with a brief exploration of elementary emission line properties of the galaxies in the GAMA sample. We demonstrate the luminosity dependence of the Balmer decrement, consistent with previously published results, and explore further how Balmer decrement varies with galaxy mass and redshift. We also investigate the mass and redshift dependencies of the [N II]/Hα versus [O III]/Hβ spectral diagnostic diagram, commonly used to discriminate between star forming and nuclear activity in galaxies.

Managed grassland alters soil N dynamics and N2O emissions in temperate steppe.

PubMed

Xu, Lijun; Xu, Xingliang; Tang, Xuejuan; Xin, Xiaoping; Ye, Liming; Yang, Guixia; Tang, Huajun; Lv, Shijie; Xu, Dawei; Zhang, Zhao

2018-04-01

Reclamation of degraded grasslands as managed grasslands has been increasingly accelerated in recent years in China. Land use change affects soil nitrogen (N) dynamics and nitrous oxide (N 2 O) emissions. However, it remains unclear how large-scale grassland reclamation will impact the grassland ecosystem as a whole. Here, we investigated the effects of the conversion from native to managed grasslands on soil N dynamics and N2O emissions by field experiments in Hulunber in northern China. Soil (0-10cm), nitrate (NO 3 - ), ammonium (NH 4 + ), and microbial N were measured in plots in a temperate steppe (Leymus chinensis grassland) and two managed grasslands (Medicago sativa and Bromus inermis grasslands) in 2011 and 2012. The results showed conversion of L. chinensis grassland to M. sativa or B. inermis grasslands decreased concentrations of NO 3 - -N, but did not change NH 4 + -N. Soil microbial N was slightly decreased by the conversion of L. chinensis grassland to M. sativa, but increased by the conversion to B. inermis. The conversion of L. chinensis grassland to M. sativa (i.e., a legume grass) increased N 2 O emissions by 26.2%, while the conversion to the B. inermis (i.e., a non-legume grass) reduced N 2 O emissions by 33.1%. The conversion from native to managed grasslands caused large created variations in soil NO 3 - -N and NH 4 + -N concentrations. Net N mineralization rates did not change significantly in growing season or vegetation type, but to net nitrification rate. These results provide evidence on how reclamation may impact the grassland ecosystem in terms of N dynamics and N 2 O emissions. Copyright © 2017. Published by Elsevier B.V.

Isomers in the excited state of electron-transferring flavoprotein from Megasphaera elsdenii: spectral resolution from the time-resolved fluorescence spectra.

PubMed

Sato, Kyosuke; Nishina, Yasuzo; Shiga, Kiyoshi; Tanaka, Fumio

2008-02-27

Electron-transferring flavoprotein (Holo-ETF) from Megasphaera elsdenii contains two FAD's, one of which easily dissociates to form Iso-ETF (contains one FAD). Time-resolved fluorescence of FAD in Iso-ETF, and Holo-ETF were measured at 5 degrees C and 25 degrees C. Wavelength-dependent fluorescence decays of the both ETF at 5 degrees C and 25 degrees C were analyzed to resolve them into two independent spectra. It was found that Iso-ETF displayed two spectra with lifetime of 0.605 ns (emission peak, 508 nm) and with lifetime of 1.70 ns (emission peak, 540 nm) at 5 degrees C, and with lifetime of 0.693 ns (emission peak, 508 nm) and with lifetime of 2.75 ns (emission peak, 540 nm) at 25 degrees C. Holo-ETF displayed two spectra with lifetime of 0.739 ns (emission peak, 508 nm) and with lifetime of 2.06 ns (emission peak, 545 nm) at 5 degrees C, and with lifetime of 0.711 ns (emission peak, 527 nm) and with lifetime of 3.08 ns (emission peak, 540 nm) at 25 degrees C. Thus fluorescence lifetimes of every spectrum increased upon elevating temperature. Emission peaks Iso-ETF did not change much upon elevating temperature. Activation enthalpy changes, activation entropy changes and activation Gibbs energy changes of quenching rates all displayed negative. Two emission species in the both ETF may be hydrogen-bonding isomers, because isoalloxazine ring of FAD contains four hydrogen acceptors and one donor.

Modelling and observations of molecules in discs around young stars

NASA Astrophysics Data System (ADS)

Ilee, John David

2013-04-01

This thesis contains a study of molecules within circumstellar discs around young stars. Firstly, the chemistry of a disc around a young, Class 0 protostar is modelled. Such discs are thought to be massive, and thus experience gravitational instabilities, which produce spiral density waves. These affect the chemistry in three ways; by desorbing molecules from dust grains, by providing extra energy for new reactions to take place, and by mixing the internal structure of the disc to provide a rich chemistry near the midplane. Secondly, high resolution near-infrared spectra of 20 massive young stellar objects are presented. The objects display CO first overtone bandhead emission, which is excited in the conditions expected within circumstellar discs. The emission is modelled using a simple analytic model of a Keplerian disc, and good fits are found to all spectra. On average, the discs correspond to being geometrically thin, spread across a wide range of inclinations. The discs are located within the dust sublimation radius, providing strong evidence that the CO emission originates in small gaseous discs, supporting the scenario in which massive stars form via disc accretion. Finally, medium resolution near-infrared spectra of 5 Herbig Ae/Be stars are presented. The spectra cover both CO bandhead and Br gamma emission. Accretion rates are derived from the measuring the Br gamma emission and through modelling the CO emission, however these accretion rates are found to be inconsistent. High resolution archival data of one of the targets is presented, and it is shown that this CO disc model is unable to fit the high resolution data. Therefore, it is concluded that to properly fit CO spectra, high resolution data are needed, and that previously published information determined from low resolution spectra should be treated with caution.

Some Results from Studies of Microwave Discharges in Liquid Heavy Hydrocarbons

NASA Astrophysics Data System (ADS)

Averin, K. A.; Lebedev, Yu. A.; Shakhatov, V. A.

2018-01-01

Some results from studies of microwave discharges in heavy hydrocarbons are presented. Microwave energy was introduced into liquid hydrocarbon via a coaxial line. The pressure above the liquid surface was equal to the atmospheric pressure. The discharge was ignited in a mixture of argon and hydrocarbon vapor. Argon was supplied through a channel in the central conductor of the coaxial line. The emission spectra of discharges in different liquid hydrocarbons were studied. It is shown that the emission spectra mainly consist of sequences of Swan bands, while radiation of other plasma components is on the noise level. Spectra of plasma emission are presented for discharges in liquid n-heptane, nefras, and C-9 oil used to produce chemical fibers. The rotational (gas) and vibrational temperatures are determined by processing the observed spectra.

Organic holographic polymer dispersed liquid crystal distributed feedback laser from different diffraction orders

NASA Astrophysics Data System (ADS)

Liu, Minghuan; Liu, Yonggang; Zhang, Guiyang; Peng, Zenghui; Li, Dayu; Ma, Ji; Xuan, Li

2016-11-01

Holographic polymer dispersed liquid crystal (HPDLC) based distributed feedback (DFB) lasers were prepared with poly (-methoxy-5-(2‧-ethyl-hexyloxy)-1,4-phenylene-vinylene) (MEH-PPV) film as the active medium layer. The HPDLC grating film was fabricated via holographic induced photopolymerization. The pure film spectra of MEH-PPV and the amplified spontaneous emission (ASE) spectrum were investigated. The laser device was single-longitudinal mode operation. The tunability of the HPDLC DFB laser was achieved by selecting different grating periods. The lasing performances were also characterized and compared from different diffraction orders. The lasing threshold increased with the diffraction order and the third order laser possessed the largest conversion efficiency in this device. The experimental results were in good agreement with the theoretical calculations.

Defect-mediated photoluminescence up-conversion in cadmium sulfide nanobelts (Conference Presentation)

NASA Astrophysics Data System (ADS)

Morozov, Yurii; Kuno, Masaru K.

2017-02-01

The concept of optical cooling of solids has existed for nearly 90 years ever since Pringsheim proposed a way to cool solids through the annihilation of phonons via phonon-assisted photoluminescence (PL) up-conversion. In this process, energy is removed from the solid by the emission of photons with energies larger than those of incident photons. However, actually realizing optical cooling requires exacting parameters from the condensed phase medium such as near unity external quantum efficiencies as well as existence of a low background absorption. Until recently, laser cooling has only been successfully realized in rare earth doped solids. In semiconductors, optical cooling has very recently been demonstrated in cadmium sulfide (CdS) nanobelts as well as in hybrid lead halide perovskites. For the former, large internal quantum efficiencies, sub-wavelength thicknesses, which decrease light trapping, and low background absorption, all make near unity external quantum yields possible. Net cooling by as much as 40 K has therefore been possible with CdS nanobelts. In this study, we describe a detailed investigation of the nature of efficient anti-Stokes photoluminescence (ASPL) in CdS nanobelts. Temperature-dependent PL up-conversion and optical absorption studies on individual NBs together with frequency-dependent up-converted PL intensity spectroscopies suggest that ASPL in CdS nanobelts is defect-mediated through involvement of defect levels below the band gap.

The Infrared Spectra of Polycyclic Aromatic Hydrocarbons with Excess Peripheral H Atoms (H(sub n)-PAHs) and their Relation to the 3.4 and 6.9 Micrometer PAH Emission Features

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Bernstein, Max P.; Materese, Christopher K.

2013-01-01

A population of polycyclic aromatic hydrocarbons (PAHs) and related materials are thought to be responsible for the family of infrared emission features that are seen towards a wide variety of astrophysical environments. A potentially important subclass of these materials are polycyclic aromatic hydrocarbons whose edges contain excess H atoms (H(sub n)-PAHs). While it has been suggested that this type of compound may be present in the interstellar population, it has been difficult to properly assess this possibility because of a lack of suitable infrared laboratory spectra to assist with analysis of the astronomical data. We present the 4000-500 cm(exp -1) (2.5-20 micrometers) infrared spectra of 23 H(sub n)-PAHs and related molecules isolated in argon matrices, under conditions suitable for use in the interpretation of astronomical data. The spectra of molecules with mixed aromatic and aliphatic domains show unique characteristics that distinguish them from their fully aromatic PAH equivalents. We discuss the changes to the spectra of these types of molecules as they transition from fully aromatic to fully aliphatic forms. The implications for the interpretation of astronomical spectra are discussed with specific emphasis on the 3.4 and 6.9 micrometer features. Laboratory data is compared with emission spectra from IRAS 21282+5050, an object with normal PAH emission features, in addition to IRAS 22272+5435 and IRAS 0496+3429, two protoplanetary nebulae with abnormally large 3.4 micrometer features. We show that 'normal' PAH emission objects contain relatively few H(sub n)-PAHs in their emitter populations, but less evolved protoplanetary nebulae may contain significant abundances of these molecules.

Single particle size and fluorescence spectra from emissions of burning materials in a tube furnace to simulate burn pits

NASA Astrophysics Data System (ADS)

Pan, Yong-Le; Houck, Joshua D. T.; Clark, Pamela A.; Pinnick, Ronald G.

2013-08-01

A single-particle fluorescence spectrometer (SPFS) and an aerodynamic particle sizer were used to measure the fluorescence spectra and particle size distribution from the particulate emissions of 12 different burning materials in a tube furnace to simulate open-air burning of garbage. Although the particulate emissions are likely dominated by particles <1 μm diameter, only the spectra of supermicron particles were measured here. The overall fluorescence spectral profiles exhibit either one or two broad bands peaked around 300-450 nm within the 280-650 nm spectral range, when the particles are illuminated with a 263-nm laser. Different burning materials have different profiles, some of them (cigarette, hair, uniform, paper, and plastics) show small changes during the burning process, and while others (beef, bread, carrot, Styrofoam, and wood) show big variations, which initially exhibit a single UV peak (around 310-340 nm) and a long shoulder in visible, and then gradually evolve into a bimodal spectrum with another visible peak (around 430-450 nm) having increasing intensity during the burning process. These spectral profiles could mainly derive from polycyclic aromatic hydrocarbons with the combinations of tyrosine-like, tryptophan-like, and other humic-like substances. About 68 % of these single-particle fluorescence spectra can be grouped into 10 clustered spectral templates that are derived from the spectra of millions of atmospheric aerosol particles observed in three locations; while the others, particularly these bimodal spectra, do not fall into any of the 10 templates. Therefore, the spectra from particulate emissions of burning materials can be easily discriminated from that of common atmospheric aerosol particles. The SFFS technology could be a good tool for monitoring burning pit emissions and possibly for distinguishing them from atmospheric aerosol particles.

High-Performance First-Principles Molecular Dynamics for Predictive Theory and Modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gygi, Francois; Galli, Giulia; Schwegler, Eric

This project focused on developing high-performance software tools for First-Principles Molecular Dynamics (FPMD) simulations, and applying them in investigations of materials relevant to energy conversion processes. FPMD is an atomistic simulation method that combines a quantum-mechanical description of electronic structure with the statistical description provided by molecular dynamics (MD) simulations. This reliance on fundamental principles allows FPMD simulations to provide a consistent description of structural, dynamical and electronic properties of a material. This is particularly useful in systems for which reliable empirical models are lacking. FPMD simulations are increasingly used as a predictive tool for applications such as batteries, solarmore » energy conversion, light-emitting devices, electro-chemical energy conversion devices and other materials. During the course of the project, several new features were developed and added to the open-source Qbox FPMD code. The code was further optimized for scalable operation of large-scale, Leadership-Class DOE computers. When combined with Many-Body Perturbation Theory (MBPT) calculations, this infrastructure was used to investigate structural and electronic properties of liquid water, ice, aqueous solutions, nanoparticles and solid-liquid interfaces. Computing both ionic trajectories and electronic structure in a consistent manner enabled the simulation of several spectroscopic properties, such as Raman spectra, infrared spectra, and sum-frequency generation spectra. The accuracy of the approximations used allowed for direct comparisons of results with experimental data such as optical spectra, X-ray and neutron diffraction spectra. The software infrastructure developed in this project, as applied to various investigations of solids, liquids and interfaces, demonstrates that FPMD simulations can provide a detailed, atomic-scale picture of structural, vibrational and electronic properties of complex systems relevant to energy conversion devices.« less

Temperature-dependent luminescence and temperature-stimulated NIR-to-VIS up-conversion in Nd3+-doped La2O3-Na2O-ZnO-TeO2 glasses

NASA Astrophysics Data System (ADS)

Sobczyk, Marcin

2013-04-01

Telluride glasses of the composition xNd2O3-(7-x)La2O3-3Na2O-25ZnO-65TeO2, where (0≤x≤7) were prepared by the melt quench technique. Some physical and optical properties of the glasses were evaluated. The thermal behavior i.e. glass transition and crystallization temperatures were studied by using TGA-DTA technique. Optical properties of Nd3+-doped telluride glasses were investigated between 298 and 700 K. Basing on the obtained values of J-O parameter values (×10-20 cm2: Ω2=4.49±0.84, Ω4=5.03±0.61, Ω6=4.31±0.73), the radiative transition probabilities (AT), radiative lifetimes (τR), fluorescence branching ratios (β) and emission cross-sections (σem) were calculated for the 4F3/2→4IJ/2 (where J=9, 11 and 13) transitions of Nd3+ ions. The τR value of the 4F3/2 level amount to 164 μs and is slightly higher than the measured decay time of 162 μs. With the increasing of Nd2O3 concentration from 0.5 to 7.0 mol% the experimental lifetime of the fluorescent level decreases from 162 to 5.6 μs. The estimated quantum efficiency amount to 100%, based on a comparison of τR and the experimental decay time of a slightly doped Nd3+ telluride glass. An analysis of the non-radiative decay was based on the cross-relaxation mechanisms. The 4F3/2→4I9/2 and 4F5/2→4I9/2 transitions were analyzed with respect to the fluorescence intensity ratio (FIR) and were found to be temperature dependent. Infrared-to-visible up-conversion emissions with a maximum at 603.0 and 635.3 nm were observed at high temperatures using the 804 nm excitation and are due to the 4G5/2→4I9/2 and 4G5/2→4I11/2 transitions of Nd3+ ions, respectively. The near quadratic dependence of fluorescence on excitation laser power confirms that two photons contribute to up-conversion of the orange emissions. The temperature-stimulated up-conversion excitation processes have been analyzed in detail. The optical results indicate that the investigated glasses are potentially applicable as a 1063 nm laser host as well as an optical sensor for temperature measurements.

A New Era of Submillimeter GRB Afterglow Follow-Ups with the Greenland Telescope

NASA Astrophysics Data System (ADS)

Urata, Yuji; Huang, Kuiyun; Asada, Keiichi; Hirashita, Hiroyuki; Inoue, Makoto; Ho, Paul T. P.

A planned rapid submillimeter (submm) Gamma Ray Burst (GRBs) follow-up observations conducted using the Greenland Telescope (GLT) is presented. The GLT is a 12-m submm telescope to be located at the top of the Greenland ice sheet, where the high-altitude and dry weather porvides excellent conditions for observations at submm wavelengths. With its combination of wavelength window and rapid responding system, the GLT will explore new insights on GRBs. Summarizing the current achievements of submm GRB follow-ups, we identify the following three scientific goals regarding GRBs: (1) systematic detection of bright submm emissions originating from reverse shock (RS) in the early afterglow phase, (2) characterization of forward shock and RS emissions by capturing their peak flux and frequencies and performing continuous monitoring, and (3) detections of GRBs as a result of the explosion of first-generation stars result of GRBs at a high redshift through systematic rapid follow ups. The light curves and spectra calculated by available theoretical models clearly show that the GLT could play a crucial role in these studies.

Synchrotron and Synchrotron Self-Compton Spectral Signatures and Blazar Emission Models

NASA Technical Reports Server (NTRS)

Chiang, James; Boettcher, Markus; White, Nicholas E. (Technical Monitor)

2002-01-01

We find that energy losses due to synchrotron self-Compton (BBC) emission in Blazar jets can produce distinctive signatures in the time-averaged synchrotron and SSC spectra of these objects. For a fairly broad range of particle injection distributions, SSC-loss-dominated synchrotron emission exhibits a spectral dependence Fv approximately v (exp -3/2). The presence or absence of this dependence in the optical and ultraviolet spectra of flat-spectrum radio quasars such as PC 279 and in the soft X-ray spectra of high-frequency BL Lac objects such as Mark 501 gives a robust measure of the importance of SSC losses. Furthermore, for partially cooled particle distributions, spectral breaks of varying sizes can appear in the synchrotron and SSC spectra and will be related to the spectral indices of the emission below the break. These spectral signatures place constraints on the size scale and the nonthermal particle content of the emitting plasma, as well as the observer orientation relative to the jet axis.

Study of an efficient conversion of 1,3-dimethyl-5-(Arylazo)-6-Amino-Uracils to 1,3-dimethyl-8-(Aryl)-Azapurin-2,6-Diones

NASA Astrophysics Data System (ADS)

Debnath, Diptanu; Purkayastha, Atanu; Kirillov, Alexander; Ganguly, Rakesh; Misra, Tarun Kumar

2017-12-01

6-Aminouracils have extensively been used as precursors for synthesizing numerous uracil derivatives of biological and pharmaceutical significance. This study describes an application of 1,3-dimethyl-5-(arylazo)-6-aminouracils (Uazo: Uazo1-Uazo4, precursors) for an efficient synthesis of a series of 8-substituted-azapurins (AP), namely 1,3-dimethyl-8-(aryl)-azapurin-2,6-diones (aryl = p-HC6H4 (AP1), -MeC6H4 (AP2), sbnd ClC6H4 (AP3), and sbnd SO2NH2C6H4 (AP4)) following an oxidation method in the presence of copper (II) nitrate and in alkaline medium. The obtained compounds were isolated in good yields as crystalline air-stable products and have been fully characterized in the solution by UV-vis and NMR spectroscopy, as well as in the solid state by FT-IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction (for AP2 and AP4). UV-vis study evidences that the conversion of the 6-aminouracil precursors occurs via an intermediate, Cu(II)-complex and a plausible mechanism for the formation of AP1-AP4 has been proposed. Unlike AP2 the crystal structure of AP4 reveals the formation of interdigitated 1D H-bonded chains that has been topologically classified within the 2C1 type. The 1H NMR spectra of the products have proton signals that completely devoid of hydrazone (sbnd NHsbnd) and imine (=NH) signals of their parent Uazo derivatives, thus confirming their full conversion and a stability of the AP1-AP4 in solution. The excitation and emission spectra of AP1-AP4 were also recorded in solution, revealing electronic transitions between similar vibrational energy levels of S0 (singlet ground state) and S1 (singlet first excited state).

Experimental protocol for high-fidelity heralded photon-to-atom quantum state transfer.

PubMed

Kurz, Christoph; Schug, Michael; Eich, Pascal; Huwer, Jan; Müller, Philipp; Eschner, Jürgen

2014-11-21

A quantum network combines the benefits of quantum systems regarding secure information transmission and calculational speed-up by employing quantum coherence and entanglement to store, transmit and process information. A promising platform for implementing such a network are atom-based quantum memories and processors, interconnected by photonic quantum channels. A crucial building block in this scenario is the conversion of quantum states between single photons and single atoms through controlled emission and absorption. Here we present an experimental protocol for photon-to-atom quantum state conversion, whereby the polarization state of an absorbed photon is mapped onto the spin state of a single absorbing atom with >95% fidelity, while successful conversion is heralded by a single emitted photon. Heralded high-fidelity conversion without affecting the converted state is a main experimental challenge, in order to make the transferred information reliably available for further operations. We record >80 s(-1) successful state transfer events out of 18,000 s(-1) repetitions.

Archival Study of Energetic Processes in the Upper Atmosphere of the Outer Planets

NASA Technical Reports Server (NTRS)

Ballester, Gilda E.; Harris, Walter M.

1998-01-01

We compare International Ultraviolet Explorer (IUE) spectral observations of Jupiter's UltraViolet (UV) aurora in H-Lyman alpha (H-Lya) and H2 emissions with images of the UV aurora with HST to make more realistic interpretations of the IUE dataset. Use the limited spatial information in the IUE line-by-line spectra of the bright H-Lya line emission in the form of pseudo-monochromatic images at the IUE 3.5 arcsec resolution (Lya pseudo-images), to derive information on the emissions. Analysing of H2 spectra of Saturn's UV aurora to infer atmospheric level of auroral excitation from the methane absorption (color ratios). Analysing of a Uranus IUE dataset to determine periodicity in the emissions attributable to auroral emission fixed in magnetic longitude. Reviewing of the results from IUE observations of the major planets, upper atmospheres and interactions with the planets magnetospheres. Analysing of IUE spectra of the UV emissions from Io to identify excitation processes and infer properties of the Io-torus-Jupiter system.

Ultraviolet observations of clusters of Wolf-Rayet stars in the SBm3 galaxy NGC 4214 and Ultraviolet and optical observations of LINER's

NASA Technical Reports Server (NTRS)

Filippenko, Alexei V.

1992-01-01

The purpose of the grant was to obtain and analyze IUE (UV) and ground-based (optical) spectra of the central bar of NGC 4214, which contains several bright H II regions, in order to further explore the properties of the Wolf-Rayet stars in this galaxy. Several spatially distinct regions, with widely different equivalent widths of optical Wolf-Rayet lines, could be sampled by the large IUE entrance aperture. By using newly developed extraction techniques, the spectra of these H II regions could be isolated, and differences in their stellar populations would be systematically studied. Data were obtained with IUE in late February and early March, 1992. Some of the shifts were successful, but a few were not -- apparently the blind offset from the nearby star did not work equally well in all cases. Thus, the signal-to-noise ratio is somewhat lower than we had hoped. This necessitated a more careful extraction of the spectra of individual H II regions from the two-dimensional spectra. (A program that models the point spread function in the spatial direction was used to deblend the distinct H II regions.) The IUE data are currently being analyzed in conjunction with ground-based optical spectra. There appear to be obvious variations in the stellar population over angular scales of only a few arc seconds. The second part of the research performed under this grant was a continuation of a project that uses IUE (UV) and ground-based (optical) spectra to infer the physical conditions in Low-Ionization Nuclear Emission-Line Regions (LINER's). We have obtained spectra of a few key objects that cover a representative range in LINER continuum and emission-line properties. The overall goals are to (1) separate the emission into spatially distinct components, (2) establish whether the observed nuclear ultraviolet continua indicate sufficient photoionizing fluxes to account for the emission lines, (3) determine whether the nuclear emission can be explained by hot stars alone, (4) detect and measure the strengths of UV emission lines, and (5) search for systematic differences in the UV spectra of LINER's whose other properties differ in some respects.

Manipulation of spontaneous emission in a tapered photonic crystal fibre

NASA Astrophysics Data System (ADS)

Myers, S. J.; Fussell, D. P.; Dawes, J. M.; Mägi, E.; McPhedran, R. C.; Eggleton, B. J.; de Sterke, C. Martijn

2006-12-01

We characterize the spontaneous emission of dye that is introduced into the central core of a tapered photonic crystal fiber. Since the photonic crystal period in the fibre cladding varies along the taper, the transmission and spontaneous emission spectra over a wide range of relative frequencies can be observed. The spontaneous emission spectra of the fibre transverse to the fiber axis show suppression due to partial band-gaps of the structure, and also enhancement of spontaneous emission near the band edges. We associate these with van Hove features, as well as finite cluster size effects.

Evidence for Stable v = 0, j = 1 → 0 SiO Maser Emission from VY Canis Majoris

NASA Astrophysics Data System (ADS)

McIntosh, G. C.; Rislow, B.

2009-02-01

Observations of the SiO v = 0, J = 1 → 0 spectra from VY CMa from 2003 through 2006 indicate an unusually long-lived, highly linearly polarized maser emission at a V lsr of approximately 18.5 km s-1. A time series cross-correlation analysis has been developed for calculating the characteristic lifetime of linearly polarized spectra. Applying the cross-correlation to these spectra indicates a characteristic lifetime of 5600 ± 400 days. These emission characteristics may be generated in a region of relatively stable outflow geometry and magnetic field rather than in the more ephemeral circumstellar environment.

Inference of Surface Chemical and Physical Properties Using Mid-Infrared (MIR) Spectral Observations

NASA Technical Reports Server (NTRS)

Roush, Ted L.

2016-01-01

Reflected or emitted energy from solid surfaces in the solar system can provide insight into thermo-physical and chemical properties of the surface materials. Measurements have been obtained from instruments located on Earth-based telescopes and carried on several space missions. The characteristic spectral features commonly observed in Mid-Infrared (MIR) spectra of minerals will be reviewed, along with methods used for compositional interpretations of MIR emission spectra. The influence of surface grain size, and space weathering processes on MIR emissivity spectra will also be discussed. Methods used for estimating surface temperature, emissivity, and thermal inertias from MIR spectral observations will be reviewed.

A rocket measurement of the extreme ultraviolet dayglow

NASA Technical Reports Server (NTRS)

Christensen, A. B.

1976-01-01

Extreme ultraviolet spectra of the mid-latitude dayglow in the wavelength range of 550 to 1250A have been obtained with a rocket borne grating spectrometer at a resolution of 20A. Spectra were obtained in the altitude range of 140 to 280 km. The spectra are dominated by emissions from atomic multiplets and no molecular bands have been identified with certainty. The strongest emissions other than H Lyman-alpha are OI (989) and OII (834). Other prominent emissions include He I(584), N II(916) and N II(1085). An unexpected feature near 612A has an intensity comparable to He I(584).

Singularities in x-ray spectra of metals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mahan, G.D.

1987-08-01

The x-ray spectroscopies discussed are absorption, emission, and photoemission. The singularities show up in each of them in a different manner. In absorption and emission they show up as power law singularities at the thresholds frequencies. This review will emphasize two themes. First a simple model is proposed to describe this phenomena, which is now called the MND model after MAHAN-NOZIERES-DeDOMINICIS. Exact analytical solutions are now available for this model for the three spectroscopies discussed above. These analytical models can be evaluated numerically in a simple way. The second theme of this review is that great care must be usedmore » when comparing the theory to experiment. A number of factors influence the edge shapes in x-ray spectroscopy. The edge singularities play an important role, and are observed in many matals. Quantitative fits of the theory to experiment require the consideration of other factors. 51 refs.« less

NIF unconverted light and its influence on DANTE measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Girard, Frederic; Suter, Larry; Landen, Otto

2009-06-15

NIF laser facility produces 1053 nm light and a fundamental requirement for NIF is to give up to 1.8 MJ of 351 nm light for target physics experiments. The 351 nm light is provided by frequency tripling the 1053 nm light in nonlinear crystals in the final optics assembly, just before the laser light enters the target chamber. Since this tripling process is not 100% efficient, unconverted light from the conversion process also enters the chamber. This unconverted light does not directly hit the target but it can strike target support structures at average intensities of few TW/cm{sup 2} wheremore » it can generate unwanted, background soft x-rays that are measured by the soft x-ray diagnostic DANTE installed on the NIF target chamber. This diagnostic quantifies the x-radiation intensity inside the hohlraum by measuring the x-ray flux coming from the target's laser entrance hole. Due to its centimeter wide field of view, it integrates x-ray emission from both the flux exiting a hohlraum laser entrance hole and from the target support structure irradiated by residual 1{omega} and 2{omega} unconverted light. This work gives quantitative evaluations of the unconverted light for the first time and the effects on DANTE measurements for the future NIF tuning experiment called ''Shock timing.'' Emission spectra are significantly modified leading to an overestimation of radiative temperature during the foot of the laser pulse since background x-rays are predominant in first two DANTE channel measurements. Mitigations of these effects by coating silicon paddle with plastic, using a smaller collimator to reduce DANTE field of view or eliminating DANTE channels in the analysis have been investigated.« less

NIF unconverted light and its influence on DANTE measurements.

PubMed

Girard, Frederic; Suter, Larry; Landen, Otto; Munro, Dave; Regan, Sean; Kline, John

2009-06-01

NIF laser facility produces 1053 nm light and a fundamental requirement for NIF is to give up to 1.8 MJ of 351 nm light for target physics experiments. The 351 nm light is provided by frequency tripling the 1053 nm light in nonlinear crystals in the final optics assembly, just before the laser light enters the target chamber. Since this tripling process is not 100% efficient, unconverted light from the conversion process also enters the chamber. This unconverted light does not directly hit the target but it can strike target support structures at average intensities of few TW/cm2 where it can generate unwanted, background soft x-rays that are measured by the soft x-ray diagnostic DANTE installed on the NIF target chamber. This diagnostic quantifies the x-radiation intensity inside the hohlraum by measuring the x-ray flux coming from the target's laser entrance hole. Due to its centimeter wide field of view, it integrates x-ray emission from both the flux exiting a hohlraum laser entrance hole and from the target support structure irradiated by residual 1omega and 2omega unconverted light. This work gives quantitative evaluations of the unconverted light for the first time and the effects on DANTE measurements for the future NIF tuning experiment called "Shock timing." Emission spectra are significantly modified leading to an overestimation of radiative temperature during the foot of the laser pulse since background x-rays are predominant in first two DANTE channel measurements. Mitigations of these effects by coating silicon paddle with plastic, using a smaller collimator to reduce DANTE field of view or eliminating DANTE channels in the analysis have been investigated.

The modification of spectral characteristics of cytostatics by optical beams

NASA Astrophysics Data System (ADS)

Pascu, Mihail Lucian; Brezeanu, Mihail; Carstocea, Benone D.; Voicu, Letitia; Gazdaru, Doina M.; Smarandache, Adriana A.

2004-10-01

Besides the biochemical action of methotrexate (MTX) and 5-fluorouracil (FU) their effect in destroying cancer tumours could be enhanced by exposure to light at different doses. Absorption, excitation and emission spectra of 10-4M - 10-5M MTX solutions in natural saline and sodium hydroxide at pH = 8.4 were measured, while their exposure to coherent and uncoherent light in the visible and near ultraviolet (UV) spectral ranges was made (Hg lamps and Nitrogen pulsed laser radiation were used). Absorption spectra exhibit spectral bands in the range 200 nm - 450 nm. The 200 - 450 nm excitation spectra were measured with emission centered on 470 nm; MTX fluorescence excitation was measured at 390 nm and the emission was detected between 400 nm and 600 nm showing a maximum at 470 nm. Spectra modifications, nonlinearly depending on exposure time (varying from 1 min to 20 min), evidenced MTX photo-dissociation to the fluorescent compound 2,4 diamino-formylpteridine. In the 5-FU case the absorption spectra exhibit bands between 200 nm and 450 nm. The emission fluorescence spectra were measured between 400 nm and 600 nm, with λex = 350 nm for UV Hg lamp and with λex = 360 nm for laser irradiated samples; at irradiation with N2 laser emitted radiation the excitation spectra were measured in the range of 200 nm - 400 nm, with λem = 440 nm. New vascularity rapid destruction was observed for conjunctive impregnated with 5-FU solution whilst exposed to incoherent UV and visible light.

New two-photon excitation chromophores for cellular imaging

NASA Astrophysics Data System (ADS)

D'Alfonso, Laura; Chirico, Giuseppe; Collini, Maddalena; Baldini, Giancarlo; Diaspro, Alberto; Ramoino, Paola; Abbotto, Alessandro; Beverina, Luca; Pagani, Giorgio A.

2003-10-01

The one photon and two photon excitation spectral properties (absorption, emission spectra, singlet lifetime) of a very efficient two photon absorber, dimethyl-pepep, have been measured in solution. The one photon excitation peak lye near 525 nm and the emission falls at 600 nm, where autofluorescence of cells is weak. The value of the singlet-triplet conversion rate, obtained by two-photon excitation fluorescence correlation spectroscopy, has a quadratic dependence on the excitation power and is comparable to that shown by the dye rhodamine. Preliminary results on stained cells from yeast Saccaromices cerevisiae and Paramecium primaurelia show that the dye preferentially stains DNA in the cell. A direct comparison with a DNA stainer, Dapi, is also performed. Some measurements of the dye functionalized to react with lysine and n-terminal residues of protein are presented. Moreover, this dye can be employed in order to follow in detail some cellular processes such as nuclei division. In vitro fluorescence titration of dimethyl-pepep with calf thymus DNA allowed to estimate the values of the dye-DNA association constant versus ionic strength, and an affinity close to that of ethidium bromide is found.

X-ray emission spectroscopy of biomimetic Mn coordination complexes

DOE PAGES

Jensen, Scott C.; Davis, Katherine M.; Sullivan,

2017-05-19

Understanding the function of Mn ions in biological and chemical redox catalysis requires precise knowledge of their electronic structure. X-ray emission spectroscopy (XES) is an emerging technique with a growing application to biological and biomimetic systems. Here, we report an improved, cost-effective spectrometer used to analyze two biomimetic coordination compounds, [Mn IV(OH) 2(Me 2EBC)] 2+ and [Mn IV(O)(OH)(Me 2EBC)] +, the second of which contains a key Mn IV=O structural fragment. Despite having the same formal oxidation state (Mn IV) and tetradentate ligands, XES spectra from these two compounds demonstrate different electronic structures. Experimental measurements and DFT calculations yield differentmore » localized spin densities for the two complexes resulting from Mn IV–OH conversion to Mn IV=O. The relevance of the observed spectroscopic changes is discussed for applications in analyzing complex biological systems such as photosystem II. In conclusion, a model of the S 3 intermediate state of photosystem II containing a Mn IV=O fragment is compared to recent time-resolved X-ray diffraction data of the same state.« less

Self-consistent Non-LTE Model of Infrared Molecular Emissions and Oxygen Dayglows in the Mesosphere and Lower Thermosphere

NASA Technical Reports Server (NTRS)

Feofilov, Artem G.; Yankovsky, Valentine A.; Pesnell, William D.; Kutepov, Alexander A.; Goldberg, Richard A.; Mauilova, Rada O.

2007-01-01

We present the new version of the ALI-ARMS (for Accelerated Lambda Iterations for Atmospheric Radiation and Molecular Spectra) model. The model allows simultaneous self-consistent calculating the non-LTE populations of the electronic-vibrational levels of the O3 and O2 photolysis products and vibrational level populations of CO2, N2,O2, O3, H2O, CO and other molecules with detailed accounting for the variety of the electronic-vibrational, vibrational-vibrational and vibrational-translational energy exchange processes. The model was used as the reference one for modeling the O2 dayglows and infrared molecular emissions for self-consistent diagnostics of the multi-channel space observations of MLT in the SABER experiment It also allows reevaluating the thermalization efficiency of the absorbed solar ultraviolet energy and infrared radiative cooling/heating of MLT by detailed accounting of the electronic-vibrational relaxation of excited photolysis products via the complex chain of collisional energy conversion processes down to the vibrational energy of optically active trace gas molecules.

X-ray Emission Spectroscopy of Biomimetic Mn Coordination Complexes.

PubMed

Jensen, Scott C; Davis, Katherine M; Sullivan, Brendan; Hartzler, Daniel A; Seidler, Gerald T; Casa, Diego M; Kasman, Elina; Colmer, Hannah E; Massie, Allyssa A; Jackson, Timothy A; Pushkar, Yulia

2017-06-15

Understanding the function of Mn ions in biological and chemical redox catalysis requires precise knowledge of their electronic structure. X-ray emission spectroscopy (XES) is an emerging technique with a growing application to biological and biomimetic systems. Here, we report an improved, cost-effective spectrometer used to analyze two biomimetic coordination compounds, [Mn IV (OH) 2 (Me 2 EBC)] 2+ and [Mn IV (O)(OH)(Me 2 EBC)] + , the second of which contains a key Mn IV ═O structural fragment. Despite having the same formal oxidation state (Mn IV ) and tetradentate ligands, XES spectra from these two compounds demonstrate different electronic structures. Experimental measurements and DFT calculations yield different localized spin densities for the two complexes resulting from Mn IV -OH conversion to Mn IV ═O. The relevance of the observed spectroscopic changes is discussed for applications in analyzing complex biological systems such as photosystem II. A model of the S 3 intermediate state of photosystem II containing a Mn IV ═O fragment is compared to recent time-resolved X-ray diffraction data of the same state.

Influence of Gd3+ concentration on luminescence properties of Eu3+ ions in sol-gel materials

NASA Astrophysics Data System (ADS)

Szpikowska-Sroka, Barbara; Pawlik, Natalia; Pisarski, Wojciech A.

2016-12-01

The sol-gel powders doubly-doped with Gd3+/Eu3+ ions with different concentration of Gd3+ have been successfully obtained. The spectroscopic characterization of prepared samples was conducted based on excitation and emission spectra as well as luminescence decay analysis. Upon direct excitation of Eu3+ active ions, the characteristic 5D0 → 7F1 (orange) and 5D0 → 7F2 (red) emission bands were observed. The energy transfer from Gd3+ to Eu3+ ions was registered upon λexc = 273 nm excitation. An efficient conversion of ultraviolet radiation (UV) into visible luminescence was successfully observed. The energy transfer process from Gd3+ to Eu3+ led to longer luminescence decay from the 5D0 state in comparison to that obtained under direct excitation of Eu3+ ions (λexc = 393 nm). Generally, obtained results clearly indicated the beneficial influence of increasing concentration of Gd3+ ions on luminescence properties of Eu3+ in studied silica sol-gel phosphors.

Spreadsheet-Based Program for Simulating Atomic Emission Spectra

ERIC Educational Resources Information Center

Flannigan, David J.

2014-01-01

A simple Excel spreadsheet-based program for simulating atomic emission spectra from the properties of neutral atoms (e.g., energies and statistical weights of the electronic states, electronic partition functions, transition probabilities, etc.) is described. The contents of the spreadsheet (i.e., input parameters, formulas for calculating…

A new photoluminescence emission peak of ZnO SiO2 nanocomposites and its energy transfer to Eu3+ ions

NASA Astrophysics Data System (ADS)

Hong, Jian-He; Cong, Chang-Jie; Zhang, Zhi-Guo; Zhang, Ke-Li

2007-07-01

This work reports a new photoluminescence (PL) emission peak at about 402 nm from amorphous ZnO nanoparticles in a silica matrix, and the energy transfer from it to Eu3+ ions. The amorphous ZnO SiO2 nanocomposites were prepared by the sol gel method, which is verified by X-ray diffraction (XRD) profiles and FT IR spectra. The luminescence emission spectra are fitted by four Gauss profiles, two of which at longer wavelength are due to the defects of the material and the others to amorphous ZnO nanoparticles and the Zn O Si interface state. With the reduction of Zn/Si ratio and diethanolamine, the relative intensities of visible emission decrease. The weak visible emission is due to the reduction of defects after calcined at high temperature. The new energy state at the Zn O Si interface results in strong emission at about 402 nm. When Eu3+ ions are co-doped, weak energy transfer from ZnO SiO2 nanocomposites to Eu3+ emission are observed in the excitation spectra.

Unreported Emission Lines of Rb, Ce, La, Sr, Y, Zr, Pb and Se Detected Using Laser-Induced Breakdown Spectroscopy

NASA Technical Reports Server (NTRS)

Lepore, K. H.; Mackie, J.; Dyar, M. D.; Fassett, C. I.

2017-01-01

Information on emission lines for major and minor elements is readily available from the National Institute of Standards and Technology (NIST) as part of the Atomic Spectra Database. However, tabulated emission lines are scarce for some minor elements and the wavelength ranges presented on the NIST database are limited to those included in existing studies. Previous work concerning minor element calibration curves measured using laser-induced break-down spectroscopy found evidence of Zn emission lines that were not documented on the NIST database. In this study, rock powders were doped with Rb, Ce, La, Sr, Y, Zr, Pb and Se in concentrations ranging from 10 percent to 10 parts per million. The difference between normalized spectra collected on samples containing 10 percent dopant and those containing only 10 parts per million were used to identify all emission lines that can be detected using LIBS (Laser-Induced Breakdown Spectroscopy) in a ChemCam-like configuration at the Mount Holyoke College LIBS facility. These emission spectra provide evidence of many previously undocumented emission lines for the elements measured here.

A new near infrared photosensitizing nanoplatform containing blue-emitting up-conversion nanoparticles and hypocrellin A for photodynamic therapy of cancer cells

NASA Astrophysics Data System (ADS)

Jin, Shan; Zhou, Liangjun; Gu, Zhanjun; Tian, Gan; Yan, Liang; Ren, Wenlu; Yin, Wenyan; Liu, Xiaodong; Zhang, Xiao; Hu, Zhongbo; Zhao, Yuliang

2013-11-01

The utilization of up-conversion nanoparticles (UCNPs) for photodynamic therapy (PDT) has gained significant interest due to their unique ability to convert near infrared light to UV/visible light. Previous work mainly focused on the fabrication of green and red emitting UCNPs to load photosensitizers (PSs) for PDT. In this work, we firstly developed a new multifunctional nanoplatform combining blue-emitting UCNPs with blue-light excited PS (hypocrellin A, HA) as a NIR photosensitizing nanoplatform for PDT of cancer cells. Tween 20 coated NaYbF4:Tm, Gd@NaGdF4 UCNPs (Tween 20-UCNPs) with strong blue up-conversion luminescence and good water dispersibility were prepared for use as PS carriers. The blue emission band matched well with the efficient absorption band of HA, thereby facilitating the resonance energy transfer from UCNPs to HA and then activating HA to produce singlet oxygen (1O2). The in vitro study showed that these Tween 20-UCNPs@HA complexes could efficiently produce 1O2 to kill cancer cells under 980 nm NIR excitation. Moreover, these Gd3+ and Yb3+ containing nanoparticles also exhibited positive contrast effects in both T1 weighted magnetic resonance imaging (MRI) and computed tomography (CT) imaging, making them become a multifunctional platform for simultaneous PDT and bio-imaging.The utilization of up-conversion nanoparticles (UCNPs) for photodynamic therapy (PDT) has gained significant interest due to their unique ability to convert near infrared light to UV/visible light. Previous work mainly focused on the fabrication of green and red emitting UCNPs to load photosensitizers (PSs) for PDT. In this work, we firstly developed a new multifunctional nanoplatform combining blue-emitting UCNPs with blue-light excited PS (hypocrellin A, HA) as a NIR photosensitizing nanoplatform for PDT of cancer cells. Tween 20 coated NaYbF4:Tm, Gd@NaGdF4 UCNPs (Tween 20-UCNPs) with strong blue up-conversion luminescence and good water dispersibility were prepared for use as PS carriers. The blue emission band matched well with the efficient absorption band of HA, thereby facilitating the resonance energy transfer from UCNPs to HA and then activating HA to produce singlet oxygen (1O2). The in vitro study showed that these Tween 20-UCNPs@HA complexes could efficiently produce 1O2 to kill cancer cells under 980 nm NIR excitation. Moreover, these Gd3+ and Yb3+ containing nanoparticles also exhibited positive contrast effects in both T1 weighted magnetic resonance imaging (MRI) and computed tomography (CT) imaging, making them become a multifunctional platform for simultaneous PDT and bio-imaging. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr03515h

Stimulated emission pumping spectroscopy of the [X](1)A' state of CHF.

PubMed

Mukarakate, Calvin; Tao, Chong; Jordan, Christopher D; Polik, William F; Reid, Scott A

2008-01-24

We have recorded stimulated emission pumping (SEP) spectra of the A1A' ' 1A' system of CHF, which reveal rich detail concerning the rovibronic structure of the 1A' state up to approximately 7000 cm-1 above the vibrationless level. Using several intermediate A1A' ' state levels, we obtained rotationally resolved spectra for 16 of the 33 levels observed in our previous single vibronic level (SVL) emission study (Fan et al., J. Chem. Phys. 2005, 123, 014314), in addition to one new level. An anharmonic effective Hamiltonian model poorly reproduces the term energies even with the improved set of data because of the extensive interactions among levels in a given polyad (p) having combinations of nu1, nu2, nu3, which satisfy the relationship p = 2nu1 + nu2 + nu3. However, the precise A rotational constants determined from the SEP data were invaluable in clarifying the assignments for these strongly perturbed levels, and the data are well reproduced using a multiresonance effective Hamiltonian model. The derived vibrational parameters are in good agreement with high level ab initio calculations. The experimental frequencies were combined with those of CDF to derive a harmonic force field and average (rz,r(z)e) structures for the ground state.

ON THE VIABILITY OF THE PAH MODEL AS AN EXPLANATION OF THE UNIDENTIFIED INFRARED EMISSION FEATURES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yong; Kwok, Sun, E-mail: zhangy96@hku.hk, E-mail: sunkwok@hku.hk

2015-01-01

Polycyclic aromatic hydrocarbon (PAH) molecules are widely considered the preferred candidate for the carrier of the unidentified infrared emission bands observed in the interstellar medium and circumstellar envelopes. In this paper, we report the results of fitting a variety of non-PAH spectra (silicates, hydrogenated amorphous carbon, coal, and even artificial spectra) using the theoretical infrared spectra of PAHs from the NASA Ames PAH IR Spectroscopic Database. We show that these non-PAH spectra can be well fitted by PAH mixtures. This suggests that a general match between astronomical spectra and those of PAH mixtures does not necessarily provide definitive support formore » the PAH hypothesis.« less

Roadmap on optical energy conversion

DOE PAGES

Boriskina, Svetlana V.; Green, Martin A.; Catchpole, Kylie; ...

2016-06-24

For decades, progress in the field of optical (including solar) energy conversion was dominated by advances in the conventional concentrating optics and materials design. In recent years, however, conceptual and technological breakthroughs in the fields of nanophotonics and plasmonics combined with a better understanding of the thermodynamics of the photon energy-conversion processes reshaped the landscape of energy-conversion schemes and devices. Nanostructured devices and materials that make use of size quantization effects to manipulate photon density of states offer a way to overcome the conventional light absorption limits. Novel optical spectrum splitting and photon-recycling schemes reduce the entropy production in themore » optical energy-conversion platforms and boost their efficiencies. Optical design concepts are rapidly expanding into the infrared energy band, offering new approaches to harvest waste heat, to reduce the thermal emission losses, and to achieve noncontact radiative cooling of solar cells as well as of optical and electronic circuitries. Light-matter interaction enabled by nanophotonics and plasmonics underlie the performance of the third- and fourth-generation energy-conversion devices, including up- and down-conversion of photon energy, near-field radiative energy transfer, and hot electron generation and harvesting. Finally, the increased market penetration of alternative solar energy-conversion technologies amplifies the role of cost-driven and environmental considerations. This roadmap on optical energy conversion provides a snapshot of the state of the art in optical energy conversion, remaining challenges, and most promising approaches to address these challenges. Leading experts authored 19 focused short sections of the roadmap where they share their vision on a specific aspect of this burgeoning research field. The roadmap opens up with a tutorial section, which introduces major concepts and terminology. As a result, it is our hope that the roadmap will serve as an important resource for the scientific community, new generations of researchers, funding agencies, industry experts, and investors.« less

From plasma to nanoparticles: optical and particle emission of a spark discharge generator.

PubMed

Kohut, A; Ludvigsson, L; Meuller, B O; Deppert, K; Messing, M E; Galbács, G; Geretovszky, Zs

2017-11-24

The increased demand for high purity nanoparticles (NPs) of defined geometry necessitates the continuous development of generation routes. One of the most promising physical techniques for producing metal, semiconductor or alloy NPs in the gas phase is spark discharge NP generation. The technique has a great potential for up-scaling without altering the particles. Despite the simplicity of the setup, the formation of NPs in a spark discharge takes place via complex multi-scale processes, which greatly hinders the investigation via conventional NP measurement techniques. In the present work, time-resolved optical emission spectroscopy (OES) was used to provide information on the species present in the spark from as early as approximately 100 ns after the initiation of the discharge. We demonstrate that operando emission spectroscopy can deliver valuable insights into NP formation. The emission spectra of the spark are used to identify, among others, the main stages of material erosion and to calculate the quenching rate of the generated metal vapour. We demonstrate that the alteration of key control parameters, that are typically used to optimize NP generation, clearly affect the emission spectra. We report for Cu and Au NPs that the intensity of spectral lines emitted by metal atoms levels off when spark energy is increased above an energy threshold, suggesting that the maximum concentration of metal vapour produced in the generator is limited. This explains the size variation of the generated NPs. We report a strong correlation between the optical and particle emission of the spark discharge generator, which demonstrate the suitability of OES as a valuable characterization tool that will allow for the more deliberate optimization of spark-based NP generation.

VNIR Reflectance and MIR Emissivity Spectra of Ordinary Chondrite Meteorites Under Simulated Asteroid Surface Conditions

NASA Astrophysics Data System (ADS)

Gemma, M.; Shirley, K.; Glotch, T. D.; Ebel, D. S. S.

2017-12-01

Recent missions have revealed much about the nature of many Near-Earth asteroids, including the NEAR-Shoemaker target 433 Eros and Hayabusa target 25142 Itokawa. Both asteroids appear to have mineralogy consistent with ordinary chondrite meteorites. Laboratory spectral analysis of well-constrained meteorite samples can be employed as a reference tool to characterize and constrain data from current and future asteroid studies. A sample set of ordinary chondrite meteorites was chosen from the collection at the American Museum of Natural History. Six meteorites, spanning groups H, L, and LL, were prepared at four different size fractions (25-63 μm, 63-90 μm, 90-125 μm, 125-250 μm) in an attempt to mimic regolith known to exist on asteroids such as 433 Eros and 25142 Itokawa. At the Center for Planetary Exploration at Stony Brook University, spectra of the ordinary chondrite material were measured under simulated asteroid surface conditions ( 10-6 mbar, 150 K chamber temperature, low intensity illumination). The samples were used in two experiments: one measuring visible and near-infrared (VNIR) reflectance spectra at a series of temperatures, and the other measuring mid-infrared (MIR) emissivity spectra. The emissivity measurements require accurate simulation of the thermal environment within asteroid regolith, achieved by inducing a thermal gradient within the sample that results in a surface brightness temperature around 323 K (similar to the surface of 25142 Itokawa). Mid-IR emissivity spectra were collected for each sample at a surface temperature of 323 K, and reflectance spectra were collected in increments of 10 K, over the range 283 K to 373 K. Preliminary VNIR spectra show spreads similar to those seen in Hinrichs and Lucey (2002). Preliminary MIR emissivity spectra suggest that under asteroid surface conditions, the position of the Christiansen feature shifts to shorter wavelengths and emissivity is lower in the Reststrahlen bands when compared to spectra measured under terrestrial conditions. Experimental studies such as this one will enhance interpretation of current and future planetary remote sensing data sets. This work is the beginning of an effort to develop a comprehensive spectral library of materials relevant to airless bodies and future missions such as OSIRIS-REx and Hayabusa 2.

A 21st century investigation of the lightning spectrum

NASA Astrophysics Data System (ADS)

Walker, Thomas Daniel

In the mid 1960s, Martin Uman, Leon Salanave and Richard Orville laid the foundation for lightning spectroscopy. They were among the first to acquire time resolved return stroke spectra and the first to use spectroscopy as a diagnostic technique to characterize physical properties of the lightning channel. Now, almost 50 years later, technology, including CMOS and CCD high speed cameras, volume-phase holographic (VPH) gratings, and triggered lightning, has progressed to the point at which new studies in lightning spectroscopy are needed to verify and extend past measurements. New spectral lines have been discovered in the lightning spectrum as a result of the modern studies, mainly doubly ionized nitrogen lines which had not been observed in the past. The modern technique uses CMOS and CCD cameras with frame rates of up to 1Mfps with exposure down to 0.5mus. The high frame rate paired with camera memory enables a view into the quick high temperature heating period within the first few microseconds of the return stroke, as well as a detailed look at the cooling period which can last for milliseconds. The spectra are recorded digitally and discretely, hence the data can be summed to to view different exposure times revealing long lasting low emission lines during the cooling period as well. Spectral line identification for the natural and triggered lightning are for a range of wavelengths from soft ultraviolet around 3800A to the near infrared at 9500A. The first few microseconds of the lightning return stroke spectrum consists of hydrogen from disassociated water and singly and doubly ionized lines of atomic atmospheric constituents, i.e. argon, nitrogen, and oxygen. Temperatures calculated during this period have been measured above 40000 K. The peak temperature is measured from the first spectrum of the return stroke. After this the channel continuously cools over the lifetime of the return stroke unless there is an increase in the continuing current. Tens of microseconds after the onset, a cool period in the spectra exists which consists solely of neutral atomic emission lines. The cooling period temperature measurements begin in the low 20000 K range and decrease slowly over the course of milliseconds until strength of the emission lines drop below measurement threshold. Besides the return stroke, other specific lightning processes analyzed include stepped leaders, dart-stepped leaders, and m-components within the continuing current. Stepped and dart-stepped leader spectra consist both of pulsing singly ionized lines and steadily growing neutral lines. Each step within these processes cause increased ionization to occur in the channel upward from the step, demonstrating a pulsing temperature throughout the lifetime of these stepped features. Spectra of the stroke processes, m-components and continuing currents, consist of neutral atmospheric emission lines and copper emission lines which demonstrate the long duration of the channel milliseconds after the initial stages. These spectra indicate long lasting low temperatures which should give insight into temperature profiles where NOx reactions occur. From the spectra, emission identification and lifetime as well as calculations of physical parameters such as temperature, number density, and conductivity about each of these processes give insight into what is physically happening within the channel throughout the lifetime of a stroke.

Whispering gallery modes in photoluminescence and Raman spectra of a spherical microcavity with CdTe quantum dots: anti-Stokes emission and interference effects

PubMed Central

Gaponik, Nikolai; Gerlach, Matthias; Donegan, John F; Savateeva, Diana; Rogach, Andrey L

2006-01-01

We have studied the photoluminescence and Raman spectra of a system consisting of a polystyrene latex microsphere coated by CdTe colloidal quantum dots. The cavity-induced enhancement of the Raman scattering allows the observation of Raman spectra from only a monolayer of CdTe quantum dots. Periodic structure with very narrow peaks in the photoluminescence spectra of a single microsphere was detected both in the Stokes and anti-Stokes spectral regions, arising from the coupling between the emission of quantum dots and spherical cavity modes.

Detection and evaluation of normal and malignant cells using laser-induced fluorescence spectroscopy.

PubMed

Khosroshahi, Mohamad E; Rahmani, Mahya

2012-01-01

The aim of this research is to study the normalized fluorescence spectra (intensity variations and area under the fluorescence signal), relative quantum yield, extinction coefficient and intracellular properties of normal and malignant human bone cells. Using Laser-Induced Fluorescence Spectroscopy (LIFS) upon excitation of 405 nm, the comparison of emission spectra of bone cells revealed that fluorescence intensity and the area under the spectra of malignant bone cells was less than that of normal. In addition, the area ratio and shape factor were changed. We obtained two emission bands in spectra of normal cells centered at about 486 and 575 nm and for malignant cells about 482 and 586 nm respectively, which are most likely attributed to NADH and riboflavins. Using fluorescein sodium emission spectrum, the relative quantum yield of bone cells is numerically determined.

Evidence for Secondary Emission as the Origin of Hard Spectra in TeV Blazars

NASA Astrophysics Data System (ADS)

Zheng, Y. G.; Kang, T.

2013-02-01

We develop a model for the possible origin of hard, very high energy (VHE) spectra from a distant blazar. In the model, both the primary photons produced in the source and secondary photons produced outside it contribute to the observed high-energy γ-ray emission. That is, the primary photons are produced through the synchrotron self-Compton process, and the secondary photons are produced through high-energy proton interactions with background photons along the line of sight. We apply the model to a characteristic case of VHE γ-ray emission in the distant blazar 1ES 1101-232. Assuming suitable electron and proton spectra, we obtain excellent fits to the observed spectra of this blazar. This indicated that the surprisingly low attenuation of the high-energy γ-rays, especially the shape of the VHE γ-ray tail of the observed spectra, can be explained by secondary γ-rays produced in interactions of cosmic-ray protons with background photons in intergalactic space.

Population trapping: The mechanism for the lost resonance lines in Pm-like ions

NASA Astrophysics Data System (ADS)

Kato, Daiji; Sakaue, Hiroyuki A.; Murakami, Izumi; Nakamura, Nobuyuki

2017-10-01

We report a population kinetics study on line emissions of the Pm-like Bi22+ performed by using a collisional-radiative (CR) model. Population rates of excited levels are analyzed to explain the population trapping in the 4f135s2 state which causes the loss of the 5s - 5p resonance lines in emission spectra. Based on the present analysis, we elucidate why the population trapping is not facilitated for a meta-stable excited level of the Sm-like Bi21+. The emission line spectra are calculated for the Pm-like isoelectronic sequence from Au18+ through W13+ and compared with experimental measurements by electron-beam-ion-traps (EBITs). Structures of the spectra are similar for all of the cases except for calculated W13+ spectra. The calculated spectra are hardly reconciled with the measured W13+ spectrum using the compact electron-beam-ion-trap (CoBIT) [Phys. Rev. A 92 (2015) 022510].

ROSAT x ray survey observations of active chromospheric binary systems and other selected sources

NASA Technical Reports Server (NTRS)

Ramsey, Lawrence W.

1993-01-01

The connection between processes that produce optical chromospheric activity indicators and those that produce x-rays in RS CVn binary systems by taking advantage of the ROSAT All-Sky Survey (RASS) results and our unique ground-based data set was investigated. In RS CVn systems, excess emission in the Ca 2 resonance (K & H) and infrared triplet (IRT) lines and in the Balmer lines of hydrogen is generally cited as evidence for chromospheric activity, which is usually modeled as scaled up solar-type activity. X-ray emission in RS CVn systems is believed to arise from coronal loop structures. Results from spectra data obtained from RASS observations are discussed and presented.

Results from the Mars global surveyor thermal emission spectrometer

USGS Publications Warehouse

Christensen, P.R.; Anderson, D.L.; Chase, S.C.; Clancy, R.T.; Clark, R.N.; Conrath, B.J.; Kieffer, H.H.; Kuzmin, R.O.; Malin, M.C.; Pearl, J.C.; Roush, T.L.; Smith, M.D.

1998-01-01

The Thermal Emission Spectrometer spectra of low albedo surface materials suggests that a four to one mixture of pyroxene to plagioclase, together with about a 35 percent dust component provides the best fit to the spectrum. Qualitative upper limits can be placed on the concentration of carbonates (<10 percent), olivine (<10 percent), clay minerals (<20 percent), and quartz (<5 percent) in the limited regions observed. Limb observations in the northern hemisphere reveal low-lying dust hazes and detached water-ice clouds at altitudes up to 55 kilometers. At an aerocentric longitude of 224??a major dust storm developed in the Noachis Terra region. The south polar cap retreat was similar to that observed by Viking.

The ^58,60Ni(n,α) Reactions from Threshold to 50 MeV

NASA Astrophysics Data System (ADS)

Haight, R. C.; Bateman, F. B.; Sterbenz, S. M.; Chadwick, M. B.; Young, P. G.; Grimes, S. M.; Wasson, O. A.; Vonach, H.; Maier-Komor, P.

1996-10-01

Information on nuclear level densities over a wide range of excitation energies can be obtained from data on (n,α) reactions.(M. B. Chadwick et al., this meeting) We have measured α-particle emission cross sections, angular distributions and emission spectra for neutrons up to 50 MeV on targets of ^58Ni and ^60Ni using the pulsed spallation source of fast neutrons at the Los Alamos Neutron Science Center. The results will be compared with our previous measurements on ^59Co.(S. M. Grimes et al., Nuclear Science and Engineering in press) The possibilities of extending this method to much heavier nuclides will be discussed.

Monitoring Engine Vibrations And Spectrum Of Exhaust

NASA Technical Reports Server (NTRS)

Martinez, Carol L.; Randall, Michael R.; Reinert, John W.

1991-01-01

Real-time computation of intensities of peaks in visible-light emission spectrum of exhaust combined with real-time spectrum analysis of vibrations into developmental monitoring technique providing up-to-the-second information on conditions of critical bearings in engine. Conceived to monitor conditions of bearings in turbopump suppling oxygen to Space Shuttle main engine, based on observations that both vibrations in bearings and intensities of visible light emitted at specific wavelengths by exhaust plume of engine indicate wear and incipient failure of bearings. Applicable to monitoring "health" of other machinery via spectra of vibrations and electromagnetic emissions from exhausts. Concept related to one described in "Monitoring Bearing Vibrations For Signs Of Damage", (MFS-29734).

International Ultraviolet Explorer (IUE)

NASA Technical Reports Server (NTRS)

Boehm, Karl-Heinz

1992-01-01

The observation, data reduction, and interpretation of ultraviolet spectra (obtained with the International Ultraviolet Explorer) of Herbig-Haro objects, stellar jets, and (in a few cases) reflection nebulae in star-forming regions is discussed. Intermediate results have been reported in the required semi-annual reports. The observations for this research were obtained in 23 (US1) IUE shifts. The spectra were taken in the low resolution mode with the large aperture. The following topics were investigated: (1) detection of UV spectra of high excitation Herbig-Haro (HH) objects, identification of emission lines, and a preliminary study of the energy distribution of the ultraviolet continuum; (2) details of the continuum energy distribution of these spectra and their possible interpretation; (3) the properties of the reddening (extinction) of HH objects; (4) the possible time variation of strong emission lines in high excitation HH objects; (5) the ultraviolet emission of low excitation HH objects, especially in the fluorescent lines of the H2 molecule; (6) the ultraviolet emission in the peculiar object HH24; (7) the spatial emission distribution of different lines and different parts of the continuum in different HH objects; and (8) some properties of reflection nebula, in the environment of Herbig-Haro objects. Each topic is discussed.

Spectroscopy of the extreme ultraviolet dayglow at 6.5A resolution - Atomic and ionic emissions between 530 and 1240A

NASA Technical Reports Server (NTRS)

Gentieu, E. P.; Feldman, P. D.; Meier, R. R.

1979-01-01

EUV spectra (530-1500A) of the day airglow in up, down and horizontal aspect orientations have been obtained with 6.5A resolution and a limiting sensitivity of 5R from a rocket experiment. Below 834A the spectrum is rich in previously unobserved OII transitions connecting with 4S(0), 2D(0), and 2P(0) states. Recent broad-band photometric observations of geocoronal HeI 584A emission in terms of the newly observed OII emissions are shown. The OI 989A and OI 1304A emissions exhibit similar dependence on altitude and viewing geometry with the OI 989A brightness 1/15 that of OI 1340. Emission at 1026A is identified as geocoronal HI Lyman beta rather than OI multiplet emission and observed intensities agree well with model estimates. An unexpectedly high NI 1200/NI 1134A brightness ratio is evidence of a significant contribution from photodissociative excitation of N2 to the NI 1200A source function.

Differential multi-electron emission induced by swift highly charged gold ions penetrating carbon foils

NASA Astrophysics Data System (ADS)

Rothard, H.; Moshammer, R.; Ullrich, J.; Kollmus, H.; Mann, R.; Hagmann, S.; Zouros, T. J. M.

2007-05-01

First results on swift heavy ion induced electron emission from solids obtained with a reaction microscope are presented. This advanced technique, which is successfully used since quite some time to study electron ejection in ion-atom collisions, combines the measurement of the time-of-flight of electrons with imaging techniques. A combination of electric and magnetic fields guides the ejected electrons onto a position sensitive detector, which is capable to accept multiple hits. From position and time-of-flight measurement the full differential emission characteristics of up to 10 electrons per single incoming ion can be extracted. As a first example, we show energy spectra, angular distributions and the multiplicity distribution of electrons from impact of Au24+ (11 MeV/u) on a thin carbon foil (28 μg/cm2).

A Spectral Library of Emissivity Spectra for MERTIS on BepiColombo

NASA Astrophysics Data System (ADS)

Maturilli, A.; Helbert, J.; Varatharajan, I.; D'Amore, M.; Hiesinger, H.

2018-05-01

At PSL we measured emissivity spectra in vacuum for a suite of Mercury surface analogues for temperatures from 100°C to >400°C. The spectral library is completed by reflectance on samples fresh and post-heating (0.2 to 200 µm spectral range).

High Resolution Optical Spectroscopy of the Classical Nova V5668 Sgr Showing the Presence of Lithium

NASA Astrophysics Data System (ADS)

Wagner, R. Mark; Woodward, Charles E.; Starrfield, Sumner; Ilyin, Ilya; Strassmeier, Klaus

2018-01-01

The classical nova (CN) V5668 Sgr was discovered on 2015 March 15.634 and initial optical spectra implied it was an Fe II-class CN. We obtained high resolution optical spectroscopy on 30 nights between 2015 April 3 and 2016 June 5 with the 2 x 8.4 m Large Binocular Telescope (LBT) and the 1.8 m Vatican Advanced Technology Telescope (VATT) using the Potsdam Echelle Polarimetric Spectroscopic Instrument (PEPSI). The spectra cover all or part of the 3830-9065 Å spectral region at a spectral resolution of up to 270,000 (1 km/s); the highest resolution currently available on any 8-10 m class telescope. The early spectra are dominated by emission lines of the Balmer and Paschen series of hydrogen, Fe II, Ca II, and Na I with P Cyg-type line profiles as well as emission lines of [O I]. Numerous interstellar lines and bands are readily apparent at high spectral resolution. The permitted line profiles show complex and dramatic variations in the multi-component P Cyg-type line profiles with time. We detect a weak blue-shifted absorption line at a velocity consistent with Li I 6708 Å when compared with the line profiles of Hβ, Fe II 5169 Å, and Na I D. This line is present in spectra obtained on 7 of 8 consecutive nights up to day 21 of the outburst; but absent on day 42 when it is evident that the ionization of the ejecta has significantly increased. The equivalent width of the line converted to a column density, and the resulting mass fraction, imply a significant enrichment of 7Li in the ejecta. 7Li is produced by the decay of unstable 7Be created during the thermonuclear runaway. The discovery of the resonance lines of 7Be II in the optical spectra of the recent CNe V339 Del, V2944 Oph, and V5668 Sgr by Tajitsu et al. (2016) and its subsequent decay to 7Li (half life of 53 days) suggests a significant enrichment of 7Li in the Galaxy from CNe is possible. Our observations of the Li I 6708 Å line in the early optical spectra of V5668 Sgr mark the second direct detection of Li in a CN following the detection of Li I in the early optical spectra of V1369 Cen by Izzo et al. (2015). SS acknowledges partial support from NSF and NASA grants to ASU. CEW acknowledges support from NASA.

Luminescence properties of Eu3+ doped CdF2 single crystals

NASA Astrophysics Data System (ADS)

Boubekri, H.; Diaf, M.; Guerbous, L.; Jouart, J. P.

2018-04-01

This paper reports the photoluminescence properties of Eu3+ doped CdF2 single crystals. The pulled crystals were prepared by use of the Bridgman technique from a vacuum furnace in fluoride atmosphere. Absorption, excitation and emission spectra of the crystal doped with three Eu3+ concentrations (0.02%, 0.1% and 0.6% mol.) were recorded at room temperature. The emission spectra exhibit a strong yellow and red emissions in the spectral range 550-720 nm which are assigned to 5D0 → 7FJ (J = 1, 2, 4) transitions and a weak infrared emission around 816 nm corresponding to 5D0 → 7F6 transition. The magnetic dipole emission (5D0 → 7F1) is the most intense for each Eu3+ concentration. The Judd-Ofelt intensity parameters Ω2, Ω4, Ω6 for 4f-4f transitions of Eu3+ ions were computed from the emission spectra using the 5D0 → 7FJ (J = 1, 2, 4, 6) transitions. Via these phenomenological intensity parameters, the spontaneous emission probabilities, branching ratios, radiative lifetimes, quantum efficiencies and emission cross-sections for the main Eu3+ emitting levels are evaluated.

New Data On The Cathodoluminescence Of White Marbles: Interpretation Of Peaks And Relationships To Weathering

NASA Astrophysics Data System (ADS)

Garcia-Guinea, J.; Crespo-Feo, E.; Correcher, V.; Iordanidis, A.; Charalampides, G.; Karamitrou-Mentessidi, G.

This work focus on the Thermoluminescence (TL), the Spatially Resolved Spectral Cathodoluminescence (CL) and Raman spectroscopy (Raman) of white marble specimens collected from the archaeological park of Aiani (Greece) and from patterns of Iceland calcite and Macael marble for comparison purposes. The spectra CL were measured with a high sensitivity cathodoluminescence spectrometer MonoCL3 of Gatan (UK) attached to an FEI-ESEM microscope (CL-ESEM). The experimental set of spectra CL curves of Aiani white marbles suggest that the blue band is more resistant to weathering in comparison with the red band which drops down easily under weathering. The comparison among CL spectra of CaCO3 patterns give a slight difference between the small 330 nm peak, detected in marble and not observed in the monocrystal pattern of Iceland calcite. The Backscattering Electron Dispersed (BSED) images of the white marble are similar to the CL monochromatic plots at 330 nm which highlight the surfaces with remarkable clarity, suggesting a CL emission-defect associated to the marble crystal interfaces, such as protons or hydroxyls. Conversely, the 395 nm monochromatic mapping depicts a CL image emitting from bulk and not from interfaces attributable to point defects or cationic activators in Ca2+ positions. The blue band of the spectra luminescence of marble is composed by several peaks associated to very different types of luminescent defects. This statement is not inconsequential since in archaeological TL dating of marbles the regenerated luminescence in the blue region of the spectrum is a serious difficulty and further research on this topic is necessary.

INDOOR EMISSIONS FROM CONVERSION VARNISHES

EPA Science Inventory

Conversion varnishes are two-component, acid-catalyzed varnishes that are commonly used to finish cabinets. They are valued for their water- and stain-resistance, as well as their appearance. They have been found, however, to contribute to indoor emissions of organic compounds. F...

Temperature dependence of metal-enhanced fluorescence of photosystem I from Thermosynechococcus elongatus.

PubMed

Ashraf, Imran; Konrad, Alexander; Lokstein, Heiko; Skandary, Sepideh; Metzger, Michael; Djouda, Joseph M; Maurer, Thomas; Adam, Pierre M; Meixner, Alfred J; Brecht, Marc

2017-03-23

We report the temperature dependence of metal-enhanced fluorescence (MEF) of individual photosystem I (PSI) complexes from Thermosynechococcus elongatus (T. elongatus) coupled to gold nanoparticles (AuNPs). A strong temperature dependence of shape and intensity of the emission spectra is observed when PSI is coupled to AuNPs. For each temperature, the enhancement factor (EF) is calculated by comparing the intensity of individual AuNP-coupled PSI to the mean intensity of 'uncoupled' PSI. At cryogenic temperature (1.6 K) the average EF was 4.3-fold. Upon increasing the temperature to 250 K the EF increases to 84-fold. Single complexes show even higher EFs up to 441.0-fold. At increasing temperatures the different spectral pools of PSI from T. elongatus become distinguishable. These pools are affected differently by the plasmonic interactions and show different enhancements. The remarkable increase of the EFs is explained by a rate model including the temperature dependence of the fluorescence yield of PSI and the spectral overlap between absorption and emission spectra of AuNPs and PSI, respectively.

Miniature fiber optic spectrometer-based quantitative fluorescence resonance energy transfer measurement in single living cells.

PubMed

Chai, Liuying; Zhang, Jianwei; Zhang, Lili; Chen, Tongsheng

2015-03-01

Spectral measurement of fluorescence resonance energy transfer (FRET), spFRET, is a widely used FRET quantification method in living cells today. We set up a spectrometer-microscope platform that consists of a miniature fiber optic spectrometer and a widefield fluorescence microscope for the spectral measurement of absolute FRET efficiency (E) and acceptor-to-donor concentration ratio (R(C)) in single living cells. The microscope was used for guiding cells and the spectra were simultaneously detected by the miniature fiber optic spectrometer. Moreover, our platform has independent excitation and emission controllers, so different excitations can share the same emission channel. In addition, we developed a modified spectral FRET quantification method (mlux-FRET) for the multiple donors and multiple acceptors FRET construct (mD∼nA) sample, and we also developed a spectra-based 2-channel acceptor-sensitized FRET quantification method (spE-FRET). We implemented these modified FRET quantification methods on our platform to measure the absolute E and R(C) values of tandem constructs with different acceptor/donor stoichiometries in single living Huh-7 cells.

Thermal infrared spectroscopy and modeling of experimentally shocked basalts

USGS Publications Warehouse

Johnson, J. R.; Staid, M.I.; Kraft, M.D.

2007-01-01

New measurements of thermal infrared emission spectra (250-1400 cm-1; ???7-40 ??m) of experimentally shocked basalt and basaltic andesite (17-56 GPa) exhibit changes in spectral features with increasing pressure consistent with changes in the structure of plagioclase feldspars. Major spectral absorptions in unshocked rocks between 350-700 cm-1 (due to Si-O-Si octahedral bending vibrations) and between 1000-1250 cm-1 (due to Si-O antisymmetric stretch motions of the silica tetrahedra) transform at pressures >20-25 GPa to two broad spectral features centered near 950-1050 and 400-450 cm-1. Linear deconvolution models using spectral libraries composed of common mineral and glass spectra replicate the spectra of shocked basalt relatively well up to shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation in plagioclase. Inclusion of shocked feldspar spectra in the libraries improves fits for more highly shocked basalt. However, deconvolution models of the basaltic andesite select shocked feldspar end-members even for unshocked samples, likely caused by the higher primary glass content in the basaltic andesite sample.

Mid infrared emission spectroscopy of carbon plasma.

PubMed

Nemes, Laszlo; Brown, Ei Ei; S-C Yang, Clayton; Hommerich, Uwe

2017-01-05

Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results. Copyright © 2016 Elsevier B.V. All rights reserved.

Third harmonic from air breakdown plasma induced by nanosecond laser pulses

NASA Astrophysics Data System (ADS)

Stafe, M.; Negutu, C.; Puscas, N. N.

2018-06-01

Harmonic generation is a nonlinear optical effect consisting in frequency up-conversion of intense laser radiation when phase-matching conditions are fulfilled. Here, we study the mechanisms involved in the third harmonic (TH) generation process, the conversion efficiency, and the properties of TH radiation generated in air by focusing infrared linearly polarized nanosecond laser pulses at intensities of the order of TW/cm2. By analyzing the emission from the air breakdown plasma, we demonstrate that filamentary breakdown plasma containing molecular nitrogen ions acts as an optical nonlinear medium enabling generation of TH radiation in the axial direction. The data reveal important properties of the TH radiation: maximum conversion efficiency of 0.04%, sinc2 dependence of the TH intensity on the square root of the pump intensity, and three times smaller divergence and pulse duration of TH as compared to the pump radiation.

Mid-infrared spectra of comet nuclei

NASA Astrophysics Data System (ADS)

Kelley, Michael S. P.; Woodward, Charles E.; Gehrz, Robert D.; Reach, William T.; Harker, David E.

2017-03-01

Comet nuclei and D-type asteroids have several similarities at optical and near-IR wavelengths, including near-featureless red reflectance spectra, and low albedos. Mineral identifications based on these characteristics are fraught with degeneracies, although some general trends can be identified. In contrast, spectral emissivity features in the mid-infrared provide important compositional information that might not otherwise be achievable. Jovian Trojan D-type asteroids have emissivity features strikingly similar to comet comae, suggesting that they have the same compositions and that the surfaces of the Trojans are highly porous. However, a direct comparison between a comet and asteroid surface has not been possible due to the paucity of spectra of comet nuclei at mid-infrared wavelengths. We present 5-35 μm thermal emission spectra of comets 10P/Tempel 2, and 49P/Arend-Rigaux observed with the Infrared Spectrograph on the Spitzer Space Telescope. Our analysis reveals no evidence for a coma or tail at the time of observation, suggesting the spectra are dominated by the comet nucleus. We fit each spectrum with the near-Earth asteroid thermal model (NEATM) and find sizes in agreement with previous values. However, the NEATM beaming parameters of the nuclei, 0.74-0.83, are systematically lower than the Jupiter-family comet population mean of 1.03 ± 0.11, derived from 16- and 22-μm photometry. We suggest this may be either an artifact of the spectral reduction, or the consequence of an emissivity low near 16 μm. When the spectra are normalized by the NEATM model, a weak 10-μm silicate plateau is evident, with a shape similar to those seen in mid-infrared spectra of D-type asteroids. A silicate plateau is also evident in previously published Spitzer spectra of the nucleus of comet 9P/Tempel 1. We compare, in detail, these comet nucleus emission features to those seen in spectra of the Jovian Trojan D-types (624) Hektor, (911) Agamemnon, and (1172) Aneas, as well as those seen in the spectra of seven comet comae. The comet comae present silicate features with two distinct shapes, either trapezoidal, or more rounded, the latter apparently due to enhanced emission near 8 to 8.5 μm. The surfaces of Tempel 2, Arend-Rigaux, and Hektor best agree with the comae that present trapezoidal features, furthering the hypothesis that the surfaces of these targets must have high porosities in order to exhibit a spectrum similar to a comet coma. An emissivity minimum at 15 μm, present in the spectra of Tempel 2, Arend-Rigaux, Hektor, and Agamemnon, is also described, the origin of which remains unidentified. The compositional similarity between D-type asteroids and comets is discussed, and our data supports the hypothesis that they have similar origins in the early Solar System.

Forest carbon emissions from cropland expansion in the Brazilian Cerrado biome

NASA Astrophysics Data System (ADS)

Noojipady, Praveen; Morton, C. Douglas; Macedo, N. Marcia; Victoria, C. Daniel; Huang, Chengquan; Gibbs, K. Holly; Edson Bolfe, L.

2017-02-01

Land use, land use change, and forestry accounted for two-thirds of Brazil’s greenhouse gas emissions profile in 2005. Amazon deforestation has declined by more than 80% over the past decade, yet Brazil’s forests extend beyond the Amazon biome. Rapid expansion of cropland in the neighboring Cerrado biome has the potential to undermine climate mitigation efforts if emissions from dry forest and woodland conversion negate some of the benefits of avoided Amazon deforestation. Here, we used satellite data on cropland expansion, forest cover, and vegetation carbon stocks to estimate annual gross forest carbon emissions from cropland expansion in the Cerrado biome. Nearly half of the Cerrado met Brazil’s definition of forest cover in 2000 (≥0.5 ha with ≥10% canopy cover). In areas of established crop production, conversion of both forest and non-forest Cerrado formations for cropland declined during 2003-2013. However, forest carbon emissions from cropland expansion increased over the past decade in Matopiba, a new frontier of agricultural production that includes portions of Maranhão, Tocantins, Piauí, and Bahia states. Gross carbon emissions from cropland expansion in the Cerrado averaged 16.28 Tg C yr-1 between 2003 and 2013, with forest-to-cropland conversion accounting for 29% of emissions. The fraction of forest carbon emissions from Matopiba was much higher; between 2010-2013, large-scale cropland conversion in Matopiba contributed 45% of total Cerrado forest carbon emissions. Carbon emissions from Cerrado-to-cropland transitions offset 5%-7% of the avoided emissions from reduced Amazon deforestation rates during 2011-2013. Comprehensive national estimates of forest carbon fluxes, including all biomes, are critical to detect cross-biome leakage within countries and achieve climate mitigation targets to reduce emissions from land use, land use change, and forestry.

Rare earth-doped lead borate glasses and transparent glass-ceramics: structure-property relationship.

PubMed

Pisarski, W A; Pisarska, J; Mączka, M; Lisiecki, R; Grobelny, Ł; Goryczka, T; Dominiak-Dzik, G; Ryba-Romanowski, W

2011-08-15

Correlation between structure and optical properties of rare earth ions in lead borate glasses and glass-ceramics was evidenced by X-ray-diffraction, Raman, FT-IR and luminescence spectroscopy. The rare earths were limited to Eu(3+) and Er(3+) ions. The observed BO(3)↔BO(4) conversion strongly depends on the relative PbO/B(2)O(3) ratios in glass composition, giving important contribution to the luminescence intensities associated to (5)D(0)-(7)F(2) and (5)D(0)-(7)F(1) transitions of Eu(3+). The near-infrared luminescence and up-conversion spectra for Er(3+) ions in lead borate glasses before and after heat treatment were measured. The more intense and narrowing luminescence lines suggest partial incorporation of Er(3+) ions into the orthorhombic PbF(2) crystalline phase, which was identified using X-ray diffraction analysis. Copyright © 2010 Elsevier B.V. All rights reserved.

Spectroscopic characterisation of Er-doped LuVO4 single crystals

NASA Astrophysics Data System (ADS)

Lisiecki, R.; Dominiak-Dzik, G.; Solarz, P.; Strzęp, A.; Ryba-Romanowski, W.; Łukasiewicz, T.

2010-12-01

The LuVO4:Er single crystals were grown by the Czochralski technique. The crystal-field split energy levels of Er3+ ion were derived experimentally employing absorption and emission spectra measured at T=10 K. The Judd-Ofelt phenomenological method was used to estimate intensity parameters, radiative lifetimes and branching ratios of luminescence. The excited state dynamics of the LuVO4:Er systems was investigated and experimental lifetimes of emitting levels were measured. The emission cross section of the 4I13/2→4I15/2 transition in the infrared was calculated by the Füchtbauer-Ladenburg method. The gain cross section, estimated for several inverse-population parameters, allowed us to evaluate a potential laser activity of the LuVO4:Er system at 1.6 μm. Also, the potential range of the optical pumping was assessed based on absorption spectra achieved at the room temperature. The optical losses related to the green up-converted emission, encountered under the 978 nm excitation between 300 and 670 K were indicated and discussed. Spectroscopic peculiarities of the Er3+-doped LuVO4 crystal were discussed in relation to optical properties of the YVO4:Er and GdVO4:Er crystals. Taking into account the high quantum efficiency of the 4I13/2 level, and satisfactory absorption and emission features, the LuVO4:Er crystal can be considered as a promising active material for laser operation near 1.6 μm.

Dual emissive manganese and copper Co-doped Zn-In-S quantum dots as a single color-converter for high color rendering white-light-emitting diodes.

PubMed

Yuan, Xi; Ma, Ruixin; Zhang, Wenjin; Hua, Jie; Meng, Xiangdong; Zhong, Xinhua; Zhang, Jiahua; Zhao, Jialong; Li, Haibo

2015-04-29

Novel white light emitting diodes (LEDs) with environmentally friendly dual emissive quantum dots (QDs) as single color-converters are one of the most promising high-quality solid-state lighting sources for meeting the growing global demand for resource sustainability. A facile method was developed for the synthesis of the bright green-red-emitting Mn and Cu codoped Zn-In-S QDs with an absorption bangdgap of 2.56 eV (485 nm), a large Stokes shift of 150 nm, and high emission quantum yield up to 75%, which were suitable for warm white LEDs based on blue GaN chips. The wide photoluminescence (PL) spectra composed of Cu-related green and Mn-related red emissions in the codoped QDs could be controlled by varying the doping concentrations of Mn and Cu ions. The energy transfer processes in Mn and Cu codoped QDs were proposed on the basis of the changes in PL intensity and lifetime measured by means of steady-state and time-resolved PL spectra. By integrating these bicolor QDs with commercial GaN-based blue LEDs, the as-fabricated tricolor white LEDs showed bright natural white light with a color rendering index of 95, luminous efficacy of 73.2 lm/W, and color temperature of 5092 K. These results indicated that (Mn,Cu):Zn-In-S/ZnS QDs could be used as a single color-converting material for the next generation of solid-state lighting.

Competition of the self-activated and Mn-related luminescence in ZnS single crystals

NASA Astrophysics Data System (ADS)

Bacherikov, Yu. Yu.; Vorona, I. P.; Markevich, I. V.; Korsunska, N. O.; Kurichka, R. V.

2018-06-01

The photoluminescence (PL) and photoluminescence excitation (PLE) spectra of ZnS single crystals thermally doped from ZnS/MnS mixture were studied at 300 and 77 K. PL spectra exhibit bands caused by Mn-related centers and centers of self-activated (SA) emission. Besides intrinsic maximum, a number of narrow peaks corresponded to Mn-related absorption are found in the PLE spectra of both SA and Mn-related emission. A redistribution of SA and Mn-related emission intensities is observed with temperature change. The mechanism of this phenomenon involving free hole trapping by MnZn and the possible position of a ground energy level of substitutional Mn are discussed.

Coronal Abundances In Xi Boo A, Abundances in the Corona of FK Aqr and the Origin of Cosmic Ray

NASA Technical Reports Server (NTRS)

Drake, Jeremy; Oliversen, Ronald J. (Technical Monitor)

2002-01-01

Both Xi Boo A and FK Agr observations have been acquired, reduced and analysed. The results of the Xi Boo A study were published in ApJ (Drake, J.J., Kashyap, V., 2001, Up, 547, 428). Work is ongoing to determine the coronet metallicity of FK Aqr based on EUVE spectra and DO photometer data, using the techniques developed in the Drake & Kashyap paper. Preliminary synthetic spectra for FK Aqr have been developed, and further work to heap define the hot plasma emission measure distribution is underway. Progress on spectral analysis has been hampered following the post-doctoral scientist, Vinay Kashyap, taking up new position. A suitable replacement has been difficult to find, but new hire is expected shortly. However, good progress has been made on analysis of DO photometric variations in FK Age, with a publication now ready (Kashyap, V., Drake, J.J., Guedel, M., Audard, M.) for submission to a mainstream astrophysical journal.

X-shooter spectroscopy of young stellar objects. III. Photospheric and chromospheric properties of Class III objects

NASA Astrophysics Data System (ADS)

Stelzer, B.; Frasca, A.; Alcalá, J. M.; Manara, C. F.; Biazzo, K.; Covino, E.; Rigliaco, E.; Testi, L.; Covino, S.; D'Elia, V.

2013-10-01

Context. Traditionally, the chromospheres of late-type stars are studied through their strongest emission lines, Hα and Ca ii HK emission. Our knowledge on the whole emission line spectrum is more elusive as a result of the limited spectral range and sensitivity of most available spectrographs. Aims: We intend to reduce this gap with a comprehensive spectroscopic study of the chromospheric emission line spectrum of a sample of non-accreting pre-main sequence stars (Class III sources). Methods: We analyzed X-shooter/VLT spectra of 24 Class III sources from three nearby star-forming regions (σ Orionis, Lupus III, and TW Hya). We determined the effective temperature, surface gravity, rotational velocity, and radial velocity by comparing the observed spectra with synthetic BT-Settl model spectra. We investigated in detail the emission lines emerging from the stellar chromospheres and combined these data with archival X-ray data to allow for a comparison between chromospheric and coronal emissions. Results: For some objects in the sample the atmospheric and kinematic parameters are presented here for the first time. The effective temperatures are consistent with those derived for the same stars from an empirical calibration with spectral types. Small differences in the surface gravity found between the stars can be attributed to differences in the average age of the three star-forming regions. The strength of lithium absorption and radial velocities confirm the young age of all but one object in the sample (Sz 94). Both X-ray and Hα luminosity as measured in terms of the bolometric luminosity are independent of the effective temperature for early-M stars but decline toward the end of the spectral M sequence. For the saturated early-M stars the average emission level is almost one dex higher for X-rays than for Hα: log (Lx/Lbol) = -2.85 ± 0.36 vs. log (LHα/Lbol) = -3.72 ± 0.21. When all chromospheric emission lines (including the Balmer series up to H11, Ca ii HK, the Ca ii infrared triplet, and several He i lines) are summed up the coronal flux still dominates that of the chromosphere, typically by a factor 2-5. Flux-flux relations between activity diagnostics that probe different atmospheric layers (from the lower chromosphere to the corona) separate our sample of active pre-main sequence stars from the bulk of field M dwarfs studied in the literature. Flux ratios between individual optical emission lines show a smooth dependence on the effective temperature. The Balmer decrements can roughly be reproduced by an NLTE radiative transfer model devised for another young star of similar age. Future, more complete chromospheric model grids can be tested against this data set. Based on observations collected at the Very Large Telescope of the European Southern Observatory under programs 084.C-0269, 085.C-0238, 086.C-0173, 087.C-0244, and 089.C-0143.Tables 2-4 are available in electronic form at http://www.aanda.org

Atmospheric pressure resistive barrier air plasma jet induced bacterial inactivation in aqueous environment

NASA Astrophysics Data System (ADS)

Thiyagarajan, Magesh; Sarani, Abdollah; Gonzales, Xavier

2013-03-01

An atmospheric pressure resistive barrier air plasma jet is designed to inactivate bacteria in aqueous media in direct and indirect exposure modes of treatment. The resistive barrier plasma jet is designed to operate at both dc and standard 50-60 Hz low frequency ac power input and the ambient air at 50% humidity level was used as the operating gas. The voltage-current characteristics of the plasma jet were analyzed and the operating frequency of the discharge was measured to be 20 kHz and the plasma power was measured to be 26 W. The plasma jet rotational temperatures (Trot) are obtained from the optical emission spectra, from the N2C-B(2+) transitions by matching the experimental spectrum results with the Spectra Air (SPECAIR) simulation spectra. The reactive oxygen and nitrogen species were measured using optical emission spectroscopy and gas analyzers, for direct and indirect treatment modes. The nitric oxides (NO) were observed to be the predominant long lived reactive nitrogen species produced by the plasma. Three different bacteria including Staphylococcus aureus (Gram-positive), Escherichia coli (Gram-negative), and Neisseria meningitidis (Gram-negative) were suspended in an aqueous media and treated by the resistive barrier air plasma jet in direct and indirect exposure modes. The results show that a near complete bacterial inactivation was achieved within 120 s for both direct and indirect plasma treatment of S. aureus and E. coli bacteria. Conversely, a partial inactivation of N. meningitidis was observed by 120 s direct plasma exposure and insignificant inactivation was observed for the indirect plasma exposure treatment. Plasma induced shifts in N. meningitidis gene expression was analyzed using pilC gene expression as a representative gene and the results showed a reduction in the expression of the pilC gene compared to untreated samples suggesting that the observed protection against NO may be regulated by other genes.

Blinded by the light: on the relationship between CO first overtone emission and mass accretion rate in massive young stellar objects

NASA Astrophysics Data System (ADS)

Ilee, J. D.; Oudmaijer, R. D.; Wheelwright, H. E.; Pomohaci, R.

2018-07-01

To date, there is no explanation as to why disc-tracing CO first overtone (or `bandhead') emission is not a ubiquitous feature in low- to medium-resolution spectra of massive young stellar objects (MYSOs), but instead is only detected towards approximately 25 per cent of their spectra. In this paper, we investigate the hypothesis that only certain mass accretion rates result in detectable bandhead emission in the near-infrared spectra of MYSOs. Using an analytic disc model combined with an LTE model of the CO emission, we find that high accretion rates (≳10-4 M⊙ yr-1) result in large dust sublimation radii, a larger contribution to the K-band continuum from hot dust at the dust sublimation radius, and therefore correspondingly lower CO emission with respect to the continuum. On the other hand, low accretion rates (≲10-6 M⊙ yr-1) result in smaller dust sublimation radii, a correspondingly smaller emitting area of CO, and thus also lower CO emission with respect to the continuum. In general, moderate accretion rates produce the most prominent, and therefore detectable, CO first overtone emission. We compare our findings to a recent near-infrared spectroscopic survey of MYSOs, finding results consistent with our hypothesis. We conclude that the detection rate of CO bandhead emission in the spectra of MYSOs could be the result of MYSOs exhibiting a range of mass accretion rates, perhaps due to the variable accretion suggested by recent multi-epoch observations of these objects.

Blinded by the light: on the relationship between CO first overtone emission and mass accretion rate in massive young stellar objects

NASA Astrophysics Data System (ADS)

Ilee, J. D.; Oudmaijer, R. D.; Wheelwright, H. E.; Pomohaci, R.

2018-04-01

To date, there is no explanation as to why disc-tracing CO first overtone (or `bandhead') emission is not a ubiquitous feature in low- to medium-resolution spectra of massive young stellar objects, but instead is only detected toward approximately 25 per cent of their spectra. In this paper, we investigate the hypothesis that only certain mass accretion rates result in detectable bandhead emission in the near infrared spectra of MYSOs. Using an analytic disc model combined with an LTE model of the CO emission, we find that high accretion rates (≳ 10-4 M⊙yr-1) result in large dust sublimation radii, a larger contribution to the K-band continuum from hot dust at the dust sublimation radius, and therefore correspondingly lower CO emission with respect to the continuum. On the other hand, low accretion rates (≲ 10-6 M⊙yr-1) result in smaller dust sublimation radii, a correspondingly smaller emitting area of CO, and thus also lower CO emission with respect to the continuum. In general, moderate accretion rates produce the most prominent, and therefore detectable, CO first overtone emission. We compare our findings to a recent near-infrared spectroscopic survey of MYSOs, finding results consistent with our hypothesis. We conclude that the detection rate of CO bandhead emission in the spectra of MYSOs could be the result of MYSOs exhibiting a range of mass accretion rates, perhaps due to the variable accretion suggested by recent multi-epoch observations of these objects.

Analysis of soft x-ray emission spectra of laser-produced dysprosium, erbium and thulium plasmas

NASA Astrophysics Data System (ADS)

Sheil, John; Dunne, Padraig; Higashiguchi, Takeshi; Kos, Domagoj; Long, Elaine; Miyazaki, Takanori; O'Reilly, Fergal; O'Sullivan, Gerard; Sheridan, Paul; Suzuki, Chihiro; Sokell, Emma; White, Elgiva; Kilbane, Deirdre

2017-03-01

Soft x-ray emission spectra of dysprosium, erbium and thulium ions created in laser-produced plasmas were recorded with a flat-field grazing-incidence spectrometer in the 2.5-8 nm spectral range. The ions were produced using an Nd:YAG laser of 7 ns pulse duration and the spectra were recorded at various power densities. The experimental spectra were interpreted with the aid of the Cowan suite of atomic structure codes and the flexible atomic code. At wavelengths above 5.5 nm the spectra are dominated by overlapping n = 4 - n = 4 unresolved transition arrays from adjacent ion stages. Below 6 nm, n = 4 - n = 5 transitions also give rise to a series of interesting overlapping spectral features.

Two-dimensional correlation and codistribution spectroscopy (2DCOS and 2DCDS) analyses of time-dependent ATR IR spectra of D-glucose anomers undergoing mutarotation process in water

NASA Astrophysics Data System (ADS)

Noda, Isao

2018-05-01

Two cyclic diastereoisomeric structures, known as α- and β-anomers of D-glucose with different configurations around C1 with OH groups in axial or equitroial positions, undergo the mutarotation conversion to each other in water. Two-dimensional correlation and codistribution spectroscopy (2DCOS and 2DCDS) analyses were applied to the time-dependent ATR IR spectra of aqueous solutions of α- and β-D-glucose undergoing such mutarotation conversion. 2DCOS analysis reveals that the increase and decrease in the IR intensities after the dissolution of α- or β-D-glucose are not fully synchronized, suggesting the mutarotation of D-glucose in water is not a simple binary conversion process but a multi-step reaction involving an intermediate species with a finite and observable concentration level and lifetime. 2DCDS analysis of the time-dependent ATR IR spectra clearly demonstrated the presence of intermediate species contributing to the band positions overlapped close to bands for α- and β-D-glucose. The fact that band positions identified for the intermediate species for α- to β-D-glucose conversion are the same for the reverse reaction suggests that they arise from the same species, most likely the open-ring structure produced by the hydrolysis.

Investigation on photoluminescence emission of (reduced) graphene oxide paper

NASA Astrophysics Data System (ADS)

Ding, J. J.; Chen, H. X.; Feng, D. Q.; Fu, H. W.

2018-01-01

In order to contrastively investigate optical properties of graphene oxide (GO) and reduced graphene oxide (rGO) paper, GO is prepared by improved Hummer method and controlled reduced using hydration hydrazine to obtain good dispersive rGO in organic solvent. Finally, GO and rGO paper are obtained by vacuum filtration method. Samples morphology and optical properties are analyzed by scanning electron microscopy (SEM) images, Raman spectra, absorbance spectra and photoluminescence (PL) spectra. Results indicate that there are large numbers of localized states in both GO and rGO paper, and optical gaps of two samples are 0.62 eV. In PL spectra of GO paper, we observe three emission peaks at 565, 578 and 608 nm, respectively whose intensity decreases evidently after reduced, which is due to the decrease of oxide functionalized groups and expansion of sp2 clusters. PL emission will gradually decrease during GO are reduced.

Theoretical studies on absorption, emission, and resonance Raman spectra of Coumarin 343 isomers

NASA Astrophysics Data System (ADS)

Wu, Wenpeng; Cao, Zexing; Zhao, Yi

2012-03-01

The vibrationally resolved spectral method and quantum chemical calculations are employed to reveal the structural and spectral properties of Coumarin 343 (C343), an ideal candidate for organic dye photosensitizers, in vacuum and solution. The results manifest that the ground-state energies are dominantly determined by different placements of hydrogen atom in carboxylic group of C343 conformations. Compared to those in vacuum, the electronic absorption spectra in methanol solvent show a hyperchromic property together with the redshift and blueshift for the neutral C343 isomers and their deprotonated anions, respectively. From the absorption, emission, and resonance Raman spectra, it is found that the maximal absorption and emission come from low-frequency modes whereas the high-frequency modes have high Raman activities. The detailed spectra are further analyzed for the identification of the conformers and understanding the potential charge transfer mechanism in their photovoltaic applications.

Fourier spectroscopy of the stratospheric emission

NASA Technical Reports Server (NTRS)

Carli, B.; Mencaraglia, F.; Bonetti, A.

1980-01-01

Stratospheric emission spectra in the submillimeter range have been recorded with a resolution of 0.0033/cm with a balloon-borne interferometer. Several minor atmospheric constituents have been identified in a preliminary analysis of the spectra; these are water vapor, oxygen, ozone isotopes, nitric acid, nitrous oxide, hydrofluoric and hydrochloric acids, and carbon monoxide.

Discernment of lint trash in raw cotton using multivariate analysis of excitation-emission luminescence spectra

USDA-ARS?s Scientific Manuscript database

Excitation-Emission luminescence spectra of basic (pH 12.5) phosphate buffer solution extracts were used to distinguish among botanical components of trash within seed cotton. All components were separated from whole plants removed from a field in southern New Mexico. Unfolded Principal Component An...

Are TiC Grains a Carrier of the 21 Micron Emission Band Observed around Post-Asymptotic Giant Branch Objects?

NASA Astrophysics Data System (ADS)

Chigai, Takeshi; Yamamoto, Tetsuo; Kaito, Chihiro; Kimura, Yuki

2003-04-01

The carrier of the 21 μm band observed in post-asymptotic giant branch (post-AGB) stars is examined. We analyze the infrared spectra of the TiC clusters measured by von Helden et al. in 2000 and determine the absorption efficiency Q in the 21 μm band. Using Q, we estimate the Ti/Si abundance ratios needed to realize the flux ratios of the 21 and 11 μm emission observed in the infrared spectra of the post-AGB stars exhibiting both 21 and 11 μm emission. In view of the nature of the TiC condensation by which TiC grains are quickly mantled by graphite, we calculate the emission spectra of the graphite-coated TiC grains and other possible types of core-mantle grains and compare with the observed spectra. Both the abundance and condensation considerations strongly suggest that TiC is an implausible carrier of the observed infrared 21 μm feature around carbon-rich post-AGB stars.

DFT study of electron absorption and emission spectra of pyramidal LnPc(OAc) complexes of some lanthanide ions in the solid state

NASA Astrophysics Data System (ADS)

Hanuza, J.; Godlewska, P.; Lisiecki, R.; Ryba-Romanowski, W.; Kadłubański, P.; Lorenc, J.; Łukowiak, A.; Macalik, L.; Gerasymchuk, Yu.; Legendziewicz, J.

2018-05-01

The electron absorption and emission spectra were measured for the pyramidal LnPc(OAc) complexes in the solid state and co-doped in silica glass, where Ln = Er, Eu and Ho. The theoretical electron spectra were determined from the quantum chemical DFT calculation using four approximations CAM-B3LYP/LANL2DZ, CAM-B3LYP/CC-PVDZ, B3LYP/LANL2DZ and B3LYP/CC-PVDZ. It was shown that the best agreement between the calculated and experimental structural parameters and spectroscopic data was reached for the CAM-B3LYP/LANL2DZ model. The emission spectra were measured using the excitations both in the ligand and lanthanide absorption ranges. The possibility of energy transfer between the phthalocyanine ligand and excited states of lanthanide ions was discussed. It was shown that the back energy transfer from metal states to phthalocyanine state is responsible for the observed emission of the studied complexes both in the polycrystalline state and silica glass.

Gamma-Ray Burst Spectral Indices: Evidence for Deceleration of Synchrotron Shocks

NASA Technical Reports Server (NTRS)

Preece, R. D.; Briggs, M. S.; Giblin, T.; Mallozzi, R. S.; Pendleton, G. N.; Paciesas, W. S.; Band, D. L.

2000-01-01

The current scenario for gamma-ray bursts (GRBs) involves internal shocks for the prompt GRB emission phase and external shocks for the afterglow phase. Assuming synchrotron emission from energetic shocked electrons. GRB spectra observed with a low-energy power-law spectral index greater than -2/3 (for positive photon number indices E(sup alpha) indicate a problem with this model. The remaining spectra can test the synchrotron shock model prediction that the emission from a single distribution of electrons, cooling rapidly, is responsible for both the low-energy and high-energy power-low portions of the spectra. We find that the inferred relationship between the two spectral indices of observed GRB spectra is inconsistent with the constraints from the model, posing another problem for the synchrotron shock emission model. To overcome this problem, we describe a model where the average of -1, rather than the value of -3/2 predicted for cooling electrons. Situations where this might arise have been discussed in other contexts, and involve deceleration of the internal shocks during the GRB phase.

DFT study of electron absorption and emission spectra of pyramidal LnPc(OAc) complexes of some lanthanide ions in the solid state.

PubMed

Hanuza, J; Godlewska, P; Lisiecki, R; Ryba-Romanowski, W; Kadłubański, P; Lorenc, J; Łukowiak, A; Macalik, L; Gerasymchuk, Yu; Legendziewicz, J

2018-05-05

The electron absorption and emission spectra were measured for the pyramidal LnPc(OAc) complexes in the solid state and co-doped in silica glass, where Ln=Er, Eu and Ho. The theoretical electron spectra were determined from the quantum chemical DFT calculation using four approximations CAM-B3LYP/LANL2DZ, CAM-B3LYP/CC-PVDZ, B3LYP/LANL2DZ and B3LYP/CC-PVDZ. It was shown that the best agreement between the calculated and experimental structural parameters and spectroscopic data was reached for the CAM-B3LYP/LANL2DZ model. The emission spectra were measured using the excitations both in the ligand and lanthanide absorption ranges. The possibility of energy transfer between the phthalocyanine ligand and excited states of lanthanide ions was discussed. It was shown that the back energy transfer from metal states to phthalocyanine state is responsible for the observed emission of the studied complexes both in the polycrystalline state and silica glass. Copyright © 2018. Published by Elsevier B.V.

Fieldable computer system for determining gamma-ray pulse-height distributions, flux spectra, and dose rates from Little Boy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moss, C.E.; Lucas, M.C.; Tisinger, E.W.

1984-01-01

Our system consists of a LeCroy 3500 data acquisition system with a built-in CAMAC crate and eight bismuth-germanate detectors 7.62 cm in diameter and 7.62 cm long. Gamma-ray pulse-height distributions are acquired simultaneously for up to eight positions. The system was very carefully calibrated and characterized from 0.1 to 8.3 MeV using gamma-ray spectra from a variety of radioactive sources. By fitting the pulse-height distributions from the sources with a function containing 17 parameters, we determined theoretical repsonse functions. We use these response functions to unfold the distributions to obtain flux spectra. A flux-to-dose-rate conversion curve based on the workmore » of Dimbylow and Francis is then used to obtain dose rates. Direct use of measured spectra and flux-to-dose-rate curves to obtain dose rates avoids the errors that can arise from spectrum dependence in simple gamma-ray dosimeter instruments. We present some gamma-ray doses for the Little Boy assembly operated at low power. These results can be used to determine the exposures of the Hiroshima survivors and thus aid in the establishment of radation exposure limits for the nuclear industry.« less

Complex organic matter in space: about the chemical composition of carriers of the Unidentified Infrared Bands (UIBs) and protoplanetary emission spectra recorded from certain astrophysical objects.

PubMed

Cataldo, Franco; Keheyan, Yeghis; Heymann, Dieter

2004-02-01

In this communication we present the basic concept that the pure PAHs (Polycyclic Aromatic Hydrocarbons) can be considered only the ideal carriers of the UIBs (Unidentified Infrared Bands), the emission spectra coming from a large variety of astronomical objects. Instead we have proposed that the carriers of UIBs and of protoplanetary nebulae (PPNe) emission spectra are much more complex molecular mixtures possessing also complex chemical structures comparable to certain petroleum fractions obtained from the petroleum refining processes. The demonstration of our proposal is based on the comparison between the emission spectra recorded from the protoplanetary nebulae (PPNe) IRAS 22272+ 5435 and the infrared absorption spectra of certain 'heavy' petroleum fractions. It is shown that the best match with the reference spectrum is achieved by highly aromatic petroleum fractions. It is shown that the selected petroleum fractions used in the present study are able to match the band pattern of anthracite coal. Coal has been proposed previously as a model for the PPNe and UIBs but presents some drawbacks which could be overcome by adopting the petroleum fractions as model for PPNe and UIBs in place of coal. A brief discussion on the formation of the petroleum-like fractions in PPNe objects is included.

Cassini/CIRS Observations of Water Vapor in Saturn's Stratosphere

NASA Technical Reports Server (NTRS)

Bjoraker, Gordon; Achterberg, R. K.; Simon-Miller, A. A.; Jennings, D. E.

2010-01-01

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2001. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory [1] and subsequently confirmed by the Submillimeter Wave Astronomy Satellite [2], CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. long integrations at the full 0.5/cm spectral resolution were performed at targeted latitudes on Saturn. High emission angles were chosen to enhance stratospheric emission. Over the course of the prime and extended mission a set of observations has been built up spaced roughly every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v'4 band centered at 1501/cm. The origin of water vapor is believed to be from the ablation of micrometeorites containing eater ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney [3] proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al [4] interpreted a minimum in the abundance of acetylene from ultraviolet spectra gear 41S on Saturn as possibly due to an enhanced influx of water. We will be able to test the "ring rain" mechanism by searching, for localized water vapor enhancement at mid-latitudes. Our results may be used to constrain photochemical models of Saturn's stratosphere [5].

HERSCHEL/SPIRE SUBMILLIMETER SPECTRA OF LOCAL ACTIVE GALAXIES {sup ,}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pereira-Santaella, Miguel; Spinoglio, Luigi; Busquet, Gemma

2013-05-01

We present the submillimeter spectra from 450 to 1550 GHz of 11 nearby active galaxies observed with the SPIRE Fourier Transform Spectrometer (SPIRE/FTS) on board Herschel. We detect CO transitions from J{sub up} = 4 to 12, as well as the two [C I] fine structure lines at 492 and 809 GHz and the [N II]1461 GHz line. We used radiative transfer models to analyze the observed CO spectral line energy distributions. The FTS CO data were complemented with ground-based observations of the low-J CO lines. We found that the warm molecular gas traced by the mid-J CO transitions hasmore » similar physical conditions (n{sub H{sub 2}}{approx} 10{sup 3.2}-10{sup 3.9} cm{sup -3} and T{sub kin} {approx} 300-800 K) in most of our galaxies. Furthermore, we found that this warm gas is likely producing the mid-IR rotational H{sub 2} emission. We could not determine the specific heating mechanism of the warm gas, however, it is possibly related to the star formation activity in these galaxies. Our modeling of the [C I] emission suggests that it is produced in cold (T{sub kin} < 30 K) and dense (n{sub H{sub 2}}>10{sup 3} cm{sup -3}) molecular gas. Transitions of other molecules are often detected in our SPIRE/FTS spectra. The HF J = 1-0 transition at 1232 GHz is detected in absorption in UGC 05101 and in emission in NGC 7130. In the latter, near-infrared pumping, chemical pumping, or collisional excitation with electrons are plausible excitation mechanisms likely related to the active galactic nucleus of this galaxy. In some galaxies, few H{sub 2}O emission lines are present. Additionally, three OH{sup +} lines at 909, 971, and 1033 GHz are identified in NGC 7130.« less

Analysis of waste electrical and electronic equipment (WEEE) using laser induced breakdown spectroscopy (LIBS) and multivariate analysis.

PubMed

Ángel Aguirre, Miguel; Hidalgo, Montserrat; Canals, Antonio; Nóbrega, Joaquim A; Pereira-Filho, Edenir R

2013-12-15

This study shows the application of laser induced breakdown spectroscopy (LIBS) for waste electrical and electronic equipment (WEEE) investigation. Several emission spectra were obtained for 7 different mobiles from 4 different manufacturers. Using the emission spectra of the black components it was possible to see some differences among the manufacturers and some emission lines from organic elements and molecules (N, O, CN and C2) led to the highest contribution for this differentiation. Some polymeric internal parts in contact with the inner pieces of the mobiles and covered with a special paint presented a strong emission signal for Cr. The white pieces presented mainly Al, Ba and Ti in their composition. Finally, this study developed a procedure for LIBS emission spectra using chemometric strategies and suitable information can be obtained for identification of manufacturer and counterfeit products. In addition, the results obtained can improve the classification for establishing recycling strategies of e-waste. © 2013 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurgalin, S. D.; Tchuvil’sky, Yu. M., E-mail: tchuvl@nucl-th.sinp.msu.ru; Churakova, T. A.

A universal theoretical model intended for calculating internal-bremsstrahlung spectra is proposed. In this model, which can be applied to describing nuclear decays of various type (such as alpha decay, cluster decay, and proton emission), use is made of realistic nucleus–nucleus potentials. Theoretical internal-bremsstrahlung spectra were obtained for the alpha decay of the {sup 214}Po nucleus, as well as for the decay of the {sup 222}Ra nucleus via the emission of a {sup 14}C cluster and for the decay of the {sup 113}Cs nucleus via proton emission, and the properties of these spectra were studied. The contributions of various regions (internal,more » subbarrier, and external) to the internal-bremsstrahlung amplitude were analyzed in detail. It is shown that the contribution of the internal region to the amplitude for internal bremsstrahlung generated in nuclear decay via proton emission is quite large, but that this is not so for alpha decay and decay via cluster emission. Thus, a process in which strong interaction of nuclear particles affects the internal-bremsstrahlung spectrum if found.« less

Infrared emission spectra of candidate interstellar aromatic molecules

NASA Technical Reports Server (NTRS)

Schlemmer, S.; Balucani, N.; Wagner, D. R.; Steiner, B.; Saykally, R. J.

1996-01-01

Interstellar dust is responsible, through surface reactions, for the creation of molecular hydrogen, the main component of the interstellar clouds in which new stars form. Intermediate between small, gas-phase molecules and dust are the polycyclic aromatic hydrocarbons (PAHs). Such molecules could account for 2-30% of the carbon in the Galaxy, and may provide nucleation sites for the formation of carbonaceous dust. Although PAHs have been proposed as the sources of the unidentified infrared emission bands that are observed in the spectra of a variety of interstellar sources, the emission characteristics of such molecules are still poorly understood. Here we report laboratory emission spectra of several representative PAHs, obtained in conditions approximating those of the interstellar medium, and measured over the entire spectral region spanned by the unidentified infrared bands. We find that neutral PAHs of small and moderate size can at best make only a minor contribution to these emission bands. Cations of these molecules, as well as much larger PAHs and their cations, remain viable candidates for the sources of these bands.

New Chandra observations of the jet in 3C273. 1. Softer X-ray than radio spectra and the X-ray emission mechanism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jester, Sebastian; /Fermilab; Harris, D.E.

2006-05-01

The jet in 3C273 is a high-power quasar jet with radio, optical and X-ray emission whose size and brightness allow a detailed study of the emission processes acting in it. We present deep Chandra observations of this jet and analyze the spectral properties of the jet emission from radio through X-rays. We find that the X-ray spectra are significantly softer than the radio spectra in all regions of the bright part of the jet except for the first bright ''knot A'', ruling out a model in which the X-ray emission from the entire jet arises from beamed inverse-Compton scattering ofmore » cosmic microwave background photons in a single-zone jet flow. Within two-zone jet models, we find that a synchrotron origin for the jet's X-rays requires fewer additional assumptions than an inverse-Compton model, especially if velocity shear leads to efficient particle acceleration in jet flows.« less

Outer atmospheres of cool stars. XII - A survey of IUE ultraviolet emission line spectra of cool dwarf stars

NASA Technical Reports Server (NTRS)

Linsky, J. L.; Bornmann, P. L.; Carpenter, K. G.; Hege, E. K.; Wing, R. F.; Giampapa, M. S.; Worden, S. P.

1982-01-01

Quantitative information is obtained on the chromospheres and transition regions of M dwarf stars, in order to determine how the outer atmospheres of dMe stars differ from dM stars and how they compare with the outer atmospheres of quiet and active G and K type dwarfs. IUE spectra of six dMe and four dM stars, together with ground-based photometry and spectroscopy of the Balmer and Ca II H and K lines, show no evidence of flares. It is concluded, regarding the quiescent behavior of these stars, that emission-line spectra resemble that of the sun and contain emission lines formed in regions with 4000-20,000 K temperatures that are presumably analogous to the solar chromosphere, as well as regions with temperatures of 20,000-200,000 K that are presumably analogous to the solar transition region. Emission-line surface fluxes are proportional to the emission measure over the range of temperatures at which the lines are formed.

Estimating global "blue carbon" emissions from conversion and degradation of vegetated coastal ecosystems.

PubMed

Pendleton, Linwood; Donato, Daniel C; Murray, Brian C; Crooks, Stephen; Jenkins, W Aaron; Sifleet, Samantha; Craft, Christopher; Fourqurean, James W; Kauffman, J Boone; Marbà, Núria; Megonigal, Patrick; Pidgeon, Emily; Herr, Dorothee; Gordon, David; Baldera, Alexis

2012-01-01

Recent attention has focused on the high rates of annual carbon sequestration in vegetated coastal ecosystems--marshes, mangroves, and seagrasses--that may be lost with habitat destruction ('conversion'). Relatively unappreciated, however, is that conversion of these coastal ecosystems also impacts very large pools of previously-sequestered carbon. Residing mostly in sediments, this 'blue carbon' can be released to the atmosphere when these ecosystems are converted or degraded. Here we provide the first global estimates of this impact and evaluate its economic implications. Combining the best available data on global area, land-use conversion rates, and near-surface carbon stocks in each of the three ecosystems, using an uncertainty-propagation approach, we estimate that 0.15-1.02 Pg (billion tons) of carbon dioxide are being released annually, several times higher than previous estimates that account only for lost sequestration. These emissions are equivalent to 3-19% of those from deforestation globally, and result in economic damages of $US 6-42 billion annually. The largest sources of uncertainty in these estimates stems from limited certitude in global area and rates of land-use conversion, but research is also needed on the fates of ecosystem carbon upon conversion. Currently, carbon emissions from the conversion of vegetated coastal ecosystems are not included in emissions accounting or carbon market protocols, but this analysis suggests they may be disproportionally important to both. Although the relevant science supporting these initial estimates will need to be refined in coming years, it is clear that policies encouraging the sustainable management of coastal ecosystems could significantly reduce carbon emissions from the land-use sector, in addition to sustaining the well-recognized ecosystem services of coastal habitats.

Triggered lightning spectroscopy: Part 1. A qualitative analysis

NASA Astrophysics Data System (ADS)

Walker, T. Daniel; Christian, Hugh J.

2017-08-01

The first high-speed spectra of triggered lightning have been obtained. During the summers of 2012 and 2013, spectra were recorded at the International Center for Lightning Research and Testing, Camp Blanding, FL. The spectra were recorded with a high-speed camera with a grism mounted in front of it. The triggered lightning channels observed were generally at low altitude in a region that included the copper wire. Spectral emissions were recorded at each phase: the initial stage, dart leader, return stroke, and continuing current. These spectra are separated into two major regions: soft ultraviolet to visible (3800-6200 Å) and visible to near infrared (6200-8700 Å). The emissions during the initial stage reflect those of a copper wire burn in air. The majority of the emissions are neutral copper. After the initial stage comes the first return stroke which contains no detected molecular emissions; however, it does contain neutral, singly, and doubly ionized nitrogen and oxygen, neutral argon, and neutral hydrogen. Occasionally, before a return stroke, the dart leader coming down the channel will be stepped. During these occasions the leader spectra resemble that of the return stroke but are dimmer and shorter lived. After the initial portion of the return stroke, there are often changes in the luminosity of the spectrum which corresponds with fluctuations in the continuing current. During these "reillumination phases" no singly or doubly ionized lines have been observed to reemerge over the detection threshold, only neutral emission features.

The Infrared Spectra of Polycyclic Aromatic Hydrocarbons with Excess Peripheral H Atoms (Hn-PAHs) and their Relation to the 3.4 and 6.9 µm PAH Emission Features

PubMed Central

Sandford, Scott A.; Bernstein, Max P.; Materese, Christopher K.

2015-01-01

Polycyclic aromatic hydrocarbons (PAHs) are likely responsible for the family of infrared emission features seen in a wide variety of astrophysical environments. A potentially important subclass of these materials are PAHs whose edges contain excess H atoms (Hn-PAHs). This type of compound may be present in space, but it has been difficult to assess this possibility because of a lack of suitable laboratory spectra to assist with analysis of astronomical data. We present 4000-500 cm−1 (2.5–20 µm) infrared spectra of 23 Hn-PAHs and related molecules isolated in argon matrices under conditions suitable for interpretation of astronomical data. Spectra of molecules with mixed aromatic and aliphatic domains show characteristics that distinguish them from fully aromatic PAH equivalents. Two major changes occur as PAHs become more hydrogenated: (1) aromatic C-H stretching bands near 3.3 µm weaken and are replaced with stronger aliphatic bands near 3.4 µm, and (2) aromatic C-H out-of-plane bending mode bands in the 11–15 µm region shift and weaken concurrent with growth of a strong aliphatic -CH2-deformation mode near 6.9 µm. Implications for interpreting astronomical spectra are discussed with emphasis on the 3.4 and 6.9 µm features. Laboratory data is compared with emission spectra from IRAS 21282+5050, an object with normal PAH emission features, and IRAS 22272+5435 and IRAS 0496+3429, two protoplanetary nebulae with abnormally large 3.4 µm features. We show that ‘normal’ PAH emission objects contain relatively few Hn-PAHs in their emitter populations, but less evolved protoplanetary nebulae may contain significant abundances of these molecules. PMID:26435553

Down- and up-conversion emissions in Er-doped transparent fluorotellurite glass-ceramics

NASA Astrophysics Data System (ADS)

Miguel, A.; Morea, R.; Gonzalo, J.; Fernandez, J.; Balda, R.

2015-03-01

In this work, we report the near infrared and upconversion emissions of Er3+-doped transparent fluorotellurite glassceramics obtained by heat treatment of the precursor Er-doped TeO2-ZnO-ZnF2 glass. Structural analysis shows that ErF3 nanocrystals nucleated in the glass-ceramic sample are homogeneously distributed in the glass matrix with a typical size of 45±10 nm. The comparison of the fluorescence properties of Er3+-doped precursor glass and glass-ceramic confirms the successful incorporation of the rare-earth into the nanocrystals. An enhancement of the red upconversion emission due to 4F9/2→4I15/2 transition together with weak emission bands due to transitions from 2H9/2, 4F3/2,5/2, and 4F7/2 levels to the ground state are observed under excitation at 801 nm in the glass-ceramic sample. The temporal evolution of the red emission together with the excitation upconversion spectrum suggest that energy transfer processes are responsible for the enhancement of the red emission.

Luminescence in Conjugated Molecular Materials under Sub-bandgap Excitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

So, Franky

2014-05-08

Light emission in semiconductors occurs when they are under optical and electrical excitation with energy larger than the bandgap energy. In some low-dimensional semiconductor heterostructure systems, this thermodynamic limit can be violated due to radiative Auger recombination (AR), a process in which the sub-bandgap energy released from a recombined electron-hole pair is transferred to a third particle leading to radiative band-to-band recombination.1 Thus far, photoluminescence up-conversion phenomenon has been observed in some low dimensional semiconductor systems, and the effect is very weak and it can only be observed at low temperatures. Recently, we discovered that efficient electroluminescence in poly[2-methoxy-5-(2’-ethylhexyloxy)-1, phenylenevinylene]more » (MEH-PPV) polymer light-emitting devices (PLEDs) at drive voltages below its bandgap voltage could be observed when a ZnO nanoparticles (NPs) electron injection layer was inserted between the polymer and the aluminum electrode. Specifically, emitted photons with energy of 2.13 eV can be detected at operating voltages as low as 1.2 V at room temperature. Based on these data, we propose that the sub-bandgap turn-on in the MEH-PPV device is due to an Auger-assisted energy up-conversion process. The significance of this discovery is three-fold. First, radiative recombination occurs at operating voltages below the thermodynamic bandgap voltage. This process can significantly reduce the device operating voltage. For example, the current density of the device with the ZnO NC layer is almost two orders of magnitude higher than that of the device without the NC layer. Second, a reactive metal is no longer needed for the cathode. Third, this electroluminescence up-conversion process can be applied to inorganic semiconductors systems as well and their operation voltages of inorganic LEDs can be reduced to about half of the bandgap energy. Based on our initial data, we propose that the sub-bandgap turn-on in MEH-PPV devices is due to Auger-assisted energy up-conversion process. Specifically, we propose that the up-conversion process is due to charge accumulation at the polymer/NPs interface. This model requires that holes should be the dominant carriers in the polymer and the polymer/ZnO NCs heterojunction should be a type II alignment. In order to determine the mechanism of the up-conversion process, we will characterize devices fabricated using polymers with different carrier transporting properties to determine whether hole accumulation at the polymer/nanocrystals is required. Likewise, we will also use NPs with different electronic structures to fabricate devices to determine how electron accumulation affects the up-conversion process. Finally, we will measure quantitatively the interface charge accumulation by electroabsorption and correlate the results with the up-conversion photoluminescence efficiency measurements under an applied electric field.« less

Comparison of broadband noise mechanisms, analyses, and experiments on helicopters, propellers, and wind turbines

NASA Technical Reports Server (NTRS)

George, A. R.; Chou, S.-T.

1983-01-01

Experimental data on broadband noise from airfoils are compared, together with analytical methods, in order to identify the mechanisms of noise emission. Rotor noise is categorized into discrete frequency, impulsive, and broadband components, the last having a continuous spectrum originating from a random source. The results of computer simulations of different rotor blade types which produce broadband noise were compared with experimental data and among themselves in terms of predictions of the spectra obtained. Consideration was given to the overall sound pressure level, unsteady turbulence forces, rotational forces, inflow turbulence, self-generated turbulence, and turbulence in the flow. Data are presented for a helicopter rotor and light aircraft propeller. The most significant source was found to be inflow turbulence induced lift fluctuations in helicopter rotors and boundary layer trailing edge noise on large wind energy conversion systems

INFRARED SPECTROSCOPY: A TOOL FOR DETERMINATION OF THE DEGREE OF CONVERSION IN DENTAL COMPOSITES

PubMed Central

Moraes, Luciene Gonçalves Palmeira; Rocha, Renata Sanches Ferreira; Menegazzo, Lívia Maluf; de AraÚjo, Eudes Borges; Yukimitu, Keizo; Moraes, João Carlos Silos

2008-01-01

Infrared spectroscopy is one of the most widely used techniques for measurement of conversion degree in dental composites. However, to obtain good quality spectra and quantitative analysis from spectral data, appropriate expertise and knowledge of the technique are mandatory. This paper presents important details to use infrared spectroscopy for determination of the conversion degree. PMID:19089207

Spectral Emissivity (6 - 38 µm) of Jupiter's Trojan Asteroids

NASA Astrophysics Data System (ADS)

Martin, Audrey; Emery, Joshua P.; Lindsay, Sean S.

2016-10-01

Jovian Trojan asteroids, located in Jupiter's stable Lagrange points, are an extensive population of primitive bodies in the Solar System. Previous work in the visible and NIR shows Trojans have featureless, red-sloped spectra and low albedos, making mineralogical characterization difficult. However, it has been shown that three Trojans exhibit silicate emissivity features in the thermal IR (6 - 38 μm Emery et al. 2006, Icarus 182). The detected features indicate the presence of fine-grained (micron-sized) silicate dust on the surfaces, and closely resemble spectral features measured of cometary comae. We hypothesize that Trojan surface mineralogy is fairly uniform and is similar to comet dust. The principal goal of this work is, therefore, to derive primary surface mineralogy from thermal emission spectra. We present thermal IR spectra of 12 Trojans observed with NASA's Spitzer space telescope, using the InfraRed Spectrograph (IRS) in Staring Mode from June 2006 to June 2007. Eight objects were observed over the 5.2 - 38 µm spectral range, and four objects over the 7.5 - 38 µm range. Using the NEATM thermal model, we have computed size, albedo, and beaming parameter for the 12 Trojans. Results for these physical parameters are comparable to those derived from WISE data (Grav et al. 2011, ApJ 742 (1); Grav et al. 2012, ApJ 759 (49)). There are, however, some discrepancies, especially with 2797 Teucer. The emissivity spectra fall into groups that directly correlate with the red and less-red spectral slope groupings described in Emery et al. (2011, ApJ, 141(1)). Strong 10 µm emission features appear in each object, suggesting the presence of fine-grained silicates. Features found between 12-13 µm, and 18-19 µm are also observed in all spectra. We will present these new Trojan asteroid data with mineralogical estimates derived from the emissivity spectra.

Multiple visible emissions by means of up-conversion process in a microstructured tellurite glass optical fiber.

PubMed

Boetti, Nadia G; Lousteau, Joris; Negro, Davide; Mura, Emanuele; Scarpignato, Gerardo; Abrate, Silvio; Milanese, Daniel

2012-02-27

We present a microstructured fiber whose 9 µm diameter core consists in three concentric rings made of three active glasses having different rare earth oxide dopants, Yb3+/Er3+, Yb3+/Tm3+ and Yb3+/Pr3+, respectively. Morphological and optical characterization of the optical fiber are presented. The photoluminescence spectrum is investigated for different pumping conditions using a commercial 980 nm laser diode. Tuning of the RGB (or white light) emission is demonstrated not only by adjusting the pump power but also by using an optical iris as spatial filter which, thanks to the microstructured core, also acts as a spectral filter.

White-emissive tandem-type hybrid organic/polymer diodes with (0.33, 0.33) chromaticity coordinates.

PubMed

Guo, Tzung-Fang; Wen, Ten-Chin; Huang, Yi-Shun; Lin, Ming-Wei; Tsou, Chuan-Cheng; Chung, Chia-Tin

2009-11-09

This study reports fabrication of white-emissive, tandem-type, hybrid organic/polymer light-emitting diodes (O/PLED). The tandem devices are made by stacking a blue-emissive OLED on a yellow-emissive phenyl-substituted poly(para-phenylene vinylene) copolymer-based PLED and applying an organic oxide/Al/molybdenum oxide (MoO(3)) complex structure as a connecting structure or charge-generation layer (CGL). The organic oxide/Al/MoO(3) CGL functions as an effective junction interface for the transport and injection of opposite charge carriers through the stacked configuration. The electroluminescence (EL) spectra of the tandem-type devices can be tuned by varying the intensity of the emission in each emissive component to yield the visible-range spectra from 400 to 750 nm, with Commission Internationale de l'Eclairage chromaticity coordinates of (0.33, 0.33) and a high color rendering capacity as used for illumination. The EL spectra also exhibit good color stability under various bias conditions. The tandem-type device of emission with chromaticity coordinates, (0.30, 0.31), has maximum brightness and luminous efficiency over 25,000 cd/m(2) and approximately 4.2 cd/A, respectively.

A Ratio-Analysis Method to the Dynamics of Excited State Proton Transfer: Pyranine in Water and Micelles.

PubMed

Sahu, Kalyanasis; Nandi, Nilanjana; Dolai, Suman; Bera, Avisek

2018-06-05

Emission spectrum of a fluorophore undergoing excited state proton transfer (ESPT) often exhibits two distinct bands each representing emissions from protonated and deprotonated forms. The relative contribution of the two bands, best represented by an emission intensity ratio (R) (intensity maximum of the protonated band / intensity maximum of the deprotonated band), is an important parameter which usually denotes feasibility or promptness of the ESPT process. However, the use of ratio is only limited to the interpretation of steady-state fluorescence spectra. Here, for the first time, we exploit the time-dependence of the ratio (R(t)), calculated from time-resolved emission spectra (TRES) at different times, to analyze ESPT dynamics. TRES at different times were fitted with a sum of two lognormal-functions representing each peaks and then, the peak intensity ratio, R(t) was calculated and further fitted with an analytical function. Recently, a time-resolved area-normalized emission spectra (TRANES)-based analysis was presented where the decay of protonated emission or the rise of deprotonated emission intensity conveniently accounts for the ESPT dynamics. We show that these two methods are equivalent but the new method provides more insights on the nature of the ESPT process.

Building a laboratory foundation for interpreting spectral emission from x-ray binary and black hole accretion disks

NASA Astrophysics Data System (ADS)

Loisel, Guillaume

2016-10-01

Emission from accretion powered objects accounts for a large fraction of all photons in the universe and is a powerful diagnostic for their behavior and structure. Quantitative interpretation of spectrum emission from these objects requires a spectral synthesis model for photoionized plasma, since the ionizing luminosity is so large that photon driven atomic processes dominate over collisions. This is a quandary because laboratory experiments capable of testing the spectral emission models are non-existent. The models must predict the photoionized charge state distribution, the photon emission processes, and the radiation transport influence on the observed emission. We have used a decade of research at the Z facility to achieve the first simultaneous measurements of emission and absorption from photoionized plasmas. The extraordinary spectra are reproducible to within +/-2% and the E/dE 500 spectral resolution has enabled unprecedented tests of atomic structure calculations. The absorption spectra enable determination of plasma density, temperature, and charge state distribution. The emission spectra then enable tests of spectral emission models. The emission has been measured from plasmas with varying size to elucidate the radiation transport effects. This combination of measurements will provide strong constraints on models used in astrophysics. Sandia is a multi-program laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy under contract DE-AC04-94AL85000.

Bright x-ray stainless steel K-shell source development at the National Ignition Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

May, M. J.; Fournier, K. B.; Colvin, J. D.

2015-06-15

High x-ray conversion efficiency (XRCE) K-shell sources are being developed for high energy density experiments for use as backlighters and for the testing of materials exposed to high x-ray fluxes and fluences. Recently, sources with high XRCE in the K-shell x-ray energy range of iron and nickel were investigated at the National Ignition Facility (NIF). The x-ray conversion efficiency in the 5–9 keV spectral range was determined to be 6.8% ± 0.3%. These targets were 4.1 mm diameter, 4 mm tall hollow epoxy tubes having a 50 μm thick wall supporting a tube of 3 to 3.5 μm thick stainless steel. The NIF laser deposited ∼460 kJ ofmore » 3ω light into the target in a 140 TW, 3.3 ns square pulse. The absolute x-ray emission of the source was measured by two calibrated Dante x-ray spectrometers. Time resolved images filtered for the Fe K-shell were recorded to follow the heating of the target. Time integrated high-resolution spectra were recorded in the K-shell range.« less

Bright x-ray stainless steel K-shell source development at the National Ignition Facility

DOE PAGES

May, M. J.; Fournier, K. B.; Colvin, J. D.; ...

2015-06-01

High x-ray conversion efficiency (XRCE) K-shell sources are being developed for high energy density experiments for use as backlighters and for the testing of materials exposed to high x-ray fluxes and fluences. Recently, sources with high XRCE in the K-shell x-ray energy range of iron and nickel were investigated at the National Ignition Facility (NIF). The x-ray conversion efficiency in the 5–9 keV spectral range was determined to be 6.8% ± 0.3%. These targets were 4.1 mm diameter, 4 mm tall hollow epoxy tubes having a 50 μm thick wall supporting a tube of 3 to 3.5 μm thick stainlessmore » steel. The NIF laser deposited ~460 kJ of 3ω light into the target in a 140 TW, 3.3 ns square pulse. The absolute x-ray emission of the source was measured by two calibrated Dante x-ray spectrometers. In conclusion, time resolved images filtered for the Fe K-shell were recorded to follow the heating of the target. Time integrated high-resolution spectra were recorded in the K-shell range« less

Bright x-ray stainless steel K-shell source development at the National Ignition Facility

NASA Astrophysics Data System (ADS)

May, M. J.; Fournier, K. B.; Colvin, J. D.; Barrios, M. A.; Dewald, E. L.; Hohenberger, M.; Moody, J.; Patterson, J. R.; Schneider, M.; Widmann, K.; Regan, S. P.

2015-06-01

High x-ray conversion efficiency (XRCE) K-shell sources are being developed for high energy density experiments for use as backlighters and for the testing of materials exposed to high x-ray fluxes and fluences. Recently, sources with high XRCE in the K-shell x-ray energy range of iron and nickel were investigated at the National Ignition Facility (NIF). The x-ray conversion efficiency in the 5-9 keV spectral range was determined to be 6.8% ± 0.3%. These targets were 4.1 mm diameter, 4 mm tall hollow epoxy tubes having a 50 μm thick wall supporting a tube of 3 to 3.5 μm thick stainless steel. The NIF laser deposited ˜460 kJ of 3ω light into the target in a 140 TW, 3.3 ns square pulse. The absolute x-ray emission of the source was measured by two calibrated Dante x-ray spectrometers. Time resolved images filtered for the Fe K-shell were recorded to follow the heating of the target. Time integrated high-resolution spectra were recorded in the K-shell range.

Synchronous x-ray and radio mode switches: a rapid global transformation of the pulsar magnetosphere.

PubMed

Hermsen, W; Hessels, J W T; Kuiper, L; van Leeuwen, J; Mitra, D; de Plaa, J; Rankin, J M; Stappers, B W; Wright, G A E; Basu, R; Alexov, A; Coenen, T; Grießmeier, J-M; Hassall, T E; Karastergiou, A; Keane, E; Kondratiev, V I; Kramer, M; Kuniyoshi, M; Noutsos, A; Serylak, M; Pilia, M; Sobey, C; Weltevrede, P; Zagkouris, K; Asgekar, A; Avruch, I M; Batejat, F; Bell, M E; Bell, M R; Bentum, M J; Bernardi, G; Best, P; Bîrzan, L; Bonafede, A; Breitling, F; Broderick, J; Brüggen, M; Butcher, H R; Ciardi, B; Duscha, S; Eislöffel, J; Falcke, H; Fender, R; Ferrari, C; Frieswijk, W; Garrett, M A; de Gasperin, F; de Geus, E; Gunst, A W; Heald, G; Hoeft, M; Horneffer, A; Iacobelli, M; Kuper, G; Maat, P; Macario, G; Markoff, S; McKean, J P; Mevius, M; Miller-Jones, J C A; Morganti, R; Munk, H; Orrú, E; Paas, H; Pandey-Pommier, M; Pandey, V N; Pizzo, R; Polatidis, A G; Rawlings, S; Reich, W; Röttgering, H; Scaife, A M M; Schoenmakers, A; Shulevski, A; Sluman, J; Steinmetz, M; Tagger, M; Tang, Y; Tasse, C; ter Veen, S; Vermeulen, R; van de Brink, R H; van Weeren, R J; Wijers, R A M J; Wise, M W; Wucknitz, O; Yatawatta, S; Zarka, P

2013-01-25

Pulsars emit from low-frequency radio waves up to high-energy gamma-rays, generated anywhere from the stellar surface out to the edge of the magnetosphere. Detecting correlated mode changes across the electromagnetic spectrum is therefore key to understanding the physical relationship among the emission sites. Through simultaneous observations, we detected synchronous switching in the radio and x-ray emission properties of PSR B0943+10. When the pulsar is in a sustained radio-"bright" mode, the x-rays show only an unpulsed, nonthermal component. Conversely, when the pulsar is in a radio-"quiet" mode, the x-ray luminosity more than doubles and a 100% pulsed thermal component is observed along with the nonthermal component. This indicates rapid, global changes to the conditions in the magnetosphere, which challenge all proposed pulsar emission theories.

Investigating the high-frequency spectral features of SNRs Tycho, W44 and IC443 with the Sardinia Radio Telescope

NASA Astrophysics Data System (ADS)

Loru, S.; Pellizzoni, A.; Egron, E.; Righini, S.; Iacolina, M. N.; Mulas, S.; Cardillo, M.; Marongiu, M.; Ricci, R.; Bachetti, M.; Pilia, M.; Trois, A.; Ingallinera, A.; Petruk, O.; Murtas, G.; Serra, G.; Concu, F. Buffa R.; Gaudiomonte, F.; Melis, A.; Navarrini, A.; Perrodin, D.; Valente, G.

2018-05-01

The main characteristics in the radio continuum spectra of Supernova Remnants (SNRs) result from simple synchrotron emission. In addition, electron acceleration mechanisms can shape the spectra in specific ways, especially at high radio frequencies. These features are connected to the age and the peculiar conditions of the local interstellar medium interacting with the SNR. Whereas the bulk radio emission is expected at up to 20 - 50 GHz, sensitive high-resolution images of SNRs above 10 GHz are lacking and are not easily achievable, especially in the confused regions of the Galactic Plane. In the framework of the early science observations with the Sardinia Radio Telescope in February-March 2016, we obtained high-resolution images of SNRs Tycho, W44 and IC443 that provided accurate integrated flux density measurements at 21.4 GHz: 8.8 ± 0.9 Jy for Tycho, 25 ± 3 Jy for W44 and 66 ± 7 Jy for IC443. We coupled the SRT measurements with radio data available in the literature in order to characterise the integrated and spatially-resolved spectra of these SNRs, and to find significant frequency- and region-dependent spectral slope variations. For the first time, we provide direct evidence of a spectral break in the radio spectral energy distribution of W44 at an exponential cutoff frequency of 15 ± 2 GHz. This result constrains the maximum energy of the accelerated electrons in the range 6 - 13 GeV, in agreement with predictions indirectly derived from AGILE and Fermi-LAT gamma-ray observations. With regard to IC443, our results confirm the noticeable presence of a bump in the integrated spectrum around 20 - 70 GHz that could result from a spinning dust emission mechanism.

Properties of Polycyclic Aromatic Hydrocarbons in the Northwest Photon Dominated Region of NGC 7023. I. PAH Size, Charge, Composition, and Structure Distribution

NASA Technical Reports Server (NTRS)

Boersma, C.; Bregman, Jesse; Allamandola, L. J

2013-01-01

Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer Infrared Spectrograph spectral map of the northwest photon dominated region (PDR) in NGC 7023 was analyzed exclusively using PAH spectra from the NASA Ames PAH IR Spectroscopic Database (www.astrochem.org/pahdb). The 5-15 micron spectrum at each pixel is fitted using a non-negative-least-squares fitting approach. The fits are of good quality, allowing decomposition of the PAH emission into four subclasses: size, charge, composition, and hydrogen adjacency (structure). Maps tracing PAH subclass distributions across the region paint a coherent astrophysical picture. Once past some 20 seconds of arc from HD 200775, the emission is dominated by the more stable, large, symmetric, compact PAH cations with smaller, neutral PAHs taking over along the lines-of-sight toward the more distant molecular cloud. The boundary between the PDR and the denser cloud material shows up as a distinct discontinuity in the breakdown maps. Noteworthy is the requirement for PANH cations to fit the bulk of the 6.2 and 11.0 micron features and the indication of PAH photo-dehydrogenation and fragmentation close to HD 200775. Decomposition of the spectral maps into "principal" subclass template spectra provides additional insight into the behavior of each subclass. However, the general applicability of this computationally more efficient approach is presently undetermined. This is the first time the spectra of individual PAHs are exclusively used to fit the 5-15 micron region and analyze the spatial behavior of the aromatic infrared bands, providing fundamental, new information about astronomical PAH subpopulations including their dependence on, and response to, changes in local conditions.

Properties of Polycyclic Aromatic Hydrocarbons in the Northwest Photon Dominated Region of NGC 7023. I. PAH Size, Charge, Composition, and Structure Distribution

NASA Astrophysics Data System (ADS)

Boersma, C.; Bregman, J. D.; Allamandola, L. J.

2013-06-01

Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer Infrared Spectrograph spectral map of the northwest photon dominated region (PDR) in NGC 7023 was analyzed exclusively using PAH spectra from the NASA Ames PAH IR Spectroscopic Database (www.astrochem.org/pahdb). The 5-15 μm spectrum at each pixel is fitted using a non-negative-least-squares fitting approach. The fits are of good quality, allowing decomposition of the PAH emission into four subclasses: size, charge, composition, and hydrogen adjacency (structure). Maps tracing PAH subclass distributions across the region paint a coherent astrophysical picture. Once past some 20 seconds of arc from HD 200775, the emission is dominated by the more stable, large, symmetric, compact PAH cations with smaller, neutral PAHs taking over along the lines-of-sight toward the more distant molecular cloud. The boundary between the PDR and the denser cloud material shows up as a distinct discontinuity in the breakdown maps. Noteworthy is the requirement for PANH cations to fit the bulk of the 6.2 and 11.0 μm features and the indication of PAH photo-dehydrogenation and fragmentation close to HD 200775. Decomposition of the spectral maps into "principal" subclass template spectra provides additional insight into the behavior of each subclass. However, the general applicability of this computationally more efficient approach is presently undetermined. This is the first time the spectra of individual PAHs are exclusively used to fit the 5-15 μm region and analyze the spatial behavior of the aromatic infrared bands, providing fundamental, new information about astronomical PAH subpopulations including their dependence on, and response to, changes in local conditions.